Special Issue in Honor of Professor S. Ted Oyama: 2014 ACS Distinguished Researcher Award in Petroleum Chemistry and Storch Award in Fuel Science

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bravo-Suárez, Juan J.; Wang, Xianqin; Li, Wei

This special issue of Topics in Catalysis honors Professor S. Ted Oyama for his Awards in Petroleum Chemistry and Fuel Science Research. These awards were celebrated at two American Chemical Society (ACS) symposia in 2014. First, the ACS’s Distinguished Research Award in Petroleum Chemistry Symposium, took place at the 247th ACS National Meeting in Dallas, TX, during March 17-19, 2014 and the second one, the ACS’s Storch Award in Fuel Science Symposium, took place at the 248th ACS National Meeting in San Francisco, CA, during August 10-12, 2014. Professor Oyama received the 2014 ACS Distinguished Research Award in Petroleum Chemistrymore » ‘‘for his substantial contributions to the field of heterogeneous catalysis’’ including the discovery of highly active transition metal phosphide catalysts for hydrotreatment of petroleum and coal-derived feedstocks and biomass refining, the development of new compositions, and the understanding of their reaction mechanisms by in situ spectroscopic techniques at high temperatures and pressures of reaction. In light of this recognition, Professor Oyama was also awarded the 2014 ACS Storch Award in Fuel Science ‘‘for his broad contributions to the field of fuel science’’ including the production of hydrogen by catalytic reforming, selective oxidation of hydrocarbons, biomass conversion, their reaction kinetics and mechanisms, and spectrokinetic methods to study catalysts in situ at reaction conditions and theory and application of inorganic membranes for separation of hydrogen and fuel-relevant gases. Finally, this special issue consists of contributions by catalysis researchers who participated in the two ACS symposia honoring Professor Oyama’s Awards.« less

Petroleum marketing monthly, September 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum product sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensuresmore » the accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.« less

Petroleum marketing monthly, February 1999 with data for November 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1999-02-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products aremore » presented in the Petroleum Marketing Monthly in six sections: Initial Estimates; Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. 7 figs., 50 tabs.« less

Petroleum marketing monthly, March 1999 with data for December 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1999-03-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products aremore » presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products aremore » presented in the Petroleum Marketing Monthly in five sections: summary statistics; crude oil prices; prices of petroleum products; volumes of petroleum products; and prime supplier sales volumes of petroleum products for local consumption. 7 figs., 50 tabs.« less

Petroleum marketing monthly, April 1997 with data for January 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1997-04-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

Petroleum marketing monthly, January 1998 with data for October 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1998-01-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. 7 figs., 50 tabs.

Petroleum marketing monthly with data for May 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1997-08-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures themore » accuracy, quality, and confidentiality of the published data in the Petroleum Marketing Monthly.« less

Petroleum marketing monthly, June 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-06-01

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, and the refiners` acquisition cost of crude oil. Refined petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. Monthly statistics on purchases of crude oil and sales of petroleum products aremore » presented in five sections: Summary Statistics; Crude Oil Prices; Prices of Petroleum Products; Volumes of Petroleum Products; and Prime Supplier Sales Volumes of Petroleum Products for Local Consumption. The feature article is entitled ``The Second Oxygenated Gasoline Season.`` 7 figs., 50 tabs.« less

13 CFR 121.511 - What is the size standard for buying Government-owned petroleum?

Code of Federal Regulations, 2011 CFR

2011-01-01

... buying Government-owned petroleum? 121.511 Section 121.511 Business Credit and Assistance SMALL BUSINESS... Government-owned petroleum? A concern is small for this purpose if it is primarily engaged in petroleum refining and meets the size standard for a petroleum refining business. ...

13 CFR 121.511 - What is the size standard for buying Government-owned petroleum?

Code of Federal Regulations, 2010 CFR

2010-01-01

... buying Government-owned petroleum? 121.511 Section 121.511 Business Credit and Assistance SMALL BUSINESS... Government-owned petroleum? A concern is small for this purpose if it is primarily engaged in petroleum refining and meets the size standard for a petroleum refining business. ...

40 CFR 60.100 - Applicability, designation of affected facility, and reconstruction.

Code of Federal Regulations, 2011 CFR

2011-07-01

... petroleum refineries: fluid catalytic cracking unit catalyst regenerators, fuel gas combustion devices, and... petroleum refinery. (b) Any fluid catalytic cracking unit catalyst regenerator or fuel gas combustion device...) and (d) of this section. (c) Any fluid catalytic cracking unit catalyst regenerator under paragraph (b...

40 CFR 60.100 - Applicability, designation of affected facility, and reconstruction.

Code of Federal Regulations, 2012 CFR

2012-07-01

... petroleum refineries: fluid catalytic cracking unit catalyst regenerators, fuel gas combustion devices, and... petroleum refinery. (b) Any fluid catalytic cracking unit catalyst regenerator or fuel gas combustion device...) and (d) of this section. (c) Any fluid catalytic cracking unit catalyst regenerator under paragraph (b...

40 CFR 60.100 - Applicability, designation of affected facility, and reconstruction.

Code of Federal Regulations, 2010 CFR

2010-07-01

... petroleum refineries: fluid catalytic cracking unit catalyst regenerators, fuel gas combustion devices, and... petroleum refinery. (b) Any fluid catalytic cracking unit catalyst regenerator or fuel gas combustion device...) and (d) of this section. (c) Any fluid catalytic cracking unit catalyst regenerator under paragraph (b...

Chapter 19: Catalysis by Metal Carbides and Nitrides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schaidle, Joshua A; Nash, Connor P; Yung, Matthew M

Early transition metal carbides and nitrides (ETMCNs), materials in which carbon or nitrogen occupies interstitial sites within a parent metal lattice, possess unique physical and chemical properties that motivate their use as catalysts. Specifically, these materials possess multiple types of catalytic sites, including metallic, acidic, and basic sites, and as such, exhibit reactivities that differ from their parent metals. Moreover, their surfaces are dynamic under reaction conditions. This chapter reviews recent (since 2010) experimental and computational investigations into the catalytic properties of ETMCN materials for applications including biomass conversion, syngas and CO2 upgrading, petroleum and natural gas refining, and electrocatalyticmore » energy conversion, energy storage, and chemicals production, and attempts to link catalyst performance to active site identity/surface structure in order to elucidate the present level of understanding of structure-function relationships for these materials. The chapter concludes with a perspective on leveraging the unique properties of these materials to design and develop improved catalysts through a dedicated, multidisciplinary effort.« less

Practical Advances in Petroleum Processing

NASA Astrophysics Data System (ADS)

Hsu, Chang S.; Robinson, Paul R.

"This comprehensive book by Robinson and Hsu will certainly become the standard text book for the oil refining business...[A] must read for all who are associated with oil refining." - Dr. Walter Fritsch, Senior Vice President Refining, OMV "This book covers a very advanced horizon of petroleum processing technology. For all refiners facing regional and global environmental concerns, and for those who seek a more sophisticated understanding of the refining of petroleum resources, this book has been long in coming." - Mr. Naomasa Kondo, Cosmo Oil Company, Ltd.

Reductions in Northeast Refining Activity: Potential Implications for Petroleum Product Markets

EIA Publications

2011-01-01

This report is the Energy Information Administration's (EIA) initial effort to provide information and analysis on the potential impacts on petroleum product markets from reductions in Northeast petroleum refining activity.

Process for magnetic beneficiating petroleum cracking catalyst

DOEpatents

Doctor, R.D.

1993-10-05

A process is described for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded. 1 figures.

Process for magnetic beneficiating petroleum cracking catalyst

DOEpatents

Doctor, Richard D.

1993-01-01

A process for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded.

Heterolytic Activation of Hydrogen Promoted by Ruthenium Nanoparticles immobilized on Basic Supports and Hydrogenation of Aromatic Compounds

NASA Astrophysics Data System (ADS)

Fang, Minfeng

Despite the aggressive development and deployment of new renewable and nuclear technologies, petroleum-derived transportation fuels---gasoline, diesel and jet fuels---will continue to dominate the markets for decades. Environmental legislation imposes severe limits on the tolerable proportion of aromatics, sulfur and nitrogen contents in transportation fuels, which is difficult to achieve with current refining technologies. Catalytic hydrogenation plays an important role in the production of cleaner fuels, both as a direct means to reduce the aromatics and as a key step in the hydrodenitrogenation (HDN) and hydrodesulfurization (HDS) processes. However, conventional catalysts require drastic conditions and/or are easily poisoned by S or N aromatics. Therefore, there is still a need for new efficient catalysts for hydrogenation reactions relevant to the production of cleaner fossil fuels. Our catalyst design involves metallic nanoparticles intimately associated with a basic support, with the aim of creating a nanostructure capable of promoting the heterolytic activation of hydrogen and ionic hydrogenation mechanisms, as a strategy to avoid catalyst poisoning and enhance catalytic activity. We have designed and prepared a new nanostructured catalytic material composed of RuNPs immobilized on the basic polymer P4VPy. We have demonstrated that the Ru/P4VPy catalyst can promote heterolytic hydrogen activation and a unique surface ionic hydrogenation mechanism for the efficient hydrogenation of N-aromatics. This is the first time these ionic hydrogenation pathways have been demonstrated on solid surfaces. For the RuNPs surfaces without basic sites in close proximity, the conventional homolytic H2 splitting is otherwise involved. Using the mechanistic concepts from Ru/P4VPy, we have designed and prepared the Ru/MgO catalyst, with the aim to improve the catalytic efficiency for the hydrogenation of heteroatom aromatics operating by the ionic hydrogenation mechanism. The Ru/MgO catalyst significantly improves the catalytic efficiency for hydrogenation of a variety of N-/S-heteroaromatics and mono-/polycyclic aromatic hydrocarbons representative of components of petroleum-derived fuels. The catalyst is superior to the few other known supported noble metal catalysts for these reactions. Mechanistic studies also point to the ionic hydrogenation mechanism on the Ru/MgO surfaces. In addition, the Ru/MgO catalyst is highly recyclable and long-lived.

Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elliott, Douglas C.

2006-02-14

The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOPmore » and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.« less

Selective recovery of molybdenum from spent HDS catalyst using oxidative soda ash leach/carbon adsorption method.

PubMed

Park, Kyung Ho; Mohapatra, D; Reddy, B Ramachandra

2006-11-16

The petroleum refining industry makes extensive use of hydroprocessing catalysts. These catalysts contain environmentally critical and economically valuable metals such as Mo, V, Ni and Co. In the present study, a simple hydrometallurgical processing of spent hydrodesulphurization (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixture was investigated. Recovery of molybdenum was largely dependent on the concentrations of Na2CO3 and H2O2 in the reaction medium, which in turn controls the pH of leach liquor and the presence of Al and Ni as impurities. Under the optimum leaching conditions (40 g L(-1) Na2CO3, 6 vol.% H2O2, room temperature, 1h) about 85% recovery of Mo was achieved. The leach liquor was processed by the carbon adsorption method, which selectively adsorbs Mo at pH around 0.75. Desorption of Mo was selective at 15 vol.% NH4OH. With a single stage contact, it was found possible to achieve >99%, adsorption and desorption efficiency. Using this method, recovery of molybdenum as MoO3 product of 99.4% purity was achieved.

Microwave-assisted Extraction of Rare Earth Elements from Petroleum Refining Catalysts and Ambient Fine Aerosols Prior to Inductively Coupled Plasma - Mass Spectrometry

NASA Technical Reports Server (NTRS)

Mittlefehldt, David W.; Kulkarni, Pranav; Chellam, Shankar

2006-01-01

In the absence of a certified reference material, a robust microwave-assisted acid digestion procedure followed by inductively coupled plasma - mass spectrometry (ICP-MS) was developed to quantify rare earth elements (REEs) in fluidized-bed catalytic cracking (FCC) catalysts and atmospheric fine particulate matter (PM2.5). High temperature (200 C), high pressure (200 psig), acid digestion (HNO3, HF, and H3BO3) with 20 minute dwell time effectively solubilized REEs from six fresh catalysts, a spent catalyst, and PM2.5. This method was also employed to measure 27 non-REEs including Na, Mg, Al, Si, K, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Zr, Mo, Cd, Cs, Ba, Pb, and U. Complete extraction of several REEs (Y, La, Ce, Pr, Nd, Tb, Dy, and Er) required HF indicating that they were closely associated with the aluminosilicate structure of the zeolite FCC catalysts. Internal standardization using 115In quantitatively corrected non-spectral interferences in the catalyst digestate matrix. Inter-laboratory comparison using ICP-optical emission spectroscopy (ICP-OES) and instrumental neutron activation analysis (INAA) demonstrated the applicability of the newly developed analytical method for accurate analysis of REEs in FCC catalysts. The method developed for FCC catalysts was also successfully implemented to measure trace to ultra-trace concentrations of La, Ce, Pr, Nd, Sm, Gd, Eu, and Dy in ambient PM2.5 in an industrial area of Houston, TX.

Bioleaching of nickel from spent petroleum catalyst using Acidithiobacillus thiooxidans DSM- 11478.

PubMed

Sharma, Mohita; Bisht, Varsha; Singh, Bina; Jain, Pratiksha; Mandal, Ajoy K; Lal, Banwari; Sarma, Priyangshu M

2015-06-01

The present work deals with optimization of culture conditions and process parameters for bioleaching of spent petroleum catalyst collected from a petroleum refinery. The efficacy of Ni bioleaching from spent petroleum catalyst was determined using pure culture of Acidithiobacillus thiooxidans DSM- 11478. The culture conditions of pH, temperature and headspace volume to media volume ratio were optimized. EDX analysis was done to confirm the presence of Ni in the spent catalyst after roasting it to decoke its surface. The optimum temperature for A. thiooxidans DSM-11478 growth was found to be 32 degrees C. The enhanced recovery of nickel at very low pH was attributed to the higher acidic strength of sulfuric acid produced in the culture medium by the bacterium. During the bioleaching process, 89% of the Ni present in the catalyst waste could be successfully recovered in optimized conditions. This environment friendly bioleaching process proved efficient than the chemical method. Taking leads from the lab scale results, bioleaching in larger volumes (1, 5 and 10 L) was also performed to provide guidelines for taking up this technology for in situ industrial waste management.

40 CFR 60.100 - Applicability, designation of affected facility, and reconstruction.

Code of Federal Regulations, 2013 CFR

2013-07-01

... petroleum refineries: fluid catalytic cracking unit catalyst regenerators, fuel gas combustion devices, and... petroleum refinery. (b) Any fluid catalytic cracking unit catalyst regenerator or fuel gas combustion device... regenerator under paragraph (b) of this section which commences construction, reconstruction, or modification...

40 CFR 60.100 - Applicability, designation of affected facility, and reconstruction.

Code of Federal Regulations, 2014 CFR

2014-07-01

... petroleum refineries: fluid catalytic cracking unit catalyst regenerators, fuel gas combustion devices, and... petroleum refinery. (b) Any fluid catalytic cracking unit catalyst regenerator or fuel gas combustion device... regenerator under paragraph (b) of this section which commences construction, reconstruction, or modification...

Technological Change and Its Labor Impact in Five Energy Industries. Coal Mining/Oil and Gas Extraction/Petroleum Refining/Petroleum Pipeline Transportation/Electric and Gas Utilities.

ERIC Educational Resources Information Center

Bureau of Labor Statistics (DOL), Washington, DC.

This bulletin appraises major technological changes emerging in five American industries (coal mining, oil and gas extraction, petroleum refining, petroleum pipeline transportation, and electric and gas utilities) and discusses the impact of these changes on productivity and occupations over the next five to ten years. Its separate reports on each…

Nutrient and suspended solids removal from petrochemical wastewater via microalgal biofilm cultivation.

PubMed

Hodges, Alan; Fica, Zachary; Wanlass, Jordan; VanDarlin, Jessica; Sims, Ronald

2017-05-01

Wastewater derived from petroleum refining currently accounts for 33.6 million barrels per day globally. Few wastewater treatment strategies exist to produce value-added products from petroleum refining wastewater. In this study, mixed culture microalgal biofilm-based treatment of petroleum refining wastewater using rotating algae biofilm reactors (RABRs) was compared with suspended-growth open pond lagoon reactors for removal of nutrients and suspended solids. Triplicate reactors were operated for 12 weeks and were continuously fed with petroleum refining wastewater. Effluent wastewater was monitored for nitrogen, phosphorus, total suspended solids (TSS), and chemical oxygen demand (COD). RABR treatment demonstrated a statistically significant increase in removal of nutrients and suspended solids, and increase in biomass productivity, compared to the open pond lagoon treatment. These trends translate to a greater potential for the production of biomass-based fuels, feed, and fertilizer as value-added products. This study is the first demonstration of the cultivation of mixed culture biofilm microalgae on petroleum refining wastewater for the dual purposes of treatment and biomass production. Copyright © 2017 Elsevier Ltd. All rights reserved.

Single-layer transition metal sulfide catalysts

DOEpatents

Thoma, Steven G [Albuquerque, NM

2011-05-31

Transition Metal Sulfides (TMS), such as molybdenum disulfide (MoS.sub.2), are the petroleum industry's "workhorse" catalysts for upgrading heavy petroleum feedstocks and removing sulfur, nitrogen and other pollutants from fuels. We have developed an improved synthesis technique to produce SLTMS catalysts, such as molybdenum disulfide, with potentially greater activity and specificity than those currently available. Applications for this technology include heavy feed upgrading, in-situ catalysis, bio-fuel conversion and coal liquefaction.

Petroleum marketing monthly, May 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-05-26

The Petroleum Marketing Monthly (PMM) provides information and statistical data on a variety of crude oils and refined petroleum products. The publication presents statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the f.o.b. and landed cost of imported crude oil, petroleum product sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published datamore » in the Petroleum Marketing Monthly.« less

40 CFR 98.390 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... petroleum products and natural gas liquids as listed in Table MM-1 of this subpart. (a) A petroleum refinery... products or natural gas liquids as listed in Table MM-1 of this subpart. Any blender or refiner of refined... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Petroleum Products § 98.390 Definition of the...

40 CFR 98.390 - Definition of the source category.

Code of Federal Regulations, 2013 CFR

2013-07-01

... petroleum products and natural gas liquids as listed in Table MM-1 of this subpart. (a) A petroleum refinery... products or natural gas liquids as listed in Table MM-1 of this subpart. Any blender or refiner of refined... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Petroleum Products § 98.390 Definition of the...

40 CFR 98.390 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

... petroleum products and natural gas liquids as listed in Table MM-1 of this subpart. (a) A petroleum refinery... products or natural gas liquids as listed in Table MM-1 of this subpart. Any blender or refiner of refined... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Petroleum Products § 98.390 Definition of the...

40 CFR 98.390 - Definition of the source category.

Code of Federal Regulations, 2014 CFR

2014-07-01

... petroleum products and natural gas liquids as listed in Table MM-1 of this subpart. (a) A petroleum refinery... products or natural gas liquids as listed in Table MM-1 of this subpart. Any blender or refiner of refined... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Petroleum Products § 98.390 Definition of the...

40 CFR 98.390 - Definition of the source category.

Code of Federal Regulations, 2012 CFR

2012-07-01

... petroleum products and natural gas liquids as listed in Table MM-1 of this subpart. (a) A petroleum refinery... products or natural gas liquids as listed in Table MM-1 of this subpart. Any blender or refiner of refined... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Suppliers of Petroleum Products § 98.390 Definition of the...

75 FR 66761 - Agency Information Collection Activities: Final Collection; Comment Request

Federal Register 2010, 2011, 2012, 2013, 2014

2010-10-29

... strengthen sanctions against Iran, the Act contains language prohibiting Ex-Im Bank from: Authoriz[ing] any... refiner that continues to: (A) Provide Iran with significant refined petroleum resources; (B) materially contribute to Iran's capability to import refined petroleum resources; or (C) allow Iran to maintain or...

Discovery of optimal zeolites for challenging separations and chemical transformations using predictive materials modeling

NASA Astrophysics Data System (ADS)

Bai, Peng; Jeon, Mi Young; Ren, Limin; Knight, Chris; Deem, Michael W.; Tsapatsis, Michael; Siepmann, J. Ilja

2015-01-01

Zeolites play numerous important roles in modern petroleum refineries and have the potential to advance the production of fuels and chemical feedstocks from renewable resources. The performance of a zeolite as separation medium and catalyst depends on its framework structure. To date, 213 framework types have been synthesized and >330,000 thermodynamically accessible zeolite structures have been predicted. Hence, identification of optimal zeolites for a given application from the large pool of candidate structures is attractive for accelerating the pace of materials discovery. Here we identify, through a large-scale, multi-step computational screening process, promising zeolite structures for two energy-related applications: the purification of ethanol from fermentation broths and the hydroisomerization of alkanes with 18-30 carbon atoms encountered in petroleum refining. These results demonstrate that predictive modelling and data-driven science can now be applied to solve some of the most challenging separation problems involving highly non-ideal mixtures and highly articulated compounds.

Desulfurization of gasoline.

PubMed Central

Berger, J E

1975-01-01

Although gasoline blending streams exhibit widely varying sulfur concentrations, significant quantities of low-sulfur motor gasoline cannot be manufactured by reallocation of existing components without substantial sacrifices in the useful properties of the remaining fuels having normal sulfur levels. To meet the anticipated demand for low-sulfur unleaded gasoline which may be required for catalyst-equipped automobiles it will be necessary to install process equipment based on known hydrotreating technology. The effects which this construction program would exert on the activities, abilities and needs of one petroleum refiner are sketched for two degrees of sulfur removal. The impacts of installing the process facilities which would be necessary are discussed in terms of time requirements, capital needs, and added energy expenditures. PMID:1157782

Integrated process for the solvent refining of coal

DOEpatents

Garg, Diwakar

1983-01-01

A process is set forth for the integrated liquefaction of coal by the catalytic solvent refining of a feed coal in a first stage to liquid and solid products and the catalytic hydrogenation of the solid product in a second stage to produce additional liquid product. A fresh inexpensive, throw-away catalyst is utilized in the second stage hydrogenation of the solid product and this catalyst is recovered and recycled for catalyst duty in the solvent refining stage without any activation steps performed on the used catalyst prior to its use in the solvent refining of feed coal.

XAS Study at Mo and Co K-Edges of the Sulfidation of a CoMo / Al2O3 Hydrotreating Catalyst

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pichon, C.; Gandubert, A. D.; Legens, C.

2007-02-02

Because of its impact on environment, the removal of sulfur is an indispensable step, called hydrotreatment, in the refining of petroleum. One of the most commonly used hydrotreating catalysts is CoMo-type catalyst which is composed of molybdenum disulfide slabs promoted by cobalt atoms (CoMoS phase) and well dispersed on a high specific area alumina. As far as the highest sulfur content allowed in gasoline and diesel is continually decreasing, more and more efficient and active hydrotreating catalysts are required. In order to optimize the reactivity of the CoMo-type catalyst in hydrotreatment, a better understanding of the processes used to producemore » the active phase (CoMoS slabs) of the catalyst is necessary. The study reported here deals with the sulfiding mechanism of the slabs and the influence of temperature on the phenomenon. Ex situ X-ray absorption spectroscopy (XANES and EXAFS) was used to study the evolution of the structure of CoMo-type catalyst sulfided at various temperatures (from 293 to 873 K). XAS analysis was performed at both molybdenum and cobalt K-edges to obtain a cross-characterization of the sulfidation of the slabs. It evidenced the formation of various compounds, including two molybdenum oxides, MoS3 (or MoS3-like compound) and Co9S8, at specific steps of the sulfiding process. It showed the role of intermediate played by MoS3 (or MoS3-like compound) during the formation of the slabs and the competition between the appearance of promoted slabs (CoMoS phase) and Co9S8. At last, it leaded to the proposal of a mechanism for the sulfidation of the catalyst.« less

Petroleum marketing annual 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1995-01-01

The Petroleum Marketing Annual (PMA) contains statistical data on a variety of crude oils and refined petroleum products. The publication provides statistics on crude oil costs and refined petroleum products sales for use by industry, government, private sector analysts, educational institutions, and consumers. Data on crude oil include the domestic first purchase price, the free-on-board (f.o.b.) and landed cost of imported crude oil, and the refiners acquisition cost of crude oil. Sales data for motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane are presented. For this publication, all estimates have been recalculated since their earlier publication in the Petroleummore » Marketing Monthly (PMM). These calculations made use of additional data and corrections that were received after the PMM publication dates.« less

Petroleum: An Energy Profile 1999

EIA Publications

1999-01-01

Explains in layman's terms the major components and operations of the U.S. petroleum industry that include: petroleum products, resources and reserves, drilling and exploration, refining, storage and transportation, imports, exports, and petroleum marketing.

CITGO Petroleum Corporation and PDV Midwest Refining, LLC Settlement

EPA Pesticide Factsheets

CITGO Petroleum Corporation and PDV Midwest Refining, LLC (collectively, CITGO) have agreed to pay a $1,955,000 civil penalty, perform environmental projects totaling more than $2 million, and spend an estimated $42 million in injunctive relief to resolve.

Comprehensive Data Collected from the Petroleum Refining Sector

EPA Pesticide Factsheets

On April 1, 2011 EPA sent a comprehensive industry-wide information collection request (ICR) to all facilities in the U.S. petroleum refining industry. EPA has received this ICR data and compiled these data into databases and spreadsheets for the web

Development Of Simulation Model For Fluid Catalytic Cracking

NASA Astrophysics Data System (ADS)

Ghosh, Sobhan

2010-10-01

Fluid Catalytic Cracking (FCC) is the most widely used secondary conversion process in the refining industry, for producing gasoline, olefins, and middle distillate from heavier petroleum fractions. There are more than 500 units in the world with a total processing capacity of about 17 to 20% of the crude capacity. FCC catalyst is the highest consumed catalyst in the process industry. On one hand, FCC is quite flexible with respect to it's ability to process wide variety of crudes with a flexible product yield pattern, and on the other hand, the interdependence of the major operating parameters makes the process extremely complex. An operating unit is self balancing and some fluctuations in the independent parameters are automatically adjusted by changing the temperatures and flow rates at different sections. However, a good simulation model is very useful to the refiner to get the best out of the process, in terms of selection of the best catalyst, to cope up with the day to day changing of the feed quality and the demands of different products from FCC unit. In addition, a good model is of great help in designing the process units and peripherals. A simple empirical model is often adequate to monitor the day to day operations, but they are not of any use in handling the other problems such as, catalyst selection or, design / modification of the plant. For this, a kinetic based rigorous model is required. Considering the complexity of the process, large number of chemical species undergoing "n" number of parallel and consecutive reactions, it is virtually impossible to develop a simulation model based on the kinetic parameters. The most common approach is to settle for a semi empirical model. We shall take up the key issues for developing a FCC model and the contribution of such models in the optimum operation of the plant.

40 CFR 261.3 - Definition of hazardous waste.

Code of Federal Regulations, 2014 CFR

2014-07-01

... discharged to the refinery oil recovery sewer before primary oil/water/solids separation—heat exchanger bundle cleaning sludge from the petroleum refining industry (EPA Hazardous Waste No. K050), crude oil... oil tank sediment and/or in-line filter/separation solids from petroleum refining operations (EPA...

40 CFR 261.3 - Definition of hazardous waste.

Code of Federal Regulations, 2012 CFR

2012-07-01

... discharged to the refinery oil recovery sewer before primary oil/water/solids separation—heat exchanger bundle cleaning sludge from the petroleum refining industry (EPA Hazardous Waste No. K050), crude oil... oil tank sediment and/or in-line filter/separation solids from petroleum refining operations (EPA...

40 CFR 261.3 - Definition of hazardous waste.

Code of Federal Regulations, 2013 CFR

2013-07-01

... discharged to the refinery oil recovery sewer before primary oil/water/solids separation—heat exchanger bundle cleaning sludge from the petroleum refining industry (EPA Hazardous Waste No. K050), crude oil... oil tank sediment and/or in-line filter/separation solids from petroleum refining operations (EPA...

Satisfaction of the Automotive Fleet Fuel Demand and Its Impact on the Oil Refining Industry

DOT National Transportation Integrated Search

1980-12-01

Because virtually all transportation fuels are based on petroleum, it is essential to include petroleum refining in any assessment of potential changes in the transportation system. A number of changes in the automotive fleet have been proposed to im...

Catalytic ozonation of p-chlorobenzoic acid by activated carbon and nickel supported activated carbon prepared from petroleum coke.

PubMed

Li, Xukai; Zhang, Qiuyun; Tang, Lili; Lu, Ping; Sun, Fengqiang; Li, Laisheng

2009-04-15

The aim of this research was to investigate catalytic activity of petroleum coke, activated carbon (AC) prepared from this material, Ni supported catalyst on activated carbon (Ni/AC) in the ozonation of aqueous phase p-chlorobenzoic acid (p-CBA). Activated carbon and Ni/AC catalyst were characterized by XRD and SEM. The presence of petroleum coke did not improve the degradation of p-CBA compared to ozonation alone, but it was advantageous for p-CBA mineralization (total organic carbon, TOC, reduction), indicating the generation of highly oxidant species (*OH) in the medium. The presence of either activated carbon or Ni/AC considerably improves TOC removal during p-CBA ozonation. Ni/AC catalyst shows the better catalytic activity and stability based on five repeated tests during p-CBA ozonation. During the ozonation (50 mg/h ozone flow rate) of a 10 mg/L p-CBA (pH 4.31), it can be more mineralized in the presence of Ni/AC catalyst (5.0 g/L), TOC removal rate is over 60% in 60 min, 43% using activated carbon as catalyst, only 30% with ozonation alone.

Monthly Petroleum Product Price Report, October 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1981-01-01

Data are reported on the prices of petroleum products for the period January 1980 through October 1981. The following products are included in the survey: gasoline, diesel fuels, residual fuels, aviation fuels, kerosene, liquefied petroleum gases heating oils, and No. 5 and No. 6 fuel oils. This report provides Congress and the public with information on monthly national weighted average prices for refined petroleum products. The data published are the primary source of price data for refined products for the refining, reselling, and retailing sectors necessary for the Department of Energy (DOE) to execute its role in monitoring prices. Inmore » addition, the data provide the information necessary for Congress, DOE, and the public to perform analyses and projections related to energy supplies, demands, and prices. Price data in this publication were collected from separate surveys. Average prices are derived from a survey of refiners, large resellers and/or retailers, and independent gas plant operators. Data from this monthly survey are available from July 1975. Average No. 2 heating oil prices were derived from a sample survey of refiners, resellers, and retailers who sell heating oil. The geographic coverage for this report is the 50 States and the District of Columbia.« less

Airborne concentrations of metals and total dust during solid catalyst loading and unloading operations at a petroleum refinery.

PubMed

Lewis, Ryan C; Gaffney, Shannon H; Le, Matthew H; Unice, Ken M; Paustenbach, Dennis J

2012-09-01

Workers handle catalysts extensively at petroleum refineries throughout the world each year; however, little information is available regarding the airborne concentrations and plausible exposures during this type of work. In this paper, we evaluated the airborne concentrations of 15 metals and total dust generated during solid catalyst loading and unloading operations at one of the largest petroleum refineries in the world using historical industrial hygiene samples collected between 1989 and 2006. The total dust and metals, which included aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, molybdenum, nickel, platinum, silicon, silver, vanadium, and zinc, were evaluated in relation to the handling of four different types of solid catalysts associated with three major types of catalytic processes. Consideration was given to the known components of the solid catalysts and any metals that were likely deposited onto them during use. A total of 180 analytical results were included in this analysis, representing 13 personal and 54 area samples. Of the long-term personal samples, airborne concentrations of metals ranged from <0.001 to 2.9mg/m(3), and, in all but one case, resulted in concentrations below the current U.S. Occupational Safety and Health Administration's Permissible Exposure Limits and the American Conference of Governmental Industrial Hygienists' Threshold Limit Values. The arithmetic mean total dust concentration resulting from long-term personal samples was 0.31mg/m(3). The data presented here are the most complete set of its kind in the open literature, and are useful for understanding the potential exposures during solid catalyst handling activities at this petroleum refinery and perhaps other modern refineries during the timeframe examined. Copyright © 2011 Elsevier GmbH. All rights reserved.

40 CFR 280.200 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the production of crude oil or other forms of petroleum (as defined in § 280.12) as well as the..., distillation, separation, conversion, upgrading, and finishing of refined petroleum or petroleum products. (3...

Hydroprocessing full-range of heavy oils and bitumen using ultradispersed catalysts at low severity

NASA Astrophysics Data System (ADS)

Peluso, Enzo

The progressive exhaustion of light crude oils is forcing the petroleum industry to explore new alternatives for the exploitation of unconventional oils. New approaches are searching for technologies able to produce, transport and refine these feedstocks at lower costs, in which symbiotic processes between the enhanced oil recovery (EOR) and the conventional upgrading technologies are under investigation. The process explored in this thesis is an interesting alternative for in-situ upgrading of these crude oils in the presence of ultradispersed (UD) catalysts, which are included as a disperse phase able to circulate along with the processed feed. The objectives of this work are: (a) study the performance of UD catalysts in the presence of a full range (non fractioned) heavy oil and bitumen and (b) evaluate the recyclability of the UD catalysts. Four different heavy crude oils were evaluated in the presence with UD catalysts at a total pressure of 2.8 MPa, residence time of 8 hours and reaction temperatures from 360 up to 400ºC. Thermal and catalytic hydro-processing were compared in terms of conversion and product stability. A comparison between the different crude oils was additionally derived in terms of SARA, initial micro-carbon content and virgin oil stability among other properties. Advantages of catalytic hydro-processing over thermal hydro-processing were evidenced, with UD catalysts playing an essential hydrogenating role while retarding coke formation; microcarbon and asphaltenes reduction in the presence of UD catalysts was observed. To evaluate the feasibility of recycling the UD catalysts, a micro-slurry recycled unit was developed as part of this research. These main results showed: (a) a successful design of this unit, (b) that temperature, LHSV and fractional recycling ratio have more impact on VGO conversion, while pressure has almost no effect, and (c) an UD catalysts agglomeration process was detected, however this process is slow and reversible.

Nitrogen Chemistry and Coke Transformation of FCC Coked Catalyst during the Regeneration Process

NASA Astrophysics Data System (ADS)

Shi, Junjun; Guan, Jianyu; Guo, Dawei; Zhang, Jiushun; France, Liam John; Wang, Lefu; Li, Xuehui

2016-06-01

Regeneration of the coked catalyst is an important process of fluid catalytic cracking (FCC) in petroleum refining, however, this process will emit environmentally harmful gases such as nitrogen and carbon oxides. Transformation of N and C containing compounds in industrial FCC coke under thermal decomposition was investigated via TPD and TPO to examine the evolved gaseous species and TGA, NMR and XPS to analyse the residual coke fraction. Two distinct regions of gas evolution are observed during TPD for the first time, and they arise from decomposition of aliphatic carbons and aromatic carbons. Three types of N species, pyrrolic N, pyridinic N and quaternary N are identified in the FCC coke, the former one is unstable and tends to be decomposed into pyridinic and quaternary N. Mechanisms of NO, CO and CO2 evolution during TPD are proposed and lattice oxygen is suggested to be an important oxygen resource. Regeneration process indicates that coke-C tends to preferentially oxidise compared with coke-N. Hence, new technology for promoting nitrogen-containing compounds conversion will benefit the in-situ reduction of NO by CO during FCC regeneration.

International energy annual 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-12-01

The International Energy Annual presents information and trends on world energy production and consumption for petroleum, natural gas, coal, and electricity. Production and consumption data are reported in standard units as well as British thermal units (Btu). Trade and reserves are shown for petroleum, natural gas, and coal. Data are provided on crude oil refining capacity and electricity installed capacity by type. Prices are included for selected crude oils and for refined petroleum products in selected countries. Population and Gross Domestic Product data are also provided.

Preparation and Characterization of NiMo/Al2O3Catalyst for Hydrocracking Processing

NASA Astrophysics Data System (ADS)

Widiyadi, Aditya; Guspiani, Gema Adil; Riady, Jeffry; Andreanto, Rikky; Chaiunnisa, Safina Dea; Widayat

2018-02-01

Hydrocracking is a chemical process used in petroleum refineries for converting high boiling hydrocarbons in petroleum crude oils to more valuable lower boiling products such as gasoline, kerosene, and diesel oil that operate at high temperature and pressure. Catalyst was used in hydrocracking to reduce temperature and pressure. Hydrocracking catalyst are composed of active components and support. Alumina is widely used in hydrocracking process as catalyst support due to its high surface area, high thermal stability, and low prices. The objective of this research was preparated NiMo/Al2O3 catalyst that used as hydrocracking catalyst. Catalyst was synthesized by wetness impregnation method and simple heating method with various kind of Al2O3. The physicochemical properties of catalyst were investigated by X-ray diffraction (XRD) to determine type of crystal and scanning electron microscopy (SEM) to determine morphology of the catalyst. The NiMo/Al2O3 catalyst prepared by aluminium potassium sulfate dodecahydrate exhibited the highest crystallinity of 90.23% and it is clear that MoO3 and NiO crystallites are highly dispersed on the NiMo/Al2O3 catalyst which indicates as the best catalyst. The catalytic activity in hydrocracking process was successfully examined to convert fatty acid into hydrocarbon.

Monthly petroleum-product price report. [January 1981 through June 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1982-06-01

Data are reported on the prices of petroleum products for the period January 1981 through June 1982. The following products are included in the survey: gasoline, diesel fuels, No. 1 and No. 2 heating oils, No. 5 and No. 6 fuel oils, aviation fuels, kerosene, and liquified petroleum gases. Prices are also indexed according to ultimate consumer. This report provides Congress and the pubilc with information on monthly national weighted average prices for refined petroleum products. The data published are the primary source of price data for refined products for the refining, reselling, and retailing sectors necessary for the Departmentmore » of Energy (DOE) to execute its role in monitoring prices. In addition, the data provide the information necessary for Congress, DOE, and the public to perform analyses and projections related to energy supplies, demands, and prices. Price data in this publication were collected from separate surveys. Average prices are derived from a survey of refiners, large resellers and/or retailers, and independent gas plant operators. The geographic coverage for this report is the 50 states and the District of Columbia. (DMC)« less

Monthly petroleum product price report. [January 1981-March 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Riner, C.

1982-03-01

Data are reported on the prices of petroleum products for the period January 1981 through March 1982. The following products are included in the survey: gasoline, diesel fuels, No. 1 and No. 2 heating oils, No. 5 and No. 6 fuel oils, aviation fuels, residual fuels, kerosene and liquefied petroleum gases. Prices are also indexed according to ultimate consumer. This report provides Congress and the public with information on monthly national weighted average prices for refined petroleum products. The data published are the primary source of price data for refined products for the refining, reselling, and retailing sectors necessary formore » the Department of Energy (DOE) to execute its role in monitoring prices. In addition, the data provide the information necessary for Congress, DOE, and the public to perform analyses and projections related to energy supplies, demands, and prices. Price data in this pubication were collected from separate surveys. Average prices are derived from a survey of refiners, large resellers and/or retailers, and independent gas plant operators. The geographic coverage for this report is the 50 states and the District of Columbia. (DMC)« less

Monthly petroleum product price report. [January 1981-May 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1982-05-01

Data are reported on the prices of petroleum products for the period January 1981 through May 1982. The following products are included in the survey: gasoline, diesel fuels, No. 1 and No. 2 heating oils, No. 5 and No. 6 fuel oils, aviation fuels, residual fuels, kerosene, and liquefied petroleum gases. Prices are also indexed according to ultimate consumer. This report provides Congress and the public with information on monthly national weighted average prices for refined petroleum products. The data published are the primary source of price data for refined products for the refining, reselling, and retailing sectors necessary formore » the Department of Energy (DOE) to execute its role in monitoring prices. In addition, the data provide the information necessary for Congress, DOE, and the public to perform analyses and projections related to energy supplies, demands, and prices. Price data in this publication were collected from separate surveys. Average prices are derived from a survey of refiners, large resellers and/or retailers, and independent gas plant operators. The geographic coverage for this report is the 50 states and the District of Columbia. (DMC)« less

Petroleum Market Model of the National Energy Modeling System. Part 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The purpose of this report is to define the objectives of the Petroleum Market Model (PMM), describe its basic approach, and provide detail on how it works. This report is intended as a reference document for model analysts, users, and the public. The PMM models petroleum refining activities, the marketing of petroleum products to consumption regions, the production of natural gas liquids in gas processing plants, and domestic methanol production. The PMM projects petroleum product prices and sources of supply for meeting petroleum product demand. The sources of supply include crude oil, both domestic and imported; other inputs including alcoholsmore » and ethers; natural gas plant liquids production; petroleum product imports; and refinery processing gain. In addition, the PMM estimates domestic refinery capacity expansion and fuel consumption. Product prices are estimated at the Census division level and much of the refining activity information is at the Petroleum Administration for Defense (PAD) District level.« less

Monthly petroleum product price report, November 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1982-03-03

This report provides Congress and the public with information on monthly national weighted average prices for refined petroleum products (motor gasoline, diesel fuels, residual fuel oils, aviation fuels, kerosene, petrochemical feedstocks, heating oils, and liquefied petroleum gases). The data published are the primary source of price data for refined products for the refining, reselling, and retailing sectors necessary for the Department of Energy to execute its role in monitoring prices. In addition, the data provide the information necessary for Congress, DOE, and the public to perform analyses and projections related to energy supplies, demands, and prices. Price data in thismore » publication were collected from separate surveys. Average prices are derived from a survey of refiners, large resellers and/or retailers, and independent gas plant operators. Data from this monthly survey are available from July 1975. Average No. 2 heating oil prices were derived from a sample survey of refiners, resellers, and retailers who sell heating oil. The geographic coverage for this report is the 50 states and the District of Columbia.« less

Monthly petroleum product price report, December 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1982-03-30

This report provides Congress and the public with information on monthly national weighted average prices for refined petroleum products (motor gasoline, diesel fuels, residual fuel oils, aviation fuels, kerosene, petrochemical feedstocks, heating oils, and liquefied petroleum gases). The data published are the primary source of price data for refined products for the refining, reselling, and retailing sectors necessary for the Department of Energy to execute its role in monitoring prices. In addition, the data provide the information necessary for Congress, DOE, and the public to perform analyses and projections related to energy supplies, demands, and prices. Price data in thismore » publication were collected from separate surveys. Average prices are derived from a survey of refiners, large resellers and/or retailers, and independent gas plant operators. Data from this monthly survey are available from July 1975. Average No. 2 heating oil prices were derived from a sample survey of refiners, resellers, and retailers who sell heating oil. The geographic coverage for this report is the 50 states and the District of Columbia.« less

Handbook of Petroleum Processing

NASA Astrophysics Data System (ADS)

Jones, David S. J.; Pujado, Peter P.

This handbook describes and discusses the features that make up the petroleum refining industry. It begins with a description of the crude oils and their nature, and continues with the saleable products from the refining processes, with a review of the environmental impact. There is a complete overview of the processes that make up the refinery with a brief history of those processes.

Updated estimation of energy efficiencies of U.S. petroleum refineries.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Palou-Rivera, I.; Wang, M. Q.

2010-12-08

Evaluation of life-cycle (or well-to-wheels, WTW) energy and emission impacts of vehicle/fuel systems requires energy use (or energy efficiencies) of energy processing or conversion activities. In most such studies, petroleum fuels are included. Thus, determination of energy efficiencies of petroleum refineries becomes a necessary step for life-cycle analyses of vehicle/fuel systems. Petroleum refinery energy efficiencies can then be used to determine the total amount of process energy use for refinery operation. Furthermore, since refineries produce multiple products, allocation of energy use and emissions associated with petroleum refineries to various petroleum products is needed for WTW analysis of individual fuels suchmore » as gasoline and diesel. In particular, GREET, the life-cycle model developed at Argonne National Laboratory with DOE sponsorship, compares energy use and emissions of various transportation fuels including gasoline and diesel. Energy use in petroleum refineries is key components of well-to-pump (WTP) energy use and emissions of gasoline and diesel. In GREET, petroleum refinery overall energy efficiencies are used to determine petroleum product specific energy efficiencies. Argonne has developed petroleum refining efficiencies from LP simulations of petroleum refineries and EIA survey data of petroleum refineries up to 2006 (see Wang, 2008). This memo documents Argonne's most recent update of petroleum refining efficiencies.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snowden-Swan, Lesley J.; Spies, Kurt A.; Lee, Guo-Shuh J.

Bio-oil from fast pyrolysis of biomass requires multi-stage catalytic hydroprocessing to produce hydrocarbon drop-in fuels. The current proposed process design involves fixed beds of ruthenium-based catalyst and conventional petroleum hydrotreating catalyst. Similar to petroleum processing, the catalyst is spent as a result of coking and other deactivation mechanisms, and must be changed out periodically. Biofuel life cycle greenhouse gas (GHG) assessments typically ignore the impact of catalyst consumed during fuel conversion as a result of limited lifetime, representing a data gap in the analyses. To help fill this data gap, life cycle GHGs were estimated for two representative examples ofmore » fast pyrolysis bio-oil hydrotreating catalyst, NiMo/Al2O3 and Ru/C, and integrated into the conversion-stage GHG analysis. Life cycle GHGs for the NiMo/Al2O3 and Ru/C catalysts are estimated at 5.5 and 81 kg CO2-e/kg catalyst, respectively. Contribution of catalyst consumption to total conversion-stage GHGs is 0.5% for NiMo/Al2O3 and 5% for Ru/C. This analysis does not consider secondary sourcing of metals for catalyst manufacture and therefore these are likely to be conservative estimates compared to applications where a spent catalyst recycler can be used.« less

Petroleum Technology: From Refinery To Home, Business, and Industry.

ERIC Educational Resources Information Center

Shewell, John A.

1997-01-01

Discusses the application of petroleum technology and presents activities designed to raise students' awareness of the importance of petroleum-based products in their lives. Includes a handout designed to help students understand the refining processes in which the crude oil from the drill site is transformed into nearly 6,000 petroleum-based…

EIA model documentation: Petroleum market model of the national energy modeling system

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-12-28

The purpose of this report is to define the objectives of the Petroleum Market Model (PMM), describe its basic approach, and provide detail on how it works. This report is intended as a reference document for model analysts, users, and the public. Documentation of the model is in accordance with EIA`s legal obligation to provide adequate documentation in support of its models. The PMM models petroleum refining activities, the marketing of petroleum products to consumption regions, the production of natural gas liquids in gas processing plants, and domestic methanol production. The PMM projects petroleum product prices and sources of supplymore » for meeting petroleum product demand. The sources of supply include crude oil, both domestic and imported; other inputs including alcohols and ethers; natural gas plant liquids production; petroleum product imports; and refinery processing gain. In addition, the PMM estimates domestic refinery capacity expansion and fuel consumption. Product prices are estimated at the Census division level and much of the refining activity information is at the Petroleum Administration for Defense (PAD) District level.« less

Monthly petroleum product price report. [January 1981-January 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Riner, C.

1982-01-01

This report provides information on monthly national weighted average prices for refined petroleum products. The data published are the primary source of price data for refined products for the refining, reselling, and retailing sectors necessary for the Department of Energy (DOE) to execute its role in monitoring prices. In addition, the data provide the information necessary for Congress, DOE, and the public to perform analyses and projections related to energy supplies, demands, and prices. Price data in this publication were collected from separate surveys. Average prices are derived from a survey of refiners, large resellers and/or retailers, and independent gasmore » plant operators. Data from this monthly survey are available from July 1975. Average No. 2 heating oil prices were derived from a sample survey of refiners, resellers, and retailers who sell heating oil. The geographic coverage for this report is the 50 states and the District of Columbia. Data are presented on the following: gasoline, No. 1 and No. 2 diesel fuels, No. 1 and No. 2 heating oils, residual fuel oil, aviation fuels, kerosene, and liquefied petroleum gases.« less

Monthly petroleum product price report. [January 1981-February 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Riner, C.

1982-02-01

This report provides information on monthly national weighted average prices for refined petroleum products. The data published are the primary source of price data for refined products for the refining, reselling, and retailing sectors necessary for the Department of Energy (DOE) to execute its role in monitoring prices. In addition, the data provide the information necessary for Congress, DOE, and the public to perform analyses and projections related to energy supplies, demands, and prices. Price data in this publication were collected from separate surveys. Average prices are derived from a survey of refiners, large resellers and/or retailers, and independent gasmore » plant operators. Data from this monthly survey are available from July 1975. Average No. 2 heating oil prices were derived from a sample survey of refiners, resellers, and retailers who sell heating oil. The geographic coverage for this report is the 50 states and the District of Columbia. Data are presented on the following: gasoline, No. 1 and No. 2 diesel fuels, No. 1 and No. 2 heating oils, residual fuel oil, aviation fuels, kerosene, and liquefied petroleum gases.« less

Fundamentals of Petroleum.

ERIC Educational Resources Information Center

Bureau of Naval Personnel, Washington, DC.

Basic information on petroleum is presented in this book prepared for naval logistics officers. Petroleum in national defense is discussed in connection with consumption statistics, productive capacity, world's resources, and steps in logistics. Chemical and geological analyses are made in efforts to familiarize methods of refining, measuring,…

10 CFR 626.7 - Royalty transfer and exchange.

Code of Federal Regulations, 2011 CFR

2011-01-01

... DEPARTMENT OF ENERGY (CONTINUED) SALES REGULATION PROCEDURES FOR ACQUISITION OF PETROLEUM FOR THE STRATEGIC PETROLEUM RESERVE § 626.7 Royalty transfer and exchange. (a) General. DOE shall conduct royalty transfers... supply or refining capability, logistical problems for moving petroleum products, macroeconomic factors...

Econometrics of joint production: another approach. [Petroleum refining and petrochemicals production

DOE Office of Scientific and Technical Information (OSTI.GOV)

Griffin, J.M.

1977-11-01

The pseudo data approach to the joint production of petroleum refining and chemicals is described as an alternative that avoids the multicollinearity of time series data and allows a complex technology to be characterized in a statistical price possibility frontier. Intended primarily for long-range analysis, the pseudo data method can be used as a source of elasticity estimate for policy analysis. 19 references.

Thermal and catalytic coprocessing of coal and waste materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Orr, E.C.; Tuntawiroon, W.; Ding, W.B.

1995-12-31

Coprocessing of coal with waste materials to produce liquid fuels with emphasis on finding reasonable reaction pathways and catalysts for such processing is presently the subject of intensive investigation. Polymer wastes such as polyethylene, polystyrene, polypropylene and used rubber tires are not naturally degraded over time. More than 22 million tons of plastic waste are annually discarded in landfills and over 75 percent of used rubber tires are similarly treated. In order to obtain distillate liquids or petroleum compatible refined products from coal, addition of hydrogen is necessary. A possible method for hydrogen addition is coprocessing of coal with polymericmore » waste materials since these latter materials contain hydrogen at levels much higher than are found in coal. The breakdown of waste rubber tires is interesting because the liquids derived may prove to be important as a coal dissolution and/or hydrogen donor solvent. Recently, Badger and coworkers reported that hydrogenated tire oils (hydrogenated in the presence of CoMo catalyst) were effective for the dissolution of coal. Studies on the coprocessing of coal and waste materials have only recently been done intensively. Limited data are available on reaction conditions and catalytic effects for processing coal mixed with post-consumer wastes. The purpose of the present study was to determine the effects of reaction temperature, pressure, catalysts, and mixture ratio on the coprocessing of coal and waste materials.« less

10 CFR 626.6 - Acquiring oil by direct purchase.

Code of Federal Regulations, 2014 CFR

2014-01-01

... or refining capability, logistical problems for moving petroleum products, macroeconomic factors, and... capability, logistical problems for moving petroleum products, macroeconomic factors, and any other...

10 CFR 626.6 - Acquiring oil by direct purchase.

Code of Federal Regulations, 2012 CFR

2012-01-01

... or refining capability, logistical problems for moving petroleum products, macroeconomic factors, and... capability, logistical problems for moving petroleum products, macroeconomic factors, and any other...

10 CFR 626.6 - Acquiring oil by direct purchase.

Code of Federal Regulations, 2013 CFR

2013-01-01

... or refining capability, logistical problems for moving petroleum products, macroeconomic factors, and... capability, logistical problems for moving petroleum products, macroeconomic factors, and any other...

Catalyst Residence Time Distributions in Riser Reactors for Catalytic Fast Pyrolysis. Part 2: Pilot-Scale Simulations and Operational Parameter Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Foust, Thomas D.; Ziegler, Jack L.; Pannala, Sreekanth

2017-02-21

Here, wsing the validated simulation model developed in part one of this study for biomass catalytic fast pyrolysis (CFP), we assess the functional utility of using this validated model to assist in the development of CFP processes in fluidized catalytic cracking (FCC) reactors to a commercially viable state. Specifically, we examine the effects of mass flow rates, boundary conditions (BCs), pyrolysis vapor molecular weight variation, and the impact of the chemical cracking kinetics on the catalyst residence times. The factors that had the largest impact on the catalyst residence time included the feed stock molecular weight and the degree ofmore » chemical cracking as controlled by the catalyst activity. Lastly, because FCC reactors have primarily been developed and utilized for petroleum cracking, we perform a comparison analysis of CFP with petroleum and show the operating regimes are fundamentally different.« less

10 CFR 626.6 - Acquiring oil by direct purchase.

Code of Federal Regulations, 2011 CFR

2011-01-01

... Energy DEPARTMENT OF ENERGY (CONTINUED) SALES REGULATION PROCEDURES FOR ACQUISITION OF PETROLEUM FOR THE STRATEGIC PETROLEUM RESERVE § 626.6 Acquiring oil by direct purchase. (a) General. For the direct purchase... or refining capability, logistical problems for moving petroleum products, macroeconomic factors, and...

Towards an understanding of the role of clay minerals in crude oil formation, migration and accumulation

NASA Astrophysics Data System (ADS)

Wu, Lin Mei; Zhou, Chun Hui; Keeling, John; Tong, Dong Shen; Yu, Wei Hua

2012-12-01

This article reviews progress in the understanding of the role of clay minerals in crude oil formation, migration and accumulation. Clay minerals are involved in the formation of kerogen, catalytic cracking of kerogen into petroleum hydrocarbon, the migration of crude oil, and the continued change to hydrocarbon composition in underground petroleum reservoirs. In kerogen formation, clay minerals act as catalysts and sorbents to immobilize organic matter through ligand exchange, hydrophobic interactions and cation bridges by the mechanisms of Maillard reactions, polyphenol theory, selective preservation and sorptive protection. Clay minerals also serve as catalysts in acid-catalyzed cracking of kerogen into petroleum hydrocarbon through Lewis and Brønsted acid sites on the clay surface. The amount and type of clay mineral affect the composition of the petroleum. Brønsted acidity of clay minerals is affected by the presence and state of interlayer water, and displacement of this water is a probable driver in crude oil migration from source rocks. During crude oil migration and accumulation in reservoirs, the composition of petroleum is continually modified by interaction with clay minerals. The clays continue to function as sorbents and catalysts even while they are being transformed by diagenetic processes. The detail of chemical interactions and reaction mechanisms between clay minerals and crude oil formation remains to be fully explained but promises to provide insights with broader application, including catalytic conversion of biomass as a source of sustainable energy into the future.

Nitrogen Chemistry and Coke Transformation of FCC Coked Catalyst during the Regeneration Process

PubMed Central

Shi, Junjun; Guan, Jianyu; Guo, Dawei; Zhang, Jiushun; France, Liam John; Wang, Lefu; Li, Xuehui

2016-01-01

Regeneration of the coked catalyst is an important process of fluid catalytic cracking (FCC) in petroleum refining, however, this process will emit environmentally harmful gases such as nitrogen and carbon oxides. Transformation of N and C containing compounds in industrial FCC coke under thermal decomposition was investigated via TPD and TPO to examine the evolved gaseous species and TGA, NMR and XPS to analyse the residual coke fraction. Two distinct regions of gas evolution are observed during TPD for the first time, and they arise from decomposition of aliphatic carbons and aromatic carbons. Three types of N species, pyrrolic N, pyridinic N and quaternary N are identified in the FCC coke, the former one is unstable and tends to be decomposed into pyridinic and quaternary N. Mechanisms of NO, CO and CO2 evolution during TPD are proposed and lattice oxygen is suggested to be an important oxygen resource. Regeneration process indicates that coke-C tends to preferentially oxidise compared with coke-N. Hence, new technology for promoting nitrogen-containing compounds conversion will benefit the in-situ reduction of NO by CO during FCC regeneration. PMID:27270486

Petroleum and individual polycyclic aromatic hydrocarbons

USGS Publications Warehouse

Albers, Peter H.; Hoffman, David J.; Rattner, Barnett A.; Burton, G. Allen; Cairns, John

1995-01-01

Crude petroleum, refined-petroleum products, and individual polycyclic aromatic hydrocarbons (PAHs) contained within petroleum are found throughout the world. their presence has been detected in living and nonliving components of ecosystems. Petroleum can be an environmental hazard for wild animals and plants. Individual PAHs are also hazardous to wildlife, but they are most commonly associated with human illnesses. Because petroleum is a major environmental source of these PAHs, petroleum and PAHs are jointly presented in this chapter. Composition, sources, environmental fate, and toxic effects on all living components of aquatic and terrestrial environments are addessed.

Identification of refined petroleum products in contaminated soils using an identification index for GC chromatograms.

PubMed

Kwon, Dongwook; Ko, Myoung-Soo; Yang, Jung-Seok; Kwon, Man Jae; Lee, Seung-Woo; Lee, Seunghak

2015-08-01

Hydrocarbons found in the environment are typically characterized by gas chromatography (GC). The shape of the GC chromatogram has been used to identify the source of petroleum contamination. However, the conventional practice of simply comparing the peak patterns of source products to those of environmental samples is dependent on the subjective decisions of individual analysts. We have developed and verified a quantitative analytical method for interpreting GC chromatograms to distinguish refined petroleum products in contaminated soils. We found that chromatograms for gasoline, kerosene, and diesel could be divided into three ranges with boundaries at C6, C8, C16, and C26. In addition, the relative peak area (RPA(GC)) of each range, a dimensionless ratio of the peak area within each range to that of the total range (C6-C26), had a unique value for each petroleum product. An identification index for GC chromatograms (ID(GC)), defined as the ratio of RPA(GC) of C8-C16 to that of C16-C26, was able to identify diesel and kerosene sources in samples extracted from artificially contaminated soils even after weathering. Thus, the ID(GC) can be used to effectively distinguish between refined petroleum products in contaminated soils.

Pt-based Bi-metallic Monolith Catalysts for Partial Upgrading of Microalgae Oil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lawal, Adeniyi; Manganaro, James; Goodall, Brian

Valicor’s proprietary wet extraction process in conjunction with thermochemical pre-treatment was performed on algal biomass from two different algae strains, Nannochloropsis Salina (N.S.) and Chlorella to produce algae oils. Polar lipids such as phospholipids were hydrolyzed, and metals and metalloids, known catalyst poisons, were separated into the aqueous phase, creating an attractive “pre-refined” oil for hydrodeoxygenation (HDO) upgrading by Stevens. Oil content and oil extraction efficiency of approximately 30 and 90% respectively were achieved. At Stevens, we formulated a Pt-based bi-metallic catalyst which was demonstrated to be effective in the hydro-treating of the algae oils to produce ‘green’ diesel. Themore » bi-metallic catalyst was wash-coated on a monolith, and in conjunction with a high throughput high pressure (pilot plant) reactor system, was used in hydrotreating algae oils from N.S. and Chlorella. Mixtures of these algae oils and refinery light atmospheric gas oil (LAGO) supplied by our petroleum refiner partner, Marathon Petroleum Corporation, were co-processed in the pilot plant reactor system using the Pt-based bi-metallic monolith catalyst. A 26 wt% N.S. algae oil/74 wt % LAGO mixture hydrotreated in the reactor system was subjected to the ASTM D975 Diesel Fuel Specification Test and it met all the important requirements, including a cetane index of 50.5. An elemental oxygen analysis performed by an independent and reputable lab reported an oxygen content of trace to none found. The successful co-processing of a mixture of algae oil and LAGO will enable integration of algae oil as a refinery feedstock which is one of the goals of DOE-BETO. We have presented experimental data that show that our precious metal-based catalysts consume less hydrogen than the conventional hydrotreating catalyst NiMo Precious metal catalysts favor the hydrodecarbonylation/hydrodecarboxylation route of HDO over the dehydration route preferred by base metal catalysts, and consumes less hydrogen, if methanation can be mitigated. Our methanation data on Pt and Rh indicate effective suppression of methanation. Our data also show that our catalysts are less susceptible to coking; and unlike NiMo and CoMo, precious metal catalysts are not deactivated by water, a by-product of HDO of algae oil. Finally, our catalysts do not need to be sulfided to be active. A rigorous techno-economic analysis of our process for commercial scale production of 10,000 barrels per day of hydrotreated algae oil, with nutraceuticals co-product claiming only 0.05% of the raw algae oil, indicates an estimated plant gate price of ~$10/gal. Sensitivity analysis shows that critical parameters affecting sale price include (1) algae doubling time (2) biomass oil content (3) CAPEX, and (4) moisture content of post extracted algae residue. Modest improvements in these areas will result in enhanced and competitive economics. Based on a life cycle assessment for greenhouse gas emission, we found that if algae oil replaced 10% of the US consumption, this would result in a CO2e reduction of 210,000 tons per day. Improving the drying process for animal feed by 50% would result in further significant reduction in CO2e.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effectsmore » of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and electrostatic precipitator (ESP) fly ash collection efficiency.« less

Synthesis and Stabilization of Supported Metal Catalysts by Atomic Layer Deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, Junling; Elam, Jeffrey W.; Stair, Peter C.

2013-03-12

Supported metal nanoparticles are among the most important cata-lysts for many practical reactions, including petroleum refining, automobile exhaust treatment, and Fischer–Tropsch synthesis. The catalytic performance strongly depends on the size, composition, and structure of the metal nanoparticles, as well as the underlying support. Scientists have used conventional synthesis methods including impregnation, ion exchange, and deposition–precipitation to control and tune these factors, to establish structure–performance relationships, and to develop better catalysts. Meanwhile, chemists have improved the stability of metal nanoparticles against sintering by the application of protective layers, such as polymers and oxides that encapsulate the metal particle. This often leadsmore » to decreased catalytic activity due to a lack of precise control over the thickness of the protective layer. A promising method of catalyst synthesis is atomic layer deposition (ALD). ALD is a variation on chemical vapor deposition in which metals, oxides, and other materials are deposited on surfaces by a sequence of self-limiting reactions. The self-limiting character of these reactions makes it possible to achieve uniform deposits on high-surface-area porous solids. Therefore, design and synthesis of advanced catalysts on the nanoscale becomes possible through precise control over the structure and composition of the underlying support, the catalytic active sites, and the protective layer. In this Account, we describe our advances in the synthesis and stabilization of supported metal catalysts by ALD. After a short introduction to the technique of ALD, we show several strategies for metal catalyst synthesis by ALD that take advantage of its self-limiting feature. Monometallic and bimetallic catalysts with precise control over the metal particle size, composition, and structure were achieved by combining ALD sequences, surface treatments, and deposition temperature control. Next, we describe ALD oxide overcoats applied with atomically precise thickness control that stabilize metal catalysts while preserving their catalytic function. We also discuss strategies for generation and control over the porosity of the overcoats that allow the embedded metal particles to remain accessible by reactants, and the details for ALD alumina overcoats on metal catalysts. Moreover, using methanol decomposition and oxidative dehydrogenation of ethane as probe reactions, we demonstrate that selectively blocking low coordination metal sites by oxide overcoats can provide another strategy to enhance both the durability and selectivity of metal catalysts.« less

10 CFR 625.2 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-01-01

.... Petroleum means crude oil, residual fuel oil or any refined petroleum product (including any natural gas liquid and any natural gas liquid product) owned or contracted for by DOE and in storage in any permanent...

10 CFR 625.2 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-01-01

.... Petroleum means crude oil, residual fuel oil or any refined petroleum product (including any natural gas liquid and any natural gas liquid product) owned or contracted for by DOE and in storage in any permanent...

10 CFR 625.2 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-01-01

.... Petroleum means crude oil, residual fuel oil or any refined petroleum product (including any natural gas liquid and any natural gas liquid product) owned or contracted for by DOE and in storage in any permanent...

10 CFR 625.2 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-01-01

.... Petroleum means crude oil, residual fuel oil or any refined petroleum product (including any natural gas liquid and any natural gas liquid product) owned or contracted for by DOE and in storage in any permanent...

10 CFR 625.2 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-01-01

.... Petroleum means crude oil, residual fuel oil or any refined petroleum product (including any natural gas liquid and any natural gas liquid product) owned or contracted for by DOE and in storage in any permanent...

A historical review of additives and modifiers used in paving asphalt refining processes in the United States.

PubMed

Mundt, Diane J; Adams, Robert C; Marano, Kristin M

2009-11-01

The U.S. asphalt paving industry has evolved over time to meet various performance specifications for liquid petroleum asphalt binder (known as bitumen outside the United States). Additives to liquid petroleum asphalt produced in the refinery may affect exposures to workers in the hot mix paving industry. This investigation documented the changes in the composition and distribution of the liquid petroleum asphalt products produced from petroleum refining in the United States since World War II. This assessment was accomplished by reviewing documents and interviewing individual experts in the industry to identify current and historical practices. Individuals from 18 facilities were surveyed; the number of facilities reporting use of any material within a particular class ranged from none to more than half the respondents. Materials such as products of the process stream, polymers, elastomers, and anti-strip compounds have been added to liquid petroleum asphalt in the United States over the past 50 years, but modification has not been generally consistent by geography or time. Modifications made to liquid petroleum asphalt were made generally to improve performance and were dictated by state specifications.

Synthetic Zeolites and Other Microporous Oxide Molecular Sieves

NASA Astrophysics Data System (ADS)

Sherman, John D.

1999-03-01

Use of synthetic zeolites and other microporous oxides since 1950 has improved insulated windows, automobile air-conditioning, refrigerators, air brakes on trucks, laundry detergents, etc. Their large internal pore volumes, molecular-size pores, regularity of crystal structures, and the diverse framework chemical compositions allow "tailoring" of structure and properties. Thus, highly active and selective catalysts as well as adsorbents and ion exchangers with high capacities and selectivities were developed. In the petroleum refining and petrochemical industries, zeolites have made possible cheaper and lead-free gasoline, higher performance and lower-cost synthetic fibers and plastics, and many improvements in process efficiency and quality and in performance. Zeolites also help protect the environment by improving energy efficiency, reducing automobile exhaust and other emissions, cleaning up hazardous wastes (including the Three Mile Island nuclear power plant and other radioactive wastes), and, as specially tailored desiccants, facilitating the substitution of new refrigerants for the ozone-depleting chlorofluorocarbons banned by the Montreal Protocol.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aegerter, P.A.

Phillips Petroleum Company scientists and engineers have been operating petroleum refining and separations pilot plants for five years in the Process Development Center. The 26 pilot plants in this building, with one exception, operate under complete computer-control, allowing maximum utilization of limited operating manpower. This centralization and automation of pilot plants has allowed Phillips to more than double the number of operating pilot plants in the petroleum refining area without an increase in manpower. At the same time, the quantity and quality of data has increased correspondingly. This paper discusses Phillips philosophy of operation and management of these pilot plants.more » In addition, details of day-to-day operations and a brief description of the control system are also presented.« less

Discovery of optimal zeolites for challenging separations and chemical conversions through predictive materials modeling

NASA Astrophysics Data System (ADS)

Siepmann, J. Ilja; Bai, Peng; Tsapatsis, Michael; Knight, Chris; Deem, Michael W.

2015-03-01

Zeolites play numerous important roles in modern petroleum refineries and have the potential to advance the production of fuels and chemical feedstocks from renewable resources. The performance of a zeolite as separation medium and catalyst depends on its framework structure and the type or location of active sites. To date, 213 framework types have been synthesized and >330000 thermodynamically accessible zeolite structures have been predicted. Hence, identification of optimal zeolites for a given application from the large pool of candidate structures is attractive for accelerating the pace of materials discovery. Here we identify, through a large-scale, multi-step computational screening process, promising zeolite structures for two energy-related applications: the purification of ethanol beyond the ethanol/water azeotropic concentration in a single separation step from fermentation broths and the hydroisomerization of alkanes with 18-30 carbon atoms encountered in petroleum refining. These results demonstrate that predictive modeling and data-driven science can now be applied to solve some of the most challenging separation problems involving highly non-ideal mixtures and highly articulated compounds. Financial support from the Department of Energy Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences under Award DE-FG02-12ER16362 is gratefully acknowledged.

Bio-dissolution of Ni, V and Mo from spent petroleum catalyst using iron oxidizing bacteria.

PubMed

Pradhan, Debabrata; Kim, Dong J; Roychaudhury, Gautam; Lee, Seoung W

2010-01-01

Bioleaching studies of spent petroleum catalyst containing Ni, V and Mo were carried out using iron oxidizing bacteria. Various leaching parameters such as Fe(II) concentration, pulp density, pH, temperature and particle size were studied to evaluate their effects on the leaching efficiency as well as the kinetics of dissolution. The percentage of leaching of Ni and V were higher than Mo. The leaching process followed a diffusion controlled model and the product layer was observed to be impervious due to formation of ammonium jarosite (NH(4))Fe(3)(SO(4))(2)(OH)(6). Apart from this, the lower leaching efficiency of Mo was due to a hydrophobic coating of elemental sulfur over Mo matrix in the spent catalyst. The diffusivities of the attacking species for Ni, V and Mo were also calculated.

Report to Congress on the feasibility of establishing a heating oil component to the Strategic Petroleum Reserve. Volume 2: Appendices

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Nine appendices to the main report are included in this volume. They are: Northeastern US distillate supply systems; New England fuel oil storage capacities and inventories; Characteristics of the northeast natural gas market; Documentation of statistical models and calculation of benefits; Regional product reserve study; Other countries` experience with refined product storage; Global refining supply demand appraisal; Summary of federal authorities relevant to the establishment of petroleum product reserves; Product stability and turnover requirements.

Catalytic ozonation of petroleum refinery wastewater utilizing Mn-Fe-Cu/Al2O 3 catalyst.

PubMed

Chen, Chunmao; Yoza, Brandon A; Wang, Yandan; Wang, Ping; Li, Qing X; Guo, Shaohui; Yan, Guangxu

2015-04-01

There is of great interest to develop an economic and high-efficient catalytic ozonation system (COS) for the treatment of biologically refractory wastewaters. Applications of COS require options of commercially feasible catalysts. Experiments in the present study were designed to prepare and investigate a novel manganese-iron-copper oxide-supported alumina-assisted COS (Mn-Fe-Cu/Al2O3-COS) for the pretreatment of petroleum refinery wastewater. The highly dispersed composite metal oxides on the catalyst surface greatly promoted the performance of catalytic ozonation. Hydroxyl radical mediated oxidation is a dominant reaction in Mn-Fe-Cu/Al2O3-COS. Mn-Fe-Cu/Al2O3-COS enhanced COD removal by 32.7% compared with a single ozonation system and by 8-16% compared with Mn-Fe/Al2O3-COS, Mn-Cu/Al2O3-COS, and Fe-Cu/Al2O3-COS. The O/C and H/C ratios of oxygen-containing polar compounds significantly increased after catalytic ozonation, and the biodegradability of petroleum refinery wastewater was significantly improved. This study illustrates potential applications of Mn-Fe-Cu/Al2O3-COS for pretreatment of biologically refractory wastewaters.

40 CFR 80.92 - Baseline auditor requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... total of more than 10 percent of its net worth with the refiner or importer; nor (iii) Receive... determination. It shall have personnel familiar with petroleum refining processes, including associated... worked at least five (5) years in either refinery operations or as a consultant for the refining industry...

40 CFR 80.92 - Baseline auditor requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... total of more than 10 percent of its net worth with the refiner or importer; nor (iii) Receive... determination. It shall have personnel familiar with petroleum refining processes, including associated... worked at least five (5) years in either refinery operations or as a consultant for the refining industry...

40 CFR 80.92 - Baseline auditor requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... total of more than 10 percent of its net worth with the refiner or importer; nor (iii) Receive... determination. It shall have personnel familiar with petroleum refining processes, including associated... worked at least five (5) years in either refinery operations or as a consultant for the refining industry...

Bioleaching of metals from spent refinery petroleum catalyst using moderately thermophilic bacteria: effect of particle size.

PubMed

Srichandan, Haragobinda; Singh, Sradhanjali; Pathak, Ashish; Kim, Dong-Jin; Lee, Seoung-Won; Heyes, Graeme

2014-01-01

The present work investigated the leaching potential of moderately thermophilic bacteria in the recovery of metals from spent petroleum catalyst of varying particle sizes. The batch bioleaching experiments were conducted by employing a mixed consortium of moderate thermophilic bacteria at 45°C and by using five different particle sizes (from 45 to >2000 μm) of acetone-washed spent catalyst. The elemental mapping by FESEM confirmed the presence of Al, Ni, V and Mo along with sulfur in the spent catalyst. During bioleaching, Ni (92-97%) and V (81-91%) were leached in higher concentrations, whereas leaching yields of Al (23-38%) were found to be lowest in all particle sizes investigated. Decreasing the particle size from >2000 μm to 45-106 μm caused an increase in leaching yields of metals during initial hours. However, the final metals leaching yields were almost independent of particle sizes of catalyst. Leaching kinetics was observed to follow the diffusion-controlled model showing the linearity more close than the chemical control. The results of the present study suggested that bioleaching using moderate thermophilic bacteria was highly effective in removing the metals from spent catalyst. Moreover, bioleaching can be conducted using spent catalyst of higher particle size (>2000 μm), thus saving the grinding cost and making process attractive for larger scale application.

Identification of unresolved complex mixtures (UCMs) of hydrocarbons in commercial fish oil supplements.

PubMed

Reid, Anna-Jean M; Budge, Suzanne M

2015-01-01

Heightened awareness of the health benefits of fish oil consumption has led to a great increase in the number of fish oil supplements available to the consumer. Therefore manufacturers are continually looking for ways to distinguish their products from those of competitors. Minimally refined or virgin fish oils provide a unique feature; however, petroleum hydrocarbon contamination from oil spills is a reality in the world's oceans. The question arises whether oil produced from fish species caught in these polluted areas is free of petroleum hydrocarbons, with particular interest in unresolved complex mixtures (UCMs). This study investigates the presence of UCMs in commercially available fish oil supplements advertised as being virgin, as well as refined. Weathered petroleum hydrocarbons in the form of a UCM were found at 523 µg g(-1) in a virgin Alaskan salmon oil supplement. Supplements that were refined were free of this contamination. Fish used in the production of fish oil supplements appear to have accumulated petrogenic hydrocarbons in their tissues which were not removed by minimal oil refining. Further study is required to determine if there are any health implications associated with long-term consumption of these contaminated supplements. © 2014 Society of Chemical Industry.

Petroleum Refining Industry Final Air Toxics Rule Fact Sheets

EPA Pesticide Factsheets

This page contains a July 1995 fact sheet for the final NESHAP for Petroleum Refineries. This page also contains a June 2013 fact sheet with information regarding the final amendments to the 2013 final rule for the NESHAP.

Petroleum Market Model of the National Energy Modeling System

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1997-01-01

The purpose of this report is to define the objectives of the Petroleum Market Model (PMM), describe its basic approach, and provide detail on how it works. This report is intended as a reference document for model analysts, users, and the public. The PMM models petroleum refining activities, the marketing of petroleum products to consumption regions. The production of natural gas liquids in gas processing plants, and domestic methanol production. The PMM projects petroleum product prices and sources of supply for meeting petroleum product demand. The sources of supply include crude oil, both domestic and imported; other inputs including alcoholsmore » and ethers; natural gas plant liquids production; petroleum product imports; and refinery processing gain. In addition, the PMM estimates domestic refinery capacity expansion and fuel consumption. Product prices are estimated at the Census division level and much of the refining activity information is at the Petroleum Administration for Defense (PAD) District level. This report is organized as follows: Chapter 2, Model Purpose; Chapter 3, Model Overview and Rationale; Chapter 4, Model Structure; Appendix A, Inventory of Input Data, Parameter Estimates, and Model Outputs; Appendix B, Detailed Mathematical Description of the Model; Appendix C, Bibliography; Appendix D, Model Abstract; Appendix E, Data Quality; Appendix F, Estimation methodologies; Appendix G, Matrix Generator documentation; Appendix H, Historical Data Processing; and Appendix I, Biofuels Supply Submodule.« less

Downstream Petroleum Mergers and Acquisitions by U.S. Major Oil Companies

EIA Publications

2009-01-01

A summary presentation of mergers and acquisitions by U.S. major oil companies (including the U.S. affiliates of foreign major oil companies). The presentation focuses on petroleum refining over the last several years through late 2009.

Monthly petroleum-product price report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1982-07-01

This report provides Congress and the public with information on monthly national weighted average prices for refined petroleum products. the data published are the primary source of price data for refined products for the refining, reselling, and retailing sectors necessary for the Department of Energy (DOE) to execute its role in monitoring prices. In addition, the data provide the information necessary for Congress, DOE, and the public to perform analyses and projections related to energy supplies, demands, and prices. The legislative authority for this survey is the Federal Energy Administration Act of 1974 (PL 93-275). Price data in this publicationmore » were collected fronm separate surveys. Average prices are derived from a survey of refiners, large resellers and/or retailers, and independent gas plant operators. Data from this monthly survey are available from July 1975. Average No. 2 heating oil prices were derived from a sample survye of refiners, resellers, and retailers who sell heating oil. The geographic coverage for this report is the 50 states and the District of Columbia.« less

Washington State petroleum markets data book. [Contains Glossary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lagerberg, B.; Anderson, M.

1992-01-01

The Data Book is a resource for policymakers and analysis who work on energy issues. It is also for Washington citizens who are interested in knowing more about the role petroleum plays in Washington State. The Data Book is organized into four parts and four appendixes. Each part discusses a particular aspect of the petroleum market: supply (crude and refined products, refinery production, and distribution); consumption (by sector and by fuel); prices (crude and refined products, spot and transaction, wholesale and retail); and reliability of supply (stocks, reserves, emergencies, and the environment). Each part is followed by tables of supportingmore » data. The appendixes contain related and supporting tables, a glossary of technical terms, and a list of the sources of data for each part of the book.« less

Electrochemical catalyst recovery method

DOEpatents

Silva, L.J.; Bray, L.A.

1995-05-30

A method of recovering catalyst material from latent catalyst material solids includes: (a) combining latent catalyst material solids with a liquid acid anolyte solution and a redox material which is soluble in the acid anolyte solution to form a mixture; (b) electrochemically oxidizing the redox material within the mixture into a dissolved oxidant, the oxidant having a potential for oxidation which is effectively higher than that of the latent catalyst material; (c) reacting the oxidant with the latent catalyst material to oxidize the latent catalyst material into at least one oxidized catalyst species which is soluble within the mixture and to reduce the oxidant back into dissolved redox material; and (d) recovering catalyst material from the oxidized catalyst species of the mixture. The invention is expected to be particularly useful in recovering spent catalyst material from petroleum hydroprocessing reaction waste products having adhered sulfides, carbon, hydrocarbons, and undesired metals, and as well as in other industrial applications. 3 figs.

Electrochemical catalyst recovery method

DOEpatents

Silva, Laura J.; Bray, Lane A.

1995-01-01

A method of recovering catalyst material from latent catalyst material solids includes: a) combining latent catalyst material solids with a liquid acid anolyte solution and a redox material which is soluble in the acid anolyte solution to form a mixture; b) electrochemically oxidizing the redox material within the mixture into a dissolved oxidant, the oxidant having a potential for oxidation which is effectively higher than that of the latent catalyst material; c) reacting the oxidant with the latent catalyst material to oxidize the latent catalyst material into at least one oxidized catalyst species which is soluble within the mixture and to reduce the oxidant back into dissolved redox material; and d) recovering catalyst material from the oxidized catalyst species of the mixture. The invention is expected to be particularly useful in recovering spent catalyst material from petroleum hydroprocessing reaction waste products having adhered sulfides, carbon, hydrocarbons, and undesired metals, and as well as in other industrial applications.

77 FR 13313 - Agency Information Collection Extension

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-06

...;'' EIA-782A, ``Refiners'/Gas Plant Operators' Monthly Petroleum Product Sales Report;'' EIA-782C, ``Monthly Report of Prime Supplier Sales of Petroleum Products Sold For Local Consumption;'' EIA-821, ``Annual Fuel Oil and Kerosene Sales Report;'' EIA-856, ``Monthly Foreign Crude Oil Acquisition Report...

ASSESSING DETOXIFICATION AND DEGRADATION OF WOOD PRESERVING AND PETROLEUM WASTES IN CONTAMINATED SOIL

EPA Science Inventory

This study was undertaken to evaluate in-situ soil bioremediation processes, including degradation and detoxification, for two types of wood preserving wastes and two types of petroleum refining wastes at high concentrations in an unacclimated soil. The soil solid phase, water so...

77 FR 47048 - Agency Information Collection Extension

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-07

... collection requests a three-year extension of its Petroleum Marketing Program, OMB Control Number 1905-0174... as the needs of EIA's public and private customers. Data collected include costs, sales, prices, and... petroleum marketing survey forms listed below: EIA-14, ``Refiners' Monthly Cost Report'' EIA-182, ``Domestic...

The influence of nickel on the bioremediation of multi-component contaminated tropical soil: microcosm and batch bioreactor studies.

PubMed

Taketani, Natália Franco; Taketani, Rodrigo Gouvêa; Leite, Selma Gomes Ferreira; Rizzo, Andrea Camardella de Lima; Tsai, Siu Mui; da Cunha, Cláudia Duarte

2015-07-01

Large petrochemical discharges are responsible for organic and inorganic pollutants in the environment. The purpose of this study was to evaluate the influence of nickel, one of the most abundant inorganic element in crude oil and the main component of hydrogen catalysts for oil refining, on the microbial community structure in artificially petroleum-contaminated microcosms and in solid phase bioreactor studies. In the presence of metals, the oil biodegradation in microcosms was significantly delayed during the first 7 days of operation. Also, increasing amounts of moisture generated a positive influence on the biodegradation processes. The oil concentration, exhibiting the most negative influence at the end of the treatment period. Molecular fingerprinting analyses (denaturing gradient gel electrophoresis--DGGE) indicated that the inclusion of nickel into the contaminated soil promoted direct changes to the microbial community structure. By the end of the experiments, the results of the total petroleum hydrocarbons removal in the bioreactor and the microcosm were similar, but reductions in the treatment times were observed with the bioreactor experiments. An analysis of the microbial community structure by DGGE using various markers showed distinct behaviors between two treatments containing high nickel concentrations. The main conclusion of this study was that Nickel promotes a significant delay in oil biodegradation, despite having only a minor effect over the microbial community.

Liquefaction Of Coal With Surfactant And Disposable Catalyst

NASA Technical Reports Server (NTRS)

Hickey, Gregory S.; Sharma, Pramod K.

1996-01-01

Fuels derived from coal more competitive with petroleum products. Improved coal-liquefaction process exploits synergistic effects of disposable iron oxide catalyst and cheap anionic surfactant. Efficiency of conversion achieved in significantly higher than efficiencies obtained with addition of either surfactant or catalyst alone. No costly pretreatment necessary, and increase in conversion achieved under processing conditions milder than those used heretofore in liquefaction of coal. Quality of distillates obtained after liquefaction in process expected superior to distillates obtained after liquefaction by older techniques.

Bandwidth Study on Energy Use and Potential Energy Savings Opportunities in U.S. Petroleum Refining

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sabine Brueske, Caroline Kramer, Aaron Fisher

2015-06-01

Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. petroleum refining. The study relies on multiple sources to estimate the energy used in nine individual process areas, representing 68% of sector-wide energy consumption. Energy savings opportunities for individual processes are based on technologies currently in use or under development; these potential savings are then extrapolated to estimate sector-wide energy savings opportunity.

Petroleum supply monthly, with data for September 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-11-01

The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major U.S. geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products inmore » the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States.« less

Synthetic zeolites and other microporous oxide molecular sieves

PubMed Central

Sherman, John D.

1999-01-01

Use of synthetic zeolites and other microporous oxides since 1950 has improved insulated windows, automobile air-conditioning, refrigerators, air brakes on trucks, laundry detergents, etc. Their large internal pore volumes, molecular-size pores, regularity of crystal structures, and the diverse framework chemical compositions allow “tailoring” of structure and properties. Thus, highly active and selective catalysts as well as adsorbents and ion exchangers with high capacities and selectivities were developed. In the petroleum refining and petrochemical industries, zeolites have made possible cheaper and lead-free gasoline, higher performance and lower-cost synthetic fibers and plastics, and many improvements in process efficiency and quality and in performance. Zeolites also help protect the environment by improving energy efficiency, reducing automobile exhaust and other emissions, cleaning up hazardous wastes (including the Three Mile Island nuclear power plant and other radioactive wastes), and, as specially tailored desiccants, facilitating the substitution of new refrigerants for the ozone-depleting chlorofluorocarbons banned by the Montreal Protocol. PMID:10097059

METHANE EMISSIONS FROM THE U.S. PETROLEUM INDUSTRY

EPA Science Inventory

The report quantifies methane (CH4) emissions from the U.S. petroleum industry by identifying sources of CH4 from the production, transportation, and refining of oil. Emissions are reported for the base year 1993 and for the years 1986 through 1992, based on adjustments to the ba...

40 CFR 280.92 - Definition of terms.

Code of Federal Regulations, 2014 CFR

2014-07-01

... to the SEC; (2) an annual report of tangible net worth submitted to Dun and Bradstreet; or (3) annual... or refined and all facilities from which petroleum is sold or transferred to other petroleum.... Tangible net worth means the tangible assets that remain after deducting liabilities; such assets do not...

40 CFR 280.92 - Definition of terms.

Code of Federal Regulations, 2011 CFR

2011-07-01

... to the SEC; (2) an annual report of tangible net worth submitted to Dun and Bradstreet; or (3) annual... or refined and all facilities from which petroleum is sold or transferred to other petroleum.... Tangible net worth means the tangible assets that remain after deducting liabilities; such assets do not...

40 CFR 280.92 - Definition of terms.

Code of Federal Regulations, 2013 CFR

2013-07-01

... to the SEC; (2) an annual report of tangible net worth submitted to Dun and Bradstreet; or (3) annual... or refined and all facilities from which petroleum is sold or transferred to other petroleum.... Tangible net worth means the tangible assets that remain after deducting liabilities; such assets do not...

Impact of Environmental Compliance Costs on U.S. Refining Profitability 1995-2001

EIA Publications

2003-01-01

This report assesses the effects of pollution abatement requirements on the financial performance of U.S. petroleum refining and marketing operations during the 1995 to 2001 period. This study is a follow-up to the October 1997 publication entitled The Impact of Environmental Compliance Costs on U.S. Refining Profitability, that focused on the financial impacts of U.S. refining pollution abatement investment requirements in the 1988 to1995 period.

Substitution for petroleum products in Brasil: Urgent issues

DOE Office of Scientific and Technical Information (OSTI.GOV)

de Araujo, J.L.; Ghirardi, A.

Brazililan energy policy during the last decade has focused on the replacement of imported petroleum with domestic energy sources, combined with efforts at conservation. The substitution results, however, have been more spectacular by far. The strategy of replacement is based on two elements. first, to increase domestic petroleum exploration and production. Second, to promote non-petroleum fuels as alternatives to the industrial and transportation sectors, for the substitution of fuel oil and gasoline, respectively. A combination of the substitution strategy, the country's petroleum refining structure, and the composition of the substitution strategy, the country's petroleum refining structure, and the composition ofmore » demand, has resulted in large surpluses of both gasoline and fuel oil, while diesel has become the most used among petroleum products. The surpluses are not easily exportable because there is ample availability of fuel oil in the world market, and because the low octane number of the gasoline produced in Brasil is not compatible with the engines of cars elsewhere in the region and in the world. Furthermore, although gasoline might be upgraded, the question remains that prospects for the world market are not encouraging, and an export-based strategy does not seem justified in view of the growing surpluses. The objective of this analysis is to review the mechanisms of themajor petroleum-substitution programs currently in existence, identifying their past impact on the energy market and the possible consequences of changes in the goals and operating conditions of these programs, in the light of the new prospects for increased domestic oil production and self-sufficiency. 23 refs., 2 figs., 1 tab.« less

Heterogeneous catalysis in complex, condensed reaction media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cantu, David C.; Wang, Yang-Gang; Yoon, Yeohoon

Many reactions required for the upgrading of biomass into fuels and chemicals—hydrogenation, hydrodeoxygenation, hydrocracking—are ostensibly similar to those practiced in the upgrading of petroleum into fuels. But, repurposing hydroprocessing catalysts from refinery operations to treat bio-oil has proved to be unsatisfactory. New catalysts are needed because the composition of the biogenic reactants differs from that of petroleum-derived feedstocks (e.g. the low concentration of sulfur in cellulose-derived biomass precludes use of metal sulfide catalysts unless sulfur is added to the reaction stream). New processes are needed because bio-oils oligomerize rapidly, forming intractable coke and “gunk”, at temperatures so low that themore » desired upgrading reactions are impractically slow, and so low that the bio-oil upgrading must be handled as a condensed fluid. Ideally, the new catalysts and processes would exploit the properties of the multiple phases present in condensed bio-oil, notably the polarizability and structure of the fluid near a catalyst’s surface in the cybotactic region. The results of preliminary modeling of the cybotactic region of different catalyst surfaces in the hydrogenation of phenol suggest that Pd catalysts supported on hydrophilic surfaces are more active than catalysts based on lipophilic supports because the former serve to enhance the concentration of the phenol in the vicinity of the Pd. The effect stems from thermodynamics, not the rate of mass transport. This work was supported by the US Department of Energy, Office of Energy Efficiency and Renewable Energy, Bioenergy Technologies Office. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.« less

[Evolution of technology and occupational exposures in petrochemical industry and in petroleum refining].

PubMed

Cottica, Danilo; Grignani, Elena

2013-01-01

The industry of oil refining and petrochemical play an important role in terms of number of employees in the Italian production. Often the terms "petroleum refining" and "petrochemical" are used interchangeably to define processes that occur in complex plants, which grow outdoors on large surfaces and a visual impact is not irrelevant. In reality, the two areas involve potential exposure to different chemical agents, related to raw materials processed and the specific products. The petrochemical uses as raw materials, the oil fractions, obtained by distillation in the refinery, or natural gas; petrochemical products are, usually, single compounds with a specific degree of purity, used as basic raw materials for the entire industry of organic chemistry, from the production of plastics to pharmaceuticals. The oil refining, that is the topic of this paper, processes mainly oil to obtain mixtures of hydrocarbon compounds, the products of which are specified on the basis of aptitude for use. For example gasolines, are obtained by mixing of fractions of the first distillation, reforming products, antiknock. The paper illustrates, necessarily broadly due to the complexity of the productive sectors, the technological and organizational changes that have led to a significant reduction of occupational exposure to chemical agents, the results of environmental monitoring carried out in some refineries both during routine conditions that during scheduled maintenance activities with plant shutdown and a store of petroleum products. The chemical agents measured are typical for presence, physico-chemical properties and toxicological characteristics of the manufacturing processes of petroleum products like benzene, toluene, xylenes, ethyl benzene, n-hexane, Volatile Hydrocarbons belonging to gasoline, kerosene, diesel fuel. Data related to both personal sampling and fixed positions.

30 CFR 208.2 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the period for which any royalty or net profit share is accrued or reserved to the United States... only be made if substantial amounts of royalty oil are turned back. Refined petroleum product means gasoline, kerosene, distillates (including Number 2 fuel oil), refined lubricating oils, or diesel fuel...

30 CFR 1208.2 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... the period for which any royalty or net profit share is accrued or reserved to the United States... only be made if substantial amounts of royalty oil are turned back. Refined petroleum product means gasoline, kerosene, distillates (including Number 2 fuel oil), refined lubricating oils, or diesel fuel...

30 CFR 1208.2 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... the period for which any royalty or net profit share is accrued or reserved to the United States... only be made if substantial amounts of royalty oil are turned back. Refined petroleum product means gasoline, kerosene, distillates (including Number 2 fuel oil), refined lubricating oils, or diesel fuel...

Potential Impacts of Reductions in Refinery Activity on Northeast Petroleum Product Markets

EIA Publications

2012-01-01

Potential Impacts of Reductions in Refinery Activity on Northeast Petroleum Product Markets is an update to a previous Energy Information Administration (EIA) report, Reductions in Northeast Refining Activity: Potential Implications for Petroleum Product Markets, released in December 2011. This update analyzes possible market responses and impacts in the event Sunoco's Philadelphia refinery closes this summer, in addition to the recently idled refineries on the East Coast and in the U.S. Virgin Islands.

77 FR 22226 - Regulation of Oil-Bearing Hazardous Secondary Materials From the Petroleum Refining Industry...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-13

... does not expect adverse effects on human health or the environment from this regulation. EPA finds that... Petroleum Institute (API) (docket item EPA-HQ- RCRA-2008-0808-0010) and the Metals Industries Recycling... on potentially affecting the use of waste reduction and recycling activities. Neither report...

Zeolites Remove Sulfur From Fuels

NASA Technical Reports Server (NTRS)

Voecks, Gerald E.; Sharma, Pramod K.

1991-01-01

Zeolites remove substantial amounts of sulfur compounds from diesel fuel under relatively mild conditions - atmospheric pressure below 300 degrees C. Extracts up to 60 percent of sulfur content of high-sulfur fuel. Applicable to petroleum refineries, natural-gas processors, electric powerplants, and chemical-processing plants. Method simpler and uses considerably lower pressure than current industrial method, hydro-desulfurization. Yields cleaner emissions from combustion of petroleum fuels, and protects catalysts from poisoning by sulfur.

Ecuador Country Analysis Brief

EIA Publications

2015-01-01

In Ecuador, the oil sector accounts for more than half of the country's export earnings and approximately two-fifths of public sector revenues. Resource nationalism and debates about the economic, strategic, and environmental implications of oil sector development are prominent issues in the politics of Ecuador and the policies of its government. Ecuador is the smallest producer in the Organization of the Petroleum Exporting Countries (OPEC) and it produced 556,000 barrels per day (bbl/d) of petroleum and other liquids in 2014, of which crude oil production was 555,000 bbl/d. A lack of sufficient domestic refining capacity to meet local demand has forced Ecuador to import refined products, limiting net oil revenue.

Hazardous Waste Cleanup: Exxon Bayway Refining Company in Linden, New Jersey

EPA Pesticide Factsheets

The Exxon Bayway Refining Company (Exxon) site is situated on approximately 1,300 acres at 1400 Park Avenue, in the city of Linden in Union County, New Jersey. Exxon had been producing petroleum products at this facility since 1909. The site was sold to

30 CFR 1208.2 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... lease during the period for which any royalty or net profit share is accrued or reserved to the United... royalty oil are turned back. Refined petroleum product means gasoline, kerosene, distillates (including Number 2 fuel oil), refined lubricating oils, or diesel fuel. Royalty oil means that amount of oil that...

Petroleum supply monthly, October 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-10-26

The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products inmore » the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.« less

Petroleum supply monthly, January 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The Petroleum Supply Monthly (PSM) is one of a family of four publications produced by the Petroleum Supply Division within the Energy Information Administration (EIA) reflecting different levels of data timeliness and completeness. The other publications are the Weekly Petroleum Status Report (WPSR), the Winter Fuels Report, and the Petroleum Supply Annual (PSA). Data presented in the PSM describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products inmore » the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics.« less

Advanced reactors and novel reactions for the conversion of triglyceride based oils into high quality renewable transportation fuels

NASA Astrophysics Data System (ADS)

Linnen, Michael James

Sustainable energy continues to grow more important to all societies, leading to the research and development of a variety of alternative and renewable energy technologies. Of these, renewable liquid transportation fuels may be the most visible to consumers, and this visibility is further magnified by the long-term trend of increasingly expensive petroleum fuels that the public consumes. While first-generation biofuels such as biodiesel and fuel ethanol have been integrated into the existing fuel infrastructures of several countries, the chemical differences between them and their petroleum counterparts reduce their effectiveness. This gives rise to the development and commercialization of second generation biofuels, many of which are intended to have equivalent properties to those of their petroleum counterparts. In this dissertation, the primary reactions for a second-generation biofuel process, known herein as the University of North Dakota noncatalytic cracking process (NCP), have been studied at the fundamental level and improved. The NCP is capable of producing renewable fuels and chemicals that are virtually the same as their petroleum counterparts in performance and quality (i.e., petroleum-equivalent). In addition, a novel analytical method, FIMSDIST was developed which, within certain limitations, can increase the elution capabilities of GC analysis and decrease sample processing times compared to other high resolution methods. These advances are particularly useful for studies of highly heterogeneous fuel and/or organic chemical intermediates, such as those studied for the NCP. However the data from FIMSDIST must be supplemented with data from other methods such as for certain carboxylic acid, to provide accurate, comprehensive results, From a series of TAG cracking experiments that were performed, it was found that coke formation during cracking is most likely the result of excessive temperature and/or residence time in a cracking reactor. Based on this, a tubular cracking reactor was developed that could operate continuously without coke formation. The design also was proven to be scalable. Yields from the reactor were determined under a variety of conditions in order to predict the outputs from the NCP and to establish relationships/correlations between operating parameters and the product distribution. These studies led to the conclusion that the most severe operating conditions which do not induce coking are optimal over the experimental domain. In order to develop economical deoxygenation catalysts for use within the NCP, a series of experiments were performed using nickel catalysts, demonstrating that nickel catalysts could outperform their predecessor, a high cost palladium-based catalyst. A nickel catalyst was then tested in a packed bed reactor in order to determine suitable operating conditions for its commercial utilization in packed bed reactors.

40 CFR 60.101a - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... suspended in a fluidized bed to improve feedstock quality for additional processing and the catalyst or... the oils derived from tar sands, shale, and coal. Petroleum refinery means any facility engaged in...

Saudi Arabia Country Analysis Brief

EIA Publications

2014-01-01

Saudi Arabia is the world's largest holder of crude oil proved reserves and was the largest exporter of total petroleum liquids in 2013. In 2013, Saudi Arabia was the world's second-largest petroleum liquids producer behind the United States and was the world's second-largest crude oil producer behind Russia. Saudi Arabia's economy remains heavily dependent on petroleum. Petroleum exports accounted for 85% of total Saudi export revenues in 2013, according to the Organization of the Petroleum Exporting Countries (OPEC)'s Annual Statistical Bulletin 2014. With the largest oil projects nearing completion, Saudi Arabia is expanding its natural gas, refining, petrochemicals, and electric power industries. Saudi Arabia's oil and natural gas operations are dominated by Saudi Aramco, the national oil and gas company and the world's largest oil company in terms of production. Saudi Arabia's Ministry of Petroleum and Mineral Resources and the Supreme Council for Petroleum and Minerals have oversight of the oil and natural gas sector and Saudi Aramco.

Investigation of bio-composites using Novolac type liquefied wood resin: effects of liquefaction and fabrication conditions

Treesearch

Hui Pan; Chung-Yun Hse; Todd F. Shupe

2009-01-01

Wood liquefaction using an organic solvent and an acid catalyst has long been studied as a novel technique to utilize biomass as an alternative to petroleum-based products. Oxalic acid is a weaker organic acid than a mineral acid and wood liquefaction with oxalic acid as a catalyst will result in a higher amount of wood residue than that with a mineral acid....

Inert Reassessment Document for Cerous Chloride

EPA Pesticide Factsheets

The rare earth chlorides have a wide variety of scientific applications. They a re used in superconductors, lasers, magnets, catalytic converters, fertilizes, supper alloys, cigarette lighters and as catalysts in the production of petroleum products.

Petroleum supply monthly, June 1999, with data for April 1999

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the US and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the US (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated, the datamore » reported by these sectors approximately represent the consumption of petroleum products in the US. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.« less

Petroleum supply monthly, February 1999, with data for December 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Data presented in the Petroleum Supply Monthly (PSM) describes the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in primary supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated,more » the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections: Summary Statistics and Detailed Statistics. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. 16 figs., 66 tabs.« less

Petroleum Refinery Information Collection Request (ICR) Emissions Test Report for BP-Husky Refining LLC

EPA Pesticide Factsheets

On March 31, 2011, U.S. EPA sent a Section 114 letter to the BP-Husky Refining Company in Oregon, Ohio stating that the facility was subject to the ICR and that certain information would need to be submitted by the facility to satisfy U.S. EPA’s ICR.

Hazardous Waste Cleanup: Commonwealth Oil and Refining Company, Incorporated in Peñuellas, Puerto Rico

EPA Pesticide Factsheets

The Commonwealth Oil and Refining Company, Inc. (CORCO) facility is located on the south coast of Puerto Rico, on Route 127 in the Municipio (town) de Peñuelas, approximately 7 miles west of the city of Ponce. The facility was formerly a large petroleum

76 FR 5107 - Regulation of Oil-Bearing Hazardous Secondary Materials From the Petroleum Refining Industry...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-28

... Processed in a Gasification System To Produce Synthesis Gas; Tentative Determination To Deny Petition for... Synthesis Gas,'' published in the Federal Register on January 2, 2008. The EPA considered the petition... Refining Industry Processed in a Gasification System to Produce Synthesis Gas'' (Gasification Rule). This...

Acoustic-wave sensor apparatus for analyzing a petroleum-based composition and sensing solidification of constituents therein

DOEpatents

Spates, J.J.; Martin, S.J.; Mansure, A.J.

1997-08-26

An acoustic-wave sensor apparatus and method are disclosed. The apparatus for analyzing a normally liquid petroleum-based composition includes at least one acoustic-wave device in contact with the petroleum-based composition for sensing or detecting the presence of constituents (e.g. paraffins or petroleum waxes) therein which solidify upon cooling of the petroleum-based composition below a cloud-point temperature. The acoustic-wave device can be a thickness-shear-mode device (also termed a quartz crystal microbalance), a surface-acoustic-wave device, an acoustic-plate-mode device or a flexural plate-wave device. Embodiments of the present invention can be used for measuring a cloud point, a pour point and/or a freeze point of the petroleum-based composition, and for determining a temperature characteristic of each point. Furthermore, measurements with the acoustic-wave sensor apparatus can be made off-line by using a sample having a particular petroleum-based composition; or in-situ with the petroleum-based composition contained within a pipeline or storage tank. The acoustic-wave sensor apparatus has uses in many different petroleum technology areas, including the recovery, transport, storage, refining and use of petroleum and petroleum-based products. 7 figs.

Acoustic-wave sensor apparatus for analyzing a petroleum-based composition and sensing solidification of constituents therein

DOEpatents

Spates, James J.; Martin, Stephen J.; Mansure, Arthur J.

1997-01-01

An acoustic-wave sensor apparatus and method. The apparatus for analyzing a normally liquid petroleum-based composition includes at least one acoustic-wave device in contact with the petroleum-based composition for sensing or detecting the presence of constituents (e.g. paraffins or petroleum waxes) therein which solidify upon cooling of the petroleum-based composition below a cloud-point temperature. The acoustic-wave device can be a thickness-shear-mode device (also termed a quartz crystal mircrobalance), a surface-acoustic-wave device, an acoustic-plate-mode device or a flexural plate-wave device. Embodiments of the present invention can be used for measuring a cloud point, a pour point and/or a freeze point of the petroleum-based composition, and for determining a temperature characteristic of each point. Furthermore, measurements with the acoustic-wave sensor apparatus can be made off-line by using a sample having a particular petroleum-based composition; or in-situ with the petroleum-based composition contained within a pipeline or storage tank. The acoustic-wave sensor apparatus has uses in many different petroleum technology areas, including the recover transport, storage, refining and use of petroleum and petroleum-based products.

Petroleum supply monthly, February 1991. [Glossary included

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-02-01

Data presented in the Petroleum Supply Monthly (PSM) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated,more » the data reported by these sectors approximately represent the consumption of petroleum products in the United States. Data presented in the PSM are divided into two sections (1) the Summary Statistics and (2) the Detailed Statistics. Explanatory Notes, located at the end of this publication, present information describing data collection, sources, estimation methodology, data quality control procedures, modifications to reporting requirements and interpretation of tables. Industry terminology and product definitions are listed alphabetically in the Glossary. 12 figs., 54 tabs.« less

Catalytic Upgrading of Biomass Pyrolysis Oxygenates with Vacuum Gas Oil Using a Davison Circulating Riser Reactor

DOE PAGES

Jarvis, Mark W.; Olstad, Jessica; Parent, Yves; ...

2018-01-02

We investigate and quantitate the changes in hydrocarbon product composition while evaluating the performance and operability of the National Renewable Energy Laboratory's Davison Circulating Riser (DCR) reactor system when biomass model compounds are cofed with traditional fluid catalyst cracking (FCC) feeds and catalyst: vacuum gas oil (VGO) and equilibrium zeolite catalyst (E-Cat). Three compounds (acetic acid, guaiacol, and sorbitan monooleate) were selected to represent the major classes of oxygenates present in biomass pyrolysis vapors. These vapors can contain 30-50% oxygen as oxygenates, which create conversion complications (increased reactivity and coking) when integrating biomass vapors and liquids into fuel and chemicalmore » processes long dominated by petroleum feedstocks. We used these model compounds to determine the appropriate conditions for coprocessing with petroleum and ultimately pure pyrolysis vapors only as compared with standard baseline conditions obtained with VGO and E-Cat only in the DCR. Model compound addition decreased the DCR catalyst circulation rate, which controls reactor temperature and measures reaction heat demand, while increasing catalyst coking rates. Liquid product analyses included 2-dimensional gas chromatography time-of-flight mass spectroscopy (2D GCxGC TOFS), simulated distillation (SIM DIST), 13C NMR, and carbonyl content. Aggregated results indicated that the model compounds were converted during reaction, and despite functional group differences, product distributions for each model compound were very similar. In addition, we determined that adding model compounds to the VGO feed did not significantly affect the DCR's operability or performance. Future work will assess catalytic upgrading of biomass pyrolysis vapor to fungible hydrocarbon products using upgrading catalysts currently being developed at NREL and at Johnson Matthey.« less

Catalytic Upgrading of Biomass Pyrolysis Oxygenates with Vacuum Gas Oil Using a Davison Circulating Riser Reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jarvis, Mark W.; Olstad, Jessica; Parent, Yves

We investigate and quantitate the changes in hydrocarbon product composition while evaluating the performance and operability of the National Renewable Energy Laboratory's Davison Circulating Riser (DCR) reactor system when biomass model compounds are cofed with traditional fluid catalyst cracking (FCC) feeds and catalyst: vacuum gas oil (VGO) and equilibrium zeolite catalyst (E-Cat). Three compounds (acetic acid, guaiacol, and sorbitan monooleate) were selected to represent the major classes of oxygenates present in biomass pyrolysis vapors. These vapors can contain 30-50% oxygen as oxygenates, which create conversion complications (increased reactivity and coking) when integrating biomass vapors and liquids into fuel and chemicalmore » processes long dominated by petroleum feedstocks. We used these model compounds to determine the appropriate conditions for coprocessing with petroleum and ultimately pure pyrolysis vapors only as compared with standard baseline conditions obtained with VGO and E-Cat only in the DCR. Model compound addition decreased the DCR catalyst circulation rate, which controls reactor temperature and measures reaction heat demand, while increasing catalyst coking rates. Liquid product analyses included 2-dimensional gas chromatography time-of-flight mass spectroscopy (2D GCxGC TOFS), simulated distillation (SIM DIST), 13C NMR, and carbonyl content. Aggregated results indicated that the model compounds were converted during reaction, and despite functional group differences, product distributions for each model compound were very similar. In addition, we determined that adding model compounds to the VGO feed did not significantly affect the DCR's operability or performance. Future work will assess catalytic upgrading of biomass pyrolysis vapor to fungible hydrocarbon products using upgrading catalysts currently being developed at NREL and at Johnson Matthey.« less

Production of carbon nanotubes: Chemical vapor deposition synthesis from liquefied petroleum gas over Fe-Co-Mo tri-metallic catalyst supported on MgO

NASA Astrophysics Data System (ADS)

Setyopratomo, P.; Wulan, Praswasti P. D. K.; Sudibandriyo, M.

2016-06-01

Carbon nanotubes were produced by chemical vapor deposition method to meet the specifications for hydrogen storage. So far, the various catalyst had been studied outlining their activities, performances, and efficiencies. In this work, tri-metallic catalyst consist of Fe-Co-Mo supported on MgO was used. The catalyst was prepared by wet-impregnation method. Liquefied Petroleum Gas (LPG) was used as carbon source. The synthesis was conducted in atmospheric fixed bed reactor at reaction temperature range 750 - 850 °C for 30 minutes. The impregnation method applied in this study successfully deposed metal component on the MgO support surface. It found that the deposited metal components might partially replace Mg(OH)2 or MgO molecules in their crystal lattice. Compare to the original MgO powder; it was significant increases in pore volume and surface area has occurred during catalyst preparation stages. The size of obtained carbon nanotubes is ranging from about 10.83 nm OD/4.09 nm ID up to 21.84 nm OD/6.51 nm ID, which means that multiwall carbon nanotubes were formed during the synthesis. Yield as much as 2.35 g.CNT/g.catalyst was obtained during 30 minutes synthesis and correspond to carbon nanotubes growth rate of 0.2 μm/min. The BET surface area of the obtained carbon nanotubes is 181.13 m2/g and around 50 % of which is contributed by mesopores. Micropore with half pore width less than 1 nm contribute about 10% volume of total micro and mesopores volume of the carbon nanotubes. The existence of these micropores is very important to increase the hydrogen storage capacity of the carbon nanotubes.

From Sugars to Wheels: The Conversion of Ethanol to 1,3-Butadiene over Metal-Promoted Magnesia-Silicate Catalysts.

PubMed

Shylesh, Sankaranarayanapillai; Gokhale, Amit A; Scown, Corinne D; Kim, Daeyoup; Ho, Christopher R; Bell, Alexis T

2016-06-22

1,3-Butadiene (1,3-BD) is a high-value chemical intermediate used mainly as a monomer for the production of synthetic rubbers. The ability to source 1,3-BD from biomass is of considerable current interest because it offers the potential to reduce the life-cycle greenhouse gas (GHG) impact associated with 1,3-BD production from petroleum-derived naphtha. Herein, we report the development and investigation of a new catalyst and process for the one-step conversion of ethanol to 1,3-BD. The catalyst is prepared by the incipient impregnation of magnesium oxide onto a silica support followed by the deposition of Au nanoparticles by deposition-precipitation. The resulting Au/MgO-SiO2 catalyst exhibits a high activity and selectivity to 1,3-BD and low selectivities to diethyl ether, ethylene, and butenes. Detailed characterization of the catalyst shows that the desirable activity and selectivity of Au/MgO-SiO2 are a consequence of a critical balance between the acidic-basic sites associated with a magnesium silicate hydrate phase and the redox properties of the Au nanoparticles. A process for the conversion of ethanol to 1,3-BD, which uses our catalyst, is proposed and analyzed to determine the life-cycle GHG impact of the production of this product from biomass-derived ethanol. We show that 1,3-BD produced by our process can reduce GHG emissions by as much as 155 % relative to the conventional petroleum-based production of 1,3-BD. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Implications of Increasing Light Tight Oil Production for U.S. Refining

EIA Publications

2015-01-01

EIA retained Turner, Mason & Company to provide analysis of the implications of increasing domestic light tight oil production for U.S. refining, focusing on regional crude supply/demand balances, refinery crude slates, operations, capital investment, product yields, crude oil exports/imports, petroleum product exports, infrastructure constraints and expansions, and crude oil price relationships.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Melancon, R.

In June, 1995, the National Petroleum Refiners Association (NPRA) adhoc committee on Contractor Safety Training, turned over the task of developing reciprocity agreements with all Contractor Safety Training Councils to the Executive Directors of each of the Council`s. The Council representatives were to develop these agreements based on the NPRA adhoc committee training objectives that were developed jointly by representatives of the petroleum industry, chemical industry, contractors and the Council`s.

40 CFR Appendix A to Part 122 - NPDES Primary Industry Categories

Code of Federal Regulations, 2013 CFR

2013-07-01

... coating Copper forming Electrical and electronic components Electroplating Explosives manufacturing... chemicals manufacturing Paint and ink formulation Pesticides Petroleum refining Pharmaceutical preparations...

40 CFR Appendix A to Part 122 - NPDES Primary Industry Categories

Code of Federal Regulations, 2012 CFR

2012-07-01

... coating Copper forming Electrical and electronic components Electroplating Explosives manufacturing... chemicals manufacturing Paint and ink formulation Pesticides Petroleum refining Pharmaceutical preparations...

40 CFR Appendix A to Part 122 - NPDES Primary Industry Categories

Code of Federal Regulations, 2014 CFR

2014-07-01

... coating Copper forming Electrical and electronic components Electroplating Explosives manufacturing... chemicals manufacturing Paint and ink formulation Pesticides Petroleum refining Pharmaceutical preparations...

40 CFR Appendix A to Part 122 - NPDES Primary Industry Categories

Code of Federal Regulations, 2011 CFR

2011-07-01

... coating Copper forming Electrical and electronic components Electroplating Explosives manufacturing... chemicals manufacturing Paint and ink formulation Pesticides Petroleum refining Pharmaceutical preparations...

Analysis of solvent dyes in refined petroleum products by electrospray ionization mass spectrometry

USGS Publications Warehouse

Rostad, C.E.

2010-01-01

Solvent dyes are used to color refined petroleum products to enable differentiation between gasoline, diesel, and jet fuels. Analysis for these dyes in the hydrocarbon product is difficult due to their very low concentrations in such a complex matrix. Flow injection analysis/electrospray ionization/mass spectrometry in both negative and positive mode was used to optimize ionization of ten typical solvent dyes. Samples of hydrocarbon product were analyzed under similar conditions. Positive electrospray ionization produced very complex spectra, which were not suitably specific for targeting only the dyes. Negative electrospray ionization produced simple spectra because aliphatic and aromatic moieties were not ionized. This enabled screening for a target dye in samples of hydrocarbon product from a spill.

Exposure assessment of particulates of diesel and natural gas fuelled buses in silico.

PubMed

Pietikäinen, Mari; Oravisjärvi, Kati; Rautio, Arja; Voutilainen, Arto; Ruuskanen, Juhani; Keiski, Riitta L

2009-12-15

Lung deposition estimates of particulate emissions of diesel and natural gas (CNG) fuelled vehicles were studied by using in silico methodology. Particulate emissions and particulate number size distributions of two Euro 2 petroleum based diesel buses and one Euro 3 gas bus were measured. One of the petroleum based diesel buses used in the study was equipped with an oxidation catalyst on the vehicle (DI-OC) while the second had a partial-DPF catalyst (DI-pDPF). The third bus used was the gas bus with an oxidation catalyst on the vehicle (CNG-OC). The measurements were done using a transient chassis dynamometer test cycle (Braunschweig cycle) and an Electric Low Pressure Impactor (ELPI) with formed particulates in the size range of 7 nm to 10 microm. The total amounts of the emitted diesel particulates were 88-fold for DI-OC and 57-fold for DI-pDPF compared to the total amount of emitted CNG particulates. Estimates for the deposited particulates were computed with a lung deposition model ICRP 66 using in-house MATLAB scripts. The results were given as particulate numbers and percentages deposited in five different regions of the respiratory system. The percentages of particulates deposited in the respiratory system were 56% for DI-OC, 51% for DI-pDPF and 77% for CNG-OC of all the inhaled particulates. The result shows that under similar conditions the total lung dose of particulates originating from petroleum diesel fuelled engines DI-OC and DI-pDPF was more than 60-fold and 35-fold, respectively, compared to the lung dose of particulates originating from the CNG fuelled engine. The results also indicate that a majority (35-50%) of the inhaled particulates emitted from the tested petroleum diesel and CNG engines penetrate deep into the unciliated regions of the lung where gas-exchange occurs.

Petroleum supply monthly, April 1991. [Glossary included

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-04-29

Data presented in the PSM (Petroleum Supply Monthly) describe the supply and disposition of petroleum products in the United States and major US geographic regions. The data series describe production, imports and exports, inter-Petroleum Administration for Defense (PAD) District movements, and inventories by the primary suppliers of petroleum products in the United States (50 States and the District of Columbia). The reporting universe includes those petroleum sectors in Primary Supply. Included are: petroleum refiners, motor gasoline blenders, operators of natural gas processing plants and fractionators, inter-PAD transporters, importers, and major inventory holders of petroleum products and crude oil. When aggregated,more » the data reported by these sectors approximately represent the consumption of petroleum products in the United States. The tables and figures in the Summary Statistics section of the PSM present a time series of selected petroleum data on a US level. Most time series include preliminary estimates for one month. The Detailed Statistics tables of the PSM present statistics for the most current month available as well as year-to-date. Industry terminology and product definitions are listed alphabetically in the Glossary. 14 figs., 65 tabs.« less

Method to upgrade bio-oils to fuel and bio-crude

DOEpatents

Steele, Philip H; Pittman, Jr., Charles U; Ingram, Jr., Leonard L; Gajjela, Sanjeev; Zhang, Zhijun; Bhattacharya, Priyanka

2013-12-10

This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.

Engaging a Diverse Group of Students with a Broad Spectrum of Geological Experience: The CSUN Catalyst Approach and a MARGINS Application

NASA Astrophysics Data System (ADS)

Marsaglia, K. M.; Vazquez, J.; Yule, J. D.; Simila, G.

2007-12-01

Imagine the challenge of teaching a one-unit Geoscience course composed of a diverse mix of first-year graduate majors, senior to freshman majors, and high school students with little earth science background. With the help of Geodiversity grants from NSF (CSUN Catalyst program), we have developed a successful environment for learning and mentorship via a series of short (2-3 week) inquiry-based exercises that emphasize teamwork. Each exercise is organized around research projects headed by Catalyst Faculty members: Northridge Earthquake, San Andreas Fault System, Yellowstone and Long Valley supervolcanoes, and New Zealand MARGIN geology. After participating in the course, students conduct independent research within one of four research groups as part of their MS or BS theses including summer research experiences. One exercise, constructed as a version of "The Oil Game," is meant to familiarize students with MARGINS Source-to-Sink focus (Waipaoa Sedimentary System, North Island) and alternate focus (Bounty Fan, South Island) sites in New Zealand. Students are divided into rival petroleum companies (Tiger Oil and Flower Petroleum) and asked to evaluate offshore areas for an impending government lease sale and to provide the rationale for competitive sealed bids that they recommend in a final presentation to management (Catalyst Faculty). To accomplish this they are supplied with reference materials on onshore geology and known petroleum production, samples of New Zealand rock units and stream sediments, and a limited budget. In addition to geological parameters (source rocks, seals, reservoir rocks, trapping mechanisms) they must also take into account environmental, economic and infrastructure concerns. Other projects included documenting volcanic hazards around Long Valley caldera and evaluating seismic hazards of local high school sites. The tiered structure of the projects perhaps best serves the undergraduate participants, who benefit from being mentored by graduate students as well as serving as mentors for the high school students.

Zinc sulfide liquefaction catalyst

DOEpatents

Garg, Diwakar

1984-01-01

A process for the liquefaction of carbonaceous material, such as coal, is set forth wherein coal is liquefied in a catalytic solvent refining reaction wherein an activated zinc sulfide catalyst is utilized which is activated by hydrogenation in a coal derived process solvent in the absence of coal.

Catalysts for coal liquefaction processes

DOEpatents

Garg, Diwakar

1986-01-01

Improved catalysts for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprise a combination of zinc or copper, or a compound thereof, and a Group VI or non-ferrous Group VIII metal, or a compound thereof.

Catalysts for coal liquefaction processes

DOEpatents

Garg, D.

1986-10-14

Improved catalysts for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprise a combination of zinc or copper, or a compound thereof, and a Group VI or non-ferrous Group VIII metal, or a compound thereof.

EIA model documentation: Petroleum Market Model of the National Energy Modeling System

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1994-12-30

The purpose of this report is to define the objectives of the Petroleum Market Model (PMM), describe its basic approach, and provide detail on how it works. This report is intended as a reference document for model analysts, users, and the public. Documentation of the model is in accordance with EIA`s legal obligation to provide adequate documentation in support of its models (Public Law 94-385, section 57.b.2). The PMM models petroleum refining activities, the marketing of products, the production of natural gas liquids and domestic methanol, projects petroleum provides and sources of supplies for meeting demand. In addition, the PMMmore » estimates domestic refinery capacity expansion and fuel consumption.« less

High-throughput investigation of catalysts for JP-8 fuel cracking to liquefied petroleum gas.

PubMed

Bedenbaugh, John E; Kim, Sungtak; Sasmaz, Erdem; Lauterbach, Jochen

2013-09-09

Portable power technologies for military applications necessitate the production of fuels similar to LPG from existing feedstocks. Catalytic cracking of military jet fuel to form a mixture of C₂-C₄ hydrocarbons was investigated using high-throughput experimentation. Cracking experiments were performed in a gas-phase, 16-sample high-throughput reactor. Zeolite ZSM-5 catalysts with low Si/Al ratios (≤25) demonstrated the highest production of C₂-C₄ hydrocarbons at moderate reaction temperatures (623-823 K). ZSM-5 catalysts were optimized for JP-8 cracking activity to LPG through varying reaction temperature and framework Si/Al ratio. The reducing atmosphere required during catalytic cracking resulted in coking of the catalyst and a commensurate decrease in conversion rate. Rare earth metal promoters for ZSM-5 catalysts were screened to reduce coking deactivation rates, while noble metal promoters reduced onset temperatures for coke burnoff regeneration.

Catalysis in biodiesel processing

USDA-ARS?s Scientific Manuscript database

A substantial industry has grown in recent years to achieve the industrial scale production of biodiesel, a renewable replacement for petroleum-derived diesel fuel. The prevalent technology for biodiesel production at this time involves use of the long known single-use catalysts sodium hydroxide (o...

Study of Selected Petroleum Refining Residuals

EPA Pesticide Factsheets

The document describes EPA's approach to conducting the industry study required by the Environmental Defense Fund (EDF)/EPA consent decree and characterizes the study residuals and how they are managed.

Well-to-Wheels Greenhouse Gas Emissions Analysis of High-Octane Fuels with Various Market Shares and Ethanol Blending Levels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, Jeongwoo; Elgowainy, Amgad; Wang, Michael

2015-07-14

In this study, we evaluated the impacts of producing HOF with a RON of 100, using a range of ethanol blending levels (E10, E25, and E40), vehicle efficiency gains, and HOF market penetration scenarios (3.4% to 70%), on WTW petroleum use and GHG emissions. In particular, we conducted LP modeling of petroleum refineries to examine the impacts of different HOF production scenarios on petroleum refining energy use and GHG emissions. We compared two cases of HOF vehicle fuel economy gains of 5% and 10% in terms of MPGGE to baseline regular gasoline vehicles. We incorporated three key factors in GREETmore » — (1) refining energy intensities of gasoline components for the various ethanol blending options and market shares, (2) vehicle efficiency gains, and (3) upstream energy use and emissions associated with the production of different crude types and ethanol — to compare the WTW GHG emissions of various HOF/vehicle scenarios with the business-as-usual baseline regular gasoline (87 AKI E10) pathway.« less

Synthesis of biodiesel from pongamia oil using heterogeneous ion-exchange resin catalyst.

PubMed

Jaya, N; Selvan, B Karpanai; Vennison, S John

2015-11-01

Biodiesel is a clean-burning renewable substitute fuel for petroleum. Biodiesel could be effectively produced by transesterification reaction of triglycerides of vegetable oils with short-chain alcohols in the presence of homogeneous or heterogeneous catalysts. Conventionally, biodiesel manufacturing processes employ strong acids or bases as catalysts. But, separation of the catalyst and the by-product glycerol from the product ester is too expensive to justify the product use as an automobile fuel. Hence heterogeneous catalysts are preferred. In this study, transesterification of pongamia oil with ethanol was performed using a solid ion-exchange resin catalyst. It is a macro porous strongly basic anion exchange resin. The process parameters affecting the ethyl ester yield were investigated. The reaction conditions were optimized for the maximum yield of fatty acid ethyl ester (FAEE) of pongamia oil. The properties of FAEE were compared with accepted standards of biodiesel. Engine performance was also studied with pongamia oil diesel blend and engine emission characteristics were observed. Copyright © 2015 Elsevier Inc. All rights reserved.

Measurement fundamentals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Webb, R.A.

The need to have accurate petroleum measurement is obvious. Petroleum measurement is the basis of commerce between oil producers, royalty owners, oil transporters, refiners, marketers, the Department of Revenue, and the motoring public. Furthermore, petroleum measurements are often used to detect operational problems or unwanted releases in pipelines, tanks, marine vessels, underground storage tanks, etc. Therefore, consistent, accurate petroleum measurement is an essential part of any operation. While there are several methods and different types of equipment used to perform petroleum measurement, the basic process stays the same. The basic measurement process is the act of comparing an unknown quantity,more » to a known quantity, in order to establish its magnitude. The process can be seen in a variety of forms; such as measuring for a first-down in a football game, weighing meat and produce at the grocery, or the use of an automobile odometer.« less

Environmental Regulations and Changes in Petroleum Refining Operations (Short-Term Energy Outlook Supplement June 1998)

EIA Publications

1998-01-01

Changes in domestic refining operations are identified and related to the summer Reid vapor pressure (RVP) restrictions and oxygenate blending requirements. This analysis uses published Energy Information Administration survey data and linear regression equations from the Short-Term Integrated Forecasting System (STIFS). The STIFS model is used for producing forecasts appearing in the Short-Term Energy Outlook.

Industrial Catalysis: A Practical Guide

NASA Astrophysics Data System (ADS)

Farrauto, Robert J.

Every student of chemistry, material science, and chemical engineering should be schooled in catalysis and catalytic reactions. The reason is quite simple; most products produced in the chemical and petroleum industry utilize catalysts to enhance the rate of reaction and selectivity to desired products. Catalysts are also extensively used to minimize harmful byproduct pollutants in environmental applications. Enhanced reaction rates translate to higher production volumes at lower temperatures with smaller and less exotic materials of construction necessary. When a highly selective catalyst is used, large volumes of desired products are produced with virtually no undesirable byproducts. Gasoline, diesel, home heating oil, and aviation fuels owe their performance quality to catalytic processing used to upgrade crude oil.

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

Argonne National Laboratory researchers have invented a technology for recovering oil and refined petroleum products from bodies of water. Oleo Sponge offers several key advantages over the technologies and techniques that are currently used to combat this problem.

10 CFR 626.7 - Royalty transfer and exchange.

Code of Federal Regulations, 2010 CFR

2010-01-01

...) of this section, DOE determines there is a high probability that the cost to the Government can be... supply or refining capability, logistical problems for moving petroleum products, macroeconomic factors...

Recycling of waste spent catalyst in road construction and masonry blocks.

PubMed

Taha, Ramzi; Al-Kamyani, Zahran; Al-Jabri, Khalifa; Baawain, Mahad; Al-Shamsi, Khalid

2012-08-30

Waste spent catalyst is generated in Oman as a result of the cracking process of petroleum oil in the Mina Al-Fahl and Sohar Refineries. The disposal of spent catalyst is of a major concern to oil refineries. Stabilized spent catalyst was evaluated for use in road construction as a whole replacement for crushed aggregates in the sub-base and base layers and as a partial replacement for Portland cement in masonry blocks manufacturing. Stabilization is necessary as the waste spent catalyst exists in a powder form and binders are needed to attain the necessary strength required to qualify its use in road construction. Raw spent catalyst was also blended with other virgin aggregates, as a sand or filler replacement, for use in road construction. Compaction, unconfined compressive strength and leaching tests were performed on the stabilized mixtures. For its use in masonry construction, blocks were tested for unconfined compressive strength at various curing periods. Results indicate that the spent catalyst has a promising potential for use in road construction and masonry blocks without causing any negative environmental impacts. Copyright © 2012 Elsevier B.V. All rights reserved.

Fischer-Tropsch Catalyst for Aviation Fuel Production

NASA Technical Reports Server (NTRS)

deLaRee, Ana B.; Best, Lauren M.; Hepp, Aloysius F.

2011-01-01

As the oil supply declines, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to non-petroleum sources as a feedstock for aviation (and other transportation) fuels. The Fischer-Tropsch process uses a gas mixture of carbon monoxide and hydrogen which is converted into various liquid hydrocarbons; this versatile gas-to-liquid technology produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fischer-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur and aromatic compounds. It is most commonly catalyzed by cobalt supported on alumina, silica, or titania or unsupported alloyed iron powders. Cobalt is typically used more often than iron, in that cobalt is a longer-active catalyst, has lower water-gas shift activity, and lower yield of modified products. Promoters are valuable in improving Fischer-Tropsch catalyst as they can increase cobalt oxide dispersion, enhance the reduction of cobalt oxide to the active metal phase, stabilize a high metal surface area, and improve mechanical properties. Our goal is to build up the specificity of the Fischer-Tropsch catalyst while adding less-costly transition metals as promoters; the more common promoters used in Fischer-Tropsch synthesis are rhenium, platinum, and ruthenium. In this report we will describe our preliminary efforts to design and produce catalyst materials to achieve our goal of preferentially producing C8 to C18 paraffin compounds in the NASA Glenn Research Center Gas-To-Liquid processing plant. Efforts at NASA Glenn Research Center for producing green fuels using non-petroleum feedstocks support both the Sub-sonic Fixed Wing program of Fundamental Aeronautics and the In Situ Resource Utilization program of the Exploration Technology Development and Demonstration program.

Methods of refining and producing dibasic esters and acids from natural oil feedstocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snead, Thomas E; Cohen, Steven A; Gildon, Demond L

2015-04-07

Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

Methods of refining and producing dibasic esters and acids from natural oil feedstocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.

2016-03-15

Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

Iran Refined Petroleum Sanctions Act

THOMAS, 111th Congress

Sen. Bayh, Evan [D-IN

2009-04-28

Senate - 04/28/2009 Read twice and referred to the Committee on Banking, Housing, and Urban Affairs. (All Actions) Tracker: This bill has the status IntroducedHere are the steps for Status of Legislation:

Molecular molybdenum persulfide and related catalysts for generating hydrogen from water

DOEpatents

Long, Jeffrey R.; Chang, Christopher J.; Karunadasa, Hemamala I.; Majda, Marcin

2016-11-22

New metal persulfido compositions of matter are described. In one embodiment the metal is molybdenum and the metal persulfido complex mimics the structure and function of the triangular active edge site fragments of MoS.sub.2, a material that is the current industry standard for petroleum hydro desulfurization, as well as a promising low-cost alternative to platinum for electrocatalytic hydrogen production. This molecular [(PY5W.sub.2)MoS.sub.2].sup.x+ containing catalyst is capable of generating hydrogen from acidic-buffered water or even seawater at very low overpotentials at a turnover frequency rate in excess of 500 moles H.sub.2 per mole catalyst per second, with a turnover number (over a 20 hour period) of at least 19,000,000 moles H.sub.2 per mole of catalyst.

Molecular molybdenum persulfide and related catalysts for generating hydrogen from water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Long, Jeffrey R.; Chang, Christopher J.; Karunadasa, Hemamala I.

New metal persulfido compositions of matter are described. In one embodiment the metal is molybdenum and the metal persulfido complex mimics the structure and function of the triangular active edge site fragments of MoS.sub.2, a material that is the current industry standard for petroleum hydro desulfurization, as well as a promising low-cost alternative to platinum for electrocatalytic hydrogen production. This molecular [(PY5W.sub.2)MoS.sub.2].sup.x+ containing catalyst is capable of generating hydrogen from acidic-buffered water or even seawater at very low overpotentials at a turnover frequency rate in excess of 500 moles H.sub.2 per mole catalyst per second, with a turnover number (overmore » a 20 hour period) of at least 19,000,000 moles H.sub.2 per mole of catalyst.« less

CO{sub 2} Reuse in Petrochemical Facilities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jason Trembly; Brian Turk; Maruthi Pavani

2010-12-31

To address public concerns regarding the consequences of climate change from anthropogenic carbon dioxide (CO{sub 2}) emissions, the U.S. Department of Energy's National Energy Technology Laboratory (DOE/NETL) is actively funding a CO{sub 2} management program to develop technologies capable of mitigating CO{sub 2} emissions from power plant and industrial facilities. Over the past decade, this program has focused on reducing the costs of carbon capture and storage technologies. Recently, DOE/NETL launched an alternative CO{sub 2} mitigation program focused on beneficial CO{sub 2} reuse to support the development of technologies that mitigate emissions by converting CO{sub 2} into valuable chemicals andmore » fuels. RTI, with DOE/NETL support, has been developing an innovative beneficial CO{sub 2} reuse process for converting CO{sub 2} into substitute natural gas (SNG) by using by-product hydrogen (H{sub 2)-containing fuel gas from petrochemical facilities. This process leveraged commercial reactor technology currently used in fluid catalytic crackers in petroleum refining and a novel nickel (Ni)-based catalyst developed by RTI. The goal was to generate an SNG product that meets the pipeline specifications for natural gas, making the SNG product completely compatible with the existing natural gas infrastructure. RTI's technology development efforts focused on demonstrating the technical feasibility of this novel CO{sub 2} reuse process and obtaining the necessary engineering information to design a pilot demonstration unit for converting about 4 tons per day (tons/day) of CO{sub 2} into SNG at a suitable host site. This final report describes the results of the Phase I catalyst and process development efforts. The methanation activity of several commercial fixed-bed catalysts was evaluated under fluidized-bed conditions in a bench-scale reactor to identify catalyst performance targets. RTI developed two fluidizable Ni-based catalyst formulations (Cat-1 and Cat-3) that demonstrated equal or better performance than that of commercial methanation catalysts. The Cat-1 and Cat-3 formulations were successfully scaled up using commercial manufacturing equipment at the Sud-Chemie Inc. pilot-plant facility in Louisville, KY. Pilot transport reactor testing with RTI's Cat-1 formulation at Kellog Brown & Root's Technology Center demonstrated the ability of the process to achieve high single-pass CO{sub 2} conversion. Using information acquired from bench- and pilot-scale testing, a basic engineering design package was prepared for a 4-ton/day CO{sub 2} pilot demonstration unit, including process and instrumentation diagrams, equipment list, control philosophy, and preliminary cost estimate.« less

TiO2 Nanorods Decorated with Pd Nanoparticles for Enhanced Liquefied Petroleum Gas Sensing Performance.

PubMed

Dhawale, Dattatray S; Gujar, Tanaji P; Lokhande, Chandrakant D

2017-08-15

Development of highly sensitive and selective semiconductor-based metal oxide sensor devices to detect toxic, explosive, flammable, and pollutant gases is still a challenging research topic. In the present work, we systematically enhanced the liquefied petroleum gas (LPG) sensing performance of chemical bath deposited TiO 2 nanorods by decorating Pd nanoparticle catalyst. Surface morphology with elemental mapping, crystal structure, composition and oxidation states, and surface area measurements of pristine TiO 2 and Pd:TiO 2 nanorods was examined by high resolution transmission electron microscopy with energy-dispersive X-ray spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and nitrogen adsorption-desorption characterization techniques. LPG sensing performance of pristine TiO 2 and Pd:TiO 2 nanorods was investigated in different LPG concentration and operating temperature ranges. The LPG response of 21% for pristine TiO 2 nanorods is enhanced to 49% after Pd catalyst decoration with reasonably fast response and recovery times. Further, the sensor exhibited long-term stability, which could be due to the strong metal support (Pd:TiO 2 ) interaction and catalytic properties offered by the Pd nanoparticle catalyst. The work described herein demonstrates a general and scalable approach that provides a promising route for rational design of variety of sensor devices for LPG detection.

Petroleum Oils

EPA Pesticide Factsheets

Different types of crude oil and refined product, of all different chemical compositions, have distinct physical properties. These properties affect the way oil spreads and breaks down, its hazard to marine and human life, and the likelihood of threat.

New insides in the characterization of HDS industrial catalysts by HAADF-STEM

NASA Astrophysics Data System (ADS)

Del Angel, Paz; Ponce, Arturo; Arellano, Josefina; Yacaman, Miguel J.; Hernandez-Pichardo, Martha; Montoya, J. Ascencion; Escobar, Jose

2015-03-01

Hydrodesulfurization (HDS) catalysts are of great importance in the petroleum industry. Transition metal sulphides catalysts of Ni(Co)Mo(W)/Al2O3 are widely used for hydrotreating reactions, like hydrodenitrogenation and HDS. One of the main issue in these catalysts is to understand the mechanism of the reaction, where MoS2 plays the most important role in the catalytic activity. We studied an industrial NiMo/Alumina sulfide catalyst highly active by using aberration-corrected HAADF-STEM techniques. The used catalysts was a state-of- the art commercial nickel-molybdenum alumina-supported formulation, including organic agent modifier. This type of material belongs to a novel family of catalysts specially designed for ultra-low sulfur production from straight-run gas oil (SRGO), cycle oil, coker gas oil, or their combinations at operating conditions of commercial interest in hydrotreating units at industrial scale. Aberration corrected HAADF-STEM allowed to observe the nanostructure and location of MoS2 and his interaction with the alumina. The results indicate that the MoS2 is highly dispersed on the alumina, however the location of Ni is one of the task of this kind of catalyst.

Preparation and characterization of bi-metallic nanoparticle catalyst having better anti-coking properties using reverse micelle technique

NASA Astrophysics Data System (ADS)

Zacharia, Thomas

Energy needs are rising on an exponential basis. The mammoth energy sources like coal, natural gas and petroleum are the cause of pollution. The large outcry for an alternate energy source which is environmentally friendly and energy efficient is heard during the past few years. This is where “Clean-Fuel” like hydrogen gained its ground. Hydrogen is mainly produced by steam methane reforming (SMR). An alternate sustainable process which can reduce the cost as well as eliminate the waste products is Tri-reforming. In both these reforming processes nickel is used as catalyst. However as the process goes on the catalyst gets deactivated due to coking on the catalytic surface. This goal of this thesis work was to develop a bi-metallic catalyst which has better anti-coking properties compared to the conventional nickel catalyst. Tin was used to dope nickel. It was found that Ni3Sn complex around a core of Ni is coking resistant compared to pure nickel catalyst. Reverse micelle synthesis of catalyst preparation was used to control the size and shape of catalytic particles. These studies will benefit researches on hydrogen production and catalyst manufactures who work on different bi-metallic combinations.

Liquefaction of kraft lignin by hydrocracking with simultaneous use of a novel dual acid-base catalyst and a hydrogenation catalyst.

PubMed

Wang, Jindong; Li, Wenzhi; Wang, Huizhen; Ma, Qiaozhi; Li, Song; Chang, Hou-Min; Jameel, Hasan

2017-11-01

In this study, a novel catalyst, S 2 O 8 2- -KNO 3 /TiO 2 , which has active acidic and basic sites, was prepared and used in lignin hydrocracking with a co-catalyst, Ru/C. Ru/C is an efficient hydrogenation catalyst and S 2 O 8 2- -KNO 3 /TiO 2 is a dual catalyst, which could efficiently degrade lignin. This catalytic hydrogenation system can reduce solid products to less than 1%, while giving a high liquid product yield of 93%. Catalytic hydrocracking of kraft lignin at 320°C for 6h gave 93% liquid product with 0.5% solid product. Most of this liquid product was soluble in petroleum ether (60% of 93%), which is a clear liquid and comprises mainly of monomeric and dimeric degradation products. These results demonstrated that the combination of the two catalysts is an efficient catalyst for liquefaction of lignin, with little char formation (∼1%). This concept has the potential to produce valuable chemicals and fuels from lignin under moderate conditions. Copyright © 2017 Elsevier Ltd. All rights reserved.

REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1998-09-01

A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it maymore » adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.« less

Evaluation of biochars by temperature programmed oxidation/mass spectrometry

Treesearch

Michael Jackson; Thomas Eberhardt; Akwasi Boateng; Charles Mullen; Les Groom

2013-01-01

Biochars produced from thermochemical conversions of biomass were evaluated by temperature programmed oxidation (TPO). This technique, used to characterize carbon deposits on petroleum cracking catalysts, provides information on the oxidative stability of carbonaceous solids, where higher temperature reactivity indicates greater structural order, an important property...

27 CFR 21.127 - Shellac (refined).

Code of Federal Regulations, 2014 CFR

2014-04-01

... Gutzeit Method (AOAC method 25.020; for incorporation by reference, see § 21.6(c)). (b) Color. White or... layer (at least 50 ml) and filter if cloudy. Evaporate the petroleum ether and test as follows: Solution...

27 CFR 21.127 - Shellac (refined).

Code of Federal Regulations, 2012 CFR

2012-04-01

... Gutzeit Method (AOAC method 25.020; for incorporation by reference, see § 21.6(c)). (b) Color. White or... layer (at least 50 ml) and filter if cloudy. Evaporate the petroleum ether and test as follows: Solution...

27 CFR 21.127 - Shellac (refined).

Code of Federal Regulations, 2011 CFR

2011-04-01

... Gutzeit Method (AOAC method 25.020; for incorporation by reference, see § 21.6(c)). (b) Color. White or... layer (at least 50 ml) and filter if cloudy. Evaporate the petroleum ether and test as follows: Solution...

27 CFR 21.127 - Shellac (refined).

Code of Federal Regulations, 2013 CFR

2013-04-01

... Gutzeit Method (AOAC method 25.020; for incorporation by reference, see § 21.6(c)). (b) Color. White or... layer (at least 50 ml) and filter if cloudy. Evaporate the petroleum ether and test as follows: Solution...

Refining of Military Jet Fuels from Shale Oil. Volume I. Part II. Preparation of Laboratory-Scale Fuel Samples.

DTIC Science & Technology

1982-03-01

ON SPEC Meeting Specifications *1 OXY Test Series on In Situ Shale Oil P Pressure (P + N) Paraffins and Naphthenes PHO Test Series on Above-Ground...material, the crude shale is heated and processed through caustic desalt- ing similar to conventional technology. The desalted oil is mixed with recycle...with hot regenerated catalyst. Spent catalyst and oil vapors are disengaqed by -.eans of high temperature cyclones. The spent catalyst first passes

Synthesis of biodiesel from a model waste oil feedstock using a carbon-based solid acid catalyst: reaction and separation.

PubMed

Shu, Qing; Nawaz, Zeeshan; Gao, Jixian; Liao, Yuhui; Zhang, Qiang; Wang, Dezheng; Wang, Jinfu

2010-07-01

A solid acid catalyst that can keep high activity and stability is necessary when low cost feedstocks are utilized for biodiesel synthesis because the reaction medium contains a large amount of water. Three solid acid catalysts were prepared by the sulfonation of carbonized vegetable oil asphalt and petroleum asphalt. The structure of these catalysts was characterized by a variety of techniques. A new process that used the coupling of the reaction and separation was employed, which greatly improved the conversion of cottonseed oil (triglyceride) and free fatty acids (FFA) when a model waste oil feedstock was used. The vegetable oil asphalt-based catalyst showed the highest catalytic activity. This was due to the high density and stability of its acid sites, its loose irregular network, its hydrophobicity that prevented the hydration of -OH species, and large pores that provided more acid sites for the reactants. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

The Potential of Biodiesel Production derived from Fish Waste

NASA Astrophysics Data System (ADS)

Farzana Samat, Amira; Amirah Safiah Muhamad, Nor; Rasib, Nur Aziera Abd; Hassan, Siti Aminah Mohd; Sohaimi, Khairunissa Syairah Ahmad; Izzati Iberahim, Nur

2018-03-01

Petroleum based diesel is one of the largest greenhouse emitters in the worlds based on its contribution to more likely of all carbon, methane and other greenhouse emissions. Besides, the depletion of fossil fuel that indirectly increased its price has force the global oil industry not to be so dependent on the fossil fuel but instead start focusing on alternative sources. Biodiesel is recognized as a clean alternative fuel or as a fuel additive to reduce pollutant from combustion equipment. In this study, the discarded parts of mixed marine fish species were used as the raw material to produce biodiesel. Marine fish oil was extracted from the discarded part of fish and if refined through a series of pretreatment process. The refined marine fish oil undergoes esterification process to reduce the amount of free fatty acid. The oil was then transesterified with methanol and sodium hydroxide as an alkaline catalyst that will speed up the conversion of oil to methyl ester. The three process parameters considered for this study were reaction time, reaction temperature and methanol to oil molar ratio. Biodiesel obtained was then analyzed using gas chromatography (GC). Statistical analyses were performed using SPSS software. The data obtained was analyzed by using one way analysis of variance (ANOVA) repeated measure. The results obtained showed that the conversion of FAME yield is the highest at reaction time 180 minutes, reaction temperature 60°C and methanol to oil molar ratio at 15:1 with FAME yield 80.16%, 80.03% and 80.39%. Thus, it can be concluded that the conversion of biodiesel increased as the reaction time, temperature and

Evaluation of the Liberian Petroleum Refining Company operations: crude oil refining vs product importation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Samuels, G.; Barron, W.F.; Barnes, R.W.

1985-02-01

This report is one of a series of project papers providing background information for an assessment of energy options for Liberia, West Africa. It presents information on a controversial recommendation of the energy assessment - that the only refinery in the country be closed and refined products be imported for a savings of approximately $20 million per year. The report reviews refinery operations, discusses a number of related issues, and presents a detailed analysis of the economics of the refinery operations as of 1982. This analysis corroborates the initial estimate of savings to be gained from importing all refined products.more » 1 reference, 24 tables.« less

Hopkins during SODI-DCMIX 2 Experiment

NASA Image and Video Library

2013-11-30

ISS038-E-009255 (26 Nov. 2013) --- In the International Space Station?s Destiny laboratory, NASA astronaut Michael Hopkins, Expedition 38 flight engineer, prepares to install and activate the Selectable Optics Diagnostic Instrument (SODI) cell array two in the Microgravity Science Glovebox (MSG) for the Selectable Optics Diagnostic Instrument-Diffusion Coefficient in Mixtures 2 (SODI-DCMIX 2) experiment. SODI-DCMIX 2 is supporting research to determine diffusion coefficients in different petroleum field samples and refine petroleum reservoir models to help lead to more efficient extraction of oil resources.

Hopkins during SODI-DCMIX 2 Experiment

NASA Image and Video Library

2013-11-30

ISS038-E-009253 (26 Nov. 2013) --- In the International Space Station’s Destiny laboratory, NASA astronaut Michael Hopkins, Expedition 38 flight engineer, prepares to install and activate the Selectable Optics Diagnostic Instrument (SODI) cell array two in the Microgravity Science Glovebox (MSG) for the Selectable Optics Diagnostic Instrument-Diffusion Coefficient in Mixtures 2 (SODI-DCMIX 2) experiment. SODI-DCMIX 2 is supporting research to determine diffusion coefficients in different petroleum field samples and refine petroleum reservoir models to help lead to more efficient extraction of oil resources.

High-Flux, High Performance H2O2 Catalyst Bed for ISTAR

NASA Technical Reports Server (NTRS)

Ponzo, J.

2005-01-01

On NASA's ISTAR RBCC program packaging and performance requirements exceeded traditional H2O2 catalyst bed capabilities. Aerojet refined a high performance, monolithic 90% H202 catalyst bed previously developed and demonstrated. This approach to catalyst bed design and fabrication was an enabling technology to the ISTAR tri-fluid engine. The catalyst bed demonstrated 55 starts at throughputs greater than 0.60 lbm/s/sq in for a duration of over 900 seconds in a physical envelope approximately 114 of traditional designs. The catalyst bed uses photoetched plates of metal bonded into a single piece monolithic structure. The precise control of the geometry and complete mixing results in repeatable, quick starting, high performing catalyst bed. Three different beds were designed and tested, with the best performing bed used for tri-fluid engine testing.

Review of the development of laser fluorosensors for oil spill application.

PubMed

Brown, Carl E; Fingas, Mervin F

2003-01-01

As laser fluorosensors provide their own source of excitation, they are known as active sensors. Being active sensors, laser fluorosensors can be employed around the clock, in daylight or in total darkness. Certain compounds, such as aromatic hydrocarbons, present in petroleum oils absorb ultraviolet laser light and become electronically excited. This excitation is quickly removed by the process of fluorescence emission, primarily in the visible region of the spectrum. By careful choice of the excitation laser wavelength and range-gated detection at selected emission wavelengths, petroleum oils can be detected and classified into three broad categories: light refined, crude or heavy refined. This paper will review the development of laser fluorosensors for oil spill application, with emphasis on system components such as excitation laser source, and detection schemes that allow these unique sensors to be employed for the detection and classification of petroleum oils. There have been a number of laser fluorosensors developed in recent years, many of which are strictly research and development tools. Certain of these fluorosensors have been ship-borne instruments that have been mounted in aircraft for the occasional airborne mission. Other systems are mounted permanently on aircraft for use in either surveillance or spill response roles.

Recovery of Cobalt from leach solution of spent oil Hydrodesulphurization catalyst using a synergistic system consisting of VersaticTM10 and Cyanex®272

NASA Astrophysics Data System (ADS)

Yuliusman; Ramadhan, I. T.; Huda, M.

2018-03-01

Catalyst are often used in the petroleum refinery industry, especially cobalt-based catalyst such as CoMoX. Every year, Indonesia’s oil industry produces around 1350 tons of spent hydrodesulphurization catalyst in which cobalt makes up for 7%wt. of them. Cobalt is a non-renewable and highly valuable resource. Taking into account the aforementioned reasons, this research was made to recover cobalt from spent hydrodesulphurization catalyst so that it can be reused by industries needing them. The methods used in the recovery of cobalt from the waste catalyst leach solution are liquid-liquid extraction using a synergistic system of VersaticTM 10 and Cyanex®272. Based on the experiments done using the aforementioned methods and materials, the optimum condition for the extraction process: concentration of VersaticTM 10 of 0.35 M, Cyanex®272 of 0.25 M, temperature of 23-25°C (room temperature), and pH of 6 with an extraction percentage of 98.80% and co-extraction of Ni at 93.51%.

Methods of refining natural oils, and methods of producing fuel compositions

DOEpatents

Firth, Bruce E.; Kirk, Sharon E.

2015-10-27

A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent that comprises nitric acid; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.

Navy mobility fuels forecasting system report: World petroleum trade forecasts for the year 2000

DOE Office of Scientific and Technical Information (OSTI.GOV)

Das, S.

1991-12-01

The Middle East will continue to play the dominant role of a petroleum supplier in the world oil market in the year 2000, according to business-as-usual forecasts published by the US Department of Energy. However, interesting trade patterns will emerge as a result of the democratization in the Soviet Union and Eastern Europe. US petroleum imports will increase from 46% in 1989 to 49% in 2000. A significantly higher level of US petroleum imports (principally products) will be coming from Japan, the Soviet Union, and Eastern Europe. Several regions, the Far East, Japan, Latin American, and Africa will import moremore » petroleum. Much uncertainty remains about of the level future Soviet crude oil production. USSR net petroleum exports will decrease; however, the United States and Canada will receive some of their imports from the Soviet Union due to changes in the world trade patterns. The Soviet Union can avoid becoming a net petroleum importer as long as it (1) maintains enough crude oil production to meet its own consumption and (2) maintains its existing refining capacities. Eastern Europe will import approximately 50% of its crude oil from the Middle East.« less

The effects of aniline impurities on monopropellant hydrazine thruster performance

NASA Technical Reports Server (NTRS)

Holcomb, L.; Mattson, L.; Oshiro, R.

1976-01-01

Both a 0.45-N and a 0.9-N thruster representative of the designs being flown on 3-axis stabilized spacecraft were used in testing various grades of hydrazine for the phenomenon of monopropellant hydrazine thruster catalyst bed poisoning. Both designs employed Shell 405 ABSG spontaneous catalyst. It is found that pulse shape distortion can be minimized, if not eliminated, by using aniline-free hydrazine. The mechanisms for both steady-state and pulse-mode performance loss are associated with the formation of a catalyst coke similar to the polycyclic aromatic poisons encountered in the petroleum industry. These poisoning mechanisms are reversible, with high-temperature operation being required to drive off the aniline coke deposits. It is recommended that a purified-grade hydrazine be considered for any mission that imposes operational conditions on a thruster which can result in aniline-induced poisoning of the catalyst bed.

Waste cockle shell as natural catalyst for biodiesel production from jatropha oil

NASA Astrophysics Data System (ADS)

Hadi, Norulakmal Nor; Idrus, Nur Afini; Ghafar, Faridah; Salleh, Marmy Roshaidah Mohd

2017-12-01

Due to the increasing of industrialization and modernization of the world, the demand of petroleum has risen rapidly. The increasing demand for energy and environmental awareness has prompted many researches to embark on alternative fuel platforms that are environmentally acceptable. In this study, jatropha oil was used to produce biodiesel by a new transesterification routine in which cockle shell was used as source of heterogeneous catalyst. The investigation showed the catalyst that was calcined at temperature of 800 °C has the optimum capability to produce high yield. The highest yield of biodiesel production of 93.20 % were obtained by using 1.5 wt% of catalyst. The reaction was conducted at a temperature of 65 °C with the optimum methanol to oil ratio of 6:1. It was found that the physical properties of the biodiesel produced were significant to ASTM standard of fatty acid methyl ester (FAME).

Study of variation grain size in desulfurization process of calcined petroleum coke

NASA Astrophysics Data System (ADS)

Pintowantoro, Sungging; Setiawan, Muhammad Arif; Abdul, Fakhreza

2018-04-01

Indonesia is a country with abundant natural resources, such as mineral mining and petroleum. In petroleum processing, crude oil can be processed into a source of fuel energy such as gasoline, diesel, oil, petroleum coke, and others. One of crude oil potentials in Indonesia is petroleum coke. Petroleum coke is a product from oil refining process. Sulfur reducing process in calcined petroleum cokes can be done by desulfurization process. The industries which have potential to become petroleum coke processing consumers are industries of aluminum smelting (anode, graphite block, carbon mortar), iron riser, calcined coke, foundry coke, etc. Sulfur reducing process in calcined petroleum coke can be done by thermal desulfurization process with alkaline substance NaOH. Desulfurization of petroleum coke process can be done in two ways, which are thermal desulfurization and hydrodesulphurization. This study aims to determine the effect of various grain size on sulfur, carbon, and chemical bond which contained by calcined petroleum coke. The raw material use calcined petroleum coke with 0.653% sulfur content. The grain size that used in this research is 50 mesh, then varied to 20 mesh and 100 mesh for each desulfurization process. Desulfurization are tested by ICP, UV-VIS, and FTIR to determine levels of sulfur, carbon, chemical bonding and sulfur dissolved water which contained in the residual washing of calcined petroleum coke. From various grain size that mentioned before, the optimal value is on 100 mesh grain size, where the sulfur content in petroleum coke is 0.24% and carbon content reaches the highest level of 97.8%. Meanwhile for grain size 100 mesh in the desulfurization process is enough to break the chemical bonds of organic sulfur in petroleum coke.

Carbon and Mo transformations during the synthesis of mesoporous Mo2C/carbon catalysts by carbothermal hydrogen reduction

NASA Astrophysics Data System (ADS)

Wang, Haiyan; Liu, Shida; Liu, Bing; Montes, Vicente; Hill, Josephine M.; Smith, Kevin J.

2018-02-01

The synthesis of mesoporous Mo2C/carbon catalysts by carbothermal hydrogen reduction is reported. Petroleum coke (petcoke) was activated with KOH at 800 °C to obtain high surface area microporous activated petcoke (APC; 2000 m2/g). The APC was wet impregnated with ammonium heptamolybdate (AHM: 10 wt% Mo), dried and reduced in H2 at temperatures from 400 to 800 °C, to yield Mo2C/APC catalysts. Increased reduction temperature increased the Mo2C yield and the mesoporous volume of the Mo2C/APC. At a reduction temperature of 750 °C the mesopore volume of the catalyst doubled compared to the APC support and accounted for 37% of the total pore volume. Maintaining the final CHR temperature for 90 min further increased the Mo2C yield and mesoporosity of the catalyst. The role of Mo2C in the catalytic hydrogenation of the APC and mesopore generation is demonstrated. The activity of the Mo2C/carbon catalysts in the hydrodeoxygenation of 4-methyl phenol increased with increased CHR temperature and catalyst mesoporosity.

Types of Refined Petroleum Products

EPA Pesticide Factsheets

These are derived from crude oils through processes such as catalytic cracking and fractional distillation. Examples described here are gasoline, kerosene, no. 2 fuel oil, no. 4 fuel oil, no. 5 fuel oil, no. 6 fuel oil, and lubricating oil.

77 FR 3762 - Magellan Pipeline Company, L.P.; Notice of Petition for Declaratory Order

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-25

... declaratory order that approves priority committed space and the overall rate structure involving the proposed partial reversal and expansion of Magellan's refined petroleum products pipeline system in Texas to move...

40 CFR 419.31 - Specialized definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Petrochemical Subcategory § 419.31 Specialized... apply. (b) The term petrochemical operations shall mean the production of second-generation petrochemicals (i.e., alcohols, ketones, cumene, styrene, etc.) or first generation petrochemicals and...

40 CFR 419.31 - Specialized definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Petrochemical Subcategory § 419.31 Specialized... apply. (b) The term petrochemical operations shall mean the production of second-generation petrochemicals (i.e., alcohols, ketones, cumene, styrene, etc.) or first generation petrochemicals and...

Impact of refined petroleum spills on water quality, macro-invertebrate and microbial communities of a tropical aquatic environment.

PubMed

Chukwu, L O; Nwachukwu, S C U

2005-07-01

Water quality characteristics, benthic macro-invertebrates and microbial communities of three first order streams in South West Nigeria were investigated to assess the effects of refined petroleum five months after spillage. All physical and chemical conditions except temperature and pH were significantly different (P<0.01) at the upstream control stations and impacted stations reflecting the perturbational stress. The benthic macro-invertebrate fauna were dominated by arthropods, but the faunal spectrum was dissimilar at all the stations studied. Sampling stations at the epicentre of the spill showed considerable reduction in faunal compositions and relative abundance. Generally, the microbial density and diversity were highest in both soil and water samples from impacted sites than in control sites. There was a significantly higher proportion (P < 0.05) of hydrocarbon utilizers in soil than in water samples in all stations except in samples from stations (P<0.05).

Toxicological and ecotoxicological properties of gas-to-liquid (GTL) products. 1. Mammalian toxicology.

PubMed

Boogaard, Peter J; Carrillo, Juan-Carlos; Roberts, Linda G; Whale, Graham F

2017-02-01

Gas-to-liquid (GTL) products are synthetic hydrocarbons produced from natural gas using a Fischer-Tropsch process. This process yields a synthetic crude oil that consists of saturated hydrocarbons, primarily linear alkanes, with increasing amounts of branched (methyl-groups) alkanes as the chains get longer. In addition, small amounts of cycloalkanes (branched cyclopentanes and cyclohexanes) may be formed as the polymerization reaction prolongs. This synthetic crude can subsequently be refined to a range of products very similar to petroleum refining. However, in contrast to their petroleum-derived analogs, GTL products are essentially free of unsaturated or aromatic constituents and also no sulfur-, oxygen-, or nitrogen-containing constituents are present. From a regulatory perspective, GTL products are new substances which require extensive testing to assess their hazardous properties. As a consequence, a wide range of GTL products, covering the entire portfolio of GTL products, have been tested over the past few years in a wide variety of toxicological studies, including reproductive and prenatal development toxicity studies. This review provides an overview of the hazardous properties of the various GTL products. In general, the data collected on GTL products provide strong proof that they exert minimal health effects. In addition, these data provide supporting evidence for what is known on the mechanisms of mammalian toxicology of their petroleum-derived analogs. In the few cases where adverse effects were found for the GTL substances, these were usually less severe than the adverse effects observed with their petroleum-derived analogs.

Transition metal catalysis in the generation of petroleum and natural gas. Progress report, [1992--1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mango, F.

1993-08-01

A new hypothesis is introduced for the generation of petroleum and natural gas. The transition metals, activated under the reducing conditions of diagenesis, are proposed as catalysts in the generation of light hydrocarbons. The objective of this proposal is to test that hypothesis. Transition metals (Ni, V, Ti, Co, Fe), in kerogen, porphyrins, and as pure compounds, will be tested under catagenic conditions for catalytic activity in the conversion of normal paraffins and hydrogen into light hydrocarbons. If the hypothesis is correct, kerogenous transition metals should become catalytically active under the reducing conditions of diagenesis and catalyze the conversion ofmore » paraffins into the light hydrocarbons seen in petroleum. Moreover, the C{sub 1}-C{sub 4} hydrocarbons generated catalytically should be similar in molecular and isotopic compositions to natural gas.« less

Sub-nanometer surface chemistry and orbital hybridization in lanthanum-doped ceria nano-catalysts revealed by 3D electron microscopy.

PubMed

Collins, Sean M; Fernandez-Garcia, Susana; Calvino, José J; Midgley, Paul A

2017-07-14

Surface chemical composition, electronic structure, and bonding characteristics determine catalytic activity but are not resolved for individual catalyst particles by conventional spectroscopy. In particular, the nano-scale three-dimensional distribution of aliovalent lanthanide dopants in ceria catalysts and their effect on the surface electronic structure remains unclear. Here, we reveal the surface segregation of dopant cations and oxygen vacancies and observe bonding changes in lanthanum-doped ceria catalyst particle aggregates with sub-nanometer precision using a new model-based spectroscopic tomography approach. These findings refine our understanding of the spatially varying electronic structure and bonding in ceria-based nanoparticle aggregates with aliovalent cation concentrations and identify new strategies for advancing high efficiency doped ceria nano-catalysts.

76 FR 10329 - Foreign-Trade Zone 3-San Francisco, California; Application for Subzone; Valero Refining Company...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-02-24

... Pier 95, near the Benicia-Martinez Bridge, Benicia. The refinery is used to produce fuels and other petroleum products. Products include gasoline, diesel, jet fuel, propane, butane, fuel oil, residual oil...

On-board measurement of emissions from liquefied petroleum gas, gasoline and diesel powered passenger cars in Algeria.

PubMed

Chikhi, Saâdane; Boughedaoui, Ménouèr; Kerbachi, Rabah; Joumard, Robert

2014-08-01

On-board measurements of unit emissions of CO, HC, NOx and CO₂ were conducted on 17 private cars powered by different types of fuels including gasoline, dual gasoline-liquefied petroleum gas (LPG), gasoline, and diesel. The tests performed revealed the effect of LPG injection technology on unit emissions and made it possible to compare the measured emissions to the European Artemis emission model. A sequential multipoint injection LPG kit with no catalyst installed was found to be the most efficient pollutant reduction device for all of the pollutants, with the exception of the NOx. Specific test results for a sub-group of LPG vehicles revealed that LPG-fueled engines with no catalyst cannot compete with catalyzed gasoline and diesel engines. Vehicle age does not appear to be a determining parameter with regard to vehicle pollutant emissions. A fuel switch to LPG offers many advantages as far as pollutant emissions are concerned, due to LPG's intrinsic characteristics. However, these advantages are being rapidly offset by the strong development of both gasoline and diesel engine technologies and catalyst converters. The LPG's performance on a chassis dynamometer under real driving conditions was better than expected. The enforcement of pollutant emission standards in developing countries is an important step towards introducing clean technology and reducing vehicle emissions. Copyright © 2014. Published by Elsevier B.V.

Assessment of Energy Efficiency Improvement in the United States Petroleum Refining Industry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morrow, William R.; Marano, John; Sathaye, Jayant

2013-02-01

Adoption of efficient process technologies is an important approach to reducing CO 2 emissions, in particular those associated with combustion. In many cases, implementing energy efficiency measures is among the most cost-effective approaches that any refiner can take, improving productivity while reducing emissions. Therefore, careful analysis of the options and costs associated with efficiency measures is required to establish sound carbon policies addressing global climate change, and is the primary focus of LBNL’s current petroleum refining sector analysis for the U.S. Environmental Protection Agency. The analysis is aimed at identifying energy efficiency-related measures and developing energy abatement supply curves andmore » CO 2 emissions reduction potential for the U.S. refining industry. A refinery model has been developed for this purpose that is a notional aggregation of the U.S. petroleum refining sector. It consists of twelve processing units and account s for the additional energy requirements from steam generation, hydrogen production and water utilities required by each of the twelve processing units. The model is carbon and energy balanced such that crud e oil inputs and major refinery sector outputs (fuels) are benchmarked to 2010 data. Estimates of the current penetration for the identified energy efficiency measures benchmark the energy requirements to those reported in U.S. DOE 2010 data. The remaining energy efficiency potential for each of the measures is estimated and compared to U.S. DOE fuel prices resulting in estimates of cost- effective energy efficiency opportunities for each of the twelve major processes. A combined cost of conserved energy supply curve is also presented along with the CO 2 emissions abatement opportunities that exist in the U.S. petroleum refinery sector. Roughly 1,200 PJ per year of primary fuels savings and close to 500 GWh per y ear of electricity savings are potentially cost-effective given U.S. DOE fuel price forecasts. This represents roughly 70 million metric tonnes of CO 2 emission reductions assuming 2010 emissions factor for grid electricity. Energy efficiency measures resulting in an additional 400 PJ per year of primary fuels savings and close to 1,700 GWh per year of electricity savings, and an associated 24 million metric tonnes of CO 2 emission reductions are not cost-effective given the same assumption with respect to fuel prices and electricity emissions factors. Compared to the modeled energy requirements for the U.S. petroleum refining sector, the cost effective potential represents a 40% reduction in fuel consumption and a 2% reduction in electricity consumption. The non-cost-effective potential represents an additional 13% reduction in fuel consumption and an additional 7% reduction in electricity consumption. The relative energy reduction potentials are mu ch higher for fuel consumption than electricity consumption largely in part because fuel is the primary energy consumption type in the refineries. Moreover, many cost effective fuel savings measures would increase electricity consumption. The model also has the potential to be used to examine the costs and benefits of the other CO 2 mitigation options, such as combined heat and power (CHP), carbon capture, and the potential introduction of biomass feedstocks. However, these options are not addressed in this report as this report is focused on developing the modeling methodology and assessing fuels savings measures. These opportunities to further reduce refinery sector CO 2 emissions and are recommended for further research and analysis.« less

Air impacts from three alternatives for producing JP-8 jet fuel.

PubMed

Kositkanawuth, Ketwalee; Gangupomu, Roja Haritha; Sattler, Melanie L; Dennis, Brian H; MacDonnell, Frederick M; Billo, Richard; Priest, John W

2012-10-01

To increase U.S. petroleum energy independence, the University of Texas at Arlington (UT Arlington) has developed a direct coal liquefaction process which uses a hydrogenated solvent and a proprietary catalyst to convert lignite coal to crude oil. This sweet crude can be refined to form JP-8 military jet fuel, as well as other end products like gasoline and diesel. This paper presents an analysis of air pollutants resulting from using UT Arlington's liquefaction process to produce crude and then JP-8, compared with 2 alternative processes: conventional crude extraction and refining (CCER), and the Fischer-Tropsch process. For each of the 3 processes, air pollutant emissions through production of JP-8 fuel were considered, including emissions from upstream extraction/ production, transportation, and conversion/refining. Air pollutants from the direct liquefaction process were measured using a LandTEC GEM2000 Plus, Draeger color detector tubes, OhioLumex RA-915 Light Hg Analyzer, and SRI 8610 gas chromatograph with thermal conductivity detector. According to the screening analysis presented here, producing jet fuel from UT Arlington crude results in lower levels of pollutants compared to international conventional crude extraction/refining. Compared to US domestic CCER, the UTA process emits lower levels of CO2-e, NO(x), and Hg, and higher levels of CO and SO2. Emissions from the UT Arlington process for producing JP-8 are estimated to be lower than for the Fischer-Tropsch process for all pollutants, with the exception of CO2-e, which were high for the UT Arlington process due to nitrous oxide emissions from crude refining. When comparing emissions from conventional lignite combustion to produce electricity, versus UT Arlington coal liquefaction to make JP-8 and subsequent JP-8 transport, emissions from the UT Arlington process are estimated to be lower for all air pollutants, per MJ of power delivered to the end user. The United States currently imports two-thirds of its crude oil, leaving its transportation system especially vulnerable to disruptions in international crude supplies. At current use rates, U.S. coal reserves (262 billion short tons, including 23 billion short tons lignite) would last 236 years. Accordingly, the University of Texas at Arlington (UT Arlington) has developed a process that converts lignite to crude oil, at about half the cost of regular crude. According to the screening analysis presented here, producing jet fuel from UT Arlington crude generates lower levels of pollutants compared to international conventional crude extraction/refining (CCER).

Reducing power production costs by utilizing petroleum coke. Annual report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Galbreath, K.C.

1998-07-01

A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it maymore » adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.« less

Hydrocarbon-soluble low-melting corrosion inhibitor TAL-3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nesterenko, S.A.; Sorokin, V.I.; Naumenko, O.V.

1987-03-01

The inhibitor TAL-3 is intended for the corrosion protection of metals that come into contact with two-phase systems of the hydrocarbon-water type. It is applicable to the service conditions of equipment and pipelines of the petroleum and petroleum refining industries. The purpose of this paper was to electrochemically assess its solubility in such systems and its inhibitory properties on samples of 08kp steel toward the effects of refinery and oil field waste water and process emulsions both on the laboratory scale and in field tests.

40 CFR 419.21 - Specialized definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Specialized definitions. 419.21 Section 419.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.21 Specialized definitions...

40 CFR 419.21 - Specialized definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Specialized definitions. 419.21 Section 419.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.21 Specialized definitions...

Reformulated diesel fuel and method

DOEpatents

McAdams, Hiramie T [Carrollton, IL; Crawford, Robert W [Tucson, AZ; Hadder, Gerald R [Oak Ridge, TN; McNutt, Barry D [Arlington, VA

2006-08-22

A method for mathematically identifying at least one diesel fuel suitable for combustion in an automotive diesel engine with significantly reduced emissions and producible from known petroleum blendstocks using known refining processes, including the use of cetane additives (ignition improvers) and oxygenated compounds.

77 FR 43614 - Notice of Lodging of Consent Decree Pursuant to the Clean Air Act

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-25

... (``LDAR'') for hazardous air pollutants, 40 CFR Part 63, Subparts A, H and CC, at an asphalt petroleum... penalty. In addition, although the plant has not refined asphalt since 2008, Chevron agrees to implement...

40 CFR 60.16 - Priority list.

Code of Federal Regulations, 2012 CFR

2012-07-01

... production 21. Vegetable Oil 22. Industrial Surface Coating: Metal Coil 23. Petroleum Transportation and... Coating: Automobiles 28. Industrial Surface Coating: Large Appliances 29. Crude Oil and Natural Gas... 53. Starch 54. Perlite 55. Phosphoric Acid: Thermal Process (Deleted) 56. Uranium Refining 57. Animal...

40 CFR 60.16 - Priority list.

Code of Federal Regulations, 2011 CFR

2011-07-01

... production 21. Vegetable Oil 22. Industrial Surface Coating: Metal Coil 23. Petroleum Transportation and... Coating: Automobiles 28. Industrial Surface Coating: Large Appliances 29. Crude Oil and Natural Gas... 53. Starch 54. Perlite 55. Phosphoric Acid: Thermal Process (Deleted) 56. Uranium Refining 57. Animal...

40 CFR 60.16 - Priority list.

Code of Federal Regulations, 2013 CFR

2013-07-01

... production 21. Vegetable Oil 22. Industrial Surface Coating: Metal Coil 23. Petroleum Transportation and... Coating: Automobiles 28. Industrial Surface Coating: Large Appliances 29. Crude Oil and Natural Gas... 53. Starch 54. Perlite 55. Phosphoric Acid: Thermal Process (Deleted) 56. Uranium Refining 57. Animal...

40 CFR 60.16 - Priority list.

Code of Federal Regulations, 2014 CFR

2014-07-01

... production 21. Vegetable Oil 22. Industrial Surface Coating: Metal Coil 23. Petroleum Transportation and... Coating: Automobiles 28. Industrial Surface Coating: Large Appliances 29. Crude Oil and Natural Gas... 53. Starch 54. Perlite 55. Phosphoric Acid: Thermal Process (Deleted) 56. Uranium Refining 57. Animal...

Methods for suppressing isomerization of olefin metathesis products

DOEpatents

Firth, Bruce E.; Kirk, Sharon E.

2015-10-27

A method for suppressing isomerization of an olefin metathesis product produced in a metathesis reaction includes adding an isomerization suppression agent that includes nitric acid to a mixture that includes the olefin metathesis product and residual metathesis catalyst from the metathesis reaction under conditions that are sufficient to passivate at least a portion of the residual metathesis catalyst. Methods of refining a natural oil are described.

Complex organic matter in space: about the chemical composition of carriers of the Unidentified Infrared Bands (UIBs) and protoplanetary emission spectra recorded from certain astrophysical objects.

PubMed

Cataldo, Franco; Keheyan, Yeghis; Heymann, Dieter

2004-02-01

In this communication we present the basic concept that the pure PAHs (Polycyclic Aromatic Hydrocarbons) can be considered only the ideal carriers of the UIBs (Unidentified Infrared Bands), the emission spectra coming from a large variety of astronomical objects. Instead we have proposed that the carriers of UIBs and of protoplanetary nebulae (PPNe) emission spectra are much more complex molecular mixtures possessing also complex chemical structures comparable to certain petroleum fractions obtained from the petroleum refining processes. The demonstration of our proposal is based on the comparison between the emission spectra recorded from the protoplanetary nebulae (PPNe) IRAS 22272+ 5435 and the infrared absorption spectra of certain 'heavy' petroleum fractions. It is shown that the best match with the reference spectrum is achieved by highly aromatic petroleum fractions. It is shown that the selected petroleum fractions used in the present study are able to match the band pattern of anthracite coal. Coal has been proposed previously as a model for the PPNe and UIBs but presents some drawbacks which could be overcome by adopting the petroleum fractions as model for PPNe and UIBs in place of coal. A brief discussion on the formation of the petroleum-like fractions in PPNe objects is included.

Platform Chemicals from an Oilseed Biorefinery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tupy, Mike; Schrodi Yann

2006-11-06

The US chemical industry is $460 billion in size where a $150 billion segment of which is non-oxygenated chemicals that is sourced today via petroleum but is addressable by a renewable feedstock if one considers a more chemically reduced feedstock such as vegetable oils. Vegetable oil, due to its chemical functionality, provides a largely untapped opportunity as a renewable chemical source to replace petroleum-derived chemicals and produce platform chemicals unavailable today. This project examined the fertile intersection between the rich building blocks provided by vegetable oils and the enhanced chemical modification capability provided by metathesis chemistry. The technology advanced inmore » this study is the process of ethylene cross-metathesis (referred to as ethenolysis) with vegetable oil and vegetable oil derivatives to manufacture the platform-chemical 9-decenoic acid (or 9DA) and olefin co-products. The project team meet its goals of demonstrating improved catalyst efficiencies of several multiples, deepening the mechanistic understanding of metathesis, synthesis and screening of dozens of new catalysts, designing and modeling commercial processes, and estimating production costs. One demonstrable result of the study was a step change improvement in catalyst turnover number in the ethenolysis of methyl oleate as reported here. We met our key measurable of producing 100 lbs of 9DA at the pilot-scale, which demonstrated ability to scale-up ethenolysis. DOE Project funding had significant positive impact on development of metathetically modified vegetable oils more broadly as the Cargill/Materia partnership, that was able to initiate primarily due to DOE funding, has succeeded in commercializing products, validating metathesis as a platform technology, and expanding a diverse products portfolio in high value and in large volume markets. Opportunities have expanded and business development has gained considerable momentum and enabled further expansion of the Materia/Cargill relationship. This project exceeded expectations and is having immediate impact on DOE success by replacing petroleum products with renewables in a large volume application today.« less

Field-to-Fuel Performance Testing of Lignocellulosic Feedstocks for Fast Pyrolysis and Upgrading: Techno-economic Analysis and Greenhouse Gas Life Cycle Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyer, Pimphan A.; Snowden-Swan, Lesley J.; Rappé, Kenneth G.

This work shows preliminary results from techno-economic analysis and life cycle greenhouse gas analysis of the conversion of seven (7) biomass feedstocks to produce liquid transportation fuels via fast pyrolysis and upgrading via hydrodeoxygenation. The biomass consists of five (5) pure feeds (pine, tulip poplar, hybrid poplar, switchgrass, corn stover) and two blends. Blend 1 consists of equal weights of pine, tulip poplar and switchgrass, and blend 2 is 67% pine and 33% hybrid poplar. Upgraded oil product yield is one of the most significant parameters affecting the process economics, and is a function of both fast pyrolysis oil yieldmore » and hydrotreating oil yield. Pure pine produced the highest overall yield, while switchgrass produced the lowest. Interestingly, herbaceous materials blended with woody biomass performed nearly as well as pure woody feedstock, suggesting a non-trivial relationship between feedstock attributes and production yield. Production costs are also highly dependent upon hydrotreating catalyst-related costs. The catalysts contribute an average of ~15% to the total fuel cost, which can be reduced through research and development focused on achieving performance at increased space velocity (e.g., reduced catalyst loading) and prolonging catalyst lifetime. Green-house-gas reduction does not necessarily align with favorable economics. From the greenhouse gas analysis, processing tulip poplar achieves the largest GHG emission reduction relative to petroleum (~70%) because of its lower hydrogen consumption in the upgrading stage that results in a lower natural gas requirement for hydrogen production. Conversely, processing blend 1 results in the smallest GHG emission reduction from petroleum (~58%) because of high natural gas demand for hydrogen production.« less

Iron catalyzed coal liquefaction process

DOEpatents

Garg, Diwakar; Givens, Edwin N.

1983-01-01

A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

Vapor-phase catalytic oxidesulfurization (ODS) of organosulfur compounds over supported metal oxide catalysts

NASA Astrophysics Data System (ADS)

Choi, Sukwon

Sulfur in transportation fuels remains a leading source of SOx emissions from vehicle engines and is a major source of air pollution. The very low levels of sulfur globally mandated for transportation fuels in the near future cannot be achieved by current practices of hydrodesulfurization (HDS) for sulfur removal, which operate under severe conditions (high T, P) and use valuable H2. Novel vapor-phase catalytic oxidesulfurization (ODS) processes of selectively oxidizing various organosulfur compounds (carbonyl sulfide, carbon disulfide, methanethiol, dimethyl sulfide (DMS), dimethyl disulfide (DMDS), thiophene, 2,5-dimenthylthiophene) typically found in various industrial streams (e.g., petroleum refining, pulp and paper) into valuable chemical intermediates (H 2CO, CO, H2, maleic anhydride and concentrated SO2) has been extensively studied. This research has primarily focused on establishing the fundamental kinetics and mechanisms of these selective oxidation reactions over well-defined supported metal oxide catalysts. The selective oxidation reactions of COS + O2 → CO + SO2; 2CS2 + 5O2 → 2CO + 4SO2; CH3SH + 2O 2 → H2CO + SO2 + H2O; C4 H4S + 3O2 → C4H2O 3 + H2O + SO2; were studied. Raman spectroscopy revealed that the supported metal oxide phases were 100% dispersed on the oxide substrate. All the catalysts were highly active and selective for the oxidesulfurization of carbonyl sulfide, carbon disulfide, methanethiol, and thiophene between 290--330°C, 230--270°C, 350--400°C, and 250--400°C, respectively and did not deactivate. The TOFs (turnover frequency, normalized activity per active catalytic site) for all ODS reactions over supported vanadia catalysts, only containing molecularly dispersed surface vanadia species, varied within one order of magnitude and revealed the V-O-Support bridging bond was involved in the critical rate-determining kinetic steps. The surface reaction mechanism for each reaction was revealed by in situ IR (infrared) and temperature programmed surface reaction-mass spectroscopy (TPSR-MS). The systematic investigation of vapor-phase oxidesulfurization (ODS) reactions of organosulfur compounds over catalytic supported metal oxides revealed the facile S-O exchange mechanisms allow for the efficient removal of sulfur while producing value-added chemicals and represents the discovery of a new series of catalytic reactions.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grubbs, Robert H

Over the past decade, a new family of homogeneous metathesis catalysts has been developed that will tolerate most organic functionalities as well as water and air. These homogeneous catalysts are finding numerous applications in the pharmaceutical industry as well as in the production of functional polymers. In addition the catalysts are being used to convert seed oils into products that can substitute for those that are now made from petroleum products. Seed oils are unsaturated, contain double bonds, and are a ready source of linear hydrocarbon fragments that are specifically functionalized. To increase the number of applications in the areamore » of biomaterial conversion to petrol chemicals, the activity and efficiency of the catalysts need to be as high as possible. The higher the efficiency of the catalysts, the lower the cost of the conversion and a larger number of practical applications become available. Active supported catalysts were prepared and tested in the conversion of seed oils and other important starting materials. The outcome of the work was successful and the technology has been transferred to a commercial operation to develop viable applications of the discovered systems. A biorefinery that converts seed oils is under construction in Indonesia. The catalysts developed in this study will be considered for the next generation of operations.« less

40 CFR 419.20 - Applicability; description of the cracking subcategory.

Code of Federal Regulations, 2010 CFR

2010-07-01

... cracking subcategory. 419.20 Section 419.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.20 Applicability; description of the cracking subcategory. The provisions of this subpart are...

40 CFR 419.20 - Applicability; description of the cracking subcategory.

Code of Federal Regulations, 2011 CFR

2011-07-01

... cracking subcategory. 419.20 Section 419.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.20 Applicability; description of the cracking subcategory. The provisions of this subpart are...

40 CFR 63.5935 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... plating; semiconductor manufacturing; petroleum production, refining, and storage; mining; textile... manufacture, it must be used for repair or replacement, and the manufacturing schedule must be based on the... National Emissions Standards for Hazardous Air Pollutants: Reinforced Plastic Composites Production Other...

Hazardous Waste Cleanup: Buckeye Caribbean Terminals Incorporated in Yabucoa, Puerto Rico

EPA Pesticide Factsheets

The Buckeye Caribbean Terminals, Inc. (formerly Shell Chemical Yabucoa, Inc.) is located on Road 901 about two miles east of the town of Yabucoa, Puerto Rico. Petroleum refining operations have been in progress at the site since May 1971.

10 CFR 209.21 - Purpose and scope.

Code of Federal Regulations, 2011 CFR

2011-01-01

... OF ENERGY OIL INTERNATIONAL VOLUNTARY AGREEMENTS Development of Voluntary Agreements § 209.21 Purpose... business of producing, transporting, refining, distributing. or storing petroleum products shall develop... International Energy Program. (b) This subpart does not apply to meetings of bodies created by the International...

10 CFR 209.21 - Purpose and scope.

Code of Federal Regulations, 2010 CFR

2010-01-01

... OF ENERGY OIL INTERNATIONAL VOLUNTARY AGREEMENTS Development of Voluntary Agreements § 209.21 Purpose... business of producing, transporting, refining, distributing. or storing petroleum products shall develop... International Energy Program. (b) This subpart does not apply to meetings of bodies created by the International...

Too much FCC catalyst activity can cut yields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wichers, W.R.; Upson, L.

1984-03-19

For many people working in the field of catalytic cracking, high equilibrium catalyst activity is inherently good. It is surprising how many times this line of reasoning is accepted by the refiner. There also seems to be something psychologically satisfying in seeing an equilibrium catalyst report where the catalyst activity is reported as a high number. Generally, everyone is happy when the reported activity of equilibrium catalyst is increasing and unhappy when it is going down. In the past, increasing catalyst activity did result in improved operations. For units that operated with substantial amounts of bed cracking, higher activity catalystmore » allowed the amount of bed cracking to be reduced and the relative amount of cracking that occurred in the riser to be increased. The switch from bed to riser cracking decreased catalytic coke make and gasoline overcracking, thus reducing regenerator temperature and improving gasoline yields.« less

Petroleum contaminated water and health symptoms: a cross-sectional pilot study in a rural Nigerian community.

PubMed

Kponee, Kalé Zainab; Chiger, Andrea; Kakulu, Iyenemi Ibimina; Vorhees, Donna; Heiger-Bernays, Wendy

2015-11-06

The oil-rich Niger Delta suffers from extensive petroleum contamination. A pilot study was conducted in the region of Ogoniland where one community, Ogale, has drinking water wells highly contaminated with a refined oil product. In a 2011 study, the United Nations Environment Programme (UNEP) sampled Ogale drinking water wells and detected numerous petroleum hydrocarbons, including benzene at concentrations as much as 1800 times higher than the USEPA drinking water standard. UNEP recommended immediate provision of clean drinking water, medical surveillance, and a prospective cohort study. Although the Nigerian government has provided emergency drinking water, other UNEP recommendations have not been implemented. We aimed to (i) follow up on UNEP recommendations by investigating health symptoms associated with exposure to contaminated water; and (ii) assess the adequacy and utilization of the government-supplied emergency drinking water. We recruited 200 participants from Ogale and a reference community, Eteo, and administered questionnaires to investigate water use, perceived water safety, and self-reported health symptoms. Our multivariate regression analyses show statistically significant associations between exposure to Ogale drinking water and self-reported health symptoms consistent with petroleum exposure. Participants in Ogale more frequently reported health symptoms related to neurological effects (OR = 2.8), hematological effects (OR = 3.3), and irritation (OR = 2.7). Our results are the first from a community relying on drinking water with such extremely high concentrations of benzene and other hydrocarbons. The ongoing exposure and these pilot study results highlight the need for more refined investigation as recommended by UNEP.

Synthesis of fatty acid methyl ester from crude jatropha (Jatropha curcas Linnaeus) oil using aluminium oxide modified Mg-Zn heterogeneous catalyst.

PubMed

Olutoye, M A; Hameed, B H

2011-06-01

The synthesis of fatty acid methyl esters (FAME) as a substitute to petroleum diesel was investigated in this study from crude jatropha oil (CJO), a non-edible, low-cost alternative feedstock, using aluminium modified heterogeneous basic oxide (Mg-Zn) catalyst. The transesterification reaction with methanol to methyl esters yielded 94% in 6h with methanol-oil ratio of 11:1, catalyst loading of 8.68 wt.% at 182°C and the properties of CJO fuel produced were determine and found to be comparable to the standards according to ASTM. In the range of experimental parameters investigated, it showed that the catalyst is selective to production of methyl esters from oil with high free fatty acid (FFA) and water content of 7.23% and 3.28%, respectively in a single stage process. Thus, jatropha oil is a promising feedstock for methyl ester production and large scale cultivation will help to reduce the product cost. Copyright © 2011 Elsevier Ltd. All rights reserved.

Production of hydrocarbon fuels from pyrolysis of soybean oils using a basic catalyst.

PubMed

Xu, Junming; Jiang, Jianchun; Sun, Yunjuan; Chen, Jie

2010-12-01

Triglycerides obtained from animals and plants have attracted great attention from researchers for developing an environmental friendly and high-quality fuel, free of nitrogen and sulfur. In the present work, the production of biofuel by catalytic cracking of soybean oil over a basic catalyst in a continuous pyrolysis reactor at atmospheric pressure has been studied. Experiments were designed to study the effect of different types of catalysts on the yield and acid value of the diesel and gasoline fractions from the pyrolytic oil. It was found that basic catalyst gave a product with relatively low acid number. These pyrolytic oils were also further reacted with alcohol in order to decrease their acid value. After esterification, the physico-chemical properties of these biofuels were characterized, and compared with Chinese specifications for conventional diesel fuels. The results showed that esterification of pyrolytic oil from triglycerides represents an alternative technique for producing biofuels from soybean oils with characteristics similar to those of petroleum fuels. Published by Elsevier Ltd.

Organic chemistry. A rhodium catalyst for single-step styrene production from benzene and ethylene.

PubMed

Vaughan, Benjamin A; Webster-Gardiner, Michael S; Cundari, Thomas R; Gunnoe, T Brent

2015-04-24

Rising global demand for fossil resources has prompted a renewed interest in catalyst technologies that increase the efficiency of conversion of hydrocarbons from petroleum and natural gas to higher-value materials. Styrene is currently produced from benzene and ethylene through the intermediacy of ethylbenzene, which must be dehydrogenated in a separate step. The direct oxidative conversion of benzene and ethylene to styrene could provide a more efficient route, but achieving high selectivity and yield for this reaction has been challenging. Here, we report that the Rh catalyst ((Fl)DAB)Rh(TFA)(η(2)-C2H4) [(Fl)DAB is N,N'-bis(pentafluorophenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene; TFA is trifluoroacetate] converts benzene, ethylene, and Cu(II) acetate to styrene, Cu(I) acetate, and acetic acid with 100% selectivity and yields ≥95%. Turnover numbers >800 have been demonstrated, with catalyst stability up to 96 hours. Copyright © 2015, American Association for the Advancement of Science.

Chemical Conversions of Biomass-Derived Platform Chemicals over Copper-Silica Nanocomposite Catalysts.

PubMed

Upare, Pravin P; Hwang, Young Kyu; Lee, Jong-Min; Hwang, Dong Won; Chang, Jong-San

2015-07-20

Biomass and biomass-derived carbohydrates have a high extent of functionality, unlike petroleum, which has limited functionality. In biorefinery applications, the development of methods to control the extent of functionality in final products intended for use as fuels and chemicals is a challenge. In the chemical industry, heterogeneous catalysis is an important tool for the defunctionalization of functionalized feedstocks and biomass-derived platform chemicals to produce value-added chemicals. Herein, we review the recent progress in this field, mainly of vapor phase chemical conversion of biomass-derived C4 -C6 carboxylic acids and esters using copper-silica nanocomposite catalysts. We also demonstrate that these nanocomposite catalysts very efficiently convert biomass-derived platform chemicals into cyclic compounds, such as lactones and hydrofurans, with high selectivities and yields. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Direct Conversion of Cellulose into Ethyl Lactate in Supercritical Ethanol-Water Solutions.

PubMed

Yang, Lisha; Yang, Xiaokun; Tian, Elli; Lin, Hongfei

2016-01-08

Biomass-derived ethyl lactate is a green solvent with a growing market as the replacement for petroleum-derived toxic organic solvents. Here we report, for the first time, the production of ethyl lactate directly from cellulose with the mesoporous Zr-SBA-15 silicate catalyst in a supercritical mixture of ethanol and water. The relatively strong Lewis and weak Brønsted acid sites on the catalyst, as well as the surface hydrophobicity, were beneficial to the reaction and led to synergy during consecutive reactions, such as depolymerization, retro-aldol condensation, and esterification. Under the optimum reaction conditions, ∼33 % yield of ethyl lactate was produced from cellulose with the Zr-SBA-15 catalyst at 260 °C in supercritical 95:5 (w/w) ethanol/water. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Methods of refining natural oils and methods of producing fuel compositions

DOEpatents

Firth, Bruce E; Kirk, Sharon E; Gavaskar, Vasudeo S

2015-11-04

A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent selected from the group consisting of phosphorous acid, phosphinic acid, and a combination thereof; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.

40 CFR 261.4 - Exclusions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... exclusion from the definition of solid waste. (18) Petrochemical recovered oil from an associated organic... for benzene (§ 261.24, waste code D018); and (ii) The oil generated by the organic chemical... petroleum refining process. An “associated organic chemical manufacturing facility” is a facility where the...

40 CFR 419.37 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Pretreatment standards for new sources (PSNS). 419.37 Section 419.37 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Petrochemical Subcategory § 419...

40 CFR 419.35 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Pretreatment standards for existing sources (PSES). 419.35 Section 419.35 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Petrochemical Subcategory § 419...

Effects of Removing Restrictions on U.S. Crude Oil Exports

EIA Publications

2015-01-01

This report examines the implications of removing current restrictions on U.S. crude oil exports for the price of domestic and global marker crude oil streams, gasoline prices, domestic crude oil production, domestic refining activity, and trade in crude oil and petroleum products.

Modest Labor-Management Bargains Continue in 1984 Despite the Recovery.

ERIC Educational Resources Information Center

Ruben, George

1985-01-01

Major collective bargaining agreements in 1984 resulted in modest settlements, due to concern about foreign competition, domestic deregulation, and inflation. Agreements occurred in the following industries: auto, soft coal, airlines, aircraft and aerospace, construction, petroleum refining, longshore industry, railroads, trucking, steel, West…

Morocco Country Analysis Brief

EIA Publications

2014-01-01

Morocco is a net hydrocarbon importer. The country produces marginal amounts of oil, natural gas, and refined petroleum products, which is mainly consumed domestically. Morocco has two refineries with a total crude oil distillation capacity of about 155,000 barrels per day (bbl/d), according to Oil & Gas Journal.

ZnO nanorods as catalyts for biodiesel production from olive oil

NASA Astrophysics Data System (ADS)

Molina, Carmen Maria Miralda

The motivation to determine a viable alternative to petroleum based energy has risen in recent years due to increased greenhouse gas emissions, environmental pollution, and the fear of exhausting oil and natural gas reserves. Biodiesel derived from the transesterification of vegetable oils or animal fats has emerged as a viable alternative to petroleum diesel. However, for this to become an option available to the average consumer it is vital to find an effective catalyst. Metal oxides have emerged as potential heterogeneous catalysts. ZnO in particular is attractive because it is abundant. The use of nanostructures has been shown to improve the catalytic performance of ZnO. ZnO nanorods were synthesized using a solution approach. The crystalline structure, morphology, and surface area were confirmed using XRD, SEM, and BET surface area respectively. The characterized nanorods were used as catalysts for the production of biodiesel. The nanorods achieved conversions of 94.8% at 150°C for reaction times of eight hours. They also demonstrated better catalytic performance, attributed to their increased degree of crystallinity, than conventional ZnO. A kinetic study at 150°C to determine the reaction rate parameters was also conducted. Due to the presence of three distinct phases in the reaction, initially the reaction rate is dominated by mass transfer limitations. However, these are eventually overcome and the reaction proceeds with a pseudo-first order with respect to the oil and a reaction rate constant of 0.5136 h-1.

Refinery suppliers face tough times

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rotman, D.; Walsh, K.

1997-03-12

Despite a handful of bright spots in hydroprocessing and petrochemical sectors, economic woes plague much of the refinery and petrochemical catalysts business, as suppliers are feeling the impact of mature markets and refiners` ongoing cost cutting. Industry experts say the doldrums could spur further restructuring in the catalyst business, with suppliers scrambling for market share and jockeying for position in growing sectors. Expect further consolidation over the next several years, says Pierre Bonnifay, president of IFP Enterprises (New York). {open_quotes}There are still too many players for the mature [refinery catalyst] markets.{close_quotes} Others agree. {open_quotes}Only about seven [or] eight major suppliersmore » will survive,{close_quotes} says Robert Allsmiller, v.p./refinery and petrochemical catalysts at United Catalysts Inc. (UCI; Louisville, KY). {open_quotes}Who they [will be] is still up in the air.{close_quotes}« less

40 CFR 419.25 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Pretreatment standards for existing sources (PSES). 419.25 Section 419.25 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.25...

40 CFR 419.27 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Pretreatment standards for new sources (PSNS). 419.27 Section 419.27 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.27...

40 CFR 419.27 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Pretreatment standards for new sources (PSNS). 419.27 Section 419.27 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.27...

40 CFR 419.25 - Pretreatment standards for existing sources (PSES).

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Pretreatment standards for existing sources (PSES). 419.25 Section 419.25 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.25...

Inert Reassessment Document for 2-methyl-2,4-pentanediol - CAS No. 107-41-5

EPA Pesticide Factsheets

2-methyl-2,4-pentanediol is used as a chemical intermediate, a selective solvent in petroleum refining, a component of hydraulic fluids, an additive for cement, a component of industrial coatings, a solvent for inks, an additive for fuel and lubricants

Establishing Priorities for Postsecondary Energy-Related Technology Programs

ERIC Educational Resources Information Center

Brooking, Walter J.

1977-01-01

Data from a Shell Oil Company forecast of national energy requirements through 1990 and from a national invitational conference on energy-related postsecondary programs are presented under the following headings: Coal mining beneficiation and processing, petroleum extraction and refining, nuclear power production, solar energy, and energy…

40 CFR 80.84 - Treatment of interface and transmix.

Code of Federal Regulations, 2010 CFR

2010-07-01

... processing facility means any refinery that produces TGP from transmix by distillation or other refining processes, but does not produce gasoline by processing crude oil. (5) Transmix processor means any person... Test Method for Distillation of Petroleum Products at Atmospheric Pressure”, which is incorporated by...

77 FR 20616 - Agency Information Collection Extension

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-05

..., pursuant to the Paperwork Reduction Act of 1995, intends to extend for 3 years the petroleum marketing survey forms listed below with the Office of Management and Budget (OMB): EIA-14, ``Refiners' Monthly... Marketing Program; (3) Type of Request: Renewal with change; (4) Purpose: The Federal Energy Administration...

40 CFR 419.36 - Standards of performance for new sources (NSPS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Standards of performance for new sources (NSPS). 419.36 Section 419.36 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Petrochemical Subcategory § 419...

75 FR 72761 - Production Measurement Documents Incorporated by Reference

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-26

... of crude oil, refined products, or lubricating oils. Natural gas liquids and liquid petroleum gases... standards into the regulations governing oil, gas, and sulphur operations in the Outer Continental Shelf... oil and gas production volumes. This will result in more efficient measurement of oil and gas...

A GHS-consistent approach to health hazard classification of petroleum substances, a class of UVCB substances.

PubMed

Clark, Charles R; McKee, Richard H; Freeman, James J; Swick, Derek; Mahagaokar, Suneeta; Pigram, Glenda; Roberts, Linda G; Smulders, Chantal J; Beatty, Patrick W

2013-12-01

The process streams refined from petroleum crude oil for use in petroleum products are among those designated by USEPA as UVCB substances (unknown or variable composition, complex reaction products and biological materials). They are identified on global chemical inventories with unique Chemical Abstract Services (CAS) numbers and names. The chemical complexity of most petroleum substances presents challenges when evaluating their hazards and can result in differing evaluations due to the varying level of hazardous constituents and differences in national chemical control regulations. Global efforts to harmonize the identification of chemical hazards are aimed at promoting the use of consistent hazard evaluation criteria. This paper discusses a systematic approach for the health hazard evaluation of petroleum substances using chemical categories and the United Nations (UN) Globally Harmonized System (GHS) of classification and labeling. Also described are historical efforts to characterize the hazard of these substances and how they led to the development of categories, the identification of potentially hazardous constituents which should be considered, and a summary of the toxicology of the major petroleum product groups. The use of these categories can increase the utility of existing data, provide better informed hazard evaluations, and reduce the amount of animal testing required. Copyright © 2013 The Authors. Published by Elsevier Inc. All rights reserved.

Integrated report on the toxicological mitigation of coal liquids by hydrotreatment and other processes. [Petroleum and coal-derived products

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guerin, M.R.; Griest, W.H.; Ho, C.H.

1986-06-01

Research here on the toxicological properties of coal-derived liquids focuses on characterizing the refining process and refined products. Principle attention is given to the potential tumorigenicity of coal-derived fuels and to the identification of means to further reduce tumorigenicity should this be found necessary. Hydrotreatment is studied most extensively because it will be almost certainly required to produce commercial products and because it is likely to also greatly reduce tumorigenic activity relative to that of crude coal-liquid feedstocks. This report presents the results of a lifetime C3H mouse skin tumorigenicity assay of an H-Coal series of oils and considers themore » relationships between tumorigenicity, chemistry, and processing. Lifetime assay results are reported for an H-Coal syncrude mode light oil/heavy oil blend, a low severity hydrotreatment product, a high severity hydrotreatment product, a naphtha reformate, a heating oil, a petroleum-derived reformate, and a petroleum derived heating oil. Data are compared with those for an earlier study of an SRC-II blend and products of its hydrotreatment. Adequate data are presented to allow an independent qualitative assessment of the conclusions while statistical evaluation of the data is being completed. The report also documents the physical and chemical properties of the oils tested. 33 refs., 14 figs., 53 tabs.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lilga, Michael A.; Padmaperuma, Asanga B.; Auberry, Deanna L.

We studied a new process for direct conversion of either levulinic acid (LA) or γ-valerolactone (GVL) to hydrocarbon fuel precursors. The process involves passing an aqueous solution of LA or GVL containing a reducing agent, such as ethylene glycol or formic acid, over a ketonization catalyst at 380–400 °C and atmospheric pressure to form a biphasic liquid product. The organic phase is significantly oligomerized and deoxygenated and comprises a complex mixture of open-chain alkanes and olefins, aromatics, and low concentrations of ketones, alcohols, ethers, and carboxylates or lactones. Carbon content in the aqueous phase decreases with decreasing feed rate; themore » aqueous phase can be reprocessed through the same catalyst to form additional organic oils to improve carbon yield. Catalysts are readily regenerated to restore initial activity. Furthermore, the process might be valuable in converting cellulosics to biorenewable gasoline, jet, and diesel fuels as a means to decrease petroleum use and decrease greenhouse gas emissions.« less

40 CFR 419.26 - Standards of performance for new sources (NSPS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Standards of performance for new sources (NSPS). 419.26 Section 419.26 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.26...

40 CFR 419.26 - Standards of performance for new sources (NSPS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Standards of performance for new sources (NSPS). 419.26 Section 419.26 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.26...

EVALUATING THE IMPACTS OF ENVIRONMENTAL ENFORCEMENT: THE CASE OF EFFLUENT DISCHARGES IN THE PETROLEUM REFINING INDUSTRY

EPA Science Inventory

This paper looks at the impact of enforcement activity on facility-level behavior and derives quantitative estimates of the impact. We measure facility-level behavior as the levels of Biological Oxygen Demand (BOD) and Total Suspended Solids (TSS) pollutant discharges generated b...

Hazardous Waste Management System - Identification and Listing of Hazardous Waste - Toxicity Characteristic - Hydrocarbon Recovery Operations - Federal Register Notice, October 5, 1990

EPA Pesticide Factsheets

The Agency is promulgating an interim final rule to extend the compliance date of the Toxicity Characteristic rule for petroleum refining facilities, marketing terminals and bulk plants engaged in the recovery and remediation operation for 120 days.

26 CFR 1.355-2 - Limitations.

Code of Federal Regulations, 2014 CFR

2014-04-01

... (g). Assume that C, D, P, and S are corporations, X is an unrelated individual, each of the... member, and P did not purchase that C stock within the pre-distribution period. See paragraph (g)(2)(ii... production, transportation, and refining of petroleum products. In 1985, X acquires all of the properties of...

26 CFR 1.355-2 - Limitations.

Code of Federal Regulations, 2012 CFR

2012-04-01

... (g). Assume that C, D, P, and S are corporations, X is an unrelated individual, each of the... member, and P did not purchase that C stock within the pre-distribution period. See paragraph (g)(2)(ii... production, transportation, and refining of petroleum products. In 1985, X acquires all of the properties of...

26 CFR 1.355-2 - Limitations.

Code of Federal Regulations, 2013 CFR

2013-04-01

... (g). Assume that C, D, P, and S are corporations, X is an unrelated individual, each of the... member, and P did not purchase that C stock within the pre-distribution period. See paragraph (g)(2)(ii... production, transportation, and refining of petroleum products. In 1985, X acquires all of the properties of...

From Petroleum to Penicillin. The First Hundred Years of Modern Chemical Engineering 1859-1959.

ERIC Educational Resources Information Center

Burnett, J. Nicholas

1986-01-01

Describes a chemical engineering course for liberal arts students that is taught from a scientific, social, and symbolic perspective. A summary of the early days of oil refining is included as representative of one of the major content segments of the course. (ML)

40 CFR 98.396 - Data reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... natural gas liquid listed in table MM-1 of this subpart that enters the refinery to be further refined or... standard method or other industry standard practice used. For natural gas liquids, quantity shall reflect the individual components of the product. (2) For each petroleum product or natural gas liquid listed...

40 CFR 98.396 - Data reporting requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... natural gas liquid listed in table MM-1 of this subpart that enters the refinery to be further refined or... standard method or other industry standard practice used. For natural gas liquids, quantity shall reflect the individual components of the product. (2) For each petroleum product or natural gas liquid listed...

40 CFR 98.396 - Data reporting requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... natural gas liquid listed in table MM-1 of this subpart that enters the refinery to be further refined or... standard method or other industry standard practice used. For natural gas liquids, quantity shall reflect the individual components of the product. (2) For each petroleum product or natural gas liquid listed...

40 CFR 98.396 - Data reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... natural gas liquid listed in table MM-1 of this subpart that enters the refinery to be further refined or... standard method or other industry standard practice used. For natural gas liquids, quantity shall reflect the individual components of the product. (2) For each petroleum product or natural gas liquid listed...

40 CFR 268.35 - Waste specific prohibitions-petroleum refining wastes.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.35 Waste... contaminated with these radioactive mixed wastes, are prohibited from land disposal. (b) The requirements of... Universal Treatment Standard levels of § 268.48, the waste is prohibited from land disposal, and all...

40 CFR 268.35 - Waste specific prohibitions-petroleum refining wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.35 Waste... contaminated with these radioactive mixed wastes, are prohibited from land disposal. (b) The requirements of... Universal Treatment Standard levels of § 268.48, the waste is prohibited from land disposal, and all...

40 CFR 268.35 - Waste specific prohibitions-petroleum refining wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.35 Waste... contaminated with these radioactive mixed wastes, are prohibited from land disposal. (b) The requirements of... Universal Treatment Standard levels of § 268.48, the waste is prohibited from land disposal, and all...

40 CFR 268.35 - Waste specific prohibitions-petroleum refining wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.35 Waste... contaminated with these radioactive mixed wastes, are prohibited from land disposal. (b) The requirements of... Universal Treatment Standard levels of § 268.48, the waste is prohibited from land disposal, and all...

40 CFR 268.35 - Waste specific prohibitions-petroleum refining wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.35 Waste... contaminated with these radioactive mixed wastes, are prohibited from land disposal. (b) The requirements of... Universal Treatment Standard levels of § 268.48, the waste is prohibited from land disposal, and all...

40 CFR 419.37 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 30 2013-07-01 2012-07-01 true Pretreatment standards for new sources...) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Petrochemical Subcategory § 419.37 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source...

A Study of the Effect of Surfactants on the Aggregation Behavior of Crude Oil Aqueous Dispersions through Steady-State Fluorescence Spectrometry.

PubMed

Vallejo-Cardona, Alba A; Cerón-Camacho, Ricardo; Karamath, James R; Martínez-Palou, Rafael; Aburto, Jorge

2017-07-01

Unconventional crude oil as heavy, extra heavy, bitumen, tight, and shale oils will meet 10% of worldwide needs for 2035, perhaps earlier. Petroleum companies will face problems concerning crude oil extraction, production, transport, and refining, and some of these are addressed by the use of surfactants and other chemicals. For example, water-in-crude oil emulsions are frequently found during the production of mature wells where enhanced recovery techniques have been deployed. Nevertheless, the selection of adequate surfactant, dosage, type of water (sea, tap or oilfield), kind of crude oil (light, heavy, extra heavy, tight, shale, bitumen) affect the effectivity of treatment and usual bottle tests give limited information. We developed a fluorescence technique to study the effect of surfactants on medium, heavy, and extra heavy crude oil employing the natural fluorophore molecules from petroleum. We first carried out the characterization of commercial and synthetic surfactants, then dispersions of petroleum in water were studied by steady-state fluorometry and the size of petroleum aggregates were measured. The aggregation of petroleum incremented from medium to extra heavy crude oil and we discussed the effect of different surfactants on such aggregation.

Progress in the Development of Oxygen Reduction Reaction Catalysts for Low-Temperature Fuel Cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Dongguo; Lv, Haifeng; Kang, Yijin

2016-04-06

In this paper, we present a brief summary on the most recent progress in the design of catalysts for electrochemical reduction of oxygen. The main challenge in the wide spread of fuel cell technology is to lower the content of, or even eliminate, Pt and other precious metals in catalysts without sacrificing their performance. Pt-based nanosized catalysts with novel and refined architectures continue to dominate in catalytic performance, and formation of Pt-skin-like surfaces is key to achieving the highest values in activity. Moreover, durability has also been improved in Pt-based systems with addition of Au, which plays an important rolemore » in stabilizing the Pt topmost layers against dissolution. However, various carbon-based materials without precious metal have shown improvement in activity and durability and have been explored to serve as catalyst supports. Finally, understanding how the doped elements interact with each other and/or carbon is challenging and necessary in the design of robust fuel cell catalysts.« less

Production of biodiesel fuel by transesterification of different vegetable oils with methanol using Al₂O₃ modified MgZnO catalyst.

PubMed

Olutoye, M A; Hameed, B H

2013-03-01

An active heterogeneous Al2O3 modified MgZnO (MgZnAlO) catalyst was prepared and the catalytic activity was investigated for the transesterification of different vegetable oils (refined palm oil, waste cooking palm oil, palm kernel oil and coconut oil) with methanol to produce biodiesel. The catalyst was characterized by using X-ray diffraction, Fourier transform infrared spectra, thermo gravimetric and differential thermal analysis to ascertain its versatility. Effects of important reaction parameters such as methanol to oil molar ratio, catalyst dosage, reaction temperature and reaction time on oil conversion were examined. Within the range of studied variability, the suitable transesterification conditions (methanol/oil ratio 16:1, catalyst loading 3.32 wt.%, reaction time 6h, temperature 182°C), the oil conversion of 98% could be achieved with reference to coconut oil in a single stage. The catalyst can be easily recovered and reused for five cycles without significant deactivation. Copyright © 2013 Elsevier Ltd. All rights reserved.

Liquid hydrocarbon fuels obtained by the pyrolysis of soybean oils.

PubMed

Junming, Xu; Jianchun, Jiang; Yanju, Lu; Jie, Chen

2009-10-01

The pyrolysis reactions of soybean oils have been studied. The pyrolytic products were analyzed by GC-MS and FTIR and show the formation of olefins, paraffins, carboxylic acids and aldehydes. Several kinds of catalysts were compared. It was found that the amounts of carboxylic acids and aldehydes were significantly decreased by using base catalysts such as Na(2)CO(3) and K(2)CO(3). The low acid value pyrolytic products showed good cold flow properties and good solubility in diesel oil at low temperature. The results presented in this work have shown that the pyrolysis of soybean oils generates fuels that have chemical composition similar to petroleum based fuels.

Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Freeman, Charles J.; Jones, Susanne B.; Padmaperuma, Asanga B.

2013-04-01

In order to meet U.S. biofuel objectives over the coming decade the conversion of a broad range of biomass feedstocks, using diverse processing options, will be required. Further, the production of both gasoline and diesel biofuels will employ biomass conversion methods that produce wide boiling range intermediate oils requiring treatment similar to conventional refining processes (i.e. fluid catalytic cracking, hydrocracking, and hydrotreating). As such, it is widely recognized that leveraging existing U.S. petroleum refining infrastructure is key to reducing overall capital demands. This study examines how existing U.S. refining location, capacities and conversion capabilities match in geography and processing capabilitiesmore » with the needs projected from anticipated biofuels production.« less

Sustainable Energy Production from Jatropha Bio-Diesel

NASA Astrophysics Data System (ADS)

Yadav, Amit Kumar; Krishna, Vijai

2012-10-01

The demand for petroleum has risen rapidly due to increasing industrialization and modernization of the world. This economic development has led to a huge demand for energy, where the major part of that energy is derived from fossil sources such as petroleum, coal and natural gas. Continued use of petroleum sourced fuels is now widely recognized as unsustainable because of depleting supplies. There is a growing interest in using Jatropha curcas L. oil as the feedstock for biodiesel production because it is non-edible and thus does not compromise the edible oils, which are mainly used for food consumption. Further, J. curcas L. seed has a high content of free fatty acids that is converted in to biodiesel by trans esterification with alcohol in the presence of a catalyst. The biodiesel produced has similar properties to that of petroleum-based diesel. Biodiesel fuel has better properties than petro diesel fuel; it is renewable, biodegradable, non-toxic, and essentially free of sulfur and aromatics. Biodiesel seems to be a realistic fuel for future. Biodiesel has the potential to economically, socially, and environmentally benefit communities as well as countries, and to contribute toward their sustainable development.

Elevated production of NH4NO3 from the photochemical processing of vehicle exhaust: Implications for air quality in the Seoul Metropolitan Region

NASA Astrophysics Data System (ADS)

Link, Michael F.; Kim, Jounghwa; Park, Gyutae; Lee, Taehyoung; Park, Taehyun; Babar, Zaeem Bin; Sung, Kijae; Kim, Pilho; Kang, Seokwon; Kim, Jeong Soo; Choi, Yongjoo; Son, Jihawn; Lim, Ho-Jin; Farmer, Delphine K.

2017-05-01

A vehicle fleet representative of passenger vehicles driven in the Seoul Metropolitan Region was investigated for primary emissions and secondary chemistry. Exhaust was photochemically oxidized in a flow reactor to determine the ammonium nitrate (NH4NO3) aerosol formation potential from vehicles of gasoline, diesel and liquid petroleum gasoline (LPG) fuel types. Secondary formation of aerosol NH4NO3, was larger than primary emissions for all vehicle fuel types except diesel, for which negligible secondary NH4NO3 production was observed. Although diesel vehicles emitted more primary nitrogen oxides than other vehicle types, ammonia emitted from gasoline and liquid petroleum gasoline fuels types limited the secondary production of NH4NO3. The results suggest that gasoline and liquid petroleum gasoline vehicles with three-way catalysts could be an important source of ammonia for NH4NO3 aerosol formation in ammonia-limited environments, including the Seoul Metropolitan Region.

Synthesis and analysis of jet fuel from shale oil and coal syncrudes

NASA Technical Reports Server (NTRS)

Gallagher, J. P.; Collins, T. A.; Nelson, T. J.; Pedersen, M. J.; Robison, M. G.; Wisinski, L. J.

1976-01-01

Thirty-two jet fuel samples of varying properties were produced from shale oil and coal syncrudes, and analyzed to assess their suitability for use. TOSCO II shale oil and H-COAL and COED syncrudes were used as starting materials. The processes used were among those commonly in use in petroleum processing-distillation, hydrogenation and catalytic hydrocracking. The processing conditions required to meet two levels of specifications regarding aromatic, hydrogen, sulfur and nitrogen contents at two yield levels were determined and found to be more demanding than normally required in petroleum processing. Analysis of the samples produced indicated that if the more stringent specifications of 13.5% hydrogen (min.) and 0.02% nitrogen (max.) were met, products similar in properties to conventional jet fuels were obtained. In general, shale oil was easier to process (catalyst deactivation was seen when processing coal syncrudes), consumed less hydrogen and yielded superior products. Based on these considerations, shale oil appears to be preferred to coal as a petroleum substitute for jet fuel production.

New catalysts for coal liquefaction and new nanocrystalline catalysts synthesis methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Linehan, J.C.; Matson, D.W.; Darab, J.G.

1994-09-01

The use of coal as a source of transportation fuel is currently economically unfavorable due to an abundant world petroleum supply and the relatively high cost of coal liquefaction. Consequently, a reduction in the cost of coal liquefaction, for example by using less and/or less costly catalysts or lower liquefaction temperatures, must be accomplished if coal is to play an significant role as a source of liquid feedstock for the petrochemical industry. The authors and others have investigated the applicability of using inexpensive iron-based catalysts in place of more costly and environmentally hazardous metal catalysts for direct coal liquefaction. Iron-basedmore » catalysts can be effective in liquefying coal and in promoting carbon-carbon bond cleavage in model compounds. The authors have been involved in an ongoing effort to develop and optimize iron-based powders for use in coal liquefaction and related petrochemical applications. Research efforts in this area have been directed at three general areas. The authors have explored ways to optimize the effectiveness of catalyst precursor species through use of nanocrystalline materials and/or finely divided powders. In this effort, the authors have developed two new nanophase material production techniques, Modified Reverse Micelle (MRM) and the Rapid Thermal Decomposition of precursors in Solution (RTDS). A second effort has been aimed at optimizing the effectiveness of catalysts by variations in other factors. To this, the authors have investigated the effect that the crystalline phase has on the capacity of iron-based oxide and oxyhydroxide powders to be effectively converted to an active catalyst phase under liquefaction conditions. And finally, the authors have developed methods to produce active catalyst precursor powders in quantities sufficient for pilot-scale testing. Major results in these three areas are summarized.« less

In situ X-ray absorption fine structure analysis of redox reactions of nickel species with variable particle sizes supported on silica

NASA Astrophysics Data System (ADS)

Yamamoto, Yusaku; Suzuki, Atsushi; Tsutsumi, Naoki; Katagiri, Masaki; Yamashita, Shohei; Niwa, Yasuhiro; Katayama, Misaki; Inada, Yasuhiro

2018-02-01

The chemical states of Ni species were systematically investigated using an in situ XAFS technique for a series of SiO2-supported Ni catalysts with different Ni particle sizes. The Ni particles were refined by varying the Ni loading in the range between 0.10 and 5 wt% and by adding citric acid into the precursor solution. An in situ observation cell for fluorescence-yield XAFS measurements was developed for the dilute Ni catalysts. The chemical state of the supported Ni species converted between Ni(0) and NiO, and no other stable species were formed during the temperature-programmed oxidation and reduction processes. Refinement of the Ni particles resulted in decreasing the oxidation temperature and increasing the reduction temperature. These shifts were explained by the affinity of NiO to SiO2, and more effective stabilization was thus anticipated for flattened small NiO particles with an increased contact area. In addition, the inhomogeneous distribution of small Ni particles observed for dilute catalysts was explained in terms of the precursor solution volume when nuclei of the precursor compound precipitated on SiO2 during the drying process.

US energy industry financial developments, 1993 first quarter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-06-25

Net income for 259 energy companies-- including, 20 major US petroleum companies-- rose 38 percent between the first quarter of 1992 and the first quarter of 1993. An increased level of economic activity, along with colder weather, helped lift the demand for natural gas. crude oil, coal, and electricity. The sharp rise in the domestic price of natural gas at the wellhead relative to the year-ago quarter was the most significant development in US energy during the first quarter. As a consequence of higher natural gas prices, the upstream segment of the petroleum industry reported large gains in income, whilemore » downstream income rose due to higher refined product demand. Increased economic activity and higher weather-related natural gas demand also led to improvements in income for the rate-regulated energy segment. However, declining domestic oil production continued to restrain upstream petroleum industry earnings growth, despite a moderate rise in crude oil prices.« less

Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks

DOEpatents

Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.; Beltran, Leslie V.; Kunz, Linda A.; Pals, Tessa M.; Quinn, Jordan R; Behrends, Jr., Raymond T.; Bernhardt, Randal J.

2016-07-05

Methods are provided for refining natural oil feedstocks and producing isomerized esters and acids. The methods comprise providing a C4-C18 unsaturated fatty ester or acid, and isomerizing the fatty acid ester or acid in the presence of heat or an isomerization catalyst to form an isomerized fatty ester or acid. In some embodiments, the methods comprise forming a dibasic ester or dibasic acid prior to the isomerizing step. In certain embodiments, the methods further comprise hydrolyzing the dibasic ester to form a dibasic acid. In certain embodiments, the olefin is formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having unsaturated esters.

Methods for suppressing isomerization of olefin metathesis products

DOEpatents

Firth, Bruce E.; Kirk, Sharon E.; Gavaskar, Vasudeo S.

2015-09-22

A method for suppressing isomerization of an olefin metathesis product produced in a metathesis reaction includes adding an isomerization suppression agent to a mixture that includes the olefin metathesis product and residual metathesis catalyst from the metathesis reaction under conditions that are sufficient to passivate at least a portion of the residual metathesis catalyst. The isomerization suppression agent is phosphorous acid, a phosphorous acid ester, phosphinic acid, a phosphinic acid ester or combinations thereof. Methods of refining natural oils are described.

HIGH RESOLTUION GEOELECTRICAL MEASUREMENTS OF BIODEGRADATION AND SURFACTANT REMEDIATION: LAB AND FIELD STUDES AND A NEW CHARACTERIZATION TEST CELL FIELD RESEARCH SITE

EPA Science Inventory

Laboratory and field high vertical resolution geophysical research has shown that geoelectrical measurements can detect and monitor the natural attenuation of petroleum hydrocarbons. These results have lead to the continued development and refinement of the conductive model for h...

27 CFR 21.127 - Shellac (refined).

Code of Federal Regulations, 2010 CFR

2010-04-01

... Gutzeit Method (AOAC method 25.020; for incorporation by reference, see § 21.6(c)). (b) Color. White or orange. (c) Rosin content. None when tested by the following method: Add 20 ml of absolute alcohol or... petroleum ether and mix thoroughly. Add approximately 2 liters of water and separate a portion of the ether...

78 FR 50446 - Notice of Lodging of Proposed Consent Decree Under the Clean Air Act

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-19

... Blanchard Refining Company LLC (hereinafter ``Blanchard''), a wholly owned subsidiary of Marathon Petroleum Company LP. The proposed Ninth Amendment also resolves alleged violations by BP Products at the Texas City Refinery of the Clean Air Act's Standards of Performance for New Stationary Sources: VOC Emissions for...

Field Operations and Enforcement Manual for Air Pollution Control. Volume III: Inspection Procedures for Specific Industries.

ERIC Educational Resources Information Center

Weisburd, Melvin I.

The Field Operations and Enforcement Manual for Air Pollution Control, Volume III, explains in detail the following: inspection procedures for specific sources, kraft pulp mills, animal rendering, steel mill furnaces, coking operations, petroleum refineries, chemical plants, non-ferrous smelting and refining, foundries, cement plants, aluminum…

Labor Market Slackens for New Science and Engineering Graduates. Science Resources Studies Highlights.

ERIC Educational Resources Information Center

National Science Foundation, Washington, DC. Div. of Science Resources Studies.

Recent recruiting experiences of firms that employ scientific and engineering (S/E) personnel were determined in a followup to a 1981 survey. The following industries, which employ almost three-fourths of the scientists and engineers in private industry, were included in the survey: mining, construction, petroleum refining and extraction,…

76 FR 4540 - Approval and Disapproval and Promulgation of Air Quality Implementation Plans; Colorado...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-26

..., particulates, carbon monoxide and sulfur dioxide. The revision involves the deletion of obsolete, the adoption... Regulation refer to Colorado's Regulation 1. (vi) The initials SO2 mean or refer to sulfur dioxide, HC mean... modifies the method for calculating compliance with emission limits for petroleum refining and cement...

40 CFR 419.17 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 30 2013-07-01 2012-07-01 true Pretreatment standards for new sources...) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Topping Subcategory § 419.17 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source subject to...

40 CFR 419.27 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 30 2013-07-01 2012-07-01 true Pretreatment standards for new sources...) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Cracking Subcategory § 419.27 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source subject to...

40 CFR 419.47 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 30 2013-07-01 2012-07-01 true Pretreatment standards for new sources...) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Lube Subcategory § 419.47 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source subject to...

40 CFR 419.57 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 30 2013-07-01 2012-07-01 true Pretreatment standards for new sources...) EFFLUENT GUIDELINES AND STANDARDS PETROLEUM REFINING POINT SOURCE CATEGORY Integrated Subcategory § 419.57 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source subject to...

Using comprehensive two-dimensional gas chromatography to explore the geochemistry of the Santa Barbara oil seeps

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reddy, Christopher; Nelson, Robert

The development of comprehensive two-dimensional gas chromatography (GC x GC) has expanded the analytical window for studying complex mixtures like oil. Compared to traditional gas chromatography, this technology separates and resolves at least an order of magnitude more compounds, has a much larger signal to noise ratio, and sorts compounds based on their chemical class; hence, providing highly refined inventories of petroleum hydrocarbons in geochemical samples that was previously unattainable. In addition to the increased resolution afforded by GC x GC, the resulting chromatograms have been used to estimate the liquid vapor pressures, aqueous solubilities, octanol-water partition coefficients, and vaporizationmore » enthalpies of petroleum hydrocarbons. With these relationships, powerful and incisive analyses of phase-transfer processes affecting petroleum hydrocarbon mixtures in the environment are available. For example, GC x GC retention data has been used to quantitatively deconvolve the effects of phase transfer processes such as water washing and evaporation. In short, the positive attributes of GC x GC-analysis have led to a methodology that has revolutionized the analysis of petroleum hydrocarbons. Overall, this research has opened numerous fields of study on the biogeochemical "genetics" (referred to as petroleomics) of petroleum samples in both subsurface and surface environments. Furthermore, these new findings have already been applied to the behavior of oil at other seeps as well, for petroleum exploration and oil spill studies.« less

Re-manufacture of cobalt-manganese-bromide as a liquid catalyst from spent catalyst containing cobalt generated from petrochemical processes via hydrometallurgy.

PubMed

Joo, Sung-Ho; Shin, Dong Ju; Oh, Chang Hyun; Wang, Jei-Pil; Shin, Shun Myung

2016-11-15

Cobalt and manganese have been the subject of individual separation studies because their fields of application are different. However, this study shows that high-value products can be manufactured in the form of a cobalt-manganese-bromide (CMB) liquid catalyst by simultaneously recovering cobalt and manganese. Na-bis-(2,4,4-tri-methyl-pentyl)phosphinic acid was employed in order to manufacture the CMB liquid catalyst from the spent catalyst generated from petroleum chemistry processes. The pH-isotherm, degree of saponification of solvent and separation factor values were investigated. ΔpH50 and separation factor values show that Co and Mn can be separated from impurities such as Mg and Ca. Further, the extraction stages and organic/aqueous ratio isotherms were investigated using counter-current simulation extraction batch tests. To prepare CMB from a loaded organic phase obtained in a stripping study using hydrogen bromide, the Co and Mn were completely stripped and concentrated by a factor of 6 using a 2M hydrogen bromide solution. When compared with manufactured and commercial CMB, the CMB liquid catalyst could be produced by supplying a shortage of Mn in the form of manganese bromide. Finally, the method of manufacture of CMB was subjected to a real pilot plant test. Copyright © 2016. Published by Elsevier B.V.

Effect of biogenic fermentation impurities on lactic acid hydrogenation to propylene glycol.

PubMed

Zhang, Zhigang; Jackson, James E; Miller, Dennis J

2008-09-01

The effect of residual impurities from glucose fermentation to lactic acid (LA) on subsequent ruthenium-catalyzed hydrogenation of LA to propylene glycol (PG) is examined. Whereas refined LA feed exhibits stable conversion to PG over carbon-supported ruthenium catalyst in a trickle bed reactor, partially refined LA from fermentation shows a steep decline in PG production over short (<40 h) reaction times followed by a further slow decay in performance. Addition of model impurities to refined LA has varying effects: organic acids, sugars, or inorganic salts have little effect on conversion; alanine, a model amino acid, results in a strong but reversible decline in conversion via competitive adsorption between alanine and LA on the Ru surface. The sulfur-containing amino acids cysteine and methionine irreversibly poison the catalyst for LA conversion. Addition of 0.1 wt% albumin as a model protein leads to slow decline in rate, consistent with pore plugging or combined pore plugging and poisoning of the Ru surface. This study points to the need for integrated design and operation of biological processes and chemical processes in the biorefinery in order to make efficient conversion schemes viable.

An observational study on changes in biometry and generation time of Odontophora villoti (Nematoda, Axonolaimidae) related to petroleum pollution in Bizerte bay, Tunisia.

PubMed

Boufahja, Fehmi; Hedfi, Amor; Essid, Naceur; Aïssa, Patricia; Mahmoudi, Ezzeddine; Beyrem, Hamouda

2012-03-01

We conducted a yearly polluted-reference sampling to assess the effects of petroleum pollution on life cycle characteristics of the meiobenthic nematode Odontophora villoti. Samples were taken every 15 days between 26 November 2004 and 25 November 2005 from two beaches of Bizerte bay (Tunisia), Rimel and Tunisian Refining Industries Company (TRIC). The latter site is located in front of the "Tunisian Refining Industries Company" runoff. When compared to the reference site, the mean body dimensions of O. villoti from the impacted site were significantly lower. The small size of affected nematodes was represented both by the length and width as a function of the life stage. It was also established that changes in lengths of body parts during molts were different between the two study sites. The low availability of oxygen from April to August seems to prevent the formation of embryos of O. villoti. Thus, two annual reproductive cycles with different durations were observed in Rimel and TRIC. Under stress, juvenile phase and egg production were generally shorter. Globally, the impact of petroleum pollution on O. villoti was expressed by a short egg-to-egg development time. Our study assessed the usefulness of life cycle characteristics (biometry and life stage durations) of O. villoti in biomonitoring, and the results are generally consistent suggesting that this species may be considered as an efficient bioindicator.

Anicteric hepatoxicity: a potential health risk of occupational exposures in Nigerian petroleum oil refining and distribution industry.

PubMed

Ezejiofor, Tobias I Ndubuisi; Ezejiofor, Anthonet N; Orisakwe, Orish E; Nwigwe, Hariet C; Osuala, Ferdinand Ou; Iwuala, Moses Oe

2014-01-22

Literature abounds linking one's job to certain unpalatable health outcomes. Since exposures to hazardous conditions in industrial environments often results in sundry health effects among workers, we embarked on this study to investigate the hepatic health effects of occupational activities in the petroleum refining and distribution industry. Biochemical markers of liver functions were assayed in plasma, using Reflotron dry chemistry spectrophotometric system. The study was conducted on randomly selected workers of Port Harcourt Refining Company (PHRC) and Pipelines and Petroleum Product Marketing Company (PPMC) both in Alesa-Eleme near Port Harcourt, Nigeria, as well as non-oil work civil servants serving as control subjects. Results showed that, bilirubin ranged 0.3-1.6 mg/dl with a mean of 0.66±0.20mg/dl among the oil workers as against 0.5-1.00mg/dl with a mean of 0.58±0.13mg/dl in non-oil workers, Alkaline phosphatase ranged 50.00-296.00u/l (mean: 126.21±39.49u/l) in oil workers as against 40.20-111u/l (mean: 66.83±18.54u/l) for non-oil workers, Aspartic transaminases (AST) ranged 5.80-140.20u/l (mean: 21.81±11.49u/l) in oil workers against 18.00-44.00u/l (mean: 26.89±6.99u/l) for non-oil workers, while Alanine transaminases (ALT) ranged 4.90-86.00u/l (mean: 22.14±11.28u/l) in oil workers as against 10.00-86.60u/l (mean: 22.30±10.22u/l) for the non-oil workers. A close study of the results revealed that although the mean values for all the studied parameters were still within the parametric reference ranges, however, relative to the referents, there were significant increases (P<0.05) in plasma bilirubin (though anicteric) and alkaline phosphatase that was not matched with a corresponding increase in the plasma transaminases, suggesting a possibility that toxic anicteric hepatoxicity is part of the potential health effects of sundry exposures in the Nigeria petroleum oil refining and distribution industry. Gender differentiation data showed that though the mean values for the parameters were higher in males than females, the increases were not significant in most cases (P>0.05), whereas data for age and exposure period classifications revealed that irrespective of the age of the worker, the effects are likely to start after the first five years, manifesting fully after the first decade of occupational exposures. Thus, an update of industrial/occupational health measures is necessary for a safer and healthier work environment.

Anicteric hepatoxicity: a potential health risk of occupational exposures in Nigerian petroleum oil refining and distribution industry

PubMed Central

2014-01-01

Background Literature abounds linking one’s job to certain unpalatable health outcomes. Since exposures to hazardous conditions in industrial environments often results in sundry health effects among workers, we embarked on this study to investigate the hepatic health effects of occupational activities in the petroleum refining and distribution industry. Method Biochemical markers of liver functions were assayed in plasma, using Reflotron dry chemistry spectrophotometric system. The study was conducted on randomly selected workers of Port Harcourt Refining Company (PHRC) and Pipelines and Petroleum Product Marketing Company (PPMC) both in Alesa-Eleme near Port Harcourt, Nigeria, as well as non-oil work civil servants serving as control subjects. Result and conclusion Results showed that, bilirubin ranged 0.3-1.6 mg/dl with a mean of 0.66±0.20mg/dl among the oil workers as against 0.5-1.00mg/dl with a mean of 0.58±0.13mg/dl in non-oil workers, Alkaline phosphatase ranged 50.00-296.00u/l (mean: 126.21±39.49u/l) in oil workers as against 40.20-111u/l (mean: 66.83±18.54u/l) for non-oil workers, Aspartic transaminases (AST) ranged 5.80-140.20u/l (mean: 21.81±11.49u/l) in oil workers against 18.00-44.00u/l (mean: 26.89±6.99u/l) for non-oil workers, while Alanine transaminases (ALT) ranged 4.90-86.00u/l (mean: 22.14±11.28u/l) in oil workers as against 10.00-86.60u/l (mean: 22.30±10.22u/l) for the non-oil workers. A close study of the results revealed that although the mean values for all the studied parameters were still within the parametric reference ranges, however, relative to the referents, there were significant increases (P<0.05) in plasma bilirubin (though anicteric) and alkaline phosphatase that was not matched with a corresponding increase in the plasma transaminases, suggesting a possibility that toxic anicteric hepatoxicity is part of the potential health effects of sundry exposures in the Nigeria petroleum oil refining and distribution industry. Gender differentiation data showed that though the mean values for the parameters were higher in males than females, the increases were not significant in most cases (P>0.05), whereas data for age and exposure period classifications revealed that irrespective of the age of the worker, the effects are likely to start after the first five years, manifesting fully after the first decade of occupational exposures. Thus, an update of industrial/occupational health measures is necessary for a safer and healthier work environment. PMID:24457023

Grouping of Petroleum Substances as Example UVCBs by Ion Mobility-Mass Spectrometry to Enable Chemical Composition-Based Read-Across.

PubMed

Grimm, Fabian A; Russell, William K; Luo, Yu-Syuan; Iwata, Yasuhiro; Chiu, Weihsueh A; Roy, Tim; Boogaard, Peter J; Ketelslegers, Hans B; Rusyn, Ivan

2017-06-20

Substances of Unknown or Variable composition, Complex reaction products, and Biological materials (UVCBs), including many refined petroleum products, present a major challenge in regulatory submissions under the EU Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) and US High Production Volume regulatory regimes. The inherent complexity of these substances, as well as variability in composition obfuscates detailed chemical characterization of each individual substance and their grouping for human and environmental health evaluation through read-across. In this study, we applied ion mobility mass spectrometry in conjunction with cheminformatics-based data integration and visualization to derive substance-specific signatures based on the distribution and abundance of various heteroatom classes. We used petroleum substances from four petroleum substance manufacturing streams and evaluated their chemical composition similarity based on high-dimensional substance-specific quantitative parameters including m/z distribution, drift time, carbon number range, and associated double bond equivalents and hydrogen-to-carbon ratios. Data integration and visualization revealed group-specific similarities for petroleum substances. Observed differences within a product group were indicative of batch- or manufacturer-dependent variation. We demonstrate how high-resolution analytical chemistry approaches can be used effectively to support categorization of UVCBs based on their heteroatom composition and how such data can be used in regulatory decision-making.

Assessment of three approaches of bioremediation (Natural Attenuation, Landfarming and Bioagumentation - Assistited Landfarming) for a petroleum hydrocarbons contaminated soil.

PubMed

Guarino, C; Spada, V; Sciarrillo, R

2017-03-01

Contamination with total petroleum hydrocarbons (TPH) subsequent to refining activities, is currently one of the major environmental problems. Among the biological remediation approaches, landfarming and in situ bioremediation strategies are of great interest. Purpose of this study was to verify the feasibility of a remediation process wholly based on biological degradation applied to contaminated soils from a decommissioned refinery. This study evaluated through a pot experiment three bioremediation strategies: a) Natural Attenuation (NA), b) Landfarming (L), c) Bioaugmentation-assisted Landfarming (LB) for the treatment of a contaminated soil with petroleum hydrocarbons (TPHs). After a 90-days trial, Bioagumentation - assistited Landfarming approach produced the best results and the greatest evident effect was shown with the most polluted samples reaching a reduction of about 86% of total petroleum hydrocarbons (TPH), followed by Landfarming (70%), and Natural Attenuation (57%). The results of this study demonstrated that the combined use of bioremediation strategies was the most advantageous option for the treatment of contaminated soil with petroleum hydrocarbons, as compared to natural attenuation, bioaugmentation or landfarming applied alone. Besides, our results indicate that incubation with an autochthonous bacterial consortium may be a promising method for bioremediation of TPH-contaminated soils. Copyright © 2016 Elsevier Ltd. All rights reserved.

War without Oil: A Catalyst for True Transformation

DTIC Science & Technology

2006-02-17

of oil consumed figure from Amidon, “America’s Strategic Imperative, A ‘ Manhattan Project ’ for...Strategic Imperative, A ‘ Manhattan Project ’ for Energy”, 70. 21 2 trillion barrel figure derived from EIA, “World Proved Reserves of Oil and Gas...Imperative, A ‘ Manhattan Project ’ for Energy”, 70. - 7 - Global Oil Supply/Demand 22Table 1 – 2004 Top 10 Petroleum Producers and Consumers

Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds

DOEpatents

Comolli, Alfred G.; Lee, Lap-Keung

2001-01-01

A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

Lipase-catalyzed biodiesel production and quality with Jatropha curcas oil: exploring its potential for Central America.

PubMed

Bueso, Francisco; Moreno, Luis; Cedeño, Mathew; Manzanarez, Karla

2015-01-01

Extensive native Jatropha curcas L. (Jatropha) crop areas have been planted in Central America marginal lands since 2008 as a non-edible prospective feedstock alternative to high-value, edible palm oil. Jatropha biodiesel is currently exclusively produced in the region at commercial scale utilizing alkaline catalysts. Recently, a free, soluble Thermomyces lanuginosus (TL) 1,3 specific lipase has shown promise as biocatalyst, reportedly yielding up to 96 % ASTM D6751 compliant biodiesel after 24 h transesterification of soybean, canola oils and other feedstocks. Biodiesel conversion rate and quality of enzymatically catalyzed transesterification of Jatropha oil was evaluated. Two lipases: free, soluble TL and immobilized Candida antarctica (CA) catalyzed methanolic transesterification of crude Jatropha and refined palm oil. Jatropha yields were similar to palm biodiesel with NaOH as catalyst. After 24 h transesterification, Jatropha (81 %) and palm oil (86 %) biodiesel yields with TL as catalyst were significantly higher than CA (<70 %) but inferior to NaOH (>90 %). Enzymatic catalysts (TL and CA) produced Jatropha biodiesel with optimum flow properties but did not complied with ASTM D6751 stability parameters (free fatty acid content and oil stability index). Biodiesel production with filtered, degummed, low FFA Jatropha oil using a free liquid lipase (TL) as catalyst showed higher yielding potential than immobilized CA lipase as substitute of RBD palm oil with alkaline catalyst. However, Jatropha enzymatic biodiesel yield and stability were inferior to alkaline catalyzed biodiesel and not in compliance with international quality standards. Lower quality due to incomplete alcoholysis and esterification, potential added costs due to need of more than 24 h to achieve comparable biodiesel yields and extra post-transesterification refining reactions are among the remaining drawbacks for the environmentally friendlier enzymatic catalysis of crude Jatropha oil to become an economically viable alternative to chemical catalysis.

Mapping the petroleum system - An investigative technique to explore the hydrocarbon fluid system

USGS Publications Warehouse

Magoon, L.B.; Dow, W.G.

2000-01-01

Creating a petroleum system map includes a series of logical steps that require specific information to explain the origin in time and space of discovered hydrocarbon occurrences. If used creatively, this map provides a basis on which to develop complementary plays and prospects. The logical steps include the characterization of a petroleum system (that is, to identify, map, and name the hydrocarbon fluid system) and the summary of these results on a folio sheet. A petroleum system map is based on the understanding that there are several levels of certainty from "guessing" to "knowing" that specific oil and gas accumulations emanated from a particular pod of active source rock. Levels of certainty start with the close geographic proximity of two or more accumulations, continues with the close stratigraphic proximity, followed by the similarities in bulk properties, and then detailed geochemical properties. The highest level of certainty includes the positive geochemical correlation of the hydrocarbon fluid in the accumulations to the extract of the active source rock. A petroleum system map is created when the following logic is implemented. Implementation starts when the oil and gas accumulations of a petroleum province are grouped stratigraphically and geographically. Bulk and geochemical properties are used to further refine the groups through the determination of genetically related oil and gas types. To this basic map, surface seeps and well shows are added. Similarly, the active source rock responsible for these hydrocarbon occurrences are mapped to further define the extent of the system. A folio sheet constructed for a hypothetical case study of the Deer-Boar(.) petroleum system illustrates this methodology.

76 FR 55111 - United States v. General Electric Co., et al.; Proposed Final Judgment and Competitive Impact...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-09-06

... areas in the energy industry, including coal, oil, natural gas, and nuclear energy, as well as in... higher power ratings. 12. In processing and refining crude oil into petroleum products, oil refineries... energy industry, including coal, oil, natural gas, and nuclear energy, as well as in renewable resources...

Challenges and opportunities for animal conservation from renewable energy development

Treesearch

T.A. Katzner; J.A. Johnson; D.M. Evans; T.W.J. Garner; M.E. Gompper; R. Altwegg; T.A. Branch; I.J. Gordon; N. Pettorelli

2013-01-01

Global climate change is among the greatest threats confronting both human and natural systems (IPCC, 2007). A substantial component of greenhouse gas (GHG) emissions is from energy production, generated via the burning of fossil fuels, especially coal, natural gas and refined petroleum. Given that reduction in global energy consumption is unlikely over the next...

75 FR 38116 - Notice of Availability of Record of Decision for the Approved Pony Express Resource Management...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-07-01

... Plan Amendment; UNEV Refined Liquid Petroleum Products Pipeline Environmental Impact Statement AGENCY... Environmental Impact Statement (EIS) published on April 16, 2010, is the same as that selected in the ROD. The..., Tooele, Juab, Millard, Beaver, Iron, and Washington Counties in Utah, and in Lincoln and Clark Counties...

40 CFR 281.39 - Lender liability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... management of the UST or UST system as defined under § 280.210 of this chapter, and who does not engage in petroleum production, refining, and marketing as defined under § 280.200(b) of this chapter is not: (A) An..., provided the holder is not in control of or does not have responsibility for the daily operation of the UST...

31 CFR 575.408 - Offshore transactions.

Code of Federal Regulations, 2010 CFR

2010-07-01

.... person knows, or has reason to know, that the Government of Iraq has or has had an interest since the..., transport, act as a broker for the sale or transport of, or otherwise deal in, Iraqi crude oil or petroleum products refined in Iraq. (2) A U.S. person may not, within the United States or abroad, conduct...

Demand and supply of hydrogen as chemical feedstock in USA

NASA Technical Reports Server (NTRS)

Huang, C. J.; Tang, K.; Kelley, J. H.; Berger, B. J.

1979-01-01

Projections are made for the demand and supply of hydrogen as chemical feedstock in USA. Industrial sectors considered are petroleum refining, ammonia synthesis, methanol production, isocyanate manufacture, edible oil processing, coal liquefaction, fuel cell electricity generation, and direct iron reduction. Presently, almost all the hydrogen required is produced by reforming of natural gas or petroleum fractions. Specific needs and emphases are recommended for future research and development to produce hydrogen from other sources to meet the requirements of these industrial sectors. The data and the recommendations summarized in this paper are based on the Workshop 'Supply and Demand of Hydrogen as Chemical Feedstock' held at the University of Houston on December 12-14, 1977.

Study on nickel and vanadium removal in thermal conversion of oil sludge and oil shale sludge

NASA Astrophysics Data System (ADS)

Sombral, L. G. S.; Pickler, A. C.; Aires, J. R.; Riehl, C. A.

2003-05-01

The petroleum refining processes and of oil shale industrialization generate solid and semi-solid residues. In those residues heavy metals are found in concentrations that vary according to the production sector. The destination of those residues is encouraging researches looking for new technologies that reach the specifications of environmental organisms, and are being developed and applied to the industry. In this work it is shown that the heavy metals concentrations, previously in the petroleum oily solid residues and in those of the oils shale, treated by low temperature thermal conversion, obtaining in both cases concentrations below Ippm to Nickel and below 5ppm to vanadium.

Formation of hydrocarbon compounds during the hydrocracking of non-edible vegetable oils with cobalt-nickel supported on hierarchical HZSM-5 catalyst

NASA Astrophysics Data System (ADS)

Marlinda, L.; Al-Muttaqii, M.; Roesyadi, A.; Prajitno, D. H.

2017-05-01

The hierarchical Co-Ni/HZSM-5 catalyst with hierarchical pore structure was prepared by desilication and incipient wetness impregnation. Hydrocracking of non-edible vegetable oils at temperature of 400 °C, 20±5 bar for 2 h was performed in the presence of this type of catalyst under hydrogen initial pressure in pressured batch reactor. Non-edible vegetable oils, such as Reutealis trisperma (Blanco) airy shaw (sunan candlenut) and Hevea brasiliensis (rubber seed) were chosen to study the effect of the degree of saturation and lateral chain length on hydrocarbon compounds obtained through hydrocracking. Cerbera manghas oil was also tested for comparison because the composition of fatty acid was different with the other oils The hydrocracking test indicated that liquid product produced has a similar hydrocarbon compounds with petroleum diesel. The most abundant hydrocarbon is pentadecane (n-C15) and heptadecane (n-C17). The high aromatic compounds were found in liquid product produced in hydrocracking of Sunan candlenut oil.

Ketonization of levulinic acid and γ-valerolactone to hydrocarbon fuel precursors

DOE PAGES

Lilga, Michael A.; Padmaperuma, Asanga B.; Auberry, Deanna L.; ...

2017-06-21

We studied a new process for direct conversion of either levulinic acid (LA) or γ-valerolactone (GVL) to hydrocarbon fuel precursors. The process involves passing an aqueous solution of LA or GVL containing a reducing agent, such as ethylene glycol or formic acid, over a ketonization catalyst at 380–400 °C and atmospheric pressure to form a biphasic liquid product. The organic phase is significantly oligomerized and deoxygenated and comprises a complex mixture of open-chain alkanes and olefins, aromatics, and low concentrations of ketones, alcohols, ethers, and carboxylates or lactones. Carbon content in the aqueous phase decreases with decreasing feed rate; themore » aqueous phase can be reprocessed through the same catalyst to form additional organic oils to improve carbon yield. Catalysts are readily regenerated to restore initial activity. Furthermore, the process might be valuable in converting cellulosics to biorenewable gasoline, jet, and diesel fuels as a means to decrease petroleum use and decrease greenhouse gas emissions.« less

Refinery Integration of By-Products from Coal-Derived Jet Fuels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Caroline Clifford; Andre Boehman; Chunshan Song

2008-03-31

The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using knownmore » refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler designed for natural gas/fuel oil, and determining the boiler performance when firing the five fuels. Two different co-processed fuel oils were tested: one that had been partially hydrotreated, and the other a product of fractionation before hydrotreating. Task 5 focused on examining refining methods that would utilize coal and produce thermally stable jet fuel, included delayed coking and solvent extraction. Delayed coking was done on blends of decant oil and coal, with the goal to produce a premium carbon product and liquid fuels. Coking was done on bench scale and large laboratory scale cokers. Two coals were examined for co-coking, using Pittsburgh seam coal and Marfork coal product. Reactions in the large, laboratory scaled coker were reproducible in yields of products and in quality of products. While the co-coke produced from both coals was of sponge coke quality, minerals left in the coke made it unacceptable for use as anode or graphite grade filler.« less

Rapid identification of oil-contaminated soils using visible near-infrared diffuse reflectance spectroscopy.

PubMed

Chakraborty, Somsubhra; Weindorf, David C; Morgan, Cristine L S; Ge, Yufeng; Galbraith, John M; Li, Bin; Kahlon, Charanjit S

2010-01-01

In the United States, petroleum extraction, refinement, and transportation present countless opportunities for spillage mishaps. A method for rapid field appraisal and mapping of petroleum hydrocarbon-contaminated soils for environmental cleanup purposes would be useful. Visible near-infrared (VisNIR, 350-2500 nm) diffuse reflectance spectroscopy (DRS) is a rapid, nondestructive, proximal-sensing technique that has proven adept at quantifying soil properties in situ. The objective of this study was to determine the prediction accuracy of VisNIR DRS in quantifying petroleum hydrocarbons in contaminated soils. Forty-six soil samples (including both contaminated and reference samples) were collected from six different parishes in Louisiana. Each soil sample was scanned using VisNIR DRS at three combinations of moisture content and pretreatment: (i) field-moist intact aggregates, (ii) air-dried intact aggregates, (iii) and air-dried ground soil (sieved through a 2-mm sieve). The VisNIR spectra of soil samples were used to predict total petroleum hydrocarbon (TPH) content in the soil using partial least squares (PLS) regression and boosted regression tree (BRT) models. Each model was validated with 30% of the samples that were randomly selected and not used in the calibration model. The field-moist intact scan proved best for predicting TPH content with a validation r2 of 0.64 and relative percent difference (RPD) of 1.70. Because VisNIR DRS was promising for rapidly predicting soil petroleum hydrocarbon content, future research is warranted to evaluate the methodology for identifying petroleum contaminated soils.

Catalyst for hydrotreating carbonaceous liquids

DOEpatents

Berg, Lloyd; McCandless, Frank P.; Ramer, Ronald J.

1982-01-01

A catalyst for denitrogenating and desulfurating carbonaceous liquid such as solvent refined coal includes catalytic metal oxides impregnated within a porous base of mostly alumina with relatively large pore diameters, surface area and pore volume. The base material includes pore volumes of 0.7-0.85 ml/g, surface areas of 200-350 m.sup.2 /g and pore diameters of 85-200 Angstroms. The catalytic metals impregnated into these base materials include the oxides of Group VI metals, molybdenum and tungsten, and the oxides of Group VIII metals, nickel and cobalt, in various combinations. These catalysts and bases in combination have effectively promoted the removal of chemically combined sulfur and nitrogen within a continuous flowing mixture of carbonaceous liquid and hydrogen gas.

Microwave effects on NiMoS and CoMoS single-sheet catalysts.

PubMed

Borges, I; Silva, Alexander M; Modesto-Costa, Lucas

2018-05-04

Single-sheet nanoclusters of MoS 2 , NiMoS or CoMoS are widely used in hydrodesulfurization (HDS) catalysis in the petroleum industry. In HDS reactions under microwave irradiation, experiments indirectly pointed out that for pristine MoS 2 reaction rates are accelerated because hot spots are generated on the catalyst bed. In this work, we investigated NiMoS and CoMoS isolated single-sheet substituted catalysts before and after thiophene adsorption focusing on quantifying the effect of microwave irradiation. For that purpose, density functional theory (DFT) molecular charge densities of each system were decomposed according to the distributed multipole analysis (DMA) of Stone. Site dipole values of each system were directly associated with a larger or smaller interaction with the microwave field according to a proposed general approach. We showed that microwave enhancement of HDS reaction rates can occur more efficiently in the CoMoS and NiMoS promoted clusters compared to pristine MoS 2 in the following order: CoMoS > NiMoS > MoS 2 . The atomic origin of the catalyst hot spots induced by microwaves was clearly established in the promoted clusters.

Coprocessing of plastics with coal and petroleum resid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Joo, H.; Curtis, C.W.

1995-12-31

Waste plastics have become an increasing problem in the United States since land filling is no longer considered a feasible disposal method. Since plastics are petroleum-derived materials, coprocessing then with coal to produce transportation fuels is a feasible alternative. In this study, catalytic coprocessing reactions were performed using Blind Canyon bituminous coal, Manji petroleum resid, and waste plastics. Model polymers including polystyrene, low density polyethylene (LDPE) and polyethylene tereplithalare (PET) were selected because they represent a substantial portion of the waste plastics generated in the United States. Coprocessing reactions of coal, resid, and polymer as well as reactions of individualmore » components and combinations of two components were performed at 430{degrees}C for one hour with an initial H{sub 2} pressure of 8.5 MPa introduced at ambient temperature with presulfided NiMo/Al{sub 2}O{sub 3} as catalyst. Coprocessing all three materials resulted in a substantial improvement in the total conversion compared to the coal plus polymer reaction and slightly less conversion than the resid plus polymer combinations.« less

Analyzing the Effects of the Weapon Systems Acquisition Reform Act

DTIC Science & Technology

2014-06-01

otherwise, an ICD is developed. The ICD is the first key document that JCIDS contributes to the acquisition system. This document feeds into the MSA...WSARA is the initiator of bottom-line change, if not the catalyst for changes that occur. . The bottom line in the corporate world is profit. For a...combat engineering, force sustainment, petroleum and water, sets, kits, outfits and tools, test 22 measurement and diagnostic equipment, and

Analyzing the Effects of the Weapon Systems Acquisition Reform Act

DTIC Science & Technology

2014-05-28

an ICD is developed. The ICD is the first key document that JCIDS contributes to the acquisition system. This document feeds into the MSA and the...make an assumption that the WSARA is the initiator of bottom-line change, if not the catalyst for changes that occur. The bottom line in the...force sustainment, petroleum and water, sets, kits, outfits and tools, test measurement and diagnostic equipment, and contingency basing infrastructure

Environmental hazard and risk characterisation of petroleum substances: a guided "walking tour" of petroleum hydrocarbons.

PubMed

Bierkens, Johan; Geerts, Lieve

2014-05-01

Petroleum substances are used in large quantities, primarily as fuels. They are complex mixtures whose major constituents are hydrocarbons derived from crude oil by distillation and fractionation. Determining the complete molecular composition of petroleum and its refined products is not feasible with current analytical techniques because of the huge number of molecular components. This complex nature of petroleum products, with their varied number of constituents, all of them exhibiting different fate and effect characteristics, merits a dedicated hazard and risk assessment approach. From a regulatory perspective they pose a great challenge in a number of REACH processes, in particular in the context of dossier and substance evaluation but also for priority setting activities. In order to facilitate the performance of hazard and risk assessment for petroleum substances the European oil company association, CONCAWE, has developed the PETROTOX and PETRORISK spreadsheet models. Since the exact composition of many petroleum products is not known, an underlying assumption of the PETROTOX and PETRORISK tools is that the behaviour and fate of a total petroleum substance can be simulated based on the physical-chemical properties of representative structures mapped to hydrocarbon blocks (HBs) and on the relative share of each HB in the total mass of the product. To assess how differing chemical compositions affect the simulated chemical fate and toxicity of hydrocarbon mixtures, a series of model simulations were run using an artificial petroleum substance, containing 386 (PETROTOX) or 160 (PETRORISK) HBs belonging to different chemical classes and molecular weight ranges, but with equal mass assigned to each of them. To this artificial petroleum substance a guided series of subsequent modifications in mass allocation to a delineated number of HBs belonging to different chemical classes and carbon ranges was performed, in what we perceived as a guided "walking tour" through the chemical space of petroleum substances. We show that the PETROTOX and PETRORISK predictions reflect changes in mass distribution introduced to selected HBs by affecting hazard and risk estimates in correspondence with what is expected based on physical-chemical properties of individual constituents in the corresponding HBs. Copyright © 2014 Elsevier Ltd. All rights reserved.

Iran`s petroleum policy: Current trends and the future outlook

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pezeshki, S.; Fesharaki, F.

1994-12-01

The Iranian economy and political situation have undergone radical changes since the 1979 Islamic revolution. The excesses of the early years of the revolution have gradually given way to moderation and a more pragmatic economic policy--based on the principles of the free market. The petroleum policy, as a subset of the economic policies, has been somewhat affected by the political and economic developments in Iran. The petroleum policy has changed from a position of no foreign participation to a position that includes a desire for foreign participation, the text of a model contract, and an attempt to introduce new technologiesmore » in the upstream sector. This report provides an overview of the key issues facing the Iranian oil industry and the economic context in which the oil industry is operating in Iran. It describes the evolution of policies meant to move the oil industry toward the free market; it discusses Iran`s oil trading partners, the outlook for refining and project investments, and current and likely future developments in the natural gas and petrochemical sectors. In short, the report provides an up-to-date assessment of the Iranian petroleum sector and its likely evolution in the future.« less

Isolation, biomass estimation and characterization of the biofuel potential of diatom Navicula Sphaerophora

NASA Astrophysics Data System (ADS)

Papu, Nabam Hina; Lingfa, Pradip

2018-04-01

Navicula Sphaerophora was isolated from a fresh water reservoir in Arunachal Pradesh, India. N. Sphaerophora was grown on two different culture media, chu13 medium and Miracle Gro-medium. The maximum yield was obtained by using culture medium chu13(5.08 g/100ml of culture media). Microalgae crude oil was extracted using soxhlation method with three different solvents n-hexane, iso-propanol and hexane/ iso-propanol mixture. The maximum crude oil was obtained using n-hexane as a solvent (13.8% of dry weight biomass). The crude oil was converted into biodiesel using single stage transesterification process with sodium hydroxide (NaOH) as a base catalyst. Fuel properties of algae biodiesel satisfied biodiesel standard ASTM D6751 and use of this fuel should be comparable with petroleum diesel. Further short term engine test was conducted on single cylinder direct injection diesel engine at four different load (25%,50%,75% and 100%). Three different petroleum diesel and Microalgae Biodiesel blends (10%, 20% and 30%) were prepared. The influence of biodiesel blends on BSFC (brake specific fuel consumption), BTE (brake thermal efficiency), oxides of nitrogen (NOx), UBHC (unburnt hydrocarbons), carbonmonoxide (CO) and smoke opacity was studied and compared with petroleum diesel. Microalgae methyl ester 50% blend (B50) had lowest brake thermal efficiency (BTE) and highest Brake specific fuel consumption (BSFC) as compared to diesel; this may be due to Lower calorific value. HC, CO emission and smoke opacity reduces significantly with microalgae methyl ester. However, the NOx emission increases with all blends when compared to petroleum diesel. 10% microalgae blend with petroleum diesel showed the closet performance to petroleum diesel. Results obtained from present investigation confirmed the biofuel potentiality of Navicula Sphaerophora.

77 FR 21619 - Office of Commercial Space Transportation; Notice of Intent To Prepare an Environmental Impact...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-10

... rocket propellant-1 or refined petroleum-1 (RP-1), as propellants to carry payloads into orbit. The... tank with a maximum propellant (RP-1 and LOX) load of approximately 6,900 gallons. As part of the... processing-hangar, a launch pad and stand with its associated flame duct, propellant storage and handling...

Model for refining operations

NASA Technical Reports Server (NTRS)

Dunbar, D. N.; Tunnah, B. G.

1979-01-01

Program predicts production volumes of petroleum refinery products, with particular emphasis on aircraft-turbine fuel blends and their key properties. It calculates capital and operating costs for refinery and its margin of profitability. Program also includes provisions for processing of synthetic crude oils from oil shale and coal liquefaction processes and contains highly-detailed blending computations for alternative jet-fuel blends of varying endpoint specifications.

3 CFR - Expediting Review of Pipeline Projects From Cushing, Oklahoma, to Port Arthur, Texas, and Other...

Code of Federal Regulations, 2013 CFR

2013-01-01

..., the most important driver of the price here at home is the world oil price—making our economy... buildings, and facilitating the safe and responsible development of our natural gas resources. But for the... efficient cars and trucks, and a world-class refining sector that last year was a net exporter of petroleum...

Small Changes to Catalysts; Big Impacts for our Nation

ScienceCinema

Bullock, Morris; Shaw, Wendy; O'Hagan, Molly

2018-01-16

Hydrogen is at the heart of producing ammonia. It's what we need to make the fertilizers that grow our food, and to refine crude oil into fuels that meet clean air standards. But it is produced from non-renewable resources, typically natural gas.

Small Changes to Catalysts; Big Impacts for our Nation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bullock, Morris; Shaw, Wendy; O'Hagan, Molly

2013-08-29

Hydrogen is at the heart of producing ammonia. It's what we need to make the fertilizers that grow our food, and to refine crude oil into fuels that meet clean air standards. But it is produced from non-renewable resources, typically natural gas.

Water requirements of the petroleum refining industry

USGS Publications Warehouse

Otts, Louis Ethelbert

1964-01-01

About 3,500 million gallons of water was withdrawn daily in 1955 for use by petroleum refineries in the United States. This was about 3 percent of the estimated daily withdrawal of industrial water in the United States in 1955. An average of 468 gallons of water was required to refine a barrel of crude oil, and the median was 95 gallons of water per barrel of crude charge; withdrawals ranged from 6.5 to 3,240 gallons per barrel. Ninety-one percent of the water requirements of the petroleum refineries surveyed was for cooling. One-third of the refineries reused their cooling water from 10 to more than 50 times. Only 17 refineries used once-through cooling systems. Refineries with recirculating cooling systems circulated about twice as much cooling water but needed about 25 times less makeup; however, they consumed about 24 times more water per barrel of charge than refineries using once-through cooling systems. The average noncracking refinery used about 375 gallons of water per barrel of crude, which is less than the 471-gallon average of refineries with cracking facilities. Refineries are composed of various processing units, and the water requirements of such units varied ; median makeup needs ranged from about 125 gallons per barrel for polymerization and alkylation units to 15.5 gallons per barrel for distillation units. Refinery-owned sources of water supplied 95 percent of the makeup-water requirements. Surface-water sources provided 86 percent of the makeup-water demand. Less than 1 percent of the makeup water was obtained from reprocessed municipal sewage.

Liberian energy consumption and sectoral distribution for 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Samuels, G.

1985-02-01

This report is one of a series of project papers providing background information for an assessment of energy options for Liberia, West Africa; it summarizes 1981 Liberian energy consumption data collected during 1982. Total Liberian primary energy consumption in 1981 was equivalent to 11,400,000 barrels of crude oil (BCOE) - 64% from wood, 31% from petroleum, and 5% from hydro. About 71% (8,100,000 BCOE) entered the domestic market. The difference represents exports (400,000 BCOE), refining losses (200,000 BCOE), and losses in converting wood to charcoal (2,600,000 BCOE). Of the 8,100,000 BCOE entering the domestic market, 58% was in the formmore » of wood and charcoal, 35% petroleum products, and 7% hydro. Excluding wood and charcoal, electricity generation consumed 59% of the energy entering the domestic market. The three iron ore mining companies accounted for 60% of all electricity production; the Liberia Electricity Corporation for 35%, and private organizations and individuals for 5%. The mining operations (including electricity generation and transportation uses) consumed about 60% of all petroleum products. The transportation sector consumed 30% of all petroleum of which 85% was for road transport, 12% for the railroads owned and operated by the mining companies, and 3% for sea and air transport. Nontransportation energy use in the industrial, commercial, government, and agriculture and forestry sectors is small. Together, these sectors account for less than 10% of the petroleum products consumed. Wood and charcoal were used almost entirely by the residential sector, which also consumed an additional 530,000 BCOE of other fuels. Over 90% of the 530,000 BCOE was for electricity and 290,000 (56%) was from petroleum. Over half of the petroleum (150,000 BCOE) was for generation at the mines for their associated communities. 8 references, 10 tables.« less

Process development of short-chain polyols synthesis from corn stover by combination of enzymatic hydrolysis and catalytic hydrogenolysis.

PubMed

Fang, Zhen-Hong; Zhang, Jian; Lu, Qi-Ming; Bao, Jie

2014-09-01

Currently short-chain polyols such as ethanediol, propanediol, and butanediol are produced either from the petroleum feedstock or from the starch-based food crop feedstock. In this study, a combinational process of enzymatic hydrolysis with catalytic hydrogenolysis for short-chain polyols production using corn stover as feedstock was developed. The enzymatic hydrolysis of the pretreated corn stover was optimized to produce stover sugars at the minimum cost. Then the stover sugars were purified and hydrogenolyzed into polyols products catalyzed by Raney nickel catalyst. The results show that the yield of short-chain polyols from the stover sugars was comparable to that of the corn-based glucose. The present study provided an important prototype for polyols production from lignocellulose to replace the petroleum- or corn-based polyols for future industrial applications.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jarvis, Jacqueline M.; Sudasinghe, Nilusha M.; Albrecht, Karl O.

We apply Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) for direct characterization of iron-porphyrins in hydrothermal liquefaction (HTL) biocrude oils derived from two algae: Tetraselmis sp. and cyanobacteria. The ironporphyrin compounds are shown to cause catalyst bed plugging during hydroprocessing due to iron deposition. Inductively-coupled plasma optical emission spectrometry (ICPOES) was utilized for iron quantitation in the plugged catalyst beds formed through hydroprocessing of the two HTL biocrudes and identifies an enrichment of iron in the upper five centimeters of the catalyst bed for Tetraselmis sp. (Fe=100,728 ppm) and cyanobacteria (Fe=115,450 ppm). Direct infusion FT-ICR MS analysis ofmore » the two HTL biocrudes with optimized instrument conditions facilitates rapid screening and identification of iron-porphyrins without prior chromatographic separation. With FT-ICR MS we identify 138 unique iron-porphyrin compounds in the two HTL biocrudes that are structurally similar to metal-porphyrins (e.g. Ni and V) observed in petroleum. No ironporphyrins are observed in the cyanobacteria HTL biocrude after hydroprocessing, which indicates that iron-porphyrin structures in the HTL biocrude are degraded during hydroprocessing. Hydrodemetallization reactions that occur through hydroprocessing of HTL biocrudes could be responsible for the decomposition of iron-porphyrin structures leading to metal deposition in the catalyst bed that result in catalyst deactivation and bed plugging, and must be addressed for effective upgrading of algal HTL biocrudes.« less

Carbon nanotubes shynthesis in fluidized bed reactor equipped with a cyclone

NASA Astrophysics Data System (ADS)

Setyopratomo, P.; Sudibandriyo, M.; Wulan, P. P. D. K.

2018-03-01

This work aimed to observe the performance of a fluidized bed reactor which was equipped with a cyclone in the synthesis of carbon nanotubes (CNT) by chemical vapor deposition. Liquefied petroleum gas with a constant volumetric flow rate of 1940 cm3/minutes was fed to the reactor as a carbon source, while a combination of metal components of Fe-Co-Mo supported on MgO was used as catalyst. The CNT synthesis was carried out at a reaction temperature which was maintained at around 800 – 850 °C for 1 hour. The CNT yield was decreased sharply when the catalyst feed was increased. The carbon efficiency is directly proportional to the mass of catalyst fed. It was found from the experiment that the mass of as-grown CNT increased in proportion to the increase of the catalyst mass fed. A sharp increase of the mass percentage of carbon nanotubes entrainment happened when the catalyst feed was raised from 3 to 7 grams. Agglomerates of carbon nanotubes have been formed. The agglomerates composed of mutually entangled carbon nanotubes which have an outer diameter range 8 – 14 nm and an inner diameter range 4 – 10 nm, which confirmed that the multi-walled carbon nanotubes were formed in this synthesis. It was found that the mesopores dominate the pore structure of the CNT product and contribute more than 90 % of the total pore volume.

Kinetic Modeling of a Heterogeneous Fenton Oxidative Treatment of Petroleum Refining Wastewater

PubMed Central

Basheer Hasan, Diya'uddeen; Abdul Raman, Abdul Aziz; Wan Daud, Wan Mohd Ashri

2014-01-01

The mineralisation kinetics of petroleum refinery effluent (PRE) by Fenton oxidation were evaluated. Within the ambit of the experimental data generated, first-order kinetic model (FKM), generalised lumped kinetic model (GLKM), and generalized kinetic model (GKM) were tested. The obtained apparent kinetic rate constants for the initial oxidation step (k 2′), their final oxidation step (k 1′), and the direct conversion to endproducts step (k 3′) were 10.12, 3.78, and 0.24 min−1 for GKM; 0.98, 0.98, and nil min−1 for GLKM; and nil, nil, and >0.005 min−1 for FKM. The findings showed that GKM is superior in estimating the mineralization kinetics. PMID:24592152

Evaluating photo-degradation of COD and TOC in petroleum refinery wastewater by using TiO2/ZnO photo-catalyst.

PubMed

Aljuboury, Dheeaa Al Deen Atallah; Palaniandy, Puganeshwary; Abdul Aziz, Hamidi Bin; Feroz, Shaik; Abu Amr, Salem S

2016-09-01

The aim of this study is to investigate the performance of combined solar photo-catalyst of titanium oxide/zinc oxide (TiO 2 /ZnO) with aeration processes to treat petroleum wastewater. Central composite design with response surface methodology was used to evaluate the relationships between operating variables for TiO 2 dosage, ZnO dosage, air flow, pH, and reaction time to identify the optimum operating conditions. Quadratic models for chemical oxygen demand (COD) and total organic carbon (TOC) removals prove to be significant with low probabilities (<0.0001). The obtained optimum conditions included a reaction time of 170 min, TiO 2 dosage (0.5 g/L), ZnO dosage (0.54 g/L), air flow (4.3 L/min), and pH 6.8 COD and TOC removal rates of 99% and 74%, respectively. The TOC and COD removal rates correspond well with the predicted models. The maximum removal rate for TOC and COD was 99.3% and 76%, respectively at optimum operational conditions of TiO 2 dosage (0.5 g/L), ZnO dosage (0.54 g/L), air flow (4.3 L/min), reaction time (170 min) and pH (6.8). The new treatment process achieved higher degradation efficiencies for TOC and COD and reduced the treatment time comparing with other related processes.

Selective catalytic oxidation: a new catalytic approach to the desulfurization of natural gas and liquid petroleum gas for fuel cell reformer applications

NASA Astrophysics Data System (ADS)

Lampert, J.

In both natural gas and liquid petroleum gas (LPG), sulfur degrades the performance of the catalysts used in fuel reformers and fuel cells. In order to improve system performance, the sulfur must be removed to concentrations of less than 200 ppbv (in many applications to less than 20 ppbv) before the fuel reforming operation. Engelhard Corporation presents a unique approach to the desulfurization of natural gas and LPG. This new method catalytically converts the organic and inorganic sulfur species to sulfur oxides. The sulfur oxides are then adsorbed on a high capacity adsorbent. The sulfur compounds in the fuel are converted to sulfur oxides by combining the fuel with a small amount of air. The mixture is then heated from 250 to 270 °C, and contacted with a monolith supported sulfur tolerant catalyst at atmospheric pressure. When Engelhard Corporation demonstrated this catalytic approach in the laboratory, the result showed sulfur breakthrough to be less than 10 ppbv in the case of natural gas, and less than 150 ppbv for LPG. We used a simulated natural gas and LPG mixture, doped with a 50-170 ppmv sulfur compound containing equal concentrations of COS, ethylmercaptan, dimethylsulfide, methylethylsulfide and tetrahydrothiophene. There is no need for recycled H 2 as in the case for hydrodesulfurization.

Linking performance benchmarking of refinery process chemicals to refinery key performance indicators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cook, J.M.; Nieman, L.D.

In 1977 Solomon Associates, Inc. issued its first study of refining in the US entitled, Comparative Performance Analysis for Fuel Product Refineries, most commonly referred to as the Solomon Study, or the Fuels Study. In late 1993, both the Water and Waste Water Management, and Petroleum Divisions of Nalco Chemical Company came to the same conclusion; that they must have a better understanding of the Solomon Study process, and have some input to this system of measurement. The authors first approached Solomon Associates with the idea that a specific study should be done of specialty chemicals used in the refinery.more » They felt that this would result in two studies, one for water treatment applications, and one for process. The water treatment study came first, and was completed in 1993 with the United States Petroleum Refineries Water Treatment Performance Analysis for Operating Year 1993. The process study, entitled United States Petroleum Refinery Process Treatment Performance Analysis for Operating Years 1994--95 will be issued in the 2nd quarter of this year by Nalco/Exxon Energy Chemicals, L.P, which includes the combined resources of the former Petroleum Division of Nalco Chemical Company (including the petroleum related portions of most of its overseas companies), and the petroleum related specialty chemical operations of Exxon Chemical on a global basis. What follows is a recap of the process study focus, some examples of output, and comment on both the linkage to key refinery operating indicators, as well as the perception of the effect of such measurement on the supplier relationship of the future.« less

Simultaneous application of chemical oxidation and extraction processes is effective at remediating soil Co-contaminated with petroleum and heavy metals.

PubMed

Yoo, Jong-Chan; Lee, Chadol; Lee, Jeung-Sun; Baek, Kitae

2017-01-15

Chemical extraction and oxidation processes to clean up heavy metals and hydrocarbon from soil have a higher remediation efficiency and take less time than other remediation processes. In batch extraction/oxidation process, 3% hydrogen peroxide (H 2 O 2 ) and 0.1 M ethylenediaminetetraacetic acid (EDTA) could remove approximately 70% of the petroleum and 60% of the Cu and Pb in the soil, respectively. In particular, petroleum was effectively oxidized by H 2 O 2 without addition of any catalysts through dissolution of Fe oxides in natural soils. Furthermore, heavy metals bound to Fe-Mn oxyhydroxides could be extracted by metal-EDTA as well as Fe-EDTA complexation due to the high affinity of EDTA for metals. However, the strong binding of Fe-EDTA inhibited the oxidation of petroleum in the extraction-oxidation sequential process because Fe was removed during the extraction process with EDTA. The oxidation-extraction sequential process did not significantly enhance the extraction of heavy metals from soil, because a small portion of heavy metals remained bound to organic matter. Overall, simultaneous application of oxidation and extraction processes resulted in highly efficient removal of both contaminants; this approach can be used to remove co-contaminants from soil in a short amount of time at a reasonable cost. Copyright © 2016 Elsevier Ltd. All rights reserved.

Coal-oil coprocessing at HTI - development and improvement of the technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stalzer, R.H.; Lee, L.K.; Hu, J.

1995-12-31

Co-Processing refers to the combined processing of coal and petroleum-derived heavy oil feedstocks. The coal feedstocks used are those typically utilized in direct coal liquefaction: bituminous, subbituminous, and lignites. Petroleum-derived oil, is typically a petroleum residuum, containing at least 70 W% material boiling above 525{degrees}C. The combined coal and oil feedstocks are processed simultaneously with the dual objective of liquefying the coal and upgrading the petroleum-derived residuum to lower boiling (<525{degrees}C) premium products. HTI`s investigation of the Co-Processing technology has included work performed in laboratory, bench and PDU scale operations. The concept of co-processing technology is quite simple and amore » natural outgrowth of the work done with direct coal liquefaction. A 36 month program to evaluate new process concepts in coal-oil coprocessing at the bench-scale was begun in September 1994 and runs until September 1997. Included in this continuous bench-scale program are provisions to examine new improvements in areas such as: interstage product separation, feedstock concentrations (coal/oil), improved supported/dispersed catalysts, optimization of reactor temperature sequencing, and in-line hydrotreating. This does not preclude other ideas from DOE contracts and other sources that can lead to improved product quality and economics. This research work has led to important findings which significantly increased liquid yields, improved product quality, and improved process economics.« less

The Strategic Petroleum Reserve: History, Perspectives, and Issues

DTIC Science & Technology

2009-12-28

Germany , Greece, Hungary, Ireland, Italy, Japan, Republic of Korea, Luxembourg, the Netherlands, New Zealand, Norway, Portugal, Spain, Sweden...Iran. Firms providing, or insuring tankers carrying, refined product to Iran would also be included in the prohibition. The Drawdown Authorities The...taking place in the operation of oil markets after the experiences of the 1970s, and deregulation of oil price and supply. Sales of SPR oil authorized

Manufacturing Industries with High Concentrations of Scientists and Engineers Lead in 1965-77 Employment Growth. Science Resources Studies Highlights, April 20, 1979.

ERIC Educational Resources Information Center

National Science Foundation, Washington, DC. Div. of Science Resources Studies.

Presented are the results of a survey of over 100,000 manufacturing establishments, conducted for the National Science Foundation by the Bureau of Labor Statistics, covering average annual employment for calendar year 1977. Industries whose relative concentration of scientists and engineers was high in 1977, such as petroleum refining, chemicals,…

40 CFR 52.420 - Identification of plan.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Section 8.0 Nitrogen Dioxide 9/11/08 8/11/10, 75 FR 48566 Section 10.0 Lead 9/11/08 8/11/10, 75 FR 48566....0 Restrictions on Petroleum Refining Operations 9/11/08 8/11/10, 75 FR 48566 1112Control of Nitrogen.../Liquid Material Balance 9/11/08 8/11/10, 75 FR 48566 Appendix K Emission Estimation Methodologies 9/11/08...

40 CFR 52.420 - Identification of plan.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Section 8.0 Nitrogen Dioxide 9/11/08 8/11/10, 75 FR 48566 Section 10.0 Lead 9/11/08 8/11/10, 75 FR 48566....0 Restrictions on Petroleum Refining Operations 9/11/08 8/11/10, 75 FR 48566 1112Control of Nitrogen... to Determine Length of Rolling Period for Liquid/Liquid Material Balance 9/11/08 8/11/10, 75 FR 48566...

A comparative assessment of resource efficiency in petroleum refining

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, Jeongwoo; Forman, Grant S.; Elgowainy, Amgad

Because of increasing environmental and energy security concerns, a detailed understanding of energy efficiency and greenhouse gas (GHG) emissions in the petroleum refining industry is critical for fair and equitable energy and environmental policies. To date, this has proved challenging due in part to the complex nature and variability within refineries. In an effort to simplify energy and emissions refinery analysis, we delineated LP modeling results from 60 large refineries from the US and EU into broad categories based on crude density (API gravity) and heavy product (HP) yields. Product-specific efficiencies and process fuel shares derived from this study weremore » incorporated in Argonne National Laboratory’s GREET life-cycle model, along with regional upstream GHG intensities of crude, natural gas and electricity specific to the US and EU regions. The modeling results suggest that refineries that process relatively heavier crude inputs and have lower yields of HPs generally have lower energy efficiencies and higher GHG emissions than refineries that run lighter crudes with lower yields of HPs. The former types of refineries tend to utilize energy-intensive units which are significant consumers of utilities (heat and electricity) and hydrogen. Among the three groups of refineries studied, the major difference in the energy intensities is due to the amount of purchased natural gas for utilities and hydrogen, while the sum of refinery feed inputs are generally constant. These results highlight the GHG emissions cost a refiner pays to process deep into the barrel to produce more of the desirable fuels with low carbon to hydrogen ratio.« less

A Comparative Assessment of Resource Efficiency in Petroleum Refining

DOE Office of Scientific and Technical Information (OSTI.GOV)

Han, Jeongwoo; Forman, G; Elgowainy, Amgad

2015-10-01

Because of increasing environmental and energy security concerns, a detailed understanding of energy efficiency and greenhouse gas (GHG) emissions in the petroleum refining industry is critical for fair and equitable energy and environmental policies. To date, this has proved challenging due in part to the complex nature and variability within refineries. In an effort to simplify energy and emissions refinery analysis, we delineated LP modeling results from 60 large refineries from the US and EU into broad categories based on crude density (API gravity) and heavy product (HP) yields. Product-specific efficiencies and process fuel shares derived from this study weremore » incorporated in Argonne National Laboratory's GREET life-cycle model, along with regional upstream GHG intensities of crude, natural gas and electricity specific to the US and EU regions. The modeling results suggest that refineries that process relatively heavier crude inputs and have lower yields of HPs generally have lower energy efficiencies and higher GHG emissions than refineries that run lighter crudes with lower yields of HPs. The former types of refineries tend to utilize energy-intensive units which are significant consumers of utilities (heat and electricity) and hydrogen. Among the three groups of refineries studied, the major difference in the energy intensities is due to the amount of purchased natural gas for utilities and hydrogen, while the sum of refinery feed inputs are generally constant. These results highlight the GHG emissions cost a refiner pays to process deep into the barrel to produce more of the desirable fuels with low carbon to hydrogen ratio. (c) 2015 Argonne National Laboratory. Published by Elsevier Ltd.« less

A comparative assessment of resource efficiency in petroleum refining

DOE PAGES

Han, Jeongwoo; Forman, Grant S.; Elgowainy, Amgad; ...

2015-03-25

Because of increasing environmental and energy security concerns, a detailed understanding of energy efficiency and greenhouse gas (GHG) emissions in the petroleum refining industry is critical for fair and equitable energy and environmental policies. To date, this has proved challenging due in part to the complex nature and variability within refineries. In an effort to simplify energy and emissions refinery analysis, we delineated LP modeling results from 60 large refineries from the US and EU into broad categories based on crude density (API gravity) and heavy product (HP) yields. Product-specific efficiencies and process fuel shares derived from this study weremore » incorporated in Argonne National Laboratory’s GREET life-cycle model, along with regional upstream GHG intensities of crude, natural gas and electricity specific to the US and EU regions. The modeling results suggest that refineries that process relatively heavier crude inputs and have lower yields of HPs generally have lower energy efficiencies and higher GHG emissions than refineries that run lighter crudes with lower yields of HPs. The former types of refineries tend to utilize energy-intensive units which are significant consumers of utilities (heat and electricity) and hydrogen. Among the three groups of refineries studied, the major difference in the energy intensities is due to the amount of purchased natural gas for utilities and hydrogen, while the sum of refinery feed inputs are generally constant. These results highlight the GHG emissions cost a refiner pays to process deep into the barrel to produce more of the desirable fuels with low carbon to hydrogen ratio.« less

Supervised Machine-Learning-Based Determination of Three-Dimensional Structure of Metallic Nanoparticles

DOE PAGES

Timoshenko, Janis; Lu, Deyu; Lin, Yuewei; ...

2017-09-29

Tracking the structure of heterogeneous catalysts under operando conditions remains a challenge due to the paucity of experimental techniques that can provide atomic-level information for catalytic metal species. Here we report on the use of X-ray absorption near edge structure (XANES) spectroscopy and supervised machine learning (SML) for refining the three-dimensional geometry of metal catalysts. SML is used to unravel the hidden relationship between the XANES features and catalyst geometry. To train our SML method, we rely on ab-initio XANES simulations. Our approach allows one to solve the structure of a metal catalyst from its experimental XANES, as demonstrated heremore » by reconstructing the average size, shape and morphology of well-defined platinum nanoparticles. This method is applicable to the determination of the nanoparticle structure in operando studies and can be generalized to other nanoscale systems. In conclusion, it also allows on-the-fly XANES analysis, and is a promising approach for high-throughput and time-dependent studies.« less

Catalytic hydroprocessing of coal-derived gasification residues to fuel blending stocks: effect of reaction variables and catalyst on hydrodeoxygenation (HDO), hydrodenitrogenation (HDN), and hydrodesulfurization (HDS)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dieter Leckel

2006-10-15

Gas liquors, tar oils, and tar products resulting from the coal gasification of a high-temperature Fischer-Tropsch plant can be successfully refined to fuel blending components by the use of severe hydroprocessing conditions. High operating temperatures and pressures combined with low space velocities ensure the deep hydrogenation of refractory oxygen, sulfur, and nitrogen compounds. Hydrodeoxygenation, particularly the removal of phenolic components, hydrodesulfurization, and hydrodenitrogenation were obtained at greater than 99% levels using the NiMo and NiW on {gamma}-Al{sub 2}O{sub 3} catalysts. Maximum deoxygenation activity was achieved using the NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst having a maximum pore size distribution in the rangemore » of 110-220{angstrom}. The NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst, which also has a relatively high proportion of smaller pore sizes (35-60 {angstrom}), displays lower hydrogenation activity. 30 refs., 1 fig. 8 tabs.« less

An initial analysis of short- and medium-range correlations potential non-Pt catalysts in CoNx

NASA Astrophysics Data System (ADS)

Peterson, Joe

2009-10-01

A potential show stopper for the development of fuel cells for the commercial automotive industry is the design of low-cost catalysts. The best catalysts are based on platinum, which is a rare and expensive noble metal. Our group has been involved in the characterization of potential materials for non-Pt catalysts. In this presentation, I will present some preliminary neutron scattering data from a nanocrystalline powder sample of CoNx. It is apparent that the diffraction data cannot be analyzed with standard Riedveld refinement, and we have to invoke pair distribution function (PDF) analysis. The PDF provides insight into short-range correlations, as it measures the probabilities of short- and mid-range interatomic distances in a material. The analysis reveals a strong incoherent scattering response, which is indicative of the presence of hydrogen in the sample. After correcting for the incoherent scattering, one obtains the normalized scattering function S(Q), whose Fourier transform yields the PDF.

An initial analysis of short- and medium-range correlations potential non-Pt catalysts in CoNx

NASA Astrophysics Data System (ADS)

Peterson, Joe

2010-03-01

A potential show stopper for the development of fuel cells for the commercial automotive industry is the design of low-cost catalysts. The best catalysts are based on platinum, which is a rare and expensive noble metal. Our group has been involved in the characterization of potential materials for non-Pt catalysts. In this presentation, I will present some preliminary neutron scattering data from a nanocrystalline powder sample of CoNx. It is apparent that the diffraction data cannot be analyzed with standard Riedveld refinement, and we have to invoke pair distribution function (PDF) analysis. The PDF provides insight into short-range correlations, as it measures the probabilities of short- and mid-range interatomic distances in a material. The analysis reveals a strong incoherent scattering response, which is indicative of the presence of hydrogen in the sample. After correcting for the incoherent scattering, one obtains the normalized scattering function S(Q), whose Fourier transform yields the PDF.

Supervised Machine-Learning-Based Determination of Three-Dimensional Structure of Metallic Nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Timoshenko, Janis; Lu, Deyu; Lin, Yuewei

Tracking the structure of heterogeneous catalysts under operando conditions remains a challenge due to the paucity of experimental techniques that can provide atomic-level information for catalytic metal species. Here we report on the use of X-ray absorption near edge structure (XANES) spectroscopy and supervised machine learning (SML) for refining the three-dimensional geometry of metal catalysts. SML is used to unravel the hidden relationship between the XANES features and catalyst geometry. To train our SML method, we rely on ab-initio XANES simulations. Our approach allows one to solve the structure of a metal catalyst from its experimental XANES, as demonstrated heremore » by reconstructing the average size, shape and morphology of well-defined platinum nanoparticles. This method is applicable to the determination of the nanoparticle structure in operando studies and can be generalized to other nanoscale systems. In conclusion, it also allows on-the-fly XANES analysis, and is a promising approach for high-throughput and time-dependent studies.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pihl, Josh A.; Toops, Todd J.; Fisher, Galen B.

Lean gasoline engines running on ethanol/gasoline blends and equipped with a silver/alumina catalyst for selective catalytic reduction (SCR) of NO by ethanol provide a pathway to reduced petroleum consumption through both increased biofuel utilization and improved engine efficiency relative to the current stoichiometric gasoline engines that dominate the U.S. light duty vehicle fleet. A pre-commercial silver/alumina catalyst demonstrated high NO x conversions over a moderate temperature window with both neat ethanol and ethanol/gasoline blends containing at least 50% ethanol. Selectivity to NH 3 increases with HC dosing and ethanol content in gasoline blends, but appears to saturate at around 45%.more » NO 2 and acetaldehyde behave like intermediates in the ethanol SCR of NO. NH 3 SCR of NO x does not appear to play a major role in the ethanol SCR reaction mechanism. Ethanol is responsible for the low temperature SCR activity observed with the ethanol/gasoline blends. In conclusion, the gasoline HCs do not deactivate the catalyst ethanol SCR activity, but they also do not appear to be significantly activated by the presence of ethanol.« less

The economic production of alcohol fuels from coal-derived synthesis gas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kugler, E.L.; Dadyburjor, D.B.; Yang, R.Y.K.

1995-12-31

The objectives of this project are to discover, (1) study and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas. Specifically, alternative methods of preparing catalysts are to be investigated, and novel catalysts, including sulfur-tolerant ones, are to be pursued. (Task 1); (2) explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. (Task 1); (3) simulate by computer the most energy efficient and economically efficient process for converting coal to energy, with primary focus on converting syngas to fuel alcohols. (Task 2);more » (4) develop on the bench scale the best holistic combination of chemistry, catalyst, reactor and total process configuration integrated with the overall coal conversion process to achieve economic optimization for the conversion of syngas to liquid products within the framework of achieving the maximum cost effective transformation of coal to energy equivalents. (Tasks 1 and 2); and (5) evaluate the combustion, emission and performance characteristics of fuel alcohols and blends of alcohols with petroleum-based fuels. (Task 2)« less

Efficient and selective degradation of polyethylenes into liquid fuels and waxes under mild conditions.

PubMed

Jia, Xiangqing; Qin, Chuan; Friedberger, Tobias; Guan, Zhibin; Huang, Zheng

2016-06-01

Polyethylene (PE) is the largest-volume synthetic polymer, and its chemical inertness makes its degradation by low-energy processes a challenging problem. We report a tandem catalytic cross alkane metathesis method for highly efficient degradation of polyethylenes under mild conditions. With the use of widely available, low-value, short alkanes (for example, petroleum ethers) as cross metathesis partners, different types of polyethylenes with various molecular weights undergo complete conversion into useful liquid fuels and waxes. This method shows excellent selectivity for linear alkane formation, and the degradation product distribution (liquid fuels versus waxes) can be controlled by the catalyst structure and reaction time. In addition, the catalysts are compatible with various polyolefin additives; therefore, common plastic wastes, such as postconsumer polyethylene bottles, bags, and films could be converted into valuable chemical feedstocks without any pretreatment.

Efficient and selective degradation of polyethylenes into liquid fuels and waxes under mild conditions

PubMed Central

Jia, Xiangqing; Qin, Chuan; Friedberger, Tobias; Guan, Zhibin; Huang, Zheng

2016-01-01

Polyethylene (PE) is the largest-volume synthetic polymer, and its chemical inertness makes its degradation by low-energy processes a challenging problem. We report a tandem catalytic cross alkane metathesis method for highly efficient degradation of polyethylenes under mild conditions. With the use of widely available, low-value, short alkanes (for example, petroleum ethers) as cross metathesis partners, different types of polyethylenes with various molecular weights undergo complete conversion into useful liquid fuels and waxes. This method shows excellent selectivity for linear alkane formation, and the degradation product distribution (liquid fuels versus waxes) can be controlled by the catalyst structure and reaction time. In addition, the catalysts are compatible with various polyolefin additives; therefore, common plastic wastes, such as postconsumer polyethylene bottles, bags, and films could be converted into valuable chemical feedstocks without any pretreatment. PMID:27386559

Effect of impurities in polybutene on the quality of alkenylsuccinic anhydrides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yarmolyuk, B.M.; Pustovit, V.E.; Bereza, L.I.

1984-03-01

Synthesis of alkenylsuccini anhydrides (ASAs) was carried out in thermostable ampules at 230/sup 0/C in the course of 12 hours at an MA:PB molar ratio of 1.3:1 in a medium of prepurified petroleum xylene (30%). Freshly distilled maleic anhydride and industrial specimens of polybutene were used in the experiments. It was established that the main impurities which are formed in the production of polybutene and in its processing are ions of sodium, peroxide compounds and products of decomposition of the polymerization catalyst. The concentration of sodium ion was determined by an atomic adsorption method on an A-3000 instrument, the concentrationmore » of peroxides was determined by iodometry (3), and the concentration of catalyst decomposition products was determined from the amount of mechanical impurities.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Settle, Amy E.; Berstis, Laura; Rorrer, Nicholas A.

In this tutorial review, we provide an overview of heterogeneous Diels–Alder catalysis for the production of lignocellulosic biomass-derived aromatic compounds. Diels–Alder reactions afford an extremely selective and efficient route for carbon–carbon cycloadditions to produce intermediates that can readily undergo subsequent dehydration or dehydrogenation reactions for aromatization. As a result, catalysis of Diels–Alder reactions with biomass-derived dienes and dienophiles has seen a growth of interest in recent years; however, significant opportunities remain to (i) tailor heterogeneous catalyst materials for tandem Diels–Alder and aromatization reactions, and (ii) utilize biomass-derived dienes and dienophiles to access both conventional and novel aromatic monomers. As such,more » this review discusses the mechanistic aspects of Diels–Alder reactions from both an experimental and computational perspective, as well as the synergy of Brønsted–Lewis acid catalysts to facilitate tandem Diels–Alder and aromatization reactions. Heterogeneous catalyst design strategies for Diels–Alder reactions are reviewed for two exemplary solid acid catalysts, zeolites and polyoxometalates, and recent efforts for targeting direct replacement aromatic monomers from biomass are summarized. In conclusion, we point out important research directions for progressing Diels–Alder catalysis to target novel, aromatic monomers with chemical functionality that enables new properties compared to monomers that are readily accessible from petroleum.« less

Transesterification of coconut oil for FAME production using ultrasound

NASA Astrophysics Data System (ADS)

Supriadi, Eko; Marlinda, Lenny; Prajitno, Danawati Hari; Mahfud, Mahfud

2017-05-01

To overcome energy crisis, the vegetable oils-derived biofuel can be chosen as an alternative to petroleum-based diesel. The transesterification of coconut oil in methanol with K/γ-Al2O3 catalyst using ultrasound-assisted to produce fatty acid methyl ester (FAME) as one of type biofuel was studied. The reaction occurred in batch reactor at a 9 : 1 molar ratio of methanol to coconut oil. The following reaction conditions were used in the catalytic test : concentration of catalyst to oil of 0.5, 1.0, 1.5, 2.0, and 2.5%, the reaction time of 10, 20, 30, 60, 90, 120, and 150 s, and the frequency ultrasonication of 20 and 40 KHz. At first, the preparation of K/γ-Al2O3 catalyst was done and followed by transesterification process. After reaction, the phase separation and purification from impurities were done. Finally, FAME was analized based on this parameters, i.e., yield, density, viscosity, and flash point. FAME yield of 93.76% was obtained at the frequency ultrasonication of 40 kHz with K/γ-Al2O3 catalyst concentration to oil of 2.5 wt.% for 150 s. It's the best conditions for FAME production by transesterification of coconut oil using ultrasound-assisted.

Heterogeneous Diels–Alder catalysis for biomass-derived aromatic compounds

DOE PAGES

Settle, Amy E.; Berstis, Laura; Rorrer, Nicholas A.; ...

2017-05-17

In this tutorial review, we provide an overview of heterogeneous Diels–Alder catalysis for the production of lignocellulosic biomass-derived aromatic compounds. Diels–Alder reactions afford an extremely selective and efficient route for carbon–carbon cycloadditions to produce intermediates that can readily undergo subsequent dehydration or dehydrogenation reactions for aromatization. As a result, catalysis of Diels–Alder reactions with biomass-derived dienes and dienophiles has seen a growth of interest in recent years; however, significant opportunities remain to (i) tailor heterogeneous catalyst materials for tandem Diels–Alder and aromatization reactions, and (ii) utilize biomass-derived dienes and dienophiles to access both conventional and novel aromatic monomers. As such,more » this review discusses the mechanistic aspects of Diels–Alder reactions from both an experimental and computational perspective, as well as the synergy of Brønsted–Lewis acid catalysts to facilitate tandem Diels–Alder and aromatization reactions. Heterogeneous catalyst design strategies for Diels–Alder reactions are reviewed for two exemplary solid acid catalysts, zeolites and polyoxometalates, and recent efforts for targeting direct replacement aromatic monomers from biomass are summarized. In conclusion, we point out important research directions for progressing Diels–Alder catalysis to target novel, aromatic monomers with chemical functionality that enables new properties compared to monomers that are readily accessible from petroleum.« less

Energy Efficient Materials Manufacturing from Secondary Resources

NASA Astrophysics Data System (ADS)

Apelian, Diran; Mishra, Brajendra

Rare earths metals, including yttrium and scandium, are being increasingly used in clean energy technologies, colored phosphors, lasers and high intensity magnets. There are important defense applications such as fighter jet engines, missile guidance systems and space based satellite and communication systems, based on these metals. The commitment to clean energy technologies by various governments, as well as the projected growth in power and transportation sectors across the globe will certainly escalate the demand for rare earth metals and compounds. This demand implies that to ensure unhindered technological innovation, it is essential to possess secure supply chains for rare earth elements. The United States continues to be one of the largest consumers and importer of rare earths and the trend is expected to continue as the demand increases. In order to ensure secure rare earth supply and attenuate supply-demand imbalances post 2014, it is not only necessary to encourage and support exploration of newer reserves, build a rare earth stockpile, but it is also of utmost importance to look at opportunities to recycle and reuse Rare Earth Elements (REE) from secondary sources, such as post-consumer and manufacturing process wastes. This research describes the technological developments made to convert these valuable resources into functional manufactured materials for lighting industry, automotive and petroleum refining catalysts, and high density permanent magnets. In addition, production of rhenium from advanced aerospace alloys is also discussed from the perspective that it can be recovered for introduction in turbine alloys.

Biomass Pyrolysis to Hydrocarbon Fuels in the Petroleum Refining Context: Cooperative Research and Development Final Report, CRADA Number CRD-12-500

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chum, Helena L.

This work focuses on developing a thermochemical route to produce biofuels from agricultural wastes such as sugar cane bagasse, wood chips or corn stover; more specifically it intends to develop the biomass pyrolysis route, which produces bio-oils. Production of bio-oils by pyrolysis is a commercial technology. However, bio-oils are currently not being used for liquid fuels production. Although bio-oils can be produced by high-pressure liquefaction, pyrolysis is a less expensive technology. Nevertheless, bio-oils cannot be used directly as a transportation fuel without upgrading, since they are generally unstable, viscous, and acidic. Thus NREL and Petrobras intend to use their combinedmore » expertise to develop a two-step route to biofuels production: in the first step, a stable bio-oil is produced by NREL biomass pyrolysis technology, while in the second step it is upgraded by using two distinct catalytic processes under development by Petrobras. The first process converts bio-oil into gasoline, LPG, and fuel oil using the catalytic cracking process, while the second one, converts bio-oil into synthesis gas. Syngas gasification catalysts provided by both NREL and Petrobras will be tested. The work includes experiments at both sites to produce bio-oil and then biofuels, life-cycle analysis of each route, personnel training and development of analytical methods with a duration time of two years.« less

Quantitative determination of oxygen defects, surface lewis acidity, and catalytic properties of mesoporous MoO3/SBA-15 catalysts

NASA Astrophysics Data System (ADS)

González, Julio; Wang, Jin An; Chen, Lifang; Manríquez, Maria; Salmones, José; Limas, Roberto; Arellano, Ulises

2018-07-01

A set of MoO3/SBA-15 mesoporous catalysts were characterized with a variety of spectroscopic techniques and their crystalline structures were refined with Rietveld method. Oxygen defect concentration, crystallite size, phase composition, surface acidity, mesoporous regularity, and textural properties were reported. Both α-MoO3 and β-MoO3 phases coexisted but α-MoO3 was predominated. Oxygen defects were created in the orthorhombic structure and its concentration decreased from 3.08% for the 20 wt%MoO3/SBA-15 to 0.55% for the 25 wt%MoO3/SBA-15. All the MoO3/SBA-15 catalysts chiefly contained a big number of Lewis acid sites originating from oxygen defects in MoO3 crystals. In the absence of formic acid, the oxidation of 4,6-dibenzothiophene (4,6-DMDBT) in a model diesel was almost proportional to the number of Lewis acid sites. In the presence of formic acid, 4,6-DMDBT oxidation was significantly affected by the formation of surface peroxometallic complex and Lewis acidity. Formic acid addition could improve the ODS efficiency by promoting peroxometallic complex formation and enhancing oxidant stability. Under the optimal reaction condition using the best 15 and 20 wt%MoO3/SBA-15 catalysts, more than 99% 4,6-DMDBT could be removed at 70 °C within 30 min. This work confirmed that 4,6-DMDBT oxidation is a texture and particle size sensitive and Lewis acidity dependent reaction. This work also shows that crystalline structure refinement combination with experiments can gain new insights in the design of heterogeneous nanocatalysts and help to better understand the catalytic behavior in the oxidative desulfurization reactions.

Nickel, vanadium, and lead as indicators of sediment contamination of marina, refinery, and shipyard areas.

PubMed

Pereira, Thayane Lúcia; Wallner-Kersanach, Mônica; Costa, Luiza Dy Fonseca; Costa, Daniel Pereira; Baisch, Paulo Roberto Martins

2018-01-01

Metallic elements found in the aquatic environment may originate in areas where petroleum is refined and vessels are maintained and repaired. This study aims to assess contamination caused by nickel (Ni), lead (Pb), and vanadium (V) in sediment of the Lagoa dos Patos estuary (RS, Brazil) and to evaluate them as indicators of areas under the influence of petroleum products and antifouling paints. Surface sediments were collected in summer and in winter in areas of marinas, shipyards, refinery, and a control station. High Pb and V concentrations in shipyards and at the Yacht Club showed that some organisms may be affected by toxicity. High Pb results of the index of geoaccumulation (Igeo) were found at the Yacht Club and shipyards. Al, Ni, and V had similar distribution in the sediment in both seasons. Ni and V had high relation in winter at the Yacht Club and at the Santos Shipyard, thus suggesting that these elements come mainly from petroleum products. The same happened to the relations between Pb and V, as well as Pb and Ni at the Santos Shipyard. These elements are employed as useful tools as indicators to identify places with moderate to high localized anthropogenic inputs of petroleum derivatives and antifouling paints.

Wear resistance evaluation of palm fatty acid distillate using four-ball tribotester

NASA Astrophysics Data System (ADS)

Golshokouh, Iman; Ani, Farid Nasir; Syahrullail, S.

2012-06-01

Petroleum reserves are declining nowadays while ironically petroleum is a major source of pollution despite many uses. Researchers are in effort to find an alternative to replace petroleum as a lubricant. One of the best replace sources for petroleum is bio-oil. In this paper, a comparative study of friction and wear was carried out using a fourball tester. In this research, Palm Fatty Acid Distillate (PFAD) and Jatropha oil, two well-known oils from the vegetable family oils were compared with Hydraulic mineral oil and commercial mineral Engine oil. All investigated oils in this study are used in industries as lubricants. PFAD is a product from refined crude palm oil. It exists as a light brown solid at room temperature and Jatropa oil is produced from the seeds of the Jatropha cruces, a plant that grows in marginal lands. For the wear test, the experimental research condition was comparing four kind of oils with ASTM condition in which the load applied was 392N. The sliding speed was 1200rpm under the lubricant temperature of 75 degree Celsius. The experiment was run for 3600 seconds. The experimental results demonstrated that the PFAD and Jatropha oils exhibited better performance in term of friction and wear compared to Hydraulic and Engine mineral oils.

Future of American oil: the experts testify. [Fourteen professors, economists, ang financial experts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wyman, H. Jr.; Markun, P.M.

In this volume, the American Petroleum Institute has gathered from the record the Congressional testimony of fourteen authorities on two burning issues that deeply affect the petroleum industry. One is a bill to legalize divestiture/dismemberment of integrated oil companies of the United States--to limit these companies to just one aspect of petroleum development: exploration/production, transportation, refining, or marketing. The other proposal would prevent the oil companies, the nation's most experienced energy producers, from participating in developing other sources of energy. Ten testimonies on vertical divestiture are included: Legal Consequences of Dismemberment, Bator, Peter A.; The Energy Crisis and the Oilmore » Industry, Erickson, Edward W.; The Effect of Petroleum Divestiture on Price and Supply, Friedman, Barry A.; Twenty Years of Chaos, Gary, Raymond B.; International Aspects of Divestiture, Jacoby, Neil H.; Competition in the Petroleum Industry, Mancke, Richard B.; The Case for Vertical Integration, Mitchell, Edward J.; Pipelines: The Cost of Capital, Myers, Stewart C.; Vertical Integration into Oil Pipelines, Swenson, Gary L.; and Financing the Oil Industry, Wilson, Wallace W. Six testimonials on horizontal divestiture are entitled: Public Policy and the Monopoly Myth, Erickson, Edward W.; Justice Looks at Energy Diversification, Kauper, Thomas E.; Horizontal Diversification by Oil Companies, Moore, Thomas Gale; Oil Companies in the Coal Industry, Moyer, Reed; Oil Companies in the Uranium Industry, Ray, Dixy Lee; and Who's Mining the Coal, Wilson, Wallace W. (MCW)« less

Green diesel production via catalytic hydrogenation/decarboxylation of triglycerides and fatty acids of vegetable oil and brown grease

NASA Astrophysics Data System (ADS)

Sari, Elvan

Increase in the petroleum prices, projected increases in the world's energy demand and environmental awareness have shifted the research interest to the alternative fuel technologies. In particular, green diesel, vegetable oil/animal fat/waste oil and grease derived hydrocarbons in diesel boiling range, has become an attractive alternative to biodiesel---a mixture of fatty acid methyl esters, particularly due to its superior fuel properties that are similar to petroleum diesel. Hence, green diesel can be used as a drop-in fuel in the current diesel engines. The current technology for production of green diesel-hydrodeoxygenation of triglycerides and fatty acids over conventional hydrotreating catalysts suffers from fast catalyst deactivation in the absence of hydrogen combined with high temperatures and high fatty acid content in the feedstock. Additionally, excess hydrogen requirement for hydrodeoxygenation technique leads to high production costs. This thesis proposes a new technology-selective decarboxylation of brown grease, which is a mixture of fats and oils collected from waste water trap and rich in fatty acids, over a supported noble metal catalyst that overcomes the green diesel production challenges. In contrast to other feedstocks used for liquid biofuel production, brown grease is inexpensive and non-food competing feedstock, therefore the process finds solution to waste management issues, reduces the renewable fuel production cost and does not add to the global food shortage problems. Special catalyst formulations were developed to have a high activity and stability in the absence of hydrogen in the fatty acid decarboxylation process. The study shows how catalyst innovations can lead to a new technology that overcomes the process challenges. First, the effect of reaction parameters on the activity and the selectivity of brown grease decarboxylation with minimum hydrogen consumption over an activated carbon supported palladium catalyst were investigated. A 90% conversion of brown grease in a semi-batch mode was obtained in 7 hours. In contrast, in a batch reaction the conversion was roughly 40% in the same reaction time. However, by pre-treating the "as received" brown grease with H 2, the conversion in a batch reactor was increased 1.4--fold; and when the H2 to BG ratio was increased to 3/1 (mol/mol), the conversion was further improved. Therefore, such a two-step processing with selective hydrogenation prior to the decarboxylation of BG improves the product selectivity. The commercial 5% Pd/C catalyst was highly active for the decarboxylation of brown grease to green diesel at 300 °C and 1.5 MPa. Second, a class of Pd catalyst supported on a silica-activated carbon nanocomposite for free fatty acid decarboxylation was developed, and displayed excellent activity and operation stability selectively for the green diesel hydrocarbons formation in the absence of hydrogen under mild reaction conditions. The decarboxylation activities of different amount of silica containing catalysts were investigated in a batch reactor under inert gas. Among them, the formulation with the fewer oxygen surface groups (Pd/Si--C--4) was the most active catalyst for the decarboxylation of an unsaturated fatty acid. The high activity of the Pd/Si--C--4 catalyst is attributed to its accessible and well-distributed metallic Pd nanoparticles inside hybrid mesopores as well as to its low acidity, weak surface interactions and inertness. Thus, Pd supported on carbon modified with silica may be regarded as a prospective decarboxylation catalyst for the removal of oxygen from vegetable oil/animal fat without the need of additional hydrogen. Third, in order to design a suitable catalyst for conversion of brown grease to green diesel, a systematic study of the model compounds--oleic acid was conducted on various catalysts in super-critical water to understand the reaction pathways in the absence of hydrogen. A Si--C support was more effective than activated carbon itself for both decarboxylation of oleic acid and hydrogenation of alkenes. In an additional effort to reduce Pd amount in the catalyst, Pd2Co/C catalysts with various Pd content were prepared and the catalytic activity study showed that 0.5 wt% Pd2Co/C catalyst performs even better than a 5 wt% Pd/C catalyst. Pd and Co alloys were very well dispersed and formed fine clusters, which led to a higher active metal surface area and hence favored the decarboxylation of oleic acid. This study showed that an alloy of Pd on carbon with a significantly low Pd content is much more active and selective to diesel hydrocarbons production from an unsaturated fatty acid in super-critical water and may be regarded as a prospective feasible decarboxylation catalyst for the removal of oxygen from vegetable oil/animal fat without the need of additional hydrogen.

Bifunctional catalysts for upgrading of biomass-derived oxygenates: A review

DOE PAGES

Robinson, Allison M.; Hensley, Jesse E.; Medlin, J. Will

2016-06-21

Deoxygenation is an important reaction in the conversion of biomass-derived oxygenates to fuels and chemicals. A key route for biomass refining involves the production of pyrolysis oil through rapid heating of the raw biomass feedstock. Pyrolysis oil as produced is highly oxygenated, so the feasibility of this approach depends in large part on the ability to selectively deoxygenate pyrolysis oil components to create a stream of high-value finished products. Identification of catalytic materials that are active and selective for deoxygenation of pyrolysis oil components has therefore represented a major research area. One catalyst is rarely capable of performing the differentmore » types of elementary reaction steps required to deoxygenate biomass-derived compounds. For this reason, considerable attention has been placed on bifunctional catalysts, where two different active materials are used to provide catalytic sites for diverse reaction steps. Here, we review recent trends in the development of catalysts, with a focus on catalysts for which a bifunctional effect has been proposed. We summarize recent studies of hydrodeoxygenation (HDO) of pyrolysis oil and model compounds for a range of materials, including supported metal and bimetallic catalysts as well as transition-metal oxides, sulfides, carbides, nitrides, and phosphides. Particular emphasis is placed on how catalyst structure can be related to performance via molecular-level mechanisms. Finally, these studies demonstrate the importance of catalyst bifunctionality, with each class of materials requiring hydrogenation and C-O scission sites to perform HDO at reasonable rates.« less

On the hydrothermal stability of Cu/SSZ-13 SCR catalysts

DOE PAGES

Gao, Feng; Szanyi, Janos

2018-05-07

Cu/SSZ-13 SCR catalysts have been extensively studied in the past decade or so. Hydrothermal stability of these catalysts has been identified as the most important criterion for application. In this perspective, we describe recent atomic-level understanding of their hydrothermal stability. In particular, electron paramagnetic resonance (EPR) is shown to rather accurately quantify isolated Cu(II) ions and CuO clusters in fresh and aged catalysts to demonstrate the remarkable hydrothermal stability for Cu 2+ ions located in 6-membered ring windows, and the conversion of [Cu(OH)] + ions in Chabazite cages to CuO clusters. The hydrothermal stability difference of the two isolated Cu(II)more » ions is confirmed with DFT simulations and the conversion of [Cu(OH)] + to CuO is proposed to involve formation, migration and condensation of Cu(OH) 2 intermediates. The structural destructive role of CuO clusters is attributed to mesopore formation from their migration, which more severely damages the catalysts than dealumination. Lastly, perspectives are given on new strategies for low-temperature NO x removal, rational design and refinement of Cu/SSZ-13, and development of new Cu/zeolite SCR catalysts with even better performance than the state-of-the-art Cu/SSZ-13.« less

On the hydrothermal stability of Cu/SSZ-13 SCR catalysts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, Feng; Szanyi, Janos

Cu/SSZ-13 SCR catalysts have been extensively studied in the past decade or so. Hydrothermal stability of these catalysts has been identified as the most important criterion for application. In this perspective, we describe recent atomic-level understanding of their hydrothermal stability. In particular, electron paramagnetic resonance (EPR) is shown to rather accurately quantify isolated Cu(II) ions and CuO clusters in fresh and aged catalysts to demonstrate the remarkable hydrothermal stability for Cu 2+ ions located in 6-membered ring windows, and the conversion of [Cu(OH)] + ions in Chabazite cages to CuO clusters. The hydrothermal stability difference of the two isolated Cu(II)more » ions is confirmed with DFT simulations and the conversion of [Cu(OH)] + to CuO is proposed to involve formation, migration and condensation of Cu(OH) 2 intermediates. The structural destructive role of CuO clusters is attributed to mesopore formation from their migration, which more severely damages the catalysts than dealumination. Lastly, perspectives are given on new strategies for low-temperature NO x removal, rational design and refinement of Cu/SSZ-13, and development of new Cu/zeolite SCR catalysts with even better performance than the state-of-the-art Cu/SSZ-13.« less

A Systematic Approach to In Situ Bioremediation in Groundwater Including Decision Trees on In Situ Bioremediation for Nitrates, Carbon Tetrachloride, and Perchlorate

DTIC Science & Technology

2002-08-01

and Disease Registry (ATSDR). When conducting risk assessments , primary and secondary contaminants must be incorporated into the exposure...industry; acid production; textile bleaching; petroleum refining; refrigeration; production of pulp , paper , and rubber; as a catalytic agent in...memorandum from Michael Honeycutt, Ph.D., Toxicology and Risk Assessment Section, Office of Permitting, Remediation and Registration, Texas Natural Resource

Determining the Water Bootprint of the Army’s Supply Chain

DTIC Science & Technology

2011-05-01

water, flue gas desulfurization ) • Water consumption estimates will be compared with other modeling techniques Utility Energy Methods Army End Users...Sector Gas /Petroleum Refining Retail Less Gas /Retail Trade Food & Beverages/ Food & Drinking Places Concession/Personal Care Services CY10 Retail...this study • Data collected to support initial reporting of Greenhouse Gas (GHG) Inventory (pursuant to EO 13514) can be leveraged to support this

A user-centred design process of new cold-protective clothing for offshore petroleum workers operating in the Barents Sea

PubMed Central

NAESGAARD, Ole Petter; STORHOLMEN, Tore Christian Bjørsvik; WIGGEN, Øystein Nordrum; REITAN, Jarl

2017-01-01

Petroleum operations in the Barents Sea require personal protective clothing (PPC) to ensure the safety and performance of the workers. This paper describes the accomplishment of a user-centred design process of new PPC for offshore workers operating in this area. The user-centred design process was accomplished by mixed-methods. Insights into user needs and context of use were established by group interviews and on-the-job observations during a field-trip. The design was developed based on these insights, and refined by user feedback and participatory design. The new PPC was evaluated via field-tests and cold climate chamber tests. The insight into user needs and context of use provided useful input to the design process and contributed to tailored solutions. Providing users with clothing prototypes facilitated participatory design and iterations of design refinement. The group interviews following the final field test showed consensus of enhanced user satisfaction compared to PPC in current use. The final cold chamber test indicated that the new PPC provides sufficient thermal protection during the 60 min of simulated work in a wind-chill temperature of −25°C. Conclusion: Accomplishing a user-centred design process contributed to new PPC with enhanced user satisfaction and included relevant functional solutions. PMID:29046494

A user-centred design process of new cold-protective clothing for offshore petroleum workers operating in the Barents Sea.

PubMed

Naesgaard, Ole Petter; Storholmen, Tore Christian Bjørsvik; Wiggen, Øystein Nordrum; Reitan, Jarl

2017-12-07

Petroleum operations in the Barents Sea require personal protective clothing (PPC) to ensure the safety and performance of the workers. This paper describes the accomplishment of a user-centred design process of new PPC for offshore workers operating in this area. The user-centred design process was accomplished by mixed-methods. Insights into user needs and context of use were established by group interviews and on-the-job observations during a field-trip. The design was developed based on these insights, and refined by user feedback and participatory design. The new PPC was evaluated via field-tests and cold climate chamber tests. The insight into user needs and context of use provided useful input to the design process and contributed to tailored solutions. Providing users with clothing prototypes facilitated participatory design and iterations of design refinement. The group interviews following the final field test showed consensus of enhanced user satisfaction compared to PPC in current use. The final cold chamber test indicated that the new PPC provides sufficient thermal protection during the 60 min of simulated work in a wind-chill temperature of -25°C. Accomplishing a user-centred design process contributed to new PPC with enhanced user satisfaction and included relevant functional solutions.

Catalytic coal liquefaction process

DOEpatents

Garg, D.; Sunder, S.

1986-12-02

An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

Catalytic coal liquefaction process

DOEpatents

Garg, Diwakar; Sunder, Swaminathan

1986-01-01

An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.

Homogeneous catalytic hydrogenations of complex carbonaceous substrates. [16 references

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cox, J L; Wilcox, W A; Roberts, G L

1976-11-05

Results of homogeneous catalytic hydrogenation of complex unsaturated substrates including coal and coal-derived materials are reported, with organic soluble molecular complexes as catalysts. Among the substrates used were Hvab coal, solvent-refined coal, and COED pyrolysate. The hydrogenations were carried out in an autoclave. The results are summarized in tables.

Research on solvent-refined coal. Quarterly technical progress report, July 1-September 30, 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1982-07-01

This report describes progress on the Research on Solvent Refined Coal project by The Pittsburg and Midway Coal Mining Company's Merriam Laboratory during the third quarter of 1981. A four-part experiment was conducted with subbituminous Edna coal, pyrite and/or bituminous Ireland coal at 457/sup 0/C and 1800 psig or 450/sup 0/C and 2250 psig. The purpose was to determine the conditions appropriate for processing a 50/50 by weight blend of these coals. A total of four runs (11 experiments) discussed this quarter were directed toward the study of disposable catalysts. Subbituminous coals from the Edna and Belle Ayr Mines weremore » processed in the SRC II mode. Additives investigated were pyrite, ferric oxide, molybdenum doped ferric oxide and iron dispersed on silica-alumina. The level and type of sulfur added in conjunction with ferric oxide catalysts was also explored as well as addition of sulfur by itself. Two solvent hydrogenation runs and five SRC I runs were directed toward a preliminary investigation of short residence time processing of western (Belle Ayr) coals.« less

Selective Deoxygenation of Biomass‐Derived Bio‐oils within Hydrogen‐Modest Environments: A Review and New Insights

PubMed Central

Rogers, Kyle A.

2016-01-01

Abstract Research development of processes for refining bio‐oils is becoming increasingly popular. One issue that these processes possess is their high requirement for H2 gas. In response, researchers must develop catalysts that perform deoxygenation while minimizing H2 consumption—selective deoxygenation. Unlike traditional deoxygenation processes, selective deoxygenation reactions and catalysts represent an information gap that, prior to this publication, has yet to be reviewed. This review addresses the gap by providing both a summary of recent research developments and insight into future developments of new catalytic materials. Bifunctional catalysts containing a combination of oxophilicity and an active metal phase appear to be the most beneficial for selective deoxygenation processes in a H2‐modest environment. It is important that catalysts have a supply of disassociated hydrogen, because without such, activity and stability will suffer. The authors recommend to maximize the use of internally available hydrogen in bio‐fuel, which may be the only viable approach for deoxygenation if external H2 gas is limited. This would be possible through the development of catalysts that promote both the water–gas‐shift and deoxygenation reactions. PMID:27385663

Aerosols emitted in underground mine air by diesel engine fueled with biodiesel.

PubMed

Bugarski, Aleksandar D; Cauda, Emanuele G; Janisko, Samuel J; Hummer, Jon A; Patts, Larry D

2010-02-01

Using biodiesel in place of petroleum diesel is considered by several underground metal and nonmetal mine operators to be a viable strategy for reducing the exposure of miners to diesel particulate matter. This study was conducted in an underground experimental mine to evaluate the effects of soy methyl ester biodiesel on the concentrations and size distributions of diesel aerosols and nitric oxides in mine air. The objective was to compare the effects of neat and blended biodiesel fuels with those of ultralow sulfur petroleum diesel. The evaluation was performed using a mechanically controlled, naturally aspirated diesel engine equipped with a muffler and a diesel oxidation catalyst. The effects of biodiesel fuels on size distributions and number and total aerosol mass concentrations were found to be strongly dependent on engine operating conditions. When fueled with biodiesel fuels, the engine contributed less to elemental carbon concentrations for all engine operating modes and exhaust configurations. The substantial increases in number concentrations and fraction of organic carbon (OC) in total carbon over the baseline were observed when the engine was fueled with biodiesel fuels and operated at light-load operating conditions. Size distributions for all test conditions were found to be single modal and strongly affected by engine operating conditions, fuel type, and exhaust configuration. The peak and total number concentrations as well as median diameter decreased with an increase in the fraction of biodiesel in the fuels, particularly for high-load operating conditions. The effects of the diesel oxidation catalyst, commonly deployed to counteract the potential increase in OC emissions due to use of biodiesel, were found to vary depending upon fuel formulation and engine operating conditions. The catalyst was relatively effective in reducing aerosol number and mass concentrations, particularly at light-load conditions, but also showed the potential for an increase in nitrogen dioxide concentrations at high-load modes.

Current technologies, economics, and perspectives for 2,5-dimethylfuran production from biomass-derived intermediates.

PubMed

Saha, Basudeb; Abu-Omar, Mahdi M

2015-04-13

Since the U.S. Department of Energy (DOE) published a perspective article that described the potential of the top ten biomass-derived platform chemicals as petroleum replacements for high-value commodity and specialty chemicals, researchers around the world have been motivated to develop technologies for the conversion of biomass and biomass-derived intermediates into chemicals and fuels. Among several biorefinery processes, the conversion of biomass carbohydrates into 2,5-dimethylfuran (DMF) has received significant attention because of its low oxygen content, high energy content, and high octane value. DMF can further serve as a petroleum-replacement, biorenewable feedstock for the production of p-xylene (pX). In this review, we aim specifically to present a concise and up-to-date analysis of DMF production technologies with a critical discussion on catalytic systems, mechanistic insight, and process economics, which includes sensitivity analysis, so that more effective catalysts can be designed. Special emphasis has been given to bifunctional catalysts that improve DMF yields and selectivity and the synergistic effect of the bifunctional sites. Process economics for the current processes and the scope for further improvement are discussed. It is anticipated that the chemistry detailed in this review will guide researchers to develop more practical catalytic processes to enable the economic production of bio-based DMF. Processes for the upgrade of DMF to pX are also described. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Effect of pretreating of host oil on coprocessing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hajdu, P.E.; Tierney, J.W.; Wender, I.

1995-12-31

The principal objective of this research was to determine if coprocessing performance (i.e., coal conversion and oil yield) could be significantly improved by pretreating the heavy resid prior to reacting it with coal. For this purpose, two petroleum vacuum resids (1000{degrees}F+), one from the Amoco Co. and another from the Citgo Co., were used as such and after they had been pretreated by catalytic hydrogenation and hydrocracking reactions. The pretreatments were aimed at improving the host oil by; (1) converting any aromatic structures in the petroleum to hydroaromatic compounds capable of donating hydrogen, (2) cracking the heavy oil to lowermore » molecular weight material that might serve as a better solvent, (3) reducing the coking propensity of the heavy oil through the hydrogenation of polynuclear aromatic compounds, and (4) removing metals and heteroatoms that might poison a coprocessing catalyst. Highly dispersed catalysts, including fine particle Fe- and Mo-based, and dicobalt octacarbonyl, Co{sub 2}(CO){sub 8}, were used in this study. The untreated and pretreated resids were extensively characterized in order to determine chemical changes brought about by the pretreatments. The modified heavy oils were then coprocessed with an Illinois No. 6 coal as well as with a Wyodak coal, and compared to coprocessing with untreated resids under the same hydroliquefaction conditions. The amount of oil derived from coal was estimated by measuring the level of phenolic oxygen (derived mainly from coal) present in the oil products. Results are presented and discussed.« less

Membrane technology as a promising alternative in biodiesel production: a review.

PubMed

Shuit, Siew Hoong; Ong, Yit Thai; Lee, Keat Teong; Subhash, Bhatia; Tan, Soon Huat

2012-01-01

In recent years, environmental problems caused by the use of fossil fuels and the depletion of petroleum reserves have driven the world to adopt biodiesel as an alternative energy source to replace conventional petroleum-derived fuels because of biodiesel's clean and renewable nature. Biodiesel is conventionally produced in homogeneous, heterogeneous, and enzymatic catalysed processes, as well as by supercritical technology. All of these processes have their own limitations, such as wastewater generation and high energy consumption. In this context, the membrane reactor appears to be the perfect candidate to produce biodiesel because of its ability to overcome the limitations encountered by conventional production methods. Thus, the aim of this paper is to review the production of biodiesel with a membrane reactor by examining the fundamental concepts of the membrane reactor, its operating principles and the combination of membrane and catalyst in the catalytic membrane. In addition, the potential of functionalised carbon nanotubes to serve as catalysts while being incorporated into the membrane for transesterification is discussed. Furthermore, this paper will also discuss the effects of process parameters for transesterification in a membrane reactor and the advantages offered by membrane reactors for biodiesel production. This discussion is followed by some limitations faced in membrane technology. Nevertheless, based on the findings presented in this review, it is clear that the membrane reactor has the potential to be a breakthrough technology for the biodiesel industry. Copyright © 2012 Elsevier Inc. All rights reserved.

Magnetic susceptibility of petroleum fluids

NASA Astrophysics Data System (ADS)

Ivakhnenko, O. P.; Potter, D. K.

2003-04-01

Technological progress in petroleum exploration, production and processing requires a profound knowledge of the magnetic properties of the petroleum fluids. However, as far as we know there are not widely available constants of magnetic susceptibility for the majority of petroleum fluids. We have therefore measured the mass magnetic susceptibility (χ_m) of several petroleum fluids (such as crude oils, refined oil fractions, and formation waters) from local and worldwide sites. The magnetic features of natural reservoir petroleum fluids, together with fluids connected with the petroleum industry (such as drilling fluids etc.), fall into the following categories: diamagnetic solutions, paramagnetic suspensions and ferromagnetic "ferrofluid" suspensions. In the current investigations we have concentrated on the natural reservoir fluids, which are generally diamagnetic. There were distinct differences between the χ_m of the crude oils and the formation waters, with the oils having generally a more negative value of χ_m. The magnetic susceptibility of the oils appears to be related to their main physical and chemical properties, such as density, composition of group hydrocarbons, sulphur content and concentration of organometallic compounds. Low acidity and low sulphur oils have more negative values of χ_m. Light fractions of crude oil consisting mainly of paraffinic and naphtenic hydrocarbons are the most diamagnetic. The content of the less diamagnetic aromatics increases in the kerosene and gas oil fractions, and results in an increase in the magnetic susceptibility. Also, the magnetic susceptibility of the heavy oil fraction has a significantly higher χ_m than the light fractions, which appears to be connected with a higher concentration of paramagnetic components in the heavy fraction. The χ_m of the oil from various oil provinces were compared and found to be different. It seems that values of χ_m reflect specific features of the geological conditions for the oil and the geochemical history of the oil provinces.

Key structure-activity relationships in the vanadium phosphorus oxide catalyst system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thompson, M.R.; Ebner, J.R.

1990-04-01

The crystal structure of vanadyl pyrophosphate has been redetermined using single crystals obtained from a near solidified melt of a microcrystalline catalyst sample. Crystals that index as vanadyl pyrophosphate obtained from this melt are variable in color. Crystallographic refinement of the single crystal x-ray diffraction data indicates that structural differences among these materials can be described in terms of crystal defects associated with linear disorder of the vanadium atoms. The importance of the disorder is outlined in the context of its effect on the proposed surface topology parallel to (1,0,0). Models of the surface topology simply and intuitively account formore » the non-stoichometric surface atomic P/V ratio exhibited by selective catalysts of this phase. These models also point to the possible role of the excess phosphorus in providing site isolation of reactive centers at the surface. 33 refs., 7 figs.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xing, Rong; Dagle, Vanessa Lebarbier; Flake, Matthew

In this study we examine feasibility for steam reforming the mixed oxygenate aqueous fraction derived from mildly hydrotreated fast pyrolysis bio-oils. Catalysts selective towards hydrogen formation and resistant to carbon formation utilizing feeds with relatively low steam-to-carbon (S/C) ratios are desired. Rh (5 wt%), Pt (5 wt%), Ru (5 wt%), Ir (5 wt%), Ni (15 wt%), and Co (15 wt%) metals supported on MgAl 2O 4 were evaluated for catalytic performance at 500°C and 1 atm using a complex feed mixture comprising of acids, polyols, cycloalkanes, and phenolic compounds. The Rh catalyst was found to be the most active andmore » resistant to carbon formation. The Ni and Co catalysts were found to be more active than the other noble metal catalysts investigated (Pt, Ru, and Ir). However, Ni was found to form significantly more carbon (coke) on the catalyst surface. Furthermore, Co was found to be the most selective towards H 2 formation. Evaluating the effect of temperature on stability for the Rh catalyst we found that catalyst stability was best when operated at 500°C as compared to the higher temperatures investigated (700, 800°C). When operating at 700°C significantly more graphitic formation was observed on the spent catalyst surface. Operating at 800°C resulted in reactor plugging as a result of thermal decomposition of the reactants. Thus, a concept analogous to the petroleum industries’ use of a pre-reformer, operated at approximately 500°C for steam reforming of the heavier naphtha components, followed by a high temperature methane reforming operated in the 600-850°C temperature range, could be applied in the case of steam reforming biomass derived oxygenates. Moreover, stability evaluations were performed over the Rh, Ni, and Co catalysts at 500°C and 1 atm, under similar initial conversions, reveal the Co catalyst to be the most stable and selective towards H 2 production. Conversion and selectivity to CH 4 over Co remained relatively stable at approximately 80% and 1.2%, respectively. By contrast, the Rh and Ni catalysts CH 4 selectivity’s were approximately 7-8%. Thus suggesting that a Co type catalyst may be more suitable for the steam reforming of biomass derived oxygenates as compared to the more conventional Ni and Rh type steam reforming catalysts. However, deposition of carbon on the surface was observed. High resolution TEM on the spent catalysts revealed the formation of graphitic carbon on the Rh catalyst, and filamentous carbon formation was observed on both the Ni and Co catalysts, albeit less pronounced on Co. Thus there is certainly opportunity for improvement in Co catalyst design and/or with process optimization.« less

Can microbes economically remove sulfur

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fox, J.L.

Researchers have reported that refiners who now rely on costly physic-chemical procedures to desulfurize petroleum will soon have an alternative microbial-enzyme-based approach to this process. This new approach is still under development and considerable number chemical engineering problems need to be solved before this process is ready for large-scale use. This paper reviews the several research projects dedicated solving the problems that keep a biotechnology-based alternative from competing with chemical desulfurization.

Twin Screw Extruder Production of MTTP Decoy Flares SERDP WP-1240

DTIC Science & Technology

2005-12-01

5 3. Carnauba Wax ( wax from palm tree exudate, a common ingredient in high quality car polish) Hazards of the remaining formulations were...1. Microsere 5866, a microcrystalline wax derived from refining petroleum 2. Elvax 250, poly(ethylene-co-vinyl acetate) (hot glue ingredient...5866 Poor performance when 1-gm sample ignited Elvax 250 Poor performance when 1-gm sample ignited Carnuba Wax Poor performance when 1-gm sample

Expedient Measures in Postattack Industrial Recovery: Petroleum Refining

DTIC Science & Technology

1980-12-01

type of damage chAZge from superficial damage of [Fagile equipiivtt (e.g., iv- strtments with glass covers) vero buckling of heavy steel framing andj t...Pressure vessels, cylindrical A. horizontal, glass -lined 1 B. horizontal, unlined 48 1 C. horizontal, near ground 2 D. vertical 75 2 30. Package...Pressure vessels, cylindrical A. horizontal, glass -lined 320 350 30 B. horizontal, unlined 260 290 48 C. horizontal, near ground 230 250 48 D

Acute, Five- and Ten-Day Inhalation Study of Hydroprocessed Esters and Fatty Acids-Mixed Fats (HEFA-F) Jet Fuel

DTIC Science & Technology

2012-09-01

Groups ...................18 Table 6. Urine Specific Gravity in the Ten-Day Duration Groups ...............................................19 Table 7...exposed rats were not consistently significant compared to control groups and were considered random due to small group sizes. In urine samples...sources. Alternative fuels may be developed by synthesis from simpler molecules (e.g., natural gas) or by refining from non-petroleum sources (e.g

Translations on USSR Science and Technology, Biomedical and Behavioral Sciences, Number 21

DTIC Science & Technology

1978-02-03

L. M. Shabad, 193*0, some semifinished products of the aniline dye industry (G. E. Kleynenberg, 1938, 1939), amino- azo compounds (L. S...been reduced in connection with its diminished use in the production of azo dyes . A special medical supervision of workers at aniline dye production ...enterprises and carci- nogenic products of the aniline dye industry or resins and pitches of by- product coke and petroleum refining plants enter into

Alternative Sources of Energy - An Introduction to Fuel Cells

USGS Publications Warehouse

Merewether, E.A.

2003-01-01

Fuel cells are important future sources of electrical power and could contribute to a reduction in the amount of petroleum imported by the United States. They are electrochemical devices similar to a battery and consist of a container, an anode, a cathode, catalysts, an intervening electrolyte, and an attached electrical circuit. In most fuel cell systems, hydrogen is supplied to the anode and oxygen to the cathode which results in the production of electricity, water, and heat. Fuel cells are comparatively efficient and reliable, have no moving parts, operate without combustion, and are modular and scale-able. Their size and shape are flexible and adaptable. In operation, they are nearly silent, are relatively safe, and generally do not pollute the environment. During recent years, scientists and engineers have developed and refined technologies relevant to a variety of fuel cells. Types of fuel cells are commonly identified by the composition of their electrolyte, which could be either phosphoric acid, an alkaline solution, a molten carbonate, a solid metal oxide, or a solid polymer membrane. The electrolyte in stationary power plants could be phosphoric acid, molten carbonates, or solid metal oxides. For vehicles and smaller devices, the electrolyte could be an alkaline solution or a solid polymer membrane. For most fuel cell systems, the fuel is hydrogen, which can be extracted by several procedures from many hydrogen-bearing substances, including alcohols, natural gas (mainly methane), gasoline, and water. There are important and perhaps unresolved technical problems associated with using fuel cells to power vehicles. The catalysts required in several systems are expensive metals of the platinum group. Moreover, fuel cells can freeze and not work in cold weather and can be damaged by impacts. Storage tanks for the fuels, particularly hydrogen, must be safe, inexpensive, of a reasonable size, and contain a supply sufficient for a trip of several hundred miles. Additional major problems will be the extensive and costly changes in the national infrastructure to obtain, store, and distribute large amounts of the fuels, and in related manufacturing

Utilization of alternative fuels in diesel engines

NASA Technical Reports Server (NTRS)

Lestz, S. A.

1984-01-01

Performance and emission data are collected for various candidate alternate fuels and compare these data to that for a certified petroleum based number two Diesel fuel oil. Results for methanol, ethanol, four vegetable oils, two shale derived oils, and two coal derived oils are reported. Alcohol fumigation does not appear to be a practical method for utilizing low combustion quality fuels in a Diesel engine. Alcohol fumigation enhances the bioactivity of the emitted exhaust particles. While it is possible to inject many synthetic fuels using the engine stock injection system, wholly acceptable performance is only obtained from a fuel whose specifications closely approach those of a finished petroleum based Diesel oil. This is illustrated by the contrast between the poor performance of the unupgraded coal derived fuel blends and the very good performance of the fully refined shale derived fuel.

Ethanol mandate thrown out by appeals court

DOE Office of Scientific and Technical Information (OSTI.GOV)

Begley, R.

1995-05-10

In a victory for the oil industry, a federal appeals court has overturned EPA`s mandate for ethanol use in reformulated gasoline (REG), saying the agency lacks authority to require 30% of the oxygenate market be reserved for ethanol. EPA says the ruling does not prevent ethanols use in RFG - {open_quotes}It only says that EPA cannot dictate the recipe.{close_quotes} Charles DiBona, president of the American Petroleum Institute (API), says {open_quotes}API and its member companies are not opposed to the use of ethanol as an oxygenate. We oppose this illegal mandate.{close_quotes} Urvan Sternfels, president of the National Petroleum Refiners Association, says,more » {open_quotes}Mandating market shares for any product is unsound economic policy.{close_quotes} The two trade groups led the legal battle against the ethanol requirement.« less

Kinetic Evaluation of Lipid Oils Conversion to Biofuel Using Layered Double Hydroxide Doped with Triazabicyclodece Catalyst

NASA Astrophysics Data System (ADS)

Nato Lopez, Frank D.

Worldwide, there is an ever increasing need for sustainable, renewable fuels that will accommodate the rapidly increasing energy demand and provide independence from fossil fuels. The search for a sustainable alternative to petroleum based fuels has been a great challenge to the scientific community; therefore, great efforts are being made to overcome the fossil fuels dependence by exploring the prominent field of biofuels (bioethanol and biodiesel). Traditional biodiesel is produced from feedstocks such as vegetable oils and animal fats by converting the triglycerides with methanol in the presence of a homogeneous catalyst to produce fatty acid methyl esters (FAMEs). However, drawbacks of this process are the undesired glycerol byproduct and post reaction processing, including separation from reaction mixture, that results in high costs factors. In the present work, the reaction kinetics of a glycerol-free biodiesel method is studied. This method consists of the transesterification of a vegetable oil (i.e. canola oil) using dimethyl carbonate (DMC) as an alternative methylating agent in presence of layered double hydroxides doped with triazabicyclodecene catalyst (a basic organocatalyst). Furthermore, is theorized that this heterogeneous catalyst (TBD/LDH) simultaneously converts both FFAs and triglycerides due to acid sites formed by Al3+ active sites of the LDH structure. Additionally, the versatility of the Raman in situ technique was used as quantitative analysis tool to monitor the reaction kinetics and collect real time data.

Characterization of Catalyst Materials for Production of Aerospace Fuels

NASA Technical Reports Server (NTRS)

Best, Lauren M.; De La Ree, Ana B.; Hepp, Aloysius F.

2012-01-01

Due to environmental, economic, and security issues, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to non-petroleum sources as a feedstock for aviation (and other transportation) fuels. Additionally, efforts are concentrated on reducing costs coupled with fuel production from non-conventional sources. One solution to this issue is Fischer-Tropsch gas-to-liquid technology. Fischer-Tropsch processing of synthesis gas (CO/H2) produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fisher-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur or aromatic compounds. This process is most commonly catalyzed by heterogeneous (in this case, silver and platinum) catalysts composed of cobalt supported on alumina or unsupported alloyed iron powders. Physisorption, chemisorptions, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) are described to better understand the potential performance of Fischer-Tropsch cobalt on alumina catalysts promoted with silver and platinum. The overall goal is to preferentially produce C8 to C18 paraffin compounds for use as aerospace fuels. Progress towards this goal will eventually be updated and achieved by a more thorough understanding of the characterization of catalyst materials. This work was supported by NASA s Subsonic Fixed Wing and In-situ Resource Utilization projects.

Characterization of Catalyst Materials for Production of Aerospace Fuels

NASA Technical Reports Server (NTRS)

DeLaRee, Ana B.; Hepp, Aloysius F.

2011-01-01

Due to environmental, economic, and security issues, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to non-petroleum sources as a feedstock for aviation (and other transportation) fuels. Additionally, efforts are concentrated on reducing costs coupled with fuel production from non-conventional sources. One solution to this issue is Fischer-Tropsch gas-to-liquid technology. Fischer-Tropsch processing of synthesis gas (CO/H2) produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fisher-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur or aromatic compounds. This process is most commonly catalyzed by heterogeneous (in this case, silver and platinum) catalysts composed of cobalt supported on alumina or unsupported alloyed iron powders. Physisorption, chemisorptions, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) are described to better understand the potential performance of Fischer-Tropsch cobalt on alumina catalysts promoted with silver and platinum. The overall goal is to preferentially produce C8 to C18 paraffin compounds for use as aerospace fuels. Progress towards this goal will eventually be updated and achieved by a more thorough understanding of the characterization of catalyst materials. This work was supported by NASA s Subsonic Fixed Wing and In-situ Resource Utilization projects.

Mixed alkyl esters from cottonseed oil: Improved biodiesel properties and blends with ultra-low sulfur diesel fuel

USDA-ARS?s Scientific Manuscript database

Transesterification of refined cottonseed oil was carried out with methanol, ethanol, 1-butanol, and various mixtures of these alcohols at constant volume ratio of alcohol to oil (1:2) using KOH (1 wt%) as catalyst to produce biodiesel. In the mixed alcohol transesterifications, the formation of met...

Methods for recovering precious metals from industrial waste

NASA Astrophysics Data System (ADS)

Canda, L.; Heput, T.; Ardelean, E.

2016-02-01

The accelerated rate of industrialization increases the demand for precious metals, while high quality natural resources are diminished quantitatively, with significant operating costs. Precious metals recovery can be successfully made from waste, considered to be secondary sources of raw material. In recent years, concerns and interest of researchers for more increasing efficient methods to recover these metals, taking into account the more severe environmental protection legislation. Precious metals are used in a wide range of applications, both in electronic and communications equipment, spacecraft and jet aircraft engines and for mobile phones or catalytic converters. The most commonly recovered precious metals are: gold from jewellery and electronics, silver from X- ray films and photographic emulsions, industrial applications (catalysts, batteries, glass/mirrors), jewellery; platinum group metals from catalytic converters, catalysts for the refining of crude oil, industrial catalysts, nitric acid manufacturing plant, the carbon-based catalyst, e-waste. An important aspect is the economic viability of recycling processes related to complex waste flows. Hydrometallurgical and pyrometallurgical routes are the most important ways of processing electrical and electronic equipment waste. The necessity of recovering precious metals has opened new opportunities for future research.

Beyond Texas City: the state of process safety in the unionized U.S. oil refining industry.

PubMed

McQuiston, Thomas H; Lippin, Tobi Mae; Bradley-Bull, Kristin; Anderson, Joseph; Beach, Josie; Beevers, Gary; Frederick, Randy J; Frederick, James; Greene, Tammy; Hoffman, Thomas; Lefton, James; Nibarger, Kim; Renner, Paul; Ricks, Brian; Seymour, Thomas; Taylor, Ren; Wright, Mike

2009-01-01

The March 2005 British Petroleum (BP) Texas City Refinery disaster provided a stimulus to examine the state of process safety in the U.S. refining industry. Participatory action researchers conducted a nation-wide mail-back survey of United Steelworkers local unions and collected data from 51 unionized refineries. The study examined the prevalence of highly hazardous conditions key to the Texas City disaster, refinery actions to address those conditions, emergency preparedness and response, process safety systems, and worker training. Findings indicate that the key highly hazardous conditions were pervasive and often resulted in incidents or near-misses. Respondents reported worker training was insufficient and less than a third characterized their refineries as very prepared to respond safely to a hazardous materials emergency. The authors conclude that the potential for future disasters plagues the refining industry. In response, they call for effective proactive OSHA regulation and outline ten urgent and critical actions to improve refinery process safety.

Recent advances in petroleum microbiology.

PubMed

Van Hamme, Jonathan D; Singh, Ajay; Ward, Owen P

2003-12-01

Recent advances in molecular biology have extended our understanding of the metabolic processes related to microbial transformation of petroleum hydrocarbons. The physiological responses of microorganisms to the presence of hydrocarbons, including cell surface alterations and adaptive mechanisms for uptake and efflux of these substrates, have been characterized. New molecular techniques have enhanced our ability to investigate the dynamics of microbial communities in petroleum-impacted ecosystems. By establishing conditions which maximize rates and extents of microbial growth, hydrocarbon access, and transformation, highly accelerated and bioreactor-based petroleum waste degradation processes have been implemented. Biofilters capable of removing and biodegrading volatile petroleum contaminants in air streams with short substrate-microbe contact times (<60 s) are being used effectively. Microbes are being injected into partially spent petroleum reservoirs to enhance oil recovery. However, these microbial processes have not exhibited consistent and effective performance, primarily because of our inability to control conditions in the subsurface environment. Microbes may be exploited to break stable oilfield emulsions to produce pipeline quality oil. There is interest in replacing physical oil desulfurization processes with biodesulfurization methods through promotion of selective sulfur removal without degradation of associated carbon moieties. However, since microbes require an environment containing some water, a two-phase oil-water system must be established to optimize contact between the microbes and the hydrocarbon, and such an emulsion is not easily created with viscous crude oil. This challenge may be circumvented by application of the technology to more refined gasoline and diesel substrates, where aqueous-hydrocarbon emulsions are more easily generated. Molecular approaches are being used to broaden the substrate specificity and increase the rates and extents of desulfurization. Bacterial processes are being commercialized for removal of H(2)S and sulfoxides from petrochemical waste streams. Microbes also have potential for use in removal of nitrogen from crude oil leading to reduced nitric oxide emissions provided that technical problems similar to those experienced in biodesulfurization can be solved. Enzymes are being exploited to produce added-value products from petroleum substrates, and bacterial biosensors are being used to analyze petroleum-contaminated environments.

Recent Advances in Petroleum Microbiology

PubMed Central

Van Hamme, Jonathan D.; Singh, Ajay; Ward, Owen P.

2003-01-01

Recent advances in molecular biology have extended our understanding of the metabolic processes related to microbial transformation of petroleum hydrocarbons. The physiological responses of microorganisms to the presence of hydrocarbons, including cell surface alterations and adaptive mechanisms for uptake and efflux of these substrates, have been characterized. New molecular techniques have enhanced our ability to investigate the dynamics of microbial communities in petroleum-impacted ecosystems. By establishing conditions which maximize rates and extents of microbial growth, hydrocarbon access, and transformation, highly accelerated and bioreactor-based petroleum waste degradation processes have been implemented. Biofilters capable of removing and biodegrading volatile petroleum contaminants in air streams with short substrate-microbe contact times (<60 s) are being used effectively. Microbes are being injected into partially spent petroleum reservoirs to enhance oil recovery. However, these microbial processes have not exhibited consistent and effective performance, primarily because of our inability to control conditions in the subsurface environment. Microbes may be exploited to break stable oilfield emulsions to produce pipeline quality oil. There is interest in replacing physical oil desulfurization processes with biodesulfurization methods through promotion of selective sulfur removal without degradation of associated carbon moieties. However, since microbes require an environment containing some water, a two-phase oil-water system must be established to optimize contact between the microbes and the hydrocarbon, and such an emulsion is not easily created with viscous crude oil. This challenge may be circumvented by application of the technology to more refined gasoline and diesel substrates, where aqueous-hydrocarbon emulsions are more easily generated. Molecular approaches are being used to broaden the substrate specificity and increase the rates and extents of desulfurization. Bacterial processes are being commercialized for removal of H2S and sulfoxides from petrochemical waste streams. Microbes also have potential for use in removal of nitrogen from crude oil leading to reduced nitric oxide emissions provided that technical problems similar to those experienced in biodesulfurization can be solved. Enzymes are being exploited to produce added-value products from petroleum substrates, and bacterial biosensors are being used to analyze petroleum-contaminated environments. PMID:14665675

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dayton, David C; Kataria, Atish; Gupta, Rabhubir

The objective of the project is to develop and demonstrate a novel fluidized-bed process module called a Therminator to simultaneously destroy and/or remove tar, NH3 and H2S from raw syngas produced by a fluidized-bed biomass gasifier. The raw syngas contains as much as 10 g/m3 of tar, 4,000 ppmv of NH3 and 100 ppmv of H2S. The goal of the Therminator module would be to use promising regenerable catalysts developed for removing tar, ammonia, and H2S down to low levels (around 10 ppm). Tars are cracked to a non-condensable gas and coke that would deposit on the acid catalyst. Wemore » will deposit coke, much like a fluid catalytic cracker (FCC) in a petroleum refinery. The deposited coke fouls the catalyst, much like FCC, but the coke would be burned off in the regenerator and the regenerated catalyst would be returned to the cracker. The rapid circulation between the cracker and regenerator would ensure the availability of the required amount of regenerated catalyst to accomplish our goal. Also, by removing sulfur down to less than 10 ppmv, NH3 decomposition would also be possible in the cracker at 600-700°C. In the cracker, tar decomposes and lays down coke on the acid sites of the catalyst, NH3 is decomposed using a small amount of metal (e.g., nickel or iron) catalyst incorporated into the catalyst matrix, and H2S is removed by a small amount of a metal oxide (e.g. zinc oxide or zinc titanate) by the H2S-metal oxide reaction to form metal sulfide. After a tolerable decline in activity for these reactions, the catalyst particles (and additives) are transported to the regenerator where they are exposed to air to remove the coke and to regenerate the metal sulfide back to metal oxide. Sulfate formation is avoided by running the regeneration with slightly sub-stoichiometric quantity of oxygen. Following regeneration, the catalyst is transported back to the cracker and the cycling continues. Analogous to an FCC reactor system, rapid cycling will allow the use of very active cracking catalysts that lose activity due to coking within the order of several seconds.« less

Strategies for improving the performance and stability of Ni-based catalysts for reforming reactions.

PubMed

Li, Shuirong; Gong, Jinlong

2014-11-07

Owing to the considerable publicity that has been given to petroleum related economic, environmental, and political problems, renewed attention has been focused on the development of highly efficient and stable catalytic materials for the production of chemical/fuel from renewable resources. Supported nickel nanoclusters are widely used for catalytic reforming reactions, which are key processes for generating synthetic gas and/or hydrogen. New challenges were brought out by the extension of feedstock from hydrocarbons to oxygenates derivable from biomass, which could minimize the environmental impact of carbonaceous fuels and allow a smooth transition from fossil fuels to a sustainable energy economy. This tutorial review describes the recent efforts made toward the development of nickel-based catalysts for the production of hydrogen from oxygenated hydrocarbons via steam reforming reactions. In general, three challenges facing the design of Ni catalysts should be addressed. Nickel nanoclusters are apt to sinter under catalytic reforming conditions of high temperatures and in the presence of steam. Severe carbon deposition could also be observed on the catalyst if the surface carbon species adsorbed on metal surface are not removed in time. Additionally, the production of hydrogen rich gas with a low concentration of CO is a challenge using nickel catalysts, which are not so active in the water gas shift reaction. Accordingly, three strategies were presented to address these challenges. First, the methodologies for the preparation of highly dispersed nickel catalysts with strong metal-support interaction were discussed. A second approach-the promotion in the mobility of the surface oxygen-is favored for the yield of desired products while promoting the removal of surface carbon deposition. Finally, the process intensification via the in situ absorption of CO2 could produce a hydrogen rich gas with low CO concentration. These approaches could also guide the design of other types of heterogeneous base-metal catalysts for high temperature processes including methanation, dry reforming, and hydrocarbon combustion.

Executive Order 13514: Federal Leadership in Environmental, Energy, and Economic Performance; Comprehensive Federal Fleet Management Handbook (Book)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daley, R.; Ahdieh, N.; Bentley, J.

2014-01-01

A comprehensive Federal Fleet Management Handbook that builds upon the "Guidance for Federal Agencies on E.O. 13514 Section 12-Federal Fleet Management" and provides information to help fleet managers select optimal greenhouse gas and petroleum reduction strategies for each location, meeting or exceeding related fleet requirements, acquiring vehicles to support these strategies while minimizing fleet size and vehicle miles traveled, and refining strategies based on agency performance.

Energy conservation: Industry. Citations from the NITS data base

NASA Astrophysics Data System (ADS)

Hundemann, A. S.

1980-07-01

The 335 citations, 37 of which are new entries, discuss potential methods of conserving energy. Many abstracts deal with reports that also cover processes used, amount of energy consumed, and environmental considerations of energy conserving options. Industries covered include food, paper, chemical, cement, metals, petroleum refining, contract construction, synthetic rubber, plastics, drug manufacturing, and stone, clay, and glass. Energy conservation through the use of waste heat is covered in a related Published Search entitled Waste Heat Utilization.

Upgrading Lignocellulosic Products to Drop-In Biofuels via Dehydrogenative Cross-Coupling and Hydrodeoxygenation Sequence.

PubMed

Sreekumar, Sanil; Balakrishnan, Madhesan; Goulas, Konstantinos; Gunbas, Gorkem; Gokhale, Amit A; Louie, Lin; Grippo, Adam; Scown, Corinne D; Bell, Alexis T; Toste, F Dean

2015-08-24

Life-cycle analysis (LCA) allows the scientific community to identify the sources of greenhouse gas (GHG) emissions of novel routes to produce renewable fuels. Herein, we integrate LCA into our investigations of a new route to produce drop-in diesel/jet fuel by combining furfural, obtained from the catalytic dehydration of lignocellulosic pentose sugars, with alcohols that can be derived from a variety of bio- or petroleum-based feedstocks. As a key innovation, we developed recyclable transition-metal-free hydrotalcite catalysts to promote the dehydrogenative cross-coupling reaction of furfural and alcohols to give high molecular weight adducts via a transfer hydrogenation-aldol condensation pathway. Subsequent hydrodeoxygenation of adducts over Pt/NbOPO4 yields alkanes. Implemented in a Brazilian sugarcane biorefinery such a process could result in a 53-79% reduction in life-cycle GHG emissions relative to conventional petroleum fuels and provide a sustainable source of low carbon diesel/jet fuel. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Methyl ester of [Maclura pomifera (Rafin.) Schneider] seed oil: biodiesel production and characterization.

PubMed

Saloua, Fatnassi; Saber, Chatti; Hedi, Zarrouk

2010-05-01

Oil extracted from seeds of Maclura pomifera fruits grown in Tunisia was investigated as an alternative feedstock for the production of biodiesel fuel. Biodiesel was prepared by transesterification of the crude oil with methanol in the presence of NaOH as catalyst. Maximum oil to ester conversion was 90%. The viscosity of the biodiesel oil (4.66 cSt) is similar to that of petroleum diesel (2.5-3.5 cSt). The density (0.889 g/cm(3)), kinematic viscosity (4.66 cSt), flash point (180 degrees Celsius), iodine number (125 degrees Celsius), neutralization number (0.4), pour point (-9 degrees Celsius), cloud point (-5 degrees Celsius), cetane number (48) are very similar to the values set forth by the ASTM and EN biodiesel standards for petroleum diesel (No. 2). The comparison shows that the methyl esters of M. pomifera oil could be possible diesel fuel replacements. Copyright 2009 Elsevier Ltd. All rights reserved.

The growth of zeolites A, X and mordenite in space

NASA Technical Reports Server (NTRS)

Sacco, Albert, Jr.; Bac, N.; Coker, E. N.; Dixon, A. G.; Warzywoda, J.; Thompson, R. W.

1994-01-01

Zeolites are a class of crystalline aluminosilicate materials that form the backbone of the chemical process industry worldwide. They are used primarily as adsorbents and catalysts and support to a significant extent the positive balance of trade realized by the chemical industry in the United States (around $19 billion in 1991). The magnitude of their efforts can be appreciated when one realizes that since their introduction as 'cracking catalysts' in the early 1960's, they have saved the equivalent of 60 percent of the total oil production from Alaska's North Slope. Thus the performance of zeolite catalysts can have a profound effect on the U.S. economy. It is estimated that a 1 percent increase in yield of the gasoline fraction per barrel of oil would represent a savings of 22 million barrels of crude oil per year, representing a reduction of $400 million in the United States' balance of payments. Thus any activity that results in improvement in zeolite catalyst performance is of significant scientific and industrial interest. In addition, due to their 'stability,' uniformity, and, within limits, their 'engineerable' structures, zeolites are being tested as potential adsorbents to purify gases and liquids at the parts-per-billion levels needed in today's electronic, biomedical, and biotechnology industries and for the environment. Other exotic applications, such as host materials for quantum-confined semiconductor atomic arrays, are also being investigated. Because of the importance of this class of material, extensive efforts have been made to characterize their structures and to understand their nucleation and growth mechanisms, so as to be able to custom-make zeolites for a desired application. To date, both the nucleation mechanics and chemistry (such as what are the 'key' nutrients) are, as yet, still unknown for many, if not all, systems. The problem is compounded because there is usually a 'gel' phase present that is assumed to control the degree of supersaturation, and this gel undergoes a continuous 'polymerization' type reaction during nucleation and growth. Generally, for structure characterization and diffusion studies, which are useful in evaluating zeolites for improving yield in petroleum refining as well as for many of the proposed new applications (e.g., catalytic membranes, molecular electronics, chemical sensors) large zeolites (greater than 100 to 1000 times normal size) with minimum lattice defects are desired. Presently, the lack of understanding of zeolite nucleation and growth precludes the custom design of zeolites for these or other uses. It was hypothesized that the microgravity levels achieved in an orbiting spacecraft could help to isolate the possible effects of natural convection (which affects defect formation) and minimize sedimentation, which occurs since zeolites are twice as dense as the solution from which they are formed. This was expected to promote larger crystals by allowing growing crystals a longer residence time in a high-concentration nutrient field. Thus it was hypothesized that the microgravity environment of Earth orbit would allow the growth of large, more defect-free zeolite crystals in high yield.

Spontaneous mutual ordering of nucleic acids and proteins.

PubMed

Wills, Peter R

2014-12-01

It is proposed that the prebiotic ordering of nucleic acid and peptide sequences was a cooperative process in which nearly random populations of both kinds of polymers went through a codependent series of self-organisation events that simultaneously refined not only the accuracy of genetic replication and coding but also the functional specificity of protein catalysts, especially nascent aminoacyl-tRNA synthetase "urzymes".

Pop-Up Retailing: The Design, Implementation, and Five-Year Evolution of an Experiential Learning Project

ERIC Educational Resources Information Center

Burgess, Brigitte

2012-01-01

Educators continually seek innovative methods by which to engage students. Kolb's experiential learning theory was a catalyst for designing and incorporating a pop-up retail consignment store into a junior level retail promotion course. After five years of use and refinement, the project has proven to be a powerful method to engage students in the…

Research on solvent-refined coal. Quarterly technical progress report, April 1, 1981-June 30, 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1981-10-01

This report describes progress on the Research on Solvent Refined Coal project by The Pittsburg and Midway Coal Mining Co.'s Merriam Laboratory during the second quarter of 1981. Alexander Mine coal was evaluated as a feedstock for major liquefaction facilities and had a yield structure similar to other reactive Pittsburgh seam coals at standard SRC II conditions. Two lots of coal from the Ireland Mine (Pittsburgh seam) were found to be of nearly the same composition and produced essentially the same yields. Two experiments in which coal-derived nonvolatile organic matter was processed without fresh coal feed indicate constant rates ofmore » conversion of SRC to oil and gas. Insoluble organic matter (IOM) remained unconverted. The naphtha and middle distillate products from the deep conversion contained less sulfur but more nitrogen than those from conventional SRC II processing. Encouraging results were obtained when a very small amount of iron oxide dispersed on alumina was added to Kaiparowits coal which cannot be processed at normal SRC II conditions without added catalyst. Subbituminous coals from the McKinley and Edna Mines were processed successfully with added pyrite but would not run when the added catalyst was removed.« less

Modelling and validation of particle size distributions of supported nanoparticles using the pair distribution function technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gamez-Mendoza, Liliana; Terban, Maxwell W.; Billinge, Simon J. L.

The particle size of supported catalysts is a key characteristic for determining structure–property relationships. It is a challenge to obtain this information accurately andin situusing crystallographic methods owing to the small size of such particles (<5 nm) and the fact that they are supported. In this work, the pair distribution function (PDF) technique was used to obtain the particle size distribution of supported Pt catalysts as they grow under typical synthesis conditions. The PDF of Pt nanoparticles grown on zeolite X was isolated and refined using two models: a monodisperse spherical model (single particle size) and a lognormal size distribution.more » The results were compared and validated using scanning transmission electron microscopy (STEM) results. Both models describe the same trends in average particle size with temperature, but the results of the number-weighted lognormal size distributions can also accurately describe the mean size and the width of the size distributions obtained from STEM. Since the PDF yields crystallite sizes, these results suggest that the grown Pt nanoparticles are monocrystalline. This work shows that refinement of the PDF of small supported monocrystalline nanoparticles can yield accurate mean particle sizes and distributions.« less

Development and characterization of a cell line from Pacific herring, Clupea harengus pallasi, sensitive to both naphthalene cytotoxicity and infection by viral hemorrhagic septicemia virus.

PubMed

Ganassin, R C; Sanders, S M; Kennedy, C J; Joyce, E M; Bols, N C

1999-01-01

A cell line, PHL, has been successfully established from newly hatched herring larvae. The cells are maintained in growth medium consisting of Leibovitz's L-15 supplemented with 15% fetal bovine serum (FBS), and have been cryopreserved and maintain viability after thawing. These cells retain a diploid karotype after 65 population doublings. PHL are susceptible to infection by the North American strain of viral hemorrhagic septicemia (VHS) virus, and are sensitive to the cytotoxic effects of naphthalene, a common environmental contaminant. Naphthalene is a component of crude and refined oil, and may be found in the marine environment following acute events such as oil spills. In addition, chronic sources of naphthalene contamination include offshore drilling and petroleum contamination from areas such as docks and marinas that have creosote-treated docks and pilings and also receive constant small inputs of petroleum products. This cell line should be useful for investigations of the toxicity of naphthalene and other petroleum components to juvenile herring. In addition, studies of the VHS virus will be facilitated by the availability of a susceptible cell line from an alternative species.

Pollution prevention and control procedure case study: an application for petroleum refineries.

PubMed

Rodríguez, Encarnación; Martínez, Jose-Luis

2005-06-01

There is global environmental concern about the pollution from industries and other organizations that should not only be controlled but also prevented. Many alternatives are available to those in charge of environmental protection, but they should be able to draw on a systematic procedure to help implement prevention and control measures. At present, there are three immediate tasks: defining the objective of any environmental study, identifying the potential pollution sources, and selecting alternatives to these sources. However, it is necessary to evaluate these alternatives by using as large a number of criteria as possible and making them cumulative so as to enable the classification and selection of the best available techniques for each pollution source. The petroleum refining industry plays an important role in the developed economies and also has a potential for pollution generation that must be controlled. The best solution for all (i.e., petroleum companies, the public, and the environment) is pollution prevention, because this option will protect all of them and will also reduce costs in terms of lower raw materials consumption as well as reducing potential fines. The procedure we have presented in this article has been applied successfully.

Explaining EIA Crude Oil and Petroleum Product Price Data and Comparing with Other U.S. Government Data Sources, 2001 to 2010

EIA Publications

2012-01-01

This article describes the sampling frames and basic data collection methods for petroleum price data reported by Energy Information Administration (EIA) and other Government agencies. In addition, it compares and contrasts annual average prices reported by EIA with comparable prices from the Bureau of Labor Statistics (BLS) CPI (Consumer Price Indexes) for the retail prices of residential No. 2 distillate, on-highway diesel fuel and motor gasoline (all grades.) Further, it compares refiner wholesale/resale prices for No. 2 fuel oil, No. 2 diesel fuel, motor gasoline (all grades,) kerosene-type jet fuel and residual fuel oil reported by EIA with comparable prices from the BLS PPI (Producer Price Index.) A discussion of the various crude oil prices and spot/futures prices published by EIA and other Government agencies is also included in the article.

Laser measurement of the spectral extinction coefficients of fluorescent, highly absorbing liquids. [crude petroleum oils

NASA Technical Reports Server (NTRS)

Hoge, F. E.

1982-01-01

A conceptual method is developed to deduce rapidly the spectral extinction coefficient of fluorescent, highly absorbing liquids, such as crude or refined petroleum oils. The technique offers the advantage of only requiring one laser wavelength and a single experimental assembly and execution for any specific fluorescent liquid. The liquid is inserted into an extremely thin wedge-shaped cavity for stimulation by a laser from one side and flurescence measurement on the other side by a monochromator system. For each arbitrarily selected extinction wavelength, the wedge is driven slowly to increasing thicknesses until the fluorescence extinguishes. The fluorescence as a function of wedge thickness permits a determination of the extinction coefficient using an included theoretical model. When the monochromator is set to the laser emission wavelength, the extinction coefficient is determined using the usual on-wavelength signal extinction procedure.

Refining and end use study of coal liquids II - linear programming analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lowe, C.; Tam, S.

1995-12-31

A DOE-funded study is underway to determine the optimum refinery processing schemes for producing transportation fuels that will meet CAAA regulations from direct and indirect coal liquids. The study consists of three major parts: pilot plant testing of critical upgrading processes, linear programming analysis of different processing schemes, and engine emission testing of final products. Currently, fractions of a direct coal liquid produced form bituminous coal are being tested in sequence of pilot plant upgrading processes. This work is discussed in a separate paper. The linear programming model, which is the subject of this paper, has been completed for themore » petroleum refinery and is being modified to handle coal liquids based on the pilot plant test results. Preliminary coal liquid evaluation studies indicate that, if a refinery expansion scenario is adopted, then the marginal value of the coal liquid (over the base petroleum crude) is $3-4/bbl.« less

The Asphaltenes

NASA Astrophysics Data System (ADS)

Mullins, Oliver C.

2011-07-01

Asphaltenes, the most aromatic of the heaviest components of crude oil, are critical to all aspects of petroleum utilization, including reservoir characterization, production, transportation, refining, upgrading, paving, and coating materials. The asphaltenes, which are solid, have or impart crucial and often deleterious attributes in fluids such as high viscosity, emulsion stability, low distillate yields, and inopportune phase separation. Nevertheless, fundamental uncertainties had precluded a first-principles approach to asphaltenes until now. Recently, asphaltene science has undergone a renaissance; many basic molecular and nanocolloidal properties have been resolved and codified in the modified Yen model (also known as the Yen-Mullins model), thereby enabling predictive asphaltene science. Advances in analytical chemistry, especially mass spectrometry, enable the identification of tens of thousands of distinct chemical species in crude oils and asphaltenes. These and other powerful advances in asphaltene science fall under the banner of petroleomics, which incorporates predictive petroleum science and provides a framework for future developments.

Toxicology of oil field wastes. Hazards to livestock associated with the petroleum industry.

PubMed

Edwards, W C

1989-07-01

In oil-producing states, the proximity of livestock to drilling operations and production sites often results in poisoning of animals from ingestion of crude oil, condensate, salt water, heavy metals, and caustic chemicals. The heavy metals encountered most frequently are lead from pipe joint compound and arsenicals and chromates used as corrosion inhibitors. Numerous toxic and caustic chemicals are used in drilling muds and fluids. Crude oil and salt water spills are common occurrences around production sites. Pipeline breaks may result in exposure of livestock to crude oil or refined petroleum hydrocarbons. Ingestion of petroleum hydrocarbons may result in sudden death from peracute bloat. The most common cause of illness or death following exposure to petroleum hydrocarbons is aspiration pneumonia, which may cause a chronic progressive deterioration of health, with death after several days or weeks. Cases in which livestock are exposed to oil, salt water, or caustic chemicals, but do not die acutely or from aspiration pneumonia are more frustrating to diagnose. In these cases, parasitism, poor nutrition, and other debilitating diseases must be considered. Anorexia, weight loss, and decreased rumen motility may be caused by a disruption of normal rumen function. Petroleum hydrocarbons, salt water, and caustic chemicals have the potential of altering rumen flora and enzymatic processes as well as damaging the ruminal and gastrointestinal epithelium. The toxicity of petroleum hydrocarbons appears to be related more closely to the volatility and viscosity of the product than to other factors. The more volatile straight chain and aromatic petroleum hydrocarbons have a greater potential for aspiration pneumonia and may produce an anesthetic-like action if absorbed systemically. The more volatile petroleum hydrocarbons also are more irritating to skin and mucous membranes and appear to be more damaging to rumen flora. Treatment of petroleum hydrocarbon ingestion is aimed at preventing aspiration pneumonia and the animal's absorption of highly volatile components. Activated charcoal slurries and, in some instances, vegetable oil may be used to absorb the ingested petroleum or alter its viscosity to minimize absorption and aspiration. These procedures should be followed by the administration of rumenatories or saline cathartics to hasten the evacuation of the gastrointestinal tract. Chronic poor performance animals with anorexia and rumen dysfunction may respond to fresh rumen inoculant, intravenous glucose, and B-complex vitamins. Prognosis primarily hinges on whether or not aspiration pneumonia has occurred. Treatment of aspiration pneumonia rarely is effe

Could petroleum biodegradation be a joint achievement of aerobic and anaerobic microrganisms in deep sea reservoirs?

PubMed Central

2011-01-01

Several studies suggest that petroleum biodegradation can be achieved by either aerobic or anaerobic microorganisms, depending on oxygen input or other electron acceptors and appropriate nutrients. Evidence from in vitro experiments with samples of petroleum formation water and oils from Pampo Field indicate that petroleum biodegradation is more likely to be a joint achievement of both aerobic and anaerobic bacterial consortium, refining our previous observations of aerobic degradation. The aerobic consortium depleted, in decreasing order, hydrocarbons > hopanes > steranes > tricyclic terpanes while the anaerobic consortium depleted hydrocarbons > steranes > hopanes > tricyclic terpanes. The oxygen content of the mixed consortia was measured from time to time revealing alternating periods of microaerobicity (O2 ~0.8 mg.L-1) and of aerobicity (O2~6.0 mg.L-1). In this experiment, the petroleum biodegradation changed from time to time, alternating periods of biodegradation similar to the aerobic process and periods of biodegradation similar to the anaerobic process. The consortia showed preferences for metabolizing hydrocarbons > hopanes > steranes > tricyclic terpanes during a 90-day period, after which this trend changed and steranes were more biodegraded than hopanes. The analysis of aerobic oil degrading microbiota by the 16S rRNA gene clone library detected the presence of Bacillus, Brevibacterium, Mesorhizobium and Achromobacter, and the analysis of the anaerobic oil degrading microbiota using the same technique detected the presence of Bacillus and Acinetobacter (facultative strains). In the mixed consortia Stenotrophomonas, Brevibacterium, Bacillus, Rhizobium, Achromobacter and 5% uncultured bacteria were detected. This is certainly a new contribution to the study of reservoir biodegradation processes, combining two of the more important accepted hypotheses. PMID:22196374

Sensors and devices containing ultra-small nanowire arrays

DOEpatents

Xiao, Zhili

2014-09-23

A network of nanowires may be used for a sensor. The nanowires are metallic, each nanowire has a thickness of at most 20 nm, and each nanowire has a width of at most 20 nm. The sensor may include nanowires comprising Pd, and the sensor may sense a change in hydrogen concentration from 0 to 100%. A device may include the hydrogen sensor, such as a vehicle, a fuel cell, a hydrogen storage tank, a facility for manufacturing steel, or a facility for refining petroleum products.

Sensors and devices containing ultra-small nanowire arrays

DOEpatents

Xiao, Zhili

2017-04-11

A network of nanowires may be used for a sensor. The nanowires are metallic, each nanowire has a thickness of at most 20 nm, and each nanowire has a width of at most 20 nm. The sensor may include nanowires comprising Pd, and the sensor may sense a change in hydrogen concentration from 0 to 100%. A device may include the hydrogen sensor, such as a vehicle, a fuel cell, a hydrogen storage tank, a facility for manufacturing steel, or a facility for refining petroleum products.

Quantification of the luminescence intensity of natural materials

NASA Technical Reports Server (NTRS)

Watson, R. D.; Hessin, T. D.; Hemphill, W. R.

1973-01-01

Review of some of the results of an evaluation of the use of an airborne Fraunhofer line discriminator (FLD) for the detection of sun-stimulated luminescence emitted by rhodamine WT dye and some other materials. Rhodamine dye is reported to have been detected by airborne FDL in sea water in concentrations of less than 2 ppb. Experiments with a fluorescence spectrometer in the laboratory indicate that luminescence of some samples of crude and refined petroleum exceeds the luminescence intensity of rhodamine dye in concentrations of 10 ppm.

The potential for industrial cogeneration development by 1990

NASA Astrophysics Data System (ADS)

1981-07-01

The cogeneration study focused on five industries that constitute three quarters of industrial steam demand: pulp and paper, chemicals, petroleum refining, steel, and food processing. These industries use almost one fifth of the total energy consumed in the United States. The analysis reflected the investment and regulatory concerns in the United States. The analysis reflected the investment used by industrial and utility managers. Phone discussions were held with approximately 70 companies to verify and augment the process and energy use data for the five industries.

Systems and methods for integrating ion mobility and ion trap mass spectrometers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ibrahim, Yehia M.; Garimella, Sandilya; Prost, Spencer A.

Described herein are examples of systems and methods for integrating IMS and MS systems. In certain examples, systems and methods for decoding double multiplexed data are described. The systems and methods can also perform multiple refining procedures in order to minimize the demultiplexing artifacts. The systems and methods can be used, for example, for the analysis of proteomic and petroleum samples, where the integration of IMS and high mass resolution are used for accurate assignment of molecular formulae.

[Evaluation of treatment technology of odor pollution source in petrochemical industry].

PubMed

Mu, Gui-Qin; Sui, Li-Hua; Guo, Ya-Feng; Ma, Chuan-Jun; Yang, Wen-Yu; Gao, Yang

2013-12-01

Using an environmental technology assessment system, we put forward the evaluation index system for treatment technology of the typical odor pollution sources in the petroleum refining process, which has been applied in the assessment of the industrial technology. And then the best available techniques are selected for emissions of gas refinery sewage treatment plant, headspace gas of acidic water jars, headspace gas of cold coke jugs/intermediate oil tank/dirty oil tank, exhaust of oxidative sweetening, and vapors of loading and unloading oil.

Effect of support on catalytic cracking of bio-oil over Ni/silica-alumina

NASA Astrophysics Data System (ADS)

Sunarno, Herman, Syamsu; Rochmadi, Mulyono, Panut; Budiman, Arief

2017-03-01

Depletion of petroleum and environmental problem have led to look for an alternative fuel sources In many ways, biomass is a potential renewable source. Among the many forms of biomass, oil palm empty fruit bunch (EFB) is a very attractive feedstock due to its abudance, low price and non-competitiveness with the food chain. EFB can be converted bio-oil by pyrolysis process. but this product can not be used directly as a transportation fuel, so it needs upgrading bio-oil through a catalytic cracking process. The catalyst plays an important role in the catalytic cracking process. The objective of this research is to study the effect of Ni concentrations (1,3,5 and 7 wt.%) on the characteristics of the catalyst Ni / Silica-Alumina and the performance test for the catalytic cracking of bio-oil. Preparation of the catalyst Ni / Silica-Alumina was done by impregnation at 80°C for 3 hours, then done to calcination and reduction at 500°C for 2 hours. The performance test was conducted on catalytic cracking temperature of 500°C. Results show that increasing concentration of Ni from 1 to 7 %, the pore diameter of the catalyst decreased from 35.71 to 32.70 A and surface area decreased from 209.78 to 188.53 m2/gram. With the increase of Ni concentration, the yield of oil reduced from 22.5 to 11.25 %, while the heating value of oil increased from 34.4 to 36.41MJ/kg.

The mammalian toxicological hazards of petroleum-derived substances: an overview of the petroleum industry response to the high production volume challenge program.

PubMed

McKee, Richard H; White, Russell

2014-01-01

Petroleum-derived substances are complex and composed of aliphatic (normal-, iso-, and cycloparaffins), olefinic, and/or aromatic constituents. Approximately 400 of these complex substances were evaluated as part of the US Environmental Protection Agency voluntary High Production Volume (HPV) Challenge program. The substances were separated into 13 groups (categories), and all available data were assessed. Toxicology testing was conducted as necessary to fully address the end points encompassed by the HPV initiative. In a broad sense, volatile hydrocarbons may cause acute central nervous system effects, and those that are liquids at room temperature pose aspiration hazards if taken into the lungs as liquids and may also cause skin irritation. Higher boiling substances may contain polycyclic aromatic constituents (PACs) that can be mutagenic and carcinogenic and may also cause developmental effects. Substances containing PACs can also cause target organ and developmental effects. The effects of aliphatic constituents include liver enlargement and/or renal effects in male rats via an α-2u-globulin-mediated process and, in some cases, small but statistically significant reductions in hematological parameters. Crude oils may contain other constituents, particularly sulfur- and nitrogen-containing compounds, which are removed during refining. Aside from these more generic considerations, some specific petroleum substances may contain unusually toxic constituents including benzene, 1,3-butadiene, and/or n-hexane, which should also be taken into account if present at toxicologically relevant levels.

A compositional multiphase model for groundwater contamination by petroleum products: 1. Theoretical considerations

USGS Publications Warehouse

Corapcioglu, M. Yavuz; Baehr, Arthur L.

1987-01-01

A mathematical model is developed to describe the fate of hydrocarbon constituents of petroleum products introduced to soils as an immiscible liquid from sources such as leaking underground storage tanks and ruptured pipelines. The problem is one of multiphase transport (oil (immiscible), air, and water phases) of a reactive contaminant with constituents such as benzene, toluene, and xylene found in refined petroleum products like gasoline. In the unsaturated zone, transport of each constituent can occur as a solute in the water phase, vapor in the air phase, and as an unaltered constituent in the oil phase. Additionally, the model allows for adsorption. Molecular transformations, microbially mediated or abiotic, are incorporated as sink terms in the conservation of mass equations. An equilibrium approximation, applicable to any immiscible organic contaminant is applied to partition constituent mass between the air, oil, water, and adsorbed phases for points in the region where the oil phase exists. Outside the oil plume the equilibrium approximation takes on a simpler form to partition constituent mass between the air, water, and adsorbed phases only. Microbial degradation of petroleum products is first discussed in a general model, then the conservation of mass equation for oxygen is incorporated into the analysis which takes advantage of the key role played by oxygen in the metabolism of hydrocarbon utilizing microbes in soil environments. Approximations to two subproblems, oil plume establishment in the unsaturated zone, and solute and vapor transport subsequent to immiscible plume establishment are then developed from the general model.

Novel Catalysts and Processing Technologies for Production of Aerospace Fuels from Non-Petroleum Raw Materials

NASA Technical Reports Server (NTRS)

Hepp, Aloysius F.; Kulis, Michael J.; Psarras, Peter C.; Ball, David W.; Timko, Michael T.; Wong, Hsi-Wu; Peck, Jay; Chianelli, Russell R.

2014-01-01

Transportation fuels production (including aerospace propellants) from non-traditional sources (gases, waste materials, and biomass) has been an active area of research and development for decades. Reducing terrestrial waste streams simultaneous with energy conversion, plentiful biomass, new low-cost methane sources, and/or extra-terrestrial resource harvesting and utilization present significant technological and business opportunities being realized by a new generation of visionary entrepreneurs. We examine several new approaches to catalyst fabrication and new processing technologies to enable utilization of these nontraditional raw materials. Two basic processing architectures are considered: a single-stage pyrolysis approach that seeks to basically re-cycle hydrocarbons with minimal net chemistry or a two-step paradigm that involves production of supply or synthesis gas (mainly carbon oxides and H2) followed by production of fuel(s) via Sabatier or methanation reactions and/or Fischer-Tröpsch synthesis. Optimizing the fraction of product stream relevant to targeted aerospace (and other transportation) fuels via modeling, catalyst fabrication and novel reactor design are described. Energy utilization is a concern for production of fuels for either terrestrial or space operations; renewable sources based on solar energy and/or energy efficient processes may be mission enabling. Another important issue is minimizing impurities in the product stream(s), especially those potentially posing risks to personnel or operations through (catalyst) poisoning or (equipment) damage. Technologies being developed to remove (and/or recycle) heteroatom impurities are briefly discussed as well as the development of chemically robust catalysts whose activities are not diminished during operation. The potential impacts on future missions by such new approaches as well as balance of system issues are addressed.

Novel Catalysts and Processing Technologies for Production of Aerospace Fuels from Non-Petroleum Raw Materials

NASA Technical Reports Server (NTRS)

Hepp, A. F.; Kulis, M. J.; Psarras, P. C.; Ball, D. W.; Timko, M. T.; Wong, H.-W.; Peck, J.; Chianelli, R. R.

2014-01-01

Transportation fuels production (including aerospace propellants) from non-traditional sources (gases, waste materials, and biomass) has been an active area of research and development for decades. Reducing terrestrial waste streams simultaneous with energy conversion, plentiful biomass, new low-cost methane sources, and/or extra-terrestrial resource harvesting and utilization present significant technological and business opportunities being realized by a new generation of visionary entrepreneurs. We examine several new approaches to catalyst fabrication and new processing technologies to enable utilization of these non-traditional raw materials. Two basic processing architectures are considered: a single-stage pyrolysis approach that seeks to basically re-cycle hydrocarbons with minimal net chemistry or a two-step paradigm that involves production of supply or synthesis gas (mainly carbon oxides and hydrogen) followed by production of fuel(s) via Sabatier or methanation reactions and/or Fischer-Tropsch synthesis. Optimizing the fraction of product stream relevant to targeted aerospace (and other transportation) fuels via modeling, catalyst fabrication and novel reactor design are described. Energy utilization is a concern for production of fuels for either terrestrial or space operations; renewable sources based on solar energy and/or energy efficient processes may be mission enabling. Another important issue is minimizing impurities in the product stream(s), especially those potentially posing risks to personnel or operations through (catalyst) poisoning or (equipment) damage. Technologies being developed to remove (and/or recycle) heteroatom impurities are briefly discussed as well as the development of chemically robust catalysts whose activity are not diminished during operation. The potential impacts on future missions by such new approaches as well as balance of system issues are addressed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Setyopratomo, P., E-mail: puguh-sptm@yahoo.com; Wulan, Praswasti P. D. K., E-mail: wulanmakmur@gmail.com; Sudibandriyo, M., E-mail: msudib@che.ui.ac.id

Carbon nanotubes were produced by chemical vapor deposition method to meet the specifications for hydrogen storage. So far, the various catalyst had been studied outlining their activities, performances, and efficiencies. In this work, tri-metallic catalyst consist of Fe-Co-Mo supported on MgO was used. The catalyst was prepared by wet-impregnation method. Liquefied Petroleum Gas (LPG) was used as carbon source. The synthesis was conducted in atmospheric fixed bed reactor at reaction temperature range 750 – 850 °C for 30 minutes. The impregnation method applied in this study successfully deposed metal component on the MgO support surface. It found that the depositedmore » metal components might partially replace Mg(OH){sub 2} or MgO molecules in their crystal lattice. Compare to the original MgO powder; it was significant increases in pore volume and surface area has occurred during catalyst preparation stages. The size of obtained carbon nanotubes is ranging from about 10.83 nm OD/4.09 nm ID up to 21.84 nm OD/6.51 nm ID, which means that multiwall carbon nanotubes were formed during the synthesis. Yield as much as 2.35 g.CNT/g.catalyst was obtained during 30 minutes synthesis and correspond to carbon nanotubes growth rate of 0.2 μm/min. The BET surface area of the obtained carbon nanotubes is 181.13 m{sup 2}/g and around 50 % of which is contributed by mesopores. Micropore with half pore width less than 1 nm contribute about 10% volume of total micro and mesopores volume of the carbon nanotubes. The existence of these micropores is very important to increase the hydrogen storage capacity of the carbon nanotubes.« less

Fischer-Tropsch Catalyst for Aviation Fuel Production

NASA Technical Reports Server (NTRS)

DeLaRee, Ana B.; Best, Lauren M.; Bradford, Robyn L.; Gonzalez-Arroyo, Richard; Hepp, Aloysius F.

2012-01-01

As the oil supply declines, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to nonpetroleum sources as a feedstock for aviation (and other transportation) fuels. The Fischer-Tropsch process uses a gas mixture of carbon monoxide and hydrogen which is converted into various liquid hydrocarbons; this versatile gas-to-liquid technology produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fischer-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur and aromatic compounds. It is most commonly catalyzed by cobalt supported on alumina, silica, or titania or unsupported alloyed iron powders. Cobalt is typically used more often than iron, in that cobalt is a longer-active catalyst, has lower water-gas shift activity, and lower yield of modified products. Promoters are valuable in improving Fischer-Tropsch catalyst as they can increase cobalt oxide dispersion, enhance the reduction of cobalt oxide to the active metal phase, stabilize a high metal surface area, and improve mechanical properties. Our goal is to build up the specificity of the Fischer-Tropsch catalyst while adding less-costly transition metals as promoters; the more common promoters used in Fischer-Tropsch synthesis are rhenium, platinum, and ruthenium. In this report we will describe our preliminary efforts to design and produce catalyst materials to achieve our goal of preferentially producing C8 to C18 paraffin compounds in the NASA Glenn Research Center Gas-To-Liquid processing plant. Efforts at NASA Glenn Research Center for producing green fuels using non-petroleum feedstocks support both the Sub-sonic Fixed Wing program of Fundamental Aeronautics and the In Situ Resource Utilization program of the Exploration Technology Development and Demonstration program.

Recycling oil: a question of quality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jacobs, M.

If all used U.S. petroleum products could be recycled, a saving of 70,000 barrels a day could be realized on U.S. imported oil. After the sludge, water, and other contaminants are removed from used oil, a satisfactory basestock product remains. The Energy Policy and Conservation Act of 1975 directed the National Bureau of Standards to develop test procedures that can be used to establish the substantial equivalency of recycled oil with virgin oil for each potential end use. The tasks being performed by NBS on recycled oil are discussed. The researchers are also looking at the polynuclear aromatic hydrocarbons foundmore » in used and re-refined lubricating oils. It is estimated that by 1985 some 125 companies will refine nearly 20 million barrels of oil yearly with a value of $1 billion. (MCW)« less

U. S. refining margins languishing: Ominous undercurrent

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-12-17

In recent weeks, most petroleum product prices have plunged on both the US Gulf and West Coasts. Even though most crude oil prices have weakened as well, the refining sector ends 1991 on a powerless note. The problem: from 1992 forward, continued cast infusions will scarcely afford sufficient processing and capacity changes in preparation for dramatic Clean Air Act requirements, while reluctant demand will scarcely accommodate cost increase pass throughs. This issue updates prices and margins for several important crudes processed in the US and tracks recent product price trends. The issue also presents the following: (1) the ED Refiningmore » Netback Data Series for the US Gulf and West Coasts, Rotterdam, and Singapore as of Dec. 6, 1991; and (2) the ED Fuel Price/Tax Series for countries of the Western Hemisphere, December 1991 edition.« less

Biodiesel Production using Heterogeneous Catalyst in CSTR: Sensitivity Analysis and Optimization

NASA Astrophysics Data System (ADS)

Keong, L. S.; Patle, D. S.; Shukor, S. R.; Ahmad, Z.

2016-03-01

Biodiesel as a renewable fuel has emerged as a potential replacement for petroleum-based diesels. Heterogeneous catalyst has become the focus of researches in biodiesel production with the intention to overcome problems associated with homogeneous catalyzed processes. The simulation of heterogeneous catalyzed biodiesel production has not been thoroughly studied. Hence, a simulation of carbon-based solid acid catalyzed biodiesel production from waste oil with high FFA content (50 weight%) was developed in the present work to study the feasibility and potential of the simulated process. The simulated process produces biodiesel through simultaneous transesterification and esterification with the consideration of reaction kinetics. The developed simulation is feasible and capable to produce 2.81kmol/hr of FAME meeting the international standard (EN 14214). Yields of 68.61% and 97.19% are achieved for transesterification and esterification respectively. Sensitivity analyses of FFA composition in waste oil, methanol to oil ratio, reactor pressure and temperature towards FAME yield from both reactions were carried out. Optimization of reactor temperature was done to maximize FAME products.

Chelating agent-free, vapor-assisted crystallization method to synthesize hierarchical microporous/mesoporous MIL-125 (Ti).

PubMed

McNamara, Nicholas D; Hicks, Jason C

2015-03-11

Titanium-based microporous heterogeneous catalysts are widely studied but are often limited by the accessibility of reactants to active sites. Metal-organic frameworks (MOFs), such as MIL-125 (Ti), exhibit enhanced surface areas due to their high intrinsic microporosity, but the pore diameters of most microporous MOFs are often too small to allow for the diffusion of larger reactants (>7 Å) relevant to petroleum and biomass upgrading. In this work, hierarchical microporous MIL-125 exhibiting significantly enhanced interparticle mesoporosity was synthesized using a chelating-free, vapor-assisted crystallization method. The resulting hierarchical MOF was examined as an active catalyst for the oxidation of dibenzothiophene (DBT) with tert-butyl hydroperoxide and outperformed the solely microporous analogue. This was attributed to greater access of the substrate to surface active sites, as the pores in the microporous analogues were of inadequate size to accommodate DBT. Moreover, thiophene adsorption studies suggested the mesoporous MOF contained larger amounts of unsaturated metal sites that could enhance the observed catalytic activity.

Highly Selective Upgrading of Biomass-Derived Alcohol Mixtures for Jet/Diesel-Fuel Components.

PubMed

Liu, Qiang; Xu, Guoqiang; Wang, Xicheng; Liu, Xiaoran; Mu, Xindong

2016-12-20

In light of the increasing concern about the energy and environmental problems caused by the combustion of petroleum-based fuels (e.g., jet and diesel fuels), the development of new procedures for their sustainable production from renewable biomass-derived platform compounds has attracted tremendous attention recently. Long-chain ketones/alcohols are promising fuel components owing to the fuel properties that closely resemble those of traditional fuels. The focus of this report is the production of long-chain ketones/alcohols by direct upgrading of biomass-derived short-chain alcohol mixtures (e.g., isopropanol-butanol-ethanol mixtures) in pure water. An efficient Pd catalyst system was developed for these highly selective transformations. Long-chain ketones/alcohols (C 8 -C 19 ), which can be used as precursors for renewable jet/diesel fuel, were obtained in good-to-high selectivity (>90 %) by using the developed Pd catalyst. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil

DOEpatents

Knauss, Kevin G.; Copenhaver, Sally C.; Aines, Roger D.

2000-01-01

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Catalytic transformations of biomass substrates using mixed metal oxides derived from substituted hydrotalcites

NASA Astrophysics Data System (ADS)

Macala, Gerald Stephen, II

Fueled by seemingly endless reserves of cheap and easily accessible fossil energy, the industrial age has brought to the developed world tremendous advances in human health and well being. Unfortunately the burning of fossil fuels has also been implicated in increasing atmospheric CO2 concentrations and global climate change. Concerns about short-term and long-term supply further build a case for the need for alternative energy sources. Biomass derived materials are a tantalizing source of fuels and fine chemicals. Unlike petroleum derived hydrocarbons, biomass can be both renewable and carbon neutral. Crops can be regenerated annually or even more often in tropical climates, and since the captured carbon originates as atmospheric CO2, the overall cycle has the potential to be nearly carbon neutral regardless of the final fate of the carbon. In contrast to petroleum derived hydrocarbons, which can often be made more valuable by adding functionality, biomass derived materials are already highly functionalized and can usually be made more valuable by selective removal of functionality. The development of robust catalysts capable of selective defuntionalization of biomass derived substrates remains an important challenge with potentially enormous economic and societal impact. In addition to being robust and selective, catalysts should preferably be heterogeneous to allow for easier removal and regeneration after the reaction is complete. New materials consisting of Mg-Al hydrotalcite-like structures, with a limiting percentage of Mg or Al substituted with other M2+ or M3+ cations, were synthesized by a co-precipitation process in basic aqueous solution with carbonate as counterion. Calcination of these materials at 460 °C resulted in evolution of CO2 and water and yielded high surface area mixed metal oxides with enhanced reactivity. Materials were characterized by ICP for elemental analysis, XRD for structural information, XPS for surface elemental analysis and TEM for morphology. Substituting some of the Al for ferric ion resulted in enhanced basicity and enhanced reactivity towards transesterification of seed oil and the model compound triacetin. Substituting some of the Mg for cupric ion resulted in a transfer hydrogenation catalyst capable of single pot dehydrogenation of methanol and hydrogenation of the model compound dihydrobenzofuran.

Mechanical and solubility properties of bio-nanocomposite film of semi refined kappa carrageenan/ZnO nanoparticles

NASA Astrophysics Data System (ADS)

Saputri, Apriliana Eka; Praseptiangga, Danar; Rochima, Emma; Panatarani, Camellia; Joni, I. Made

2018-02-01

The aim of this present work is to develop semi refined kappa carrageenan based bio-nanocomposite film as an alternative to synthetic petroleum based food packaging materials. Among natural polymers, carrageenan is one of the most promising material, since it is a renewable bioresource. The ZnO nanoparticles (0.5%; 1.0%; 1.5% w/w carrageenan) was incorporated into carrageenan polymer to prepare bio-nanocomposite films, where ZnO acts as reinforcement for carrageenan matrix. The mechanical and solubility properties of the prepared films were investigated as a function of ZnO concentration. The results indicated that the addition of ZnO exhibits greater solubility compared to the neat film. The elongation at break is insignificantly different on the films with and without addition ZnO. The tensile strength of the film was highest for the sample with 0.5% ZnO. These mechanical and solubility properties suggest that bio-nanocomposite film of semi refined kappa carrageenan and nanoparticle ZnO can be effectively used as food packaging material.

Electro-catalytic biodiesel production from canola oil in methanolic and ethanolic solutions with low cost stainless steel and hybrid ion-exchange resin grafted electrodes

NASA Astrophysics Data System (ADS)

Allioux, Francois-Marie; Holland, Brendan J.; Kong, Lingxue; Dumée, Ludovic F.

2017-07-01

Biodiesel is a growing alternative to petroleum fuels and is produced by the catalysed transesterification of fats in presence of an alcohol base. Transesterification processes using homogeneous catalysts are considered to be amongst the most efficient methods but rely on the feedstock quality and low water content in order to avoid undesirable saponification reactions. In this work, the electro-catalytic conversion of canola oil to biodiesel in a 1% aqueous methanolic and ethanolic reaction mixture was performed without the addition of external catalyst or co-solvent. An inexpensive stainless steel electrode and a hybrid stainless steel electrode coated with an ion-exchange resin catalyst were used as cathode materials while the anode was composed of a plain carbon paper. The cell voltages were varied from 10 to 40 V and the reaction temperature maintained at 20 or 40°C. The canola oil conversion rates were found to be superior at 40°C without saponification reactions for cell voltages below 30 V. The conversion rates were as high as 87% for the hybrid electrode and 81% for the plain stainless steel electrode. This work could inspire new process development for the conversion of high water content feedstock for the production of second-generation biodiesel.

Influence of the Crystal Structure of Titanium Oxide on the Catalytic Activity of Rh/TiO2 in Steam Reforming of Propane at Low Temperature.

PubMed

Yu, Lin; Sato, Katsutoshi; Toriyama, Takaaki; Yamamoto, Tomokazu; Matsumura, Syo; Nagaoka, Katsutoshi

2018-06-21

Solid oxide fuel cells (SOFCs) with liquefied petroleum gas (LPG) reduce CO 2 emissions due to their high-energy-conversion efficiency. Although SOFCs can convert LPG directly, coking occurs easily by decomposition of hydrocarbons, including C-C bonds on the electrode of fuel cell stacks. It is therefore necessary to develop an active steam pre-reforming catalyst that eliminates the hydrocarbons at low temperature, in which waste heat of SOFCs is used. Herein, we show that the crystal structure of the TiO 2 that anchors Rh particles is crucial for catalytic activity of Rh/TiO 2 catalysts for propane pre-reforming. Our experimental results revealed that strong metal support interaction (SMSI) induced during H 2 pre-reduction were optimized over Rh/TiO 2 with a rutile structure; this catalyst catalyzed the reaction much more effectively than conventional Rh/γ-Al 2 O 3 . In contrast, the SMSI was too strong for Rh/TiO 2 with an anatase structure, and the surface of the Rh particles was therefore covered mostly with partially reduced TiO 2 . The result was very low activity. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Recovery of Ni Metal from Spent Catalyst with Emulsion Liquid Membrane Using Cyanex 272 as Extractant

NASA Astrophysics Data System (ADS)

Yuliusman; Huda, M.; Ramadhan, I. T.; Farry, A. R.; Wulandari, P. T.; Alfia, R.

2018-03-01

In this study was conducted to recover nickel metal from spent nickel catalyst resulting from hydrotreating process in petroleum industry. The nickel extraction study with the emulsion liquid membrane using Cyanex 272 as an extractant to extract and separate nickel from the feed phase solution. Feed phase solution was preapred from spent catalyst using sulphuric acid. Liquid membrane consists of a kerosene as diluent, a Span 80 as surfactant, a Cyanex 272 as carrier and sulphuric acid solutions have been used as the stripping solution. The important parameters governing the permeation of nickel and their effect on the separation process have been studied. These parameters are surfactant concentration, extractant concentration feed phase pH. The optimum conditions of the emulsion membrane making process is using 0.06 M Cyanex 272, 8% w/v SPAN 80, 0.05 M H2SO4, internal phase extractant / phase volume ratio: 1/1, and stirring speed 1150 rpm for 60 Minute that can produce emulsion membrane with stability level above 90% after 4 hours. In the extraction process with optimum condition pH 6 for feed phase, ratio of phase emulsion/phase of feed: 1/2, and stirring speed 175 rpm for 15 minutes with result 81.51% nickel was extracted.

Desulfurization of benzonaphthothiophenes and dibenzothiophene with a Raney nickel catalyst and its relationship to the. pi. -electron density

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nagai, M.; Urimoto, H.; Uetake, K.

The hydrodesulfurization of heavy petroleum feedstocks and coal-derived liquids requires the conversion of high molecular weight compounds like dibenzothiophene and benzonaphthothiophenes. There are several studies in the literature which deal with the mechanism of the hydrodesulfurization of multi-ring thiophenic compounds on cobalt or nickel molybdenum catalysts at high pressure. However, there are only a few studies which relate the chemical reactivity of these compounds to their electronic structure. The reactivity of a multi-ring sulfur-containing compound is not determined solely by the size of the molecule. In addition, others studied the relationship between the first step in the hydrotreating reaction ofmore » benzonaphthothiophene and the Coulombic interaction term of the compounds using the CNDO/S method. Because there is competition between the different processes (hydrogenation and desulfurization) during reaction, it is difficult to understand the relationship between desulfurization and the electronic properties of the compounds under reaction conditions. The calculation of electronic structures necessarily involves many sigma bonds of hydrogenated aromatic rings as well as many electrons of high molecular weight compounds. For this reason, it is best to select a catalyst and reaction conditions under which desulfurization takes place without hydrogenation.« less

The effect of Fe-Rh alloying on CO hydrogenation to C 2+ oxygenates

DOE PAGES

Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; ...

2015-05-20

A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO 2 catalysts for the synthesis of ethanol and other C 2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of Fe–Rh alloys for catalyst with 1–7 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburizationmore » as evidenced by the formation of small amounts of Fe 3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeO x also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of Fe–Rh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

At the opening of the Symposium, Dr. Sharrah, Senior Vice President of Continental Oil Company, addressed the attendees, and his remarks are included in this volume. The Symposium was concluded by workshops which addressed specific topics. The topical titles are as follows: alcohol uses; production; environment and safety; and socio-economic. The workshops reflected a growing confidence among the attendees that the alcohols from coal, remote natural gas and biomass do offer alternatives to petroleum fuels. Further, they may, in the long run, prove to be equal or superior to the petroleum fuels when the aspects of performance, environment, health andmore » safety are combined with the renewable aspect of the biomass derived alcohols. Although considerable activity in the production and use of alcohols is now appearing in many parts of the world, the absence of strong, broad scale assessment and support for these fuels by the United States Federal Government was a noted point of concern by the attendees. The environmental consequence of using alcohols continues to be more benign in general than the petroleum based fuels. The exception is the family of aldehydes. Although the aldehydes are easily suppressed by catalysts, it is important to understand their production in the combustion process. Progress is being made in this regard. Of course, the goal is to burn the alcohols so cleanly that catalytic equipment can be eliminated. Separate abstracts are prepared for the Energy Data Base for individual presentations.« less

Applications of density functional theory calculations to selected problems in hydrocarbon processing

NASA Astrophysics Data System (ADS)

Nabar, Rahul

Recent advances in theoretical techniques and computational hardware have made it possible to apply Density Functional Theory (DFT) methods to realistic problems in heterogeneous catalysis. Hydrocarbon processing is economically, and strategically, a very important industrial sector in today's world. In this thesis, we employ DFT methods to examine several important problems in hydrocarbon processing. Fischer Tropsch Synthesis (FTS) is a mature technology to convert synthesis gas derived from coal, natural-gas or biomass into liquid fuels, specifically diesel. Iron is an active FTS catalyst, but the absence of detailed reaction mechanisms make it difficult to maximize activity and optimize product distribution. We evaluate thermochemistry, kinetics and Rate Determining Steps (RDS) for Fischer Tropsch Synthesis on several models of Fe catalysts: Fe(110), Fe(211) and Pt promoted Fe(110). Our studies indicated that CO-dissociation is likely to be the RDS under most reaction conditions, but the DFT-calculated activation energy ( Ea) for direct CO dissociation was too large to explain the observed catalyst activity. Consequently we demonstrate that H-assisted CO-dissociation pathways are competitive with direct CO dissociation on both Co and Fe catalysts and could be responsible for a major fraction of the reaction flux (especially at high CO coverages). We then extend this alternative mechanistic model to closed-packed facets of nine transition metal catalysts (Fe, Co, Ni, Ru, Rh, Pd, Os, Ir and Pt). H-assisted CO dissociation offers a kinetically easier route on each of the metals studied. DFT methods are also applied to another problem from the petroleum industry: discovery of poison-resistant, bimetallic, alloy catalysts (poisons: C, S, CI, P). Our systematic screening studies identify several Near Surface Alloys (NSAs) that are expected to be highly poison-resistant yet stable and avoiding adsorbate induced reconstruction. Adsorption trends are also correlated with electronic structure. Eventually we extend this work to compile a database of Binding Energies for 17 adsorbates of catalytic interest on a set of 17 transition metals and their NSAs. Practical examples of how such a database, in conjunction with screening criteria, can be fruitfully utilized for rational catalyst design, are also provided.

Microbial denitrogenation of fossil fuels.

PubMed

Benedik, M J; Gibbs, P R; Riddle, R R; Willson, R C

1998-09-01

The microbial degradation of nitrogen compounds from fossil fuels is important because of the contribution these contaminants make to the formation of nitrogen oxides (NOx) and hence to air pollution and acid rain. They also contribute to catalyst poisoning during the refining of crude oil, thus reducing process yields. We review the current status of microbial degradation of aromatic nitrogen compounds and discuss the potential of microbial processes to alleviate these problems.

Modelling and validation of particle size distributions of supported nanoparticles using the pair distribution function technique

DOE PAGES

Gamez-Mendoza, Liliana; Terban, Maxwell W.; Billinge, Simon J. L.; ...

2017-04-13

The particle size of supported catalysts is a key characteristic for determining structure–property relationships. It is a challenge to obtain this information accurately and in situ using crystallographic methods owing to the small size of such particles (<5 nm) and the fact that they are supported. In this work, the pair distribution function (PDF) technique was used to obtain the particle size distribution of supported Pt catalysts as they grow under typical synthesis conditions. The PDF of Pt nanoparticles grown on zeolite X was isolated and refined using two models: a monodisperse spherical model (single particle size) and a lognormalmore » size distribution. The results were compared and validated using scanning transmission electron microscopy (STEM) results. Both models describe the same trends in average particle size with temperature, but the results of the number-weighted lognormal size distributions can also accurately describe the mean size and the width of the size distributions obtained from STEM. Since the PDF yields crystallite sizes, these results suggest that the grown Pt nanoparticles are monocrystalline. As a result, this work shows that refinement of the PDF of small supported monocrystalline nanoparticles can yield accurate mean particle sizes and distributions.« less

Modelling and validation of particle size distributions of supported nanoparticles using the pair distribution function technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gamez-Mendoza, Liliana; Terban, Maxwell W.; Billinge, Simon J. L.

The particle size of supported catalysts is a key characteristic for determining structure–property relationships. It is a challenge to obtain this information accurately and in situ using crystallographic methods owing to the small size of such particles (<5 nm) and the fact that they are supported. In this work, the pair distribution function (PDF) technique was used to obtain the particle size distribution of supported Pt catalysts as they grow under typical synthesis conditions. The PDF of Pt nanoparticles grown on zeolite X was isolated and refined using two models: a monodisperse spherical model (single particle size) and a lognormalmore » size distribution. The results were compared and validated using scanning transmission electron microscopy (STEM) results. Both models describe the same trends in average particle size with temperature, but the results of the number-weighted lognormal size distributions can also accurately describe the mean size and the width of the size distributions obtained from STEM. Since the PDF yields crystallite sizes, these results suggest that the grown Pt nanoparticles are monocrystalline. As a result, this work shows that refinement of the PDF of small supported monocrystalline nanoparticles can yield accurate mean particle sizes and distributions.« less

Refining cocoon to prepare (N, S, and Fe) ternary-doped porous carbon aerogel as efficient catalyst for the oxygen reduction reaction in alkaline medium

NASA Astrophysics Data System (ADS)

Li, Changqing; Sun, Fengzhan; Lin, Yuqing

2018-04-01

Various advanced sulfur doped Fe-N-C non-noble metal catalysts of oxygen reduction reaction (ORR) have been recently designed and reported with excellent catalytic activity. Herein, we refined cocoon with several steps to form silk fibroin solution, treated with iron salt to prepare an easy available, heteroatom (N, S, and Fe) ternary-doped, porous carbon aerogel (HDCA). Heteroatom existed in organic compounds in silk fibroin endow active site for ORR of the resultant carbon frameworks. Moreover, the amino acids presented in silk fibroin acted as ligands, functioning with Fe ions to form FeNx coordination compounds, which also served as active sites towards ORR. The synthesized HDCA electrocatalysts, especially HDCA-800 (obtained at 800 °C) displayed excellent catalytic activity with onsets, half-wave potential of 0.94 V, 0.79 V and higher limited current density of 3.80 mA cm-2 through a near four-electron reduction pathway with an average electron transferred number of 3.86, making them promising alternatives for state-of-the-art ORR electrocatalysts in fuel cell field. The porous structure with synergistic effect of N and S heteroatom doping has been proposed to play a key role in facilitating the desired ORR reaction.

Effect of Co-Production of Renewable Biomaterials on the Performance of Asphalt Binder in Macro and Micro Perspectives.

PubMed

Qu, Xin; Liu, Quan; Wang, Chao; Wang, Dawei; Oeser, Markus

2018-02-06

Conventional asphalt binder derived from the petroleum refining process is widely used in pavement engineering. However, asphalt binder is a non-renewable material. Therefore, the use of a co-production of renewable bio-oil as a modifier for petroleum asphalt has recently been getting more attention in the pavement field due to its renewability and its optimization for conventional petroleum-based asphalt binder. Significant research efforts have been done that mainly focus on the mechanical properties of bio-asphalt binder. However, there is still a lack of studies describing the effects of the co-production on performance of asphalt binders from a micro-scale perspective to better understand the fundamental modification mechanism. In this study, a reasonable molecular structure for the co-production of renewable bio-oils is created based on previous research findings and the observed functional groups from Fourier-transform infrared spectroscopy tests, which are fundamental and critical for establishing the molecular model of bio-asphalt binder with various biomaterials contents. Molecular simulation shows that the increase of biomaterial content causes the decrease of cohesion energy density, which can be related to the observed decrease of dynamic modulus. Additionally, a parameter of Flexibility Index is employed to characterize the ability of asphalt binder to resist deformation under oscillatory loading accurately.

Catalytic conversion of lactic acid and its derivatives

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kokitkar, P.B.; Langford, R.; Miller, D.J.

1993-12-31

The catalytic upgrading of lactic acid and methyl lactate is being investigated. With the commercialization of inexpensive starch fermentation technologies, US production of lactic acid is undergoing a surge. Dropping cost and increased availability offer a major opportunity to develop lactic acid as a renewable feedstock for chemicals production. IT can be catalytically converted into several important chemical intermediates currently derived from petroleum including acrylic acid, propanoic acid, and 2,3-pentanedione. The process can expand the potential of biomass as a substitute feedstock for petroleum and can benefit both the US chemical process industry and US agriculture via increased production ofmore » high-value, non-food products from crops and crop byproducts. Reaction studies of lactic acid and its ester are conducted in fixed bed reactors at 250-380{degrees}C and 0.1-0.5 MPa (1-5 atm) using salt catalysts on low surface area supports. Highest selectivities achieved are 42% to acrylic acid and 55% to 2,3-pentanedione from lactic acid over NaNO{sub 3} catalyst on low surface area silica support. High surface area (microporous) or highly acidic supports promote fragmentation to acetaldehyde and thus reduce yields of desirable products. The support acidity gives rice to lactic acid from neat methyl lactate feed but the lactic acid yield goes down after the nitrate salt is impregnated on the support. Both lactic acid and methyl lactate form 2,3-pentanedione. Methyl lactate reactions are more complex since it forms all the products obtained from lactic acid as well as many corresponding esters of the acids obtained from lactic acid (mainly methyl acrylate, methyl propionate, methyl acetate). At high temperatures, methyl acetate and acetic acid yields become significant from methyl lactate whereas lactic acid gives significant amount of acetol at high temperatures.« less