Solid state phase change materials for thermal energy storage in passive solar heated buildings

NASA Astrophysics Data System (ADS)

Benson, D. K.; Christensen, C.

1983-11-01

A set of solid state phase change materials was evaluated for possible use in passive solar thermal energy storage systems. The most promising materials are organic solid solutions of pentaerythritol, pentaglycerine and neopentyl glycol. Solid solution mixtures of these compounds can be tailored so that they exhibit solid-to-solid phase transformations at any desired temperature within the range from less than 25 deg to 188 deg. Thermophysical properties such as thermal conductivity, density and volumetric expansion were measured. Computer simulations were used to predict the performance of various Trombe wall designs incorporating solid state phase change materials. Optimum performance was found to be sensitive to the choice of phase change temperatures and to the thermal conductivity of the phase change material. A molecular mechanism of the solid state phase transition is proposed and supported by infrared spectroscopic evidence.

Investigation of wall-bounded turbulence over sparsely distributed roughness

NASA Astrophysics Data System (ADS)

Placidi, Marco; Ganapathisubramani, Bharath

2011-11-01

The effects of sparsely distributed roughness elements on the structure of a turbulent boundary layer are examined by performing a series of Particle Image Velocimetry (PIV) experiments in a wind tunnel. From the literature, the best way to characterise a rough wall, especially one where the density of roughness elements is sparse, is unclear. In this study, rough surfaces consisting of sparsely and uniformly distributed LEGO® blocks are used. Five different patterns are adopted in order to examine the effects of frontal solidity (λf, frontal area of the roughness elements per unit wall-parallel area), plan solidity (λp, plan area of roughness elements per unit wall-parallel area) and the geometry of the roughness element (square and cylindrical elements), on the turbulence structure. The Karman number, Reτ , has been matched, at the value of approximately 2300, in order to compare across the different cases. In the talk, we will present detailed analysis of mean and rms velocity profiles, Reynolds stresses and quadrant decomposition.

Simultaneous Determination of Parathion, Malathion, Diazinon, and Pirimiphos Methyl in Dried Medicinal Plants Using Solid-Phase Microextraction Fibre Coated with Single-Walled Carbon Nanotubes

PubMed Central

Ahmadkhaniha, Reza; Samadi, Nasrin; Salimi, Mona; Sarkhail, Parisa; Rastkari, Noushin

2012-01-01

A reliable and sensitive headspace solid-phase microextraction gas chromatography-mass spectrometry method for simultaneous determination of different organophosphorus pesticides in dried medicinal plant samples is described. The analytes were extracted by single-walled carbon nanotubes as a new solid-phase microextraction adsorbent. The developed method showed good performance. For diazinon and pirimiphos methyl calibration, curves were linear (r 2 ≥ 0.993) over the concentration ranges from 1.5 to 300 ng g−1, and the limit of detection at signal-to-noise ratio of 3 was 0.3 ng g−1. For parathion and malathion, the linear range and limit of detection were 2.5–300 (r 2 ≥ 0.991) and 0.5 ng g−1, respectively. In addition, a comparative study between the single-walled carbon nanotubes and a commercial polydimethylsiloxane fibre for the determination of target analytes was carried out. Single-walled carbon nanotubes fibre showed higher extraction capacity, better thermal stability (over 350°C), and longer lifespan (over 250 times) than the commercial polydimethylsiloxane fibre. The developed method was successfully applied to determine target organophosphorus pesticides in real samples. PMID:22645439

Hopper apparatuses for processing a bulk solid, and related systems and methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Westover, Tyler Lott; Ryan, John Chadron Benjamin; Matthews, Austin Colter

A hopper apparatus comprises a movable wall comprising opposing walls movably connected to a support assembly and oriented at acute angles relative to a central vertical axis of the support assembly, and movement control devices configured and positioned to move the opposing walls along the support assembly to control dimensions of a discharge outlet at least partially defined by converging ends of the opposing walls; a liner assembly comprising liner structures at least partially overlying inner surfaces of the opposing walls and configured to remain at least partially stationary relative to the opposing walls during movement of the opposing walls;more » and pressure sensors between the inner surfaces of opposing walls and portions of the liner structures thereover. A bulk solids processing system and a method of processing a bulk solid are also described.« less

FLEXWAL: A computer program for predicting the wall modifications for two-dimensional, solid, adaptive-wall tunnels

NASA Technical Reports Server (NTRS)

Everhart, J. L.

1983-01-01

A program called FLEXWAL for calculating wall modifications for solid, adaptive-wall wind tunnels is presented. The method used is the iterative technique of NASA TP-2081 and is applicable to subsonic and transonic test conditions. The program usage, program listing, and a sample case are given.

Thermal Dispersion Within a Porous Medium Near a Solid Wall

NASA Technical Reports Server (NTRS)

Simon, T.; McFadden, G.; Ibrahim, M.

2006-01-01

The regenerator is a key component to Stirling cycle machine efficiency. Typical regenerators are of sintered fine wires or layers of fine-wire screens. Such porous materials are contained within solid-waH casings. Thermal energy exchange between the regenerator and the casing is important to cycle performance for the matrix and casing would not have the same axial temperature profile in an actual machine. Exchange from one to the other may allow shunting of thermal energy, reducing cycle efficiency. In this paper, temperature profiles within the near-wall region of the matrix are measured and thermal energy transport, termed thermal dispersion, is inferred. The data show how the wall affects thermal transport. Transport normal to the mean flow direction is by conduction within the solid and fluid and by advective transport within the matrix. In the near-wall region, both may be interrupted from their normal in-core pattern. Solid conduction paths are broken and scales of advective transport are damped. An equation is presented which describes this change for a wire screen mesh. The near-wall layer typically acts as an insulating layer. This should be considered in design or analysis. Effective thermal conductivity within the core is uniform. In-core transverse thermal effective conductivity values are compared to direct and indirect measurements reported elsewhere and to 3D numerical simulation results, computed previously and reported elsewhere. The 3-D CFD model is composed of six cylinders in cross flow, staggered in arrangement to match the dimensions and porosity of the matrix used in the experiments. The commercial code FLUENT is used to obtain the flow and thermal fields. The thermal dispersion and effective thermal conductivities for the matrix are computed from the results.

Study of an array of two circular jets impinging on a flat surface

NASA Astrophysics Data System (ADS)

Simionescu, Ştefan-Mugur; Dhondoo, Nilesh; Bălan, Corneliu

2018-02-01

In this study, the flow characteristics of an array of two circular, laminar air jets impinging on a smooth solid wall are experimentally and numerically investigated. Direct visualizations using high speed/resolution camera are performed. The evolution of the vortical structures in the area where the jet is deflected from axial to radial direction is emphasized, as well as the interaction between the two jets. A set of CFD numerical simulations in 2D flow domains are performed by using the commercial software Fluent, in the context of Reynolds-averaged Navier-Stokes (RANS) modeling. The numerical resultsare compared and validated with the experiments. The vorticity number is computed and plotted at two different positions from the jet nozzle, and a study of its distribution gives a clue on how the jets are interacting with each other in the proximity of the solid wall.

Experiments in a three-dimensional adaptive-wall wind tunnel

NASA Technical Reports Server (NTRS)

Schairer, E. T.

1983-01-01

Three dimensional adaptive-wall experiments were performed in the Ames Research Center (ARC) 25- by 13-cm indraft wind tunnel. A semispan wing model was mounted to one sidewall of a test section with solid sidewalls, and slotted top and bottom walls. The test section had separate top and bottom plenums which were divided into streamwise and cross-stream compartments. An iterative procedure was demonstrated for measuring wall interference and for adjusting the plenum compartment pressures to eliminate such interference. The experiments were conducted at a freestream Mach number of 0.60 and model angles of attack between 0 and 6 deg. Although in all the experiments wall interference was reduced after the plenum pressures were adjusted, interference could not be completely eliminated.

Investigation of wall-bounded turbulence over regularly distributed roughness

NASA Astrophysics Data System (ADS)

Placidi, Marco; Ganapathisubramani, Bharathram

2012-11-01

The effects of regularly distributed roughness elements on the structure of a turbulent boundary layer are examined by performing a series of Planar (high resolution l+ ~ 30) and Stereoscopic Particle Image Velocimetry (PIV) experiments in a wind tunnel. An adequate description of how to best characterise a rough wall, especially one where the density of roughness elements is sparse, is yet to be developed. In this study, rough surfaces consisting of regularly and uniformly distributed LEGO® blocks are used. Twelve different patterns are adopted in order to systematically examine the effects of frontal solidity (λf, frontal area of the roughness elements per unit wall-parallel area) and plan solidity (λp, plan area of roughness elements per unit wall-parallel area), on the turbulence structure. The Karman number, Reτ , is approximately 4000 across the different cases. Spanwise 3D vector fields at two different wall-normal locations (top of the canopy and within the log-region) are also compared to examine the spanwise homogeneity of the flow across different surfaces. In the talk, a detailed analysis of mean and rms velocity profiles, Reynolds stresses, and quadrant decomposition for the different patterns will be presented.

Applying Hanford Tank Mixing Data to Define Pulse Jet Mixer Operation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wells, Beric E.; Bamberger, Judith A.; Recknagle, Kurtis P.

Pulse jet mixed (PJM) process vessels are being developed for storing, blending, and chemical processing of nuclear waste slurries at the Waste Treatment and Immobilization Plant (WTP) to be built at Hanford, Washington. These waste slurries exhibit variable process feed characteristics including Newtonian to non-Newtonian rheologies over a range of solids loadings. Waste feed to the WTP from the Hanford Tank Farms will be accomplished via the Waste Feed Delivery (WFD) system which includes million-gallon underground storage double-shell tanks (DSTs) with dual-opposed jet mixer pumps. Experience using WFD type jet mixer pumps to mobilize actual Hanford waste in DSTs maymore » be used to establish design threshold criteria of interest to pulse jet mixed process vessel operation. This paper describes a method to evaluate the pulse jet mixed vessel capability to process waste based on information obtained during mobilizing and suspending waste by the WFD system jet mixer pumps in a DST. Calculations of jet velocity and wall shear stress in a specific pulse jet mixed process vessel were performed using a commercial computational fluid dynamics (CFD) code. The CFD-modelled process vessel consists of a 4.9-m- (16-ft-) diameter tank with a 2:1 semi-elliptical head, a single, 10-cm (4-in.) downward facing 60-degree conical nozzle, and a 0.61-m (24-in.) inside diameter PJM. The PJM is located at 70% of the vessel radius with the nozzle stand-off-distance 14 cm (6 in.) above the vessel head. The CFD modeled fluid velocity and wall shear stress can be used to estimate vessel waste-processing performance by comparison to available actual WFD system process data. Test data from the operation of jet mixer pumps in the 23-m (75-ft) diameter DSTs have demonstrated mobilization, solid particles in a sediment matrix were moved from their initial location, and suspension, mobilized solid particles were moved to a higher elevation in the vessel than their initial location, of waste solids. Jet mixer pumps were used in Hanford waste tank 241-AZ-101, and at least 95% of the 0.46-m (18-in.) deep sediment, with a shear strength of 1,500 to 4,200 Pa, was mobilized. Solids with a median particle size of 43 μm, 90th percentile of 94μm, were suspended in tank 241-AZ-101 to at least 5.5 m (216 in.) above the vessel bottom. Analytical calculations for this jet mixer pump test were used to estimate the velocities and wall shear stress that mobilized and suspended the waste. These velocities and wall shear stresses provide design threshold criteria which are metrics for system performance that can be evaluated via testing. If the fluid motion in a specific pulse jet mixed process vessel meets or exceeds the fluid motion of the demonstrated performance in the WFD system, confidence is provided that that vessel will similarly mobilize and suspend those solids if they were within the WTP. The single PJM CFD-calculated jet velocity and wall shear stress compare favorably with the design threshold criterion estimated for the tank 241-AZ-101 process data. Therefore, for both mobilization and suspension, the performance data evaluated from the WFD system testing increases confidence that the performance of the pulse jet mixed process vessels will be sufficient to process that waste even if that waste is not fully characterized.« less

Numerical Modeling of Reactive Multiphase Flow for FCC and Hot Gas Desulfurization Circulating Fluidized Beds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, Aubrey L.

2005-07-01

This work was carried out to understand the behavior of the solid and gas phases in a CFB riser. Only the riser is modeled as a straight pipe. A model with linear algebraic approximation to solids viscosity of the form, {musubs} = 5.34{epsisubs}, ({espisubs} is the solids volume fraction) with an appropriate boundary condition at the wall obtained by approximate momentum balance solution at the wall to acount for the solids recirculation is tested against experimental results. The work done was to predict the flow patterns in the CFB risers from available experimental data, including data from a 7.5-cm-ID CFBmore » riser at the Illinois Institute of Technology and data from a 20.0-cm-ID CFB riser at the Particulate Solid Research, Inc., facility. This research aims at modeling the removal of hydrogen sulfide from hot coal gas using zinc oxide as the sorbent in a circulating fluidized bed and in the process indentifying the parameters that affect the performance of the sulfidation reactor. Two different gas-solid reaction models, the unreacted shrinking core (USC) and the grain model were applied to take into account chemical reaction resistances. Also two different approaches were used to affect the hydrodynamics of the process streams. The first model takes into account the effect of micro-scale particle clustering by adjusting the gas-particle drag law and the second one assumes a turbulent core with pseudo-steady state boundary condition at the wall. A comparison is made with experimental results.« less

Two-dimensional model of a Space Station Freedom thermal energy storage canister

NASA Astrophysics Data System (ADS)

Kerslake, Thomas W.; Ibrahim, Mounir B.

1990-08-01

The Solar Dynamic Power Module being developed for Space Station Freedom uses a eutectic mixture of LiF-CaF2 phase change salt contained in toroidal canisters for thermal energy storage. Results are presented from heat transfer analyses of the phase change salt containment canister. A 2-D, axisymmetric finite difference computer program which models the canister walls, salt, void, and heat engine working fluid coolant was developed. Analyses included effects of conduction in canister walls and solid salt, conduction and free convection in liquid salt, conduction and radiation across salt vapor filled void regions and forced convection in the heat engine working fluid. Void shape, location, growth or shrinkage (due to density difference between the solid and liquid salt phases) were prescribed based on engineering judgement. The salt phase change process was modeled using the enthalpy method. Discussion of results focuses on the role of free-convection in the liquid salt on canister heat transfer performance. This role is shown to be important for interpreting the relationship between ground based canister performance (in l-g) and expected on-orbit performance (in micro-g). Attention is also focused on the influence of void heat transfer on canister wall temperature distributions. The large thermal resistance of void regions is shown to accentuate canister hot spots and temperature gradients.

Two-dimensional model of a Space Station Freedom thermal energy storage canister

NASA Astrophysics Data System (ADS)

Kerslake, Thomas W.; Ibrahim, Mounir B.

The Solar Dynamic Power Module being developed for Space Station Freedom uses a eutectic mixture of LiF-CaF2 phase change salt contained in toroidal canisters for thermal energy storage. Results are presented from heat transfer analyses of the phase-change salt containment canister. A 2-D, axisymmetric finite-difference computer program which models the canister walls, salt, void, and heat engine working fluid coolant was developed. Analyses included effects of conduction in canister walls and solid salt, conduction and free convection in liquid salt, conduction and radiation across salt vapor filled void regions, and forced convection in the heat engine working fluid. Void shape, location, and growth or shrinkage (due to density difference between the solid and liquid salt phases) were prescribed based on engineering judgement. The salt phase change process was modeled using the enthalpy method. Discussion of results focuses on the role of free-convection in the liquid salt on canister heat transfer performance. This role is shown to be important for interpreting the relationship between groundbased canister performance (in 1-g) and expected on-orbit performance (in micro-g). Attention is also focused on the influence of void heat transfer on canister wall temperature distributions. The large thermal resistance of void regions is shown to accentuate canister hot spots and temperature gradients.

Two-dimensional model of a Space Station Freedom thermal energy storage canister

NASA Technical Reports Server (NTRS)

Kerslake, Thomas W.; Ibrahim, Mounir B.

1990-01-01

The Solar Dynamic Power Module being developed for Space Station Freedom uses a eutectic mixture of LiF-CaF2 phase change salt contained in toroidal canisters for thermal energy storage. Results are presented from heat transfer analyses of the phase-change salt containment canister. A 2-D, axisymmetric finite-difference computer program which models the canister walls, salt, void, and heat engine working fluid coolant was developed. Analyses included effects of conduction in canister walls and solid salt, conduction and free convection in liquid salt, conduction and radiation across salt vapor filled void regions, and forced convection in the heat engine working fluid. Void shape, location, and growth or shrinkage (due to density difference between the solid and liquid salt phases) were prescribed based on engineering judgement. The salt phase change process was modeled using the enthalpy method. Discussion of results focuses on the role of free-convection in the liquid salt on canister heat transfer performance. This role is shown to be important for interpreting the relationship between groundbased canister performance (in 1-g) and expected on-orbit performance (in micro-g). Attention is also focused on the influence of void heat transfer on canister wall temperature distributions. The large thermal resistance of void regions is shown to accentuate canister hot spots and temperature gradients.

Two-dimensional model of a Space Station Freedom thermal energy storage canister

NASA Technical Reports Server (NTRS)

Kerslake, Thomas W.; Ibrahim, Mounir B.

1990-01-01

The Solar Dynamic Power Module being developed for Space Station Freedom uses a eutectic mixture of LiF-CaF2 phase change salt contained in toroidal canisters for thermal energy storage. Results are presented from heat transfer analyses of the phase change salt containment canister. A 2-D, axisymmetric finite difference computer program which models the canister walls, salt, void, and heat engine working fluid coolant was developed. Analyses included effects of conduction in canister walls and solid salt, conduction and free convection in liquid salt, conduction and radiation across salt vapor filled void regions and forced convection in the heat engine working fluid. Void shape, location, growth or shrinkage (due to density difference between the solid and liquid salt phases) were prescribed based on engineering judgement. The salt phase change process was modeled using the enthalpy method. Discussion of results focuses on the role of free-convection in the liquid salt on canister heat transfer performance. This role is shown to be important for interpreting the relationship between ground based canister performance (in l-g) and expected on-orbit performance (in micro-g). Attention is also focused on the influence of void heat transfer on canister wall temperature distributions. The large thermal resistance of void regions is shown to accentuate canister hot spots and temperature gradients.

Electrode property of single-walled carbon nanotubes in all-solid-state lithium ion battery using polymer electrolyte

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sakamoto, Y.; Ishii, Y.; Kawasaki, S., E-mail: kawasaki.shinji@nitech.ac.jp

2016-07-06

Electrode properties of single-walled carbon nanotubes (SWCNTs) in an all-solid-state lithium ion battery were investigated using poly-ethylene oxide (PEO) solid electrolyte. Charge-discharge curves of SWCNTs in the solid electrolyte cell were successfully observed. It was found that PEO electrolyte decomposes on the surface of SWCNTs.

Growth mechanisms of perturbations in boundary layers over a compliant wall

NASA Astrophysics Data System (ADS)

Malik, M.; Skote, Martin; Bouffanais, Roland

2018-01-01

The temporal modal and nonmodal growth of three-dimensional perturbations in the boundary layer flow over an infinite compliant flat wall is considered. Using a wall-normal velocity and wall-normal vorticity formalism, the dynamic boundary condition at the compliant wall admits a linear dependence on the eigenvalue parameter, as compared to a quadratic one in the canonical formulation of the problem. As a consequence, the continuous spectrum is accurately obtained. This enables us to effectively filter the pseudospectra, which is a prerequisite to the transient growth analysis. An energy-budget analysis for the least-decaying hydroelastic (static divergence, traveling wave flutter, and near-stationary transitional) and Tollmien-Schlichting modes in the parameter space reveals the primary routes of energy flow. Moreover, the maximum transient growth rate increases more slowly with the Reynolds number than for the solid wall case. The slowdown is due to a complex dependence of the wall-boundary condition with the Reynolds number, which translates into a transition of the fluid-solid interaction from a two-way to a one-way coupling. Unlike the solid-wall case, viscosity plays a pivotal role in the transient growth. The initial and optimal perturbations are compared with the boundary layer flow over a solid wall; differences and similarities are discussed.

Novel nano bearings constructed by physical adsorption

PubMed Central

Zhang, Yongbin

2015-01-01

The paper proposes a novel nano bearing formed by the physical adsorption of the confined fluid to the solid wall. The bearing is formed between two parallel smooth solid plane walls sliding against one another, where conventional hydrodynamic lubrication theory predicted no lubricating effect. In this bearing, the stationary solid wall is divided into two subzones which respectively have different interaction strengths with the lubricating fluid. It leads to different physical adsorption and slip properties of the lubricating fluid at the stationary solid wall respectively in these two subzones. It was found that a significant load-carrying capacity of the bearing can be generated for low lubricating film thicknesses, because of the strong physical adsorption and non-continuum effects of the lubricating film. PMID:26412488

Determination of type A trichothecenes in coix seed by magnetic solid-phase extraction based on magnetic multi-walled carbon nanotubes coupled with ultra-high performance liquid chromatography-tandem mass spectrometry.

PubMed

Dong, Maofeng; Si, Wenshuai; Wang, Weimin; Bai, Bing; Nie, Dongxia; Song, Weiguo; Zhao, Zhihui; Guo, Yirong; Han, Zheng

2016-09-01

Magnetic solid-phase extraction (m-SPE) is a promising sample preparation approach due to its convenience, speed, and simplicity. For the first time, a rapid and reliable m-SPE approach using magnetic multi-walled carbon nanotubes (m-MWCNTs) as the adsorbent was proposed for purification of type A trichothecenes including T-2 toxins (T2), HT-2 toxins (HT-2), diacetoxyscirpenol (DAS), and neosolaniol (NEO) in coix seed. The m-MWCNTs were synthesized by assembling the magnetic nanoparticles (Fe3O4) with MWCNTs by sonication through an aggregation wrap mechanism, and characterized by transmission electron microscope. Several key parameters affecting the performance of the procedure were extensively investigated including extraction solutions, desorption solvents, and m-MWCNT amounts. Under the optimal sample preparation conditions followed by analysis with ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS), high sensitivity (limit of quantification in the range of 0.3-1.5 μg kg(-1)), good linearity (R (2) > 0.99), satisfactory recovery (73.6-90.6 %), and acceptable precision (≤2.5 %) were obtained. The analytical performance of the developed method has also been successfully evaluated in real coix seed samples. Graphical Abstract Flow chart of determination of type A trichothecenes in coix seed by magnetic solid-phase extraction coupled with ultra-high performance liquid chromatography-tandem mass spectrometry.

Improper origin of polar displacements at CaTiO3 and CaMnO3 twin walls

NASA Astrophysics Data System (ADS)

Barone, Paolo; Di Sante, Domenico; Picozzi, Silvia

2014-04-01

Recent interest in novel functionalities arising at domain walls of ferroic materials naturally calls for a microscopic understanding. To this end, first-principles calculations have been performed in order to provide solid evidence of polar distortions in the twin walls of nonpolar CaTiO3 and magnetic CaMnO3. We show that such polar displacements arise from rotation and/or tilting octahedral distortions—cooperatively acting at the twin wall in both considered systems—rather than from a proper secondary ferroelectric instability, as often believed. Our results are in excellent agreement with experimental observations of domain walls in CaTiO3. In addition, we show that magnetic properties at the twin wall in CaMnO3 are also modified, thus suggesting an unexplored route to achieve and detect multiferroic ordering in a single-phase material.

[Individualized fluid-solid coupled model of intracranial aneurysms based on computed tomography angiography data].

PubMed

Wang, Fuyu; Xu, Bainan; Sun, Zhenghui; Liu, Lei; Wu, Chen; Zhang, Xiaojun

2012-10-01

To establish an individualized fluid-solid coupled model of intracranial aneurysms based on computed tomography angiography (CTA) image data. The original Dicom format image data from a patient with an intracranial aneurysm were imported into Mimics software to construct the 3D model. The fluid-solid coupled model was simulated with ANSYS and CFX software, and the sensitivity of the model was analyzed. The difference between the rigid model and fluid-solid coupled model was also compared. The fluid-solid coupled model of intracranial aneurysm was established successfully, which allowed direct simulation of the blood flow of the intracranial aneurysm and the deformation of the solid wall. The pressure field, stress field, and distribution of Von Mises stress and deformation of the aneurysm could be exported from the model. A small Young's modulus led to an obvious deformation of the vascular wall, and the walls with greater thicknesses had smaller deformations. The rigid model and the fluid-solid coupled model showed more differences in the wall shear stress and blood flow velocity than in pressure. The fluid-solid coupled model more accurately represents the actual condition of the intracranial aneurysm than the rigid model. The results of numerical simulation with the model are reliable to study the origin, growth and rupture of the aneurysms.

Rheology of the Cu-H2O nanofluid in porous channel with heat transfer: Multiple solutions

NASA Astrophysics Data System (ADS)

Raza, J.; Rohni, A. M.; Omar, Z.; Awais, M.

2017-02-01

Dynamics of nanofluid comprising a base fluid (water) with copper (Cu) nanoparticles have been considered in channel with porous walls under magnetic field influence. The channel walls are considered to be permeable in order to analyze the wall mass transfer phenomenon. Relevant mathematical modelling has been performed and the derived PDEs are converted into coupled nonlinear ODEs by using suitable transformations. Computations have been made numerically by employing the shooting technique. It is noted that multiple solutions occur for the variation of suction Reynolds number, solid volume fraction and magnetic parameters which are interpreted in detail.

Magnetic dummy molecularly imprinted polymers based on multi-walled carbon nanotubes for rapid selective solid-phase extraction of 4-nonylphenol in aqueous samples.

PubMed

Rao, Wei; Cai, Rong; Yin, Yuli; Long, Fang; Zhang, Zhaohui

2014-10-01

In this paper, a highly selective sample clean-up procedure combining magnetic dummy molecular imprinting with solid-phase extraction was developed for rapid separation and determination of 4-nonylphenol (NP) in the environmental water samples. The magnetic dummy molecularly imprinted polymers (mag-DMIPs) based on multi-walled carbon nanotubes were successfully synthesized with a surface molecular imprinting technique using 4-tert-octylphenol as the dummy template and tetraethylorthosilicate as the cross-linker. The maximum adsorption capacity of the mag-DMIPs for NP was 52.4 mg g(-1) and it took about 20 min to achieve the adsorption equilibrium. The mag-DMIPs exhibited the specific selective adsorption toward NP. Coupled with high performance liquid chromatography analysis, the mag-DMIPs were used to extract solid-phase and detect NP in real water samples successfully with the recoveries of 88.6-98.1%. Copyright © 2014 Elsevier B.V. All rights reserved.

Optimization of Tape Winding Process Parameters to Enhance the Performance of Solid Rocket Nozzle Throat Back Up Liners using Taguchi's Robust Design Methodology

NASA Astrophysics Data System (ADS)

Nath, Nayani Kishore

2017-08-01

The throat back up liners is used to protect the nozzle structural members from the severe thermal environment in solid rocket nozzles. The throat back up liners is made with E-glass phenolic prepregs by tape winding process. The objective of this work is to demonstrate the optimization of process parameters of tape winding process to achieve better insulative resistance using Taguchi's robust design methodology. In this method four control factors machine speed, roller pressure, tape tension, tape temperature that were investigated for the tape winding process. The presented work was to study the cogency and acceptability of Taguchi's methodology in manufacturing of throat back up liners. The quality characteristic identified was Back wall temperature. Experiments carried out using L 9 ' (34) orthogonal array with three levels of four different control factors. The test results were analyzed using smaller the better criteria for Signal to Noise ratio in order to optimize the process. The experimental results were analyzed conformed and successfully used to achieve the minimum back wall temperature of the throat back up liners. The enhancement in performance of the throat back up liners was observed by carrying out the oxy-acetylene tests. The influence of back wall temperature on the performance of throat back up liners was verified by ground firing test.

Solids fluidizer-injector

DOEpatents

Bulicz, Tytus R.

1990-01-01

An apparatus and process for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine.

Enhanced heat sink with geometry induced wall-jet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hossain, Md. Mahamudul, E-mail: sohel0991@gmail.com; Tikadar, Amitav; Bari, Fazlul

Mini-channels embedded in solid matrix have already proven to be a very efficient way of electronic cooling. Traditional mini-channel heat sinks consist of single layer of parallel channels. Although mini-channel heat sink can achieve very high heat flux, its pumping requirement for circulating liquid through the channel increase very sharply as the flow velocity increases. The pumping requirements of the heat sink can be reduced by increasing its performance. In this paper a novel approach to increase the thermal performance of the mini-channel heat sink is proposed through geometry induced wall jet which is a passive technique. Geometric irregularities alongmore » the channel length causes abrupt pressure change between the channels which causes cross flow through the interconnections thus one channel faces suction and other channel jet action. This suction and jet action disrupts boundary layer causing enhanced heat transfer performance. A CFD model has been developed using commercially available software package FLUENT to evaluate the technique. A parametric study of the velocities and the effect of the position of the wall-jets have been performed. Significant reduction in thermal resistance has been observed for wall-jets, it is also observed that this reduction in thermal resistance is dependent on the position and shape of the wall jet.« less

University of Maryland Wall Washer Retrofit - LED Modules Replace Halogen Lamps in a Performing Arts Center

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilkerson, Andrea M.; Abell, Thomas C.; Perrin, Tess E.

The University of Maryland (UMD) began retrofitting halogen wall washers in the Clarice Smith Performing Arts Center (CSPAC) in April 2014. The U.S. Department of Energy (DOE) Solid-State Lighting (SSL) GATEWAY program documented this process through the final installation in March 2015, summarized in this report. The wall washers illuminate hallways lining the atrium, providing task illuminance for transitioning between spaces and visual interest to the atrium boundaries. The main goals of the retrofit were to maintain the visual appearance of the space while reducing maintenance costs – energy savings was considered an additional benefit by UMD Facilities Management. UMDmore » Facilities Management is pleased with the results of this retrofit, and continues to initiate LED retrofit projects across the UMD campus.« less

From Tls Survey to 3d Solid Modeling for Documentation of Built Heritage: the Case Study of Porta Savonarola in Padua

NASA Astrophysics Data System (ADS)

Guarnieri, A.; Fissore, F.; Masiero, A.; Vettore, A.

2017-08-01

It is a matter of fact that 3D visualisation and proper documentation of cultural objects helps to preserve the history and memories of historic buildings, archaeological sites and cultural landscapes, and supports economic growth by stimulating cultural tourism. Preservation, visualisation and recreation of valuable historical and architectural objects and places has always been a serious challenge for specialists in the field. Today, the rapid developments in the fields of close-range photogrammetry, terrestrial laser scanning (TLS) and computer vision (CV) enable to carry out highly accurate 3D models so as to be extremely effective and intuitive for users who have stringent requirements and high expectations. In this note we present the results of the survey and 3D modeling of an ancient gate, Porta Savonarola, located within the remains of the medieval town walls surrounding the historical city center of Padua, Italy. The work has been undertaken within the framework of the project "Walls Multimedia Museum" (WMM) promoted by the local private association "Padua Walls Committee". The goal of the project was to develop a prototype of an "extended" virtual museum, spreaded along most interesting locations of the town walls. The survey of the ancient gate was performed with a Leica C10 and P20 terrestrial laser scanners. Once the acquired scans were properly merged together, a solid model was generated from the global point cloud, and plans and elevations were extracted from it for restoration purposes. A short multimedia video was also created for the "Walls Multimedia Museum", showing both the outer and inner part of the gate. In the paper we will discuss all the steps and challenges addressed to provide the 3D solid model of Porta Savonarola from the TLS data.

Solid-phase microextraction fiber development for sampling and analysis of volatile organohalogen compounds in air.

PubMed

Attari, Seyed Ghavameddin; Bahrami, Abdolrahman; Shahna, Farshid Ghorbani; Heidari, Mahmoud

2014-01-01

A green, environmental friendly and sensitive method for determination of volatile organohalogen compounds was described in this paper. The method is based on a homemade sol-gel single-walled carbon nanotube/silica composite coated solid-phase microextraction to develop for sampling and analysis of Carbon tetrachloride, Benzotrichloride, Chloromethyl methyl ether and Trichloroethylene in air. Application of this method was investigated under different laboratory conditions. Predetermined concentrations of each analytes were prepared in a home-made standard chamber and the influences of experimental parameters such as temperature, humidity, extraction time, storage time, desorption temperature, desorption time and the sorbent performance were investigated. Under optimal conditions, the use of single-walled carbon nanotube/silica composite fiber showed good performance, high sensitive and fast sampling of volatile organohalogen compounds from air. For linearity test the regression correlation coefficient was more than 98% for analyte of interest and linear dynamic range for the proposed fiber and the applied Gas Chromatography-Flame Ionization Detector technique was from 1 to 100 ngmL(-1). Method detection limits ranged between 0.09 to 0.2 ngmL(-1) and method quantification limits were between 0.25 and 0.7 ngmL(-1). Single-walled carbon nanotube/silica composite fiber was highly reproducible, relative standard deviations were between 4.3 to 11.7 percent.

Solids fluidizer-injector

DOEpatents

Bulicz, T.R.

1990-04-17

An apparatus and process are described for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine. 3 figs.

Atomistic Modeling of the Fluid-Solid Interface in Simple Fluids

NASA Astrophysics Data System (ADS)

Hadjiconstantinou, Nicolas; Wang, Gerald

2017-11-01

Fluids can exhibit pronounced structuring effects near a solid boundary, typically manifested in a layered structure that has been extensively shown to directly affect transport across the interface. We present and discuss several results from molecular-mechanical modeling and molecular-dynamics (MD) simulations aimed at characterizing the structure of the first fluid layer directly adjacent to the solid. We identify a new dimensionless group - termed the Wall number - which characterizes the degree of fluid layering, by comparing the competing effects of wall-fluid interaction and thermal energy. We find that in the layering regime, several key features of the first layer layer - including its distance from the solid, its width, and its areal density - can be described using mean-field-energy arguments, as well as asymptotic analysis of the Nernst-Planck equation. For dense fluids, the areal density and the width of the first layer can be related to the bulk fluid density using a simple scaling relation. MD simulations show that these results are broadly applicable and robust to the presence of a second confining solid boundary, different choices of wall structure and thermalization, strengths of fluid-solid interaction, and wall geometries.

Highly compressible and all-solid-state supercapacitors based on nanostructured composite sponge.

PubMed

Niu, Zhiqiang; Zhou, Weiya; Chen, Xiaodong; Chen, Jun; Xie, Sishen

2015-10-21

Based on polyaniline-single-walled carbon nanotubes -sponge electrodes, highly compressible all-solid-state supercapacitors are prepared with an integrated configuration using a poly(vinyl alcohol) (PVA)/H2 SO4 gel as the electrolyte. The unique configuration enables the resultant supercapacitors to be compressed as an integrated unit arbitrarily during 60% compressible strain. Furthermore, the performance of the resultant supercapacitors is nearly unchanged even under 60% compressible strain. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Comparison of airfoil results from an adaptive wall test section and a porous wall test section

NASA Technical Reports Server (NTRS)

Mineck, Raymond E.

1989-01-01

Two wind tunnel investigations were conducted to assess two different wall interference alleviation/correction techniques: adaptive test section walls and classical analytical corrections. The same airfoil model has been tested in the adaptive wall test section of the NASA-Langley 0.3 m Transonic Cryogenic Tunnel (TCT) and in the National Aeronautical Establishment (NAE) High Reynolds Number 2-D facility. The model has a 9 in. chord and a CAST 10-2/DOA 2 airfoil section. The 0.3 m TCT adaptive wall test section has four solid walls with flexible top and bottom walls. The NAE test section has porous top and bottom walls and solid side walls. The aerodynamic results corrected for top and bottom wall interference at Mach numbers from 0.3 to 0.8 at a Reynolds number of 10 by 1,000,000. Movement of the adaptive walls was used to alleviate the top and bottom wall interference in the test results from the NASA tunnel.

Bacterial cell wall composition and the influence of antibiotics by cell-wall and whole-cell NMR

PubMed Central

Romaniuk, Joseph A. H.; Cegelski, Lynette

2015-01-01

The ability to characterize bacterial cell-wall composition and structure is crucial to understanding the function of the bacterial cell wall, determining drug modes of action and developing new-generation therapeutics. Solid-state NMR has emerged as a powerful tool to quantify chemical composition and to map cell-wall architecture in bacteria and plants, even in the context of unperturbed intact whole cells. In this review, we discuss solid-state NMR approaches to define peptidoglycan composition and to characterize the modes of action of old and new antibiotics, focusing on examples in Staphylococcus aureus. We provide perspectives regarding the selected NMR strategies as we describe the exciting and still-developing cell-wall and whole-cell NMR toolkit. We also discuss specific discoveries regarding the modes of action of vancomycin analogues, including oritavancin, and briefly address the reconsideration of the killing action of β-lactam antibiotics. In such chemical genetics approaches, there is still much to be learned from perturbations enacted by cell-wall assembly inhibitors, and solid-state NMR approaches are poised to address questions of cell-wall composition and assembly in S. aureus and other organisms. PMID:26370936

Numerical investigation of influence on heat transfer characteristics to pneumatically conveyed dense phase flow by selecting models and boundary conditions

NASA Astrophysics Data System (ADS)

Zheng, Y.; Liu, Q.; Li, Y.

2012-03-01

Solids moving with a gas stream in a pipeline can be found in many industrial processes, such as power generation, chemical, pharmaceutical, food and commodity transfer processes. A mass flow rate of the solids is important characteristic that is often required to be measured (and controlled) to achieve efficient utilization of energy and raw materials in pneumatic conveying systems. The methods of measuring the mass flow rate of solids in a pneumatic pipeline can be divided into direct and indirect (inferential) measurements. A thermal solids' mass flow-meter, in principle, should ideally provide a direct measurement of solids flow rate, regardless of inhomogeneities in solids' distribution and environmental impacts. One key issue in developing a thermal solids' mass flow-meter is to characterize the heat transfer between the hot pipe wall and the gas-solids dense phase flow. The Eulerian continuum modeling with gas-solid two phases is the most common method for pneumatic transport. To model a gas-solid dense phase flow passing through a heated region, the gas phase is described as a continuous phase and the particles as the second phase. This study aims to describe the heat transfer characteristics between the hot wall and the gas-solids dense phase flow in pneumatic pipelines by modeling a turbulence gas-solid plug passing through the heated region which involves several actual and crucial issues: selections of interphase exchange coefficient, near-wall region functions and different wall surface temperatures. A sensitivity analysis was discussed to identify the influence on the heat transfer characteristics by selecting different interphase exchange coefficient models and different boundary conditions. Simulation results suggest that sensitivity analysis in the choice of models is very significant. The simulation results appear to show that a combination of choosing the Syamlal-O'Brien interphase exchange coefficient model and the standard k-ɛ model along with the standard wall function model might be the best approach, by which, the simulation data seems to be closest to the experimental results.

Solid-state NMR on bacterial cells: selective cell wall signal enhancement and resolution improvement using dynamic nuclear polarization.

PubMed

Takahashi, Hiroki; Ayala, Isabel; Bardet, Michel; De Paëpe, Gaël; Simorre, Jean-Pierre; Hediger, Sabine

2013-04-03

Dynamic nuclear polarization (DNP) enhanced solid-state nuclear magnetic resonance (NMR) has recently emerged as a powerful technique for the study of material surfaces. In this study, we demonstrate its potential to investigate cell surface in intact cells. Using Bacillus subtilis bacterial cells as an example, it is shown that the polarizing agent 1-(TEMPO-4-oxy)-3-(TEMPO-4-amino)propan-2-ol (TOTAPOL) has a strong binding affinity to cell wall polymers (peptidoglycan). This particular interaction is thoroughly investigated with a systematic study on extracted cell wall materials, disrupted cells, and entire cells, which proved that TOTAPOL is mainly accumulating in the cell wall. This property is used on one hand to selectively enhance or suppress cell wall signals by controlling radical concentrations and on the other hand to improve spectral resolution by means of a difference spectrum. Comparing DNP-enhanced and conventional solid-state NMR, an absolute sensitivity ratio of 24 was obtained on the entire cell sample. This important increase in sensitivity together with the possibility of enhancing specifically cell wall signals and improving resolution really opens new avenues for the use of DNP-enhanced solid-state NMR as an on-cell investigation tool.

Attrition-free pyrolysis to produce bio-oil and char.

PubMed

Mauviel, Guillain; Guillain, Mauviel; Kies, Fairouz; Fairouz, Kies; René, Mar Sans; Mar, Sans Rene; Ferrer, Monique; Monique, Ferrer; Lédé, Jacques; Jacques, Lédé

2009-12-01

Experiments are performed on a laboratory scale setup where beech wood chips are heated by gas convection and walls radiation. This study shows that it is possible to obtain high bio-oil and char yields with relatively low external heat transfer coefficients. The main advantage of this convection/radiation heat transfer mode compared to solid-solid collisions, applied in fluidized bed or twin screw reactors, is the reduction of solid attrition (char and sand). Thus tricky gas-solid separation through hot cyclones and/or hot filters could be avoided or reduced. It should be possible to recover directly bio-oil with less char particles and char free of sand dust. These qualities would allow easier use of these bio-products in different applications.

Multiphysics simulation of a novel concept of MEMS-based solid propellant thruster for space propulsion

NASA Astrophysics Data System (ADS)

Moríñigo, José A.; Hermida-Quesada, José

2011-12-01

This work analyzes a novel MEMS-based architecture of submillimeter size thruster for the propulsion of small spacecrafts, addressing its preliminary characterization of performance. The architecture of microthruster comprises a setup of miniaturized channels surrounding the solid-propellant reservoir filled up with a high-energetic polymer. These channels guide the hot gases from the combustion region towards the nozzle entrance located at the opposite side of the thruster. Numerical simulations of the transient response of the combustion gases and wafer heating in thruster firings have been conducted with FLUENT under a multiphysics modelling that fully couples the gas and solid parts involved. The approach includes the gas-wafer and gas-polymer thermal exchange, burnback of the polymer with a simplified non-reacting gas pyrolysis model at its front, and a slip-model inside the nozzle portion to incorporate the effect of gas-surface and rarefaction onto the gas expansion. Besides, accurate characterization of thruster operation requires the inclusion of the receding front of the polymer and heat transfer in the moving gas-solid interfaces. The study stresses the improvement attained in thermal management by the inclusion of lateral micro-channels in the device. In particular, the temperature maps reveal the significant dependence of the thermal loss on the instantaneous surface of the reservoir wall exposed to the heat flux of hot gases. Specifically, the simulations stress the benefit of implementing such a pattern of micro-channels connecting the exit of the combustion reservoir with the nozzle. The results prove that hot gases flowing along the micro-channels exert a sealing action upon the heat flux at the reservoir wall and partly mitigate the overall thermal loss at the inner-wall vicinity during the burnback. The analysis shows that propellant decomposition rate is accelerated due to surface preheating and it suggests that a delay of the flame extinction into the reservoir is possible. The simulated operation of the thruster concept shows encouraging performance.

Microstructural effects in drug release by solid and cellular polymeric dosage forms: A comparative study.

PubMed

Blaesi, Aron H; Saka, Nannaji

2017-11-01

In recent studies, we have introduced melt-processed polymeric cellular dosage forms to achieve both immediate drug release and predictable manufacture. Dosage forms ranging from minimally-porous solids to highly porous, open-cell and thin-walled structures were prepared, and the drug release characteristics investigated as the volume fraction of cells and the excipient molecular weight were varied. In the present study, both minimally-porous solid and cellular dosage forms consisting of various weight fractions of Acetaminophen drug and polyethylene glycol (PEG) excipient are prepared and analyzed. Microstructures of the solid forms and the cell walls range from single-phase solid solutions of the excipient and a small amount of drug molecules to two-phase composites of the excipient and tightly packed drug particles. Results of dissolution experiments show that the minimally-porous solid forms disintegrate and release drug by slow surface erosion. The erosion rate decreases as the drug weight fraction is increased. By contrast, the open-cell structures disintegrate rapidly by viscous exfoliation, and the disintegration time is independent of drug weight fraction. Drug release models suggest that the solid forms erode by convective mass transfer of the faster-eroding excipient if the drug volume fraction is small. At larger drug volume fractions, however, the slower-eroding drug particles hinder access of the free-flowing fluid to the excipient, thus slowing down erosion of the composite. Conversely, the disintegration rate of the cellular forms is limited by diffusion of the dissolution fluid into the excipient phase of the thin cell walls. Because the wall thickness is of the order of the drug particle size, and the particles are enveloped by the excipient during melt-processing, the drug particles cannot hinder diffusion through the excipient across the walls. Thus the disintegration time of the cellular forms is mostly unaffected by the volume fraction of drug in the walls. Copyright © 2017 Elsevier B.V. All rights reserved.

Effect of surface morphology on drag and roughness sublayer in flows over regular roughness elements

NASA Astrophysics Data System (ADS)

Placidi, Marco; Ganapathisubramani, Bharathram

2014-11-01

The effects of systematically varied roughness morphology on bulk drag and on the spatial structure of turbulent boundary layers are examined by performing a series of wind tunnel experiments. In this study, rough surfaces consisting of regularly and uniformly distributed LEGO™ bricks are employed. Twelve different patterns are adopted in order to methodically examine the individual effects of frontal solidity (λF, frontal area of the roughness elements per unit wall-parallel area) and plan solidity (λP, plan area of roughness elements per unit wall-parallel area), on both the bulk drag and the turbulence structure. A floating element friction balance based on Krogstad & Efros (2010) was designed and manufactured to measure the drag generated by the different surfaces. In parallel, high resolution planar and stereoscopic Particle Image Velocimetry (PIV) was applied to investigate the flow features. This talk will focus on the effects of each solidity parameter on the bulk drag and attempt to relate the observed trends to the flow structures in the roughness sublayer. Currently at City University London.

Atomistic modelling of evaporation and explosive boiling of thin film liquid argon over internally recessed nanostructured surface

NASA Astrophysics Data System (ADS)

Hasan, Mohammad Nasim; Shavik, Sheikh Mohammad; Rabbi, Kazi Fazle; Haque, Mominul

2016-07-01

Molecular dynamics (MD) simulations have been carried out to investigate evaporation and explosive boiling phenomena of thin film liquid argon on nanostructured solid surface with emphasis on the effect of solid-liquid interfacial wettability. The nanostructured surface considered herein consists of trapezoidal internal recesses of the solid platinum wall. The wetting conditions of the solid surface were assumed such that it covers both the hydrophilic and hydrophobic conditions and hence effect of interfacial wettability on resulting evaporation and boiling phenomena was the main focus of this study. The initial configuration of the simulation domain comprised of a three phase system (solid platinum, liquid argon and vapor argon) on which equilibrium molecular dynamics (EMD) was performed to reach equilibrium state at 90 K. After equilibrium of the three-phase system was established, the wall was set to different temperatures (130 K and 250 K for the case of evaporation and explosive boiling respectively) to perform non-equilibrium molecular dynamics (NEMD). The variation of temperature and density as well as the variation of system pressure with respect to time were closely monitored for each case. The heat flux normal to the solid surface was also calculated to illustrate the effectiveness of heat transfer for hydrophilic and hydrophobic surfaces in cases of both nanostructured surface and flat surface. The results obtained show that both the wetting condition of the surface and the presence of internal recesses have significant effect on normal evaporation and explosive boiling of the thin liquid film. The heat transfer from solid to liquid in cases of surface with recesses are higher compared to flat surface without recesses. Also the surface with higher wettability (hydrophilic) provides more favorable conditions for boiling than the low-wetting surface (hydrophobic) and therefore, liquid argon responds quickly and shifts from liquid to vapor phase faster in case of hydrophilic surface. The heat transfer rate is also much higher in case of hydrophilic surface.

Dual-Chamber/Dual-Anode Proportional Counter Incorporating an Intervening Thin-Foil Solid Neutron Converter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boatner, Lynn A; Neal, John S; Blackston, Matthew A

2012-01-01

A dual-chamber/dual-anode gas proportional counter utilizing thin solid 6LiF or 10B neutron converters coated on a 2-micon-thick Mylar film that is positioned between the two counter chambers and anodes has been designed, fabricated, and tested using a variety of fill gases including naturally abundant helium. In this device, neutron conversion products emitted from both sides of the coated converter foil are detected rather than having half of the products absorbed in the wall of a conventional tube type counter where the solid neutron converter is deposited on the tube wall. Geant4-based radiation transport calculations were used to determine the optimummore » neutron converter coating thickness for both isotopes. Solution methods for applying these optimized-thickness coatings on a Mylar film were developed that were carried out at room temperature without any specialized equipment and that can be adapted to standard coating methods such as silk screen or ink jet printing. The performance characteristics of the dual-chamber/dual-anode neutron detector were determined for both types of isotopically enriched converters. The experimental performance of the 6LiF converter-based detector was described well by modeling results from Geant4. Additional modeling studies of multiple-foil/multiple-chamber/anode configurations addressed the basic issue of the relatively longer absorption range of neutrons versus the shorter range of the conversion products for 6LiF and 10B. Combined with the experimental results, these simulations indicate that a high-performance neutron detector can be realized in a single device through the application of these multiple-foil/solid converter, multiple-chamber detector concepts.« less

Acoustically Generated Flows in Flexural Plate Wave Sensors: a Multifield Analysis

NASA Astrophysics Data System (ADS)

Sayar, Ersin; Farouk, Bakhtier

2011-11-01

Acoustically excited flows in a microchannel flexural plate wave device are explored numerically with a coupled solid-fluid mechanics model. The device can be exploited to integrate micropumps with microfluidic chips. A comprehensive understanding of the device requires the development of coupled two or three-dimensional fluid structure interactive (FSI) models. The channel walls are composed of layers of ZnO, Si3N4 and Al. An isothermal equation of state for the fluid (water) is employed. The flexural motions of the channel walls and the resulting flowfields are solved simultaneously. A parametric analysis is performed by varying the values of the driving frequency, voltage of the electrical signal and the channel height. The time averaged axial velocity is found to be proportional to the square of the wave amplitude. The present approach is superior to the method of successive approximations where the solid-liquid coupling is weak.

Paraganglioma of the vagina: a case report and review of the literature

PubMed Central

Cai, Tao; Li, Yucong; Jiang, Qingming; Wang, Dong; Huang, Yu

2014-01-01

Vaginal paraganglioma is a rare and unusual tumor occurring in the vaginal wall. It is a solitary primary paraganglioma, especially in atypical sites. Herein, we report an unusual case of a 17-year-old woman who had not experienced vomiting, or hypertension. She was found to have an immobile solid mass in the right side of her vaginal wall. Positron emission tomography/computed tomography scans revealed a well-defined solid ovoid mass adjacent to the bladder and pelvic floor. Tumor markers were within the normal range. A transient blood pressure increase occurred during the biopsy. After oral administration of antihypertensive drugs, surgery was performed to completely remove the mass. Histopathological examination indicated that it was a paraganglioma of the vagina. Repeat computed tomography examination did not reveal any local recurrence or distant metastasis during the 12-month follow-up period. PMID:24959083

Gas Near a Wall: Shortened Mean Free Path, Reduced Viscosity, and the Manifestation of the Knudsen Layer in the Navier-Stokes Solution of a Shear Flow

NASA Astrophysics Data System (ADS)

Abramov, Rafail V.

2018-06-01

For the gas near a solid planar wall, we propose a scaling formula for the mean free path of a molecule as a function of the distance from the wall, under the assumption of a uniform distribution of the incident directions of the molecular free flight. We subsequently impose the same scaling onto the viscosity of the gas near the wall and compute the Navier-Stokes solution of the velocity of a shear flow parallel to the wall. Under the simplifying assumption of constant temperature of the gas, the velocity profile becomes an explicit nonlinear function of the distance from the wall and exhibits a Knudsen boundary layer near the wall. To verify the validity of the obtained formula, we perform the Direct Simulation Monte Carlo computations for the shear flow of argon and nitrogen at normal density and temperature. We find excellent agreement between our velocity approximation and the computed DSMC velocity profiles both within the Knudsen boundary layer and away from it.

Mechanically driven centrifugal pyrolyzer

DOEpatents

Linck, Martin Brendan [Mount Prospect, IL; Bush, Phillip Vann [Bartlett, IL

2012-03-06

An apparatus for fast pyrolysis of biomass and other solid organic materials including a vertically oriented cylindrical vessel having a solids outlet proximate the bottom thereof, a vapor outlet, a top wall forming at least one opening, and an adjacent heated side wall. Disposed within the cylindrical vessel and extending through the at least one opening in the top wall is a rotor having a rotatable shaft coincident with the longitudinal axis of the cylindrical vessel to which is attached at least one substantially vertically oriented blade having one edge connected directly or indirectly with the rotatable shaft and having an opposite edge spaced apart from the heated side wall, whereby a non-radial, preferably tangential, force is imparted on the feedstock in the cylindrical vessel. Also disclosed is a method for fast pyrolysis of biomass and other solid organic materials.

Polymer mobility in cell walls of cucumber hypocotyls

NASA Technical Reports Server (NTRS)

Fenwick, K. M.; Apperley, D. C.; Cosgrove, D. J.; Jarvis, M. C.

1999-01-01

Cell walls were prepared from the growing region of cucumber (Cucumis sativus) hypocotyls and examined by solid-state 13C NMR spectroscopy, in both enzymically active and inactivated states. The rigidity of individual polymer segments within the hydrated cell walls was assessed from the proton magnetic relaxation parameter, T2, and from the kinetics of cross-polarisation from 1H to 13C. The microfibrils, including most of the xyloglucan in the cell wall, as well as cellulose, behaved as very rigid solids. A minor xyloglucan fraction, which may correspond to cross-links between microfibrils, shared a lower level of rigidity with some of the pectic galacturonan. Other pectins, including most of the galactan side-chain residues of rhamnogalacturonan I, were much more mobile and behaved in a manner intermediate between the solid and liquid states. The only difference observed between the enzymically active and inactive cell walls, was the loss of a highly mobile, methyl-esterified galacturonan fraction, as the result of pectinesterase activity.

Architectural design, interior decoration, and three-dimensional plumbing en route to multifunctional nanoarchitectures.

PubMed

Long, Jeffrey W

2007-09-01

Ultraporous aperiodic solids, such as aerogels and ambigels, are sol-gel-derived equivalents of architectures. The walls are defined by the nanoscopic, covalently bonded solid network of the gel. The vast open, interconnected space characteristic of a building is represented by the three-dimensionally continuous nanoscopic pore network. We discuss how an architectural construct serves as a powerful metaphor that guides the chemist in the design of aerogel-like nanoarchitectures and in their physical and chemical transformation into multifunctional objects that yield high performance for rate-critical applications.

Nano scale dynamics of bubble nucleation in confined liquid subjected to rapid cooling: Effect of solid-liquid interfacial wettability

NASA Astrophysics Data System (ADS)

Hasan, Mohammad Nasim; Rabbi, Kazi Fazle; Mukut, K. M.; Tamim, Saiful Islam; Faisal, A. H. M.

2017-06-01

This study focuses on the occurrence of bubble nucleation in a liquid confined in a nano scale confinement and subjected to rapid cooling at one of its wall. Due to the very small size scale of the present problem, we adopt the molecular dynamics (MD) approach. The liquid (Argon) is confined within two solid (Platinum) walls. The temperature of the upper wall of the confinement is maintained at 90 K while the lower wall is being cooled rapidly to 50 K from initial equilibrium temperature of 90 K within 0.1 ns. This results in the nucleation and formation of nanobubbles in the liquid. The pattern of bubble nucleation has been studied for three different conditions of solid-liquid interfacial wettability such as hydrophilic, hydrophobic and neutral. Behavior of bubble nucleation is significantly different in the three case of solid-liquid interfacial wettability. In case of the hydrophobic confinement (weakly adsorbing), the liquid cannot achieve deeper metastability; vapor layers appear immediately on the walls. In case of the neutral confinement (moderately adsorbing), bubble nucleation is promoted by the walls where the nucleation is heterogeneous. In case of the hydrophilic walls (strongly adsorbing) bubbles are developed inside the liquid; that is the nucleation process is homogeneous. The variation in bubble nucleation under different conditions of surface wettability has been studied by the analysis of number density distribution, spatial temperature distribution, spatial number density distribution and heat flux through the upper and lower walls of the confinement. The present study indicates that the variation of heat transfer efficiency due to different surface wettability has significant effect on the size, shape and location of bubble nucleation in case rapid cooling of liquid in nano confinement.

High energy efficient solid state laser sources. [slab geometry laser sources

NASA Technical Reports Server (NTRS)

Byer, R. L.

1983-01-01

Slab glass performance studies demonstate 18 J of output at 2 Hz with 2.3% wall plug efficiency. The goal is to achieve 10 J per pulse at 10 Hz and 3% wall plug efficiency during the next annual period. The slab concept was extended to Nd:YAG and to Nd:GGG. To date over 80 W of CW output power at 2% efficiency was generated in slab Nd:YAG. A multiplexed slab Nd:YAG pre-amplifier was invented and a Nd:YAG oscillator was demonstrated with 100kHz linewidth for eventual use in wind velocity measurements.

The optimal density of cellular solids in axial tension.

PubMed

Mihai, L Angela; Alayyash, Khulud; Wyatt, Hayley

2017-05-01

For cellular bodies with uniform cell size, wall thickness, and shape, an important question is whether the same volume of material has the same effect when arranged as many small cells or as fewer large cells. To answer this question, for finite element models of periodic structures of Mooney-type material with different structural geometry and subject to large strain deformations, we identify a nonlinear elastic modulus as the ratio between the mean effective stress and the mean effective strain in the solid cell walls, and show that this modulus increases when the thickness of the walls increases, as well as when the number of cells increases while the volume of solid material remains fixed. Since, under the specified conditions, this nonlinear elastic modulus increases also as the corresponding mean stress increases, either the mean modulus or the mean stress can be employed as indicator when the optimum wall thickness or number of cells is sought.

A two-system, single-analysis, fluid-structure interaction technique for modelling abdominal aortic aneurysms.

PubMed

Kelly, S C; O'Rourke, M J

2010-01-01

This work reports on the implementation and validation of a two-system, single-analysis, fluid-structure interaction (FSI) technique that uses the finite volume (FV) method for performing simulations on abdominal aortic aneurysm (AAA) geometries. This FSI technique, which was implemented in OpenFOAM, included fluid and solid mesh motion and incorporated a non-linear material model to represent AAA tissue. Fully implicit coupling was implemented, ensuring that both the fluid and solid domains reached convergence within each time step. The fluid and solid parts of the FSI code were validated independently through comparison with experimental data, before performing a complete FSI simulation on an idealized AAA geometry. Results from the FSI simulation showed that a vortex formed at the proximal end of the aneurysm during systolic acceleration, and moved towards the distal end of the aneurysm during diastole. Wall shear stress (WSS) values were found to peak at both the proximal and distal ends of the aneurysm and remain low along the centre of the aneurysm. The maximum von Mises stress in the aneurysm wall was found to be 408kPa, and this occurred at the proximal end of the aneurysm, while the maximum displacement of 2.31 mm occurred in the centre of the aneurysm. These results were found to be consistent with results from other FSI studies in the literature.

Wind tunnel and numerical data on the ventilation performance of windcatcher with wing wall.

PubMed

Nejat, Payam; Calautit, John Kaiser; Abd Majid, Muhd Zaimi; Hughes, Ben Richard; Zeynali, Iman; Jomehzadeh, Fatemeh

2016-12-01

The data presented in this article were the basis for the study reported in the research articles entitled "Evaluation of a two-sided windcatcher integrated with wing wall (as a new design) and comparison with a conventional windcatcher" (P. Nejat, J.K. Calautit, M.Z.A. Majid, B.R. Hughes, I. Zeynali, F. Jomehzadeh, 2016) [1] which presents the effect of wing wall on the air flow distribution under using the windcatchers as a natural ventilation equipment. Here, we detail the wind tunnel testing and numerical set-up used for obtaining the data on ventilation rates and indoor airflow distribution inside a test room with a two-sided windcatcher and wing wall. Three models were integrated with wing wall angled at 30°, 45° and 60° and another windcatcher was a conventional two-sided device. The computer-aided design (CAD) three-dimensional geometries which were produced using Solid Edge modeler are also included in the data article.

Study on the CFD simulation of refrigerated container

NASA Astrophysics Data System (ADS)

Arif Budiyanto, Muhammad; Shinoda, Takeshi; Nasruddin

2017-10-01

The objective this study is to performed Computational Fluid Dynamic (CFD) simulation of refrigerated container in the container port. Refrigerated container is a thermal cargo container constructed from an insulation wall to carry kind of perishable goods. CFD simulation was carried out use cross sectional of container walls to predict surface temperatures of refrigerated container and to estimate its cooling load. The simulation model is based on the solution of the partial differential equations governing the fluid flow and heat transfer processes. The physical model of heat-transfer processes considered in this simulation are consist of solar radiation from the sun, heat conduction on the container walls, heat convection on the container surfaces and thermal radiation among the solid surfaces. The validation of simulation model was assessed uses surface temperatures at center points on each container walls obtained from the measurement experimentation in the previous study. The results shows the surface temperatures of simulation model has good agreement with the measurement data on all container walls.

Multi-dimensional modeling of a thermal energy storage canister. M.S. Thesis - Cleveland State Univ., Dec. 1990

NASA Technical Reports Server (NTRS)

Kerslake, Thomas W.

1991-01-01

The Solar Dynamic Power Module being developed for Space Station Freedom uses a eutectic mixture of LiF-CaF2 phase change material (PCM) contained in toroidal canisters for thermal energy storage. Presented are the results from heat transfer analyses of a PCM containment canister. One and two dimensional finite difference computer models are developed to analyze heat transfer in the canister walls, PCM, void, and heat engine working fluid coolant. The modes of heat transfer considered include conduction in canister walls and solid PCM, conduction and pseudo-free convection in liquid PCM, conduction and radiation across PCM vapor filled void regions, and forced convection in the heat engine working fluid. Void shape, location, growth or shrinkage (due to density difference between the solid and liquid PCM phases) are prescribed based on engineering judgment. The PCM phase change process is analyzed using the enthalpy method. The discussion of the results focuses on how canister thermal performance is affected by free convection in the liquid PCM and void heat transfer. Characterizing these effects is important for interpreting the relationship between ground-based canister performance (in 1-g) and expected on-orbit performance (in micro-g). Void regions accentuate canister hot spots and temperature gradients due to their large thermal resistance. Free convection reduces the extent of PCM superheating and lowers canister temperatures during a portion of the PCM thermal charge period. Surprisingly small differences in canister thermal performance result from operation on the ground and operation on-orbit. This lack of a strong gravity dependency is attributed to the large contribution of container walls in overall canister energy redistribution by conduction.

Double diffusive conjugate heat transfer: Part III

NASA Astrophysics Data System (ADS)

Soudagar, Manzoor Elahi M.; Azeem

2018-05-01

The placement of a small solid wall towards cold surface of square porous cavity affects the heat transfer behavior of porous region due to restriction of fluid motion in the region occupied by solid wall. An investigation of heat transfer is carried out to understand the fluid flow and heat transfer behavior in porous cavity by solving the governing partial differential equations. Galerkin's approach is used to convert the partial differential equations into algebraic form of equations by applying finite element method. The heat transfer increases for solid towards right surface as compared to the case of solid at center of cavity.

A compact 300 kV solid-state high-voltage nanosecond generator for dielectric wall accelerator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen, Yi; Wang, Wei; Liu, Yi

2015-05-15

Compact solid-state system is the main development trend in pulsed power technologies. A compact solid-state high-voltage nanosecond pulse generator with output voltage of 300 kV amplitude, 10 ns duration (FWHM), and 3 ns rise-time was designed for a dielectric wall accelerator. The generator is stacked by 15 planar-plate Blumlein pulse forming lines (PFL). Each Blumlein PFL consists of two solid-state planar transmission lines, a GaAs photoconductive semiconductor switch, and a laser diode trigger. The key components of the generator and the experimental results are reported in this paper.

Liquefaction process for solid carbonaceous materials containing alkaline earth metal humates

DOEpatents

Epperly, William R.; Deane, Barry C.; Brunson, Roy J.

1982-01-01

An improved liquefaction process wherein wall scale and particulate agglomeration during the liquefaction of solid carbonaceous materials containing alkaline earth metal humates is reduced and/or eliminated by subjecting the solid carbonaceous materials to controlled cyclic cavitation during liquefaction. It is important that the solid carbonaceous material be slurried in a suitable solvent or diluent during liquefaction. The cyclic cavitation may be imparted via pressure cycling, cyclic agitation and the like. When pressure cycling or the like is employed an amplitude equivalent to at least 25 psia is required to effectively remove scale from the liquefaction vessel walls.

Atomistic modelling of evaporation and explosive boiling of thin film liquid argon over internally recessed nanostructured surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hasan, Mohammad Nasim, E-mail: nasim@me.buet.ac.bd.com; Shavik, Sheikh Mohammad, E-mail: shavik@me.buet.ac.bd.com; Rabbi, Kazi Fazle, E-mail: rabbi35.me10@gmail.com

2016-07-12

Molecular dynamics (MD) simulations have been carried out to investigate evaporation and explosive boiling phenomena of thin film liquid argon on nanostructured solid surface with emphasis on the effect of solid-liquid interfacial wettability. The nanostructured surface considered herein consists of trapezoidal internal recesses of the solid platinum wall. The wetting conditions of the solid surface were assumed such that it covers both the hydrophilic and hydrophobic conditions and hence effect of interfacial wettability on resulting evaporation and boiling phenomena was the main focus of this study. The initial configuration of the simulation domain comprised of a three phase system (solidmore » platinum, liquid argon and vapor argon) on which equilibrium molecular dynamics (EMD) was performed to reach equilibrium state at 90 K. After equilibrium of the three-phase system was established, the wall was set to different temperatures (130 K and 250 K for the case of evaporation and explosive boiling respectively) to perform non-equilibrium molecular dynamics (NEMD). The variation of temperature and density as well as the variation of system pressure with respect to time were closely monitored for each case. The heat flux normal to the solid surface was also calculated to illustrate the effectiveness of heat transfer for hydrophilic and hydrophobic surfaces in cases of both nanostructured surface and flat surface. The results obtained show that both the wetting condition of the surface and the presence of internal recesses have significant effect on normal evaporation and explosive boiling of the thin liquid film. The heat transfer from solid to liquid in cases of surface with recesses are higher compared to flat surface without recesses. Also the surface with higher wettability (hydrophilic) provides more favorable conditions for boiling than the low-wetting surface (hydrophobic) and therefore, liquid argon responds quickly and shifts from liquid to vapor phase faster in case of hydrophilic surface. The heat transfer rate is also much higher in case of hydrophilic surface.« less

Porous honeycomb structures formed from interconnected MnO2 sheets on CNT-coated substrates for flexible all-solid-state supercapacitors

NASA Astrophysics Data System (ADS)

Ko, Wen-Yin; Chen, You-Feng; Lu, Ke-Ming; Lin, Kuan-Jiuh

2016-01-01

The use of lightweight and easily-fabricated MnO2/carbon nanotube (CNT)-based flexible networks as binder-free electrodes and a polyvinyl alcohol/H2SO4 electrolyte for the formation of stretchable solid-state supercapacitors was examined. The active electrodes were fabricated from 3D honeycomb porous MnO2 assembled from cross-walled and interconnected sheet-architectural MnO2 on CNT-based plastic substrates (denoted as honeycomb MnO2/CNT textiles).These substrates were fabricated through a simple two-step procedure involving the coating of multi-walled carbon nanotubes (MWCNTs) onto commercial textiles by a dipping-drying process and subsequent electrodeposition of the interconnected MnO2 sheets onto the MWCNT-coated textile. With such unique MnO2 architectures integrated onto CNT flexible films, good performance was achieved with a specific capacitance of 324 F/g at 0.5 A/g. A maximum energy density of 7.2 Wh/kg and a power density as high as 3.3 kW/kg were exhibited by the honeycomb MnO2/CNT network device, which is comparable to the performance of other carbon-based and metal oxide/carbon-based solid-state supercapacitor devices. Specifically, the long-term cycling stability of this material is excellent, with almost no loss of its initial capacitance and good Coulombic efficiency of 82% after 5000 cycles. These impressive results identify these materials as a promising candidate for use in environmentally friendly, low-cost, and high-performance flexible energy-storage devices.

Porous honeycomb structures formed from interconnected MnO2 sheets on CNT-coated substrates for flexible all-solid-state supercapacitors

PubMed Central

Ko, Wen-Yin; Chen, You-Feng; Lu, Ke-Ming; Lin, Kuan-Jiuh

2016-01-01

The use of lightweight and easily-fabricated MnO2/carbon nanotube (CNT)-based flexible networks as binder-free electrodes and a polyvinyl alcohol/H2SO4 electrolyte for the formation of stretchable solid-state supercapacitors was examined. The active electrodes were fabricated from 3D honeycomb porous MnO2 assembled from cross-walled and interconnected sheet-architectural MnO2 on CNT-based plastic substrates (denoted as honeycomb MnO2/CNT textiles).These substrates were fabricated through a simple two-step procedure involving the coating of multi-walled carbon nanotubes (MWCNTs) onto commercial textiles by a dipping-drying process and subsequent electrodeposition of the interconnected MnO2 sheets onto the MWCNT-coated textile. With such unique MnO2 architectures integrated onto CNT flexible films, good performance was achieved with a specific capacitance of 324 F/g at 0.5 A/g. A maximum energy density of 7.2 Wh/kg and a power density as high as 3.3 kW/kg were exhibited by the honeycomb MnO2/CNT network device, which is comparable to the performance of other carbon-based and metal oxide/carbon-based solid-state supercapacitor devices. Specifically, the long-term cycling stability of this material is excellent, with almost no loss of its initial capacitance and good Coulombic efficiency of 82% after 5000 cycles. These impressive results identify these materials as a promising candidate for use in environmentally friendly, low-cost, and high-performance flexible energy-storage devices. PMID:26726724

High performance anode-supported tubular solid oxide fuel cells fabricated by a novel slurry-casting method

PubMed Central

Duan, Nan-Qi; Yan, Dong; Chi, Bo; Pu, Jian; Jian, Li

2015-01-01

Tubular solid oxide fuel cells were fabricated and evaluated for their microstructure and electrochemical performance. The tubular substrate was prepared by casting NiO-Y2O3 stabilized ZrO2 (YSZ) slurry on the inner wall of a plastic mold (tube). The wall thickness and uniformity were controlled by slurry viscosity and rotation speed of the tube. The cells consisted of Ni-YSZ functional anode, YSZ electrolyte and (La0.8Sr0.2)0.95MnO3-δ (LSM)-YSZ cathode prepared in sequence on the substrate by dip-coating and sintering. Their dimension was 50 mm in length, 0.8 mm in thickness and 10.5 mm in outside diameter. The peak power density of the cell at temperatures between 650 and 850°C was in the range from 85 to 522 mW cm−2 and was greatly enhanced to the range from 308 to 1220 mW cm−2 by impregnating PdO into LSM-YSZ cathode. During a cell testing at 0.7 A cm−2 and 750°C for 282 h, the impregnated PdO particles grew by coalescence, which increased the cathode polarization resistance and so that decreased the cell performance. According to the degradation tendency, the cell performance will be stabilized in a longer run. PMID:25640168

A wall interference assessment/correction system

NASA Technical Reports Server (NTRS)

Lo, Ching F.; Overby, Glenn; Qian, Cathy X.; Sickles, W. L.; Ulbrich, N.

1992-01-01

A Wall Signature method originally developed by Hackett has been selected to be adapted for the Ames 12-ft Wind Tunnel WIAC system in the project. This method uses limited measurements of the static pressure at the wall, in conjunction with the solid wall boundary condition, to determine the strength and distribution of singularities representing the test article. The singularities are used in turn for estimating blockage wall interference. The lifting interference will be treated separately by representing in a horseshoe vortex system for the model's lifting effects. The development and implementation of a working prototype will be completed, delivered and documented with a software manual. The WIAC code will be validated by conducting numerically simulated experiments rather than actual wind tunnel experiments. The simulations will be used to generate both free-air and confined wind-tunnel flow fields for each of the test articles over a range of test configurations. Specifically, the pressure signature at the test section wall will be computed for the tunnel case to provide the simulated 'measured' data. These data will serve as the input for the WIAC method--Wall Signature method. The performance of the WIAC method then may be evaluated by comparing the corrected data with those of the free-air simulation.

A particle-based model to simulate the micromechanics of single-plant parenchyma cells and aggregates

NASA Astrophysics Data System (ADS)

Van Liedekerke, P.; Ghysels, P.; Tijskens, E.; Samaey, G.; Smeedts, B.; Roose, D.; Ramon, H.

2010-06-01

This paper is concerned with addressing how plant tissue mechanics is related to the micromechanics of cells. To this end, we propose a mesh-free particle method to simulate the mechanics of both individual plant cells (parenchyma) and cell aggregates in response to external stresses. The model considers two important features in the plant cell: (1) the cell protoplasm, the interior liquid phase inducing hydrodynamic phenomena, and (2) the cell wall material, a viscoelastic solid material that contains the protoplasm. In this particle framework, the cell fluid is modeled by smoothed particle hydrodynamics (SPH), a mesh-free method typically used to address problems with gas and fluid dynamics. In the solid phase (cell wall) on the other hand, the particles are connected by pairwise interactions holding them together and preventing the fluid to penetrate the cell wall. The cell wall hydraulic conductivity (permeability) is built in as well through the SPH formulation. Although this model is also meant to be able to deal with dynamic and even violent situations (leading to cell wall rupture or cell-cell debonding), we have concentrated on quasi-static conditions. The results of single-cell compression simulations show that the conclusions found by analytical models and experiments can be reproduced at least qualitatively. Relaxation tests revealed that plant cells have short relaxation times (1 µs-10 µs) compared to mammalian cells. Simulations performed on cell aggregates indicated an influence of the cellular organization to the tissue response, as was also observed in experiments done on tissues with a similar structure.

Extraction of ochratoxin A in red wine with dopamine-coated magnetic multi-walled carbon nanotubes.

PubMed

Wan, Hong; Zhang, Bo; Bai, Xiao-Lin; Zhao, Yan; Xiao, Meng-Wei; Liao, Xun

2017-10-01

A new, rapid, green, and cost-effective magnetic solid-phase extraction of ochratoxin A from red wine samples was developed using polydopamine-coated magnetic multi-walled carbon nanotubes as the absorbent. The polydopamine-coated magnetic multi-walled carbon nanotubes were fabricated with magnetic multi-walled carbon nanotubes and dopamine by an in situ oxidative self-polymerization approach. Transmission electron microscopy, dynamic light scattering, X-ray photoelectron spectroscopy and vibrating sample magnetometry were used to characterize the absorbents. Ochratoxin A was quantified with high-performance liquid chromatography coupled with fluorescence detection, with excitation and emission wavelengths of 338 and 455 nm, respectively. The conditions affecting the magnetic solid-phase extraction procedure, such as pH, extraction solution, extraction time, absorbent amount, desorption solution and desorption time were investigated to obtain the optimal extraction conditions. Under the optimized conditions, the extraction recovery was 91.8-104.5% for ochratoxin A. A linear calibration curve was obtained in the range of 0.1-2.0 ng/mL. The limit of detection was 0.07 ng/mL, and the limit of quantitation was 0.21 ng/mL. The recoveries of ochratoxin A for spiked red wine sample ranged from 95.65 to 100.65% with relative standard deviation less than 8%. The polydopamine-coated magnetic multi-walled carbon nanotubes showed a high affinity toward ochratoxin A, allowing selective extraction and quantification of ochratoxin A from complex sample matrixes. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Acoustic streaming induced by two orthogonal ultrasound standing waves in a microfluidic channel.

PubMed

Doinikov, Alexander A; Thibault, Pierre; Marmottant, Philippe

2018-07-01

A mathematical model is derived for acoustic streaming in a microfluidic channel confined between a solid wall and a rigid reflector. Acoustic streaming is produced by two orthogonal ultrasound standing waves of the same frequency that are created by two pairs of counter-propagating leaky surface waves induced in the solid wall. The magnitudes and phases of the standing waves are assumed to be different. Full analytical solutions are found for the equations of acoustic streaming. The obtained solutions are used in numerical simulations to reveal the structure of the acoustic streaming. It is shown that the interaction of two standing waves leads to the appearance of a cross term in the equations of acoustic streaming. If the phase lag between the standing waves is nonzero, the cross term brings about circular vortices with rotation axes perpendicular to the solid wall of the channel. The vortices make fluid particles rotate and move alternately up and down between the solid wall and the reflector. The obtained results are of immediate interest for acoustomicrofluidic applications such as the ultrasonic micromixing of fluids and the manipulation of microparticles. Copyright © 2018 Elsevier B.V. All rights reserved.

Roughening of surfaces under intense and rapid heating

NASA Astrophysics Data System (ADS)

Andersen, Michael Louis

The High Average Power Laser (HAPL) project is aimed at a chamber design with a solid first wall in pursuit of sustained Laser Inertial Confinement Fusion. The wall must be able to withstand cyclic high temperatures and the corresponding thermal stresses. Tungsten was proposed as a suitable armor for the wall, because as a refractory metal, it has a high melting temperature and can act as a stress dampener. The nature of the surface loading consists of x-rays, ions, and neutrons, which through mainly thermal loading, create a biaxial surface stress. This condition causes the surface to roughen as ridges and valleys form to relieve the elastic energy. As the valleys deepen they eventually become cracks and traditional fracture mechanics can be used to determine the life of the first wall. Beginning from the Asaro-Tiller-Grinfeld instability, sharp interface calculations can be performed to determine the surface profile as a result of the interplay between surface stress energy and mass transport mechanisms. One successful approach to determine interface evolution is phase field theory and its embodiment in the numerical level-set method. Applications of the method included problems of solid/liquid and solid/vapor interfaces. In the present method, however, we develop a numerical procedure for surface profile tracking directly without the need to develop partial differential equations for the phase field, which typically smooth out sharp interfaces. Surface roughening instabilities, which are driven by a competition between elastic and surface energy contributions, are shown to be significantly controlled by plastic energy dissipation. We consider here a general parametric description of the surface of a stressed solid and through a mechanical kinetic transport mechanism, follow the temporal evolution of the surface morphology. It is found that once a groove reaches a certain depth and curvature, an instability is created that cannot be followed through elasticity alone. It is shown in this thesis that these morphological instabilities do not experience unbounded growth, as predicted by consideration of elastic energy alone, and that their growth will be severely limited by dislocation emission from high curvature grooves. Comparisons between perturbation theory and the present numerical approach are given along with comparisons to results from laser, ion, and x-ray experiments. Finally, the model is applied to the conditions of Inertial Confinement Fusion chamber walls to determine the number of cycles for crack nucleation.

Effects of Pectin Molecular Weight Changes on the Structure, Dynamics, and Polysaccharide Interactions of Primary Cell Walls of Arabidopsis thaliana: Insights from Solid-State NMR.

PubMed

Phyo, Pyae; Wang, Tuo; Xiao, Chaowen; Anderson, Charles T; Hong, Mei

2017-09-11

Significant cellulose-pectin interactions in plant cell walls have been reported recently based on 2D 13 C solid-state NMR spectra of intact cell walls, but how these interactions affect cell growth has not been probed. Here, we characterize two Arabidopsis thaliana lines with altered expression of the POLYGALACTURONASE INVOLVED IN EXPANSION1 (PGX1) gene, which encodes a polygalacturonase that cleaves homogalacturonan (HG). PGX1 AT plants overexpress PGX1, have HG with lower molecular weight, and grow larger, whereas pgx1-2 knockout plants have HG with higher molecular weight and grow smaller. Quantitative 13 C solid-state NMR spectra show that PGX1 AT cell walls have lower galacturonic acid and xylose contents and higher HG methyl esterification than controls, whereas high molecular weight pgx1-2 walls have similar galacturonic acid content and methyl esterification as controls. 1 H-transferred 13 C INEPT spectra indicate that the interfibrillar HG backbones are more aggregated whereas the RG-I side chains are more dispersed in PGX1 AT cell walls than in pgx1-2 walls. In contrast, the pectins that are close to cellulose become more mobile and have weaker cross peaks with cellulose in PGX1 AT walls than in pgx1-2 walls. Together, these results show that polygalacturonase-mediated plant growth is accompanied by increased esterification and decreased cross-linking of HG, increased aggregation of interfibrillar HG, and weaker HG-cellulose interactions. These structural and dynamical differences give molecular insights into how pectins influence wall dynamics during cell growth.

Reducing wall plasma expansion with gold foam irradiated by laser

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Lu; Ding, Yongkun, E-mail: ding-yk@vip.sina.com; Jiang, Shaoen, E-mail: jiangshn@vip.sina.com

The experimental study on the expanding plasma movement of low-density gold foam (∼1% solid density) irradiated by a high power laser is reported in this paper. Experiments were conducted using the SG-III prototype laser. Compared to solid gold with 19.3 g/cc density, the velocities of X-ray emission fronts moving off the wall are much smaller for gold foam with 0.3 g/cc density. Theoretical analysis and MULTI 1D simulation results also show less plasma blow-off, and that the density contour movement velocities of gold foam are smaller than those of solid gold, agreeing with experimental results. These results indicate that foam walls havemore » advantages in symmetry control and lowering plasma fill when used in ignition hohlraum.« less

Water Walls for Life Support

NASA Technical Reports Server (NTRS)

Hammoudeh, Mona (Inventor); Flynn, Michael T. (Inventor); Gormly, Sherwin J. (Inventor); Richardson, Tra-My Justine (Inventor)

2017-01-01

A method and associated system for processing waste gases, liquids and solids, produced by human activity, to separate (i) liquids suitable for processing to produce potable water, (ii) solids and liquids suitable for construction of walls suitable for enclosing a habitat volume and for radiation shielding, and (iii) other fluids and solids that are not suitable for processing. A forward osmosis process and a reverse osmosis process are sequentially combined to reduce fouling and to permit accumulation of different processable substances. The invention may be used for long term life support of human activity.

Analysis of Solar Chimneys in Different Climate Zones - Case of Social Housing in Ecuador

NASA Astrophysics Data System (ADS)

Godoy-Vaca, Luis; Almaguer, Manuel; Martínez-Gómez, Javier; Lobato, Andrea; Palme, Massimo

2017-10-01

The aim of this research is to simulate the performance of a solar chimney located in different macro-zones in Ecuador. The proposed solar chimney model was simulated using a python script in order to predict the temperature distribution and the mass flow over time. The results obtained were firstly compared with experimental data for dry-warm climate. Then, the model was evaluated and tested in real weather conditions: dry-warm, moist-warm and rainy-cold. In addition, the assumed chimney dimensions were chosen according to the literature for the studied conditions. In spite of evaluating the best nightly ventilation, different chimney wall materials were tested: solid brick, common brick and reinforced concrete. The results showed that concrete in a dry-warm climate, a metallic layer on the gap with solid brick in a moist-warm climate and reinforced concrete in a rainy cold climate used for the absorbent wall improve the thermal inertia of the social housing.

Molecular dynamic simulation of Copper and Platinum nanoparticles Poiseuille flow in a nanochannels

NASA Astrophysics Data System (ADS)

Toghraie, Davood; Mokhtari, Majid; Afrand, Masoud

2016-10-01

In this paper, simulation of Poiseuille flow within nanochannel containing Copper and Platinum particles has been performed using molecular dynamic (MD). In this simulation LAMMPS code is used to simulate three-dimensional Poiseuille flow. The atomic interaction is governed by the modified Lennard-Jones potential. To study the wall effects on the surface tension and density profile, we placed two solid walls, one at the bottom boundary and the other at the top boundary. For solid-liquid interactions, the modified Lennard-Jones potential function was used. Velocity profiles and distribution of temperature and density have been obtained, and agglutination of nanoparticles has been discussed. It has also shown that with more particles, less time is required for the particles to fuse or agglutinate. Also, we can conclude that the agglutination time in nanochannel with Copper particles is faster that in Platinum nanoparticles. Finally, it is demonstrated that using nanoparticles raises thermal conduction in the channel.

Fluid-solid interaction: benchmarking of an external coupling of ANSYS with CFX for cardiovascular applications.

PubMed

Hose, D R; Lawford, P V; Narracott, A J; Penrose, J M T; Jones, I P

2003-01-01

Fluid-solid interaction is a primary feature of cardiovascular flows. There is increasing interest in the numerical solution of these systems as the extensive computational resource required for such studies becomes available. One form of coupling is an external weak coupling of separate solid and fluid mechanics codes. Information about the stress tensor and displacement vector at the wetted boundary is passed between the codes, and an iterative scheme is employed to move towards convergence of these parameters at each time step. This approach has the attraction that separate codes with the most extensive functionality for each of the separate phases can be selected, which might be important in the context of the complex rheology and contact mechanics that often feature in cardiovascular systems. Penrose and Staples describe a weak coupling of CFX for computational fluid mechanics to ANSYS for solid mechanics, based on a simple Jacobi iteration scheme. It is important to validate the coupled numerical solutions. An extensive analytical study of flow in elastic-walled tubes was carried out by Womersley in the late 1950s. This paper describes the performance of the coupling software for the straight elastic-walled tube, and compares the results with Womersley's analytical solutions. It also presents preliminary results demonstrating the application of the coupled software in the context of a stented vessel.

Desleucyl-Oritavancin with a Damaged d-Ala-d-Ala Binding Site Inhibits the Transpeptidation Step of Cell-Wall Biosynthesis in Whole Cells of Staphylococcus aureus.

PubMed

Kim, Sung Joon; Singh, Manmilan; Sharif, Shasad; Schaefer, Jacob

2017-03-14

We have used solid-state nuclear magnetic resonance to characterize the exact nature of the dual mode of action of oritavancin in preventing cell-wall assembly in Staphylococcus aureus. Measurements performed on whole cells labeled selectively in vivo have established that des-N-methylleucyl-N-4-(4-fluorophenyl)benzyl-chloroeremomycin, an Edman degradation product of [ 19 F]oritavancin, which has a damaged d-Ala-d-Ala binding aglycon, is a potent inhibitor of the transpeptidase activity of cell-wall biosynthesis. The desleucyl drug binds to partially cross-linked peptidoglycan by a cleft formed between the drug aglycon and its biphenyl hydrophobic side chain. This type of binding site is present in other oritavancin-like glycopeptides, which suggests that for these drugs a similar transpeptidase inhibition occurs.

Carbon-Nanotube Schottky Diodes

NASA Technical Reports Server (NTRS)

Manohara, Harish; Wong, Eric; Schlecht, Erich; Hunt, Brian; Siegel, Peter

2006-01-01

Schottky diodes based on semiconducting single-walled carbon nanotubes are being developed as essential components of the next generation of submillimeter-wave sensors and sources. Initial performance predictions have shown that the performance characteristics of these devices can exceed those of the state-of-the-art solid-state Schottky diodes that have been the components of choice for room-temperature submillimeter-wave sensors for more than 50 years. For state-of-the-art Schottky diodes used as detectors at frequencies above a few hundred gigahertz, the inherent parasitic capacitances associated with their semiconductor junction areas and the resistances associated with low electron mobilities limit achievable sensitivity. The performance of such a detector falls off approximately exponentially with frequency above 500 GHz. Moreover, when used as frequency multipliers for generating signals, state-of-the-art solid-state Schottky diodes exhibit extremely low efficiencies, generally putting out only micro-watts of power at frequencies up to 1.5 THz. The shortcomings of the state-of-the-art solid-state Schottky diodes can be overcome by exploiting the unique electronic properties of semiconducting carbon nanotubes. A single-walled carbon nanotube can be metallic or semiconducting, depending on its chirality, and exhibits high electron mobility (recently reported to be approx.= 2x10(exp 5)sq cm/V-s) and low parasitic capacitance. Because of the narrowness of nanotubes, Schottky diodes based on carbon nanotubes have ultra-small junction areas (of the order of a few square nanometers) and consequent junction capacitances of the order of 10(exp -18) F, which translates to cutoff frequency >5 THz. Because the turn-on power levels of these devices are very low (of the order of nano-watts), the input power levels needed for pumping local oscillators containing these devices should be lower than those needed for local oscillators containing state-of-the-art solid-state Schottky diodes.

High-Power Piezoelectric Acoustic-Electric Power Feedthru for Metal Walls

NASA Technical Reports Server (NTRS)

Bao, Xiaoqi; Biederman, Will; Sherrit, Stewart; Badescu, Mircea; Bar-Cohen, Yoseph; Jones, Christopher; Aldrich, Jack; Chang, Zensheu

2008-01-01

Piezoelectric acoustic-electric power feed-through devices transfer electric power wirelessly through a solid wall by using acoustic waves. This approach allows for the removal of holes through structures. The technology is applicable to power supply for electric equipment inside sealed containers, vacuum or pressure vessels, etc where the holes on the wall are prohibitive or result in significant performance degrade or complex designs. In the author's previous work, 100-W electric power was transferred through a metal wall by a small, simple-structure piezoelectric device. To meet requirements of higher power applications, the feasibility to transfer kilowatts level power was investigated. Pre-stressed longitudinal piezoelectric feedthru devices were analyzed by finite element model. An equivalent circuit model was developed to predict the power transfer characteristics to different electric loads. Based on the analysis results, a prototype device was designed, fabricated and a demonstration of the transmission of electric power up to 1-kW was successfully conducted. The methods to minimize the plate wave excitation on the wall were also analyzed. Both model analysis and experimental results are presented in detail in this presentation.

Experimental and numerical investigation on the ignition and combustion stability in solid fuel ramjet with swirling flow

NASA Astrophysics Data System (ADS)

Musa, Omer; Xiong, Chen; Changsheng, Zhou

2017-08-01

The present article investigates experimentally and numerically the ignition and flame stability of high-density polyethylene solid fuel with incoming swirling air through a solid fuel ramjet (SFRJ). A new design of swirler is proposed and used in this work. Experiments on connected pipes test facility were performed for SFRJ with and without swirl. An in-house code has been developed to simulate unsteady, turbulent, reacting, swirling flow in the SFRJ. Four different swirl intensities are utilized to study experimentally and numerically the effect of swirl number on the transient regression, ignition of the solid fuel in a hot-oxidizing flow and combustion phenomenon in the SFRJ. The results showed that using swirl flow decreases the ignition time delay, recirculation zone length, and the distance between the flame and the wall, meanwhile, increases the residence time, heat transfer, regression rate and mixing degree, thus, improving the combustion efficiency and stability.

Particle control and plasma performance in the Lithium Tokamak eXperimenta)

NASA Astrophysics Data System (ADS)

Majeski, R.; Abrams, T.; Boyle, D.; Granstedt, E.; Hare, J.; Jacobson, C. M.; Kaita, R.; Kozub, T.; LeBlanc, B.; Lundberg, D. P.; Lucia, M.; Merino, E.; Schmitt, J.; Stotler, D.; Biewer, T. M.; Canik, J. M.; Gray, T. K.; Maingi, R.; McLean, A. G.; Kubota, S.; Peebles, W. A.; Beiersdorfer, P.; Clementson, J. H. T.; Tritz, K.

2013-05-01

The Lithium Tokamak eXperiment is a small, low aspect ratio tokamak [Majeski et al., Nucl. Fusion 49, 055014 (2009)], which is fitted with a stainless steel-clad copper liner, conformal to the last closed flux surface. The liner can be heated to 350 °C. Several gas fueling systems, including supersonic gas injection and molecular cluster injection, have been studied and produce fueling efficiencies up to 35%. Discharges are strongly affected by wall conditioning. Discharges without lithium wall coatings are limited to plasma currents of order 10 kA, and discharge durations of order 5 ms. With solid lithium coatings discharge currents exceed 70 kA, and discharge durations exceed 30 ms. Heating the lithium wall coating, however, results in a prompt degradation of the discharge, at the melting point of lithium. These results suggest that the simplest approach to implementing liquid lithium walls in a tokamak—thin, evaporated, liquefied coatings of lithium—does not produce an adequately clean surface.

Evidence for a Saponin Biosynthesis Pathway in the Body Wall of the Commercially Significant Sea Cucumber Holothuria scabra.

PubMed

Mitu, Shahida Akter; Bose, Utpal; Suwansa-Ard, Saowaros; Turner, Luke H; Zhao, Min; Elizur, Abigail; Ogbourne, Steven M; Shaw, Paul Nicholas; Cummins, Scott F

2017-11-07

The sea cucumber (phylum Echinodermata) body wall is the first line of defense and is well known for its production of secondary metabolites; including vitamins and triterpenoid glycoside saponins that have important ecological functions and potential benefits to human health. The genes involved in the various biosynthetic pathways are unknown. To gain insight into these pathways in an echinoderm, we performed a comparative transcriptome analysis and functional annotation of the body wall and the radial nerve of the sea cucumber Holothuria scabra ; to define genes associated with body wall metabolic functioning and secondary metabolite biosynthesis. We show that genes related to signal transduction mechanisms were more highly represented in the H. scabra body wall, including genes encoding enzymes involved in energy production. Eight of the core triterpenoid biosynthesis enzymes were found, however, the identity of the saponin specific biosynthetic pathway enzymes remains unknown. We confirm the body wall release of at least three different triterpenoid saponins using solid phase extraction followed by ultra-high-pressure liquid chromatography-quadrupole time of flight-mass spectrometry. The resource we have established will help to guide future research to explore secondary metabolite biosynthesis in the sea cucumber.

Multimaterial lamination as a means of retarding penetration and spallation failures in plates

NASA Technical Reports Server (NTRS)

Dibattista, J. D.; Humes, D. H.

1972-01-01

Experimental data are presented which show that hypervelocity impact spallation and penetration failures of a single solid aluminum plate and of a solid aluminum plate spaced a distance behind a Whipple meteor bumper may be retarded by replacing the solid aluminum plate with a laminated plate. Four sets of experiments were conducted. The first set of experiments was conducted with projectile mass and velocity held constant and with polycarbonate cylinders impacted into single plates of different construction. The second set of experiments was done with single plates of various construction and aluminum spherical projectiles of similar mass but different velocities. These two experiments showed that a laminated plate of aluminum and polycarbonate or aluminum and methyl methacrylate could prevent spallation and penetration failures with a lower areal density than either an all-aluminum laminated plate or a solid aluminum plate. The aluminum laminated plate was in turn superior to the solid aluminum plate in resisting spallation and penetration failures. In addition, through an example of 6061-T6 aluminum and methyl methacrylate, it is shown that a laminated structure ballistically superior to its parent materials may be built. The last two sets of experiments were conducted using bumper-protected main walls of solid aluminum and of laminated aluminum and polycarbonate. Again, under hypervelocity impact conditions, the laminated main walls were superior to the solid aluminum main walls in retarding spallation and penetration failures.

Dry-Surface Simulation Method for the Determination of the Work of Adhesion of Solid-Liquid Interfaces.

PubMed

Leroy, Frédéric; Müller-Plathe, Florian

2015-08-04

We introduce a methodology, referred to as the dry-surface method, to calculate the work of adhesion of heterogeneous solid-liquid interfaces by molecular simulation. This method employs a straightforward thermodynamic integration approach to calculate the work of adhesion as the reversible work to turn off the attractive part of the actual solid-liquid interaction potential. It is formulated in such a way that it may be used either to evaluate the ability of force fields to reproduce reference values of the work of adhesion or to optimize force-field parameters with reference values of the work of adhesion as target quantities. The methodology is tested in the case of water on a generic model of nonpolar substrates with the structure of gold. It is validated through a quantitative comparison to phantom-wall calculations and against a previous characterization of the thermodynamics of the gold-water interface. It is found that the work of adhesion of water on nonpolar substrates is a nonlinear function of the microscopic solid-liquid interaction energy parameter. We also comment on the ability of mean-field approaches to predict the work of adhesion of water on nonpolar substrates. In addition, we discuss in detail the information on the solid-liquid interfacial thermodynamics delivered by the phantom-wall approach. We show that phantom-wall calculations yield the solid-liquid interfacial tension relative to the solid surface tension rather than the absolute solid-liquid interfacial tension as previously believed.

Improvements of the cyclone separator performance by down-comer tubes.

PubMed

Ganegama Bogodage, Sakura; Leung, A Y T

2016-07-05

Enhancement of fine particle (PM2.5) separation is important for cyclone separators to reduce any extra purification process required at the outlet. Therefore, the present experimental research was performed to explore the performance of cyclone separators modified with down-comer tubes at solid loading rates from 0 to 8.0 g/m(3) with a 10 m/s inlet velocity. The study proved the effectiveness of down-comer tubes in reducing the particle re-entrainment and increasing the finer separation with acceptable pressure drops, which was pronounced at low solid loading conditions. The experimental results were compared with theories of Smolik and Muschelknautz. Theories were acceptable for certain ranges, and theory breakdown was mainly due to the neglect of particle agglomeration, re-entrainment and the reduction of swirling energy, as well as the increase of wall friction due to presence of particles. Copyright © 2016. Published by Elsevier B.V.

Solid oxide fuel cell having compound cross flow gas patterns

DOEpatents

Fraioli, A.V.

1983-10-12

A core construction for a fuel cell is disclosed having both parallel and cross flow passageways for the fuel and the oxidant gases. Each core passageway is defined by electrolyte and interconnect walls. Each electrolyte wall consists of cathode and anode materials sandwiching an electrolyte material. Each interconnect wall is formed as a sheet of inert support material having therein spaced small plugs of interconnect material, where cathode and anode materials are formed as layers on opposite sides of each sheet and are electrically connected together by the interconnect material plugs. Each interconnect wall in a wavy shape is connected along spaced generally parallel line-like contact areas between corresponding spaced pairs of generally parallel electrolyte walls, operable to define one tier of generally parallel flow passageways for the fuel and oxidant gases. Alternate tiers are arranged to have the passageways disposed normal to one another. Solid mechanical connection of the interconnect walls of adjacent tiers to the opposite sides of the common electrolyte wall therebetween is only at spaced point-like contact areas, 90 where the previously mentioned line-like contact areas cross one another.

Solid oxide fuel cell having compound cross flow gas patterns

DOEpatents

Fraioli, Anthony V.

1985-01-01

A core construction for a fuel cell is disclosed having both parallel and cross flow passageways for the fuel and the oxidant gases. Each core passageway is defined by electrolyte and interconnect walls. Each electrolyte wall consists of cathode and anode materials sandwiching an electrolyte material. Each interconnect wall is formed as a sheet of inert support material having therein spaced small plugs of interconnect material, where cathode and anode materials are formed as layers on opposite sides of each sheet and are electrically connected together by the interconnect material plugs. Each interconnect wall in a wavy shape is connected along spaced generally parallel line-like contact areas between corresponding spaced pairs of generally parallel electrolyte walls, operable to define one tier of generally parallel flow passageways for the fuel and oxidant gases. Alternate tiers are arranged to have the passageways disposed normal to one another. Solid mechanical connection of the interconnect walls of adjacent tiers to the opposite sides of the common electrolyte wall therebetween is only at spaced point-like contact areas, 90 where the previously mentioned line-like contact areas cross one another.

Simulation of forced convection in a channel with nanofluid by the lattice Boltzmann method

PubMed Central

2013-01-01

This paper presents a numerical study of the thermal performance of fins mounted on the bottom wall of a horizontal channel and cooled with either pure water or an Al2O3-water nanofluid. The bottom wall of the channel is heated at a constant temperature and cooled by mixed convection of laminar flow at a relatively low temperature. The results of the numerical simulation indicate that the heat transfer rate of fins is significantly affected by the Reynolds number (Re) and the thermal conductivity of the fins. The influence of the solid volume fraction on the increase of heat transfer is more noticeable at higher values of the Re. PMID:23594696

Production, properties, and applications of hydrocolloid cellular solids.

PubMed

Nussinovitch, Amos

2005-02-01

Many common synthetic and edible materials are, in fact, cellular solids. When classifying the structure of cellular solids, a few variables, such as open vs. closed cells, flexible vs. brittle cell walls, cell-size distribution, cell-wall thickness, cell shape, the uniformity of the structure of the cellular solid and the different scales of length are taken into account. Compressive stress-strain relationships of most cellular solids can be easily identified according to their characteristic sigmoid shape, reflecting three deformation mechanisms: (i) elastic distortion under small strains, (ii) collapse and/or fracture of the cell walls, and (iii) densification. Various techniques are used to produce hydrocolloid (gum) cellular solids. The products of these include (i) sponges, obtained when the drying gel contains the occasionally produced gas bubbles; (ii) sponges produced by the immobilization of microorganisms; (iii) solid foams produced by drying foamed solutions or gels containing oils, and (iv) hydrocolloid sponges produced by enzymatic reactions. The porosity of the manufactured cellular solid is subject to change and depends on its composition and the processing technique. The porosity is controlled by a range of methods and the resulting surface structures can be investigated by microscopy and analyzed using fractal methods. Models used to describe stress-strain behaviors of hydrocolloid cellular solids as well as multilayered products and composites are discussed in detail in this manuscript. Hydrocolloid cellular solids have numerous purposes, simple and complex, ranging from dried texturized fruits to carriers of vitamins and other essential micronutrients. They can also be used to control the acoustic response of specific dry food products, and have a great potential for future use in countless different fields, from novel foods and packaging to medicine and medical care, daily commodities, farming and agriculture, and the environmental, chemical, and even electronic industries.

Monolithic Solid Based on Single-Walled Carbon Nanohorns: Preparation, Characterization, and Practical Evaluation as a Sorbent.

PubMed

Fresco-Cala, Beatriz; López-Lorente, Ángela I; Cárdenas, Soledad

2018-05-25

A monolithic solid based solely on single walled carbon nanohorns (SWNHs) was prepared without the need of radical initiators or gelators. The procedure involves the preparation of a wet jelly-like system of pristine SWNHs followed by slow drying (48 h) at 25 °C. As a result, a robust and stable porous network was formed due to the interaction between SWNHs not only via π-π and van der Waals interactions, but also via the formation of carbon bonds similar to those observed within dahlia aggregates. Pristine SWNHs and the SWNH monolith were characterized by several techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), confocal laser scanning microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and nitrogen intrusion porosimetry. Taking into account the efficiency of carbon nanoparticles in sorption processes, the potential applicability of the SWNH-monolith in this research field was explored using toluene; m-, p-, and o-xylene; ethylbenzene; and styrene, as target analytes. Detection limits were 0.01 µg·L -1 in all cases and the inter-day precision was in the interval 7.4⁻15.7%. The sorbent performance of the nanostructured monolithic solid was evaluated by extracting the selected compounds from different water samples with recovery values between 81.5% and 116.4%.

Progress Towards a Cartesian Cut-Cell Method for Viscous Compressible Flow

NASA Technical Reports Server (NTRS)

Berger, Marsha; Aftosmis, Michael J.

2011-01-01

The proposed paper reports advances in developing a method for high Reynolds number compressible viscous flow simulations using a Cartesian cut-cell method with embedded boundaries. This preliminary work focuses on accuracy of the discretization near solid wall boundaries. A model problem is used to investigate the accuracy of various difference stencils for second derivatives and to guide development of the discretization of the viscous terms in the Navier-Stokes equations. Near walls, quadratic reconstruction in the wall-normal direction is used to mitigate mesh irregularity and yields smooth skin friction distributions along the body. Multigrid performance is demonstrated using second-order coarse grid operators combined with second-order restriction and prolongation operators. Preliminary verification and validation for the method is demonstrated using flat-plate and airfoil examples at compressible Mach numbers. Simulations of flow on laminar and turbulent flat plates show skin friction and velocity profiles compared with those from boundary-layer theory. Airfoil simulations are performed at laminar and turbulent Reynolds numbers with results compared to both other simulations and experimental data

Superamphiphobic Silicon-Nanowire-Embedded Microsystem and In-Contact Flow Performance of Gas and Liquid Streams.

PubMed

Ko, Dong-Hyeon; Ren, Wurong; Kim, Jin-Oh; Wang, Jun; Wang, Hao; Sharma, Siddharth; Faustini, Marco; Kim, Dong-Pyo

2016-01-26

Gas and liquid streams are invariably separated either by a solid wall or by a membrane for heat or mass transfer between the gas and liquid streams. Without the separating wall, the gas phase is present as bubbles in liquid or, in a microsystem, as gas plugs between slugs of liquid. Continuous and direct contact between the two moving streams of gas and liquid is quite an efficient way of achieving heat or mass transfer between the two phases. Here, we report a silicon nanowire built-in microsystem in which a liquid stream flows in contact with an underlying gas stream. The upper liquid stream does not penetrate into the lower gas stream due to the superamphiphobic nature of the silicon nanowires built into the bottom wall, thereby preserving the integrity of continuous gas and liquid streams, although they are flowing in contact. Due to the superamphiphobic nature of silicon nanowires, the microsystem provides the best possible interfacial mass transfer known to date between flowing gas and liquid phases, which can achieve excellent chemical performance in two-phase organic syntheses.

A new model for two-dimensional numerical simulation of pseudo-2D gas-solids fluidized beds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Tingwen; Zhang, Yongmin

2013-10-11

Pseudo-two dimensional (pseudo-2D) fluidized beds, for which the thickness of the system is much smaller than the other two dimensions, is widely used to perform fundamental studies on bubble behavior, solids mixing, or clustering phenomenon in different gas-solids fluidization systems. The abundant data from such experimental systems are very useful for numerical model development and validation. However, it has been reported that two-dimensional (2D) computational fluid dynamic (CFD) simulations of pseudo-2D gas-solids fluidized beds usually predict poor quantitative agreement with the experimental data, especially for the solids velocity field. In this paper, a new model is proposed to improve themore » 2D numerical simulations of pseudo-2D gas-solids fluidized beds by properly accounting for the frictional effect of the front and back walls. Two previously reported pseudo-2D experimental systems were simulated with this model. Compared to the traditional 2D simulations, significant improvements in the numerical predictions have been observed and the predicted results are in better agreement with the available experimental data.« less

Preliminary Results of Solid Gas Generator Micropropulsion

NASA Technical Reports Server (NTRS)

deGroot, Wilhelmus A.; Reed, Brian D.; Brenizer, Marshall

1999-01-01

A decomposing solid thruster concept, which creates a more benign thermal and chemical environment than solid propellant combustion, while maintaining, performance similar to solid combustion, is described. A Micro-Electro-Mechanical (MEMS) thruster concept with diode laser and fiber-optic initiation is proposed, and thruster components fabricated with MEMS technology are presented. A high nitrogen content solid gas generator compound is evaluated and tested in a conventional axisymmetric thrust chamber with nozzle throat area ratio of 100. Results show incomplete decomposition of this compound in both low pressure (1 kPa) and high pressure (1 MPa) environments, with decomposition of up to 80% of the original mass. Chamber pressures of 1.1 MPa were obtained, with maximum calculated thrust of approximately 2.7 N. Resistively heated wires and resistively heated walls were used to initiate decomposition. Initiation tests using available lasers were unsuccessful, but infrared spectra of the compound show that the laser initiation tests used inappropriate wavelengths for optimal propellant absorption. Optimal wavelengths for laser ignition were identified. Data presented are from tests currently in progress. Alternative solid gas generator compounds are being evaluated for future tests.

30 CFR 18.38 - Leads through common walls.

Code of Federal Regulations, 2014 CFR

2014-07-01

... APPROVAL OF MINING PRODUCTS ELECTRIC MOTOR-DRIVEN MINE EQUIPMENT AND ACCESSORIES Construction and Design... from one explosion-proof enclosure to another through conduit, tubing, piping, or other solid-wall...

30 CFR 18.38 - Leads through common walls.

Code of Federal Regulations, 2013 CFR

2013-07-01

... APPROVAL OF MINING PRODUCTS ELECTRIC MOTOR-DRIVEN MINE EQUIPMENT AND ACCESSORIES Construction and Design... from one explosion-proof enclosure to another through conduit, tubing, piping, or other solid-wall...

30 CFR 18.38 - Leads through common walls.

Code of Federal Regulations, 2011 CFR

2011-07-01

... APPROVAL OF MINING PRODUCTS ELECTRIC MOTOR-DRIVEN MINE EQUIPMENT AND ACCESSORIES Construction and Design... from one explosion-proof enclosure to another through conduit, tubing, piping, or other solid-wall...

30 CFR 18.38 - Leads through common walls.

Code of Federal Regulations, 2012 CFR

2012-07-01

... APPROVAL OF MINING PRODUCTS ELECTRIC MOTOR-DRIVEN MINE EQUIPMENT AND ACCESSORIES Construction and Design... from one explosion-proof enclosure to another through conduit, tubing, piping, or other solid-wall...

Propagation behavior of the stress wave in a hollow Hopkinson transmission bar

NASA Astrophysics Data System (ADS)

Zou, G.; Shen, X.; Guo, C.; Vecchio, K. S.; Jiang, F.

2018-03-01

In order to investigate the stress wave propagation behavior through a hollow elastic bar that is used in a Hopkinson-bar-loaded fracture testing system, three-point bending fracture experiments were performed in such a system. The effects of sample span and diameter and wall thickness of the hollow elastic bar on the stress wave propagation behavior were studied numerically using the software of ANSYS/LS-DYNA. The experimental results demonstrated that the incident, reflected, and transmitted pulses calculated by the finite element method are coincident with those obtained from the Hopkinson-bar-loaded fracture tests. Compared to the solid transmission bar, the amplitude of the transmitted pulse is relatively larger in the hollow transmission bar under the same loading conditions and decreases with increasing wall thickness. On the other hand, when the inside diameter is fixed, the effect of the wall thickness on the stress wave characteristics is more obvious.

12. INTERIOR OF FRONT BEDROOM SHOWING ELECTRICAL WALL HEATER ON ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

12. INTERIOR OF FRONT BEDROOM SHOWING ELECTRICAL WALL HEATER ON BACK WALL, OPEN FIVE-PANELED DOOR TO LIVING ROOM AT PHOTO LEFT, AND OPEN SOLID DOOR TO BATHROOM AT PHOTO CENTER. VIEW TO WEST. - Bishop Creek Hydroelectric System, Plant 4, Worker Cottage, Bishop Creek, Bishop, Inyo County, CA

A novel mechanism for direct real-time polymerase chain reaction that does not require DNA isolation from prokaryotic cells.

PubMed

Soejima, Takashi; Xiao, Jin-Zhong; Abe, Fumiaki

2016-06-23

Typically, polymerase chain reaction (PCR) is performed after DNA isolation. Real-time PCR (qPCR), also known as direct qPCR in mammalian cells with weak membranes, is a common technique using crude samples subjected to preliminary boiling to elute DNA. However, applying this methodology to prokaryotic cells, which have solid cell walls, in contrast to mammalian cells which immediately burst in water, can result in poor detection. We successfully achieved PCR elongation with the addition of 1.3 cfu of Cronobacter muytjensii to a newly developed direct qPCR master mix without performing any crude DNA extraction (detection limit of 1.6 × 10(0) cfu/ml for the test sample compared with a detection limit of 1.6 × 10(3) cfu/ml primarily for crude (boiling) or classical DNA isolation). We revealed that the chromosomal DNA retained in prokaryotic cells can function as a PCR template, similarly to the mechanism in in situ PCR. Elucidating this reaction mechanism may contribute to the development of an innovative master mix for direct qPCR to detect genes in a single bacterium with solid cell walls and might lead to numerous novel findings in prokaryotic genomics research.

Gravity settling

DOEpatents

Davis, Hyman R.; Long, R. H.; Simone, A. A.

1979-01-01

Solids are separated from a liquid in a gravity settler provided with inclined solid intercepting surfaces to intercept the solid settling path to coalesce the solids and increase the settling rate. The intercepting surfaces are inverted V-shaped plates, each formed from first and second downwardly inclined upwardly curved intersecting conical sections having their apices at the vessel wall.

Improved Boundary Layer Module (BLM) for the Solid Performance Program (SPP)

NASA Astrophysics Data System (ADS)

Coats, D. E.; Cebeci, T.

1982-03-01

The requirements for a replacement to the Bartz boundary layer code, the standard method of computing the performance loss due to viscous effects by the solid performance program, were discussed by the propulsion community along with four nationally recognized boundary layer experts. A consensus was reached regarding the preferred features for the analysis of the replacement code. The major points that were agreed upon are: (1) finite difference methods are preferred over integral methods; (2) a single equation eddy viscosity model was considered to be adequate for the purpose of computing performance loss; (3) a variable grid capability in both coordinate directions would be required; (4) a proven finite difference algorithm which is not stability restricted should be used, that is, an implicit numerical scheme would be required; and (5) the replacement code should be able to compute both turbulent and laminar flows. The program should treat mass addition at the wall as well as being able to calculate a stagnation point starting line.

Hydrodynamics of high solids anaerobic reactor: Characterization of solid segregation and liquid mixing pattern in a pilot plant VALORGA facility under different reactor geometry.

PubMed

Álvarez, C; Colón, J; Lópes, A C; Fernández-Polanco, M; Benbelkacem, H; Buffière, P

2018-06-01

One of the main problems of dry anaerobic digestion plants treating urban solid waste is the loss of useful volume by the sedimentation of solids (inerts) into the bottom of the digester, or by accumulation of floating materials in its upper part. This entails a periodic cost of emptying and cleaning the digesters, a decrease in biogas production and complications in maintenance. Usually the sedimentation is a consequence of the heterogeneity of waste that, in addition to organic matter, drags particles of high density that end up obstructing the digesters. To reduce this bottleneck, URBASER has designed a new configuration of VALORGA reactor. That is, the VALORGA central wall has been removed and an inclined bottom has been added. To test the sedimentability and the overall performance of both configurations (current and new design), hydrodynamic tests have been carried out in a pilot digester (digester of 95 m 3 capacity). To simulate the liquid phase and the solid phase of the reactor, lithium tracers and tags of different densities with RFID (radio frequency identification reader) have been used respectively. The results of the study showed an improvement in the performance of the new reactor design at pilot level. Copyright © 2018 Elsevier Ltd. All rights reserved.

Contact angle of sessile drops in Lennard-Jones systems.

PubMed

Becker, Stefan; Urbassek, Herbert M; Horsch, Martin; Hasse, Hans

2014-11-18

Molecular dynamics simulations are used for studying the contact angle of nanoscale sessile drops on a planar solid wall in a system interacting via the truncated and shifted Lennard-Jones potential. The entire range between total wetting and dewetting is investigated by varying the solid-fluid dispersive interaction energy. The temperature is varied between the triple point and the critical temperature. A correlation is obtained for the contact angle in dependence of the temperature and the dispersive interaction energy. Size effects are studied by varying the number of fluid particles at otherwise constant conditions, using up to 150,000 particles. For particle numbers below 10,000, a decrease of the contact angle is found. This is attributed to a dependence of the solid-liquid surface tension on the droplet size. A convergence to a constant contact angle is observed for larger system sizes. The influence of the wall model is studied by varying the density of the wall. The effective solid-fluid dispersive interaction energy at a contact angle of θ = 90° is found to be independent of temperature and to decrease linearly with the solid density. A correlation is developed that describes the contact angle as a function of the dispersive interaction, the temperature, and the solid density. The density profile of the sessile drop and the surrounding vapor phase is described by a correlation combining a sigmoidal function and an oscillation term.

A method for the modelling of porous and solid wind tunnel walls in computational fluid dynamics codes

NASA Technical Reports Server (NTRS)

Beutner, Thomas John

1993-01-01

Porous wall wind tunnels have been used for several decades and have proven effective in reducing wall interference effects in both low speed and transonic testing. They allow for testing through Mach 1, reduce blockage effects and reduce shock wave reflections in the test section. Their usefulness in developing computational fluid dynamics (CFD) codes has been limited, however, by the difficulties associated with modelling the effect of a porous wall in CFD codes. Previous approaches to modelling porous wall effects have depended either upon a simplified linear boundary condition, which has proven inadequate, or upon detailed measurements of the normal velocity near the wall, which require extensive wind tunnel time. The current work was initiated in an effort to find a simple, accurate method of modelling a porous wall boundary condition in CFD codes. The development of such a method would allow data from porous wall wind tunnels to be used more readily in validating CFD codes. This would be beneficial when transonic validations are desired, or when large models are used to achieve high Reynolds numbers in testing. A computational and experimental study was undertaken to investigate a new method of modelling solid and porous wall boundary conditions in CFD codes. The method utilized experimental measurements at the walls to develop a flow field solution based on the method of singularities. This flow field solution was then imposed as a pressure boundary condition in a CFD simulation of the internal flow field. The effectiveness of this method in describing the effect of porosity changes on the wall was investigated. Also, the effectiveness of this method when only sparse experimental measurements were available has been investigated. The current work demonstrated this approach for low speed flows and compared the results with experimental data obtained from a heavily instrumented variable porosity test section. The approach developed was simple, computationally inexpensive, and did not require extensive or intrusive measurements of the boundary conditions during the wind tunnel test. It may be applied to both solid and porous wall wind tunnel tests.

Numerical simulation of water evaporation inside vertical circular tubes

NASA Astrophysics Data System (ADS)

Ocłoń, Paweł; Nowak, Marzena; Majewski, Karol

2013-10-01

In this paper the results of simplified numerical analysis of water evaporation in vertical circular tubes are presented. The heat transfer in fluid domain (water or wet steam) and solid domain (tube wall) is analyzed. For the fluid domain the temperature field is calculated solving energy equation using the Control Volume Method and for the solid domain using the Finite Element Method. The heat transfer between fluid and solid domains is conjugated using the value of heat transfer coefficient from evaporating liquid to the tube wall. It is determined using the analytical Steiner-Taborek correlation. The pressure changes in fluid are computed using Friedel model.

David Adler Lectureship Award in the Field of Materials Physics: Racetrack Memory - a high-performance, storage class memory using magnetic domain-walls manipulated by current

NASA Astrophysics Data System (ADS)

Parkin, Stuart

2012-02-01

Racetrack Memory is a novel high-performance, non-volatile storage-class memory in which magnetic domains are used to store information in a ``magnetic racetrack'' [1]. The magnetic racetrack promises a solid state memory with storage capacities and cost rivaling that of magnetic disk drives but with much improved performance and reliability: a ``hard disk on a chip''. The magnetic racetrack is comprised of a magnetic nanowire in which a series of magnetic domain walls are shifted to and fro along the wire using nanosecond-long pulses of spin polarized current [2]. We have demonstrated the underlying physics that makes Racetrack Memory possible [3,4] and all the basic functions - creation, and manipulation of a train of domain walls and their detection. The physics underlying the current induced dynamics of domain walls will also be discussed. In particular, we show that the domain walls respond as if they have mass, leading to significant inertial driven motion of the domain walls over long times after the current pulses are switched off [3]. We also demonstrate that in perpendicularly magnetized nanowires there are two independent current driving mechanisms: one derived from bulk spin-dependent scattering that drives the domain walls in the direction of electron flow, and a second interfacial mechanism that can drive the domain walls either along or against the electron flow, depending on subtle changes in the nanowire structure. Finally, we demonstrate thermally induced spin currents are large enough that they can be used to manipulate domain walls. [4pt] [1] S.S.P. Parkin, US Patent 6,834,005 (2004); S.S.P. Parkin et al., Science 320, 190 (2008); S.S.P. Parkin, Scientific American (June 2009). [0pt] [2] M. Hayashi, L. Thomas, R. Moriya, C. Rettner and S.S.P. Parkin, Science 320, 209 (2008). [0pt] [3] L. Thomas, R. Moriya, C. Rettner and S.S.P. Parkin, Science 330, 1810 (2010). [0pt] [4] X. Jiang et al. Nat. Comm. 1:25 (2010) and Nano Lett. 11, 96 (2011).

Wall Turbulence.

ERIC Educational Resources Information Center

Hanratty, Thomas J.

1980-01-01

This paper gives an account of research on the structure of turbulence close to a solid boundary. Included is a method to study the flow close to the wall of a pipe without interferring with it. (Author/JN)

Multi-residue determination of 171 pesticides in cowpea using modified QuEChERS method with multi-walled carbon nanotubes as reversed-dispersive solid-phase extraction materials.

PubMed

Han, Yongtao; Song, Le; Zou, Nan; Chen, Ronghua; Qin, Yuhong; Pan, Canping

2016-09-15

A rapid and sensitive method for the determination of 171 pesticides in cowpea was developed using multi-walled carbon nanotubes (MWCNTs) as reversed-dispersive solid-phase (r-DSPE) extraction materials. The clean-up performance of MWCNTs was proved to be obviously superior to PSA and GCB. This method was validated on cowpea spiked at 0.01 and 0.1mgkg(-1) with five replicates. The mean recoveries for 169 pesticides ranged from 74% to 129% with relative standard deviations (RSDs) (n=5) lower than 16.4%, except diflufenican and quizalofop-ethyl. Good linearity for all pesticides was obtained with the calibration curve coefficients (R(2)) larger than 0.9970. The limit of detection (LODs) and limit of quantification (LOQs) for the 171 pesticides ranged from 0.001 to 0.003mgkg(-1) and from 0.002 to 0.009mgkg(-1), respectively. The method was demonstrated to be reliable and sensitive for the routine monitoring of the 171 pesticides in cowpea samples. Copyright © 2016 Elsevier B.V. All rights reserved.

Dependency of the apparent contact angle on nonisothermal conditions

NASA Astrophysics Data System (ADS)

Krahl, Rolf; Gerstmann, Jens; Behruzi, Philipp; Bänsch, Eberhard; Dreyer, Michael E.

2008-04-01

The dynamic behavior of liquids in partly filled containers is influenced to a large extend by the angle between the gas-liquid phase boundary and the solid container wall at the contact line. This contact angle in turn is influenced by nonisothermal conditions. In the case of a cold liquid meniscus spreading over a hot solid wall, the contact angle apparently becomes significantly larger. In this paper we want to establish a quantitative equation for this enlargement, both from experimental and numerical data. Our findings can be used to build a subgrid model for computations, where the resolution is not sufficient to resolve the boundary layers. This might be the case for large containers which are exposed to low accelerations and where the contact angle boundary condition determines the position of the free surface. These types of computation are performed, for example, to solve propellant management problems in launcher and satellite tanks. In this application, the knowledge of the position of the free surface is very important for the withdrawal of liquid and the calculation of heat and mass transfer.

Integrated computational study of ultra-high heat flux cooling using cryogenic micro-solid nitrogen spray

NASA Astrophysics Data System (ADS)

Ishimoto, Jun; Oh, U.; Tan, Daisuke

2012-10-01

A new type of ultra-high heat flux cooling system using the atomized spray of cryogenic micro-solid nitrogen (SN2) particles produced by a superadiabatic two-fluid nozzle was developed and numerically investigated for application to next generation super computer processor thermal management. The fundamental characteristics of heat transfer and cooling performance of micro-solid nitrogen particulate spray impinging on a heated substrate were numerically investigated and experimentally measured by a new type of integrated computational-experimental technique. The employed Computational Fluid Dynamics (CFD) analysis based on the Euler-Lagrange model is focused on the cryogenic spray behavior of atomized particulate micro-solid nitrogen and also on its ultra-high heat flux cooling characteristics. Based on the numerically predicted performance, a new type of cryogenic spray cooling technique for application to a ultra-high heat power density device was developed. In the present integrated computation, it is clarified that the cryogenic micro-solid spray cooling characteristics are affected by several factors of the heat transfer process of micro-solid spray which impinges on heated surface as well as by atomization behavior of micro-solid particles. When micro-SN2 spraying cooling was used, an ultra-high cooling heat flux level was achieved during operation, a better cooling performance than that with liquid nitrogen (LN2) spray cooling. As micro-SN2 cooling has the advantage of direct latent heat transport which avoids the film boiling state, the ultra-short time scale heat transfer in a thin boundary layer is more possible than in LN2 spray. The present numerical prediction of the micro-SN2 spray cooling heat flux profile can reasonably reproduce the measurement results of cooling wall heat flux profiles. The application of micro-solid spray as a refrigerant for next generation computer processors is anticipated, and its ultra-high heat flux technology is expected to result in an extensive improvement in the effective cooling performance of large scale supercomputer systems.

Modification of polydopamine-coated Fe3O4 nanoparticles with multi-walled carbon nanotubes for magnetic-μ-dispersive solid-phase extraction of antiepileptic drugs in biological matrices.

PubMed

Zhang, Ruiqi; Wang, Siming; Yang, Ye; Deng, Yulan; Li, Di; Su, Ping; Yang, Yi

2018-06-01

In this study, multi-walled carbon nanotubes were coated on the surface of magnetic nanoparticles modified by polydopamine. The synthesized composite was characterized and applied to magnetic-μ-dispersive solid-phase extraction of oxcarbazepine (OXC), phenytoin (PHT), and carbamazepine (CBZ) from human plasma, urine, and cerebrospinal fluid samples prior to analysis by a high-performance liquid chromatography-photodiode array detector. The extraction parameters were investigated and the optimum condition was obtained when the variables were set to the following: sorbent type, Fe 3 O 4 @polyDA-MWCNTs (length < 2 μm); sample pH, 6; amount of sorbent, 15 mg; sorption time, 1.5 min at room temperature; type and volume of the eluent, 2.5 mL methanol; and salt content, none added. Under the optimized conditions, the calibration curves are linear in the concentration range 2-2000 ng/mL, the limits of detection are in the range 0.4-3.1 ng/mL, and the relative standard deviations and relative recoveries of plasma (spiked at 200 ng/mL) and CSF (spiked at 50 ng/mL) are in the ranges 1.4-8.2% and 92.8-96.5%, respectively. The applicability of the method was successfully confirmed by extraction and determination of OXC, PHT, and CBZ in biological matrices. Graphical abstract Magnetic multi-walled carbon nanotube core-shell composites were applied as magnetic-μ-dispersive solid-phase extraction adsorbents for determination of antiepileptic drugs in biological matrices.

High-power piezoelectric acoustic-electric power feedthru for metal walls

NASA Astrophysics Data System (ADS)

Bao, Xiaoqi; Biederman, Will; Sherrit, Stewart; Badescu, Mircea; Bar-Cohen, Yoseph; Jones, Christopher; Aldrich, Jack; Chang, Zensheu

2008-03-01

Piezoelectric acoustic-electric power feed-through devices transfer electric power wirelessly through a solid wall using elastic waves. This approach allows for the elimination of the need for holes through structures for cabling or electrical feed-thrus . The technology supplies power to electric equipment inside sealed containers, vacuum or pressure vessels, etc where holes in the wall are prohibitive or may result in significant performance degradation or requires complex designs. In the our previous work, 100-W of electric power was transferred through a metal wall by a small, piezoelectric device with a simple-structure. To meet requirements of higher power applications, the feasibility to transfer kilowatts level power was investigated. Pre-stressed longitudinal piezoelectric feed-thru devices were analyzed by finite element modeling. An equivalent circuit model was developed to predict the characteristics of power transfer to different electric loads. Based on the analytical results, a prototype device was designed, fabricated and successfully demonstrated to transfer electric power at a level of 1-kW. Methods of minimizing plate wave excitation on the wall were also analyzed. Both model analysis and experimental results are presented in detail in this paper.

Automated synthesis of arabinoxylan-oligosaccharides enables characterization of antibodies that recognize plant cell wall glycans.

PubMed

Schmidt, Deborah; Schuhmacher, Frank; Geissner, Andreas; Seeberger, Peter H; Pfrengle, Fabian

2015-04-07

Monoclonal antibodies that recognize plant cell wall glycans are used for high-resolution imaging, providing important information about the structure and function of cell wall polysaccharides. To characterize the binding epitopes of these powerful molecular probes a library of eleven plant arabinoxylan oligosaccharides was produced by automated solid-phase synthesis. Modular assembly of oligoarabinoxylans from few building blocks was enabled by adding (2-naphthyl)methyl (Nap) to the toolbox of orthogonal protecting groups for solid-phase synthesis. Conjugation-ready oligosaccharides were obtained and the binding specificities of xylan-directed antibodies were determined on microarrays. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Simulation of radial solute segregation in vertical Bridgman growth of pyridine-doped benzene, a surrogate for binary organic nonlinear optical materials

NASA Astrophysics Data System (ADS)

Lee, Hanjie; Pearlstein, Arne J.

2000-09-01

We present steady axisymmetric computations of solute distributions and radial segregation for vertical Bridgman growth of pyridine-doped benzene, a binary aromatic system with anisotropic solid-phase thermal conductivity, that serves as a model of solute transport in crystal growth of organic nonlinear optical materials. The radial variation of solid-phase mass fraction ( Cs) of pyridine, which is rejected at the growing interface, depends strongly on growth conditions. High growth velocities tend to increase Cs near the centerline, the ampoule wall, or both, and low growth velocities give more nearly uniform radial distributions. The maximum ampoule-wall temperature gradient also affects radial segregation, with convex-to-the-liquid interfaces at small temperature gradients being associated with radially monotonic Cs distributions, and ridged interfaces at higher gradients being associated with nonmonotonic distributions having maxima at the centerline and ampoule wall. Nonuniformity is strongly determined by both interface shape and the nature of the flow near the interface. Solute is transported down to the interface by a large toroidal vortex, and swept radially inward to the centerline by a second, flattened toroidal cell. When the interface is depressed at its junction with the ampoule wall, rejected solute accumulates in the overlying liquid, where convection is relatively weak, resulting in local solute enrichment of the solid. Computations at normal and zero gravity show that for two very similar interface shapes, a maximum in the radial solid-phase solute distribution at the ampoule wall is associated with the interface shape, while the maximum on the centerline is associated with sweeping of solute to the centerline by a vortical flow on the interface. We also show that radial solute segregation depends significantly on whether account is taken of the anisotropy of the solid-phase thermal conductivity. Finally, the computations provide guidance as to the minimum ampoule length required to produce an axially uniform solute distribution over at least part of the length of a boule.

Crystallization of soft matter under confinement at interfaces and in wedges

NASA Astrophysics Data System (ADS)

Archer, Andrew J.; Malijevský, Alexandr

2016-06-01

The surface freezing and surface melting transitions that are exhibited by a model two-dimensional soft matter system are studied. The behaviour when confined within a wedge is also considered. The system consists of particles interacting via a soft purely repulsive pair potential. Density functional theory (DFT) is used to calculate density profiles and thermodynamic quantities. The external potential due to the confining walls is modelled via a hard wall with an additional repulsive Yukawa potential. The surface phase behaviour depends on the range and strength of this repulsion: when the repulsion is weak, the wall promotes freezing at the surface of the wall. The thickness of this frozen layer grows logarithmically as the bulk liquid-solid phase coexistence is approached. Our mean-field DFT predicts that this crystalline layer at the wall must be nucleated (i.e. there is a free energy barrier) and its formation is necessarily a first-order transition, referred to as ‘prefreezing’, by analogy with the prewetting transition. However, in contrast to the latter, prefreezing cannot terminate in a critical point, since the phase transition involves a change in symmetry. If the wall-fluid interaction is sufficiently long ranged and the repulsion is strong enough, surface melting can occur instead. Then the interface between the wall and the bulk crystalline solid is wetted by the liquid phase as the chemical potential is decreased towards the value at liquid-solid coexistence. It is observed that the finite thickness fluid film at the wall has a broken translational symmetry due to its proximity to the bulk crystal, and so the nucleation of the wetting film can be either first order or continuous. Our mean-field theory predicts that for certain wall potentials there is a premelting critical point analogous to the surface critical point for the prewetting transition. When the fluid is confined within a linear wedge, this can strongly promote freezing when the opening angle of the wedge is commensurate with the crystal lattice.

Projectile-generating explosive access tool

DOEpatents

Jakaboski, Juan-Carlos [Albuquerque, NM; Hughs, Chance G [Tijeras, NM; Todd, Steven N [Rio Rancho, NM

2011-10-18

An explosive device that can generate a projectile from the opposite side of a wall from the side where the explosive device is detonated. The projectile can be generated without breaching the wall of the structure or container. The device can optionally open an aperture in a solid wall of a structure or a container and form a high-kinetic-energy projectile from the portion of the wall removed to create the aperture.

Catalyst cartridge for carbon dioxide reduction unit

NASA Technical Reports Server (NTRS)

Holmes, R. F. (Inventor)

1973-01-01

A catalyst cartridge, for use in a carbon dioxide reducing apparatus in a life support system for space vehicles, is described. The catalyst cartridge includes an inner perforated metal wall, an outer perforated wall space outwardly from the inner wall, a base plate closing one end of the cartridge, and a cover plate closing the other end of the cartridge. The cover plate has a central aperture through which a supply line with a heater feeds a gaseous reaction mixture comprising hydrogen and carbon dioxide at a temperature from about 1000 to about 1400 F. The outer surfaces of the internal wall and the inner surfaces of the outer wall are lined with a ceramic fiber batting material of sufficient thickness to prevent carbon formed in the reaction from passing through it. The portion of the surfaces of the base and cover plates defined within the inner and outer walls are also lined with ceramic batting. The heated reaction mixture passes outwardly through the inner perforated wall and ceramic batting and over the catalyst. The solid carbon product formes is retained within the enclosure containing the catalyst. The solid carbon product formed is retained within the enclosure containing the catalyst. The water vapor and unreacted carbon dioxide and any intermediate products pass through the perforations of the outer wall.

Synthesis of highly conductive thin-walled Al-doped ZnO single-crystal microtubes by a solid state method

NASA Astrophysics Data System (ADS)

Hu, Shuopeng; Wang, Yue; Wang, Qiang; Xing, Cheng; Yan, Yinzhou; Jiang, Yijian

2018-06-01

ZnO has attracted considerable attention in fundamental studies and practical applications for the past decade due to its outstanding performance in gas sensing, photocatalytic degradation, light harvesting, UV-light emitting/lasing, etc. The large-sized thin-walled ZnO (TW-ZnO) microtube with stable and rich VZn-related acceptors grown by optical vapor supersaturated precipitation (OVSP) is a novel multifunctional optoelectronic material. Unfortunately, the OVSP cannot achieve doping due to the vapor growth process. To obtain doped TW-ZnO microtubes, a solid state method is introduced in this work to achieve thin-walled Al-doping ZnO (TW-ZnO:Al) microtubes with high electrical conductivity. The morphology and microstructures of ZnO:Al microtubes are similar to undoped ones. The Al3+ ions are confirmed to substitute Zn2+ sites and Zn(0/-1) vacancies in the lattice of ZnO by EDS, XRD, Raman and temperature-dependent photoluminescence analyses. The Al dopant acting as a donor level offers massive free electrons to increase the carrier concentrations. The resistivity of the ZnO:Al microtube is reduced down to ∼10-3 Ω·cm, which is one order of magnitude lower than that of the undoped microtube. The present work provides a simple way to achieve doped ZnO tubular components for potential device applications in optoelectronics.

Association Between Pseudotumor Formation and Patient Factors in Metal-on-Metal Total Hip Arthroplasty Population.

PubMed

Kleeman, Lindsay T; Goltz, Daniel; Seyler, Thorsten M; Mammarappallil, Joseph G; Attarian, David E; Wellman, Samuel S; Bolognesi, Michael P

2018-07-01

Pseudotumor formation from metal-on-metal (MoM) hip implants is associated with implant revision. The relationship between pseudotumor type and patient outcomes is unknown. We retrospectively reviewed patients with a MoM total hip arthroplasty and metal artifact reduction sequence magnetic resonance imaging. Pseudotumors were graded using a validated classification system by a fellowship-trained radiologist. Patient demographics, metal ion levels, and implant survival were analyzed. Pseudotumors were present in 49 hips (53%). Thirty-two (65%) pseudotumors were cystic thin walled, 8 (16%) were cystic thick walled, and 9 (18%) were solid masses. Patients with pseudotumors had high offset stems (P = .030) but not higher metal ion levels. Patients with thick-walled cystic or solid masses were more likely to be symptomatic (P = .025) and were at increased risk for revision (P = .004) compared to patients with cystic lesions. Pseudotumor formation is present in 53% of patients with a MoM total hip arthroplasty, of which 40% were asymptomatic. Patients with thick-walled cystic and solid lesions were more likely to be symptomatic and undergo revision. Copyright © 2018 Elsevier Inc. All rights reserved.

Gas storage materials, including hydrogen storage materials

DOEpatents

Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

2013-02-19

A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

Gas storage materials, including hydrogen storage materials

DOEpatents

Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

2014-11-25

A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

Multi-walled carbon nanotubes as solid-phase extraction sorbents for simultaneous determination of type A trichothecenes in maize, wheat and rice by ultra-high performance liquid chromatography-tandem mass spectrometry.

PubMed

Dong, Maofeng; Si, Wenshuai; Jiang, Keqiu; Nie, Dongxia; Wu, Yongjiang; Zhao, Zhihui; De Saeger, Sarah; Han, Zheng

2015-12-04

A solid-phase extraction (SPE) procedure using multi-walled carbon nanotubes (MWCNTs) as sorbents coupled with ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) was developed for simultaneous determination of four type A trichothecenes in maize, wheat and rice for the first time. Several key parameters including the composition of sample loading solutions, washing and elution solvents were thoroughly investigated to achieve optimal SPE recoveries and efficiency. Performance of the MWCNTs materials was significantly affected by pH, and after optimization, n-hexane and 5% methanol aqueous solution as the washing solutions and methanol containing 1% formic acid as the elution solvent presented an excellent purification efficiency for the four targets in the different matrices. The method was validated by determining the linearity (R(2)≥0.992), recovery (73.4-113.7%), precision (1.2-17.1%) and sensitivity (limit of quantification in the range of 0.02-0.10μg/kg), and was further applied for simultaneous determination of type A trichothecenes in 30 samples. Although low contamination levels of type A trichothecenes in wheat, maize and rice were observed revealing mitigated risks to consumers in Shanghai, China, the developed method has proven to be a valuable tool for type A trichothecenes monitoring in complex crop matrices. Copyright © 2015 Elsevier B.V. All rights reserved.

Use of Precast Concrete Walls for Blast Protection of Steel Stud Construction Preprint

DTIC Science & Technology

2007-11-01

Side Elevation Front Elevation Front Elevation Side Elevation a) Sandwich Wall b) Solid Wall I I---6’-10" " 11.. Exterior Face - Form finish 2------C...damage to the interior drywall was visible. The instnunentation consisted of three external reflected pressure gages at the front face of the test

Methods of conveying fluids and methods of sublimating solid particles

DOEpatents

Turner, Terry D; Wilding, Bruce M

2013-10-01

A heat exchanger and associated methods for sublimating solid particles therein, for conveying fluids therethrough, or both. The heat exchanger includes a chamber and a porous member having a porous wall having pores in communication with the chamber and with an interior of the porous member. A first fluid is conveyed into the porous member while a second fluid is conveyed into the porous member through the porous wall. The second fluid may form a positive flow boundary layer along the porous wall to reduce or eliminate substantial contact between the first fluid and the interior of the porous wall. The combined first and second fluids are conveyed out of the porous member. Additionally, the first fluid and the second fluid may each be conveyed into the porous member at different temperatures and may exit the porous member at substantially the same temperature.

Active hopper for promoting flow of bulk granular or powdered solids

DOEpatents

Saunders, Timothy; Brady, John D.

2013-04-02

An apparatus that promotes the flow of materials has a body having an inner shape for holding the materials, a wall having a shape that approximates a portion of the inner shape of the body, and a vibrator attached to the wall. The wall may be disposed vertically within the body close to the body's inner shape. The vibrator transfers vibrations to the wall to agitate the material and encourage material flow.

Microfluidic device, and related methods

NASA Technical Reports Server (NTRS)

Wong, Eric W. (Inventor)

2010-01-01

A method of making a microfluidic device is provided. The method features patterning a permeable wall on a substrate, and surrounding the permeable wall with a solid, non-permeable boundary structure to establish a microfluidic channel having a cross-sectional dimension less than 5,000 microns and a cross-sectional area at least partially filled with the permeable wall so that fluid flowing through the microfluidic channel at least partially passes through the permeable wall.

Field-portable supercritical CO{sub 2} extractor

DOEpatents

Wright, B.W.; Zemanian, T.S.; Robins, W.H.; Woodcock, L.J.

1997-06-10

The present invention is an apparatus for extracting organic compounds from solid materials. A generator vessel has a removable closure for receiving a solid or liquid solvent which is heated with a resistive heating element to a gaseous or supercritical phase. The removable closure is unencumbered because the side wall is penetrated with an outlet for the gaseous or supercritical solvent. The generator vessel further has a pressure transducer that provides an electronic signal related to pressure of the gaseous or supercritical solvent. The apparatus of the present invention further includes at least one extraction cell having a top and a bottom and a wall extending there between, wherein the bottom is sealably penetrated by an inlet for gaseous or supercritical solvent received through a manifold connected to the outlet, the top having an easy-open removable closure cap, and the wall having an outlet port. Finally, a permeable sample cartridge is included for holding the solid materials and to provide radial-flow of the extraction fluid, which is placed within the extraction cell. 10 figs.

Field-portable supercritical CO.sub.2 extractor

DOEpatents

Wright, Bob W.; Zemanian, Thomas S.; Robins, William H.; Woodcock, Leslie J.

1997-01-01

The present invention is an apparatus for extracting organic compounds from solid materials. A generator vessel has a removable closure for receiving a solid or liquid solvent which is heated with a resistive heating element to a gaseous or supercritical phase. The removable closure is unencumbered because the side wall is penetrated with an outlet for the gaseous or supercritical solvent. The generator vessel further has a pressure transducer that provides an electronic signal related to pressure of the gaseous or supercritical solvent. The apparatus of the present invention further includes at least one extraction cell having a top and a bottom and a wall extending therebetween, wherein the bottom is sealably penetrated by an inlet for gaseous or supercritical solvent received through a manifold connected to the outlet, the top having an easy-open removable closure cap, and the wall having an outlet port. Finally, a permeable sample cartridge is included for holding the solid materials and to provide radial-flow of the extraction fluid, which is placed within the extraction cell.

Performance of JT-60SA divertor Thomson scattering diagnostics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kajita, Shin, E-mail: kajita.shin@nagoya-u.jp; Hatae, Takaki; Tojo, Hiroshi

2015-08-15

For the satellite tokamak JT-60 Super Advanced (JT-60SA), a divertor Thomson scattering measurement system is planning to be installed. In this study, we improved the design of the collection optics based on the previous one, in which it was found that the solid angle of the collection optics became very small, mainly because of poor accessibility to the measurement region. By improvement, the solid angle was increased by up to approximately five times. To accurately assess the measurement performance, background noise was assessed using the plasma parameters in two typical discharges in JT-60SA calculated from the SONIC code. Moreover, themore » influence of the reflection of bremsstrahlung radiation by the wall is simulated by using a ray tracing simulation. The errors in the temperature and the density are assessed based on the simulation results for three typical field of views.« less

Performance of JT-60SA divertor Thomson scattering diagnostics.

PubMed

Kajita, Shin; Hatae, Takaki; Tojo, Hiroshi; Enokuchi, Akito; Hamano, Takashi; Shimizu, Katsuhiro; Kawashima, Hisato

2015-08-01

For the satellite tokamak JT-60 Super Advanced (JT-60SA), a divertor Thomson scattering measurement system is planning to be installed. In this study, we improved the design of the collection optics based on the previous one, in which it was found that the solid angle of the collection optics became very small, mainly because of poor accessibility to the measurement region. By improvement, the solid angle was increased by up to approximately five times. To accurately assess the measurement performance, background noise was assessed using the plasma parameters in two typical discharges in JT-60SA calculated from the SONIC code. Moreover, the influence of the reflection of bremsstrahlung radiation by the wall is simulated by using a ray tracing simulation. The errors in the temperature and the density are assessed based on the simulation results for three typical field of views.

Vascular mechanics of the coronary artery

NASA Technical Reports Server (NTRS)

Veress, A. I.; Vince, D. G.; Anderson, P. M.; Cornhill, J. F.; Herderick, E. E.; Klingensmith, J. D.; Kuban, B. D.; Greenberg, N. L.; Thomas, J. D.

2000-01-01

This paper describes our research into the vascular mechanics of the coronary artery and plaque. The three sections describe the determination of arterial mechanical properties using intravascular ultrasound (IVUS), a constitutive relation for the arterial wall, and finite element method (FEM) models of the arterial wall and atheroma. METHODS: Inflation testing of porcine left anterior descending coronary arteries was conducted. The changes in the vessel geometry were monitored using IVUS, and intracoronary pressure was recorded using a pressure transducer. The creep and quasistatic stress/strain responses were determined. A Standard Linear Solid (SLS) was modified to reproduce the non-linear elastic behavior of the arterial wall. This Standard Non-linear Solid (SNS) was implemented into an axisymetric thick-walled cylinder numerical model. Finite element analysis models were created for five age groups and four levels of stenosis using the Pathobiological Determinants of Atherosclerosis Youth (PDAY) database. RESULTS: The arteries exhibited non-linear elastic behavior. The total tissue creep strain was epsilon creep = 0.082 +/- 0.018 mm/mm. The numerical model could reproduce both the non-linearity of the porcine data and time dependent behavior of the arterial wall found in the literature with a correlation coefficient of 0.985. Increasing age had a strong positive correlation with the shoulder stress level, (r = 0.95). The 30% stenosis had the highest shoulder stress due to the combination of a fully formed lipid pool and a thin cap. CONCLUSIONS: Studying the solid mechanics of the arterial wall and the atheroma provide important insights into the mechanisms involved in plaque rupture.

Dosimetric impact in the dose-volume histograms of rectal and vesical wall contouring in prostate cancer IMRT treatments.

PubMed

Gómez, Laura; Andrés, Carlos; Ruiz, Antonio

2017-01-01

The main purpose of this study was to evaluate the differences in dose-volume histograms of IMRT treatments for prostate cancer based on the delineation of the main organs at risk (rectum and bladder) as solid organs or by contouring their wall. Rectum and bladder have typically been delineated as solid organs, including the waste material, which, in practice, can lead to an erroneous assessment of the risk of adverse effects. A retrospective study was made on 25 patients treated with IMRT radiotherapy for prostate adenocarcinoma. 76.32 Gy in 36 fractions was prescribed to the prostate and seminal vesicles. In addition to the delineation of the rectum and bladder as solid organs (including their content), the rectal and bladder wall were also delineated and the resulting dose-volume histograms were analyzed for the two groups of structures. Data analysis shows statistically significant differences in the main parameters used to assess the risk of toxicity of a prostate radiotherapy treatment. Higher doses were received on the rectal and bladder walls compared to doses received on the corresponding solid organs. The observed differences in terms of received doses to the rectum and bladder based on the method of contouring could gain greater importance in inverse planning treatments, where the treatment planning system optimizes the dose in these volumes. So, one should take into account the method of delineating of these structures to make a clinical decision regarding dose limitation and risk assessment of chronic toxicity.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

Three solid-breeder water-cooled blanket concepts have been developed for ITER based on a multilayer configuration. The primary difference among the concepts is in the fabricated form of breeder and multiplier. All the concepts have beryllium for neutron multiplication and solid-breeder temperature control. The blanket design does not use helium gaps or insulator material to control the solid breeder temperature. Lithium oxide (Li{sub 2}O) and lithium zirconate (Li{sub 2}ZrO{sub 3}) are the primary and the backup breeder materials, respectively. The lithium-6 enrichment is 95%. The use of high lithium-6 enrichment reduces the solid breeder volume required in the blanket and consequentlymore » the total tritium inventory in the solid breeder material. Also, it increases the blanket capability to accommodate power variation. The multilayer blanket configuration can accommodate up to a factor of two change in the neutron wall loading without violating the different design guidelines. The blanket material forms are sintered products and packed bed of small pebbles. The first concept has a sintered product material (blocks) for both the beryllium multiplier and the solid breeder. The second concept, the common ITER blanket, uses a packed bed breeder and beryllium blocks. The last concept is similar to the first except for the first and the last beryllium zones. Two small layers of beryllium pebbles are located behind the first wall and the back of the last beryllium zone to reduce the total inventory of the beryllium material and to improve the blanket performance. The design philosophy adopted for the blanket is to produce the necessary tritium required for the ITER operation and to operate at power reactor conditions as much as possible. Also, the reliability and the safety aspects of the blanket are enhanced by using low-pressure water coolant and the separation of the tritium purge flow from the coolant system by several barriers.« less

Determination of pyrazole and pyrrole pesticides in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with high-performance liquid chromatography.

PubMed

Ma, Jiping; Lu, Xi; Xia, Yan; Yan, Fengli

2015-02-01

A solid-phase extraction (SPE) method using multi-walled carbon nanotubes as adsorbent coupled with high-performance liquid chromatography was developed for the determination of four pyrazole and pyrrole pesticides (fenpyroximate, chlorfenapyr, fipronil and flusilazole) in environmental water samples. Several parameters, such as extraction adsorbent, elution solvent and volume and sample loading flow rate were optimized to obtain high SPE recoveries and extraction efficiency. The calibration curves for the pesticides extracted were linear in the range of 0.05-10 μg L(-1) for chlorfenapyr and fenpyroximate and 0.05-20 μg L(-1) for fipronil and flusilazole, with the correlation coefficients (r(2)) between 0.9966 and 0.9990. The method gave good precisions (relative standard deviation %) from 2.9 to 10.1% for real spiked samples from reservoir water and seawater; method recoveries ranged 92.2-105.9 and 98.5-103.9% for real spiked samples from reservoir water and seawater, respectively. Limits of detection (S/N = 3) for the method were determined to be 8-19 ng L(-1). The optimized method was successfully applied to the determination of four pesticides of pyrazoles and pyrroles in real environmental water samples. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Solid-state NMR investigations of cellulose structure and interactions with matrix polysaccharides in plant primary cell walls.

PubMed

Wang, Tuo; Hong, Mei

2016-01-01

Until recently, the 3D architecture of plant cell walls was poorly understood due to the lack of high-resolution techniques for characterizing the molecular structure, dynamics, and intermolecular interactions of the wall polysaccharides in these insoluble biomolecular mixtures. We introduced multidimensional solid-state NMR (SSNMR) spectroscopy, coupled with (13)C labelling of whole plants, to determine the spatial arrangements of macromolecules in near-native plant cell walls. Here we review key evidence from 2D and 3D correlation NMR spectra that show relatively few cellulose-hemicellulose cross peaks but many cellulose-pectin cross peaks, indicating that cellulose microfibrils are not extensively coated by hemicellulose and all three major polysaccharides exist in a single network rather than two separate networks as previously proposed. The number of glucan chains in the primary-wall cellulose microfibrils has been under active debate recently. We show detailed analysis of quantitative (13)C SSNMR spectra of cellulose in various wild-type (WT) and mutant Arabidopsis and Brachypodium primary cell walls, which consistently indicate that primary-wall cellulose microfibrils contain at least 24 glucan chains. © The Author 2015. Published by Oxford University Press on behalf of the Society for Experimental Biology. All rights reserved. For permissions, please email: journals.permissions@oup.com.

Method of fabricating a monolithic core for a solid oxide fuela cell

DOEpatents

Zwick, S.A.; Ackerman, J.P.

1983-10-12

A method is disclosed for forming a core for use in a solid oxide fuel cell that electrochemically combines fuel and oxidant for generating galvanic output. The core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support consisting instead only of the active anode, cathode, electrolyte and interconnect materials. Each electrolyte wall consists of cathode and anode materials sandwiching electrolyte material therebetween, and each interconnect wall consists of the cathode and anode materials sandwiching interconnect material therebetween. The electrolyte and interconnect walls define a plurality of substantially parallel core passageways alternately having respectively the inside faces thereof with only the anode material or with only the cathode material exposed. In the wall structure, the electrolyte and interconnect materials are only 0.002 to 0.01 cm thick; and the cathode and anode materials are only 0.002 to 0.05 cm thick. The method consists of building up the electrolyte and interconnect walls by depositing each material on individually and endwise of the wall itself, where each material deposit is sequentially applied for one cycle; and where the depositing cycle is repeated many times until the material buildup is sufficient to formulate the core. The core is heat cured to become dimensionally and structurally stable.

Method of fabricating a monolithic core for a solid oxide fuel cell

DOEpatents

Zwick, Stanley A.; Ackerman, John P.

1985-01-01

A method is disclosed for forming a core for use in a solid oxide fuel cell that electrochemically combines fuel and oxidant for generating galvanic output. The core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support consisting instead only of the active anode, cathode, electrolyte and interconnect materials. Each electrolyte wall consists of cathode and anode materials sandwiching electrolyte material therebetween, and each interconnect wall consists of the cathode and anode materials sandwiching interconnect material therebetween. The electrolyte and interconnect walls define a plurality of substantially parallel core passageways alternately having respectively the inside faces thereof with only the anode material or with only the cathode material exposed. In the wall structure, the electrolyte and interconnect materials are only 0.002-0.01 cm thick; and the cathode and anode materials are only 0.002-0.05 cm thick. The method consists of building up the electrolyte and interconnect walls by depositing each material on individually and endwise of the wall itself, where each material deposit is sequentially applied for one cycle; and where the depositing cycle is repeated many times until the material buildup is sufficient to formulate the core. The core is heat cured to become dimensionally and structurally stable.

Projectile-generating explosive access tool

DOEpatents

Jakaboski, Juan-Carlos; Hughs, Chance G; Todd, Steven N

2013-06-11

A method for generating a projectile using an explosive device that can generate a projectile from the opposite side of a wall from the side where the explosive device is detonated. The projectile can be generated without breaching the wall of the structure or container. The device can optionally open an aperture in a solid wall of a structure or a container and form a high-kinetic-energy projectile from the portion of the wall removed to create the aperture.

Indirect measurement of the solid/liquid interface using the minimization technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Choi, H.; Chun, M.

1985-11-01

The phenomenon of solidification of a flowing fluid in a vertical tube is closely related to the relocation dynamics of molten nuclear fuels in hypothetical core-disruptive accidents of a liquid-metal fast breeder reactor. The knowledge of the transient shape and the position of the liquid/solid interface is of practical importance in analysis of phase change processes. Sparrow and Broadbent directly measured the solid liquid interface via experiments, whereas Viskanta observed the solid/liquid interface motion via a photographic method. In this paper, a new method to predict the transient position of the solid/liquid interface is developed. This method is based onmore » the minimization technique. To use this method one needs the temperature of the wall on which the phase change is to take place. The new technique is useful, in particular, for the case of inward solidification of a flowing fluid in a tube where direct measurement of the solid/liquid interface is not possible, whereas the tube wall temperature measurement is relatively easy.« less

Assessment of Various Flow Solvers Used to Predict the Thermal Environment inside Space Shuttle Solid Rocket Motor Joints

NASA Technical Reports Server (NTRS)

Wang, Qun-Zhen; Cash, Steve (Technical Monitor)

2002-01-01

It is very important to accurately predict the gas pressure, gas and solid temperature, as well as the amount of O-ring erosion inside the space shuttle Reusable Solid Rocket Motor (RSRM) joints in the event of a leak path. The scenarios considered are typically hot combustion gas rapid pressurization events of small volumes through narrow and restricted flow paths. The ideal method for this prediction is a transient three-dimensional computational fluid dynamics (CFD) simulation with a computational domain including both combustion gas and surrounding solid regions. However, this has not yet been demonstrated to be economical for this application due to the enormous amount of CPU time and memory resulting from the relatively long fill time as well as the large pressure and temperature rising rate. Consequently, all CFD applications in RSRM joints so far are steady-state simulations with solid regions being excluded from the computational domain by assuming either a constant wall temperature or no heat transfer between the hot combustion gas and cool solid walls.

Optimized suspension culture: the rotating-wall vessel

NASA Technical Reports Server (NTRS)

Hammond, T. G.; Hammond, J. M.

2001-01-01

Suspension culture remains a popular modality, which manipulates mechanical culture conditions to maintain the specialized features of cultured cells. The rotating-wall vessel is a suspension culture vessel optimized to produce laminar flow and minimize the mechanical stresses on cell aggregates in culture. This review summarizes the engineering principles, which allow optimal suspension culture conditions to be established, and the boundary conditions, which limit this process. We suggest that to minimize mechanical damage and optimize differentiation of cultured cells, suspension culture should be performed in a solid-body rotation Couette-flow, zero-headspace culture vessel such as the rotating-wall vessel. This provides fluid dynamic operating principles characterized by 1) solid body rotation about a horizontal axis, characterized by colocalization of cells and aggregates of different sedimentation rates, optimally reduced fluid shear and turbulence, and three-dimensional spatial freedom; and 2) oxygenation by diffusion. Optimization of suspension culture is achieved by applying three tradeoffs. First, terminal velocity should be minimized by choosing microcarrier beads and culture media as close in density as possible. Next, rotation in the rotating-wall vessel induces both Coriolis and centrifugal forces, directly dependent on terminal velocity and minimized as terminal velocity is minimized. Last, mass transport of nutrients to a cell in suspension culture depends on both terminal velocity and diffusion of nutrients. In the transduction of mechanical culture conditions into cellular effects, several lines of evidence support a role for multiple molecular mechanisms. These include effects of shear stress, changes in cell cycle and cell death pathways, and upstream regulation of secondary messengers such as protein kinase C. The discipline of suspension culture needs a systematic analysis of the relationship between mechanical culture conditions and biological effects, emphasizing cellular processes important for the industrial production of biological pharmaceuticals and devices.

Active ultrasonic cross-correlation flowmeters for mixed-phase pipe flows

NASA Astrophysics Data System (ADS)

Sheen, S. H.; Raptis, A. C.

Two ultrasonic flowmeters which employ the active cross-correlation technique and use a simple clamp-on transducer arrangement are discussed. The flowmeter for solid/liquid flows was tested over a wide range of coal concentration in water and oil. The measured velocity based on the peak position of the cross-correlation function is consistently higher by about 15% than the average velocity measured by flow diversion. The origin of the difference results mainly from the flow velocity profiles and the transit-time probability distribution. The flowmeter that can measure particle velocity in a solid/gas flow requires acoustic decoupling arrangement between two sensing stations. The measured velocity is mainly associated with the particles near the wall. Performance of both flowmeters is presented.

Investigation of column flotation process on sulphide ore using 2-electrode capacitance sensor: The effect of air flow rate and solid percentage

NASA Astrophysics Data System (ADS)

Haryono, Didied; Harjanto, Sri; Wijaya, Rifky; Oediyani, Soesaptri; Nugraha, Harisma; Huda, Mahfudz Al; Taruno, Warsito Purwo

2018-04-01

Investigation of column flotation process on sulphide ore using 2-electrode capacitance sensor is presented in this paper. The effect of air flow rate and solid percentage on column flotation process has been experimentally investigated. The purpose of this paper is to understand the capacitance signal characteristic affected by the air flow rate and the solid percentage which can be used to determine the metallurgical performance. Experiments were performed using a laboratory column flotation cell which has a diameter of 5 cm and the total height of 140 cm. The sintered ceramic sparger and wash water were installed at the bottom and above of the column. Two-electrode concave type capacitance sensor was also installed at a distance of 50 cm from the sparger. The sensor was attached to the outer wall of the column, connected to data acquisition system, manufactured by CTECH Labs Edwar Technology and personal computer for further data processing. Feed consisting ZnS and SiO2 with the ratio of 3:2 was mixed with some reagents to make 1 litre of slurry. The slurry was fed into the aerated column at 100 cm above the sparger with a constant rate and the capacitance signals were captured during the process. In this paper, 7.5 and 10% of solid and 2-4 L/min of air flow rate with 0.5 L/min intervals were used as independent variables. The results show that the capacitance signal characteristics between the 7.5 and 10% of solid are different at any given air flow rate in which the 10% solid produced signals higher than those of 7.5%. Metallurgical performance and capacitance signal exhibit a good correlation.

Knee arthrodesis with the Vari-Wall nail for treatment of infected total knee arthroplasty.

PubMed

Garcia-Lopez, Ignacio; Aguayo, Miguel Anguel; Cuevas, Antonio; Navarro, Pablo; Prieto, Cristobal; Carpintero, Pedro

2008-12-01

We reviewed 20 patients who had undergone one-stage (7 cases) or two-stage (13 cases) knee arthrodesis using the Vari-Wall intramedullary nail, as a salvage operation following infection of a total knee arthroplasty. The procedure was followed by systemic antibiotic administration and early rehabilitation. Intraoperative microbiological cultures were taken. The average period of follow-up was 20 months. Solid union was achieved in 80%; mean time to fusion was 9 months. There was no recurrence of infection. The average limb length discrepancy was 2.45 cm. A walking aid was needed by 95% of the patients. The complication rate was 30% including 4 pseudarthroses, one intraoperative fracture and one peroneal nerve palsy. The Vari-Wall intramedullary nail is a good option when an arthrodesis is indicated for salvage of an infected total knee arthroplasty. It can be performed in one or two stages depending on several factors such as microbiologic culture results. It achieved good pain relief and acceptable functional results in this study.

Intrathoracic tumor of the chest wall: A case of Castleman's disease mimicking myositis of the lower extremities.

PubMed

Tampakis, Athanasios; Tampaki, Ekaterini Christina; Daikeler, Thomas; Lardinois, Didier

2017-11-01

Castleman's disease refers to a group of uncommon lymphoproliferative disorders which exhibit common lymph-node histological features. A 72-year-old male patient presented with signs of lower limb myositis. Detailed work-up focused initially on evaluating hematological malignancies, the presence of a solid tumor, autoimmune diseases and degenerative disorders of the peripheral nerves. Finally, a PET-CT scan was performed to exclude paraneoplastic manifestations of a primary tumor, revealing  however a tumor of the thoracic wall. The definite histological diagnosis confirmed the presence of unicentric Castleman's disease of the chest wall. The manifestations of the present case suggest that a systemic inflammation might occur in the unicentric form of the disease possibly due to cytokine hypersecretion. The unicentric manifestation of the disease should be well distinguished from the multicentric appearance. Unicentric disease is a surgical condition and warrants a follow-up based on the systemic inflammation that might occur.

Analysis of advanced solid rocket motor ignition phenomena

NASA Technical Reports Server (NTRS)

Foster, Winfred A., Jr.; Jenkins, Rhonald M.

1995-01-01

This report presents the results obtained from an experimental analysis of the flow field in the slots of the star grain section in the head-end of the advanced solid rocket motor during the ignition transient. This work represents an extension of the previous tests and analysis to include the effects of using a center port in conjunction with multiple canted igniter ports. The flow field measurements include oil smear data on the star slot walls, pressure and heat transfer coefficient measurements on the star slot walls and velocity measurements in the star slot.

Gradients in Wall Mechanics and Polysaccharides along Growing Inflorescence Stems.

PubMed

Phyo, Pyae; Wang, Tuo; Kiemle, Sarah N; O'Neill, Hugh; Pingali, Sai Venkatesh; Hong, Mei; Cosgrove, Daniel J

2017-12-01

At early stages of Arabidopsis ( Arabidopsis thaliana ) flowering, the inflorescence stem undergoes rapid growth, with elongation occurring predominantly in the apical ∼4 cm of the stem. We measured the spatial gradients for elongation rate, osmotic pressure, cell wall thickness, and wall mechanical compliances and coupled these macroscopic measurements with molecular-level characterization of the polysaccharide composition, mobility, hydration, and intermolecular interactions of the inflorescence cell wall using solid-state nuclear magnetic resonance spectroscopy and small-angle neutron scattering. Force-extension curves revealed a gradient, from high to low, in the plastic and elastic compliances of cell walls along the elongation zone, but plots of growth rate versus wall compliances were strikingly nonlinear. Neutron-scattering curves showed only subtle changes in wall structure, including a slight increase in cellulose microfibril alignment along the growing stem. In contrast, solid-state nuclear magnetic resonance spectra showed substantial decreases in pectin amount, esterification, branching, hydration, and mobility in an apical-to-basal pattern, while the cellulose content increased modestly. These results suggest that pectin structural changes are connected with increases in pectin-cellulose interaction and reductions in wall compliances along the apical-to-basal gradient in growth rate. These pectin structural changes may lessen the ability of the cell wall to undergo stress relaxation and irreversible expansion (e.g. induced by expansins), thus contributing to the growth kinematics of the growing stem. © 2017 American Society of Plant Biologists. All Rights Reserved.

Flow Regime Study in a High Density Circulating Fluidized Bed Riser with an Abrupt Exit

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mei, J.S.; Shadle, L.J.; Yue, P.C.

2007-01-01

Flow regime study was conducted in a 0.3 m diameter, 15.5 m height circulating fluidized bed (CFB) riser with an abrupt exit at the National Energy Technology Laboratory of the U.S. Department of Energy. Local particle velocities were measured at various radial positions and riser heights using an optical fiber probe. On-line measurement of solid circulating rate was continuously recorded by the Spiral. Glass beads of mean diameter 61 μm and particle density of 2,500 kg/m3 were used as bed material. The CFB riser was operated at various superficial gas velocities ranging from 3 to 7.6 m/s and solid massmore » flux from 20 to 550 kg/m2-s. At a constant riser gas velocity, transition from fast fluidization to dense suspension upflow (DSU) regime started at the bottom of the riser with increasing solid flux. Except at comparatively low riser gas velocity and solid flux, the apparent solid holdup at the top exit region was higher than the middle section of the riser. The solid fraction at this top region could be much higher than 7% under high riser gas velocity and solid mass flux. The local particle velocity showed downward flow near the wall at the top of the riser due to its abrupt exit. This abrupt geometry reflected the solids and, therefore, caused solid particles traveling downward along the wall. However, at location below, but near, the top of the riser the local particle velocities were observed flowing upward at the wall. Therefore, DSU was identified in the upper region of the riser with an abrupt exit while the fully developed region, lower in the riser, was still exhibiting core-annular flow structure. Our data were compared with the flow regime boundaries proposed by Kim et al. [1] for distinguishing the dilute pneumatic transport, fast fluidization, and DSU.« less

A wall interference assessment/correction system

NASA Technical Reports Server (NTRS)

Lo, Ching F.; Ulbrich, N.; Sickles, W. L.; Qian, Cathy X.

1992-01-01

A Wall Signature method, the Hackett method, has been selected to be adapted for the 12-ft Wind Tunnel wall interference assessment/correction (WIAC) system in the present phase. This method uses limited measurements of the static pressure at the wall, in conjunction with the solid wall boundary condition, to determine the strength and distribution of singularities representing the test article. The singularities are used in turn for estimating wall interferences at the model location. The Wall Signature method will be formulated for application to the unique geometry of the 12-ft Tunnel. The development and implementation of a working prototype will be completed, delivered and documented with a software manual. The WIAC code will be validated by conducting numerically simulated experiments rather than actual wind tunnel experiments. The simulations will be used to generate both free-air and confined wind-tunnel flow fields for each of the test articles over a range of test configurations. Specifically, the pressure signature at the test section wall will be computed for the tunnel case to provide the simulated 'measured' data. These data will serve as the input for the WIAC method-Wall Signature method. The performance of the WIAC method then may be evaluated by comparing the corrected parameters with those for the free-air simulation. Each set of wind tunnel/test article numerical simulations provides data to validate the WIAC method. A numerical wind tunnel test simulation is initiated to validate the WIAC methods developed in the project. In the present reported period, the blockage correction has been developed and implemented for a rectangular tunnel as well as the 12-ft Pressure Tunnel. An improved wall interference assessment and correction method for three-dimensional wind tunnel testing is presented in the appendix.

Propulsion by passive filaments and active flagella near boundaries.

PubMed

Evans, Arthur A; Lauga, Eric

2010-10-01

Confinement and wall effects are known to affect the kinematics and propulsive characteristics of swimming microorganisms. When a solid body is dragged through a viscous fluid at constant velocity, the presence of a wall increases fluid drag, and thus the net force required to maintain speed has to increase. In contrast, recent optical trapping experiments have revealed that the propulsive force generated by human spermatozoa is decreased by the presence of boundaries. Here, we use a series of simple models to analytically elucidate the propulsive effects of a solid boundary on passively actuated filaments and model flagella. For passive flexible filaments actuated periodically at one end, the presence of the wall is shown to increase the propulsive forces generated by the filaments in the case of displacement-driven actuation, while it decreases the force in the case of force-driven actuation. In the case of active filaments as models for eukaryotic flagella, we demonstrate that the manner in which a solid wall affects propulsion cannot be known a priori, but is instead a nontrivial function of the flagellum frequency, wavelength, its material characteristics, the manner in which the molecular motors self-organize to produce oscillations (prescribed activity model or self-organized axonemal beating model), and the boundary conditions applied experimentally to the tethered flagellum. In particular, we show that in some cases, the increase in fluid friction induced by the wall can lead to a change in the waveform expressed by the flagella, which results in a decrease in their propulsive force.

Method of altering the effective bulk density of solid material and the resulting product

DOEpatents

Kool, Lawrence B.; Nolen, Robert L.; Solomon, David E.

1983-01-01

A method of adjustably tailoring the effective bulk density of a solid material in which a mixture comprising the solid material, a film-forming polymer and a volatile solvent are sprayed into a drying chamber such that the solvent evaporates and the polymer dries into hollow shells having the solid material captured within the shell walls. Shell density may be varied as a function of solid/polymer concentration, droplet size and drying temperature.

Effects of freezing and thawing on texture, microstructure and cell wall composition changes in papaya tissues.

PubMed

Phothiset, Suphatta; Charoenrein, Sanguansri

2014-01-30

During storage, frozen fruit may be thawed and refrozen many times before consumption, which may be extremely damaging to the texture of the frozen fruit and reverse the advantage of fast freezing. The effects of freezing and thawing on texture, microstructure and cell wall composition changes in papaya tissues were investigated. The frozen-thawed papayas had an increase in drip loss and a decrease in firmness with increasing number of freeze-thaw cycles. Light microscopy showed irregular shapes and cell damage in parenchyma cells of frozen-thawed papayas, whereas transmission electron microscopy showed loss of cell wall materials in middle lamella. Moreover, destruction of cell wall was observed after being subjected to five freeze-thaw cycles. These changes related with a significant decrease in alcohol-insoluble solids, Na₂CO₃- and 24% KOH-soluble fractions and an increase in the water-, EDTA- and 4% KOH-soluble fractions. This was due to a decrease in the molecular mass of pectic and hemicellulosic polymers in frozen-thawed papayas using high-performance size-exclusion chromatography. The freezing and thawing processes caused fine structural damage and cell wall composition changes which contributed to a loss of drip volume and firmness of papaya tissues. © 2013 Society of Chemical Industry.

Dynamic analysis of a circulating fluidized bed riser

DOE Office of Scientific and Technical Information (OSTI.GOV)

Panday, Rupen; Shadle, Lawrence J.; Guenther, Chris

2012-01-01

A linear state model is proposed to analyze dynamic behavior of a circulating fluidized bed riser. Different operating regimes were attained with high density polyethylene beads at low and high system inventories. The riser was operated between the classical choking velocity and the upper transport velocity demarcating fast fluidized and transport regimes. At a given riser superficial gas velocity, the aerations fed at the standpipe were modulated resulting in a sinusoidal solids circulation rate that goes into the riser via L-valve. The state model was derived based on the mass balance equation in the riser. It treats the average solidsmore » fraction across the entire riser as a state variable. The total riser pressure drop was modeled using Newton’s second law of motion. The momentum balance equation involves contribution from the weight of solids and the wall friction caused by the solids to the riser pressure drop. The weight of solids utilizes the state variable and hence, the riser inventory could be easily calculated. The modeling problem boils down to estimating two parameters including solids friction coefficient and time constant of the riser. It has been shown that the wall friction force acts in the upward direction in fast fluidized regime which indicates that the solids were moving downwards on the average with respect to the riser wall. In transport regimes, the friction acts in the opposite direction. This behavior was quantified based on a sign of Fanning friction factor in the momentum balance equation. The time constant of the riser appears to be much higher in fast fluidized regime than in transport conditions.« less

Intermittent nature of acceleration in near wall turbulence.

PubMed

Lee, Changhoon; Yeo, Kyongmin; Choi, Jung-Il

2004-04-09

Using direct numerical simulation of a fully developed turbulent channel flow, we investigate the behavior of acceleration near a solid wall. We find that acceleration near the wall is highly intermittent and the intermittency is in large part associated with the near wall organized coherent turbulence structures. We also find that acceleration of large magnitude is mostly directed towards the rotation axis of the coherent vortical structures, indicating that the source of the intermittent acceleration is the rotational motion associated with the vortices that causes centripetal acceleration.

Shrinkage void formation and its effect on freeze and thaw processes of lithium and lithium-fluoride for space applications

NASA Astrophysics Data System (ADS)

Yang, Jae-Young; El-Genk, M. S.

1991-07-01

The effects of shrinkage void forming during freezing of lithium and lithium-fluoride on subsequent thaw processes are investigated using a numerical scheme that is based on a single (solid/liquid) cell approach. Results show that a void forming at the wall appreciably reduces the solid-liquid interface velocity, during both freeze and thaw, and causes a substantial rise in the wall temperature during thaw. However, in the case of Li, the maximum wall temperature was much lower than the melting temperature of PWC-11, which is used as the structure material in the SP-100 system. Hence, it is concluded that a formation of hot spots is unlikely during the startup or restart of the SP-100 system.

Shrinkage void formation and its effect on freeze and thaw processes of lithium and lithium-fluoride for space applications

NASA Technical Reports Server (NTRS)

Yang, Jae Y.; El-Genk, Mohamed S.

1991-01-01

The effects of shrinkage void forming during freezing of lithium and lithium fluoride on subsequent thaw processes are investigated using a numerical scheme that is based on a single (solid/liquid) cell approach. Results show that a void forming at the wall appreciably reduces the solid-liquid interface velocity, during both freeze and thaw, and causes a substantial rise in the wall temperature during thaw. However, in the case of Li, the maximum wall temperature was much lower than the melting temperature of PWC-11, which is used as the structure material in the SP-100 system. Hence, it is concluded that a formation of hot spots is unlikely during the startup or restart of the SP-100 system.

Porous Teflon ring-solid disk electrode arrangement for differential mass spectrometry measurements in the presence of convective flow generated by a jet impinging electrode in the wall-jet configuration.

PubMed

Treufeld, Imre; Jebaraj, Adriel Jebin Jacob; Xu, Jing; Martins de Godoi, Denis; Scherson, Daniel

2012-06-19

A porous Teflon ring|solid disk electrode is herein described specifically designed for acquiring online mass spectrometric measurements under well-defined forced convection created by liquid emerging from a circular nozzle impinging on the disk under wall-jet conditions. Measurements were performed for the oxidation of hydrazine, N(2)H(4), in a deaerated phosphate buffer electrolyte (pH 7) on Au, a process known to yield dinitrogen as the product. The N(2)(+) ion currents, measured by the mass spectrometer, i(N(2)(+)), as well as the corresponding polarization curves recorded simultaneously displayed very similar s-like shapes when plotted as a function of the potential applied to the Au disk. In fact, the limiting currents observed both electrochemically and spectrometrically were found to be proportional to [N(2)H(4)]. However, the limiting values of i(N(2)(+)) did not increase monotonically with the flow rate, ν(f), reaching instead a maximum and then decreasing to values independent of ν(f). This behavior has been attributed in part to hindrances in the mass transport of gases through the porous materials.

The North American Product Standard for Cross-Laminated Timber

Treesearch

Borjen Yeh; Sylvain Gagnon; Tom Williamson; Ciprian Pirvu; Conroy Lum; Dave Kretschmann

2012-01-01

Cross-laminated timber (CLT) is a prefabricated solid engineered wood product made of at least three orthogonally bonded layers of solid-sawn lumber or structural composite lumber that are laminated by gluing of longitudinal and transverse layers with structural adhesives to form a solid rectangular-shaped, straight, and plane timber intended for roof, floor, or wall...

Critical evaluation and comparison of enrichment efficiency of multi-walled carbon nanotubes, C18 silica and activated carbon towards some pesticides from environmental waters.

PubMed

El-Sheikh, Amjad H; Sweileh, Jamal A; Al-Degs, Yahya S; Insisi, Ahmad A; Al-Rabady, Nancy

2008-02-15

In this work, optimization of multi-residue solid phase extraction (SPE) procedures coupled with high-performance liquid chromatography for the determination of Propoxur, Atrazine and Methidathion from environmental waters is reported. Three different sorbents were used in this work: multi-walled carbon nanotubes (MWCNTs), C18 silica and activated carbon (AC). The three optimized SPE procedures were compared in terms of analytical performance, application to environmental waters, cartridge re-use, adsorption capacity and cost of adsorbent. Although the adsorption capacity of MWCNT was larger than AC and C18, however, the analytical performance of AC could be made close to the other sorbents by appropriate optimization of the SPE procedures. A sample of AC was then oxidized with various oxidizing agents to show that ACs of various surface properties has different enrichment efficiencies. Thus researchers are advised to try AC of various surface properties in SPE of pollutants prior to using expensive sorbents (such as MWCNT and C18 silica).

Swimming trajectories of a three-sphere microswimmer near a wall

NASA Astrophysics Data System (ADS)

Daddi-Moussa-Ider, Abdallah; Lisicki, Maciej; Hoell, Christian; Löwen, Hartmut

2018-04-01

The hydrodynamic flow field generated by self-propelled active particles and swimming microorganisms is strongly altered by the presence of nearby boundaries in a viscous flow. Using a simple model three-linked sphere swimmer, we show that the swimming trajectories near a no-slip wall reveal various scenarios of motion depending on the initial orientation and the distance separating the swimmer from the wall. We find that the swimmer can either be trapped by the wall, completely escape, or perform an oscillatory gliding motion at a constant mean height above the wall. Using a far-field approximation, we find that, at leading order, the wall-induced correction has a source-dipolar or quadrupolar flow structure where the translational and angular velocities of the swimmer decay as inverse third and fourth powers with distance from the wall, respectively. The resulting equations of motion for the trajectories and the relevant order parameters fully characterize the transition between the states and allow for an accurate description of the swimming behavior near a wall. We demonstrate that the transition between the trapping and oscillatory gliding states is first order discontinuous, whereas the transition between the trapping and escaping states is continuous, characterized by non-trivial scaling exponents of the order parameters. In order to model the circular motion of flagellated bacteria near solid interfaces, we further assume that the spheres can undergo rotational motion around the swimming axis. We show that the general three-dimensional motion can be mapped onto a quasi-two-dimensional representational model by an appropriate redefinition of the order parameters governing the transition between the swimming states.

Cellulose-Pectin Spatial Contacts Are Inherent to Never-Dried Arabidopsis Primary Cell Walls: Evidence from Solid-State Nuclear Magnetic Resonance1[OPEN

PubMed Central

Wang, Tuo; Park, Yong Bum; Hong, Mei

2015-01-01

The structural role of pectins in plant primary cell walls is not yet well understood because of the complex and disordered nature of the cell wall polymers. We recently introduced multidimensional solid-state nuclear magnetic resonance spectroscopy to characterize the spatial proximities of wall polysaccharides. The data showed extensive cross peaks between pectins and cellulose in the primary wall of Arabidopsis (Arabidopsis thaliana), indicating subnanometer contacts between the two polysaccharides. This result was unexpected because stable pectin-cellulose interactions are not predicted by in vitro binding assays and prevailing cell wall models. To investigate whether the spatial contacts that give rise to the cross peaks are artifacts of sample preparation, we now compare never-dried Arabidopsis primary walls with dehydrated and rehydrated samples. One-dimensional 13C spectra, two-dimensional 13C-13C correlation spectra, water-polysaccharide correlation spectra, and dynamics data all indicate that the structure, mobility, and intermolecular contacts of the polysaccharides are indistinguishable between never-dried and rehydrated walls. Moreover, a partially depectinated cell wall in which 40% of homogalacturonan is extracted retains cellulose-pectin cross peaks, indicating that the cellulose-pectin contacts are not due to molecular crowding. The cross peaks are observed both at −20°C and at ambient temperature, thus ruling out freezing as a cause of spatial contacts. These results indicate that rhamnogalacturonan I and a portion of homogalacturonan have significant interactions with cellulose microfibrils in the native primary wall. This pectin-cellulose association may be formed during wall biosynthesis and may involve pectin entrapment in or between cellulose microfibrils, which cannot be mimicked by in vitro binding assays. PMID:26036615

Variable-transparency wall regulates temperatures of structures

NASA Technical Reports Server (NTRS)

Osullivan, W. J., Jr.

1964-01-01

An effective temperature regulating wall consists of one layer /e.g., one of the paraffins/ relatively opaque to thermal radiation in the solid state and transparent to it in the molten state and placed between two transparent layers. A mirror coating is applied to back layer.

Unified first wall - blanket structure for plasma device applications

DOEpatents

Gruen, D.M.

A plasma device is described for use in controlling nuclear reactions within the plasma including a first wall and blanket formed in a one-piece structure composed of a solid solution containing copper and lithium and melting above about 500/sup 0/C.

Evaluation of analytical procedures for prediction of turbulent boundary layers on a porous wall

NASA Technical Reports Server (NTRS)

Towne, C. E.

1974-01-01

An analytical study has been made to determine how well current boundary layer prediction techniques work when there is mass transfer normal to the wall. The data that were considered in this investigation were for two-dimensional, incompressible, turbulent boundary layers with suction and blowing. Some of the bleed data were taken in an adverse pressure gradient. An integral prediction method was used three different porous wall skin friction relations, in addition to a solid-surface relation for the suction cases. A numerical prediction method was also used. Comparisons were made between theoretical and experimental skin friction coefficients, displacement and momentum thicknesses, and velocity profiles. The integral method with one of the porous wall skin friction laws gave very good agreement with data for most of the cases considered. The use of the solid-surface skin friction law caused the integral to overpredict the effectiveness of the bleed. The numerical techniques also worked well for most of the cases.

An experimental study of wall-injected flows in a rectangular cylinder

NASA Astrophysics Data System (ADS)

Perrotta, A.; Romano, G. P.; Favini, B.

2018-01-01

An experimental investigation of the flow inside a rectangular cylinder with air injected continuously along the wall is performed. This kind of flow is a two-dimensional approximation of what happens inside a solid rocket motor, where the lateral grain burns expelling exhaust gas or in processes with air filtration or devices to attain uniform flows. We propose a brief derivation of some analytical solutions and a comparison between these solutions and experimental data, which are obtained using the particle image velocimetry technique, to provide a global reconstruction of the flowfield. The flow, which enters orthogonal to the injecting wall, turns suddenly its direction being pushed towards the exit of the chamber. Under the incompressible and inviscid flow hypothesis, two analytical solutions are reported and compared. The first one, known as Hart-McClure solution, is irrotational and the injection velocity is non-perpendicular to the injecting wall. The other one, due to Taylor and Culick, has non-zero vorticity and constant, vertical injection velocity. The comparison with laminar solutions is useful to assess whether transition to turbulence is reached and how the disturbance thrown in by the porous injection influences and modifies those solutions.

Deconstructing a Plant Macromolecular Assembly: Chemical Architecture, Molecular Flexibility, And Mechanical Performance of Natural and Engineered Potato Suberins

PubMed Central

2015-01-01

Periderms present in plant barks are essential protective barriers to water diffusion, mechanical breakdown, and pathogenic invasion. They consist of densely packed layers of dead cells with cell walls that are embedded with suberin. Understanding the interplay of molecular structure, dynamics, and biomechanics in these cell wall-associated insoluble amorphous polymeric assemblies presents substantial investigative challenges. We report solid-state NMR coordinated with FT-IR and tensile strength measurements for periderms from native and wound-healing potatoes and from potatoes with genetically modified suberins. The analyses include the intact suberin aromatic–aliphatic polymer and cell-wall polysaccharides, previously reported soluble depolymerized transmethylation products, and undegraded residues including suberan. Wound-healing suberized potato cell walls, which are 2 orders of magnitude more permeable to water than native periderms, display a strikingly enhanced hydrophilic–hydrophobic balance, a degradation-resistant aromatic domain, and flexibility suggestive of an altered supramolecular organization in the periderm. Suppression of ferulate ester formation in suberin and associated wax remodels the periderm with more flexible aliphatic chains and abundant aromatic constituents that can resist transesterification, attenuates cooperative hydroxyfatty acid motions, and produces a mechanically compromised and highly water-permeable periderm. PMID:24502663

Dynamics of a flexible helical filament rotating in a viscous fluid near a rigid boundary

NASA Astrophysics Data System (ADS)

Jawed, M. K.; Reis, P. M.

2017-03-01

We study the effect of a no-slip rigid boundary on the dynamics of a flexible helical filament rotating in a viscous fluid, at low Reynolds number conditions (Stokes limit). This system is taken as a reduced model for the propulsion of uniflagellar bacteria, whose locomotion is known to be modified near solid boundaries. Specifically, we focus on how the propulsive force generated by the filament, as well as its buckling onset, are modified by the presence of a wall. We tackle this problem through numerical simulations that couple the elasticity of the filament, the hydrodynamic loading, and the wall effect. Each of these three ingredients is respectively modeled by the discrete elastic rods method (for a geometrically nonlinear description of the filament), Lighthill's slender body theory (for a nonlocal fluid force model), and the method of images (to emulate the boundary). The simulations are systematically validated by precision experiments on a rescaled macroscopic apparatus. We find that the propulsive force increases near the wall, while the critical rotation frequency for the onset of buckling usually decreases. A systematic parametric study is performed to quantify the dependence of the wall effects on the geometric parameters of the helical filament.

Deconstructing a plant macromolecular assembly: chemical architecture, molecular flexibility, and mechanical performance of natural and engineered potato suberins.

PubMed

Serra, Olga; Chatterjee, Subhasish; Figueras, Mercè; Molinas, Marisa; Stark, Ruth E

2014-03-10

Periderms present in plant barks are essential protective barriers to water diffusion, mechanical breakdown, and pathogenic invasion. They consist of densely packed layers of dead cells with cell walls that are embedded with suberin. Understanding the interplay of molecular structure, dynamics, and biomechanics in these cell wall-associated insoluble amorphous polymeric assemblies presents substantial investigative challenges. We report solid-state NMR coordinated with FT-IR and tensile strength measurements for periderms from native and wound-healing potatoes and from potatoes with genetically modified suberins. The analyses include the intact suberin aromatic-aliphatic polymer and cell-wall polysaccharides, previously reported soluble depolymerized transmethylation products, and undegraded residues including suberan. Wound-healing suberized potato cell walls, which are 2 orders of magnitude more permeable to water than native periderms, display a strikingly enhanced hydrophilic-hydrophobic balance, a degradation-resistant aromatic domain, and flexibility suggestive of an altered supramolecular organization in the periderm. Suppression of ferulate ester formation in suberin and associated wax remodels the periderm with more flexible aliphatic chains and abundant aromatic constituents that can resist transesterification, attenuates cooperative hydroxyfatty acid motions, and produces a mechanically compromised and highly water-permeable periderm.

Turbulence modeling of gas-solid suspension flows

NASA Technical Reports Server (NTRS)

Chen, C. P.

1988-01-01

The purpose here is to discuss and review advances in two-phase turbulent modeling techniques and their applications in various gas-solid suspension flow situations. In addition to the turbulence closures, heat transfer effect, particle dispersion and wall effects are partially covered.

Proteomic analysis of extracellular proteins from Aspergillus oryzae grown under submerged and solid-state culture conditions.

PubMed

Oda, Ken; Kakizono, Dararat; Yamada, Osamu; Iefuji, Haruyuki; Akita, Osamu; Iwashita, Kazuhiro

2006-05-01

Filamentous fungi are widely used for the production of homologous and heterologous proteins. Recently, there has been increasing interest in Aspergillus oryzae because of its ability to produce heterologous proteins in solid-state culture. To provide an overview of protein secretion by A. oryzae in solid-state culture, we carried out a comparative proteome analysis of extracellular proteins in solid-state and submerged (liquid) cultures. Extracellular proteins prepared from both cultures sequentially from 0 to 40 h were subjected to two-dimensional electrophoresis, and protein spots at 40 h were identified by peptide mass fingerprinting using matrix-assisted laser desorption ionization-time-of-flight mass spectrometry. We also attempted to identify cell wall-bound proteins of the submerged culture. We analyzed 85 spots from the solid-state culture and 110 spots from the submerged culture. We identified a total of 29 proteins, which were classified into 4 groups. Group 1 consisted of extracellular proteins specifically produced in the solid-state growth condition, such as glucoamylase B and alanyl dipeptidyl peptidase. Group 2 consisted of extracellular proteins specifically produced in the submerged condition, such as glucoamylase A (GlaA) and xylanase G2 (XynG2). Group 3 consisted of proteins produced in both conditions, such as xylanase G1. Group 4 consisted of proteins that were secreted to the medium in the solid-state growth condition but trapped in the cell wall in the submerged condition, such as alpha-amylase (TAA) and beta-glucosidase (Bgl). A Northern analysis of seven genes from the four groups suggested that the secretion of TAA and Bgl was regulated by trapping these proteins in the cell wall in submerged culture and that secretion of GlaA and XynG2 was regulated at the posttranscriptional level in the solid-state culture.

Proteomic Analysis of Extracellular Proteins from Aspergillus oryzae Grown under Submerged and Solid-State Culture Conditions

PubMed Central

Oda, Ken; Kakizono, Dararat; Yamada, Osamu; Iefuji, Haruyuki; Akita, Osamu; Iwashita, Kazuhiro

2006-01-01

Filamentous fungi are widely used for the production of homologous and heterologous proteins. Recently, there has been increasing interest in Aspergillus oryzae because of its ability to produce heterologous proteins in solid-state culture. To provide an overview of protein secretion by A. oryzae in solid-state culture, we carried out a comparative proteome analysis of extracellular proteins in solid-state and submerged (liquid) cultures. Extracellular proteins prepared from both cultures sequentially from 0 to 40 h were subjected to two-dimensional electrophoresis, and protein spots at 40 h were identified by peptide mass fingerprinting using matrix-assisted laser desorption ionization-time-of-flight mass spectrometry. We also attempted to identify cell wall-bound proteins of the submerged culture. We analyzed 85 spots from the solid-state culture and 110 spots from the submerged culture. We identified a total of 29 proteins, which were classified into 4 groups. Group 1 consisted of extracellular proteins specifically produced in the solid-state growth condition, such as glucoamylase B and alanyl dipeptidyl peptidase. Group 2 consisted of extracellular proteins specifically produced in the submerged condition, such as glucoamylase A (GlaA) and xylanase G2 (XynG2). Group 3 consisted of proteins produced in both conditions, such as xylanase G1. Group 4 consisted of proteins that were secreted to the medium in the solid-state growth condition but trapped in the cell wall in the submerged condition, such as α-amylase (TAA) and β-glucosidase (Bgl). A Northern analysis of seven genes from the four groups suggested that the secretion of TAA and Bgl was regulated by trapping these proteins in the cell wall in submerged culture and that secretion of GlaA and XynG2 was regulated at the posttranscriptional level in the solid-state culture. PMID:16672490

Ice Layer Spreading along a Solid Substrate during Solidification of Supercooled Water: Experiments and Modeling.

PubMed

Schremb, Markus; Campbell, James M; Christenson, Hugo K; Tropea, Cameron

2017-05-16

The thermal influence of a solid wall on the solidification of a sessile supercooled water drop is experimentally investigated. The velocity of the initial ice layer propagating along the solid substrate prior to dendritic solidification is determined from videos captured using a high-speed video system. Experiments are performed for varying substrate materials and liquid supercooling. In contrast to recent studies at moderate supercooling, in the case of metallic substrates only a weak influence of the substrate's thermal properties on the ice layer velocity is observed. Using the analytical solution of the two-phase Stefan problem, a semiempirical model for the ice layer velocity is developed. The experimental data are well described for all supercooling levels in the entire diffusion limited solidification regime. For higher supercooling, the model overestimates the freezing velocity due to kinetic effects during molecular attachment at the solid-liquid interface, which are not accounted for in the model. The experimental findings of the present work offer a new perspective on the design of anti-icing systems.

Investigation of Tokamak Solid Divertor Target Options.

DTIC Science & Technology

1981-05-26

but materials are not known which could operate at the high resulting wall temperatures . Mist- steam flows would also demand a relatively high ...flux P = coolant density = bulk coolant viscosity w = coolant viscosity at average wall temperature = units conversion At high heat loads and moderate...therefore, the inner wall temperature will be over 300 OF, posing a high temp- erature materials challenge. E. Swirl and Mixed Flow Schemes Extensive work

Apparatus for the pulverization and burning of solid fuels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sayler, W.H.; White, J.C.

1988-06-07

This patent describes an apparatus for pulverizing coarsely-divided, solid fuel, such as coal, and for feeding the pulverized fuel to a burner. It comprises an upstanding housing having side, bottom and top walls; an upstanding shaft axially mounted for rotation within the housing; means for rotating the shaft; a slinger having an annular opening therethrough concentric with and closely encircling the shaft; fan means secured to the shaft immediately below the top wall of the housing; air-turbulating means comprising a pair of spiders; air-inlet means in the housing below the slinger so that air will flow upwardly through the annularmore » opening as well as peripherally of the slinger, entraining fine solid fuel particles during passage through the housing interior for further pulverization by size attrition between the spiders; outlet means provided through the side of the housing adjacent to the fan means; and outlet means being adapted for connection with the burner; and solid fuel input mans leading into the housing and positioned to feed coarsely-divided solid fuel onto the slinger.« less

Flame front propagation in a channel with porous walls

NASA Astrophysics Data System (ADS)

Golovastov, S. V.; Bivol, G. Yu

2016-11-01

Propagation of the detonation front in hydrogen-air mixture was investigated in rectangular cross-section channels with sound-absorbing boundaries. The front of luminescence was detected in a channel with acoustically absorbing walls as opposed to a channel with solid walls. Flame dynamics was recorded using a high-speed camera. The flame was observed to have a V-shaped profile in the acoustically absorbing section. The possible reason for the formation of the V-shaped flame front is friction under the surface due to open pores. In these shear flows, the kinetic energy of the flow on the surface can be easily converted into heat. A relatively small disturbance may eventually lead to significant local stretching of the flame front surface. Trajectories of the flame front along the axis and the boundary are presented for solid and porous surfaces.

Turbulent Flow Over Large Roughness Elements: Effect of Frontal and Plan Solidity on Turbulence Statistics and Structure

NASA Astrophysics Data System (ADS)

Placidi, M.; Ganapathisubramani, B.

2018-04-01

Wind-tunnel experiments were carried out on fully-rough boundary layers with large roughness (δ /h ≈ 10, where h is the height of the roughness elements and δ is the boundary-layer thickness). Twelve different surface conditions were created by using LEGO™ bricks of uniform height. Six cases are tested for a fixed plan solidity (λ _P) with variations in frontal density (λ _F), while the other six cases have varying λ _P for fixed λ _F. Particle image velocimetry and floating-element drag-balance measurements were performed. The current results complement those contained in Placidi and Ganapathisubramani (J Fluid Mech 782:541-566, 2015), extending the previous analysis to the turbulence statistics and spatial structure. Results indicate that mean velocity profiles in defect form agree with Townsend's similarity hypothesis with varying λ _F, however, the agreement is worse for cases with varying λ _P. The streamwise and wall-normal turbulent stresses, as well as the Reynolds shear stresses, show a lack of similarity across most examined cases. This suggests that the critical height of the roughness for which outer-layer similarity holds depends not only on the height of the roughness, but also on the local wall morphology. A new criterion based on shelter solidity, defined as the sheltered plan area per unit wall-parallel area, which is similar to the `effective shelter area' in Raupach and Shaw (Boundary-Layer Meteorol 22:79-90, 1982), is found to capture the departure of the turbulence statistics from outer-layer similarity. Despite this lack of similarity reported in the turbulence statistics, proper orthogonal decomposition analysis, as well as two-point spatial correlations, show that some form of universal flow structure is present, as all cases exhibit virtually identical proper orthogonal decomposition mode shapes and correlation fields. Finally, reduced models based on proper orthogonal decomposition reveal that the small scales of the turbulence play a significant role in assessing outer-layer similarity.

Unified description of the slip phenomena in sheared polymer films: A molecular dynamics study

NASA Astrophysics Data System (ADS)

Priezjev, Nikolai

2010-03-01

The dynamic behavior of the slip length in shear flow of polymer melts past atomically smooth surfaces is investigated using MD simulations. The polymer melt was modeled as a collection of FENE-LJ bead-spring chains. We consider shear flow conditions at low pressures and weak wall-fluid interaction energy so that fluid velocity profiles are linear throughout the channel at all shear rates examined. In agreement with earlier studies we confirm that for shear- thinning fluids the slip length passes through a local minimum at low shear rates and then increases rapidly at higher shear rates. We found that the rate dependence of the slip length depends on the lattice orientation at high shear rates. The MD results show that the ratio of slip length to viscosity follows a master curve when plotted as a function of a single variable that depends on the structure factor, contact density and temperature of the first fluid layer near the solid wall. The universal dependence of the slip length holds for a number of parameters of the interface: fluid density and structure (chain length), wall-fluid interaction energy, wall density, lattice orientation, thermal or solid walls.

Solid oxide fuel cell having monolithic core

DOEpatents

Ackerman, John P.; Young, John E.

1984-01-01

A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween, and each interconnect wall consists of thin layers of the cathode and anode materials sandwiching a thin layer of interconnect material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick.

Evaluation of Wall Interference Effects in a Two-Dimensional Transonic Wind Tunnel by Subsonic Linear Theory,

DTIC Science & Technology

1979-02-01

tests were conducted on two geometrica lly similar models of each of two aerofoil sections -—t he NA CA 00/ 2 and the BGK- 1 sections -and covered a...and slotted-wall tes t sections are corrected for wind tunnel wall interference efJ~cts by the application of classical linearized theory. For the...solid wall results , these corrections appear to produce data which are very close to being free of the effects of interference. In the case of

Built-up outer wall and roofing sections for double walled envelope homes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brodhead, B.

1980-01-01

A site built system that uses the inner envelope wall is described. Blocking and vertical nailers are attached to this wall and sheathed with foil faced drywall to create the envelope cavity. An outer layer of 3 1/2 in. of Expended Poly Styrene provides continuous solid insulation. The trusses are also sheathed in foil faced drywall and insulated with 5 1/2 in. of E.P.S. This effectively surrounds the building with a continuous vapor and infiltration barrier. Construction details as well as cost breakdowns are presented.

Determination of six sulfonylurea herbicides in environmental water samples by magnetic solid-phase extraction using multi-walled carbon nanotubes as adsorbents coupled with high-performance liquid chromatography.

PubMed

Ma, Jiping; Jiang, Lianhua; Wu, Gege; Xia, Yan; Lu, Wenhui; Li, Jinhua; Chen, Lingxin

2016-09-30

Magnetic solid-phase extraction (MSPE) using magnetic multi-walled carbon nanotubes (mag-MWCNTs) as adsorbents, coupled with high-performance liquid chromatography-diode-array detector (HPLC-DAD), was developed for the simultaneous separation and determination of six types of sulfonylurea herbicides (SUs) in environmental water samples. Several variables affecting MSPE efficiency were systematically investigated, including the type and volume of desorption solvent, sample solution pH, salt concentration, amount of mag-MWCNTs, and extraction and desorption time. Response surface was employed to assist in the MSPE optimization. Under optimized conditions, excellent linearity was achieved in the range of 0.05-5.0μg/L for all six SUs, with coefficients of correlation r>0.9994, and preconcentration factors ranging from 178 to 210. Limits of detection and quantification were 0.01-0.04μg/L and 0.03-0.13μg/L, respectively. The intra-day and inter-day precision (relative standard deviations, n=6, %) at three spiked levels were 2.0-11.0% and 2.1-12.9% in terms of peak area, respectively. The method recoveries at three fortified concentrations were obtained within 76.7-106.9% for reservoir water samples and 78.2-105.4% for tap water samples. The developed MSPE-HPLC method demonstrated high sensitivity, repeatability, simplicity, rapidity, and excellent practical applicability. Copyright © 2016 Elsevier B.V. All rights reserved.

Manipulation and control of instabilities for surfactant-laden liquid film flowing down an inclined plane using a deformable solid layer

NASA Astrophysics Data System (ADS)

Tomar, Dharmendra S.; Sharma, Gaurav

2018-01-01

We analyzed the linear stability of surfactant-laden liquid film with a free surface flowing down an inclined plane under the action of gravity when the inclined plane is coated with a deformable solid layer. For a flow past a rigid incline and in the presence of inertia, the gas-liquid (GL) interface is prone to the free surface instability and the presence of surfactant is known to stabilize the free surface mode when the Marangoni number increases above a critical value. The rigid surface configuration also admits a surfactant induced Marangoni mode which remains stable for film flows with a free surface. This Marangoni mode was observed to become unstable for a surfactant covered film flow past a flexible inclined plane in a creeping flow limit when the wall is made sufficiently deformable. In view of these observations, we investigate the following two aspects. First, what is the effect of inertia on Marangoni mode instability induced by wall deformability? Second, and more importantly, whether it is possible to use a deformable solid coating to obtain stable flow for the surfactant covered film for cases when the Marangoni number is below the critical value required for stabilization of free surface instability. In order to explore the first question, we continued the growth rates for the Marangoni mode from the creeping flow limit to finite Reynolds numbers (Re) and observed that while the increase in Reynolds number has a small stabilizing effect on growth rates, the Marangoni mode still remains unstable for finite Reynolds numbers as long as the wall is sufficiently deformable. The Marangoni mode remains the dominant mode for zero and small Reynolds numbers until the GL mode also becomes unstable with the increase in Re. Thus, for a given set of parameters and beyond a critical Re, there is an exchange of dominant mode of instability from the Marangoni to free surface GL mode. With respect to the second important aspect, our results clearly demonstrate that for cases when the stabilizing contribution of surfactant is not sufficient for suppressing GL mode instability, a deformable solid coating could be employed to suppress free surface instability without triggering Marangoni or liquid-solid interfacial modes. Specifically, we have shown that for a given solid thickness, as the shear modulus of the solid layer decreases (i.e., the solid becomes more deformable) the GL mode instability is suppressed. With further decrease in shear modulus, the Marangoni and liquid-solid interfacial modes become unstable. Thus, there exists a stability window in terms of shear modulus where the surfactant-laden film flow remains stable even when the Marangoni number is below the critical value required for free surface instability suppression. Further, when the Marangoni number is greater than the critical value so that the GL mode remains stable in the rigid limit or with the deformable wall, the increase in wall deformability or solid thickness triggers Marangoni mode instability and, thus, renders a stable flow configuration into an unstable one. Thus, we show that the soft solid layer can be used to manipulate and control the stability of surfactant-laden film flows.

Direct numerical simulation of turbulent boundary layer with fully resolved particles at low volume fraction.

PubMed

Luo, Kun; Hu, Chenshu; Wu, Fan; Fan, Jianren

2017-05-01

In the present work, a direct numerical simulation (DNS) of dilute particulate flow in a turbulent boundary layer has been conducted, containing thousands of finite-sized solid rigid particles. The particle surfaces are resolved with the multi-direct forcing immersed-boundary method. This is, to the best of the authors' knowledge, the first DNS study of a turbulent boundary layer laden with finite-sized particles. The particles have a diameter of approximately 11.3 wall units, a density of 3.3 times that of the fluid, and a solid volume fraction of 1/1000. The simulation shows that the onset and the completion of the transition processes are shifted earlier with the inclusion of the solid phase and that the resulting streamwise mean velocity of the boundary layer in the particle-laden case is almost consistent with the results of the single-phase case. At the same time, relatively stronger particle movements are observed in the near-wall regions, due to the driving of the counterrotating streamwise vortexes. As a result, increased levels of dissipation occur on the particle surfaces, and the root mean square of the fluctuating velocities of the fluid in the near-wall regions is decreased. Under the present parameters, including the particle Stokes number St + = 24 and the particle Reynolds number Re p = 33 based on the maximum instantaneous fluid-solid velocity lag, no vortex shedding behind the particle is observed. Lastly, a trajectory analysis of the particles shows the influence of turbophoresis on particle wall-normal concentration, and the particles that originated between y + = 60 and 2/3 of the boundary-layer thickness are the most influenced.

Direct numerical simulation of turbulent boundary layer with fully resolved particles at low volume fraction

PubMed Central

Luo, Kun; Hu, Chenshu; Wu, Fan; Fan, Jianren

2017-01-01

In the present work, a direct numerical simulation (DNS) of dilute particulate flow in a turbulent boundary layer has been conducted, containing thousands of finite-sized solid rigid particles. The particle surfaces are resolved with the multi-direct forcing immersed-boundary method. This is, to the best of the authors’ knowledge, the first DNS study of a turbulent boundary layer laden with finite-sized particles. The particles have a diameter of approximately 11.3 wall units, a density of 3.3 times that of the fluid, and a solid volume fraction of 1/1000. The simulation shows that the onset and the completion of the transition processes are shifted earlier with the inclusion of the solid phase and that the resulting streamwise mean velocity of the boundary layer in the particle-laden case is almost consistent with the results of the single-phase case. At the same time, relatively stronger particle movements are observed in the near-wall regions, due to the driving of the counterrotating streamwise vortexes. As a result, increased levels of dissipation occur on the particle surfaces, and the root mean square of the fluctuating velocities of the fluid in the near-wall regions is decreased. Under the present parameters, including the particle Stokes number St+ = 24 and the particle Reynolds number Rep = 33 based on the maximum instantaneous fluid-solid velocity lag, no vortex shedding behind the particle is observed. Lastly, a trajectory analysis of the particles shows the influence of turbophoresis on particle wall-normal concentration, and the particles that originated between y+ = 60 and 2/3 of the boundary-layer thickness are the most influenced. PMID:29104418

Direct numerical simulation of turbulent boundary layer with fully resolved particles at low volume fraction

NASA Astrophysics Data System (ADS)

Luo, Kun; Hu, Chenshu; Wu, Fan; Fan, Jianren

2017-05-01

In the present work, a direct numerical simulation (DNS) of dilute particulate flow in a turbulent boundary layer has been conducted, containing thousands of finite-sized solid rigid particles. The particle surfaces are resolved with the multi-direct forcing immersed-boundary method. This is, to the best of the authors' knowledge, the first DNS study of a turbulent boundary layer laden with finite-sized particles. The particles have a diameter of approximately 11.3 wall units, a density of 3.3 times that of the fluid, and a solid volume fraction of 1/1000. The simulation shows that the onset and the completion of the transition processes are shifted earlier with the inclusion of the solid phase and that the resulting streamwise mean velocity of the boundary layer in the particle-laden case is almost consistent with the results of the single-phase case. At the same time, relatively stronger particle movements are observed in the near-wall regions, due to the driving of the counterrotating streamwise vortexes. As a result, increased levels of dissipation occur on the particle surfaces, and the root mean square of the fluctuating velocities of the fluid in the near-wall regions is decreased. Under the present parameters, including the particle Stokes number St+ = 24 and the particle Reynolds number Rep = 33 based on the maximum instantaneous fluid-solid velocity lag, no vortex shedding behind the particle is observed. Lastly, a trajectory analysis of the particles shows the influence of turbophoresis on particle wall-normal concentration, and the particles that originated between y+ = 60 and 2/3 of the boundary-layer thickness are the most influenced.

Analysis of solid particles falling down and interacting in a channel with sedimentation using fictitious boundary method

NASA Astrophysics Data System (ADS)

Usman, K.; Walayat, K.; Mahmood, R.; Kousar, N.

2018-06-01

We have examined the behavior of solid particles in particulate flows. The interaction of particles with each other and with the fluid is analyzed. Solid particles can move freely through a fixed computational mesh using an Eulerian approach. Fictitious boundary method (FBM) is used for treating the interaction between particles and the fluid. Hydrodynamic forces acting on the particle's surface are calculated using an explicit volume integral approach. A collision model proposed by Glowinski, Singh, Joseph and coauthors is used to handle particle-wall and particle-particle interactions. The particulate flow is computed using multigrid finite element solver FEATFLOW. Numerical experiments are performed considering two particles falling and colliding and sedimentation of many particles while interacting with each other. Results for these experiments are presented and compared with the reference values. Effects of the particle-particle interaction on the motion of the particles and on the physical behavior of the fluid-particle system has been analyzed.

A custom acoustic emission monitoring system for harsh environments: application to freezing-induced damage in alpine rock-walls

NASA Astrophysics Data System (ADS)

Girard, L.; Beutel, J.; Gruber, S.; Hunziker, J.; Lim, R.; Weber, S.

2012-06-01

We present a custom acoustic emission (AE) monitoring system designed to perform long-term measurements on high-alpine rock-walls. AE monitoring is a common technique for characterizing damage evolution in solid materials. The system is based on a two-channel AE sensor node (AE-node) integrated into a Wireless Sensor Network (WSN) customized for operation in harsh environments. This wireless architecture offers flexibility in the deployment of AE-nodes at any position of the rock-wall that needs to be monitored, within a range of a few hundred meters from a core station connected to the internet. The system achieves near real-time data delivery and allows the user to remotely control the AE detection threshold. In order to protect AE sensors and capture acoustic signals from specific depths of the rock-wall, a special casing was developed. The monitoring system is completed by two probes that measure rock temperature and liquid water content, both probes being also integrated into the WSN. We report a first deployment of the monitoring system on a rock-wall at Jungfraujoch, 3500 m a.s.l., Switzerland. While this first deployment of the monitoring system aims to support fundamental research on processes that damage rock under cold climate, the system could serve a number of other applications, including rock-fall hazard surveillance or structural monitoring of concrete structures.

A custom acoustic emission monitoring system for harsh environments: application to freezing-induced damage in alpine rock walls

NASA Astrophysics Data System (ADS)

Girard, L.; Beutel, J.; Gruber, S.; Hunziker, J.; Lim, R.; Weber, S.

2012-11-01

We present a custom acoustic emission (AE) monitoring system designed to perform long-term measurements on high-alpine rock walls. AE monitoring is a common technique for characterizing damage evolution in solid materials. The system is based on a two-channel AE sensor node (AE-node) integrated into a wireless sensor network (WSN) customized for operation in harsh environments. This wireless architecture offers flexibility in the deployment of AE-nodes at any position of the rock wall that needs to be monitored, within a range of a few hundred meters from a core station connected to the internet. The system achieves near real-time data delivery and allows the user to remotely control the AE detection threshold. In order to protect AE sensors and capture acoustic signals from specific depths of the rock wall, a special casing was developed. The monitoring system is completed by two probes that measure rock temperature and liquid water content, both probes being also integrated into the WSN. We report a first deployment of the monitoring system on a rock wall at Jungfraujoch, 3500 m a.s.l., Switzerland. While this first deployment of the monitoring system aims to support fundamental research on processes that damage rock under cold climate, the system could serve a number of other applications, including rock fall hazard surveillance or structural monitoring of concrete structures.

An effective simplified model of composite compression struts for partially-restrained steel frame with reinforced concrete infill walls

NASA Astrophysics Data System (ADS)

Sun, Guohua; Chuang-Sheng, Walter Yang; Gu, Qiang; DesRoches, Reginald

2018-04-01

To resolve the issue regarding inaccurate prediction of the hysteretic behavior by micro-based numerical analysis for partially-restrained (PR) steel frames with solid reinforced concrete (RC) infill walls, an innovative simplified model of composite compression struts is proposed on the basis of experimental observation on the cracking distribution, load transferring mechanism, and failure modes of RC infill walls filled in PR steel frame. The proposed composite compression struts model for the solid RC infill walls is composed of α inclined struts and main diagonal struts. The α inclined struts are used to reflect the part of the lateral force resisted by shear connectors along the frame-wall interface, while the main diagonal struts are introduced to take into account the rest of the lateral force transferred along the diagonal direction due to the complicated interaction between the steel frame and RC infill walls. This study derives appropriate formulas for the effective widths of the α inclined strut and main diagonal strut, respectively. An example of PR steel frame with RC infill walls simulating simulated by the composite inclined compression struts model is illustrated. The maximum lateral strength and the hysteresis curve shape obtained from the proposed composite strut model are in good agreement with those from the test results, and the backbone curve of a PR steel frame with RC infill walls can be predicted precisely when the inter-story drift is within 1%. This simplified model can also predict the structural stiffness and the equivalent viscous damping ratio well when the inter-story drift ratio exceeds 0.5%.

Effect of solid boundaries on swimming dynamics of microorganisms in a viscoelastic fluid

PubMed Central

Li, G. -J.; Karimi, A.

2015-01-01

We numerically study the effect of solid boundaries on the swimming behavior of a motile microorganism in viscoelastic media. Understanding the swimmer-wall hydrodynamic interactions is crucial to elucidate the adhesion of bacterial cells to nearby substrates which is precursor to the formation of the microbial biofilms. The microorganism is simulated using a squirmer model that captures the major swimming mechanisms of potential, extensile, and contractile types of swimmers, while neglecting the biological complexities. A Giesekus constitutive equation is utilized to describe both viscoelasticity and shear-thinning behavior of the background fluid. We found that the viscoelasticity strongly affects the near-wall motion of a squirmer by generating an opposing polymeric torque which impedes the rotation of the swimmer away from the wall. In particular, the time a neutral squirmer spends at the close proximity of the wall is shown to increase with polymer relaxation time and reaches a maximum at Weissenberg number of unity. The shear-thinning effect is found to weaken the solvent stress and therefore, increases the swimmer-wall contact time. For a puller swimmer, the polymer stretching mainly occurs around its lateral sides, leading to reduced elastic resistance against its locomotion. The neutral and puller swimmers eventually escape the wall attraction effect due to a releasing force generated by the Newtonian viscous stress. In contrast, the pusher is found to be perpetually trapped near the wall as a result of the formation of a highly stretched region behind its body. It is shown that the shear-thinning property of the fluid weakens the wall-trapping effect for the pusher squirmer. PMID:26855446

First wall structural analysis of the aqueous self-cooled blanket concept

DOE Office of Scientific and Technical Information (OSTI.GOV)

O'Brien, D.A.; Steiner, D.; Embrechts, M.J.

1986-11-01

A recently proposed blanket concept using water coolant with dissolved lithium compounds for breeding employs water cooled first walls. Water cooled first walls for blankets have also been proposed for some solid breeder blankets. Design options for water cooled first walls are examined in this paper. Four geometries and three materials are analyzed for water coolant at 300/sup 0/C and 13.8 MPa (2000 psi). Maximum neutron wall loads (with surface heat loads being 25% of neutron wall load) are determined for each geometry and material combination. Of the materials studied, only vanadium alloy is found to be capable of withstandingmore » high wall loads (>10MW/m/sup 2/ neutron and >2.5 MW/m/sup 2/ heat).« less

Technique for Performing Dielectric Property Measurements at Microwave Frequencies

NASA Technical Reports Server (NTRS)

Barmatz, Martin B.; Jackson, Henry W.

2010-01-01

A paper discusses the need to perform accurate dielectric property measurements on larger sized samples, particularly liquids at microwave frequencies. These types of measurements cannot be obtained using conventional cavity perturbation methods, particularly for liquids or powdered or granulated solids that require a surrounding container. To solve this problem, a model has been developed for the resonant frequency and quality factor of a cylindrical microwave cavity containing concentric cylindrical samples. This model can then be inverted to obtain the real and imaginary dielectric constants of the material of interest. This approach is based on using exact solutions to Maxwell s equations for the resonant properties of a cylindrical microwave cavity and also using the effective electrical conductivity of the cavity walls that is estimated from the measured empty cavity quality factor. This new approach calculates the complex resonant frequency and associated electromagnetic fields for a cylindrical microwave cavity with lossy walls that is loaded with concentric, axially aligned, lossy dielectric cylindrical samples. In this approach, the calculated complex resonant frequency, consisting of real and imaginary parts, is related to the experimentally measured quantities. Because this approach uses Maxwell's equations to determine the perturbed electromagnetic fields in the cavity with the material(s) inserted, one can calculate the expected wall losses using the fields for the loaded cavity rather than just depending on the value of the fields obtained from the empty cavity quality factor. These additional calculations provide a more accurate determination of the complex dielectric constant of the material being studied. The improved approach will be particularly important when working with larger samples or samples with larger dielectric constants that will further perturb the cavity electromagnetic fields. Also, this approach enables the ability to have a larger sample of interest, such as a liquid or powdered or granulated solid, inside a cylindrical container.

The complex chemistry of outflow cavity walls exposed: the case of low-mass protostars

NASA Astrophysics Data System (ADS)

Drozdovskaya, Maria N.; Walsh, Catherine; Visser, Ruud; Harsono, Daniel; van Dishoeck, Ewine F.

2015-08-01

Complex organic molecules are ubiquitous companions of young low-mass protostars. Recent observations suggest that their emission stems, not only from the traditional hot corino, but also from offset positions. In this work, 2D physicochemical modelling of an envelope-cavity system is carried out. Wavelength-dependent radiative transfer calculations are performed and a comprehensive gas-grain chemical network is used to simulate the physical and chemical structure. The morphology of the system delineates three distinct regions: the cavity wall layer with time-dependent and species-variant enhancements; a torus rich in complex organic ices, but not reflected in gas-phase abundances and the remaining outer envelope abundant in simpler solid and gaseous molecules. Strongly irradiated regions, such as the cavity wall layer, are subject to frequent photodissociation in the solid phase. Subsequent recombination of the photoproducts leads to frequent reactive desorption, causing gas-phase enhancements of several orders of magnitude. This mechanism remains to be quantified with laboratory experiments. Direct photodesorption is found to be relatively inefficient. If radicals are not produced directly in the icy mantle, the formation of complex organics is impeded. For efficiency, a sufficient number of FUV photons needs to penetrate the envelope, and elevated cool dust temperatures need to enable grain-surface radical mobility. As a result, a high stellar luminosity and a sufficiently wide cavity favour chemical complexity. Furthermore within this paradigm, complex organics are demonstrated to have unique lifetimes and be grouped into early (formaldehyde, ketene, methanol, formic acid, methyl formate, acetic acid and glycolaldehyde) and late (acetaldehyde, dimethyl ether and ethanol) species.

StegoWall: blind statistical detection of hidden data

NASA Astrophysics Data System (ADS)

Voloshynovskiy, Sviatoslav V.; Herrigel, Alexander; Rytsar, Yuri B.; Pun, Thierry

2002-04-01

Novel functional possibilities, provided by recent data hiding technologies, carry out the danger of uncontrolled (unauthorized) and unlimited information exchange that might be used by people with unfriendly interests. The multimedia industry as well as the research community recognize the urgent necessity for network security and copyright protection, or rather the lack of adequate law for digital multimedia protection. This paper advocates the need for detecting hidden data in digital and analog media as well as in electronic transmissions, and for attempting to identify the underlying hidden data. Solving this problem calls for the development of an architecture for blind stochastic hidden data detection in order to prevent unauthorized data exchange. The proposed architecture is called StegoWall; its key aspects are the solid investigation, the deep understanding, and the prediction of possible tendencies in the development of advanced data hiding technologies. The basic idea of our complex approach is to exploit all information about hidden data statistics to perform its detection based on a stochastic framework. The StegoWall system will be used for four main applications: robust watermarking, secret communications, integrity control and tamper proofing, and internet/network security.

Use of an Accurate DNS Particulate Flow Method to Supply and Validate Boundary Conditions for the MFIX Code

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhi-Gang Feng

2012-05-31

The simulation of particulate flows for industrial applications often requires the use of two-fluid models, where the solid particles are considered as a separate continuous phase. One of the underlining uncertainties in the use of the two-fluid models in multiphase computations comes from the boundary condition of the solid phase. Typically, the gas or liquid fluid boundary condition at a solid wall is the so called no-slip condition, which has been widely accepted to be valid for single-phase fluid dynamics provided that the Knudsen number is low. However, the boundary condition for the solid phase is not well understood. Themore » no-slip condition at a solid boundary is not a valid assumption for the solid phase. Instead, several researchers advocate a slip condition as a more appropriate boundary condition. However, the question on the selection of an exact slip length or a slip velocity coefficient is still unanswered. Experimental or numerical simulation data are needed in order to determinate the slip boundary condition that is applicable to a two-fluid model. The goal of this project is to improve the performance and accuracy of the boundary conditions used in two-fluid models such as the MFIX code, which is frequently used in multiphase flow simulations. The specific objectives of the project are to use first principles embedded in a validated Direct Numerical Simulation particulate flow numerical program, which uses the Immersed Boundary method (DNS-IB) and the Direct Forcing scheme in order to establish, modify and validate needed energy and momentum boundary conditions for the MFIX code. To achieve these objectives, we have developed a highly efficient DNS code and conducted numerical simulations to investigate the particle-wall and particle-particle interactions in particulate flows. Most of our research findings have been reported in major conferences and archived journals, which are listed in Section 7 of this report. In this report, we will present a brief description of these results.« less

Molecular discriminators using single wall carbon nanotubes

NASA Astrophysics Data System (ADS)

Bhattacharyya, Tamoghna; Dasgupta, Anjan Kr; Ranjan Ray, Nihar; Sarkar, Sabyasachi

2012-09-01

The interaction between single wall carbon nanotubes (SWNTs) and amphiphilic molecules has been studied in a solid phase. SWNTs are allowed to interact with different amphiphilic probes (e.g. lipids) in a narrow capillary interface. Contact between strong hydrophobic and amphiphilic interfaces leads to a molecular restructuring of the lipids at the interface. The geometry of the diffusion front and the rate and the extent of diffusion of the interface are dependent on the structure of the lipid at the interface. Lecithin having a linear tail showed greater mobility of the interface as compared to a branched tail lipid like dipalmitoyl phosphatidylcholine, indicating the hydrophobic interaction between single wall carbon nanotube core and the hydrophobic tail of the lipid. Solid phase interactions between SWNT and lipids can thus become a very simple but efficient means of discriminating amphiphilic molecules in general and lipids in particular.

Entrainment of solid particles over irregular wavy walls

NASA Astrophysics Data System (ADS)

Milici, Barbara

2017-11-01

The distribution of inertial particles in turbulent flows is highly nonuniform and is governed by the dynamics of turbulent structures of the underlying carrier flow field which, in turn, is affected by the presence of a loading of dispersed particles. The issue is discussed here focusing on the coupling between near-bed coherent structures and suspended solid particles dynamics, in wall-bounded turbulent multiphase flows, bounded by rough boundaries. The friction Reynolds number of the unladen flow is Reτ=180 and the dispersed phase spans one order of magnitude of particle diameter. The analysis takes into account fluid-particle interaction (two-way coupling) in the frame of the Particle-Source-In-Cell (PSIC) method, using Direct Numerical Simulations (DNS) for the carrier phase coupled with Lagrangian Particle Tracking (LPT) for the dispersed phase. The effect of the wall's roughness is taken into account modelling the elastic rebound of particles onto it, instead of using a virtual rebound model.

High-performance multi-functional reverse osmosis membranes obtained by carbon nanotube·polyamide nanocomposite

PubMed Central

Inukai, Shigeki; Cruz-Silva, Rodolfo; Ortiz-Medina, Josue; Morelos-Gomez, Aaron; Takeuchi, Kenji; Hayashi, Takuya; Tanioka, Akihiko; Araki, Takumi; Tejima, Syogo; Noguchi, Toru; Terrones, Mauricio; Endo, Morinobu

2015-01-01

Clean water obtained by desalinating sea water or by purifying wastewater, constitutes a major technological objective in the so-called water century. In this work, a high-performance reverse osmosis (RO) composite thin membrane using multi-walled carbon nanotubes (MWCNT) and aromatic polyamide (PA), was successfully prepared by interfacial polymerization. The effect of MWCNT on the chlorine resistance, antifouling and desalination performances of the nanocomposite membranes were studied. We found that a suitable amount of MWCNT in PA, 15.5 wt.%, not only improves the membrane performance in terms of flow and antifouling, but also inhibits the chlorine degradation on these membranes. Therefore, the present results clearly establish a solid foundation towards more efficient large-scale water desalination and other water treatment processes. PMID:26333385

Examination of water phase transitions in Loblolly pine and cell wall components by differential scanning calorimetry

Treesearch

Samuel L. Zelinka; Michael J. Lambrecht; Samuel V. Glass; Alex C. Wiedenhoeft; Daniel J. Yelle

2012-01-01

This paper examines phase transformations of water in wood and isolated wood cell wall components using differential scanning calorimetry with the purpose of better understanding "Type II water" or "freezable bound water" that has been reported for cellulose and other hydrophilic polymers. Solid loblolly pine (Pinus taeda...

Microfluidics with fluid walls.

PubMed

Walsh, Edmond J; Feuerborn, Alexander; Wheeler, James H R; Tan, Ann Na; Durham, William M; Foster, Kevin R; Cook, Peter R

2017-10-10

Microfluidics has great potential, but the complexity of fabricating and operating devices has limited its use. Here we describe a method - Freestyle Fluidics - that overcomes many key limitations. In this method, liquids are confined by fluid (not solid) walls. Aqueous circuits with any 2D shape are printed in seconds on plastic or glass Petri dishes; then, interfacial forces pin liquids to substrates, and overlaying an immiscible liquid prevents evaporation. Confining fluid walls are pliant and resilient; they self-heal when liquids are pipetted through them. We drive flow through a wide range of circuits passively by manipulating surface tension and hydrostatic pressure, and actively using external pumps. Finally, we validate the technology with two challenging applications - triggering an inflammatory response in human cells and chemotaxis in bacterial biofilms. This approach provides a powerful and versatile alternative to traditional microfluidics.The complexity of fabricating and operating microfluidic devices limits their use. Walsh et al. describe a method in which circuits are printed as quickly and simply as writing with a pen, and liquids in them are confined by fluid instead of solid walls.

Solid oxide fuel cell having monolithic core

DOEpatents

Ackerman, J.P.; Young, J.E.

1983-10-12

A solid oxide fuel cell is described for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick.

Laser Beam Failure Mode Effects and Analysis (FMEA) of the Solid State Heat Capacity Laser (SSHCL)

DOE Office of Scientific and Technical Information (OSTI.GOV)

King, J.

2015-09-07

A laser beam related FMEA of the SSHCL was performed to determine potential personnel and equipment safety issues. As part of the FMEA, a request was made to test a sample of the drywall material used for walls in the room for burn-through. This material was tested with a full power beam for five seconds. The surface paper material burned off and the inner calcium carbonate turned from white to brown. The result of the test is shown in the photo below.

Research on wall shear stress considering wall roughness when shear swirling flow vibration cementing

NASA Astrophysics Data System (ADS)

Cui, Zhihua; Ai, Chi; Feng, Fuping

2017-01-01

When shear swirling flow vibration cementing, the casing is revolving periodically and eccentrically, which leads to the annulus fluid in turbulent swirling flow state. The wall shear stress is more than that in laminar flow field when conventional cementing. The paper mainly studied the wall shear stress distribution on the borehole wall when shear swirling flow vibration cementing based on the finite volume method. At the same time, the wall roughness affected and changed the turbulent flow near the borehole wall and the wall shear stress. Based on the wall function method, the paper established boundary conditions considering the wall roughness and derived the formula of the wall shear stress. The results showed that the wall roughness significantly increases the wall shear stress. However, the larger the wall roughness, the greater the thickness of mud cake, which weakening the cementing strength. Considering the effects in a comprehensive way, it is discovered that the particle size of solid phase in drilling fluid is about 0.1 mm to get better cementing quality.

Cause and Cure-Deterioration in Accuracy of CFD Simulations with Use of High-Aspect-Ratio Triangular/Tetrahedral Grids

NASA Technical Reports Server (NTRS)

Chang, Sin-Chung; Chang, Chau-Lyan; Venkatachari, Balaji

2017-01-01

In the multi-dimensional space-time conservation element and solution element16 (CESE) method, triangles and tetrahedral mesh elements turn out to be the most natural building blocks for 2D and 3D spatial grids, respectively. As such, the CESE method is naturally compatible with the simplest 2D and 3D unstructured grids and thus can be easily applied to solve problems with complex geometries. However, because (a) accurate solution of a high-Reynolds number flow field near a solid wall requires that the grid intervals along the direction normal to the wall be much finer than those in a direction parallel to the wall and, as such, the use of grid cells with extremely high aspect ratio (103 to 106) may become mandatory, and (b) unlike quadrilateral hexahedral grids, it is well-known that accuracy of gradient computations involving triangular tetrahedral grids tends to deteriorate rapidly as cell aspect ratio increases. As a result, the use of triangular tetrahedral grid cells near a solid wall has long been deemed impractical by CFD researchers. In view of (a) the critical role played by triangular tetrahedral grids in the CESE development, and (b) the importance of accurate resolution of high-Reynolds number flow field near a solid wall, as will be presented in the main paper, a comprehensive and rigorous mathematical framework that clearly identifies the reasons behind the accuracy deterioration as described above has been developed for the 2D case involving triangular cells. By avoiding the pitfalls identified by the 2D framework, and its 3D extension, it has been shown numerically.

Ion-exchange hollow fibers

NASA Technical Reports Server (NTRS)

Rembaum, A.; Yen, S. P. S.; Klein, E. (Inventor)

1976-01-01

An ion-exchange hollow fiber is prepared by introducing into the wall of the fiber polymerizable liquid monomers, and polymerizing the monomers therein to form solid, insoluble, crosslinked, ion-exchange resin particles which embed in the wall of the fiber. Excess particles blocking the central passage or bore of the fiber are removed by forcing liquid through the fiber. The fibers have high ion-exchange capacity, a practical wall permeability and good mechanical strength even with very thin wall dimensions. Experimental investigation of bundles of ion-exchange hollow fibers attached to a header assembly have shown the fiber to be very efficient in removing counterions from solution.

A multilevel simulation approach to derive the slip boundary condition of the solid phase in two-fluid models

NASA Astrophysics Data System (ADS)

Feng, Zhi-Gang; Michaelides, Efstathios; Mao, Shaolin

2011-11-01

The simulation of particulate flows for industrial applications often requires the use of a two-fluid model (TFM), where the solid particles are considered as a separate continuous phase. One of the underlining uncertainties in the use of aTFM in multiphase computations comes from the boundary condition of the solid phase. The no-slip condition at a solid boundary is not a valid assumption for the solid phase. Instead, several researchers advocate a slip condition as a more appropriate boundary condition. However, the question on the selection of an exact slip length or a slip velocity coefficient is still unanswered. In the present work we propose a multilevel simulation approach to compute the slip length that is applicable to a TFM. We investigate the motion of a number of particles near a vertical solid wall, while the particles are in fluidization using a direct numerical simulation (DNS); the positions and velocities of the particles are being tracked and analyzed at each time step. It is found that the time- and vertical-space averaged values of the particle velocities converge, yielding velocity profiles that can be used to deduce the particle slip length close to a solid wall. This work was supported by a grant from the DOE-NETL (DE-NT0008064) and by a grant from NSF (HRD-0932339).

Active control of nanolitre droplet contents with convective concentration gradients across permeable walls.

PubMed

Zeitoun, Ramsey I; Goudie, Marcus J; Zwier, Jacob; Mahawilli, David; Burns, Mark A

2011-12-07

Nanolitre droplets in microfluidic devices can be used to perform thousands of independent chemical and biological experiments while minimizing reagents, cost and time. However, the absence of simple and versatile methods capable of controlling the contents of these nanolitre chemical systems limits their scientific potential. To address this, we have developed a method that is simple to fabricate and can continuously control nanolitre chemical systems by integrating a time-resolved convective flow signal across a permeable membrane wall. With this method, we can independently control the volume and concentration of nanolitre-sized drops without ever directly contacting the fluid. Transport occurring in these systems was also analyzed and thoroughly characterized. We achieved volumetric fluid introduction and removal rates ranging from 0.23 to 4.0 pL s(-1). Furthermore, we expanded this method to perform chemical processes. We precipitated silver chloride using a flow signal of sodium chloride and silver nitrate droplets. From there, we were able to separate sodium chloride reactants with a water flow signal, and dissolve silver chloride solids with an ammonia hydroxide flow signal. Finally, we demonstrate the potential to deliver large molecules and perform physical processes like crystallization and particle packing.

A knittable fiber-shaped supercapacitor based on natural cotton thread for wearable electronics

NASA Astrophysics Data System (ADS)

Zhou, Qianlong; Jia, Chunyang; Ye, Xingke; Tang, Zhonghua; Wan, Zhongquan

2016-09-01

At present, the topic of building high-performance, miniaturized and mechanically flexible energy storage modules which can be directly integrated into textile based wearable electronics is a hotspot in the wearable technology field. In this paper, we reported a highly flexible fiber-shaped electrode fabricated through a one-step convenient hydrothermal process. The prepared graphene hydrogels/multi-walled carbon nanotubes-cotton thread derived from natural cotton thread is electrochemically active and mechanically strong. Fiber-shaped supercapacitor based on the prepared fiber electrodes and polyvinyl alcohol-H3PO4 gel electrolyte exhibits good capacitive performance (97.73 μF cm-1 at scan rate of 2 mV s-1), long cycle life (95.51% capacitance retention after 8000 charge-discharge cycles) and considerable stability (90.75% capacitance retention after 500 continuous bending cycles). Due to its good mechanical and electrochemical properties, the graphene hydrogels/multi-walled carbon nanotubes-cotton thread based all-solid fiber-shaped supercapacitor can be directly knitted into fabrics and maintain its original capacitive performance. Such a low-cost textile thread based versatile energy storage device may hold great potential for future wearable electronics applications.

A One-Dimensional Global-Scaling Erosive Burning Model Informed by Blowing Wall Turbulence

NASA Technical Reports Server (NTRS)

Kibbey, Timothy P.

2014-01-01

A derivation of turbulent flow parameters, combined with data from erosive burning test motors and blowing wall tests results in erosive burning model candidates useful in one-dimensional internal ballistics analysis capable of scaling across wide ranges of motor size. The real-time burn rate data comes from three test campaigns of subscale segmented solid rocket motors tested at two facilities. The flow theory admits the important effect of the blowing wall on the turbulent friction coefficient by using blowing wall data to determine the blowing wall friction coefficient. The erosive burning behavior of full-scale motors is now predicted more closely than with other recent models.

Ultra-fast vapour-liquid-solid synthesis of Si nanowires using ion-beam implanted gallium as catalyst.

PubMed

Hetzel, Martin; Lugstein, Alois; Zeiner, Clemens; Wójcik, Tomasz; Pongratz, Peter; Bertagnolli, Emmerich

2011-09-30

The feasibility of gallium as a catalyst for vapour-liquid-solid (VLS) nanowire (NW) growth deriving from an implantation process in silicon by a focused ion beam (FIB) is investigated. Si(100) substrates are subjected to FIB implantation of gallium ions with various ion fluence rates. NW growth is performed in a hot wall chemical vapour deposition (CVD) reactor at temperatures between 400 and 500 °C with 2% SiH(4)/He as precursor gas. This process results in ultra-fast growth of (112)- and (110)-oriented Si-NWs with a length of several tens of micrometres. Further investigation by transmission electron microscopy indicates the presence of a NW core-shell structure: while the NW core yields crystalline structuring, the shell consists entirely of amorphous material.

Origin of melting point depression for rare gas solids confined in carbon pores

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morishige, Kunimitsu, E-mail: morishi@chem.ous.ac.jp; Kataoka, Takaaki

To obtain insights into the mechanism of the melting-point depression of rare gas solids confined in crystalline carbon pores, we examined the freezing and melting behavior of Xe and Ar confined to the crystalline pores of ordered mesoporous carbons as well as compressed exfoliated graphite compared to the amorphous pores of ordered mesoporous silicas, by means of X-ray diffraction. For the Xe and Ar confined to the crystalline carbon pores, there was no appreciable thermal hysteresis between freezing and melting. Furthermore, the position of the main diffraction peak did not change appreciably on freezing and melting. This strongly suggests thatmore » the liquids confined in the carbon pores form a multilayered structure parallel to the smooth walls. For the Xe and Ar confined to the amorphous silica pores, on the other hand, the position of the main diffraction peak shifted into higher scattering angle on freezing suggested that the density of the confined solid is distinctly larger than for the confined liquid. Using compressed exfoliated graphite with carbon walls of higher crystallinity, we observed that three-dimensional (3D) microcrystals of Xe confined in the slit-shaped pores melted to leave the unmelted bilayers on the pore walls below the bulk triple point. The lattice spacing of the 3D microcrystals confined is larger by ∼0.7% than that of the bilayer next to the pore walls in the vicinity of the melting point.« less

Analysis of close-contact melting with inner wall temperature variation in a horizontal cylindrical capsule

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saitoh, T.S.; Hoshi, Akira

1997-12-31

Melting and solidification of a phase change material (PCM) in a capsule is of practical importance in latent heat thermal energy storage (LHTES) systems which are considered to be very promising to reduce a peak demand of electricity in the summer season. Two melting modes are involved in melting in capsules. One is close-contact melting between the solid bulk and the capsule wall, and another is natural convection melting in the liquid region. In recent years, close-contact melting processes for a single enclosure have been solved using several numerical methods (e.g., Saitoh and Kato (1994)). However, there is no theoreticalmore » solution considering the inner wall temperature variation within cylindrical or spherical capsules. In this report close-contact melting heat transfer characteristics including melt flow in the liquid film under inner wall temperature distribution were analyzed and simple approximate equations are presented, which facilitates designing of the practical capsule bed LHTES systems. The effects of Stefan number and variable temperature profile etc. were clarified in detail. And the melting velocity of the solid bulk under various conditions was also studied theoretically. In addition, the effects of variable inner wall temperature on molten mass fraction were investigated.« less

Drag reduction induced by superhydrophobic surfaces in turbulent pipe flow

NASA Astrophysics Data System (ADS)

Costantini, Roberta; Mollicone, Jean-Paul; Battista, Francesco

2018-02-01

The drag reduction induced by superhydrophobic surfaces is investigated in a turbulent pipe flow. Wetted superhydrophobic surfaces are shown to trap gas bubbles in their asperities. This stops the liquid from coming in direct contact with the wall in that location, allowing the flow to slip over the air bubbles. We consider a well-defined texture with streamwise grooves at the walls in which the gas is expected to be entrapped. This configuration is modeled with alternating no-slip and shear-free boundary conditions at the wall. With respect to the classical turbulent pipe flow, a substantial drag reduction is observed which strongly depends on the grooves' dimension and on the solid fraction, i.e., the ratio between the solid wall surface and the total surface of the pipe's circumference. The drag reduction is due to the mean slip velocity at the wall which increases the flow rate at a fixed pressure drop. The enforced boundary conditions also produce peculiar turbulent structures which on the contrary decrease the flow rate. The two concurrent effects provide an overall flow rate increase as demonstrated by means of the mean axial momentum balance. This equation provides the balance between the mean pressure gradient, the Reynolds stress, the mean flow rate, and the mean slip velocity contributions.

Response of Solid He-4 to External Stress: Interdigital Capacitor Solid Level Detector and Optical Interferometer

NASA Technical Reports Server (NTRS)

Fay, J.; Wada, Y.; Masutomi, R.; Elkholy, T.; Kojima, H.

2003-01-01

Two experiments are being conducted to observe the liquid/solid interface of He-4 near 1 K. Interesting instabilities are expected to occur when the solid is non-hydrostatically stressed. (1)A compact interdigital capacitor is used as a level detector to observe solid He-4 to which stresses are applied externally. The capacitor consists of 38 interlaced 50 m wide and 3.8 mm long gold films separated by 50 m and deposited onto a 5 mm by 5 mm sapphire substrate. The capacitor is placed on one flat end wall of a cylindrical chamber (xx mm diameter and xx mm long). The solid is grown to a known height and a stress is applied by a tubular PZT along the cylindrical axis. The observed small change in height of the solid at the wall is linearly proportional to the applied stress. The solid height decreases under compressive stress but does not change under tensile stress. The response of the solid on compressive stress is consistent with the expected quadratic dependence on strain. (2)Interferometric techniques are being developed for observing the solid He-4 surface profile. A laser light source is brought into the low temperature region via single mode optical fiber. The interference pattern is transmitted back out of the low temperature apparatus via optical fiber bundle. The solid He-4 growth chamber will be equipped with two PZT's such that stress can be applied from orthogonal directions. Orthogonally applied stress is expected to induce surface instability with island-like deformation on a grid pattern. Apparatus design and progress of its construction are described.

Buckling of thin walled composite cylindrical shell filled with solid propellant

NASA Astrophysics Data System (ADS)

Dash, A. P.; Velmurugan, R.; Prasad, M. S. R.

2017-12-01

This paper investigates the buckling of thin walled composite cylindrical tubes that are partially filled with solid propellant equivalent elastic filler. Experimental investigation is conducted on thin composite tubes made out of S2-glass epoxy, which is made by using filament winding technique. The composite tubes are filled with elastic filler having similar mechanical properties as that of a typical solid propellant used in rocket motors. The tubes are tested for their buckling strength against the external pressure in the presence of the filler. Experimental data confirms the enhancement of external pressure carrying capacity of the composite tubes by up to three times as that of empty tubes for a volumetric loading fraction (VLF) of 0.9. Furthermore, the finite element based geometric nonlinearity analysis predicts the buckling behaviour of the partially filled composite tubes close to the experimental results.

Development of an improved model for runback water on aircraft surfaces

NASA Technical Reports Server (NTRS)

Al-Khalil, Kamel M.; Keith, Theo G., Jr.; De Witt, Kenneth J.

1992-01-01

A computer simulation for 'running wet' and evaporative aircraft anti-icing systems is developed. The model is based on the analysis of the liquid water film which forms in the regions of direct impingement and, then, breaks up near the impingement limits into rivulets. The wetness factor distribution resulting from the film breakup and the rivulet configuration on the surface are predicted using a stability analysis theory and the laws of mass energy conservation. The solid structure is modeled as a multiple layer wall. The anti-icing system modeled is of the thermal type utilizing hot air and/or electrical heating elements embedded within the wall layers. Experimental observations revealing some of the basic physics of the water flow on the surface are presented. Detailed qualitative documentation of the tests are given. Several numerical examples are considered, and the effect of some of the involved parameters on the system performance are investigated.

Improving Sorbents for Glycerol Capture in Biodiesel Refinement

PubMed Central

Johnson, Brandy J.; Melde, Brian J.; Moore, Martin H.; Malanoski, Anthony P.; Taft, Jenna R.

2017-01-01

Biodiesel is produced by transesterification of animal fat, vegetable oil, or waste cooking oil with alcohol. After production costs, the economic viability of biodiesel is dependent on what steps are necessary to remove impurities following synthesis and the effectiveness of quality control analysis. Solid-phase extraction offers a potentially advantageous approach in biodiesel processing applications. Nanoporous scaffolds were investigated for adsorption of glycerol, a side product of biodiesel synthesis that is detrimental to engine combustion when present. Materials were synthesized with varying pore wall composition, including ethane and diethylbenzene bridging groups, and sulfonated to promote hydrogen bonding interactions with glycerol. Materials bearing sulfonate groups throughout the scaffold walls as well as those post-synthetically grafted onto the surfaces show notably superior performance for uptake of glycerol. The sorbents are effective when used in biodiesel mixtures, removing greater than 90% of glycerol from a biodiesel preparation. PMID:28773042

Improving Sorbents for Glycerol Capture in Biodiesel Refinement.

PubMed

Johnson, Brandy J; Melde, Brian J; Moore, Martin H; Malanoski, Anthony P; Taft, Jenna R

2017-06-21

Biodiesel is produced by transesterification of animal fat, vegetable oil, or waste cooking oil with alcohol. After production costs, the economic viability of biodiesel is dependent on what steps are necessary to remove impurities following synthesis and the effectiveness of quality control analysis. Solid-phase extraction offers a potentially advantageous approach in biodiesel processing applications. Nanoporous scaffolds were investigated for adsorption of glycerol, a side product of biodiesel synthesis that is detrimental to engine combustion when present. Materials were synthesized with varying pore wall composition, including ethane and diethylbenzene bridging groups, and sulfonated to promote hydrogen bonding interactions with glycerol. Materials bearing sulfonate groups throughout the scaffold walls as well as those post-synthetically grafted onto the surfaces show notably superior performance for uptake of glycerol. The sorbents are effective when used in biodiesel mixtures, removing greater than 90% of glycerol from a biodiesel preparation.

Universal fuel basket for use with an improved oxide reduction vessel and electrorefiner vessel

DOEpatents

Herrmann, Steven D.; Mariani, Robert D.

2002-01-01

A basket, for use in the reduction of UO.sub.2 to uranium metal and in the electrorefining of uranium metal, having a continuous annulus between inner and outer perforated cylindrical walls, with a screen adjacent to each wall. A substantially solid bottom and top plate enclose the continuous annulus defining a fuel bed. A plurality of scrapers are mounted adjacent to the outer wall extending longitudinally thereof, and there is a mechanism enabling the basket to be transported remotely.

Method for storage of solid waste

DOEpatents

Mecham, William J.

1976-01-01

Metal canisters for long-term storage of calcined highlevel radioactive wastes can be made self-sealing against a breach in the canister wall by the addition of powdered cement to the canister with the calcine before it is sealed for storage. Any breach in the canister wall will permit entry of water which will mix with the cement and harden to form a concrete patch, thus sealing the opening in the wall of the canister and preventing the release of radioactive material to the cooling water or atmosphere.

Treatment of a unicameral bone cyst of calcaneus with endoscopic curettage and percutaneous filling with corticocancellous allograft.

PubMed

Yildirim, Cengiz; Mahiroğullari, Mahir; Kuşkucu, Mesih; Akmaz, Ibrahim; Keklikci, Kenan

2010-01-01

The surgical procedures for unicameral solitary calcaneal bone cysts have ranged from simple curettage and grafting to subperiosteal resection with internal fixation and grafting. In this article, an endoscopically assisted technique is proposed for the curettage of a simple calcaneal cyst that takes advantage of direct visualization of the cyst wall and contents and permits accurate assessment of the extent of the lesion. After curettage, percutaneous filling of the defect with corticocancellous allograft makes the technique a complete, minimally invasive surgical approach for this condition. The technique uses 2 lateral portals, one for viewing and the other for manipulation, both of which are created under fluoroscopic control. Once the cyst has been located, the 30 degrees arthroscope is used to evacuate fluid, after which more solid cyst contents are fragmented and removed. Thereafter, curettage of the inner surface of the cavernous cyst wall is performed. Finally, complete packing of the previously cystic cavity with crushed corticocancellous allograft is performed under endoscopic visualization and confirmed radiographically. Copyright 2010 American College of Foot and Ankle Surgeons. Published by Elsevier Inc. All rights reserved.

Combustion performance and scale effect from N2O/HTPB hybrid rocket motor simulations

NASA Astrophysics Data System (ADS)

Shan, Fanli; Hou, Lingyun; Piao, Ying

2013-04-01

HRM code for the simulation of N2O/HTPB hybrid rocket motor operation and scale effect analysis has been developed. This code can be used to calculate motor thrust and distributions of physical properties inside the combustion chamber and nozzle during the operational phase by solving the unsteady Navier-Stokes equations using a corrected compressible difference scheme and a two-step, five species combustion model. A dynamic fuel surface regression technique and a two-step calculation method together with the gas-solid coupling are applied in the calculation of fuel regression and the determination of combustion chamber wall profile as fuel regresses. Both the calculated motor thrust from start-up to shut-down mode and the combustion chamber wall profile after motor operation are in good agreements with experimental data. The fuel regression rate equation and the relation between fuel regression rate and axial distance have been derived. Analysis of results suggests improvements in combustion performance to the current hybrid rocket motor design and explains scale effects in the variation of fuel regression rate with combustion chamber diameter.

Numerical slope stability simulations of chasma walls in Valles Marineris/Mars using a distinct element method (dem).

NASA Astrophysics Data System (ADS)

Imre, B.

2003-04-01

NUMERICAL SLOPE STABILITY SIMULATIONS OF CHASMA WALLS IN VALLES MARINERIS/MARS USING A DISTINCT ELEMENT METHOD (DEM). B. Imre (1) (1) German Aerospace Center, Berlin Adlershof, bernd.imre@gmx.net The 8- to 10-km depths of Valles Marineris (VM) offer excellent views into the upper Martian crust. Layering, fracturing, lithology, stratigraphy and the content of volatiles have influenced the evolution of the Valles Marineris wallslopes. But these parameters also reflect the development of VM and its wall slopes. The scope of this work is to gain understanding in these parameters by back-simulating the development of wall slopes. For that purpose, the two dimensional Particle Flow Code PFC2D has been chosen (ITASCA, version 2.00-103). PFC2D is a distinct element code for numerical modelling of movements and interactions of assemblies of arbitrarily sized circular particles. Particles may be bonded together to represent a solid material. Movements of particles are unlimited. That is of importance because results of open systems with numerous unknown variables are non-unique and therefore highly path dependent. This DEM allows the simulation of whole development paths of VM walls what makes confirmation of the model more complete (e.g. Oreskes et al., Science 263, 1994). To reduce the number of unknown variables a proper (that means as simple as possible) field-site had to be selected. The northern wall of eastern Candor Chasma has been chosen. This wall is up to 8-km high and represents a significant outcrop of the upper Martian crust. It is quite uncomplex, well-aligned and of simple morphology. Currently the work on the model is at the stage of performing the parameter study. Results will be presented via poster by the EGS-Meeting.

Peptidoglycan and Teichoic Acid Levels and Alterations in Staphylococcus aureus by Cell-Wall and Whole-Cell Nuclear Magnetic Resonance.

PubMed

Romaniuk, Joseph A H; Cegelski, Lynette

2018-06-11

Gram-positive bacteria surround themselves with a multilayered macromolecular cell wall that is essential to cell survival and serves as a major target for antibiotics. The cell wall of Staphylococcus aureus is composed of two major structural components, peptidoglycan (PG) and wall teichoic acid (WTA), together creating a heterogeneous and insoluble matrix that poses a challenge to quantitative compositional analysis. Here, we present 13 C cross polarization magic angle spinning solid-state nuclear magnetic resonance (NMR) spectra of intact cell walls, purified PG, and purified WTA. The spectra reveal the clear molecular differences in the two polymers and enable quantification of PG and WTA in isolated cell walls, an attractive alternative to estimating teichoic acid content from a phosphate analysis of completely pyrolyzed cell walls. Furthermore, we discovered that unique PG and WTA spectral signatures could be identified in whole-cell NMR spectra and used to compare PG and WTA levels among intact bacterial cell samples. The distinguishing whole-cell 13 C NMR contributions associated with PG include the GlcNAc-MurNAc sugar carbons and glycyl α-carbons. WTA contributes carbons from the phosphoribitol backbone. Distinguishing 15 N spectral signatures include glycyl amide nitrogens in PG and the esterified d-alanyl amine nitrogens in WTA. 13 C NMR analysis was performed with samples at natural abundance and included 10 whole-cell sample comparisons. Changes consistent with altered PG and WTA content were detected in whole-cell spectra of bacteria harvested at different growth times and in cells treated with tunicamycin. This use of whole-cell NMR provides quantitative parameters of composition in the context of whole-cell activity.

Performance enhancement of fin attached ice-on-coil type thermal storage tank for different fin orientations using constrained and unconstrained simulations

NASA Astrophysics Data System (ADS)

Kim, M. H.; Duong, X. Q.; Chung, J. D.

2017-03-01

One of the drawbacks in latent thermal energy storage system is the slow charging and discharging time due to the low thermal conductivity of the phase change materials (PCM). This study numerically investigated the PCM melting process inside a finned tube to determine enhanced heat transfer performance. The influences of fin length and fin numbers were investigated. Also, two different fin orientations, a vertical and horizontal type, were examined, using two different simulation methods, constrained and unconstrained. The unconstrained simulation, which considers the density difference between the solid and liquid PCM showed approximately 40 % faster melting rate than that of constrained simulation. For a precise estimation of discharging performance, unconstrained simulation is essential. Thermal instability was found in the liquid layer below the solid PCM, which is contrary to the linear stability theory, due to the strong convection driven by heat flux from the coil wall. As the fin length increases, the area affected by the fin becomes larger, thus the discharging time becomes shorter. The discharging performance also increased as the fin number increased, but the enhancement of discharging performance by more than two fins was not discernible. The horizontal type shortened the complete melting time by approximately 10 % compared to the vertical type.

nPIV velocity measurement of nanofluids in the near-wall region of a microchannel.

PubMed

Anoop, Kanjirakat; Sadr, Reza

2012-05-31

Colloidal suspensions of nano-sized particles in a base fluid, nanofluids, have recently gained popularity as cooling fluids mainly due to their enhanced heat transfer capabilities. However, there is controversy in the literature on the reported properties of nanofluids and their applicability, especially since there is no fundamental understanding that explains these enhancements. A better understanding of these fluids and how they interact with a solid boundary may be achieved by a detailed near-wall fluid flow study at nanoscale. This work presents for the first time the near-wall velocity measurements for nanofluids using nanoparticle image velocimetry. This novel technique uses evanescent illumination in the solid-fluid interface to measure near-wall velocity field with an out-of-plane resolution on the order of O(100 nm). Nanofluids of different concentrations were prepared by dispersing silicon dioxide particles (10 to 20 nm) in water as the base fluid. Initially, viscosity measurements were conducted for the prepared nanofluids. The near-wall velocity data were then measured and compared with that of the base fluid at the same flow condition. It was observed that even though nanofluid viscosity had increased with particle loading, the near-wall velocity values were similar to that of the base fluid for a given flow rate. Together, these measurements vindicate the homogenous and Newtonian characteristics of the nanofluids in the near-wall region. Despite the low particle concentrations investigated, the present work also discusses the complexity involved in utilizing the methodology and possible errors arising during experimentation so as to implement this measurement tool more effectively in the future.

Influence of the solid dielectric over the electric field from the ozone cell gap with double dielectric barrier

NASA Astrophysics Data System (ADS)

Ganea, I.

2017-05-01

The distilled water has the advantage of high value dielectric constant (ε = 81) in relation to ceramic glass materials, currently used for constructing the dielectric barrier. It was necessary to build a thin-walled enclosure of solid insulating material that contain distilled water to achieve a dielectric barrier. This was necessary to avoid exposing the liquid to the direct action of ozone. Dielectric permittivity of the solid dielectric material and the thickness of these walls have diminished the value of the electric field form the gaseous gap of the ozone cell compared to the case with the dielectric barrier from distilled water. The author of this work deduced theoretical relationships that express the values of the electric field intensity in the gap of the cell with two dielectrics and compared them with similar relationships of the intensity of the electric field from the gap of the ozone cell with one dielectric. In this work the author presenting experimental results which confirm the theoretical deducting regarding the use of the solid dielectric as enclosure for the liquid dielectric.

Ionic Liquid-Mediated Multi-Walled Carbon Nanotube-Polydimethylsiloxane Fiber for Headspace Solid-Phase Microextraction of Phenolic Compounds in Aqueous Samples by Gas Chromatography Coupled to Flame Ionization Detector.

PubMed

Sadri, Minoo; Vatani, Hossein

2017-02-01

An ionic liquid-mediated multi-walled carbon nanotube (MWCNT)-polydimethylsiloxane (PDMS) sorbent was developed for headspace solid-phase microextraction (HS-SPME) of phenolic compounds from human urine samples. Sol-gel method was used to prepare this sorbent. For this purpose, MWCNTs were functionalized covalently and were attached chemically to the hydroxyl-terminated PDMS. Prepared fiber showed high thermal stability (over than 320°C) and good lifespan (>210 times). These good performances can be attributed to the performance of carbon nanotubes and sol-gel method. Affecting parameters on the efficiency of HS-SPME were investigated and optimized. Under the optimal conditions, linear dynamic ranges were observed over a range of 0.002-200 ng mL -1 with limits of detection from 0.0005 to 0.005 ng mL -1 and limits of quantitation between 0.002 and 0.02 ng mL -1 The relative standard deviations for one fiber (repeatability) (n = 5) at three different concentrations (0.05, 2 and 100 ng mL -1 ) were obtained from 4.6 up to 6.7% and between fibers or batch to batch (n = 3) (reproducibility) in the range of 5.7-7.8%. Urine samples were used as real samples. All real samples were spiked at 0.5 ng mL -1 of understudy analytes and the relative recovery percentages obtained from 90.7 to 102.1%. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Ion-exchange hollow fibers

NASA Technical Reports Server (NTRS)

Rembaum, Alan (Inventor); Yen, Shiao-Ping S. (Inventor); Klein, Elias (Inventor)

1980-01-01

An ion-exchange hollow fiber is prepared by introducing into the wall of the fiber polymerizable liquid monomers, and polymerizing the monomers therein to form solid, insoluble, cross-linked, ion-exchange resin particles which embed in the wall of the fiber. Excess particles blocking the central passage or bore of the fiber are removed by forcing liquid through the fiber. The fibers have high ion-exchange capacity, a practical wall permeability and good mechanical strength even with very thin wall dimensions. Experimental investigation of bundles of ion-exchange hollow fibers attached to a header assembly have shown the fiber to be very efficient in removing counterions from solution.

Ion-exchange hollow fibers

NASA Technical Reports Server (NTRS)

Rembaum, Alan (Inventor); Yen, Shiao-Ping S. (Inventor); Klein, Elias (Inventor)

1977-01-01

An ion-exchange hollow fiber is prepared by introducing into the wall of the fiber polymerizable liquid monomers, and polymerizing the monomers therein to form solid, insoluble, cross-linked, ion-exchange resin particles which embed in the wall of the fiber. Excess particles blocking the central passage or bore of the fiber are removed by forcing liquid through the fiber. The fibers have high ion-exchange capacity, a practical wall permeability and good mechanical strength even with very thin wall dimensions. Experimental investigation of bundles of ion-exchange hollow fibers attached to a header assembly have shown the fiber to be very efficient in removing counterions from solution.

Calibration of the 13- by 13-inch adaptive wall test section for the Langley 0.3-meter transonic cryogenic tunnel

NASA Technical Reports Server (NTRS)

Mineck, Raymond E.; Hill, Acquilla S.

1990-01-01

A 13 by 13 inch adaptive wall test section was installed in the 0.3 Meter Transonic Cryogenic Tunnel circuit. This new test section is configured for 2-D airfoil testing. It has four solid walls. The top and bottom walls are flexible and movable whereas the sidewalls are rigid and fixed. The wall adaptation strategy employed requires the test section wall shapes associated with uniform test section Mach number distributions. Calibration tests with the test section empty were conducted with the top and bottom walls linearly diverged to approach a uniform Mach number distribution. Pressure distributions were measured in the contraction cone, the test section, and the high speed diffuser at Mach numbers from 0.20 to 0.95 and Reynolds numbers from 10 to 100 x 10 (exp 6)/per foot.

Investigation of erosion behavior in different pipe-fitting using Eulerian-Lagrangian approach

NASA Astrophysics Data System (ADS)

Kulkarni, Harshwardhan; Khadamkar, Hrushikesh; Mathpati, Channamallikarjun

2017-11-01

Erosion is a wear mechanism of piping system in which wall thinning occurs because of turbulent flow along with along with impact of solid particle on the pipe wall, because of this pipe ruptures causes costly repair of plant and personal injuries. In this study two way coupled Eulerian-Lagrangian approach is used to solve the liquid solid (water-ferrous suspension) flow in the different pipe fitting namely elbow, t-junction, reducer, orifice and 50% open gate valve. Simulations carried out using incomressible transient solver in OpenFOAM for different Reynolds's number (10k, 25k, 50k) and using WenYu drag model to find out possible higher erosion region in pipe fitting. Used transient solver is a hybrid in nature which is combination of Lagrangian library and pimpleFoam. Result obtained from simulation shows that exit region of elbow specially downstream of straight, extradose of the bend section more affected by erosion. Centrifugal force on solid particle at bend affect the erosion behavior. In case of t-junction erosion occurs below the locus of the projection of branch pipe on the wall. For the case of reducer, orifice and a gate valve reduction area as well as downstream is getting more affected by erosion because of increase in velocities.

Numerical simulation of gas-phonon coupling in thermal transpiration flows.

PubMed

Guo, Xiaohui; Singh, Dhruv; Murthy, Jayathi; Alexeenko, Alina A

2009-10-01

Thermal transpiration is a rarefied gas flow driven by a wall temperature gradient and is a promising mechanism for gas pumping without moving parts, known as the Knudsen pump. Obtaining temperature measurements along capillary walls in a Knudsen pump is difficult due to extremely small length scales. Meanwhile, simplified analytical models are not applicable under the practical operating conditions of a thermal transpiration device, where the gas flow is in the transitional rarefied regime. Here, we present a coupled gas-phonon heat transfer and flow model to study a closed thermal transpiration system. Discretized Boltzmann equations are solved for molecular transport in the gas phase and phonon transport in the solid. The wall temperature distribution is the direct result of the interfacial coupling based on mass conservation and energy balance at gas-solid interfaces and is not specified a priori unlike in the previous modeling efforts. Capillary length scales of the order of phonon mean free path result in a smaller temperature gradient along the transpiration channel as compared to that predicted by the continuum solid-phase heat transfer. The effects of governing parameters such as thermal gradients, capillary geometry, gas and phonon Knudsen numbers and, gas-surface interaction parameters on the efficiency of thermal transpiration are investigated in light of the coupled model.

A comparison of the mechanical and sensory properties of baked and extruded confectionery products

NASA Astrophysics Data System (ADS)

Butt, Saba; Charalambides, Maria; Mohammed, Idris K.; Powell, Hugh

2017-10-01

Traditional baking is the most common way of producing confectionery wafers, however over the past few decades, the extrusion process has become an increasingly important food manufacturing method and is commonly used in the manufacturing of breakfast cereals and filled snack products. This study aims to characterise products made via each of these manufacturing processes in order to understand the important parameters involved in the resulting texture of confectionery products such as wafers. Both of the named processes result in brittle, cellular foams comprising of cell walls and cell pores which may contain some of the confectionery filling. The mechanical response of the cell wall material and the geometry of the products influence the consumer perception and preference. X-Ray micro tomography (XRT) was used to generate geometry of the microstructure which was then fed to Finite Element (FE) for numerical analysis on both products. The FE models were used to determine properties such as solid modulus of the cell walls, Young's modulus of the entire foam and to investigate and compare the microstructural damage of baked wafers and extruded products. A sensory analysis study was performed on both products by a qualified sensory panel. The results of this study were then used to draw links between the mechanical behaviour and sensory perception of a consumer. The extruded product was found to be made up of a stiffer solid material and had a higher compressive modulus and fracture stress when compared to the baked wafer. The sensory panel observed textural differences between the baked and extruded products which were also found in the differences of the mechanical properties of the two products.

The Lattice Dynamics of Colloidal Crystals.

NASA Astrophysics Data System (ADS)

Hurd, Alan James

Colloidal crystals are ordered arrays of highly charged microspheres in water that exhibit spectacular optical diffraction effects by virtue of a large lattice parameter. The microspheres perform Brownian motion that is influenced by the interparticle and fluid forces. The purpose of this study was to understand the nature of the collective motions in colloidal crystals in terms of classical lattice dynamics. In the theoretical analysis, the particle displacements due to Brownian motion were formally decomposed into phonon -like lattice disturbances analogous to the phonons in atomic and molecular solids except that they are heavily damped. The analysis was based on a harmonic solid model with special attention paid to the hydrodynamic interaction between particles. A hydrodynamic model using the Oseen interaction was worked for a three-dimensional lattice but it failed in two important respects: it overestimated the friction factor for long wavelength modes and did not predict a previously observed propagating transverse mode. Both of these failures were corrected by a hydrodynamic model based on periodic solutions to the Stokes equation. In addition, the effects of fluid inertia and constraining walls were considered. Intensity autocorrelation spectroscopy was used to probe the lattice dynamics by measuring the phonon dispersion curves. A thin-film cell was used to reduce multiple scattering to acceptable levels. An experiment to measure wall effects on Brownian motion was necessary to determine the decrease in diffusion rate inherent in the thin-film geometry. The wall effects were found to agree with macroscopic hydrodynamics. An additional experiment measured the elastic anisotropy of the crystal lattice from the thermal diffuse scattering. The theoretical dispersion curves were found to agree well with the measured curves.

Modeling Heat Loss through Piston and Effects of Thermal Boundary Coatings in Diesel Engine Simulations using Conjugate Heat Transfer models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kundu, Prithwish; Scarcelli, Riccardo; Som, Sibendu

Heat loss through wall boundaries play a dominant role in the overall performance and efficiency of internal combustion engines. Typical engine simulations use constant temperature wall boundary conditions. These boundary conditions cannot be estimated accurately from experiments due to the complexities involved with engine combustion. As a result they introduce a large uncertainty in engine simulations and serve as a tuning parameter. Modeling the process of heat transfer through the solid walls in an unsteady engine computational fluid dynamics (CFD) simulation can lead to the development of higher fidelity engine calculations. These models can be used to study the impactmore » of heat loss on engine efficiency and explore new design methodologies that can reduce heat losses. In this work, a single cylinder diesel engine is modeled along with the solid piston coupled to the fluid domain. Conjugate heat transfer (CHT) modeling techniques were implemented to model heat losses for a full cycle of a Navistar diesel engine. This CFD model is then validated against experimental data available from thermocouples embedded inside the piston surface. The overall predictions from the model match closely with the experimental observations. The validated model is further used to explore the benefits of thermal barrier coatings (TBC) on piston bowls. The effect of TBC coatings were modeled as a thermal resistance in the heat transfer models. Full cycle 3D engine simulations provide quantitative insights into heat loss and thus calculate the efficiency gain by the use of TBC coatings. The work establishes a validated modeling framework for CHT modeling in reciprocating engine simulations.« less

Parametric Thermal and Flow Analysis of ITER Diagnostic Shield Module

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khodak, A.; Zhai, Y.; Wang, W.

As part of the diagnostic port plug assembly, the ITER Diagnostic Shield Module (DSM) is designed to provide mechanical support and the plasma shielding while allowing access to plasma diagnostics. Thermal and hydraulic analysis of the DSM was performed using a conjugate heat transfer approach, in which heat transfer was resolved in both solid and liquid parts, and simultaneously, fluid dynamics analysis was performed only in the liquid part. ITER Diagnostic First Wall (DFW) and cooling tubing were also included in the analysis. This allowed direct modeling of the interface between DSM and DFW, and also direct assessment of themore » coolant flow distribution between the parts of DSM and DFW to ensure DSM design meets the DFW cooling requirements. Design of the DSM included voids filled with Boron Carbide pellets, allowing weight reduction while keeping shielding capability of the DSM. These voids were modeled as a continuous solid with smeared material properties using analytical relation for thermal conductivity. Results of the analysis lead to design modifications improving heat transfer efficiency of the DSM. Furthermore, the effect of design modifications on thermal performance as well as effect of Boron Carbide will be presented.« less

Parametric Thermal and Flow Analysis of ITER Diagnostic Shield Module

DOE PAGES

Khodak, A.; Zhai, Y.; Wang, W.; ...

2017-06-19

As part of the diagnostic port plug assembly, the ITER Diagnostic Shield Module (DSM) is designed to provide mechanical support and the plasma shielding while allowing access to plasma diagnostics. Thermal and hydraulic analysis of the DSM was performed using a conjugate heat transfer approach, in which heat transfer was resolved in both solid and liquid parts, and simultaneously, fluid dynamics analysis was performed only in the liquid part. ITER Diagnostic First Wall (DFW) and cooling tubing were also included in the analysis. This allowed direct modeling of the interface between DSM and DFW, and also direct assessment of themore » coolant flow distribution between the parts of DSM and DFW to ensure DSM design meets the DFW cooling requirements. Design of the DSM included voids filled with Boron Carbide pellets, allowing weight reduction while keeping shielding capability of the DSM. These voids were modeled as a continuous solid with smeared material properties using analytical relation for thermal conductivity. Results of the analysis lead to design modifications improving heat transfer efficiency of the DSM. Furthermore, the effect of design modifications on thermal performance as well as effect of Boron Carbide will be presented.« less

Additive erosion reduction influences in the turbulent boundary layer

NASA Astrophysics Data System (ADS)

Buckingham, A. C.

1981-05-01

Results of a sequence of flow, heat and mass transfer calculations are presented which theoretically characterize the erosive environment at the wall surface of refractory metal coated and uncoated gun barrels. The theoretical results include analysis of the wall surface temperature, heat flux, and shear stress time histories on thin (10 mil.) Cr, Mo, Nb, and Ta plated steel barrel walls as uncoated steel walls. The calculations combine effects of a number of separate processes which were previously (and purposely) studied individually. These include solid particle additive concentrations, gas wall thermochemical influences, and transient turbulent wall boundary layer flow with multicomponent molecular diffusion and reactions from interaction of propellant combustion and the eroding surface. The boundary layer model includes particulate additive concentrations as well as propellant combustion products, considered for the present to be in the local thermochemical equilibrium.

A conserved fungal glycosyltransferase facilitates pathogenesis of plants by enabling hyphal growth on solid surfaces

PubMed Central

Plummer, Amy; Halsey, Kirstie; Lovegrove, Alison; Hammond-Kosack, Kim

2017-01-01

Pathogenic fungi must extend filamentous hyphae across solid surfaces to cause diseases of plants. However, the full inventory of genes which support this is incomplete and many may be currently concealed due to their essentiality for the hyphal growth form. During a random T-DNA mutagenesis screen performed on the pleomorphic wheat (Triticum aestivum) pathogen Zymoseptoria tritici, we acquired a mutant unable to extend hyphae specifically when on solid surfaces. In contrast “yeast-like” growth, and all other growth forms, were unaffected. The inability to extend surface hyphae resulted in a complete loss of virulence on plants. The affected gene encoded a predicted type 2 glycosyltransferase (ZtGT2). Analysis of >800 genomes from taxonomically diverse fungi highlighted a generally widespread, but discontinuous, distribution of ZtGT2 orthologues, and a complete absence of any similar proteins in non-filamentous ascomycete yeasts. Deletion mutants of the ZtGT2 orthologue in the taxonomically un-related fungus Fusarium graminearum were also severely impaired in hyphal growth and non-pathogenic on wheat ears. ZtGT2 expression increased during filamentous growth and electron microscopy on deletion mutants (ΔZtGT2) suggested the protein functions to maintain the outermost surface of the fungal cell wall. Despite this, adhesion to leaf surfaces was unaffected in ΔZtGT2 mutants and global RNAseq-based gene expression profiling highlighted that surface-sensing and protein secretion was also largely unaffected. However, ΔZtGT2 mutants constitutively overexpressed several transmembrane and secreted proteins, including an important LysM-domain chitin-binding virulence effector, Zt3LysM. ZtGT2 likely functions in the synthesis of a currently unknown, potentially minor but widespread, extracellular or outer cell wall polysaccharide which plays a key role in facilitating many interactions between plants and fungi by enabling hyphal growth on solid matrices. PMID:29020037

Solid-state selective (13)C excitation and spin diffusion NMR to resolve spatial dimensions in plant cell walls.

PubMed

Foston, Marcus; Katahira, Rui; Gjersing, Erica; Davis, Mark F; Ragauskas, Arthur J

2012-02-15

The average spatial dimensions between major biopolymers within the plant cell wall can be resolved using a solid-state NMR technique referred to as a (13)C cross-polarization (CP) SELDOM (selectively by destruction of magnetization) with a mixing time delay for spin diffusion. Selective excitation of specific aromatic lignin carbons indicates that lignin is in close proximity to hemicellulose followed by amorphous and finally crystalline cellulose. (13)C spin diffusion time constants (T(SD)) were extracted using a two-site spin diffusion theory developed for (13)C nuclei under magic angle spinning (MAS) conditions. These time constants were then used to calculate an average lower-limit spin diffusion length between chemical groups within the plant cell wall. The results on untreated (13)C enriched corn stover stem reveal that the lignin carbons are, on average, located at distances ∼0.7-2.0 nm from the carbons in hemicellulose and cellulose, whereas the pretreated material had larger separations.

Fluid-dynamically coupled solid propellant combustion instability - cold flow simulation

NASA Astrophysics Data System (ADS)

Ben-Reuven, M.

1983-10-01

The near-wall processes in an injected, axisymmetric, viscous flow is examined. Solid propellant rocket instability, in which cold flow simulation is evaluated as a tool to elucidate possible instability driving mechanisms is studied. One such prominent mechanism seems to be visco-acoustic coupling. The formulation is presented in terms of a singular boundary layer problem, with detail (up to second order) given only to the near wall region. The injection Reynolds number is assumed large, and its inverse square root serves as an appropriate small perturbation quantity. The injected Mach number is also small, and taken of the same order as the aforesaid small quantity. The radial-dependence of the inner solutions up to second order is solved, in polynominal form. This leaves the (x,t) dependence to much simpler partial differential equations. Particular results demonstrate the existence of a first order pressure perturbation, which arises due to the dissipative near wall processes. This pressure and the associated viscous friction coefficient are shown to agree very well with experimental injected flow data.

Folding of xylan onto cellulose fibrils in plant cell walls revealed by solid-state NMR

NASA Astrophysics Data System (ADS)

Simmons, Thomas J.; Mortimer, Jenny C.; Bernardinelli, Oigres D.; Pöppler, Ann-Christin; Brown, Steven P.; Deazevedo, Eduardo R.; Dupree, Ray; Dupree, Paul

2016-12-01

Exploitation of plant lignocellulosic biomass is hampered by our ignorance of the molecular basis for its properties such as strength and digestibility. Xylan, the most prevalent non-cellulosic polysaccharide, binds to cellulose microfibrils. The nature of this interaction remains unclear, despite its importance. Here we show that the majority of xylan, which forms a threefold helical screw in solution, flattens into a twofold helical screw ribbon to bind intimately to cellulose microfibrils in the cell wall. 13C solid-state magic-angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy, supported by in silico predictions of chemical shifts, shows both two- and threefold screw xylan conformations are present in fresh Arabidopsis stems. The twofold screw xylan is spatially close to cellulose, and has similar rigidity to the cellulose microfibrils, but reverts to the threefold screw conformation in the cellulose-deficient irx3 mutant. The discovery that induced polysaccharide conformation underlies cell wall assembly provides new principles to understand biomass properties.

Folding of xylan onto cellulose fibrils in plant cell walls revealed by solid-state NMR.

PubMed

Simmons, Thomas J; Mortimer, Jenny C; Bernardinelli, Oigres D; Pöppler, Ann-Christin; Brown, Steven P; deAzevedo, Eduardo R; Dupree, Ray; Dupree, Paul

2016-12-21

Exploitation of plant lignocellulosic biomass is hampered by our ignorance of the molecular basis for its properties such as strength and digestibility. Xylan, the most prevalent non-cellulosic polysaccharide, binds to cellulose microfibrils. The nature of this interaction remains unclear, despite its importance. Here we show that the majority of xylan, which forms a threefold helical screw in solution, flattens into a twofold helical screw ribbon to bind intimately to cellulose microfibrils in the cell wall. 13 C solid-state magic-angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy, supported by in silico predictions of chemical shifts, shows both two- and threefold screw xylan conformations are present in fresh Arabidopsis stems. The twofold screw xylan is spatially close to cellulose, and has similar rigidity to the cellulose microfibrils, but reverts to the threefold screw conformation in the cellulose-deficient irx3 mutant. The discovery that induced polysaccharide conformation underlies cell wall assembly provides new principles to understand biomass properties.

Hysteresis of the Contact Angle of a Meniscus Inside a Capillary with Smooth, Homogeneous Solid Walls.

PubMed

Kuchin, Igor V; Starov, Victor M

2016-05-31

A theory of contact angle hysteresis of a meniscus inside thin capillaries with smooth, homogeneous solid walls is developed in terms of surface forces (disjoining/conjoining pressure isotherm) using a quasi-equilibrium approach. The disjoining/conjoining pressure isotherm includes electrostatic, intermolecular, and structural components. The values of the static receding θr, advancing θa, and equilibrium θe contact angles in thin capillaries were calculated on the basis of the shape of the disjoining/conjoining pressure isotherm. It was shown that both advancing and receding contact angles depend on the capillary radius. The suggested mechanism of the contact angle hysteresis has a direct experimental confirmation: the process of receding is accompanied by the formation of thick β-films on the capillary walls. The effect of the transition from partial to complete wetting in thin capillaries is predicted and analyzed. This effect takes place in very thin capillaries, when the receding contact angle decreases to zero.

Effects of cell wall components on the functionality of wheat gluten.

PubMed

Autio, K

2006-01-01

Normal white wheat flours and especially whole meal flour contain solids from the inner endosperm cell walls, from germ, aleurone layer and the outer layers of cereal grains. These solids can prevent either gluten formation or gas cell structure. The addition of small amounts of pericarp layers (1-2%) to wheat flour had a marked detrimental effect on loaf volume. Microstructural studies indicated that in particular the epicarp hairs appeared to disturb the gas cell structure. The detrimental effects of insoluble cell walls can be prevented by using endoxylanases. It has been shown that some oxidative enzymes, naturally present in flour or added to the dough, will oxidise water-extractable arabinoxylans via ferulic acid bridges, and the resulting arabinoxylan gel will hinder gluten formation. The negative effects of water-unextractable arabinoxylans on gluten yield and rheological properties can be compensated by the addition of ferulic acid. Free ferulic acid can probably prevent arabinoxylan cross-linking via ferulic acid.

Sedimentation of a sphere in a fluid channel

NASA Astrophysics Data System (ADS)

Pitois, Olivier; Fritz, Christelle; Pasol, Laurentiu; Vignes-Adler, Michèle

2009-10-01

We studied both experimentally and numerically the sedimentation velocity of small solid particles through liquid channels merging at the intersection of three soap films. The wall mobility induces a nontrivial behavior for the particle drag coefficient, providing particular transport properties that are not observed for channels with rigid walls. It is shown that for sufficiently small particles, slow and fast motions are observed for the particle along the channel, depending on the particle position within the channel cross section and the sphere/channel size ratio. The velocity corresponding to fast motions can be as high as twice the Stokes velocity in an unbounded fluid. Moreover, the fast motions are not observed anymore when the size ratio exceeds a critical value, which has been found to be approximately equal to 0.5. As another major difference with the solid wall channel, the sphere velocity does not vanish when the size ratio reaches unity. Instead, the smallest value is found to be 1/4 of the Stokes velocity.

Solid-State (13)C NMR Delineates the Architectural Design of Biopolymers in Native and Genetically Altered Tomato Fruit Cuticles.

PubMed

Chatterjee, Subhasish; Matas, Antonio J; Isaacson, Tal; Kehlet, Cindie; Rose, Jocelyn K C; Stark, Ruth E

2016-01-11

Plant cuticles on outer fruit and leaf surfaces are natural macromolecular composites of waxes and polyesters that ensure mechanical integrity and mitigate environmental challenges. They also provide renewable raw materials for cosmetics, packaging, and coatings. To delineate the structural framework and flexibility underlying the versatile functions of cutin biopolymers associated with polysaccharide-rich cell-wall matrices, solid-state NMR spectra and spin relaxation times were measured in a tomato fruit model system, including different developmental stages and surface phenotypes. The hydrophilic-hydrophobic balance of the cutin ensures compatibility with the underlying polysaccharide cell walls; the hydroxy fatty acid structures of outer epidermal cutin also support deposition of hydrophobic waxes and aromatic moieties while promoting the formation of cell-wall cross-links that rigidify and strengthen the cuticle composite during fruit development. Fruit cutin-deficient tomato mutants with compromised microbial resistance exhibit less efficient local and collective biopolymer motions, stiffening their cuticular surfaces and increasing their susceptibility to fracture.

Nano Liquid Crystal Droplet Impact on Solid Surfaces

NASA Astrophysics Data System (ADS)

Zhang, Rui; de Pablo, Juan; dePablo Team

2015-03-01

Liquid droplet impaction on solid surfaces is an important problem with a wide range of applications in everyday life. Liquid crystals (LCs) are anisotropic liquids whose internal structure gives rise to rich optical and morphological phenomena. In this work we study the liquid crystal droplet impaction on solid surfaces by molecular dynamics simulations. We employ a widely used Gay-Berne model to describe the elongated liquid crystal molecules and their interactions. Our work shows that, in contrast to isotropic liquids, drop deformation is symmetric unless an instability kicks in, in which case a nano scale liquid crystal droplet exhibits distinct anisotropic spreading modes that do not occur in simple liquids. The drop prefers spreading along the low viscosity direction, but inertia can in some cases overcome that bias. The effects of the director field of the droplet, preferred anchoring direction and the anchoring strength of the wall are investigated. Large scale (0.1 micron) simulations are performed to connect our nano scale results to the experiments. Our studies indicate that LCs could provide an interesting alternative for development of next-generation printing inks.

A theoretical evaluation of aluminum gel propellant two-phase flow losses on vehicle performance

NASA Technical Reports Server (NTRS)

Mueller, Donn C.; Turns, Stephen R.

1993-01-01

A one-dimensional model of a hydrocarbon/Al/O2(gaseous) fueled rocket combustion chamber was developed to study secondary atomization effects on propellant combustion. This chamber model was coupled with a two dimensional, two-phase flow nozzle code to estimate the two-phase flow losses associated with solid combustion products. Results indicate that moderate secondary atomization significantly reduces propellant burnout distance and Al2O3 particle size; however, secondary atomization provides only moderate decreases in two-phase flow induced I(sub sp) losses. Despite these two-phase flow losses, a simple mission study indicates that aluminum gel propellants may permit a greater maximum payload than the hydrocarbon/O2 bi-propellant combination for a vehicle of fixed propellant volume. Secondary atomization was also found to reduce radiation losses from the solid combustion products to the chamber walls, primarily through reductions in propellant burnout distance.

Hygrothermal analysis of surface layers of historical masonry

NASA Astrophysics Data System (ADS)

Kočí, Václav; Maděra, Jiří; Keppert, Martin; Černý, Robert

2017-11-01

The paper deals with the hygrothermal analysis of surface layers of historical masonry. Solid brick provided with a traditional and two modified lime-based plasters is studied. The heat and moisture transport in the envelope is induced by an exposure of the wall from the exterior side to dynamic climatic conditions of Olomouc, Czech Republic. The transport processes are described using diffusion type of mathematical model based on experimentally determined material properties. The computational results indicate that hygric transport and accumulation properties of exterior plasters affect the hygrothermal performance of the underlying solid brick in a very significant way, being able to regulate the amount of transported moisture. The modified lime plasters are not found generally superior to the traditional lime plasters in that respect. Therefore, their suitability for historical masonry should be assessed case by case, with a particular attention to the climatic conditions and to the properties of the load bearing structure.

Comparative analysis of solid-state bioprocessing and enzymatic treatment of finger millet for mobilization of bound phenolics.

PubMed

Yadav, Geetanjali; Singh, Anshu; Bhattacharya, Patrali; Yuvraj, Jude; Banerjee, Rintu

2013-11-01

The present work investigates the probable bioprocessing technique to mobilize the bound phenolics naturally found in finger millet cell wall for enriching it with dietary antioxidants. Comparative study was performed between the exogenous enzymatic treatment and solid-state fermentation of grain (SSF) with a food grade organism Rhizopus oryzae. SSF results indicated that at the 6th day of incubation, total phenolic content (18.64 mg gallic acid equivalent/gds) and antioxidant property (DPPH radical scavenging activity of 39.03 %, metal chelating ability of 54 % and better reducing power) of finger millet were drastically enhanced when fermented with GRAS filamentous fungi. During the enzymatic bioprocessing, most of the phenolics released during the hydrolysis, leached out into the liquid portion rather than retaining them within the millet grain, resulting in overall loss of dietary antioxidant. The present study establishes the most effective strategy to enrich the finger millet with phenolic antioxidants.

V2O5 encapsulated MWCNTs in 2D surface architecture: Complete solid-state bendable highly stabilized energy efficient supercapacitor device

NASA Astrophysics Data System (ADS)

Pandit, Bidhan; Dubal, Deepak P.; Gómez-Romero, Pedro; Kale, Bharat B.; Sankapal, Babasaheb R.

2017-03-01

A simple and scalable approach has been reported for V2O5 encapsulation over interconnected multi-walled carbon nanotubes (MWCNTs) network using chemical bath deposition method. Chemically synthesized V2O5/MWCNTs electrode exhibited excellent charge-discharge capability with extraordinary cycling retention of 93% over 4000 cycles in liquid-electrolyte. Electrochemical investigations have been performed to evaluate the origin of capacitive behavior from dual contribution of surface-controlled and diffusion-controlled charge components. Furthermore, a complete flexible solid-state, flexible symmetric supercapacitor (FSS-SSC) device was assembled with V2O5/MWCNTs electrodes which yield remarkable values of specific power and energy densities along with enhanced cyclic stability over liquid configuration. As a practical demonstration, the constructed device was used to lit the ‘VNIT’ acronym assembled using 21 LED’s.

Partially nanofibrous architecture of 3D tissue engineering scaffolds.

PubMed

Wei, Guobao; Ma, Peter X

2009-11-01

An ideal tissue-engineering scaffold should provide suitable pores and appropriate pore surface to induce desired cellular activities and to guide 3D tissue regeneration. In the present work, we have developed macroporous polymer scaffolds with varying pore wall architectures from smooth (solid), microporous, partially nanofibrous, to entirely nanofibrous ones. All scaffolds are designed to have well-controlled interconnected macropores, resulting from leaching sugar sphere template. We examine the effects of material composition, solvent, and phase separation temperature on the pore surface architecture of 3D scaffolds. In particular, phase separation of PLLA/PDLLA or PLLA/PLGA blends leads to partially nanofibrous scaffolds, in which PLLA forms nanofibers and PDLLA or PLGA forms the smooth (solid) surfaces on macropore walls, respectively. Specific surface areas are measured for scaffolds with similar macroporosity but different macropore wall architectures. It is found that the pore wall architecture predominates the total surface area of the scaffolds. The surface area of a partially nanofibrous scaffold increases linearly with the PLLA content in the polymer blend. The amounts of adsorbed proteins from serum increase with the surface area of the scaffolds. These macroporous scaffolds with adjustable pore wall surface architectures may provide a platform for investigating the cellular responses to pore surface architecture, and provide us with a powerful tool to develop superior scaffolds for various tissue-engineering applications.

Temporal transcriptome analysis of the white-rot fungus Obba rivulosa shows expression of a constitutive set of plant cell wall degradation targeted genes during growth on solid spruce wood.

PubMed

Marinović, Mila; Aguilar-Pontes, Maria Victoria; Zhou, Miaomiao; Miettinen, Otto; de Vries, Ronald P; Mäkelä, Miia R; Hildén, Kristiina

2018-03-01

The basidiomycete white-rot fungus Obba rivulosa, a close relative of Gelatoporia (Ceriporiopsis) subvermispora, is an efficient degrader of softwood. The dikaryotic O. rivulosa strain T241i (FBCC949) has been shown to selectively remove lignin from spruce wood prior to depolymerization of plant cell wall polysaccharides, thus possessing potential in biotechnological applications such as pretreatment of wood in pulp and paper industry. In this work, we studied the time-course of the conversion of spruce by the genome-sequenced monokaryotic O. rivulosa strain 3A-2, which is derived from the dikaryon T241i, to get insight into transcriptome level changes during prolonged solid state cultivation. During 8-week cultivation, O. rivulosa expressed a constitutive set of genes encoding putative plant cell wall degrading enzymes. High level of expression of the genes targeted towards all plant cell wall polymers was detected at 2-week time point, after which majority of the genes showed reduced expression. This implicated non-selective degradation of lignin by the O. rivulosa monokaryon and suggests high variation between mono- and dikaryotic strains of the white-rot fungi with respect to their abilities to convert plant cell wall polymers. Copyright © 2017 Elsevier Inc. All rights reserved.

Fluid-Structure Model of Lymphatic Valve and Vessel

NASA Astrophysics Data System (ADS)

Wolf, Ki; Ballard, Matthew; Nepiyushchikh, Zhanna; Razavi, Mohammad; Dixon, Brandon; Alexeev, Alexander

The lymphatic system is a part of the circulatory system that performs a range of important functions such as transportation of interstitial fluid, fatty acid, and immune cells. The lymphatic vessels are composed of contractile walls to pump lymph against adverse pressure gradient and lymphatic valves that prevent back flow. Despite the importance of lymphatic system, the contribution of mechanical and geometric changes of lymphatic valves and vessels in pathologies of lymphatic dysfunction, such as lymphedema, is not well understood. We developed a coupled fluid-solid computational model to simultaneously simulate a lymphatic vessel, valve, and flow. A lattice Boltzmann model is used to represent the fluid component, while lattice spring model is used for the solid component of the lymphatic vessel, whose mechanical properties are derived experimentally. Behaviors such as lymph flow pattern and lymphatic valve performance against backflow and adverse pressure gradient under varied parameters of lymphatic valve and vessel geometry and mechanical properties are investigated to provide a better insight into the dynamics of lymphatic vessels, valves, and system and give insight into how they might fail in disease. NSF CMMI-1635133.

Molecular-dynamics simulations of crosslinking and confinement effects on structure, segmental mobility and mechanics of filled elastomers

NASA Astrophysics Data System (ADS)

Davris, Theodoros; Lyulin, Alexey V.

2016-05-01

The significant drop of the storage modulus under uniaxial deformation (Payne effect) restrains the performance of the elastomer-based composites and the development of possible new applications. In this paper molecular-dynamics (MD) computer simulations using LAMMPS MD package have been performed to study the mechanical properties of a coarse-grained model of this family of nanocomposite materials. Our goal is to provide simulational insights into the viscoelastic properties of filled elastomers, and try to connect the macroscopic mechanics with composite microstructure, the strength of the polymer-filler interactions and the polymer mobility at different scales. To this end we simulate random copolymer films capped between two infinite solid (filler aggregate) walls. We systematically vary the strength of the polymer-substrate adhesion interactions, degree of polymer confinement (film thickness), polymer crosslinking density, and study their influence on the equilibrium and non-equilibrium structure, segmental dynamics, and the mechanical properties of the simulated systems. The glass-transition temperature increases once the mesh size became smaller than the chain radius of gyration; otherwise it remained invariant to mesh-size variations. This increase in the glass-transition temperature was accompanied by a monotonic slowing-down of segmental dynamics on all studied length scales. This observation is attributed to the correspondingly decreased width of the bulk density layer that was obtained in films whose thickness was larger than the end-to-end distance of the bulk polymer chains. To test this hypothesis additional simulations were performed in which the crystalline walls were replaced with amorphous or rough walls.

A New Axi-Symmetric Element for Thin Walled Structures

NASA Astrophysics Data System (ADS)

Cardoso, Rui P. R.; Yoon, Jeong Whan; Dick, Robert E.

2010-06-01

A new axi-symmetric finite element for sheet metal forming applications is presented in this work. It uses the solid-shell element's concept with only a single element layer and multiple integration points along the thickness direction. The cross section of the element is composed of four nodes with two degrees of freedom each. The proposed formulation overcomes major locking pathologies including transverse shear locking, Poisson's locking and volumetric locking. Some examples are shown to demonstrate the performance and accuracy of the proposed element with special focus on the numerical simulations for the beverage can industry.

Cellulose Structural Polymorphism in Plant Primary Cell Walls Investigated by High-Field 2D Solid-State NMR Spectroscopy and Density Functional Theory Calculations.

PubMed

Wang, Tuo; Yang, Hui; Kubicki, James D; Hong, Mei

2016-06-13

The native cellulose of bacterial, algal, and animal origins has been well studied structurally using X-ray and neutron diffraction and solid-state NMR spectroscopy, and is known to consist of varying proportions of two allomorphs, Iα and Iβ, which differ in hydrogen bonding, chain packing, and local conformation. In comparison, cellulose structure in plant primary cell walls is much less understood because plant cellulose has lower crystallinity and extensive interactions with matrix polysaccharides. Here we have combined two-dimensional magic-angle-spinning (MAS) solid-state nuclear magnetic resonance (solid-state NMR) spectroscopy at high magnetic fields with density functional theory (DFT) calculations to obtain detailed information about the structural polymorphism and spatial distributions of plant primary-wall cellulose. 2D (13)C-(13)C correlation spectra of uniformly (13)C-labeled cell walls of several model plants resolved seven sets of cellulose chemical shifts. Among these, five sets (denoted a-e) belong to cellulose in the interior of the microfibril while two sets (f and g) can be assigned to surface cellulose. Importantly, most of the interior cellulose (13)C chemical shifts differ significantly from the (13)C chemical shifts of the Iα and Iβ allomorphs, indicating that plant primary-wall cellulose has different conformations, packing, and hydrogen bonding from celluloses of other organisms. 2D (13)C-(13)C correlation experiments with long mixing times and with water polarization transfer revealed the spatial distributions and matrix-polysaccharide interactions of these cellulose structures. Celluloses f and g are well mixed chains on the microfibril surface, celluloses a and b are interior chains that are in molecular contact with the surface chains, while cellulose c resides in the core of the microfibril, outside spin diffusion contact with the surface. Interestingly, cellulose d, whose chemical shifts differ most significantly from those of bacterial, algal, and animal cellulose, interacts with hemicellulose, is poorly hydrated, and is targeted by the protein expansin during wall loosening. To obtain information about the C6 hydroxymethyl conformation of these plant celluloses, we carried out DFT calculations of (13)C chemical shifts, using the Iα and Iβ crystal structures as templates and varying the C5-C6 torsion angle. Comparison with the experimental chemical shifts suggests that all interior cellulose favor the tg conformation, but cellulose d also has a similar propensity to adopt the gt conformation. These results indicate that cellulose in plant primary cell walls, due to their interactions with matrix polysaccharides, and has polymorphic structures that are not a simple superposition of the Iα and Iβ allomorphs, thus distinguishing them from bacterial and animal celluloses.

Cellulose Structural Polymorphism in Plant Primary Cell Walls Investigated by High-Field 2D Solid-State NMR Spectroscopy and Density Functional Theory Calculations

PubMed Central

Wang, Tuo; Yang, Hui; Kubicki, James D.; Hong, Mei

2017-01-01

The native cellulose of bacterial, algal, and animal origins has been well studied structurally using X-ray and neutron diffraction and solid-state NMR spectroscopy, and is known to consist of varying proportions of two allomorphs, Iα and Iβ, which differ in hydrogen bonding, chain packing, and local conformation. In comparison, cellulose structure in plant primary cell walls is much less understood because plant cellulose has lower crystallinity and extensive interactions with matrix polysaccharides. Here we have combined two-dimensional magic-angle-spinning (MAS) solid-state nuclear magnetic resonance (solid-state NMR) spectroscopy at high magnetic fields with density functional theory (DFT) calculations to obtain detailed information about the structural polymorphism and spatial distributions of plant primary-wall cellulose. 2D 13C-13C correlation spectra of uniformly 13C-labeled cell walls of several model plants resolved seven sets of cellulose chemical shifts. Among these, five sets (denoted a-e) belong to cellulose in the interior of the microfibril while two sets (f and g) can be assigned to surface cellulose. Importantly, most of the interior cellulose 13C chemical shifts differ significantly from the 13C chemical shifts of the Iα and Iβ allomorphs, indicating that plant primary-wall cellulose has different conformations, packing and hydrogen bonding from celluloses of other organisms. 2D 13C-13C correlation experiments with long mixing times and with water polarization transfer revealed the spatial distributions and matrix-polysaccharide interactions of these cellulose structures. Cellulose f and g are well mixed chains on the microfibril surface, cellulose a and b are interior chains that are in molecular contact with the surface chains, while cellulose c resides in the core of the microfibril, outside spin diffusion contact with the surface. Interestingly, cellulose d, whose chemical shifts differ most significantly from those of bacterial, algal and animal cellulose, interacts with hemicellulose, is poorly hydrated, and is targeted by the protein expansin during wall loosening. To obtain information about the C6 hydroxymethyl conformation of these plant celluloses, we carried out DFT calculations of 13C chemical shifts, using the Iα and Iβ crystal structures as templates and varying the C5-C6 torsion angle. Comparison with the experimental chemical shifts suggests that all interior cellulose favor the tg conformation, but cellulose d also has a similar propensity to adopt the gt conformation. These results indicate that cellulose in plant primary cell walls, due to their interactions with matrix polysaccharides, has polymorphic structures that are not a simple superposition of the Iα and Iβ allomorphs, thus distinguishing them from bacterial and animal celluloses. PMID:27192562

DEM study of granular flow around blocks attached to inclined walls

NASA Astrophysics Data System (ADS)

Samsu, Joel; Zhou, Zongyan; Pinson, David; Chew, Sheng

2017-06-01

Damage due to intense particle-wall contact in industrial applications can cause severe problems in industries such as mineral processing, mining and metallurgy. Studying the flow dynamics and forces on containing walls can provide valuable feedback for equipment design and optimising operations to prolong the equipment lifetime. Therefore, solids flow-wall interaction phenomena, i.e. induced wall stress and particle flow patterns should be well understood. In this work, discrete element method (DEM) is used to study steady state granular flow in a gravity-fed hopper like geometry with blocks attached to an inclined wall. The effects of different geometries, e.g. different wall angles and spacing between blocks are studied by means of a 3D DEM slot model with periodic boundary conditions. The findings of this work include (i) flow analysis in terms of flow patterns and particle velocities, (ii) force distributions within the model geometry, and (iii) wall stress vs. model height diagrams. The model enables easy transfer of the key findings to other industrial applications handling granular materials.

An engineering study of hybrid adaptation of wind tunnel walls for three-dimensional testing

NASA Technical Reports Server (NTRS)

Brown, Clinton; Kalumuck, Kenneth; Waxman, David

1987-01-01

Solid wall tunnels having only upper and lower walls flexing are described. An algorithm for selecting the wall contours for both 2 and 3 dimensional wall flexure is presented and numerical experiments are used to validate its applicability to the general test case of 3 dimensional lifting aircraft models in rectangular cross section wind tunnels. The method requires an initial approximate representation of the model flow field at a given lift with wallls absent. The numerical methods utilized are derived by use of Green's source solutions obtained using the method of images; first order linearized flow theory is employed with Prandtl-Glauert compressibility transformations. Equations are derived for the flexed shape of a simple constant thickness plate wall under the influence of a finite number of jacks in an axial row along the plate centerline. The Green's source methods are developed to provide estimations of residual flow distortion (interferences) with measured wall pressures and wall flow inclinations as inputs.

Bacterial community radial-spatial distribution in biofilms along pipe wall in chlorinated drinking water distribution system of East China.

PubMed

Liu, Jingqing; Ren, Hongxing; Ye, Xianbei; Wang, Wei; Liu, Yan; Lou, Liping; Cheng, Dongqing; He, Xiaofang; Zhou, Xiaoyan; Qiu, Shangde; Fu, Liusong; Hu, Baolan

2017-01-01

Biofilms in the pipe wall may lead to water quality deterioration and biological instability in drinking water distribution systems (DWDSs). In this study, bacterial community radial-spatial distribution in biofilms along the pipe wall in a chlorinated DWDS of East China was investigated. Three pipes of large diameter (300, 600, and 600 mm) were sampled in this DWDS, including a ductile cast iron pipe (DCIP) with pipe age of 11 years and two gray cast iron pipes (GCIP) with pipe ages of 17 and 19 years, and biofilms in the upper, middle, and lower parts of each pipe wall were collected. Real-time quantitative polymerase chain reaction (qPCR) and culture-based method were used to quantify bacteria. 454 pyrosequencing was used for bacterial community analysis. The results showed that the biofilm density and total solid (TS) and volatile solid (VS) contents increased gradually from the top to the bottom along the pipe wall. Microorganisms were concentrated in the upper and lower parts of the pipe wall, together accounting for more than 80 % of the total biomass in the biofilms. The bacterial communities in biofilms were significantly different in different areas of the pipe wall and had no strong interaction. Compared with the upper and lower parts of the pipe wall, the bacterial community in the middle of the pipe wall was distributed evenly and had the highest diversity. The 16S rRNA genes of various possible pathogens, including Escherichia coli, Staphylococcus epidermidis, Pseudomonas aeruginosa, and Salmonella enterica, were detected in the biofilms, and the abundances of these possible pathogens were highest in the middle of the pipe wall among three areas. The detachment of the biofilms is the main reason for the deterioration of the water quality in DWDSs. The results of this study suggest that the biofilms in the middle of the pipe wall have highly potential risk for drinking water safety, which provides new ideas for the study of the microbial ecology in DWDS.

Water-polysaccharide interactions in the primary cell wall of Arabidopsis thaliana from polarization transfer solid-state NMR.

PubMed

White, Paul B; Wang, Tuo; Park, Yong Bum; Cosgrove, Daniel J; Hong, Mei

2014-07-23

Polysaccharide-rich plant cell walls are hydrated under functional conditions, but the molecular interactions between water and polysaccharides in the wall have not been investigated. In this work, we employ polarization transfer solid-state NMR techniques to study the hydration of primary-wall polysaccharides of the model plant, Arabidopsis thaliana. By transferring water (1)H polarization to polysaccharides through distance- and mobility-dependent (1)H-(1)H dipolar couplings and detecting it through polysaccharide (13)C signals, we obtain information about water proximity to cellulose, hemicellulose, and pectins as well as water mobility. Both intact and partially extracted cell wall samples are studied. Our results show that water-pectin polarization transfer is much faster than water-cellulose polarization transfer in all samples, but the extent of extraction has a profound impact on the water-polysaccharide spin diffusion. Removal of calcium ions and the consequent extraction of homogalacturonan (HG) significantly slowed down spin diffusion, while further extraction of matrix polysaccharides restored the spin diffusion rate. These trends are observed in cell walls with similar water content, thus they reflect inherent differences in the mobility and spatial distribution of water. Combined with quantitative analysis of the polysaccharide contents, our results indicate that calcium ions and HG gelation increase the amount of bound water, which facilitates spin diffusion, while calcium removal disrupts the gel and gives rise to highly dynamic water, which slows down spin diffusion. The recovery of spin diffusion rates after more extensive extraction is attributed to increased water-exposed surface areas of the polysaccharides. Water-pectin spin diffusion precedes water-cellulose spin diffusion, lending support to the single-network model of plant primary walls in which a substantial fraction of the cellulose surface is surrounded by pectins.

Numerical simulation of the effect of groundwater salinity on artificial freezing wall in coastal area

NASA Astrophysics Data System (ADS)

Hu, Rui; Liu, Quan

2017-04-01

During the engineering projects with artificial ground freezing (AFG) techniques in coastal area, the freezing effect is affected by groundwater salinity. Based on the theories of artificially frozen soil and heat transfer in porous material, and with the assumption that only the variations of total dissolved solids (TDS) impact on freezing point and thermal conductivity, a numerical model of an AFG project in a saline aquifer was established and validated by comparing the simulated temperature field with the calculated temperature based on the analytic solution of rupak (reference) for single-pipe freezing temperature field T. The formation and development of freezing wall were simulated with various TDS. The results showed that the variety of TDS caused the larger temperature difference near the frozen front. With increasing TDS in the saline aquifer (1 35g/L), the average thickness of freezing wall decreased linearly and the total formation time of the freezing wall increased linearly. Compared with of the scenario of fresh-water (<1g/L), the average thickness of frozen wall decreased by 6% and the total formation time of the freezing wall increased by 8% with each increasing TDS of 7g/L. Key words: total dissolved solids, freezing point, thermal conductivity, freezing wall, numerical simulation Reference D.J.Pringel, H.Eicken, H.J.Trodahl, etc. Thermal conductivity of landfast Antarctic and Arctic sea ice[J]. Journal of Geophysical Research, 2007, 112: 1-13. Lukas U.Arenson, Dave C.Sego. The effect of salinity on the freezing of coarse- grained sand[J]. Canadian Geotechnical Journal, 2006, 43: 325-337. Hui Bing, Wei Ma. Laboratory investigation of the freezing point of saline soil[J]. Cold Regions Science and Technology, 2011, 67: 79-88.

Simulation of granular and gas-solid flows using discrete element method

NASA Astrophysics Data System (ADS)

Boyalakuntla, Dhanunjay S.

2003-10-01

In recent years there has been increased research activity in the experimental and numerical study of gas-solid flows. Flows of this type have numerous applications in the energy, pharmaceuticals, and chemicals process industries. Typical applications include pulverized coal combustion, flow and heat transfer in bubbling and circulating fluidized beds, hopper and chute flows, pneumatic transport of pharmaceutical powders and pellets, and many more. The present work addresses the study of gas-solid flows using computational fluid dynamics (CFD) techniques and discrete element simulation methods (DES) combined. Many previous studies of coupled gas-solid flows have been performed assuming the solid phase as a continuum with averaged properties and treating the gas-solid flow as constituting of interpenetrating continua. Instead, in the present work, the gas phase flow is simulated using continuum theory and the solid phase flow is simulated using DES. DES treats each solid particle individually, thus accounting for its dynamics due to particle-particle interactions, particle-wall interactions as well as fluid drag and buoyancy. The present work involves developing efficient DES methods for dense granular flow and coupling this simulation to continuum simulations of the gas phase flow. Simulations have been performed to observe pure granular behavior in vibrating beds. Benchmark cases have been simulated and the results obtained match the published literature. The dimensionless acceleration amplitude and the bed height are the parameters governing bed behavior. Various interesting behaviors such as heaping, round and cusp surface standing waves, as well as kinks, have been observed for different values of the acceleration amplitude for a given bed height. Furthermore, binary granular mixtures (granular mixtures with two particle sizes) in a vibrated bed have also been studied. Gas-solid flow simulations have been performed to study fluidized beds. Benchmark 2D fluidized bed simulations have been performed and the results have been shown to satisfactorily compare with those published in the literature. A comprehensive study of the effect of drag correlations on the simulation of fluidized beds has been performed. It has been found that nearly all the drag correlations studied make similar predictions of global quantities such as the time-dependent pressure drop, bubbling frequency and growth. In conclusion, discrete element simulation has been successfully coupled to continuum gas-phase. Though all the results presented in the thesis are two-dimensional, the present implementation is completely three dimensional and can be used to study 3D fluidized beds to aid in better design and understanding. Other industrially important phenomena like particle coating, coal gasification etc., and applications in emerging areas such as nano-particle/fluid mixtures can also be studied through this type of simulation. (Abstract shortened by UMI.)

Double diffusive conjugate heat transfer: Part I

NASA Astrophysics Data System (ADS)

Azeem, Soudagar, Manzoor Elahi M.

2018-05-01

The present work is undertaken to investigate the effect of solid wall being placed at left of square cavity filled with porous medium. The presence of a solid wall in the porous medium turns the situation into a conjugate heat transfer problem. The boundary conditions are such that the left vertical surface is maintained at highest temperature and concentration whereas right vertical surface at lowest temperature and concentration in the medium. The top and bottom surfaces are adiabatic. The additional conduction equation along with the regular momentum and energy equations of porous medium are solved in an iterative manner with the help of finite element method. It is seen that the heat and mass transfer rate is lesser due to smaller thermal and concentration gradients.

Observations of the freeze/thaw performance of lithium fluoride by motion picture photography

NASA Technical Reports Server (NTRS)

Jaworske, D. A.; Perry, W. D.

1991-01-01

To gain direct observation of the molten salt phase change, a novel containerless technique was developed where the high surface tension of lithium fluoride was used to suspend a bead of the molten salt inside a specially designed wire cage. By varying the current passing through the wire, the cage also served as a variable heat source. In this way, the freeze/thaw performance of the lithium fluoride could be photographed by motion picture photography without the influence of container walls. The motion picture photography of the lithium fluoride sample revealed several zones during the phase change, a solid zone and a liquid zone, as expected, and a slush zone that was predicted by thermal analysis modeling.

Multi-walled carbon nanotubes-dispersive solid-phase extraction combined with liquid chromatography-tandem mass spectrometry for the analysis of 18 sulfonamides in pork.

PubMed

Hou, Xiao-Lin; Wu, Yin-Liang; Yang, Ting; Du, Xiang-Dang

2013-06-15

A simple and cost-effective pre-treatment procedure was developed for 18 sulfonamides in pork using dispersive solid phase extraction (dSPE) with multi-walled carbon nanotubes (MWCNTs). The sample was analysed after purification by ultra high-performance liquid chromatography-positive electrospray ionisation tandem mass spectrometry (UHPLC-ESI-MS/MS). After extraction with phosphate buffer (pH 6.0), a dSPE procedure was conducted with MWCNTs. The pH value of the extract, extraction time with MWCNTs, type and amount of MWCNTs and type of eluent were optimised to increase the sample throughput and sensitivity. The samples were quantified using sulfamethazine-(13)C6 as an internal standard. The recoveries of the target compounds from the pork samples were most efficient when 150mg of MWCNTs with an outer diameter of less than 8nm and a length of 0.5-2μm was used. A mixture of acetonitrile/50mM ammonium acetate (95:5, v/v) was shown to be the most suitable solvent for desorbing the compounds from the MWCNTs. The proposed method was validated according to the European Commission Decision 2002/657/EC, which determines linearity, specificity, decision limit (CCα), detection capability (CCβ), recovery, precision and stability. Copyright © 2013 Elsevier B.V. All rights reserved.

Understanding and Mitigating Vortex-Dominated, Tip-Leakage and End-Wall Losses in a Transonic Splittered Rotor Stage

DTIC Science & Technology

2015-04-23

blade geometry parameters the TPL design 9   tool was initiated by running the MATLAB script (*.m) Main_SpeedLine_Auto. Main_SpeedLine_Auto...SolidWorks for solid model generation of the blade shapes. Computational Analysis With solid models generated of the gas -path air wedge, automated...287 mm (11.3 in) Constrained by existing TCR geometry Number of Passages 12 None A blade tip-down design approach was used. The outputs of the

Thermal and velocity slip effects on the MHD peristaltic flow with carbon nanotubes in an asymmetric channel: application of radiation therapy

NASA Astrophysics Data System (ADS)

Akbar, Noreen Sher; Nadeem, S.; Khan, Zafar Hayat

2014-10-01

Peristaltic flow is used to study the flow and heat transfer of carbon nanotubes in an asymmetric channel with thermal and velocity slip effects. Two types of carbon nanotubes, namely, single- and multi-wall carbon nanotubes are utilized to see the analysis with water as base fluids. Empirical correlations are used for the thermo-physical properties of carbon nanotubes (CNTs) in terms of solid volume fraction of CNTs. The governing equations are simplified using long wavelength and low Reynolds number approximation. Exact solutions have been evaluated for velocity, pressure gradient, the solid volume fraction of CNTs and temperature profile. The effects of various flow parameters, i.e. Hatmann number M, the solid volume fraction of the nanoparticles ϕ, Grashof number G, velocity slip parameter β, thermal slip parameter γ and Prandtl number P r are presented graphically for both single- (SWCNT) and multi-wall carbon nanotubes (MWCNT).

Malachite green interferes with postantibiotic recovery of mycobacteria.

PubMed

Gelman, Ekaterina; McKinney, John D; Dhar, Neeraj

2012-07-01

The genus Mycobacterium comprises slow-growing species with generation times ranging from hours to weeks. The protracted incubation time before colonies appear on solid culture medium can result in overgrowth by faster-growing microorganisms. To prevent contamination, the solid media used in laboratories and clinics for cultivation of mycobacteria contain the arylmethane compound malachite green, which has broad-spectrum antimicrobial activity. Malachite green has no impact on the plating efficiency of mycobacteria when cells are grown under normal conditions. However, we found that malachite green interfered with colony formation when bacteria were preexposed to antibiotics targeting cell wall biogenesis (isoniazid, ethionamide, ethambutol). This inhibitory effect of malachite green was not observed when bacteria were preexposed to antibiotics targeting cellular processes other than cell wall biogenesis (rifampin, moxifloxacin, streptomycin). Sputum specimens from tuberculosis patients are routinely evaluated on solid culture medium containing high concentrations of malachite green. This practice could lead to underestimation of bacterial loads and overestimation of chemotherapeutic efficacy.

Malachite Green Interferes with Postantibiotic Recovery of Mycobacteria

PubMed Central

Gelman, Ekaterina; McKinney, John D.

2012-01-01

The genus Mycobacterium comprises slow-growing species with generation times ranging from hours to weeks. The protracted incubation time before colonies appear on solid culture medium can result in overgrowth by faster-growing microorganisms. To prevent contamination, the solid media used in laboratories and clinics for cultivation of mycobacteria contain the arylmethane compound malachite green, which has broad-spectrum antimicrobial activity. Malachite green has no impact on the plating efficiency of mycobacteria when cells are grown under normal conditions. However, we found that malachite green interfered with colony formation when bacteria were preexposed to antibiotics targeting cell wall biogenesis (isoniazid, ethionamide, ethambutol). This inhibitory effect of malachite green was not observed when bacteria were preexposed to antibiotics targeting cellular processes other than cell wall biogenesis (rifampin, moxifloxacin, streptomycin). Sputum specimens from tuberculosis patients are routinely evaluated on solid culture medium containing high concentrations of malachite green. This practice could lead to underestimation of bacterial loads and overestimation of chemotherapeutic efficacy. PMID:22526306

Effect of high surface area activated carbon on thermal degradation of jet fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gergova, K.; Eser, S.; Arumugam, R.

1995-05-01

Different solid carbons added to jet fuel during thermal stressing cause substantial changes in pyrolytic degradation reactions. Activated carbons, especially high surface area activated carbons were found to be very effective in suppressing solid deposition on metal reactor walls during stressing at high temperatures (425 and 450{degrees}C). The high surface area activated carbon PX-21 prevented solid deposition on reactor walls even after 5h at 450{degrees}C. The differences seen in the liquid product composition when activated carbon is added indicated that the carbon surfaces affect the degradation reactions. Thermal stressing experiments were carried out on commercial petroleum-derived JPTS jet fuel. Wemore » also used n-octane and n-dodecane as model compounds in order to simplify the study of the chemical changes which take place upon activated carbon addition. In separate experiments, the presence of a hydrogen donor, decalin, together with PX-21 was also studied.« less

Heteroepitaxial Growth of Single-Walled Carbon Nanotubes from Boron Nitride

PubMed Central

Tang, Dai-Ming; Zhang, Li-Li; Liu, Chang; Yin, Li-Chang; Hou, Peng-Xiang; Jiang, Hua; Zhu, Zhen; Li, Feng; Liu, Bilu; Kauppinen, Esko I.; Cheng, Hui-Ming

2012-01-01

The growth of single-walled carbon nanotubes (SWCNTs) with predefined structure is of great importance for both fundamental research and their practical applications. Traditionally, SWCNTs are grown from a metal catalyst with a vapor-liquid-solid mechanism, where the catalyst is in liquid state with fluctuating structures, and it is intrinsically unfavorable for the structure control of SWCNTs. Here we report the heteroepitaxial growth of SWCNTs from a platelet boron nitride nanofiber (BNNF), which is composed of stacked (002) planes and is stable at high temperatures. SWCNTs are found to grow epitaxially from the open (002) edges of the BNNFs, and the diameters of the SWCNTs are multiples of the BN (002) interplanar distance. In situ transmission electron microscopy observations coupled with first principles calculations reveal that the growth of SWCNTs from the BNNFs follows a vapor-solid-solid mechanism. Our work opens opportunities for the control over the structure of SWCNTs by hetero-crystallographic epitaxy. PMID:23240076

Split Tolerance in a Murine Model of Heterotopic En Bloc Chest Wall Transplantation

PubMed Central

Oh, Byoungchol; Furtmüller, Georg J.; Malek, Veronika; Fryer, Madeline L.; Brayton, Cory; Walczak, Piotr; Janowski, Miroslaw

2017-01-01

Background: Congenital and acquired chest wall deformities represent a significant challenge to functional reconstruction and may impact feasibility of heart transplantation for patients with end-stage organ failure. In the recent past, the concept of replacing like-with-like tissue by using vascularized composite allografts (VCA) has been enthusiastically employed for reconstruction of complex tissue defects. Methods: In this study, we introduce a novel murine model for en bloc chest wall, heart, and thymus transplantation and thereby the use of complex tissue allografts for reconstruction of both chest wall defects and also end-stage organ failure. Additionally, this model allows us to study the features of combined vascularized bone marrow (VBM), thymus, and heart transplantation on allograft survival and function. Heterotopic chest wall, thymus, and heart transplants were performed in untreated syngeneic and allogeneic combinations and in allogeneic combinations treated with costimulation blockade (CTLA4-Ig and MR-1). Results: Indefinite (ie, 150 d, N = 3) graft survival was observed in syngeneic controls. In untreated recipients of allogeneic grafts, the skin component was rejected after 10 (±1) days, whereas rejection of the heart occurred after 13 (± 1) days (N = 3). Costimulation blockade treatment prolonged survival of the heart and chest wall component (130 d, N = 3) as well as the VBM niche as evidenced by donor-specific chimerism (average: 2.35 ± 1.44%), whereas interestingly, the skin component was rejected after 13 (±1) days. Conclusion: Thus, this novel microsurgical model of VCA combined with solid organ transplantation is technically feasible and results in split tolerance when treated with costimulatory blockade. PMID:29632774

Solid-on-solid contact in a sphere-wall collision in a viscous fluid

NASA Astrophysics Data System (ADS)

Birwa, Sumit Kumar; Rajalakshmi, G.; Govindarajan, Rama; Menon, Narayanan

2018-04-01

We study experimentally the collision between a sphere falling through a viscous fluid and a solid plate below. It is known that there is a well-defined threshold Stokes number above which the sphere rebounds from such a collision. Our experiment tests for direct contact between the colliding bodies and, contrary to prior theoretical predictions, shows that solid-on-solid contact occurs even for Stokes numbers just above the threshold for rebounding. The dissipation is fluid dominated, though details of the contact mechanics depend on the surface and bulk properties of the solids. Our experiments and a model calculation indicate that mechanical contact between the two colliding objects is generic and will occur for any realistic surface roughness.

Statistical Calibration and Validation of a Homogeneous Ventilated Wall-Interference Correction Method for the National Transonic Facility

NASA Technical Reports Server (NTRS)

Walker, Eric L.

2005-01-01

Wind tunnel experiments will continue to be a primary source of validation data for many types of mathematical and computational models in the aerospace industry. The increased emphasis on accuracy of data acquired from these facilities requires understanding of the uncertainty of not only the measurement data but also any correction applied to the data. One of the largest and most critical corrections made to these data is due to wall interference. In an effort to understand the accuracy and suitability of these corrections, a statistical validation process for wall interference correction methods has been developed. This process is based on the use of independent cases which, after correction, are expected to produce the same result. Comparison of these independent cases with respect to the uncertainty in the correction process establishes a domain of applicability based on the capability of the method to provide reasonable corrections with respect to customer accuracy requirements. The statistical validation method was applied to the version of the Transonic Wall Interference Correction System (TWICS) recently implemented in the National Transonic Facility at NASA Langley Research Center. The TWICS code generates corrections for solid and slotted wall interference in the model pitch plane based on boundary pressure measurements. Before validation could be performed on this method, it was necessary to calibrate the ventilated wall boundary condition parameters. Discrimination comparisons are used to determine the most representative of three linear boundary condition models which have historically been used to represent longitudinally slotted test section walls. Of the three linear boundary condition models implemented for ventilated walls, the general slotted wall model was the most representative of the data. The TWICS code using the calibrated general slotted wall model was found to be valid to within the process uncertainty for test section Mach numbers less than or equal to 0.60. The scatter among the mean corrected results of the bodies of revolution validation cases was within one count of drag on a typical transport aircraft configuration for Mach numbers at or below 0.80 and two counts of drag for Mach numbers at or below 0.90.

Intracranial Vascular Disease Evaluation With Combined Vessel Wall Imaging And Patient Specific Hemodynamics

NASA Astrophysics Data System (ADS)

Samson, Kurt; Mossa-Basha, Mahmud; Yuan, Chun; Canton, Maria De Gador; Aliseda, Alberto

2017-11-01

Intracranial vascular pathologies are evaluated with angiography, conventional digital subtraction angiography or non-invasive (MRI, CT). Current techniques present limitations on the resolution with which the vessel wall characteristics can be measured, presenting a major challenge to differential diagnostic of cerebral vasculopathies. A new combined approach is presented that incorporates patient-specific image-based CFD models with intracranial vessel-wall MRI (VWMRI). Comparisons of the VWMRI measurements, evaluated for the presence of wall enhancement and thin-walled regions, against CFD metrics such as wall shear stress (WSS), and oscillatory shear index (OSI) are used to understand how the new imaging technique developed can predict the influence of hemodynamics on the deterioration of the aneurysmal wall, leading to rupture. Additionally, histology of each resected aneurysm, evaluated for inflammatory infiltration and wall thickness features, is used to validate the analysis from VWMRI and CFD. This data presents a solid foundation on which to build a new framework for combined VWMRI-CFD to predict unstable wall changes in unruptured intracranial aneurysms, and support clinical monitoring and intervention decisions.

NanoRelease: Pilot interlaboratory comparison of a weathering protocol applied to resilient and labile polymers with and without embedded carbon nanotubes

EPA Science Inventory

A major use of multi-walled carbon nanotubes (MWCNTs) is as functional fillers embedded in a solid matrix, such as plastics or coatings. Weathering and abrasion of the solid matrix during use can lead to environmental releases of the MWCNTs. Here we focus on a protocol to identif...

Vortex dynamics of collapsing bubbles: Impact on the boundary layer measured by chronoamperometry.

PubMed

Reuter, Fabian; Cairós, Carlos; Mettin, Robert

2016-11-01

Cavitation bubbles collapsing in the vicinity to a solid substrate induce intense micro-convection at the solid. Here we study the transient near-wall flows generated by single collapsing bubbles by chronoamperometric measurements synchronously coupled with high-speed imaging. The individual bubbles are created at confined positions by a focused laser pulse. They reach a maximum expansion radius of approximately 425μm. Several stand-off distances to the flat solid boundary are investigated and all distances are chosen sufficiently large that no gas phase of the expanding and collapsing bubble touches the solid directly. With a microelectrode embedded into the substrate, the time-resolved perturbations in the liquid shear layer are probed by means of a chronoamperometric technique. The measurements of electric current are synchronized with high-speed imaging of the bubble dynamics. The perturbations of the near-wall layer are found to result mainly from ring vortices created by the jetting bubble. Other bubble induced flows, such as the jet and flows following the radial bubble oscillations are perceptible with this technique, but show a minor influence at the stand-off distances investigated. Copyright © 2016 Elsevier B.V. All rights reserved.

Adaptive wall technology for minimization of wall interferences in transonic wind tunnels

NASA Technical Reports Server (NTRS)

Wolf, Stephen W. D.

1988-01-01

Modern experimental techniques to improve free air simulations in transonic wind tunnels by use of adaptive wall technology are reviewed. Considered are the significant advantages of adaptive wall testing techniques with respect to wall interferences, Reynolds number, tunnel drive power, and flow quality. The application of these testing techniques relies on making the test section boundaries adjustable and using a rapid wall adjustment procedure. A historical overview shows how the disjointed development of these testing techniques, since 1938, is closely linked to available computer support. An overview of Adaptive Wall Test Section (AWTS) designs shows a preference for use of relatively simple designs with solid adaptive walls in 2- and 3-D testing. Operational aspects of AWTS's are discussed with regard to production type operation where adaptive wall adjustments need to be quick. Both 2- and 3-D data are presented to illustrate the quality of AWTS data over the transonic speed range. Adaptive wall technology is available for general use in 2-D testing, even in cryogenic wind tunnels. In 3-D testing, more refinement of the adaptive wall testing techniques is required before more widespread use can be planned.

Effect of wall heat transfer on shock-tube test temperature at long times

NASA Astrophysics Data System (ADS)

Frazier, C.; Lamnaouer, M.; Divo, E.; Kassab, A.; Petersen, E.

2011-02-01

When performing chemical kinetics experiments behind reflected shock waves at conditions of lower temperature (<1,000 K), longer test times on the order of 10-20 ms may be required. The integrity of the test temperature during such experiments may be in question, because heat loss to the tube walls may play a larger role than is generally seen in shock-tube kinetics experiments that are over within a millisecond or two. A series of detailed calculations was performed to estimate the effect of longer test times on the temperature uniformity of the post-shock test gas. Assuming the main mode of heat transfer is conduction between the high-temperature gas and the colder shock-tube walls, a comprehensive set of calculations covering a range of conditions including test temperatures between 800 and 1,800 K, pressures between 1 and 50 atm, driven-tube inner diameters between 3 and 16.2 cm, and test gases of N2 and Ar was performed. Based on the results, heat loss to the tube walls does not significantly reduce the area-averaged temperature behind the reflected shock wave for test conditions that are likely to be used in shock-tube studies for test times up to 20 ms (and higher), provided the shock-tube inner diameter is sufficiently large (>8cm). Smaller diameters on the order of 3 cm or less can experience significant temperature loss near the reflected-shock region. Although the area-averaged gas temperature decreases due to the heat loss, the main core region remains spatially uniform so that the zone of temperature change is limited to only the thermal layer adjacent to the walls. Although the heat conduction model assumes the gas and wall to behave as solid bodies, resulting in a core gas temperature that remains constant at the initial temperature, a two-zone gas model that accounts for density loss from the core to the colder thermal layer indicates that the core temperature and gas pressure both decrease slightly with time. A full CFD solution of the shock-tube flow field and heat transfer at long test times was also performed for one typical condition (800 K, 1 atm, Ar), the results of which indicate that the simpler analytical conduction model is realistic but somewhat conservative in that it over predicts the mean temperature loss by a few Kelvins. This paper presents the first comprehensive study on the effects of long test times on the average test gas temperature behind the reflected shock wave for conditions representative of chemical kinetics experiments.

Modeling the Gas Dynamics Environment in a Subscale Solid Rocket Test Motor

NASA Technical Reports Server (NTRS)

Eaton, Andrew M.; Ewing, Mark E.; Bailey, Kirk M.; McCool, Alex (Technical Monitor)

2001-01-01

Subscale test motors are often used for the evaluation of solid rocket motor component materials such as internal insulation. These motors are useful for characterizing insulation performance behavior, screening insulation material candidates and obtaining material thermal and ablative property design data. One of the primary challenges associated with using subscale motors however, is the uncertainty involved when extrapolating the results to full-scale motor conditions. These uncertainties are related to differences in such phenomena as turbulent flow behavior and boundary layer development, propellant particle interactions with the wall, insulation off-gas mixing and thermochemical reactions with the bulk flow, radiation levels, material response to the local environment, and other anomalous flow conditions. In addition to the need for better understanding of physical mechanisms, there is also a need to better understand how to best simulate these phenomena using numerical modeling approaches such as computational fluid dynamics (CFD). To better understand and model interactions between major phenomena in a subscale test motor, a numerical study of the internal flow environment of a representative motor was performed. Simulation of the environment included not only gas dynamics, but two-phase flow modeling of entrained alumina particles like those found in an aluminized propellant, and offgassing from wall surfaces similar to an ablating insulation material. This work represents a starting point for establishing the internal environment of a subscale test motor using comprehensive modeling techniques, and lays the groundwork for improving the understanding of the applicability of subscale test data to full-scale motors. It was found that grid resolution, and inclusion of phenomena in addition to gas dynamics, such as two-phase and multi-component gas composition are all important factors that can effect the overall flow field predictions.

Magnetic antiskyrmions above room temperature in tetragonal Heusler materials

NASA Astrophysics Data System (ADS)

Nayak, Ajaya K.; Kumar, Vivek; Ma, Tianping; Werner, Peter; Pippel, Eckhard; Sahoo, Roshnee; Damay, Franoise; Rößler, Ulrich K.; Felser, Claudia; Parkin, Stuart S. P.

2017-08-01

Magnetic skyrmions are topologically stable, vortex-like objects surrounded by chiral boundaries that separate a region of reversed magnetization from the surrounding magnetized material. They are closely related to nanoscopic chiral magnetic domain walls, which could be used as memory and logic elements for conventional and neuromorphic computing applications that go beyond Moore’s law. Of particular interest is ‘racetrack memory’, which is composed of vertical magnetic nanowires, each accommodating of the order of 100 domain walls, and that shows promise as a solid state, non-volatile memory with exceptional capacity and performance. Its performance is derived from the very high speeds (up to one kilometre per second) at which chiral domain walls can be moved with nanosecond current pulses in synthetic antiferromagnet racetracks. Because skyrmions are essentially composed of a pair of chiral domain walls closed in on themselves, but are, in principle, more stable to perturbations than the component domain walls themselves, they are attractive for use in spintronic applications, notably racetrack memory. Stabilization of skyrmions has generally been achieved in systems with broken inversion symmetry, in which the asymmetric Dzyaloshinskii-Moriya interaction modifies the uniform magnetic state to a swirling state. Depending on the crystal symmetry, two distinct types of skyrmions have been observed experimentally, namely, Bloch and Néel skyrmions. Here we present the experimental manifestation of another type of skyrmion—the magnetic antiskyrmion—in acentric tetragonal Heusler compounds with D2d crystal symmetry. Antiskyrmions are characterized by boundary walls that have alternating Bloch and Néel type as one traces around the boundary. A spiral magnetic ground-state, which propagates in the tetragonal basal plane, is transformed into an antiskyrmion lattice state under magnetic fields applied along the tetragonal axis over a wide range of temperatures. Direct imaging by Lorentz transmission electron microscopy shows field-stabilized antiskyrmion lattices and isolated antiskyrmions from 100 kelvin to well beyond room temperature, and zero-field metastable antiskyrmions at low temperatures. These results enlarge the family of magnetic skyrmions and pave the way to the engineering of complex bespoke designed skyrmionic structures.

Highlights of experience with a flexible walled test section in the NASA Langley 0.3-meter transonic cryogenic tunnel

NASA Technical Reports Server (NTRS)

Wolf, Stephen W. D.; Ray, Edward J.

1988-01-01

The unique combination of adaptive wall technology with a contonuous flow cryogenic wind tunnel is described. This powerful combination allows wind tunnel users to carry out 2-D tests at flight Reynolds numbers with wall interference essentially eliminated. Validation testing was conducted to support this claim using well tested symmetrical and cambered airfoils at transonic speeds and high Reynolds numbers. The test section hardware has four solid walls, with the floor and ceiling flexible. The method of adapting/shaping the floor and ceiling to eliminate top and bottom wall interference at its source is outlined. Data comparisons for different size models tested and others in several sophisticated 2-D wind tunnels are made. In addition, the effects of Reynolds number, testing at high lift with associated large flexible wall movements, the uniqueness of the adapted wall shapes, and the effects of sidewall boundary layer control are examined. The 0.3-m TCT is now the most advanced 2-D research facility anywhere.

Conceptual design of the early implementation of the NEutron Detector Array (NEDA) with AGATA

NASA Astrophysics Data System (ADS)

Hüyük, Tayfun; Di Nitto, Antonio; Jaworski, Grzegorz; Gadea, Andrés; Javier Valiente-Dobón, José; Nyberg, Johan; Palacz, Marcin; Söderström, Pär-Anders; Jose Aliaga-Varea, Ramon; de Angelis, Giacomo; Ataç, Ayşe; Collado, Javier; Domingo-Pardo, Cesar; Egea, Francisco Javier; Erduran, Nizamettin; Ertürk, Sefa; de France, Gilles; Gadea, Rafael; González, Vicente; Herrero-Bosch, Vicente; Kaşkaş, Ayşe; Modamio, Victor; Moszynski, Marek; Sanchis, Enrique; Triossi, Andrea; Wadsworth, Robert

2016-03-01

The NEutron Detector Array (NEDA) project aims at the construction of a new high-efficiency compact neutron detector array to be coupled with large γ-ray arrays such as AGATA. The application of NEDA ranges from its use as selective neutron multiplicity filter for fusion-evaporation reaction to a large solid angle neutron tagging device. In the present work, possible configurations for the NEDA coupled with the Neutron Wall for the early implementation with AGATA has been simulated, using Monte Carlo techniques, in order to evaluate their performance figures. The goal of this early NEDA implementation is to improve, with respect to previous instruments, efficiency and capability to select multiplicity for fusion-evaporation reaction channels in which 1, 2 or 3 neutrons are emitted. Each NEDA detector unit has the shape of a regular hexagonal prism with a volume of about 3.23l and it is filled with the EJ301 liquid scintillator, that presents good neutron- γ discrimination properties. The simulations have been performed using a fusion-evaporation event generator that has been validated with a set of experimental data obtained in the 58Ni + 56Fe reaction measured with the Neutron Wall detector array.

Solidification studies of monotectic systems

NASA Technical Reports Server (NTRS)

Chang, K.

1982-01-01

Described is an attempt to determine critical wetting temperatures in monotectic systems and to investigate the wetting phase on container walls and the phase preferential wetting of a monotectic solid.

Solid-phase microfibers based on polyethylene glycol modified single-walled carbon nanotubes for the determination of chlorinated organic carriers in textiles.

PubMed

Zhang, Wei-Ya; Sun, Yin; Wang, Cheng-Ming; Wu, Cai-Ying

2011-09-01

Based on polyethylene glycol modified single-walled carbon nanotubes, a novel sol-gel fiber coating was prepared and applied to the headspace microextraction of chlorinated organic carriers (COCs) in textiles by gas chromatography-electron capture detection. The preparation of polyethylene glycol modified single-walled carbon nanotubes and the sol-gel fiber coating process was stated and confirmed by infrared spectra, Raman spectroscopy, and scanning electron microscopy. Several parameters affecting headspace microextraction, including extraction temperature, extraction time, salting-out effect, and desorption time, were optimized by detecting 11 COCs in simulative sweat samples. Compared with the commercial solid-phase microextraction fibers, the sol-gel polyethylene glycol modified single-walled carbon nanotubes fiber showed higher extraction efficiency, better thermal stability, and longer life span. The method detection limits for COCs were in the range from 0.02 to 7.5 ng L(-1) (S/N = 3). The linearity of the developed method varied from 0.001 to 50 μg L(-1) for all analytes, with coefficients of correlation greater than 0.974. The developed method was successfully applied to the analysis of trace COCs in textiles, the recoveries of the analytes indicated that the developed method was considerably useful for the determination of COCs in ecological textile samples.

Coded excitation speeds up the detection of the fundamental flexural guided wave in coated tubes

NASA Astrophysics Data System (ADS)

Song, Xiaojun; Moilanen, Petro; Zhao, Zuomin; Ta, Dean; Pirhonen, Jalmari; Salmi, Ari; Hæeggström, Edward; Myllylä, Risto; Timonen, Jussi; Wang, Weiqi

2016-09-01

The fundamental flexural guided wave (FFGW) permits ultrasonic assessment of the wall thickness of solid waveguides, such as tubes or, e.g., long cortical bones. Recently, an optical non-contact method was proposed for ultrasound excitation and detection with the aim of facilitating the FFGW reception by suppressing the interfering modes from the soft coating. This technique suffers from low SNR and requires iterative physical scanning across the source-receiver distance for 2D-FFT analysis. This means that SNR improvement achieved by temporal averaging becomes time-consuming (several minutes) which reduces the applicability of the technique, especially in time-critical applications such as clinical quantitative ultrasound. To achieve sufficient SNR faster, an ultrasonic excitation by a base-sequence-modulated Golay code (BSGC, 64-bit code pair) on coated tube samples (1-5 mm wall thickness and 5 mm soft coating layer) was used. This approach improved SNR by 21 dB and speeded up the measurement by a factor of 100 compared to using a classical pulse excitation with temporal averaging. The measurement now took seconds instead of minutes, while the ability to determine the wall thickness of the phantoms was maintained. The technique thus allows rapid noncontacting assessment of the wall thickness in coated solid tubes, such as the human bone.

Sensitivity Study of the Wall Interference Correction System (WICS) for Rectangular Tunnels

NASA Technical Reports Server (NTRS)

Walker, Eric L.; Everhart, Joel L.; Iyer, Venkit

2001-01-01

An off-line version of the Wall Interference Correction System (WICS) has been implemented for the NASA Langley National Transonic Facility. The correction capability is currently restricted to corrections for solid wall interference in the model pitch plane for Mach numbers less than 0.45 due to a limitation in tunnel calibration data. A study to assess output sensitivity to measurement uncertainty was conducted to determine standard operational procedures and guidelines to ensure data quality during the testing process. Changes to the current facility setup and design recommendations for installing the WICS code into a new facility are reported.

Pilot-Scale Batch Alkaline Pretreatment of Corn Stover

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuhn, Erik M.; O’Brien, Marykate H.; Ciesielski, Peter N.

The goal of biomass pretreatment is to increase the enzymatic digestibility of the plant cell wall polysaccharides to produce sugars for upgrading to biofuels. Alkaline pretreatment has the ability to solubilize much of the lignin in biomass while the carbohydrates remain insoluble. With an increased research focus to produce high-value products from lignin, a low molecular weight, lignin-rich stream in a biorefinery is desirable. Here, this work reports on batch alkaline pretreatment of corn stover conducted using a three-factor, two-level central composite experimental design in a pilot-scale reactor to determine the relationship between sodium hydroxide (NaOH) loading, temperature, and anthraquinonemore » (AQ) charge on solids solubilization, component yields, and enzymatic digestibility of the residual solids. Operating conditions were 100 to 140 °C, 40 to 70 mg NaOH/g dry corn stover, and 0.05% to 0.2% (w/w) AQ loading. An enzymatic hydrolysis screening study was performed at 2% cellulose loading. Empirical modeling results showed that NaOH loading and temperature are both significant factors, solubilizing 15% to 35% of the solids and up to 54% of the lignin. Enzymatic hydrolysis of the residual solids produced good monomeric glucose (>90%) and xylose (>70%) yields at the more severe pretreatment conditions. We also found that the AQ charge was not a significant factor at the conditions studied, so efforts to reduce xylan and increase lignin solubilization using this compound were not successful. Lastly, while good lignin solubilization was achieved, effectively recovering this stream remains a challenge, and demonstrating performance in continuous reactors is still needed.« less

Pilot-Scale Batch Alkaline Pretreatment of Corn Stover

DOE PAGES

Kuhn, Erik M.; O’Brien, Marykate H.; Ciesielski, Peter N.; ...

2015-12-18

The goal of biomass pretreatment is to increase the enzymatic digestibility of the plant cell wall polysaccharides to produce sugars for upgrading to biofuels. Alkaline pretreatment has the ability to solubilize much of the lignin in biomass while the carbohydrates remain insoluble. With an increased research focus to produce high-value products from lignin, a low molecular weight, lignin-rich stream in a biorefinery is desirable. Here, this work reports on batch alkaline pretreatment of corn stover conducted using a three-factor, two-level central composite experimental design in a pilot-scale reactor to determine the relationship between sodium hydroxide (NaOH) loading, temperature, and anthraquinonemore » (AQ) charge on solids solubilization, component yields, and enzymatic digestibility of the residual solids. Operating conditions were 100 to 140 °C, 40 to 70 mg NaOH/g dry corn stover, and 0.05% to 0.2% (w/w) AQ loading. An enzymatic hydrolysis screening study was performed at 2% cellulose loading. Empirical modeling results showed that NaOH loading and temperature are both significant factors, solubilizing 15% to 35% of the solids and up to 54% of the lignin. Enzymatic hydrolysis of the residual solids produced good monomeric glucose (>90%) and xylose (>70%) yields at the more severe pretreatment conditions. We also found that the AQ charge was not a significant factor at the conditions studied, so efforts to reduce xylan and increase lignin solubilization using this compound were not successful. Lastly, while good lignin solubilization was achieved, effectively recovering this stream remains a challenge, and demonstrating performance in continuous reactors is still needed.« less

A new axi-symmetric element for thin walled structures

NASA Astrophysics Data System (ADS)

Cardoso, Rui P. R.; Yoon, Jeong Whan; Dick, Robert E.

2010-03-01

A new axi-symmetric finite element for thin walled structures is presented in this work. It uses the solid-shell element’s concept with only a single element and multiple integration points along the thickness direction. The cross-section of the element is composed of four nodes with two degrees of freedom each. The proposed formulation overcomes many locking pathologies including transverse shear locking, Poisson’s locking and volumetric locking. For transverse shear locking, the formulation uses the selective reduced integration technique, for Poisson’s locking it uses the enhanced assumed strain (EAS) method with only one enhancing variable. The B-bar approach is used to eliminate the isochoric deformations in the hourglass field while the EAS method is used to alleviate the volumetric locking in the constant part of the deformation tensor. Several examples are shown to demonstrate the performance and accuracy of the proposed element with special focus on the numerical simulations for the beverage can industry.

Haemodynamics of giant cerebral aneurysm: A comparison between the rigid-wall, one-way and two-way FSI models

NASA Astrophysics Data System (ADS)

Khe, A. K.; Cherevko, A. A.; Chupakhin, A. P.; Bobkova, M. S.; Krivoshapkin, A. L.; Orlov, K. Yu

2016-06-01

In this paper a computer simulation of a blood flow in cerebral vessels with a giant saccular aneurysm at the bifurcation of the basilar artery is performed. The modelling is based on patient-specific clinical data (both flow domain geometry and boundary conditions for the inlets and outlets). The hydrodynamic and mechanical parameters are calculated in the frameworks of three models: rigid-wall assumption, one-way FSI approach, and full (two-way) hydroelastic model. A comparison of the numerical solutions shows that mutual fluid- solid interaction can result in qualitative changes in the structure of the fluid flow. Other characteristics of the flow (pressure, stress, strain and displacement) qualitatively agree with each other in different approaches. However, the quantitative comparison shows that accounting for the flow-vessel interaction, in general, decreases the absolute values of these parameters. Solving of the hydroelasticity problem gives a more detailed solution at a cost of highly increased computational time.

Effect of Wall Shear Stress on Corrosion Inhibitor Film Performance

NASA Astrophysics Data System (ADS)

Canto Maya, Christian M.

In oil and gas production, internal corrosion of pipelines causes the highest incidence of recurring failures. Ensuring the integrity of ageing pipeline infrastructure is an increasingly important requirement. One of the most widely applied methods to reduce internal corrosion rates is the continuous injection of chemicals in very small quantities, called corrosion inhibitors. These chemical substances form thin films at the pipeline internal surface that reduce the magnitude of the cathodic and/or anodic reactions. However, the efficacy of such corrosion inhibitor films can be reduced by different factors such as multiphase flow, due to enhanced shear stress and mass transfer effects, loss of inhibitor due to adsorption on other interfaces such as solid particles, bubbles and droplets entrained by the bulk phase, and due to chemical interaction with other incompatible substances present in the stream. The first part of the present project investigated the electrochemical behavior of two organic corrosion inhibitors (a TOFA/DETA imidazolinium, and an alkylbenzyl dimethyl ammonium chloride), with and without an inorganic salt (sodium thiosulfate), and the resulting enhancement. The second part of the work explored the performance of corrosion inhibitor under multiphase (gas/liquid, solid/liquid) flow. The effect of gas/liquid multiphase flow was investigated using small and large scale apparatus. The small scale tests were conducted using a glass cell and a submersed jet impingement attachment with three different hydrodynamic patterns (water jet, CO 2 bubbles impact, and water vapor cavitation). The large scale experiments were conducted applying different flow loops (hilly terrain and standing slug systems). Measurements of weight loss, linear polarization resistance (LPR), and adsorption mass (using an electrochemical quartz crystal microbalance, EQCM) were used to quantify the effect of wall shear stress on the performance and integrity of corrosion inhibitor films. Different scenarios were evaluated in this section of the work, such as the loss of corrosion inhibitor due to the formation of foam, and the effect of different substrates on the adsorption of corrosion inhibitor. Erosion/corrosion effects due to solids carried by a multiphase flow were investigated both on a small and large scale. Small scale experiments were performed in order to determine whether the corrosion inhibitor concentration was diminished because of adsorption onto the large surface area of entrained solid particles. The large scale experiments were done to evaluate the effect of mechanical erosion corrosion on inhibitor film performance, and vice versa. The analysis of the results obtained by electrochemical characterization shows that the adsorption mechanism having a corrosion inhibitor competing with water molecules for a place on the steel surface is an accurate approach to describe this phenomenon. From the experimental results obtained in the multiphase part of this research project, it can be concluded that the performance of corrosion inhibitor films is not significantly impacted by mechanical forces alone; even under the worst case scenarios tested here (standing slug and erosion/corrosion). Reduction of inhibitor performance was found to be primarily due to the loss of inhibitor due to consumption by adsorption particularly when a gas phase was present, leading to foam formation.

Transparent and flexible supercapacitors with single walled carbon nanotube thin film electrodes.

PubMed

Yuksel, Recep; Sarioba, Zeynep; Cirpan, Ali; Hiralal, Pritesh; Unalan, Husnu Emrah

2014-09-10

We describe a simple process for the fabrication of transparent and flexible, solid-state supercapacitors. Symmetric electrodes made up of binder-free single walled carbon nanotube (SWCNT) thin films were deposited onto polydimethylsiloxane substrates by vacuum filtration followed by a stamping method, and solid-state supercapacitor devices were assembled using a gel electrolyte. An optical transmittance of 82% was found for 0.02 mg of SWCNTs, and a specific capacitance of 22.2 F/g was obtained. The power density can reach to 41.5 kW · kg(-1) and shows good capacity retention (94%) upon cycling over 500 times. Fabricated supercapacitors will be relevant for the realization of transparent and flexible devices with energy storage capabilities, displays and touch screens in particular.

Turbulent flame-wall interaction: a DNS study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Jackie; Hawkes, Evatt R; Sankaran, Ramanan

2010-01-01

A turbulent flame-wall interaction (FWI) configuration is studied using three-dimensional direct numerical simulation (DNS) and detailed chemical kinetics. The simulations are used to investigate the effects of the wall turbulent boundary layer (i) on the structure of a hydrogen-air premixed flame, (ii) on its near-wall propagation characteristics and (iii) on the spatial and temporal patterns of the convective wall heat flux. Results show that the local flame thickness and propagation speed vary between the core flow and the boundary layer, resulting in a regime change from flamelet near the channel centreline to a thickened flame at the wall. This findingmore » has strong implications for the modelling of turbulent combustion using Reynolds-averaged Navier-Stokes or large-eddy simulation techniques. Moreover, the DNS results suggest that the near-wall coherent turbulent structures play an important role on the convective wall heat transfer by pushing the hot reactive zone towards the cold solid surface. At the wall, exothermic radical recombination reactions become important, and are responsible for approximately 70% of the overall heat release rate at the wall. Spectral analysis of the convective wall heat flux provides an unambiguous picture of its spatial and temporal patterns, previously unobserved, that is directly related to the spatial and temporal characteristic scalings of the coherent near-wall turbulent structures.« less

Blanket design and optimization demonstrations of the first wall/blanket/shield design and optimization system (BSDOS).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gohar, Y.; Nuclear Engineering Division

2005-05-01

In fusion reactors, the blanket design and its characteristics have a major impact on the reactor performance, size, and economics. The selection and arrangement of the blanket materials, dimensions of the different blanket zones, and different requirements of the selected materials for a satisfactory performance are the main parameters, which define the blanket performance. These parameters translate to a large number of variables and design constraints, which need to be simultaneously considered in the blanket design process. This represents a major design challenge because of the lack of a comprehensive design tool capable of considering all these variables to definemore » the optimum blanket design and satisfying all the design constraints for the adopted figure of merit and the blanket design criteria. The blanket design capabilities of the First Wall/Blanket/Shield Design and Optimization System (BSDOS) have been developed to overcome this difficulty and to provide the state-of-the-art research and design tool for performing blanket design analyses. This paper describes some of the BSDOS capabilities and demonstrates its use. In addition, the use of the optimization capability of the BSDOS can result in a significant blanket performance enhancement and cost saving for the reactor design under consideration. In this paper, examples are presented, which utilize an earlier version of the ITER solid breeder blanket design and a high power density self-cooled lithium blanket design for demonstrating some of the BSDOS blanket design capabilities.« less

Blanket Design and Optimization Demonstrations of the First Wall/Blanket/Shield Design and Optimization System (BSDOS)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gohar, Yousry

2005-05-15

In fusion reactors, the blanket design and its characteristics have a major impact on the reactor performance, size, and economics. The selection and arrangement of the blanket materials, dimensions of the different blanket zones, and different requirements of the selected materials for a satisfactory performance are the main parameters, which define the blanket performance. These parameters translate to a large number of variables and design constraints, which need to be simultaneously considered in the blanket design process. This represents a major design challenge because of the lack of a comprehensive design tool capable of considering all these variables to definemore » the optimum blanket design and satisfying all the design constraints for the adopted figure of merit and the blanket design criteria. The blanket design capabilities of the First Wall/Blanket/Shield Design and Optimization System (BSDOS) have been developed to overcome this difficulty and to provide the state-of-the-art research and design tool for performing blanket design analyses. This paper describes some of the BSDOS capabilities and demonstrates its use. In addition, the use of the optimization capability of the BSDOS can result in a significant blanket performance enhancement and cost saving for the reactor design under consideration. In this paper, examples are presented, which utilize an earlier version of the ITER solid breeder blanket design and a high power density self-cooled lithium blanket design for demonstrating some of the BSDOS blanket design capabilities.« less

Application of Pressure-Based Wall Correction Methods to Two NASA Langley Wind Tunnels

NASA Technical Reports Server (NTRS)

Iyer, V.; Everhart, J. L.

2001-01-01

This paper is a description and status report on the implementation and application of the WICS wall interference method to the National Transonic Facility (NTF) and the 14 x 22-ft subsonic wind tunnel at the NASA Langley Research Center. The method calculates free-air corrections to the measured parameters and aerodynamic coefficients for full span and semispan models when the tunnels are in the solid-wall configuration. From a data quality point of view, these corrections remove predictable bias errors in the measurement due to the presence of the tunnel walls. At the NTF, the method is operational in the off-line and on-line modes, with three tests already computed for wall corrections. At the 14 x 22-ft tunnel, initial implementation has been done based on a test on a full span wing. This facility is currently scheduled for an upgrade to its wall pressure measurement system. With the addition of new wall orifices and other instrumentation upgrades, a significant improvement in the wall correction accuracy is expected.

Method and apparatus for maximizing throughput of indirectly heated rotary kilns

DOE Office of Scientific and Technical Information (OSTI.GOV)

Coates, Ralph L; Smoot, Douglas L.; Hatfield, Kent E

An apparatus and method for achieving improved throughput capacity of indirectly heated rotary kilns used to produce pyrolysis products such as shale oils or coal oils that are susceptible to decomposition by high kiln wall temperatures is disclosed. High throughput is achieved by firing the kiln such that optimum wall temperatures are maintained beginning at the point where the materials enter the heating section of the kiln and extending to the point where the materials leave the heated section. Multiple high velocity burners are arranged such that combustion products directly impact on the area of the kiln wall covered internallymore » by the solid material being heated. Firing rates for the burners are controlled to maintain optimum wall temperatures.« less

Method and apparatus for maximizing throughput of indirectly heated rotary kilns

DOEpatents

Coates, Ralph L; Smoot, L. Douglas; Hatfield, Kent E

2012-10-30

An apparatus and method for achieving improved throughput capacity of indirectly heated rotary kilns used to produce pyrolysis products such as shale oils or coal oils that are susceptible to decomposition by high kiln wall temperatures is disclosed. High throughput is achieved by firing the kiln such that optimum wall temperatures are maintained beginning at the point where the materials enter the heating section of the kiln and extending to the point where the materials leave the heated section. Multiple high velocity burners are arranged such that combustion products directly impact on the area of the kiln wall covered internally by the solid material being heated. Firing rates for the burners are controlled to maintain optimum wall temperatures.

Mechanical Characterization of the Vessel Wall by Data Assimilation of Intravascular Ultrasound Studies

PubMed Central

Maso Talou, Gonzalo D.; Blanco, Pablo J.; Ares, Gonzalo D.; Guedes Bezerra, Cristiano; Lemos, Pedro A.; Feijóo, Raúl A.

2018-01-01

Atherosclerotic plaque rupture and erosion are the most important mechanisms underlying the sudden plaque growth, responsible for acute coronary syndromes and even fatal cardiac events. Advances in the understanding of the culprit plaque structure and composition are already reported in the literature, however, there is still much work to be done toward in-vivo plaque visualization and mechanical characterization to assess plaque stability, patient risk, diagnosis and treatment prognosis. In this work, a methodology for the mechanical characterization of the vessel wall plaque and tissues is proposed based on the combination of intravascular ultrasound (IVUS) imaging processing, data assimilation and continuum mechanics models within a high performance computing (HPC) environment. Initially, the IVUS study is gated to obtain volumes of image sequences corresponding to the vessel of interest at different cardiac phases. These sequences are registered against the sequence of the end-diastolic phase to remove transversal and longitudinal rigid motions prescribed by the moving environment due to the heartbeat. Then, optical flow between the image sequences is computed to obtain the displacement fields of the vessel (each associated to a certain pressure level). The obtained displacement fields are regarded as observations within a data assimilation paradigm, which aims to estimate the material parameters of the tissues within the vessel wall. Specifically, a reduced order unscented Kalman filter is employed, endowed with a forward operator which amounts to address the solution of a hyperelastic solid mechanics model in the finite strain regime taking into account the axially stretched state of the vessel, as well as the effect of internal and external forces acting on the arterial wall. Due to the computational burden, a HPC approach is mandatory. Hence, the data assimilation and computational solid mechanics computations are parallelized at three levels: (i) a Kalman filter level; (ii) a cardiac phase level; and (iii) a mesh partitioning level. To illustrate the capabilities of this novel methodology toward the in-vivo analysis of patient-specific vessel constituents, mechanical material parameters are estimated using in-silico and in-vivo data retrieved from IVUS studies. Limitations and potentials of this approach are exposed and discussed. PMID:29643815

Analytical solutions for combined close-contact and natural convection melting in horizontal cylindrical heat storage capsule

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saitoh, T.S.; Hoshi, A.

1998-07-01

Melting and solidification of a phase change material (PCM) in a capsule is of practical importance in latent heat thermal energy storage (LHTES) systems which are considered to be very promising to reduce a peak demand of electricity in the summer season and carbon dioxide (CO{sub 2}) emissions. Two melting modes are involved in melting of capsules. One is close-contact melting between the solid bulk and the capsule wall, and another is natural convection melting in the liquid region. Close-contact melting processes for a single enclosure have been solved using several numerical methods (e.g., Saitoh and Kato (1994)). In additionmore » close-contact melting heat transfer characteristics including melt flow in the liquid film under inner wall temperature distribution were analyzed and simple approximate equations were already presented by Saitoh and Hoshi (1997). The effects of Stefan number and variable temperature profile etc. were clarified in detail. And the melting velocity of the solid bulk under various conditions was also studied theoretically. In addition the effects of variable inner wall temperature on molten mass fraction were investigated. The present paper reports analytical solutions for combined close-contact and natural convection melting in horizontal cylindrical capsule. Moreover, natural convection melting in the liquid region were analyzed in this report. The upper interface shape of the solid bulk is approximated by a circular arc throughout the melting process. For the sake of verification, close-contact melting heat-transfer characteristics including natural convection in the liquid region were studied experimentally. Apparent shift of upper solid-liquid interface is good agreement with the experiment. The present simple approximate solutions will be useful to facilitate designing of the practical capsule bed LHTES systems.« less

An investigation of voids formation mechanisms and their effects on freeze and thaw processes of lithium and lithium fluoride

NASA Technical Reports Server (NTRS)

El-Genk, Mohamed S.; Yang, Jae-Young

1991-01-01

The mechanisms of void formation during the cooldown and freezing of lithium coolant within the primary loop of SP-100 type systems are investigated. These mechanisms are: (1) homogeneous nucleation; (2) heterogeneous nucleation; (3) normal segregation of helium gas dissolved in liquid lithium; and (4) shrinkage of lithium during freezing. To evaluate the void formation potential due to segregation, a numerical scheme that couples the freezing and mass diffusion processes in both the solid and liquid regions is developed. The results indicated that the formation of He bubbles is unlikely by either homogeneous or heterogeneous nucleation during the cooldown process. However, homogeneous nucleation of He bubbles following the segregation of dissolved He in liquid lithium ahead of the solid-liquid interface is likely to occur. Results also show that total volume of He void is insignificant when compared to that of shrinkage voids. In viewing this, the subsequent research focuses on the effects of shrinkage void forming during freezing of lithium on subsequent thaw processes are investigated using a numerical scheme that is based on a single (solid/liquid) cell approach. The cases of lithium-fluoride are also investigated to show the effect of larger volume shrinkage upon freezing on the freeze and thaw processes. Results show that a void forming at the wall appreciably reduces the solid-liquid interface velocity, during both freeze and thaw, and causes a substantial rise in the wall temperature during thaw. However, in the case of Li, the maximum wall temperature was much lower than the melting temperature of PWC-11, which is used as the structure material in the SP-100 system. Hence, it is included that a formation of hot spots is unlikely during the startup or restart of the SP-100 system.

MHD convective heat transfer in a discretely heated square cavity with conductive inner block using two-phase nanofluid model.

PubMed

Alsabery, A I; Sheremet, M A; Chamkha, A J; Hashim, I

2018-05-09

The problem of steady, laminar natural convection in a discretely heated and cooled square cavity filled by an alumina/water nanofluid with a centered heat-conducting solid block under the effects of inclined uniform magnetic field, Brownian diffusion and thermophoresis is studied numerically by using the finite difference method. Isothermal heaters and coolers are placed along the vertical walls and the bottom horizontal wall, while the upper horizontal wall is kept adiabatic. Water-based nanofluids with alumina nanoparticles are chosen for investigation. The governing parameters of this study are the Rayleigh number (10 3  ≤ Ra ≤ 10 6 ), the Hartmann number (0 ≤ Ha ≤ 50), thermal conductivity ratio (0.28 ≤ k w  ≤ 16), centered solid block size (0.1 ≤ D ≤ 0.7) and the nanoparticles volume fraction (0 ≤ ϕ ≤ 0.04). The developed computational code is validated comprehensively using the grid independency test and numerical and experimental data of other authors. The obtained results reveal that the effects of the thermal conductivity ratio, centered solid block size and the nanoparticles volume fraction are non-linear for the heat transfer rate. Therefore, it is possible to find optimal parameters for the heat transfer enhancement in dependence on the considered system. Moreover, high values of the Rayleigh number and nanoparticles volume fraction characterize homogeneous distributions of nanoparticles inside the cavity. High concentration of nanoparticles can be found near the centered solid block where thermal plumes from the local heaters interact.

Roughness topographical effects on mean momentum and stress budgets in developed turbulent channel flows

NASA Astrophysics Data System (ADS)

Aghaei Jouybari, Mostafa; Yuan, Junlin

2017-11-01

Direct numerical simulations of turbulent channel flows are carried out over two surfaces: a synthesized sand-grain surface and a realistic turbine roughness that is characterized by more prominent large-scale surface features. To separate the effects of wall-normal variation of the roughness area fraction from the (true) variation of flow statistics, the governing equations are area-averaged using intrinsic averaging, contrary to the usually practice based on the total area (i.e., superficial averaging). Additional terms appear in the mean-momentum equation resulted from the wall-normal variation of the solid fraction and play a role in the near-wall balance. Results from surfaces with a step solidity function (e.g., cubes) will also be discussed. Compared to the sand grains, the turbine surface generates stronger form-induced fluctuations, despite weaker dispersive shear stress. This is associated with more significant form-induced productions (comparable to shear production) in Reynolds stress budgets, weaker pressure work, and, consequently, more anisotropic redistribution of turbulent kinetic energy in the roughness sublayer, which potentially leads to different turbulent responses between the two surfaces in non-equilibrium flows.

Analysis of pinching in deterministic particle separation

NASA Astrophysics Data System (ADS)

Risbud, Sumedh; Luo, Mingxiang; Frechette, Joelle; Drazer, German

2011-11-01

We investigate the problem of spherical particles vertically settling parallel to Y-axis (under gravity), through a pinching gap created by an obstacle (spherical or cylindrical, center at the origin) and a wall (normal to X axis), to uncover the physics governing microfluidic separation techniques such as deterministic lateral displacement and pinched flow fractionation: (1) theoretically, by linearly superimposing the resistances offered by the wall and the obstacle separately, (2) computationally, using the lattice Boltzmann method for particulate systems and (3) experimentally, by conducting macroscopic experiments. Both, theory and simulations, show that for a given initial separation between the particle centre and the Y-axis, presence of a wall pushes the particles closer to the obstacle, than its absence. Experimentally, this is expected to result in an early onset of the short-range repulsive forces caused by solid-solid contact. We indeed observe such an early onset, which we quantify by measuring the asymmetry in the trajectories of the spherical particles around the obstacle. This work is partially supported by the National Science Foundation Grant Nos. CBET- 0731032, CMMI-0748094, and CBET-0954840.

Fluid Structural Analysis of Human Cerebral Aneurysm Using Their Own Wall Mechanical Properties

PubMed Central

Valencia, Alvaro; Burdiles, Patricio; Ignat, Miguel; Mura, Jorge; Rivera, Rodrigo; Sordo, Juan

2013-01-01

Computational Structural Dynamics (CSD) simulations, Computational Fluid Dynamics (CFD) simulation, and Fluid Structure Interaction (FSI) simulations were carried out in an anatomically realistic model of a saccular cerebral aneurysm with the objective of quantifying the effects of type of simulation on principal fluid and solid mechanics results. Eight CSD simulations, one CFD simulation, and four FSI simulations were made. The results allowed the study of the influence of the type of material elements in the solid, the aneurism's wall thickness, and the type of simulation on the modeling of a human cerebral aneurysm. The simulations use their own wall mechanical properties of the aneurysm. The more complex simulation was the FSI simulation completely coupled with hyperelastic Mooney-Rivlin material, normal internal pressure, and normal variable thickness. The FSI simulation coupled in one direction using hyperelastic Mooney-Rivlin material, normal internal pressure, and normal variable thickness is the one that presents the most similar results with respect to the more complex FSI simulation, requiring one-fourth of the calculation time. PMID:24151523

A hybrid method for airway segmentation and automated measurement of bronchial wall thickness on CT.

PubMed

Xu, Ziyue; Bagci, Ulas; Foster, Brent; Mansoor, Awais; Udupa, Jayaram K; Mollura, Daniel J

2015-08-01

Inflammatory and infectious lung diseases commonly involve bronchial airway structures and morphology, and these abnormalities are often analyzed non-invasively through high resolution computed tomography (CT) scans. Assessing airway wall surfaces and the lumen are of great importance for diagnosing pulmonary diseases. However, obtaining high accuracy from a complete 3-D airway tree structure can be quite challenging. The airway tree structure has spiculated shapes with multiple branches and bifurcation points as opposed to solid single organ or tumor segmentation tasks in other applications, hence, it is complex for manual segmentation as compared with other tasks. For computerized methods, a fundamental challenge in airway tree segmentation is the highly variable intensity levels in the lumen area, which often causes a segmentation method to leak into adjacent lung parenchyma through blurred airway walls or soft boundaries. Moreover, outer wall definition can be difficult due to similar intensities of the airway walls and nearby structures such as vessels. In this paper, we propose a computational framework to accurately quantify airways through (i) a novel hybrid approach for precise segmentation of the lumen, and (ii) two novel methods (a spatially constrained Markov random walk method (pseudo 3-D) and a relative fuzzy connectedness method (3-D)) to estimate the airway wall thickness. We evaluate the performance of our proposed methods in comparison with mostly used algorithms using human chest CT images. Our results demonstrate that, on publicly available data sets and using standard evaluation criteria, the proposed airway segmentation method is accurate and efficient as compared with the state-of-the-art methods, and the airway wall estimation algorithms identified the inner and outer airway surfaces more accurately than the most widely applied methods, namely full width at half maximum and phase congruency. Copyright © 2015. Published by Elsevier B.V.

Analysis of film cooling in rocket nozzles

NASA Technical Reports Server (NTRS)

Woodbury, Keith A.

1992-01-01

Computational Fluid Dynamics (CFD) programs are customarily used to compute details of a flow field, such as velocity fields or species concentrations. Generally they are not used to determine the resulting conditions at a solid boundary such as wall shear stress or heat flux. However, determination of this information should be within the capability of a CFD code, as the code supposedly contains appropriate models for these wall conditions. Before such predictions from CFD analyses can be accepted, the credibility of the CFD codes upon which they are based must be established. This report details the progress made in constructing a CFD model to predict the heat transfer to the wall in a film cooled rocket nozzle. Specifically, the objective of this work is to use the NASA code FDNS to predict the heat transfer which will occur during the upcoming hot-firing of the Pratt & Whitney 40K subscale nozzle (1Q93). Toward this end, an M = 3 wall jet is considered, and the resulting heat transfer to the wall is computed. The values are compared against experimental data available in Reference 1. Also, FDNS's ability to compute heat flux in a reacting flow will be determined by comparing the code's predictions against calorimeter data from the hot firing of a 40K combustor. The process of modeling the flow of combusting gases through the Pratt & Whitney 40K subscale combustor and nozzle is outlined. What follows in this report is a brief description of the FDNS code, with special emphasis on how it handles solid wall boundary conditions. The test cases and some FDNS solution are presented next, along with comparison to experimental data. The process of modeling the flow through a chamber and a nozzle using the FDNS code will also be outlined.

Arabidopsis thalianafrom Polarization Transfer Solid-State NMR

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, Paul B; Wang, Tuo; Park, Yong Bum

2014-07-23

Polysaccharide-rich plant cell walls are hydrated under functional conditions, but the molecular interactions between water and polysaccharides in the wall have not been investigated. In this work, we employ polarization transfer solid-state NMR techniques to study the hydration of primary-wall polysaccharides of the model plant, Arabidopsis thaliana. By transferring water 1H polarization to polysaccharides through distance- and mobility-dependent 1H–1H dipolar couplings and detecting it through polysaccharide 13C signals, we obtain information about water proximity to cellulose, hemicellulose, and pectins as well as water mobility. Both intact and partially extracted cell wall samples are studied. Our results show that water–pectin polarizationmore » transfer is much faster than water–cellulose polarization transfer in all samples, but the extent of extraction has a profound impact on the water–polysaccharide spin diffusion. Removal of calcium ions and the consequent extraction of homogalacturonan (HG) significantly slowed down spin diffusion, while further extraction of matrix polysaccharides restored the spin diffusion rate. These trends are observed in cell walls with similar water content, thus they reflect inherent differences in the mobility and spatial distribution of water. Combined with quantitative analysis of the polysaccharide contents, our results indicate that calcium ions and HG gelation increase the amount of bound water, which facilitates spin diffusion, while calcium removal disrupts the gel and gives rise to highly dynamic water, which slows down spin diffusion. The recovery of spin diffusion rates after more extensive extraction is attributed to increased water-exposed surface areas of the polysaccharides. Water–pectin spin diffusion precedes water–cellulose spin diffusion, lending support to the single-network model of plant primary walls in which a substantial fraction of the cellulose surface is surrounded by pectins.« less

The ALE Discontinuous Galerkin Method for the Simulatio of Air Flow Through Pulsating Human Vocal Folds

NASA Astrophysics Data System (ADS)

Feistauer, Miloslav; Kučera, Václav; Prokopová, Jaroslav; Horáček, Jaromír

2010-09-01

The aim of this work is the simulation of viscous compressible flows in human vocal folds during phonation. The computational domain is a bounded subset of IR2, whose geometry mimics the shape of the human larynx. During phonation, parts of the solid impermeable walls are moving in a prescribed manner, thus simulating the opening and closing of the vocal chords. As the governing equations we take the compressible Navier-Stokes equations in ALE form. Space semidiscretization is carried out by the discontinuous Galerkin method combined with a linearized semi-implicit approach. Numerical experiments are performed with the resulting scheme.

Welded Titanium Case for Space-Probe Rocket Motor

NASA Technical Reports Server (NTRS)

Brothers, A. J.; Boundy, R. A.; Martens, H. E.; Jaffe, L. D.

1959-01-01

The high strength-to-weight ratio of titanium alloys suggests their use for solid-propellant rocket-motor cases for high-performance orbiting or space-probe vehicles. The paper describes the fabrication of a 6-in.-diam., 0.025-in.-wall rocket-motor from the 6A1-4V titanium alloy. The rocket-motor case, used in the fourth stage of a successful JPL-NASA lunar-probe flight, was constructed using a design previously proven satisfactory for Type 410 stainless steel. The nature and scope of the problems peculiar to the use of the titanium alloy, which effected an average weight saving of 34%, are described.

Intense photoluminescence from dried double-stranded DNA and single-walled carbon nanotube hybrid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ito, M.; Kobayashi, T.; Ito, Y.

2014-01-27

Semiconducting single-walled carbon nanotubes (SWNTs) show near-infrared photoluminescence (PL) when they are individually isolated. This was an obstacle to use photonic properties of SWNTs on a solid surface. We show that SWNTs wrapped with DNA maintain intense PL under the dry conditions. SWNTs are well isolated individually by DNA even when the DNA-SWNT hybrids are agglomerated. This finding opens up application of SWNTs to photonic devices.

A Mitogen-Activated Protein Kinase Tmk3 Participates in High Osmolarity Resistance, Cell Wall Integrity Maintenance and Cellulase Production Regulation in Trichoderma reesei

PubMed Central

Wang, Mingyu; Zhao, Qiushuang; Yang, Jinghua; Jiang, Baojie; Wang, Fangzhong; Liu, Kuimei; Fang, Xu

2013-01-01

The mitogen-activated protein kinase (MAPK) pathways are important signal transduction pathways conserved in essentially all eukaryotes, but haven't been subjected to functional studies in the most important cellulase-producing filamentous fungus Trichoderma reesei. Previous reports suggested the presence of three MAPKs in T. reesei: Tmk1, Tmk2, and Tmk3. By exploring the phenotypic features of T. reesei Δtmk3, we first showed elevated NaCl sensitivity and repressed transcription of genes involved in glycerol/trehalose biosynthesis under higher osmolarity, suggesting Tmk3 participates in high osmolarity resistance via derepression of genes involved in osmotic stabilizer biosynthesis. We also showed significant downregulation of genes encoding chitin synthases and a β-1,3-glucan synthase, decreased chitin content, ‘budded’ hyphal appearance typical to cell wall defective strains, and increased sensitivity to calcofluor white/Congo red in the tmk3 deficient strain, suggesting Tmk3 is involved in cell wall integrity maintenance in T. reesei. We further observed the decrease of cellulase transcription and production in T. reesei Δtmk3 during submerged cultivation, as well as the presence of MAPK phosphorylation sites on known transcription factors involved in cellulase regulation, suggesting Tmk3 is also involved in the regulation of cellulase production. Finally, the expression of cell wall integrity related genes, the expression of cellulase coding genes, cellulase production and biomass accumulation were compared between T. reesei Δtmk3 grown in solid state media and submerged media, showing a strong restoration effect in solid state media from defects resulted from tmk3 deletion. These results showed novel physiological processes that fungal Hog1-type MAPKs are involved in, and present the first experimental investigation of MAPK signaling pathways in T. reesei. Our observations on the restoration effect during solid state cultivation suggest that T. reesei is evolved to favor solid state growth, bringing up the proposal that the submerged condition normally used during investigations on fungal physiology might be misleading. PMID:23991059

Hydrodynamic Stability Analysis of Particle-Laden Solid Rocket Motors

NASA Astrophysics Data System (ADS)

Elliott, T. S.; Majdalani, J.

2014-11-01

Fluid-wall interactions within solid rocket motors can result in parietal vortex shedding giving rise to hydrodynamic instabilities, or unsteady waves, that translate into pressure oscillations. The oscillations can result in vibrations observed by the rocket, rocket subsystems, or payload, which can lead to changes in flight characteristics, design failure, or other undesirable effects. For many years particles have been embedded in solid rocket propellants with the understanding that their presence increases specific impulse and suppresses fluctuations in the flowfield. This study utilizes a two dimensional framework to understand and quantify the aforementioned two-phase flowfield inside a motor case with a cylindrical grain perforation. This is accomplished through the use of linearized Navier-Stokes equations with the Stokes drag equation and application of the biglobal ansatz. Obtaining the biglobal equations for analysis requires quantification of the mean flowfield within the solid rocket motor. To that end, the extended Taylor-Culick form will be utilized to represent the gaseous phase of the mean flowfield while the self-similar form will be employed for the particle phase. Advancing the mean flowfield by quantifying the particle mass concentration with a semi-analytical solution the finalized mean flowfield is combined with the biglobal equations resulting in a system of eight partial differential equations. This system is solved using an eigensolver within the framework yielding the entire spectrum of eigenvalues, frequency and growth rate components, at once. This work will detail the parametric analysis performed to demonstrate the stabilizing and destabilizing effects of particles within solid rocket combustion.

Direct simulation of isothermal-wall supersonic channel flow

NASA Technical Reports Server (NTRS)

Coleman, Gary N.

1993-01-01

The motivation for this work is the fact that in turbulent flows where compressibility effects are important, they are often poorly understood. A few examples of such flows are those associated with astrophysical phenomena and those found in combustion chambers, supersonic diffusers and nozzles, and over high-speed airfoils. For this project, we are primarily interested in compressibility effects near solid surfaces. Our main objective is an improved understanding of the fundamentals of compressible wall-bounded turbulence, which can in turn be used to cast light upon modeling concepts such as the Morkovin hypothesis and the Van Driest transformation. To this end, we have performed a direct numerical simulation (DNS) study of supersonic turbulent flow in a plane channel with constant-temperature walls. All of the relevant spatial and temporal scales are resolved so that no sub grid scale or turbulence model is necessary. The channel geometry was chosen so that finite Mach number effects can be isolated by comparing the present results to well established incompressible channel data. Here the fluid is assumed to be an ideal gas with constant specific heats, constant Prandtl number, and power-law temperature-dependent viscosity. Isothermal-wall boundary conditions are imposed so that a statistically stationary state may be obtained. The flow is driven by a uniform (in space) body force (rather than a mean pressure gradient) to preserve stream wise homogeneity, with the body force defined so that the total mass flux is constant.

A new model for fluid velocity slip on a solid surface.

PubMed

Shu, Jian-Jun; Teo, Ji Bin Melvin; Chan, Weng Kong

2016-10-12

A general adsorption model is developed to describe the interactions between near-wall fluid molecules and solid surfaces. This model serves as a framework for the theoretical modelling of boundary slip phenomena. Based on this adsorption model, a new general model for the slip velocity of fluids on solid surfaces is introduced. The slip boundary condition at a fluid-solid interface has hitherto been considered separately for gases and liquids. In this paper, we show that the slip velocity in both gases and liquids may originate from dynamical adsorption processes at the interface. A unified analytical model that is valid for both gas-solid and liquid-solid slip boundary conditions is proposed based on surface science theory. The corroboration with the experimental data extracted from the literature shows that the proposed model provides an improved prediction compared to existing analytical models for gases at higher shear rates and close agreement for liquid-solid interfaces in general.

Effects of walking in deep venous thrombosis: a new integrated solid and fluid mechanics model.

PubMed

López, Josep M; Fortuny, Gerard; Puigjaner, Dolors; Herrero, Joan; Marimon, Francesc; Garcia-Bennett, Josep

2017-05-01

Deep venous thrombosis (DVT) is a common disease. Large thrombi in venous vessels cause bad blood circulation and pain; and when a blood clot detaches from a vein wall, it causes an embolism whose consequences range from mild to fatal. Walking is recommended to DVT patients as a therapeutical complement. In this study the mechanical effects of walking on a specific patient of DVT were simulated by means of an unprecedented integration of 3 elements: a real geometry, a biomechanical model of body tissues, and a computational fluid dynamics study. A set of computed tomography images of a patient's leg with a thrombus in the popliteal vein was employed to reconstruct a geometry model. Then a biomechanical model was used to compute the new deformed geometry of the vein as a function of the fiber stretch level of the semimembranosus muscle. Finally, a computational fluid dynamics study was performed to compute the blood flow and the wall shear stress (WSS) at the vein and thrombus walls. Calculations showed that either a lengthening or shortening of the semimembranosus muscle led to a decrease of WSS levels up to 10%. Notwithstanding, changes in blood viscosity properties or blood flow rate may easily have a greater impact in WSS. Copyright © 2016 John Wiley & Sons, Ltd.

A Numerical Multiscale Framework for Modeling Patient-Specific Coronary Artery Bypass Surgeries

NASA Astrophysics Data System (ADS)

Ramachandra, Abhay B.; Kahn, Andrew; Marsden, Alison

2014-11-01

Coronary artery bypass graft (CABG) surgery is performed to revascularize diseased coronary arteries, using arterial, venous or synthetic grafts. Vein grafts, used in more than 70% of procedures, have failure rates as high as 50% in less than 10 years. Hemodynamics is known to play a key role in the mechano-biological response of vein grafts, but current non-invasive imaging techniques cannot fully characterize the hemodynamic and biomechanical environment. We numerically compute hemodynamics and wall mechanics in patient-specific 3D CABG geometries using stabilized finite element methods. The 3D patient-specific domain is coupled to a 0D lumped parameter circulatory model and parameters are tuned to match patient-specific blood pressures, stroke volumes, heart rates and heuristic flow-split values. We quantify differences in hemodynamics between arterial and venous grafts and discuss possible correlations to graft failure. Extension to a deformable wall approximation will also be discussed. The quantification of wall mechanics and hemodynamics is a necessary step towards coupling continuum models in solid and fluid mechanics with the cellular and sub-cellular responses of grafts, which in turn, should lead to a more accurate prediction of the long term outcome of CABG surgeries, including predictions of growth and remodeling.

Viscous flow past a collapsible channel as a model for self-excited oscillation of blood vessels.

PubMed

Tang, Chao; Zhu, Luoding; Akingba, George; Lu, Xi-Yun

2015-07-16

Motivated by collapse of blood vessels for both healthy and diseased situations under various circumstances in human body, we have performed computational studies on an incompressible viscous fluid past a rigid channel with part of its upper wall being replaced by a deformable beam. The Navier-Stokes equations governing the fluid flow are solved by a multi-block lattice Boltzmann method and the structural equation governing the elastic beam motion by a finite difference method. The mutual coupling of the fluid and solid is realized by the momentum exchange scheme. The present study focuses on the influences of the dimensionless parameters controlling the fluid-structure system on the collapse and self-excited oscillation of the beam and fluid dynamics downstream. The major conclusions obtained in this study are described as follows. The self-excited oscillation can be intrigued by application of an external pressure on the elastic portion of the channel and the part of the beam having the largest deformation tends to occur always towards the end portion of the deformable wall. The blood pressure and wall shear stress undergo significant variations near the portion of the greatest oscillation. The stretching motion has the most contribution to the total potential elastic energy of the oscillating beam. Copyright © 2015 Elsevier Ltd. All rights reserved.

Rise of Racetrack Memory! Domain Wall Spin-Orbitronics

NASA Astrophysics Data System (ADS)

Parkin, Stuart

Memory-storage devices based on the current controlled motion of a series of domain walls (DWs) in magnetic racetracks promise performance and reliability beyond that of conventional magnetic disk drives and solid state storage devices (1). Racetracks that are formed from atomically thin, perpendicularly magnetized nano-wires, interfaced with adjacent metal layers with high spin-orbit coupling, give rise to domain walls that exhibit a chiral Néel structure (2). These DWs can be moved very efficiently with current via chiral spin-orbit torques (2,3). Record-breaking current-induced DW speeds exceeding 1,000 m/sec are found in synthetic antiferromagnetic structures (3) in which the net magnetization of the DWs is tuned to almost zero, making them ``invisible''. Based on these recent discoveries, Racetrack Memory devices have the potential to operate on picosecond timescales and at densities more than 100 times greater than other memory technologies. (1) S.S.P. Parkin et al., Science 320, 5873 (2008); S.S.P. Parkin and S.-H. Yang, Nat. Nano. 10, 195 (2015). (2) K.-S. Ryu metal. Nat. Nano. 8, 527 (2013). (3) S.-H. Yang, K.-S. Ryu and S.S.P. Parkin, Nat. Nano. 10, 221 (2015). (4). S.S.P. Parkin, Phys. Rev. Lett. 67, 3598 (1991).

Investigation of Artificial Forced Cooling in the Bridgman Crystal Growth of Cadmium Zinc Telluride

NASA Astrophysics Data System (ADS)

Liu, Juncheng; Li, Jiao; Zhang, Guodong; Li, Changxing; Lennon, Craig; Sivananthan, Siva

2007-08-01

The effects of artificial forced cooling on the solid liquid interface and on solute segregation were investigated by modeling the vertical Bridgman method for the single-crystal growth of CdZnTe, taking into consideration effects such as increasing the axial outward heat flux from the crucible bottom, the radial outward heat flux from the crucible wall, and the carbon film thickness on the crucible inner wall. Axial artificially forced cooling noticeably increases convection and the temperature gradient in the melt next to the solid liquid interface, and substantially reduces interface concavity at the initial solidification stage. Interface concavity increases a little when the solidification proceeds further, however. Axial artificially forced cooling reduces radial solute segregation of the initial segment of the grown crystal and slightly increases the solute iso-concentration segment. Radial artificially forced cooling enhances melt convection substantially, affects solid liquid interface concavity only slightly, and hardly affects solute segregation in the grown crystal. Doubling the carbon film thickness weakens convection of the melt in front of the interface, substantially increases interface concavity, and hardly affects solute segregation in the grown crystal.

Understanding Lymphatic Valve Function via Computational Modeling

NASA Astrophysics Data System (ADS)

Wolf, Ki; Nepiyushchikh, Zhanna; Razavi, Mohammad; Dixon, Brandon; Alexeev, Alexander

2017-11-01

The lymphatic system is a crucial part to the circulatory system with many important functions, such as transport of interstitial fluid, fatty acid, and immune cells. Lymphatic vessels' contractile walls and valves allow lymph flow against adverse pressure gradients and prevent back flow. Yet, the effect of lymphatic valves' geometric and mechanical properties to pumping performance and lymphatic dysfunctions like lymphedema is not well understood. Our coupled fluid-solid computational model based on lattice Boltzmann model and lattice spring model investigates the dynamics and effectiveness of lymphatic valves in resistance minimization, backflow prevention, and viscoelastic response under different geometric and mechanical properties, suggesting the range of lymphatic valve parameters with effective pumping performance. Our model also provides more physiologically relevant relations of the valve response under varied conditions to a lumped parameter model of the lymphatic system giving an integrative insight into lymphatic system performance, including its failure due to diseases. NSF CMMI-1635133.

Solar shutter arrangement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fulkerson, P.L.

1988-02-02

In a structure having a roof with a skylight including a glass panel which transmits solar energy, a shutter arrangement supported on the roof is described comprising an insulative flat one-piece solid shutter in the form of a panel selectively and linearly slidable on tracks which conceal the side edges thereof from a position blocking transmittal of solar energy through the glass panel of the skylight into an area within the structure to a position permitting transmittal of solar energy through the glass panel of the skylight into the area within the structure. The skylight presents a space between themore » glass panel and the selectively and linearly slidable insulative flat one-piece solid shutter, where the latter serves as the selective inner wall of the space contiguous with the area within the structure and the glass panel serves as the fixed outer wall of the space, where temperature responsive means is disposed within the space and in direct engagement with the inner surface of the glass panel, where the temperature responsive means is a black thermocouple operating a motor in a driving relationship with the insulative flat one-piece solid shutter. The insulative flat one-piece solid shutter is supported by a cable secured to a rotatable shaft controlled by the motor, where bi-directional movement of the rotatable shaft achieves raising and lowering of the insulative flat one-piece solid shutter to each of the solar energy blocking and transmittal positions, and where the insulative flat one-piece solid shutter includes a reflective surface facing the skylight and a decorative surface facing the area within the structure.« less

MCNP modelling of the wall effects observed in tissue-equivalent proportional counters.

PubMed

Hoff, J L; Townsend, L W

2002-01-01

Tissue-equivalent proportional counters (TEPCs) utilise tissue-equivalent materials to depict homogeneous microscopic volumes of human tissue. Although both the walls and gas simulate the same medium, they respond to radiation differently. Density differences between the two materials cause distortions, or wall effects, in measurements, with the most dominant effect caused by delta rays. This study uses a Monte Carlo transport code, MCNP, to simulate the transport of secondary electrons within a TEPC. The Rudd model, a singly differential cross section with no dependence on electron direction, is used to describe the energy spectrum obtained by the impact of two iron beams on water. Based on the models used in this study, a wall-less TEPC had a higher lineal energy (keV.micron-1) as a function of impact parameter than a solid-wall TEPC for the iron beams under consideration. An important conclusion of this study is that MCNP has the ability to model the wall effects observed in TEPCs.

A phenomenological continuum model for force-driven nano-channel liquid flows

NASA Astrophysics Data System (ADS)

Ghorbanian, Jafar; Celebi, Alper T.; Beskok, Ali

2016-11-01

A phenomenological continuum model is developed using systematic molecular dynamics (MD) simulations of force-driven liquid argon flows confined in gold nano-channels at a fixed thermodynamic state. Well known density layering near the walls leads to the definition of an effective channel height and a density deficit parameter. While the former defines the slip-plane, the latter parameter relates channel averaged density with the desired thermodynamic state value. Definitions of these new parameters require a single MD simulation performed for a specific liquid-solid pair at the desired thermodynamic state and used for calibration of model parameters. Combined with our observations of constant slip-length and kinematic viscosity, the model accurately predicts the velocity distribution and volumetric and mass flow rates for force-driven liquid flows in different height nano-channels. Model is verified for liquid argon flow at distinct thermodynamic states and using various argon-gold interaction strengths. Further verification is performed for water flow in silica and gold nano-channels, exhibiting slip lengths of 1.2 nm and 15.5 nm, respectively. Excellent agreements between the model and the MD simulations are reported for channel heights as small as 3 nm for various liquid-solid pairs.

Perspectives on continuum flow models for force-driven nano-channel liquid flows

NASA Astrophysics Data System (ADS)

Beskok, Ali; Ghorbanian, Jafar; Celebi, Alper

2017-11-01

A phenomenological continuum model is developed using systematic molecular dynamics (MD) simulations of force-driven liquid argon flows confined in gold nano-channels at a fixed thermodynamic state. Well known density layering near the walls leads to the definition of an effective channel height and a density deficit parameter. While the former defines the slip-plane, the latter parameter relates channel averaged density with the desired thermodynamic state value. Definitions of these new parameters require a single MD simulation performed for a specific liquid-solid pair at the desired thermodynamic state and used for calibration of model parameters. Combined with our observations of constant slip-length and kinematic viscosity, the model accurately predicts the velocity distribution and volumetric and mass flow rates for force-driven liquid flows in different height nano-channels. Model is verified for liquid argon flow at distinct thermodynamic states and using various argon-gold interaction strengths. Further verification is performed for water flow in silica and gold nano-channels, exhibiting slip lengths of 1.2 nm and 15.5 nm, respectively. Excellent agreements between the model and the MD simulations are reported for channel heights as small as 3 nm for various liquid-solid pairs.

Process for separating metallic from semiconducting single-walled carbon nanotubes

NASA Technical Reports Server (NTRS)

Sun, Ya-Ping (Inventor)

2008-01-01

A method for separating semiconducting single-walled carbon nanotubes from metallic single-walled carbon nanotubes is disclosed. The method utilizes separation agents that preferentially associate with semiconducting nanotubes due to the electrical nature of the nanotubes. The separation agents are those that have a planar orientation, .pi.-electrons available for association with the surface of the nanotubes, and also include a soluble portion of the molecule. Following preferential association of the separation agent with the semiconducting nanotubes, the agent/nanotubes complex is soluble and can be solubilized with the solution enriched in semiconducting nanotubes while the residual solid is enriched in metallic nanotubes.

Digital Fresnel reflection holography for high-resolution 3D near-wall flow measurement.

PubMed

Kumar, S Santosh; Hong, Jiarong

2018-05-14

We propose a novel backscatter holographic imaging system, as a compact and effective tool for 3D near-wall flow diagnostics at high resolutions, utilizing light reflected at the solid-liquid interface as a reference beam. The technique is fully calibrated, and is demonstrated in a densely seeded channel to achieve a spatial resolution of near-wall flows equivalent to or exceeding prior digital inline holographic measurements using local tracer seeding technique. Additionally, we examined the effects of seeding concentration and laser coherence on the measurement resolution and sample volume resolved, demonstrating the potential to manipulate sample domain by tuning the laser coherence profile.

Emerging technology for transonic wind-tunnel-wall interference assessment and corrections

NASA Technical Reports Server (NTRS)

Newman, P. A.; Kemp, W. B., Jr.; Garriz, J. A.

1988-01-01

Several nonlinear transonic codes and a panel method code for wind tunnel/wall interference assessment and correction (WIAC) studies are reviewed. Contrasts between two- and three-dimensional transonic testing factors which affect WIAC procedures are illustrated with airfoil data from the NASA/Langley 0.3-meter transonic cyrogenic tunnel and Pathfinder I data. Also, three-dimensional transonic WIAC results for Mach number and angle-of-attack corrections to data from a relatively large 20 deg swept semispan wing in the solid wall NASA/Ames high Reynolds number Channel I are verified by three-dimensional thin-layer Navier-Stokes free-air solutions.

9 CFR 3.3 - Sheltered housing facilities.

Code of Federal Regulations, 2012 CFR

2012-01-01

... attending veterinarian. Dry bedding, solid resting boards, or other methods of conserving body heat must be... wire, wood, metal, or concrete; and (iii) All walls, boxes, houses, dens, and other surfaces in contact...

9 CFR 3.3 - Sheltered housing facilities.

Code of Federal Regulations, 2013 CFR

2013-01-01

... attending veterinarian. Dry bedding, solid resting boards, or other methods of conserving body heat must be... wire, wood, metal, or concrete; and (iii) All walls, boxes, houses, dens, and other surfaces in contact...

9 CFR 3.3 - Sheltered housing facilities.

Code of Federal Regulations, 2014 CFR

2014-01-01

... attending veterinarian. Dry bedding, solid resting boards, or other methods of conserving body heat must be... wire, wood, metal, or concrete; and (iii) All walls, boxes, houses, dens, and other surfaces in contact...

Vaginal cysts

MedlinePlus

... essential to determine what type of cyst or mass you may have. A mass or bulge of the vaginal wall may be ... to rule out vaginal cancer, especially if the mass appears to be solid. If the cyst is ...

Hemodynamics model of fluid–solid interaction in internal carotid artery aneurysms

PubMed Central

Fu-Yu, Wang; Lei, Liu; Xiao-Jun, Zhang; Hai-Yue, Ju

2010-01-01

The objective of this study is to present a relatively simple method to reconstruct cerebral aneurysms as 3D numerical grids. The method accurately duplicates the geometry to provide computer simulations of the blood flow. Initial images were obtained by using CT angiography and 3D digital subtraction angiography in DICOM format. The image was processed by using MIMICS software, and the 3D fluid model (blood flow) and 3D solid model (wall) were generated. The subsequent output was exported to the ANSYS workbench software to generate the volumetric mesh for further hemodynamic study. The fluid model was defined and simulated in CFX software while the solid model was calculated in ANSYS software. The force data calculated firstly in the CFX software were transferred to the ANSYS software, and after receiving the force data, total mesh displacement data were calculated in the ANSYS software. Then, the mesh displacement data were transferred back to the CFX software. The data exchange was processed in workbench software. The results of simulation could be visualized in CFX-post. Two examples of grid reconstruction and blood flow simulation for patients with internal carotid artery aneurysms were presented. The wall shear stress, wall total pressure, and von Mises stress could be visualized. This method seems to be relatively simple and suitable for direct use by neurosurgeons or neuroradiologists, and maybe a practical tool for planning treatment and follow-up of patients after neurosurgical or endovascular interventions with 3D angiography. PMID:20812022

Hemodynamics model of fluid-solid interaction in internal carotid artery aneurysms.

PubMed

Bai-Nan, Xu; Fu-Yu, Wang; Lei, Liu; Xiao-Jun, Zhang; Hai-Yue, Ju

2011-01-01

The objective of this study is to present a relatively simple method to reconstruct cerebral aneurysms as 3D numerical grids. The method accurately duplicates the geometry to provide computer simulations of the blood flow. Initial images were obtained by using CT angiography and 3D digital subtraction angiography in DICOM format. The image was processed by using MIMICS software, and the 3D fluid model (blood flow) and 3D solid model (wall) were generated. The subsequent output was exported to the ANSYS workbench software to generate the volumetric mesh for further hemodynamic study. The fluid model was defined and simulated in CFX software while the solid model was calculated in ANSYS software. The force data calculated firstly in the CFX software were transferred to the ANSYS software, and after receiving the force data, total mesh displacement data were calculated in the ANSYS software. Then, the mesh displacement data were transferred back to the CFX software. The data exchange was processed in workbench software. The results of simulation could be visualized in CFX-post. Two examples of grid reconstruction and blood flow simulation for patients with internal carotid artery aneurysms were presented. The wall shear stress, wall total pressure, and von Mises stress could be visualized. This method seems to be relatively simple and suitable for direct use by neurosurgeons or neuroradiologists, and maybe a practical tool for planning treatment and follow-up of patients after neurosurgical or endovascular interventions with 3D angiography.

Random close packing of disks and spheres in confined geometries

NASA Astrophysics Data System (ADS)

Desmond, Kenneth W.; Weeks, Eric R.

2009-11-01

Studies of random close packing of spheres have advanced our knowledge about the structure of systems such as liquids, glasses, emulsions, granular media, and amorphous solids. In confined geometries, the structural properties of random-packed systems will change. To understand these changes, we study random close packing in finite-sized confined systems, in both two and three dimensions. Each packing consists of a 50-50 binary mixture with particle size ratio of 1.4. The presence of confining walls significantly lowers the overall maximum area fraction (or volume fraction in three dimensions). A simple model is presented, which quantifies the reduction in packing due to wall-induced structure. This wall-induced structure decays rapidly away from the wall, with characteristic length scales comparable to the small particle diameter.

An experimental study of wall adaptation and interference assessment using Cauchy integral formula

NASA Technical Reports Server (NTRS)

Murthy, A. V.

1991-01-01

This paper summarizes the results of an experimental study of combined wall adaptation and residual interference assessment using the Cauchy integral formula. The experiments were conducted on a supercritical airfoil model in the Langley 0.3-m Transonic Cryogenic Tunnel solid flexible wall test section. The ratio of model chord to test section height was about 0.7. The method worked satisfactorily in reducing the blockage interference and demonstrated the primary requirement for correcting for the blockage effects at high model incidences to correctly determine high lift characteristics. The studies show that the method has potential for reducing the residual interference to considerably low levels. However, corrections to blockage and upwash velocities gradients may still be required for the final adapted wall shapes.

Modeling of Cluster-Induced Turbulence in Particle-Laden Channel Flow

NASA Astrophysics Data System (ADS)

Baker, Michael; Capecelatro, Jesse; Kong, Bo; Fox, Rodney; Desjardins, Olivier

2017-11-01

A phenomenon often observed in gas-solid flows is the formation of mesoscale clusters of particles due to the relative motion between the solid and fluid phases that is sustained through the dampening of collisional particle motion from interphase momentum coupling inside these clusters. The formation of such sustained clusters, leading to cluster-induced turbulence (CIT), can have a significant impact in industrial processes, particularly in regards to mixing, reaction progress, and heat transfer. Both Euler-Lagrange (EL) and Euler-Euler anisotropic Gaussian (EE-AG) approaches are used in this work to perform mesoscale simulations of CIT in fully developed gas-particle channel flow. The results from these simulations are applied in the development of a two-phase Reynolds-Averaged Navier-Stokes (RANS) model to capture the wall-normal flow characteristics in a less computationally expensive manner. Parameters such as mass loading, particle size, and gas velocity are varied to examine their respective impact on cluster formation and turbulence statistics. Acknowledging support from the NSF (AN:1437865).

Debonding Stress Concentrations in a Pressurized Lobed Sandwich-Walled Generic Cryogenic Tank

NASA Technical Reports Server (NTRS)

Ko, William L.

2004-01-01

A finite-element stress analysis has been conducted on a lobed composite sandwich tank subjected to internal pressure and cryogenic cooling. The lobed geometry consists of two obtuse circular walls joined together with a common flat wall. Under internal pressure and cryogenic cooling, this type of lobed tank wall will experience open-mode (a process in which the honeycomb is stretched in the depth direction) and shear stress concentrations at the junctures where curved wall changes into flat wall (known as a curve-flat juncture). Open-mode and shear stress concentrations occur in the honeycomb core at the curve-flat junctures and could cause debonding failure. The levels of contributions from internal pressure and temperature loading to the open-mode and shear debonding failure are compared. The lobed fuel tank with honeycomb sandwich walls has been found to be a structurally unsound geometry because of very low debonding failure strengths. The debonding failure problem could be eliminated if the honeycomb core at the curve-flat juncture is replaced with a solid core.

Calculation of heat flux through a wall containing a cavity: Comparison of several models

NASA Astrophysics Data System (ADS)

Park, J. E.; Kirkpatrick, J. R.; Tunstall, J. N.; Childs, K. W.

1986-02-01

This paper describes the calculation of the heat transfer through the standard stud wall structure of a residential building. The wall cavity contains no insulation. Results from five test cases are presented. The first four represent progressively more complicated approximations to the heat transfer through and within a hollow wall structure. The fifth adds the model components necessary to severely inhibit the radiative energy transport across the empty cavity. Flow within the wall cavity is calculated from the Navier-Stokes equations and the energy conservation equation for an ideal gas using an improvement to the Implicit-Compressible Eulerian (ICE) algorithm of Harlow and Amsden. An algorithm is described to efficiently couple the fluid flow calculations to the radiation-conduction model for the solid portions of the system. Results indicate that conduction through still plates contributes less than 2% of the total heat transferred through a composite wall. All of the other elements (conduction through wall board, sheathing, and siding; convection from siding and wallboard to am bients; and radiation across the wall cavity) are required to accurately predict the heat transfer through a wall. Addition of a foil liner on one inner surface of the wall cavity reduces the total heat transferred by almost 50%.

PERFORMANCE IMPROVEMENT OF CROSS-FLOW FILTRATION FOR HIGH LEVEL WASTE TREATMENT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Duignan, M.; Nash, C.; Poirier, M.

2011-01-12

In the interest of accelerating waste treatment processing, the DOE has funded studies to better understand filtration with the goal of improving filter fluxes in existing cross-flow equipment. The Savannah River National Laboratory (SRNL) was included in those studies, with a focus on start-up techniques, filter cake development, the application of filter aids (cake forming solid precoats), and body feeds (flux enhancing polymers). This paper discusses the progress of those filter studies. Cross-flow filtration is a key process step in many operating and planned waste treatment facilities to separate undissolved solids from supernate slurries. This separation technology generally has themore » advantage of self-cleaning through the action of wall shear stress created by the flow of waste slurry through the filter tubes. However, the ability of filter wall self-cleaning depends on the slurry being filtered. Many of the alkaline radioactive wastes are extremely challenging to filtration, e.g., those containing compounds of aluminum and iron, which have particles whose size and morphology reduce permeability. Unfortunately, low filter flux can be a bottleneck in waste processing facilities such as the Savannah River Modular Caustic Side Solvent Extraction Unit and the Hanford Waste Treatment Plant. Any improvement to the filtration rate would lead directly to increased throughput of the entire process. To date increased rates are generally realized by either increasing the cross-flow filter axial flowrate, limited by pump capacity, or by increasing filter surface area, limited by space and increasing the required pump load. SRNL set up both dead-end and cross-flow filter tests to better understand filter performance based on filter media structure, flow conditions, filter cleaning, and several different types of filter aids and body feeds. Using non-radioactive simulated wastes, both chemically and physically similar to the actual radioactive wastes, the authors performed several tests to demonstrate increases in filter performance. With the proper use of filter flow conditions and filter enhancers, filter flow rates can be increased over rates currently realized today.« less

National Program for Inspection of Non-Federal Dams. Abbey Lake Dam MA 00305, Connecticut River Basin, Sandisfield, Massachusetts. Phase I Inspection Report.

DTIC Science & Technology

1980-02-01

There are three anti-vortex walls placed perpendicular to and across the top of the weir walls with a solid concrete platform bridging the two upstream...F- cc: wIX 0 0-. w a -- a: U : <w >- w w 0o 0 w ~ I a .. U&SO 5U "* " - . V , -. - - -. -. "." " r ". -V-, .- --- "i - -.- r w

Role of MRI in the early diagnosis of tubal ectopic pregnancy.

PubMed

Si, Ming-Jue; Gui, Shuang; Fan, Qin; Han, Hong-Xiu; Zhao, Qian-Qian; Li, Zhi-Xin; Zhao, Jiang-Min

2016-07-01

To determine the role of MRI in the early diagnosis of tubal ectopic pregnancy (EP). Clinical and MRI features of 27 cases of tubal pregnancy were reviewed. A thick-walled gestational sac (GS)-like structure was demonstrated lateral to the uterus in all cases. On T2-weighted images, the thick wall typically exhibited 3 discrete rings in 22 cases (81 %), among which 17 cases (63 %) displayed small vessels and 6 cases (33 %) exhibited small areas of fresh haemorrhage inside the thick wall. The contents demonstrated non-specific liquid in 26 %, papillary solid components in 56 %, and fresh blood or fluid-fluid level in 19 % of the cases. Dilatation of the affected fallopian tube associated with hematosalpinx was demonstrated in 18 cases (67 %) and marked enhancement of the tubal wall was observed in 22 cases (81 %). No correlation was found between the size of the GS and the estimated gestational age (r = 0.056). MRI plays an important role in the early diagnosis and management of tubal pregnancy. The characteristic MRI features include a GS-like structure with a "three rings" appearance on T2-weighted images, presence of solid components in the sac, dilatation of the affected fallopian tube with hematosalpinx, and tubal wall enhancement. • MR imaging has served as a problem-solving procedure in ectopic pregnancy. • MR imaging features can be criteria for early diagnosis of tubal pregnancy. • Detailed assessment of ectopic implantation is necessary for management decision-making.

Boundary slip and wetting properties of interfaces: correlation of the contact angle with the slip length.

PubMed

Voronov, Roman S; Papavassiliou, Dimitrios V; Lee, Lloyd L

2006-05-28

Correlations between contact angle, a measure of the wetting of surfaces, and slip length are developed using nonequilibrium molecular dynamics for a Lennard-Jones fluid in Couette flow between graphitelike hexagonal-lattice walls. The fluid-wall interaction is varied by modulating the interfacial energy parameter epsilonr=epsilonsfepsilonff and the size parameter sigmar=sigmasfsigmaff, (s=solid, f=fluid) to achieve hydrophobicity (solvophobicity) or hydrophilicity (solvophilicity). The effects of surface chemistry, as well as the effects of temperature and shear rate on the slip length are determined. The contact angle increases from 25 degrees to 147 degrees on highly hydrophobic surfaces (as epsilonr decreases from 0.5 to 0.1), as expected. The slip length is functionally dependent on the affinity strength parameters epsilonr and sigmar: increasing logarithmically with decreasing surface energy epsilonr (i.e., more hydrophobic), while decreasing with power law with decreasing size sigmar. The mechanism for the latter is different from the energetic case. While weak wall forces (small epsilonr) produce hydrophobicity, larger sigmar smoothes out the surface roughness. Both tend to increase the slip. The slip length grows rapidly with a high shear rate, as wall velocity increases three decades from 100 to 10(5) ms. We demonstrate that fluid-solid interfaces with low epsilonr and high sigmar should be chosen to increase slip and are prime candidates for drag reduction.

Wall-interference assessment and corrections for transonic NACA 0012 airfoil data from various wind tunnels. M.S. Thesis - George Washington Univ., 1988

NASA Technical Reports Server (NTRS)

Green, Lawrence L.; Newman, Perry A.

1991-01-01

A nonlinear, four wall, post-test wall interference assessment/correction (WIAC) code was developed for transonic airfoil data from solid wall wind tunnels with flexibly adaptable top and bottom walls. The WIAC code was applied over a broad range of test conditions to four sets of NACA 0012 airfoil data, from two different adaptive wall wind tunnels. The data include many test points for fully adapted walls, as well as numerous partially adapted and unadapted test points, which together represent many different model/tunnel configurations and possible wall interference effects. Small corrections to the measured Mach numbers and angles of attack were obtained from the WIAC code even for fully adapted data; these corrections generally improve the correlation among the various sets of airfoil data and simultaneously improve the correlation of the data with calculations for a 2-D, free air, Navier-Stokes code. The WIAC corrections for airfoil data taken in fully adapted wall test sections are shown to be significantly smaller than those for comparable airfoil data from straight, slotted wall test sections. This indicates, as expected, a lesser degree of wall interference in the adapted wall tunnels relative to the slotted wall tunnels. Application of the WIAC code to this data was, however, somewhat more difficult and time consuming than initially expected from similar previous experience with WIAC applications to slotted wall data.

Towards wall functions for the prediction of solute segregation in plane front directional solidification

NASA Astrophysics Data System (ADS)

Chatelain, M.; Rhouzlane, S.; Botton, V.; Albaric, M.; Henry, D.; Millet, S.; Pelletier, D.; Garandet, J. P.

2017-10-01

The present paper focuses on solute segregation occurring in directional solidification processes with sharp solid/liquid interface, like silicon crystal growth. A major difficulty for the simulation of such processes is their inherently multi-scale nature: the impurity segregation problem is controlled at the solute boundary layer scale (micrometers) while the thermal problem is ruled at the crucible scale (meters). The thickness of the solute boundary layer is controlled by the convection regime and requires a specific refinement of the mesh of numerical models. In order to improve numerical simulations, wall functions describing solute boundary layers for convecto-diffusive regimes are derived from a scaling analysis. The aim of these wall functions is to obtain segregation profiles from purely thermo-hydrodynamic simulations, which do not require solute boundary layer refinement at the solid/liquid interface. Regarding industrial applications, various stirring techniques can be used to enhance segregation, leading to fully turbulent flows in the melt. In this context, the scaling analysis is further improved by taking into account the turbulent solute transport. The solute boundary layers predicted by the analytical model are compared to those obtained by transient segregation simulations in a canonical 2D lid driven cavity configuration for validation purposes. Convective regimes ranging from laminar to fully turbulent are considered. Growth rate and molecular diffusivity influences are also investigated. Then, a procedure to predict concentration fields in the solid phase from a hydrodynamic simulation of the solidification process is proposed. This procedure is based on the analytical wall functions and on solute mass conservation. It only uses wall shear-stress profiles at the solidification front as input data. The 2D analytical concentration fields are directly compared to the results of the complete simulation of segregation in the lid driven cavity configuration. Finally, an additional output from the analytical model is also presented. We put in light the correlation between different species convecto-diffusive behaviour; we use it to propose an estimation method for the segregation parameters of various chemical species knowing segregation parameters of one specific species.

Rapid solar-thermal decarbonization of methane

NASA Astrophysics Data System (ADS)

Dahl, Jaimee Kristen

Due to the ever-increasing demand for energy and the concern over the environmental impact of continuing to produce energy using current methods, there is interest in developing a hydrogen economy. Hydrogen is a desirable energy source because it is abundant in nature and burns cleanly. One method for producing hydrogen is to utilize a renewable energy source to obtain high enough temperatures to decompose a fossil fuel into its elements. This thesis work is directed at developing a solar-thermal aerosol flow reactor to dissociate methane to carbon black and hydrogen. The technology is intended as a "bridge" between current hydrogen production methods, such as conventional steam-methane reformers, and future "zero emission" technology for producing hydrogen, such as dissociating water using a renewable heating source. A solar furnace is used to heat a reactor to temperatures in excess of 2000 K. The final reactor design studied consists of three concentric vertical tubes---an outer quartz protection tube, a middle solid graphite heating tube, and an inner porous graphite reaction tube. A "fluid-wall" is created on the inside wall of the porous reaction tube in order to prevent deposition of the carbon black co-product on the reactor tube wall. The amorphous carbon black produced aids in heating the gas stream by absorbing radiation from the reactor wall. Conversions of 90% are obtained at a reactor wall temperature of 2100 K and an average residence time of 0.01 s. Computer modeling is also performed to study the gas flow and temperature profiles in the reactor as well as the kinetics of the methane dissociation reaction. The simulations indicate that there is little flow of the fluid-wall gas through the porous wall in the hot zone region, but this can be remedied by increasing the inlet temperature of the fluid-wall gas and/or increasing the tube permeability only in the hot zone region of the wall. The following expression describes the kinetics of methane dissociation in a solar-thermal fluid-wall reactor: dXdt=5.8x108 exp-155,600RT 1-X 7.2s-1. The experimental and theoretical work reported in this thesis is the groundwork that will be utilized in scaling up the reactor to produce hydrogen in distributed or centralized facilities.

A Novel UV-Shielding and Transparent Polymer Film: When Bioinspired Dopamine-Melanin Hollow Nanoparticles Join Polymers.

PubMed

Wang, Yang; Su, Jing; Li, Ting; Ma, Piming; Bai, Huiyu; Xie, Yi; Chen, Mingqing; Dong, Weifu

2017-10-18

Ultraviolet (UV) light is known to be harmful to human health and cause organic materials to undergo photodegradation. In this Research Article, bioinspired dopamine-melanin solid nanoparticles (Dpa-s NPs) and hollow nanoparticles (Dpa-h NPs) as UV-absorbers were introduced to enhance the UV-shielding performance of polymer. First, Dpa-s NPs were synthesized through autoxidation of dopamine in alkaline aqueous solution. Dpa-h NPs were prepared by the spontaneous oxidative polymerization of dopamine solution onto polystyrene (PS) nanospheres template, followed by removal of the template. Poly(vinyl alcohol) (PVA)/Dpa nanocomposite films were subsequently fabricated by a simple casting solvent. UV irradiation protocols were set up, allowing selective study of the extra-shielding effects of Dpa-s versus Dpa-h NPs. In contrast to PVA/Dpa-s films, PVA/Dpa-h films exhibit stronger UV-shielding capabilities and can almost block the complete UV region (200-400 nm). The excellent UV-shielding performance of the PVA/Dpa-h films mainly arises from multiple absorption because of the hollow structure and large specific area of Dpa-h NPs. Moreover, the wall thickness of Dpa-h NPs can be simply controlled from 28 to 8 nm, depending on the ratio between PS and dopamine. The resulting films with Dpa-h NPs (wall thickness = ∼8 nm) maintained relatively high transparency to visible light because of the thinner wall thickness. The results indicate that the prepared Dpa-h NPs can be used as a novel UV absorber for next-generation transparent UV-shielding materials.

Evaluation of Skin Friction Drag for Liner Applications in Aircraft

NASA Technical Reports Server (NTRS)

Gerhold, Carl H.; Brown, Martha C.; Jasinski, Christopher M.

2016-01-01

A parameter that is gaining significance in the evaluation of acoustic liner performance is the skin friction drag induced by air flow over the liner surface. Estimates vary widely regarding the amount of drag the liner induces relative to a smooth wall, from less than a 20% increase to nearly 100%, and parameters such as face sheet perforate hole diameter, percent open area, and sheet thickness are expected to figure prominently in the skin friction drag. Even a small increase in liner drag can impose an economic penalty, and current research is focused on developing 'low drag' liner concepts, with the goal being to approach the skin friction drag of a smooth wall. The issue of skin friction drag takes on greater significance as airframe designers investigate the feasibility of putting sound absorbing liners on the non-lifting surfaces of the wings and fuselage, for the purpose of reducing engine noise reflected and scattered toward observers on the ground. Researchers at the NASA Langley Research Center have embarked on investigations of liner skin friction drag with the aims of: developing a systematic drag measurement capability, establishing the drag of current liners, and developing liners that produce reduced drag without compromising acoustic performance. This paper discusses the experimental procedures that have been developed to calculate the drag coefficient based on the change in momentum thickness and the companion research program being carried out to measure the drag directly using a force balance. Liner samples that are evaluated include a solid wall with known roughness and conventional liners with perforated facesheets of varying hole diameter and percent open area.

Fast mean and variance computation of the diffuse sound transmission through finite-sized thick and layered wall and floor systems

NASA Astrophysics Data System (ADS)

Decraene, Carolina; Dijckmans, Arne; Reynders, Edwin P. B.

2018-05-01

A method is developed for computing the mean and variance of the diffuse field sound transmission loss of finite-sized layered wall and floor systems that consist of solid, fluid and/or poroelastic layers. This is achieved by coupling a transfer matrix model of the wall or floor to statistical energy analysis subsystem models of the adjacent room volumes. The modal behavior of the wall is approximately accounted for by projecting the wall displacement onto a set of sinusoidal lateral basis functions. This hybrid modal transfer matrix-statistical energy analysis method is validated on multiple wall systems: a thin steel plate, a polymethyl methacrylate panel, a thick brick wall, a sandwich panel, a double-leaf wall with poro-elastic material in the cavity, and a double glazing. The predictions are compared with experimental data and with results obtained using alternative prediction methods such as the transfer matrix method with spatial windowing, the hybrid wave based-transfer matrix method, and the hybrid finite element-statistical energy analysis method. These comparisons confirm the prediction accuracy of the proposed method and the computational efficiency against the conventional hybrid finite element-statistical energy analysis method.

FUN3D Airload Predictions for the Full-Scale UH-60A Airloads Rotor in a Wind Tunnel

NASA Technical Reports Server (NTRS)

Lee-Rausch, Elizabeth M.; Biedron, Robert T.

2013-01-01

An unsteady Reynolds-Averaged Navier-Stokes solver for unstructured grids, FUN3D, is used to compute the rotor performance and airloads of the UH-60A Airloads Rotor in the National Full-Scale Aerodynamic Complex (NFAC) 40- by 80-foot Wind Tunnel. The flow solver is loosely coupled to a rotorcraft comprehensive code, CAMRAD-II, to account for trim and aeroelastic deflections. Computations are made for the 1-g level flight speed-sweep test conditions with the airloads rotor installed on the NFAC Large Rotor Test Apparatus (LRTA) and in the 40- by 80-ft wind tunnel to determine the influence of the test stand and wind-tunnel walls on the rotor performance and airloads. Detailed comparisons are made between the results of the CFD/CSD simulations and the wind tunnel measurements. The computed trends in solidity-weighted propulsive force and power coefficient match the experimental trends over the range of advance ratios and are comparable to previously published results. Rotor performance and sectional airloads show little sensitivity to the modeling of the wind-tunnel walls, which indicates that the rotor shaft-angle correction adequately compensates for the wall influence up to an advance ratio of 0.37. Sensitivity of the rotor performance and sectional airloads to the modeling of the rotor with the LRTA body/hub increases with advance ratio. The inclusion of the LRTA in the simulation slightly improves the comparison of rotor propulsive force between the computation and wind tunnel data but does not resolve the difference in the rotor power predictions at mu = 0.37. Despite a more precise knowledge of the rotor trim loads and flight condition, the level of comparison between the computed and measured sectional airloads/pressures at an advance ratio of 0.37 is comparable to the results previously published for the high-speed flight test condition.

Thin film conductors for self-equalizing cables

NASA Astrophysics Data System (ADS)

Owen, G.; Trutna, W. R.; Orsley, T. J.; Lucia, F.; Daly, C. B.

2017-10-01

Self-equalizing cables using hollow conductors with wall thickness less than the skin depth were proposed in 1929. However, they do not appear ever to have been widely used, although the idea has resurfaced and been refined from time to time. In the early 2000's, self-equalizing conductors consisting of solid magnetic steel cores coated with silver were developed by W.L. Gore, and used in their 2.5 Gb/s "Eye-Opener" cables, although higher speed versions never appeared. We have revived the original 1929 idea, proposing to use glass as a solid insulating core. This technology can potentially work at frequencies of many 10's of GHz. Possible uses include short range GHz links such as USB and Thunderbolt, and intra-rack interconnections in data centers. Our feasibility experiments have validated the principle. Copper coated glass fibers can, in principle, be manufactured, but in these tests, the conductors were capillaries internally coated with silver as these are easily obtainable, relatively inexpensive and serve to test the concept. The performance of these experimental twin lead cables corresponds to calculations, confirming the general principle. By calculation, we have compared the performance of cables made from copper-on-insulator conductors to that of similar cables made with solid copper conductors, and verified that copper-on-insulator cables have significantly less frequency dependent loss. We have also made and tested cables with copper on PEEK conductors as surrogates for copper on glass fiber.

Reliable prediction of heat transfer coefficient in three-phase bubble column reactor via adaptive neuro-fuzzy inference system and regularization network

NASA Astrophysics Data System (ADS)

Garmroodi Asil, A.; Nakhaei Pour, A.; Mirzaei, Sh.

2018-04-01

In the present article, generalization performances of regularization network (RN) and optimize adaptive neuro-fuzzy inference system (ANFIS) are compared with a conventional software for prediction of heat transfer coefficient (HTC) as a function of superficial gas velocity (5-25 cm/s) and solid fraction (0-40 wt%) at different axial and radial locations. The networks were trained by resorting several sets of experimental data collected from a specific system of air/hydrocarbon liquid phase/silica particle in a slurry bubble column reactor (SBCR). A special convection HTC measurement probe was manufactured and positioned in an axial distance of 40 and 130 cm above the sparger at center and near the wall of SBCR. The simulation results show that both in-house RN and optimized ANFIS due to powerful noise filtering capabilities provide superior performances compared to the conventional software of MATLAB ANFIS and ANN toolbox. For the case of 40 and 130 cm axial distance from center of sparger, at constant superficial gas velocity of 25 cm/s, adding 40 wt% silica particles to liquid phase leads to about 66% and 69% increasing in HTC respectively. The HTC in the column center for all the cases studied are about 9-14% larger than those near the wall region.

Study of Solid Particle Behavior in High Temperature Gas Flows

NASA Astrophysics Data System (ADS)

Majid, A.; Bauder, U.; Stindl, T.; Fertig, M.; Herdrich, G.; Röser, H.-P.

2009-01-01

The Euler-Lagrangian approach is used for the simulation of solid particles in hypersonic entry flows. For flow field simulation, the program SINA (Sequential Iterative Non-equilibrium Algorithm) developed at the Institut für Raumfahrtsysteme is used. The model for the effect of the carrier gas on a particle includes drag force and particle heating only. Other parameters like lift Magnus force or damping torque are not taken into account so far. The reverse effect of the particle phase on the gaseous phase is currently neglected. Parametric analysis is done regarding the impact of variation in the physical input conditions like position, velocity, size and material of the particle. Convective heat fluxes onto the surface of the particle and its radiative cooling are discussed. The variation of particle temperature under different conditions is presented. The influence of various input conditions on the trajectory is explained. A semi empirical model for the particle wall interaction is also discussed and the influence of the wall on the particle trajectory with different particle conditions is presented. The heat fluxes onto the wall due to impingement of particles are also computed and compared with the heat fluxes from the gas.

Heat transfer evaluation in a plasma core reactor

NASA Technical Reports Server (NTRS)

Smith, D. E.; Smith, T. M.; Stoenescu, M. L.

1976-01-01

Numerical evaluations of heat transfer in a fissioning uranium plasma core reactor cavity, operating with seeded hydrogen propellant, was performed. A two-dimensional analysis is based on an assumed flow pattern and cavity wall heat exchange rate. Various iterative schemes were required by the nature of the radiative field and by the solid seed vaporization. Approximate formulations of the radiative heat flux are generally used, due to the complexity of the solution of a rigorously formulated problem. The present work analyzes the sensitivity of the results with respect to approximations of the radiative field, geometry, seed vaporization coefficients and flow pattern. The results present temperature, heat flux, density and optical depth distributions in the reactor cavity, acceptable simplifying assumptions, and iterative schemes. The present calculations, performed in cartesian and spherical coordinates, are applicable to any most general heat transfer problem.

Salt efflorescence due to water-rock interaction on the surface of tuff cave in the Yoshimi-Hyakuana Historic Site, central Japan

NASA Astrophysics Data System (ADS)

Oguchi, Chiaki T.; Kodama, Shogo; Mohammad, Rajib; Tharanga Udagedara, Dashan

2016-04-01

Artificial cave walls in Yoshimi Hyakuana Historic Site have been suffering from salt weathering since 1945 when the caves were made. To consider the processes of weathering and subsequent crystallization of secondary minerals, water-rock experiment using tuff from this area was performed. Rocks, surface altered materials, groundwater and rainwater were collected, and chemical and mineralogical characteristics of those samples were investigated. The XRD and SEM-EDS analyses were carried out for the solid samples and ICP-OES analysis was performed for the solution generated from the experiment, groundwater and rainwater. Gypsum is detected in original tuff, and on grey and whiter coloured altered materials. General chemical changes were observed on this rock. However, it is found that purple and black altered materials were mainly made due to microbiological processes.

Two-dimensional symmetry breaking of fluid density distribution in closed nanoslits.

PubMed

Berim, Gersh O; Ruckenstein, Eli

2008-01-14

Stable and metastable fluid density distributions (FDDs) in a closed nanoslit between two identical parallel solid walls have been identified on the basis of a nonlocal canonical ensemble density functional theory. Similar to Monte Carlo simulations, periodicity of the FDD in one of the lateral (parallel to the walls surfaces) directions, denoted as the x direction, was assumed. In the other lateral direction, y direction, the FDD was considered uniform. It was found that depending on the average fluid density in the slit, both uniform as well as nonuniform FDDs in the x direction can occur. The uniform FDDs are either symmetric or asymmetric about the middle plane between walls; the latter FDD being the consequence of a symmetry breaking across the slit. The nonuniform FDDs in the x direction occur either in the form of a bump on a thin liquid film covering the walls or as a liquid bridge between those walls and provide symmetry breaking in the x direction. For small and large average densities, the stable state is uniform in the x direction and is symmetric about the middle plane between walls. In the intermediate range of the average density and depending on the length L(x) of the FDD period, the stable state can be represented either by a FDD, which is uniform in the x direction and asymmetric about the middle of the slit (small values of L(x)), or by a bump- and bridgelike FDD for intermediate and large values of L(x), respectively. These results are in agreement with the Monte Carlo simulations performed earlier by other authors. Because the free energy of the stable state decreases monotonically with increasing L(x), one can conclude that the real period is very large (infinite) and that for the values of the parameters employed, a single bridge of finite length over the entire slit is generated.

A material sensitivity study on the accuracy of deformable organ registration using linear biomechanical models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chi, Y.; Liang, J.; Yan, D.

2006-02-15

Model-based deformable organ registration techniques using the finite element method (FEM) have recently been investigated intensively and applied to image-guided adaptive radiotherapy (IGART). These techniques assume that human organs are linearly elastic material, and their mechanical properties are predetermined. Unfortunately, the accurate measurement of the tissue material properties is challenging and the properties usually vary between patients. A common issue is therefore the achievable accuracy of the calculation due to the limited access to tissue elastic material constants. In this study, we performed a systematic investigation on this subject based on tissue biomechanics and computer simulations to establish the relationshipsmore » between achievable registration accuracy and tissue mechanical and organ geometrical properties. Primarily we focused on image registration for three organs: rectal wall, bladder wall, and prostate. The tissue anisotropy due to orientation preference in tissue fiber alignment is captured by using an orthotropic or a transversely isotropic elastic model. First we developed biomechanical models for the rectal wall, bladder wall, and prostate using simplified geometries and investigated the effect of varying material parameters on the resulting organ deformation. Then computer models based on patient image data were constructed, and image registrations were performed. The sensitivity of registration errors was studied by perturbating the tissue material properties from their mean values while fixing the boundary conditions. The simulation results demonstrated that registration error for a subvolume increases as its distance from the boundary increases. Also, a variable associated with material stability was found to be a dominant factor in registration accuracy in the context of material uncertainty. For hollow thin organs such as rectal walls and bladder walls, the registration errors are limited. Given 30% in material uncertainty, the registration error is limited to within 1.3 mm. For a solid organ such as the prostate, the registration errors are much larger. Given 30% in material uncertainty, the registration error can reach 4.5 mm. However, the registration error distribution for prostates shows that most of the subvolumes have a much smaller registration error. A deformable organ registration technique that uses FEM is a good candidate in IGART if the mean material parameters are available.« less

Green Walls as an Approach in Grey Water Treatment

NASA Astrophysics Data System (ADS)

Rysulova, Martina; Kaposztasova, Daniela; Vranayova, Zuzana

2017-10-01

Grey water contributes significantly to waste water parameters such as biochemical oxygen demand (BOD), chemical oxygen demand (COD), total suspended solids (TSS), total phosphorus (Ptotal), total nitrogen (Ntotal), ammonium, boron, metals, salts, surfactants, synthetic chemicals, oils and greases, xenobiotic substances and microorganisms. Concentration of these pollutants and the water quality highlights the importance of treatment process in grey water systems. Treatment technologies operating under low energy and maintenance are usually preferred, since they are more cost effective for users. Treatment technologies based on natural processes represent an example of such technology including vegetated wall. Main aim of this paper is to introduce the proposal of vegetated wall managing grey water and brief characteristic of proposed system. Is expected that prepared experiment will establish the purifying ability and the potential of green wall application as an efficient treatment technology.

Rationally Designed 2D Covalent Organic Framework with a Brick-Wall Topology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cai, Song-Liang; Zhang, Kai; Tan, Jing-Bo

In this paper, we report the design and synthesis of an imine-based two-dimensional covalent organic framework (2D COF) with a novel brick-wall topology by judiciously choosing a tritopic T-shaped building block and a ditopic linear linker. Unlike the main body of COF frameworks reported to-date, which consists of higher-symmetry 2D topologies, the unconventional layered brick-wall topology have only been proposed but never been realized experimentally. The brick-wall structure was characterized by powder X-ray diffraction analysis, FT-IR, solid state 13C NMR spectroscopy, nitrogen, and carbon oxide adsorption-desorption measurements as well as theoretical simulations. Lastly, our present work opens the door tomore » the design of novel 2D COFs and will broaden the scope of emerging COF materials.« less

Rationally Designed 2D Covalent Organic Framework with a Brick-Wall Topology

DOE PAGES

Cai, Song-Liang; Zhang, Kai; Tan, Jing-Bo; ...

2016-11-23

In this paper, we report the design and synthesis of an imine-based two-dimensional covalent organic framework (2D COF) with a novel brick-wall topology by judiciously choosing a tritopic T-shaped building block and a ditopic linear linker. Unlike the main body of COF frameworks reported to-date, which consists of higher-symmetry 2D topologies, the unconventional layered brick-wall topology have only been proposed but never been realized experimentally. The brick-wall structure was characterized by powder X-ray diffraction analysis, FT-IR, solid state 13C NMR spectroscopy, nitrogen, and carbon oxide adsorption-desorption measurements as well as theoretical simulations. Lastly, our present work opens the door tomore » the design of novel 2D COFs and will broaden the scope of emerging COF materials.« less

A viscoelastic fluid-structure interaction model for carotid arteries under pulsatile flow.

PubMed

Wang, Zhongjie; Wood, Nigel B; Xu, Xiao Yun

2015-05-01

In this study, a fluid-structure interaction model (FSI) incorporating viscoelastic wall behaviour is developed and applied to an idealized model of the carotid artery under pulsatile flow. The shear and bulk moduli of the arterial wall are described by Prony series, where the parameters can be derived from in vivo measurements. The aim is to develop a fully coupled FSI model that can be applied to realistic arterial geometries with normal or pathological viscoelastic wall behaviour. Comparisons between the numerical and analytical solutions for wall displacements demonstrate that the coupled model is capable of predicting the viscoelastic behaviour of carotid arteries. Comparisons are also made between the solid only and FSI viscoelastic models, and the results suggest that the difference in radial displacement between the two models is negligible. Copyright © 2015 John Wiley & Sons, Ltd.

The Influence of Phase Change Materials on the Properties of Self-Compacting Concrete.

PubMed

Fenollera, María; Míguez, José Luis; Goicoechea, Itziar; Lorenzo, Jaime; Ángel Álvarez, Miguel

2013-08-15

The aim of this paper is to research new thermally-efficient concrete walls, analyzing the mechanical behavior of a self-compacting concrete to manufacture an uncoated solid structural panel, with the incorporation of a micro-encapsulated phase change material as additive. Different dosages are tested and mechanical properties of the product obtained from the molding of concrete specimens are evaluated, testing mechanical compressive strength, slump flow, and density. The results reveal the optimum percentage of additive in the mixture that enables compliance with the technical specifications required by the product to be manufactured. A test is also performed for measuring the thermal conductivity for the optimal sample obtained and it evidences the reduction thereof.

The Processing and Mechanical Properties of High Temperature/ High Performance Composites. Mechanism-Based Constitutive Laws and Design. Book 1

DTIC Science & Technology

1994-03-01

H. Pestes Composites S . V . Kamat J. P. Hirth KJS 4/27/94 I I I I I M I BOOK 3 FATIGUE AND CREEP 32. Mode I Fatigue Cracking in a Fiber D . P. Walls...Mater.. 7 (1989) 305-17. Are: + 2(Am + 4m)(c, + d ) - (3;m + 2m)a mAT 9. Brindley. P. K.. Draper. S . L.. Nathal. M. V . & dm = R Eldridge. J. I...Mech. Ph vs. A 22A, 2975 (1991). Solids 24, 141 (1976). 8. S . Majumdar and P. V . Jr. McLaughlin, J. appl. Mech. 14. P. D . Warren, A. G. Mackin and A. G

Parameter Sensitivity Study of the Wall Interference Correction System (WICS)

NASA Technical Reports Server (NTRS)

Walker, Eric L.; Everhart, Joel L.; Iyer, Venkit

2001-01-01

An off-line version of the Wall Interference Correction System (WICS) has been implemented for the "NASA Langley National Transonic Facility. The correction capability is currently restricted to corrections for solid wall interference in the model pitch plane for Mach numbers, less than 0.45 due to a limitation in tunnel calibration data. A study to assess output sensitivity to the aerodynamic parameters of Reynolds number and Mach number was conducted on this code to further ensure quality during the correction process. In addition, this paper includes all investigation into possible correction due to a semispan test technique using a non metric standoff and all improvement to the standard data rejection algorithm.

Laser and Pressure Resistance Weld of Thin-Wall Cladding for LWR Accident-Tolerant Fuels

NASA Astrophysics Data System (ADS)

Gan, J.; Jerred, N.; Perez, E.; Haggard, D. C.

2017-12-01

FeCrAl alloy with typical composition of approximately Fe-15Cr-5Al is considered a primary candidate cladding material for light water reactor accident-tolerant fuel because of its superior resistance to oxidation in high-temperature steam compared with Zircaloy cladding. Thin-walled FeCrAl cladding at 350 μm wall thickness is required, and techniques for joining endplug to cladding need to be developed. Fusion-based laser weld and solid-state joining with pressure resistance weld were investigated in this study. The results of microstructural characterization, mechanical property evaluation by tensile testing, and hydraulic pressure burst testing of the welds for the cladding-endplug specimen are discussed.

Laser and Pressure Resistance Weld of Thin-Wall Cladding for LWR Accident-Tolerant Fuels

NASA Astrophysics Data System (ADS)

Gan, J.; Jerred, N.; Perez, E.; Haggard, D. C.

2018-02-01

FeCrAl alloy with typical composition of approximately Fe-15Cr-5Al is considered a primary candidate cladding material for light water reactor accident-tolerant fuel because of its superior resistance to oxidation in high-temperature steam compared with Zircaloy cladding. Thin-walled FeCrAl cladding at 350 μm wall thickness is required, and techniques for joining endplug to cladding need to be developed. Fusion-based laser weld and solid-state joining with pressure resistance weld were investigated in this study. The results of microstructural characterization, mechanical property evaluation by tensile testing, and hydraulic pressure burst testing of the welds for the cladding-endplug specimen are discussed.

Molecular mechanics and structure of the fluid-solid interface in simple fluids

NASA Astrophysics Data System (ADS)

Wang, Gerald J.; Hadjiconstantinou, Nicolas G.

2017-09-01

Near a fluid-solid interface, the fluid spatial density profile is highly nonuniform at the molecular scale. This nonuniformity can have profound effects on the dynamical behavior of the fluid and has been shown to play an especially important role when modeling a wide variety of nanoscale heat and momentum transfer phenomena. We use molecular-mechanics arguments and molecular-dynamics (MD) simulations to develop a better understanding of the structure of the first fluid layer directly adjacent to the solid in the layering regime, as delineated by a nondimensional number that compares the effects of wall-fluid interaction to thermal energy. Using asymptotic analysis of the Nernst-Planck equation, we show that features of the fluid density profile close to the wall, such as the areal density of the first layer ΣFL (defined as the number of atoms in this layer per unit of fluid-solid interfacial area), can be expressed as polynomial functions of the fluid average density ρave. This is found to be in agreement with MD simulations, which also show that the width of the first layer hFL is a linear function of the average density and only a weak function of the temperature T . These results can be combined to show that, for system average densities corresponding to a dense fluid (ρave≥0.7 ), the ratio C ≡ΣFLρavehFL, representing a density enhancement with respect to the bulk fluid, depends only weakly on temperature and is essentially independent of density. Further MD simulations suggest that the above results, nominally valid for large systems (solid in contact with semi-infinite fluid), also describe fluid-solid interfaces under considerable nanoconfinement, provided ρave is appropriately defined.

Hermetically sealable package for hybrid solid-state electronic devices and the like

NASA Technical Reports Server (NTRS)

Miller, Wilson N. (Inventor); Gray, Ormal E. (Inventor)

1988-01-01

A light-weight, inexpensively fabricated, hermetically sealable, repairable package for small electronic or electromechanical units, having multiple connections, is described. A molded ring frame of polyamide-imide plastic (Torlon) is attached along one edge to a base plate formed of a highly heat conducting material, such as aluminum or copper. Bores are placed through a base plate within the area of the edge surface of ring frame which result in an attachment of the ring frame to the base plate during molding. Electrical leads are molded into the ring frame. The leads are L-shaped gold-plated copper wires imbedded within widened portions of the side wall of the ring frame. Within the plastic ring frame wall the leads are bent (typically, though not necessarily at 90 deg) so that they project into the interior volume of the ring frame for connection to the solid state devices.

Electromagnetic augmentation for casting of thin metal sheets

DOEpatents

Hull, J.R.

1987-10-28

Thin metal sheets are cast by magnetically levitating molten metal deposited in a model within a ferromagnetic yoke and between AC conducting coils and linearly displacing the magnetically levitated liquid metal while it is being cooled by the water-cooled walls of the mold to form a solid metal sheet. A conducting shield is electrically coupled to the molten metal sheet to provide a return path for eddy currents induced in the metal sheet by the current in the AC conducting coils. In another embodiment, a DC conducting coil is coupled to the metal sheet for providing a direct current therein which interacts with the magnetic field to levitate the moving metal sheet. Levitation of the metal sheet in both molten and solid forms reduces its contact pressure with the mold walls while maintaining sufficient engagement therebetween to permit efficient conductive cooling by the mold through which a coolant fluid may be circulated. 8 figs.

Biochemistry and Cell Wall Changes Associated with Noni (Morinda citrifolia L.) Fruit Ripening.

PubMed

Cárdenas-Coronel, Wendy G; Carrillo-López, Armando; Vélez de la Rocha, Rosabel; Labavitch, John M; Báez-Sañudo, Manuel A; Heredia, José B; Zazueta-Morales, José J; Vega-García, Misael O; Sañudo-Barajas, J Adriana

2016-01-13

Quality and compositional changes were determined in noni fruit harvested at five ripening stages, from dark-green to thaslucent-grayish. Fruit ripening was accompanied by acidity and soluble solids accumulation but pH diminution, whereas the softening profile presented three differential steps named early (no significant softening), intermediate (significant softening), and final (dramatic softening). At early step the extensive depolymerization of hydrosoluble pectins and the significantly increment of pectinase activities did not correlate with the slight reduction in firmness. The intermediate step showed an increment of pectinases and hemicellulases activities. The final step was accompanied by the most significant reduction in the yield of alcohol-insoluble solids as well as in the composition of uronic acids and neutral sugars; pectinases increased their activity and depolymerization of hemicellulosic fractions occurred. Noni ripening is a process conducted by the coordinated action of pectinases and hemicellulases that promote the differential dissasembly of cell wall polymers.

Physicochemical characterization of a new pineapple hybrid (FLHORAN41 Cv.).

PubMed

Brat, Pierre; Hoang, Lan Nguyen Thi; Soler, Alain; Reynes, Max; Brillouet, Jean-Marc

2004-10-06

The physicochemical characteristics (pH, total and soluble solids, and titratable acidity), sugars, organic acids, carotenoids, anthocyanins, volatile compounds, and cell wall polysaccharides of a new pineapple hybrid (FLHORAN41 cultivar) were measured throughout maturation and compared with the Smooth Cayenne cv. At full maturity, the FLHORAN41 cv. has a higher titratable acidity and soluble solids content than the Smooth Cayenne cv. The golden yellow flesh and red-orange to scarlet shell of ripe FLHORAN41 cv. fruits are due to carotenoid and anthocyanin levels that are, respectively, 2.5 and 1.5 times higher than those of the flesh and shell of the ripe Smooth Cayenne cv., respectively. During maturation of the FLHORAN41 cv., there was an increase in all classes of aroma compounds (mainly terpene hydrocarbons and esters), although their relative proportions were similar in both cultivars at full maturity. Cell wall polysaccharides undergo little change during maturation.

Flow-induced flutter in a wall-bounded elastic sheet

NASA Astrophysics Data System (ADS)

Weidman, M. S.; Argentina, M.; Hosoi, A. E.; Mahadevan, L.

2004-11-01

Inspired by voice production in natural and artificial systems, we consider the flow between a long but finite flexible elastic sheet and a rigid wall close to it. We derive evolution equations for the coupled dynamics of the fluid and solid in two limits corresponding to the viscously dominated and inertially dominated regimes of the flow. In both situations, the inertia of the solid remains important. We show that a long wavelength instability via a 1:1 resonance mechanism arises in both situations when the flow rate is increased beyond a critical threshold. We also compare the results of our analytical, numerical and scaling calculations with those of simple experiments. Finally we comment on the rich nonlinear dynamics of these systems which suggest that at least some aspects of voice and song production may be more a manifestation of physics rather than neurophysiology.

Serially connected solid oxide fuel cells having monolithic cores

DOEpatents

Herceg, Joseph E.

1987-01-01

A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of cell segments electrically serially connected in the flow direction, each segment consisting of electrolyte walls and interconnect that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageways; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte composite materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick. Between 2 and 50 cell segments may be connected in series.

THREE-DIMENSIONAL MODELING OF THE DYNAMICS OF THERAPEUTIC ULTRASOUND CONTRAST AGENTS

PubMed Central

Hsiao, Chao-Tsung; Lu, Xiaozhen; Chahine, Georges

2010-01-01

A 3-D thick-shell contrast agent dynamics model was developed by coupling a finite volume Navier-Stokes solver and a potential boundary element method flow solver to simulate the dynamics of thick-shelled contrast agents subjected to pressure waves. The 3-D model was validated using a spherical thick-shell model validated by experimental observations. We then used this model to study shell break-up during nonspherical deformations resulting from multiple contrast agent interaction or the presence of a nearby solid wall. Our simulations indicate that the thick viscous shell resists the contrast agent from forming a re-entrant jet, as normally observed for an air bubble oscillating near a solid wall. Instead, the shell thickness varies significantly from location to location during the dynamics, and this could lead to shell break-up caused by local shell thinning and stretching. PMID:20950929

All-solid-state flexible microsupercapacitors based on reduced graphene oxide/multi-walled carbon nanotube composite electrodes

NASA Astrophysics Data System (ADS)

Mao, Xiling; Xu, Jianhua; He, Xin; Yang, Wenyao; Yang, Yajie; Xu, Lu; Zhao, Yuetao; Zhou, Yujiu

2018-03-01

All-solid-state flexible microsupercapacitors have been intensely investigated in order to meet the rapidly growing demands for portable microelectronic devices. Herein, we demonstrate a facile, readily scalable and cost-effective laser induction process for preparing reduced graphene oxide/multi-walled carbon nanotube composite, which can be used as the interdigital electrodes in microsupercapacitors. The obtained composite exhibits high volumetric capacitance about 49.35 F cm-3, which is nearly 5 times higher than that of the pristine reduced graphene oxide film in aqueous 1.0 M H2SO4 solution (measured at a current density of 5 A cm-3 in a three-electrode testing). Additionally, an all-solid-state flexible microsupercapacitor employing these composite electrodes with PVA/H3PO4 gel electrolyte delivers high volumetric energy density of 6.47 mWh cm-3 at 10 mW cm-3 under the current density of 20 mA cm-3 as well as achieve excellent cycling stability retaining 88.6% of its initial value and outstanding coulombic efficiency after 10,000 cycles. Furthermore, the microsupercapacitors array connected in series/parallel can be easily adjusted to achieve the demands in practical applications. Therefore, this work brings a promising new candidate of prepare technologies for all-solid-state flexible microsupercapacitors as miniaturized power sources used in the portable and wearable electronics.

Modifications of Saccharomyces pastorianus cell wall polysaccharides with brewing process.

PubMed

Bastos, Rita; Coelho, Elisabete; Coimbra, Manuel A

2015-06-25

The cell wall polysaccharides of brewers spent yeast Saccharomyces pastorianus (BSY) and the inoculum yeast (IY) were studied in order to understand the changes induced by the brewing process. The hot water and alkali extractions performed solubilized mainly mannoproteins, more branched for BSY than those of IY. Also, (31)P solid state NMR showed that the BSY mannoproteins were 3 times more phosphorylated. By electron microscopy it was observed that the final residues of alkali sequential extraction until 4M KOH preserved the yeast three-dimensional structure. The final residues, composed mainly by glucans (92%), showed that the BSY, when compared with IY, contained higher amount of (1→4)-linked Glc (43% for BSY and 16% for IY) and lower (1→3)-linked Glc (17% for BSY and 42% for IY). The enzymatic treatment of final residue showed that both BSY and IY had (α1→4)-linked Glc and (β1→4)-linked Glc, in a 2:1 ratio, showing that S. pastorianus increases their cellulose-like linkages with the brewing process. Copyright © 2015 Elsevier Ltd. All rights reserved.

Numerical and Experimental Analysis on Inorganic Phase Change Material Usage in Construction

NASA Astrophysics Data System (ADS)

Muthuvel, S.; Saravanasankar, S.; Sudhakarapandian, R.; Muthukannan, M.

2014-12-01

This work demonstrates the significance of Phase Change Material (PCM) in the construction of working sheds and product storage magazines in fireworks industries to maintain less temperature variation by passive cooling. The inorganic PCM, namely Calcium Chloride Hexahydrate (CCH) is selected in this study. First, the performance of two models with inbuilt CCH was analysed, using computational fluid dynamics. A significant change in the variation of inner wall temperature was observed, particularly during the working hours. This is mainly due to passive cooling, where the heat transfer from the surroundings to the room is partially used for the phase change from solid to liquid. The experiment was carried out by constructing two models, one with PCM packed in hollow brick walls and roof, and the other one as a conventional construction. The experimental results show that the temperature of the room got significantly reduced up to 7 °C. The experimental analysis results had good agreement with the numerical analysis results, and this reveals the advantage of the PCM in the fireworks industry construction.

Macroporous Silica with Thick Framework for Steam-Stable and High-Performance Poly(ethyleneimine)/Silica CO2 Adsorbent.

PubMed

Min, Kyungmin; Choi, Woosung; Choi, Minkee

2017-06-09

Poly(ethyleneimine) (PEI)/silica has been widely studied as a solid adsorbent for post-combustion CO 2 capture. In this work, a highly macroporous silica (MacS), synthesized by secondary sintering of fumed silica, is compared with various mesoporous silicas with different pore structures as a support for PEI. The silicas with large pore diameter and volume enabled high CO 2 adsorption kinetics and capacity, because pore occlusion by the supported PEI was minimized. The steam stability of the silica structures increased with the silica wall thickness owing to suppressed framework ripening. The silicas with low steam stability showed rapid leaching of PEI, which indicated that the PEI squeezed out of the collapsed silica pores leached more readily. Consequently, MacS that had an extra-large pore volume (1.80 cm 3  g -1 ) and pore diameter (56.0 nm), and a thick wall (>10 nm), showed the most promising CO 2 adsorption kinetics and capacity as well as steam stability. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

3-D Modeling of Double-Diffusive Convection During Directional Solidification of a Non-Dilute Alloy with Application to the HgCdTe Growth Under Microgravity Conditions

NASA Technical Reports Server (NTRS)

Bune, Andris V.; Gillies, Donald C.; Lehoczky, Sandor L.

1998-01-01

A numerical calculation for a non-dilute alloy solidification was performed using the FIDAP finite element code. For low growth velocities plane front solidification occurs. The location and the shape of the interface was determined using melting temperatures from the HgCdTe liquidus curve. The low thermal conductivity of the solid HgCdTe causes thermal short circuit through the ampoule walls, resulting in curved isotherms in the vicinity of the interface. Double-diffusive convection in the melt is caused by radial temperature gradients and by material density inversion with temperature. Cooling from below and the rejection at the solid-melt interface of the heavier HgTe-rich solute each tend to reduce convection. Because of these complicating factors dimensional rather then non-dimensional modeling was performed. Estimates of convection contributions for various gravity conditions was performed parametrically. For gravity levels higher then 1 0 -7 of earth's gravity it was found that the maximum convection velocity is extremely sensitive to gravity vector orientation and can be reduced at least by factor of 50% for precise orientation of the ampoule in the microgravity environment. The predicted interface shape is in agreement with one obtained experimentally by quenching. The results of 3-D modeling are compared with previous 2-D finding. A video film featuring melt convection will be presented.

Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode.

PubMed

Hao, Pin; Zhao, Zhenhuan; Tian, Jian; Li, Haidong; Sang, Yuanhua; Yu, Guangwei; Cai, Huaqiang; Liu, Hong; Wong, C P; Umar, Ahmad

2014-10-21

Renewable, cost-effective and eco-friendly electrode materials have attracted much attention in the energy conversion and storage fields. Bagasse, the waste product from sugarcane that mainly contains cellulose derivatives, can be a promising candidate to manufacture supercapacitor electrode materials. This study demonstrates the fabrication and characterization of highly porous carbon aerogels by using bagasse as a raw material. Macro and mesoporous carbon was first prepared by carbonizing the freeze-dried bagasse aerogel; consequently, microporous structure was created on the walls of the mesoporous carbon by chemical activation. Interestingly, it was observed that the specific surface area, the pore size and distribution of the hierarchical porous carbon were affected by the activation temperature. In order to evaluate the ability of the hierarchical porous carbon towards the supercapacitor electrode performance, solid state symmetric supercapacitors were assembled, and a comparable high specific capacitance of 142.1 F g(-1) at a discharge current density of 0.5 A g(-1) was demonstrated. The fabricated solid state supercapacitor displayed excellent capacitance retention of 93.9% over 5000 cycles. The high energy storage ability of the hierarchical porous carbon was attributed to the specially designed pore structures, i.e., co-existence of the micropores and mesopores. This research has demonstrated that utilization of sustainable biopolymers as the raw materials for high performance supercapacitor electrode materials is an effective way to fabricate low-cost energy storage devices.

Development of an On-board Failure Diagnostics and Prognostics System for Solid Rocket Booster

NASA Technical Reports Server (NTRS)

Smelyanskiy, Vadim N.; Luchinsky, Dmitry G.; Osipov, Vyatcheslav V.; Timucin, Dogan A.; Uckun, Serdar

2009-01-01

We develop a case breach model for the on-board fault diagnostics and prognostics system for subscale solid-rocket boosters (SRBs). The model development was motivated by recent ground firing tests, in which a deviation of measured time-traces from the predicted time-series was observed. A modified model takes into account the nozzle ablation, including the effect of roughness of the nozzle surface, the geometry of the fault, and erosion and burning of the walls of the hole in the metal case. The derived low-dimensional performance model (LDPM) of the fault can reproduce the observed time-series data very well. To verify the performance of the LDPM we build a FLUENT model of the case breach fault and demonstrate a good agreement between theoretical predictions based on the analytical solution of the model equations and the results of the FLUENT simulations. We then incorporate the derived LDPM into an inferential Bayesian framework and verify performance of the Bayesian algorithm for the diagnostics and prognostics of the case breach fault. It is shown that the obtained LDPM allows one to track parameters of the SRB during the flight in real time, to diagnose case breach fault, and to predict its values in the future. The application of the method to fault diagnostics and prognostics (FD&P) of other SRB faults modes is discussed.

Doppler Assessment of Diastolic Function Reflect the Severity of Injury in Rats With Chronic Heart Failure.

PubMed

Sanchez, Pablo; Lancaster, Jordan J; Weigand, Kyle; Mohran, Saffie-Alrahman Ezz-Eldin; Goldman, Steven; Juneman, Elizabeth

2017-10-01

For chronic heart failure (CHF), more emphasis has been placed on evaluation of systolic as opposed to diastolic function. Within the study of diastology, measurements of left ventricular (LV) longitudinal myocardial relaxation have the most validation. Anterior wall radial myocardial tissue relaxation velocities along with mitral valve inflow (MVI) patterns are applicable diastolic parameters in the differentiation between moderate and severe disease in the ischemic rat model of CHF. Myocardial tissue relaxation velocities correlate with traditional measurements of diastolic function (ie, hemodynamics, Tau, and diastolic pressure-volume relationships). Male Sprague-Dawley rats underwent left coronary artery ligation or sham operation. Echocardiography was performed at 3 and 6 weeks after coronary ligation to evaluate LV ejection fraction (EF) and LV diastolic function through MVI patterns (E, A, and E/A) and Doppler imaging of the anterior wall (e' and a'). The rats were categorized into moderate or severe CHF according to their LV EF at 3 weeks postligation. Invasive hemodynamic measurements with solid-state pressure catheters were obtained at the 6-week endpoint. Moderate (N = 20) and severe CHF (N = 22) rats had significantly (P < .05) different EFs, hemodynamics, and diastolic pressure-volume relationships. Early diastolic anterior wall radial relaxation velocities as well as E/e' ratios separated moderate from severe CHF and both diastolic parameters had strong correlations with invasive hemodynamic measurements of diastolic function. Radial anterior wall e' and E/e' can be used for serial assessment of diastolic function in rats with moderate and severe CHF. Copyright © 2017 Elsevier Inc. All rights reserved.

Effects of sedimenting particles on the turbulence structure in a horizontal channel flow

NASA Astrophysics Data System (ADS)

Tay, Godwin F. K.; Kuhn, David C. S.; Tachie, Mark F.

2015-02-01

This work presents the results of experiments conducted in a horizontal channel to characterize low Reynolds number turbulent flows in the presence of small solid particles. The particle diameter relative to the integral length scale, dp/Λx, is approximately 0.02. Particles and fluid turbulence characteristics are measured for three average solid volume fractions of approximately ϕv = 2.0 × 10-4, 4.0 × 10-4, and 8.0 × 10-4 under conditions where the particle number density is evolving due to deposition. The results indicate that the mean slip between particles and the fluid is important only close to the wall. Away from the wall, the particles and unladen fluid mean velocities are similar. Differences between particles and the unladen fluid statistics are more pronounced in the wall-normal velocity fluctuations than the streamwise velocity fluctuations and Reynolds shear stress due to the stronger effect of the gravitational force in the wall-normal direction. The fluid turbulent intensities show no dependency on loading, but the peak Reynolds shear stress is significantly reduced. A quadrant decomposition of the Reynolds shear stress revealed a corresponding reduction in the ejections and sweeps for the laden flow in comparison with the unladen flow. Swirling strength and vorticity root-mean-square fluctuations decayed due to the damping effect of particles. The influence of particles on the turbulence structure was examined using two-point correlations of the velocity fluctuations and swirling strength, where it was demonstrated that the wall structures are attached eddies which are more extensive (much larger) in the particle-laden flow compared to the unladen flow.

Polarization-induced local pore-wall functionalization for biosensing: from micropore to nanopore.

PubMed

Liu, Jie; Pham, Pascale; Haguet, Vincent; Sauter-Starace, Fabien; Leroy, Loïc; Roget, André; Descamps, Emeline; Bouchet, Aurélie; Buhot, Arnaud; Mailley, Pascal; Livache, Thierry

2012-04-03

The use of biological-probe-modified solid-state pores in biosensing is currently hindered by difficulties in pore-wall functionalization. The surface to be functionalized is small and difficult to target and is usually chemically similar to the bulk membrane. Herein, we demonstrate the contactless electrofunctionalization (CLEF) approach and its mechanism. This technique enables the one-step local functionalization of the single pore wall fabricated in a silica-covered silicon membrane. CLEF is induced by polarization of the pore membrane in an electric field and requires a sandwich-like composition and a conducting or semiconducting core for the pore membrane. The defects in the silica layer of the micropore wall enable the creation of an electric pathway through the silica layer, which allows electrochemical reactions to take place locally on the pore wall. The pore diameter is not a limiting factor for local wall modification using CLEF. Nanopores with a diameter of 200 nm fabricated in a silicon membrane and covered with native silica layer have been successfully functionalized with this method, and localized pore-wall modification was obtained. Furthermore, through proof-of-concept experiments using ODN-modified nanopores, we show that functionalized nanopores are suitable for translocation-based biosensing.

Effect of solid boundaries on a motile microorganism in a viscoelastic fluid

NASA Astrophysics Data System (ADS)

Karimi, Alireza; Li, Gaojin; Ardekani, Arezoo

2014-11-01

Microorganisms swimming in viscoelastic fluids are ubiquitous in nature; this includes biofilms grown on surfaces, Helicobacter pylori colonizing in the mucus layer covering the stomach and spermatozoa swimming through cervical mucus inside the mammalian female reproductive tract. Previous studies have focused on the locomotion of microorganisms in an unbounded viscoelastic fluid. However in many situations, microorganisms interact with solid boundaries and their hydrodynamic interaction is poorly understood. In this work, we numerically study the effect of solid boundaries on the swimming behavior of an archetypal low-Reynolds number swimmer, called ``squirmer,'' in a viscoelastic fluid. A Giesekus constitutive equation is used to model both viscoelasticity and shear-thinning behavior of the background fluid. We found that the time a neutral squirmer spends in the close proximity of the wall increases with polymer relaxation time and reaches a maximum at Weissenberg number of unity. A pusher is found to be trapped near the wall in a viscoelastic fluid, but the puller is less affected. This publication was made possible, in part, with support from NSF (Grant No. CBET-1150348-CAREER) and Indiana Clinical and Translational Sciences Institute Collaboration in Biomedical/Translational Research (Grant No. TR000006) from NIH.

Thin and flexible all-solid supercapacitor prepared from novel single wall carbon nanotubes/polyaniline thin films obtained in liquid-liquid interfaces

NASA Astrophysics Data System (ADS)

de Souza, Victor Hugo Rodrigues; Oliveira, Marcela Mohallem; Zarbin, Aldo José Gorgatti

2014-08-01

The present work describes for the first time the synthesis and characterization of single wall carbon nanotubes/polyaniline (SWNTs/PAni) nanocomposite thin films in a liquid-liquid interface, as well as the subsequent construction of a flexible all-solid supercapacitor. Different SWNTs/PAni nanocomposites were prepared by varying the ratio of SWNT to aniline, and the samples were characterized by scanning and transmission electron microscopy, Raman and UV-Vis spectroscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The pseudo-capacitive behavior of the nanocomposites was evaluated by charge/discharge galvanostatic measurements. The presence of the SWNTs affected the electronic and vibrational properties of the polyaniline and also improved the pseudo-capacitive behavior of the conducting polymer. A very thin and flexible all-solid device was manufactured using two electrodes (polyethylene terephthalate-PET covered with the SWNT/PAni nanocomposite separated by a H2SO4-PVA gel electrolyte). The pseudo-capacitive behavior was characterized by a volumetric specific capacitance of approximately 76.7 F cm-3, even under mechanical deformation, indicating that this nanocomposite has considerable potential for application in new-generation energy storage devices.

Glass Masonry - Experimental Verification of Bed Joint under Shear

NASA Astrophysics Data System (ADS)

Fíla, J.; Eliášová, M.; Sokol, Z.

2017-10-01

Glass is considered as a traditional material for building industry but was mostly used for glazing of the windows. At present, glass is an integral part of contemporary architecture where glass structural elements such as beams, stairs, railing ribs or columns became popular in the last two decades. However, using glass as structural material started at the beginning of 20th century, when masonry from hollow glass blocks were used. Using solid glass brick is very rare and only a few structures with solid glass bricks walls have been built in the last years. Pillars and walls made from solid glass bricks are mainly loaded by compression and/or bending from the eccentricity of vertical load or wind load. Due to high compressive strength of glass, the limiting factor of the glass masonry is the joint between the glass bricks as the smooth surface requires another type of mortar / glue compared to traditional masonry. Shear resistance and failure modes of brick bed joint was determined during series of tests using various mortars, two types of surface treatment and different thickness of the mortar joint. Shear tests were completed by small scale tests for mortar - determination of flexural and compressive strength of hardened mortar.

Numerical studies of cavitation erosion on an elastic-plastic material caused by shock-induced bubble collapse

NASA Astrophysics Data System (ADS)

Turangan, C. K.; Ball, G. J.; Jamaluddin, A. R.; Leighton, T. G.

2017-09-01

We present a study of shock-induced collapse of single bubbles near/attached to an elastic-plastic solid using the free-Lagrange method, which forms the latest part of our shock-induced collapse studies. We simulated the collapse of 40 μm radius single bubbles near/attached to rigid and aluminium walls by a 60 MPa lithotripter shock for various scenarios based on bubble-wall separations, and the collapse of a 255 μm radius bubble attached to aluminium foil with a 65 MPa lithotripter shock. The coupling of the multi-phases, compressibility, axisymmetric geometry and elastic-plastic material model within a single solver has enabled us to examine the impingement of high-speed liquid jets from the shock-induced collapsing bubbles, which imposes an extreme compression in the aluminium that leads to pitting and plastic deformation. For certain scenarios, instead of the high-speed jet, a radially inwards flow along the aluminium surface contracts the bubble to produce a `mushroom shape'. This work provides methods for quantifying which parameters (e.g. bubble sizes and separations from the solid) might promote or inhibit erosion on solid surfaces.

Heat Transfer at a Long Electrically-Simulated Water Wall in a Circulating Fluidised Bed

NASA Astrophysics Data System (ADS)

Sundaresan, R.; Kolar, Ajit Kumar

In the present work, heat transfer measurements are reported in a 100mm square, 5.5 m tall, cold CFB. The test section is a 19 mm OD electrically heated heat transfer tube, 4.64 m tall (covering more than 80% of the CFB height), sandwiched between two equally tall dummy tubes of 19mm OD, thus simulating a water wall geometry, forming one wall of the CFB. Narrow cut sand particles of mean diameters 156, 256, and 362 micrometers, and a wide cut sample of mean diameter 265 micrometer were used as the bed material. The superficial gas velocity ranged from 4.2 to 8.2 m/s, and the solids recycle flux varied from 17 to 110 kg/m2s. Local heat transfer coefficient at the simulated water wall varies, as expected from a low value at the top of the riser to a high value at the bottom, with an interesting increasing and decreasing trend in between. The average heat transfer coefficients were compared with those available in open literature. Correlations for average heat transfer coefficient are presented, both in terms of an average suspension density and also in terms of important nondimensional numbers, namely, Froude number, relative solids flux and velocity ratio. Comparisons are also made with predictions of relevant heat transfer models. Based on the present fifty-five experimental data points, the following correlation was presented with a correlation coefficient of 0.862 and maximum error is ± 15 %.

High coupling efficiency of foam spherical hohlraum driven by 2ω laser light

NASA Astrophysics Data System (ADS)

Chen, Yao-Hua; Lan, Ke; Zheng, Wanguo; Campbell, E. M.

2018-02-01

The majority of solid state laser facilities built for laser fusion research irradiate targets with third harmonic light (0.35 μm) up-converted from the fundamental Nd wavelength at 1.05 μm. The motivation for this choice of wavelength is improved laser-plasma coupling. Significant disadvantages to this choice of wavelength are the reduced damage threshold of optical components and the efficiency of energy conversion to third harmonic light. Both these issues are significantly improved if second harmonic (0.53 μm) radiation is used, but theory and experiments have shown lower optical to x-ray energy conversion efficiency and increased levels of laser-plasma instabilities, resulting in reduced laser-target coupling. In this letter, we propose to use a 0.53 μm laser for the laser ignition facilities and use a low density foam wall to increase the coupling efficiency from the laser to the capsule and present two-dimensional radiation-hydrodynamic simulations of 0.53 μm laser light irradiating an octahedral-spherical hohlraum with a low density foam wall. The simulations show that the reduced optical depth of the foam wall leads to an increased laser-light conversion into thermal x-rays and about 10% higher radiation flux on the capsule than that achieved with 0.35 μm light irradiating a solid density wall commonly used in laser indirect drive fusion research. The details of the simulations and their implications and suggestions for wavelength scaling coupled with innovative hohlraum designs will be discussed.

Reusable glucose sensing using carbon nanotube-based self-assembly

NASA Astrophysics Data System (ADS)

Bhattacharyya, Tamoghna; Samaddar, Sarbani; Dasgupta, Anjan Kr.

2013-09-01

Lipid functionalized single walled carbon nanotube-based self assembly forms a super-micellar structure. This assemblage has been exploited to trap glucose oxidase in a molecular cargo for glucose sensing. The advantage of such a molecular trap is that all components of this unique structure (both the trapping shell and the entrapped enzyme) are reusable and rechargeable. The unique feature of this sensing method lies in the solid state functionalization of single walled carbon nanotubes that facilitates liquid state immobilization of the enzyme. The method can be used for soft-immobilization (a new paradigm in enzyme immobilization) of enzymes with better thermostability that is imparted by the strong hydrophobic environment provided through encapsulation by the nanotubes.Lipid functionalized single walled carbon nanotube-based self assembly forms a super-micellar structure. This assemblage has been exploited to trap glucose oxidase in a molecular cargo for glucose sensing. The advantage of such a molecular trap is that all components of this unique structure (both the trapping shell and the entrapped enzyme) are reusable and rechargeable. The unique feature of this sensing method lies in the solid state functionalization of single walled carbon nanotubes that facilitates liquid state immobilization of the enzyme. The method can be used for soft-immobilization (a new paradigm in enzyme immobilization) of enzymes with better thermostability that is imparted by the strong hydrophobic environment provided through encapsulation by the nanotubes. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr02609d

Direct Determination of Hydroxymethyl Conformations of Plant Cell Wall Cellulose Using 1H Polarization Transfer Solid-State NMR.

PubMed

Phyo, Pyae; Wang, Tuo; Yang, Yu; O'Neill, Hugh; Hong, Mei

2018-05-14

In contrast to the well-studied crystalline cellulose of microbial and animal origins, cellulose in plant cell walls is disordered due to its interactions with matrix polysaccharides. Plant cell wall (PCW) is an undisputed source of sustainable global energy; therefore, it is important to determine the molecular structure of PCW cellulose. The most reactive component of cellulose is the exocyclic hydroxymethyl group: when it adopts the tg conformation, it stabilizes intrachain and interchain hydrogen bonding, while gt and gg conformations destabilize the hydrogen-bonding network. So far, information about the hydroxymethyl conformation in cellulose has been exclusively obtained from 13 C chemical shifts of monosaccharides and oligosaccharides, which do not reflect the environment of cellulose in plant cell walls. Here, we use solid-state Nuclear Magnetic Resonance (ssNMR) spectroscopy to measure the hydroxymethyl torsion angle of cellulose in two model plants, by detecting distance-dependent polarization transfer between H4 and H6 protons in 2D 13 C- 13 C correlation spectra. We show that the interior crystalline portion of cellulose microfibrils in Brachypodium and Arabidopsis cell walls exhibits H4-H6 polarization transfer curves that are indicative of a tg conformation, whereas surface cellulose chains exhibit slower H4-H6 polarization transfer that is best fit to the gt conformation. Joint constraints by the H4-H6 polarization transfer curves and 13 C chemical shifts indicate that it is unlikely for interior cellulose to have a significant population of the gt and gg conformation mixed with the tg conformation, while surface cellulose may adopt a small percentage of the gg conformation. These results provide new constraints to the structure and matrix interactions of cellulose in plant cell walls, and represent the first direct determination of a torsion angle in an important noncrystalline carbohydrate polymer.

5. Credit BG. View looking northwest at eastern facade of ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

5. Credit BG. View looking northwest at eastern facade of Test Stand 'E' (Building 4259/E-60), solid rocket motor test facility. Central bay (high concrete walls) was used for testing large solid motors in a vertical position. A second smaller bay to the north fired smaller motors horizontally. Just south of the large bay is an equipment room with access to the tunnel system; entrance is by small single door on east side. The large double doors lead to a third bay used for X-raying solid rocket motors before testing. - Jet Propulsion Laboratory Edwards Facility, Test Stand E, Edwards Air Force Base, Boron, Kern County, CA

Numerical Modeling of Conjugate Heat Transfer in Fluid Network

NASA Technical Reports Server (NTRS)

Majumdar, Alok

2004-01-01

Fluid network modeling with conjugate heat transfer has many applications in Aerospace engineering. In modeling unsteady flow with heat transfer, it is important to know the variation of wall temperature in time and space to calculate heat transfer between solid to fluid. Since wall temperature is a function of flow, a coupled analysis of temperature of solid and fluid is necessary. In cryogenic applications, modeling of conjugate heat transfer is of great importance to correctly predict boil-off rate in propellant tanks and chill down of transfer lines. In TFAWS 2003, the present author delivered a paper to describe a general-purpose computer program, GFSSP (Generalized Fluid System Simulation Program). GFSSP calculates flow distribution in complex flow circuit for compressible/incompressible, with or without heat transfer or phase change in all real fluids or mixtures. The flow circuit constitutes of fluid nodes and branches. The mass, energy and specie conservation equations are solved at the nodes where as momentum conservation equations are solved at the branches. The proposed paper describes the extension of GFSSP to model conjugate heat transfer. The network also includes solid nodes and conductors in addition to fluid nodes and branches. The energy conservation equations for solid nodes solves to determine the temperatures of the solid nodes simultaneously with all conservation equations governing fluid flow. The numerical scheme accounts for conduction, convection and radiation heat transfer. The paper will also describe the applications of the code to predict chill down of cryogenic transfer line and boil-off rate of cryogenic propellant storage tank.

Obseration of flow regime transition in CFB riser using an LDV

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yue, Paul C.; Mei, Joseph S.; Shadle, Lawrence J.

2011-01-01

The solids flow in a circulating fluidized bed (CFB) riser is often described to have a core-annular structure. For a given superficial gas velocity, at the initial introduction of solids into a riser a flow structure of dilute upflow regime exists. Continuing to increase the solids flow in the riser transitions the flow structure to the core-annular flow regime. However, with further increase of solids flow a condition is reached, depending on the superficial gas velocity, where all the solids across the riser cross section flow upwards, even those at the wall. When the solids flux, solids fraction and gasmore » velocity are relatively high, such a condition is described as the dense phase suspense upflow (DSU) regime. In this paper we report our observations of these flow regime transitions by using a laser Doppler velocimeter (LDV) to monitor the upward and downward particle flow velocities at and near the riser wall of the National Energy Technology Laboratory’s 30.4 centimeters diameter CFB cold flow model. The particles were high density polyethylene (PPE) spheres with a Sauter mean diameter of 861 micron and a density of 800 kg/m3. Three superficial gas velocities of 6.55 m/s, 10.67 m/s and 13.72 m/s were used in this study. For the case of superficial gas velocity 6.55 m/s, the experimental data show that the transition from dilute upflow to core-annular flow occurred when the solids flux was about 7 kg/m{sup 2}-s and the transition from core-annular flow to dense suspension upflow was about 147 kg/m{sup 2}-s. As the superficial gas velocity was increased to 10.67 m/s the corresponding flow regime transitions were at 34 kg/m{sup 2}-s and 205 kg/m{sup 2}-s, respectively. For the case of superficial gas velocity of 13.72 m/s the data showed no distinct transition of flow regimes. The particles were all upflow for the range of solids fluxes from 10 kg/m{sup 2}-s to 286 kg/m{sup 2}-s.« less

Thermal Counterflow in a Periodic Channel with Solid Boundaries

NASA Astrophysics Data System (ADS)

Baggaley, Andrew W.; Laurie, Jason

2015-01-01

We perform numerical simulations of finite temperature quantum turbulence produced through thermal counterflow in superfluid He, using the vortex filament model. We investigate the effects of solid boundaries along one of the Cartesian directions, assuming a laminar normal fluid with a Poiseuille velocity profile, whilst varying the temperature and the normal fluid velocity. We analyze the distribution of the quantized vortices, reconnection rates, and quantized vorticity production as a function of the wall-normal direction. We find that the quantized vortex lines tend to concentrate close to the solid boundaries with their position depending only on temperature and not on the counterflow velocity. We offer an explanation of this phenomenon by considering the balance of two competing effects, namely the rate of turbulent diffusion of an isotropic tangle near the boundaries and the rate of quantized vorticity production at the center. Moreover, this yields the observed scaling of the position of the peak vortex line density with the mutual friction parameter. Finally, we provide evidence that upon the transition from laminar to turbulent normal fluid flow, there is a dramatic increase in the homogeneity of the tangle, which could be used as an indirect measure of the transition to turbulence in the normal fluid component for experiments.

Polydopamine-coated magnetic molecularly imprinted polymer for the selective solid-phase extraction of cinnamic acid, ferulic acid and caffeic acid from radix scrophulariae sample.

PubMed

Yin, Yuli; Yan, Liang; Zhang, Zhaohui; Wang, Jing; Luo, Ningjing

2016-04-01

We describe novel cinnamic acid polydopamine-coated magnetic imprinted polymers for the simultaneous selective extraction of cinnamic acid, ferulic acid and caffeic acid from radix scrophulariae sample. The novel magnetic imprinted polymers were synthesized by surface imprinting polymerization using magnetic multi-walled carbon nanotubes as the support material, cinnamic acid as the template and dopamine as the functional monomer. The magnetic imprinted polymers were characterized by transmission electron microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy and vibrating sample magnetometry. The results revealed that the magnetic imprinted polymers had outstanding magnetic properties, high adsorption capacity, selectivity and fast kinetic binding toward cinnamic acid, ferulic acid and caffeic acid. Coupled with high-performance liquid chromatography, the extraction conditions of the magnetic imprinted polymers as a magnetic solid-phase extraction sorbent were investigated in detail. The proposed imprinted magnetic solid phase extraction procedure has been used for the purification and enrichment of cinnamic acid, ferulic acid and caffeic acid successfully from radix scrophulariae extraction sample with recoveries of 92.4-115.0% for cinnamic acid, 89.4-103.0% for ferulic acid and 86.6-96.0% for caffeic acid. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

An Internal Thermal Environment Model of an Aluminized Solid Rocket Motor with Experimental Validation

NASA Technical Reports Server (NTRS)

Martin, Heath T.

2015-01-01

Due to the severity of the internal solid rocket motor (SRM) environment, very few direct measurements of that environment exist; therefore, the appearance of such data provides a unique opportunity to assess current thermal/fluid modeling capabilities. As part of a previous study of SRM internal insulation performance, the internal thermal environment of a laboratory-scale SRM featuring aluminized propellant was characterized with two types of custom heat-flux calorimeters: one that measured the total heat flux to a graphite slab within the SRM chamber and another that measured the thermal radiation flux. Therefore, in the current study, a thermal/fluid model of this lab-scale SRM was constructed using ANSYS Fluent to predict not only the flow field structure within the SRM and the convective heat transfer to the interior walls, but also the resulting dispersion of alumina droplets and the radiative heat transfer to the interior walls. The dispersion of alumina droplets within the SRM chamber was determined by employing the Lagrangian discrete phase model that was fully coupled to the Eulerian gas-phase flow. The P1-approximation was engaged to model the radiative heat transfer through the SRM chamber where the radiative contributions of the gas phase were ignored and the aggregate radiative properties of the alumina dispersion were computed from the radiative properties of its individual constituent droplets, which were sourced from literature. The convective and radiative heat fluxes computed from the thermal/fluid model were then compared with those measured in the lab-scale SRM test firings and the modeling approach evaluated.

Augmenting groundwater monitoring networks near landfills with slurry cutoff walls.

PubMed

Hudak, Paul F

2004-01-01

This study investigated the use of slurry cutoff walls in conjunction with monitoring wells to detect contaminant releases from a solid waste landfill. The 50 m wide by 75 m long landfill was oriented oblique to regional groundwater flow in a shallow sand aquifer. Computer models calculated flow fields and the detection capability of six monitoring networks, four including a 1 m wide by 50 m long cutoff wall at various positions along the landfill's downgradient boundaries and upgradient of the landfill. Wells were positioned to take advantage of convergent flow induced downgradient of the cutoff walls. A five-well network with no cutoff wall detected 81% of contaminant plumes originating within the landfill's footprint before they reached a buffer zone boundary located 50 m from the landfill's downgradient corner. By comparison, detection efficiencies of networks augmented with cutoff walls ranged from 81 to 100%. The most efficient network detected 100% of contaminant releases with four wells, with a centrally located, downgradient cutoff wall. In general, cutoff walls increased detection efficiency by delaying transport of contaminant plumes to the buffer zone boundary, thereby allowing them to increase in size, and by inducing convergent flow at downgradient areas, thereby funneling contaminant plumes toward monitoring wells. However, increases in detection efficiency were too small to offset construction costs for cutoff walls. A 100% detection efficiency was also attained by an eight-well network with no cutoff wall, at approximately one-third the cost of the most efficient wall-augmented network.

Validation of a Node-Centered Wall Function Model for the Unstructured Flow Code FUN3D

NASA Technical Reports Server (NTRS)

Carlson, Jan-Renee; Vasta, Veer N.; White, Jeffery

2015-01-01

In this paper, the implementation of two wall function models in the Reynolds averaged Navier-Stokes (RANS) computational uid dynamics (CFD) code FUN3D is described. FUN3D is a node centered method for solving the three-dimensional Navier-Stokes equations on unstructured computational grids. The first wall function model, based on the work of Knopp et al., is used in conjunction with the one-equation turbulence model of Spalart-Allmaras. The second wall function model, also based on the work of Knopp, is used in conjunction with the two-equation k-! turbulence model of Menter. The wall function models compute the wall momentum and energy flux, which are used to weakly enforce the wall velocity and pressure flux boundary conditions in the mean flow momentum and energy equations. These wall conditions are implemented in an implicit form where the contribution of the wall function model to the Jacobian are also included. The boundary conditions of the turbulence transport equations are enforced explicitly (strongly) on all solid boundaries. The use of the wall function models is demonstrated on four test cases: a at plate boundary layer, a subsonic di user, a 2D airfoil, and a 3D semi-span wing. Where possible, different near-wall viscous spacing tactics are examined. Iterative residual convergence was obtained in most cases. Solution results are compared with theoretical and experimental data for several variations of grid spacing. In general, very good comparisons with data were achieved.

Facile preparation of raisin-bread sandwich-structured magnetic graphene/mesoporous silica composites with C18-modified pore-walls for efficient enrichment of phthalates in environmental water.

PubMed

Huang, Danni; Wang, Xianying; Deng, Chunhui; Song, Guoxin; Cheng, Hefa; Zhang, Xiangmin

2014-01-17

In this study, novel raisin-bread sandwich-structured magnetic graphene/mesoporous silica composites with C18-modified interior pore-walls (mag-graphene@mSiO2-C18) were synthesized by coating mesoporous silica layers onto each side of magnetic graphene through a surfactant-mediated co-condensation sol-gel process. The prepared functionalized nanocomposites possessed marvelous properties of extended plate-like morphology, fine water dispersibility, high magnetic response, large surface area (315.4cm(2)g(-1)), uniform pore size (3.3nm) and C18-modified interior pore-walls. Several kinds of phthalates were selected as model analytes to systematically evaluate the performance of adsorbents in extracting hydrophobic molecules followed by gas chromatography-mass spectrometry analyses. Various extraction parameters, including pH value of sample solution, amounts of adsorbents, adsorption time, species and volume of eluting solvent, and desorption time were optimized. The anti-interference ability to macromolecular proteins was also investigated. Method validations such as linearity, recovery, reproducibility, and limit of detection were also studied. Finally, mag-graphene@mSiO2-C18 composites were successfully applied to analyzing phthalates in environmental water samples. The results indicated that this novel approach offered an attractive alternative for rapid, convenient, efficient and selective magnetic solid-phase extraction for targeted hydrophobic compounds. Copyright © 2013 Elsevier B.V. All rights reserved.

Inertial Waves and Steady Flows in a Liquid Filled Librating Cylinder

NASA Astrophysics Data System (ADS)

Subbotin, Stanislav; Dyakova, Veronika

2018-05-01

The fluid flow in a non-uniformly rotating (librating) cylinder about a horizontal axis is experimentally studied. In the absence of librations the fluid performs a solid-body rotation together with the cavity. Librations lead to the appearance of steady zonal flow in the whole cylinder and the intensive steady toroidal flows near the cavity corners. If the frequency of librations is twice lower than the mean rotation rate the inertial waves are excited. The oscillating motion associated with the propagation of inertial wave in the fluid bulk leads to the appearance of an additional steady flow in the Stokes boundary layers on the cavity side wall. In this case the heavy particles of the visualizer are assembled on the side wall into ring structures. The patterns are determined by the structure of steady flow, which in turn depends on the number of reflections of inertial wave beams from the cavity side wall. For some frequencies, inertial waves experience spatial resonance, resulting in inertial modes, which are eigenmodes of the cavity geometry. The resonance of the inertial modes modifies the steady flow structure close to the boundary layer that is manifested in the direct rebuilding of patterns. It is shown that the intensity of zonal flow, as well as the intensity of steady flows excited by inertial waves, is proportional to the square of the amplitude of librations.

Single-stage evaluation of highly-loaded high-Mach-number compressor stages 5. Data and performance of baseline, corner-blow wall suction and combined corner blow wall suction stator

NASA Technical Reports Server (NTRS)

Nikkanen, J. P.; Brooky, J. P.

1972-01-01

A single-stage compressor with a rotor tip speed of 1600 ft/sec and a 0.5 hub tip ratio was used to investigate the effects of several stator endwall treatment methods on stage range and performance. These endwall treatment methods consisted of stator corner-blow, annular wall suction upstream of stator leading edge, and combined corner-blow and annular wall suction. The overall stage performance with corner blow was essentially the same as the baseline performance. The performance for the annular wall suction and the combined corner-blow and wall suction showed a reduction in peak efficiency of 2.5 percentage points compared to the baseline data.

Heat exchangers comprising at least one porous member positioned within a casing

DOEpatents

Turner, Terry D [Idaho Falls, ID; Wilding, Bruce M [Idaho Falls, ID

2011-11-22

A heat exchanger and associated methods for sublimating solid particles therein, for conveying fluids therethrough, or both. The heat exchanger includes a chamber, and a porous member having a porous wall having pores in communication with the chamber and an interior of the porous member. A first fluid is conveyed into the porous member while a second fluid is conveyed into the porous member through the porous wall. The second fluid may form a positive flow boundary layer along the porous wall to reduce or eliminate substantial contact between the first fluid and the interior of the porous wall. The combined first and second fluids are conveyed out of the porous member. Additionally, the first fluid and the second fluid may each be conveyed into the porous member at different temperatures and may exit the porous member at substantially the same temperature.

ESS Smelting Technology

NASA Astrophysics Data System (ADS)

Erasmus, L. J.; Fourie, L. J.

2017-02-01

The envirosteel smelter is a rectangular furnace with a large free board volume and multiple channel inductors mounted below the hearth. The raw materials are charged against the back wall forming an inclined heap sloping toward the front long wall. The feed blend is spread in thin layers over the surface of the heap and is heated by exposure to radiation from the free board. Reducing conditions in the top layer of the heap permit gas-solid reduction. Metal, in the hearth of the furnace, flows into the channel inductor where it is heated. The heated metal flows back against the front long wall to under the heap. The bottom of the heap is continuously melted by energy transferred from the metal layer. The two off-gas ducts are located in the short end walls. The combustion air is heated to around 800°C by a furnace gas in an external heat exchanger.

An experimental investigation of the subcritical and supercritical flow about a swept semispan wing

NASA Technical Reports Server (NTRS)

Lockman, W. K.; Seegmiller, H. L.

1983-01-01

An experimental investigation of the turbulent, subcritical and supercritical flow over a swept, semispan wing in a solid wall wind tunnel is described. The program was conducted over a range of Mach numbers, Reynolds numbers, and angles of attack to provide a variety of test cases for assessment of wing computer codes and tunnel wall interference effects. Wing flows both without and with three dimensional flow separation are included. Data include mean surface pressures for both the wing and tunnel walls; surface oil flow patterns on the wing; and mean velocity, flow field surveys. The results are given in tabular form and presented graphically to illustrate some of the effects of the test parameters. Comparisons of the wing pressure data with the results from two inviscid wing codes are also shown to assess the importance of viscous flow and tunnel wall effects.

Cellular schwannoma arising from the gastric wall misdiagnosed as a gastric stromal tumor: A case report.

PubMed

Wang, Guangyao; Chen, Ping; Zong, Liang; Shi, Lei; Zhao, Wei

2014-02-01

Cellular schwannomas have been previously described at almost every anatomic location of the human body, but reports in the gastric wall are rare. The current study presents a rare case of cellular schwannoma originating from the gastric wall. Computed tomography revealed a 5.6×5.3×4.0-cm 3 solid mass located in the posterior wall of the stomach. Open laparotomy confirmed its mesenchymal origin. Microscopically, the tissue was composed of spindle-shaped and fascicularly-arranged cells, but mitotic figures were rare. Immunohistochemical staining showed that the tumor was negative for cluster of differentiation (CD)117, CD34, smooth muscle actin and desmin, but positive for S-100 and Ki67. The patient presented no evidence of recurrence and metastasis during follow-up. Gastric cellular schwannomas may be diagnosed by clinical characteristics, histological observations and immunohistochemical markers.

The collapse of a cavitation bubble in a corner

NASA Astrophysics Data System (ADS)

Peters, Ivo; Tagawa, Yoshiyuki

2017-11-01

The collapse of cavitation bubbles is influenced by the surrounding geometry. A classic example is the collapse of a bubble near a solid wall, where a fast jet is created towards the wall. The addition of a second wall creates a non-axisymmetric flow field, which influences the displacement and jet formation during the collapse of a bubble. In this experimental study we generate mm-sized vapor bubbles using a focused pulsed laser, giving us full control over the position of the bubble. The corner geometry is formed by two glass slides. High-speed imaging reveals the directional motion of the bubble during the collapse. We find that the bubble displacement cannot be fully described by a simple superposition of the bubble dynamics of the two walls individually. Comparison of our experimental results to a model based on potential flow shows a good agreement for the direction of displacement.

Consistent Structural Integrity and Efficient Certification with Analysis. Volume 3: Appendices of Verification and Validation Examples, Correlation Factors, and Failure Criteria

DTIC Science & Technology

2005-05-01

TANK WALL.........................74 6 VERIFICATION - BONDED JOINT HOMOGENOUS ISOTROPIC AND ORTHOTROPIC DELALE & ERDOGAN PUBLICATION (SIX EXAMPLES...developed for verification of BondJo 87 6.3.2 Adhesive stress comparisons between BondJo, Ansys solid model FEA and Delale and Erdogan plate theory 88...comparisons for condition 1 91 6.3.6 Adhesive stress comparisons between BondJo, Ansys solid model FEA and Delale and Erdogan plate theory 92 x FIGURE

The Development of the Wall Momentum Erosive Burning Scaling Law and Macro Scale Erosive Burning Model

DTIC Science & Technology

2010-05-01

burn rate in excess of 2 in/sec at 1000 psi, and Mach numbers that reach 1.0 at the aft end at ignition . Typically, motors with high burning rate...37 VI I. INTRODUCTION Interior ballistics of solid propellant rocket motors continues to be an engineering discipline that is...and one open source paper published between 2005 and 2009 [2, 3, 13]. II. BACKGROUND Erosive burning is a term used in the solid rocket motor

Investigation of Small-Caliber Primer Function Using a Multiphase Computational Model

DTIC Science & Technology

2008-07-01

all solid walls along with specified inflow at the primer orifice (0.102 cm < Y < 0.102 cm at X = 0). Initially , the entire flowfield is filled...to explicitly treat both the gas and solid phase. The model is based on the One Dimensional Turbulence modeling approach that has recently emerged as...a powerful tool in multiphase simulations. Initial results are shown for the model run as a stand-alone code and are compared to recent experiments

Controlled functionalization of carbonaceous fibers for asymmetric solid-state micro-supercapacitors with high volumetric energy density.

PubMed

Yu, Dingshan; Goh, Kunli; Zhang, Qiang; Wei, Li; Wang, Hong; Jiang, Wenchao; Chen, Yuan

2014-10-22

A 1.8 V asymmetric solid-state flexible micro-supercapacitor is designed with one MnO2 -coated reduced graphene oxide/single-walled carbon nanotube (rGO/SWCNT) composite fiber as positive electrode and one nitrogen-doped rGO/SWCNT fiber as negative electrode, which demonstrates ultrahigh volumetric energy density, comparable to some thin-film lithium batteries, along with high power density, long cycle life, and good flexibility. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Solid Propellant Subscale Burning Rate Analysis Methods for US and Selected NATO Facilities

DTIC Science & Technology

2002-01-01

impossibility of the center of a particle lying closer than its radius from a solid boundary, * Due to surface tension and sedimentation (tends to level...34 effect (for bottom cast or bayonet cast grains) may consist of sedimentation of larger particles against the walls during casting flow, with the...February 2000. 91 Ratti A., "Metodi di Riduzione Dati Balistici per i Boosters a Propellente Solido di Ariane-4 e di Ariane-5," M.Sc. Thesis in Aerospace

An Investigation into the Comparative Costs of Additive Manufacture vs. Machine from Solid for Aero Engine Parts

DTIC Science & Technology

2006-05-01

welding power sources are not totally efficient at converting power drawn from the wall into heat energy used for the welding process . TIG sources are...Powder bed + Laser • Wire + Laser • Wire + Electron Beam • Wire + TIG Each system has its own unique attributes in terms of process variables...relative economics of producing a near net shape by Additive Manufacturing (AM) processes compared with traditional machine from solid processes (MFS

Starlight: A stationary inertial-confinement-fusion reactor with nonvaporizing walls

NASA Astrophysics Data System (ADS)

Pitts, John H.

1989-09-01

The Starlight concept for an inertial-confinement-fusion (ICF) reactor utilizes a softball-sized solid-lithium x ray and debris shield that surrounds each fuel pellet as it is injected into the reactor. The shield is sacrificial and vaporizes as it absorbs x ray and ion-debris energy emanating from the fusion reactions in the fuel pellets. However, the energy deposition time at the surface if the first wall is lengthened by four orders of magnitude (to greater than 100 microns) which allows the energy to be conducted into the wall fast enough to prevent vaporization. Starlight operates at 5 Hz with 300-MJ-yield fuel pellets. It features a stationary, nonvaporizing first wall that eliminates erosion and shock waves which can destroy the wall; also, it allows arbitrary fuel pellet illumination geometries so that efficient coupling of either laser or heavy ion beam driver energy to the fuel pellet can be achieved. When neutrons penetrate the shield, the wall experiences neutron damage that limits its lifetime. Hence, we must choose wall materials that have ab economic lifetime. We describe the general concept and a specific design for laser drivers using a 6-m-radius, 2 1/4 Cr 1 Mo steel first wall. We include heat transfer calculations used to establish the radius and structural analysis that shows stresses are within allowable limits. A wall lifetime of over six years is predicted.

Heavy metal contents of play dough, face and finger paint samples sold in turkish markets.

PubMed

Erbas, Zeliha; Karatepe, Aslihan; Soylak, Mustafa

2017-08-01

Lead, cadmium, nickel, manganese, cobalt and copper contents of some play dough, face and finger paint samples were determined by using a new solid phase extraction method which has been developed by using multi-walled carbon nanotube with patent blue (V) sodium salt to selectively separate and preconcentrate these metal ions. Flame atomic absorption spectrometry was used to determine the metal ions. Analytical parameters affecting the complex formation and solid phase extraction performance such as pH, the amount of ligand and volume of sample solution were investigated. The recoveries of the studied metal ions were not affected by the foreign ions. Analytes were recovered quantitatively at pH 5.5 and with a nitric acid of 2molL -1 as eluent. Analysis of a certified reference material was performed to validate the method before applying it to determine the metal ions in the real samples. Detection limits were found to be as Pb(II): 7.71μgL -1 , Cu(II): 1.43μgL -1 , Cd(III): 0.21μgL -1 , Mn(II): 0.47μgL -1 , Ni(II): 3.52μgL -1 and Co(II): 1.96μgL -1 . Copyright © 2017 Elsevier B.V. All rights reserved.

STS-28 Columbia, OV-102, Commander Shaw on middeck

NASA Technical Reports Server (NTRS)

1989-01-01

At open middeck stowage locker, Commander Brewster H. Shaw pauses to have his picture taken. Behind Shaw on port side wall are solid sorbent air sampler, a plastic storage bag filled with wheat crackers, and various food and beverage containers.

Numerical study of radiative heat transfer and effects of thermal boundary conditions on CLC fuel reactor

NASA Astrophysics Data System (ADS)

Ben-Mansour, R.; Li, H.; Habib, M. A.; Hossain, M. M.

2018-02-01

Global warming has become a worldwide concern due to its severe impacts and consequences on the climate system and ecosystem. As a promising technology proving good carbon capture ability with low-efficiency penalty, Chemical Looping Combustion technology has risen much interest. However, the radiative heat transfer was hardly studied, nor its effects were clearly declared. The present work provides a mathematical model for radiative heat transfer within fuel reactor of chemical looping combustion systems and conducts a numerical research on the effects of boundary conditions, solid particles reflectivity, particles size, and the operating temperature. The results indicate that radiative heat transfer has very limited impacts on the flow pattern. Meanwhile, the temperature variations in the static bed region (where solid particles are dense) brought by radiation are also insignificant. However, the effects of radiation on temperature profiles within free bed region (where solid particles are very sparse) are obvious, especially when convective-radiative (mixed) boundary condition is applied on fuel reactor walls. Smaller oxygen carrier particle size results in larger absorption & scattering coefficients. The consideration of radiative heat transfer within fuel reactor increases the temperature gradient within free bed region. On the other hand, the conversion performance of fuel is nearly not affected by radiation heat transfer within fuel reactor. However, the consideration of radiative heat transfer enhances the heat transfer between the gas phase and solid phase, especially when the operating temperature is low.

An experimental facility for the visual study of turbulent flows.

NASA Technical Reports Server (NTRS)

Brodkey, R. S.; Hershey, H. C.; Corino, E. R.

1971-01-01

An experimental technique which allows visual observations of the wall area in turbulent pipe flow is described in detail. It requires neither the introduction of any injection or measuring device into the flow nor the presence of a two-phase flow or of a non-Newtonian fluid. The technique involves suspending solid MgO particles of colloidal size in trichloroethylene and photographing their motions near the wall with a high speed movie camera moving with the flow. Trichloroethylene was chosen in order to eliminate the index of refraction problem in a curved wall. Evaluation of the technique including a discussion of limitations is included. Also the technique is compared with previous methods of visual observations of turbulent flow.

Influence of Dissipative Particle Dynamics parameters and wall models on planar micro-channel flows

NASA Astrophysics Data System (ADS)

Wang, Yuyi; She, Jiangwei; Zhou, Zhe-Wei; microflow Group Team

2017-11-01

Dissipative Particle Dynamics (DPD) is a very effective approach in simulating mesoscale hydrodynamics. The influence of solid boundaries and DPD parameters are typically very strong in DPD simulations. The present work studies a micro-channel Poisseuille flow. Taking the neutron scattering experiment and molecular dynamics simulation result as bench mark, the DPD results of density distribution and velocity profile are systematically studied. The influence of different levels of coarse-graining, the number densities of wall and fluid, conservative force coefficients, random and dissipative force coefficients, different wall model and reflective boundary conditions are discussed. Some mechanisms behind such influences are discussed and the artifacts in the simulation are identified with the bench mark. Chinese natural science foundation (A020405).

Seismic Performance of Composite Shear Walls Constructed Using Recycled Aggregate Concrete and Different Expandable Polystyrene Configurations.

PubMed

Liu, Wenchao; Cao, Wanlin; Zhang, Jianwei; Qiao, Qiyun; Ma, Heng

2016-03-02

The seismic performance of recycled aggregate concrete (RAC) composite shear walls with different expandable polystyrene (EPS) configurations was investigated. Six concrete shear walls were designed and tested under cyclic loading to evaluate the effect of fine RAC in designing earthquake-resistant structures. Three of the six specimens were used to construct mid-rise walls with a shear-span ratio of 1.5, and the other three specimens were used to construct low-rise walls with a shear-span ratio of 0.8. The mid-rise and low-rise shear walls consisted of an ordinary recycled concrete shear wall, a composite wall with fine aggregate concrete (FAC) protective layer (EPS modules as the external insulation layer), and a composite wall with sandwiched EPS modules as the insulation layer. Several parameters obtained from the experimental results were compared and analyzed, including the load-bearing capacity, stiffness, ductility, energy dissipation, and failure characteristics of the specimens. The calculation formula of load-bearing capacity was obtained by considering the effect of FAC on composite shear walls as the protective layer. The damage process of the specimen was simulated using the ABAQUS Software, and the results agreed quite well with those obtained from the experiments. The results show that the seismic resistance behavior of the EPS module composite for shear walls performed better than ordinary recycled concrete for shear walls. Shear walls with sandwiched EPS modules had a better seismic performance than those with EPS modules lying outside. Although the FAC protective layer slightly improved the seismic performance of the structure, it undoubtedly slowed down the speed of crack formation and the stiffness degradation of the walls.

Seismic Performance of Composite Shear Walls Constructed Using Recycled Aggregate Concrete and Different Expandable Polystyrene Configurations

PubMed Central

Liu, Wenchao; Cao, Wanlin; Zhang, Jianwei; Qiao, Qiyun; Ma, Heng

2016-01-01

The seismic performance of recycled aggregate concrete (RAC) composite shear walls with different expandable polystyrene (EPS) configurations was investigated. Six concrete shear walls were designed and tested under cyclic loading to evaluate the effect of fine RAC in designing earthquake-resistant structures. Three of the six specimens were used to construct mid-rise walls with a shear-span ratio of 1.5, and the other three specimens were used to construct low-rise walls with a shear-span ratio of 0.8. The mid-rise and low-rise shear walls consisted of an ordinary recycled concrete shear wall, a composite wall with fine aggregate concrete (FAC) protective layer (EPS modules as the external insulation layer), and a composite wall with sandwiched EPS modules as the insulation layer. Several parameters obtained from the experimental results were compared and analyzed, including the load-bearing capacity, stiffness, ductility, energy dissipation, and failure characteristics of the specimens. The calculation formula of load-bearing capacity was obtained by considering the effect of FAC on composite shear walls as the protective layer. The damage process of the specimen was simulated using the ABAQUS Software, and the results agreed quite well with those obtained from the experiments. The results show that the seismic resistance behavior of the EPS module composite for shear walls performed better than ordinary recycled concrete for shear walls. Shear walls with sandwiched EPS modules had a better seismic performance than those with EPS modules lying outside. Although the FAC protective layer slightly improved the seismic performance of the structure, it undoubtedly slowed down the speed of crack formation and the stiffness degradation of the walls. PMID:28773274

[Esophageal bronchogenic cyst: an uncommon cause of dysphagia in adults. Case report and literature review].

PubMed

Ceniceros-Cabrales, Ana P; Sánchez-Fernández, Patricio

2018-01-01

Bronchogenic cysts result from abnormal budding of the primitive tracheobronchial tube and are rare congenital cystic lesions. The location of the cyst depends on the embryological stage of abnormal budding. Although periesophageal bronchogenic cysts have been frequently reported, a completely intramural cyst is very rare. A 42-year-old female patient, a three-month course with retrosternal pain associated with food intake, accompanied by intermittent dysphagia to solids. Esophagogram, high resolution thoracic tomography and endoscopic ultrasound are performed, concluding a probable esophageal bronchogenic cyst. Resection is performed by video-assisted thoracic surgery, without complications. Patient presents with adequate evolution and complete remission of the symptomatology. Bronchogenic cysts of the esophageal wall are extremely uncommon lesions. Its surgical treatment is indicated to be symptomatic; video-assisted thoracoscopic surgery resection is of choice, with excellent long-term results and minimal morbidity. Copyright: © 2018 Permanyer.

Friction Stir Welding of ODS and RAFM Steels

DOE PAGES

Yu, Zhenzhen; Feng, Zhili; Hoelzer, David; ...

2015-09-14

Advanced structural materials such as oxide dispersion strengthened steels and reduced-activation ferritic/martensitic steels are desired in fusion reactors as primary candidate materials for first wall and blanket structures, due to their excellent radiation and high-temperature creep resistance. However, their poor fusion weldability has been the major technical challenge limiting practical applications. For this reason, solid-state friction stir welding (FSW) has been considered for such applications. In this paper, the effect of FSW parameters on joining similar and dissimilar advanced structural steels was investigated. Scanning electron microscopy and electron backscatter diffraction methods were used to reveal the effects of FSW onmore » grain size, micro-texture distribution, and phase stability. Hardness mapping was performed to evaluate mechanical properties. Finally, post weld heat treatment was also performed to tailor the microstructure in the welds in order to match the weld zone mechanical properties to the base material.« less

X-ray shadow imprint of hydrodynamic instabilities on the surface of inertial confinement fusion capsules by the fuel fill tube

DOE PAGES

MacPhee, A. G.; Casey, D. T.; Clark, D. S.; ...

2017-03-30

Measurements of hydrodynamic instability growth for a high-density carbon ablator for indirectly driven inertial confinement fusion implosions on the National Ignition Facility are reported. We observe significant unexpected features on the capsule surface created by shadows of the capsule fill tube, as illuminated by laser-irradiated x-ray spots on the hohlraum wall. These shadows increase the spatial size and shape of the fill tube perturbation in a way that can significantly degrade performance in layered implosions compared to previous expectations. The measurements were performed at a convergence ratio of ~2 using in-flight x-ray radiography. The initial seed due to shadow imprintmore » is estimated to be equivalent to ~50–100 nm of solid ablator material. As a result, this discovery has prompted the need for a mitigation strategy for future inertial confinement fusion designs as proposed here.« less

X-ray shadow imprint of hydrodynamic instabilities on the surface of inertial confinement fusion capsules by the fuel fill tube

DOE Office of Scientific and Technical Information (OSTI.GOV)

MacPhee, A. G.; Casey, D. T.; Clark, D. S.

Measurements of hydrodynamic instability growth for a high-density carbon ablator for indirectly driven inertial confinement fusion implosions on the National Ignition Facility are reported. We observe significant unexpected features on the capsule surface created by shadows of the capsule fill tube, as illuminated by laser-irradiated x-ray spots on the hohlraum wall. These shadows increase the spatial size and shape of the fill tube perturbation in a way that can significantly degrade performance in layered implosions compared to previous expectations. The measurements were performed at a convergence ratio of ~2 using in-flight x-ray radiography. The initial seed due to shadow imprintmore » is estimated to be equivalent to ~50–100 nm of solid ablator material. As a result, this discovery has prompted the need for a mitigation strategy for future inertial confinement fusion designs as proposed here.« less

Noniterative implicit method for tracking particles in mixed Lagrangian-Eulerian formulations

NASA Technical Reports Server (NTRS)

Shih, T. I.-P.; Dasgupta, A.

1993-01-01

The existing implicit methods for the current initial value problems (IVPs) concerning particle-laden flows are complicated and iterative in nature. This paper presents a noniterative implicit method which can be used with pressure-based as well as with density-based algorithms. The method is illustrated by analyzing a dilute dispersion of noninteracting solid particles in an isothermal flow in a passage bounded by one straight wall and one wavy wall, in which all particles are spherical and have a finite velociy relative to the continuum phase at the inflow boundary.

Application of NASTRAN in nonlinear analysis of a cartridge case neck separation malfunction

NASA Technical Reports Server (NTRS)

Yang, J. C. S.; Frederick, D. L.

1975-01-01

The problem of case neck separation malfunction in the field of ammunition structural analysis is investigated. The axi-symmetric solid of revolution RING element was utilized in the manual piecewise linear analysis to obtain the expansion of the wall of the cartridge case and barrel chamber by the pressure of propellant gases and the stresses in the structure. The analysis included the varying material properties along the wall of the case and the chamber. Additional instructions were provided to change the element material ID's without recomputing the entire stiffness matrix.

Surprising synthesis of nanodiamond from single-walled carbon nanotubes by the spark plasma sintering process

NASA Astrophysics Data System (ADS)

Mirzaei, Ali; Ham, Heon; Na, Han Gil; Kwon, Yong Jung; Kang, Sung Yong; Choi, Myung Sik; Bang, Jae Hoon; Park, No-Hyung; Kang, Inpil; Kim, Hyoun Woo

2016-10-01

Nanodiamond (ND) was successfully synthesized using single-walled carbon nanotubes (SWCNTs) as a pure solid carbon source by means of a spark plasma sintering process. Raman spectra and X-ray diffraction patterns revealed the generation of the cubic diamond phase by means of the SPS process. Lattice-resolved TEM images confirmed that diamond nanoparticles with a diameter of about ˜10 nm existed in the products. The NDs were generated mainly through the gas-phase nucleation of carbon atoms evaporated from the SWCNTs. [Figure not available: see fulltext.

Long ligands reinforce biological adhesion under shear flow

NASA Astrophysics Data System (ADS)

Belyaev, Aleksey V.

2018-04-01

In this work, computer modeling has been used to show that longer ligands allow biological cells (e.g., blood platelets) to withstand stronger flows after their adhesion to solid walls. A mechanistic model of polymer-mediated ligand-receptor adhesion between a microparticle (cell) and a flat wall has been developed. The theoretical threshold between adherent and non-adherent regimes has been derived analytically and confirmed by simulations. These results lead to a deeper understanding of numerous biophysical processes, e.g., arterial thrombosis, and to the design of new biomimetic colloid-polymer systems.

Investigating impact of waste reuse on the sustainability of municipal solid waste (MSW) incineration industry using emergy approach: A case study from Sichuan province, China.

PubMed

Wang, Yanqing; Zhang, Xiaohong; Liao, Wenjie; Wu, Jun; Yang, Xiangdong; Shui, Wei; Deng, Shihuai; Zhang, Yanzong; Lin, Lili; Xiao, Yinlong; Yu, Xiaoyu; Peng, Hong

2018-04-25

China has become the largest generator of municipal solid waste (MSW) in the world with its rapid urbanization, population growth and raising living standard. Among diverse solid waste disposal technologies, MSW incineration has been becoming an attractive choice. In terms of systematic point, an integrated MSW incineration system should include an incineration subsystem and a bottom ash (BA) disposal subsystem. This paper employed an extend emergy assessment method with several improved indicators, which considers the emissions' impact, to evaluate the comprehensive performances of an integrated MSW incineration system. One existing incineration plant in Yibin City, Sichuan Province, China, as a case study, is evaluated using the proposed method. Three alternative scenarios (scenario A: the incineration subsystem + the BA landfill subsystem; scenario B: the incineration subsystem + the concrete paving brick production subsystem using BA as raw material; scenario C: the incineration subsystem + the non-burnt wall brick production subsystem using BA as raw material) were compared. The study results reveal that the ratio of positive output is 1.225, 2.861 and 1.230, the improved environmental loading ratio is 2.715, 2.742 and 1.533, and the improved environmental sustainability index is 0.451, 1.043 and 0.803 for scenario A, B and C respectively. Therefore, reuse of BA can enhance the sustainability level of this integrated system greatly. Comparatively, scenario B has the best comprehensive performance among the three scenarios. Finally, some targeted recommendations are put forward for decision-making. Copyright © 2018. Published by Elsevier Ltd.

Freezing Temperatures, Ice Nanotubes Structures, and Proton Ordering of TIP4P/ICE Water inside Single Wall Carbon Nanotubes.

PubMed

Pugliese, P; Conde, M M; Rovere, M; Gallo, P

2017-11-16

A very recent experimental paper importantly and unexpectedly showed that water in carbon nanotubes is already in the solid ordered phase at the temperature where bulk water boils. The water models used so far in literature for molecular dynamics simulations in carbon nanotubes show freezing temperatures lower than the experiments. We present here results from molecular dynamics simulations of water inside single walled carbon nanotubes using an extremely realistic model for both liquid and icy water, the TIP4P/ICE. The water behavior inside nanotubes of different diameters has been studied upon cooling along the isobars at ambient pressure starting from temperatures where water is in a liquid state. We studied the liquid/solid transition, and we observed freezing temperatures higher than in bulk water and that depend on the diameter of the nanotube. The maximum freezing temperature found is 390 K, which is in remarkable agreement with the recent experimental measurements. We have also analyzed the ice structure called "ice nanotube" that water forms inside the single walled carbon nanotubes when it freezes. The ice forms observed are in agreement with previous results obtained with different water models. A novel finding, a partial proton ordering, is evidenced in our ice nanotubes at finite temperature.

Wall effects in Stokes experiment with a liquid foam

NASA Astrophysics Data System (ADS)

Gao, Haijing; Subramani, Hariprasad; Harris, Michael; Basaran, Osman

2011-11-01

Liquid foams are widely used in numerous applications ranging from the oil and gas industry to beauty, healthcare, and household products industries. A fundamental understanding of the relationships between the properties of liquid foams and their flow responses is, however, still in its infancy compared to that involving the fluid dynamics of simple fluids. In this talk, the flow of a dry liquid foam around a spherical bead, i.e. the Stokes problem for liquid foams, is studied experimentally. In contrast to previous work (cf. Cantat 2006), the focus of the present research is to probe the effect of a solid wall that is located a few bubble radii from the bead. The new experimental results show that the elastic modulus of dry liquid foams is directly proportional to the surface tension of the foaming agents and inversely proportional to the average bubble size in the foams, in agreement with previous theoretical and experimental studies. The experiments further show that the close proximity of the solid wall causes profound structural changes to the gas bubbles as the foam flows past the bead. A good understanding of these structural changes and how they can affect the elastic modulus of foams can be indispensable in formulating improved models for accurately describing the dynamical response of foams within the realm of continuum mechanics.

Selective Individual Primary Cell Capture Using Locally Bio-Functionalized Micropores

PubMed Central

Liu, Jie; Bombera, Radoslaw; Leroy, Loïc; Roupioz, Yoann; Baganizi, Dieudonné R.; Marche, Patrice N.; Haguet, Vincent; Mailley, Pascal; Livache, Thierry

2013-01-01

Background Solid-state micropores have been widely employed for 6 decades to recognize and size flowing unlabeled cells. However, the resistive-pulse technique presents limitations when the cells to be differentiated have overlapping dimension ranges such as B and T lymphocytes. An alternative approach would be to specifically capture cells by solid-state micropores. Here, the inner wall of 15-µm pores made in 10 µm-thick silicon membranes was covered with antibodies specific to cell surface proteins of B or T lymphocytes. The selective trapping of individual unlabeled cells in a bio-functionalized micropore makes them recognizable just using optical microscopy. Methodology/Principal Findings We locally deposited oligodeoxynucleotide (ODN) and ODN-conjugated antibody probes on the inner wall of the micropores by forming thin films of polypyrrole-ODN copolymers using contactless electro-functionalization. The trapping capabilities of the bio-functionalized micropores were validated using optical microscopy and the resistive-pulse technique by selectively capturing polystyrene microbeads coated with complementary ODN. B or T lymphocytes from a mouse splenocyte suspension were specifically immobilized on micropore walls functionalized with complementary ODN-conjugated antibodies targeting cell surface proteins. Conclusions/Significance The results showed that locally bio-functionalized micropores can isolate target cells from a suspension during their translocation throughout the pore, including among cells of similar dimensions in complex mixtures. PMID:23469221

Liquid spray experiments

NASA Astrophysics Data System (ADS)

Lapham, Gary; McHugh, John

When waves on the ocean surface interact with a solid object, the result is often a complex pattern of spray. The solid object may be a coastal barrier such as a breakwater, or a ship or drilling rig. Another spray-related case is the presence of large industrial tanks of liquid, and often dangerous liquids, that exist around the world. Tens of thousands of such tanks are rapidly becoming obsolete. Recent experience has shown that when such tanks burst, the resulting spray may shoot several hundreds of meters from the tank. These tanks often have a wall or dam (barrier) surrounding them in an attempt to contain any leakage, catastrophic or otherwise. When the tank bursts it is akin to the dam-break problem. A wall of water rushes forth and impinges on the barrier creating spray. Previous experiments (McHugh and Watt, 1998) considered the related configuration of a solitary wave impinging on a vertical wall. The present experiments more closely model the bursting tank case, and treat the effect of the distance between the tank and barrier. Results show that there is a sweet spot where height and horizontal distance of spray droplets are maximized. This ideal distance between tank and barrier is constant when scaled by the initial tank depth.

Advances in compact manufacturing for shape and performance controllability of large-scale components-a review

NASA Astrophysics Data System (ADS)

Qin, Fangcheng; Li, Yongtang; Qi, Huiping; Ju, Li

2017-01-01

Research on compact manufacturing technology for shape and performance controllability of metallic components can realize the simplification and high-reliability of manufacturing process on the premise of satisfying the requirement of macro/micro-structure. It is not only the key paths in improving performance, saving material and energy, and green manufacturing of components used in major equipments, but also the challenging subjects in frontiers of advanced plastic forming. To provide a novel horizon for the manufacturing in the critical components is significant. Focused on the high-performance large-scale components such as bearing rings, flanges, railway wheels, thick-walled pipes, etc, the conventional processes and their developing situations are summarized. The existing problems including multi-pass heating, wasting material and energy, high cost and high-emission are discussed, and the present study unable to meet the manufacturing in high-quality components is also pointed out. Thus, the new techniques related to casting-rolling compound precise forming of rings, compact manufacturing for duplex-metal composite rings, compact manufacturing for railway wheels, and casting-extruding continuous forming of thick-walled pipes are introduced in detail, respectively. The corresponding research contents, such as casting ring blank, hot ring rolling, near solid-state pressure forming, hot extruding, are elaborated. Some findings in through-thickness microstructure evolution and mechanical properties are also presented. The components produced by the new techniques are mainly characterized by fine and homogeneous grains. Moreover, the possible directions for further development of those techniques are suggested. Finally, the key scientific problems are first proposed. All of these results and conclusions have reference value and guiding significance for the integrated control of shape and performance in advanced compact manufacturing.

Final Technical Report: Using Solid Particles as Heat Transfer Fluid for use in Concentrating Solar Power (CSP) Plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lattanzi, Aaron; Hrenya, Christine

In today’s industrial economy, energy consumption has never been higher. Over the last 15 years the US alone has consumed an average of nearly 100 quadrillion BTUs per year [21]. A need for clean and renewable energy sources has become quite apparent. The SunShot Initiative is an ambitious effort taken on by the United States Department of Energy that targets the development of solar energy that is cost-competitive with other methods for generating electricity. Specifically, this work is concerned with the development of concentrating solar power plants (CSPs) with granular media as the heat transfer fluid (HTF) from the solarmore » receiver. Unfortunately, the prediction of heat transfer in multiphase flows is not well understood. For this reason, our aim is to fundamentally advance the understanding of multiphase heat transfer, particularly in gas-solid flows, while providing quantitative input for the design of a near black body receiver (NBB) that uses solid grains (like sand) as the HTF. Over the course of this three-year project, a wide variety of contributions have been made to advance the state-of-the art description for non-radiative heat transfer in dense, gas-solid systems. Comparisons between a state-of-the-art continuum heat transfer model and discrete element method (DEM) simulations have been drawn. The results of these comparisons brought to light the limitations of the continuum model due to inherent assumptions in its derivation. A new continuum model was then developed for heat transfer at a solid boundary by rigorously accounting for the most dominant non-radiative heat transfer mechanism (particle-fluid-wall conduction). The new model is shown to be in excellent agreement with DEM data and captures the dependence of heat transfer on particle size, a dependency that previous continuum models were not capable of. DEM and the new continuum model were then employed to model heat transfer in a variety of receiver geometries. The results provided crucial feedback on the efficiency and feasibility of various designs. Namely, a prototype design consisting of an array of heated hexagonal tubes was later supplanted by a vertical conduit with internal baffles. Due to low solids heat transfer on the bottom faces of the hexagonal tubes in the prototype, the predicted wall temperature gradients exceeded the design limitations. By contrast, the vertical conduit can be constructed to continually force particle-wall contacts, and thus, result in more desirable solids heat transfer and wall temperature gradients. Finally, a new heat flux boundary condition was developed for DEM simulations to assess the aforementioned wall temperature gradients. The new boundary condition advances current state-of-the-art techniques by allowing the heat fluxes to each phase to vary with space and time while the total flux remains constant. Simulations with the new boundary condition show that the total boundary heat flux is in good agreement with the imposed total boundary heat flux. While the methods we have utilized here are primarily numerical and fundamental by nature, they offer some key advantages of: (i) being robust and valid over a large range of conditions, (ii) able to quickly explore large parameter spaces, and (iii) aid in the construction of experiments. We have ultimately leveraged our computational capabilities to provide feedback on the design of a CSP which possesses great potential to become a cost effective source of clean and renewable electricity. Overall, ensuring that future energy demands are met in a responsible and efficient manner has far reaching impacts that span both ecologic and economic concerns. Regarding logistics, the project was successfully re-negotiated after the go/no-decisions of Years 1 and 2. All milestones were successfully completed.« less

Microsandwich cellular solids

NASA Technical Reports Server (NTRS)

Balakrishna Bhat, T.; O'Donnell, Tim; Wang, Taylor G.

1989-01-01

This article introduces a new concept of microsandwiching in which the cell wall itself is a sandwich structure and is substantially stiffer. Some experimental results are presented to show the efficacy of this approach. A method for optimizing the design of honeycomb microsandwich is also briefly outlined.

The Effect of Aortic Compliance on Left Ventricular Power Requirement

NASA Astrophysics Data System (ADS)

Pahlevan, Niema; Gharib, Morteza

2009-11-01

Aortic compliance depends on both geometry and mechanical properties of the aorta. Reduction in arterial compliance has been associated with aging, smoking, and multiple cardiovascular diseases. Increased stiffness of the aorta affects the wave dynamics in the aorta by increasing both pulse pressure amplitude and wave speed. We hypothesized that decreased aortic compliance leads to an increased left ventricular power requirement for a fixed cardiac output due to altered pulse pressure and pulse wave velocity. We used a computational approach using the finite element method for solid and fluid domains coupled to each other by using the direct coupling method. A nonlinear material model was used for the solid wall. The fluid flow model was considered to be Newtonian, incompressible, and laminar. The simulation was performed for a heart rate of 75 beats per minute for six different compliances while keeping the cardiac output and the peripheral resistance constant. The results show a trend towards increased left ventricular energy expenditure per cycle with decreased compliance. The relevance of these findings to clinical observations will be discussed.

Preparation of a novel hyperbranched carbosilane-silica hybrid coating for trace amount detection by solid phase microextraction/gas chromatography.

PubMed

Chen, Guowen; Li, Wenjie; Zhang, Chen; Zhou, Chuanjian; Feng, Shengyu

2012-09-21

Phenyl-ended hyperbranched carbosilane (HBC) is synthesized and immobilized onto the inner wall of a fused silica capillary column using a sol-gel process. The hybrid coating layer formed is used as a stationary phase for gas chromatography (GC) and as an adsorption medium for solid phase microextraction (SPME). Trifluoroacetic acid, as a catalyst in this process, helps produce a homogeneous hybrid coating layer. This result is beneficial for better column chromatographic performances, such as high efficiency and high resolution. Extraction tests using the novel hybrid layer show an extraordinarily large adsorption capacity and specific adsorption behavior for aromatic compounds. A 1 ppm trace level detectability is obtained with the SPME/GC work model when both of the stationary phase and adsorption layer bear a hyperbranched structure. A large amount of phenyl groups and a low viscosity of hyperbranched polymers contribute to these valuable properties, which are important to environment and safety control, wherein detection sensitivity and special adsorption behavior are usually required. Copyright © 2012 Elsevier B.V. All rights reserved.

Sputtered silver films to improve chromium carbide based solid lubricant coatings for use to 900 C

NASA Technical Reports Server (NTRS)

Dellacorte, Christopher; Sliney, Harold E.; Deadmore, Daniel L.

1988-01-01

Thin silver films, 250 to 3500 A thick, were sputtered onto PS200, a plasma sprayed, chromium carbide based solid lubricant coating, to reduce run-in wear and improve tribological properties. The coating contains bonded chromium carbide as the wear resistant base stock with silver and barium fluoride/calcium fluoride eutectic added as low and high temperature lubricants, respectively. Potential applications for the PS200 coating are cylinder wall/piston ring lubrication for Stirling engines and foil bearing journal lubrication. In this preliminary program, the silver film overlay thickness was optimized based on tests using a pin-on-disk tribometer. The friction and wear studies were performed in a helium atmosphere at temperatures from 25 to 760 C with a sliding velocity of 2.7 m/s under a 4.9 N load. Films between 1000 and 1500 A provide the best lubrication of the counterface material. The films enrich the sliding surface with lubricant and reduce the initial abrasiveness of the as ground, plasma-sprayed coating surface, thus reducing wear.

Sputtered silver films to improve chromium carbide based solid lubricant coatings for use to 900 C

NASA Technical Reports Server (NTRS)

Dellacorte, Christopher; Sliney, Harold E.; Deadmore, Daniel L.

1988-01-01

Thin silver films, 250 to 3500 A thick, were sputtered onto PS200, a plasma sprayed, chromium carbide based solid lubricant coating, to reduce run-in wear and improve tribological properties. The coating contains bonded chromium carbide as the wear resistant base stock with silver and barium fluoride/calcium fluoride eutectic added as low and high temperature lubricants respectively. Potential applications for the PS200 coating are cylinder wall/piston ring lubrication for Stirling engines and foil bearing journal lubrication. In this preliminary program, the silver film overlay thickness was optimized based on tests using a pin-on-disk tribometer. The friction and wear studies were performed in a helium atmosphere at temperatures from 25 to 760 C with a sliding velocity of 2.7 m/s under a 4.9 N load. Films between 1000 and 1500 A provide the best lubrication of the counterface material. The films enrich the sliding surface with lubricant and reduce the initial abrasiveness of the as ground, plasma-sprayed coating surface, thus reducing wear.

Polymeric ionic liquid bucky gels as sorbent coatings for solid-phase microextraction.

PubMed

Zhang, Cheng; Anderson, Jared L

2014-05-30

Novel cross-linked polymeric ionic liquid (PIL) bucky gels were formed by free-radical polymerization of polymerizable ionic liquids gelled with multi-walled carbon nanotubes (MWCNT) and used as sorbent coatings for solid-phase microextraction (SPME). The combination of PIL with MWCNTs significantly enhanced the π-π interaction between the sorbent coatings and the aromatic analytes. Compared to the neat PIL-based sorbent coating, the PIL bucky gel sorbent coatings demonstrated higher extraction efficiency for the extraction of polycyclic aromatic hydrocarbons (PAHs). A partitioning extraction mechanism was observed for the PIL/MWCNT-based sorbent coatings indicating that the addition of MWCNTs did not seem to affect the extraction mechanism of the sorbent coating. The analyte-to-coating partition coefficients (logKfs) were estimated and the limits of detection (LOD) for selected PIL bucky gel sorbent coating were determined to be in the range of 1-2.5 ng L(-1). Recovery studies were also performed for PAHs in river and tap water to validate the applicability of the developed method. Copyright © 2014 Elsevier B.V. All rights reserved.

Study on seismic performance of BFRP geogrid reinforced Tibetan rubble wall

NASA Astrophysics Data System (ADS)

Yang, Dan; Jia, Bin; Huang, Hui; Deng, Chuangli

2018-03-01

For the study of BFRP geogrid influence on Tibetan rubble wall seismic performance, in this paper, on the premise of not change the way of traditional masonry, laying and not join geogrid respectively on the the rubble wall, and carries on the cyclic loading experiment on them. The damage characteristics, crack width and seismic performance of the rubble walls with BFRP geogrid are studied. The experimental results show that the deformation of the rubble wall is mainly the shear deformation under the action of horizontal force, and the bearing capacity and energy dissipation capacity of the wall can be improved significantly after joining the geogrid.

A model for cell wall dissolution in mating yeast cells: polarized secretion and restricted diffusion of cell wall remodeling enzymes induces local dissolution.

PubMed

Huberman, Lori B; Murray, Andrew W

2014-01-01

Mating of the budding yeast, Saccharomyces cerevisiae, occurs when two haploid cells of opposite mating types signal using reciprocal pheromones and receptors, grow towards each other, and fuse to form a single diploid cell. To fuse, both cells dissolve their cell walls at the point of contact. This event must be carefully controlled because the osmotic pressure differential between the cytoplasm and extracellular environment causes cells with unprotected plasma membranes to lyse. If the cell wall-degrading enzymes diffuse through the cell wall, their concentration would rise when two cells touched each other, such as when two pheromone-stimulated cells adhere to each other via mating agglutinins. At the surfaces that touch, the enzymes must diffuse laterally through the wall before they can escape into the medium, increasing the time the enzymes spend in the cell wall, and thus raising their concentration at the point of attachment and restricting cell wall dissolution to points where cells touch each other. We tested this hypothesis by studying pheromone treated cells confined between two solid, impermeable surfaces. This confinement increases the frequency of pheromone-induced cell death, and this effect is diminished by reducing the osmotic pressure difference across the cell wall or by deleting putative cell wall glucanases and other genes necessary for efficient cell wall fusion. Our results support the model that pheromone-induced cell death is the result of a contact-driven increase in the local concentration of cell wall remodeling enzymes and suggest that this process plays an important role in regulating cell wall dissolution and fusion in mating cells.

A Model for Cell Wall Dissolution in Mating Yeast Cells: Polarized Secretion and Restricted Diffusion of Cell Wall Remodeling Enzymes Induces Local Dissolution

PubMed Central

Huberman, Lori B.; Murray, Andrew W.

2014-01-01

Mating of the budding yeast, Saccharomyces cerevisiae, occurs when two haploid cells of opposite mating types signal using reciprocal pheromones and receptors, grow towards each other, and fuse to form a single diploid cell. To fuse, both cells dissolve their cell walls at the point of contact. This event must be carefully controlled because the osmotic pressure differential between the cytoplasm and extracellular environment causes cells with unprotected plasma membranes to lyse. If the cell wall-degrading enzymes diffuse through the cell wall, their concentration would rise when two cells touched each other, such as when two pheromone-stimulated cells adhere to each other via mating agglutinins. At the surfaces that touch, the enzymes must diffuse laterally through the wall before they can escape into the medium, increasing the time the enzymes spend in the cell wall, and thus raising their concentration at the point of attachment and restricting cell wall dissolution to points where cells touch each other. We tested this hypothesis by studying pheromone treated cells confined between two solid, impermeable surfaces. This confinement increases the frequency of pheromone-induced cell death, and this effect is diminished by reducing the osmotic pressure difference across the cell wall or by deleting putative cell wall glucanases and other genes necessary for efficient cell wall fusion. Our results support the model that pheromone-induced cell death is the result of a contact-driven increase in the local concentration of cell wall remodeling enzymes and suggest that this process plays an important role in regulating cell wall dissolution and fusion in mating cells. PMID:25329559

The Influence of Phase Change Materials on the Properties of Self-Compacting Concrete

PubMed Central

Fenollera, María; Míguez, José Luis; Goicoechea, Itziar; Lorenzo, Jaime; Ángel Álvarez, Miguel

2013-01-01

The aim of this paper is to research new thermally-efficient concrete walls, analyzing the mechanical behavior of a self-compacting concrete to manufacture an uncoated solid structural panel, with the incorporation of a micro-encapsulated phase change material as additive. Different dosages are tested and mechanical properties of the product obtained from the molding of concrete specimens are evaluated, testing mechanical compressive strength, slump flow, and density. The results reveal the optimum percentage of additive in the mixture that enables compliance with the technical specifications required by the product to be manufactured. A test is also performed for measuring the thermal conductivity for the optimal sample obtained and it evidences the reduction thereof. PMID:28811450

Solid-state NMR Reveals the Carbon-based Molecular Architecture of Cryptococcus neoformans Fungal Eumelanins in the Cell Wall*

PubMed Central

Chatterjee, Subhasish; Prados-Rosales, Rafael; Itin, Boris; Casadevall, Arturo; Stark, Ruth E.

2015-01-01

Melanin pigments protect against both ionizing radiation and free radicals and have potential soil remediation capabilities. Eumelanins produced by pathogenic Cryptococcus neoformans fungi are virulence factors that render the fungal cells resistant to host defenses and certain antifungal drugs. Because of their insoluble and amorphous characteristics, neither the pigment bonding framework nor the cellular interactions underlying melanization of C. neoformans have yielded to comprehensive molecular-scale investigation. This study used the C. neoformans requirement of exogenous obligatory catecholamine precursors for melanization to produce isotopically enriched pigment “ghosts” and applied 2D 13C-13C correlation solid-state NMR to reveal the carbon-based architecture of intact natural eumelanin assemblies in fungal cells. We demonstrated that the aliphatic moieties of solid C. neoformans melanin ghosts include cell-wall components derived from polysaccharides and/or chitin that are associated proximally with lipid membrane constituents. Prior to development of the mature aromatic fungal pigment, these aliphatic moieties form a chemically resistant framework that could serve as the scaffold for melanin synthesis. The indole-based core aromatic moieties show interconnections that are consistent with proposed melanin structures consisting of stacked planar assemblies, which are associated spatially with the aliphatic scaffold. The pyrrole aromatic carbons of the pigments bind covalently to the aliphatic framework via glycoside or glyceride functional groups. These findings establish that the structure of the pigment assembly changes with time and provide the first biophysical information on the mechanism by which melanin is assembled in the fungal cell wall, offering vital insights that can advance the design of bioinspired conductive nanomaterials and novel therapeutics. PMID:25825492

Solid-state NMR Reveals the Carbon-based Molecular Architecture of Cryptococcus neoformans Fungal Eumelanins in the Cell Wall.

PubMed

Chatterjee, Subhasish; Prados-Rosales, Rafael; Itin, Boris; Casadevall, Arturo; Stark, Ruth E

2015-05-29

Melanin pigments protect against both ionizing radiation and free radicals and have potential soil remediation capabilities. Eumelanins produced by pathogenic Cryptococcus neoformans fungi are virulence factors that render the fungal cells resistant to host defenses and certain antifungal drugs. Because of their insoluble and amorphous characteristics, neither the pigment bonding framework nor the cellular interactions underlying melanization of C. neoformans have yielded to comprehensive molecular-scale investigation. This study used the C. neoformans requirement of exogenous obligatory catecholamine precursors for melanization to produce isotopically enriched pigment "ghosts" and applied 2D (13)C-(13)C correlation solid-state NMR to reveal the carbon-based architecture of intact natural eumelanin assemblies in fungal cells. We demonstrated that the aliphatic moieties of solid C. neoformans melanin ghosts include cell-wall components derived from polysaccharides and/or chitin that are associated proximally with lipid membrane constituents. Prior to development of the mature aromatic fungal pigment, these aliphatic moieties form a chemically resistant framework that could serve as the scaffold for melanin synthesis. The indole-based core aromatic moieties show interconnections that are consistent with proposed melanin structures consisting of stacked planar assemblies, which are associated spatially with the aliphatic scaffold. The pyrrole aromatic carbons of the pigments bind covalently to the aliphatic framework via glycoside or glyceride functional groups. These findings establish that the structure of the pigment assembly changes with time and provide the first biophysical information on the mechanism by which melanin is assembled in the fungal cell wall, offering vital insights that can advance the design of bioinspired conductive nanomaterials and novel therapeutics. © 2015 by The American Society for Biochemistry and Molecular Biology, Inc.

Shape of Strained Solid He-4 at Low Temperatures

NASA Technical Reports Server (NTRS)

Kojima, Harry

2004-01-01

(1) Interferometer apparatus for measuring surface profile (2) For small strains, the expected linear decrease in height is not seen. (3) For large strains, undulation and irreversible deformations begin to set in, but we cannot yet make clear connection with stress-driven instability theory. Torii and Balibar have observed appearances of deformations beyond threshold stress on He-4 solid surface. The difference of our results from theory real? We are not ready to claim in affirmative. To be able to answer: 1) improve crystal growth techniques; (orientation, annealing, better pressure control) 2) improve homogeneity of stress; (better alignment with vertical, better understanding of interaction between solid He-4 and walls) 4) improve optics.

A film-based wall shear stress sensor for wall-bounded turbulent flows

NASA Astrophysics Data System (ADS)

Amili, Omid; Soria, Julio

2011-07-01

In wall-bounded turbulent flows, determination of wall shear stress is an important task. The main objective of the present work is to develop a sensor which is capable of measuring surface shear stress over an extended region applicable to wall-bounded turbulent flows. This sensor, as a direct method for measuring wall shear stress, consists of mounting a thin flexible film on the solid surface. The sensor is made of a homogeneous, isotropic, and incompressible material. The geometry and mechanical properties of the film are measured, and particles with the nominal size of 11 μm in diameter are embedded on the film's surface to act as markers. An optical technique is used to measure the film deformation caused by the flow. The film has typically deflection of less than 2% of the material thickness under maximum loading. The sensor sensitivity can be adjusted by changing the thickness of the layer or the shear modulus of the film's material. The paper reports the sensor fabrication, static and dynamic calibration procedure, and its application to a fully developed turbulent channel flow at Reynolds numbers in the range of 90,000-130,000 based on the bulk velocity and channel full height. The results are compared to alternative wall shear stress measurement methods.

A numerical study of the effects of wind tunnel wall proximity on an airfoil model

NASA Technical Reports Server (NTRS)

Potsdam, Mark; Roberts, Leonard

1990-01-01

A procedure was developed for modeling wind tunnel flows using computational fluid dynamics. Using this method, a numerical study was undertaken to explore the effects of solid wind tunnel wall proximity and Reynolds number on a two-dimensional airfoil model at low speed. Wind tunnel walls are located at varying wind tunnel height to airfoil chord ratios and the results are compared with freestream flow in the absence of wind tunnel walls. Discrepancies between the constrained and unconstrained flows can be attributed to the presence of the walls. Results are for a Mach Number of 0.25 at angles of attack through stall. A typical wind tunnel Reynolds number of 1,200,000 and full-scale flight Reynolds number of 6,000,000 were investigated. At this low Mach number, wind tunnel wall corrections to Mach number and angle of attack are supported. Reynolds number effects are seen to be a consideration in wind tunnel testing and wall interference correction methods. An unstructured grid Navier-Stokes code is used with a Baldwin-Lomax turbulence model. The numerical method is described since unstructured flow solvers present several difficulties and fundamental differences from structured grid codes, especially in the area of turbulence modeling and grid generation.

A Theoretical Evaluation of Secondary Atomization Effects on Engine Performance for Aluminum Gel Propellants

NASA Technical Reports Server (NTRS)

Mueller, D. C.; Turns, S. R.

1994-01-01

A one-dimensional model of a gel-fueled rocket combustion chamber has been developed. This model includes the processes of liquid hydrocarbon burnout, secondary atomization. aluminum ignition, and aluminum combustion. Also included is a model of radiative heat transfer from the solid combustion products to the chamber walls. Calculations indicate that only modest secondary atomization is required to significantly reduce propellant burnout distances, aluminum oxide residual size and radiation heat wall losses. Radiation losses equal to approximately 2-13 percent of the energy released during combustion were estimated. A two-dimensional, two-phase nozzle code was employed to estimate radiation and nozzle two-phase flow effects on overall engine performance. Radiation losses yielded a 1 percent decrease in engine I(sub sp). Results also indicate that secondary atomization may have less effect on two-phase losses than it does on propellant burnout distance and no effect if oxide particle coagulation and shear induced droplet breakup govern oxide particle size. Engine I(sub sp) was found to decrease from 337.4 to 293.7 seconds as gel aluminum mass loading was varied from 0-70 wt percent. Engine I(sub sp) efficiencies, accounting for radiation and two-phase flow effects, on the order of 0.946 were calculated for a 60 wt percent gel, assuming a fragmentation ratio of 5.

Light-Frame Wall Systems: Performance and Predictability.

Treesearch

David S. Gromala

1983-01-01

This paper compares results of all wall tests with analytical predictions of performance.Conventional wood-stud walls of one configuration failed at bending loads that were 4 to 6 times design load.The computer model overpredicted wall strength by and average of 10 percent and deflection by an average of 6 percent.

Single-Walled Carbon Nanotubes: Mimics of Biological Ion Channels.

PubMed

Amiri, Hasti; Shepard, Kenneth L; Nuckolls, Colin; Hernández Sánchez, Raúl

2017-02-08

Here we report on the ion conductance through individual, small diameter single-walled carbon nanotubes. We find that they are mimics of ion channels found in natural systems. We explore the factors governing the ion selectivity and permeation through single-walled carbon nanotubes by considering an electrostatic mechanism built around a simplified version of the Gouy-Chapman theory. We find that the single-walled carbon nanotubes preferentially transported cations and that the cation permeability is size-dependent. The ionic conductance increases as the absolute hydration enthalpy decreases for monovalent cations with similar solid-state radii, hydrated radii, and bulk mobility. Charge screening experiments using either the addition of cationic or anionic polymers, divalent metal cations, or changes in pH reveal the enormous impact of the negatively charged carboxylates at the entrance of the single-walled carbon nanotubes. These observations were modeled in the low-to-medium concentration range (0.1-2.0 M) by an electrostatic mechanism that mimics the behavior observed in many biological ion channel-forming proteins. Moreover, multi-ion conduction in the high concentration range (>2.0 M) further reinforces the similarity between single-walled carbon nanotubes and protein ion channels.

A supercritical airfoil experiment

NASA Technical Reports Server (NTRS)

Mateer, G. G.; Seegmiller, H. L.; Hand, L. A.; Szodruck, J.

1994-01-01

The purpose of this investigation is to provide a comprehensive data base for the validation of numerical simulations. The objective of the present paper is to provide a tabulation of the experimental data. The data were obtained in the two-dimensional, transonic flowfield surrounding a supercritical airfoil. A variety of flows were studied in which the boundary layer at the trailing edge of the model was either attached or separated. Unsteady flows were avoided by controlling the Mach number and angle of attack. Surface pressures were measured on both the model and wind tunnel walls, and the flowfield surrounding the model was documented using a laser Doppler velocimeter (LDV). Although wall interference could not be completely eliminated, its effect was minimized by employing the following techniques. Sidewall boundary layers were reduced by aspiration, and upper and lower walls were contoured to accommodate the flow around the model and the boundary-layer growth on the tunnel walls. A data base with minimal interference from a tunnel with solid walls provides an ideal basis for evaluating the development of codes for the transonic speed range because the codes can include the wall boundary conditions more precisely than interference connections can be made to the data sets.

Wall shear measurement in sand-water mixture flows

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yucel, O.; Grad, W.H.

1975-07-01

The wall shear stress was measured in clear-water and sand-water mixture flows with the use of a flush-mounting hot-film shear-sensor. Data were obtained with 2 shear-sensors and 2 different sands (d50 = 0.45 mm and d50 = 0.88 mm) with solids concentrations of up to Cmax = 1.6% by vol, and for flow Reynolds number of 10/sup 5/ < RD < 6 x 10/sup 5/. The measured sensor wall shear stresses were compared with the true wall shear stresses obtained with the energy head loss measurements conducted in a pipeline system. The results of the tests in the clear-water flowsmore » confirmed the relationship between the sensor power output, Ps, and the wall shear stress, tauo, given by tauo1/3 = APs + B, in which A and B are calibration coefficients. The tests with the low-concentration sand-water mixtures in a vertical pipe indicated that for the present range of experiments, sensor power outputs with the mixtures exceeded those for clear-water by an average of 5%. It is shown that the shear sensors are delicate but accurate instruments that can be used for the measurement of the wall shear stress. (13 refs.)« less

A New Formulation of Time Domain Boundary Integral Equation for Acoustic Wave Scattering in the Presence of a Uniform Mean Flow

NASA Technical Reports Server (NTRS)

Hu, Fang; Pizzo, Michelle E.; Nark, Douglas M.

2017-01-01

It has been well-known that under the assumption of a constant uniform mean flow, the acoustic wave propagation equation can be formulated as a boundary integral equation, in both the time domain and the frequency domain. Compared with solving partial differential equations, numerical methods based on the boundary integral equation have the advantage of a reduced spatial dimension and, hence, requiring only a surface mesh. However, the constant uniform mean flow assumption, while convenient for formulating the integral equation, does not satisfy the solid wall boundary condition wherever the body surface is not aligned with the uniform mean flow. In this paper, we argue that the proper boundary condition for the acoustic wave should not have its normal velocity be zero everywhere on the solid surfaces, as has been applied in the literature. A careful study of the acoustic energy conservation equation is presented that shows such a boundary condition in fact leads to erroneous source or sink points on solid surfaces not aligned with the mean flow. A new solid wall boundary condition is proposed that conserves the acoustic energy and a new time domain boundary integral equation is derived. In addition to conserving the acoustic energy, another significant advantage of the new equation is that it is considerably simpler than previous formulations. In particular, tangential derivatives of the solution on the solid surfaces are no longer needed in the new formulation, which greatly simplifies numerical implementation. Furthermore, stabilization of the new integral equation by Burton-Miller type reformulation is presented. The stability of the new formulation is studied theoretically as well as numerically by an eigenvalue analysis. Numerical solutions are also presented that demonstrate the stability of the new formulation.

[Three dimensional mathematical model of tooth for finite element analysis].

PubMed

Puskar, Tatjana; Vasiljević, Darko; Marković, Dubravka; Jevremović, Danimir; Pantelić, Dejan; Savić-Sević, Svetlana; Murić, Branka

2010-01-01

The mathematical model of the abutment tooth is the starting point of the finite element analysis of stress and deformation of dental structures. The simplest and easiest way is to form a model according to the literature data of dimensions and morphological characteristics of teeth. Our method is based on forming 3D models using standard geometrical forms (objects) in programmes for solid modeling. Forming the mathematical model of abutment of the second upper premolar for finite element analysis of stress and deformation of dental structures. The abutment tooth has a form of a complex geometric object. It is suitable for modeling in programs for solid modeling SolidWorks. After analysing the literature data about the morphological characteristics of teeth, we started the modeling dividing the tooth (complex geometric body) into simple geometric bodies (cylinder, cone, pyramid,...). Connecting simple geometric bodies together or substricting bodies from the basic body, we formed complex geometric body, tooth. The model is then transferred into Abaqus, a computational programme for finite element analysis. Transferring the data was done by standard file format for transferring 3D models ACIS SAT. Using the programme for solid modeling SolidWorks, we developed three models of abutment of the second maxillary premolar: the model of the intact abutment, the model of the endodontically treated tooth with two remaining cavity walls and the model of the endodontically treated tooth with two remaining walls and inserted post. Mathematical models of the abutment made according to the literature data are very similar with the real abutment and the simplifications are minimal. These models enable calculations of stress and deformation of the dental structures. The finite element analysis provides useful information in understanding biomechanical problems and gives guidance for clinical research.

Magnetic resonance tells microbiology where to go; bacterial teichoic acid protects liquid water at sub-zero temperatures

NASA Astrophysics Data System (ADS)

Rice, Charles V.; Wickham, Jason R.; Eastman, Margaret A.; Harrison, William; Pereira, Mark P.; Brown, Eric D.

2008-08-01

Numerous chemical additives lower the freezing point of water, but life at sub-zero temperatures is sustained by a limited number of biological cryoprotectants. Antifreeze proteins in fish, plants, and insects provide protection to a few degrees below freezing. Microbes have been found to survive at even lower temperatures, although, with a few exceptions, antifreeze proteins are missing. Survival has been attributed to external factors, such as high salt concentration (brine veins) and adhesion to particulates or ice crystal defects. Teichoic acid is a phosphodiester polymer ubiquitous in Gram positive bacteria, composing 50% of the mass of the bacterial cell wall and excreted into the extracellular space of biofilm communities. We have found that when bound to the peptidoglycan cell wall (wall teichoic acid) or as a free molecule (lipoteichoic acid), teichoic acid is surrounded by liquid water at temperatures significantly below freezing. Using solid-state NMR, we are unable to collect 31P CPMAS spectra for frozen solutions of lipoteichoic acid at temperatures above -60 °C. For wall teichoic acid in D2O, signals are not seen above -30 °C. These results can be explained by the presence of liquid water, which permits rapid molecular motion to remove 1H/31P dipolar coupling. 2H quadrupole echo NMR spectroscopy reveals that both liquid and solid water are present. We suggest that teichoic acids could provide a shell of liquid water around biofilms and planktonic bacteria, removing the need for brine veins to prevent bacterial freezing.

Organic/hybrid nanoparticles and single-walled carbon nanotubes: preparation methods and chiral applications.

PubMed

Alhassen, Haysem; Antony, Vijy; Ghanem, Ashraf; Yajadda, Mir Massoud Aghili; Han, Zhao Jun; Ostrikov, Kostya Ken

2014-11-01

Nanoparticles are molecular-sized solids with at least one dimension measuring between 1-100 nm or 10-1000 nm depending on the individual discipline's perspective. They are aggregates of anywhere from a few hundreds to tens of thousands of atoms which render them larger than molecules but smaller than bulk solids. Consequently, they frequently exhibit physical and chemical properties somewhere between. On the other hand, nanocrystals are a special class of nanoparticles which have started gaining attention recently owing to their unique crystalline structures which provide a larger surface area and promising applications including chiral separations. Hybrid nanoparticles are supported by the growing interest of chemists, physicists, and biologists, who are researching to fully exploit them. These materials can be defined as molecular or nano-composites with mixed (organic or bio) and inorganic components, where at least one of the component domain has a dimension ranging from a few Å to several nanometers. Similarly, and due to their extraordinary physical, chemical, and electrical properties, single-walled carbon nanotubes have been the subject of intense research. In this short review, the focus is mainly on the current well-established simple preparation techniques of chiral organic and hybrid nanoparticles as well as single-walled carbon nanotubes and their applications in separation science. Of particular interest, cinchonidine, chitosan, and β-CD-modified gold nanoparticles (GNPs) are discussed as model examples for organic and hybrid nanoparticles. Likewise, the chemical vapor deposition method, used in the preparation of single-walled carbon nanotubes, is discussed. The enantioseparation applications of these model nanomaterials is also presented. © 2014 Wiley Periodicals, Inc.

Fully-resolved prolate spheroids in turbulent channel flows: A lattice Boltzmann study

NASA Astrophysics Data System (ADS)

Eshghinejadfard, Amir; Hosseini, Seyed Ali; Thévenin, Dominique

2017-09-01

Particles are present in many natural and industrial multiphase flows. In most practical cases, particle shape is not spherical, leading to additional difficulties for numerical studies. In this paper, DNS of turbulent channel flows with finite-size prolate spheroids is performed. The geometry includes a straight wall-bounded channel at a frictional Reynolds number of 180 seeded with particles. Three different particle shapes are considered, either spheroidal (aspect ratio λ =2 or 4) or spherical (λ =1 ). Solid-phase volume fraction has been varied between 0.75% and 1.5%. Lattice Boltzmann method (LBM) is used to model the fluid flow. The influence of the particles on the flow field is simulated by immersed boundary method (IBM). In this Eulerian-Lagrangian framework, the trajectory of each particle is computed individually. All particle-particle and particle-fluid interactions are considered (four-way coupling). Results show that, in the range of examined volume fractions, mean fluid velocity is reduced by addition of particles. However, velocity reduction by spheroids is much lower than that by spheres; 2% and 1.6%, compared to 4.6%. Maximum streamwise velocity fluctuations are reduced by addition of particle. By comparing particle and fluid velocities, it is seen that spheroids move faster than the fluid before reaching the same speed in the channel center. Spheres, on the other hand, move slower than the fluid in the buffer layer. Close to the wall, all particle types move faster than the fluid. Moreover, prolate spheroids show a preferential orientation in the streamwise direction, which is stronger close to the wall. Far from the wall, the orientation of spheroidal particles tends to isotropy.

NACA Transonic Wind-tunnel Test Sections

NASA Technical Reports Server (NTRS)

Wright, Ray H; Ward, Vernon G

1955-01-01

Report presents an approximate subsonic theory for the solid-blockage interference in circular wind tunnels with walls slotted in the direction of flow. This theory indicated the possibility of obtaining zero blockage interference. Tests in a circular slotted tunnel based on the theory confirmed the theoretical predictions.

Hybrid fibers made of molybdenum disulfide, reduced graphene oxide, and multi-walled carbon nanotubes for solid-state, flexible, asymmetric supercapacitors.

PubMed

Sun, Gengzhi; Zhang, Xiao; Lin, Rongzhou; Yang, Jian; Zhang, Hua; Chen, Peng

2015-04-07

One of challenges existing in fiber-based supercapacitors is how to achieve high energy density without compromising their rate stability. Owing to their unique physical, electronic, and electrochemical properties, two-dimensional (2D) nanomaterials, e.g., molybdenum disulfide (MoS2 ) and graphene, have attracted increasing research interest and been utilized as electrode materials in energy-related applications. Herein, by incorporating MoS2 and reduced graphene oxide (rGO) nanosheets into a well-aligned multi-walled carbon nanotube (MWCNT) sheet followed by twisting, MoS2 -rGO/MWCNT and rGO/MWCNT fibers are fabricated, which can be used as the anode and cathode, respectively, for solid-state, flexible, asymmetric supercapacitors. This fiber-based asymmetric supercapacitor can operate in a wide potential window of 1.4 V with high Coulombic efficiency, good rate and cycling stability, and improved energy density. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Solid-contact pH-selective electrode using multi-walled carbon nanotubes.

PubMed

Crespo, Gastón A; Gugsa, Derese; Macho, Santiago; Rius, F Xavier

2009-12-01

Multi-walled carbon nanotubes (MWCNT) are shown to be efficient transducers of the ionic-to-electronic current. This enables the development of a new solid-contact pH-selective electrode that is based on the deposition of a 35-microm thick layer of MWCNT between the acrylic ion-selective membrane and the glassy carbon rod used as the electrical conductor. The ion-selective membrane was prepared by incorporating tridodecylamine as the ionophore, potassium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as the lipophilic additive in a polymerized methylmethacrylate and an n-butyl acrylate matrix. The potentiometric response shows Nernstian behaviour and a linear dynamic range between 2.89 and 9.90 pH values. The response time for this electrode was less than 10 s throughout the whole working range. The electrode shows a high selectivity towards interfering ions. Electrochemical impedance spectroscopy and chronopotentiometry techniques were used to characterise the electrochemical behaviour and the stability of the carbon-nanotube-based ion-selective electrodes.

Effect of silicone oil on solid propellant combustion in small motors. [for rockets

NASA Technical Reports Server (NTRS)

Ramohalli, K.

1980-01-01

The feasibility of reducing troublesome nozzle blockage (by condensation deposits) in laboratory-scale solid rockets by addition of a silicone oil as a propellant ingredient was explored experimentally. An aluminized composite propellant and its counterpart with 1% silicone oil replacing part of the binder were fired in a 63.5 mm diameter, end-burning, all-metal burner. Pressure-time histories were recorded for all of the tests by a Taber gauge mounted at the downstream end of the chamber; temperature-time data at the nozzle throat were obtained in some of the runs by thermocouples having junctions positioned at the wall but insulated from the metal. Deposition of condensables on the nozzle walls causing a progressive increase in the chamber pressure with time was noted. The fraction of firings exhibiting practically no condensation was 59% with silicone and 32% without. On the average, temperature readings at the nozzle throat were higher with the silicone propellants. Although various phenomena may contribute to these findings, the results are not understood completely.

Wide-angle x-ray scattering and solid-state nuclear magnetic resonance data combined to test models for cellulose microfibrils in mung bean cell walls.

PubMed

Newman, Roger H; Hill, Stefan J; Harris, Philip J

2013-12-01

A synchrotron wide-angle x-ray scattering study of mung bean (Vigna radiata) primary cell walls was combined with published solid-state nuclear magnetic resonance data to test models for packing of (1→4)-β-glucan chains in cellulose microfibrils. Computer-simulated peak shapes, calculated for 36-chain microfibrils with perfect order or uncorrelated disorder, were sharper than those in the experimental diffractogram. Introducing correlated disorder into the models broaden the simulated peaks but only when the disorder was increased to unrealistic magnitudes. Computer-simulated diffractograms, calculated for 24- and 18-chain models, showed good fits to experimental data. Particularly good fits to both x-ray and nuclear magnetic resonance data were obtained for collections of 18-chain models with mixed cross-sectional shapes and occasional twinning. Synthesis of 18-chain microfibrils is consistent with a model for cellulose-synthesizing complexes in which three cellulose synthase polypeptides form a particle and six particles form a rosette.

Theoretical study of nonadiabatic boundary-layer stabilization times in a cryogenic wind tunnel for typical stainless steel wing and fuselage models

NASA Technical Reports Server (NTRS)

Johnson, C. B.

1980-01-01

The time varying effect of nonadiabatic wall conditions on boundary layer properties was studied for a two dimensional wing section and an axisymmetric fuselage. The wing and fuselage sections are representative of the wing root chord and fuselage of a typical transport model for the National Transonic Facility. The analysis was made with a solid wing and three fuselage configurations (one solid and two hollow with varying skin thicknesses) all made from AISI type 310S stainless steel. The displacement thickness and local skin friction were investigated at a station on the model in terms of the time required for these two boundary layer properties to reach an adiabatic wall condition after a 50 K step change in total temperature. The analysis was made for a free stream Mach number of 0.85, a total temperature of 117 K, and stagnation pressures of 2, 6, and 9 atm.

Serially connected solid oxide fuel cells having monolithic cores

DOEpatents

Herceg, J.E.

1985-05-20

Disclosed is a solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output. The cell core has an array of cell segments electrically serially connected in the flow direction, each segment consisting of electrolyte walls and interconnect that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageways; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte composite materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick. Between 2 and 50 cell segments may be connected in series.

Adsorption of Cationic Peptides to Solid Surfaces of Glass and Plastic

PubMed Central

Kristensen, Kasper; Henriksen, Jonas R.; Andresen, Thomas L.

2015-01-01

Cationic membrane-active peptides have been studied for years in the hope of developing them into novel types of therapeutics. In this article, we investigate an effect that might have significant experimental implications for investigators who wish to study these peptides, namely, that the peptides adsorb to solid surfaces of glass and plastic. Specifically, we use analytical HPLC to systematically quantify the adsorption of the three cationic membrane-active peptides mastoparan X, melittin, and magainin 2 to the walls of commonly used glass and plastic sample containers. Our results show that, at typical experimental peptide concentrations, 90% or more of the peptides might be lost from solution due to rapid adsorption to the walls of the sample containers. Thus, our results emphasize that investigators should always keep these adsorption effects in mind when designing and interpreting experiments on cationic membrane-active peptides. We conclude the article by discussing different strategies for reducing the experimental impact of these adsorption effects. PMID:25932639

Gasless laparoscopic surgery plus abdominal wall lifting for giant hiatal hernia-our single-center experience.

PubMed

Yu, Jiang-Hong; Wu, Ji-Xiang; Yu, Lei; Li, Jian-Ye

2016-12-01

Giant hiatal hernia (GHH) comprises 5% of hiatal hernia and is associated with significant complications. The traditional operative procedure, no matter transthoracic or transabdomen repair of giant hiatal hernia, is characteristic of more invasion and more complications. Although laparoscopic repair as a minimally invasive surgery is accepted, a part of patients can not tolerate pneumoperitoneum because of combination with cardiopulmonary diseases or severe posterior mediastinal and neck emphesema during operation. The aim of this article was to analyze our experience in gasless laparoscopic repair with abdominal wall lifting to treat the giant hiatal hernia. We performed a retrospective review of patients undergoing gasless laparoscopic repair of GHH with abdominal wall lifting from 2012 to 2015 at our institution. The GHH was defined as greater than one-third of the stomach in the chest. Gasless laparoscopic repair of GHH with abdominal wall lifting was attempted in 27 patients. Mean age was 67 years. The results showed that there were no conversions to open surgery and no intraoperative deaths. The mean duration of operation was 100 min (range: 90-130 min). One-side pleura was injured in 4 cases (14.8%). The mean postoperative length of stay was 4 days (range: 3-7 days). Median follow- up was 26 months (range: 6-38 months). Transient dysphagia for solid food occurred in three patients (11.1%), and this symptom disappeared within three months. There was one patient with recurrent hiatal hernia who was reoperated on. Two patients still complained of heartburn three months after surgery. Neither reoperation nor endoscopic treatment due to signs of postoperative esophageal stenosis was required in any patient. Totally, satisfactory outcome was reported in 88.9% patients. It was concluded that the gasless laparoscopic approach with abdominal wall lifting to the repair of GHH is feasible, safe, and effective for the patients who cannot tolerate the pneumoperitoneum.

MHD mixed convection and entropy generation of water-alumina nanofluid flow in a double lid driven cavity with discrete heating

NASA Astrophysics Data System (ADS)

Hussain, S.; Mehmood, K.; Sagheer, M.

2016-12-01

In the present study, entropy generation due to mixed convection in a partially heated square double lid driven cavity filled with Al2O3 -water nanofluid under the influence of inclined magnetic field is numerically investigated. At the lower wall of the cavity two heat sources are fixed, with the condition that the remaining part of the bottom wall is kept insulated. Top wall and vertically moving walls are maintained at constant cold temperature. Buoyant force is responsible for the flow along with the two moving vertical walls. Governing equations are discretized in space using LBB-stable finite element pair Q2 / P1disc which lead to 3rd and 2nd order accuracy in the L2-norm for the velocity/temperature and pressure, respectively and the fully implicit Crank-Nicolson scheme of 2nd order accuracy is utilized for the temporal discretization. The discretized systems of nonlinear equations are treated by using the Newton method and the associated linear subproblems are solved by means of Guassian elimination method. Numerical results are presented and analyzed by means of streamlines, isotherms, tables and some useful plots. Impacts of emerging parameters on the flow, in specific ranges such as Reynolds number (1 ≤ Re ≤ 100) , Richardson number (1 ≤ Ri ≤ 50) , Hartman number (0 ≤ Ha ≤ 100) , solid volume fraction (0 ≤ ϕ ≤ 0.2) as well as the angles of inclined magnetic field (0 ° ≤ γ ≤ 90 °) are investigated and the findings are exactly of the same order as that of the previously performed analysis. Calculation of average Nusselt number, entropy generation due to heat transfer, fluid friction and magnetic field, total entropy generation, Bejan number and kinetic energy are the main focus of our study.

Some Finite Difference Solutions of the Laminar Compressible Boundary Layer Showing the Effects of Upstream Transpiration Cooling

NASA Technical Reports Server (NTRS)

Howe, John T.

1959-01-01

Three numerical solutions of the partial differential equations describing the compressible laminar boundary layer are obtained by the finite difference method described in reports by I. Flugge-Lotz, D.C. Baxter, and this author. The solutions apply to steady-state supersonic flow without pressure gradient, over a cold wall and over an adiabatic wall, both having transpiration cooling upstream, and over an adiabatic wall with upstream cooling but without upstream transpiration. It is shown that for a given upstream wall temperature, upstream transpiration cooling affords much better protection to the adiabatic solid wall than does upstream cooling without transpiration. The results of the numerical solutions are compared with those of approximate solutions. The thermal results of the finite difference solution lie between the results of Rubesin and Inouye, and those of Libby and Pallone. When the skin-friction results of one finite difference solution are used in the thermal analysis of Rubesin and Inouye, improved agreement between the thermal results of the two methods of solution is obtained.

Interaction between a laminar starting immersed micro-jet and a parallel wall

NASA Astrophysics Data System (ADS)

Cabaleiro, Juan Martin; Laborde, Cecilia; Artana, Guillermo

2015-01-01

In the present work, we study the starting transient of an immersed micro-jet in close vicinity to a solid wall parallel to its axis. The experiments concern laminar jets (Re < 200) issuing from a 100 μm internal tip diameter glass micro-pipette. The effect of the confinement was studied placing the micro-pipette at different distances from the wall. The characterization of the jet was carried out by visualizations on which the morphology of the vortex head and trajectories was analyzed. Numerical simulations were used as a complementary tool for the analysis. The jet remains stable for very long distances away from the tip allowing for a similarity analysis. The self-similar behavior of the starting jet has been studied in terms of the frontline position with time. A symmetric and a wall dominated regime could be identified. The starting jet in the wall type regime, and in the symmetric regime as well, develops a self-similar behavior that has a relative rapid loss of memory of the preceding condition of the flow. Scaling for both regimes are those that correspond to viscous dominated flows.

Effects of Melt Convection and Solid Transport on Macrosegregation and Grain Structure in Equiaxed Al-Cu Alloys

NASA Technical Reports Server (NTRS)

Rerko, Rodney S.; deGroh, Henry C., III; Beckermann, Christoph

2000-01-01

Macrosegregation in metal casting can be caused by thermal and solutal melt convection, and the transport of unattached solid crystals resulting from nucleation in the bulk liquid or dendrite fragmentation. To develop a comprehensive numerical model for the casting of alloys, an experimental study has been conducted to generate benchmark data with which such a solidification model could be tested. The objectives were: (1) experimentally study the effects of solid transport and thermosolutal convection on macrosegregation and grain size; and (2) provide a complete set of boundary conditions temperature data, segregation data, and grain size data - to validate numerical models. Through the control of end cooling and side wall heating, radial temperature gradients in the sample and furnace were minimized. Thus the vertical crucible wall was adiabatic. Samples at room temperature were 24 cc and 95 mm long. The alloys used were Al-1 wt. pct. Cu, and Al- 10 wt. pct. Cu; the starting point for solidification was isothermal at 710 and 685 C respectively. To induce an equiaxed structure various amounts of the grain refiner TiB2 were added. Samples were either cooled from the top, or the bottom. Several trends in the data stand out. In attempting to model these experiments, concentrating on these trends or differences may be beneficial.

Mode of alpha-amylase production by the shochu koji mold Aspergillus kawachii.

PubMed

Nagamine, Kazuki; Murashima, Kenji; Kato, Taku; Shimoi, Hitoshi; Ito, Kiyoshi

2003-10-01

Aspergillus kawachii produces two kinds of alpha-amylase, one is an acid-unstable alpha-amylase and the other is an acid-stable alpha-amylase. Because the quality of the shochu depends strongly on the activities of the alpha-amylases, the culture conditions under which these alpha-amylases are produced were examined. In liquid culture, acid-unstable alpha-amylase was produced abundantly, but, acid-stable alpha-amylase was not produced. The acid-unstable alpha-amylase was produced significantly when glycerol or glucose was used as a carbon source, similarly to the use of inducers such as starch or maltose. In liquid culture, A. kawachii assimilated starch at pH 3.0, but no alpha-amylase activity was recognized in the medium. Instead, the alpha-amylase was found to be trapped in the cell wall. The trapped form was identified as acid-unstable alpha-amylase. Usually, acid-unstable alpha-amylase is unstable at pH 3.0, so its stability appeared to be due to its immobilization in the cell wall. In solid-state culture, both kinds of alpha-amylase were produced. The production of acid-stable alpha-amylase seems to be solid-state culture-specific and was affected by the moisture content in the solid medium.