2002-01-01
W. Ding, Phys. Rev. B 67, 04541 3 (2003) . [13] M. Dresselhaus, G . Dresselhaus, and P. Avouris, eds., Carbon Nanotubes : Synthesis , Structure...Polaritonics System 2 . Carbon Nanotube Yarns and Sheets for Enhanced Thermal Conductivit y Phonon Transistor with Charge Injection Gate I UT D Our...Main Systems and Materials : 1 . New Mechanism of Phonon - Polariton Thermal Conductivity 2 . Carbon Nanotubes with Enhanced K(T) CNT in CNT Yarns and
Phonon engineering for nanostructures.
Aubry, Sylvie; Friedmann, Thomas Aquinas; Sullivan, John Patrick; Peebles, Diane Elaine; Hurley, David H.; Shinde, Subhash L.; Piekos, Edward Stanley; Emerson, John Allen
2010-01-01
Understanding the physics of phonon transport at small length scales is increasingly important for basic research in nanoelectronics, optoelectronics, nanomechanics, and thermoelectrics. We conducted several studies to develop an understanding of phonon behavior in very small structures. This report describes the modeling, experimental, and fabrication activities used to explore phonon transport across and along material interfaces and through nanopatterned structures. Toward the understanding of phonon transport across interfaces, we computed the Kapitza conductance for {Sigma}29(001) and {Sigma}3(111) interfaces in silicon, fabricated the interfaces in single-crystal silicon substrates, and used picosecond laser pulses to image the thermal waves crossing the interfaces. Toward the understanding of phonon transport along interfaces, we designed and fabricated a unique differential test structure that can measure the proportion of specular to diffuse thermal phonon scattering from silicon surfaces. Phonon-scale simulation of the test ligaments, as well as continuum scale modeling of the complete experiment, confirmed its sensitivity to surface scattering. To further our understanding of phonon transport through nanostructures, we fabricated microscale-patterned structures in diamond thin films.
Phonon Engineering in Metals from First Principles
NASA Astrophysics Data System (ADS)
Lanzillo, Nicholas; Thomas, J.; Watson, E. B.; Washington, M.; Nayak, Saroj K.
2013-03-01
The electron-phonon interaction in metallic systems controls the electronic transport properties, including both electrical and thermal resistivity. The effect of compressive strain on the electron-phonon interaction in metals is investigated using first-principles density functional theory, and we propose various ways to ``engineer'' this interaction for various technological applications. In particular, we show that by applying compressive strain on the FCC crystals of Al, Cu, Ag and Au, the net electron-phonon scattering rate decreases and likewise the electrical resistivity decreases with increasing pressure. This trend is corroborated by experimental measurements of the resistance of a 0.5 mm diameter high-purity Al wire pressurized up to 2 GPa in a solid-media pressure apparatus at room temperature. The rate of the decrease in electrical resistivity as a function of pressure as determined by experiment is matched by the rate predicted by theory. Our simulations show that Al nanowires have the same response to strain as the bulk crystal; the net electron-phonon scattering can be reduced through compressive strain. Modifying the electron-phonon interaction in metallic structures shows great promise for future nano-electronic devices.
Engineering dissipation with phononic spectral hole burning.
Behunin, R O; Kharel, P; Renninger, W H; Rakich, P T
2017-03-01
Optomechanics, nano-electromechanics, and integrated photonics have brought about a renaissance in phononic device physics and technology. Central to this advance are devices and materials supporting ultra-long-lived photonic and phononic excitations that enable novel regimes of classical and quantum dynamics based on tailorable photon-phonon coupling. Silica-based devices have been at the forefront of such innovations for their ability to support optical excitations persisting for nearly 1 billion cycles, and for their low optical nonlinearity. While acoustic phonon modes can persist for a similar number of cycles in crystalline solids at cryogenic temperatures, it has not been possible to achieve such performance in silica, as silica becomes acoustically opaque at low temperatures. We demonstrate that these intrinsic forms of phonon dissipation are greatly reduced (by >90%) by nonlinear saturation using continuous drive fields of disparate frequencies. The result is a form of steady-state phononic spectral hole burning that produces a wideband transparency window with optically generated phonon fields of modest (nW) powers. We developed a simple model that explains both dissipative and dispersive changes produced by phononic saturation. Our studies, conducted in a microscale device, represent an important step towards engineerable phonon dynamics on demand and the use of glasses as low-loss phononic media.
Engineering dissipation with phononic spectral hole burning
NASA Astrophysics Data System (ADS)
Behunin, R. O.; Kharel, P.; Renninger, W. H.; Rakich, P. T.
2017-03-01
Optomechanics, nano-electromechanics, and integrated photonics have brought about a renaissance in phononic device physics and technology. Central to this advance are devices and materials supporting ultra-long-lived photonic and phononic excitations that enable novel regimes of classical and quantum dynamics based on tailorable photon-phonon coupling. Silica-based devices have been at the forefront of such innovations for their ability to support optical excitations persisting for nearly 1 billion cycles, and for their low optical nonlinearity. While acoustic phonon modes can persist for a similar number of cycles in crystalline solids at cryogenic temperatures, it has not been possible to achieve such performance in silica, as silica becomes acoustically opaque at low temperatures. We demonstrate that these intrinsic forms of phonon dissipation are greatly reduced (by >90%) by nonlinear saturation using continuous drive fields of disparate frequencies. The result is a form of steady-state phononic spectral hole burning that produces a wideband transparency window with optically generated phonon fields of modest (nW) powers. We developed a simple model that explains both dissipative and dispersive changes produced by phononic saturation. Our studies, conducted in a microscale device, represent an important step towards engineerable phonon dynamics on demand and the use of glasses as low-loss phononic media.
Engineering dissipation with phononic spectral hole burning
NASA Astrophysics Data System (ADS)
Behunin, R. O.; Kharel, P.; Renninger, W. H.; Rakich, P. T.
2016-12-01
Optomechanics, nano-electromechanics, and integrated photonics have brought about a renaissance in phononic device physics and technology. Central to this advance are devices and materials supporting ultra-long-lived photonic and phononic excitations that enable novel regimes of classical and quantum dynamics based on tailorable photon-phonon coupling. Silica-based devices have been at the forefront of such innovations for their ability to support optical excitations persisting for nearly 1 billion cycles, and for their low optical nonlinearity. While acoustic phonon modes can persist for a similar number of cycles in crystalline solids at cryogenic temperatures, it has not been possible to achieve such performance in silica, as silica becomes acoustically opaque at low temperatures. We demonstrate that these intrinsic forms of phonon dissipation are greatly reduced (by >90%) by nonlinear saturation using continuous drive fields of disparate frequencies. The result is a form of steady-state phononic spectral hole burning that produces a wideband transparency window with optically generated phonon fields of modest (nW) powers. We developed a simple model that explains both dissipative and dispersive changes produced by phononic saturation. Our studies, conducted in a microscale device, represent an important step towards engineerable phonon dynamics on demand and the use of glasses as low-loss phononic media.
2005-09-01
Zeolite Encapsulated Nanotubes ………………………………… 76 2.2. Synthesis of Conjugated Polymer-CNT Complexes ……………………………. 84 3. CHARACTERIZATION AND OPTIMIZATION OF... Nanotubes : Synthesis , Structure, Properties and Applications (Springer, Berlin, 2000). [14] D. Cahill, W. Ford, K. Goodson, G. Mahan, A. Majumdar, H. Maris...of vibrational dynamics of “bulk” flat and closed carbon and boron - nitride (BN) nanostructures allows immediate transition to the boundary condition
Phonon bandgap engineering of strained monolayer MoS₂.
Jiang, Jin-Wu
2014-07-21
The phonon band structure of monolayer MoS₂ is characteristic of a large energy gap between acoustic and optical branches, which protects the vibration of acoustic modes from being scattered by optical phonon modes. Therefore, the phonon bandgap engineering is of practical significance for the manipulation of phonon-related mechanical or thermal properties in monolayer MoS₂. We perform both phonon analysis and molecular dynamics simulations to investigate the tension effect on the phonon bandgap and the compression induced instability of the monolayer MoS₂. Our key finding is that the phonon bandgap can be narrowed by the uniaxial tension, and is completely closed at ε = 0.145; while the biaxial tension only has a limited effect on the phonon bandgap. We also demonstrate the compression induced buckling for the monolayer MoS₂. The critical strain for buckling is extracted from the band structure analysis of the flexure mode in the monolayer MoS₂ and is further verified by molecular dynamics simulations and the Euler buckling theory. Our study illustrates the uniaxial tension as an efficient method for manipulating the phonon bandgap of the monolayer MoS₂, while the biaxial compression as a powerful tool to intrigue buckling in the monolayer MoS₂.
Research Update: Phonon engineering of nanocrystalline silicon thermoelectrics
NASA Astrophysics Data System (ADS)
Shiomi, Junichiro
2016-10-01
Nanocrystalline silicon thermoelectrics can be a solution to improve the cost-effectiveness of thermoelectric technology from both material and integration viewpoints. While their figure-of-merit is still developing, recent advances in theoretical/numerical calculations, property measurements, and structural synthesis/fabrication have opened up possibilities to develop the materials based on fundamental physics of phonon transport. Here, this is demonstrated by reviewing a series of works on nanocrystalline silicon materials using calculations of multiscale phonon transport, measurements of interfacial heat conduction, and synthesis from nanoparticles. Integration of these approaches allows us to engineer phonon transport to improve the thermoelectric performance by introducing local silicon-oxide structures.
Electron-phonon interaction and scattering in Si and Ge: Implications for phonon engineering
Tandon, Nandan; Albrecht, J. D.; Ram-Mohan, L. R.
2015-07-28
We report ab-initio results for electron-phonon (e-ph) coupling and display the existence of a large variation in the coupling parameter as a function of electron and phonon dispersion. This variation is observed for all phonon modes in Si and Ge, and we show this for representative cases where the initial electron states are at the band gap edges. Using these e-ph matrix elements, which include all possible phonon modes and electron bands within a relevant energy range, we evaluate the imaginary part of the electron self-energy in order to obtain the associated scattering rates. The temperature dependence is seen through calculations of the scattering rates at 0 K and 300 K. The results provide a basis for understanding the impacts of phonon scattering vs. orientation and geometry in the design of devices, and in analysis of transport phenomena. This provides an additional tool for engineering the transfer of energy from carriers to the lattice.
Engineering surface waves in flat phononic plates
NASA Astrophysics Data System (ADS)
Estrada, Héctor; Candelas, Pilar; Belmar, Francisco; Uris, Antonio; García de Abajo, F. Javier; Meseguer, Francisco
2012-05-01
Surface acoustic-wave phenomena span a wide range of length scales going from the devastation of earthquakes down to image reconstruction of buried nanostructures. In solid-fluid systems, the so-called Scholte-Stoneley waves (SSWs) dominate the scene at the interface with their evanescent fields decaying away into both media. Understanding and manipulating these waves in patterned surfaces would enable new applications of sound to be devised for imaging and acoustic signal processing, although this task has so far remained elusive. Here, we report SSW modes displaying directional gaps and band folding in fluid-loaded solid phononic plates. The plates are inhomogeneously patterned with in-plane periodic modulations of the elastic constants, but present flat surfaces free of corrugations. We experimentally demonstrate control of SSWs, which opens a promising route toward acoustic fluid sensing, microscopy, and signal processing.
Structural engineering of three-dimensional phononic crystals
NASA Astrophysics Data System (ADS)
Delpero, Tommaso; Schoenwald, Stefan; Zemp, Armin; Bergamini, Andrea
2016-02-01
Artificially-structured materials are attracting the research interest of a growing community of scientists for the possibility to develop novel materials with advantageous properties that arise from the ability to tailor the propagation of elastic waves, and thus energy, through them. In this work, we propose a three-dimensional phononic crystal whose unit cell has been engineered to obtain a strong wave-attenuation band in the middle of the acoustic frequency range. The combination of its acoustic properties with the dimensions of the unit cell and its static mechanical properties makes it an interesting material for possibly several applications in civil and mechanical engineering, for instance as the core of an acoustically insulating sandwich panel. A sample of this crystal has been manufactured and experimentally tested with respect to its acoustic transmissibility. The performance of the phononic crystal core is remarkable both in terms of amplitude reduction in the transmissibility and width of the attenuation band. A parametric study has been finally conducted on selected geometrical parameters of the unit cell and on their effect on the macroscopic properties of the crystal. This work represents an application-oriented example of how the macroscopic properties of an artificially-structured material can be designed, according to specific needs, by a conventional engineering of its unit cell.
Grain-boundary layering transitions and phonon engineering
NASA Astrophysics Data System (ADS)
Rickman, J. M.; Harmer, M. P.; Chan, H. M.
2016-09-01
We employ semi-grand canonical Monte Carlo simulation to investigate layering transitions at grain boundaries in a prototypical binary alloy. We demonstrate the existence of such transitions among various interfacial states and examine the role of elastic fields in dictating state equilibria. The results of these studies are summarized in the form of diagrams that highlight interfacial state coexistence in this system. Finally, we examine the impact of layering transitions on the phononic properties of the system, as given by the specific heat and, by extension, the thermal conductivity. Thus, it is suggested that by inducing interfacial layering transitions via changes in temperature or pressure, one can thereby engineer thermodynamic and transport properties in materials.
Engineering the hypersonic phononic band gap of hybrid Bragg stacks.
Schneider, Dirk; Liaqat, Faroha; El Boudouti, El Houssaine; El Hassouani, Youssef; Djafari-Rouhani, Bahram; Tremel, Wolfgang; Butt, Hans-Jürgen; Fytas, George
2012-06-13
We report on the full control of phononic band diagrams for periodic stacks of alternating layers of poly(methyl methacrylate) and porous silica combining Brillouin light scattering spectroscopy and theoretical calculations. These structures exhibit large and robust on-axis band gaps determined by the longitudinal sound velocities, densities, and spacing ratio. A facile tuning of the gap width is realized at oblique incidence utilizing the vector nature of the elastic wave propagation. Off-axis propagation involves sagittal waves in the individual layers, allowing access to shear moduli at nanoscale. The full theoretical description discerns the most important features of the hypersonic one-dimensional crystals forward to a detailed understanding, a precondition to engineer dispersion relations in such structures.
Engineering thermal conductance using a two-dimensional phononic crystal
Zen, Nobuyuki; Puurtinen, Tuomas A.; Isotalo, Tero J.; Chaudhuri, Saumyadip; Maasilta, Ilari J.
2014-01-01
Controlling thermal transport has become relevant in recent years. Traditionally, this control has been achieved by tuning the scattering of phonons by including various types of scattering centres in the material (nanoparticles, impurities, etc). Here we take another approach and demonstrate that one can also use coherent band structure effects to control phonon thermal conductance, with the help of periodically nanostructured phononic crystals. We perform the experiments at low temperatures below 1 K, which not only leads to negligible bulk phonon scattering, but also increases the wavelength of the dominant thermal phonons by more than two orders of magnitude compared to room temperature. Thus, phononic crystals with lattice constants ≥1 μm are shown to strongly reduce the thermal conduction. The observed effect is in quantitative agreement with the theoretical calculation presented, which accurately determined the ballistic thermal conductance in a phononic crystal device. PMID:24647049
Engineering interactions between superconducting qubits and phononic nanostructures
NASA Astrophysics Data System (ADS)
Arrangoiz-Arriola, Patricio; Safavi-Naeini, Amir H.
2016-12-01
Nanomechanical systems can support highly coherent microwave-frequency excitations at cryogenic temperatures. However, generating sufficient coupling between these devices and superconducting quantum circuits is challenging due to the vastly different length scales of acoustic and electromagnetic excitations. Here we demonstrate a general method for calculating piezoelectric interactions between quantum circuits and arbitrary phononic nanostructures. We illustrate our technique by studying the coupling between a transmon qubit and bulk acoustic-wave, Lamb-wave, and phononic crystal resonators, and show that very large coupling rates are possible in all three cases. Our results suggest a route to phononic circuits and systems that are nonlinear at the single-phonon level.
Phonon engineering of electronic transport in hybrid nanotubes
NASA Astrophysics Data System (ADS)
Balandin, Alexander A.; Fonoberov, Vladimir A.
2006-03-01
Recently, a number of biological nanoscale objects, including tobacco mosaic viruses (TMV), have been employed as templates for assembly of inorganic nanostructures. This approach can potentially lead to a new method of fabrication of nanoelectronic circuits beyond conventional CMOS. Here we theoretically demonstrate that in addition to their role as nano-templates [1], the elastically soft TMVs can improve electron transport in the nanotubes grown on them [2]. In the simulated hybrid nanostructures, which consist of silicon or silica nanotubes on TMVs, the confined acoustic phonons are found to be redistributed between the nanotube shell and the acoustically soft virus enclosure. As a result, the low-temperature electron mobility in the hybrid TMV-silicon nanotube can increase up to a factor of four compared to that of an empty silicon nanotube [2]. Our estimates also indicate an enhancement of the low-temperature thermal conductivity in the TMV-silicon nanotube, which can lead to improvements in heat removal from the hybrid nanostructure-based circuits. The authors acknowledge the support of MARCO and its Functional Engineered Nano Architectonics (FENA) Focus Center. [1] W.L. Liu, K. Alim, A.A. Balandin et al., Appl. Phys. Lett. 86, 253108 (2005); [2] V.A. Fonoberov and A.A. Balandin, Nano Lett. 5, 1920 (2005).
Engineering thermal conductance using a two-dimensional phononic crystal
NASA Astrophysics Data System (ADS)
Maasilta, Ilari
2014-03-01
Controlling thermal transport has become very relevant in recent years, in light of the strong push to develop novel energy harvesting techniques based on thermoelectricity, the need to improve the heat dissipation out of semiconductor devices, and the push to increase the sensitivity of bolometric radiation detectors. Traditionally, this control has been achieved by tuning the scattering of phonons by including various types of scattering centers in the material (nanoparticles, impurities etc.). Recently we have taken another approach and demonstrated that one can also use coherent bandstructure effects to control phonon thermal conductance, with the help of periodically nanostructured phononic crystals. Working at around 1 Kelvin where the wavelength of the dominant thermal phonons is more than two orders of magnitude longer than at room temperature, we have created phononic crystals with a period of 1 μm that strongly reduce the thermal conduction. In addition, we performed theoretical calculations that accurately determine the ballistic thermal conductance in a phononic crystal device, showing full quantitative agreement with the experiments.
Controlling thermal and electrical properties of graphene by strain-engineering its flexural phonons
NASA Astrophysics Data System (ADS)
Conley, Hiram; Nicholl, Ryan; Bolotin, Kirill
2014-03-01
We explore the effects of flexural phonons on the thermal and electrical properties of graphene. To control the amplitude of flexural phonons, we developed a technique to engineer uniform mechanical strain between 0 and 1% in suspended graphene. We determine the level of strain, thermal conductivity and carrier mobility of graphene through a combination of mechanical resonance and electrical transport measurements. Depending on strain, we find significant changes in the thermal expansion coefficient, thermal conductivity, and carrier mobility of suspended graphene. These changes are consistent with the expected contribution of flexural phonons.
25th Anniversary Article: Ordered Polymer Structures for the Engineering of Photons and Phonons
Lee, Jae-Hwang; Koh, Cheong Yang; Singer, Jonathan P; Jeon, Seog-Jin; Maldovan, Martin; Stein, Ori; Thomas, Edwin L
2014-01-01
The engineering of optical and acoustic material functionalities via construction of ordered local and global architectures on various length scales commensurate with and well below the characteristic length scales of photons and phonons in the material is an indispensable and powerful means to develop novel materials. In the current mature status of photonics, polymers hold a pivotal role in various application areas such as light-emission, sensing, energy, and displays, with exclusive advantages despite their relatively low dielectric constants. Moreover, in the nascent field of phononics, polymers are expected to be a superior material platform due to the ability for readily fabricated complex polymer structures possessing a wide range of mechanical behaviors, complete phononic bandgaps, and resonant architectures. In this review, polymer-centric photonic and phononic crystals and metamaterials are highlighted, and basic concepts, fabrication techniques, selected functional polymers, applications, and emerging ideas are introduced. PMID:24338738
Cooling phonons with phonons: Acoustic reservoir engineering with silicon-vacancy centers in diamond
NASA Astrophysics Data System (ADS)
Kepesidis, K. V.; Lemonde, M.-A.; Norambuena, A.; Maze, J. R.; Rabl, P.
2016-12-01
We study a setup where a single negatively-charged silicon-vacancy center in diamond is magnetically coupled to a low-frequency mechanical bending mode and via strain to the high-frequency phonon continuum of a semiclamped diamond beam. We show that under appropriate microwave driving conditions, this setup can be used to induce a laser-cooling-like effect for the low-frequency mechanical vibrations, where the high-frequency longitudinal compression modes of the beam serve as an intrinsic low-temperature reservoir. We evaluate the experimental conditions under which cooling close to the quantum ground state can be achieved and describe an extended scheme for the preparation of a stationary entangled state between two mechanical modes. By relying on intrinsic properties of the mechanical beam only, this approach offers an interesting alternative for quantum manipulation schemes of mechanical systems, where otherwise efficient optomechanical interactions are not available.
Modulations of thermal properties of graphene by strain-induced phonon engineering
NASA Astrophysics Data System (ADS)
Tada, Kento; Funatani, Takashi; Konabe, Satoru; Sasaoka, Kenji; Ogawa, Matsuto; Souma, Satofumi; Yamamoto, Takahiro
2017-02-01
Modulation of the thermal properties of graphene due to strain-induced phononic band engineering was theoretically investigated by first-principles calculations based on the density functional theory. The high-energy phonon modes are found to exhibit softening owing to the strain, whereas a low-energy acoustic mode (out-of-plane mode) exhibits hardening. Moreover, the dispersion relation of the out-of-plane mode associated with the strain essentially changes from quadratic (∝ k 2) to linear (∝ k). Accordingly, the temperature dependence of the low-temperature specific heat also changes from linear (∝ T) to quadratic (∝ T 2).
Phonon Spectrum Engineering in Rolled-up Micro- and Nano-Architectures
Fomin, Vladimir M.; Balandin, Alexander A.
2015-10-10
We report on a possibility of efficient engineering of the acoustic phonon energy spectrum in multishell tubular structures produced by a novel high-tech method of self-organization of micro- and nano-architectures. The strain-driven roll-up procedure paved the way for novel classes of metamaterials such as single semiconductor radial micro- and nano-crystals and multi-layer spiral micro- and nano-superlattices. The acoustic phonon dispersion is determined by solving the equations of elastodynamics for InAs and GaAs material systems. It is shown that the number of shells is an important control parameter of the phonon dispersion together with the structure dimensions and acoustic impedance mismatchmore » between the superlattice layers. The obtained results suggest that rolled up nano-architectures are promising for thermoelectric applications owing to a possibility of significant reduction of the thermal conductivity without degradation of the electronic transport.« less
Phonon Spectrum Engineering in Rolled-up Micro- and Nano-Architectures
Fomin, Vladimir M.; Balandin, Alexander A.
2015-10-10
We report on a possibility of efficient engineering of the acoustic phonon energy spectrum in multishell tubular structures produced by a novel high-tech method of self-organization of micro- and nano-architectures. The strain-driven roll-up procedure paved the way for novel classes of metamaterials such as single semiconductor radial micro- and nano-crystals and multi-layer spiral micro- and nano-superlattices. The acoustic phonon dispersion is determined by solving the equations of elastodynamics for InAs and GaAs material systems. It is shown that the number of shells is an important control parameter of the phonon dispersion together with the structure dimensions and acoustic impedance mismatch between the superlattice layers. The obtained results suggest that rolled up nano-architectures are promising for thermoelectric applications owing to a possibility of significant reduction of the thermal conductivity without degradation of the electronic transport.
Nanoscale interface engineering in ZnO twin nanorods for proposed phonon tunnel devices.
Singh, Avanendra; Senapati, Kartik; Satpati, Biswarup; Kumar, Mohit; Sahoo, Pratap K
2015-02-14
Zinc oxide twin nanorods, with two identical crystalline sections connected by an amorphous layer, were reproducibly grown using a simple one-step hydrothermal technique. The thickness of the amorphous layer between the crystalline segments was tunable with growth parameters, as confirmed by high resolution transmission electron microscopy. The photoluminescence spectra of these twin nanorods exhibit strong near band edge emission in the UV range, with convoluted phonon sidebands. De-convolution analyses of these spectra showed that the amorphous interlayers act as effective phonon barriers beyond a certain thickness. Such oriented grown individual crystalline-amorphous-crystalline structures may be a suitable test system for fundamental studies of phonon tunneling in the nanostructure. While physical vapor deposition techniques are seriously constrained in realizing crystalline-amorphous-crystalline structures, our results show the viability of engineering embedded interfaces via chemical routes.
Unusual Exciton-Phonon Interactions at van der Waals Engineered Interfaces.
Chow, Colin M; Yu, Hongyi; Jones, Aaron M; Yan, Jiaqiang; Mandrus, David G; Taniguchi, Takashi; Watanabe, Kenji; Yao, Wang; Xu, Xiaodong
2017-02-08
Raman scattering is a ubiquitous phenomenon in light-matter interactions, which reveals a material's electronic, structural, and thermal properties. Controlling this process would enable new ways of studying and manipulating fundamental material properties. Here, we report a novel Raman scattering process at the interface between different van der Waals (vdW) materials as well as between a monolayer semiconductor and 3D crystalline substrates. We find that interfacing a WSe2 monolayer with materials such as SiO2, sapphire, and hexagonal boron nitride (hBN) enables Raman transitions with phonons that are either traditionally inactive or weak. This Raman scattering can be amplified by nearly 2 orders of magnitude when a foreign phonon mode is resonantly coupled to the A exciton in WSe2 directly or via an A1(') optical phonon from WSe2. We further showed that the interfacial Raman scattering is distinct between hBN-encapsulated and hBN-sandwiched WSe2 sample geometries. This cross-platform electron-phonon coupling, as well as the sensitivity of 2D excitons to their phononic environments, will prove important in the understanding and engineering of optoelectronic devices based on vdW heterostructures.
Unusual exciton–phonon interactions at van der Waals engineered interfaces
Chow, Colin M.; Yu, Hongyi; Jones, Aaron M.; ...
2017-01-13
Raman scattering is a ubiquitous phenomenon in light–matter interactions, which reveals a material’s electronic, structural, and thermal properties. Controlling this process would enable new ways of studying and manipulating fundamental material properties. Here, we report a novel Raman scattering process at the interface between different van der Waals (vdW) materials as well as between a monolayer semiconductor and 3D crystalline substrates. We find that interfacing a WSe2 monolayer with materials such as SiO2, sapphire, and hexagonal boron nitride (hBN) enables Raman transitions with phonons that are either traditionally inactive or weak. This Raman scattering can be amplified by nearly 2more » orders of magnitude when a foreign phonon mode is resonantly coupled to the A exciton in WSe2 directly or via an A1' optical phonon from WSe2. We further showed that the interfacial Raman scattering is distinct between hBN-encapsulated and hBN-sandwiched WSe2 sample geometries. Finally, this cross-platform electron–phonon coupling, as well as the sensitivity of 2D excitons to their phononic environments, will prove important in the understanding and engineering of optoelectronic devices based on vdW heterostructures.« less
25th anniversary article: ordered polymer structures for the engineering of photons and phonons.
Lee, Jae-Hwang; Koh, Cheong Yang; Singer, Jonathan P; Jeon, Seog-Jin; Maldovan, Martin; Stein, Ori; Thomas, Edwin L
2014-01-01
The engineering of optical and acoustic material functionalities via construction of ordered local and global architectures on various length scales commensurate with and well below the characteristic length scales of photons and phonons in the material is an indispensable and powerful means to develop novel materials. In the current mature status of photonics, polymers hold a pivotal role in various application areas such as light-emission, sensing, energy, and displays, with exclusive advantages despite their relatively low dielectric constants. Moreover, in the nascent field of phononics, polymers are expected to be a superior material platform due to the ability for readily fabricated complex polymer structures possessing a wide range of mechanical behaviors, complete phononic bandgaps, and resonant architectures. In this review, polymer-centric photonic and phononic crystals and metamaterials are highlighted, and basic concepts, fabrication techniques, selected functional polymers, applications, and emerging ideas are introduced. © 2013 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
El-Kady, Ihab F [Albuquerque, NM; Olsson, Roy H [Albuquerque, NM
2012-01-10
Phononic crystals that have the ability to modify and control the thermal black body phonon distribution and the phonon component of heat transport in a solid. In particular, the thermal conductivity and heat capacity can be modified by altering the phonon density of states in a phononic crystal. The present invention is directed to phononic crystal devices and materials such as radio frequency (RF) tags powered from ambient heat, dielectrics with extremely low thermal conductivity, thermoelectric materials with a higher ratio of electrical-to-thermal conductivity, materials with phononically engineered heat capacity, phononic crystal waveguides that enable accelerated cooling, and a variety of low temperature application devices.
Cattaneo, R; Zucchelli, G; Garlaschi, F M; Finzi, L; Jennings, R C
1995-11-21
Absorption spectra of the isolated D1/D2/cytochrome b-559 complex have been measured in the temperature range 80-300 K. All spectra were analyzed in terms of a linear combination of Gaussian bands and the thermal broadening data interpreted in terms of a model in which the spectrum of each pigment site is broadened by (a) a homogeneous component due to linear electron-phonon coupling to a low-frequency protein vibration and (b) an inhomogeneous component associated with stochastic fluctuations at each pigment site. In order to obtain a numerically adequate description of the absorption spectra, a minimum number of five sub-bands is required. Further refinement of this sub-band description was achieved by taking into account published data from hole burning and absorption difference spectroscopy. In this way, both a six sub-band description and a seven sub-band description were generated. In arriving at the seven sub-band description, the original five sub-band wavelength positions were essentially unchanged. Thermal broadening analysis of the seven sub-band description yielded data which displayed the closest correspondence with the literature observations. The wavelength positions of the sub-bands were near 661, 667, 670, and 675 nm, with two bands near 680 and 684 nm. The two almost isoenergetic sub-bands near 680 nm, identified as P680 and pheophytin, have optical reorganization energies around 40 and 16 cm-1, respectively. All other sub-bands, identified as accessory pigments, have optical reorganization energies close to 16 cm-1.(ABSTRACT TRUNCATED AT 250 WORDS)
Noise Reduction using Frequency Sub-Band Adaptive Spectral Subtraction
NASA Technical Reports Server (NTRS)
Kozel, David
2000-01-01
A frequency sub-band based adaptive spectral subtraction algorithm is developed to remove noise from noise-corrupted speech signals. A single microphone is used to obtain both the noise-corrupted speech and the estimate of the statistics of the noise. The statistics of the noise are estimated during time frames that do not contain speech. These statistics are used to determine if future time frames contain speech. During speech time frames, the algorithm determines which frequency sub-bands contain useful speech information and which frequency sub-bands contain only noise. The frequency sub-bands, which contain only noise, are subtracted off at a larger proportion so the noise does not compete with the speech information. Simulation results are presented.
Hierarchical image coding with diamond-shaped sub-bands
NASA Technical Reports Server (NTRS)
Li, Xiaohui; Wang, Jie; Bauer, Peter; Sauer, Ken
1992-01-01
We present a sub-band image coding/decoding system using a diamond-shaped pyramid frequency decomposition to more closely match visual sensitivities than conventional rectangular bands. Filter banks are composed of simple, low order IIR components. The coder is especially designed to function in a multiple resolution reconstruction setting, in situations such as variable capacity channels or receivers, where images must be reconstructed without the entire pyramid of sub-bands. We use a nonlinear interpolation technique for lost subbands to compensate for loss of aliasing cancellation.
Sub-band/transform compression of video sequences
NASA Technical Reports Server (NTRS)
Sauer, Ken; Bauer, Peter
1992-01-01
The progress on compression of video sequences is discussed. The overall goal of the research was the development of data compression algorithms for high-definition television (HDTV) sequences, but most of our research is general enough to be applicable to much more general problems. We have concentrated on coding algorithms based on both sub-band and transform approaches. Two very fundamental issues arise in designing a sub-band coder. First, the form of the signal decomposition must be chosen to yield band-pass images with characteristics favorable to efficient coding. A second basic consideration, whether coding is to be done in two or three dimensions, is the form of the coders to be applied to each sub-band. Computational simplicity is of essence. We review the first portion of the year, during which we improved and extended some of the previous grant period's results. The pyramid nonrectangular sub-band coder limited to intra-frame application is discussed. Perhaps the most critical component of the sub-band structure is the design of bandsplitting filters. We apply very simple recursive filters, which operate at alternating levels on rectangularly sampled, and quincunx sampled images. We will also cover the techniques we have studied for the coding of the resulting bandpass signals. We discuss adaptive three-dimensional coding which takes advantage of the detection algorithm developed last year. To this point, all the work on this project has been done without the benefit of motion compensation (MC). Motion compensation is included in many proposed codecs, but adds significant computational burden and hardware expense. We have sought to find a lower-cost alternative featuring a simple adaptation to motion in the form of the codec. In sequences of high spatial detail and zooming or panning, it appears that MC will likely be necessary for the proposed quality and bit rates.
Formation of a protected sub-band for conduction in quantum point contacts under extreme biasing.
Lee, J; Han, J E; Xiao, S; Song, J; Reno, J L; Bird, J P
2014-02-01
Managing energy dissipation is critical to the scaling of current microelectronics and to the development of novel devices that use quantum coherence to achieve enhanced functionality. To this end, strategies are needed to tailor the electron-phonon interaction, which is the dominant mechanism for cooling non-equilibrium ('hot') carriers. In experiments aimed at controlling the quantum state, this interaction causes decoherence that fundamentally disrupts device operation. Here, we show a contrasting behaviour, in which strong electron-phonon scattering can instead be used to generate a robust mode for electrical conduction in GaAs quantum point contacts, driven into extreme non-equilibrium by nanosecond voltage pulses. When the amplitude of these pulses is much larger than all other relevant energy scales, strong electron-phonon scattering induces an attraction between electrons in the quantum-point-contact channel, which leads to the spontaneous formation of a narrow current filament and to a renormalization of the electronic states responsible for transport. The lowest of these states coalesce to form a sub-band separated from all others by an energy gap larger than the source voltage. Evidence for this renormalization is provided by a suppression of heating-related signatures in the transient conductance, which becomes pinned near 2e(2)/h (e, electron charge; h, Planck constant) for a broad range of source and gate voltages. This collective non-equilibrium mode is observed over a wide range of temperature (4.2-300 K) and may provide an effective means to manage electron-phonon scattering in nanoscale devices.
Engineering a squeezed phonon reservoir with a bichromatic driving of a quantum dot
NASA Astrophysics Data System (ADS)
Gao, Bo; Li, Gao-xiang; Ficek, Zbigniew
2016-09-01
We demonstrate how an acoustic phonon bath when coupled to a quantum dot with the help of a bichromatic laser field may effectively form a quantum squeezed reservoir. This approach allows one to achieve an arbitrary degree of squeezing of the effective reservoir and it incorporates the properties of the reservoir into two parameters, which can be controlled by varying the ratio of the Rabi frequencies of the bichromatic field. It is found that for unequal Rabi frequencies, the effective reservoir may appear as a quantum squeezed field of ordinary or inverted harmonic oscillators. When the Rabi frequencies are equal the effective reservoir appears as a perfectly squeezed field in which the decay of one of the polarization quadratures of the quantum dot dipole moment is inhibited. The decay of the quantum dot to a stationary state which depends on the initial coherence is predicted. This unusual result is shown to be a consequence of a quantum-nondemolition-type coupling of the quantum dot to the engineered squeezed reservoir. The effect of the initial coherence on the steady-state dressed-state population distribution and the fluorescence spectrum is discussed in detail. The complete polarization of the dressed state population and asymmetric spectra composed of only a single Rabi sideband peak are obtained under strictly resonant excitation.
Engineering single-phonon number states of a mechanical oscillator via photon subtraction
NASA Astrophysics Data System (ADS)
Khan, M. Miskeen; Akram, M. Javed; Paternostro, M.; Saif, F.
2016-12-01
We introduce an optomechanical scheme for the probabilistic preparation of single-phonon Fock states of mechanical modes based on photosubtraction. The quality of the produced mechanical state is confirmed by a number of indicators, including phonon statistics and conditional fidelity. We assess the detrimental effect of parameters such as the temperature of the mechanical system and address the feasibility of the scheme with state-of-the-art technology.
NASA Technical Reports Server (NTRS)
Rippert, Edward D.; Ketterson, John B.; Chen, Jun; Song, Shenian; Lomatch, Susanne; Maglic, Stevan R.; Thomas, Christopher; Cheida, M. A.; Ulmer, Melville P.
1992-01-01
An engineered structure is proposed that can alleviate quasi-particle recombination losses via the existence of a phononic band gap that overlaps the 2-Delta energy of phonons produced during recombination of quasi-particles. Attention is given to a 1D Kronig-Penny model for phonons normally incident to the layers of a multilayered superconducting tunnel junction as an idealized example. A device with a high density of Bragg resonances is identified as desirable; both Nb/Si and NbN/SiN superlattices have been produced, with the latter having generally superior performance.
NASA Astrophysics Data System (ADS)
Rippert, Edward D.; Ketterson, John B.; Chen, Jun; Song, Shenian; Lomatch, Susanne; Maglic, Stevan R.; Thomas, Christopher; Cheida, M. A.; Ulmer, Melville P.
1992-10-01
An engineered structure is proposed that can alleviate quasi-particle recombination losses via the existence of a phononic band gap that overlaps the 2-Delta energy of phonons produced during recombination of quasi-particles. Attention is given to a 1D Kronig-Penny model for phonons normally incident to the layers of a multilayered superconducting tunnel junction as an idealized example. A device with a high density of Bragg resonances is identified as desirable; both Nb/Si and NbN/SiN superlattices have been produced, with the latter having generally superior performance.
NASA Technical Reports Server (NTRS)
Rippert, Edward D.; Ketterson, John B.; Chen, Jun; Song, Shenian; Lomatch, Susanne; Maglic, Stevan R.; Thomas, Christopher; Cheida, M. A.; Ulmer, Melville P.
1992-01-01
An engineered structure is proposed that can alleviate quasi-particle recombination losses via the existence of a phononic band gap that overlaps the 2-Delta energy of phonons produced during recombination of quasi-particles. Attention is given to a 1D Kronig-Penny model for phonons normally incident to the layers of a multilayered superconducting tunnel junction as an idealized example. A device with a high density of Bragg resonances is identified as desirable; both Nb/Si and NbN/SiN superlattices have been produced, with the latter having generally superior performance.
Sensitivity Modulation of Upconverting Thermometry through Engineering Phonon Energy of a Matrix.
Suo, Hao; Guo, Chongfeng; Zheng, Jiming; Zhou, Bo; Ma, Chonggeng; Zhao, Xiaoqi; Li, Ting; Guo, Ping; Goldys, Ewa M
2016-11-09
Investigation of the unclear influential factors to thermal sensing capability is the only way to achieve highly sensitive thermometry, which is greatly needed to meet the growing demand for potential sensing applications. Here, the effect from the phonon energy of a matrix on the sensitivity of upconversion (UC) microthermometers is elaborately discussed using a controllable method. Uniform truncated octahedral YF3:Er(3+)/Yb(3+) microcrystals were prepared by a hydrothermal approach, and phase transformation from YF3 to YOF and Y2O3 with nearly unchanged morphology and size was successfully realized by controlling the annealing temperature. The phonon energies of blank matrixes were determined by FT-IR spectra and Raman scattering. Upon 980 nm excitation, phonon energy-dependent UC emitting color was finely tuned from green to yellow for three samples, and the mechanisms were proposed. Thermal sensing behaviors based on the TCLs ((2)H11/2/(4)S3/2) were evaluated, and the sensitivities gradually grew with the increase in the matrix's phonon energy. According to chemical bond theory and first-principle calculations, the most intrinsic factors associated with thermometric ability were qualitatively demonstrated through analyzing the inner relation between the phonon energy and bond covalency. The exciting results provide guiding insights into employing appropriate host materials with desired thermometric ability while offering the possibility of highly accurate measurement of temperature.
Phonon manipulation with phononic crystals.
Kim Bongsang; Hopkins, Patrick Edward; Leseman, Zayd C.; Goettler, Drew F.; Su, Mehmet F.; El-Kady, Ihab Fathy; Reinke, Charles M.; Olsson, Roy H., III
2012-01-01
In this work, we demonstrated engineered modification of propagation of thermal phonons, i.e. at THz frequencies, using phononic crystals. This work combined theoretical work at Sandia National Laboratories, the University of New Mexico, the University of Colorado Boulder, and Carnegie Mellon University; the MESA fabrication facilities at Sandia; and the microfabrication facilities at UNM to produce world-leading control of phonon propagation in silicon at frequencies up to 3 THz. These efforts culminated in a dramatic reduction in the thermal conductivity of silicon using phononic crystals by a factor of almost 30 as compared with the bulk value, and about 6 as compared with an unpatterned slab of the same thickness. This work represents a revolutionary advance in the engineering of thermoelectric materials for optimal, high-ZT performance. We have demonstrated the significant reduction of the thermal conductivity of silicon using phononic crystal structuring using MEMS-compatible fabrication techniques and in a planar platform that is amenable to integration with typical microelectronic systems. The measured reduction in thermal conductivity as compared to bulk silicon was about a factor of 20 in the cross-plane direction [26], and a factor of 6 in the in-plane direction. Since the electrical conductivity was only reduced by a corresponding factor of about 3 due to the removal of conductive material (i.e., porosity), and the Seebeck coefficient should remain constant as an intrinsic material property, this corresponds to an effective enhancement in ZT by a factor of 2. Given the number of papers in literature devoted to only a small, incremental change in ZT, the ability to boost the ZT of a material by a factor of 2 simply by reducing thermal conductivity is groundbreaking. The results in this work were obtained using silicon, a material that has benefitted from enormous interest in the microelectronics industry and that has a fairly large thermoelectric power
A Multiple-Channel Sub-Band Transient Detection System
David A. Smith
1998-11-01
We have developed a unique multiple-channel sub-band transient detection system to record transient electromagnetic signals in carrier-dominated radio environments; the system has been used to make unique observations of weak, transient HF signals. The detection system has made these observations possible through improved sensitivity compared to conventional broadband transient detection systems; the sensitivity improvement is estimated to be at least 20 dB. The increase in sensitivity has been achieved through subdivision of the band of interest (an 18 MHz tunable bandwidth) into eight sub-band independent detection channels, each with a 400 kHz bandwidth and its own criteria. The system generates a system trigger signal when a predetermined number of channels (typically five) trigger within a predetermined window of time (typically 100 ~s). Events are recorded with a broadband data acquisition system sampling at 50 or 100 Msample/s, so despite the fact that the detection system operates on portions of the signal confined to narrow bands, data acquisition is broadband. Between May and September of 1994, the system was used to detect and record over six thousand transient events in the frequency band from 3 to 30 MHz. Approximately 500 of the events have been characterized as paired bursts of radio noise with individual durations of 2 to 10 ps and separations between the bursts of 5 to 160 ps. The paired transients are typically 5 to 40 dB brighter than the background electromagnetic spectrum between carrier signals. We have termed these events SubIonospheric Pulse Pairs (SIPPS) and presently have no explanation as to their source. Our observations of SIPPS resemble observations of TransIonospheric Pulse Pairs (TIPPs) recorded by the Blackboard instrument on the ALEXIS satellite; the source of TIPP events is also unknown. Most of the recorded SIPP events do not exhibit frequency dispersion, implying propagation along a line-of-sight (groundwave) path; but seven of
The FORTE receiver and sub-band triggering unit
Enemark, D.C.; Shipley, M.E.
1994-08-01
The FORTE payload receiver and trigger unit represent a significant advance over the currently flying BLACKBEARD payload aboard the ALEXIS satellite. Not only is the polarization sensitive antenna array massive compared to the BLACKBEARD monopole, but the event triggering scheme is completely different. Electromagnetic pulses (EWs) are dispersed when they pass through the ionosphere creating a chirped frequency signal which can be helpful in discriminating between natural and man-made signals. Payloads designed to digitize and store the RF signatures of these signals must include sophisticated triggering circuitry to select events of interest and prevent false alarms from wasting the available memory storage resources. The FORTE wideband receiver tunes from 20 to 320 MHz with eight sub-band trigger channels distributed across the 20 MHz IF bandwidth. The conditions which must be satisfied to generate an event trigger are processor controlled. Early testing of the prototype indicates an ability to reliably trigger on chirped RF signals several dB below the noise level. FORTE is scheduled to be launched with a Pegasus XL vehicle in late 1995.
Sandonas, Leonardo Medrano; Gutierrez, Rafael; Pecchia, Alessandro; Seifert, Gotthard; Cuniberti, Gianaurelio
2017-01-04
Novel two-dimensional (2D) materials show unusual physical properties which combined with strain engineering open up the possibility of new potential device applications in nanoelectronics. In particular, transport properties have been found to be very sensitive to applied strain. In the present work, using a density-functional based tight-binding (DFTB) method in combination with Green's function (GF) approaches, we address the effect of strain engineering of the transport setup (contact-device(scattering)-contact regions) on the electron and phonon transport properties of two-dimensional materials, focusing on hexagonal boron-nitride (hBN), phosphorene, and MoS2 monolayers. Considering unstretched contact regions, we show that the electronic bandgap displays an anomalous behavior and the thermal conductance continuously decreases after increasing the strain level in the scattering region. However, when the whole system (contact and device regions) is homogeneously strained, the bandgap for hBN and MoS2 monolayers decreases, while for phosphorene it first increases and then tends to zero with larger strain levels. Additionally, the thermal conductance shows specific strain dependence for each of the studied 2D materials. These effects can be tuned by modifying the strain level in the stretched contact regions.
Streyer, W.; Law, S.; Rosenberg, A.; Wasserman, D.; Roberts, C.; Podolskiy, V. A.; Hoffman, A. J.
2014-03-31
We demonstrate excitation of surface phonon polaritons on patterned gallium phosphide surfaces. Control over the light-polariton coupling frequencies is demonstrated by changing the pattern periodicity and used to experimentally determine the gallium phosphide surface phonon polariton dispersion curve. Selective emission via out-coupling of thermally excited surface phonon polaritons is experimentally demonstrated. Samples are characterized experimentally by Fourier transform infrared reflection and emission spectroscopy, and modeled using finite element techniques and rigorous coupled wave analysis. The use of phonon resonances for control of emissivity and excitation of bound surface waves offers a potential tool for the exploration of long-wavelength Reststrahlen band frequencies.
Accessing high energy sub-bands in bilayer graphene - a transport study
NASA Astrophysics Data System (ADS)
Efetov, Dmitri K.; Maher, Patrick; Glinskis, Simas; Kim, Philip
2011-03-01
In contrast to single layer graphene sheets with its two distinct valence and conduction bands merging at the Dirac Point, multilayer graphene sheets are known to have additional sub-bands at higher energies. Whereas the low energy sub-bands in these systems are well studied, the higher energy sub-bands could so far not be accessed in a transport measurement of graphene samples sitting on typical Si O2 /Si back gates. Employing a poly(ethylene)oxide- CsCl O4 solid polymer electrolyte gate we demonstrate the filling up of the high energy sub-bands in bilayer graphene samples at carrier densities above ~ 2.7 x 1013 cm-2 . The onset of these sub-bands is defined by a slight increase of the resistivity and the onset of Shubnikov de Haas (SdH) oscillations. Measurements of the magneto-resistance, the SdH oscillations and the Hall Effect enable us to deduce the carrier densities and mobilities for both, the high and low energy bands simultaneously. In addition, we find that the onset energy of these sub-bands can be tuned by varying the bilayer interlayer asymmetry.
Giant phonon anomaly associated with superconducting fluctuations in the pseudogap phase of cuprates
Liu, Ye-Hua; Konik, Robert M.; Rice, T. M.; Zhang, Fu-Chun
2016-01-01
The pseudogap in underdoped cuprates leads to significant changes in the electronic structure, and was later found to be accompanied by anomalous fluctuations of superconductivity and certain lattice phonons. Here we propose that the Fermi surface breakup due to the pseudogap, leads to a breakup of the pairing order into two weakly coupled sub-band amplitudes, and a concomitant low energy Leggett mode due to phase fluctuations between them. This increases the temperature range of superconducting fluctuations containing an overdamped Leggett mode. In this range inter-sub-band phonons show strong damping due to resonant scattering into an intermediate state with a pair of overdamped Leggett modes. In the ordered state, the Leggett mode develops a finite energy, changing the anomalous phonon damping into an anomaly in the dispersion. This proposal explains the intrinsic connection between the anomalous pseudogap phase, enhanced superconducting fluctuations and giant anomalies in the phonon spectra. PMID:26785835
Giant phonon anomaly associated with superconducting fluctuations in the pseudogap phase of cuprates
Liu, Ye-Hua; Konik, Robert M.; Rice, T. M.; ...
2016-01-20
The pseudogap in underdoped cuprates leads to significant changes in the electronic structure, and was later found to be accompanied by anomalous fluctuations of superconductivity and certain lattice phonons. Here we propose that the Fermi surface breakup due to the pseudogap, leads to a breakup of the pairing order into two weakly coupled sub-band amplitudes, and a concomitant low energy Leggett mode due to phase fluctuations between them. This increases the temperature range of superconducting fluctuations containing an overdamped Leggett mode. In this range inter-sub-band phonons show strong damping due to resonant scattering into an intermediate state with a pairmore » of overdamped Leggett modes. In the ordered state, the Leggett mode develops a finite energy, changing the anomalous phonon damping into an anomaly in the dispersion. Finally, this proposal explains the intrinsic connection between the anomalous pseudogap phase, enhanced superconducting fluctuations and giant anomalies in the phonon spectra.« less
Giant phonon anomaly associated with superconducting fluctuations in the pseudogap phase of cuprates
Liu, Ye-Hua; Konik, Robert M.; Rice, T. M.; Zhang, Fu-Chun
2016-01-20
The pseudogap in underdoped cuprates leads to significant changes in the electronic structure, and was later found to be accompanied by anomalous fluctuations of superconductivity and certain lattice phonons. Here we propose that the Fermi surface breakup due to the pseudogap, leads to a breakup of the pairing order into two weakly coupled sub-band amplitudes, and a concomitant low energy Leggett mode due to phase fluctuations between them. This increases the temperature range of superconducting fluctuations containing an overdamped Leggett mode. In this range inter-sub-band phonons show strong damping due to resonant scattering into an intermediate state with a pair of overdamped Leggett modes. In the ordered state, the Leggett mode develops a finite energy, changing the anomalous phonon damping into an anomaly in the dispersion. Finally, this proposal explains the intrinsic connection between the anomalous pseudogap phase, enhanced superconducting fluctuations and giant anomalies in the phonon spectra.
Jahidin, A H; Megat Ali, M S A; Taib, M N; Tahir, N Md; Yassin, I M; Lias, S
2014-04-01
This paper elaborates on the novel intelligence assessment method using the brainwave sub-band power ratio features. The study focuses only on the left hemisphere brainwave in its relaxed state. Distinct intelligence quotient groups have been established earlier from the score of the Raven Progressive Matrices. Sub-band power ratios are calculated from energy spectral density of theta, alpha and beta frequency bands. Synthetic data have been generated to increase dataset from 50 to 120. The features are used as input to the artificial neural network. Subsequently, the brain behaviour model has been developed using an artificial neural network that is trained with optimized learning rate, momentum constant and hidden nodes. Findings indicate that the distinct intelligence quotient groups can be classified from the brainwave sub-band power ratios with 100% training and 88.89% testing accuracies. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.
Nonlinear phononics using atomically thin membranes
NASA Astrophysics Data System (ADS)
Midtvedt, Daniel; Isacsson, Andreas; Croy, Alexander
2014-09-01
Phononic crystals and acoustic metamaterials are used to tailor phonon and sound propagation properties by utilizing artificial, periodic structures. Analogous to photonic crystals, phononic band gaps can be created, which influence wave propagation and, more generally, allow engineering of the acoustic properties of a system. Beyond that, nonlinear phenomena in periodic structures have been extensively studied in photonic crystals and atomic Bose-Einstein condensates in optical lattices. However, creating nonlinear phononic crystals or nonlinear acoustic metamaterials remains challenging and only few examples have been demonstrated. Here, we show that atomically thin and periodically pinned membranes support coupled localized modes with nonlinear dynamics. The proposed system provides a platform for investigating nonlinear phononics.
Tian, Ruoming; Kearley, Gordon J.; Yu, Dehong; Ling, Chris D.; Pham, Anh; Embs, Jan P.; Shoko, Elvis; Li, Sean
2016-01-01
Phonons in condensed matter materials transmit energy through atomic lattices as coherent vibrational waves. Like electronic and photonic properties, an improved understanding of phononic properties is essential for the development of functional materials, including thermoelectric materials. Recently, an Einstein rattling mode was found in thermoelectric material Na0.8CoO2, due to the large displacement of Na between the [CoO2] layers. In this work, we have realized a different type of rattler in another thermoelectric material Ca3Co4O9 by chemical doping, which possesses the same [CoO2] layer as Na0.8CoO2. It remarkably suppressed the thermal conductivity while enhancing its electrical conductivity. This new type of rattler was investigated by inelastic neutron scattering experiments in conjunction with ab-initio molecular dynamics simulations. We found that the large mass of dopant rather than the large displacement is responsible for such rattling in present study, which is fundamentally different from skutterudites, clathrates as well as Na analogue. We have also tentatively studied the phonon band structure of this material by DFT lattice dynamics simulation, showing the relative contribution to phonons in the distinct layers of Ca3Co4O9. PMID:27456817
NASA Astrophysics Data System (ADS)
Tian, Ruoming; Kearley, Gordon J.; Yu, Dehong; Ling, Chris D.; Pham, Anh; Embs, Jan P.; Shoko, Elvis; Li, Sean
2016-07-01
Phonons in condensed matter materials transmit energy through atomic lattices as coherent vibrational waves. Like electronic and photonic properties, an improved understanding of phononic properties is essential for the development of functional materials, including thermoelectric materials. Recently, an Einstein rattling mode was found in thermoelectric material Na0.8CoO2, due to the large displacement of Na between the [CoO2] layers. In this work, we have realized a different type of rattler in another thermoelectric material Ca3Co4O9 by chemical doping, which possesses the same [CoO2] layer as Na0.8CoO2. It remarkably suppressed the thermal conductivity while enhancing its electrical conductivity. This new type of rattler was investigated by inelastic neutron scattering experiments in conjunction with ab-initio molecular dynamics simulations. We found that the large mass of dopant rather than the large displacement is responsible for such rattling in present study, which is fundamentally different from skutterudites, clathrates as well as Na analogue. We have also tentatively studied the phonon band structure of this material by DFT lattice dynamics simulation, showing the relative contribution to phonons in the distinct layers of Ca3Co4O9.
NASA Astrophysics Data System (ADS)
Perrin, Bernard
2007-06-01
phonons can help tracking dark matter. These 328 presentations gave rise to 185 articles published in the present proceedings. The traditional topics of this conference series (phonons in superconductors and new materials, lattice dynamics, phonons in glasses and disordered materials, phase transitions, light, neutrons and x-ray inelastic scattering) were still very important in the scientific program but an increasing number of contributions occurred in the fields of coherent phonon generation, phonons in nanoscaled structures and nano/micro thermal phonon transport, expressing the growing involvement of condensed matter physicists in nanosciences. Areas like acoustic solitons and phononic crystals are now well established. Two noteworthy contributions have been brought in the long term quest for an operational SASER : one by Harold De Wijn's group from Utrecht in the classical ruby system and another one by Anthony Kent's group from Nottingham, who used semiconductor nanodevices to realize both an amplifying medium and a cavity. With these semiconductor devices the possibility for engineering, generation and detection of THz acoustic phonons are now imminent. By tradition, a prize is awarded every three years at the International Conference on Phonon Scattering in Condensed Matter to honour a scientist for his outstanding contributions to the field of phonon physics. For this twelfth edition, Humphrey Maris has been honoured for his numerous breakthroughs in the physics of phonons and quantum fluids. According to the words of James Wolfe 'Humphrey Maris has delighted and innovated the members of our phonon community with an entertaining style and challenging wit'. Prizes were also awarded for the best presentations during the poster sessions. The two winners were Peter van Capel from Utrecht, Netherlands, ('Simulations of acoustic soliton-induced chirping of exciton resonances') and Patrick Emery from Lille, France, ('Acoustic attenuation in silica in the 100-250 GHz
Otelaja, O. O.; Robinson, R. D.
2015-10-26
In this work, the mechanism for enhanced phonon backscattering in silicon is investigated. An understanding of phonon propagation through substrates has implications for engineering heat flow at the nanoscale, for understanding sources of decoherence in quantum systems, and for realizing efficient phonon-mediated particle detectors. In these systems, phonons that backscatter from the bottom of substrates, within the crystal or from interfaces, often contribute to the overall detector signal. We utilize a microscale phonon spectrometer, comprising superconducting tunnel junction emitters and detectors, to specifically probe phonon backscattering in silicon substrates (∼500 μm thick). By etching phonon “enhancers” or deep trenches (∼90 μm) around the detectors, we show that the backscattered signal level increases by a factor of ∼2 for two enhancers versus one enhancer. Using a geometric analysis of the phonon pathways, we show that the mechanism of the backscattered phonon enhancement is due to confinement of the ballistic phonon pathways and increased scattering off the enhancer walls. Our result is applicable to the geometric design and patterning of substrates that are employed in phonon-mediated detection devices.
Electronic Band Structure and Sub-band-gap Absorption of Nitrogen Hyperdoped Silicon
Zhu, Zhen; Shao, Hezhu; Dong, Xiao; Li, Ning; Ning, Bo-Yuan; Ning, Xi-Jing; Zhao, Li; Zhuang, Jun
2015-01-01
We investigated the atomic geometry, electronic band structure, and optical absorption of nitrogen hyperdoped silicon based on first-principles calculations. The results show that all the paired nitrogen defects we studied do not introduce intermediate band, while most of single nitrogen defects can introduce intermediate band in the gap. Considering the stability of the single defects and the rapid resolidification following the laser melting process in our sample preparation method, we conclude that the substitutional nitrogen defect, whose fraction was tiny and could be neglected before, should have considerable fraction in the hyperdoped silicon and results in the visible sub-band-gap absorption as observed in the experiment. Furthermore, our calculations show that the substitutional nitrogen defect has good stability, which could be one of the reasons why the sub-band-gap absorptance remains almost unchanged after annealing. PMID:26012369
Contextual filtering method applied to sub-bands of interferometric image decomposition
NASA Astrophysics Data System (ADS)
Belhadj-Aissa, S.; Hocine, F.; Boughacha, M. S.; Belhadj-Aissa, M.
2016-10-01
The precision and accuracy of Digital elevation model and deformation measurement, from SAR interferometry (InSAR/DInSAR) depend mainly on the quality of the interferogram. However, the phase noise, which is mainly due to decorrelation between the images and the speckle, makes the step of phase unwrapping most delicate. In this paper, we propose a filtering method that combines the techniques of decomposition into sub-bands and nonlinear local weights. The Spectral / Contextual filter that we propose, inspired from to Goldstein filter is applied to the sub-bands from the wavelet decomposition. To validate the results, we applied to interferometric products tandem pair ERS1/ERS2 taken in the region of Algiers Algeria.
Analysis of mammogram images based on texture features of curvelet sub-bands
NASA Astrophysics Data System (ADS)
Gardezi, Syed Jamal Safdar; Faye, Ibrahima; Eltoukhy, Mohamed Meselhy
2014-01-01
Image texture analysis plays an important role in object detection and recognition in image processing. The texture analysis can be used for early detection of breast cancer by classifying the mammogram images into normal and abnormal classes. This study investigates breast cancer detection using texture features obtained from the grey level cooccurrence matrices (GLCM) of curvelet sub-band levels combined with texture feature obtained from the image itself. The GLCM were constructed for each sub-band of three curvelet decomposition levels. The obtained feature vector presented to the classifier to differentiate between normal and abnormal tissues. The proposed method is applied over 305 region of interest (ROI) cropped from MIAS dataset. The simple logistic classifier achieved 86.66% classification accuracy rate with sensitivity 76.53% and specificity 91.3%.
Electronic Band Structure and Sub-band-gap Absorption of Nitrogen Hyperdoped Silicon.
Zhu, Zhen; Shao, Hezhu; Dong, Xiao; Li, Ning; Ning, Bo-Yuan; Ning, Xi-Jing; Zhao, Li; Zhuang, Jun
2015-05-27
We investigated the atomic geometry, electronic band structure, and optical absorption of nitrogen hyperdoped silicon based on first-principles calculations. The results show that all the paired nitrogen defects we studied do not introduce intermediate band, while most of single nitrogen defects can introduce intermediate band in the gap. Considering the stability of the single defects and the rapid resolidification following the laser melting process in our sample preparation method, we conclude that the substitutional nitrogen defect, whose fraction was tiny and could be neglected before, should have considerable fraction in the hyperdoped silicon and results in the visible sub-band-gap absorption as observed in the experiment. Furthermore, our calculations show that the substitutional nitrogen defect has good stability, which could be one of the reasons why the sub-band-gap absorptance remains almost unchanged after annealing.
Sub-band processing for grating lobe disambiguation in sparse arrays
NASA Astrophysics Data System (ADS)
Hersey, Ryan K.; Culpepper, Edwin
2014-06-01
Combined synthetic aperture radar (SAR) and ground moving target indication (GMTI) radar modes simultaneously generate SAR and GMTI products from the same radar data. This hybrid mode provides the benefit of combined imaging and moving target displays as well as improved target recognition. However, the differing system, antenna, and waveform requirements between SAR and GMTI modes make implementing the hybrid mode challenging. The Air Force Research Laboratory (AFRL) Gotcha radar has collected wide-bandwidth, multi-channel data that can be used for both SAR and GMTI applications. The spatial channels on the Gotcha array are sparsely separated, which causes spatial grating lobes during the digital beamforming process. Grating lobes have little impact on SAR, which typically uses a single spatial channel. However, grating lobes have a large impact on GMTI, where spatial channels are used to mitigate clutter and estimate the target angle of arrival (AOA). The AOA ambiguity has a significant impact in the Gotcha data, where detections from the sidelobes and skirts of the mainlobe wrap back into the main scene causing a significant number of false alarms. This paper presents a sub-banding method to disambiguate grating lobes in the GMTI processing. This method divides the wideband SAR data into multiple frequency sub-bands. Since each sub-band has a different center frequency, the grating lobes for each sub-band appear at different angles. The method uses this variation to disambiguate target returns and places them at the correct angle of arrival (AOA). Results are presented using AFRL Gotcha radar data.
Toward an Impurity Band PV: Dynamics of Carriers Generated via Sub-band gap Photons
NASA Astrophysics Data System (ADS)
Sullivan, Joseph; Simmons, Christie; Akey, Austin; Aziz, Michael; Buonassisi, Tonio
2013-03-01
Intermediate band solar cells are a pathway to cells that surpass the Shockley-Queisser limit by enabling the utilization of sub-band gap photons. A proposed method for fabricating an intermediate band material is to use impurities that introduce electronic levels within the band gap. At sufficiently high dopant concentrations, band formation may lead to a suppression of Shockley-Reed-Hall recombination, an idea known as ``lifetime recovery''. We investigate a proposed intermediate band material, silicon hyper-doped with sulfur. This material system exhibits strong sub-band gap optical absorption and metallic conductivity at sufficiently high sulfur concentrations, which makes it a strong candidate for an impurity-band material. We employ low-temperature photoconductivity using sub-band gap light to estimate the trapping rate of electrons in the conduction band. We vary the sulfur concentration near the critical value for the metal-insulator transition to test the idea of ``lifetime recovery'' in the S:Si system.
NASA Astrophysics Data System (ADS)
Eichenfield, Matthew
The dynamic back-action caused by electromagnetic forces (radiation pressure) in optical and microwave cavities is of growing interest. Back-action cooling, for example, is being pursued as a means of achieving the quantum ground state of macroscopic mechanical oscillators. Work in the optical domain has revolved around millimeter- or micrometer-scale structures using the radiation pressure force. By comparison, in microwave devices, low-loss superconducting structures have been used for gradient-force-mediated coupling to a nanomechanical oscillator of picogram mass. In this thesis, two different nanometer-scale structures that use combinations of gradient and radiation pressure optical forces are described theoretically and demonstrated experimentally. These structures merge the fields of cavity optomechanics and nanomechanics into nano-optomechanical systsms (NOMS). The first device, the “Zipper” optomechanical cavity, consists of a pair of doubly-clamped nanoscale beams separated by approximately 100 nanometers, each beam having a mass of 20 picograms and being patterned with a quasi-1D photonic crystal bandgap cavity. The optical mode of the coupled system is exquisitely sensitive to differential motion of the beams, producing optomechanical coupling right at the fundamental limit set by optical diffraction. The mechanical modes of the beam probed with a background sensitivity only a factor of 4 above the standard quantum limit, and the application of less than a milliwatt of optical power is shown to increase the mechanical rigidity of the system by almost an order of magnitude. The second device focuses on just one of the doubly-clamped nanoscale beams of the Zipper. We show that, in addition to a photonic bandgap cavity, the periodic patterning of the beam also produces a phononic bandgap cavity with localized mechanical modes having frequencies in the microwave regime. We call these photonic and phononic crystal bandgap cavities optomechanical crystals
Model for topological phononics and phonon diode
NASA Astrophysics Data System (ADS)
Liu, Yizhou; Xu, Yong; Zhang, Shou-Cheng; Duan, Wenhui
2017-08-01
The quantum anomalous Hall effect, an exotic topological state first theoretically predicted by Haldane and recently experimentally observed, has attracted enormous interest for low-power-consumption electronics. In this work, we derived a Schrödinger-like equation of phonons, where topology-related quantities, time-reversal symmetry, and its breaking can be naturally introduced similar to the process for electrons. Furthermore, we proposed a phononic analog of the Haldane model, which makes the novel quantum (anomalous) Hall-like phonon states characterized by one-way gapless edge modes immune to scattering. The topologically nontrivial phonon states are useful not only for conducting phonons without dissipation but also for designing highly efficient phononic devices, like an ideal phonon diode, which could find important applications in future phononics.
Switchable topological phonon channels
NASA Astrophysics Data System (ADS)
Süsstrunk, Roman; Zimmermann, Philipp; Huber, Sebastian D.
2017-01-01
Guiding energy deliberately is one of the central elements in engineering and information processing. It is often achieved by designing specific transport channels in a suitable material. Topological metamaterials offer a way to construct stable and efficient channels of unprecedented versatility. However, due to their stability it can be tricky to terminate them or to temporarily shut them off without changing the material properties massively. While a lot of effort was put into realizing mechanical topological metamaterials, almost no works deal with manipulating their edge channels in sight of applications. Here, we take a step in this direction, by taking advantage of local symmetry breaking potentials to build a switchable topological phonon channel.
NASA Astrophysics Data System (ADS)
Pourghasemi, Mahyar; Garg, Jivtesh
2015-03-01
There is a huge desire to increase operation speeds in modern integrated circuits as they get more compact. Heat generation in such a submicron devices is a key factor limiting their performances. As a solution, thermoelectric cooling in heterostructures can address heat dissipation issue in submicron devices. Performance of single barrier heterostructures depends strongly on several parameters including barrier height, barrier width and thermal conductivity of barrier. Superlattice structures have been known to have the lowest thermal conductivities reported for crystalline materials. Low thermal conductivity is beneficial for thermoelectric cooling as it reduces the heat flow from hot end to cold junction. Moreover the band offset between the barrier and base material can be easily tuned by changing the superlattice period. By optimizing the conduction band offset (barrier height), it is possible to control the Joule heating and also optimize the amount of heat absorbed due to Peltier cooling. We investigate the feasibility of using PbSe/PbSnSe superlattice in heterostructures using Monte Carlo simulation. The effect of different parameters such as barrier height, barrier width and superlattice thermal conductivity on thermoelectric cooling of such structures will be presented.
NASA Astrophysics Data System (ADS)
Mukherjee, Sushovan; Scarpa, Fabrizio; Gopalakrishnan, S.
2015-04-01
A novel design for the geometric configuration of honeycombs using a seamless combination of auxetic and conventional cores-elements with negative and positive Possion ratios respectively, has been presented. The proposed design has been shown to generate a superior band gap property while retaining all major advantages of a purely conventional or purely auxetic honeycomb structure. Seamless combination ensures that joint cardinality is also retained. Several configurations involving different degree of auxeticity and different proportions auxetic and conventional elements have been analyzed. It has been shown that the preferred configurations open up wide and clean band gap at a significantly lower frequency ranges compared to their pure counterparts. In view of existence of band gaps being desired feature for the phononic applications, reported results might be appealing. Use of such design may enable superior vibration control as well. Proposed configurations can be made isovolumic and iso-weight giving designers a fairer ground of applying such configurations without significantly changing size and weight criteria.
Kassambara, Alboukadel; Hose, Dirk; Moreaux, Jérôme; Walker, Brian A.; Protopopov, Alexei; Reme, Thierry; Pellestor, Franck; Pantesco, Véronique; Jauch, Anna; Morgan, Gareth; Goldschmidt, Hartmut; Klein, Bernard
2012-01-01
Background Genetic abnormalities are common in patients with multiple myeloma, and may deregulate gene products involved in tumor survival, proliferation, metabolism and drug resistance. In particular, translocations may result in a high expression of targeted genes (termed spike expression) in tumor cells. We identified spike genes in multiple myeloma cells of patients with newly-diagnosed myeloma and investigated their prognostic value. Design and Methods Genes with a spike expression in multiple myeloma cells were picked up using box plot probe set signal distribution and two selection filters. Results In a cohort of 206 newly diagnosed patients with multiple myeloma, 2587 genes/expressed sequence tags with a spike expression were identified. Some spike genes were associated with some transcription factors such as MAF or MMSET and with known recurrent translocations as expected. Spike genes were not associated with increased DNA copy number and for a majority of them, involved unknown mechanisms. Of spiked genes, 36.7% clustered significantly in 149 out of 862 documented chromosome (sub)bands, of which 53 had prognostic value (35 bad, 18 good). Their prognostic value was summarized with a spike band score that delineated 23.8% of patients with a poor median overall survival (27.4 months versus not reached, P<0.001) using the training cohort of 206 patients. The spike band score was independent of other gene expression profiling-based risk scores, t(4;14), or del17p in an independent validation cohort of 345 patients. Conclusions We present a new approach to identify spike genes and their relationship to patients’ survival. PMID:22102711
Malekiha, Mahdi; Tselniker, Igor; Plant, David V
2015-12-14
We propose and experimentally demonstrate a novel sub-band multiplexed data architecture for chromatic dispersion (CD) mitigation. We have demonstrated 32 GBaud multi-sub-band (MSB) dual-polarization (DP) 16QAM transmission over 2400 km. Using this approach, the transmitted signal bandwidth is divided into multiple narrow-bandwidth sub-bands, each operating at a lower baud rate. Within each sub-band bandwidth, the CD frequency response can be approximated as a linear-phase band-pass filter, which can be considered as an analog delay that does not require compensation. Therefore, the resulting receiver digital signal processing (DSP) is simplified due to the removal of the CD compensation equalizer. In addition, this leads to efficient parallelization of DSP tasks by deploying multiple independent sub-band processors running at a lower clock rate. The proposed system reduces receiver computational complexity and offers 1 dB higher Kerr-nonlinearity tolerance and 2% extended transmission reach in comparison to the conventional single carrier systems.
NASA Astrophysics Data System (ADS)
Limaye, Mukta V.; Chen, S. C.; Lee, C. Y.; Chen, L. Y.; Singh, Shashi B.; Shao, Y. C.; Wang, Y. F.; Hsieh, S. H.; Hsueh, H. C.; Chiou, J. W.; Chen, C. H.; Jang, L. Y.; Cheng, C. L.; Pong, W. F.; Hu, Y. F.
2015-06-01
The correlation between sub-band gap absorption and the chemical states and electronic and atomic structures of S-hyperdoped Si have been extensively studied, using synchrotron-based x-ray photoelectron spectroscopy (XPS), x-ray absorption near-edge spectroscopy (XANES), extended x-ray absorption fine structure (EXAFS), valence-band photoemission spectroscopy (VB-PES) and first-principles calculation. S 2p XPS spectra reveal that the S-hyperdoped Si with the greatest (~87%) sub-band gap absorption contains the highest concentration of S2- (monosulfide) species. Annealing S-hyperdoped Si reduces the sub-band gap absorptance and the concentration of S2- species, but significantly increases the concentration of larger S clusters [polysulfides (Sn2-, n > 2)]. The Si K-edge XANES spectra show that S hyperdoping in Si increases (decreased) the occupied (unoccupied) electronic density of states at/above the conduction-band-minimum. VB-PES spectra evidently reveal that the S-dopants not only form an impurity band deep within the band gap, giving rise to the sub-band gap absorption, but also cause the insulator-to-metal transition in S-hyperdoped Si samples. Based on the experimental results and the calculations by density functional theory, the chemical state of the S species and the formation of the S-dopant states in the band gap of Si are critical in determining the sub-band gap absorptance of hyperdoped Si samples.
Study of sub band gap absorption of Sn doped CdSe thin films
NASA Astrophysics Data System (ADS)
Kaur, Jagdish; Rani, Mamta; Tripathi, S. K.
2014-04-01
The nanocrystalline thin films of Sn doped CdSe at different dopants concentration are prepared by thermal evaporation technique on glass substrate at room temperature. The effect of Sn doping on the optical properties of CdSe has been studied. A decrease in band gap value is observed with increase in Sn concentration. Constant photocurrent method (CPM) is used to study the absorption coefficient in the sub band gap region. Urbach energy has been obtained from CPM spectra which are found to increase with amount of Sn dopants. The refractive index data calculated from transmittance is used for the identification of oscillator strength and oscillator energy using single oscillator model which is found to be 7.7 and 2.12 eV, 6.7 and 2.5 eV for CdSe:Sn 1% and CdSe:Sn 5% respectively.
Manipulation of Phonons with Phononic Crystals
Leseman, Zayd Chad
2015-07-09
There were three research goals associated with this project. First, was to experimentally demonstrate phonon spectrum control at THz frequencies using Phononic Crystals (PnCs), i.e. demonstrate coherent phonon scattering with PnCs. Second, was to experimentally demonstrate analog PnC circuitry components at GHz frequencies. The final research goal was to gain a fundamental understanding of phonon interaction using computational methods. As a result of this work, 7 journal papers have been published, 1 patent awarded, 14 conference presentations given, 4 conference publications, and 2 poster presentations given.
Thermally induced effect on sub-band gap absorption in Ag doped CdSe thin films
NASA Astrophysics Data System (ADS)
Kaur, Jagdish; Sharma, Kriti; Bharti, Shivani; Tripathi, S. K.
2015-05-01
Thin films of Ag doped CdSe have been prepared by thermal evaporation using inert gas condensation (IGC) method taking Argon as inert gas. The prepared thin films are annealed at 363 K for one hour. The sub-band gap absorption spectra in the as deposited and annealed thin films have been studied using constant photocurrent method (CPM). The absorption coefficient in the sub-band gap region is described by an Urbach tail in both as deposited and annealed thin films. The value of Urbach energy and number density of trap states have been calculated from the absorption coefficient in the sub-band gap region which have been found to increase after annealing treatment indicating increase in disorderness in the lattice. The energy distribution of the occupied density of states below Fermi level has also been studied using derivative procedure of absorption coefficient.
Micolich, A P; Zülicke, U
2011-09-14
The semiconductor quantum point contact has long been a focal point for studies of one-dimensional (1D) electron transport. Their electrical properties are typically studied using ac conductance methods, but recent work has shown that the dc conductance can be used to obtain additional information, with a density-dependent Landé effective g-factor recently reported (Chen et al 2009 Phys. Rev. B 79 081301). We discuss previous dc conductance measurements of quantum point contacts, demonstrating how valuable additional information can be extracted from the data. We provide a comprehensive and general framework for dc conductance measurements that provides a path to improving the accuracy of existing data and obtaining useful additional data. A key aspect is that dc conductance measurements can be used to map the energy of the 1D sub-band edges directly, giving new insight into the physics that takes place as the spin-split 1D sub-bands populate. Through a re-analysis of the data obtained by Chen et al, we obtain two findings. The first is that the 2↓ sub-band edge closely tracks the source chemical potential when it first begins populating before dropping more rapidly in energy. The second is that the 2↑ sub-band populates more rapidly as the sub-band edge approaches the drain potential. This second finding suggests that the spin-gap may stop opening, or even begin to close again, as the 2↑ sub-band continues populating, consistent with recent theoretical calculations and experimental studies.
Nanoscale pillar hypersonic surface phononic crystals
NASA Astrophysics Data System (ADS)
Yudistira, D.; Boes, A.; Graczykowski, B.; Alzina, F.; Yeo, L. Y.; Sotomayor Torres, C. M.; Mitchell, A.
2016-09-01
We report on nanoscale pillar-based hypersonic phononic crystals in single crystal Z-cut lithium niobate. The phononic crystal is formed by a two-dimensional periodic array of nearly cylindrical nanopillars 240 nm in diameter and 225 nm in height, arranged in a triangular lattice with a 300-nm lattice constant. The nanopillars are fabricated by the recently introduced nanodomain engineering via laser irradiation of patterned chrome followed by wet etching. Numerical simulations and direct measurements using Brillouin light scattering confirm the simultaneous existence of nonradiative complete surface phononic band gaps. The band gaps are found below the sound line at hypersonic frequencies in the range 2-7 GHz, formed from local resonances and Bragg scattering. These hypersonic structures are realized directly in the piezoelectric material lithium niobate enabling phonon manipulation at significantly higher frequencies than previously possible with this platform, opening new opportunities for many applications in plasmonic, optomechanic, microfluidic, and thermal engineering.
Reprogrammable Phononic Metasurfaces.
Bilal, Osama R; Foehr, André; Daraio, Chiara
2017-08-25
Phononic metamaterials rely on the presence of resonances in a structured medium to control the propagation of elastic waves. Their response depends on the geometry of their fundamental building blocks. A major challenge in metamaterials design is the realization of basic building blocks that can be tuned dynamically. Here, a metamaterial plate is realized that can be dynamically tuned by harnessing geometric and magnetic nonlinearities in the individual unit cells. The proposed tuning mechanism allows a stiffness variability of the individual unit cells and can control the amplitude of transmitted excitation through the plate over three orders of magnitude. The concepts can be extended to metamaterials at different scales, and they can be applied in a broad range of engineering applications, from seismic shielding at low frequency to ultrasonic cloaking at higher frequency ranges. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
NASA Astrophysics Data System (ADS)
Elfimchev, S.; Chandran, M.; Akhvlediani, R.; Hoffman, A.
2017-07-01
In this study the origin of visible sub-band gap photoelectron emission (PEE) from polycrystalline diamond films is investigated. The PEE yields as a function of temperature were studied in the wavelengths range of 360-520 nm. Based on the comparison of electron emission yields from diamond films deposited on silicon and molybdenum substrates, with different thicknesses and nitrogen doping levels, we suggested that photoelectrons are generated from nitrogen related centers in diamond. Our results show that diamond film thickness and substrate material have no significant influence on the PEE yield. We found that nanocrystalline diamond films have low electron emission yields, compared to microcrystalline diamond, due to the presence of high amount of defects in the former, which trap excited electrons before escaping into the vacuum. However, the low PEE yield of nanocrystalline diamond films was found to increase with temperature. The phenomenon was explained by the trap assisted photon enhanced thermionic emission (ta-PETE) model. According to the ta-PETE model, photoelectrons are trapped by shallow traps, followed by thermal excitation at elevated temperatures and escape into the vacuum. Activation energies of trap levels were estimated for undoped nanocrystalline, undoped microcrystalline and N-doped diamond films using the Richardson-Dushman equation, which gives 0.13, 0.39 and 0.04 eV, respectively. Such low activation energy of trap levels makes the ta-PETE process very effective at elevated temperatures.
Sub-band denoising and spline curve fitting method for hemodynamic measurement in perfusion MRI
NASA Astrophysics Data System (ADS)
Lin, Hong-Dun; Huang, Hsiao-Ling; Hsu, Yuan-Yu; Chen, Chi-Chen; Chen, Ing-Yi; Wu, Liang-Chi; Liu, Ren-Shyan; Lin, Kang-Ping
2003-05-01
In clinical research, non-invasive MR perfusion imaging is capable of investigating brain perfusion phenomenon via various hemodynamic measurements, such as cerebral blood volume (CBV), cerebral blood flow (CBF), and mean trasnit time (MTT). These hemodynamic parameters are useful in diagnosing brain disorders such as stroke, infarction and periinfarct ischemia by further semi-quantitative analysis. However, the accuracy of quantitative analysis is usually affected by poor signal-to-noise ratio image quality. In this paper, we propose a hemodynamic measurement method based upon sub-band denoising and spline curve fitting processes to improve image quality for better hemodynamic quantitative analysis results. Ten sets of perfusion MRI data and corresponding PET images were used to validate the performance. For quantitative comparison, we evaluate gray/white matter CBF ratio. As a result, the hemodynamic semi-quantitative analysis result of mean gray to white matter CBF ratio is 2.10 +/- 0.34. The evaluated ratio of brain tissues in perfusion MRI is comparable to PET technique is less than 1-% difference in average. Furthermore, the method features excellent noise reduction and boundary preserving in image processing, and short hemodynamic measurement time.
Acoustic classification of battlefield transient events using wavelet sub-band features
NASA Astrophysics Data System (ADS)
Azimi-Sadjadi, M. R.; Jiang, Y.; Srinivasan, S.
2007-04-01
Detection, localization and classification of battlefield acoustic transient events are of great importance especially for military operations in urban terrain (MOUT). Generally, there can be a wide variety of battlefield acoustic transient events such as different caliber gunshots, artillery fires, and mortar fires. The discrimination of different types of transient sources is plagued by highly non-stationary nature of these signals, which makes the extraction of representative features a challenging task. This is compounded by the variations in the environmental and operating conditions and existence of a wide range of possible interference. This paper presents new approaches for transient signal estimation and feature extraction from acoustic signatures collected by several distributed sensor nodes. A maximum likelihood (ML)-based method is developed to remove noise/interference and fading effects and restore the acoustic transient signals. The estimated transient signals are then represented using wavelets. The multi-resolution property of the wavelets allows for capturing fine details in the transient signals that can be utilized to successfully classify them. Wavelet sub-band higher order moments and energy-based features are used to characterize the transient signals. The discrimination ability of the subband features for transient signal classification has been demonstrated on several different caliber gunshots. Important findings and observations on these results are also presented.
Limaye, Mukta V.; Chen, S. C.; Lee, C. Y.; Chen, L. Y.; Singh, Shashi B.; Shao, Y. C.; Wang, Y. F.; Hsieh, S. H.; Hsueh, H. C.; Chiou, J. W.; Chen, C. H.; Jang, L. Y.; Cheng, C. L.; Pong, W. F.; Hu, Y. F.
2015-01-01
The correlation between sub-band gap absorption and the chemical states and electronic and atomic structures of S-hyperdoped Si have been extensively studied, using synchrotron-based x-ray photoelectron spectroscopy (XPS), x-ray absorption near-edge spectroscopy (XANES), extended x-ray absorption fine structure (EXAFS), valence-band photoemission spectroscopy (VB-PES) and first-principles calculation. S 2p XPS spectra reveal that the S-hyperdoped Si with the greatest (~87%) sub-band gap absorption contains the highest concentration of S2− (monosulfide) species. Annealing S-hyperdoped Si reduces the sub-band gap absorptance and the concentration of S2− species, but significantly increases the concentration of larger S clusters [polysulfides (Sn2−, n > 2)]. The Si K-edge XANES spectra show that S hyperdoping in Si increases (decreased) the occupied (unoccupied) electronic density of states at/above the conduction-band-minimum. VB-PES spectra evidently reveal that the S-dopants not only form an impurity band deep within the band gap, giving rise to the sub-band gap absorption, but also cause the insulator-to-metal transition in S-hyperdoped Si samples. Based on the experimental results and the calculations by density functional theory, the chemical state of the S species and the formation of the S-dopant states in the band gap of Si are critical in determining the sub-band gap absorptance of hyperdoped Si samples. PMID:26098075
Robins, Lawrence H.; Bertness, Kris A.; Barker, Joy M.; Sanford, Norman A.; Schlager, John B.
2007-06-01
GaN nanowires with diameters of 50-250 nm, grown by catalyst-free molecular beam epitaxy, were characterized by photoluminescence (PL) and cathodoluminescence (CL) spectroscopy at temperatures from 3 to 297 K. Both as-grown samples and dispersions of the nanowires onto other substrates were examined. The properties of the near-band-edge PL and CL spectra were discussed in Part I of this study by [Robins et al. [L. H. Robins, K. A. Bertness, J. M. Barker, N. A. Sanford, and J. B. Schlager, J. Appl. Phys. 101,113505 (2007)]. Spectral features below the band gap, and the effect of extended electron irradiation on the CL, are discussed in Part II. The observed sub-band-gap PL and CL peaks are identified as phonon replicas of the free-exciton transitions, or excitons bound to structural defects or surface states. The defect-related peaks in the nanowires are correlated with luminescence lines previously reported in GaN films, denoted the Y lines [M. A. Reshchikov and H. Morkoc, J. Appl. Phys. 97, 061301 (2005)]. The CL was partially quenched by electron beam irradiation for an extended time; the quenching was stronger for the free and shallow-donor-bound exciton peaks than for the defect-related peaks. The quenching appeared to saturate at high irradiation dose (with final intensity {approx_equal}30% of initial intensity) and was reversible on thermal cycling to room temperature. The electron irradiation-induced quenching of the CL is ascribed to charge injection and trapping phenomena.
NASA Astrophysics Data System (ADS)
Robins, Lawrence H.; Bertness, Kris A.; Barker, Joy M.; Sanford, Norman A.; Schlager, John B.
2007-06-01
GaN nanowires with diameters of 50-250 nm, grown by catalyst-free molecular beam epitaxy, were characterized by photoluminescence (PL) and cathodoluminescence (CL) spectroscopy at temperatures from 3 to 297 K. Both as-grown samples and dispersions of the nanowires onto other substrates were examined. The properties of the near-band-edge PL and CL spectra were discussed in Part I of this study by [Robins et al. [L. H. Robins, K. A. Bertness, J. M. Barker, N. A. Sanford, and J. B. Schlager, J. Appl. Phys. 101,113505 (2007)]. Spectral features below the band gap, and the effect of extended electron irradiation on the CL, are discussed in Part II. The observed sub-band-gap PL and CL peaks are identified as phonon replicas of the free-exciton transitions, or excitons bound to structural defects or surface states. The defect-related peaks in the nanowires are correlated with luminescence lines previously reported in GaN films, denoted the Y lines [M. A. Reshchikov and H. Morkoc, J. Appl. Phys. 97, 061301 (2005)]. The CL was partially quenched by electron beam irradiation for an extended time; the quenching was stronger for the free and shallow-donor-bound exciton peaks than for the defect-related peaks. The quenching appeared to saturate at high irradiation dose (with final intensity ≈30% of initial intensity) and was reversible on thermal cycling to room temperature. The electron irradiation-induced quenching of the CL is ascribed to charge injection and trapping phenomena.
NASA Astrophysics Data System (ADS)
Peelaers, H.; Partoens, B.; Peeters, F. M.
2009-09-01
The phonon spectra of thin freestanding, hydrogen passivated, Ge nanowires are calculated by ab initio techniques. The effect of confinement on the phonon modes as caused by the small diameters of the wires is investigated. Confinement causes a hardening of the optical modes and a softening of the longitudinal acoustic modes. The stability of the nanowires, undoped or doped with B or P atoms, is investigated using the obtained phonon spectra. All considered wires were stable, except for highly doped, very thin nanowires.
Gorishnyy, T; Ullal, C K; Maldovan, M; Fytas, G; Thomas, E L
2005-03-25
In this Letter we propose the use of hypersonic phononic crystals to control the emission and propagation of high frequency phonons. We report the fabrication of high quality, single crystalline hypersonic crystals using interference lithography and show that direct measurement of their phononic band structure is possible with Brillouin light scattering. Numerical calculations are employed to explain the nature of the observed propagation modes. This work lays the foundation for experimental studies of hypersonic crystals and, more generally, phonon-dependent processes in nanostructures.
Phonon filtering for reduced thermal conductance in unconventional superlattices
NASA Astrophysics Data System (ADS)
Wei, Zhiyong; Chen, Weiyu; Chen, Zhen; Bi, Kedong; Yang, Juekuan; Chen, Yunfei
2017-08-01
The thermal transport of an unconventional superlattice is investigated by nonequilibrium molecular dynamics simulation. It is shown that the thermal conductance of a two-order superlattice decreases by 15-29% as compared with that of a conventional superlattice. This result is unambiguously explained by the phonon transmission functions of similar one-dimensional superlattice atomic chains calculated by Green’s function method. It is demonstrated that the multiscale structure introduces additional phonon bandgaps, leading to the reduction in thermal conductance due to phonon filtering effects. The proposed unconventional superlattice may find potential applications in phonon engineering, such as thermoelectrics and thermal isolation.
Quantum Transport and Sub-Band Structure of Modulation-Doped GaAs/AlAs Core-Superlattice Nanowires.
Irber, Dominik M; Seidl, Jakob; Carrad, Damon J; Becker, Jonathan; Jeon, Nari; Loitsch, Bernhard; Winnerl, Julia; Matich, Sonja; Döblinger, Markus; Tang, Yang; Morkötter, Stefanie; Abstreiter, Gerhard; Finley, Jonathan J; Grayson, Matthew; Lauhon, Lincoln J; Koblmüller, Gregor
2017-08-09
Modulation-doped III-V semiconductor nanowire (NW) heterostructures have recently emerged as promising candidates to host high-mobility electron channels for future high-frequency, low-energy transistor technologies. The one-dimensional geometry of NWs also makes them attractive for studying quantum confinement effects. Here, we report correlated investigations into the discrete electronic sub-band structure of confined electrons in the channel of Si δ-doped GaAs-GaAs/AlAs core-superlattice NW heterostructures and the associated signatures in low-temperature transport. On the basis of accurate structural and dopant analysis using scanning transmission electron microscopy and atom probe tomography, we calculated the sub-band structure of electrons confined in the NW core and employ a labeling system inspired by atomic orbital notation. Electron transport measurements on top-gated NW transistors at cryogenic temperatures revealed signatures consistent with the depopulation of the quasi-one-dimensional sub-bands, as well as confinement in zero-dimensional-like states due to an impurity-defined background disorder potential. These findings are instructive toward reaching the ballistic transport regime in GaAs-AlGaAs based NW systems.
Toward quantitative modeling of silicon phononic thermocrystals
Lacatena, V.; Haras, M.; Robillard, J.-F. Dubois, E.; Monfray, S.; Skotnicki, T.
2015-03-16
The wealth of technological patterning technologies of deca-nanometer resolution brings opportunities to artificially modulate thermal transport properties. A promising example is given by the recent concepts of 'thermocrystals' or 'nanophononic crystals' that introduce regular nano-scale inclusions using a pitch scale in between the thermal phonons mean free path and the electron mean free path. In such structures, the lattice thermal conductivity is reduced down to two orders of magnitude with respect to its bulk value. Beyond the promise held by these materials to overcome the well-known “electron crystal-phonon glass” dilemma faced in thermoelectrics, the quantitative prediction of their thermal conductivity poses a challenge. This work paves the way toward understanding and designing silicon nanophononic membranes by means of molecular dynamics simulation. Several systems are studied in order to distinguish the shape contribution from bulk, ultra-thin membranes (8 to 15 nm), 2D phononic crystals, and finally 2D phononic membranes. After having discussed the equilibrium properties of these structures from 300 K to 400 K, the Green-Kubo methodology is used to quantify the thermal conductivity. The results account for several experimental trends and models. It is confirmed that the thin-film geometry as well as the phononic structure act towards a reduction of the thermal conductivity. The further decrease in the phononic engineered membrane clearly demonstrates that both phenomena are cumulative. Finally, limitations of the model and further perspectives are discussed.
Toward quantitative modeling of silicon phononic thermocrystals
NASA Astrophysics Data System (ADS)
Lacatena, V.; Haras, M.; Robillard, J.-F.; Monfray, S.; Skotnicki, T.; Dubois, E.
2015-03-01
The wealth of technological patterning technologies of deca-nanometer resolution brings opportunities to artificially modulate thermal transport properties. A promising example is given by the recent concepts of "thermocrystals" or "nanophononic crystals" that introduce regular nano-scale inclusions using a pitch scale in between the thermal phonons mean free path and the electron mean free path. In such structures, the lattice thermal conductivity is reduced down to two orders of magnitude with respect to its bulk value. Beyond the promise held by these materials to overcome the well-known "electron crystal-phonon glass" dilemma faced in thermoelectrics, the quantitative prediction of their thermal conductivity poses a challenge. This work paves the way toward understanding and designing silicon nanophononic membranes by means of molecular dynamics simulation. Several systems are studied in order to distinguish the shape contribution from bulk, ultra-thin membranes (8 to 15 nm), 2D phononic crystals, and finally 2D phononic membranes. After having discussed the equilibrium properties of these structures from 300 K to 400 K, the Green-Kubo methodology is used to quantify the thermal conductivity. The results account for several experimental trends and models. It is confirmed that the thin-film geometry as well as the phononic structure act towards a reduction of the thermal conductivity. The further decrease in the phononic engineered membrane clearly demonstrates that both phenomena are cumulative. Finally, limitations of the model and further perspectives are discussed.
Phonon lifetimes and phonon decay in InN
NASA Astrophysics Data System (ADS)
Pomeroy, J. W.; Kuball, M.; Lu, H.; Schaff, W. J.; Wang, X.; Yoshikawa, A.
2005-05-01
We report on the Raman analysis of A1(LO) (longitudinal optical) and E2 phonon lifetimes in InN and their temperature dependence from 80 to 700 K. Our experimental results show that among the various possible decay channels, the A1(LO) phonon decays asymmetrically into a high energy and a low energy phonon, whereas the E2 phonon predominantly decays into three phonons. Possible decay channels of the A1(LO) phonon may involve combinations of transverse optical and acoustic phonons. Phonon lifetimes of 1.3 and 4 ps were measured at 80 K for the A1(LO) and the E2 phonons, respectively. This rather long A1(LO) phonon lifetime suggests that hot phonon effects will play a role in InN for carrier relaxation.
Liu, Yanhong; Li, La; Wang, Song; Gao, Ping; Pan, Lujun; Zhang, Jialiang; Zhou, Peng; Li, Jinhua; Weng, Zhankun
2015-02-09
In this paper, we discuss a model of sub-band in resistive switching nonvolatile memories with a structure of silver/aluminum oxide/p-type silicon (Ag/Al{sub x}O{sub y}/p-Si), in which the sub-band is formed by overlapping of wave functions of electron-occupied oxygen vacancies in Al{sub x}O{sub y} layer deposited by atomic layer deposition technology. The switching processes exhibit the characteristics of the bipolarity, discreteness, and no need of forming process, all of which are discussed deeply based on the model of sub-band. The relationships between the SET voltages and distribution of trap levels are analyzed qualitatively. The semiconductor-like behaviors of ON-state resistance affirm the sub-band transport mechanism instead of the metal filament mechanism.
Birefringent phononic structures
Psarobas, I. E. Exarchos, D. A.; Matikas, T. E.
2014-12-15
Within the framework of elastic anisotropy, caused in a phononic crystal due to low crystallographic symmetry, we adopt a model structure, already introduced in the case of photonic metamaterials, and by analogy, we study the effect of birefringence and acoustical activity in a phononic crystal. In particular, we investigate its low-frequency behavior and comment on the factors which determine chirality by reference to this model.
Temperature dependence of phonon-defect interactions: phonon scattering vs. phonon trapping
Bebek, M. B.; Stanley, C. M.; Gibbons, T. M.; Estreicher, S. K.
2016-01-01
The interactions between thermal phonons and defects are conventionally described as scattering processes, an idea proposed almost a century ago. In this contribution, ab-initio molecular-dynamics simulations provide atomic-level insight into the nature of these interactions. The defect is the Si|X interface in a nanowire containing a δ-layer (X is C or Ge). The phonon-defect interactions are temperature dependent and involve the trapping of phonons for meaningful lengths of time in defect-related, localized, vibrational modes. No phonon scattering occurs and the momentum of the phonons released by the defect is unrelated to the momentum of the phonons that generated the excitation. The results are extended to the interactions involving only bulk phonons and to phonon-defect interactions at high temperatures. These do resemble scattering since phonon trapping occurs for a length of time short enough for the momentum of the incoming phonon to be conserved. PMID:27535463
Tripathy, Rajesh Kumar; Dandapat, Samarendra
2017-04-01
The complex wavelet sub-band bi-spectrum (CWSB) features are proposed for detection and classification of myocardial infarction (MI), heart muscle disease (HMD) and bundle branch block (BBB) from 12-lead ECG. The dual tree CW transform of 12-lead ECG produces CW coefficients at different sub-bands. The higher-order CW analysis is used for evaluation of CWSB. The mean of the absolute value of CWSB, and the number of negative phase angle and the number of positive phase angle features from the phase of CWSB of 12-lead ECG are evaluated. Extreme learning machine and support vector machine (SVM) classifiers are used to evaluate the performance of CWSB features. Experimental results show that the proposed CWSB features of 12-lead ECG and the SVM classifier are successful for classification of various heart pathologies. The individual accuracy values for MI, HMD and BBB classes are obtained as 98.37, 97.39 and 96.40%, respectively, using SVM classifier and radial basis function kernel function. A comparison has also been made with existing 12-lead ECG-based cardiac disease detection techniques.
Annealing-induced optical and sub-band-gap absorption parameters of Sn-doped CdSe thin films
NASA Astrophysics Data System (ADS)
Kaur, Jagdish; Tripathi, S. K.
2016-01-01
Thin films of Sn-doped CdSe were prepared by thermal evaporation onto glass substrates in an argon gas atmosphere and annealed at different temperatures. Structural evaluation of the films was carried out using X-ray diffraction and their stoichiometry studied by energy-dispersive X-ray analysis. The films exhibit a preferred orientation along the hexagonal direction of CdSe. The optical transmittance of the films shows a red shift of the absorption edge with annealing. The fundamental absorption edge corresponds to a direct energy gap with a temperature coefficient of 3.34 × 10-3 eV K-1. The refractive index, optical conductivity and real and imaginary parts of the dielectric constants were found to increase after annealing. The sub-band gap absorption coefficient was evaluated using the constant photocurrent method. It varies exponentially with photon energy. The Urbach energy, the density of defect states, and the steepness of the density of localized states were evaluated from the sub-band-gap absorption.
Distinguishing between spatial coherence and temporal coherence of phonons
NASA Astrophysics Data System (ADS)
Latour, Benoit; Chalopin, Yann
2017-06-01
Coherent phonon transport is regarded as a promising strategy for controlling thermal properties in solids using the wave nature of phonons. However, no clear distinction between the spatial and temporal phonon coherence has been accounted for and a formalism that quantifies these two effects is still to be found. In this work, we propose a statistical approach for calculating the spatial and temporal coherence spectra using molecular dynamics simulations. We provide a microscopic assessment of these properties and we theoretically demonstrate that, while temporal and spatial coherence can be analytically related under specific conditions, they represent two characteristic lengths that set apart different physical effects. The former is associated with the phonon mean free path while the latter can be regarded as a measure of localization, representing the spatial extension of phonon wave packets. This provides a framework to engineer heat conduction in solids by quantitatively revealing the wave/particle nature of the vibrational modes.
Phonon squeezed states: quantum noise reduction in solids
NASA Astrophysics Data System (ADS)
Hu, Xuedong; Nori, Franco
1999-03-01
This article discusses quantum fluctuation properties of a crystal lattice, and in particular, phonon squeezed states. Squeezed states of phonons allow a reduction in the quantum fluctuations of the atomic displacements to below the zero-point quantum noise level of coherent phonon states. Here we discuss our studies of both continuous-wave and impulsive second-order Raman scattering mechanisms. The later approach was used to experimentally suppress (by one part in a million) fluctuations in phonons. We calculate the expectation values and fluctuations of both the atomic displacement and the lattice amplitude operators, as well as the effects of the phonon squeezed states on macroscopically measurable quantities, such as changes in the dielectric constant. These results are compared with recent experiments. Further information, including preprints and animations, are available in http://www-personal.engin.umich.edu/∼nori/squeezed.html.
Phononic crystal diffraction gratings
NASA Astrophysics Data System (ADS)
Moiseyenko, Rayisa P.; Herbison, Sarah; Declercq, Nico F.; Laude, Vincent
2012-02-01
When a phononic crystal is interrogated by an external source of acoustic waves, there is necessarily a phenomenon of diffraction occurring on the external enclosing surfaces. Indeed, these external surfaces are periodic and the resulting acoustic diffraction grating has a periodicity that depends on the orientation of the phononic crystal. This work presents a combined experimental and theoretical study on the diffraction of bulk ultrasonic waves on the external surfaces of a 2D phononic crystal that consists of a triangular lattice of steel rods in a water matrix. The results of transmission experiments are compared with theoretical band structures obtained with the finite-element method. Angular spectrograms (showing frequency as a function of angle) determined from diffraction experiments are then compared with finite-element simulations of diffraction occurring on the surfaces of the crystal. The experimental results show that the diffraction that occurs on its external surfaces is highly frequency-dependent and has a definite relation with the Bloch modes of the phononic crystal. In particular, a strong influence of the presence of bandgaps and deaf bands on the diffraction efficiency is found. This observation opens perspectives for the design of efficient phononic crystal diffraction gratings.
The effect of n- and p-type doping on coherent phonons in GaN.
Ishioka, Kunie; Kato, Keiko; Ohashi, Naoki; Haneda, Hajime; Kitajima, Masahiro; Petek, Hrvoje
2013-05-22
The effect of doping on the carrier-phonon interaction in wurtzite GaN is investigated by pump-probe reflectivity measurements using 3.1 eV light in near resonance with the fundamental band gap of 3.39 eV. Coherent modulations of the reflectivity due to the E2 and A1(LO) modes, as well as the 2A1(LO) overtone are observed. Doping of acceptor and donor atoms enhances the dephasing of the polar A1(LO) phonon via coupling with plasmons, with the effect of donors being stronger. Doping also enhances the relative amplitude of the coherent A1(LO) phonon with respect to that of the high-frequency E2 phonon, though it does not affect the relative intensity in Raman spectroscopic measurements. We attribute this enhanced coherent amplitude to the transient depletion field screening (TDFS) excitation mechanism, which, in addition to impulsive stimulated Raman scattering (ISRS), contributes to the generation of coherent polar phonons even for sub-band gap excitation. Because the TDFS mechanism requires photoexcitation of carriers, we argue that the interband transition is made possible at a surface with photon energies below the bulk band gap through the Franz-Keldysh effect.
Phonon waveguides for electromechanical circuits.
Hatanaka, D; Mahboob, I; Onomitsu, K; Yamaguchi, H
2014-07-01
Nanoelectromechanical systems (NEMS), utilizing localized mechanical vibrations, have found application in sensors, signal processors and in the study of macroscopic quantum mechanics. The integration of multiple mechanical elements via electrical or optical means remains a challenge in the realization of NEMS circuits. Here, we develop a phonon waveguide using a one-dimensional array of suspended membranes that offers purely mechanical means to integrate isolated NEMS resonators. We demonstrate that the phonon waveguide can support and guide mechanical vibrations and that the periodic membrane arrangement also creates a phonon bandgap that enables control of the phonon propagation velocity. Furthermore, embedding a phonon cavity into the phonon waveguide allows mobile mechanical vibrations to be dynamically switched or transferred from the waveguide to the cavity, thereby illustrating the viability of waveguide-resonator coupling. These highly functional traits of the phonon waveguide architecture exhibit all the components necessary to permit the realization of all-phononic NEMS circuits.
Surface Phonons and Polaritons.
1976-01-01
for an impurity in the surface of a crystal could be observed in the one phonon cross section for the resonant absorption or e.ission of ,—rays by...localized at the surface. The w5 — dependence has a simple physical origin. It is well known that the cross section for scattering of bulk phonons by a...propagate. In Section II of the present Chapter we present the theory underlying the surface induced vibrational properties of crystals which we have
Li, Zenghui; Xu, Bin; Yang, Jian; Song, Jianshe
2015-01-01
This paper focuses on suppressing spectral overlap for sub-band spectral estimation, with which we can greatly decrease the computational complexity of existing spectral estimation algorithms, such as nonlinear least squares spectral analysis and non-quadratic regularized sparse representation. Firstly, our study shows that the nominal ability of the high-order analysis filter to suppress spectral overlap is greatly weakened when filtering a finite-length sequence, because many meaningless zeros are used as samples in convolution operations. Next, an extrapolation-based filtering strategy is proposed to produce a series of estimates as the substitutions of the zeros and to recover the suppression ability. Meanwhile, a steady-state Kalman predictor is applied to perform a linearly-optimal extrapolation. Finally, several typical methods for spectral analysis are applied to demonstrate the effectiveness of the proposed strategy. PMID:25609038
Li, Zenghui; Xu, Bin; Yang, Jian; Song, Jianshe
2014-12-24
This paper focuses on suppressing spectral overlap for sub-band spectral estimation, with which we can greatly decrease the computational complexity of existing spectral estimation algorithms, such as nonlinear least squares spectral analysis and non-quadratic regularized sparse representation. Firstly, our study shows that the nominal ability of the high-order analysis filter to suppress spectral overlap is greatly weakened when filtering a finite-length sequence, because many meaningless zeros are used as samples in convolution operations. Next, an extrapolation-based filtering strategy is proposed to produce a series of estimates as the substitutions of the zeros and to recover the suppression ability. Meanwhile, a steady-state Kalman predictor is applied to perform a linearly-optimal extrapolation. Finally, several typical methods for spectral analysis are applied to demonstrate the effectiveness of the proposed strategy.
PHONONS IN INTRINSIC JOSEPHSON SYSTEMS
C. PREIS; K. SCHMALZL; ET AL
2000-10-01
Subgap structures in the I-V curves of layered superconductors are explained by the excitation of phonons by Josephson oscillations. In the presence of a magnetic field applied parallel to the layers additional structures due to fluxon motion appear. Their coupling with phonons is investigated theoretically and a shift of the phonon resonances in strong magnetic fields is predicted.
Phonon dispersion in hypersonic two-dimensional phononic crystal membranes
NASA Astrophysics Data System (ADS)
Graczykowski, B.; Sledzinska, M.; Alzina, F.; Gomis-Bresco, J.; Reparaz, J. S.; Wagner, M. R.; Sotomayor Torres, C. M.
2015-02-01
We investigate experimentally and theoretically the acoustic phonon propagation in two-dimensional phononic crystal membranes. Solid-air and solid-solid phononic crystals were made of square lattices of holes and Au pillars in and on 250 nm thick single crystalline Si membrane, respectively. The hypersonic phonon dispersion was investigated using Brillouin light scattering. Volume reduction (holes) or mass loading (pillars) accompanied with second-order periodicity and local resonances are shown to significantly modify the propagation of thermally activated GHz phonons. We use numerical modeling based on the finite element method to analyze the experimental results and determine polarization, symmetry, or three-dimensional localization of observed modes.
ERIC Educational Resources Information Center
Reid, John S.
1977-01-01
Discussed are how the thermal vibrations of a solid are described in terms of lattice waves, how these waves interact with other waves, or with themselves, and how one is led from such a description in terms of waves to the concept of a phonon. (Author/MA)
Zarkevich, Nikolai
2014-11-24
ThermoPhonon is a stand-alone code, which can be integrated into other software packages. Typically, it is used together with a density functional theory (DFT) code (such as VASP, Wien2k, AbInit, SIESTA) and a phonon code (such as Phonopy or Phon). The workflow is the following. Molecular dynamics (MD) in a supercell at a given temperature T is performed using another code. After sufficient equilibration, the output in the form of atomic positions and forces for a large number of selected MD steps is recorded into a file. If needed, one can modify this file by applying additional constraints, such as enforced crystal symmetry or subtracted motion of the center of mass. ThermoPhonon reads the file with atomic positions and forces and writes a new file with the force constants. Force constants can be used by another code (such as Phonopy or Phon) to produce phonon spectrum for plotting, in the assumption of known equilibrium atomic positions provided in a separate file.
Phonon properties of americium phosphide
Arya, B. S.; Aynyas, Mahendra; Sanyal, S. P.
2016-05-23
Phonon properties of AmP have been studied by using breathing shell models (BSM) which includes breathing motion of electrons of the Am atoms due to f-d hybridization. The phonon dispersion curves, specific heat calculated from present model. The calculated phonon dispersion curves of AmP are presented follow the same trend as observed in uranium phosphide. We discuss the significance of this approach in predicting the phonon dispersion curves of these compounds and examine the role of electron-phonon interaction.
Phonon properties of americium phosphide
NASA Astrophysics Data System (ADS)
Arya, B. S.; Aynyas, Mahendra; Sanyal, S. P.
2016-05-01
Phonon properties of AmP have been studied by using breathing shell models (BSM) which includes breathing motion of electrons of the Am atoms due to f-d hybridization. The phonon dispersion curves, specific heat calculated from present model. The calculated phonon dispersion curves of AmP are presented follow the same trend as observed in uranium phosphide. We discuss the significance of this approach in predicting the phonon dispersion curves of these compounds and examine the role of electron-phonon interaction.
Geometrical tuning of thermal phonon spectrum in nanoribbons
NASA Astrophysics Data System (ADS)
Ramiere, Aymeric; Volz, Sebastian; Amrit, Jay
2016-03-01
Phonon spectral energy transmission in silicon nanoribbons is investigated using Monte-Carlo simulations in the boundary scattering regime by changing the length and width geometrical parameters. We show that the transition frequency from specular scattering to diffuse scattering is inversely proportional to the edge roughness σ with a geometry independent factor of proportionality. The increase of the length over width ratio \\zeta leads to a decrease of the energy transmission in the diffuse scattering regime which evolves as {{≤ft(1+{{\\zeta}0.59}\\right)}-1} . This trend is explained by developing a model of phonon energy transmission in the fully diffuse scattering regime which takes into account the probability for a diffusively scattered phonon to be directly transmitted from any position on the edge of the nanoribbon. This model establishes the importance of the solid angles in the energy transmission evolution with \\zeta . The transition from unity energy transmission in the specular scattering regime to reduced transmission in the diffuse scattering regime constitutes a low-pass frequency filter for phonons. Our simulations show an energy rejection rate better than 90% for high \\zeta , which paves the way for potential high performance filters. Filtering out high frequency phonons is of significant interest for phononic crystal applications, which use band engineering of phonons in the wave regime with low frequencies.
Superconductivity without phonons.
Monthoux, P; Pines, D; Lonzarich, G G
2007-12-20
The idea of superconductivity without the mediating role of lattice vibrations (phonons) has a long history. It was realized soon after the publication of the Bardeen-Cooper-Schrieffer (BCS) theory of superconductivity 50 years ago that a full treatment of both the charge and spin degrees of freedom of the electron predicts the existence of attractive components of the effective interaction between electrons even in the absence of lattice vibrations--a particular example is the effective interaction that depends on the relative spins of the electrons. Such attraction without phonons can lead to electronic pairing and to unconventional forms of superconductivity that can be much more sensitive than traditional (BCS) superconductivity to the precise details of the crystal structure and to the electronic and magnetic properties of a material.
Chattopadhyay, P.; Karim, B.; Guha Roy, S.
2013-12-28
The sub-band gap optical absorption in chemical bath deposited cadmium sulphide thin films annealed at different temperatures has been critically analyzed with special reference to Urbach relation. It has been found that the absorption co-efficient of the material in the sub-band gap region is nearly constant up to a certain critical value of the photon energy. However, as the photon energy exceeds the critical value, the absorption coefficient increases exponentially indicating the dominance of Urbach rule. The absorption coefficients in the constant absorption region and the Urbach region have been found to be sensitive to annealing temperature. A critical examination of the temperature dependence of the absorption coefficient indicates two different kinds of optical transitions to be operative in the sub-band gap region. After a careful analyses of SEM images, energy dispersive x-ray spectra, and the dc current-voltage characteristics, we conclude that the absorption spectra in the sub-band gap domain is possibly associated with optical transition processes involving deep levels and the grain boundary states of the material.
Yu, Si-Yuan; Sun, Xiao-Chen; Ni, Xu; Wang, Qing; Yan, Xue-Jun; He, Cheng; Liu, Xiao-Ping; Feng, Liang; Lu, Ming-Hui; Chen, Yan-Feng
2016-12-01
Strategic manipulation of wave and particle transport in various media is the key driving force for modern information processing and communication. In a strongly scattering medium, waves and particles exhibit versatile transport characteristics such as localization, tunnelling with exponential decay, ballistic, and diffusion behaviours due to dynamical multiple scattering from strong scatters or impurities. Recent investigations of graphene have offered a unique approach, from a quantum point of view, to design the dispersion of electrons on demand, enabling relativistic massless Dirac quasiparticles, and thus inducing low-loss transport either ballistically or diffusively. Here, we report an experimental demonstration of an artificial phononic graphene tailored for surface phonons on a LiNbO3 integrated platform. The system exhibits Dirac quasiparticle-like transport, that is, pseudo-diffusion at the Dirac point, which gives rise to a thickness-independent temporal beating for transmitted pulses, an analogue of Zitterbewegung effects. The demonstrated fully integrated artificial phononic graphene platform here constitutes a step towards on-chip quantum simulators of graphene and unique monolithic electro-acoustic integrated circuits.
NASA Astrophysics Data System (ADS)
Yu, Si-Yuan; Sun, Xiao-Chen; Ni, Xu; Wang, Qing; Yan, Xue-Jun; He, Cheng; Liu, Xiao-Ping; Feng, Liang; Lu, Ming-Hui; Chen, Yan-Feng
2016-12-01
Strategic manipulation of wave and particle transport in various media is the key driving force for modern information processing and communication. In a strongly scattering medium, waves and particles exhibit versatile transport characteristics such as localization, tunnelling with exponential decay, ballistic, and diffusion behaviours due to dynamical multiple scattering from strong scatters or impurities. Recent investigations of graphene have offered a unique approach, from a quantum point of view, to design the dispersion of electrons on demand, enabling relativistic massless Dirac quasiparticles, and thus inducing low-loss transport either ballistically or diffusively. Here, we report an experimental demonstration of an artificial phononic graphene tailored for surface phonons on a LiNbO3 integrated platform. The system exhibits Dirac quasiparticle-like transport, that is, pseudo-diffusion at the Dirac point, which gives rise to a thickness-independent temporal beating for transmitted pulses, an analogue of Zitterbewegung effects. The demonstrated fully integrated artificial phononic graphene platform here constitutes a step towards on-chip quantum simulators of graphene and unique monolithic electro-acoustic integrated circuits.
Yoctocalorimetry: phonon counting in nanostructures
NASA Astrophysics Data System (ADS)
Roukes, M. L.
1999-03-01
It appears feasible with nanostructures to perform calorimetry at the level of individual thermal phonons. Here I outline an approach employing monocrystalline mesoscopic insulators, which can now be patterned from semiconductor heterostructures into complex geometries with full, three-dimensional relief. Successive application of these techniques also enables definition of integrated nanoscale thermal transducers; coupling these to a dc SQUID readout yields the requisite energy sensitivity and temporal resolution with minimal back action. The prospect of phonon counting opens intriguing experimental possibilities with analogies in quantum optics. These include fluctuation-based phonon spectroscopy, phonon shot noise in the energy relaxation of nanoscale systems, and quantum statistical phenomena such as phonon bunching and anticorrelated electron-phonon exchange.
Effect of the Substrate on Phonon Properties of Graphene Estimated by Raman Spectroscopy
NASA Astrophysics Data System (ADS)
Tivanov, M. S.; Kolesov, E. A.; Korolik, O. V.; Saad, A. M.; Komissarov, I. V.
2017-08-01
Low-temperature Raman studies of supported graphene are presented. A linear temperature dependence of 2D peak linewidths was observed with the coefficients of 0.036 and 0.033 cm^{-1} /K for graphene on copper and glass substrates, respectively, while G peak linewidths remained unchanged throughout the whole temperature range. The different values observed for graphene on glass and copper substrates were explained in terms of the substrate effect on phonon-phonon and electron-phonon interaction properties of the material. The results of the present study can be used to consider substrate effects on phonon transport in graphene for nanoelectronic device engineering.
Estreicher, S. K. Gibbons, T. M.; Kang, By.; Bebek, M. B.
2014-01-07
Defects in semiconductors introduce vibrational modes that are distinct from bulk modes because they are spatially localized in the vicinity of the defect. Light impurities produce high-frequency modes often visible by Fourier-transform infrared absorption or Raman spectroscopy. Their vibrational lifetimes vary by orders of magnitude and sometimes exhibit unexpectedly large isotope effects. Heavy impurities introduce low-frequency modes sometimes visible as phonon replicas in photoluminescence bands. But other defects such as surfaces or interfaces exhibit spatially localized modes (SLMs) as well. All of them can trap phonons, which ultimately decay into lower-frequency bulk phonons. When heat flows through a material containing defects, phonon trapping at localized modes followed by their decay into bulk phonons is usually described in terms of phonon scattering: defects are assumed to be static scattering centers and the properties of the defect-related SLMs modes are ignored. These dynamic properties of defects are important. In this paper, we quantify the concepts of vibrational localization and phonon trapping, distinguish between normal and anomalous decay of localized excitations, discuss the meaning of phonon scattering in real space at the atomic level, and illustrate the importance of phonon trapping in the case of heat flow at Si/Ge and Si/C interfaces.
Phononic crystals with one-dimensional defect as sensor materials
NASA Astrophysics Data System (ADS)
Aly, Arafa H.; Mehaney, Ahmed
2017-04-01
Recently, sensor technology has attracted great attention in many fields due to its importance in many engineering applications. In the present work, we introduce a study using the innovative properties of phononic crystals in enhancing a new type of sensors based on the intensity of transmitted frequencies inside the phononic band gaps. Based on the transfer matrix method and Bloch theory, the expressions of the reflection coefficient and dispersion relation are presented. Firstly, the influences of filling fraction ratio and the angle of incidence on the band gap width are discussed. Secondly, the localization of waves inside band gaps is discussed by enhancing the properties of the defected phononic crystal. Compared to the periodic structure, localization modes involved within the band structure of phononic crystals with one and two defect layers are presented and compared. Trapped localized modes can be detected easily and provide more information about defected structures. Such method could increase the knowledge of manufacturing defects by measuring the intensity of propagated waves in the resonant cavities and waveguides. Moreover, several factors enhance the role of the defect layer on the transmission properties of defected phononic crystals are presented. The acoustic band gap can be used to detect or sense the type of liquids filling the defect layer. The liquids make specific resonant modes through the phononic band gaps that related to the properties of each liquid. The frequency where the maximum resonant modes occur is correlated to material properties and allows to determine several parameters such as the type of an unknown material.
Phononic crystals with one-dimensional defect as sensor materials
NASA Astrophysics Data System (ADS)
Aly, Arafa H.; Mehaney, Ahmed
2017-09-01
Recently, sensor technology has attracted great attention in many fields due to its importance in many engineering applications. In the present work, we introduce a study using the innovative properties of phononic crystals in enhancing a new type of sensors based on the intensity of transmitted frequencies inside the phononic band gaps. Based on the transfer matrix method and Bloch theory, the expressions of the reflection coefficient and dispersion relation are presented. Firstly, the influences of filling fraction ratio and the angle of incidence on the band gap width are discussed. Secondly, the localization of waves inside band gaps is discussed by enhancing the properties of the defected phononic crystal. Compared to the periodic structure, localization modes involved within the band structure of phononic crystals with one and two defect layers are presented and compared. Trapped localized modes can be detected easily and provide more information about defected structures. Such method could increase the knowledge of manufacturing defects by measuring the intensity of propagated waves in the resonant cavities and waveguides. Moreover, several factors enhance the role of the defect layer on the transmission properties of defected phononic crystals are presented. The acoustic band gap can be used to detect or sense the type of liquids filling the defect layer. The liquids make specific resonant modes through the phononic band gaps that related to the properties of each liquid. The frequency where the maximum resonant modes occur is correlated to material properties and allows to determine several parameters such as the type of an unknown material.
Phonons in twisted bilayer graphene
NASA Astrophysics Data System (ADS)
Cocemasov, Alexandr I.; Nika, Denis L.; Balandin, Alexander A.
2013-07-01
We theoretically investigate phonon dispersion in AA-stacked, AB-stacked, and twisted bilayer graphene with various rotation angles. The calculations are performed using the Born-von Karman model for the intralayer atomic interactions and the Lennard-Jones potential for the interlayer interactions. It is found that the stacking order affects the out-of-plane acoustic phonon modes the most. The difference in the phonon densities of states in the twisted bilayer graphene and in AA- or AB-stacked bilayer graphene appears in the phonon frequency range 90-110 cm-1. Twisting bilayer graphene leads to the emergence of different phonon branches—termed hybrid folded phonons—which originate from the mixing of phonon modes from different high-symmetry directions in the Brillouin zone. The frequencies of the hybrid folded phonons depend strongly on the rotation angle and can be used for noncontact identification of the twist angles in graphene samples. The obtained results and the tabulated frequencies of phonons in twisted bilayer graphene are important for the interpretation of experimental Raman data and in determining the thermal conductivity of these material systems.
Jamaloo, Fatemeh; Mikaeili, Mohammad
2015-01-01
Common spatial pattern (CSP) is a method commonly used to enhance the effects of event-related desynchronization and event-related synchronization present in multichannel electroencephalogram-based brain-computer interface (BCI) systems. In the present study, a novel CSP sub-band feature selection has been proposed based on the discriminative information of the features. Besides, a distinction sensitive learning vector quantization based weighting of the selected features has been considered. Finally, after the classification of the weighted features using a support vector machine classifier, the performance of the suggested method has been compared with the existing methods based on frequency band selection, on the same BCI competitions datasets. The results show that the proposed method yields superior results on "ay" subject dataset compared against existing approaches such as sub-band CSP, filter bank CSP (FBCSP), discriminative FBCSP, and sliding window discriminative CSP.
NASA Astrophysics Data System (ADS)
Wang, Yan; Rademaker, Louk; Dagotto, Elbio; Johnston, Steven
2017-08-01
The discovery of an enhanced superconducting transition temperature Tc in monolayers of FeSe grown on several oxide substrates has opened a different route to high-Tc superconductivity through interface engineering. One proposal for the origin of the observed enhancement is an electron-phonon (e -ph) interaction across the interface that is peaked at small momentum transfers. In this paper, we examine the implications of such a coupling on the phononic properties of the system. We show that a strong forward scattering leads to a sizable broadening of phonon line shape, which may result in charge instabilities at long wavelengths. However, we further find that the inclusion of Coulombic screening significantly reduces the phonon broadening. Our results show that one might not expect anomalously broad phonon linewidths in the FeSe interface systems, despite the fact that the e -ph interaction has a strong peak in the forward-scattering (small q ) direction.
High resolution infrared spectroscopy of [1.1.1]propellane: The region of the ν_{9sub}> band
Maki, Arthur; Weber, Alfons; Nibler, Joseph W.; Masiello, Tony; Blake, Thomas A.; Kirkpatrick, Robynne
2010-11-01
The region of the infrared-active band of the ν_{9} CH2 bending mode [1.1.1]propellane has been recorded at a resolution (0.0025 cm^{-1}) sufficient to distinguish individual rovibrational lines. This region includes the partially overlapping bands ν_{9} (e') = 1459 cm^{-1}, 2ν_{18} (l = 2, E') = 1430 cm^{-1}, ν_{6} + ν_{12} (E') = 1489 cm-1, and ν_{4} + ν_{15} (A_{2}") = 1518 cm^{-1}. In addition, the difference band ν_{4} - ν_{15} (A2") was observed in the far infrared near 295 cm^{-1} and analyzed to give good constants for the upper ν_{4} levels. The close proximities of the four bands in the ν_{9} region suggest that Coriolis and Fermi resonance couplings could be significant and theoretical band parameters obtained from Gaussian ab initio calculations were helpful in guiding the band analyses. The analyses of all four bands were accomplished, based on our earlier report of ground state constants determined from combination differences involving more than 4000 pairs of transitions from five fundamental and four combination bands. This paper presents the analyses and the determination of the upper state constants of all four bands in the region of the ν_{9sub> band. Complications were most evident in the 2ν18 (l = 2, E') band, which showed significant perturbations due to mixing with the nearby 2ν18 (l = 0, A1') and ν4 + ν12 (E') levels which are either infrared inactive as transitions from the ground state, or, in the latter case, too weak to observe. Finally, these complications are discussed and a comparison of all molecular constants with those available from the ab initio calculations at the anharmonic level is presented.}
NASA Astrophysics Data System (ADS)
Wong, Joe
2004-03-01
The phonon spectra of plutonium and its alloys have been sought after in the past few decades following the discovery of this actinide element in 1941, but with no success. This was due to a combination of the high neutron absorption cross section of 239Pu, the common isotope, and non-availability of large single crystals of any Pu-bearing materials. We have recent designed a high resolution inelastic x-ray scattering experiment using a bright synchrotron x-ray beam at the European Sychrotron Radiation Facility (ESRF), Grenoble and mapped the full phonon dispersion curves of an fcc delta-phase polycrystalline Pu-Ga alloy (1). Several unusual features including, a large elastic anisotropy, a small shear elastic modulus C', a Kohn-like anomaly in the T1[011] branch, and a pronounced softening of the [111] transverse modes are found. These features can be related to the phase transitions of plutonium and to strong coupling between the lattice structure and the 5f valence instabilities. Our results also provide a critical test for theoretical treatments of highly correlated 5f electron systems as exemplified by recent dynamical mean field theory (DMFT) calculations for d-plutonium.(2) This work was performed in collaboration with Dr. M. Krisch (ESRF)) and Prof. T.-C. Chiang (UIU), and under the auspices of the U. S. Department of Energy by the University of California, Lawrence Livermore National Laboratory under Contract No. W-7405-Eng-48. 1. Joe Wong et al. Science, vol.301, 1078 (2003) 2. X. Dai et al. Science, vol.300, 953 (2003)
Phonon spectra of alkali metals
NASA Astrophysics Data System (ADS)
Zeković, S.; Vukajlović, F.; Veljković, V.
1982-10-01
In this work we used a simple local model pseudopotential which includes screening for the phonon spectra calculations of alkali metals. The results obtained are in very good agreement with experimental data. In some branches of phonon spectra the differences between theoretical and experimental results are within 1-2%, while the maximum error is about 6%. The suggested form of the pseudopotential allows us to describe the phonon spectra of Na, K and Rb with only one, and, at the same time, a unique, parameter. In this case, the maximum disagreements from experiment are 9% for Na, 8% for K and 7% for Rb.
Dynamical Cooper pairing in nonequilibrium electron-phonon systems
NASA Astrophysics Data System (ADS)
Knap, Michael; Babadi, Mehrtash; Refael, Gil; Martin, Ivar; Demler, Eugene
2016-12-01
We analyze Cooper pairing instabilities in strongly driven electron-phonon systems. The light-induced nonequilibrium state of phonons results in a simultaneous increase of the superconducting coupling constant and the electron scattering. We demonstrate that the competition between these effects leads to an enhanced superconducting transition temperature in a broad range of parameters. Our results may explain the observed transient enhancement of superconductivity in several classes of materials upon irradiation with high intensity pulses of terahertz light, and may pave new ways for engineering high-temperature light-induced superconducting states.
Dynamical Cooper pairing in nonequilibrium electron-phonon systems
Knap, Michael; Babadi, Mehrtash; Refael, Gil; Martin, Ivar; Demler, Eugene
2016-12-08
In this paper, we analyze Cooper pairing instabilities in strongly driven electron-phonon systems. The light-induced nonequilibrium state of phonons results in a simultaneous increase of the superconducting coupling constant and the electron scattering. We demonstrate that the competition between these effects leads to an enhanced superconducting transition temperature in a broad range of parameters. Finally, our results may explain the observed transient enhancement of superconductivity in several classes of materials upon irradiation with high intensity pulses of terahertz light, and may pave new ways for engineering high-temperature light-induced superconducting states.
Weak Coupling Electron-Phonon for High Tc Superconductors
NASA Astrophysics Data System (ADS)
Labbe, J.
1989-01-01
Our opinion is that, in the high Tc copper oxides, the electronic correlations are not large enough to allow the localization of the electrons of the half-filled d-p sub-band. Thus, we treat them as itinerant electrons, in a bidimensional structure. And we show that, contrary to a widely held opinion, the electron-phonon interaction can induce high Tc superconductivity in these compounds, even in the weak coupling limit. This is due to the fact that, because of the bidimensionality, the electronic density of states is sharply peaked in the neighbourhood of the Fermi energy. A small coupling between nearest neighbouring CuO2 planes is sufficient to prevent a very large reduction of Tc by the critical fluctuations. The calculated isotope effect is much smaller than usually in the BCS theory. And, in our weak coupling theory, the antiferromagnetic (AF) phase is much more rapidly destabilized by dopping or internal charge transfer than the superconducting phase, which takes place when the AF phase has vanished.
Hussein, Mahmoud I.; El-Kady, Ihab; Li, Baowen; ...
2014-12-31
“Phononics” is an interdisciplinary branch of physics and engineering that deals with the behavior of phonons, and more broadly elastic and acoustic waves in similar context, and their manipulation in solids and/or fluids to benefit technological applications. Compared to resembling disciplines, such as electronics and photonics, phononics is a youthful field. It is growing at a remarkable rate, especially when viewed liberally with no limiting constraints on any particular length scale, discipline or application.
Wong, Joe; Krisch, M.; Farber, D.; Occelli, F.; Schwartz, A.; Chiang, T.C.; Wall, M.; Boro, C.; Xu, Ruqing
2010-11-16
Plutonium (Pu) is well known to have complex and unique physico-chemical properties. Notably, the pure metal exhibits six solid-state phase transformations with large volume expansions and contractions along the way to the liquid state: {alpha} {yields} {beta} {yields} {gamma} {yields} {delta} {yields} {delta}{prime} {yields} {var_epsilon} {yields} liquid. Unalloyed Pu melts at a relatively low temperature {approx}640 C to yield a higher density liquid than that of the solid from which it melts, (Figure 1). Detailed understanding of the properties of plutonium and plutonium-based alloys is critical for the safe handling, utilization, and long-term storage of these important, but highly toxic materials. However, both technical and and safety issues have made experimental observations extremely difficult. Phonon dispersion curves (PDCs) are key experimenta l data to the understanding of the basic properties of Pu materials such as: force constants, sound velocities, elastic constants, thermodynamics, phase stability, electron-phonon coupling, structural relaxation, etc. However, phonon dispersion curves (PDCs) in plutonium (Pu) and its alloys have defied measurement for the past few decades since the discovery of this element in 1941. This is due to a combination of the high thermal-neutron absorption cross section of plutonium and the inability to grow the large single crystals (with dimensions of a few millimeters) necessary for inelastic neutron scattering. Theoretical simulations of the Pu PDC continue to be hampered by the lack of suitable inter -atomic potentials. Thus, until recently the PDCs for Pu and its alloys have remained unknown experimentally and theoretically. The experimental limitations have recently been overcome by using a tightly focused undulator x-ray micro-beam scattered from single -grain domains in polycrystalline specimens. This experimental approach has been applied successfully to map the complete PDCs of an fcc d-Pu-Ga alloy using the
Phonons with orbital angular momentum
Ayub, M. K.; Ali, S.; Mendonca, J. T.
2011-10-15
Ion accoustic waves or phonon modes are studied with orbital angular momentum (OAM) in an unmagnetized collissionless uniform plasma, whose constituents are the Boltzmann electrons and inertial ions. For this purpose, we have employed the fluid equations to obtain a paraxial equation in terms of ion density perturbations and discussed its Gaussian beam and Laguerre-Gauss (LG) beam solutions. Furthermore, an approximate solution for the electrostatic potential problem is presented, allowing to express the components of the electric field in terms of LG potential perturbations. The energy flux due to phonons is also calculated and the corresponding OAM is derived. Numerically, it is shown that the parameters such as azimuthal angle, radial and angular mode numbers, and beam waist, strongly modify the profiles of the phonon LG potential. The present results should be helpful in understanding the phonon mode excitations produced by Brillouin backscattering of laser beams in a uniform plasma.
Phonon dynamics of neptunium chalcogenides
NASA Astrophysics Data System (ADS)
Aynyas, Mahendra; Rukmangad, Aditi; Arya, Balwant S.; Sanyal, Sankar P.
2012-06-01
We have performed phonon calculations of Neptunium Chalcogenides (NpX) (X= S, Se, Te) based on breathing shell model (BSM) which includes breathing motion of electron of the Np-atoms due to f-d hybridization. The model predicts that the short range breathing phenomenon play a dominant role in the phonon properties. We also report, for the first time specific heat for these compounds.
Scattering Tools for Nanostructure Phonon Engineering
2013-09-25
from the original buckled membrane. Figure 0-4: Schematic of the undercutting and edge induced flattening mechanism . (a) Schematic of flattening...Arlington, VA 22203 AFOSR The vibrational properties of solids have crucial roles underpinning functional properties ranging from thermal conductivity...to electron mobility. It has long been known that the modification of the mechanical boundary conditions imposed by the minimal spatial extent of
Coherent phonon control via electron-lattice interaction in ferromagnetic Co/Pt multilayers
Kim, Chul Hoon; Shim, Je-Ho; Lee, Kyung Min; Jeong, Jong-Ryul; Kim, Dong-Hyun; Kim, Dong Eon
2016-01-01
The manipulation of coherent phonons in condensed systems has attracted fundamental interest, particularly for its applications to future devices. We demonstrate that a coherent phonon in Co/Pt nano-multilayer can be quantitatively controlled via electron-lattice coupling, specifically by changing the multilayer repeat number. To that end, systematic measurement of the time-resolved reflectivity and magneto-optical Kerr effect in Co/Pt multilayers was performed. The coherent phonon frequency was observed to be shifted with the change of the multilayer repeat number. This shift could be clearly explained based on the two-temperature model. Detailed analysis indicated that the lattice heat capacity and electron-lattice coupling strength are linearly dependent on the repeat number of the periodic multilayer structures. Accessing the control of coherent phonons using nanostructures opens a new avenue for advanced phonon-engineering applications. PMID:26928846
Phonons and thermal transport in graphene and graphene-based materials.
Nika, Denis L; Balandin, Alexander A
2017-03-01
A discovery of the unusual thermal properties of graphene stimulated experimental, theoretical and computational research directed at understanding phonon transport and thermal conduction in two-dimensional material systems. We provide a critical review of recent results in the graphene thermal field focusing on phonon dispersion, specific heat, thermal conductivity, and comparison of different models and computational approaches. The correlation between the phonon spectrum in graphene-based materials and the heat conduction properties is analyzed in details. The effects of the atomic plane rotations in bilayer graphene, isotope engineering, and relative contributions of different phonon dispersion branches are discussed. For readers' convenience, the summaries of main experimental and theoretical results on thermal conductivity as well as phonon mode contributions to thermal transport are provided in the form of comprehensive annotated tables.
Phonons and thermal transport in graphene and graphene-based materials
NASA Astrophysics Data System (ADS)
Nika, Denis L.; Balandin, Alexander A.
2017-03-01
A discovery of the unusual thermal properties of graphene stimulated experimental, theoretical and computational research directed at understanding phonon transport and thermal conduction in two-dimensional material systems. We provide a critical review of recent results in the graphene thermal field focusing on phonon dispersion, specific heat, thermal conductivity, and comparison of different models and computational approaches. The correlation between the phonon spectrum in graphene-based materials and the heat conduction properties is analyzed in details. The effects of the atomic plane rotations in bilayer graphene, isotope engineering, and relative contributions of different phonon dispersion branches are discussed. For readers’ convenience, the summaries of main experimental and theoretical results on thermal conductivity as well as phonon mode contributions to thermal transport are provided in the form of comprehensive annotated tables.
Modification of phonon processes in nanostructured rare-earth-ion-doped crystals
NASA Astrophysics Data System (ADS)
Lutz, Thomas; Veissier, Lucile; Thiel, Charles W.; Cone, Rufus L.; Barclay, Paul E.; Tittel, Wolfgang
2016-07-01
Nano-structuring impurity-doped crystals affects the phonon density of states and thereby modifies the atomic dynamics induced by interaction with phonons. We propose the use of nano-structured materials in the form of powders or phononic bandgap crystals to enable or improve persistent spectral hole burning and coherence for inhomogeneously broadened absorption lines in rare-earth-ion-doped crystals. This is crucial for applications such as ultra-precise radio-frequency spectrum analyzers and optical quantum memories. As an example, we discuss how phonon engineering can enable spectral hole burning in erbium-doped materials operating in the convenient telecommunication band and present simulations for density of states of nano-sized powders and phononic crystals for the case of Y2SiO5 , a widely used material in current quantum memory research.
NASA Astrophysics Data System (ADS)
Hong, Jiawang; Li, Chen W.; May, A. F.; Bansal, D.; Chi, S.; Hong, T.; Ehlers, G.; Delaire, Olivier
The promising thermoelectric material SnSe exhibits ultra-low and strongly anisotropic thermal conductivity. By combining first-principles calculations and inelastic neutron scattering measurements, we have investigated the phonon dispersions and phonon scattering mechanisms, and probed the origin of the large anharmonicity in SnSe. We will discuss the connection between the phonon properties and the high-temperature structural phase transition, and how the electronic structure leads to large anharmonic phonon interactions in SnSe. The present results provide a microscopic picture connecting electronic structure and phonon anharmonicity in SnSe, which could help design materials with ultralow thermal conductivity. Computations were performed using the OLCF at ORNL. Modeling of neutron data was performed in CAMM, measurements were funded by the US DOE, BES, Materials Science and Engineering Division.
Malekiha, Mahdi; Tselniker, Igor; Nazarathy, Moshe; Tolmachev, Alex; Plant, David V
2015-10-05
We experimentally demonstrate a novel digital signal processing (DSP) structure for reduced guard-interval (RGI) OFDM coherent optical systems. The proposed concept is based on digitally slicing optical channel bandwidth into multiple spectrally disjoint sub-bands which are then processed in parallel. Each low bandwidth sub-band has a smaller delay-spread compared to a full-band signal. This enables compensation of both chromatic dispersion (CD) and polarization mode dispersion using a simple timing and one-tap-per-symbol frequency domain equalizer with a small cyclic prefix overhead. In terms of the DSP architecture, this allows for a highly efficient parallelization of DSP tasks performed over the received signal samples by deploying multiple processors running at a lower clock rate. It should be noted that this parallelization is performed in the frequency domain and it allows for flexible optical transceiver schemes. In addition, the resulting optical receiver is simplified due to the removal of the CD compensation equalizer compared to conventional RGI-OFDM systems. In this paper we experimentally demonstrate digital sub-banding of optical bandwidth. We test the system performance for different modulation formats (QPSK, 16QAM and 32QAM) over various transmission distances and optical launch powers using a 1.5% CP overhead in all scenarios. We also compare the proposed RGI-OFDM architecture performance against common single carrier modulation formats. At the same total data rate and signal bandwidth both systems have similar performance and transmission reach whereas the proposed method allows for a significant reduction of computational complexity due to removal of CD pre/post compensation equalizer.
Yater, J. E. Shaw, J. L.; Pate, B. B.; Feygelson, T. I.
2016-02-07
Secondary-electron-emission (SEE) current measured from high-purity, single-crystal (100) chemical-vapor-deposited diamond is found to increase when sub-band gap (3.06 eV) photons are incident on the hydrogenated surface. Although the light does not produce photoemission directly, the SEE current increases by more than a factor of 2 before saturating with increasing laser power. In energy distribution curves (EDCs), the emission peak shows a corresponding increase in intensity with increasing laser power. However, the emission-onset energy in the EDCs remains constant, indicating that the bands are pinned at the surface. On the other hand, changes are observed on the high-energy side of the distribution as the laser power increases, with a well-defined shoulder becoming more pronounced. From an analysis of this feature in the EDCs, it is deduced that upward band bending is present in the near-surface region during the SEE measurements and this band bending suppresses the SEE yield. However, sub-band gap photon illumination reduces the band bending and thereby increases the SEE current. Because the bands are pinned at the surface, we conclude that the changes in the band levels occur below the surface in the electron transport region. Sample heating produces similar effects as observed with sub-band gap photon illumination, namely, an increase in SEE current and a reduction in band bending. However, the upward band bending is not fully removed by either increasing laser power or temperature, and a minimum band bending of ∼0.8 eV is established in both cases. The sub-band gap photo-excitation mechanism is under further investigation, although it appears likely at present that defect or gap states play a role in the photo-enhanced SEE process. In the meantime, the study demonstrates the ability of visible light to modify the electronic properties of diamond and enhance the emission capabilities, which may have potential impact for diamond-based vacuum electron
NASA Astrophysics Data System (ADS)
Yater, J. E.; Shaw, J. L.; Pate, B. B.; Feygelson, T. I.
2016-02-01
Secondary-electron-emission (SEE) current measured from high-purity, single-crystal (100) chemical-vapor-deposited diamond is found to increase when sub-band gap (3.06 eV) photons are incident on the hydrogenated surface. Although the light does not produce photoemission directly, the SEE current increases by more than a factor of 2 before saturating with increasing laser power. In energy distribution curves (EDCs), the emission peak shows a corresponding increase in intensity with increasing laser power. However, the emission-onset energy in the EDCs remains constant, indicating that the bands are pinned at the surface. On the other hand, changes are observed on the high-energy side of the distribution as the laser power increases, with a well-defined shoulder becoming more pronounced. From an analysis of this feature in the EDCs, it is deduced that upward band bending is present in the near-surface region during the SEE measurements and this band bending suppresses the SEE yield. However, sub-band gap photon illumination reduces the band bending and thereby increases the SEE current. Because the bands are pinned at the surface, we conclude that the changes in the band levels occur below the surface in the electron transport region. Sample heating produces similar effects as observed with sub-band gap photon illumination, namely, an increase in SEE current and a reduction in band bending. However, the upward band bending is not fully removed by either increasing laser power or temperature, and a minimum band bending of ˜0.8 eV is established in both cases. The sub-band gap photo-excitation mechanism is under further investigation, although it appears likely at present that defect or gap states play a role in the photo-enhanced SEE process. In the meantime, the study demonstrates the ability of visible light to modify the electronic properties of diamond and enhance the emission capabilities, which may have potential impact for diamond-based vacuum electron
NASA Astrophysics Data System (ADS)
Chen, Gang
In this talk, we will discuss different modes of heat conduction in nanostructures. Ballistic transport happens when phonon mean free path is longer than the characteristic size of the structure. We will discuss how we compute phonon mean free path distributions based on first-principles and measure the distributions with optical pump-probe techniques by exploring ballistic phonon transport processes. In superlattice structures, ballistic phonon transport across the whole thickness of the superlattices implies phase coherence. We observed this coherent transport in GaAs/AlAs superlattices with fixed periodic thickness and varying number of periods. Simulations show that although high frequency phonons are scattering by roughness, remaining long wavelength phonons maintain their phase and traverse the superlattices ballistically. Accessing the coherent heat conduction regime opens a new venue for phonon engineering. We show further that phonon heat conduction localization happens in GaAs/AlAs superlattice by placing ErAs nanodots at interfaces. This heat-conduction localization phenomenon is confirmed by nonequilibrium atomic Green's function simulation. These ballistic and localization effects can be exploited to improve thermoelectric energy conversion materials via reducing their thermal conductivity. In another opposite, we will discuss phonon hydrodynamic transport mode in graphene via first-principle simulations. In this mode, phonons drift with an average velocity under a temperature gradient, similar to fluid flow in a pipe. Conditions for observing such phonon hydrodynamic modes will be discussed. Finally, we will talk about the one-dimensional nature of heat conduction in polymer chains. Such 1D nature can lead to divergent thermal conductivity. Inspired by simulation, we have experimentally demonstrated high thermal conductivity in ultra-drawn polyethylene nanofibers and sheets. Work supported by DOE Office of Basic Energy Sciences under Award Number: DE
NASA Astrophysics Data System (ADS)
Banerjee, Debika; Trudeau, Charles; Gerlein, Luis Felipe; Cloutier, Sylvain G.
2016-03-01
The nanoscale engineering of silicon can significantly change its bulk optoelectronic properties to make it more favorable for device integration. Phonon process engineering is one way to enhance inter-band transitions in silicon's indirect band structure alignment. This paper demonstrates phonon localization at the tip of silicon nanowires fabricated by galvanic displacement using wet electroless chemical etching of a bulk silicon wafer. High-resolution Raman micro-spectroscopy reveals that such arrayed structures of silicon nanowires display phonon localization behaviors, which could help their integration into the future generations of nano-engineered silicon nanowire-based devices such as photodetectors and solar cells.
Phonons in active microfluidic crystals
NASA Astrophysics Data System (ADS)
Tsang, Alan Cheng Hou; Kanso, Eva
2016-11-01
One-dimensional crystals of driven particles confined in quasi two-dimensional microfluidic channels have been shown to exhibit propagating sound waves in the form of 'phonons', including both transverse and longitudinal normal modes. Here, we focus on one-dimensional crystals of motile particles in uniform external flows. We study the propagation of phonons in the context of an idealized model that accounts for hydrodynamic interactions among the motile particles. We obtain a closed-form analytical expression for the dispersion relation of the phonons. In the moving frame of reference of the crystals, the traveling directions of the phonons depend on the intensity of the external flow, and are exactly opposite for the transverse and longitudinal modes. We further investigate the stability of the phonons and show that the longitudinal mode is linearly stable, whereas the transverse mode is subject to an instability arising from the activity and orientation dynamics of the motile particles. These findings are important for understanding the propagation of disturbances and instabilities in confined motile particles, and could generate practical insights into the transport of motile cells in microfluidic devices.
Unified phonon-based approach to the thermodynamics of solid, liquid and gas states
NASA Astrophysics Data System (ADS)
Bolmatov, Dima; Zav'yalov, Dmitry; Zhernenkov, Mikhail; Musaev, Edvard T.; Cai, Yong Q.
2015-12-01
We introduce a unified approach to states of matter (solid, liquid and gas) and describe the thermodynamics of the pressure-temperature phase diagram in terms of phonon excitations. We derive the effective Hamiltonian with low-energy cutoff in two transverse phonon polarizations (phononic band gaps) by breaking the symmetry in phonon interactions. Further, we construct the statistical mechanics of states of aggregation employing the Debye approximation. The introduced formalism covers the Debye theory of solids, the phonon theory of liquids, and thermodynamic limits such as the Dulong-Petit thermodynamic limit (cV = 3kB), the ideal gas limit (cV =3/2 kB) and the new thermodynamic limit (cV = 2kB), dubbed here the Frenkel line thermodynamic limit. We discuss the phonon propagation and localization effects in liquids above and below the Frenkel line, and explain the "fast sound" phenomenon. As a test for our theory we calculate velocity-velocity autocorrelation and pair distribution functions within the Green-Kubo formalism. We show the consistency between dynamics of phonons and pair correlations in the framework of the unified approach. New directions towards advancements in phononic band gaps engineering, hypersound manipulation technologies and exploration of exotic behaviour of fluids relevant to geo- and planetary sciences are discussed. The presented results are equally important both for practical implications and for fundamental research.
NASA Astrophysics Data System (ADS)
Yang, Jia-Yue; Qin, Guangzhao; Hu, Ming
2016-12-01
The macroscopic thermal transport is fundamentally determined by the intrinsic interactions among microscopic electrons and phonons. In conventional insulators and semiconductors, phonons dominate the thermal transport, and the contribution of electron-phonon interaction (EPI) is negligible. However, in polar semiconductors, the Fröhlich electron-phonon coupling is strong and its influence on phononic thermal transport is of great significance. In this work, the effect of EPI on phonon dispersion and lattice thermal conductivity of wurtzite gallium nitride (GaN) is comprehensively investigated from the atomistic level by performing first-principles calculations. Due to the existence of relatively large electronegativity difference between Ga and N atoms, the Fröhlich coupling in wurtzite GaN is remarkably strong. Consequently, the lattice thermal conductivity of natural wurtzite GaN at room temperature is reduced by ˜24%-34% when including EPI, and the resulted thermal conductivity value is in better agreement with experiments. Furthermore, the scattering rate of phonons due to EPI, the intrinsic phonon-phonon interaction (PPI) as well as isotope disorder is computed and analyzed. It shows that the EPI scattering rate is comparable to PPI for low-frequency heat-carrying phonons. This work attempts to explore the mechanism of thermal transport beyond intrinsic PPI for polar semiconductors, with a great potential of thermal conductivity engineering for desired performance.
Phonon bottleneck identification in disordered nanoporous materials
NASA Astrophysics Data System (ADS)
Romano, Giuseppe; Grossman, Jeffrey C.
2017-09-01
Nanoporous materials are a promising platform for thermoelectrics in that they offer high thermal conductivity tunability while preserving good electrical properties, a crucial requirement for high-efficiency thermal energy conversion. Understanding the impact of the pore arrangement on thermal transport is pivotal to engineering realistic materials, where pore disorder is unavoidable. Although there has been considerable progress in modeling thermal size effects in nanostructures, it has remained a challenge to screen such materials over a large phase space due to the slow simulation time required for accurate results. We use density functional theory in connection with the Boltzmann transport equation to perform calculations of thermal conductivity in disordered porous materials. By leveraging graph theory and regressive analysis, we identify the set of pores representing the phonon bottleneck and obtain a descriptor for thermal transport, based on the sum of the pore-pore distances between such pores. This approach provide a simple tool to estimate phonon suppression in realistic porous materials for thermoelectric applications and enhance our understanding of heat transport in disordered materials.
Detecting phonon blockade with photons
Didier, Nicolas; Pugnetti, Stefano; Fazio, Rosario; Blanter, Yaroslav M.
2011-08-01
Measuring the quantum dynamics of a mechanical system, when few phonons are involved, remains a challenge. We show that a superconducting microwave resonator linearly coupled to the mechanical mode constitutes a very powerful probe for this scope. This new coupling can be much stronger than the usual radiation pressure interaction by adjusting a gate voltage. We focus on the detection of phonon blockade, showing that it can be observed by measuring the statistics of the light in the cavity. The underlying reason is the formation of an entangled state between the two resonators. Our scheme realizes a phonotonic Josephson junction, giving rise to coherent oscillations between phonons and photons as well as a self-trapping regime for a coupling smaller than a critical value. The transition from the self-trapping to the oscillating regime is also induced dynamically by dissipation.
Wave phenomena in phononic crystals
NASA Astrophysics Data System (ADS)
Sukhovich, Alexey
Novel wave phenomena in two- and three-dimensional (2D and 3D) phononic crystals were investigated experimentally using ultrasonic techniques. These ultrasonic techniques allow the full wave field to be imaged directly, which is a considerable advantage in fundamental studies of wave propagation in periodic media. Resonant tunnelling of ultrasonic waves was successfully observed for the first time by measuring the transmission of ultrasound pulses through a double barrier consisting of two 3D phononic crystals separated by a cavity. This effect is the classical analogue of resonant tunnelling of a quantum mechanical particle through a double potential barrier, in which transmission reaches unity at resonant frequencies. For phononic crystals, the tunnelling peak was found to be less than unity, an effect that was explained by absorption. Absorption introduces a small propagating component inside the crystals in addition to the dominant evanescent mode at band gap frequencies, and causes leakage of the pulse from the cavity. The dynamics of resonant tunnelling was explored by measuring the group velocities of the ultrasonic pulses. Very slow and very fast velocities were found at frequencies close to and at the resonance, respectively. These extreme values are less than the speed of sound in air and greater than the speed of sound in any of the crystal's constituent materials. Negative refraction and focusing effects in 2D phononic crystals were also observed. Negative refraction of ultrasound was demonstrated unambiguously in a prism-shaped 2D crystal at frequencies in the 2nd pass band, where the equifrequency contours are circular so that the wave vector and group velocity are antiparallel. The Multiple Scattering Theory and Snell's law allowed theoretical predictions of the refraction angles. Excellent agreement was found between theory and experiment. The negative refraction experiments revealed a mechanism that can be used to focus ultrasound using a flat
Phonon dynamics of americium telluride
NASA Astrophysics Data System (ADS)
Arya, B. S.; Aynyas, Mahendra; Ahirwar, Ashok K.; Sanyal, S. P.
2013-06-01
We report for the first time the complete phonon dispersion curves for Americium telluride (AmTe) using a breathing shell models (BSM) to establish their predominant ionic nature. The results obtained in the present study show the general features of the phonon spectrum. We could not compare our results with the experimental measurements as they are not available so far. We emphasize the need of neutron scattering measurements to compare our results. We also report, for the first time specific heat for this compound.
Phonon creation by gravitational waves
NASA Astrophysics Data System (ADS)
Sabín, Carlos; Bruschi, David Edward; Ahmadi, Mehdi; Fuentes, Ivette
2014-08-01
We show that gravitational waves create phonons in a Bose-Einstein condensate (BEC). A traveling spacetime distortion produces particle creation resonances that correspond to the dynamical Casimir effect in a BEC phononic field contained in a cavity-type trap. We propose to use this effect to detect gravitational waves. The amplitude of the wave can be estimated applying recently developed relativistic quantum metrology techniques. We provide the optimal precision bound on the estimation of the wave's amplitude. Finally, we show that the parameter regime required to detect gravitational waves with this technique could be, in principle, within experimental reach in a medium-term timescale.
Scattering of phonons by vacancies
Ratsifaritana, C.A.; Klemens, P.G.
1987-11-01
The scattering of phonons by vacancies is estimated by a perturbation technique in terms of the missing mass and the missing linkages. An argument is given why distortion effects can be disregarded. The resonance frequency of the defect is sufficiently high so that resonance effects can be disregarded for phonons in the important frequency range for thermal conduction. The theory is applied to the thermal resistance by vacancies in cases where the vacancy concentration is known: potassium chloride with divalent cations, nonstoichiometric zirconium carbide, and tin telluride.
Optimizing phonon space in the phonon-coupling model
NASA Astrophysics Data System (ADS)
Tselyaev, V.; Lyutorovich, N.; Speth, J.; Reinhard, P.-G.
2017-08-01
We present a new scheme to select the most relevant phonons in the phonon-coupling model, named here the time-blocking approximation (TBA). The new criterion, based on the phonon-nucleon coupling strengths rather than on B (E L ) values, is more selective and thus produces much smaller phonon spaces in the TBA. This is beneficial in two respects: first, it curbs the computational cost, and second, it reduces the danger of double counting in the expansion basis of the TBA. We use here the TBA in a form where the coupling strength is regularized to keep the given Hartree-Fock ground state stable. The scheme is implemented in a random-phase approximation and TBA code based on the Skyrme energy functional. We first explore carefully the cutoff dependence with the new criterion and can work out a natural (optimal) cutoff parameter. Then we use the freshly developed and tested scheme for a survey of giant resonances and low-lying collective states in six doubly magic nuclei looking also at the dependence of the results when varying the Skyrme parametrization.
Cavity-type hypersonic phononic crystals
NASA Astrophysics Data System (ADS)
Sato, A.; Pennec, Y.; Yanagishita, T.; Masuda, H.; Knoll, W.; Djafari-Rouhani, B.; Fytas, G.
2012-11-01
We report on the engineering of the phonon dispersion diagram in monodomain anodic porous alumina (APA) films through the porosity and physical state of the material residing in the nanopores. Lattice symmetry and inclusion materials are theoretically identified to be the main factors which control the hypersonic acoustic wave propagation. This involves the interaction between the longitudinal and the transverse modes in the effective medium and a flat band characteristic of the material residing in the cavities. Air and filled nanopores, therefore, display markedly different dispersion relations and the inclusion materials lead to a locally resonant structural behavior uniquely determining their properties under confinement. APA films emerge as a new platform to investigate the rich acoustic phenomena of structured composite matter.
Sound and heat revolutions in phononics.
Maldovan, Martin
2013-11-14
The phonon is the physical particle representing mechanical vibration and is responsible for the transmission of everyday sound and heat. Understanding and controlling the phononic properties of materials provides opportunities to thermally insulate buildings, reduce environmental noise, transform waste heat into electricity and develop earthquake protection. Here I review recent progress and the development of new ideas and devices that make use of phononic properties to control both sound and heat. Advances in sonic and thermal diodes, optomechanical crystals, acoustic and thermal cloaking, hypersonic phononic crystals, thermoelectrics, and thermocrystals herald the next technological revolution in phononics.
Nanoscale control of phonon excitations in graphene
Kim, Hyo Won; Ko, Wonhee; Ku, JiYeon; Jeon, Insu; Kim, Donggyu; Kwon, Hyeokshin; Oh, Youngtek; Ryu, Seunghwa; Kuk, Young; Hwang, Sung Woo; Suh, Hwansoo
2015-01-01
Phonons, which are collective excitations in a lattice of atoms or molecules, play a major role in determining various physical properties of condensed matter, such as thermal and electrical conductivities. In particular, phonons in graphene interact strongly with electrons; however, unlike in usual metals, these interactions between phonons and massless Dirac fermions appear to mirror the rather complicated physics of those between light and relativistic electrons. Therefore, a fundamental understanding of the underlying physics through systematic studies of phonon interactions and excitations in graphene is crucial for realising graphene-based devices. In this study, we demonstrate that the local phonon properties of graphene can be controlled at the nanoscale by tuning the interaction strength between graphene and an underlying Pt substrate. Using scanning probe methods, we determine that the reduced interaction due to embedded Ar atoms facilitates electron–phonon excitations, further influencing phonon-assisted inelastic electron tunnelling. PMID:26109454
Isotope scattering and phonon thermal conductivity in light atom compounds: LiH and LiF
Lindsay, Lucas R.
2016-11-08
Engineered isotope variation is a pathway toward modulating lattice thermal conductivity (κ) of a material through changes in phonon-isotope scattering. The effects of isotope variation on intrinsic thermal resistance is little explored, as varying isotopes have relatively small differences in mass and thus do not affect bulk phonon dispersions. However, for light elements isotope mass variation can be relatively large (e.g., hydrogen and deuterium). Using a first principles Peierls-Boltzmann transport equation approach the effects of isotope variance on lattice thermal transport in ultra-low-mass compound materials LiH and LiF are characterized. The isotope mass variance modifies the intrinsic thermal resistance viamore » modulation of acoustic and optic phonon frequencies, while phonon-isotope scattering from mass disorder plays only a minor role. This leads to some unusual cases where values of isotopically pure systems (6LiH, 7Li2H and 6LiF) are lower than the values from their counterparts with naturally occurring isotopes and phonon-isotope scattering. However, these differences are relatively small. The effects of temperature-driven lattice expansion on phonon dispersions and calculated κ are also discussed. This work provides insight into lattice thermal conductivity modulation with mass variation and the interplay of intrinsic phonon-phonon and phonon-isotope scattering in interesting light atom systems.« less
Isotope scattering and phonon thermal conductivity in light atom compounds: LiH and LiF
Lindsay, Lucas R.
2016-11-08
Engineered isotope variation is a pathway toward modulating lattice thermal conductivity (κ) of a material through changes in phonon-isotope scattering. The effects of isotope variation on intrinsic thermal resistance is little explored, as varying isotopes have relatively small differences in mass and thus do not affect bulk phonon dispersions. However, for light elements isotope mass variation can be relatively large (e.g., hydrogen and deuterium). Using a first principles Peierls-Boltzmann transport equation approach the effects of isotope variance on lattice thermal transport in ultra-low-mass compound materials LiH and LiF are characterized. The isotope mass variance modifies the intrinsic thermal resistance via modulation of acoustic and optic phonon frequencies, while phonon-isotope scattering from mass disorder plays only a minor role. This leads to some unusual cases where values of isotopically pure systems (^{6}LiH, ^{7}Li^{2}H and ^{6}LiF) are lower than the values from their counterparts with naturally occurring isotopes and phonon-isotope scattering. However, these differences are relatively small. The effects of temperature-driven lattice expansion on phonon dispersions and calculated κ are also discussed. This work provides insight into lattice thermal conductivity modulation with mass variation and the interplay of intrinsic phonon-phonon and phonon-isotope scattering in interesting light atom systems.
A holographic perspective on phonons and pseudo-phonons
NASA Astrophysics Data System (ADS)
Amoretti, Andrea; Areán, Daniel; Argurio, Riccardo; Musso, Daniele; Zayas, Leopoldo A. Pando
2017-05-01
We analyze the concomitant spontaneous breaking of translation and conformal symmetries by introducing in a CFT a complex scalar operator that acquires a spatially dependent expectation value. The model, inspired by the holographic Q-lattice, provides a privileged setup to study the emergence of phonons from a spontaneous translational symmetry breaking in a conformal field theory and offers valuable hints for the treatment of phonons in QFT at large. We first analyze the Ward identity structure by means of standard QFT techniques, considering both spontaneous and explicit symmetry breaking. Next, by implementing holographic renormalization, we show that the same set of Ward identities holds in the holographic Q-lattice. Eventually, relying on the holographic and QFT results, we study the correlators realizing the symmetry breaking pattern and how they encode information about the low-energy spectrum.
NASA Astrophysics Data System (ADS)
Feng, Tianli; Ruan, Xiulin; Ye, Zhenqiang; Cao, Bingyang
2015-06-01
The spectral phonon properties in defected graphene have been unclear due to the lack of advanced techniques for predicting the phonon-defect scattering rate without fitting parameters. Taking advantage of the extended phonon normal mode analysis, we obtained the spectral phonon relaxation time and mean free path (MFP) in defected graphene and studied the impacts of three common types of defects: Stone-Thrower-Wales (STW) defect, double vacancy (DV), and monovacancy (MV). The phonon-STW defect scattering rate is found to have no significant frequency dependence, and as a result, the relative contribution of long-wavelength phonons sharply decreases. In contrast, the phonon scattering by DVs or MVs exhibits a frequency dependence of τp-d -1˜ω1.1 -1.3 except for a few long-wavelength phonons, revisiting the traditionally used ˜ω4 dependence. We note that although MV-defected graphene has the lowest thermal conductivity as compared to the other two defected graphene samples at the same defect concentration, it has a portion of phonons with the longest MFP. The contribution from the long-MFP and long-wavelength phonons does not decrease much as the vacancy concentration increases. STW defect and MV block more out-of-plane modes than in-plane modes, while DV has less bias for which mode to block. As the MV concentration increases from 0 to 1.1%, the relative contribution from out-of-plane modes decreases from 30% to 18%, while that of the transverse acoustic mode remains at around 30%. These findings of spectral phonon properties can provide more insight than the effective properties and benefit the prospective phononic engineering.
Phonon assisted resonant tunneling and its phonons control
NASA Astrophysics Data System (ADS)
Kusmartsev, F. V.; Krevchik, V. D.; Semenov, M. B.; Filatov, D. O.; Shorokhov, A. V.; Bukharaev, A. A.; Dakhnovsky, Y.; Nikolaev, A. V.; Pyataev, N. A.; Zaytsev, R. V.; Krevchik, P. V.; Egorov, I. A.; Yamamoto, K.; Aringazin, A. K.
2016-09-01
We observe a series of sharp resonant features in the tunneling differential conductance of InAs quantum dots. We found that dissipative quantum tunneling has a strong influence on the operation of nanodevices. Because of such tunneling the current-voltage characteristics of tunnel contact created between atomic force microscope tip and a surface of InAs/GaAs quantum dots display many interesting peaks. We found that the number, position, and heights of these peaks are associated with the phonon modes involved. To describe the found effect we use a quasi-classical approximation. There the tunneling current is related to a creation of a dilute instanton-anti-instanton gas. Our experimental data are well described with exactly solvable model where one charged particle is weakly interacting with two promoting phonon modes associated with external medium. We conclude that the characteristics of the tunnel nanoelectronic devices can thus be controlled by a proper choice of phonons existing in materials, which are involved.
Edge phonons in black phosphorus
Ribeiro, H. B.; Villegas, C. E. P.; Bahamon, D. A.; Muraca, D.; Castro Neto, A. H.; de Souza, E. A. T.; Rocha, A. R.; Pimenta, M. A.; de Matos, C. J. S.
2016-01-01
Black phosphorus has recently emerged as a new layered crystal that, due to its peculiar and anisotropic crystalline and electronic band structures, may have important applications in electronics, optoelectronics and photonics. Despite the fact that the edges of layered crystals host a range of singular properties whose characterization and exploitation are of utmost importance for device development, the edges of black phosphorus remain poorly characterized. In this work, the atomic structure and behaviour of phonons near different black phosphorus edges are experimentally and theoretically studied using Raman spectroscopy and density functional theory calculations. Polarized Raman results show the appearance of new modes at the edges of the sample, and their spectra depend on the atomic structure of the edges (zigzag or armchair). Theoretical simulations confirm that the new modes are due to edge phonon states that are forbidden in the bulk, and originated from the lattice termination rearrangements. PMID:27412813
Edge phonons in black phosphorus
NASA Astrophysics Data System (ADS)
Ribeiro, H. B.; Villegas, C. E. P.; Bahamon, D. A.; Muraca, D.; Castro Neto, A. H.; de Souza, E. A. T.; Rocha, A. R.; Pimenta, M. A.; de Matos, C. J. S.
2016-07-01
Black phosphorus has recently emerged as a new layered crystal that, due to its peculiar and anisotropic crystalline and electronic band structures, may have important applications in electronics, optoelectronics and photonics. Despite the fact that the edges of layered crystals host a range of singular properties whose characterization and exploitation are of utmost importance for device development, the edges of black phosphorus remain poorly characterized. In this work, the atomic structure and behaviour of phonons near different black phosphorus edges are experimentally and theoretically studied using Raman spectroscopy and density functional theory calculations. Polarized Raman results show the appearance of new modes at the edges of the sample, and their spectra depend on the atomic structure of the edges (zigzag or armchair). Theoretical simulations confirm that the new modes are due to edge phonon states that are forbidden in the bulk, and originated from the lattice termination rearrangements.
Phononic crystals of poroelastic spheres
NASA Astrophysics Data System (ADS)
Alevizaki, A.; Sainidou, R.; Rembert, P.; Morvan, B.; Stefanou, N.
2016-11-01
An extension of the layer-multiple-scattering method to phononic crystals of poroelastic spheres immersed in a fluid medium is developed. The applicability of the method is demonstrated on specific examples of close-packed fcc crystals of submerged water-saturated meso- and macroporous silica microspheres. It is shown that, by varying the pore size and/or the porosity, the transmission, reflection, and absorption spectra of finite slabs of these crystals are significantly altered. Strong absorption, driven by the slow waves in the poroelastic material and enhanced by multiple scattering, leads to negligible transmittance over an extended frequency range, which might be useful for practical applications in broadband acoustic shielding. The results are analyzed by reference to relevant phononic dispersion diagrams in the viscous and inertial coupling limits, and a consistent interpretation of the underlying physics is provided.
Influence of electron–phonon interactions in single dopant nanowire transistors
Carrillo-Nuñez, H. Bescond, M. Cavassilas, N.; Dib, E.; Lannoo, M.
2014-10-28
Single dopant nanowire transistors can be viewed as the ultimate miniaturization of nano electronic devices. In this work, we theoretically investigate the influence of the electron-phonon coupling on their transport properties using a non-equilibrium Green's function approach in the self-consistent Born approximation. For an impurity located at the center of the wire we find that, at room temperature, acoustic phonons broaden the impurity level so that the bistability predicted in the ballistic regime is suppressed. Optical phonons are found to have a beneficial impact on carrier transport via a phonon-assisted tunneling effect. We discuss the position and temperature dependence of these effects, showing that such systems might be very promising for engineering of ultimate devices.
Konstantopoulou, A; Sgouros, A P; Sigalas, M M
2017-03-15
Using molecular dynamics and semi-empirical potentials, large scale transition metal dichalcogenides monolayers (TMDM) were examined. The focus of the study was the modification of the phonon spectrum of TMDMs by engineering substitutional defects to produce phononic resonators and waveguides on the atomic scale. The resonant frequencies of the aforementioned structures can be tuned by applying tensile or compressive stresses. The TMDMs exhibited wide phononic band gaps (PBG) in their phonon spectrum because they consist of atoms with quite different atomic masses. The PBG from the present semi-empirical calculations were found to be in reasonable agreement with previous ab initio calculations. The problem is very broad since many varieties of TMDMs (with or without defects) can be made. The present study focused on MX2 composites with M being Mo or W and X being S or Se. The most interesting behavior was found in WS2 with substitutional defects of either S ↔ Se or W ↔ Mo.
Scanning Tunneling Microscopy Observation of Phonon Condensate
Altfeder, Igor; Balatsky, Alexander V.; Voevodin, Andrey A.; ...
2017-02-22
Using quantum tunneling of electrons into vibrating surface atoms, phonon oscillations can be observed on the atomic scale. Phonon interference patterns with unusually large signal amplitudes have been revealed by scanning tunneling microscopy in intercalated van der Waals heterostructures. Our results show that the effective radius of these phonon quasi-bound states, the real-space distribution of phonon standing wave amplitudes, the scattering phase shifts, and the nonlinear intermode coupling strongly depend on the presence of defect-induced scattering resonance. The observed coherence of these quasi-bound states most likely arises from phase- and frequency-synchronized dynamics of all phonon modes, and indicates the formationmore » of many-body condensate of optical phonons around resonant defects. We found that increasing the strength of the scattering resonance causes the increase of the condensate droplet radius without affecting the condensate fraction inside it. The condensate can be observed at room temperature.« less
Wide-Stopband Aperiodic Phononic Filters
NASA Technical Reports Server (NTRS)
Rostem, Karwan; Chuss, David; Denis, K. L.; Wollack, E. J.
2016-01-01
We demonstrate that a phonon stopband can be synthesized from an aperiodic structure comprising a discrete set of phononic filter stages. Each element of the set has a dispersion relation that defines a complete bandgap when calculated under a Bloch boundary condition. Hence, the effective stopband width in an aperiodic phononic filter (PnF) may readily exceed that of a phononic crystal with a single lattice constant or a coherence scale. With simulations of multi-moded phononic waveguides, we discuss the effects of finite geometry and mode-converting junctions on the phonon transmission in PnFs. The principles described may be utilized to form a wide stopband in acoustic and surface wave media. Relative to the quantum of thermal conductance for a uniform mesoscopic beam, a PnF with a stopband covering 1.6-10.4 GHz is estimated to reduce the thermal conductance by an order of magnitude at 75 mK.
Topologically protected elastic waves in phononic metamaterials
Mousavi, S. Hossein; Khanikaev, Alexander B.; Wang, Zheng
2015-01-01
Surface waves in topological states of quantum matter exhibit unique protection from backscattering induced by disorders, making them ideal carriers for both classical and quantum information. Topological matters for electrons and photons are largely limited by the range of bulk properties, and the associated performance trade-offs. In contrast, phononic metamaterials provide access to a much wider range of material properties. Here we demonstrate numerically a phononic topological metamaterial in an elastic-wave analogue of the quantum spin Hall effect. A dual-scale phononic crystal slab is used to support two effective spins for phonons over a broad bandwidth, and strong spin–orbit coupling is realized by breaking spatial mirror symmetry. By preserving the spin polarization with an external load or spatial symmetry, phononic edge states are shown to be robust against scattering from discrete defects as well as disorders in the continuum, demonstrating topological protection for phonons in both static and time-dependent regimes. PMID:26530426
Circular Phonon Dichroism in Weyl Semimetals
NASA Astrophysics Data System (ADS)
Liu, Donghao; Shi, Junren
2017-08-01
We derive the phonon dynamics of magnetic metals in the presence of strong spin-orbit coupling. We show that both a dissipationless viscosity and a dissipative viscosity arise in the dynamics. While the dissipationless viscosity splits the dispersion of left-handed and right-handed circularly polarized phonons, the dissipative viscosity damps them differently, inducing circular phonon dichroism. The effect offers a new degree of manipulation of phonons, i.e., the control of the phonon polarization. We investigate the effect in Weyl semimetals. We find that there exists strong circular phonon dichroism in Weyl semimetals breaking both the time-reversal and the inversion symmetry, making them potential materials for realizing the acoustic circular polarizer.
Scanning Tunneling Microscopy Observation of Phonon Condensate
Altfeder, Igor; Voevodin, Andrey A.; Check, Michael H.; Eichfeld, Sarah M.; Robinson, Joshua A.; Balatsky, Alexander V.
2017-01-01
Using quantum tunneling of electrons into vibrating surface atoms, phonon oscillations can be observed on the atomic scale. Phonon interference patterns with unusually large signal amplitudes have been revealed by scanning tunneling microscopy in intercalated van der Waals heterostructures. Our results show that the effective radius of these phonon quasi-bound states, the real-space distribution of phonon standing wave amplitudes, the scattering phase shifts, and the nonlinear intermode coupling strongly depend on the presence of defect-induced scattering resonance. The observed coherence of these quasi-bound states most likely arises from phase- and frequency-synchronized dynamics of all phonon modes, and indicates the formation of many-body condensate of optical phonons around resonant defects. We found that increasing the strength of the scattering resonance causes the increase of the condensate droplet radius without affecting the condensate fraction inside it. The condensate can be observed at room temperature. PMID:28225066
Scanning Tunneling Microscopy Observation of Phonon Condensate.
Altfeder, Igor; Voevodin, Andrey A; Check, Michael H; Eichfeld, Sarah M; Robinson, Joshua A; Balatsky, Alexander V
2017-02-22
Using quantum tunneling of electrons into vibrating surface atoms, phonon oscillations can be observed on the atomic scale. Phonon interference patterns with unusually large signal amplitudes have been revealed by scanning tunneling microscopy in intercalated van der Waals heterostructures. Our results show that the effective radius of these phonon quasi-bound states, the real-space distribution of phonon standing wave amplitudes, the scattering phase shifts, and the nonlinear intermode coupling strongly depend on the presence of defect-induced scattering resonance. The observed coherence of these quasi-bound states most likely arises from phase- and frequency-synchronized dynamics of all phonon modes, and indicates the formation of many-body condensate of optical phonons around resonant defects. We found that increasing the strength of the scattering resonance causes the increase of the condensate droplet radius without affecting the condensate fraction inside it. The condensate can be observed at room temperature.
Topologically protected elastic waves in phononic metamaterials.
Mousavi, S Hossein; Khanikaev, Alexander B; Wang, Zheng
2015-11-04
Surface waves in topological states of quantum matter exhibit unique protection from backscattering induced by disorders, making them ideal carriers for both classical and quantum information. Topological matters for electrons and photons are largely limited by the range of bulk properties, and the associated performance trade-offs. In contrast, phononic metamaterials provide access to a much wider range of material properties. Here we demonstrate numerically a phononic topological metamaterial in an elastic-wave analogue of the quantum spin Hall effect. A dual-scale phononic crystal slab is used to support two effective spins for phonons over a broad bandwidth, and strong spin-orbit coupling is realized by breaking spatial mirror symmetry. By preserving the spin polarization with an external load or spatial symmetry, phononic edge states are shown to be robust against scattering from discrete defects as well as disorders in the continuum, demonstrating topological protection for phonons in both static and time-dependent regimes.
Scanning Tunneling Microscopy Observation of Phonon Condensate
NASA Astrophysics Data System (ADS)
Altfeder, Igor; Voevodin, Andrey A.; Check, Michael H.; Eichfeld, Sarah M.; Robinson, Joshua A.; Balatsky, Alexander V.
2017-02-01
Using quantum tunneling of electrons into vibrating surface atoms, phonon oscillations can be observed on the atomic scale. Phonon interference patterns with unusually large signal amplitudes have been revealed by scanning tunneling microscopy in intercalated van der Waals heterostructures. Our results show that the effective radius of these phonon quasi-bound states, the real-space distribution of phonon standing wave amplitudes, the scattering phase shifts, and the nonlinear intermode coupling strongly depend on the presence of defect-induced scattering resonance. The observed coherence of these quasi-bound states most likely arises from phase- and frequency-synchronized dynamics of all phonon modes, and indicates the formation of many-body condensate of optical phonons around resonant defects. We found that increasing the strength of the scattering resonance causes the increase of the condensate droplet radius without affecting the condensate fraction inside it. The condensate can be observed at room temperature.
Wide-Stopband Aperiodic Phononic Filters
NASA Technical Reports Server (NTRS)
Rostem, Karwan; Chuss, David; Denis, K. L.; Wollack, E. J.
2016-01-01
We demonstrate that a phonon stopband can be synthesized from an aperiodic structure comprising a discrete set of phononic filter stages. Each element of the set has a dispersion relation that defines a complete bandgap when calculated under a Bloch boundary condition. Hence, the effective stopband width in an aperiodic phononic filter (PnF) may readily exceed that of a phononic crystal with a single lattice constant or a coherence scale. With simulations of multi-moded phononic waveguides, we discuss the effects of finite geometry and mode-converting junctions on the phonon transmission in PnFs. The principles described may be utilized to form a wide stopband in acoustic and surface wave media. Relative to the quantum of thermal conductance for a uniform mesoscopic beam, a PnF with a stopband covering 1.6-10.4 GHz is estimated to reduce the thermal conductance by an order of magnitude at 75 mK.
Coherent Phonon Rabi Oscillations with a High-Frequency Carbon Nanotube Phonon Cavity.
Zhu, Dong; Wang, Xin-He; Kong, Wei-Cheng; Deng, Guang-Wei; Wang, Jiang-Tao; Li, Hai-Ou; Cao, Gang; Xiao, Ming; Jiang, Kai-Li; Dai, Xing-Can; Guo, Guang-Can; Nori, Franco; Guo, Guo-Ping
2017-02-08
Phonon-cavity electromechanics allows the manipulation of mechanical oscillations similar to photon-cavity systems. Many advances on this subject have been achieved in various materials. In addition, the coherent phonon transfer (phonon Rabi oscillations) between the phonon cavity mode and another oscillation mode has attracted many interest in nanoscience. Here, we demonstrate coherent phonon transfer in a carbon nanotube phonon-cavity system with two mechanical modes exhibiting strong dynamical coupling. The gate-tunable phonon oscillation modes are manipulated and detected by extending the red-detuned pump idea of photonic cavity electromechanics. The first- and second-order coherent phonon transfers are observed with Rabi frequencies 591 and 125 kHz, respectively. The frequency quality factor product fQm ∼ 2 × 10(12) Hz achieved here is larger than kBTbase/h, which may enable the future realization of Rabi oscillations in the quantum regime.
Heat guiding and focusing using ballistic phonon transport in phononic nanostructures
Anufriev, Roman; Ramiere, Aymeric; Maire, Jeremie; Nomura, Masahiro
2017-01-01
Unlike classical heat diffusion at macroscale, nanoscale heat conduction can occur without energy dissipation because phonons can ballistically travel in straight lines for hundreds of nanometres. Nevertheless, despite recent experimental evidence of such ballistic phonon transport, control over its directionality, and thus its practical use, remains a challenge, as the directions of individual phonons are chaotic. Here, we show a method to control the directionality of ballistic phonon transport using silicon membranes with arrays of holes. First, we demonstrate that the arrays of holes form fluxes of phonons oriented in the same direction. Next, we use these nanostructures as directional sources of ballistic phonons and couple the emitted phonons into nanowires. Finally, we introduce thermal lens nanostructures, in which the emitted phonons converge at the focal point, thus focusing heat into a spot of a few hundred nanometres. These results motivate the concept of ray-like heat manipulations at the nanoscale. PMID:28516909
Heat guiding and focusing using ballistic phonon transport in phononic nanostructures
NASA Astrophysics Data System (ADS)
Anufriev, Roman; Ramiere, Aymeric; Maire, Jeremie; Nomura, Masahiro
2017-05-01
Unlike classical heat diffusion at macroscale, nanoscale heat conduction can occur without energy dissipation because phonons can ballistically travel in straight lines for hundreds of nanometres. Nevertheless, despite recent experimental evidence of such ballistic phonon transport, control over its directionality, and thus its practical use, remains a challenge, as the directions of individual phonons are chaotic. Here, we show a method to control the directionality of ballistic phonon transport using silicon membranes with arrays of holes. First, we demonstrate that the arrays of holes form fluxes of phonons oriented in the same direction. Next, we use these nanostructures as directional sources of ballistic phonons and couple the emitted phonons into nanowires. Finally, we introduce thermal lens nanostructures, in which the emitted phonons converge at the focal point, thus focusing heat into a spot of a few hundred nanometres. These results motivate the concept of ray-like heat manipulations at the nanoscale.
Heat guiding and focusing using ballistic phonon transport in phononic nanostructures.
Anufriev, Roman; Ramiere, Aymeric; Maire, Jeremie; Nomura, Masahiro
2017-05-18
Unlike classical heat diffusion at macroscale, nanoscale heat conduction can occur without energy dissipation because phonons can ballistically travel in straight lines for hundreds of nanometres. Nevertheless, despite recent experimental evidence of such ballistic phonon transport, control over its directionality, and thus its practical use, remains a challenge, as the directions of individual phonons are chaotic. Here, we show a method to control the directionality of ballistic phonon transport using silicon membranes with arrays of holes. First, we demonstrate that the arrays of holes form fluxes of phonons oriented in the same direction. Next, we use these nanostructures as directional sources of ballistic phonons and couple the emitted phonons into nanowires. Finally, we introduce thermal lens nanostructures, in which the emitted phonons converge at the focal point, thus focusing heat into a spot of a few hundred nanometres. These results motivate the concept of ray-like heat manipulations at the nanoscale.
NASA Astrophysics Data System (ADS)
Iglesias, José M.; Rengel, Raúl; Mokhtar Hamham, El; Pascual, Elena; Martín, María J.
2017-08-01
The interaction between out-of-equilibrium phonons and Joule heating in the static electron transport properties of monolayer graphene supported on \\text{Si}{{\\text{O}}2} is investigated. An ensemble Monte Carlo electronic transport engine with a self-consistent out-of-equilibrium phonon population is coupled to a thermal resistive model describing the heat dissipation, so experimental velocity-field curves are successfully reproduced for samples 7 μm wide and 4 μm long. The separate effect of self-heating and hot phonons is analyzed in depth, showing that neglecting the hot phonon effect yields to an overestimation of the lattice temperature and drift velocity. In particular, the lowest energy surface polar phonon mode is found to present a strong coupling between both effects, which need to be considered together in a consistent manner to correctly describe the heating of graphene samples at high fields.
Temperature Dependence of Phonons in Pyrolitic Graphite
DOE R&D Accomplishments Database
Brockhouse, B. N.; Shirane, G.
1977-01-01
Dispersion curves for longitudinal and transverse phonons propagating along and near the c-axis in pyrolitic graphite at temperatures between 4°K and 1500°C have been measured by neutron spectroscopy. The observed frequencies decrease markedly with increasing temperature (except for the transverse optical ''rippling'' modes in the hexagonal planes). The neutron groups show interesting asymmetrical broadening ascribed to interference between one phonon and many phonon processes.
Acoustic-phonon transmission in quasiperiodic superlattices
NASA Astrophysics Data System (ADS)
Tamura, S.; Wolfe, J. P.
1987-08-01
Acoustic-phonon transmission through a realistic Fibonacci superlattice is studied theoretically. We find a number of transmission dips corresponding to Bragg-like reflections of phonons. The transmission spectrum is much more complex than in the periodic case; however, the strongest dips in transmission are remarkably correlated with those of the periodic superlattice. We also present the first realistic calculations of the phonon dispersion relations in an actual quasiperiodic superlattice. For oblique angles of incidence, intermode Bragg-like reflections of the phonons are predicted.
Effect of Rattling Phonons on Sommerfeld Constant
NASA Astrophysics Data System (ADS)
Hotta, Takashi
2008-10-01
By employing a numerical renormalization group technique, we evaluate electronic specific heat coefficient γ of the Anderson model coupled with local anharmonic phonons for the oscillation of a caged atom. For the rattling-type cage potential with a flat and wide region in the bottom, we find that phonon-mediated attraction is largely enhanced. When the potential shape is deformed from the rattling type, there occurs a cancellation between Coulomb repulsion and the phonon-mediated attraction. In such a situation, spin and charge fluctuations are comparable to each other, leading to the realization of exotic electron-phonon complex state with large and magnetically robust γ.
Ballistic phonon transport in holey silicon.
Lee, Jaeho; Lim, Jongwoo; Yang, Peidong
2015-05-13
When the size of semiconductors is smaller than the phonon mean free path, phonons can carry heat with no internal scattering. Ballistic phonon transport has received attention for both theoretical and practical aspects because Fourier's law of heat conduction breaks down and the heat dissipation in nanoscale transistors becomes unpredictable in the ballistic regime. While recent experiments demonstrate room-temperature evidence of ballistic phonon transport in various nanomaterials, the thermal conductivity data for silicon in the length scale of 10-100 nm is still not available due to experimental challenges. Here we show ballistic phonon transport prevails in the cross-plane direction of holey silicon from 35 to 200 nm. The thermal conductivity scales linearly with the length (thickness) even though the lateral dimension (neck) is as narrow as 20 nm. We assess the impact of long-wavelength phonons and predict a transition from ballistic to diffusive regime using scaling models. Our results support strong persistence of long-wavelength phonons in nanostructures and are useful for controlling phonon transport for thermoelectrics and potential phononic applications.
Phonon-assisted transient electroluminescence in Si
Cheng, Tzu-Huan; Chu-Su, Yu; Liu, Chien-Sheng; Lin, Chii-Wann
2014-06-30
The phonon-replica infrared emission is observed at room temperature from indirect band gap Si light-emitting diode under forward bias. With increasing injection current density, the broadened electroluminescence spectrum and band gap reduction are observed due to joule heating. The spectral-resolved temporal response of electroluminescence reveals the competitiveness between single (TO) and dual (TO + TA) phonon-assisted indirect band gap transitions. As compared to infrared emission with TO phonon-replica, the retarder of radiative recombination at long wavelength region (∼1.2 μm) indicates lower transition probability of dual phonon-replica before thermal equivalent.
Electron-phonon interactions from first principles
NASA Astrophysics Data System (ADS)
Giustino, Feliciano
2017-01-01
This article reviews the theory of electron-phonon interactions in solids from the point of view of ab initio calculations. While the electron-phonon interaction has been studied for almost a century, predictive nonempirical calculations have become feasible only during the past two decades. Today it is possible to calculate from first principles many materials properties related to the electron-phonon interaction, including the critical temperature of conventional superconductors, the carrier mobility in semiconductors, the temperature dependence of optical spectra in direct and indirect-gap semiconductors, the relaxation rates of photoexcited carriers, the electron mass renormalization in angle-resolved photoelectron spectra, and the nonadiabatic corrections to phonon dispersion relations. In this article a review of the theoretical and computational framework underlying modern electron-phonon calculations from first principles as well as landmark investigations of the electron-phonon interaction in real materials is given. The first part of the article summarizes the elementary theory of electron-phonon interactions and their calculations based on density-functional theory. The second part discusses a general field-theoretic formulation of the electron-phonon problem and establishes the connection with practical first-principles calculations. The third part reviews a number of recent investigations of electron-phonon interactions in the areas of vibrational spectroscopy, photoelectron spectroscopy, optical spectroscopy, transport, and superconductivity.
Hypersonic phonon propagation in one-dimensional surface phononic crystal
NASA Astrophysics Data System (ADS)
Graczykowski, B.; Sledzinska, M.; Kehagias, N.; Alzina, F.; Reparaz, J. S.; Sotomayor Torres, C. M.
2014-03-01
Hypersonic, thermally activated surface acoustic waves propagating in the surface of crystalline silicon patterned with periodic stripes were studied by Brillouin light scattering. Two characteristic directions (normal and parallel to the stripes) of surface acoustic waves propagation were examined exhibiting a distinctive propagation behavior. The measured phononic band structure exhibits diverse features, such as zone folding, band gap opening, and hybridization to local resonance for waves propagating normal to the stripes, and a variety of dispersive modes propagating along the stripes. Experimental results were supported by theoretical calculations performed using finite element method.
Soltanipour, Asieh; Sadri, Saeed; Rabbani, Hossein; Akhlaghi, Mohammad Reza
2015-01-01
This paper presents a new procedure for automatic extraction of the blood vessels and optic disk (OD) in fundus fluorescein angiogram (FFA). In order to extract blood vessel centerlines, the algorithm of vessel extraction starts with the analysis of directional images resulting from sub-bands of fast discrete curvelet transform (FDCT) in the similar directions and different scales. For this purpose, each directional image is processed by using information of the first order derivative and eigenvalues obtained from the Hessian matrix. The final vessel segmentation is obtained using a simple region growing algorithm iteratively, which merges centerline images with the contents of images resulting from modified top-hat transform followed by bit plane slicing. After extracting blood vessels from FFA image, candidates regions for OD are enhanced by removing blood vessels from the FFA image, using multi-structure elements morphology, and modification of FDCT coefficients. Then, canny edge detector and Hough transform are applied to the reconstructed image to extract the boundary of candidate regions. At the next step, the information of the main arc of the retinal vessels surrounding the OD region is used to extract the actual location of the OD. Finally, the OD boundary is detected by applying distance regularized level set evolution. The proposed method was tested on the FFA images from angiography unit of Isfahan Feiz Hospital, containing 70 FFA images from different diabetic retinopathy stages. The experimental results show the accuracy more than 93% for vessel segmentation and more than 87% for OD boundary extraction. PMID:26284170
NASA Astrophysics Data System (ADS)
Sharma, Kriti; Al-Kabbi, A. S.; Singh, Baljinder; Saini, G. S. S.; Tripathi, S. K.
2011-12-01
Nanocrystalline CdSe thin films have been prepared by thermal vaccum evaporation technique using Inert Gas Condensation method using Argon as inert gas. XRD confirms the crystalline cubic nature of nc-CdSe thin films. The optical band gap is calculated for as deposited nc-CdSe and it comes out to be 2.1 eV. CPM has been used to measure sub-band gap absorption in nanocrystalline CdSe thin films. The thin films of nc-CdSe have been annealed at 80 °C for one hour and sub-bandgap absorption in annealed samples has also been calculated. Slope of Urbach tail which is a measure of disorder in both as deposited and annealed samples has been calculated. In the case of as deposited nc-CdSe thin films, Urbach slope is 354 meV. It decreases to the value 198 meV after annealing which shows structural disorder decreases after annealing.
NASA Astrophysics Data System (ADS)
Sen, Prabal; Balasubrahmaniyam, M.; Kar, Durgesh; Kasiviswanathan, S.
2017-05-01
The size and spectral dependence of the persistent photocurrent (PPC) of dc sputtered indium oxide (IO) films has been studied under UV and sub-band gap illuminations. PPC follows bi-exponential decay with a fast and a slow process having time constants (denoted by τ f and τ s , respectively) that differ by about two orders of magnitude. τ s is associated with carrier scattering from an initial surface state to a surface or bulk state with the former dominating below a characteristic length scale of ˜60 nm. On the other hand, τ f is characterized by the process where both the initial and final states are surface related. Treating the IO film surface with tetramethyl tetraphenyl trisiloxane (TTTS) decreases τ s by a factor of 5 with τ f remaining almost unaffected, which is a clear indication of reduction of defects specific to the slow relaxation process. Based on the molecular structure and chemical activity of TTTS, it is suggested that TTTS may passivate mainly the dangling oxygen-bonds at the film surface. The spectral dependence of τ s indicates that the associated surface states exhibit a maximum around 2.5 eV above the level from where strong optical transitions are allowed.
Li, Junqiang; Shan, Xin; Bade, Sri Ganesh R; Geske, Thomas; Jiang, Qinglong; Yang, Xin; Yu, Zhibin
2016-10-03
Charge-carrier injection into an emissive semiconductor thin film can result in electroluminescence and is generally achieved by using a multilayer device structure, which requires an electron-injection layer (EIL) between the cathode and the emissive layer and a hole-injection layer (HIL) between the anode and the emissive layer. The recent advancement of halide perovskite semiconductors opens up a new path to electroluminescent devices with a greatly simplified device structure. We report cesium lead tribromide light-emitting diodes (LEDs) without the aid of an EIL or HIL. These so-called single-layer LEDs have exhibited a sub-band gap turn-on voltage. The devices obtained a brightness of 591 197 cd m(-2) at 4.8 V, with an external quantum efficiency of 5.7% and a power efficiency of 14.1 lm W(-1). Such an advancement demonstrates that very high efficiency of electron and hole injection can be obtained in perovskite LEDs even without using an EIL or HIL.
Splash, pop, sizzle: Information processing with phononic computing
Sklan, Sophia R.
2015-05-15
Phonons, the quanta of mechanical vibration, are important to the transport of heat and sound in solid materials. Recent advances in the fundamental control of phonons (phononics) have brought into prominence the potential role of phonons in information processing. In this review, the many directions of realizing phononic computing and information processing are examined. Given the relative similarity of vibrational transport at different length scales, the related fields of acoustic, phononic, and thermal information processing are all included, as are quantum and classical computer implementations. Connections are made between the fundamental questions in phonon transport and phononic control and the device level approach to diodes, transistors, memory, and logic. .
Enhanced electron-phonon coupling for a semiconductor charge qubit in a surface phonon cavity
Chen, J. C. H.; Sato, Y.; Kosaka, R.; Hashisaka, M.; Muraki, K.; Fujisawa, T.
2015-01-01
Electron-phonon coupling is a major decoherence mechanism, which often causes scattering and energy dissipation in semiconductor electronic systems. However, this electron-phonon coupling may be used in a positive way for reaching the strong or ultra-strong coupling regime in an acoustic version of the cavity quantum electrodynamic system. Here we propose and demonstrate a phonon cavity for surface acoustic waves, which is made of periodic metal fingers that constitute Bragg reflectors on a GaAs/AlGaAs heterostructure. Phonon band gap and cavity phonon modes are identified by frequency, time and spatially resolved measurements of the piezoelectric potential. Tunneling spectroscopy on a double quantum dot indicates the enhancement of phonon assisted transitions in a charge qubit. This encourages studying of acoustic cavity quantum electrodynamics with surface phonons. PMID:26469629
Microfabricated phononic crystal devices and applications
NASA Astrophysics Data System (ADS)
Olsson, R. H., III; El-Kady, I.
2009-01-01
Phononic crystals are the acoustic wave analogue of photonic crystals. Here a periodic array of scattering inclusions located in a homogeneous host material forbids certain ranges of acoustic frequencies from existence within the crystal, thus creating what are known as acoustic bandgaps. The majority of previously reported phononic crystal devices have been constructed by hand, assembling scattering inclusions in a viscoelastic medium, predominantly air, water or epoxy, resulting in large structures limited to frequencies below 1 MHz. Recently, phononic crystals and devices have been scaled to VHF (30-300 MHz) frequencies and beyond by utilizing microfabrication and micromachining technologies. This paper reviews recent developments in the area of micro-phononic crystals including design techniques, material considerations, microfabrication processes, characterization methods and reported device structures. Micro-phononic crystal devices realized in low-loss solid materials are emphasized along with their potential application in radio frequency communications and acoustic imaging for medical ultrasound and nondestructive testing. The reported advances in batch micro-phononic crystal fabrication and simplified testing promise not only the deployment of phononic crystals in a number of commercial applications but also greater experimentation on a wide variety of phononic crystal structures.
Hybrid functional calculation of electronic and phonon structure of BaSnO{sub 3}
Kim, Bog G.; Jo, J.Y.; Cheong, S.W.
2013-01-15
Barium stannate, BaSnO{sub 3} (BSO), with a cubic perovskite structure, has been highlighted as a promising host material for the next generation transparent oxide electrodes. This study examined theoretically the electronic structure and phonon structure of BSO using hybrid density functional theory based on the HSE06 functional. The electronic structure results of BSO were corrected by extending the phonon calculations based on the hybrid density functional. The fundamental thermal properties were also predicted based on a hybrid functional calculation. Overall, a detailed understanding of the electronic structure, phonon modes and phonon dispersion of BSO will provide a theoretical starting-point for engineering applications of this material. - Graphical Abstract: (a) Crystal structure of BaSnO{sub 3}. The center ball is Ba and small (red) ball on edge is oxygen and SnO{sub 6} octahedrons are plotted as polyhedron. (b) Electronic band structure along the high symmetry point in the Brillouin zone using the HSE06 hybrid functional. (c) The phonon dispersion curve calculated using the HSE06 hybrid functional (d) Zone center lowest energy F{sub 1u} phonon mode. Highlights: Black-Right-Pointing-Pointer We report the full hybrid functional calculation of not only the electronic structure but also the phonon structure for BaSnO{sub 3}. Black-Right-Pointing-Pointer The band gap calculation of HSE06 revealed an indirect gap with 2.48 eV. Black-Right-Pointing-Pointer The effective mass at the conduction band minimum and valence band maximum was calculated. Black-Right-Pointing-Pointer In addition, the phonon structure of BSO was calculated using the HSE06 functional. Black-Right-Pointing-Pointer Finally, the heat capacity was calculated and compared with the recent experimental result.
Phonon Analysis in Multiphonon Transitions
NASA Astrophysics Data System (ADS)
Huang, Kun; Gu, Zongquan
In the investigation of multiphonon transitions, single-mode or single-frequency models are widely used. In view of the fact that such oversimplified models can be seriously inadequate, the present work bridges the gap between the complexity of the general formal theory and the simplicity required for concrete applications by introducing the concept of multi-frequency models. That is, the theory is so formulated that a general system can be approximated by multi-frequency models of any degree of elaboration. A statistical thermodynamic formalism is developed for treating such multi-frequency models, which, on the one hand, greatly reduces the labour of calculation with such models and, on the other hand, leads directly to a simple statistical distribution law for numbers of phonons of each frequency participating in a multiphonon transition. Applications of the theory to concrete models lead to certain general conclusions on frequency dispersion effects in multiphonon transitions. The use of the theory is further demonstrated by fully accounting for the paradoxical experimental results reported by Jia and Yen that the isotopic substitution of H by D in CsMn Cl3· 2H2O reduces the multiphonon nonradiative transition probability of excited Mn2+ ion by more than ten-fold, and yet leaves the corresponding luminescence phonon sideband little changed. In the last section of the paper, the relation between the statistical thermodynamic formalism and existing multiphonon transition theory is elucidated, thereby the theoretical basis of the statistical formalism becomes clearly defined.
Multiple magneto-phonon resonances in graphene
NASA Astrophysics Data System (ADS)
Basko, D. M.; Leszczynski, P.; Faugeras, C.; Binder, J.; Nicolet, A. A. L.; Kossacki, P.; Orlita, M.; Potemski, M.
2016-03-01
Our low-temperature magneto-Raman scattering measurements performed on graphene-like locations on the surface of bulk graphite, carries the energyite reveal a new series of magneto-phonon resonances involving both K point and Γ point phonons. These are resonances between a purely electronic excitation, an electronic excitation accompanied by one phonon, and a two-phonon excitation. In particular, we observe the resonant splitting of three crossing excitation branches. We give a detailed theoretical analysis of these multi-excitation resonances. Our results highlight the role of combined excitations and the importance of multi-phonon processes (from both K and Γ points) for the relaxation of hot carriers in graphene.
Phononic crystals and elastodynamics: Some relevant points
NASA Astrophysics Data System (ADS)
Aravantinos-Zafiris, N.; Sigalas, M. M.; Kafesaki, M.; Economou, E. N.
2014-12-01
In the present paper we review briefly some of the first works on wave propagation in phononic crystals emphasizing the conditions for the creation of acoustic band-gaps and the role of resonances to the band-gap creation. We show that useful conclusions in the analysis of phononic band gap structures can be drawn by considering the mathematical similarities of the basic classical wave equation (Helmholtz equation) with Schrödinger equation and by employing basic solid state physics concepts and conclusions regarding electronic waves. In the second part of the paper we demonstrate the potential of phononic systems to be used as elastic metamaterials. This is done by demonstrating negative refraction in phononic crystals and subwavelength waveguiding in a linear chain of elastic inclusions, and by proposing a novel structure with close to pentamode behavior. Finally the potential of phononic structures to be used in liquid sensor applications is discussed and demonstrated.
Lattice Boltzmann modeling of phonon transport
NASA Astrophysics Data System (ADS)
Guo, Yangyu; Wang, Moran
2016-06-01
A novel lattice Boltzmann scheme is proposed for phonon transport based on the phonon Boltzmann equation. Through the Chapman-Enskog expansion, the phonon lattice Boltzmann equation under the gray relaxation time approximation recovers the classical Fourier's law in the diffusive limit. The numerical parameters in the lattice Boltzmann model are therefore rigorously correlated to the bulk material properties. The new scheme does not only eliminate the fictitious phonon speed in the diagonal direction of a square lattice system in the previous lattice Boltzmann models, but also displays very robust performances in predicting both temperature and heat flux distributions consistent with analytical solutions for diverse numerical cases, including steady-state and transient, macroscale and microscale, one-dimensional and multi-dimensional phonon heat transport. This method may provide a powerful numerical tool for deep studies of nonlinear and nonlocal heat transports in nanosystems.
Ultrafast Structure Switching through Nonlinear Phononics
NASA Astrophysics Data System (ADS)
Juraschek, D. M.; Fechner, M.; Spaldin, N. A.
2017-02-01
We describe a mechanism by which nonlinear phononics allows ultrafast coherent and directional control of transient structural distortions. With ErFeO3 as a model system, we use density functional theory to calculate the structural properties as input into an anharmonic phonon model that describes the response of the system to a pulsed optical excitation. We find that the trilinear coupling of two orthogonal infrared-active phonons to a Raman-active phonon causes a transient distortion of the lattice. In contrast to the quadratic-linear coupling that has been previously explored, the direction of the distortion is determined by the polarization of the exciting light, introducing a novel mechanism for nonlinear phononic switching. Since the occurrence of the coupling is determined by the symmetry of the system we propose that it is a universal feature of orthorhombic and tetragonal perovskites.
Phononic crystals and elastodynamics: Some relevant points
Aravantinos-Zafiris, N.; Sigalas, M. M.; Kafesaki, M.; Economou, E. N.
2014-12-15
In the present paper we review briefly some of the first works on wave propagation in phononic crystals emphasizing the conditions for the creation of acoustic band-gaps and the role of resonances to the band-gap creation. We show that useful conclusions in the analysis of phononic band gap structures can be drawn by considering the mathematical similarities of the basic classical wave equation (Helmholtz equation) with Schrödinger equation and by employing basic solid state physics concepts and conclusions regarding electronic waves. In the second part of the paper we demonstrate the potential of phononic systems to be used as elastic metamaterials. This is done by demonstrating negative refraction in phononic crystals and subwavelength waveguiding in a linear chain of elastic inclusions, and by proposing a novel structure with close to pentamode behavior. Finally the potential of phononic structures to be used in liquid sensor applications is discussed and demonstrated.
Phonon Drag Dislocations at High Pressures
Wolfer, W.G.
1999-10-19
Phonon drag on dislocations is the dominant process which determines the flow stress of metals at elevated temperatures and at very high plastic deformation rates. The dependence of the phonon drag on pressure or density is derived using a Mie-Grueneisen equation of state. The phonon drag is shown to increase nearly linearly with temperature but to decrease with density or pressure. Numerical results are presented for its variation for shock-loaded copper and aluminum. In these cases, density and temperature increase simultaneously, resulting in a more modest net increase in the dislocation drag coefficient. Nevertheless, phonon drag increases by more than an order of magnitude during shock deformations which approach melting. Since the dependencies of elastic moduli and of the phonon drag coefficient on pressure and temperature are fundamentally different, the effect of pressure on the constitutive law for plastic deformation can not simply be accounted for by its effect on the elastic shear modulus.
Phonon counting and intensity interferometry of a nanomechanical resonator.
Cohen, Justin D; Meenehan, Seán M; MacCabe, Gregory S; Gröblacher, Simon; Safavi-Naeini, Amir H; Marsili, Francesco; Shaw, Matthew D; Painter, Oskar
2015-04-23
In optics, the ability to measure individual quanta of light (photons) enables a great many applications, ranging from dynamic imaging within living organisms to secure quantum communication. Pioneering photon counting experiments, such as the intensity interferometry performed by Hanbury Brown and Twiss to measure the angular width of visible stars, have played a critical role in our understanding of the full quantum nature of light. As with matter at the atomic scale, the laws of quantum mechanics also govern the properties of macroscopic mechanical objects, providing fundamental quantum limits to the sensitivity of mechanical sensors and transducers. Current research in cavity optomechanics seeks to use light to explore the quantum properties of mechanical systems ranging in size from kilogram-mass mirrors to nanoscale membranes, as well as to develop technologies for precision sensing and quantum information processing. Here we use an optical probe and single-photon detection to study the acoustic emission and absorption processes in a silicon nanomechanical resonator, and perform a measurement similar to that used by Hanbury Brown and Twiss to measure correlations in the emitted phonons as the resonator undergoes a parametric instability formally equivalent to that of a laser. Owing to the cavity-enhanced coupling of light with mechanical motion, this effective phonon counting technique has a noise equivalent phonon sensitivity of 0.89 ± 0.05. With straightforward improvements to this method, a variety of quantum state engineering tasks using mesoscopic mechanical resonators would be enabled, including the generation and heralding of single-phonon Fock states and the quantum entanglement of remote mechanical elements.
Interlayer electron-phonon coupling in WSe2/hBN heterostructures
NASA Astrophysics Data System (ADS)
Jin, Chenhao; Kim, Jonghwan; Suh, Joonki; Shi, Zhiwen; Chen, Bin; Fan, Xi; Kam, Matthew; Watanabe, Kenji; Taniguchi, Takashi; Tongay, Sefaattin; Zettl, Alex; Wu, Junqiao; Wang, Feng
2017-02-01
Engineering layer-layer interactions provides a powerful way to realize novel and designable quantum phenomena in van der Waals heterostructures. Interlayer electron-electron interactions, for example, have enabled fascinating physics that is difficult to achieve in a single material, such as the Hofstadter's butterfly in graphene/boron nitride (hBN) heterostructures. In addition to electron-electron interactions, interlayer electron-phonon interactions allow for further control of the physical properties of van der Waals heterostructures. Here we report an interlayer electron-phonon interaction in WSe2/hBN heterostructures, where optically silent hBN phonons emerge in Raman spectra with strong intensities through resonant coupling to WSe2 electronic transitions. Excitation spectroscopy reveals the double-resonance nature of such enhancement, and identifies the two resonant states to be the A exciton transition of monolayer WSe2 and a new hybrid state present only in WSe2/hBN heterostructures. The observation of an interlayer electron-phonon interaction could open up new ways to engineer electrons and phonons for device applications.
Interlayer electron-phonon coupling in WSe2/hBN heterostructures
NASA Astrophysics Data System (ADS)
Jin, Chenhao; Kim, Jonghwan; Suh, Joonki; Shi, Zhiwen; Chen, Bin; Fan, Xi; Kam, Matthew; Watanabe, Kenji; Taniguchi, Takashi; Tongay, Sefaattin; Zettl, Alex; Wu, Junqiao; Wang, Feng
2016-10-01
Engineering layer-layer interactions provides a powerful way to realize novel and designable quantum phenomena in van der Waals heterostructures. Interlayer electron-electron interactions, for example, have enabled fascinating physics that is difficult to achieve in a single material, such as the Hofstadter's butterfly in graphene/boron nitride (hBN) heterostructures. In addition to electron-electron interactions, interlayer electron-phonon interactions allow for further control of the physical properties of van der Waals heterostructures. Here we report an interlayer electron-phonon interaction in WSe2/hBN heterostructures, where optically silent hBN phonons emerge in Raman spectra with strong intensities through resonant coupling to WSe2 electronic transitions. Excitation spectroscopy reveals the double-resonance nature of such enhancement, and identifies the two resonant states to be the A exciton transition of monolayer WSe2 and a new hybrid state present only in WSe2/hBN heterostructures. The observation of an interlayer electron-phonon interaction could open up new ways to engineer electrons and phonons for device applications.
Light-enhanced electron-phonon coupling from nonlinear electron-phonon coupling
NASA Astrophysics Data System (ADS)
Sentef, M. A.
2017-05-01
We investigate an exact nonequilibrium solution of a two-site electron-phonon model, where an infrared-active phonon that is nonlinearly coupled to the electrons is driven by a laser field. The time-resolved electronic spectrum shows coherence-incoherence spectral weight transfer, a clear signature of light-enhanced electron-phonon coupling. The present study is motivated by recent evidence for enhanced electron-phonon coupling in pump-probe terahertz and angle-resolved photoemission spectroscopy in bilayer graphene when driven near resonance with an infrared-active phonon mode [E. Pomarico et al., Phys. Rev. B 95, 024304 (2017), 10.1103/PhysRevB.95.024304], and by a theoretical study suggesting that transient electronic attraction arises from nonlinear electron-phonon coupling [D. M. Kennes et al., Nat. Phys. 13, 479 (2017), 10.1038/nphys4024]. We show that a linear scaling of light-enhanced electron-phonon coupling with the pump field intensity emerges, in accordance with a time-nonlocal self-energy based on a mean-field decoupling using quasiclassical phonon coherent states. Finally, we demonstrate that this leads to enhanced double occupancies in accordance with an effective electron-electron attraction. Our results suggest that materials with strong phonon nonlinearities provide an ideal playground to achieve light-enhanced electron-phonon coupling and possibly light-induced superconductivity.
Two-Dimensional Phononic Crystals: Disorder Matters.
Wagner, Markus R; Graczykowski, Bartlomiej; Reparaz, Juan Sebastian; El Sachat, Alexandros; Sledzinska, Marianna; Alzina, Francesc; Sotomayor Torres, Clivia M
2016-09-14
The design and fabrication of phononic crystals (PnCs) hold the key to control the propagation of heat and sound at the nanoscale. However, there is a lack of experimental studies addressing the impact of order/disorder on the phononic properties of PnCs. Here, we present a comparative investigation of the influence of disorder on the hypersonic and thermal properties of two-dimensional PnCs. PnCs of ordered and disordered lattices are fabricated of circular holes with equal filling fractions in free-standing Si membranes. Ultrafast pump and probe spectroscopy (asynchronous optical sampling) and Raman thermometry based on a novel two-laser approach are used to study the phononic properties in the gigahertz (GHz) and terahertz (THz) regime, respectively. Finite element method simulations of the phonon dispersion relation and three-dimensional displacement fields furthermore enable the unique identification of the different hypersonic vibrations. The increase of surface roughness and the introduction of short-range disorder are shown to modify the phonon dispersion and phonon coherence in the hypersonic (GHz) range without affecting the room-temperature thermal conductivity. On the basis of these findings, we suggest a criteria for predicting phonon coherence as a function of roughness and disorder.
Flow stabilization by subsurface phonons
Hussein, M. I.; Biringen, S.; Bilal, O. R.; Kucala, A.
2015-01-01
The interaction between a fluid and a solid surface in relative motion represents a dynamical process that is central to the problem of laminar-to-turbulent transition (and consequent drag increase) for air, sea and land vehicles, as well as long-range pipelines. This problem may in principle be alleviated via a control stimulus designed to impede the generation and growth of instabilities inherent in the flow. Here, we show that phonon motion underneath a surface may be tuned to passively generate a spatio-temporal elastic deformation profile at the surface that counters these instabilities. We theoretically demonstrate this phenomenon and the underlying mechanism of frequency-dependent destructive interference of the unstable flow waves. The converse process of flow destabilization is illustrated as well. This approach provides a condensed-matter physics treatment to fluid–structure interaction and a new paradigm for flow control. PMID:27547095
Electrons and Phonons in Semiconductor Multilayers
NASA Astrophysics Data System (ADS)
Ridley, B. K.
2014-08-01
Introduction; 1. Simple models of the electron-phonon interaction; 2. Quantum confinement of carriers; 3. Quasicontinuum theory of lattice vibrations; 4. Bulk vibratory modes in an isotropic continuum; 5. Optical modes in a quantum well; 6. Superlattice modes; 7. Optical modes in various structures; 8. Electron-phonon interaction in a quantum well; 9. Other scattering mechanisms; 10. Quantum screening; 11. The electron distribution function; 12. Spin relaxation; 13. Electrons and phonons in the Wurtzite lattice; 14. Nitride heterostructures; 15. Terahertz sources; References; Index.
Acoustic superfocusing by solid phononic crystals
Zhou, Xiaoming; Assouar, M. Badreddine Oudich, Mourad
2014-12-08
We propose a solid phononic crystal lens capable of acoustic superfocusing beyond the diffraction limit. The unit cell of the crystal is formed by four rigid cylinders in a hosting material with a cavity arranged in the center. Theoretical studies reveal that the solid lens produces both negative refraction to focus propagating waves and surface states to amplify evanescent waves. Numerical analyses of the superfocusing effect of the considered solid phononic lens are presented with a separated source excitation to the lens. In this case, acoustic superfocusing beyond the diffraction limit is evidenced. Compared to the fluid phononic lenses, the solid lens is more suitable for ultrasonic imaging applications.
Ballistic phonon transmission in quasiperiodic acoustic nanocavities
NASA Astrophysics Data System (ADS)
Mo, Yuan; Huang, Wei-Qing; Huang, Gui-Fang; Chen, Yuan; Hu, Wangyu; Wang, Ling-Ling; Pan, Anlian
2011-04-01
Ballistic phonon transport is investigated in acoustic nanocavities modulated in a quasiperiodic manner at low temperatures. Two different types of quasiperiodic acoustic nanocavities are considered: the lengths of nanocavities (QPL) and the lengths of the bridges (QPD) connecting two successive nanocavities are modulated according to the Fibonacci rule. We demonstrate that the transmission spectra and thermal conductance in both systems are similar, which is more prominent in QPD than in QPL. The transmission and thermal conductance of QPD are larger than those of QPL due to the fact that constant nanocavity length in QPD would strengthen ballistic phonon resonant transport, while varying nanocavity length in QPL lead to strong phonon scattering.
Acoustic superfocusing by solid phononic crystals
NASA Astrophysics Data System (ADS)
Zhou, Xiaoming; Assouar, M. Badreddine; Oudich, Mourad
2014-12-01
We propose a solid phononic crystal lens capable of acoustic superfocusing beyond the diffraction limit. The unit cell of the crystal is formed by four rigid cylinders in a hosting material with a cavity arranged in the center. Theoretical studies reveal that the solid lens produces both negative refraction to focus propagating waves and surface states to amplify evanescent waves. Numerical analyses of the superfocusing effect of the considered solid phononic lens are presented with a separated source excitation to the lens. In this case, acoustic superfocusing beyond the diffraction limit is evidenced. Compared to the fluid phononic lenses, the solid lens is more suitable for ultrasonic imaging applications.
Electron-phonon superconductivity in YIn3
NASA Astrophysics Data System (ADS)
Billington, D.; Llewellyn-Jones, T. M.; Maroso, G.; Dugdale, S. B.
2013-08-01
First-principles calculations of the electron-phonon coupling were performed on the cubic intermetallic compound YIn3. The electron-phonon coupling constant was found to be λep = 0.42. Using the Allen-Dynes formula with a Coulomb pseudopotential of μ* = 0.10, a Tc of approximately 0.77 K is obtained which is reasonably consistent with the experimentally observed temperature (between 0.8 and 1.1 K). The results indicate that conventional electron-phonon coupling is capable of producing the superconductivity in this compound.
One-dimensional hypersonic phononic crystals.
Gomopoulos, N; Maschke, D; Koh, C Y; Thomas, E L; Tremel, W; Butt, H-J; Fytas, G
2010-03-10
We report experimental observation of a normal incidence phononic band gap in one-dimensional periodic (SiO(2)/poly(methyl methacrylate)) multilayer film at gigahertz frequencies using Brillouin spectroscopy. The band gap to midgap ratio of 0.30 occurs for elastic wave propagation along the periodicity direction, whereas for inplane propagation the system displays an effective medium behavior. The phononic properties are well captured by numerical simulations. The porosity in the silica layers presents a structural scaffold for the introduction of secondary active media for potential coupling between phonons and other excitations, such as photons and electrons.
Yudistira, D; Boes, A; Djafari-Rouhani, B; Pennec, Y; Yeo, L Y; Mitchell, A; Friend, J R
2014-11-21
We theoretically and experimentally demonstrate the existence of complete surface acoustic wave band gaps in surface phonon-polariton phononic crystals, in a completely monolithic structure formed from a two-dimensional honeycomb array of hexagonal shape domain-inverted inclusions in single crystal piezoelectric Z-cut lithium niobate. The band gaps appear at a frequency of about twice the Bragg band gap at the center of the Brillouin zone, formed through phonon-polariton coupling. The structure is mechanically, electromagnetically, and topographically homogeneous, without any physical alteration of the surface, offering an ideal platform for many acoustic wave applications for photonics, phononics, and microfluidics.
Electron-phonon superconductivity in BaSn5
NASA Astrophysics Data System (ADS)
Billington, David; Ernsting, David; Millichamp, Thomas E.; Dugdale, Stephen B.
2015-05-01
First-principles calculations of the electronic structure and phonon dispersion relation of the superconducting compound ? were performed. This has allowed the calculation of the electron-phonon matrix elements from which the electron-phonon coupling constant was found to be ?. Application of the Allen-Dynes formula with ? yielded a superconducting transition temperature of ? K. The calculated ? agrees well with the available experimental data and indicates that ? is an electron-phonon superconductor with intermediate strength electron-phonon coupling.
Phonon transport in silicon nanowires: The reduced group velocity and surface-roughness scattering
NASA Astrophysics Data System (ADS)
Zhu, Liyan; Li, Baowen; Li, Wu
2016-09-01
Using a linear-scaling Kubo simulation approach, we have quantitatively investigated the effects of confinement and surface roughness on phonon transport in silicon nanowires (SiNWs) as thick as 55 nm in diameter R . The confinement effect leads to significant reduction of phonon group velocity v in SiNWs compared to bulk silicon except at extremely low phonon frequencies f , which very likely persists in SiNWs several hundreds of nanometers thick, suggesting the inapplicability of bulk properties, including anharmonic phonon scattering, to SiNWs. For instance, the velocity can be reduced by more than 30% for phonons with f >4.5 THz in 55-nm-thick nanowires. In rough SiNWs Casimir's limit, which is valid in confined macroscopic systems, can underestimate the surface scattering by more than one order of magnitude. For a roughness profile with Lorentzian correlation characterized by root-mean-square roughness σ and correlation length Lr, the frequency-dependent phonon diffusivity D follows power-law dependences D ∝Rασ-βLrγ , where α ˜2 and β ˜1 . On average, γ increases from 0 to 0.5 as R /σ increases. The mean free path and the phonon lifetime essentially follow the same power-law dependences. These dependences are in striking contrast to Casimir's limit, i.e., D ˜v R /3 , and manifest the dominant role of the change in the number of atoms due to roughness. The thermal conductivity κ can vary by one order of magnitude with varying σ and Lr in SiNWs, and increasing σ and shortening Lr can efficiently lower κ below Casimir's limit by one order of magnitude. Our work provides different insights to understand the ultralow thermal conductivity of SiNWs reported experimentally and guidance to manipulate κ via surface roughness engineering.
Phonon assignments in GaN bulk
NASA Astrophysics Data System (ADS)
Kunert, H. W.
2004-07-01
The measured phonon-density of states of bulk GaN by time-of-flight neutron spectroscopy has been recently reported by Nipko et al. [CITE]. The authors have also calculated the true partial and total DOS as well as the phonon dispersion curves along major symmetry directions in the Brillouin zone. However, the group-theoretical phonon assignments have not been provided. Based on calculated symmetry allowed modes spanned by displacement representation and on the derived connectivity relations along the major directions in the Brillouin zone we have assigned Nipko's phonon dispersion curves to irreducible representations (species) of the C^46v (P63mc) space group of GaN.
Watching surface waves in phononic crystals.
Wright, Oliver B; Matsuda, Osamu
2015-08-28
In this paper, we review results obtained by ultrafast imaging of gigahertz surface acoustic waves in surface phononic crystals with one- and two-dimensional periodicities. By use of quasi-point-source optical excitation, we show how, from a series of images that form a movie of the travelling waves, the dispersion relation of the acoustic modes, their corresponding mode patterns and the position and widths of phonon stop bands can be obtained by temporal and spatio-temporal Fourier analysis. We further demonstrate how one can follow the temporal evolution of phononic eigenstates in k-space using data from phononic-crystal waveguides as an example. © 2015 The Author(s) Published by the Royal Society. All rights reserved.
Phonon limited electronic transport in Pb
NASA Astrophysics Data System (ADS)
Rittweger, F.; Hinsche, N. F.; Mertig, I.
2017-09-01
We present a fully ab initio based scheme to compute electronic transport properties, i.e. the electrical conductivity σ and thermopower S, in the presence of electron-phonon interaction. We explicitly investigate the \
Toward stimulated interaction of surface phonon polaritons
Kong, B. D.; Trew, R. J.; Kim, K. W.
2013-12-21
Thermal emission spectra mediated by surface phonon polariton are examined by using a theoretical model that accounts for generation processes. Specifically, the acoustic phonon fusion mechanism is introduced to remedy theoretical deficiencies of the near thermal equilibrium treatments. The model clarifies the thermal excitation mechanism of surface phonon polaritons and the energy transfer path under non-zero energy flow. When applied to GaAs and SiC semi-infinite surfaces, the nonequilibrium model predicts that the temperature dependence of the quasi-monochromatic peak can exhibit distinctly different characteristics of either sharp increase or slow saturation depending on the materials, which is in direct contrast with the estimate made by the near-equilibrium model. The proposed theoretical tool can accurately analyze the nonequilibrium steady states, potentially paving a pathway to demonstrate stimulated interaction/emission of thermally excited surface phonon polaritons.
Toward stimulated interaction of surface phonon polaritons
NASA Astrophysics Data System (ADS)
Kong, B. D.; Trew, R. J.; Kim, K. W.
2013-12-01
Thermal emission spectra mediated by surface phonon polariton are examined by using a theoretical model that accounts for generation processes. Specifically, the acoustic phonon fusion mechanism is introduced to remedy theoretical deficiencies of the near thermal equilibrium treatments. The model clarifies the thermal excitation mechanism of surface phonon polaritons and the energy transfer path under non-zero energy flow. When applied to GaAs and SiC semi-infinite surfaces, the nonequilibrium model predicts that the temperature dependence of the quasi-monochromatic peak can exhibit distinctly different characteristics of either sharp increase or slow saturation depending on the materials, which is in direct contrast with the estimate made by the near-equilibrium model. The proposed theoretical tool can accurately analyze the nonequilibrium steady states, potentially paving a pathway to demonstrate stimulated interaction/emission of thermally excited surface phonon polaritons.
Stationary Phonon Squeezing by Optical Polaron Excitation
NASA Astrophysics Data System (ADS)
Papenkort, T.; Axt, V. M.; Kuhn, T.
2017-03-01
We demonstrate that a stationary squeezed phonon state can be prepared by a pulsed optical excitation of a semiconductor quantum well. Unlike previously discussed scenarios for generating squeezed phonons, the corresponding uncertainties become stationary after the excitation and do not oscillate in time. The effect is caused by two-phonon correlations within the excited polaron. We demonstrate by quantum kinetic simulations and by a perturbation analysis that the energetically lowest polaron state comprises two-phonon correlations which, after the pulse, result in an uncertainty of the lattice momentum that is continuously lower than in the ground state of the semiconductor. The simulations show the dynamics of the polaron formation process and the resulting time-dependent lattice uncertainties.
Characterizing phonon dynamics using stochastic sampling
Kunal, K.; Aluru, N. R.
2016-03-21
Predicting phonon relaxation time from molecular dynamics (MD) requires a long simulation time to compute the mode energy auto-correlation function. Here, we present an alternative approach to infer the phonon life-time from an approximate form of the energy auto-correlation function. The method requires as an input a set of sampled equilibrium configurations. A stochastic sampling method is used to generate the equilibrium configurations. We consider a truncated Taylor series expansion of the phonon energy auto-correlation function. The different terms in the truncated correlation function are obtained using the stochastic sampling approach. The expansion terms, thus, obtained are in good agreement with the corresponding values obtained using MD. We then use the approximate function to compute the phonon relaxation time. The relaxation time computed using this method is compared with that obtained from the exact correlation function. The two values are in agreement with each other.
Phonon stop bands in amorphous superlattices
NASA Astrophysics Data System (ADS)
Koblinger, O.; Mebert, J.; Dittrich, E.; Döttinger, S.; Eisenmenger, W.; Santos, P. V.; Ley, L.
1987-06-01
In periodically layered media the phonon-dispersion relation shows energy ranges in which phonon propagation is not possible. The existence of such phonon stop bands in crystalline superlattices has been observed in work by V. Narayanamurti, H. L. Störmer, M. A. Chin, A. C. Gossard, and W. Wiegman [Phys. Rev. Lett. 43, 2012 (1979)]. In this Communication we report the observation of phonon stop bands in amorphous superlattices. The filter characteristic of these amorphous superlattices is much sharper than in the case of the crystalline superlattices studied earlier. The investigated superlattices have been prepared by alternating evaporation of Si and SiO2 layers as well as by plasma-enhanced chemical vapor deposition of a-Si:H/a-SiNx:H films in a glow-discharge reactor.
Glass-like phonon scattering from a spontaneous nanostructure in AgSbTe2
Ma, J.; Delaire, O.; May, A. F.; Carlton, C. E.; McGuire, M. A.; VanBebber, L. H.; Abernathy, D. L.; Ehlers, G.; Hong, Tao; Huq, A.; Tian, Wei; Keppens, V. M.; Shao-Horn, Y.; Sales, B. C.
2013-06-02
Materials with very low thermal conductivity are of high interest for both thermoelectric and optical phase-change applications. Synthetic nanostructuring is most promising to suppress thermal conductivity by scattering phonons, but challenges remain in producing bulk samples. We show that in crystalline AgSbTe2, a spontaneously-forming nanostructure leads to a suppression of thermal conductivity to a glass-like level. Our mappings of phonon mean-free-paths provide a novel bottom- up microscopic account of thermal conductivity, and also reveal intrinsic anisotropies associated with the nanostructure. Ground-state degeneracy in AgSbTe2 leads to the natural formation of nanoscale domains with different orderings on the cation sublattice, and correlated atomic displacements, which efficiently scatter phonons. This mechanism is general and points to a new avenue in nano- scale engineering of materials, to achieve low thermal conductivities for efficient thermoelectric converters and phase-change memory devices.
Exciton dynamics within the band-edge manifold states: the onset of an acoustic phonon bottleneck.
Rainò, Gabriele; Moreels, Iwan; Hassinen, Antti; Stöferle, Thilo; Hens, Zeger; Mahrt, Rainer F
2012-10-10
Exciton dynamics within the band-edge state manifold of CdSe/ZnS and CdSe/CdS quantum dots (QDs) have been investigated. Low-temperature time-resolved photoluminescence (PL) experiments demonstrate that exciton relaxation is mediated by LO phonons, whereas an acoustic phonon bottleneck is observed for splitting energies lower than the optical phonon energy. This has important implications since the main source affecting exciton dephasing is considered to be a spin-flip process. Our results concur with recent observations of long exciton dephasing times in CdSe/CdS QDs and show a way to engineer nanoparticles with enhanced coherence time, a prerequisite for their use in quantum optical applications.
The role of anharmonic phonons in under-barrier spin relaxation of single molecule magnets
NASA Astrophysics Data System (ADS)
Lunghi, Alessandro; Totti, Federico; Sessoli, Roberta; Sanvito, Stefano
2017-03-01
The use of single molecule magnets in mainstream electronics requires their magnetic moment to be stable over long times. One can achieve such a goal by designing compounds with spin-reversal barriers exceeding room temperature, namely with large uniaxial anisotropies. Such strategy, however, has been defeated by several recent experiments demonstrating under-barrier relaxation at high temperature, a behaviour today unexplained. Here we propose spin-phonon coupling to be responsible for such anomaly. With a combination of electronic structure theory and master equations we show that, in the presence of phonon dissipation, the relevant energy scale for the spin relaxation is given by the lower-lying phonon modes interacting with the local spins. These open a channel for spin reversal at energies lower than that set by the magnetic anisotropy, producing fast under-barrier spin relaxation. Our findings rationalize a significant body of experimental work and suggest a possible strategy for engineering room temperature single molecule magnets.
Dexterous acoustic trapping and patterning of particles assisted by phononic crystal plate
Wang, Tian; Ke, Manzhu Xu, Shengjun; Feng, Junheng; Qiu, Chunyin; Liu, Zhengyou
2015-04-20
In this letter, we present experimental demonstration of multi-particles trapping and patterning by the artificially engineered acoustic field of phononic crystal plate. Polystyrene particles are precisely trapped and patterned in two dimensional arrays, for example, the square, triangular, or quasi-periodic arrays, depending on the structures of the phononic crystal plates with varying sub-wavelength holes array. Analysis shows that the enhanced acoustic radiation force, induced by the resonant transmission field highly localized near the sub-wavelength apertures, accounts for the particles self-organizing. It can be envisaged that this kind of simple design of phononic crystal plates would pave an alternative route for self-assembly of particles and may be utilized in the lab-on-a-chip devices.
The role of anharmonic phonons in under-barrier spin relaxation of single molecule magnets.
Lunghi, Alessandro; Totti, Federico; Sessoli, Roberta; Sanvito, Stefano
2017-03-06
The use of single molecule magnets in mainstream electronics requires their magnetic moment to be stable over long times. One can achieve such a goal by designing compounds with spin-reversal barriers exceeding room temperature, namely with large uniaxial anisotropies. Such strategy, however, has been defeated by several recent experiments demonstrating under-barrier relaxation at high temperature, a behaviour today unexplained. Here we propose spin-phonon coupling to be responsible for such anomaly. With a combination of electronic structure theory and master equations we show that, in the presence of phonon dissipation, the relevant energy scale for the spin relaxation is given by the lower-lying phonon modes interacting with the local spins. These open a channel for spin reversal at energies lower than that set by the magnetic anisotropy, producing fast under-barrier spin relaxation. Our findings rationalize a significant body of experimental work and suggest a possible strategy for engineering room temperature single molecule magnets.
Phonon broadening in high entropy alloys
NASA Astrophysics Data System (ADS)
Körmann, Fritz; Ikeda, Yuji; Grabowski, Blazej; Sluiter, Marcel H. F.
2017-09-01
Refractory high entropy alloys feature outstanding properties making them a promising materials class for next-generation high-temperature applications. At high temperatures, materials properties are strongly affected by lattice vibrations (phonons). Phonons critically influence thermal stability, thermodynamic and elastic properties, as well as thermal conductivity. In contrast to perfect crystals and ordered alloys, the inherently present mass and force constant fluctuations in multi-component random alloys (high entropy alloys) can induce significant phonon scattering and broadening. Despite their importance, phonon scattering and broadening have so far only scarcely been investigated for high entropy alloys. We tackle this challenge from a theoretical perspective and employ ab initio calculations to systematically study the impact of force constant and mass fluctuations on the phonon spectral functions of 12 body-centered cubic random alloys, from binaries up to 5-component high entropy alloys, addressing the key question of how chemical complexity impacts phonons. We find that it is crucial to include both mass and force constant fluctuations. If one or the other is neglected, qualitatively wrong results can be obtained such as artificial phonon band gaps. We analyze how the results obtained for the phonons translate into thermodynamically integrated quantities, specifically the vibrational entropy. Changes in the vibrational entropy with increasing the number of elements can be as large as changes in the configurational entropy and are thus important for phase stability considerations. The set of studied alloys includes MoTa, MoTaNb, MoTaNbW, MoTaNbWV, VW, VWNb, VWTa, VWNbTa, VTaNbTi, VWNbTaTi, HfZrNb, HfMoTaTiZr.
Phonon Cooling by an Optomechanical Heat Pump.
Dong, Ying; Bariani, F; Meystre, P
2015-11-27
We propose and analyze theoretically a cavity optomechanical analog of a heat pump that uses a polariton fluid to cool mechanical modes coupled to a single precooled phonon mode via external modulation of the substrate of the mechanical resonator. This approach permits us to cool phonon modes of arbitrary frequencies not limited by the cavity-optical field detuning deep into the quantum regime from room temperature.
Slow light and broadband coherent phonon generation
NASA Astrophysics Data System (ADS)
Wang, Zheng; Rakich, Peter; Reinke, Charles; Camacho, Ryan; Davids, Paul
2012-03-01
Recent advance in controlling optical forces using nanostructures suggests that nanoscale optical waveguides are capable of generating coherent acoustic phonons efficiently through a combination of radiation pressure and electrostriction. We discuss the critical roles of group velocity in such processes. This photon-phonon coupling would allow an acoustic intermediary to perform on-chip optical delay with a capacity 105 greater than photonic delay lines of the same size.
NASA Astrophysics Data System (ADS)
Biroju, Ravi K.; Giri, P. K.
2017-07-01
Fabrication and optoelectronic applications of graphene based hybrid 2D-1D semiconductor nanostructures have gained tremendous research interest in recent times. Herein, we present a systematic study on the origin and evolution of strong broad band visible and near infrared (NIR) photoluminescence (PL) from vertical ZnO nanorods (NRs) and nanowires (NWs) grown on single layer graphene using both above band gap and sub-band gap optical excitations. High resolution field emission scanning electron microscopy and X-ray diffraction studies are carried out to reveal the morphology and crystalline quality of as-grown and annealed ZnO NRs/NWs on graphene. Room temperature PL studies reveal that besides the UV and visible PL bands, a new near-infrared (NIR) PL emission band appears in the range between 815 nm and 886 nm (1.40-1.52 eV). X-ray photoelectron spectroscopy studies revealed excess oxygen content and unreacted metallic Zn in the as-grown ZnO nanostructures, owing to the low temperature growth by a physical vapor deposition method. Post-growth annealing at 700 °C in the Ar gas ambient results in the enhanced intensity of both visible and NIR PL bands. On the other hand, subsequent high vacuum annealing at 700 °C results in a drastic reduction in the visible PL band and complete suppression of the NIR PL band. PL decay dynamics of green emission in Ar annealed samples show tri-exponential decay on the nanosecond timescale including a very slow decay component (time constant ˜604.5 ns). Based on these results, the NIR PL band comprising two peaks centered at ˜820 nm and ˜860 nm is tentatively assigned to neutral and negatively charged oxygen interstitial (Oi) defects in ZnO, detected experimentally for the first time. The evidence for oxygen induced trap states on the ZnO NW surface is further substantiated by the slow photocurrent response of graphene-ZnO NRs/NWs. These results are important for tunable light emission, photodetection, and other cutting edge
Wang, Jing; Chen, Di; Wallace, Joseph; Gigax, Jonathan; Wang, Xuemei; Shao, Lin
2014-05-12
Through integrated molecular dynamics (MD) simulations and experimental studies, we demonstrated the feasibility of an ion-irradiation-and-annealing based phonon engineering technique to enhance thermal conductivity of carbon nanotube (CNT) films. Upon ion irradiation of CNT films, both inter-tube defects and intra-tube defects are introduced. Our MD simulations show that inter-tube defects created between neighboring tubes are much more stable than intra-tube defects created on tube graphitic planes. Upon thermal annealing, intra-tube defects are preferentially removed but inter-tube defects stay. Consequently, axial phonon transport increases due to reduced phonon scattering and off-axial phonon transport is sustained due to the high stability of inter-tube defects, leading to a conductivity enhancement upon annealing. The modeling predictions agree with experimental observations that thermal conductivities of CNT films were enhanced after 2 MeV hydrogen ion irradiations and conductivities were further enhanced upon post irradiation annealing.
Ab initio phonon limited transport
NASA Astrophysics Data System (ADS)
Verstraete, Matthieu
We revisit the thermoelectric (TE) transport properties of two champion materials, PbTe and SnSe, using fully first principles methods. In both cases the performance of the material is due to subtle combinations of structural effects, scattering, and phase space reduction. In PbTe anharmonic effects are completely opposite to the predicted quasiharmonic evolution of phonon frequencies and to frequently (and incorrectly) cited extrapolations of experiments. This stabilizes the material at high T, but also tends to enhance its thermal conductivity, in a non linear manner, above 600 Kelvin. This explains why PbTe is in practice limited to room temperature applications. SnSe has recently been shown to be the most efficient TE material in bulk form. This is mainly due to a strongly enhanced carrier concentration and electrical conductivity, after going through a phase transition from 600 to 800 K. We calculate the transport coefficients as well as the defect concentrations ab initio, showing excellent agreement with experiment, and elucidating the origin of the double phase transition as well as the new charge carriers. AH Romero, EKU Gross, MJ Verstraete, and O Hellman PRB 91, 214310 (2015) O. Hellman, IA Abrikosov, and SI Simak, PRB 84 180301 (2011)
Squeezed Phonons: Modulating Quantum Fluctuations of Atomic Displacements.
NASA Astrophysics Data System (ADS)
Hu, Xuedong; Nori, Franco
1997-03-01
We have studied phonon squeezed states and also put forward several proposals for their generation(On phonon parametric process, X. Hu and F. Nori, Phys. Rev. Lett. 76), 2294 (1996); on polariton mechanism, X. Hu and F. Nori, Phys. Rev. B 53, 2419 (1996); on second-order Raman scattering, X. Hu and F. Nori, preprint.. Here, we compare the relative merits and limitations of these approaches, including several factors that will limit the amount of phonon squeezing. In particular, we investigate the effect of the initial thermal states on the phonon modes. Using a model for the phonon density matrix, we also study the mixing of the phonon squeezed states with thermal states, which describes the decay of the phonon coherence. Finally, we calculate the maximum possible squeezing from a phonon parametric process limited by phonon decay.
Lüer, Larry; Gadermaier, Christoph; Crochet, Jared; Hertel, Tobias; Brida, Daniele; Lanzani, Guglielmo
2009-03-27
We excite and detect coherent phonons in semiconducting (6,5) carbon nanotubes via a sub-10-fs pump-probe technique. Simulation of the amplitude and phase profile via time-dependent wave packet theory yields excellent agreement with experimental results under the assumption of molecular excitonic states and allows determining the electron-phonon coupling strength for the two dominant vibrational modes.
NASA Astrophysics Data System (ADS)
Rury, Aaron S.
2016-06-01
This study reports experimental, computational, and theoretical evidence for a previously unobserved coherent phonon-phonon interaction in an organic solid that can be described by the application of Fano's analysis to a case without the presence of a continuum. Using Raman spectroscopy of the hydrogen-bonded charge-transfer material quinhydrone, two peaks appear near 700 cm-1 we assign as phonons whose position and line-shape asymmetry depend on the sample temperature and light scattering excitation energy. Density functional theory calculations find two nearly degenerate phonons possessing frequencies near the values found in experiment that share similar atomic motion out of the aromatic plane of electron donor and acceptor molecules of quinhydrone. Further analytical modeling of the steady-state light scattering process using the Peierls-Hubbard Hamiltonian and time-dependent perturbation theory motivates assignment of the physical origin of the asymmetric features of each peak's line shape to an interaction between two discrete phonons via nonlinear electron-phonon coupling. In the context of analytical model results, characteristics of the experimental spectra upon 2.33 eV excitation of the Raman scattering process are used to qualify the temperature dependence of the magnitude of this coupling in the valence band of quinhydrone. These results broaden the range of phonon-phonon interactions in materials in general while also highlighting the rich physics and fundamental attributes specific to organic solids that may determine their applicability in next generation electronics and photonics technologies.
Non-equilibrium Phonons in CaWO4: Issues for Phonon Mediated Particle Detectors
NASA Astrophysics Data System (ADS)
Msall, Madeleine; Head, Timothy; Jumper, Daniel
2009-03-01
The CRESST experiment looks for evidence of dark matter particles colliding with nuclei in CaWO4, using cryogenic bolometers sensitive to energy deposition ˜ 10 keV with a few percent accuracy. Calibration of the energy deposited in the phonon system depends upon the details of the evolution of the non-equilibrium energy in the CaWO4 absorber. Our phonon images sensitively measure variations in angular phonon flux, providing key information about the elastic constants and scattering rates that determine the energy evolution. Phonon pulses, created by focused photoexcitation of a 150 nm Cu film, are detected after propagation through 3 mm of CaWO4. The 20 ns Ar-ion laser pulse creates a localized (10-3 mm^2) source of 10-20 K blackbody phonons. The sample is at 2 K. Our images show that the elastic constants derived from ultrasonic velocities along high symmetry axes do not accurately predict the total phonon flux along non-symmetry directions. We present new data on the dependence of phonon flux on excitation level and discuss the influence of isotope and anharmonic decay on the shape of phonon pulses in these ultrapure samples. Thanks to J.P. Wolfe and the Frederick Seitz Materials Research Laboratory, Urbana, IL, for partial support of this work.
Alaie, Seyedhamidreza; Goettler, Drew F; Su, Mehmet; Leseman, Zayd C; Reinke, Charles M; El-Kady, Ihab
2015-06-24
Large reductions in the thermal conductivity of thin silicon membranes have been demonstrated in various porous structures. However, the role of coherent boundary scattering in such structures has become a matter of some debate. Here we report on the first experimental observation of coherent phonon boundary scattering at room temperature in 2D phononic crystals formed by the introduction of air holes in a silicon matrix with minimum feature sizes >100 nm. To delaminate incoherent from coherent boundary scattering, phononic crystals with a fixed minimum feature size, differing only in unit cell geometry, were fabricated. A suspended island technique was used to measure the thermal conductivity. We introduce a hybrid thermal conductivity model that accounts for partially coherent and partially incoherent phonon boundary scattering. We observe excellent agreement between this model and experimental data, and the results suggest that significant room temperature coherent phonon boundary scattering occurs.
Seeing the invisible plasma with transient phonons in cuprous oxide
Frazer, Laszlo; Schaller, Richard D.; Chang, Kelvin B.; ...
2016-12-12
Here, the emission of phonons from electron–hole plasma is the primary limit on the efficiency of photovoltaic devices operating above the bandgap. In cuprous oxide (Cu2O) there is no luminescence from electron–hole plasma. Therefore, we searched for optical phonons emitted by energetic charge carriers using phonon-to-exciton upconversion transitions. We found 14 meV phonons with a lifetime of 0.916 ± 0.008 ps and 79 meV phonons that are longer lived and overrepresented. It is surprising that the higher energy phonon has a longer lifetime.
Seeing the invisible plasma with transient phonons in cuprous oxide
Frazer, Laszlo; Schaller, Richard D.; Chang, Kelvin B.; Chernatynskiy, Aleksandr; Poeppelmeier, Kenneth R.
2016-12-12
Here, the emission of phonons from electron–hole plasma is the primary limit on the efficiency of photovoltaic devices operating above the bandgap. In cuprous oxide (Cu_{2}O) there is no luminescence from electron–hole plasma. Therefore, we searched for optical phonons emitted by energetic charge carriers using phonon-to-exciton upconversion transitions. We found 14 meV phonons with a lifetime of 0.916 ± 0.008 ps and 79 meV phonons that are longer lived and overrepresented. It is surprising that the higher energy phonon has a longer lifetime.
Phonon Recycling for Ultrasensitive Kinetic Inductance Detectors
NASA Astrophysics Data System (ADS)
Zmuidzinas, Jonas
Initially proposed (Day et al. 2003; Zmuidzinas 2012) in 1999 by our Caltech/JPL group, and thanks to strong support from NASA, the superconducting (microwave) kinetic inductance detector (MKID or KID) technology continues to develop rapidly as it transitions into applications. The development effort worldwide is intensifying and NASA's continued support of KID development is essential in order to keep pace. Here we propose to investigate and demonstrate a new, low-TRL concept, which we call phonon recycling, that promises to open broad new avenues in KID design and performance. Briefly, phonon recycling allows the detector designer to tailor the responsivity and sensitivity of a KID to match the needs of the application by using geometry to restrict the rate at which recombination phonons are allowed to escape from the detector. In particular, phonon recycling should allow very low noise-equivalent power (NEP) to be achieved without requiring very low operating tem- peratures. Phonon recycling is analogous to the use of micromachined suspension legs to control the flow of heat in a bolometer, as measured by the thermal conductivity G. However, phonon recycling exploits the non-thermal distribution of recombination phonons as well as their very slow decay in crystals at low temperatures. These properties translate to geometrical and mechanical requirements for a phonon-recycled KID that are considerably more relaxed than for a bolometer operating at the same temperature and NEP. Our ultimate goal is to develop detector arrays suitable for a far-infrared (FIR) space mission, which will impose strict requirements on the array sensitivity, yield, uniformity, multiplexing density, etc. Through previous NASA support under the Strategic Astrophysics Technology (SAT) program, we have successfully demonstrated the MAKO submillimeter camera at the Caltech Submillimeter Observatory and have become familiar with these practical issues. If our demonstration of phonon recycling
Symmetry-adapted phonon analysis of nanotubes
NASA Astrophysics Data System (ADS)
Aghaei, Amin; Dayal, Kaushik; Elliott, Ryan S.
2013-02-01
The characteristics of phonons, i.e. linearized normal modes of vibration, provide important insights into many aspects of crystals, e.g. stability and thermodynamics. In this paper, we use the Objective Structures framework to make concrete analogies between crystalline phonons and normal modes of vibration in non-crystalline but highly symmetric nanostructures. Our strategy is to use an intermediate linear transformation from real-space to an intermediate space in which the Hessian matrix of second derivatives is block-circulant. The block-circulant nature of the Hessian enables us to then follow the procedure to obtain phonons in crystals: namely, we use the Discrete Fourier Transform from this intermediate space to obtain a block-diagonal matrix that is readily diagonalizable. We formulate this for general Objective Structures and then apply it to study carbon nanotubes of various chiralities that are subjected to axial elongation and torsional deformation. We compare the phonon spectra computed in the Objective Framework with spectra computed for armchair and zigzag nanotubes. We also demonstrate the approach by computing the Density of States. In addition to the computational efficiency afforded by Objective Structures in providing the transformations to almost-diagonalize the Hessian, the framework provides an important conceptual simplification to interpret the phonon curves. Our findings include that, first, not all non-optic long-wavelength modes are zero energy and conversely not all zero energy modes are long-wavelength; second, the phonon curves accurately predict both the onset as well as the soft modes for instabilities such as torsional buckling; and third, unlike crystals where phonon stability does not provide information on stability with respect to non-rank-one deformation modes, phonon stability in nanotubes is sufficient to guarantee stability with respect to all perturbations that do not involve structural modes. Our finding of characteristic
Ionizing particle detection based on phononic crystals
NASA Astrophysics Data System (ADS)
Aly, Arafa H.; Mehaney, Ahmed; Eissa, Mostafa F.
2015-08-01
Most conventional radiation detectors are based on electronic or photon collections. In this work, we introduce a new and novel type of ionizing particle detector based on phonon collection. Helium ion radiation treats tumors with better precision. There are nine known isotopes of helium, but only helium-3 and helium-4 are stable. Helium-4 is formed in fusion reactor technology and in enormous quantities during Big Bang nucleo-synthesis. In this study, we introduce a technique for helium-4 ion detection (sensing) based on the innovative properties of the new composite materials known as phononic crystals (PnCs). PnCs can provide an easy and cheap technique for ion detection compared with conventional methods. PnC structures commonly consist of a periodic array of two or more materials with different elastic properties. The two materials are polymethyl-methacrylate and polyethylene polymers. The calculations showed that the energies lost to target phonons are maximized at 1 keV helium-4 ion energy. There is a correlation between the total phonon energies and the transmittance of PnC structures. The maximum transmission for phonons due to the passage of helium-4 ions was found in the case of making polyethylene as a first layer in the PnC structure. Therefore, the concept of ion detection based on PnC structure is achievable.
Ionizing particle detection based on phononic crystals
Aly, Arafa H. E-mail: arafa.hussien@science.bsu.edu.eg; Mehaney, Ahmed; Eissa, Mostafa F.
2015-08-14
Most conventional radiation detectors are based on electronic or photon collections. In this work, we introduce a new and novel type of ionizing particle detector based on phonon collection. Helium ion radiation treats tumors with better precision. There are nine known isotopes of helium, but only helium-3 and helium-4 are stable. Helium-4 is formed in fusion reactor technology and in enormous quantities during Big Bang nucleo-synthesis. In this study, we introduce a technique for helium-4 ion detection (sensing) based on the innovative properties of the new composite materials known as phononic crystals (PnCs). PnCs can provide an easy and cheap technique for ion detection compared with conventional methods. PnC structures commonly consist of a periodic array of two or more materials with different elastic properties. The two materials are polymethyl-methacrylate and polyethylene polymers. The calculations showed that the energies lost to target phonons are maximized at 1 keV helium-4 ion energy. There is a correlation between the total phonon energies and the transmittance of PnC structures. The maximum transmission for phonons due to the passage of helium-4 ions was found in the case of making polyethylene as a first layer in the PnC structure. Therefore, the concept of ion detection based on PnC structure is achievable.
Phonon dynamics of graphene on metals
NASA Astrophysics Data System (ADS)
Taleb, Amjad Al; Farías, Daniel
2016-03-01
The study of surface phonon dispersion curves is motivated by the quest for a detailed understanding of the forces between the atoms at the surface and in the bulk. In the case of graphene, additional motivation comes from the fact that thermal conductivity is dominated by contributions from acoustic phonons, while optical phonon properties are essential to understand Raman spectra. In this article, we review recent progress made in the experimental determination of phonon dispersion curves of graphene grown on several single-crystal metal surfaces. The two main experimental techniques usually employed are high-resolution electron energy loss spectroscopy (HREELS) and inelastic helium atom scattering (HAS). The different dispersion branches provide a detailed insight into the graphene-substrate interaction. Softening of optical modes and signatures of the substrate‧s Rayleigh wave are observed for strong graphene-substrate interactions, while acoustic phonon modes resemble those of free-standing graphene for weakly interacting systems. The latter allows determining the bending rigidity and the graphene-substrate coupling strength. A comparison between theory and experiment is discussed for several illustrative examples. Perspectives for future experiments are discussed.
Atomistic modeling of phonon transport in turbostratic graphitic structures
Mao, Rui; Chen, Yifeng; Kim, Ki Wook
2016-05-28
Thermal transport in turbostratic graphitic systems is investigated by using an atomistic analytical model based on the 4th-nearest-neighbor force constant approximation and a registry-dependent interlayer potential. The developed model is shown to produce an excellent agreement with the experimental data and ab initio results in the calculation of bulk properties. Subsequent analysis of phonon transport in combination with the Green's function method illustrates the significant dependence of key characteristics on the misorientation angle, clearly indicating the importance of this degree of freedom in multi-stacked structures. Selecting three angles with the smallest commensurate unit cells, the thermal resistance is evaluated at the twisted interface between two AB stacked graphite. The resulting values in the range of 35 × 10{sup −10} K m{sup 2}/W to 116 × 10{sup −10} K m{sup 2}/W are as large as those between two dissimilar material systems such as a metal and graphene. The strong rotational effect on the cross-plane thermal transport may offer an effective means of phonon engineering for applications such as thermoelectric materials.
Hierarchical thermoelectrics: crystal grain boundaries as scalable phonon scatterers
NASA Astrophysics Data System (ADS)
Selli, Daniele; Boulfelfel, Salah Eddine; Schapotschnikow, Philipp; Donadio, Davide; Leoni, Stefano
2016-02-01
Thermoelectric materials are strategically valuable for sustainable development, as they allow for the generation of electrical energy from wasted heat. In recent years several strategies have demonstrated some efficiency in improving thermoelectric properties. Dopants affect carrier concentration, while thermal conductivity can be influenced by alloying and nanostructuring. Features at the nanoscale positively contribute to scattering phonons, however those with long mean free paths remain difficult to alter. Here we use the concept of hierarchical nano-grains to demonstrate thermal conductivity reduction in rocksalt lead chalcogenides. We demonstrate that grains can be obtained by taking advantage of the reconstructions along the phase transition path that connects the rocksalt structure to its high-pressure form. Since grain features naturally change as a function of size, they impact thermal conductivity over different length scales. To understand this effect we use a combination of advanced molecular dynamics techniques to engineer grains and to evaluate thermal conductivity in PbSe. By affecting grain morphologies only, i.e. at constant chemistry, two distinct effects emerge: the lattice thermal conductivity is significantly lowered with respect to the perfect crystal, and its temperature dependence is markedly suppressed. This is due to an increased scattering of low-frequency phonons by grain boundaries over different size scales. Along this line we propose a viable process to produce hierarchical thermoelectric materials by applying pressure via a mechanical load or a shockwave as a novel paradigm for material design.
Hierarchical thermoelectrics: crystal grain boundaries as scalable phonon scatterers.
Selli, Daniele; Boulfelfel, Salah Eddine; Schapotschnikow, Philipp; Donadio, Davide; Leoni, Stefano
2016-02-14
Thermoelectric materials are strategically valuable for sustainable development, as they allow for the generation of electrical energy from wasted heat. In recent years several strategies have demonstrated some efficiency in improving thermoelectric properties. Dopants affect carrier concentration, while thermal conductivity can be influenced by alloying and nanostructuring. Features at the nanoscale positively contribute to scattering phonons, however those with long mean free paths remain difficult to alter. Here we use the concept of hierarchical nano-grains to demonstrate thermal conductivity reduction in rocksalt lead chalcogenides. We demonstrate that grains can be obtained by taking advantage of the reconstructions along the phase transition path that connects the rocksalt structure to its high-pressure form. Since grain features naturally change as a function of size, they impact thermal conductivity over different length scales. To understand this effect we use a combination of advanced molecular dynamics techniques to engineer grains and to evaluate thermal conductivity in PbSe. By affecting grain morphologies only, i.e. at constant chemistry, two distinct effects emerge: the lattice thermal conductivity is significantly lowered with respect to the perfect crystal, and its temperature dependence is markedly suppressed. This is due to an increased scattering of low-frequency phonons by grain boundaries over different size scales. Along this line we propose a viable process to produce hierarchical thermoelectric materials by applying pressure via a mechanical load or a shockwave as a novel paradigm for material design.
Phonon and magnon heat transport and drag effects
NASA Astrophysics Data System (ADS)
Heremans, Joseph P.
2014-03-01
Thermoelectric generators and coolers constitute today's solid-state energy converters. The two goals in thermoelectrics research are to enhance the thermopower while simultaneously maintaining a high electrical conductivity of the same material, and to minimize its lattice thermal conductivity without affecting its electronic properties. Up to now the lattice thermal conductivity has been minimized by using alloy scattering and, more recently, nanostructuring. In the first part of the talk, a new approach to minimize the lattice thermal conductivity is described that affects phonon scattering much more than electron scattering. This can be done by selecting potential thermoelectric materials that have a very high anharmonicity, because this property governs phonon-phonon interaction probability. Several possible types of chemical bonds will be described that exhibit such high anharmonicity, and particular emphasis will be put on solids with highly-polarizable lone-pair electrons, such as the rock salt I-V-VI2 compounds (e.g. NaSbSe2). The second part of the talk will give an introduction to a completely new class of solid-state thermal energy converters based on spin transport. One configuration for such energy converters is based on the recently discovered spin-Seebeck effect (SSE). This quantity is expressed in the same units as the conventional thermopower, and we have recently shown that it can be of the same order of magnitude. The main advantage of SSE converters is that the problem of optimization is now distributed over two different materials, a ferromagnet in which a flux of magnetization is generated by a thermal gradient, and a normal metal where the flux of magnetization is converted into electrical power. The talk will focus on the basic physics behind the spin-Seebeck effect. Recent developments will then be described based on phonon-drag of spin polarized electrons. This mechanism has made it possible to reach magnitudes of SSE that are comparable
Kuleyev, I. G. Kuleyev, I. I.; Bakharev, S. M.; Ustinov, V. V.
2016-09-15
We study the effect of anisotropy in elastic properties on the electron–phonon drag and thermoelectric phenomena in gapless semiconductors with degenerate charge-carrier statistics. It is shown that phonon focusing leads to a number of new effects in the drag thermopower at low temperatures, when diffusive phonon scattering from the boundaries is the predominant relaxation mechanism. We analyze the effect of phonon focusing on the dependences of the thermoelectromotive force (thermopower) in HgSe:Fe crystals on geometric parameters and the heat-flow directions relative to the crystal axes in the Knudsen regime of the phonon gas flow. The crystallographic directions that ensure the maximum and minimum values of the thermopower are determined and the role of quasi-longitudinal and quasi-transverse phonons in the drag thermopower in HgSe:Fe crystals at low temperatures is analyzed. It is shown that the main contribution to the drag thermopower comes from slow quasi-transverse phonons in the directions of focusing in long samples.
NASA Astrophysics Data System (ADS)
Tea, Eric; Hamzeh, Hani; Aniel, Frédéric
2011-12-01
We present a study of the photo-excited charge carriers relaxation dynamics in polar semiconductors comparing calculations to pump probe experiments. Hot carrier densities in the 1018cm-3 range can easily be photo-generated using moderately intense optical excitations. This can lead to known phenomena, namely, hot phonon populations and the coupling of polar optical phonons with plasmon modes. However, these two phenomena can affect the hot carriers relaxation and have never been examined together. This is a problem for the theoretical study of future Hot Carrier Solar Cells, where the conditions allow both of these phenomena to occur. The charge carriers dynamics and the coupling of polar optical phonons with plasmon modes are treated by a Full Band Ensemble Monte Carlo simulation code featuring a self-consistent dielectric function. To take into consideration hot phonon populations and the subsequent phonon bottleneck for the carriers relaxation, the charge carriers simulation code is coupled to a phonon dedicated Ensemble Monte Carlo code. This enables for the first time an accurate study of both the charge carriers and phonon systems dynamics, the latter being most of the time overly simplified in previous studies. The present work explores to which extent the two aforementioned phenomena affect the photo-generated charge carriers relaxation in GaAs and can be easily adapted to other polar semiconductors.
Luo, Yixiu; Wang, Jiemin; Li, Yiran; Wang, Jingyang
2016-01-01
Modification of lattice thermal conductivity (κL) of a solid by means of hydrostatic pressure (P) has been a crucially interesting approach that targets a broad range of advanced materials from thermoelectrics and thermal insulators to minerals in mantle. Although it is well documented knowledge that thermal conductivity of bulk materials normally increase upon hydrostatic pressure, such positive relationship is seriously challenged when it comes to ceramics with complex crystal structure and heterogeneous chemical bonds. In this paper, we predict an abnormally negative trend dκL/dP < 0 in Y2Si2O7 silicate using density functional theoretical calculations. The mechanism is disclosed as combined effects of slightly decreased group velocity and significantly augmented scattering of heat-carrying acoustic phonons in pressured lattice, which is originated from pressure-induced downward shift of low-lying optic and acoustic phonons. The structural origin of low-lying optic phonons as well as the induced phonon anharmonicity is also qualitatively elucidated with respect to intrinsic bonding heterogeneity of Y2Si2O7. The present results are expected to bring deeper insights for phonon engineering and modulation of thermal conductivity in complex solids with diverging structural flexibility, enormous bonding heterogeneity, and giant phonon anharmonicity. PMID:27430670
NASA Astrophysics Data System (ADS)
Luo, Yixiu; Wang, Jiemin; Li, Yiran; Wang, Jingyang
2016-07-01
Modification of lattice thermal conductivity (κL) of a solid by means of hydrostatic pressure (P) has been a crucially interesting approach that targets a broad range of advanced materials from thermoelectrics and thermal insulators to minerals in mantle. Although it is well documented knowledge that thermal conductivity of bulk materials normally increase upon hydrostatic pressure, such positive relationship is seriously challenged when it comes to ceramics with complex crystal structure and heterogeneous chemical bonds. In this paper, we predict an abnormally negative trend dκL/dP < 0 in Y2Si2O7 silicate using density functional theoretical calculations. The mechanism is disclosed as combined effects of slightly decreased group velocity and significantly augmented scattering of heat-carrying acoustic phonons in pressured lattice, which is originated from pressure-induced downward shift of low-lying optic and acoustic phonons. The structural origin of low-lying optic phonons as well as the induced phonon anharmonicity is also qualitatively elucidated with respect to intrinsic bonding heterogeneity of Y2Si2O7. The present results are expected to bring deeper insights for phonon engineering and modulation of thermal conductivity in complex solids with diverging structural flexibility, enormous bonding heterogeneity, and giant phonon anharmonicity.
Joshi, Trinity; Kang, Ji-Hun; Jiang, Lili; Wang, Sheng; Tarigo, Theron; Lyu, Tairu; Kahn, Salman; Shi, Zhiwen; Shen, Yuen-Ron; Crommie, Michael F; Wang, Feng
2017-06-14
Surface plasmons (SPs) and phonon polaritons (PhPs) are two distinctive quasiparticles resulting from the strong coupling of photons with electrons and optical phonons, respectively. In this Letter, we investigate the interactions between one-dimensional (1D) plasmons in silver nanowires with two-dimensional (2D) surface phonon polaritons of the silicon carbide (SiC) substrate. Using near-field infrared spectroscopy of the silver nanowire-SiC heterostructure at wavelengths close to the phonon resonance of SiC, we observe that the 1D plasmon dispersion is strongly modified by the 2D phonon polaritons in SiC. In particular, we observe for the first time well-defined 1D plasmon oscillations with the plasmon wavelengths longer than the free-space photon wavelengths due to the 1D plasmon-2D phonon polariton coupling. Our work demonstrates that unusual polariton behavior can emerge from interactions between polariton excitons of different dimensionality, which can enable new ways to engineer plasmons in hybrid structures.
Calculating the Phonon Dispersion From First Principles
NASA Astrophysics Data System (ADS)
Ceballos, Frank; O'Hara, Andy; Slepko, Alexander; Demkov, Alexander
2011-10-01
The goal of this project was to construct a user-friendly tool that can compute the phonon dispersion for any solid with a periodic crystal structure. The phonon dispersion describes the crystal's vibrational properties and thermodynamic properties of the solid. Using the Vienna Ab-initio Simulation Package (VASP) we compute the forces between the atoms. Assuming harmonic approximation we numerically evaluate force constant matrix. The lattice Fourier transform of the force constants yields the dynamical matrix, whose eigenvalues and eigenvectors represent the allowed phonon frequencies and displacement patterns for specific k-vectors. Our code then plots the frequencies along high symmetry lines in the Brillouin zone. We will present our results for silicon, GaAs and ZrO2.
Polaron action for multimode dispersive phonon systems
NASA Astrophysics Data System (ADS)
Kornilovitch, P. E.
2006-03-01
The path-integral approach to the tight-binding polaron is extended to multiple optical phonon modes of arbitrary dispersion and polarization. The nonlinear lattice effects are neglected. Only one electron band is considered. The electron-phonon interaction is of the density-displacement type, but can be of arbitrary spatial range and shape. Feynman’s analytical integration of ion trajectories is performed by transforming the electron-ion forces to the basis in which the phonon dynamical matrix is diagonal. The resulting polaron action is derived for the periodic and shifted boundary conditions in imaginary time. The former can be used for calculating polaron thermodynamics while the latter for the polaron mass and spectrum. The developed formalism is the analytical basis for numerical analysis of such models by path-integral Monte Carlo methods.
Phonon wave interference and thermal bandgap materials
NASA Astrophysics Data System (ADS)
Maldovan, Martin
2015-07-01
Wave interference modifies phonon velocities and density of states, and in doing so creates forbidden energy bandgaps for thermal phonons. Materials that exhibit wave interference effects allow the flow of thermal energy to be manipulated by controlling the material's thermal conductivity or using heat mirrors to reflect thermal vibrations. The technological potential of these materials, such as enhanced thermoelectric energy conversion and improved thermal insulation, has fuelled the search for highly efficient phonon wave interference and thermal bandgap materials. In this Progress Article, we discuss recent developments in the understanding and manipulation of heat transport. We show that the rational design and fabrication of nanostructures provides unprecedented opportunities for creating wave-like behaviour of heat, leading to a fundamentally new approach for manipulating the transfer of thermal energy.
Phonon Anomaly in High-Pressure Zn
NASA Astrophysics Data System (ADS)
Li, Zhiqiang; Tse, John S.
2000-12-01
The equation of states and phonon dispersions of hexagonal zinc have been calculated by the plane-wave pseudopotential method within the generalized-gradient approximation. Weak discontinuities are found in the pressure-volume relation as well as the c/a-volume curve. Phonon dispersions of Zn under pressure have been obtained with a direct method and the results are consistent with the neutron scattering data. At V/V0~0.88, the calculated frequencies of the acoustic phonons near the zone center softened substantially as a result of an electronic topological transition. The theoretical result is consistent with the observed anomaly in the Lam-Mössbauer factor at low temperature.
NASA Astrophysics Data System (ADS)
Yan, Zhequan; Chen, Liang; Yoon, Mina; Kumar, Satish
2016-02-01
Hexagonal boron nitride (h-BN) is a promising substrate for graphene based nano-electronic devices. We investigate the ballistic phonon transport at the interface of vertically stacked graphene and h-BN heterostructures using first principles density functional theory and atomistic Green's function simulations considering the influence of lattice stacking. We compute the frequency and wave-vector dependent transmission function and observe distinct stacking-dependent phonon transmission features for the h-BN/graphene/h-BN sandwiched systems. We find that the in-plane acoustic modes have the dominant contributions to the phonon transmission and thermal boundary conductance (TBC) for the interfaces with the carbon atom located directly on top of the boron atom (C-B matched) because of low interfacial spacing. The low interfacial spacing is a consequence of the differences in the effective atomic volume of N and B and the difference in the local electron density around N and B. For the structures with the carbon atom directly on top of the nitrogen atom (C-N matched), the spatial distance increases and the contribution of in-plane modes to the TBC decreases leading to higher contributions by out-of-plane acoustic modes. We find that the C-B matched interfaces have stronger phonon-phonon coupling than the C-N matched interfaces, which results in significantly higher TBC (more than 50%) in the C-B matched interface. The findings in this study will provide insights to understand the mechanism of phonon transport at h-BN/graphene/h-BN interfaces, to better explain the experimental observations and to engineer these interfaces to enhance heat dissipation in graphene based electronic devices.
Ab initio and molecular dynamics predictions for electron and phonon transport in bismuth telluride
NASA Astrophysics Data System (ADS)
Huang, Bao-Ling; Kaviany, Massoud
2008-03-01
Phonon and electron transport in Bi2Te3 has been investigated using a multiscale approach, combining the first-principles calculations, molecular dynamics (MD) simulations, and Boltzmann transport equations (BTEs). Good agreements are found with the available experimental results. The MD simulations along with the Green-Kubo autocorrelation decay method are used to calculate the lattice thermal conductivity in both the in-plane and cross-plane directions, where the required classical interatomic potentials for Bi2Te3 are developed on the basis of first-principles calculations and experimental results. In the decomposition of the lattice thermal conductivity, the contributions from the short-range acoustic and optical phonons are found to be temperature independent and direction independent, while the long-range acoustic phonons dominate the phonon transport with a strong temperature and direction dependence (represented by a modified Slack relation). The sum of the short-range acoustic and optical phonon contribution is about 0.2W/mK and signifies the limit when the long-range transport is suppressed by nanostructure engineering. The electrical transport is calculated using the full-band structure from the linearized augmented plane-wave method, BTE, and the energy-dependent relaxation-time models with the nonparabolic Kane energy dispersion. Temperature dependence of the energy gap is found to be important for the prediction of electrical transport in the intrinsic regime. Appropriate modeling of relaxation times is also essential for the calculation of electric and thermal transport, especially in the intrinsic regime. The maximum of the Seebeck coefficient appears when the chemical potential approaches the band edge and can be estimated by a simple expression containing the band gap. The scatterings by the acoustic, optical, and polar-optical phonons dominate the electrical conductivity and electric thermal conductivity.
Yan, Zhequan; Chen, Liang; Yoon, Mina; Kumar, Satish
2016-02-21
Hexagonal boron nitride (h-BN) is a promising substrate for graphene based nano-electronic devices. We investigate the ballistic phonon transport at the interface of vertically stacked graphene and h-BN heterostructures using first principles density functional theory and atomistic Green's function simulations considering the influence of lattice stacking. We compute the frequency and wave-vector dependent transmission function and observe distinct stacking-dependent phonon transmission features for the h-BN/graphene/h-BN sandwiched systems. We find that the in-plane acoustic modes have the dominant contributions to the phonon transmission and thermal boundary conductance (TBC) for the interfaces with the carbon atom located directly on top of the boron atom (C-B matched) because of low interfacial spacing. The low interfacial spacing is a consequence of the differences in the effective atomic volume of N and B and the difference in the local electron density around N and B. For the structures with the carbon atom directly on top of the nitrogen atom (C-N matched), the spatial distance increases and the contribution of in-plane modes to the TBC decreases leading to higher contributions by out-of-plane acoustic modes. We find that the C-B matched interfaces have stronger phonon-phonon coupling than the C-N matched interfaces, which results in significantly higher TBC (more than 50%) in the C-B matched interface. The findings in this study will provide insights to understand the mechanism of phonon transport at h-BN/graphene/h-BN interfaces, to better explain the experimental observations and to engineer these interfaces to enhance heat dissipation in graphene based electronic devices.
Refraction characteristics of phononic crystals
NASA Astrophysics Data System (ADS)
Nemat-Nasser, Sia
2015-08-01
Some of the most interesting refraction properties of phononic crystals are revealed by examining the anti-plane shear waves in doubly periodic elastic composites with unit cells containing rectangular and/or elliptical multi-inclusions. The corresponding band structure, group velocity, and energy-flux vector are calculated using a powerful mixed variational method that accurately and efficiently yields all the field quantities over multiple frequency pass-bands. The background matrix and the inclusions can be anisotropic, each having distinct elastic moduli and mass densities. Equifrequency contours and energy-flux vectors are readily calculated as functions of the wave-vector components. By superimposing the energy-flux vectors on equifrequency contours in the plane of the wave-vector components, and supplementing this with a three-dimensional graph of the corresponding frequency surface, a wealth of information is extracted essentially at a glance. This way it is shown that a composite with even a simple square unit cell containing a central circular inclusion can display negative or positive energy and phase velocity refractions, or simply performs a harmonic vibration (standing wave), depending on the frequency and the wave-vector. Moreover, that the same composite when interfaced with a suitable homogeneous solid can display: (1) negative refraction with negative phase velocity refraction; (2) negative refraction with positive phase velocity refraction; (3) positive refraction with negative phase velocity refraction; (4) positive refraction with positive phase velocity refraction; or even (5) complete reflection with no energy transmission, depending on the frequency, and direction and the wavelength of the plane-wave that is incident from the homogeneous solid to the interface. For elliptical and rectangular inclusion geometries, analytical expressions are given for the key calculation quantities. Expressions for displacement, velocity, linear momentum
Second Harmonic Generation of Nanoscale Phonon Wave Packets.
Bojahr, A; Gohlke, M; Leitenberger, W; Pudell, J; Reinhardt, M; von Reppert, A; Roessle, M; Sander, M; Gaal, P; Bargheer, M
2015-11-06
Phonons are often regarded as delocalized quasiparticles with certain energy and momentum. The anharmonic interaction of phonons determines macroscopic properties of the solid, such as thermal expansion or thermal conductivity, and a detailed understanding becomes increasingly important for functional nanostructures. Although phonon-phonon scattering processes depicted in simple wave-vector diagrams are the basis of theories describing these macroscopic phenomena, experiments directly accessing these coupling channels are scarce. We synthesize monochromatic acoustic phonon wave packets with only a few cycles to introduce nonlinear phononics as the acoustic counterpart to nonlinear optics. Control of the wave vector, bandwidth, and consequently spatial extent of the phonon wave packets allows us to observe nonlinear phonon interaction, in particular, second harmonic generation, in real time by wave-vector-sensitive Brillouin scattering with x-rays and optical photons.
Phonon dispersion of indium along [111
Bakulin, A. S.; Overhauser, A. W.; Kaiser, H.; Werner, S. A.; Fernandez-Baca, J. A.; Smith, H. G.
2001-02-01
The phonon spectrum of indium along [111], measured by inelastic neutron scattering, is reported. The two shear modes at the zone-boundary point (1/2, 1/2, 1/2) are split slightly (on account of a 7.5% tetragonal distortion). They have very low frequencies, {approx}0.7 and 1.0 THz, compared to the longitudinal mode, {approx}3.4 THz. These measurements verify the theoretical dispersion predicted by the dynamic pseudopotential theory of phonons for free-electron-like metals.
Phonon-Josephson resonances in atomtronic circuits
NASA Astrophysics Data System (ADS)
Bidasyuk, Y. M.; Prikhodko, O. O.; Weyrauch, M.
2016-09-01
We study the resonant excitation of sound modes from Josephson oscillations in Bose-Einstein condensates. From the simulations for various setups using the Gross-Pitaevskii mean-field equations and Josephson equations we observe additional tunneling currents induced by resonant phonons. The proposed experiment may be used for spectroscopy of phonons as well as other low-energy collective excitations in Bose-Einstein condensates. We also argue that the observed effect may mask the observation of Shapiro resonances if not carefully controlled.
Phononic Phase Conjugation in an Optomechanical System
NASA Astrophysics Data System (ADS)
Buchmann, Lukas; Wright, Ewan; Meystre, Pierre
2013-05-01
We study theoretically the phase conjugation of a phononic field in an optomechanical system with two mechanical modes coupled to a common optical field. Phase conjugation becomes the dominant process for an appropriate choice of driving field parameters, and he effective coupling coefficients between phonon modes can result in amplification and entanglement, phase-conjugation or a mixture thereof. We discuss surprising consequences of mechanical phase-conjugation that could lead to the preparation of mechanical states with negative temperature, the improvement of quantum memories and the study of the quantum-classical transition. Supported by DARPA ORCHID program.
THZ Phonon Spectroscopy of Bi-2223 and Bi-2212: Evidence for Phonon Pairing
NASA Astrophysics Data System (ADS)
Ponomarev, Ya. G.; Van, Hoang Hoai
Facts are presented evidencing the strong electron-phonon interaction and the scaling of a superconducting gap and a critical temperature in doped Bi-2212 single crystals. A sharp extra structure in the current-voltage characteristics (CVC's) of Bi-2212 contacts is attributed to the presence of the extended van Hove singularity (EVHS) close to the Fermi level in slightly overdoped and slightly underdoped samples. THZ phonon spectroscopy studies of Bi-2223 and Bi-2212 are overviewed. An observed giant instability in I(V) - characteristics of Bi-2223 nanosteps is probably caused by a resonant emission of 2Δ - optical phonons in a process of recombination of nonequilibrium quasiparticles (Krasnov model).
NASA Astrophysics Data System (ADS)
Dinh Hien, Nguyen; Dinh, Le; Thanh Lam, Vo; Cong Phong, Tran
2016-06-01
We investigate the influence of phonon confinement on the optically detected electrophonon resonance (ODEPR) effect and ODEPR line-width in quantum wells. The obtained numerical result for the GaAs/AlAs quantum well shows that the ODEPR line-widths depend on the well's width and temperature. Besides, in the two cases of confined and bulk phonons, the linewidth (LW) decreases with the increase of well's width and increases with the increase of temperature. Furthermore, in the small range of the well's width, the influence of phonon confinement plays an important role and cannot be neglected in considering the ODEPR line-width.
Soft surfaces of nanomaterials enable strong phonon interactions
NASA Astrophysics Data System (ADS)
Bozyigit, Deniz; Yazdani, Nuri; Yarema, Maksym; Yarema, Olesya; Lin, Weyde Matteo Mario; Volk, Sebastian; Vuttivorakulchai, Kantawong; Luisier, Mathieu; Juranyi, Fanni; Wood, Vanessa
2016-03-01
Phonons and their interactions with other phonons, electrons or photons drive energy gain, loss and transport in materials. Although the phonon density of states has been measured and calculated in bulk crystalline semiconductors, phonons remain poorly understood in nanomaterials, despite the increasing prevalence of bottom-up fabrication of semiconductors from nanomaterials and the integration of nanometre-sized components into devices. Here we quantify the phononic properties of bottom-up fabricated semiconductors as a function of crystallite size using inelastic neutron scattering measurements and ab initio molecular dynamics simulations. We show that, unlike in microcrystalline semiconductors, the phonon modes of semiconductors with nanocrystalline domains exhibit both reduced symmetry and low energy owing to mechanical softness at the surface of those domains. These properties become important when phonons couple to electrons in semiconductor devices. Although it was initially believed that the coupling between electrons and phonons is suppressed in nanocrystalline materials owing to the scarcity of electronic states and their large energy separation, it has since been shown that the electron-phonon coupling is large and allows high energy-dissipation rates exceeding one electronvolt per picosecond (refs 10, 11, 12, 13). Despite detailed investigations into the role of phonons in exciton dynamics, leading to a variety of suggestions as to the origins of these fast transition rates and including attempts to numerically calculate them, fundamental questions surrounding electron-phonon interactions in nanomaterials remain unresolved. By combining the microscopic and thermodynamic theories of phonons and our findings on the phononic properties of nanomaterials, we are able to explain and then experimentally confirm the strong electron-phonon coupling and fast multi-phonon transition rates of charge carriers to trap states. This improved understanding of phonon
A Comprehensive Approach to Phonon Control for Enhanced Device Performance
2006-07-12
program include (i) the development of novel theoretical and experimental (ultrafast laser and x-ray) methods to generate and probe coherent high...frequency sound, optical phonons and polaritons, (ii) the improvement of phonon-based imaging techniques and development of new methods of phonon detection...acoustic phonon sources using both ultrafast lasers and electrical methods , and (iii) the application and improvement of state- of-the-art materials
Angular dependence of phonon transmission through a Fibonacci superlattice
NASA Astrophysics Data System (ADS)
Hurley, D. C.; Tamura, S.; Wolfe, J. P.; Ploog, K.; Nagle, J.
1988-05-01
Phonon imaging is employed to examine the propagation of acoustic phonons through a Fibonacci superlattice. Ballistic transmission of phonons with ν>850 GHz through 750 superlattice interfaces is detected. In addition, sharp variations in the phonon intensity with propagation angle are observed. These measurements are consistent with Monte Carlo simulations presented in this paper. Distinct stop bands are expected theoretically, and the angular dependence of these structures is remarkably similar to those predicted for a periodic superlattice.
Depth-Dependent Defect Studies Using Coherent Acoustic Phonons
2014-09-29
12211 Research Triangle Park, NC 27709-2211 coherent acoustic phonons, diamond, silicon, photelastic coefficients , refractive index, graphene, Second...attributed to the cooling of the subsystem of hot optical phonons by optical- acoustic phonon scattering . We observe that at different pump energy and...SECURITY CLASSIFICATION OF: Presented is our scientific progress in two areas of research. The first is coherent acoustic phonon (CAP) spectroscopy of
Honeycomb phononic crystals with self-similar hierarchy
NASA Astrophysics Data System (ADS)
Mousanezhad, Davood; Babaee, Sahab; Ghosh, Ranajay; Mahdi, Elsadig; Bertoldi, Katia; Vaziri, Ashkan
2015-09-01
We highlight the effect of structural hierarchy and deformation on band structure and wave-propagation behavior of two-dimensional phononic crystals. Our results show that the topological hierarchical architecture and instability-induced pattern transformations of the structure under compression can be effectively used to tune the band gaps and directionality of phononic crystals. The work provides insights into the role of structural organization and hierarchy in regulating the dynamic behavior of phononic crystals, and opportunities for developing tunable phononic devices.
Manipulating Heat Flow through 3 Dimensional Nanoscale Phononic Crystal Structure
2014-06-02
Nanoscale Phononic Crystal Structure 5a. CONTRACT NUMBER FA23861214047 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Baowen Li 5d...through computer simulation, how the three dimensional (3D) phononic crystal structures can confine phonon and thus reduce thermal conductivity...phononic crystal (PnC) with spherical pores, which can reduce thermal conductivity of bulk Si by a factor up to 10,000 times at room temperature. The
Yi, Kyung-Soo; Kim, Hye-Jung
2017-02-15
We investigate spectral behavior of phonon spectral functions in an interacting multi-component hot carrier plasma. Spectral analysis of various phonon spectral functions is performed considering carrier-phonon channels of polar and nonpolar optical phonons, acoustic deformation-potential, and piezoelectric Coulomb couplings. Effects of phonon self-energy corrections are examined at finite temperature within a random phase approximation extended to include the effects of dynamic screening, plasmon-phonon coupling, and local-field corrections of the plasma species. We provide numerical data for the case of a photo-generated electron-hole plasma formed in a wurtzite GaN. Our result shows the clear significance of the multiplicity of the plasma species in the phonon spectral functions of a multi-component plasma giving rise to a variety of spectral behaviors of carrier-phonon coupled collective modes. A useful sum rule on the plasma-species-resolved dielectric functions is also found.
NASA Astrophysics Data System (ADS)
Yi, Kyung-Soo; Kim, Hye-Jung
2017-02-01
We investigate spectral behavior of phonon spectral functions in an interacting multi-component hot carrier plasma. Spectral analysis of various phonon spectral functions is performed considering carrier-phonon channels of polar and nonpolar optical phonons, acoustic deformation-potential, and piezoelectric Coulomb couplings. Effects of phonon self-energy corrections are examined at finite temperature within a random phase approximation extended to include the effects of dynamic screening, plasmon-phonon coupling, and local-field corrections of the plasma species. We provide numerical data for the case of a photo-generated electron-hole plasma formed in a wurtzite GaN. Our result shows the clear significance of the multiplicity of the plasma species in the phonon spectral functions of a multi-component plasma giving rise to a variety of spectral behaviors of carrier-phonon coupled collective modes. A useful sum rule on the plasma-species-resolved dielectric functions is also found.
Demonstration of acoustic waveguiding and tight bending in phononic crystals
Ghasemi Baboly, M.; Raza, A.; Brady, J.; ...
2016-10-31
The systematic design, fabrication, and characterization of an isolated, single-mode, 90° bend phononic crystal (PnC) waveguide are presented. A PnC consisting of a 2D square array of circular air holes in an aluminum substrate is used, and waveguides are created by introducing a line defect in the PnC lattice. A high transmission coefficient is observed (–1 dB) for the straight sections of the waveguide, and an overall 2.3 dB transmission loss is observed (a transmission coefficient of 76%) for the 90° bend. Further optimization of the structure may yield higher transmission efficiencies. Lastly, this manuscript shows the complete design processmore » for an engineered 90° bend PnC waveguide from inception to experimental demonstration.« less
Observation of the Phononic Lamb Shift with a Synthetic Vacuum
NASA Astrophysics Data System (ADS)
Rentrop, T.; Trautmann, A.; Olivares, F. A.; Jendrzejewski, F.; Komnik, A.; Oberthaler, M. K.
2016-10-01
In contrast to classical empty space, the quantum vacuum fundamentally alters the properties of embedded particles. This paradigm shift allows one to explain the discovery of the celebrated Lamb shift in the spectrum of the hydrogen atom. Here, we engineer a synthetic vacuum, building on the unique properties of ultracold atomic gas mixtures, offering the ability to switch between empty space and quantum vacuum. Using high-precision spectroscopy, we observe the phononic Lamb shift, an intriguing many-body effect originally conjectured in the context of solid-state physics. We find good agreement with theoretical predictions based on the Fröhlich model. Our observations establish this experimental platform as a new tool for precision benchmarking of open theoretical challenges, especially in the regime of strong coupling between the particles and the quantum vacuum.
Demonstration of acoustic waveguiding and tight bending in phononic crystals
Ghasemi Baboly, M.; Raza, A.; Brady, J.; Reinke, C. M.; Leseman, Z. C.; El-Kady, I.
2016-10-31
The systematic design, fabrication, and characterization of an isolated, single-mode, 90° bend phononic crystal (PnC) waveguide are presented. A PnC consisting of a 2D square array of circular air holes in an aluminum substrate is used, and waveguides are created by introducing a line defect in the PnC lattice. A high transmission coefficient is observed (–1 dB) for the straight sections of the waveguide, and an overall 2.3 dB transmission loss is observed (a transmission coefficient of 76%) for the 90° bend. Further optimization of the structure may yield higher transmission efficiencies. Lastly, this manuscript shows the complete design process for an engineered 90° bend PnC waveguide from inception to experimental demonstration.
Nonlinear propagation and control of acoustic waves in phononic superlattices
NASA Astrophysics Data System (ADS)
Jiménez, Noé; Mehrem, Ahmed; Picó, Rubén; García-Raffi, Lluís M.; Sánchez-Morcillo, Víctor J.
2016-05-01
The propagation of intense acoustic waves in a one-dimensional phononic crystal is studied. The medium consists in a structured fluid, formed by a periodic array of fluid layers with alternating linear acoustic properties and quadratic nonlinearity coefficient. The spacing between layers is of the order of the wavelength, therefore Bragg effects such as band gaps appear. We show that the interplay between strong dispersion and nonlinearity leads to new scenarios of wave propagation. The classical waveform distortion process typical of intense acoustic waves in homogeneous media can be strongly altered when nonlinearly generated harmonics lie inside or close to band gaps. This allows the possibility of engineer a medium in order to get a particular waveform. Examples of this include the design of media with effective (e.g., cubic) nonlinearities, or extremely linear media (where distortion can be canceled). The presented ideas open a way towards the control of acoustic wave propagation in nonlinear regime.
NASA Astrophysics Data System (ADS)
Wang, Yan; Lu, Zexi; Ruan, Xiulin
2016-06-01
The effect of phonon-electron (p-e) scattering on lattice thermal conductivity is investigated for Cu, Ag, Au, Al, Pt, and Ni. We evaluate both phonon-phonon (p-p) and p-e scattering rates from first principles and calculate the lattice thermal conductivity (κL). It is found that p-e scattering plays an important role in determining the κL of Pt and Ni at room temperature, while it has negligible effect on the κL of Cu, Ag, Au, and Al. Specifically, the room temperature κLs of Cu, Ag, Au, and Al predicted from density-functional theory calculations with the local density approximation are 16.9, 5.2, 2.6, and 5.8 W/m K, respectively, when only p-p scattering is considered, while it is almost unchanged when p-e scattering is also taken into account. However, the κL of Pt and Ni is reduced from 7.1 and 33.2 W/m K to 5.8 and 23.2 W/m K by p-e scattering. Even though Al has quite high electron-phonon coupling constant, a quantity that characterizes the rate of heat transfer from hot electrons to cold phonons in the two-temperature model, p-e scattering is not effective in reducing κL owing to the relatively low p-e scattering rates in Al. The difference in the strength of p-e scattering in different metals can be qualitatively understood by checking the amount of electron density of states that is overlapped with the Fermi window. Moreover, κL is found to be comparable to the electronic thermal conductivity in Ni.
Wang, Yan; Lu, Zexi; Ruan, Xiulin
2016-06-14
The effect of phonon-electron (p-e) scattering on lattice thermal conductivity is investigated for Cu, Ag, Au, Al, Pt, and Ni. We evaluate both phonon-phonon (p-p) and p-e scattering rates from first principles and calculate the lattice thermal conductivity (κ{sub L}). It is found that p-e scattering plays an important role in determining the κ{sub L} of Pt and Ni at room temperature, while it has negligible effect on the κ{sub L} of Cu, Ag, Au, and Al. Specifically, the room temperature κ{sub L}s of Cu, Ag, Au, and Al predicted from density-functional theory calculations with the local density approximation are 16.9, 5.2, 2.6, and 5.8 W/m K, respectively, when only p-p scattering is considered, while it is almost unchanged when p-e scattering is also taken into account. However, the κ{sub L} of Pt and Ni is reduced from 7.1 and 33.2 W/m K to 5.8 and 23.2 W/m K by p-e scattering. Even though Al has quite high electron-phonon coupling constant, a quantity that characterizes the rate of heat transfer from hot electrons to cold phonons in the two-temperature model, p-e scattering is not effective in reducing κ{sub L} owing to the relatively low p-e scattering rates in Al. The difference in the strength of p-e scattering in different metals can be qualitatively understood by checking the amount of electron density of states that is overlapped with the Fermi window. Moreover, κ{sub L} is found to be comparable to the electronic thermal conductivity in Ni.
Phonon dispersion in austenitic stainless steel Fe18Cr12Ni2Mo
NASA Astrophysics Data System (ADS)
Hoelzel, M.; Danilkin, S. A.; Hoser, A.; Ehrenberg, H.; Wieder, T.; Fuess, H.
The phonon dispersion of Fe18Cr12Ni2Mo austenitic stainless steel was measured along the symmetry directions [001], [110] and [111]. Data were analysed in the frame of the Born-von Karman model of lattice dynamics. The obtained force constants were used to evaluate the elastic constants and the engineering elastic moduli. Our results for the elastic constants confirm empirical relationships between the elastic constants found for FCC FeCrNi alloys.
Electron-phonon interactions and the phonon anomaly in [beta]-phase NiTi
Zhao, G.L.; Harmon, B.N. )
1993-07-15
The electronic structure of [beta]-phase NiTi has been calculated using a first-principles linear-combination-of-atomic-orbitals method. The resulting band structure was fitted with a nonorthogonal tight-binding Hamiltonian from which electron-phonon matrix elements were evaluated. The soft phonon near [ital Q][sub 0]=(2/3, 2) / (3 ,0)[pi]/[ital a], which is responsible for the premartensitic phase transition in [beta]-phase NiTi, is found to arise from the strong electron-phonon coupling of nested electronic states on the Fermi surface. Thermal vibrations and changes in electronic occupation cause a smearing of the nested features, which in turn cause a hardening of the phonon anomaly.
Three-dimensional adaptive soft phononic crystals
NASA Astrophysics Data System (ADS)
Babaee, Sahab; Wang, Pai; Bertoldi, Katia
2015-06-01
We report a new class of three-dimensional (3D) adaptive phononic crystals whose dynamic response is controlled by mechanical deformation. Using finite element analysis, we demonstrate that the bandgaps of the proposed 3D structure can be fully tuned by the externally applied deformation. In fact, our numerical results indicate that the system acts as a reversible phononic switch: a moderate level of applied strain (i.e., -0.16) is sufficient to completely suppress the bandgap, and upon the release of applied strain, the deformed structure recovers its original shape, which can operate with a sizable bandgap under dynamic loading. In addition, we investigate how material damping significantly affects the propagation of elastic waves in the proposed 3D soft phononic crystal. We believe that our results pave the way for the design of a new class of soft, adaptive, and re-configurable 3D phononic crystals, whose bandgaps can be easily tuned and switched on/off by controlling the applied deformation.
Hyperbolic phonon polaritons in hexagonal boron nitride
NASA Astrophysics Data System (ADS)
Dai, Siyuan
2015-03-01
Uniaxial materials whose axial and tangential permittivities have opposite signs are referred to as indefinite or hyperbolic media. While hyperbolic responses are normally achieved with metamaterials, hexagonal boron nitride (hBN) naturally possesses this property due to the anisotropic phonons in the mid-infrared. Using scattering-type scanning near-field optical microscopy, we studied polaritonic phenomena in hBN. We performed infrared nano-imaging of highly confined and low-loss hyperbolic phonon polaritons in hBN. The polariton wavelength was shown to be governed by the hBN thickness according to a linear law persisting down to few atomic layers [Science, 343, 1125-1129 (2014)]. Additionally, we carried out the modification of hyperbolic response in heterostructures comprised of a mononlayer graphene deposited on hBN. Electrostatic gating of the top graphene layer allows for the modification of wavelength and intensity of hyperbolic phonon polaritons in bulk hBN. The physics of the modification originates from the plasmon-phonon coupling in the hyperbolic medium. Furthermore, we demonstrated the ``hyperlens'' for subdiffractional imaging and focusing using a slab of hBN.
Phonon dispersion in red mercuric iodide
Sim, H.; Chang, Y. ); James, R.B. )
1994-02-15
We present theoretical studies of phonon modes of undoped HgI[sub 2] in its red tetragonal form. A rigid-ion model including the Coulomb interaction is used which gives the best fit to the neutron scattering, infrared reflectivity, and Raman scattering data. The calculated sound velocities are also in accord with experiment.
Phononic subsurface: Flow stabilization by crystals
NASA Astrophysics Data System (ADS)
Hussein, Mahmoud I.; Biringen, Sedat; Bilal, Osama R.; Kucala, Alec
2015-11-01
Flow control is a century-old problem where the goal is to alter a flow's natural state to achieve improved performance, such as delay of laminar-to-turbulent transition or reduction of drag in a fully developed turbulent flow. Meeting this goal promises to significantly reduce the dependence on fossil fuels for global transport. In this work, we show that phonon motion underneath a surface interacting with a flow may be tuned to cause the flow to stabilize, or destabilize, as desired. This concept is demonstrated by simulating a fully developed plane Poiseuille (channel) flow whereby a small portion of an otherwise rigid wall is replaced with a one-dimensional phononic crystal. A Tollmien-Schlichting (TS) wave is introduced to the flow as an evolving disturbance. Upon tuning the frequency-dependent phase and amplitude relations of the surface of the phononic crystal that interfaces with the flow, the TS wave is shown to stabilize, or destabilize, as needed. A theory of subsurface phonons is presented that provides an accurate prediction of this behavior without the need for a flow simulation. This represents an unprecedented capability to passively synchronize wave propagation across a fluid-structure interface and achieve favorable, and predictable, alterations to the flow properties. National Science Foundation, Grant No. 1131802.
``Forbidden'' phonon in the iron chalcogenide series
NASA Astrophysics Data System (ADS)
Fobes, David M.; Zaliznyak, Igor A.; Xu, Zhijun; Gu, Genda; Tranquada, John M.
2015-03-01
Recently, we uncovered evidence for the formation of a bond-order wave (BOW) leading to ferro-orbital order at low temperature, acting to stabilize the bicollinear AFM order, in the iron-rich parent compound, Fe1+yTe. Investigating the inelastic spectra centered near (100) in Fe1+yTe, a signature peak for the BOW formation in the monoclinic phase, we observed an acoustic phonon dispersion in both tetragonal and monoclinic phases. While a structural Bragg peak accompanies the mode in the monoclinic phase, in the tetragonal phase Bragg scattering at this Q is forbidden by symmetry, and we observed no elastic peak. This phonon mode was also observed in superconducting FeTe0.6Se0.4, where structural and magnetic transitions are suppressed. LDA frozen phonon calculations suggested that this mode could result from a spin imbalance between neighboring Fe atoms, but polarized neutron measurements revealed no additional magnetic scattering. We propose that this ``forbidden'' phonon mode may originate from dynamically broken symmetry, perhaps related to the strong dynamic spin correlations in these materials. Work at BNL was supported by BES, US DOE, under Contract No. DE-AC02-98CH10886. Research at ORNL's HFIR and SNS sponsored by Scientific User Facilities Division, BES, US DOE. We acknowledge the support of NIST, in providing neutron research facilities.
Kohn anomaly in phonon driven superconductors
NASA Astrophysics Data System (ADS)
Das, M. P.; Chaudhury, R.
2014-08-01
Anomalies often occur in the physical world. Sometimes quite unexpectedly anomalies may give rise to new insight to an unrecognized phenomenon. In this paper we shall discuss about Kohn anomaly in a conventional phonon-driven superconductor by using a microscopic approach. Recently Aynajian et al.'s experiment showed a striking feature; the energy of phonon at a particular wave-vector is almost exactly equal to twice the energy of the superconducting gap. Although the phonon mechanism of superconductivity is well known for many conventional superconductors, as has been noted by Scalapino, the new experimental results reveal a genuine puzzle. In our recent work we have presented a detailed theoretical analysis with the help of microscopic calculations to unravel this mystery. We probe this aspect of phonon behaviour from the properties of electronic polarizability function in the superconducting phase of a Fermi liquid metal, leading to the appearance of a Kohn singularity. We show the crossover to the standard Kohn anomaly of the normal phase for temperatures above the transition temperature. Our analysis provides a nearly complete explanation of this new experimentally discovered phenomenon. This report is a shorter version of our recent work in JPCM.
Synthetic thermoelectric materials comprising phononic crystals
El-Kady, Ihab F; Olsson, Roy H; Hopkins, Patrick; Reinke, Charles; Kim, Bongsang
2013-08-13
Synthetic thermoelectric materials comprising phononic crystals can simultaneously have a large Seebeck coefficient, high electrical conductivity, and low thermal conductivity. Such synthetic thermoelectric materials can enable improved thermoelectric devices, such as thermoelectric generators and coolers, with improved performance. Such synthetic thermoelectric materials and devices can be fabricated using techniques that are compatible with standard microelectronics.
Illustrative numerical comparisons between phonon mean free paths and phonon thermal conductivity
NASA Astrophysics Data System (ADS)
MacDonald, W. M.; Anderson, A. C.
Measurements of thermal conductivity are often used as an interrogative technique to learn about phonon scattering processes in solids. In general the relationship between thermal conductivity lambda and a phonon mean free path 1 is complex and it is therefore necessary to make some simplifying assumptions in order to make this relationship tractable. These assumptions may lead to erroneous conclusions, many of which have appeared in the published literature. An intuitive insight is provided to the relationship between lambda and 1.
Unified theory of electron-phonon renormalization and phonon-assisted optical absorption.
Patrick, Christopher E; Giustino, Feliciano
2014-09-10
We present a theory of electronic excitation energies and optical absorption spectra which incorporates energy-level renormalization and phonon-assisted optical absorption within a unified framework. Using time-independent perturbation theory we show how the standard approaches for studying vibronic effects in molecules and those for addressing electron-phonon interactions in solids correspond to slightly different choices for the non-interacting Hamiltonian. Our present approach naturally leads to the Allen-Heine theory of temperature-dependent energy levels, the Franck-Condon principle, the Herzberg-Teller effect and to phonon-assisted optical absorption in indirect band gap materials. In addition, our theory predicts sub-gap phonon-assisted optical absorption in direct gap materials, as well as an exponential edge which we tentatively assign to the Urbach tail. We also consider a semiclassical approach to the calculation of optical absorption spectra which simultaneously captures energy-level renormalization and phonon-assisted transitions and is especially suited to first-principles electronic structure calculations. We demonstrate this approach by calculating the phonon-assisted optical absorption spectrum of bulk silicon.
Acoustic phonon lifetimes and thermal transport in free-standing and strained graphene.
Bonini, Nicola; Garg, Jivtesh; Marzari, Nicola
2012-06-13
We use first-principles methods based on density functional perturbation theory to characterize the lifetimes of the acoustic phonon modes and their consequences on the thermal transport properties of graphene. We show that using a standard perturbative approach, the transverse and longitudinal acoustic phonons in free-standing graphene display finite lifetimes in the long-wavelength limit, making them ill-defined as elementary excitations in samples of dimensions larger than ∼1 μm. This behavior is entirely due to the presence of the quadratic dispersions for the out-of-plane phonon (ZA) flexural modes that appear in free-standing low-dimensional systems. Mechanical strain lifts this anomaly, and all phonons remain well-defined at any wavelength. Thermal transport is dominated by ZA modes, and the thermal conductivity is predicted to diverge with system size for any amount of strain. These findings highlight strain and sample size as key parameters in characterizing or engineering heat transport in graphene.
Large phonon entropy drives the metallization of vanadium dioxide (VO2)
NASA Astrophysics Data System (ADS)
Hong, Jiawang
2015-03-01
Vanadium dioxide (VO2) exhibits a first-order metal-insulator transition (MIT) near room temperature, where conductivity is suppressed and the lattice changes from tetragonal to monoclinic on cooling. This MIT in VO2 has attracted intense interest from both fundamental and technological perspectives. However, most studies performed in the past 50 years have focused on the electronic structure and energetics of the transition, ignoring the role of phonons and their entropic contribution to the phase stability. Much of the reason is that the standard tool of neutron scattering does not yield coherent scattering from V nuclei, and first-principles methods with harmonic approximation cannot capture the stable phonons for the rutile phase. We close this gap by using a combination of ab initio molecular dynamics calculations and neutron/x-ray scattering to establish that the entropy driving the MIT is dominated by soft, anharmonic phonons of the metallic phase. The MIT results from the competition between lower electronic energy in insulating M1 phase due to the Peierls instability, and the higher entropy of the metallic rutile phase resulting from soft anharmonic phonons. This understanding of the role of lattice dynamics and their relationship to electronic structure provides a critical component for developing more complete physical models of phase competition in functional transition metal oxides. Theoretical calculations were performed using the NERSC at LBNL. Modeling of neutron data was performed in CAMM, measurements were funded by the US DOE, BES, Materials Science and Engineering Division.
Tunable evolutions of wave modes and bandgaps in quasi-1D cylindrical phononic crystals
NASA Astrophysics Data System (ADS)
Meidani, Mehrashk; Kim, Eunho; Li, Feng; Yang, Jinkyu; Ngo, Duc
2015-01-01
We investigate the tunable characteristics of mechanical waves propagating in quasi-1D phononic crystals composed of horizontally stacked short cylinders at various contact angles and offsets. According to the Hertzian contact theory, elastic compression of laterally-touching cylindrical bodies exhibits a various range of contact stiffness depending on their alignment angles. In this study, we first assemble cylindrical particles in various combinations of inclination angles and systematically examine their forming mechanisms of frequency bandgaps. We also investigate the effect of the rattling motions of cylindrical particles by introducing asymmetric center-of-mass offsets with respect to their contact points. We find that the frequency responses of these quasi-1D phononic crystals evolve into multiple band structures as we employ higher deviations of contact angles and offsets. We calculate the dispersive behavior of propagating waves using a discrete particle model for simple zero-offset cases, while we use a finite element method for simulating the rattling motions of particles under non-zero offsets. We report branching behavior of frequency band structures and the evolution of their vibration modes as we manipulate the contact angles and offsets of the phononic crystals. This study implies that we can leverage the versatile wave filtering characteristics of quasi-1D phononic crystals to construct tunable wave filtering devices for engineering applications.
Thickness-Dependent Coherent Phonon Frequency in Ultrathin FeSe/SrTiO₃ Films.
Yang, Shuolong; Sobota, Jonathan A; Leuenberger, Dominik; Kemper, Alexander F; Lee, James J; Schmitt, Felix T; Li, Wei; Moore, Rob G; Kirchmann, Patrick S; Shen, Zhi-Xun
2015-06-10
Ultrathin FeSe films grown on SrTiO3 substrates are a recent milestone in atomic material engineering due to their important role in understanding unconventional superconductivity in Fe-based materials. By using femtosecond time- and angle-resolved photoelectron spectroscopy, we study phonon frequencies in ultrathin FeSe/SrTiO3 films grown by molecular beam epitaxy. After optical excitation, we observe periodic modulations of the photoelectron spectrum as a function of pump-probe delay for 1-unit-cell, 3-unit-cell, and 60-unit-cell thick FeSe films. The frequencies of the coherent intensity oscillations increase from 5.00 ± 0.02 to 5.25 ± 0.02 THz with increasing film thickness. By comparing with previous works, we attribute this mode to the Se A1g phonon. The dominant mechanism for the phonon softening in 1-unit-cell thick FeSe films is a substrate-induced lattice strain. Our results demonstrate an abrupt phonon renormalization due to a lattice mismatch between the ultrathin film and the substrate.
Folded acoustic phonons in (Al,Ga)As quasiperiodic superlattices
NASA Astrophysics Data System (ADS)
Nakayama, M.; Kato, H.; Nakashima, S.
1987-08-01
We have investigated Raman scattering by acoustic phonons in (Al,Ga)As Fibonacci superlattices grown by molecular-beam epitaxy. Many sharp doublet peaks, which are analogous to those produced by Raman scattering by folded acoustic phonons in periodic superlattices, appear at nonequal intervals in the Raman spectra. Assuming that the quasiperiodicities originating in the Fibonacci sequence cause zone-folding effects on acoustic phonons, folded-phonon frequencies calculated using an elastic continuum model are in good agreement with observed doublet-peak frequencies. We also discuss the intensity profiles of Raman scattering by folded phonons on the basis of a photoelastic model.
Controlling thermal emission of phonon by magnetic metasurfaces
NASA Astrophysics Data System (ADS)
Zhang, X.; Liu, H.; Zhang, Z. G.; Wang, Q.; Zhu, S. N.
2017-02-01
Our experiment shows that the thermal emission of phonon can be controlled by magnetic resonance (MR) mode in a metasurface (MTS). Through changing the structural parameter of metasurface, the MR wavelength can be tuned to the phonon resonance wavelength. This introduces a strong coupling between phonon and MR, which results in an anticrossing phonon-plasmons mode. In the process, we can manipulate the polarization and angular radiation of thermal emission of phonon. Such metasurface provides a new kind of thermal emission structures for various thermal management applications.
Phonon-plasmon coupled modes in GaN
NASA Astrophysics Data System (ADS)
Dyson, A.
2009-04-01
The phonon lifetime in GaN is known to exhibit a dependence on electron density. Recent noise measurements have also shown the lifetime to be temperature dependent. The source of these dependences is the coupling of the phonon and plasmon populations through the dielectric function. The effect of this anharmonicity is illustrated by comparing the frequency and wavevector dependent coupled-mode momentum relaxation rate with the phonon momentum relaxation rate obtained by Callen. A simple model that includes the anharmonic interaction and phonon migration yields phonon lifetimes depending on both electron density and temperature.
Controlling thermal emission of phonon by magnetic metasurfaces
Zhang, X.; Liu, H.; Zhang, Z. G.; Wang, Q.; Zhu, S. N.
2017-01-01
Our experiment shows that the thermal emission of phonon can be controlled by magnetic resonance (MR) mode in a metasurface (MTS). Through changing the structural parameter of metasurface, the MR wavelength can be tuned to the phonon resonance wavelength. This introduces a strong coupling between phonon and MR, which results in an anticrossing phonon-plasmons mode. In the process, we can manipulate the polarization and angular radiation of thermal emission of phonon. Such metasurface provides a new kind of thermal emission structures for various thermal management applications. PMID:28157206
Controlling thermal emission of phonon by magnetic metasurfaces.
Zhang, X; Liu, H; Zhang, Z G; Wang, Q; Zhu, S N
2017-02-03
Our experiment shows that the thermal emission of phonon can be controlled by magnetic resonance (MR) mode in a metasurface (MTS). Through changing the structural parameter of metasurface, the MR wavelength can be tuned to the phonon resonance wavelength. This introduces a strong coupling between phonon and MR, which results in an anticrossing phonon-plasmons mode. In the process, we can manipulate the polarization and angular radiation of thermal emission of phonon. Such metasurface provides a new kind of thermal emission structures for various thermal management applications.
NASA Astrophysics Data System (ADS)
Zhang, Li; Shi, Jun-jie
2005-06-01
Within the framework of the dielectric continuum approximation and Loudon's uniaxial crystal model, the interface optical (IO) phonon modes and the corresponding Fröhlich electron phonon interaction Hamiltonian in a wurtzite AlN/GaN/AlN quantum well wire (QWW) are derived and studied. Numerical calculations are mainly focused on the frequency dispersion of the IO phonons and electron phonon interaction coupling function. Results reveal that, in general, there are four branches of IO phonon modes in the systems. The dispersions of the four branches of IO phonon modes are obvious only when the axial direction wave number kz or the azimuthal quantum number m is small. The degenerating behaviour of the IO phonon modes in wurtzite QWW has also been observed for small kz or m. When kz or m are relatively large, with the increasing of them, the frequencies of these IO phonon modes converge to the two definite limiting frequencies in wurtzite single planar heterostructure, and this feature has been explained reasonably from the mathematical and physical viewpoints. The calculations of the electron phonon coupling function show that, though some branches of IO phonon modes exchange their localized positions with each other at a large m, there always exist two branches of IO phonon modes localized on each interface. The high-frequency IO phonon modes compared with the low-frequency ones play a more important role in the electron phonon interaction. Detailed comparison of the dispersion behaviours of the IO phonons and electron IO phonon couplings properties in wurtzite QWWs with those in zinc-blende QWWs has also been made.
Review of microwave electro-phononics in semiconductor nanostructures
NASA Astrophysics Data System (ADS)
Akimov, Andrey V.; Poyser, Caroline L.; Kent, Anthony J.
2017-05-01
Electro-phononics aims at developing devices which transform high frequency acoustic waves into electrical or microwave signals and back. This would eliminate the need for expensive and nonportable mode-locked lasers in phononic experiments increasing their ease and portability. The present review describes the main achievements in electro-phononics during the last decade. The first three sections of the review concern well developed ultrasonic and picosecond acoustic methods. While the next three sections give a review of recent experiments with various semiconductor nanodevices which allow the detection and generation of coherent acoustic phonons. Depending on the design of the electro-phononic device, it becomes possible to measure the actual or rectified temporal evolutions of the high-frequency acoustic field. A variation on these techniques is to exploit heterodyne mixing of coherent phonons with microwaves, it is then possible to perform sub-THz phonon spectroscopy experiments by lowering the frequency of the detected signal and using GHz detection electrical techniques. A further interesting approach is the phononic chip where various electro-phononic devices are integrated into a single complex nanostructure. Electro-phononic principles of the generation of THz phonons are developed utilizing the unique properties of doped semiconductor superlattices.
Molecular dynamics study of phonon screening in graphene
NASA Astrophysics Data System (ADS)
Javvaji, Brahmanandam; Roy Mahapatra, D.; Raha, S.
2014-04-01
Phonon interaction with electrons or phonons or with structural defects result in a phonon mode conversion. The mode conversion is governed by the frequency wave-vector dispersion relation. The control over phonon mode or the screening of phonon in graphene is studied using the propagation of amplitude modulated phonon wave-packet. Control over phonon properties like frequency and velocity opens up several wave guiding, energy transport and thermo-electric applications of graphene. One way to achieve this control is with the introduction of nano-structured scattering in the phonon path. Atomistic model of thermal energy transport is developed which is applicable to devices consisting of source, channel and drain parts. Longitudinal acoustic phononmode is excited fromone end of the device. Molecular dynamics based time integration is adopted for the propagation of excited phonon to the other end of the device. The amount of energy transfer is estimated from the relative change of kinetic energy. Increase in the phonon frequency decreases the kinetic energy transmission linearly in the frequency band of interest. Further reduction in transmission is observed with the tuning of channel height of the device by increasing the boundary scattering. Phonon mode selective transmission control have potential application in thermal insulation or thermo-electric application or photo-thermal amplification.
Phononic Origins of Friction in Carbon Nanotube Oscillators.
Prasad, Matukumilli V D; Bhattacharya, Baidurya
2017-03-01
Phononic coupling can have a significant role in friction between nanoscale surfaces. We find frictional dissipation per atom in carbon nanotube (CNT) oscillators to depend significantly on interface features such as contact area, commensurability, and by end-capping of the inner core. We perform large-scale phonon wavepacket MD simulations to study phonon coupling between a 250 nm long (10,10) outer tube and inner cores of four different geometries. Five different phonon polarizations known to have dominant roles in thermal transport are selected, and transmission coefficient plots for a range of phonon energies along with phonon scattering dynamics at specific energies are obtained. We find that the length of interface affects friction only through LA phonon scattering and has a significant nonlinear effect on total frictional force. Incommensurate contact does not always give rise to superlubricity: the net effect of two competing interaction mechanisms shown by longitudinal and transverse phonons decides the role of commensurability. Capping of the core has no effect on acoustic phonons but destroys the coherence of transverse optical phonons and creates diffusive scattering. In contrast, the twisting and radial breathing phonon modes have perfect transmission at all energies and can be deemed as the enablers of ultralow friction in CNT oscillators. Our work suggests that tuning of interface geometries can give rise to desirable friction properties in nanoscale devices.
Towards a microscopic understanding of the phonon bottleneck
Garanin, D. A.
2007-03-01
The problem of the phonon bottleneck in the relaxation of two-level systems (spins) to a narrow group of resonant phonons via emission-absorption processes is investigated from first principles. It is shown that the kinetic approach based on the Pauli master equation is invalid because of the narrow distribution of the phonons exchanging their energy with the spins. This results in a long-memory effect that can be best taken into account by introducing an additional dynamical variable corresponding to the nondiagonal matrix elements responsible for spin-phonon correlation. The resulting system of dynamical equations describes the phonon-bottleneck plateau in the spin excitation, as well as a gap in the spin-phonon spectrum, for any finite concentration of spins. On the other hand, it does not accurately render the line shape of emitted phonons and still needs improving.
Acoustic phonon confinement in silicon nanolayers: Effect on electron mobility
NASA Astrophysics Data System (ADS)
Donetti, L.; Gámiz, F.; Roldán, J. B.; Godoy, A.
2006-07-01
We demonstrate the confinement of acoustic phonons in ultrathin silicon layers and study its effect on electron mobility. We develop a model for confined acoustic phonons in an ideal single-layer structure and in a more realistic three-layer structure. Phonon quantization is recovered, and the dispersion relations for distinct phonon modes are computed. This allows us to obtain the confined phonon scattering rates and, using Monte Carlo simulations, to compute the electron mobility in ultrathin silicon on insulator inversion layers. Thus, comparing the results with those obtained using the bulk phonon model, we are able to conclude that it is very important to include confined acoustic phonon models in the electron transport simulations of ultrathin devices, if we want to reproduce the actual behavior of electron transport in silicon layers of nanometric thickness.
NASA Astrophysics Data System (ADS)
Dermez, Rasim
2016-10-01
It is solved a time-dependent Hamiltonian using a unitary transformation method which Λ(t) type is used to engineer a cascade Ξ scheme interaction between the vibrational phonons and trapped three-level ion. Quantum entanglement is characterized by comparing concurrence and negativity of the time-dependent ionic-phononic system. In this quantum system, we obtain that the amount of concurrence can be tuned between 0 and 0.99 while the amount of negativity changes between 0 and 0.49.
Frequency stabilization of the zero-phonon line of a quantum dot via phonon-assisted active feedback
Hansom, Jack; Schulte, Carsten H. H.; Matthiesen, Clemens; Stanley, Megan J.; Atatüre, Mete
2014-10-27
We report on the feedback stabilization of the zero-phonon emission frequency of a single InAs quantum dot. The spectral separation of the phonon-assisted component of the resonance fluorescence provides a probe of the detuning between the zero-phonon transition and the resonant driving laser. Using this probe in combination with active feedback, we stabilize the zero-phonon transition frequency against environmental fluctuations. This protocol reduces the zero-phonon fluorescence intensity noise by a factor of 22 by correcting for environmental noise with a bandwidth of 191 Hz, limited by the experimental collection efficiency. The associated sub-Hz fluctuations in the zero-phonon central frequency are reduced by a factor of 7. This technique provides a means of stabilizing the quantum dot emission frequency without requiring access to the zero-phonon emission.
Zhou, Changjiang; Sai, Yi; Chen, Jiujiu
2016-09-01
This paper theoretically investigates the band gaps of Lamb mode waves in two-dimensional magnetoelastic phononic crystal slabs by an applied external magnetostatic field. With the assumption of uniformly oriented magnetization, an equivalent piezomagnetic material model is used. The effects of magnetostatic field on phononic crystals are considered carefully in this model. The numerical results indicate that the width of the first band gap is significantly changed by applying the external magnetic field with different amplitude, and the ratio between the maximum and minimum gap widths reaches 228%. Further calculations demonstrate that the orientation of the magnetic field obviously affects the width and location of the first band gap. The contactless tunability of the proposed phononic crystal slabs shows many potential applications of vibration isolation in engineering. Copyright © 2016 Elsevier B.V. All rights reserved.
Yan, Zhequan; Chen, Liang; Yoon, Mina; ...
2016-01-12
Hexagonal boron nitride (h-BN) is a substrate for graphene based nano-electronic devices. We investigate the ballistic phonon transport at the interface of vertically stacked graphene and h-BN heterostructures using first principles density functional theory and atomistic Green's function simulations considering the influence of lattice stacking. We compute the frequency and wave-vector dependent transmission function and observe distinct stacking-dependent phonon transmission features for the h-BN/graphene/h-BN sandwiched systems. We find that the in-plane acoustic modes have the dominant contributions to the phonon transmission and thermal boundary conductance (TBC) for the interfaces with the carbon atom located directly on top of the boronmore » atom (C–B matched) because of low interfacial spacing. The low interfacial spacing is a consequence of the differences in the effective atomic volume of N and B and the difference in the local electron density around N and B. For the structures with the carbon atom directly on top of the nitrogen atom (C–N matched), the spatial distance increases and the contribution of in-plane modes to the TBC decreases leading to higher contributions by out-of-plane acoustic modes. We find that the C–B matched interfaces have stronger phonon–phonon coupling than the C–N matched interfaces, which results in significantly higher TBC (more than 50%) in the C–B matched interface. The findings in this study will provide insights to understand the mechanism of phonon transport at h-BN/graphene/h-BN interfaces, to better explain the experimental observations and to engineer these interfaces to enhance heat dissipation in graphene based electronic devices.« less
Yan, Zhequan; Chen, Liang; Yoon, Mina; Kumar, Satish
2016-01-12
Hexagonal boron nitride (h-BN) is a substrate for graphene based nano-electronic devices. We investigate the ballistic phonon transport at the interface of vertically stacked graphene and h-BN heterostructures using first principles density functional theory and atomistic Green's function simulations considering the influence of lattice stacking. We compute the frequency and wave-vector dependent transmission function and observe distinct stacking-dependent phonon transmission features for the h-BN/graphene/h-BN sandwiched systems. We find that the in-plane acoustic modes have the dominant contributions to the phonon transmission and thermal boundary conductance (TBC) for the interfaces with the carbon atom located directly on top of the boron atom (C–B matched) because of low interfacial spacing. The low interfacial spacing is a consequence of the differences in the effective atomic volume of N and B and the difference in the local electron density around N and B. For the structures with the carbon atom directly on top of the nitrogen atom (C–N matched), the spatial distance increases and the contribution of in-plane modes to the TBC decreases leading to higher contributions by out-of-plane acoustic modes. We find that the C–B matched interfaces have stronger phonon–phonon coupling than the C–N matched interfaces, which results in significantly higher TBC (more than 50%) in the C–B matched interface. The findings in this study will provide insights to understand the mechanism of phonon transport at h-BN/graphene/h-BN interfaces, to better explain the experimental observations and to engineer these interfaces to enhance heat dissipation in graphene based electronic devices.
Strain effects on phonon transport in antimonene investigated using a first-principles study.
Zhang, Ai-Xia; Liu, Jiang-Tao; Guo, San-Dong; Li, Hui-Chao
2017-06-07
Strain engineering is a very effective method to continuously tune the electronic, topological, optical and thermoelectric properties of materials. In this work, strain-dependent phonon transport of recently-fabricated antimonene (Sb monolayers) under biaxial strain is investigated using a combination of first-principles calculations and the linearized phonon Boltzmann equation within the single-mode relaxation time approximation (RTA). It is found that the ZA dispersion of antimonene with strain less than -1% gives imaginary frequencies, which suggests that compressive strain can induce structural instability. Experimentally, it is possible to enhance structural stability by tensile strain. The calculated results show that lattice thermal conductivity increases with strain increasing from -1% to 6%, and lattice thermal conductivity at 6% strain is 5.6 times larger than that at -1% strain at room temperature. It is interesting that lattice thermal conductivity is inversely proportional to the buckling parameter h in a considered strain range. Such a strain dependence of lattice thermal conductivity is attributed to enhanced phonon lifetimes caused by increased strain, while group velocities have a decreased effect on lattice thermal conductivity with increasing strain. It is found that acoustic branches dominate the lattice thermal conductivity over the full strain range. The cumulative room-temperature lattice thermal conductivity at -1% strain converges to a maximum with the phonon mean free path (MFP) at 50 nm, while that at 6% strain becomes as large as 44 μm, which suggests that strain can give rise to very strong size effects on lattice thermal conductivity in antimonene. Finally, the increased lattice thermal conductivity caused by increasing strain can be explained by a reduced polarized covalent bond, inducing weak phonon anharmonicity. These results may provide guidance on fabrication techniques of group-VA element (As, Sb, Bi) monolayers, and offer
Polaronic behavior and electron-phonon interaction in cuprates
NASA Astrophysics Data System (ADS)
Gunnarsson, Olle
2005-03-01
Photoemission and neutron scattering indicate a substantial electron-phonon coupling in high-Tc cuprates. To address the associated anomalous softening of a half-breathing Cu-O bond-stretching phonon, we derive a t-J model with electron-phonon coupling.^1 Using input parameters from band structure calculations and solving the model by exact diagonalization, we obtain a good description of the phonon softening.^1 We study the interplay of the electron-phonon and Coulomb interactions for a (weakly) doped Mott-Hubbard insulator. Using sum-rules, we find that that the effect of the electron-phonon interaction on the phonon self-energy is strongly suppressed, while there is no corresponding suppression for the electron self-energy or the phonon-induced carrier-carrier interaction.^2 Photoemission suggests polaronic behavior in undoped cuprates. Calculating the electron-phonon interaction in a shell model of an undoped cuprate, we find sufficiently strong coupling to give polaronic behavior. Using an adiabatic approximation, we discuss the dispersion and width of the corresponding phonon side-band. ^1O. Rösch and O. Gunnarsson, Phys. Rev. Lett. 92, 146403 (2004); ^2O. Rösch and O. Gunnarsson, Phys. Rev. Lett. (in press), cond-mat/0407064.
Phonon populations and electrical power dissipation in carbon nanotube transistors.
Steiner, Mathias; Freitag, Marcus; Perebeinos, Vasili; Tsang, James C; Small, Joshua P; Kinoshita, Megumi; Yuan, Dongning; Liu, Jie; Avouris, Phaedon
2009-05-01
Carbon nanotubes and graphene are candidate materials for nanoscale electronic devices. Both materials show weak acoustic phonon scattering and long mean free paths for low-energy charge carriers. However, high-energy carriers couple strongly to optical phonons, which leads to current saturation and the generation of hot phonons. A non-equilibrium phonon distribution has been invoked to explain the negative differential conductance observed in suspended metallic nanotubes, while Raman studies have shown the electrical generation of hot G-phonons in metallic nanotubes. Here, we present a complete picture of the phonon distribution in a functioning nanotube transistor including the G and the radial breathing modes, the Raman-inactive zone boundary K mode and the intermediate-frequency mode populated by anharmonic decay. The effective temperatures of the high- and intermediate-frequency phonons are considerably higher than those of acoustic phonons, indicating a phonon-decay bottleneck. Most importantly, inclusion of scattering by substrate polar phonons is needed to fully account for the observed electronic transport behaviour.
Design of materials configurations for enhanced phononic and electronic properties
NASA Astrophysics Data System (ADS)
Daraio, Chiara
The discovery of novel nonlinear dynamic and electronic phenomena is presented for the specific cases of granular materials and carbon nanotubes. This research was conducted for designing and constructing optimized macro-, micro- and nano-scale structural configurations of materials, and for studying their phononic and electronic behavior. Variation of composite arrangements of granular elements with different elastic properties in a linear chain-of-sphere, Y-junction or 3-D configurations led to a variety of novel phononic phenomena and interesting physical properties, which can be potentially useful for security, communications, mechanical and biomedical engineering applications. Mechanical and electronic properties of carbon nanotubes with different atomic arrangements and microstructures were also investigated. Electronic properties of Y-junction configured carbon nanotubes exhibit an exciting transistor switch behavior which is not seen in linear configuration nanotubes. Strongly nonlinear materials were designed and fabricated using novel and innovative concepts. Due to their unique strongly nonlinear and anisotropic nature, novel wave phenomena have been discovered. Specifically, violations of Snell's law were detected and a new mechanism of wave interaction with interfaces between NTPCs (Nonlinear Tunable Phononic Crystals) was established. Polymer-based systems were tested for the first time, and the tunability of the solitary waves speed was demonstrated. New materials with transformed signal propagation speed in the manageable range of 10-100 m/s and signal amplitude typical for audible speech have been developed. The enhancing of the mitigation of solitary and shock waves in 1-D chains were demonstrated and a new protective medium was designed for practical applications. 1-D, 2-D and 3-D strongly nonlinear system have been investigated providing a broad impact on the whole area of strongly nonlinear wave dynamics and creating experimental basis for new
Anyon pairing via phonon-mediated interaction
NASA Astrophysics Data System (ADS)
Kandemir, B. S.
2006-08-01
In this paper, we study the pairing of anyons subjected to an external uniform magnetic field and confined in a two-dimensional parabolic quantum dot within the framework of Fröhlich large bipolaron theory, motivated by the Wilczek’s prescription that treats anyons as composites having both charges and fictitious flux tubes. In this model, electrons bound to Aharanov-Bohm type flux tubes and surrounded by a cloud of virtual LO phonons interact with each other through the long range Coulomb and statistical potentials. In order to discuss the effects of both spatial confinement potential and external uniform magnetic field on the boundaries of the stability region of such a pairing in real space, we perform a self-consistent treatment of the ground-state energies of both an interacting anyon pair and two noninteracting anyons. Our results suggest that two interacting anyons can be bound into a condensate anyon pair through a phonon-mediated interaction.
Dispersion of Acoustic Phonons in Quasiperiodic Superlattices
NASA Astrophysics Data System (ADS)
Mishra, R. K.; Misra, K. D.; Tiwari, R. P.
The aim of this work is to present an up-to-date study of acoustic phonon excitations that can propagate in multilayered structure with constituents arranged in quasiperiodic fashion. In this paper, the dispersion relation of acoustic phonons for the quasiperiodic superlattice using different semiconducting materials, with the help of transfer matrix method, is derived at normal angle of incidence. Calculation is presented for (a) Ge/Si and (b) Nb/Cu semiconductor superlattices from 5th to 9th generations and dispersion diagrams are plotted using the famous Kronning-Penny model obtained from the transfer matrix of the structure. The concept of allowed and forbidden bands with the help of these dispersion curves in various generations of Fibonacci superlattices and the relation between imaginary value of propagation vector and the existence of forbidden bands is demonstrated.
Phonon arithmetic in a trapped ion system.
Um, Mark; Zhang, Junhua; Lv, Dingshun; Lu, Yao; An, Shuoming; Zhang, Jing-Ning; Nha, Hyunchul; Kim, M S; Kim, Kihwan
2016-04-21
Single-quantum level operations are important tools to manipulate a quantum state. Annihilation or creation of single particles translates a quantum state to another by adding or subtracting a particle, depending on how many are already in the given state. The operations are probabilistic and the success rate has yet been low in their experimental realization. Here we experimentally demonstrate (near) deterministic addition and subtraction of a bosonic particle, in particular a phonon of ionic motion in a harmonic potential. We realize the operations by coupling phonons to an auxiliary two-level system and applying transitionless adiabatic passage. We show handy repetition of the operations on various initial states and demonstrate by the reconstruction of the density matrices that the operations preserve coherences. We observe the transformation of a classical state to a highly non-classical one and a Gaussian state to a non-Gaussian one by applying a sequence of operations deterministically.
Phonon arithmetic in a trapped ion system
Um, Mark; Zhang, Junhua; Lv, Dingshun; Lu, Yao; An, Shuoming; Zhang, Jing-Ning; Nha, Hyunchul; Kim, M. S.; Kim, Kihwan
2016-01-01
Single-quantum level operations are important tools to manipulate a quantum state. Annihilation or creation of single particles translates a quantum state to another by adding or subtracting a particle, depending on how many are already in the given state. The operations are probabilistic and the success rate has yet been low in their experimental realization. Here we experimentally demonstrate (near) deterministic addition and subtraction of a bosonic particle, in particular a phonon of ionic motion in a harmonic potential. We realize the operations by coupling phonons to an auxiliary two-level system and applying transitionless adiabatic passage. We show handy repetition of the operations on various initial states and demonstrate by the reconstruction of the density matrices that the operations preserve coherences. We observe the transformation of a classical state to a highly non-classical one and a Gaussian state to a non-Gaussian one by applying a sequence of operations deterministically. PMID:27097897
Phonon dispersion relation of metallic glasses
NASA Astrophysics Data System (ADS)
Crespo, Daniel; Bruna, Pere; Valles, Araceli; Pineda, Eloi
2016-10-01
Experimental data on the phase sound speed of metallic glasses show anomalies in the terahertz range, reflecting an underlying complex behavior of their phonon dispersion spectrum not yet explained. We determine the phonon dispersion curve of metallic glasses by means of massive molecular dynamics simulations, allowing us to obtain the low-q region behavior with unprecedented detail. Results confirm that the sound speed is constant below the THz range, down to the macroscopic limit. On the contrary, a hardening of the sound speed, more notable in the transverse case, is found in the THz range. This behavior is modeled in terms of a relaxation model. The model gives quantitative agreement and allows us to determine a new threshold frequency ωh, at the end of the boson-peak region. Above ωh the shear modulus increases dramatically, reflecting the end of the amorphous-like acoustic propagation region characterized by the excess density of vibrational states.
Magnon rainbows filtered through phonon clouds
NASA Astrophysics Data System (ADS)
Boona, Stephen R.
2016-06-01
The study of heat flow in magnetic insulators is a topic of significant interest in spin caloritronics, especially for understanding the nuanced origins of the spin Seebeck effect (SSE). Recent work by Diniz and Costa (2016 New J. Phys. 18 052002) provides insight into this subject by presenting a microscopic model for the spectral dependence of magnon-phonon interactions in magnetic insulators, which has been a challenging puzzle for decades. Their new paper shows that phonon-mediated magnon-magnon interactions affect the lifetime of magnons differently depending on the magnon wavelength. As a result, low energy magnons transport spin more efficiently, and are more sensitive to applied magnetic fields. These results help explain some unexpected behavior in the SSE recently reported in several experiments.
Ignatov, Anatoly A.
2014-08-28
The current (voltage) responsivity of a superlattice-based diode detector has been studied theoretically in the terahertz frequency band that includes the region of the polar-optical phonon frequencies. Within the framework of an equivalent circuit approach, the electro-dynamical model which allows one to analyze the responsivity taking into account the hybridization of the plasma and polar-optical phonon modes both in the substrate and in the cladding layers of the diode has been suggested. It has been shown that the presence of the plasma and polar-optical phonon modes gives rise to strong features in the frequency dependence of the responsivity, i.e., to the resonance dips and peaks at frequencies of hybridized plasmons and polar-optical phonons. It has been suggested that by judicious engineering of the superlattice-based diodes, it would be possible to enhance substantially their responsivity in the terahertz frequency band.
Zeng, Lingping; Collins, Kimberlee C; Hu, Yongjie; Luckyanova, Maria N; Maznev, Alexei A; Huberman, Samuel; Chiloyan, Vazrik; Zhou, Jiawei; Huang, Xiaopeng; Nelson, Keith A; Chen, Gang
2015-11-27
Heat conduction in semiconductors and dielectrics depends upon their phonon mean free paths that describe the average travelling distance between two consecutive phonon scattering events. Nondiffusive phonon transport is being exploited to extract phonon mean free path distributions. Here, we describe an implementation of a nanoscale thermal conductivity spectroscopy technique that allows for the study of mean free path distributions in optically absorbing materials with relatively simple fabrication and a straightforward analysis scheme. We pattern 1D metallic grating of various line widths but fixed gap size on sample surfaces. The metal lines serve as both heaters and thermometers in time-domain thermoreflectance measurements and simultaneously act as wire-grid polarizers that protect the underlying substrate from direct optical excitation and heating. We demonstrate the viability of this technique by studying length-dependent thermal conductivities of silicon at various temperatures. The thermal conductivities measured with different metal line widths are analyzed using suppression functions calculated from the Boltzmann transport equation to extract the phonon mean free path distributions with no calibration required. This table-top ultrafast thermal transport spectroscopy technique enables the study of mean free path spectra in a wide range of technologically important materials.
Zeng, Lingping; Collins, Kimberlee C.; Hu, Yongjie; ...
2015-11-27
Heat conduction in semiconductors and dielectrics depends upon their phonon mean free paths that describe the average travelling distance between two consecutive phonon scattering events. Nondiffusive phonon transport is being exploited to extract phonon mean free path distributions. Here, we describe an implementation of a nanoscale thermal conductivity spectroscopy technique that allows for the study of mean free path distributions in optically absorbing materials with relatively simple fabrication and a straightforward analysis scheme. We pattern 1D metallic grating of various line widths but fixed gap size on sample surfaces. The metal lines serve as both heaters and thermometers in time-domainmore » thermoreflectance measurements and simultaneously act as wiregrid polarizers that protect the underlying substrate from direct optical excitation and heating. We demonstrate the viability of this technique by studying length-dependent thermal conductivities of silicon at various temperatures. The thermal conductivities measured with different metal line widths are analyzed using suppression functions calculated from the Boltzmann transport equation to extract the phonon mean free path distributions with no calibration required. Furthermore, this table-top ultrafast thermal transport spectroscopy technique enables the study of mean free path spectra in a wide range of technologically important materials.« less
Zeng, Lingping; Collins, Kimberlee C.; Hu, Yongjie; Luckyanova, Maria N.; Maznev, Alexei A.; Huberman, Samuel; Chiloyan, Vazrik; Zhou, Jiawei; Huang, Xiaopeng; Nelson, Keith A.; Chen, Gang
2015-11-27
Heat conduction in semiconductors and dielectrics depends upon their phonon mean free paths that describe the average travelling distance between two consecutive phonon scattering events. Nondiffusive phonon transport is being exploited to extract phonon mean free path distributions. Here, we describe an implementation of a nanoscale thermal conductivity spectroscopy technique that allows for the study of mean free path distributions in optically absorbing materials with relatively simple fabrication and a straightforward analysis scheme. We pattern 1D metallic grating of various line widths but fixed gap size on sample surfaces. The metal lines serve as both heaters and thermometers in time-domain thermoreflectance measurements and simultaneously act as wiregrid polarizers that protect the underlying substrate from direct optical excitation and heating. We demonstrate the viability of this technique by studying length-dependent thermal conductivities of silicon at various temperatures. The thermal conductivities measured with different metal line widths are analyzed using suppression functions calculated from the Boltzmann transport equation to extract the phonon mean free path distributions with no calibration required. Furthermore, this table-top ultrafast thermal transport spectroscopy technique enables the study of mean free path spectra in a wide range of technologically important materials.
Zeng, Lingping; Collins, Kimberlee C.; Hu, Yongjie; Luckyanova, Maria N.; Maznev, Alexei A.; Huberman, Samuel; Chiloyan, Vazrik; Zhou, Jiawei; Huang, Xiaopeng; Nelson, Keith A.; Chen, Gang
2015-01-01
Heat conduction in semiconductors and dielectrics depends upon their phonon mean free paths that describe the average travelling distance between two consecutive phonon scattering events. Nondiffusive phonon transport is being exploited to extract phonon mean free path distributions. Here, we describe an implementation of a nanoscale thermal conductivity spectroscopy technique that allows for the study of mean free path distributions in optically absorbing materials with relatively simple fabrication and a straightforward analysis scheme. We pattern 1D metallic grating of various line widths but fixed gap size on sample surfaces. The metal lines serve as both heaters and thermometers in time-domain thermoreflectance measurements and simultaneously act as wire-grid polarizers that protect the underlying substrate from direct optical excitation and heating. We demonstrate the viability of this technique by studying length-dependent thermal conductivities of silicon at various temperatures. The thermal conductivities measured with different metal line widths are analyzed using suppression functions calculated from the Boltzmann transport equation to extract the phonon mean free path distributions with no calibration required. This table-top ultrafast thermal transport spectroscopy technique enables the study of mean free path spectra in a wide range of technologically important materials. PMID:26612032
NASA Astrophysics Data System (ADS)
Zeng, Lingping; Collins, Kimberlee C.; Hu, Yongjie; Luckyanova, Maria N.; Maznev, Alexei A.; Huberman, Samuel; Chiloyan, Vazrik; Zhou, Jiawei; Huang, Xiaopeng; Nelson, Keith A.; Chen, Gang
2015-11-01
Heat conduction in semiconductors and dielectrics depends upon their phonon mean free paths that describe the average travelling distance between two consecutive phonon scattering events. Nondiffusive phonon transport is being exploited to extract phonon mean free path distributions. Here, we describe an implementation of a nanoscale thermal conductivity spectroscopy technique that allows for the study of mean free path distributions in optically absorbing materials with relatively simple fabrication and a straightforward analysis scheme. We pattern 1D metallic grating of various line widths but fixed gap size on sample surfaces. The metal lines serve as both heaters and thermometers in time-domain thermoreflectance measurements and simultaneously act as wire-grid polarizers that protect the underlying substrate from direct optical excitation and heating. We demonstrate the viability of this technique by studying length-dependent thermal conductivities of silicon at various temperatures. The thermal conductivities measured with different metal line widths are analyzed using suppression functions calculated from the Boltzmann transport equation to extract the phonon mean free path distributions with no calibration required. This table-top ultrafast thermal transport spectroscopy technique enables the study of mean free path spectra in a wide range of technologically important materials.
Comments on polaron-phonon scattering theory
NASA Astrophysics Data System (ADS)
Tulub, A. V.
2015-10-01
We use the polaron state function described in terms of coupled classical and quantum fields to calculate the cross section of phonon scattering on a polaron. The value of the resonance momentum is determined by asymptotic values of several integrals. Calculating them with crystal parameters taken into account leads to bounds on the maximum value of the coupling constant. We confirm that the applicability domain of the strong-coupling approximation is near zero.
Quantum Coherent Electron-Phonon Nanolaboratories
2006-05-31
published as “Single-crystal aluminum nitride nanomechanical resonators”, A.N. Cleland, M. Pophristic and I. Ferguson , Appl. Phys. Lett. 79, 2070 (2001...nanostructured phononic crystals”, Phys. Rev. B 64, 172301 (2001) A.N. Cleland, M. Pophristic and I. Ferguson , “Single-crystal aluminum nitride...Phys. Lett. 79, 1202 ~2001!. 6 M. J. Kelly, R. J. Brown, C. G. Smith, D. A. Wharam, M. Pepper , H. Ahmed, D. G. Hasko, D. C. Peacock, J. E. F. Frost, and
NASA Astrophysics Data System (ADS)
Romano, Giuseppe; Kolpak, Alexie M.
2017-03-01
Boundary-engineering in nanostructures has the potential to dramatically impact the development of materials for high- efficiency conversion of thermal energy directly into electricity. In particular, nanostructuring of semiconductors can lead to strong suppression of heat transport with little degradation of electrical conductivity. Although this combination of material properties is promising for thermoelectric materials, it remains largely unexplored. In this work, we introduce a novel concept, the directional phonon suppression function, to unravel boundary-dominated heat transport in unprecedented detail. Using a combination of density functional theory and the Boltzmann transport equation, we compute this quantity for nanoporous silicon materials. We first compute the thermal conductivity for the case with aligned circular pores, confirming a significant thermal transport degradation with respect to the bulk. Then, by analyzing the information on the directionality of phonon suppression in this system, we identify a new structure of rectangular pores with the same porosity that enables a four-fold decrease in thermal transport with respect to the circular pores. Our results illustrate the utility of the directional phonon suppression function, enabling new avenues for systematic thermal conductivity minimization and potentially accelerating the engineering of next-generation thermoelectric devices.
Romano, Giuseppe; Kolpak, Alexie M.
2017-01-01
Boundary-engineering in nanostructures has the potential to dramatically impact the development of materials for high- efficiency conversion of thermal energy directly into electricity. In particular, nanostructuring of semiconductors can lead to strong suppression of heat transport with little degradation of electrical conductivity. Although this combination of material properties is promising for thermoelectric materials, it remains largely unexplored. In this work, we introduce a novel concept, the directional phonon suppression function, to unravel boundary-dominated heat transport in unprecedented detail. Using a combination of density functional theory and the Boltzmann transport equation, we compute this quantity for nanoporous silicon materials. We first compute the thermal conductivity for the case with aligned circular pores, confirming a significant thermal transport degradation with respect to the bulk. Then, by analyzing the information on the directionality of phonon suppression in this system, we identify a new structure of rectangular pores with the same porosity that enables a four-fold decrease in thermal transport with respect to the circular pores. Our results illustrate the utility of the directional phonon suppression function, enabling new avenues for systematic thermal conductivity minimization and potentially accelerating the engineering of next-generation thermoelectric devices. PMID:28338003
NASA Astrophysics Data System (ADS)
Xiong, Shiyun; Sääskilahti, Kimmo; Kosevich, Yuriy A.; Han, Haoxue; Donadio, Davide; Volz, Sebastian
2016-07-01
Understanding the design rules to obtain materials that enable a tight control of phonon transport over a broad range of frequencies would aid major developments in thermoelectric energy harvesting, heat management in microelectronics, and information and communication technology. Using atomistic simulations we show that the metamaterials approach relying on localized resonances is very promising to engineer heat transport at the nanoscale. Combining designed resonant structures to alloying can lead to extremely low thermal conductivity in silicon nanowires. The hybridization between resonant phonons and propagating modes greatly reduces the group velocities and the phonon mean free paths in the low frequency acoustic range below 4 THz. Concurrently, alloy scattering hinders the propagation of high frequency thermal phonons. Our calculations establish a rationale between the size, shape, and period of the resonant structures, and the thermal conductivity of the nanowire, and demonstrate that this approach is even effective to block phonon transport in wavelengths much longer than the size and period of the surface resonant structures. A further consequence of using resonant structures is that they are not expected to scatter electrons, which is beneficial for thermoelectric applications.
Phonon-lifetimes in demixing systems
NASA Astrophysics Data System (ADS)
Davaasambuu, J.; Güthoff, F.; Petri, M.; Hradil, K.; Schober, H.; Ollivier, J.; Eckold, G.
2012-06-01
The dynamics of silver-alkali halide mixed single crystals (AgxNa1-xBr, x = 0.23, 0.35, 0.40 and 0.70) were studied by inelastic neutron scattering during the process of spinodal decomposition. Using the thermal three-axes spectrometer PUMA as well as the time-of-flight spectrometer IN5, the time evolution of phonons was observed in time-resolved, stroboscopic measurements. Complementary to the study of long wavelength acoustic phonons, as studied previously, we extended these investigations to Brillouin-zone boundary modes that are particularly sensitive to variations of the local structure. Starting from the homogeneous mixed phase the behaviour of these modes during demixing is observed in real-time. A simple dynamical model based on local structure variants helps to interpret the results. It is shown that the phonon lifetimes vary strongly during the phase separation and increase drastically during the coarsening process. Up to a critical size of precipitates of about 10 nm, zone-boundary modes are found to be strongly damped, while beyond the line widths are reduced to the experimental resolution. This finding leads to the conclusion that the typical mean free path of these modes is of the order of 10 nm, which corresponds to 20 unit cells.
Phonons of the anomalous element cerium
Krisch, Michael; Farber, D. L.; Xu, R.; Antonangeli, Daniele; Aracne, C. M.; Beraud, Alexandre; Chiang, Tai-Chang; Zarestky, J.; Kim, Duck Young; Isaev, Eyvaz I.; Ahuja, Rajeev; Johansson, Börje
2011-01-01
Many physical and chemical properties of the light rare-earths and actinides are governed by the active role of f electrons, and despite intensive efforts the details of the mechanisms of phase stability and transformation are not fully understood. A prominent example which has attracted a lot of interest, both experimentally and theoretically over the years is the isostructural γ - α transition in cerium. We have determined by inelastic X-ray scattering, the complete phonon dispersion scheme of elemental cerium across the γ → α transition, and compared it with theoretical results using ab initio lattice dynamics. Several phonon branches show strong changes in the dispersion shape, indicating large modifications in the interactions between phonons and conduction electrons. This is reflected as well by the lattice Grüneisen parameters, particularly around the X point. We derive a vibrational entropy change , illustrating the importance of the lattice contribution to the transition. Additionally, we compare first principles calculations with the experiments to shed light on the mechanism underlying the isostructural volume collapse in cerium under pressure. PMID:21597000
Universal exchange-driven phonon splitting
NASA Astrophysics Data System (ADS)
Deisenhofer, Joachim; Kant, Christian; Schmidt, Michael; Wang, Zhe; Mayr, Franz; Tsurkan, Vladimir; Loidl, Alois
2012-02-01
We report on a linear dependence of the phonon splitting on the non-dominant exchange coupling Jnd in the antiferromagnetic monoxides MnO, Fe0.92O, CoO and NiO, and in the highly frustrated antiferromagnetic spinels CdCr2O4, MgCr2O4 and ZnCr2O4. For the monoxides our results directly confirm the theoretical prediction of a predominantly exchange induced splitting of the zone-centre optical phonon [1,2]. We find the linear relation δφ= βJndS^2 with slope β = 3.7. This relation also holds for a very different class of systems, namely the highly frustrated chromium spinels. Our finding suggests a universal dependence of the exchange-induced phonon splitting at the antiferromagnetic transition on the non-dominant exchange coupling [3].[4pt] [1] S. Massidda et al., Phys. Rev. Lett. 82, 430 (1999).[0pt] [2] W. Luo et al., Solid State Commun. 142, 504 (2007).[0pt] [3] Ch. Kant et al., arxiv:1109.4809.
Disruption of superlattice phonons by interfacial mixing
NASA Astrophysics Data System (ADS)
Huberman, Samuel C.; Larkin, Jason M.; McGaughey, Alan J. H.; Amon, Cristina H.
2013-10-01
Molecular dynamics simulations and lattice dynamics calculations are used to study the vibrational modes and thermal transport in Lennard-Jones superlattices with perfect and mixed interfaces. The secondary periodicity of the superlattices leads to a vibrational spectrum (i.e., dispersion relation) that is distinct from the bulk spectra of the constituent materials. The mode eigenvectors of the perfect superlattices are found to be good representations of the majority of the modes in the mixed superlattices for up to 20% interfacial mixing, allowing for extraction of phonon frequencies and lifetimes. Using the frequencies and lifetimes, the in-plane and cross-plane thermal conductivities are predicted using a solution of the Boltzmann transport equation (BTE), with agreement found with predictions from the Green-Kubo method for the perfect superlattices. For the mixed superlattices, the Green-Kubo and BTE predictions agree for the cross-plane direction, where thermal conductivity is dominated by low-frequency modes whose eigenvectors are not affected by the mixing. For the in-plane direction, mid-frequency modes that contribute to thermal transport are disrupted by the mixing, leading to an underprediction of thermal conductivity by the BTE. The results highlight the importance of using a dispersion relation that includes the secondary periodicity when predicting phonon properties in perfect superlattices and emphasize the challenges of estimating the effects of disorder on phonon properties.
Nonlocal dynamics of dissipative phononic fluids
NASA Astrophysics Data System (ADS)
Nemati, Navid; Lee, Yoonkyung E.; Lafarge, Denis; Duclos, Aroune; Fang, Nicholas
2017-06-01
We describe the nonlocal effective properties of a two-dimensional dissipative phononic crystal made by periodic arrays of rigid and motionless cylinders embedded in a viscothermal fluid such as air. The description is based on a nonlocal theory of sound propagation in stationary random fluid/rigid media that was proposed by Lafarge and Nemati [Wave Motion 50, 1016 (2013), 10.1016/j.wavemoti.2013.04.007]. This scheme arises from a deep analogy with electromagnetism and a set of physics-based postulates including, particularly, the action-response procedures, whereby the effective density and bulk modulus are determined. Here, we revisit this approach, and clarify further its founding physical principles through presenting it in a unified formulation together with the two-scale asymptotic homogenization theory that is interpreted as the local limit. Strong evidence is provided to show that the validity of the principles and postulates within the nonlocal theory extends to high-frequency bands, well beyond the long-wavelength regime. In particular, we demonstrate that up to the third Brillouin zone including the Bragg scattering, the complex and dispersive phase velocity of the least-attenuated wave in the phononic crystal which is generated by our nonlocal scheme agrees exactly with that reproduced by a direct approach based on the Bloch theorem and multiple scattering method. In high frequencies, the effective wave and its associated parameters are analyzed by treating the phononic crystal as a random medium.
Phonon induced magnetism in ionic materials
NASA Astrophysics Data System (ADS)
Restrepo, Oscar D.; Antolin, Nikolas; Jin, Hyungyu; Heremans, Joseph P.; Windl, Wolfgang
2014-03-01
Thermoelectric phenomena in magnetic materials create exciting possibilities in future spin caloritronic devices by manipulating spin information using heat. An accurate understanding of the spin-lattice interactions, i.e. the coupling between magnetic excitations (magnons) and lattice vibrations (phonons), holds the key to unraveling their underlying physics. We report ab initio frozen-phonon calculations of CsI that result in non-zero magnetization when the degeneracy between spin-up and spin-down electronic density of states is lifted for certain phonon displacement patterns. For those, the magnetization as a function of atomic displacement shows a sharp resonance due to the electronic states on the displaced Cs atoms, while the electrons on indium form a continuous background magnetization. We relate this resonance to the generation of a two-level system in the spin-polarized Cs partial density of states as a function of displacement, which we propose to be described by a simple resonant-susceptibility model. Current work extends these investigations to semiconductors such as InSb. ODR and WW are supported by the Center for Emergent Materials, an NSF MRSEC at OSU (Grant DMR-0820414).HJ and JPH are supported by AFOSR MURI Cryogenic Peltier Cooling, Contract #FA9550-10-1-0533.
Energy Guiding and Harvesting through Phonon-Engineered Graphene
2016-01-28
improve the performance of carbon nanotube array transistors. Such transistors suffer about two orders of magnitude performance penalty due to high... nanotube - nanotube resistances in the current pathways from source to drain. Thus, under normal operation CNT array 1. REPORT DATE (DD-MM-YYYY) 4. TITLE...Research Office P.O. Box 12211 Research Triangle Park, NC 27709-2211 Carbon Nanotubes , FETs, Nanosoldering REPORT DOCUMENTATION PAGE 11. SPONSOR
Topological phononic states of underwater sound based on coupled ring resonators
He, Cheng; Li, Zheng; Ni, Xu; Sun, Xiao-Chen; Yu, Si-Yuan; Lu, Ming-Hui Liu, Xiao-Ping; Chen, Yan-Feng
2016-01-18
We report a design of topological phononic states for underwater sound using arrays of acoustic coupled ring resonators. In each individual ring resonator, two degenerate acoustic modes, corresponding to clockwise and counter-clockwise propagation, are treated as opposite pseudospins. The gapless edge states arise in the bandgap resulting in protected pseudospin-dependent sound transportation, which is a phononic analogue of the quantum spin Hall effect. We also investigate the robustness of the topological sound state, suggesting that the observed pseudospin-dependent sound transportation remains unless the introduced defects facilitate coupling between the clockwise and counter-clockwise modes (in other words, the original mode degeneracy is broken). The topological engineering of sound transportation will certainly promise unique design for next generation of acoustic devices in sound guiding and switching, especially for underwater acoustic devices.
From Modal Mixing to Tunable Functional Switches in Nonlinear Phononic Crystals
NASA Astrophysics Data System (ADS)
Ganesh, R.; Gonella, S.
2015-02-01
We introduce a paradigm for spatial and modal wave manipulation based on nonlinear phononic crystals and explore its potential for engineering wave control systems with tunable, adaptive, and multifunctional characteristics. Our approach exploits nonlinear mechanisms to stretch the frequency signature of the wave response and distribute it over multiple modes, thereby activating a mixture of modal characteristics and enabling functionalities associated with high-frequency optical modes, even while operating in the low-frequency regime. To elucidate the versatility of this approach, we consider different granular crystal configurations that span the available landscape of crystal topologies and wave control functionalities. The ability to switch between complementary functionalities allows rethinking nonlinear phononic crystals as programmable acoustic ports that form the building blocks of a new structural logic framework enabled by nonlinearity.
A new class of tunable hypersonic phononic crystals based on polymer-tethered colloids.
Alonso-Redondo, E; Schmitt, M; Urbach, Z; Hui, C M; Sainidou, R; Rembert, P; Matyjaszewski, K; Bockstaller, M R; Fytas, G
2015-09-22
The design and engineering of hybrid materials exhibiting tailored phononic band gaps are fundamentally relevant to innovative material technologies in areas ranging from acoustics to thermo-optic devices. Phononic hybridization gaps, originating from the anti-crossing between local resonant and propagating modes, have attracted particular interest because of their relative robustness to structural disorder and the associated benefit to 'manufacturability'. Although hybridization gap materials are well known, their economic fabrication and efficient control of the gap frequency have remained elusive because of the limited property variability and expensive fabrication methodologies. Here we report a new strategy to realize hybridization gap materials by harnessing the 'anisotropic elasticity' across the particle-polymer interface in densely polymer-tethered colloidal particles. Theoretical and Brillouin scattering analysis confirm both the robustness to disorder and the tunability of the resulting hybridization gap and provide guidelines for the economic synthesis of new materials with deliberately controlled gap position and width frequencies.
Two-Dimensional Phononic-Photonic Band Gap Optomechanical Crystal Cavity
NASA Astrophysics Data System (ADS)
Safavi-Naeini, Amir H.; Hill, Jeff T.; Meenehan, Seán; Chan, Jasper; Gröblacher, Simon; Painter, Oskar
2014-04-01
We present the fabrication and characterization of an artificial crystal structure formed from a thin film of silicon that has a full phononic band gap for microwave X-band phonons and a two-dimensional pseudo-band gap for near-infrared photons. An engineered defect in the crystal structure is used to localize optical and mechanical resonances in the band gap of the planar crystal. Two-tone optical spectroscopy is used to characterize the cavity system, showing a large coupling (g0/2π≈220 kHz) between the fundamental optical cavity resonance at ωo/2π =195 THz and colocalized mechanical resonances at frequency ωm/2π ≈9.3 GHz.
Acoustic phonon transmission spectra in piezoelectric AlN/GaN Fibonacci phononic crystals
NASA Astrophysics Data System (ADS)
Sesion, P. D., Jr.; Albuquerque, E. L.; Chesman, C.; Freire, V. N.
2007-08-01
We study the acoustic-phonon transmission spectra in periodic and quasiperiodic (Fibonacci type) superlattices made up from the III-V nitride materials AlN and GaN. The phonon dynamics is described by a coupled elastic and electromagnetic equations within the static field approximation model, stressing the importance of the piezoelectric polarization field in a strained condition. We use a transfer-matrix treatment to simplify the algebra, which would be otherwise quite complicated, allowing a neat analytical expressions for the phonon transmission coefficients. Numerical results, for the normal incidence case, show a strike self-similar pattern for both hexagonal (class 6 mm) and cubic symmetries crystalizations of the nitrides.
Single Circuit Parallel Computing with Phonons through Magneto-acoustics
NASA Astrophysics Data System (ADS)
Sklan, Sophia; Grossman, Jeffrey
2013-03-01
Phononic computing - the use of (typically thermal) vibrations for information processing - is a nascent technology; its capabilities are still being discovered. We analyze an alternative form of phononic computing inspired by optical, rather than electronic, computing. Using the acoustic Faraday effect, we design a phonon gyrator and thereby a means of performing computation through the manipulation of polarization in transverse phonon currents. Moreover, we establish that our gyrators act as generalized transistors and can construct digital logic gates. Exploiting the wave nature of phonons and the similarity of our logic gates, we demonstrate parallel computation within a single circuit, an effect presently unique to phonons. Finally, a generic method of designing these parallel circuits is introduced and used to analyze the feasibility of magneto-acoustic materials in realizing these circuits. This material is based upon work supported by the National Science Foundation Graduate Research Fellowship under Grant No. 1122374.
Phonon Scattering Dynamics of Thermophoretic Motion in Carbon Nanotube Oscillators.
Prasad, Matukumilli V D; Bhattacharya, Baidurya
2016-04-13
Using phonon wave packet molecular dynamics simulations, we find that anomalous longitudinal acoustic (LA) mode phonon scattering in low to moderate energy ranges is responsible for initiating thermophoretic motion in carbon nanotube oscillators. The repeated scattering of a single mode LA phonon wave packet near the ends of the inner nanotube provides a net unbalanced force that, if large enough, initiates thermophoresis. By applying a coherent phonon pulse on the outer tube, which generalizes the single mode phonon wave packet, we are able to achieve thermophoresis in a carbon nanotube oscillator. We also find the nature of the unbalanced force on end-atoms to be qualitatively similar to that under an imposed thermal gradient. The thermodiffusion coefficient obtained for a range of thermal gradients and core lengths suggest that LA phonon scattering is the dominant mechanism for thermophoresis in longer cores, whereas for shorter cores, it is the highly diffusive mechanism that provides the effective force.
Reduction of Thermal Conductivity by Nanoscale 3D Phononic Crystal
Yang, Lina; Yang, Nuo; Li, Baowen
2013-01-01
We studied how the period length and the mass ratio affect the thermal conductivity of isotopic nanoscale three-dimensional (3D) phononic crystal of Si. Simulation results by equilibrium molecular dynamics show isotopic nanoscale 3D phononic crystals can significantly reduce the thermal conductivity of bulk Si at high temperature (1000 K), which leads to a larger ZT than unity. The thermal conductivity decreases as the period length and mass ratio increases. The phonon dispersion curves show an obvious decrease of group velocities in 3D phononic crystals. The phonon's localization and band gap is also clearly observed in spectra of normalized inverse participation ratio in nanoscale 3D phononic crystal. PMID:23378898
Heterodyne x-ray diffuse scattering from coherent phonons
Kozina, M.; Trigo, M.; Chollet, M.; ...
2017-08-10
Here in this paper, we report Fourier-transform inelastic x-ray scattering measurements of photoexcited GaAs with embedded ErAs nanoparticles. We observe temporal oscillations in the x-ray scattering intensity, which we attribute to inelastic scattering from coherent acoustic phonons. Unlike in thermal equilibrium, where inelastic x-ray scattering is proportional to the phonon occupation, we show that the scattering is proportional to the phonon amplitude for coherent states. The wavevectors of the observed phonons extend beyond the excitation wavevector. The nanoparticles break the discrete translational symmetry of the lattice, enabling the generation of large wavevector coherent phonons. Elastic scattering of x-ray photons frommore » the nanoparticles provides a reference for heterodyne mixing, yielding signals proportional to the phonon amplitude.« less
Acoustic phonon spectrum and thermal transport in nanoporous alumina arrays
Kargar, Fariborz; Ramirez, Sylvester; Debnath, Bishwajit; Malekpour, Hoda; Lake, Roger; Balandin, Alexander A.
2015-10-28
We report results of a combined investigation of thermal conductivity and acoustic phonon spectra in nanoporous alumina membranes with the pore diameter decreasing from D=180 nm to 25 nm. The samples with the hexagonally arranged pores were selected to have the same porosity Ø ≈13%. The Brillouin-Mandelstam spectroscopy measurements revealed bulk-like phonon spectrum in the samples with D = 180 nm pores and spectral features, which were attributed to spatial confinement, in the samples with 25 nm and 40 nm pores. The velocity of the longitudinal acoustic phonons was reduced in the samples with smaller pores. As a result, analysis of the experimental data and calculated phonon dispersion suggests that both phonon-boundary scattering and phonon spatial confinement affect heat conduction in membranes with the feature sizes D < 40 nm.
Phonons and elasticity of cementite through the Curie temperature
NASA Astrophysics Data System (ADS)
Mauger, L.; Herriman, J. E.; Hellman, O.; Tracy, S. J.; Lucas, M. S.; Muñoz, J. A.; Xiao, Yuming; Li, J.; Fultz, B.
2017-01-01
Phonon partial densities of states (pDOS) of Fe573C were measured from cryogenic temperatures through the Curie transition at 460 K using nuclear resonant inelastic x-ray scattering. The cementite pDOS reveal that low-energy acoustic phonons shift to higher energies (stiffen) with temperature before the magnetic transition. This unexpected stiffening suggests strongly nonharmonic vibrational behavior that impacts the thermodynamics and elastic properties of cementite. Density functional theory calculations reproduced the anomalous stiffening observed experimentally in cementite by accounting for phonon-phonon interactions at finite temperatures. The calculations show that the low-energy acoustic phonon branches with polarizations along the [010] direction are largely responsible for the anomalous thermal stiffening. The effect was further localized to the motions of the FeII site within the orthorhombic structure, which participates disproportionately in the anomalous phonon stiffening.
Interaction of excitons with optical phonons in layer crystals
NASA Astrophysics Data System (ADS)
Nitsovich, Bohdan M.; Zenkova, C. Y.; Kramar, N. K.
2002-02-01
The investigation is concerned with layer crystals of the GaSe, InSe, GaTe, MoS2-type and other inorganic semiconductors, whose phonon spectrum has a great number of peculiarities, among them the availability of low-energy optical phonons. In this case the dispersion of these phonons can be essential and vary in character. The mass operator of the exciton-phonon system and the light absorption coefficient for different dispersion laws of optical phonons have been calculated. The influence of the sign of the phonon 'effective mass' on the exciton absorption band of layer crystals, which causes the opposite in sign dynamics of the absorption maximum shift, and the change of the absorption curve asymmetry have been determined.
Electron-Phonon Coupling in a CdSe Nanowire
NASA Astrophysics Data System (ADS)
Barrett, Christopher; Wang, Lin-Wang
2012-02-01
It is important to calculate the coupling between phonons and electrons in realistic nanostructures, e.g. to understand carrier cooling and dynamics in a nanowire. In this talk, we will present results of phonon spectrum calculations using a customized valence force field (VFF) method. This customized VFF method is developed to be fittable to the results of any ab-initio calculations, with density functional theory (DFT) results being used in this work. By fitting many different DFT calculations on different motifs and their perturbations, we have obtained in the custom VFF a very efficient method that closely reproduces DFT phonons for CdSe nanowires with (10-10) surfaces having Cd-Se dimerization. We have also combined the results of these phonon spectrum calculations with electronic structure calculations to obtain the electron-phonon coupling. We will present this result and and show how the electron-phonon coupling affects the carrier dynamics in the nanowire.
Phonon spectrum in a CdSe nanowire
NASA Astrophysics Data System (ADS)
Barrett, Chris; Wang, Lin-Wang
2011-03-01
It is important to calculate the phonon spectrum of realistic nanowires, e.g. to understand its thermo conductivity or to calculate the electron-phonon interaction. In this talk, we will present results of phonon spectrum calculation using valence force field (VFF) method. An important issue is to construct the VFF to describe the surface atomic displacement. We have developed a general VFF formalism to fit our VFF result with the density functional theory (DFT) calculated surface atom displacement energies. In particular, the (10-10) CdSe surface is modelled with Cd-Se dimerization. We will discuss the quality of such VFF model. The phonon spectrum of the nanowire will be presented, and its implication on the phonon transport and electron-phonon coupling will also be discussed. This work is supported by U.S. Department of Energy BES, office of science, under Contract No. DE-AC02-05CH11231.
Phonon blockade in a quadratically coupled optomechanical system
NASA Astrophysics Data System (ADS)
Xie, Hong; Liao, Chang-Geng; Shang, Xiao; Ye, Ming-Yong; Lin, Xiu-Min
2017-07-01
Phonon blockade is achieved in a quadratically coupled optomechanical system, in which the nonlinear interaction between phonons is induced by a driving field via radiation pressure. It is different from the previous standard methods, where the nonlinear interaction for observing phonon blockade is obtained by coupling the mechanical resonator to a two-level system. The effective coupling strength can be tuned by controlling the amplitudes of the driving field, which allows large nonlinearities for the optomechanical system. The second-order correlation function is discussed both analytically and numerically to characterize the phonon statistical properties and the results show that the phonon blockade is available when the effective coupling strength is larger than the mechanical decay rate. This work provides a possible way to experimentally realize phonon blockade.
Reduction of thermal conductivity by nanoscale 3D phononic crystal.
Yang, Lina; Yang, Nuo; Li, Baowen
2013-01-01
We studied how the period length and the mass ratio affect the thermal conductivity of isotopic nanoscale three-dimensional (3D) phononic crystal of Si. Simulation results by equilibrium molecular dynamics show isotopic nanoscale 3D phononic crystals can significantly reduce the thermal conductivity of bulk Si at high temperature (1000 K), which leads to a larger ZT than unity. The thermal conductivity decreases as the period length and mass ratio increases. The phonon dispersion curves show an obvious decrease of group velocities in 3D phononic crystals. The phonon's localization and band gap is also clearly observed in spectra of normalized inverse participation ratio in nanoscale 3D phononic crystal.
Pump pulse duration dependence of coherent phonon amplitudes in antimony
Misochko, O. V.
2016-08-15
Coherent optical phonons of A{sub 1k} and E{sub k} symmetry in antimony have been studied using the femtosecond pump–probe technique. By varying the pump-pulse duration and keeping the probe duration constant, it was shown that the amplitude of coherent phonons of both symmetries exponentially decreases with increasing pulse width. It was found that the amplitude decay rate for the fully symmetric phonons with larger frequency is greater than that of the doubly degenerate phonons, whereas the frequency and lifetime for coherent phonons of both symmetries do not depend on the pump-pulse duration. Based on this data, the possibility of separation between dynamic and kinematic contributions to the generation mechanism of coherent phonons is discussed.
Phonon response of some heavy Fermion systems in dynamic limit
NASA Astrophysics Data System (ADS)
Sahoo, Jitendra; Shadangi, Namita; Nayak, Pratibindhya
2017-05-01
The phonon excitation spectrum of some Heavy Fermion (HF) systems in the presence of electron-phonon interaction is studied in the dynamic limit (ω≠0). The renormalized excitation phonon frequencies (ω˜ = ω/ω0) are evaluated through Periodic Anderson Model (PAM) in the presence of electron-phonon interaction using Zubarev-type double time temperature-dependent Green function. The calculated renormalized phonon energy is analyzed through the plots of (ω˜ = ω/ω0) against temperature for different system parameters like effective coupling strength ‘g’ and the position of f-level ‘d’. The observed behavior is analyzed and found to agree with the general features of HF systems found in experiments. Further, it is observed that in finite but small q-values the propagating phonons harden and change to localized peaks.
Acoustic phonon spectrum and thermal transport in nanoporous alumina arrays
Kargar, Fariborz; Ramirez, Sylvester; Debnath, Bishwajit; ...
2015-10-28
We report results of a combined investigation of thermal conductivity and acoustic phonon spectra in nanoporous alumina membranes with the pore diameter decreasing from D=180 nm to 25 nm. The samples with the hexagonally arranged pores were selected to have the same porosity Ø ≈13%. The Brillouin-Mandelstam spectroscopy measurements revealed bulk-like phonon spectrum in the samples with D = 180 nm pores and spectral features, which were attributed to spatial confinement, in the samples with 25 nm and 40 nm pores. The velocity of the longitudinal acoustic phonons was reduced in the samples with smaller pores. As a result, analysismore » of the experimental data and calculated phonon dispersion suggests that both phonon-boundary scattering and phonon spatial confinement affect heat conduction in membranes with the feature sizes D < 40 nm.« less
Electron-phonon coupling in anthracene-pyromellitic dianhydride
NASA Astrophysics Data System (ADS)
Vermeulen, Derek; Corbin, Nathan; Goetz, Katelyn P.; Jurchescu, Oana D.; Coropceanu, Veaceslav; McNeil, L. E.
2017-06-01
In this study, the electron-phonon coupling constants of the mixed-stack organic semiconductor anthracene-pyromellitic dianhydride (A-PMDA) are determined from experimental resonant Raman and absorption spectra of the charge transfer (CT) exciton using a time-dependent resonant Raman model. The reorganization energies of both intermolecular and intramolecular phonons are determined and compared with theoretical estimates derived from density functional theory calculations; they are found to agree well. We found that the dominant contribution to the total reorganization energy is due to intramolecular phonons, with intermolecular phonons only contributing a small percentage. This work goes beyond prior studies of the electron-phonon coupling in A-PMDA by including the coupling of all Raman-active phonons to the charge transfer exciton. The possibility of orientational disorder in A-PMDA at 80 K is inferred from the inhomogeneous broadening of the absorption line shape.
Suppressing phonon transport in nanowires: A simple model for phonon-surface-roughness interaction
NASA Astrophysics Data System (ADS)
Muttalib, K. A.; Abhinav, S.
2017-08-01
Suppressing phonon propagation in nanowires is an essential goal towards achieving efficient thermoelectric devices. Recent experiments have shown unambiguously that surface roughness is a key factor that can reduce the thermal conductivity well below the Casimir limit in thin crystalline silicon nanowires. We use insights gained from the experimental studies to construct a simple analytically tractable model of the phonon-surface-roughness interaction that provides a better theoretical understanding of the effects of surface roughness on the thermal conductivity, which could potentially help in designing better thermoelectric devices.
1985-10-01
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The Seebeck Coefficient and Phonon Drag in Silicon
Mahan, Gerald; Lindsay, Lucas R.; Broido, David
2014-12-29
We present a theory of the phonon-drag Seebeck coe cient in nondegenerate semiconductors, and apply it to silicon for temperatures 30 < T < 300K. Our calculation uses only parameters from the literature, and previous calculations of the phonon lifetime. We nd excellent agreement with the measurements of Geballe and Hull [Phys.Rev. 98, 940 (1955)]. The phonon-drag term dominates at low temperature, and shows an important dependence on the dimensions of the experimental sample.
Weak phonon scattering effect of twin boundaries on thermal transmission
Dong, Huicong; Xiao, Jianwei; Melnik, Roderick; Wen, Bin
2016-01-01
To study the effect of twin boundaries on thermal transmission, thermal conductivities of twinned diamond with different twin thicknesses have been studied by NEMD simulation. Results indicate that twin boundaries show a weak phonon scattering effect on thermal transmission, which is only caused by the additional twin boundaries’ thermal resistance. Moreover, according to phonon kinetic theory, this weak phonon scattering effect of twin boundaries is mainly caused by a slightly reduced average group velocity. PMID:26822675
Computational modeling of geometry dependent phonon transport in silicon nanostructures
NASA Astrophysics Data System (ADS)
Cheney, Drew A.
Recent experiments have demonstrated that thermal properties of semiconductor nanostructures depend on nanostructure boundary geometry. Phonons are quantized mechanical vibrations that are the dominant carrier of heat in semiconductor materials and their aggregate behavior determine a nanostructure's thermal performance. Phonon-geometry scattering processes as well as waveguiding effects which result from coherent phonon interference are responsible for the shape dependence of thermal transport in these systems. Nanoscale phonon-geometry interactions provide a mechanism by which nanostructure geometry may be used to create materials with targeted thermal properties. However, the ability to manipulate material thermal properties via controlling nanostructure geometry is contingent upon first obtaining increased theoretical understanding of fundamental geometry induced phonon scattering processes and having robust analytical and computational models capable of exploring the nanostructure design space, simulating the phonon scattering events, and linking the behavior of individual phonon modes to overall thermal behavior. The overall goal of this research is to predict and analyze the effect of nanostructure geometry on thermal transport. To this end, a harmonic lattice-dynamics based atomistic computational modeling tool was created to calculate phonon spectra and modal phonon transmission coefficients in geometrically irregular nanostructures. The computational tool is used to evaluate the accuracy and regimes of applicability of alternative computational techniques based upon continuum elastic wave theory. The model is also used to investigate phonon transmission and thermal conductance in diameter modulated silicon nanowires. Motivated by the complexity of the transmission results, a simplified model based upon long wavelength beam theory was derived and helps explain geometry induced phonon scattering of low frequency nanowire phonon modes.
Weak phonon scattering effect of twin boundaries on thermal transmission.
Dong, Huicong; Xiao, Jianwei; Melnik, Roderick; Wen, Bin
2016-01-29
To study the effect of twin boundaries on thermal transmission, thermal conductivities of twinned diamond with different twin thicknesses have been studied by NEMD simulation. Results indicate that twin boundaries show a weak phonon scattering effect on thermal transmission, which is only caused by the additional twin boundaries' thermal resistance. Moreover, according to phonon kinetic theory, this weak phonon scattering effect of twin boundaries is mainly caused by a slightly reduced average group velocity.
Observation of anomalous phonons in orthorhombic rare-earth manganites
NASA Astrophysics Data System (ADS)
Gao, P.; Chen, H. Y.; Tyson, T. A.; Liu, Z. X.; Bai, J. M.; Wang, L. P.; Choi, Y. J.; Cheong, S.-W.
2010-12-01
We observe the appearance of a phonon near the lock-in temperature in orthorhombic REMnO3 (RE denotes rare earth) (RE: Lu and Ho) and anomalous phonon hardening in orthorhombic LuMnO3. The anomalous phonon occurs at the onset of spontaneous polarization. No such changes were found in incommensurate orthorhombic DyMnO3. These observations directly reveal different electric polarization mechanisms in the E-type and incommensurate-type orthorhombic REMnO3.
Lifetime of the phonons in the PLT ceramic
Barba-Ortega, J. Joya, M. R.; Londoño, F. A.
2014-11-05
The lifetimes at higher temperatures on lanthanum-modified lead titanate (PLT) are mainly due to the anharmonic decay of optical phonons into low-energy phonons. The temperature-independent contributions from inherent crystal defects and from boundary scattering become comparable to the phonon scattering contribution at lower temperatures. The thermal interaction is large at higher temperatures which decreases the phonon mean free path, and so the decay lifetime decreases as the temperature of the system is increased. This leads to the increased line width at higher temperatures. We made an estimate of the lifetimes for different concentrations and temperatures in PLT.
Observation of coherent acoustic phonons in Fibonacci superlattices
NASA Astrophysics Data System (ADS)
Mizoguchi, Kohji; Matsutani, Kei; Nakashima, Shin-Ichi; Dekorsy, Thomas; Kurz, Heinrich; Nakayama, Masaaki
1997-04-01
Coherent acoustic phonons are observed in the femtosecond time-resolved reflectivity of GaAs/AlAs Fibonacci superlattices. The time-domain data reveal a complicated superposition of many folded acoustic modes induced by the quasiperiodicity of the Fibonacci sequence. We discuss the phonon spectra from the viewpoint of the polarizability modulation due to the acoustic phonons on the basis of a photoelastic model. In addition, we demonstrate that the resonance of the heavy-hole exciton transition remarkably modifies the oscillation amplitude of the coherent phonons.
Theory of coherent phonon spectroscopy in carbon nanotubes
NASA Astrophysics Data System (ADS)
Sanders, G. D.; Stanton, C. J.; Lim, Y. S.; Yee, K. J.; Kim, J. H.; Haroz, E. H.; Booshehri, L. G.; Kono, J.
2008-03-01
We develop a theory for the generation and detection of coherent phonons in single wall carbon nanotubes. Coherent phonons are generated in the nanotube by ultrafast laser pulses via the deformation potential electron-phonon interaction with the photogenerated carriers. The electronic states are treated in a tight binding formalism which gives a description of the states over the nanotube Brillouin zone while the nanotube phonon modes are treated in a valence force field model that includes bond-stretching, in-plane and out-of-plane bond-bending, and bond-twisting interactions. Equations of motion for the coherent phonon amplitudes are obtained in a density matrix formalism and we find that the coherent phonon amplitudes satisfy driven oscillator equations. In coherent phonon spectroscopy the coherent phonons are detected by ultrafast pump probe differential transmission measurements. We find that for uniform illumination with a 5 fs pump pulse only the q = 0 radial breathing mode and a high frequency G mode are strongly excited. We will discuss excitation strengths for different coherent phonon modes and compare to recent experiments.
Three material and four material one-dimensional phononic crystals
NASA Astrophysics Data System (ADS)
Kriegel, Ilka; Scotognella, Francesco
2017-01-01
In this work, we studied one-dimensional phononic structures for selective acoustic filtering. The structures are composed of three and four materials which have different elastic properties. We have observed that the phononic band gaps split in two and three transmission valleys for the three-material and the four-material based phononic structures, respectively. Furthermore, the number of transmission peaks between the split gaps is directly related to the number of unit cells composing the phononic structures. The observations of this work can be useful for the fabrication of acoustic filters with the possibility to select the transmission of particular frequencies.
Nonperturbative theory of exciton-phonon resonances in semiconductor absorption
NASA Astrophysics Data System (ADS)
Hannewald, K.; Bobbert, P. A.
2005-09-01
We develop a theory of exciton-phonon sidebands in the absorption spectra of semiconductors. The theory does not rely on an ad hoc exciton-phonon picture, but is based on a more fundamental electron-phonon Hamiltonian, thus avoiding a priori assumptions about excited-state properties. We derive a nonperturbative compact solution that can be looked upon as the semiconductor version of the textbook absorption formula for a two-level system coupled to phonons. Accompanied by an illustrative numerical example, the importance and usefulness of our approach with respect to practical applications for semiconductors is demonstrated.
Bloch oscillations in the presence of plasmons and phonons
Ghosh; Jonsson; Wilkins
2000-07-31
The coupling between Bloch oscillating electrons and longitudinal optical phonons in a superlattice leads to resonant phonon excitation but no gap in the Bloch-phonon spectrum. In addition, we predict a sharp transition from plasma to Bloch oscillations at nu(B) = 2nu(P). From a microscopic description with phenomenological dampings, we numerically map out the behavior of coupled Bloch-plasmon-phonon modes for a wide range of parameters, and mimic experimental conditions. Our results are in good agreement with recent experiments by Dekorsy et al. [Phys. Rev. Lett. 85, 1080 (2000)].
Stimulated emission of phonons in an acoustic cavity
NASA Astrophysics Data System (ADS)
Tilstra, Lieuwe Gijsbert
2001-10-01
This thesis will present experiments on stimulated emission of phonons in dilute ruby following complete population inversion of the Zeeman-split E(2E) Kramers doublet by selective pulsed optical pumping into its upper component. The resulting phonon avalanches are detected by use of the R1 luminescence emanating from the inverted zone, located near the end face where the laser beam enters the crystal. The phonons appear to team up into a highly directional phonon beam. The phonon frequency is tunable from, say, 10-100 GHz via the magnetic field splitting of the doublet. Remarkably, the population of the lower doublet component, which is a measure of the number of phonons generated, evolves with a sequence of distinct steps. The time interval in between these steps equals 2L/v, corresponding to the time the phonons need to return to the inverted zone by reflection at the opposite end face at a distance L. The end faces of the ruby crystal thus form an acoustic cavity. The phonon beam passes the inverted zone repeatedly to be amplified further, in a manner similar to light in an optical laser. In other words, the basic ingredients for a phonon laser have been established.
A new hybrid phononic crystal in low frequencies
NASA Astrophysics Data System (ADS)
Zhang, Z.; Han, X. K.
2016-11-01
A novel hybrid phononic crystal is designed to obtain wider band gaps in low frequency range. The hybrid phononic crystal consists of rubber slab with periodic holes and plumbum stubs. In comparison with the phononic crystal without periodic holes, the new designed phononic crystal can obtain wider band gaps and better vibration damping characteristics. The wider band gap can be attributed to the interaction of local resonance and Bragg scattering. The controlling of the BG is explained by the strain energy of the hybrid PC and the introduced effective mass. The effects of the geometrical parameters and the shapes of the stubs and holes on the controlling of waves are further studied.
Phononic glass: a robust acoustic-absorption material.
Jiang, Heng; Wang, Yuren
2012-08-01
In order to achieve strong wide band acoustic absorption under high hydrostatic pressure, an interpenetrating network structure is introduced into the locally resonant phononic crystal to fabricate a type of phononic composite material called "phononic glass." Underwater acoustic absorption coefficient measurements show that the material owns high underwater sound absorption coefficients over 0.9 in 12-30 kHz. Moreover, the quasi-static compressive behavior shows that the phononic glass has a compressive strength over 5 MPa which is crucial for underwater applications.
Focusing of ultrasonic waves by negative refraction in phononic crystals
NASA Astrophysics Data System (ADS)
Page, J. H.
2016-12-01
Negative refraction and focusing phenomena in phononic crystals is reviewed, starting with their initial discovery over 10 years ago in flat three-dimensional (3D) phononic crystals. This work soon led to direct observations of negative refraction in 2D phononic crystals, and an extensive series of experiments, simulations and theoretical predictions to explore and optimize focusing by flat phononic crystal lenses. More recently, the emphasis has been on demonstrating how super-resolution focusing that beats the diffraction limit can be achieved. Ultrasonic experiments, in combination with theory and simulations, have played an important role in developing a detailed understanding of these phenomena.
Souvatzis, P; Björkman, T; Eriksson, O; Andersson, P; Katsnelson, M I; Rudin, S P
2009-04-29
A recently developed self-consistent ab initio lattice dynamical method has been applied to the high temperature body centered cubic (bcc) phase of La and Th, which are dynamically unstable at low temperatures. The bcc phase of these metals is found to be stabilized by phonon-phonon interactions. The calculated high temperature phonon frequencies for La are found to be in good agreement with the corresponding experimental data.
Coherent phonon optics in a chip with an electrically controlled active device.
Poyser, Caroline L; Akimov, Andrey V; Campion, Richard P; Kent, Anthony J
2015-02-05
Phonon optics concerns operations with high-frequency acoustic waves in solid media in a similar way to how traditional optics operates with the light beams (i.e. photons). Phonon optics experiments with coherent terahertz and sub-terahertz phonons promise a revolution in various technical applications related to high-frequency acoustics, imaging, and heat transport. Previously, phonon optics used passive methods for manipulations with propagating phonon beams that did not enable their external control. Here we fabricate a phononic chip, which includes a generator of coherent monochromatic phonons with frequency 378 GHz, a sensitive coherent phonon detector, and an active layer: a doped semiconductor superlattice, with electrical contacts, inserted into the phonon propagation path. In the experiments, we demonstrate the modulation of the coherent phonon flux by an external electrical bias applied to the active layer. Phonon optics using external control broadens the spectrum of prospective applications of phononics on the nanometer scale.
Coherent phonon optics in a chip with an electrically controlled active device
Poyser, Caroline L.; Akimov, Andrey V.; Campion, Richard P.; Kent, Anthony J.
2015-01-01
Phonon optics concerns operations with high-frequency acoustic waves in solid media in a similar way to how traditional optics operates with the light beams (i.e. photons). Phonon optics experiments with coherent terahertz and sub-terahertz phonons promise a revolution in various technical applications related to high-frequency acoustics, imaging, and heat transport. Previously, phonon optics used passive methods for manipulations with propagating phonon beams that did not enable their external control. Here we fabricate a phononic chip, which includes a generator of coherent monochromatic phonons with frequency 378 GHz, a sensitive coherent phonon detector, and an active layer: a doped semiconductor superlattice, with electrical contacts, inserted into the phonon propagation path. In the experiments, we demonstrate the modulation of the coherent phonon flux by an external electrical bias applied to the active layer. Phonon optics using external control broadens the spectrum of prospective applications of phononics on the nanometer scale. PMID:25652241
Quantifying electron-phonon coupling in CdTe1-xSex nanocrystals via coherent phonon manipulation
NASA Astrophysics Data System (ADS)
Spann, B. T.; Xu, X.
2014-08-01
We employ ultrafast transient absorption spectroscopy with temporal pulse shaping to manipulate coherent phonon excitation and quantify the strength of electron-phonon coupling in CdTe1-xSex nanocrystals (NCs). Raman active CdSe and CdTe longitudinal optical phonon (LO) modes are excited and probed in the time domain. By temporally controlling pump pulse pairs to coherently excite and cancel coherent phonons in the CdTe1-xSex NCs, we estimate the relative amount of optical energy that is coupled to the coherent CdSe LO mode.
NASA Astrophysics Data System (ADS)
Iyer, Srikanth S.; Candler, Robert N.
2016-03-01
In this work, we determine the intrinsic mechanical energy dissipation limit for single-crystal resonators due to anharmonic phonon-phonon scattering in the Akhiezer (Ω τ ≪1 ) regime. The energy loss is derived using perturbation theory and the linearized Boltzmann transport equation for phonons, and includes the direction- and polarization-dependent mode-Grüneisen parameters in order to capture the strain-induced anharmonicity among phonon branches. This expression reveals the fundamental differences among the internal friction limits for different types of bulk-mode elastic waves. For cubic crystals, 2D-extensional modes have increased dissipation compared to width-extensional modes because the biaxial deformation opposes the natural Poisson contraction of the solid. Additionally, we show that shear-mode vibrations, which preserve volume, have significantly reduced energy loss because dissipative phonon-phonon scattering is restricted to pure-shear phonon branches, indicating that Lamé- or wineglass-mode resonators will have the highest upper limit on mechanical efficiency. Finally, we employ key simplifications to evaluate the quality factor limits for common mode shapes in single-crystal silicon devices, explicitly including the correct effective elastic storage moduli for different vibration modes and crystal orientations. Our expression satisfies the pressing need for a reliable analytical model that can predict the phonon-phonon dissipation limits for modern resonant microelectromechanical systems, where precise manufacturing techniques and accurate finite-element methods can be used to select particular vibrational mode shapes and crystal orientations.
Measurement and control of electron-phonon interactions in graphene
NASA Astrophysics Data System (ADS)
Remi, Sebastian
Despite the weak interaction between electrons and atomic vibrations (phonons) in the one-atom thick crystal of carbon called graphene, the scattering of electrons off phonons limits coherent electron transport in pristine devices over mesoscopic length scales. The future of graphene as a replacement to silicon and other materials in advanced electronic devices will depend on the success of controlling and optimizing electronic transport. In this dissertation, we explore the electron-phonon interaction via Raman scattering, elucidating the effects of filling and emptying charge states on the phonons in both the metallic state and when levels are quantized by an applied perpendicular magnetic field. In zero magnetic field, the phonon energy shifts due to electronic screening by charge carriers. Previously, a logarithmic divergence of the phonon energy was predicted as a function of the charge carrier density. For the first time, we observe signatures of this logarithmic divergence at liquid He temperatures after vacuum annealing on single layers. We also measure the electron-phonon coupling strength, Fermi velocity, and broadening of electronic quantum levels from Raman scattering and correlate these parameters to electronic transport. In a strong perpendicular magnetic field, the energy bands split into discrete Landau levels. Here, we observe kinks and splitting of the optical phonon energy, even when the Landau level transitions are far from resonant with the phonons. We discover that the kinks are attributed to charge filling of Landau levels, as understood from a linearized model based on electron-phonon interactions. Moreover, we show that material parameters determined without magnetic fields also describe phonon behavior in high magnetic fields.
Phonon hydrodynamics and its applications in nanoscale heat transport
NASA Astrophysics Data System (ADS)
Guo, Yangyu; Wang, Moran
2015-09-01
Phonon hydrodynamics is an effective macroscopic method to study heat transport in dielectric solid and semiconductor. It has a clear and intuitive physical picture, transforming the abstract and ambiguous heat transport process into a concrete and evident process of phonon gas flow. Furthermore, with the aid of the abundant models and methods developed in classical hydrodynamics, phonon hydrodynamics becomes much easier to implement in comparison to the current popular approaches based on the first-principle method and kinetic theories involving complicated computations. Therefore, it is a promising tool for studying micro- and nanoscale heat transport in rapidly developing micro and nano science and technology. However, there still lacks a comprehensive account of the theoretical foundations, development and implementation of this approach. This work represents such an attempt in providing a full landscape, from physical fundamental and kinetic theory of phonons to phonon hydrodynamics in view of descriptions of phonon systems at microscopic, mesoscopic and macroscopic levels. Thus a systematical kinetic framework, summing up so far scattered theoretical models and methods in phonon hydrodynamics as individual cases, is established through a frame of a Chapman-Enskog solution to phonon Boltzmann equation. Then the basic tenets and procedures in implementing phonon hydrodynamics in nanoscale heat transport are presented through a review of its recent wide applications in modeling thermal transport properties of nanostructures. Finally, we discuss some pending questions and perspectives highlighted by a novel concept of generalized phonon hydrodynamics and possible applications in micro/nano phononics, which will shed more light on more profound understanding and credible applications of this new approach in micro- and nanoscale heat transport science.
Temperature dependent phonon properties of thermoelectric materials
NASA Astrophysics Data System (ADS)
Hellman, Olle; Broido, David; Fultz, Brent
2015-03-01
We present recent developments using the temperature dependent effective potential technique (TDEP) to model thermoelectric materials. We use ab initio molecular dynamics to generate an effective Hamiltonian that reproduce neutron scattering spectra, thermal conductivity, phonon self energies, and heat capacities. Results are presented for (among others) SnSe, Bi2Te3, and Cu2Se proving the necessity of careful modelling of finite temperature properties for strongly anharmonic materials. Supported by the Swedish Research Council (VR) Project Number 637-2013-7296.
Large scale phononic metamaterials for seismic isolation
Aravantinos-Zafiris, N.; Sigalas, M. M.
2015-08-14
In this work, we numerically examine structures that could be characterized as large scale phononic metamaterials. These novel structures could have band gaps in the frequency spectrum of seismic waves when their dimensions are chosen appropriately, thus raising the belief that they could be serious candidates for seismic isolation structures. Different and easy to fabricate structures were examined made from construction materials such as concrete and steel. The well-known finite difference time domain method is used in our calculations in order to calculate the band structures of the proposed metamaterials.
Shear surface waves in phononic crystals.
Kutsenko, A A; Shuvalov, A L
2013-02-01
The existence of shear horizontal (SH) surface waves in two-dimensional periodic phononic crystals with an asymmetric depth-dependent profile is theoretically reported. Examples of dispersion spectra with bandgaps for subsonic and supersonic SH surface waves are demonstrated. The link between the effective (quasistatic) speeds of the SH bulk and surface waves is established. Calculation and analysis is based on the integral form of a projector on the subspace of evanescent modes which means no need for their explicit finding. This method can be extended to the vector waves and the three-dimensional case.
Band gaps in bubble phononic crystals
NASA Astrophysics Data System (ADS)
Leroy, V.; Bretagne, A.; Lanoy, M.; Tourin, A.
2016-12-01
We investigate the interaction between Bragg and hybridization effects on the band gap properties of bubble phononic crystals. These latter consist of air cavities periodically arranged in an elastomer matrix and are fabricated using soft-lithography techniques. Their transmission properties are affected by Bragg effects due to the periodicity of the structure as well as hybridization between the propagating mode of the embedding medium and bubble resonance. The hybridization gap survives disorder while the Bragg gap requires a periodic distribution of bubbles. The distance between two bubble layers can be tuned to make the two gaps overlap or to create a transmission peak in the hybridization gap.
Phonons at the Fe(110) surface.
Slezak, T; Łazewski, J; Stankov, S; Parlinski, K; Reitinger, R; Rennhofer, M; Rüffer, R; Sepiol, B; Slezak, M; Spiridis, N; Zajac, M; Chumakov, A I; Korecki, J
2007-08-10
The in-plane density of phonon states of clean Fe(110) surface was measured separately for the first, second, and further atomic monolayers using nuclear inelastic scattering of synchrotron radiation. The results show that atoms of the first layer vibrate with frequencies significantly lower and amplitudes much larger than those in the bulk, and that vibrational spectra along two perpendicular in-surface directions are different. The vibrations of the second layer are already very close to those of the bulk. The good agreement of the experimental results and the first-principles calculations allows for detailed understanding of the observed phenomena.
Phonon scattering in graphene over substrate steps
Sevinçli, H.; Brandbyge, M.
2014-10-13
We calculate the effect on phonon transport of substrate-induced bends in graphene. We consider bending induced by an abrupt kink in the substrate, and provide results for different step-heights and substrate interaction strengths. We find that individual substrate steps reduce thermal conductance in the range between 5% and 47%. We also consider the transmission across linear kinks formed by adsorption of atomic hydrogen at the bends and find that individual kinks suppress thermal conduction substantially, especially at high temperatures. Our analysis show that substrate irregularities can be detrimental for thermal conduction even for small step heights.
Temperature dependence of coherent phonons in TbVO4 crystal probed by ultrafast optical spectroscopy
NASA Astrophysics Data System (ADS)
Jin, Z.; Ma, H.; Li, D.; Wang, L.; Ma, G.; Guo, F.; Chen, J.
2011-07-01
Coherent optical phonons in terbium vanadate (TbVO4) are investigated by using femtosecond time-resolved pump-probe spectroscopy at temperatures from 20 to 300 K. Combined with the Raman spectrum, the coherent phonon mode is attributed to an optical phonon mode of B1g symmetry. The main generation mechanism of the coherent optical phonons is revealed to be the impulsive stimulated Raman scattering. The temperature dependence of the dephasing time reveals that the main mechanism of the coherent phonon population decay is anharmonic phonon-phonon coupling, which causes a redshift of the coherent phonon frequency with increasing temperature.
NASA Astrophysics Data System (ADS)
Bilal, Osama R.
Transmission of everyday sound and heat can be traced back to a physical particle, or wave, called a "phonon". Understanding, analyzing and manipulating phonons across multiple scales/disciplines can be achieved using phononic materials. That is a class of material systems featuring a basic pattern that repeats spatially. Among many qualities, it exhibits distinct frequency characteristics such as band gaps, where vibrational waves of certain frequencies are prohibited from propagation. These properties can benefit a multitude of applications, ranging from vibration isolation and converting waste heat into electricity to exotic concepts like acoustic cloaking. Using unit-cell design and optimization, phononic materials/devices with extraordinary properties may be realized. Since many of these applications are based on band-gap utilization, a critical design objective is to widen band-gap size or precisely synthesize its characteristics. Approaching this problem at the unit cell level is advantageous in many aspects, mostly because it provides a complete picture of the intrinsic local dynamics which is often obscured when analyzing the structure as a whole. Moreover, it is computationally less expensive than designing an entire structure. Unit-cell dispersion engineering is also scale independent; an optimized unit cell may be used to manipulate waves ranging from a few Hz to GHz, or higher, with proper scaling. In order to keep the structure/device size as small as possible, the band-gap central frequency is tuned to be as low as possible. The objective of this thesis is to explore and advance unit-cell design and optimization of phononic materials in one, two and three-dimensions for a broad range of applications. In particular, an application for flow control is investigated where a phononic material is shown to manipulate and alter a flow field in a favorable manner. Results involving unit-cell design and coupled fluid-structure simulations (as part of a
Nonperturbative Quantum Nature of the Dislocation–Phonon Interaction
Li, Mingda; Ding, Zhiwei; Meng, Qingping; ...
2017-01-31
Despite the long history of dislocation–phonon interaction studies, there are many problems that have not been fully resolved during this development. These include an incompatibility between a perturbative approach and the long-range nature of a dislocation, the relation between static and dynamic scattering, and their capability of dealing with thermal transport phenomena for bulk material only. Here in this paper, by utilizing a fully quantized dislocation field, which we called a “dislon”, a phonon interacting with a dislocation is renormalized as a quasi-phonon, with shifted quasi-phonon energy, and accompanied by a finite quasi-phonon lifetime, which are reducible to classical results.more » A series of outstanding legacy issues including those above can be directly explained within this unified phonon renormalization approach. For instance, a renormalized phonon naturally resolves the decade-long debate between dynamic and static dislocation–phonon scattering approaches, as two limiting cases. In particular, at nanoscale, both the dynamic and static approaches break down, while the present renormalization approach remains valid by capturing the size effect, showing good agreement with lattice dynamics simulations.« less
Phonon localization transition in relaxor ferroelectric PZN-5%PT
Manley, Michael E.; Christianson, Andrew D.; Abernathy, Douglas L.; ...
2017-03-27
Relaxor ferroelectric behavior occurs in many disordered ferroelectric materials but is not well understood at the atomic level. Recent experiments and theoretical arguments indicate that Anderson localization of phonons instigates relaxor behavior by driving the formation of polar nanoregions (PNRs). Here, we use inelastic neutron scattering to observe phonon localization in relaxor ferroelectric PZN-5%PT (0.95[Pb(Zn1/3 Nb2/3)O3]–0.05PbTiO3) and detect additional features of the localization process. In the lead, up to phonon localization on cooling, the local resonant modes that drive phonon localization increase in number. The increase in resonant scattering centers is attributed to a known increase in the number ofmore » locally off centered Pb atoms on cooling. The transition to phonon localization occurs when these random scattering centers increase to a concentration where the Ioffe-Regel criterion is satisfied for localizing the phonon. Finally, we also model the effects of damped mode coupling on the observed phonons and phonon localization structure.« less
Topological Phonons and Weyl Lines in Three Dimensions
NASA Astrophysics Data System (ADS)
Stenull, Olaf; Kane, C. L.; Lubensky, T. C.
2016-08-01
Topological mechanics and phononics have recently emerged as an exciting field of study. Here we introduce and study generalizations of the three-dimensional pyrochlore lattice that have topologically protected edge states and Weyl lines in their bulk phonon spectra, which lead to zero surface modes that flip from one edge to the opposite as a function of surface wave number.
Multiple Quantum Wells for P T -Symmetric Phononic Crystals
NASA Astrophysics Data System (ADS)
Poshakinskiy, A. V.; Poddubny, A. N.; Fainstein, A.
2016-11-01
We demonstrate that the parity-time symmetry for sound is realized in laser-pumped multiple-quantum-well structures. Breaking of the parity-time symmetry for the phonons with wave vectors corresponding to the Bragg condition makes the structure a highly selective acoustic wave amplifier. Single-mode distributed feedback phonon lasing is predicted for structures with realistic parameters.
Remarkable reduction of thermal conductivity in phosphorene phononic crystal
NASA Astrophysics Data System (ADS)
Xu, Wen; Zhang, Gang
2016-05-01
Phosphorene has received much attention due to its interesting physical and chemical properties, and its potential applications such as thermoelectricity. In thermoelectric applications, low thermal conductivity is essential for achieving a high figure of merit. In this work, we propose to reduce the thermal conductivity of phosphorene by adopting the phononic crystal structure, phosphorene nanomesh. With equilibrium molecular dynamics simulations, we find that the thermal conductivity is remarkably reduced in the phononic crystal. Our analysis shows that the reduction is due to the depressed phonon group velocities induced by Brillouin zone folding, and the reduced phonon lifetimes in the phononic crystal. Interestingly, it is found that the anisotropy ratio of thermal conductivity could be tuned by the ‘non-square’ pores in the phononic crystal, as the phonon group velocities in the direction with larger projection of pores is more severely suppressed, leading to greater reduction of thermal conductivity in this direction. Our work provides deep insight into thermal transport in phononic crystals and proposes a new strategy to reduce the thermal conductivity of monolayer phosphorene.
Colloquium: Phononics: Manipulating heat flow with electronic analogs and beyond
NASA Astrophysics Data System (ADS)
Li, Nianbei; Ren, Jie; Wang, Lei; Zhang, Gang; Hänggi, Peter; Li, Baowen
2012-07-01
The form of energy termed heat that typically derives from lattice vibrations, i.e., phonons, is usually considered as waste energy and, moreover, deleterious to information processing. However, in this Colloquium, an attempt is made to rebut this common view: By use of tailored models it is demonstrated that phonons can be manipulated similarly to electrons and photons, thus enabling controlled heat transport. Moreover, it is explained that phonons can be put to beneficial use to carry and process information. In the first part ways are presented to control heat transport and to process information for physical systems which are driven by a temperature bias. In particular, a toolkit of familiar electronic analogs for use of phononics is put forward, i.e., phononic devices are described which act as thermal diodes, thermal transistors, thermal logic gates, and thermal memories. These concepts are then put to work to transport, control, and rectify heat in physically realistic nanosystems by devising practical designs of hybrid nanostructures that permit the operation of functional phononic devices; the first experimental realizations are also reported. Next, richer possibilities to manipulate heat flow by use of time-varying thermal bath temperatures or various other external fields are discussed. These give rise to many intriguing phononic nonequilibrium phenomena such as, for example, the directed shuttling of heat, geometrical phase-induced heat pumping, or the phonon Hall effect, which may all find their way into operation with electronic analogs.
Phonon thermal transport through tilt grain boundaries in strontium titanate
Zheng, Zexi; Chen, Xiang; Yang, Shengfeng; Xiong, Liming; Chen, Youping; Deng, Bowen; Chernatynskiy, Aleksandr
2014-08-21
In this work, we perform nonequilibrium molecular dynamics simulations to study phonon scattering at two tilt grain boundaries (GBs) in SrTiO{sub 3}. Mode-wise energy transmission coefficients are obtained based on phonon wave-packet dynamics simulations. The Kapitza conductance is then quantified using a lattice dynamics approach. The obtained results of the Kapitza conductance of both GBs compare well with those obtained by the direct method, except for the temperature dependence. Contrary to common belief, the results of this work show that the optical modes in SrTiO{sub 3} contribute significantly to phonon thermal transport, accounting for over 50% of the Kapitza conductance. To understand the effect of the GB structural disorder on phonon transport, we compare the local phonon density of states of the atoms in the GB region with that in the single crystalline grain region. Our results show that the excess vibrational modes introduced by the structural disorder do not have a significant effect on phonon scattering at the GBs, but the absence of certain modes in the GB region appears to be responsible for phonon reflections at GBs. This work has also demonstrated phonon mode conversion and simultaneous generation of new modes. Some of the new modes have the same frequency as the initial wave packet, while some have the same wave vector but lower frequencies.
Landau-Khalatnikov phonon damping in strongly interacting Fermi gases
NASA Astrophysics Data System (ADS)
Kurkjian, Hadrien; Castin, Yvan; Sinatra, Alice
2016-11-01
We derive the phonon damping rate due to the four-phonon Landau-Khalatnikov process in low-temperature strongly interacting Fermi gases using quantum hydrodynamics, correcting and extending the original calculation of Landau and Khalatnikov (Zh. Eksp. Teor. Fiz., 19 (1949) 637). Our predictions can be tested in state-of-the-art experiments with cold atomic gases in the collisionless regime.
Electron-interface phonon interaction in multiple quantum well structures
NASA Astrophysics Data System (ADS)
Sun, J. P.; Teng, H. B.; Haddad, G. I.; Stroscio, M. A.
1998-08-01
Intersubband relaxation rates due to electron interactions with the interface phonons are evaluated for multiple quantum well structures designed for step quantum well lasers operating at mid-infrared to submillimetre wavelengths. The interface phonon modes and electron-phonon interaction Hamiltonians for the structures are derived using the transfer matrix method, based on the macroscopic dielectric continuum model, whereas the electron wavefunctions are obtained by solving the Schrödinger equation. Fermi's golden rule is employed to calculate the electron relaxation rates between the subbands in these structures. The relaxation rates for two different structures are examined and compared with those calculated using the bulk phonon modes and the Fröhlich interaction Hamiltonian. The sum rule for the relationship between the form factors of the various localized phonon modes and the bulk phonon modes is verified. The results obtained in this work illustrate that the transfer matrix method provides a convenient way for deriving the properties of the interface phonon modes in different structures of current interest and that, for preferential electron relaxation in intersubband laser structures, the effects of the interface phonon modes are significant and should be considered for optimal design of these laser structures.
Remarkable reduction of thermal conductivity in phosphorene phononic crystal.
Xu, Wen; Zhang, Gang
2016-05-05
Phosphorene has received much attention due to its interesting physical and chemical properties, and its potential applications such as thermoelectricity. In thermoelectric applications, low thermal conductivity is essential for achieving a high figure of merit. In this work, we propose to reduce the thermal conductivity of phosphorene by adopting the phononic crystal structure, phosphorene nanomesh. With equilibrium molecular dynamics simulations, we find that the thermal conductivity is remarkably reduced in the phononic crystal. Our analysis shows that the reduction is due to the depressed phonon group velocities induced by Brillouin zone folding, and the reduced phonon lifetimes in the phononic crystal. Interestingly, it is found that the anisotropy ratio of thermal conductivity could be tuned by the 'non-square' pores in the phononic crystal, as the phonon group velocities in the direction with larger projection of pores is more severely suppressed, leading to greater reduction of thermal conductivity in this direction. Our work provides deep insight into thermal transport in phononic crystals and proposes a new strategy to reduce the thermal conductivity of monolayer phosphorene.
Low Temperature Phonon Properties of Orthorhombic REMnO3
NASA Astrophysics Data System (ADS)
Liu, Zhenxian; Gao, Peng; Chen, Haiyan; Tyson, Trevor A.
2010-03-01
We present the temperature dependent phonon spectra of orthorhombic-LuMnO3 and DyMnO3. The temperature dependent phonon spectra results are compared with the XAFS measurement results to probe for structural changes in the low temperature region which may coincide with ferroelectric behavior.
New quantum properties of phonons and their detection
NASA Technical Reports Server (NTRS)
Artoni, Maurizo; Birman, Joseph L.
1994-01-01
We present a theoretical investigation on new and interesting properties of the phonon polarization field in solids. In particular, non-classical aspects of the phonon population and an experimental scheme that would enable one to detect them will be discussed.
Enhancing phonon flow through one-dimensional interfaces by impedance matching
Polanco, Carlos A. Ghosh, Avik W.
2014-08-28
We extend concepts from microwave engineering to thermal interfaces and explore the principles of impedance matching in 1D. The extension is based on the generalization of acoustic impedance to nonlinear dispersions using the contact broadening matrix Γ(ω), extracted from the phonon self energy. For a single junction, we find that for coherent and incoherent phonons, the optimal thermal conductance occurs when the matching Γ(ω) equals the Geometric Mean of the contact broadenings. This criterion favors the transmission of both low and high frequency phonons by requiring that (1) the low frequency acoustic impedance of the junction matches that of the two contacts by minimizing the sum of interfacial resistances and (2) the cut-off frequency is near the minimum of the two contacts, thereby reducing the spillage of the states into the tunneling regime. For an ultimately scaled single atom/spring junction, the matching criterion transforms to the arithmetic mean for mass and the harmonic mean for spring constant. The matching can be further improved using a composite graded junction with an exponential varying broadening that functions like a broadband antireflection coating. There is, however, a trade off as the increased length of the interface brings in additional intrinsic sources of scattering.
Modulation of the Band Gaps of Phononic Crystals with Thermal Effects
NASA Astrophysics Data System (ADS)
Aly, Arafa H.; Mehaney, Ahmed
2015-11-01
Band gaps of elastic waves, both in-plane and shear waves, propagating through one-dimensional perfect/defect phononic crystals (PnCs) that involve thermal effects are studied in this paper. Based on the transfer matrix method and Bloch theory, the expressions of the reflection coefficients and dispersion relation are presented. Elastic waves localization is obtained by immersing a defect layer through a perfect structure. Compared with the periodic structure, we observed that defected PnCs introduced localized modes or peaks within the phononic band gaps. Hence, Numerical simulations are performed to investigate the influences of the defect layer thickness and type on the number and intensity of the localized modes. Moreover, we have observed that temperature changes have prominent effects on the localized modes and band gaps width, especially at plane wave propagation. Such effects could change thermal properties of the PnCs structure such as thermal conductivity and could control the thermal emission contributed by phonons in many engineering structures.
Lattice dynamics and electron-phonon coupling calculations using nondiagonal supercells
NASA Astrophysics Data System (ADS)
Lloyd-Williams, Jonathan; Monserrat, Bartomeu
Quantities derived from electron-phonon coupling matrix elements require a fine sampling of the vibrational Brillouin zone. Converged results are typically not obtainable using the direct method, in which a perturbation is frozen into the system and the total energy derivatives are calculated using a finite difference approach, because the size of simulation cell needed is prohibitively large. We show that it is possible to determine the response of a periodic system to a perturbation characterized by a wave vector with reduced fractional coordinates (m1 /n1 ,m2 /n2 ,m3 /n3) using a supercell containing a number of primitive cells equal to the least common multiple of n1, n2, and n3. This is accomplished by utilizing supercell matrices containing nonzero off-diagonal elements. We present the results of electron-phonon coupling calculations using the direct method to sample the vibrational Brillouin zone with grids of unprecedented size for a range of systems, including the canonical example of diamond. We also demonstrate that the use of nondiagonal supercells reduces by over an order of magnitude the computational cost of obtaining converged vibrational densities of states and phonon dispersion curves. J.L.-W. is supported by the Engineering and Physical Sciences Research Council (EPSRC). B.M. is supported by Robinson College, Cambridge, and the Cambridge Philosophical Society. This work was supported by EPSRC Grants EP/J017639/1 and EP/K013564/1.
The role of anharmonic phonons in under-barrier spin relaxation of single molecule magnets
Lunghi, Alessandro; Totti, Federico; Sessoli, Roberta; Sanvito, Stefano
2017-01-01
The use of single molecule magnets in mainstream electronics requires their magnetic moment to be stable over long times. One can achieve such a goal by designing compounds with spin-reversal barriers exceeding room temperature, namely with large uniaxial anisotropies. Such strategy, however, has been defeated by several recent experiments demonstrating under-barrier relaxation at high temperature, a behaviour today unexplained. Here we propose spin–phonon coupling to be responsible for such anomaly. With a combination of electronic structure theory and master equations we show that, in the presence of phonon dissipation, the relevant energy scale for the spin relaxation is given by the lower-lying phonon modes interacting with the local spins. These open a channel for spin reversal at energies lower than that set by the magnetic anisotropy, producing fast under-barrier spin relaxation. Our findings rationalize a significant body of experimental work and suggest a possible strategy for engineering room temperature single molecule magnets. PMID:28262663
Phonon-mediated quantum spin simulator employing a planar ionic crystal in a Penning trap
NASA Astrophysics Data System (ADS)
Wang, C.-C. Joseph; Keith, Adam C.; Freericks, J. K.
2013-01-01
We derive the normal modes for a rotating Coulomb ion crystal in a Penning trap, quantize the motional degrees of freedom, and illustrate how they can be driven by a spin-dependent optical dipole force to create a quantum spin simulator on a triangular lattice with hundreds of spins. The analysis for the axial modes (oscillations perpendicular to the two-dimensional crystal plane) follow a standard normal-mode analysis, while the remaining planar modes are more complicated to analyze because they have velocity-dependent forces in the rotating frame. After quantizing the normal modes into phonons, we illustrate some of the different spin-spin interactions that can be generated by entangling the motional degrees of freedom with the spin degrees of freedom via a spin-dependent optical dipole force. In addition to the well-known power-law dependence of the spin-spin interactions when driving the axial modes blue of the phonon band, we notice certain parameter regimes in which the level of frustration between the spins can be engineered by driving the axial or planar phonon modes at different frequencies. These systems may allow for the analog simulation of quantum spin glasses with large numbers of spins.
An Artificial Ising System with Phononic Excitations
NASA Astrophysics Data System (ADS)
Ghaffari, Hamed; Griffith, W. Ashley; Benson, Philip; Nasseri, M. H. B.; Young, R. Paul
Many intractable systems and problems can be reduced to a system of interacting spins. Here, we report mapping collective phononic excitations from different sources of crystal vibrations to spin systems. The phononic excitations in our experiments are due to micro and nano cracking (yielding crackling noises due to lattice distortion). We develop real time mapping of the multi-array senores to a network-space and then mapping the excitation- networks to spin-like systems. We show that new mapped system satisfies the quench (impulsive) characteristics of the Ising model in 2D classical spin systems. In particular, we show that our artificial Ising system transits between two ground states and approaching the critical point accompanies with a very short time frozen regime, inducing formation of domains separated by kinks. For a cubic-test under a true triaxial test (3D case), we map the system to a 6-spin ring under a transversal-driving field where using functional multiplex networks, the vector components of the spin are inferred (i.e., XY model). By visualization of spin patterns of the ring per each event, we demonstrate that ``kinks'' (as defects) proliferate when system approach from above to its critical point. We support our observations with employing recorded acoustic excitations during distortion of crystal lattices in nano-indentation tests on different crystals (silicon and graphite), triaxial loading test on rock (poly-crystal) samples and a true 3D triaxial test.
Thermoelectric amplification of phonons in graphene
NASA Astrophysics Data System (ADS)
Dompreh, K. A.; Mensah, N. G.; Mensah, S. Y.; Fosuhene, S. K.
2016-06-01
Amplification of acoustic in-plane phonons due to an external temperature gradient (∇T) in single-layer graphene (SLG) was studied theoretically. The threshold temperature gradient (∇ T ) 0 g and the threshold voltage (V T ) 0 g in SLG were evaluated. For T = 77 K , the calculated value for (∇ T ) 0 g = 746.8 K / cm and (V T ) 0 g = 6.6 mV . The calculation was done in the hypersound regime. Further, the dependence of the normalized amplification ( Γ / Γ 0 ) on the frequency ω q and ∇ T / T were evaluated numerically and presented graphically. The calculated threshold temperature gradient (V T ) 0 g for SLG was higher than that obtained for homogeneous semiconductors (n-InSb) (∇ T ) 0 hom ≈ 10 3 K / cm , superlattices (∇ T ) 0 S L ≈ 384 K / cm , and cylindrical quantum wire (∇ T ) 0 c q w ≈ 10 2 K / cm . This makes SLG a much better material for thermoelectric phonon amplification.
Phonon analog of topological nodal semimetals
NASA Astrophysics Data System (ADS)
Po, Hoi Chun; Bahri, Yasaman; Vishwanath, Ashvin
2016-05-01
Topological band structures in electronic systems like topological insulators and semimetals give rise to highly unusual physical properties. Analogous topological effects have also been discussed in bosonic systems, but the novel phenomena typically occur only when the system is excited by finite-frequency probes. A mapping recently proposed by C. L. Kane and T. C. Lubensky [Nat. Phys. 10, 39 (2014), 10.1038/nphys2835], however, establishes a closer correspondence. It relates the zero-frequency excitations of mechanical systems to topological zero modes of fermions that appear at the edges of an otherwise gapped system. Here we generalize the mapping to systems with an intrinsically gapless bulk. In particular, we construct mechanical counterparts of topological semimetals. The resulting gapless bulk modes are physically distinct from the usual acoustic Goldstone phonons and appear even in the absence of continuous translation invariance. Moreover, the zero-frequency phonon modes feature adjustable momenta and are topologically protected as long as the lattice coordination is unchanged. Such protected soft modes with tunable wave vector may be useful in designing mechanical structures with fault-tolerant properties.
Phonon anomalies in some iron telluride materials
C. C. Homes; Dai, Y. M.; Schneeloch, J.; ...
2016-03-21
In this paper, the detailed temperature dependence of the infrared-active mode in Fe1.03Te (TN ≃ 68 K) and Fe1.13Te (TN ≃ 56 K) has been examined, and the position, width, strength, and asymmetry parameter have been determined using an asymmetric Fano profile superimposed on an electronic background. In both materials the frequency of the mode increases as the temperature is reduced; however, there is also a slight asymmetry in the line shape, indicating that the mode is coupled to either spin or charge excitations. Below TN there is an anomalous decrease in frequency, and the mode shows little temperature dependence,more » at the same time becoming more symmetric, suggesting a reduction in spin- or electron-phonon coupling. The frequency of the infrared-active mode and the magnitude of the shift below TN are predicted reasonably well by first-principles calculations; however, the predicted splitting of the mode is not observed. In superconducting FeTe0.55Se0.45 (Tc ≃ 14 K) the infrared-active Eu mode displays asymmetric line shape at all temperatures, which is most pronounced between 100 – 200 K, indicating the presence of either spin- or electron-phonon coupling, which may be a necessary prerequisite for superconductivity in this class of materials.« less
Resonant and nonlocal properties of phononic metasolids
NASA Astrophysics Data System (ADS)
Torrent, Daniel; Pennec, Yan; Djafari-Rouhani, Bahram
2015-11-01
We derive a general theory of effective properties in metasolids based on phononic crystals with low frequency resonances. We demonstrate that in general these structures need to be described by means of a frequency-dependent and nonlocal anisotropic mass density, stiffness tensor and a third-rank coupling tensor, which shows that they behave like a nonlocal Willis medium. The effect of nonlocality and coupling tensor manifest themselves for some particular resonances, whereas they become negligible for other resonances. Considering the example of a two-dimensional phononic crystal, consisting of triangular arrangements of cylindrical shells in an elastic matrix, we show that its mass density tensor is strongly resonant and anisotropic presenting both positive and negative divergent values, while becoming scalar in the quasistatic limit. Moreover, it is found that the negative value of transverse component of the mass density is induced by a dipolar resonance, while that of the vertical component is induced by a monopolar one. Finally, the dispersion relation obtained by the effective parameters of the crystal is compared with the band structure, showing good agreement for the low-wave-number region, although the nonlocal effects are important given the existence of some resonant values of the wave number.
Size effects in thermal conduction by phonons
NASA Astrophysics Data System (ADS)
Allen, Philip B.
2014-08-01
Heat transport in nanoscale systems is both hard to measure microscopically, and hard to interpret. Ballistic and diffusive heat flow coexist, adding confusion. This paper looks at a very simple case: a nanoscale crystal repeated periodically. This is a popular model for simulation of bulk heat transport using classical molecular dynamics (MD), and is related to transient thermal grating experiments. Nanoscale effects are seen in perhaps their simplest form. The model is solved by an extension of standard quasiparticle gas theory of bulk solids. Both structure and heat flow are constrained by periodic boundary conditions. Diffusive transport is fully included, while ballistic transport by phonons of a long mean free path is diminished in a specific way. Heat current J (x) and temperature gradient ∇T (x') have a nonlocal relationship, via κ (x-x'), over a distance |x-x'| determined by phonon mean free paths. In MD modeling of bulk conductivity, finite computer resources limit system size. Long mean free paths, comparable to the scale of heating and cooling, cause undesired finite-size effects that have to be removed by extrapolation. The present model allows this extrapolation to be quantified. Calculations based on the Peierls-Boltzmann equation, using a generalized Debye model, show that extrapolation involves fractional powers of 1/L. It is also argued that heating and cooling should be distributed sinusoidally [ė∝cos(2πx/L)] to improve convergence of numerics.
Phonon anharmonicity of monoclinic zirconia and yttrium-stabilized zirconia
Li, Chen W.; Smith, Hillary L.; Lan, Tian; ...
2015-04-13
Inelastic neutron scattering measurements on monoclinic zirconia (ZrO2) and 8 mol% yttrium-stabilized zirconia were performed at temperatures from 300 to 1373 ωK. We reported temperature-dependent phonon densities of states (DOS) and Raman spectra obtained at elevated temperatures. First-principles lattice dynamics calculations with density functional theory gave total and partial phonon DOS curves and mode Grüneisen parameters. These mode Grüneisen parameters were used to predict the experimental temperature dependence of the phonon DOS with partial success. However, substantial anharmonicity was found at elevated temperatures, especially for phonon modes dominated by the motions of oxygen atoms. Yttrium-stabilized zirconia (YSZ) was somewhat moremore » anharmonic and had a broader phonon spectrum at low temperatures, owing in part to defects in its structure. YSZ also has a larger vibrational entropy than monoclinic zirconia.« less
Phononic Frequency Comb via Intrinsic Three-Wave Mixing
NASA Astrophysics Data System (ADS)
Ganesan, Adarsh; Do, Cuong; Seshia, Ashwin
2017-01-01
Optical frequency combs have resulted in significant advances in optical frequency metrology and found wide applications in precise physical measurements and molecular fingerprinting. A direct analogue of frequency combs in the phononic or acoustic domain has not been reported to date. In this Letter, we report the first clear experimental evidence for a phononic frequency comb. We show that the phononic frequency comb is generated through the intrinsic coupling of a driven phonon mode with an autoparametrically excited subharmonic mode. The experiments depict the comb generation process evidenced by a spectral response consisting of equally spaced discrete and phase coherent comb lines. Through systematic experiments at different drive frequencies and amplitudes, we portray the well-connected process of phononic frequency comb formation and define the attributes to control the features associated with comb formation in such a system. In addition to the demonstration of frequency comb, the interplay between the nonlinear resonances and the well-known Duffing phenomenon is also observed.
Phonon localization drives polar nanoregions in a relaxor ferroelectric.
Manley, M E; Lynn, J W; Abernathy, D L; Specht, E D; Delaire, O; Bishop, A R; Sahul, R; Budai, J D
2014-04-10
Relaxor ferroelectrics exemplify a class of functional materials where interplay between disorder and phase instability results in inhomogeneous nanoregions. Although known for about 30 years, there is no definitive explanation for polar nanoregions (PNRs). Here we show that ferroelectric phonon localization drives PNRs in relaxor ferroelectric PMN-30%PT using neutron scattering. At the frequency of a preexisting resonance mode, nanoregions of standing ferroelectric phonons develop with a coherence length equal to one wavelength and the PNR size. Anderson localization of ferroelectric phonons by resonance modes explains our observations and, with nonlinear slowing, the PNRs and relaxor properties. Phonon localization at additional resonances near the zone edges explains competing antiferroelectric distortions known to occur at the zone edges. Our results indicate the size and shape of PNRs that are not dictated by complex structural details, as commonly assumed, but by phonon resonance wave vectors. This discovery could guide the design of next generation relaxor ferroelectrics.
Phonon-assisted dark exciton preparation in a quantum dot
NASA Astrophysics Data System (ADS)
Lüker, S.; Kuhn, T.; Reiter, D. E.
2017-05-01
In semiconductor quantum dots, coupling to the environment, i.e., to phonons, plays a crucial role for optical state preparation. We analyze the phonon impact on two methods for direct optical preparation of the dark exciton, which is enabled by a tilted magnetic field: excitation with a chirped laser pulse and excitation with a detuned pulse. Our study reveals that for both methods, phonons either do not impede the proposed mechanism or they are made useful by widening the parameter range where dark state preparation is possible due to phonon-assisted dark exciton preparation. In view of the positive impact of phonons on optical preparation, the use of dark excitons in quantum dots becomes even more attractive.
Phonon anharmonicity of monoclinic zirconia and yttrium-stabilized zirconia
Li, Chen W.; Smith, Hillary L.; Lan, Tian; Niedziela, Jennifer L.; Munoz, Jorge A.; Keith, J. Brian; Mauger, L.; Abernathy, Douglas L; Fultz, B.
2015-04-13
Inelastic neutron scattering measurements on monoclinic zirconia (ZrO_{2}) and 8 mol% yttrium-stabilized zirconia were performed at temperatures from 300 to 1373 ωK. We reported temperature-dependent phonon densities of states (DOS) and Raman spectra obtained at elevated temperatures. First-principles lattice dynamics calculations with density functional theory gave total and partial phonon DOS curves and mode Grüneisen parameters. These mode Grüneisen parameters were used to predict the experimental temperature dependence of the phonon DOS with partial success. However, substantial anharmonicity was found at elevated temperatures, especially for phonon modes dominated by the motions of oxygen atoms. Yttrium-stabilized zirconia (YSZ) was somewhat more anharmonic and had a broader phonon spectrum at low temperatures, owing in part to defects in its structure. YSZ also has a larger vibrational entropy than monoclinic zirconia.
Phonon sidebands of photoluminescence in single wall carbon nanotubes
NASA Astrophysics Data System (ADS)
Yu, Guili; Liang, Qifeng; Jia, Yonglei; Dong, Jinming
2010-01-01
The multiphonon-assisted photoluminescence (PL) of the single wall carbon nanotubes (SWNTs) have been studied by solving the Schrödinger equation, showing a set of phonon sidebands, both the Stokes and anti-Stokes lines, which are induced by the longitudinal optical phonon and radial breathing mode phonon. All the calculated results are in a good agreement with the recent experimental PL spectra of the SWNTs [F. Plentz, H. B. Ribeiro, A. Jorio, M. S. Strano, and M. A. Pimenta, Phys. Rev. Lett. 95, 247401 (2005)] and J. Lefebvre and P. Finnie, Phys. Rev. Lett. 98, 167406 (2007)]. In addition, it is very interesting to find in the calculated PL several additional phonon sidebands with rather weak intensities, which are caused by the exciton's coupling with two kinds of phonons, and expected to be observed in future experiments.
Suppression of Phonon Transport in Molecular Christmas Trees.
Famili, Marjan; Grace, Iain; Sadeghi, Hatef; Lambert, Colin J
2017-05-19
Minimising the phonon thermal conductance of self-assembled molecular films, whilst preserving their electrical properties, is highly desirable, both for thermal management at the nanoscale and for the design of high-efficiency thermoelectric materials. Here we highlight a new strategy for minimising the phonon thermal conductance of Christmas-tree-like molecules composed of a long trunk, along which phonons can propagate, attached to pendant molecular branches. We demonstrate that phonon transport along the trunk is suppressed by Fano resonances associated with internal vibrational modes of the branches and that thermal conductance is suppressed most-effectively in molecules with pendant branches of different lengths. As examples, we use density functional theory to demonstrate the reduction in phonon transport in tree-like molecules formed from alkane or acene trunks with various pendant branches. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Dissipation induced by phonon elastic scattering in crystals
Li, Guolong; Ren, Zhongzhou; Zhang, Xin
2016-01-01
We demonstrate that the phonon elastic scattering leads to a dominant dissipation in crystals at low temperature. The two-level systems (TLSs) should be responsible for the elastic scattering, whereas the dissipation induced by static-point defects (SPDs) can not be neglected. One purpose of this work is to show how the energy splitting distribution of the TLS ensemble affects the dissipation. Besides, this article displays the proportion of phonon-TLS elastic scattering to total phonon dissipation. The coupling coefficient of phonon-SPD scattering and the constant P0 of the TLS distribution are important that we estimate their magnitudes in this paper. Our results is useful to understand the phonon dissipation mechanism, and give some clues to improve the performance of mechanical resonators, apply the desired defects, or reveal the atom configuration in lattice structure of disordered crystals. PMID:27669517
Mean free path dependent phonon contributions to interfacial thermal conductance
NASA Astrophysics Data System (ADS)
Tao, Yi; Liu, Chenhan; Chen, Weiyu; Cai, Shuang; Chen, Chen; Wei, Zhiyong; Bi, Kedong; Yang, Juekuan; Chen, Yunfei
2017-06-01
Interfacial thermal conductance as an accumulation function of the phonon mean free path is rigorously derived from the thermal conductivity accumulation function. Based on our theoretical model, the interfacial thermal conductance accumulation function between Si/Ge is calculated. The results show that the range of mean free paths (MFPs) for phonons contributing to the interfacial thermal conductance is far narrower than that for phonons contributing to the thermal conductivity. The interfacial thermal conductance is mainly contributed by phonons with shorter MFPs, and the size effects can be observed only for an interface constructed by nanostructures with film thicknesses smaller than the MFPs of those phonons mainly contributing to the interfacial thermal conductance. This is why most experimental measurements cannot detect size effects on interfacial thermal conductance. A molecular dynamics simulation is employed to verify our proposed model.
Shear viscosity due to phonons in superfluid neutron stars
NASA Astrophysics Data System (ADS)
Manuel, Cristina; Tolos, Laura
2011-12-01
We compute the contribution of phonons to the shear viscosity η in superfluid neutron stars, assuming neutron pairing in a S01 channel. We use a Boltzmann equation amended by a collision term that takes into account the binary collisions of phonons. We use effective field theory techniques to extract the phonon scattering rates, written as a function of the equation of state of the system. Our formulation is rather general, and can be used to extract the shear viscosity due to binary collisions of phonons for other superfluids, such as the cold Fermi gas in the unitarity limit. We find that η∝1/T5, the proportionality factor depending on the equation of state of the system. Our results indicate that the phonon contribution to η cannot be ignored and might have relevant effects in the dynamics of the different oscillation modes of the star.
Phononic Frequency Comb via Intrinsic Three-Wave Mixing.
Ganesan, Adarsh; Do, Cuong; Seshia, Ashwin
2017-01-20
Optical frequency combs have resulted in significant advances in optical frequency metrology and found wide applications in precise physical measurements and molecular fingerprinting. A direct analogue of frequency combs in the phononic or acoustic domain has not been reported to date. In this Letter, we report the first clear experimental evidence for a phononic frequency comb. We show that the phononic frequency comb is generated through the intrinsic coupling of a driven phonon mode with an autoparametrically excited subharmonic mode. The experiments depict the comb generation process evidenced by a spectral response consisting of equally spaced discrete and phase coherent comb lines. Through systematic experiments at different drive frequencies and amplitudes, we portray the well-connected process of phononic frequency comb formation and define the attributes to control the features associated with comb formation in such a system. In addition to the demonstration of frequency comb, the interplay between the nonlinear resonances and the well-known Duffing phenomenon is also observed.
Quantum noise theory for phonon transport through nanostructures
NASA Astrophysics Data System (ADS)
Wan, Li; Huang, Yunmi; Huang, Changcheng
2017-04-01
We have developed a quantum noise approach to study the phonon transport through nanostructures. The nanostructures acting as phonon channels are attached to two phonon reservoirs. And the temperature drop between the two reservoirs drives the phonon transport through the channels. We have derived a quantum Langevin equation(QLE) to describe the phonon transport with the quantum noise originated from the thermal fluctuation of the reservoirs. Within the Markov approximation, the QLE is used to get the thermal conductivity κ of the nanostructures and the finite size effect of the κ then is studied. In this study, the advantage of the quantum noise approach lays on the fact that no any local temperature needs to be defined for the nanostructures in its non-equilibrium state.
Investigation of phonon coherence and backscattering using silicon nanomeshes
NASA Astrophysics Data System (ADS)
Lee, Jaeho; Lee, Woochul; Wehmeyer, Geoff; Dhuey, Scott; Olynick, Deirdre L.; Cabrini, Stefano; Dames, Chris; Urban, Jeffrey J.; Yang, Peidong
2017-01-01
Phonons can display both wave-like and particle-like behaviour during thermal transport. While thermal transport in silicon nanomeshes has been previously interpreted by phonon wave effects due to interference with periodic structures, as well as phonon particle effects including backscattering, the dominant mechanism responsible for thermal conductivity reductions below classical predictions still remains unclear. Here we isolate the wave-related coherence effects by comparing periodic and aperiodic nanomeshes, and quantify the backscattering effect by comparing variable-pitch nanomeshes. We measure identical (within 6% uncertainty) thermal conductivities for periodic and aperiodic nanomeshes of the same average pitch, and reduced thermal conductivities for nanomeshes with smaller pitches. Ray tracing simulations support the measurement results. We conclude phonon coherence is unimportant for thermal transport in silicon nanomeshes with periodicities of 100 nm and higher and temperatures above 14 K, and phonon backscattering, as manifested in the classical size effect, is responsible for the thermal conductivity reduction.
Renormalisation of Nonequilibrium Phonons Under Strong Perturbative Influences.
NASA Astrophysics Data System (ADS)
Mehta, Sushrut Madhukar
Effects of strong perturbative influences, namely the presence of a narrow distribution of acoustic phonons, and the presence of an electron plasma, on the dynamics of nonequilibrium, near zone center, longitudinal optical phonons in GaP have been investigated in two separate experiments. The study of the effects of the interaction between the LO phonons and a heavily populated, narrow distribution of acoustic phonons lead to the observation of a new optically driven nonequilibrium phonon state. Time Resolved Coherent Antistokes Raman Scattering (TR-CARS), with picosecond resolution, was used to investigate the new mode. In order to achieve high occupation numbers in the acoustic branch, the picosecond laser pulses used were amplified up to 1.0 GW/cm^2 peak power per laser beam. An important characteristic property of the new state which differentiates it from the well known LO phonon state is the fact that rather than having the single decay rate observed under thermal equilibrium, the new state has two decay rates. Moreover, these two decay rates depend strongly on the distribution of the acoustic phonon occupation number. The coupling of the LO phonons with an electron plasma, on the other hand, was investigated by measurements of the shape of the Raman scattered line associated with the phonon-plasmon coupled mode. The plasma was generated by thermal excitation of carriers in doped samples. It was possible to study a large variety of plasma excitations by controlling the concentration of the dopant and the ambient temperature. A complete, self consistant model based on standard dielectric response theory is presented, and applied to the measurements of the phonon-plasmon coupled mode. It is possible to recover, via this model, the effective coupled mode damping rate, the plasma damping rate, and the plasma frequency as functions of ambient temperature, or the carrier concentration.
Interplay between phononic bandgaps and piezoelectric microstructures for energy harvesting
NASA Astrophysics Data System (ADS)
Gonella, Stefano; To, Albert C.; Liu, Wing Kam
2009-03-01
The paper introduces a multifunctional structural design combining superior mechanical wave filtering properties and energy harvesting capabilities. The proposed concept is based on the ability of most periodic structures to forbid elastic waves from propagating within specific frequency ranges known as phononic bandgaps. The bandgap density and the resulting filtering effect are dramatically enhanced through the introduction of a microstructure consisting of stiff inclusions which resonate at specific frequencies and produce significant strain and energy localization. Energy harvesting is achieved as a result of the conversion of the localized kinetic energy into electrical energy through the piezoelectric effect featured by the material in the microstructure. The idea is illustrated through the application to hexagonal truss-core honeycombs featuring periodically distributed stiff cantilever beams provided with piezoelectric electrodes. The multifunctional capability results from the localized oscillatory phenomena exhibited by the cantilevers for excitations falling in the neighborhood of the bending fundamental frequencies of the beams. This application is of particular interest for advanced aerospace and mechanical engineering applications where distinct capabilities are simultaneously pursued and weight containment represents a critical design constraint. The scalability of the analysis suggests the possibility to miniaturize the design to the microscale for microelectromechanical systems (MEMS) applications such as self-powered microsystems and wireless sensors.
Diffusion and Phonon-drag Thermopower in Gated Silicon Nanoribbons
NASA Astrophysics Data System (ADS)
Ryu, Hyuk Ju; Aksamija, Zlatan; Paskiewicz, Deborah; Scott, Shelley; Lagally, Max; Knezevic, Irena; Eriksson, Mark
2010-03-01
Thermoelectric devices are attracting interest for the targeted cooling of local hotspots in integrated circuits and the harvesting of waste heat to generate power. Special interest in silicon as a thermoelectric material arises from the possibility of monolithic integration, significant reduction in thermal conductivity for nanopatterned silicon wires, and the potential to use bandstructure engineering to improve the power factor. We present measurements of the thermopower in gate-tunable silicon nanoribbons. The gate voltage effectively modulates the thermopower by changing both the 2D electron density and the confinement electric field. The thermopower varies by almost a factor of four in the density range studied. We understand much of this variation and its temperature dependence by considering the roles of the carrier diffusion and phonon-drag contributions to the thermopower. The data are well fit by theoretical calculations based on the Boltzmann transport equation and self-consistent modeling of the confinement electrostatics. We discuss the optimization of the power factor and the cooling efficiency in gated silicon nanoribbons. This work is supported by AFOSR, DOE, NSF, and NDSEG.
Extremely high electron mobility in a phonon-glass semimetal.
Ishiwata, S; Shiomi, Y; Lee, J S; Bahramy, M S; Suzuki, T; Uchida, M; Arita, R; Taguchi, Y; Tokura, Y
2013-06-01
The electron mobility is one of the key parameters that characterize the charge-carrier transport properties of materials, as exemplified by the quantum Hall effect as well as high-efficiency thermoelectric and solar energy conversions. For thermoelectric applications, introduction of chemical disorder is an important strategy for reducing the phonon-mediated thermal conduction, but is usually accompanied by mobility degradation. Here, we show a multilayered semimetal β-CuAgSe overcoming such a trade-off between disorder and mobility. The polycrystalline ingot shows a giant positive magnetoresistance and Shubnikov de Haas oscillations, indicative of a high-mobility small electron pocket derived from the Ag s-electron band. Ni doping, which introduces chemical and lattice disorder, further enhances the electron mobility up to 90,000 cm(2) V(-1) s(-1) at 10 K, leading not only to a larger magnetoresistance but also a better thermoelectric figure of merit. This Ag-based layered semimetal with a glassy lattice is a new type of promising thermoelectric material suitable for chemical engineering.
Thickness-dependent coherent phonon frequency in ultrathin FeSe/SrTiO_{3} films
Yang, Shuolong; Sobota, Jonathan A.; Leuenberger, Dominik; Kemper, Alexander F.; Lee, James J.; Schmitt, Felix T.; Li, Wei; Moore, Rob G.; Kirchmann, Patrick S.; Shen, Zhi -Xun
2015-06-01
Ultrathin FeSe films grown on SrTiO_{3} substrates are a recent milestone in atomic material engineering due to their important role in understanding unconventional superconductivity in Fe-based materials. By using femtosecond time- and angle-resolved photoelectron spectroscopy, we study phonon frequencies in ultrathin FeSe/SrTiO_{3} films grown by molecular beam epitaxy. After optical excitation, we observe periodic modulations of the photoelectron spectrum as a function of pump–probe delay for 1-unit-cell, 3-unit-cell, and 60-unit-cell thick FeSe films. The frequencies of the coherent intensity oscillations increase from 5.00 ± 0.02 to 5.25 ± 0.02 THz with increasing film thickness. By comparing with previous works, we attribute this mode to the Se A_{1g} phonon. The dominant mechanism for the phonon softening in 1-unit-cell thick FeSe films is a substrate-induced lattice strain. Results demonstrate an abrupt phonon renormalization due to a lattice mismatch between the ultrathin film and the substrate.
Razdolski, Ilya; Chen, Yiguo; Giles, Alexander J; Gewinner, Sandy; Schöllkopf, Wieland; Hong, Minghui; Wolf, Martin; Giannini, Vincenzo; Caldwell, Joshua D; Maier, Stefan A; Paarmann, Alexander
2016-11-09
We report on the strong enhancement of mid-infrared second-harmonic generation (SHG) from SiC nanopillars due to the resonant excitation of localized surface phonon polaritons within the Reststrahlen band. A strong dependence of the SHG enhancement upon the optical mode distribution was observed. One such mode, the monopole, exhibits an enhancement that is beyond what is anticipated from field localization and dispersion of the linear and nonlinear SiC optical properties. Comparing the results for the identical nanostructures made of 4H and 6H SiC polytypes, we demonstrate the interplay of localized surface phonon polaritons with zone-folded weak phonon modes of the anisotropic crystal. Tuning the monopole mode in and out of the region where the zone-folded phonon is excited in 6H-SiC, we observe a further prominent increase of the already enhanced SHG output when the two modes are coupled. Envisioning this interplay as one of the showcase features of mid-infrared nonlinear nanophononics, we discuss its prospects for the effective engineering of nonlinear-optical materials with desired properties in the infrared spectral range.
YPHON: A package for calculating phonons of polar materials
NASA Astrophysics Data System (ADS)
Wang, Yi; Chen, Long-Qing; Liu, Zi-Kui
2014-11-01
In our recent works, we have developed a mixed-space approach within the framework of direct method for the first-principle calculation of phonon properties. It makes full use of the accuracy of the force constants calculated in the real space and the dipole-dipole interactions in the reciprocal space, making the accurate phonon calculation possible with the direct method for polar materials. In this paper, an efficient C++ implementation of the mixed-space approach, YPHON, is provided as open source, including demos and Linux scripts for extracting input data to YPHON from the output of VASP.5. The functions of the current package include the calculations of: (1) the phonon dispersions; (2) the phonon density of states; (3) the neutron scattering section weighted phonon density of state; (4) the phonons of the high symmetry structure using the force constants from low symmetry structure; (5) the phonon dispersions of random alloys; and (6) the analysis of the vibrational modes using the point group theory.
Phonon interference in crystalline and amorphous confined nanoscopic films
NASA Astrophysics Data System (ADS)
Liang, Zhi; Wilson, Thomas E.; Keblinski, Pawel
2017-02-01
Using molecular dynamics phonon wave packet simulations, we study phonon transmission across hexagonal (h)-BN and amorphous silica (a-SiO2) nanoscopic thin films sandwiched by two crystalline leads. Due to the phonon interference effect, the frequency-dependent phonon transmission coefficient in the case of the crystalline film (Si|h-BN|Al heterostructure) exhibits a strongly oscillatory behavior. In the case of the amorphous film (Si|a-SiO2|Al and Si|a-SiO2|Si heterostructures), in spite of structural disorder, the phonon transmission coefficient also exhibits oscillatory behavior at low frequencies (up to ˜1.2 THz), with a period of oscillation consistent with the prediction from the two-beam interference equation. Above 1.2 THz, however, the phonon interference effect is greatly weakened by the diffuse scattering of higher-frequency phonons within an a-SiO2 thin film and at the two interfaces confining the a-SiO2 thin film.
Self-consistent description of a system of interacting phonons
NASA Astrophysics Data System (ADS)
Poluektov, Yu. M.
2015-11-01
A proposal for a method of self-consistent description of phonon systems. This method generalizes the Debye model to account for phonon-phonon interaction. The idea of "self-consistent" phonons is introduced; their speed depends on the temperature and is determined by solving a non-linear equation. The Debye energy is also a function of the temperature within the framework of the proposed approach. The thermodynamics of "self-consistent" phonon gas are built. It is shown that at low temperatures the cubic law temperature dependence of specific heat acquires an additional term that is proportional to the seventh power of the temperature. This seems to explain the reason why the cubic law for specific heat is observed only at relatively low temperatures. At high temperatures, the theory predicts a linear deviation with respect to temperature from the Dulong-Petit law, which is observed experimentally. A modification to the melting criteria is considered, to account for the phonon-phonon interaction.
Phonon confinement in Ge nanocrystals in silicon oxide matrix
NASA Astrophysics Data System (ADS)
Jie, Yiaxiong; Wee, A. T. S.; Huan, C. H. A.; Shen, Z. X.; Choi, W. K.
2011-02-01
Spherical Ge nanocrystals well-dispersed in amorphous silicon oxide matrix have been synthesized with different sizes, and significant size-dependent Raman shift and broadening have been observed. The lattice constant of Ge nanocrystals well-bonded to silicon oxide matrix has been characterized nearly size-independent. With our proposed stress generation and relaxation mechanisms, stress effects in our samples have been analyzed to be insignificant with respect to phonon confinement effects. The phenomenological model introduced by [Richter, Wang, and Ley, Solid State Commun. 39, 625 (1981] with Gaussian weighting function and TO2 phonon dispersion function has been found to give a quite good description of the measured size-dependence of Raman shift and broadening. A 3-peak fitting method has been proposed to determine Ge nanocrystal size and film crystallinity. After physically quantizing quantum-confined one-dimensional elastic waves, we have deduced that each quantum-confined phonon possesses an instantaneous momentum of a given magnitude ℏk with an equal chance of being either positive or negative and momentum conservation is retained in an electron-phonon scattering process. Therefore, on the basis of the first-principle microscopic model and our experimental results, we deduced that Raman scattering in spherical nanocrystals is a concurrent two-phonon process, one phonon generation and one phonon transition.
Variable-Range Hopping through Marginally Localized Phonons
NASA Astrophysics Data System (ADS)
Banerjee, Sumilan; Altman, Ehud
2016-03-01
We investigate the effect of coupling Anderson localized particles in one dimension to a system of marginally localized phonons having a symmetry protected delocalized mode at zero frequency. This situation is naturally realized for electrons coupled to phonons in a disordered nanowire as well as for ultracold fermions coupled to phonons of a superfluid in a one-dimensional disordered trap. To determine if the coupled system can be many-body localized we analyze the phonon-mediated hopping transport for both the weak and strong coupling regimes. We show that the usual variable-range hopping mechanism involving a low-order phonon process is ineffective at low temperature due to discreteness of the bath at the required energy. Instead, the system thermalizes through a many-body process involving exchange of a diverging number n ∝-log T of phonons in the low temperature limit. This effect leads to a highly singular prefactor to Mott's well-known formula and strongly suppresses the variable range hopping rate. Finally, we comment on possible implications of this physics in higher dimensional electron-phonon coupled systems.
Variable-Range Hopping through Marginally Localized Phonons.
Banerjee, Sumilan; Altman, Ehud
2016-03-18
We investigate the effect of coupling Anderson localized particles in one dimension to a system of marginally localized phonons having a symmetry protected delocalized mode at zero frequency. This situation is naturally realized for electrons coupled to phonons in a disordered nanowire as well as for ultracold fermions coupled to phonons of a superfluid in a one-dimensional disordered trap. To determine if the coupled system can be many-body localized we analyze the phonon-mediated hopping transport for both the weak and strong coupling regimes. We show that the usual variable-range hopping mechanism involving a low-order phonon process is ineffective at low temperature due to discreteness of the bath at the required energy. Instead, the system thermalizes through a many-body process involving exchange of a diverging number n∝-logT of phonons in the low temperature limit. This effect leads to a highly singular prefactor to Mott's well-known formula and strongly suppresses the variable range hopping rate. Finally, we comment on possible implications of this physics in higher dimensional electron-phonon coupled systems.
Parity-Time Synthetic Phononic Media.
Christensen, J; Willatzen, M; Velasco, V R; Lu, M-H
2016-05-20
Classical systems containing cleverly devised combinations of loss and gain elements constitute extremely rich building units that can mimic non-Hermitian properties, which conventionally are attainable in quantum mechanics only. Parity-time (PT) symmetric media, also referred to as synthetic media, have been devised in many optical systems with the ground breaking potential to create nonreciprocal structures and one-way cloaks of invisibility. Here we demonstrate a feasible approach for the case of sound where the most important ingredients within synthetic materials, loss and gain, are achieved through electrically biased piezoelectric semiconductors. We study first how wave attenuation and amplification can be tuned, and when combined, can give rise to a phononic PT synthetic media with unidirectional suppressed reflectance, a feature directly applicable to evading sonar detection.
Phonon spectra of plutonium at high temperatures
NASA Astrophysics Data System (ADS)
Dorado, Boris; Bottin, François; Bouchet, Johann
2017-03-01
Ab initio molecular dynamics calculations are used to investigate the vibrational properties of the high-temperature δ and ɛ phases of plutonium. We combine the local-density approximation (LDA)+U for strong electron correlations and the temperature-dependent effective potential method in order to calculate the phonon spectra of the two phases, as well as their dependence on temperature. Our results show that the ɛ phase can only be stabilized when temperature and correlations are simultaneously accounted for. We are also able to quantify the degree of anharmonicity of the two phases. While the δ phase is fairly harmonic up to 1000 K, we find that the ɛ phase is strongly anharmonic, which explains why this structure dominates the phase diagram at high temperature.
The phonon theory of liquid thermodynamics.
Bolmatov, D; Brazhkin, V V; Trachenko, K
2012-01-01
Heat capacity of matter is considered to be its most important property because it holds information about system's degrees of freedom as well as the regime in which the system operates, classical or quantum. Heat capacity is well understood in gases and solids but not in the third main state of matter, liquids, and is not discussed in physics textbooks as a result. The perceived difficulty is that interactions in a liquid are both strong and system-specific, implying that the energy strongly depends on the liquid type and that, therefore, liquid energy can not be calculated in general form. Here, we develop a phonon theory of liquids where this problem is avoided. The theory covers both classical and quantum regimes. We demonstrate good agreement of calculated and experimental heat capacity of 21 liquids, including noble, metallic, molecular and hydrogen-bonded network liquids in a wide range of temperature and pressure.
The phonon theory of liquid thermodynamics
Bolmatov, D.; Brazhkin, V. V.; Trachenko, K.
2012-01-01
Heat capacity of matter is considered to be its most important property because it holds information about system's degrees of freedom as well as the regime in which the system operates, classical or quantum. Heat capacity is well understood in gases and solids but not in the third main state of matter, liquids, and is not discussed in physics textbooks as a result. The perceived difficulty is that interactions in a liquid are both strong and system-specific, implying that the energy strongly depends on the liquid type and that, therefore, liquid energy can not be calculated in general form. Here, we develop a phonon theory of liquids where this problem is avoided. The theory covers both classical and quantum regimes. We demonstrate good agreement of calculated and experimental heat capacity of 21 liquids, including noble, metallic, molecular and hydrogen-bonded network liquids in a wide range of temperature and pressure. PMID:22639729
Phonon hydrodynamics in two-dimensional materials.
Cepellotti, Andrea; Fugallo, Giorgia; Paulatto, Lorenzo; Lazzeri, Michele; Mauri, Francesco; Marzari, Nicola
2015-03-06
The conduction of heat in two dimensions displays a wealth of fascinating phenomena of key relevance to the scientific understanding and technological applications of graphene and related materials. Here, we use density-functional perturbation theory and an exact, variational solution of the Boltzmann transport equation to study fully from first-principles phonon transport and heat conductivity in graphene, boron nitride, molybdenum disulphide and the functionalized derivatives graphane and fluorographene. In all these materials, and at variance with typical three-dimensional solids, normal processes keep dominating over Umklapp scattering well-above cryogenic conditions, extending to room temperature and more. As a result, novel regimes emerge, with Poiseuille and Ziman hydrodynamics, hitherto typically confined to ultra-low temperatures, characterizing transport at ordinary conditions. Most remarkably, several of these two-dimensional materials admit wave-like heat diffusion, with second sound present at room temperature and above in graphene, boron nitride and graphane.
Phonon Overlaps in Molecular Quantum Dot Systems
NASA Astrophysics Data System (ADS)
Chang, Connie; Sethna, James
2004-03-01
We model the amplitudes and frequencies of the vibrational sidebands for the new molecular quantum dot systems. We calculate the Franck-Condon phonon overlaps in the 3N-dimensional configuration sapce. We solve the general case where the vibrational frequencies and eigenmodes change during the transition. We perform PM3 and DFT calculations for the case of the dumb bell-shaped C140 molecule. We find that the strongest amplitudes are associated with the 11 meV stretch mode, in agreement with experiment. The experimental amplitudes vary from molecule to molecule; indicating that the molecular overlaps are environment dependent. We explore overlaps in the presence of external electric fields from image charges and counter ions.
Parity-Time Synthetic Phononic Media
NASA Astrophysics Data System (ADS)
Christensen, J.; Willatzen, M.; Velasco, V. R.; Lu, M.-H.
2016-05-01
Classical systems containing cleverly devised combinations of loss and gain elements constitute extremely rich building units that can mimic non-Hermitian properties, which conventionally are attainable in quantum mechanics only. Parity-time (P T ) symmetric media, also referred to as synthetic media, have been devised in many optical systems with the ground breaking potential to create nonreciprocal structures and one-way cloaks of invisibility. Here we demonstrate a feasible approach for the case of sound where the most important ingredients within synthetic materials, loss and gain, are achieved through electrically biased piezoelectric semiconductors. We study first how wave attenuation and amplification can be tuned, and when combined, can give rise to a phononic P T synthetic media with unidirectional suppressed reflectance, a feature directly applicable to evading sonar detection.
Basic phononic diagnostic measurements in fluid columns
NASA Astrophysics Data System (ADS)
Hazony, D.; Hazony, Y.
2010-07-01
A pre-selected 21 MHz ultrasonic transducer was used to produce characteristic pulses, arbitrarily similar to the quantum-mechanical concept of a phonon, describable as having a single-frequency modulated Gaussian shape. The propagation of such pulses in water-acoustic channels was studied in conjunction with nonlinear regression analysis and an Erlangian model for size distribution of molecular aggregates. Experimental results obtained distinguish between surface and bulk phenomena and provide quantitative measures of an average molecular cluster size in water. The relevance of the Erlangian model, in studying the near front of the channel, provides a significant distinction between the behavior of pure water and Ringer's solution of water. The inherent consistency between the various results re-enforces the theoretical approach, implying new venues for future research.
Phonon hydrodynamics in two-dimensional materials
NASA Astrophysics Data System (ADS)
Cepellotti, Andrea; Fugallo, Giorgia; Paulatto, Lorenzo; Lazzeri, Michele; Mauri, Francesco; Marzari, Nicola
2015-03-01
The conduction of heat in two dimensions displays a wealth of fascinating phenomena of key relevance to the scientific understanding and technological applications of graphene and related materials. Here, we use density-functional perturbation theory and an exact, variational solution of the Boltzmann transport equation to study fully from first-principles phonon transport and heat conductivity in graphene, boron nitride, molybdenum disulphide and the functionalized derivatives graphane and fluorographene. In all these materials, and at variance with typical three-dimensional solids, normal processes keep dominating over Umklapp scattering well-above cryogenic conditions, extending to room temperature and more. As a result, novel regimes emerge, with Poiseuille and Ziman hydrodynamics, hitherto typically confined to ultra-low temperatures, characterizing transport at ordinary conditions. Most remarkably, several of these two-dimensional materials admit wave-like heat diffusion, with second sound present at room temperature and above in graphene, boron nitride and graphane.
Phonon-Mediated Nonclassical Interference in Diamond
NASA Astrophysics Data System (ADS)
England, Duncan G.; Fisher, Kent A. G.; MacLean, Jean-Philippe W.; Bustard, Philip J.; Heshami, Khabat; Resch, Kevin J.; Sussman, Benjamin J.
2016-08-01
Quantum interference of single photons is a fundamental aspect of many photonic quantum processing and communication protocols. Interference requires that the multiple pathways through an interferometer be temporally indistinguishable to within the coherence time of the photon. In this Letter, we use a diamond quantum memory to demonstrate interference between quantum pathways, initially temporally separated by many multiples of the optical coherence time. The quantum memory can be viewed as a light-matter beam splitter, mapping a THz-bandwidth single photon to a variable superposition of the output optical mode and stored phononic mode. Because the memory acts both as a beam splitter and as a buffer, the relevant coherence time for interference is not that of the photon, but rather that of the memory. We use this mechanism to demonstrate nonclassical single-photon and two-photon interference between quantum pathways initially separated by several picoseconds, even though the duration of the photons themselves is just ˜250 fs .
Phonon limited superconducting correlations in metallic nanograins
NASA Astrophysics Data System (ADS)
Croitoru, M. D.; Shanenko, A. A.; Vagov, A.; Milošević, M. V.; Axt, V. M.; Peeters, F. M.
2015-11-01
Conventional superconductivity is inevitably suppressed in ultra-small metallic grains for characteristic sizes smaller than the Anderson limit. Experiments have shown that above the Anderson limit the critical temperature may be either enhanced or reduced when decreasing the particle size, depending on the superconducting material. In addition, there is experimental evidence that whether an enhancement or a reduction is found depends on the strength of the electron-phonon interaction in the bulk. We reveal how the strength of the e-ph interaction interplays with the quantum-size effect and theoretically obtain the critical temperature of the superconducting nanograins in excellent agreement with experimental data. We demonstrate that strong e-ph scattering smears the peak structure in the electronic density-of-states of a metallic grain and enhances the electron mass, and thereby limits the highest Tc achievable by quantum confinement.
Phonon anomalies in some iron telluride materials
C. C. Homes; Dai, Y. M.; Schneeloch, J.; Zhong, R. D.; Gu, G. D.
2016-03-21
In this paper, the detailed temperature dependence of the infrared-active mode in Fe_{1.03}Te (T_{N} ≃ 68 K) and Fe_{1.13}Te (T_{N} ≃ 56 K) has been examined, and the position, width, strength, and asymmetry parameter have been determined using an asymmetric Fano profile superimposed on an electronic background. In both materials the frequency of the mode increases as the temperature is reduced; however, there is also a slight asymmetry in the line shape, indicating that the mode is coupled to either spin or charge excitations. Below T_{N} there is an anomalous decrease in frequency, and the mode shows little temperature dependence, at the same time becoming more symmetric, suggesting a reduction in spin- or electron-phonon coupling. The frequency of the infrared-active mode and the magnitude of the shift below T_{N} are predicted reasonably well by first-principles calculations; however, the predicted splitting of the mode is not observed. In superconducting FeTe_{0.55}Se_{0.45} (T_{c} ≃ 14 K) the infrared-active E_{u} mode displays asymmetric line shape at all temperatures, which is most pronounced between 100 – 200 K, indicating the presence of either spin- or electron-phonon coupling, which may be a necessary prerequisite for superconductivity in this class of materials.
NASA Astrophysics Data System (ADS)
Jin, Jae Sik
2017-03-01
Phonon dynamics in nanostructures is critically important to thermoelectric and optoelectronic devices because it determines the transport and other crucial properties. However, accurately evaluating the phonon lifetimes is extremely difficult. This study reports on the development of a new semi-empirical method to estimate the full-spectrum phonon lifetimes in thin silicon films at room temperature based on the experimental data on the phonon mean-free-path spectrum in bulk silicon and a phenomenological consideration of phonon transport in thin films. The bulk of this work describes the theory and the validation; then, we discuss the trend of the phonon lifetimes in thin silicon films when their thicknesses decrease.
Modeling and Simulation of Phonon Transport at the Nanoscale for Optimum Thermal Management
NASA Astrophysics Data System (ADS)
Mao, Rui
mixed bonding force between the Pd and C atoms results in incomplete hybridization of Pd and graphene orbital states at the junction, leading effectively to two phonon interfaces and a larger than expected thermal resistance. Comparison with available experimental data shows good agreement. The result clearly suggests the feasibility of phonon engineering for thermal property optimization at the interface. Transition-metal dichalcogenides (TMDs) MX2 (M=Mo,W; X=S,Se), one of the beyond- graphene two-dimensional semiconductor materials, have emerged as promising candidates due to their distinctive electronic and optical properties. Unlike the zero-bandgap graphene, TMDs have intrinsic bandgaps in the range of 1.1--2.2eV, allowing low off-current for field effect transistors. Thermal transport properties at the metal/MoS2 interfaces are then analyzed by using the atomistic phonon transport model. The considered structures include chemisorbed Sc(0001)/MoS2 and Ru(0001)/MoS 2, physisorbed Au(111)/MoS2, as well as Pd(111)/MoS 2 with intermediate characteristics. Calculated results illustrate a distinctive dependence of thermal transfer on the details of interfacial microstructures. More specifically, the chemisorbed case with a stronger bonding exhibits a generally smaller interfacial thermal resistance than the physisorbed. Comparison between metal/MoS2 and metal/graphene systems suggests that metal/MoS 2 is significantly more resistive. Further examination of lattice dynamics identifies the presence of multiple distinct atomic planes and bonding patterns at the interface as the key origin of the observed large thermal resistance. Finally, since the commensurate-incommensurate transitions are ubiquitous in the fabrication of the 2D material based devices, we have extended our investigation to the thermal/phonon transport across the misoriented 2D nanostructures. An analytical model that can incorporate the atomic level detail as well as being time-efficient is developed for
First-Principles Calculation of forces and phonons in solid
NASA Astrophysics Data System (ADS)
Ning, Zhenhua; Shelton, William
We have developed a multiple scattering theory approach to calculate Hellmann-Feynman forces and phonons via the calculation of the force constant and dynamical matrix. To demonstrate the accuracy and validity of our approach we compare with the ELK code, which is a full potential Linear Augmented Plane Wave (FLAPW) based method. As we will show our forces and phonon dispersion curves are in good agreement with the FLAPW code. This work lays the foundation for developing a first principles approach for calculation of phonons in substitutionally disordered materials.
Observation of Anomalous Phonons in Orthorhombic Rare-earth Manganites
P Gao; H Chen; T Tyson; Z Liu; J Bai; L Wang; Y Chio; S Cheong
2011-12-31
We observe the appearance of a phonon near the lock-in temperature in orthorhombic REMnO{sub 3} (RE denotes rare earth) (RE: Lu and Ho) and anomalous phonon hardening in orthorhombic LuMnO{sub 3}. The anomalous phonon occurs at the onset of spontaneous polarization. No such changes were found in incommensurate orthorhombic DyMnO{sub 3}. These observations directly reveal different electric polarization mechanisms in the E-type and incommensurate-type orthorhombic REMnO{sub 3}.
The anharmonic phonon decay rate in group-III nitrides
NASA Astrophysics Data System (ADS)
Srivastava, G. P.
2009-04-01
Measured lifetimes of hot phonons in group-III nitrides have been explained theoretically by considering three-phonon anharmonic interaction processes. The basic ingredients of the theory include full phonon dispersion relations obtained from the application of an adiabatic bond charge model and crystal anharmonic potential within the isotropic elastic continuum model. The role of various decay routes, such as Klemens, Ridley, Vallée-Bogani and Barman-Srivastava channels, in determining the lifetimes of the Raman active zone-centre longitudinal optical (LO) modes in BN (zincblende structure) and A1(LO) modes in AlN, GaN and InN (wurtzite structure) has been quantified.
Analog model for quantum gravity effects: phonons in random fluids.
Krein, G; Menezes, G; Svaiter, N F
2010-09-24
We describe an analog model for quantum gravity effects in condensed matter physics. The situation discussed is that of phonons propagating in a fluid with a random velocity wave equation. We consider that there are random fluctuations in the reciprocal of the bulk modulus of the system and study free phonons in the presence of Gaussian colored noise with zero mean. We show that, in this model, after performing the random averages over the noise function a free conventional scalar quantum field theory describing free phonons becomes a self-interacting model.
Phonon Dispersion in Chiral Single-Wall Carbon Nanotubes
NASA Astrophysics Data System (ADS)
Mu, Weihua; Vamivakas, Anthony Nickolas; Fang, Yan; Wang, Bolin
The method to obtain phonon dispersion of achiral single-wall carbon nanotubes (SWNTs) from 6×6 matrix proposed by Mahan and Jeon7 has been extended to chiral SWNTs. The number of calculated phonon modes of a chiral SWNT (10, 1) is much larger than that of a zigzag one (10, 0) because the number of atoms in the translational unit cell of chiral SWNT is larger than that of an achiral one even though they have relative similar radius. The possible application of our approach to other models with more phonon potential terms beyond Mahan and Jeon's model is discussed.
Vortex-phonon interaction in the Kosterlitz-Thouless theory
Kozik, Evgeny; Prokof'ev, Nikolay; Svistunov, Boris
2006-03-01
The 'canonical' variables of the Kosterlitz-Thouless theory--fields {phi}{sub 0}(r) and {phi}(r), generally believed to stand for vortices and phonons (or their XY equivalents, like spin waves, etc.) turn out to be neither vortices and phonons, nor, strictly speaking, canonical variables. The latter fact explains paradoxes of (i) absence of interaction between {phi}{sub 0} and {phi}, and (ii) nonphysical contribution of small vortex pairs to long-range phase correlations. We resolve the paradoxes by explicitly relating {phi}{sub 0} and {phi} to canonical vortex-pair and phonon variables.
Phonon Quasidiffusion in Cryogenic Dark Matter Search Large Germanium Detectors
Leman, S.W.; Cabrera, B.; McCarthy, K.A.; Pyle, M.; Resch, R.; Sadoulet, B.; Sundqvist, K.M.; Brink, P.L.; Cherry, M.; Do Couto E Silva, E.; Figueroa-Feliciano, E.; Mirabolfathi, N.; Serfass, B.; Tomada, A.; /Stanford U., Phys. Dept.
2012-06-04
We present results on quasidiffusion studies in large, 3 inch diameter, 1 inch thick [100] high purity germanium crystals, cooled to 50 mK in the vacuum of a dilution refrigerator, and exposed with 59.5 keV gamma-rays from an Am-241 calibration source. We compare data obtained in two different detector types, with different phonon sensor area coverage, with results from a Monte Carlo. The Monte Carlo includes phonon quasidiffusion and the generation of phonons created by charge carriers as they are drifted across the detector by ionization readout channels.
Quantum symmetries induced by phonons in the Hubbard model
NASA Astrophysics Data System (ADS)
Montorsi, Arianna; Rasetti, Mario
1994-03-01
We show how the addition of a phonon field to the Hubbard model deforms the superconducting su(2) part of the global symmetry Lie algebra su(2)⊗su(2)/openZ2, holding at half filling for the customary model, into a quantum [su(2)]q symmetry, holding for a filling which depends on the electron-phonon interaction strength. Such symmetry originates in the feature that in the presence of phonons the hopping amplitude turns out to depend on the coupling strength. The states generated by resorting to this q symmetry exhibit both off-diagonal long-range order and pairing.
Signatures of the Chiral Anomaly in Phonon Dynamics
NASA Astrophysics Data System (ADS)
Rinkel, P.; Lopes, P. L. S.; Garate, Ion
2017-09-01
Discovered in high-energy physics, the chiral anomaly has recently made way to materials science by virtue of Weyl semimetals (WSM). Thus far, the main efforts to probe the chiral anomaly in WSM have concentrated on electronic phenomena. Here, we show that the chiral anomaly can have a large impact in the A1 phonons of enantiomorphic WSM. In these materials, the chiral anomaly produces an unusual magnetic-field-induced resonance in the effective phonon charge, which in turn leads to anomalies in the phonon dispersion, optical reflectivity, and the Raman scattering.
Room-temperature phonon boundary scattering below the Casimir limit
Sadhu, J; Sinha, S
2011-09-26
Thermal conductivity data for rough surface silicon nanowires suggest the breakdown of the Casimir limit which assumes completely diffuse phonon boundary scattering. We show that coherent effects in phonon transport at room temperature indeed lead to such breakdown. Correlated multiple scattering of phonons off the rough surface lead to a reduced thermal conductivity that is dependent not only on the roughness amplitude but more importantly on the roughness correlation length. A correlation length less than the diameter of the wire is typically necessary for lowering the thermal conductivity below the Casimir limit. Our model explains seeming anomalies in data reported for electrolessly etched and electron beam lithography defined nanowires.
Single phase 3D phononic band gap material.
Warmuth, Franziska; Wormser, Maximilian; Körner, Carolin
2017-06-19
Phononic band gap materials are capable of prohibiting the propagation of mechanical waves in certain frequency ranges. Band gaps are produced by combining different phases with different properties within one material. In this paper, we present a novel cellular material consisting of only one phase with a phononic band gap. Different phases are modelled by lattice structure design based on eigenmode analysis. Test samples are built from a titanium alloy using selective electron beam melting. For the first time, the predicted phononic band gaps via FEM simulation are experimentally verified. In addition, it is shown how the position and extension of the band gaps can be tuned by utilizing knowledge-based design.
Spin-seebeck effect: a phonon driven spin distribution.
Jaworski, C M; Yang, J; Mack, S; Awschalom, D D; Myers, R C; Heremans, J P
2011-05-06
Here we report on measurements of the spin-Seebeck effect in GaMnAs over an extended temperature range alongside the thermal conductivity, specific heat, magnetization, and thermoelectric power. The amplitude of the spin-Seebeck effect in GaMnAs scales with the thermal conductivity of the GaAs substrate and the phonon-drag contribution to the thermoelectric power of the GaMnAs, demonstrating that phonons drive the spin redistribution. A phenomenological model involving phonon-magnon drag explains the spatial and temperature dependence of the measured spin distribution.
Acoustic-optical phonon up-conversion and hot-phonon bottleneck in lead-halide perovskites.
Yang, Jianfeng; Wen, Xiaoming; Xia, Hongze; Sheng, Rui; Ma, Qingshan; Kim, Jincheol; Tapping, Patrick; Harada, Takaaki; Kee, Tak W; Huang, Fuzhi; Cheng, Yi-Bing; Green, Martin; Ho-Baillie, Anita; Huang, Shujuan; Shrestha, Santosh; Patterson, Robert; Conibeer, Gavin
2017-01-20
The hot-phonon bottleneck effect in lead-halide perovskites (APbX3) prolongs the cooling period of hot charge carriers, an effect that could be used in the next-generation photovoltaics devices. Using ultrafast optical characterization and first-principle calculations, four kinds of lead-halide perovskites (A=FA(+)/MA(+)/Cs(+), X=I(-)/Br(-)) are compared in this study to reveal the carrier-phonon dynamics within. Here we show a stronger phonon bottleneck effect in hybrid perovskites than in their inorganic counterparts. Compared with the caesium-based system, a 10 times slower carrier-phonon relaxation rate is observed in FAPbI3. The up-conversion of low-energy phonons is proposed to be responsible for the bottleneck effect. The presence of organic cations introduces overlapping phonon branches and facilitates the up-transition of low-energy modes. The blocking of phonon propagation associated with an ultralow thermal conductivity of the material also increases the overall up-conversion efficiency. This result also suggests a new and general method for achieving long-lived hot carriers in materials.
Acoustic-optical phonon up-conversion and hot-phonon bottleneck in lead-halide perovskites
Yang, Jianfeng; Wen, Xiaoming; Xia, Hongze; Sheng, Rui; Ma, Qingshan; Kim, Jincheol; Tapping, Patrick; Harada, Takaaki; Kee, Tak W.; Huang, Fuzhi; Cheng, Yi-Bing; Green, Martin; Ho-Baillie, Anita; Huang, Shujuan; Shrestha, Santosh; Patterson, Robert; Conibeer, Gavin
2017-01-01
The hot-phonon bottleneck effect in lead-halide perovskites (APbX3) prolongs the cooling period of hot charge carriers, an effect that could be used in the next-generation photovoltaics devices. Using ultrafast optical characterization and first-principle calculations, four kinds of lead-halide perovskites (A=FA+/MA+/Cs+, X=I−/Br−) are compared in this study to reveal the carrier-phonon dynamics within. Here we show a stronger phonon bottleneck effect in hybrid perovskites than in their inorganic counterparts. Compared with the caesium-based system, a 10 times slower carrier-phonon relaxation rate is observed in FAPbI3. The up-conversion of low-energy phonons is proposed to be responsible for the bottleneck effect. The presence of organic cations introduces overlapping phonon branches and facilitates the up-transition of low-energy modes. The blocking of phonon propagation associated with an ultralow thermal conductivity of the material also increases the overall up-conversion efficiency. This result also suggests a new and general method for achieving long-lived hot carriers in materials. PMID:28106061
NASA Astrophysics Data System (ADS)
Kuleev, I. I.; Bakharev, S. M.; Kuleev, I. G.; Ustinov, V. V.
2017-01-01
Effect of anisotropy of elastic energy on the phonon propagation in single-crystal nanowires made of Fe, Cu, MgO, InSb, and GaAs materials that are used to fabricate spintronics devices in the regime of the Knudsen flow of phonon gas has been studied. A new method of analyzing the focusing of quasi-transverse modes has been suggested, which made it possible to determine the average values of the densities of phonon states in the regions of focusing and defocusing slow and fast quasi-transverse modes. The effect of phonon focusing on the anisotropy of heat conductivity and lengths of the phonon free paths has been analyzed for all acoustic modes that exist in spintronics nanostructures. It has been shown that for all the nanowires investigated the angular dependences of the free paths of fast and slow transverse modes in the {100} and {110} planes correlate with the angular dependences of the densities of phonon states for these modes. Directions of the heat flux that ensure the maximum and minimum phonon heat conductivity in the nanowires have been determined.
Acoustic-optical phonon up-conversion and hot-phonon bottleneck in lead-halide perovskites
NASA Astrophysics Data System (ADS)
Yang, Jianfeng; Wen, Xiaoming; Xia, Hongze; Sheng, Rui; Ma, Qingshan; Kim, Jincheol; Tapping, Patrick; Harada, Takaaki; Kee, Tak W.; Huang, Fuzhi; Cheng, Yi-Bing; Green, Martin; Ho-Baillie, Anita; Huang, Shujuan; Shrestha, Santosh; Patterson, Robert; Conibeer, Gavin
2017-01-01
The hot-phonon bottleneck effect in lead-halide perovskites (APbX3) prolongs the cooling period of hot charge carriers, an effect that could be used in the next-generation photovoltaics devices. Using ultrafast optical characterization and first-principle calculations, four kinds of lead-halide perovskites (A=FA+/MA+/Cs+, X=I-/Br-) are compared in this study to reveal the carrier-phonon dynamics within. Here we show a stronger phonon bottleneck effect in hybrid perovskites than in their inorganic counterparts. Compared with the caesium-based system, a 10 times slower carrier-phonon relaxation rate is observed in FAPbI3. The up-conversion of low-energy phonons is proposed to be responsible for the bottleneck effect. The presence of organic cations introduces overlapping phonon branches and facilitates the up-transition of low-energy modes. The blocking of phonon propagation associated with an ultralow thermal conductivity of the material also increases the overall up-conversion efficiency. This result also suggests a new and general method for achieving long-lived hot carriers in materials.
Origin of coherent phonons in Bi2Te3 excited by ultrafast laser pulses
NASA Astrophysics Data System (ADS)
Wang, Yaguo; Guo, Liang; Xu, Xianfan; Pierce, Jonathan; Venkatasubramanian, Rama
2013-08-01
Femtosecond laser pulses are used to excite coherent optical phonons in single crystal Bi2Te3 thin films. Oscillations from low- and high-frequency A1g phonon modes are observed. A perturbation model based on molecular dynamics reveals various possibilities of phonon generation due to complex interactions among different phonon modes. In order to elucidate the process of phonon generation, measurements on thin films with thicknesses below the optical absorption depth are carried out, showing that a gradient force is necessary to excite the observed A1g phonon modes, which provides a refined picture of displacive excitation of coherent phonon.
EMRS Spring Meeting 2014 Symposium D: Phonons and fluctuations in low dimensional structures
NASA Astrophysics Data System (ADS)
2014-11-01
The E-MRS 2014 Spring meeting, held from 26-30th May 2014 in Lille included the Symposium D entitled ''Phonons and Fluctuations in Low Dimensional Structures'', the first edition of its kind. The symposium was organised in response to the increasing interest in the study of phonons in the context of advances in condensed matter physics, electronics, experimental methods and theory and, in particular, the transfer of energy across atomic interfaces and the propagation of energy in the nm-scale. Steering heat by light or vice versa and examining nano-scale energy conversion (as in thermoelectricity and harvesting e.g. in biological systems) are two aspects that share the underlying science of energy processes across atomic interfaces and energy propagation in the nanoscale and or in confined systems. The nanometer scale defies several of the bulk relationships as confinement of electrons and phonons, locality and non-equilibrium become increasingly important. The propagation of phonons as energy carriers impacts not only heat transfer, but also the very concept and handling of temperature in non-equilibrium and highly localised conditions. Much of the needed progress depends on the materials studied and this symposium targeted the interface material aspects as well as the emerging concepts to advance in this field. The symposium had its origins in a series of meetings and seminars including: (1) the first Phonon Engineering Workshop, funded by Catalan Institute for Research and Advanced Studies (ICREA), the then MICINN, the CNRS, VTT, and several EU projects, held in Saint Feliu de Guixols (Girona, Spain) from 24th to 27th of May 2010 with 65 participants from Europe, the USA and Japan; (2) the first Phonons and Fluctuations workshop, held in Paris on 8th and 9th November 2010, supported by French, Spanish and Finnish national projects and EU projects, attended by about 50 researchers; (3) the second Phonon and Fluctuations workshop, held in Paris on 8th and 9th
Theoretical study of the phonon spectra of multiferroic BiFeO(3) nanoparticles.
Apostolova, I; Apostolov, A T; Wesselinowa, J M
2009-01-21
The phonon properties of multiferroic BiFeO(3) (BFO) nanoparticles are studied using a Green's function technique on the basis of the Heisenberg and the transverse Ising models, taking into account anharmonic spin-phonon and phonon-phonon interaction terms. The phonon spectrum is obtained for different exchange, magnetoelectric, and spin-phonon interaction constants. The influence of temperature, surface and size effects on the phonon energy and damping is discussed. The phonon energy and damping in BFO nanoparticles are greater in comparison to those in bulk BFO. The strong spin-phonon interactions lead to anomalies in the phonon spectrum around the magnetic and ferroelectric phase transitions. The influence of an applied magnetic field is studied, too. The predictions are consistent with experimental results.
Mapping gigahertz vibrations in a plasmonic-phononic crystal
NASA Astrophysics Data System (ADS)
Kelf, Timothy A.; Hoshii, Wataru; Otsuka, Paul H.; Sakuma, Hirotaka; Veres, Istvan A.; Cole, Robin M.; Mahajan, Sumeet; Baumberg, Jeremy J.; Tomoda, Motonobu; Matsuda, Osamu; Wright, Oliver B.
2013-02-01
We image the gigahertz vibrational modes of a plasmonic-phononic crystal at sub-micron resolution by means of an ultrafast optical technique, using a triangular array of spherical gold nanovoids as a sample. Light is strongly coupled to the plasmonic modes, which interact with the gigahertz phonons by a process akin to surface-enhanced stimulated Brillouin scattering. A marked enhancement in the observed optical reflectivity change at the centre of a void on phononic resonance is likely to be caused by this mechanism. By comparison with numerical simulations of the vibrational field, we identify resonant breathing deformations of the voids and elucidate the corresponding mode shapes. We thus establish scanned optomechanical probing of periodic plasmonic-phononic structures as a new means of investigating their coupled excitations on the nanoscale.
Plasmon–phonon coupling in monolayer WS{sub 2}
Zhao, Weiwei; Li, Mei; Zhang, Yan; Bi, Kedong; Chen, Yunfei E-mail: zhni@seu.edu.cn; Wu, Qisheng; Hao, Qi; Wang, Jinlan; Ni, Zhenhua E-mail: zhni@seu.edu.cn
2016-03-28
The excitation of plasmon in metallic nanostructures produces intense and strongly localized near fields that enhance light-matter interaction. Here, we report plasmon–phonon coupling in monolayer WS{sub 2} deposited with gold and silver nanoparticles. The Raman spectra reveal phonon modes arising from the coupling between plasmon and WS{sub 2}. The localized surface plasmon resonance mediated excitation activates the Raman process without requiring defect for momentum conservation. Our results also reveal that the momentum induced by localized surface plasmon resonances losses to WS{sub 2} and the metal atoms adsorption modulated spin–orbit split are the two essential elements for the observed plasmon–phonon coupling. This work will open up exciting prospects for plasmon–phonon coupling in two dimensional systems.
Strain-phonon coupling in (111)-oriented perovskite oxides
NASA Astrophysics Data System (ADS)
Moreau, Magnus; Marthinsen, Astrid; Selbach, Sverre M.; Tybell, Thomas
2017-09-01
Strain-phonon coupling, in terms of the shift in phonon frequencies under biaxial strain, is studied by density functional theory calculations for 20 perovskite oxides strained in their (111) and (001) planes. While the strain-phonon coupling under (001) strain follows the established, intuitive trends, the response to (111) strain is more complex. Here we show that strain-phonon coupling under (111) strain can be rationalized in terms of the Goldschmidt tolerance factor and the formal cation oxidation states. The established trends for coupling between (111) strain and in-phase and out-of-phase octahedral rotational modes as well as polar modes provide guidelines for rational design of (111)-oriented perovskite thin films.
Phonon-assisted relaxation in a frustrated antiferromagnet
Ehlers, Georg
2006-01-01
A thermally activated magnetic relaxation is observed using neutron spin-echo in the pyrochlore slab (kagom{acute e} bilayer) compound SrCr{sub 9x}Ga{sub 12-9x}O{sub 19} (x=0.95) in a restricted temperature range, 4K < T < 4K, above a cross-over to a low temperature relaxation regime with a weaker temperature dependence. The activation energy of the thermally activated relaxation, of the order of 7 meV, coincides with the energy of a phonon mode observed with neutron and Raman spectroscopy, indicating a phonon-assisted regime. The experimental observation of phonon-assisted process gives additional insight to the importance of spin-phonon coupling in frustrated magnets with regard to the models mostly based on purely magnetic interactions.
The phononic crystals: An unending quest for tailoring acoustics
NASA Astrophysics Data System (ADS)
Kushwaha, Manvir S.
2016-07-01
Periodicity (in time or space) is a part and parcel of every living being: one can see, hear and feel it. Everyday examples are locomotion, respiration and heart beat. The reinforced N-dimensional periodicity over two or more crystalline solids results in the so-called phononic band gap crystals. These can have dramatic consequences on the propagation of phonons, vibrations and sound. The fundamental physics of cleverly fabricated phononic crystals can offer a systematic route to realize the Anderson localization of sound and vibrations. As to the applications, the phononic crystals are envisaged to find ways in the architecture, acoustic waveguides, designing transducers, elastic/acoustic filters, noise control, ultrasonics, medical imaging and acoustic cloaking, to mention a few. This review focuses on the brief sketch of the progress made in the field that seems to have prospered even more than was originally imagined in the early nineties.
Topological Phonon Modes in a Two-Dimensional Wigner Crystal
NASA Astrophysics Data System (ADS)
Ji, Wen-Cheng; Shi, Jun-Ren
2017-03-01
We investigate the spin-orbit coupling effect in a two-dimensional Wigner crystal. We show that sufficiently strong spin-orbit coupling and an appropriate sign of g-factor could transform the Wigner crystal to a topological phonon system. We demonstrate the existence of chiral phonon edge modes in finite size samples, as well as the robustness of the modes in the topological phase. We explore the possibility of realizing the topological phonon system in two-dimensional Wigner crystals confined in semiconductor quantum wells/heterostructure. We find that the spin-orbit coupling is too weak for driving a topological phase transition in these systems. We argue that one may look for the topological phonon system in correlated Wigner crystals with emergent effective spin-orbit coupling.
Planck distribution of phonons in a Bose-Einstein condensate.
Schley, R; Berkovitz, A; Rinott, S; Shammass, I; Blumkin, A; Steinhauer, J
2013-08-02
The Planck distribution of photons emitted by a blackbody led to the development of quantum theory. An analogous distribution of phonons should exist in a Bose-Einstein condensate. We observe this Planck distribution of thermal phonons in a 3D condensate. This observation provides an important confirmation of the basic nature of the condensate's quantized excitations. In contrast to the bunching effect, the density fluctuations are seen to increase with increasing temperature. This is due to the nonconservation of the number of phonons. In the case of rapid cooling, the phonon temperature is out of equilibrium with the surrounding thermal cloud. In this case, a Bose-Einstein condensate is not as cold as previously thought. These measurements are enabled by our in situ k-space technique.
Flexural-Phonon Scattering Induced by Electrostatic Gating in Graphene
NASA Astrophysics Data System (ADS)
Gunst, Tue; Kaasbjerg, Kristen; Brandbyge, Mads
2017-01-01
Graphene has an extremely high carrier mobility partly due to its planar mirror symmetry inhibiting scattering by the highly occupied acoustic flexural phonons. Electrostatic gating of a graphene device can break the planar mirror symmetry, yielding a coupling mechanism to the flexural phonons. We examine the effect of the gate-induced one-phonon scattering on the mobility for several gate geometries and dielectric environments using first-principles calculations based on density functional theory and the Boltzmann equation. We demonstrate that this scattering mechanism can be a mobility-limiting factor, and show how the carrier density and temperature scaling of the mobility depends on the electrostatic environment. Our findings may explain the high deformation potential for in-plane acoustic phonons extracted from experiments and, furthermore, suggest a direct relation between device symmetry and resulting mobility.
Ab initio study of electron-phonon coupling in rubrene
NASA Astrophysics Data System (ADS)
Ordejón, P.; Boskovic, D.; Panhans, M.; Ortmann, F.
2017-07-01
The use of ab initio methods for accurate simulations of electronic, phononic, and electron-phonon properties of molecular materials such as organic crystals is a challenge that is often tackled stepwise based on molecular properties calculated in gas phase and perturbatively treated parameters relevant for solid phases. In contrast, in this work we report a full first-principles description of such properties for the prototypical rubrene crystals. More specifically, we determine a Holstein-Peierls-type Hamiltonian for rubrene, including local and nonlocal electron-phonon couplings. Thereby, a recipe for circumventing the issue of numerical inaccuracies with low-frequency phonons is presented. In addition, we study the phenyl group motion with a molecular dynamics approach.
The Electron-Phonon Interaction as Studied by Photoelectron Spectroscopy
D.W. Lynch
2004-09-30
With recent advances in energy and angle resolution, the effects of electron-phonon interactions are manifest in many valence-band photoelectron spectra (PES) for states near the Fermi level in metals.
Molecular Detection and Phonon Filtering in Heat-Transfer Spectroscopy
NASA Astrophysics Data System (ADS)
Walczak, Kamil; Yerkes, Kirk
2014-03-01
We examine heat transport carried by acoustic phonons in the systems composed of nanoscale chains of masses coupled to two thermal baths of different temperatures. Thermal conductance is obtained by using linearized Landauer formula for heat flux with phonon transmission probability calculated within atomistic Green's functions (AGF) method. AGF formalism is extended onto dissipative chains of masses with harmonic coupling beyond nearest-neighbor approximation, while atomistic description of heat reservoirs is also included into computational scheme. The resonant structure of phonon transmission spectrum is analyzed with respect to reservoir-dimensionality effects, molecular damping, and mass-to-mass harmonic coupling. Analysis of transmission zeros (antiresonances) and their accompanied Fano-shape resonances are discussed as a result of interference effects between different vibrational modes. Specifically, we show that the heat-transfer-based characterization method may be used to identify individual molecules or filter out specific phonon modes from the whole frequency spectrum. This work is supported by AFOSR grant.
Dispersive Phonon Imaging in Iii-V Semiconductors.
NASA Astrophysics Data System (ADS)
Hebboul, Saad Eddine
Low-temperature transport properties of high-frequency acoustic phonons are investigated in GaAs, InSb, InP and InAs using the phonon-imaging technique. In this method, a focused laser beam provides a movable heat source on one side of a cooled crystal (<=q2 K). A single small phonon detector on the opposite face records the transmitted heat flux as a function of propagation direction. Ballistic phonons channel along directions in the crystal which are completely determined by the detailed shape of constant-energy surfaces in wavevector space. The resulting focusing patterns are characterized by sharp phonon caustics which are clearly identified from the continuous background due to scattered phonons. In the dispersive regime, where phonon wavelength is comparable to atomic spacing, the angular positions of these caustic lines are very sensitive to phonon frequency, thus providing a novel test for lattice dynamics theories. Experiments are performed with superconducting tunnel junctions and Al bolometers to probe both the high-frequency and low -frequency regimes, respectively. We find that large-k ballistic phonons give rise to distinct focusing patterns in all four types of crystals, with thicknesses varying between 0.4 and 0.8 mm. Due to isotope scattering in the bulk, tunnel-junction experiments yield well-defined caustic patterns with a dominant frequency given by the detector gap 2Delta. In InSb, where zone boundary frequencies are small (nu_ {TA} ~ 1.2 THz), the frequency dependence of the dispersive phonon focusing patterns are measured using PbTl (0.43, 0.59 THz) and PbBi (0.69, 0.73, 0.78, 0.82 THz) tunnel junction detectors. The results are interpreted with Monte Carlo calculations based on rigid, dipole, shell, and bond-charge models. Although each model yields satisfactory fits to the previously measured dispersion curves, the predicted patterns show remarkable differences in the caustic structures. This result underscores the utility of phonon imaging
Phonon Routing in Integrated Optomechanical Cavity-waveguide Systems
2015-08-20
brillouin scat- tering in photonic integrated circuits ,” Nat. Commun., vol. 6, p. 6396, 2015. [41] J. Capmany, B. Ortega, and D. Pastor, “A tutorial on...Phonon routing in integrated optomechanical cavity-waveguide systems Kejie Fang,1, 2 Matthew H. Matheny,1, 2 Xingsheng Luan,1, 2 and Oskar Painter1...together to form optomechanical circuits . Using a pair of optomechanical cavities coupled together via a phonon waveguide we demonstrate a tunable delay and
On-chip photonic-phononic emitter-receiver apparatus
Cox, Jonathan Albert; Jarecki, Jr., Robert L.; Rakich, Peter Thomas; Wang, Zheng; Shin, Heedeuk; Siddiqui, Aleem; Starbuck, Andrew Lea
2017-07-04
A radio-frequency photonic devices employs photon-phonon coupling for information transfer. The device includes a membrane in which a two-dimensionally periodic phononic crystal (PnC) structure is patterned. The device also includes at least a first optical waveguide embedded in the membrane. At least a first line-defect region interrupts the PnC structure. The first optical waveguide is embedded within the line-defect region.
Correlations of collective observables and the phonon structure of nuclei
Casten, R.F.; Zamfir, N.V. ||
1994-07-01
A ``horizontal`` view of nuclear structures is described in which various observables are correlated over broad mass ranges. This approach leads to a number of remarkable correlations, to new understanding of the evolution of structure, to a challenge to microscopic theories, and to new signatures of structure that will be especially useful with radioactive beam experiments. In particular, this and other evidence suggests a nearly universal and pervasive role of phonon and multi-phonon excitations in nuclei.
Acoustic Bloch oscillations in a two-dimensional phononic crystal
NASA Astrophysics Data System (ADS)
He, Zhaojian; Peng, Shasha; Cai, Feiyan; Ke, Manzhu; Liu, Zhengyou
2007-11-01
We report the observation of acoustic Bloch oscillations at megahertz frequency in a two-dimensional phononic crystal. By creating periodically arrayed cavities with a decreasing gradient in width along one direction in the phononic crystal, acoustic Wannier-Stark ladders are created in the frequency domain. The oscillatory motion of an incident Gaussian pulse inside the sample is demonstrated by both simulation and experiment.
Brownian motion description of heat conduction by phonons.
Naqvi, K Razi; Waldenstrøm, S
2005-08-05
A non-Markovian partial differential equation, rooted in the theory of Brownian motion, is proposed for describing heat conduction by phonons. Although a finite speed of propagation is a built-in feature of the equation, it does not give rise to an inauthentic wave front that results from the application of Cattaneo's equation. Even a simplified, analytically tractable version of the equation yields results close to those found by solving, through more elaborate means, the equation of phonon radiative transfer.
Orbitally-driven giant phonon anharmonicity in SnSe
Li, Chen W.; Hong, Jiawang; May, Andrew F.; Bansal, Dipanshu; Chi, Songxue; Hong, Tao; Ehlers, Georg; Delaire, Olivier A.
2015-10-19
We understand that elementary excitations and their couplings in condensed matter systems is critical to develop better energy-conversion devices. In thermoelectric materials, the heat-to-electricity conversion efficiency is directly improved by suppressing the propagation of phonon quasiparticles responsible for macroscopic thermal transport. The material with the current record for thermoelectric conversion efficiency, SnSe, achieves an ultra-low thermal conductivity, but the mechanism enabling this strong phonon scattering remains largely unknown. Using inelastic neutron scattering measurements and first-principles simulations, we mapped the four-dimensional phonon dispersion surfaces of SnSe, and revealed the origin of ionic-potential anharmonicity responsible for the unique properties of SnSe. We show that the giant phonon scattering arises from an unstable electronic structure, with orbital interactions leading to a ferroelectric-like lattice instability. Our results provide a microscopic picture connecting electronic structure and phonon anharmonicity in SnSe, and offers precious insights on how electron-phonon and phononphonon interactions may lead to the realization of ultra-low thermal conductivity.
Electron-phonon coupling in hybrid lead halide perovskites
NASA Astrophysics Data System (ADS)
Wright, Adam D.; Verdi, Carla; Milot, Rebecca L.; Eperon, Giles E.; Pérez-Osorio, Miguel A.; Snaith, Henry J.; Giustino, Feliciano; Johnston, Michael B.; Herz, Laura M.
2016-05-01
Phonon scattering limits charge-carrier mobilities and governs emission line broadening in hybrid metal halide perovskites. Establishing how charge carriers interact with phonons in these materials is therefore essential for the development of high-efficiency perovskite photovoltaics and low-cost lasers. Here we investigate the temperature dependence of emission line broadening in the four commonly studied formamidinium and methylammonium perovskites, HC(NH2)2PbI3, HC(NH2)2PbBr3, CH3NH3PbI3 and CH3NH3PbBr3, and discover that scattering from longitudinal optical phonons via the Fröhlich interaction is the dominant source of electron-phonon coupling near room temperature, with scattering off acoustic phonons negligible. We determine energies for the interacting longitudinal optical phonon modes to be 11.5 and 15.3 meV, and Fröhlich coupling constants of ~40 and 60 meV for the lead iodide and bromide perovskites, respectively. Our findings correlate well with first-principles calculations based on many-body perturbation theory, which underlines the suitability of an electronic band-structure picture for describing charge carriers in hybrid perovskites.
Orbitally-driven giant phonon anharmonicity in SnSe
Li, Chen W.; Hong, Jiawang; May, Andrew F.; ...
2015-10-19
We understand that elementary excitations and their couplings in condensed matter systems is critical to develop better energy-conversion devices. In thermoelectric materials, the heat-to-electricity conversion efficiency is directly improved by suppressing the propagation of phonon quasiparticles responsible for macroscopic thermal transport. The material with the current record for thermoelectric conversion efficiency, SnSe, achieves an ultra-low thermal conductivity, but the mechanism enabling this strong phonon scattering remains largely unknown. Using inelastic neutron scattering measurements and first-principles simulations, we mapped the four-dimensional phonon dispersion surfaces of SnSe, and revealed the origin of ionic-potential anharmonicity responsible for the unique properties of SnSe. Wemore » show that the giant phonon scattering arises from an unstable electronic structure, with orbital interactions leading to a ferroelectric-like lattice instability. Our results provide a microscopic picture connecting electronic structure and phonon anharmonicity in SnSe, and offers precious insights on how electron-phonon and phononphonon interactions may lead to the realization of ultra-low thermal conductivity.« less
Phonon assisted carrier motion on the Wannier-Stark ladder
NASA Astrophysics Data System (ADS)
Cheung, Alfred; Berciu, Mona
2014-03-01
It is well known that at zero temperature and in the absence of electron-phonon coupling, the presence of an electric field leads to localization of carriers residing in a single band of finite bandwidth. In this talk, we will present an implementation of the self-consistent Born approximation (SCBA) to study the effect of weak electron-phonon coupling on the motion of a carrier in a biased system. At moderate and strong electron-phonon coupling, we supplement the SCBA, describing the string of phonons left behind by the carrier, with the momentum average approximation to describe the phonon cloud that accompanies the resulting polaron. We find that coupling to the lattice delocalizes the carrier, as expected, although long-lived resonances resulting from the Wannier-Stark states of the polaron may appear in certain regions of the parameter space. We end with a discussion of how our method can be improved to model disorder, other types of electron-phonon coupling, and electron-hole pair dissociation in a biased system.
Topological phononic insulator with robust pseudospin-dependent transport
NASA Astrophysics Data System (ADS)
Xia, Bai-Zhan; Liu, Ting-Ting; Huang, Guo-Liang; Dai, Hong-Qing; Jiao, Jun-Rui; Zang, Xian-Guo; Yu, De-Jie; Zheng, Sheng-Jie; Liu, Jian
2017-09-01
Topological phononic states, which facilitate unique acoustic transport around defects and disorders, have significantly revolutionized our scientific cognition of acoustic systems. Here, by introducing a zone folding mechanism, we realize the topological phase transition in a double Dirac cone of the rotatable triangular phononic crystal with C3 v symmetry. We then investigate the distinct topological edge states on two types of interfaces of our phononic insulators. The first one is a zigzag interface which simultaneously possesses a symmetric mode and an antisymmetric mode. Hybridization of the two modes leads to a robust pseudospin-dependent one-way propagation. The second one is a linear interface with a symmetric mode or an antisymmetric mode. The type of mode is dependent on the topological phase transition of the phononic insulators. Based on the rotatability of triangular phononic crystals, we consider several complicated contours defined by the topological zigzag interfaces. Along these contours, the acoustic waves can unimpededly transmit without backscattering. Our research develops a route for the exploration of the topological phenomena in experiments and provides an excellent framework for freely steering the acoustic backscattering-immune propagation within topological phononic structures.
Phonon anharmonicity and negative thermal expansion in SnSe
Bansal, Dipanshu; Hong, Jiawang; Li, Chen W.; ...
2016-08-09
In this paper, the anharmonic phonon properties of SnSe in the Pnma phase were investigated with a combination of experiments and first-principles simulations. Using inelastic neutron scattering (INS) and nuclear resonant inelastic X-ray scattering (NRIXS), we have measured the phonon dispersions and density of states (DOS) and their temperature dependence, which revealed a strong, inhomogeneous shift and broadening of the spectrum on warming. First-principles simulations were performed to rationalize these measurements, and to explain the previously reported anisotropic thermal expansion, in particular the negative thermal expansion within the Sn-Se bilayers. Including the anisotropic strain dependence of the phonon free energy,more » in addition to the electronic ground state energy, is essential to reproduce the negative thermal expansion. From the phonon DOS obtained with INS and additional calorimetry measurements, we quantify the harmonic, dilational, and anharmonic components of the phonon entropy, heat capacity, and free energy. Finally, the origin of the anharmonic phonon thermodynamics is linked to the electronic structure.« less
Electron-phonon coupling in hybrid lead halide perovskites.
Wright, Adam D; Verdi, Carla; Milot, Rebecca L; Eperon, Giles E; Pérez-Osorio, Miguel A; Snaith, Henry J; Giustino, Feliciano; Johnston, Michael B; Herz, Laura M
2016-05-26
Phonon scattering limits charge-carrier mobilities and governs emission line broadening in hybrid metal halide perovskites. Establishing how charge carriers interact with phonons in these materials is therefore essential for the development of high-efficiency perovskite photovoltaics and low-cost lasers. Here we investigate the temperature dependence of emission line broadening in the four commonly studied formamidinium and methylammonium perovskites, HC(NH2)2PbI3, HC(NH2)2PbBr3, CH3NH3PbI3 and CH3NH3PbBr3, and discover that scattering from longitudinal optical phonons via the Fröhlich interaction is the dominant source of electron-phonon coupling near room temperature, with scattering off acoustic phonons negligible. We determine energies for the interacting longitudinal optical phonon modes to be 11.5 and 15.3 meV, and Fröhlich coupling constants of ∼40 and 60 meV for the lead iodide and bromide perovskites, respectively. Our findings correlate well with first-principles calculations based on many-body perturbation theory, which underlines the suitability of an electronic band-structure picture for describing charge carriers in hybrid perovskites.
Electron–phonon coupling in hybrid lead halide perovskites
Wright, Adam D.; Verdi, Carla; Milot, Rebecca L.; Eperon, Giles E.; Pérez-Osorio, Miguel A.; Snaith, Henry J.; Giustino, Feliciano; Johnston, Michael B.; Herz, Laura M.
2016-01-01
Phonon scattering limits charge-carrier mobilities and governs emission line broadening in hybrid metal halide perovskites. Establishing how charge carriers interact with phonons in these materials is therefore essential for the development of high-efficiency perovskite photovoltaics and low-cost lasers. Here we investigate the temperature dependence of emission line broadening in the four commonly studied formamidinium and methylammonium perovskites, HC(NH2)2PbI3, HC(NH2)2PbBr3, CH3NH3PbI3 and CH3NH3PbBr3, and discover that scattering from longitudinal optical phonons via the Fröhlich interaction is the dominant source of electron–phonon coupling near room temperature, with scattering off acoustic phonons negligible. We determine energies for the interacting longitudinal optical phonon modes to be 11.5 and 15.3 meV, and Fröhlich coupling constants of ∼40 and 60 meV for the lead iodide and bromide perovskites, respectively. Our findings correlate well with first-principles calculations based on many-body perturbation theory, which underlines the suitability of an electronic band-structure picture for describing charge carriers in hybrid perovskites. PMID:27225329