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Sample records for power negative ion

  1. Development of negative ion extractor in the high-power and long-pulse negative ion source for fusion application

    SciTech Connect

    Kashiwagi, M. Umeda, N.; Tobari, H.; Kojima, A.; Yoshida, M.; Taniguchi, M.; Dairaku, M.; Maejima, T.; Yamanaka, H.; Watanabe, K.; Inoue, T.; Hanada, M.

    2014-02-15

    High power and long-pulse negative ion extractor, which is composed of the plasma grid (PG) and the extraction grid (EXG), is newly developed toward the neutral beam injector for heating and current drive of future fusion machines such as ITER, JT-60 Super Advanced and DEMO reactor. The PG is designed to enhance surface production of negative ions efficiently by applying the chamfered aperture. The efficiency of the negative ion production for the discharge power increased by a factor of 1.3 against that of the conventional PG. The EXG is also designed with the thermal analysis to upgrade the cooling capability for the long pulse operation of >1000 s required in ITER. Though the magnetic field for electron suppression is reduced to 0.75 of that in the conventional EXG due to this upgrade, it was experimentally confirmed that the extracted electron current can be suppressed to the allowable level for the long pulse operation. These results show that newly developed extractor has the high potential for the long pulse extraction of the negative ions.

  2. Negative ion generator

    DOEpatents

    Stinnett, Regan W.

    1984-01-01

    A negative ion generator is formed from a magnetically insulated transmission line having a coating of graphite on the cathode for producing negative ions and a plurality of apertures on the opposed anode for the release of negative ions. Magnetic insulation keeps electrons from flowing from the cathode to the anode. A transverse magnetic field removes electrons which do escape through the apertures from the trajectory of the negative ions.

  3. Negative ion generator

    DOEpatents

    Stinnett, R.W.

    1984-05-08

    A negative ion generator is formed from a magnetically insulated transmission line having a coating of graphite on the cathode for producing negative ions and a plurality of apertures on the opposed anode for the release of negative ions. Magnetic insulation keeps electrons from flowing from the cathode to the anode. A transverse magnetic field removes electrons which do escape through the apertures from the trajectory of the negative ions. 8 figs.

  4. Negative Ion Density Fronts

    SciTech Connect

    Igor Kaganovich

    2000-12-18

    Negative ions tend to stratify in electronegative plasmas with hot electrons (electron temperature Te much larger than ion temperature Ti, Te > Ti ). The boundary separating a plasma containing negative ions, and a plasma, without negative ions, is usually thin, so that the negative ion density falls rapidly to zero-forming a negative ion density front. We review theoretical, experimental and numerical results giving the spatio-temporal evolution of negative ion density fronts during plasma ignition, the steady state, and extinction (afterglow). During plasma ignition, negative ion fronts are the result of the break of smooth plasma density profiles during nonlinear convection. In a steady-state plasma, the fronts are boundary layers with steepening of ion density profiles due to nonlinear convection also. But during plasma extinction, the ion fronts are of a completely different nature. Negative ions diffuse freely in the plasma core (no convection), whereas the negative ion front propagates towards the chamber walls with a nearly constant velocity. The concept of fronts turns out to be very effective in analysis of plasma density profile evolution in strongly non-isothermal plasmas.

  5. Design considerations for a negative ion source for dc operation of high-power, multi-megaelectron-volt neutral beams

    SciTech Connect

    Tsai, C.C.; Stirling, W.L.; Akerman, M.A.; Becraft, W.R.; Dagenhart, W.K.; Haselton, H.H.; Ryan, P.M.; Schechter, D.E.; Whealton, J.H.

    1988-03-01

    A dc negative hydrogen and/or deuterium ion source is needed to prouce high-power, high-energy neutral beams for alpha diagnostics and current drive applicatiosn in fusion devices. The favorable beam particle energy for such applications extends to 1.5 MeV/amu. Continuous-wave (cw) radio-frequency quadrupole (RFQ) accelerators have been proposed to accelerate negative ions effeciently to this energy range. In this paper, the desired beam properties for ion beams injected into cw RFQ accelerators are summariezed. A number of candidate ion sources being developed at Culham, JAERI, LBL, and ORNL may prove useful for these applications. The properties of the Volume Ionization with Transverse Extraction (VITEX) ion sources being developed at ORNL are presented. Scaling such a dc ion source to produce ampere beams is discussed. 53 refs., 4 figs., 2 tabs.

  6. Design considerations for a negative ion source for dc operation of high-power, multi-megaelectron-volt neutral beams

    SciTech Connect

    Tsai, C.C.; Stirling, W.L.; Akerman, M.A.; Becraft, W.R.; Dagenhart, W.K.; Haselton, H.H.; Ryan, P.M.; Schechter, D.E.; Whealton, J.H.

    1987-01-01

    A dc negative hydrogen and/or deuterium ion source is needed to produce high-power, high-energy neutral beams for alpha diagnostics and current drive applications in fusion devices. The favorable beam particle energy for such applications extends to 1.5 MeV/amu. Continuous-wave (cw) radiofrequency quadrupole (RFQ) accelerators have been proposed to accelerate negative ions efficiently to this energy range. In this paper, the desired beam properties for ion beams injected into cw RFQ accelerators are summarized. A number of candidate ion sources being developed at Culham, JAERI, LBL, and ORNL may prove useful for these applications. The properties of the Volume Ionization with Transverse Extraction (VITEX) ion sources being developed at ORNL are presented. Scaling such a dc ion source to produce ampere beams is discussed. 53 refs., 4 figs., 2 tabs.

  7. Progress in long-pulse production of powerful negative ion beams for JT-60SA and ITER

    NASA Astrophysics Data System (ADS)

    Kojima, A.; Umeda, N.; Hanada, M.; Yoshida, M.; Kashiwagi, M.; Tobari, H.; Watanabe, K.; Akino, N.; Komata, M.; Mogaki, K.; Sasaki, S.; Seki, N.; Nemoto, S.; Shimizu, T.; Endo, Y.; Ohasa, K.; Dairaku, M.; Yamanaka, H.; Grisham, L. R.

    2015-06-01

    Significant progress in the extension of pulse durations of powerful negative ion beams has been made to realize the neutral beam injectors for JT-60SA and ITER. In order to overcome common issues of the long-pulse production/acceleration of negative ion beams in JT-60SA and ITER, new technologies have been developed in the JT-60SA ion source and the MeV accelerator in Japan Atomic Energy Agency. As for the long-pulse production of high-current negative ions for the JT-60SA ion source, the pulse durations have been successfully increased from 30 s at 13 A on JT-60U to 100 s at 15 A by modifying the JT-60SA ion source, which satisfies the required pulse duration of 100 s and 70% of the rated beam current for JT-60SA. This progress was based on the R&D efforts for the temperature control of the plasma grid and uniform negative ion productions with the modified tent-shaped filter field configuration. Moreover, each parameter of the required beam energy, current and pulse has been achieved individually by these R&D efforts. The developed techniques are useful to design the ITER ion source because the sustainment of the caesium coverage in the large extraction area is one of the common issues between JT-60SA and ITER. As for the long-pulse acceleration of high power density beams in the MeV accelerator for ITER, the pulse duration of MeV-class negative ion beams has been extended by more than 2 orders of magnitude by modifying the extraction grid with a high cooling capability and a high transmission of negative ions. A long-pulse acceleration of 60 s has been achieved at 70 MW m-2 (683 keV, 100 A m-2) which has reached the power density of JT-60SA level of 65 MW m-2. No degradations of the voltage holding capability of the acceleration voltage and the beam optics due to the distortion of the acceleration grids have been observed in this power density level. These results are the longest pulse durations of high-current and high-power-density negative ion beams in the

  8. Long pulse acceleration of MeV class high power density negative H{sup −} ion beam for ITER

    SciTech Connect

    Umeda, N. Kojima, A.; Kashiwagi, M.; Tobari, H.; Hiratsuka, J.; Watanabe, K.; Dairaku, M.; Yamanaka, H.; Hanada, M.

    2015-04-08

    R and D of high power density negative ion beam acceleration has been carried out at MeV test facility in JAEA to realize ITER neutral beam accelerator. The main target is H{sup −} ion beam acceleration up to 1 MeV with 200 A/m{sup 2} for 60 s whose pulse length is the present facility limit. For long pulse acceleration at high power density, new extraction grid (EXG) has been developed with high cooling capability, which electron suppression magnet is placed under cooling channel similar to ITER. In addition, aperture size of electron suppression grid (ESG) is enlarged from 14 mm to 16 mm to reduce direct interception on the ESG and emission of secondary electron which leads to high heat load on the upstream acceleration grid. By enlarging ESG aperture, beam current increased 10 % at high current beam and total acceleration grid heat load reduced from 13 % to 10 % of input power at long pulse beam. In addition, heat load by back stream positive ion into the EXG is measured for the first time and is estimated as 0.3 % of beam power, while heat load by back stream ion into the source chamber is estimated as 3.5 ~ 4.0 % of beam power. Beam acceleration up to 60 s which is the facility limit, has achieved at 683 keV, 100 A/m{sup 2} of negative ion beam, whose energy density increases two orders of magnitude since 2011.

  9. Towards large and powerful radio frequency driven negative ion sources for fusion

    NASA Astrophysics Data System (ADS)

    Heinemann, B.; Fantz, U.; Kraus, W.; Schiesko, L.; Wimmer, C.; Wünderlich, D.; Bonomo, F.; Fröschle, M.; Nocentini, R.; Riedl, R.

    2017-01-01

    The ITER neutral beam system will be equipped with radio-frequency (RF) negative ion sources, based on the IPP Garching prototype source design. Up to 100 kW at 1 MHz is coupled to the RF driver, out of which the plasma expands into the main source chamber. Compared to arc driven sources, RF sources are maintenance free and without evaporation of tungsten. The modularity of the driver concept permits to supply large source volumes. The prototype source (one driver) demonstrated operation in hydrogen and deuterium up to one hour with ITER relevant parameters. The ELISE test facility is operating with a source of half the ITER size (four drivers) in order to validate the modular source concept and to gain early operational experience at ITER relevant dimensions. A large variety of diagnostics allows improving the understanding of the relevant physics and its link to the source performance. Most of the negative ions are produced on a caesiated surface by conversion of hydrogen atoms. Cs conditioning and distribution have been optimized in order to achieve high ion currents which are stable in time. A magnetic filter field is needed to reduce the electron temperature and co-extracted electron current. The influence of different field topologies and strengths on the source performance, plasma and beam properties is being investigated. The results achieved in short pulse operation are close to or even exceed the ITER requirements with respect to the extracted ion currents. However, the extracted negative ion current for long pulse operation (up to 1 h) is limited by the increase of the co-extracted electron current, especially in deuterium operation.

  10. Concepts of magnetic filter fields in powerful negative ion sources for fusion

    SciTech Connect

    Kraus, W. Fantz, U.; Heinemann, B.; Wünderlich, D.

    2016-02-15

    The performance of large negative ion sources used in neutral beam injection systems is in long pulses mainly determined by the increase of the currents of co-extracted electrons. This is in particular a problem in deuterium and limits the ion currents which are for long pulses below the requirements for the ITER source. In the source of the ELISE test facility, the magnetic field in front of the first grid, which is essential to reduce the electron current, is generated by a current of several kA flowing through the plasma facing grid. Weakening of this field by the addition of permanent magnets placed close to the lateral walls has led to a reduction of the electron current by a factor three without loss of ion current when source was operated in volume production. If this effect can be validated for the cesiated source, it would be a large step towards achieving the ITER parameter in long pulses.

  11. Polarized negative ions

    SciTech Connect

    Haeberli, W.

    1981-04-01

    This paper presents a survey of methods, commonly in use or under development, to produce beams of polarized negative ions for injection into accelerators. A short summary recalls how the hyperfine interaction is used to obtain nuclear polarization in beams of atoms. Atomic-beam sources for light ions are discussed. If the best presently known techniques are incorporated in all stages of the source, polarized H/sup -/ and D/sup -/ beams in excess of 10 ..mu..A can probably be achieved. Production of polarized ions from fast (keV) beams of polarized atoms is treated separately for atoms in the H(25) excited state (Lamb-Shift source) and atoms in the H(1S) ground state. The negative ion beam from Lamb-Shift sources has reached a plateau just above 1 ..mu..A, but this beam current is adequate for many applications and the somewhat lower beam current is compensated by other desirable characteristics. Sources using fast polarized ground state atoms are in a stage of intense development. The next sections summarize production of polarized heavy ions by the atomic beam method, which is well established, and by optical pumping, which has recently been demonstrated to yield very large nuclear polarization. A short discussion of proposed ion sources for polarized /sup 3/He/sup -/ ions is followed by some concluding remarks.

  12. Negative ion source

    DOEpatents

    Leung, Ka-Ngo; Ehlers, Kenneth W.

    1984-01-01

    An ionization vessel is divided into an ionizing zone and an extraction zone by a magnetic filter. The magnetic filter prevents high-energy electrons from crossing from the ionizing zone to the extraction zone. A small positive voltage impressed on a plasma grid, located adjacent an extraction grid, positively biases the plasma in the extraction zone to thereby prevent positive ions from migrating from the ionizing zone to the extraction zone. Low-energy electrons, which would ordinarily be dragged by the positive ions into the extraction zone, are thereby prevented from being present in the extraction zone and being extracted along with negative ions by the extraction grid. Additional electrons are suppressed from the output flux using ExB drift provided by permanent magnets and the extractor grid electrical field.

  13. Negative ion source

    DOEpatents

    Leung, K.N.; Ehlers, K.W.

    1982-08-06

    An ionization vessel is divided into an ionizing zone and an extraction zone by a magnetic filter. The magnetic filter prevents high-energy electrons from crossing from the ionizing zone to the extraction zone. A small positive voltage impressed on a plasma grid, located adjacent an extraction grid, positively biases the plasma in the extraction zone to thereby prevent positive ions from migrating from the ionizing zone to the extraction zone. Low-energy electrons, which would ordinarily be dragged by the positive ions into the extraction zone, are thereby prevented from being present in the extraction zone and being extracted along with negative ions by the extraction grid. Additional electrons are suppressed from the output flux using ExB drift provided by permanent magnets and the extractor grid electrical field.

  14. Negative ion source

    DOEpatents

    Leung, K.N.; Ehlers, K.W.

    1984-12-04

    An ionization vessel is divided into an ionizing zone and an extraction zone by a magnetic filter. The magnetic filter prevents high-energy electrons from crossing from the ionizing zone to the extraction zone. A small positive voltage impressed on a plasma grid, located adjacent an extraction grid, positively biases the plasma in the extraction zone to thereby prevent positive ions from migrating from the ionizing zone to the extraction zone. Low-energy electrons, which would ordinarily be dragged by the positive ions into the extraction zone, are thereby prevented from being present in the extraction zone and being extracted along with negative ions by the extraction grid. Additional electrons are suppressed from the output flux using ExB drift provided by permanent magnets and the extractor grid electrical field. 14 figs.

  15. Experimental Evaluation of a Negative Ion Source for a Heavy Ion Fusion Negative Ion Driver

    SciTech Connect

    Grisham, L. R.; Hahto, S. K.; Hahto, S. T.; Kwan, J. W.; Leung, K. N.

    2004-06-16

    Negative halogen ions have recently been proposed as a possible alternative to positive ions for heavy ion fusion drivers because electron accumulation would not be a problem in the accelerator, and if desired, the beams could be photo-detached to neutrals. To test the ability to make suitable quality beams, an experiment was conducted at Lawrence Berkeley National Laboratory using chlorine in an RF-driven ion source. Without introducing any cesium (which is required to enhance negative ion production in hydrogen ion sources) a negative chlorine current density of 45 mA/cm{sup 2} was obtained under the same conditions that gave 57 45 mA/cm{sup 2} of positive chlorine, suggesting the presence of nearly as many negative ions as positive ions in the plasma near the extraction plane. The negative ion spectrum was 99.5% atomic chlorine ions, with only 0.5% molecular chlorine, and essentially no impurities. Although this experiment did not incorporate the type of electron suppression technology that i s used in negative hydrogen beam extraction, the ratio of co-extracted electrons to Cl{sup -} was as low as 7 to 1, many times lower than the ratio of their mobilities, suggesting that few electrons are present in the near-extractor plasma. This, along with the near-equivalence of the positive and negative ion currents, suggests that the plasma in this region was mostly an ion-ion plasma. The negative chlorine current density was relatively insensitive to pressure, and scaled linearly with RF power. If this linear scaling continues to hold at higher RF powers, it should permit current densities of 100 45 mA/cm{sup 2}, sufficient for present heavy ion fusion injector concepts. The effective ion temperatures of the positive and negative ions appeared to be similar and relatively low for a plasma source.

  16. Improved negative ion source

    DOEpatents

    Delmore, J.E.

    1984-05-01

    A method and apparatus for providing a negative ion source accelerates electrons away from a hot filament electron emitter into a region of crossed electric and magnetic fields arranged in a magnetron configuration. During a portion of the resulting cycloidal path, the electron velocity is reduced below its initial value. The electron accelerates as it leaves the surface at a rate of only slightly less than if there were no magnetic field, thereby preventing a charge buildup at the surface of the emitter. As the electron traverses the cycloid, it is decelerated during the second, third, and fourth quadrants, then reaccelerated as it approaches the end of the fourth quadrant to regain its original velocity. The minimum velocity occurs during the fourth quadrant, and corresponds to an electron temperature of 200 to 500/sup 0/C for the electric and magnetic fields commonly encountered in the ion sources of magnetic sector mass spectrometers. An ion source using the above-described thermalized electrons is also disclosed.

  17. Negative ion source

    DOEpatents

    Delmore, James E.

    1987-01-01

    A method and apparatus for providing a negative ion source accelerates electrons away from a hot filament electron emitter into a region of crossed electric and magnetic fields arranged in a magnetron configuration. During a portion of the resulting cycloidal path, the electron velocity is reduced below its initial value. The electron accelerates as it leaves the surface at a rate of only slightly less than if there were no magnetic field, thereby preventing a charge buildup at the surface of the emitter. As the electron traverses the cycloid, it is decelerated during the second, third, and fourth quadrants, then reeccelerated as it approaches the end of the fourth quadrant to regain its original velocity. The minimum velocity occurs during the fourth quadrant, and corresponds to an electron temperature of 200.degree. to 500.degree. for the electric and magnetic fields commonly encountered in the ion sources of magnetic sector mass spectrometers. An ion source using the above-described thermalized electrons is also disclosed.

  18. Discharge Characteristics of Large-Area High-Power RF Ion Source for Positive and Negative Neutral Beam Injectors

    NASA Astrophysics Data System (ADS)

    Doo-Hee, Chang; Seung, Ho Jeong; Min, Park; Tae-Seong, Kim; Bong-Ki, Jung; Kwang, Won Lee; Sang Ryul, In

    2016-12-01

    A large-area high-power radio-frequency (RF) driven ion source was developed for positive and negative neutral beam injectors at the Korea Atomic Energy Research Institute (KAERI). The RF ion source consists of a driver region, including a helical antenna and a discharge chamber, and an expansion region. RF power can be transferred at up to 10 kW with a fixed frequency of 2 MHz through an optimized RF matching system. An actively water-cooled Faraday shield is located inside the driver region of the ion source for the stable and steady-state operations of high-power RF discharge. Plasma ignition of the ion source is initiated by the injection of argon-gas without a starter-filament heating, and the argon-gas is then slowly exchanged by the injection of hydrogen-gas to produce pure hydrogen plasmas. The uniformities of the plasma parameter, such as a plasma density and an electron temperature, are measured at the lowest area of the driver region using two RF-compensated electrostatic probes along the direction of the short-and long-dimensions of the driver region. The plasma parameters will be compared with those obtained at the lowest area of the expansion bucket to analyze the plasma expansion properties from the driver region to the expansion region. supported by the Ministry of Science, ICT and Future Planning of the Republic of Korea under the ITER Technology R&D Program, and National R&D Program Through the National Research Foundation of Korea (NRF) Funded by the Ministry of Science, ICT & Future Planning (NRF-2014M1A7A1A03045372)

  19. Simulation Based on Ion Propulsion Rocket System with Using Negative ion - Negative Ion Pair Techniques

    NASA Astrophysics Data System (ADS)

    Sathiyavel, C.

    2016-07-01

    Ion propulsion rocket system is expected to become popular with the development of ion-ion pair techniques because of their stimulated of low propellant, Design of Thrust range is 1N with low electric power and high efficiency. A Negative ion-Negative ion pair of ion propulsion rocket system is proposed in this work .Negative Ion Based Rocket system consists of three parts 1.ionization chamber 2. Repulsion force and ion accelerator 3. Exhaust of Nozzle. The Negative ions from electro negatively gas are produced by attachment of the gas ,such as chlorine with electron emitted from a Electron gun ionization chamber. The formulate of large stable negative ion is achievable in chlorine gas with respect to electron affinity (∆E). The electron affinity is a measure of the energy change when an electron is added to a neutral atom to form a negative ion. When a neutral chlorine atom in the gaseous form picks up an electron to form a Cl- ion, it releases energy of 349 kJ/mol or 3.6 ev/atom. It is said to have an electron affinity of -349 kJ/mol ,the negative sign indicating that energy is released during this process .The mechanisms of attachment involve the formation of intermediate states. In that reason for , the highly repulsive force created between the same negative ions. The distance between same negative ions is important for the evaluate of the rocket thrust and is also determined by the exhaust velocity of the propellant. The mass flow rate of propellant is achieved by the ratio of total mass of the propellant (Kg) needed for operation to time period(s). Accelerate the Negative ions to a high velocity in the thrust vector direction with a significantly intense Magnetic field and the exhaust of negative ions through Nozzle. The simulation of the ion propulsion system has been carried out by MATLAB. By comparing the simulation results with the theoretical and previous results, we have found that the proposed method is achieved of thrust value with estimated

  20. Negative Ion Beam Extraction and Emittance

    SciTech Connect

    Holmes, Andrew J. T.

    2007-08-10

    The use of magnetic fields to both aid the production of negative ions and suppress the co-extracted electrons causes the emittance and hence the divergence of the negative ion beam to increase significantly due to the plasma non-uniformity from jxB drift. This drift distorts the beam-plasma meniscus and experimental results of the beam emittance are presented, which show that non-uniformity causes the square of the emittance to be proportional to the 2/3 power of the extracted current density. This can cause the divergence of the negative ion beam to be significantly larger than its positive ion counterpart. By comparing results from positive and negative ion beam emittances from the same source, it is also possible to draw conclusions about their vulnerability to magnetic effects. Finally emittances of caesiated and un-caesiated negative ion beams are compared to show how the surface and volume modes of production interact.

  1. Negative hydrogen ion production mechanisms

    SciTech Connect

    Bacal, M.; Wada, M.

    2015-06-15

    Negative hydrogen/deuterium ions can be formed by processes occurring in the plasma volume and on surfaces facing the plasma. The principal mechanisms leading to the formation of these negative ions are dissociative electron attachment to ro-vibrationally excited hydrogen/deuterium molecules when the reaction takes place in the plasma volume, and the direct electron transfer from the low work function metal surface to the hydrogen/deuterium atoms when formation occurs on the surface. The existing theoretical models and reported experimental results on these two mechanisms are summarized. Performance of the negative hydrogen/deuterium ion sources that emerged from studies of these mechanisms is reviewed. Contemporary negative ion sources do not have negative ion production electrodes of original surface type sources but are operated with caesium with their structures nearly identical to volume production type sources. Reasons for enhanced negative ion current due to caesium addition to these sources are discussed.

  2. Negative hydrogen ion production mechanisms

    NASA Astrophysics Data System (ADS)

    Bacal, M.; Wada, M.

    2015-06-01

    Negative hydrogen/deuterium ions can be formed by processes occurring in the plasma volume and on surfaces facing the plasma. The principal mechanisms leading to the formation of these negative ions are dissociative electron attachment to ro-vibrationally excited hydrogen/deuterium molecules when the reaction takes place in the plasma volume, and the direct electron transfer from the low work function metal surface to the hydrogen/deuterium atoms when formation occurs on the surface. The existing theoretical models and reported experimental results on these two mechanisms are summarized. Performance of the negative hydrogen/deuterium ion sources that emerged from studies of these mechanisms is reviewed. Contemporary negative ion sources do not have negative ion production electrodes of original surface type sources but are operated with caesium with their structures nearly identical to volume production type sources. Reasons for enhanced negative ion current due to caesium addition to these sources are discussed.

  3. Negative ions of polyatomic molecules.

    PubMed Central

    Christophorou, L G

    1980-01-01

    In this paper general concepts relating to, and recent advances in, the study of negative ions of polyatomic molecules area discussed with emphasis on halocarbons. The topics dealt with in the paper are as follows: basic electron attachment processes, modes of electron capture by molecules, short-lived transient negative ions, dissociative electron attachment to ground-state molecules and to "hot" molecules (effects of temperature on electron attachment), parent negative ions, effect of density, nature, and state of the medium on electron attachment, electron attachment to electronically excited molecules, the binding of attached electrons to molecules ("electron affinity"), and the basic and the applied significance of negative-ion studies. PMID:7428744

  4. Negative ions of polyatomic molecules.

    PubMed

    Christophorou, L G

    1980-06-01

    In this paper general concepts relating to, and recent advances in, the study of negative ions of polyatomic molecules area discussed with emphasis on halocarbons. The topics dealt with in the paper are as follows: basic electron attachment processes, modes of electron capture by molecules, short-lived transient negative ions, dissociative electron attachment to ground-state molecules and to "hot" molecules (effects of temperature on electron attachment), parent negative ions, effect of density, nature, and state of the medium on electron attachment, electron attachment to electronically excited molecules, the binding of attached electrons to molecules ("electron affinity"), and the basic and the applied significance of negative-ion studies.

  5. Negative Ions in Space.

    PubMed

    Millar, Thomas J; Walsh, Catherine; Field, Thomas A

    2017-02-08

    Until a decade ago, the only anion observed to play a prominent role in astrophysics was H(-). The bound-free transitions in H(-) dominate the visible opacity in stars with photospheric temperatures less than 7000 K, including the Sun. The H(-) anion is also believed to have been critical to the formation of molecular hydrogen in the very early evolution of the Universe. Once H2 formed, about 500 000 years after the Big Bang, the expanding gas was able to lose internal gravitational energy and collapse to form stellar objects and "protogalaxies", allowing the creation of heavier elements such as C, N, and O through nucleosynthesis. Although astronomers had considered some processes through which anions might form in interstellar clouds and circumstellar envelopes, including the important role that polycyclic aromatic hydrocarbons might play in this, it was the detection in 2006 of rotational line emission from C6H(-) that galvanized a systematic study of the abundance, distribution, and chemistry of anions in the interstellar medium. In 2007, the Cassini mission reported the unexpected detection of anions with mass-to-charge ratios of up to ∼10 000 in the upper atmosphere of Titan; this observation likewise instigated the study of fundamental chemical processes involving negative ions among planetary scientists. In this article, we review the observations of anions in interstellar clouds, circumstellar envelopes, Titan, and cometary comae. We then discuss a number of processes by which anions can be created and destroyed in these environments. The derivation of accurate rate coefficients for these processes is an essential input for the chemical kinetic modeling that is necessary to fully extract physics from the observational data. We discuss such models, along with their successes and failings, and finish with an outlook on the future.

  6. Three chamber negative ion source

    DOEpatents

    Leung, K.N.; Ehlers, K.W.; Hiskes, J.R.

    1983-11-10

    It is an object of this invention provide a negative ion source which efficiently provides a large flux of negatively ionized particles. This invention provides a volume source of negative ions which has a current density sufficient for magnetic fusion applications and has electrons suppressed from the output. It is still another object of this invention to provide a volume source of negative ions which can be electrostatically accelerated to high energies and subsequently neutralized to form a high energy neutral beam for use with a magnetically confined plasma.

  7. X-ray photoelectron spectroscopy of negative electrodes from high-power lithium-ion cells showing various levels of power fade

    SciTech Connect

    Herstedt, Marie; Abraham, Daniel P.; Kerr, John B.

    2004-02-28

    High-power lithium-ion cells for transportation applications are being developed and studied at Argonne National Laboratory. The current generation of cells containing LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2}-based cathodes, graphite-based anodes, and LiPF6-based electrolytes show loss of capacity and power during accelerated testing at elevated temperatures. Negative electrode samples harvested from some cells that showed varying degrees of power and capacity fade were examined by X-ray photoelectron spectroscopy (XPS). The samples exhibited a surface film on the graphite, which was thicker on samples from cells that showed higher fade. Furthermore, solvent-based compounds were dominant on samples from low power fade cells, whereas LiPF{sub 6}-based products were dominant on samples from high power fade cells. The effect of sample rinsing and air exposure is discussed. Mechanisms are proposed to explain the formation of compounds suggested by the XPS data.

  8. Characteristics of a high-power RF source of negative hydrogen ions for neutral beam injection into controlled fusion devices

    NASA Astrophysics Data System (ADS)

    Abdrashitov, G. F.; Belchenko, Yu. I.; Gusev, I. A.; Ivanov, A. A.; Kondakov, A. A.; Sanin, A. L.; Sotnikov, O. Z.; Shikhovtsev, I. V.

    2017-01-01

    An injector of hydrogen atoms with an energy of 0.5-1 MeV and equivalent current of up to 1.5 A for purposes of controlled fusion research is currently under design at the Budker Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences. Within this project, a multiple-aperture RF surface-plasma source of negative hydrogen ions is designed. The source design and results of experiments on the generation of a negative ion beam with a current of >1 A in the long-pulse mode are presented.

  9. Experimental evaluation of a negative ion source for a heavy ionfusion negative ion driver

    SciTech Connect

    Grisham, L.R.; Hahto, S.K.; Hahto, S.T.; Kwan, J.W.; Leung, K.N.

    2005-01-18

    Negative halogen ions have recently been proposed as a possible alternative to positive ions for heavy ion fusion drivers because electron accumulation would not be a problem in the accelerator, and if desired, the beams could be photodetached to neutrals [1,2,3]. To test the ability to make suitable quality beams, an experiment was conducted at Lawrence Berkeley National Laboratory using chlorine in an RF-driven ion source. Without introducing any cesium (which is required to enhance negative ion production in hydrogen ion sources) a negative chlorine current density of 45 mA/cm{sup 2} was obtained under the same conditions that gave 57 mA/cm{sup 2} of positive chlorine, suggesting the presence of nearly as many negative ions as positive ions in the plasma near the extraction plane. The negative ion spectrum was 99.5% atomic chlorine ions, with only 0.5% molecular chlorine, and essentially no impurities. Although this experiment did not incorporate the type of electron suppression technology that is used in negative hydrogen beam extraction, the ratio of co-extracted electrons to Cl{sup -} was as low as 7 to 1, many times lower than the ratio of their mobilities, suggesting that few electrons are present in the near-extractor plasma. This, along with the near-equivalence of the positive and negative ion currents, suggests that the plasma in this region was mostly an ion-ion plasma. The negative chlorine current density was relatively insensitive to pressure, and scaled linearly with RF power. If this linear scaling continues to hold at higher RF powers, it should permit current densities of 100 mA/cm{sup 2}, sufficient for present heavy ion fusion injector concepts. The effective ion temperatures of the positive and negative ions appeared to be similar and relatively low for a plasma source.

  10. Three chamber negative ion source

    DOEpatents

    Leung, Ka-Ngo; Ehlers, Kenneth W.; Hiskes, John R.

    1985-01-01

    A negative ion vessel is divided into an excitation chamber, a negative ionization chamber and an extraction chamber by two magnetic filters. Input means introduces neutral molecules into a first chamber where a first electron discharge means vibrationally excites the molecules which migrate to a second chamber. In the second chamber a second electron discharge means ionizes the molecules, producing negative ions which are extracted into or by a third chamber. A first magnetic filter prevents high energy electrons from entering the negative ionization chamber from the excitation chamber. A second magnetic filter prevents high energy electrons from entering the extraction chamber from the negative ionizing chamber. An extraction grid at the end of the negative ion vessel attracts negative ions into the third chamber and accelerates them. Another grid, located adjacent to the extraction grid, carries a small positive voltage in order to inhibit positive ions from migrating into the extraction chamber and contour the plasma potential. Additional electrons can be suppressed from the output flux using ExB forces provided by magnetic field means and the extractor grid electric potential.

  11. Negative-ion plasma sources

    NASA Astrophysics Data System (ADS)

    Sheehan, D. P.; Rynn, N.

    1988-08-01

    Three designs for negative-ion plasma sources are described. Two sources utilize metal hexafluorides such as SF6 and WF6 to scavenge electrons from electron-ion plasmas and the third relies upon surface ionization of alkali halide salts on heated alumina and zirconia. SF6 introduced into electron-ion plasmas yielded negative-ion plasma densities of 10 to the 10th/cu cm with low residual electron densities. On alumina, plasma densities of 10 to the 9th/cu cm were obtained for CsCl, CsI, and KI and 10 to the 9th/cu cm for KCl. On zirconia 10 to the 10th/cu cm densities were obtained for CsCl. For alkali halide sources, electron densities of less than about 10 to the -4th have been achieved.

  12. Development of versatile multiaperture negative ion sources

    SciTech Connect

    Cavenago, M.; Minarello, A.; Sattin, M.; Serianni, G.; Antoni, V.; Bigi, M.; Pasqualotto, R.; Recchia, M.; Veltri, P.; Agostinetti, P.; Barbisan, M.; Baseggio, L.; Cervaro, V.; Degli Agostini, F.; Franchin, L.; Laterza, B.; Ravarotto, D.; Rossetto, F.; Zaniol, B.; Zucchetti, S.; and others

    2015-04-08

    Enhancement of negative ion sources for production of large ion beams is a very active research field nowadays, driven from demand of plasma heating in nuclear fusion devices and accelerator applications. As a versatile test bench, the ion source NIO1 (Negative Ion Optimization 1) is being commissioned by Consorzio RFX and INFN. The nominal beam current of 135 mA at −60 kV is divided into 9 beamlets, with multiaperture extraction electrodes. The plasma is sustained by a 2 MHz radiofrequency power supply, with a standard matching box. A High Voltage Deck (HVD) placed inside the lead shielding surrounding NIO1 contains the radiofrequency generator, the gas control, electronics and power supplies for the ion source. An autonomous closed circuit water cooling system was installed for the whole system, with a branch towards the HVD, using carefully optimized helical tubing. Insulation transformer is installed in a nearby box. Tests of several magnetic configurations can be performed. Status of experiments, measured spectra and plasma luminosity are described. Upgrades of magnetic filter, beam calorimeter and extraction grid and related theoretical issues are reviewed.

  13. Ion Accelerator With Negatively Biased Decelerator Grid

    NASA Technical Reports Server (NTRS)

    Brophy, John R.

    1994-01-01

    Three-grid ion accelerator in which accelerator grid is biased at negative potential and decelerator grid downstream of accelerator grid biased at smaller negative potential. This grid and bias arrangement reduces frequency of impacts, upon accelerator grid, of charge-exchange ions produced downstream in collisions between accelerated ions and atoms and molecules of background gas. Sputter erosion of accelerator grid reduced.

  14. EDITORIAL: Negative ion based neutral beam injection

    NASA Astrophysics Data System (ADS)

    Hemsworth, R. S.

    2006-06-01

    It is widely recognized that neutral beam injection (NBI), i.e. the injection of high energy, high power, beams of H or D atoms, is a flexible and reliable system that has been the main heating system on a large variety of fusion devices, and NBI has been chosen as one of the three heating schemes of the International Tokomak Reactor (ITER). To date, all the NBI systems but two have been based on the neutralization (in a simple gas target) of positive hydrogen or deuterium ions accelerated to <100 keV/nucleon. Above that energy the neutralization of positive ions falls to unacceptably low values, and higher energy neutral beams have to be created by the neutralization of accelerated negative ions (in a simple gas target), as this remains high (approx60%) up to >1 MeV/nucleon. Unfortunately H- and D- are difficult to create, and the very characteristic that makes them attractive, the ease with which the electron is detached from the ion, means that it is difficult to create high concentrations or fluxes of them, and it is difficult to avoid substantial, collisional, losses in the extraction and acceleration processes. However, there has been impressive progress in negative ion sources and accelerators over the past decade, as demonstrated by the two pioneering, operational, multi-megawatt, negative ion based, NBI systems at LHD (180 keV, H0) and JT-60U (500 keV, D0), both in Japan. Nevertheless, the system proposed for ITER represents a substantial technological challenge as an increase is required in beam energy, to 1 MeV, D0, accelerated ion (D-) current, to 40 A, accelerated current density, 200 A m-2 of D-, and pulse length, to 1 h. At the Fourth IAEA Technical Meeting on Negative Ion Based Neutral Beam Injectors, hosted by the Consorzio RFX, Padova, Italy, 9-11 May 2005, the status of the R&D aimed at the realization of the injectors for ITER was presented. Because of the importance of this development to the success of the ITER project, participants at that

  15. Self-induced steady-state magnetic field in the negative ion sources with localized rf power deposition

    SciTech Connect

    Shivarova, A.; Todorov, D. Lishev, St.

    2016-02-15

    The study is in the scope of a recent activity on modeling of SPIDER (Source for Production of Ions of Deuterium Extracted from RF plasma) which is under development regarding the neutral beam injection heating system of ITER. The regime of non-ambipolarity in the source, established before, is completed here by introducing in the model the steady state magnetic field, self-induced in the discharge due to the dc current flowing in it. Strong changes in the discharge structure are reported.

  16. Negative Halogen Ions for Fusion Applications

    SciTech Connect

    Grisham, L.R.; Kwan, J.W.; Hahto, S.K.; Hahto, S.T.; Leung, K.N.; Westenskow, G.

    2006-01-01

    Over the past quarter century, advances in hydrogen negative ion sources have extended the usable range of hydrogen isotope neutral beams to energies suitable for large magnetically confined fusion devices. Recently, drawing upon this experience, negative halogen ions have been proposed as an alternative to positive ions for heavy ion fusion drivers in inertial confinement fusion, because electron accumulation would be prevented in negative ion beams, and if desired, the beams could be photo-detached to neutrals. This paper reports the results of an experiment comparing the current density and beam emittance of Cl+ and Cl- extracted from substantially ion-ion plasmas with that of Ar+ extracted from an ordinary electron-ion plasma, all using the same source, extractor, and emittance scanner. At similar discharge conditions, the Cl- current was typically 85 – 90% of the positive chlorine current, with an e-/ Cl- ratio as low as seven without grid magnets. The Cl- was as much as 76% of the Ar+ current from a discharge with the same RF drive. The minimum normalized beam emittance and inferred ion temperatures of Cl+, Cl-, and Ar+ were all similar, so the current density and optical quality of Cl- appear as suitable for heavy ion fusion driver applications as a positive noble gas ion of similar mass. Since F, I, and Br should all behave similarly in an ion source, they should also be suitable as driver beams.

  17. Cavity Ring-Down System for Density Measurement of Negative Hydrogen Ion on Negative Ion Source

    SciTech Connect

    Nakano, Haruhisa; Tsumori, Katsuyoshi; Nagaoka, Kenichi; Shibuya, Masayuki; Kisaki, Masashi; Ikeda, Katsunori; Osakabe, Masaki; Kaneko, Osamu; Asano, Eiji; Kondo, Tomoki; Sato, Mamoru; Komada, Seiji; Sekiguchi, Haruo; Takeiri, Yasuhiko; Fantz, Ursel

    2011-09-26

    A Cavity Ring-Down (CRD) system was applied to measure the density of negative hydrogen ion (H{sup -}) in vicinity of extraction surface in the H{sup -} source for the development of neutral beam injector on Large Helical Device (LHD). The density measurement with sampling time of 50 ms was carried out. The measured density with the CRD system is relatively good agreement with the density evaluated from extracted beam-current with applying a similar relation of positive ion sources. In cesium seeded into ion-source plasma, the linearity between an arc power of the discharge and the measured density with the CRD system was observed. Additionally, the measured density was proportional to the extracted beam current. These characteristics indicate the CRD system worked well for H{sup -} density measurement in the region of H{sup -} and extraction.

  18. Negative and positive cesium ion studies

    NASA Technical Reports Server (NTRS)

    Kuehn, D. G.; Sutliff, D. E.; Chanin, L. M.

    1978-01-01

    Mass spectrometric analyses have been performed on the positive and negative species from discharges in Cs, He-Cs, and He-H2-Cs mixtures. Sampling was conducted through the electrodes of normal glow discharges and from close-spaced heated-cathode conditions, which approximate a cesium thermionic converter. No negative Cs ions were observed for Cs pressures less than .01 torr. Identified species included Cs(+), Cs2(+), Cs(-), and what appeared to be multiply charged ions. Low-mass negative and positive ions attributed to H2 were observed when an He-H2 mixture was also present in the discharge region.

  19. An advanced negative hydrogen ion source

    SciTech Connect

    Goncharov, Alexey A. Dobrovolsky, Andrey N.; Goretskii, Victor P.

    2016-02-15

    The results of investigation of emission productivity of negative particles source with cesiated combined discharge are presented. A cylindrical beam of negative hydrogen ions with density about 2 A/cm{sup 2} in low noise mode on source emission aperture is obtained. The total beam current values are up to 200 mA for negative hydrogen ions and up to 1.5 A for all negative particles with high divergence after source. The source has simple design and can produce stable discharge with low level of oscillation.

  20. Negative electrodes for Na-ion batteries.

    PubMed

    Dahbi, Mouad; Yabuuchi, Naoaki; Kubota, Kei; Tokiwa, Kazuyasu; Komaba, Shinichi

    2014-08-07

    Research interest in Na-ion batteries has increased rapidly because of the environmental friendliness of sodium compared to lithium. Throughout this Perspective paper, we report and review recent scientific advances in the field of negative electrode materials used for Na-ion batteries. This paper sheds light on negative electrode materials for Na-ion batteries: carbonaceous materials, oxides/phosphates (as sodium insertion materials), sodium alloy/compounds and so on. These electrode materials have different reaction mechanisms for electrochemical sodiation/desodiation processes. Moreover, not only sodiation-active materials but also binders, current collectors, electrolytes and electrode/electrolyte interphase and its stabilization are essential for long cycle life Na-ion batteries. This paper also addresses the prospect of Na-ion batteries as low-cost and long-life batteries with relatively high-energy density as their potential competitive edge over the commercialized Li-ion batteries.

  1. Negative hydrogen ions in a linear helicon plasma device

    NASA Astrophysics Data System (ADS)

    Corr, Cormac; Santoso, Jesse; Samuell, Cameron; Willett, Hannah; Manoharan, Rounak; O'Byrne, Sean

    2015-09-01

    Low-pressure negative ion sources are of crucial importance to the development of high-energy (>1 MeV) neutral beam injection systems for the ITER experimental tokamak device. Due to their high power coupling efficiency and high plasma densities, helicon devices may be able to reduce power requirements and potentially remove the need for caesium. In helicon sources, the RF power can be coupled efficiently into the plasma and it has been previously observed that the application of a small magnetic field can lead to a significant increase in the plasma density. In this work, we investigate negative ion dynamics in a high-power (20 kW) helicon plasma source. The negative ion fraction is measured by probe-based laser photodetachment, electron density and temperature are determined by a Langmuir probe and tuneable diode laser absorption spectroscopy is used to determine the density of the H(n = 2) excited atomic state and the gas temperature. The negative ion density and excited atomic hydrogen density display a maximum at a low applied magnetic field of 3 mT, while the electron temperature displays a minimum. The negative ion density can be increased by a factor of 8 with the application of the magnetic field. Spatial and temporal measurements will also be presented. The Australian Research Grants Council is acknowledged for funding.

  2. Negative Ions for Emerging Interdisciplinary Applications

    NASA Astrophysics Data System (ADS)

    Guharay, Samar K.

    2011-09-01

    In many applications related to ion beam-materials interactions negative ions are particularly desirable due to its merit to yield a very low surface charge-up voltage, ˜ a few volts, for both electrically isolated surfaces and insulators. Some important applications pertaining to ion beam-material interactions include surface analysis by secondary ion mass spectrometry (SIMS), voltage-contrast microscopy for semiconductor device inspection, materials processing, and ion beam lithography. These applications primarily require vacuum environments. On the other hand, a distinct area of activities constitutes formation of ions and ion transport in ambient environmental conditions, i.e., at atmospheric pressures. In this context, ion mobility spectrometry (IMS) is an important analytical device that uses negative ions and operates at ambient conditions. IMS is widely used in both physical and biological sciences including monitoring environmental conditions, security screening and disease detection. This article highlights several critical issues related to the ionization sources and ion transport in IMS. Additionally, the critical issues related to ion sources, transport and focusing are discussed in the context of SIMS with sub-micrometer spatial resolution.

  3. Surface Production of Negative Hydrogen Ions.

    DTIC Science & Technology

    2014-09-26

    Identify by block number) -ii -"Measurements of sputtering of adsorbed hydrogen by cesium ion bombardment -m r -J have been completed. The temperature...of the desorbed negative hydrogen ions - Ad is about 0.5 percent of the bombarding energy. An experiment for studying bombardment with cesium and...hydrogen ions has been constructed. Formation of cesium coverage due to cesium bombardment of a molybdenum target has been studied. Cesium coverage is

  4. Production of negative hydrogen and deuterium ions in microwave-driven ion sources.

    SciTech Connect

    Spence, D.

    1998-09-11

    The authors report progress they have made in the production of negative hydrogen and deuterium atomic ions in magnetically-confined microwave-driven (2.45 GHz) ion sources. The influence of source surface material, microwave power, source gas pressure and magnetic field configuration on the resulting ion current is discussed. Results strongly suggest that, at least in the source, vibrationally excited molecular hydrogen, the precursor to atomic negative ion production, is produced via a surface mechanism suggested by Hall et al. rather than via a gas phase reaction as is generally believed to be the case in most ion sources.

  5. Negative hydrogen ion yields at plasma grid surface in a negative hydrogen ion source

    SciTech Connect

    Wada, M.; Kenmotsu, T.; Sasao, M.

    2015-04-08

    Negative hydrogen (H{sup −}) ion yield from the plasma grid due to incident hydrogen ions and neutrals has been evaluated with the surface collision cascade model, ACAT (Atomic Collision in Amorphous Target) coupled to a negative surface ionization models. Dependence of negative ion fractions upon the velocity component normal to the surface largely affect the calculation results of the final energy and angular distributions of the H{sup −} ions. The influence is particularly large for H{sup −} ions desorbed from the surface due to less than several eV hydrogen particle implact. The present calculation predicts that H{sup −} ion yield can be maximized by setting the incident angle of hydrogen ions and neutrals to be 65 degree. The Cs thickness on the plasma grid should also affect the yields and mean energies of surface produced H{sup −} ions by back scattering and ion induced desorption processes.

  6. Negative hydrogen ion yields at plasma grid surface in a negative hydrogen ion source

    NASA Astrophysics Data System (ADS)

    Wada, M.; Kenmotsu, T.; Sasao, M.

    2015-04-01

    Negative hydrogen (H-) ion yield from the plasma grid due to incident hydrogen ions and neutrals has been evaluated with the surface collision cascade model, ACAT (Atomic Collision in Amorphous Target) coupled to a negative surface ionization models. Dependence of negative ion fractions upon the velocity component normal to the surface largely affect the calculation results of the final energy and angular distributions of the H- ions. The influence is particularly large for H- ions desorbed from the surface due to less than several eV hydrogen particle implact. The present calculation predicts that H- ion yield can be maximized by setting the incident angle of hydrogen ions and neutrals to be 65 degree. The Cs thickness on the plasma grid should also affect the yields and mean energies of surface produced H- ions by back scattering and ion induced desorption processes.

  7. Generation of intense negative ion beams

    NASA Technical Reports Server (NTRS)

    Chutjian, Ara (Inventor); Orient, Otto J. (Inventor); Aladzhadzhyan, Samuel H. (Inventor)

    1987-01-01

    An electron gun is used with a mirror electrostatic field to produce zero or near zero velocity electrons by forming a turning point in their trajectories. A gas capable of attaching zero or near zero velocity is introduced at this turning point, and negative ions are produced by the attachment or dissociative attachment process. Operation may be continuous or pulsed. Ions thus formed are extracted by a simple lens system and suitable biasing of grids.

  8. Negative Electrodes for Li-Ion Batteries

    SciTech Connect

    Kinoshita, Kim; Zaghib, Karim

    2001-10-01

    Graphitized carbons have played a key role in the successful commercialization of Li-ion batteries. The physicochemical properties of carbon cover a wide range; therefore identifying the optimum active electrode material can be time consuming. The significant physical properties of negative electrodes for Li-ion batteries are summarized, and the relationship of these properties to their electrochemical performance in nonaqueous electrolytes, are discussed in this paper.

  9. The production and destruction of negative ions

    SciTech Connect

    Pegg, D.J.

    1993-01-01

    Single photon absorption-single electron detachment from few-electron atomic negative ions was studied. A crossed beam apparatus is being used to perform energy- and angle-resolved photoelectron spectroscopic measurements following photodetachment. Forward-directed electrons were collected and energy analyzed. The kinetic energies and yields of the photoelectrons were obtained by fitting the spectral peaks to Gaussian functions. Electron affinities, asymmetry parameters and cross sections are determined from these measurements. A ratio method in which the cross section for the ion of interest is measured relative to that of a reference ion was used. The study of the photodetachment of Li[sup [minus

  10. Negative ion sound solitary waves revisited

    NASA Astrophysics Data System (ADS)

    Cairns, R. A.; Cairns

    2013-12-01

    Some years ago, a group including the present author and Padma Shukla showed that a suitable non-thermal electron distribution allows the formation of ion sound solitary waves with either positive or negative density perturbations, whereas with Maxwellian electrons only a positive density perturbation is possible. The present paper discusses the qualitative features of this distribution allowing the negative waves and shared with suitable two-temperature distributions.

  11. Modeling of negative ion transport in a plasma source

    NASA Astrophysics Data System (ADS)

    Riz, David; Paméla, Jérôme

    1998-08-01

    A code called NIETZSCHE has been developed to simulate the negative ion transport in a plasma source, from their birth place to the extraction holes. The ion trajectory is calculated by numerically solving the 3-D motion equation, while the atomic processes of destruction, of elastic collision H-/H+ and of charge exchange H-/H0 are handled at each time step by a Monte-Carlo procedure. This code can be used to calculate the extraction probability of a negative ion produced at any location inside the source. Calculations performed with NIETZSCHE have allowed to explain, either quantitatively or qualitatively, several phenomena observed in negative ion sources, such as the isotopic H-/D- effect, and the influence of the plasma grid bias or of the magnetic filter on the negative ion extraction. The code has also shown that in the type of sources contemplated for ITER, which operate at large arc power densities (>1 W cm-3), negative ions can reach the extraction region provided if they are produced at a distance lower than 2 cm from the plasma grid in the case of «volume production» (dissociative attachment processes), or if they are produced at the plasma grid surface, in the vicinity of the extraction holes.

  12. Metal negative ion beam extraction from a radio frequency ion source

    SciTech Connect

    Kanda, S.; Yamada, N.; Kasuya, T.; Romero, C. F. P.; Wada, M.

    2015-04-08

    A metal ion source of magnetron magnetic field geometry has been designed and operated with a Cu hollow target. Radio frequency power at 13.56 MHz is directly supplied to the hollow target to maintain plasma discharge and induce self-bias to the target for sputtering. The extraction of positive and negative Cu ion beams have been tested. The ion beam current ratio of Cu{sup +} to Ar{sup +} has reached up to 140% when Ar was used as the discharge support gas. Cu{sup −} ion beam was observed at 50 W RF discharge power and at a higher Ar gas pressure in the ion source. Improvement of poor RF power matching and suppression of electron current is indispensable for a stable Cu{sup −} ion beam production from the source.

  13. Improvement of JT-60U Negative Ion Source Performance

    SciTech Connect

    L.R. Grisham; M. Kuriyama; M. Kawai; T. Itoh; N. Umeda; JT-60U Team

    2000-11-15

    The negative ion neutral beam system now operating on JT-60U was the first application of negative ion technology to the production of beams of high current and power for conversion to neutral beams, and has successfully demonstrated the feasibility of negative ion beam heating systems for ITER and future tokamak reactors [1, 2]. It also demonstrated significant electron heating[3] and high current drive efficiency in JT-60U[4]. Because this was such a large advance in the state of the art with respect to all system parameters, many new physical processes appeared during the earlier phases of the beam injection experiments. We have explored the physical mechanisms responsible for these processes, and implemented solutions for some of them, in particular excessive beam stripping, the secular dependence of the arc and beam parameters, and nonuniformity of the plasma illuminating the beam extraction grid. This has reduced the percentage of beam heat loading on the downstream grids by roug hly a third, and permitted longer beam pulses at higher powers. Progress is being made in improving the negative ion current density, and in coping with the sensitivity of the cesium in the ion sources to oxidation by tiny air or water leaks, and the cathode operation is being altered.

  14. Reversal ion source - A new source of negative ion beams

    NASA Technical Reports Server (NTRS)

    Orient, O. J.; Chutjian, A.; Alajajian, S. H.

    1985-01-01

    A new type of ion source utilizing beams of electrons and target molecules, rather than a diffuse, volume plasma, is described. The source utilizes an electrostatic electron 'mirror' which reverses trajectories in an electron beam, producing electrons at their turning point having a distribution of velocities centered at zero velocity. A gas which attaches zero-velocity electrons is introduced at this turning point. Negative ions are produced by an attachment or dissociative attachment process. For many of the thermal electron-attaching molecules the cross sections can be quite large, varying as the inverse square root of the electron energy or just the s-wave threshold law. The efficiency and current density of the ion source for production of Cl(-) through the large, thermal energy attachment process is estimated. It is argued that the source can be used for the production of negative ions through attachment resonances located at higher energies as well.

  15. Negative hydrogen ion production in a helicon plasma source

    SciTech Connect

    Santoso, J. Corr, C. S.; Manoharan, R.; O'Byrne, S.

    2015-09-15

    In order to develop very high energy (>1 MeV) neutral beam injection systems for applications, such as plasma heating in fusion devices, it is necessary first to develop high throughput negative ion sources. For the ITER reference source, this will be realised using caesiated inductively coupled plasma devices, containing either hydrogen or deuterium discharges, operated with high rf input powers (up to 90 kW per driver). It has been suggested that due to their high power coupling efficiency, helicon devices may be able to reduce power requirements and potentially obviate the need for caesiation due to the high plasma densities achievable. Here, we present measurements of negative ion densities in a hydrogen discharge produced by a helicon device, with externally applied DC magnetic fields ranging from 0 to 8.5 mT at 5 and 10 mTorr fill pressures. These measurements were taken in the magnetised plasma interaction experiment at the Australian National University and were performed using the probe-based laser photodetachment technique, modified for the use in the afterglow of the plasma discharge. A peak in the electron density is observed at ∼3 mT and is correlated with changes in the rf power transfer efficiency. With increasing magnetic field, an increase in the negative ion fraction from 0.04 to 0.10 and negative ion densities from 8 × 10{sup 14 }m{sup −3} to 7 × 10{sup 15 }m{sup −3} is observed. It is also shown that the negative ion densities can be increased by a factor of 8 with the application of an external DC magnetic field.

  16. Negative hydrogen ion production in a helicon plasma source

    NASA Astrophysics Data System (ADS)

    Santoso, J.; Manoharan, R.; O'Byrne, S.; Corr, C. S.

    2015-09-01

    In order to develop very high energy (>1 MeV) neutral beam injection systems for applications, such as plasma heating in fusion devices, it is necessary first to develop high throughput negative ion sources. For the ITER reference source, this will be realised using caesiated inductively coupled plasma devices, containing either hydrogen or deuterium discharges, operated with high rf input powers (up to 90 kW per driver). It has been suggested that due to their high power coupling efficiency, helicon devices may be able to reduce power requirements and potentially obviate the need for caesiation due to the high plasma densities achievable. Here, we present measurements of negative ion densities in a hydrogen discharge produced by a helicon device, with externally applied DC magnetic fields ranging from 0 to 8.5 mT at 5 and 10 mTorr fill pressures. These measurements were taken in the magnetised plasma interaction experiment at the Australian National University and were performed using the probe-based laser photodetachment technique, modified for the use in the afterglow of the plasma discharge. A peak in the electron density is observed at ˜3 mT and is correlated with changes in the rf power transfer efficiency. With increasing magnetic field, an increase in the negative ion fraction from 0.04 to 0.10 and negative ion densities from 8 × 1014 m-3 to 7 × 1015 m-3 is observed. It is also shown that the negative ion densities can be increased by a factor of 8 with the application of an external DC magnetic field.

  17. Modeling of negative ion transport in a plasma source (invited)

    NASA Astrophysics Data System (ADS)

    Riz, David; Paméla, Jérôme

    1998-02-01

    A code called NIETZSCHE has been developed to simulate the negative ion transport in a plasma source, from their birth place to the extraction holes. The H-/D- trajectory is calculated by numerically solving the 3D motion equation, while the atomic processes of destruction, of elastic collision with H+/D+ and of charge exchange with H0/D0 are handled at each time step by a Monte Carlo procedure. This code can be used to calculate the extraction probability of a negative ion produced at any location inside the source. Calculations performed with NIETZSCHE have been allowed to explain, either quantitatively or qualitatively, several phenomena observed in negative ion sources, such as the isotopic H-/D- effect, and the influence of the plasma grid bias or of the magnetic filter on the negative ion extraction. The code has also shown that, in the type of sources contemplated for ITER, which operate at large arc power densities (>1 W cm-3), negative ions can reach the extraction region provided they are produced at a distance lower than 2 cm from the plasma grid in the case of volume production (dissociative attachment processes), or if they are produced at the plasma grid surface, in the vicinity of the extraction holes.

  18. Negative ion chemistry in Titan's upper atmosphere

    NASA Astrophysics Data System (ADS)

    Vuitton, V.; Lavvas, P.; Yelle, R. V.; Wellbrock, A.; Lewis, G. R.; Coates, A.; Thissen, R.; Dutuit, O.

    2008-09-01

    In the upper part of atmospheres lies the ionosphere, a region of particular interest for planetary science, because it provides the link between the neutral atmosphere, and the ionizing processes from outer space. On Titan, it is created by the interaction of solar ultraviolet radiation and magnetospheric electrons with the main atmospheric constituents, N2 and CH4. Cassini has revealed that an extremely complex chemistry occurs in Titan's ionosphere. The INMS mass spectrometer detected positively charged hydrocarbons and nitrogen-bearing species with a charge-to-mass ratio (m/z) up to 100 amu [1]. In 2007, the Electron Spectrometer (ELS), one of the sensors making up the Cassini Plasma Spectrometer (CAPS) revealed the existence of numerous negative ions in Titan's upper atmosphere [2]. The data showed evidence for negatively charged ions with m/z up to 10,000 amu and at lower m/z for two distinct peaks below 50 amu, corresponding to a total density of ~200 cm-3, giving an anion to cation ratio of ~0.1. This detection happened almost simultaneously with the surprising discovery of four negative ions in the interstellar medium: C4H-, C6H-, C8H- and C3N- [3; 4; 5; 6; 7]. The possible presence of negative ions in Titan's upper atmosphere had only been briefly discussed before the Cassini-Huygens mission. Three-body electron attachment to radicals or collisional charging of aerosols had been suggested as a source of negatively charged species. Because the first process is negligible at high altitude (neutral densities lower than 1015 cm-3) and because aerosols were not expected above ~500 km, ionospheric models considered the presence of negatively charged species to be highly unlikely. However, the observations clearly show that Titan has the most complex ionosphere of the Solar System with an intense chemistry, leading to an increase of molecular size. By analyzing the optical properties of the detached haze layer observed at 520 km in Titan's mesosphere, Lavvas et

  19. Negative ion source with external RF antenna

    DOEpatents

    Leung, Ka-Ngo; Hahto, Sami K.; Hahto, Sari T.

    2007-02-13

    A radio frequency (RF) driven plasma ion source has an external RF antenna, i.e. the RF antenna is positioned outside the plasma generating chamber rather than inside. The RF antenna is typically formed of a small diameter metal tube coated with an insulator. An external RF antenna assembly is used to mount the external RF antenna to the ion source. The RF antenna tubing is wound around the external RF antenna assembly to form a coil. The external RF antenna assembly is formed of a material, e.g. quartz, which is essentially transparent to the RF waves. The external RF antenna assembly is attached to and forms a part of the plasma source chamber so that the RF waves emitted by the RF antenna enter into the inside of the plasma chamber and ionize a gas contained therein. The plasma ion source is typically a multi-cusp ion source. A converter can be included in the ion source to produce negative ions.

  20. Density trends of negative ions at Titan

    NASA Astrophysics Data System (ADS)

    Wellbrock, A.; Coates, A. J.; Jones, G. H.; Arridge, C. S.; Lewis, G.; Sittler, E. C.; Young, D. T.

    2012-12-01

    The Electron Spectrometer part of the Cassini Plasma Spectrometer (CAPS-ELS) has revealed the existence of negative ions in Titan's ionosphere (Coates et al, 2007, Waite et al, 2007). These are observed during every encounter when the instrument points in the ram direction at altitudes between 950 and 1400 km. The heaviest ions observed so far have masses up to 13 800 amu/q. This suggests that complex hydrocarbon and nitrile chemical processes take place in Titan's upper atmosphere, probably playing a role in haze formation. Even heavier particles such as tholins can form which fall to lower altitudes and build up on Titan's surface (Coates et al., 2009). Coates et al. (2009) discussed trends in the highest masses observed with solar zenith angle (SZA), altitude and latitude. We are extending this study to density trends of different masses. With data from over 34 encounters and taking advantage of an increase in the duty cycle of measurements during recent flybys we have accumulated a large negative ion database. Groups of masses can be identified because recurrent peaks are observed in the mass-per-charge spectra of different encounters. We have updated these mass groups according to the spectra including the most recent flybys. This includes a heavy group of 625 amu/q and above. We investigate the effects of different controlling parameters such as altitude, solar zenith angle, latitude and possible seasonal effects. The aim of this study is to help constrain the chemical formation and destruction processes of negative ions in Titan's ionosphere. By studying SZA trends we can for example learn about whether nightside reactions or photochemical reactions yield higher densities for the different groups. We present the results and discuss their implications. For instance, the heaviest mass group (>625 amu/q) negative ions are only present at altitudes below 1100 km. Densities of this mass group are highest on the nightside however there are some moderate densities

  1. Negative ion source with low temperature transverse divergence optical system

    DOEpatents

    Whealton, J.H.; Stirling, W.L.

    1985-03-04

    A negative ion source is provided which has extremely low transverse divergence as a result of a unique ion focusing system in which the focal line of an ion beam emanating from an elongated, concave converter surface is outside of the ion exit slit of the source and the path of the exiting ions. The beam source operates with a minimum ion temperature which makes possible a sharply focused (extremely low transverse divergence) ribbon like negative ion beam.

  2. Negative ion source with low temperature transverse divergence optical system

    DOEpatents

    Whealton, John H.; Stirling, William L.

    1986-01-01

    A negative ion source is provided which has extremely low transverse divergence as a result of a unique ion focusing system in which the focal line of an ion beam emanating from an elongated, concave converter surface is outside of the ion exit slit of the source and the path of the exiting ions. The beam source operates with a minimum ion temperature which makes possible a sharply focused (extremely low transverse divergence) ribbon like negative ion beam.

  3. Ion collector design for an energy recovery test proposal with the negative ion source NIO1

    NASA Astrophysics Data System (ADS)

    Variale, V.; Cavenago, M.; Agostinetti, P.; Sonato, P.; Zanotto, L.

    2016-02-01

    Commercial viability of thermonuclear fusion power plants depends also on minimizing the recirculation power used to operate the reactor. The neutral beam injector (NBI) remains one of the most important method for plasma heating and control. For the future fusion power plant project DEMO, a NBI wall plug efficiency at least of 0.45 is required, while efficiency of present NBI project is about 0.25. The D- beam from a negative ion source is partially neutralized by a gas cell, which leaves more than 40% of energy in residual beams (D- and D+), so that an ion beam energy recovery system can significantly contribute to optimize efficiency. Recently, the test negative ion source NIO1 (60 keV, 9 beamlets with 15 mA H- each) has been designed and built at RFX (Padua) for negative ion production efficiency and the beam quality optimization. In this paper, a study proposal to use the NIO1 source also for a beam energy recovery test experiment is presented and a preliminary design of a negative ion beam collector with simulations of beam energy recovery is discussed.

  4. Ion collector design for an energy recovery test proposal with the negative ion source NIO1

    SciTech Connect

    Variale, V.; Cavenago, M.; Agostinetti, P.; Sonato, P.; Zanotto, L.

    2016-02-15

    Commercial viability of thermonuclear fusion power plants depends also on minimizing the recirculation power used to operate the reactor. The neutral beam injector (NBI) remains one of the most important method for plasma heating and control. For the future fusion power plant project DEMO, a NBI wall plug efficiency at least of 0.45 is required, while efficiency of present NBI project is about 0.25. The D{sup −} beam from a negative ion source is partially neutralized by a gas cell, which leaves more than 40% of energy in residual beams (D{sup −} and D{sup +}), so that an ion beam energy recovery system can significantly contribute to optimize efficiency. Recently, the test negative ion source NIO1 (60 keV, 9 beamlets with 15 mA H{sup −} each) has been designed and built at RFX (Padua) for negative ion production efficiency and the beam quality optimization. In this paper, a study proposal to use the NIO1 source also for a beam energy recovery test experiment is presented and a preliminary design of a negative ion beam collector with simulations of beam energy recovery is discussed.

  5. Ion collector design for an energy recovery test proposal with the negative ion source NIO1.

    PubMed

    Variale, V; Cavenago, M; Agostinetti, P; Sonato, P; Zanotto, L

    2016-02-01

    Commercial viability of thermonuclear fusion power plants depends also on minimizing the recirculation power used to operate the reactor. The neutral beam injector (NBI) remains one of the most important method for plasma heating and control. For the future fusion power plant project DEMO, a NBI wall plug efficiency at least of 0.45 is required, while efficiency of present NBI project is about 0.25. The D(-) beam from a negative ion source is partially neutralized by a gas cell, which leaves more than 40% of energy in residual beams (D(-) and D(+)), so that an ion beam energy recovery system can significantly contribute to optimize efficiency. Recently, the test negative ion source NIO1 (60 keV, 9 beamlets with 15 mA H(-) each) has been designed and built at RFX (Padua) for negative ion production efficiency and the beam quality optimization. In this paper, a study proposal to use the NIO1 source also for a beam energy recovery test experiment is presented and a preliminary design of a negative ion beam collector with simulations of beam energy recovery is discussed.

  6. Simulation Based on Negative ion pair Techniques of Electric propulsion In Satellite Mission Using Chlorine Gas

    NASA Astrophysics Data System (ADS)

    Bakkiyaraj, R.

    R.Bakkiyaraj,Assistant professor,Government college of Engineering ,Bargur,Tamilnadu. *C.Sathiyavel, PG Student and Department of Aeronautical Engineering/Branch of Avionics, PSN college of Engineering and Technology,Tirunelveli,India. Abstract: Ion propulsion rocket system is expected to become popular with the development of ion-ion pair techniques because of their stimulated of low propellant, Design of repulsive between negative ions with low electric power and high efficiency. A Negative ion pair of ion propulsion rocket system is proposed in this work .Negative Ion Based Rocket system consists of three parts 1.ionization chamber 2. Repulsion force and ion accelerator 3. Exhaust of Nozzle. The Negative ions from electro negatively gas are produced by attachment of the gas ,such as chlorine with electron emitted from a Electron gun ionization chamber. The formulate of large stable negative ion is achievable in chlorine gas with respect to electron affinity (∆E). When a neutral chlorine atom in the gaseous form picks up an electron to form a cl- ion, it releases energy of 349 kJ/mol or 3.6 eV/atom. It is said to have an electron affinity of -349 kJ/mol ,the negative sign indicating that energy is released during this process .The distance between negative ions pair is important for the evaluation of the rocket thrust and is also determined by the exhaust velocity of the propellant. The mass flow rate of ions is related to the ion beam current. Accelerate the Negative ions to a high velocity in the thrust vector direction with a significantly intense grids and the exhaust of negative ions through Nozzle. The simulation of the ion propulsion system has been carried out by MATLAB. By comparing the simulation results with the theoretical and previous results, we have found that the proposed method is achieved of thrust value with low electric power for simulating the ion propulsion rocket system

  7. Electron-less negative ion extraction from ion-ion plasmas

    SciTech Connect

    Rafalskyi, Dmytro; Aanesland, Ane

    2015-03-09

    This paper presents experimental results showing that continuous negative ion extraction, without co-extracted electrons, is possible from highly electronegative SF{sub 6} ion-ion plasma at low gas pressure (1 mTorr). The ratio between the negative ion and electron densities is more than 3000 in the vicinity of the two-grid extraction and acceleration system. The measurements are conducted by both magnetized and non-magnetized energy analyzers attached to the external grid. With these two analyzers, we show that the extracted negative ion flux is almost electron-free and has the same magnitude as the positive ion flux extracted and accelerated when the grids are biased oppositely. The results presented here can be used for validation of numerical and analytical models of ion extraction from ion-ion plasma.

  8. Cesium injection system for negative ion duoplasmatrons

    DOEpatents

    Kobayashi, Maasaki; Prelec, Krsto; Sluyters, Theodorus J

    1978-01-01

    Longitudinally extending, foraminous cartridge means having a cylindrical side wall forming one flat, circular, tip end surface and an opposite end; an open-ended cavity, and uniformly spaced orifices for venting the cavity through the side wall in the annulus of a plasma ring for uniformly ejecting cesium for coating the flat, circular, surface. To this end, the cavity is filled with a cesium containing substance and attached to a heater in a hollow-discharge duoplasmatron. By coating the flat circular surface with a uniform monolayer of cesium and locating it in an electrical potential well at the end of a hollow-discharge, ion duoplasmatron source of an annular hydrogen plasma ring, the negative hydrogen production from the duoplasmatron is increased. The negative hydrogen is produced on the flat surface of the cartridge and extracted by the electrical potential well along a trajectory coaxial with the axis of the plasma ring.

  9. Negative hydrogen ion sources for accelerators

    SciTech Connect

    Moehs, D.P.; Peters, J.; Sherman, J.; /Los Alamos

    2005-08-01

    A variety of H{sup -} ion sources are in use at accelerator laboratories around the world. A list of these ion sources includes surface plasma sources with magnetron, Penning and surface converter geometries as well as magnetic-multipole volume sources with and without cesium. Just as varied is the means of igniting and maintaining magnetically confined plasmas. Hot and cold cathodes, radio frequency, and microwave power are all in use, as well as electron tandem source ignition. The extraction systems of accelerator H{sup -} ion sources are highly specialized utilizing magnetic and electric fields in their low energy beam transport systems to produce direct current, as well as pulsed and/or chopped beams with a variety of time structures. Within this paper, specific ion sources utilized at accelerator laboratories shall be reviewed along with the physics of surface and volume H{sup -} production in regard to source emittance. Current research trends including aperture modeling, thermal modeling, surface conditioning, and laser diagnostics will also be discussed.

  10. Noise reduction in negative-ion quadrupole mass spectrometry

    DOEpatents

    Chastagner, Philippe

    1993-01-01

    A quadrupole mass spectrometer (QMS) system having an ion source, quadrupole mass filter, and ion collector/recorder system. A weak, transverse magnetic field and an electron collector are disposed between the quadrupole and ion collector. When operated in negative ion mode, the ion source produces a beam of primarily negatively-charged particles from a sample, including electrons as well as ions. The beam passes through the quadrupole and enters the magnetic field, where the electrons are deflected away from the beam path to the electron collector. The negative ions pass undeflected to the ion collector where they are detected and recorded as a mass spectrum.

  11. Noise reduction in negative-ion quadrupole mass spectrometry

    DOEpatents

    Chastagner, P.

    1993-04-20

    A quadrupole mass spectrometer (QMS) system is described having an ion source, quadrupole mass filter, and ion collector/recorder system. A weak, transverse magnetic field and an electron collector are disposed between the quadrupole and ion collector. When operated in negative ion mode, the ion source produces a beam of primarily negatively-charged particles from a sample, including electrons as well as ions. The beam passes through the quadrupole and enters the magnetic field, where the electrons are deflected away from the beam path to the electron collector. The negative ions pass undeflected to the ion collector where they are detected and recorded as a mass spectrum.

  12. Negative ion studies on the RF plasma device MAGPIE

    NASA Astrophysics Data System (ADS)

    Willett, Hannah; Santoso, Jesse; Corr, Cormac; Gibson, Kieran

    2016-10-01

    Neutral beam injection (NBI) systems provide both heating and current drive in tokamak fusion reactors. High energy (> 1 MeV) neutral beams are produced by neutralising accelerated ions, for which negative ions are used; the neutralisation cross section for positive ions becomes negligible at these energies. This requires very high throughput negative ion sources. Currently this is achieved using inductively coupled plasma sources, which incorporate caesium to improve the production rate. It has been proposed that helicon plasma sources could provide a more efficient, higher throughput method of producing negative ions for NBI, possibly even removing the need for caesium. We report on studies of the negative hydrogen ion population in the MAGPIE helicon device (Australian National University) under a variety of operating conditions. The probe-based laser photodetachment method and Langmuir probes are employed to estimate the negative hydrogen ion density throughout the device. Initial results support the viability of helicon-based negative ion sources.

  13. Models for Cometary Comae Containing Negative Ions

    NASA Technical Reports Server (NTRS)

    Cordiner, M. A.; Charnley, S. B.

    2012-01-01

    The presence of negative ions (anions) in cometary comae is known from Giotto mass spectrometry of IP/Halley. The anions O(-), OH(-), C(-), CH(-) and CN(-) have been detected, as well as unidentified anions with masses 22-65 and 85-110 amu [I]. Organic molecular anions such as C4H(-) and C6H(-) are known to have a significant impact on the charge balance of interstellar clouds and circumstellar envelopes and have been shown to act as catalysts for the gas phase synthesis of larger hydrocarbon molecules in the ISM, but their importance in cometary comae has not yet been fully explored. We present details of our new models for the chemistry of cometary comae that include atomic and molecular anions. We calculate the impact of these anions on the charge balance and examine their importance for cometary coma chemistry.

  14. Negative ion source with hollow cathode discharge plasma

    DOEpatents

    Hershcovitch, A.; Prelec, K.

    1980-12-12

    A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface is described. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

  15. Negative ion source with hollow cathode discharge plasma

    DOEpatents

    Hershcovitch, Ady; Prelec, Krsto

    1983-01-01

    A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

  16. Improvement of JT-60U negative ion source performance

    NASA Astrophysics Data System (ADS)

    Grisham, L. R.; Kuriyama, M.; Kawai, M.; Itoh, T.; Umeda, N.; JT-60U Team

    2001-05-01

    The several hundred keV neutral beamline which is now operating on JT-60U marks the first usage of negative ion sources to produce high power neutral beams. Because this was such a large advance in the state of the art with respect to all system parameters, many new physical processes appeared during the earlier phases of the beam injection experiments. The physical mechanisms responsible for these processes have been explored, and solutions have been implemented for some of them, in particular excessive beam stripping, the secular dependence of the arc and beam parameters, and the non-uniformity of the plasma illuminating the beam extraction grid. This has reduced the percentage of beam heat loading on the downstream grids by roughly a third and has permitted longer beam pulses at higher powers. Progress is being made in improving the negative ion current density and in coping with the sensitivity of the caesium in the ion sources to oxidation by tiny air or water leaks, and the cathode operation is being altered.

  17. Production of negative hydrogen ions on metal grids

    SciTech Connect

    Oohara, W.; Maetani, Y.; Takeda, Takashi; Takeda, Toshiaki; Yokoyama, H.; Kawata, K.

    2015-03-15

    Negative hydrogen ions are produced on a nickel grid with positive-ion irradiation. In order to investigate the production mechanism, a copper grid without the chemisorption of hydrogen atoms and positive helium ions without negative ionization are used for comparison. Positive hydrogen ions reflected on the metal surface obtain two electrons from the surface and become negatively ionized. It is found that the production yield of negative ions by desorption ionization of chemisorbed hydrogen atoms seems to be small, and the production is a minor mechanism.

  18. Threshold photodetachment spectroscopy of negative ions

    SciTech Connect

    Kitsopoulos, T.N.

    1991-12-01

    This thesis is concerned with the development and application of high resolution threshold photodetachment spectroscopy of negative ions. Chapter I deals with the principles of our photodetachment technique, and in chapter II a detailed description of the apparatus is presented. The threshold photodetachment spectra of I{sup {minus}}, and SH{sup {minus}}, presented in the last sections of chapter II, indicated that a resolution of 3 cm{sup {minus}1} can be achieved using our technique. In chapter III the threshold photodetachment spectroscopy study of the transition state region of I + HI and I + Di reactions is discussed. Our technique probes the transition state region directly, and the results of our study are the first unambiguous observations of reactive resonances in a chemical reaction. Chapters IV, V and VI are concerned with the spectroscopy of small silicon and carbon clusters. From our spectra we were able to assign electronic state energies and vibrational frequencies for the low lying electronics states of Si{sub n} (n=2,3,4), C{sub 5} and their corresponding anions.

  19. Investigations of negative and positive cesium ion species

    NASA Technical Reports Server (NTRS)

    Chanin, L. M.

    1978-01-01

    A direct test is provided of the hypothesis of negative ion creation at the anode or collector of a diode operating under conditions simulating a cesium thermionic converter. The experimental technique involves using direct ion sampling through the collector electrode with mass analysis using a quadrupole mass analyzer. Similar measurements are undertaken on positive ions extracted through the emitter electrode. Measurements were made on a variety of gases including pure cesium, helium-cesium mixtures and cesium-hydrogen as well as cesium-xenon mixtures. The gas additive was used primarily to aid in understanding the negative ion formation processes. Measurements were conducted using emitter (cathode) temperatures up to about 1000 F. The major negative ion identified through the collector was Cs(-) with minor negative ion peaks tentatively identified as H(-), H2(-), H3(-), He(-) and a mass 66. Positive ions detected were believed to be Cs(+), Cs2(+) and Cs3(+).

  20. Extraction of negative hydrogen ions from a compact 14 GHz microwave ion source

    SciTech Connect

    Wada, M.; Kasuya, T.; Nishida, T.; Kenmotsu, T.; Maeno, S.; Nishiura, M.; Shinto, K.; Yamaoka, H.

    2012-02-15

    A pair of permanent magnets has formed enough intensity to realize electron cyclotron resonance condition for a 14 GHz microwave in a 2 cm diameter 9 cm long alumina discharge chamber. A three-electrode extraction system assembled in a magnetic shielding has formed a stable beam of negative hydrogen ions (H{sup -}) in a direction perpendicular to the magnetic field. The measured H{sup -} current density was about 1 mA/cm{sup 2} with only 50 W of discharge power, but the beam intensity had shown saturation against further increase in microwave power. The beam current decreased monotonically against increasing pressure.

  1. Spectroscopy of transient neutral species via negative ion photoelectron spectroscopy

    SciTech Connect

    Weaver, A.

    1991-12-01

    Negative ion photoelectron spectroscopy has been used to study two types of transient neutral species: bound free radicals (NO{sub 2} and NO{sub 3}) and unstable neutral species ([IHI] and [FH{sub 2}]). The negative ion time-of-flight photoelectron spectrometer used for these experiments is described in detail.

  2. Spectroscopy of transient neutral species via negative ion photoelectron spectroscopy

    SciTech Connect

    Weaver, A.

    1991-12-01

    Negative ion photoelectron spectroscopy has been used to study two types of transient neutral species: bound free radicals (NO{sub 2} and NO{sub 3}) and unstable neutral species ((IHI) and (FH{sub 2})). The negative ion time-of-flight photoelectron spectrometer used for these experiments is described in detail.

  3. Observation of the negative ions: Ra[sup [minus

    SciTech Connect

    Zhao, X.; Nadeau, M.; Garwan, M.A.; Kilius, L.R.; Litherland, A.E. )

    1993-11-01

    The negative ions of the isotopes [sup 226]Ra, [sup 231]Pa, and [sup 244]Pu have been observed by means of accelerator mass spectrometry and their properties compared with the negative ions of Th and U. The electron affinities of all these elements have been estimated to be similar and greater than 50 meV.

  4. RF-Plasma Source Commissioning in Indian Negative Ion Facility

    NASA Astrophysics Data System (ADS)

    Singh, M. J.; Bandyopadhyay, M.; Bansal, G.; Gahlaut, A.; Soni, J.; Kumar, Sunil; Pandya, K.; Parmar, K. G.; Sonara, J.; Yadava, Ratnakar; Chakraborty, A. K.; Kraus, W.; Heinemann, B.; Riedl, R.; Obermayer, S.; Martens, C.; Franzen, P.; Fantz, U.

    2011-09-01

    The Indian program of the RF based negative ion source has started off with the commissioning of ROBIN, the inductively coupled RF based negative ion source facility under establishment at Institute for Plasma research (IPR), India. The facility is being developed under a technology transfer agreement with IPP Garching. It consists of a single RF driver based beam source (BATMAN replica) coupled to a 100 kW, 1 MHz RF generator with a self excited oscillator, through a matching network, for plasma production and ion extraction and acceleration. The delivery of the RF generator and the RF plasma source without the accelerator, has enabled initiation of plasma production experiments. The recent experimental campaign has established the matching circuit parameters that result in plasma production with density in the range of 0.5-1×1018/m3, at operational gas pressures ranging between 0.4-1 Pa. Various configurations of the matching network have been experimented upon to obtain a stable operation of the set up for RF powers ranging between 25-85 kW and pulse lengths ranging between 4-20 s. It has been observed that the range of the parameters of the matching circuit, over which the frequency of the power supply is stable, is narrow and further experiments with increased number of turns in the coil are in the pipeline to see if the range can be widened. In this paper, the description of the experimental system and the commissioning data related to the optimisation of the various parameters of the matching network, to obtain stable plasma of required density, are presented and discussed.

  5. Electron energy recovery system for negative ion sources

    DOEpatents

    Dagenhart, W.K.; Stirling, W.L.

    1979-10-25

    An electron energy recovery system for negative ion sources is provided. The system, employing crossed electric and magnetic fields, separates the electrons from the ions as they are extracted from the ion source plasma generator and before the ions are accelerated to their full energy. With the electric and magnetic fields oriented 90/sup 0/ to each other, the electrons remain at approximately the electrical potential at which they were generated. The electromagnetic forces cause the ions to be accelerated to the full accelerating supply voltage energy while being deflected through an angle of less than 90/sup 0/. The electrons precess out of the accelerating field region into an electron recovery region where they are collected at a small fraction of the full accelerating supply energy. It is possible, by this method, to collect > 90% of the electrons extracted along with the negative ions from a negative ion source beam at < 4% of full energy.

  6. Negative ions as a source of low energy neutral beams

    SciTech Connect

    Fink, J.H.

    1980-01-01

    Little consideration has been given to the impact of recent developments in negative ion source technology on the design of low energy neutral beam injectors. However, negative ion sources of improved operating efficiency, higher gas efficiency, and smaller beam divergence will lead to neutral deuterium injectors, operating at less than 100 keV, with better operating efficiencies and more compact layouts than can be obtained from positive ion systems.

  7. About the Extraction of Surface Produced Ions in Negative Ion Sources

    NASA Astrophysics Data System (ADS)

    Taccogna, Francesco; Minelli, Pierpaolo; Longo, Savino; Capitelli, Mario

    2011-09-01

    The enhancement of extracted negative ion current in cesiated sources is usually explained by the surface production of negative ions. In this contribution, the self-consistent production and transport of H- in the extraction region of a radio-frequency driven negative ion source is modelled by means of a parallel two-dimensional Particle-in-Cell/Monte Carlo Collision simulation. It is shown that the number of surface-produced negative ions extracted is regulated by a potential well developed in front of the plasma grid such that the extracted current does not proportionally increase with the flux of negative ions emitted at the surface.

  8. Experiments on Negative Ion Plasmas in a Q-Machine

    NASA Astrophysics Data System (ADS)

    An, Tao

    Three experiments on negative ion plasmas in the University of Iowa Q-machine IQ-2 are described in this thesis. In the Lower-Hybrid wave experiment, the low-frequency (ion-ion mode) waves are excited, waves propagate at a right angle to the magnetic field. The wave frequencies increase as the negative ion concentration increases, in agreement with the dispersion relation obtained from fluid theory. In the Kelvin-Helmholtz instability experiment, the negative ions have a generally destabilizing effect on the instability driven by a relative drift between ions in adjacent layers. However, for large negative ion concentrations, enhanced radial diffusion associated with the Kelvin-Helmholtz oscillations tends to have a stabilizing effect due to a "mixing" of ion flows in adjacent layer. In the diffusion experiment, the K^ {+} ions experience a displacement across the magnetic filed on the order of their gyroradius upon collision with a negative ion, leading to an enhancement in the rate of cross-field diffusion over that expected in the ordinary K^{+}/electron plasma.

  9. Study on space charge compensation in negative hydrogen ion beam

    SciTech Connect

    Zhang, A. L.; Chen, J. E.; Peng, S. X. Ren, H. T.; Zhang, T.; Zhang, J. F.; Xu, Y.; Guo, Z. Y.

    2016-02-15

    Negative hydrogen ion beam can be compensated by the trapping of ions into the beam potential. When the beam propagates through a neutral gas, these ions arise due to gas ionization by the beam ions. However, the high neutral gas pressure may cause serious negative hydrogen ion beam loss, while low neutral gas pressure may lead to ion-ion instability and decompensation. To better understand the space charge compensation processes within a negative hydrogen beam, experimental study and numerical simulation were carried out at Peking University (PKU). The simulation code for negative hydrogen ion beam is improved from a 2D particle-in-cell-Monte Carlo collision code which has been successfully applied to H{sup +} beam compensated with Ar gas. Impacts among ions, electrons, and neutral gases in negative hydrogen beam compensation processes are carefully treated. The results of the beam simulations were compared with current and emittance measurements of an H{sup −} beam from a 2.45 GHz microwave driven H{sup −} ion source in PKU. Compensation gas was injected directly into the beam transport region to modify the space charge compensation degree. The experimental results were in good agreement with the simulation results.

  10. A negative ion source test facility

    SciTech Connect

    Melanson, S.; Dehnel, M. Potkins, D.; Theroux, J.; Hollinger, C.; Martin, J.; Stewart, T.; Jackle, P.; Withington, S.; Philpott, C.; Williams, P.; Brown, S.; Jones, T.; Coad, B.

    2016-02-15

    Progress is being made in the development of an Ion Source Test Facility (ISTF) by D-Pace Inc. in collaboration with Buckley Systems Ltd. in Auckland, NZ. The first phase of the ISTF is to be commissioned in October 2015 with the second phase being commissioned in March 2016. The facility will primarily be used for the development and the commercialization of ion sources. It will also be used to characterize and further develop various D-Pace Inc. beam diagnostic devices.

  11. Time evolution of negative ion profile in a large cesiated negative ion source applicable to fusion reactors

    SciTech Connect

    Yoshida, M. Hanada, M.; Kojima, A.; Kashiwagi, M.; Umeda, N.; Hiratsuka, J.; Ichikawa, M.; Watanabe, K.; Grisham, L.R.; Tsumori, K.; Kisaki, M.

    2016-02-15

    To understand the physics of the cesium (Cs) recycling in the large Cs-seeded negative ion sources relevant to ITER and JT-60SA with ion extraction area of 45-60 cm × 110-120 cm, the time evolution of the negative ion profile was precisely measured in JT-60SA where the ion extraction area is longitudinally segmented into 5. The Cs was seeded from the oven at 180 °C to the ion source. After 1 g of Cs input, surface production of the negative ions appeared only in the central segment where a Cs nozzle was located. Up to 2 g of Cs, the negative ion profile was longitudinally expanded over full ion extraction area. The measured time evolution of the negative ion profile has the similar tendency of distribution of the Cs atoms that is calculated. From the results, it is suggested that Cs atom distribution is correlated with the formation of the negative ion profile.

  12. Production of intense negative hydrogen beams with polarized nuclei by selective neutralization of cold negative ions

    DOEpatents

    Hershcovitch, A.

    1984-02-13

    A process for selectively neutralizing H/sup -/ ions in a magnetic field to produce an intense negative hydrogen ion beam with spin polarized protons. Characteristic features of the process include providing a multi-ampere beam of H/sup -/ ions that are

  13. Negative ion-driven associated particle neutron generator

    SciTech Connect

    Antolak, A. J.; Leung, K. N.; Morse, D. H.; Donovan, D. C.; Chames, J. M.; Whaley, J. A.; Buchenauer, D. A.; Chen, A. X.; Hausladen, P. A.; Liang, F.

    2015-10-09

    We describe an associated particle neutron generator that employs a negative ion source to produce high neutron flux from a small source size. Furthermore, negative ions produced in an rf-driven plasma source are extracted through a small aperture to form a beam which bombards a positively biased, high voltage target electrode. Electrons co-extracted with the negative ions are removed by a permanent magnet electron filter. The use of negative ions enables high neutron output (100% atomic ion beam), high quality imaging (small neutron source size), and reliable operation (no high voltage breakdowns). Finally, the neutron generator can operate in either pulsed or continuous-wave (cw) mode and has been demonstrated to produce 106 D-D n/s (equivalent to similar to 108 D-T n/s) from a 1 mm-diameter neutron source size to facilitate high fidelity associated particle imaging.

  14. Negative ion-driven associated particle neutron generator

    NASA Astrophysics Data System (ADS)

    Antolak, A. J.; Leung, K. N.; Morse, D. H.; Donovan, D. C.; Chames, J. M.; Whaley, J. A.; Buchenauer, D. A.; Chen, A. X.; Hausladen, P. A.; Liang, F.

    2016-01-01

    An associated particle neutron generator is described that employs a negative ion source to produce high neutron flux from a small source size. Negative ions produced in an rf-driven plasma source are extracted through a small aperture to form a beam which bombards a positively biased, high voltage target electrode. Electrons co-extracted with the negative ions are removed by a permanent magnet electron filter. The use of negative ions enables high neutron output (100% atomic ion beam), high quality imaging (small neutron source size), and reliable operation (no high voltage breakdowns). The neutron generator can operate in either pulsed or continuous-wave (cw) mode and has been demonstrated to produce 106 D-D n/s (equivalent to ~108 D-T n/s) from a 1 mm-diameter neutron source size to facilitate high fidelity associated particle imaging.

  15. Negative Ions Enhance Survival of Membrane Protein Complexes

    NASA Astrophysics Data System (ADS)

    Liko, Idlir; Hopper, Jonathan T. S.; Allison, Timothy M.; Benesch, Justin L. P.; Robinson, Carol V.

    2016-06-01

    Membrane protein complexes are commonly introduced to the mass spectrometer solubilized in detergent micelles. The collisional activation used to remove the detergent, however, often causes protein unfolding and dissociation. As in the case for soluble proteins, electrospray in the positive ion mode is most commonly used for the study of membrane proteins. Here we show several distinct advantages of employing the negative ion mode. Negative polarity can yield lower average charge states for membrane proteins solubilized in saccharide detergents, with enhanced peak resolution and reduced adduct formation. Most importantly, we demonstrate that negative ion mode electrospray ionization (ESI) minimizes subunit dissociation in the gas phase, allowing access to biologically relevant oligomeric states. Together, these properties mean that intact membrane protein ions can be generated in a greater range of solubilizing detergents. The formation of negative ions, therefore, greatly expands the possibilities of using mass spectrometry on this intractable class of protein.

  16. Negative ion-driven associated particle neutron generator

    DOE PAGES

    Antolak, A. J.; Leung, K. N.; Morse, D. H.; ...

    2015-10-09

    We describe an associated particle neutron generator that employs a negative ion source to produce high neutron flux from a small source size. Furthermore, negative ions produced in an rf-driven plasma source are extracted through a small aperture to form a beam which bombards a positively biased, high voltage target electrode. Electrons co-extracted with the negative ions are removed by a permanent magnet electron filter. The use of negative ions enables high neutron output (100% atomic ion beam), high quality imaging (small neutron source size), and reliable operation (no high voltage breakdowns). Finally, the neutron generator can operate in eithermore » pulsed or continuous-wave (cw) mode and has been demonstrated to produce 106 D-D n/s (equivalent to similar to 108 D-T n/s) from a 1 mm-diameter neutron source size to facilitate high fidelity associated particle imaging.« less

  17. Volume production of negative ions in the reflex-type ion source

    SciTech Connect

    Jimbo, K.

    1982-06-01

    The production of negative hydrogen ions is investigated in the reflex-type negative ion source. The extracted negative hydrogen currents of 9.7 mA (100 mA/cm/sup 2/) for H/sup -/ and of 4.1 mA(42 mA/cm/sup 2/) for D/sup -/ are obtained continuously. The impurity is less than 1%. An isotope effect of negative ion production is observed.

  18. Discovery of heavy negative ions in Titan's ionosphere

    NASA Astrophysics Data System (ADS)

    Coates, A. J.; Crary, F. J.; Lewis, G. R.; Young, D. T.; Waite, J. H.; Sittler, E. C.

    2007-11-01

    Titan's ionosphere contains a rich positive ion population including organic molecules. Here, using CAPS electron spectrometer data from sixteen Titan encounters, we reveal the existence of negative ions. These ions, with densities up to ~100 cm-3, are in mass groups of 10-30, 30-50, 50-80, 80-110, 110-200 and 200+ amu/charge. During one low encounter, negative ions with mass per charge as high as 10,000 amu/q are seen. Due to their unexpectedly high densities at ~950 km altitude, these negative ions must play a key role in the ion chemistry and they may be important in the formation of organic-rich aerosols (tholins) eventually falling to the surface.

  19. Review of Negative Hydrogen Ion Sources

    DTIC Science & Technology

    1990-09-01

    250 mA/cm 2 Second Symposium (1980) BNL 51304, with reduced e/H" ratios. At high cesium levels, where extraction Third Symposium ( 1983 ) ABp Conf...Sym. on Ion Sources and Formation of Ion Beams, Typically the accelerator usage has stressed duty factor, Berkeley, LBL -3399 (1974) VIII-1. reliability...source and for low-duty usage the lifetime can be NS-30 ( 1983 ) 2743. many months to a year as witnessed by operating magnetrons. 13. H. S. Zhang, G.-G

  20. High current DC negative ion source for cyclotron

    NASA Astrophysics Data System (ADS)

    Etoh, H.; Onai, M.; Aoki, Y.; Mitsubori, H.; Arakawa, Y.; Sakuraba, J.; Kato, T.; Mitsumoto, T.; Hiasa, T.; Yajima, S.; Shibata, T.; Hatayama, A.; Okumura, Y.

    2016-02-01

    A filament driven multi-cusp negative ion source has been developed for proton cyclotrons in medical applications. In Cs-free operation, continuous H- beam of 10 mA and D- beam of 3.3 mA were obtained stably at an arc-discharge power of 3 kW and 2.4 kW, respectively. In Cs-seeded operation, H- beam current reached 22 mA at a lower arc power of 2.6 kW with less co-extracted electron current. The optimum gas flow rate, which gives the highest H- current, was 15 sccm in the Cs-free operation, while it decreased to 4 sccm in the Cs-seeded operation. The relationship between H- production and the design/operating parameters has been also investigated by a numerical study with KEIO-MARC code, which gives a reasonable explanation to the experimental results of the H- current dependence on the arc power.

  1. High current DC negative ion source for cyclotron

    SciTech Connect

    Etoh, H. Aoki, Y.; Mitsubori, H.; Arakawa, Y.; Sakuraba, J.; Kato, T.; Mitsumoto, T.; Hiasa, T.; Yajima, S.; Onai, M.; Hatayama, A.; Shibata, T.; Okumura, Y.

    2016-02-15

    A filament driven multi-cusp negative ion source has been developed for proton cyclotrons in medical applications. In Cs-free operation, continuous H{sup −} beam of 10 mA and D{sup −} beam of 3.3 mA were obtained stably at an arc-discharge power of 3 kW and 2.4 kW, respectively. In Cs-seeded operation, H{sup −} beam current reached 22 mA at a lower arc power of 2.6 kW with less co-extracted electron current. The optimum gas flow rate, which gives the highest H{sup −} current, was 15 sccm in the Cs-free operation, while it decreased to 4 sccm in the Cs-seeded operation. The relationship between H{sup −} production and the design/operating parameters has been also investigated by a numerical study with KEIO-MARC code, which gives a reasonable explanation to the experimental results of the H{sup −} current dependence on the arc power.

  2. Negative air ion effects on human performance and physiological condition.

    PubMed

    Buckalew, L W; Rizzuto, A P

    1984-08-01

    Beneficial effects of exposure to negative air ions have been suggested, to include improved performance, mood, attention, and physiological condition. Existing support is clouded by methodological problems of control and standardization in treatment and equipment. This study investigated effects of negative ions produced by a commercially marketed air purification device on grip magnitude, coding, motor dexterity, reaction time, tracking, pulse, blood pressure, and temperature. Two groups of 12 males were exposed to 6 continuous h of either negative or "normal" ion environments under a double blind condition. Repeated measures (0,3,6 h) on each variable were obtained. MANOVA applied to change scores revealed no differences between groups, and 0 vs. 3 and 0 vs. 6-h group differences showed no significant alteration in any measure. Negative ions generated by an air purification device were concluded to produce no general or specific alteration of cognitive or psychomotor performance or physiological condition.

  3. Cesium vapor thermionic converter anomalies arising from negative ion emission

    NASA Astrophysics Data System (ADS)

    Rasor, Ned S.

    2016-08-01

    Compelling experimental evidence is given that a longstanding limit encountered on cesium vapor thermionic energy converter performance improvement and other anomalies arise from thermionic emission of cesium negative ions. It is shown that the energy that characterizes thermionic emission of cesium negative ions is 1.38 eV and, understandably, is not the electron affinity 0.47 eV determined for the photodetachment threshold of the cesium negative ion. The experimental evidence includes measurements of collector work functions and volt-ampere characteristics in quasi-vacuum cesium vapor thermionic diodes, along with reinterpretation of the classic Taylor-Langmuir S-curve data on electron emission in cesium vapor. The quantitative effects of negative ion emission on performance in the ignited, unignited, and quasi-vacuum modes of cesium vapor thermionic converter operation are estimated.

  4. High brilliance negative ion and neutral beam source

    DOEpatents

    Compton, Robert N.

    1991-01-01

    A high brilliance mass selected (Z-selected) negative ion and neutral beam source having good energy resolution. The source is based upon laser resonance ionization of atoms or molecules in a small gaseous medium followed by charge exchange through an alkali oven. The source is capable of producing microampere beams of an extremely wide variety of negative ions, and milliampere beams when operated in the pulsed mode.

  5. Electron and Negative Ion Densities in C(2)F(6) and CHF(3) Containing Inductively Coupled Discharges

    SciTech Connect

    HEBNER,GREGORY A.; MILLER,PAUL A.

    1999-12-07

    Electron and negative ion densities have been measured in inductively coupled discharges containing C{sub 2}F{sub 6} and CHF{sub 3}. Line integrated electron density was determined using a microwave interferometer, negative ion densities were inferred using laser photodetachment spectroscopy, and electron temperature was determined using a Langmuir probe. For the range of induction powers, pressures and bias power investigated, the electron density peaked at 9 x 10{sup 12} cm{sup -2} (line-integrated) or approximately 9 x 10{sup 11} cm{sup -3}. The negative ion density peaked at approximately 1.3 x 10{sup 11} cm{sup -3}. A maximum in the negative ion density as a function of induction coil power was observed. The maximum is attributed to a power dependent change in the density of one or more of the potential negative ion precursor species since the electron temperature did not depend strongly on power. The variation of photodetachment with laser wavelength indicated that the dominant negative ion was F{sup -}. Measurement of the decay of the negative ion density in the afterglow of a pulse modulated discharge was used to determine the ion-ion recombination rate for CF{sub 4}, C{sub 2}F{sub 6} and CHF{sub 3} discharges.

  6. Field-Reversal Source for Negative Halogen Ions

    NASA Technical Reports Server (NTRS)

    Chutjian, A.; Orient, O. J.; Aladzhadzhyan, S. H.

    1987-01-01

    Large zero-energy electron-attachment cross sections result in intense ion beams. Concept for producing negative halogen ions takes advantage of large cross sections at zero kinetic energy for dissociative attachment of electrons to such halogen-containing gases as SF6, CFCI3, and CCI4.

  7. A negative ion model in the lower stratosphere

    NASA Astrophysics Data System (ADS)

    Kawamoto, H.; Ogawa, T.

    1985-12-01

    There are a number of problems in the electricity of the stratosphere at middle latitudes; e.g., the positive relation between the seasonal variations of negative polar conductivity and that of ozone density, the observed dependence of the daytime variation of conductivity on the solar zenith angle, and the interaction between the ions and aerosols, particularly the processes of the conversion from negative ions to the sulfate aerosols; e.g., ion-nucleation and the growth through multi-ion complexes. As a basic tool for investigating these problems, a negative ion chemical model was constructed in the altitude region of 15 to 30 km. Recently, the success of in situ mass analysis of stratospheric ions has revealed the nature of the most abundant ions in the stratosphere. Further, the height variations of negative ion composition between 15 and 34 km were obtained with the balloon-borne mass spectrometer by another researcher. A comparison of the calculated result with the observed result is given.

  8. A negative ion model in the lower stratosphere

    NASA Technical Reports Server (NTRS)

    Kawamoto, H.; Ogawa, T.

    1985-01-01

    There are a number of problems in the electricity of the stratosphere at middle latitudes; e.g., the positive relation between the seasonal variations of negative polar conductivity and that of ozone density, the observed dependence of the daytime variation of conductivity on the solar zenith angle, and the interaction between the ions and aerosols, particularly the processes of the conversion from negative ions to the sulfate aerosols; e.g., ion-nucleation and the growth through multi-ion complexes. As a basic tool for investigating these problems, a negative ion chemical model was constructed in the altitude region of 15 to 30 km. Recently, the success of in situ mass analysis of stratospheric ions has revealed the nature of the most abundant ions in the stratosphere. Further, the height variations of negative ion composition between 15 and 34 km were obtained with the balloon-borne mass spectrometer by another researcher. A comparison of the calculated result with the observed result is given.

  9. Negative thermal ion mass spectrometry of osmium, rhenium, and iridium

    NASA Technical Reports Server (NTRS)

    Creaser, R. A.; Papanastassiou, D. A.; Wasserburg, G. J.

    1991-01-01

    This paper describes a technique for obtaining, in a conventional surface ionization mass spectrometer, intense ion beams of negatively charged oxides of Os, Re, and Ir by thermal ionization. It is shown that the principal ion species of these ions are OsO3(-), ReO4(-), and IrO2(-), respectively. For Re-187/Os-187 studies, this technique offers the advantage of isotopic analyses without prior chemical separation of Re from Os.

  10. Study of the negative ion extraction mechanism from a double-ion plasma in negative ion sources

    SciTech Connect

    Goto, I.; Nishioka, S.; Hatayama, A.; Miyamoto, K.

    2015-04-08

    We have developed a 2D3V-PIC model of the extraction region, aiming to clarify the basic extraction mechanism of H{sup −} ions from the double-ion plasma in H{sup −} negative ion sources. The result shows the same tendency of the H{sup −} ion density n{sub H{sup −}} as that observed in the experiments, i.e.,n{sub H{sup −}} in the upstream region away from the plasma meniscus (H{sup −} emitting surface) has been reduced by applying the extraction voltage. At the same time, relatively slow temporal oscillation of the electric potential compared with the electron plasma frequency has been observed in the extraction region. Results of the systematic study using a 1D3V-PIC model with the uniform magnetic field confirm the result that the electrostatic oscillation is identified to be lower hybrid wave. The effect of this oscillation on the H{sup −} transport will be studied in the future.

  11. Role of positive ions on the surface production of negative ions in a fusion plasma reactor type negative ion source—Insights from a three dimensional particle-in-cell Monte Carlo collisions model

    SciTech Connect

    Fubiani, G.; Boeuf, J. P.

    2013-11-15

    Results from a 3D self-consistent Particle-In-Cell Monte Carlo Collisions (PIC MCC) model of a high power fusion-type negative ion source are presented for the first time. The model is used to calculate the plasma characteristics of the ITER prototype BATMAN ion source developed in Garching. Special emphasis is put on the production of negative ions on the plasma grid surface. The question of the relative roles of the impact of neutral hydrogen atoms and positive ions on the cesiated grid surface has attracted much attention recently and the 3D PIC MCC model is used to address this question. The results show that the production of negative ions by positive ion impact on the plasma grid is small with respect to the production by atomic hydrogen or deuterium bombardment (less than 10%)

  12. Improving efficiency of negative ion production in ion source with saddle antenna

    SciTech Connect

    Dudnikov, V. Johnson, R. P.; Murrey, S.; Pinnisi, T.; Piller, C.; Santana, M.; Stockli, M.; Welton, R.; Johnson, C.; Turvey, M.

    2014-02-15

    Extraction of negative ions from a saddle antenna radio-frequency surface plasma source is considered. Several versions of new plasma generators with different antennas and magnetic field configurations were tested in the smal Oak Ridge National Laboratory Spallation Neutron Source Test Stand. The efficiency of positive ion generation in plasma has been improved to 200 mA/cm{sup 2} kW from 2.5 mA/cm{sup 2} kW. A small oven was developed for cesiation by cesium compounds and alloy decomposition. After cesiation, a current of negative ions to the collector was increased from 1 mA to 10 mA with 1.5 kW RF power in the plasma and longitudinal magnetic field B{sub l} ∼ 250 G. The specific efficiency of H{sup −} production was increased to 20 mA/cm{sup 2} kW from 2.5 mA/cm{sup 2} kW.

  13. Improving efficiency of negative ion production in ion source with saddle antenna.

    PubMed

    Dudnikov, V; Johnson, R P; Murrey, S; Pinnisi, T; Piller, C; Santana, M; Stockli, M; Welton, R; Johnson, C; Turvey, M

    2014-02-01

    Extraction of negative ions from a saddle antenna radio-frequency surface plasma source is considered. Several versions of new plasma generators with different antennas and magnetic field configurations were tested in the smal Oak Ridge National Laboratory Spallation Neutron Source Test Stand. The efficiency of positive ion generation in plasma has been improved to 200 mA/cm(2) kW from 2.5 mA/cm(2) kW. A small oven was developed for cesiation by cesium compounds and alloy decomposition. After cesiation, a current of negative ions to the collector was increased from 1 mA to 10 mA with 1.5 kW RF power in the plasma and longitudinal magnetic field Bl ∼ 250 G. The specific efficiency of H(-) production was increased to 20 mA/cm(2) kW from 2.5 mA/cm(2) kW.

  14. Production of intense negative hydrogen beams with polarized nuclei by selective neutralization of negative ions

    DOEpatents

    Hershcovitch, Ady

    1987-01-01

    A process for selectively neutralizing H.sup.- ions in a magnetic field to produce an intense negative hydrogen ion beam with spin polarized protons. Characteristic features of the process include providing a multi-ampere beam of H.sup.- ions that are intersected by a beam of laser light. Photodetachment is effected in a uniform magnetic field that is provided around the beam of H.sup.- ions to spin polarize the H.sup.- ions and produce first and second populations or groups of ions, having their respective proton spin aligned either with the magnetic field or opposite to it. The intersecting beam of laser light is directed to selectively neutralize a majority of the ions in only one population, or given spin polarized group of H.sup.- ions, without neutralizing the ions in the other group thereby forming a population of H.sup.- ions each of which has its proton spin down, and a second group or population of H.sup.o atoms having proton spin up. Finally, the two groups of ions are separated from each other by magnetically bending the group of H.sup.- ions away from the group of neutralized ions, thereby to form an intense H.sup.- ion beam that is directed toward a predetermined objective.

  15. Negative Dielectric Constant Material Based on Ion Conducting Materials

    NASA Technical Reports Server (NTRS)

    Gordon, Keith L. (Inventor); Kang, Jin Ho (Inventor); Park, Cheol (Inventor); Lillehei, Peter T. (Inventor); Harrison, Joycelyn S. (Inventor)

    2014-01-01

    Metamaterials or artificial negative index materials (NIMs) have generated great attention due to their unique and exotic electromagnetic properties. One exemplary negative dielectric constant material, which is an essential key for creating the NIMs, was developed by doping ions into a polymer, a protonated poly(benzimidazole) (PBI). The doped PBI showed a negative dielectric constant at megahertz (MHz) frequencies due to its reduced plasma frequency and an induction effect. The magnitude of the negative dielectric constant and the resonance frequency were tunable by doping concentration. The highly doped PBI showed larger absolute magnitude of negative dielectric constant at just above its resonance frequency than the less doped PBI.

  16. Evaluation of negative ion distribution changes by image processing diagnostic

    SciTech Connect

    Ikeda, K. Nakano, H.; Tsumori, K.; Kisaki, M.; Nagaoka, K.; Tokuzawa, T.; Osakabe, M.; Takeiri, Y.; Kaneko, O.; Geng, S.

    2015-04-08

    Distributions of hydrogen Balmer-α (H{sub α}) intensity and its reduction behavior close to a plasma grid (PG) surface have been observed by a spectrally selective imaging system in an arc discharge type negative hydrogen ion source in National Institute for Fusion Science. H{sub α} reduction indicates a reduction of negative hydrogen ions because the mutual neutralization process between H{sup +} and H{sup −} ions causes the dominant excitation process for H{sub α} emission in the rich H{sup −} condition such as in ionic plasma. We observed a significant change in H{sub α} reduction distribution due to change in the bias voltage, which is used to suppress the electron influx. Small H{sub α} reduction in higher bias is likely because the production of negative ions is suppressed by the potential difference between the plasma and PG surface.

  17. Volume production of negative ions in the reflex type ion source

    SciTech Connect

    Jimbo, K.

    1982-01-01

    The production of negative hydrogen ions is investigated in the reflex-type negative ion source. The extracted negative hydrogen currents of 9.7 mA (100 mA/cm/sup 2/) for H/sup -/ and of 4.1 mA (42 mA/cm/sup 2/) for D/sup -/ are obtained continuously. The impurity is less then 1%. An isotope effect of negative ion production is observed. When anomalous diffusion in the positive column was found by Lehnert and Hoh (1960), it was pointed out that the large particle loss produced by anomalous diffusion is compensated by the large particle production inside the plasma, i.e., the plasma tries to maintain itself. The self-sustaining property of the plasma is applied to the reflex-type negative ion source. Anomalous diffusion was artificially encouraged by changing the radial electric field inside the reflex discharge. The apparent encouragement of negative ion diffusion by the increase of density fluctuation amplitude is observed. Twice as much negative ion current was obtained with the artificial encouragement as without. It is found from the quasilinear theory that the inwardly directed radial electric field destabilizes the plasma in the reflex-type ion source. The nonlinear theory based on Yoshikawa method (1962) is extended, and the anomalous diffusion coefficient in a weakly ionized plasma is obtained. The electrostatic sheath trap, which increases the confinement of negative ions in the reflex-type ion source, is also discussed.

  18. A future, intense source of negative hydrogen ions

    NASA Technical Reports Server (NTRS)

    Siefken, Hugh; Stein, Charles

    1994-01-01

    By directly heating lithium hydride in a vacuum, up to 18 micro-A/sq cm of negative hydrogen has been obtained from the crystal lattice. The amount of ion current extracted and analyzed is closely related to the temperature of the sample and to the rate at which the temperature is changed. The ion current appears to be emission limited and saturates with extraction voltage. For a fixed extraction voltage, the ion current could be maximized by placing a grid between the sample surface and the extraction electrode. Electrons accompanying the negative ions were removed by a magnetic trap. A Wein velocity filter was designed and built to provide definitive mass analysis of the extracted ion species. This technique when applied to other alkali hydrides may produce even higher intensity beams possessing low values of emittance.

  19. Maximizing Ion Current by Space Charge Neutralization using Negative Ions and Dust Particles

    SciTech Connect

    A. Smirnov; Y. Raitses; N.J. Fisch

    2005-01-25

    Ion current extracted from an ion source (ion thruster) can be increased above the Child-Langmuir limit if the ion space charge is neutralized. Similarly, the limiting kinetic energy density of the plasma flow in a Hall thruster might be exceeded if additional mechanisms of space charge neutralization are introduced. Space charge neutralization with high-mass negative ions or negatively charged dust particles seems, in principle, promising for the development of a high current or high energy density source of positive light ions. Several space charge neutralization schemes that employ heavy negatively charged particles are considered. It is shown that the proposed neutralization schemes can lead, at best, only to a moderate but nonetheless possibly important increase of the ion current in the ion thruster and the thrust density in the Hall thruster.

  20. Molecular and negative ion production by a standard electron cyclotron resonance ion source.

    PubMed

    Rácz, R; Biri, S; Juhász, Z; Sulik, B; Pálinkás, J

    2012-02-01

    Molecular and negative ion beams, usually produced in special ion sources, play an increasingly important role in fundamental and applied atomic physics. The ATOMKI-ECRIS is a standard ECR ion source, designed to provide highly charged ion (HCI) plasmas and beams. In the present work, H(-), O(-), OH(-), O(2)(-), C(-), C(60)(-) negative ions and H(2)(+), H(3)(+), OH(+), H(2)O(+), H(3)O(+), O(2)(+) positive molecular ions were generated in this HCI-ECRIS. Without any major modification in the source and without any commonly applied tricks (such as usage of cesium or magnetic filter), negative ion beams of several μA and positive molecular ion beams in the mA range were successfully obtained.

  1. Molecular and negative ion production by a standard electron cyclotron resonance ion source

    SciTech Connect

    Racz, R.; Biri, S.; Juhasz, Z.; Sulik, B.

    2012-02-15

    Molecular and negative ion beams, usually produced in special ion sources, play an increasingly important role in fundamental and applied atomic physics. The ATOMKI-ECRIS is a standard ECR ion source, designed to provide highly charged ion (HCI) plasmas and beams. In the present work, H{sup -}, O{sup -}, OH{sup -}, O{sub 2}{sup -}, C{sup -}, C{sub 60}{sup -} negative ions and H{sub 2}{sup +}, H{sub 3}{sup +}, OH{sup +}, H{sub 2}O{sup +}, H{sub 3}O{sup +}, O{sub 2}{sup +} positive molecular ions were generated in this HCI-ECRIS. Without any major modification in the source and without any commonly applied tricks (such as usage of cesium or magnetic filter), negative ion beams of several {mu}A and positive molecular ion beams in the mA range were successfully obtained.

  2. Development of multiampere negative ion sources

    SciTech Connect

    Alessi, J.; Hershcovitch, A.; Prelec, K.; Sluyters, T.

    1981-01-01

    The Neutral Beam Development Group at BNL is developing H-/D- surface plasma sources as part of a high energy neutral beam injector. Uncooled Penning and magnetron sources have operated at a maximum beam current of 1 A (10 ms pulses, Mk III) and a maximum pulse length of 200 ms (0.3 A, Mk IV). A magnetron source with focusing grooves on the cathode and an asymmetric anode-cathode geometry operates at a power efficiency of 8 kW/A and a 6% gas efficiency. As the next step, a water cooled magnetron, designed to give a steady state beam of 1 to 2 A, has been constructed. Experiments are in progress to test a modification of the magnetron which may significantly improve its performance. By injecting a sheet of plasma, produced by a highly gas efficient hollow cathode discharge, into a magnetron type anode-cathode geometry, we anticipate a reduction of the source operating pressure by at least three orders of magnitude. Initial experiments have given indications of H/sup -/ production. The next plasma injection experiment is designed to give a steady state beam of approx. = 1 A.

  3. Issues in the understanding of negative ion extraction for fusion

    NASA Astrophysics Data System (ADS)

    Boeuf, J. P.; Fubiani, G.; Garrigues, L.

    2016-08-01

    A number of recent papers have been devoted to the modeling of negative ion extraction using particle simulations but the published results are not entirely satisfactory and not fully consistent with experiments. Issues raised by the simulations concern the saturation of the negative ion current emitted from the caesiated plasma grid surface, its distribution along the surface, the shape of the meniscus formed around each grid aperture, the distribution and depth of the potential in the virtual cathode, and the profile of the extracted beamlet. These are important issues since they have direct impact on the properties of the extracted negative ion beam (intensity, brightness, aberration). In this paper we first summarize recently published model results that are unexpected and counter-intuitive since they predict that negative ions are extracted from regions of the grid that are directly exposed to the large extraction voltage (i.e. as in vacuum and without the need for a neutralizing background plasma). We then illustrate, with results from two-dimensional particle-in-cell Monte Carlo collision simulations, some regimes of negative ion extraction that are more consistent with the expected physics.

  4. Negative hydrogen ion beam extraction from an AC heated cathode driven Bernas-type ion source

    NASA Astrophysics Data System (ADS)

    Okano, Y.; Miyamoto, N.; Kasuya, T.; Wada, M.

    2015-04-01

    A plasma grid structure was installed to a Bernas-type ion source used for ion implantation equipment. A negative hydrogen (H-) ion beam was extracted by an AC driven ion source by adjusting the bias to the plasma grid. The extracted electron current was reduced by positively biasing the plasma grid, while an optimum plasma grid bias voltage for negative ion beam extraction was found to be positive 3 V with respect to the arc chamber. Source operations with AC cathode heating show extraction characteristics almost identical to that with DC cathode heating, except a minute increase in H- current at higher frequency of cathode heating current.

  5. Electron energy recovery system for negative ion sources

    DOEpatents

    Dagenhart, William K.; Stirling, William L.

    1982-01-01

    An electron energy recovery system for negative ion sources is provided. The system, employs crossed electric and magnetic fields to separate the electrons from ions as they are extracted from a negative ion source plasma generator and before the ions are accelerated to their full kinetic energy. With the electric and magnetic fields oriented 90.degree. to each other, the electrons are separated from the plasma and remain at approximately the electrical potential of the generator in which they were generated. The electrons migrate from the ion beam path in a precessing motion out of the ion accelerating field region into an electron recovery region provided by a specially designed electron collector electrode. The electron collector electrode is uniformly spaced from a surface of the ion generator which is transverse to the direction of migration of the electrons and the two surfaces are contoured in a matching relationship which departs from a planar configuration to provide an electric field component in the recovery region which is parallel to the magnetic field thereby forcing the electrons to be directed into and collected by the electron collector electrode. The collector electrode is maintained at a potential slightly positive with respect to the ion generator so that the electrons are collected at a small fraction of the full accelerating supply voltage energy.

  6. An experimental study of waveguide coupled microwave heating with conventional multicusp negative ion sources

    NASA Astrophysics Data System (ADS)

    Komppula, J.; Kalvas, T.; Koivisto, H.; Laulainen, J.; Tarvainen, O.

    2015-04-01

    Negative ion production with conventional multicusp plasma chambers utilizing 2.45 GHz microwave heating is demonstrated. The experimental results were obtained with the multicusp plasma chambers and extraction systems of the RF-driven RADIS ion source and the filament driven arc discharge ion source LIISA. A waveguide microwave coupling system, which is almost similar to the one used with the SILHI ion source, was used. The results demonstrate that at least one third of negative ion beam obtained with inductive RF-coupling (RADIS) or arc discharge (LIISA) can be achieved with 1 kW of 2.45 GHz microwave power in CW mode without any modification of the plasma chamber. The co-extracted electron to H- ratio and the optimum pressure range were observed to be similar for both heating methods. The behaviour of the plasma implies that the energy transfer from the microwaves to the plasma electrons is mainly an off-resonance process.

  7. Doubly Excited Resonances in the Positronium Negative Ion

    NASA Technical Reports Server (NTRS)

    Ho, Y.K.

    2007-01-01

    The recent theoretical studies on the doubly excited states of the Ps' ion are described. The results obtained by using the method of complex coordinate rotation show that the three-lepton system behaves very much like an XYX tri-atomic molecule. Furthermore, the recent investigation on the positronium negative ion embedded in Debye plasma environments is discussed. The problem is modeled by the use of a screened Coulomb potential to represent the interaction between the charge particles.

  8. Positive and negative cluster ions from liquid ethanol by fast ion bombardment.

    PubMed

    Kaneda, M; Shimizu, M; Hayakawa, T; Iriki, Y; Tsuchida, H; Itoh, A

    2010-04-14

    Secondary ion mass spectra have been measured for the first time for a liquid ethanol target bombarded by 2.0 MeV He(+) ions. Positive and negative ion spectra exhibit evidently a series of cluster ions of the forms [(EtOH)(n)H](+) and [(EtOH)(n)-H](-), respectively, in addition to light fragment ions from intact parent molecules. It was found that these cluster ions are produced only from liquid phase ethanol. Both positive and negative secondary ion spectra show similar cluster size distributions with almost the same decay slope. We also present for the first time the cluster ion distribution emitted from the liquid at different liquid temperatures.

  9. Negative ion-based neutral injection on DIII-D

    SciTech Connect

    Stewart, L.D.; Bhadra, D.K.; Colleraine, A.P.; Kim, J.

    1990-01-01

    High energy negative ion-based neutral beam injection is a strong candidate for heating and non-inductive current drive in tokamaks. Many of the questions related to the physics and engineering of this technique remain unanswered. In this paper, we consider the possibility of negative ion-based neutral beam injection on DIII-D. We establish the desired parameter space by examining physics trades. This is combined with potential design constraints and a survey of component technology options to establish an injector concept. Injector performance is estimated assuming particular component technologies, and concept flexibility with respect to incorporating alternate technologies is described. 9 refs., 6 figs., 4 tabs.

  10. Photodetachment of hydrogen negative ions with screened Coulomb interaction

    SciTech Connect

    Zhang, Song Bin; Chen, Xiang Jun; Wang, Jian Guo; Janev, R. K.; Qu, Yi Zhi

    2010-06-15

    The effects of Coulomb interaction screening on photodetachment cross sections of hydrogen negative ions below the n =2 excitation threshold is investigated by using the R-matrix method with pseudostates. The contributions of Feshbach and shape resonances to H{sup -} photodetachment cross section are presented when screening length (D) varies from D = {infinity} to D = 4.6 a.u. It is found that the interaction screening has dramatic effects on the photodetachment cross sections of hydrogen negative ions in the photoelectron energy region around the n = 2 excitation threshold by strongly affecting the evolution of near-threshold resonances.

  11. Negative ion formation in potassium-adenine collisions

    NASA Astrophysics Data System (ADS)

    Chunha, T.; Mendes, M.; Ferreira da Silva, F.; García, G.; Limáo Vieira, P.

    2016-09-01

    We have devoted experimental studies to time-of-flight negative ion formation in electron transfer experiments from neutral potassium atoms with neutral adenine molecules1. Total partial cross sections have been obtained as a function of the collision energy, together with branching ratios for the most relevant fragment anions. Additional set of measurements in adenine derivatives have been performed in order to probe the role of negative ions as well as to probe whether site- and bond-selective excision is also a prevalent mechanism within electron transfer in atom-molecule collision experiments.

  12. Bimolecular reaction dynamics from photoelectron spectroscopy of negative ions

    SciTech Connect

    Bradforth, S.E.

    1992-11-01

    The transition state region of a neutral bimolecular reaction may be experimentally investigated by photoelectron spectroscopy of an appropriate negative ion. The photoelectron spectrum provides information on the spectroscopy and dynamics of the short lived transition state and may be used to develop model potential energy surfaces that are semi-quantitative in this important region. The principles of bound [yields] bound negative ion photoelectron spectroscopy are illustrated by way of an example: a full analysis of the photoelectron bands of CN[sup [minus

  13. Solitons in a relativistic plasma with negative ions--

    SciTech Connect

    Das, G.C. ); Karmakar, B. ); Ibohanbi Singh, KH. )

    1990-02-01

    The interaction of the nonlinearity and the dispersiveness causing the solitary waves are studied in a relativistic plasma with negative ions through the derivation of a nonlinear partial differential equation known as the Korteweg-Devries (K-DV) equation. The negative ions play a salient feature on the existence and behavior of the solitons and could be of interest in laboratory plasmas. First, the observations are made in a nonisothermal plasma, and later the reduction to the nonisothermality of the plasma shows entirely different characteristics as compared to the solitons in the isothermal plasmas. A comparison with the various solutions has been emphasized.

  14. Production of negative ions of hydrogen isotopes. [Patent application

    SciTech Connect

    Garscadden, A.

    1981-05-14

    A process for generating negative ions of hydrogen isotopes is described which comprises cooling the hydrogen gas below 300K, and preferably to about 200K, vibrationally exciting the molecules of the gas, and then dissociating the molecules by electron impact into neutral hydrogen atoms and negative hydrogen ions. Alternatively, the gas may first be vibrationally excited by heating or the like, and then cooled translationally, for example, by rapid expansion prior to dissociation by electron impact. The processes of this invention are characterized by control of non-equilibrium conditions to obtain large increases in dissociative attachment rates by increasing the population of hydrogen gas molecules having a higher vibrational energy state.

  15. Unresolved problems in cesiation processes of negative hydrogen ion sources

    NASA Astrophysics Data System (ADS)

    Wada, Motoi

    2013-09-01

    Attempts are being made to optimize negative hydrogen (H-) ion current by introducing Cs into an ion source, but there are some unanswered questions in properly handling Cs to realize stable extraction of H- ion beams. For example, Cs amount to optimize H- production often becomes much larger than the amount predicted to realize partial monolayer of Cs on the source wall. Additional charge of Cs into a source to recover reduced H- current by continuous operation does not necessarily realize the original value. Beam intensity of H- changes with the impurity content in the ion source. The purpose of the present paper is to list up these uncertainties and unknown factors in negative ion source performance operated with Cs. The paper tries to identify possible mechanisms causing these problems by running a simulation code ACAT (Atomic Collision in Amorphous Target). The code predicts that glancing injection of hydrogen ions doubles the numbers of both reflection coefficients and ion induced desorption yields from those for the normal incidence. It also indicates smaller hydrogen desorption yields for thick layer of adsorbed hydrogen on the surface. These results are compared with experimental data obtained in UHV conditions.

  16. Computer System for Unattended Control of Negative Ion Source

    SciTech Connect

    Zubarev, P. V.; Khilchenko, A. D.; Kvashnin, A. N.; Moiseev, D. V.; Puriga, E. A.; Sanin, A. L.; Savkin, V. Ya.

    2011-09-26

    The computer system for control of cw surface-plasma source of negative ions is described. The system provides an automatic handling of source parameters by the specified scenario. It includes the automatic source start and long-term operation with switching and control of the power supplies blocks, setting and reading of source parameters like hydrogen feed, cesium seed, electrodes' temperature, checking of the protection and blockings elements like vacuum degradation, absence of cooling water, etc. The semi-automatic mode of control is also available, where the order of steps and magnitude of parameters, included to scenario, is corrected in situ by the operator. Control system includes the main controller and a set of peripheral local controllers. Commands execution is carried out by the main controller. Each peripheral controller is driven by the stand-alone program, stored in its ROM. Control system is handled from PC via Ethernet. The PC and controllers are connected by fiber optic lines, which provide the high voltage insulation and the stable system operation in spite the breakdowns and electromagnetic noise of cross-field discharge. The PC program for data setting and information display is developed under the LabView.

  17. Effect of Coulomb collision on the negative ion extraction mechanism in negative ion sources

    SciTech Connect

    Goto, I. Nishioka, S.; Abe, S.; Hatayama, A.; Miyamoto, K.; Mattei, S.; Lettry, J.

    2016-02-15

    To improve the H{sup −} ion beam optics, it is necessary to understand the energy relaxation process of surface produced H{sup −} ions in the extraction region of Cs seeded H{sup −} ion sources. Coulomb collisions of charged particles have been introduced to the 2D3V-PIC (two dimension in real space and three dimension in velocity space particle-in-cell) model for the H{sup −} extraction by using the binary collision model. Due to Coulomb collision, the lower energy part of the ion energy distribution function of H{sup −} ions has been greatly increased. The mean kinetic energy of the surface produced H{sup −} ions has been reduced to 0.65 eV from 1.5 eV. It has been suggested that the beam optics of the extracted H{sup −} ion beam is strongly affected by the energy relaxation process due to Coulomb collision.

  18. Propagation of ion acoustic shock waves in negative ion plasmas with nonextensive electrons

    SciTech Connect

    Hussain, S.; Akhtar, N.; Mahmood, S.

    2013-09-15

    Nonlinear ion acoustic shocks (monotonic as well as oscillatory) waves in negative ion plasmas are investigated. The inertialess electron species are assumed to be nonthermal and follow Tsallis distribution. The dissipation in the plasma is considered via kinematic viscosities of both positive and negative ion species. The Korteweg-de Vries Burgers (KdVB) equation is derived using small amplitude reductive perturbation technique and its analytical solution is presented. The effects of variation of density and temperature of negative ions and nonthermal parameter q of electrons on the strength of the shock structures are plotted for illustration. The numerical solutions of KdVB equation using Runge Kutta method are obtained, and transition from oscillatory to monotonic shock structures is also discussed in detail for negative ions nonthermal plasmas.

  19. Simulation Studies of Hydrogen Ion reflection from Tungsten for the Surface Production of Negative Hydrogen Ions

    SciTech Connect

    Kenmotsu, Takahiro; Wada, Motoi

    2011-09-26

    The production efficiency of negative ions at tungsten surface by particle reflection has been investigated. Angular distributions and energy spectra of reflected hydrogen ions from tungsten surface are calculated with a Monte Carlo simulation code ACAT. The results obtained with ACAT have indicated that angular distributions of reflected hydrogen ions show narrow distributions for low-energy incidence such as 50 eV, and energy spectra of reflected ions show sharp peaks around 90% of incident energy. These narrow angular distributions and sharp peaks are favorable for the efficient extraction of negative ions from an ion source equipped with tungsten surface as negative ionization converter. The retained hydrogen atoms in tungsten lead to the reduction in extraction efficiency due to boarded angular distributions.

  20. Simulation Studies of Hydrogen Ion reflection from Tungsten for the Surface Production of Negative Hydrogen Ions

    NASA Astrophysics Data System (ADS)

    Kenmotsu, Takahiro; Wada, Motoi

    2011-09-01

    The production efficiency of negative ions at tungsten surface by particle reflection has been investigated. Angular distributions and energy spectra of reflected hydrogen ions from tungsten surface are calculated with a Monte Carlo simulation code ACAT. The results obtained with ACAT have indicated that angular distributions of reflected hydrogen ions show narrow distributions for low-energy incidence such as 50 eV, and energy spectra of reflected ions show sharp peaks around 90% of incident energy. These narrow angular distributions and sharp peaks are favorable for the efficient extraction of negative ions from an ion source equipped with tungsten surface as negative ionization converter. The retained hydrogen atoms in tungsten lead to the reduction in extraction efficiency due to boarded angular distributions.

  1. PIC modeling of negative ion sources for fusion

    NASA Astrophysics Data System (ADS)

    Taccogna, F.; Minelli, P.

    2017-01-01

    This work represents the first attempt to model the full-size ITER negative ion source prototype including expansion, extraction and part of the acceleration regions keeping the resolution fine enough to resolve every single aperture of the extraction grid. The model consists of a 2.5-dimensional Particle-in-Cell/Monte Carlo Collision representation of the plane perpendicular to the filter field lines. Both the magnetic filter and electron deflection fields have been included. A negative ion current density of {j}{H-}=500 {{A}} {{{m}}}-2 produced by neutral conversion from the plasma grid is used as fixed parameter, while negative ions produced by electron dissociative attachment of vibrationally excited molecules and by ionic conversion on plasma grid are self-consistently simulated. Results show the non-ambipolar character of the transport in the expansion region driven by electron magnetic drifts in the plane perpendicular to the filter field. It induces a top-bottom asymmetry detected up to the extraction grid which in turn leads to a tilted positive ion flow hitting the plasma grid and a tilted negative ion flow emitted from the plasma grid. As a consequence, the plasma structure is not uniform around the single aperture: the meniscus assumes a form of asymmetric lobe and a deeper potential well is detected from one side of the aperture relative to the other side. Therefore, the surface-produced contribution to the negative ion extraction is not equally distributed between both the sides around the aperture but it come mainly from the lower side of the grid giving an asymmetrical current distribution in the single beamlet.

  2. National negative-ion-based neutral-beam development plan

    SciTech Connect

    Cooper, W.S.; Pyle, R.V.

    1983-08-01

    The plan covers facilities required, program milestones, and decision points. It includes identification of applications, experiments, theoretical research areas, development of specific technologies and reactor development and demonstration facilities required to bring about the successful application of negative-ion-based neutral beams. Particular emphasis is placed on those activities leading to use on existing plasma confinement experiments or their upgrades.

  3. Negative ions at Titan: New results using spacecraft attitude changes

    NASA Astrophysics Data System (ADS)

    Wellbrock, A.; Coates, A. J.; Lewis, G. R.; Jones, G. H.; Arridge, C. S.; Magee, B. A.; Crary, F. J.; Waite, J. H.; Sittler, E. C.; Young, D. T.

    2009-04-01

    A. Wellbrock, A. J. Coates, G. R. Lewis, G. H. Jones, C. S. Arridge, B. A. Magee, F. J. Crary, J. H. Waite, E. C. Sittler, D. T. Young The ELS (ELectron Spectrometer) part of the Cassini Plasma Spectrometer (CAPS) revealed the existence of negative ions in Titan's ionosphere (Coates et al, 2007, Waite et al, 2007). The instrument is mounted on a rotating platform called the actuator. The negative ions are detected when this actuator points in the direction in which the spacecraft travels (the ‘ram direction'). This is because the negative ions have slow thermal speeds compared to the spacecraft speed, whereas electrons have much higher thermal speeds and are detected in any direction as their distribution is isotropic. Hence the negative ions can be identified as narrow spikes in the ELS electron spectrograms. During most Titan flybys, the spacecraft attitude is oriented such that the central anode of the instrument points in the ram direction. However, during Titan encounters when the spacecraft rotates, other anodes can point in the ram direction for short periods of time, or in a direction very close to the ram direction. In the latter case, only higher mass ions are detected. Comparing data from different anodes in and near the ram direction can be used to obtain information related to the ion velocity and temperature, which we discuss. The study of measurements from all anodes of the instrument also significantly increases the number of negative ion spikes available for analysis. The resulting set of data allows a statistical study of the different mass groups at a range of altitudes and latitudes, and their scale heights. We summarise and discuss the results. References: Coates, A.J., F.J. Crary, G.R. Lewis, D.T. Young, J.H. Waite, Jr., E.C.Sittler Jr., Discovery of heavy negative ions in Titan's ionosphere, Geophys. Res. Lett., 34, L22103, 2007. Waite, J. H., Jr., D. T. Young, T. E. Cravens, A. J. Coates, F. J. Crary, B. Magee and J. Westlake, The Process

  4. Fluid and kinetic models of negative ion sheaths

    SciTech Connect

    Cavenago, M.

    2011-09-26

    Due to the presence of a large transverse magnetic field (B{sub x} and B{sub y} where z is the extraction axis), the extraction of electrons from a negative ion source is likely to happen with a large angle with respect to z axis. The negative ion and electron sheaths are here studied both with kinetic and with fluid models. First, Vlasov-Poisson models are reduced to one dimensional integrodifferential equations, discussing also trapped orbits. The integrodifferential equations for electron transport are analytically solved for a variety of extraction potentials (in 1D). Collision frequency dependency from electron flow speed and temperature is discussed. Then both ion and electron space charge and fluid motion are solved, using electron densities expression consistent with kinetic model. Results for the sheath charge profile and extraction field as a function of B{sub x} are shown.

  5. Fragmentation of peptide negative molecular ions induced by resonance electron capture

    PubMed Central

    Vasil’ev, Yury V.; Figard, Benjamin J.; Morré, Jeff; Deinzer, Max L.

    2009-01-01

    A simple robust method to study resonance gas-phase reactions between neutral peptides of low volatility and free electrons has been designed and implemented. Resonance electron capture (REC) experiments were performed by several neutral model peptides and two naturally occurring peptides. The assignment of negative ions (NIs) formed in these gas-phase reactions was based on high mass-resolving power experiments. From these accurate mass measurements, it was concluded that fragment NIs formed by low (1–2 eV) energy REC are of the same types as those observed in electron capture∕transfer dissociation, where the positive charge is a factor. The main feature resulting from these REC experiments by peptides is the occurrence of zn−1 ions, which are invariably of the highest abundances in the negative ion mass spectra of larger peptides. [M–H]− NIs presumably the carboxylate anion structure dominate the REC spectra of smaller peptides. There was no evidence for the occurrence of the complementary reaction, i.e., the formations of cn+1 ions. Instead, cn ions arose without hydrogen∕proton transfer albeit with lower abundances than that observed for zn−1 ions. Only the amide forms of small peptides showed more abundant ion peaks for the cn ions than for the zn−1 ions. The mechanisms for the N–Cα bond cleavage are discussed. PMID:19655877

  6. Fragmentation of peptide negative molecular ions induced by resonance electron capture

    SciTech Connect

    Vasil'ev, Yury V.; Figard, Benjamin J.; Morre, Jeff; Deinzer, Max L.

    2009-07-28

    A simple robust method to study resonance gas-phase reactions between neutral peptides of low volatility and free electrons has been designed and implemented. Resonance electron capture (REC) experiments were performed by several neutral model peptides and two naturally occurring peptides. The assignment of negative ions (NIs) formed in these gas-phase reactions was based on high mass-resolving power experiments. From these accurate mass measurements, it was concluded that fragment NIs formed by low (1-2 eV) energy REC are of the same types as those observed in electron capture/transfer dissociation, where the positive charge is a factor. The main feature resulting from these REC experiments by peptides is the occurrence of z{sub n}-1 ions, which are invariably of the highest abundances in the negative ion mass spectra of larger peptides. [M-H]{sup -} NIs presumably the carboxylate anion structure dominate the REC spectra of smaller peptides. There was no evidence for the occurrence of the complementary reaction, i.e., the formations of c{sub n}+1 ions. Instead, c{sub n} ions arose without hydrogen/proton transfer albeit with lower abundances than that observed for z{sub n}-1 ions. Only the amide forms of small peptides showed more abundant ion peaks for the c{sub n} ions than for the z{sub n}-1 ions. The mechanisms for the N-C{sub {alpha}} bond cleavage are discussed.

  7. Transport Properties of Negative Ions in HBR Plasmas

    NASA Astrophysics Data System (ADS)

    Stojanovic, Vladimir; Ivanovic, Nenad; Radmilovic-Radjenovic, Marija; Raspopovic, Zoran; Bojarov, Aleksandar; Petrovic, Zoran

    2014-10-01

    Low temperature plasma in halogenated gases is standard environment for dry etching of semiconductors. Amount of negative ions in HBr plasmas determines electronegativity so modeling etching devices requires data for anion transport properties. In this work we present cross section set for Br- ions in HBr assembled by using Denpoh-Nanbu theory. The threshold energy values were calculated by known heats of formation. The calculated total cross section accounts for ion-induced-dipole and ion-permanent-dipole interaction by using the local-dipole model. The total cross section was corrected to fit the reduced mobility obtained by SACM (Statistical Adiabatic Channel Model) approximation. Existing cross section measurements were used to scale calculated cross sections. Finally, we used Monte Carlo method to determine transport parameters for Br- as a function of reduced electric fields that can be used in fluid and hybrid plasma models.

  8. Negative deuterium ions for tandem mirror next step and tandem mirror reactors

    SciTech Connect

    Hamilton, G.W.

    1980-09-25

    Recent designs for mirror fusion reactors with good power balance include ambipolar potential plugs to reduce end losses and thermal barriers to maintain a difference in electron temperature between the large-volume central cell plasma and the confining end plugs. These designs led to several new requirements for D/sup 0/ neutral beams derived from negative ions at energies of 150 to 200 keV and possibly higher. Such beams are required for injection of fat ions into the plugs and the barrier and for charge-exchange pumping of thermal ions diffusing into the barrier. Negative ions are preferred for these purposes because of their relatively high efficiency of neutralization and their high purity of single-energy D/sup -/. Examples of injector designs for Tandem Mirror Next Step (TMNS) and Tandem Mirror Reactors (TMR) are presented.

  9. MgO-templated carbon as a negative electrode material for Na-ion capacitors

    NASA Astrophysics Data System (ADS)

    Kado, Yuya; Soneda, Yasushi

    2016-12-01

    In this study, MgO-templated carbon with different pore structures was investigated as a negative electrode material for Na-ion capacitors. With increasing the Brunauer-Emmett-Teller surface area, the irreversible capacity increased, and the coulombic efficiency of the 1st cycle decreased because of the formation of solid electrolyte interface layers. MgO-templated carbon annealed at 1000 °C exhibited the highest capacity and best rate performance, suggesting that an appropriate balance between surface area and crystallinity is imperative for fast Na-ion storage, attributed to the storage mechanism: combination of non-faradaic electric double-layer capacitance and faradaic Na intercalation in the carbon layers. Finally, a Na-ion capacitor cell using MgO-templated carbon and activated carbon as the negative and positive electrodes, respectively, exhibited an energy density at high power density significantly greater than that exhibited by the cell using a commercial hard carbon negative electrode.

  10. First experiments with Cs doped Mo as surface converter for negative hydrogen ion sources

    NASA Astrophysics Data System (ADS)

    Schiesko, L.; Cartry, G.; Hopf, C.; Höschen, T.; Meisl, G.; Encke, O.; Heinemann, B.; Achkasov, K.; Amsalem, P.; Fantz, U.

    2015-08-01

    A study was conducted on the properties of molybdenum implanted with caesium as an approach to reduce the Cs consumption of negative hydrogen ion sources based on evaporated Cs. The depth profiles of the implanted Cs were simulated by SDTrimSP and experimentally determined by X-ray photoelectron spectroscopy depth profiling. In particular, one year after implantation, the depth profiles showed no signs of Cs diffusion into the molybdenum, suggesting long term stability of the implanted Cs atoms. The H- surface generation mechanisms on the implanted samples in hydrogen plasma were investigated, and the stability of the H- yield during four hours low power hydrogen plasma discharges was demonstrated. An estimation of the work function reduction (-0.8 eV) by the Cs implantation was performed, and a comparison of the relative negative ion yields between the implanted samples and highly oriented pyrolitic graphite showed that the Cs doped Mo negative ion yield was larger.

  11. Experimental validation of the dual positive and negative ion beam acceleration in the plasma propulsion with electronegative gases thruster

    SciTech Connect

    Rafalskyi, Dmytro Popelier, Lara; Aanesland, Ane

    2014-02-07

    The PEGASES (Plasma Propulsion with Electronegative Gases) thruster is a gridded ion thruster, where both positive and negative ions are accelerated to generate thrust. In this way, additional downstream neutralization by electrons is redundant. To achieve this, the thruster accelerates alternately positive and negative ions from an ion-ion plasma where the electron density is three orders of magnitude lower than the ion densities. This paper presents a first experimental study of the alternate acceleration in PEGASES, where SF{sub 6} is used as the working gas. Various electrostatic probes are used to investigate the source plasma potential and the energy, composition, and current of the extracted beams. We show here that the plasma potential control in such system is key parameter defining success of ion extraction and is sensitive to both parasitic electron current paths in the source region and deposition of sulphur containing dielectric films on the grids. In addition, large oscillations in the ion-ion plasma potential are found in the negative ion extraction phase. The oscillation occurs when the primary plasma approaches the grounded parts of the main core via sub-millimetres technological inputs. By controlling and suppressing the various undesired effects, we achieve perfect ion-ion plasma potential control with stable oscillation-free operation in the range of the available acceleration voltages (±350 V). The measured positive and negative ion currents in the beam are about 10 mA for each component at RF power of 100 W and non-optimized extraction system. Two different energy analyzers with and without magnetic electron suppression system are used to measure and compare the negative and positive ion and electron fluxes formed by the thruster. It is found that at alternate ion-ion extraction the positive and negative ion energy peaks are similar in areas and symmetrical in position with +/− ion energy corresponding to the amplitude of the applied

  12. Low-Power Ion Thruster Development Status

    NASA Technical Reports Server (NTRS)

    Patterson, Michael J.

    1999-01-01

    An effort is on-going to examine scaling relationships and design criteria for ion propulsion systems, and to address the need for a light weight, low power, high specific impulse propulsion option for small spacecraft. An element of this activity is the development of a low-power (sub-0.5 kW) ion thruster. This development effort has led to the fabrication and preliminary performance assessment of an 8 cm prototype xenon ion thruster operating over an input power envelope of 0.1-0.3 kW. Efficiencies for the thruster vary from 0.31 at 1750 seconds specific impulse at 0.1 kW, to about 0.48 at 2700 seconds specific impulse and 0.3 kW input power. Discharge losses for the thruster over this power range varied from about 320-380 W/A down to about 220-250 W/A. Ion optics performance compare favorably to that obtained with 30 cm ion optics, when scaled for the difference in beam area. The neutralizer, fabricated using 3 mm hollow cathode technology, operated at keeper currents of about 0.2-0.3 A, at a xenon flow rate of about 0.06 mg/s, over the 0.1-0.3 kW thruster input power envelope.

  13. Travelling-wave ion mobility and negative ion fragmentation of high mannose N-glycans

    PubMed Central

    Harvey, David J.; Scarff, Charlotte A.; Edgeworth, Matthew; Struwe, Weston B.; Pagel, Kevin; Thalassinos, Konstantinos; Crispin, Max; Scrivens, Jim

    2016-01-01

    The isomeric structure of high-mannose N-glycans can significantly impact biological recognition events. Here, the utility of travelling-wave ion mobility-mass spectrometry (TW IM-MS)for isomer separation of high-mannose N-glycans is investigated. Negative ion fragmentation using collision-induced dissociation (CID) gave more informative spectra than positive ion spectra with mass-different fragment ions characterizing many of the isomers. Isomer separation by ion mobility in both ionization modes was generally limited, with the arrival time distributions (ATD) often showing little sign of isomers. However, isomers could be partially resolved by plotting extracted fragment ATDs of the diagnostic fragment ions from the negative ion spectra and the fragmentation spectra of the isomers could be extracted by using ions from limited areas of the ATD peak. In some cases, asymmetric ATDs were observed but no isomers could be detected by fragmentation. In these cases, it was assumed that conformers were being separated. Collision cross sections (CCSs) of the isomers in positive and negative fragmentation mode were estimated from TW IM-MS data using dextran glycans as calibrant. More complete CCS data were achieved in negative ion mode by utilizing the diagnostic fragment ions. Examples of isomer separations are shown for N-glycans released from the well-characterized glycoproteins chicken ovalbumin, porcine thyroglobulin and gp120 from the human immunodeficiency virus. In addition to the cross sectional data, details of the negative ion collision-induced dissociation (CID) spectra of all resolved isomers are discussed. PMID:26956389

  14. 100 s extraction of negative ion beams by using actively temperature-controlled plasma grid

    SciTech Connect

    Kojima, A. Hanada, M.; Yoshida, M.; Tobari, H.; Kashiwagi, M.; Umeda, N.; Watanabe, K.; Grisham, L. R.

    2014-02-15

    Long pulse beam extraction with a current density of 120 A/m{sup 2} for 100 s has been achieved with a newly developed plasma grid (PG) for the JT-60SA negative ion source which is designed to produce high power and long pulse beams with a negative ion current of 130 A/m{sup 2} (22 A) and a pulse length of 100 s. The PG temperature is regulated by fluorinated fluids in order to keep the high PG temperature for the cesium-seeded negative ion production. The time constant for temperature controllability of the PG was measured to be below 10 s, which was mainly determined by the heat transfer coefficient of the fluorinated fluid. The measured decay time of the negative ion current extracted from the actively temperature-controlled PG was 430 s which was sufficient for the JT-60SA requirement, and much longer than that by inertial-cooling PG of 60 s. Obtained results of the long pulse capability are utilized to design the full size PG for the JT-60SA negative ion source.

  15. Inner-Shell Photodetachment of Nickel Negative Ions

    NASA Astrophysics Data System (ADS)

    Dumitriu, Ileana; Bilodeau, Rene; Gibson, Daniel; Walter, Wes; Gorczyca, Thomas; Aguilar, Alex; Rolles, Daniel; Pesic, Zoran; Berrah, Nora

    2015-05-01

    Transition metals are of interest for their catalytic properties and participation of d-orbital electrons in the bonding properties. Theoretical studies of transition metal negative ions are challenging due to strong electron correlation effects and existence of low-lying electronic states as a result of open d-shell configurations. Experimental studies of transition metal negative ions are limited compared with the ions belonging to the main groups of periodic table and these studies have mostly investigated the valence-shell electrons using laser spectroscopy. Our experiment focuses on inner-shell photodetachment studies of Ni- transition metal ions using the Ion-Photon Beamline on the ALS beamline 10.0.1. Inner-shell photodetachment spectrum was recorded over a range of 30 to 90 eV which includes the 3 p threshold for Ni-. The higher-charge state formation was also observed, indicating multi-electron ejection processes. The absolute cross-section for the production of Ni+ will also be presented.

  16. Strong Turbulence in Alkali Halide Negative Ion Plasmas

    NASA Astrophysics Data System (ADS)

    Sheehan, Daniel

    1999-11-01

    Negative ion plasmas (NIPs) are charge-neutral plasmas in which the negative charge is dominated by negative ions rather than electrons. They are found in laser discharges, combustion products, semiconductor manufacturing processes, stellar atmospheres, pulsar magnetospheres, and the Earth's ionosphere, both naturally and man-made. They often display signatures of strong turbulence^1. Development of a novel, compact, unmagnetized alkali halide (MX) NIP source will be discussed, it incorporating a ohmically-heated incandescent (2500K) tantulum solenoid (3cm dia, 15 cm long) with heat shields. The solenoid ionizes the MX vapor and confines contaminant electrons, allowing a very dry (electron-free) source. Plasma densities of 10^10 cm-3 and positive to negative ion mass ratios of 1 <= fracm_+m- <= 20 are achievable. The source will allow tests of strong turbulence theory^2. 1 Sheehan, D.P., et al., Phys. Fluids B5, 1593 (1993). 2 Tsytovich, V. and Wharton, C.W., Comm. Plasma Phys. Cont. Fusion 4, 91 (1978).

  17. Rogue wave triplets in an ion-beam dusty plasma with superthermal electrons and negative ions

    NASA Astrophysics Data System (ADS)

    Guo, Shimin; Mei, Liquan; Shi, Weijuan

    2013-11-01

    A new dust ion-acoustic wave structure called ‘Rogue wave triplets’ is investigated in an unmagnetized plasma consisting of stationary negatively charged dust grains, charged positive and negative ions, and electrons obeying kappa distribution, which is penetrated by an ion beam. The reductive perturbation theory is used to derive the nonlinear Schrödinger equation governing the dynamics as well as the modulation of wave packets. The rogue wave triplets which are composed of three separate Peregrine breathers can be generated in the modulation instability region. It has been suggested that a laboratory experiment be performed to test the theory presented here.

  18. Observation of the negative muonium ion in vacuum

    SciTech Connect

    Kuang, Yunan

    1989-05-01

    The negative muonium ion (M/sup /minus//), which is the bound system of a positive muon and two electrons, has been produced and observed for the first time. Its counterpart H/sup /minus// is well known, and spectroscopy and collision studies with H/sup /minus// have yielded many fruitful results. Noteworthy are recent investigations of the photoionization of a relativistic H/sup /minus// beam. The negative positronium ion has also been formed and observed. The discovery of M/sup /minus// provides us with a new leptonic system for spectroscopy and collision studies, which may reveal interesting physics associated with mass effects. Since M/sup /minus// is a charged particle, it can also be used to produce a beam of exotic atoms with a small phase space. This dissertation is a detailed account of the observation of M/sup /minus//. 93 refs., 54 figs., 18 tabs.

  19. Time-fractional Gardner equation for ion-acoustic waves in negative-ion-beam plasma with negative ions and nonthermal nonextensive electrons

    NASA Astrophysics Data System (ADS)

    Guo, Shimin; Mei, Liquan; Zhang, Zhengqiang

    2015-05-01

    Nonlinear propagation of ion-acoustic waves is investigated in a one-dimensional, unmagnetized plasma consisting of positive ions, negative ions, and nonthermal electrons featuring Tsallis distribution that is penetrated by a negative-ion-beam. The classical Gardner equation is derived to describe nonlinear behavior of ion-acoustic waves in the considered plasma system via reductive perturbation technique. We convert the classical Gardner equation into the time-fractional Gardner equation by Agrawal's method, where the time-fractional term is under the sense of Riesz fractional derivative. Employing variational iteration method, we construct solitary wave solutions of the time-fractional Gardner equation with initial condition which depends on the nonlinear and dispersion coefficients. The effect of the plasma parameters on the compressive and rarefactive ion-acoustic solitary waves is also discussed in detail.

  20. Time-fractional Gardner equation for ion-acoustic waves in negative-ion-beam plasma with negative ions and nonthermal nonextensive electrons

    SciTech Connect

    Guo, Shimin Mei, Liquan; Zhang, Zhengqiang

    2015-05-15

    Nonlinear propagation of ion-acoustic waves is investigated in a one-dimensional, unmagnetized plasma consisting of positive ions, negative ions, and nonthermal electrons featuring Tsallis distribution that is penetrated by a negative-ion-beam. The classical Gardner equation is derived to describe nonlinear behavior of ion-acoustic waves in the considered plasma system via reductive perturbation technique. We convert the classical Gardner equation into the time-fractional Gardner equation by Agrawal's method, where the time-fractional term is under the sense of Riesz fractional derivative. Employing variational iteration method, we construct solitary wave solutions of the time-fractional Gardner equation with initial condition which depends on the nonlinear and dispersion coefficients. The effect of the plasma parameters on the compressive and rarefactive ion-acoustic solitary waves is also discussed in detail.

  1. Negative hydrogen ion beam extraction from an AC heated cathode driven Bernas-type ion source

    SciTech Connect

    Okano, Y.; Miyamoto, N.; Kasuya, T.; Wada, M.

    2015-04-08

    A plasma grid structure was installed to a Bernas-type ion source used for ion implantation equipment. A negative hydrogen (H{sup −}) ion beam was extracted by an AC driven ion source by adjusting the bias to the plasma grid. The extracted electron current was reduced by positively biasing the plasma grid, while an optimum plasma grid bias voltage for negative ion beam extraction was found to be positive 3 V with respect to the arc chamber. Source operations with AC cathode heating show extraction characteristics almost identical to that with DC cathode heating, except a minute increase in H{sup −} current at higher frequency of cathode heating current.

  2. Efficient cesiation in RF driven surface plasma negative ion source

    SciTech Connect

    Belchenko, Yu.; Ivanov, A.; Konstantinov, S.; Sanin, A. Sotnikov, O.

    2016-02-15

    Experiments on hydrogen negative ions production in the large radio-frequency negative ion source with cesium seed are described. The system of directed cesium deposition to the plasma grid periphery was used. The small cesium seed (∼0.5 G) provides an enhanced H{sup −} production during a 2 month long experimental cycle. The gradual increase of negative ion yield during the long-term source runs was observed after cesium addition to the source. The degraded H{sup −} production was recorded after air filling to the source or after the cesium washing away from the driver and plasma chamber walls. The following source conditioning by beam shots produces the gradual recovery of H{sup −} yield to the high value. The effect of H{sup −} yield recovery after cesium coverage passivation by air fill was studied. The concept of cesium coverage replenishment and of H{sup −} yield recovery due to sputtering of cesium from the deteriorated layers is discussed.

  3. Dust ion-acoustic solitary waves in a dusty plasma with positive and negative ions

    SciTech Connect

    Sayed, F.; Haider, M. M.; Mamun, A. A.; Shukla, P. K.; Eliasson, B.; Adhikary, N.

    2008-06-15

    Properties of small but finite amplitude dust ion-acoustic (DIA) solitary waves in a dusty plasma composed of inertialess electrons, positive and negative inertial ions, and immobile negative/positive charged dust grains are investigated. By using the multifluid dusty plasma model, the Kortweg-de Vries equation and energy integral for small and large amplitude solitary pulses, are derived. It is found that the presence of the negative ions modifies the properties of the solitary DIA waves, and provides the possibility of positive and negative solitary potential structures to coexist. The present results may be useful for understanding the salient features of localized DIA excitations that may appear in data from forthcoming laboratory experiments and space observations.

  4. Effect of high energy electrons on H- production and destruction in a high current DC negative ion source for cyclotron

    NASA Astrophysics Data System (ADS)

    Onai, M.; Etoh, H.; Aoki, Y.; Shibata, T.; Mattei, S.; Fujita, S.; Hatayama, A.; Lettry, J.

    2016-02-01

    Recently, a filament driven multi-cusp negative ion source has been developed for proton cyclotrons in medical applications. In this study, numerical modeling of the filament arc-discharge source plasma has been done with kinetic modeling of electrons in the ion source plasmas by the multi-cusp arc-discharge code and zero dimensional rate equations for hydrogen molecules and negative ions. In this paper, main focus is placed on the effects of the arc-discharge power on the electron energy distribution function and the resultant H- production. The modelling results reasonably explains the dependence of the H- extraction current on the arc-discharge power in the experiments.

  5. Effect of high energy electrons on H⁻ production and destruction in a high current DC negative ion source for cyclotron.

    PubMed

    Onai, M; Etoh, H; Aoki, Y; Shibata, T; Mattei, S; Fujita, S; Hatayama, A; Lettry, J

    2016-02-01

    Recently, a filament driven multi-cusp negative ion source has been developed for proton cyclotrons in medical applications. In this study, numerical modeling of the filament arc-discharge source plasma has been done with kinetic modeling of electrons in the ion source plasmas by the multi-cusp arc-discharge code and zero dimensional rate equations for hydrogen molecules and negative ions. In this paper, main focus is placed on the effects of the arc-discharge power on the electron energy distribution function and the resultant H(-) production. The modelling results reasonably explains the dependence of the H(-) extraction current on the arc-discharge power in the experiments.

  6. Negative ion photoelectron spectroscopic studies of transition metal cluster

    NASA Astrophysics Data System (ADS)

    Marcy, Timothy Paul

    The studies reported in this thesis were performed using a negative ion photoelectron spectrometer consisting of a cold cathode DC discharge ion source, a flowing afterglow ion-molecule reactor, a magnetic sector mass analyzer, an argon ion laser for photodetachment and a hemispherical electron kinetic energy analyzer and microchannel plate detector for photoelectron spectrum generation. The 476.5 nm (2.601 eV), 488.0 nm (2.540 eV) and 514.5 nm (2.410 eV) negative ion photoelectron spectra of VMn are reported and compared to the previously studied spectra of isoelectronic Cr2.1 The photoelectron spectra are remarkably similar to those of Cr2 in electron affinity and vibrational frequencies. The 488.0 nm photoelectron spectra and electron affinities of Nb n- (n = 1 - 9) are reported with discussion of observed vibrational structure. There are transitions to several electronic states of Nb2 in the reported spectra with overlapping vibrational progressions. The spectra of Nb3, Nb4 and Nb6 show partially resolved vibrational structure in the transitions to the lowest observed electronic state of each cluster. There is a single distinct active vibrational mode in the transition to the ground state of Nb8. Spin-orbit energies of Nb- are also reported. The 488.0 nm negative ion photoelectron spectra of Nb3H(D) are reported and compared to those of Nb3. There is a single vibrational mode active in the spectra of Nb3H(D) which is very similar to the most distinct mode active in the spectrum of Nb3. The 488.0 nm photoelectron spectra of the NbxCyH(D) y- (x = 1, 2, 3, y = 2, 4, 6) dehydrogenated products of the reactions of ethylene with niobium cluster anions are reported. Temperature studies of some of these species give evidence for the presence of multiple isomers of each molecule in the ion beam. The spectra of NbC6H(D) 6 are identical to those obtained from the reactions of benzene with niobium clusters and indicate that benzene is being formed from ethylene in the flow

  7. Comparison of measured and modelled negative hydrogen ion densities at the ECR-discharge HOMER

    NASA Astrophysics Data System (ADS)

    Rauner, D.; Kurutz, U.; Fantz, U.

    2015-04-01

    As the negative hydrogen ion density nH- is a key parameter for the investigation of negative ion sources, its diagnostic quantification is essential in source development and operation as well as for fundamental research. By utilizing the photodetachment process of negative ions, generally two different diagnostic methods can be applied: via laser photodetachment, the density of negative ions is measured locally, but only relatively to the electron density. To obtain absolute densities, the electron density has to be measured additionally, which induces further uncertainties. Via cavity ring-down spectroscopy (CRDS), the absolute density of H- is measured directly, however LOS-averaged over the plasma length. At the ECR-discharge HOMER, where H- is produced in the plasma volume, laser photodetachment is applied as the standard method to measure nH-. The additional application of CRDS provides the possibility to directly obtain absolute values of nH-, thereby successfully bench-marking the laser photodetachment system as both diagnostics are in good agreement. In the investigated pressure range from 0.3 to 3 Pa, the measured negative hydrogen ion density shows a maximum at 1 to 1.5 Pa and an approximately linear response to increasing input microwave powers from 200 up to 500 W. Additionally, the volume production of negative ions is 0-dimensionally modelled by balancing H- production and destruction processes. The modelled densities are adapted to the absolute measurements of nH- via CRDS, allowing to identify collisions of H- with hydrogen atoms (associative and non-associative detachment) to be the dominant loss process of H- in the plasma volume at HOMER. Furthermore, the characteristic peak of nH- observed at 1 to 1.5 Pa is identified to be caused by a comparable behaviour of the electron density with varying pressure, as ne determines the volume production rate via dissociative electron attachment to vibrationally excited hydrogen molecules.

  8. Simplified power processing for inert gas ion thrusters

    NASA Technical Reports Server (NTRS)

    Rawlin, V. K.; Pinero, L. R.; Hamley, J. A.

    1993-01-01

    Significant simplifications to power processors for inert gas ion thrusters in the 1 to 5 kW range have been identified. They include elimination of all but three power supplies - one each for the neutralizer, main discharge, and beam. The neutralizer and discharge power supplies would provide both cathode heating and plasma generating functions. This dual-use power supply concept was validated via integration tests with a 30 cm diameter xenon ion thruster. The beam/accelerator power supply would have positive and negative outputs to allow a single power supply to provide both functions. The discharge and beam power supplies would incorporate full-bridge inverters similar to those proven for flight-ready arcjet propulsion systems. Operation of this simplified power processing scheme at an inverter frequency of 50 kHz results in a projected power processor design with low mass and high efficiency. A 2 kW reference point design has estimated values of specific mass of 5.4 kg/kW and an efficiency of 93 percent.

  9. Negative hydrogen ion beam extracted from a Bernas-type ion source

    SciTech Connect

    Miyamoto, N.; Wada, M.

    2011-09-26

    Negative hydrogen (H{sup -}) ion beam was produced without cesium seeding by a Bernas-type ion source with a coaxial hot cathode. The amount of H{sup -} ion beam current extracted from an original Bernas-type ion source using a hairpin shape filament as a hot cathode was 1 {mu}A with the 0.4 A arc current, while that 300 eV beam energy. In the other hand, H{sup -} ion beam current using the Bernas-type ion source with a coaxial hot cathode reached 4 {mu}A under the same condition. Production efficiency was enhanced by the focused plasma produced by a coaxial hot cathode.

  10. Semiempirical Theories of the Affinities of Negative Atomic Ions

    NASA Technical Reports Server (NTRS)

    Edie, John W.

    1961-01-01

    The determination of the electron affinities of negative atomic ions by means of direct experimental investigation is limited. To supplement the meager experimental results, several semiempirical theories have been advanced. One commonly used technique involves extrapolating the electron affinities along the isoelectronic sequences, The most recent of these extrapolations Is studied by extending the method to Include one more member of the isoelectronic sequence, When the results show that this extension does not increase the accuracy of the calculations, several possible explanations for this situation are explored. A different approach to the problem is suggested by the regularities appearing in the electron affinities. Noting that the regular linear pattern that exists for the ionization potentials of the p electrons as a function of Z, repeats itself for different degrees of ionization q, the slopes and intercepts of these curves are extrapolated to the case of the negative Ion. The method is placed on a theoretical basis by calculating the Slater parameters as functions of q and n, the number of equivalent p-electrons. These functions are no more than quadratic in q and n. The electron affinities are calculated by extending the linear relations that exist for the neutral atoms and positive ions to the negative ions. The extrapolated. slopes are apparently correct, but the intercepts must be slightly altered to agree with experiment. For this purpose one or two experimental affinities (depending on the extrapolation method) are used in each of the two short periods. The two extrapolation methods used are: (A) an isoelectronic sequence extrapolation of the linear pattern as such; (B) the same extrapolation of a linearization of this pattern (configuration centers) combined with an extrapolation of the other terms of the ground configurations. The latter method Is preferable, since it requires only experimental point for each period. The results agree within

  11. Summary of the status of negative-ion-based neutral beams

    SciTech Connect

    Cooper, W.S.

    1983-01-01

    Negative-ion-based neutral beam systems can perform multiple functions for fusion reactors, such as heating, current drive in tokamak reactors, and establishing and maintaining potential barriers in tandem mirror reactors. Practical systems operating continuously at the 200 keV, 1 MW level can be built using present-day technology. Ion sources have been demonstrated that produce D/sup -/ beams with <5% electron content, and that operate at linear current densities that are within a factor of 2 of what conservatively designed accelerator/transport structures can handle. Concepts are in hand for transporting the negative ion beam through a neutron maze before neutralization, thus permitting a radiation-hardened beamline. With an advanced laser photoneutralizer, overall system power efficiencies of 70% should be possible. A national program is being planned to achieve the goal of application of 475 keV systems on a mirror ETR in 1994.

  12. Oxidative Ionization Under Certain Negative-Ion Mass Spectrometric Conditions

    NASA Astrophysics Data System (ADS)

    Hassan, Isra; Pavlov, Julius; Errabelli, Ramu; Attygalle, Athula B.

    2017-02-01

    1,4-Hydroquinone and several other phenolic compounds generate (M - 2) -• radical-anions, rather than deprotonated molecules, under certain negative-ion mass spectrometric conditions. In fact, spectra generated under helium-plasma ionization (HePI) conditions from 1,4-hydroquinone and 1,4-benzoquinone (by electron capture) were practically indistinguishable. Because this process involves a net loss of H• and H+, it can be termed oxidative ionization. The superoxide radical-anion (O2 -•), known to be present in many atmospheric-pressure plasma ion sources operated in the negative mode, plays a critical role in the oxidative ionization process. The presence of a small peak at m/z 142 in the spectrum of 1,4-hydroquinone, but not in that of 1,4-benzoquinone, indicated that the initial step in the oxidative ionization process is the formation of an O2 -• adduct. On the other hand, under bona fide electrospray ionization (ESI) conditions, 1,4-hydroquinone generates predominantly an (M - 1) - ion. It is known that at sufficiently high capillary voltages, corona discharges begin to occur even in an ESI source. At lower ESI capillary voltages, deprotonation predominates; as the capillary voltage is raised, the abundance of O2 -• present in the plasma increases, and the source in turn increasingly behaves as a composite ESI/APCI source. While maintaining post-ionization ion activation to a minimum (to prevent fragmentation), and monitoring the relative intensities of the m/z 109 (due to deprotonation) and 108 (oxidative ionization) peaks recorded from 1,4-hydroquinone, a semiquantitative estimation of the APCI contribution to the overall ion-generation process can be obtained.

  13. Oxidative Ionization Under Certain Negative-Ion Mass Spectrometric Conditions.

    PubMed

    Hassan, Isra; Pavlov, Julius; Errabelli, Ramu; Attygalle, Athula B

    2017-02-01

    1,4-Hydroquinone and several other phenolic compounds generate (M - 2) (-•) radical-anions, rather than deprotonated molecules, under certain negative-ion mass spectrometric conditions. In fact, spectra generated under helium-plasma ionization (HePI) conditions from 1,4-hydroquinone and 1,4-benzoquinone (by electron capture) were practically indistinguishable. Because this process involves a net loss of H(•) and H(+), it can be termed oxidative ionization. The superoxide radical-anion (O2(-•)), known to be present in many atmospheric-pressure plasma ion sources operated in the negative mode, plays a critical role in the oxidative ionization process. The presence of a small peak at m/z 142 in the spectrum of 1,4-hydroquinone, but not in that of 1,4-benzoquinone, indicated that the initial step in the oxidative ionization process is the formation of an O2(-•) adduct. On the other hand, under bona fide electrospray ionization (ESI) conditions, 1,4-hydroquinone generates predominantly an (M - 1) (-) ion. It is known that at sufficiently high capillary voltages, corona discharges begin to occur even in an ESI source. At lower ESI capillary voltages, deprotonation predominates; as the capillary voltage is raised, the abundance of O2(-•) present in the plasma increases, and the source in turn increasingly behaves as a composite ESI/APCI source. While maintaining post-ionization ion activation to a minimum (to prevent fragmentation), and monitoring the relative intensities of the m/z 109 (due to deprotonation) and 108 (oxidative ionization) peaks recorded from 1,4-hydroquinone, a semiquantitative estimation of the APCI contribution to the overall ion-generation process can be obtained. Graphical Abstract ᅟ.

  14. High Power ECR Ion Thruster Discharge Characterization

    NASA Technical Reports Server (NTRS)

    Foster, John E.; Kamhawi, Hani; Haag, Thomas; Carpenter, Christian; Williams, George W.

    2006-01-01

    Electron cyclotron resonance (ECR) based ion thrusters with carbon based ion optics can potentially satisfy lifetime requirements for long duration missions (approximately 10 years) because grid erosion and cathode insert depletion issues are virtually eliminated. Though the ECR plasma discharge has been found to typically operate at slightly higher discharge losses than conventional DC ion thrusters (for high total thruster power applications), the discharge power fraction is small (less than 1 percent at 25 kW). In this regard, the benefits of increased life, low discharge plasma potentials, and reduced complexity are welcome tradeoffs for the associated discharge efficiency decrease. Presented here are results from discharge characterization of a large area ECR plasma source for gridded ion thruster applications. These measurements included load matching efficacy, bulk plasma properties via Langmuir probe, and plasma uniformity as measured using current probes distributed at the exit plane. A high degree of plasma uniformity was observed (flatness greater than 0.9). Additionally, charge state composition was qualitatively evaluated using emission spectroscopy. Plasma induced emission was dominated by xenon ion lines. No doubly charged xenon ions were detected.

  15. The 30-cm ion thruster power processor

    NASA Technical Reports Server (NTRS)

    Herron, B. G.; Hopper, D. J.

    1978-01-01

    A power processor unit for powering and controlling the 30 cm Mercury Electron-Bombardment Ion Thruster was designed, fabricated, and tested. The unit uses a unique and highly efficient transistor bridge inverter power stage in its implementation. The system operated from a 200 to 400 V dc input power bus, provides 12 independently controllable and closely regulated dc power outputs, and has an overall power conditioning capacity of 3.5 kW. Protective circuitry was incorporated as an integral part of the design to assure failure-free operation during transient and steady-state load faults. The implemented unit demonstrated an electrical efficiency between 91.5 and 91.9 at its nominal rated load over the 200 to 400 V dc input bus range.

  16. Electron and negative ion densities in a CW and pulsed 100 MHz capacitively coupled plasma discharge

    NASA Astrophysics Data System (ADS)

    Sirse, Nishant; Ellingboe, Bert; Tsutsumi, Takayoshi; Makoto, Sekine; Hori, Masaru

    2016-09-01

    Capacitively coupled plasma (CCP) discharges operating at a very high frequency, 30 -300 MHz, are becoming very popular now a days due to enhanced plasma processing rates and lower damage to the substrate. This is mainly achieved due to higher plasma densities and lower electron temperature produced at higher driving frequencies. Moreover, pulsing of the discharge system is known to deliver charging-free plasma processes which is highly desirable for high-aspect-ratio plasma etching. In this study, we present electron and negative ion densities in a CW and pulsed 100 MHz CCP discharge produced in O2 and Ar/O2/C4F8 gas mixture. Electron density is determined by the Hairpin probe and negative ion density is determined by the pulse laser photo-detachment combined with Hairpin probe. Photo-detachment is performed at 532, 355 and 266 nm laser wavelengths in order to selectively photo-detach different negative ions present in the discharge. Experimental results are presented for several power (100-500 W), pressure (1-10 Pa) conditions and for several duty ratios (25 - 75%) for 1 KHz pulse repetition frequency. In CW O2 plasma, we observed a similar trend in electron and negative ion density vs power, whereas, in Ar/O2/C4F8 gas mixture an opposite trend is observed in electron and negative ion density. This publication has emanated from research conducted with the financial support of Science Foundation Ireland under the International Strategic Cooperation Award Grant Number SFI/13/ISCA/2846.

  17. Detection of negative pickup ions at Saturn's moon Dione

    NASA Astrophysics Data System (ADS)

    Nordheim, T.; Jones, G. H.; Coates, A. J.; Wellbrock, A.; Hand, K. P.; Waite, J. H., Jr.

    2015-12-01

    Negative ions may be formed in both tenuous and dense planetary atmospheres and have been observed in-situ at Earth, Titan [Coates et al., 2007, 2009; Wellbrock et al., 2013] and Enceladus [Coates et al., 2010] as well as at comet Halley [Chaizy et al., 1991]. In the case of Titan, heavy hydrocarbon and nitrile based ions with masses reaching almost 14,000 amu/q have been observed using the CAPS Electron Spectrometer (ELS) onboard Cassini. These are believed to form even more massive organic aerosols termed tholins which fall to lower altitudes where they make up the distinct haze layers, and eventually rain down onto Titan's surface perhaps forming the organic-rich dunes. Very tenuous atmospheres were predicted at the smaller icy moons of Saturn [Sittler et al., 2004; Saur and Strobel, 2005], and subsequently detected [Teolis et al., 2010; Tokar et al., 2012]. These are produced when charged particles from Saturn's magnetosphere interact with moon surfaces, ejecting neutral species. Some portion of these atmospheric neutrals will in turn become ionized and 'picked up' by Saturn's corotating magnetosphere. These pickup ions will then move in cycloidal trajectories that we may intercept using the Cassini spacecraft, even at considerable distance from the moon itself. In this fashion, negative and positive pickup ions have been used to infer a tenuous CO2-O2 atmosphere at Saturn's moon Rhea [Teolis et al., 2010], and positive pickup ions at Dione [Tokar et al., 2012]. Here we report on the detection of negative pickup ions during a close flyby of Dione by the Cassini CAPS ELS instrument, and the implications that these observations may have for the Dionian atmosphere. Chaizy, P., et al. (1991), Nature, 349(6308), 393-396 Coates, A. J., et al. (2007), Geophys. Res. Lett., 34(22), 6-11 Coates, A. J., et al. (2009), Planet. Space Sci., 57(14-15), 1866-1871 Coates, A. J., et al. (2010), Icarus, 206(2), 618-622 Saur, J., and D. F. Strobel (2005), Astrophys. J. Lett., 620

  18. Positive and negative ion beam merging system for neutral beam production

    DOEpatents

    Leung, Ka-Ngo; Reijonen, Jani

    2005-12-13

    The positive and negative ion beam merging system extracts positive and negative ions of the same species and of the same energy from two separate ion sources. The positive and negative ions from both sources pass through a bending magnetic field region between the pole faces of an electromagnet. Since the positive and negative ions come from mirror image positions on opposite sides of a beam axis, and the positive and negative ions are identical, the trajectories will be symmetrical and the positive and negative ion beams will merge into a single neutral beam as they leave the pole face of the electromagnet. The ion sources are preferably multicusp plasma ion sources. The ion sources may include a multi-aperture extraction system for increasing ion current from the sources.

  19. Wigner time delay in photodetachment of negative ions

    NASA Astrophysics Data System (ADS)

    Saha, S.; Deshmukh, P. C.; Jose, J.; Kkeifets, A. S.; Manson, S. T.

    2016-05-01

    In recent years, there has been much interest in studies on Wigner time delay in atomic photoionization using various experimental techniques and theoretical methodologies. In the present work, we report time delay in the photodetachment of negative ions using the relativistic-random-phase approximation (RRPA), which includes relativistic and important correlation effects. Time delay is obtained as energy derivative of phase of the photodetachment complex transition amplitude. We investigate the time delay in the dipole n p --> ɛd channels in the photodetachment of F- and Cl-, and in n f --> ɛg channels in the photodetachment of Tm-. In photodetachment of the negative ions, the photoelectron escapes in the field of the neutral atom and thus does not experience the nuclear Coulomb field; hence the phase is devoid of the Coulomb component. The systems chosen are well suited to examine the sensitivity of the photodetachment time delay to the centrifugal potential. The ions chosen have closed shells, and thus amenable to the RPA. Work supported by DOE, Office of Chemical Sciences, DST (India), and the Australian Research Council.

  20. Beam-plasma interactions in a positive ion-negative ion plasma

    NASA Technical Reports Server (NTRS)

    Intrator, T.; Hershkowitz, N.; Stern, R.

    1983-01-01

    An electron-free plasma consisting of negative ions /SF6(-)/ and positive ions /Ar(+)/, and negligible neutral-ion collision frequencies has been created in the laboratory. This plasma has a mass ratio of approximately 3.5-similar to many computer particle-in-cell simulated systems. A fluid description of this positive and negative ion confinement (PANIC) plasma is given and compared to experimental measurements of a beam-plasma instability for both beam species and a wide range of beam energies. The fluid dispersion relation and most growing modes are predicted to be insensitive to many parameters of the PANIC beam-plasma system, and found to the consistent with the data.

  1. Models of radiofrequency coupling for negative ion sources

    SciTech Connect

    Cavenago, M.; Petrenko, S.

    2012-02-15

    Radiofrequency heating for ICP (inductively coupled plasma) ion sources depends on the source operating pressure, the presence or absence of a Faraday shield, the driver coil geometry, the frequency used, and the magnetic field configuration: in negative ion source a magnetic filter seems necessary for H{sup -} survival. The result of single particle simulations showing the possibility of electron acceleration in the preglow regime and for reasonable driver chamber radius (15 cm) is reported, also as a function of the static external magnetic field. An effective plasma conductivity, depending not only from electron density, temperature, and rf field but also on static magnetic field is here presented and compared to previous models. Use of this conductivity and of multiphysics tools for a plasma transport and heating model is shown and discussed for a small source.

  2. Studies of transition states and radicals by negative ion photodetachment

    SciTech Connect

    Metz, R.B.

    1991-12-01

    Negative ion photodetachment is a versatile tool for the production and study of transient neutral species such as reaction intermediates and free radicals. Photodetachment of the stable XHY{sup {minus}} anion provides a direct spectroscopic probe of the transition state region of the potential energy surface for the neutral hydrogen transfer reaction X + HY {yields} XH + Y, where X and Y are halogen atoms. The technique is especially sensitive to resonances, which occur at a specific energy, but the spectra also show features due to direct scattering. We have used collinear adiabatic simulations of the photoelectron spectra to evaluate trail potential energy surfaces for the biomolecular reactions and have extended the adiabatic approach to three dimensions and used it to evaluate empirical potential energy surfaces for the I + Hl and Br + HI reactions. In addition, we have derived an empirical, collinear potential energy surface for the Br + HBr reaction that reproduces our experimental results and have extended this surface to three dimensions. Photodetachment of a negative ion can be also used to study neutral free radicals. We have studied the vibrational and electronic spectroscopy of CH{sub 2}NO{sub 2} by photoelectron spectroscopy of CH{sub 2}NO{sub 2}{sup {minus}}, determining the electron affinity of CH{sub 2}NO{sub 2}, gaining insight on the bonding of the {sup 2}B{sub 1} ground state and observing the {sup 2}A{sub 2} excited state for the first time. Negative ion photodetachment also provides a novel and versatile source of mass-selected, jet-cooled free radicals. We have studied the photodissociation of CH{sub 2}NO{sub 2} at 270, 235, and 208 nm, obtaining information on the dissociation products by measuring the kinetic energy release in the photodissociation.

  3. Development of a novel radio-frequency negative hydrogen ion source in conically converging configuration.

    PubMed

    Jung, B K; Dang, J J; An, Y H; Chung, K J; Hwang, Y S

    2014-02-01

    Volume-produced negative ion source still requires enhancement of current density with lower input RF (radio-frequency) power in lower operating pressure for various applications. To confirm recent observation of efficient negative ion production with a short cylindrical chamber with smaller effective plasma size, the RF-driven transformer-coupled plasma H(-) ion source at Seoul National University is modified by adopting a newly designed quartz RF window to reduce the chamber length. Experiments with the reduced chamber length show a few times enhancement of H(-) ion beam current compared to that extracted from the previous chamber design, which is consistent with the measured H(-) ion population. Nevertheless, decrease in H(-) ion beam current observed in low pressure regime below ∼5 mTorr owing to insufficient filtering of high energy electrons in the extraction region needs to be resolved to address the usefulness of electron temperature control by the change of geometrical configuration of the discharge chamber. A new discharge chamber with conically converging configuration has been developed, in which the chamber diameter decreases as approaching to the extraction region away from the planar RF antenna such that stronger filter magnetic field can be utilized to prohibit high energy electrons from transporting to the extraction region. First experimental results for the H(-) ion beam extraction with this configuration show that higher magnetic filter field makes peak negative beam currents happen in lower operating pressure. However, overall decrease in H(-) ion beam current due to the change of chamber geometry still requires further study of geometrical effect on particle transport and optimization of magnetic field in this novel configuration.

  4. Interferences in photodetachment of a triatomic negative ion

    SciTech Connect

    Afaq, A.; Ahmad, M. A.; Rashid, A.; Ahmad, Iftikhar; Tahir, B. A.; Hussain, Muhammad Tahir

    2009-01-26

    The photodetachment of a triatomic negative ion is studied and the detached-electron wave function is obtained as a superposition of coherent waves originating from each atom of the system. The photodetached electron flux is evaluated on a screen placed at a large distance from the system, which displays strong interferences. A simple analytical formula is also obtained for the total photodetachment cross section. The formula approaches one time the cross sections for the one-center and two-center systems in the high photon energy limits. Also it approaches three times the cross section for one-center system in the low photon energy limits.

  5. Cesium control and diagnostics in surface plasma negative ion sources

    SciTech Connect

    Dudnikov, Vadim; Chapovsky, Pavel; Dudnikov, Andrei

    2010-02-15

    For efficient and reliable negative ion generation it is very important to improve a cesium control and diagnostics. Laser beam attenuation and resonance fluorescence can be used for measurement of cesium distribution and cesium control. Resonant laser excitation and two-photon excitation can be used for improved cesium ionization and cesium trapping in the discharge chamber. Simple and inexpensive diode lasers can be used for cesium diagnostics and control. Cesium migration along the surface is an important mechanism of cesium escaping. It is important to develop a suppression of cesium migration and cesium accumulation on the extraction system.

  6. Electrical shielding box measurement of the negative hydrogen beam from Penning ion gauge ion source.

    PubMed

    Wang, T; Yang, Z; Dong, P; long, J D; He, X Z; Wang, X; Zhang, K Z; Zhang, L W

    2012-06-01

    The cold-cathode Penning ion gauge (PIG) type ion source has been used for generation of negative hydrogen (H(-)) ions as the internal ion source of a compact cyclotron. A novel method called electrical shielding box dc beam measurement is described in this paper, and the beam intensity was measured under dc extraction inside an electrical shielding box. The results of the trajectory simulation and dc H(-) beam extraction measurement were presented. The effect of gas flow rate, magnetic field strength, arc current, and extraction voltage were also discussed. In conclusion, the dc H(-) beam current of about 4 mA from the PIG ion source with the puller voltage of 40 kV and arc current of 1.31 A was extrapolated from the measurement at low extraction dc voltages.

  7. Ion Stopping Powers and CT Numbers

    SciTech Connect

    Moyers, Michael F.; Sardesai, Milind; Sun, Sean; Miller, Daniel W.

    2010-10-01

    One of the advantages of ion beam therapy is the steep dose gradient produced near the ion's range. Use of this advantage makes knowledge of the stopping powers for all materials through which the beam passes critical. Most treatment planning systems calculate dose distributions using depth dose data measured in water and an algorithm that converts the kilovoltage X-ray computed tomography (CT) number of a given material to its linear stopping power relative to water. Some materials present in kilovoltage scans of patients and simulation phantoms do not lie on the standard tissue conversion curve. The relative linear stopping powers (RLSPs) of 21 different tissue substitutes and positioning, registration, immobilization, and beamline materials were measured in beams of protons accelerated to energies of 155, 200, and 250 MeV; carbon ions accelerated to 290 MeV/n; and iron ions accelerated to 970 MeV/n. These same materials were scanned with both kilovoltage and megavoltage CT scanners to obtain their CT numbers. Measured RLSPs and CT numbers were compared with calculated and/or literature values. Relationships of RLSPs to physical densities, electronic densities, kilovoltage CT numbers, megavoltage CT numbers, and water equivalence values converted by a treatment planning system are given. Usage of CT numbers and substitution of measured values into treatment plans to provide accurate patient and phantom simulations are discussed.

  8. The role of high Rydberg states in the generation of negative ions in negative-ion discharges

    SciTech Connect

    Hiskes, J.R.

    1995-11-28

    The generation of substantial yields of H{sup {minus}} ions in a laser excited H{sub 2} gas has been reported by Pinnaduwage and Christoforu. These H{sup {minus}} yields have been attributed to (2 + 1) REMP photoexcitation processes leading to dissociative attachment of doubly-excited or superexcited states (SES), or dissociative attachment of high Rydberg product states. The new feature of these experiments is the implied large dissociative attachment rates, of order 10{sup {minus}6} cm{sup 3} sec{sup {minus}1}, values that are orders-of-magnitude larger than the dissociative attachment of the vibrationally excited levels of the ground electronic state. While these laser excitations are not directly applicable to a hydrogen negative-ion discharge, the implication of large dissociative attachment rates to the high Rydberg states may affect both the total negative-ion density and the interpretation of discharge performance. Within the discharge energetic electrons will collisionally excite the higher Rydberg states, and the relative contribution of the dissociative attachment of these states when compared with the dissociative attachment to the ground state vibrational levels, is the topic of this paper.

  9. NSTAR Ion Thrusters and Power Processors

    NASA Technical Reports Server (NTRS)

    Bond, T. A.; Christensen, J. A.

    1999-01-01

    The purpose of the NASA Solar Electric Propulsion Technology Applications Readiness (NSTAR) project is to validate ion propulsion technology for use on future NASA deep space missions. This program, which was initiated in September 1995, focused on the development of two sets of flight quality ion thrusters, power processors, and controllers that provided the same performance as engineering model hardware and also met the dynamic and environmental requirements of the Deep Space 1 Project. One of the flight sets was used for primary propulsion for the Deep Space 1 spacecraft which was launched in October 1998.

  10. Perspective on the Role of Negative Ions and Ion-Ion Plasmas in Heavy Ion Fusion Science, Magnetic Fusion Energy,and Related Fields

    SciTech Connect

    Grisham, L. R.; Kwan, J. W.

    2008-08-01

    Some years ago it was suggested that halogen negative ions could offer a feasible alternative path to positive ions as a heavy ion fusion driver beam which would not suffer degradation due to electron accumulation in the accelerator and beam transport system, and which could be converted to a neutral beam by photodetachment near the chamber entrance if desired. Since then, experiments have demonstrated that negative halogen beams can be extracted and accelerated away from the gas plume near the source with a surviving current density close to what could be achieved with a positive ion of similar mass, and with comparable optical quality. In demonstrating the feasibility of halogen negative ions as heavy ion driver beams, ion - ion plasmas, an interesting and somewhat novel state of matter, were produced. These plasmas, produced near the extractor plane of the sources, appear, based upon many lines of experimental evidence, to consist of almost equal densities of positive and negative chlorine ions, with only a small component of free electrons. Serendipitously, the need to extract beams from this plasma for driver development provides a unique diagnostic tool to investigate the plasma, since each component - positive ions, negative ions, and electrons - can be extracted and measured separately. We discuss the relevance of these observations to understanding negative ion beam extraction from electronegative plasmas such as halogens, or the more familiar hydrogen of magnetic fusion ion sources. We suggest a concept which might improve negative hydrogen extraction by the addition of a halogen. The possibility and challenges of producing ion - ion plasmas with thin targets of halogens or, perhaps, salt, is briefly addressed.

  11. Perspective on the Role of Negative Ions and Ion-Ion Plasmas in Heavy Ion Fusion Science, Magnetic Fusion Energy, and Related Fields

    SciTech Connect

    Grisham, L.R.; Kwan, J.W.

    2008-08-01

    Some years ago it was suggested that halogen negative ions [1]could offer a feasible alternative path to positive ions as a heavy ion fusion driver beam which would not suffer degradation due to electron accumulation in the accelerator and beam transport system, and which could be converted to a neutral beam by photodetachment near the chamber entrance if desired. Since then, experiments have demonstrated that negative halogen beams can be extracted and accelerated away from the gas plume near the source with a surviving current density close to what could be achieved with a positive ion of similar mass, and with comparable optical quality. In demonstrating the feasibility of halogen negative ions as heavy ion driver beams, ion - ion plasmas, an interesting and somewhat novel state of matter, were produced. These plasmas, produced near the extractor plane of the sources, appear, based upon many lines of experimental evidence, to consist of almost equal densities of positive and negative chlorine ions, with only a small component of free electrons. Serendipitously, the need to extract beams from this plasma for driver development provides a unique diagnostic tool to investigate the plasma, since each component - positive ions, negative ions, and electrons -- can be extracted and measured separately. We discuss the relevance of these observations to understanding negative ion beam extraction from electronegative plasmas such as halogens, or the more familiar hydrogen of magnetic fusion ion sources. We suggest a concept which might improve negative hydrogen extraction by the addition of a halogen. The possibility and challenges of producing ion-ion plasmas with thin targets of halogens or, perhaps, salt, is briefly addressed.

  12. Perspective on the Role of Negative Ions and Ion-Ion Plasmas in Heavy Ion Fusion Science, Magnetic Fusion Energy, and Related Fields

    SciTech Connect

    L. Grisham and J.W. Kwan

    2008-08-12

    Some years ago it was suggested that halogen negative ions [1] could offer a feasible alternative path to positive ions as a heavy ion fusion driver beam which would not suffer degradation due to electron accumulation in the accelerator and beam transport system, and which could be converted to a neutral beam by photodetachment near the chamber entrance if desired. Since then, experiments have demonstrated that negative halogen beams can be extracted and accelerated away from the gas plume near the source with a surviving current density close to what could be achieved with a positive ion of similar mass, and with comparable optical quality. In demonstrating the feasibility of halogen negative ions as heavy ion driver beams, ion - ion plasmas, an interesting and somewhat novel state of matter, were produced. These plasmas, produced near the extractor plane of the sources, appear, based upon many lines of experimental evidence, to consist of almost equal densities of positive and negative chlorine ions, with only a small component of free electrons. Serendipitously, the need to extract beams from this plasma for driver development provides a unique diagnostic tool to investigate the plasma, since each component - positive ions, negative ions, and electrons -- can be extracted and measured separately. We discuss the relevance of these observations to understanding negative ion beam extraction from electronegative plasmas such as halogens, or the more familiar hydrogen of magnetic fusion ion sources. We suggest a concept which might improve negative hydrogen extraction by the addition of a halogen. The possibility and challenges of producing ion-ion plasmas with thin targets of halogens or, perhaps, salt, is briefly addressed.

  13. Alternative solutions to caesium in negative-ion sources: a study of negative-ion surface production on diamond in H2/D2 plasmas

    NASA Astrophysics Data System (ADS)

    Cartry, Gilles; Kogut, Dmitry; Achkasov, Kostiantyn; Layet, Jean-Marc; Farley, Thomas; Gicquel, Alix; Achard, Jocelyn; Brinza, Ovidiu; Bieber, Thomas; Khemliche, Hocine; Roncin, Philippe; Simonin, Alain

    2017-02-01

    This paper deals with a study of H‑/D‑ negative ion surface production on diamond in low pressure H2/D2 plasmas. A sample placed in the plasma is negatively biased with respect to plasma potential. Upon positive ion impacts on the sample, some negative ions are formed and detected according to their mass and energy by a mass spectrometer placed in front of the sample. The experimental methods developed to study negative ion surface production and obtain negative ion energy and angle distribution functions are first presented. Different diamond materials ranging from nanocrystalline to single crystal layers, either doped with boron or intrinsic, are then investigated and compared with graphite. The negative ion yields obtained are presented as a function of different experimental parameters such as the exposure time, the sample bias which determines the positive ion impact energy and the sample surface temperature. It is concluded from these experiments that the electronic properties of diamond materials, among them the negative electron affinity, seem to be favourable for negative-ion surface production. However, the negative ion yield decreases with the plasma induced defect density.

  14. Negative ion production and beam extraction processes in a large ion source (invited)

    SciTech Connect

    Tsumori, K. Nakano, H.; Goto, M.; Nagaoka, K.; Osakabe, M.; Takeiri, Y.; Kaneko, O.; Ikeda, K.; Kisaki, M.; Geng, S.; Wada, M.; Sasaki, K.; Nishiyama, S.; Serianni, G.; Agostinetti, P.; Sartori, E.; Brombin, M.; Veltri, P.; Wimmer, C.

    2016-02-15

    Recent research results on negative-ion-rich plasmas in a large negative ion source have been reviewed. Spatial density and flow distributions of negative hydrogen ions (H{sup −}) and positive hydrogen ions together with those of electrons are investigated with a 4-pin probe and a photodetachment (PD) signal of a Langmuir probe. The PD signal is converted to local H{sup −} density from signal calibration to a scanning cavity ring down PD measurement. Introduction of Cs changes the slope of plasma potential local distribution depending upon the plasma grid bias. A higher electron density H{sub 2} plasma locally shields the bias potential and behaves like a metallic free electron gas. On the other hand, the bias and extraction electric fields penetrate in a Cs-seeded electronegative plasma even when the electron density is similar. Electrons are transported by the penetrated electric fields from the driver region along and across the filter and electron deflection magnetic fields. Plasma ions exhibited a completely different response against the penetration of electric fields.

  15. Bimolecular reaction dynamics from photoelectron spectroscopy of negative ions

    SciTech Connect

    Bradforth, S.E.

    1992-11-01

    The transition state region of a neutral bimolecular reaction may be experimentally investigated by photoelectron spectroscopy of an appropriate negative ion. The photoelectron spectrum provides information on the spectroscopy and dynamics of the short lived transition state and may be used to develop model potential energy surfaces that are semi-quantitative in this important region. The principles of bound {yields} bound negative ion photoelectron spectroscopy are illustrated by way of an example: a full analysis of the photoelectron bands of CN{sup {minus}}, NCO{sup {minus}} and NCS{sup {minus}}. Transition state photoelectron spectra are presented for the following systems Br + HI, Cl + HI, F + HI, F + CH{sub 3}0H,F + C{sub 2}H{sub 5}OH,F + OH and F + H{sub 2}. A time dependent framework for the simulation and interpretation of the bound {yields} free transition state photoelectron spectra is subsequently developed and applied to the hydrogen transfer reactions Br + HI, F + OH {yields} O({sup 3}P, {sup 1}D) + HF and F + H{sub 2}. The theoretical approach for the simulations is a fully quantum-mechanical wave packet propagation on a collinear model reaction potential surface. The connection between the wavepacket time evolution and the photoelectron spectrum is given by the time autocorrelation function. For the benchmark F + H{sub 2} system, comparisons with three-dimensional quantum calculations are made.

  16. Study of negative ion transport phenomena in a plasma source

    NASA Astrophysics Data System (ADS)

    Riz, D.; Paméla, J.

    1996-07-01

    NIETZSCHE (Negative Ions Extraction and Transport ZSimulation Code for HydrogEn species) is a negative ion (NI) transport code developed at Cadarache. This code calculates NI trajectories using a 3D Monte-Carlo technique, taking into account the main destruction processes, as well as elastic collisions (H-/H+) and charge exchanges (H-/H0). It determines the extraction probability of a NI created at a given position. According to the simulations, we have seen that in the case of volume production, only NI produced close to the plasma grid (PG) can be extracted. Concerning the surface production, we have studied how NI produced on the PG and accelerated by the plasma sheath backward into the source could be extracted. We demonstrate that elastic collisions and charge exchanges play an important role, which in some conditions dominates the magnetic filter effect, which acts as a magnetic mirror. NI transport in various conditions will be discussed: volume/surface production, high/low plasmas density, tent filter/transverse filter.

  17. Chemical Properties of Dipole-Bound Negative Ions

    NASA Astrophysics Data System (ADS)

    Liu, Y.

    2005-05-01

    In dipole bound negative ions the extra electron is weakly bound by the dipole potential of the neutral molecule in a diffuse orbital localized near the positive end of the dipole. In consequence, it is reasonable to expect that such species will be highly reactive and possess chemical properties similar to those of Rydberg atoms, which also contain a weakly-bound electron in a diffuse orbital. These properties are being examined using a negative ion Penning trap. Data for electron transfer in collisions with attaching targets such as SF6 show that the rate constants for this process are large, ˜ 10-7 cm^3 s-1, and similar to those for free electron attachment. This suggests that collisions can be described in terms of an essentially-free electron model. This is further reinforced by the observation that rotational energy transfer in collisions with polar molecules can lead to rapid electron detachment, again with large rate constants of ˜ 10 -7 cm^3 s-1. Results for several target species will be presented and discussed in light of a free electron model.

  18. Observation of a shape resonance of the positronium negative ion

    PubMed Central

    Michishio, Koji; Kanai, Tsuneto; Kuma, Susumu; Azuma, Toshiyuki; Wada, Ken; Mochizuki, Izumi; Hyodo, Toshio; Yagishita, Akira; Nagashima, Yasuyuki

    2016-01-01

    When an electron binds to its anti-matter counterpart, the positron, it forms the exotic atom positronium (Ps). Ps can further bind to another electron to form the positronium negative ion, Ps− (e−e+e−). Since its constituents are solely point-like particles with the same mass, this system provides an excellent testing ground for the three-body problem in quantum mechanics. While theoretical works on its energy level and dynamics have been performed extensively, experimental investigations of its characteristics have been hampered by the weak ion yield and short annihilation lifetime. Here we report on the laser spectroscopy study of Ps−, using a source of efficiently produced ions, generated from the bombardment of slow positrons onto a Na-coated W surface. A strong shape resonance of 1Po symmetry has been observed near the Ps (n=2) formation threshold. The resonance energy and width measured are in good agreement with the result of three-body calculations. PMID:26983496

  19. Negative ion gas-phase chemistry of arenes.

    PubMed

    Danikiewicz, Witold; Zimnicka, Magdalena

    2016-01-01

    Reactions of aromatic and heteroaromatic compounds involving anions are of great importance in organic synthesis. Some of these reactions have been studied in the gas phase and are occasionally mentioned in reviews devoted to gas-phase negative ion chemistry, but no reviews exist that collect all existing information about these reactions. This work is intended to fill this gap. In the first part of this review, methods for generating arene anions in the gas phase and studying their physicochemical properties and fragmentation reactions are presented. The main topics in this part are as follows: processes in which gas-phase arene anions are formed, measurements and calculations of the proton affinities of arene anions, proton exchange reactions, and fragmentation processes of substituted arene anions, especially phenide ions. The second part is devoted to gas-phase reactions of arene anions. The most important of these are reactions with electrophiles such as carbonyl compounds and α,β-unsaturated carbonyl and related compounds (Michael acceptors). Other reactions including oxidation of arene anions and halogenophilic reactions are also presented. In the last part of the review, reactions of electrophilic arenes with nucleophiles are discussed. The best known of these is the aromatic nucleophilic substitution (SN Ar) reaction; however, other processes that lead to the substitution of a hydrogen atom in the aromatic ring are also very important. Aromatic substrates in these reactions are usually but not always nitroarenes bearing other substituents in the ring. The first step in these reactions is the formation of an anionic σ-adduct, which, depending on the substituents in the aromatic ring and the structure of the attacking nucleophile, is either an intermediate or a transition state in the reaction path. In the present review, we attempted to collect the results of both experimental and computational studies of the aforementioned reactions conducted since the

  20. Actively cooled plasma electrode for long pulse operations in a cesium-seeded negative ion source

    NASA Astrophysics Data System (ADS)

    Fujiwara, Yukio; Watanabe, Kazuhiro; Okumura, Yoshikazu; Trainham, Rusty; Jacquot, Claude

    2005-01-01

    An actively cooled plasma electrode has been developed for long pulse operation in a cesium-seeded negative ion source. To keep the electrode temperature at about 300°C, which is the optimum range of temperature to enhance cesium effects, the electrode cooling structure has been designed using three-dimensional numerical simulation assuming that the heat flux from the source plasma was 15W/cm2. Water cooling tubes were brazed to the plasma electrode substrate with spacers made of stainless steel, which acts as a thermal resistance. The fabricated plasma electrode has been tested in a cesium-seeded volume negative ion source called Kamaboko source. The temperature of the electrode reached 280°C for the arc power of 41kW, which is the operating condition required for producing D- beams with current densities exceeding 20mA/cm2. It was demonstrated that the actively cooled plasma electrode is applicable to long pulse operations, meeting the temperature requirement for optimizing the surface-production process of negative ions in the cesium-seeded ion source.

  1. Method and apparatus for efficient photodetachment and purification of negative ion beams

    DOEpatents

    Beene, James R [Oak Ridge, TN; Liu, Yuan [Knoxville, TN; Havener, Charles C [Knoxville, TN

    2008-02-26

    Methods and apparatus are described for efficient photodetachment and purification of negative ion beams. A method of purifying an ion beam includes: inputting the ion beam into a gas-filled multipole ion guide, the ion beam including a plurality of ions; increasing a laser-ion interaction time by collisional cooling the plurality of ions using the gas-filled multipole ion guide, the plurality of ions including at least one contaminant; and suppressing the at least one contaminant by selectively removing the at least one contaminant from the ion beam by electron photodetaching at least a portion of the at least one contaminant using a laser beam.

  2. Simulating Negative Pickup Ions and Ion Cyclotron Wave Generation at Europa (Invited)

    NASA Astrophysics Data System (ADS)

    Desai, R. T.; Cowee, M.; Gary, S. P.; Wei, H.; Coates, A. J.; Kataria, D. O.; Fu, X.

    2015-12-01

    The mass loading of space environments through the ionisation of planetary atmospheres is a fundamental process governing the plasma interactions and long term evolution of celestial bodies across the solar system. Regions containing significant pickup ion populations have been observed to exhibit a rich variety of electromagnetic plasma wave phenomena, the characteristics and properties of which can be used to infer the ion species present, their spatial and temporal distributions, and the global ionisation rates of the neutral material. In this study we present hybrid (kinetic ion, massless fluid electron) simulations of ion pickup and Ion Cyclotron (IC) waves observed in the Jovian magnetosphere and draw comparisons to sub-alfvénic pickup observed by Cassini in the Saturnian system, and also to supra-alfvénic pickup at planetary bodies immersed directly in the solar wind. At Jupiter, Europa has been identified as the secondary mass loader in the magnetosphere, orbiting within a neutral gas torus at ~9.38 Rj. Near Europa, Galileo magnetometer observations displayed bursty IC wave characteristics at the gyrofrequency of a number of species including SO2, K, Cl, O2, and Na, suggesting a complex mass loading environment. A particular deduction from the dataset was the presence of both positively and negatively charged pickup ions, inferred from the left and right hand polarisations of the transverse waves. Using hybrid simulations for both positively and negatively charged Cl pickup ions we are able to self-consistently reproduce the growth of both right and left hand near-circularly polarised waves in agreement with linear theory and, using the observed wave amplitudes, estimate Cl pickup ion densities at Europa.

  3. An experimental study of waveguide coupled microwave heating with conventional multicusp negative ion sources

    SciTech Connect

    Komppula, J.; Kalvas, T.; Koivisto, H.; Laulainen, J.; Tarvainen, O.

    2015-04-08

    Negative ion production with conventional multicusp plasma chambers utilizing 2.45 GHz microwave heating is demonstrated. The experimental results were obtained with the multicusp plasma chambers and extraction systems of the RF-driven RADIS ion source and the filament driven arc discharge ion source LIISA. A waveguide microwave coupling system, which is almost similar to the one used with the SILHI ion source, was used. The results demonstrate that at least one third of negative ion beam obtained with inductive RF-coupling (RADIS) or arc discharge (LIISA) can be achieved with 1 kW of 2.45 GHz microwave power in CW mode without any modification of the plasma chamber. The co-extracted electron to H{sup −} ratio and the optimum pressure range were observed to be similar for both heating methods. The behaviour of the plasma implies that the energy transfer from the microwaves to the plasma electrons is mainly an off-resonance process.

  4. Electrostatic Power Generation from Negatively Charged, Simulated Lunar Regolith

    NASA Technical Reports Server (NTRS)

    Choi, Sang H.; King, Glen C.; Kim, Hyun-Jung; Park, Yeonjoon

    2010-01-01

    Research was conducted to develop an electrostatic power generator for future lunar missions that facilitate the utilization of lunar resources. The lunar surface is known to be negatively charged from the constant bombardment of electrons and protons from the solar wind. The resulting negative electrostatic charge on the dust particles, in the lunar vacuum, causes them to repel each other minimizing the potential. The result is a layer of suspended dust about one meter above the lunar surface. This phenomenon was observed by both Clementine and Surveyor spacecrafts. During the Apollo 17 lunar landing, the charged dust was a major hindrance, as it was attracted to the astronauts' spacesuits, equipment, and the lunar buggies. The dust accumulated on the spacesuits caused reduced visibility for the astronauts, and was unavoidably transported inside the spacecraft where it caused breathing irritation [1]. In the lunar vacuum, the maximum charge on the particles can be extremely high. An article in the journal "Nature", titled "Moon too static for astronauts?" (Feb 2, 2007) estimates that the lunar surface is charged with up to several thousand volts [2]. The electrostatic power generator was devised to alleviate the hazardous effects of negatively charged lunar soil by neutralizing the charged particles through capacitive coupling and thereby simultaneously harnessing power through electric charging [3]. The amount of power generated or collected is dependent on the areal coverage of the device and hovering speed over the lunar soil surface. A thin-film array of capacitors can be continuously charged and sequentially discharged using a time-differentiated trigger discharge process to produce a pulse train of discharge for DC mode output. By controlling the pulse interval, the DC mode power can be modulated for powering devices and equipment. In conjunction with a power storage system, the electrostatic power generator can be a power source for a lunar rover or other

  5. Experimental studies of the Negative Ion of Hydrogen. Final Report

    SciTech Connect

    Bryant, Howard C.

    1999-06-30

    This document presents an overview of the results of the DOE'S support of experimental research into the structure and interactions of the negative ion of hydrogen conducted by the Department of Physics and Astronomy of the University of New Mexico at the Los Alamos National Laboratory. The work involves many collaborations with scientists from both institutions, as well as others. Although official DOE support for this work began in 1977, the experiment that led to it was done in 1971, near the time the 800 MeV linear accelerator at Los Alamos (LAMPF) first came on line. Until the mid nineties, the work was performed using the relativistic beam at LAMFF. The most recent results were obtained using the 35 keV injector beam for the Ground Test Accelerator at Los Alamos. A list of all published results from this work is presented.

  6. High-Resolution Laser Spectroscopy on the Negative Osmium Ion

    SciTech Connect

    Warring, U.; Amoretti, M.; Canali, C.; Fischer, A.; Heyne, R.; Meier, J. O.; Morhard, Ch.; Kellerbauer, A.

    2009-01-30

    We have applied a combination of laser excitation and electric-field detachment to negative atomic ions for the first time, resulting in an enhancement of the excited-state detection efficiency for spectroscopy by at least 2 orders of magnitude. Applying the new method, a measurement of the bound-bound electric-dipole transition frequency in {sup 192}Os{sup -} was performed using collinear spectroscopy with a narrow-bandwidth cw laser. The transition frequency was found to be 257.831 190(35) THz [wavelength 1162.747 06(16) nm, wave number 8600.3227(12) cm{sup -1}], in agreement with the only prior measurement, but with more than 100-fold higher precision.

  7. Fragmentation of negative ions in a strong laser field

    NASA Astrophysics Data System (ADS)

    Berry, Ben; Jochim, Bethany; Severt, T.; Feizollah, Peyman; Rajput, Jyoti; Hayes, D.; Carnes, K. D.; Esry, B. D.; Ben-Itzhak, I.

    2016-05-01

    The fragmentation of negative ions in a strong laser field can provide a testing ground for a variety of unique phenomena. For example, anions with a loosely bound electron allow for the study of rescattering phenomena at lower laser intensities than for neutral targets. We study the behavior of keV anion beams in an ultrafast, intense laser field. The use of a fast-beam target facilitates the measurement of neutral fragments. This capability allows us to explore laser-induced dynamics in both ionic and neutral charge states. Using a coincidence 3D momentum imaging technique, we obtain the full 3D momentum of all nuclear fragments. In this preliminary work, we study atomic (H-) and molecular (H2-,F2-)systems with the goal of identifying and controlling their fragmentation pathways. This work was supported by the Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy.

  8. Improvement of uniformity of the negative ion beams by tent-shaped magnetic field in the JT-60 negative ion source

    NASA Astrophysics Data System (ADS)

    Yoshida, Masafumi; Hanada, Masaya; Kojima, Atsushi; Kashiwagi, Mieko; Grisham, Larry R.; Akino, Noboru; Endo, Yasuei; Komata, Masao; Mogaki, Kazuhiko; Nemoto, Shuji; Ohzeki, Masahiro; Seki, Norikazu; Sasaki, Shunichi; Shimizu, Tatsuo; Terunuma, Yuto

    2014-02-01

    Non-uniformity of the negative ion beams in the JT-60 negative ion source with the world-largest ion extraction area was improved by modifying the magnetic filter in the source from the plasma grid (PG) filter to a tent-shaped filter. The magnetic design via electron trajectory calculation showed that the tent-shaped filter was expected to suppress the localization of the primary electrons emitted from the filaments and created uniform plasma with positive ions and atoms of the parent particles for the negative ions. By modifying the magnetic filter to the tent-shaped filter, the uniformity defined as the deviation from the averaged beam intensity was reduced from 14% of the PG filter to ˜10% without a reduction of the negative ion production.

  9. Improvement of uniformity of the negative ion beams by tent-shaped magnetic field in the JT-60 negative ion source

    SciTech Connect

    Yoshida, Masafumi Hanada, Masaya; Kojima, Atsushi; Kashiwagi, Mieko; Akino, Noboru; Endo, Yasuei; Komata, Masao; Mogaki, Kazuhiko; Nemoto, Shuji; Ohzeki, Masahiro; Seki, Norikazu; Sasaki, Shunichi; Shimizu, Tatsuo; Terunuma, Yuto; Grisham, Larry R.

    2014-02-15

    Non-uniformity of the negative ion beams in the JT-60 negative ion source with the world-largest ion extraction area was improved by modifying the magnetic filter in the source from the plasma grid (PG) filter to a tent-shaped filter. The magnetic design via electron trajectory calculation showed that the tent-shaped filter was expected to suppress the localization of the primary electrons emitted from the filaments and created uniform plasma with positive ions and atoms of the parent particles for the negative ions. By modifying the magnetic filter to the tent-shaped filter, the uniformity defined as the deviation from the averaged beam intensity was reduced from 14% of the PG filter to ∼10% without a reduction of the negative ion production.

  10. Improvement of uniformity of the negative ion beams by tent-shaped magnetic field in the JT-60 negative ion source.

    PubMed

    Yoshida, Masafumi; Hanada, Masaya; Kojima, Atsushi; Kashiwagi, Mieko; Grisham, Larry R; Akino, Noboru; Endo, Yasuei; Komata, Masao; Mogaki, Kazuhiko; Nemoto, Shuji; Ohzeki, Masahiro; Seki, Norikazu; Sasaki, Shunichi; Shimizu, Tatsuo; Terunuma, Yuto

    2014-02-01

    Non-uniformity of the negative ion beams in the JT-60 negative ion source with the world-largest ion extraction area was improved by modifying the magnetic filter in the source from the plasma grid (PG) filter to a tent-shaped filter. The magnetic design via electron trajectory calculation showed that the tent-shaped filter was expected to suppress the localization of the primary electrons emitted from the filaments and created uniform plasma with positive ions and atoms of the parent particles for the negative ions. By modifying the magnetic filter to the tent-shaped filter, the uniformity defined as the deviation from the averaged beam intensity was reduced from 14% of the PG filter to ∼10% without a reduction of the negative ion production.

  11. Recent Progress in the Negative-Ion-Based Neutral Beam Injectors in Large Helical Device

    SciTech Connect

    Takeiri, Y.; Tsumori, K.; Ikeda, K.; Osakabe, M.; Nagaoka, K.; Oka, Y.; Asano, E.; Kondo, T.; Sato, M.; Shibuya, M.; Komada, S.; Kaneko, O.

    2009-03-12

    Negative-ion-based neutral beam injection (negative-NBI) system has been operated for 10 years in Large Helical Device (LHD). The injection power has been increased year by year, according to the improvement of the negative ion sources. Up to now, every injector achieves the designed injection energy and power of 180 keV-5 MW with hydrogen beams, and the total injection power exceeds 16 MW with three injectors. In the multi-round aperture grounded grid (GG), the diameter of a round aperture has been enlarged for higher GG transparency. Then, the GG heat load is reduced, as well as in the multi-slotted GG, and the voltage holding ability in the beam acceleration was improved. As a result, the beam energy is raised and the injection power is increased. To improve the anisotropic property of the beamlet convergence condition between the perpendicular and the parallel directions to the slots in the multi-slotted GG, a round-shape aperture of the steering grid (SG) has been changed to a racetrack shape. As a result, the difference of the beamlet conversion condition is much mitigated, and the injection efficiency (port-transmission efficiency) is improved, leading to 188 keV-6.4 MW injection. The Cs consumption is observed to be proportional to the tungsten evaporation from filaments. The Cs behavior is investigated with optical emission spectroscopy. During the beam extraction, the Cs recycling is dominated by Cs on the backplate, which is evaporated into the plasma by the backstreaming positive ions, and the wall surfaces should be loss regions for the supplied Cs.

  12. Recent Progress in the Negative-Ion-Based Neutral Beam Injectors in Large Helical Device

    NASA Astrophysics Data System (ADS)

    Takeiri, Y.; Tsumori, K.; Ikeda, K.; Osakabe, M.; Nagaoka, K.; Oka, Y.; Asano, E.; Kondo, T.; Sato, M.; Shibuya, M.; Komada, S.; Kaneko, O.

    2009-03-01

    Negative-ion-based neutral beam injection (negative-NBI) system has been operated for 10 years in Large Helical Device (LHD). The injection power has been increased year by year, according to the improvement of the negative ion sources. Up to now, every injector achieves the designed injection energy and power of 180 keV-5 MW with hydrogen beams, and the total injection power exceeds 16 MW with three injectors. In the multi-round aperture grounded grid (GG), the diameter of a round aperture has been enlarged for higher GG transparency. Then, the GG heat load is reduced, as well as in the multi-slotted GG, and the voltage holding ability in the beam acceleration was improved. As a result, the beam energy is raised and the injection power is increased. To improve the anisotropic property of the beamlet convergence condition between the perpendicular and the parallel directions to the slots in the multi-slotted GG, a round-shape aperture of the steering grid (SG) has been changed to a racetrack shape. As a result, the difference of the beamlet conversion condition is much mitigated, and the injection efficiency (port-transmission efficiency) is improved, leading to 188 keV-6.4 MW injection. The Cs consumption is observed to be proportional to the tungsten evaporation from filaments. The Cs behavior is investigated with optical emission spectroscopy. During the beam extraction, the Cs recycling is dominated by Cs on the backplate, which is evaporated into the plasma by the backstreaming positive ions, and the wall surfaces should be loss regions for the supplied Cs.

  13. Negative ion photodetachment and the electron effective mass in liquids

    SciTech Connect

    Baird, J.K.

    1983-07-01

    The electron photodetachment cross section for a negative ion in the gas phase is compared with the photodetachment cross section for the same ion when it is dissolved in a liquid supporting ''free'' electron propagation. The ratio of the amplitudes of these two cross sections near threshold is found to depend upon the effective mass m* of an electron in the conduction band of the liquid. We apply this result to electron photodetachment from O/sub 2//sup -/. In terms of the electron's free mass m, we find for liquid argon at 87 K (m* = 0.26 m), 2,2-dimethylbutane at 296 K (m* = 0.27 m), 2,2,4-trimethylpentane at 296 K (m* = 0.27 m), and tetramethylsilane at 296 K (m* = 0.27 m). At 200 K, the effective mass in tetramethylsilane decreases to m* = 0.21 m. In the case of liquid argon, the effective mass calculated herein agrees qualitatively with values which can be estimated from measurements of the electron mobility and exciton spectrum.

  14. Independent-particle models for light negative atomic ions

    NASA Technical Reports Server (NTRS)

    Ganas, P. S.; Talman, J. D.; Green, A. E. S.

    1980-01-01

    For the purposes of astrophysical, aeronomical, and laboratory application, a precise independent-particle model for electrons in negative atomic ions of the second and third period is discussed. The optimum-potential model (OPM) of Talman et al. (1979) is first used to generate numerical potentials for eight of these ions. Results for total energies and electron affinities are found to be very close to Hartree-Fock solutions. However, the OPM and HF electron affinities both depart significantly from experimental affinities. For this reason, two analytic potentials are developed whose inner energy levels are very close to the OPM and HF levels but whose last electron eigenvalues are adjusted precisely with the magnitudes of experimental affinities. These models are: (1) a four-parameter analytic characterization of the OPM potential and (2) a two-parameter potential model of the Green, Sellin, Zachor type. The system O(-) or e-O, which is important in upper atmospheric physics is examined in some detail.

  15. Single element of the matrix source of negative hydrogen ions: Measurements of the extracted currents combined with diagnostics

    SciTech Connect

    Yordanov, D. Lishev, St.; Shivarova, A.

    2016-02-15

    Combining measurements of the extracted currents with probe and laser-photodetachment diagnostics, the study is an extension of recent tests of factors and gas-discharge conditions stimulating the extraction of volume produced negative ions. The experiment is in a single element of a rf source with the design of a matrix of small-radius inductively driven discharges. The results are for the electron and negative-ion densities, for the plasma potential and for the electronegativity in the vicinity of the plasma electrode as well as for the currents of the extracted negative ions and electrons. The plasma-electrode bias and the rf power have been varied. Necessity of a high bias to the plasma electrode and stable linear increase of the extracted currents with the rf power are the main conclusions.

  16. Dust negative ion acoustic shock waves in a dusty multi-ion plasma with positive dust charging current

    SciTech Connect

    Duha, S. S.

    2009-11-15

    Recent analysis of Mamun et al.[ Phys. Lett. A 373, 2355 (2009)], who considered electrons, light positive ions, heavy negative ions, and extremely massive (few micron size) charge fluctuating dust, has been extended by positive dust charging current, i.e., considering the charging currents for positively charged dust grains. A dusty multi-ion plasma system consisting of electrons, light positive ions, negative ions, and extremely massive (few micron size) charge fluctuating stationary dust have been considered. The electrostatic shock waves associated with negative ion dynamics and dust charge fluctuation have been investigated by employing the reductive perturbation method. It has been shown that the dust charge fluctuation is a source of dissipation and is responsible for the formation of dust negative ion acoustic (DNIA) shock structures. The basic features of such DNIA shock structures have been identified. The findings of this investigation may be useful in understanding the laboratory phenomena and space dusty plasmas.

  17. Comparison of measured and modelled negative hydrogen ion densities at the ECR-discharge HOMER

    SciTech Connect

    Rauner, D.; Kurutz, U.; Fantz, U.

    2015-04-08

    As the negative hydrogen ion density n{sub H{sup −}} is a key parameter for the investigation of negative ion sources, its diagnostic quantification is essential in source development and operation as well as for fundamental research. By utilizing the photodetachment process of negative ions, generally two different diagnostic methods can be applied: via laser photodetachment, the density of negative ions is measured locally, but only relatively to the electron density. To obtain absolute densities, the electron density has to be measured additionally, which induces further uncertainties. Via cavity ring-down spectroscopy (CRDS), the absolute density of H{sup −} is measured directly, however LOS-averaged over the plasma length. At the ECR-discharge HOMER, where H{sup −} is produced in the plasma volume, laser photodetachment is applied as the standard method to measure n{sub H{sup −}}. The additional application of CRDS provides the possibility to directly obtain absolute values of n{sub H{sup −}}, thereby successfully bench-marking the laser photodetachment system as both diagnostics are in good agreement. In the investigated pressure range from 0.3 to 3 Pa, the measured negative hydrogen ion density shows a maximum at 1 to 1.5 Pa and an approximately linear response to increasing input microwave powers from 200 up to 500 W. Additionally, the volume production of negative ions is 0-dimensionally modelled by balancing H{sup −} production and destruction processes. The modelled densities are adapted to the absolute measurements of n{sub H{sup −}} via CRDS, allowing to identify collisions of H{sup −} with hydrogen atoms (associative and non-associative detachment) to be the dominant loss process of H{sup −} in the plasma volume at HOMER. Furthermore, the characteristic peak of n{sub H{sup −}} observed at 1 to 1.5 Pa is identified to be caused by a comparable behaviour of the electron density with varying pressure, as n{sub e} determines

  18. First experiments with Cs doped Mo as surface converter for negative hydrogen ion sources

    SciTech Connect

    Schiesko, L. Hopf, C.; Höschen, T.; Meisl, G.; Encke, O.; Heinemann, B.; Fantz, U.; Cartry, G.; Amsalem, P.; Achkasov, K.

    2015-08-21

    A study was conducted on the properties of molybdenum implanted with caesium as an approach to reduce the Cs consumption of negative hydrogen ion sources based on evaporated Cs. The depth profiles of the implanted Cs were simulated by SDTrimSP and experimentally determined by X-ray photoelectron spectroscopy depth profiling. In particular, one year after implantation, the depth profiles showed no signs of Cs diffusion into the molybdenum, suggesting long term stability of the implanted Cs atoms. The H{sup −} surface generation mechanisms on the implanted samples in hydrogen plasma were investigated, and the stability of the H{sup −} yield during four hours low power hydrogen plasma discharges was demonstrated. An estimation of the work function reduction (−0.8 eV) by the Cs implantation was performed, and a comparison of the relative negative ion yields between the implanted samples and highly oriented pyrolitic graphite showed that the Cs doped Mo negative ion yield was larger.

  19. A set of powerful negative selection systems for unmodified Enterobacteriaceae.

    PubMed

    Khetrapal, Varnica; Mehershahi, Kurosh; Rafee, Shazmina; Chen, Siyi; Lim, Chiew Ling; Chen, Swaine L

    2015-07-27

    Creation of defined genetic mutations is a powerful method for dissecting mechanisms of bacterial disease; however, many genetic tools are only developed for laboratory strains. We have designed a modular and general negative selection strategy based on inducible toxins that provides high selection stringency in clinical Escherichia coli and Salmonella isolates. No strain- or species-specific optimization is needed, yet this system achieves better selection stringency than all previously reported negative selection systems usable in unmodified E. coli strains. The high stringency enables use of negative instead of positive selection in phage-mediated generalized transduction and also allows transfer of alleles between arbitrary strains of E. coli without requiring phage. The modular design should also allow further extension to other bacteria. This negative selection system thus overcomes disadvantages of existing systems, enabling definitive genetic experiments in both lab and clinical isolates of E. coli and other Enterobacteriaceae.

  20. A set of powerful negative selection systems for unmodified Enterobacteriaceae

    PubMed Central

    Khetrapal, Varnica; Mehershahi, Kurosh; Rafee, Shazmina; Chen, Siyi; Lim, Chiew Ling; Chen, Swaine L.

    2015-01-01

    Creation of defined genetic mutations is a powerful method for dissecting mechanisms of bacterial disease; however, many genetic tools are only developed for laboratory strains. We have designed a modular and general negative selection strategy based on inducible toxins that provides high selection stringency in clinical Escherichia coli and Salmonella isolates. No strain- or species-specific optimization is needed, yet this system achieves better selection stringency than all previously reported negative selection systems usable in unmodified E. coli strains. The high stringency enables use of negative instead of positive selection in phage-mediated generalized transduction and also allows transfer of alleles between arbitrary strains of E. coli without requiring phage. The modular design should also allow further extension to other bacteria. This negative selection system thus overcomes disadvantages of existing systems, enabling definitive genetic experiments in both lab and clinical isolates of E. coli and other Enterobacteriaceae. PMID:25800749

  1. Scaling of Ion Thrusters to Low Power

    NASA Technical Reports Server (NTRS)

    Patterson, Michael J.; Grisnik, Stanley P.; Soulas, George C.

    1998-01-01

    Analyses were conducted to examine ion thruster scaling relationships in detail to determine performance limits, and lifetime expectations for thruster input power levels below 0.5 kW. This was motivated by mission analyses indicating the potential advantages of high performance, high specific impulse systems for small spacecraft. The design and development status of a 0.1-0.3 kW prototype small thruster and its components are discussed. Performance goals include thruster efficiencies on the order of 40% to 54% over a specific impulse range of 2000 to 3000 seconds, with a lifetime in excess of 8000 hours at full power. Thruster technologies required to achieve the performance and lifetime targets are identified.

  2. The power to resist: the relationship between power, stigma, and negative symptoms in schizophrenia.

    PubMed

    Campellone, Timothy R; Caponigro, Janelle M; Kring, Ann M

    2014-02-28

    Stigmatizing beliefs about mental illness can be a daily struggle for people with schizophrenia. While investigations into the impact of internalizing stigma on negative symptoms have yielded mixed results, resistance to stigmatizing beliefs has received little attention. In this study, we examined the linkage between internalized stigma, stigma resistance, negative symptoms, and social power, or perceived ability to influence others during social interactions among people with schizophrenia. Further, we sought to determine whether resistance to stigma would be bolstered by social power, with greater power in relationships with other possibly buffering against motivation/pleasure negative symptoms. Fifty-one people with schizophrenia or schizoaffective disorder completed measures of social power, internalized stigma, and stigma resistance. Negative symptoms were assessed using the Clinical Assessment Interview for Negative Symptoms (CAINS). Greater social power was associated with less internalized stigma and negative symptoms as well as more stigma resistance. Further, the relationship between social power and negative symptoms was partially mediated by stigma resistance. These findings provide evidence for the role of stigma resistance as a viable target for psychosocial interventions aimed at improving motivation and social power in people with schizophrenia.

  3. Stopping power of charged particles due to ion wave excitations.

    PubMed

    Nitta, H; Muroki, C; Nambu, M

    2002-08-01

    Stopping power due to ion wave excitations is derived for a charged particle moving in a two-component plasma. Unlike previous theories based on ion-acoustic-wave approximation (IAWA), the excitation of short-wavelength ion waves is taken into account. The obtained stopping power has a magnitude larger than that of IAWA. Stopping power at subsonic velocities, where stopping power in IAWA disappears, is even larger than that of supersonic velocities.

  4. Stopping power of charged particles due to ion wave excitations

    NASA Astrophysics Data System (ADS)

    Nitta, H.; Muroki, C.; Nambu, M.

    2002-08-01

    Stopping power due to ion wave excitations is derived for a charged particle moving in a two-component plasma. Unlike previous theories based on ion-acoustic-wave approximation (IAWA), the excitation of short-wavelength ion waves is taken into account. The obtained stopping power has a magnitude larger than that of IAWA. Stopping power at subsonic velocities, where stopping power in IAWA disappears, is even larger than that of supersonic velocities.

  5. High-Power Ion Thruster Technology

    NASA Technical Reports Server (NTRS)

    Beattie, J. R.; Matossian, J. N.

    1996-01-01

    Performance data are presented for the NASA/Hughes 30-cm-diam 'common' thruster operated over the power range from 600 W to 4.6 kW. At the 4.6-kW power level, the thruster produces 172 mN of thrust at a specific impulse of just under 4000 s. Xenon pressure and temperature measurements are presented for a 6.4-mm-diam hollow cathode operated at emission currents ranging from 5 to 30 A and flow rates of 4 sccm and 8 sccm. Highly reproducible results show that the cathode temperature is a linear function of emission current, ranging from approx. 1000 C to 1150 C over this same current range. Laser-induced fluorescence (LIF) measurements obtained from a 30-cm-diam thruster are presented, suggesting that LIF could be a valuable diagnostic for real-time assessment of accelerator-arid erosion. Calibration results of laminar-thin-film (LTF) erosion badges with bulk molybdenum are presented for 300-eV xenon, krypton, and argon sputtering ions. Facility-pressure effects on the charge-exchange ion current collected by 8-cm-diam and 30-cm-diam thrusters operated on xenon propellant are presented to show that accel current is nearly independent of facility pressure at low pressures, but increases rapidly under high-background-pressure conditions.

  6. NSTAR Ion Propulsion System Power Electronics

    NASA Technical Reports Server (NTRS)

    1996-01-01

    The NASA Solar Electric Propulsion Technology Application Readiness (NSTAR) program, managed by the Jet Propulsion Laboratory (JPL), is currently developing a high performance, simplified ion propulsion system. This propulsion system, which is throttleable from 0.5- to 2.3-kW output power to the thruster, targets primary propulsion applications for planetary and Earth-space missions and has been baselined as the primary propulsion system for the first New Millennium spacecraft. The NASA Lewis Research Center is responsible for the design and delivery of a breadboard power processing unit (PPU) and an engineering model thruster (EMT) for this system and will manage the contract for the delivery of the flight hardware to JPL. The PPU requirements, which dictate a mass of less than 12 kg with an efficiency of 0.9 or greater at a 2.3-kW output, forced a departure from the state-of-the-art ion thruster PPU design. Several innovations--including dual-use topologies, simplified thruster control, and the use of ferrite magnetic materials--were necessary to meet these requirements.

  7. A CW radiofrequency ion source for production of negative hydrogen ion beams for cyclotrons

    SciTech Connect

    Kalvas, T.; Tarvainen, O.; Komppula, J.; Koivisto, H.; Tuunanen, J.; Potkins, D.; Stewart, T.; Dehnel, M. P.

    2015-04-08

    A CW 13.56 MHz radiofrequency-driven ion source RADIS for production of H{sup −} and D{sup −} beams is under development for replacing the filament-driven ion source of the MCC30/15 cyclotron. The RF ion source has a 16-pole multicusp plasma chamber, an electromagnet-based magnetic filter and an external planar spiral RF antenna behind an AlN window. The extraction is a 5-electrode system with an adjustable puller electrode voltage for optimizing the beam formation, a water-cooled electron dump electrode and an accelerating einzel lens. At 2650 W of RF power, the source produces 1 mA of H{sup −} (2.6 mA/cm{sup 2}), which is the intensity needed at injection for production of 200 µA H{sup +} with the filament-driven ion source. A simple pepperpot device has been developed for characterizing the beam emittance. Plans for improving the power efficiency with the use of a new permanent magnet front plate is discussed.

  8. Negative capacitance for ultra-low power computing

    NASA Astrophysics Data System (ADS)

    Khan, Asif Islam

    Owing to the fundamental physics of the Boltzmann distribution, the ever-increasing power dissipation in nanoscale transistors threatens an end to the almost-four-decade-old cadence of continued performance improvement in complementary metal-oxide-semiconductor (CMOS) technology. It is now agreed that the introduction of new physics into the operation of field-effect transistors---in other words, "reinventing the transistor'"--- is required to avert such a bottleneck. In this dissertation, we present the experimental demonstration of a novel physical phenomenon, called the negative capacitance effect in ferroelectric oxides, which could dramatically reduce power dissipation in nanoscale transistors. It was theoretically proposed in 2008 that by introducing a ferroelectric negative capacitance material into the gate oxide of a metal-oxide-semiconductor field-effect transistor (MOSFET), the subthreshold slope could be reduced below the fundamental Boltzmann limit of 60 mV/dec, which, in turn, could arbitrarily lower the power supply voltage and the power dissipation. The research presented in this dissertation establishes the theoretical concept of ferroelectric negative capacitance as an experimentally verified fact. The main results presented in this dissertation are threefold. To start, we present the first direct measurement of negative capacitance in isolated, single crystalline, epitaxially grown thin film capacitors of ferroelectric Pb(Zr0.2Ti0.8)O3. By constructing a simple resistor-ferroelectric capacitor series circuit, we show that, during ferroelectric switching, the ferroelectric voltage decreases, while the stored charge in it increases, which directly shows a negative slope in the charge-voltage characteristics of a ferroelectric capacitor. Such a situation is completely opposite to what would be observed in a regular resistor-positive capacitor series circuit. This measurement could serve as a canonical test for negative capacitance in any novel

  9. Power processing technology for spacecraft primary ion propulsion

    NASA Technical Reports Server (NTRS)

    Biess, J. J.; Inouye, L. Y.; Frye, R. J.

    1980-01-01

    Advanced technologies developed in support of Ion Propulsion power processing, including the power circuitry portion of the Series L-C Resonant Inverter, Beam Supply, power components, packaging and heat pipe cooling of the 30 cm Ion Engine Power Processor are described. Both the transistorized and SCR versions of the Series L-C Resonant Inverter Beam Supply are discussed. A BIMOD Ion Thruster/Power Processor Prototype Assembly is undergoing environmental and life testing. These advanced technologies can be applied advantageously to other applications of future high power space power processing equipment.

  10. General theory of electron detachment in negative ion collisions

    SciTech Connect

    Wang, T.S.

    1983-01-01

    In this thesis a general theory of electron detachment in slow collisions of negative ions with atoms is presented. The theory is based upon a semiclassical close-coupling framework, following the work of Taylor and Delos. The Schrodinger equation is reduced, under certain assumptions, to a non-denumerably infinite set of coupled equations. A new method for solving these equations is developed that is more general than the methods used by Taylor and Delos. A zero-order approximation of the solution is applied to the case of H-(D-) on Ne collisions, the results are compared with the experimental data, and good agreement between theory and experiment, particularly with regard to the isotope effect, is found. A first-order approximation of the solution is proved to be very close to the exact solution, and it is applied to the case of H-(D-) on He collisions. Quadratic and quartic approximations are used for the energy gap ..delta..(t) to calculate, among other things, the survival probability and electron energy spectrum. There are some interesting results of the electron energy spectrum which have not yet been observed in experiments.

  11. Electron detachment from negative ions in a short laser pulse

    SciTech Connect

    Shearer, S. F. C.; Smyth, M. C.; Gribakin, G. F.

    2011-09-15

    We present an efficient and accurate method to study electron detachment from negative ions by a few-cycle linearly polarized laser pulse. The adiabatic saddle-point method of Gribakin and Kuchiev [Phys. Rev. A 55, 3760 (1997)] is adapted to calculate the transition amplitude for a short laser pulse. Its application to a pulse with N optical cycles produces 2(N+1) saddle points in complex time, which form a characteristic 'smile.' Numerical calculations are performed for H{sup -} in a 5-cycle pulse with frequency 0.0043 a.u. and intensities of 10{sup 10}, 5x10{sup 10}, and 10{sup 11} W/cm{sup 2}, and for various carrier-envelope phases. We determine the spectrum of the photoelectrons as a function of both energy and emission angle, as well as the angle-integrated energy spectra and total detachment probabilities. Our calculations show that the dominant contribution to the transition amplitude is given by 5-6 central saddle points, which correspond to the strongest part of the pulse. We examine the dependence of the photoelectron angular distributions on the carrier-envelope phase and show that measuring such distributions can provide a way of determining this phase.

  12. Freak waves in negative-ion plasmas: an experiment revisited

    NASA Astrophysics Data System (ADS)

    Kourakis, Ioannis; Elkamash, Ibrahem; Reville, Brian

    2016-10-01

    Extreme events in the form of rogue waves (freak waves) occur widely in the open sea. These are space- and time-localised excitations, which appear unexpectedly and are characterised by a significant amplitude. Beyond ocean dynamics, the mechanisms underlying rogue wave formation are now being investigated in various physical contexts, including materials science, nonlinear optics and plasma physics, to mention but a few. We have undertaken an investigation, from first principles, of the occurrence of rogue waves associated with the propagation of electrostatic wavepackets in plasmas. Motivated by recent experimental considerations involving freak waves in negative-ion plasmas (NIP), we have addresed the occurrence of freak waves in NIP from first principles. An extended range of plasma parameter values was identified, where freak wave formation is possible, in terms of relevant plasma parameters. Our results extend -and partly contradict- the underlying assumptions in the interpretation of the aforementioned experiment, where a critical plasma configuration was considered and a Gardner equation approach was adopted. This work was supported from CPP/QUB funding. One of us (I. Elkamash) acknowledges financial support by an Egyptian Government fellowship.

  13. Ion Mobility Studies on the Negative Ion-Molecule Chemistry of Isoflurane and Enflurane

    NASA Astrophysics Data System (ADS)

    González-Méndez, Ramón; Watts, Peter; Howse, David C.; Procino, Immacolata; McIntyre, Henry; Mayhew, Chris A.

    2017-02-01

    In the present work we present an investigation of the negative ion-molecule chemistry of the anaesthetics isoflurane, ISOF, and enflurane, ENF, in an ion mobility spectrometry/mass spectrometry (IMS/MS), in both air and nitrogen. Hexachloroethane (HCE) was introduced in both air and nitrogen to produce Cl- as a reactant ion. This study was undertaken owing to uncertainties in the chemical processes, which lead to the cluster ions reported in other work (Eiceman et al. Anal. Chem. 61, 1093-1099, 1). In particular for ISOF the product ion observed was ISOF.Cl-, and it was suggested that the Cl- was formed by dissociative electron attachment (DEA) although there was mention of a chlorine containing contaminant. We show in this study that ISOF and ENF do not produce Cl- in an IMS system either by capture of free electrons or reaction with O2 -. This demonstrates that the Cl- containing ions, reported in the earlier study, must have been the result of a chlorine containing contaminant as suggested. The failure of ISOF and ENF to undergo DEA was initially surprising given the high calculated electron affinities, but further calculations showed that this was a result of the large positive vertical attachment energies (VAEs). This experimental work has been supported by electronic structure calculations at the B3LYP level, and is consistent with those obtained in a crossed electron-molecular beam two sector field mass spectrometer. An unusual observation is that the monomer complexes of ISOF and ENF with O2 - are relatively unstable compared with the dimer complexes.

  14. Effect of nickel grid parameters on production of negative hydrogen ions

    SciTech Connect

    Oohara, W.; Yokoyama, H.; Takeda, Toshiaki; Maetani, Y.; Takeda, Takashi; Kawata, K.

    2014-06-15

    Negative hydrogen ions are produced by plasma-assisted catalytic ionization using a nickel grid. When positive ions passing through the grid are decelerated by an electric field, the extraction current density of passing positive ions is sharply reduced by neutralization and negative ionization of the ions. This phenomenon is found to depend on the specific surface area of the grid and the current density.

  15. Charged particle flows in the beam extraction region of a negative ion source for NBI

    SciTech Connect

    Geng, S.; Tsumori, K.; Nakano, H.; Osakabe, M.; Nagaoka, K.; Takeiri, Y.; Kaneko, O.; Kisaki, M.; Ikeda, K.; Shibuya, M.

    2016-02-15

    Experiments by a four-pin probe and photodetachment technique were carried out to investigate the charged particle flows in the beam extraction region of a negative hydrogen ion source for neutral beam injector. Electron and positive ion flows were obtained from the polar distribution of the probe saturation current. Negative hydrogen ion flow velocity and temperature were obtained by comparing the recovery times of the photodetachment signals at opposite probe tips. Electron and positive ions flows are dominated by crossed field drift and ambipolar diffusion. Negative hydrogen ion temperature is evaluated to be 0.12 eV.

  16. Negative ion source development for a photoneutralization based neutral beam system for future fusion reactors

    NASA Astrophysics Data System (ADS)

    Simonin, A.; Agnello, R.; Bechu, S.; Bernard, J. M.; Blondel, C.; Boeuf, J. P.; Bresteau, D.; Cartry, G.; Chaibi, W.; Drag, C.; Duval, B. P.; de Esch, H. P. L.; Fubiani, G.; Furno, I.; Grand, C.; Guittienne, Ph; Howling, A.; Jacquier, R.; Marini, C.; Morgal, I.

    2016-12-01

    In parallel to the developments dedicated to the ITER neutral beam (NB) system, CEA-IRFM with laboratories in France and Switzerland are studying the feasibility of a new generation of NB system able to provide heating and current drive for the future DEMOnstration fusion reactor. For the steady-state scenario, the NB system will have to provide a high NB power level with a high wall-plug efficiency (η ˜ 60%). Neutralization of the energetic negative ions by photodetachment (so called photoneutralization), if feasible, appears to be the ideal solution to meet these performances, in the sense that it could offer a high beam neutralization rate (>80%) and a wall-plug efficiency higher than 60%. The main challenge of this new injector concept is the achievement of a very high power photon flux which could be provided by 3 MW Fabry-Perot optical cavities implanted along the 1 MeV D- beam in the neutralizer stage. The beamline topology is tall and narrow to provide laminar ion beam sheets, which will be entirely illuminated by the intra-cavity photon beams propagating along the vertical axis. The paper describes the present R&D (experiments and modelling) addressing the development of a new ion source concept (Cybele source) which is based on a magnetized plasma column. Parametric studies of the source are performed using Langmuir probes in order to characterize and compare the plasma parameters in the source column with different plasma generators, such as filamented cathodes, radio-frequency driver and a helicon antenna specifically developed at SPC-EPFL satisfying the requirements for the Cybele (axial magnetic field of 10 mT, source operating pressure: 0.3 Pa in hydrogen or deuterium). The paper compares the performances of the three plasma generators. It is shown that the helicon plasma generator is a very promising candidate to provide an intense and uniform negative ion beam sheet.

  17. Long-pulse production of high current negative ion beam by using actively temperature controlled plasma grid for JT-60SA negative ion source

    SciTech Connect

    Kojima, A.; Hanada, M.; Yoshida, M.; Umeda, N.; Hiratsuka, J.; Kashiwagi, M.; Tobari, H.; Watanabe, K.; Grisham, L. R.

    2015-04-08

    The temperature control system of the large-size plasma grid has been developed to realize the long pulse production of high-current negative ions for JT-60SA. By using this prototype system for the JT-60SA ion source, 15 A negative ions has been sustained for 100 s for the first time, which is three times longer than that obtained in JT-60U. In this system, a high-temperature fluorinated fluid with a high boiling point of 270 degree Celsius is circulated in the cooling channels of the plasma grids (PG) where a cesium (Cs) coverage is formed to enhance the negative ion production. Because the PG temperature control had been applied to only 10% of the extraction area previously, the prototype PG with the full extraction area (110 cm × 45 cm) was developed to increase the negative ion current in this time. In the preliminary results of long pulse productions of high-current negative ions at a Cs conditioning phase, the negative ion production was gradually degraded in the last half of 100 s pulse where the temperature of an arc chamber wall was not saturated. From the spectroscopic measurements, it was found that the Cs flux released from the wall might affect to the negative ion production, which implied the wall temperature should be kept low to control the Cs flux to the PG for the long-pulse high-current production. The obtained results of long-pulse production and the PG temperature control method contributes the design of the ITER ion source.

  18. A High-Intensity, RF Plasma-Sputter Negative Ion Source

    SciTech Connect

    Alton, G.D.; Bao, Y.; Cui, B.; Lohwasser, R.; Reed, C.A.; Zhang, T.

    1999-03-02

    A high-intensity, plasma-sputter negative-ion source based on the use of RF power for plasma generation has been developed that can be operated in either pulsed or dc modes. The source utilizes a high-Q, self-igniting, inductively coupled antenna system, operating at 80 MHz that has been optimized to generate Cs-seeded plasmas at low pressures (typically, <1 mTorr for Xe). The source is equipped with a 19-mm diameter spherical-sector cathode machined from the desired material. To date, the source has been utilized to generate dc negative-ion beams from a variety of species, including: C{sup {minus}}(610 {micro}A); F{sup {minus}}(100 {micro}A); Si{sup {minus}}(500 {micro}A); S{sup {minus}}(500 {micro}A); P{sup {minus}}(125 {micro}A); Cl{sup {minus}}(200 {micro}A); Ni{sup {minus}}(150 {micro}A); Cu{sup {minus}}(230 {micro}A); Ge{sup {minus}}(125 {micro}A); As{sup {minus}}(100 {micro}A); Se{sup {minus}}(200 {micro}A); Ag{sup {minus}}(70 {micro}A); Pt{sup {minus}}(125 {micro}A); Au{sup {minus}}(250 {micro}A). The normalized emittance {var_epsilon}{sub n} of the source at the 80% contour is: {var_epsilon}{sub n} = 7.5 mm.mrad.(MeV){sup 1/2}. The design principles of the source, operational parameters, ion optics, emittance and intensities for a number of negative-ion species will be presented in this report.

  19. Linear and nonlinear obliquely propagating ion-acoustic waves in magnetized negative ion plasma with non-thermal electrons

    NASA Astrophysics Data System (ADS)

    Mishra, M. K.; Jain, S. K.; Jain

    2013-10-01

    Ion-acoustic solitons in magnetized low-β plasma consisting of warm adiabatic positive and negative ions and non-thermal electrons have been studied. The reductive perturbation method is used to derive the Korteweg-de Vries (KdV) equation for the system, which admits an obliquely propagating soliton solution. It is found that due to the presence of finite ion temperature there exist two modes of propagation, namely fast and slow ion-acoustic modes. In the case of slow-mode if the ratio of temperature to mass of positive ion species is lower (higher) than the negative ion species, then there exist compressive (rarefactive) ion-acoustic solitons. It is also found that in the case of slow mode, on increasing the non-thermal parameter (γ) the amplitude of the compressive (rarefactive) soliton decreases (increases). In fast ion-acoustic mode the nature and characteristics of solitons depend on negative ion concentration. Numerical investigation in case of fast mode reveals that on increasing γ, the amplitude of compressive (rarefactive) soliton increases (decreases). The width of solitons increases with an increase in non-thermal parameters in both the modes for compressive as well as rarefactive solitons. There exists a value of critical negative ion concentration (α c ), at which both compressive and rarefactive ion-acoustic solitons appear as described by modified KdV soliton. The value of α c decreases with increase in γ.

  20. Size scaling of negative hydrogen ion sources for fusion

    NASA Astrophysics Data System (ADS)

    Fantz, U.; Franzen, P.; Kraus, W.; Schiesko, L.; Wimmer, C.; Wünderlich, D.

    2015-04-01

    The RF-driven negative hydrogen ion source (H-, D-) for the international fusion experiment ITER has a width of 0.9 m and a height of 1.9 m and is based on a ⅛ scale prototype source being in operation at the IPP test facilities BATMAN and MANITU for many years. Among the challenges to meet the required parameters in a caesiated source at a source pressure of 0.3 Pa or less is the challenge in size scaling of a factor of eight. As an intermediate step a ½ scale ITER source went into operation at the IPP test facility ELISE with the first plasma in February 2013. The experience and results gained so far at ELISE allowed a size scaling study from the prototype source towards the ITER relevant size at ELISE, in which operational issues, physical aspects and the source performance is addressed, highlighting differences as well as similarities. The most ITER relevant results are: low pressure operation down to 0.2 Pa is possible without problems; the magnetic filter field created by a current in the plasma grid is sufficient to reduce the electron temperature below the target value of 1 eV and to reduce together with the bias applied between the differently shaped bias plate and the plasma grid the amount of co-extracted electrons. An asymmetry of the co-extracted electron currents in the two grid segments is measured, varying strongly with filter field and bias. Contrary to the prototype source, a dedicated plasma drift in vertical direction is not observed. As in the prototype source, the performance in deuterium is limited by the amount of co-extracted electrons in short as well as in long pulse operation. Caesium conditioning is much harder in deuterium than in hydrogen for which fast and reproducible conditioning is achieved. First estimates reveal a caesium consumption comparable to the one in the prototype source despite the large size.

  1. Letter: High-mass capabilities of positive-ion and negative-ion direct analysis in real time mass spectrometry.

    PubMed

    Gross, Jürgen H

    2016-01-01

    Of the ionic liquid 1-butyl-3-methylimidazolium (C(+)) tricyanomethide (A(-)) high-mass cluster ions of both positive ([C(n)A(n-1)](+)) and negative ([C(n-1)A(n)](-)) charge were generated and detected by direct analysis in real time (DART) Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry (MS). After optimization of the settings of the DART ionization source and of the mass analyzer ions of m/z values unprecedented in DART-MS were detected. Thus, the upper m/z limits of positive-ion and negative-ion DART- MS were substantially expanded. Negative-ion DART-MS delivered cluster ions up to [C(15)A(16)](-), m/z 3527 (nominal mass of monoisotopic ion), while positive-ion DART-MS even yielded ions up to [C(30)A(29)](+), m/z 6784. The identification of the cluster ions is supported by their accurate mass and exact mass differences corresponding to CA between adjacent cluster ion peaks.

  2. A new grid-type electron filter for volume-production negative-ion source

    NASA Astrophysics Data System (ADS)

    Rafalskyi, D. V.; Dudin, S. V.

    2012-03-01

    A new system providing continuous generation of broad negative-ion beam is described and characterized. The key element of the system is the grid-type electron filter allowing the formation without magnetic field of a stationary highly electronegative plasma which can be biased negatively with respect to a relatively high-area electrode that allows to extract the negative ions. Measurements of negative-ion energy distribution functions conducted using a magnetically filtered energy analyzer show broad (250 mm) negative-ion beam formation with controllable energy starting from several eV. A conclusion is made about the possibility of practical application of the grid-type electron filter in negative ion sources for electric propulsion and etching technologies.

  3. Sodium titanate nanotubes as negative electrode materials for sodium-ion capacitors.

    PubMed

    Yin, Jiao; Qi, Li; Wang, Hongyu

    2012-05-01

    The lithium-based energy storage technology is currently being considered for electric automotive industry and even electric grid storage. However, the hungry demand for vast energy sources in the modern society will conflict with the shortage of lithium resources on the earth. The first alternative choice may be sodium-related materials. Herein, we propose an electric energy storage system (sodium-ion capacitor) based on porous carbon and sodium titanate nanotubes (Na-TNT, Na(+)-insertion compounds) as positive and negative electrode materials, respectively, in conjunction with Na(+)-containing non-aqueous electrolytes. As a low-voltage (0.1-2 V) sodium insertion nanomaterial, Na-TNT was synthesized via a simple hydrothermal reaction. Compared with bulk sodium titanate, the predominance of Na-TNT is the excellent rate performance, which exactly caters to the need for electrochemical capacitors. The sodium-ion capacitors exhibited desirable energy density and power density (34 Wh kg(-1), 889 W kg(-1)). Furthermore, the sodium-ion capacitors had long cycling life (1000 cycles) and high coulombic efficiency (≈ 98 % after the second cycle). More importantly, the conception of sodium-ion capacitor has been put forward.

  4. Relative stopping powers for atomic and molecular ions in carbon

    NASA Astrophysics Data System (ADS)

    Steuer, Malcolm F.

    1986-03-01

    Electronic stopping powers of carbon for atomic and molecular nitrogen ions have been calculated using semi-classical free electron scattering from Herman-Skillman potentials, parametrized to include an adjustable exponential screening factor F( tv, Z), representing atomic ions. For molecular ions, aligned along the beam direction and having velocity 1.2 a.u., the stopping powers for individual atomic components were calculated as a function of internuclear separation. Screening factors for the two centers of force were assumed to decrease linearly from the value at zero internuclear separation, equivalent to that of a silicon ion, to that for nitrogen ions at large separations. Results are consistent with the diminishment of average stopping power per atomic ion which has been observed for beam-aligned nitrogen molecular ions. Similar calculations for molecular hydrogen in carbon agree with the enhancement of stopping power which has been observed. Evidence of nonlinear effects is indicated.

  5. The structure of the stable negative ion of calcium

    SciTech Connect

    Pegg, D.J.; Thompson, J.S.; Compton, R.N.; Alton, G.D.

    1988-01-01

    The structure of the Ca/sup /minus// ion has been determined using a crossed laser-ion beams apparatus. The photoelectron detachment spectrum shows that, contrary to earlier expectations, the Ca/sup /minus// ion is stably bound in the (4s/sup 2/4p)/sup 2/p state. The electron affinity of Ca was measured to be 0.043 /sup + -/ 0.007 eV.

  6. Excitation of dust acoustic waves by an ion beam in a plasma cylinder with negatively charged dust grains

    SciTech Connect

    Sharma, Suresh C.; Kaur, Daljeet; Gahlot, Ajay; Sharma, Jyotsna

    2014-10-15

    An ion beam propagating through a plasma cylinder having negatively charged dust grains drives a low frequency electrostatic dust acoustic wave (DAW) to instability via Cerenkov interaction. The unstable wave frequencies and the growth rate increase with the relative density of negatively charged dust grains. The growth rate of the unstable mode scales to the one-third power of the beam density. The real part of the frequency of the unstable mode increases with the beam energy and scales to almost one-half power of the beam energy. The phase velocity, frequency, and wavelength results of the unstable mode are in compliance with the experimental observations.

  7. Silicon Carbide Power Device Performance Under Heavy-Ion Irradiation

    NASA Technical Reports Server (NTRS)

    Lauenstein, Jean-Marie; Casey, Megan; Topper, Alyson; Wilcox, Edward; Phan, Anthony; Ikpe, Stanley; LaBel, Ken

    2015-01-01

    Heavy-ion induced degradation and catastrophic failure data for SiC power MOSFETs and Schottky diodes are examined to provide insight into the challenge of single-event effect hardening of SiC power devices.

  8. The effects of CO2 on the negative reactant ions of IMS

    NASA Technical Reports Server (NTRS)

    Spangler, Glenn E.

    1995-01-01

    In the presence of CO2, the negative reactant ions of ion mobility spectrometry (IMS) are ion clusters of CO4(-) and CO3(-). Methyl salicylate is ionized by the CO4(-)(H2O(n))(N2(m)) reactant ions, but not by the CO3(-)(H2O(n))(N2(m)) reactant ions. While the CO4(-) ions are formed by direct association, the CO3(-) ions require additional energy to be formed. The additional energy is provided by either excited neutral gas molecules in a metastable state or UV (ultraviolet) radiation.

  9. NEGATIVE-ION MASS SPECTROMETRY OF SULFONYLUREA HERBICIDES

    EPA Science Inventory

    Sulfonylurea herbicides have been studied using neg-ion desorption chem.-ionization (DCI) mass spectrometry (MS) and DCI-MS/MS techniques. Both {M-H]- and M.- ions were obsd. in the DCI mass spectra. The collisonally activated dissocn. (CAD) spectra were characteristic of the str...

  10. Installation of spectrally selective imaging system in RF negative ion source

    NASA Astrophysics Data System (ADS)

    Ikeda, K.; Wünderlich, D.; Fantz, U.; Heinemann, B.; Kisaki, M.; Nagaoka, K.; Nakano, H.; Osakabe, M.; Tsumori, K.; Geng, S.; Kaneko, O.; Takeiri, Y.

    2016-02-01

    A spectrally selective imaging system has been installed in the RF negative ion source in the International Thermonuclear Experimental Reactor-relevant negative ion beam test facility ELISE (Extraction from a Large Ion Source Experiment) to investigate distribution of hydrogen Balmer-α emission (Hα) close to the production surface of hydrogen negative ion. We selected a GigE vision camera coupled with an optical band-path filter, which can be controlled remotely using high speed network connection. A distribution of Hα emission near the bias plate has been clearly observed. The same time trend on Hα intensities measured by the imaging diagnostic and the optical emission spectroscopy is confirmed.

  11. Size scaling of negative hydrogen ion sources for fusion

    SciTech Connect

    Fantz, U. Franzen, P.; Kraus, W.; Schiesko, L.; Wimmer, C.; Wünderlich, D.

    2015-04-08

    The RF-driven negative hydrogen ion source (H{sup −}, D{sup −}) for the international fusion experiment ITER has a width of 0.9 m and a height of 1.9 m and is based on a ⅛ scale prototype source being in operation at the IPP test facilities BATMAN and MANITU for many years. Among the challenges to meet the required parameters in a caesiated source at a source pressure of 0.3 Pa or less is the challenge in size scaling of a factor of eight. As an intermediate step a ½ scale ITER source went into operation at the IPP test facility ELISE with the first plasma in February 2013. The experience and results gained so far at ELISE allowed a size scaling study from the prototype source towards the ITER relevant size at ELISE, in which operational issues, physical aspects and the source performance is addressed, highlighting differences as well as similarities. The most ITER relevant results are: low pressure operation down to 0.2 Pa is possible without problems; the magnetic filter field created by a current in the plasma grid is sufficient to reduce the electron temperature below the target value of 1 eV and to reduce together with the bias applied between the differently shaped bias plate and the plasma grid the amount of co-extracted electrons. An asymmetry of the co-extracted electron currents in the two grid segments is measured, varying strongly with filter field and bias. Contrary to the prototype source, a dedicated plasma drift in vertical direction is not observed. As in the prototype source, the performance in deuterium is limited by the amount of co-extracted electrons in short as well as in long pulse operation. Caesium conditioning is much harder in deuterium than in hydrogen for which fast and reproducible conditioning is achieved. First estimates reveal a caesium consumption comparable to the one in the prototype source despite the large size.

  12. Ion Distribution And Electronic Stopping Power For Au ions In Silicon Carbide

    SciTech Connect

    Jin, Ke; Zhang, Yanwen; Xue, Haizhou; Zhu, Zihua; Weber, William J.

    2013-07-15

    Accurate knowledge of ion distribution and electronic stopping power for heavy ions in light targets is highly desired due to the large errors in prediction by the widely used Stopping and Range of Ions in Matter (SRIM) code. In this study, Rutherford backscattering spectrometry (RBS)and secondary ion mass spectrometry (SIMS) are used as complementary techniques to determine the distribution of Au ions in SiC with energie sfrom 700 keV to 15 MeV. In addition, asingle ion technique with an improved data analysis procedure is applied to measure the electronic stopping power for Au ions in SiC with energies up to ~70 keV/nucleon. Large overestimation of the electronic stopping power is found by SRIM prediction in the low energy regime up to ~50 keV/nucleon. The stopping power data and the ion ranges are crosschecked with each other and a good agreement is achieved.

  13. Evidence for the existence of negative ions in the D and lower E regions at twilight

    NASA Technical Reports Server (NTRS)

    Kane, J. A.

    1972-01-01

    Evidence for negative ions in the lower ionosphere is based on the difference between simultaneously measured profiles of electron and positive ion density. The electron density profiles reported were obtained from ground-to-rocket radio wave absorption measurements while Gerdien ion traps were used to measure the positive ion profiles. Results from a series of three rockets launched from Thumba, India near sunset on 27 March, 1970 indicate that a significant number of negative ions are formed at altitudes as high as 95 km at twilight.

  14. A tandem time-of-flight spectrometer for negative-ion/positive-ion coincidence measurements with soft x-ray excitation

    NASA Astrophysics Data System (ADS)

    Strâhlman, Christian; Sankari, Rami; Kivimäki, Antti; Richter, Robert; Coreno, Marcello; Nyholm, Ralf

    2016-01-01

    We present a newly constructed spectrometer for negative-ion/positive-ion coincidence spectroscopy of gaseous samples. The instrument consists of two time-of-flight ion spectrometers and a magnetic momentum filter for deflection of electrons. The instrument can measure double and triple coincidences between mass-resolved negative and positive ions with high detection efficiency. First results include identification of several negative-ion/positive-ion coincidence channels following inner-shell photoexcitation of sulfur hexafluoride (SF6).

  15. Design of the Prototype Negative Ion Source for Neutral Beam Injector at ASIPP

    NASA Astrophysics Data System (ADS)

    Wei, Jianglong; Xie, Yahong; Liang, Lizhen; Gu, Yuming; Yi, Wei; Li, Jun; Hu, Chundong; Xie, Yuanlai; Jiang, Caichao; Tao, Ling; Sheng, Peng; Xu, Yongjian

    2016-09-01

    In order to support the design, manufacture and commissioning of the negative-ion-based neutral beam injection (NBI) system for the Chinese Fusion Engineering Test Reactor (CFETR), the Hefei utility negative ion test equipment with RF source (HUNTER) was proposed at ASIPP. A prototype negative ion source will be developed at first. The main bodies of plasma source and accelerator of the prototype negative ion source are similar to that of the ion source for EAST-NBI. But instead of the filament-arc driver, an RF driver is adopted for the prototype negative ion source to fulfill the requirement of long pulse operation. A cesium seeding system and a magnetic filter are added for enhancing the negative ion density near the plasma grid and minimizing co-extracted electrons. Besides, an ITER-like extraction system is applied inside the accelerator, where the negative ion beam is extracted and accelerated up to 50 kV. supported by National Natural Science Foundation of China (Nos. 11505224, 11575240, 11405207), the National Magnetic Confinement Fusion Science Program of China (Nos. 2013GB101001, 2013GB101002, 2013GB101003), International Science and Technology Cooperation Program of China (No. 2014DFG61950), and Foundation of ASIPP (No. DSJJ-14-JC07)

  16. Magnetized retarding field energy analyzer measuring the particle flux and ion energy distribution of both positive and negative ions.

    PubMed

    Rafalskyi, Dmytro; Dudin, Stanislav; Aanesland, Ane

    2015-05-01

    This paper presents the development of a magnetized retarding field energy analyzer (MRFEA) used for positive and negative ion analysis. The two-stage analyzer combines a magnetic electron barrier and an electrostatic ion energy barrier allowing both positive and negative ions to be analyzed without the influence of electrons (co-extracted or created downstream). An optimal design of the MRFEA for ion-ion beams has been achieved by a comparative study of three different MRFEA configurations, and from this, scaling laws of an optimal magnetic field strength and topology have been deduced. The optimal design consists of a uniform magnetic field barrier created in a rectangular channel and an electrostatic barrier consisting of a single grid and a collector placed behind the magnetic field. The magnetic barrier alone provides an electron suppression ratio inside the analyzer of up to 6000, while keeping the ion energy resolution below 5 eV. The effective ion transparency combining the magnetic and electrostatic sections of the MRFEA is measured as a function of the ion energy. It is found that the ion transparency of the magnetic barrier increases almost linearly with increasing ion energy in the low-energy range (below 200 eV) and saturates at high ion energies. The ion transparency of the electrostatic section is almost constant and close to the optical transparency of the entrance grid. We show here that the MRFEA can provide both accurate ion flux and ion energy distribution measurements in various experimental setups with ion beams or plasmas run at low pressure and with ion energies above 10 eV.

  17. Magnetized retarding field energy analyzer measuring the particle flux and ion energy distribution of both positive and negative ions

    SciTech Connect

    Rafalskyi, Dmytro; Aanesland, Ane; Dudin, Stanislav

    2015-05-15

    This paper presents the development of a magnetized retarding field energy analyzer (MRFEA) used for positive and negative ion analysis. The two-stage analyzer combines a magnetic electron barrier and an electrostatic ion energy barrier allowing both positive and negative ions to be analyzed without the influence of electrons (co-extracted or created downstream). An optimal design of the MRFEA for ion-ion beams has been achieved by a comparative study of three different MRFEA configurations, and from this, scaling laws of an optimal magnetic field strength and topology have been deduced. The optimal design consists of a uniform magnetic field barrier created in a rectangular channel and an electrostatic barrier consisting of a single grid and a collector placed behind the magnetic field. The magnetic barrier alone provides an electron suppression ratio inside the analyzer of up to 6000, while keeping the ion energy resolution below 5 eV. The effective ion transparency combining the magnetic and electrostatic sections of the MRFEA is measured as a function of the ion energy. It is found that the ion transparency of the magnetic barrier increases almost linearly with increasing ion energy in the low-energy range (below 200 eV) and saturates at high ion energies. The ion transparency of the electrostatic section is almost constant and close to the optical transparency of the entrance grid. We show here that the MRFEA can provide both accurate ion flux and ion energy distribution measurements in various experimental setups with ion beams or plasmas run at low pressure and with ion energies above 10 eV.

  18. Determination of N-linked Glycosylation in Viral Glycoproteins by Negative Ion Mass Spectrometry and Ion Mobility.

    PubMed

    Bitto, David; Harvey, David J; Halldorsson, Steinar; Doores, Katie J; Pritchard, Laura K; Huiskonen, Juha T; Bowden, Thomas A; Crispin, Max

    2015-01-01

    Glycan analysis of virion-derived glycoproteins is challenging due to the difficulties in glycoprotein isolation and low sample abundance. Here, we describe how ion mobility mass spectrometry can be used to obtain spectra from virion samples. We also describe how negative ion fragmentation of glycans can be used to probe structural features of virion glycans.

  19. Determination of N-linked glycosylation in viral glycoproteins by negative ion mass spectrometry and ion mobility

    PubMed Central

    Bitto, David; Harvey, David J.; Halldorsson, Steinar; Doores, Katie J.; Pritchard, Laura K.; Huiskonen, Juha T.; Bowden, Thomas A.; Crispin, Max

    2016-01-01

    Summary Glycan analysis of virion-derived glycoproteins is challenging due to the difficulties in glycoprotein isolation and low sample abundance. Here, we describe how ion mobility mass spectrometry can be used to obtain spectra from virion samples. We also describe how negative ion fragmentation of glycans can be used to probe structural features of virion glycans. PMID:26169737

  20. Electron energy distributions, vibrational population distributions, and negative-ion concentrations in hydrogen discharges

    SciTech Connect

    Hiskes, J.R.; Karo, A.M.

    1982-06-28

    We consider the negative ion concentrations in hydrogen discharges caused by electron excitation and dissociative attachment processes. The principal formation and destruction processes are discussed for electron densities in the range 10/sup 8/ to 10/sup 13/ electrons cm/sup -3/. Expressions are developed for calculating the high energy portion of the electron energy distribution in the discharge; using these energy distributions the electron excitation rates are evaluated. At low densities, the vibrational distribution arises from singlet electronic excitations and triplet excitations through the /sup 3/..pi../sub u/ state, in equilibrium with wall de-excitation processes. At high densities singlet excitations predominate in equilibrium with atom-molecule de-excitation processes. Possibilities for negative ion generation in a two-chamber tandem system are discussed in which the vibrational excitation occurs in a high power, high electron temperature discharge, kT/sub e/ = 5 eV, and dissociative attachment occurs in a low temperature kT/sub e/ = 1 eV, plasma chamber.

  1. Arc plasma generator of atomic driver for steady-state negative ion source

    SciTech Connect

    Ivanov, A. A.; Belchenko, Yu. I.; Davydenko, V. I.; Ivanov, I. A.; Kolmogorov, V. V.; Listopad, A. A. Mishagin, V. V.; Shulzhenko, G. I.; Putvinsky, S. V.; Smirnov, A.

    2014-02-15

    The paper reviews the results of development of steady-state arc-discharge plasma generator with directly heated LaB{sub 6} cathode. This arc-discharge plasma generator produces a plasma jet which is to be converted into an atomic one after recombination on a metallic plate. The plate is electrically biased relative to the plasma in order to control the atom energies. Such an intensive jet of hydrogen atoms can be used in negative ion sources for effective production of negative ions on a cesiated surface of plasma grid. All elements of the plasma generator have an augmented water cooling to operate in long pulse mode or in steady state. The thermo-mechanical stresses and deformations of the most critical elements of the plasma generator were determined by simulations. Magnetic field inside the discharge chamber was optimized to reduce the local power loads. The first tests of the steady-state arc plasma generator prototype have performed in long-pulse mode.

  2. Arc plasma generator of atomic driver for steady-state negative ion source.

    PubMed

    Ivanov, A A; Belchenko, Yu I; Davydenko, V I; Ivanov, I A; Kolmogorov, V V; Listopad, A A; Mishagin, V V; Putvinsky, S V; Shulzhenko, G I; Smirnov, A

    2014-02-01

    The paper reviews the results of development of steady-state arc-discharge plasma generator with directly heated LaB6 cathode. This arc-discharge plasma generator produces a plasma jet which is to be converted into an atomic one after recombination on a metallic plate. The plate is electrically biased relative to the plasma in order to control the atom energies. Such an intensive jet of hydrogen atoms can be used in negative ion sources for effective production of negative ions on a cesiated surface of plasma grid. All elements of the plasma generator have an augmented water cooling to operate in long pulse mode or in steady state. The thermo-mechanical stresses and deformations of the most critical elements of the plasma generator were determined by simulations. Magnetic field inside the discharge chamber was optimized to reduce the local power loads. The first tests of the steady-state arc plasma generator prototype have performed in long-pulse mode.

  3. Preliminary results from the Small Negative Ion Facility (SNIF) at CCFE

    NASA Astrophysics Data System (ADS)

    Zacks, J.; McAdams, R.; Booth, J.; Flinders, K.; Holmes, A. J. T.; Simmonds, M.; Stevens, B.; Stevenson, P.; Surrey, E.; Warder, S.; Whitehead, A.; Young, D.

    2013-02-01

    At Culham Centre for Fusion Energy, a new beam extraction test facility has been built with the purpose of studying and enhancing negative ion beam production and transport. The multipole hydrogen ion source is based on a RF generated plasma using a continuous 5kW power supply operating at the industrial standard frequency of 13.56MHz. The cylindrical source has a diameter of 30cm and a depth of 20cm, with a flat spiral antenna driving the source through a quartz window. The magnet configuration is arranged to produce a dipole filter field across the ion source close to the plasma grid. The plasma load is matched to the RF generator using a Pi matching network. The accelerator uses a single extraction aperture of 14mm diameter, with a biased insert for electron suppression. The accelerator is a triode design with a beam energy of up to 30kV. The beamline consists of a turbomolecular pumped vacuum tank with an instrumented beam dump and ports for additional diagnostics. The ITER Neutral Beam source operates with the enhancement of caesium, which, when scaled up to a reactor, will be heavily consumed. The small size of SNIF allows for fast turn around of modifications and alternative materials to caesium can be tested. A full description of the facility and planned diagnostics is given. Initial results are presented, including measurements and calculations of the plasma load on the RF generator, and beam extraction measurements.

  4. Trial of a negative ion generator device in remediating problems related to indoor air quality

    SciTech Connect

    Daniell, W.; Camp, J.; Horstman, S. )

    1991-06-01

    It has been suggested that supplementation of indoor air with negative ions can improve air quality. This study examined the effects of a negative ion-generator device on air contaminants and symptom reporting in two office buildings. Separate sets of functional and nonfunctional negative ion generators were monitored using a double blind, crossover design involving two 5-week exposure periods. There were no detectable direct or residual effects of negative ion generator use on air ion levels, airborn particulates, carbon dioxide levels, or symptom reporting. Symptom reporting declined at both sites initially and appeared to be consistent with placebo effect. Job dissatisfaction was an apparent contributor to symptom reporting, with a magnitude comparable to presumed effects of air quality. Further testing of such devices is needed before they should be considered for office air quality problems.

  5. High electronegativity multi-dipolar electron cyclotron resonance plasma source for etching by negative ions

    NASA Astrophysics Data System (ADS)

    Stamate, E.; Draghici, M.

    2012-04-01

    A large area plasma source based on 12 multi-dipolar ECR plasma cells arranged in a 3 × 4 matrix configuration was built and optimized for silicon etching by negative ions. The density ratio of negative ions to electrons has exceeded 300 in Ar/SF6 gas mixture when a magnetic filter was used to reduce the electron temperature to about 1.2 eV. Mass spectrometry and electrostatic probe were used for plasma diagnostics. The new source is free of density jumps and instabilities and shows a very good stability for plasma potential, and the dominant negative ion species is F-. The magnetic field in plasma volume is negligible and there is no contamination by filaments. The etching rate by negative ions measured in Ar/SF6/O2 mixtures was almost similar with that by positive ions reaching 700 nm/min.

  6. Effects of negative air ions on oxygen uptake kinetics, recovery and performance in exercise: a randomized, double-blinded study

    NASA Astrophysics Data System (ADS)

    Nimmerichter, Alfred; Holdhaus, Johann; Mehnen, Lars; Vidotto, Claudia; Loidl, Markus; Barker, Alan R.

    2014-09-01

    Limited research has suggested that acute exposure to negatively charged ions may enhance cardio-respiratory function, aerobic metabolism and recovery following exercise. To test the physiological effects of negatively charged air ions, 14 trained males (age: 32 ± 7 years; : 57 ± 7 mL min-1 kg-1) were exposed for 20 min to either a high-concentration of air ions (ION: 220 ± 30 × 103 ions cm-3) or normal room conditions (PLA: 0.1 ± 0.06 × 103 ions cm-3) in an ionization chamber in a double-blinded, randomized order, prior to performing: (1) a bout of severe-intensity cycling exercise for determining the time constant of the phase II response ( τ) and the magnitude of the slow component (SC); and (2) a 30-s Wingate test that was preceded by three 30-s Wingate tests to measure plasma [adrenaline] (ADR), [nor-adrenaline] (N-ADR) and blood [lactate] (BLac) over 20 min during recovery in the ionization chamber. There was no difference between ION and PLA for the phase II τ (32 ± 14 s vs. 32 ± 14 s; P = 0.7) or SC (404 ± 214 mL vs 482 ± 217 mL; P = 0.17). No differences between ION and PLA were observed at any time-point for ADR, N-ADR and BLac as well as on peak and mean power output during the Wingate tests (all P > 0.05). A high-concentration of negatively charged air ions had no effect on aerobic metabolism during severe-intensity exercise or on performance or the recovery of the adrenergic and metabolic responses after repeated-sprint exercise in trained athletes.

  7. Optimum plasma grid bias for a negative hydrogen ion source operation with Cs

    SciTech Connect

    Bacal, Marthe; Sasao, Mamiko; Wada, Motoi; McAdams, Roy

    2016-02-15

    The functions of a biased plasma grid of a negative hydrogen (H{sup −}) ion source for both pure volume and Cs seeded operations are reexamined. Proper control of the plasma grid bias in pure volume sources yields: enhancement of the extracted negative ion current, reduction of the co-extracted electron current, flattening of the spatial distribution of plasma potential across the filter magnetic field, change in recycling from hydrogen atomic/molecular ions to atomic/molecular neutrals, and enhanced concentration of H{sup −} ions near the plasma grid. These functions are maintained in the sources seeded with Cs with additional direct emission of negative ions under positive ion and neutral hydrogen bombardment onto the plasma electrode.

  8. Extraction and neutralization of positive and negative ions from a pulsed electronegative inductively coupled plasma

    NASA Astrophysics Data System (ADS)

    Marinov, D.; el Otell, Z.; Bowden, M. D.; Braithwaite, N. St. J.

    2015-12-01

    Almost electron-free (ion-ion) plasmas can be transiently formed during the afterglow phase of pulsed plasmas in electronegative gases. In ion-ion plasmas, both positive and negative ions can be extracted which makes them advantageous for a number of applications. In this paper, we investigate the extraction and acceleration of positive and negative ion beams from a pulsed inductively coupled plasma in SF6. The plasma is bounded by two electrodes biased synchronously with the discharge modulation. It is shown that when a DC bias voltage is applied during the afterglow phase, positive/negative ions are accelerated in a positive/negative space charge sheath formed in front of one of the electrodes. The energy of extracted ions closely follows the amplitude of the applied bias voltage (25-150 V) and the peak beam current density reaches 2 A m-2. With a view to using the described system as a source of energetic neutral beams for low damage material processing, simultaneous extraction and surface neutralization of positive and negative ions using an extraction electrode with high aspect ratio apertures is investigated.

  9. Hydrogen atom temperature measured with wavelength-modulated laser absorption spectroscopy in large scale filament arc negative hydrogen ion source

    SciTech Connect

    Nakano, H. Goto, M.; Tsumori, K.; Kisaki, M.; Ikeda, K.; Nagaoka, K.; Osakabe, M.; Takeiri, Y.; Kaneko, O.; Nishiyama, S.; Sasaki, K.

    2015-04-08

    The velocity distribution function of hydrogen atoms is one of the useful parameters to understand particle dynamics from negative hydrogen production to extraction in a negative hydrogen ion source. Hydrogen atom temperature is one of the indicators of the velocity distribution function. To find a feasibility of hydrogen atom temperature measurement in large scale filament arc negative hydrogen ion source for fusion, a model calculation of wavelength-modulated laser absorption spectroscopy of the hydrogen Balmer alpha line was performed. By utilizing a wide range tunable diode laser, we successfully obtained the hydrogen atom temperature of ∼3000 K in the vicinity of the plasma grid electrode. The hydrogen atom temperature increases as well as the arc power, and becomes constant after decreasing with the filling of hydrogen gas pressure.

  10. Negative Ion Formation with Electron Impact to Simulants

    DTIC Science & Technology

    1990-12-01

    approved for publica- ALAN GARSCADDEN , Research Physicist LOWELL D. MASSIE Advanced Plasma Research Group Chief, Power Components Branch Power Components...ALAN GARSCADDEN DD Form 1473, JUN 86 Previous editions are obsolete. SECURITY CLASSIFICATION OF THIS PAGE UNCLASSIFIED Contents Summary 1 I Introduction

  11. Plasma Transport in a Magnetic Multicusp Negative Hydrogen Ion Source

    DTIC Science & Technology

    1991-12-01

    the Extraction Electrode ............................ 4-4 Analysis of the Effect of Temperature Gradients on the Flux...Measured vs Predicted Ion Species Percentages ......... 5-31 x Abstract An analysis of plasma transport through the magnetic filter in mag- netic...diffusion through the magnetic filter field into the extraction chamber. The goal was not, however, simply to calculate the plasma potential. Analysis of

  12. Modeling of surface-dominated plasmas: from electric thruster to negative ion source.

    PubMed

    Taccogna, F; Schneider, R; Longo, S; Capitelli, M

    2008-02-01

    This contribution shows two important applications of the particle-in-cell/monte Carlo technique on ion sources: modeling of the Hall thruster SPT-100 for space propulsion and of the rf negative ion source for ITER neutral beam injection. In the first case translational degrees of freedom are involved, while in the second case inner degrees of freedom (vibrational levels) are excited. Computational results show how in both cases, plasma-wall and gas-wall interactions play a dominant role. These are secondary electron emission from the lateral ceramic wall of SPT-100 and electron capture from caesiated surfaces by positive ions and atoms in the rf negative ion source.

  13. Negative ion beam injection apparatus with magnetic shield and electron removal means

    DOEpatents

    Anderson, Oscar A.; Chan, Chun F.; Leung, Ka-Ngo

    1994-01-01

    A negative ion source is constructed to produce H.sup.- ions without using Cesium. A high percentage of secondary electrons that typically accompany the extracted H.sup.- are trapped and eliminated from the beam by permanent magnets in the initial stage of acceleration. Penetration of the magnetic field from the permanent magnets into the ion source is minimized. This reduces the destructive effect the magnetic field could have on negative ion production and extraction from the source. A beam expansion section in the extractor results in a strongly converged final beam.

  14. Air ion mobility spectra and concentrations upwind and downwind of overhead AC high voltage power lines

    NASA Astrophysics Data System (ADS)

    Wright, Matthew D.; Buckley, Alison J.; Matthews, James C.; Shallcross, Dudley E.; Henshaw, Denis L.

    2014-10-01

    Corona ions produced by high-voltage power lines (HVPLs) can alter the nearby electrical environment, potentially increasing aerosol charge levels downwind. However, there is a lack of knowledge concerning the concentration and mobility of ions from AC HVPLs and their dispersion away from the line. We present ion concentration and mobility measurements made near AC HVPLs in South-West England. Examples of typical mobility spectra are shown highlighting features commonly observed. Corona was observed during 33 of 46 measurements, at 9 of 11 sites, with positive or ‘bipolar' (both polarities) ion production commonly seen. Ion production usually increases atmospheric concentrations by only a modest amount, but extreme cases can enhance concentration by an order of magnitude or more. A polarity imbalance is required to increase aerosol charge via ion attachment; this was observed on 15 of 24 days when positive corona was observed, but was not seen for negative ions. Ion mobility was higher downwind compared with upwind for both ion polarities, but the increase was not statistically significant. Future work should focus on identifying and characterising ‘heavy-producing' HVPLs, and obtaining results in conditions which may favour negative ion production e.g. high humidity, inclement weather or during nighttime.

  15. Research progress on ionic plasmas generated in an intense hydrogen negative ion source

    SciTech Connect

    Takeiri, Y. Tsumori, K.; Nagaoka, K.; Kaneko, O.; Ikeda, K.; Nakano, H.; Kisaki, M.; Tokuzawa, T.; Osakabe, M.; Kondo, T.; Sato, M.; Shibuya, M.; Komada, S.; Sekiguchi, H.; Geng, S.

    2015-04-08

    Characteristics of ionic plasmas, observed in a high-density hydrogen negative ion source, are investigated with a multi-diagnostics system. The ionic plasma, which consists of hydrogen positive- and negative-ions with a significantly low-density of electrons, is generated in the ion extraction region, from which the negative ions are extracted through the plasma grid. The negative ion density, i.e., the ionic plasma density, as high as the order of 1×10{sup 17}m{sup −3}, is measured with cavity ring-down spectroscopy, while the electron density is lower than 1×10{sup 16}m{sup −3}, which is confirmed with millimeter-wave interferometer. Reduction of the negative ion density is observed at the negative ion extraction, and at that time the electron flow into the ionic plasma region is observed to conserve the charge neutrality. Distribution of the plasma potential is measured in the extraction region in the direction normal to the plasma grid surface with a Langmuir probe, and the results suggest that the sheath is formed at the plasma boundary to the plasma grid to which the bias voltage is applied. The beam extraction should drive the negative ion transport in the ionic plasma across the sheath formed on the extraction surface. Larger reduction of the negative ions at the beam extraction is observed in a region above the extraction aperture on the plasma grid, which is confirmed with 2D image measurement of the Hα emission and cavity ring-down spectroscopy. The electron distribution is also measured near the plasma grid surface. These various properties observed in the ionic plasma are discussed.

  16. Uniform H(-) ion beam extraction in a large negative ion source with a tent-shaped magnetic filter.

    PubMed

    Tobari, H; Hanada, M; Kashiwagi, M; Taniguchi, M; Umeda, N; Watanabe, K; Inoue, T; Sakamoto, K; Takado, N

    2008-02-01

    Based on previous studies on the spatial uniformity of the negative ion beam, the external magnetic filter was replaced to a novel tent-shaped magnetic filter in the JAEA 10 A negative ion source. The line-cusp field configuration on the source chamber was also changed to form a symmetric magnetic field like many of positive ion sources aiming at high proton yield. This magnetic field configuration allows fast electrons emitted from filament cathodes to rotate azimuthally inside the source chamber. The source configuration thus prevents localization of fast electrons due to their B x grad B drift in the filter field. As a result, the H(-) ion beam profile extracted from a wide region of 340 x 170 mm(2) showed reduction of standard deviation from 16% in the original to 7.9% with the tent filter. The negative ion source with the tent filter satisfied the requirement of the beam uniformity for a large negative ion source in the ITER neutral beam injection.

  17. EFFECT OF NEGATIVE ION ATMOSPHERIC LOADING ON COGNITIVE PERFORMANCE IN HUMAN VOLUNTEERS

    PubMed Central

    Andrade, A. Chitra; Fernandes, Charlotte; Verghese, Leila; Andrade, Chittaranjan

    1992-01-01

    Negative ion atmospheric loading has been reported to affect a range of psychological functions, from alertness to circadian rhythms, and has been suggested to benefit a variety of medical conditions, from allergies to migraine. In a double-blind study planned to assess the effect of negative ions on cognitive performance in human volunteers, 65 female graduate course students were randomized into ionized atmosphere (n = 34) and control (n = 31) groups. The following cognitive tasks were administered: Digit Symbol Substitution Test, Addition Test, Visual Memory (Complex Figure) Test, Verbal Memeory (Complex Passage) Test, Ideational Fluency Test and Clerical Speed and Accuracy test. On all but the last two tests, the negative ion groupperfonned significantly better (to a 15-40% extent) than controls. It is concluded that negative ionization of the atmosphere by artificial means may be of benefit in certain common, practical situation in which depletion of these ions occurs. PMID:21776128

  18. Detection of artificially created negative ion clouds with incoherent scatter radar

    NASA Technical Reports Server (NTRS)

    Sultan, Peter J.; Mendillo, Michael; Oliver, William L.; Holt, John M.

    1992-01-01

    The physical mechanisms by which negative ions change the shape of the incoherent scatter spectrum, and the way in which shape changes may be used to detect the presence of heavy positive and negative ions in an ambient ionosphere are investigated. In order to detect heavy negative ions, the temperature structure of the ionosphere is fixed to a prevent average measurement, and any changes in spectral shape during the experiment are interpreted as being caused by changes in composition, and not by changes in the temperature ratio Te/Ti. The spatial and temporal development of heavy negative ion plasma clouds created during four active chemical release experiments was observed. Concentrations of 10-40-percent SF6(-) were detected in SPINEX 1, SPINEX 2, and IMS data sets. An average uncertainty of +/-10-percent SF6(-) is present in all three experiments. Concentrations of 30-percent Br(-) were detected in the NICARE 1 release, with uncertainties of +/-4 percent.

  19. Study of negative hydrogen ion beam optics using the 3D3V PIC model

    SciTech Connect

    Miyamoto, K.; Nishioka, S.; Goto, I.; Hatayama, A.; Hanada, M.; Kojima, A.

    2015-04-08

    The mechanism of negative ion extraction under real conditions with the complex magnetic field is studied by using the 3D PIC simulation code. The extraction region of the negative ion source for the negative ion based neutral beam injection system in fusion reactors is modelled. It is shown that the E x B drift of electrons is caused by the magnetic filter and the electron suppression magnetic field, and the resultant asymmetry of the plasma meniscus. Furthermore, it is indicated that that the asymmetry of the plasma meniscus results in the asymmetry of negative ion beam profile including the beam halo. It could be demonstrated theoretically that the E x B drift is not significantly weakened by the elastic collisions of the electrons with neutral particles.

  20. Ion Thruster Power Levels Extended by a Factor of 10

    NASA Technical Reports Server (NTRS)

    Patterson, Michael J.

    2004-01-01

    In response to two NASA Office of Space Science initiatives, the NASA Glenn Research Center is now developing a 7-kW-class xenon ion thruster system for near-term solar-powered spacecraft and a 25-kW ion engine for nuclear-electric spacecraft. The 7-kW ion thruster and power processor can be throttled down to 1 kW and are applicable to 25-kW flagship missions to the outer planets, asteroids, and comets. This propulsion system was scaled up from the 2.5-kW ion thruster and power processor that was developed successfully by Glenn, Boeing, the Jet Propulsion Laboratory (JPL), and Spectrum Astro for the Deep Space 1 spacecraft. The 7-kW ion thruster system is being developed under NASA's Evolutionary Xenon Thruster (NEXT) project, which includes partners from JPL, Aerojet, Boeing, the University of Michigan, and Colorado State University.

  1. Studies of Transition States, Clusters, and Radicals by Negative Ion Photodetachment and Photodissociation

    DTIC Science & Technology

    2006-04-24

    developed a new method for high resolution photodetachment spectroscopy of negative ions based on photoelectron imaging ( SEVI , or Slow photoElectron...new method for high resolution photodetachment spectroscopy of negative ions based on photoelectron imaging ( SEVI , or Slow photoElectron Velocity-map...velocity map imaging and anion threshold photodetachment. This method, Slow Electron Velocity-map Imaging ( SEVI ), provides spectral line widths of better

  2. A Benign, Low Z Electron Capture Agent for Negative Ion TPCs

    NASA Technical Reports Server (NTRS)

    Martoff, C. J.; Dion, M. P.; Hosack, M.; Barton, D.; Black, J. K.

    2008-01-01

    We have identified nitromethane (CH3NO2) as an effective electron capture agent for negative ion TPCs (NITPCs). We present drift velocity and longitudinal diffusion measurements for negative ion gas mixtures using nitromethane as the capture agent. Not only is nitromethane substantially more benign than the only other identified capture agent, CS2, but its low atomic number will enable the use of the NITPC as a photoelectric X-ray polarimeter in the 1-10 keV band.

  3. Anion exchangers with negatively charged functionalities in hyperbranched ion-exchange layers for ion chromatography.

    PubMed

    Uzhel, Anna S; Zatirakha, Alexandra V; Smirnov, Konstantin N; Smolenkov, Alexandr D; Shpigun, Oleg A

    2017-01-27

    Novel pellicular poly(styrene-divinylbenzene)-based (PS-DVB) anion exchangers with covalently-bonded hyperbranched functional ion-exchange layers containing negatively charged functionalities are obtained and examined. The hyperbranched coating is created on the surface of aminated PS-DVB substrate by repeating the modification cycles including alkylation with 1,4-butanediol diglycidyl ether (1,4-BDDGE), and amination of the terminal epoxide rings with methylamine (MA) or glycine (Gly). The influence of the position and the number of the layers with glycine, as well as of the total number of the layers of amine in the coating on the chromatographic properties of the obtained stationary phases is investigated. Chromatographic performance of the obtained stationary phases is evaluated using the model mixtures of inorganic and organic anions with hydroxide eluent. It is shown that the best selectivity toward weakly retained organic acids and oxyhalides is possessed by the anion exchanger obtained after 5 modification cycles, with glycine being used in the first one. Such anion exchanger packed in 25-cm long column is capable of separating 22 anions in 58min including 7 standard anions, mono-, di- and trivalent organic acids, oxyhalides, and some other double- and triple-charged anions.

  4. Air Purification Effect of Positively and Negatively Charged Ions Generated by Discharge Plasma at Atmospheric Pressure

    NASA Astrophysics Data System (ADS)

    Nishikawa, Kazuo; Nojima, Hideo

    2001-08-01

    In this paper, the air purification effect of positively and negatively charged ions generated by discharge plasma at atmospheric pressure is reported. We have developed a novel ion generation device which consists of a cylindrical glass tube and attached inner and outer mesh electrodes. With the application of AC voltage between the electrodes, positively charged ions and negatively charged ions have been generated at atmospheric pressure. The ion densities of 3.0× 104--7.0× 104 counts/cm3 have been obtained with the AC voltage of 1.8-2.3 kV (effective value). We have examined the air purification properties of this device. By the operation of this device, the initial oxygen nitride (NO) density of 10 ppm in 1 m3 (in cigarette smoke) was decreased to 1 ppm after 30 min. The number of suspended germs in air has been significantly reduced by the use of this type of ion generation device.

  5. Development of a versatile multiaperture negative ion sourcea)

    NASA Astrophysics Data System (ADS)

    Cavenago, M.; Kulevoy, T.; Petrenko, S.; Serianni, G.; Antoni, V.; Bigi, M.; Fellin, F.; Recchia, M.; Veltri, P.

    2012-02-01

    A 60 kV ion source (9 beamlets of 15 mA each of H-) and plasma generators are being developed at Consorzio RFX and INFN-LNL, for their versatility in experimental campaigns and for training. Unlike most experimental sources, the design aimed at continuous operation. Magnetic configuration can achieve a minimum |B| trap, smoothly merged with the extraction filter. Modular design allows for quick substitution and upgrading of parts such as the extraction and postacceleration grids or the electrodes in contact with plasma. Experiments with a radio frequency plasma generator and Faraday cage inside the plasma are also described.

  6. Development of a versatile multiaperture negative ion source.

    PubMed

    Cavenago, M; Kulevoy, T; Petrenko, S; Serianni, G; Antoni, V; Bigi, M; Fellin, F; Recchia, M; Veltri, P

    2012-02-01

    A 60 kV ion source (9 beamlets of 15 mA each of H(-)) and plasma generators are being developed at Consorzio RFX and INFN-LNL, for their versatility in experimental campaigns and for training. Unlike most experimental sources, the design aimed at continuous operation. Magnetic configuration can achieve a minimum ∣B∣ trap, smoothly merged with the extraction filter. Modular design allows for quick substitution and upgrading of parts such as the extraction and postacceleration grids or the electrodes in contact with plasma. Experiments with a radio frequency plasma generator and Faraday cage inside the plasma are also described.

  7. Development of a versatile multiaperture negative ion source

    SciTech Connect

    Cavenago, M.; Kulevoy, T.; Petrenko, S.; Serianni, G.; Antoni, V.; Bigi, M.; Fellin, F.; Recchia, M.; Veltri, P.

    2012-02-15

    A 60 kV ion source (9 beamlets of 15 mA each of H{sup -}) and plasma generators are being developed at Consorzio RFX and INFN-LNL, for their versatility in experimental campaigns and for training. Unlike most experimental sources, the design aimed at continuous operation. Magnetic configuration can achieve a minimum |B| trap, smoothly merged with the extraction filter. Modular design allows for quick substitution and upgrading of parts such as the extraction and postacceleration grids or the electrodes in contact with plasma. Experiments with a radio frequency plasma generator and Faraday cage inside the plasma are also described.

  8. Ion beam transport: modelling and experimental measurements on a large negative ion source in view of the ITER heating neutral beam

    NASA Astrophysics Data System (ADS)

    Veltri, P.; Sartori, E.; Agostinetti, P.; Aprile, D.; Brombin, M.; Chitarin, G.; Fonnesu, N.; Ikeda, K.; Kisaki, M.; Nakano, H.; Pimazzoni, A.; Tsumori, K.; Serianni, G.

    2017-01-01

    Neutral beam injectors are among the most important methods of plasma heating in magnetic confinement fusion devices. The propagation of the negative ions, prior to their conversion into neutrals, is of fundamental importance in determining the properties of the beam, such as its aiming and focusing at long-distances, so as to deposit the beam power in the proper position inside the confined plasma, as well as to avoid interaction with the material surfaces along the beam path. The final design of the ITER Heating Neutral Beam prototype has been completed at Consorzio RFX (Padova, Italy), in the framework of a close collaboration with European, Japanese and Indian fusion research institutes. The physical and technical rationales on which the design is based were essentially driven by numerical modelling of the relevant physical processes, and the same models and codes will be useful to design the DEMO neutral beam injector in the near future. This contribution presents a benchmark study of the codes used for this purpose, by comparing their results against the measures performed in an existing large-power device, hosted at the National Institute for Fusion Science, Japan. In particular, the negative ion formation and acceleration are investigated. A satisfactory agreement was found between codes and experiments, leading to an improved understanding of beam transport dynamics. The interpretation of the discrepancies identified in previous works, possibly related to the non-uniformity of the extracted negative ion current, is also presented.

  9. The influence of fast ions on the magnetohydrodynamic stability of negative shear profiles

    SciTech Connect

    Helander, P.; Gimblett, C.G.; Hastie, R.J.; McClements, K.G.

    1997-06-01

    The influence of energetic ions on the stability of ideal double kink modes in a tokamak plasma with negative magnetic shear is investigated. It is found that the fast ions play a similar role as for the ordinary m=n=1 internal kink. In particular, phenomena analogous to sawtooth stabilization and fishbone excitation are possible.

  10. Negative Ion Metal Etching by Employing Magnetic Filter in Halogen Plasma

    NASA Astrophysics Data System (ADS)

    Horiike, Y.

    1998-10-01

    To neutralize the positively charged-up bottom surfaces of high aspect ratio holes or gaps, generation of negative ions in halogen downstream plasmas and their alternate irradiation by the transformer coupling of the RF field with the electrode have been studied. In the previous work, the Si etching employing negative ions revealed the high etching reactivity which resulted from the fact that dominant negative species were formed by ions of atoms like F^- in SF6 and Cl^- in Cl2 plasmas. It is expected that the negative ion etching is more effective for metals because the metal bonding is weakened by supply of negative charge. Indeed, the Al-Si-Cu etch rate of 130 nm/sec was achieved. However, the negative ions are difficult to be introduced to an electrode covered by insulators such as an electrostatic chucking due to generation of the self biasing. To overcome this problem, the trapping of electrons was examined in the downstream choline plasma by employing a magnetic filter, which consisted of a pair of water-cooled high current coils set in the etching chamber. The ratio of positively biasing to negatively biasing saturation currents was reduced as low as several. However, at present still remained electrons generate a little self biasing, thus lowering Al etch rates.

  11. Stopping Power and Range of Ions in Matter

    SciTech Connect

    2001-06-19

    SRIM is a group of programs which calculate the stopping and range of ions (10ev - 2 GeV/amu) into matter. TRIM (the Transport of Ions in Matter) is the most comprehensive program included. Trim will accept complex targets made of compound materials with up to eight layers, each with different materials. It will calculate both the final 3d distribution of the inner ions and also all kinetic phenomena associated with the ion''s energy loss; target damage, sputtering, ionization, and phonon production. All targets atom cascades in the target are followed in detail. It can be used for physics of recoil cascades, physics of sputtering, the stopping of ions in compounds and stopping power for ions in gases; This included radiation damage from neutron , electrons, and photons.

  12. Linac4 low energy beam measurements with negative hydrogen ions

    NASA Astrophysics Data System (ADS)

    Scrivens, R.; Bellodi, G.; Crettiez, O.; Dimov, V.; Gerard, D.; Granemann Souza, E.; Guida, R.; Hansen, J.; Lallement, J.-B.; Lettry, J.; Lombardi, A.; Midttun, Ø.; Pasquino, C.; Raich, U.; Riffaud, B.; Roncarolo, F.; Valerio-Lizarraga, C. A.; Wallner, J.; Yarmohammadi Satri, M.; Zickler, T.

    2014-02-01

    Linac4, a 160 MeV normal-conducting H- linear accelerator, is the first step in the upgrade of the beam intensity available from the LHC proton injectors at CERN. The Linac4 Low Energy Beam Transport (LEBT) line from the pulsed 2 MHz RF driven ion source, to the 352 MHz RFQ (Radiofrequency Quadrupole) has been built and installed at a test stand, and has been used to transport and match to the RFQ a pulsed 14 mA H- beam at 45 keV. A temporary slit-and-grid emittance measurement system has been put in place to characterize the beam delivered to the RFQ. In this paper a description of the LEBT and its beam diagnostics is given, and the results of beam emittance measurements and beam transmission measurements through the RFQ are compared with the expectation from simulations.

  13. Linac4 low energy beam measurements with negative hydrogen ions

    SciTech Connect

    Scrivens, R. Bellodi, G.; Crettiez, O.; Dimov, V.; Gerard, D.; Granemann Souza, E.; Guida, R.; Hansen, J.; Lallement, J.-B.; Lettry, J.; Lombardi, A.; Midttun, Ø.; Pasquino, C.; Raich, U.; Riffaud, B.; Roncarolo, F.; Valerio-Lizarraga, C. A.; Wallner, J.; Yarmohammadi Satri, M.; Zickler, T.

    2014-02-15

    Linac4, a 160 MeV normal-conducting H{sup −} linear accelerator, is the first step in the upgrade of the beam intensity available from the LHC proton injectors at CERN. The Linac4 Low Energy Beam Transport (LEBT) line from the pulsed 2 MHz RF driven ion source, to the 352 MHz RFQ (Radiofrequency Quadrupole) has been built and installed at a test stand, and has been used to transport and match to the RFQ a pulsed 14 mA H{sup −} beam at 45 keV. A temporary slit-and-grid emittance measurement system has been put in place to characterize the beam delivered to the RFQ. In this paper a description of the LEBT and its beam diagnostics is given, and the results of beam emittance measurements and beam transmission measurements through the RFQ are compared with the expectation from simulations.

  14. Electrochemical Study of Hollow Carbon Nanospheres as High-Rate and Low Temperature Negative Electrodes for Lithium Ion Batteries

    NASA Astrophysics Data System (ADS)

    Cox, Jonathan David

    The continued advancements in portable electronics have demanded more advanced power sources. To date, lithium ion batteries have been the state-of-the-art for portable devices. One significant drawback of lithium ion batteries is the slow charging times and their performance at low temperatures. In this dissertation, we explore the electrochemical behavior of a new lithium ion, negative electrode active material, hollow carbon nanospheres (HCNS). HCNS are ˜50 nm in diameter hollow spheres with ˜5 - 10 nm graphic walls which have a nominal reversible capacity of ˜220 mAh/g. We assembled and cycled HCNS as a lithium ion anode material and compared it to graphite, currently used as the anode material in most commercial lithium ion batteries. The charging mechanism of HCNS is an intercalation of the lithium ions into the graphitic walls of the spheres, similar to graphite, determined by diffraction and electroanalytical techniques. However, the HCNS electrodes cycled at much higher charge and discharge rates than graphite. Additionally, we demonstrated HCNS cycling at low temperatures (-20 *C) in electrolytes not obtainable by graphite due to material exfoliation during cycling. Although, due to the large surface area of HCNS, the first cycle coulombic losses are very high. This work has resulted in an understanding of a potentially new lithium ion battery anode material with significantly better cycling attributes than the current anode material.

  15. Simplified power supplies for ion thrusters

    NASA Technical Reports Server (NTRS)

    Gruber, R. P.

    1981-01-01

    The initial development and demonstration of power supplies with an order of magnitude reduction in parts count, leading to increased reliability at lower weight, while still maintaining thrust system performance are discussed. Two new self-regulating keeper power supply circuits were developed and tested. One supply comprises 14 parts and uses an input voltage range of 18 to 36 volts, the other operates from 200 to 400 volts and requires 22 components. A technique for controlling heater power is also demonstrated.

  16. High voltage holding in the negative ion sources with cesium deposition

    SciTech Connect

    Belchenko, Yu.; Abdrashitov, G.; Ivanov, A.; Sanin, A.; Sotnikov, O.

    2016-02-15

    High voltage holding of the large surface-plasma negative ion source with cesium deposition was studied. It was found that heating of ion-optical system electrodes to temperature >100 °C facilitates the source conditioning by high voltage pulses in vacuum and by beam shots. The procedure of electrode conditioning and the data on high-voltage holding in the negative ion source with small cesium seed are described. The mechanism of high voltage holding improvement by depletion of cesium coverage is discussed.

  17. Solutions to heavy ion induced avalanche burnout in power devices

    SciTech Connect

    Wrobel, T.F.; Beutler, D.E.

    1991-01-01

    Silicon power devices fall into two broad categories, bipolar and field effect. Transistors using both of these technologies are often used in satellite applications for power conversion. The present trend is toward integrating power transistors and control electronics on the same chip. In this case, it is the power portion of the chip that is most susceptible to burnout failures, because of it's high voltage operation. Hence, it is important to understand the operational limitations of power transistors when exposed to intense heavy ion and/or dose-rate environments. Reviews of normal breakdown and current induced avalanche breakdown mechanisms in silicon power transistors are presented. We show the applicability of the current induced avalanche model to heavy ion induced burnouts and present solutions to current induced avalanche in silicon power semiconductors. 9 refs., 5 figs.

  18. Observation of Plasma Recombination with the Negative Ions in Detached Plasma

    NASA Astrophysics Data System (ADS)

    Tonegawa, Akira; Shirota, Isao; Yoshida, Kenichi; Sugimoto, Tatunori; Kawamura, Kazutaka; Watanabe, Tsuguhiro; Ohyabu, Nobuyoshi; Takayama, Kazuo

    2000-10-01

    Detached divertors regimes are characterized by a low temperature (few eV) and high density plasma near the divertor plates. Recently, a new recombination process associated with excited hydrogen molecule, that is, molecular activated recombination (MAR), is expected to lead to an enhancement of the reduction of ion particle flux, and to modify the structure of detached recombining plasmas. In particular, negative ions play a key role in detached divertors regimes in charge exchange recombination of MAR. We present the experimental investigation of effects of the negative ions on detached plasma with MAR in the linear divertor plasma simulator, TPDSHEET-IV (Test Plasma produced by Directed current for SHEET plasma) device. The hydrogen plasma were generated with the hydrogen gas flow of 100 sccm at the discharge current of 50 A and the magnetic field of 0.7 kG. The negative ion density of hydrogen atom was measure by a probe-assisted laser photodetachment method. The reduction of the heat load to the target plate was clearly observed in hydrogen plasma with the hydrogen gas puff. At the same time, negative ions of hydrogen atom are localized in the region of cold electrons (2 eV) of the circumference of the sheet plasma. The charge exchange recombination rate of MAR is about 4 times of magnitude larger than three body recombination rate coefficients at this temperature. These experimental results suggest that the plasma recombination process comes from the negative ion of hydrogen atom.

  19. Installation of spectrally selective imaging system in RF negative ion source

    SciTech Connect

    Ikeda, K. Kisaki, M.; Nagaoka, K.; Nakano, H.; Osakabe, M.; Tsumori, K.; Kaneko, O.; Takeiri, Y.; Wünderlich, D.; Fantz, U.; Heinemann, B.; Geng, S.

    2016-02-15

    A spectrally selective imaging system has been installed in the RF negative ion source in the International Thermonuclear Experimental Reactor-relevant negative ion beam test facility ELISE (Extraction from a Large Ion Source Experiment) to investigate distribution of hydrogen Balmer-α emission (H{sub α}) close to the production surface of hydrogen negative ion. We selected a GigE vision camera coupled with an optical band-path filter, which can be controlled remotely using high speed network connection. A distribution of H{sub α} emission near the bias plate has been clearly observed. The same time trend on H{sub α} intensities measured by the imaging diagnostic and the optical emission spectroscopy is confirmed.

  20. Laser photodetachment diagnostics of a 1/3-size negative hydrogen ion source for NBI

    SciTech Connect

    Geng, S.; Tsumori, K.; Nakano, H.; Kisaki, M.; Ikeda, K.; Takeiri, Y.; Osakabe, M.; Nagaoka, K.; Kaneko, O.

    2015-04-08

    To investigate the flows of charged particles in front of the plasma grid (PG) in a negative hydrogen ion source, the information of the local densities of electrons and negative hydrogen ions (H-) are necessary. For this purpose, the laser photodetachment is applied for pure hydrogen plasmas and Cs-seeded plasma in a 1/3-size negative hydrogen ion source in NIFS-NBI test stand. The H- density obtained by photodetachment is calibrated by the results from cavity ring-down (CRD). The pressure dependence and PG bias dependence of the local H- density are presented and discussed. The results show that H- density increases significantly by seeding Cs into the plasma. In Cs-seeded plasma, relativity exists between the H- ion density and plasma potential.

  1. Parallel-velocity-shear-modified drift wave in negative ion plasmas

    NASA Astrophysics Data System (ADS)

    Ichiki, R.; Kaneko, T.; Hayashi, K.; Tamura, S.; Hatakeyama, R.

    2009-03-01

    A systematic investigation of the effects of a parallel velocity shear and negative ions on the collisionless drift wave instability has for the first time been realized by simultaneously using a segmented tungsten hot plate of a Q-machine and sulfur hexafluoride (SF6) gas in a magnetized potassium plasma. The parallel velocity shear of the positive ion flow tends to decrease the fluctuation level of the drift wave. The introduction of negative ions first increases the fluctuation level and then starts to decrease it at the negative ion exchange fraction of around 10%, while keeping the above-mentioned shear effect qualitatively. In addition, a simple dispersion relation based on the local model has been calculated to show that it can predict wave characteristics similar to the experimental results. Our findings provide a potential for gaining a more profound insight into the physics of space/circumterrestrial plasmas.

  2. Roles of a plasma grid in a negative hydrogen ion source

    SciTech Connect

    Bacal, M.; Sasao, M.; Wada, M.; McAdams, R.

    2015-04-08

    The plasma grid is electrically biased with respect to other parts of source chamber wall in both volume sources and sources seeded with alkali metals. The roles of the plasma grid in these two kinds of sources will be described. The main functions of the plasma grid in volume sources are: optimizing the extracted negative ion current, reducing the co-extracted electron current, controlling the axial plasma potential profile, recycling the hydrogen atoms to molecules, concentrating the negative ions near its surface and, when biased positive, depleting the electron population near its surface. These functions are maintained in the sources seeded with alkali metals. However an additional function appears in the Cs seeded sources, namely direct emission of negative ions under positive ion and neutral hydrogen bombardment.

  3. Effects of negative air ions on growth and regeneration in the Indian stick insect

    NASA Astrophysics Data System (ADS)

    Hinsull, S. M.; Evans, G. S.; Bellamy, D.; Head, E. L.

    1983-06-01

    Nymphs of the Indian stick insect Carausius morosus, Brunner were maintained at ambient or 4.2×104 negative ions per c.c. Regenerative processes were initiated in each nymph by stimulation of the leg autotomy reflex. Aspects of growth, the moulting cycles and leg renewal were studied. Few significant weight differences were found between the insects growing in the control and ionized environments. However, the growth curve of the ion treated insects was irregular, unlike that of the control group which increased smoothly. Slight delays in the intermoult period and in the rate of leg regeneration were also noted in those insects exposed to negative ions. Previous workers have shown significant increases in the growth of some insects exposed to negative ions. These new results show no significant effects but suggest growth may be inhibited.

  4. Simulation of space charge compensation in a multibeamlet negative ion beam

    SciTech Connect

    Sartori, E. Veltri, P.; Serianni, G.; Maceina, T. J.; Cavenago, M.

    2016-02-15

    Ion beam space charge compensation occurs by cumulating in the beam potential well charges having opposite polarity, usually generated by collisional processes. In this paper we investigate the case of a H{sup −} ion beam drift, in a bi-dimensional approximation of the NIO1 (Negative Ion Optimization phase 1) negative ion source. H{sup −} beam ion transport and plasma formation are studied via particle-in-cell simulations. Differential cross sections are sampled to determine the velocity distribution of secondary particles generated by ionization of the residual gas (electrons and slow H{sub 2}{sup +} ions) or by stripping of the beam ions (electrons, H, and H{sup +}). The simulations include three beamlets of a horizontal section, so that multibeamlet space charge and secondary particle diffusion between separate generation regions are considered, and include a repeller grid biased at various potentials. Results show that after the beam space charge is effectively screened by the secondary plasma in about 3 μs (in agreement with theoretical expectations), a plasma grows across the beamlets with a characteristic time three times longer, and a slight overcompensation of the electric potential is verified as expected in the case of negative ions.

  5. Development of a negative ion-based neutral beam injector in Novosibirsk

    NASA Astrophysics Data System (ADS)

    Ivanov, A. A.; Abdrashitov, G. F.; Anashin, V. V.; Belchenko, Yu. I.; Burdakov, A. V.; Davydenko, V. I.; Deichuli, P. P.; Dimov, G. I.; Dranichnikov, A. N.; Kapitonov, V. A.; Kolmogorov, V. V.; Kondakov, A. A.; Sanin, A. L.; Shikhovtsev, I. V.; Stupishin, N. V.; Sorokin, A. V.; Popov, S. S.; Tiunov, M. A.; Belov, V. P.; Gorbovsky, A. I.; Kobets, V. V.; Binderbauer, M.; Putvinski, S.; Smirnov, A.; Sevier, L.

    2014-02-01

    A 1000 keV, 5 MW, 1000 s neutral beam injector based on negative ions is being developed in the Budker Institute of Nuclear Physics, Novosibirsk in collaboration with Tri Alpha Energy, Inc. The innovative design of the injector features the spatially separated ion source and an electrostatic accelerator. Plasma or photon neutralizer and energy recuperation of the remaining ion species is employed in the injector to provide an overall energy efficiency of the system as high as 80%. A test stand for the beam acceleration is now under construction. A prototype of the negative ion beam source has been fabricated and installed at the test stand. The prototype ion source is designed to produce 120 keV, 1.5 A beam.

  6. Development of a negative ion-based neutral beam injector in Novosibirsk.

    PubMed

    Ivanov, A A; Abdrashitov, G F; Anashin, V V; Belchenko, Yu I; Burdakov, A V; Davydenko, V I; Deichuli, P P; Dimov, G I; Dranichnikov, A N; Kapitonov, V A; Kolmogorov, V V; Kondakov, A A; Sanin, A L; Shikhovtsev, I V; Stupishin, N V; Sorokin, A V; Popov, S S; Tiunov, M A; Belov, V P; Gorbovsky, A I; Kobets, V V; Binderbauer, M; Putvinski, S; Smirnov, A; Sevier, L

    2014-02-01

    A 1000 keV, 5 MW, 1000 s neutral beam injector based on negative ions is being developed in the Budker Institute of Nuclear Physics, Novosibirsk in collaboration with Tri Alpha Energy, Inc. The innovative design of the injector features the spatially separated ion source and an electrostatic accelerator. Plasma or photon neutralizer and energy recuperation of the remaining ion species is employed in the injector to provide an overall energy efficiency of the system as high as 80%. A test stand for the beam acceleration is now under construction. A prototype of the negative ion beam source has been fabricated and installed at the test stand. The prototype ion source is designed to produce 120 keV, 1.5 A beam.

  7. A discharge with a magnetic X-point as a negative hydrogen ion source

    SciTech Connect

    Tsankov, Tsanko; Czarnetzki, Uwe

    2011-09-26

    The study presents first results from investigations of a novel low-pressure plasma source, intended for a negative hydrogen ion production. The source utilizes a dc magnetic field, shaped to form a cusp with a magnetic null-point (X-point). Beside the common role of filtering out the high energy electrons, this magnetic field configuration ensures in the present case also an interesting mechanism of coupling the RF power to the plasma. Investigations performed using radio frequency modulation spectroscopy (RFMOS) reveal that the main power coupling to the electrons is confined in the region on one side of the X-point. The modulation of the light intensity indicates also the presence of a strong dc drift close to the plane of the X-point. Several hypothesises for its explanation are raised: an azimuthal diamagnetic drift due to strong axial gradients of the electron energy, the excitation of a standing helicon wave, which couples to the radial magnetic field in the plane of the X-point, or a Trivelpiece-Gould wave which is resonantly absorbed near the plane of the X-point.

  8. Thomson spectrometer-microchannel plate assembly calibration for MeV-range positive and negative ions, and neutral atoms

    SciTech Connect

    Prasad, R.; Abicht, F.; Braenzel, J.; Priebe, G.; Schnuerer, M.; Borghesi, M.; Ter-Avetisyan, S.; Nickles, P. V.

    2013-05-15

    We report on the absolute calibration of a microchannel plate (MCP) detector, used in conjunction with a Thomson parabola spectrometer. The calibration delivers the relation between a registered count numbers in the CCD camera (on which the MCP phosphor screen is imaged) and the number of ions incident on MCP. The particle response of the MCP is evaluated for positive, negative, and neutral particles at energies below 1 MeV. As the response of MCP depends on the energy and the species of the ions, the calibration is fundamental for the correct interpretation of the experimental results. The calibration method and arrangement exploits the unique emission symmetry of a specific source of fast ions and atoms driven by a high power laser.

  9. Thomson spectrometer-microchannel plate assembly calibration for MeV-range positive and negative ions, and neutral atoms

    NASA Astrophysics Data System (ADS)

    Prasad, R.; Abicht, F.; Borghesi, M.; Braenzel, J.; Nickles, P. V.; Priebe, G.; Schnürer, M.; Ter-Avetisyan, S.

    2013-05-01

    We report on the absolute calibration of a microchannel plate (MCP) detector, used in conjunction with a Thomson parabola spectrometer. The calibration delivers the relation between a registered count numbers in the CCD camera (on which the MCP phosphor screen is imaged) and the number of ions incident on MCP. The particle response of the MCP is evaluated for positive, negative, and neutral particles at energies below 1 MeV. As the response of MCP depends on the energy and the species of the ions, the calibration is fundamental for the correct interpretation of the experimental results. The calibration method and arrangement exploits the unique emission symmetry of a specific source of fast ions and atoms driven by a high power laser.

  10. Ar^+ recombination with negative ions in a flowing afterglow: A new approach.

    NASA Astrophysics Data System (ADS)

    Miller, Thomas M.; Viggiano, A. A.

    2006-05-01

    Ion-ion recombination (mutual neutralization) has been previously studied in a flowing-afterglow Langmuir-probe apparatus, using the probe to measure the positive-ion and negative-ion densities as a function of distance (time) along the flow tube axis.^1 A different approach has been taken in the present work, applicable to Ar^+ (or Kr^+ and Xe^+) recombination reactions. A flowing electron-Ar^+ afterglow plasma is first established, and the ambipolar diffusion frequency is measured. Then, an electron attaching gas is added to the afterglow, and the electron attachment rate constant and product ion branching fractions are measured in the usual manner.^2 Finally, the reactant gas concentration is reduced enough that the attachment reaction has not gone to completion by the end of the flow tube. Modeling of the diffusion, attachment, and recombination processes allows us to determine rate constants for each negative ion type recombining with Ar^+. For example, Ar^+ neutralized by Cl^-, Cl2^-, and CCl2O^- produced in attachment to oxalyl chloride,^2 shows that Cl2^- recombines at about half the rate constant of CCl2O^-, and Cl^- + Ar^+ recombination is negligible. ^1D. Smith and N. G. Adams, in Physics of Ion-Ion and Electron-Ion Collisions, Ed. F. Brouillard and J. W. McGowan (Plenum, New York, 1983). ^2J. M. Van Doren, T. M. Miller, and A. A. Viggiano, J. Chem. Phys. (submitted).

  11. Irradiation effect of carbon negative-ion implantation on polytetrafluoroethylene for controlling cell-adhesion property

    NASA Astrophysics Data System (ADS)

    Sommani, Piyanuch; Tsuji, Hiroshi; Kojima, Hiroyuki; Sato, Hiroko; Gotoh, Yasuhito; Ishikawa, Junzo; Takaoka, Gikan H.

    2010-10-01

    We have investigated the irradiation effect of negative-ion implantation on the changes of physical surface property of polytetrafluoroethylene (PTFE) for controlling the adhesion property of stem cells. Carbon negative ions were implanted into PTFE sheets at fluences of 1 × 10 14-1 × 10 16 ions/cm 2 and energies of 5-20 keV. Wettability and atomic bonding state including the ion-induced functional groups on the modified surfaces were investigated by water contact angle measurement and XPS analysis, respectively. An initial value of water contact angles on PTFE decreased from 104° to 88° with an increase in ion influence to 1 × 10 16 ions/cm 2, corresponding to the peak shifting of XPS C1s spectra from 292.5 eV to 285 eV with long tail on the left peak-side. The change of peak position was due to decrease of C-F 2 bonds and increase of C-C bonds with the formation of hydrophilic oxygen functional groups of OH and C dbnd O bonds after the ion implantation. After culturing rat mesenchymal stem cells (MSC) for 4 days, the cell-adhesion properties on the C --patterned PTFE were observed by fluorescent microscopy with staining the cell nuclei and their actin filament (F-actin). The clear adhesion patterning of MSCs on the PTFE was obtained at energies of 5-10 keV and a fluence of 1 × 10 15 ions/cm 2. While the sparse patterns and the uncontrollable patterns were found at a low fluence of 3 × 10 14 ions/cm 2 and a high fluence of 3 × 10 15 ions/cm 2, respectively. As a result, we could improve the surface wettability of PTFE to control the cell-adhesion property by carbon negative-ion implantation.

  12. Negative ion effects on hemispheric processing and selective attention in the mentally retarded.

    PubMed

    Morton, L L; Kershner, J R

    1987-06-01

    The effect of high concentrations of negative air ions on a dichotic digits task was investigated in 19 mentally retarded individuals. Subjects were assigned randomly to an ion or to an unmodified-air placebo condition under double-blind testing. Left and right ears were precued for report order and this order was reversed for the second set of trials. Negative ions promoted greater left hemisphere lateralization on the first set of trials, and enhanced recall when switching to the opposite channels, in the second set of trials. However, the ion-induced REA occurred at the expense of selective attention to the left channel and superior left ear recall after the right ear first condition is an anomalous dichotic listening pattern. Such paradoxical results suggest that negative ions are not necessarily beneficial or detrimental to processing. Negative ions may increase arousal, in this case amplifying a time-phased, information processing disorder in the retarded characterized by excessive right hemisphere inhibition during early processing of receptive speech and diffuse interhemispheric excitatory activation during later processing.

  13. Suppression of drift wave instability due to sheared field-aligned flow and negative ions

    NASA Astrophysics Data System (ADS)

    Ichiki, Ryuta; Hayashi, Kenichiro; Kaneko, Toshiro; Hatakeyama, Rikizo

    2006-10-01

    Sheared field-aligned plasma flow is a significant topic in space/circumterrestrial plasmas. Taking into account negative ions or dust grains will make the space plasma physics more general and accurate. Using the QT-Upgrade Machine, we have conducted laboratory experiments to examine negative ion effects on shear-modified drift waves. Field-aligned K^+ ion flow and its shear strength are controlled with a concentrically segmented W hot plate. Negative ions SF6^- are produced by introducing SF6 gas in the plasma. The drift wave shows a gradual monotonic decrease in amplitude as the shear strength is increased from zero. However, as the shear strength is decreased from zero to negative values, the amplitude increases up to a certain shear strength and rapidly decreases after the peaking. The negative ion introduction, in general, suppresses this instability while retaining the dependence of the amplitude on the shear. These wave characteristics are interpreted using the theories of current-driven (kinetic) and of D’Angelo (fluid) instabilities.

  14. Capillary Ion Concentration Polarization for Power-Free Salt Purification

    NASA Astrophysics Data System (ADS)

    Park, Sungmin; Jung, Yeonsu; Cho, Inhee; Kim, Ho-Young; Kim, Sung Jae

    2014-11-01

    In this presentation, we experimentally and theoretically demonstrated the capillary based ion concentration polarization for power-free salt purification system. Traditional ion concentration polarization phenomenon has been studied for a decade for both fundamental nanoscale fluid dynamics and novel engineering applications such as desalination, preconcentration and energy harvesting devices. While the conventional system utilizes an external power source, the system based on capillary ion concentration polarization is capable of perm-selective ion transportation only by capillarity so that the same ion depletion zone can be formed without any external power sources. An ion concentration profile near the nanostructure was tracked using fluorescent probes and analyzed by solving the modified Nernst-Planck equation. As a result, the concentration in the vicinity of the nanostructure was at least 10 times lower than that of bulk electrolyte and thus, the liquid absorbed into the nanostructure had the low concentration. This mechanism can be used for the power free salt purification system which would be significantly useful in underdeveloped and remote area. This work was supported by Samsung Research Funding Center of Samsung Electronics under Project Number SRFC-MA1301-02.

  15. Negative ion research at the Culham Centre for Fusion Energy (CCFE)

    NASA Astrophysics Data System (ADS)

    McAdams, R.; Holmes, A. J. T.; King, D. B.; Surrey, E.; Turner, I.; Zacks, J.

    2016-12-01

    A summary of negative ion development work being presently undertaken at the Culham Centre for Fusion Energy is given. The small negative ion facility has an RF driven volume ion source with beam extraction at energies up to 30 keV. The extracted beam of H- ions has an associated co-extracted electron beam with an electron to ion ratio of <1 over the whole range of operating parameters. In order to understand this performance spectroscopic investigations have been undertaken using the Balmer series line to determine the electron temperature. In addition a 1D fluid model of an RF driven ion source is also under development. This model is based on a successful model for both arc discharge positive and negative ion sources. Additional system studies of neutral beam injection systems for future fusion machines beyond ITER are being carried out. This is required to understand the limits of various neutralisation and energy recovery systems in order to maximise overall electrical efficiency.

  16. Specific interaction between negative atmospheric ions and organic compounds in atmospheric pressure corona discharge ionization mass spectrometry.

    PubMed

    Sekimoto, Kanako; Sakai, Mami; Takayama, Mitsuo

    2012-06-01

    The interaction between negative atmospheric ions and various types of organic compounds were investigated using atmospheric pressure corona discharge ionization (APCDI) mass spectrometry. Atmospheric negative ions such as O(2)(-), HCO(3)(-), COO(-)(COOH), NO(2)(-), NO(3)(-), and NO(3)(-)(HNO(3)) having different proton affinities served as the reactant ions for analyte ionization in APCDI in negative-ion mode. The individual atmospheric ions specifically ionized aliphatic and aromatic compounds with various functional groups as atmospheric ion adducts and deprotonated analytes. The formation of the atmospheric ion adducts under certain discharge conditions is most likely attributable to the affinity between the analyte and atmospheric ion and the concentration of the atmospheric ion produced under these conditions. The deprotonated analytes, in contrast, were generated from the adducts of the atmospheric ions with higher proton affinity attributable to efficient proton abstraction from the analyte by the atmospheric ion.

  17. Power processor for a 20CM ion thruster

    NASA Technical Reports Server (NTRS)

    Biess, J. J.; Schoenfeld, A. D.; Cohen, E.

    1973-01-01

    A power processor breadboard for the JPL 20CM Ion Engine was designed, fabricated, and tested to determine compliance with the electrical specification. The power processor breadboard used the silicon-controlled rectifier (SCR) series resonant inverter as the basic power stage to process all the power to the ion engine. The breadboard power processor was integrated with the JPL 20CM ion engine and complete testing was performed. The integration tests were performed without any silicon-controlled rectifier failure. This demonstrated the ruggedness of the series resonant inverter in protecting the switching elements during arcing in the ion engine. A method of fault clearing the ion engine and returning back to normal operation without elaborate sequencing and timing control logic was evolved. In this method, the main vaporizer was turned off and the discharge current limit was reduced when an overload existed on the screen/accelerator supply. After the high voltage returned to normal, both the main vaporizer and the discharge were returned to normal.

  18. Effects of feedstock availability on the negative ion behavior in a C{sub 4}F{sub 8} inductively coupled plasma

    SciTech Connect

    Zhao, Shu-Xia; Gao, Fei; Wang, Ya-Ping; Wang, You-Nian; Bogaerts, Annemie

    2015-07-21

    In this paper, the negative ion behavior in a C{sub 4}F{sub 8} inductively coupled plasma (ICP) is investigated using a hybrid model. The model predicts a non-monotonic variation of the total negative ion density with power at low pressure (10–30 mTorr), and this trend agrees well with experiments that were carried out in many fluorocarbon (fc) ICP sources, like C{sub 2}F{sub 6}, CHF{sub 3}, and C{sub 4}F{sub 8}. This behavior is explained by the availability of feedstock C{sub 4}F{sub 8} gas as a source of the negative ions, as well as by the presence of low energy electrons due to vibrational excitation at low power. The maximum of the negative ion density shifts to low power values upon decreasing pressure, because of the more pronounced depletion of C{sub 4}F{sub 8} molecules, and at high pressure (∼50 mTorr), the anion density continuously increases with power, which is similar to fc CCP sources. Furthermore, the negative ion composition is identified in this paper. Our work demonstrates that for a clear understanding of the negative ion behavior in radio frequency C{sub 4}F{sub 8} plasma sources, one needs to take into account many factors, like the attachment characteristics, the anion composition, the spatial profiles, and the reactor configuration. Finally, a detailed comparison of our simulation results with experiments is conducted.

  19. Theory and observation of a dynamically evolving negative ion plasma. [in F region

    NASA Technical Reports Server (NTRS)

    Mendillo, M.; Forbes, J.

    1982-01-01

    The study described here examines the full range of negative-ion chemistry in the upper ionosphere by using current reaction rate data to investigate the many chemical paths SF6-type injections might take in an F region environment. Special attention is given to the conditions required to create heavy negative ions that persist long enough to affect the dynamical properties of the F region. The ambipolar diffusion characteristics of a three-component plasma are described, and estimates are given of the incoherent scatter spectra obtained from such a plasma. Model calculations using a first-order chemical code are defined and tested in order to investigate the actual types of negative-ion plasma capable of being created under nighttime conditions.

  20. Modeling of plasma transport and negative ion extraction in a magnetized radio-frequency plasma source

    NASA Astrophysics Data System (ADS)

    Fubiani, G.; Garrigues, L.; Hagelaar, G.; Kohen, N.; Boeuf, J. P.

    2017-01-01

    Negative ion sources for fusion are high densities plasma sources in large discharge volumes. There are many challenges in the modeling of these sources, due to numerical constraints associated with the high plasma density, to the coupling between plasma and neutral transport and chemistry, the presence of a magnetic filter, and the extraction of negative ions. In this paper we present recent results concerning these different aspects. Emphasis is put on the modeling approach and on the methods and approximations. The models are not fully predictive and not complete as would be engineering codes but they are used to identify the basic principles and to better understand the physics of the negative ion sources.

  1. Photodissociation and charge transfer dynamics of negative ions studied with femtosecond photoelectron spectroscopy

    SciTech Connect

    Zanni, Martin Thomas

    1999-12-01

    This dissertation presents studies aimed at understanding the potential energy surfaces and dynamics of isolated negative ions, and the effects of solvent on each. Although negative ions play important roles in atmospheric and solution phase chemistry, to a large extent the ground and excited state potential energy surfaces of gas phase negative ions are poorly characterized, and solvent effects even less well understood. In an effort to fill this gap, the author's coworkers and the author have developed a new technique, anion femtosecond photoelectron spectroscopy, and applied it to gas phase photodissociation and charge transfer processes. Studies are presented that (1) characterize the ground and excited states of isolated and clustered anions, (2) monitor the photodissociation dynamics of isolated and clustered anions, and (3) explore the charge-transfer-to-solvent states of atomic iodide clustered with polar and non-polar solvents.

  2. Potential formation in a collisionless plasma produced in an open magnetic field in presence of volume negative ion source

    SciTech Connect

    Phukan, Ananya Goswami, K. S.; Bhuyan, P. J.

    2014-08-15

    The electric potential near a wall for a multi-species plasma with volume produced negative ions in presence of axially varying magnetic field is studied following an analytical-numerical approach. A constant negative ion source is assumed throughout the plasma volume, along with finite temperature positive ions and Boltzmann electrons. The particles are assumed to be guided by an open magnetic field that has its maximum at the centre, and field strength decreasing towards the walls. The one dimensional (1D) Poisson equation is derived using an analytical approach, and then solved numerically to study the potential profiles. Effect of (a) negative ion production rate, (b) magnetic field profile, and (c) negative ion temperature on the potential profile has been investigated. A potential peak appears near the wall when the negative ion temperature and density are sufficiently high. Also, the presence of negative ions further decreases the potential in the plasma region for a finite Debye Length (λ{sub D})

  3. Negative ions from alkali hydrides as a source for H(-) beams

    NASA Technical Reports Server (NTRS)

    Srivastava, S. K.

    1989-01-01

    The production of H(-) ions by heating LiH powder in a high-temperature crucible was investigated experimentally and theoretically. It is found that the efficiency of H(-) ion production by this method is high. However, the theory for the negative surface ionization indicates that such high efficiency is not possible at crucible temperatures of about 750 C. The need for a further study of LiH ionization is emphasized.

  4. The effects of negative air ions on various physiological functions during work in a hot environment

    NASA Astrophysics Data System (ADS)

    Inbar, O.; Rotstein, A.; Dlin, R.; Dotan, R.; Sulman, F. G.

    1982-06-01

    The effects of negative air-ions on human physical performance has been investigated. Twenty-one healthy males, 20 25 years old (X=23.6±2.6) were exposed to two 180-min rest and exercise sessions two weeks apart. The subjects were randomly assigned into either an experimental group (n=12) or to a control group (n=9). The experimental group performed the first session in neutral air conditions and the second one in air containing 1.36 to 1.90×105 negative air ions and 1.40 to 1.66×102 positive air ions/ml. The control group performed both sessions under neutral air conditions. All sessions were held at Ta=40±1‡C and 25±5% RH. Each session included one hour of resting under the respective ionization conditions, followed by 3 30-min cycle ergometer work bouts, separated by 7-min rest periods. The mechanical work-load during the bicycle exercise was 1.64±0.6 W/kg BW. The experimental group showed a significant reduction with negative air-ions in heart rate (HR), in rectal temperature, and in the rating of perceived exertion (RPE), all when compared with their own neutral session. The control group showed no significant changes between the first and the second exposure. Although not statistically significant, being exposed to negative air-ions seems also to reduce total sweat rate and minute ventilation (VE), and to increase O2 pulse. It is suggested that under the conditions of this study negative air ions can improve various cardiovascular and thermoregulatory functions as well as subjective feelings during physical effort. It is felt that such positive influences may be augmented by increasing the exposure time to negative ionized air and/or prolonging the stressful conditions.

  5. Swift Heavy Ion Irradiation Effects on NPN rf Power Transistors

    NASA Astrophysics Data System (ADS)

    Pushpa, N.; Prakash, A. P. Gnana; Gupta, S. K.; Revannasiddaiah, D.

    2011-07-01

    The dc characteristics of NPN rf power transistors were studied systematically before and after irradiation by 50 MeV Li3+ ions, 100 MeV F8+ ions and 140 MeV Si10+ ions in the dose range of 100 krad to 100 Mrad. The transistor parameters such as excess base current (ΔIB = IBpost-IBpre), dc current gain (hFE), and collector-saturation current (ICSat) were determined before and after irradiation. The base current (IB) was found to increase significantly after ion irradiation and this in turn decreases the hFE of the transistors. Further, the output characteristics of the irradiated devices exhibit the decrease in the collector current at the saturation region (ICSat) with increase of ion dose.

  6. Method and apparatus for providing negative ions of actinide-metal hexafluorides

    DOEpatents

    Compton, Robert N.; Reinhardt, Paul W.; Garrett, William R.

    1978-01-01

    This invention relates to a novel method and a novel generator, or source, for providing gaseous negative ions of selected metal hexafluorides. The method is summarized as follows: in an evacuated zone, reacting gaseous fluorine with an actinide-metal body selected from the group consisting of uranium, plutonium, neptunium, and americium to convert at least part of the metal to the hexafluoride state, thus producing gaseous negatively charged metal-hexafluoride ions in the evacuated zone, and applying an electric field to the zone to remove the ions therefrom. The ion source comprises a chamber defining a reaction zone; means for evacuating the zone; an actinide-metal body in the zone, the metal being uranium, plutonium, neptunium, or americium; means for contacting the body with gaseous fluorine to convert at least a part thereof to the hexafluoride state; and means for applying an electric field to the evacuated zone to extract gaseous, negatively charged metal-hexafluoride ions therefrom. The invention provides unique advantages over conventional surface-ionization techniques for producing such ions.

  7. Numerical simulations of the first operational conditions of the negative ion test facility SPIDER

    SciTech Connect

    Serianni, G. Agostinetti, P.; Antoni, V.; Baltador, C.; Chitarin, G.; Marconato, N.; Pasqualotto, R.; Sartori, E.; Toigo, V.; Veltri, P.; Cavenago, M.

    2016-02-15

    In view of the realization of the negative ion beam injectors for ITER, a test facility, named SPIDER, is under construction in Padova (Italy) to study and optimize production and extraction of negative ions. The present paper is devoted to the analysis of the expected first operations of SPIDER in terms of single-beamlet and multiple-beamlet simulations of the hydrogen beam optics in various operational conditions. The effectiveness of the methods adopted to compensate for the magnetic deflection of the particles is also assessed. Indications for a sequence of the experimental activities are obtained.

  8. Numerical simulations of the first operational conditions of the negative ion test facility SPIDER

    NASA Astrophysics Data System (ADS)

    Serianni, G.; Agostinetti, P.; Antoni, V.; Baltador, C.; Cavenago, M.; Chitarin, G.; Marconato, N.; Pasqualotto, R.; Sartori, E.; Toigo, V.; Veltri, P.

    2016-02-01

    In view of the realization of the negative ion beam injectors for ITER, a test facility, named SPIDER, is under construction in Padova (Italy) to study and optimize production and extraction of negative ions. The present paper is devoted to the analysis of the expected first operations of SPIDER in terms of single-beamlet and multiple-beamlet simulations of the hydrogen beam optics in various operational conditions. The effectiveness of the methods adopted to compensate for the magnetic deflection of the particles is also assessed. Indications for a sequence of the experimental activities are obtained.

  9. Charging-delay induced dust acoustic collisionless shock wave: Roles of negative ions

    SciTech Connect

    Ghosh, Samiran; Bharuthram, R.; Khan, Manoranjan; Gupta, M. R.

    2006-11-15

    The effects of charging-delay and negative ions on nonlinear dust acoustic waves are investigated. It has been found that the charging-delay induced anomalous dissipation causes generation of dust acoustic collisionless shock waves in an electronegative dusty plasma. The small but finite amplitude wave is governed by a Korteweg-de Vries Burger equation in which the Burger term arises due to the charging-delay. Numerical investigations reveal that the charging-delay induced dissipation and shock strength decreases (increases) with the increase of negative ion concentration (temperature)

  10. Characteristics of plasma grid bias in large-scaled negative ion source

    SciTech Connect

    Kisaki, M.; Tsumori, K.; Ikeda, K.; Nakano, H.; Osakabe, M.; Nagaoka, K.; Takeiri, Y.; Kaneko, O.

    2014-02-15

    The electron density was measured at various bias voltages to understand how the plasma grid bias affects the electron near the plasma grid in large-scaled negative ion sources. It was found that the response of the electron to the bias voltage changes depending on negative ion production processes. The electron density remarkably decreases with increasing the bias voltage in the pure-volume plasma. On the other hand, the electron density depends on the bias voltage weakly in the Cs-seeded plasma. In addition, it was observed that the response of the co-extracted electron current to the bias voltage has similar trend to that of the electron density.

  11. Complete positive ion, electron, and ram negative ion measurements near Comet Halley (COPERNIC) plasma experiment for the European Giotto Mission

    NASA Technical Reports Server (NTRS)

    Lin, Robert P.

    1988-01-01

    Participation of U.S. scientists on the COPERNIC (COmplete Positive ions, Electrons and Ram Negative Ion measurements near Comet Halley) plasma experiment on the Giotto mission is described. The experiment consisted of two detectors: the EESA (electron electrostatic analyzer) which provided three-dimensional measurements of the distribution of electrons from 10 eV to 30 keV, and the PICCA (positive ion cluster composition analyzer) which provided mass analysis of positively charged cold cometary ions from mass 10 to 210 amu. In addition, a small 3 deg wide sector of the EESA looking in the ram direction was devoted to the detection of negatively charged cold cometary ions. Both detectors operated perfectly up to near closest approach (approx. 600 km) to Halley, but impacts of dust particles and neutral gas on the spacecraft contaminated parts of the data during the last few minutes. Although no flight hardware was fabricated in the U.S., The U.S. made very significant contributions to the hardware design, ground support equipment (GSE) design and fabrication, and flight and data reduction software required for the experiment, and also participated fully in the data reduction and analysis, and theoretical modeling and interpretation. Cometary data analysis is presented.

  12. Dust charging processes with a Cairns-Tsallis distribution function with negative ions

    SciTech Connect

    Abid, A. A.; Khan, M. Z.; Yap, S. L.; Terças, H.; Mahmood, S.

    2016-01-15

    Dust grain charging processes are presented in a non-Maxwellian dusty plasma following the Cairns-Tsallis (q, α)–distribution, whose constituents are the electrons, as well as the positive/negative ions and negatively charged dust grains. For this purpose, we have solved the current balance equation for a negatively charged dust grain to achieve an equilibrium state value (viz., q{sub d} = constant) in the presence of Cairns-Tsallis (q, α)–distribution. In fact, the current balance equation becomes modified due to the Boltzmannian/streaming distributed negative ions. It is numerically found that the relevant plasma parameters, such as the spectral indexes q and α, the positive ion-to-electron temperature ratio, and the negative ion streaming speed (U{sub 0}) significantly affect the dust grain surface potential. It is also shown that in the limit q → 1 the Cairns-Tsallis reduces to the Cairns distribution; for α = 0 the Cairns-Tsallis distribution reduces to pure Tsallis distribution and the latter reduces to Maxwellian distribution for q → 1 and α = 0.

  13. The High Power Electric Propulsion (HiPEP) Ion Thruster

    NASA Technical Reports Server (NTRS)

    Foster, John E.; Haag, Tom; Patterson, Michael; Williams, George J., Jr.; Sovey, James S.; Carpenter, Christian; Kamhawi, Hani; Malone, Shane; Elliot, Fred

    2004-01-01

    Practical implementation of the proposed Jupiter Icy Moon Orbiter (JIMO) mission, which would require a total delta V of approximately 38 km/s, will require the development of a high power, high specific impulse propulsion system. Initial analyses show that high power gridded ion thrusters could satisfy JIMO mission requirements. A NASA GRC-led team is developing a large area, high specific impulse, nominally 25 kW ion thruster to satisfy both the performance and the lifetime requirements for this proposed mission. The design philosophy and development status as well as a thruster performance assessment are presented.

  14. Electronic stopping power for heavy ions in hot targets

    NASA Astrophysics Data System (ADS)

    Wang, You-Nian; Ma, Teng-Cai; Gong, Ye

    1993-03-01

    An investigation on the electronic stopping power and the effective charge for a heavy ion in a hot target is made using linear-response dielectric theory. The charge distribution of the electrons bound to a projectile is determined by the Brandt-Kitagawa (BK) model [Phys. Rev. B 25, 3631 (1982)]. Some analytical expressions of the electronic stopping power and the effective charge are obtained in the limits of the low and high velocities, respectively. The theoretical results are compared with the experimental data for high-velocity ions.

  15. Formation of negative ions by electron impact on SiF4 and CF4

    NASA Technical Reports Server (NTRS)

    Iga, I.; Rao, M. V. V. S.; Srivastava, S. K.; Nogueira, J. C.

    1992-01-01

    First measurements of cross sections for the formation of negative ions by electron attachment to SiF4 and CF4 are reported for an electron impact energy range of 0 to 50 eV. The energies at which the various ions appear and the positions at which the ionization efficiency curves peak have been obtained and compared with previous measurements. Thermochemical data have been used to predict and identify the various channels of dissociation. Cross sections for the production of ion pairs through the process of polar dissociation have also been measured.

  16. Effects due to adsorbed atoms upon angular and energy distributions of surface produced negative hydrogen ions

    NASA Astrophysics Data System (ADS)

    Wada, M.; Bacal, M.; Kasuya, T.; Kato, S.; Kenmotsu, T.; Sasao, M.

    2013-02-01

    Exposure to Cs added hydrogen discharge makes surface of plasma grid of a negative hydrogen ion source covered with Cs and hydrogen. A Monte-Carlo particle simulation code ACAT was run to evaluate the effects due to adsorbed Cs and H atoms upon the angular and energy distributions of H atoms leaving the surface. Accumulation of H atoms on the surface reduces particle reflection coefficients and the mean energy of backscattered H atoms. Angular distributions of H atoms reflected from the hydrogen covered surface tend to be under-cosine at lower energies. Desorption of adsorbed H atoms is more efficient for hydrogen positive ions than for Cs positive ions at lower incident energy. At higher energy more than 100 eV, Cs ions desorb adsorbed H atoms more efficiently than hydrogen ions.

  17. The production and destruction of negative ions. Progress report, September 1, 1992--August 31, 1993

    SciTech Connect

    Pegg, D.J.

    1993-04-01

    Single photon absorption-single electron detachment from few-electron atomic negative ions was studied. A crossed beam apparatus is being used to perform energy- and angle-resolved photoelectron spectroscopic measurements following photodetachment. Forward-directed electrons were collected and energy analyzed. The kinetic energies and yields of the photoelectrons were obtained by fitting the spectral peaks to Gaussian functions. Electron affinities, asymmetry parameters and cross sections are determined from these measurements. A ratio method in which the cross section for the ion of interest is measured relative to that of a reference ion was used. The study of the photodetachment of Li{sup {minus}} was completed, and attention has turned to the photodetachment of the stable ion B{sup {minus}} and the metastable ion Be{sup {minus}}.

  18. Plasma Outages in Pulsed, High-Power RF Hydrogen Ion Sources

    NASA Astrophysics Data System (ADS)

    Stockli, Martin; Han, Baoxi; Murray, Syd; Pennisi, Terry; Piller, Chip; Santana, Manuel; Welton, Robert

    2011-04-01

    Pulsed, high-power RF ion sources are needed to produce copious amounts of negative H-ions for high-power accelerators with charge-changing injection schemes. When increasing the RF power, the plasma inductance changes the RF resonance, which drifts away from the low-power resonance. When the RF circuit is tuned to maximize the (pulsed) plasma power, the (off-resonance) power at the beginning of the pulse is reduced. If the induced electric fields fall below the breakdown strength of the hydrogen gas, the plasma fails to develop. This can be avoided with a compromise tune and/or by increasing the inductance of the resonant circuit. However, the breakdown strength of the hydrogen gas increases with time due to the gradual decrease of the electron-rich plasma impurities, which causes plasma outages after weeks of reliable operation. In this paper we discuss the success of different mitigations that were tested and implemented to overcome this fundamental problem of pulsed, high-power RF hydrogen ion sources.

  19. Effects of negative air ions on activity of neural substrates involved in autonomic regulation in rats

    NASA Astrophysics Data System (ADS)

    Suzuki, Satoko; Yanagita, Shinya; Amemiya, Seiichiro; Kato, Yumi; Kubota, Natsuko; Ryushi, Tomoo; Kita, Ichiro

    2008-07-01

    The neural mechanism by which negative air ions (NAI) mediate the regulation of autonomic nervous system activity is still unknown. We examined the effects of NAI on physiological responses, such as blood pressure (BP), heart rate (HR), and heart rate variability (HRV) as well as neuronal activity, in the paraventricular nucleus of the hypothalamus (PVN), locus coeruleus (LC), nucleus ambiguus (NA), and nucleus of the solitary tract (NTS) with c-Fos immunohistochemistry in anesthetized, spontaneously breathing rats. In addition, we performed cervical vagotomy to reveal the afferent pathway involved in mediating the effects of NAI on autonomic regulation. NAI significantly decreased BP and HR, and increased HF power of the HRV spectrum. Significant decreases in c-Fos positive nuclei in the PVN and LC, and enhancement of c-Fos expression in the NA and NTS were induced by NAI. After vagotomy, these physiological and neuronal responses to NAI were not observed. These findings suggest that NAI can modulate autonomic regulation through inhibition of neuronal activity in PVN and LC as well as activation of NA neurons, and that these effects of NAI might be mediated via the vagus nerves.

  20. High-Power, High-Thrust Ion Thruster (HPHTion)

    NASA Technical Reports Server (NTRS)

    Peterson, Peter Y.

    2015-01-01

    Advances in high-power photovoltaic technology have enabled the possibility of reasonably sized, high-specific power solar arrays. At high specific powers, power levels ranging from 50 to several hundred kilowatts are feasible. Ion thrusters offer long life and overall high efficiency (typically greater than 70 percent efficiency). In Phase I, the team at ElectroDynamic Applications, Inc., built a 25-kW, 50-cm ion thruster discharge chamber and fabricated a laboratory model. This was in response to the need for a single, high-powered engine to fill the gulf between the 7-kW NASA's Evolutionary Xenon Thruster (NEXT) system and a notional 25-kW engine. The Phase II project matured the laboratory model into a protoengineering model ion thruster. This involved the evolution of the discharge chamber to a high-performance thruster by performance testing and characterization via simulated and full beam extraction testing. Through such testing, the team optimized the design and built a protoengineering model thruster. Coupled with gridded ion thruster technology, this technology can enable a wide range of missions, including ambitious near-Earth NASA missions, Department of Defense missions, and commercial satellite activities.

  1. Electrostatic energy analyzer measurements of low energy zirconium beam parameters in a plasma sputter-type negative ion source

    SciTech Connect

    Malapit, Giovanni M.; Mahinay, Christian Lorenz S.; Poral, Matthew D.; Ramos, Henry J.

    2012-02-15

    A plasma sputter-type negative ion source is utilized to produce and detect negative Zr ions with energies between 150 and 450 eV via a retarding potential-type electrostatic energy analyzer. Traditional and modified semi-cylindrical Faraday cups (FC) inside the analyzer are employed to sample negative Zr ions and measure corresponding ion currents. The traditional FC registered indistinct ion current readings which are attributed to backscattering of ions and secondary electron emissions. The modified Faraday cup with biased repeller guard ring, cut out these signal distortions leaving only ringings as issues which are theoretically compensated by fitting a sigmoidal function into the data. The mean energy and energy spread are calculated using the ion current versus retarding potential data while the beam width values are determined from the data of the transverse measurement of ion current. The most energetic negative Zr ions yield tighter energy spread at 4.11 eV compared to the least energetic negative Zr ions at 4.79 eV. The smallest calculated beam width is 1.04 cm for the negative Zr ions with the highest mean energy indicating a more focused beam in contrast to the less energetic negative Zr ions due to space charge forces.

  2. Electrostatic energy analyzer measurements of low energy zirconium beam parameters in a plasma sputter-type negative ion source.

    PubMed

    Malapit, Giovanni M; Mahinay, Christian Lorenz S; Poral, Matthew D; Ramos, Henry J

    2012-02-01

    A plasma sputter-type negative ion source is utilized to produce and detect negative Zr ions with energies between 150 and 450 eV via a retarding potential-type electrostatic energy analyzer. Traditional and modified semi-cylindrical Faraday cups (FC) inside the analyzer are employed to sample negative Zr ions and measure corresponding ion currents. The traditional FC registered indistinct ion current readings which are attributed to backscattering of ions and secondary electron emissions. The modified Faraday cup with biased repeller guard ring, cut out these signal distortions leaving only ringings as issues which are theoretically compensated by fitting a sigmoidal function into the data. The mean energy and energy spread are calculated using the ion current versus retarding potential data while the beam width values are determined from the data of the transverse measurement of ion current. The most energetic negative Zr ions yield tighter energy spread at 4.11 eV compared to the least energetic negative Zr ions at 4.79 eV. The smallest calculated beam width is 1.04 cm for the negative Zr ions with the highest mean energy indicating a more focused beam in contrast to the less energetic negative Zr ions due to space charge forces.

  3. Electric prototype power processor for a 30cm ion thruster

    NASA Technical Reports Server (NTRS)

    Biess, J. J.; Inouye, L. Y.; Schoenfeld, A. D.

    1977-01-01

    An electrical prototype power processor unit was designed, fabricated and tested with a 30 cm mercury ion engine for primary space propulsion. The power processor unit used the thyristor series resonant inverter as the basic power stage for the high power beam and discharge supplies. A transistorized series resonant inverter processed the remaining power for the low power outputs. The power processor included a digital interface unit to process all input commands and internal telemetry signals so that electric propulsion systems could be operated with a central computer system. The electrical prototype unit included design improvement in the power components such as thyristors, transistors, filters and resonant capacitors, and power transformers and inductors in order to reduce component weight, to minimize losses, and to control the component temperature rise. A design analysis for the electrical prototype is also presented on the component weight, losses, part count and reliability estimate. The electrical prototype was tested in a thermal vacuum environment. Integration tests were performed with a 30 cm ion engine and demonstrated operational compatibility. Electromagnetic interference data was also recorded on the design to provide information for spacecraft integration.

  4. Pseudocapacitance of MXene nanosheets for high-power sodium-ion hybrid capacitors

    PubMed Central

    Wang, Xianfen; Kajiyama, Satoshi; Iinuma, Hiroki; Hosono, Eiji; Oro, Shinji; Moriguchi, Isamu; Okubo, Masashi; Yamada, Atsuo

    2015-01-01

    High-power Na-ion batteries have tremendous potential in various large-scale applications. However, conventional charge storage through ion intercalation or double-layer formation cannot satisfy the requirements of such applications owing to the slow kinetics of ion intercalation and the small capacitance of the double layer. The present work demonstrates that the pseudocapacitance of the nanosheet compound MXene Ti2C achieves a higher specific capacity relative to double-layer capacitor electrodes and a higher rate capability relative to ion intercalation electrodes. By utilizing the pseudocapacitance as a negative electrode, the prototype Na-ion full cell consisting of an alluaudite Na2Fe2(SO4)3 positive electrode and an MXene Ti2C negative electrode operates at a relatively high voltage of 2.4 V and delivers 90 and 40 mAh g−1 at 1.0 and 5.0 A g−1 (based on the weight of the negative electrode), respectively, which are not attainable by conventional electrochemical energy storage systems. PMID:25832913

  5. Development of the negative ion beams relevant to ITER and JT-60SA at Japan Atomic Energy Agency

    SciTech Connect

    Hanada, M. Kojima, A.; Tobari, H.; Nishikiori, R.; Hiratsuka, J.; Kashiwagi, M.; Umeda, N.; Yoshida, M.; Ichikawa, M.; Watanabe, K.; Yamano, Y.; Grisham, L. R.

    2016-02-15

    In order to realize negative ion sources and accelerators to be applicable to International Thermonuclear Experimental Reactor and JT-60 Super Advanced, a large cesium (Cs)-seeded negative ion source and a multi-aperture and multi-stage electric acceleration have been developed at Japan Atomic Energy Agency (JAEA). Long pulse production and acceleration of the negative ion beams have been independently carried out. The long pulse production of the high current beams has achieved 100 s at the beam current of 15 A by modifying the JT-60 negative ion source. The pulse duration time is increased three times longer than that before the modification. As for the acceleration, a pulse duration time has been also extended two orders of magnitudes from 0.4 s to 60 s. The developments of the negative ion source and acceleration at JAEA are well in progress towards the realization of the negative ion sources and accelerators for fusion applications.

  6. Development of the negative ion beams relevant to ITER and JT-60SA at Japan Atomic Energy Agency.

    PubMed

    Hanada, M; Kojima, A; Tobari, H; Nishikiori, R; Hiratsuka, J; Kashiwagi, M; Umeda, N; Yoshida, M; Ichikawa, M; Watanabe, K; Yamano, Y; Grisham, L R

    2016-02-01

    In order to realize negative ion sources and accelerators to be applicable to International Thermonuclear Experimental Reactor and JT-60 Super Advanced, a large cesium (Cs)-seeded negative ion source and a multi-aperture and multi-stage electric acceleration have been developed at Japan Atomic Energy Agency (JAEA). Long pulse production and acceleration of the negative ion beams have been independently carried out. The long pulse production of the high current beams has achieved 100 s at the beam current of 15 A by modifying the JT-60 negative ion source. The pulse duration time is increased three times longer than that before the modification. As for the acceleration, a pulse duration time has been also extended two orders of magnitudes from 0.4 s to 60 s. The developments of the negative ion source and acceleration at JAEA are well in progress towards the realization of the negative ion sources and accelerators for fusion applications.

  7. Development Status of the NSTAR Ion Propulsion System Power Processor

    NASA Technical Reports Server (NTRS)

    Hamley, John A.; Pinero, Luis R.; Rawlin, Vincent K.; Miller, John R.; Cartier, Kevin C.; Bowers, Glen E.

    1995-01-01

    A 0.5-2.3 kW xenon ion propulsion system is presently being developed under the NASA Solar Electric Propulsion Technology Application Readiness (NSTAR) program. This propulsion system includes a 30 cm diameter xenon ion thruster, a Digital Control Interface Unit, a xenon feed system, and a power processing unit (PPU). The PPU consists of the power supply assemblies which operate the thruster neutralizer, main discharge chamber, and ion optics. Also included are recycle logic and a digital microcontroller. The neutralizer and discharge power supplies employ a dual use configuration which combines the functions of two power supplies into one, significantly simplifying the PPU. Further simplification was realized by implementing a single thruster control loop which regulates the beam current via the discharge current. Continuous throttling is possible over a 0.5-2.3 kW output power range. All three power supplies have been fabricated and tested with resistive loads, and have been combined into a single breadboard unit with the recycle logic and microcontroller. All line and load regulation test results show the power supplies to be within the NSTAR flight PPU specified power output of 1.98 kW. The overall efficiency of the PPU, calculated as the combined efficiencies of the power supplies and controller, at 2.3 kW delivered to resistive loads was 0.90. The component was 6.16 kg. Integration testing of the neutralizer and discharge power supplies with a functional model thruster revealed no issues with discharge ignition or steady state operation.

  8. Landau damping effects on dust-acoustic solitary waves in a dusty negative-ion plasma

    SciTech Connect

    Barman, Arnab; Misra, A. P. E-mail: apmisra@gmail.com

    2014-07-15

    The nonlinear theory of dust-acoustic waves (DAWs) with Landau damping is studied in an unmagnetized dusty negative-ion plasma in the extreme conditions when the free electrons are absent. The cold massive charged dusts are described by fluid equations, whereas the two-species of ions (positive and negative) are described by the kinetic Vlasov equations. A Korteweg-de Vries (KdV) equation with Landau damping, governing the dynamics of weakly nonlinear and weakly dispersive DAWs, is derived following Ott and Sudan [Phys. Fluids 12, 2388 (1969)]. It is shown that for some typical laboratory and space plasmas, the Landau damping (and the nonlinear) effects are more pronounced than the finite Debye length (dispersive) effects for which the KdV soliton theory is not applicable to DAWs in dusty pair-ion plasmas. The properties of the linear phase velocity, solitary wave amplitudes (in presence and absence of the Landau damping) as well as the Landau damping rate are studied with the effects of the positive ion to dust density ratio (μ{sub pd}) as well as the ratios of positive to negative ion temperatures (σ) and masses (m)

  9. Design of the new extraction grid for the NIO1 negative ion source

    NASA Astrophysics Data System (ADS)

    Veltri, P.; Cavenago, M.; Baltador, C.

    2015-04-01

    NIO1 is a compact source of negative ions jointly developed by RFX and INFN, to study the physics of production and acceleration of H- beams. Negative ions, up to 120 mA of current, are extracted from a radiofrequency driven plasma, by means of a gridded electrode (plasma grid, PG) featuring 9 apertures arranged in a 3x3 square lattice. The same aperture pattern is replicated in the following electrodes, allowing ion acceleration up to 60 keV. All electrodes are realized in copper, by electro-deposition technique, leaving empty slots in the metal to place magnets and to flow water for the grid cooling. The first set of electrodes was completed, installed in the source and tested. At the same time, an upgrade of the extraction system was carried out, in order to optimize the beam optics and to explore alternative electrostatic configurations. In particular, the accelerator will be modified by completely replacing the EG grid, exploiting the modularity of NIO1. The new electrode will feature other slots in between apertures, to place additional magnets. This allows testing different magnetic configurations, to optimize electron filtering and residual ion deflection. The present paper describes the theoretical activities driving the design of these new extractors, carried out with most updated numerical codes, and exploiting the synergy with the refined modeling of the 40 A ITER negative ion sources, under development at Consorzio RFX. Beam simulations are performed both with tracing codes (SLACCAD and OPERA) and with particle in cell codes (ACCPIC)

  10. Flashover lithium ion source development for large pulsed power accelerators

    SciTech Connect

    Bieg, K.W.; Burns, E.J.T.; Gerber, R.A.; Olsen, J.N.; Lamppa, K.P.

    1985-01-01

    PBFA II, a light-ion pulsed power accelerator intended for inertial confinement fusion (ICF) applications, is currently under construction at Sandia National Laboratories. The accelerator will deliver a 30 MV, 5 MA lithium beam from an Applied-B diode to drive an ICF target. The ion source for this diode will require a thin (approx.1 mm), dense (10 W cm S) anode plasma layer of singly-ionized lithium over an anode area of 10T cmS. One type of source being investigated is the flashover ion source, which generates the anode plasma via vacuum flashover of a lithium-bearing dielectric material. Experiments with a LiF flashover source on the 0.03 TW Nereus accelerator have shown that contaminant ions account for as much as 70% of the extracted ion beam current. To overcome this, we have explored in-diode cleaning of the externally-prepared anode surface by glow discharge cleaning and vacuum baking as well as in-diode preparation of the anode surface by vacuum evaporation of the lithium dielectric. Lithium-bearing dielectric materials which have been investigated include LiF, LiI, LiNO3, and Li3N. These techniques have resulted in a two- to three-fold improvement in the extracted lithium ion purity. As a result, a glow-discharge cleaned LiF flashover source will be used for initial pulsed-power testing on PBFA II.

  11. Cross-sections for the formation of negative ions by electron impact on silane

    NASA Technical Reports Server (NTRS)

    Srivastava, S. K.; Krishnakumar, E.; De A. E Souza, A. C.

    1991-01-01

    Cross-sections and appearance potentials for the production of various negative ion species by electron impact on SiH4 have been measured. They are compared with two previous measurements which widely differ with each other. Hess' law has been applied to predict the various possible channels of dissociation.

  12. Observation of electron spin resonance of negative ions in liquid helium

    NASA Technical Reports Server (NTRS)

    Reichert, J. F.; Dahm, A. J.

    1973-01-01

    Electron spin resonance signals of negative ions in liquid helium were observed. The line width and g-value were measured. Electrons injected into helium by field emission from ferromagnetic tips are shown to be polarized. A new technique for the measurement of electron spin polarization is presented.

  13. Negative Ion Drift Velocity and Longitudinal Diffusion in Mixtures of Carbon Disulfide and Methane

    NASA Technical Reports Server (NTRS)

    Dion, Michael P.; Son, S.; Hunter, S. D.; deNolfo, G. A.

    2011-01-01

    Negative ion drift velocity and longitudinal diffusion has been measured for gas mixtures of carbon disulfide (CS2) and methane (CH4)' Measurements were made as a function of total pressure, CS2 partial pressure and electric field. Constant mobility and thermal-limit longitudinal diffusion is observed for all gas mixtures tested. Gas gain for some of the mixtures is also included.

  14. ELECTRON AFFINITIES OF POLYNUCLEAR AROMATIC HYDROCARBONS AND NEGATIVE ION CHEMICAL IONIZATION SENSITIVITIES

    EPA Science Inventory

    Negative-ion chemical-ionization mass spectrometry (NICI MS) has the potential to be a very useful technique in identifying various polycyclic aromatic hydrocarbons (PAHs) in soil and sediment samples. Some PAHs give much stronger signals under NICI MS conditions than others. On ...

  15. New source of MeV negative ion and neutral atom beams

    SciTech Connect

    Ter-Avetisyan, S.; Braenzel, J.; Schnürer, M.; Prasad, R.; Borghesi, M.; Jequier, S.; Tikhonchuk, V.

    2016-02-15

    The scenario of “electron-capture and -loss” was recently proposed for the formation of negative ion and neutral atom beams with MeV kinetic energies. However, it does not explain why the formation of negative ions in a liquid spray is much more efficient than with an isolated atom. The role of atomic excited states in the charge-exchange processes is considered, and it is shown that it cannot account for the observed phenomena. The processes are more complex than the single electron-capture and -loss approach. It is suggested that the shell effects in the electronic structure of the projectile ion and/or target atoms may influence the capture/loss probabilities.

  16. Cesium dynamics in long pulse operation of negative hydrogen ion sources for fusion.

    PubMed

    Fantz, U; Wimmer, C

    2012-02-01

    Large scale negative hydrogen ion sources operating stable for 1 h (cw mode) are required for the neutral beam heating system of the fusion experiment ITER. The formation of negative hydrogen ions relies on the surface effect for which cesium is evaporated into the source. In order to monitor the cesium dynamics the laser absorption spectroscopy technique is applied to the long pulse test facility MANITU. In the vacuum phase, without plasma operation the evaporation of cesium and the built-up of the cesium in the source are measured. Typical neutral cesium densities are 10(15) m(-3). During plasma operation and after the plasma phase a high cesium dynamics is observed, showing also depletion of cesium during long pulses with low cesium amount. The co-extracted electron current decreases with the cesium amount to a certain level whereas the ion current indicates an optimum density range.

  17. The photodetachment cross-section and threshold energy of negative ions in carbon dioxide

    NASA Technical Reports Server (NTRS)

    Helmy, E. M.; Woo, S. B.

    1974-01-01

    Threshold energy and sunlight photodetachment measurements on negative carbon dioxide ions, using a 2.5 kw light pressure xenon lamp, show that: (1) Electron affinity of CO3(+) is larger than 2.7 e.V. and that an isomeric form of CO3(+) is likely an error; (2) The photodetachment cross section of CO3(-) will roughly be like a step function across the range of 4250 to 2500A, having its threshold energy at 4250A; (3) Sunlight photodetachment rate for CO3(-) is probably much smaller than elsewhere reported; and (4) The probability of having photodetached electrons re-attach to form negative ions is less than 1%. Mass identifying drift tube tests confirm that the slower ion is CO3(-), formed through the O(-) + 2CO2 yields CO3(-) + CO2 reaction.

  18. Cesium dynamics in long pulse operation of negative hydrogen ion sources for fusion

    SciTech Connect

    Fantz, U.; Wimmer, C.

    2012-02-15

    Large scale negative hydrogen ion sources operating stable for 1 h (cw mode) are required for the neutral beam heating system of the fusion experiment ITER. The formation of negative hydrogen ions relies on the surface effect for which cesium is evaporated into the source. In order to monitor the cesium dynamics the laser absorption spectroscopy technique is applied to the long pulse test facility MANITU. In the vacuum phase, without plasma operation the evaporation of cesium and the built-up of the cesium in the source are measured. Typical neutral cesium densities are 10{sup 15} m{sup -3}. During plasma operation and after the plasma phase a high cesium dynamics is observed, showing also depletion of cesium during long pulses with low cesium amount. The co-extracted electron current decreases with the cesium amount to a certain level whereas the ion current indicates an optimum density range.

  19. Numerical analysis of electronegative plasma in the extraction region of negative hydrogen ion sources

    SciTech Connect

    Kuppel, S.; Matsushita, D.; Hatayama, A.; Bacal, M.

    2011-01-01

    This numerical study focuses on the physical mechanisms involved in the extraction of volume-produced H{sup -} ions from a steady state laboratory negative hydrogen ion source with one opening in the plasma electrode (PE) on which a dc-bias voltage is applied. A weak magnetic field is applied in the source plasma transversely to the extracted beam. The goal is to highlight the combined effects of the weak magnetic field and the PE bias voltage (upon the extraction process of H{sup -} ions and electrons). To do so, we focus on the behavior of electrons and volume-produced negative ions within a two-dimensional model using the particle-in-cell method. No collision processes are taken into account, except for electron diffusion across the magnetic field using a simple random-walk model at each time step of the simulation. The results show first that applying the magnetic field (without PE bias) enhances H{sup -} ion extraction, while it drastically decreases the extracted electron current. Secondly, the extracted H{sup -} ion current has a maximum when the PE bias is equal to the plasma potential, while the extracted electron current is significantly reduced by applying the PE bias. The underlying mechanism leading to the above results is the gradual opening by the PE bias of the equipotential lines towards the parts of the extraction region facing the PE. The shape of these lines is due originally to the electron trapping by the magnetic field.

  20. [Negative air ions generated by plants upon pulsed electric field stimulation applied to soil].

    PubMed

    Wu, Ren-ye; Deng, Chuan-yuan; Yang, Zhi-jian; Weng, Hai-yong; Zhu, Tie-jun-rong; Zheng, Jin-gui

    2015-02-01

    This paper investigated the capacity of plants (Schlumbergera truncata, Aloe vera var. chinensis, Chlorophytum comosum, Schlumbergera bridgesii, Gymnocalycium mihanovichii var. friedrichii, Aspidistra elatior, Cymbidium kanran, Echinocactus grusonii, Agave americana var. marginata, Asparagus setaceus) to generate negative air ions (NAI) under pulsed electric field stimulation. The results showed that single plant generated low amounts of NAI in natural condition. The capacity of C. comosum and G. mihanovichii var. friedrichii generated most NAI among the above ten species, with a daily average of 43 ion · cm(-3). The least one was A. americana var. marginata with the value of 19 ion · cm(-3). When proper pulsed electric field stimulation was applied to soil, the NAI of ten plant species were greatly improved. The effect of pulsed electric field u3 (average voltage over the pulse period was 2.0 x 10(4) V, pulse frequency was 1 Hz, and pulse duration was 50 ms) was the greatest. The mean NAI concentration of C. kanran was the highest 1454967 ion · cm(-3), which was 48498.9 times as much as that in natural condition. The lowest one was S. truncata with the value of 34567 ion · cm(-3), which was 843.1 times as much as that in natural condition. The capacity of the same plants to generate negative air ion varied extremely under different intensity pulsed electric fields.

  1. Generalization of the Child-Langmuir law to the alternate extraction of positive and negative ions

    NASA Astrophysics Data System (ADS)

    Lafleur, T.; Aanesland, A.

    2014-12-01

    Using a combined analytical and simulation approach, we investigate positive and negative ion extraction between two electrodes from an ion-ion plasma source. With a square voltage waveform applied to the electrodes, we obtain approximate analytical solutions for the time-averaged extracted current densities, which are given simply by: Jp a c = [ α - f L √{ /M p q p V 0 } ] Jp d c , and Jn a c = [ ( 1 - α ) - f L √{ /M n q n V 0 } ] Jn d c , where Jac is the time-averaged current density, α is the square waveform duty cycle, f is the frequency, L is the electrode gap length, M is the ion mass, q is the ion charge, V0 is the applied voltage amplitude, Jdc is the dc extracted current density, and the subscripts p and n refer to positive and negative ions, respectively. In particular, if Jdc is the dc space-charge limited current density, then these equations describe the square waveform generalization of the Child-Langmuir law.

  2. Generalization of the Child-Langmuir law to the alternate extraction of positive and negative ions

    SciTech Connect

    Lafleur, T.; Aanesland, A.

    2014-12-15

    Using a combined analytical and simulation approach, we investigate positive and negative ion extraction between two electrodes from an ion-ion plasma source. With a square voltage waveform applied to the electrodes, we obtain approximate analytical solutions for the time-averaged extracted current densities, which are given simply by: J{sub p}{sup ac}=[α−fL√((M{sub p})/(q{sub p}V{sub 0}) )]J{sub p}{sup dc}, and J{sub n}{sup ac}=[(1−α)−fL√((M{sub n})/(q{sub n}V{sub 0}) )]J{sub n}{sup dc}, where J{sup ac} is the time-averaged current density, α is the square waveform duty cycle, f is the frequency, L is the electrode gap length, M is the ion mass, q is the ion charge, V{sub 0} is the applied voltage amplitude, J{sup dc} is the dc extracted current density, and the subscripts p and n refer to positive and negative ions, respectively. In particular, if J{sup dc} is the dc space-charge limited current density, then these equations describe the square waveform generalization of the Child-Langmuir law.

  3. Negative ions: The overlooked species in thin film growth by pulsed laser deposition

    SciTech Connect

    Esposito, M.; Bator, M.; Lippert, T.; Schneider, C. W.; Wokaun, A.; Doebeli, M.

    2011-11-07

    Plasma plume species from a ceramic La{sub 0.4}Ca{sub 0.6}MnO{sub 3} target were studied by plasma mass spectrometry as a function of laser fluence, background gas, and deposition pressure to understand the interplay between plasma composition and oxide thin film growth by pulsed laser deposition. The plume composition reveals a significant contribution of up to 24% of negative ions, most notably using a N{sub 2}O background. The significance of negative ions for thin film growth is shown for La{sub 0.4}Ca{sub 0.6}MnO{sub 3} films grown in different background conditions where the best structural properties coincide with the largest amount of negative plasma species.

  4. Enhanced surface production in H- ion sources by introducing a negatively biased secondary electrodea)

    NASA Astrophysics Data System (ADS)

    An, YoungHwa; Jung, BongKi; Hwang, Y. S.

    2010-02-01

    A transformer coupled plasma negative hydrogen ion source with an external rf antenna has been developed at SNU, which is capable of continuous operation with long lifetime. A positively biased plasma electrode (PE) has been successfully used for the optimization of H- extraction. With molybdenum-coated stainless steel PE, the enhancement of H- production at the electrode surface was observed at the bias voltage lower than the plasma potential. However, the low bias voltage is unfavorable to H- beam extraction since the negative ions are repelled. A second electrode is inserted in front of the PE to enhance H- production at the electrode surface without impeding beam extraction. By biasing the secondary electrode (SE) more negatively, H- production is clearly enhanced although the SE itself reduces H- beam currents because of suppressed electron transport in front of the PE. In this configuration enhancement of surface productions is most pronounced in tantalum electrode among various electrode materials.

  5. Simplification of power electronics for ion thruster neutralizers

    NASA Technical Reports Server (NTRS)

    Gruber, R. P.

    1982-01-01

    A need exists for less complex and lower cost ion thruster systems. Design approaches and the demonstration of neutralizer power electronics for relaxed neutralizer keeper, tip heater, and vaporizer requirements are discussed. The neutralizer circuitry is operated from a 200 to 400 V bus and demonstrates an order of magnitude reduction in parts count. Furthermore, a new technique is described for regulating tip heater power and automatically switching over to provide keeper power with only four additional components. A new design to control the flow rate of the neutralizer with one integrated circuit is also presented.

  6. High Power Accelerator and Magnetically Insulated Ion Diode for Ion Ring Studies.

    NASA Astrophysics Data System (ADS)

    Jones, Stephen Edward

    Ion ring generation for Cornell University's Megavolt Ion Coil Experiment (MICE) requires a suitable pulsed power accelerator to drive a high-power magnetically insulated ion diode. The diode then emits an intense ion-beam which forms an ion ring by using a cusped magnetic field. The goal of this thesis is to provide the necessary beam to form the ion-ring, and the present work consists of two parts: (1) the design, construction, testing, and operation of the pulsed power accelerator; and (2) the design, construction, testing, operation, and physics studies of a magnetically insulated diode for ion ring generation. For the required pulsed-power driver, we use a modified 2-MV, 100 kJ Marx generator, connected to a new 2-Omega-200-nsec pulse-forming line. For the diode, we use a novel applied-B, extraction diode with anode-side as well as cathode-side coils. This coil arrangement forms an easily variable pseudo-separatrix within the gap allowing flexibility for diode studies and optimization. Diode investigations reveal the efficacy of such a pseudo-separatrix located in the gap near the flashboard, in terms of anode turn-on and ion beam current. Further results (1) support the hypothesis that leakage electrons to the flashboard are instrumental for anode turn-on, (2) indicate that the gap electron-population has two different electron sources, and (3) discuss the possible long development time scale for diode development. Extensive computer simulations have also been conducted on the accelerator and diode, and results are compared with experiment. A driving constraint throughout this work is affordability on a university budget; also, unfortunately, some of the experiments had to be cut short due to funding cuts.

  7. Effect of high energy electrons on H{sup −} production and destruction in a high current DC negative ion source for cyclotron

    SciTech Connect

    Onai, M. Fujita, S.; Hatayama, A.; Etoh, H.; Aoki, Y.; Shibata, T.; Mattei, S.; Lettry, J.

    2016-02-15

    Recently, a filament driven multi-cusp negative ion source has been developed for proton cyclotrons in medical applications. In this study, numerical modeling of the filament arc-discharge source plasma has been done with kinetic modeling of electrons in the ion source plasmas by the multi-cusp arc-discharge code and zero dimensional rate equations for hydrogen molecules and negative ions. In this paper, main focus is placed on the effects of the arc-discharge power on the electron energy distribution function and the resultant H{sup −} production. The modelling results reasonably explains the dependence of the H{sup −} extraction current on the arc-discharge power in the experiments.

  8. Preparation of graphene on Cu foils by ion implantation with negative carbon clusters

    NASA Astrophysics Data System (ADS)

    Li, Hui; Shang, Yan-Xia; Zhang, Zao-Di; Wang, Ze-Song; Zhang, Rui; Fu, De-Jun

    2015-01-01

    We report on few-layer graphene synthesized on Cu foils by ion implantation using negative carbon cluster ions, followed by annealing at 950 °C in vacuum. Raman spectroscopy reveals IG/I2D values varying from 1.55 to 2.38 depending on energy and dose of the cluster ions, indicating formation of multilayer graphene. The measurements show that the samples with more graphene layers have fewer defects. This is interpreted by graphene growth seeded by the first layers formed via outward diffusion of C from the Cu foil, though nonlinear damage and smoothing effects also play a role. Cluster ion implantation overcomes the solubility limit of carbon in Cu, providing a technique for multilayer graphene synthesis. Project supported by the National Natural Science Foundation of China (Grant Nos. 11105100, 11205116, and 11375135) and the State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, China (Grant No. AWJ-M13-03).

  9. Negative ion production in the RF multiaperture surface-plasma source

    SciTech Connect

    Abdrashitov, G.; Belchenko, Yu. Dranichnikov, A.; Gorbovsky, A.; Kapitonov, V.; Kolmogorov, V.; Kondakov, A.; Konstantinov, S.; Sanin, A.; Selivanov, A.; Selivanov, P.; Shikhovtsev, I.; Stupishin, N.; Tiunov, M.; Ivanov, A.; Sotnikov, O.; Binderbauer, M.; Putvinski, S.; Smirnov, A.; Sevier, L.

    2015-04-08

    The experiments on negative hydrogen ion beam production in a multi-aperture long-pulse surface-plasma source are described. H- ions are produced on the surface of a plasma grid covered by cesium and illuminated by fast plasma particles. The source uses a radio-frequency driver to generate plasma. A composite magnet system made of external permanent magnets confines and filters electrons in the plasma region, and deflects them in the extraction area. A multiaperture, multi-electrode ion optical system is used for beam formation. The electrode heating and cooling during long pulses is accomplished by circulating a heat transfer fluid through channels drilled in the electrodes bodies. H- ions extraction through a single aperture and 21 apertures was performed and studied. A stable H- beam with the current up to 0.7 A, energy up to 74 kV, and pulse duration up to 7 s was routinely obtained.

  10. Interaction of wide band gap single crystals with 248 nm excimer laser radiation. XII. The emission of negative atomic ions from alkali halides

    SciTech Connect

    Kimura, Kenichi; Langford, S. C.; Dickinson, J. T.

    2007-12-01

    Many wide band gap materials yield charged and neutral emissions when exposed to sub-band-gap laser radiation at power densities below the threshold for optical breakdown and plume formation. In this work, we report the observation of negative alkali ions from several alkali halides under comparable conditions. We observe no evidence for negative halogen ions, in spite of the high electron affinities of the halogens. Significantly, the positive and negative alkali ions show a high degree of spatial and temporal overlap. A detailed study of all the relevant particle emissions from potassium chloride (KCl) suggests that K{sup -} is formed by the sequential attachment of two electrons to K{sup +}.

  11. Sensitive Ion Pump Current Monitoring Using an In-House Built Ion Pump Power Supply

    SciTech Connect

    Hansknecht, J.; Adderley, P.; Stutzman, M. L.; Poelker, M.

    2009-08-04

    Ion pumps are common vacuum pumps on DC high voltage photoguns and baked-accelerator beamlines. Commercial ion pump power supplies provide a measure of the electrical current drawn by the pump, but typically have resolution to only {approx}0.1 uA, which corresponds to pressure {approx}10{sup -9} Torr, a value considerably higher than the minimum pressure required by photoguns and nearby beamline. This submission describes a very sensitive in-house-built ion pump power supply with current monitoring capability good to less than 1 nA, and corresponding pressure in the low-minus;10{sup -11} Torr range. Besides providing 'free' pressure monitoring on a scale equivalent to the best available commercial pressure gauges, the ion pump power supply also serves as a sensitive diagnostic for detecting field emission from the photogun cathode electrode and bad electron beam orbits that could diminish photogun operating lifetime. Since its inception, this ion pump power supply has become an invaluable tool for operating the CEBAF polarized electron source. It is also a very useful low-cost diagnostic for ultrahigh vacuum studies in the laboratory.

  12. Dopant-assisted negative photoionization ion mobility spectrometry for sensitive detection of explosives.

    PubMed

    Cheng, Shasha; Dou, Jian; Wang, Weiguo; Chen, Chuang; Hua, Lei; Zhou, Qinghua; Hou, Keyong; Li, Jinghua; Li, Haiyang

    2013-01-02

    Ion mobility spectrometry (IMS) is a key trace detection technique for explosives and the development of a simple, stable, and efficient nonradioactive ionization source is highly demanded. A dopant-assisted negative photoionization (DANP) source has been developed for IMS, which uses a commercial VUV krypton lamp to ionize acetone as the source of electrons to produce negative reactant ions in air. With 20 ppm of acetone as the dopant, a stable current of reactant ions of 1.35 nA was achieved. The reactant ions were identified to be CO(3)(-)(H(2)O)(n) (K(0) = 2.44 cm(2) V(-1) s(-1)) by atmospheric pressure time-of-flight mass spectrometry, while the reactant ions in (63)Ni source were O(2)(-)(H(2)O)(n) (K(0) = 2.30 cm(2) V(-1) s(-1)). Finally, its capabilities for detection of common explosives including ammonium nitrate fuel oil (ANFO), 2,4,6-trinitrotoluene (TNT), N-nitrobis(2-hydroxyethyl)amine dinitrate (DINA), and pentaerythritol tetranitrate (PETN) were evaluated, and the limits of detection of 10 pg (ANFO), 80 pg (TNT), and 100 pg (DINA) with a linear range of 2 orders of magnitude were achieved. The time-of-flight mass spectra obtained with use of DANP source clearly indicated that PETN and DINA can be directly ionized by the ion-association reaction of CO(3)(-) to form PETN·CO(3)(-) and DINA·CO(3)(-) adduct ions, which result in good sensitivity for the DANP source. The excellent stability, good sensitivity, and especially the better separation between the reactant and product ion peaks make the DANP a potential nonradioactive ionization source for IMS.

  13. Measurements of negative ion densities in 13.56-MHz rf plasmas of CF4, C2F6, CHF3, and C3F8 using microwave resonance and the photodetachment effect

    NASA Astrophysics Data System (ADS)

    Haverlag, M.; Kono, A.; Passchier, D.; Kroesen, G. M. W.; Goedheer, W. J.; de Hoog, F. J.

    1991-10-01

    The high-power density of a frequency quadrupled pulsed Nd-YAG laser has been used to photodetach electrons from negative ions in rf plasmas generated within a microwave cavity. Negative ion densities have been determined by measuring the frequency shift of the resonance transmission, the shift being caused by the photoelectrons created by irradiating the plasma with the laser pulse. By measurement of the shape of the resonance curve as a function of time and of microwave frequency, and consecutive fitting of a parabola to the top of the resonance curve, the negative ion density has been determined as a function of gas pressure, rf power, and position in the plasma. Measurements were performed in plasmas of CF4, C2F6, CHF3, and C3F8. The results indicate that the negative ion densities are about one order of magnitude larger than the electron density, which is in good agreement with a fluid model calculation. The pressure and power dependence of the electron density and of the negative ion density gives insight in the relation between the electron temperature and the macroscopic plasma parameters. Measurements as a function of the laser wavelength, using a pulsed dye laser, show that in CF4 the negative ions mainly consist of F-, whereas in C2F6 significant densities of other negative ions may occur.

  14. Improvements of the magnetic field design for SPIDER and MITICA negative ion beam sources

    SciTech Connect

    Chitarin, G.; Agostinetti, P.; Aprile, D.; Marconato, N.; Veltri, P.

    2015-04-08

    The design of the magnetic field configuration in the SPIDER and MITICA negative ion beam sources has evolved considerably during the past four years. This evolution was driven by three factors: 1) the experimental results of the large RF-driven ion sources at IPP, which have provided valuable indications on the optimal magnetic configurations for reliable RF plasma source operation and for large negative ion current extraction, 2) the comprehensive beam optics and heat load simulations, which showed that the magnetic field configuration in the accelerator is crucial for keeping the heat load due to electrons on the accelerator grids within tolerable limits, without compromising the optics of the negative ion beam in the foreseen operating scenarios, 3) the progress of the detailed mechanical design of the accelerator, which stimulated the evaluation of different solutions for the correction of beamlet deflections of various origin and for beamlet aiming. On this basis, new requirements and solution concepts for the magnetic field configuration in the SPIDER and MITICA beam sources have been progressively introduced and updated until the design converged. The paper presents how these concepts have been integrated into a final design solution based on a horizontal “long-range” field (few mT) in combination with a “local” vertical field of some tens of mT on the acceleration grids.

  15. Positive/negative ion velocity mapping apparatus for electron-molecule reactions.

    PubMed

    Wu, Bin; Xia, Lei; Li, Hong-Kai; Zeng, Xian-Jin; Tian, Shan Xi

    2012-01-01

    In molecular dissociative ionization by electron collisions and dissociative electron attachment to molecule, the respective positively and negatively charged fragments are the important products. A compact ion velocity mapping apparatus is developed for the angular distribution measurements of the positive or negative fragments produced in the electron-molecule reactions. This apparatus consists of a pulsed electron gun, a set of ion velocity mapping optic lenses, a two-dimensional position detector including two pieces of micro-channel plates, and a phosphor screen, and a charge-coupled-device camera for data acquisition. The positive and negative ion detections can be simply realized by changing the voltage polarity of ion optics and detector. Velocity sliced images can be directly recorded using a narrow voltage pulse applied on the rear micro-channel plate. The efficient performance of this system is evaluated by measuring the angular distribution of O(-) from the electron attachments to NO at 7.3 and 8.3 eV and O(+) from the electron collision with CO at 40.0 eV.

  16. Simulation of the Partially Ionized Reacting Plasma Flow in a Negative Hydrogen Ion Source

    NASA Astrophysics Data System (ADS)

    Gatsonis, Nikolaos; Averkin, Sergey; Olson, Lynn

    2012-10-01

    A High Pressure Discharge Negative Ion Source (HPDNIS) operating on hydrogen is been under investigation. The Negative Ion Production (NIP) section of the HPDNIS attaches to the 10-100 Torr RF-discharge chamber with a micronozzle and ends with a grid that extracts the negative ion beam. The partially ionized and reacting plasma flow in the NIP section is simulated using an unstructured three-dimensional Direct Simulation Monte Carlo (U3DSMC) code. The NIP section contains a low-pressure plasma that includes H2, vibrationally-rotationally excited H2^*, negative hydrogen atoms H^-, and electrons. Primary reactions in the NIP section are dissociate attachment, H2^*+e->H^0+H^-and electron collisional detachment, e+H^-->H+2e. The U3DSMC computational domain includes the entrance to the NIP nozzle and the extraction grid at the exit. The flow parameters at the entrance are based on conditions in the RF-discharge chamber and are implemented in U3DSMC using a Kinetic-Moment subsonic boundary conditions method. The rotational and vibrational degrees of freedom in U3DSMC are implemented using the Larsen-Borgnakke model. Chemical reactions are implemented in U3DSMC using the Quantum-Kinetic model. Simulations cover the regime of operation of the HPDNIS and examine the flow characteristics inside the NIP section.

  17. Mixed Pierce-two-stream instability development in an extraction system of a negative ion source

    NASA Astrophysics Data System (ADS)

    Barminova, H. Y.; Chikhachev, A. S.

    2016-02-01

    Mixed Pierce-two-stream instability may occur in an extraction system of a negative ion source based on a volume-produced plasma. The reasons for instability development are discussed. Analytically the conditions of unstable beam propagation are determined. The instability threshold is shown to be increased compared with the pure Pierce instability. The influence of inclined perturbations on the instability behavior is investigated. The numerical calculations are performed in COMSOL Multiphysics. The simulation results confirm the existence of such a mixed instability appearance that develops due to both the electrons of the external circuit and the background positive ions.

  18. Mixed Pierce-two-stream instability development in an extraction system of a negative ion source

    SciTech Connect

    Barminova, H. Y.; Chikhachev, A. S.

    2016-02-15

    Mixed Pierce-two-stream instability may occur in an extraction system of a negative ion source based on a volume-produced plasma. The reasons for instability development are discussed. Analytically the conditions of unstable beam propagation are determined. The instability threshold is shown to be increased compared with the pure Pierce instability. The influence of inclined perturbations on the instability behavior is investigated. The numerical calculations are performed in COMSOL Multiphysics. The simulation results confirm the existence of such a mixed instability appearance that develops due to both the electrons of the external circuit and the background positive ions.

  19. Modified Ion-Acoustic Shock Waves and Double Layers in a Degenerate Electron-Positron-Ion Plasma in Presence of Heavy Negative Ions

    NASA Astrophysics Data System (ADS)

    Hossen, M. A.; Hossen, M. R.; Mamun, A. A.

    2014-12-01

    A general theory for nonlinear propagation of one dimensional modified ion-acoustic waves in an unmagnetized electron-positron-ion (e-p-i) degenerate plasma is investigated. This plasma system is assumed to contain relativistic electron and positron fluids, non-degenerate viscous positive ions, and negatively charged static heavy ions. The modified Burgers and Gardner equations have been derived by employing the reductive perturbation method and analyzed in order to identify the basic features (polarity, width, speed, etc.) of shock and double layer (DL) structures. It is observed that the basic features of these shock and DL structures obtained from this analysis are significantly different from those obtained from the analysis of standard Gardner or Burgers equations. The implications of these results in space and interstellar compact objects (viz. non-rotating white dwarfs, neutron stars, etc.) are also briefly mentioned.

  20. Ion optics for high power 50-cm-diam ion thrusters

    NASA Technical Reports Server (NTRS)

    Rawlin, Vincent K.; Millis, Marc G.

    1989-01-01

    The process used at the NASA-Lewis to fabricate 30 and 50-cm-diameter ion optics is described. The ion extraction capabilities of the 30 and 50-cm diameter ion optics were evaluated on divergent field and ring-cusp discharge chambers and compared. Perveance was found to be sensitive to the effects of the type and power of the discharge chamber and to the accelerator electrode hole diameter. Levels of up to 0.64 N and 20 kW for thrust and input power, respectively, were demonstrated with the divergent-field discharge chamber. Thruster efficiencies and specific impulse values up to 79 percent and 5000 sec., respectively, were achieved with the ring-cusp discharge chamber.

  1. Flashover lithium ion source development for large pulsed power accelerators

    SciTech Connect

    Bieg, K.W.; Burns, E.J.T.; Gerber, R.A.; Olsen, J.N.; Lamppa, K.P.

    1986-05-01

    The Particle Beam Fusion Accelerator II (PBFA II), a light-ion pulsed power accelerator intended for inertial confinement fusion (ICF) applications, is currently under construction at Sandia National Laboratories. The accelerator will deliver a 30 MV, 5 MA lithium beam from an Applied-B diode to drive an ICF target. The ion source for this diode will require a thin (approx.1 mm), dense (10/sup 16/ cm/sup -2/) anode plasma layer of singly ionized lithium over an anode area of 10/sup 3/ cm/sup 2/. One type of source being investigated is the flashover ion source, which generates the anode plasma via vacuum flashover of a lithium-bearing dielectric material. Experiments with a LiF flashover source on the 0.03 TW Nereus accelerator have shown that contaminant ions account for as much as 70% of the extracted ion beam current. To overcome this, we have explored in-diode cleaning of the externally prepared anode surface by glow discharge cleaning and vacuum baking as well as in-diode preparation of the anode surface by vacuum evaporation of the lithium dielectric. Lithium-bearing dielectric materials which have been investigated include LiF, LiI, LiNO/sub 3/, and Li/sub 3/N. These techniques have resulted in a two to threefold improvement in the extracted lithium ion purity. As a result, a glow-discharge cleaned LiF flashover source will be used for initial pulsed-power testing on PBFA II.

  2. Development of spectrally selective imaging system for negative hydrogen ion source

    SciTech Connect

    Ikeda, K. Nakano, H.; Tsumori, K.; Kisaki, M.; Nagaoka, K.; Osakabe, M.; Takeiri, Y.; Kaneko, O.

    2014-02-15

    A spectrally selective imaging system has been developed to obtain a distribution of H{sub α} emissions at the extraction region in a hydrogen negative ion source. The diagnostic system consisted of an aspherical lens, optical filters, a fiber image conduit, and a charge coupled device detector was installed on the 1/3-scaled hydrogen negative ion source in the National Institute for Fusion Science. The center of sight line passes beside the plasma grid (PG) surface with the distance of 11 mm, and the viewing angle has coverage 35 mm from the PG surface. Two dimensional H{sub α} distribution in the range up to 20 mm from the PG surface was clearly observed. The reduction area for H{sub α} emission caused by beam extraction was widely distributed in the extraction region near the PG surface.

  3. Negative ion formation by Rydberg electron transfer: Isotope-dependent rate constants

    SciTech Connect

    Carman, H.S. Jr.; Klots, C.E.; Compton, R.N.

    1991-01-01

    The formation of negative ions during collisions of rubidium atoms in selected ns and nd Rydberg states with carbon disulfide molecules has been studied for a range of effective principal quantum numbers (10 {le} n* {le} 25). For a narrow range of n* near n* = 17, rate constants for CS{sub 2}{sup {minus}} formation are found to depend upon the isotopic composition of the molecule, producing a negative ion isotope ratio (mass 78 to mass 76, amu) up to 10.5 times larger than the natural abundance ratio of CS{sub 2} isotopes in the reagent. The isotope ratio is found to depend strongly upon the initial quantum state of the Rydberg atom and perhaps upon the collision energy and CS{sub 2} temperature. 32 refs., 5 figs., 1 tab.

  4. Numerical Analysis of Electronegative Plasma near the Extraction Grid in Negative Ion Sources

    SciTech Connect

    Kuppel, S.; Matsushita, D.; Hatayama, A.; Bacal, M.

    2009-03-12

    The effects of plasma electrode (PE) bias on the extraction process in a negative ion source are studied with a series of two-dimensional (2D) electrostatic particle simulations. Motion of charged particles in their self-consistent electric field is modeled by the Particle-In-Cell (PIC) method. The effect of a weak transverse magnetic field is also taken into account. Extracted electron current density gradually decreases as the PE bias increases, while the absolute value of PE net current density initially increases and is saturated for higher values of PE bias. The extracted negative ion current density reaches a weak peak when the PE bias approaches the bulk plasma potential (Vpf) in the case without the PE bias, but the decrease afterwards is mild. Physical mechanisms leading to these results are discussed.

  5. Design of a cavity ring-down spectroscopy diagnostic for negative ion rf source SPIDER

    SciTech Connect

    Pasqualotto, R.; Alfier, A.; Lotto, L.

    2010-10-15

    The rf source test facility SPIDER will test and optimize the source of the 1 MV neutral beam injection systems for ITER. Cavity ring-down spectroscopy (CRDS) will measure the absolute line-of-sight integrated density of negative (H{sup -} and D{sup -}) ions, produced in the extraction region of the source. CRDS takes advantage of the photodetachment process: negative ions are converted to neutral hydrogen atoms by electron stripping through absorption of a photon from a laser. The design of this diagnostic is presented with the corresponding simulation of the expected performance. A prototype operated without plasma has provided CRDS reference signals, design validation, and results concerning the signal-to-noise ratio.

  6. Simple model analysis on the negative-ion extraction from a plasma

    SciTech Connect

    Lishev, St.; Shivarova, A.; Tarnev, Kh.

    2009-12-01

    Extraction of negative hydrogen ions from a plasma is analyzed with a view to the description of the extraction region of the negative hydrogen ion-beam sources developed for additional heating of fusion plasmas. The numerical procedure introduced in the study is a modification of the indirect Poisson-Vlasov method. It uses a condition for the plasma meniscus and employs analogy with the particle-in-cell model simulation. The analysis of the results shows that the charged particle velocity distribution at the entrance of the extraction region influences the properties of the extracted beams and its effect should be considered when conditions for well converged beams are looked for through variation in the plasma density and in the potentials of the electrodes of the extraction system.

  7. Effect of plasma grid bias on extracted currents in the RF driven surface-plasma negative ion source

    SciTech Connect

    Belchenko, Yu. Ivanov, A.; Sanin, A.; Sotnikov, O.; Shikhovtsev, I.

    2016-02-15

    Extraction of negative ions from the large inductively driven surface-plasma negative ion source was studied. The dependencies of the extracted currents vs plasma grid (PG) bias potential were measured for two modifications of radio-frequency driver with and without Faraday screen, for different hydrogen feeds and for different levels of cesium conditioning. The maximal PG current was independent of driver modification and it was lower in the case of inhibited cesium. The maximal extracted negative ion current depends on the potential difference between the near-PG plasma and the PG bias potentials, while the absolute value of plasma potential in the driver and in the PG area is less important for the negative ion production. The last conclusion confirms the main mechanism of negative ion production through the surface conversion of fast atoms.

  8. Low-Power Ion Propulsion for Small Spacecraft

    NASA Technical Reports Server (NTRS)

    Patterson, Michael J.; Oleson, Steven R.

    1997-01-01

    Analyses were conducted which indicate that sub kW-class ion thrusters may provide performance benefits for near-Earth space commercial and science missions. Small spacecraft applications with masses ranging from 50 to 500 kg and power levels less than 0.5 kW were considered. To demonstrate the efficacy of propulsion systems of this class, two potential missions were chosen as examples; a geosynchronous north-south station keeping application, and an Earth orbit magnetospheric mapping satellite constellation. Xenon ion propulsion system solutions using small thrusters were evaluated for these missions. A payload mass increase of more than 15% is provided by a 300-W ion system for the north-south station keeping mission. A launch vehicle reduction from four to one results from using the ion thruster for the magnetospheric mapping mission. Typical projected thruster performance over the input power envelope of 100-300 W range from approximately 40% to 54% efficiency and approximately 2000 to 3000 seconds specific impulse. Thruster technologies required to achieve the mission-required performance and lifetime are identified.

  9. Design of the new extraction grid for the NIO1 negative ion source

    SciTech Connect

    Veltri, P. Baltador, C.; Cavenago, M.

    2015-04-08

    NIO1 is a compact source of negative ions jointly developed by RFX and INFN, to study the physics of production and acceleration of H{sup −} beams. Negative ions, up to 120 mA of current, are extracted from a radiofrequency driven plasma, by means of a gridded electrode (plasma grid, PG) featuring 9 apertures arranged in a 3x3 square lattice. The same aperture pattern is replicated in the following electrodes, allowing ion acceleration up to 60 keV. All electrodes are realized in copper, by electro-deposition technique, leaving empty slots in the metal to place magnets and to flow water for the grid cooling. The first set of electrodes was completed, installed in the source and tested. At the same time, an upgrade of the extraction system was carried out, in order to optimize the beam optics and to explore alternative electrostatic configurations. In particular, the accelerator will be modified by completely replacing the EG grid, exploiting the modularity of NIO1. The new electrode will feature other slots in between apertures, to place additional magnets. This allows testing different magnetic configurations, to optimize electron filtering and residual ion deflection. The present paper describes the theoretical activities driving the design of these new extractors, carried out with most updated numerical codes, and exploiting the synergy with the refined modeling of the 40 A ITER negative ion sources, under development at Consorzio RFX. Beam simulations are performed both with tracing codes (SLACCAD and OPERA) and with particle in cell codes (ACCPIC)

  10. Li-ion synaptic transistor for low power analog computing

    SciTech Connect

    Fuller, Elliot J.; Gabaly, Farid El; Leonard, Francois; Agarwal, Sapan; Plimpton, Steven J.; Jacobs-Gedrim, Robin B.; James, Conrad D.; Marinella, Matthew J.; Talin, Albert Alec

    2016-11-22

    Nonvolatile redox transistors (NVRTs) based upon Li-ion battery materials are demonstrated as memory elements for neuromorphic computer architectures with multi-level analog states, “write” linearity, low-voltage switching, and low power dissipation. Simulations of back propagation using the device properties reach ideal classification accuracy. Finally, physics-based simulations predict energy costs per “write” operation of <10 aJ when scaled to 200 nm × 200 nm.

  11. Innovative Ionic Liquids: Electrolytes for Ion Power Sources

    DTIC Science & Technology

    2008-01-01

    PFESI–, MMBI+TFSI–, and MMBI+PFESI–. 1,2-dimethyl-3-n-propylimidazolium-MMPI + 1,2-dimethyl-3-n-butylimidazolium-MMBI + Bis ( trifluoromethanesulfonyl ... imide -TFSI – Bis (perfluoroethanesulfonyl) imide -PFESI – (a) (b) (c) (d) 2008 NRL REVIEW 145 CHEMICAL/BIOCHEMICAL RESEARCH lithium ion power sources, but...charged ring system, and an anion, such as a perfluorinated imide . It is this thermal and electrochemical stability and the stability of the organic

  12. Contribution of intracellular negative ion capacity to Donnan effect across the membrane in alkaliphilic Bacillus spp.

    PubMed

    Goto, Toshitaka; Hirabayashi, Toshinao; Morimoto, Hajime; Yamazaki, Koji; Inoue, Norio; Matsuyama, Hidetoshi; Yumoto, Isao

    2016-02-01

    To elucidate the energy production mechanism of alkaliphiles, the relationship between the H(+) extrusion rate by the respiratory chain and the corresponding ATP synthesis rate was determined in the facultative alkaliphile Bacillus cohnii YN-2000 and compared with those in the obligate alkaliphile Bacillus clarkii DSM 8720(T) and the neutralophile Bacillus subtilis IAM 1026. Under high aeration condition, much higher ATP synthesis rates and larger Δψ in the alkaliphilic Bacillus spp. grown at pH 10 than those in the neutralophilic B. subtilis grown at pH 7 were observed. This high ATP productivity could be attributed to the larger Δψ in alkaliphiles than in B. subtilis because the H(+) extrusion rate in alkaliphiles cannot account for the high ATP productivity. However, the large Δψ in the alkaliphiles could not be explained only by the H(+) translocation rate in the respiratory chain in alkaliphiles. There is a possibility that the Donnan effect across the membrane has the potential to contribute to the large Δψ. To estimate the contribution of the Donnan effect to the large Δψ in alkaliphilic Bacillus spp. grown at pH 10, intracellular negative ion capacity was examined. The intracellular negative ion capacities in alkaliphiles grown at pH 10 under high aeration condition corresponding to their intracellular pH (pH 8.1) were much higher than those in alkaliphiles grown under low aeration condition. A proportional relationship is revealed between the negative ion capacity and Δψ in alkaliphiles grown under different aeration conditions. This relationship strongly suggests that the intracellular negative ion capacity contributes to the formation of Δψ through the Donnan effect in alkaliphilic Bacillus spp. grown at pH 10.

  13. On the nonlinear dynamics of breathers waves in electronegative plasmas with Maxwellian negative ions

    NASA Astrophysics Data System (ADS)

    El-Tantawy, S. A.; Wazwaz, A. M.; Ali Shan, S.

    2017-02-01

    Theoretical investigations depending on the observation data are carried out for the nonlinear amplitude modulation of ion-acoustic waves propagating in an unmagnetized plasma composed of Maxwellian electrons and light negative ions in addition to mobile cold positive ions. The basic set of fluid equations is reduced to a nonlinear Schrödinger equation (NLSE) for describing the modulational instability process. The regions of the stable and unstable wavepackets have been confined precisely for various regimes. Moreover, the criteria for the existence of the breathers have been obtained. Analytical solutions of the NLSE in the forms of Akhmediev breathers, Kuznetsov-Ma (KM) solitons, and rogue waves are obtained. The characteristics of the profile of Akhmediev breathers, KM solitons, and freak waves are examined depending on the relevant physical parameters of the observed data.

  14. Modeling of the Plasma Electrode Bias in the Negative Ion Sources with 1D PIC Method

    SciTech Connect

    Matsushita, D.; Kuppel, S.; Hatayama, A.; Fukano, A.; Bacal, M.

    2009-03-12

    The effect of the plasma electrode bias voltage in the negative ion sources is modeled and investigated with one-dimensional plasma simulation. A particle-in-cell (PIC) method is applied to simulate the motion of charged particles in their self-consistent electric field. In the simulation, the electron current density is fixed to produce the bias voltage. The tendency of current-voltage characteristics obtained in the simulation show agreement with the one obtained from a simple probe theory. In addition, the H{sup -} ion density peak appears at the bias voltage close to the plasma potential as observed in the experiment. The physical mechanism of this peak H{sup -} ion density is discussed.

  15. Negative ion ESI-MS analysis of natural yellow dye flavonoids--An isotopic labelling study

    NASA Astrophysics Data System (ADS)

    McNab, Hamish; Ferreira, Ester S. B.; Hulme, Alison N.; Quye, Anita

    2009-07-01

    Flavonoids are amongst the most commonly used natural yellow colourants in paintings, as lakes, and in historical textiles as mordant dyes. In this paper, evidence from isotopically labelled substrates is used to propose negative ion electrospray collision induced decomposition mechanisms of flavones, flavonols and an isoflavone. These mechanisms include a retro-Diels-Alder fragmentation (observed for flavones and flavonols) and an M-122 fragmentation (characteristic of 3',4'-dihydroxyflavonols). In addition, the presence of a m/z 125 fragment ion is shown to be characteristic of 2'-hydroxyflavonols and an ion at m/z 149 is shown to be characteristic of 4'-hydroxyflavones. Applications of these methods are exemplified by the identification of a minor component of Dyer's camomile (Anthemis tinctoria L.) and the identification of the dye source in green threads sampled from an 18th Century Scottish tartan fragment.

  16. Space charge compensation in the Linac4 low energy beam transport line with negative hydrogen ions.

    PubMed

    Valerio-Lizarraga, Cristhian A; Lallement, Jean-Baptiste; Leon-Monzon, Ildefonso; Lettry, Jacques; Midttun, Øystein; Scrivens, Richard

    2014-02-01

    The space charge effect of low energy, unbunched ion beams can be compensated by the trapping of ions or electrons into the beam potential. This has been studied for the 45 keV negative hydrogen ion beam in the CERN Linac4 Low Energy Beam Transport using the package IBSimu [T. Kalvas et al., Rev. Sci. Instrum. 81, 02B703 (2010)], which allows the space charge calculation of the particle trajectories. The results of the beam simulations will be compared to emittance measurements of an H(-) beam at the CERN Linac4 3 MeV test stand, where the injection of hydrogen gas directly into the beam transport region has been used to modify the space charge compensation degree.

  17. Solitary and freak waves in a dusty plasma with negative ions

    SciTech Connect

    Abdelsalam, U. M.; Moslem, W. M.; Khater, A. H.; Shukla, P. K.

    2011-09-15

    It is shown that solitary and freak waves can propagate in a dusty plasma composed of positive and negative ions, as well as nonextensive electrons. The evolution of the solitary waves is described by the Korteweg-de Vries (KdV) equation. However, when the frequency of the carrier wave is much smaller than the ion plasma frequency then the KdV equation is also used to study the nonlinear evolution of modulationally unstable modified ion-acoustic wavepackets through the derivation of the nonlinear Schroedinger (NLS) equation. In order to show that the characteristics of the solitary and freak waves are influenced by the plasma parameters, the relevant numerical analysis of the appropriate nonlinear solutions is presented. The relevance of the present investigation to nonlinear waves in astrophysical plasma environments is discussed.

  18. Operation of RF driven negative ion source in a pure-hydrogen mode

    NASA Astrophysics Data System (ADS)

    Abdrashitov, G.; Belchenko, Yu.; Ivanov, A. A.; Gusev, I.; Senkov, D.; Sanin, A.; Shikhovtsev, I.; Sotnikov, O.; Kondakov, A.

    2015-04-01

    The production of negative hydrogen ions in the radio-frequency driven long-pulsed source with external antenna is studied. RF drivers with various geometry of external antenna, Faraday shield and magnets at the rear flange were examined. H- beam extraction through the single emission aperture was performed in the source pure-hydrogen mode with no external seed of alkali additives. H- beam with ion emission current density up to 5 mA/cm2 and energy up to 75 keV was regularly obtained in the 1 s pulses of the pure-hydrogen mode. The regular temporal increase of H- ion production due to deposition of impurities on the plasma grid surface was recorded. The H- emission current density increased up to 9 mA/cm2 in this case.

  19. Operation of RF driven negative ion source in a pure-hydrogen mode

    SciTech Connect

    Abdrashitov, G.; Belchenko, Yu. Gusev, I.; Senkov, D.; Sanin, A.; Shikhovtsev, I.; Kondakov, A.; Ivanov, A. A.; Sotnikov, O.

    2015-04-08

    The production of negative hydrogen ions in the radio-frequency driven long-pulsed source with external antenna is studied. RF drivers with various geometry of external antenna, Faraday shield and magnets at the rear flange were examined. H- beam extraction through the single emission aperture was performed in the source pure-hydrogen mode with no external seed of alkali additives. H- beam with ion emission current density up to 5 mA/cm{sup 2} and energy up to 75 keV was regularly obtained in the 1 s pulses of the pure-hydrogen mode. The regular temporal increase of H- ion production due to deposition of impurities on the plasma grid surface was recorded. The H- emission current density increased up to 9 mA/cm{sup 2} in this case.

  20. Oscillatory instability development in extraction system of a negative ion source

    SciTech Connect

    Barminova, H. Y.; Chikhachev, A. S.

    2016-02-15

    Conditions of oscillatory instability development in the extraction system of a negative hydrogen ion source based on a volume-produced plasma are studied. Such an ion source is characterized by the presence of the parent gas in the extraction system due to the leakage from the gas-discharge chamber. The secondary electrons in the area of the ion-optical system become the reason of oscillation appearance and possible beam current modulation. Analytically the range of the stable beam propagation is found. The instability increment is shown to be rather small. Maximum increment of the oscillations corresponds to the beam velocity equal to the thermal velocity of plasma electrons. The group velocity of the oscillations is close to the beam velocity so the oscillations are convective. Simulation of the low energy beam propagation is performed in COMSOL Multiphysics, the beam current modulation being observed.

  1. Inductively driven surface-plasma negative ion source for N-NBI use (invited)

    SciTech Connect

    Belchenko, Yu. Abdrashitov, G.; Deichuli, P.; Ivanov, A.; Gorbovsky, A.; Kondakov, A.; Sanin, A.; Sotnikov, O.; Shikhovtsev, I.

    2016-02-15

    The long-pulse surface-plasma source prototype is developed at Budker Institute of Nuclear Physics for negative-ion based neutral beam injector use. The essential source features are (1) an active temperature control of the ion-optical system electrodes by circulation of hot thermal fluid through the channels, drilled in the electrode bodies, (2) the concaved transverse magnetic field in the extraction and acceleration gaps, preventing the electrons trapping and avalanching, and (3) the directed cesium deposition via distribution tubes adjacent to the plasma grid periphery. The long term effect of cesium was obtained just with the single cesium deposition. The high voltage strength of ion-optical system electrodes was improved with actively heated electrodes. A stable H{sup −} beam with a current ∼1 A and energy 90 keV was routinely extracted and accelerated.

  2. Positive and negative gas-phase ion chemistry of chlorofluorocarbons in air at atmospheric pressure.

    PubMed

    Bosa, Elisabetta; Paradisi, Cristina; Scorrano, Gianfranco

    2003-01-01

    This paper presents a report on the ionization/dissociation of some representative chlorofluorocarbons (CFCs) induced by corona discharges in air at atmospheric pressure. Both positive and negative ions formed from Freons 1,1,1-trichlorotrifluoroethane (CFC 113a), 1,1,2-trichlorotrifluoroethane (CFC 113), and 1,1,1,2-tetrachlorodifluoroethane (CFC 112a) were analyzed using an atmospheric pressure chemical ionization mass spectrometry (APCI-MS) instrument. Energy-resolved mass spectra were obtained by modulating the kinetic energy of the ions via adjustment of the sampling cone potential (V(cone)). Positive ion spectra of the CFCs (M) at low V(cone) show no signals due to either M(+)* or MH(+) but only those due to species [M - Cl](+) and CX(3)(+) (X = Cl, F), likely formed via C-Cl and C-C bond cleavages following ionization via charge exchange. Charge localization in the products of C-C bond cleavage in M(+)* is driven by the stability of the neutral fragment. At low V(cone) the hydrates [M - Cl](+)(H(2)O) are also observed. In the case of 1,1,2,-trichlorotrifluoroethane, [M - F](+) species also form as a result of ion-molecule reactions. As V(cone) is increased collision-induced dissociation of [M - Cl](+) and [M - F](+), i.e., the perhalogenated cations C(2)X(5)(+) (X = Cl, F), takes place via carbene elimination. In some cases such elimination is preceded or accompanied by rearrangements involving transfer of halogen from one carbon to the other. Evidence is also presented for the occurrence of a condensation reaction of C(2)Cl(3)F(2)(+) with water to form a C(2)Cl(2)F(2)HO(+) species via elimination of HCl. Negative ion spectra are dominated by Cl(-) and its ion-neutral complexes with M and with water. Additional components of the plasma include ion-neutral complexes O(3)(-)(M), the molecular anion M(-) (observed only with 1,1,2-trichlorotrifluoroethane), and an interesting species corresponding to [M - Cl + O](-). The origin and structure of these [M - Cl + O

  3. Comparison of negative-ion proton-transfer with iodide ion chemical ionization mass spectrometry for quantification of isocyanic acid in ambient air

    NASA Astrophysics Data System (ADS)

    Woodward-Massey, Robert; Taha, Youssef M.; Moussa, Samar G.; Osthoff, Hans D.

    2014-12-01

    Isocyanic acid (HNCO) is a trace gas pollutant of potential importance to human health whose measurement has recently become possible through the development of negative-ion proton-transfer chemical ionization mass spectrometry (NI-PT-CIMS) with acetate reagent ion. In this manuscript, an alternative ionization and detection scheme, in which HNCO is quantified by iodide CIMS (iCIMS) as a cluster ion at m/z 170, is described. The sensitivity was inversely proportional to water vapor concentration but could be made independent of humidity changes in the sampled air by humidifying the ion-molecule reaction (IMR) region of the CIMS. The performance of the two ionization schemes was compared and contrasted using ambient air measurements of HNCO mixing ratios in Calgary, AB, Canada, by NI-PT-CIMS with acetate reagent ion from Dec 16 to 20, 2013, and by the same CIMS operated in iCIMS mode from Feb 3 to 7, 2014. The iCIMS exhibited a greater signal-to-noise ratio than the NI-PT-CIMS, not because of its sensitivity, which was lower (˜0.083 normalized counts per second (NCPS) per parts-per-trillion by volume (pptv) compared to ˜9.7 NCPS pptv-1), but because of a much lower and more stable background (3 ± 4 compared to a range of ˜2 × 103 to ˜6 × 103 NCPS). For the Feb 2014 data set, the HNCO mixing ratios in Calgary air ranged from <12 to 94 pptv (median 34 pptv), were marginally higher at night than during day, and correlated with nitrogen oxide (NOx = NO + NO2) mixing ratios and submicron particle volume. The ratios of HNCO to NOx observed are within the range of emission ratios reported for gasoline-powered motor vehicles.

  4. Simulation of diatomic gas-wall interaction and accommodation coefficients for negative ion sources and accelerators.

    PubMed

    Sartori, E; Brescaccin, L; Serianni, G

    2016-02-01

    Particle-wall interactions determine in different ways the operating conditions of plasma sources, ion accelerators, and beams operating in vacuum. For instance, a contribution to gas heating is given by ion neutralization at walls; beam losses and stray particle production-detrimental for high current negative ion systems such as beam sources for fusion-are caused by collisional processes with residual gas, with the gas density profile that is determined by the scattering of neutral particles at the walls. This paper shows that Molecular Dynamics (MD) studies at the nano-scale can provide accommodation parameters for gas-wall interactions, such as the momentum accommodation coefficient and energy accommodation coefficient: in non-isothermal flows (such as the neutral gas in the accelerator, coming from the plasma source), these affect the gas density gradients and influence efficiency and losses in particular of negative ion accelerators. For ideal surfaces, the computation also provides the angular distribution of scattered particles. Classical MD method has been applied to the case of diatomic hydrogen molecules. Single collision events, against a frozen wall or a fully thermal lattice, have been simulated by using probe molecules. Different modelling approximations are compared.

  5. Simulation of diatomic gas-wall interaction and accommodation coefficients for negative ion sources and accelerators

    NASA Astrophysics Data System (ADS)

    Sartori, E.; Brescaccin, L.; Serianni, G.

    2016-02-01

    Particle-wall interactions determine in different ways the operating conditions of plasma sources, ion accelerators, and beams operating in vacuum. For instance, a contribution to gas heating is given by ion neutralization at walls; beam losses and stray particle production—detrimental for high current negative ion systems such as beam sources for fusion—are caused by collisional processes with residual gas, with the gas density profile that is determined by the scattering of neutral particles at the walls. This paper shows that Molecular Dynamics (MD) studies at the nano-scale can provide accommodation parameters for gas-wall interactions, such as the momentum accommodation coefficient and energy accommodation coefficient: in non-isothermal flows (such as the neutral gas in the accelerator, coming from the plasma source), these affect the gas density gradients and influence efficiency and losses in particular of negative ion accelerators. For ideal surfaces, the computation also provides the angular distribution of scattered particles. Classical MD method has been applied to the case of diatomic hydrogen molecules. Single collision events, against a frozen wall or a fully thermal lattice, have been simulated by using probe molecules. Different modelling approximations are compared.

  6. Single discharge of the matrix source of negative hydrogen ions: Influence of the neutral particle dynamics

    SciTech Connect

    Paunska, Ts.; Todorov, D. Shivarova, A.; Tarnev, Kh.

    2015-04-08

    The study presents two-dimensional (2D) fluid-plasma-model description of a planar-coil inductively-driven discharge, considered as a single element of a matrix source of volume-produced negative hydrogen ions. Whereas the models developed up to now have been directed towards description of the charged particle behavior in the discharge, including that of the negative ions, this model stresses on the role of the neutral particle dynamics and of the surface processes in the formation of the discharge structure. The latter is discussed based on comparison of results obtained for discharges in a flowing gas and at a constant gas pressure as well as for different values of the coefficient of atom recombination on the walls. The conclusions are that the main plasma parameters – electron density and temperature and plasma potential – determining the gas discharge regime stay stable, regardless of changes in the redistribution of the densities of the neutral particles and of the positive ions. With regards to the volume production of the ions, which requires high density of (vibrationally excited) molecules, the impact on the degree of dissociation of the coefficient of atom recombination on the wall is discussed.

  7. Simulation of diatomic gas-wall interaction and accommodation coefficients for negative ion sources and accelerators

    SciTech Connect

    Sartori, E. Serianni, G.; Brescaccin, L.

    2016-02-15

    Particle-wall interactions determine in different ways the operating conditions of plasma sources, ion accelerators, and beams operating in vacuum. For instance, a contribution to gas heating is given by ion neutralization at walls; beam losses and stray particle production—detrimental for high current negative ion systems such as beam sources for fusion—are caused by collisional processes with residual gas, with the gas density profile that is determined by the scattering of neutral particles at the walls. This paper shows that Molecular Dynamics (MD) studies at the nano-scale can provide accommodation parameters for gas-wall interactions, such as the momentum accommodation coefficient and energy accommodation coefficient: in non-isothermal flows (such as the neutral gas in the accelerator, coming from the plasma source), these affect the gas density gradients and influence efficiency and losses in particular of negative ion accelerators. For ideal surfaces, the computation also provides the angular distribution of scattered particles. Classical MD method has been applied to the case of diatomic hydrogen molecules. Single collision events, against a frozen wall or a fully thermal lattice, have been simulated by using probe molecules. Different modelling approximations are compared.

  8. Enhanced Sensitivity for High Spatial Resolution Lipid Analysis by Negative Ion Mode MALDI Imaging Mass Spectrometry

    PubMed Central

    Angel, Peggi M.; Spraggins, Jeffrey M.; Baldwin, H. Scott; Caprioli, Richard

    2012-01-01

    We have achieved enhanced lipid imaging to a ~10 μm spatial resolution using negative ion mode matrix assisted laser desorption ionization (MALDI) imaging mass spectrometry, sublimation of 2,5-dihydroxybenzoic acid as the MALDI matrix and a sample preparation protocol that uses aqueous washes. We report on the effect of treating tissue sections by washing with volatile buffers at different pHs prior to negative ion mode lipid imaging. The results show that washing with ammonium formate, pH 6.4, or ammonium acetate, pH 6.7, significantly increases signal intensity and number of analytes recorded from adult mouse brain tissue sections. Major lipid species measured were glycerophosphoinositols, glycerophosphates, glycerolphosphoglycerols, glycerophosphoethanolamines, glycerophospho-serines, sulfatides, and gangliosides. Ion images from adult mouse brain sections that compare washed and unwashed sections are presented and show up to fivefold increases in ion intensity for washed tissue. The sample preparation protocol has been found to be applicable across numerous organ types and significantly expands the number of lipid species detectable by imaging mass spectrometry at high spatial resolution. PMID:22243218

  9. Improvement of photocatalytic efficiency of rutile titania by silver negative-ion implantation

    NASA Astrophysics Data System (ADS)

    Tsuji, Hiroshi; Sugahara, Hiromitsu; Gotoh, Yasuhito; Ishikawa, Junzo

    2003-05-01

    Optical absorption and photocatalytic properties of metal negative-ion implanted rutile-type titania (TiO 2) were studied to show metal nanoparticle formation in the surface region and improvement of photocatalytic efficiency. Silver negative ions were implanted into titania substrate (rutile crystalline substrate) at 65 keV with a dose of 3 × 10 16-1 × 10 17 ions/cm 2. The Ag-implanted rutile also showed a strong optical absorption near 2.1 eV after annealing above 400 °C, those well agreed with theoretical absorption peaks due to surface plasmon resonance. This means that Ag nanoparticles were formed in the surface layers of the titania. Photocatalytic efficiencies for Ag-implanted titania were evaluated by means of decolorization of methylene blue solution under fluorescent light. Ag-implanted titania (Ag: 65 keV, 5 × 10 16 ions/cm 2, 500 °C annealed) showed the better photocatalytic efficiency higher 2.2 times than that of unimplanted rutile titania. In the evaluation under fluorescent light through UV-cut filter, the Ag-implanted rutile showed 6.7 times better efficiency.

  10. Multi-dipolar microwave plasmas and their application to negative ion production

    SciTech Connect

    Béchu, S.; Bès, A.; Lacoste, A.; Aleiferis, S.; Ivanov, A. A. Jr.; Bacal, M.

    2013-10-15

    During the past decade multi-dipolar plasmas have been employed for various purposes such as surface treatments in biomedicine, physical and chemical vapour deposition for hydrogen storage, and applications in mechanical engineering. On the other hand, due to the design and operational mode of these plasma sources (i.e., strong permanent magnets for the electron cyclotron resonance coupling, low working pressure, and high electron density achieved) they are suitable for studying fundamental mechanisms involved in negative ion sources used in magnetically confined fusion and particle accelerators. Thus, this study presents an overview of fundamental results obtained with: (i) a single dipolar source, (ii) a network of seven dipolar plasma sources inserted into a magnetic multipolar chamber (Camembert III), and (iii) four dipolar sources housed in a smaller metallic cylinder (ROSAE III). Investigations with Langmuir probes of electron energy probability functions revealed the variation of the plasma properties versus the radial distance from the axis of a dipolar source in its mid plane and allowed the determination of the proportion between hot and cold electron populations in both chambers. These results are compared with the density of hydrogen negative ions, measured using the photodetachment technique. Electron energy probability functions obtained in these different configurations show the possibility of both hot and cold electron production. The former is a prerequisite for increasing the vibrational level of molecules and the dissociation degree and the latter for producing negative ions via dissociative attachment of the cold electrons or via surface production induced by H atoms.

  11. Negative ion extraction via particle simulation for fusion: critical assessment of recent contributions

    NASA Astrophysics Data System (ADS)

    Garrigues, L.; Fubiani, G.; Boeuf, J. P.

    2017-01-01

    Particle-in-cell (PIC) models have been extensively used in the last few years to describe negative ion extraction for neutral beam injection applications. We show that some of these models have been employed in conditions far from the requirements of particle simulations and that questionable conclusions about negative ion extraction, not supported by experimental evidence, have been obtained. We present a critical analysis of the method that has led to these conclusions and propose directions toward a more accurate and realistic description of negative ion extraction. We show in particular that, as expected in PIC simulations, mesh convergence is reached only if the grid spacing is on the order of or smaller than the minimum Debye length in the simulation domain, and that strong aberrations in the extracted beam are observed if this constraint is not respected. The method of injection of charged particles in the simulated plasma is also discussed, and we show that some injection methods used in the literature lead to unphysical results.

  12. Volume generation of negative ions in high density hydrogen discharges. Revision 1

    SciTech Connect

    Hiskes, J.R.; Karo, A.M.

    1983-11-11

    An optimized tandem two-chamber negative-ion source system is discussed. In the first chamber high energy (E > 20 eV) electron collisions provide for H/sub 2/ vibrational excitation, while in the second chamber negative ions are formed by dissociative attachment. The gas density, electron density, and system scale length are varied as independent parameters. The extracted negative ion current density passes through a maximum as electron and gas densities are varied. This maximum scales inversely with system scale length, R. The optimum extracted current densities occur for electron densities near nR = 10/sup 13/ electrons cm/sup -2/ and for gas densities, N/sub 2/R, in the range 10/sup 14/ to 10/sup 15/ molecules cm/sup -2/. The extracted current densities are sensitive to the atomic concentration in the discharge. The atomic concentration is parametrized by the wall recombination coefficient, ..gamma.., and scale length, R. As ..gamma.. ranges from 0.1 to 1.0 and for system scale lengths of one centimeter, extracted current densities range from 8.0 to 80. mA cm/sup -2/.

  13. Effect of Negative Ions on the Conductivity of the Titan Atmosphere

    NASA Technical Reports Server (NTRS)

    Borucki, W. J.; Bakes, E.; Whitten, R. C.; DeVincenzi, Donald L. (Technical Monitor)

    2000-01-01

    In an earlier paper, Borucki et al (1987) calculated the electrical conductivity and electrical charge on aerosols in Titan's atmosphere due to the ionization by galactic cosmic rays and electron precipitation from Saturn's magnetosphere. The lower atmosphere was predicted to be substantially more conducting than the atmospheres of Earth and Venus because of the high concentration of free electrons. The prediction of a high conductivity is based on the lack of electrophillic species which form negative ions with low mobility and which reduce the number of free electrons. At that time, no molecular species capable of forming negative ions in concentrations sufficient to perturb the atmospheric conductivity were identified. Recently, E. Bakes and her colleagues have been investigating the formation of nitrogenous macromolecules using quantum mechanical methods. Their calculations indicate that the molecules will be highly electrophillic and are likely to be present in the atmosphere at mixing ratios of order 10(exp -7). This mixing ratio is sufficiently large that a substantial reduction in the conductivity is expected at altitudes below 100 km. Revision of the atmospheric model to accommodate the presence of negative ions and to increase the fidelity of the modeling will be described.

  14. Development Efforts Expanded in Ion Propulsion: Ion Thrusters Developed With Higher Power Levels

    NASA Technical Reports Server (NTRS)

    Patterson, Michael J.; Rawlin, Vincent K.; Sovey, James S.

    2003-01-01

    The NASA Glenn Research Center was the major contributor of 2-kW-class ion thruster technology to the Deep Space 1 mission, which was successfully completed in early 2002. Recently, NASA s Office of Space Science awarded approximately $21 million to Glenn to develop higher power xenon ion propulsion systems for large flagship missions such as outer planet explorers and sample return missions. The project, referred to as NASA's Evolutionary Xenon Thruster (NEXT), is a logical follow-on to the ion propulsion system demonstrated on Deep Space 1. The propulsion system power level for NEXT is expected to be as high as 25 kW, incorporating multiple ion thrusters, each capable of being throttled over a 1- to 6-kW power range. To date, engineering model thrusters have been developed, and performance and plume diagnostics are now being documented. The project team-Glenn, the Jet Propulsion Laboratory, General Dynamics, Boeing Electron Dynamic Devices, the Applied Physics Laboratory, the University of Michigan, and Colorado State University-is in the process of developing hardware for a ground demonstration of the NEXT propulsion system, which comprises a xenon feed system, controllers, multiple thrusters, and power processors. The development program also will include life assessments by tests and analyses, single-string tests of ion thrusters and power systems, and finally, multistring thruster system tests in calendar year 2005. In addition, NASA's Office of Space Science selected Glenn to lead the development of a 25-kW xenon thruster to enable NASA to conduct future missions to the outer planets of Jupiter and beyond, under the High Power Electric Propulsion (HiPEP) program. The development of a 100-kW-class ion propulsion system and power conversion systems are critical components to enable future nuclear-electric propulsion systems. In fiscal year 2003, a team composed of Glenn, the Boeing Company, General Dynamics, the Applied Physics Laboratory, the Naval Research

  15. The negative inotropic effect of raised extracellular potassium and caesium ions on isolated frog atrial trabeculae.

    PubMed

    Chapman, R A; Rodrigo, G C

    1987-10-01

    The exposure of frog atrial trabeculae to Ringer solution containing an elevated K+ concentration, produces a depolarization of the membrane and a reduction of both the duration of the action potential and the strength of the heart beat. In voltage-clamped preparations, the effect of perfusion with K+-rich Ringer solution is threefold. First, a sustained inward current develops at the holding potential (-80 mV). Secondly, the contractions evoked by depolarizing clamp pulses are reduced: this effect which is greater upon the tonic phase of the contraction than the early phasic tension, is also seen to follow the addition of Cs+ ions to the bathing fluid; at equal concentrations K+ ions are the more effective. Thirdly, when measured with an ion-sensitive micro-electrode in ventricular trabeculae, the intracellular Na+ ion activity (aiNa) declines with a time course similar to the development of the negative inotropic effect. This suggests that the actions of raised [K+]o or [Cs+]o upon tension may be secondary to an effect on the movement of Na+ ions across the cell membrane, which by reducing aiNa may affect tension by way of the Na-Ca exchange.

  16. Enhancing glycan isomer separations with metal ions and positive and negative polarity ion mobility spectrometry-mass spectrometry analyses

    SciTech Connect

    Zheng, Xueyun; Zhang, Xing; Schocker, Nathaniel S.; Renslow, Ryan S.; Orton, Daniel J.; Khamsi, Jamal; Ashmus, Roger A.; Almeida, Igor C.; Tang, Keqi; Costello, Catherine E.; Smith, Richard D.; Michael, Katja; Baker, Erin S.

    2016-09-07

    Glycomics has become an increasingly important field of research since glycans play critical roles in biology processes ranging from molecular recognition and signaling to cellular communication. Glycans often conjugate with other biomolecules such as proteins and lipids, and alter their properties and functions, so understanding the effect glycans have on cellular systems is essential. However the analysis of glycans is extremely difficult due to their complexity and structural diversity (i.e., the number and identity of monomer units, and configuration of their glycosidic linkages and connectivities). In this work, we coupled ion mobility spectrometry with mass spectrometry (IMS-MS) to characterize glycan standards and biologically important isomers of synthetic αGal-containing O-glycans including glycotopes of the protozoan parasite Trypanosoma cruzi, which is the causative agent of Chagas disease. IMS-MS results showed significant differences for the glycan structural isomers when analyzed in positive and negative polarity and complexed with different metal cations. These results suggest specific metal ions or ion polarities could be used to target and baseline separate glycan isomers of interest with IMS-MS.

  17. RTV silicone rubber surface modification for cell biocompatibility by negative-ion implantation

    NASA Astrophysics Data System (ADS)

    Zheng, Chenlong; Wang, Guangfu; Chu, Yingjie; Xu, Ya; Qiu, Menglin; Xu, Mi

    2016-03-01

    A negative cluster ion implantation system was built on the injector of a GIC4117 tandem accelerator. Next, the system was used to study the surface modification of room temperature vulcanization silicone rubber (RTV SR) for cell biocompatibility. The water contact angle was observed to decrease from 117.6° to 99.3° as the C1- implantation dose was increased to 1 × 1016 ions/cm2, and the effects of C1-, C2- and O1- implantation result in only small differences in the water contact angle at 3 × 1015 ions/cm2. These findings indicate that the hydrophilicity of RTV SR improves as the dose is increased and that the radiation effect has a greater influence than the doping effect on the hydrophilicity. There are two factors influence hydrophilicity of RTV: (1) based on the XPS and ATR-FTIR results, it can be inferred that ion implantation breaks the hydrophobic functional groups (Sisbnd CH3, Sisbnd Osbnd Si, Csbnd H) of RTV SR and generates hydrophilic functional groups (sbnd COOH, sbnd OH, Sisbnd (O)x (x = 3,4)). (2) SEM reveals that the implanted surface of RTV SR appears the micro roughness such as cracks and wrinkles. The hydrophilicity should be reduced due to the lotus effect (Zhou Rui et al., 2009). These two factors cancel each other out and make the C-implantation sample becomes more hydrophilic in general terms. Finally, cell culture demonstrates that negative ion-implantation is an effective method to improve the cell biocompatibility of RTV SR.

  18. Nuclear powered Mars cargo transport mission utilizing advanced ion propulsion

    SciTech Connect

    Galecki, D.L.; Patterson, M.J.

    1987-01-01

    Nuclear-powered ion propulsion technology was combined with detailed trajectory analysis to determine propulsion system and trajectory options for an unmanned cargo mission to Mars in support of manned Mars missions. A total of 96 mission scenarios were identified by combining two power levels, two propellants, four values of specific impulse per propellant, three starting altitudes, and two starting velocities. Sixty of these scenarios were selected for a detailed trajectory analysis; a complete propulsion system study was then conducted for 20 of these trajectories. Trip times ranged from 344 days for a xenon propulsion system operating at 300 kW total power and starting from lunar orbit with escape velocity, to 770 days for an argon propulsion system operating at 300 kW total power and starting from nuclear start orbit with circular velocity. Trip times for the 3 MW cases studied ranged from 356 to 413 days. Payload masses ranged from 5700 to 12,300 kg for the 300 kW power level, and from 72,200 to 81,500 kg for the 3 MW power level.

  19. The Impact of Early Powered Mobility on Parental Stress, Negative Emotions, and Family Social Interactions

    ERIC Educational Resources Information Center

    Tefft, Donita; Guerette, Paula; Furumasu, Jan

    2011-01-01

    Powered mobility has been found to have positive effects on young children with severe physical disabilities, but the impact on the family has been less well documented. We evaluated the impact of early powered mobility on parental stress, negative emotions, perceived social interactions, and parental satisfaction with wheelchair characteristics…

  20. Study of a High Voltage Ion Engine Power Supply

    NASA Technical Reports Server (NTRS)

    Stuart, Thomas A.; King, Roger J.; Mayer, Eric

    1996-01-01

    A complete laboratory breadboard version of a ion engine power converter was built and tested. This prototype operated on a line voltage of 80-120 Vdc, and provided output ratings of 1100 V at 1.8 kW, and 250 V at 20 mA. The high-voltage (HV) output voltage rating was revised from the original value of 1350 V at the beginning of the project. The LV output was designed to hold up during a 1-A surge current lasting up to 1 second. The prototype power converter included a internal housekeeping power supply which also operated from the line input. The power consumed in housekeeping was included in the overall energy budget presented for the ion engine converter. HV and LV output voltage setpoints were commanded through potentiometers. The HV converter itself reached its highest power efficiency of slightly over 93% at low line and maximum output. This would dip below 90% at high line. The no-load (rated output voltages, zero load current) power consumption of the entire system was less than 13 W. A careful loss breakdown shows that converter losses are predominately Metal-Oxide-Semiconductor Field Effect Transistor (MOSFET) conduction losses and HV rectifier snubbing losses, with the rectifier snubbing losses becoming predominant at high line. This suggests that further improvements in power efficiency could best be obtained by either developing a rectifier that was adequately protected against voltage overshoot with less snubbing, or by developing a pre-regulator to reduced the range of line voltage on the converter. The transient testing showed the converter to be fully protected against load faults, including a direct short-circuit from the HV output to the LV output terminals. Two currents sensors were used: one to directly detect any core ratcheting on the output transformer and re-initiate a soft start, and the other to directly detect a load fault and quickly shut down the converter for load protection. The finished converter has been extensively fault tested

  1. On the meniscus formation and the negative hydrogen ion extraction from ITER neutral beam injection relevant ion source

    NASA Astrophysics Data System (ADS)

    Mochalskyy, S.; Wünderlich, D.; Ruf, B.; Fantz, U.; Franzen, P.; Minea, T.

    2014-10-01

    The development of a large area (Asource,ITER = 0.9 × 2 m2) hydrogen negative ion (NI) source constitutes a crucial step in construction of the neutral beam injectors of the international fusion reactor ITER. To understand the plasma behaviour in the boundary layer close to the extraction system the 3D PIC MCC code ONIX is exploited. Direct cross checked analysis of the simulation and experimental results from the ITER-relevant BATMAN source testbed with a smaller area (Asource,BATMAN ≈ 0.32 × 0.59 m2) has been conducted for a low perveance beam, but for a full set of plasma parameters available. ONIX has been partially benchmarked by comparison to the results obtained using the commercial particle tracing code for positive ion extraction KOBRA3D. Very good agreement has been found in terms of meniscus position and its shape for simulations of different plasma densities. The influence of the initial plasma composition on the final meniscus structure was then investigated for NIs. As expected from the Child-Langmuir law, the results show that not only does the extraction potential play a crucial role on the meniscus formation, but also the initial plasma density and its electronegativity. For the given parameters, the calculated meniscus locates a few mm downstream of the plasma grid aperture provoking a direct NI extraction. Most of the surface produced NIs do not reach the plasma bulk, but move directly towards the extraction grid guided by the extraction field. Even for artificially increased electronegativity of the bulk plasma the extracted NI current from this region is low. This observation indicates a high relevance of the direct NI extraction. These calculations show that the extracted NI current from the bulk region is low even if a complete ion-ion plasma is assumed, meaning that direct extraction from surface produced ions should be present in order to obtain sufficiently high extracted NI current density. The calculated extracted currents, both ions

  2. A collisional radiative model of hydrogen plasmas developed for diagnostic purposes of negative ion sources

    SciTech Connect

    Iordanova, Snejana Paunska, Tsvetelina

    2016-02-15

    A collisional radiative model of low-pressure hydrogen plasmas is elaborated and applied in optical emission spectroscopy diagnostics of a single element of a matrix source of negative hydrogen ions. The model accounts for the main processes determining both the population densities of the first ten states of the hydrogen atom and the densities of the positive hydrogen ions H{sup +}, H{sub 2}{sup +}, and H{sub 3}{sup +}. In the calculations, the electron density and electron temperature are varied whereas the atomic and molecular temperatures are included as experimentally obtained external parameters. The ratio of the H{sub α} to H{sub β} line intensities is calculated from the numerical results for the excited state population densities, obtained as a solution of the set of the steady-state rate balance equations. The comparison of measured and theoretically obtained ratios of line intensities yields the values of the electron density and temperature as well as of the degree of dissociation, i.e., of the parameters which have a crucial role for the volume production of the negative ions.

  3. Modeling activities on the negative-ion-based Neutral Beam Injectors of the Large Helical Device

    SciTech Connect

    Agostinetti, P.; Antoni, V.; Chitarin, G.; Pilan, N.; Serianni, G.; Veltri, P.; Cavenago, M.; Nakano, H.; Takeiri, Y.; Tsumori, K.

    2011-09-26

    At the National Institute for Fusion Science (NIFS) large-scaled negative ion sources have been widely used for the Neutral Beam Injectors (NBIs) mounted on the Large Helical Device (LHD), which is the world-largest superconducting helical system. These injectors have achieved outstanding performances in terms of beam energy, negative-ion current and optics, and represent a reference for the development of heating and current drive NBIs for ITER.In the framework of the support activities for the ITER NBIs, the PRIMA test facility, which includes a RF-drive ion source with 100 keV accelerator (SPIDER) and a complete 1 MeV Neutral Beam system (MITICA) is under construction at Consorzio RFX in Padova.An experimental validation of the codes has been undertaken in order to prove the accuracy of the simulations and the soundness of the SPIDER and MITICA design. To this purpose, the whole set of codes have been applied to the LHD NBIs in a joint activity between Consorzio RFX and NIFS, with the goal of comparing and benchmarking the codes with the experimental data. A description of these modeling activities and a discussion of the main results obtained are reported in this paper.

  4. Upgraded millimeter-wave interferometer for measuring the electron density during the beam extraction in the negative ion source.

    PubMed

    Tokuzawa, T; Kisaki, M; Nagaoka, K; Tsumori, K; Ito, Y; Ikeda, K; Nakano, H; Osakabe, M; Takeiri, Y; Kaneko, O

    2016-11-01

    The upgraded millimeter-wave interferometer with the frequency of 70 GHz is installed on a large-scaled negative ion source. Measurable line-averaged electron density is from 2 × 10(15) to 3 × 10(18) m(-3) in front of the plasma grid. Several improvements such as the change to shorter wavelength probing with low noise, the installation of special ordered horn antenna, the signal modulation for a high accuracy digital phase detection, the insertion of insulator, and so on, are carried out for the measurement during the beam extraction by applying high voltage. The line-averaged electron density is successfully measured and it is found that it increases linearly with the arc power and drops suddenly at the beam extraction.

  5. Upgraded millimeter-wave interferometer for measuring the electron density during the beam extraction in the negative ion source

    NASA Astrophysics Data System (ADS)

    Tokuzawa, T.; Kisaki, M.; Nagaoka, K.; Tsumori, K.; Ito, Y.; Ikeda, K.; Nakano, H.; Osakabe, M.; Takeiri, Y.; Kaneko, O.

    2016-11-01

    The upgraded millimeter-wave interferometer with the frequency of 70 GHz is installed on a large-scaled negative ion source. Measurable line-averaged electron density is from 2 × 1015 to 3 × 1018 m-3 in front of the plasma grid. Several improvements such as the change to shorter wavelength probing with low noise, the installation of special ordered horn antenna, the signal modulation for a high accuracy digital phase detection, the insertion of insulator, and so on, are carried out for the measurement during the beam extraction by applying high voltage. The line-averaged electron density is successfully measured and it is found that it increases linearly with the arc power and drops suddenly at the beam extraction.

  6. Low power RF amplifier circuit for ion trap applications

    NASA Astrophysics Data System (ADS)

    Noriega, J. R.; García-Delgado, L. A.; Gómez-Fuentes, R.; García-Juárez, A.

    2016-09-01

    A low power RF amplifier circuit for ion trap applications is presented and described. The amplifier is based on a class-D half-bridge amplifier with a voltage mirror driver. The RF amplifier is composed of an RF class-D amplifier, an envelope modulator to ramp up the RF voltage during the ion analysis stage, a detector or amplitude demodulation circuit for sensing the output signal amplitude, and a feedback amplifier that linearizes the steady state output of the amplifier. The RF frequency is set by a crystal oscillator and the series resonant circuit is tuned to the oscillator frequency. The resonant circuit components have been chosen, in this case, to operate at 1 MHz. In testings, the class-D stage operated at a maximum of 78 mW at 1.1356 MHz producing 225 V peak.

  7. Analysis of the beam halo in negative ion sources by using 3D3V PIC code.

    PubMed

    Miyamoto, K; Nishioka, S; Goto, I; Hatayama, A; Hanada, M; Kojima, A; Hiratsuka, J

    2016-02-01

    The physical mechanism of the formation of the negative ion beam halo and the heat loads of the multi-stage acceleration grids are investigated with the 3D PIC (particle in cell) simulation. The following physical mechanism of the beam halo formation is verified: The beam core and the halo consist of the negative ions extracted from the center and the periphery of the meniscus, respectively. This difference of negative ion extraction location results in a geometrical aberration. Furthermore, it is shown that the heat loads on the first acceleration grid and the second acceleration grid are quantitatively improved compared with those for the 2D PIC simulation result.

  8. Effects of roughness and temperature on low-energy hydrogen positive and negative ion reflection from silicon and carbon surfaces.

    PubMed

    Tanaka, N; Kato, S; Miyamoto, T; Nishiura, M; Tsumori, K; Matsumoto, Y; Kenmotsu, T; Okamoto, A; Kitajima, S; Sasao, M; Wada, M; Yamaoka, H

    2014-02-01

    Angle-resolved energy distribution functions of positive and negative hydrogen ions produced from a rough-finished Si surface under 1 keV proton irradiation have been measured. The corresponding distribution from a crystalline surface and a carbon surface are also measured for comparison. Intensities of positive and negative ions from the rough-finished Si are substantially smaller than those from crystalline Si. The angular distributions of these species are broader for rough surface than the crystalline surface. No significant temperature dependence for positive and negative ion intensities is observed for all samples in the temperature range from 300 to 400 K.

  9. Analysis of the beam halo in negative ion sources by using 3D3V PIC code

    SciTech Connect

    Miyamoto, K.; Nishioka, S.; Goto, I.; Hatayama, A.; Hanada, M.; Kojima, A.; Hiratsuka, J.

    2016-02-15

    The physical mechanism of the formation of the negative ion beam halo and the heat loads of the multi-stage acceleration grids are investigated with the 3D PIC (particle in cell) simulation. The following physical mechanism of the beam halo formation is verified: The beam core and the halo consist of the negative ions extracted from the center and the periphery of the meniscus, respectively. This difference of negative ion extraction location results in a geometrical aberration. Furthermore, it is shown that the heat loads on the first acceleration grid and the second acceleration grid are quantitatively improved compared with those for the 2D PIC simulation result.

  10. Enhanced surface production in H{sup -} ion sources by introducing a negatively biased secondary electrode

    SciTech Connect

    An, Young Hwa; Jung, Bong Ki; Hwang, Y. S.

    2010-02-15

    A transformer coupled plasma negative hydrogen ion source with an external rf antenna has been developed at SNU, which is capable of continuous operation with long lifetime. A positively biased plasma electrode (PE) has been successfully used for the optimization of H{sup -} extraction. With molybdenum-coated stainless steel PE, the enhancement of H{sup -} production at the electrode surface was observed at the bias voltage lower than the plasma potential. However, the low bias voltage is unfavorable to H{sup -} beam extraction since the negative ions are repelled. A second electrode is inserted in front of the PE to enhance H{sup -} production at the electrode surface without impeding beam extraction. By biasing the secondary electrode (SE) more negatively, H{sup -} production is clearly enhanced although the SE itself reduces H{sup -} beam currents because of suppressed electron transport in front of the PE. In this configuration enhancement of surface productions is most pronounced in tantalum electrode among various electrode materials.

  11. Diagnosis of power fade mechanisms in high-power lithium-ion cells

    NASA Astrophysics Data System (ADS)

    Abraham, D. P.; Liu, J.; Chen, C. H.; Hyung, Y. E.; Stoll, M.; Elsen, N.; MacLaren, S.; Twesten, R.; Haasch, R.; Sammann, E.; Petrov, I.; Amine, K.; Henriksen, G.

    Hybrid electric vehicles (HEV) need long-lived high-power batteries as energy storage devices. Batteries based on lithium-ion technology can meet the high-power goals but have been unable to meet HEV calendar-life requirements. As part of the US Department of Energy's Advanced Technology Development (ATD) Program, diagnostic studies are being conducted on 18650-type lithium-ion cells that were subjected to accelerated aging tests at temperatures ranging from 40 to 70 °C. This article summarizes data obtained by gas chromatography, liquid chromatography, electron microscopy, X-ray spectroscopy and electrochemical techniques, and identifies cell components that are responsible for the observed impedance rise and power fade.

  12. Aharonov-Bohm Effect in the Photodetachment Microscopy of Hydrogen Negative Ions in an Electric Field

    NASA Astrophysics Data System (ADS)

    Wang, Dehua

    2014-09-01

    The Aharonov-Bohm (AB) effect in the photodetachment microscopy of the H- ions in an electric field has been studied on the basis of the semiclassical theory. After the H- ion is irradiated by a laser light, they provide a coherent electron source. When the detached electron is accelerated by a uniform electric field, two trajectories of a detached electron which run from the source to the same point on the detector, will interfere with each other and lead to an interference pattern in the photodetachment microscopy. After the solenoid is electrified beside the H- ion, even though no Lorentz force acts on the electron outside the solenoid, the photodetachment microscopy interference pattern on the detector is changed with the variation in the magnetic flux enclosed by the solenoid. This is caused by the AB effect. Under certain conditions, the interference pattern reaches the macroscopic dimensions and could be observed in a direct AB effect experiment. Our study can provide some predictions for the future experimental study of the AB effect in the photodetachment microscopy of negative ions.

  13. Ion-implanted high microwave power indium phosphide transistors

    NASA Technical Reports Server (NTRS)

    Biedenbender, Michael D.; Kapoor, Vik J.; Messick, Louis J.; Nguyen, Richard

    1989-01-01

    Encapsulated rapid thermal annealing (RTA) has been used in the fabrication of InP power MISFETs with ion-implanted source, drain, and active-channel regions. The MISFETs had a gate length of 1.4 microns. Six to ten gate fingers per device, with individual gate finger widths of 100 or 125 microns, were used to make MISFETs with total gate widths of 0.75, 0.8, or 1 mm. The source and drain contact regions and the channel region of the MISFETs were fabricated using Si implants in InP at energies from 60 to 360 keV with doses of (1-560) x 10 to the 12th/sq cm. The implants were activated using RTA at 700 C for 30 sec in N2 or H2 ambients using an Si3N4 encapsulant. The high-power high-efficiency MISFETs were characterized at 9.7 GHz, and the output microwave power density for the RTA conditions used was as high as 2.4 W/mm. For a 1-W input at 9.7 GHz gains up to 3.7 dB were observed, with an associated power-added efficiency of 29 percent and output power density 70 percent greater than that of GaAs MESFETs.

  14. A Negative-Surface Ionization for Generation of Halogen Radioactive Ion Beams

    SciTech Connect

    Zaim, H.

    2001-04-16

    A simple and efficient negative surface ionization source has been designed, fabricated and initially tested for on-line generation of radioactive ion beams of the halogens (Cl, Br, I, and At) for use in the nuclear-structure and nuclear-astrophysics research programs at the Holifield Radioactive Ion Beam Facility. The source utilizes a solid, spherical geometry LaB{sub 6} surface ionizer for forming highly electronegative atoms and molecules. Despite its widely publicized propensity for being easily poisoned, no evidences of this effect were experienced during testing of the source. Nominal efficiencies of 15% for Br{sup {minus}} beam generation were obtained during off-line evaluation of the source with AlBr3 feed material when account is taken of the fractional dissociation of the molecule. Principles of operation, design features, operational parameter data, initial performance results, and beam quality data (emittance) are presented in this article.

  15. First negative ion beam measurement by the Short-Time Retractable Instrumented Kalorimeter Experiment (STRIKE)

    SciTech Connect

    Serianni, G. De Muri, M.; Veltri, P.; Bonomo, F.; Chitarin, G.; Pasqualotto, R.; Pavei, M.; Rizzolo, A.; Valente, M.; Muraro, A.; Franzen, P.; Ruf, B.; Schiesko, L.

    2014-02-15

    The Source for Production of Ion of Deuterium Extracted from Rf plasma (SPIDER) test facility is under construction in Padova to optimise the operation of the beam source of ITER neutral beam injectors. The SPIDER beam will be characterised by the instrumented calorimeter STRIKE, whose main components are one-directional carbon-fibre-carbon-composite tiles. A small-scale version of the entire system has been employed in the BAvarian Test MAchine for Negative ions (BATMAN) testbed by arranging two prototype tiles in the vertical direction. The paper presents a description of the mini-STRIKE system and of the data analysis procedures, as well as some results concerning the BATMAN beam under varying operating conditions.

  16. Instability range of microsolvated multiply charged negative ions: prediction from detachment energy of stable hydrated clusters.

    PubMed

    Pathak, A K; Samanta, A K; Maity, D K; Mukherjee, T; Ghosh, S K

    2011-02-01

    We have presented a first-principle theory-based derivation of an exact expression for the solvent number-dependent electron-detachment energy of a solvated species in the thermodynamic limit. We also propose a generalized equation bridging the electron detachment energies for small and infinitely large clusters, thus providing a new route to calculate the ionization potential of a negatively charged ion from the electron-detachment energies of its stable hydrated clusters. Most importantly, it has the ability to predict the instability range of microhydrated anions. The calculated results for the ionization potential for a number of ions are found to be in good agreement with the available experimental results, and the predicted instability range for the doubly charged anions SO₄²⁻ and C₂O₄²⁻ is also consistent with experimental and ab initio results.

  17. Monitoring Surface Condition of Plasma Grid of a Negative Hydrogen Ion Source

    SciTech Connect

    Wada, M.; Kasuya, T.; Tokushige, S.; Kenmotsu, T.

    2011-09-26

    Surface condition of a plasma grid in a negative hydrogen ion source is controlled so as to maximize the beam current under a discharge operation with introducing Cs into the ion source. Photoelectric current induced by laser beams incident on the plasma grid can produce a signal to monitor the surface condition, but the signal detection can be easily hindered by plasma noise. Reduction in size of a detection electrode embedded in the plasma grid can improve signal-to-noise ratio of the photoelectric current from the electrode. To evaluate the feasibility of monitoring surface condition of a plasma gird by utilizing photoelectric effect, a small experimental setup capable of determining quantum yields of a surface in a cesiated plasma environment is being assembled. Some preliminary test results of the apparatus utilizing oxide cathodes are reported.

  18. Ambipolar escape from Venus, Mars and Titan, and negative ions at Titan

    NASA Astrophysics Data System (ADS)

    Coates, Andrew

    2016-07-01

    Ionospheric photoelectrons are a natural product of the photo-ionisation of planetary atmospheres. Their energy spectrum is distinctive and depends on the solar spectrum in the EUV and X-ray region. On production, the energetic electrons move along the magnetic field (open or draped), setting up an ambipolar electric field which can extract ions. This provides an escape mechanism similar to Earth's 'polar wind'. As these objects are unmagnetised, this produces an extended escape mechanism over the whole sunlit ionosphere. Here, we review recent measurements of photoelectrons far from the parent objects at Venus, Mars and Titan, from Venus Express, Mars Express, Maven and Cassini, and discuss similarities and related escape rates. We also review the pioneering observations of the remarkably heavy negative ions discovered in Titan's ionosphere.

  19. Early time evolution of negative ion clouds and electron density depletions produced during electron attachment chemical release experiments

    NASA Technical Reports Server (NTRS)

    Scales, W. A.; Bernhardt, P. A.; Ganguli, G.

    1994-01-01

    Two-dimensional electrostatic particle-in-cell simulations are used to study the early time evolution of electron depletions and negative ion clouds produced during electron attachment chemical releases in the ionosphere. The simulation model considers the evolution in the plane perpendicular to the magnetic field and a three-species plasma that contains electrons, positive ions, and also heavy negative ions that result as a by-product of the electron attachment reaction. The early time evolution (less than the negative ion cyclotron period) of the system shows that a negative charge surplus initially develops outside of the depletion boundary as the heavy negative ions move across the boundary. The electrons are initially restricted from moving into the depletion due to the magnetic field. An inhomogenous electric field develops across the boundary layer due to this charge separation. A highly sheared electron flow velocity develops in the depletion boundary due to E x B and Delta-N x B drifts that result from electron density gradients and this inhomogenous electric field. Structure eventually develops in the depletion boundary layer due to low-frequency electrostatic waves that have growth times shorter than the negative ion cyclotron period. It is proposed that these waves are most likely produced by the electron-ion hybrid instability that results from sufficiently large shears in the electron flow velocity.

  20. Fluid Model Analysis of the Distribution of the Negative Ion Density before the Extraction from a Tandem Type of a Plasma Source

    SciTech Connect

    St Lishev, Stiliyan; Shivarova, Antonia P.; Tarnev, Khristo Ts.

    2011-09-26

    Unified description of the expansion (through a magnetic filter) and extraction regions, including also the driver, of volume-production based sources of negative hydrogen ions is presented in the study. The model is one-dimensional, developed within the fluid plasma theory. It covers description of both the second chamber of the tandem sources and a single inductively-driven (with a planar coil) discharge of a matrix source. Four parameters have been varied in the analysis of the results: type, position and magnitude of the filter field and rf power applied for the discharge maintenance. The obtained results for the spatial distribution of the plasma parameters as well as for the electronegativity, for the negative ion beam current and its ratio to the electron current at the position of the extraction are discussed regarding optimum conditions for the source operation. The conclusion is that a magnetic field extended over a large region till the extraction favors locality in the discharge behavior and, respectively, the local production of the negative ions. This leads to high density of the extracted negative ion beam current at reasonable values of its ratio to the electron current density.

  1. Ion accelerator systems for high power 30 cm thruster operation

    NASA Technical Reports Server (NTRS)

    Aston, G.

    1982-01-01

    Two and three-grid accelerator systems for high power ion thruster operation were investigated. Two-grid translation tests show that over compensation of the 30 cm thruster SHAG grid set spacing the 30 cm thruster radial plasma density variation and by incorporating grid compensation only sufficient to maintain grid hole axial alignment, it is shown that beam current gains as large as 50% can be realized. Three-grid translation tests performed with a simulated 30 cm thruster discharge chamber show that substantial beamlet steering can be reliably affected by decelerator grid translation only, at net-to-total voltage ratios as low as 0.05.

  2. Development Status of a Power Processing Unit for Low Power Ion Thrusters

    NASA Technical Reports Server (NTRS)

    Pinero, Luis R.; Bowers, Glen E.; Lafontaine, Eric M.

    2000-01-01

    An advanced breadboard Power Processing Unit (PPU) for a low power ion propulsion system incorporating mass reduction techniques was designed and fabricated. As a result of similar output current requirements, the discharge supply was also used to provide the neutralizer heater and discharge heater functions by using three relays to switch the output connections. This multi-function supply reduces to four the number of power converters needed to produce the required six electrical outputs. Switching frequencies of 20 and 50 kHz were chosen as a compromise between the size of the magnetic components and switching losses. The advanced breadboard PPU is capable of a maximum total output power of 0.47 kW. Its component mass is 0.65 kg and its total mass 1.9 kg. The total efficiency at full power is 0.89.

  3. Characterisation of polyacetylenes isolated from carrot (Daucus carota) extracts by negative ion tandem mass spectrometry.

    PubMed

    Rai, Dilip K; Brunton, Nigel P; Koidis, Anastasios; Rawson, Ashish; McLoughlin, Padraig; Griffiths, William J

    2011-08-15

    The potential use of negative electrospray ionisation mass spectrometry (ESI-MS) in the characterisation of the three polyacetylenes common in carrots (Daucus carota) has been assessed. The MS scans have demonstrated that the polyacetylenes undergo a modest degree of in-source decomposition in the negative ionisation mode while the positive ionisation mode has shown predominantly sodiated ions and no [M+H](+) ions. Tandem mass spectrometric (MS/MS) studies have shown that the polyacetylenes follow two distinct fragmentation pathways: one that involves cleavage of the C3-C4 bond and the other with cleavage of the C7-C8 bond. The cleavage of the C7-C8 bond generated product ions m/z 105.0 for falcarinol, m/z 105/107.0 for falcarindiol, m/z 147.0/149.1 for falcarindiol-3-acetate. In addition to these product ions, the transitions m/z 243.2 → 187.1 (falcarinol), m/z 259.2 → 203.1 (falcarindiol), m/z 301.2 → 255.2/203.1 (falcarindiol-3-acetate), mostly from the C3-C4 bond cleavage, can form the basis of multiple reaction monitoring (MRM)-quantitative methods which are poorly represented in the literature. The 'MS(3) ' experimental data confirmed a less pronounced homolytic cleavage site between the C11-C12 bond in the falcarinol-type polacetylenes. The optimised liquid chromatography (LC)/MS conditions have achieved a baseline chromatographic separation of the three polyacetylenes investigated within 40 min total run-time.

  4. Optics of the NIFS negative ion source test stand by infrared calorimetry and numerical modelling

    SciTech Connect

    Veltri, P. Antoni, V.; Agostinetti, P.; Brombin, M.; Sartori, E.; Serianni, G.; Ikeda, K.; Kisaki, M.; Nakano, H.; Takeiri, Y.; Tsumori, K.

    2016-02-15

    At National Institute for Fusion Science (NIFS), a multi-ampere negative ion source is used to support the R&D on H{sup −} production, extraction, and acceleration. In this contribution, we study the characteristics of the acceleration system of this source, in order to characterize the beam optics at different operational conditions. A dedicated experimental campaign was carried out at NIFS, using as main diagnostic the infra-red imaging of the beam profiles. The experimental measurements are also compared with 3D numerical simulations, in order to validate the codes and to assess their degree of reliability. The simulations show a satisfactory agreement with the experimental results.

  5. Improvement of accelerator of negative ion source on the Large Helical Device

    SciTech Connect

    Kisaki, M. Ikeda, K.; Osakabe, M.; Tsumori, K.; Nakano, H.; Nagaoka, K.; Kaneko, O.; Takeiri, Y.; Geng, S.

    2016-02-15

    To improve the performance of negative-ion based neutral beam injection on the Large Helical Device, the accelerator was modified on the basis of numerical investigations. A field limiting ring was installed on the upper side of a grounded grid (GG) support and a multi-slot GG was adopted instead of a multi-aperture GG. As a result, the voltage holding capability is improved and the heat load on the GG decreases by 40%. In addition, the arc efficiency is improved significantly only by replacing the GG.

  6. Negative ion mass spectrometry and the detection of carbonyls and HCN from clover

    NASA Astrophysics Data System (ADS)

    Custer, Thomas G.; Kato, Shuji; Fall, Ray; Bierbaum, Veronica M.

    2000-12-01

    We have demonstrated that negative ion-chemical ionization mass spectrometry (NI-CIMS) can be used to distinguish several isomeric volatile organic compounds (VOCs) that are emitted from wounded plants. Reaction chemistry with HO-, hydrogen/deuterium exchange patterns, and collision-induced dissociation spectra allow identification of the isomers. Laboratory studies of emissions from wounded clover using NI-CIMS show several previously detected VOCs, but also clearly demonstrate the emission of HCN. This compound is presumably formed by the decomposition of cyanogenic glycosides which also form aldehyde and ketone byproducts. These results suggest that NI-CIMS may be a valuable tool for investigating VOCs and HCN release from vegetation.

  7. Studies of Compound States of Atomic Negative Ions Using Laser Beams

    DTIC Science & Technology

    1984-07-01

    Miller, J. Inorg. NucL Chem. 7, 351 (1958). 13. D. R. Bates, Proc. Roy . Irish Acad. A 51, 151 (1947). 14. H.S.W. Massey, NEGATIVE IONS (3rd Ed...Beam are Collinear. RESUME NAME: Thomas Jay Kvale TITLE: Postdoctoral Fellow in Physics EDUCATION: A.B. Gustavus Adolphus College (Cum Laude), 1975 M.S...Photography ___ __’ii Thomas Jay Kvale REFEREED PAPERS 1. J. E. Aldag, J. L. Peacher, P. J. Martin, V. C. Sutcliffe, J. George, E. Redd, T. J. Kvale, D

  8. Enhanced negative ion formation via electron attachment to electronically-excited states

    SciTech Connect

    Pinnaduwage, L.A. |

    1995-12-31

    Recent basic studies on electron attachment to laser-excited molecules show that electron attachment to electronically-excited states can have orders of magnitude larger cross sections compared to the respective ground electronic states. Even though systematic studies have not been conducted, there are indications that electronically-excited states may play a significant role in negative ion formation in gas discharges. The high-lying Rydberg states could be of particular significance since, (i) their production efficiencies are high, and (ii) they have comparatively long lifetimes. Such states could be populated in discharge sources via direct electron impact or via excitation transfer from metastable states of inert gases.

  9. Off-normal and failure condition analysis of the MITICA negative-ion accelerator

    SciTech Connect

    Chitarin, Giuseppe Aprile, Daniele; Agostinetti, Piero; Marconato, Nicolò; Marcuzzi, Diego; Serianni, Gianluigi; Veltri, Pierluigi; Zaccaria, Pierluigi

    2016-02-15

    The negative-ion accelerator for the MITICA neutral beam injector has been designed and optimized in order to reduce the thermo-mechanical stresses in all components below limits compatible with the required fatigue life. However, deviation from the expected beam performances can be caused by “off-normal” operating conditions of the accelerator. The purpose of the present work is to identify and analyse all the “off-normal” operating conditions, which could possibly become critical in terms of thermo-mechanical stresses or of degradation of the optical performances of the beam.

  10. Off-normal and failure condition analysis of the MITICA negative-ion accelerator

    NASA Astrophysics Data System (ADS)

    Chitarin, Giuseppe; Agostinetti, Piero; Aprile, Daniele; Marconato, Nicolò; Marcuzzi, Diego; Serianni, Gianluigi; Veltri, Pierluigi; Zaccaria, Pierluigi

    2016-02-01

    The negative-ion accelerator for the MITICA neutral beam injector has been designed and optimized in order to reduce the thermo-mechanical stresses in all components below limits compatible with the required fatigue life. However, deviation from the expected beam performances can be caused by "off-normal" operating conditions of the accelerator. The purpose of the present work is to identify and analyse all the "off-normal" operating conditions, which could possibly become critical in terms of thermo-mechanical stresses or of degradation of the optical performances of the beam.

  11. Off-normal and failure condition analysis of the MITICA negative-ion accelerator.

    PubMed

    Chitarin, Giuseppe; Agostinetti, Piero; Aprile, Daniele; Marconato, Nicolò; Marcuzzi, Diego; Serianni, Gianluigi; Veltri, Pierluigi; Zaccaria, Pierluigi

    2016-02-01

    The negative-ion accelerator for the MITICA neutral beam injector has been designed and optimized in order to reduce the thermo-mechanical stresses in all components below limits compatible with the required fatigue life. However, deviation from the expected beam performances can be caused by "off-normal" operating conditions of the accelerator. The purpose of the present work is to identify and analyse all the "off-normal" operating conditions, which could possibly become critical in terms of thermo-mechanical stresses or of degradation of the optical performances of the beam.

  12. Core-level positive-ion and negative-ion fragmentation of gaseous and condensed HCCl3 using synchrotron radiation

    NASA Astrophysics Data System (ADS)

    Lu, K. T.; Chen, J. M.; Lee, J. M.; Haw, S. C.; Liang, Y. C.; Deng, M. J.

    2011-07-01

    We investigated the dissociation dynamics of positive-ion and negative-ion fragments of gaseous and condensed HCCl3 following photoexcitation of Cl 2p electrons to various resonances. Based on ab initio calculations at levels HF/cc-pVTZ and QCISD/6-311G*, the first doublet structures in Cl L-edge x-ray absorption spectrum of HCCl3 are assigned to transitions from the Cl (2P3/2,1/2) initial states to the 10a1* orbitals. The Cl 2p → 10a1* excitation of HCCl3 induces a significant enhancement of the Cl+ desorption yield in the condensed phase and a small increase in the HCCl+ yield in the gaseous phase. Based on the resonant photoemission of condensed HCCl3, excitations of Cl 2p electrons to valence orbitals decay predominantly via spectator Auger transitions. The kinetic energy distributions of Cl+ ion via the Cl 2p → 10a1* excitation are shifted to higher energy ˜0.2 eV and ˜0.1 eV relative to those via the Cl 2p → 10e* excitation and Cl 2p → shape resonance excitation, respectively. The enhancement of the yields of ionic fragments at specific core-excited resonance states is assisted by a strongly repulsive surface that is directly related to the spectator electrons localized in the antibonding orbitals. The Cl- anion is significantly reinforced in the vicinity of Cl 2p ionization threshold of gaseous HCCl3, mediated by photoelectron recapture through post-collision interaction.

  13. Towards 20 A negative hydrogen ion beams for up to 1 h: Achievements of the ELISE test facility (invited)

    SciTech Connect

    Fantz, U. Heinemann, B.; Wünderlich, D.; Riedl, R.; Kraus, W.; Nocentini, R.; Bonomo, F.

    2016-02-15

    The large-scale RF-driven ion source of the test facility extraction from a large ion source experiment is aimed to deliver an accelerated ion current of 20 A D{sup −} (23 A H{sup −}) with an extracted electron-to-ion ratio below one for up to 1 h. Since the first plasma pulses for 20 s in volume operation in early 2013, followed by caesiation of the ion source, substantial progress has been achieved in extending the pulse length and the RF power. The record pulses in hydrogen are stable 400 s pulses with an extracted ion current of 18.3 A at 180 kW total RF power and 9.3 A at 80 kW stable for 1 h. For deuterium pulse, length and RF power are limited by the amount of co-extracted electrons.

  14. Spatial and temporal evolution of negative ions in a pulsed inductively coupled hydrogen plasma source across a magnetic filter

    NASA Astrophysics Data System (ADS)

    Nulty, Stuart; Corr, Cormac

    2015-09-01

    Low-temperature electronegative plasmas have important applications in high-energy sources for fusion energy, plasma thrusters and materials processing. Neutral beam injection systems and space thruster technology such as the PEGASUS propulsion system rely on efficiently producing extractable negative ions. In this work we investigate the production of hydrogen negative ions in a pulsed inductively coupled plasma across a magnetic filter. The electron energy distribution function, plasma density and electron temperature are determined using an RF compensated Langmuir probe, and time-resolved laser photo-detachment is used to measure the negative ion fraction. The spatial and temporal evolution of these plasma parameters within the plasma source will be presented. Using a pulsed plasma and a magnetic filter, the electron temperature can be efficiently controlled and a higher density of negative ions compared to electrons can be obtained at certain locations within the source.

  15. CHLORIDEDETERMINATION IN HIGH IONIC STRENGTH SOLUTION OF AMMONIUM ACETATE USING NEGATIVE ION ELECTRON SPRAY IONIZATION (HPLC/MS)

    EPA Science Inventory

    A precise ion chromatography method has been developed for the determination of chloride in high ionic strength ammonium acetate solutions (10-5 M-5 M) using sodium carbonate/sodium bicarbonate as eluent. Negative ion electrospray ionization (ESI) mass spectrometry was used for q...

  16. The effect of exposure to negative air ions on the recovery of physiological responses after moderate endurance exercise

    NASA Astrophysics Data System (ADS)

    Ryushi, T.; Kita, Ichirou; Sakurai, Tomonobu; Yasumatsu, Mikinobu; Isokawa, Masanori; Aihara, Yasutugu; Hama, Kotaro

    This study examined the effects of negative air ion exposure on the human cardiovascular and endocrine systems during rest and during the recovery period following moderate endurance exercise. Ten healthy adult men were studied in the presence (8,000-10,000 cm-3) or absence (200-400 cm-3) of negative air ions (25° C, 50% humidity) after 1 h of exercise. The level of exercise was adjusted to represent a 50-60% load compared with the subjects' maximal oxygen uptake, which was determined using a bicycle ergometer in an unmodified environment (22-23° C, 30-35% humidity, 200-400 negative air ions.cm-3). The diastolic blood pressure (DBP) values during the recovery period were significantly lower in the presence of negative ions than in their absence. The plasma levels of serotonin (5-HT) and dopamine (DA) were significantly lower in the presence of negative ions than in their absence. These results demonstrated that exposure to negative air ions produced a slow recovery of DBP and decreases in the levels of 5-HT and DA in the recovery period after moderate endurance exercise. 5-HT is thought to have contributed to the slow recovery of DBP.

  17. Particle model of full-size ITER-relevant negative ion source

    SciTech Connect

    Taccogna, F. Minelli, P.; Ippolito, N.

    2016-02-15

    This work represents the first attempt to model the full-size ITER-relevant negative ion source including the expansion, extraction, and part of the acceleration regions keeping the mesh size fine enough to resolve every single aperture. The model consists of a 2.5D particle-in-cell Monte Carlo collision representation of the plane perpendicular to the filter field lines. Magnetic filter and electron deflection field have been included and a negative ion current density of j{sub H{sup −}} = 660 A/m{sup 2} from the plasma grid (PG) is used as parameter for the neutral conversion. The driver is not yet included and a fixed ambipolar flux is emitted from the driver exit plane. Results show the strong asymmetry along the PG driven by the electron Hall (E × B and diamagnetic) drift perpendicular to the filter field. Such asymmetry creates an important dis-homogeneity in the electron current extracted from the different apertures. A steady state is not yet reached after 15 μs.

  18. Differential negative air ion effects on learning disabled and normal-achieving children

    NASA Astrophysics Data System (ADS)

    Morton, L. L.; Kershner, J. R.

    1990-03-01

    Forty normal-achieving and 33 learning disabled (LD) children were assigned randomly to either a negative ion or placebo test condition. On a dichotic listening task using consonant-vowel (CV) combinations, both groups showed an ioninduced increase in the normal right ear advantage (REA). However, the mechanisms for this effect were different for each group. The LDs showed the effect at the right ear/left hemisphere (enhancement). The normal achievers showed the effect at the left ear/right hemisphere (inhibition). The results are consistent with an activation-inhibition model of cerebral function and suggest a functional relationship between arousal, interhemispheric activation-inhibition, and learning disabilities. The LDs may have an interhemispheric dysfunction. Both groups showed superior right ear report and the normal achiever showed overall superiority. Normal achievers showed higher consonant intrusion scores, probably due to a greater cognitive capacity. Age was a significant covariate reflecting developmental capacity changes. Negative air ions are seen to be a tool with potential theoretical and remedial applications.

  19. Vibrational excitation and negative-ion production in magnetic multicusp hydrogen discharges

    NASA Astrophysics Data System (ADS)

    Gorse, C.; Capitelli, M.; Bretagne, J.; Bacal, M.

    1985-02-01

    A self-consistent approach based on the simultaneous solution of the vibrational master equation, the Boltzmann equation and the plasma chemistry describing the dissociation process has been used to obtain: (a) vibrational distributions, (b) electron energy distribution functions, (c) electron number densities ( n c) and electron temperatures ( T c), (d) degree of dissociation, and (e) the concentration of negative ions ( NH -) in magnetic multicusp H 2 plasmas. The approach is an extension of a model presented earlier. The main differences come from the insertion of a source term (an electron beam) instead of the electric field in the Boltzmann equation and from the inclusion of new important processes in the vibrational master equation. The results which are in satisfactory agreement with the experimental vibrational distributions obtained by CARS spectroscopy, with the n c, T c values obtained by probe techniques and with the production of negative ions obtained by a photodetachment technique, show the importance of hydrogen atoms and of wall deactivation in affecting the properties of multicusp H 2 plasmas.

  20. Stable excited Au= and Pt= negative ions: A Regge-pole prediction

    NASA Astrophysics Data System (ADS)

    Felfli, Z.; Msezane, A. Z.; Sokolovski, D.

    2010-03-01

    Electron elastic scattering from Au and Pt atoms is investigated in the energy region E < 4.0 eV in search of the possibility of forming and observing stable excited Au= and Pt= negative ions as Regge resonances. Total elastic cross sections (TCSs) and differential cross sections (DCSs) in both impact energy and scattering angle for the excited Au and Pt atoms are calculated. The investigation uses the recent Regge-pole methodology [1] wherein is embedded the vital electron-electron correlations together with a Thomas-Fermi type potential that incorporates the crucial core-polarization interaction, essential for the existence and stability of most negative ions. From the characteristic dramatically sharp resonances in the elastic total and Mulholland partial cross sections we identify excited Au= and Pt= anions and extract their binding energies (BEs). Ramsauer-Townsend minima and shape resonances are also determined. The DCSs also yield the BEs of the Au= and Pt= anions [2]. The TCSs for the excited and ground Au= and Pt= anions are contrasted as well; they provide a clue to the significant catalytic properties of their nanoparticles. [1] D. Sokolovski et al, Phys. Rev. A 76, 012705 (2007); [2] Z. Felfli et al, NIMB, At Press (2010). Supported by U.S. DOE, AFOSR and CAU CFNM, NSF-CREST Program

  1. A Micromegas-based Directional Dark Matter Detector for Use with Negative Ion Gases

    NASA Astrophysics Data System (ADS)

    Nicoloff, Catherine; Battat, James

    2017-01-01

    Directional dark matter detectors seek to measure the direction of WIMP-induced nuclear recoils. The angular distribution of these recoils provides a unique signature that is not mimicked by any known background population. Low-pressure gas time projection chambers (TPCs) have a long and successful history in directional dark matter searches. The benefit of the low-pressure gas target is that nuclear recoils from dark matter extend long enough to be reliably reconstructed. For the last decade, the DRIFT collaboration has employed a MWPC-based negative-ion TPC for directional dark matter detection. DRIFT recently published the leading limit from a directional detector on the spin-dependent WIMP-proton interaction (1.1 pb at a WIMP mass of 100 GeV/c2) . Although the effective spatial granularity along the drift direction is 60 um, the MWPC wire spacing of 2 mm limits DRIFT's track reconstruction. DRIFT is now exploring TPC readouts that offer higher spatial resolution. Here, we report on one such effort that uses a Micromegas for gas amplification with orthogonal strips for charge signal readout. The detector can be used with both electron drift and negative ion gases. We will describe the detector design and present preliminary commissioning data taken in a surface laboratory. Research Corporation, NSF, and MA Space Grant.

  2. Electron cyclotron resonance heating by magnetic filter field in a negative hydrogen ion source

    SciTech Connect

    Kim, June Young Cho, Won-Hwi; Dang, Jeong-Jeung; Chung, Kyoung-Jae Hwang, Y. S.

    2016-02-15

    The influence of magnetic filter field on plasma properties in the heating region has been investigated in a planar-type inductively coupled radio-frequency (RF) H{sup −} ion source. Besides filtering high energy electrons near the extraction region, the magnetic filter field is clearly observed to increase the electron temperature in the heating region at low pressure discharge. With increasing the operating pressure, enhancement of electron temperature in the heating region is reduced. The possibility of electron cyclotron resonance (ECR) heating in the heating region due to stray magnetic field generated by a filter magnet located at the extraction region is examined. It is found that ECR heating by RF wave field in the discharge region, where the strength of an axial magnetic field is approximately ∼4.8 G, can effectively heat low energy electrons. Depletion of low energy electrons in the electron energy distribution function measured at the heating region supports the occurrence of ECR heating. The present study suggests that addition of axial magnetic field as small as several G by an external electromagnet or permanent magnets can greatly increase the generation of highly ro-vibrationally excited hydrogen molecules in the heating region, thus improving the performance of H{sup −} ion generation in volume-produced negative hydrogen ion sources.

  3. Ionization Efficiency of Doubly Charged Ions Formed from Polyprotic Acids in Electrospray Negative Mode

    NASA Astrophysics Data System (ADS)

    Liigand, Piia; Kaupmees, Karl; Kruve, Anneli

    2016-07-01

    The ability of polyprotic acids to give doubly charged ions in negative mode electrospray was studied and related to physicochemical properties of the acids via linear discriminant analysis (LDA). It was discovered that the compound has to be strongly acidic (low p K a1 and p K a2) and to have high hydrophobicity (log P ow) to become multiply charged. Ability to give multiply charged ions in ESI/MS cannot be directly predicted from the solution phase acidities. Therefore, for the first time, a quantitative model to predict the charge state of the analyte in ESI/MS is proposed and validated for small anions. Also, a model to predict ionization efficiencies of these analytes was developed. Results indicate that acidity of the analyte, its octanol-water partition coefficient, and charge delocalization are important factors that influence ionization efficiencies as well as charge states of the analytes. The pH of the solvent was also found to be an important factor influencing the ionization efficiency of doubly charged ions.

  4. Quantification Of Cesium In Negative Hydrogen Ion Sources By Laser Absorption Spectroscopy

    SciTech Connect

    Fantz, U.; Wimmer, Ch.

    2011-09-26

    The use of cesium in negative hydrogen ion sources and the resulting cesium dynamics caused by the evaporation and redistribution in the vacuum and plasma phase makes a reliable and on-line monitoring of the cesium amount in the source highly desirable. For that purpose, a robust and compact laser absorption setup suitable for the ion source environment has been developed utilizing the Cs D{sub 2} resonance line at 852.1 nm. First measurements are taken in a small laboratory plasma chamber with cesium evaporation. A detection limit of {approx_equal}5x10{sup 13} m{sup -3} at a typical path length of 15 cm has been obtained with a dynamic range of more than three orders of magnitude, limited by line saturation at high densities. For on-line monitoring an automatic data analysis is established achieving a temporal resolution of 100 ms. The setup has then been applied to the ITER prototype ion sources developed at IPP. It is been shown that the method is well suited for routine measurements revealing a new insight into the cesium dynamics during source operation and cesium conditioning.

  5. Power supply circuit for an ion engine sequentially operated power inverters

    NASA Technical Reports Server (NTRS)

    Cardwell, Jr., Gilbert I. (Inventor)

    2000-01-01

    A power supply circuit for an ion engine suitable for a spacecraft has a voltage bus having input line and a return line. The power supply circuit includes a pulse width modulation circuit. A plurality of bridge inverter circuits is coupled to the bus and the pulse width modulation circuit. The pulse width modulation circuit generates operating signals having a variable duty cycle. Each bridge inverter has a primary winding and a secondary winding. Each secondary winding is coupled to a rectifier bridge. Each secondary winding is coupled in series with another of the plurality of rectifier bridges.

  6. Negative Ion MALDI Mass Spectrometry of Polyoxometalates (POMs): Mechanism of Singly Charged Anion Formation and Chemical Properties Evaluation

    NASA Astrophysics Data System (ADS)

    Boulicault, Jean E.; Alves, Sandra; Cole, Richard B.

    2016-08-01

    MALDI-MS has been developed for the negative ion mode analysis of polyoxometalates (POMs). Matrix optimization was performed using a variety of matrix compounds. A first group of matrixes offers MALDI mass spectra containing abundant intact singly charged anionic adduct ions, as well as abundant in-source fragmentations at elevated laser powers. A relative ranking of the ability to induce POM fragmentation is found to be: DAN > CHCA > CNA > DIT> HABA > DCTB > IAA. Matrixes of a second group provide poorer quality MALDI mass spectra without observable fragments. Sample preparation, including the testing of salt additives, was performed to optimize signals for a model POM, POMc12, the core structure of which bears four negative charges. The matrix 9-cyanoanthracene (CNA) provided the best signals corresponding to singly charged intact POMc12 anions. Decompositions of these intact anionic species were examined in detail, and it was concluded that hydrogen radical-induced mechanisms were not prevalent, but rather that the observed prompt fragments originate from transferred energy derived from initial electronic excitation of the CNA matrix. Moreover, in obtained MALDI mass spectra, clear evidence of electron transfer to analyte POM species was found: a manifestation of the POMs ability to readily capture electrons. The affinity of polyanionic POMc12 toward a variety of cations was evaluated and the following affinity ranking was established: Fe3+ > Al3+ > Li+ > Ga3+ > Co2+ > Cr3+ > Cu2+ > [Mn2+, Mg2+] > [Na+, K+]. Thus, from the available cationic species, specific adducts are preferentially formed, and evidence is given that these higher affinity POM complexes are formed in the gas phase during the early stages of plume expansion.

  7. VUV emission spectroscopy diagnostics of a 14 GHz ECR negative hydrogen ion source

    SciTech Connect

    Tamura, R. Ichikawa, T.; Kasuya, T.; Wada, M.; Nishiura, M.; Shimozuma, T.

    2015-04-08

    Vacuum Ultra Violet(VUV) emission from a 4 cm diameter 2 cm long compact ion source excited by 14 GHz microwave has been investigated. Intensity ratio of band spectrum emission near Ly-α to Ly-α line spectrum is determined from the measured spectrum. which shows preferential excitation of molecules near the entrance of microwave input power. The ratio does not depend strongly upon pressure nor the input microwave power when the intensity is integrated over the volume of the plasma. The spatial distribution of the spectrum intensity ratio exhibits concentrations near microwave inlet and the opposite side where the microwave matching structure is located. The ratio at these peripheral regions is about two times as high as that of the central region. The ratio increased in proportion to the ion source pressure up to about 3.0 Pa, indicating efficient production of high energy electrons by ECR up to this pressure.

  8. Lifetime of negative molecular ions of tetracene and pentacene with respect to the autodetachment of an electron

    NASA Astrophysics Data System (ADS)

    Khatymov, R. V.; Tuktarov, R. F.; Muftakhov, M. V.

    2011-06-01

    The processes of nondissociative resonant attachment and autodetachment of electrons in a number of poly-cyclic aromatic hydrocarbon molecules have been investigated by mass spectrometry. Long-lived negative molecular ions of phenanthrene and triphenylene have not been observed. Such ions have been detected for anthracene, pyrene, and benzo[e]pyrene capturing thermal electrons. Negative molecular ions of tetracene and pentacene have also been observed up to 2.5-3 eV. The lifetimes of these ions with respect to the auto-detachment of an electron have been measured throughout the energy range where they are observed. This lifetime for tetracene and pentacene is more than 10 ms, which is two or three orders of magnitude larger than that for remaining compounds. Correlation between the lifetime of ions and the electron affinity of the molecules has been revealed.

  9. High power targets for production of intense radioactive ion beams

    SciTech Connect

    Talbert, W. L.; Drake, D. M.; Wilson, M. T.; Walker, J. J.; Lenz, J. W.

    1999-04-26

    Issues are discussed in producing intense Radioactive Ion Beams (RIB) using the Isotope Separator On-Line (ISOL) approach, based on the use of thick targets employed at existing facilities. Some new physics studies may possibly be addressed by improving the performance of these existing targets through improvements in release and effusion properties to optimize the RIB yields. It is, however, acknowledged that many desired physics objectives using RIB can be met only by employing production beams of energetic light ions or protons with currents up to 100 {mu}A. Development of targets that use such intense production beams needs to address the requirement to control operational temperatures derived from internal production beam interactions with the target materials. In addition, issues arise for target materials in terms of their thermal characteristics, such as thermal conductivity and thermo-mechanical properties. A target concept is described for an in-beam test of a prototype target for actual thermal behavior under RIB production conditions. For such a test, a high-power test facility is needed; fortunately, the prototypical production beam currents required exist at the TRIUMF accelerator facility. An experimental proposal has been approved for such a test.

  10. A high power ion thruster for deep space missions

    NASA Astrophysics Data System (ADS)

    Polk, James E.; Goebel, Dan M.; Snyder, John S.; Schneider, Analyn C.; Johnson, Lee K.; Sengupta, Anita

    2012-07-01

    The Nuclear Electric Xenon Ion System ion thruster was developed for potential outer planet robotic missions using nuclear electric propulsion (NEP). This engine was designed to operate at power levels ranging from 13 to 28 kW at specific impulses of 6000-8500 s and for burn times of up to 10 years. State-of-the-art performance and life assessment tools were used to design the thruster, which featured 57-cm-diameter carbon-carbon composite grids operating at voltages of 3.5-6.5 kV. Preliminary validation of the thruster performance was accomplished with a laboratory model thruster, while in parallel, a flight-like development model (DM) thruster was completed and two DM thrusters fabricated. The first thruster completed full performance testing and a 2000-h wear test. The second successfully completed vibration tests at the full protoflight levels defined for this NEP program and then passed performance validation testing. The thruster design, performance, and the experimental validation of the design tools are discussed in this paper.

  11. Stopping-Power and Range Tables for Electrons, Protons, and Helium Ions

    National Institute of Standards and Technology Data Gateway

    SRD 124 Stopping-Power and Range Tables for Electrons, Protons, and Helium Ions (Web, free access)   The databases ESTAR, PSTAR, and ASTAR calculate stopping-power and range tables for electrons, protons, or helium ions. Stopping-power and range tables can be calculated for electrons in any user-specified material and for protons and helium ions in 74 materials.

  12. Tomographic reconstruction of the beam emissivity profile in the negative ion source NIO1

    NASA Astrophysics Data System (ADS)

    Fonnesu, N.; Agostini, M.; Pasqualotto, R.; Serianni, G.; Veltri, P.

    2016-12-01

    A versatile negative hydrogen ion source named NIO1 of a moderate size (130 mA total extracted H- current, 9 apertures, 60 kV total acceleration) has been developed and installed at Consorzio RFX. It will allow great experimental flexibility, very beneficial for studying several important issues related to beam extraction, optics and performance optimization, in view of SPIDER and MITICA, the two full-scale experiments for the ITER neutral beam injector under construction at RFX. The main target of emission tomography applied to an ion beam is the reconstruction of the emissivity profile, from which the ion density distribution can be obtained. The measurement of the beam density profile and of its uniformity throughout the pulse duration with a non-invasive diagnostic, such as tomography, would represent an effective method for monitoring the ion source operation and for malfunction detection. The application of this diagnostic to the NIO1 beam will represent the experimental verification of the possibility to reconstruct a multi-beamlet profile, in the interest of the next tomography systems for SPIDER and MITICA. In this paper, a feasibility study of the tomographic diagnostic for NIO1 is presented. A tomography code based on algebraic reconstruction techniques has been developed for this purpose and the transport of the nine H- beamlets is simulated with a Monte Carlo particle tracking code from the ion source to the tomography plane, where the beam emissivity profile to be reconstructed is calculated. The reference emissivity profile is reconstructed by the tomography code considering different possible layouts of the detection system, in order to find the best compromise between the quality of reconstructions and the complexity of the diagnostic. Results show that a tomography system based on six linear CCD cameras should be capable of reconstructing the NIO1 emissivity profile with an rms error lower than 10%. How instrumental noise in the integrated

  13. Overview of the negative ion based neutral beam injectors for ITER

    SciTech Connect

    Schunke, B. Boilson, D.; Chareyre, J.; Choi, C.-H.; Decamps, H.; El-Ouazzani, A.; Geli, F.; Graceffa, J.; Hemsworth, R.; Kushwah, M.; Roux, K.; Shah, D.; Singh, M.; Svensson, L.; Urbani, M.

    2016-02-15

    The ITER baseline foresees 2 Heating Neutral Beams (HNB’s) based on 1 MeV 40 A D{sup −} negative ion accelerators, each capable of delivering 16.7 MW of deuterium atoms to the DT plasma, with an optional 3rd HNB injector foreseen as a possible upgrade. In addition, a dedicated diagnostic neutral beam will be injecting ≈22 A of H{sup 0} at 100 keV as the probe beam for charge exchange recombination spectroscopy. The integration of the injectors into the ITER plant is nearly finished necessitating only refinements. A large number of components have passed the final design stage, manufacturing has started, and the essential test beds—for the prototype route chosen—will soon be ready to start.

  14. Metal hydrides used as negative electrode materials for Li-ion batteries

    NASA Astrophysics Data System (ADS)

    Sartori, Sabrina; Cuevas, Fermin; Latroche, Michel

    2016-02-01

    Energy is a key issue for future generation. Researches are conducted worldwide to develop new efficient means for energy conversion and storage. Electrochemical storage is foreseen as an efficient way to handle intermittent renewable energy production. The most advanced batteries are nowadays based on lithium-ion technology though their specific capacities should be significantly increased to bring solution to mass storage. Conversion reactions are one way to step forward larger capacities at the anode. We here review the possibility to use metallic or complex hydrides as negative electrode using conversion reaction of hydride with lithium. Moreover, promising alloying of lithium with the metallic species might provide additional reversible capacities. Both binary and ternary systems are reviewed and results are compared in the frame of the electrochemical application.

  15. Numerical analysis of atomic density distribution in arc driven negative ion sources

    SciTech Connect

    Yamamoto, T. Shibata, T.; Hatayama, A.; Kashiwagi, M.; Hanada, M.; Sawada, K.

    2014-02-15

    The purpose of this study is to calculate atomic (H{sup 0}) density distribution in JAEA 10 ampere negative ion source. A collisional radiative model is developed for the calculation of the H{sup 0} density distribution. The non-equilibrium feature of the electron energy distribution function (EEDF), which mainly determines the H{sup 0} production rate, is included by substituting the EEDF calculated from 3D electron transport analysis. In this paper, the H{sup 0} production rate, the ionization rate, and the density distribution in the source chamber are calculated. In the region where high energy electrons exist, the H{sup 0} production and the ionization are enhanced. The calculated H{sup 0} density distribution without the effect of the H{sup 0} transport is relatively small in the upper region. In the next step, the effect should be taken into account to obtain more realistic H{sup 0} distribution.

  16. Experiments on a reflex-type sheet plasma negative-ion source

    SciTech Connect

    Ando, A.; Kuroda, T.; Oka, Y.; Kaneko, O.; Karita, A.; Kawamoto, T. )

    1990-01-01

    Negative hydrogen ions are extracted from a reflex-type sheet plasma. Electron density and temperature profiles are measured with changing the filling gas pressure, and they are optimized to the H{sup {minus}} production at the optimum gas pressure. The optimum gas pressure is 5 mTorr for the discharge current {ital I}{sub {ital d}} =2 A. As the discharge current {ital I}{sub {ital d}} increases, H{sup {minus}} current increases linearly corresponding to the density increase in the center region, but saturates above {ital I}{sub {ital d}} =40 A. The maximum extracted H{sup {minus}} current density of 4 mA/cm{sup 2} is obtained at {ital I}{sub {ital d}}=100 A.

  17. Interpreting electron transmission spectroscopy and negative ion mass spectrometry data using a spherical potential well model

    SciTech Connect

    Asfandiarov, N. L. Nafikova, E. P.; Pshenichnyuk, S. A.

    2007-03-15

    Experimental data obtained using electron transmission spectroscopy and negative ion mass spectrometry based on resonance electron capture are interpreted within the framework of a spherical potential well model in application to a series of chloro-and bromoalkane molecules. Allowance for the scattering of a single partial p-wave of the incoming electron makes possible (i) reproduction of the ratio of a resonance peak width to the electron energy observed in the electron transmission spectra and (ii) establishment of a relation between the total cross section of electron scattering on a molecule and the dissociative electron attachment cross section. The proposed model offers a radical simplification of the approach developed previously based on the Fashbach-Fano resonance theory.

  18. Photoelectron spectroscopic study of the negative ions of 4-thiouracil and 2,4-dithiouracil

    NASA Astrophysics Data System (ADS)

    Li, Xiang; Chen, Jing; Bowen, Kit H.

    2011-02-01

    We report the photoelectron spectra of the negative ions of 4-thiouracil (4-TU)- and 2,4-dithiouracil (2,4-DTU)-. Both of these spectra are indicative of valence anions, and they are each dominated by a single broad band with vertical detachment energies of 1.05 and 1.4 eV, respectively. Complementary calculations by Dolgounitcheva, Zakrzewski, and Ortiz (see companion paper) are in accord with our experimental results and conclude that the (4-TU)- and (2,4-DTU)- anions, reported herein, are valence anions of canonical 4-thiouracil and canonical dithiouracil. Comparisons among the anions and corresponding neutrals of 4-thiouracil, 2,4-dithiouracil, 5-chlorouracil, 5-fluorouracil, and uracil itself show that both sulfur and halogen modifications of uracil give rise to significant changes in the electronic structure. The electron affinities of the first four are all substantially larger than that of the canonical uracil.

  19. Total electron scattering cross-sections and negative ion states of halogenated methanes

    SciTech Connect

    Underwood-Lemons, T.; Winkler, D.C.; Moore, J.H.; Tossell, J.A.

    1993-12-01

    The interaction of low energy electrons with halogenated methanes plays an important role in both their atmospheric and plasma processing chemistry. In this work, the total electron scattering cross-sections of mixed fluorohalomethanes (CF{sub n}X{sub 4-n}) were measured for incident electrons in the energy range of 0.2-12 eV using electron transmission spectroscopy. Resonances in the scattering cross-sections may be interpreted as the capture of low energy electrons into unoccupied molecular orbitals. To aid in the assignments of the resulting negative ion states, the authors performed quantum mechanical calculations of the electron attachment energies and measured the dissociative attachment cross-sections. The effect of halogen substitution on the orbitals participating in electron capture are examined.

  20. 21 CFR 878.4683 - Non-Powered suction apparatus device intended for negative pressure wound therapy.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Non-Powered suction apparatus device intended for... Surgical Devices § 878.4683 Non-Powered suction apparatus device intended for negative pressure wound therapy. (a) Identification. A non-powered suction apparatus device intended for negative pressure...

  1. Negative ion beam characterisation in BATMAN by mini-STRIKE: Improved design and new measurements

    NASA Astrophysics Data System (ADS)

    Serianni, G.; Bonomo, F.; Brombin, M.; Cervaro, V.; Chitarin, G.; Cristofaro, S.; Delogu, R.; De Muri, M.; Fasolo, D.; Fonnesu, N.; Franchin, L.; Franzen, P.; Ghiraldelli, R.; Molon, F.; Muraro, A.; Pasqualotto, R.; Ruf, B.; Schiesko, L.; Tollin, M.; Veltri, P.

    2015-04-01

    The ITER project requires additional heating provided by two injectors of neutral beams resulting from the neutralisation of accelerated negative ions. To study and optimise negative ion production, the SPIDER test facility (particle energy 100keV; beam current 50A) is under construction in Padova, with the aim of testing beam characteristics and to verify the source proper operation. The SPIDER beam will be characterised by the instrumented calorimeter STRIKE, whose main components are one-directional carbon fibre carbon composite tiles. Some prototype tiles have been employed in 2012 as a small-scale version (mini-STRIKE) of the entire system to investigate the features of the beam from BATMAN at IPP-Garching. As the BATMAN beamlets are superposed at the measurement position, about 1m from the grounded grid, an actively cooled copper mask is located in front of the tiles; holes in the mask create an artificial beamlet structure. Recently the mini-STRIKE has been updated, taking into account the results obtained in the first campaign. In particular the spatial resolution of the system has been improved by increasing the number of the copper mask holes. Moreover a custom measurement system has been realized for the thermocouple signals and employed in BATMAN in view of its use in SPIDER. The present contribution gives a description of the new design of the system as well as of the thermocouple measurements system and its field test. A new series of measurements has been carried out in BATMAN. The BATMAN beam characterisation in different experimental conditions is presented.

  2. Negative ion beam characterisation in BATMAN by mini-STRIKE: Improved design and new measurements

    SciTech Connect

    Serianni, G. Brombin, M.; Cervaro, V.; Chitarin, G.; Delogu, R.; Fasolo, D.; Fonnesu, N.; Franchin, L.; Ghiraldelli, R.; Molon, F.; Pasqualotto, R.; Tollin, M.; Veltri, P.; Bonomo, F.; Cristofaro, S.; De Muri, M.; Franzen, P.; Ruf, B.; Schiesko, L.; Muraro, A.

    2015-04-08

    The ITER project requires additional heating provided by two injectors of neutral beams resulting from the neutralisation of accelerated negative ions. To study and optimise negative ion production, the SPIDER test facility (particle energy 100keV; beam current 50A) is under construction in Padova, with the aim of testing beam characteristics and to verify the source proper operation. The SPIDER beam will be characterised by the instrumented calorimeter STRIKE, whose main components are one-directional carbon fibre carbon composite tiles. Some prototype tiles have been employed in 2012 as a small-scale version (mini-STRIKE) of the entire system to investigate the features of the beam from BATMAN at IPP-Garching. As the BATMAN beamlets are superposed at the measurement position, about 1m from the grounded grid, an actively cooled copper mask is located in front of the tiles; holes in the mask create an artificial beamlet structure. Recently the mini-STRIKE has been updated, taking into account the results obtained in the first campaign. In particular the spatial resolution of the system has been improved by increasing the number of the copper mask holes. Moreover a custom measurement system has been realized for the thermocouple signals and employed in BATMAN in view of its use in SPIDER. The present contribution gives a description of the new design of the system as well as of the thermocouple measurements system and its field test. A new series of measurements has been carried out in BATMAN. The BATMAN beam characterisation in different experimental conditions is presented.

  3. Spatial distribution of the plasma parameters in the RF negative ion source prototype for fusion

    SciTech Connect

    Lishev, S.; Schiesko, L.; Wünderlich, D.; Fantz, U.

    2015-04-08

    A numerical model, based on the fluid plasma theory, has been used for description of the spatial distribution of the plasma parameters (electron density and temperature, plasma potential as well as densities of the three types of positive hydrogen ions) in the IPP prototype RF negative hydrogen ion source. The model covers the driver and the expansion plasma region of the source with their actual size and accounts for the presence of the magnetic filter field with its actual value and location as well as for the bias potential applied to the plasma grid. The obtained results show that without a magnetic filter the two 2D geometries considered, respectively, with an axial symmetry and a planar one, represent accurately the complex 3D structure of the source. The 2D model with a planar symmetry (where the E×B and diamagnetic drifts could be involved in the description) has been used for analysis of the influence, via the charged-particle and electron-energy fluxes, of the magnetic filter and of the bias potential on the spatial structure of the plasma parameters in the source. Benchmarking of results from the code to experimental data shows that the model reproduces the general trend in the axial behavior of the plasma parameters in the source.

  4. Resolving a discrepancy between experimental and theoretical lifetimes in atomic negative ions

    NASA Astrophysics Data System (ADS)

    Brage, Tomas; Grumer, Jon

    2017-01-01

    A recent measurement of the lifetime of the excited 3p5 {}2{P}1/2 state in the S- negative ion, which is dominated by a forbidden magnetic dipole transition to the {}2{P}3/2 ground state, reveals a discrepancy with earlier theoretical predictions. To investigate this we have performed systematic and large-scale multiconfiguration Dirac-Hartree-Fock calculations for this system. After including a careful treatment of correlation and relativistic effects, we predict a well-converged value for this lifetime, with an uncertainty considerably less than 1%, thereby removing the apparent conflict between theory and experiment. We also show that this result corresponds to the non-relativistic limit in the LS coupling approximation for the magnetic dipole transition within this 2 P term. In addition we demonstrate the usefulness of the latter approach for 2 P transitions in O-, Se- and Te-, as well as for analogous M1 transitions within 2 D terms in Ni- and Pt- ions.

  5. Low energy electron induced reactions in fluorinated acetamide - probing negative ions and neutral stable counterparts*

    NASA Astrophysics Data System (ADS)

    Kopyra, Janina; König-Lehmann, Constanze; Illenberger, Eugen; Warneke, Jonas; Swiderek, Petra

    2016-06-01

    Electron impact to trifluoroacetamide (CF3CONH2, TFAA) in the energy range 0-12 eV leads to a variety of negative fragment ions which are formed via dissociative electron attachment (DEA). The underlying reactions range from single bond cleavages to remarkably complex reactions that lead to loss of the neutral units HF, H2O and HNCO as deduced from their directly observed ionic counterparts (M - H2O)-, (M - HF)- and (M - HNCO)-. Also formed are the pseudo-halogen ions CN- and OCN-. All these reactions proceed dominantly via a resonance located near 1 eV, i.e., electrons at subexcitation energies trigger reactions involving multiple bond cleavages. The electron induced generation of the neutral molecules HF, H2O and HNCO in condensed TFAA films is probed by temperature controlled thermal desorption spectrometry (TDS) which can be viewed as a complementary techniques to gas-phase experiments in DEA to directly probe the neutral counterparts. Contribution to the Topical Issue "Advances in Positron and Electron Scattering", edited by Paulo Limao-Vieira, Gustavo Garcia, E. Krishnakumar, James Sullivan, Hajime Tanuma and Zoran Petrovic.

  6. Cross-B convection of artificially created, negative-ion clouds and plasma depressions - Low-speed flow

    NASA Technical Reports Server (NTRS)

    Bernhardt, Paul A.

    1988-01-01

    A negative-ion, positive-ion plasma produced by the release of an electron attachment chemical into the F region becomes electrically polarized by collisions with neutrals moving across magnetic field lines. The resulting electric field causes E x B drift of the two ion species and the residual electrons. The cross-field flow of the modified ionosphere is computed using a two-dimensional numerical simulation which includes electron attachment and mutual neutralization chemistry, self-consistent electric fields, and three-species plasma transport. The velocity of the plasma is initially in the direction of the neutral wind because the negative-ion cloud is a Pedersen conductivity enhancement. As the positive and negative ions react, the Pedersen conductivity becomes depressed below the ambient value and the velocity of the plasma reverses direction. A plasma hole remains after the positive and negative ions have mutually neutralized. The E x B gradient drift instability produces irregularities on the upwind edge of the hole.

  7. A collisional radiative model for caesium and its application to an RF source for negative hydrogen ions

    SciTech Connect

    Wünderlich, D. Wimmer, C.; Friedl, R.

    2015-04-08

    A collisional radiative (CR) model for caesium atoms in low-temperature, low-pressure hydrogen-caesium plasmas is introduced. This model includes the caesium ground state, 14 excited states, the singly charged caesium ion and the negative hydrogen ion. The reaction probabilities needed as input are based on data from the literature, using some scaling and extrapolations. Additionally, new cross sections for electron collision ionization and three-body recombination have been calculated. The relevance of mutual neutralization of positive caesium ions and negative hydrogen ions is highlighted: depending on the densities of the involved particle species, this excitation channel can have a significant influence on the population densities of excited states in the caesium atom. This strong influence is successfully verified by optical emission spectroscopy measurements performed at the IPP prototype negative hydrogen ion source for ITER NBI. As a consequence, population models for caesium in electronegative low-temperature, low-pressure hydrogen-caesium plasmas need to take into account the mutual neutralization process. The present CR model is an example for such models and represents an important prerequisite for deducing the total caesium density in surface production based negative hydrogen ion sources.

  8. Non-linear photoelectron effect contributes to the formation of negative matrix ions in UV-MALDI.

    PubMed

    Alonso, E; Zenobi, R

    2016-07-20

    The mechanism of negative ion formation in matrix-assisted laser desorption/ionization (MALDI) is less well understood than that of positive ions: electron capture, disproportionation, and liberation of negatively charged sample molecules or clusters have been proposed to produce the initial anions in MALDI. Here, we propose that the non-linear photoelectric effect can explain the emission of electrons from the metallic target material. Moreover, electrons with sufficient kinetic energy (0-10 eV) could be responsible for the formation of initial negative ions. Gas-phase electron capture by neutral 2,5-dihydroxy benzoic acid (DHB) to yield M(-) is investigated on the basis of a coupled physical and chemical dynamics (CPCD) theory from the literature. A three-layer energy mass balance model is utilized to calculate the surface temperature of the matrix, which is used to determine the translational temperature, the number of desorbed matrix molecules per unit area, and the ion velocity. Calculations of dissociative attachment and autoionization rates of DHB are presented. It was found that both processes contribute significantly to the formation of [M - H](-) and [M - H2](-), although the predicted yield in the fluence range of 5-100 mJ cm(-2) is low, certainly less than that for positive ions M(+). This work represents the first proposal for a comprehensive theoretical description of negative ion formation in UV-MALDI.

  9. A collisional radiative model for caesium and its application to an RF source for negative hydrogen ions

    NASA Astrophysics Data System (ADS)

    Wünderlich, D.; Wimmer, C.; Friedl, R.

    2015-04-01

    A collisional radiative (CR) model for caesium atoms in low-temperature, low-pressure hydrogen-caesium plasmas is introduced. This model includes the caesium ground state, 14 excited states, the singly charged caesium ion and the negative hydrogen ion. The reaction probabilities needed as input are based on data from the literature, using some scaling and extrapolations. Additionally, new cross sections for electron collision ionization and three-body recombination have been calculated. The relevance of mutual neutralization of positive caesium ions and negative hydrogen ions is highlighted: depending on the densities of the involved particle species, this excitation channel can have a significant influence on the population densities of excited states in the caesium atom. This strong influence is successfully verified by optical emission spectroscopy measurements performed at the IPP prototype negative hydrogen ion source for ITER NBI. As a consequence, population models for caesium in electronegative low-temperature, low-pressure hydrogen-caesium plasmas need to take into account the mutual neutralization process. The present CR model is an example for such models and represents an important prerequisite for deducing the total caesium density in surface production based negative hydrogen ion sources.

  10. High-powered pulsed-ion-beam acceleration and transport

    SciTech Connect

    Humphries, S. Jr.; Lockner, T.R.

    1981-11-01

    The state of research on intense ion beam acceleration and transport is reviewed. The limitations imposed on ion beam transport by space charge effects and methods available for neutralization are summarized. The general problem of ion beam neutralization in regions free of applied electric fields is treated. The physics of acceleration gaps is described. Finally, experiments on multi-stage ion acceleration are summarized.

  11. Energetic negative ion and neutral atom beam generation at passage of laser accelerated high energy positive ions through a liquid spray

    NASA Astrophysics Data System (ADS)

    Abicht, F.; Prasad, R.; Priebe, G.; Braenzel, J.; Ehrentraut, L.; Andreev, A.; Nickles, P. V.; Schnürer, M.; Tikhonchuk, V.; Ter-Avetisyan, Sargis

    2013-05-01

    Beams of energetic negative ions and neutral atoms are obtained from water and ethanol spray targets irradiated by high intensity (5×1019 W/cm2) and ultrashort (50 fs) laser pulses. The resulting spectra were measured with the Thomson parabola spectrometer, which enabled absolute measurements of both: positive and negative ions. The generation of a beam of energetic neutral hydrogen atoms was confirmed with CR-39 track detectors and their spectral characteristics have been measured using time of flight technique. Generation is ascribed to electron-capture and -loss processes in the collisions of laser-accelerated high-energy protons with spray of droplets. The same method can be applied to generate energetic negative ions and neutral atoms of different species.

  12. Positive and negative ion mode ESI-MS and MS/MS for studying drug-DNA complexes

    NASA Astrophysics Data System (ADS)

    Rosu, Frédéric; Pirotte, Sophie; Pauw, Edwin De; Gabelica, Valérie

    2006-07-01

    We report systematic investigation of duplex DNA complexes with minor groove binders (Hoechsts 33258 and 33342, netropsin and DAPI) and intercalators (daunomycin, doxorubicin, actinomycin D, ethidium, cryptolepine, neocryptolepine, m-Amsacrine, proflavine, ellipticine and mitoxantrone) by ESI-MS and ESI-MS/MS in the negative ion mode and in the positive ion mode. The apparent solution phase equilibrium binding constants can be determined by measuring relative intensities in the ESI-MS spectrum. While negative ion mode gives reliable results, positive ion mode gives a systematic underestimation of the binding constants and even a complete suppression of the complexes for intercalators lacking functional groups capable of interacting in the grooves. In the second part of the paper we systematically compare MS/MS fragmentation channels and breakdown curves in the positive and the negative modes, and discuss the possible uses and caveats of MS/MS in drug-DNA complexes. In the negative mode, the drugs can be separated in three groups: (1) those that leave the complex with no net charge; (2) those that leave the complex with a negative charge; and (3) those that remain attached on the strands upon dissociation of the duplex due to their positive charge. In the positive ion mode, all complexes fragment via the loss of protonated drug. Information on the stabilization of the complex by drug-DNA noncovalent interactions can be obtained straightforwardly only in the case of neutral drug loss. In all other cases, proton affinity (in the positive ion mode), gas-phase basicity (in the negative ion mode) and coulombic repulsion are the major factors influencing the fragmentation channel and the dissociation kinetics.

  13. Numerical experiment to estimate the validity of negative ion diagnostic using photo-detachment combined with Langmuir probing

    SciTech Connect

    Oudini, N.; Sirse, N.; Ellingboe, A. R.; Benallal, R.; Taccogna, F.; Bendib, A.

    2015-07-15

    This paper presents a critical assessment of the theory of photo-detachment diagnostic method used to probe the negative ion density and electronegativity α = n{sub -}/n{sub e}. In this method, a laser pulse is used to photo-detach all negative ions located within the electropositive channel (laser spot region). The negative ion density is estimated based on the assumption that the increase of the current collected by an electrostatic probe biased positively to the plasma is a result of only the creation of photo-detached electrons. In parallel, the background electron density and temperature are considered as constants during this diagnostics. While the numerical experiments performed here show that the background electron density and temperature increase due to the formation of an electrostatic potential barrier around the electropositive channel. The time scale of potential barrier rise is about 2 ns, which is comparable to the time required to completely photo-detach the negative ions in the electropositive channel (∼3 ns). We find that neglecting the effect of the potential barrier on the background plasma leads to an erroneous determination of the negative ion density. Moreover, the background electron velocity distribution function within the electropositive channel is not Maxwellian. This is due to the acceleration of these electrons through the electrostatic potential barrier. In this work, the validity of the photo-detachment diagnostic assumptions is questioned and our results illustrate the weakness of these assumptions.

  14. K-P-Burgers equation in negative ion-rich relativistic dusty plasma including the effect of kinematic viscosity

    NASA Astrophysics Data System (ADS)

    Dev, A. N.; Deka, M. K.; Sarma, J.; Saikia, D.; Adhikary, N. C.

    2016-10-01

    The stationary solution is obtained for the K-P-Burgers equation that describes the nonlinear propagations of dust ion acoustic waves in a multi-component, collisionless, un-magnetized relativistic dusty plasma consisting of electrons, positive and negative ions in the presence of charged massive dust grains. Here, the Kadomtsev-Petviashvili (K-P) equation, three-dimensional (3D) Burgers equation, and K-P-Burgers equations are derived by using the reductive perturbation method including the effects of viscosity of plasma fluid, thermal energy, ion density, and ion temperature on the structure of a dust ion acoustic shock wave (DIASW). The K-P equation predictes the existences of stationary small amplitude solitary wave, whereas the K-P-Burgers equation in the weakly relativistic regime describes the evolution of shock-like structures in such a multi-ion dusty plasma.

  15. Observation of the emission of positive and negative ions in triple and quadruple collisions in a solid under bombardment with keV argon ions

    NASA Astrophysics Data System (ADS)

    Babenko, P. Yu.; Shergin, A. P.

    2006-12-01

    Particles that leave a solid as a result of several consecutive binary collisions are detected in the energy spectra of positive and negative ions emitted upon the irradiation of C, Si, Ge, and In targets with 2-to 5-keV Ar+ ions. The appearance of a spectral structure due to the sequence of three and four collisions in the solid can be attributed to the selective role of the surface, which is similar to the channeling effect in crystals.

  16. Photodetachment Studies Of Atomic Negative Ions Through Velocity-Map Imaging Spectroscopy

    NASA Astrophysics Data System (ADS)

    Chartkunchand, Kiattichart

    The technique of velocity-map imaging (VMI) spectroscopy as been adapted to a keV-level negative ion beamline for studies of photon-negative ion collisions. The design and operation of the VMI spectrometer takes into consideration the use of continuous, fast-moving (5 keV to 10 keV) ion beams, as well as a continuous wave (CW) laser as the source of photons. The VMI spectrometer has been used in photodetachment studies of the Group 14 negative ions Ge--, Sn--, and Pb-- at a photon wavelength of 532 nm. Measurements of the photoelectron angular distributions and asymmetry parameters for Ge-- and Sn-- were benchmarked against those measured previously [W. W. Williams, D. L. Carpenter, A. M. Covington, and J. S. Thompson, Phys. Rev. A 59, 4368 (1999), V. T. Davis, J. Ashokkumar, and J. S. Thompson, Phys. Rev. A 65, 024702 (2002)], while fine-structure-resolved asymmetry parameters for Pb-- were measured for the first time. Definitive evidence of a "forbidden" 4S 3/2→1D2 transition was observed in both the Ge-- and Sn-- photoelectron kinetic energy spectra. This transition is explained in terms of the inadequacy of the single-configuration description for the 1D2 excited state in the corresponding neutral. Near-threshold photodetachment studies of S-- were carried out in order to measure the spectral dependence of the photoelectron angular distribution. The resulting asymmetry parameters were measured at several photon wavelengths in the range of 575 nm (2.156 eV photon energy) to 615 nm (2.016 eV photon energy). Comparison of the measurements to a qualitative model of p-electron photodetachment [D. Hanstorp, C. Bengtsson, and D. J. Larson, Phys. Rev. A 40, 670 (1989)] were made. Deviations of the measured asymmetry parameters from the Hanstorp model near photodetachment thresholds suggests a reduced degree of suppression of d partial-waves than predicted by models. Measurement of the electron affinity of terbium was performed along with a determination of the

  17. Generation of pulsed ion beams by an inductive storage pulsed power generator

    NASA Astrophysics Data System (ADS)

    Katsuki, Sunao; Akiyama, Hidenori; Maeda, Sadao

    1990-10-01

    A pulsed power generator by an inductive energy storage system is extremely compact and light in comparison with a conventional pulsed power generator, which consists of a Marx bank and a water pulse forming line. A compact and light pulse power generator is applied to the generation of pulsed ion beams. A thin copper fuse is used an an opening switch, which is necessary in the inductive storage pulsed power generator. A magnetically insulated diode is used for the generation of ion beams. The pulsed ion beams are successfully generated by the inductive storage pulsed power generator for the first time.

  18. Reinstating lead for high-loaded efficient negative electrode for rechargeable sodium-ion battery

    NASA Astrophysics Data System (ADS)

    Darwiche, Ali; Dugas, Romain; Fraisse, Bernard; Monconduit, Laure

    2016-02-01

    Due to its weight and toxicity, Pb is usually not considered as possible anode for Li- and Na-ion (NIBs) batteries. Nevertheless the toxicity is related to specific applications and its recycling is more than 99% which is one of the highest recycling rates on the planet where no other power source is utilized in more applications with such sustainability. For this reason, we have investigated micrometric lead particles as electrode for NIBs in an ether-based electrolyte (1 M NaPF6 in diglyme). The cyclability, coulombic efficiency and rate capability of lead were unexpected. A high loaded lead electrode with 98%wt of Pb and only 1% of carbon additive showed i) a capacity retention of 464 mA h/g after 50 cycles with only 1.5% of capacity loss, which represents a high volumetric capacity of 5289 mA h/cm3 due to the high density of Pb and ii) a very interesting capacity retention even at high current rate (1950 mA/g). In situ XRD study confirmed a sodiation-desodiation process in four steps. Preliminary tests in Pb//Na3V2(PO4)2F3 full cells showed promising results demonstrating that Pb could be a practical candidate for future high energy density Na-ion batteries with an efficient sodiated or non sodiated positive electrode.

  19. Performance degradation of high-power lithium-ion cells-Electrochemistry of harvested electrodes

    NASA Astrophysics Data System (ADS)

    Abraham, D. P.; Knuth, J. L.; Dees, D. W.; Bloom, I.; Christophersen, J. P.

    The performance of 18650-type high-power lithium-ion cells is being evaluated as part of the U.S. Department of Energy's (DOEs) Advanced Technology Development (ATD) program. In this article, we present accelerated aging data acquired on 18650-cells containing LiNi 0.8Co 0.15Al 0.05O 2- or LiNi 0.8Co 0.1Al 0.1O 2-based positive electrodes, MAG-10 graphite-based negative electrodes, and 1.2-M LiPF 6 in EC:EMC (3:7 by wt.) electrolyte. Capacity and impedance data acquired on electrodes harvested from these cells highlight the contributions of the positive and negative electrodes to the degradation of cell performance. We also describe test methodologies used to examine the electrochemical characteristics of the harvested electrodes. Identifying and optimizing cell components responsible for performance degradation should enable the development of new lithium-ion cell chemistries that will meet the 15-year cell calendar life goal established by DOEs FreedomCar initiative.

  20. Characteristics of positive and negative secondary ions emitted from [Formula: see text] and [Formula: see text] impacts.

    PubMed

    Debord, J D; Fernandez-Lima, F A; Verkhoturov, S V; Schweikert, E A; Della-Negra, S

    2013-01-01

    The current limitation for SIMS analyses is insufficient secondary ion yields, due in part to the inefficiency of traditional primary ions. Massive gold clusters are shown to be a route to significant gains in secondary ion yields relative to other commonly used projectiles. At an impact energy of 520 keV, [Formula: see text] is capable of generating an average of greater than ten secondary ions per projectile, with some impact events generating >100 secondary ions. The capability of this projectile for signal enhancement is further displayed through the observation of up to seven deprotonated molecular ions from a single impact on a neat target of the model pentapeptide leu-enkephalin. Positive and negative spectra of leu-enkephalin reveal two distinct emission regimes responsible for the emission of either intact molecular ions with low internal energies or small fragment species. The internal energy distribution for this projectile is measured using a series of benzylpyridinium salts and compared with the small polyatomic projectile [Formula: see text] at 110 keV as well as distributions previously reported for electrospray ionization and fast atom bombardment. These results show that [Formula: see text] offers high secondary ion yields not only for small fragment ions, e.g. CN(-), typically observed in SIMS analyses, but also for characteristic molecular ions. For the leu-enkephalin example, the yields for each of these species are greater than unity.