Social physique anxiety, obligation to exercise, and exercise choices among college students.

PubMed

Chu, Hui-Wen; Bushman, Barbara A; Woodard, Rebecca J

2008-01-01

The authors examined relationships among social physique anxiety, obligation to exercise, and exercise choices. College students (N = 337; 200 women, 137 men) volunteered to complete 3 questionnaires: the Social Physique Anxiety Scale (SPAS), Obligatory Exercise Questionnaire (OEQ), and Physical Activity Specification Survey (PASS). On the SPAS, men (M score = 31.9 +/- 8.8) differed from women (M score = 37.3 +/- 8.3; p = .001). Men (M score = 43.0 +/- 9.9) and women (M score = 43.0 +/- 9.6) responded similarly (p = .94) on the OEQ. There was no interaction between sex and exercise level on the SPAS or OEQ. When separated by low, medium, and high SPAS scores, neither OEQ nor exercise scores differed. Obligation to exercise appears to be similar for both sexes. Women, however, appear to have higher levels of anxiety regarding how others evaluate their physique than do men. The combination of level of activity and sex do not appear to be associated with social physique anxiety or obligation to exercise.

Examining social physique anxiety and disordered eating in college women. The roles of social comparison and body surveillance.

PubMed

Fitzsimmons-Craft, Ellen E; Harney, Megan B; Brownstone, Lisa M; Higgins, M K; Bardone-Cone, Anna M

2012-12-01

Social physique anxiety has been found to be associated with disordered eating. However, what is not yet known is what behaviors college women may engage in that strengthen this relation. In the current study, we examined two possible moderating factors, social comparison and body surveillance. We examined whether these moderators might also generalize to trait anxiety, as well. Participants were 265 women attending a Southeastern university. Social comparison (both general and appearance-related) and body surveillance were tested as moderators of the relation between social physique anxiety and disordered eating. Results indicated that general social comparison, appearance-related social comparison, and body surveillance significantly moderated this relation. Individuals who were high in social physique anxiety and who reported high levels of general or appearance-related social comparison or body surveillance reported much higher levels of disordered eating than those with high social physique anxiety and low levels of these behaviors. Results indicated that only the trait anxiety×body surveillance interaction was significant in identifying elevated disordered eating. Results provide information regarding who may experience high levels of disordered eating in association with social physique anxiety, which has clinical implications including the conceptualization of social comparison and body surveillance as safety behaviors. Copyright © 2012 Elsevier Ltd. All rights reserved.

Colloquy to Paul Musset

ScienceCinema

None

2017-12-09

En honneur de Paul Musset il a été décidé de faire plutôt un colloque scientifique à la place d'une cérémonie. Plusieurs personnes temoignent de leurs estime et amitié pour ce physicien et ses activités

Rapport sur l'état du patrimoine astronomique dans les observatoires français de la fin du XIXè siècle

NASA Astrophysics Data System (ADS)

Damm, E.; Pécontal, E.

2012-12-01

Suite au colloque sur la sauvegarde du patrimoine astronomique organisé par le MAEE et la SAF, sous l'égide de l'UNESCO, qui a conduit à l'adoption de la Déclaration de Paris, les directeurs d'observatoires institutionnels qui étaient absents du colloque ont ressenti le besoin de discuter de ces conclusions prises en leur nom. L'initiative d'organiser une réunion des directeurs des Observatoires des Sciences de l'Univers (OSU) à ce sujet le 30 janvier 2012 a été prise par François Vernotte, directeur de l'Observatoire de Besançon. Le présent compte-rendu de visite résulte d'une initiative spontanée d'Emmanuel Pécontal, astronome responsable du Patrimoine à l'observatoire de Lyon, et d'Evelyne Damm, membre de la Commission Nationale de classement des Monuments Historiques (CNMH) et élue à la communauté d'agglomération des Portes de l'Essonne oû est sis l'observatoire de Camille Flammarion.

Elemental analysis of different varieties of rice samples using XRF technique

NASA Astrophysics Data System (ADS)

Kaur, Jaspreet; Kumar, Anil

2016-05-01

Rice is most consumed staple food in the world providing over 21% of the calorie intake of world's population having high yielding capacity. Elements detected in rice are Al, As, Br, Cd, Cl, Co, Cs, Cu, Fe, Hg, K, Mg, Mn, Mo, Rb, Se and Zn by using Instrumental Neutron Activation with k0 standardization (R. Jayasekera etal,2004). Some of these trace elements are C, H, O, N, S, Ca, P, K, Na, Cl, Mn, Ti, Mg, Cu, Fe, Ni, Si and Zn are essential for growth of human physique The deficiency or excess of these elements in food is known to cause a variety of malnutrition or health disorders in the world. Every year, various varieties of rice are launched by Punjab Agriculture University, Ludhiana. The main purpose of which is to increases the yield to attain the maximum profit. But this leads to changing the elemental concentration in them, which may affect the human health according to variation in the nutrition values. The main objective is to study the presence of elemental concentration in various varieties of rice using EDXRF technique.

Exercise dependence, social physique anxiety, and social support in experienced and inexperienced bodybuilders and weightlifters

PubMed Central

Hurst, R.; Hale, B.; Smith, D.; Collins, D.

2000-01-01

Objectives—To investigate psychological correlates of exercise dependence in experienced and inexperienced bodybuilders and weightlifters. Secondary objectives included measuring social physique anxiety, bodybuilding identity, and social support among bodybuilders and weightlifters. Methods—Thirty five experienced bodybuilders, 31 inexperienced bodybuilders, and 23 weightlifters completed the bodybuilding dependence scale, a bodybuilding version of the athletic identity measurement scale, the social physique anxiety scale, and an adapted version of the social support survey-clinical form. Results—A between subjects multivariate analysis of variance was calculated on the scores of the three groups of lifters for the four questionnaires. Univariate F tests and follow up tests indicated that experienced bodybuilders scored significantly higher than inexperienced bodybuilders and weightlifters on bodybuilding dependence (p<0.001), social identity and exclusivity subscales of bodybuilding identity (p<0.001), and social support scales (p<.001), and significantly lower on social physique anxiety (p<0.001). Conclusion—Experienced bodybuilders exhibit more exercise dependence, show greater social support behaviour, and experience less social physique anxiety than inexperienced bodybuilders and weightlifters. Key Words: bodybuilding; exercise dependence; social physical anxiety; social support; athletic identity PMID:11131230

The Social Physique Anxiety Scale: construct validity in adolescent females.

PubMed

McAuley, E; Burman, G

1993-09-01

Hart, Leary, and Rejeski have developed the Social Physique Anxiety Scale (SPA), a measure of the anxiety experienced in response to having one's physique evaluated by other people. The present study cross-validated the psychometric properties of this measure in a sample (N = 236) of adolescent competitive female gymnasts. Employing structural equation modeling, the proposed unidimensional factor structure of the SPA was supported, although some questions regarding the robustness of the fit are raised. Construct validity was demonstrated by significant inverse relationships between aspects of physical efficacy (perceived physical ability and physical self-presentation confidence) and degree of social physique anxiety. These findings are discussed in terms of possible alternative factor structures and integration of social anxiety and other psychosocial constructs to better understand physical activity behavior.

Media effects of experimental presentation of the ideal physique on eating disorder symptoms: a meta-analysis of laboratory studies.

PubMed

Hausenblas, Heather A; Campbell, Anna; Menzel, Jessie E; Doughty, Jessica; Levine, Michael; Thompson, J Kevin

2013-02-01

Older meta-analyses of the effects of the media's portrayal of the ideal physique have found small effects revealing that exposure to the ideal physique increases body image concerns. These meta-analyses also included correlational, quasi-experimental, and experimental studies, with limited examination of moderators and other relevant outcomes besides body image. We conducted a systematic literature search and identified 33 experimental (i.e., pre and post data for both experimental and control groups) laboratory studies examining the effects of acute exposure to the media's portrayal of the ideal physique on eating disorder symptoms (i.e., body image, positive affect, negative affect, self-esteem, anger, anxiety and depression) and the mechanisms that moderate this effect. Fourteen separate meta-analyses revealed a range of small to moderate effect sizes for change in outcomes from pre to post for both experimental and control groups. Exposure to images of the ideal physique resulted in small effect sizes for increased depression and anger and decreased self-esteem and positive affect. Moderator analyses revealed moderate effect sizes for increased depression and body dissatisfaction among high-risk participants. This meta-analysis makes it clear that media exposure of the ideal physique results in small changes in eating disorder symptoms, particularly with participants at high risk for developing an eating disorder. Further research is needed to examine the longitudinal effects of media exposure of eating disorder symptoms. Copyright © 2012 Elsevier Ltd. All rights reserved.

Les Annales de Réadaptation et de Médecine Physique publication in 2008.

PubMed

Thevenon, A

2009-03-01

In 2008 the European Society of Physical and Rehabilitation Medicine (ESPRM) established a network of European journal and promoted collaboration among the European Physical and Rehabilitation Medicine (PRM) journals. In this connection, the authors present here the articles published in the Annales de Réadaptation et Médecine Physique in 2008. In the same time, the European Journal presents in the Annales de Réadaptation et Médecine Physique its main articles of year 2008. The papers published in the Annales de Réadaptation et Médecine Physique in 2008 were reviewed, classified by topics and discussed. Sixty-four papers are described, with a coverage of all the fields of PRM, from childhood to elderly, from basic science to clinical research, from case studies to epidemiological works. The aim of this paper was to provide physiatrists with some articles of the Annales de Réadaptation et Médecine Physique related to their working condition. Next year, the name of our journal will become Annals of Physical and Rehabilitation Medicine, as most of the articles will be published in French and in English, with the hope that more and more European authors and readers will find it more convenient.

Social Physique Anxiety and Intention to Be Physically Active: A Self-Determination Theory Approach.

PubMed

Sicilia, Álvaro; Sáenz-Alvarez, Piedad; González-Cutre, David; Ferriz, Roberto

2016-12-01

Based on self-determination theory, the purpose of this study was to analyze the relationship between social physique anxiety and intention to be physically active, while taking into account the mediating effects of the basic psychological needs and behavioral regulations in exercise. Having obtained parents' prior consent, 390 students in secondary school (218 boys, 172 girls; M age  = 15.10 years, SD = 1.94 years) completed a self-administered questionnaire during physical education class that assessed the target variables. Preliminary analyses included means, standard deviations, and bivariate correlations among the target variables. Next, a path analysis was performed using the maximum likelihood estimation method with the bootstrapping procedure in the statistical package AMOS 19. Analysis revealed that social physique anxiety negatively predicted intention to be physically active through mediation of the basic psychological needs and the 3 autonomous forms of motivation (i.e., intrinsic motivation, integrated regulation, and identified regulation). The results suggest that social physique anxiety is an internal source of controlling influence that hinders basic psychological need satisfaction and autonomous motivation in exercise, and interventions aimed at reducing social physique anxiety could promote future exercise.

The Physique of Elite Female Artistic Gymnasts: A Systematic Review.

PubMed

Bacciotti, Sarita; Baxter-Jones, Adam; Gaya, Adroaldo; Maia, José

2017-09-01

It has been suggested that successful young gymnasts are a highly select group in terms of the physique. This review summarizes the available literature on elite female gymnasts' anthropometric characteristics, somatotype, body composition and biological maturation. The main aims were to identify: (i) a common physique and (ii) the differences, if any, among competitive/performance levels. A systematic search was conducted online using five different databases. Of 407 putative papers, 17 fulfilled all criteria and were included in the review. Most studies identified similar physiques based on: physical traits (small size and low body mass), a body type (predominance of ecto-mesomorphy), body composition (low fat mass), and maturity status (late skeletal maturity as well as late age-at-menarche). However, there was no consensus as to whether these features predicted competitive performance, or even differentiated between gymnasts within distinctive competitive levels. In conclusion, gymnasts, as a group, have unique pronounced characteristics. These characteristics are likely due to selection for naturally-occurring inherited traits. However, data available for world class competitions were mostly outdated and sample sizes were small. Thus, it was difficult to make any conclusions about whether physiques differed between particular competitive levels.

Niveaux d'étude du cerveau, et sagesse physique

NASA Astrophysics Data System (ADS)

Toulouse, Gérard

1993-02-01

The brain is a complex spatio-temporal affair. Several brain theories propose the definition of three superposed levels of study. But physics, though the experience of condensed matter physics, suggests that it is unwise to enforce onto brain theories a unified hierarchical scheme, the inspiration for which seems to come from the realm of sub-molecular physics. Le cerveau est une affaire spatio-temporelle complexe. Plusieurs théories du cerveau proposent de définir trois niveaux d'études superposés. Mais la physique, à travers l'expérience de la physique de la matière condensée, suggère qu'il n'est pas sage d'imposer sur les théories du cerveau un schéma hiérarchique unifié, dont l'inspiration semble provenir du domaine de la physique sub-moléculaire.

Une vie saine et active : des directives en matière d’activité physique chez les enfants et les adolescents

PubMed Central

Lipnowski, Stan; LeBlanc, Claire MA

2012-01-01

RÉSUMÉ L’épidémie d’obésité juvénile augmente partout dans le monde. Même si les facteurs de risque d’obésité sont multifactoriels, bon nombre sont liés au mode de vie et se prêtent à une intervention. Ces facteurs incluent le comportement sédentaire et la thermogenèse sans activité physique, de même que la fréquence, l’intensité, la quantité et le type d’activité physique. Les dispensateurs de soins de première ligne sont en position idéale pour surveiller le taux d’activité physique des enfants, des adolescents et de leur famille, évaluer les choix liés au mode de vie et offrir des conseils pertinents. Le présent document de principes contient des directives visant à réduire le comportement sédentaire et à accroître le taux d’activité physique au sein de la population pédiatrique. Des recommandations d’activités physiques adaptées au développement et visant les nourrissons, les tout-petits, les enfants d’âge préscolaire, les enfants et les adolescents sont présentées. Des stratégies de promotion d’une vie saine et active sur les scènes locale, municipale, provinciale, territoriale et fédérale sont proposées.

Le langage ecrit: Actes du 6e colloque d'orthophonie/logopedie (Written Language: Proceedings of the Sixth Colloquium on Speech Therapy/Speech Pathology) (Neuchatel, Switzerland, September 21-22, 2000).

ERIC Educational Resources Information Center

de Weck, Genevieve, Ed.; Sovilla, Jocelyne Buttet, Ed.

This collection of papers discusses various theoretical, clinical, and assessment issues in reading and writing delays and disorders. Topics include the following: integrating different theoretical approaches (cognitive psychology, neuropsychology, constructivism) into clinical approaches to reading and writing difficulties; difficulties of…

Symposium on Television Violence (Colloque sur la Violence a la Television); Queen's University, Kingston, Ontario, Canada, August 24-26, 1975.

ERIC Educational Resources Information Center

Canadian Radio-Television Commission, Ottawa (Ontario).

This book presents material from a symposium on television violence that was organized by the Canadian Radio-Television Commission. Part 1, "The Public Issue," discusses the social effects of mass media and violence as a dramatic convention. Part 2, "The Social Effects of Television Violence," provides experiments, research,…

Comparing a Yoga Class with a Resistance Exercise Class: Effects on Body Satisfaction and Social Physique Anxiety in University Women.

PubMed

Gammage, Kimberley L; Drouin, Breanne; Lamarche, Larkin

2016-11-01

The current study compared a single yoga group exercise class and a resistance group exercise class for their effects on state body satisfaction and social physique anxiety in women. A pretest-posttest design was used. Participants (N = 46) completed both a resistance exercise class and yoga class in a counterbalanced order. Measures of body satisfaction and social physique anxiety were completed immediately before and after each class. A 2 (time) × 2 (class type) repeatedmeasures multiple analysis of variance showed a significant overall Time × Class Type interaction (F 2,44 = 5.69, P < .01, η p 2 = .21). There was a significant increase in body satisfaction after the yoga class. After both classes, there was a significant decrease in social physique anxiety, but the magnitude of the change was larger after the yoga class than after the resistance class. Both types of exercise class were associated with improvements in body image, but there were greater improvements after the yoga class. This study provided evidence of the positive effects of yoga for reducing state social physique anxiety and increasing state body satisfaction, adding to correlational evidence suggesting that yoga is particularly beneficial for improving body image-related outcomes in women.

Development of Chinese reference man deformable surface phantom and its application to the influence of physique on electromagnetic dosimetry

NASA Astrophysics Data System (ADS)

Yu, D.; Wang, M.; Liu, Q.

2015-09-01

A reference man is a theoretical individual that represents the average anatomical structure and physiological and metabolic features of a specific group of people and has been widely used in radiation safety research. With the help of an advantage in deformation, the present work proposed a Chinese reference man adult-male polygon-mesh surface phantom based on the Visible Chinese Human segment image dataset by surface rendering and deforming. To investigate the influence of physique on electromagnetic dosimetry in humans, a series of human phantoms with 10th, 50th and 90th body mass index and body circumference percentile physiques for Chinese adult males were further constructed by deforming the Chinese reference man surface phantom. All the surface phantoms were then voxelized to perform electromagnetic field simulation in a frequency range of 20 MHz to 3 GHz using the finite-difference time-domain method and evaluate the whole-body average and organ average specific absorption rate and the ratios of absorbed energy in skin, fat and muscle to the whole body. The results indicate thinner physique leads to higher WBSAR and the volume of subcutaneous fat, the penetration depth of the electromagnetic field in tissues and standing-wave occurrence may be the influence factors of physique on electromagnetic dosimetry.

Elemental analysis of different varieties of rice samples using XRF technique

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaur, Jaspreet, E-mail: gillpreet05051812@gmail.com; Kumar, Anil, E-mail: gilljaspreet06@gmail.com

Rice is most consumed staple food in the world providing over 21% of the calorie intake of world’s population having high yielding capacity. Elements detected in rice are Al, As, Br, Cd, Cl, Co, Cs, Cu, Fe, Hg, K, Mg, Mn, Mo, Rb, Se and Zn by using Instrumental Neutron Activation with k0 standardization (R. Jayasekera etal,2004). Some of these trace elements are C, H, O, N, S, Ca, P, K, Na, Cl, Mn, Ti, Mg, Cu, Fe, Ni, Si and Zn are essential for growth of human physique The deficiency or excess of these elements in food is knownmore » to cause a variety of malnutrition or health disorders in the world. Every year, various varieties of rice are launched by Punjab Agriculture University, Ludhiana. The main purpose of which is to increases the yield to attain the maximum profit. But this leads to changing the elemental concentration in them, which may affect the human health according to variation in the nutrition values. The main objective is to study the presence of elemental concentration in various varieties of rice using EDXRF technique.« less

Actes du colloque: Tendances actuelles de la recherche sur la langue parlee (Conference Presentations: Current Trends in Research on Oral Language).

ERIC Educational Resources Information Center

Auger, Julie, Ed.

Student papers presented at a sociolinguistics conference include: "La variation phonologique [d'une voyelle] a Hull"; "La force illocutoire des pronoms personnels 'je' et 'tu' en tant qu'insignes des places d'ou parlent les femmes et les hommes"; "L'emploi des modes indicatif et subjonctif dans le francais parle de la…

La Description des langues naturelles en vue d'applications linguistiques: Actes du colloque (The Description of Natural Languages with a View to Linguistic Applications: Conference Papers). Publication K-10.

ERIC Educational Resources Information Center

Ouellon, Conrad, Comp.

Presentations from a colloquium on applications of research on natural languages to computer science address the following topics: (1) analysis of complex adverbs; (2) parser use in computerized text analysis; (3) French language utilities; (4) lexicographic mapping of official language notices; (5) phonographic codification of Spanish; (6)…

Seventh Colloquium on High Resolution Molecular Spectroscopy 14 to 18 September 1981 (Septieme Colloque sur la Spectroscopie Moleculaire a Haute Resolution 14 a 18 Septembre 1981).

DTIC Science & Technology

1981-01-01

K61n, D-5000 K61n 41 In our attempt to observe the high resolution infra- red spectra of the astrophysically interesting cyanopolyyne molecules, we...cyclobutylsilane could exist in two possible con- formations with the silylgroup in either the axial or equatorial position with respect to the puckered

Actes des journees de linguistique: Colloque sur la recherche etudiante (Proceedings of the Linguistics Conference: Colloquium on Student Research) (Quebec, Canada, March 18-19, 1988).

ERIC Educational Resources Information Center

Lepage, Danielle, Ed.; Dominik, Annette, Ed.

Presentations by students at a colloquium on student research on the occasion of the 50th anniversary of the University of Laval's Faculty of Letters, March 18-19, 1988, include: "Une enquete sur la qualite du francais ecrit au Quebec"; "Amenagement linguistique et neologie"; "Analyse syntaxique des 'arrets et retours' en…

Bilinguisme et biculturalisme: Theories et pratiques professionnelles. Actes du 2eme colloque d'orthophomie/logopedie (Neuchatel, 17-18 septembre, 1992). (Bilingualism and Biculturalism: Theories and Professional Practices. Colloquium on Orthophony/Logopedy (2nd, Neuchatel, Switzerland, September 17-18, 1992)).

ERIC Educational Resources Information Center

Py, Bernard, Ed.

1993-01-01

The conference papers from a colloquium on issues in bilingualism and biculturalism include: "Le bilinguisme et biculturalisme: essai de definition" ("Bilingualism and Biculturalism: Attempt at Definition") (Francois Grosjean); "La variation individuelle dans l'acquisition d'une langue seconde" ("Individual…

Tranel, Numero Special. Actes du 2eme colloque regional de linguistique, Neuchatel 2-3 Oct. 1986 (Tranel, Special Number. Proceedings of the Second Regional Linguistics Colloquium, Neuchatel, Switzerland, October 2-3, 1986).

ERIC Educational Resources Information Center

Neuchatel Univ. (Switzerland).

This publication presents 20 conference papers in French and German on aspects of linguistic research. Papers include: "Objectivite et subjectivite dans la connaissance du langage" (Mahmoudian); "Focalisation et antifocus"(Bearth); "Remarques sur la notion d''etymologie populaire'"(Chambon); "Sur la construction serielle en malgache"; (Fugier)…

African Regional Symposium on Telematics for Development. Report and Recommendations = Colloque regional africain la telematique au service du developpement. Rapport et recommandations (Addis Ababa, Ethiopia, April 3-7, 1995).

ERIC Educational Resources Information Center

International Telecommunication Union, Geneva (Switzerland).

The African Regional Symposium on Telematics for Development was organized in view of the special educational and communication needs of Africa in a time of accelerating change and development of information technologies. The symposium brought together more than 150 African specialists, and over 40 participants from other regions and development…

Actes du colloque sur le bilinguisme, Universite de Neuchatel, 14/15 Septembre, 1981 (Proceedings of the Colloquium on Bilingualism, University of Neuchatel, September 14-15, 1981).

ERIC Educational Resources Information Center

TRANEL, 1982

1982-01-01

This issue contains proceedings of a colloquium on linguistics at the University of Neuchatel: (1) "Propositions epistemologiques pour une etude du bilinguisme (Epistemological Propositions for a Study of Bilingualism)," by B. Py; (2) "Comment on di ca? Prolegomenes a une etude de la composante semantique du langage des migrants (How Do You Say…

Introduction to Solid Rocket Propulsion

DTIC Science & Technology

2004-01-01

totally valid. Fluid-“ structure ” coupling: structure is understood here as the assembly of all the solid parts of the motor: restrictors, grain, case...Conference and Exhibit, San Diego, CA, July 12, 1995. ASSM/POP Program [10] Fonctionnement des moteurs à propergol solide segmentés pour lanceurs ...spatiaux, Colloque CNES/ONERA, Châtillon, FR, Dec. 8-9, 1992. [11] Fonctionnement des moteurs à propergol solide segmentés pour lanceurs spatiaux

Stress and Thermal Stress Compensation in Quartz SAW Devices

DTIC Science & Technology

1991-08-01

Laboratoire De Physique Et Metrologie Des Oscillateurs E. Bigler, D. Hauden, S. Ballandras OTIC hELECTLE E P19 99f "j APPROVED FOR PUBLIC RELASE, DISTRIBUTION...ORGANIZATION NAME(S) AND ADDRE$S(ES) 8. PERFORMING ORGANIZATION Laboratoire De Physique Et Metrologie Des Oscillateurs REPORT NUMBER Center National de la

Developmental and Contextual Risks of Social Physique Anxiety among Female Athletes

ERIC Educational Resources Information Center

Gay, Jennifer L.; Monsma, Eva V.; Torres-McGehee, Toni M.

2011-01-01

In the present study, we examined developmental and contextual factors that may increase the odds of reporting higher social physique anxiety (SPA) among 404 adolescent athletes 11 to 16 years old. Findings showed older, later maturing athletes past peak height velocity and with greater body mass index (BMI) reported higher SPA. Individual…

Social Physique Anxiety in Adolescence: An Exploration of Influences, Coping Strategies, and Health Behaviors

ERIC Educational Resources Information Center

Sabiston, C. M.; Sedgwick, W. A.; Crocker, P. R. E.; Kowalski, K. C.; Mack, D. E.

2007-01-01

This study explored adolescent females' experiences of social physique anxiety (SPA) and related coping strategies. A final sample of 31 adolescent females ages 13 to 18 years discussed dealing with SPA during individual semistructured interviews. Resultant themes pertaining to the transactional experiences of SPA were coded using content…

An examination of eating attitudes and physical activity levels of Turkish university students with regard to self-presentational concern.

PubMed

Aşçi, F Hülya; Tüzün, Macide; Koca, Canan

2006-11-01

This study aimed to examine eating attitudes and physical activity level of young women and men university students with regard to social physique anxiety level. 482 university students participated in this study voluntarily. "Eating Attitude Test (EAT-40)", "Social Physique Anxiety Scale" and "Physical Activity Assessment Questionnaire" were used to assess the eating attitude, social physique anxiety and physical activity level of participants, respectively. Women and men participants in this study were assigned to high (HSPA) and low (LSPA) social physique anxiety groups with respect to their median scores. Men had favorable eating attitudes and higher physical activity level than women. In addition, participants in the HSPA group had unfavorable eating attitudes and higher physical activity MET values than participants in the LSPA group. On the other hand, groupxgender interaction was only significant for the eating attitudes scores but, not for physical activity level. Women in the HSPA group scored higher on the EAT-40 than men in HSPA and women and men in the LSPA groups.

Examining Combinations of Social Physique Anxiety and Motivation Regulations Using Latent Profile Analysis

ERIC Educational Resources Information Center

Ullrich-French, Sarah; Cox, Anne E.; Cooper, Brittany Rhoades

2016-01-01

Previous research has used cluster analysis to examine how social physique anxiety (SPA) combines with motivation in physical education. This study utilized a more advanced analytic approach, latent profile analysis (LPA), to identify profiles of SPA and motivation regulations. Students in grades 9-12 (N = 298) completed questionnaires at two time…

A Polytomous Item Response Theory Analysis of Social Physique Anxiety Scale

ERIC Educational Resources Information Center

Fletcher, Richard B.; Crocker, Peter

2014-01-01

The present study investigated the social physique anxiety scale's factor structure and item properties using confirmatory factor analysis and item response theory. An additional aim was to identify differences in response patterns between groups (gender). A large sample of high school students aged 11-15 years (N = 1,529) consisting of n =…

Give or Take a Few? Comparing Measured and Self-Reported Height and Weight as Correlates of Social Physique Anxiety

ERIC Educational Resources Information Center

Gay, Jennifer; Monsma, Eva V.; Torres-McGehee, Toni

2009-01-01

Statistically controlling for physical size is common practice, especially in self-perception studies uncovering the etiology of maladaptive behaviors, such as eating disorders. For example, social physique anxiety (SPA)--apprehension about social evaluations while presenting oneself in front of others (Leary, 1992)--is a prominent correlate of…

Physical and Physiological Correlates of Social Physique Anxiety in College Students

ERIC Educational Resources Information Center

Yaman, Çetin

2017-01-01

The purpose of the present study was to explore the relationship among social physique anxiety, physical measures such as body fat and physical self-concept. 367 (226 male and 141 female) college students ranging in age from 21 to 33 participated in the study. Participants were randomly chosen among the healthy students without any metabolic and…

Examining the Moderating Effect of Appearance Impression Motivation on the Relationship between Perceived Physical Appearance and Social Physique Anxiety

ERIC Educational Resources Information Center

Amorose, Anthony J.; Hollembeak, Jill

2005-01-01

Despite the conceptual importance of impression motivation in predicting social anxiety (Leary & Kowalski, 1995; Schlenker & Leary, 1982), no research has tested the link between impression motivation specifically regarding one's physical appearance (appearance impression motivation, or AIM) and social physique anxiety (SPA). The purpose of this…

Social Physique Anxiety and Intention to Be Physically Active: A Self-Determination Theory Approach

ERIC Educational Resources Information Center

Sicilia, Álvaro; Sáenz-Alvarez, Piedad; González-Cutre, David; Ferriz, Roberto

2016-01-01

Purpose: Based on self-determination theory, the purpose of this study was to analyze the relationship between social physique anxiety and intention to be physically active, while taking into account the mediating effects of the basic psychological needs and behavioral regulations in exercise. Method: Having obtained parents' prior consent, 390…

Bibliography on Future Trends in Terrorism

DTIC Science & Technology

1998-09-01

Bernhard Restel, et alia. "La police en interfaces: Colloque universitaire de l’Institut Suisse de Police," Revue Internationale de Criminologie et...Convenzione di Ginevra per l’Istituzione di una Corte Penale Internazionale sul Terrorismo : Un document da tornare a leggere," Il Politico, [Rome], 62...The author, who is president of Peru , points out that terrorist organizations in Peru have struggled for a decade to erode the democratic system and

School Exchanges Present and Future. Proceedings of the Symposium (Barcelona, Spain, March 13-17, 1991) = Bilan et Perspectives des Echanges Scolaires. Actes du colloque (Barcelone, Spain, 13-17 mar 1991).

ERIC Educational Resources Information Center

Commission of the European Communities, Brussels (Belgium).

This document sets forth the proceedings of a symposium on the subject of international educational exchanges. Part 1 of the document includes introductory remarks by Catalonia's minister of education and David Coyne of the European Commission's task force on human relations. Part 2 offers specific introductory material on political, theoretical,…

Les situations de communication. Actes du Colloque d'orthophonie/logopedie, (1er, Neuchatel, Suisse, 9-10 mars 1990). (Communication Situations. Papers from the Conference on Speech and Reading Therapy (1st, Neuchatel, Switzerland, March 9-10, 1990)).

ERIC Educational Resources Information Center

Py, Bernard, Ed.

1990-01-01

The following papers were presented at the conference (titles are translated from the French): "Linguistic Approaches to Verbal Interaction and Its Context" (Jean-Francois de Pietro); "Pragmatic Approaches to the Rehabilitation of Aphasia Patients" (Marie-Pierre de Partz); "Contributions of Communication Development Theories: Limits of Their…

Le Changement linguistique: Evolution, variation, and heterogeneite. Actes du colloque de Neuchatel Universite (Neuchatel, Suisse, 2-4 Octobre 2000) (Linguistic Change: Evolution, Variation, Heterogeneity. Proceedings of the University of Neuchatel Colloquium [Neuchatel, Switzerland, October 2-4, 2000]).

ERIC Educational Resources Information Center

Matthey, Marinette, Ed.

2001-01-01

Articles in this issue focus on language evolution, variation, and heterogeneity. The following are English translations of the French article titles appearing in the issue: "Irregular Phonetic Development Due to Frequency; Regional Traits in Proto-Romance"; "Linguistic Evolution and Evolution of Perspective in the Comparative…

Quand la réadaptation blesse? Éducateurs victimes de violence

PubMed Central

Geoffrion, Steve; Ouellet, Frédéric

2014-01-01

Cette étude vise à comprendre le phénomène de la violence physique vécue par les éducateurs œuvrant dans dix Centres Jeunesse (CJ) du Québec. Pour ce faire, un sondage de victimisation a été administré à 586 éducateurs en internat. En premier lieu, la prévalence de cette problématique sera établie. Par la suite, les facteurs individuels et environnementaux prédisposant aux agressions physiques seront identifiés. Des édu-cateurs sondés, 53,9 % rapportent avoir été victimes de violence physique au cours de la dernière année. Sur le plan individuel, être affecté par les manifestations agressives des clients et la fréquence des violences psychologiques subies augmentent les risques de victimisation physique. Quant au contexte, l’âge de la clientèle et le motif de l’interven-tion (basé sur la loi justifiant le placement) auprès de l’enfant ou de l’adolescent influencent l’occurrence des actes violents dirigés contre les éducateurs. Nos analyses montrent également que les violences physiques dont sont victimes les éducateurs affectent autant l’individu que l’institution. L’identification de facteurs permettant de prédire les risques de victimisation pourrait notamment servir à orienter les programmes de prévention de la violence dans les CJ, mais aussi à cibler les éducateurs les plus à risque afin de leur fournir un soutien adapté. PMID:24976673

Social Physique Anxiety and Pressure to Be Thin in Adolescent Ballet Dancers, Rhythmic Gymnastics and Swimming Athletes

ERIC Educational Resources Information Center

Kosmidou, Evdoxia; Giannitsopoulou, Evgenia; Moysidou, Dimitra

2017-01-01

Participation in sports may influence negative body image and Social Physique Anxiety (SPA) as there is pressure by significant others to have a certain body image. The aim of the present study was to examine possible differences in SPA and perceived pressure to be thin between female preadolescent and adolescent ballet dancers, rhythmic…

Traditional medicine in Central Sahara: pharmacopoeia of Tassili N'ajjer.

PubMed

Hammiche, Victoria; Maiza, Khadra

2006-05-24

Further to the previously reported ethnobotanical surveys of North-Sahara and Ahaggar [Maiza, K., Brac de la Perrière, R.A., Bounaga, N., Hammiche, V., 1990. Usages traditionnels des plantes spontanées d'El Goléa. Actes du Colloque de l'Association. Française pour la Conservation des Espèces Végétales, Mulhouse; Maiza, K., Hammiche, V, Bounaga, N., Brac de la Perrière, R.A., 1992. Inventaire des plantes médicinales de trois régions d'Algérie. Actes du Colloque International hommage à Jean Pernès: Complexes d'espèces, flux de gènes, ressources génétiques des plantes. Paris, pp. 631-633; Maiza, K., Brac de la Perrière, R.A., Hammiche, V., 1993a. Traditional Saharian pharmacopoeia. Acta Horticulturae, I.S.H.S. 332, 37-42; Maiza, K., Brac de la Perrière, R.A., Hammiche, V., 1993b. Récents apports à l'ethnopharmacologie du Sahara algérien: Actes du 2ème Colloque Européen d'Ethnopharmacologie & 11ème Conférence Internationale d'Ethnomédecine. Heidelberg, pp. 169-171; Maiza, K., Brac de la Perrière, R.A., Hammiche, V., 1995. Pharmacopée traditionnelle saharienne. Revue de Médecines et Pharmacopées Africaines, 9 (No. 1), 71-75; Maiza, K., Smati, D., Brac de la Perrière, R.A., et Hammiche, V., 2005. Pharmacopée traditionnelle au Sahara Central: Pharmacopée de l'Ahaggar. Retenu pour publication. Revue de Médecines et Pharmacopées Africaines.], we have now moved our investigations on Tassili N'Ajjer, another distinct region of the Southern Algerian Sahara. Ethnobotanic research has been carried out through interviews with nomad populations and the traditional pratictionners of recognised competence. To date, 80 wild indigenous medicinal plants have been identified and are currently used by the local population for various illnesses. Information on their vernacular Tamahaq and Arabic names, their flowering distribution, the parts used, the modes of preparation and routes of administration are reported and discussed in this paper. This work completes our investigation in Central Sahara.

Application of the Semantics Enrichment Concept in the Information Fusion for Command Support

DTIC Science & Technology

2006-12-01

ACRONYM(S) 11. SPONSOR/MONITOR’S REPORT NUMBER(S) 12. DISTRIBUTION/AVAILABILITY STATEMENT Approved for public release, distribution unlimited 13 ...Arcueil. Juin 93. Rudnianski M. L’aide à la décision tactique dans la crise internationale. in Colloque de l’ARESAD. Paris. Novembre 1989...is defined by : μR A x C (x,z):: Maxy∈B [Min [μR A x B (x,y), μR B x C (y,z)

Interventions en groupe et interactions. Actes du 3eme colloque d'orthophonie/logopedie (Neuchatel, 29-30 septembre, 1994) (Group Interventions and Interactions. Proceedings of the Colloquium on Speech Therapy (3rd, Neuchatel, Switzerland, September 29-30, 1994).

ERIC Educational Resources Information Center

Py, Bernard, Ed.

1995-01-01

Conference papers on group methods of speech therapy include: "Donnees nouvelles sur les competences du jeune enfant. Proposition de nouveaux concepts" (New Data on the Competences of the Young Child. Proposition of New Concepts) (Hubert Montagner); "Interactions sociales et apprentissages: quels savoirs en jeu" (Social Interactions and Teaching:…

Language, etayage et interactions therapeutiques: Actes du 5eme colloque d'orthophonie/logopedie (Language, Scaffolding and Therepeutic Interactions: Proceedings of the 5th Colloquium on Speech Therapy and Speech Pathology) (Neuchatel, Switzerland, September 25-26, 1998).

ERIC Educational Resources Information Center

Sovilla, J. Buttet, Ed.; de Weck, G., Ed.

1998-01-01

These articles on scaffolding in language and speech pathology/therapy are included in this issue: "Strategies d'etayage avec des enfants disphasiques: sont-elles specifiques?" ("Scaffolding Strategies for Dysphasic Children: Are They Specific?") (Genevieve de Weck); "Comparaison des strategies discursives d'etayage dans un conte et un recit…

Familes en Mutation dans une Societe en Mutation: Actes du Colloque, Bruxelles, 8-10 fevrier, 1992 (Families in Transition in a Society in Transition: Conference Proceedings, Brussels, February 8-10, 1992).

ERIC Educational Resources Information Center

United Nations Educational, Scientific, and Cultural Organization, Paris (France). International Council of Women.

This collection of essays on the family includes: "Discours d'ouverture" [Opening Speech] (L. Boeykens); "Transformer la famille, transformer l'homme et la femme, transformer la societe" [Transform the Family, Transform the Man and the Woman, Transform Society] (H. Sokalski); and "Vers un nouveau contrat social. Le role des femmes dans la famille"…

An Examination of Motivational Regulations, Dispositional Flow and Social Physique Anxiety among College Students for Exercise: A Self-Determination Theory Approach

ERIC Educational Resources Information Center

Ersöz, Gözde

2016-01-01

Based on self-determination theory (SDT), the main goal of this study is to analyze dispositional flow and social physique anxiety (SPA) that could be predicted by gender, BMI and motivational regulations and to examine motivational regulations, dispositional flow and SPA of college students in terms of stage of change for exercise. Participants…

Human Factors Aspects of Aircraft Accidents

DTIC Science & Technology

1982-10-01

preexistante (incapacite soudaine ou non en vo_l) La plus dangereuse (en particulier dans les phases decollage et atterrissage) est l’in- capacite... soudaine . Elle peut 6tre mortelle - dans ce caa, generalement eardiaque - ou sa traduire par des troubles psychiques - d’un developpement brutal et...done conduire a une lncapacite plus ou moins soudaine en vol. pefaillances physiques accidentelles Kors les defaillances physiques classiques

Caracterisation Physique des Sols Camp Militaire de Petawawa (Physical Characterization of the Soil in Military Camp of Petawawa).

DTIC Science & Technology

1979-10-01

AD-AO95 392 DEFENCE RESEARCH ESTABLISHMENT OTTAWA (ONTARIO) FI6 8/13 CARACTERISATION PHY SI QUE DES SOLS CAMP MILITAIRE DE PETAWAWA (P--ETC(U) OCT 79...defense nationale 2b, GROUP Ottawa, Ontario -KIA-04----- , I D )kI1,vlt Nr Ti fti CARACTERISATION PHYSIQUE DES SOLS, BASE DES FORCES CANADIENNES PETAWAAA I

Examining the Stability of the 7-Item Social Physique Anxiety Scale Using a Test-Retest Method

ERIC Educational Resources Information Center

Scott, Lisa A.; Burke, Kevin L.; Joyner, A. Barry; Brand, Jennifer S.

2004-01-01

This study examined the stability of the 7-item Social Physique Anxiety Scale (SPAS-7) using a test-retest method. Collegiate, undergraduate (N = 201) students completed two administrations of the SPAS-7, with a 14-day separation between the administrations. The scale was administered either at the beginning or end of the physical activity class.…

The Examination of the Correlation between Social Physique Anxiety Levels and Narcissism Levels of the Students Who Studied at the SPES

ERIC Educational Resources Information Center

Gezer, Engin

2014-01-01

The aim of the study was to discover the correlation between social physique anxiety levels and narcissism levels of the students of the school of the physical education and sports. A total of 308 students who studied at different academic departments of the school of the physical education and sports of Mustafa Kemal University participated in…

Optimizing Operational Physical Fitness (Optimisation de L’Aptitude Physique Operationnelle)

DTIC Science & Technology

2009-01-01

NORTH ATLANTIC TREATY ORGANISATION RESEARCH AND TECHNOLOGY ORGANISATION AC/323(HFM-080)TP/200 www.rto.nato.int RTO TECHNICAL REPORT TR... RESEARCH AND TECHNOLOGY ORGANISATION AC/323(HFM-080)TP/200 www.rto.nato.int RTO TECHNICAL REPORT TR-HFM-080 Optimizing Operational Physical...Fitness (Optimisation de l’aptitude physique opérationnelle) Final Report of Task Group 019. ii RTO-TR-HFM-080 The Research and

What’s in a Surname? Physique, Aptitude, and Sports Type Comparisons between Tailors and Smiths

PubMed Central

Voracek, Martin; Rieder, Stephan; Stieger, Stefan; Swami, Viren

2015-01-01

Combined heredity of surnames and physique, coupled with past marriage patterns and trade-specific physical aptitude and selection factors, may have led to differential assortment of bodily characteristics among present-day men with specific trade-reflecting surnames (Tailor vs. Smith). Two studies reported here were partially consistent with this genetic-social hypothesis, first proposed by Bäumler (1980). Study 1 (N = 224) indicated significantly higher self-rated physical aptitude for prototypically strength-related activities (professions, sports, hobbies) in a random sample of Smiths. The counterpart effect (higher aptitude for dexterity-related activities among Tailors) was directionally correct, but not significant, and Tailor-Smith differences in basic physique variables were nil. Study 2 examined two large total-population-of-interest datasets (Austria/Germany combined, and UK: N = 7001 and 20532) of men’s national high-score lists for track-and-field events requiring different physiques. In both datasets, proportions of Smiths significantly increased from light-stature over medium-stature to heavy-stature sports categories. The predicted counterpart effect (decreasing prevalences of Tailors along these categories) was not supported. Related prior findings, the viability of possible alternative interpretations of the evidence (differential positive selection for trades and occupations, differential endogamy and assortative mating patterns, implicit egotism effects), and directions for further inquiry are discussed in conclusion. PMID:26161803

Psychophysiological Tracking of a Female Physique Competitor through Competition Preparation

PubMed Central

ROHRIG, BRANDON J.; PETTITT, ROBERT W.; PETTITT, CHERIE D.; KANZENBACH, TODD L.

2017-01-01

Natural physique competitions are based on subjective judgments of how a competitor appears on show day. Prior to competition, there is a prolonged dieting phase referred to as contest preparation. The primary goal is to reduce body fat levels while maintaining skeletal muscle mass. The study tracked the physiological and psychological changes for a 24 year old female preparing for a physique competition. Purpose: The study was conducted to describe the physiological and psychological changes of a female physique competitor who engages in long-term contest preparation. Methods: Diet, body composition, blood work, energy expenditure, mood, and performance were evaluated through contest preparation. Results: The participant lost 10.1kg throughout contest preparation in a strong weekly linear pattern (R2=0.97). Body fat was reduced from 30.45% to 15.85% while fat free mass was maintained. Mood for the participant remained stable until month five, when an observed variation occurred, with performance maintaining. Conclusions: Contest preparation was successful in reducing the body fat in the participant while having a minimum effect on both performance and fat free mass. For athletes looking to lose large amounts of body fat with minimal performance decrements a prolonged diet period with moderate exercise and food restriction can be an effective solution. PMID:28344742

Psychophysiological Tracking of a Female Physique Competitor through Competition Preparation.

PubMed

Rohrig, Brandon J; Pettitt, Robert W; Pettitt, Cherie D; Kanzenbach, Todd L

2017-01-01

Natural physique competitions are based on subjective judgments of how a competitor appears on show day. Prior to competition, there is a prolonged dieting phase referred to as contest preparation. The primary goal is to reduce body fat levels while maintaining skeletal muscle mass. The study tracked the physiological and psychological changes for a 24 year old female preparing for a physique competition. The study was conducted to describe the physiological and psychological changes of a female physique competitor who engages in long-term contest preparation. Diet, body composition, blood work, energy expenditure, mood, and performance were evaluated through contest preparation. The participant lost 10.1kg throughout contest preparation in a strong weekly linear pattern (R 2 =0.97). Body fat was reduced from 30.45% to 15.85% while fat free mass was maintained. Mood for the participant remained stable until month five, when an observed variation occurred, with performance maintaining. Contest preparation was successful in reducing the body fat in the participant while having a minimum effect on both performance and fat free mass. For athletes looking to lose large amounts of body fat with minimal performance decrements a prolonged diet period with moderate exercise and food restriction can be an effective solution.

What's in a Surname? Physique, Aptitude, and Sports Type Comparisons between Tailors and Smiths.

PubMed

Voracek, Martin; Rieder, Stephan; Stieger, Stefan; Swami, Viren

2015-01-01

Combined heredity of surnames and physique, coupled with past marriage patterns and trade-specific physical aptitude and selection factors, may have led to differential assortment of bodily characteristics among present-day men with specific trade-reflecting surnames (Tailor vs. Smith). Two studies reported here were partially consistent with this genetic-social hypothesis, first proposed by Bäumler (1980). Study 1 (N = 224) indicated significantly higher self-rated physical aptitude for prototypically strength-related activities (professions, sports, hobbies) in a random sample of Smiths. The counterpart effect (higher aptitude for dexterity-related activities among Tailors) was directionally correct, but not significant, and Tailor-Smith differences in basic physique variables were nil. Study 2 examined two large total-population-of-interest datasets (Austria/Germany combined, and UK: N = 7001 and 20,532) of men's national high-score lists for track-and-field events requiring different physiques. In both datasets, proportions of Smiths significantly increased from light-stature over medium-stature to heavy-stature sports categories. The predicted counterpart effect (decreasing prevalences of Tailors along these categories) was not supported. Related prior findings, the viability of possible alternative interpretations of the evidence (differential positive selection for trades and occupations, differential endogamy and assortative mating patterns, implicit egotism effects), and directions for further inquiry are discussed in conclusion.

International Conference on Fixed Point Theory and Applications (Colloque International Theorie Du Point Fixe et Applications)

DTIC Science & Technology

1989-06-09

Theorem and the Perron - Frobenius Theorem in matrix theory. We use the Hahn-Banach theorem and do not use any fixed-point related concepts. 179 A...games defined b’, tions 87 Isac G. Fixed point theorems on convex cones , generalized pseudo-contractive mappings and the omplementarity problem 89...and (II), af(x) ° denotes the negative polar cone ot of(x). This condition are respectively called "inward" and "outward". Indeed, when X is convex

2-Extendability in Two Classes of Claw-Free Graphs

DTIC Science & Technology

1992-01-01

extendability of planar graphs, Discrete Math ., 96, 1991, 81-99. [Lai M. Las Verguas, A note on matchings in graphs, Colloque sur la Thiorie des Graphes...43, 1987, 187-222. [LP L. Loviss and M.D. Plummet, Matching Theory, Ann. Discrete Math . 29, North-Holland, Amsterdam, 1986. [P11 M.D. Plummer, On n...extendable graphs, Discrete Math . 31, 1960, 201-210. [P21 Extending matchinp in planar graphs IV, Proc. of the Conference in honor of Cert Sabidussi, Ann

Discours oraux--discours ecrits: quelles relations? Actes du 4eme colloque d'orthophoine/logopedie (Neuchatel, 3-4 octobre, 1996) (Oral Discourse--Written Discourse: What Is the Relationship? Proceedings of the Colloquium on Speech Therapy (4th, Neuchatel, Switzerland, October 3-4, 1996).

ERIC Educational Resources Information Center

Py, Bernard, Ed.

1996-01-01

Research papers on the relationship between oral and written language include: "Une distinction bien fragile: oral/ecrit" ("A Fragile Distinction: Oral/Written") (Francoise Gadet); "Oral et ecrit dans les representations des enseignants et dans les pratiques quotidiennes de la classe de francais" ("Oral and Written Language in Teachers'…

Second Colloquim on the Scattering of Ultrasonic Waves (Deuxieme Colloque sur la Diffusion des Ondes Ultrasonores).

DTIC Science & Technology

1985-01-29

France. I specially hope that out of our studies on resonances, and of the related experiments, new methods and applications will be developed in the...say so, such an echo in France. I specially hope that out of our studies on resonances, and of the related experiments, new methods and applications...length, due to the non-separability of this problem, results for the eigenfrequencies can nevertheless be obtained here by the use of special methods

Actes du colloque sur la didactique des langues aujourdi'hui: Pratiques et realite. (29 Sept./1 Oct. 1983) [Proceedings of a Colloquium on the Teaching of Modern Languages Today: Practice and Reality. (September 29-October 1, 1983)].

ERIC Educational Resources Information Center

Travaux Neuchatelois de Linguistique (TRANEL), 1984

1984-01-01

The eight papers in this collection include: "Un enseignant de langues a la recherche de la pierre philosophale" (A Language Teacher in Search of the Philosopher's Stone); "Apprentissage autodirige: Compte rendu d'experience 1978-83" (Self-Directed Learning: Report of Experience 1978-83); "Teaching Without a Language Syllabus But With a Linguistic…

Crowd Confrontation and Non-Lethal Weapons: A Literature Review and Conceptual Model

DTIC Science & Technology

2008-03-01

what he knows (cognitive state), and what he feels physically (physical state) or psychologically (emotional state). 7. Communication (i.e. the act of...ressent physiquement (état physique) ou psychologiquement (état émotionnel). 7. La communication (c.-à-d. l’action de transmettre de l’information) joue...riot situations during peacekeeping operations, for example in Drvar, Bosnia, in April 1998 [ Coombs , 2006]. The Canadian Forces thus have a need to

Characteristics of muscle dysmorphia in male football, weight training, and competitive natural and non-natural bodybuilding samples.

PubMed

Baghurst, Timothy; Lirgg, Cathy

2009-06-01

The purpose of this study was to identify differences in traits associated with muscle dysmorphia between collegiate football players (n=66), weight trainers for physique (n=115), competitive non-natural bodybuilders (n=47), and competitive natural bodybuilders (n=65). All participants completed demographic questionnaires in addition to the Muscle Dysmorphia Inventory (Rhea, Lantz, & Cornelius, 2004). Results revealed a significant main effect for group, and post hoc tests found that the non-natural bodybuilding group did not score significantly higher than the natural bodybuilding group on any subscale except for Pharmacological Use. Both the non-natural and natural bodybuilding groups scored significantly higher than those that weight trained for physique on the Dietary Behavior and Supplement Use subscales. The collegiate football players scored lowest on all subscales of the Muscle Dysmorphia Inventory except for Physique Protection where they scored highest. Findings are discussed with future research expounded.

Physique traits of lightweight rowers and their relationship to competitive success

PubMed Central

Slater, G; Rice, A; Mujika, I; Hahn, A; Sharpe, K; Jenkins, D

2005-01-01

Objectives: Physique traits and their relationship to competitive success were assessed amongst lightweight rowers competing at the 2003 Australian Rowing Championships. Methods: Full anthropometric profiles were collected from 107 lightweight rowers (n = 65 males, n = 45 females) competing in the Under 23 and Open age categories. Performance assessments were obtained for 66 of these rowers based on results in the single sculls events. The relationship between physique traits and competitive success was then determined. Results: Lower body fat (heat time estimate –8.4 s kg–1, p<0.01), greater total body mass (heat time estimate –4.4 s kg–1, p = 0.03), and muscle mass (heat time estimate –10.2 s kg–1, p<0.01) were associated with faster 2000 m heat times. Conclusions: The more successful lightweight rowers were those who had lower body fat and greater total muscle mass. PMID:16183770

The influence of social anxiety on the body checking behaviors of female college students.

PubMed

White, Emily K; Warren, Cortney S

2014-09-01

Social anxiety and eating pathology frequently co-occur. However, there is limited research examining the relationship between anxiety and body checking, aside from one study in which social physique anxiety partially mediated the relationship between body checking cognitions and body checking behavior (Haase, Mountford, & Waller, 2007). In an independent sample of 567 college women, we tested the fit of Haase and colleagues' foundational model but did not find evidence of mediation. Thus we tested the fit of an expanded path model that included eating pathology and clinical impairment. In the best-fitting path model (CFI=.991; RMSEA=.083) eating pathology and social physique anxiety positively predicted body checking, and body checking positively predicted clinical impairment. Therefore, women who endorse social physique anxiety may be more likely to engage in body checking behaviors and experience impaired psychosocial functioning. Published by Elsevier Ltd.

The Relationship of Gender and Self-Efficacy on Social Physique Anxiety among College Students.

PubMed

Rothberger, Sara M; Harris, Brandonn S; Czech, Daniel R; Melton, Bridget

The anxiety or fear associated with physique evaluation is defined as Social Physique Anxiety (SPA). Numerous studies have examined this construct, yet a gap exists exploring this phenomenon among current college students with SPA, self-efficacy, and gender concurrently. Therefore, the purposes of this study included quantitatively analyzing the association between SPA, gender, and self-efficacy. Participants included 237 students at a Southeastern university participating in jogging, body conditioning, or weight training courses. Analysis of Variance yielded a significant main effect for self-efficacy as well, as those with lower self-efficacy displayed higher levels of SPA ( p < 0.001). Stepwise regression analysis indicated self-efficacy and gender were both significant predictors of SPA. This information could aid in creating interventions designed to decrease the prevalence of SPA and increase levels of self-efficacy among the current college student population.

Préface

NASA Astrophysics Data System (ADS)

Moncorgé, R.

2006-12-01

Cette nouvelle édition du Colloque UVX avait pour objectifs de : - réunir les chercheurs et les industriels intéressés par les applications et les développements les plus récents obtenus sur les sources UV, VUV et X, cohérentes ou incohérentes, et les optiques et matériaux associés ; - dresser un bilan des sources de photons à haute énergie et de leurs applications courantes et futures ; - susciter de nouvelles collaborations ; - ouvrir de nouveaux champs disciplinaires. Elle a été organisée par le laboratoire CIRIL au VVF de Colleville-sur-Mer, dans le département du Calvados, du 6 au 9 juin 2006, la journée du 5 juin ayant été consacrée à une réunion de travail du GDR CNRS SAXO, ce GDR regroupant une majorité de scientifiques concernés par le Colloque UVX. La manifestation a réuni ainsi une centaine de participants dont une dizaine d'exposants industriels. Parmi ces participants, trente étaient invités à donner une conférence orale. Une sélection a été faite également parmi les meilleures communications soumises par affiches pour qu'elles soient présentées oralement. Une trentaine de ces communications ont été préparées sous la forme d'articles de 6 à 12 pages et font l'objet de cet ouvrage. De nombreux travaux récents ont été exposés tant au niveau des sources que des techniques de caractérisation et des applications, ceci dans des domaines très divers allant de la physique des lasers et de la mise en forme spatiale et temporelle des faisceaux au domaine de l'imagerie médicale et biologiques en passant par les techniques de fabrication des cristaux, fibres et films minces organiques et inorganiques. Plusieurs résultats marquants en sont ressortis. Dans le domaine des sources, la mise en forme spatiale du faisceau laser utilisé pour la production d'harmoniques d'ordre élevé dans les gaz, ceci à l'aide de lames de phase peu onéreuses et simples d'utilisation, semble être une bonne solution pour accroître les efficacités de conversion et pour produire des impulsions UVX de quelques dizaines de microjoules. Parallèlement, des progrès notables ont été effectués dans la génération d'impulsions sub-100 as isolées accordables et de large bande spectrale en utilisant des impulsions de pompe ultracourtes bien contrôlée en phase. Il apparaît que la gamme spectrale accessible peut être encore largement étendue en jouant sur la longueur d'onde excitatrice et sur le milieu générateur pour pouvoir atteindre des impulsions de moins de 10 as. Des premiers résultats ont été aussi exposés concernant l'obtention d'un laser X à 18,9 nm pompé en incidence rasante (technique GRIP) à partir d'une cible de molybdène nickelloide et d'un laser Ti:Sa produisant des impulsions de plus de 2 microjoules. L'intérêt des milieux gazeux à excimères a été également de nouveau démontré pour l'amplification d'impulsions ultracourtes intenses TW dans le proche UV avec un contraste élevé (>1011). Bien qu'encore marginale, il faut enfin signaler l'arrivée des fibres optiques microstructurées avec la génération de supercontinuum de longueurs d'onde (spectre blanc) jusque dans le proche UV. Du côté des processus fondamentaux et des applications, sont particulièrement ressortis la caractérisation de plasmas denses utilisant des harmoniques élevées à l'aide d'une expérience interférométrique originale, la caractérisation de plasmas de taille nanométrique émetteurs de rayonnement X produits par interaction d'impulsions laser ultracourtes avec des agrégats de gaz rares ainsi que le dépôt de couches minces de biomolécules à l'aide de la technique MAPLE, technique susceptible d'améliorer la conservation des molécules, en particulier des protéines. Enfin, dans le domaine de la métrologie et de l'imagerie, l'importance des lames de phase dans la mise en forme spatiale des faisceaux, en particulier pour le projet Mega-Joule, a été de nouveau souligné, des progrès significatifs (réflectivité, bande passante, stabilité temporelle et thermique) ont été obtenus dans le domaine des revêtements interférentiels multicouches pour laser EUV autour de 40 nm, et des améliorations significatives, en particulier au niveau des détecteurs, ont été signalées dans le domaine de l'imagerie X du petit animal, la conception de sources dédiées à microfoyers délivrant des rayons X de basses énergies très rapides pour éviter le flou inhérent aux mouvements de l'animal restant encore nécessaire. Le Colloque a permis des échanges très fructueux entre laséristes et utilisateurs et entre scientifiques et industriels commercialisant sources, systèmes et détecteurs. Il a permis également de donner la parole à des intervenants très jeunes et souvent très brillants (doctorants et jeunes chercheurs) qui seront sans aucun doute les futurs responsables de nos laboratoires, centres de recherche et entreprises. Les progrès constatés résultant de travaux portant souvent sur les deux années écoulées (puisque c'est la fréquence choisie pour ce Colloque) et les résultats obtenus comme les perspectives annoncées montrant de nouveau toute la pertinence de cette manifestation, celle-ci sera reconduite en 2008.

Torleif Ericson 60th Birthday

ScienceCinema

None

2017-12-09

Plusieurs discours à l'occasion du 60me anniversaire de Torleif Ericson, physicien né à Lund (Suède), et remerciements pour son travail et son effort de relier la physique des particules à la physique nucléaire. A la fin de la cérémonie un document scientifique de 400 pages "die Festschrift" lui est remis comme cadeau d'anniversaire avec un grand nombre de contributions d'amis etc...

Ohio State University Symposium (45th) on Molecular Spectroscopy Held in Columbus, Ohio on 11-15 Jun 1990

DTIC Science & Technology

1990-06-15

Atmospheric Administration, Boulder, CO 80303. Address of Ortigoso and Escribano: Instituto de Estructura de al Materia, Consejo Superior de investigaciones ...10 min.(1:42) J. M. GUILMOT anO M. HERMAN, Laboratoire de Chimie Physique Moleculaire, tjniversit’c Libre de ...CANY-PEYRET, Laboratoire de Physique Mole’*u’ai:e et Atmospherique, Universite Pierre et Marie Curie et CNRS, 75252 Paris, France. MF4. FIR LASER STARK

Women's anxiety about social and exercise settings.

PubMed

Walton, Vicki R; Finkenberg, Mel E

2002-04-01

This study involved a comparison of social physique anxiety, assessed through the application of a modified version of the Social Physique Anxiety Scale, with 28 women who were new members exercising at all-female facilities compared to 43 new female members exercising at coeducational facilities. Analyses indicated there were no significant differences in means between the groups. The scores of women attending all-female facilities were significantly more influenced by the sex of members when choosing a facility.

SOME ASPECTS OF RECENT FINDINGS PERTAINING TO THE BODY COMPOSITION OF ATHLETES, OBESE INDIVIDUALS AND PATIENTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Behnke, A.R.; Taylor, W.L.

Whole-body density determinations are reported for a small group of athletes (weight lifters), and an analysis is presented of data derived from several investigations in which similar techniques were employed to measure total body water and the total exchangeable sodium, chloride (bromine space), and potassium in the body. The mean value for body density (1.080) obtained on the athletes was similar to that obtained previously on professional football players and much higher than the mean value usually obtained on young men (-- 1.060). In addition to the low body fat content characteristic of the athletes, the ratio of excha&eable K/submore » e/ to Cl/sub e/ was higher in these men than in men of average physique. In turn, the values for K/sub e/Cl/sub e/ were even lower in obese individuals and in patients. In healthy individuals, the sum (K/sub e/ + Cl/sub e/) is highly correlated (r = 0.99) with total body water, and this finding provides an independent estimate of lean body weight. In patients afflicted with certain types of chronic diseases, particularly those associated with the edematous state, the exchangeable Na/sub e/ to K/sub e/ ratio is strikingly higher than it is in healthy individuals. Estimates of the amount of transudate in edematous patients may be made from analyses of total body water andd total exchangeable Na/sub e/ and K/sub e/. Additional determinations, such as whole body density and red cell mass, are required to assess accurately the size of the lean body mass in these patients. Normal adult lean body size prior to illness may be estimated from skeletal measurements. (auth)« less

Influence of players' physique on rugby football injuries.

PubMed Central

Lee, A J; Myers, J L; Garraway, W M

1997-01-01

OBJECTIVES: To determine whether there is an association between a player's physique and injuries incurred while playing rugby football. METHODS: A cohort study was carried out involving all senior rugby clubs in the Scottish Borders during the 1993-1994 rugby season. Somatotype estimates were determined for 1152 (95%) of the 1216 eligible players. Body mass index (BMI), chest to waist ratio, and the ponderal index (PI) were used to classify players' physique as endomorphic (obese), mesomorphic (muscular), and ectomorphic (linear). RESULTS: A strong association was found between physique and age (chi 2 test: chi 2 = 317.2, df = 10, P < 0.0001). More younger players were ectomorphs. Older players were more often endomorphic. The physiques of forwards and backs were significantly different (chi 2 test: chi 2 = 58.6, df = 2, P < 0.0001), with forwards being of a heavier build than three-quarters, even after adjustment for age. Endomorphic players were more likely than ectomorphs to be injured in a match after adjustment for age (age-adjusted mean BMI for players who were injured in a match was 25.4 compared with 24.6 for players who were not injured in a match, P < 0.0001; adjusted chest to waist ratio means were 1.136 and 1.125 respectively, P = 0.0307; adjusted PI means were 0.414 and 0.417 respectively, P = 0.0056). Increased risk of injury may occur when players play out of position, since one fifth of all injuries occurred in this circumstance. CONCLUSIONS: Further research needs to be conducted using a more objective method of measuring somatotype on a further cohort of players so that the risk of injury for different body types can be examined more closely and related to other potential confounding factors. The level of increased risk for individuals playing out of their usual playing position needs to be established with a greater degree of certainty. PMID:9192128

Encyclopédie scientifique de l'universe: les étoiles - le système solaire.

NASA Astrophysics Data System (ADS)

This book is a revised, extended and updated edition of the volume published in 1979 (27.003.156).Contents: Première partie - le système solaire: 1. Astronomie des positions (J. Lévy). 2. Le système des constantes astronomiques; les données fondamentales (A. Bec-Borsenberger, F. Chollet). 3. Mécanique du système solaire (B. Morando). 4. Relief et structure des planètes telluriques et des satellites (A. Cazenave, P. Masson, P. Thomas). 5. Physique des atmosphères planétaires denses (D. Gautier, M. Combes,G. Moreels, J. P. Parisot, O. Tallagrand). 6. Les anneaux entourant les planètes (N. Borderies, A. Dollfus). 7. Les comètes et les météorites (A. Levasseur-Regourd). 8. L'environnement du Soleil et de la Terre (J.-L. Steinberg, J.-P. Bibring, A. Boischot, P. Couturier, R. Dumont, T. Encrenaz, P. Lamy).Deuxième partie - le Soleil et les bases de la physique stellaire: 9. Théorie des atmosphères du Soleil et des étoiles (R. Michard). 10. Physique de l'atmosphère solaire {non perturbée} (P. Mein). 11. Les centres actifs (J.-C. Hénoux, J.-C. Vial). 12. Éruptions solaires et phénomènes transitoires (J.-C. Hénoux, M. Pick, G. Trottet). 13. Le cycle solaire (J. Latour, P. Simon).Troisième partie - physique des étoiles: 14. Acquisition des données fondamentales (F. Spite). 15. Les étoiles doubles (R. Bouigue, P. Muller). 16. Les étoiles variables (M. Auvergne, A. Baglin, D. Ducatel, J.-M. Le Contel, J. C. Valtier). 17. Structure interne et évolution des étoiles (J.-P. Zahn). 18. Les familles physiques d'étoiles (G. Cayrel).

Canadian Journal of Physics. Volume 69, Number 2 (Revue Canadienne de Physique. Volume 69, Numero 2

DTIC Science & Technology

1991-02-01

4KNational Research Conseil national Council Canada de recherches Canada SMC CtRC Canadian Journal Revue canadienne of Physics de physique Volume 69...Number 2, February 1991 Volume 69, num~ro 2, W~rier 1991 AD-A235 711 Aviliable for $36.00 from National Research Council of Canada, Ottawa, Ont...Publid par THE NATIONAL RESEARCH COUNCIL OF CANADA LE CONSEIL NATIONAL DE RECHERCHES DU CANADA Editor R. W. NICHOLLS Directeur scientifique Editorial

MICROMECHANICS AND MICROSTRUCTURE EVOLUTION: Modeling, Simulation and Experiments. Held in Madrid, Spain on 12-16 September 2005

DTIC Science & Technology

2006-10-30

acknowledges funding from the ‘‘ Programa Torres Quevedo’’ of the Spanish Ministerio de Educación y Ciencia. References [1] Nix WD. Metall Mater Trans A...University of Madrid E. T. S. de Ingenieros de Caminos Madrid 28040 Spain 8. PERFORMING ORGANIZATION REPORT NUMBER N/A 10. SPONSOR...Rodney * Génie Physique et Mécanique des Matériaux (UMR CNRS 5010), Institut National Polytechnique de Grenoble, 101 rue de la Physique, 38402

Micromechanics and Microstructure Evolution: Modeling, Simulation and Experiments. Conference Held in Madrid, Spain, 12-16 Sep 2005

DTIC Science & Technology

2006-10-30

acknowledges funding from the ‘‘ Programa Torres Quevedo’’ of the Spanish Ministerio de Educación y Ciencia. References [1] Nix WD. Metall Mater Trans A...University of Madrid E. T. S. de Ingenieros de Caminos Madrid 28040 Spain 8. PERFORMING ORGANIZATION REPORT NUMBER N/A 10. SPONSOR...Rodney * Génie Physique et Mécanique des Matériaux (UMR CNRS 5010), Institut National Polytechnique de Grenoble, 101 rue de la Physique, 38402

Modeling the human body shape in bioimpedance vector measurements.

PubMed

Kim, Chul-Hyun; Park, Jae-Hyeon; Kim, Hyeoijin; Chung, Sochung; Park, Seung-Hun

2010-01-01

Human body shape, called somatotype, has described physique of humans in health and sports applications, relating anthropometric measurements to fatness, muscularity and linearity in a structured way. Here we propose a new method based on bioelectric impedance vector analysis (BIVA) of R/H and Xc/H to represent the cross-sectional area and the body cell mass in a given surface area (m(2)) respectively. Data from six gymnasts, ten dancers, and five fashion models, groups whose physiques and BMI ranges were distinct from one another, were measured for somatotype and BIVA. The models had highest values of the R/H and gymnasts the lowest. Xc/H was lower in models than in the dancers and gymnasts (p < 0.05). Phase angle was lowest in the models and highest in gymnasts significantly (p < 0.05). Pattern analysis from BIVA corresponded to the calculated anthropometric somatotype supporting the hypothesis that BIA's resistance (R) and reactance (Xc) are meaningful discriminates of body size and function which relate to physique in a purposive way.

Psychometric properties of the Social Physique Anxiety Scale (SPAS-7) in Spanish adolescents.

PubMed

Sáenz-Alvarez, Piedad; Sicilia, Álvaro; González-Cutre, David; Ferriz, Roberto

2013-01-01

The purpose of this study was to validate the Spanish version of Motl and Conroy's model of the Social Physique Anxiety Scale (SPAS-7). To achieve this goal, a sample of 398 secondary school students was used, and the psychometric properties of the SPAS-7 were examined through different analyses. The results supported the seven-item model, although the item 5 did not show any significant correlation with two items from this model and had a lower factor loading than the rest of items. The structure of the model was invariant across gender and Body Mass Index (BMI). Alpha value over .70 and suitable levels of temporal stability were obtained. Girls and students classified according to the BMI as overweight and obese had higher scores in social physique anxiety than boys and the group classified as underweight and normal range. The findings of this study provided reliability and validity for the SPAS-7 in a Spanish adolescent sample.

Dermatoglyphic characters and physique: a correlation study.

PubMed

Rothhammer, F; Llop, E; Neel, J V

1982-01-01

The association of anthropometrics, particularly hand measurements, with dermatoglyphic characters is quantified. Children with square hands exhibit higher main line indices, a-b ridge counts, and more open atd angles. Adults with broader hands have more arches. Taller individuals with larger hands present higher a-b ridge counts and leaner subjects with long narrow hands, closer atd angles. The correlation of physique and dermatoglyphics is small but if verified, suggests that at early fetal stages, factors responsible for the establishment of dermatoglyphic patterns interact with genetic determinants of adult shape that are already active.

High Maternal Age and Low Pre-Pregnancy Body Mass Index Correlate with Lower Birth Weight of Male Infants.

PubMed

Fukuda, Sayuri; Tanaka, Yurika; Harada, Kiyomi; Saruwatari, Ayako; Kitaoka, Kaori; Odani, Kiyoko; Aoi, Wataru; Wada, Sayori; Nishi, Yukari; Oguni, Tatsuya; Asano, Hiroaki; Hagiwara, Nobuko; Higashi, Akane

2017-02-01

In Japan, the percentage of leanness has been increasing in young women, and the percentage of low birth weight infants (< 2,500 g) has increased. Moreover, the average age of primiparas rose 3.5 years during the last 30 years. The purpose of this study was to clarify the relationship between maternal age and the influence of maternal pre-pregnancy physique on the neonatal physique of infants. Questionnaires were issued to the participants and collected when they submitted their gestational notifications at their local ward office in Kyoto Prefecture. After delivery, we obtained information on the course of the pregnancy and the neonatal physique of the infants from the participant's maternal passbooks. A total of 454 mothers (age 20 ≥) were analyzed: 161 young mothers (aged 20 to 29 years), 185 mothers (aged 30 to 34 years), and 108 older mothers (age ≥ 35). Overall, the mean rate of leanness (pre-pregnancy BMI < 18.5) was 23.8%. We found that birth weight was significantly lower in female infants, born to lean young mothers, compared to non-lean young mothers, whereas no significant difference was detected in other mothers (age ≥ 30), irrespective of pre-pregnancy BMI. By contrast, male infants, born to older lean mothers (age ≥ 35), showed significantly lower birth weight. Thus, maternal pre-pregnancy BMI exerts differential effects on the fetal growth (neonatal physique), depending on the maternal age and the sex of infants. We need to improve BMI in pre-pregnancy women, especially those in the twenties and 35 years old or over.

Physique and Body Composition in Soccer Players across Adolescence

PubMed Central

Nikolaidis, Pantelis Theodoros; Vassilios Karydis, Nikos

2011-01-01

Purpose Although the contribution of physique and body composition in soccer performance was recognized, these parameters of physical fitness were not well-studied in adolescent players. Aim of this study was to investigate physique and body composition across adolescence. Methods Male adolescents (N=297 aged 12.01–20.98 y), classified into nine one-year age-groups, child (control group, N=16 aged 7.34–11.97 y) and adult players (control group, N=29 aged 21.01–31.59 y), all members of competitive soccer clubs, performed a series of anthropometric measures (body mass, height, skinfolds, circumferences and girths), from which body mass index (BMI), percentage of body fat (BF%), fat mass (FM), fat free mass (FFM) and somatotype (Heath-Carter method) were calculated. Results Age had a positive association with FM (r=0.2, P<0.001) and FFM (r=0.68, P<0.001), and a negative association with BF (r=−0.12, P=0.047). Somatotype components changed across adolescence as well; age was linked to endomorphy (r=−0.17, P=0.005), mesomorphy (r=0.14, P=0.019) and ectomorphy (r=−0.17, P=0.004). Compared with age-matched general population, participants exhibited equal body mass, higher stature, lower body mass index and lower BF. Conclusion During adolescence, soccer players presented significant differences in terms of body composition and physique. Thus, these findings could be employed by coaches and fitness trainers engaged in soccer training in the context of physical fitness assessment and talent identification. PMID:22375222

Colloquium on High Resolution Molecular Spectroscopy (8th), 19-23 September 1983 (Colloque sur la Spectroscopie Moleculaire a Haute Resolution (Huitieme), 19-23 Septembre 1983).

DTIC Science & Technology

1983-09-23

avec lea autres State. A FITTING PROCEDURE FOP EXTENSIVELY PERTURBED HAMILTONIANS APPLICATION TO THE A1I- STATE OF CO ANDRE LE FLOCH AND JEAN MASSON...BENICHOU, Jean -Claude DEROCHE Laboratoire d’Infrarouge, Associg au C.N.R.S. Universitf de Paris-Sud, Bitiment 350 91405 ORSAY Cfdex, France Le pompage...MEUDON, FRANCE and Jean -Yves RONCIN Equipe de Spectroscopie, C.N.R.S. (L.A. 171, Universitis de Lyon I et Saint-Etienne) 158 bis Cours Fauriel, 42023

Notional Syllabuses: Theory into Practice. L'enseignement de la competence de communication en langues secondes. Actes du colloque de la Commission interuniversitaire suisse de linguistique appliquee. Bulletin CILA (The Teaching of Communicative Competence in Second Languages. Acts of the Colloquium of the Swiss Interuniversity Commission for Applied Linguistics. CILA Bulletin).

ERIC Educational Resources Information Center

Wilkins, David

This paper discusses the theory and practice of the notional syllabus, three specific problems arising from it, and an experimental course proposed as one way of implementing it. Basically, a notional syllabus aims to organize language teaching in terms of the purposes of communication. Its foundation is a system of notional categories and the…

Club of Rome

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2006-04-18

Le Club de Rome s'est fait connaître du grand public par la publication du premier ouvrage "Halte à la croissance" qui a fait l'object d'un débat, il y a 2 ans. Le Prof. Tinbergen a commencé par s'adonner à la physique, il est docteur en physique et très tôt il s'est tourné vers les problèmes sociaux économiques. Il est expert auprès des nombreux gouvernements et organisations internationales et il a vu ses travaux couronnés par le prix Nobel en 1969.

Major Events Coordinated Security Solutions Technical Report Closeout (MECSS): The Application of Science and Technology to Reduce Risk for V2010 and G8/G20 Summits

DTIC Science & Technology

2010-12-01

CBRNE), aux infrastructures essentielles, à la surveillance, à la sécurité physique, à la cybernétique et à la socio- psychologie . Le présent rapport...la socio- psychologie . Dans le cadre du projet SCSGE, on a produit plus de 195 rapports scientifiques, fruit des efforts, du dévouement et du...aux infrastructures essentielles, à la surveillance, à la sécurité physique, à la cybernétique et à la socio- psychologie . Le présent rapport

Etude theorique des fluctuations structurales dans les composes organiques a dimensionnalite reduite

NASA Astrophysics Data System (ADS)

Dumoulin, Benoit

Les systemes a dimensionnalite reduite constituent maintenant une branche entiere de la physique de la matiere condensee. Cette derniere s'est developpee rapidement au cours des dernieres annees, avec la decouverte des materiaux organiques qui presentent, justement, des proprietes physiques fortement anisotropes. Cette these presente une etude en trois parties de plusieurs composes organiques qui, bien que tres differents du point de vue de leurs compositions chimiques et de leurs proprietes physiques a haute temperature, subissent tous une instabilite structurale a tres basse temperature. De plus, dans chacun des cas, l'instabilite structurale est precedee d'un important regime fluctuatif a partir duquel les proprietes physiques changent de maniere significative. Notre etude suit un ordre chronologique inverse puisque nous nous attardons en premier lieu au cas de composes recemment decouverts: les composes de la famille des (BCPTTF)2X (X = PF6 , AsF6). Ces derniers sont des isolants magnetiques a la temperature ambiante et subissent une instabilite structurale de type spin-Peierls a une temperature appelee TSP. En particulier, nous nous interessons a l'etude des proprietes physiques de ces systemes dans le regime fluctuatif, qui precede cette instabilite. Notre etude theorique nous permet de comprendre en detail comment ces systemes s'approchent de l'instabilite struturale. Dans la seconde partie de cette these, nous etudions le regime fluctuatif (pre-transitionnel) observe experimentalement dans le compose de (TMTTF)2PF6. Ce compose organique, dont la structure s'apparente aux sels de Bechgaard, subit une instabilite de type spin-Peierls a une temperature T SP = 19K. Bien que ce compose possede la particularite d'etre un bon conducteur a la temperature ambiante, il subit une transition de type Mott-Hubbard a une temperature Trho ≈ 220K et devient alors un isolant magnetique, analogue aux composes de la famille des (BCPTTF)2X. Le regime fluctuatif precedant l'instabilite spin-Peierls apparait ensuite vers 60K. Notre etude theorique montre qu'un modele d'electrons en interaction de type "g-ologie" avec possibilite de processus umklapp permet de bien rendre compte des proprietes physiques de ce systeme. Finalement, la troisieme partie de cette these porte sur l'etude des premiers composes organiques quasi-unidimensionnels a avoir ete synthetises: les composes de la famille du TTF-TCNQ. Notre etude theorique des instabilites structurales que presentent ces composes n'est evidemment pas la premiere. L'originalite de cette derniere est qu'elle tient compte des fortes interactions entre les electrons, presentent dans ces composes. Pour tenir compte de telles interactions, nous avons choisi la formulation "liquide de Luttinger" qui nous permet de mieux traiter ce regimne dit de couplage fort.

Prospective associations of concerns about physique and the development of obesity, binge drinking, and drug use among adolescent boys and young adult men.

PubMed

Field, Alison E; Sonneville, Kendrin R; Crosby, Ross D; Swanson, Sonja A; Eddy, Kamryn T; Camargo, Carlos A; Horton, Nicholas J; Micali, Nadia

2014-01-01

Relatively little is known about the prevalence of concerns with physique and eating disorders among males and their relation to subsequent adverse outcomes. A broader range of eating disorders needs to be defined to diagnose these illnesses appropriately in males. To investigate whether males with psychiatric symptoms related to disordered eating and concern about physique are more likely to become obese, to start using drugs, to consume alcohol frequently (binge drinking), or to develop high levels of depressive symptoms. The data come from questionnaires sent every 12 to 36 months from 1999 through 2010 to youth in a prospective cohort study, the Growing Up Today Study. The analysis included 5527 males aged 12 to 18 years in 1999 from across the United States who responded to the Growing Up Today Study questionnaires. Development of obesity and high levels of depressive symptoms and initiation of drug use and binge drinking at least monthly. From 1999 through 2011 in at least 1 study year, 9.2% of respondents reported high concerns with muscularity but no bulimic behaviors; 2.4%, high concerns with muscularity and use of supplements, growth hormone derivatives, or anabolic steroids to achieve their desired physique; 2.5%, high concerns with thinness but no bulimic behaviors; and 6.3%, high concerns with thinness and muscularity. For eating disorders, 0.8% had partial- or full-criteria bulimia nervosa or purging disorder and 2.9% had partial or full-criteria binge eating disorder but no association with the outcomes of interest. Infrequent binge eating or purging or overeating without a loss of control were reported by 31.0%. However, independent of age and body mass index, males with high concerns about thinness but not muscularity were more likely to develop high depressive symptoms (odds ratio, 2.72; 95% CI, 1.36-5.44). Males with high concerns about muscularity and thinness were more likely than their peers to use drugs (odds ratio, 2.13; 95% CI, 1.31-3.46), and males with high concerns about muscularity who used supplements and other products to enhance physique were more likely to start binge drinking frequently (2.06; 1.58-2.69) and using drugs (2.16; 1.49-3.11). High concerns with muscularity are relatively common among adolescent boys and young men. Males with these concerns who use potentially unhealthy products to improve their physique are at increased risk of adverse outcomes but may not be recognized by their health care providers as having a weight-related disorder because of the sex-specific presentation.

A qualitative examination of women's self-presentation and social physique anxiety during injury rehabilitation.

PubMed

Driediger, Molly V; McKay, Carly D; Hall, Craig R; Echlin, Paul S

2016-12-01

To understand women's self-presentation experiences in the rehabilitation setting, and their attitudes and preferences toward the social and physical features of the rehabilitation environment. Qualitative study. Outpatient physiotherapy clinic. Ten women (age 18 to 64) with high social physique anxiety (Social Physique Anxiety Scale score ≥25) referred for physiotherapy following acute injury. Semi-structured interviews were conducted prior to commencement of treatment, and again after a third treatment session. Participants experienced extensive self-presentational concerns that were intensified due to the nature of the physiotherapy environment. The women reported that their self-presentational anxiety did not diminish over time, and was related to others' negative perceptions regarding their physical appearance and inability to perform exercises as well as expected. The presence of men or younger women in the clinic was identified as a barrier to appointment attendance, along with open concept clinic settings, which were associated with the most potential for evaluation. Mirrors and windows in the physiotherapy clinic were highlighted as anxiety provoking. The women suggested that they would feel apprehensive about advocating for themselves if they felt uncomfortable with the area in which they were receiving treatment, and instead used avoidance coping strategies (e.g., hiding behind equipment, preventing eye contact) to manage their anxiety. Physique-anxious women experience extensive self-presentational concerns in the rehabilitation environment, which could affect treatment adherence. Modifying the treatment setting, providing protective self-presentational strategies such as positive self-talk, and open patient-therapist communication could be implemented to help mitigate these concerns. Copyright © 2015 Chartered Society of Physiotherapy. Published by Elsevier Ltd. All rights reserved.

The protective role of general self-determination against 'thin ideal' media exposure on women's body image and eating-related concerns.

PubMed

Mask, Lisa; Blanchard, Céline M

2011-04-01

Women's responses to 'thin ideal' media pending their level of general self-determination (GSD) were examined. High and low GSD women (N = 99) viewed a 'thin physique salient' (TPS) video or a 'thin physique non-salient' (TPNS) video. Following exposure to the TPS video, perceptions of pressure from the media to be thin, body dissatisfaction, and concerns over quantity of food were greater for low but not high GSD women. However, high GSD women reported greater concerns over the quality of food they eat following exposure to the TPNS video. Prevention efforts aimed at enhancing GSD are discussed.

Club of Rome

ScienceCinema

None

2017-12-09

Le Club de Rome s'est fait connaître du grand public par la publication du premier ouvrage "Halte à la croissance" qui a fait l'object d'un débat, il y a 2 ans. Le Prof. Tinbergen a commencé par s'adonner à la physique, il est docteur en physique et très tôt il s'est tourné vers les problèmes sociaux économiques. Il est expert auprès des nombreux gouvernements et organisations internationales et il a vu ses travaux couronnés par le prix Nobel en 1969.

Mesure de coefficients d'absorption de plasmas créés par laser nanoseconde

NASA Astrophysics Data System (ADS)

Thais, F.; Chenais-Popovics, C.; Eidmann, K.; Bastiani, S.; Blenski, T.; Gilleron, F.

2005-06-01

La mesure des coefficients d'absorption dans les plasmas chauds est particulièrement utile dans le domaine de la fusion par confinement inertiel ainsi que dans divers contextes en astrophysique. Le développement des calculs de physique atomique qui y sont associés repose sur des hypothèses qu'il est nécessaire de vérifier dans la plus large gamme possible de conditions physiques. Nous présentons ici la méthode de mesure et d'analyse employée en nous appuyant sur l'exemple des cibles multicouches nickel/aluminium.

Role of Physique on Probability of Injury to the Low Back

NASA Astrophysics Data System (ADS)

Shaibani, Saami J.

2009-03-01

In a related study of the response of the upper and lower cervical spine[1], there was some correlation between a change in physique and the potential for injury to the neck during automotive events. A similar undertaking in this research on the lumbar spine and sacral spine revealed a much more marked effect, namely an increase in injury potential to the low back when weight is increased. Although there were some exceptions to this, the overall trend was distinct. This is perhaps to be expected when one considers that most additional weight at the same height tends to be located in the center or lower torso. However, it is first time in any comparable analysis of injury causation that there has been a more noticeable pattern for the low back than the neck. The latter was more pronounced with environment geometry, as seen when the height of the seat back was varied. Such changeability again reinforces previous findings that injury outcomes for individual patients cannot always be predicted by what happens in general. 1. http://meetings.aps.org/link/BAPS.2007.MAR.K1.2 (Role of physique on probability of injury to the neck).

The Social Physique Anxiety Scale: an example of the potential consequence of negatively worded items in factorial validity studies.

PubMed

Motl, R W; Conroy, D E; Horan, P M

2000-01-01

Social physique anxiety (SPA) based on Hart, Leary, and Rejeski's (1989) Social Physique Anxiety Scale (SPAS) was originally conceptualized to be a unidimensional construct. Empirical evidence on the factorial validity of the SPAS has been contradictory, yielding both one- and two-factor models. The two-factor model, which consists of separate factors associated with positively and negatively worded items, has stimulated an ongoing debate about the dimensionality and content of the SPAS. The present study employed confirmatory factor analysis (CFA) to examine whether the two-factor solution to the 12-item SPAS was substantively meaningful or a methodological artifact. Results of the CFAs, which were performed on responses from four different samples (Eklund, Kelley, and Wilson, 1997; Eklund, Mack, and Hart, 1996), supported the existence of a single substantive SPA factor underlying responses to the 12-item SPAS. There were, in addition, method effects associated with the negatively worded items that could be modeled to achieve good fit. Therefore, it was concluded that a single substantive factor and a non-substantive method effect primarily related to the negatively worded items best represented the 12-item SPAS.

Fibrillation auriculaire et activité physique

PubMed Central

Bosomworth, N. John

2015-01-01

Résumé Objectif Examiner les données probantes portant sur les effets de divers niveaux d’activité physique sur l’incidence de fibrillation auriculaire (FA) dans la population générale et chez les athlètes d’endurance. Sources des données Une recherche a initialement été menée sur PubMed à l’aide des titres MeSH ou des mots-de-texte anglais (avec descripteur de zone de recherche TIAB [title and abstract]) atrial fibrillation et exercise ou physical activity ou athlet* ou sport*, sans filtre additionnel. Le système GRADE (grading of recommendations, assessment, development, and evaluation) a été utilisé pour tirer les conclusions au sujet de la qualité et du niveau de preuve. Sélection des études Aucune étude d’intervention n’est ressortie de la recherche. Les études d’observation ont alors été jugées acceptables et, bien que des études prospectives de cohortes à long terme de plus grande envergure auraient été préférables, des essais cas-témoins ou transversaux ont aussi été inclus dans cette révision. Synthèse Les données disponibles laissent croire à un lien proportionnel à la dose entre l’exercice plus intense et l’incidence réduite de FA chez les femmes. Il en va de même pour les hommes dont le niveau d’activité physique est de faible à modéré. Chez les hommes seulement, l’activité intense est associée à un risque accru de FA et ce, dans la plupart des études, mais pas la totalité d’entre elles. Ce risque est modéré, le rapport de risque instantané étant de 1,29 dans l’une des études de meilleure qualité. Le risque de FA chez la plupart des personnes régulièrement actives est plus faible que le risque observé dans la population sédentaire appariée. Conclusion La fibrillation auriculaire est probablement moins fréquente à mesure que le niveau d’activité physique augmente, la relation dose-réponse étant démontrable. À toutes les intensités, l’exercice doit être encouragé pour ses effets sur le bien-être physique et la réduction de la mortalité. Chez les hommes qui pratiquent des activités vigoureuses, les effets bénéfiques sur la FA pourraient disparaître et le risque pourrait surpasser celui observé dans la population sédentaire; cependant les données probantes à cet effet ne sont ni robustes ni constantes. Ces hommes devraient être mis au courant de cette hausse modeste du risque s’ils choisissent de poursuivre leurs activités physiques vigoureuses.

The role of physical activity, body mass index and maturity status in body-related perceptions and self-esteem of adolescents.

PubMed

Altıntaş, A; Aşçı, F H; Kin-İşler, A; Güven-Karahan, B; Kelecek, S; Özkan, A; Yılmaz, A; Kara, F M

2014-01-01

Adolescence represents a transitional period which is marked by physical, social and psychological changes. Changes in body shape and physical activity especially alter and shape the psychological well-being of adolescents. The purpose of this study was to determine the role of physical activity level, body mass index and maturity status in body-related perception and self-esteem of 11-18 years old adolescents. A total of 1012 adolescents participated in this study. The "Social Physique Anxiety Scale", "Body Image Satisfaction Scale", "Physical Self-Perception Profile for Children" and "Rosenberg Self-Esteem Inventory" were administered. Physical activity level and body mass index were assessed using the "Physical Activity Questionnaire" and "Bioelectrical Impedance Analyzer", respectively. Regression analysis indicated that body mass index was the only predictor of perceived body attractiveness, social physique anxiety, body image satisfaction and self-esteem for female adolescents. For male adolescents, both physical activity and body mass index were correlated with perceived body attractiveness and social physique anxiety. Pubertal status were not correlated with self-esteem and body-related perceptions for both males and females adolescents. In summary, body mass index and physical activity plays an important role in body-related perceptions and self-esteem of adolescents.

Social physique anxiety and physical activity behaviour of male and female exercisers.

PubMed

Portman, Robert M; Bradbury, Jane; Lewis, Kiara

2018-03-01

Despite females consistently reporting greater social physique anxiety (SPA), previous literature has yet to demonstrate whether SPA gender differences are linked to the way males and females perform physical activity. This study investigated an association between SPA and physical activity frequency, history of exercise, and physical activity intensity. Participants were represented by currently active users (N = 33 males; N = 31 females) of an on-campus university-run gym and completed a background physical activity questionnaire and the nine-item Social Physique Anxiety Scale. Participants also performed an exercise session at a self-selected level of exertion, with the intensity of each session measured via heart rate monitor. SPA was not associated with physical activity frequency, history of exercise (length of gym membership), or intensity for male and female exercisers. With respect to male participants, females reported higher SPA and a preference for performing higher intensity physical activity. Females and males also indicated a preference for performing aerobic and anaerobic physical activity respectively. Our findings suggest the experience of SPA does not deter body-conscious individuals from the performance of regular physical activity. Findings also suggest the discrepancy in male and female SPA is not linked to differences in the way physical activity is performed.

Apprendre a vivre ensemble grace a l'enseignement de l'histoire et de la geographie. Rapport final du colloque sur le theme. (Learning To Live Together Thanks to the Teaching of History and Geography. Final Report on a Colloquium on That Theme.) Proceedings of a Colloquium Organized Jointly by the International Bureau of Education (UNESCO) and the University of Geneva (Geneva, Switzerland, June 12, 1998).

ERIC Educational Resources Information Center

Andre, Yves, Ed.; Mouzoune, Abdelkrim, Ed.

These Proceedings contain 14 chapters (or papers) from a colloquium on learning to live together in peaceful co-existence thanks to the teaching of history and geography. All the papers in the Proceedings are in French, but each paper has both an English summary and a Spanish summary. The 14 papers are, as follows: (1) "Introduction"…

Lung function in children in relation to ethnicity, physique and socio-economic factors

PubMed Central

Lum, Sooky; Bountziouka, Vassiliki; Sonnappa, Samatha; Wade, Angie; Cole, Tim J; Harding, Seeromanie; Wells, Jonathan CK; Griffiths, Chris; Treleaven, Philip; Bonner, Rachel; Kirkby, Jane; Lee, Simon; Raywood, Emma; Legg, Sarah; Sears, Dave; Cottam, Philippa; Feyeraband, Colin; Stocks, Janet

2015-01-01

Question Can ethnic differences in spirometry be attributed to differences in physique and socio-economic factors? Methods Assessments were undertaken in 2171 London primary school-children on two occasions a year apart whenever possible, as part of the Size and Lung function In Children study. Measurements included spirometry, detailed anthropometry, 3-D photonic scanning for regional body shape, body composition, information on ethnic ancestry, birth and respiratory history, socio-economic circumstances and tobacco smoke exposure. Results Technically acceptable spirometry was obtained from 1901 children (mean age: 8.3yrs (range: 5.2-11.8yrs), 46% boys, 35% White; 29% Black-African origin; 24% South-Asian; 12% Other/mixed) on 2767 test occasions. After adjusting for sex, age and height, FEV1 was 1.32, 0.89 and 0.51 z-score units lower in Black, South-Asian and Other ethnicity children respectively, when compared with White children, with similar decrements for FVC (p<0.001 for all). Although further adjustment for sitting height and chest width reduced differences attributable to ethnicity by up to 16%, significant differences persisted after adjusting for all potential determinants including socio-economic circumstances. Answer Ethnic differences in spirometric lung function persist despite adjusting for a wide range of potential determinants, including body physique and socio-economic circumstances, emphasising the need to use ethnic-specific equations when interpreting results. PMID:26493801

Foreword

NASA Astrophysics Data System (ADS)

Villain, Jacques

2017-01-01

The present issue of the Comptes Rendus Physique aims to provide the scientific reader with an opportunity to become acquainted with current scientific trends that have been distinguished by prizes of the French Academy of Sciences.

History without time: Buffon's natural history as a nonmathematical physique.

PubMed

Hoquet, Thierry

2010-03-01

While "natural history" is practically synonymous with the name of Buffon, the term itself has been otherwise overlooked by historians of science. This essay attempts to address this omission by investigating the meanings of "physique," "natural philosophy," and "history," among other terms, with the purpose of understanding Buffon's actual objectives. It also shows that Buffon never claimed to be a Newtonian and should not be considered as such; the goal is to provide a historical analysis that resituates Buffon's thought within his own era. This is done, primarily, by eschewing the often-studied question of time in Buffon. Instead, this study examines the nontemporal meanings of the word "history" within the naturalist's theory and method. The title of his Natural History is examined both as an indicator of the kind of science that Buffon was hoping to achieve and as a source of great misinterpretation among his peers. Unlike Buffon, many of his contemporaries actually envisioned the study of nature from a Baconian perspective where history was restricted to the mere collection of facts and where philosophy, which was the implicit and ultimate goal of studying nature, was seen, at least for the present, as unrealizable. Buffon confronts this tendency insofar as his Histoire naturelle claims to be the real physique that, along with describing nature, also sought to identify general laws and provide clear insight into what true knowledge of nature is or should be. According to Buffon, history (both natural and civil) is not analogous to mathematics; it is a nonmathematical method whose scope encompasses both nature and society. This methodological stance gives rise to the "physicization" of certain moral concepts--a gesture that was interpreted by his contemporaries as Epicurean and atheist. In addition, Buffon reduces a number of metaphysically tainted historical concepts (e.g., antediluvian monuments) to objects of physical analysis, thereby confronting the very foundation of natural theology. In Buffon, as this essay makes clear, natural history is paving the way for a new physique (science of natural beings), independent from mathematics and from God, that treats naturalia in a philosophical and "historical" manner that is not necessarily "temporal."

Colloque S&T Symposium 2009: Understanding the Human Dimension in 21st Century Conflict/Warfare: Taking Care of the Front Line (comprendre la dimension humaine dans les conflits/la conduite de la guerre au xxle siecle: veiller a la ligne de front)

DTIC Science & Technology

2009-06-01

à un adversaire d’un type différent. Il a ajouté que le modèle de gestion du personnel doit également s’adapter aux changements importants que subit...humaines; on risque d’assister à un manque d’imagination et de sang- froid si nous ne nous penchons pas sur les possibilités sur le plan technologique...la conduite de la guerre au XXIe siècle: Veiller à la ligne de front Stefan Wolejszo DGMPRA Kyle Fraser DGMPRA Orrick White (Editor) DRDC Corporate

Drive for leanness and health-related behavior within a social/cultural perspective.

PubMed

Tod, David; Edwards, Christian; Hall, Gareth

2013-09-01

We examined relationships between drive for leanness and perceived media pressure to change appearance, internalization of an ideal physique, exercise frequency, and dieting. Men and women (N=353) completed the Drive for Leanness Scale, the Sociocultural Attitudes Toward Appearance Questionnaire-3, the Eating Attitudes Test-26, and a demographic inventory. Drive for leanness was significantly correlated with athletic internalization (.52), pressure to attain an ideal physique (.25), exercise frequency (.36), and dieting (.25). Structural equation modeling revealed a good fitting model (χ(2)=2.85, p<.241; CFI=.99; NNFI=.98; RMSEA=.04; SRMR=.02) with internalization predicting drive for leanness, which in turn predicted dieting and exercise. Results reveal social/cultural theory helps enhance the understanding of the drive for leanness and its relationship with health-related behavior. Copyright © 2013 Elsevier Ltd. All rights reserved.

Promotion of Healthy Weight-Control Practices in Young Athletes.

PubMed

Carl, Rebecca L; Johnson, Miriam D; Martin, Thomas J

2017-09-01

Children and adolescents may participate in sports that favor a particular body type. Some sports, such as gymnastics, dance, and distance running, emphasize a slim or lean physique for aesthetic or performance reasons. Participants in weight-class sports, such as wrestling and martial arts, may attempt weight loss so they can compete at a lower weight class. Other sports, such as football and bodybuilding, highlight a muscular physique; young athletes engaged in these sports may desire to gain weight and muscle mass. This clinical report describes unhealthy methods of weight loss and gain as well as policies and approaches used to curb these practices. The report also reviews healthy strategies for weight loss and weight gain and provides recommendations for pediatricians on how to promote healthy weight control in young athletes. Copyright © 2017 by the American Academy of Pediatrics.

A Self-determination Theory approach to the study of body image concerns, self-presentation and self-perceptions in a sample of aerobic instructors.

PubMed

Thøgersen-Ntoumani, Cecilie; Ntoumanis, Nikos

2007-03-01

This study examined motivational predictors of body image concerns, self-presentation and self-perceptions using Self-determination Theory as a guiding framework. Aerobic instructors (N = 149) completed questionnaires measuring general need satisfaction, exercise motivational regulations, body image concerns, social physique anxiety and self-perceptions. Introjected regulation predicted all outcome variables in the expected direction. Intrinsic motivation positively predicted physical self-worth. Further, autonomy need satisfaction negatively predicted body image concerns. Finally, differences existed in need satisfaction, introjected regulation, self-perceptions and social physique anxiety between those at risk of developing eating disorders and those not at risk. The results underline the importance of overall and exercise-specific feelings of self-determination in dealing with body image concerns and low self-perceptions of aerobics instructors.

The effect of labour on somatotype of males during the adolescent growth period.

PubMed

Ozener, B; Duyar, I

2008-01-01

Although the effect of labour and physical stress on the height and weight of growing children is relatively well known, rather limited information concerning the influences of the work environment on the physique of working children and adolescents is available. The purpose of this study was to increase our knowledge of the effects of mechanical stress on the human physique via somatotype during the adolescent growth period. Anthropometric measurements of 509 male apprentices aged 13.50-18.49 years and measurements of 451 nonworking youth (control group) of the same age group were taken. The members of both groups were from the lower socioeconomic strata and had similar living conditions. The apprentices were working an average of 11h per day in vocations requiring intense physical effort. The subjects were somatotyped using the Heath-Carter anthropometric protocol. The overall mean somatotypes were 2.3-4.4-3.3 for working adolescents, and 2.5-3.9-3.6 for the nonworking controls. A one-way multivariate analysis of variance (MANOVA) indicated significant differences between the groups. Working adolescents were more mesomorphic and less ectomorphic than their nonworking peers. In both groups, endomorphy decreased with age up to age 15; then remained stable for the labourers but increased for the nonworking peers. In both groups, mesomorphy was stable, but decreased with ectomorphy. These results indicate that physical stress not only causes retardation in linear growth, but also produces changes in human physique during the growth period.

Body size and physique among Canadians of First Nation and European ancestry.

PubMed

Katzmarzyk, P T; Malina, R M

1999-02-01

The purpose of this study was to compare body size and physique among Canadians of Aboriginal (First Nation [FN]) and European ancestry (EA) from the northern Ontario communities of Temagami and Bear Island. The sample consisted of 130 FN and 494 EA participants including adults (20-75 years: 214 men, 234 women) and youth (5-19 years: 97 boys, 79 girls). Indicators of body size and physique included stature, the sitting height-to-stature ratio (SSR), body mass, BMI, estimated upper-arm muscle area, biacromial, bicristal, biepicondylar, and bicondylar breadths, and the Heath-Carter anthropometric somatotype (endomorphy, mesomorphy, and ectomorphy). There were few differences in body size between FN and EA, with the exception of adult females. Adult FN females were significantly heavier and had greater bone breadths than EA women (P < 0.001). On the other hand, somatotype differed significantly between EA and FN by age and sex, except for 5-19-year-old females. Among boys and men, FN had greater endomorphy (P < 0.03), whereas FN men also had lower ectomorphy (P < 0.01). Among women, FN were significantly more endomorphic and mesomorphic and less ectomorphic (P < 0.001). Although results for 5-19-year-old females were not significant, they were in the same direction as the other groups (greater endomorphy). Forward stepwise discriminant function analyses indicated that endomorphy was the most important discriminator between FN and EA by age and sex.

Evulvalution: the portrayal of women's external genitalia and physique across time and the current barbie doll ideals.

PubMed

Schick, Vanessa R; Rima, Brandi N; Calabrese, Sarah K

2011-01-01

Media images of the female body commonly represent reigning appearance ideals of the era in which they are published. To date, limited documentation of the genital appearance ideals in mainstream media exists. Analysis 1 sought to describe genital appearance ideals (i.e., mons pubis and labia majora visibility, labia minora size and color, and pubic hair style) and general physique ideals (i.e., hip, waist, and bust size, height, weight, and body mass index [BMI]) across time based on 647 Playboy Magazine centerfolds published between 1953 and 2007. Analysis 2 focused exclusively on the genital appearance ideals embodied by models in 185 Playboy photographs published between 2007 and 2008. Taken together, results suggest the perpetuation of a "Barbie Doll" ideal characterized by a low BMI, narrow hips, a prominent bust, and hairless, undefined genitalia resembling those of a prepubescent female.

Physical appearance concerns are uniquely associated with the severity of steroid dependence and depression in anabolic-androgenic steroid users.

PubMed

Griffiths, Scott; Jacka, Brendan; Degenhardt, Louisa; Murray, Stuart B; Larance, Briony

2018-02-27

Emerging research suggests that the sub-population of anabolic-androgenic steroid (AAS) users who experience physical appearance concerns may suffer greater psychological dysfunction than other sub-populations, including users with athletic or occupational concerns. Thus, among current AAS users, we sought to determine whether, and to what extent, social physique anxiety-an established measure of appearance concern-was associated with psychological dysfunction. Interviews were conducted with a sample of 74 male AAS users living in Australia. Users completed self-report instruments of the severity of AAS dependence, depression, hazardous and risky drinking, use of non-AAS illicit drugs, psychological side-effects due to AAS use and abnormal test results due to AAS use. Multivariate analyses revealed that greater social physique anxiety was uniquely associated with more severe symptoms of both AAS dependence and depression. Moreover, the effect size of these relationships was large. Social physique anxiety was not associated with hazardous or risky drinking, non-AAS illicit drug use, psychological side-effects or abnormal test results. Limitations notwithstanding, the study is consistent with the notion that AAS users who experience appearance concerns are at heightened risk of co-morbid psychological dysfunction. Given trends indicating an increase in the prevalence of AAS use in Australia and elsewhere, the findings suggest that health-care systems may need to consider prioritising the sub-population of AAS users who experience appearance concerns. Further investigation of the clinical syndrome of AAS dependence is required, including its relation to body image and eating disorders. © 2018 Australasian Professional Society on Alcohol and other Drugs.

Colloquium P.G.de Gennes

ScienceCinema

None

2018-05-18

Lecture from Professor Pierre Gilles from Gennes, who received the Nobel Prize for Physics in 1991, became a professor at the Collège de France in 1971, director of the Ecole de Physique et Chimie (School of Physics and Chemistry) in Paris, etc.

Individual variability in the core interthreshold zone as related to body physique, somatotype, and physical constitution.

PubMed

Kakitsuba, Naoshi; Mekjavic, Igor B; Katsuura, Tetsuo

2009-11-01

For evaluating the effect of body physique, somatotype, and physical constitution on individual variability in the core interthreshold zone (CIZ), data from 22 healthy young Japanese male subjects were examined. The experiment was carried out in a climatic chamber in which air temperature was maintained at 20-24 degrees C. The subjects' body physique and the maximum work load were measured. Somatotype was predicted from the Heath-Carter Somatotype method. In addition, factors reflecting physical constitution, for example, susceptibility to heat and cold, and quality of sleep were obtained by questionnaire. The subjects wore a water-perfused suit which was perfused with water at a temperature of 25 degrees C and at a rate of 600 cc/min, and exercised on an ergometer at 50% of their maximum work rate for 10-15 min until their sweating rate increased. They then remained continuously seated without exercise until shivering increased. Rectal temperature (T(re)) and skin temperatures at four sites were monitored by thermistors, and sweating rate was measured at the forehead with a sweat rate monitor. Oxygen uptake was monitored with a gas analyzer. The results showed individual variability in the CIZ. According to the reciprocal cross-inhibition (RCI) theory, thermoafferent information from peripheral and core sensors is activated by T(re), mean skin temperature (T(sk)), and their changes. Since T(sk) was relatively unchanged, the data were selected to eliminate the influence of the core cooling rate on the sensor-to-effector pathway before RCI, and the relationship between the CIZ and the various factors was then analyzed. The results revealed that susceptibility to heat showed a good correlation with the CIZ, indicating that individual awareness of heat may change the CIZ due to thermoregulatory behavior.

Eating attitudes, self-esteem and social physique anxiety among Iranian females who participate in fitness programs.

PubMed

Gargari, B P; Khadem-Haghighian, M; Taklifi, E; Hamed-Behzad, M; Shahraki, M

2010-03-01

Today, women's participation in sports has substantially increased. This growth has been accompanied by concerns about health risks, as eating disorders, and psychological features, as self-esteem (SE) and social physique anxiety (SPA). The purpose of this study was to determine disordered eating attitudes and their relation to SE, SPA, as well as body weight, and body mass index (BMI), in Iranian females who participate in fitness programs. Subjects were 250 females, aged 14-51 years, who participated in fitness programs. Eating attitude test-26 (EAT-26), Rosenberg's self esteem scale (RSES), and social physique anxiety scale (SPAS), were used. Body weight and height were measured, and then Body Mass Index (BMI) was calculated. According to BMI cut-offs, 36% of subjects were overweight or obese. 28.4% and 19.6% of subjects were disordered eating attitudes (EAT-26>or=20) and low self-esteem (RSES<15), respectively. Disordered eating attitude subjects had lower SE and higher SPA, body weight and BMI than normal subjects (P<0.05). The low SE group had higher SPAS than normal one (P<0.02). In bivariate analysis, EAT-26 score was correlated negatively with RSES (r=-0.13, P<0.04) and positively with body weight, BMI, and SPAS (r=0.40, 0.42, and 0.47, respectively, P<0.001). SPAS had positive correlation with body weight and BMI (r=0.22, 0.19, It can be concluded that disordered eating attitudes are prevalent among Iranian females who participate in fitness programs. In this group, high SPA, body weight and BMI, and low SE accompany disordered eating attitudes.

Fluid dynamics alter Caenorhabditis elegans body length via TGF-β/DBL-1 neuromuscular signaling

PubMed Central

Harada, Shunsuke; Hashizume, Toko; Nemoto, Kanako; Shao, Zhenhua; Higashitani, Nahoko; Etheridge, Timothy; Szewczyk, Nathaniel J; Fukui, Keiji; Higashibata, Akira; Higashitani, Atsushi

2016-01-01

Skeletal muscle wasting is a major obstacle for long-term space exploration. Similar to astronauts, the nematode Caenorhabditis elegans displays negative muscular and physical effects when in microgravity in space. It remains unclear what signaling molecules and behavior(s) cause these negative alterations. Here we studied key signaling molecules involved in alterations of C. elegans physique in response to fluid dynamics in ground-based experiments. Placing worms in space on a 1G accelerator increased a myosin heavy chain, myo-3, and a transforming growth factor-β (TGF-β), dbl-1, gene expression. These changes also occurred when the fluid dynamic parameters viscosity/drag resistance or depth of liquid culture were increased on the ground. In addition, body length increased in wild type and body wall cuticle collagen mutants, rol-6 and dpy-5, grown in liquid culture. In contrast, body length did not increase in TGF-β, dbl-1, or downstream signaling pathway, sma-4/Smad, mutants. Similarly, a D1-like dopamine receptor, DOP-4, and a mechanosensory channel, UNC-8, were required for increased dbl-1 expression and altered physique in liquid culture. As C. elegans contraction rates are much higher when swimming in liquid than when crawling on an agar surface, we also examined the relationship between body length enhancement and rate of contraction. Mutants with significantly reduced contraction rates were typically smaller. However, in dop-4, dbl-1, and sma-4 mutants, contraction rates still increased in liquid. These results suggest that neuromuscular signaling via TGF-β/DBL-1 acts to alter body physique in response to environmental conditions including fluid dynamics. PMID:28725724

Epidemiological investigation of physique situation for birth high-risk children aged 9-15 years in Chengdu, Southwest China.

PubMed

Xiong, F; Yang, F; Huo, T Z; Li, P; Mao, M

2014-01-01

As the intrauterine environment can effect children's growth and development, this study aimed to explore the relationship between birth high-risk and physique situation of 9 to 15-year-old children by cross-sectional investigation, and to provide clues for the monitoring, prevention, and treatment of growth deviation in children. This study recruited 7,194 students aged 9 to 15 years in primary and junior schools. Their parents were asked to complete the birth situation questionnaire. Measurements included height, weight, and body mass index (BMI). Birth high-risk infant was defined according to the gestational age and birth weight. Growth deviation was classified as underweight, short stature, overweight, and obesity. The prevalence of all kinds of growth deviations in preterm, full-term, and post-term birth groups were similar, the same as the physique situation at school age among both sexes. The incidence of small for gestational age (SGA) was 6.23%, when at school age, part of SGA had catch-up growth. However, the prevalence of underweight and short stature for SGA was highest in three groups. The weight and height at school age in SGA group was less than that in appropriate for gestational age (AGA) and large for gestational age (LGA) groups. The prevalence of overweight and obesity for LGA and macrosomia were highest in three groups. At school age, the weight in macrosomia and LGA groups was higher than that in the other groups. Longitudinal height and weight development and growth of children with birth high-risk are different from normal children. In order to improve healthy situation, more attention should be paid to height and weight development of those children with birth high-risk at school age, even in pre-school age. Prevention may already begin during pregnancy.

Soins primaires aux adultes ayant une déficience développementale

PubMed Central

Sullivan, William F.; Berg, Joseph M.; Bradley, Elspeth; Cheetham, Tom; Denton, Richard; Heng, John; Hennen, Brian; Joyce, David; Kelly, Maureen; Korossy, Marika; Lunsky, Yona; McMillan, Shirley

2011-01-01

Résumé Objectif Mettre à jour les lignes directrices canadiennes de 2006 sur les soins primaires aux adultes ayant une déficience développementale (DD) et présenter des recommandations pratiques fondées sur les connaissances actuelles pour traiter des problèmes de santé particuliers chez des adultes ayant une DD. Qualité des preuves Des professionnels de la santé expérimentés participant à un colloque et un groupe de travail subséquent ont discuté et convenu des révisions aux lignes directrices de 2006 en se fondant sur une recherche documentaire exhaustive, la rétroaction obtenue des utilisateurs du guide de pratique et les expériences cliniques personnelles. La plupart des preuves disponibles dans ce domaine viennent de l’opinion d’experts ou de déclarations consensuelles publiées (niveau III). Message principal Les adultes ayant une DD ont des problèmes de santé complexes, dont plusieurs diffèrent de ceux de la population en général. De bons soins primaires permettent d’identifier les problèmes de santé particuliers dont souffrent les adultes ayant une DD pour améliorer leur qualité de vie et leur accès aux soins de santé et prévenir la morbidité et le décès prématuré. Ces lignes directrices résument les problèmes de santé générale, physique, comportementale et mentale des adultes ayant une DD que devraient connaître les professionnels des soins primaires et présentent des recommandations pour le dépistage et la prise en charge en se basant sur les connaissances actuelles que les cliniciens peuvent mettre en pratique. En raison de l’interaction des facteurs biologiques, psychoaffectifs et sociaux qui contribuent à la santé et au bien-être des adultes ayant une DD, ces lignes directrices insistent sur la participation des aidants, l’adaptation des interventions, au besoin, et la consultation auprès de divers professionnels de la santé quand ils sont accessibles. Elles mettent aussi en évidence la nature éthique des soins. Les lignes directrices sont formulées dans le contexte d’un cadre éthique qui tient compte des questions comme le consentement éclairé et l’évaluation des bienfaits pour la santé par rapport aux risques de préjudice. Conclusion La mise en œuvre des lignes directrices proposées ici améliorerait la santé des adultes ayant une DD et minimiserait les disparités sur les plans de la santé et des soins de santé entre les adultes ayant une DD et la population en général.

Effects of Age and Sex on the Development of Personal Space Schemata Towards Body Build

ERIC Educational Resources Information Center

Lerner, Richard M.; And Others

1975-01-01

This study assessed personal space schemata of children towards stimulus figures representing male and female body build stereotypes. Greater spatial distances were used towards the Endomorph than other physique types and significant sex differences were found. (GO)

The obesity penalty in the labor market using longitudinal Canadian data.

PubMed

Chu, Filmer; Ohinmaa, Arto

2016-12-01

A Canadian study of weight discrimination also known as the obesity wage-penalty. This paper adds to the limited Canadian literature while also introducing a causal model, which can be applied to future Canadian studies. A general working-class sample group is utilized with personal income, which removes many biases introduced in other studies. The evidence suggests that a 1-unit increase in lagged BMI is associated with a 0.7% decrease in personal for obese Canadian females. Similar to other studies, the male results are inconsistent. The evidence brought forward in this study can provide an effective financial incentive for health promotion among Canadians for law and policy makers. Beyond health reasons, these results can also be applied as empirical evidence of gender discrimination based on body image perception. The evidence suggests that male physique is not a contributing factor in income, but larger female physique is associated with lower personal income. Copyright © 2016 Elsevier B.V. All rights reserved.

Variability in body size and shape of UK offshore workers: A cluster analysis approach.

PubMed

Stewart, Arthur; Ledingham, Robert; Williams, Hector

2017-01-01

Male UK offshore workers have enlarged dimensions compared with UK norms and knowledge of specific sizes and shapes typifying their physiques will assist a range of functions related to health and ergonomics. A representative sample of the UK offshore workforce (n = 588) underwent 3D photonic scanning, from which 19 extracted dimensional measures were used in k-means cluster analysis to characterise physique groups. Of the 11 resulting clusters four somatotype groups were expressed: one cluster was muscular and lean, four had greater muscularity than adiposity, three had equal adiposity and muscularity and three had greater adiposity than muscularity. Some clusters appeared constitutionally similar to others, differing only in absolute size. These cluster centroids represent an evidence-base for future designs in apparel and other applications where body size and proportions affect functional performance. They also constitute phenotypic evidence providing insight into the 'offshore culture' which may underpin the enlarged dimensions of offshore workers. Copyright © 2016 Elsevier Ltd. All rights reserved.

Self-compassion: a potential resource for young women athletes.

PubMed

Mosewich, Amber D; Kowalski, Kent C; Sabiston, Catherine M; Sedgwick, Whitney A; Tracy, Jessica L

2011-02-01

Self-compassion has demonstrated many psychological benefits (Neff, 2009). In an effort to explore self-compassion as a potential resource for young women athletes, we explored relations among self-compassion, proneness to self-conscious emotions (i.e., shame, guilt-free shame, guilt, shame-free guilt, authentic pride, and hubristic pride), and potentially unhealthy self-evaluative thoughts and behaviors (i.e., social physique anxiety, obligatory exercise, objectified body consciousness, fear of failure, and fear of negative evaluation). Young women athletes (N = 151; Mage = 15.1 years) participated in this study. Self-compassion was negatively related to shame proneness, guilt-free shame proneness, social physique anxiety, objectified body consciousness, fear of failure, and fear of negative evaluation. In support of theoretical propositions, self-compassion explained variance beyond self-esteem on shame proneness, guilt-free shame proneness, shame-free guilt proneness, objectified body consciousness, fear of failure, and fear of negative evaluation. Results suggest that, in addition to self-esteem promotion, self-compassion development may be beneficial in cultivating positive sport experiences for young women.

Marked for life? A prospective study of tattoos on appearance anxiety and dissatisfaction, perceptions of uniqueness, and self-esteem.

PubMed

Swami, Viren

2011-06-01

Previous studies on psychosocial aspects of tattooing have not examined prospective changes in self- and body-related attitudes as a result of obtaining a tattoo. In the present study, 82 British residents obtaining their first tattoo completed measures of state appearance anxiety and dissatisfaction prior to, and immediately after, obtaining a tattoo. They also completed measures of trait body appreciation, distinctive appearance investment, self-ascribed uniqueness, social physique anxiety, and self-esteem before obtaining a tattoo and three weeks later. Results showed that both women and men had significantly lower appearance anxiety and dissatisfaction immediately after obtaining their tattoo, and significantly higher body appreciation, distinctive appearance investment, self-ascribed uniqueness, and self-esteem after three weeks. Women reported greater social physique anxiety after three weeks, whereas men reported lower anxiety. These results are discussed in relation to the positive impacts of obtaining body art and the mainstreaming of tattooing in Western societies. Copyright © 2011 Elsevier Ltd. All rights reserved.

Nutrition for winter sports.

PubMed

Meyer, Nanna L; Manore, Melinda M; Helle, Christine

2011-01-01

Winter sports are played in cold conditions on ice or snow and often at moderate to high altitude. The most important nutritional challenges for winter sport athletes exposed to environmental extremes include increased energy expenditure, accelerated muscle and liver glycogen utilization, exacerbated fluid loss, and increased iron turnover. Winter sports, however, vary greatly regarding their nutritional requirements due to variable physiological and physique characteristics, energy and substrate demands, and environmental training and competition conditions. What most winter sport athletes have in common is a relatively lean physique and high-intensity training periods, thus they require greater energy and nutrient intakes, along with adequate food and fluid before, during, and after training. Event fuelling is most challenging for cross-country skiers competing in long events, ski jumpers aiming to reduce their body weight, and those winter sport athletes incurring repeated qualification rounds and heats. These athletes need to ensure carbohydrate availability throughout competition. Finally, winter sport athletes may benefit from dietary and sport supplements; however, attention should be paid to safety and efficacy if supplementation is considered.

Reticulation des fibres lignocellulosiques

NASA Astrophysics Data System (ADS)

Landrevy, Christel

Pour faire face à la crise économique la conception de papier à valeur ajoutée est développée par les industries papetières. Le but de se projet est l'amélioration des techniques actuelles de réticulation des fibres lignocellulosiques de la pâte à papier visant à produire un papier plus résistant. En effet, lors des réactions de réticulation traditionnelles, de nombreuses liaisons intra-fibres se forment ce qui affecte négativement l'amélioration anticipée des propriétés physiques du papier ou du matériau produit. Pour éviter la formation de ces liaisons intra-fibres, un greffage sur les fibres de groupements ne pouvant pas réagir entre eux est nécessaire. La réticulation des fibres par une réaction de « click chemistry » appelée cycloaddition de Huisgen entre un azide et un alcyne vrai, catalysée par du cuivre (CuAAC) a été l'une des solutions trouvée pour remédier à ce problème. De plus, une adaptation de cette réaction en milieux aqueux pourrait favoriser son utilisation en milieu industriel. L'étude que nous désirons entreprendre lors de ce projet vise à optimiser la réaction de CuAAC et les réactions intermédiaires (propargylation, tosylation et azidation) sur la pâte kraft, en milieu aqueux. Pour cela, les réactions ont été adaptées en milieu aqueux sur la cellulose microcristalline afin de vérifier sa faisabilité, puis transférée à la pâte kraft et l'influence de différents paramètres comme le temps de réaction ou la quantité de réactifs utilisée a été étudiée. Dans un second temps, une étude des différentes propriétés conférées au papier par les réactions a été réalisée à partir d'une série de tests papetiers optiques et physiques. Mots Clés Click chemistry, Huisgen, CuAAC, propargylation, tosylation, azidation, cellulose, pâte kraft, milieu aqueux, papier.

Calendar of Selected Aeronautical and Space Meetings (Calendrier des Manifestations Aeronautiques et Spatiales (Selection)).

DTIC Science & Technology

1983-07-01

Structures, Matiriaux et Micanique appliquie 51 08 - Physique de l’Atmosphire et Environnement terrestre 70 09 - Information, Documentation et...78712 US VDE Verband Deutscher Elektrotechniker: Zentralstelle Tagungen, Stresemannallee 21, D-6000 Frankfurt am Main 70 GE WEC World Energy Conference

A Psychometric Evaluation of the Self-Presentational Efficacy Scale

ERIC Educational Resources Information Center

Lamarche, Larkin; Gammage, Kimberley L.; Sullivan, Philip J.; Gabriel, David A.

2013-01-01

This study examined the psychometric properties of the Self-Presentational Efficacy Scale (SPES) developed by Gammage, Hall, and Martin Ginis (2004). University students (196 men and 269 women) completed the SPES and measures of social physique anxiety, fear of negative evaluation, and physical activity. Participants also completed the SPES a…

Stalking the Feast Beast.

ERIC Educational Resources Information Center

Trimpey, Lois

This paper discusses the use of Rational Recovery (RR) as a counseling technique in treating people who feel fat, particularly women. Fatness is viewed as a philosophy, not a physical condition. Cultural influences defining and stressing ideal femininity come down hard on women whose physiques or appearances do not measure up. RR gives people…

Puberty and Physical Self-Perceptions of Competitive Female Figure Skaters: An Interdisciplinary Approach

ERIC Educational Resources Information Center

Monsma, Eva V.; Malina, Robert M.; Feltz, Deborah L.

2006-01-01

This study considered the interrelationships among biological maturation and its physical correlates, social physique anxiety, and appearance-related physical self-perceptions in 113 adolescent female figure skaters participating in solo (n = 73) or partner contexts (n = 40). Participants were interviewed about their menarcheal status, underwent a…

Solar Power

ScienceCinema

None

2017-12-09

Le Prof. Broda, Prof. de Biochimie, Physique et Radiochimie à l'Université de Vienne, ville où il est né et où il a étudié, fait une brillante carrière accadémique et nous parle de l'énergie solaire.

Teenage Nutrition and Physique.

ERIC Educational Resources Information Center

Huenemann, Ruth L.; And Others

Body size, composition, and conformation in a teen-age population, and associated factors were studied to obtain useful data for planning programs in public health nutrition. This book describes the purpose, methods, and findings of this four-year longitudinal and cross-sectional study conducted in Berkeley, California, during the years 1961 to…

Literacy Is More than Books and Pens

ERIC Educational Resources Information Center

Roseboro, Anna J. Small

2012-01-01

Like parents, educators should prepare their students to do without them. To achieve this they must understand two concepts they hear about in the world of education: multiple intelligences and media literacy. Research on ways people learn and demonstrate knowledge shows that both are as diverse as the physiques of the students. Some of them learn…

Eating Attitudes and Their Psychological Correlates among Turkish Adolescents

ERIC Educational Resources Information Center

Bas, Murat; Asci, F. Hulya; Karabudak, Efsun; Kiziltan, Gul

2004-01-01

This study examined the eating attitudes and psychological characteristics of Turkish late adolescents. Seven hundred eighty-three university students were administered the Eating Attitudes Test, Rosenberg Self-Esteem Scale, State-Trait Anxiety Inventory, and Social Physique Anxiety Scale. More than one in ten (9.2% of the males and 13.1% of the…

Using Computer-Generated Random Numbers to Calculate the Lifetime of a Comet.

ERIC Educational Resources Information Center

Danesh, Iraj

1991-01-01

An educational technique to calculate the lifetime of a comet using software-generated random numbers is introduced to undergraduate physiques and astronomy students. Discussed are the generation and eligibility of the required random numbers, background literature related to the problem, and the solution to the problem using random numbers.…

Contributions and Implications of the Medford, Oregon, Boys' Growth Study.

ERIC Educational Resources Information Center

Clarke, H. H.

The overall and long-range purposes of the Medford Boys' Growth Study are: (1) to construct physical and motor growth curves and growth acceleration curves of boys seven to 18 years old; (2) to relate these traits to physiological maturity, physique type, nutritional status, socio-personal adjustment, interests, and scholastic aptitude and…

Free Space Optics Communication for Mobile Military Platforms

DTIC Science & Technology

2003-12-01

Federal Communications Commission FDA Food and Drug Administration FOV Field-of-View FSO Free Space Optics FWHM Full Width at Half Maximum Gbps...Physique et de Métrologie des Oscillateurs (LPMO) du CNRS UPR3203, associé à l’Université de Franche -Comté, 15 March 2002 [Schenk 2000] H. Schenk

L'education physique en Suisse Histoire et situation actuelle.

ERIC Educational Resources Information Center

Burgener, Louis

The document presents major aspects of the historical development and current situation of physical education in Switzerland. The study is designed as a manual for education students; as a reference book for educators, youth federations, sports associations, and the press; and as a volume to acquaint foreign readers with particular aspects of the…

The new role of scientists

ScienceCinema

None

2017-12-09

Le D.G. Jentschke fait l'introduction et présente le Prof.Kowarsky, spécialiste en microbiologie, physique nucléaire et une des fondateurs du Cern. Il parle entre autre de l'énergie nucléaire (pacifique)et de remise en questions des valeurs scientifiques et techniques

Calendar of Selected Aeronautical and Space Meetings (Calendrier des Manifestations Aeronautiques et Spatiales (Selection))

DTIC Science & Technology

1989-01-01

Structurces, Matdriaux et MWcanique appliqu&c 53 08 - Physique de U’Atmosph~re et Environnement terrestre 73 09 -Information, Documentation et Informatique 77...CO 80840 US UTIIS University of Tokyo Institute of Industrial Science: 7-22-1 Roppongi, Minato-ku, Tokyo 106 JA VDE Verband Deutscher

Calendar of Selected Aeronautical and Space Meetings, July 1989 (Calendrier des Manifestations Aeronautiques et Spatiales (Selection), Juillet 1989)

DTIC Science & Technology

1989-07-01

Matdriaux et Mcanique appliqude 56 08 - Physique de l’Atmosph6re et Environnement terrestre 76 09 - Information, Documentation et Informatique 82 10...S 917, 12201 Sunrise Valley Drive, Reston, VA 22092 US VDE Verband Deutscher Elektrotechniker: Zentralstelle Tagungen, Stresemannallee 15, D-6000

Calendar of Selected Aeronautical and Space Meetings (Calendrier des Manifestations Aeronautiques et Spatiales (Selection). Juillet-July 1984.

DTIC Science & Technology

1984-06-01

Structures, Mat~riaux et M~canique appliquce 47 08 - Physique de l’Atmnosph~re et Environnement terrestre 62 09 - Information, Documentation et...University Institute of Technology: Box 534,75121 Uppsala SW UW University of Wisconsin: Madison, WI 53706 US VDE Verbend Deutacher Elektroteclker

Nitramine Propellant Ignition and Combustion Research: New Tools and New Directions

DTIC Science & Technology

1989-02-01

promising innovation for the application of laser diagnostics to combustion studies is the use of planar imaging techniques. 13 This allows the...A.M. and Trott , W.M., J. de Physique 48, Colloq. C4, 179-188 (1987) 96. Fontijin, A., Ed. "Gas-Phase Chemiluminescence and Chemi-lonization," North

Stress habituation and alterations in perceived stress predict BMI percentile changes across a school year

USDA-ARS?s Scientific Manuscript database

Adolescents experience stressful situations at a high rate during school. Indeed, school is the most common source of stress for teens. This high rate of stress may promote increases in adiposity during a developmental period important for establishing the adult physique. Adiposity gains may be th...

Illustrating the body: Cross-sectional and prospective investigations of the impact of life drawing sessions on body image.

PubMed

Swami, Viren

2016-01-30

Life drawing sessions, where individuals produce drawings of the human figure from observations of a live model, may contain embodying elements that promote healthier body image. Two pilot studies were conducted to test this hypothesis. In Study 1, 138 individuals recruited from life drawing sessions in London, UK, estimated how many sessions they had attended in their lifetime and completed measures of negative and positive body image. In women, greater attendance was significantly associated with higher body appreciation and lower drive for thinness and social physique anxiety. In men, greater attendance was significantly associated with higher body appreciation, but not drive for muscularity or social physique anxiety. In Study 2, 37 women took part in a life drawing session for the first time. Compared to pre-session scores, participants had significantly more positive state body image and appearance satisfaction after the session. The findings of these studies suggest that life drawing may promote healthier body image, particularly among women, but further research is needed. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

Vibrations et relaxations dans les molécules biologiques. Apports de la diffusion incohérente inélastique de neutrons

NASA Astrophysics Data System (ADS)

Zanotti, J.-M.

2005-11-01

Le présent document ne se veut pas un article de revue mais plutôt un élément d'initiation à une technique encore marginale en Biologie. Le lecteur est supposé être un non spécialiste de la diffusion de neutrons poursuivant une thématique à connotation biologique ou biophysique mettant en jeu des phénomènes dynamiques. En raison de la forte section de diffusion incohérente de l'atome d'hydrogène et de l'abondance de cet élément dans les protéines, la diffusion incohérente inélastique de neutrons est une technique irremplaçable pour sonder la dynamique interne des macromolécules biologiques. Après un rappel succinct des éléments théoriques de base, nous décrivons le fonctionnement de différents types de spectromètres inélastiques par temps de vol sur source continue ou pulsée et discutons leurs mérites respectifs. Les deux alternatives utilisées pour décrire la dynamique des protéines sont abordées: (i)l'une en termes de physique statistique, issue de la physique des verres, (ii) la seconde est une interprétation mécanistique. Nous montrons dans ce cas, comment mettre à profit les complémentarités de domaines en vecteur de diffusion et de résolution en énergie de différents spectromètres inélastiques de neutrons (temps de vol, backscattering et spin-écho) pour accéder, à l'aide d'un modèle physique simple, à la dynamique des protéines sur une échelle de temps allant d'une fraction de picoseconde à quelques nanosecondes.

Fluctuations quantiques et instabilites structurales dans les conducteurs a basse dimensionalite

NASA Astrophysics Data System (ADS)

Dikande, Alain Moise

Un engouement particulier s'est manifeste ces dernieres annees pour les systemes electroniques fortement correles, ce en rapport avec l'immense richesse de leurs proprietes physiques. En general, ces proprietes sont induites par la presence d'interactions entre electrons qui, combinees a la structure du reseau moleculaire, donnent parfois lieu a une tres grande variete de phases electroniques et structurales ayant des incidences directes sur les phenomenes de transport dans ces materiaux. Les systemes electroniques couples a un reseau moleculaire et designes systemes electron-phonon font partie de cette classe de materiaux qui ont recemment capte l'attention, en raison notamment de la competition entre plusieurs echelles d'energie dans un environnement caracterise par une forte anisotropie cristalline et une dynamique moleculaire assez importante. En effet, en plus des proprietes electroniques et structurales particulieres la dimensionalite de ces systemes contribue egalement a leur richesse. Ainsi, une tres forte anisotropie structurale peut rehausser de facon considerable l'importance des interactions entre electrons et entre molecules constituant le reseau au point ou la physique du systeme soit regie par de tres fortes fluctuations. Ce dernier contexte est devenu un domaine a part de la physique des systemes fortement correles, a savoir celui des les phenomenes critiques quantiques . Parmi les systemes electron-phonon, on retrouve les composes inorganique KCP et organique TTF-TCNQ decouverts durant les annees 70, et explores en profondeur a cause de leur tendance vers une instabilite du type onde de densite de charge a basse temperature. Ces composes, en general designes systemes de Peierls en reference a l'instabilite de leurs structures electroniques regie par le reseau moleculaire, ont recemment connu un regain d'interet a la lumiere des nouveaux developpements dans les techniques de caracterisation des structures electroniques ainsi que sur le plan de concepts tel le Liquide de Luttinger, propres aux systemes electroniques a une dimension. (Abstract shortened by UMI.)

All-Manganite Tunnel Junctions with Interface-Induced Barrier Magnetism

NASA Astrophysics Data System (ADS)

Sefrioui, Zouhair

2011-03-01

The recent discovery of several unexpected phases at complex oxide interfaces is providing new insights into the physics of strongly correlated electron systems. The possibility of tailoring the electronic structure of such interfaces has triggered a great technological drive to functionalize them into devices. In this communication, we describe an alternative strategy to produce spin filtering by inducing a ferromagnetic insulating state in an ultrathin antiferromagnetic layer in contact with a ferromagnetic layer. This artificially induced spin filtering persists up to relatively high temperatures and operates at high applied bias voltages. The results suggest that after playing a key role in exchange-bias for spin-valves, uncompensated moments at engineered antiferromagnetic interfaces represent a novel route for generating highly spin-polarized currents with antiferromagnets. Work done in collaboration with M. Bibes, C. Carrétéro, A. Barthélémy (Unité Mixte de Physique CNRS/Thales, Campus de Polytechnique, 1, Avenue A. Fresnel, 91767 Palaiseau (France) and Université Paris-Sud, 91045 Orsay (France)), F.A. Cuellar, C. Visani, A. Rivera-Calzada, , C. León, J. Santamaria (Grupo de Física de Materiales Complejos, Universidad Complutense de Madrid, 28040 Madrid (Spain)), M.J. Calderón, L. Brey (Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, 28049 Madrid (Spain)), K. March, M. Walls, D. Imhoff (Laboratoire de Physique des Solides, CNRS, Université Paris-Sud, 91405 Orsay (France)), R. Lopez Anton, T.R. Charlton (ISIS, Rutherford Appleton Laboratory, Chilton, Oxon OX11 0QX (United Kingdom)), E. Iborra (Universidad Politécnica de Madrid, Escuela Técnica Superior de Ingenieros de Telecomunicaciones, 28040 Madrid (Spain)), F. Ott (Léon Brillouin, CEA/CNRS, UMR 12, 91191 Gif-sur-Yvette (France)). This work was supported by the Spanish Ministry for Science and Education programs MAT2008 06517, and the Réseau Thématique de Recherche Avancée (RTRA) ``Triangle de la Physique.''

Effects of High vs. Low Protein Intake on Body Composition and Maximal Strength in Aspiring Female Physique Athletes Engaging in an 8-Week Resistance Training Program.

PubMed

Campbell, Bill I; Aguilar, Danielle; Conlin, Laurin; Vargas, Andres; Schoenfeld, Brad Jon; Corson, Amey; Gai, Chris; Best, Shiva; Galvan, Elfego; Couvillion, Kaylee

2018-02-06

Aspiring female physique athletes are often encouraged to ingest relatively high levels of dietary protein in conjunction with their resistance-training programs. However, there is little to no research investigating higher vs. lower protein intakes in this population. This study examined the influence of a high vs. low protein diet in conjunction with an 8-week resistance training program in this population. Seventeen females (21.2±2.1 years; 165.1±5.1 cm; 61±6.1 kg) were randomly assigned to a high protein diet (HP: 2.5g/kg/day; n=8) or a low protein diet (LP: 0.9g/kg/day, n=9) and were assessed for body composition and maximal strength prior to and after the 8-week protein intake and exercise intervention. Fat-free mass (FFM) increased significantly more in the HP group as compared to the LP group (p=0.009), going from 47.1 ± 4.5kg to 49.2 ± 5.4kg (+2.1kg) and from 48.1 ± 2.7kg to 48.7 ± 2 (+0.6kg) in the HP and LP groups, respectively. Fat mass significantly decreased over time in the HP group (14.1 ± 3.6kg to 13.0 ± 3.3kg; p<0.01) but no change was observed in the LP group (13.2 ± 3.7kg to 12.5 ± 3.0kg). While maximal strength significantly increased in both groups, there were no differences in strength improvements between the two groups. In aspiring female physique athletes, a higher protein diet is superior to a lower protein diet in terms of increasing FFM in conjunction with a resistance training program.

Foreword

NASA Astrophysics Data System (ADS)

Derrida, Bernard; Gaspard, Pierre; Van den Broeck, Christian

2007-06-01

We introduce and present the proceedings of the conference "Work, dissipation, and fluctuations in nonequilibrium physics" held in Brussels, 22-25 March 2006 under the auspices of the International Solvay Institutes for Physics and Chemistry and organized by the Center for Nonlinear Phenomena and Complex Systems of the Université Libre de Bruxelles. To cite this article: B. Derrida et al., C. R. Physique 8 (2007).

Psychological Well-Being and Motivation in a Turkish Physical Education Context

ERIC Educational Resources Information Center

Erturan-Ilker, Gökçe

2014-01-01

Using Self Determination as a framework, the purpose of the study was to examine the relationships between basic psychological needs, motivational regulations, self-esteem, subjective vitality, and social physique anxiety in physical education. One thousand and eighty two high school students aged between 14 and 19 [mean (M) = 15.89 ± 0.95 years]…

The Education and Training of Physics Teachers Worldwide. A Survey.

ERIC Educational Resources Information Center

Davies, Brian, Ed.

The Group Internationale de Recherche sur l'Enseignment de la Physique (GIREP), known in English as The International Research Group on Physics Teaching, is an independent association for the improvement of physics teaching in schools and, to a lesser extent, at the interface between school and university. Provided in this three-part book is…

Body Image Concerns in College-Aged Male Physical Education Students: A Descriptive Inquiry

ERIC Educational Resources Information Center

Olson, Michele S.; Esco, Michael R.; Willifo, Hank

2009-01-01

The purpose of this study was to examine body image concerns in college-aged male physical education majors. Sixty volunteers completed validated body image instruments including two-dimensional figure drawings. In general, the sample reported that they preferred a larger, more muscular physique reflective of male images that currently abound the…

Constitutive Behavior and Modeling of Al-Cu Alloy Systems

DTIC Science & Technology

2013-05-01

Mechanical Threshold of Dynamically Deformed Copper and Nitronic 40 ." Journal de Physique, 1985: 25- 34. Gama, B. A., S. L. Lopatnikov, and J. W. G...38 3. MODIFIED ZERILLI-ARMSTRONG MODEL .................................... 40 3.1 Introduction... 40 3.2 Former Modifications to ZA Model by Zerilli and Armstrong .. 42 3.3 Modifications to ZA Model

An example of a chaotic micromixer: the cross-channel micromixer

NASA Astrophysics Data System (ADS)

Dodge, Arash; Jullien, Marie-Caroline; Lee, Yi-Kuen; Niu, X.; Okkels, Fridolin; Tabeling, Patrick

2004-06-01

In this article dedicated to micromixing, we concentrate here on a particular micromixer - the 'cross-channel micromixer'. This mixer exploits an oscillatory perturbation to induce chaotic trajectories, favoring mixing. We present here theory, numerical simulations and experiments performed on this system. To cite this article: A. Dodge et al., C. R. Physique 5 (2004).

Health and Physique of School Children. Bulletin, 1925, No. 21

ERIC Educational Resources Information Center

Rogers, James Frederick

1925-01-01

This bulletin reports on the changes and progress in practice and conditions in: (1) School Housing; (2) Playgrounds; (3) Medical inspection; (4) Dental work; (5) Nutrition; (6) Open-air schools and open-window rooms; (7) The summer camp; (8) Other special schools and classes; (9) Health education; (10) Physical training; (11) Safety and first…

Effect of Eight-Week Exercise Program on Social Physique Anxiety Conditions in Adult Males

ERIC Educational Resources Information Center

Akyüz, Öznur

2017-01-01

Physiological changes occurring with physical activity have played role in appearance of a different field of study. Thus, examination of the effect of eight-week exercise program on SPA in adult males forms the purpose of the study. 20 sedentary males aged 18-25 voluntarily participated in the research. Volunteers were applied resistance exercise…

Psychometric Validation of the Brief Adaptation to Disability Scale-Revised for Persons with Spinal Cord Injury in Taiwan

ERIC Educational Resources Information Center

Lin, Chen-Ping; Wang, Chia-Chiang; Fujikawa, Mayu; Brooks, Jessica; Eastvold-Walton, Lissa; Maxwell, Kristin; Chan, Fong

2013-01-01

Purpose: To examine the measurement structure of the Brief Adaptation to Disability Scale-Revised (B-ADS-R). Measure: A 12-item measure of disability acceptance based on the four value changes (enlarging the scope of values, containing the effects of the disability, subordinating the physique, and transforming comparative-status values to asset…

Low Temperature Quartz Crystal Oscillator Fast Warm-Up Saw Oscillator.

DTIC Science & Technology

1981-07-01

TASK_Q Centre National de la Recherche ScientifiqueARA&WKLI k Laboratoire de Physique et Metrologie des!2 Oscillateurs - 50 Bsnon-F 2 3 32 av. o l...propri6t6s non lin6aires des ondes Alastiques de sur- face : applications aux oscillateurs et aux capteurs A quartz", Thse Besanqon, 1979. (6) D. Hauden, G

Partager : des technologies de pointe au service de la société

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2011-02-14

Médecine, climatologie, métrologie et informatique, les techniques utilisées par le LHC trouvent déjà des répercussions dans d’autres domaines scientifiques. Utilisant des techniques inédites, la physique des particules en fait bénéficier la société toute entière.

Body physique and proportionality of Brazilian female artistic gymnasts.

PubMed

Bacciotti, Sarita; Baxter-Jones, Adam; Gaya, Adroaldo; Maia, José

2018-04-01

This study aimed to identify physique characteristics (anthropometry, somatotype, body proportionality) of Brazilian female artistic gymnasts, and to compare them across competitive levels (sub-elite versus non-elite) within competitive age-categories. Two hundred forty-nine female gymnasts (68 sub-elite; 181 non-elite) from 26 Brazilian gymnastics clubs, aged 9-20 years and split into four age-categories, were sampled. Gymnasts were assessed for 16 anthropometric traits (height, weight, lengths, widths, girths, and skinfolds); somatotype was determined according to Heath-Carter method, body fat was estimated by bioimpedance, and proportionality was computed based on the z-phantom strategy. Non-elite and sub-elite gymnasts had similar values in anthropometric characteristics, however non-elite had higher fat folds in all age-categories (P < 0.01). In general, mesomorphy was the salient somatotype component in all age-categories, and an increase in endomorphy, followed by a decrease in ectomorphy across age was observed. Regarding proportionality, profile similarity was found between sub-elite and non-elite within age-categories. In conclusion results suggest the presence of a typical gymnast's physical prototype across age and competitive level, which can be useful to coaches during their selection processes in clubs and regional/national teams.

Sex differences in relative foot length and perceived attractiveness of female feet: relationships among anthropometry, physique, and preference ratings.

PubMed

Voracek, Martin; Fisher, Maryanne L; Rupp, Barbara; Lucas, Deanna; Fessler, Daniel M T

2007-06-01

Foot size proportionate to stature is smaller in women than in men, and small feet apparently contribute to perceived physical attractiveness of females. This exploratory study investigated the sex difference in relative foot length and interrelations among foot length, physique, and foot preference ratings in samples from Austria and Canada, each comprised of 75 men and 75 women. The findings included the following lines of evidence: the sex difference in relative foot length replicated in both data sets; the magnitude of this sex effect was large. Relative foot length was smaller in young, nulliparous, and slim women. Pointed-toe and high-heel shoes were more likely worn by smaller, lighter, and slimmer women. Men reported liking women's feet in general more than vice versa. A vast majority of both men and women favored small feet in women, but large feet in men. One's own foot size appeared to correspond to evaluations of attractiveness; particularly, women with small feet preferred small feet in women in general. The preference for small feet in women was convergent across different methods of evaluating attractiveness. Directions for investigations in this emerging field of research on physical attractiveness are discussed.

Etude vibroacoustique d'un systeme coque-plancher-cavite avec application a un fuselage simplifie

NASA Astrophysics Data System (ADS)

Missaoui, Jemai

L'objectif de ce travail est de developper des modeles semi-analytiques pour etudier le comportement structural, acoustique et vibro-acoustique d'un systeme coque-plancher-cavite. La connection entre la coque et le plancher est assuree en utilisant le concept de rigidite artificielle. Ce concept de modelisation flexible facilite le choix des fonctions de decomposition du mouvement de chaque sous-structure. Les resultats issus de cette etude vont permettre la comprehension des phenomenes physiques de base rencontres dans une structure d'avion. Une approche integro-modale est developpee pour calculer les caracteristiques modales acoustiques. Elle utilise une discretisation de la cavite irreguliere en sous-cavites acoustiques dont les bases de developpement sont connues a priori. Cette approche, a caractere physique, presente l'avantage d'etre efficace et precise. La validite de celle-ci a ete demontree en utilisant des resultats disponibles dans la litterature. Un modele vibro-acoustique est developpe dans un but d'analyser et de comprendre les effets structuraux et acoustiques du plancher dans la configuration. La validite des resultats, en termes de resonance et de fonction de transfert, est verifiee a l'aide des mesures experimentales realisees au laboratoire.

Exercise in middle-aged adults: self-efficacy and self-presentational outcomes.

PubMed

McAuley, E; Bane, S M; Mihalko, S L

1995-07-01

Whereas self-efficacy expectations have been identified as important determinants of exercise participation patterns, little empirical work that examines efficacy expectations as outcomes of exercise participation or their theoretical relationship to other psychological outcomes associated with exercise has been conducted. In the context of middle-aged males and females, the present study attempted to integrate social cognitive and impression management perspectives with respect to anxiety associated with exercise. Formerly sedentary subjects participated in a 5-month exercise program with assessments of physique anxiety, efficacy, outcome expectations, and anthropometric variables prior to and following the program. Both acute bouts and long-term participation in exercise resulted in significant increases in self-efficacy. In turn, these changes in efficacy and initial positive outcome expectations were significant predictors of reductions in physique anxiety, even when controlling for the influence of gender and reductions in body fat, weight, and circumferences. The findings are discussed in terms of the implications for structure and content of exercise environments and the utility of the proposed theoretical integration. Strategies for enhancing beliefs regarding health and fitness outcomes associated with exercise rather than appearance outcomes may be required to maximize reductions in negative body image.

List of Participants

NASA Astrophysics Data System (ADS)

2008-11-01

Mohab Abou ZeidInstitut des Hautes Études Scientifiques, Bures-sur-Yvette Ido AdamMax-Planck-Institut für Gravitationsphysik (AEI), Potsdam Henrik AdorfLeibniz Universität Hannover Mohammad Ali-AkbariIPM, Tehran Antonio Amariti Università di Milano-Bicocca Nicola Ambrosetti Université de Neuchâtel Martin Ammon Max-Planck-Institut für Physik, München Christopher AndreyÉcole Polytechnique Fédérale de Lausanne (EPFL) Laura AndrianopoliPolitecnico di Torino David AndriotLPTHE, Université UPMC Paris VI Carlo Angelantonj Università di Torino Pantelis ApostolopoulosUniversitat de les Illes Balears, Palma Gleb ArutyunovInstitute for Theoretical Physics, Utrecht University Davide AstolfiUniversità di Perugia Spyros AvramisUniversité de Neuchâtel Mirela BabalicChalmers University, Göteborg Foday BahDigicom Ioannis Bakas University of Patras Igor BandosUniversidad de Valencia Jose L F BarbonIFTE UAM/CSIC Madrid Till BargheerMax-Planck-Institut für Gravitationsphysik (AEI), Potsdam Marco Baumgartl Eidgenössische Technische Hochschule (ETH), Zürich James BedfordImperial College London Raphael BenichouLaboratoire de Physique Théorique, École Normale Supérieure, Paris Francesco Benini SISSA, Trieste Eric Bergshoeff Centre for Theoretical Physics, University of Groningen Alice BernamontiVrije Universiteit, Brussel Julia BernardLaboratoire de Physique Théorique, École Normale Supérieure, Paris Adel Bilal Laboratoire de Physique Théorique, École Normale Supérieure, Paris Marco Billo' Università di Torino Matthias Blau Université de Neuchâtel Guillaume BossardAlbert-Einstein-Institut, Golm Leonardo BriziÉcole Polytechnique Fédérale de Lausanne (EPFL) Johannes BroedelLeibniz Universität Hannover (AEI) Tom BrownQueen Mary, University of London Ilka BrunnerEidgenössische Technische Hochschule (ETH), Zürich Erling BrynjolfssonUniversity of Iceland Dmitri BykovSteklov Institute, Moscow and Trinity College, Dublin Joan CampsUniversitat de Barcelona Davide CassaniLaboratoire de Physique Théorique, École Normale Supérieure, Paris Alejandra CastroUniversity of Michigan Claudio Caviezel Max-Planck-Institut für Physik, München Alessio Celi Universitat de Barcelona Anna Ceresole Istituto Nazionale di Fisica Nucleare, Università di Torino Athanasios ChatzistavrakidisNational Technical University of Athens Wissam ChemissanyCentre for Theoretical Physics, University of Groningen Eugen-Mihaita CioroianuUniversity of Craiova Andres CollinucciTechnische Universität Wien Paul CookUniversità di Roma, Tor Vergata Lorenzo CornalbaUniversità di Milano-Bicocca Aldo CotroneKatholieke Universiteit Leuven Ben Craps Vrije Universiteit, Brussel Stefano Cremonesi SISSA, Trieste Riccardo D'AuriaPolitecnico di Torino Gianguido Dall'AgataUniversity of Padova Jose A de AzcarragaUniversidad de Valencia Jan de BoerInstituut voor Theoretische Fysica, Universiteit van Amsterdam Sophie de BuylInstitut des Hautes Études Scientifiques, Bures-sur-Yvette Marius de LeeuwUtrecht University Frederik De RooVrije Universiteit, Brussel Jan De Rydt Katholieke Universiteit Leuven and CERN, Geneva Bernard de WitInstitute for Theoretical Physics, Utrecht University Stephane DetournayIstituto Nazionale di Fisica Nucleare, Sezione di Milano Paolo Di Vecchia Niels Bohr Institute, København Eugen DiaconuUniversity of Craiova Vladimir Dobrev Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences, Sofia Nick DoreyUniversity of Cambridge Hajar Ebrahim NajafabadiIPM, Tehran Federico Elmetti Università di Milano Oleg Evnin Vrije Universiteit, Brussel Francesco Fiamberti Università di Milano Davide Forcella SISSA, Trieste and CERN, Geneva Valentina Forini Humboldt-Universität zu Berlin Angelos Fotopoulos Università di Torino Denis Frank Université de Neuchâtel Marialuisa Frau Università di Torino Matthias Gaberdiel Eidgenössische Technische Hochschule (ETH), Zürich Diego Gallego SISSA/ISAS, Trieste Maria Pilar Garcia del MoralIstituto Nazionale di Fisica Nucleare, Università di Torino Valentina Giangreco Marotta PulettiUppsala University Valeria L GiliQueen Mary, University of London Luciano GirardelloUniversità di Milano-Bicocca Gian GiudiceCERN, Geneva Kevin Goldstein Institute for Theoretical Physics, Utrecht University Joaquim Gomis Universitat de Barcelona Pietro Antonio GrassiUniversità del Piemonte Orientale, Alessandria Viviane GraßLudwig-Maximilians-Universität, München Gianluca Grignani Università di Perugia Luca Griguolo Università di Parma Johannes GrosseJagiellonian University, Krakow Umut Gursoy École Polytechnique, Palaiseau Norberto Gutierrez RodriguezUniversity of Oviedo Babak HaghighatPhysikalisches Institut, Universität Bonn Troels Harmark Niels Bohr Institute, København Robert HaslhoferEidgenössische Technische Hochschule (ETH), Zürich Tae-Won HaPhysikalisches Institut, Universität Bonn Alexander HauptImperial College London and Max-Planck-Institut für Gravitationsphysik (AEI), Potsdam Marc HenneauxUniversité Libre de Bruxelles Johannes HennLAPTH, Annecy-le-Vieux Shinji HiranoNiels Bohr Institute, København Stefan HoheneggerEidgenössische Technische Hochschule (ETH), Zürich Jan HomannLudwig-Maximilians-Universität, München Gabriele Honecker CERN, Geneva Joost HoogeveenInstituut voor Theoretische Fysica, Universiteit van Amsterdam Mechthild HuebscherUniversidad Autónoma de Madrid Chris HullImperial College London Carmen-Liliana IonescuUniversity of Craiova Ella JasminUniversité Libre de Bruxelles Konstantin KanishchevInstitute of Theoretical Physics, University of Warsaw Stefanos Katmadas Utrecht University Alexandros KehagiasNational Technical University of Athens Christoph Keller Eidgenössische Technische Hochschule (ETH), Zürich Patrick Kerner Max-Planck-Institut für Physik, München Rebiai KhaledLaboratoire de Physique Mathématique et Physique Subatomique, Université Mentouri, Constantine Elias Kiritsis Centre de Physique Théorique, École Polytechnique, Palaiseau and University of Crete Denis KleversPhysikalisches Institut, Universität Bonn Paul Koerber Max-Planck-Institut für Physik, München Simon Koers Max-Planck-Institut für Physik, München Karl KollerLudwig-Maximilians-Universität, München Peter Koroteev Institute for Theoretical and Experimental Physics (ITEP), Moscow and Max-Planck-Institut für Gravitationsphysik (AEI), Potsdam Alexey KoshelevVrije Universiteit, Brussel Costas KounnasÉcole Normale Supérieure, Paris Daniel KreflCERN, Geneva Charlotte KristjansenNiels Bohr Institute, København Finn LarsenCERN, Geneva and University of Michigan Arnaud Le DiffonÉcole Normale Supérieure, Lyon Michael LennekCentre de Physique Théorique, École Polytechnique, Palaiseau Alberto Lerda Università del Piemonte Orientale, Alessandria Andreas LiberisUniversity of Patras Maria A Lledo Universidad de Valencia Oscar Loaiza-Brito CINVESTAV, Mexico Florian Loebbert Max-Planck-Institut für Gravitationsphysik (AEI), Potsdam Yolanda Lozano University of Oviedo Dieter Luest Ludwig-Maximilians-Universität, München Tomasz Łukowski Jagiellonian University, Krakow Diego Mansi University of Crete Alberto Mariotti Università di Milano-Bicocca Raffaele Marotta Istituto Nazionale di Fisica Nucleare, Napoli Alessio Marrani Istituto Nazionale di Fisica Nucleare and LNF, Firenze Andrea Mauri University of Crete Liuba Mazzanti École Polytechnique, Palaiseau Sean McReynoldsUniversità di Milano-Bicocca AKM Moinul Haque Meaze Chittagong University Patrick Meessen Instituto de Física Teórica, Universidad Autónoma de Madrid Carlo MeneghelliUniversità di Parma and Albert-Einstein-Institut, Golm Lotta Mether University of Helsinki and CERN, Geneva René Meyer Max-Planck-Institut für Physik, München Georgios MichalogiorgakisCenter de Physique Théorique, École Polytechnique, Palaiseau Giuseppe Milanesi Eidgenössische Technische Hochschule (ETH), Zürich Samuel Monnier Université de Genève Wolfgang MueckUniversità di Napoli Federico II Elena Méndez Escobar University of Edinburgh Iulian Negru University of Craiova Emil NissimovInstitute for Nuclear Research and Nuclear Energy, Sofia Teake NutmaCentre for Theoretical Physics, University of Groningen Niels Obers Niels Bohr Institute, København Olof Ohlsson SaxUppsala University Rodrigo OleaIstituto Nazionale di Fisica Nucleare, Sezione di Milano Domenico OrlandoUniversité de Neuchâtel Marta Orselli Niels Bohr Institute, København Tomas OrtinInstituto de Física Teórica, Universidad Autónoma de Madrid Yaron OzTel Aviv University Enrico PajerLudwig-Maximilians-Universität, München Angel Paredes GalanUtrecht University Sara PasquettiUniversité de Neuchâtel Silvia PenatiUniversità di Milano-Bicocca Jan PerzKatholieke Universiteit Leuven Igor PesandoUniversità di Torino Tassos PetkouUniversity of Crete Marios PetropoulosCenter de Physique Théorique, École Polytechnique, Palaiseau Franco PezzellaIstituto Nazionale di Fisica Nucleare, Sezione di Napoli Moises Picon PonceUniversity of Padova Marco PirroneUniversità di Milano-Bicocca Andrea PrinslooUniversity of Cape Town Joris RaeymaekersKatholieke Universiteit Leuven Alfonso RamalloUniversidade de Santiago de Compostela Carlo Alberto RattiUniversità di Milano-Bicocca Marco RauchPhysikalisches Institut, Universität Bonn Ronald Reid-EdwardsUniversity of Hamburg Patricia RitterUniversity of Edinburgh Peter RoenneDESY, Hamburg Jan RosseelUniversità di Torino Clement RuefService de Physique Théorique, CEA Saclay Felix RustMax-Planck-Institut für Physik, München Thomas RyttovNiels Bohr Institute, København and CERN, Geneva Agustin Sabio VeraCERN, Geneva Christian SaemannTrinity College, Dublin Houman Safaai SISSA, Trieste Henning SamtlebenÉcole Normale Supérieure, Lyon Alberto SantambrogioIstituto Nazionale di Fisica Nucleare, Sezione di Milano Silviu Constantin SararuUniversity of Craiova Ricardo SchiappaCERN, Geneva Ionut Romeo SchiopuChalmers University, Göteborg Cornelius Schmidt-ColinetEidgenössische Technische Hochschule (ETH), Zürich Johannes SchmudeSwansea University Waldemar SchulginLaboratoire de Physique Théorique, École Normale Supérieure, Paris Domenico SeminaraUniversità di Firenze Alexander SevrinVrije Universiteit, Brussel Konstadinos SfetsosUniversity of Patras Igor ShenderovichSt Petersburg State University Jonathan ShockUniversidade de Santiago de Compostela Massimo SianiUniversità di Milano-Bicocca Christoph SiegUniversità Degli Studi di Milano Joan SimonUniversity of Edinburgh Paul SmythUniversity of Hamburg Luca SommovigoUniversidad de Valencia Dmitri Sorokin Istituto Nazionale di Fisica Nucleare, Padova Christos SourdisUniversity of Patras Wieland StaessensVrije Universiteit, Brussel Ivan StefanovUniversity of Patras Sigurdur StefanssonUniversity of Iceland Kellogg Stelle Imperial College London Giovanni Tagliabue Università di Milano Laura Tamassia Katholieke Universiteit Leuven Javier TarrioUniversidade de Santiago de Compostela Dimitri TerrynVrije Universiteit, Brussel Larus Thorlacius University of Iceland Mario ToninDipartimento Di Fisica, Sezione Di Padova Mario Trigiante Politecnico di Torino Efstratios TsatisUniversity of Patras Arkady TseytlinImperial College London Pantelis TziveloglouCornell University, New York and CERN, Geneva Angel Uranga CERN, Geneva Dieter Van den Bleeken Katholieke Universiteit Leuven Ernst van Eijk Università di Napoli Federico II Antoine Van Proeyen Katholieke Universiteit Leuven Maaike van ZalkUtrecht University Pierre Vanhove Service de Physique Théorique, CEA Saclay Silvia Vaula Instituto de Física Teórica, Universidad Autónoma de Madrid Cristian Vergu Service de Physique Théorique, CEA Saclay Alessandro VichiÉcole Polytechnique Fédérale de Lausanne (EPFL) Marlene WeissCERN, Geneva and Eidgenössische Technische Hochschule (ETH), Zürich Sebastian Weiss Université de Neuchâtel Alexander WijnsUniversity of Iceland Linus WulffUniversity of Padova Thomas WyderKatholieke Universiteit Leuven Ahmed YoussefAstroParticule et Cosmologie (APC), Université Paris Diderot Daniela ZanonUniversità Degli Studi di Milano Andrea ZanziPhysikalisches Institut, Universität Bonn Andrey ZayakinInstitute for Theoretical and Experimental Physics (ITEP), Moscow Tobias ZinggUniversity of Iceland Dimitrios ZoakosUniversidade de Santiago de Compostela Emanuele ZorzanUniversità di Milano Konstantinos ZoubosNiels Bohr Institute, København

Evaluation de L’Effet du Vieillissement des Equipages sur les Consequences du Decalage Horaire (Evaluation of Crew Members Aging on Jet-Lag Consequences)

DTIC Science & Technology

2000-08-01

Ergonomia , 1987, 30, 13 79- physique que psychologique. Cela tend A damontrer que 1393. dans des conditions militaires op~rationnelles, les 2...melatonin. Ergonomia , 1987, 30, 1379- 1393. 2 - BLOIS R, FEINBERG I., GAILLARD J.M., KUPFER D.J. and WEBB W.B. Sleep in normal and pathological aging

Supersymmetric Higgs and radiative electroweak breaking

NASA Astrophysics Data System (ADS)

Ibáñez, Luis E.; Ross, Graham G.

2007-11-01

We review the mechanism of radiative electroweak symmetry breaking taking place in SUSY versions of the Standard Model. We further discuss different proposals for the origin of SUSY-breaking and the corresponding induced SUSY-breaking soft terms. Several proposals for the understanding of the little hierarchy problem are critically discussed. To cite this article: L.E. Ibáñez, G.G. Ross, C. R. Physique 8 (2007).

The Canadian Human Rights Act. Physical Handicap and Employment = Loi canadienne sur les droits de la personne. Le handicap physique et l'emploi.

ERIC Educational Resources Information Center

Canadian Human Rights Commission, Ottawa (Ontario).

This booklet presents administrative criteria for implementation of the Canadian Human Rights Act to be used by the Canadian Human Rights Commission to evaluate employment decisions affecting physically handicapped individuals. They are of value to employers who need to know how the Commission will analyze employer arguments that they have not…

Immersion francaise precoce: Education physique 1-7 (Early French Immersion: Physical Education for Grades 1-7).

ERIC Educational Resources Information Center

Burt, Andy; And Others

This curriculum guide for physical education is intended for use in grades 1-7 in the early French immersion program. It is a translation of the regular physical education program and a compilation of references and supplementary teaching material. It is noted that because of the comparative lack of references in French, much of the reference…

InSight Prelaunch Briefing

NASA Image and Video Library

2018-05-03

Philippe Lognonné, SEIS investigation lead, Institut de Physique du Globe de Paris (IPGP) discusses NASA's InSight mission during a prelaunch media briefing, Thursday, May 3, 2018, at Vandenberg Air Force Base in California. InSight, short for Interior Exploration using Seismic Investigations, Geodesy and Heat Transport, is a Mars lander designed to study the "inner space" of Mars: its crust, mantle, and core. Photo Credit: (NASA/Bill Ingalls)

Physics 30: Grade 12 Diploma Examination = Physique 30: Examen en vue du diplome 12 annee.

ERIC Educational Resources Information Center

Alberta Dept. of Education, Edmonton. Student Evaluation Branch.

This document, in both English and French versions, is the Physics 30 Grade 12 Diploma Examination from Alberta Education. It is a 2.5 hour closed-book examination consisting of 37 multiple-choice and 12 numerical-response questions of equal value that are worth 70% of the examination, and 2 written-response questions of equal value worth 30% of…

The experimental violation of Bell's inequality [as predicted by quantum mechanics]: A contribution to the study of its meaning

NASA Astrophysics Data System (ADS)

Hespel, Bertrand

Au vu des expériences déjà réalisées, il est permis de penser que la violation de l'inégalité de Bell conformément aux prédictions de la mécanique quantique sera bientôt un fait établi. D'après les lectures qui en ont été le plus souvent données, en raison de la non- localité qu'il met en évidence et de l'incompatibilité qu'il y aurait entre cette propriété et celle de localité postulée par la relativité, ce fait annihilerait inéluctablement l'espoir qui animait le fondateur de la physique moderne et bon nombre de ses successeurs: à moins d'accepter d'abandonner l'exigence d'exactitude, nous devrions définitivement nous résoudre à admettre que nous ne pourrons jamais fournir du monde qu'une image incomplète. L'histoire de la philosophie suggère une toute autre interprétation. Lorsqu'on reconstitue les tentatives oubliées menées par Spinoza, Malebranche et Leibniz, pour bâtir, comme Newton, à la suite de Descartes, un Monde tout à la fois exact et complet, ce fait apparaît plutôt comme la preuve empirique que le monde est tout à la fois local et inséparable-phénoménalement local mais fondamentalement inséparable-et qu'une image adéquate ne pourra donc en être donnée qu'à la condition de reconnaître qu'il ne se réduit pas au contenu de l'espace-temps, c'est-à-dire que ce monde qui est l'objet de la physique n'est pas le tout du monde et qu'il convient de prolonger cette science, désormais quantique et relativiste, par une méta-physique.

Violences conjugales à Antananarivo (Madagascar): un enjeu de santé publique

PubMed Central

Gastineau, Bénédicte; Gathier, Lucy

2012-01-01

Introduction La violence conjugale a été étudiée dans beaucoup de pays développés mais peu en Afrique subsaharienne. Madagascar est un pays où ce phénomène est peu documenté. Méthodes En 2007, une enquête sur la violence conjugale à Antananarivo (ELVICA) a été menée sur la violence conjugale envers les femmes dans la capitale malgache. ELVICA a interrogé 400 femmes en union, de 15 à 59 ans. Des informations sur les caractéristiques démographiques, socioéconomiques des couples ont été collectées ainsi que sur les actes de violences physiques des hommes sur leurs épouses. L’objectif de cet article est d’identifier les facteurs de risques de la violence conjugale grave, celle qui a des conséquences sur la santé physique des femmes. Résultats Trente-cinq pour cent des femmes qui ont déclaré avoir subi au moins une forme de violence physique au cours des 12 mois précédent l’enquête. Presque la moitié (46%) des femmes violentées ont déclaré avoir déjà eu des hématomes, et environ un quart (23%) des plaies avec saignement. Vingt-deux pour cent ont déjà dû consulter un médecin. Parmi les nombreuses variables socioéconomiques et démographiques testées, quelques-unes sont associées positivement au risque de violence conjugale grave: le fait pour une femme d’être en union consensuelle et d’avoir une activité professionnelle. Il y aussi un lien entre la violence subie et l’autonomie des femmes (liberté accordée par le mari de travailler, de circuler, de voir sa famille). Conclusion A Madagascar, comme ailleurs, la lutte contre les violences conjugales est un élément majeur de l’amélioration du statut et de la santé des femmes. PMID:22514757

Preferential Surface Adsorption in Miscible Blends of Polystyrene and Poly(vinyl methyl ether).

DTIC Science & Technology

1988-02-02

D. J. Phys. Chem. 1973, 74, 356. , c’’ 26~’::~ ~ ~ q,.,rf~.. w KRINMNIMVWU94M ~ ~ W-.TO"Kśtv X"- uV 23 25. Ober, R.; Paz, L.: Taupin , C.; Pincus, P...Boileau, S. Macromolecules 1983, 16 50. 26. DiMeglio, J.M.; Ober, R.; Paz, L.; Taupin , C.; Pincus, P.; Boileau, S. J. Physique 1983,4!, 1035. 27

Optimism and Cardiovascular Function in Children with Congenital Heart Disease

DTIC Science & Technology

2010-02-17

their theories. For example, Sigmund Freud (1856-1939) included references to both optimism and pessimism in his theory of human nature and...optimistic side of human nature and the drive towards death represents the pessimistic aspect of human nature ( Freud , 1927/1961, p. 8). The...W. (1977). Longitudinal physique changes among healthy white veterans at Boston. Human Biology, 49, 541-558. Freud , S. (1927/1961). Civilization

TREPS, a tool for coordinate and time transformations in space physics

NASA Astrophysics Data System (ADS)

Génot, V.; Renard, B.; Dufourg, N.; Bouchemit, M.; Lormant, N.; Beigbeder, L.; Popescu, D.; Toniutti, J.-P.; André, N.; Pitout, F.; Jacquey, C.; Cecconi, B.; Gangloff, M.

2018-01-01

We present TREPS (Transformation de REpères en Physique Spatiale) an online tool to perform coordinate transformations commonly used in planetology and heliophysics. It is based on SPICE kernels developed by NASA/NAIF. Its usage is straightforward, with a 4-step process, including various import/export options. Interoperability with external services is available through Virtual Observatory technology which is illustrated in a use case.

Picosecond Laser Pulse Interactions with Metallic and Semiconductor Surfaces.

DTIC Science & Technology

1983-11-01

Materials Research Society-Europe Meeting, Laset Solid Interactions and Transient Thermal Processing of Materials. Strasbourg, May 1983, 3. de Physique...of or assisting the heating of the sample. In this experiment the the Brillouin zone are involved, the index variations are de - probe fluence was...the entire range -of fluences below the threshold for phase transition. A de - tailed analysis of this fitting procedure is beyond the scope of 900

Medically Unexplained Physical Symptoms in Military Health (Symptomes physiques medicalement inexpliques dans la sante militaire)

DTIC Science & Technology

2017-12-01

Development of Persistent Pain and psychological Morbidity after Motor Vehicle Collision: Integrating the Potential Role of Stress Response Systems... abnormalities of quantitative EEG which suggest a THE LONG-TERM COSTS OF TRAUMATIC STRESS: INTERTWINED PHYSICAL AND PSYCHOLOGICAL CONSEQUENCES STO-TR-HFM...S.A., Clauw, D.J., Abelson, J.L. et al., The development of persistent pain and psychological morbidity after motor vehicle collision: integrating

Calendar of Selected Aeronautical and Space Meetings (Calendrier des Manifestations Aeronautiques et Spatiales (Selection)).

DTIC Science & Technology

1983-01-01

Physique de l’Atmosphire et Environnement terrestre 71 09 - Information, Documentation et Informatique 74 10 - Thimes gin~raux (pluridisciplinaires) et...March Louisiana (US) Fiber Communication Optical Communications IEEE Fibre Optics Electro-Optics 02-08 7-9 March Baden-Baden VDE -IEEE Specialists...Conference on Very Large Electronic Systems VDE (GE) Scale Integrated Circuits Solid State Devices IEEE Integrated Circuits Engineering Design Fabrication

Nonlinear Optical Interactions in Semiconductors.

DTIC Science & Technology

1985-12-10

Physique du Solide et Energie Solaire We had on-going interaction with Dr. Christian Verie on the growth of high quality narrow-gap semiconductor crystals...The band gap energy of the semiconductor decreases with increasing temperature. Consequently, the absorption of light in the energy region of the...gas and, more importantly, will modulate the electron energy at the difference frequency, wI - 02" Under ordinary circumstances such an energy (or

Nonlinear Optical Interactions in Semiconductors

DTIC Science & Technology

1984-10-01

TACAN Aerospace Corporation. 6 V. Coupling A. C.N.R.S., Physique du Solide et Energie Solaire We have an on-going interaction with Dr. Christian...optical fiber to the semiconductor sample and back to the analyzing electronics. The band-gap energy of the semiconductor decreases with increasing...temperature. Consequently, the absorption of light in the energy region of the band-gap changes with temperature. From the measured light absorption, the

Nonlinear Optical Interactions in Semiconductors

DTIC Science & Technology

1984-03-16

aU internal audits for TACAN Corporation. 7 V. Coupling A, C. N. R. S., Physique du Solide et Energie Solaire We have an ongoing interaction with Dr...fiber to the semiconductor sample and back to the analyzing electronics. The band gap energy of the semiconductor decreases with increasing tem- perature...Consequently, the absorption of light in the energy region of the band gap changes with temperature. From the measured light absorp- tion, the

The low birth-weight infants of Saudi adolescents: maternal implications.

PubMed

al-Sibai, M H; Khwaja, S S; al-Suleiman, S A; Magbool, G

1987-11-01

Maternal factors and perinatal outcome of low birth-weight (less than or equal to 2,500 g) infants of 46 adolescent mothers was studied and compared with 160 adolescents who delivered infants weighing greater than 2,500 g. The significant factors found in the low birth-weight group were anaemia, small maternal physique and preterm delivery. Expectedly, the perinatal mortality rate was significantly increased in low birth-weight infants.

Association between somatotypes and blood pressure in an adult Chuvasha population.

PubMed

Kalichman, Leonid; Livshits, Gregory; Kobyliansky, Eugene

2004-01-01

The relationship between blood pressure (BP) and anthropometrical characteristics has been indeed examined extensively, but only a few studies have investigated any connection of somatotypes to BP. to evaluate the association between BP and various anthropometrical characteristics, including components of somatotypes (using the methods of Heath and Carter and of Deriabin). The study sample comprised 783 males aged 18-89 years and 720 females aged 18-90 years, all residents of the Chuvasha, Russian Federation. We used multiple regression, Pearson's and canonical correlation analyses. Significant correlations (r = 0.19-0.28, p < 0.05) were obtained between BP and anthropometric characteristics associated with body compositions and somatotypes. The most impressive were the canonical correlations between BP and somatotype components derived according to Heath and Carter (0.275), and according to Deriabin's (0.333) method. Different body types were highly significantly (P < 0.001) associated with systolic and diastolic BP. Individuals of robust physique (with high endomorphy and mesomorphy) showed high mean values of systolic and diastolic BP, whereas the smallest persons had the lowest BP values. These findings suggest the existence of common physiological paths in the development of body physique and blood pressure regulation and may possibly be indicative of the involvement of pleiotropic genetic and/or epigenetic mechanisms in this regulation.

Somatotype in elderly type 2 diabetes patients.

PubMed

Buffa, Roberto; Floris, Giovanni; Putzu, Paolo F; Carboni, Luciano; Marini, Elisabetta

2007-09-01

Somatotyping is a practical technique for the description of physique. Individuals with Type 2 diabetes are characterized by physical peculiarities, such as overweight, obesity and a central pattern of body fat distribution. Somatotype applications to diabetes are limited. The objective of this study is to describe the somatotype of elderly type 2 diabetes patients. The sample consisted of 110 patients with type 2 diabetes (45 men, mean age 69.4 +/- 7.0 years; 65 women, mean age 72.9 +/- 7.1 years). The pathological subjects were compared with a control group consisting of 280 healthy individuals (134 men, mean age 74.2 +/- 7.3 years; 146 women, mean age 74.9 +/- 7.4 years). The Heath-Carter somatotype was applied. Diabetic men and women (mean somatotype, respectively: 6.8-5.6-0.6 and 8.6-6.4-0.2) presented significantly higher values of endomorphy than the controls (p = 0.043 in men, p = 0.003 in women); men also had a lower mesomorphic component (p = 0.000). The somatotype method revealed physical peculiarities in type 2 diabetes patients. The marked endomorphy in the pathological individuals can be related to general fatness, which is a well known disease risk factor. The somatotype appears to be a suitable technique for the assessment of physique in type 2 diabetes patients.

Self-identity and the theory of planned behaviour: between- and within-participants analyses.

PubMed

Hagger, Martin S; Chatzisarantis, Nikos L D

2006-12-01

Two studies addressed the hypothesis that a minority of people are more oriented towards their self-identity when forming intentions to act than the traditional antecedents of intentional action; attitudes, subjective norms and perceived behavioural control (PBC). In Study 1, participants (N=241) completed measures of an augmented version of theory of planned behaviour (TPB) that included self-identity for 30 behaviours. Using within-participants multiple regression analyses, the sample was classified into self-identity-oriented (SI-oriented) and TPB-oriented groups. Between-participants multiple regression analyses revealed that self-identity was a significantly stronger predictor of intentions and accounted for significantly more incremental variance in intentions in the SI-oriented sample compared with the TPB-oriented sample across the 30 behaviours. In Study 2, participants (N=250) completed the same TPB and self-identity measures used in Study 1 as well as measures of generalized self-concept and social physique anxiety for dieting behaviour. Results indicated that self-identity was significantly associated with the generalized self-related measures, and self-concept and social physique anxiety moderated the self-identity-intention relationship. This investigation provides some preliminary evidence to support the effect of individual differences in self-identity on the formation of intentions to act.

Dietary Intake, Body Composition, and Menstrual Cycle Changes during Competition Preparation and Recovery in a Drug-Free Figure Competitor: A Case Study

PubMed Central

Halliday, Tanya M.; Loenneke, Jeremy P.; Davy, Brenda M.

2016-01-01

Physique competitions are events in which competitors are judged on muscular appearance and symmetry. The purpose of this retrospective case study was to describe changes in dietary intake, body mass/composition, and the menstrual cycle during the 20-week competition preparation (PREP) and 20-week post competition recovery (REC) periods of a drug-free amateur female figure competitor (age = 26–27, BMI = 19.5 kg/m2). Dietary intake (via weighed food records) and body mass were assessed daily and averaged weekly. Body composition was estimated via Dual-energy X-ray absorptiometry (DXA) and 7-site skinfold measurements. Energy intake, body mass and composition, and energy availability decreased during the 20-week PREP period (changes of ~298 kcals, 5.1 kg, 6.5% body fat, and 5.4 kcal/kg fat free mass, respectively) and returned to baseline values by end of the 20-week REC period. Menstrual cycle irregularity was reported within the first month of PREP and the last menstruation was reported at week 11 of PREP. Given the potentially adverse health outcomes associated with caloric restriction, future, prospective cohort studies on the physiological response to PREP and REC are warranted in drug-free, female physique competitors. PMID:27879627

Prise en charge en cabinet des lésions cérébrales traumatiques légères chez les enfants et les adolescents

PubMed Central

Garcia-Rodriguez, Juan Antonio; Thomas, Roger E.

2014-01-01

Résumé Objectif Fournir aux médecins de famille de l’information à jour, pratique et factuelle sur les lésions cérébrales traumatiques légères et les commotions cérébrales dans la population pédiatrique. Sources d’information Une recherche a été effectuée dans MEDLINE (de 1950 à février 2013), la base de données des revues systématiques Cochrane (de 2005 à 2013), le registre central Cochrane des essais contrôlés (de 2005 à 2013) et DARE (2005 à 2013) à l’aide de mots-clés liés aux commotions cérébrales et aux traumatismes crâniens. Des lignes directrices, énoncés de position, articles et rapports de recherche originaux pertinents aux lésions cérébrales traumatiques légères ont été sélectionnés. Message principal Le traumatisme est la cause principale de décès chez les enfants de plus d’un an et, dans ce groupe, le traumatisme crânien est la cause la plus fréquente d’incapacité et de décès. Neuf pour cent des blessures sportives rapportées chez les élèves du secondaire sont associées à une lésion cérébrale traumatique légère. Les médecins de famille doivent effectuer une anamnèse ciblée et un examen physique et neurologique, utiliser les instruments d’évaluation standardisés (Échelle de Glasgow; Outil d’évaluation des commotions cérébrales dans le sport, version 3; version pédiatrique de l’Outil d’évaluation des commotions cérébrales dans le sport; et échelle BESS [Balance Error Scoring System]), expliquer aux parents comment surveiller leurs enfants, décider des circonstances où les soignants ne sont pas une ressource dûment responsable, faire un suivi prompt auprès des patients, guider le retour sécuritaire au jeu ou à l’école et décider dans quelles circonstances un test neuropsychologique est nécessaire au suivi à long terme. Conclusion La prise en charge par le médecin de famille des lésions cérébrales traumatiques légères chez les enfants repose sur une anamnèse détaillée, un examen physique et neurologique, le recours à des instruments validés qui fourniront un cadre objectif et des suivis périodiques.

Moving to Inclusion. Active Living through Physical Education: Maximizing Opportunities for Students with a Disability = Integration en Mouvement. La vie active par l'education physique: Multipliez les possibilities offertes aux eleves ayant un handicap.

ERIC Educational Resources Information Center

Active Living Alliance for Canadians with a Disability, Gloucester (Ontario).

This document is composed of 10 manuals which provide both general and specific guidelines to facilitate the inclusion of Canadian students with disabilities in physical education programs. An introductory manual identifies general concepts, strategies, and practical approaches that can be used in an inclusive physical education program. It…

Characteristics of a Steadily Operating Metal Combustor

DTIC Science & Technology

1976-08-01

Physique, Serie 7, Vol. 17, p. 510-576, 1899. 18. Zintl, E., Harder, A., and Dauth, B., "Gitterstruktur Der Oxyde , Sulfide, Selenide Und Telluride Des...ethyl alcohol were added to the cylinder along with three drops of alizarin Red S indicator (1%). The solution was titrated with thorium nitrate until...the appearance of a faint pink color. The thorium nitrate precipitated thorium fluoride which is insoluble in ethyl alcohol , and the indicator detected

MEASUREMENT OF THE RADIOACTIVE CONTAMINATION OF THE FOOD CHAIN (in French)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chevallier, A.; Schneider, R.

ABS>The results obtained at the Laboratoire de Protection of 1'Institut de Physique Biologique, Strasbourg, from 1958 to 1960 on the contamination of food are tabulated. The methods used for the measurement of the total beta activity and for the radiochemical separations and determination of the elements isolated are described for milk and vegetables. The activities found in milk, vegetables, and animal skeletons are given in tabular form. (J.S.R.)

Free field theory as a string theory?

NASA Astrophysics Data System (ADS)

Gopakumar, Rajesh

2004-11-01

An approach to systematically implement open-closed string duality for free large N gauge theories is summarised. We show how the relevant closed string moduli space emerges from a reorganisation of the Feynman diagrams contributing to free field correlators. We also indicate why the resulting integrand on moduli space has the right features to be that of a string theory on AdS. To cite this article: R. Gopakumar, C. R. Physique 5 (2004).

Calendar of Selected Aeronautical and Space Meetings January 1991 Onwards (Calendrier des Manifestations Aeronautiques et Spatiales (Selection) Janvier 1991 et au-dela)

DTIC Science & Technology

1990-12-01

e 39 08 - Physique de l’Atmosph~re et Environnement terrestre 55 09 - Information, Documentation et Informatique 58 10 - Th~rnes g6n6raux...Fax (02) 692 2012 OS UV University of Vienna: Liebigasse 4/3-4, A- 1010 Wien Tel 43.1.43.67.12 Fax 43.1.43.01.97 AU VDE Verband Deutscher

Préface

NASA Astrophysics Data System (ADS)

Ouerdane, Youcef; Laporte, Pierre

2005-06-01

L'objectif de la série de colloques UVX est de réunir, au rythme d'une fois tous les deux ans, les scientifiques et industriels travaillant dans le domaine du développement des sources de photon de grande énergie (UV, VUV, et X) et de leurs applications. En particulier cette manifestation est l'occasion de faire se rencontrer une communauté très pluridisciplinaire (physique, chimie, biologie, sciences de l'univers) liée à des domaines en forte évolution technologique (lasers et rayonnement synchrotron notamment). Le colloque UVX 2004 s'est tenu au Palais des Congrès de Saint-Étienne (42000) du 7 au 11 juin 2004. La période écoulée depuis l'édition précédente (Oléron 2002) a été particulièrement active dans tous les domaines concernés : grands projets de sources, méthodes de diagnostic au sens large. Une nouvelle fois on constate que le bref et l'ultra-bref ont une place privilégiée, qu'il s'agisse du travail sur les accélérateurs ou sur les lasers qui, bien sûr, dans la course aux temps courts remportent la palme avec la présence de spécialistes du domaine attoseconde. La communauté représentée a la chance d'être en prise directe avec de très grands projets en phase active de réalisation comme le Laser Megajoule (LMJ), la source SOLEIL, et un projet d'ampleur plus modeste mais remarquable dans son domaine : la source LASERIX d'Orsay/Palaiseau. On pourra citer aussi le projet Arc en Ciel qui, lui, est encore au stade de sa définition. - SOLEIL, source de nouvelle génération de rayonnement synchrotron (plateau de Saclay) est dans une phase active de réalisation : achèvement de l'infrastructure en 2005 et injection du 1o faisceau dans l'anneau de stockage prévu également en 2005. Cette source devrait être la meilleure au monde dans le domaine VUV/X mous, tout en restant très polyvalente (brillance, accordabilité, structure temporelle, polarisation) et complémentaire de l'ESRF. Au final on disposera de 21 lignes de lumière sur onduleurs et 22 sur aimants de courbure. Les premiers “utilisateurs” sont prévus au printemps 2006 avec couverture de l'IR jusqu'aux X durs pour des études variées notamment dans le domaine de la matière condensée. - La LIL (ligne d'intégration laser) du LMJ fonctionne avec 4 faisceaux (de 30 kJ à 351 nm) et un ensemble de diagnostics plasma est en cours de validation (énergie, imagerie X, spectrométrie X). Un souci d'ouverture collaborative (France et étranger) est affiché. - LASERIX (LIXAM, LOA) a pour but de doter les scientifiques français d'un laser émettant en “quasi-routine” de l'émission laser X à 6 tirs/mn basée sur différents schémas collisionnels et donc différentes longueurs d'ondes, et mettant en oeuvre un laser saphir-titane ultra bref de 40 J pour la génération plasma. - Le projet Arc en Ciel (CEA, LOA) se penche sur la possibilité de mise en oeuvre d'une source de “4^ogénération”. Ces sources se veulent à la fois brillantes, cohérentes, dans la gamme des 100 femtosecondes, ce qui conduit à tourner le dos aux anneaux de stockage pour se focaliser sur la combinaison accélérateur linéaire/onduleur, complétée par un laser saphir-titane (génération d'harmoniques UV/X dans des gaz). - Une avancée particulièrement intéressante a été récemment réalisée, notamment au LOA, par injection d'un laser X (plasma) par un faisceau X de bonne qualité (polarisation, divergence, temps, contraste...) issu de la génération d'harmoniques élevées par une chaîne saphir-titane femto. - On notera aussi les avancées réalisées dans le domaine des sources incohérentes de forte intensité dans le domaine des X par interaction optimisée de l'interaction laser de puissance-agrégats (GPS-Paris 6 et 7, CEA Saclay), ainsi que par techniques X-pinch à fils à foyer de 10 microns (LPTP-École Polytechnique). - La génération d'harmoniques d'ordres élevés à partir de chaînes laser amplifiées a continué à faire l'objet de très belles études, d'une part par génération dans les gaz et l'obtention bien maîtrisée et caractérisée de rayonnement attoseconde utilisé maintenant pour des mesures effectives de processus électroniques au sein des atomes, et d'autre part par focalisation sur cible solide. Ces derniers travaux (CEA et LOA), par mise en oeuvre du concept de “miroir plasma” qui combat l'ASE, ont permis de monter que la génération d'harmoniques cohérents sur solide était effective. - Dans le domaine des sources UV deux exposés ont présenté l'état de l'art des sources diodes ellesmêmes (LED et Lasers), ainsi que le développement des sources laser ps haute cadence (multikHz/MHz) avec génération d'harmoniques, de puissance moyenne élevée adaptée à de nombreux secteurs applicatifs (traitement des matériaux, biologie, microscopie...). L'aspect “sources”, au sens large était, on le voit, particulièrement représenté avec de belles perspectives pour les années qui viennent. Au delà de ces développements, les sources X ont été utilisées pour des réalisations instrumentales intéressantes dans le domaine de la microscopie X, de la microscopie interférentielle, et de la reconstruction 3D. De tels travaux sont susceptibles de rapides transferts en direction du secteur bio/santé. On notera également l'avancée que représente la réalisation d'un spectromètre à transformée de Fourier pour VUV/XUV (LCFIO/LPPM/SOLEIL). Le domaine du diagnostic, de la mesure, et de la modélisation dans les plasmas est, lui aussi, très actif avec des outils expérimentaux et théoriques très conséquents : modélisation des propriétés spectrales des ions multichargés (CEA-DAM) ; coefficients d'absorption de plasmas lasers (CEA-DSM, LULI, CEA-DAM) ; spectres d'absorption X dans les plasmas femtosecondes incluant des expériences type “pompe-sonde” résolues spatialement et spectralement (LULI, CEA-DAM, CELIA) ; interaction laseratome/molécule en régime UVX ultra-bref (CELIA)... Dans le domaine que l'on peut appeler, au sens large, “travail des matériaux”, on distinguera particulièrement les avancées dans le domaine de la microlithographie “prévues” par road map, avec l'arrivée semble-t-il inéluctable des technologies UVX à 13,5 nm. Les enjeux économiques favorisent des avancées technologiques multiples (optiques multicouches en réflexion, sources...). Par ailleurs l'aptitude des technologies femto pour l'ablation quasi athermique (micro-usinage) et le dépôt de couches minces spécifiques se confirme tout à fait. Enfin, à fluence plus faible, l'outil laser reste un instrument de choix pour l'étude de l'interaction photon-surface : désorption sous illumination laser à excimères à 157 nm et photoémission/photoconductivité du diamant sous éclairement ultra-bref de l'infrarouge à l'UVX. Nous tenons à remercier les membres du comité d'organisation, le comité scientifique et les différents partenaires, institutionnels et industriels, qui par leur soutien ont permis que le colloque UVX puisse se dérouler. Ce colloque a été parrainé par plusieurs départements du CNRS, la Délégation Générale de l'Armement (DGA), le CEA DRECAM, le CEA DAM, le Conseil Général de la Loire, l'Université Jean MONNET de Saint-Étienne, Saint-Étienne Métropole, la ville de Saint-Étienne, Le Pôle Optique Rhône-Alpes, la Société Française d'Optique et le Groupement de Recherche “SAXO” du CNRS. À tous, nous donnons rendez-vous à Caen pour UVX-2006. Youcef OUERDANE Pierre LAPORTE

Partager : des technologies de pointe au service de la société

ScienceCinema

None

2018-04-27

Médecine, climatologie, métrologie et informatique, les techniques utilisées par le LHC trouvent déjà des répercussions dans d’autres domaines scientifiques. Utilisant des techniques inédites, la physique des particules en fait bénéficier la société toute entière.

High-Lift System Aerodynamics (L’Aerodynamique des Systems Hypersustentateurs)

DTIC Science & Technology

1993-09-01

les kcouleinents incoinpressibles sur les profils L -a pr~sente m~thode num~rique montre que la simulation multi-corps, qui est un...de l ’&oulement du d𔄀chelle de discrdtisation, d’origine physique, introduit des m~me ordre que l ’~paisseur des couches limites sur le point de...hypersustentateurs. Enfin, les consequences des exigences de furtivite sur la forme des aeronefs - c’est it dire la creation de configurations telles que

Voyage dans le noir. Trous noirs, matière noire, énergie noire et antimatière [Journey in the dark. Black holes, dark matter, dark energy and antimatter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alvarez-Gaume, Luis; Doser, Michael; Grojean, Chri

2009-11-26

Et si nous faisions avec les physiciens un voyage dans le noir ? De l'astrophysique à la physique des particules les trois noirs, la matière noire, l'énergie noire ou l’antimatière intriguent et fascinent. Que sont ces objets qui bousculent nos idées et qui véhiculent parfois des craintes irraisonnées? Luis Alvarez-Gaume, Michael Doser et Christophe Grojean, physiciens du CERN vous invitent à mettre en lumière (!) les constituants de base de la matière et à explorer les mystères de la physique contemporaine. Une soirée lumineuse pour éclairer des concepts et ne plus avoir peur du noir. [ What if we mademore » a trip to the physicists in the dark? From astrophysics to particle physics the three blacks, dark matter, dark energy or antimatter intrigue and fascinate. What are these objects that jostle our ideas and sometimes convey irrational fears? Luis Alvarez-Gaume, Michael Doser and Christophe Grojean, CERN physicists invite you to highlight (!) The basic constituents of matter and to explore the mysteries of contemporary physics. A bright evening to illuminate concepts and not be afraid of the dark.]« less

Social Physique Anxiety, Mental Health, and Exercise: Analyzing the Role of Basic Psychological Needs and Psychological Inflexibility.

PubMed

Alcaraz-Ibáñez, Manuel; Sicilia, Álvaro; Burgueño, Rafael

2017-02-22

This study aimed to determine the usefulness of integrating basic psychological needs theory (BPNT) and relational frames theory (RFT) in order to explain the effects of social physique anxiety (SPA) - in the context of exercise - on exercisers' mental health. A total of 296 recreational cyclists and triathletes (100% males) aged 18 to 60 years old (M age = 35.65, SD = 9.49) completed a multi-section questionnaire assessing the target variables. Two models of structural equations with multiple mediators were tested using 5000 bootstrap samples. While the BPNT-based model explained 20% of variance in satisfaction with life (SWL) and 25% of variance in mental health (MH), the model that also incorporated RFT explained 43% of variance in both of those variables. Results showed that SPA negatively impacted exercisers' mental health via two different mechanisms: a) through a decrease in perceived satisfaction of basic psychological needs (β = -.05, p = .045 for SWL; β = -.07, p = .002 for MH); b) through an increase in psychological inflexibility, generated directly by SPA (β = -.24, p < .001 for SWL; β = -.20, p < .001 for MH) and also mediated by basic psychological need thwarting (β = -.09, p < .001 for SWL; β = -.08, p = .002 for MH). Results supported integrating the two theories, elucidating the processes by which a controlling social factor like SPA can affect the potential benefits of exercise.

Clinical significance of low result of 1-h 50-g glucose-challenge test in pregnant women.

PubMed

Oawada, Nozomi; Aoki, Shigeru; Sakamaki, Kentaro; Obata, Soichiro; Seki, Kazuo; Hirahara, Fumiki

2018-01-31

The objective of this study is to examine the effect of low-glucose value on the 1-h 50-g glucose challenge test (GCT) on neonatal body weight in low-risk Asian singleton pregnant women. We retrospectively analyzed women who delivered a singleton neonate at term at a tertiary center and underwent GCT at 24-28 weeks of gestation between June 2001 and June 2015. The low GCT group was defined as <75 mg/dL and 75-139 mg/dL were control. We compared these two groups of maternal characteristics, small for gestational age neonate (SGA), large for gestational age neonate (LGA), low-birth weight, and macrosomia. The χ 2 test, Fisher's exact test, and Student's t test were used. There were 313 low GCT groups and 4611 control. The low GCT group were younger, had lower prepregnancy body weight, higher stature, and lower prepregnancy body mass index (BMI). After adjusting these variables, the low GCT group had a lower rate of LGA and a higher rate of SGA. Neonatal body weight is more influenced by maternal physique than by low GCT result (standardized coefficient (β); GCT 0.071, height 0.188, prepregnancy BMI 0.143). Neonatal body weight was only slightly influenced by low GCT result, but markedly influenced by maternal physique, such as height and prepregnancy BMI.

PEOPLE IN PHYSICS: 'Lady Newton' - an eighteenth century Marquise

NASA Astrophysics Data System (ADS)

Badilescu, Simona

1996-07-01

The contribution of Voltaire and Mme du Châtelet to the diffusion of Newtonian physics in eighteenth century France is outlined. Their most important writings in the realm of physics (Philosophical Letters, Elements de la philosophie de Newton, Institutions de Physique) are analysed and the impact of the new ideas on the traditional Cartesian physics is emphasized. The genesis of the first French translation of Newton's Principia is described. The usefulness of the historically connected stories in the teaching of physics is envisaged.

CFD Simulations of a Ferry in Head Seas

DTIC Science & Technology

2011-03-01

la durée de vie en fatigue globale du navire. Il est important, pour la conception, l’exploitation et la gestion du cycle de ...vibration de frottement qui exerce une contrainte sur la structure de coque primaire et qui a un effet défavorable sur la durée de vie en fatigue globale du ...laquelle ne peut simuler directement la physique du tossage. Le présent rapport contient les résultats d’une étude faisant

Hig Resolution Seismometer Insensitive to Extremely Strong Magnetic Fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abramovich, Igor A.

A highly sensitive broadband seismic sensor has been developed successfully to be used in beam focusing systems of particale accelerators. The sensor is completely insensitive to extremely strong magnetic fields and to hard radiation conditions that exist at the place of their installation. A unique remote sensor calibration method has been invented and implemented. Several such sensors were sold to LAPP (LAPP-IN2P3/CNRS-Université de Savoie; Laboratoire d'Annecy-le-Vieux de Physique des Particules)

Retirement Kjell Johnsen

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2007-12-05

A l'occasion de son 65me anniversaire plusieurs orateurs (aussi l'ambassadeur de Norvège) remercient Kjell Johnsen, né en juin 1921 en Norvège, pour ses 34 ans de service au Cern et retracent sa vie et son travail. K.Johnsen a pris part aux premières études sur les accélérateurs du futur centre de physique et fut aussi le père et le premier directeur de l'Ecole du Cern sur les accélérateurs (CAS)

Transcendental Meditation

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2005-11-29

K.Wallace, qui vient des Etats Unis, parle des effects physiologiques de la méditation transcendantale. Il a fait son bachelor en physique à l'Université de Los Angeles et son doctorat en physiologie aussi à Los Angeles, mais à l'Institut de Recherche sur le cerveau. Il travaille maintenat à Harvard Medical School ou il continue des recherches biochimiques et physiologiques sur l'application médicale de la méditation transcendantale. Il s'occupe principalement des maladies cardiaques et de hypertension artérielle.

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

Plusieurs orateurs rendent hommage au grand physicien et scientifique Vladimir Jurko Glaser (1924 - 1984) qui travaillait au Ruder Boscovic Institut à Zagreb avant de venir au Cern en 1957 où il trouvait un poste permanent au département de physique théorique. Walter Tearing, Harry Lehmann,Henry Epstein, Jacques Bros et André Martin font des résumés biographiques de leurs collègue et ami en honorant ses grands qualités d'homme et ses remarquables conquêtes de la science et leurs accomplissement.

Self-reported Health and Well-being Outcomes of ASERE Students

DTIC Science & Technology

2005-07-01

mesure normalisée) des scores légèrement plus faibles dans l’évaluation de la santé physique à la fin du cours comparativement à ceux indiqués avant...faibles après le cours comparativement à ceux obtenus lors de l’évaluation antérieure au cours...Zachariassen, 2000, p. 334). Indeed, the need for control is so great in humans that stress can trigger a variety of behaviors specifically designed to

Effects of Stencil Width on Surface Ocean Geostrophic Velocity and Vorticity Estimation from Gridded Satellite Altimeter Data

DTIC Science & Technology

2012-03-17

Texas at Austin, Austin, Texas, USA. g dq ’Departement de Physique and LPO, Universite de Bretagne V _ /" r5r’ Occidental, Brest ...grid points are used in the calculation, so that the grid spacing is 8 times larger than on the original grid. The 3-point stencil differences are sig...that the difference between narrow and wide stencil estimates increases over that found on the original higher resolution grid. Interpolation of the

Estimates of Surface Drifter Trajectories in the Equatorial Atlantic: A Multi-model Ensemble Approach

DTIC Science & Technology

2012-01-01

Physique des Oceans UMR6523 (CNRS. I B(). IFREMER. IRD). Brest , France C. N. Barron E. Joseph Metzger Naval Research Laboratory, Stennis Space...AF447 flight from Rio to Paris . The airplane disappeared on June 1st 2009 near 3° N and 31° W, and a large international effort was organized to...to Runge-Kutta trajectory integration. The low- pass filter was accomplished by convolving the original (XiCM velocity fields at each time step and

Motivational and psychological correlates of bodybuilding dependence

PubMed Central

EMINI, NEIM N.; BOND, MALCOLM J.

2014-01-01

Abstract Background and aims: Exercise may become physically and psychologically maladaptive if taken to extremes. One example is the dependence reported by some individuals who engage in weight training. The current study explored potential psychological, motivational, emotional and behavioural concomitants of bodybuilding dependence, with a particular focus on motives for weight training. Using a path analysis paradigm, putative causal models sought to explain associations among key study variables. Methods: A convenience sample of 101 men aged between 18 and 67 years was assembled from gymnasia in Adelaide, South Australia. Active weight trainers voluntarily completed a questionnaire that included measures of bodybuilding dependence (social dependency, training dependency, and mastery), anger, hostility and aggression, stress and motivations for weight training. Results: Three motives for weight training were identified: mood control, physique anxiety and personal challenge. Of these, personal challenge and mood control were the most directly salient to dependence. Social dependency was particularly relevant to personal challenge, whereas training dependency was associated with both personal challenge and mood control. Mastery demonstrated a direct link with physique anxiety, thus reflecting a unique component of exercise dependence. Conclusions: While it was not possible to determine causality with the available data, the joint roles of variables that influence, or are influenced by, bodybuilding dependence are identified. Results highlight unique motivations for bodybuilding and suggest that dependence could be a result of, and way of coping with, stress manifesting as aggression. A potential framework for future research is provided through the demonstration of plausible causal linkages among these variables. PMID:25317342

Motivational and psychological correlates of bodybuilding dependence.

PubMed

Emini, Neim N; Bond, Malcolm J

2014-09-01

Exercise may become physically and psychologically maladaptive if taken to extremes. One example is the dependence reported by some individuals who engage in weight training. The current study explored potential psychological, motivational, emotional and behavioural concomitants of bodybuilding dependence, with a particular focus on motives for weight training. Using a path analysis paradigm, putative causal models sought to explain associations among key study variables. A convenience sample of 101 men aged between 18 and 67 years was assembled from gymnasia in Adelaide, South Australia. Active weight trainers voluntarily completed a questionnaire that included measures of bodybuilding dependence (social dependency, training dependency, and mastery), anger, hostility and aggression, stress and motivations for weight training. Three motives for weight training were identified: mood control, physique anxiety and personal challenge. Of these, personal challenge and mood control were the most directly salient to dependence. Social dependency was particularly relevant to personal challenge, whereas training dependency was associated with both personal challenge and mood control. Mastery demonstrated a direct link with physique anxiety, thus reflecting a unique component of exercise dependence. While it was not possible to determine causality with the available data, the joint roles of variables that influence, or are influenced by, bodybuilding dependence are identified. RESULTS highlight unique motivations for bodybuilding and suggest that dependence could be a result of, and way of coping with, stress manifesting as aggression. A potential framework for future research is provided through the demonstration of plausible causal linkages among these variables.

Fear of negative appearance evaluation: development and evaluation of a new construct for risk factor work in the field of eating disorders.

PubMed

Lundgren, Jennifer D; Anderson, Drew A; Thompson, Joel Kevin

2004-01-01

The psychometric properties and correlates of a measure designed to assess fear of negative appearance evaluation are presented. In Study 1, 165 college females completed the Fear of Negative Appearance Evaluation Scale [FNAES; Thomas, C.M., Keery, H., Williams, R., & Thompson, J. K. (1998, November). The Fear of Negative Appearance Evaluation Scale: Development and preliminary validation. Paper presented at the annual meeting of the Association for the Advancement of Behavior Therapy, Washington, DC] along with measures of body image, eating disturbance, and depression. Results replicated previous analyses indicating the presence of a single factor, good internal consistency, and significant association with measures of body image and eating disturbance. Additionally, the FNAES accounted for unique variance beyond that explained by general fear of negative evaluation, and other measures of body image and eating disturbance, in the prediction of body shape dysphoria, dietary restraint, and trait anxiety. Study 2 further examined the validity of the FNAES, finding it to correlate significantly with measures of social physique anxiety, body image, eating attitude, and mood. The FNAES did not significantly correlate with body mass index (BMI). Regression analyses found the FNAES to predict levels of body image, eating attitude, and mood beyond variance explained by social physique anxiety. The FNAES appears to measure a conceptually unique aspect of body image that has not been indexed by previous measures and may serve a useful role in risk factor and preventive work.

Nutritional recommendations for water polo.

PubMed

Cox, Gregory R; Mujika, Iñigo; van den Hoogenband, Cees Rein

2014-08-01

Water polo is an aquatic team sport that requires endurance, strength, power, swimming speed, agility, tactical awareness, and specific technical skills, including ball control. Unlike other team sports, few researchers have examined the nutritional habits of water polo athletes or potential dietary strategies that improve performance in water polo match play. Water polo players are typically well muscled, taller athletes; female players display higher levels of adiposity compared with their male counterparts. Positional differences exist: Center players are heavier and have higher body fat levels compared with perimeter players. Knowledge of the physical differences that exist among water polo players offers the advantage of player identification as well as individualizing nutrition strategies to optimize desired physique goals. Individual dietary counseling is warranted to ensure dietary adequacy, and in cases of physique manipulation. Performance in games and during quality workouts is likely to improve by adopting strategies that promote high carbohydrate availability, although research specific to water polo is lacking. A planned approach incorporating strategies to facilitate muscle glycogen refueling and muscle protein synthesis should be implemented following intensified training sessions and matches, particularly when short recovery times are scheduled. Although sweat losses of water polo players are less than what is reported for land-based athletes, specific knowledge allows for appropriate planning of carbohydrate intake strategies for match play and training. Postgame strategies to manage alcohol intake should be developed with input from the senior player group to minimize the negative consequences on recovery and player welfare.

Voyage dans le noir. Trous noirs, matière noire, énergie noire et antimatière [Journey in the dark. Black holes, dark matter, dark energy and antimatter

ScienceCinema

Alvarez-Gaume, Luis; Doser, Michael; Grojean, Chri

2018-05-24

Et si nous faisions avec les physiciens un voyage dans le noir ? De l'astrophysique à la physique des particules les trois noirs, la matière noire, l'énergie noire ou l’antimatière intriguent et fascinent. Que sont ces objets qui bousculent nos idées et qui véhiculent parfois des craintes irraisonnées? Luis Alvarez-Gaume, Michael Doser et Christophe Grojean, physiciens du CERN vous invitent à mettre en lumière (!) les constituants de base de la matière et à explorer les mystères de la physique contemporaine. Une soirée lumineuse pour éclairer des concepts et ne plus avoir peur du noir. [ What if we made a trip to the physicists in the dark? From astrophysics to particle physics the three blacks, dark matter, dark energy or antimatter intrigue and fascinate. What are these objects that jostle our ideas and sometimes convey irrational fears? Luis Alvarez-Gaume, Michael Doser and Christophe Grojean, CERN physicists invite you to highlight (!) The basic constituents of matter and to explore the mysteries of contemporary physics. A bright evening to illuminate concepts and not be afraid of the dark.

Synthese de champs sonores adaptative

NASA Astrophysics Data System (ADS)

Gauthier, Philippe-Aubert

La reproduction de champs acoustiques est une approche physique au probleme technologique de la spatialisation sonore. Cette these concerne l'aspect physique de la reproduction de champs acoustiques. L'objectif principal est l'amelioration de la reproduction de champs acoustiques par "synthese de champs acoustiques" ("Wave Field Synthesis", WFS), une approche connue, basee sur des hypotheses de champ libre, a l'aide du controle actif par l'ajout de capteurs de l'erreur de reproduction et d'une boucle fermee. Un premier chapitre technique (chapitre 4) expose les resultats d'appreciation objective de la WFS par simulations et mesures experimentales. L'effet indesirable de la salle de reproduction sur les qualites objectives de la WFS fut illustre. Une premiere question de recherche fut ensuite abordee (chapitre 5), a savoir s'il est possible de reproduire des champs progressifs en salle dans un paradigme physique de controle actif: cette possibilite fut prouvee. L'approche technique privilegiee, "synthese de champs adaptative" ("Adaptive Wave Field Synthesis" [AWFS]), fut definie, puis simulee (chapitre 6). Cette approche d'AWFS comporte une originalite en controle actif et en reproduction de champs acoustiques: la fonction cout quadratique representant la minimisation des erreurs de reproduction inclut une regularisation de Tikhonov avec solution a priori qui vient de la WFS. L'etude de l'AWFS a l'aide de la decomposition en valeurs singulieres (chapitre 7) a permis de comprendre les mecanismes propres a l'AWFS. C'est la deuxieme principale originalite de la these. L'algorithme FXLMS (LMS et reference filtree) est modifie pour l'AWFS (chapitre 8). Le decouplage du systeme par decomposition en valeurs singulieres est illustre dans le domaine du traitement de signal et l'AWFS basee sur le controle independant des modes de rayonnement est simulee (chapitre 8). Ce qui constitue la troisieme originalite principale de cette these. Ces simulations du traitement de signal montrent l'efficacite des algorithmes et la capacite de l'AWFS a attenuer les erreurs attribuables a des reflexions acoustiques. Le neuvieme chapitre presente des resultats experimentaux d'AWFS. L'objectif etait de valider la methode et d'evaluer les performances de l'AWFS. Un autre algorithme prometteur est aussi teste. Les resultats demontrent la bonne marche de l'AWFS et des algorithmes testes. Autant dans le cas de la reproduction de champs harmoniques que dans le cas de la reproduction de champs a large bande, l'AWFS reduit l'erreur de reproduction de la WFS et les effets indesirables causes par les lieux de reproduction.

Age related changes in pelvis size among adolescent and adult females with reference to parturition from Naraingarh, Haryana (India).

PubMed

Sharma, Krishan; Gupta, Puneet; Shandilya, Shailza

2016-08-01

This research examines the ontogenic patterns of changes in growth during adolescence, pelvis variations and growth during twenties and thirties of age, structural remodeling of pelvis related to childbirth and relationship of pelvis area with physique based on the cross-sectional data on 391 females from the state of Haryana. Peak growth velocity for body height and breadths of skeletal traits occurred between 11 and 12 years, much before mean age of menarche at 13.5 years; while for body weight and body mass index (BMI) occurred between 14 and 15 years, after the mean age of menarche. Untill the age 11 years, 11.87% of growth in stature was remaining, 19.37% for bi-cristal breadth, 25.96% for bi-ischial breadth and 35.82% for pelvic area. The hypothesis of critical value of pelvic width of 240mm at iliocristale for menarche to occur has been only a statistical association. Higher prevalence of malnutrition during pubertal phase than pre- and post-pubertal phases was due to greater nutritional needs during puberty. Among adult females, BMI was very poorly correlated with stature but very strongly correlated with body breadths, body breadth-stature indices and body weight. The body mass and pelvis size continued to change during 20s and first half of 30s. The continued increase of BMI was due to increase in body fat and muscle mass in females 18 years and older. To tease apart age and parturition effects on pelvis variations, the analysis showed that pelvic bones remodeling took place after the first child was born and not after the subsequent births, and it was a sign of childbirth phenotypic plasticity rather than age. Pelvis area was strongly associated with stature, BMI and age. Mean pelvic area of tall females was greater than those of medium and short stature. Females with broad shoulders had significantly greater mean pelvis area than those with narrow shoulders and medium shoulders. Females having thin/lean physique had the smallest mean pelvis area compared to those having medium and obese types of physiques. The stepwise multiple regression analysis revealed that BMI was the major determinant factor (multiple r=0.37) of pelvis area; addition of stature component increased the value of multiple r to 0.50, while addition of age marginally increased multiple r to 0.53. Copyright © 2016 Elsevier GmbH. All rights reserved.

The Scoring of Integrative Complexity as a Tool in Forecasting Adversary Intentions: Three Case Studies

DTIC Science & Technology

2010-04-01

certaines crises internationales. En analysant des documents et des archives sonores remis par des chefs nationaux et des groupes dirigeants, on a constaté...de lettres, de notes officielles, etc., de chefs et de groupes dirigeants identifiés, comme les conseils de ministre ou des équipes de résolution...Voulant conserver le pouvoir, les fidèles de Mugabe ont lancé une série d’attaques physiques contre les chefs et les membres de l’opposition, et ce

Transcendental Meditation

ScienceCinema

None

2017-12-09

K.Wallace, qui vient des Etats Unis, parle des effects physiologiques de la méditation transcendantale. Il a fait son bachelor en physique à l'Université de Los Angeles et son doctorat en physiologie aussi à Los Angeles, mais à l'Institut de Recherche sur le cerveau. Il travaille maintenat à Harvard Medical School ou il continue des recherches biochimiques et physiologiques sur l'application médicale de la méditation transcendantale. Il s'occupe principalement des maladies cardiaques et de hypertension artérielle.

Modelling of Molecular Structures and Properties in Physical Chemistry and Biophysics, Forty-Fourth International Meeting (Modelisation des Structures et Proprietes Moleculaires en Chimie Physique et en Biophysique, Quarante- Quatrieme Reunion Internationale)

DTIC Science & Technology

1989-09-01

pyridone).Previous work on, py/ridimum, pyrazinjumn or pyrimidi im salts Koon 2 -pyrimloone and 2 - pyrimidone salts [43j have shown that some...forces. Acct . r ~[U... •K;.i. LJ , ’ 0, ’’ .t_I ..- .It . ( :.. 2 A VIBRATIONAL MOLECULAR FORCE FIELD FOR .ACROMOLECULA-R MODELLI= Gerard VERGOTENi...microscopic point of view are (1) understanding, ( 2 ) interpretation of experimental results, (3) semiquantitative estimates of experimental results and (4

A scientist born in amiens : jacques rohault (1620-1672) (French Title: Un savant amiénois : jacques rohault (1620-1672))

NASA Astrophysics Data System (ADS)

Le Boeuffle, A.

2004-12-01

Jacques Rohault is born in Amiens town at the beginning of the seventeen century. After the Middle Ages, science try to use nex methods and want to abandon Greek's dogmas. Rohault came to Paris to continue his studies and met J.B. Poquelin (Molière). He became a friend an a supporter of René Descartes. He was a very popular scientist. He practised many experiments in public and writed the book La physique to popularize science.

U.S. truck driver anthropometric study and multivariate anthropometric models for cab designs.

PubMed

Guan, Jinhua; Hsiao, Hongwei; Bradtmiller, Bruce; Kau, Tsui-Ying; Reed, Matthew R; Jahns, Steven K; Loczi, Josef; Hardee, H Lenora; Piamonte, Dominic Paul T

2012-10-01

This study presents data from a large-scale anthropometric study of U.S. truck drivers and the multivariate anthropometric models developed for the design of next-generation truck cabs. Up-to-date anthropometric information of the U.S. truck driver population is needed for the design of safe and ergonomically efficient truck cabs. We collected 35 anthropometric dimensions for 1,950 truck drivers (1,779 males and 171 females) across the continental United States using a sampling plan designed to capture the appropriate ethnic, gender, and age distributions of the truck driver population. Truck drivers are heavier than the U.S.general population, with a difference in mean body weight of 13.5 kg for males and 15.4 kg for females. They are also different in physique from the U.S. general population. In addition, the current truck drivers are heavier and different in physique compared to their counterparts of 25 to 30 years ago. The data obtained in this study provide more accurate anthropometric information for cab designs than do the current U.S. general population data or truck driver data collected 25 to 30 years ago. Multivariate anthropometric models, spanning 95% of the current truck driver population on the basis of a set of 12 anthropometric measurements, have been developed to facilitate future cab designs. The up-to-date truck driver anthropometric data and multivariate anthropometric models will benefit the design of future truck cabs which, in turn, will help promote the safety and health of the U.S. truck drivers.

Recognition of body image and food behavior factors among middle school students in San Francisco area

PubMed Central

2007-01-01

The purpose of this study was to determine the recognition of body image and food behavior factors according to the BMI. The subjects of this study were 242 7th grade students resided in San Francisco area. The degree of recognition for self-estimated physique of subjects by gender and by race showed no significant differences by gender but significant differences by race, showing that 20.0% was considered as underweight in Asian and 7.5% was considered as underweight in White students. This showed the same tendency as actual physique status (BMI). Also, the ratio of being recognized as more than overweight was 17.3% in Asian, 23.3% in Hispanic, and 13.4% in White students. In case of female students, the ratio of dieting experience was 63.3%, and 49.3% of White students and 63.3% of Hispanic students experienced dieting. In case of students answered not healthy, their body weight were significantly higher than those answered as healthy, and the BMI was also over 19, showing significant differences. Thus cases that answered as not healthy had greater body weight and BMI. Also it showed that frequent dieting experience is related to higher height and weight. The analysis of food behavior factors perceived by body shape showed that the group perceived itself as overweight consumed more 'fast food' but had low scores in 'vegetables' intake, with frequent intake of 'soda' and tendency to 'overeat'. Also, the tendency for 'balanced life' was significantly lower and for skipping breakfast was significantly higher, suggesting problematic food behavior. PMID:20535383

Agression sexuelle et violence dans les relations amoureuses : Le rôle médiateur du stress post-traumatique

PubMed Central

Hébert, Martine; Daspe, Marie-Ève; Blais, Martin; Lavoie, Francine; Guerrier, Mireille

2017-01-01

Résumé Cette étude vise à documenter le rôle médiateur des symptômes de stress post-traumatique (SSPT) dans le lien entre l’agression sexuelle et différentes formes de victimisation vécues dans le contexte de relations amoureuses. L’étude se fonde sur l’Enquête sur les parcours amoureux des jeunes (PAJ), réalisée au sein de 34 écoles secondaires du Québec. Les jeunes ont rempli un questionnaire portant sur leurs expériences de victimisation, y compris l’agression sexuelle vécue pendant l’enfance et la violence psychologique, physique et sexuelle vécue au sein de leurs relations amoureuses dans les 12 derniers mois. Les SSPT ont été évalués à l’aide du UCLA PTSD Index. Sur un total de 8 194 adolescents, 15% des filles et 4% des garçons ont rapporté avoir vécu une agression sexuelle. Les résultats des analyses acheminatoires semblent indiquer que le fait d’avoir été victime d’agression sexuelle est associé à davantage de SSPT et qu’en retour, les SSPT sont positivement associés à la violence psychologique, physique et sexuelle subie de la part d’un partenaire amoureux. Cette étude comporte des implications pratiques pour la prévention et l’intervention sur le plan de la violence dans les relations amoureuses chez les victimes d’agression sexuelle. PMID:29321695

Do Bodybuilders Use Evidence-Based Nutrition Strategies to Manipulate Physique?

PubMed Central

Gifford, Janelle; Estermann, Frederico

2017-01-01

Competitive bodybuilders undergo strict dietary and training practices to achieve an extremely lean and muscular physique. The purpose of this study was to identify and describe different dietary strategies used by bodybuilders, their rationale, and the sources of information from which these strategies are gathered. In-depth interviews were conducted with seven experienced (10.4 ± 3.4 years bodybuilding experience), male, natural bodybuilders. Participants were asked about training, dietary and supplement practices, and information resources for bodybuilding strategies. Interviews were transcribed verbatim and analyzed using qualitative content analysis. During the off-season, energy intake was higher and less restricted than during the in-season to aid in muscle hypertrophy. There was a focus on high protein intake with adequate carbohydrate to permit high training loads. To create an energy deficit and loss of fat mass, energy intake was gradually and progressively reduced during the in-season via a reduction in carbohydrate and fat intake. The rationale for weekly higher carbohydrate refeed days was to offset declines in metabolic rate and fatigue, while in the final “peak week” before competition, the reasoning for fluid and sodium manipulation and carbohydrate loading was to enhance the appearance of leanness and vascularity. Other bodybuilders, coaches and the internet were significant sources of information. Despite the common perception of extreme, non-evidence-based regimens, these bodybuilders reported predominantly using strategies which are recognized as evidence-based, developed over many years of experience. Additionally, novel strategies such as weekly refeed days to enhance fat loss, and sodium and fluid manipulation, warrant further investigation to evaluate their efficacy and safety.

Studies of human physique and sexual attractiveness: sexual preferences of men and women in China.

PubMed

Dixson, Barnaby J; Dixson, Alan F; Li, Baoguo; Anderson, M J

2007-01-01

Men and women at Northwest University (n = 631), Xi'an, China, were asked to rate the attractiveness of male or female figures manipulated to vary somatotype, waist-to-hip ratio (WHR), secondary sexual traits, and other features. In study 1, women rated the average masculine somatotype as most attractive, followed by the mesomorphic (muscular), ectomorphic (slim), and endomorphic (heavily built) somatotypes, in descending order of preference. In study 2, the amount and distribution of masculine trunk (chest and abdominal) hair were altered progressively in a series of front-posed figures. Women rated figures with no or little trunk hair as most attractive. Study 3 assessed the attractiveness of front-posed male figures which varied only in length of their nonerect penis. Numerical ratings for this trait were low, but moderate lengthening of the penis (22% or 33% above average) resulted in a significant increase in scores for attractiveness. In study 4, Chinese men rated the attractiveness of back-posed female images varying in waist-to-hip ratio (WHR from 0.5-1.0). The 0.6 WHR figure was most preferred, followed by 0.7, while figures with higher ratios (0.9 or 1.0) were significantly less attractive. Study 5 rated the attractiveness of female skin color: men expressed a marked preference for images which were lighter in color, as compared to images of average or darker skin colors. These results, the first of their kind reported for a Chinese population, support the view that sexual selection has influenced the evolution of human physique and sexual attractiveness in men and women.

Still life with less: North Korean young adult defectors in South Korea show continued poor nutrition and physique.

PubMed

Choi, Seul Ki; Park, Sang Min; Joung, Hyojee

2010-04-01

North Korean defectors who settle in South Korea have experienced severe food shortage and transition of food environment which could affect their health status. However, little is known about their anthropometric measurements and dietary intake after settlement in South Korea. The purpose of this study is to compare anthropometric measurements and dietary intake between North Korean young adults who defected to South Korea and those of South Koreans. We hypothesized that North Korean young adults' physiques and dietary intake would be poorer than that of South Koreans. We compared anthropometric measurements and dietary intake from 3-day food records in a cross-sectional study of 103 North Korean young adult defectors, aged 12 to 24 and 309 South Korean subjects. North Korean subjects were significantly shorter (4.9 to 10.8 cm) and lighter (6.0 to 12.5 kg) than the control group. Body mass index were significantly different between North and South Korean groups only in men. North Korean young adult defectors had lower mean daily intakes of energy and most nutrients and food groups compared to the control group, while North Korean subjects had higher nutrient density diet than that of South Koreans. The proportion of subjects who had dietary intakes of nutrients of less than the Estimated Average Requirement was higher in North Korean subjects than in controls except for in the cases of vitamin A and vitamin C. In conclusion, we recommend providing nutrition support programs for North Korean young adult defectors to secure adequate nutrient intake.

Social physique anxiety and disturbed eating attitudes and behaviors in adolescents: moderating effects of sport, sport-related characteristics, and gender.

PubMed

Lanfranchi, Marie-Christine; Maïano, Christophe; Morin, Alexandre J S; Therme, Pierre

2015-02-01

The involvement of adolescents presenting high levels of social physique anxiety (SPA) in sport practice has been hypothesized as potentially problematic in terms of being associated with disturbed eating attitudes and behaviors (DEAB). Indeed, sport practice itself has been reported to be associated with higher levels of SPA and DEAB, and sport settings may sometimes promote unhealthy life habits. Nevertheless, current studies are few and present several limitations. The objective of the present study was to examine these relationships among adolescents involved or not in various types (i.e., leanness and individual) and contexts (i.e., organized and competitive) of sport practice. The sample included 766 French adolescents (337 boys and 429 girls), aged between 11 and 18 years, involved (n = 335) or not (n = 431) in sport practice. SPA and DEAB were assessed using French adaptations of the SPA scale and the Eating Attitudes Test-26. The results reveal a significant and positive association between SPA and the DEAB scales. Furthermore, they show a positive relationship between SPA and (a) vomiting-purging behaviors in adolescents involved in individual sports and (b) generic DEAB (i.e., a subscale covering fear of getting fat, food preoccupation, and eating-related guilt), particularly in adolescents involved in individual sports. The relationship between SPA and DEAB does not differ according to adolescents' involvement in sport practice or according to their involvement in organized, competitive, or leanness sport practice more specifically. However, higher levels of SPA and DEAB were observed in adolescents involved in individual sports.

Nutritional and environmental studies on an ocean-going oil tanker. 3. Energy balances and physique

PubMed Central

Eddy, T. P.; Stock, Anne L.; Wheeler, Erica F.

1971-01-01

Eddy, T. P., Stock, Anne L., and Wheeler, Erica F. (1971).Brit. J. industr. Med.,28, 330-341. Nutritional and environmental studies on an ocean-going oil tanker. 3. Energy balances and physique. During the voyage of the oil tanker S.S. Esso Newcastle to the Persian Gulf(July to August, 1967) the average dietary intake of the whole ship's complement was measured on eight days at different periods of the voyage. In addition, the individual intakes of six subjects (three crew and three students) were measured on three occasions over periods of three days. Estimates were also made of the energy expenditures of three members of the crew and body weight and skinfold thickness were measured. Energy expenditure balanced energy intake in two of the crew members investigated. In the third crew subject, expenditure exceeded intake and there was a slight loss of weight. Two out of the three student subjects showed a significant gain in weight by the end of the voyage. The average calorie intake for the ship was 15·07 megajoules (MJ) (3600 kcal) per man per day (of which 13·23 MJ (3160 kcal) were derived from non-alcoholic sources). This is the United Kingdom recommended intake for very active men. Issues on the Esso Newcastle were 18·83 MJ (4500 kcal)/man/day; the difference between provision and consumption was found to be similar to that reported for Scandinavian vessels. Though the crew tended to be heavier than British landsmen, they did not appear to be abnormally fat. Weight was attributable to muscularity. PMID:5124833

Cumulants and large deviations of the current through non-equilibrium steady states

NASA Astrophysics Data System (ADS)

Bodineau, Thierry; Derrida, Bernard

2007-06-01

Using a generalisation of detailed balance for systems maintained out of equilibrium by contact with 2 reservoirs at unequal temperatures or at unequal densities, one can recover the fluctuation theorem for the large deviation function of the current. For large diffusive systems, we show how the large deviation function of the current can be computed using a simple additivity principle. The validity of this additivity principle and the occurrence of phase transitions are discussed in the framework of the macroscopic fluctuation theory. To cite this article: T. Bodineau, B. Derrida, C. R. Physique 8 (2007).

Real-Time Physiological and Psycho-Physiological Status Monitoring (Suivi en Temps reel de l’Etat Physiologique et Psycho-Physiologique)

DTIC Science & Technology

2010-07-01

des Maquis du Grésivaudan 38702 La Tronche Cedex Phone: +33 4 7663 6975 Fax: +33 4 7663 6945 email: lionelbourdon@crssa.net VC...imassa.fr ICT Chantal JIMENEZ CRSSA/Unité de l’Exercice Physique & Hydromineral 24, av. des Maquis du Grésivaudan BP 87 38702 La Tronche Cedex...d’un état physiologique associé à une mesure de fiabilité des données, etc. Le chapitre du Dr. Gunga énumère les méthodologies d’évaluation des

Retirement Kjell Johnsen

ScienceCinema

None

2017-12-09

A l'occasion de son 65me anniversaire plusieurs orateurs (aussi l'ambassadeur de Norvège) remercient Kjell Johnsen, né en juin 1921 en Norvège, pour ses 34 ans de service au Cern et retracent sa vie et son travail. K.Johnsen a pris part aux premières études sur les accélérateurs du futur centre de physique et fut aussi le père et le premier directeur de l'Ecole du Cern sur les accélérateurs (CAS)

The Problem of Preconcentration of Uranium Ores by Physical Processes; LES PROBLEMES DE LA PRECONCENTRATION DES MINERAIS D'URANIUM PAR VOIE PHYSIQUE. LE TRIAGE ELECTRONIQUE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vuchot, L.; Ginocchio, A. et al.

1959-10-31

As uranium ores, like most other ores, are not definite substances which can be treated directly for the production of the metal, the ores must be concentrated. The common physical processes used for all ores, such as sieving, gravimetric separation, flotation, electromagnetic separation, and electrostatic separation, are applicable to the beneficiation of uranium. The radioactivity of uranium ores has led to a radiometric method for the concentration. This method is described in detail. As an example, the preconcentration of Forez ores is discussed. (J.S.R.)

Modelling of Molecular Structures and Properties. Proceedings of the International Meeting of Physical Chemistry on Modeling of Molecular Structures and Properties in Physical Chemistry and Biophysics Organized by the Division de Chimie Physique of the Societe Francaise de Chimie Held in Nancy, France on 11-15 September 1989

DTIC Science & Technology

1990-01-01

expert systems, "intelligent" computer-aided instruction , symbolic learning . These aspects will be discussed, focusing on the specific problems the...VLSI chips) according to preliminary specifications. Finally ES are also used in computer-aided instruction (CAI) due to their ability of... instructions to process controllers), academic teaching (for mathematics , physics, foreign language, etc.). Domains of application The different

Dynamique d'un oscillateur photoréfractif : instabilités et analogie avec la loi de Curie-Weiss

NASA Astrophysics Data System (ADS)

Mathey, P.; Odoulov, S. G.; Rytz, D.

2002-06-01

La dynamique et l'état stationnaire du faisceau issu d'une cavité oscillante comprenant un cristal non-linéaire de titanate de baryum utilisé en tant que miroir à conjugaison de phase sont étudiés. Le paramètre du système étant le gain du milieu non-linéaire, les dépendances de l'intensité de l'oscillation et de l'inverse du temps de réponse sont similaires aux lois de Curie en physique du solide.

Using hegemonic masculinity to explain gay male attraction to muscular and athletic men.

PubMed

Lanzieri, Nicholas; Hildebrandt, Tom

2011-01-01

This article reviews relevant research on male homosexual attraction. Utilizing masculinity as its theoretical frame, the authors use childhood experiences with both fathers and peers, the gay community's inculcation of heteronormative ideologies, and the gay media's adherence to masculine prototypes, to provide causal explanations for the appeal of muscular, lean, and athletic physiques. While the authors acknowledge that not all individuals within the gay community look toward muscularity and athleticism as the primary components of attractiveness, it nonetheless remains important to examine the theoretical perspectives that may explain the appeal of this specific aesthetic.

Shin Clearance in the Hawk Mk115

DTIC Science & Technology

2008-01-01

represented by the Minister of National Defence, 2008 © Sa Majesté la Reine (en droit du Canada), telle que représentée par le ministre de la Défense... de sélection anthropométrique pour les pilotes. La nouvelle norme base l’acceptation ou le rejet des candidats selon qu’ils sont physiquement...compatibles avec les postes de pilotage de la flotte; la norme précédente n’était pas aussi spécifique. En conséquence, la compatibilité des élèves pilotes

Relaxation plastique d'un film mince par émission de dislocations filantes vis

NASA Astrophysics Data System (ADS)

Bonnet, Roland; Youssef, Sami; Neily, Salem; Gutakowskii, A. K.

2008-03-01

The system formed by a thin film coherent with a crystalline substrate can relax its internal energy by annealing. Threading dislocations emitted after ten minutes annealing at 350 °C of the Si 0.68Ge 0.32/Si(001) heterostructure are observed in transmission electron microscopy, and then identified by comparison to simulated images of angular dislocations placed in a semi infinite medium. They are of screw character, which explains the rapid coverage of the interface by 60° dislocations oriented <110>. To cite this article: R. Bonnet et al., C. R. Physique 9 (2008).

Comprendre. La détection des ondes gravitationnelles

NASA Astrophysics Data System (ADS)

Man, Catherine Nary

2017-12-01

Détecter les ondes gravitationnelles sur Terre est un défi fou relevé depuis les années 80. Cette infime vibration de l'espacetemps chère à Einstein et prédite par lui il y a plus de cent ans, est enfin mesurée par trois interféromètres géants dont un européen Virgo et deux américains LIGO, tous trois mis au point depuis presque deux décennies et travaillant en étroite collaboration dans tous les domaines de la physique.

[Comparative study of retention of a Zn phosphate cement and 4-META].

PubMed

Maroto Garcia, J

1990-12-01

The recent appearance, in the market of the supercements, suggest to us, news concepts of retention-adhesion, of our preparations, that they are going to put in to the mouth. Between his applications, we have the cementation of crowns, post or dowels, adhesive-prosthesis, and inlays. According to the manufactures, the long duration of the bond power, his great physiques properties, and his easy management, gives to this products a good conditions, to use in the mouth. The present report to prove in vitro, the retentive capacity on the dentine without treatment, and metal.

Memorial V.J.Glaser

ScienceCinema

None

2017-12-09

Plusieurs orateurs rendent hommage au grand physicien et scientifique Vladimir Jurko Glaser (1924 - 1984) qui travaillait au Ruder Boscovic Institut à Zagreb avant de venir au Cern en 1957 où il trouvait un poste permanent au département de physique théorique. Walter Tearing, Harry Lehmann,Henry Epstein, Jacques Bros et André Martin font des résumés biographiques de leurs collègue et ami en honorant ses grands qualités d'homme et ses remarquables conquêtes de la science et leurs accomplissement.

Traitements didactiques preventifs d'un type de conceptions erronees en sciences physiques chez des eleves du secondaire

NASA Astrophysics Data System (ADS)

Blondin, Andre

Dans un contexte constructiviste, les connaissances anterieures d'un individu sont essentielles a la construction de nouvelles connaissances. Quelle qu'en soit la source (certaines de ces connaissances ont ete elaborees en classe, d'autres ont ete elaborees par interaction personnelle de l'individu avec son environnement physique et social), ces connaissances, une fois acquises, constituent les matieres premieres de l'elaboration des nouvelles conceptions de cet individu. Generalement, cette influence est consideree comme positive. Cependant, dans un milieu scolaire ou l'apprentissage de certaines conceptions enchassees dans un programme d'etudes et enterinees par l'ensemble d'une communaute est obligatoire, certaines connaissances anterieures peuvent entraver la construction des conceptions exigees par la communaute. La litterature abonde de tels exemples. Cependant, certaines connaissances anterieures, en soi tout a fait conformes a l'Heritage, peuvent aussi, parce qu'utilisees de facon non pertinente, entraver la construction d'une conception exigee par la communaute. Ici, la litterature nous donne peu d'exemples de ce type, mais nous en fournirons quelques-uns dans le cadre theorique, et ce sera un d'entre eux qui servira de base a nos propos. En effet, une grande proportion d'eleves inscrits a un cours de sciences physiques de la quatrieme secondaire, en reponse a un probleme deja solutionne durant l'annee et redonne lors d'un examen sommatif, "Pourquoi la Lune nous montre-t-elle toujours la meme face?", attribue principalement la cause de ce phenomene a la rotation de la Terre sur son axe. En tant que responsable de l'enseignement de ce programme d'etudes, plusieurs questions nous sont venues a l'esprit, entre autres, comment, dans un contexte constructiviste, est-il possible de reduire chez un eleve, l'impact de cette connaissance anterieure dans l'elaboration de la solution et ainsi prevenir la construction d'une conception erronee? Nous avons teste nos hypotheses avec la cohorte suivante d'eleves chez qui se repetaient les memes conditions d'apprentissage. Nous avons utilise le design de recherche "posttest only" de Campbell et Stanley. En mai, apres le moment prevu dans la planification du programme pour donner le probleme aux eleves, nous avons suggere deux facons differentes de reviser la solution de ce probleme. Les eleves du premier groupe experimental ont revise sans que soit activee la connaissance anterieure apprehendee de la rotation de la Terre. Les eleves du deuxieme groupe experimental ont ete confrontes, par des questions et une simulation, au fait que la rotation de la Terre n'est pas une connaissance pertinente pour resoudre le probleme. Les groupes temoins et les groupes experimentaux ont ete choisis au hasard dans le bassin des ecoles secondaires de la commission scolaire. (Abstract shortened by UMI.)

Etudes physiques des mélanges eau-cryoprotecteurs

NASA Astrophysics Data System (ADS)

Vassoille, R.; Perez, J.

The aim of the following review is to present the most important studies concerning the physical properties of water-solutes mixtures used in cryobiology. Cryobiology is a branch of biology which deals with the very low temperature behaviour of cells. This technique is developed today in several directions. The creation of banks of cells and perhaps in a short time of small organs, is the purpose of much research in this domain. Before freezing, living cells are generally put in a solution containing one or more solutes. The role of these solutes is to protect the cells against damage due to crystallization of water (cryoprotectors). The mechanisms of cryoprotection are not well known ; nevertheless the vitreous state formation during cooling is often invoked. So, it is possible to avoid crystallization damage such as mechanical strain (due to an increase of volume of about 10 %) and salt effects (due to osmotic pressure). The conditions in which the vitreous state is obtained, maintained during cooling, storage at low temperature and rewarming can be defined by physical studies presented in the following review. Le présent travail est essentiellement une revue bibliographique des principales études physiques qui ont été réalisées avec des solutions de composés habituellement employés en cryobiologie. La cryobiologie est une branche de la biologie qui s'intéresse au comportement des cellules à basse température. Cette discipline est actuellement en plein développement dans des domaines très divers. Son principal but est la création de banques de cellules de plus en plus complexes avec comme perspective la conservation des organes. Les cellules vivantes sont généralement placées avant congélation dans une solution contenant divers composés dont le rôle est de protéger les cellules contre les effets de la cristallisation de l'eau. L'action protectrice de ces cryoprotecteurs est encore mal connue; cependant, la formation d'un état vitreux lors du refroidissement est souvent invoquée. Ainsi, il est possible d'éviter les dommages liés à la cristallisation : contrainte mécanique due à l'augmentation de volume, effets de sel dus à l'existence d'un gradient de pression osmotique de part et d'autre de la membrane cellulaire. Les conditions d'obtention et de maintien de cet état vitreux lors des opérations de congélation peuvent être définies par des études physiques dont nous proposons une revue.

Influence of subject presentation on interpretation of body composition change after 6 months of self-selected training and diet in athletic males.

PubMed

Kerr, Ava D; Slater, Gary J; Byrne, Nuala M

2018-06-01

High precision body composition assessment methods accurately monitor physique traits in athletes. The acute impact of subject presentation (ad libitum food and fluid intake plus physical activity) on body composition estimation using field and laboratory methods has been quantified, but the impact on interpretation of longitudinal change is unknown. This study evaluated the impact of athlete presentation (standardised versus non-standardised) on interpretation of change in physique traits over time. Thirty athletic males (31.2 ± 7.5 years; 182.2 ± 6.5 cm; 91.7 ± 10.3 kg; 27.6 ± 2.6 kg/m 2 ) underwent two testing sessions on 1 day including surface anthropometry, dual-energy X-ray absorptiometry (DXA), bioelectrical impedance spectroscopy (BIS) and air displacement plethysmography (via the BOD POD), with combinations of these used to establish three-compartment (3C) and four-compartment (4C) models. Tests were conducted after an overnight fast (BASEam) and ~ 7 h later after ad libitum food/fluid and physical activity (BASEpm). This procedure was repeated 6 months later (POSTam and POSTpm). Magnitude of changes in the mean was assessed by standardisation. After 6 months of self-selected training and diet, standardised presentation testing (BASEam to POSTam) identified trivial changes from the smallest worthwhile effect (SWE) in fat-free mass (FFM) and fat mass (FM) for all methods except for BIS (FM) where there was a large change (7.2%) from the SWE. Non-standardised follow-up testing (BASEam to POSTpm) showed trivial changes from the SWE except for small changes in FFM (BOD POD) of 1.1%, and in FM (3C and 4C models) of 6.4 and 3.5%. Large changes from the SWE were found in FFM (BIS, 3C and 4C models) of 2.2, 1.8 and 1.8% and in FM (BIS) of 6.4%. Non-standardised presentation testing (BASEpm to POSTpm) identified trivial changes from the SWE in FFM except for BIS which was small (1.1%). A moderate change from the SWE was found for BOD POD (3.3%) and large for BIS (9.4%) in FM estimations. Changes in body composition utilising non-standardised presentation were more substantial and often in the opposite direction to those identified using standardised presentation, causing misinterpretation of change in physique traits. Standardised presentation prior to body composition assessment for athletic populations should be advocated to enhance interpretation of true change.

PHENIX Collaboration

NASA Astrophysics Data System (ADS)

Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Akimoto, R.; Al-Bataineh, H.; Al-Ta'ani, H.; Alexander, J.; Alfred, M.; Andrews, K. R.; Angerami, A.; Aoki, K.; Apadula, N.; Aphecetche, L.; Appelt, E.; Aramaki, Y.; Armendariz, R.; Aronson, S. H.; Asai, J.; Asano, H.; Aschenauer, E. C.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Bai, M.; Bai, X.; Baksay, G.; Baksay, L.; Baldisseri, A.; Bandara, N. S.; Bannier, B.; Barish, K. N.; Barnes, P. D.; Bassalleck, B.; Basye, A. T.; Bathe, S.; Batsouli, S.; Baublis, V.; Baumann, C.; Baumgart, S.; Bazilevsky, A.; Beaumier, M.; Beckman, S.; Belikov, S.; Belmont, R.; Ben-Benjamin, J.; Bennett, R.; Berdnikov, A.; Berdnikov, Y.; Bhom, J. H.; Bickley, A. A.; Bing, X.; Black, D.; Blau, D. S.; Boissevain, J. G.; Bok, J. S.; Borel, H.; Boyle, K.; Brooks, M. L.; Broxmeyer, D.; Bryslawskyj, J.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Butsyk, S.; Camacho, C. M.; Campbell, S.; Caringi, A.; Castera, P.; Chang, B. S.; Chang, W. C.; Charvet, J.-L.; Chen, C.-H.; Chernichenko, S.; Chi, C. Y.; Chiba, J.; Chiu, M.; Choi, I. J.; Choi, J. B.; Choi, S.; Choudhury, R. K.; Christiansen, P.; Chujo, T.; Chung, P.; Churyn, A.; Chvala, O.; Cianciolo, V.; Citron, Z.; Cleven, C. R.; Cole, B. A.; Comets, M. P.; Conesa del Valle, Z.; Connors, M.; Constantin, P.; Cronin, N.; Crossette, N.; Csanád, M.; Csörgő, T.; Dahms, T.; Dairaku, S.; Danchev, I.; Das, K.; Datta, A.; Daugherity, M. S.; David, G.; Dayananda, M. K.; Deaton, M. B.; DeBlasio, K.; Dehmelt, K.; Delagrange, H.; Denisov, A.; d'Enterria, D.; Deshpande, A.; Desmond, E. J.; Dharmawardane, K. V.; Dietzsch, O.; Ding, L.; Dion, A.; Do, J. H.; Donadelli, M.; Drapier, O.; Drees, A.; Drees, K. A.; Dubey, A. K.; Durham, J. M.; Durum, A.; Dutta, D.; Dzhordzhadze, V.; D'Orazio, L.; Edwards, S.; Efremenko, Y. V.; Egdemir, J.; Ellinghaus, F.; Emam, W. S.; Engelmore, T.; Enokizono, A.; En'yo, H.; Esumi, S.; Eyser, K. O.; Fadem, B.; Feege, N.; Fields, D. E.; Finger, M.; Finger, M.; Fleuret, F.; Fokin, S. L.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fujiwara, K.; Fukao, Y.; Fusayasu, T.; Gadrat, S.; Gainey, K.; Gal, C.; Gallus, P.; Garg, P.; Garishvili, A.; Garishvili, I.; Ge, H.; Giordano, F.; Glenn, A.; Gong, H.; Gong, X.; Gonin, M.; Gosset, J.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grim, G.; Grosse Perdekamp, M.; Gu, Y.; Gunji, T.; Guo, L.; Guragain, H.; Gustafsson, H.-Å.; Hachiya, T.; Hadj Henni, A.; Haegemann, C.; Haggerty, J. S.; Hahn, K. I.; Hamagaki, H.; Hamblen, J.; Han, R.; Han, S. Y.; Hanks, J.; Harada, H.; Harper, C.; Hartouni, E. P.; Haruna, K.; Hasegawa, S.; Hashimoto, K.; Haslum, E.; Hayano, R.; Hayashi, S.; He, X.; Heffner, M.; Hemmick, T. K.; Hester, T.; Hiejima, H.; Hill, J. C.; Hobbs, R.; Hohlmann, M.; Hollis, R. S.; Holzmann, W.; Homma, K.; Hong, B.; Horaguchi, T.; Hori, Y.; Hornback, D.; Hoshino, T.; Huang, J.; Huang, S.; Ichihara, T.; Ichimiya, R.; Ide, J.; Iinuma, H.; Ikeda, Y.; Imai, K.; Imazu, Y.; Imrek, J.; Inaba, M.; Inoue, Y.; Iordanova, A.; Isenhower, D.; Isenhower, L.; Ishihara, M.; Isinhue, A.; Isobe, T.; Issah, M.; Isupov, A.; Ivanischev, D.; Ivanishchev, D.; Iwanaga, Y.; Jacak, B. V.; Javani, M.; Jeon, S. J.; Jezghani, M.; Jia, J.; Jiang, X.; Jin, J.; Jinnouchi, O.; John, D.; Johnson, B. M.; Jones, T.; Joo, E.; Joo, K. S.; Jouan, D.; Jumper, D. S.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kamin, J.; Kanda, S.; Kaneta, M.; Kaneti, S.; Kang, B. H.; Kang, J. H.; Kang, J. S.; Kanou, H.; Kapustinsky, J.; Karatsu, K.; Kasai, M.; Kawall, D.; Kawashima, M.; Kazantsev, A. V.; Kempel, T.; Key, J. A.; Khachatryan, V.; Khandai, P. K.; Khanzadeev, A.; Kihara, K.; Kijima, K. M.; Kikuchi, J.; Kim, A.; Kim, B. I.; Kim, C.; Kim, D. H.; Kim, D. J.; Kim, E.; Kim, E.-J.; Kim, H.-J.; Kim, H. J.; Kim, K.-B.; Kim, M.; Kim, S. H.; Kim, Y.-J.; Kim, Y. K.; Kinney, E.; Kiriluk, K.; Kiss, Á.; Kistenev, E.; Kiyomichi, A.; Klatsky, J.; Klay, J.; Klein-Boesing, C.; Kleinjan, D.; Kline, P.; Koblesky, T.; Kochenda, L.; Kochetkov, V.; Kofarago, M.; Komatsu, Y.; Komkov, B.; Konno, M.; Koster, J.; Kotchetkov, D.; Kotov, D.; Kozlov, A.; Král, A.; Kravitz, A.; Krizek, F.; Kubart, J.; Kunde, G. J.; Kurihara, N.; Kurita, K.; Kurosawa, M.; Kweon, M. J.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lai, Y. S.; Lajoie, J. G.; Layton, D.; Lebedev, A.; Lee, B.; Lee, D. M.; Lee, G. H.; Lee, J.; Lee, K.; Lee, K. B.; Lee, K. S.; Lee, M. K.; Lee, S. H.; Lee, S. R.; Lee, T.; Leitch, M. J.; Leite, M. A. L.; Leitgab, M.; Leitner, E.; Lenzi, B.; Lewis, B.; Li, X.; Lichtenwalner, P.; Liebing, P.; Lim, S. H.; Linden Levy, L. A.; Liška, T.; Litvinenko, A.; Liu, H.; Liu, M. X.; Love, B.; Luechtenborg, R.; Lynch, D.; Maguire, C. F.; Makdisi, Y. I.; Ma, M.; Malakhov, A.; Malik, M. D.; Manion, A.; Manko, V. I.; Mannel, E.; Mao, Y.; Maruyama, T.; Mašek, L.; Masui, H.; Masumoto, S.; Matathias, F.; McCumber, M.; McGaughey, P. L.; McGlinchey, D.; McKinney, C.; Means, N.; Meles, A.; Mendoza, M.; Meredith, B.; Miake, Y.; Mibe, T.; Midori, J.; Mignerey, A. C.; Mikeš, P.; Miki, K.; Miller, A. J.; Miller, T. E.; Milov, A.; Mioduszewski, S.; Mishra, D. K.; Mishra, M.; Mitchell, J. T.; Mitrovski, M.; Miyachi, Y.; Miyasaka, S.; Mizuno, S.; Mohanty, A. K.; Montuenga, P.; Moon, H. J.; Moon, T.; Morino, Y.; Morreale, A.; Morrison, D. P.; Moskowitz, M.; Motschwiller, S.; Moukhanova, T. V.; Mukhopadhyay, D.; Murakami, T.; Murata, J.; Mwai, A.; Nagae, T.; Nagamiya, S.; Nagata, Y.; Nagle, J. L.; Naglis, M.; Nagy, M. I.; Nakagawa, I.; Nakagomi, H.; Nakamiya, Y.; Nakamura, K. R.; Nakamura, T.; Nakano, K.; Nam, S.; Nattrass, C.; Nederlof, A.; Netrakanti, P. K.; Newby, J.; Nguyen, M.; Nihashi, M.; Niida, T.; Norman, B. E.; Nouicer, R.; Novak, T.; Novitzky, N.; Nukariya, A.; Nyanin, A. S.; Oakley, C.; Obayashi, H.; O'Brien, E.; Oda, S. X.; Ogilvie, C. A.; Ohnishi, H.; Oide, H.; Oka, M.; Okada, K.; Omiwade, O. O.; Onuki, Y.; Orjuela Koop, J. D.; Oskarsson, A.; Ouchida, M.; Ozaki, H.; Ozawa, K.; Pak, R.; Pal, D.; Palounek, A. P. T.; Pantuev, V.; Papavassiliou, V.; Park, B. H.; Park, I. H.; Park, J.; Park, S.; Park, S. K.; Park, W. J.; Pate, S. F.; Patel, L.; Patel, M.; Pei, H.; Peng, J.-C.; Pereira, H.; Perepelitsa, D. V.; Perera, G. D. N.; Peresedov, V.; Peressounko, D. Yu.; Perry, J.; Petti, R.; Pinkenburg, C.; Pinson, R.; Pisani, R. P.; Proissl, M.; Purschke, M. L.; Purwar, A. K.; Qu, H.; Rak, J.; Rakotozafindrabe, A.; Ravinovich, I.; Read, K. F.; Rembeczki, S.; Reuter, M.; Reygers, K.; Reynolds, D.; Riabov, V.; Riabov, Y.; Richardson, E.; Riveli, N.; Roach, D.; Roche, G.; Rolnick, S. D.; Romana, A.; Rosati, M.; Rosen, C. A.; Rosendahl, S. S. E.; Rosnet, P.; Rowan, Z.; Rubin, J. G.; Rukoyatkin, P.; Ružička, P.; Rykov, V. L.; Ryu, M. S.; Sahlmueller, B.; Saito, N.; Sakaguchi, T.; Sakai, S.; Sakashita, K.; Sakata, H.; Sako, H.; Samsonov, V.; Sano, M.; Sano, S.; Sarsour, M.; Sato, S.; Sato, T.; Savastio, M.; Sawada, S.; Schaefer, B.; Schmoll, B. K.; Sedgwick, K.; Seele, J.; Seidl, R.; Sekiguchi, Y.; Semenov, A. Yu.; Semenov, V.; Sen, A.; Seto, R.; Sett, P.; Sexton, A.; Sharma, D.; Shaver, A.; Shein, I.; Shevel, A.; Shibata, T.-A.; Shigaki, K.; Shim, H. H.; Shimomura, M.; Shoji, K.; Shukla, P.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Silvestre, C.; Sim, K. S.; Singh, B. K.; Singh, C. P.; Singh, V.; Skolnik, M.; Skutnik, S.; Slunečka, M.; Sodre, T.; Solano, S.; Soldatov, A.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Soumya, M.; Sourikova, I. V.; Sparks, N. A.; Staley, F.; Stankus, P. W.; Steinberg, P.; Stenlund, E.; Stepanov, M.; Ster, A.; Stoll, S. P.; Stone, M. R.; Sugitate, T.; Suire, C.; Sukhanov, A.; Sumita, T.; Sun, J.; Sziklai, J.; Tabaru, T.; Takagi, S.; Takagui, E. M.; Takahara, A.; Taketani, A.; Tanabe, R.; Tanaka, Y.; Taneja, S.; Tanida, K.; Tannenbaum, M. J.; Tarafdar, S.; Taranenko, A.; Tarján, P.; Tennant, E.; Themann, H.; Thomas, D.; Thomas, T. L.; Timilsina, A.; Todoroki, T.; Togawa, M.; Toia, A.; Tojo, J.; Tomášek, L.; Tomášek, M.; Tomita, Y.; Torii, H.; Towell, M.; Towell, R.; Towell, R. S.; Tram, V.-N.; Tserruya, I.; Tsuchimoto, Y.; Tsuji, T.; Utsunomiya, K.; Vale, C.; Valle, H.; van Hecke, H. W.; Vargyas, M.; Vazquez-Zambrano, E.; Veicht, A.; Velkovska, J.; Vértesi, R.; Vinogradov, A. A.; Virius, M.; Voas, B.; Vossen, A.; Vrba, V.; Vznuzdaev, E.; Wagner, M.; Walker, D.; Wang, X. R.; Watanabe, D.; Watanabe, K.; Watanabe, Y.; Watanabe, Y. S.; Wei, F.; Wei, R.; Wessels, J.; Whitaker, S.; White, S. N.; Winter, D.; Wolin, S.; Wood, J. P.; Woody, C. L.; Wright, R. M.; Wysocki, M.; Xia, B.; Xie, W.; Xue, L.; Yalcin, S.; Yamaguchi, Y. L.; Yamaura, K.; Yang, R.; Yanovich, A.; Yasin, Z.; Ying, J.; Yokkaichi, S.; Yoo, J. S.; Yoon, I.; You, Z.; Young, G. R.; Younus, I.; Yushmanov, I. E.; Zajc, W. A.; Zaudtke, O.; Zelenski, A.; Zhang, C.; Zhou, S.; Zimányi, J.; Zolin, L.

2014-12-01

We thank the staff of the Collider-Accelerator and Physics Departments at Brookhaven National Laboratory and the staff of the other PHENIX participating institutions for their vital contributions. We acknowledge support from the Office of Nuclear Physics in the Office of Science of the Department of Energy, the National Science Foundation, a sponsored research grant from Renaissance Technologies LLC, Abilene Christian University Research Council, Research Foundation of SUNY, and Dean of the College of Arts and Sciences, Vanderbilt University (USA), Ministry of Education, Culture, Sports, Science, and Technology and the Japan Society for the Promotion of Science (Japan), Conselho Nacional de Desenvolvimento Científico e Tecnológico and Fundação de Amparo à Pesquisa do Estado de São Paulo (Brazil), Natural Science Foundation of China, (People's Republic of China), Ministry of Science, Education, and Sports (Croatia), Ministry of Education, Youth and Sports (Czech Republic), Centre National de la Recherche Scientifique, Commissariat à l'Énergie Atomique, and Institut National de Physique Nucléaire et de Physique des Particules (France), Bundesministerium für Bildung und Forschung, Deutscher Akademischer Austausch Dienst, and Alexander von Humboldt Stiftung (Germany), OTKA NK 101 428 grant and the Ch. Simonyi Fund (Hungary), Department of Atomic Energy and Department of Science and Technology (India), Israel Science Foundation (Israel), National Research Foundation and WCU program of the Ministry Education Science and Technology (Republic of Korea), Physics Department, Lahore University of Management Sciences (Pakistan), Ministry of Education and Science, Russian Academy of Sciences, Federal Agency of Atomic Energy (Russia), VR and Wallenberg Foundation (Sweden), the US Civilian Research and Development Foundation for the Independent States of the Former Soviet Union, and the US-Israel Binational Science Foundation.

PHENIX Collaboration

NASA Astrophysics Data System (ADS)

Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Akimoto, R.; Al-Bataineh, H.; Al-Ta'ani, H.; Alexander, J.; Alfred, M.; Andrews, K. R.; Angerami, A.; Aoki, K.; Apadula, N.; Aphecetche, L.; Appelt, E.; Aramaki, Y.; Armendariz, R.; Aronson, S. H.; Asai, J.; Asano, H.; Aschenauer, E. C.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Bai, M.; Bai, X.; Baksay, G.; Baksay, L.; Baldisseri, A.; Bandara, N. S.; Bannier, B.; Barish, K. N.; Barnes, P. D.; Barnes, P. D.; Bassalleck, B.; Basye, A. T.; Bathe, S.; Batsouli, S.; Baublis, V.; Baumann, C.; Baumgart, S.; Bazilevsky, A.; Beaumier, M.; Beckman, S.; Belikov, S.; Belmont, R.; Ben-Benjamin, J.; Bennett, R.; Berdnikov, A.; Berdnikov, Y.; Bhom, J. H.; Bickley, A. A.; Bing, X.; Black, D.; Blau, D. S.; Boissevain, J. G.; Bok, J.; Bok, J. S.; Borel, H.; Boyle, K.; Brooks, M. L.; Broxmeyer, D.; Bryslawskyj, J.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Butsyk, S.; Camacho, C. M.; Campbell, S.; Caringi, A.; Castera, P.; Chang, B. S.; Chang, W. C.; Charvet, J.-L.; Chen, C.-H.; Chernichenko, S.; Chi, C. Y.; Chiba, J.; Chiu, M.; Choi, I. J.; Choi, J. B.; Choi, S.; Choudhury, R. K.; Christiansen, P.; Chujo, T.; Chung, P.; Churyn, A.; Chvala, O.; Cianciolo, V.; Citron, Z.; Cleven, C. R.; Cole, B. A.; Comets, M. P.; Conesa del Valle, Z.; Connors, M.; Constantin, P.; Cronin, N.; Crossette, N.; Csanád, M.; Csörgő, T.; Dahms, T.; Dairaku, S.; Danchev, I.; Das, K.; Datta, A.; Daugherity, M. S.; David, G.; Dayananda, M. K.; Deaton, M. B.; DeBlasio, K.; Dehmelt, K.; Delagrange, H.; Denisov, A.; d'Enterria, D.; Deshpande, A.; Desmond, E. J.; Dharmawardane, K. V.; Dietzsch, O.; Ding, L.; Dion, A.; Do, J. H.; Donadelli, M.; Drapier, O.; Drees, A.; Drees, K. A.; Dubey, A. K.; Durham, J. M.; Durum, A.; Dutta, D.; Dzhordzhadze, V.; D'Orazio, L.; Edwards, S.; Efremenko, Y. V.; Egdemir, J.; Ellinghaus, F.; Emam, W. S.; Engelmore, T.; Enokizono, A.; En'yo, H.; Esumi, S.; Eyser, K. O.; Fadem, B.; Feege, N.; Fields, D. E.; Finger, M.; Finger, M.; Fleuret, F.; Fokin, S. L.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fujiwara, K.; Fukao, Y.; Fusayasu, T.; Gadrat, S.; Gainey, K.; Gal, C.; Gallus, P.; Garg, P.; Garishvili, A.; Garishvili, I.; Ge, H.; Giordano, F.; Glenn, A.; Gong, H.; Gong, X.; Gonin, M.; Gosset, J.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grim, G.; Grosse Perdekamp, M.; Gu, Y.; Gunji, T.; Guo, L.; Guragain, H.; Gustafsson, H.-Å.; Hachiya, T.; Hadj Henni, A.; Haegemann, C.; Haggerty, J. S.; Hahn, K. I.; Hamagaki, H.; Hamblen, J.; Han, R.; Han, S. Y.; Hanks, J.; Harada, H.; Harper, C.; Hartouni, E. P.; Haruna, K.; Hasegawa, S.; Hashimoto, K.; Haslum, E.; Hayano, R.; Hayashi, S.; He, X.; Heffner, M.; Hemmick, T. K.; Hester, T.; Hiejima, H.; Hill, J. C.; Hobbs, R.; Hohlmann, M.; Hollis, R. S.; Holzmann, W.; Homma, K.; Hong, B.; Horaguchi, T.; Hori, Y.; Hornback, D.; Hoshino, T.; Huang, J.; Huang, S.; Ichihara, T.; Ichimiya, R.; Ide, J.; Iinuma, H.; Ikeda, Y.; Imai, K.; Imazu, Y.; Imrek, J.; Inaba, M.; Inoue, Y.; Iordanova, A.; Isenhower, D.; Isenhower, L.; Ishihara, M.; Isinhue, A.; Isobe, T.; Issah, M.; Isupov, A.; Ivanischev, D.; Ivanishchev, D.; Iwanaga, Y.; Jacak, B. V.; Javani, M.; Jeon, S. J.; Jezghani, M.; Jia, J.; Jiang, X.; Jin, J.; Jinnouchi, O.; John, D.; Johnson, B. M.; Jones, T.; Joo, E.; Joo, K. S.; Jouan, D.; Jumper, D. S.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kamin, J.; Kanda, S.; Kaneta, M.; Kaneti, S.; Kang, B. H.; Kang, J. H.; Kang, J. S.; Kanou, H.; Kapustinsky, J.; Karatsu, K.; Kasai, M.; Kawall, D.; Kawashima, M.; Kazantsev, A. V.; Kempel, T.; Key, J. A.; Khachatryan, V.; Khandai, P. K.; Khanzadeev, A.; Kihara, K.; Kijima, K. M.; Kikuchi, J.; Kim, A.; Kim, B. I.; Kim, C.; Kim, D. H.; Kim, D. J.; Kim, E.; Kim, E.-J.; Kim, H.-J.; Kim, H. J.; Kim, K.-B.; Kim, M.; Kim, S. H.; Kim, Y.-J.; Kim, Y. K.; Kinney, E.; Kiriluk, K.; Kiss, Á.; Kistenev, E.; Kiyomichi, A.; Klatsky, J.; Klay, J.; Klein-Boesing, C.; Kleinjan, D.; Kline, P.; Koblesky, T.; Kochenda, L.; Kochetkov, V.; Kofarago, M.; Komatsu, Y.; Komkov, B.; Konno, M.; Koster, J.; Kotchetkov, D.; Kotov, D.; Kozlov, A.; Král, A.; Kravitz, A.; Krizek, F.; Kubart, J.; Kunde, G. J.; Kurihara, N.; Kurita, K.; Kurosawa, M.; Kweon, M. J.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lai, Y. S.; Lajoie, J. G.; Layton, D.; Lebedev, A.; Lee, B.; Lee, D. M.; Lee, G. H.; Lee, J.; Lee, K.; Lee, K. B.; Lee, K. S.; Lee, M. K.; Lee, S. H.; Lee, S. R.; Lee, T.; Leitch, M. J.; Leite, M. A. L.; Leitgab, M.; Leitner, E.; Lenzi, B.; Lewis, B.; Li, X.; Lichtenwalner, P.; Liebing, P.; Lim, S. H.; Linden Levy, L. A.; Liška, T.; Litvinenko, A.; Liu, H.; Liu, M. X.; Love, B.; Luechtenborg, R.; Lynch, D.; Maguire, C. F.; Makdisi, Y. I.; Maai, M.; Malakhov, A.; Malik, M. D.; Manion, A.; Manko, V. I.; Mannel, E.; Mao, Y.; Maruyama, T.; Mašek, L.; Masui, H.; Masumoto, S.; Matathias, F.; McCumber, M.; McGaughey, P. L.; McGlinchey, D.; McKinney, C.; Means, N.; Meles, A.; Mendoza, M.; Meredith, B.; Miake, Y.; Mibe, T.; Midori, J.; Mignerey, A. C.; Mikeš, P.; Miki, K.; Miller, A. J.; Miller, T. E.; Milov, A.; Mioduszewski, S.; Mishra, D. K.; Mishra, M.; Mitchell, J. T.; Mitrovski, M.; Miyachi, Y.; Miyasaka, S.; Mizuno, S.; Mohanty, A. K.; Montuenga, P.; Moon, H. J.; Moon, T.; Morino, Y.; Morreale, A.; Morrison, D. P.; Moskowitz, M.; Motschwiller, S.; Moukhanova, T. V.; Mukhopadhyay, D.; Murakami, T.; Murata, J.; Mwai, A.; Nagae, T.; Nagamiya, S.; Nagata, Y.; Nagle, J. L.; Naglis, M.; Nagy, M. I.; Nakagawa, I.; Nakagomi, H.; Nakamiya, Y.; Nakamura, K. R.; Nakamura, T.; Nakano, K.; Nam, S.; Nattrass, C.; Nederlof, A.; Netrakanti, P. K.; Newby, J.; Nguyen, M.; Nihashi, M.; Niida, T.; Norman, B. E.; Nouicer, R.; Novak, T.; Novitzky, N.; Nukariya, A.; Nyanin, A. S.; Oakley, C.; Obayashi, H.; O'Brien, E.; Oda, S. X.; Ogilvie, C. A.; Ohnishi, H.; Oide, H.; Oka, M.; Okada, K.; Omiwade, O. O.; Onuki, Y.; Orjuela Koop, J. D.; Oskarsson, A.; Ouchida, M.; Ozaki, H.; Ozawa, K.; Pak, R.; Pal, D.; Palounek, A. P. T.; Pantuev, V.; Papavassiliou, V.; Park, B. H.; Park, I. H.; Park, J.; Park, S.; Park, S. K.; Park, W. J.; Pate, S. F.; Patel, L.; Patel, M.; Pei, H.; Peng, J.-C.; Pereira, H.; Perepelitsa, D. V.; Perera, G. D. N.; Peresedov, V.; Peressounko, D. Yu.; Perry, J.; Petti, R.; Pinkenburg, C.; Pinson, R.; Pisani, R. P.; Proissl, M.; Purschke, M. L.; Purwar, A. K.; Qu, H.; Rak, J.; Rakotozafindrabe, A.; Ravinovich, I.; Read, K. F.; Rembeczki, S.; Reuter, M.; Reygers, K.; Reynolds, D.; Riabov, V.; Riabov, Y.; Richardson, E.; Riveli, N.; Roach, D.; Roche, G.; Rolnick, S. D.; Romana, A.; Rosati, M.; Rosen, C. A.; Rosendahl, S. S. E.; Rosnet, P.; Rowan, Z.; Rubin, J. G.; Rukoyatkin, P.; Ružička, P.; Rykov, V. L.; Ryu, M. S.; Sahlmueller, B.; Saito, N.; Sakaguchi, T.; Sakai, S.; Sakashita, K.; Sakata, H.; Sako, H.; Samsonov, V.; Sano, M.; Sano, S.; Sarsour, M.; Sato, S.; Sato, T.; Savastio, M.; Sawada, S.; Schaefer, B.; Schmoll, B. K.; Sedgwick, K.; Seele, J.; Seidl, R.; Sekiguchi, Y.; Semenov, A. Yu.; Semenov, V.; Sen, A.; Seto, R.; Sett, P.; Sexton, A.; Sharma, D.; Shaver, A.; Shein, I.; Shevel, A.; Shibata, T.-A.; Shigaki, K.; Shim, H. H.; Shimomura, M.; Shoji, K.; Shukla, P.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Silvestre, C.; Sim, K. S.; Singh, B. K.; Singh, C. P.; Singh, V.; Skolnik, M.; Skutnik, S.; Slunečka, M.; Sodre, T.; Solano, S.; Soldatov, A.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Soumya, M.; Sourikova, I. V.; Sparks, N. A.; Staley, F.; Stankus, P. W.; Steinberg, P.; Stenlund, E.; Stepanov, M.; Ster, A.; Stoll, S. P.; Stone, M. R.; Sugitate, T.; Suire, C.; Sukhanov, A.; Sumita, T.; Sun, J.; Sziklai, J.; Tabaru, T.; Takagi, S.; Takagui, E. M.; Takahara, A.; Taketani, A.; Tanabe, R.; Tanaka, Y.; Taneja, S.; Tanida, K.; Tannenbaum, M. J.; Tarafdar, S.; Taranenko, A.; Tarján, P.; Tennant, E.; Themann, H.; Thomas, D.; Thomas, T. L.; Timilsina, A.; Todoroki, T.; Togawa, M.; Toia, A.; Tojo, J.; Tomášek, L.; Tomášek, M.; Tomita, Y.; Torii, H.; Towell, M.; Towell, R.; Towell, R. S.; Tram, V.-N.; Tserruya, I.; Tsuchimoto, Y.; Tsuji, T.; Utsunomiya, K.; Vale, C.; Valle, H.; van Hecke, H. W.; Vargyas, M.; Vazquez-Zambrano, E.; Veicht, A.; Velkovska, J.; Vértesi, R.; Vinogradov, A. A.; Virius, M.; Voas, B.; Vossen, A.; Vrba, V.; Vznuzdaev, E.; Wagner, M.; Walker, D.; Wang, X. R.; Watanabe, D.; Watanabe, K.; Watanabe, Y.; Watanabe, Y. S.; Wei, F.; Wei, R.; Wessels, J.; Whitaker, S.; White, S. N.; Winter, D.; Wolin, S.; Wood, J. P.; Woody, C. L.; Wright, R. M.; Wysocki, M.; Xia, B.; Xie, W.; Xue, L.; Yalcin, S.; Yamaguchi, Y. L.; Yamaura, K.; Yang, R.; Yanovich, A.; Yasin, Z.; Ying, J.; Yokkaichi, S.; Yoo, J. S.; Yoon, I.; You, Z.; Young, G. R.; Younus, I.; Yushmanov, I. E.; Zajc, W. A.; Zaudtke, O.; Zelenski, A.; Zhang, C.; Zhou, S.; Zimányi, J.; Zolin, L.

2014-11-01

We thank the staff of the Collider-Accelerator and Physics Departments at Brookhaven National Laboratory and the staff of the other PHENIX participating institutions for their vital contributions. We acknowledge support from the Office of Nuclear Physics in the Office of Science of the Department of Energy, the National Science Foundation, a sponsored research grant from Renaissance Technologies LLC, Abilene Christian University Research Council, Research Foundation of SUNY, and Dean of the College of Arts and Sciences, Vanderbilt University (USA), Ministry of Education, Culture, Sports, Science, and Technology and the Japan Society for the Promotion of Science (Japan), Conselho Nacional de Desenvolvimento Científico e Tecnológico and Fundaç ao de Amparo à Pesquisa do Estado de São Paulo (Brazil), Natural Science Foundation of China (People's Republic of China), Ministry of Science, Education, and Sports (Croatia), Ministry of Education, Youth and Sports (Czech Republic), Centre National de la Recherche Scientifique, Commissariat à l'Énergie Atomique, and Institut National de Physique Nucléaire et de Physique des Particules (France), Bundesministerium für Bildung und Forschung, Deutscher Akademischer Austausch Dienst, and Alexander von Humboldt Stiftung (Germany), OTKA NK 101 428 grant and the Ch. Simonyi Fund (Hungary), Department of Atomic Energy and Department of Science and Technology (India), Israel Science Foundation (Israel), National Research Foundation and WCU program of the Ministry Education Science and Technology (Korea), Physics Department, Lahore University of Management Sciences (Pakistan), Ministry of Education and Science, Russian Academy of Sciences, Federal Agency of Atomic Energy (Russia), VR and Wallenberg Foundation (Sweden), the US Civilian Research and Development Foundation for the Independent States of the Former Soviet Union, and the US-Israel Binational Science Foundation.

The influence of somatotype on anaerobic performance

PubMed Central

Faulkner, James; Jobson, Simon

2018-01-01

The link between athlete physique and performance in sports is well established. However, a direct link between somatotype three-numeral rating and anaerobic performance has not yet been reported. The purpose of this study was to assess the relations between somatotype and anaerobic performance using both singular and multivariate analyses. Thirty-six physically active males (mean ± standard deviation age 26.0 ± 9.8 years; body mass 79.5 ± 12.9 kg; height 1.82 ± 0.07 m) were somatotype-rated using the Heath-Carter method. Subjects were assessed for 3 repetition maximum (3 RM) bench press and back squat, and completed a 30-second maximal sprint cycle test. Positive correlations were observed between mesomorphy and 3 RM bench press (r = 0.560, p < 0.001), mesomorphy and 3 RM back squat (r = 0.550, p = 0.001) and between mesomorphy and minimum power output (r = 0.357, p = 0.033). Negative correlations were observed between ectomorphy and 3 RM bench press (r = -0.381, p = 0.022), and ectomorphy and 3 RM back squat (r = -0.336, p = 0.045). Individual regression analysis indicated that mesomorphy was the best predictor of 3 RM bench press performance, with 31.4% of variance in 3 RM bench press performance accounted for by the mesomorphy rating (p < 0.001). A combination of mesomorphy and ectomorphy best predicted 3 RM back squat performance (R2 = 0.388, p < 0.04). Around one third of strength performance is predicted by somatotype-assessed physique in physically active males. This could have important implications for the identification of those predisposed to perform well in sports containing strength-based movements and prescription of training programmes. PMID:29787610

The influence of somatotype on anaerobic performance.

PubMed

Ryan-Stewart, Helen; Faulkner, James; Jobson, Simon

2018-01-01

The link between athlete physique and performance in sports is well established. However, a direct link between somatotype three-numeral rating and anaerobic performance has not yet been reported. The purpose of this study was to assess the relations between somatotype and anaerobic performance using both singular and multivariate analyses. Thirty-six physically active males (mean ± standard deviation age 26.0 ± 9.8 years; body mass 79.5 ± 12.9 kg; height 1.82 ± 0.07 m) were somatotype-rated using the Heath-Carter method. Subjects were assessed for 3 repetition maximum (3 RM) bench press and back squat, and completed a 30-second maximal sprint cycle test. Positive correlations were observed between mesomorphy and 3 RM bench press (r = 0.560, p < 0.001), mesomorphy and 3 RM back squat (r = 0.550, p = 0.001) and between mesomorphy and minimum power output (r = 0.357, p = 0.033). Negative correlations were observed between ectomorphy and 3 RM bench press (r = -0.381, p = 0.022), and ectomorphy and 3 RM back squat (r = -0.336, p = 0.045). Individual regression analysis indicated that mesomorphy was the best predictor of 3 RM bench press performance, with 31.4% of variance in 3 RM bench press performance accounted for by the mesomorphy rating (p < 0.001). A combination of mesomorphy and ectomorphy best predicted 3 RM back squat performance (R2 = 0.388, p < 0.04). Around one third of strength performance is predicted by somatotype-assessed physique in physically active males. This could have important implications for the identification of those predisposed to perform well in sports containing strength-based movements and prescription of training programmes.

Relationship of low lean body mass with body weight increase until one year of age and current lifestyles in Japanese young women.

PubMed

Miyamoto, Shoji; Murotani, Kenta; Yanagawa, Takashi; Kato, Atsushi; Matsunaga, Satoshi

2010-06-01

To investigate factors affecting the low lean body mass (LBM) of young women, we focused on the increase in body weight until one year of age and current lifestyles. In 442 young women, the increase in body weight from birth until one year of age, breast-feeding method in infancy, current physique index and body composition, and physique and lifestyles were investigated using a questionnaire. Subjects with an LBM percentile of less than 33.3 (less than 36.8 kg) were classified as having a low LBM (n = 150), and those with a 33.3 or higher LBM percentile as the control (n = 293). Based on body weight changes from birth to days 3 and 7, the subjects were divided into a rapid weight gain group and two non-rapid weight gain groups (groups 1-3). To analyze factors involved in a low LBM, multivariate analysis using a logistic model was employed. The prevalence of a low LBM in the rapid weight gain group was 0.41 times higher than in the others. The prevalence of a low LBM with a low birth weight was 0.58 times higher, indicating that a low birth weight is likely to result in a low LBM. Regarding the lifestyles, the prevalence of a low LBM in subjects with a current breakfasting habit was 0.60 times higher than in those without one. These findings suggest that the thinness of young women characterized by a low LBM is associated with the increase in body weight until one year of age and current lifestyles.

Body image issues in Lithuanian females before and during pregnancy.

PubMed

Tutkuviene, Janina; Juskaite, Austeja; Katinaite, Justina; Silove, Simona; Drasutis, Jonas; Sargautyte, Ruta; Ramasauskaite, Diana; Drasutiene, Grazina

2018-02-01

There is a risk that during pregnancy a woman's changing physique might result in stronger concerns about her appearance and may lead to negative consequences both for mother and foetus. The aim of the present study was to assess women's self-esteem, body image and weight control before and during pregnancy. A cross-sectional study was carried out at the Centre of Obstetrics and Gynaecology of Vilnius University Hospital. In total, 234 pregnant women were investigated. The Self-esteem was measured by Rosenberg's scale (1965), while the attitude towards the body size - by Stunkard's figure rating scale (1983). When rating their actual body size and the preferred body shape using Stunkard's figures, the investigated females chose, on average, 3.40 and 2.93 (respectively) size figures for the period before pregnancy ( p < 0.05), while they picked 4.38 and 3.44 (respectively) figures during pregnancy ( p < 0.05). Women's efforts not to gain weight during pregnancy were not determined by their opinion of their body size during pregnancy ( r s (232) = 0.136, p > 0.05). Regardless of their body shape assessment during pregnancy, pregnant women did not restrict their diet ( r s (232) = 0.064, p > 0.05). Conclusions: during pregnancy women assessed their weight gain adequately, pregnant women chose larger body sizes as an ideal physique if compared to the ones of the period before pregnancy, women's efforts not to gain weight during pregnancy were not determined by their body size perception during pregnancy, pregnant women, despite their body shape assessment during pregnancy, did not restrict their diet, i.e. pregnant women became psychologically adapted to their body changes during pregnancy, and the maternity became a much more important factor than the beauty ideals associated with slender figures.

Body mass prediction from skeletal frame size in elite athletes.

PubMed

Ruff, C B

2000-12-01

Body mass can be estimated from measures of skeletal frame size (stature and bi-iliac (maximum pelvic) breadth) fairly accurately in modern human populations. However, it is not clear whether such a technique will lead to systematic biases in body mass estimation when applied to earlier hominins. Here the stature/bi-iliac method is tested, using data available for modern Olympic and Olympic-caliber athletes, with the rationale that these individuals may be more representative of the general physique and degree of physical conditioning characteristic of earlier populations. The average percent prediction error of body mass among both male and female athletes is less than 3%, with males slightly underestimated and females slightly overestimated. Among males, the ratio of shoulder to hip (biacromial/bi-iliac) breadth is correlated with prediction error, while lower limb/trunk length has only a weak inconsistent effect. In both sexes, athletes in "weight" events (e.g. , shot put, weight-lifting), which emphasize strength, are underestimated, while those in more endurance-related events (e.g., long distance running) are overestimated. It is likely that the environmental pressures facing earlier hominins would have favored more generalized physiques adapted for a combination of strength, speed, agility, and endurance. The events most closely approximating these requirements in Olympic athletes are the decathlon, pentathlon, and wrestling, all of which have average percent prediction errors of body mass of 5% or less. Thus, "morphometric" estimation of body mass from skeletal frame size appears to work reasonably well in both "normal" and highly athletic modern humans, increasing confidence that the technique will also be applicable to earlier hominins. Copyright 2000 Wiley-Liss, Inc.

Alterations in physique among young children after the Great East Japan Earthquake: Results from a nationwide survey.

PubMed

Kikuya, Masahiro; Matsubara, Hiroko; Ishikuro, Mami; Sato, Yuki; Obara, Taku; Metoki, Hirohito; Isojima, Tsuyoshi; Yokoya, Susumu; Kato, Noriko; Tanaka, Toshiaki; Chida, Shoichi; Ono, Atsushi; Hosoya, Mitsuaki; Yokomichi, Hiroshi; Yamagata, Zentaro; Tanaka, Soichiro; Kure, Shigeo; Kuriyama, Shinichi

2017-10-01

Data for earthquake-related alterations in physique among young children in developed countries is lacking. The Great East Japan Earthquake caused severe damage in Iwate, Miyagi, and Fukushima Prefectures in northeastern Japan. We retrospectively obtained anthropometric measurements in nursery school from 40,046 (cohort 1, historical control) and 53,492 (cohort 2) children aged 3.5-4.5 years without overweight in October 2008, and in October 2010, respectively. At the time of the earthquake in March, 2011, children in cohort 1 had already graduated from nursery school; however, children in cohort 2 were still enrolled in nursery school at this time. We compared the onset of overweight at 1 year after the baseline between children enrolled in their school located in one of the three target prefectures versus those in other prefectures using a logistic regression model, with adjustment for sex, age, history of disease, and obesity index at baseline. Overweight was defined as an obesity index of >+15%, which was calculated as (weight minus sex- and height-specific standard weight)/sex- and height-specific standard weight. The odds ratio (OR) for the onset of overweight in the three target prefectures was significant in cohort 2 (OR 1.25; 95% confidence interval [CI], 1.01-1.55) but not in cohort 1. When the two cohort were pooled (n = 93,538), the OR of the interaction term for school location × cohort was significant (OR 1.56; 95% CI, 1.09-2.23). Incident overweight in young children was significantly more common in the three prefectures affected by the Great East Japan Earthquake than in other prefectures after the disaster. Copyright © 2017 The Authors. Production and hosting by Elsevier B.V. All rights reserved.

Anthropometric Profiles of Elite Open-Water Swimmers.

PubMed

Shaw, Gregory; Mujika, Iñigo

2018-01-01

Reports detailing the physiques of open-water (OW) swimmers are limited. Data from anthropometric screening around competition provides a unique opportunity to describe the current physical attributes of elite OW swimmers peaking for international competition. Anthropometric screening was undertaken on a group of Australian and French OW swimmers as part of performance monitoring within 2 wk of the 2015 FINA World Championships. Height, mass, and sum of 7 skinfolds were measured using ISAK standardized measurement techniques by 2 trained anthropometrists. Data were collated and compared with previously published data on OW and pool swimmers. French swimmers had lower skinfolds (57.3 ± 6.1 vs 80.5 ± 21.3 mm, P = .0258), were lighter (64.7 ± 10.8 vs 74.6 ± 11.8 kg, P = .013), and had lower lean-mass index (LMI) (34.7 ± 7.3 vs 38.2 ± 8.8, P = .035) than Australian swimmers. Male and female OW swimmers had skinfolds similar to their contemporary OW swimmers but were lower than earlier reports of OW swimmers; however, they were higher than those of pool swimmers. Male and female OW swimmers had 9% and 6% lower LMI, respectively, than pool swimmers. Lower body mass and LMI were correlated with better World Championships finishing positions (R 2  = .46, P = .0151, and R 2  = .45, P = .0177, respectively). These data are a unique report of elite OW swimmers' physiques around international competition and demonstrate a potential morphological optimization in OW swimmers that warrants further investigation in larger populations.

List of Participants

NASA Astrophysics Data System (ADS)

2007-11-01

Mohab Abou ZeidVrije Universiteit, Brussel Joke AdamKatholieke Universiteit Leuven Nikolas AkerblomMax-Planck-Institut für Physik, München Luis Fernando Alday Utrecht University Stelios Alexandris University of Patras Antonio Amariti Università di Milano-Bicocca Nicola Ambrosetti Université de Neuchâtel Pascal Anastasopoulos Università di Roma Tor Vergata Laura Andrianopoli Enrico Fermi Center Carlo Angelantonj Università di Torino Lilia Anguelova Queen Mary, University of London Daniel AreanUniversidade de Santiago de Compostela Gleb ArutyunovUtrecht University Spyros Avramis NTU Athens—University of Patras Ioannis Bakas University of Patras Subrata Bal Dublin Institute for Advanced Studies Igor Bandos Valencia University Jessica Barrett University of Iceland Marco Baumgartl Eidgenössische Technische Hochschule, Zürich Jacopo Bechi Università di Firenze James Bedford Queen Mary, University of London Jorge Bellorin Universidad Autonoma de Madrid Francesco Benini SISSA, Trieste Eric Bergshoeff Centre for Theoretical Physics, University of Groningen Gaetano BertoldiUniversity of Wales, Swansea Adel Bilal Laboratoire de Physique Théorique, École Normale Superieure, Paris Matthias Blau Université de Neuchâtel Johannes BroedelUniversität Hannover Felix Brümmer Universität Heidelberg Julio Cesar Bueno de Andrade São Paulo State University—UNESP Cliff Burgess McMaster University Agostino Butti Laboratoire de Physique Théorique, École Normale Superieure, Paris Marco Caldarelli Universitat de Barcelona Pablo G Camara Centre de Physique Théorique, École Polytechnique, Palaiseau Joan Camps Universitat de Barcelona Felipe Canoura FernandezUniversidade de Santiago de Compostela Luigi Cappiello Università di Napoli Federico II Luca Carlevaro École Polytechnique, Palaiseau Roberto Casero Centre de Physique Théorique, École Polytechnique, Palaiseau Claudio Caviezel Max-Planck-Institut für Physik, München Alessio Celi Universitat de Barcelona Anna Ceresole Istituto Nazionale di Fisica Nucleare and Università di Torino Kang Sin Choi University of Bonn Michele Cirafici University of Patras Andres Collinucci Katholieke Universiteit Leuven Aldo Cotrone Universitat de Barcelona Ben Craps Vrije Universiteit, Brussel Stefano Cremonesi SISSA, Trieste Gianguido Dall'Agata Padova University Sanjit Das Indian Institute of Technology, Kharagpur Forcella Davide SISSA, Trieste Jose A de Azcarraga Valencia University and Instituto de Fìsica Corpuscular (CSIC-UVEG), Valencia Sophie de BuylInstitut des Hautes Études Scientifiques, Bures-sur-Yvette Jean-Pierre Derendinger Université de Neuchâtel Stephane Detournay Università Degli Studi di Milano Paolo Di Vecchia NORDITA, København Oscar Dias Universitat de Barcelona Vladimir Dobrev Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences, Sofia Joel Ekstrand Department of Theoretical Physics, Uppsala University Federico Elmetti Università di Milano I Diaconu Eugen University of Craiova Oleg Evnin Vrije Universiteit, Brussel Bo Feng Imperial College, London Livia Ferro Università di Torino Pau Figueras Universitat de Barcelona Raphael Flauger University of Texas at Austin Valentina Forini Università di Perugia Angelos Fotopoulos Università di Torino Denis Frank Université de Neuchâtel Lisa Freyhult Albert-Einstein-Institut, Golm Carlos Fuertes Instituto de Física Teórica, Madrid Matthias Gaberdiel Eidgenössische Technische Hochschule, Zürich Maria Pilar Garcia del Moral Università di Torino Daniel Gerber Instituto de Física Teórica, Madrid Valentina Giangreco Marotta Puletti Uppsala University Joaquim Gomis Universitat de Barcelona Gianluca Grignani Università di Perugia Luca Griguolo Università di Parma Umut Gursoy École Polytechnique, Palaiseau and École Normale Supérieure, Paris Michael Haack Ludwig-Maximilians-Universität, München Troels Harmark Niels Bohr Institute, København Alexander Haupt Imperial College, London Michal Heller Jagiellonian University, Krakow Samuli Hemming University of Iceland Yasuaki Hikida DESY, Hamburg Christian Hillmann Max-Planck-Institut für Gravitationsphysik, Potsdam Stephan Hoehne Max-Planck-Institut für Physik, München Gabriele Honecker CERN, Geneva Carlos Hoyos University of Wales, Swansea Mechthild Huebscher Consejo Superior de Investigaciones Cientificas, Madrid Matthias Ihl University of Texas at Austin Emiliano Imeroni University of Wales, Swansea Nikos Irges University of Crete Negru Iulian University of Craiova Matthias Kaminski Ludwig-Maximilians-Universität, München Stefanos Katmadas Universiteit Utrecht Shoichi Kawamoto Oxford University Christoph Keller Eidgenössische Technische Hochschule, Zürich Arjan Keurentjes Vrije Universiteit, Brussel Sadi Khodaee Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, Iran Michael Kiermaier Massachusetts Institute of Technology, Cambridge, MA Elias Kiritsis Centre de Physique Théorique, École Polytechnique, Palaiseau and University of Crete Ingo KirschEidgenössische Technische Hochschule, Zürich Johanna Knapp CERN, Geneva Paul Koerber Max-Planck-Institut für Physik, München Simon Koers Max-Planck-Institut für Physik, München Anatoly Konechny Heriot-Watt University, Edinburgh Peter Koroteev Institute for Theoretical and Experimental Physics (ITEP), Moscow Daniel KreflLudwig-Maximilians-Universität and Max-Planck-Institut für Physik, München Chethan KrishnanUniversité Libre de Bruxelles Stanislav Kuperstein Université Libre de Bruxelles Alberto Lerda Università del Piemonte Orientale, Alessandria Roman Linares Universidad Autonoma Metropolitana, Iztapalapa, México Maria A Lledo Universidad de Valencia Dieter Luest Ludwig-Maximilians-Universität and Max-Planck-Institut für Physik, München Joseph Lykken Fermi National Accelerator Laboratory (Fermilab), Batavia, IL Carlo Maccaferri Vrije Universiteit, Brussel Oscar Macia Universidad de Valencia Tristan Maillard Centre de Physique Théorique, École Polytechnique, Palaiseau Diego Mansi Università Degli Studi di Milano Matteo Marescotti Università del Piemonte Orientale, Alessandria Alberto Mariotti Università di Milano-Bicocca Raffaele Marotta Istituto Nazionale di Fisica Nucleare, Napoli Alessio Marrani Istituto Nazionale di Fisica Nucleare and LNF, Firenze Luca Martucci Instituto de Física Teórica, Madrid and Katholieke Universiteit Leuven David Mateos University of California, Santa Barbara Andrea Mauri Università di Milano Liuba Mazzanti Università di Milano-Bicocca Patrick Meessen Instituto de Física Teórica, Universidad Autónoma de Madrid Lotta Mether Helsinki Institute of Physics Rene Meyer Max-Planck-Institut für Physik, München Giuseppe Milanesi SISSA, Trieste Cesar Miquel-Espanya Universitat de Valencia and Instituto de Física Corpuscular, Valencia Alexander Monin Institute for Theoretical and Experimental Physics (ITEP), Moscow and Moscow State University (MSU) Samuel Monnier Université de Genève Sergio Montero Instituto de Física Teórica, Madrid Nicola Mori Università di Firenze Alexander Marcel Morisse University of California, Santa Cruz Sebastian Moster Max-Planck-Institut für Physik, München Adele Nasti Queen Mary, University of London Vasilis Niarchos École Polytechnique, Palaiseau Emil Nissimov Institute for Nuclear Research and Nuclear Energy, Sofia Francesco Nitti École Polytechnique, Palaiseau Eoin O'Colgain Imperial College, London Niels Obers Niels Bohr Institute, København Rodrigo Olea Università Degli Studi di Milano Marta Orselli Niels Bohr Institute, København Enrico PajerLudwig-Maximilians-Universität, München Eran PaltiOxford University Georgios PapathanasiouBrown University, Providence, RI Angel ParedesCentre de Physique Théorique, École Polytechnique, Palaiseau Jeong-Hyuck ParkMax-Planck-Institut für Physik, München Sara PasquettiUniversità di Parma Silvia PenatiUniversità di Milano-Bicocca Igor PesandoUniversità di Torino Marios PetropoulosÉcole Polytechnique, Palaiseau Roberto PettorinoUniversità di Napoli Federico II Franco PezzellaIstituto Nazionale di Fisica Nucleare, Napoli Moises Picon PonceIstituto Nazionale di Fisica Nucleare, Padova Marco PirroneUniversità di Milano-Bicocca Erik PlauschinnMax-Planck-Institut für Physik, München Andre PloeghCentre for Theoretical Physics, University of Groningen Giuseppe PolicastroLaboratoire de Physique Théorique, École Normale Superieure, Paris Josep PonsUniversitat de Barcelona S Prem KumarUniversity of Wales, Swansea Nikolaos PrezasCERN, Geneva Carlo Alberto RattiUniversità di Milano-Bicocca Riccardo RicciImperial College, London Alejandro RiveroEscuela Universitaria Politécnica de Teruel, Universidad de Zaragoza Irene RodriguezInstituto de Física Teórica, Madrid Maria Jose RodriguezUniversitat de Barcelona Diederik RoestUniversitat de Barcelona Alberto RomagnoniLaboratoire de Physique Théorique d'Orsay, Paris Christian RomelsbergerDublin Institute for Advanced Studies Jan RosseelKatholieke Universiteit Leuven Sebastiano RossiEidgenössische Technische Hochschule, Zürich Felix RustMax-Planck-Institut für Physik, München Cheol RyouPohang University of Science and Technology (POSTECH) Christian SaemannDublin Institute for Advanced Studies Houman Safaai SISSA, Trieste Alberto SantambrogioIstituto Nazionale di Fisica Nucleare, Sezione di Milano Frank SaueressigUniversiteit Utrecht Ricardo SchiappaCERN, Geneva Cornelius Schmidt-ColinetEidgenössische Technische Hochschule, Zürich Maximilian Schmidt-SommerfeldMax-Planck-Institut für Physik, München Waldemar SchulginMax-Planck-Institut für Physik, München Claudio ScruccaUniversité de Neuchâtel Nathan SeibergInstitute of Advanced Studies, Princeton, NJ Domenico SeminaraUniversità di Firenze Alexander SevrinVrije Universiteit, Brussel Konstadinos SfetsosUniversity of Patras Kostas SiamposUniversity of Patras Christoph SiegUniversità Degli Studi di Milano Vaula Silvia Instituto de Física Teórica, Madrid Aaron Sim Imperial College, London Woojoo Sim Pohang University of Science and Technology (POSTECH) Sergey Slizovskiy Department of Theoretical Physics, Uppsala University Paul Smyth Katholieke Universiteit Leuven Corneliu Sochichiu Laboratori Nazionali di Frascati Dmitri Sorokin Istituto Nazionale di Fisica Nucleare, Padova Kellogg Stelle Imperial College, London Piotr Surowka Jagiellonian University, Krakow Yasutoshi Takayama Niels Bohr Institute, København Laura Tamassia Katholieke Universiteit Leuven Radu Tatar University of Liverpool Larus Thorlacius University of Iceland Paavo Tiitola Helsinki Institute of Physics Diego Trancanelli Stony Brook University, NY Michele TraplettiInstitut für Theoretische Physik, Universität Heidelberg Mario Trigiante Politecnico di Torino Angel Uranga CERN, Geneva and Instituto de Física Teórica, Madrid Roberto Valandro SISSA, Trieste Dieter Van den Bleeken Katholieke Universiteit Leuven Antoine Van Proeyen Katholieke Universiteit Leuven Thomas Van Riet Centre for Theoretical Physics, University of Groningen Pierre Vanhove Service de Physique Théorique, Saclay Oscar Varela Universidad de Valencia Alessandro Vichi Scuola Normale Superiore di Pisa Massimiliano VinconQueen Mary, University of London John Ward Queen Mary, University of London and CERN, Geneva Brian Wecht Massachusetts Institute of Technology, Cambridge, MA Marlene Weiss Eidgenössische Technische Hochschule, Zürich and CERN, Geneva Sebastian Weiss Université de Neuchâtel Alexander Wijns Vrije Universiteit, Brussel Przemek Witaszczyk Jagiellonian University, Krakow Timm Wrase University of Texas at Austin Jun-Bao Wu SISSA, Trieste Amos Yarom Ludwig-Maximilians-Universität, München Marco Zagermann Max-Planck-Institut für Physik, München Daniela Zanon Dipartimento di Fisica, Università di Milano Andrea Zanzi University of Bonn Andrey Zayakin Moscow State University (MSU) and Institute for Theoretical and Experimental Physics (ITEP), Moscow Konstantinos Zoubos Queen Mary, University of London

Anisotropy and Microstructure of High Coercivity Rare Earth Iron Permanent Magnets, List of Papers Published

DTIC Science & Technology

1989-01-01

EARTH IRON PERMANENT MAGNETS. LIST OF PAPERS PUBLISHED 1986 - 1989 Contract No.: DAJA45-86-C-0010 Report No.: R/D-5295-MS-01 NOV 0 � A = LIST OF...R.Gr~ssinger - ’-Does a Co substitution really improve the temperature dependence of Nd-Fe-B based permanent magnets" .’ Proc. of 91h Int. Workshop...in NdzFe,4-4-iZx B (Z=A1,Si,Co, Ga) compounds", J. de Physique 49 (1988) CS-599. (16) R.Gr8ssinger, R.Krewenka, H.Buchn~r, H.Harada " A new analysis of

Étude statistique et dynamique de la propagation d'épidémies dans un réseau de petit mondeStatistical and dynamical study of the epidemics propagation in a small world network

NASA Astrophysics Data System (ADS)

Zekri, Nouredine; Clerc, Jean Pierre

We study numerically in this work the statistical and dynamical properties of the clusters in a one dimensional small world model. The parameters chosen correspond to a realistic network of children of school age where a disease like measles can propagate. Extensive results on the statistical behavior of the clusters around the percolation threshold, as well as the evoltion with time, are discussed. To cite this article: N. Zekri, J.P. Clerc, C. R. Physique 3 (2002) 741-747.

"Does understanding the brain need proteomics and does understanding proteomics need brains?"--Second HUPO HBPP Workshop hosted in Paris.

PubMed

Hamacher, Michael; Klose, Joachim; Rossier, Jean; Marcus, Katrin; Meyer, Helmut E

2004-07-01

The second Human Brain Proteome Project (HBPP) Workshop of the Human Proteome Organisation (HUPO) took place at the Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI) from April 23-24, 2004. During two days, more than 70 attendees from Europe, Asia and the US came together to decide basic strategic approaches, standards and the beginning of a pilot phase prior to further studies of the human brain proteome. The international consortium presented the technological and scientific portfolio and scheduled the time table for the next year.

[Comparison of cardiopulmonary endurance and muscular fitness in teenagers between Hong Kong and inland cities].

PubMed

Hong, Y; Chan, K; Wang, Y

1997-01-01

A study on the data of the physique investigated in teenagers was carried out between Hong Kong and inland cities to compare their cardiopulmonary endurance and muscular fitness. Results revealed that cardiopulmonary endurance in school teenagers of both sex at different ages in inland cities was better than that in Hong Kong. Muscular strength and endurance of sports performance of teenagers, except for standing long jump, in Hong Kong were weaker than that in inland cities. It suggests that attention should be paid to the involvement of teenagers in physical education with the increase of people's living standard.

Facteurs prédictifs de succès des étudiants en première année de médecine à l'université de Parakou

PubMed Central

Adoukonou, Thierry; Tognon-Tchegnonsi, Francis; Mensah, Emile; Allodé, Alexandre; Adovoekpe, Jean-Marie; Gandaho, Prosper; Akpona, Simon

2016-01-01

Introduction Plusieurs facteurs dont les notes obtenues au BAC peuvent influencer les performances académiques des étudiants en première année de médecine. L'objectif de cette étude était d’évaluer la relation entre les résultats des étudiants au BAC et le succès en première année de médecine. Méthodes Nous avons réalisé une étude analytique ayant inclus l'ensemble des étudiants régulièrement inscrits en première année à la Faculté de Médecine de l'université de Parakou durant l'année académique 2010-2011. Les données concernant les notes par discipline et mention obtenue au BAC ont été collectées. Une analyse multivariée utilisant la régression logistique et la régression linéaire multiple a permis d’établir les meilleurs prédicteurs du succès et de la moyenne de l’étudiant en fin d'année. Le logiciel SPSS version 17.0 a été utilisé pour l'analyse des données et un p<0,05 a été considéré comme statistiquement significatif. Résultats Parmi les 414 étudiants régulièrement inscrits les données de 407 ont pu être exploitées. Ils étaient âgés de 15 à 31 ans; 262 (64,4%) étaient de sexe masculin. 98 étaient admis avec un taux de succès de 23,7%. Le sexe masculin, la note obtenue en mathématiques, en sciences physiques, la moyenne au BAC et la mention étaient associés au succès en fin d'année mais en analyse multivariée seule une note en sciences physiques > 15/20 était associée au succès (OR: 2,8 [1,32- 6,00]). Pour la moyenne générale obtenue en fin d'année seule une mention bien obtenue au BAC était associée (coefficient de l'erreur standard: 0,130 Bêta =0,370 et p=0,00001). Conclusion Les meilleurs prédicateurs du succès en première année étaient une bonne moyenne en sciences physiques au BAC et une mention bien. La prise en compte de ces éléments dans le recrutement des étudiants en première année pourrait améliorer les résultats académiques. PMID:27313819

La Sociéte Française d'Exobiologie

NASA Astrophysics Data System (ADS)

Raulin, F.

2010-12-01

L'exobiologie est une jeune science, très pluridisciplinaire qui, de façon générale, a pour objet l'étude de la vie dans l'univers. Plus précisément, elle inclut l'étude des conditions et des processus qui ont permis l'émergence du vivant sur notre planète, et ont pu oumo pourraient le permettre ailleurs, l'étude de l'évolution de la matière organique vers des structures complexes dans l'univers, et les recherches qui concernent la distribution de la vie sous toutes les formes qu'elle pourrait revêtir, et son évolution. La Société Française d'Exobiologie a été fondée en mai 2009. Elle a pour buts principaux de fédérer les recherches en exobiologie au niveau français en facilitant l'établissement de contacts interdisciplinaires entre les chercheurs français et faire connaître et expliquer l'exobiologie pour satisfaire la demande socio culturelle provenant d'un public diversifié, par le biais de conférences, d'ateliers, d'expositions. La SFE est reconnue comme Société savante. Elle compte actuellement 140 membres et vient d'organiser son premier colloque national d'exobiologie à Biarritz.

Tutankhamun and his brothers. Familial gynecomastia in the Eighteenth Dynasty.

PubMed

Paulshock, B Z

1980-07-11

Many images of the last four hereditary pharaohs of the Eighteenth Egyptian Dynasty (1559 BC to 1319 BC), Amenophis III, Amenophis IV (also known as Akhenaten), Smenkhkare, and Tutankhamun, show them with gynecomastia. Amenophis III was most probably the sire of the last three. The feminine physique and other abnormalities of Amenophis IV have been extensively commented on as indicative of some sort of pathological condition, but the gynecomastia of the others, including Tutankhamun, has been glossed over or considered an artistic mannerism of the El Amarna period. An alternative theory, that the gynecomastia was actually representational and indicative of a familial abnormality in two or three generations, is suggested.

Un regard international sur la sécurité nucléaire

NASA Astrophysics Data System (ADS)

Birkhofer, Adolf

2002-10-01

Safety has always been an important objective in nuclear technology. Starting with a set of sound physical principles and prudent design approaches, safety concepts have gradually been refined and cover now a wide range of provisions related to design, quality and operation. Research, the evaluation of operating experiences and probabilistic risk assessments constitute an essential basis and international co-operation plays a significant role in that context. Concerning future developments a major objective for new reactor concepts, such as the EPR, is to practically exclude a severe core damage accident with large scale consequences outside the plant. To cite this article: A. Birkhofer, C. R. Physique 3 (2002) 1059-1065.

Modélisation des charges d'espace dans les isolants solides par une analyse spectrale

NASA Astrophysics Data System (ADS)

Haas, V.; Scouarnec, Ch.; Franceschi, J. L.

1998-01-01

A mathematical method based on spectral algebra is developped for the thermal modulation method. These methods permit to measure the space charge distribution in solid insulators. The modelling presented permits to evaluate the performances and the limitations of the measurement method. Une linéarisation par l'algèbre spectrale a été développée dans une méthode de modulation thermique pour mesurer la distribution des charges électriques dans les isolants solides. La modélisation présentée permet d'évaluer les performances et les limites tant numériques que physiques de la méthode de mesure.

Observations of chromospheric lines from OSO-8

NASA Technical Reports Server (NTRS)

Grossmann-Doerth, U.; Kneer, F.; Uexkuell, M.; Artzner, G. E.; Vial, J. C.

1980-01-01

Results of OSO-8 measurements of the line profiles of the solar Lyman alpha, Ca II K and Mg II k lines are presented. Observations were obtained with the Laboratoire de Physique Stellaire et Planetaire spectrometer at spectral resolutions of 0.25 and 0.060 A for Lyman alpha and 0.025 A for the Mg II and Ca II lines. The Lyman alpha profiles are found to be highly variable according to spatial position with the intensities of the three lines well correlated, and confirm previous observations of the quiet solar chromosphere. Data suggest that the quiet chromosphere is a dynamical phenomenon whose description in terms of a static model atmosphere is only qualitatively valid at best.

Electronegative Gas Thruster

NASA Technical Reports Server (NTRS)

Dankanich, John; Polzin, Kurt; Walker, Mitchell

2015-01-01

The project is an international collaboration and academic partnership to mature an innovative electric propulsion thruster concept to Technology Research Level-3 (TRL-3) through direct thrust measurement. The project includes application assessment of the technology ranging from small spacecraft to high power. The Plasma propulsion with Electronegative GASES(PEGASES) basic proof of concept has been matured to TRL-2 by Ane Aanesland of Laboratoire de Physique des Plasma at Ecole Polytechnique. The concept has advantages through eliminating the neutralizer requirement and should yield longer life and lower cost over conventional gridded ion engines. The objective of this research is to validate the proof of concept through the first direct thrust measurements and mature the concept to TRL-3.

A UNIX SVR4-OS 9 distributed data acquisition for high energy physics

NASA Astrophysics Data System (ADS)

Drouhin, F.; Schwaller, B.; Fontaine, J. C.; Charles, F.; Pallares, A.; Huss, D.

1998-08-01

The distributed data acquisition (DAQ) system developed by the GRPHE (Groupe de Recherche en Physique des Hautes Energies) group is a combination of hardware and software dedicated to high energy physics. The system described here is used in the beam tests of the CMS tracker. The central processor of the system is a RISC CPU hosted in a VME card, running a POSIX compliant UNIX system. Specialized real-time OS9 VME cards perform the instrumentation control. The main data flow goes over a deterministic high speed network. The UNIX system manages a list of OS9 front-end systems with a synchronisation protocol running over a TCP/IP layer.

Atmospheric and meteorological Lidar: from pioneers to space applications

NASA Astrophysics Data System (ADS)

Flamant, Pierre H.

2005-10-01

The 'Light Detection and Ranging' technique, or Lidar, is a laser application to remote sensing. Lidar was in the laboratory stage in the 1960s and in less than 40 years it became a serious candidate for space applications at the turn of the 21st century. Over the years, the Lidar community made significant contributions to Lidar sciences and advancing the technique that makes Lidar an inevitable partner in geophysics and Earth observation. The French community, especially the Service d'Aéronomie and Laboratoire de Météorologie Dynamique, have been involved since the beginning in the Lidar venture and made significant contribution. To cite this article: P.H. Flamant, C. R. Physique 6 (2005).

Preface.

PubMed

Ditlevsen, Susanne; Lansky, Petr

2016-06-01

This Special Issue of Mathematical Biosciences and Engineering contains 11 selected papers presented at the Neural Coding 2014 workshop. The workshop was held in the royal city of Versailles in France, October 6-10, 2014. This was the 11th of a series of international workshops on this subject, the first held in Prague (1995), then Versailles (1997), Osaka (1999), Plymouth (2001), Aulla (2003), Marburg (2005), Montevideo (2007), Tainan (2009), Limassol (2010), and again in Prague (2012). Also selected papers from Prague were published as a special issue of Mathematical Biosciences and Engineering and in this way a tradition was started. Similarly to the previous workshops, this was a single track multidisciplinary event bringing together experimental and computational neuroscientists. The Neural Coding Workshops are traditionally biennial symposia. They are relatively small in size, interdisciplinary with major emphasis on the search for common principles in neural coding. The workshop was conceived to bring together scientists from different disciplines for an in-depth discussion of mathematical model-building and computational strategies. Further information on the meeting can be found at the NC2014 website at https://colloque6.inra.fr/neural_coding_2014. The meeting was supported by French National Institute for Agricultural Research, the world's leading institution in this field. This Special Issue of Mathematical Biosciences and Engineering contains 11 selected papers presented at the Neural Coding 2014 workshop. The workshop was held in the royal city of Versailles in France, October 6-10, 2014. This was the 11th of a series of international workshops on this subject, the first held in Prague (1995), then Versailles (1997), Osaka (1999), Plymouth (2001), Aulla (2003), Marburg (2005), Montevideo (2007), Tainan (2009), Limassol (2010), and again in Prague (2012). Also selected papers from Prague were published as a special issue of Mathematical Biosciences and Engineering and in this way a tradition was started. Similarly to the previous workshops, this was a single track multidisciplinary event bringing together experimental and computational neuroscientists. The Neural Coding Workshops are traditionally biennial symposia. They are relatively small in size, interdisciplinary with major emphasis on the search for common principles in neural coding. The workshop was conceived to bring together scientists from different disciplines for an in-depth discussion of mathematical model-building and computational strategies. Further information on the meeting can be found at the NC2014 website at https://colloque6.inra.fr/neural_coding_2014. The meeting was supported by French National Institute for Agricultural Research, the world's leading institution in this field. Understanding how the brain processes information is one of the most challenging subjects in neuroscience. The papers presented in this special issue show a small corner of the huge diversity of this field, and illustrate how scientists with different backgrounds approach this vast subject. The diversity of disciplines engaged in these investigations is remarkable: biologists, mathematicians, physicists, psychologists, computer scientists, and statisticians, all have original tools and ideas by which to try to elucidate the underlying mechanisms. In this issue, emphasis is put on mathematical modeling of single neurons. A variety of problems in computational neuroscience accompanied with a rich diversity of mathematical tools and approaches are presented. We hope it will inspire and challenge the readers in their own research. We would like to thank the authors for their valuable contributions and the referees for their priceless effort of reviewing the manuscripts. Finally, we would like to thank Yang Kuang for supporting us and making this publication possible.

Body-part compatibility effects are modulated by the tendency for women to experience negative social comparative emotions and the body-type of the model.

PubMed

Pila, Eva; Jovanov, Kimberely; Welsh, Timothy N; Sabiston, Catherine M

2017-01-01

Although exposure to physique-salient media images of women's bodies has been consistently linked with negative psychological consequences, little is known about the cognitive processes that lead to these negative effects. The present study employed a novel adaptation of a computerized response time (RT) task to (i) assess implicit cognitive processing when exposed to the body of another individual, and (ii) examine individual differences in social comparative emotions that may influence the cognitive processing of human bodies. Adult females with low (n = 44) or high (n = 23) tendencies for comparative emotions completed a task in which they executed responses to coloured targets presented on the hands or feet of images of ultra-thin, average-size, and above average-size female models. Although the colour of the target is the only relevant target feature, it is typically found that the to-be-ignored location of the target on the body of the model influences RTs such that RTs are shorter when the target is on a body-part that is compatible with the responding limb (e.g., hand response when target was on hand) than on a body-part that is incompatible with the responding limb (e.g., hand response when target was on foot). Findings from the present study revealed that the magnitude of the body-part compatibility effect (i.e., the index of the cognitive processing of the model) was modulated by tendencies for affective body-related comparisons. Specifically, women who were prone to experiencing social comparative emotions demonstrated stronger and more consistent body-part compatibility effects across models. Therefore, women with higher social comparison tendencies have heightened processing of bodies at a neurocognitive level and may be at higher risk of the negative outcomes linked with physique-salient media exposure.

Methodes d'amas quantiques a temperature finie appliquees au modele de Hubbard

NASA Astrophysics Data System (ADS)

Plouffe, Dany

Depuis leur decouverte dans les annees 80, les supraconducteurs a haute temperature critique ont suscite beaucoup d'interet en physique du solide. Comprendre l'origine des phases observees dans ces materiaux, telle la supraconductivite, est l'un des grands defis de la physique theorique du solide des 25 dernieres annees. L'un des mecanismes pressentis pour expliquer ces phenomenes est la forte interaction electron-electron. Le modele de Hubbard est l'un des modeles les plus simples pour tenir compte de ces interactions. Malgre la simplicite apparente de ce modele, certaines de ses caracteristiques, dont son diagramme de phase, ne sont toujours pas bien etablies, et ce malgre plusieurs avancements theoriques dans les dernieres annees. Cette etude se consacre a faire une analyse de methodes numeriques permettant de calculer diverses proprietes du modele de Hubbard en fonction de la temperature. Nous decrivons des methodes (la VCA et la CPT) qui permettent de calculer approximativement la fonction de Green a temperature finie sur un systeme infini a partir de la fonction de Green calculee sur un amas de taille finie. Pour calculer ces fonctions de Green, nous allons utiliser des methodes permettant de reduire considerablement les efforts numeriques necessaires pour les calculs des moyennes thermodynamiques, en reduisant considerablement l'espace des etats a considerer dans ces moyennes. Bien que cette etude vise d'abord a developper des methodes d'amas pour resoudre le modele de Hubbard a temperature finie de facon generale ainsi qu'a etudier les proprietes de base de ce modele, nous allons l'appliquer a des conditions qui s'approchent de supraconducteurs a haute temperature critique. Les methodes presentees dans cette etude permettent de tracer un diagramme de phase pour l'antiferromagnetisme et la supraconductivite qui presentent plusieurs similarites avec celui des supraconducteurs a haute temperature. Mots-cles : modele de Hubbard, thermodynamique, antiferromagnetisme, supraconductivite, methodes numeriques, larges matrices

Body-part compatibility effects are modulated by the tendency for women to experience negative social comparative emotions and the body-type of the model

PubMed Central

Jovanov, Kimberely; Welsh, Timothy N.; Sabiston, Catherine M.

2017-01-01

Although exposure to physique-salient media images of women’s bodies has been consistently linked with negative psychological consequences, little is known about the cognitive processes that lead to these negative effects. The present study employed a novel adaptation of a computerized response time (RT) task to (i) assess implicit cognitive processing when exposed to the body of another individual, and (ii) examine individual differences in social comparative emotions that may influence the cognitive processing of human bodies. Adult females with low (n = 44) or high (n = 23) tendencies for comparative emotions completed a task in which they executed responses to coloured targets presented on the hands or feet of images of ultra-thin, average-size, and above average-size female models. Although the colour of the target is the only relevant target feature, it is typically found that the to-be-ignored location of the target on the body of the model influences RTs such that RTs are shorter when the target is on a body-part that is compatible with the responding limb (e.g., hand response when target was on hand) than on a body-part that is incompatible with the responding limb (e.g., hand response when target was on foot). Findings from the present study revealed that the magnitude of the body-part compatibility effect (i.e., the index of the cognitive processing of the model) was modulated by tendencies for affective body-related comparisons. Specifically, women who were prone to experiencing social comparative emotions demonstrated stronger and more consistent body-part compatibility effects across models. Therefore, women with higher social comparison tendencies have heightened processing of bodies at a neurocognitive level and may be at higher risk of the negative outcomes linked with physique-salient media exposure. PMID:28632746

Simple preparations of Pd6Cl12, Pt6Cl12, and Qn[Pt2Cl8+n], n=1, 2 (Q=TBA+, PPN+) and structural characterization of [TBA][Pt2Cl9] and [PPN]2[Pt2Cl10].C7H8.

PubMed

Dell'Amico, Daniela Belli; Calderazzo, Fausto; Marchetti, Fabio; Ramello, Stefano; Samaritani, Simona

2008-02-04

The hexanuclear Pd6Cl12, i.e., the crystal phase classified as beta-PdCl2, was obtained by reacting [TBA]2[Pd2Cl6] with AlCl3 (or FeCl3) in CH2Cl2. The action of AlCl3 on PtCl42-, followed by digestion of the resulting solid in 1,2-C2H4Cl2 (DCE), CHCl3, or benzene, produced Pt6Cl12.DCE, Pt6Cl12.CHCl3, or Pt6Cl12.C6H6, respectively. Treating [TBA]2[PtCl6] with a slight excess of AlCl3 afforded [TBA][Pt2Cl9], whose anion was established crystallographically to be constituted by two "PtCl6" octahedra sharing a face. Dehydration of H2PtCl6.nH2O with SOCl2 gave an amorphous compound closely analyzing as PtCl4, reactive with [Q]Cl in SOCl2 to yield [Q][Pt2Cl9] or [Q]2[Pt2Cl10], depending on the [Q]Cl/Pt molar ratio (Q=TBA+, PPN+). A single-crystal X-ray diffraction study has shown [PPN]2[Pt2Cl10].C7H8 to contain dinuclear anions formed by two edge-sharing PtCl6 octahedra.

Quasi-monoenergetic electron acceleration in relativistic laser-plasmas

NASA Astrophysics Data System (ADS)

Pukhov, Alexander; Gordienko, Sergei; Seredov, Vasili; Kostyukov, Igor

2009-03-01

Using Particle-in-Cell simulations as well as analytical theory we study electron acceleration in underdense plasmas both in the Bubble regime and in the weakly relativistic periodic wake fields. In the Bubble regime, electron trapping is taken as a function of the propagated distance. The number of trapped electrons depends on the effective phase velocity of the X-point at the rear of the Bubble. For the weakly relativistic periodic wakes, we show that the phase synchronism between the wake and the relativistic electrons can be maintained over very long distances when the plasma density is tapered properly. Moreover, one can use layered plasmas to control and improve the accelerated beam quality. To cite this article: A. Pukhov et al., C. R. Physique 10 (2009).

Higgsless approach to electroweak symmetry breaking

NASA Astrophysics Data System (ADS)

Grojean, Christophe

2007-11-01

Higgsless models are an attempt to achieve a breaking of the electroweak symmetry via boundary conditions at the end-points of a fifth dimension compactified on an interval, as an alternative to the usual Higgs mechanism. There is no physical Higgs scalar in the spectrum and the perturbative unitarity violation scale is delayed via the exchange of massive spin-1 KK resonances. The correct mass spectrum is reproduced in a model in warped space, which inherits a custodial symmetry from a left-right gauge symmetry in the bulk. Phenomenological challenges as well as collider signatures are presented. From the AdS/CFT perspective, this model appears as a weakly coupled dual to walking technicolour models. To cite this article: C. Grojean, C. R. Physique 8 (2007).

A Unix SVR-4-OS9 distributed data acquisition for high energy physics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Drouhin, F.; Schwaller, B.; Fontaine, J.C.

1998-08-01

The distributed data acquisition (DAQ) system developed by the GRPHE (Groupe de Recherche en Physique des Hautes Energies) group is a combination of hardware and software dedicated to high energy physics. The system described here is used in the beam tests of the CMs tracker. The central processor of the system is a RISC CPU hosted in a VME card, running a POSIX compliant UNIX system. Specialized real-time OS9 VME cards perform the instrumentation control. The main data flow goes over a deterministic high speed network. The Unix system manages a list of OS9 front-end systems with a synchronization protocolmore » running over a TCP/IP layer.« less

Fat or lean: adjustment of endogenous energy stores to predictable and unpredictable changes in allostatic load

USGS Publications Warehouse

Schultner, Jannik; Kitaysky, Alexander S.; Welcker, Jorg; Hatch, Scott

2013-01-01

6. Overall, results of this study support the ‘lean and fit’ hypothesis. We conclude that increased energy stores may not necessarily reflect better environmental conditions experienced by individuals or predict their higher fitness. A major advantage of adopting a lean physique when environmental conditions allow may be the avoidance of additional energetic costs for moving a heavy body. In breeding seabirds, this advantage may be more important during chick-rearing. In the focal species, the secretion of glucocorticoids might be involved in regulation of energy stores within a life history stage but does not appear to mediate an adaptive shift in energy stores between the incubating and chick-rearing stages of reproduction.

Imaging the experiments on respiration and transpiration of Lavoisier and Séguin: two unknown drawings by Madame Lavoisier.

PubMed

Beretta, Marco

2012-01-01

This paper presents two hitherto unknown drawings by Marie-Anne-Pierrette Lavoisier dating to the early 1790s that illustrate the experiments on respiration and transpiration of her husband Antoine-Laurent Lavoisier and his assistant Armand Séguin. These works may be associated with the well-known sepia drawings that were published for the first time by Edouard Grimaux in 1888. Details contained in these newly discovered drawings by M.me Lavoisier provide fresh evidence as to the nature and aims of Lavoisier's innovative experiments. As we will show, these drawings were intended to illustrate the collection of papers on respiration being prepared by Lavoisier for his Mémoires de physique et de chimie (1792-1805).

Calculation of phase diagrams for the FeCl2, PbCl2, and ZnCl2 binary systems by using molecular dynamics simulation

NASA Astrophysics Data System (ADS)

Seo, Won-Gap; Matsuura, Hiroyuki; Tsukihashi, Fumitaka

2006-04-01

Recently, molecular dynamics (MD) simulation has been widely employed as a very useful method for the calculation of various physicochemical properties in the molten slags and fluxes. In this study, MD simulation has been applied to calculate the structural, transport, and thermodynamic properties for the FeCl2, PbCl2, and ZnCl2 systems using the Born—Mayer—Huggins type pairwise potential with partial ionic charges. The interatomic potential parameters were determined by fitting the physicochemical properties of iron chloride, lead chloride, and zinc chloride systems with experimentally measured results. The calculated structural, transport, and thermodynamic properties of pure FeCl2, PbCl2, and ZnCl2 showed the same tendency with observed results. Especially, the calculated structural properties of molten ZnCl2 and FeCl2 show the possibility of formation of polymeric network structures based on the ionic complexes of ZnCl{4/2-}, ZnCl{3/-}, FeCl{4/2-}, and FeCl{3/-}, and these calculations have successfully reproduced the measured results. The enthalpy, entropy, and Gibbs energy of mixing for the PbCl2-ZnCl2, FeCl2-PbCl2, and FeCl2-ZnCl2 systems were calculated based on the thermodynamic and structural parameters of each binary system obtained from MD simulation. The phase diagrams of the PbCl2-ZnCl2, FeCl2-PbCl2, and FeCl2-ZnCl2 systems estimated by using the calculated Gibbs energy of mixing reproduced the experimentally measured ones reasonably well.

Measurement of the absorption cross sections of SiCl4, SiCl3, SiCl2 and Cl at H Lyman-α wavelength

NASA Astrophysics Data System (ADS)

Mével, R.; Catoire, L.; Fikri, M.; Roth, P.

2013-03-01

Atomic resonance absorption spectroscopy coupled with a shock tube is a powerful technique for studying high temperature dynamics of reactive systems. Presently, high temperature pyrolysis of SiCl4-Ar mixtures has been studied behind reflected shock waves. Using time-resolved absorption profiles at 121.6 nm and a detailed reaction model, the absorption cross sections of SiCl, SiCl, SiCl and Cl have been measured. Results agree well with available data for SiCl and constitute, to our knowledge, the first measurements for SiCl, SiCl and Cl at the Lyman-α wavelength. These data are relevant to silica particle production from SiCl-oxidant mixtures combustion synthesis.

Spectroelectrochemistry of EuCl 3 in Four Molten Salt Eutectics; 3 LiCl−NaCl, 3 LiCl−2 KCl, LiCl−RbCl, and 3 LiCl−2 CsCl; at 873 K

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schroll, Cynthia A.; Chatterjee, Sayandev; Levitskaia, Tatiana

Key electrochemical properties affecting pyroprocessing of nuclear fuel were examined in four eutectic melts using using Eu3+/2+ as a representative probe. We report the electrochemical and spectroelectrochemical behavior of EuCl3 in four molten salt eutectics (3 LiCl – NaCl, 3 LiCl – 2 KCl, LiCl – RbCl and 3 LiCl – 2 CsCl) at 873 K. Cyclic voltammetry was used to determine the redox potential for Eu3+/2+ and the applied potentials for spectroelectrochemistry. Single step chronoabsorptometry and thin-layer spectroelectrochemistry were used to obtain the number of electrons transferred, redox potentials and diffusion coefficients for Eu3+ in each eutectic melt. Themore » redox potentials determined by thin-layer spectroelectrochemistry were extremely close to those obtained using cyclic voltammetry. The redox potential for Eu3+/2+ was most positive in the 3 LiCl - NaCl melt, showed a negative shift in the 3 LiCl - 2 KCl melt, and was the most negative in the LiCl - RbCl and 3 LiCl - 2 CsCl eutectics. The diffusion coefficient for Eu3+ followed this same trend; it was the largest in the 3 LiCl - NaCl melt and the smallest in the LiCl - RbCl and 3 LiCl - 2 CsCl melts. The basic one-electron reversible electron transfer for Eu3+/2+ was not changed by melt composition.« less

PREFACE: Loops 11: Non-Perturbative / Background Independent Quantum Gravity

NASA Astrophysics Data System (ADS)

Mena Marugán, Guillermo A.; Barbero G, J. Fernando; Garay, Luis J.; Villaseñor, Eduardo J. S.; Olmedo, Javier

2012-05-01

Loops 11 The international conference LOOPS'11 took place in Madrid from the 23-28 May 2011. It was hosted by the Instituto de Estructura de la Materia (IEM), which belongs to the Consejo Superior de Investigaciones Cientĺficas (CSIC). Like previous editions of the LOOPS meetings, it dealt with a wealth of state-of-the-art topics on Quantum Gravity, with special emphasis on non-perturbative background-independent approaches to spacetime quantization. The main topics addressed at the conference ranged from the foundations of Quantum Gravity to its phenomenological aspects. They encompassed different approaches to Loop Quantum Gravity and Cosmology, Polymer Quantization, Quantum Field Theory, Black Holes, and discrete approaches such as Dynamical Triangulations, amongst others. In addition, this edition celebrated the 25th anniversary of the introduction of the now well-known Ashtekar variables and the Wednesday morning session was devoted to this silver jubilee. The structure of the conference was designed to reflect the current state and future prospects of research on the different topics mentioned above. Plenary lectures that provided general background and the 'big picture' took place during the mornings, and the more specialised talks were distributed in parallel sessions during the evenings. To be more specific, Monday evening was devoted to Shape Dynamics and Phenomenology Derived from Quantum Gravity in Parallel Session A, and to Covariant Loop Quantum Gravity and Spin foams in Parallel Session B. Tuesday's three Parallel Sessions dealt with Black Hole Physics and Dynamical Triangulations (Session A), the continuation of Monday's session on Covariant Loop Quantum Gravity and Spin foams (Session B) and Foundations of Quantum Gravity (Session C). Finally, Thursday and Friday evenings were devoted to Loop Quantum Cosmology (Session A) and to Hamiltonian Loop Quantum Gravity (Session B). The result of the conference was very satisfactory and enlightening. Not only was it a showroom for the research currently being carried out by many groups throughout the world, but there was also a permanent look towards the future. During these days, the CSIC Campus witnessed many scientific conversations triggered by the interaction amongst the people and groups that participated in LOOPS'11 Madrid and which, in many cases, will crystallise into new results and advances in the field. The conference would not have been possible without the generous help of a number of national and international institutions. The organizers would like to acknowledge the financial support provided by the Spanish Ministry of Science and Innovation (Ministerio de Ciencia e Innovación), the Spanish Research Council, CSIC (Consejo Superior de Investigaciones Cientĺficas), The BBVA Foundation (Fundación BBVA), The CONSOLIDER-CPAN project, the Spanish Society for Gravitation and Relativity (SEGRE), The Universidad Carlos III of Madrid (UC3M), and the European Science Foundation (ESF). The ESF, through the Quantum Gravity and Quantum Geometry network, provided full support for a number of young participants that have contributed to these proceedings: Dario Benedetti (Albert Einstein Institute, Potsdam, Germany), Norbert Bodendorfer (Institute for Theoretical Physics III, FAU Erlangen Nürnberg, Germany), Mariam Bouhmadi López (CENTRA, Centro Multidisciplinar de Astrofĺsica, Lisbon), Timothy Budd (Institute for Theoretical Physics, Utrecht University, The Netherlands), Miguel Campiglia (Institute for Gravitation and the Cosmos, Penn State University, USA), Gianluca Delfino (School of Mathematical Sciences, University of Nottingham, UK), Maite Dupuis (Institute for Theoretical Physics III, FAU Erlangen Nürnberg, Germany), Michał Dziendzikowski (Institute of Theoretical Physics, Warsaw University, Poland), Muxin Han (Centre de Physique Théorique de Luminy, Marseille, France), Philipp Höhn (Institute for Theoretical Physics, Utrecht University, The Netherlands), Jacek Puchta (Centre de Physique Théorique de Luminy, Marseille, France), James Ryan (Albert Einstein Institute, Potsdam, Germany), Lorenzo Sindoni (Albert Einstein Institute, Golm, Germany), David Sloan (Institute for Theoretical Physics, Utrecht University, The Netherlands), Johannes Tambornino (Laboratoire de Physique, ENS Lyon, France), Andreas Thurn (Institute for Theoretical Physics III, FAU Erlangen Nürnberg, Germany), Francesca Vidotto (Laboratoire de Physique Subatomique et de Cosmologie, Grenoble, France), and Matteo Smerlak (Albert Einstein Institute, Golm, Germany). We would like to conclude this preamble by thanking all the attendants of the conference for their high and enthusiastic participation. The presence of a large number of past and present Loop Quantum Gravity practitioners, as well as a significant number of top researchers in other approaches to quantum gravity, provided ample opportunities for fruitful scientific exchanges and a very lively atmosphere. It is encouraging to see that, 25 years after the inception of Loop Quantum Gravity, there is a vibrant young community of researchers entering the field. Let us hope that, with their help, the quantization of general relativity can be successfully accomplished in the near future. The Editors Conference photograph

A model analysis of halogen kinetics: the ClOOCl catalytic cycle revisited

NASA Astrophysics Data System (ADS)

Canty, T. P.; Salawitch, R. J.; Wilmouth, D. M.

2016-12-01

We revisit prior analyses of simultaneous in situ observations of [ClO] and [ClOOCl] obtained in the Arctic polar vortex to evaluate recommended updates that govern the kinetics of the ClOOCl catalytic cycle. Available laboratory measurements of the ClOOCl absorption cross sections, the ClO+ClO reaction rate constant, and the ClO/ClOOCl equilibrium constant are considered, along with compendium evaluations of these kinetic parameters. We show that the latest recommendations for the kinetics that govern the partitioning of ClO and ClOOCl put forth by the JPL panel in Spring 2016 (JPL 15-10) are in good agreement with atmospheric observations of [ClO] and [ClOOCl]. Hence, we suggest that studies of polar ozone loss adopt these most recent recommendations. The latest JPL recommendation for the equilibrium constant suggests that ClOOCl is less stable than previously assumed, resulting in a shift in the termination temperature of polar ozone loss due to the ClOOCl catalytic cycle. Remaining uncertainties in our knowledge of the kinetics that govern the partitioning of ClO and ClOOCl within the activated vortex, and hence the efficiency of O3 loss by the ClO+ClO cycle, will be best addressed by future laboratory determinations of the absolute cross section of ClOOCl as well as measurements designed to reduce the uncertainty in the rate constant of the ClO+ClO reaction at cold temperatures characteristic of the polar, lower stratosphere.

Molecular beam studies of stratospheric photochemistry

NASA Astrophysics Data System (ADS)

Moore, Teresa Anne

1998-12-01

Photochemistry of chlorine oxide containing species plays a major role in stratospheric ozone depletion. This thesis discusses two photodissociation studies of the key molecules ClONO2 and ClOOCl which were previously thought to only produce Cl-atom (ozone depleting) products at wavelengths relevant to the stratosphere. The development of a molecular beam source of ClOOCl and the photodissociation dynamics of the model system Cl2O are also discussed. In the first chapter, the photochemistry of ClONO2 is examined at 308 nm using the technique of photofragment translational spectroscopy. Two primary decomposition pathways, leading to Cl + NO3 and ClO + NO2, were observed, with a lower limit of 0.33 for the relative yield of ClO. The angular distributions for both channels were anisotropic, indicating that the dissociation occurs within a rotational period. Chapter two revisits the photodissociation dynamics of Cl2O at 248 and 308 nm, on which we had previously reported preliminary findings. At 248 nm, three distinct dissociation pathways leading to Cl + ClO products were resolved. At 308 nm, the angular distribution was slightly more isotropic that previously reported, leaving open the possibility that Cl2O excited at 308 nm lives longer than a rotational period. Chapter three describes the development and optimization of a molecular beam source of ClOOCl. We utilized pulsed laser photolysis of ClA2O to generate ClO radicals, and cooled the cell to promote three body recombination to form ClOOCl. The principal components in the beam were Cl2, Cl2O, and ClOOCl. In the fourth chapter, the photodissociation dynamics of ClOOCl are investigated at 248 and 308 nm. We observed multiple dissociation pathways which produced ClO + ClO and 2Cl + O2 products. The relative Cl:ClO product yields are 1.0:0.13 and 1.0:0.20 for ClOOCl photolysis at 248 and 308 nm, respectively. The upper limit for the relative yield of the ClO + ClO channel was 0.19 at 248 nm and 0.31 at 308 nm. These results substantially confirm the current assumption but decrease somewhat the efficiency of the ClOOCl ozone-depleting catalytic cycle. At 248 nm, ClOOCl photolysis exhibited novel dissociation dynamics which appeared to depend on the symmetry of the excited state.

Characterization, expression patterns and functional analysis of the MAPK and MAPKK genes in watermelon (Citrullus lanatus).

PubMed

Song, Qiuming; Li, Dayong; Dai, Yi; Liu, Shixia; Huang, Lei; Hong, Yongbo; Zhang, Huijuan; Song, Fengming

2015-12-23

Mitogen-activated protein kinase (MAPK) cascades, which consist of three functionally associated protein kinases, namely MEKKs, MKKs and MPKs, are universal signaling modules in all eukaryotes and have been shown to play critical roles in many physiological and biochemical processes in plants. However, little or nothing is known about the MPK and MKK families in watermelon. In the present study, we performed a systematic characterization of the ClMPK and ClMKK families including the identification and nomenclature, chromosomal localization, phylogenetic relationships, ClMPK-ClMKK interactions, expression patterns in different tissues and in response to abiotic and biotic stress and transient expression-based functional analysis for their roles in disease resistance. Genome-wide survey identified fifteen ClMPK and six ClMKK genes in watermelon genome and phylogenetic analysis revealed that both of the ClMPK and ClMKK families can be classified into four distinct groups. Yeast two-hybrid assays demonstrated significant interactions between members of the ClMPK and ClMKK families, defining putative ClMKK2-1/ClMKK6-ClMPK4-1/ClMPK4-2/ClMPK13 and ClMKK5-ClMPK6 cascades. Most of the members in the ClMPK and ClMKK families showed differential expression patterns in different tissues and in response to abiotic (e.g. drought, salt, cold and heat treatments) and biotic (e.g. infection of Fusarium oxysporum f. sp. niveum) stresses. Transient expression of ClMPK1, ClMPK4-2 and ClMPK7 in Nicotiana benthamiana resulted in enhanced resistance to Botrytis cinerea and upregulated expression of defense genes while transient expression of ClMPK6 and ClMKK2-2 led to increased susceptibility to B. cinerea. Furthermore, transient expression of ClMPK7 also led to hypersensitive response (HR)-like cell death and significant accumulation of H2O2 in N. benthamiana. We identified fifteen ClMPK and six ClMKK genes from watermelon and analyzed their phylogenetic relationships, expression patterns and protein-protein interactions and functions in disease resistance. Our results demonstrate that ClMPK1, ClMPK4-2 and ClMPK7 positively but ClMPK6 and ClMKK2-2 negatively regulate the resistance to B. cinerea when transiently expressed in N. benthamiana and that ClMPK7 functions as a regulator of HR-like cell death through modulating the generation of H2O2.

X-ray absorption studies of chlorine valence and local environments in borosilicate waste glasses

NASA Astrophysics Data System (ADS)

McKeown, David A.; Gan, Hao; Pegg, Ian L.; Stolte, W. C.; Demchenko, I. N.

2011-01-01

Chlorine (Cl) is a constituent of certain types of nuclear wastes and its presence can affect the physical and chemical properties of silicate melts and glasses developed for the immobilization of such wastes. Cl K-edge X-ray absorption spectra (XAS) were collected and analyzed to characterize the unknown Cl environments in borosilicate waste glass formulations, ranging in Cl-content from 0.23 to 0.94 wt.%. Both X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) data for the glasses show trends dependent on calcium (Ca) content. Near-edge data for the Ca-rich glasses are most similar to the Cl XANES of CaCl 2, where Cl - is coordinated to three Ca atoms, while the XANES for the Ca-poor glasses are more similar to the mineral davyne, where Cl is most commonly coordinated to two Ca in one site, as well as Cl and oxygen nearest-neighbors in other sites. With increasing Ca content in the glass, Cl XANES for the glasses approach that for CaCl 2, indicating more Ca nearest-neighbors around Cl. Reliable structural information obtained from the EXAFS data for the glasses is limited, however, to Cl sbnd Cl, Cl sbnd O, and Cl sbnd Na distances; Cl sbnd Ca contributions could not be fit to the glass data, due to the narrow k-space range available for analysis. Structural models that best fit the glass EXAFS data include Cl sbnd Cl, Cl sbnd O, and Cl sbnd Na correlations, where Cl sbnd O and Cl sbnd Na distances decrease by approximately 0.16 Å as glass Ca content increases. XAS for the glasses indicates Cl - is found in multiple sites where most Cl-sites have Ca neighbors, with oxygen, and possibly, Na second-nearest neighbors. EXAFS analyses suggest that Cl sbnd Cl environments may also exist in the glasses in minor amounts. These results are generally consistent with earlier findings for silicate glasses, where Cl - was associated with Ca 2+ and Na + in network modifier sites.

Intracellular chloride regulation in amphibian dorsal root ganglion neurones studied with ion-selective microelectrodes.

PubMed Central

Alvarez-Leefmans, F J; Gamiño, S M; Giraldez, F; Noguerón, I

1988-01-01

1. Intracellular Cl- activity (aiCl) and membrane potential (Em) were measured in frog dorsal root ganglion neurones (DRG neurones) using double-barrelled Cl- -selective microelectrodes. In standard Ringer solution buffered with HEPES (5 mM), equilibrated with air or 100% O2, the resting membrane potential was -57.7 +/- 1.0 mV and aiCl was 23.6 +/- 1.0 mM (n = 53). The value of aiCl was 2.6 times the activity expected for an equilibrium distribution and the difference between Em and ECl was 25 mV. 2. Removal of external Cl- led to a reversible fall in aiCl. Initial rates of decay and recovery of aiCl were 4.1 and 3.3 mM min-1, respectively. During the recovery of aiCl following return to standard Ringer solution, most of the movement of Cl- occurred against the driving force for a passive distribution. Changes in aiCl were not associated with changes in Em. Chloride fluxes estimated from initial rates of change in aiCl when external Cl- was removed were too high to be accounted for by electrodiffusion. 3. The intracellular accumulation of Cl- was dependent on the extracellular Cl- activity (aoCl). The relationship between aiCl and aoCl had a sigmoidal shape with a half-maximal activation of about 50 mM-external Cl-. 4. The steady-state aiCl depended on the simultaneous presence of extracellular Na+ and K+. Similarly, the active reaccumulation of Cl- after intracellular Cl- depletion was abolished in the absence of either Na+ or K+ in the bathing solution. 5. The reaccumulation of Cl- was inhibited by furosemide (0.5-1 x 10(-3) M) or bumetanide (10(-5) M). The decrease in aiCl observed in Cl- -free solutions was also inhibited by bumetanide. 6. Cell volume changes were calculated from the observed changes in aiCl. Cells were estimated to shrink in Cl- -free solutions to about 75% their initial volume, at an initial rate of 6% min-1. 7. The present results provide direct evidence for the active accumulation of Cl- in DRG neurones. The mechanism of Cl- transport is electrically silent, dependent on the simultaneous presence of external Cl-, Na+ and K+ and inhibited by loop diuretics. It is suggested that a Na+:K+:Cl- co-transport system mediates the active transport of Cl- across the cell membrane of DRG neurones. PMID:3254412

[Adolphe Quetelet and biopolitics as secularized theology].

PubMed

Pich, Santiago

2013-01-01

The article recaptures the work of an author who has been forgotten by the contemporary social sciences, that is, the Belgium polymath Adolphe Quetelet. Focusing on his main work, Sur l'homme et le développement de ses facultés, ou Essai de physique sociale, the study underscores how the secularization of theological principles within the realm of science was important to the construction of Quetelet's work. His dual engagement in science and politics is pertinent here, as he was the main nineteenth-century force behind the incorporation of statistics as a science essential to the State's ability to govern its people. He also played a relevant role in the realization of the hegemonic political project of modernity, biopolitics, and its influence in the field of biomedicine in the nineteenth and twentieth centuries.

Super Yang Mills, matrix models and geometric transitions

NASA Astrophysics Data System (ADS)

Ferrari, Frank

2005-03-01

I explain two applications of the relationship between four-dimensional N=1 supersymmetric gauge theories, zero-dimensional gauged matrix models, and geometric transitions in string theory. The first is related to the spectrum of BPS domain walls or BPS branes. It is shown that one can smoothly interpolate between a D-brane state, whose weak coupling tension scales as N˜1/g, and a closed string solitonic state, whose weak coupling tension scales as N˜1/gs2. This is part of a larger theory of N=1 quantum parameter spaces. The second is a new purely geometric approach to sum exactly over planar diagrams in zero dimension. It is an example of open/closed string duality. To cite this article: F. Ferrari, C. R. Physique 6 (2005).

Laszlo Tisza and the two-fluid model of superfluidity

NASA Astrophysics Data System (ADS)

Balibar, Sébastien

2017-11-01

The "two-fluid model" of superfluidity was first introduced by Laszlo Tisza in 1938. On that year, Tisza published the principles of his model as a brief note in Nature and two articles in French in the Comptes rendus de l'Académie des sciences, followed in 1940 by two other articles in French in the Journal de physique et le Radium. In 1941, the two-fluid model was reformulated by Lev Landau on a more rigorous basis. Successive experiments confirmed the revolutionary idea introduced by Tisza: superfluid helium is indeed a surprising mixture of two fluids with independent velocity fields. His prediction of the existence of heat waves, a consequence of his model, was also confirmed. Then, it took several decades for the superfluidity of liquid helium to be fully understood.

Special Issue on "Instanton Counting: Moduli Spaces, Representation Theory, and Integrable Systems"

NASA Astrophysics Data System (ADS)

Bruzzo, Ugo; Sala, Francesco

2016-11-01

This special issue of the Journal of Geometry and Physics collects some papers that were presented during the workshop ;Instanton Counting: Moduli Spaces, Representation Theory, and Integrable Systems; that took place at the Lorentz Center in Leiden, The Netherlands, from 16 to 20 June 2014. The workshop was supported by the Lorentz Center, the ;Geometry and Quantum Theory; Cluster, Centre Européen pour les Mathématiques, la Physique et leurs Interactions (Lille, France), Laboratoire Angevin de Recherche en Mathématiques (Angers, France), SISSA (Trieste, Italy), and Foundation Compositio (Amsterdam, the Netherlands). We deeply thank all these institutions for making the workshop possible. We also thank the other organizers of the workshop, Professors Dimitri Markushevich, Vladimir Rubtsov and Sergey Shadrin, for their efforts and great collaboration.

Physiscope

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gaumer, Olivier

2010-10-22

Peut-on survivre à une décharge de 100000 volts? Le corps humain est-il conducteur? Qu'est-ce la charge électrique? L'air est-il conducteur? Quel est le meilleur conducteur connu? Autant de question que l'on se posera durant cette découverte de la physique et le l'électricité, par une approche originale, ludique et participative. Venez glisser en lévitation sur une trottinette supraconductrice! [Can we survive a discharge of 100,000 volts? Is the human body conductive? What is the electric charge? Is the air conductive? What is the best known driver? As much question as one will ask during this discovery of the physics and the electricity, bymore » an original, playful and participative approach. Come levitate on a superconducting scooter!]« less

Que peut-on voir avec des neutrons? Une introduction pour des non spécialistes

NASA Astrophysics Data System (ADS)

Schweizer, J.

2005-11-01

Le neutron est une particule élémentaire qui a été découverte en 1932 par James Chadwick. Ses caractéristiques principales sont résumées dans le tableau I. Il a été utilisé pour la première fois par Clifford Shull en 1946 comme outil pour des expériences de diffusion. Cette technique s'est depuis constamment développée pour concerner tous les aspects de la matière condensée: physique, chimie, matériaux, biologie. Il s'agit d'un outil tout à fait exceptionnel car le neutron possède des propriétés uniques et particulièrement adaptées pour ces études.

Body checking behaviors in men.

PubMed

Walker, D Catherine; Anderson, Drew A; Hildebrandt, Thomas

2009-06-01

Males have been facing increasing pressure from the media to attain a lean, muscular physique, and are at risk for body dissatisfaction, disturbed eating and exercise behaviors, and abuse of appearance- and performance-enhancing drugs (APEDs). The aim of the current study was to examine the relationship between body checking and mood, symptoms of muscle dysmorphia, importance of shape and weight, and APED use in undergraduate males. Body checking in males was correlated with weight and shape concern, symptoms of muscle dysmorphia, depression, negative affect, and APED use. Body checking predicted APED use and uniquely accounted for the largest amount of variance in Muscle Dysmorphic Disorder Inventory (MDDI) scores (16%). Findings support the view that body checking is an important construct in male body image, muscle dysmorphia, and body change strategies and suggest a need for further research.

Interoperability science cases with the CDPP tools

NASA Astrophysics Data System (ADS)

Nathanaël, J.; Cecconi, B.; André, N.; Bouchemit, M.; Gangloff, M.; Budnik, E.; Jacquey, C.; Pitout, F.; Durand, J.; Rouillard, A.; Lavraud, B.; Genot, V. N.; Popescu, D.; Beigbeder, L.; Toniutti, J. P.; Caussarieu, S.

2017-12-01

Data exchange protocols are never as efficient as when they are invisible for the end user who is then able to discover data, to cross compare observations and modeled data and finally to perform in depth analysis. Over the years these protocols, including SAMP from IVOA, EPN-TAP from the Europlanet 2020 RI community, backed by standard web-services, have been deployed in tools designed by the French Centre de Données de la Physique des Plasmas (CDPP) including AMDA, the Propagation Tool, 3DView, ... . This presentation will focus on science cases which show the capability of interoperability in the planetary and heliophysics contexts, involving both CDPP and companion tools. Europlanet 2020 RI has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement No 654208.

Analysis of time dependent phenomena observed with the LPSP OSO-8 instrument

NASA Technical Reports Server (NTRS)

Leibacher, J. W.

1979-01-01

The dynamics of the solar photosphere and chromosphere are studied. Observations obtained by the Laboratorie de Physique Stellaire et Planetaire's (LPSP) ultraviolet spectrometer onboard the OSO-8 spacecraft are analyzed, and dynamic models of the chromosphere and the emitted resonance line spectrum are calculated. Some of the unpublished data analysis and theoretical modeling which are being prepared for publication are discussed. A discussion of the state of the theory of velocity fields in the solar atmosphere is also presented. An invited review presented at the OSO-8 Workshop on the topic of oscillatory motions in the quiet sun is included. The results of the OSO-8 data analysis prepared in close collaboration with LPSP scientists are presented. Material for two articles is also presented.

Shared issues of wavefield inversion and illustrations in 3-D diffusive electromagnetics

NASA Astrophysics Data System (ADS)

Lesselier, Dominique; Lambert, Marc; Perrusson, Gaële

2005-07-01

Electromagnetic non-destructive evaluation of complex objects means that one has to decipher data which result from their interaction with imposed sources. This task is crucial in civil, environmental and medical engineering, to quote obvious fields, as well as for safety and reliability of industrial processes of various kinds in key energy and transportation sectors, for example. This short contribution does not attempt to review the huge variety of themes and the many applications of the science of inversion, but aims at emphasizing a number of points that seem common enough to this science to be worthwhile to be reviewed. Two illustrations and a few main references thought of good interest among the ever increasing literature are given. To cite this article: D. Lesselier et al., C. R. Physique 6 (2005).

Competition entre supraconductivite et magnetisme au voisinage de la transition de Mott dans le conducteur organique quasi-bidimensionnel k-(BEDT-TTF)2copper[N(CN)2]bromine

NASA Astrophysics Data System (ADS)

Fournier, David

Les conducteurs organiques quasi-bidimensionnels kappa-ET2X presentent d'importantes similitudes avec les SCHT telles qu'une phase isolant de Mott, un regime de pseudogap et un etat supraconducteur. L'etude de leurs proprietes apparait donc complementaire. Parmi les interrogations persistantes concernant la physique de ces systemes, l'origine du (ou des) processus exotique d'appariement, responsable de la supraconductivite est le sujet suscitant l'interet le plus marque dans la communaute. L'hypothese d'un mecanisme lie a la proximite d'un etat antiferromagnetique est privilegiee. Une etape importante dans la resolution de cette problematique est l'identification de la symetrie du parametre d'ordre. D'apres de nombreux travaux sur les systemes fortement correles, la sonde ultrasonore, de par sa sensibilite aux excitations de quasiparticule a basse temperature, est consideree comme particulierement adaptee a l'etude de cette propriete. Cependant, son emploi necessite l'utilisation d'un compose metallique a basse temperature et completement supraconducteur. Le compose metallique organique kappa-ET 2Cu[N(CN)2]Br presente toutes les caracteristiques necessaires a l'etude de cette propriete. En effet, il est situe loin de la transition du premier ordre de Mott et est completement supraconducteur. De facon surprenante, ce systeme semble se coupler fortement avec le reseau ce qui augmente significativement la sensibilite de cette sonde aux proprietes du gaz electronique. Cependant, des difficultes techniques importantes, liees a la nature intrinseque de ce materiau, doivent etre surmontees pour proceder a des mesures suivant differentes polarisations. La presente etude a profondement modifie notre comprehension de ce systeme. En effet, ces mesures ont permis de constater que le kappa-ET2Cu[N(CN)2]Br est un compose qui est situe en bordure de la zone de coexistence entre la supraconductivite et le magnetisme, ce qui constitue un resultat totalement inattendu. De plus, la variation judicieuse du cycle thermique s'est averee etre equivalente a une modification de la pression chimique. Cette derniere est modifiee par l'intermediaire d'une relaxation structurale autour de 85 K appelee la transition de verre d'ethylenes. Cela nous a permis de suivre l'evolution de cette coexistence en s'approchant de la transition de premier ordre, et ainsi de statuer sur la competition entre la supraconductivite et le magnetisme ainsi que sur l'existence d'une separation de phase d'ordre macroscopique. De plus, nous avons observe une anisotropie similaire sur les mesures de vitesse ultrasonore entre le regime de pseudogap et la supraconductivite. Ce resultat tend a confirmer l'existence d'une physique commune entre le regime de pseudogap et l'etat supraconducteur. Le regime de pseudogap, encore meconnu a ce jour, est probablement relie a des fluctuations antiferromagnetiques, dont l'origine pourrait etre un emboitement de la surface de Fermi quasi-unidimensionnelle de ce compose, ou bien relie a la proximite de la physique de Mott. Enfin, l'analyse de la symetrie du parametre d'ordre supraconducteur, qui est probablement de type s+d, tend a demontrer que les processus de couplage interplan sont d'une importance cruciale. L'approche theorique de Hubbard purement 2D dans le plan conducteur semble donc insuffisante pour la recherche du mecanisme d'appariement.

Statistical model of quiet Sun coronal heating (French Title: Modèle statistique de chauffage de la couronne solaire calme)

NASA Astrophysics Data System (ADS)

Podladchikova, O.

2002-02-01

The high temperature of the solar corona is still a puzzling problem of solar physics. However, the recent observations of satellites SoHO, Yohkoh or TRACE seem to indicate that the processes responsible for the heating of the closed regions are situated in the low corona or in the chromosphere, thus close to the sun surface, and are associated to the direct currents dissipation. Statistical data analysis suggest that the heating mechanisms result thus from numerous events of current layers dissipation of small scale and weak energy, on the resolution limit of modern instruments. We propose a statistical lattice model, resulting from an approach more physical than self-organized criticality, constituted by a magnetic energy source at small scales and by dissipation mechanisms of the currents, which can be associated either to magnetic reconnection or to anomalous resistivity. The various types of sources and mechanisms of dissipation allow to study their influence on the statistical properties of the system, in particular on the energy dissipation. With the aim of quantifying this behavior and allowing detailed comparisons between models and observations, analysis techniques little used in solar physics, such as the singular values decomposition, entropies, or Pearson technique of PDF classification are introduced and applied to the study of the spatial and temporal properties of the model. La température anormalement élevée de la couronne reste un des problèmes majeurs de la physique solaire. Toutefois, les observations récentes des satellites SoHO, Yohkoh ou TRACE semblent indiquer que les processus responsables du chauffage des régions fermées se situent dans la basse couronne ou dans la chromosphère, donc proches de la surface solaire, et sont associés à la dissipation de couches de courant continu. L'analyse statistique de données suggère que les mécanismes de chauffage résulteraient donc de nombreux événements de dissipation de couches de courant de petite échelle et de faible énergie, àla limite de la résolution des instruments modernes. Nous proposons un modèle statistique sur réseau, résultant d'une approche plus physique que la criticalité auto-organisée, constitué d'une source d'énergie magnétique de petite échelle et de mécanismes de dissipation des courants, qui peuvent être associés soit à la reconnection magnétique soit à la résistivité anormale. Les différents types de sources et de mécanismes de dissipation permettent d'étudier leur influence sur les propriétés statistiques du système, en particulier sur l'énergie dissipée. Dans le but de quantifier ces comportements et de permettre des comparaisons approfondies entres les modèles et les observations, des techniques d'analyse peu utilisées en physique solaire, telles que la décomposition en valeurs singulières, des entropies, ou la technique de Pearson de classification des densités de probabilité, sont introduites et appliquées `a l'étude des propriétés spatiales et temporelles du modèle.

Studies of ClO and BrO reactions important in the polar stratosphere: Kinetics and mechanism of the ClO+BrO and ClO+ClO reactions

NASA Technical Reports Server (NTRS)

Friedl, Randall R.; Sander, Stanley P.

1988-01-01

The reactions, BrO + ClO yields Br + ClOO (1a) yields Br + OClO (1b) yields BrCl + O2 (1c) and ClO + ClO yields Cl + CiOO (2a) yields Cl + OClO (2b) yields Cl2 + O2 (2c) yields (ClO)2 (2d) have assumed new importance in explaining the unusual springtime depletion of ozone observed in the Antarctic stratosphere. The mechanisms of these reactions involve the formation of metastable intermediates which subsequently decompose through several energetically allowed products providing the motivation to study these reactions using both the discharge flow-mass spectrometric and flash photolysis - ultraviolet absorption techniques. These methods have also been used to explore aspects of the kinetics and spectroscopy of the ClO dimer.

Chlorine-36 as a tracer of perchlorate origin

USGS Publications Warehouse

Sturchio, N.C.; Caffee, M.; Beloso, Abelardo D.; Heraty, L.J.; Böhlke, J.K.; Hatzinger, P.B.; Jackson, W.A.; Gu, B.; Heikoop, J.M.; Dale, M.

2009-01-01

Perchlorate (ClO4-) is ubiquitous in the environment. It is produced naturally by atmospheric photochemical reactions, and also is synthesized in large quantities for military, aerospace, and industrial applications. Nitrate-enriched salt deposits of the Atacama Desert (Chile) contain high concentrations of natural ClO4-, and have been exported worldwide since the mid-1800s for use in agriculture. The widespread introduction of synthetic and agricultural ClO4- into the environment has contaminated numerous municipal water supplies. Stable isotope ratio measurements of Cl and O have been applied for discrimination of different ClO4- sources in the environment. This study explores the potential of 36Cl measurements for further improving the discrimination of ClO4- sources. Groundwater and desert soil samples from the southwestern United States (U.S.) contain ClO4- having high 36Cl abundances (36Cl/Cl = 3100 ?? 10-15 to 28,800 ?? 10 -15), compared with those from the Atacama Desert (36Cl/Cl = 0.9 ?? 10-15 to 590 ?? 10-15) and synthetic ClO4- reagents and products (36Cl/Cl = 0.0 ?? 10-15 to 40 ?? 1015). In conjunction with stable Cl and O isotope ratios, 36Cl data provide a clear distinction among three principal. ClO4- source types in the environment of the southwestern U.S. ?? 2009 American Chemical Society.

Formation of chlorinated lipids post-chlorine gas exposure

PubMed Central

Ford, David A.; Honavar, Jaideep; Albert, Carolyn J.; Duerr, Mark A.; Oh, Joo Yeun; Doran, Stephen; Matalon, Sadis; Patel, Rakesh P.

2016-01-01

Exposure to chlorine (Cl2) gas can occur during accidents and intentional release scenarios. However, biomarkers that specifically indicate Cl2 exposure and Cl2-derived products that mediate postexposure toxicity remain unclear. We hypothesized that chlorinated lipids (Cl-lipids) formed by direct reactions between Cl2 gas and plasmalogens serve as both biomarkers and mediators of post-Cl2 gas exposure toxicities. The 2-chloropalmitaldehyde (2-Cl-Pald), 2-chlorostearaldehyde (2-Cl-Sald), and their oxidized products, free- and esterified 2-chloropalmitic acid (2-Cl-PA) and 2-chlorostearic acid were detected in the lungs and plasma of mouse and rat models of Cl2 gas exposure. Levels of Cl-lipids were highest immediately post-Cl2 gas exposure, and then declined over 72 h with levels remaining 20- to 30-fold higher at 24 h compared with baseline. Glutathione adducts of 2-Cl-Pald and 2-Cl-Sald also increased with levels peaking at 4 h in plasma. Notably, 3-chlorotyrosine also increased after Cl2 gas exposure, but returned to baseline within 24 h. Intranasal administration of 2-Cl-PA or 2-Cl-Pald at doses similar to those formed in the lung after Cl2 gas exposure led to increased distal lung permeability and inflammation and systemic endothelial dysfunction characterized by loss of eNOS-dependent vasodilation. These data suggest that Cl-lipids could serve as biomarkers and mediators for Cl2 gas exposure and toxicity. PMID:27324796

Formation of chlorinated lipids post-chlorine gas exposure.

PubMed

Ford, David A; Honavar, Jaideep; Albert, Carolyn J; Duerr, Mark A; Oh, Joo Yeun; Doran, Stephen; Matalon, Sadis; Patel, Rakesh P

2016-08-01

Exposure to chlorine (Cl2) gas can occur during accidents and intentional release scenarios. However, biomarkers that specifically indicate Cl2 exposure and Cl2-derived products that mediate postexposure toxicity remain unclear. We hypothesized that chlorinated lipids (Cl-lipids) formed by direct reactions between Cl2 gas and plasmalogens serve as both biomarkers and mediators of post-Cl2 gas exposure toxicities. The 2-chloropalmitaldehyde (2-Cl-Pald), 2-chlorostearaldehyde (2-Cl-Sald), and their oxidized products, free- and esterified 2-chloropalmitic acid (2-Cl-PA) and 2-chlorostearic acid were detected in the lungs and plasma of mouse and rat models of Cl2 gas exposure. Levels of Cl-lipids were highest immediately post-Cl2 gas exposure, and then declined over 72 h with levels remaining 20- to 30-fold higher at 24 h compared with baseline. Glutathione adducts of 2-Cl-Pald and 2-Cl-Sald also increased with levels peaking at 4 h in plasma. Notably, 3-chlorotyrosine also increased after Cl2 gas exposure, but returned to baseline within 24 h. Intranasal administration of 2-Cl-PA or 2-Cl-Pald at doses similar to those formed in the lung after Cl2 gas exposure led to increased distal lung permeability and inflammation and systemic endothelial dysfunction characterized by loss of eNOS-dependent vasodilation. These data suggest that Cl-lipids could serve as biomarkers and mediators for Cl2 gas exposure and toxicity. Copyright © 2016 by the American Society for Biochemistry and Molecular Biology, Inc.

Spectroelectrochemistry and Electrochemistry of Europium Ions in Alkali Chloride Melts

NASA Astrophysics Data System (ADS)

Uehara, Akihiro; Shirai, Osamu; Nagai, Takayuki; Fujii, Toshiyuki; Yamana, Hajimu

2007-04-01

In order to investigate the redox equilibrium of europium ions in molten NaCl-2CsCl, UV-Vis absorption spectrophotometry measurements were performed for Eu2+ and Eu3+ in molten NaCl- 2CsCl at 923 K under simultaneous electrolytic control of their ratio. Molar absorptivities of EuCl3 and EuCl2 in NaCl-2CsCl at 923 K were determined to be (420±21) M -1cm-1 at 31200 cm-1 and (1130±56) M-1cm-1 at 30300 cm-1, respectively. The formal redox potential of the Eu2+/Eu3+ couple in NaCl-2CsCl melt at 923 K was determined to be (-0.941 ±0.004) V vs. Cl2/Cl- by electromotive force measurements on varying concentration ratios of Eu2+ and Eu3+, which were performed using a technique based on the combination of electrolysis and spectrophotometry. Cyclic voltammetry was also carried out in order to examine the characteristics of the voltammograms for the Eu2+/Eu3+ couple in NaCl-2CsCl melt. The formal redox potential of the Eu2+/Eu3+ couple determined by a spectroelectrochemical method agreed with that determined by cyclic voltammetry [(-0.946±0.008) V vs. Cl2/Cl-]. The effects of temperature on the redox potential of the Eu2+/Eu3+ couple in NaCl-2CsCl, NaCl-KCl, LiCl-KCl, and CsCl melts were studied by cyclic voltammetry in the range from 923 to 1123 K.

Oxidative desulfurization of fuels catalyzed by Fenton-like ionic liquids at room temperature.

PubMed

Jiang, Yunqing; Zhu, Wenshuai; Li, Huaming; Yin, Sheng; Liu, Hua; Xie, Qingjie

2011-03-21

Oxidation of the sulfur-containing compounds benzothiophene (BT), dibenzothiophene (DBT), and 4,6-dimethyldibenzothiophene (4,6-DMDBT) has been studied in a desulfurization system composed of model oil, hydrogen peroxide, and different types of ionic liquids [(C(8)H(17))(3)CH(3)N]Cl/FeCl(3), [(C(8)H(17))(3)CH(3)N]Cl/CuCl(2), [(C(8)H(17))(3)CH(3)N]Cl/ZnCl(2), [(C(8)H(17))(3)CH(3)N]Cl/SnCl(2), [(C(4)H(9))(3)CH(3)N]Cl/FeCl(3), [C(10)H(21)(CH(3))(3)N]Cl/FeCl(3), [(C(10)H(21))(2)(CH(3))(2)N]Cl/FeCl(3). Deep desulfurization is achieved in the Fenton-like ionic liquid [(C(8)H(17))(3)CH(3)N]Cl/FeCl(3) at 25 °C for 1 h. The desulfurization of DBT reaches 97.9%, in consuming very low amount of [(C(8)H(17))(3)CH(3)N]Cl/FeCl(3) (only 0.702 mmol). The reaction conditions, for example, the amount of [(C(8)H(17))(3)CH(3)N]Cl/FeCl(3) or H(2)O(2), the temperature, and the molar ratio of FeCl(3) to [(C(8)H(17))(3)CH(3)N]Cl, are investigated for this system. The oxidation reactivity of the different sulfur-containing compounds is found to decrease in the order of DBT>BT>4,6-DMDBT. The desulfurization system can be recycled six times without significant decrease in activity. The sulfur level of FCC gasoline could be reduced from 360 ppm to 110 ppm. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Distinct membrane properties are differentially influenced by cardiolipin content and acyl chain composition in biomimetic membranes.

PubMed

Pennington, Edward Ross; Fix, Amy; Sullivan, E Madison; Brown, David A; Kennedy, Anthony; Shaikh, Saame Raza

2017-02-01

Cardiolipin (CL) has a critical role in maintaining mitochondrial inner membrane structure. In several conditions such as heart failure and aging, there is loss of CL content and remodeling of CL acyl chains, which are hypothesized to impair mitochondrial inner membrane biophysical organization. Therefore, this study discriminated how CL content and acyl chain composition influenced select properties of simple and complex mitochondrial mimicking model membranes. We focused on monolayer excess area/molecule (a measure of lipid miscibility), bilayer phase transitions, and microdomain organization. In monolayer compression studies, loss of tetralinoleoyl [(18:2) 4 ] CL content decreased the excess area/molecule. Replacement of (18:2) 4 CL acyl chains with tetraoleoyl [(18:1) 4 ] CL or tetradocosahexaenoyl [(22:6) 4 ] CL generally had little influence on monolayer excess area/molecule; in contrast, replacement of (18:2) 4 CL acyl chains with tetramyristoyl [(14:0) 4 ] CL increased monolayer excess area/molecule. In bilayers, calorimetric studies showed that substitution of (18:2) 4 CL with (18:1) 4 CL or (22:6) 4 CL lowered the phase transition temperature of phosphatidylcholine vesicles whereas (14:0) 4 CL had no effect. Finally, quantitative imaging of giant unilamellar vesicles revealed differential effects of CL content and acyl chain composition on microdomain organization, visualized with the fluorescent probe Texas Red DHPE. Notably, microdomain areas were decreased by differing magnitudes upon lowering of (18:2) 4 CL content and substitution of (18:2) 4 CL with (14:0) 4 CL or (22:6) 4 CL. Conversely, exchanging (18:2) 4 CL with (18:1) 4 CL increased microdomain area. Altogether, these data demonstrate that CL content and fatty acyl composition differentially target membrane physical properties, which has implications for understanding how CL regulates mitochondrial activity and the design of CL-specific therapeutics. Copyright © 2016 Elsevier B.V. All rights reserved.

Effect of EtOH/MgCl(2) molar ratios on the catalytic properties of MgCl(2)-SiO(2)/TiCl(4) Ziegler-Natta catalyst for ethylene polymerization.

PubMed

Patthamasang, Supanan; Jongsomjit, Bunjerd; Praserthdam, Piyasan

2011-09-29

MgCl(2)-SiO(2)/TiCl(4) Ziegler-Natta catalysts for ethylene polymerization were prepared by impregnation of MgCl(2) on SiO(2) in heptane and further treatment with TiCl(4). MgCl(2)·nEtOH adduct solutions were prepared with various EtOH/MgCl(2) molar ratios for preparation of the MgCl(2)-supported and MgCl(2)-SiO(2)-supported catalysts in order to investigate the effect on polymerization performance of both catalyst systems. The catalytic activities for ethylene polymerization decreased markedly with increased molar ratios of [EtOH]/[MgCl(2)] for the MgCl(2)-supported catalysts, while for the bi-supported catalysts, the activities only decreased slightly. The MgCl(2)-SiO(2)-supported catalyst had relatively constant activity, independent of the [EtOH]/[MgCl(2)] ratio. The lower [EtOH]/[MgCl(2)] in MgCl(2)-supported catalyst exhibited better catalytic activity. However, for the MgCl(2)-SiO(2)-supported catalyst, MgCl(2) can agglomerate on the SiO(2) surface at low [EtOH]/[MgCl(2)] thus not being not suitable for TiCl(4) loading. It was found that the optimized [EtOH]/[MgCl(2)] value for preparation of bi-supported catalysts having high activity and good spherical morphology with little agglomerated MgCl(2) was 7. Morphological studies indicated that MgCl(2)-SiO(2)-supported catalysts have good morphology with spherical shapes that retain the morphology of SiO(2). The BET measurement revealed that pore size is the key parameter dictating polymerization activity. The TGA profiles of the bi-supported catalyst also confirmed that it was more stable than the mono-supported catalyst, especially in the ethanol removal region.

Methadone but not morphine inhibits lubiprostone-stimulated Cl- currents in T84 intestinal cells and recombinant human ClC-2, but not CFTR Cl- currents.

PubMed

Cuppoletti, John; Chakrabarti, Jayati; Tewari, Kirti; Malinowska, Danuta H

2013-05-01

In clinical trials, methadone, but not morphine, appeared to prevent beneficial effects of lubiprostone, a ClC-2 Cl(-) channel activator, on opioid-induced constipation. Effects of methadone and morphine on lubiprostone-stimulated Cl(-) currents were measured by short circuit current (Isc) across T84 cells. Whole cell patch clamp of human ClC-2 (hClC-2) stably expressed in HEK293 cells and in a high expression cell line (HEK293EBNA) as well as human CFTR (hCFTR) stably expressed in HEK293 cells was used to study methadone and morphine effects on recombinant hClC-2 and hCFTR Cl(-) currents. Methadone but not morphine inhibited lubiprostone-stimulated Isc in T84 cells with half-maximal inhibition at 100 nM. Naloxone did not affect lubiprostone stimulation or methadone inhibition of Isc. Lubiprostone-stimulated Cl(-) currents in hClC-2/HEK293 cells, but not forskolin/IBMX-stimulated Cl(-) currents in hCFTR/HEK293 cells, were inhibited by methadone, but not morphine. HEK293EBNA cells expressing hClC-2 showed time-dependent, voltage-activated, CdCl2-inhibited Cl(-) currents in the absence (control) and the presence of lubiprostone. Methadone, but not morphine, inhibited control and lubiprostone-stimulated hClC-2 Cl(-) currents with half-maximal inhibition at 100 and 200-230 nM, respectively. Forskolin/IBMX-stimulated hClC-2 Cl(-) currents were also inhibited by methadone. Myristoylated protein kinase inhibitor (a specific PKA inhibitor) inhibited forskolin/IBMX- but not lubiprostone-stimulated hClC-2 Cl(-) currents. Methadone caused greater inhibition of lubiprostone-stimulated currents added before patching (66.1 %) compared with after patching (28.7 %). Methadone caused inhibition of lubiprostone-stimulated Cl(-) currents in T84 cells and control; lubiprostone- and forskolin/IBMX-stimulated recombinant hClC-2 Cl(-) currents may be the basis for reduced efficacy of lubiprostone in methadone-treated patients.

ClO radical yields in the reaction of O(1D) with Cl2, HCl, chloromethanes, and chlorofluoromethanes.

PubMed

Feierabend, Karl J; Papanastasiou, Dimitrios K; Burkholder, James B

2010-11-18

Absolute ClO radical product yields in the gas-phase reactions of O((1)D) with Cl(2), HCl, CCl(4), CHCl(3), CH(2)Cl(2), CH(3)Cl, CFCl(3), CF(2)Cl(2), CF(3)Cl, CHFCl(2), and CHF(2)Cl are reported. Product yields were measured using pulsed-laser photolysis of O(3) to produce O((1)D) in the presence of excess reactant combined with dual wavelength differential cavity ring-down spectroscopic detection of the ClO radical. ClO radical absorption cross sections for the A(2)Π(v = 10) ← X(2)Π(v = 0) transition band head near 280 nm were determined between 200 and 296 K as part of this work. The ClO product yields obtained at room temperature were Cl(2) (0.77 ± 0.10), HCl (0.20 ± 0.04), CCl(4) (0.79 ± 0.04), CHCl(3) (0.77 ± 0.04), CH(2)Cl(2) (0.73 ± 0.04), CH(3)Cl (0.46 ± 0.06), CFCl(3) (0.79 ± 0.04), CF(2)Cl(2) (0.76 ± 0.06), CF(3)Cl (0.82 ± 0.06), CHFCl(2) (0.73 ± 0.05), and CHF(2)Cl (0.56 ± 0.03), where the quoted error limits are 2σ of the measurement precision. ClO product yields in the O((1)D) + Cl(2) and CFCl(3) reactions were found to be independent of temperature between 200 and 296 K, within the precision of the measurements. The absolute ClO yields obtained in this study are compared with previously reported values determined using relative and indirect methods.

Optimization for zeolite regeneration and nitrogen removal performance of a hypochlorite-chloride regenerant.

PubMed

Zhang, Wei; Zhou, Zhen; An, Ying; Du, Silu; Ruan, Danian; Zhao, Chengyue; Ren, Ning; Tian, Xiaoce

2017-07-01

Simultaneous zeolites regeneration and nitrogen removal were investigated by using a mixed solution of NaClO and NaCl (NaClO-NaCl solution), and effects of the regenerant on ammonium removal performance and textural properties of zeolites were analyzed by long-term adsorption and regeneration operations. Mixed NaClO-NaCl solution removed more NH 4 + exchanged on zeolites and converted more of them to nitrogen than using NaClO or NaCl solution alone. Response surface methodological analysis indicated that molar ratio of hypochlorite and nitrogen (ClO - /N), NaCl concentration and pH value all had significant effects on zeolites regeneration and NH 4 + conversion to nitrogen, and the optimum condition was obtained at ClO - /N of 1.75, NaCl concentration of 20 g/L and pH of 10.0. Zeolites regenerated by mixed NaClO-NaCl solution showed higher ammonium adsorption rate and lower capacity than unused zeolites. Zeolites and the regeneration solution were both effective even after 20 cycles of use. Composition and morphological analysis revealed that the main mineral species and surface morphology of zeolites before and after NaClO-NaCl regeneration were unchanged. Textural analysis indicated that NaClO-NaCl regeneration leads to an increased surface area of zeolites, especially the microporosity. The results indicated that NaClO-NaCl regeneration is an attractive method to achieve sustainable removal of nitrogen from wastewater through zeolite. Copyright © 2017 Elsevier Ltd. All rights reserved.

Expression and function of CLC and cystic fibrosis transmembrane conductance regulator chloride channels in renal epithelial tubule cells: pathophysiological implications.

PubMed

Vandewalle, Alain

2007-01-01

Cl(-) channels play important roles in the regulation of a variety of functions, including electrical excitability, cell volume regulation, transepithelial transport and acidification of cellular organelles. They are expressed in plasma membranes or reside in intracellular organelles. A large number of Cl(-) channels with different functions have been identified. Some of them are highly expressed in the kidney. They include members of the CLC Cl(-) channel family: ClC-K1 (or ClC-Ka), ClC-K2 (or ClC-Kb) and ClC-5. The identification of mutations responsible for human inherited diseases (Bartter syndrome for ClC-Kb and Dent's disease for ClC-5) and studies on knockout mice models have evidenced the physiological importance of these CLC Cl(-) channels, permitting better understanding on their functions in renal tubule epithelial cells. The cystic fibrosis transmembrane conductance regulator (CFTR) Cl(-) channel, also expressed in renal tubule epithelial cells, is involved in the transepithelial transport of Cl(-) in the distal nephron. This short review focuses on intrarenal distribution, subcellular localization and function of the ClK(-1), ClC-K2 and ClC-5 Cl(-) channels in renal tubule epithelial cells, and the role of the CFTR Cl(-) channel in chloride fluxes elicited by vasopressin in the distal nephron.

Measurements of the liquidus surface and solidus transitions of the NaCl-UCl3 and NaCl-UCl3-CeCl3 phase diagrams

NASA Astrophysics Data System (ADS)

Sooby, E. S.; Nelson, A. T.; White, J. T.; McIntyre, P. M.

2015-11-01

NaCl-UCl3-PuCl3 is proposed as the fuel salt for a number of molten salt reactor concepts. No experimental data exists for the ternary system, and limited data is available for the binary compositions of this salt system. Differential scanning calorimetry is used in this study to examine the liquidus surface and solidus transition of a surrogate fuel-salt (NaCl-UCl3-CeCl3) and to reinvestigate the NaCl-UCl3 eutectic phase diagram. The results of this study show good agreement with previously reported data for the pure salt compounds used (NaCl, UCl3, and CeCl3) as well as for the eutectic points for the NaCl-UCl3 and NaCl-CeCl3 binary systems. The NaCl-UCl3 liquidus surface produced in this study predicts a 30-40 °C increase on the NaCl-rich side of the binary phase diagram. The increase in liquidus temperature could prove significant to molten salt reactor modeling.

Determination of product branching ratio of the ClO self-reaction at 298 K

NASA Astrophysics Data System (ADS)

Horowitz, A.; Bauer, D.; Crowley, J. N.; Moortgat, G. K.

1993-07-01

The Cl2-sensitized continuous photolysis of O3 mixtures in O2 was investigated at 298 K using time resolved single wavelength and diode array spectroscopy to monitor the decay of O3 and the formation of OClO. Φ-O3 was found to be 4.1±0.4. This value, combined with the determination of the initial rates of OClO formation, allowed the evaluation of the following branching ratios into the three bimolecular disproportionation channels of ClO reactions; k3a/k3 = 0.40 ± 0.08, k3b/k3 = 0.42 ± 0.08 and k3c/k3 = 0.18 ± 0.02 where ClO + ClO → Cl2 + O2 (3a), ClO + ClO → Cl + Cl + O2 (3b) and ClO + ClO → Cl + OClO (3c).

Cooperative Friedel-Crafts catalysis in heterobimetallic regime: alkylation of aromatics by pi-activated alcohols.

PubMed

Choudhury, Joyanta; Podder, Susmita; Roy, Sujit

2005-05-04

The highly active Friedel-Crafts alkylation (FCA) catalyst, [Ir(COD)Cl(SnCl3)(SnCl4)(arene)]+Cl- (1-SnCl4), is easily generated in one-pot from [Ir(COD)Cl]2 or [Ir(COD)(mu-Cl)Cl(SnCl3)]2 (1) and SnCl4. The reaction of arenes, heteroarenes with benzyl, and allyl alcohols is promoted by 1-SnCl4 (1 mol %) with high turnover frequency. Kinetic evidence is presented to establish FCA pattern. From dual-catalyst combination studies varying the transition metal and main group metal partner, the efficiency of the present catalysts is attributed to the electrophilic "IrIII-SnIV" core.

Coinage metal coordination chemistry of stable primary, secondary and tertiary ferrocenylethyl-based phosphines.

PubMed

Azizpoor Fard, M; Rabiee Kenaree, A; Boyle, P D; Ragogna, P J; Gilroy, J B; Corrigan, J F

2016-02-21

Ferrocene-based phosphines constitute an important auxiliary ligand in inorganic chemistry. Utilizing the (ferrocenylethyl)phosphines (FcCH2CH2)3-nHnP (Fc = ferrocenyl; n = 2, 1; n = 1, 2; n = 0, 3) the synthesis of a series of coordination complexes [(FcCH2CH2)3-nHnPCuCl]4 (n = 2, 1-CuCl; n = 0, 3-CuCl), [(FcCH2CH2)2HPCuCl] (2-CuCl), {[(FcCH2CH2)H2P]2AgCl}2 (1-AgCl), [(FcCH2CH2)2HPAgCl] (2-AgCl), [(FcCH2CH2)3PAgCl]4 (3-AgCl), [(FcCH2CH2)3PM(OAc)]4 (M = Cu, 3-CuOAc M = Ag, 3-AgOAc), [(FcCH2CH2)3-nHnPAuCl] (n = 1, 2-AuCl; n = 0, 3-AuCl), via the reaction between the free phosphine and MX (M = Cu, Ag and Au; X = Cl, OAc), is described. The reaction between the respective phosphine with a suspension of metal-chloride or -acetate in a 1 : 1 ratio in THF at ambient temperature affords coordinated phosphine-coinage metal complexes. Varying structural motifs are observed in the solid state, as determined via single crystal X-ray analysis of 1-CuCl, 3-CuCl, 1-AgCl, 3-AgCl, 3-CuOAc, 3-AgOAc, 2-AuCl and 3-AuCl. Complexes 1-CuCl and 3-CuCl are tetrameric Cu(i) cubane-like structures with a Cu4Cl4 core, whereas silver complexes with primary and tertiary phosphine reveal two different structural types. The structure of 1-AgCl, unlike the rest, displays the coordination of two phosphines to each silver atom and shows a quadrangle defined by two Ag and two Cl atoms. In contrast, 3-AgCl is distorted from a cubane structure via elongation of one of the ClAg distances. 3-CuOAc and 3-AgOAc are isostructural with step-like cores, while complexes 2-AuCl and 3-AuCl reveal a linear geometry of a phosphine gold(i) chloride devoid of any aurophilic interactions. All of the complexes were characterized in solution by multinuclear (1)H, (13)C{(1)H} and (31)P NMR spectroscopic techniques; the redox chemistry of the series of complexes was examined using cyclic voltammetry. This class of complexes has been found to exhibit one reversible Fe(ii)/Fe(iii) oxidation couple, suggesting the absence of electronic communication between the ferrocenyl units on individual phosphine ligands as well as between different phosphines on the polymetallic cores.

The distribution of meteoric 36Cl/Cl in the United States: A comparison of models

USGS Publications Warehouse

Moysey, S.; Davis, S.N.; Zreda, M.; Cecil, L.D.

2003-01-01

The natural distribution of 36Cl/Cl in groundwater across the continental United States has recently been reported by Davis et al. (2003). In this paper, the large-scale processes and atmospheric sources of 36Cl and chloride responsible for controlling the observed 36Cl/Cl distribution are discussed. The dominant process that affects 36Cl/Cl in meteoric groundwater at the continental scale is the fallout of stable chloride from the atmosphere, which is mainly derived from oceanic sources. Atmospheric circulation transports marine chloride to the continental interior, where distance from the coast, topography, and wind patterns define the chloride distribution. The only major deviation from this pattern is observed in northern Utah and southern Idaho where it is inferred that a continental source of chloride exists in the Bonneville Salt Flats, Utah. In contrast to previous studies, the atmospheric flux of 36Cl to the land surface was found to be approximately constant over the United States, without a strong correlation between local 36Cl fallout and annual precipitation. However, the correlation between these variables was significantly improved (R 2=0.15 to R 2=0.55) when data from the southeastern USA, which presumably have lower than average atmospheric 36Cl concentrations, were excluded. The total mean flux of 36Cl over the continental United States and total global mean flux of 36Cl are calculated to be 30.5??7.0 and 19.6??4.5 atoms m-2 s-1, respectively. The 36Cl/Cl distribution calculated by Bentley et al. (1996) underestimates the magnitude and variability observed for the measured 36Cl/Cl distribution across the continental United States. The model proposed by Hainsworth (1994) provides the best overall fit to the observed 36Cl/Cl distribution in this study. A process-oriented model by Phillips (2000) generally overestimates 36Cl/Cl in most parts of the country and has several significant local departures from the empirical data.

Contribution of Resting Conductance, GABAA-Receptor Mediated Miniature Synaptic Currents and Neurosteroid to Chloride Homeostasis in Central Neurons.

PubMed

Yelhekar, Tushar D; Druzin, Michael; Johansson, Staffan

2017-01-01

Maintenance of a low intraneuronal Cl - concentration, [Cl - ] i , is critical for inhibition in the CNS. Here, the contribution of passive, conductive Cl - flux to recovery of [Cl - ] i after a high load was analyzed in mature central neurons from rat. A novel method for quantifying the resting Cl - conductance, important for [Cl - ] i recovery, was developed and the possible contribution of GABA A and glycine receptors and of ClC-2 channels to this conductance was analyzed. The hypothesis that spontaneous, action potential-independent release of GABA is important for [Cl - ] i recovery was tested. [Cl - ] i was examined by gramicidin-perforated patch recordings in medial preoptic neurons. Cells were loaded with Cl - by combining GABA or glycine application with a depolarized voltage, and the time course of [Cl - ] i was followed by measurements of the Cl - equilibrium potential , as obtained from the current recorded during voltage ramps combined with GABA or glycine application. The results show that passive Cl - flux contributes significantly, in the same order of magnitude as does K + -Cl - cotransporter 2 (KCC2), to [Cl - ] i recovery and that Cl - conductance accounts for ∼ 6% of the total resting conductance. A major fraction of this resting Cl - conductance is picrotoxin (PTX)-sensitive and likely due to open GABA A receptors, but ClC-2 channels do not contribute. The results also show that when the decay of GABA A receptor-mediated miniature postsynaptic currents (minis) is slowed by the neurosteroid allopregnanolone, such minis may significantly quicken [Cl - ] i recovery, suggesting a possible steroid-regulated role for minis in the control of Cl - homeostasis.

Bumetanide increases Cl--dependent short-circuit current in late distal colon: Evidence for the presence of active electrogenic Cl- absorption.

PubMed

Tang, Lieqi; Fang, Xiefan; Winesett, Steven P; Cheng, Catherine Y; Binder, Henry J; Rivkees, Scott A; Cheng, Sam X

2017-01-01

Mammalian colonic epithelia consist of cells that are capable of both absorbing and secreting Cl-. The present studies employing Ussing chamber technique identified two opposing short-circuit current (Isc) responses to basolateral bumetanide in rat distal colon. Apart from the transepithelial Cl--secretory Isc in early distal colon that was inhibited by bumetanide, bumetanide also stimulated Isc in late distal colon that had not previously been identified. Since bumetanide inhibits basolateral Na+-K+-2Cl- cotransporter (NKCC) in crypt cells and basolateral K+-Cl- cotransporter (KCC) in surface epithelium, we proposed this stimulatory Isc could represent a KCC-mediated Cl- absorptive current. In support of this hypothesis, ion substitution experiments established Cl- dependency of this absorptive Isc and transport inhibitor studies demonstrated the involvement of an apical Cl- conductance. Current distribution and RNA sequencing analyses revealed that this Cl- absorptive Isc is closely associated with epithelial Na+ channel (ENaC) but is not dependent on ENaC activity. Thus, inhibition of ENaC by 10 μM amiloride or benzamil neither altered the direction nor its activity. Physiological studies suggested that this Cl- absorptive Isc senses dietary Cl- content; thus when dietary Cl- was low, Cl- absorptive Isc was up-regulated. In contrast, when dietary Cl- was increased, Cl- absorptive Isc was down-regulated. We conclude that an active Cl- extrusion mechanism exists in ENaC-expressing late distal colon and likely operates in parallel with ENaC to facilitate NaCl absorption.

Understanding the kinetics of the ClO dimer cycle

NASA Astrophysics Data System (ADS)

von Hobe, M.; Salawitch, R. J.; Canty, T.; Keller-Rudek, H.; Moortgat, G. K.; Grooß, J.-U.; Müller, R.; Stroh, F.

2006-08-01

Among the major factors controlling ozone loss in the polar winter is the kinetics of the ClO dimer catalytic cycle. The most important issues are the thermal equilibrium between ClO and Cl2O2, the rate of Cl2O2 formation, and the Cl2O2 photolysis rate. All these issues have been addressed in a large number of laboratory, field and theoretical studies, but large discrepancies between individual results exist and a self-consistent set of parameters compatible with field observations of ClO and Cl2O2 has not been identified. Here, we use thermodynamic calculations and unimolecular rate theory to constrain the ClO/Cl2O2 equilibrium constant and the rate constants for Cl2O2 formation and dissociation. This information is used together with available atmospheric data to examine Cl2O2 photolysis rates based on different Cl2O2 absorption cross sections. Good overall consistency is achieved using a ClO/Cl2O2 equilibrium constant recently suggested by Plenge et al. (2005), the Cl2O2 recombination rate constant reported by Nickolaisen et al. (1994) and Cl2O2 photolysis rates based on averaged absorption cross sections that are roughly intermediate between the JPL 2002 assessment and a laboratory study by Burkholder et al. (1990).

Effect of Chorda Tympani Nerve Transection on Salt Taste Perception in Mice

PubMed Central

Ishiwatari, Yutaka; Theodorides, Maria L.; Bachmanov, Alexander A.

2011-01-01

Effects of gustatory nerve transection on salt taste have been studied extensively in rats and hamsters but have not been well explored in the mouse. We examined the effects of chorda tympani (CT) nerve transection on NaCl taste preferences and thresholds in outbred CD-1 mice using a high-throughput phenotyping method developed in our laboratory. To measure taste thresholds, mice were conditioned by oral self-administration of LiCl or NaCl and then presented with NaCl concentration series in 2-bottle preference tests. LiCl-conditioned and control NaCl-exposed mice were given bilateral transections of the CT nerve (LiCl-CTX, NaCl-CTX) or were left intact as controls (LiCl-CNT, NaCl-CNT). After recovery from surgery, mice received a concentration series of NaCl (0–300 mM) in 48-h 2-bottle tests. CT transection increased NaCl taste thresholds in LiCl-conditioned mice and eliminated avoidance of concentrated NaCl in control NaCl-exposed mice. This demonstrates that in mice, the CT nerve is important for detection and recognition of NaCl taste and is necessary for the normal avoidance of high concentrations of NaCl. The results of this experiment also show that the method of high-throughput phenotyping of salt taste thresholds is suitable for detecting changes in the taste periphery in mouse genetic studies. PMID:21743094

Multi-parameter observation of environmental asbestos pollution at the Institut de Physique du Globe de Paris (Jussieu Campus, France).

PubMed

Besson, P; Lalanne, F X; Wang, Y; Guyot, F

1999-11-01

An original multi-parameter system has been used to study the nature of dust in the ambient air, particularly the total fibers and asbestos fibers, in eight areas of the Institut de Physique de Globe de Paris (France). These analyses provide a detailed case study of environmental pollution by asbestos fibers at low levels. The levels of total fibers with a length greater than 3 microns, measured with a real time fiber analyser monitor (FAM), give a baseline of 2.5 fibers per l., throughout the duration of sampling. The same levels, calculated during periods of effective presence of staff, are smaller than 10 fb per l. During these periods, the instantaneous value can show high peaks, reaching a maximum of 60 fb per l., but more often of about 5 to 10 fb per l. A direct cause and effect relationship exists between fiber concentrations and the presence of people, and indirectly with the variation of the other environmental parameters (temperature, humidity, air velocity). The baseline concentration of asbestos fibers, determined by analytical transmission electron microscopy (ATEM), is about 10(-1) fb per l., with a mean value during the presence of people always less than 1.5 fb per l. The low levels of asbestos fibers do not allow us to establish a precise correlation between the concentration of total fibers and the asbestos concentration, but a rough estimate suggests that asbestos could represent 10-20% of the airborne fibers monitored with the FAM. The statistical study of fiber sizes shows that 70 and 55% of analyzed chrysotile and amosite fibers respectively are smaller than 5 microns. These numbers are 40 and 35% for fibers smaller than 3 microns, which are undetected by the FAM. Amosite, which characterizes most of the asbestos-containing materials (ACM) in the analyzed areas, is detected in the ambient air in quantities ten times less important than chrysotile. The low asbestos levels and the difference between the nature of building asbestos and airborne fibers, show that the mean measured asbestos contents in the ambient air represent the geochemical background of chrysotile asbestos fibers in the Parisian air.

Relationship of body mass index to percent body fat and waist circumference among schoolchildren in Japan--the influence of gender and obesity: a population-based cross-sectional study.

PubMed

Ochiai, Hirotaka; Shirasawa, Takako; Nishimura, Rimei; Morimoto, Aya; Shimada, Naoki; Ohtsu, Tadahiro; Kujirai, Emiko; Hoshino, Hiromi; Tajima, Naoko; Kokaze, Akatsuki

2010-08-18

Although the correlation coefficient between body mass index (BMI) and percent body fat (%BF) or waist circumference (WC) has been reported, studies conducted among population-based schoolchildren to date have been limited in Japan, where %BF and WC are not usually measured in annual health examinations at elementary schools or junior high schools. The aim of the present study was to investigate the relationship of BMI to %BF and WC and to examine the influence of gender and obesity on these relationships among Japanese schoolchildren. Subjects included 3,750 schoolchildren from the fourth and seventh grade in Ina-town, Saitama Prefecture, Japan between 2004 and 2008. Information about subject's age, sex, height, weight, %BF, and WC was collected from annual physical examinations. %BF was measured with a bipedal biometrical impedance analysis device. Obesity was defined by the following two criteria: the obese definition of the Centers for Disease Control and Prevention, and the definition of obesity for Japanese children. Pearson's correlation coefficients between BMI and %BF or WC were calculated separately for sex. Among fourth graders, the correlation coefficients between BMI and %BF were 0.74 for boys and 0.97 for girls, whereas those between BMI and WC were 0.94 for boys and 0.90 for girls. Similar results were observed in the analysis of seventh graders. The correlation coefficient between BMI and %BF varied by physique (obese or non-obese), with weaker correlations among the obese regardless of the definition of obesity; most correlation coefficients among obese boys were less than 0.5, whereas most correlations among obese girls were more than 0.7. On the other hand, the correlation coefficients between BMI and WC were more than 0.8 among boys and almost all coefficients were more than 0.7 among girls, regardless of physique. BMI was positively correlated with %BF and WC among Japanese schoolchildren. The correlations could be influenced by obesity as well as by gender. Accordingly, it is essential to consider gender and obesity when using BMI as a surrogate for %BF and WC for epidemiological use.

La supraconductivité a 100 ans !

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lebrun, Philippe

2011-04-14

Il y a 100 ans, le 8 avril 1911, une découverte majeure était réalisée : celle de la supraconductivité. La supraconductivité est la caractéristique qu’ont certains métaux et alliages de perdre toute résistance électrique en dessous d’une température donnée. Cette renversante découverte, réalisée de manière presque fortuite par Kammerlingh Onnes de l’Université de Leyde (Pays-Bas) et son étudiant Gilles Holst, a ouvert un nouveau champ de recherche en physique et de fabuleuses perspectives d’applications technologiques. Du point de vue scientifique, la supraconductivité est en effet l’une des rares manifestations de la physique quantique à l’échelle macroscopique.  Du point de vuemore » des retombées techniques, elle est porteuse d’applications majeures dans le domaine de la santé, des communications et de l’énergie. 100 ans après, les physiciens n’ont toujours pas fini d’explorer ce phénomène et ses applications. Le CERN abrite des applications de la supraconductivité à des échelles inédites. L’accélérateur de particules LHC, avec ses milliers d’aimants supraconducteurs répartis sur 27 kilomètres de circonférence, est en effet la plus grande application mondiale de la supraconductivité. Il ne pourrait exister sans elle. Le CERN fête donc la découverte de la supraconductivité avec une conférence exceptionnelle donnée par Philippe Lebrun. Au cours de cette conférence, l’expérience historique de Kammerlingh Onnes sera reproduite. Philippe Lebrun racontera l’histoire de cette étonnante découverte, en la replaçant dans le contexte scientifique de l’époque. Il racontera les développements scientifiques et les applications du premier siècle de la supraconductivité. Conférence en français Merci de bien vouloir vous inscrire au : +41 22 767 76 76 ou cern.reception@cern.ch« less

Beyond Flory theory: Distribution functions for interacting lattice trees

NASA Astrophysics Data System (ADS)

Rosa, Angelo; Everaers, Ralf

2017-01-01

While Flory theories [J. Isaacson and T. C. Lubensky, J. Physique Lett. 41, 469 (1980), 10.1051/jphyslet:019800041019046900; M. Daoud and J. F. Joanny, J. Physique 42, 1359 (1981), 10.1051/jphys:0198100420100135900; A. M. Gutin et al., Macromolecules 26, 1293 (1993), 10.1021/ma00058a016] provide an extremely useful framework for understanding the behavior of interacting, randomly branching polymers, the approach is inherently limited. Here we use a combination of scaling arguments and computer simulations to go beyond a Gaussian description. We analyze distribution functions for a wide variety of quantities characterizing the tree connectivities and conformations for the four different statistical ensembles, which we have studied numerically in [A. Rosa and R. Everaers, J. Phys. A: Math. Theor. 49, 345001 (2016), 10.1088/1751-8113/49/34/345001 and J. Chem. Phys. 145, 164906 (2016), 10.1063/1.4965827]: (a) ideal randomly branching polymers, (b) 2 d and 3 d melts of interacting randomly branching polymers, (c) 3 d self-avoiding trees with annealed connectivity, and (d) 3 d self-avoiding trees with quenched ideal connectivity. In particular, we investigate the distributions (i) pN(n ) of the weight, n , of branches cut from trees of mass N by severing randomly chosen bonds; (ii) pN(l ) of the contour distances, l , between monomers; (iii) pN(r ⃗) of spatial distances, r ⃗, between monomers, and (iv) pN(r ⃗|l ) of the end-to-end distance of paths of length l . Data for different tree sizes superimpose, when expressed as functions of suitably rescaled observables x ⃗=r ⃗/√{ } or x =l / . In particular, we observe a generalized Kramers relation for the branch weight distributions (i) and find that all the other distributions (ii-iv) are of Redner-des Cloizeaux type, q (x ⃗) =C |x| θexp(-(K|x |) t) . We propose a coherent framework, including generalized Fisher-Pincus relations, relating most of the RdC exponents to each other and to the contact and Flory exponents for interacting trees.

Restauration fonctionnelle du rachis : effet du niveau initial de douleur sur les performances des sujets lombalgiques chroniques

PubMed Central

Caby, Isabelle; Olivier, N; Mendelek, F; Kheir, R Bou; Vanvelcenaher, J; Pelayo, P

2014-01-01

HISTORIQUE : La lombalgie chronique est une douleur lombaire persistante d’origine multifactorielle. Le niveau de douleur initial reste faiblement utilisé pour analyser et comparer les réponses des patients lombalgiques au programme de reconditionnement. OBJECTIFS : Apprécier et évaluer les réponses des sujets lombalgiques chroniques très douloureux à une prise en charge dynamique et intensive. MÉTHODOLOGIE : 144 sujets atteints de lombalgie chronique ont été inclus dans un programme de restauration fonctionnelle du rachis de 5 semaines. Les sujets ont été classés en deux groupes de niveau de douleur: un groupe atteint de douleur sévère (n = 28) et un groupe atteint de douleur légère à modérée (n = 106). L’ensemble des sujets ont bénéficié d’une prise en charge identique comprenant principalement de la kinésithérapie, de l’ergothérapie, du reconditionnement musculaire et cardio-vasculaire ainsi qu’un suivi psychologique. Les paramètres physiques (flexibilité, force musculaire) et psychologiques (qualité de vie) ont été mesurés avant (T0) et après le programme (T5sem). RÉSULTATS : L’ensemble des performances physiques et fonctionnelles des sujets très douloureux sont moins bonnes et le retentissement de la lombalgie sur la qualité de vie, pour ces mêmes sujets, est majoré à T0. Toutes les différences significatives constatées à T0 entre les deux groupes s’effacent à T5sem. CONCLUSIONS : Les sujets lombalgiques chroniques très douloureux répondent favorablement au programme dynamique et intensif. L’intensité douloureuse de la lombalgie n’aurait pas d’effet sur les réponses au programme. La restauration fonctionnelle du rachis apporterait aux sujets la possibilité de mieux gérer leur douleur quel que soit son niveau. PMID:25299476

Dépistage des maladies cardiovasculaires chez des étudiants de l'Université de Douala et influence des activités physiques et sportives

PubMed Central

Ewane, Marielle Epacka; Mandengue, Samuel Honoré; Priso, Eugene Belle; Tamba, Stéphane Moumbe; Ahmadou; Fouda, André Bita

2012-01-01

Introduction Les maladies cardiovasculaires (MCV) constituent l'une des principales causes de mortalité dans les pays en développement. Le dépistage de ces dernières chez des jeunes est un défi dans la lutte contre leur expansion. Le but de cette étude était de dépister ces maladies au sein d'une population jeunes d’étudiants camerounais. Methodes Deux mille six cent cinquante-huit étudiants de l'Université de Douala (23,6 ± 2,9 ans, sex-ratio H/F = 0,9) ont en Avril - Mai 2011 participé à une campagne de dépistage gratuit du diabète, de l'hypertension artérielle (HTA) et de l'obésité. Ils ont également été soumis à une d'enquête évaluant leur niveau en activités physiques et sportives (APS). Resultats 12,7% des participants avaient une pression artérielle (PA) ≥ 140/90 mmHg, 3,6% étaient obèses et 0,9% avaient une glycémie ≥1,26 g/L. Des corrélations ont été trouvées entre certains facteurs de risque (diabète, hypertension et obésité) et le niveau académique d'une part (r =0,366; p < 0,0001) et le temps passé devant la télévision d'autres part (r = 0,411; p < 0,0001). L‘APS était inversement corrélée à l‘âge (r =-0,015; p < 0,0001) et au temps passé devant la télévision (r = -0,059; p = 0,002). Conclusion La présence des MCV et leurs facteurs de risque mis en évidence dans cette étude réalisée en milieu estudiantin camerounais interpelle à une prévention et une éducation dans la lutte contre ces dernières. PMID:22655111

Une recension des écrits concernant la réalité psychoaffective des femmes ayant une vulvodynie : Difficultés rencontrées et stratégies développées

PubMed Central

Cantin-Drouin, Maude; Damant, Dominique; Turcotte, Daniel

2008-01-01

HISTORIQUE : Au cours des trois dernières décennies, une attention grandissante a été portée à l’étude du syndrome de vulvodynie, soit un inconfort vulvaire chronique inexpliqué, éprouvé en l’absence de pathologie précisée. En plus d’avoir des répercussions physiques, l’expérience de la vulvodynie comporte une dimension psychosociale. OBJECTIF : Cet article vise à faire une recension des écrits sur la réalité psychoaffective des femmes qui éprouvent une vulvodynie. MÉTHODE : Une recherche documentaire basée sur une exploration systématique de textes présentant des résultats de recherche et recensés dans les principales banques de données en sciences sociales, dont Dissertation Abstracts, Current Contents et PsycINFO, a été réalisée. RÉSULTATS : Cette recension des écrits révèle, malgré la présence de certains résultats divergents, que les femmes ayant une vulvodynie affrontent souvent des difficultés identitaires et psychologiques, qui sont influencées notamment par les normes sociales de sexualité et de féminité. Pour composer avec ces difficultés, les femmes développent différentes stratégies visant à diminuer le stress occasionné par la douleur et à améliorer leur bien-être psychologique. CONCLUSION : Les difficultés relationnelles et psychologiques vécues par les femmes ayant une vulvodynie ne découlent pas seulement de la douleur physique, mais aussi du sens qu’elles lui accordent, souvent influencé par les discours sociaux sur l’hétérosexualité et la féminité. Il importe donc d’intervenir auprès des femmes en tenant compte de l’influence du contexte social tout en poursuivant le développement des connaissances sur les aspects psychosociaux de cette expérience. PMID:18592063

No 129-L'exercice physique pendant la grossesse et le postpartum.

PubMed

Davies, Gregory A L; Wolfe, Larry A; Mottola, Michelle F; MacKinnon, Catherine

2018-02-01

Énoncer une directive canadienne visant à informer les fournisseurs de soins obstétricaux des répercussions, pour la mère, le fœtus et le nouveau-né, des exercices de conditionnement aerobique et musculaire pendant la grossesse. RéSULTATS ATTENDUS: Effets sur la morbidité maternelle, fœtale et néonatale et mesures de la forme physique maternelle. Une recherche sur MEDLINE des articles, publiés en anglais de 1966 à 2002, appartenant aux catégories suivantes : études sur le conditionnement aérobique et musculaire chez des femmes ne faisant pas jusque-là d'exercice et chez des femmes actives avant leur grossesse, ainsi que des études sur les répercussions du conditionnement aérobique et musculaire sur les issues précoces et tardives de la grossesse ou sur les issues néonatales; rapports de synthèse et méta-analyses portant sur l'exercice pendant la grossesse. Les résultats recueillis ont été revus par la Société des obstétriciens et gynécologues du Canada (Comité de la pratique clinique - obstétrique), avec la participation de la Société canadienne de physiologie de l'exercice, et ils ont été classés suivant les critères d'évaluation des preuves établis par le Groupe de travail canadien sur l'examen de santé périodique. VALIDATION: Cette directive a été approuvée par le Comité de pratique clinique - obstétrique de la SOGC, par le Comité exécutif et par le Conseil de la SOGC, ainsi que par le Conseil d'administration de la Société canadienne de physiologie de l'exercice. PARRAINé PAR: la Société des obstétriciens et gynécologues du Canada et par la Société canadienne de physiologie de l'exercice. Copyright © 2018. Published by Elsevier Inc.

Electrochemistry of Europium(III) Chloride in 3 LiCl – NaCl, 3 LiCl – 2 KCl, LiCl – RbCl, and 3 LiCl – 2 CsCl Eutectics at Various Temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schroll, Cynthia A.; Chatterjee, Sayandev; Levitskaia, Tatiana G.

Here we report the effect of changing the eutectic melt composition on the electrochemical properties of europium(III) chloride under pyroprocessing conditions. The number of electrons transferred, redox potentials and diffusion coefficients were determined using various electrochemical and spectroelectrochemical techniques in four different eutectic mixtures (3 LiCl - NaCl, 3 LiCl - 2 KCl, 3 LiCl - RbCl, and 3 LiCl - 2 CsCl) while varying the temperature of the melt. It was determined that Eu3+ undergoes a one electron reduction to Eu2+ in each melt at all temperatures evaluated. Within all the melts a positive shift in the redox potentialmore » as well as an increase in the diffusion coefficient for Eu3+ was observed as the temperature increased. Also observed was a positive shift in the redox potential and increase in the diffusion coefficient for Eu3+ as the weighted average of the cationic radii for the melt decreased.« less

75 FR 6862 - Airworthiness Directives; Bombardier, Inc. Model CL-600-1A11 (CL-600), CL-600-2A12 (CL-601), CL...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-02-12

... hydraulic accumulator screw cap or end cap failure have been experienced on CL-600-2B19 (CRJ) aircraft... experienced on CL-600-2B19 (CRJ) aircraft, resulting in loss of the associated hydraulic system and high... on CL-600-2B19 (CRJ) aircraft, resulting in loss of the associated hydraulic system and high-energy...

SODIUM CHLORIDE AND SELECTIVE DIFFUSION IN LIVING ORGANISMS.

PubMed

Loeb, J

1922-11-20

1. It is shown that NaCl acts like CaCl(2) or LaCl(3) in preventing the diffusion of strong acids through the membrane of the egg of Fundulus with this difference only that a M/8 solution of NaCl acts like a M/1,000 solution of CaCl(2) and like a M/30,000 solution of LaCl(3). 2. It is shown that these salts inhibit the diffusion of non-dissociated weak acid through the membrane of the Fundulus egg but slightly if at all. 3. Both NaCl and CaCl(2) accelerate the diffusion of dissociated strong alkali through the egg membrane of Fundulus and CaCl(2) is more efficient in this respect than NaCl. 4. It is shown that in moderate concentrations NaCl accelerates the rate of diffusion of KCl through the membrane of the egg of Fundulus while CaCl(2) does not.

X-ray spectromicroscopic investigation of natural organochlorine distribution in weathering plant material

NASA Astrophysics Data System (ADS)

Leri, Alessandra C.; Marcus, Matthew A.; Myneni, Satish C. B.

2007-12-01

Natural organochlorine (Cl org) is ubiquitous in soil humus, but the distribution and cycling of different Cl species during the humification of plant material is poorly understood. Our X-ray spectromicroscopic studies indicate that the distributions of Cl org and inorganic Cl -(Cl inorg) in oak leaf material vary dramatically with decay stage, with the most striking changes occurring at the onset of weathering. In healthy or senescent leaves harvested from trees, Cl inorg occurs in sparsely distributed, highly localized "hotspots" associated with trichomes as well as in diffuse concentration throughout the leaf tissue. The Cl inorg associated with trichomes exists either in H-bonded form or in a solid salt matrix, while the Cl inorg in diffuse areas of lower Cl concentration appears exclusively in H-bonded form. Most solid phase Cl inorg leaches from the leaf tissue during early weathering stages, whereas the H-bonded Cl inorg appears to leach away slowly as degradation progresses, persisting through advanced weathering stages. In unweathered leaves, aromatic and aliphatic Cl org were found in rare but concentrated hotspots. In weathered leaves, by contrast, aromatic Cl org hotspots are prevalent, often coinciding with areas of elevated Fe or Mn concentration. Aromatic Cl org is highly soluble in leaves at early weathering stages and insoluble at more advanced stages. These results, combined with optical microscopy, suggest that fungi play a role in the production of aromatic Cl org in weathering leaf material. Aliphatic Cl org occurs in concentrated hotspots in weathered leaves as well as in diffuse areas of low Cl concentration. The distribution and speciation of Cl in weathering oak leaves depicted by this spectromicroscopic study provides new insight into the formation and cycling of Cl org during the decay of natural organic matter.

Differential roles of WNK4 in regulation of NCC in vivo.

PubMed

Yang, Yih-Sheng; Xie, Jian; Yang, Sung-Sen; Lin, Shih-Hua; Huang, Chou-Long

2018-05-01

The Na + -Cl - cotransporter (NCC) in distal convoluted tubule (DCT) plays important roles in renal NaCl reabsorption. The current hypothesis for the mechanism of regulation of NCC focuses on WNK4 and intracellular Cl - concentration ([Cl - ] i ). WNK kinases bind Cl - , and Cl - binding decreases the catalytic activity. It is believed that hypokalemia under low K + intake decreases [Cl - ] i to activate WNK4, which thereby phosphorylates and stimulates NCC through activation of SPAK. However, increased NCC activity and apical NaCl entry would mitigate the fall in [Cl - ] i. Whether [Cl - ] i in DCT under low-K + diet is sufficiently low to activate WNK4 is unknown. Furthermore, increased luminal NaCl delivery also stimulates NCC and causes upregulation of the transporter. Unlike low K + intake, increased luminal NaCl delivery would tend to increase [Cl - ] i . Thus we investigated the role of WNK4 and [Cl - ] i in regulating NCC. We generated Wnk4-knockout mice and examined regulation of NCC by low K + intake and by increased luminal NaCl delivery in knockout (KO) and wild-type mice. Wnk4-KO mice have marked reduction in the abundance, phosphorylation, and functional activity of NCC vs. wild type. Low K + intake increases NCC phosphorylation and functional activity in wild-type mice, but not in Wnk4-KO mice. Increased luminal NaCl delivery similarly upregulates NCC, which, contrary to low K + intake, is not abolished in Wnk4-KO mice. The results reveal that modulation of WNK4 activity by [Cl - ] i is not the sole mechanism for regulating NCC. Increased luminal NaCl delivery upregulates NCC via yet unknown mechanism(s) that may override inhibition of WNK4 by high [Cl - ] i .

State-specific enhancement of Cl+ and Cl- desorption for SiCl4 adsorbed on a Si(100) surface following Cl 2 p and Si 2 p core-level excitations.

PubMed

Chen, J M; Lu, K T

2001-04-02

State-specific desorption for SiCl4 adsorbed on a Si(100) surface at approximately 90 K with variable coverage following the Cl 2p and Si 2p core-level excitations has been investigated using synchrotron radiation. The Cl+ yields show a significant enhancement following the Cl 2p-->8a*1 excitation. The Cl- yields are notably enhanced at the 8a*1 resonance at both Cl 2p and Si 2p edges. The enhancement of the Cl- yield occurs through the formation of highly excited states of the adsorbed molecules. These results provide some new dissociation processes from adsorbates on surfaces via core-level excitation.

Development of a Database of Thermochemical Parameters for Use with the SOLGASMIX Computer Program

DTIC Science & Technology

1988-07-01

TITANIUM CHLORIDE (TICL4) CL4Wl(CR) TUNGSTEN CHLORIDE (WCL4) CL4Wl(G) TUNGSTEN CHLORIDE (WCL4) CL4ZR1(CR) ZIRCONIUM CHLORIDE ( ZRCL4 ) CL4ZR1(G) ZIRCONIUM...CHLORIDE ( ZRCL4 ) % % % CL5MO1(CR) MOLYBDENUM CHLORIDE (MOCL5) CL5MO1(CR,L) MOLYBDENUM CHLORIDE (MOCL5) CL5MO1(G) MOLYBDENUM CHLORIDE (MOCL5) CL5MOI(L

Photochemical oxidation of chloride ion by ozone in acid aqueous solution.

PubMed

Levanov, Alexander V; Isaykina, Oksana Ya; Amirova, Nazrin K; Antipenko, Ewald E; Lunin, Valerii V

2015-11-01

The experimental investigation of chloride ion oxidation under the action of ozone and ultraviolet radiation with wavelength 254 nm in the bulk of acid aqueous solution at pH 0-2 has been performed. Processes of chloride oxidation in these conditions are the same as the chemical reactions in the system O3 - OH - Cl(-)(aq). Despite its importance in the environment and for ozone-based water treatment, this reaction system has not been previously investigated in the bulk solution. The end products are chlorate ion ClO3(-) and molecular chlorine Cl2. The ions of trivalent iron have been shown to be catalysts of Cl(-) oxidation. The dependencies of the products formation rates on the concentrations of O3 and H(+) have been studied. The chemical mechanism of Cl(-) oxidation and Cl2 emission and ClO3(-) formation has been proposed. According to the mechanism, the dominant primary process of chloride oxidation represents the complex interaction with hydroxyl radical OH with the formation of Cl2(-) anion-radical intermediate. OH radical is generated on ozone photolysis in aqueous solution. The key subsequent processes are the reactions Cl2(-) + O3 → ClO + O2 + Cl(-) and ClO + H2O2 → HOCl + HO2. Until the present time, they have not been taken into consideration on mechanistic description and modelling of Cl(-) oxidation. The final products are formed via the reactions 2ClO → Cl2O2, Cl2O2 + H2O → 2H(+) + Cl(-) + ClO3(-) and HOCl + H(+) + Cl(-) ⇄ H2O + Cl2. Some portion of chloride is oxidized directly by O3 molecule with the formation of molecular chlorine in the end.

Evolution of chemically processed air parcels in the lower stratosphere

NASA Technical Reports Server (NTRS)

Stolarski, Richard S.; Douglass, Anne R.; Schoeberl, Mark R.

1994-01-01

Aircraft, ground-based, and satellite measurements indicate large concentrations of ClO in the lower stratosphere in and near the polar vortex. The amount of local ozone depletion caused by these large ClO concentrations will depend on the relative rates of ozone loss and ClO recovery. ClO recovery occurs when NO(x), from HNO3 photolysis, reacts with ClO to form ClONO2. We show that air parcels with large amounts of ClO will experience a subsequent ozone depletion that depends on the solar zenith angle. When the solar zenith angle is large in the middle of winter, the recovery of the ClO concentration in the parcel is slow relative to ozone depletion. In the spring, when the solar zenith angle is smaller, the ClO recovery is much faster. After ClO recovery, the chlorine chemistry has not returned to normal. The ClO has been converted to ClONO2. ClO production from further encounters with PSCs will be limited by the heterogeneous reaction of ClONO2 with water. Large ozone depletions, of the type seen in the Antarctic, occur only if there is significant irreversible denitrification in the air parcel.

Effects of Sodium Chloride, Potassium Chloride and Calcium Chloride on the Formation of α-Dicarbonyl Compounds, Furfurals and Development of Browning in Cookies during Baking.

PubMed

Kocadağlı, Tolgahan; Gökmen, Vural

2016-10-02

Effect of NaCl, KCl, CaCl2, NaHCO3, and NH4HCO3 on the formation of glucosone, 1-deoxyglucosone, 3-deoxyglucosone, glyoxal, methylglyoxal, diacetyl, 5-hydroxymethyl-2-furfural, 2-furfural and browning were investigated in cookies. Presence of 1.5% NaCl, 1% KCl, and 1% CaCl2 on flour basis had no effect on α-dicarbonyl compounds, except 1-deoxyglucosone increased in the presence of KCl and CaCl2. The increase in 5-hydroxymethyl-2-furfural formation in the presence of NaCl, KCl, and CaCl2 did not relate to 3-deoxyglucosone formation and pH changes. NaCl, KCl, and CaCl2 increased browning in cookies. Model reaction systems indicated that NaCl, KCl, and CaCl2 enhance browning by increasing furfurals in caramelization. NaCl, KCl, and CaCl2 decreased browning intensity in heated glucose-glycine system. Usage of CaCl2 in cookies may considerably increase furfurals but not α-dicarbonyl compounds. Sodium reduction can be obtained by replacement with potassium without sacrificing the desired consequences of caramelization in sugar rich bakeries.

The Chlorine Isotope Composition of Earth’s Mantle

NASA Astrophysics Data System (ADS)

Bonifacie, M.; Jendrzejewski, N.; Agrinier, P.; Humler, E.; Coleman, M.; Javoy, M.

2008-03-01

Chlorine stable isotope compositions (δ37Cl) of 22 mid-ocean ridge basalts (MORBs) correlate with Cl content. The high-δ37Cl, Cl-rich basalts are highly contaminated by Cl-rich materials (seawater, brines, or altered rocks). The low-δ37Cl, Cl-poor basalts approach the composition of uncontaminated, mantle-derived magmas. Thus, most or all oceanic lavas are contaminated to some extent during their emplacement. MORB-source mantle has δ37Cl ≤ 1.6 per mil (‰), which is significantly lower than that of surface reservoirs (~ 0‰). This isotopic difference between the surface and deep Earth results from net Cl isotopic fractionation (associated with removal of Cl from the mantle and its return by subduction over Earth history) and/or the addition (to external reservoirs) of a late volatile supply that is 37Cl-enriched.

Separate Cl^- Conductances Activated by cAMP and Ca2+ in Cl^--Secreting Epithelial Cells

NASA Astrophysics Data System (ADS)

Cliff, William H.; Frizzell, Raymond A.

1990-07-01

We studied the cAMP- and Ca2+-activated secretory Cl^- conductances in the Cl^--secreting colonic epithelial cell line T84 using the whole-cell patch-clamp technique. Cl^- and K^+ currents were measured under voltage clamp. Forskolin or cAMP increased Cl^- current 2-15 times with no change in K^+ current. The current-voltage relation for cAMP-activated Cl^- current was linear from -100 to +100 mV and showed no time-dependent changes in current during voltage pulses. Ca2+ ionophores or increased pipette Ca2+ increased both Cl^- and K^+ currents 2-30 times. The Ca2+-activated Cl^- current was outwardly rectified, activated during depolarizing voltage pulses, and inactivated during hyperpolarizing voltage pulses. Addition of ionophore after forskolin further increased Cl^- conductance 1.5-5 times, and the current took on the time-dependent characteristics of that stimulated by Ca2+. Thus, cAMP and Ca2+ activate Cl^- conductances with different properties, implying that these second messengers activate different Cl^- channels or that they induce different conductive and kinetic states in the same Cl^- channel.

Research and progress on ClC-2

PubMed Central

Wang, Hongwei; Xu, Minghui; Kong, Qingjie; Sun, Peng; Yan, Fengyun; Tian, Wenying; Wang, Xin

2017-01-01

Chloride channel 2 (ClC-2) is one of the nine mammalian members of the ClC family. The present review discusses the molecular properties of ClC-2, including CLCN2, ClC-2 promoter and the structural properties of ClC-2 protein; physiological properties; functional properties, including the regulation of cell volume. The effects of ClC-2 on the digestive, respiratory, circulatory, nervous and optical systems are also discussed, in addition to the mechanisms involved in the regulation of ClC-2. The review then discusses the diseases associated with ClC-2, including degeneration of the retina, Sjögren's syndrome, age-related cataracts, degeneration of the testes, azoospermia, lung cancer, constipation, repair of impaired intestinal mucosa barrier, leukemia, cystic fibrosis, leukoencephalopathy, epilepsy and diabetes mellitus. It was concluded that future investigations of ClC-2 are likely to be focused on developing specific drugs, activators and inhibitors regulating the expression of ClC-2 to treat diseases associated with ClC-2. The determination of CLCN2 is required to prevent and treat several diseases associated with ClC-2. PMID:28534947

Ab initio studies of ClOx reactions. VII. Isomers of Cl2O3 and their roles in the ClO+OClO reaction

NASA Astrophysics Data System (ADS)

Zhu, R. S.; Lin, M. C.

2003-05-01

The mechanism for the reaction ClO+OClO has been investigated by ab initio molecular orbital and transition state theory calculations. Nine stable isomers of Cl2O3 (including optical isomers) are located at the B3LYP/6-311+G(3df ) level. The transition states between pairs of isomers are explored and the stability of the isomers and their dissociation mechanisms are discussed. The relative stability predicted by the modified Gaussian-2 (G2M) method at the G2M//B3LYP/6-311+G(3df ) level is ClOCl(O)O>ClOOOCl(C2)>ClOOOCl(Cs)>ClClO3(C3v)>cyc-ClOOCl(O)>ClOOClO. The formation of ClOCl(O)O is dominant at low temperatures, taking place barrierlessly with the second and third order rate constant, k1∞=3.0×10-10 cm3molecule-1 s-1 and k10=1.1×10-17 T-5.5 exp(-398/T) cm6 molecule-2 s-1 in the temperature range of 200-400 K for N2 as the third-body. Over 500 K, formation of ClOO+ClO becomes dominant and ClOCl+1O2 is also competitive. Their overall rate constants can be given by kClOO=1.0×10-22 T2.8 exp(-78/T) and kClOCl=9.6×10-22 T2.4 exp(-1670/T)cm3 molecule-1 s-1, respectively, in the temperature range of 500-2500 K.

ClC Channels and Transporters: Structure, Physiological Functions, and Implications in Human Chloride Channelopathies

PubMed Central

Poroca, Diogo R.; Pelis, Ryan M.; Chappe, Valérie M.

2017-01-01

The discovery of ClC proteins at the beginning of the 1990s was important for the development of the Cl- transport research field. ClCs form a large family of proteins that mediate voltage-dependent transport of Cl- ions across cell membranes. They are expressed in both plasma and intracellular membranes of cells from almost all living organisms. ClC proteins form transmembrane dimers, in which each monomer displays independent ion conductance. Eukaryotic members also possess a large cytoplasmic domain containing two CBS domains, which are involved in transport modulation. ClC proteins function as either Cl- channels or Cl-/H+ exchangers, although all ClC proteins share the same basic architecture. ClC channels have two gating mechanisms: a relatively well-studied fast gating mechanism, and a slow gating mechanism, which is poorly defined. ClCs are involved in a wide range of physiological processes, including regulation of resting membrane potential in skeletal muscle, facilitation of transepithelial Cl- reabsorption in kidneys, and control of pH and Cl- concentration in intracellular compartments through coupled Cl-/H+ exchange mechanisms. Several inherited diseases result from C1C gene mutations, including myotonia congenita, Bartter’s syndrome (types 3 and 4), Dent’s disease, osteopetrosis, retinal degeneration, and lysosomal storage diseases. This review summarizes general features, known or suspected, of ClC structure, gating and physiological functions. We also discuss biophysical properties of mammalian ClCs that are directly involved in the pathophysiology of several human inherited disorders, or that induce interesting phenotypes in animal models. PMID:28386229

Different blocking effects of HgCl2 and NaCl on aquaporins of pepper plants.

PubMed

Martínez-Ballesta, M Carmen; Diaz, Rafael; Martínez, Vicente; Carvajal, Micaela

2003-12-01

In this study we have compared the short-term effects of both NaCl and HgCl2 on aquaporins of Capsicum annuum L. plants, in order to determine whether or not they are similar. Stomatal conductance, turgor, root hydraulic conductance and water status were measured after 0.5, 2, 4 and 6 h of NaCl (60 mmol/L) or HgCl2 (50 micromol/L) treatment. When 60 mmol/L NaCl was added to the nutrient solution, a large decrease in stomatal conductance was observed after 2 h. However, when HgCl2 (50 micromol/L) was added, the decrease occurred after 4 h. The number of open stomata closed was always lower in plants treated with HgCl2 than in plants treated with NaCl. The water content of the Hg(2+)-treated plants was decreased, compared with controls and NaCl-treated. The root hydraulic conductance decreased after HgCl2 and NaCl treatment plants. Turgor of leaf epidermal cells was greatly reduced in plants treated with HgCl2, but remained constant in the NaCl treatment, compared with control plants. The fact that the stomatal conductance was reduced more rapidly after NaCl addition, followed by the stomatal closure, and that both water content and turgor did not differ from the control suggests that in NaCl-treated plants there must be a signal moving from root to shoot. Therefore, the control of plant homeostasis through a combined regulation of root and stomatal exchanges may be dependent on aquaporin regulation.

"JCE" Classroom Activity Connections: NaCl or CaCl[subscript 2], Smart Polymer Gel Tells More

ERIC Educational Resources Information Center

Chen, Yueh-Huey; Lin, Jia-Ying; Wang, Yu-Chen; Yaung, Jing-Fun

2010-01-01

This classroom activity connection demonstrates the differences between the effects of NaCl (a salt of monovalent metal ions) and CaCl[subscript 2] (a salt of polyvalent metal ions) on swollen superabsorbent polymer gels. Being ionic compounds, NaCl and CaCl[subscript 2] both collapse the swollen polymer gels. The gel contracted by NaCl reswells…

Drone-borne GPR design: Propagation issues

NASA Astrophysics Data System (ADS)

Chandra, Madhu; Tanzi, Tullio Joseph

2018-01-01

In this paper, we shall address the electromagnetic wave propagation issues that are critical to determining the feasibility of a drone-borne ground-penetrating radar sensor for humanitarian applications, particularly in the context of disaster management. Frequency- and polarization-dependent scattering, attenuation and dispersion of radar signals penetrating into the sub-surface region will determine the applicability of a drone-mounted radar sensor capable of registering radar echoes for observing and monitoring sub-surface features. The functionality of the radar will thus be assessed depending on key radar parameters that include the central radar frequency, the modulation depth, and the mode of radar operation (pulsed FM, FM-CW), the antenna type, the available power-budget. In the analysis to be presented, the radar equation, together with the aforementioned propagation effects, will be used to simulate the signal strength of radar echoes under different conditions arising from the chosen key-radar parameters and the assumed physical properties of the sub-surface earth medium. The analysis to be presented will indicate whether or not the drone-borne ground-penetrating radar is a feasible system and if it could be constructed with the technologies available today. Taking into account the strict constraints involved to design drone applications for Public Protection and Disaster Relief (PPDR), the ideas developed hereafter are both prospective and exploratory. The objective is to see if a solution can be found in the near future. xml:lang="fr" Dans l'analyse présentée, l'équation radar, ainsi que les effets de propagation susmentionnés, serviront à simuler la puissance du signal des échos radar sous différentes conditions découlant des paramètres clés choisis et les propriétés physiques du milieu sous la surface. L'étude a pour objectif de démontrer si le système est réalisable et s'il peut être construit avec les technologies disponibles aujourd'hui. En raison du contexte très contraignant des applications pour la protection du public et secours en cas de catastrophe, les idées ici développées ont un caractère tout à la fois prospectif et exploratoire, l'objectif étant d'examiner si, dans un avenir proche, une solution se dessinerait.

Solubility of NaCl in aqueous electrolyte solutions from 10 to 100°C

USGS Publications Warehouse

Clynne, M.A.; Potter, R.W.; Haas, J.L.

1981-01-01

The solubilities of NaCl in aqueous KCl, MgCl2, CaCl2, and mixed CaCl2-KCl solutions have been determined from 10 to 100??C. The data were fit to an equation, and the equation was used to calculate values of the change in solubility of NaCl, ???[NaCl]/???T. These values are required for calculations of the rate of migration of fluids in a thermal gradient in rock salt. The data obtained here indicate that the values of ???[NaCl]/???T are 36-73% greater for solutions containing divalent ions than for the NaCl-H2O system.

National Athletic Trainers' Association Position Statement: Anabolic-Androgenic Steroids

PubMed Central

Kersey, Robert D.; Elliot, Diane L.; Goldberg, Linn; Kanayama, Gen; Leone, James E.; Pavlovich, Mike; Pope, Harrison G.

2012-01-01

This NATA position statement was developed by the NATA Research & Education Foundation. Objective This manuscript summarizes the best available scholarly evidence related to anabolic-androgenic steroids (AAS) as a reference for health care professionals, including athletic trainers, educators, and interested others. Background Health care professionals associated with sports or exercise should understand and be prepared to educate others about AAS. These synthetic, testosterone-based derivatives are widely abused by athletes and nonathletes to gain athletic performance advantages, develop their physiques, and improve their body image. Although AAS can be ergogenic, their abuse may lead to numerous negative health effects. Recommendations Abusers of AAS often rely on questionable information sources. Sports medicine professionals can therefore serve an important role by providing accurate, reliable information. The recommendations provide health care professionals with a current and accurate synopsis of the AAS-related research. PMID:23068595

(Gas discharges and applications)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sauers, I.

1988-10-04

The traveler attended the Ninth International Conference on Gas Discharges and Their Applications, which was held in Venice, Italy, on September 19--23, 1988; presented two papers, (1) Ion Chemistry in SF{sub 6} Corona'' and (2) Production of S{sub 2}F{sub 10} by SF{sub 6} Spark Discharge''; and participated in numerous discussions with conference participants on gas discharges related to his work on SF{sub 6}. The traveler visited the Centre de Physique Atomique at the University Paul Sabatier in Toulouse, France, to discuss with Dr. J. Casanovas his work on SF{sub 6} decomposition. Following that visit, the traveler visited the Laboratoire demore » Photoelectricite at the University of Dijon to discuss with Dr. J.-P. Goudonnet his work on surface studies and on the use of tunneling electron spectroscopy for the chemical analysis of surfaces.« less

Le concept suédois pour stockage définitif des déchets nucléaires

NASA Astrophysics Data System (ADS)

Hedman, Tommy; Nyström, Anders; Thegerström, Claes

2002-10-01

The purpose of a disposal is to isolate the radioactive waste from man and the environment. If the isolation is broken, the leakage and transport of radioactive substances must be retarded. The package is one of several barriers, used to achieve these two main functions. For short-lived, low and intermediate level waste four standard containers of steel and concrete are used. Spent fuel will be placed in a canister consisting of a pressure-bearing insert of cast nodular iron and an outer corrosion barrier of copper before it is deposited in a deep geological repository. In particular, the development of a high integrity copper canister for the isolation of spent nuclear fuel is described in this paper. To cite this article: T. Hedman et al., C. R. Physique 3 (2002) 903-913.

Microscopie de fluorescence de protéines autofluorescentes uniques pour la biologie cellulaire

NASA Astrophysics Data System (ADS)

Cognet, Laurent; Coussen, Françoise; Choquet, Daniel; Lounis, Brahim

In this paper we review the applicability of autofluorescent proteins for single-molecule imaging in biology. The photophysical characteristics of several mutants of the Green Fluorescent Protein (GFP) and those of DsRed are compared and critically discussed for their use in cellular biology. The alternative use of two-photon excitation at the single-molecule level or Fluorescence Correlation Spectroscopy is envisaged for the study of individual autofluorescent proteins. Single-molecule experiments performed in live cells using eGFP and preferably eYFP fusion proteins are reviewed. Finally, the first use at the single-molecule level of citrine, a more photostable variant of the eYFP is reported when fused to a receptor for neurotransmitter in live cells. To cite this article: L. Cognet et al., C. R. Physique 3 (2002) 645-656.

The prevalence and consequences of subclinical eating disorders in female athletes.

PubMed

Beals, K A; Manore, M M

1994-06-01

A growing body of evidence suggests that the prevalence of eating disorders and excessive concerns regarding body weight in certain subpopulations of female athletes are increasing. The pressure on female athletes to improve their performances and physiques, coupled with the general sociocultural demand placed on all women to be thin, often results in attempts to achieve unrealistic body size and body weight goals. For some female athletes the pressure to achieve and maintain a low body weight leads to potentially harmful patterns of restrictive eating or chronic dieting. This paper seeks to further delineate the characteristics of a recently identified subclinical eating disorder in female athletes: anorexia athletica. Research studies that support the existence of subclinical eating disorders will be reviewed. In addition, the possible physiological and psychological consequences of subclinical eating disorders will be explored.

Analysis of time dependent phenomena observed with the LPSP OSO-8 instrument. [solar chromosphere and photosphere

NASA Technical Reports Server (NTRS)

Leibacher, J. W.

1979-01-01

Data obtained by the Laboratoire de Physique Stellaire et Planetaire's ultraviolet spectrometer onboard the OSO-8 spacecraft were analyzed in an effort to dynamically model the solar chromosphere as an aid in enhancing knowledge of the dynamical processes themselves and of spectral line formation in the dynamic chromosphere. Repeated spectral scans of strong, optically thick resonance lines formed in the solar chromosphere were examined for indications of oscillatory velocities and intensities among other indications of velocity which were studied, the blue peak is reasonably well defined, and the position of a parabolic filter fitted by the least squares method was used to define it. Observed chromospheric oscillation periods are discussed as well as the variations in altitude of the emitting region which result primarily from the motion up and down during the oscillation.

Physiscope

ScienceCinema

Gaumer, Olivier

2018-05-24

Peut-on survivre à une décharge de 100000 volts? Le corps humain est-il conducteur? Qu'est-ce la charge électrique? L'air est-il conducteur? Quel est le meilleur conducteur connu? Autant de question que l'on se posera durant cette découverte de la physique et le l'électricité, par une approche originale, ludique et participative. Venez glisser en lévitation sur une trottinette supraconductrice! [Can we survive a discharge of 100,000 volts? Is the human body conductive? What is the electric charge? Is the air conductive? What is the best known driver? As much question as one will ask during this discovery of the physics and the electricity, by an original, playful and participative approach. Come levitate on a superconducting scooter!

Chlorine-36 in seawater

NASA Astrophysics Data System (ADS)

Argento, David C.; Stone, John O.; Keith Fifield, L.; Tims, Stephen G.

2010-04-01

Natural cosmogenic 36Cl found in seawater originates from spallation of atmospheric 40Ar, capture of secondary cosmic-ray neutrons by dissolved 35Cl, and river runoff which contains 36Cl produced in situ over the surface of the continents. The long residence time of chloride in the ocean and long half-life of 36Cl compared to the oceanic mixing time should result in a homogenous 36Cl/Cl ratio throughout the ocean. Production by neutron capture in the course of nuclear weapons testing should be insignificant averaged over the oceans as a whole, but may have led to regions of elevated 36Cl concentration. Previous attempts to measure the 36Cl/Cl ratio of seawater have been hindered by interferences, contamination, or insufficient analytic sensitivity. Here we report preliminary measurements on seawater samples, which demonstrate that the 36Cl/Cl ratio is 0.5 ± 0.3 × 10 -15, in reasonable agreement with calculated contributions from the sources listed above.

Evidence for Live Cl-36 in Ca-Al-rich Inclusions from the Ningqiang Carbonaceous Chondrite

NASA Technical Reports Server (NTRS)

Lin, Y.; Guan, Y.; Leshin, L. A.; Ouyang, Z.; Wang, D.

2004-01-01

The short-lived radionuclide Cl-36 decays to either Ar-36 (98.1%, beta(sup -)) or S-36 (1.9%, epsilon and beta(sup +)), with a half life of 3.01 x 10(exp 5) yr. Both the nucleosynthetic and spallation models suggest high initial Cl-36/Cl-35 ratios ((Cl-36/Cl-35)o up to approximately 10(exp -4)) in the early solar system. Previous observed excess Ar-36 in Efremovka matrix has been interpreted to represent a much lower (Cl-36/Cl-35)o ratio of approximately 1 x 10(exp -6). From the observed S-36 excesses in sodalite in calcium aluminum-rich inclusions (CAIs), we report in this study the first direct evidence of the presence of Cl-36 in primitive meteorites. The inferred (Cl-36/Cl-35)o ratios range from approximately 5 x 10(exp -6) to approximately 1 x 10(exp -5).

Thermofluid effect on energy storage in fluidized bed reactor

NASA Astrophysics Data System (ADS)

Mahfoudi, Nadjiba; El Ganaoui, Mohammed; Moummi, Abdelhafid

2016-05-01

The development of innovative systems of heat storage is imperative to improve the efficiency of the existing systems used in the thermal solar energy applications. Several techniques were developed and realized in this context. The technology of the sand fluidized bed (sandTES) offers a promising alternative to the current state-of-the-art of the heat storage systems, such as fixed bed using a storage materials, as sand, ceramic, and stones, etc. Indeed, the use of the fluidization technique allows an effective heat transfer to the solid particles. With the sand, an important capacity of storage is obtained by an economic and ecological material [N. Mahfoudi, A. Moummi, M. El Ganaoui, Appl. Mech. Mater. 621, 214 (2014); N. Mahfoudi, A. Khachkouch, A. Moummi B. Benhaoua, M. El Ganaoui, Mech. Ind. 16, 411 (2015); N. Mahfoudi, A. Moummi, M. El Ganaoui, F. Mnasri, K.M. Aboudou, 3e Colloque internationale Francophone d"énergétique et mécanique, Comores, 2014, p. 91]. This paper presents a CFD simulation of the hydrodynamics and the thermal transient behavior of a fluidized bed reactor of sand, to determine the characteristics of storage. The simulation shows a symmetry breaking that occurs and gave way to chaotic transient generation of bubble formation after 3 s. Furthermore, the predicted average temperature of the solid phase (sand) increases gradually versus the time with a gain of 1 °C in an interval of 10 s. Contribution to the topical issue "Materials for Energy Harvesting, Conversion and Storage (ICOME 2015) - Elected submissions", edited by Jean-Michel Nunzi, Rachid Bennacer and Mohammed El Ganaoui

Patterns of aluminum hydroxychloride deposition onto the skin.

PubMed

Mayeux, Géraldine; Xhauflaire-Uhoda, Emmanuelle; Piérard, Gérald E

2012-02-01

Aluminum hydroxychloride (AlCl(3) ) is an antiperspirant. To revisit the AlCl(3) deposition in vivo and in vitro on glass slides and stratum corneum (SC) harvested by cyanoacrylate skin surface strippings (CSSS). Transepidermal water loss (TEWL) was assessed following application of 5% AlCl(3) on the forearms. The AlCl(3) -coated skin, glass slides and CSSS were observed using two ultraviolet light-emitting CCD cameras in order to record changes in specular reflectance related to AlCl(3) deposition. In addition, the corneoxenometry bioassay was performed in order to predict AlCl(3) irritation. AlCl(3) deposited on glass slides looked as linear threads and rings of similar sizes. AlCl(3) deposits on skin were almost restricted inside the microrelief lines and as annular deposits at their crossings where acrosyringia are opening. After daily AlCl(3) applications, deposits extended on the CSSS plateaus. At rest in absence of sweating, TEWL was decreased following AlCl(3) applications. During physical exercise, the TEWL increase was limited on the AlCl(3) areas. CSSS appeared unreactive to AlCl(3) at the corneoxenometry bioassay. The similar aspect of AlCl(3) deposits on human SC and on glass slides suggested a physical property of AlCl(3) . Repetitive applications of AlCl(3) increased both the deposit area and the barrier function. © 2011 John Wiley & Sons A/S.

Chlorine isotope fractionation between chloride (Cl-) and dichlorine (Cl2)

NASA Astrophysics Data System (ADS)

Giunta, Thomas; Labidi, Jabrane; Eggenkamp, Hans G. M.

2017-09-01

The use of chlorine stable isotopes (35Cl and 37Cl) can help to constrain natural processes that involve chlorine species with different oxidation states. Theoretical studies based on thermodynamic and quantum mechanical approaches predict large isotope fractionation during redox reactions but to date, these reactions have not been studied experimentally. Here, we explore the chlorine isotope fractionation during the oxidation of hydrated Cl- (redox state of -I) to Cl2 (redox state of 0) at 25 °C and at 0 °C. Our apparatus consists of a sealed glass reactor where liquid HCl is mixed with liquid H2O2, a strong oxidant. Following complex reaction pathways, this mixture ultimately leads to the oxidation of Cl- and to the formation of Cl2 gas. As long as it is degassing, the Cl2 gas is flushed out of solution using N2 as a vector-gas from the glass-reactor to a potassium hydroxide (KOH) solution (pH 14) where it disproportionates into soluble species: Cl- and ClO-. After each experiment, the chlorine isotopic composition was measured in the recovered KOH-trap solution, as well as in the residual HCl solution. Consistent with theoretical predictions, the produced Cl2 gas is always enriched in the heavier 37Cl as compared to the initial Cl-reservoir. The following isotope fractionation factors are obtained: At 0 °C the isotopic fractionation 1000ln α(Cl2-Cl-) is 4.51 (+1.65/-0.49)‰ At 25 °C the isotopic fractionation 1000ln α(Cl2-Cl-) is 3.94 (+0.69/-0.18)‰. From the obtained data it is suggested that the production of Cl2 gas in our experiments is best described by a closed-system distillation. Our results are in agreement with published theoretical ab-initio calculations.

Understanding the kinetics of the ClO dimer cycle

NASA Astrophysics Data System (ADS)

von Hobe, M.; Salawitch, R. J.; Canty, T.; Keller-Rudek, H.; Moortgat, G. K.; Grooß, J.-U.; Müller, R.; Stroh, F.

2007-06-01

Among the major factors controlling ozone loss in the polar vortices in winter/spring is the kinetics of the ClO dimer catalytic cycle. Here, we propose a strategy to test and improve our understanding of these kinetics by comparing and combining information on the thermal equilibrium between ClO and Cl2O2, the rate of Cl2O2 formation, and the Cl2O2 photolysis rate from laboratory experiments, theoretical studies and field observations. Concordant with a number of earlier studies, we find considerable inconsistencies of some recent laboratory results with rate theory calculations and stratospheric observations of ClO and Cl2O2. The set of parameters for which we find the best overall consistency - namely the ClO/Cl2O2 equilibrium constant suggested by Plenge et al. (2005), the Cl2O2 recombination rate constant reported by Nickolaisen et al. (1994) and Cl2O2 photolysis rates based on absorption cross sections in the range between the JPL 2006 assessment and the laboratory study by Burkholder et al. (1990) - is not congruent with the latest recommendations given by the JPL and IUPAC panels and does not represent the laboratory studies currently regarded as the most reliable experimental values. We show that the incorporation of new Pope et al. (2007) Cl2O2 absorption cross sections into several models, combined with best estimates for other key parameters (based on either JPL and IUPAC evaluations or on our study), results in severe model underestimates of observed ClO and observed ozone loss rates. This finding suggests either the existence of an unknown process that drives the partitioning of ClO and Cl2O2, or else some unidentified problem with either the laboratory study or numerous measurements of atmospheric ClO. Our mechanistic understanding of the ClO/Cl2O2 system is grossly lacking, with severe implications for our ability to simulate both present and future polar ozone depletion.

Selective synthesis of cis- and trans-[(NHC(Me))2PtCl2] and [NHC(Me)Pt(cod)Cl][NHC(Me)PtCl3] using NHC(Me)SiCl4.

PubMed

Lewis-Alleyne, Lesley C; Bassil, Bassem S; Böttcher, Tobias; Röschenthaler, Gerd-Volker

2014-11-14

NHC(Me)SiCl4 (NHC(Me) = 1,3-dimethylimidazolidin-2-ylidene) was used to synthesise novel NHC(Me)-Pt(ii) complexes. An atypical trans-cis isomerisation process was also achieved for [(NHC(Me))2PtCl2], while the synthesis of the unique double-complex salt [(NHC(Me))Pt(cod)Cl] [(NHC(Me))PtCl3] (cod = 1,5-cyclooctadiene) revealed the first-ever N-heterocyclic carbene analogue of the Cossa's salt anion.

FIB-SEM cathodoluminescence tomography: practical and theoretical considerations.

PubMed

De Winter, D A M; Lebbink, M N; Wiggers De Vries, D F; Post, J A; Drury, M R

2011-09-01

Focused ion beam-scanning electron microscope (FIB-SEM) tomography is a powerful application in obtaining three-dimensional (3D) information. The FIB creates a cross section and subsequently removes thin slices. The SEM takes images using secondary or backscattered electrons, or maps every slice using X-rays and/or electron backscatter diffraction patterns. The objective of this study is to assess the possibilities of combining FIB-SEM tomography with cathodoluminescence (CL) imaging. The intensity of CL emission is related to variations in defect or impurity concentrations. A potential problem with FIB-SEM CL tomography is that ion milling may change the defect state of the material and the CL emission. In addition the conventional tilted sample geometry used in FIB-SEM tomography is not compatible with conventional CL detectors. Here we examine the influence of the FIB on CL emission in natural diamond and the feasibility of FIB-SEM CL tomography. A systematic investigation establishes that the ion beam influences CL emission of diamond, with a dependency on both the ion beam and electron beam acceleration voltage. CL emission in natural diamond is enhanced particularly at low ion beam and electron beam voltages. This enhancement of the CL emission can be partly explained by an increase in surface defects induced by ion milling. CL emission enhancement could be used to improve the CL image quality. To conduct FIB-SEM CL tomography, a recently developed novel specimen geometry is adopted to enable sequential ion milling and CL imaging on an untilted sample. We show that CL imaging can be manually combined with FIB-SEM tomography with a modified protocol for 3D microstructure reconstruction. In principle, automated FIB-SEM CL tomography should be feasible, provided that dedicated CL detectors are developed that allow subsequent milling and CL imaging without manual intervention, as the current CL detector needs to be manually retracted before a slice can be milled. Due to the required high electron beam acceleration voltage for CL emission, the resolution for FIB-SEM CL tomography is currently limited to several hundreds of nm in XY and up to 650 nm in Z for diamonds. Opaque materials are likely to have an improved Z resolution, as CL emission generated deeper in the material is not able to escape from it. © 2011 The Authors Journal of Microscopy © 2011 Royal Microscopical Society.

Oxalyl chloride, ClC(O)C(O)Cl: UV/vis spectrum and Cl atom photolysis quantum yields at 193, 248, and 351 nm.

PubMed

Ghosh, Buddhadeb; Papanastasiou, Dimitrios K; Burkholder, James B

2012-10-28

Oxalyl chloride, (ClCO)(2), has been used as a Cl atom photolytic precursor in numerous laboratory kinetic and photochemical studies. In this study, the UV/vis absorption spectrum of (ClCO)(2) and the Cl atom quantum yields in its photolysis at 193, 248, and 351 nm are reported. The UV∕vis spectrum was measured between 200 and 450 nm at 296 K using diode array spectroscopy in conjunction with an absolute cross section obtained at 213.9 nm. Our results are in agreement with the spectrum reported by Baklanov and Krasnoperov [J. Phys. Chem. A 105, 97-103 (2001)], which was obtained at 11 discrete wavelengths between 193.3 and 390 nm. Cl atom quantum yields, Φ(λ), were measured using pulsed laser photolysis coupled with time resolved atomic resonance fluorescence detection of Cl. The UV photolysis of (ClCO)(2) has been shown in previous studies to occur via an impulsive three-body dissociation mechanism, (COCl)(2) + hv → ClCO* + Cl + CO (2), where the excited ClCO radical, ClCO*, either dissociates or stabilizes ClCO* → Cl + CO (3a), → ClCO (3b). ClCO is thermally unstable at the temperatures (253-298 K) and total pressures (13-128 Torr) used in our experiments ClCO + M → Cl + CO + M (4) leading to the formation of a secondary Cl atom that was resolvable in the Cl atom temporal profiles obtained in the 248 and 351 nm photolysis of (ClCO)(2). Φ(193 nm) was found to be 2.07 ± 0.37 independent of bath gas pressure (25.8-105.7 Torr, N(2)), i.e., the branching ratio for channel 2a or the direct formation of 2Cl + 2CO in the photolysis of (ClCO)(2) is >0.95. At 248 nm, the branching ratio for channel 2a was determined to be 0.79 ± 0.15, while the total Cl atom yield, i.e., following the completion of reaction (4), was found to be 1.98 ± 0.26 independent of bath gas pressure (15-70 Torr, N(2)). Φ(351 nm) was found to be pressure dependent between 7.8 and 122.4 Torr (He, N(2)). The low-pressure limit of the total Cl atom quantum yield, Φ(0)(351 nm), was 2.05 ± 0.24. As part of this work, rate coefficients for the thermal decomposition of ClCO were measured between 253 and 298 K at total pressures between 13 and 128 Torr (He and N(2) bath gases). The N(2) bath gas results were combined with the data reported in Nicovich et al. [J. Chem. Phys. 92, 3539-3544 (1990)] to yield k(4)(T, N(2)) = (4.7 ± 0.7) × 10(-10) exp [-(2987 ± 16)/T] cm(3) molecule(-1) s(-1), while the He bath gas data fit yielded k(4)(T, He) = (2.3 ± 2.1) × 10(-10) exp [-(2886 ± 218)/T] cm(3) molecule(-1) s(-1). The quoted uncertainties are at the 2σ level from the precision of the fit. In addition, the room temperature rate coefficient for the Cl + ClNO reaction was measured in this work to be (1.03 ± 0.10) × 10(-10) cm(3) molecule(-1) s(-1).

Electroneutral, HCO3(-)-independent, pH gradient-dependent uphill transport of Cl- by ileal brush-border membrane vesicles. Possible role in the pathogenesis of chloridorrhea.

PubMed Central

Vasseur, M; Caüzac, M; Alvarado, F

1989-01-01

By applying a rapid filtration technique to isolated brush border membrane vesicles from guinea pig ileum, 36Cl uptake was quantified in the presence and absence of electrical, pH and alkali-metal ion gradients. A mixture of 20 mM-Hepes and 40 mM-citric acid, adjusted to the desired pH with Tris base, was found to be the most suitable buffer. Malate and Mes could be used to replace the citrate, but succinate, acetate and maleate proved to be unsuitable. In the absence of a pH gradient (pHout:pHin = 7.5:7.5), Cl- uptake increased slightly when an inside-positive membrane potential was applied, but uphill transport was never observed. A pH gradient (pHout:pHin = 5.0:7.5) induced both a 400% increase in the initial Cl- influx rate and a long-lasting (20 to 300 s) overshoot, indicating that a proton gradient can furnish the driving force for uphill Cl- transport. Under pH gradient conditions, initial Cl- entry rates had the following characteristics. (1) They were unaffected by cis-Na+ and/or -K+, indicating the absence of Cl-/K+, Cl-/Na+ or Cl-/K+/Na+ symport activity. (2) Inhibition by 20-100 mM-trans-Na+ and/or -K+ occurred, independent of the existence of an ion gradient. (3) Cl- entry was practically unaffected by short-circuiting the membrane potential with equilibrated potassium and valinomycin. (4) Carbonyl cyanide m-chlorophenylhydrazone was strongly inhibitory and so, to a lesser extent, was 4-acetamido-4'-isothiocyanostilbene-2,2'-disulphonic acid [(SITS)], independent of the sign and size of the membrane potential. (5) Cl- entry was negligibly increased (less than 30%) by either trans-Cl- or -HCO3-, indicating the absence of an obligatory Cl-/anion antiport activity. In contrast, the height of the overshoot at 60 s was increased by trans-Cl-, indicating time-dependent inhibition of 36Cl efflux. That competitive inhibition of 36Cl fluxes by anions is involved here is supported by initial influx rate experiments demonstrating: (1) the saturability of Cl- influx, which was found to exhibit Michaelis-Menten kinetics; and (2) competitive inhibition of influx by cis-Cl- and -Br-. Quantitatively, the conclusion is warranted that over 85% of the total initial Cl- uptake energized by a pH gradient involves an electroneutral Cl-/H+ symporter or its physicochemical equivalent, a Cl-/OH- antiporter, exhibiting little Cl- uniport and either Cl-/Cl- or Cl-/HCO3- antiport activities.(ABSTRACT TRUNCATED AT 400 WORDS) PMID:2597129

Chloride-dependency of amyloid beta protein-induced enhancement of glutamate neurotoxicity in cultured rat hippocampal neurons.

PubMed

Zhang, Nan-Yan; Kitagawa, Kaori; Wu, Bo; Xiong, Zheng-Mei; Otani, Hitomi; Inagaki, Chiyoko

2006-05-15

In our previous studies, pathophysiological concentrations of amyloid-beta (Abeta) proteins increased intracellular Cl(-) concentration ([Cl(-)]i) and enhanced glutamate neurotoxicity in primary cultured neurons, suggesting Cl(-)-dependent changes in glutamate signaling. To test this possibility, we examined the effects of isethionate-replaced low Cl(-) medium on the Abeta-induced enhancement of glutamate neurotoxicity in the primary cultured rat hippocampal neurons. In a normal Cl(-) (135 mM) medium, treatment with 10 nM Abeta25-35 for 2 days increased neuronal [Cl(-)]i to a level three times higher than that of control as assayed using a Cl(-)-sensitive fluorescent dye, while in a low Cl(-) (16 mM) medium such an Abeta25-35-induced increase in [Cl(-)]i was not observed. The Abeta treatment aggravated glutamate neurotoxicity in a normal Cl(-) medium as measured by mitochondrial reducing activity and lactate dehydrogenase (LDH) release, while in a low Cl(-) medium the Abeta treatment did not enhance glutamate toxicity. Upon such Abeta plus glutamate treatment under a normal Cl(-) condition, activated anti-apoptotic molecule Akt (Akt-pS473) level monitored by Western blot significantly decreased to 74% of control. Under a low Cl(-) condition, a resting Akt-pS473 level was higher than that under a normal Cl(-) condition and did not significantly change upon Abeta plus glutamate treatment. Tyrosine phosphorylation levels of 110 and 60 kDa proteins (pp110 and pp60) increased upon Abeta plus glutamate treatment under a normal Cl(-), but not low Cl(-), condition. These findings indicated that Abeta-induced enhancement of glutamate neurotoxicity is Cl(-)-dependent. Chloride-sensitive Akt pathway and tyrosine phosphorylation of proteins (pp110 and pp60) may be involved in this process.

The structure of Pseudomonas P51 Cl-muconate lactonizing enzyme: Co-evolution of structure and dynamics with the dehalogenation function

PubMed Central

Kajander, Tommi; Lehtiö, Lari; Schlömann, Michael; Goldman, Adrian

2003-01-01

Bacterial muconate lactonizing enzymes (MLEs) catalyze the conversion of cis,cis-muconate as a part of the β-ketoadipate pathway, and some MLEs are also able to dehalogenate chlorinated muconates (Cl-MLEs). The basis for the Cl-MLEs dehalogenating activity is still unclear. To further elucidate the differences between MLEs and Cl-MLEs, we have solved the structure of Pseudomonas P51 Cl-MLE at 1.95 Å resolution. Comparison of Pseudomonas MLE and Cl-MLE structures reveals the presence of a large cavity in the Cl-MLEs. The cavity may be related to conformational changes on substrate binding in Cl-MLEs, at Gly52. Site-directed mutagenesis on Pseudomonas MLE core positions to the equivalent Cl-MLE residues showed that the variant Thr52Gly was rather inactive, whereas the Thr52Gly-Phe103Ser variant had regained part of the activity. These residues form a hydrogen bond in the Cl-MLEs. The Cl-MLE structure, as a result of the Thr-to-Gly change, is more flexible than MLE: As a mobile loop closes over the active site, a conformational change at Gly52 is observed in Cl-MLEs. The loose packing and structural motions in Cl-MLE may be required for the rotation of the lactone ring in the active site necessary for the dehalogenating activity of Cl-MLEs. Furthermore, we also suggest that differences in the active site mobile loop sequence between MLEs and Cl-MLEs result in lower active site polarity in Cl-MLEs, possibly affecting catalysis. These changes could result in slower product release from Cl-MLEs and make it a better enzyme for dehalogenation of substrate. PMID:12930985

NHC→SiCl4 : an ambivalent carbene-transfer reagent.

PubMed

Böttcher, Tobias; Steinhauer, Simon; Lewis-Alleyne, Lesley C; Neumann, Beate; Stammler, Hans-Georg; Bassil, Bassem S; Röschenthaler, Gerd-Volker; Hoge, Berthold

2015-01-07

The addition of BCl3 to the carbene-transfer reagent NHC→SiCl4 (NHC=1,3-dimethylimidazolidin-2-ylidene) gave the tetra- and pentacoordinate trichlorosilicon(IV) cations [(NHC)SiCl3 ](+) and [(NHC)2 SiCl3 ](+) with tetrachloroborate as counterion. This is in contrast to previous reactions, in which NHC→SiCl4 served as a transfer reagent for the NHC ligand. The addition of BF3 ⋅OEt2 , on the other hand, gave NHC→BF3 as the product of NHC transfer. In addition, the highly Lewis acidic bis(pentafluoroethyl)silane (C2 F5 )2 SiCl2 was treated with NHC→SiCl4 . In acetonitrile, the cationic silicon(IV) complexes [(NHC)SiCl3 ](+) and [(NHC)2 SiCl3 ](+) were detected with [(C2 F5 )SiCl3 ](-) as counterion. A similar result was already reported for the reaction of NHC→SiCl4 with (C2 F5 )2 SiH2 , which gave [(NHC)2 SiCl2 H][(C2 F5 )SiCl3 ]. If the reaction medium was changed to dichloromethane, the products of carbene transfer, NHC→Si(C2 F5 )2 Cl2 and NHC→Si(C2 F5 )2 ClH, respectively, were obtained instead. The formation of the latter species is a result of chloride/hydride metathesis. These compounds may serve as valuable precursors for electron-poor silylenes. Furthermore, the reactivity of NHC→SiCl4 towards phosphines is discussed. The carbene complex NHC→PCl3 shows similar reactivity to NHC→SiCl4 , and may even serve as a carbene-transfer reagent as well. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

A high-throughput method to measure NaCl and acid taste thresholds in mice.

PubMed

Ishiwatari, Yutaka; Bachmanov, Alexander A

2009-05-01

To develop a technique suitable for measuring NaCl taste thresholds in genetic studies, we conducted a series of experiments with outbred CD-1 mice using conditioned taste aversion (CTA) and two-bottle preference tests. In Experiment 1, we compared conditioning procedures involving either oral self-administration of LiCl or pairing NaCl intake with LiCl injections and found that thresholds were the lowest after LiCl self-administration. In Experiment 2, we compared different procedures (30-min and 48-h tests) for testing conditioned mice and found that the 48-h test is more sensitive. In Experiment 3, we examined the effects of varying strength of conditioned (NaCl or LiCl taste intensity) and unconditioned (LiCl toxicity) stimuli and concluded that 75-150 mM LiCl or its mixtures with NaCl are the optimal stimuli for conditioning by oral self-administration. In Experiment 4, we examined whether this technique is applicable for measuring taste thresholds for other taste stimuli. Results of these experiments show that conditioning by oral self-administration of LiCl solutions or its mixtures with other taste stimuli followed by 48-h two-bottle tests of concentration series of a conditioned stimulus is an efficient and sensitive method to measure taste thresholds. Thresholds measured with this technique were 2 mM for NaCl and 1 mM for citric acid. This approach is suitable for simultaneous testing of large numbers of animals, which is required for genetic studies. These data demonstrate that mice, like several other species, generalize CTA from LiCl to NaCl, suggesting that they perceive taste of NaCl and LiCl as qualitatively similar, and they also can generalize CTA of a binary mixture of taste stimuli to mixture components.

Chloride and organic chlorine in forest soils: storage, residence times, and influence of ecological conditions.

PubMed

Redon, Paul-Olivier; Abdelouas, Abdesselam; Bastviken, David; Cecchini, Sébastien; Nicolas, Manuel; Thiry, Yves

2011-09-01

Recent studies have shown that extensive chlorination of natural organic matter significantly affects chlorine (Cl) residence time in soils. This natural biogeochemical process must be considered when developing the conceptual models used as the basis for safety assessments regarding the potential health impacts of 36-chlorine released from present and planned radioactive waste disposal facilities. In this study, we surveyed 51 French forested areas to determine the variability in chlorine speciation and storage in soils. Concentrations of total chlorine (Cl(tot)) and organic chlorine (Cl(org)) were determined in litterfall, forest floor and mineral soil samples. Cl(org) constituted 11-100% of Cl(tot), with the highest concentrations being found in the humus layer (34-689 mg Cl(org) kg(-1)). In terms of areal storage (53 - 400 kg Cl(org) ha(-1)) the mineral soil dominated due to its greater thickness (40 cm). Cl(org) concentrations and estimated retention of organochlorine in the humus layer were correlated with Cl input, total Cl concentration, organic carbon content, soil pH and the dominant tree species. Cl(org) concentration in mineral soil was not significantly influenced by the studied environmental factors, however increasing Cl:C ratios with depth could indicate selective preservation of chlorinated organic molecules. Litterfall contributions of Cl were significant but generally minor compared to other fluxes and stocks. Assuming steady-state conditions, known annual wet deposition and measured inventories in soil, the theoretical average residence time calculated for total chlorine (inorganic (Cl(in)) and organic) was 5-fold higher than that estimated for Cl(in) alone. Consideration of the Cl(org) pool is therefore clearly important in studies of overall Cl cycling in terrestrial ecosystems.

Molecular emission in laser-induced breakdown spectroscopy: An investigation of its suitability for chlorine quantification on Mars

NASA Astrophysics Data System (ADS)

Vogt, D. S.; Rammelkamp, K.; Schröder, S.; Hübers, H. W.

2018-03-01

The intensity of the molecular CaCl emission in LIBS spectra is examined in order to evaluate its suitability for the detection of chlorine in a Martian environment. Various mixtures resembling Martian targets with varying Cl content are investigated under simulated Martian conditions. The reactions leading to the formation of CaCl are modeled based on reaction kinetics and are used to fit the measured CaCl band intensities. MgCl bands are also investigated as potential alternatives to CaCl, but no MgCl bands can be identified in samples containing both Mg and Cl. The study confirms that CaCl is well suited for the indirect detection of chlorine, but finds a strong dependence on the concentrations of Ca and Cl in the sample. Spectra from samples with a high chlorine concentration can have low-intensity CaCl emission due to a deficiency of Ca. A qualitative estimate of the sample composition is possible based on the ratio of the band intensity of CaCl to the intensity of Ca emission lines. Time-resolved measurements show that the CaCl concentration in the plasma is highest after about 1 μs.

Theoretical insight into the binding energy and detonation performance of ε-, γ-, β-CL-20 cocrystals with β-HMX, FOX-7, and DMF in different molar ratios, as well as electrostatic potential.

PubMed

Feng, Rui-Zhi; Zhang, Shu-Hai; Ren, Fu-de; Gou, Rui-Jun; Gao, Li

2016-06-01

Molecular dynamics method was employed to study the binding energies on the selected crystal planes of the ε-, γ-, β-conformation 2,4,6,8,10,12-hexanitrohexaazaisowurtzitane (ε-, γ-, β-CL-20) cocrystal explosives with 1,1-diamino-2,2-dinitroethylene (FOX-7), 1,3,5,7-tetranitro- 1,3,5,7-tetrazacyclooctane with β-conformation (β-HMX) and N,N-dimethylformamide (DMF) in different molar ratios. The oxygen balance, density, detonation velocity, detonation pressure, and surface electrostatic potential were analyzed. The results indicate that the binding energies E b (*) and stabilities are in the order of 1:1 > 2:1 > 3:1 > 5:1 > 8:1 (CL-20:FOX-7/β-HMX/DMF). The values of E b (*) and stabilities of the energetic-nonenergetic CL-20/DMF cocrystals are far larger than those of the energetic-energetic CL-20/FOX-7 and CL-20/β-HMX, and those of CL-20/β-HMX are the smallest. For CL-20/FOX-7 and CL-20/β-HMX, the largest E b (*) appears in the cocrystals with the 1:1, 1:2 or 1:3 molar ratio, and the stabilities of the cocrystals with the excess ratio of CL-20 are weaker than those in the cocrystals with the excess ratio of FOX-7 or β-HMX. In CL-20/FOX-7, CL-20 prefers adopting the γ-form, and ε-CL-20 is the preference in CL-20/β-HMX, and ε-CL-20 and β-CL-20 can be found in CL-20/DMF. The CL-20/FOX-7 and CL-20/β-HMX cocrystals with low molar ratios can meet the requirements of low sensitive high energetic materials. Surface electrostatic potential reveals the nature of the sensitivity change upon the cocrystal formation. Graphical Abstract MD method was employed to study the binding energies on the selected crystal planes in the ε-, γ-, β-CL-20 cocrystals with FOX-7, β-HMX and DMF in different molar ratios. Surface electrostatic potential reveals the nature of the sensitivity change in cocrystals.

Direct observation of ClO from chlorine nitrate photolysis. [as mechanism of polar ozone depletion

NASA Technical Reports Server (NTRS)

Minton, Timothy K.; Nelson, Christine M.; Moore, Teresa A.; Okumura, Mitchio

1992-01-01

Chlorine nitrate photolysis has been investigated with the use of a molecular beam technique. Excitation at both 248 and 193 nanometers led to photodissociation by two pathways, ClONO2 yields ClO + NO2 and ClONO2 yields Cl + NO3, with comparable yields. This experiment provides a direct measurement of the ClO product channel and consequently raises the possibility of an analogous channel in ClO dimer photolysis. Photodissociation of the ClO dimer is a critical step in the catalytic cycle that is presumed to dominate polar stratospheric ozone destruction. A substantial yield of ClO would reduce the efficiency of this cycle.

Ionic liquids and solids with paramagnetic anions.

PubMed

Krieger, Brenna M; Lee, Heather Y; Emge, Thomas J; Wishart, James F; Castner, Edward W

2010-08-21

Four paramagnetic ionic compounds have been prepared and their magnetic, structural and thermal properties have been investigated. The four compounds are methylbutylpyrrolidinium tetrachloroferrate(III) ([Pyrr(14)](+)/[FeCl(4)](-)), methyltributylammonium tetrachloroferrate(III) ([N(1444)](+)/[FeCl(4)](-)), butylmethylimidazolium tetrachloroferrate(III) ([bmim](+)/[FeCl(4)](-)) and tetrabutylammonium bromotrichloroferrate(III) ([N(4444)](+)/[FeBrCl(3)](-)). Temperature-dependent studies of their magnetic behaviors show that all four compounds are paramagnetic at ambient temperatures. Glass transitions are observed for only two of the four compounds, [Pyrr(14)](+)/[FeCl(4)](-) and [bmim](+)/[FeCl(4)](-). Crystal structures for [Pyrr(14)](+)/[FeCl(4)](-) and [N(1444)](+)/[FeCl(4)](-) are compared with the previously reported [N(4444)](+)/[FeBrCl(3)](-).

Physiological adjustment to salt stress in Jatropha curcas is associated with accumulation of salt ions, transport and selectivity of K+, osmotic adjustment and K+/Na+ homeostasis.

PubMed

Silva, E N; Silveira, J A G; Rodrigues, C R F; Viégas, R A

2015-09-01

This study assessed the capacity of Jatropha curcas to physiologically adjust to salinity. Seedlings were exposed to increasing NaCl concentrations (25, 50, 75 and 100 mm) for 15 days. Treatment without NaCl was adopted as control. Shoot dry weight was strongly reduced by NaCl, reaching values of 35% to 65% with 25 to 100 mm NaCl. The shoot/root ratio was only affected with 100 mm NaCl. Relative water content (RWC) increased only with 100 mm NaCl, while electrolyte leakage (EL) was much enhanced with 50 mm NaCl. The Na(+) transport rate to the shoot was more affected with 50 and 100 mm NaCl. In parallel, Cl(-) transport rate increased with 75 and 100 mm NaCl, while K(+) transport rate fell from 50 mm to 100 mm NaCl. In roots, Na(+) and Cl(-) transport rates fell slightly only in 50 mm (to Na(+)) and 50 and 100 mm (to Cl(-)) NaCl, while K(+) transport rate fell significantly with increasing NaCl. In general, our data demonstrate that J. curcas seedlings present changes in key physiological processes that allow this species to adjust to salinity. These responses are related to accumulation of Na(+) and Cl(-) in leaves and roots, K(+)/Na(+) homeostasis, transport of K(+) and selectivity (K-Na) in roots, and accumulation of organic solutes contributing to osmotic adjustment of the species. © 2015 German Botanical Society and The Royal Botanical Society of the Netherlands.

Effect of Halide Flux on Physicochemical Properties of MgCl2-Based Molten Salts for Accelerating Zirconium Production: Thermodynamic Assessment

NASA Astrophysics Data System (ADS)

Shin, Jae Hong; Park, Joo Hyun

2016-09-01

The effective halide flux additive for increasing the density of MgCl2 mixture and for decreasing the activity of MgCl2 was investigated in order to improve the reaction efficiency between gaseous ZrCl4 and fresh Mg melt to produce zirconium sponge. Thermochemical computation using FactSageTM software was primarily carried out, followed by the experimental confirmation. The addition of CaCl2, BaCl2, MgF2, and CaF2 to the molten MgCl2 increases the density of the melts, indicating that these halide additives can be a candidate to increase the density of the MgCl2-based molten salts. Among them, BaCl2, MgF2, and CaF2 are the useful additives. The activity of MgCl2 can be reduced by the addition of BaCl2, KCl, NaCl, MgF2, and CaF2, among which the CaF2 is the most effective additive to reduce the activity of MgCl2 with the strongest negative deviation from an ideality. Thus, the addition of CaF2 to the MgCl2, forming the MgCl2-CaF2 binary melt, is the most effective way not only to increase the density of the melt but also to decrease the activity of MgCl2, which was experimentally confirmed. Consequently, the production rate of zirconium sponge by magnesiothermic reduction process can be accelerated by the addition of CaF2.

Evaluating evidence for Cl sources and oxidation chemistry in a coastal, urban environment

NASA Astrophysics Data System (ADS)

Young, C. J.; Washenfelder, R. A.; Edwards, P. M.; Parrish, D. D.; Gilman, J. B.; Kuster, W. C.; Mielke, L. H.; Osthoff, H. D.; Tsai, C.; Pikelnaya, O.; Stutz, J.; Veres, P. R.; Roberts, J. M.; Griffith, S.; Dusanter, S.; Stevens, P. S.; Flynn, J.; Grossberg, N.; Lefer, B.; Holloway, J. S.; Peischl, J.; Ryerson, T. B.; Atlas, E. L.; Blake, D. R.; Brown, S. S.

2013-05-01

The role of chlorine atoms (Cl) in atmospheric oxidation was traditionally thought to be limited to the marine boundary layer, where they are produced through heterogeneous reactions involving sea salt. However, recent observation of photolytic Cl precursors (ClNO2 and Cl2) formed from anthropogenic pollution has expanded the potential importance of Cl to include coastal and continental urban areas. Measurements of ClNO2 in Los Angeles during CalNex showed it to be an important primary (first generation) radical source. Ratios of volatile organic compounds (VOCs) have been proposed as a sensitive method to quantify Cl oxidation, but have shown little evidence for a significant role of Cl outside of the Arctic. We used a box model with the Master Chemical Mechanism (MCM v3.2) chemistry scheme, constrained by observations in Los Angeles, to examine the Cl-sensitivity of the most commonly used VOC ratios (i-butane, n-butane, and propane) as a function of NOx and secondary radical production. Model results indicated these and faster reacting VOC tracer ratios could not detect the influence of Cl unless the sustained ratio of OH to Cl was below 200. However, the model results also show that secondary (second generation) OH production resulting from Cl oxidation of VOCs is strongly influenced by NOx, and that this effect can obscure the importance of Cl as a primary oxidant. Calculated concentrations of Cl showed a maximum in mid-morning due to a photolytic source from ClNO2 and loss primarily to reactions with VOCs. The OH to Cl ratio was below 200 for approximately three hours in the morning, but Cl oxidation was not evident from the measured ratios of VOCs. Instead, model simulations show that secondary OH production causes VOC ratios to follow the values expected for OH oxidation despite the significant input of primary Cl from ClNO2 photolysis in the morning. Despite the prevalence of secondary OH as an oxidant in Los Angeles, Cl may play an important role in tropospheric chemistry. The reactivity of Cl in Los Angeles during CalNex was more than an order of magnitude larger than that of OH. In addition, because of its reactivity toward different classes of VOCs and its greater propensity to participate in chain propagation rather than sink reactions, Cl atoms have a different impact on regional atmospheric oxidation than do OH radicals.

Electrical Conductivities of Low-Temperature KCl-ZrCl4 and CsCl-ZrCl4 Molten Mixtures

NASA Astrophysics Data System (ADS)

Salyulev, Alexander B.; Potapov, Alexei M.

2018-02-01

The electrical conductivities of molten KCl-ZrCl4 and CsCl-ZrCl4 mixtures, including their heterogeneous (melt+crystals) ranges, were measured for the first time. The concentration ranges were 65-72 and 66-75 mol.% of ZrCl4, and the temperature ranges were 482-711 and 548-735 K, respectively. The measurements were carried out in cells of an original design.

Matrix isolation infrared spectra, assignment and DFT investigation on reactions of iron and manganese monoxides with CH3Cl.

PubMed

Zhao, Yanying; Fan, Kexue; Huang, Yongfei; Zheng, Xuming

2013-12-01

The reactions of iron and manganese monoxide molecules (FeO, and MnO) with monochloromethane in solid argon have been studied by matrix isolation infrared spectroscopy and quantum chemistry calculations. When annealing, the reactions of FeO and MnO with CH3Cl first form the OM-(η(Cl)-CH3Cl) (MMn, Fe) complexes, which can isomerize to CH3MOCl (MMn, Fe) upon 300<λ<580 nm irradiation. The products were characterized by isotopic IR studies with CD3Cl and (13)CH3Cl and density functional calculations. Based on theoretical calculations, the OFe-(η(Cl)-CH3Cl) and OMn-(η(Cl)-CH3Cl) complexes have (5)A' and (6)A' ground state with Cs symmetry, respectively. The accurate CCSD(T) single point calculations illustrate the CH3MOCl isomerism are 13.8 and 3.1 kcal/mol lower in energy than the OM-(η(Cl)-CH3Cl) (MMn, Fe) complexes. Copyright © 2013 The Authors. Published by Elsevier B.V. All rights reserved.

ZnCl 2- and NH 4Cl-hydroponics gel electrolytes for zinc-carbon batteries

NASA Astrophysics Data System (ADS)

Khalid, N. H.; Ismail, Y. M. Baba; Mohamad, A. A.

Absorbency testing is used to determine the percentage of ZnCl 2 or NH 4Cl solution absorbed by a hydroponics gel (HPG). It is found that the absorbency of ZnCl 2 or NH 4Cl solution decreases with increasing solution concentration. The conductivity of ZnCl 2- and NH 4Cl-HPG electrolytes is dependent on the solution concentration. A mixture of salt solution with HPG yields excellent gel polymer electrolytes with conductivities of 0.026 and 0.104 S cm -1 at 3 M ZnCl 2 and 7 M NH 4Cl, respectively. These gel electrolytes are then used to produce zinc-carbon cells. The fabricated cells give capacities of 8.8 and 10.0 mAh, have an internal resistance of 25.4 and 19.8 Ω, a maximum power density of 12.7 and 12.2 mW cm -2, and a short-circuit current density of 29.1 and 33.9 mA cm -2 for ZnCl 2- and NH 4Cl-HPG electrolytes, respectively.

On the Post-Compaction Evolution of Tensile Strength of Sodium Chloride-Starch Mixture Tablets.

PubMed

Radojevic, Jovana; Zavaliangos, Antonios

2017-08-01

This study focuses on the evolution of mechanical behavior of starch and sodium chloride (NaCl) mixture tablets after compaction. This type of mixture has attracted attention in the past because such tablets exhibit lower tensile strengths than the ones of its individual components. Here we demonstrate that the strengths of NaCl-starch mixtures and NaCl tablets evolve after compaction in an opposite way. When stored at relative humidity of 60%, NaCl tablets strengthen with time, whereas NaCl-starch mixtures weaken. To explain this behavior, we propose that in the NaCl-starch mixture, the presence of 2 materials with significantly different elastic moduli leads to creation of tensile stresses at the stiffer NaCl-NaCl contacts. Such tensile stresses lead to a reduction in strength of the compacted mixtures by negating a local dissolution-reprecipitation mechanism, which strengthens the NaCl-NaCl in pure NaCl tablet. This effect is proven by experimental results from NaCl specimens diametrically loaded during storage. Copyright © 2017 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

Initial hydration processes of magnesium chloride: size-selected anion photoelectron spectroscopy and ab initio calculations.

PubMed

Feng, Gang; Liu, Cheng-Wen; Zeng, Zhen; Hou, Gao-Lei; Xu, Hong-Guang; Zheng, Wei-Jun

2017-06-14

To understand the initial hydration processes of MgCl 2 , we measured photoelectron spectra of MgCl 2 (H 2 O) n - (n = 0-6) and conducted ab initio calculations on MgCl 2 (H 2 O) n - and their neutral counterparts up to n = 7. A dramatic drop in the vertical detachment energy (VDE) was observed upon addition of the first water molecule to bare MgCl 2 - . This large variation in VDE can be associated with the charge-transfer-to-solvent (CTTS) effect occurring in the MgCl 2 (H 2 O) n - clusters, as hydration induces transfer of the excess electron of MgCl 2 - to the water molecules. Investigation of the separation of Cl - -Mg 2+ ion pair shows that, in MgCl 2 (H 2 O) n - anions, breaking of the first Mg-Cl bond occurs at n = 4, while breaking of the second Mg-Cl bond takes place at n = 6. For neutral MgCl 2 (H 2 O) n clusters, breaking of the first Mg-Cl bond starts at n = 7.

Ni(II)-tetrahedral complexes: Characterization, antimicrobial properties, theoretical studies and a new family of charge-transfer transitions

NASA Astrophysics Data System (ADS)

Sarı, Nurşen; Şahin, Songül Çiğdem; Öğütcü, Hatice; Dede, Yavuz; Yalcin, Soydan; Altundaş, Aliye; Doğanay, Kadir

2013-04-01

A new amine containing selenium and their five imine, (SeSchX)(X: -H, F, Cl, Br, CH3), and Ni (II) complexes, [Ni(SeSchX)(H2O)2]Cl/[Ni(SeSchCl)(H2O)Cl], were synthesized. The compounds were characterized by means of elemental analyses, 13C and 1H NMR (for imine), FT-IR, UV-Visible spectroscopy, TGA/DTA and elemental analyses. [Ni(SeSchCl)(H2O)Cl] complex from Ni(II) complexes changes color from yellow to orange in the range pH 5-7. [Ni(SeSchCl)(H2O)Cl] complex has ligand-to-metal charge-transfer (LMCT) transitions in the basic medium. Excitation characteristics and energetic of [Ni(SeSchCl)(H2O)Cl] complex, examined via TD-DFT calculations, reveals transitions of LMCT and π → π* character that matches the experimental values. [Ni(SeSchCl)(H2O)Cl] complex showed the highest antibacterial activity when compared to other complexes reported in this work.

The Response of ClO Radical Concentrations to Variations in NO2 Radical Concentrations in the Lower Stratosphere

NASA Technical Reports Server (NTRS)

Stimpfle, R. M.; Koplow, J. P.; Cohen, R. C.; Kohn, D. W.; Wennberg, P. O.; Judah, D. M.; Toohey, D. W.; Avallone, L. M.; Anderson, J. G.; Salawitch, R. J.

1994-01-01

The response of ClO concentrations to changes in NO2 concentrations has been inferred from simultaneous observations of [ClO], [NO], [NO2] and [O3] in the mid-latitude lower stratosphere. This analysis demonstrates that [ClO] is inversely correlated with [NO2], consistent with formation and photolysis of [ClONO2]. A factor of ten range in the concentration of NO2 was sampled (0.1 to 1 x 10(exp 9) mol/cc), with a comparable range in the ratio of [ClO] to total available inorganic chlorine (1% <= [ClO]/[Cl(sub y)] <= 5%). This analysis leads to an estimate of [ClONO2]/[Cl(sub y)] = 0.12 (x/divided by 2), in the mid-latitude, lower-stratospheric air masses sampled.

Stability of numerous novel potassium chlorides at high pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Weiwei; Oganov, Artem R.; Lobanov, Sergey S.

K-Cl is a simple system displaying all four main types of bonding, as it contains (i) metallic potassium, (ii) elemental chlorine made of covalently bonded Cl 2 molecules held together by van der Waals forces, and (iii) an archetypal ionic compound KCl. The charge balance rule, assigning classical charges of “+1” to K and “–1” to Cl, predicts that no compounds other than KCl are possible. However, our quantum-mechanical variable-composition evolutionary simulations predict an extremely complex phase diagram, with new thermodynamically stable compounds K 3Cl, K 2Cl, K 3Cl 2, K 4Cl 3, K 5Cl 4, K 3Cl 5, KClmore » 3 and KCl 7. Of particular interest are 2D-metallic homologs K n+1Cl n, the presence of positively charged Cl atoms in KCl 7, and the predicted stability of KCl 3 already at nearly ambient pressures at zero Kelvin. We have synthesized cubic Pm3¯n -KCl 3 at 40–70 GPa and trigonal P3¯cl -KCl 3 at 20–40 GPa in a laser-heated diamond anvil cell (DAC) at temperature exceeding 2000 K from KCl and Cl 2. These phases were identified using in situ synchrotron X-ray diffraction and Raman spectroscopy. Lastly, upon unloading to 10 GPa, P3¯cl -KCl 3 transforms to a yet unknown structure before final decomposition to KCl and Cl 2 at near-ambient conditions.« less

Stability of numerous novel potassium chlorides at high pressure

DOE PAGES

Zhang, Weiwei; Oganov, Artem R.; Lobanov, Sergey S.; ...

2016-05-23

K-Cl is a simple system displaying all four main types of bonding, as it contains (i) metallic potassium, (ii) elemental chlorine made of covalently bonded Cl 2 molecules held together by van der Waals forces, and (iii) an archetypal ionic compound KCl. The charge balance rule, assigning classical charges of “+1” to K and “–1” to Cl, predicts that no compounds other than KCl are possible. However, our quantum-mechanical variable-composition evolutionary simulations predict an extremely complex phase diagram, with new thermodynamically stable compounds K 3Cl, K 2Cl, K 3Cl 2, K 4Cl 3, K 5Cl 4, K 3Cl 5, KClmore » 3 and KCl 7. Of particular interest are 2D-metallic homologs K n+1Cl n, the presence of positively charged Cl atoms in KCl 7, and the predicted stability of KCl 3 already at nearly ambient pressures at zero Kelvin. We have synthesized cubic Pm3¯n -KCl 3 at 40–70 GPa and trigonal P3¯cl -KCl 3 at 20–40 GPa in a laser-heated diamond anvil cell (DAC) at temperature exceeding 2000 K from KCl and Cl 2. These phases were identified using in situ synchrotron X-ray diffraction and Raman spectroscopy. Lastly, upon unloading to 10 GPa, P3¯cl -KCl 3 transforms to a yet unknown structure before final decomposition to KCl and Cl 2 at near-ambient conditions.« less

Anion exchange pathways for Cl sup minus transport in rabbit renal microvillus membranes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Karniski, L.P.; Aronson, P.S.

1987-09-01

The authors evaluated the mechanisms of chloride transport in microvillus membrane vesicles isolated from the rabbit renal cortex. The presence of Cl-formate exchange was confirmed. Outward gradients of oxaloacetate, HCO{sub 3}, acetate, lactate, succinate, sulfate, and p-aminohippurate (PAH) stimulated the rate of Cl uptake minimally or not at all. However, an outward gradient of oxalate stimulated Cl uptake by 70%, and an outward Cl gradient induced uphill oxalate uptake, indicting Cl-oxalate exchange. Moreover, an outward formate gradient induced uphill oxalate uptake, indicating formate-oxalate exchange. Studies of inhibitor and substrate specificity indicated the probably operation of at least two separate anionmore » exchangers in mediating Cl transport. The Cl-formate exchanger accepted Cl and formate as substrates, had little or no affinity for oxalate, was sensitive to inhibition by furosemide, and was less sensitive to inhibition by 4,4{prime}-diisothiocyanostilbene-2,2{prime}-disulfonic acid (DIDS). The Cl (formate)-oxalate exchanger also accepted Cl and formate as substrates but had high affinity for oxalate, was highly sensitive to inhibition by DIDS, and was less sensitive to inhibition by furosemide. The Cl-formate exchanger was electroneutral, whereas the Cl (formate)-oxalate exchanger was electrogenic. They conclude that at least separate anion exchangers mediating Cl transport are present on the luminal membrane of the rabbit proximal tubule cell. These exchangers may play important roles in mediating transtubular Cl and oxalate transport in this nephron segment.« less

20 Years of ClO Measurements in the Antarctic Lower Stratosphere

NASA Technical Reports Server (NTRS)

Nedoluha, Gerald E.; Connor, Brian J.; Mooney, Thomas; Barrett, James W.; Parrish, Alan; Gomez, R. Michael; Boyd, Ian; Allen, Douglas R.; Kotkamp, Michael; Kremser, Stefanie;

Improvement of pre-treatment method for 36Cl/Cl measurement of Cl in natural groundwater by AMS

NASA Astrophysics Data System (ADS)

Nakata, Kotaro; Hasegawa, Takuma

2011-02-01

Estimation of 36Cl/Cl by accelerator mass spectrometry (AMS) is a useful method to trace hydrological processes in groundwater. For accurate estimation, separation of SO42- from Cl - in groundwater is required because 36S affects AMS measurement of 36Cl. Previous studies utilized the difference in solubility between BaSO 4 and BaCl 2 (BaSO 4 method) to chemically separate SO42- from Cl -. However, the accuracy of the BaSO 4 method largely depends on operator skill, and consequently Cl - recovery is typically incomplete (70-80%). In addition, the method is time consuming (>1 week), and cannot be applied directly to dilute solutions. In this study, a method based on ion-exchange column chromatography (column method) was developed for separation of Cl - and SO42-. Optimum conditions were determined for the diameter and height of column, type and amount of resin, type and concentration of eluent, and flow rate. The recovery of Cl - was almost 100%, which allowed complete separation from SO42-. The separation procedure was short (<6 h), and was successfully applied to dilute (1 mg/L Cl) solution. Extracted pore water and diluted seawater samples were processed by the column and BaSO 4 methods, and then analyzed by AMS to estimate 36S counts and 36Cl/Cl values. 36S counts in samples processed by the column method were stable and lower than those from the BaSO 4 method. The column method has the following advantages over the BaSO 4 method: (1) complete and stable separation of Cl - and SO42-, (2) less operator influence on results, (3) short processing time (<6 h), (4) high (almost 100%) recovery of Cl -, and (5) concentration of Cl - and separation from SO42- in the one system for dilute solutions.

Thermodynamic Modeling of Poorly Complexing Metals in Concentrated Electrolyte Solutions: An X-Ray Absorption and UV-Vis Spectroscopic Study of Ni(II) in the NiCl2-MgCl2-H2O System

PubMed Central

Zhang, Ning; Brugger, Joël; Etschmann, Barbara; Ngothai, Yung; Zeng, Dewen

2015-01-01

Knowledge of the structure and speciation of aqueous Ni(II)-chloride complexes is important for understanding Ni behavior in hydrometallurgical extraction. The effect of concentration on the first-shell structure of Ni(II) in aqueous NiCl2 and NiCl2-MgCl2 solutions was investigated by Ni K edge X-ray absorption (XAS) and UV-Vis spectroscopy at ambient conditions. Both techniques show that no large structural change (e.g., transition from octahedral to tetrahedral-like configuration) occurs. Both methods confirm that the Ni(II) aqua ion (with six coordinated water molecules at R Ni-O = 2.07(2) Å) is the dominant species over the whole NiCl2 concentration range. However, XANES, EXAFS and UV-Vis data show subtle changes at high salinity (> 2 mol∙kg-1 NiCl2), which are consistent with the formation of small amounts of the NiCl+ complex (up to 0.44(23) Cl at a Ni-Cl distance of 2.35(2) Å in 5.05 mol∙kg-1 NiCl2) in the pure NiCl2 solutions. At high Cl:Ni ratio in the NiCl2-MgCl2-H2O solutions, small amounts of [NiCl2]0 are also present. We developed a speciation-based mixed-solvent electrolyte (MSE) model to describe activity-composition relationships in NiCl2-MgCl2-H2O solutions, and at the same time predict Ni(II) speciation that is consistent with our XAS and UV-Vis data and with existing literature data up to the solubility limit, resolving a long-standing uncertainty about the role of chloride complexing in this system. PMID:25885410

121Sb and 35Cl NQR in RCN · SbCl5 Complexes

NASA Astrophysics Data System (ADS)

Semin, G. K.; Kuznetsov, S. I.; Raevsky, A. M.; Bryukhova, E. V.

1994-05-01

35Cl and 121Sb NQR spectra of RCN · SbCl5 complexes with R = Et, n-Pr, i-Pr, n-Bu, n-C5H11 , Cl(CH2)2, C6H4CH2, Ph, Cl, Me, CCl3 were measured and /or refined at 77 K. Redistribution of the "transferred charge" in the SbCl5 fragment of the complexes under study was investigated. The existence of a specific region of dispersion of the electron-nuclear motions (DENM) in RCN · SbCl5 complexes was established.

75 FR 8461 - Airworthiness Directives; Bombardier, Inc. Model CL-600-1A11 (CL-600), CL-600-2A12 (CL-601), and...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-02-25

... Model CL-600-1A11 AFM (Winglets). These two TRs are approved by TCCA, and should be replaced in AD 2009... the Canadair Challenger Model CL-600-1A11 AFM (Winglets). We agreed and proposed to revise Table 2 of...) 600-1/17 August 16, 2006.. Canadair Challenger Model CL-600-1A11 AFM (Winglets). (iii) 601/14 August...

Downregulation of ClC-3 in dorsal root ganglia neurons contributes to mechanical hypersensitivity following peripheral nerve injury.

PubMed

Pang, Rui-Ping; Xie, Man-Xiu; Yang, Jie; Shen, Kai-Feng; Chen, Xi; Su, Ying-Xue; Yang, Chao; Tao, Jing; Liang, Si-Jia; Zhou, Jia-Guo; Zhu, He-Quan; Wei, Xu-Hong; Li, Yong-Yong; Qin, Zhi-Hai; Liu, Xian-Guo

2016-11-01

ClC-3 chloride channel/antiporter has been demonstrated to play an important role in synaptic transmission in central nervous system. However, its expression and function in sensory neurons is poorly understood. In present work, we found that ClC-3 is expressed at high levels in dorsal root ganglia (DRG). Co-immunofluorescent data showed that ClC-3 is mainly distributed in A- and C-type nociceptive neurons. ClC-3 expression in DRG is decreased in the spared nerve injury (SNI) model of neuropathic pain. Knockdown of local ClC-3 in DRG neurons with siRNA increased mechanical sensitivity in naïve rats, while overexpression of ClC-3 reversed the hypersensitivity to mechanical stimuli after peripheral nerve injury. In addition, genetic deletion of ClC-3 enhances mouse mechanical sensitivity but did not affect thermal and cold threshold. Restoration of ClC-3 expression in ClC-3 deficient mice reversed the mechanical sensitivity. Mechanistically, loss of ClC-3 enhanced mechanical sensitivity through increasing the excitability of DRG neurons. These data indicate that ClC-3 is an endogenous inhibitor of neuropathic pain development. Downregulation of ClC-3 by peripheral nerve injury is critical for mechanical hypersensitivity. Our findings suggest that ClC-3 is a novel therapeutic target for treating neuropathic pain. Copyright © 2016 Elsevier Ltd. All rights reserved.

The Electrochemical Co-reduction of Mg-Al-Y Alloys in the LiCl-NaCl-MgCl2-AlF3-YCl3 Melts

NASA Astrophysics Data System (ADS)

Li, Mei; Liu, Yaochen; Han, Wei; Wang, Shanshan; Zhang, Milin; Yan, Yongde; Shi, Weiqun

2015-04-01

The electrochemical formation of Mg-Al-Y alloys was studied in the LiCl-NaCl-MgCl2 melts by the addition of AlF3 and YCl3 on a molybdenum electrode at 973 K (700 °C). In order to reduce the volatilization of salt solvent in the electrolysis process, the volatile loss of LiCl-NaCl-MgCl2 and LiCl-KCl-MgCl2 melts was first measured in the temperature range from 873 K to 1023 K (600 °C to 750 °C). Then, the electrochemical behaviors of Mg(II), Al(III), Y(III) ions and alloy formation processes were investigated by cyclic voltammetry, chronopotentiometry, and open circuit chronopotentiometry. The cyclic voltammograms indicate that the under-potential deposition of magnesium and yttrium on pre-deposited Al leads to formation of Mg-Al and Al-Y intermetallic compounds. The Mg-Al-Y alloys were prepared by galvanostatic electrolysis in the LiCl-NaCl-MgCl2-AlF3-YCl3 melts and characterized by X-ray diffraction and scanning electron microscopy with energy dispersive spectrometry. Composition of the alloys was analyzed by inductively coupled plasma-atomic emission spectrometer, and current efficiency was also determined by the alloy composition.

Electrical conductivity of low-temperature NaCl-KCl-ZrCl4 melts

NASA Astrophysics Data System (ADS)

Salyulev, A. B.; Khokhlov, V. A.; Red'kin, A. A.

2014-08-01

The dependences of the electrical conductivity of NaCl-KCl-ZrCl4 molten mixtures with a molar ratio NaCl : KCl = 8 : 29 on the temperature (temperature range of 300-540°C) and the ZrCl4 concentration (54.3-75.2 mol %) have been measured for the first time using unique cells.

Chlorine as a primary radical: evaluation of methods to understand its role in initiation of oxidative cycles

NASA Astrophysics Data System (ADS)

Young, C. J.; Washenfelder, R. A.; Edwards, P. M.; Parrish, D. D.; Gilman, J. B.; Kuster, W. C.; Mielke, L. H.; Osthoff, H. D.; Tsai, C.; Pikelnaya, O.; Stutz, J.; Veres, P. R.; Roberts, J. M.; Griffith, S.; Dusanter, S.; Stevens, P. S.; Flynn, J.; Grossberg, N.; Lefer, B.; Holloway, J. S.; Peischl, J.; Ryerson, T. B.; Atlas, E. L.; Blake, D. R.; Brown, S. S.

2014-04-01

The role of chlorine atoms (Cl) in atmospheric oxidation has been traditionally thought to be limited to the marine boundary layer, where they are produced through heterogeneous reactions involving sea salt. However, recent observation of photolytic Cl precursors (ClNO2 and Cl2) formed from anthropogenic pollution has expanded the potential importance of Cl to include coastal and continental urban areas. Measurements of ClNO2 in Los Angeles during CalNex (California Nexus - Research at the Nexus of Air Quality and Climate Change) showed it to be an important primary (first generation) radical source. Evolution of ratios of volatile organic compounds (VOCs) has been proposed as a method to quantify Cl oxidation, but we find no evidence from this approach for a significant role of Cl oxidation in Los Angeles. We use a box model with the Master Chemical Mechanism (MCM v3.2) chemistry scheme, constrained by observations in Los Angeles, to examine the Cl sensitivity of commonly used VOC ratios as a function of NOx and secondary radical production. Model results indicate VOC tracer ratios could not detect the influence of Cl unless the ratio of [OH] to [Cl] was less than 200 for at least a day. However, the model results also show that secondary (second generation) OH production resulting from Cl oxidation of VOCs is strongly influenced by NOx, and that this effect obscures the importance of Cl as a primary oxidant. Calculated concentrations of Cl showed a maximum in mid-morning due to a photolytic source from ClNO2 and loss primarily to reactions with VOCs. The [OH] to [Cl] ratio was below 200 for approximately 3 h in the morning, but Cl oxidation was not evident from the measured ratios of VOCs. Instead, model simulations show that secondary OH production causes VOC ratio evolution to follow that expected for OH oxidation, despite the significant input of primary Cl from ClNO2 photolysis in the morning. Even though OH is by far the dominant oxidant in Los Angeles, Cl atoms do play an important role in photochemistry there, constituting 9% of the primary radical source. Furthermore, Cl-VOC reactivity differs from that of OH, being more than an order of magnitude larger and dominated by VOCs, such as alkanes, that are less reactive toward OH. Primary Cl is also slightly more effective as a radical source than primary OH due to its greater propensity to initiate radical propagation chains via VOC reactions relative to chain termination via reaction with nitrogen oxides.

UV absorption spectrum of the ClO dimer (Cl2O2) between 200 and 420 nm.

PubMed

Papanastasiou, Dimitrios K; Papadimitriou, Vassileios C; Fahey, David W; Burkholder, James B

2009-12-10

The UV photolysis of Cl(2)O(2) (dichlorine peroxide) is a key step in the catalytic destruction of polar stratospheric ozone. In this study, the gas-phase UV absorption spectrum of Cl(2)O(2) was measured using diode array spectroscopy and absolute cross sections, sigma, are reported for the wavelength range 200-420 nm. Pulsed laser photolysis of Cl(2)O at 248 nm or Cl(2)/Cl(2)O mixtures at 351 nm at low temperature (200-228 K) and high pressure (approximately 700 Torr, He) was used to produce ClO radicals and subsequently Cl(2)O(2) via the termolecular ClO self-reaction. The Cl(2)O(2) spectrum was obtained from spectra recorded following the completion of the gas-phase ClO radical chemistry. The spectral analysis used observed isosbestic points at 271, 312.9, and 408.5 nm combined with reaction stoichiometry and chlorine mass balance to determine the Cl(2)O(2) spectrum. The Cl(2)O(2) UV absorption spectrum peaks at 244.5 nm with a cross section of 7.6(-0.5)(+0.8) x 10(-18) cm(2) molecule(-1) where the quoted error limits are 2sigma and include estimated systematic errors. The Cl(2)O(2) absorption cross sections obtained for wavelengths in the range 300-420 nm are in good agreement with the Cl(2)O(2) spectrum reported previously by Burkholder et al. (J. Phys. Chem. A 1990, 94, 687) and significantly higher than the values reported by Pope et al. (J. Phys. Chem. A 2007, 111, 4322). A possible explanation for the discrepancy in the Cl(2)O(2) cross section values with the Pope et al. study is discussed. Representative, atmospheric photolysis rate coefficients are calculated and a range of uncertainty estimated based on the determination of sigma(Cl(2)O(2))(lambda) in this work. Although improvements in our fundamental understanding of the photochemistry of Cl(2)O(2) are still desired, this work indicates that major revisions in current atmospheric chemical mechanisms are not required to simulate observed polar ozone depletion.

UV Absorption Spectrum of the ClO Dimer (Cl2O2) between 200 and 420 nm

NASA Astrophysics Data System (ADS)

Papanastasiou, Dimitrios K.; Papadimitriou, Vassileios C.; Fahey, David W.; Burkholder, James B.

2009-11-01

The UV photolysis of Cl2O2 (dichlorine peroxide) is a key step in the catalytic destruction of polar stratospheric ozone. In this study, the gas-phase UV absorption spectrum of Cl2O2 was measured using diode array spectroscopy and absolute cross sections, σ, are reported for the wavelength range 200-420 nm. Pulsed laser photolysis of Cl2O at 248 nm or Cl2/Cl2O mixtures at 351 nm at low temperature (200-228 K) and high pressure (˜700 Torr, He) was used to produce ClO radicals and subsequently Cl2O2 via the termolecular ClO self-reaction. The Cl2O2 spectrum was obtained from spectra recorded following the completion of the gas-phase ClO radical chemistry. The spectral analysis used observed isosbestic points at 271, 312.9, and 408.5 nm combined with reaction stoichiometry and chlorine mass balance to determine the Cl2O2 spectrum. The Cl2O2 UV absorption spectrum peaks at 244.5 nm with a cross section of 7.6-0.5+0.8 × 10-18 cm2 molecule-1 where the quoted error limits are 2σ and include estimated systematic errors. The Cl2O2 absorption cross sections obtained for wavelengths in the range 300-420 nm are in good agreement with the Cl2O2 spectrum reported previously by Burkholder et al. (J. Phys. Chem. A 1990, 94, 687) and significantly higher than the values reported by Pope et al. (J. Phys. Chem. A 2007, 111, 4322). A possible explanation for the discrepancy in the Cl2O2 cross section values with the Pope et al. study is discussed. Representative, atmospheric photolysis rate coefficients are calculated and a range of uncertainty estimated based on the determination of σCl2O2(λ) in this work. Although improvements in our fundamental understanding of the photochemistry of Cl2O2 are still desired, this work indicates that major revisions in current atmospheric chemical mechanisms are not required to simulate observed polar ozone depletion.

Stable Isotope Analysis of Chlorate

NASA Astrophysics Data System (ADS)

Brundrett, M.; Jackson, W. A.; Sturchio, N. C.; Bohlke, J. K.; Hatzinger, P.

2016-12-01

Studies have confirmed the presence of chlorate (ClO3-) throughout terrestrial and extraterrestrial systems generally in excess of perchlorate (ClO4-) [1, 2]. ClO3- occurrence, production, and post depositional transformation has significant implications to our understanding of atmospheric Cl cycling and potential biogeochemical reactions on Earth and Mars. The isotopic composition of oxyanions can be used to evaluate their production mechanisms and post-depositional alteration [3, 4]. However, no information is available on the natural isotopic composition of ClO3-. The objective of this study was to develop a method to measure the stable isotope composition (δ18O, δ17O and δ37Cl) of ClO3- and to determine the isotopic composition of ClO3- in natural desert salt accumulations that have been studied previously for NO3- and ClO4- isotopic composition. The process of ClO3- purification and analysis of δ18O, δ 17O and δ37Cl is problematic but has recently been resolved by adapting previously published methods for ClO4-. Competitive anions (e.g. NO3-, Cl-, ClO4-, and SO4-2) are removed through a series of processes including biological reduction, solid phase extraction, and anion or cation exchange. Initial results for control samples treated with the above method have a maximum variation of ± 2 ‰. These methods are being applied to representative samples to determine if various sources of natural and synthetic ClO3- have distinctive isotopic compositions, as reported previously for ClO4- [3, 4]. Establishing the range of isotopic composition of natural ClO3- also could provide information about atmospheric ClO3- production mechanisms and post-depositional processing, with implications for the atmospheric chemistry of oxychlorine compounds and the global biogeochemical cycling of Cl. [1] Jackson et al. (2015) EPSL 430, 470-476. [2] Rao et al. (2010) ES&T 44, 8429-8434. [3] Jackson et al. (2010) ES&T 44, 4869-4876. [4] Bao and Gu (2004) ES&T 38, 5073-5077.

Total plasma clearance versus urinary plasma clearance of (51)Cr-EDTA in patients with cirrhosis with and without fluid retention.

PubMed

Henriksen, Ulrik L; Hansen, Hanne B; Ring-Larsen, Helmer; Bendtsen, Flemming; Henriksen, Jens H

2015-01-01

In patients with fluid retention, the total plasma clearance of (51)Cr-EDTA (ClP) may overestimate the glomerular filtration rate (GFR). The present study was therefore undertaken in order to compare ClP with the urinary plasma clearance of (51)Cr-EDTA (ClU) in patients with cirrhosis with and without fluid retention. A total of 136 patients with cirrhosis (24 without fluid retention, 112 with ascites) received a quantitative intravenous injection of (51)Cr-EDTA followed by plasma and quantitative urinary samples for 5 hours. ClP was determined from the injected dose relative to the plasma concentration-time area, extrapolated to infinity. ClU was determined as urinary excretion relative to the plasma concentration-time area up to voiding. In patients without fluid retention, the difference between ClP and ClU (ClP - ClU = ClΔ) was mean 4.5 mL/min/1.73 m(2). In patients with ascites, ClΔ was significantly higher (17.6 mL/min/1.73 m(2), p < 0.0001). ClΔ increased with lower values of GFR (r = - 0.458, p < 0.001). Repeated measurements of ClU in a subgroup of patients with fluid retention (n = 25) gave almost identical values. Different types of corrections of one-pool clearance were almost identical with ClP, except for higher clearance values, which were somewhat underestimated by the former. In patients with fluid retention and ascites ClP and corrected one-pool clearance overestimates GFR substantially. Although ClU may underestimate GFR slightly, patients with ascites should collect urine quantitatively in order to obtain a reliable measurement of GFR.

Evidence for in situ production of chlorinated polycyclic aromatic hydrocarbons on tidal flats: environmental monitoring and laboratory scale experiment.

PubMed

Sankoda, Kenshi; Nomiyama, Kei; Yonehara, Takayuki; Kuribayashi, Tomonori; Shinohara, Ryota

2012-07-01

This study investigated environmental distributions and production mechanisms of chlorinated polycyclic aromatic hydrocarbons (Cl-PAHs) in the sediments from some tidal flats located in Asia. Cl-PAHs were found in sediments taken from Arao tidal flat, Kikuchigawa River and Shirakawa River. The range of ∑Cl-PAHs was from 25.5 to 483 pg g(-1) for Kikuchigawa River and Arao tidal flat, respectively. Concentrations of PAHs and Cl-PAHs showed no significant correlations (r=0.134). This result suggests that the origins of these compounds differ. In the identified Cl-PAH isomers, the most abundant Cl-PAH isomer was 9,10-dichloroanthracene (9,10-di-Cl-ANT) in the three sites. In general, concentrations of Cl-ANTs in the coastal environment are about 3-5 orders of magnitude lower than those of anthracene (ANT). However, concentration ratios between Cl-ANTs and ANT (Cl-ANTs/ANT) in the sediments ranged from 4.1% to 24.6%. This result indicated that Cl-PAHs were not generated under industrial processes but the high concentration ratios have resulted from the contribution of photochemical production of Cl-ANTs in the sediments because ANT is known to have high photochemical reactivity. For examining this phenomenon, ANT adsorbed onto glass beads was irradiated with UV under the mimicked field conditions of tidal flats. As a result, it was noticed that, while chlorinated derivatives were negligible in a light-controlled group, production of 2-Cl-ANT, 9-Cl-ANT and 9,10-diCl-ANT on the irradiated surface were found in this study. These results suggest that photochemical reaction of PAHs can be a potential source of the occurrence of Cl-PAHs in the coastal environment. Copyright © 2012 Elsevier Ltd. All rights reserved.

Characterization of constitutive and acid-induced outwardly rectifying chloride currents in immortalized mouse distal tubular cells.

PubMed

Valinsky, William C; Touyz, Rhian M; Shrier, Alvin

2017-08-01

Thiazides block Na + reabsorption while enhancing Ca 2+ reabsorption in the kidney. As previously demonstrated in immortalized mouse distal convoluted tubule (MDCT) cells, chlorothiazide application induced a robust plasma membrane hyperpolarization, which increased Ca 2+ uptake. This essential thiazide-induced hyperpolarization was prevented by the Cl - channel inhibitor 5-Nitro-2-(3-phenylpropylamino) benzoic acid (NPPB), implicating NPPB-sensitive Cl - channels, however the nature of these Cl - channels has been rarely described in the literature. Here we show that MDCT cells express a dominant, outwardly rectifying Cl - current at extracellular pH7.4. This constitutive Cl - current was more permeable to larger anions (Eisenman sequence I; I - >Br - ≥Cl - ) and was substantially inhibited by >100mM [Ca 2+ ] o , which distinguished it from ClC-K2/barttin. Moreover, the constitutive Cl - current was blocked by NPPB, along with other Cl - channel inhibitors (4,4'-diisothiocyanatostilbene-2,2'-disulfonate, DIDS; flufenamic acid, FFA). Subjecting the MDCT cells to an acidic extracellular solution (pH<5.5) induced a substantially larger outwardly rectifying NPPB-sensitive Cl - current. This acid-induced Cl - current was also anion permeable (I - >Br - >Cl - ), but was distinguished from the constitutive Cl - current by its rectification characteristics, ion sensitivities, and response to FFA. In addition, we have identified similar outwardly rectifying and acid-sensitive currents in immortalized cells from the inner medullary collecting duct (mIMCD-3 cells). Expression of an acid-induced Cl - current would be particularly relevant in the acidic IMCD (pH<5.5). To our knowledge, the properties of these Cl - currents are unique and provide the mechanisms to account for the Cl - efflux previously speculated to be present in MDCT cells. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.

Efficacy of chlorine dioxide against Listeria monocytogenes in brine chilling solutions.

PubMed

Valderrama, W B; Mills, E W; Cutter, C N

2009-11-01

Chilled brine solutions are used by the food industry to rapidly cool ready-to-eat meat products after cooking and before packaging. Chlorine dioxide (ClO(2)) was investigated as an antimicrobial additive to eliminate Listeria monocytogenes. Several experiments were performed using brine solutions made of sodium chloride (NaCl) and calcium chloride (CaCl(2)) inoculated with L. monocytogenes and/or treated with 3 ppm of ClO(2). First, 10 and 20% CaCl(2) and NaCl solutions (pH 7.0) were inoculated with a five-strain cocktail of L. monocytogenes to obtain approximately 7 log CFU/ml and incubated 8 h at 0 degrees C. The results demonstrated that L. monocytogenes survived in 10% CaCl(2), 10 and 20% NaCl, and pure water. L. monocytogenes levels were reduced approximately 1.2 log CFU/ml in 20% CaCl(2). Second, inoculated ( approximately 7 log CFU/ml) brine solutions (10 and 20% NaCl and 10% CaCl(2)) treated with 3 ppm of ClO(2) resulted in a approximately 4-log reduction of the pathogen within 90 s. The same was not observed in a solution of 20% CaCl(2); further investigation demonstrated that high levels of divalent cations interfere with the disinfectant. Spent brine solutions from hot dog and ham chilling were treated with ClO(2) at concentrations of 3 or 30 ppm. At these concentrations, ClO(2) did not reduce L. monocytogenes. Removal of divalent cations and organic material in brine solutions prior to disinfection with ClO(2) should be investigated to improve the efficacy of the compound against L. monocytogenes. The information from this study may be useful to processing establishments and researchers who are investigating antimicrobials in chilling brine solutions.

Validation of chlorine and oxygen isotope ratio analysis to differentiate perchlorate sources and to document perchlorate biodegradation

USGS Publications Warehouse

Paul B. Hatzinger,; Böhlke, John Karl; Sturchio, Neil C.; Gu, Baohua

2013-01-01

Increased health concerns about perchlorate (ClO4-) during the past decade and subsequent regulatory considerations have generated appreciable interest in source identification. The key objective of the isotopic techniques described in this guidance manual is to provide evidence concerning the origin of ClO4- in soils and groundwater and, more specifically, whether that ClO4- is synthetic or natural. Chlorine and oxygen isotopic analyses of ClO4- provide the primary direct approach whereby different sources of ClO4- can be distinguished from each other. These techniques measure the relative abundances of the stable isotopes of chlorine (37Cl and 35Cl) and oxygen (18O, 17O, and 16O) in ClO4- using isotope-ratio mass spectrometry (IRMS). In addition, the relative abundance of the radioactive chlorine isotope 36Cl is measured using accelerator mass spectrometry (AMS). Taken together, these measurements provide four independent quantities that can be used to distinguish natural and synthetic ClO4- sources, to discriminate different types of natural ClO4-, and to detect ClO4- biodegradation in the environment. Other isotopic, chemical, and geochemical techniques that can be applied in conjunction with isotopic analyses of ClO4- to provide supporting data in forensic studies are also described.

A fundamental study on the [(μ-Cl) 3 Mg 2 (THF) 6 ] + dimer electrolytes for rechargeable Mg batteries

DOE PAGES

Liu, Tianbiao; Cox, Jonathan T.; Hu, Dehong; ...

2015-01-05

We present a fundamental study on [(μ-Cl) 3 Mg 2 (THF) 6 ] + dimer electrolytes using various physical methods including Subambient Pressure Ionization with Nanoelectrospray Mass spectrometry (SPIN-MS), Raman spectroscopy, 25Mg{ 1H} NMR, 27Al{ 1H} NMR and electrochemical analysis. For the first time, long time sought THF solvated [MgCl] + species was experimentally characterized by SPIN mass spectrometry in the solution of the Mgdimer containing electrolyte, confirming the mono-Cl- abstraction reaction between MgCl 2 and an Al Lewis acid. Solvated MgCl 2 in the electrolyte was confirmed by Raman spectroscopy. The experimental results establish the previously proposed dimerization equilibriummore » of solvated [MgCl] + and MgCl2 with [(μ-Cl) 3Mg 2(THF)6] +. 25Mg{ 1H} NMR, 27Al{ 1H} NMR and electrochemical analysis on chloration reaction of [(μ-Cl) 3Mg 2(THF) 6]AlPh 3Cl with external Cl- led to further insights on the coordination chemistry of the dimer electrolyte. Finally, a comprehensive mechanism is proposed for the reversible electrochemical Mg deposition and stripping and Mg 2+ and Cl- ion transports of the Mg dimer electrolytes in rechargeable Mg batteries.« less

Stimulation of Cl- uptake and morphological changes in gill mitochondria-rich cells in freshwater tilapia (Oreochromis mossambicus).

PubMed

Chang, Il-Chi; Wei, Yuan-Yaw; Chou, Fong-In; Hwang, Pung-Pung

2003-01-01

The purpose of the present article is to examine the relationships between ion uptakes and morphologies of gill mitochondria-rich (MR) cells in freshwater tilapia. Tilapia were acclimated to three different artificial freshwaters (high Na [10 mM], high Cl [7.5 mM]; high Na, low Cl [0.02-0.07 mM], and low Na [0.5 mM], low Cl) for 1 wk, and then morphological measurements of gill MR cells were made and ion influxes were determined. The number and the apical size of wavy-convex MR cells positively associated with the level of Cl(-) influx. Conversely, Na(+) influx showed no positive correlation with the morphologies of MR cells. The dominant MR cell type in tilapia gills changed from deep-hole to wavy-convex within 6 h after acute transfer from a high-Cl(-) to a low-Cl(-) environment. Deep-hole MR cells became dominant 24-96 h after acute transfer from a low-Cl(-) to a high-Cl(-) environment. We conclude that wavy-convex MR cells associate with Cl(-) uptake but not Na(+) uptake, and the rapid formation of wavy-convex MR cells reflects the timely stimulation of Cl(-) uptake to recover the homeostasis of internal Cl(-) levels on acute challenge with low environmental Cl(-).

Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation.

PubMed

Hu, Xuefeng; Wang, Xiaowen; Dong, Liuliu; Chang, Fei; Luo, Yongming

2015-01-01

Ag speciation in a chloride medium was dependent upon the Cl/Ag ratio after releasing into surface water. In this study, the photoreaction of in situ formed Ag-Cl species and their effects on aniline photochlorination were systematically investigated. Our results suggested that formation of chloroaniline was strongly relevant to the Cl/Ag ratio and could be interpreted using the thermodynamically expected speciation of Ag in the presence of Cl-. AgCl was the main species responsible for the photochlorination of aniline. Both photoinduced hole and •OH drove the oxidation of Cl- to radical •Cl, which promoted the chlorination of aniline. Ag0 formation was observed from the surface plasmon resonance absorption during AgCl photoreaction. This study revealed that Ag+ released into Cl--containing water may result in the formation of chlorinated intermediates of organic compounds under solar light irradiation.

Solubility relations in the ternary system NaCl-CsCl-H2O at 1 atm. 1. Solubilities of halite from 20 to 100 °C

USGS Publications Warehouse

Chou, I.-Ming; Lee, R.D.

1983-01-01

Solubilities of halite in the ternary system NaCl-CsCl-H2O have been determined by the visual polythermal method at 1 atm from 20 to 100??C along five constant CsCl/(CsCl + H2O) weight ratio lines. These five constant weight ratios are 0.1, 0.2, 0.3, 0.4, and 0.5. The maximum uncertainties in these measurements are ??0.02 wt % NaCl and ??0.15??C. The data along each constant CsCl/(CsCl + H2O) weight ratio line were regressed to a smooth curve. The maximum deviation of the measured solubilities from the smooth curves is 0.06 wt % NaCl. Isothermal solubilities of halite were calculated from smoothed curves at 25, 50, and 75??C.

Re-evaluation of colorimetric Cl- data from natural waters with DOC

USGS Publications Warehouse

Norton, S.A.; Handlet, M.J.; Kahl, J.S.; Peters, N.E.

1996-01-01

Colorimetric Cl- data from natural solutions that contain dissolved organic carbon (DOC) may be biased high. We evaluated aquatic Cl- concentrations in ecosystem compartments at the Bear Brook Watershed, Maine, and from lakes in Maine, using ion chromatography and colorimetry. DOC imparts a positive interference on colorimetric Cl- results proportional to DOC concentrations at approximately 0.8 ??eq Cl-/L per mg DOC/L. The interference is not a function of Cl- concentration. The resulting bias in concentrations of Cl- may be 50% or more of typical environmental values for Cl- in areas remote from atmospheric deposition of marine aerosols. Such biased data in the literature appear to have led to spurious conclusions about recycling of Cl- by forests, the usefulness of Cl- as a conservative tracer in watershed studies, and calculations of elemental budgets, ion balance, charge density of DOC, and dry deposition factors.

Formation of dioxins during the combustion of newspapers in the presence of sodium chloride and poly(vinyl chloride).

PubMed

Yasuhara, A; Katami, T; Okuda, T; Ohno, N; Shibamoto, T

2001-04-01

Exhaust gases from the combustion of newspaper alone, from branches of London plane tree alone, and from newspapers mixed with sodium chloride (NaCl), polyethylene, or poly(vinyl chloride) (PVC) were collected. The samples were analyzed for dioxins by gas chromatography/mass spectrometry. Total amounts of dioxins found in the samples were 0.186 ng/g from newspapers alone, 1.42 ng/g from the branches of London plane, 102 ng/g from newspapers impregnated with sodium chloride (CI wt % = 3.1), 101 ng/g from newspapers impregnated with sodium chloride mixed with PVC (Cl wt % = 2.6), and 146 ng/g from newspapers mixed with PVC (Cl wt % = 5.1). Samples with a higher chloride content produced more dioxins, and there is a clear correlation between dioxin formation and chloride content. The amount of dioxins formed in the samples according to the number of chlorides was Cl5 > Cl4 > Cl6 > Cl7 > Cl8 in PCDD isomers and Cl4 > Cl5 > Cl6 > Cl7 > Cl8 in PCDF isomers, except in the case of newspapers alone. Benzofurans composed 78-92% of the total dioxins formed in the exhaust gases. The higher the number of the chlorides, the lower the production of benzofuran observed. NaCl vaporized at the temperature of the flame used for combustion of the samples (760-1080 degrees C). The results indicate that NaCl and PVC contribute significantly to dioxin formation from waste materials combusted in incinerators.

ω-Oxidation of α-Chlorinated Fatty Acids

PubMed Central

Brahmbhatt, Viral V.; Albert, Carolyn J.; Anbukumar, Dhanalakshmi S.; Cunningham, Bryce A.; Neumann, William L.; Ford, David A.

2010-01-01

Myeloperoxidase-derived HOCl targets tissue- and lipoprotein-associated plasmalogens to generate α-chlorinated fatty aldehydes, including 2-chlorohexadecanal. Under physiological conditions, 2-chlorohexadecanal is oxidized to 2-chlorohexadecanoic acid (2-ClHA). This study demonstrates the catabolism of 2-ClHA by ω-oxidation and subsequent β-oxidation from the ω-end. Mass spectrometric analyses revealed that 2-ClHA is ω-oxidized in the presence of liver microsomes with initial ω-hydroxylation of 2-ClHA. Subsequent oxidation steps were examined in a human hepatocellular cell line (HepG2). Three different α-chlorinated dicarboxylic acids, 2-chlorohexadecane-(1,16)-dioic acid, 2-chlorotetradecane-(1,14)-dioic acid, and 2-chloroadipic acid (2-ClAdA), were identified. Levels of 2-chlorohexadecane-(1,16)-dioic acid, 2-chlorotetradecane-(1,14)-dioic acid, and 2-ClAdA produced by HepG2 cells were dependent on the concentration of 2-ClHA and the incubation time. Synthetic stable isotope-labeled 2-ClHA was used to demonstrate a precursor-product relationship between 2-ClHA and the α-chlorinated dicarboxylic acids. We also report the identification of endogenous 2-ClAdA in human and rat urine and elevations in stable isotope-labeled urinary 2-ClAdA in rats subjected to intraperitoneal administration of stable isotope-labeled 2-ClHA. Furthermore, urinary 2-ClAdA and plasma 2-ClHA levels are increased in LPS-treated rats. Taken together, these data show that 2-ClHA is ω-oxidized to generate α-chlorinated dicarboxylic acids, which include α-chloroadipic acid that is excreted in the urine. PMID:20956542

Neutral and cationic phosphoramide adducts of silicon tetrachloride: synthesis and characterization of their solution and solid-state structures.

PubMed

Denmark, Scott E; Eklov, Brian M

2008-01-01

The solution and solid-state structures of hexamethylphosphoramide (HMPA) adducts of tetrachlorosilane (SiCl4) are discussed. In solution, the meridional and facial isomers of the hexa-coordinate cationic complex 3 HMPASiCl3 + Cl(-) (2) predominate at all HMPA concentrations, and are in equilibrium with the hexa-coordinate neutral trans- and cis-2 HMPASiCl4 complexes (1), as well as the penta-coordinate cationic cis-2 HMPASiCl3 + Cl(-) (3). Single crystal X-ray analyses are reported for the ionized mer-3 HMPASiCl3 + HCl2 (-) and the neutral trans-2 HMPASiCl4 complexes.

Disrupting MLC1 and GlialCAM and ClC-2 interactions in leukodystrophy entails glial chloride channel dysfunction

NASA Astrophysics Data System (ADS)

Hoegg-Beiler, Maja B.; Sirisi, Sònia; Orozco, Ian J.; Ferrer, Isidre; Hohensee, Svea; Auberson, Muriel; Gödde, Kathrin; Vilches, Clara; de Heredia, Miguel López; Nunes, Virginia; Estévez, Raúl; Jentsch, Thomas J.

2014-03-01

Defects in the astrocytic membrane protein MLC1, the adhesion molecule GlialCAM or the chloride channel ClC-2 underlie human leukoencephalopathies. Whereas GlialCAM binds ClC-2 and MLC1, and modifies ClC-2 currents in vitro, no functional connections between MLC1 and ClC-2 are known. Here we investigate this by generating loss-of-function Glialcam and Mlc1 mouse models manifesting myelin vacuolization. We find that ClC-2 is unnecessary for MLC1 and GlialCAM localization in brain, whereas GlialCAM is important for targeting MLC1 and ClC-2 to specialized glial domains in vivo and for modifying ClC-2’s biophysical properties specifically in oligodendrocytes (OLs), the cells chiefly affected by vacuolization. Unexpectedly, MLC1 is crucial for proper localization of GlialCAM and ClC-2, and for changing ClC-2 currents. Our data unmask an unforeseen functional relationship between MLC1 and ClC-2 in vivo, which is probably mediated by GlialCAM, and suggest that ClC-2 participates in the pathogenesis of megalencephalic leukoencephalopathy with subcortical cysts.

Compatibility of 2, 4, 6, 8, 10,12-Hexanitrohexaazaisowurtzitane with a Selection of Insensitive Explosives

NASA Astrophysics Data System (ADS)

Li, Xi; Lin, Qiu-han; Zhao, Xin-Ying; Han, Zhi-Wei; Wang, Bo-liang

2017-04-01

Thermal techniques (differential scanning calorimetry (DSC) and the vacuum stability test (VST)), according to STANAG 4147, and non-thermal techniques (Fourier transform infrared (FTIR) spectrometry and X-ray diffractometry (XRD)) were used to examine compatibility issues for 2,4,6,8,10,12-hexanitrohexaazaisowurtzitane (CL-20) with a selection of insensitive explosives, including nitroguanidine (NQ), 2,4,6-trinitrotoluene (TNT), 2,6-diamino-3,5-dinitropyridine-1-oxide (ANPyO), 2,4,6-triamino-1,3,5-trinitrobenzene (TATB), 3-nitro-1,2,4-triazol-5-one (NTO) and 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105). DSC measurements showed that ANPyO, TATB, NTO and LLM-105 were compatible with CL-20. The compatibility of CL-20/NQ, CL-20/TNT, CL-20/ANPyO, CL-20/TATB, CL-20/NTO and CL-20/LLM-105 mixtures was further explored using the VST, which revealed that all the selected insensitive explosives were compatible with CL-20. Possible chemical interactions were suspected for CL-20/TATB from the FTIR results and for CL-20/NTO from XRD analysis. In summary, ANPyO and LLM-105 demonstrated the optimal compatibility with CL-20.

Aquia Aquifer Dissolved Cl- and 36Cl/Cl: Implications for Flow Velocities

NASA Astrophysics Data System (ADS)

Purdy, Caroline Bascom; Helz, George R.; Mignerey, Alice C.; Kubik, Peter W.; Elmore, David; Sharma, Pankaj; Hemmick, Thomas

1996-05-01

The Aquia aquifer (southern Maryland) contains a remarkably smooth Cl- profile (0.46-3.23 ppm) along its flow path. This is interpreted as a record of historic changes in the deposition of Cl- in this region. Those changes have been influenced by the rise and fall of sea level, which has altered the distance of the recharge region from the coastline by ˜200 km. The 36Cl concentration along the flow path is not as smooth as the Cl- profile. Historic variations in cosmogenic production, atmospheric transport, precipitation, and evapotranspiration all might have influenced 36Cl concentrations. A general similarity between the 36Cl and Cl- profiles suggests that changes in precipitation and evapotranspiration rates, which influence both tracers similarly, are particularly important. To reconcile 14C, 36Cl, and hydrologic data, we propose a two-tier model for flow in the Aquia. Shallower portions of the aquifer (<60 m) were subjected to hydraulic gradients and flow rates approximately 5 times larger during the Pleistocene than modern, prepumping rates. At greater depths, flow rates were much slower and less variable; water in this region may be old enough to record some 36Cl decay.

Spatial and Temporal Variations in CHLORINE-36 Deposition in the Northern United States

NASA Astrophysics Data System (ADS)

Hainsworth, Laura J.

Chlorine-36, a cosmogenic radioisotope, has been developed for use as a tracer in hydrological systems. The deposition of atmospheric ^{36} Cl, although of primary importance to hydrological applications, has not been well studied. To begin to address this problem, ^{36}Cl has been measured in monthly, wet-only, precipitation samples collected from February, 1991, to January, 1993, at the Elms Environmental Education Center in St. Mary's County, Maryland. In addition, bulk deposition samples were collected over a 1 y period at seven sites across the Northern United States and analyzed for ^{36} Cl. The mean, wet-only ^{36} Cl/Cl ratio for the 2 y sampling period is 68 +/- 19 (x10^{-15} ) and the mean ^{36}Cl concentration is 1.2 +/- 0.1 (x10 ^6) atoms/L. The ^ {36}Cl wet deposition flux data reveal a distinct seasonal deposition pattern, with peaks occurring in March and April. This pattern is attributed to stratospheric/tropospheric exchange. The mean ^{36}Cl wet deposition flux is 38.2 +/- 5 atoms/m^2s. Comparison between wet-only and bulk deposition samples indicates that the difference accounts for approximately 25% of the total ^{36}Cl deposition flux at the Elms site. A new model, using ^{90} Sr to predict the ^{36} Cl deposition pattern, is developed to predict ^{36}Cl/Cl ratios across the United States. Chlorine-36/Cl ratios in bulk deposition samples collected across the northern United States agree well with the model predictions. A mean global ^{36}Cl production rate of approximately 28 to 38 atoms/m^2s is indicated by these samples. A comparison between ^{36 }Cl concentrations in the Aquia and Magothy aquifers in southern Maryland and bulk deposition samples collected at the Elms, MD, site indicated that modern precipitation can account for the ^{36}Cl content in the youngest water in these aquifers. Surface water samples from the Susquehanna River basin reveal ^{36}Cl and stable chloride concentrations an order of magnitude higher than in bulk deposition samples collected at State College, PA. The source of excess ^{36}Cl in the Susquehanna is not known. Possible explanations include 'bomb-pulse' ^{36}Cl and in-situ ^{36}Cl production in surface rocks.

Expression analysis of β-glucosidase genes that regulate abscisic acid homeostasis during watermelon (Citrullus lanatus) development and under stress conditions.

PubMed

Li, Qian; Li, Ping; Sun, Liang; Wang, Yanping; Ji, Kai; Sun, Yufei; Dai, Shengjie; Chen, Pei; Duan, Chaorui; Leng, Ping

2012-01-01

The aim of this study was to obtain new insights into the mechanisms that regulate endogenous abscisic acid (ABA) levels by β-glucosidase genes during the development of watermelons (Citrullus lanatus) and under drought stress conditions. In total, five cDNAs from watermelons were cloned by using reverse transcription-PCR (RT-PCR). They included three cDNAs (ClBG1, ClBG2 and ClBG3) homologous to those that encode β-glucosidase l that hydrolyzes the ABA glucose ester (ABA-GE) to release active ABA, ClNCED4, which encodes 9-cis-epoxycarotenoid dioxygenase (NCED), a key enzyme in ABA biosynthesis, and ClCYP707A1, encoding ABA 8'-hydroxylase. A BLAST homology search revealed that the sequences of cDNAs and the deduced amino acids of these genes showed a high degree of homology to comparable molecules of other plant species. During fruit development and ripening, the expressions of ClBG1, ClNCED4 and ClCYP707A1 were relatively low at an early stage, increased rapidly along with fruit ripening, and reached the highest levels at 27 days after full bloom (DAFB) at the harvest stage. This trend was consistent with the accumulation of ABA. The ClBG2 gene on the other hand was highly expressed at 5 DAFB, and then decreased gradually with fruit development. Unlike ClBG1 and ClBG2, the expression of ClBG3 was low at an early stage; its expression peak occurred at 15 DAFB and then declined to the lowest point. When watermelon seedlings were subjected to drought stress, expressions of ClBG1 and ClCYP707A1 were significantly down-regulated, while expressions of ClBG2 and ClNCED4 were up-regulated in the roots, stems and leaves. The expression of ClBG3 was down-regulated in root tissue, but was up-regulated in stems and leaves. In conclusion, endogenous ABA content was modulated by a dynamic balance between biosynthesis and catabolism regulated by ClNCED4, ClCYP707A1 and ClBGs during development and under drought stress condition. It seems likely that β-glucosidase genes are important for this regulation process. Copyright © 2011 Elsevier GmbH. All rights reserved.

Constraints on the photolysis and the equilibrium constant of ClO-dimer from airborne and balloon-borne measurements of chlorine compounds

NASA Astrophysics Data System (ADS)

Kleinboehl, A.; Canty, T. P.; Salawitch, R. J.; Khosravi, M.; Urban, J.; Toon, G. C.; Kuellmann, H.; Notholt, J.

2011-12-01

Significant differences exist between different laboratory measurements of the photolysis cross-sections of ClO-dimer, and the rate constant controlling the thermal equilibrium between ClO-dimer and ClO. This leads to uncertainties in the calculations of stratospheric ozone loss in the winter polar regions. One way to constrain the plausibility of these parameters is the measurement of ClO across the terminator in the activated polar vortex. Here we analyze measurements of ClO taken by the airborne submillimeter radiometer ASUR in the Arctic winter of 1999/2000. We use measured ClO at low solar zenith angles (SZA) to estimate the total active chlorine (ClOx). We estimate total available inorganic chlorine (Cly) using ASUR measurements of N2O in January 2000 and a N2O-Cly correlation established by a balloon measurement of the MarkIV interferometer in December 1999. We compare the ClOx estimates based on different photolysis rates of ClO-Dimer. Our results show that cross-sections leading to fast photolysis rates like the ones by Burkholder et al. [1990] or Papanastasiou et al. [2009] give ClOx mixing ratios that overlap with our estimated range of available Cly. Slower photolysis rates like the ones by von Hobe et al. [2009] and Pope et al. [2007] lead to ClOx values that are significantly higher than the available Cly. We use the calculated ClOx from low SZA to estimate the ClO in darkness with different equilibrium constants, and compare it with ASUR ClO measurements before sunrise (SZA > 95). We find that calculations with equilibrium constants published in the JPL evaluation of the last few years all give good agreement with observed ClO mixing ratios. The equilibrium constant estimated by von Hobe et al. [2005] yields ClO values that are higher than the ones observed.

Patterns of chasmogamy and cleistogamy, a mixed-mating strategy in an endangered perennial.

PubMed

Koontz, Stephanie M; Weekley, Carl W; Haller Crate, Sarah J; Menges, Eric S

2017-11-01

Cleistogamy (CL) in angiosperms historically has been understudied; however, its co-occurrence with chasmogamy (CH) across many plant species suggests a fitness advantage to maintaining this mixed-mating strategy. Maintenance of mixed-mating has been attributed to reproductive assurance, resource allocation or genetic trade-offs. Our goals were to explore patterns of CH and CL, quantify reproductive contributions measured by fruit production and determine how CL is maintained in the endangered perennial Polygala lewtonii. This species exhibits CH and both above-ground cleistogamy (CL-AG) and below-ground cleistogamy (CL-BG). In monthly censuses from 2008 to 2012, we documented flowering patterns by counting CH flowering stems, CL-AG fruits and CL-BG rhizomes per plant. Monitoring of buds on CH flowering stems in 2004 provided an estimate of CH fruits per plant. Plant excavations in 2005 of CL-BG rhizomes provided an estimate of CL-BG fruits per plant. Floral morphs were temporally separated with CH flowers observed from January to May and CL flowers from June to February. Overall, 17.5 % of plants flowered; most plants expressed CH first in spring months (63.4 %) and the rest initiated CL-AG in fall months. Reproductive output was dominated by CH (median 26 fruits) compared to combined CL (median 3.5 fruits). Annual reproductive effort of CL-AG was positively correlated with plant age while CH had no relation. Our research shows CH as the dominant form of reproductive effort with most individuals expressing CH and through greater reproductive contributions. CL appears limited by plant size or resources based on the positive relationship with plant age. CL dependency on resource availability is common in other species found in dry or low-quality habitats; however, CL contributions in this species are comparatively low. This raises more questions related to energy requirements of both floral morphs, how this affects the production of viable progeny and why CL persists.

Improved method for efficient imaging of intracellular Cl(-) with Cl-Sensor using conventional fluorescence setup.

PubMed

Friedel, Perrine; Bregestovski, Piotr; Medina, Igor

2013-01-01

Chloride (Cl(-)) homeostasis is known to be fundamental for central nervous system functioning. Alterations in intracellular Cl(-) concentration ([Cl(-)]i) and changes in the efficacy of Cl(-) extrusion are involved in numerous neurological disorders. Therefore, there is a strong need for studies of the dynamics of [Cl(-)]i in different cell types under physiological conditions and during pathology. Several previous works reported having successfully achieved recording of [Cl(-)]i using genetically encoded Cl-Sensor that is composed of the cyan fluorescent protein (CFP) and Cl(-)-sensitive mutant of the yellow fluorescent protein (YFPCl). However, all reported works were performed using specially designed setups with ultra-sensitive CCD cameras. Our multiple attempts to monitor Cl(-)-dependent fluorescence of Cl-Sensor using conventional epifluorescence microscopes did not yield successful results. In the present work, we have analysed the reason of our failures and found that they were caused by a strong inactivation of the YFPCl component of Cl-Sensor during excitation of the CFP with 430 nm light. Based on the obtained results, we reduced 20-fold the intensity of the 430 nm excitation and modified the recording protocol that allows now stable long-lasting ratiometric measurements of Cl-Sensor fluorescence in different cell types including cultured hippocampal neurons and their tiny dendrites and spines. Simultaneous imaging and patch clamp recording revealed that in mature neurons, the novel protocol allows detection of as little as 2 mM changes of [Cl(-)]i from the resting level of 5-10 mM. We demonstrate also a usefulness of the developed [Cl(-)]i measurement procedure for large scale screening of the activity of exogenously expressed potassium-chloride co-transporter KCC2, a major neuronal Cl(-) extruder that is implicated in numerous neurological disorders and is a target for novel therapeutical treatments.

Serial Change in Cervical Length for the Prediction of Emergency Cesarean Section in Placenta Previa

PubMed Central

Shin, Jae Eun; Shin, Jong Chul; Lee, Young; Kim, Sa Jin

2016-01-01

Purpose To evaluate whether serial change in cervical length (CL) over time can be a predictor for emergency cesarean section (CS) in patients with placenta previa. Methods This was a retrospective cohort study of patients with placenta previa between January 2010 and November 2014. All women were offered serial measurement of CL by transvaginal ultrasound at 19 to 23 weeks (CL1), 24 to 28 weeks (CL2), 29 to 31 weeks (CL3), and 32 to 34 weeks (CL4). We compared clinical characteristics, serial change in CL, and outcomes between the emergency CS group (case group) and elective CS group (control group). The predictive value of change in CL for emergency CS was evaluated. Results A total of 93 women were evaluated; 31 had emergency CS due to massive vaginal bleeding. CL tended to decrease with advancing gestational age in each group. Until 29–31 weeks, CL showed no significant differences between the two groups, but after that, CL in the emergency CS group decreased abruptly, even though CL in the elective CS group continued to gradually decrease. On multivariate analysis to determine risk factors, only admissions for bleeding (odds ratio, 34.710; 95% CI, 5.239–229.973) and change in CL (odds ratio, 3.522; 95% CI, 1.210–10.253) were significantly associated with emergency CS. Analysis of the receiver operating characteristic curve showed that change in CL could be the predictor of emergency CS (area under the curve 0.734, p < 0.001), with optimal cutoff for predicting emergency cesarean delivery of 6.0 mm. Conclusions Previous admission for vaginal bleeding and change in CL are independent predictors of emergency CS in placenta previa. Women with change in CL more than 6 mm between the second and third trimester are at high risk of emergency CS in placenta previa. Single measurements of short CL at the second or third trimester do not seem to predict emergency CS. PMID:26863133

Serial Change in Cervical Length for the Prediction of Emergency Cesarean Section in Placenta Previa.

PubMed

Shin, Jae Eun; Shin, Jong Chul; Lee, Young; Kim, Sa Jin

2016-01-01

To evaluate whether serial change in cervical length (CL) over time can be a predictor for emergency cesarean section (CS) in patients with placenta previa. This was a retrospective cohort study of patients with placenta previa between January 2010 and November 2014. All women were offered serial measurement of CL by transvaginal ultrasound at 19 to 23 weeks (CL1), 24 to 28 weeks (CL2), 29 to 31 weeks (CL3), and 32 to 34 weeks (CL4). We compared clinical characteristics, serial change in CL, and outcomes between the emergency CS group (case group) and elective CS group (control group). The predictive value of change in CL for emergency CS was evaluated. A total of 93 women were evaluated; 31 had emergency CS due to massive vaginal bleeding. CL tended to decrease with advancing gestational age in each group. Until 29-31 weeks, CL showed no significant differences between the two groups, but after that, CL in the emergency CS group decreased abruptly, even though CL in the elective CS group continued to gradually decrease. On multivariate analysis to determine risk factors, only admissions for bleeding (odds ratio, 34.710; 95% CI, 5.239-229.973) and change in CL (odds ratio, 3.522; 95% CI, 1.210-10.253) were significantly associated with emergency CS. Analysis of the receiver operating characteristic curve showed that change in CL could be the predictor of emergency CS (area under the curve 0.734, p < 0.001), with optimal cutoff for predicting emergency cesarean delivery of 6.0 mm. Previous admission for vaginal bleeding and change in CL are independent predictors of emergency CS in placenta previa. Women with change in CL more than 6 mm between the second and third trimester are at high risk of emergency CS in placenta previa. Single measurements of short CL at the second or third trimester do not seem to predict emergency CS.

Cloning, Functional Characterization and Site-Directed Mutagenesis of 4-Coumarate: Coenzyme A Ligase (4CL) Involved in Coumarin Biosynthesis in Peucedanum praeruptorum Dunn

PubMed Central

Liu, Tingting; Yao, Ruolan; Zhao, Yucheng; Xu, Sheng; Huang, Chuanlong; Luo, Jun; Kong, Lingyi

2017-01-01

Coumarins are the main bioactive compounds in Peucedanum praeruptorum Dunn, a common Chinese herbal medicine. Nevertheless, the genes involved in the biosynthesis of core structure of coumarin in P. praeruptorum have not been identified yet. 4-Coumarate: CoA ligase (4CL) catalyzes the formation of hydroxycinnamates CoA esters, and plays an essential role at the divergence point from general phenylpropanoid metabolism to major branch pathway of coumarin. Here, three novel putative 4CL genes (Pp4CL1, Pp4CL7, and Pp4CL10) were isolated from P. praeruptorum. Biochemical characterization of the recombinant proteins revealed that Pp4CL1 utilized p-coumaric and ferulic acids as its two main substrates for coumarin biosynthesis in P. praeruptorum. Furthermore, Pp4CL1 also exhibited activity toward caffeic, cinnamic, isoferulic, and o-coumaric acids and represented a bona fide 4CL. Pp4CL7 and Pp4CL10 had no catalytic activity toward hydroxycinnamic acid compounds. But they had close phylogenetic relationship to true 4CLs and were defined as 4CL-like genes. Among all putative 4CLs, Pp4CL1 was the most highly expressed gene in roots, and its expression level was significantly up-regulated in mature roots compared with seedlings. Subcellular localization studies showed that Pp4CL1 and Pp4CL10 proteins were localized in the cytosol. In addition, site-directed mutagenesis of Pp4CL1 demonstrated that amino acids of Tyr-239, Ala-243, Met-306, Ala-309, Gly-334, Lys-441, Gln-446, and Lys-526 were essential for substrate binding or catalytic activities. The characterization and site-directed mutagenesis studies of Pp4CL1 lays a solid foundation for elucidating the biosynthetic mechanisms of coumarins in P. praeruptorum and provides further insights in understanding the structure–function relationships of this important family of proteins. PMID:28144249

Oxalyl chloride, ClC(O)C(O)Cl: UV/vis spectrum and Cl atom photolysis quantum yields at 193, 248, and 351 nm

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ghosh, Buddhadeb; Papanastasiou, Dimitrios K.; Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado 80309

2012-10-28

Oxalyl chloride, (ClCO){sub 2}, has been used as a Cl atom photolytic precursor in numerous laboratory kinetic and photochemical studies. In this study, the UV/vis absorption spectrum of (ClCO){sub 2} and the Cl atom quantum yields in its photolysis at 193, 248, and 351 nm are reported. The UV/vis spectrum was measured between 200 and 450 nm at 296 K using diode array spectroscopy in conjunction with an absolute cross section obtained at 213.9 nm. Our results are in agreement with the spectrum reported by Baklanov and Krasnoperov [J. Phys. Chem. A 105, 97-103 (2001)], which was obtained at 11more » discrete wavelengths between 193.3 and 390 nm. Cl atom quantum yields, {Phi}({lambda}), were measured using pulsed laser photolysis coupled with time resolved atomic resonance fluorescence detection of Cl. The UV photolysis of (ClCO){sub 2} has been shown in previous studies to occur via an impulsive three-body dissociation mechanism, (COCl){sub 2}+ hv{yields} ClCO*+ Cl + CO (2), where the excited ClCO radical, ClCO*, either dissociates or stabilizes ClCO*{yields} Cl + CO (3a), {yields} ClCO (3b). ClCO is thermally unstable at the temperatures (253-298 K) and total pressures (13-128 Torr) used in our experiments ClCO + M {yields} Cl + CO + M (4) leading to the formation of a secondary Cl atom that was resolvable in the Cl atom temporal profiles obtained in the 248 and 351 nm photolysis of (ClCO){sub 2}. {Phi}(193 nm) was found to be 2.07 {+-} 0.37 independent of bath gas pressure (25.8-105.7 Torr, N{sub 2}), i.e., the branching ratio for channel 2a or the direct formation of 2Cl + 2CO in the photolysis of (ClCO){sub 2} is >0.95. At 248 nm, the branching ratio for channel 2a was determined to be 0.79 {+-} 0.15, while the total Cl atom yield, i.e., following the completion of reaction (4), was found to be 1.98 {+-} 0.26 independent of bath gas pressure (15-70 Torr, N{sub 2}). {Phi}(351 nm) was found to be pressure dependent between 7.8 and 122.4 Torr (He, N{sub 2}). The low-pressure limit of the total Cl atom quantum yield, {Phi}{sub 0}(351 nm), was 2.05 {+-} 0.24. As part of this work, rate coefficients for the thermal decomposition of ClCO were measured between 253 and 298 K at total pressures between 13 and 128 Torr (He and N{sub 2} bath gases). The N{sub 2} bath gas results were combined with the data reported in Nicovich et al. [J. Chem. Phys. 92, 3539-3544 (1990)] to yield k{sub 4}(T, N{sub 2}) = (4.7 {+-} 0.7) Multiplication-Sign 10{sup -10} exp [-(2987 {+-} 16)/T] cm{sup 3} molecule{sup -1} s{sup -1}, while the He bath gas data fit yielded k{sub 4}(T, He) = (2.3 {+-} 2.1) Multiplication-Sign 10{sup -10} exp [-(2886 {+-} 218)/T] cm{sup 3} molecule{sup -1} s{sup -1}. The quoted uncertainties are at the 2{sigma} level from the precision of the fit. In addition, the room temperature rate coefficient for the Cl + ClNO reaction was measured in this work to be (1.03 {+-} 0.10) Multiplication-Sign 10{sup -10} cm{sup 3} molecule{sup -1} s{sup -1}.« less

Measurements of the ClO radical vibrational band intensity and the ClO + ClO + M reaction product

NASA Technical Reports Server (NTRS)

Burkholder, James B.; Orlando, John J.; Hammer, Philip D.; Howard, Carleton J.; Goldman, Aaron

1988-01-01

There is considerable interest in the kinetics and concentrations of free radicals in the stratosphere. Chlorine monoxide is a critically important radical because of its role in catalytic cycles for ozone depletion. Depletion occurs under a wide variety of conditions including the Antarctic spring when unusual mechanisms such as the BrO sub x/ClO sub x, ClO dimer (Cl sub 2 O sub 2), and ClO sub x/HO sub x cycles are suggested to operate. Infrared spectroscopy is one of the methods used to measure ClO in the stratosphere (Menzies 1979 and 1983; Mumma et al., 1983). To aid the quantification of such infrared measurements, researchers measured the ClO ground state fundamental band intensity.

Chloride: from Nutrient to Toxicant.

PubMed

Geilfus, Christoph-Martin

2018-05-01

In salinized soils in which chloride (Cl-) is the dominant salt anion, growth of plants that tolerate only low concentrations of salt (glycophytes) is disturbed by Cl- toxicity. Chlorotic discolorations precede necrotic lesions, causing yield reductions. Little is known about the effects of Cl- toxicity on these dysfunctions. A lack of understanding exists regarding (i) the molecular and physiological mechanisms that lead to Cl--induced damage and (ii) the adaptive aspects of induced tolerance to Cl- salinity. Here, mechanistic explanations for the Cl--induced stress responses are proposed and novel ideas and strategies by which glycophytic plants avoid the excessive accumulation of Cl- are reviewed. New experiments are suggested to test the proposed hypotheses. Cl- salinity constrains global food security and thus we urgently need more research into the causes and consequences of Cl- salinity.

Four new chalcohalides, NaBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Br and CsBa{sub 2}SnS{sub 4}Cl: Syntheses, crystal structures and optical properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Chao; Feng, Kai; Tu, Heng

Four new chalcohalides, namely NaBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Br, and CsBa{sub 2}SnS{sub 4}Cl, have been synthesized by the conventional high temperature solid-state reactions. They crystallize in three different space groups: space group I4/mcm for NaBa{sub 2}SnS{sub 4}Cl and KBa{sub 2}SnS{sub 4}Cl, Pnma for KBa{sub 2}SnS{sub 4}Br, and P2{sub 1}/c for CsBa{sub 2}SnS{sub 4}Cl. In all four compounds, the X{sup −} halide anions are only connected to six alkali metal or Ba cations, and the Sn atoms are only tetrahedrally enjoined to four S atoms. However, the M–X–Ba pseudo layers and the SnS{sub 4} tetrahedra are arrangedmore » in different ways in the three structural types, which demonstrates the interesting effect of ionic radii on the crystal structures. UV–vis–NIR spectroscopy measurements indicate that NaBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Br, and CsBa{sub 2}SnS{sub 4}Cl have band gaps of 2.28, 2.30, 1.95, and 2.06 eV, respectively. - Graphical abstract: A new series of chalcohalides, NaBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Br and CsBa{sub 2}SnS{sub 4}Cl have been obtained. They present three different space groups: NaBa{sub 2}SnS{sub 4}Cl and KBa{sub 2}SnS{sub 4}Cl in space group I4/mcm, KBa{sub 2}SnS{sub 4}Br in Pnma and CsBa{sub 2}SnS{sub 4}Cl in space group P2{sub 1}/c. UV–vis–NIR spectroscopy measurements indicate that NaBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Br and CsBa{sub 2}SnS{sub 4}Cl have band gaps of 2.28, 2.30 1.95, and 2.06 eV, respectively. - Highlights: • Four new chalcohalides, NaBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Br and CsBa{sub 2}SnS{sub 4}Cl were obtained. • They adopt three different structures owing to different ionic radii and elemental electronegativity. • NaBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Cl, KBa{sub 2}SnS{sub 4}Br and CsBa{sub 2}SnS{sub 4}Cl have band gaps of 2.28, 2.30 1.95, and 2.06 eV, respectively.« less

Direct formation of (CH sub 3 ) sub 2 HSiCl from silicon and CH sub 3 Cl

DOE Office of Scientific and Technical Information (OSTI.GOV)

Magrini, K.A.; Falconer, J.L.; Koel, B.E.

1989-07-13

A Cu-catalyzed reaction procedure was found for the selective formation of dimethylchlorosilane ((CH{sub 3}){sub 2}HSiCl) from the direct reaction of CH{sub 3}Cl with solid Si. The new procedure is a two-step process. A Cu/Si sample is prepared by evaporating Cu onto clean polycrystalline Si under ultrahigh vacuum, and the Cu/Si surface is first activated by exposure to 10% HSiCl{sub 3}/CH{sub 3}Cl at 598 K. After the HSiCl{sub 3}CH{sub 3}Cl mixture is evacuated from the reactor, the activated Cu/Si surface is reacted in fresh CH{sub 3}Cl. For low surface concentrations of Cu, the partially hydrogenated silane, (CH{sub 3}){sub 2}HSiCl, is selectivelymore » produced. Trichlorosilane was also found to activate polycrystalline Si (in the absence of Cu) for production of highly chlorinated methylchlorosilanes at a much higher rate than on the Cu/Si surface but with poor selectively to (CH{sub 3}){sub 2}HSiCl. All reactions are carried out at atmospheric pressure in a reactor that is attached to an ultrahigh-vacuum chamber. This allows surface analysis of Auger electron spectroscopy, which detected SiCl{sub x} on reacted surfaces. These SiCl{sub x} sites, which appear necessary for methylchlorosilane formation, are apparently formed during activation by HSiCl{sub 3}.« less

Comparison of surface roughness and bacterial adhesion between cosmetic contact lenses and conventional contact lenses.

PubMed

Ji, Yong Woo; Cho, Young Joo; Lee, Chul Hee; Hong, Soon Ho; Chung, Dong Yong; Kim, Eung Kweon; Lee, Hyung Keun

2015-01-01

To compare physical characteristics of cosmetic contact lenses (Cos-CLs) and conventional contact lenses (Con-CLs) that might affect susceptibility to bacterial adhesion on the contact lens (CL) surface. Surface characteristics of Cos-CLs and Con-CLs made from the same material by the same manufacturer were measured by atomic force microscopy (AFM) and scanning electron microscopy. To determine the extent and rate of bacterial adhesion, Cos-CL and Con-CL were immersed in serum-free Roswell Park Memorial Institute media containing Staphylococcus aureus or Pseudomonas aeruginosa. Additionally, the rate of removal of adherent bacteria was evaluated using hand rubbing or immersion in multipurpose disinfecting solutions (MPDS). The mean surface roughness (root mean square and peak-to-valley value) measured by AFM was significantly higher for Cos-CL than for Con-CL. At each time point, significantly more S. aureus and P. aeruginosa adhered to Cos-CL than to Con-CL, which correlated with the surface roughness of CL. In Cos-CL, bacteria were mainly found on the tinted surface rather than on the noncolored or convex areas. Pseudomonas aeruginosa attached earlier than S. aureus to all types of CL. However, P. aeruginosa was more easily removed from the surface of CL than S. aureus by hand rubbing or MPDS soaking. Increased surface roughness is an important physical factor for bacterial adhesion in Cos-CL, which may explain why rates of bacterial keratitis rates are higher in Cos-CL users in CL physical characteristics.

A new family of multifunctional silicon clathrates: Optoelectronic and thermoelectric applications

NASA Astrophysics Data System (ADS)

Liu, Yinqiao; Jiang, Xue; Huang, Yingying; Zhou, Si; Zhao, Jijun

2017-02-01

To develop Si structures for multifunctional applications, here we proposed four new low-density silicon clathrates (Si-CL-A, Si-CL-B, Si-CL-C, and Si-CL-D) based on the same bonding topologies of clathrate hydrates. The electronic and thermal properties have been revealed by first-principles calculations. By computing their equation of states, phonon dispersion, and elastic constants, the thermodynamic, dynamic, and mechanical stabilities of Si-CL-A, Si-CL-B, Si-CL-C, and Si-CL-D allotropes are confirmed. In the low-density region of the phase diagram, Si-CL-B, Si-CL-D, and Si-CL-C would overtake diamond silicon and type II clathrate (Si-CL-II) and emerge as the most stable Si allotropes successively. Among them, the two direct semiconductors with bandgaps of 1.147 eV (Si-CL-A) and 1.086 eV (Si-CL-D) are found. The suitable bandgaps close to the optimal Shockley-Queisser limit result in better absorption efficiency in solar spectrum than conventional diamond silicon. Owing to the unique cage-based framework, the thermal conductivity of these Si allotropes at room temperature are very low (2.7-5.7 Wm-1 K-1), which are lower than that of diamond structured Si by two orders of magnitude. The suitable bandgaps, small effective masses, and low thermal conductivity of our new silicon allotropes are anticipated to find applications in photovoltaic and thermoelectric devices.

Open Component Portability Infrastructure (OPENCPI)

DTIC Science & Technology

2013-03-01

8 Figure 2. C Function vs . OpenCL Kernel...10 Figure 3. OpenCL vs . OpenCPI Layering...difference between a simple C function and the analogous OpenCL kernel. Figure 2. C Function vs . OpenCL Kernel These existing example OpenCL

Perchlorate in pleistocene and holocene groundwater in North-Central New Mexico

USGS Publications Warehouse

Plummer, Niel; Böhlke, J.K.; Doughten, M.W.

2006-01-01

Groundwater from remote parts of the Middle Rio Grande Basin in north-central New Mexico has perchlorate (ClO4-) concentrations of 0.12-1.8 ??g/L Because the water samples are mostly preanthropogenic in age (0-28 000 years) and there are no industrial sources in the study area, a natural source of the ClO4- is likely. Most of the samples have Br-, Cl-, and SO42- concentrations that are similar to those of modern bulk atmospheric deposition with evapotranspiration (ET) factors of about 7-40. Most of the ET values for Pleistocene recharge were nearly twice that for Holocene recharge. The NO3-/Cl- and ClO4-/Cl- ratios are more variable than those of Br -/Cl- or SO42-/Cl-. Samples thought to have recharged under the most arid conditions in the Holocene have relatively high NO3-/Cl- ratios and low ??15N values (+1 per mil (???)) similar to those of modern bulk atmospheric N deposition. The ??18O values of the NO 3- (-4 to 0 ???) indicate that atmospheric N0 3- was not transmitted directly to the groundwater but may have been cycled in the soils before infiltrating. Samples with nearly atmospheric NO3-/Cl- ratios have relatively high ClO4- concentrations (1.0-1.8 ??g/L) with a nearly constant ClO4-/Cl- mole ratio of (1.4 ?? 0.1) ?? 10-4, which would be consistent with an average ClO 4- concentration of 0.093 ?? 0.005 ??g/L in bulk atmospheric deposition during the late Holocene in north-central NM. Samples thought to have recharged underwetter conditions have higher ??15N values (+3 to +8 ???), lower N03-/Cl- ratios, and lower ClO4-/Cl- ratios than the ones most likely to preserve an atmospheric signal. Processes in the soils that may have depleted atmospherically derived NO3- also may have depleted ClO4- to varying degrees prior to recharge. If these interpretations are correct, then ClO4- concentrations of atmospheric origin as high as 4 ??g/L are possible in preanthropogenic groundwater in parts of the Southwest where ET approaches a factor of 40. Higher ClO4- concentrations in uncontaminated groundwater could occur in recharge beneath arid areas where ET is greater than 40, where long-term accumulations of atmospheric salts are leached suddenly from dry soils, or where other (nonatmospheric) natural sources of ClO/4- exist.

Mosquitocidal properties of IgG targeting the glutamate-gated chloride channel in three mosquito disease vectors (Diptera: Culicidae).

PubMed

Meyers, Jacob I; Gray, Meg; Foy, Brian D

2015-05-15

The glutamate-gated chloride channel (GluCl) is a highly sensitive insecticide target of the avermectin class of insecticides. As an alternative to using chemical insecticides to kill mosquitoes, we tested the effects of purified immunoglobulin G (IgG) targeting the extracellular domain of GluCl from Anopheles gambiae (AgGluCl) on the survivorship of three key mosquito disease vectors: Anopheles gambiae s.s., Aedes aegypti and Culex tarsalis. When administered through a single blood meal, anti-AgGluCl IgG reduced the survivorship of A. gambiae in a dose-dependent manner (LC50: 2.82 mg ml(-1), range 2.68-2.96 mg ml(-1)) but not A. aegypti or C. tarsalis. We previously demonstrated that AgGluCl is only located in tissues of the head and thorax of A. gambiae. To verify that AgGluCl IgG is affecting target antigens found outside the midgut, we injected it directly into the hemocoel via intrathoracic injection. A single, physiologically relevant concentration of anti-AgGluCl IgG injected into the hemocoel equally reduced mosquito survivorship of all three species. To test whether anti-AgGluCl IgG was entering the hemocoel of each of these mosquitoes, we fed mosquitoes a blood meal containing anti-AgGluCl IgG and subsequently extracted their hemolymph. We only detected IgG in the hemolymph of A. gambiae, suggesting that resistance of A. aegypti and C. tarsalis to anti-AgGluCl IgG found in blood meals is due to deficient IgG translocation across the midgut. We predicted that anti-AgGluCl IgG's mode of action is by antagonizing GluCl activity. To test this hypothesis, we fed A. gambiae blood meals containing anti-AgGluCl IgG and the GluCl agonist ivermectin (IVM). Anti-AgGluCl IgG attenuated the mosquitocidal effects of IVM, suggesting that anti-AgGluCl IgG antagonizes IVM-induced activation of GluCl. Lastly, we stained adult, female A. aegypti and C. tarsalis for GluCl expression. Neuronal GluCl expression in these mosquitoes was similar to previously reported A. gambiae GluCl expression; however, we also discovered GluCl staining on the basolateral surface of their midgut epithelial cells, suggesting important physiological differences in Culicine and Anopheline mosquitoes. © 2015. Published by The Company of Biologists Ltd.

Mosquitocidal properties of IgG targeting the glutamate-gated chloride channel in three mosquito disease vectors (Diptera: Culicidae)

PubMed Central

Meyers, Jacob I.; Gray, Meg; Foy, Brian D.

2015-01-01

ABSTRACT The glutamate-gated chloride channel (GluCl) is a highly sensitive insecticide target of the avermectin class of insecticides. As an alternative to using chemical insecticides to kill mosquitoes, we tested the effects of purified immunoglobulin G (IgG) targeting the extracellular domain of GluCl from Anopheles gambiae (AgGluCl) on the survivorship of three key mosquito disease vectors: Anopheles gambiae s.s., Aedes aegypti and Culex tarsalis. When administered through a single blood meal, anti-AgGluCl IgG reduced the survivorship of A. gambiae in a dose-dependent manner (LC50: 2.82 mg ml−1, range 2.68–2.96 mg ml−1) but not A. aegypti or C. tarsalis. We previously demonstrated that AgGluCl is only located in tissues of the head and thorax of A. gambiae. To verify that AgGluCl IgG is affecting target antigens found outside the midgut, we injected it directly into the hemocoel via intrathoracic injection. A single, physiologically relevant concentration of anti-AgGluCl IgG injected into the hemocoel equally reduced mosquito survivorship of all three species. To test whether anti-AgGluCl IgG was entering the hemocoel of each of these mosquitoes, we fed mosquitoes a blood meal containing anti-AgGluCl IgG and subsequently extracted their hemolymph. We only detected IgG in the hemolymph of A. gambiae, suggesting that resistance of A. aegypti and C. tarsalis to anti-AgGluCl IgG found in blood meals is due to deficient IgG translocation across the midgut. We predicted that anti-AgGluCl IgG's mode of action is by antagonizing GluCl activity. To test this hypothesis, we fed A. gambiae blood meals containing anti-AgGluCl IgG and the GluCl agonist ivermectin (IVM). Anti-AgGluCl IgG attenuated the mosquitocidal effects of IVM, suggesting that anti-AgGluCl IgG antagonizes IVM-induced activation of GluCl. Lastly, we stained adult, female A. aegypti and C. tarsalis for GluCl expression. Neuronal GluCl expression in these mosquitoes was similar to previously reported A. gambiae GluCl expression; however, we also discovered GluCl staining on the basolateral surface of their midgut epithelial cells, suggesting important physiological differences in Culicine and Anopheline mosquitoes. PMID:25994632

Growth in the Stratospheric Loading of Chlorinated Very Short-Lived Substances: Recent Trends and Implications for Future Ozone

NASA Astrophysics Data System (ADS)

Hossaini, R.; Chipperfield, M.; Montzka, S. A.; Leeson, A.; Dhomse, S.; Pyle, J. A.

2016-12-01

Very short-lived species (VSLS) are an important source of stratospheric halogens and contribute to ozone loss, particularly in the lower stratosphere, where ozone perturbations are most climate-relevant (Hossaini et al., 2015a,b). Chlorine VSLS, such as dichloromethane (CH2Cl2), are primarily anthropogenic and their production is not controlled by the Montreal Protocol. Long-term surface measurements of CH2Cl2, the most abundant chlorine VSLS, show its atmospheric concentration has more than doubled in the last decade. Here, we used the TOMCAT/SLIMCAT chemical transport model to quantify (i) recent trends in the emission and stratospheric input of CH2Cl2, (ii) the impact of CH2Cl2 on present day ozone & (iii) the impact of continued CH2Cl2 growth on future ozone. Constrained by time-dependent surface CH2Cl2 measurements, our model shows the contribution of CH2Cl2 to stratospheric Cl doubled between 2005 (36 ppt Cl) and 2016 (72 ppt Cl). The model reproduces well high-altitude CH2Cl2 measurements from recent NASA ATTREX missions. Increases in the stratospheric input of CH2Cl2 are attributed to increasing industrial emissions. We estimate a 1 Tg CH2Cl2/yr source is required to sustain observed present day CH2Cl2 concentrations. By comparing a simulation with CH2Cl2 considered to one without, we show that CH2Cl2 presently accounts for up to 10% of lower stratospheric Cly. Inclusion of CH2Cl2 leads to a modest reduction of the model springtime Antarctic ozone column of up to 3%. Assuming CH2Cl2 concentrations continue to increase at their present rate, our forward simulations show CH2Cl2 could account for 20-30% of lower stratospheric Cly by 2050, as the contribution from long-lived chlorocarbons declines. We find that continued CH2Cl2 growth could significantly delay the return of Antarctic ozone to pre-1980 levels by more than a decade. In conclusion, sustained future CH2Cl2 growth could significantly offset some of the future benefits of the Montreal Protocol and add uncertainty to projections of ozone recovery. - Hossaini, R., et al. Efficiency of short-lived halogens at influencing climate through depletion of stratospheric ozone, Nat. Geosci., 2015a. Hossaini, R., et al. Growth in stratospheric chlorine from short-lived chemicals not controlled by the Montreal Protocol, Geophys. Res. Lett., 2015b.

Improved sensitivity via layered-double-hydroxide-uniformity-dependent chemiluminescence.

PubMed

Li, Zenghe; Wang, Dan; Yuan, Zhiqin; Lu, Chao

2016-12-01

In the last two decades nanoparticles have been widely applied to enhance chemiluminescence (CL). The morphology of nanoparticles has an important influence on nanoparticle-amplified CL. However, studies of nanoparticle-amplified CL focus mainly on the size and shape effects, and no attempt has been made to explore the influence of uniformity in nanoparticle-amplified CL processes. In this study we have investigated nanoparticle uniformity in the luminol-H 2 O 2 CL system using layered double hydroxides (LDHs) as a model material. The results demonstrated that the uniformity of LDHs played a key role in CL amplification. A possible mechanism is that LDHs with high uniformity possess abundant catalytic active sites, which results in high CL intensity. Meanwhile, the sensitivity for H 2 O 2 detection was increased by one order of magnitude (1.0 nM). Moreover, the uniform-LDH-amplified luminol CL could be applied to selective detection of glucose in human plasma samples. Furthermore, such a uniformity-dependent CL enhancement effect could adapted to other redox CL systems-for example, the peroxynitrous acid (ONOOH) CL system.

Role of endolymphatic anion transport in forskolin-induced Cl- activity increase of scala media.

PubMed

Kitano, I; Mori, N; Matsunaga, T

1995-03-01

To determine the role of anion transport in the forskolin-induced Cl- increase of scala media (SM), effects of forskolin on the EP (endocochlear potential) and Cl- activity (ACl) in SM were examined with double-barrelled Cl(-)-selective microelectrodes. The experiments were carried out on guinea pig cochleae, using a few anion transport inhibitors: IAA-94 for a Cl- channel blocker, bumetanide (BU) for an Na+/K+/2Cl- cotransport blocker, and SITS and DIDS for Cl-/HCO3- exchange blockers. The application of forskolin (200 microM) into scala vestibuli (SV) caused a 20 mEq increase of endolymphatic ACl and a 15 mV elevation of EP, and IAA-94 with forskolin completely abolished these responses. Although each application of BU, SITS or DIDS did not completely suppress EP elevation, the concurrent application of these inhibitors completely suppressed EP with endolymphatic ACl increase. The results indicate the involvement of Cl- channels, Na+/K+/2Cl- cotransport and Cl-/HCO3- exchange in forskolin-induced increase of ACl and EP. The role of adenylate cyclase activation and Cl- transport in endolymph homeostasis was discussed.

The assessment of the energetic compound 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-Hexaazaisowurtzitane (CL-20) degradability in soil.

PubMed

Strigul, Nikolay; Braida, Washington; Christodoulatos, Christos; Balas, Wendy; Nicolich, Steven

2006-01-01

CL-20 is a relatively new energetic compound with applications in explosive and propellant formulations. Currently, information about the fate of CL-20 in ecological systems is scarce. The aim of this study is to evaluate the biodegradability of CL-20 in soil environments. Four soils were used where initial CL-20 concentrations (above water solubility) ranged from 125 to 1500 mg of CL-20 per kg dry soil (corresponding to the concentrations derived from unexploded ordnance, low order detonation, or manufacturing spills). CL-20 appears to be biodegradable in soil under anaerobic conditions, and additions of organic substrates can substantially accelerate this process. However, CL-20 is not degraded in soil under aerobic conditions kept in the dark at temperatures up to 30 degrees C without organic amendments. Additions of starch or cellulose promote the biodegradation of CL-20 under aerobic conditions. Soil microbial community mediated biodegradation and plant uptake appears to enhance CL-20 biodegradation, the latter suggesting a possible route for CL-20 to entry in the food chain.

Identification of 4CL Genes in Desert Poplars and Their Changes in Expression in Response to Salt Stress.

PubMed

Zhang, Cai-Hua; Ma, Tao; Luo, Wen-Chun; Xu, Jian-Mei; Liu, Jian-Quan; Wan, Dong-Shi

2015-09-18

4-Coumarate:CoA ligase (4CL) genes are critical for the biosynthesis of plant phenylpropanoids. Here we identified 20 4CL genes in the genomes of two desert poplars (Populus euphratica and P. pruinosa) and salt-sensitive congener (P. trichocarpa), but 12 in Salix suchowensis (Salix willow). Phylogenetic analyses clustered all Salicaceae 4CL genes into two clades, and one of them (corresponding to the 4CL-like clade from Arabidopsis) showed signals of adaptive evolution, with more genes retained in Populus than Salix and Arabidopsis. We also found that 4CL12 (in 4CL-like clade) showed positive selection along the two desert poplar lineages. Transcriptional profiling analyses indicated that the expression of 4CL2, 4CL11, and 4CL12 changed significantly in one or both desert poplars in response to salt stress compared to that of in P. trichocarpa. Our results suggest that the evolution of the 4CL genes may have contributed to the development of salt tolerance in the two desert poplars.

Application of chlorine-36 technique in determining the age of modern groundwater in the Al-Zulfi province, Saudi Arabia.

PubMed

Challan, Mohsen B

2016-06-01

The present study aims to estimate the residence time of groundwater based on bomb-produced (36)Cl. (36)Cl/Cl ratios in the water samples are determined by inductively coupled plasma mass spectrometry and liquid scintillation counting. (36)Cl/Cl ratios in the groundwater were estimated to be 1.0-2.0 × 10(-12). Estimates of residence time were obtained by comparing the measured bomb-derived (36)Cl concentrations in groundwater with the background reference. Dating based on a (36)Cl bomb pulse may be more reliable and sensitive for groundwater recharged before 1975, back as far as the mid-1950s. The above (36)Cl background concentration was deduced by determining the background-corrected Dye-3 ice core data from the frozen Arctic data, according to the estimated total (36)Cl resources. The residence time of 7.81 × 10(4) y is obtained from extrapolated groundwater flow velocity. (36)Cl concentration in groundwater does not reflect the input of bomb pulse (36)Cl, and it belongs to the era before 1950.

Structural and dynamical properties of chlorinated hydrocarbons studied with resonant inelastic x-ray scattering

NASA Astrophysics Data System (ADS)

Bohinc, R.; Žitnik, M.; Bučar, K.; Kavčič, M.; Carniato, S.; Journel, L.; Guillemin, R.; Marchenko, T.; Kawerk, E.; Simon, M.; Cao, W.

2016-04-01

We present a theoretical and experimental study of resonant inelastic x-ray scattering on a large group of chlorinated hydrocarbons: CH3Cl, CH2Cl2, CHCl3, CCl4, CH3CH2Cl, ClCH2CH2Cl, CH3CHCl2, CH3CCl3, C2H2Cl2-iso, C2H2Cl2-cis, C2H2Cl2-trans, and C6H5Cl. Differences in structural and dynamical properties of the molecules generated by diverse chemical environments are observed in the measured Cl(Kα) spectral maps as well as in the Cl(K) total fluorescence yield spectra. The energy position, relative intensity, and the width of the Franck-Condon distribution of low-lying σ∗ and π∗ resonances are extracted by a fitting procedure taking into account the experimental broadening. The theoretical values obtained with the transition potential and Δ Kohn-Sham methods are in good agreement with the experimental parameters indicating subtle differences due to variations in the molecular structure.

Structural and dynamical properties of chlorinated hydrocarbons studied with resonant inelastic x-ray scattering.

PubMed

Bohinc, R; Žitnik, M; Bučar, K; Kavčič, M; Carniato, S; Journel, L; Guillemin, R; Marchenko, T; Kawerk, E; Simon, M; Cao, W

2016-04-07

We present a theoretical and experimental study of resonant inelastic x-ray scattering on a large group of chlorinated hydrocarbons: CH3Cl, CH2Cl2, CHCl3, CCl4, CH3CH2Cl, ClCH2CH2Cl, CH3CHCl2, CH3CCl3, C2H2Cl2-iso, C2H2Cl2-cis, C2H2Cl2-trans, and C6H5Cl. Differences in structural and dynamical properties of the molecules generated by diverse chemical environments are observed in the measured Cl(K(α)) spectral maps as well as in the Cl(K) total fluorescence yield spectra. The energy position, relative intensity, and the width of the Franck-Condon distribution of low-lying σ* and π* resonances are extracted by a fitting procedure taking into account the experimental broadening. The theoretical values obtained with the transition potential and Δ Kohn-Sham methods are in good agreement with the experimental parameters indicating subtle differences due to variations in the molecular structure.

Stable isotopic composition of perchlorate and nitrate accumulated in plants: Hydroponic experiments and field data.

PubMed

Estrada, Nubia Luz; Böhlke, J K; Sturchio, Neil C; Gu, Baohua; Harvey, Greg; Burkey, Kent O; Grantz, David A; McGrath, Margaret T; Anderson, Todd A; Rao, Balaji; Sevanthi, Ritesh; Hatzinger, Paul B; Jackson, W Andrew

2017-10-01

Natural perchlorate (ClO 4 - ) in soil and groundwater exhibits a wide range in stable isotopic compositions (δ 37 Cl, δ 18 O, and Δ 17 O), indicating that ClO 4 - may be formed through more than one pathway and/or undergoes post-depositional isotopic alteration. Plants are known to accumulate ClO 4 - , but little is known about their ability to alter its isotopic composition. We examined the potential for plants to alter the isotopic composition of ClO 4 - in hydroponic and field experiments conducted with snap beans (Phaseolus vulgaris L.). In hydroponic studies, anion ratios indicated that ClO 4 - was transported from solutions into plants similarly to NO 3 - but preferentially to Cl - (4-fold). The ClO 4 - isotopic compositions of initial ClO 4 - reagents, final growth solutions, and aqueous extracts from plant tissues were essentially indistinguishable, indicating no significant isotope effects during ClO 4 - uptake or accumulation. The ClO 4 - isotopic composition of field-grown snap beans was also consistent with that of ClO 4 - in varying proportions from irrigation water and precipitation. NO 3 - uptake had little or no effect on NO 3 - isotopic compositions in hydroponic solutions. However, a large fractionation effect with an apparent ε ( 15 N/ 18 O) ratio of 1.05 was observed between NO 3 - in hydroponic solutions and leaf extracts, consistent with partial NO 3 - reduction during assimilation within plant tissue. We also explored the feasibility of evaluating sources of ClO 4 - in commercial produce, as illustrated by spinach, for which the ClO 4 - isotopic composition was similar to that of indigenous natural ClO 4 - . Our results indicate that some types of plants can accumulate and (presumably) release ClO 4 - to soil and groundwater without altering its isotopic characteristics. Concentrations and isotopic compositions of ClO 4 - and NO 3 - in plants may be useful for determining sources of fertilizers and sources of ClO 4 - in their growth environments and consequently in food supplies. Copyright © 2017 Elsevier B.V. All rights reserved.

Lithium fluxes indicate presence of Na-Cl cotransport (NCC) in human lens epithelial cells.

PubMed

Lauf, Peter K; Chimote, Ameet A; Adragna, Norma C

2008-01-01

During regulatory volume decrease (RVD) of human lens epithelial cells (hLECs) by clotrimazole (CTZ)-sensitive K fluxes, Na-K-2Cl cotransport (NKCC) remains active and K-Cl cotransport (KCC) inactive. To determine whether such an abnormal behavior was caused by RVD-induced cell shrinkage, NKCC was measured in the presence of either CTZ or in high K media to prevent RVD. NKCC transports RbCl + NaCl, and LiCl + KCl; thus ouabain-insensitive, bumetanide-sensitive (BS) or Cl-dependent (ClD) Rb and Li fluxes were determined in hyposmotic high NaCl media with CTZ, or in high KCl media alone, or with sulfamate (Sf) or nitrate as Cl replacement at varying Rb, Li or Cl mol fractions (MF). Unexpectedly, NKCC was inhibited by 80% with CTZ (IC(50) = 31 microM). In isosmotic (300 mOsM) K, Li influx was approximately 1/3 of Rb influx in Na, 50% lower in Sf, and bumetanide-insensitive (BI). In hypotonic (200 mOsM) K, only the ClD but not BS Li fluxes were detected. At Li MFs from 0.1-1, Li fluxes fitted a bell-shaped curve maxing at approximately 0.6 Li MF, with the BS fluxes equaling approximately 1/4 of the ClD-Li influx. The difference, i.e. the BI/ClD Li influx, saturated with increasing Li and Cl MFs, with K(ms) for Li of 11 with, and 7 mM without K, and of approximately 46 mM for Cl. Inhibition of this K-independent Li influx by thiazides was weak whilst furosemide (<100 microM) was ineffective. Reverse transcription polymerase chain reaction and Western blots verified presence of both NKCC1 and Na-Cl cotransport (NCC). In conclusion, in hyposmotic high K media, which prevents CTZ-sensitive K flux-mediated RVD in hLECs, NKCC1, though molecularly expressed, was functionally silent. However, a K-independent and moderately thiazide-sensitive ClD-Li flux, i.e. LiCC, likely occurring through NCC was detected operationally and molecularly. (c) 2008 S. Karger AG, Basel.

Global patterns and environmental controls of perchlorate and nitrate co-occurrence in arid and semi-arid environments

NASA Astrophysics Data System (ADS)

Jackson, W. Andrew; Böhlke, J. K.; Andraski, Brian J.; Fahlquist, Lynne; Bexfield, Laura; Eckardt, Frank D.; Gates, John B.; Davila, Alfonso F.; McKay, Christopher P.; Rao, Balaji; Sevanthi, Ritesh; Rajagopalan, Srinath; Estrada, Nubia; Sturchio, Neil; Hatzinger, Paul B.; Anderson, Todd A.; Orris, Greta; Betancourt, Julio; Stonestrom, David; Latorre, Claudio; Li, Yanhe; Harvey, Gregory J.

2015-09-01

Natural perchlorate (ClO4-) is of increasing interest due to its wide-spread occurrence on Earth and Mars, yet little information exists on the relative abundance of ClO4- compared to other major anions, its stability, or long-term variations in production that may impact the observed distributions. Our objectives were to evaluate the occurrence and fate of ClO4- in groundwater and soils/caliche in arid and semi-arid environments (southwestern United States, southern Africa, United Arab Emirates, China, Antarctica, and Chile) and the relationship of ClO4- to the more well-studied atmospherically deposited anions NO3- and Cl- as a means to understand the prevalent processes that affect the accumulation of these species over various time scales. ClO4- is globally distributed in soil and groundwater in arid and semi-arid regions on Earth at concentrations ranging from 10-1 to 106 μg/kg. Generally, the ClO4- concentration in these regions increases with aridity index, but also depends on the duration of arid conditions. In many arid and semi-arid areas, NO3- and ClO4- co-occur at molar ratios (NO3-/ClO4-) that vary between ∼104 and 105. We hypothesize that atmospheric deposition ratios are largely preserved in hyper-arid areas that support little or no biological activity (e.g. plants or bacteria), but can be altered in areas with more active biological processes including N2 fixation, N mineralization, nitrification, denitrification, and microbial ClO4- reduction, as indicated in part by NO3- isotope data. In contrast, much larger ranges of Cl-/ClO4- and Cl-/NO3- ratios indicate Cl- varies independently from both ClO4- and NO3-. The general lack of correlation between Cl- and ClO4- or NO3- implies that Cl- is not a good indicator of co-deposition and should be used with care when interpreting oxyanion cycling in arid systems. The Atacama Desert appears to be unique compared to all other terrestrial locations having a NO3-/ClO4- molar ratio ∼103. The relative enrichment in ClO4- compared to Cl- or NO3- and unique isotopic composition of Atacama ClO4- may reflect either additional in-situ production mechanism(s) or higher relative atmospheric production rates in that specific region or in the geological past. Elevated concentrations of ClO4- reported on the surface of Mars, and its enrichment with respect to Cl- and NO3-, could reveal important clues regarding the climatic, hydrologic, and potentially biologic evolution of that planet. Given the highly conserved ratio of NO3-/ClO4- in non-biologically active areas on Earth, it may be possible to use alterations of this ratio as a biomarker on Mars and for interpreting major anion cycles and processes on both Mars and Earth, particularly with respect to the less-conserved NO3- pool terrestrially.

Chloride retention and release in a boreal forest soil: effects of soil water residence time and nitrogen and chloride loads.

PubMed

Bastviken, David; Sandén, Per; Svensson, Teresia; Ståhlberg, A Carina; Magounakis, Malin; Oberg, Gunilla

2006-05-01

The common assumption that chloride (Cl-) is conservative in soils and can be used as a groundwater tracer is currently being questioned, and an increasing number of studies indicate that Cl- can be retained in soils. We performed lysimeter experiments with soil from a coniferous forest in southeast Sweden to determine whether pore water residence time and nitrogen and Cl- loads affected Cl- retention. Over the first 42 days there was a net retention of Cl- with retention rates averaging 3.1 mg CI- m(-2) d(-1) (68% of the added Cl- retained over 42 days). Thereafter, a net release of Cl- at similar rates was observed for the remaining experimental period (85 d). Longer soil water residence time and higher Cl- load gave higher initial retention and subsequent release rates than shorter residence time and lower Cl- load did. Nitrogen load did not affect Cl transformation rates. This study indicates that simultaneous retention and release of Cl- can occur in soils, and that rates may be considerable relative to the load. The retention of Cl- observed was probably due to chlorination of soil organic matter or ion exchange. The cause of the shift between net retention and net release is unclear, but we hypothesize that the presence of O2 or the presence of microbially available organic matter regulates Cl- retention and release rates.

Ab initio chemical kinetic study on Cl + ClO and related reverse processes.

PubMed

Xu, Z F; Lin, M C

2010-11-04

The reaction of ClO with Cl and its related reverse processes have been studied theoretically by ab initio quantum chemical and statistical mechanical calculations. The geometric parameters of the reactants, products, and transition states are optimized by both UMPW1PW91 and unrestricted coupled-cluster single and double excitation (UCCSD) methods with the 6-311+G(3df) basis set. The potential energy surface has been further refined (with triple excitations, T) at the UCCSD(T)/6-311+G(3df) level of theory. The results show that Cl(2) and O ((3)P) can be produced by chlorine atom abstraction via a tight transition state, while ClOCl ((1)A(1)) and ClClO ((1)A') can be formed by barrierless association processes with exothermicities of 31.8 and 16.0 kcal/mol, respectively. In principle the O ((1)D) atom can be generated with a large endothermicity of 56.9 kcal/mol; on the other hand, its barrierless reaction with Cl(2) can readily form ClClO ((1)A'), which fragments rapidly to give ClO + Cl. The rate constants of both forward and reverse processes have been predicted at 150-2000 K by the microcanonical variational transition state theory (VTST)/Rice-Ramsperger-Kassel-Marcus (RRKM) theory. The predicted rate constants are in good agreement with available experimental data within reported errors.

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, J.F.

The ratio of Cl absorbed to HCO3 secreted by the in vitro small intestine of Amphiuma was measured using TWCl and titration. The aim was to estimate the stoichiometry and thereby elucidate the underlying transport mechanisms. For every mole of HCO3 secreted 1.8 mol of Cl underwent net absorption. Indirect measures of net Cl absorption and HCO3 secretion were validated. Several known and putative Cl transport inhibitors were examined for their ability to inhibit the anion transport events. Disulfonic stilbenes (DIDS) and the diuretics piretanide and furosemide inhibited the Cl absorptive flux (J/sub m s/sup Cl/) and simultaneously the HCO3more » secretory flux (J/sup HCO3 /). The diuretics acetazolamide and bumetanide also reduced J/sup HCO3 and J/sub m s/sup Cl/, although the latter effect was not statistically significant. The ratio of inhibition, J/sub m s/sup Cl// J/sup HCO3 /, varied from 1.2 to 1.8 for the different inhibitors. The presence of Cl -HCO3 exchange at the serosal membrane was deduced from 1) the reduction of J/sub m s/sup Cl/ and J/sup HCO3 / by serosally added stilbenes, 2) the reduction of Cl absorption when serosal Cl was replaced, 3) inhibition of the secretory-to-mucosal Cl flux by serosal stilbenes, and 4) enhancement of J/sup HCO3 when serosal medium HCO3 was elevated. The observations are not consistent with one-for-one exchange of Cl for HCO3 at the mucosal membrane. The observed coupling ratio is compatible with a one-for-one exchange of Cl for HCO3 at the serosal membrane.« less

Low-energy electron stimulated desorption of neutrals from multilayers of SiCl4 on Si(111).

PubMed

Lane, Christopher D; Orlando, Thomas M

2006-04-28

The interaction of low-energy electrons with multilayers of SiCl(4) adsorbed on Si(111) leads to production and desorption of Cl((2)P(32)), Cl((2)P(12)), Si, and SiCl. Resonant structure in the yield versus incident electron energy (E(i)) between 6 and 12 eV was seen in all neutral channels and assigned to dissociative electron attachment (DEA), unimolecular decay of excited products produced via autodetachment and direct dissociation. These processes yield Cl((2)P(32)) and Cl((2)P(12)) with nonthermal kinetic energies of 425 and 608 meV, respectively. The Cl((2)P(12)) is produced solely at the vacuum surface interface, whereas the formation of Cl((2)P(32)) likely involves subsurface dissociation, off-normal trajectories, and collisions with neighbors. Structure in the Cl((2)P(32)) yield near 14 and 25 eV can originate from excitation of electrons in the 2e, 7t(2) and 6t(2), 6a(1) levels, respectively. Although the 14 eV feature was not present in the Cl((2)P(12)) yield, the broad 25 eV feature, which involves complex Auger filling of holes in the 6t(2) and 6a(1) levels of SiCl(4), is observed. Direct ionization, exciton decay, and DEA from secondary electron scattering all occur at E(i)>14 eV. Si and SiCl were detected via nonresonant ionization of SiCl(x) precursors that are produced via the same states and mechanisms that yield Cl. The Si retains the kinetic energy profile of the desorbed precursors.

Influence of salicylic acid on rubisco and rubisco activase in tobacco plant grown under sodium chloride in vitro

PubMed Central

Lee, So Young; Damodaran, Puthanveettil Narayanankutty; Roh, Kwang Soo

2014-01-01

The present study was designed to evaluate the influence of salicylic acid (SA) on the growth of salt stress (sodium chloride) induced in tobacco plants. In addition, quantification of rubisco and rubisco activase contents of the plants was also determined in treatments with the control, 10−4 mM SA, 50 mM NaCl, 100 mM NaCl, 150 mM NaCl, SA + 50 mM NaCl, SA + 100 mM NaCl and SA + 150 mM NaCl, respectively after in vitro culture for 5 weeks. The growth of the tobacco plant decreased in 50 mM and 100 mM NaCl when not treated with SA. However, the growth was accelerated by SA, and the growth retardation caused by NaCl was improved by SA. The content of rubisco was improved by SA only in plants treated with 50 mM NaCl, and the activity of rubisco was increased by SA resulting in the decreased effect of NaCl, but only in 50 mM NaCl treated plants. The content of rubisco activase decreased due to NaCl, and SA did not improve the effect caused by NaCl. The activity of rubisco activase was increased by SA resulting in decreased activity caused by NaCl, but increased effect by SA was not recovered to the level of NaCl untreated plants. The activity of rubisco and rubisco activase, which decreased due to denaturing agents, did not demonstrate significant improvement when compared to the control. PMID:25313276

Progress and developments in the turbo Grignard reagent i-PrMgCl·LiCl: a ten-year journey.

PubMed

Bao, Robert Li-Yuan; Zhao, Rong; Shi, Lei

2015-04-25

Over the past decade, the effectiveness of i-PrMgCl·LiCl has been constantly highlighted by a number of research groups. Its enhanced nucleophilicity brings prosperity to highly functionalized Grignard reagents, other useful bimetallic (alkali-metal) agents and nucleophilic alkylation products under mild reaction conditions. In this feature article, a comprehensive, systematical and in-depth overview of i-PrMgCl·LiCl is provided in a multidisciplinary idea. It involves the structural and kinetic perspectives of i-PrMgCl·LiCl as well as its unique reactivity and selectivity, with knowledge of the former helping to rationalize trends of the later.

Regulation of Cl^- Channels in Normal and Cystic Fibrosis Airway Epithelial Cells by Extracellular ATP

NASA Astrophysics Data System (ADS)

Stutts, M. J.; Chinet, T. C.; Mason, S. J.; Fullton, J. M.; Clarke, L. L.; Boucher, R. C.

1992-03-01

The rate of Cl^- secretion by human airway epithelium is determined, in part, by apical cell membrane Cl^- conductance. In cystic fibrosis airway epithelia, defective regulation of Cl^- conductance decreases the capability to secrete Cl^-. Here we report that extracytosolic ATP in the luminal bath of cultured human airway epithelia increased transepithelial Cl^- secretion and apical membrane Cl^- permeability. Single-channel studies in excised membrane patches revealed that ATP increased the open probability of outward rectifying Cl^- channels. The latter effect occurs through a receptor mechanism that requires no identified soluble second messengers and is insensitive to probes of G protein function. These results demonstrate a mode of regulation of anion channels by binding ATP at the extracellular surface. Regulation of Cl^- conductance by external ATP is preserved in cystic fibrosis airway epithelia.

Influence of Plants on Chlorine Cycling in Terrestrial Environments

NASA Astrophysics Data System (ADS)

Montelius, Malin; Thiry, Yves; Marang, Laura; Ranger, Jacques; Cornelis, Jean-Thomas; Svensson, Teresia; Bastviken, David

2016-04-01

Chlorine (Cl), one of the 20 most abundant elements on Earth, is crucial for life as a regulator of cellular ionic strength and an essential co-factor in photosynthesis. Chlorinated organic compounds (Clorg) molecules are surprisingly abundant in soils, in fact many studies during the last decades show that Clorg typically account for more than 60% of the total soil Cl pool in boreal and temperate forest soils and frequently exceed chloride (Cl-) levels. The natural and primarily biotic formation of this Clorg pool has been confirmed experimentally but the detailed content of the Clorg pool and the reasons for its high abundance remains puzzling and there is a lack of Cl budgets for different ecosystems. Recently, the radioisotope 36Cl has caused concerns because of presence in radioactive waste, a long half-life (301 000 years), potential high mobility, and limited knowledge about Cl residence times, speciation and uptake by organisms in terrestrial environments. The chlorination of organic molecules may influence the pool of available Cl- to organisms and thereby the Cl cycling dynamics. This will prolong residence times of total Cl in the soil-vegetation system, which affects exposure times in radioactive 36Cl isotope risk assessments. We tested to what extent the dominating tree species influences the overall terrestrial Cl cycling and the balance between Cl- and Clorg. Total Cl and Clorg were measured in different tree compartments and soil horizons in the Breuil experimental forest, Bourgogne, established in 1976 and located at Breuil-Chenue in Eastern France. The results from this field experiment show how the dominating tree species affected Cl cycling and accumulation over a time period of 30 years. Cl uptake by trees as well as content of both total Cl and Clorg in soil humus was much higher in experimental plots with coniferous forests compared to deciduous forests. The amounts of Clorg found in plant tissue indicate significant Clorg production inside trees in addition to substantial soil production of Clorg. A large and tree species dependent "luxury" Cl uptake, rapidly released through the leaves and returned to the soil as throughfall, was indicated for some tree species. The physiology of dominating tree species, along with tree-related soil microbial communities, thus appears more important for the local Cl levels and cycling than atmospheric Cl deposition.

Simple and scalable growth of AgCl nanorods by plasma-assisted strain relaxation on flexible polymer substrates

NASA Astrophysics Data System (ADS)

Park, Jae Yong; Lee, Illhwan; Ham, Juyoung; Gim, Seungo; Lee, Jong-Lam

2017-06-01

Implementing nanostructures on plastic film is indispensable for highly efficient flexible optoelectronic devices. However, due to the thermal and chemical fragility of plastic, nanostructuring approaches are limited to indirect transfer with low throughput. Here, we fabricate single-crystal AgCl nanorods by using a Cl2 plasma on Ag-coated polyimide. Cl radicals react with Ag to form AgCl nanorods. The AgCl is subjected to compressive strain at its interface with the Ag film because of the larger lattice constant of AgCl compared to Ag. To minimize strain energy, the AgCl nanorods grow in the [200] direction. The epitaxial relationship between AgCl (200) and Ag (111) induces a strain, which leads to a strain gradient at the periphery of AgCl nanorods. The gradient causes a strain-induced diffusion of Ag atoms to accelerate the nanorod growth. Nanorods grown for 45 s exhibit superior haze up to 100% and luminance of optical device increased by up to 33%.

Reversible five-coordinate ⇄ six-coordinate transformation in cobalt(II) complexes

NASA Astrophysics Data System (ADS)

Xiao, Linda; Bhadbhade, Mohan; Baker, Anthony T.

2018-04-01

The heterocyclic ligands 2,6-bis(pyrazol-1-yl)pyridine (L1) and 2,6-bis(benzimidazol-2-yl)pyridine (L2) and their cobalt(II) complexes were synthesized. The blue five-coordinate complex [Co(L1)Cl2] isolated initially from the reaction mixture rapidly absorbed water vapour from the atmosphere to yield the pink six-coordinate complex [Co(L1)(H2O)3]Cl2. This change is reversible upon desiccation or transferring [Co(L1)(H2O)3]Cl2 into acetonitrile. The five coordinate complex [Co(L2)Cl2], however, remains stable under similar conditions. The structures of the complexes [Co(L1)Cl2], [Co(L1)(H2O)3]Cl2 and [Co(L2)Cl2] have been determined by x-ray crystallography. The magnetic susceptibilities and the electronic spectra for [Co(L1)Cl2], [Co(L2)Cl2] and [Co(L1)(H2O)3]Cl2 are presented.

Biodegradation of the High Explosive Hexanitrohexaazaiso-wurtzitane (CL-20)

PubMed Central

Karakaya, Pelin; Christodoulatos, Christos; Koutsospyros, Agamemnon; Balas, Wendy; Nicolich, Steve; Sidhoum, Mohammed

2009-01-01

The aerobic biodegradability of the high explosive CL-20 by activated sludge and the white rot fungus Phanerochaete chrysosporium has been investigated. Although activated sludge is not effective in degrading CL-20 directly, it can mineralize the alkaline hydrolysis products. Phanerochaete chrysosporium degrades CL-20 in the presence of supplementary carbon and nitrogen sources. Biodegradation studies were conducted using various nutrient media under diverse conditions. Variables included the CL-20 concentration; levels of carbon (as glycerol) and ammonium sulfate and yeast extract as sources of nitrogen. Cultures that received CL-20 at the time of inoculation transformed CL-20 completely under all nutrient conditions studied. When CL-20 was added to pre-grown cultures, degradation was limited. The extent of mineralization was monitored by the 14CO2 time evolution; up to 51% mineralization was achieved when the fungus was incubated with [14C]-CL-20. The kinetics of CL-20 biodegradation by Phanerochaete chrysosporium follows the logistic kinetic growth model. PMID:19440524

Biodegradation of the high explosive hexanitrohexaazaiso-wurtzitane (CL-20).

PubMed

Karakaya, Pelin; Christodoulatos, Christos; Koutsospyros, Agamemnon; Balas, Wendy; Nicolich, Steve; Sidhoum, Mohammed

2009-04-01

The aerobic biodegradability of the high explosive CL-20 by activated sludge and the white rot fungus Phanerochaete chrysosporium has been investigated. Although activated sludge is not effective in degrading CL-20 directly, it can mineralize the alkaline hydrolysis products. Phanerochaete chrysosporium degrades CL-20 in the presence of supplementary carbon and nitrogen sources. Biodegradation studies were conducted using various nutrient media under diverse conditions. Variables included the CL-20 concentration; levels of carbon (as glycerol) and ammonium sulfate and yeast extract as sources of nitrogen. Cultures that received CL-20 at the time of inoculation transformed CL-20 completely under all nutrient conditions studied. When CL-20 was added to pre-grown cultures, degradation was limited. The extent of mineralization was monitored by the (14)CO(2) time evolution; up to 51% mineralization was achieved when the fungus was incubated with [(14)C]-CL-20. The kinetics of CL-20 biodegradation by Phanerochaete chrysosporium follows the logistic kinetic growth model.

AMS Measurement of 36Cl with a Q3D Magnetic Spectrometer at CIAE

NASA Astrophysics Data System (ADS)

Li, Chaoli; He, Ming; Zhang, Wei; Wu, Shaoyong; Li, Zhenyu; He, Xianwen; Liu, Jiancheng; Dong, Kejun; Jiang, Shan

2012-06-01

The ratio of 36Cl/Cl can determine the exposure age of surface rocks and monitor the secular equilibrium of 36Cl of sedimentary and igneous rock in groundwater. Due to the uncertainty effects of different chemical separation processes for removing 36S, there is a high degree of uncertainty in 36Cl accelerator mass spectrometry (AMS) measurements if the ratio of 36Cl/Cl is lower than 10-14. A 36Cl AMS higher sensitivity measurement has been set up by using a ΔE-Q3D method at the China Institute of Atomic Energy (CIAE). The performances of ΔE-Q3D method for 36Cl-AMS measurement had been systemically studied. The experimental results show that the ΔE-Q3D method has a higher isobar suppression factor. Taking advantage of direct removing 36S, the sample preparation can be simplified and the uncertainty effects of different chemical separation processes can be reduced in 36Cl AMS measurements.

Comparison of Cl2 and HCl Adsorption on Si(100)-(2x1)

DTIC Science & Technology

1992-06-01

amount of SiCl4 at ~ 500K. For HC1, the only observed etching product is SiCl2. 3 1. Introduction It is important to understand the basic chemistry of...as SiCl2 (a), SiCl3 (a) or SiCl4 (a), are not observed following either C12 or HCl adsorption at 100K. These chlorides should exhibit an asymmetric

75 FR 12152 - Airworthiness Directives; Bombardier, Inc. Model CL-600-2B19 (Regional Jet Series 100 & 440), CL...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-03-15

... DEPARTMENT OF TRANSPORTATION Federal Aviation Administration 14 CFR Part 39 [Docket No. FAA-2010.... Model CL-600-2B19 (Regional Jet Series 100 & 440), CL-600-2C10 (Regional Jet Series 700, 701 & 702), CL-600-2D15 (Regional Jet Series 705), and CL-600-2D24 (Regional Jet Series 900) Airplanes AGENCY...

Two-center three-electron bonding in ClNH 3 revealed via helium droplet infrared laser Stark spectroscopy: Entrance channel complex along the Cl + NH 3 → ClNH 2 + H reaction

DOE PAGES

Moradi, Christopher P.; Xie, Changjian; Kaufmann, Matin; ...

2016-04-22

Pyrolytic dissociation of Cl 2 is employed to dope helium droplets with single Cl atoms. Sequential addition of NH 3 to Cl-doped droplets leads to the formation of a complex residing in the entry valley to the substitution reaction Cl + NH 3 → ClNH 2 + H. Infrared Stark spectroscopy in the NH stretching region reveals symmetric and antisymmetric vibrations of a C 3v symmetric top. Frequency shifts from NH 3 and dipole moment measurements are consistent with a ClNH 3 complex containing a relatively strong two-center three-electron (2c–3e) bond. The nature of the 2c–3e bonding in ClNH 3more » is explored computationally and found to be consistent with the complexation-induced blue shifts observed experimentally. As a result, computations of interconversion pathways reveal nearly barrierless routes to the formation of this complex, consistent with the absence in experimental spectra of two other complexes, NH 3Cl and Cl–HNH 2, which are predicted in the entry valley to the hydrogen abstraction reaction Cl + NH 3 → HCl + NH 2.« less

Chloride Channelopathies of ClC-2

PubMed Central

Bi, Miao Miao; Hong, Sen; Zhou, Hong Yan; Wang, Hong Wei; Wang, Li Na; Zheng, Ya Juan

2014-01-01

Chloride channels (ClCs) have gained worldwide interest because of their molecular diversity, widespread distribution in mammalian tissues and organs, and their link to various human diseases. Nine different ClCs have been molecularly identified and functionally characterized in mammals. ClC-2 is one of nine mammalian members of the ClC family. It possesses unique biophysical characteristics, pharmacological properties, and molecular features that distinguish it from other ClC family members. ClC-2 has wide organ/tissue distribution and is ubiquitously expressed. Published studies consistently point to a high degree of conservation of ClC-2 function and regulation across various species from nematodes to humans over vast evolutionary time spans. ClC-2 has been intensively and extensively studied over the past two decades, leading to the accumulation of a plethora of information to advance our understanding of its pathophysiological functions; however, many controversies still exist. It is necessary to analyze the research findings, and integrate different views to have a better understanding of ClC-2. This review focuses on ClC-2 only, providing an analytical overview of the available literature. Nearly every aspect of ClC-2 is discussed in the review: molecular features, biophysical characteristics, pharmacological properties, cellular function, regulation of expression and function, and channelopathies. PMID:24378849

Two-center three-electron bonding in ClNH{sub 3} revealed via helium droplet infrared laser Stark spectroscopy: Entrance channel complex along the Cl + NH{sub 3} → ClNH{sub 2} + H reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moradi, Christopher P.; Douberly, Gary E., E-mail: douberly@uga.edu; Xie, Changjian

2016-04-28

Pyrolytic dissociation of Cl{sub 2} is employed to dope helium droplets with single Cl atoms. Sequential addition of NH{sub 3} to Cl-doped droplets leads to the formation of a complex residing in the entry valley to the substitution reaction Cl + NH{sub 3} → ClNH{sub 2} + H. Infrared Stark spectroscopy in the NH stretching region reveals symmetric and antisymmetric vibrations of a C{sub 3v} symmetric top. Frequency shifts from NH{sub 3} and dipole moment measurements are consistent with a ClNH{sub 3} complex containing a relatively strong two-center three-electron (2c–3e) bond. The nature of the 2c–3e bonding in ClNH{sub 3}more » is explored computationally and found to be consistent with the complexation-induced blue shifts observed experimentally. Computations of interconversion pathways reveal nearly barrierless routes to the formation of this complex, consistent with the absence in experimental spectra of two other complexes, NH{sub 3}Cl and Cl–HNH{sub 2}, which are predicted in the entry valley to the hydrogen abstraction reaction Cl + NH{sub 3} → HCl + NH{sub 2}.« less

Cardiolipin effects on membrane structure and dynamics.

PubMed

Unsay, Joseph D; Cosentino, Katia; Subburaj, Yamunadevi; García-Sáez, Ana J

2013-12-23

Cardiolipin (CL) is a lipid with unique properties solely found in membranes generating electrochemical potential. It contains four acyl chains and tends to form nonlamellar structures, which are believed to play a key role in membrane structure and function. Indeed, CL alterations have been linked to disorders such as Barth syndrome and Parkinson's disease. However, the molecular effects of CL on membrane organization remain poorly understood. Here, we investigated the structure and physical properties of CL-containing membranes using confocal microscopy, fluorescence correlation spectroscopy, and atomic force microscopy. We found that the fluidity of the lipid bilayer increased and its mechanical stability decreased with CL concentration, indicating that CL decreases the packing of the membrane. Although the presence of up to 20% CL gave rise to flat, stable bilayers, the inclusion of 5% CL promoted the formation of flowerlike domains that grew with time. Surprisingly, we often observed two membrane-piercing events in atomic force spectroscopy experiments with CL-containing membranes. Similar behavior was observed with a lipid mixture mimicking the mitochondrial outer membrane composition. This suggests that CL promotes the formation of membrane areas with apposed double bilayers or nonlamellar structures, similar to those proposed for mitochondrial contact sites. All together, we show that CL induces membrane alterations that support the role of CL in facilitating bilayer structure remodeling, deformation, and permeabilization.

Theoretical study of the S…Cl interaction between sulfides and atomic chlorine. Nature and strength of the two-center three-electron bond

NASA Astrophysics Data System (ADS)

Sutradhar, Dipankar; Zeegers-Huyskens, Thérèse; Chandra, Asit. K.

2017-05-01

The interaction between sulfides (H2S, CH3SH, CH3CH2SH, CH3SCH3 and CH3SCH2F) and atomic chlorine is investigated using DFT based LC-BLYP and CCSD(T) methods in conjugation with the aug-cc-pVTZ basis set. The intermolecular S…Cl distances in the complexes range between 2.5922 Å (H2S…Cl) and 2.5273 Å (CH3SCH3…Cl). The interaction energies ranging between -29.1 and -77.5 kJ mol-1 reveal the formation of relatively strong 2c-3e S…Cl bonds. The binding energies are linearly related to the proton affinity of the sulfides, to the charge transfer taking place from the sulfides to the Cl atom and inversely proportional to the difference between the ionization potential of the sulfides and the electron affinity of the Cl atom. The spin density analysis suggests that almost 48% of the spin is transferred from the Cl to the S atom in the strongest CH3SCH3…Cl complex. The AIM analysis shows that the S…Cl interaction possess a significant covalent character which decreases with decreasing binding strength of the complexes. All the data indicate that the S…Cl 2c-3e bonds are stronger than the O…Cl or N…Cl bonds and more covalent in nature. The variation of the CH distances and the blue shifts of the ν(CH) vibration resulting from the interaction with Cl are discussed.

Mass Spectrometry Identification of N-Chlorinated Dipeptides in Drinking Water.

PubMed

Huang, Guang; Jiang, Ping; Li, Xing-Fang

2017-04-04

We report the identification of N-chlorinated dipeptides as chlorination products in drinking water using complementary high-resolution quadrupole time-of-flight (QTOF) and quadrupole ion-trap mass spectrometry techniques. First, three model dipeptides, tyrosylglycine (Tyr-Gly), tyrosylalanine (Tyr-Ala), and phenylalanylglycine (Phe-Gly), reacted with sodium hypochlorite, and these reaction solutions were analyzed by QTOF. N-Cl-Tyr-Gly, N,N-di-Cl-Tyr-Gly, N-Cl-Phe-Gly, N,N-di-Cl-Phe-Gly, N-Cl-Tyr-Ala, and N,N-di-Cl-Tyr-Ala were identified as the major products based on accurate masses, 35 Cl/ 37 Cl isotopic patterns, and MS/MS spectra. These identified N-chlorinated dipeptides were synthesized and found to be stable in water over 10 days except N,N-di-Cl-Phe-Gly. To enable sensitive detection of N-chlorinated dipeptides in authentic water, we developed a high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) method with multiple reaction monitoring (MRM) mode. N-Cl-Tyr-Gly, N,N-di-Cl-Tyr-Gly, N-Cl-Phe-Gly, N-Cl-Tyr-Ala, and N,N-di-Cl-Tyr-Ala along with their corresponding dipeptides were detected in authentic tap water samples. The dipeptides were clearly detected in the raw water, but the N-chlorinated dipeptides were at background levels. These results suggest that the N-chlorinated dipeptides are produced by chlorination. This study has identified N-chlorinated dipeptides as new disinfection byproducts in drinking water. The strategy developed in this study can be used to identify chlorination products of other peptides in drinking water.

Assessment of Myeloperoxidase Activity by the Conversion of Hydroethidine to 2-Chloroethidium*

PubMed Central

Maghzal, Ghassan J.; Cergol, Katie M.; Shengule, Sudhir R.; Suarna, Cacang; Newington, Darren; Kettle, Anthony J.; Payne, Richard J.; Stocker, Roland

2014-01-01

Oxidants derived from myeloperoxidase (MPO) contribute to inflammatory diseases. In vivo MPO activity is commonly assessed by the accumulation of 3-chlorotyrosine (3-Cl-Tyr), although 3-Cl-Tyr is formed at low yield and is subject to metabolism. Here we show that MPO activity can be assessed using hydroethidine (HE), a probe commonly employed for the detection of superoxide. Using LC/MS/MS, 1H NMR, and two-dimensional NOESY, we identified 2-chloroethidium (2-Cl-E+) as a specific product when HE was exposed to hypochlorous acid (HOCl), chloramines, MPO/H2O2/chloride, and activated human neutrophils. The rate constant for HOCl-mediated conversion of HE to 2-Cl-E+ was estimated to be 1.5 × 105 m−1s−1. To investigate the utility of 2-Cl-E+ to assess MPO activity in vivo, HE was injected into wild-type and MPO-deficient (Mpo−/−) mice with established peritonitis or localized arterial inflammation, and tissue levels of 2-Cl-E+ and 3-Cl-Tyr were then determined by LC/MS/MS. In wild-type mice, 2-Cl-E+ and 3-Cl-Tyr were detected readily in the peritonitis model, whereas in the arterial inflammation model 2-Cl-E+ was present at comparatively lower concentrations (17 versus 0.3 pmol/mg of protein), and 3-Cl-Tyr could not be detected. Similar to the situation with 3-Cl-Tyr, tissue levels of 2-Cl-E+ were decreased substantially in Mpo−/− mice, indicative of the specificity of the assay. In the arterial inflammation model, 2-Cl-E+ was absent from non-inflamed arteries and blood, suggesting that HE oxidation occurred locally in the inflamed artery. Our data suggest that the conversion of exogenous HE to 2-Cl-E+ may be a useful selective and sensitive marker for MPO activity in addition to 3-Cl-Tyr. PMID:24436331

Ion Association in AlCl3 Aqueous Solutions from Constrained First-Principles Molecular Dynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cauet, Emilie L.; Bogatko, Stuart A.; Bylaska, Eric J.

2012-10-15

Ab initio molecular dynamics was used to investigate the ion pairing behavior between Cl- and the Al3+ ion in an aqueous AlCl3 solution containing 63 water molecules. A series of constrained simulations was carried out at 300 K for up to 16 ps each, by fixing the inter-nuclear separation (rAl-Cl) between the Al3+ ion and one of the Cl- ions. The calculated potential of mean force of the Al3+-Cl- ion pair shows a pronounced minimum at rAl-Cl = 2.3 Å corresponding to a contact ion pair (CIP). Two local minima assigned to solvent separated ion pairs (SSIP) are identified atmore » rAl-Cl= 4.4 and 6.0 Å. The positions of the free energy minima coincide with the hydration shell intervals of the Al3+ cation suggesting that the Cl- ion is inclined to reside in regions of low concentration of waters, i.e. between the 1st and 2nd shells of Al3+ and between the 2nd shell and bulk. A detailed analysis of solvent structure around the Al3+ and Cl- ions as a function of rAl-Cl is presented. The results are compared to structure data from X-ray measurements and unconstrained AIMD simulations of single ions Al3+ and Cl- and AlCl3 solutions. The dipole moment of the water molecules inside the 1st and 2nd hydration shells of Al3+ and in the bulk region and those of the Clion were calculated as a function of rAl-Cl. Major changes in the electronic structure of the system result from the removal of Cl- from the 1st hydration shell of the Al3+ cation. Finally, two unconstrained AIMD simulations of aqueous AlCl3 solutions corresponding to CIP and SSIP configurations were performed (17 ps, 300 K). Only minor structural changes are observed in these systems, confirming their stability.« less

20 years of ClO measurements in the Antarctic lower stratosphere

NASA Astrophysics Data System (ADS)

Nedoluha, Gerald E.; Connor, Brian J.; Mooney, Thomas; Barrett, James W.; Parrish, Alan; Gomez, R. Michael; Boyd, Ian; Allen, Douglas R.; Kotkamp, Michael; Kremser, Stefanie; Deshler, Terry; Newman, Paul; Santee, Michelle L.

2016-08-01

We present 20 years (1996-2015) of austral springtime measurements of chlorine monoxide (ClO) over Antarctica from the Chlorine Oxide Experiment (ChlOE1) ground-based millimeter wave spectrometer at Scott Base, Antarctica, as well 12 years (2004-2015) of ClO measurements from the Aura Microwave Limb Sounder (MLS). From August onwards we observe a strong increase in lower stratospheric ClO, with a peak column amount usually occurring in early September. From mid-September onwards we observe a strong decrease in ClO. In order to study interannual differences, we focus on a 3-week period from 28 August to 17 September for each year and compare the average column ClO anomalies. These column ClO anomalies are shown to be highly correlated with the average ozone mass deficit for September and October of each year. We also show that anomalies in column ClO are strongly anti-correlated with 30 hPa temperature anomalies, both on a daily and an interannual timescale. Making use of this anti-correlation we calculate the linear dependence of the interannual variations in column ClO on interannual variations in temperature. By making use of this relationship, we can better estimate the underlying trend in the total chlorine (Cly = HCl + ClONO2 + HOCl + 2 × Cl2 + 2 × Cl2O2 + ClO + Cl). The resultant trends in Cly, which determine the long-term trend in ClO, are estimated to be -0.5 ± 0.2, -1.4 ± 0.9, and -0.6 ± 0.4 % year-1, for zonal MLS, Scott Base MLS (both 2004-2015), and ChlOE (1996-2015) respectively. These trends are within 1σ of trends in stratospheric Cly previously found at other latitudes. The decrease in ClO is consistent with the trend expected from regulations enacted under the Montreal Protocol.

Investigation of the role of α-lipoic acid on fatty acids profile, some minerals (zinc, copper, iron) and antioxidant activity against aluminum-induced oxidative stress in the liver of male rats.

PubMed

Sahin, Zafer; Ozkaya, Ahmet; Yilmaz, Okkes; Yuce, Abdurrauf; Gunes, Mehmet

2017-07-26

We have investigated the effects of α-lipoic acid (LA), a powerful antioxidant, on the fatty acid (FA) profiles, aluminum accumulation, antioxidant activity and some minerals such as zinc, copper and iron against aluminum chloride (AlCl3)-induced oxidative stress in rat liver. Twenty-eight male Wistar rats were divided into four groups as control, LA, AlCl3 and LA+AlCl3. For 30 days, LA was intraperitoneally administrated (50 mg/kg) and AlCl3 was given via orogastric gavage (1600 ppm) every other day. AlCl3-treated animals exhibited higher hepatic malondialdehyde concentration and lower glutathione peroxidase and catalase activity, whereas these alterations were restored by the LA supplementation. Total saturated FA of the AlCl3-treated group was higher than the LA supplementation groups. Moreover, total unsaturated FA level of the LA+AlCl3 group was higher than the AlCl3-treated group. Hepatic zinc level of the AlCl3-treated group was lower than the control group, whereas it was higher in the LA and the LA+AlCl3 groups. Hepatic copper levels did not significantly change in the experimental groups. Iron level was lower in the LA and LA+AlCl3 groups compared with the AlCl3-treated group. Moreover, the liver Al concentration was found to be lower in the LA and LA+AlCl3 groups compared to the AlCl3 group. These results indicate that AlCl3 treatment can induce oxidative stress in the liver. LA supplementation has a beneficial effect on the AlCl3-induced alterations such as high lipid peroxidation, Al accumulation, FA profile ratios and mineral concentrations.

Prograde infiltration of Cl-rich fluid into the granulitic continental crust from a collision zone in East Antarctica (Perlebandet, Sør Rondane Mountains)

NASA Astrophysics Data System (ADS)

Kawakami, Tetsuo; Higashino, Fumiko; Skrzypek, Etienne; Satish-Kumar, M.; Grantham, Geoffrey; Tsuchiya, Noriyoshi; Ishikawa, Masahiro; Sakata, Shuhei; Hirata, Takafumi

2017-03-01

Utilizing microstructures of Cl-bearing biotite in pelitic and felsic metamorphic rocks, the timing of Cl-rich fluid infiltration is correlated with the pressure-temperature-time (P-T-t) path of upper amphibolite- to granulite-facies metamorphic rocks from Perlebandet, Sør Rondane Mountains (SRM), East Antarctica. Microstructural observation indicates that the stable Al2SiO5 polymorph changed from sillimanite to kyanite + andalusite + sillimanite, and P-T estimates from geothermobarometry point to a counterclockwise P-T path characteristic of the SW terrane of the SRM. In situ laser ablation inductively coupled plasma mass spectrometry for U-Pb dating of zircon inclusions in garnet yielded ca. 580 Ma, likely representing the age of garnet-forming metamorphism at Perlebandet. Inclusion-host relationships among garnet, sillimanite, and Cl-rich biotite (Cl > 0.4 wt%) reveal that formation of Cl-rich biotite took place during prograde metamorphism in the sillimanite stability field. This process probably predated partial melting consuming biotite (Cl = 0.1-0.3 wt%). This was followed by retrograde, moderately Cl-bearing biotite (Cl = 0.1-0.3 wt%) replacing garnet. Similar timings of Cl-rich biotite formation in different samples, and similar f(H2O)/f(HCl) values of coexisting fluid estimated for each stage can be best explained by prograde Cl-rich fluid infiltration. Fluid-present partial melting at the onset of prograde metamorphism probably contributed to elevate the Cl concentration (and possibly salinity) of the fluid, and consumption of the fluid resulted in the progress of dehydration melting. The retrograde fluid was released from crystallizing Cl-bearing partial melts or derived externally. The prograde Cl-rich fluid infiltration in Perlebandet presumably took place at the uppermost part of the footwall of the collision boundary. Localized distribution of Cl-rich biotite and hornblende along large-scale shear zones and detachments in the SRM supports external input of Cl-rich fluids through tectonic boundaries during continental collision.

Reaction of tin(iv) phthalocyanine dichloride with decamethylmetallocenes (M = CrII and CoII). Strong magnetic coupling of spins in (Cp*2Co+){SnIVCl2(Pc˙3-)}˙-·2C6H4Cl2.

PubMed

Konarev, Dmitri V; Troyanov, Sergey I; Shestakov, Alexander F; Yudanova, Evgeniya I; Otsuka, Akihiro; Yamochi, Hideki; Kitagawa, Hiroshi; Lyubovskaya, Rimma N

2018-01-23

The reaction of tin(iv) phthalocyanine dichloride {Sn IV Cl 2 (Pc 2- )} with decamethylmetallocenes (Cp* 2 M, M = Co, Cr) has been studied. Decamethylcobaltocene reduces Sn IV Cl 2 (Pc 2- ) to form the (Cp* 2 Co + ){Sn IV Cl 2 (Pc˙ 3- )}˙ - ·2C 6 H 4 Cl 2 (1) complex. The negative charge of {Sn IV Cl 2 (Pc˙ 3- )}˙ - is delocalized over the Pc macrocycle providing the alternation of the C-N(imine) bonds, the appearance of new bands in the NIR range and a strong blue shift of both the Soret and Q-bands in the spectrum of 1. The magnetic moment of 1 is equal to 1.68μ B at 300 K, indicating the contribution of one S = 1/2 spin of the Pc˙ 3- macrocycles. These macrocycles form closely packed double stacks in 1 with effective π-π interactions providing strong antiferromagnetic coupling of spins at a Weiss temperature of -80 K. Decamethylchromocene initially also reduces Sn IV Cl 2 (Pc 2- ) to form the [(Cp* 2 Cr + ){Sn VI Cl 2 (Pc˙ 3- )}˙ - complex but further reaction between the ions is observed. This reaction is accompanied by the substitution of one Cp* ligand of Cp* 2 Cr by chloride anions originating from {Sn IV Cl 2 (Pc˙ 3- )}˙ - to form the complex {(Cp*CrCl 2 )(Sn IV (μ-Cl)(Pc 2- ))}·C 6 H 4 Cl 2 (2) in which the (Cp*CrCl 2 ) and {Sn IV (Pc 2- )} species are bonded through the μ-bridged Cl - anion. According to the DFT calculations, this reaction proceeds via an intermediate [(Cp* 2 CrCl)(SnClPc)] complex.

Estimation of medium effects on equilibrium constants in moderate and high ionic strength solutions at elevated temperatures by using specific interaction theory (SIT): Interaction coefficients involving Cl, OH- and Ac- up to 200°C and 400 bars

PubMed Central

Xiong, Yongliang

2006-01-01

In this study, a series of interaction coefficients of the Brønsted-Guggenheim-Scatchard specific interaction theory (SIT) have been estimated up to 200°C and 400 bars. The interaction coefficients involving Cl- estimated include ε(H+, Cl-), ε(Na+, Cl-), ε(Ag+, Cl-), ε(Na+, AgCl2 -), ε(Mg2+, Cl-), ε(Ca2+, Cl-), ε(Sr2+, Cl-), ε(Ba2+, Cl-), ε(Sm3+, Cl-), ε(Eu3+, Cl-), ε(Gd3+, Cl-), and ε(GdAc2+, Cl-). The interaction coefficients involving OH- estimated include ε(Li+, OH-), ε(K+, OH-), ε(Na+, OH-), ε(Cs+, OH-), ε(Sr2+, OH-), and ε(Ba2+, OH-). In addition, the interaction coefficients of ε(Na+, Ac-) and ε(Ca2+, Ac-) have also been estimated. The bulk of interaction coefficients presented in this study has been evaluated from the mean activity coefficients. A few of them have been estimated from the potentiometric and solubility studies. The above interaction coefficients are tested against both experimental mean activity coefficients and equilibrium quotients. Predicted mean activity coefficients are in satisfactory agreement with experimental data. Predicted equilibrium quotients are in very good agreement with experimental values. Based upon its relatively rapid attainment of equilibrium and the ease of determining magnesium concentrations, this study also proposes that the solubility of brucite can be used as a pH (pcH) buffer/sensor for experimental systems in NaCl solutions up to 200°C by employing the predicted solubility quotients of brucite in conjunction with the dissociation quotients of water and the first hydrolysis quotients of Mg2+, all in NaCl solutions. PMID:16759370

Intracellular chloride ion concentration in differentiating neuronal cell and its role in growing neurite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nakajima, Ken-ichi; Marunaka, Yoshinori; Department of Bio-Ionomics, Kyoto Prefectural University of Medicine, Graduate School of Medical Science, Kyoto 602-8566

Chloride ion (Cl{sup −}) is one of the most abundant anions in our body. Increasing evidence suggests that Cl{sup −} plays fundamental roles in various cellular functions. We have previously reported that electroneutral cation-chloride cotransporters, such as Na{sup +}-K{sup +}-2Cl{sup −} cotransporter 1 (NKCC1) and K{sup +}-Cl{sup −} cotransporter 1 (KCC1), are involved in neurite outgrowth during neuronal differentiation. In the present study, we studied if there is correlation between intracellular Cl{sup −} concentrations ([Cl{sup −}]{sub i}) and the length of growing neurites. We measured [Cl{sup −}]{sub i} in the cell body and growing neurite tips using halide-sensitive fluorescent dyemore » N-(ethoxycarbonylmethyl)-6-methoxyquinolinium bromide (MQAE), revealing that [Cl{sup −}]{sub i} in the tip of growing neurite was higher than that in cell body in a single cell. Importantly, there was a significant positive correlation between the length of growing neurite and [Cl{sup −}]{sub i} in neurite tip. Bumtanide (BMT), an inhibitor of NKCC1, significantly inhibited neurite outgrowth and decreased [Cl{sup −}]{sub i} in neurite tip. The results obtained in the present study and our previous studies together strongly suggest that high [Cl{sup −}]{sub i} in neurite tip region is crucial for efficient neurite outgrowth. - Highlights: • Intracellular Cl{sup −} concentrations ([Cl{sup −}]{sub i}) in the tip of growing neurite is higher than that in cell body in a single cell. • There is a significant positive correlation between the length of growing neurite and [Cl{sup −}]{sub i} in neurite tip. • Bumetanide significantly inhibits neurite outgrowth and decreased [Cl{sup −}]{sub i} in neurite tip. • High [Cl{sup −}]{sub i} in neurite tip region is crucial for efficient neurite outgrowth.« less

Atacama perchlorate as an agricultural contaminant in groundwater: Isotopic and chronologic evidence from Long Island, New York

USGS Publications Warehouse

Böhlke, J.K.; Hatzinger, P.B.; Sturchio, N.C.; Gu, B.; Abbene, I.; Mroczkowski, S.J.

2009-01-01

Perchlorate (ClO4-) is a common groundwater constituent with both synthetic and natural sources. A potentially important source of ClO4- is past agricultural application of ClO4--bearing natural NO3- fertilizer imported from the Atacama Desert, Chile, but evidence for this hasbeenlargely circumstantial. Here we report ClO4- stable isotope data (??37Cl, ??18O, and ??17O), along with other supporting chemical and isotopic environmental tracer data, to document groundwater ClO4- contamination sources and history in parts of Long Island, New York. Sampled groundwaters were oxic and ClO4- apparently was not affected by biodegradation within the aquifers. Synthetic ClO4- was indicated by the isotopic method in groundwater near a fireworks disposal site at a former missile base. Atacama ClO4- was indicated in agricultural and urbanizing areas in groundwaters with apparent ages >20 years. In an agricultural area, ClO4- concentrations and ClO4-/NO3- ratios increased withgroundwaterage, possiblybecauseof decreasing application rates of Atacama NO3- fertilizers and/or decreasing ClO4- concentrations in Atacama NO 3- fertilizers in recent years. Because ClO 4-/NO3- ratios of Atacama NO 3- fertilizers imported in the past (???2 ?? 10-3 mol mol-1) were much higher than the ClO 4-/NO3- ratio of recommended drinking-water limits (7 ?? 10-5 mol mol-1 in New York), ClO4- could exceed drinkingwater limits even where NO3- does not, and where Atacama NO3- was only a minor source of N. Groundwater ClO4- with distinctive isotopic composition was a sensitive indicator of past Atacama NO3- fertilizer use on Long Island and may be common in other areas that received NO3- fertilizers from the late 19th century through the 20th century. ?? 2009 American Chemical Society.

Mechanical and Metabolic Responses to Traditional and Cluster Set Configurations in the Bench Press Exercise.

PubMed

García-Ramos, Amador; González-Hernández, Jorge M; Baños-Pelegrín, Ezequiel; Castaño-Zambudio, Adrián; Capelo-Ramírez, Fernando; Boullosa, Daniel; Haff, Guy G; Jiménez-Reyes, Pedro

2017-10-20

García-Ramos, A, González-Hernández, JM, Baños-Pelegrín, E, Castaño-Zambudio, A, Capelo-Ramírez, F, Boullosa, D, Haff, GG, and Jiménez-Reyes, P. Mechanical and metabolic responses to traditional and cluster set configurations in the bench press exercise. J Strength Cond Res XX(X): 000-000, 2017-This study aimed to compare mechanical and metabolic responses between traditional (TR) and cluster (CL) set configurations in the bench press exercise. In a counterbalanced randomized order, 10 men were tested with the following protocols (sets × repetitions [inter-repetition rest]): TR1: 3 × 10 (0-second), TR2: 6 × 5 (0-second), CL5: 3 × 10 (5-second), CL10: 3 × 10 (10-second), and CL15: 3 × 10 (15-second). The number of repetitions (30), interset rest (5 minutes), and resistance applied (10 repetition maximum) were the same for all set configurations. Movement velocity and blood lactate concentration were used to assess the mechanical and metabolic responses, respectively. The comparison of the first and last set of the training session revealed a significant decrease in movement velocity for TR1 (Effect size [ES]: -0.92), CL10 (ES: -0.85), and CL15 (ES: -1.08) (but not for TR2 [ES: -0.38] and CL5 [ES: -0.37]); while blood lactate concentration was significantly increased for TR1 (ES: 1.11), TR2 (ES: 0.90), and CL5 (ES: 1.12) (but not for CL10 [ES: 0.03] and CL15 [ES: -0.43]). Based on velocity loss, set configurations were ranked as follows: TR1 (-39.3 ± 7.3%) > CL5 (-20.2 ± 14.7%) > CL10 (-12.9 ± 4.9%), TR2 (-10.3 ± 5.3%), and CL15 (-10.0 ± 2.3%). The set configurations were ranked as follows based on the lactate concentration: TR1 (7.9 ± 1.1 mmol·L) > CL5 (5.8 ± 0.9 mmol·L) > TR2 (4.2 ± 0.7 mmol·L) > CL10 (3.5 ± 0.4 mmol·L) and CL15 (3.4 ± 0.7 mmol·L). These results support the use of TR2, CL10, and CL15 for the maintenance of high mechanical outputs, while CL10 and CL15 produce less metabolic stress than TR2.

High concentrations of Na+ and Cl- ions in soil solution have simultaneous detrimental effects on growth of faba bean under salinity stress.

PubMed

Tavakkoli, Ehsan; Rengasamy, Pichu; McDonald, Glenn K

2010-10-01

Despite the fact that most plants accumulate both sodium (Na(+)) and chloride (Cl(-)) ions to high concentration in their shoot tissues when grown in saline soils, most research on salt tolerance in annual plants has focused on the toxic effects of Na(+) accumulation. There have also been some recent concerns about the ability of hydroponic systems to predict the responses of plants to salinity in soil. To address these two issues, an experiment was conducted to compare the responses to Na(+) and to Cl(-) separately in comparison with the response to NaCl in a soil-based system using two varieties of faba bean (Vicia faba), that differed in salinity tolerance. The variety Nura is a salt-sensitive variety that accumulates Na(+) and Cl(-) to high concentrations while the line 1487/7 is salt tolerant which accumulates lower concentrations of Na(+) and Cl(-). Soils were prepared which were treated with Na(+) or Cl(-) by using a combination of different Na(+) salts and Cl(-) salts, respectively, or with NaCl. While this method produced Na(+)-dominant and Cl(-)-dominant soils, it unavoidably led to changes in the availability of other anions and cations, but tissue analysis of the plants did not indicate any nutritional deficiencies or toxicities other than those targeted by the salt treatments. The growth, water use, ionic composition, photosynthesis, and chlorophyll fluorescence were measured. Both high Na(+) and high Cl(-) reduced growth of faba bean but plants were more sensitive to Cl(-) than to Na(+). The reductions in growth and photosynthesis were greater under NaCl stress and the effect was mainly additive. An important difference to previous hydroponic studies was that increasing the concentrations of NaCl in the soil increased the concentration of Cl(-) more than the concentration of Na(+). The data showed that salinity caused by high concentrations of NaCl can reduce growth by the accumulation of high concentrations of both Na(+) and Cl(-) simultaneously, but the effects of the two ions may differ. High Cl(-) concentration reduces the photosynthetic capacity and quantum yield due to chlorophyll degradation which may result from a structural impact of high Cl(-) concentration on PSII. High Na(+) interferes with K(+) and Ca(2+) nutrition and disturbs efficient stomatal regulation which results in a depression of photosynthesis and growth. These results suggest that the importance of Cl(-) toxicity as a cause of reductions in growth and yield under salinity stress may have been underestimated.

Kinetics of Semiconductor Surface Chemistry: Silicon Atomic Layer Processing

DTIC Science & Technology

1993-05-01

H20 --> Si-OH + HCI; and (B) Si-OH + SiCl4 -- > Si-O-SiCl 3 + HC1. We examined reaction (A) for SiO 2 growth on Si(111)7x7 and porous silicon and... SiCl4 > Si-O-SiCl3 + HCI Repeat... • Reaction (A) and (B) are self-limiting * Expect excellent conformality Si-Cl + H20 ->Si-OH + HC1 SiCl2 LITD

Gustatory Plasticity in "C. elegans" Involves Integration of Negative Cues and NaCl Taste Mediated by Serotonin, Dopamine, and Glutamate

ERIC Educational Resources Information Center

Hukema, Renate K.; Rademakers, Suzanne; Jansen, Gert

2008-01-01

While naive "Caenorhabditis elegans" individuals are attracted to 0.1-200 mM NaCl, they become strongly repelled by these NaCl concentrations after prolonged exposure to 100 mM NaCl. We call this behavior gustatory plasticity. Here, we show that "C. elegans" displays avoidance of low NaCl concentrations only when pre-exposure to NaCl is combined…

Effect of the ZrCl4 concentration in the (NaCl-KCl)eqiv-UO2Cl2-ZrCl4 melt and the electrolysis current density on the quantitative composition of UO2-ZrO2 cathode deposits. Calculation and experiment

NASA Astrophysics Data System (ADS)

Krotov, V. E.; Filatov, E. C.

2014-08-01

A method is proposed for calculating the ZrO2 content in the (NaCl-KCl)eqiv-UO2Cl2-ZrCl4 melt. Based on the known composition of a UO2-ZrO2 cathode deposit, the content is calculated at current densities of 0.08-0.63 A/cm2 and ZrCl4 concentrations of 0-12.3 wt %. The calculated and experimental ZrO2 contents in UO2-ZrO2 cathode deposits are in qualitative and adequate quantitative agreement.

A thermochemical explanation for the stability of NaCl3 and NaCl7

NASA Astrophysics Data System (ADS)

Fernandes de Farias, Robson

2017-03-01

Thermodynamically stable cubic and orthorhombic NaCl3 as well as NaCl7 have been synthesized (Zhang et al., 2013). In the present work, a thermochemical explanation for the stability of such unusual sodium chlorides is provided, based on lattice energy values. Using the Glasser-Jenkins generalized equation (Glasser and Jenkins, 2000) lattice energies (kJ mol-1) of -162.5, -168.9 and -113.1 are calculated for Pm3n NaCl3, Pnma NaCl3 and NaCl7, respectively. It is postulated that any NaxCly compound could be synthesized, if the ionic character of the Nasbnd Cl bond in the prepared compound remains around 80%, and the sodium charge below unit.

The response of C1O radical concentrations to variations in NO2 radical concentrations in the lower stratosphere

NASA Technical Reports Server (NTRS)

Stimfle, R. M.; Koplow, J. P.; Cohen, R. C.; Kohn, D. W.; Wennberg, P. O.; Judah, D. M.; Toohey, D. W.; Avallone, L. M.; Anderson, J. G.; Salawitch, R. J.

1994-01-01

The respose of ClO concentrations to changes in NO2 concentrations has been inferred from simultaneous observations of (ClO), (NO), (NO2) and (O3) in the midlatitude lower stratosphere. This analysis demonstrates that (ClO) is inversely correlated with (NO2), consistent with formation and photolysis of (ClONO2). A factor of ten range in the concentration if NO2 was sampled (0.1 to 1 x 10(exp 9) mol/cu cm), with a comparable range in the ratio of (ClO) to total available inorganic chlorine (1% less than or equal to (ClO)/(Cl(sub y)) less than or equal to 5%. This analysis leads to an estimate of (ClONO2)/(Cl(sub y)) = 0.12 (x/2), in the mid-latitude, lower-stratospheric air masses sampled.

Rotational spectrum of the nitrogen trifluoride-chlorine monofluoride complex and the inductive effect of groups R=CH 3, H, F on R 3N/ClF interactions

NASA Astrophysics Data System (ADS)

Waclawik, E. R.; Legon, A. C.; Holloway, J. H.

1998-10-01

Rotational constants B0, centrifugal distortion constants DJ and DJK, and nuclear quadrupole coupling constants χ aa( 14N) and χaa(Cl) were determined by pulsed-nozzle, Fourier transform microwave spectroscopy for the isotopomers F314N⋯ 35ClF and F314N⋯ 37ClF of a complex formed by nitrogen trifluoride and chlorine monofluoride. The distance r(N⋯Cl) and the intermolecular stretching force constant kσ for this symmetric-top species are compared with those of several axially symmetric complexes B⋯ClF in which a nitrogen atom of the base B interacts with ClF. In particular, it is shown that r(N⋯Cl) decreases along the series R 3N⋯ClF, where R=F, H or CH 3, while kσ increases dramatically.

Chlorine-induced cardiopulmonary injury

PubMed Central

Carlisle, Matthew; Lam, Adam; Svendsen, Erik R.; Aggarwal, Saurabh; Matalon, Sadis

2016-01-01

Chlorine (Cl2) is utilized worldwide for a diverse range of industrial applications, including pulp bleaching, sanitation, and pharmaceutical development. Though Cl2 has widespread use, little is known regarding the mechanisms of toxicity associated with Cl2 exposure, which occurs during industrial accidents or acts of terrorism. Previous instances of Cl2 exposure have led to reported episodes of respiratory distress that result in high morbidity and mortality. Furthermore, studies suggest that acute Cl2 exposure also results in systemic vascular injury and subsequent myocardial contractile dysfunction. Here we review both lung and cardiac pathology associated with acute Cl2 inhalation and discuss recently published data that suggests that mitochondrial dysfunction underlies the pathogenesis of Cl2-induced toxicity. Lastly, we discuss our findings that suggest that upregulation of autophagy protects against Cl2-induced lung inflammation and can be a potential therapeutic target for ameliorating the toxic effects of Cl2 exposure. PMID:27303906

[Function of the CLC chloride channels and their implication in human pathology].

PubMed

Vandewalle, A

2002-01-01

To date, nine chloride channels belonging to the family of CLC chloride channels have been identified. They are localized either in plasma membranes or in intracellular vesicles (endosomes or lysosomes) and can have an ubiquitus or a more restrained tissue distribution. Recent studies on ClC-K1, ClC-2, ClC-3, ClC-5 and ClC-7 knockout mice and the identification of human inherited diseases caused by mutations of some of these chloride channels (myotonia congenita for ClC-1, Bartter disease for ClC-Kb, Dent's disease for ClC-5 and osteopetrose for ClC-7) have provided lines of direct evidence of the physiological relevance and importance of these chloride channels in the transport of chloride and in the endocytosis and transcytosis of proteins in specialized cells from the kidney and other tissues.

Chlorine-induced cardiopulmonary injury.

PubMed

Carlisle, Matthew; Lam, Adam; Svendsen, Erik R; Aggarwal, Saurabh; Matalon, Sadis

2016-06-01

Chlorine (Cl2 ) is utilized worldwide for a diverse range of industrial applications, including pulp bleaching, sanitation, and pharmaceutical development. Though Cl2 has widespread use, little is known regarding the mechanisms of toxicity associated with Cl2 exposure, which occurs during industrial accidents or acts of terrorism. Previous instances of Cl2 exposure have led to reported episodes of respiratory distress that result in high morbidity and mortality. Furthermore, studies suggest that acute Cl2 exposure also results in systemic vascular injury and subsequent myocardial contractile dysfunction. Here, we review both lung and cardiac pathology associated with acute Cl2 inhalation and discuss recently published data that suggest that mitochondrial dysfunction underlies the pathogenesis of Cl2 -induced toxicity. Last, we discuss our findings that suggest that upregulation of autophagy protects against Cl2 -induced lung inflammation and can be a potential therapeutic target for ameliorating the toxic effects of Cl2 exposure. © 2016 New York Academy of Sciences.

Ionic Liquids and Solids with Paramagnetic Anions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castner, Jr., E.W.; Wishart, J.; Krieger, B.M.

2010-06-18

Four paramagnetic ionic compounds have been prepared and their magnetic, structural and thermal properties have been investigated. The four compounds are methylbutylpyrrolidinium tetrachloroferrate(III) ([Pyrr{sub 14}]{sup +}/[FeCl{sub 4}]{sup -}), methyltributylammonium tetrachloroferrate(III) ([N{sub 1444}]{sup +}/[FeCl{sub 4}]{sup -}), butylmethylimidazolium tetrachloroferrate(III) ([bmim]{sup +}/[FeCl{sub 4}]{sup -}) and tetrabutylammonium bromotrichloroferrate(III) ([N{sub 4444}]{sup +}/[FeBrCl{sub 3}]{sup -}). Temperature-dependent studies of their magnetic behaviors show that all four compounds are paramagnetic at ambient temperatures. Glass transitions are observed for only two of the four compounds, [Pyrr{sub 14}]{sup +}/[FeCl{sub 4}]{sup -} and [bmim]{sup +}/[FeCl{sub 4}]{sup -}. Crystal structures for [Pyrr{sub 14}]{sup +}/[FeCl{sub 4}]{sup -} and [N{sub 1444}]{sup +}/[FeCl{sub 4}]{sup -}more » are compared with the previously reported [N{sub 4444}]{sup +}/[FeBrCl{sub 3}]{sup -}.« less