Science.gov

Sample records for praseodymium holmium erbium

  1. Visible absorption spectra of the 4f electron transitions of neodymium, praseodymium, holmium and erbium complexes with fleroxacin and their analytical application.

    PubMed

    Wang, Naixing; Jiang, Wei; Xu, Xiuqin; Si, Zhikun; Bai, Haitao; Tian, Cong

    2002-05-01

    The absorption spectra of the 4f electron transitions of neodymium, praseodymium, holmium and erbium complexes with fleroxacin in the presence of cetylpyridinium chloride were studied by normal and derivative spectrophotometry. Their molar absorptivity at the maximum absorption bands are about 5.3 (at 571 nm) times greater for neodymium, 2.8 (at 483 nm) times greater for praseodymium, 12.6 (at 448.5 nm) times greater for holmium and 9.7 (at 519 nm) times greater for erbium than those in the absence of complexing agents. The second-derivative spectrum is used both to eliminate the interference from other rare earths and to improve the sensitivity. Beer's law is obeyed from 3.0 - 70 microg ml(-1) for neodymium and holmium, from 6.0 - 70 microg ml(-1) for erbium, and from 12.0 - 70 microg ml(-1) for praseodymium. The relative standard deviations are 1.9% and 1.5% for 7.5 microg ml(-1) of neodymium and holmium, and 2.1% and 1.6% for 15.0 microg ml(-1) of praseodymium and erbium, respectively. Their detection limits (signal-to-noise ratio = 2) are 3.2 microg ml(-1), 1.3 microg ml(-1), (1.1) microg ml(-1) and 2.5 microg ml(-1) for praseodymium, neodymium, holmium and erbium, respectively. A new system for the simultaneous determinations of the praseodymium, neodymium, holmium and erbium in rare earth mixtures with good accuracy and selectivity is proposed.

  2. Discovery of dysprosium, holmium, erbium, thulium, and ytterbium isotopes

    SciTech Connect

    Fry, C.; Thoennessen, M.

    2013-09-15

    Currently, thirty-one dysprosium, thirty-two holmium, thirty-two erbium, thirty-three thulium, and thirty-one ytterbium isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  3. Combination of erbium and holmium laser radiation for tissue ablation

    NASA Astrophysics Data System (ADS)

    Pratisto, Hans S.; Frenz, Martin; Koenz, Flurin; Altermatt, Hans J.; Weber, Heinz P.

    1996-05-01

    Erbium lasers emitting at 2.94 micrometers and holmium lasers emitting at 2.1 micrometers are interesting tools for cutting, drilling, smoothing and welding of water containing tissues. The high absorption coefficient of water at these wavelengths leads to their good ablation efficiency with controlled thermally altered zones around the ablation sites. Combination of pulses with both wavelengths transmitted through one fiber were used to perform incisions in soft tissue and impacts in bone disks. Histological results and scanning electron microscope evaluations reveal the strong influence of the absorption coefficient on tissue effects, especially on the ablation efficiency and the zone of thermally damaged tissue. It is demonstrated that the combination of high ablation rates and deep coagulation zones can be achieved. The results indicate that this laser system can be considered as a first step towards a multi-functional medical instrument.

  4. Effects of the holmium:YAG and erbium:YAG lasers on endotracheal tubes.

    PubMed

    Kautzky, M; Fitzgerald, R; Dechtyar, I; Schenk, P

    1993-01-01

    Endotracheal tube (ET) fire is the most frequent complication arising with laser surgery in the upper aerodigestive tract. No data are available about the safety of commonly used ETs when used with recently developed high-energy pulsed lasers, working with only a minimal thermal component but mainly photoablative. A comparative in vitro study was performed with three types of endotracheal tubes to assess their resistance to wall and cuff damage by the laser beams of two pulsed infrared solid-state lasers. ET perforation was attempted with the erbium:YAG (lambda = 2,930 nm) and holmium:YAG (lambda = 2,120 nm) lasers. For all experiments, a repetition rate of 5 Hz was used. The 2.5-microseconds holmium:YAG pulses were coupled into a nylon fibre of 400 microns diameter. The 2.0-microseconds erbium:YAG laser pulses were applied to ETs through a lens system providing a spot size diameter of 200 microns. Polyvinyl chloride and silicon ET segments were exposed to laser pulse energies from 97 to 500 mJ in the presence of different anaesthetic gas mixtures. The time from the onset of exposure to tube perforation was recorded. Thermal gradients following laser application were measured. Laser exposure was continued for up to 90 s, unless tube ignition occurred. At all energy levels tested, the photo-ablative mechanism of laser-tube interaction, with few thermal components, led to laser-induced tube ignition if an FiO2 > 21% for the holmium:YAG and 34% for the erbium:YAG laser was established. With increasing pulse energies, ET segments ignited sooner. MLT tubes performed best in the present safety test. PMID:8446385

  5. Effects of the holmium:YAG and erbium:YAG lasers on endotracheal tubes.

    PubMed

    Kautzky, M; Fitzgerald, R; Dechtyar, I; Schenk, P

    1993-01-01

    Endotracheal tube (ET) fire is the most frequent complication arising with laser surgery in the upper aerodigestive tract. No data are available about the safety of commonly used ETs when used with recently developed high-energy pulsed lasers, working with only a minimal thermal component but mainly photoablative. A comparative in vitro study was performed with three types of endotracheal tubes to assess their resistance to wall and cuff damage by the laser beams of two pulsed infrared solid-state lasers. ET perforation was attempted with the erbium:YAG (lambda = 2,930 nm) and holmium:YAG (lambda = 2,120 nm) lasers. For all experiments, a repetition rate of 5 Hz was used. The 2.5-microseconds holmium:YAG pulses were coupled into a nylon fibre of 400 microns diameter. The 2.0-microseconds erbium:YAG laser pulses were applied to ETs through a lens system providing a spot size diameter of 200 microns. Polyvinyl chloride and silicon ET segments were exposed to laser pulse energies from 97 to 500 mJ in the presence of different anaesthetic gas mixtures. The time from the onset of exposure to tube perforation was recorded. Thermal gradients following laser application were measured. Laser exposure was continued for up to 90 s, unless tube ignition occurred. At all energy levels tested, the photo-ablative mechanism of laser-tube interaction, with few thermal components, led to laser-induced tube ignition if an FiO2 > 21% for the holmium:YAG and 34% for the erbium:YAG laser was established. With increasing pulse energies, ET segments ignited sooner. MLT tubes performed best in the present safety test.

  6. Studies on the sorption of praseodymium (III), holmium (III) and cobalt (II) from nitrate medium using TVEX-PHOR resin.

    PubMed

    El-Dessouky, S I; El-Sofany, E A; Daoud, J A

    2007-05-01

    The use of TVEX-PHOR resin for the sorption of praseodymium (III), holmium (III) and cobalt (II) from nitrate medium was carried out using batch and column techniques. Various parameters affecting the uptake of these metal ions such as v/m ratio, pH and the metal ion concentration were separately studied. Effect of temperature on the equilibrium distribution values has been studied to evaluate the changes in standard thermodynamic quantities. Experimental results of the investigated metal ions were found to fit to Freundlich isotherm model over the entire studied concentration range. Selectivity sequence of the resin for these metals is Ho>Pr>Co. The recovery of the investigated metals from the loaded resin is preformed with 0.1M sulphuric acid.

  7. Histologic comparison of needle, holmium:YAG, and erbium:YAG endoscopic goniotomy

    NASA Astrophysics Data System (ADS)

    Joos, Karen M.; Shen, Jin-Hui; Rivera, Brian K.; Hernandez, Eleut; Shetlar, Debra J.

    1995-05-01

    An endoscope allows visualization of the anterior chamber angle in porcine eyes despite the presence of cloudy corneas. The pectinate ligaments in the anterior chamber angle are a surgical model for primary infantile glaucoma. This study investigated the histologic results, one month after treating the anterior chamber angle with a goniotomy needle, the holmium:YAG laser, or the erbium:YAG laser coupled to a small endoscope. The anterior chambers were deepened with a viscoelastic material in one-month-old anesthetized pigs. An Olympus 0.8 mm diameter flexible endoscope was externally coupled to a 23 gauge needle or a 300 micron diameter fiber. The angle was treated for 120 degrees by one of the three methods, and the probe was removed. During the acute study, all three methods cut the pectinate ligaments. The histologic findings one month after healing demonstrated minimal surrounding tissue damage following goniotomy with a needle and the most surrounding tissue damage following treatment with the holmium:YAG laser.

  8. Semiempirical quantum chemistry model for the lanthanides: RM1 (Recife Model 1) parameters for dysprosium, holmium and erbium.

    PubMed

    Filho, Manoel A M; Dutra, José Diogo L; Rocha, Gerd B; Simas, Alfredo M; Freire, Ricardo O

    2014-01-01

    Complexes of dysprosium, holmium, and erbium find many applications as single-molecule magnets, as contrast agents for magnetic resonance imaging, as anti-cancer agents, in optical telecommunications, etc. Therefore, the development of tools that can be proven helpful to complex design is presently an active area of research. In this article, we advance a major improvement to the semiempirical description of lanthanide complexes: the Recife Model 1, RM1, model for the lanthanides, parameterized for the trications of Dy, Ho, and Er. By representing such lanthanide in the RM1 calculation as a three-electron atom with a set of 5 d, 6 s, and 6 p semiempirical orbitals, the accuracy of the previous sparkle models, mainly concentrated on lanthanide-oxygen and lanthanide-nitrogen distances, is extended to other types of bonds in the trication complexes' coordination polyhedra, such as lanthanide-carbon, lanthanide-chlorine, etc. This is even more important as, for example, lanthanide-carbon atom distances in the coordination polyhedra of the complexes comprise about 30% of all distances for all complexes of Dy, Ho, and Er considered. Our results indicate that the average unsigned mean error for the lanthanide-carbon distances dropped from an average of 0.30 Å, for the sparkle models, to 0.04 Å for the RM1 model for the lanthanides; for a total of 509 such distances for the set of all Dy, Ho, and Er complexes considered. A similar behavior took place for the other distances as well, such as lanthanide-chlorine, lanthanide-bromine, lanthanide, phosphorus and lanthanide-sulfur. Thus, the RM1 model for the lanthanides, being advanced in this article, broadens the range of application of semiempirical models to lanthanide complexes by including comprehensively many other types of bonds not adequately described by the previous models.

  9. Semiempirical Quantum Chemistry Model for the Lanthanides: RM1 (Recife Model 1) Parameters for Dysprosium, Holmium and Erbium

    PubMed Central

    Filho, Manoel A. M.; Dutra, José Diogo L.; Rocha, Gerd B.; Simas, Alfredo M.; Freire, Ricardo O.

    2014-01-01

    Complexes of dysprosium, holmium, and erbium find many applications as single-molecule magnets, as contrast agents for magnetic resonance imaging, as anti-cancer agents, in optical telecommunications, etc. Therefore, the development of tools that can be proven helpful to complex design is presently an active area of research. In this article, we advance a major improvement to the semiempirical description of lanthanide complexes: the Recife Model 1, RM1, model for the lanthanides, parameterized for the trications of Dy, Ho, and Er. By representing such lanthanide in the RM1 calculation as a three-electron atom with a set of 5 d, 6 s, and 6 p semiempirical orbitals, the accuracy of the previous sparkle models, mainly concentrated on lanthanide-oxygen and lanthanide-nitrogen distances, is extended to other types of bonds in the trication complexes’ coordination polyhedra, such as lanthanide-carbon, lanthanide-chlorine, etc. This is even more important as, for example, lanthanide-carbon atom distances in the coordination polyhedra of the complexes comprise about 30% of all distances for all complexes of Dy, Ho, and Er considered. Our results indicate that the average unsigned mean error for the lanthanide-carbon distances dropped from an average of 0.30 Å, for the sparkle models, to 0.04 Å for the RM1 model for the lanthanides; for a total of 509 such distances for the set of all Dy, Ho, and Er complexes considered. A similar behavior took place for the other distances as well, such as lanthanide-chlorine, lanthanide-bromine, lanthanide, phosphorus and lanthanide-sulfur. Thus, the RM1 model for the lanthanides, being advanced in this article, broadens the range of application of semiempirical models to lanthanide complexes by including comprehensively many other types of bonds not adequately described by the previous models. PMID:24497945

  10. High-power frequency comb in the range of 2-2.15  μm based on a holmium fiber amplifier seeded by wavelength-shifted Raman solitons from an erbium-fiber laser.

    PubMed

    Coluccelli, Nicola; Cassinerio, Marco; Gambetta, Alessio; Laporta, Paolo; Galzerano, Gianluca

    2014-03-15

    We demonstrate a room-temperature high-power frequency comb source covering the spectral region from 2 to 2.15 μm. The source is based on a femtosecond erbium-fiber laser operating at 1.55 μm with a repetition rate of 250 MHz, wavelength-shifted up to 2.06 μm by the solitonic Raman effect, seeding a large-mode-area holmium (Ho) fiber amplifier pumped by a thulium (Tm) fiber laser emitting at 1.94 μm. The frequency comb has an integrated power of 2 W, with overall power fluctuations as low as 0.3%. The beatnote between the comb and a high-spectral-purity, single-frequency Tm-Ho laser has a linewidth of 32 kHz over 1 ms observation time, with a signal-to-noise ratio in excess of 30 dB.

  11. Activation cross sections of proton and deuteron induced nuclear reactions on holmium and erbium, related to the production of (161)Er and (160)Er medical isotopes.

    PubMed

    Tárkányi, F; Ditrói, F; Takács, S; Hermanne, A; Baba, M

    2016-09-01

    Experimental excitation functions for long-lived products in proton induced reactions were measured with the activation method in the 37-65MeV energy range on natural holmium. Stacked foil irradiation technique and high resolution gamma spectrometry were used in order to measure cross-section data for the production of (161)Er, (160)Er and (1)(59,157)Dy. For comparison of the production routes of medically related (161)Er and (160)Er radioisotopes new experimental cross section data were deduced for the (162)Er(p,x)(161,160)Er and (162)Er(d,x)(161,160)Er reactions by re-evaluating gamma-ray spectra from earlier measurements. No earlier data were found in the literature for these reactions. The experimental data are compared with results of TALYS theoretical code reported in TENDL-2015. PMID:27451109

  12. Activation cross sections of proton and deuteron induced nuclear reactions on holmium and erbium, related to the production of (161)Er and (160)Er medical isotopes.

    PubMed

    Tárkányi, F; Ditrói, F; Takács, S; Hermanne, A; Baba, M

    2016-09-01

    Experimental excitation functions for long-lived products in proton induced reactions were measured with the activation method in the 37-65MeV energy range on natural holmium. Stacked foil irradiation technique and high resolution gamma spectrometry were used in order to measure cross-section data for the production of (161)Er, (160)Er and (1)(59,157)Dy. For comparison of the production routes of medically related (161)Er and (160)Er radioisotopes new experimental cross section data were deduced for the (162)Er(p,x)(161,160)Er and (162)Er(d,x)(161,160)Er reactions by re-evaluating gamma-ray spectra from earlier measurements. No earlier data were found in the literature for these reactions. The experimental data are compared with results of TALYS theoretical code reported in TENDL-2015.

  13. Metals fact sheet: Holmium/thulium

    SciTech Connect

    1996-02-01

    This article discusses the geology, exploitation, market, and applications of holmium and thulium. Holmium and thulium are important part in the development of specific laser technologies, x-ray film and high-temperature superconductors.

  14. Holmium laser applications of the prostate.

    PubMed

    Lerner, Lori B; Tyson, Mark D

    2009-11-01

    The high-powered holmium laser is an excellent tool for the surgical treatment of benign prostatic hyperplasia. This article discusses the background of holmium use in the prostate and describes the surgical techniques of holmium laser ablation of the prostate and holmium laser enucleation of the prostate. Operative challenges are reviewed with suggestions as to how to avoid these problems or deal with them when they arise. Surgical outcomes and a thorough literature review are both presented.

  15. Magnetic structure of holmium

    NASA Astrophysics Data System (ADS)

    Pechan, M. J.; Stassis, C.

    1984-03-01

    The magnetic structure of high purity single crystals of holmium has been studied by neutron diffraction techniques. Although the general characteristics of the magnetic structure have been found to agree with earlier measurements, some discrepancies have been resolved and new features have been observed. The magnetic form factor has been measured and compared with relativistic atomic calculations. The low temperature structure (T<20 K) is that of a conical ferromagnet with wave vector (1/6)(2π/c) along the c axis. The basal plane moment is 9.7 μB and the c-axis ferromagnetic component is 1.6 μB at T=6 K. Bunching of the basal plane moments around the easy hexagonal direction has been observed below T=50 K. Evidence for asphericity in the magnetization density is presented and discussed. The wave vector of the basal plane modulation decreases monotonically with temperature in general accordance with the Elliott-Wedgewood theory. Several inflection points were observed, however, which correspond to commensurability with the chemical lattice. The measured temperature dependence of the c- and a-axis lattice constants shows significant magnetostriction. The possibility of a c-axis modulated moment is discussed.

  16. Thermal properties of holmium-implanted gold films for a neutrino mass experiment with cryogenic microcalorimeters

    SciTech Connect

    Prasai, K.; Yanardag, S. Basak; Galeazzi, M.; Uprety, Y.; Alves, E.; Rocha, J.; Bagliani, D.; Biasotti, M.; Gatti, F.; Gomes, M. Ribeiro

    2013-08-15

    In a microcalorimetric neutrino mass experiment using the radioactive decay of {sup 163}Ho, the radioactive material must be fully embedded in the microcalorimeter absorber. One option that is being investigated is to implant the radioactive isotope into a gold absorber, as gold is successfully used in other applications. However, knowing the thermal properties at the working temperature of microcalorimeters is critical for choosing the absorber material and for optimizing the detector performance. In particular, it is paramount to understand if implanting the radioactive material in gold changes its heat capacity. We used a bolometric technique to measure the heat capacity of gold films, implanted with various concentrations of holmium and erbium (a byproduct of the {sup 163}Ho fabrication), in the temperature range 70 mK–300 mK. Our results show that the specific heat capacity of the gold films is not affected by the implant, making this a viable option for a future microcalorimeter holmium experiment.

  17. Erbium laser in gynecology.

    PubMed

    Vizintin, Z; Lukac, M; Kazic, M; Tettamanti, M

    2015-01-01

    The aim of this paper is to present a novel laser technology utilizing the erbium YAG laser for various minimally invasive, non-surgical procedures in gynecology. Non-ablative, thermal-only SMOOTH-mode erbium pulses are used to produce vaginal collagen hyperthermia, followed by collagen remodeling and the synthesis of new collagen fibers, resulting in improved vaginal tissue tightness and elasticity. This erbium laser technology is used for treatments of vaginal laxity, stress urinary incontinence, pelvic organ prolapse and vaginal atrophy. In the period from 2010 to 2014, several clinical studies covering all four indications were conducted with the aim to prove the efficacy and safety of this novel technology. An overview is presented of the results of these studies where several objective as well as subjective assessment tools were used. The results have shown that SMOOTH-mode erbium laser seems to be an effective and safe method for treating vaginal laxity, stress urinary incontinence, pelvic organ prolapses and vaginal atrophy.

  18. Erbium-doped all-fiber laser at 2.94 microm.

    PubMed

    Faucher, Dominic; Bernier, Martin; Caron, Nicolas; Vallée, Réal

    2009-11-01

    We report what we believe is the first demonstration of laser emission at 2.94 microm in an erbium-doped fluoride fiber laser. The low-loss all-fiber Fabry-Perot laser cavity was formed by two fiber Bragg gratings of 90% and 15% reflectivities in a 6.6 m, 7 mol.% Er-doped double-clad fiber. A maximum cw output power of 5.2 W was measured, which is to our knowledge the highest reported to date for a diode-pumped laser at this wavelength. A coreless endcap was fused at the output fiber end to prevent its deterioration at high output powers. Our results, including the slope efficiency of 26.6% with respect to launched pump power, suggest that erbium could be a better alternative than holmium in the search for a replacement for the flashlamp-pumped Er:YAG at 2.94 microm.

  19. Erbium diffusion in silicon dioxide

    SciTech Connect

    Lu Yingwei; Julsgaard, B.; Petersen, M. Christian; Jensen, R. V. Skougaard; Pedersen, T. Garm; Pedersen, K.; Larsen, A. Nylandsted

    2010-10-04

    Erbium diffusion in silicon dioxide layers prepared by magnetron sputtering, chemical vapor deposition, and thermal growth has been investigated by secondary ion mass spectrometry, and diffusion coefficients have been extracted from simulations based on Fick's second law of diffusion. Erbium diffusion in magnetron sputtered silicon dioxide from buried erbium distributions has in particular been studied, and in this case a simple Arrhenius law can describe the diffusivity with an activation energy of 5.3{+-}0.1 eV. Within a factor of two, the erbium diffusion coefficients at a given temperature are identical for all investigated matrices.

  20. Erbium hydride decomposition kinetics.

    SciTech Connect

    Ferrizz, Robert Matthew

    2006-11-01

    Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report are analyzed quantitatively using Redhead's method to yield kinetic parameters (E{sub A} {approx} 54.2 kcal/mol), which are then utilized to predict hydrogen outgassing in vacuum for a variety of thermal treatments. Interestingly, it was found that the activation energy for desorption can vary by more than 7 kcal/mol (0.30 eV) for seemingly similar samples. In addition, small amounts of less-stable hydrogen were observed for all erbium dihydride films. A detailed explanation of several approaches for analyzing thermal desorption spectra to obtain kinetic information is included as an appendix.

  1. Complications employing the holmium:YAG laser.

    PubMed

    Beaghler, M; Poon, M; Ruckle, H; Stewart, S; Weil, D

    1998-12-01

    We report the operative and early postoperative complications and limitations in 133 patients treated with the holmium laser. Complications included urinary tract infection (N = 3), postoperative bradycardia (1), inverted T-waves (1), intractable flank pain (1), urinary retention (1), inability to access a lower-pole calix with a 365-microm fiber (9), stone migration (5), and termination of procedure because of poor visibility (2). No ureteral perforations or strictures occurred, and no complications were directly attributable to the laser. The holmium laser was capable of fragmenting all urinary calculi in this study. In our initial experience, the holmium laser is safe and effective in the treatment of urinary pathology. Use of laser fibers larger than 200 microm occasionally limits deflection of the endoscope into a lower-pole or dependent calix.

  2. SESAM mode-locked red praseodymium laser.

    PubMed

    Gaponenko, Maxim; Metz, Philip Werner; Härkönen, Antti; Heuer, Alexander; Leinonen, Tomi; Guina, Mircea; Südmeyer, Thomas; Huber, Günter; Kränkel, Christian

    2014-12-15

    We present the first semiconductor saturable absorber mirror (SESAM) mode-locked praseodymium solid-state laser. The laser is based on a Pr(3+):LiYF(4) crystal as gain medium and a GaInP-quantum well-based SESAM. Self-starting continuous-wave mode-locked laser operation with an average output power of 16 mW is achieved at a center wavelength of 639.5 nm. The laser operates at a repetition rate of ∼85.55  MHz and emits pulses with a duration of ∼18  ps.

  3. SESAM mode-locked red praseodymium laser.

    PubMed

    Gaponenko, Maxim; Metz, Philip Werner; Härkönen, Antti; Heuer, Alexander; Leinonen, Tomi; Guina, Mircea; Südmeyer, Thomas; Huber, Günter; Kränkel, Christian

    2014-12-15

    We present the first semiconductor saturable absorber mirror (SESAM) mode-locked praseodymium solid-state laser. The laser is based on a Pr(3+):LiYF(4) crystal as gain medium and a GaInP-quantum well-based SESAM. Self-starting continuous-wave mode-locked laser operation with an average output power of 16 mW is achieved at a center wavelength of 639.5 nm. The laser operates at a repetition rate of ∼85.55  MHz and emits pulses with a duration of ∼18  ps. PMID:25503035

  4. Urological applications of the holmium laser

    NASA Astrophysics Data System (ADS)

    Beaghler, Marc A.; Poon, Michael W.; Ruckle, Herbert C.; Stewart, Steven C.; Weil, Dane

    1998-07-01

    While the role of endoscopy was initially diagnostic, the advent of improved endoscopes and working instruments have increased its therapeutic applications. One of the most recent advances is the holmium laser. It has a broad range of urological applications due to its ability to fragment all urinary calculi and its soft tissue effects. This laser is based on laser energy delivered in a pulsatile fashion at 2100 nm. The purpose of this study is to report our experience with the holmium laser. A retrospective study of patients undergoing endourological procedures with the holmium laser was performed. One hundred and forty patients underwent 157 procedures. The holmium laser was used for the treatment of urinary calculi in 122 patients. Stone location included 61 renal, 64 ureteral, and 17 bladder stones. Renal stone burden was 17 mm (range 3-50), ureteral stone size averaged 10 mm (range 3 - 35), and mean bladder stone size was 31 mm (range 10 - 60). Other uses included treatment of transitional cell carcinoma of the renal pelvis, ureter, and bladder, incision of ureteral strictures, ureterocele, and prostate, and ablation of renal hemangiomas. Intraoperative and post operative complications were noted. Follow-up for calculi consisted of a plain film of the abdomen at one week and an ultrasound or intravenous pyelogram at six to eight weeks post procedure. No ureteral perforations or strictures occurred. The Holmium laser was capable of fragmenting all urinary calculi in this study. No complications were directly attributable to the Holmium laser. In our initial experience, the Holmium laser is safe and effective in the treatment of urinary pathology. It is the most effective lithotrite available and is able to incise and coagulate soft tissue as well. This combination allows the urologist to treat a variety of urinary pathology using a single modality. Its main limitation is the ability to access lower pole lesions in the upper urinary tract due to the fiber

  5. Holmium laser lithotripsy of bladder calculi

    NASA Astrophysics Data System (ADS)

    Beaghler, Marc A.; Poon, Michael W.

    1998-07-01

    Although the overall incidence of bladder calculi has been decreasing, it is still a significant disease affecting adults and children. Prior treatment options have included open cystolitholapaxy, blind lithotripsy, extracorporeal shock wave lithotripsy, and visual lithotripsy with ultrasonic or electrohydraulic probes. The holmium laser has been found to be extremely effective in the treatment of upper tract calculi. This technology has also been applied to the treatment of bladder calculi. We report our experience with the holmium laser in the treatment of bladder calculi. Twenty- five patients over a year and a half had their bladder calculi treated with the Holmium laser. This study was retrospective in nature. Patient demographics, stone burden, and intraoperative and post-operative complications were noted. The mean stone burden was 31 mm with a range of 10 to 60 mm. Preoperative diagnosis was made with either an ultrasound, plain film of the abdomen or intravenous pyelogram. Cystoscopy was then performed to confirm the presence and determine the size of the stone. The patients were then taken to the operating room and given a regional or general anesthetic. A rigid cystoscope was placed into the bladder and the bladder stone was then vaporized using the holmium laser. Remaining fragments were washed out. Adjunctive procedures were performed on 10 patients. These included transurethral resection of the prostate, transurethral incision of the prostate, optic internal urethrotomy, and incision of ureteroceles. No major complications occurred and all patients were rendered stone free. We conclude that the Holmium laser is an effective and safe modality for the treatment of bladder calculi. It was able to vaporize all bladder calculi and provides a single modality of treating other associated genitourinary pathology.

  6. Effect of praseodymium chloride on liver microsomal enzymes of rats.

    PubMed

    Oga, S; Galvão, J F; Yasaka, W J; Araujo Filho, A P

    1986-06-01

    A single i.v. dose (5 mg/kg) of a light lanthanon, praseodymium, prolonged the duration of hexobarbital-induced sleep and zoxazolamine-induced paralysis, as well as it modified pharmacokinetic parameters of hexobarbital and zoxazolamine, in rats. Half-lives (t1/2) and area under the curve (AUC) were increased, while elimination coefficient (beta) and clearance (Cl) were decreased. However, in daily doses of 1 mg/kg i.p. for 15 days, praseodymium did not alter pharmacological effects and pharmacokinetic parameters. The in vitro hydroxylation of hexobarbital and zoxazolamine by liver microsomes was inhibited when the animals were treated previously with a single i.v. dose (5 mg/kg) of praseodymium chloride. In these animals, the amount of cytochromes P-450 and b5 were reduced significantly, whereas that of NADPH-cytochrome c reductase remained unchanged. The pretreatment of animals with phenobarbital normalized the microsomal enzyme impairment caused by praseodymium.

  7. Yttrium and rare earth stabilized fast reactor metal fuel

    SciTech Connect

    Guon, J.; Grantham, L.F.; Specht, E.R.

    1992-05-12

    This patent describes an improved metal alloy reactor fuel consisting essentially of uranium, plutonium, and at least one element from the group consisting of yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium.

  8. Holmium laser for multifunctional use in urology

    NASA Astrophysics Data System (ADS)

    Watson, Graham M.; Shroff, Sunil; Thomas, Robert; Kellett, Michael

    1994-05-01

    The holmium laser pulsed at 350 microsecond cuts tissue and fragments calculi. It has been assessed for minimally invasive urological intervention. It is useful for partly excising and partly coagulating tumors, incising strictures and the obstructed PUJ. It partly drill and partly fragments urinary calculi however hard. Other lasers are more effective at any one particular application, but this laser is a useful compromise as a multifunctional device.

  9. [Preparation of reactive bright blue praseodymium dyestuff and its spectral properties].

    PubMed

    Liu, Xiao-Zhen; Yuan, Ya-Qin; Cai, Yu; Zhu, Xian; Wang, Yan-Hong

    2004-08-01

    Reactive bright blue praseodymium dyestuff was prepared by using reactive bright blue and praseodymium oxide. The spectra of reactive bright blue praseodymium and dyed silk cloth by reactive bright blue praseodymium dyestuff were studied by UV-Vis and IR spectra respectively. In the range of 200-800 nm, reactive bright blue has four absorption peaks, and lambda(max) is 259 nm; reactive bright blue praseodymium has three absorption peaks, while lambda(max), is 264.00 nm. In the range of 420-760 nm, reactive bright blue has two absorption peaks at 661.50 and 625.50 nm, respectively, and lambda(max) is 661.50 nm; reactive bright blue praseodymium has only one absorption peak at 618.00 nm. Coordinate bond links reactive bright blue to praseodymium ion. Reactive bright blue praseodymium increases linking radicals as compared with reactive bright blue.

  10. Electronic and optical properties of Praseodymium trifluoride

    SciTech Connect

    Saini, Sapan Mohan

    2014-10-24

    We report the role of f- states on electronic and optical properties of Praseodymium trifluoride (PrF{sub 3}) compound. Full potential linearized augmented plane wave (FPLAPW) method with the inclusion of spin orbit coupling has been used. We employed the local spin density approximation (LSDA) and Coulomb-corrected local spin density approximation (LSDA+U). LSDA+U is known for treating the highly correlated 4f electrons properly. Our theoretical investigation shows that LSDA+U approximation reproduce the correct insulating ground state of PrF{sub 3}. On the other hand there is no significant difference of reflectivity calculated by LSDA and LSDA+U. We find that the reflectivity for PrF{sub 3} compound stays low till around 7 eV which is consistent with their large energy gaps. Our calculated reflectivity compares well with the experimental data. The results are analyzed in the light of transitions involved.

  11. Semiconductor disk laser-pumped subpicosecond holmium fibre laser

    SciTech Connect

    Chamorovskiy, A Yu; Marakulin, A V; Leinonen, T; Kurkov, Andrei S; Okhotnikov, Oleg G

    2012-01-31

    The first passively mode-locked holmium fibre laser has been demonstrated, with a semiconductor saturable absorber mirror (SESAM) as a mode locker. Semiconductor disk lasers have been used for the first time to pump holmium fibre lasers. We obtained 830-fs pulses at a repetition rate of 34 MHz with an average output power of 6.6 mW.

  12. Spherulitic crystallization of holmium tartrates in silica gels

    NASA Astrophysics Data System (ADS)

    Want, Basharat

    2011-09-01

    Spherulites of holmium tartrate trihydrate and holmium nitro-tartrate monohydrate have been grown in silica gel medium by making holmium nitrate to react with tartaric acid at high supersaturations. The mechanism of spherulitic growth of holmium tartrates is discussed. The spherulitic crystallization is shown to be due to heterogeneous nucleation. In the early stages of growth an amorphous spherical mass gets nucleated inside the gel. Crystal fibers diverge radially from the surface of the spherical mass giving rise to a spherical polycrystalline holmium tartrate. Thermal stability of the two types of spherulites grown in the silica gel shows that the holmium tartrate trihydrate is more stable than holmium nitro-tartrate monohydrate. The surface morphology and internal structure of the spherulites of holmium tartrates have been studied by using scanning electron microscopy. The results on growth kinetics are given by studying the variation of radius of spherulites as a function of time. A non-linear time-size relations under several conditions of growth have been observed, which suggests a non-uniform solute concentration at the crystal surface.

  13. Laser cooling, trapping, and Rydberg spectroscopy of neutral holmium atoms

    NASA Astrophysics Data System (ADS)

    Hostetter, James Allen

    This thesis focuses on progress towards using ensembles of neutral holmium for use in quantum computing operations. We are particularly interested in using a switchable interaction between neutral atoms, the Rydberg blockade, to implement a universal set of quantum gates in a collective encoding scheme that presents many benefits over quantum computing schemes which rely on physically distinct qubits. We show that holmium is uniquely suited for operations in a collective encoding basis because it has 128 ground hyperfine states, the largest number of any stable, neutral atom. Holmium is a rare earth atom that is very poorly described for our purposes as it has never been cooled and trapped, its spectrum is largely unknown, and it presents several unique experimental challenges related to its complicated atomic structure and short wavelength transitions. We demonstrate important progress towards overcoming these challenges. We produce the first laser cooling and trapping of holmium into a MOT. Because we use a broad cooling transition, our cooling technique does not require the use of a Zeeman slower. Using MOT depletion spectroscopy, we provide precise measurements of holmium's Rydberg states and its ionization potential. Our work continues towards cooling holmium into a dipole trap by calculating holmium's AC polarizability and demonstrating the results of early attempts at an optical dipole trap. We provide details of future upgrades to the experimental apparatus and discuss interesting potential for using holmium in quantum computing using single atoms in a magnetically trapped lattice. This thesis shows several promising indicators for continued work in this field.

  14. Potential applications of the erbium:YAG laser in endourology.

    PubMed

    Fried, N M

    2001-11-01

    The holmium:YAG laser has become the laser of choice in endourology because of its multiple applications in the fragmentation of kidney stones, incision of strictures, and coagulation of tumors. This paper describes the potential use of a new laser, the erbium:YAG laser, for applications in endourology. Recent studies suggest that the Er:YAG laser may be superior to the Ho:YAG laser for precise ablation of strictures with minimal peripheral thermal damage and for more efficient laser lithotripsy. The Er:YAG laser cuts urethral and ureteral tissues more precisely than does the Ho:YAG laser, leaving a residual peripheral thermal damage zone of 30 +/- 10 microm compared with 290 +/- 30 microm for the Ho:YAG laser. This result may be important in the treatment of strictures, where residual thermal damage may induce scarring and result in stricture recurrence. The Er:YAG laser may represent an alternative to the cold knife and Ho:YAG laser in applications where minimal mechanical and thermal insult to tissue is required.

  15. Holmium fibre laser with record quantum efficiency

    SciTech Connect

    Kurkov, Andrei S; Sholokhov, E M; Tsvetkov, V B; Marakulin, A V; Minashina, L A; Medvedkov, O I; Kosolapov, A F

    2011-06-30

    We report holmium-doped fibre lasers with a Ho{sup 3+} concentration of 1.6 x 10{sup 19} cm{sup -3} and lasing wavelengths of 2.02, 2.05, 2.07 and 2.1 {mu}m at a pump wavelength of 1.15 {mu}m. The slope efficiency of the lasers has been measured. The maximum efficiency, 0.455, has been obtained at a lasing wavelength of 2.05 {mu}m. The laser efficiency is influenced by both the optical loss in the wing of a vibrational absorption band of silica and active-ion clustering. (lasers)

  16. Structure and surface properties of praseodymium modified alumina

    NASA Astrophysics Data System (ADS)

    Tankov, I.; Pawelec, B.; Arishtirova, K.; Damyanova, S.

    2011-10-01

    Mixed PrO 2-Al 2O 3 oxides with different PrO 2 content (1-20 wt.%) were prepared by wetness impregnation of γ-alumina with aqueous solution of praseodymium nitrate. The samples were characterized by different techniques, using surface adsorption-desorption of N 2 ( SBET), thermogravimetric analysis (TGA), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS), temperature-programmed reduction (TPR) and temperature-programmed desorption of CO 2 (TPD-CO 2). TGA and XRD showed the presence of small praseodymium oxide species on the alumina surface. XPS and DRS detected electron deficient interaction between deposited praseodymium oxide and alumina. It was observed a lower reduction temperature for supported Pr oxide species compared to that of the bulk Pr 6O 11. TPD-CO 2 studies suggested that the deposition of Pr oxide on alumina leaded to increase of the basicity of mixed oxides.

  17. Optical characterization of ZnO nanomaterial with praseodymium ions

    NASA Astrophysics Data System (ADS)

    Sharma, Y. K.; Pal, Sudha; Goyal, Priyanka; Bind, Umesh Chandra

    2016-05-01

    ZnO nanomaterial with praseodymium ions was prepared by chemical synthesis method. The ZnO nanomaterial was characterized by XRD, SEM and TEM. Their absorption in UV-VIS/NIR regions was measured at room temperature. The experimental oscillator strengths were calculated from the areas under the absorption bands. Eight absorption bands have been observed. From these spectral data various energy interaction parameters like Slater-Condon, Lande, Racah, Nephelauxetic ratio and bonding parameters have been computed. Judd-Ofelt analysis has been carried out using the absorption spectra to evaluate the radiative properties for luminescent levels of the praseodymium ion and discussed. The observed nano particle size is 2nm.

  18. The effective thermal conductivity of an adsorbent - Praseodymium cerium oxide

    NASA Technical Reports Server (NTRS)

    Secary, J. J.; Tong, T. W.

    1992-01-01

    The results of an experimental study to determine the effective thermal conductivity of praseodymium cerium oxide are reported. Praseodymium cerium oxide is an adsorbent used in the development of adsorption compressors for spaceborne refrigeration systems. A guarded-hot-plate apparatus was built for this study. Measurements were carried out for mean temperatures ranging from 300 to 600 C under a vacuum of 10 exp -5 torr. For the temperature range studied, the effective thermal conductivity increased from 0.14 to 0.76 W/m per C with increasing temperature, while displaying a cubic temperature dependency.

  19. Perspectives of holmium laser resection of the prostate: cutting effects with the holmium:YAG laser

    NASA Astrophysics Data System (ADS)

    Eichenauer, Rolf H.; Droege, Gerit; Brinkmann, Ralf; Neuss, Malte; Gafumbegete, Evariste; Jocham, Dieter

    1998-07-01

    Laser prostatectomy shows an improvement in peak urinary flow rates, in post-void residual urine volumes and also a symptomatic improvement when compared to the transurethral resection of the prostate (TUR-P). Time to achieve symptomatic improvement is delayed with many established laser procedures compared to standard resection. However, this disadvantage can be solved with a new resection technique using a pulsed holmium laser. Nevertheless, this advanced technique shows a few problems in a first clinical trial. Besides this clinical study, in vitro experiments were carried out in order to determine the optimal irradiation parameters with respect to resection rate, incision/ablation quality and handling. Prostate tissue of radical prostatectomies and chicken breast as model were irradiated with a pulsed holmium-laser in vitro with different laser parameters using a bare fiber in contact to tissue. The incision quality (depths and coagulation/vaporization effects) was analyzed with regard to pulse energy (speed of incision, angle of incision) and fiber diameter. Fast flash photography was performed to analyze thermo-mechanical side-effects. Fast flash photography reveals cavitation bubble up to 7 mm length in water and dissections in tissue. The ablation rate increases proportional to the laser pulse energy. The Holmium Laser Resection of the Prostate (HOLRP) in humans with available instrumentation right now shows equieffective results compared to the transurethral resection, no need for transfusion, no transurethral resection syndrome, short time for catheterization. Further technical approvement may significantly improve holmium laser prostate resection. We present a new application system for the laser resection.

  20. Discovery of cesium, lanthanum, praseodymium and promethium isotopes

    SciTech Connect

    May, E.; Thoennessen, M.

    2012-09-15

    Currently, forty-one cesium, thirty-five lanthanum, thirty-two praseodymium, and thirty-one promethium isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  1. Visible upconversion lasers in praseodymium-ytterbium-doped fibers

    NASA Astrophysics Data System (ADS)

    Zellmer, H.; Riedel, P.; Tünnermann, A.

    We report on a ZBLAN-fiber-based praseodymium-ytterbium-doped upconversion fiber laser operating in the blue-green with diffraction-limited beam quality. cw output powers of more than 150 mW at 491 nm are achieved for several hours without degradation. The spectroscopic data of the active material and laser parameters including the amplitude noise are discussed.

  2. DNA based materials doped with praseodymium (III) hydroxide nanoparticles

    NASA Astrophysics Data System (ADS)

    Lazar, Cosmina Andreea; Kajzar, François; Mihaly, Maria; Pirvu, Cristian; Petcu, Adina Roxana; Olteanu, Nicoleta Liliana; Rau, Ileana

    2016-06-01

    Lanthanide ions have attracted intense research interest for their luminescence properties, which make them interesting for applications such as bioactive probes for magnetic resonance and luminescence. We present here our study related to the interaction between DNA-CTMA (hexadecyltrimethylammonium chloride) and praseodymium. The new materials synthesized were investigated from photophysical properties and morphological point of view.

  3. Synthesis of phase pure praseodymium barium copper iron oxide.

    PubMed

    Konne, Joshua L; Davis, Sean A; Glatzel, Stefan; Hall, Simon R

    2013-06-18

    The control of crystallization of praseodymium barium copper iron oxide, an intermediate temperature solid oxide fuel cell cathode material, has been demonstrated for the first time using a biotemplated sol-gel synthesis technique. The results obtained showed significant improvement in purity, synthesis time, surface area and simplicity over that previously reported.

  4. Clinical research of holmium laser therapy in extramammary Paget's disease.

    PubMed

    Ziyao, Li; Deyong, Yang; Xiangyu, Che; Huafeng, Zong; Hafeez, Adnan; Jianbo, Wang; Xishuang, Song

    2014-11-01

    This study aims to investigate the safety and efficiency of the holmium laser therapy in extramammary Paget's disease. The clinical data of 61 patients was collected since 2002 to 2012, confirmed as non-subcutaneous invasive extramammary Paget's disease by biopsy and underwent surgery. All patients were divided into two groups. Group A included 30 patients who underwent the holmium laser therapy. Group B included 31 patients who underwent the traditional surgical therapy. The clinical data of all patients included preoperative, intraoperative, and postoperative management and follow-up records. Compared with the traditional operation group, the holmium laser group had a shorter operation time and was easier to perform. There were no significant differences between the two groups in cases of intraoperative and postoperative complications, the recurrence-free survival, and the disease-specific survival. But the holmium laser group had a longer recovery time than the traditional operation group in large and deep nidus. Multiple-factor analysis of prognostic parameters of 61 patients confirmed that any of these two methods chosen was not a prognostic parameter for recurrence-free survival. The holmium laser therapy might prove to be a preferable alternative to the traditional operative therapy of extramammary Paget's disease. However, the holmium laser therapy did not demonstrate to have an obvious advantage over traditional operative therapy in the recurrence-free survival and the disease-specific survival.

  5. Wavelength agile holmium-doped fiber laser

    NASA Astrophysics Data System (ADS)

    Simakov, N.; Daniel, J. M. O.; Ward, J.; Clarkson, W. A.; Hemming, A.; Haub, J.

    2016-03-01

    For the first time, an electronically-controlled, wavelength-agile tuneable holmium-doped fibre laser is presented. A narrow-band acousto-optic tuneable filter was characterized and used as the wavelength selective element to avoid any inertial effects associated with opto-mechanical tuning mechanisms. We demonstrate operation over a 90 nm wavelength range spanning 2040 - 2130 nm. The laser produced >150 mW over this entire range with a signal-to-noise ratio of >45 dB and line-width of ~0.16 nm. Switching times of ~35 μs and sweep rates of up to 9 nm/ms were also demonstrated.

  6. Midline Prostatic Cyst Marsupialization Using Holmium Laser

    PubMed Central

    Kilinc, Mehmet; Goger, Yunus Emre; Piskin, Mesut; Balasar, Mehmet; Kandemir, Abdulkadir

    2015-01-01

    Many of the prostatic cysts are asymptomatic and only 5% are symptomatic (Hamper et al., 1990; Higashi et al., 1990). These symptoms include pelvic pain, hematospermia, infertility, voiding dysfunction, prostatitis-like syndrome, and painful ejaculation. Treatment of prostatic cysts includes TRUSG guided drainage, endoscopic transurethral resection, and in some cases even open surgery. In the literature, endoscopic interventions use marsupialization of the midline prostatic cyst with transurethral resection (TUR) or transurethral incision with endoscopic urethrotomy (Dik et al., 1996; Terris, 1995). Holmium: YAG laser was employed for the marsupialization of the cyst wall in midline prostatic cyst treatment for the first time in the present study. Symptoms, treatment, and follow-up are presented in this paper. PMID:26101688

  7. Anti-inflammatory effects of praseodymium, gadolinium and ytterbium chlorides.

    PubMed

    Basile, A C; Hanada, S; Sertié, J A; Oga, S

    1984-02-01

    Anti-inflammatory effects of chloride salts of praseodymium, gadolinium and ytterbium were investigated, using various experimental inflammatory models in rats. The lanthanide salts administered by oral route showed no significant effect, but when injected intraperitoneally they significantly inhibited the carrageenin-induced oedema, proportional to their doses ranging from 15 to 75 mg/kg. They also reduced nystatin-induced oedema and vascular permeability response to histamine and serotonin. Pronounced inhibitory effect of lanthanide salts at the dose of 50 mg/kg, i.p., was observed in histamine- and serotonin-induced changes in vascular permeability. Repeated administration of lanthanide salts in the dose of 20 mg/kg for 13 d significantly inhibited arthritis development. The same dose of these salts for a 6-d period similarly reduced granuloma formation. However, praseodymium, gadolinium and ytterbium chlorides showed no significant difference among themselves and their anti-inflammatory effects were smaller than those from phenylbutazone.

  8. Use of the holmium:YAG laser in urology

    NASA Astrophysics Data System (ADS)

    Mattioli, Stefano

    1997-12-01

    The Holmium-YAG is a versatile laser with multiple soft- tissue applications including tissue incision and vaporization, and pulsed-laser applications such as lithotripsy. At 2140 nanometers, the wavelength is highly absorbed by tissue water. Further, like CO2 laser, the Holmium produces immediate tissue vaporization while minimizing deep thermal damage to surrounding tissues. It is an excellent instrument for endopyelotomy, internal urethrotomy, bladder neck incisions and it can be used to resect the prostate. The Holmium creates an acute TUR defect which gives immediate results like the TURP. More than 50 patients were treated from Jan. 1996 to Jan. 1997 for obstructive symptoms due to benign prostatic hyperplasia, bladder neck stricture, urethral stenosis, and superficial bladder tumors.

  9. Gain and energy storage in holmium YLF

    NASA Technical Reports Server (NTRS)

    Storm, Mark E.; Deyst, John P.

    1991-01-01

    It is demonstrated that Q-switched holmium lasers are capable of high-gain and high-energy operation at 300 K. Small-signal gain coefficients of 0.50 and 0.12/cm have been measured in YLF and YAG, respectively. Small-signal gains of 0.50/cm are comparable to those achievable in Nd:YAG and are not typical of low-gain materials. This large gain in the Ho:YLF material is made possible by operating the amplifier in the ground state depletion mode. The amplifier performance data and associated analysis presented demonstrate that efficient energy storage is possible with very high excited state ion densities of the Ho 5I7 upper laser level. This is an important result since upconversion can limit the 5I7 population. Although upconversion was still present in this experiment, it was possible to achieve efficient energy storage, demonstrating that the problem is manageable even at high excitation densities in YLF.

  10. High gain holmium-doped fibre amplifiers.

    PubMed

    Simakov, Nikita; Li, Zhihong; Jung, Yongmin; Daniel, Jae M O; Barua, Pranabesh; Shardlow, Peter C; Liang, Sijing; Sahu, Jayanta K; Hemming, Alexander; Clarkson, W Andrew; Alam, Shaif-Ul; Richardson, David J

    2016-06-27

    We investigate the operation of holmium-doped fibre amplifiers (HDFAs) in the 2.1 µm spectral region. For the first time we demonstrate a diode-pumped HDFA. This amplifier provides a peak gain of 25 dB at 2040 nm with a 15 dB gain window spanning the wavelength range 2030 - 2100 nm with an external noise figure (NF) of 4-6 dB. We also compare the operation of HDFAs when pumped at 1950 nm and 2008 nm. The 1950 nm pumped HDFA provides 41 dB peak gain at 2060 nm with 15 dB of gain spanning the wavelength range 2050 - 2120 nm and an external NF of 7-10 dB. By pumping at the longer wavelength of 2008 nm the gain bandwidth of the amplifier is shifted to longer wavelengths and using this architecture a HDFA was demonstrated with a peak gain of 39 dB at 2090 nm and 15 dB of gain spanning the wavelength range 2050 - 2150 nm. The external NF over this wavelength range was 8-14 dB. PMID:27410557

  11. Holmium:YAG laser stapedotomy: preliminary evaluation

    NASA Astrophysics Data System (ADS)

    Stubig, Ingrid M.; Reder, Paul A.; Facer, G. W.; Rylander, Henry G.; Welch, Ashley J.

    1993-07-01

    This study investigated the use of a pulsed Holmium:YAG ((lambda) equals 2.09 micrometers ) laser- fiber microsurgical system for laser stapedotomy. This system ablates human stapes bones effectively with minimal thermal damage. The study was designed to determine the effectiveness of the Ho:YAG laser (Schwartz Electro Optics, Inc., Orlando, FL) for stapedotomy and to evaluate temperature changes within the cochlea during the ablation process. Human cadaveric temporal bones were obtained and the stapes portion of the ossicular chain was removed. A 200 micrometers diameter low OH quartz fiber was used to irradiate these stapes bones in an air environment. The laser was pulsed at 2 Hz, 250 microsecond(s) ec pulse width and an irradiance range of 100 - 240 J/cm2 was used to ablate holes in the stapes footplate. The resultant stapedotomies created had smooth 300 micrometers diameter holes with a minimum of circumferential charring. Animal studies in-vivo were carried out in chinchillas to determine the caloric spread within the cochlea. A 0.075 mm Type T thermocouple was placed in the round window. Average temperature change during irradiation of the stapes footplate recorded in the round window was 3.6 degree(s)C. The data suggest that stapedotomy using the Ho:YAG laser can result in a controlled ablation of the stapes footplate with minimal thermal damage to the surrounding stapes. Optical coupling using fiberoptic silica fibers is an ideal method for delivering laser energy to the stapes during stapedotomy.

  12. Holmium:YAG laser coronary angioplasty in acute myocardial infarction

    NASA Astrophysics Data System (ADS)

    Topaz, On; Luxenberg, Michael; Schumacher, Audrey

    1994-07-01

    Patients who sustain complicated acute myocardial infarction in whom thrombolytic agents either fail or are contraindicated often need mechanical revascularization other than PTCA. In 24 patients with acute infarction complicated by continuous chest pain and ischemia who either received lytics or with contraindication to lytics, a holmium:YAG laser (Eclipse Surgical Technologies, Palo Alto, CA) was utilized for thrombolysis and plaque ablation. Clinical success was achieved in 23/24 patients, with 23 patients (94%) surviving the acute infarction. Holmium:YAG laser is very effective and safe in thrombolysis and revascularization in this complicated clinical setting.

  13. Gain-switched holmium-doped fibre laser.

    PubMed

    Wu, Ka S; Ottaway, David; Munch, Jesper; Lancaster, David G; Bennetts, Shayne; Jackson, Stuart D

    2009-11-01

    We demonstrate the first gain-switched, singly doped, single-mode holmium-doped silicate glass fibre laser that operates at 2.106 microm. Using a gain-switched 1.909-microm thulium-doped fibre laser as the pump source, output pulses of energy 3.2 microJ and pulse duration of 150 ns were generated at 80 kHz and slope efficiency of 44%. Pulse stacking within the holmium-doped fibre laser resulted in significantly shorter 70 ns pulses.

  14. Fabrication and properties of erbium oxide

    SciTech Connect

    Neuman, A.; Platero, M.; Romero, R.; McClellan, K.J.; Petrovic, J.J.

    1997-03-01

    Erbium oxide (Er{sub 2}O{sub 3}) is a rare earth oxide of interest because of its chemical and thermal stability and high melting point, 2,430 C. However, there is relatively little information available regarding the relation between the structure and the mechanical properties of this material. A densification study of polycrystalline erbium oxide powders is reported here. Erbium oxide pellets were uniaxially pressed (40--280 MPa) and sintered (1,500--1,800 C) in order to obtain density data for as-received commercial powders. In addition, the particle size and distribution of as-received powders were varied by milling and the effects on densification were studied. The powders were characterized for particle size, phase and impurity content and surface area. The mechanical properties of high density sintered erbium oxide bodies were characterized using indentation hardness and toughness as a function of temperature and microstructure. Relations between the microstructure and mechanical properties are described.

  15. [Synthesis, characterization and NIR luminescence properties of erbium organic complexes].

    PubMed

    Wang, Huai-shan; Qian, Guo-dong; Wang, Min-quan; Luo, Yong-shi; Lin, Jiu-ling

    2005-03-01

    Several erbium organic complexes, hydrated erbium binary complexes with acetylacetone (AcAc) or dibenzoylmethane (DBM), erbium ternary complexes derived from 1,10-phenanthroline (Phen) with acetylacetone (AcAc), dibenzoylmethane (DBM) or trifluoroacetylacetone (TFA), were synthesized and identified by elemental analysis. The UV-Vis absorption and FTIR spectra measurements have been employed for all the erbium complexes. Near infrared (NIR) photoluminescence properties, such as luminescence intensity and effective bandwidth, of the erbium complexes were also studied. As a result, the erbium ternary complex with AcAc and Phen exhibits the most excellent luminescence properties among those investigated complexes.

  16. Resonant magnetic scattering in holmium at an undulator source

    SciTech Connect

    Gruebel, G.; Als-Nielsen, J.; Vettier, C.; Gibbs, D.; Bohr, J.; Pengra, D.

    1994-06-01

    The resonance properties of the magnetic cross section of antiferromagnetic holmium were studied at the L absorption edges. A polarization analysis of the magnetic cross section was performed at the L{sub III} and L{sub II} edges using {pi} polarized incident x-rays.

  17. Synthesis, characterization, and neutron activation of holmium metallofullerenes

    SciTech Connect

    Cagle, D.W.; Thrash, T.P.; Wilson, L.J.; Alford, M.; Chibante, L.P.F.; Ehrhardt, G.J.

    1996-08-28

    Isolation of the first macroscopic quantities of endohedral holmium metallofullerenes (principally Ho@C{sub 82}, Ho{sub 2}@C{sub 82}, and Ho{sub 3}@C{sub 82} by LD-TOF mass spectrometry) has been accomplished by carbon-arc and preparative HPLC methodologies. The detailed procedure for production and isolation of the metallofullerenes includes a new technique whereby holmium-impregnated electrodes are prepared simply by soaking porous graphite rods in an ethanolic solution of Ho(NO{sub 3}){sub 3}.xH{sub 2}O. Monoisotopic {sup 165}Ho offers a unique combination of advantages for neutron-activation studies of metallofullerenes, and purified samples containing {sup 165}Ho@C{sub 82}, {sup 165}Ho{sub 2}@C{sub 82}, and {sup 165}Ho{sub 3}@C{sub 82} have been activated by high-flux neutron irradiation ({Phi} = 4 x 10{sup 13}n cm{sup -2} s{sup -1}) to generate {sup 166}Ho metallofullerenes, which undergo {beta}{sup -} decay to produce stable {sup 166}Er. Chemical workup of the irradiated samples, followed by re-irradiation, has been used to demonstrate that observed decomposition of holmium metallofullerenes is due mainly to `fast` neutron damage rather than to holmium atom nuclear recoil (E{sub max} = 200 eV). This implies that metallofullerene damage can be minimized by using neutron fluxes with the highest possible thermal component. 60 refs., 4 figs.

  18. Spectral performance of monolithic holmium and thulium lasers

    NASA Technical Reports Server (NTRS)

    Storm, Mark E.

    1991-01-01

    Fabry-Perot resonators have been used to demonstrate single-mode lasing of holmium and neodymium YAG. The previous demonstration in the holmium laser required TE cooling the crystal to -15 C in order to achieve threshold. The present study extends that result, demonstrating +25 C operation in a 1-mm thick plano/plano resonator. The experimental configuration of lasing both the holmium and thulium lasers used a 500-mW diode laser which was collimated, circularized, and focused into a beam radius of 60 microns. The single-frequency lasing spectrum of the holmium laser is shown. By adjusting the mirror reflectivity, the ability to control the laser's wavelength is demonstrated. This laser operated with 11 mW of optical power, a 57-percent slope efficiency, and 120-mW threshold vs absorbed diode power laser for the 60-micron beam radius. The thulium laser operated very efficiently at room temperature, but on seven longitudinal modes. The Tm:TAG laser exhibits typical characteristics of spatial hole burning not seen in the Ho:Tm:YAG for flat/flat resonators.

  19. Holmium:YAG laser in the treatment of ureteral strictures

    NASA Astrophysics Data System (ADS)

    Singal, Rajiv K.; Razvi, Hassan A.; Chun, Samuel S.; Denstedt, John D.; Sales, Jack L.

    1996-05-01

    Endourologic intervention has become widely considered the initial procedure of choice for short segment ureteral strictures. Techniques employed in conjunction with endourologic access to manage the strictured area have included balloon dilation, cold knife and electrosurgical incision. More recently laser incision with the potassium titanyl phosphate (KTP) laser has been employed. The holmium:YAG laser with a wavelength of 2100 nm has recently become available for urologic use. This wavelength is able to precisely vaporize and incise tissue. In this presentation we describe our results with holmium:YAG laser incision of ureteral strictures. Seventeen patients were treated including 12 patients with distal ureteral strictures, 4 patients with ureteroileal anastomotic strictures and 1 patient with a stricture in the ureter of a transplanted kidney. The holmium:YAG laser was employed using a 400 (mu) end-firing quartz fiber placed in contact with the tissue. Clinical and radiologic follow-up of at least 3 months post-surgery (range 3 - 21 months) is available in 14 patients. At last follow-up in these patients, 10/14 (71%) of strictures have remained open. While the ultimate success of endourological techniques of stricture management are determined by the inherent nature of the stricture rather than the technique employed, the holmium:YAG laser for endoureterotomy demonstrates short term efficacy and safety comparable to that reported for other minimally- invasive techniques of stricture management.

  20. [Acute liver injury in rats by praseodymium nitrate (author's transl)].

    PubMed

    Schriewer, H; Gebauer, B; Rauen, H M

    1976-01-01

    After acute intoxication with praseodymium nitrate (10 mg/kg body weight i.v.), time functions of enzyme activities of GOT, GPT, ChE, AP and of free fatty acids concentration in rat serum were analysed and the results subjected to significance and correlation analysis. Time functions of free fatty acids concentration corresponded with those of enzyme activities of GOT and GPT. In the early state of intoxication serum concentrations of palmitoleinic and oleic acid were more increased than those of stearinic acid. There seems to be an alteration in the correlations of analysed measures with regard to their temporal changes parallel to the progress of intoxication.

  1. High pressure structural studies on nanophase praseodymium oxide

    NASA Astrophysics Data System (ADS)

    Saranya, L.; Chandra Shekar, N. V.; Amirthapandian, S.; Hussain, Shamima; Arulraj, A.; Sahu, P. Ch.

    2014-09-01

    The phase stability of nanocrystalline Pr2O3 has been investigated under pressure by in-situ high pressure X-ray diffraction using Mao-Bell type diamond anvil cell. The ambient structure and phase of the praseodymium oxide have been resolved unambiguously using x-ray diffraction, SEM and TEM techniques. Under the action of pressure the cubic phase of the system is retained up to 15 GPa. This is unusual as other isostructural rare earth oxides show structural transformations even at lower pressures. From the best fit to the P-V data with the Murnaghan equation of state yields a bulk modulus of 171 GPa.

  2. 4f electron delocalization and volume collapse in praseodymium metal

    SciTech Connect

    Bradley, Joseph A.; Moore, Kevin T.; Lipp, Magnus J.; Mattern, Brian A.; Pacold, Joseph I.; Seidler, Gerald T.; Chow, Paul; Rod, Eric; Xiao, Yuming; Evans, William J.

    2012-04-17

    We study the pressure evolution of the 4f electrons in elemental praseodymium metal compressed through several crystallographic phases, including the large volume-collapse transition at 20 GPa. Using resonant x-ray emission, we directly and quantitatively measure the development of multiple electronic configurations with differing 4f occupation numbers, the key quantum observable related to the delocalization of the strongly correlated 4f electrons. These results provide a high-fidelity test of prior predictions by dynamical mean-field theory, and support the hypothesis of a strong connection between electronic and structural degrees of freedom at the volume-collapse transition.

  3. Nonaaqua-praseodymium triiodide-thio-urea (1/2).

    PubMed

    Antonenko, Taisia A; Alikberova, Lyudmila Yu; Albov, Dmitry V

    2012-02-01

    The title compound, [Pr(H(2)O)(9)]I(3)·2CS(NH(2))(2), an adduct of nona-aqua-praseodymium triiodide with two thio-urea mol-ecules, is composed from [Pr(H(2)O)(9)](3+) cations (polyhedron: monocapped tetra-gonal anti-prism), noncoordinated thio-urea mol-ecules and iodide anions. The components are evidently connected by hydrogen bonds but in the presence of heavy atoms water H atoms have not been located. The complex cation and one of the two independent iodide anions are located on a twofold axis.

  4. Serum ornithine carbamoyltransferase (OCT) in rats poisoned with lanthanum, cerium and praseodymium.

    PubMed

    Marciniak, M; Bałtrukiewicz, Z

    1977-01-01

    Serum ornithine carbamoyltransferase (OCT) in rats poisoned with lanthanum, cerium and praseodymium. Acta Physiol. Pol., 1977, 28 (6): 589-594. The serum ornithine carbamoyltransferase in relation to doses of lanthanum, cerium and praseodymium, administered intravenously as chlorides, was investigated. A directly proportional relationship was found between the doses of these compounds and the serum enzyme level in rats. The lowest doses at which a rise in the serum OCT level occured were determined. They were: lanthanum - 0.75 mg/kg of body weight, cerium - 1.5 mg/kg, and praseodymium - 3 mh/kg. A decreasing toxicity of these elements with increasing value of atomic number was observed.

  5. Erbium-doped aluminophosphosilicate optical fibres

    SciTech Connect

    Likhachev, M E; Bubnov, M M; Zotov, K V; Medvedkov, O I; Lipatov, D S; Yashkov, M V; Gur'yanov, Aleksei N

    2010-09-10

    We have studied the active properties of erbium-doped aluminophosphosilicate (APS) core fibres in wide ranges of erbia, alumina and phosphorus pentoxide concentrations. The absorption and luminescence spectra of the P{sub 2}O{sub 5}- or Al{sub 2}O{sub 3}-enriched erbium-doped APS fibres are shown to be similar to those of the erbium-doped fibres singly doped with phosphorus pentoxide or alumina, respectively. The formation of AlPO{sub 4} in APS fibres leads not only to a reduction in the refractive index of the glass but also to a marked increase in Er{sub 2}O{sub 3} solubility in silica. (optical fibres)

  6. Resonance ionization of holmium for ion implantation in microcalorimeters

    NASA Astrophysics Data System (ADS)

    Schneider, F.; Chrysalidis, K.; Dorrer, H.; Düllmann, Ch. E.; Eberhardt, K.; Haas, R.; Kieck, T.; Mokry, C.; Naubereit, P.; Schmidt, S.; Wendt, K.

    2016-06-01

    The determination of the electron neutrino mass by calorimetric measurement of the 163 Ho electron capture spectrum requires ultra-pure samples. Several collaborations, like ECHo or HOLMES, intend to employ microcalorimeters into which 163 Ho is implanted as an ion beam. This makes a selective and additionally very efficient ion source for holmium mandatory. For this purpose, laser resonance ionization of stable holmium 165 Ho was studied, using a three step excitation scheme driven by pulsed Ti:sapphire lasers. Five measurements with sample sizes of 1014 and 1015 atoms were performed for the efficiency investigation. In average, an excellent ionization efficiency of 32(5) % could be shown, demonstrating the suitability for ion beam implantation.

  7. Near-equilibrium polymorphic phase transformations in Praseodymium under dynamic compression

    SciTech Connect

    Bastea, M; Reisman, D

    2007-02-12

    We report the first experimental observation of sequential, multiple polymorphic phase transformations occurring in Praseodymium dynamically compressed using a ramp wave. The experiments also display the signatures of reverse transformations occuring upon pressure release and reveal the presence of small hysteresys loops. The results are in very good agreement with equilibrium hydrodynamic calculations performed using a thermodynamically consistent, multi-phase equation of state for Praseodymium, suggesting a near-equilibrium transformation behavior.

  8. Holmium laser with an acousto-optic paratellurite filter

    NASA Astrophysics Data System (ADS)

    Mukhin, A. V.; Velikanov, S. D.; Glukhodedov, V. D.; Zakharov, N. G.; Frolov, Yu N.

    2016-08-01

    Experimental results on a solid-state holmium laser (Ho : YAG) with an intracavity acousto-optic paratellurite filter are presented. The laser power in cw and repetitively pulsed regimes is determined experimentally. It is shown that the use of an acoustooptic filter in the Ho : YAG laser cavity makes it possible to solve several important problems such as obtaining repetitively pulsed lasing, wavelength tuning and linearly polarised emission.

  9. Radioisotope synoviorthesis with Holmium-166-chitosan complex in haemophilic arthropathy.

    PubMed

    Cho, Y J; Kim, K I; Chun, Y S; Rhyu, K H; Kwon, B K; Kim, D Y; Yoo, M C

    2010-07-01

    Radiosynoviorthesis is a safe and easy method for synovectomy in haemophilic arthropathy. Various agents have been used in radiosynoviorthesis, especially newly developed agent Holmium-166-chitosan complex has good clinical outcome. This study analysed clinical results and radiologic evaluation of radioisotope synoviorthesis using Holmium-166-chitosan complex in haemophilic arthropathy. From March 2001 to December 2003, 58 radiosynoviorthesis were performed in 53 haemophiliacs. The average age at procedure was 13.8 years. The Arnold and Hilgartner stage of the patients was from I to IV. Holmium-166-chitosan complex was injected in 31 ankle joints, 19 elbow joints and 8 knee joints. Average follow-up was 33 months since primary procedure. The range of motion of each joint, frequency of intra-articular bleeding and factor dose used were analysed for clinical assessment. There was no significant improvement of range of motion in affected joints. After procedure, the average frequency of bleeding of the elbow joint has decreased from 3.76 to 0.47 times per month, the knee joint from 5.87 to 1.12 times per month, and the ankle joint from 3.62 to 0.73 times per month respectively (P < 0.05). After treatment, the average coagulation factor dose injected was significantly decreased to 779.3 units per month from 2814.8 units per month before treatment (P < 0.001). Radioisotope synoviorthesis with Holmium-166-chitosan complex in haemophilic arthropathy is a very safe and simple procedure with the expectation of a satisfactory outcome without serious complication. It has excellent bleeding control effect on target joint and the need for substitution of coagulation factor concentrate can be reduced.

  10. Hard and fragile holmium-based bulk metallic glasses

    SciTech Connect

    Luo, Q.; Zhao, D.Q.; Pan, M.X.; Wang, R.J.; Wang, W.H.

    2006-05-01

    A family of holmium-based bulk metallic glasses (BMGs) with high glass-forming ability is obtained. The Ho-based BMGs exhibit much larger elastic moduli and high thermal stability in contrast to other known rare-earth (RE)-based BMGs. In particular, the BMGs show a large value of fragility. It is expected that the hard RE-based glasses with high glass-forming ability and fragile behaviors make them the appropriate candidate for glass transition study.

  11. Erbium hydride thermal desorption : controlling kinetics.

    SciTech Connect

    Ferrizz, Robert Matthew

    2007-08-01

    Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report show that hydride film processing parameters directly impact thermal stability. Issues to be addressed include desorption kinetics for dihydrides and trihydrides, and the effect of film growth parameters, loading parameters, and substrate selection on desorption kinetics.

  12. Evolution of the use of the holmium laser for the treatment of benign prostatic hyperplasia

    NASA Astrophysics Data System (ADS)

    Gilling, Peter J.; Cass, Carol B.; Cresswell, Michael D.; Kennett, Katie M.; Mackey, Michael; Fraundorfer, Mark R.; Kabalin, John N.

    1997-05-01

    The holmium laser is becoming an important tool in the urologists' armamentarium. In this manuscript the evolution of laser resection of the prostate using the holmium wavelength is described. This technique represents a significant advance in the surgical management of benign prostatic hyperplasia and allows even very large prostates to be safely and efficiently managed transurethrally.

  13. X-ray resonant magnetic scattering investigations of hexagonal multiferroics R-manganese oxide (R = dysprosium, holmium, erbium)

    NASA Astrophysics Data System (ADS)

    Nandi, Shibabrata

    This dissertation is concerned with the magnetic structure of hexagonal multiferroic compounds RMnO3 (R = Ho, Dy, Er) in both zero and applied electric field. Microscopic magnetic structures in zero field were studied using x-ray resonant magnetic scattering (XRMS). Magnetic structure in applied electric field was studied using bulk magnetization, x-ray resonant magnetic scattering (XRMS), and x-ray magnetic circular dichroism (XMCD). The magnetic structures of Ho, Dy, and Er members have been determined using high-quality single-crystal samples grown by optical floating zone technique. We have determined that the magnetic structure of Ho3+ in HoMnO 3 to be Gamma3 in the intermediate temperature magnetic phase ITP (between 40 K and 4.5 K). The magnetic Ho3+ moments are aligned along the c axis and, at 12 K, the ratio between the magnetic moments of the Ho(2a) and Ho(4b) Wyckoff site is ˜ -2. The moments at the Ho(2a) site are antiferromagnetically aligned to the moments at the Ho(4b) site in the a-b plane. We also conclude that there is a change of the magnetic structure of Ho3+ at 4.5 K. Below 4.5 K, the magnetic phase can be well described by the co-existence of the ITP (Gamma3) with a decreasing 'ordered moment' and a new magnetic phase LTP with magnetic representation Gamma1 with a rapidly increasing Ho (4b) moment for decreasing temperatures. We failed to observe resonant magnetic scattering from Mn K-edge due to the presence of non-magnetic anisotropic tensor scattering at the magnetic Bragg peaks. Therefore, existence of a c component of the Mn3+ moments, predicted by symmetry analysis, can not be tested. We have also determined the magnetic structures of Dy3+ and Er3+ moments in DyMnO3 and ErMnO3, respectively. Dy3+ moments order according to the magnetic representation Gamma3 in the intermediate temperature magnetic phase, ITP (between 68 K and 8 K). In the low temperature phase, LTP (below 8 K), XRMS together with magnetization measurements indicate that Gamma 2 is the magnetic representation and the Dy3+ moments are ferrimagnetically aligned in the hexagonal c direction. For ErMnO 3, we conclude that no ITP exists and the Er3+ moments order ferrimagnetically below 3 K according to magnetic representation Gamma 2. We note that the magnetic structure in DyMnO3 is the same as in HoMnO3 in the ITP, however, in the LTP the magnetic order is different: the Ho3+ moments are antiferromagnetically aligned according to Gamma1 in contrast to the ferromagnetic alignment of the Dy3+ moments in DyMnO3. For both the Ho 3+ and Dy3+, magnetism in the ITP can be explained assuming an exchange interaction between R3+ and Mn 3+ and a crystal electric field splitting of the R3+ ground state quasidoublet/doublet. The crystal electric field splitting for Dy is ˜6 meV and that of Ho is ˜1.3 meV. From the extensive single crystal SQUID magnetization, XRMS and XMCD as well as XMCD on powder samples for two different hexagonal multiferroics, HoMnO3 and DyMnO3, we conclude that electric field up to 1x107 V/m does not change the magnetic structure of Ho 3+ moments.

  14. Pseudo-merohedrally twinned praseodymium hexacyanoferrate(III) tetrahydrate.

    PubMed

    Langer, Vratislav; Smrcok, Lubomír; Masuda, Yoshio

    2004-11-01

    Crystals of the title compound, diaquahexa-mu-cyano-ferrate(III)praseodymium(III) dihydrate, Pr[Fe(CN)(6)].4H(2)O or [PrFe(CN)(6)(H(2)O)(2)].2H(2)O, are twinned with three components. The Pr atom is coordinated by eight atoms, viz. six N and two symmetry-related water O atoms. The Pr polyhedron (Pr has site symmetry m2m, Wyckoff position 4c) is linked to an FeC(6) octahedron (Fe located on a site with imposed 2/m symmetry, Wyckoff position 4b) through N atoms, forming an infinite array. The second (symmetry independent) water molecule lies on a mirror plane, is not included in coordination and is weakly hydrogen bonded to N atoms.

  15. Buckshot colic: utilizing holmium:yag laser for ureteroscopic removal of a bullet fragment within the proximal ureter.

    PubMed

    Ziegelmann, Matthew; Carrasco, Alonso; Knoedler, John; Krambeck, Amy E

    2016-06-01

    Buckshot colic is a rare phenomenon, presenting as firearm-induced urinary tract obstruction. We present a case of gunshot-induced ureteral obstruction in a 49-year-old male, treated endoscopically with the holmium:YAG (holmium) laser. CT revealed a 1 cm bullet fragment within the left proximal ureter. A percutaneous nephrolithotomy was performed utilizing the holmium laser to fragment the metal into basket-retrievable pieces. At 4 month follow up the patient is without evidence of stricture. To our knowledge, this is the first reported utilization of the holmium laser to treat "buckshot colic". Endoscopy with holmium laser appears a feasible and safe treatment option. PMID:27347630

  16. Intracorporeal lithotripsy with the holmium:YAG laser

    NASA Astrophysics Data System (ADS)

    Denstedt, John D.; Razvi, Hassan A.; Chun, Samuel S.; Sales, Jack L.

    1995-05-01

    A variety of devices are currently available for intracorporeal stone fragmentation. Recently a new wavelength of laser, the Holmium:YAG, has demonstrated a variety of potential urologic applications including ablation of soft tissue lesions as well as stone fragmentation. This laser has a wavelength of 2100 nm and operates in a pulsed mode. Energy is delivered through a 400 um quartz end-firing fiber. In this presentation we review our clinical experience with the Holmium:YAG laser for the treatment of renal and ureteral calculi. Over a 23 month period, 63 patients underwent 67 procedures. Seven procedures consisted of percutaneous nephrolithotripsy for large or staghorn renal calculi. Sixty procedures were performed for ureteral stones. Procedures for proximal ureteral stones (6) employed a retrograde approach using flexible ureteroscopes (8.5 or 9.8). Stones in the mid ureter (12) and distal ureter (42) were approached transurethrally using a 6.9 rigid ureteroscope. Complete stone fragmentation without the need for additional procedures was achieved in 82% of cases. Treatment failures included 1 stone migration into the renal pelvis during laser activation, 6 patients who had incomplete fragmentation and 3 patients in which laser malfunction precluded complete fragmentation. Stone analysis available in 23 patients revealed calcium oxalate monohydrate (15), calcium oxalate dihydrate (2), cystine (2), uric acid (3) and calcium phosphate (1). A single complication of ureteral perforation occurred when the laser was fired without direct visual guidance. Radiographic follow-up at an average of 16 weeks is available in 22 patients and has identified 2 patients with ureteral strictures that are not believed to be related to laser lithotripsy. In summary, we have found the Holmium:YAG laser to be a reliable and versatile device for intracorporeal lithotripsy. Its safety and efficacy make it a suitable alternative for performing intracorporeal lithotripsy of urinary

  17. Evolution and success of holmium laser enucleation of the prostate

    PubMed Central

    Krambeck, Amy E.

    2010-01-01

    Aims: The purpose of this article is to review the development of instruments, current technique, and expected outcomes for holmium laser enucleation of the prostate (HoLEP). Materials and Methods: A review of published, peer-reviewed articles focusing on HoLEP was performed using the MEDLINE database. Results: Historically, the gold-standard management for symptomatic obstructing benign prostatic hyperplasia (BPH) has been transurethral resection of the prostate (TURP). With the development of new laser technology minimally invasive surgical procedures have been introduced in an attempt to decrease the morbidity experienced with standard TURP. Laser treatment of BPH has evolved from coagulation to complete adenoma enucleation. The holmium laser was initially utilized for prostate ablation and soon evolved into holmium laser tissue resection, but was limited by difficulties with extracting the prostate tissue from the bladder. With the development of a compatible tissue morcellator whole prostate lobes could be enucleated similar to an open prostate enucleation and the HoLEP procedure was developed. Currently HoLEP is the only procedure to demonstrate superior outcomes to TURP on urodynamic studies and long-term studies demonstrate its durability up to 7 years post procedure. Changes in enucleation technique have also increased the efficiency of the HoLEP procedure, such that any sized prostate can be treated. Conclusions: HoLEP is a safe and effective surgical treatment for symptomatic BPH, dependent on a high powered laser and morcellation system. The procedure continues to gain acceptance due to excellent short and long-term results, its wide application, and further simplification of technique. PMID:21116363

  18. Erbium doped tellurite photonic crystal optical fiber

    NASA Astrophysics Data System (ADS)

    Osorio, Sergio P.; Fernandez, Enver; Rodriguez, Eugenio; Cesar, Carlos L.; Barbosa, Luiz C.

    2005-04-01

    In this work we present the fabrication of tellurite glass photonic crystal fiber doped with a very large erbium concentration. Tellurite glasses are important hosts for rare earth ions due to its very high solubility, which allows up to 10,000 ppm Er3+ concentrations. The photonic crystal optical fibers and tellurite glasses can be, therefore, combined in an efficient way to produce doped fibers for large bandwidth optical amplifiers. The preform was made of a 10 mm external diameter tellurite tube filled with an array of non-periodic tellurite capillaries and an erbium-doped telluride rod that constitute the fiber core. The preform was drawn in a Heathway Drawing Tower, producing fibers with diameters between 120 - 140 μm. We show optical microscope photography of the fiber"s transverse section. The ASE spectra obtained with a spectra analyzer show a red shift as the length of the optical fiber increases.

  19. Hybrid quantum circuit with implanted erbium ions

    SciTech Connect

    Probst, S.; Rotzinger, H.; Tkalčec, A.; Kukharchyk, N.; Wieck, A. D.; Wünsch, S.; Siegel, M.; Ustinov, A. V.; Bushev, P. A.

    2014-10-20

    We report on hybrid circuit quantum electrodynamics experiments with focused ion beam implanted Er{sup 3+} ions in Y{sub 2}SiO{sub 5} coupled to an array of superconducting lumped element microwave resonators. The Y{sub 2}SiO{sub 5} crystal is divided into several areas with distinct erbium doping concentrations, each coupled to a separate resonator. The coupling strength is varied from 5 MHz to 18.7 MHz, while the linewidth ranges between 50 MHz and 130 MHz. We confirm the paramagnetic properties of the implanted spin ensemble by evaluating the temperature dependence of the coupling. The efficiency of the implantation process is analyzed and the results are compared to a bulk doped Er:Y{sub 2}SiO{sub 5} sample. We demonstrate the integration of these engineered erbium spin ensembles with superconducting circuits.

  20. Brillouin-Erbium fiber laser with enhanced feedback coupling using common Erbium gain section.

    PubMed

    Samsuri, N M; Zamzuri, A K; Al-Mansoori, M H; Ahmad, A; Mahdi, M A

    2008-10-13

    We demonstrate an enhanced architecture of Brillouin-Erbium fiber laser utilizing the reverse-S-shaped fiber section as the coupling mechanism. The enhancement is made by locating a common section of Erbium-doped fiber next to the single-mode fiber to amplify the Brillouin pumps and the oscillating Stokes lines. The requirement of having two Erbium gain sections to enhance the multiple Brillouin Stokes lines generation is neglected by the proposed fiber laser structure. The mode competitions arise from the self-lasing cavity modes of the fiber laser are efficiently suppressed by the stronger pre-amplified Brillouin pump power before entering the single mode fiber section. The maximum output power of 20 mW is obtained from the proposed fiber laser with 10 laser lines that equally separated by 0.089 nm spacing.

  1. The influence of silybin on the hepatotoxic and hypoglycemic effects of praseodymium and other lanthanides.

    PubMed

    Strubelt, O; Siegers, C P; Younes, M

    1980-01-01

    In rats, i.v. administration of praseodymium, cerium and lanthanum (3 to 14 mg/kg) produced a dose-dependent increase in the serum activities of GOT, GPT and SDH. These dose-response curves of serum enzyme activities were shifted to the right by simultaneous treatment with silybin (75 mg/kg i.p.). Silybin also attenuated the increase of bromosulphthaleine retention and prevented the accumulation of liver triglycerides induced by praseodymium (7 mg/kg i.v.). Furthermore, silybin reduced the mortality rate of rats treated with high doses of the lanthanides. Rats treated with praseodymium (7 mg/kg i.v.) developed a pronounced hypoglycemia. On the 3rd day after praseodymium injection liver glycogen decreased to 4%, liver glutathione (GSH) to 82%, hepatic microsomal cytochrome P-450 content to 53%, aniline hydroxylase activity to 58% and aminophenazone demethylase activity to 40% of the control values. Silybin prevented praseodymium-induced hypoglycemia completely and the changes in the biochemical parameters of liver function partially but did not influence the decrease of liver GSH.

  2. Magnetoelastic nature of the dodecagonal anisotropy in holmium metal.

    PubMed

    Benito, L; Ciria, M; Fraile, A; Fort, D; Abell, J S; Arnaudas, J I

    2007-06-29

    We have investigated the magnetoelastic nature of the dodecagonal anisotropy in the magnetic anisotropy energy (MAE) in the basal plane of the hcp crystalline structure in holmium single crystal. We have proved that the origin of the second harmonic of the hexagonal symmetry in MAE clearly lies on a sixth-order magnetoelastic coupling term. The appearance of a 12-fold anisotropy in MAE in a single crystal having hexagonal symmetry provides a new insight on how the magnetic anisotropy can be modified in a magnetic material with giant spin-lattice coupling.

  3. The magnetic properties of potassium holmium double tungstate

    NASA Astrophysics Data System (ADS)

    Borowiec, M. T.; Dyakonov, V. P.; Khatsko, E. N.; Zayarnyuk, T.; Zubov, E. E.; Szewczyk, A.; Gutowska, M. U.; Rykova, A. I.; Pietosa, J.; Majchrowski, A.; Michalski, E.; Hoffmann, J.-U.; Prokes, K.; Woźniak, K.; Dobrzycki, Ł.; Barański, M.; Domukhovski, V.; Shtyrkhunova, V.; Żmija, J.; Szymczak, H.

    2011-08-01

    The magnetic investigations of potassium holmium double tungstate KHo(WO4)2 have been performed. The results of measurements of magnetic susceptibility and magnetization as a function of temperature (T from 0.3 K up to 100 K) and magnetic field (up to 1.5 T) are presented. A strong anisotropy of magnetic properties was found. The magnetic measurements data were used to calculate the interaction energy. It was shown that the interactions between nearest neighbors Ho3+ ions have antiferromagnetic character.

  4. Drug metabolism: Comparison of biodistribution profile of holmium in three different compositions in healthy Wistar rats.

    PubMed

    Cerqueira-Coutinho, Cristal; Vidal, Lluis Pascual; Pinto, Suyene Rocha; Santos-Oliveira, Ralph

    2016-06-01

    Radioisotope holmium is a candidate to be used in cancer treatment and diagnosis. There are different holmium salts and they present distinct solubility and consequently different biodistribution profiles. In this work, we aimed to evaluate the biodistribution profiles of two holmium salts (chloride and sulfate) and holmium nanoparticles (oxide) through an in vivo biodistribution assay using animal model. Samples were labeled with technetium-99m and administered in Wistar rats by retro-orbital route. Holmium chloride is highly soluble in water and it was quickly filtered by the kidneys while holmium sulfate that presents lower solubility in water was mainly found in the liver and the spleen. However, both the salts showed a similar biodistribution profile. On the other hand, holmium oxide showed a very different biodistribution profile since it seemed to interact with all organs. Due to its particle size range (approximately 100nm) it was not intensively filtered by the kidneys being found in high quantities in many organs, for this reason its use as a nanoradiopharmaceutical could be promising in the oncology field. PMID:26986812

  5. The studies on the aromaticity of fullerenes and their holmium endohedral compounds.

    PubMed

    Tan, Bisheng; Peng, Rufang; Li, Hongbo; Wang, Bing; Jin, Bo; Chu, Shijin; Long, Xinping

    2011-02-01

    Density functional theory BLYP/DNP was employed to optimize a series of fullerenes and their holmium endohedral compounds, including C(20), Ho@C(20), Ho(3+)@C(20), C(60), Ho@C(60), Ho(3+)@C(60),C(70), Ho@C(70), Ho(3+)@C(70) C(78), Ho@C(78), Ho(3+)@C(78), C(82),Ho@C(82) and Ho(3+)@C(82). DFT semi core pseudospot approximation was taken into consideration in the calculations of the element holmium because of its particular electronic structure. Fullerenes and their holmium endohedral compounds' aromaticity were studied in terms of structural criteria, energetic criteria, and reactivity criteria. The results indicate that the aromaticity of fullerenes was reduced when a holmium atom was introduced into the carbon cage, and the endohedral fullerenes' reactive activity enhance; but the aromaticity of the carbon cage increased when a Ho(3+) cation was encapsulated into a fullerene. Calculations of aromaticity and stability indicate that two paths can lead to the similar aim of preparing holmium endohedral fullerenes; that is, they can form from either a holmium atom or a holmium cation (Ho(3+)) reacting with fullerenes, respectively, and the latter is more favorable.

  6. Drug metabolism: Comparison of biodistribution profile of holmium in three different compositions in healthy Wistar rats.

    PubMed

    Cerqueira-Coutinho, Cristal; Vidal, Lluis Pascual; Pinto, Suyene Rocha; Santos-Oliveira, Ralph

    2016-06-01

    Radioisotope holmium is a candidate to be used in cancer treatment and diagnosis. There are different holmium salts and they present distinct solubility and consequently different biodistribution profiles. In this work, we aimed to evaluate the biodistribution profiles of two holmium salts (chloride and sulfate) and holmium nanoparticles (oxide) through an in vivo biodistribution assay using animal model. Samples were labeled with technetium-99m and administered in Wistar rats by retro-orbital route. Holmium chloride is highly soluble in water and it was quickly filtered by the kidneys while holmium sulfate that presents lower solubility in water was mainly found in the liver and the spleen. However, both the salts showed a similar biodistribution profile. On the other hand, holmium oxide showed a very different biodistribution profile since it seemed to interact with all organs. Due to its particle size range (approximately 100nm) it was not intensively filtered by the kidneys being found in high quantities in many organs, for this reason its use as a nanoradiopharmaceutical could be promising in the oncology field.

  7. Erbium-doped-fiber optical limiting amplifiers

    NASA Astrophysics Data System (ADS)

    Graydon, Oliver C.; Nickolaos Zervas, Michael; Laming, Richard I.

    1995-05-01

    A novel configuration of an erbium-doped-fiber optical output-limiting amplifier (OLA) is presented which is realized by simply introducing a differential lump-loss between the signal and the pump power at a particular point along the fiber. The OLA exhibits an input-power dynamic range in excess of 40 dB and the capacity to control optically the level of the constant-output signal.

  8. Characterization of the surface changes during the activation of erbium/erbium oxide for hydrogen storage.

    SciTech Connect

    Zavadil, Kevin Robert; Snow, Clark Sheldon; Brumbach, Michael Todd

    2010-09-01

    Erbium is known to effectively load with hydrogen when held at high temperature in a hydrogen atmosphere. To make the storage of hydrogen kinetically feasible, a thermal activation step is required. Activation is a routine practice, but very little is known about the physical, chemical, and/or electronic processes that occur during Activation. This work presents in situ characterization of erbium Activation using variable energy photoelectron spectroscopy at various stages of the Activation process. Modification of the passive surface oxide plays a significant role in Activation. The chemical and electronic changes observed from core-level and valence band spectra will be discussed along with corroborating ion scattering spectroscopy measurements.

  9. Effect of active-ion concentration on holmium fibre laser efficiency

    SciTech Connect

    Kurkov, Andrei S; Sholokhov, E M; Marakulin, A V; Minashina, L A

    2010-08-03

    We have measured the fraction of holmium ions that relax nonradiatively to the ground level as a result of interaction at a metastable level in optical fibres with a silica-based core doped with holmium ions to 2 x 10{sup 19} - 2 x 10{sup 20} cm{sup -3}. The percentage of such ions has been shown to depend on the absolute active-ion concentration. The fibres have been used to make a number of 2.05-{mu}m lasers, and their slope efficiency has been measured. The laser efficiency decreases with increasing holmium concentration in the fibres (lasers)

  10. Characterization of holmium loaded alginate microspheres for multimodality imaging and therapeutic applications.

    PubMed

    Zielhuis, S W; Seppenwoolde, J H; Bakker, C J G; Jahnz, U; Zonnenberg, B A; van het Schip, A D; Hennink, W E; Nijsen, J F W

    2007-09-15

    In this paper the preparation and characterization of holmium-loaded alginate microspheres is described. The rapid development of medical imaging techniques offers new opportunities for the visualisation of (drug-loaded) microparticles. Therefore, suitable imaging agents have to be incorporated into these particles. For this reason, the element holmium was used in this study in order to utilize its unique imaging characteristics. The paramagnetic behaviour of this element allows visualisation with MRI and holmium can also be neutron-activated resulting in the emission of gamma-radiation, allowing visualisation with gamma cameras, and beta-radiation, suitable for therapeutic applications. Almost monodisperse alginate microspheres were obtained by JetCutter technology where alginate droplets of a uniform size were hardened in an aqueous holmium chloride solution. Ho(3+) binds via electrostatic interactions to the carboxylate groups of the alginate polymer and as a result alginate microspheres loaded with holmium were obtained. The microspheres had a mean size of 159 microm and a holmium loading of 1.3 +/- 0.1% (w/w) (corresponding with a holmium content based on dry alginate of 18.3 +/- 0.3% (w/w)). The binding capacity of the alginate polymer for Ho(3+) (expressed in molar amounts) is equal to that for Ca(2+), which is commonly used for the hardening of alginate. This indicates that Ho(3+) has the same binding affinity as Ca(2+). In line herewith, dynamic mechanical analyses demonstrated that alginate gels hardened with Ca(2+) or Ho(3+) had similar viscoelastic properties. The MRI relaxation properties of the microspheres were determined by a MRI phantom experiment, demonstrating a strong R(2)* effect of the particles. Alginate microspheres could also be labelled with radioactive holmium by adding holmium-166 to alginate microspheres, previously hardened with calcium (labelling efficiency 96%). The labelled microspheres had a high radiochemical stability (94% after

  11. Holmium Nitrate Complexation with Tri-n-butyl Phosphate in Supercritical Carbon Dioxide

    SciTech Connect

    Robert V. Fox; R. Duane Ball; Peter de B. Harrington; Harry W. Rollins; Chien M. Wai

    2005-12-01

    Holmium nitrate pentahydrate was reacted with tri-n-butyl phosphate in supercritical carbon dioxide at 308 K. The products of the complexation reaction were measured under supercritical fluid conditions using UV-vis spectroscopy. The solubility of the metal complexes in the supercritical fluid phase was measured. The mole-ratio titration method was used to determine the stoichiometry of the soluble complexes. Conditional extraction coefficients were calculated from spectral data using least-squares regression and hard-equilibria models. Data indicate that the holmium nitrate-tributyl phosphate system forms 1:2 and 1:4 holmium-tributyl phosphate complexes.

  12. Effect of the active-ion concentration on the lasing dynamics of holmium fibre lasers

    SciTech Connect

    Kurkov, Andrei S; Sholokhov, E M; Marakulin, A V; Minashina, L A

    2010-12-09

    The lasing dynamics of fibre lasers with a core based on quartz glass doped with holmium ions to concentrations in the range of 10{sup 19}-10{sup 20} cm{sup -3} is investigated. It is shown that fibre lasers with a high concentration of active holmium ions generate pulses, but a decrease in the holmium concentration changes the lasing from pulsed to cw regime. At the same time, a decrease in the active-ion concentration and the corresponding increase in the fibre length in the cavity reduce the lasing efficiency. (lasers)

  13. Study of the absorption spectra of the 4f electron transitions of the praseodymium complex with ciprofloxacin and its analytical application.

    PubMed

    Wei, J; Naixing, W; Quanjie, M; Zhikun, S; Xiuqin, X; Fuxiang, L

    2001-08-01

    Ciprofloxacin (CPFX) is proposed as a reagent for the derivative spectrophotometric determination of praseodymium in mixed rare earths. The absorption spectra of 4f electron transitions of the praseodymium complex with CPFX was studied by normal and derivative spectrophotometry. The stoichiometry of the praseodymium-CPFX complex was calculated by the molar ratio and continuous variations methods. A ratio of Pr to CPFX of 1:3 was found. The absorption bands of the 4f electron transitions of the complex were enhanced markedly. Using the third derivative spectrum. Beer's law was obeyed up to 35 microg cm(-3) of praseodymium. The relative standard deviation is 0.62% for 14 microg cm(-3) of praseodymium. The detection and quantification limits were 0.17 and 0.56 microg cm(-3) of praseodymium, respectively. A method for the direct determination of praseodymium in mixtures of rare earths with good accuracy and selectivity is described.

  14. Dielectric and conducting behaviour of polycrystalline holmium octa-molybdate

    NASA Astrophysics Data System (ADS)

    Want, Basharat; Zahoor Ahmad, Bhat; Bhat, Bilal Hamid

    2014-09-01

    Polycrystalline holmium octa-molybdate spherulites have been obtained by using gel diffusion technique and characterized by different physio-chemical techniques. The surfaces of these spherulites are composed of nano-rod with an average diameter of about 80 nm. At room temperature the initial crystal structure is triclinic, space group P1. Thermal studies suggested a phase transition occurring in holmium octa-molybdate crystals at about 793 K. The electrical properties of the system have been studied as a function of frequency and temperature in the ranges of 20 Hz-3 MHz and 290-570 K, respectively. A giant dielectric constant and two loss peaks have been observed in the permittivity formalism. The conducting behaviour of the material is also discussed. The conductivity was found to be 1572 μ Ω-1 m-1 at room temperature and 3 MHz frequency. The conductivity of the polycrystalline material was attributed to the fact that it arises due to the migration of defects on the oxygen sub-lattice. Impedance studies were also performed in the frequency domain to infer the bulk and grain boundary contributions to the overall electric response of the material. The electrical responses have been attributed to the grain, grain-boundary, and interfacial effects.

  15. Holmium:YAG laser angioplasty: treatment of acute myocardial infarction

    NASA Astrophysics Data System (ADS)

    Topaz, On

    1993-06-01

    We report our clinical experience with a group of 14 patients who presented with acute myocardial infarction. A holmium:YAG laser was applied to the infarct-related artery. This laser emits 250 - 600 mJ per pulse, with a pulse length of 250 microseconds and repetition rate of 5 Hz. Potential benefits of acute thrombolysis by lasers include the absence of systemic lytic state; a shortened thrombus clearing time relative to using thrombolytics; safe removal of the intracoronary thrombus and facilitation of adjunct balloon angioplasty. Potential clinical difficulties include targeting the obstructive clot and plaque, creation of debris and distal emboli and laser-tissue damage. It is conceivable that holmium:YAG laser can be a successful thrombolytic device as its wave length (2.1 microns) coincides with strong water absorption peaks. Since it is common to find an atherosclerotic plaque located under or distal to the thrombotic occlusion, this laser can also be applied for plaque ablation, and the patient presenting with acute myocardial infarction can clearly benefit from the combined function of this laser system.

  16. Molecular distribution and toxicity assessment of praseodymium by Spirodela polyrrhiza.

    PubMed

    Xu, Ting; Su, Chunlei; Hu, Dan; Li, Feifei; Lu, Qianqian; Zhang, Tingting; Xu, Qinsong

    2016-07-15

    Aquatic macrophytes are known to accumulate and bioconcentrate metals. In this study, the physiological, biochemical, and ultrastructural responses of Spirodela polyrrhiza to elevated concentrations of praseodymium (Pr), ranging from 0 to 60μM, were investigated over 20 d exposure. The results showed that the accumulation of Pr in S. polyrrhiza occurred in a concentration-dependent manner. The accumulation of Pr in biomacromolecules decreased in the order of cellulose and pectin (65-69%), crude proteins (18-25%), crude polysaccharides (6-10%), crude lipids (3%-4%). Significant increases in malondialdehyde (MDA), and decreases in photosynthetic pigment, soluble protein, and unsaturated fatty acids showed that Pr induced oxidative stress. Inhibitory effects on photosystem II and the degradation of the reaction center proteins D1 and D2 were revealed by chlorophyll a fluorescence transients, immunoblotting, and damage to chloroplast ultrastructure. Significant increases in cell death were observed in Pr-treated plants. However, S. polyrrhiza can combat Pr induced oxidative injury by activating various enzymatic and non-enzymatic antioxidants. These results will improve understanding of the biological consequences of rare earth elements (REEs) contamination, particularly in aquatic bodies. PMID:27017399

  17. The thermodynamic characteristics of vaporization of praseodymium triiodide

    NASA Astrophysics Data System (ADS)

    Motalov, V. B.; Kudin, L. S.; Markus, T.

    2009-03-01

    The vaporization of praseodymium triiodide was studied by high-temperature mass spectrometry. Monomeric (PrI3) and dimeric (Pr2I6) molecules and the PrI{4/-} and Pr2I{7/-} negative ions were recorded in saturated vapor over the temperature range 842-1048 K. The partial pressures of neutral vapor components were determined. The enthalpies of sublimation Δs H o(298.15 K) in the form of monomers (291 ± 10 kJ/mol) and dimers (400 ± 30 kJ/mol) were calculated by the second and third laws of thermodynamics. The equilibrium constants of ion-molecular reactions were measured and the enthalpies of the reactions determined. The enthalpies of formation Δf H o(298.15 K) of molecules and ions in the gas phase were calculated (-373 ± 11, -929 ± 31, -865 ± 25, and -1433 ± 48 kJ/mol for PrI3, Pr2I6, PrI{4/-}, and Pr2I{7/-}, respectively).

  18. Synthesis and structural studies of praseodymium doped silver borate glasses

    SciTech Connect

    Jagadeesha Gowda, G. V.; Eraiah, B.

    2013-02-05

    Praseodymium doped silver borate glasses with nominal composition xPr{sub 6}O{sub 11}-(25-x)Ag{sub 2}O-75B{sub 2}O{sub 3} (x=0, 1, 2, 3, 4, 5) were prepared by melt quench technique. XRD pattern shows that there is no sharp peak it confirms the amorphous nature of the present glasses. The glass transition temperature (T{sub g}) of this glass system have been studied using the Matac MBS-8000 Digital Signal Processing and Conventional Thermal Analysis (DTA) method. The T{sub g} of these glasses increases with increase in concentration of Pr{sub 6}O{sub 11} except at 0.2 mol%, T{sub g} value is lower. {sup 11}B MAS-NMR shows the presence of sharp peak around 0.306 ppm. Chemical shift of these glasses decreases with mol% of rare earth oxide. FTIR spectra recorded in the region of 400 to 4000 cm{sup -1}. This studies revealed that the progressive addition Ag{sub 2}O and Pr{sub 6}O{sub 11} leads to modification of B{sub 2}O{sub 3} into BO{sub 4} groups. Raman measurements of these glasses support the proposed interpretations of the experimental results.

  19. Molecular distribution and toxicity assessment of praseodymium by Spirodela polyrrhiza.

    PubMed

    Xu, Ting; Su, Chunlei; Hu, Dan; Li, Feifei; Lu, Qianqian; Zhang, Tingting; Xu, Qinsong

    2016-07-15

    Aquatic macrophytes are known to accumulate and bioconcentrate metals. In this study, the physiological, biochemical, and ultrastructural responses of Spirodela polyrrhiza to elevated concentrations of praseodymium (Pr), ranging from 0 to 60μM, were investigated over 20 d exposure. The results showed that the accumulation of Pr in S. polyrrhiza occurred in a concentration-dependent manner. The accumulation of Pr in biomacromolecules decreased in the order of cellulose and pectin (65-69%), crude proteins (18-25%), crude polysaccharides (6-10%), crude lipids (3%-4%). Significant increases in malondialdehyde (MDA), and decreases in photosynthetic pigment, soluble protein, and unsaturated fatty acids showed that Pr induced oxidative stress. Inhibitory effects on photosystem II and the degradation of the reaction center proteins D1 and D2 were revealed by chlorophyll a fluorescence transients, immunoblotting, and damage to chloroplast ultrastructure. Significant increases in cell death were observed in Pr-treated plants. However, S. polyrrhiza can combat Pr induced oxidative injury by activating various enzymatic and non-enzymatic antioxidants. These results will improve understanding of the biological consequences of rare earth elements (REEs) contamination, particularly in aquatic bodies.

  20. Amplifying properties of heavily erbium-doped active fibres

    SciTech Connect

    Plotskii, A Yu; Kurkov, Andrei S; Yashkov, M Yu; Bubnov, M M; Likhachev, M E; Sysolyatin, A A; Dianov, Evgenii M; Gur'yanov, A N

    2005-06-30

    The relative concentration of erbium ions undergoing nonradiative relaxation from the metastable to the ground level is measured in aluminosilicate glass fibres doped with erbium ions at concentration between 3x10{sup 18} and 10{sup 20} cm{sup -3}. The dependence of the fraction of such ions on the Er{sup 3+} concentration is determined for fibres containing different amounts of aluminium oxide in a core. It is shown that the fraction of erbium ions not involved in amplification substantially decreases with increasing the Al{sub 2}O{sub 3} concentration. It is found that clustering leads to a considerable decrease in the gain in heavily Er{sup 3+}-doped active fibres. The dependence of the quantum efficiency of a fibre amplifier on the erbium ion concentration is obtained based on the measurements performed. This dependence can be used for optimising the parameters of erbium-doped fibre amplifiers. (fibres. integrated-optic waveguides)

  1. Anomalous reversal of C-H and C-D quenching efficiencies in luminescent praseodymium cryptates.

    PubMed

    Scholten, Julia; Rosser, Geraldine A; Wahsner, Jessica; Alzakhem, Nicola; Bischof, Caroline; Stog, Felix; Beeby, Andrew; Seitz, Michael

    2012-08-29

    A series of selectively deuterated praseodymium cryptates has been synthesized. Their luminescence lifetimes in solution range from 150 to 595 ns for the (1)D(2) → (3)F(4) transition. Global fitting of the nonradiative deactivation rate differences of the isotopologic C-(H/D) oscillators revealed that aromatic C-D overtones anomalously quench the luminescence more than C-H vibrations. This is explained by the dominance of Franck-Condon overlap factors that greatly favor C-D oscillators, which are in almost ideal resonance with the relevant energy gap (1)D(2)-(1)G(4) of praseodymium.

  2. Holmium laser use in the treatment of selected dry eye syndrome complications

    NASA Astrophysics Data System (ADS)

    Kecik, Dariusz; Kecik, Tadeusz; Kasprzak, Jan; Kecik, Mariusz

    1996-03-01

    The authors present initial results of treatment selected complications of dry eye syndrome with holmium laser. The lacrimal puncta obliteration and coagulation of the corneal ulcer surface were done.

  3. Praseodymium hydroxide and oxide nanorods and Au/Pr6O11 nanorod catalysts for CO oxidation.

    PubMed

    Huang, P X; Wu, F; Zhu, B L; Li, G R; Wang, Y L; Gao, X P; Zhu, H Y; Yan, T Y; Huang, W P; Zhang, S M; Song, D Y

    2006-02-01

    Praseodymium hydroxide nanorods were synthesized by a two-step approach: First, metallic praseodymium was used to form praseodymium chloride, which reacted subsequently with KOH solution to produce praseodymium hydroxide. In the second step the hydroxide was treated with a concentrated alkaline solution at 180 degrees C for 45 h, yielding nanorods as shown by the scanning and transmission electron microscopy images. The results of X-ray diffraction and energy-dispersive X-ray spectroscopy experiments indicate that these nanorods are pure praseodymium hydroxide with a hexagonal structure, which can be converted into praseodymium oxide (Pr6O11) nanorods of a face-centered cubic structure after calcination at 600 degrees C for 2 h in air. Gold was loaded on the praseodymium oxide nanorods using HAuCl4 as the gold source, and NaBH4 was used to reduce the gold species to metallic nanoparticles with sizes of 8-12 nm on the nanorod surface. These Au/Pr6O11 nanorods exhibit superior catalytic activity for CO oxidation.

  4. Holmium-doped fibre amplifier operating at 2.1 μm

    SciTech Connect

    Kamynin, V A; Antipov, S O; Kurkov, A S; Baranikov, A V

    2014-02-28

    A small-signal holmium-doped fibre amplifier is demonstrated. The seed source is a cw holmium-doped fibre laser whose output power is modulated by an electro-optical modulator. The maximum gain reached (wavelength, 2.1 μm; power, 0.25 mW; pulse duration, 100 ns; pulse repetition rate, 1 μs) is 28.5 dB. (lasers)

  5. Delivery of Erbium:YAG laser radiation through side-firing germanium oxide optical fibers

    NASA Astrophysics Data System (ADS)

    Ngo, Anthony K.; Fried, Nathaniel M.

    2006-02-01

    The Erbium:YAG laser is currently being tested experimentally for endoscopic applications in urology, including more efficient laser lithotripsy and more precise incision of urethral strictures than the Holmium:YAG laser. While side-firing silica fibers are available for use with the Ho:YAG laser in urology, no such fibers exist for use with the Er:YAG laser. These applications may benefit from the availability of a side-firing, mid-infrared optical fiber capable of delivering the laser radiation at a 90-degree angle to the tissue. The objective of this study is to describe the simple construction and characterization of a side-firing germanium oxide fiber for potential use in endoscopic laser surgery. Side-firing fibers were constructed from 450-micron-core germanium oxide fibers of 1.45-m-length by polishing the distal tip at a 45-degree angle and placing a 1-cm-long protective quartz cap over the fiber tip. Er:YAG laser radiation with a wavelength of 2.94 microns, pulse duration of 300 microseconds, pulse repetition rate of 3 Hz, and pulse energies of from 5 to 550 mJ was coupled into the fibers. The fiber transmission rate and damage threshold measured 48 +/- 4 % and 149 +/- 37 mJ, respectively (n = 6 fibers). By comparison, fiber transmission through normal germanium oxide trunk fibers measured 66 +/- 3 %, with no observed damage (n = 5 fibers). Sufficient pulse energies were transmitted through the side-firing fibers for contact tissue ablation. Although these initial tests are promising, further studies will need to be conducted, focusing on assembly of more flexible, smaller diameter fibers, fiber bending transmission tests, long-term fiber reliability tests, and improvement of the fiber output spatial beam profile.

  6. Characterisation of Erbium Doped Phosphate Glass

    NASA Astrophysics Data System (ADS)

    Rasid, A. A.; Rohani, M. S.; Sahar, M. R.; Kasim, A.

    2010-03-01

    A series of erbium doped phosphate glass has been successfully fabricated, and the determination of their density and luminescence properties has been carried out. It is particularly interesting to study the effect of modifying oxides to the properties of the glass. The glass density reduces with the increasing content of Na2O. The emission spectra from luminescence spectroscopy resolved six emission peaks from the excitation wavelength of 336.8 nm (3.69 eV). The emission of 4F7/2 gives two emission peaks, where the peak near 482 nm shows a higher intensity and the peak near 491 nm gives a weak emission spectra.

  7. Bose-Einstein condensation of erbium.

    PubMed

    Aikawa, K; Frisch, A; Mark, M; Baier, S; Rietzler, A; Grimm, R; Ferlaino, F

    2012-05-25

    We report on the achievement of Bose-Einstein condensation of erbium atoms and on the observation of magnetic Feshbach resonances at low magnetic fields. By means of evaporative cooling in an optical dipole trap, we produce pure condensates of 168Er, containing up to 7×10(4) atoms. Feshbach spectroscopy reveals an extraordinary rich loss spectrum with six loss resonances already in a narrow magnetic-field range up to 3 G. Finally, we demonstrate the application of a low-field Feshbach resonance to produce a tunable dipolar Bose-Einstein condensate and we observe its characteristic d-wave collapse. PMID:23003221

  8. Energy upconversion in holmium doped lead-germano-tellurite glass

    SciTech Connect

    Kamma, Indumathi; Reddy, B. Rami

    2010-06-15

    Holmium doped lead-germano-tellurite glass was prepared by the melt quenching technique. The Judd-Ofelt intensity parameters were estimated as {Omega}{sub 2}=7.6x10{sup -20}, {Omega}{sub 4}=12.9x10{sup -20}, and {Omega}{sub 6}=2.5x10{sup -20} cm{sup 2}. Radiative transition probabilities and lifetimes were also determined for some of the levels. Room temperature upconversion emissions have been observed from Ho{sup 3+} at 497 nm under 532 nm laser excitation, and at 557 and 668 nm under 762 nm laser excitation. The upconversion emission mechanisms were found to be due to a step wise excitation process. Upconversion emission intensity enhanced in a heat treated glass.

  9. The specific heat of potassium holmium double tungstate

    NASA Astrophysics Data System (ADS)

    Borowiec, M. T.; Dyakonov, V. P.; Szewczyk, A.; Gutowska, M. U.; Zayarnyuk, T.; Zubov, E. E.; Majchrowski, A.; Michalski, E.; Hoffmann, J.-U.; Prokes, K.; Woźniak, K.; Dobrzycki, Ł.; Khatsko, E. N.; Rykova, A. I.; Domukhovski, V.; Barański, M.; Shtyrkhunova, V.; Żmija, J.; Szymczak, H.

    2011-11-01

    The results of measurements of thermal properties (specific heat) of potassium holmium double tungstate KHo(WO4)2 as a function of temperature (from 0.5 to 300 K) and magnetic field (up to 2 T) are presented. The total specific heat without the phonon and Schottky contributions is found to have the anomaly with maximum at T SPT ∼ 5 K. This anomaly is likely related with the structural phase transition (SPT) caused by the cooperative Jahn-Teller effect. The increase of specific heat at very low temperatures and its shift towards high temperatures with increasing magnetic field are observed. The origin of this behaviour can be connected with possible magnetic phase transition induced by magnetic field.

  10. Effect of praseodymium on drug metabolism in rat liver smooth and rough endoplasmic reticulum.

    PubMed

    Arvela, P; von Lehmann, B; Grajewski, O; Oberdisse, E

    1980-07-15

    A small i.v. dose (3 mg/kg) of a light lanthanon, praseodymium, impairs the drug metabolizing capacity of both the smooth and rough fractions of rat liver endoplasmic reticulum. This decrease in the activity of drug metabolizing enzymes and in the amount of cytochromes P-450 and b5 is more pronounced in the rough endoplasmic reticulum fraction.

  11. Calculation of the volume effect at an electron phase transition in pure cerium and praseodymium

    NASA Astrophysics Data System (ADS)

    Ponomareva, S. A.; Koval', Yu. N.; Ponomarev, A. P.

    2014-03-01

    The experimental values of the volume effect at an electronic phase transition in several rare-earth metals are discussed. Specifically, volume changes at phase transitions in cerium and praseodymium are calculated using a semiphenomenological relationship derived in terms of the Falikov-Ramirez-Kimball model. A number of factors influencing the amount of the volume effect at electronic phase transitions are analyzed.

  12. Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes.

    PubMed

    Zhou, Qin; Li, Hui; Lian, Yongfu; Suzuki, Mitsuaki; Bao, Lipiao; Cai, Wenting; Wang, Weiwei; Nagase, Shigeru; Lu, Xing; Akasaka, Takeshi

    2014-09-01

    Regioselective cycloaddition of adamantylidene carbene to Pr@C(2v)(9)-C82 affords the first derivative of praseodymium-containing metallofullerenes. Single-crystal X-ray crystallographic data in combination with theoretical studies demonstrate that the addition is dictated by the single metal ion encapsulated inside the fullerene cage.

  13. α-Regioselective Barbier Reaction of Carbonyl Compounds and Allyl Halides Mediated by Praseodymium.

    PubMed

    Wu, San; Li, Ying; Zhang, Songlin

    2016-09-01

    The first utility of praseodymium as a mediating metal in the Barbier reaction of carbonyl compounds with allyl halides was reported in this paper. In contrast to the traditional metal-mediated or catalyzed Barbier reactions, exclusive α-adducts were obtained in this one-pot reaction with a broad scope of substrates and feasible reaction conditions.

  14. Double fluorescence conversion in ultraviolet and visible region for some praseodymium complexes of aromatic carboxylates.

    PubMed

    Yan, Bing; Wang, Wei-Jing; Song, Yi-Shan

    2006-07-01

    Four praseodymium complexes of aromatic carboxylates (benzoate, 4-tert-butylbenzoate, 2-benzoylbe-noate, and benzimidazole-5-carboxylate) have been synthesized and characterized, whose photophysical properties have been studied with ultraviolet spectra, phosphorescence spectra, and fluorescence spectra. The fluorescent emission spectra of all praseodymium complexes show two emission peaks under the excitation band of 245 nm at about 395 and 595 nm respectively, while one peak under 415 nm at about 595 nm, which attributed to be 1S0 --> 1I6 (395 nm) transition and the characteristic emission 1D2 --> 3H4 (595 nm) transition of Pr3+ ion. The 1S0 --> 1I6 transition can be ascribed as the transition of charge transfer state, and the 1D2 --> 3H4 can be further proved that there exists an antenna effect in the fluorescence of praseodymium with aromatic carboxylic acids. In conclusion, the praseodymium complexes systems can realize the double fluorescent conversion in both ultraviolet and visible region and can be further studied the application of this conversion.

  15. Thermodynamics of reaction of praseodymium with gallium-indium eutectic alloy

    NASA Astrophysics Data System (ADS)

    Melchakov, S. Yu.; Ivanov, V. A.; Yamshchikov, L. F.; Volkovich, V. A.; Osipenko, A. G.; Kormilitsyn, M. V.

    2013-06-01

    Thermodynamic properties of Ga-In eutectic alloys saturated with praseodymium were determined for the first time employing the electromotive force method. The equilibrium potentials of the Pr-In alloys saturated with praseodymium (8.7-12.1 mol.% Pr) and Pr-Ga-In alloys (containing 0.0012-6.71 mol.% Pr) were measured between 573-1073 K. Pr-In alloy containing solid PrIn3 with known thermodynamic properties was used as the reference electrode when measuring the potentials of ternary Pr-In-Ga alloys. Activity, partial and excessive thermodynamic functions of praseodymium in alloys with indium and Ga-In eutectic were calculated. Activity (a), activity coefficients (γ) and solubility (X) of praseodymium in the studied temperature range can be expressed by the following equations: lgaα-Pr(In) = 4.425 - 11965/T ± 0.026. lgаα-Pr(Ga-In) = 5.866 - 14766/T ± 0.190. lgγα-Pr(Ga-In) = 2.351 - 9996/T ± 0.39. lgХPr(Ga-In) = 3.515 - 4770/T ± 0.20.

  16. α-Regioselective Barbier Reaction of Carbonyl Compounds and Allyl Halides Mediated by Praseodymium.

    PubMed

    Wu, San; Li, Ying; Zhang, Songlin

    2016-09-01

    The first utility of praseodymium as a mediating metal in the Barbier reaction of carbonyl compounds with allyl halides was reported in this paper. In contrast to the traditional metal-mediated or catalyzed Barbier reactions, exclusive α-adducts were obtained in this one-pot reaction with a broad scope of substrates and feasible reaction conditions. PMID:27490708

  17. Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes.

    PubMed

    Zhou, Qin; Li, Hui; Lian, Yongfu; Suzuki, Mitsuaki; Bao, Lipiao; Cai, Wenting; Wang, Weiwei; Nagase, Shigeru; Lu, Xing; Akasaka, Takeshi

    2014-09-01

    Regioselective cycloaddition of adamantylidene carbene to Pr@C(2v)(9)-C82 affords the first derivative of praseodymium-containing metallofullerenes. Single-crystal X-ray crystallographic data in combination with theoretical studies demonstrate that the addition is dictated by the single metal ion encapsulated inside the fullerene cage. PMID:25026192

  18. Holmium:YAG laser: effects on dentin demineralization

    NASA Astrophysics Data System (ADS)

    Holt, Raleigh A.; Nordquist, Robert E.

    1995-05-01

    The Holmium:YAG laser at 2.12 microns wavelength was used to compare the changes in resistance to demineralization of the dentinal root surfaces of human extracted teeth in vitro. Three protocols were used: Group #1, and application of nonfilled resin/NaF (4%) solution followed by exposure with the Holmium:YAG laser beam; Group #2, an application of an aqueous solution of NaF (4%) only; and Group #3, irradiation with the laser beam only. The teeth were exposed on the root surfaces with untreated control and experimental sites on opposite sides of the teeth. A 3 mm spot size covered an area of 3 X 5 mm with 0.450 (+/- .05) joules at a fluence of 2.66 - 3.3 J/cm2. All teeth were decalcified in a 10% Formic acid solution for a timed period. Samples were prepared for staining by sectioning the teeth at the dentoenamel junction and 3 mm apically to produce a cross-section of each tooth root surface. Each sample was placed in toluidine blue dye to observe the depth of dye penetration into the dentin of treated and control sites. Toluidine blue dye showed a consistent greater depth of dye penetration into the dentinal areas of the untreated control sites versus the resin/NaF-lased group. The topical fluoride only group did not appear different than the untreated control sites of the teeth. The lased only group showed areas of dye penetration similar to the untreated control sides with other areas of little or no dye penetration. The finding that HO:YAG laser energy/chemical agent produced increased resistance to demineralization of dentinal surfaces in vitro suggested potential clinical applications of this combined modality.

  19. Holmium laser enucleation of the prostate: patient selection and perspectives

    PubMed Central

    Marien, Tracy; Kadihasanoglu, Mustafa; Miller, Nicole L

    2016-01-01

    Background Multiple endoscopic surgical options exist to treat benign prostatic hyperplasia (BPH), including holmium laser enucleation of the prostate (HoLEP). HoLEP alleviates obstructive prostatic tissue via enucleation, both bluntly with a resectoscope and by cutting tissue with the holmium laser, and removal of adenoma via morcellation. This article reviews patient selection for HoLEP in order to optimize outcomes, costs, and patient satisfaction. Methods A literature review of all studies on HoLEP was conducted. Studies that focused on outcomes in regard to patient and procedural factors were closely reviewed and discussed. Results Various studies found that men with large or small prostates, on antithrombotic therapy, in urinary retention, with bladder hypocontractility, with prostate cancer, undergoing retreatment for BPH, or in need of concomitant surgery for bladder stones and other pathologies do well with HoLEP, as demonstrated by excellent functional and symptomatic outcomes as well as low complication rates. There is a 74–78% rate of retrograde ejaculation following HoLEP. Techniques to preserve ejaculatory function following enucleative techniques have not been able to demonstrate a significant improvement. Conclusion Patient selection for HoLEP can include most men with bothersome BPH who have evidence of bladder outlet obstruction and are healthy enough to undergo surgery. The ability to safely perform concomitant surgery with HoLEP benefits the patient by sparing them an additional anesthetic and also decreases costs. Patients should be made aware of the risk of retrograde ejaculation following HoLEP and counseled on treatment alternatives if maintaining ejaculatory function is desired. PMID:27800470

  20. Optical Frequency Comb Generation based on Erbium Fiber Lasers

    NASA Astrophysics Data System (ADS)

    Droste, Stefan; Ycas, Gabriel; Washburn, Brian R.; Coddington, Ian; Newbury, Nathan R.

    2016-06-01

    Optical frequency combs have revolutionized optical frequency metrology and are being actively investigated in a number of applications outside of pure optical frequency metrology. For reasons of cost, robustness, performance, and flexibility, the erbium fiber laser frequency comb has emerged as the most commonly used frequency comb system and many different designs of erbium fiber frequency combs have been demonstrated. We review the different approaches taken in the design of erbium fiber frequency combs, including the major building blocks of the underlying mode-locked laser, amplifier, supercontinuum generation and actuators for stabilization of the frequency comb.

  1. Erbium triflate promoted multicomponent synthesis of highly substituted imidazoles.

    PubMed

    Rajaguru, Kandasamy; Suresh, Rajendran; Mariappan, Arumugam; Muthusubramanian, Shanmugam; Bhuvanesh, Nattamai

    2014-02-01

    The synthesis of highly substituted imidazole derivatives has been achieved from various α-azido chalcones, aryl aldehydes, and anilines. This multicomponent protocol employs erbium triflate as a catalyst resulting in excellent yield of the imidazoles.

  2. Cladding-pumped erbium-doped multicore fiber amplifier.

    PubMed

    Abedin, K S; Taunay, T F; Fishteyn, M; DiGiovanni, D J; Supradeepa, V R; Fini, J M; Yan, M F; Zhu, B; Monberg, E M; Dimarcello, F V

    2012-08-27

    A cladding pumped multicore erbium-doped fiber amplifier for simultaneous amplification of 6 channels is demonstrated. Peak gain over 32 dB has been obtained at a wavelength of 1560 nm and the bandwidth measured at 20-dB gain was about 35 nm. Numerical modeling of cladding pumped multicore erbium-doped amplifier was also performed to study the properties of the amplifier. The results of experiment and simulation are found to be in good agreement.

  3. Magnetoresistance and magnetic ordering in praseodymium and neodymium hexaborides

    SciTech Connect

    Anisimov, M. A.; Bogach, A. V.; Glushkov, V. V.; Demishev, S. V.; Samarin, N. A.; Filipov, V. B.; Shitsevalova, N. Yu.; Kuznetsov, A. V.; Sluchanko, N. E.

    2009-11-15

    The magnetoresistance {Delta}{rho}/{rho} of single-crystal samples of praseodymium and neodymium hexaborides (PrB{sub 6} and NdB{sub 6}) has been measured at temperatures ranging from 2 to 20 K in a magnetic field of up to 80 kOe. The results obtained have revealed a crossover of the regime from a small negative magnetoresistance in the paramagnetic state to a large positive magnetoresistive effect in magnetically ordered phases of the PrB{sub 6} and NdB{sub 6} compounds. An analysis of the dependences {Delta}{rho}(H)/{rho} has made it possible to separate three contributions to the magnetoresistance for the compounds under investigation. In addition to the main negative contribution, which is quadratic in the magnetic field (-{Delta}{rho}/{rho} {proportional_to} H{sup 2}), a linear positive contribution ({Delta}{rho}/{rho} {proportional_to} H) and a nonlinear ferromagnetic contribution have been found. Upon transition to a magnetically ordered state, the linear positive component in the magnetoresistance of the PrB{sub 6} and NdB{sub 6} compounds becomes dominant, whereas the quadratic contribution to the negative magnetoresistance is completely suppressed in the commensurate magnetic phase of these compounds. The presence of several components in the magnetoresistance has been explained by assuming that, in the antiferromagnetic phases of PrB{sub 6} and NdB{sub 6}, ferromagnetic nanoregions (ferrons) are formed in the 5d band in the vicinity of the rareearth ions. The origin of the quadratic contribution to the negative magnetoresistance is interpreted in terms of the Yosida model, which takes into account scattering of conduction electrons by localized magnetic moments of rare-earth ions. Within the approach used, the local magnetic susceptibility {chi}{sub loc} has been estimated. It has been demonstrated that, in the temperature range T{sub N} < T < 20 K, the behavior of the local magnetic susceptibility {chi}{sub loc} for the compounds under investigation can

  4. Preparation, characterization and photocatalytic activities of holmium-doped titanium dioxide nanoparticles.

    PubMed

    Shi, Jian-Wen; Zheng, Jing-Tang; Wu, Peng

    2009-01-15

    Holmium-doped TiO2 nanoparticles with high photocatalytic activities were prepared by sol-gel method and characterized by X-ray diffraction, transmission electron microscopy, ultraviolet-visible diffuse reflectance spectroscopy, and surface area measurement by nitrogen adsorption in this study. Experimental results indicated holmium doping could increase the surface area of TiO2 nanoparticles, and inhibit the growth of crystalline size and the anatase-to-rutile phase transformation. The results of photodegrading methyl orange showed holmium doping improved the photocatalytic activity of TiO2, and the reasons could be attributed to the synergetic effects of large surface areas, small crystallite size, lattice distortion and more charge imbalance of holmium-doped TiO2. In our experiment, the optimal doped amount was 0.3mol.% for the maximum photocatalytic degradation ratio when holmium-doped TiO2 was calcined at 500 degrees C, and the optimal calcined temperature was 600 degrees C when the doped amount was 0.5mol.%.

  5. Evaluation of six holmium:YAG optical fibers for ureteroscopy: What's new in 2009?

    NASA Astrophysics Data System (ADS)

    Knudsen, Bodo E.; Teichman, Joel M. H.

    2010-02-01

    The holmium:yttrium aluminum garnet (YAG) laser is the gold standard laser for intracorporeal lithotripsy.1 Optical fibers are utilized to transmit laser energy to the surface of a stone for fragmentation via a predominant photothermal mechanism.2 Previous work has demonstrated that performance characteristics of holmium:YAG optical fibers used for laser lithotripsy varies. Performance may difference not only between fibers made by different manufacturers but also between individual fibers produced by the same manufacturer.3,4 Fiber failure with bending, such as during lower pole ureterorenoscopy, can lead to catastrophic endoscope damage resulting in costly repair. Manufacturers continue to develop new holmium:YAG optical fibers. In this study we evaluate a series of newly commercially available fibers using a previously designed testing protocol. This study was designed to determine the performance and threshold for failure of six newly available holmium:YAG laser fibers from Cook Medical and Fibertech Gmbh. We hypothesize that fiber performance will continue to vary amongst different holmium:YAG optical fibers.

  6. Safety and efficacy of holmium:YAG laser lithotripsy in patients with bleeding diatheses

    NASA Astrophysics Data System (ADS)

    Watterson, James D.; Girvan, Andrew R.; Cook, Anthony J.; Beiko, Darren T.; Nott, Linda; Auge, Brian K.; Preminger, Glenn M.; Denstedt, John D.

    2003-06-01

    Purpose: To assess the safety and efficacy of ureteroscopy and holmium:YAG (yttrium-aluminum-garnet) laser lithotripsy in the treatment of upper urinary tract calculi in patients with known and uncorrected bleeding diatheses. Materials and Methods: A retrospective chart review from 2 tertiary stone centers was performed to identify patients with known bleeding diatheses who were treated with holmium:YAG laser lithotripsy for upper urinary tract calculi. Twenty-five patients with 29 upper urinary tract calculi were treated with ureteroscopic holmium laser lithotripsy. Bleeding diatheses identified were coumadin administration for various conditions (17), liver dysfunction (3), thrombocytopenia (4), and von Willebrand's disease (1). Mean international normalized ratio (INR), platelet count and bleeding time were 2.3, 50 x 109/L, and > 16 minutes, for patients receiving coumadin or with liver dysfunction, thrombocytopenia, or von Willebrand's disease, respectively. Results: Overall, the stone-free rate was 96% (27/28) and 29 of 30 procedures were completed successfully without significant complication. One patient who was treated concomitantly with electrohydraulic lithotripsy (EHL) had a significant retroperitoneal hemorrhage that required blood transfusion. Conclusions: Treatment of upper tract urinary calculi in patients with uncorrected bleeding diatheses can be safely performed using contemporary small caliber ureteroscopes and holmium laser as the sole modality of lithotripsy. Ureteroscopic holmium laser lithotripsy without preoperative correction of hemostatic parameters limits the risk of thromboembolic complications and costs associated with an extended hospital stay. Avoidance of the use of EHL is crucial in reducing bleeding complications in this cohort of patients.

  7. A self-Q-switched all-fiber erbium laser at 1530 nm using an auxiliary 1570-nm erbium laser.

    PubMed

    Tsai, Tzong-Yow; Fang, Yen-Cheng

    2009-11-23

    We demonstrate a self-Q-switched, all-fiber, tunable, erbium laser at 1530 nm with high pulse repetition rates of 0.9-10 kHz. Through the use of an auxiliary 10-mW, 1570 nm laser that shortened the relaxation time of erbium, sequentially Q-switched pulses with pulse energies between 4 and 6 microJ and pulse widths of 40 ns were steadily achieved. A peak pulse power of 165 W was obtained.

  8. Luminescence of erbium ions in tellurite glasses

    SciTech Connect

    Savikin, Alexander P.; Grishin, Igor A.; Sharkov, Valery V.; Budruev, Andrei V.

    2013-11-15

    Optical characteristics of new generation of tellurite glasses having high stability against crystallization have been studied. As the initial reagents for the glasses synthesis on the base of tellurium oxide (TeO{sub 2}) there were used such oxides as WO{sub 3}, MoO{sub 3}, La{sub 2}O{sub 3}, Li{sub 2}CO{sub 3}, ZnO—Bi{sub 2}O{sub 2}CO{sub 3} and active components such as high purity Er{sub 2}O{sub 3}, Yb{sub 2}O{sub 3}, ErF{sub 3} and YbF{sub 3}. Intensities of luminescence at 1.53 µm of the erbium ions were determined after excitation at 975 nm. Experimental data obtained have shown the possibility to use the studied glasses doped by Er{sup 3+} and Yb{sup 3+} as active elements for fiber and integrated optics. - Graphical abstract: In contrast to the case of ZBLAN glass the TeO{sub 2}–WO{sub 3} (Er{sup 3+}) glass has bright intensity of luminescence at 1.53 µm for erbium ions that should be caused by excitation at 975 nm. Experimental data obtained have shown the possibility to use the studied glasses doped by Er{sup 3+} and Yb{sup 3+} as active elements for fiber and integrated optics. Display Omitted - Highlights: • We examined changes in growth of luminescence in doubly-doped tellurite glasses. • We found that luminescence grows in two orders by using Er{sup 3+} and Yb{sup 3+} at 1.53 μm. • We see possibility to use those glasses as active elements for integrated optics.

  9. Erbium Doped Fiber Sources and Amplifiers for Optical Fiber Sensors.

    NASA Astrophysics Data System (ADS)

    Wagener, Jefferson L.

    1996-08-01

    This thesis explores the use of erbium-doped fiber in lasers, amplified spontaneous emission sources, and amplifiers with particular attention to applications involving fiber sensor technology. Erbium-doped fiber laser output power is shown to be strongly dependent on the erbium dopant concentration in a fiber. Using multiple fibers with various erbium ion concentrations, laser output powers are found to decrease as erbium concentration is increased. Upconversion in paired ions is successfully used to model the lasers, resulting in a better understanding of the loss mechanism involved. Further investigation shows that co-doping an erbium-doped fiber with aluminum helps eliminate upconversion in paired ions, and an optimum ratio of 20 aluminum ions for every erbium ion is established. Upconversion due to paired ions is also used to predict the behavior of erbium-doped fiber amplifiers as a function of the erbium ion concentration. With this knowledge of concentration dependence, a low doped, high output power fiber is chosen for use as an amplified spontaneous emission source in a fiber optic gyroscope. Used as a single pass broadband source in one propagation direction and as a signal amplifier in the other direction, this source is tested experimentally in a high quality fiber gyroscope. Experimental results reveal an unexpected dependence on the polarization states of the optical pump and the gyroscope output signal. A theory of polarization anisotropy in the erbium ions is developed in full and accurately models the experimental observations. Using this model to optimize the source, a fiber gyroscope output stability of 4 parts per million is obtained experimentally, approaching the requirements of inertial navigation. This model is also used to explore novel single polarization amplified spontaneous emission sources. Large scale amplified sensor arrays are examined theoretically to determine component and amplification requirements. For balanced gain and loss

  10. [A Case of Holmium: YAG Laser Resection of Superficial Bladder Tumor (HoLRBT)].

    PubMed

    Sugita, Yoshiko; Shitara, Toshiya; Hirayama, Takahiro; Fujita, Tetsuo; Yoshida, Kazunari; Kubo, Seiichi; Iwamura, Masatsugu

    2015-10-01

    We present a case of holmium : YAG laser resection of superficial bladder tumor (HoLRBT). A 73-year-old male was referred to our hospital with elevated prostatic specific antigen. Due to difficulty of urination, holmium : YAG laser enucleation of the prostate was performed under the diagnosis of benign prostatic hyperplasia. During the surgery, superficial bladder tumor was incidentally identified, and HoLRBT was performed. After the operation, histopathological examination revealed urothelial carcinoma, G2 > G1, pTa. The patient has been subsequently followed up for 9 months, and there areno evidence of recurrence. Changing the holmium : YAG laser energy setting can potentially be effective and safe to approach a superficial bladder tumor.

  11. Holmium:YAG laser in dentistry: photoconditioning of dentinal surfaces

    NASA Astrophysics Data System (ADS)

    Holt, Raleigh A.; Nordquist, Robert E.

    1994-09-01

    This in vitro study was undertaken to determine energy levels necessary to produce tubule closure and surface smoothing on dentinal surfaces of human teeth and their resultant temperature increases within the pulpal canals with the Holmium:YAG laser. An optimal working spot size and even absorption pattern were produced by defocusing the laser beam and evaluated by images produced on light exposed and developed photographic paper. The surface effects on dentin were examined by scanning electron microscopy. A thermocouple was positioned in the canals of fresh dissected dog jaws and attached to a recorder which produced a graph of the temperature changes. The in vitro research model for intrapulpal temperatures changes was verified by comparing premortem and postmortem temperature readings. The same protocol was used to evaluate temperature changes in fresh human extracted teeth. In vivo histological studies were conducted to evaluate the effects of HO:YAG laser energy on pulpal tissues. The results of these studies indicate the HO:YAG laser at a wavelength of 2.12 microns can be safely and effectively used for photoconditioning of the dentinal surfaces of teeth in clinical conditions.

  12. Magnetic field-dependent spin structures of nanocrystalline holmium

    PubMed Central

    Szary, Philipp; Kaiser, Daniel; Bick, Jens-Peter; Lott, Dieter; Heinemann, André; Dewhurst, Charles; Birringer, Rainer; Michels, Andreas

    2016-01-01

    The results are reported of magnetic field-dependent neutron diffraction experiments on polycrystalline inert-gas condensed holmium with a nanometre crystallite size (D = 33 nm). At T = 50 K, no evidence is found for the existence of helifan(3/2) or helifan(2) structures for the nanocrystalline sample, in contrast with results reported in the literature for the single crystal. Instead, when the applied field H is increased, the helix pattern transforms progressively, most likely into a fan structure. It is the component of H which acts on the basal-plane spins of a given nanocrystallite that drives the disappearance of the helix; for nanocrystalline Ho, this field is about 1.3 T, and it is related to a characteristic kink in the virgin magnetization curve. For a coarse-grained Ho sample, concomitant with the destruction of the helix phase, the emergence of an unusual angular anisotropy (streak pattern) and the appearance of novel spin structures are observed. PMID:27047307

  13. An architecture for quantum computation with magnetically trapped Holmium atoms

    NASA Astrophysics Data System (ADS)

    Saffman, Mark; Hostetter, James; Booth, Donald; Collett, Jeffrey

    2016-05-01

    Outstanding challenges for scalable neutral atom quantum computation include correction of atom loss due to collisions with untrapped background gas, reduction of crosstalk during state preparation and measurement due to scattering of near resonant light, and the need to improve quantum gate fidelity. We present a scalable architecture based on loading single Holmium atoms into an array of Ioffe-Pritchard traps. The traps are formed by grids of superconducting wires giving a trap array with 40 μm period, suitable for entanglement via long range Rydberg gates. The states | F = 5 , M = 5 > and | F = 7 , M = 7 > provide a magic trapping condition at a low field of 3.5 G for long coherence time qubit encoding. The F = 11 level will be used for state preparation and measurement. The availability of different states for encoding, gate operations, and measurement, spectroscopically isolates the different operations and will prevent crosstalk to neighboring qubits. Operation in a cryogenic environment with ultra low pressure will increase atom lifetime and Rydberg gate fidelity by reduction of blackbody induced Rydberg decay. We will present a complete description of the architecture including estimates of achievable performance metrics. Work supported by NSF award PHY-1404357.

  14. Lanthanum(III) and praseodymium(III) derivatives with dithiocarbamates derived from α-amino acids

    NASA Astrophysics Data System (ADS)

    Rai, Anita; Sengupta, Soumitra K.; Pandey, Om P.

    2006-06-01

    Lanthanum(III) and praseodymium(III) complexes with dithiocarbamates have been synthesized by the reactions of lanthanum(III) and praseodymium(III) chloride with barium dithiocarbamate and complexes of type [LnCl(L)H 2O] n have been obtained (where Ln = La(III) or Pr(III); L = barium salt of dithiocarbamate derived from glycine, L-leucine, L-valine, DL-alanine). The complexes have been characterized by elemental analysis, molar conductance, electronic absorption and fluorescence, infrared, far infrared, 1H NMR spectral studies. The presence of coordinated water molecule is inferred from thermogravimetric analysis which indicates the loss of one water molecule at 150-170 °C. The oscillator strength, Judd-Ofelt intensity parameter, stimulated emission cross-section, etc. have been obtained for different transitions of Pr 3+.

  15. Interaction of some fluorinated nucleic acid components with praseodymium: an absorption spectral approach.

    PubMed

    Misra, S N

    1990-10-01

    Absorption difference and comparative absorption spectrophotometric studies on praseodymium(III) and fluorouracil, fluorocytosine, fluoroadenine, fluorothymine, fluorouridine, fluorocytidine, fluoroadenosine and fluorothymidine systems at pH approximately 5.5 and in different stoichiometries in 80% DMF medium have been carried out. Magnitudes of spectral parameters, viz. Coulombic (Fk), spin-orbit (zeta 4f), nephelauxetic (beta), bonding (b), intensity (T lambda Judd-Ofelt), and oscillator strength (P) and their variation have provided information on the binding mode of these biomolecules in terms of outer and inner sphere complexation, degree of covalency and extent of 4f orbital involvement. Preliminary ultrasonic studies have indicated that these biomolecules behave as structure breakers, hence weak ligands in aqueous medium, while strengthening water structure in semi-nonaqueous medium. The analysis of the isolated solid complexes has suggested octa- and nona-coordination for praseodymium(III) in fluorinated nucleic bases and fluorinated nucleoside complexes.

  16. Effect of praseodymium nitrate on hepatocytes and Kupffer cells in the rat.

    PubMed

    Tuchweber, B; Trost, R; Salas, M; Sieck, W

    1976-12-01

    Intravenous administration of the rare earth metal salt, praseodymium nitrate, induced hepatic damage in the rat, as assessed by morphologic examination (light and electron microscopy) and biochemical parameters (serum glutamic-pyruvic transaminase (EC 2.6.1.2) and glutamic-oxalacetic transaminase (EC 2.6.1.1) activity as well as hepatic triglyceride content). Praseodymium hepatotoxicity was only attained with lower doses (10, 20, or 40 mg/kg), whereas a larger dose (80 mg/kg) was inactive in this respect. As detected by electron microscopy, lower doses of the metal salt caused hepatocytic alterations consisting of degranulation and dilatation of rough endoplasmic reticulum, accumulation of smooth endoplasmic reticulum as well as numerous lipid droplets. No abnormalities were detected in the cell organelles following administration of a large dose of the metal salt; however, vacuoles containing markedly electron-dense material were seen in the cytoplasm of the hepatocytes and the sinusoidal Kupffer cells.

  17. Investigation of Praseodymium Fluorides: A Combined Matrix-Isolation and Quantum-Chemical Study.

    PubMed

    Vent-Schmidt, Thomas; Riedel, Sebastian

    2015-12-01

    The chemistry of the lanthanides is mostly dominated by compounds in the oxidation state +III. Only few compounds of Ce, Pr, and Tb are known with the metal in the +IV oxidation state. Removal of the last f-electron on praseodymium +IV would lead to a closed-shell system with formal oxidation state V. In this work we investigated the stability of the PrF5 molecule by theory and matrix-isolation techniques through the reaction of laser-ablated praseodymium atoms with fluorine in excess of neon, argon, krypton, or neat fluorine. Besides the known PrF3 molecule, unreported IR bands for PrF4 could be observed, and there is evidence for the formation of PrF and PrF2 but not for the formation of PrF5.

  18. Lanthanum(III) and praseodymium(III) derivatives with dithiocarbamates derived from alpha-amino acids.

    PubMed

    Rai, Anita; Sengupta, Soumitra K; Pandey, Om P

    2006-06-01

    Lanthanum(III) and praseodymium(III) complexes with dithiocarbamates have been synthesized by the reactions of lanthanum(III) and praseodymium(III) chloride with barium dithiocarbamate and complexes of type [LnCl(L)H2O]n have been obtained (where Ln=La(III) or Pr(III); L=barium salt of dithiocarbamate derived from glycine, L-leucine, L-valine, DL-alanine). The complexes have been characterized by elemental analysis, molar conductance, electronic absorption and fluorescence, infrared, far infrared, 1H NMR spectral studies. The presence of coordinated water molecule is inferred from thermogravimetric analysis which indicates the loss of one water molecule at 150-170 degrees C. The oscillator strength, Judd-Ofelt intensity parameter, stimulated emission cross-section, etc. have been obtained for different transitions of Pr3+.

  19. Investigation of Praseodymium Fluorides: A Combined Matrix-Isolation and Quantum-Chemical Study.

    PubMed

    Vent-Schmidt, Thomas; Riedel, Sebastian

    2015-12-01

    The chemistry of the lanthanides is mostly dominated by compounds in the oxidation state +III. Only few compounds of Ce, Pr, and Tb are known with the metal in the +IV oxidation state. Removal of the last f-electron on praseodymium +IV would lead to a closed-shell system with formal oxidation state V. In this work we investigated the stability of the PrF5 molecule by theory and matrix-isolation techniques through the reaction of laser-ablated praseodymium atoms with fluorine in excess of neon, argon, krypton, or neat fluorine. Besides the known PrF3 molecule, unreported IR bands for PrF4 could be observed, and there is evidence for the formation of PrF and PrF2 but not for the formation of PrF5. PMID:26544761

  20. Proximal fiber tip damage during Holmium:YAG and thulium fiber laser ablation of kidney stones

    NASA Astrophysics Data System (ADS)

    Wilson, Christopher R.; Hardy, Luke A.; Irby, Pierce B.; Fried, Nathaniel M.

    2016-02-01

    The Thulium fiber laser (TFL) is being studied as an alternative to Holmium:YAG laser for lithotripsy. TFL beam originates within an 18-μm-core thulium doped silica fiber, and its near single mode, Gaussian beam profile enables transmission of higher laser power through smaller fibers than possible during Holmium laser lithotripsy. This study examines whether TFL beam profile also reduces proximal fiber tip damage compared to Holmium laser multimodal beam. TFL beam at wavelength of 1908 nm was coupled into 105-μm-core silica fibers, with 35-mJ energy, 500-μs pulse duration, and pulse rates of 50-500 Hz. For each pulse rate, 500,000 pulses were delivered. Magnified images of proximal fiber surfaces were taken before and after each trial. For comparison, 20 single-use, 270-μm-core fibers were collected after clinical Holmium laser lithotripsy procedures using standard settings (600 mJ, 350 μs, 6 Hz). Total laser energy, number of laser pulses, and laser irradiation time were recorded, and fibers were rated for damage. For TFL studies, output power was stable, and no proximal fiber damage was observed after delivery of 500,000 pulses at settings up to 35 mJ, 500 Hz, and 17.5 W average power. In contrast, confocal microscopy images of fiber tips after Holmium lithotripsy showed proximal fiber tip degradation in all 20 fibers. The proximal fiber tip of a 105-μm-core fiber transmitted 17.5 W of TFL power without degradation, compared to degradation of 270-μm-core fibers after transmission of 3.6 W of Holmium laser power. The smaller and more uniform TFL beam profile may improve fiber lifetime, and potentially reduce costs for the surgical disposables as well.

  1. High-Resolution Spectroscopy of K-shell Praseodymium with a High-Energy Calorimeter

    SciTech Connect

    Thorn, D B; Brown, G V; Clementson, J T; Chen, H; Chen, M H; Beiersdorfer, P; Boyce, K R; Kilbourne, C A; Porter, F S; Kelley, R L

    2007-06-05

    We present a measurement of the K-shell spectrum of He-like through Be-like praseodymium ions trapped in the Livermore SuperEBIT electron beam ion trap using a bismuth absorber pixel on the XRS/EBIT microcalorimeter. This measurement is the first of its kind where the n=2 to n=1 transitions of the various charge states are spectroscopically resolved. The measured transition energies are compared with theoretical calculations from several atomic codes.

  2. Age hardening and creep resistance of cast Al–Cu alloy modified by praseodymium

    SciTech Connect

    Bai, Zhihao; Qiu, Feng; Wu, Xiaoxue; Liu, Yingying; Jiang, Qichuan

    2013-12-15

    The effects of praseodymium on age hardening behavior and creep resistance of cast Al–Cu alloy were investigated. The results indicated that praseodymium facilitated the formation of the θ′ precipitates during the age process and improved the hardness of the Al–Cu alloy. Besides, praseodymium resulted in the formation of the Al{sub 11}Pr{sub 3} phase in the grain boundaries and among the dendrites of the modified alloy. Because of the good thermal stability of Al{sub 11}Pr{sub 3} phase, it inhibits grain boundary migration and dislocation movement during the creep process, which contributes to the improvement in the creep resistance of the modified alloy at elevated temperatures. - Highlights: • Pr addition enhances the hardness and creep resistance of the Al–Cu alloy. • Pr addition facilitates the formation of the θ′ precipitates. • Pr addition results in the formation of the Al11Pr3 phase in the Al–Cu alloy.

  3. Nanothermometry using optically trapped erbium oxide nanoparticle

    NASA Astrophysics Data System (ADS)

    Baral, Susil; Johnson, Samuel C.; Alaulamie, Arwa A.; Richardson, Hugh H.

    2016-04-01

    A new optical probe technique using a laser-trapped erbium oxide nanoparticle (size ~150 nm) is introduced that can measure absolute temperature with a spatial resolution on the size of the trapped nanoparticle. This technique (scanning optical probe thermometry) is used to collect a thermal image of a gold nanodot prepared with hole-mask colloidal lithography. A convolution analysis of the thermal profile shows that the point spread function of our measurement is a Gaussian with a FWHM of 165 nm. We attribute the width of this function to clustering of Er2O3 nanoparticles in solution. The scanning optical probe thermometer is used to measure the temperature where vapor nucleation occurs in degassed water (555 K), confirming that a nanoscale object heated in water will superheat the surrounding water to the spinodal decomposition temperature. Subsequently, the temperature inside the vapor bubble rises to the melting point of the gold nanostructure (~1300) where a temperature plateau is observed. The rise in temperature is attributed to inhibition of thermal transfer to the surrounding liquid by the thermal insulating vapor cocoon.

  4. Laser cooling transitions in atomic erbium.

    PubMed

    Ban, H; Jacka, M; Hanssen, J; Reader, J; McClelland, J

    2005-04-18

    We discuss laser cooling opportunities in atomic erbium, identifying five J ? J + 1 transitions from the 4f126s2 3H6 ground state that are accessible to common visible and near-infrared continuous-wave tunable lasers. We present lifetime measurements for the 4f11(4Io 15/2)5d5/26s2 (15/2, 5/2)7o state at 11888 cm-1 and the 4f11(4Io 13/2)5d3/26s2 (13/2, 5/2)7o state at 15847 cm-1, showing values of 20 +/- 4 micros and 5.6 +/- 1.4 micros, respectively. We also present a calculated value of 13 +/- 7 s-1 for the transition rate from the 4f11(4Io 15/2)5d3/26s2 (15/2, 3/2)7 o state at 7697 cm-1 to the ground state, based on scaled Hartree-Fock energy parameters. Laser cooling on these transitions in combination with a strong, fast (5.8 ns) laser cooling transition at 401 nm, suggest new opportunities for narrowband laser cooling of a large-magnetic moment atom, with possible applications in quantum information processing, high-precision atomic clocks, quantum degenerate gases, and deterministic single-atom doping of materials.

  5. Activatino of Erbium Films for Hydrogen Storage

    SciTech Connect

    M Brumbach; j Ohlhausen; K Zavadil; C Snow; J Woicik

    2011-12-31

    Hydriding of metals can be routinely performed at high temperature in a rich hydrogen atmosphere. Prior to the hydrogen loading process, a thermal activation procedure is required to promote facile hydrogen sorption into the metal. Despite the wide spread utilization of this activation procedure, little is known about the chemical and electronic changes that occur during activation and how this thermal pretreatment leads to increased rates of hydrogen uptake. This study utilized variable kinetic energy X-ray photoelectron spectroscopy to interrogate the changes during in situ thermal annealing of erbium films, with results confirmed by time-of-flight secondary ion mass spectrometry and low energy ion scattering. Activation can be identified by a large increase in photoemission between the valence band edge and the Fermi level and appears to occur over a two stage process. The first stage involves desorption of contaminants and recrystallization of the oxide, initially impeding hydrogen loading. Further heating overcomes the first stage and leads to degradation of the passive surface oxide leading to a bulk film more accessible for hydrogen loading.

  6. Erbium concentration dependent absorbance in tellurite glass

    SciTech Connect

    Sazali, E. S. Rohani, M. S. Sahar, M. R. Arifin, R. Ghoshal, S. K. Hamzah, K.

    2014-09-25

    Enhancing the optical absorption cross-section in topically important rare earth doped tellurite glasses is challenging for photonic devices. Controlled synthesis and detailed characterizations of the optical properties of these glasses are important for the optimization. The influence of varying concentration of Er{sup 3+} ions on the absorbance characteristics of lead tellurite glasses synthesized via melt-quenching technique are investigated. The UV-Vis absorption spectra exhibits six prominent peaks centered at 490, 526, 652, 800, 982 and 1520 nm ascribed to the transitions in erbium ion from the ground state to the excited states {sup 4}F{sub 7/2}, {sup 2}H{sub 11/2}, {sup 4}F{sub 9/2}, {sup 4}I{sub 9/2}, {sup 2}H{sub 11/2} and {sup 4}I{sub 13/2}, respectively. The results are analyzed by means of optical band gap E{sub g} and Urbach energy E{sub u}. The values of the energy band gap are found decreased from 2.82 to 2.51 eV and the Urbach energy increased from 0.15 to 0.24 eV with the increase of the Er{sub 2}O{sub 3} concentration from 0 to 1.5 mol%. The excellent absorbance of the prepared tellurite glasses makes them suitable for fabricating solid state lasers.

  7. Magnetic transitions in erbium at high pressures

    NASA Astrophysics Data System (ADS)

    Thomas, Sarah A.; Tsoi, Georgiy M.; Wenger, Lowell E.; Vohra, Yogesh K.; Weir, Samuel T.

    2012-04-01

    Electrical resistance measurements have been carried out on polycrystalline erbium (Er) at temperatures down to 10 K and pressures up to 20 GPa. An abrupt change in the slope of the resistance is observed with decreasing temperature below 84 K which is associated with the c-axis modulated antiferromagnetic (AFM) ordering of the Er moments. With increasing pressure, the temperature of this resistance slope change and the corresponding AFM ordering temperature decrease until vanishing above 10.6 GPa. At higher pressures, a more gradual change in the slope of the resistance is found to occur around 45 K which disappears at pressures near 17 GPa. The transformation from the hexagonal-close-packed structural phase to a nine-layer α-Sm structural phase at a similar pressure of 11 GPa indicates (i) that the disappearance in the c-axis modulated antiferromagnetic ordering of Er moments above 10.6 GPa is correlated to the structural phase change and (ii) that the smaller resistance changes around 45 K result from a different magnetic structure associated with the α-Sm structural phase.

  8. Activation of erbium films for hydrogen storage

    NASA Astrophysics Data System (ADS)

    Brumbach, Michael T.; Ohlhausen, James A.; Zavadil, Kevin R.; Snow, Clark S.; Woicik, Joseph C.

    2011-06-01

    Hydriding of metals can be routinely performed at high temperature in a rich hydrogen atmosphere. Prior to the hydrogen loading process, a thermal activation procedure is required to promote facile hydrogen sorption into the metal. Despite the wide spread utilization of this activation procedure, little is known about the chemical and electronic changes that occur during activation and how this thermal pretreatment leads to increased rates of hydrogen uptake. This study utilized variable kinetic energy X-ray photoelectron spectroscopy to interrogate the changes during in situ thermal annealing of erbium films, with results confirmed by time-of-flight secondary ion mass spectrometry and low energy ion scattering. Activation can be identified by a large increase in photoemission between the valence band edge and the Fermi level and appears to occur over a two stage process. The first stage involves desorption of contaminants and recrystallization of the oxide, initially impeding hydrogen loading. Further heating overcomes the first stage and leads to degradation of the passive surface oxide leading to a bulk film more accessible for hydrogen loading.

  9. Use of the holmium:YAG laser in urology

    NASA Astrophysics Data System (ADS)

    Johnson, Douglas E.; Cromeens, Douglas M.; Price, Roger E.

    1992-06-01

    The Holmium:YAG (Ho:YAG) laser operating at a wavelength of 2.1 micrometers with a maximum power of 15 watts (W) and 10 different pulse-energy settings was systematically evaluated on kidney, bladder, prostate, ureteral, and vasal tissue, and was used to perform various urologic surgical procedures (partial nephrectomy, transurethral laser incision of the prostate, and laser-assisted vasovasostomy) in the dog. By using the SurgiTomeTM 3- inch straight delivery system with an energy-pulse setting of 0.5 joules (J) at 20 Hz (10 W), partial nephrectomies required slightly longer operating times (15 minutes) than when similar procedures were performed using the Neodymium:YAG (Nd:YAG) laser and a free GI fiber at 59 to 83 W (4 - 7 minutes); however, the total energy required was considerably less. Hemostasis was excellent and no sutures were required to control bleeding. Transurethral incisions of the prostate using TV monitoring were made at the 4 and 8 o'clock positions extending from the colliculus seminalis through the vesical neck with an energy/pulse setting of 1.0 J at 15 Hz (15 W). Attempts at laser-assisted vasovasostomies were unsuccessful due to excessive thermal affect. The LaparoTomeTM Delivery System proved helpful in performing laparoscopic pelvic lymphadenectomy in the pig. Our investigations showed that the Ho:YAG laser possesses both excellent cutting and adequate hemostatic abilities even in a fluid medium. Although these results are preliminary, we believe that the Ho:YAG laser is well suited for urologic surgery and may well become the 'urologist's laser of the future.'

  10. Erbium:YAG laser resurfacing using a novel portable device.

    PubMed

    Gordon, James; Khan, Misbah H; Khatri, Khalil A

    2007-05-01

    Laser resurfacing of facial rhytids has become a popular treatment for many patients who have wrinkles, photodamage, and acne scarring. Erbium:YAG laser resurfacing has emerged as one of the safer, more effective methods of facial rejuvenation and its increasing popularity has led to its widespread use for resurfacing. However, size and high initial and maintenance cost are among the problems with currently available laser devices. The LightPod portable Erbium:YAG laser from Aerolase offers a new paradigm for more cost effective means of performing ablative resurfacing with reduced initial and maintenance cost and the ease of portability with significantly reduced size and weight. The objective of this pilot study was to analyze the efficacy of The LightPod Erbium:YAG laser in different skin types for various indications.

  11. Dipolar Physics in an Erbium Quantum Gas Microscope

    NASA Astrophysics Data System (ADS)

    Hebert, Anne; Krahn, Aaron; Phelps, Gregory; Dickerson, Susannah; Greiner, Markus; Erbium Lab Team

    2016-05-01

    Erbium offers exciting possibilities for extending the single-site imaging work of current quantum gas microscopes. With a magnetic dipole moment of 7μB, the dipole-dipole interaction of erbium is 50 times that of alkali atoms. The long-range and anisotropic nature of the dipole interaction adds richness to the short-range interactions that dominate the physics of the ground-state alkali atoms commonly used in ultracold experiments today. Erbium has several abundant isotopes, giving the added flexibility of studying both bosonic and fermionic systems. We present proposed avenues of research for the dipolar microscope being developed, including studies of magnetism, the Einstein-de Haas effect, and quantum phase transitions with fractional filling factors.

  12. Luminescence of erbium-doped bismuth borate glasses

    NASA Astrophysics Data System (ADS)

    Oprea, Isabella-Ioana; Hesse, Hartmut; Betzler, Klaus

    2006-07-01

    Absorption and luminescence properties of erbium ions in the binary glass system bismuth oxide (Bi 2O 3)-boric oxide (B 2O 3) are measured for the composition range 25-65 mol% Bi 2O 3. A Judd-Ofelt analysis of the typical erbium bands in the absorption spectra reveals comparably high Judd-Ofelt coefficients. This indicates a substantial mixing of other electronic configuration into the 4f N configuration by the random crystal fields in the glasses. All coefficients are decreasing with increasing Bi 2O 3 content, this effect being most pronounced with Ω2. Luminescence decay times and radiative efficiencies show an expressed dependence on the glass composition. Radiative efficiencies of all luminescence bands increase with increasing Bi 2O 3 content—accompanied, however, by a slight narrowing of the bands. Except the common luminescence bands of erbium, upconversion luminescence at a wavelength of 0.54 μm could be detected.

  13. Laser-assisted hair transplantation: histologic comparison between holmium:YAG and CO2 lasers

    NASA Astrophysics Data System (ADS)

    Chu, Eugene A.; Rabinov, C. Rose; Wong, Brian J.; Krugman, Mark E.

    1999-06-01

    The histological effects of flash-scanned CO2 (λ=10.6μm) and pulsed Holmium:YAG (Ho:YAG, λ=2.12μm) lasers were evaluated in human scalp following the creation of hair transplant recipient channels. Ho:YAG laser irradiation created larger zones of thermal injury adjacent to the laser channels than irradiation with the CO2 laser device. When the two lasers created recipient sites of nearly equal depth, the Holmium:YAG laser caused a larger region of lateral thermal damage (589.30μm) than the CO2 laser (118.07μm). In addition, Holmium:YAG irradiated specimens exhibited fractures or discontinuities beyond the region of clear thermal injury. This shearing effect is consistent with the photoacoustic mechanism of ablation associated with pulsed mid-IR laser irradiation. In contrast, channels created with the CO2 exhibited minimal epithelial disruption and significantly less lateral thermal damage. While the Holmium:YAG laser is a useful tool for ablation soft tissue with minimal char in select applications (sinus surgery, arthroscopic surgery), this study suggests that the use of the CO2 laser for the creation of transplantation recipient channels result in significantly less lateral thermal injury for the laser parameters employed.

  14. Effects Of Holmium-YSGG Laser Irradiation On Arterial Tissue: Preliminary Results

    NASA Astrophysics Data System (ADS)

    Aretz, H. Thomas; Butterly, John R.; Jewell, Edward R.; Setzer, Suzanne E.; Shapshay, Stanley M.

    1989-06-01

    The effects of pulsed holmium-YSGG laser energy (2.1 μm) on arterial tissue were studied in vitro and in vivo. Delivered through silica optical fibers, the laser ablated calcified and noncalcified tissue in air and saline in a noncontact mode. Early in vivo healing studies in normal canine carotid arteries showed minimal chronic sequelae at 3 weeks.

  15. Holmium laser for treatment of benign prostatic hyperplasia: old wine in a new bottle?

    NASA Astrophysics Data System (ADS)

    Nelius, Thomas; de Riese, Werner T. W.

    2003-06-01

    Urinary tract symptoms related to benign prostatic hyperplasia affect 70% of men older than 70 years. Complications are common problems and a significant cause of morbidity in this population, placing a considerable burden on health services. In the early 1990s laser treatment of benign prostatic hyperplasia became widely used after the introduction of the side-firing neodym: YAG laser. However, because of technical limitations and inferior results compared to classical transurethral resection of the prostate many Urologists became desinterested in this device. With the introduction of the holmium: YAG laser a new laser generation became available for use in Urology. Beside several other applications the holmium: YAG laser can be used for incision, ablation, resection, and more recently enucleation of the prostate. In this paper we reviewed the current literature regarding the holmium: YAG laser resection and enucleation of the prostate compared to transurethral resection of the prostate and open prostatectomy. The holmium: YAG laser technique is an effective and durable surgical alternative to standard transurethral resection of the prostate. Interestingly, enucleation of the prostate with this device seems to be a safe and effective procedure for large prostatic adenomas, it may become an attractive alternative to open prostatectomy.

  16. Preparation and complex characterization of silica holmium sol-gel monoliths.

    PubMed

    Cacaina, D; Areva, S; Laaksonen, H; Simon, S; Ylänen, H

    2011-01-01

    Amorphous, sol-gel derived SiO(2) are known to biocompatible and bioresorbable materials. Biodegradable and inert materials containing radioactive isotopes have potential application as delivery vehicles of the beta radiation to the cancer tumors inside the body. Incorporation of holmium in the sol-gel derived SiO(2) could lead to the formation of a biodegradable material which could be used as carrier biomaterial for the radiation of radioactive holmium to the various cancer sites. The homogeneity of the prepared sol-gel silica holmium monoliths was investigated by Back Scattered Electron Imaging of Scanning Electron Microscope equipped with Energy Dispersive X-ray Analysis, X-ray Induced Photoelectron Spectroscopy and Nuclear Magnetic Resonance Spectroscopy. The biodegradation of the monoliths was investigated in Simulated Body Fluid and TRIS (Trizma pre-set Crystals) solution. The results show that by suitable tailoring of the sol-gel processing parameters holmium can be homogeneously incorporated in the silica matrix with a controlled biodegradation rate.

  17. Chiral holmium complex-catalyzed Diels-Alder reaction of silyloxyvinylindoles: stereoselective synthesis of hydrocarbazoles.

    PubMed

    Harada, Shinji; Morikawa, Takahiro; Nishida, Atsushi

    2013-10-18

    The catalytic and asymmetric cycloaddition between 3-[1-(silyloxy)vinyl]indoles and electron-deficient olefins gave substituted hydrocarbazoles in up to 99% yield and 94% ee. This reaction was catalyzed by a novel chiral holmium(III) complex. Alkylation of the cycloadduct gave a tricyclic compound with four continuous chiral centers, one of which was a quaternary carbon.

  18. Fiber-optic manipulation of urinary stone phantoms using holmium:YAG and thulium fiber lasers

    NASA Astrophysics Data System (ADS)

    Blackmon, Richard L.; Case, Jason R.; Trammell, Susan R.; Irby, Pierce B.; Fried, Nathaniel M.

    2013-02-01

    Fiber-optic attraction of urinary stones during laser lithotripsy may be exploited to manipulate stone fragments inside the urinary tract without mechanical grasping tools, saving the urologist time and space in the ureteroscope working channel. We compare thulium fiber laser (TFL) high pulse rate/low pulse energy operation to conventional holmium:YAG low pulse rate/high pulse energy operation for fiber-optic suctioning of plaster-of-paris (PoP) stone phantoms. A TFL (wavelength of 1908 nm, pulse energy of 35 mJ, pulse duration of 500 μs, and pulse rate of 10 to 350 Hz) and a holmium laser (wavelength of 2120 nm, pulse energy of 35 to 360 mJ, pulse duration of 300 μs, and pulse rate of 20 Hz) were tested using 270-μm-core optical fibers. A peak drag speed of ˜2.5 mm/s was measured for both TFL (35 mJ and 150 to 250 Hz) and holmium laser (210 mJ and 20 Hz). Particle image velocimetry and thermal imaging were used to track water flow for all parameters. Fiber-optic suctioning of urinary stone phantoms is feasible. TFL operation at high pulse rates/low pulse energies is preferable to holmium operation at low pulse rates/high pulse energies for rapid and smooth stone pulling. With further development, this novel technique may be useful for manipulating stone fragments in the urinary tract.

  19. Spectroscopic properties and Judd-Ofelt theory analysis of erbium chelates.

    PubMed

    Wang, Huaishan; Qian, Guodong; Wang, Zhiyu; Wang, Minquan

    2005-11-01

    Erbium chelates including tris(acetylacetonato) erbium(III) monohydrate, tris(acetylacetonato)(1,10-phenanthroline) erbium(III) and tris(trifluoroacetylacetonato)(1,10-phenanthroline) erbium(III) are synthesized. Judd-Ofelt theory is employed on basis of the UV-Vis-NIR absorption spectra of erbium chelates dissolved in methanol. Judd-Ofelt parameters of erbium chelates are determined by a least square fitting and dealt with the chemical structure of erbium chelates. Photoluminescence characteristics of erbium chelates are investigated upon excitation at 488 nm by an Ar(+) laser. The qualitative correlation of Judd-Ofelt parameters with photoluminescence properties for erbium chelates is also discussed. It is found that larger Omega(6) value for erbium chelate is and larger photoluminescence intensity at 1.54 microm is, and Omega(2) value should contribute to the photoluminescence full width at half maximum (FWHM) at 1.54 microm. The changes of Judd-Ofelt parameters result from the introduction of the second ligand phenathroline or the substitution of electron-drawing group CF(3) in beta-diketone for erbium chelates.

  20. Nonlinear optical responses of erbium-doped YAG ceramics

    NASA Astrophysics Data System (ADS)

    Sun, Wangliang; Yi, Jun; Miao, Lili; Li, Jiang; Xie, Tengfei; Zhao, Chujun; Pan, Yubai; Wen, Shuangchun

    2016-07-01

    By performing the Z-scan measurements with ultrafast femtosecond laser centered at 800 nm wavelength, we can unambiguously distinguish the real and imaginary part of the third-order optical nonlinearity of the erbium-doped YAG ceramics. The reverse saturable absorption of the erbium-doped YAG ceramics has been observed experimentally, and the nonlinear refractive index of the ceramics is estimated to be about 10-21 m2/W. The experimental results may provide design guidelines for the high power laser design and its applications.

  1. Characterization of the surface changes during the activation process of erbium/erbium oxide for hydrogen storage.

    SciTech Connect

    Zavadil, Kevin Robert; Snow, Clark Sheldon; Ohlhausen, James Anthony; Brumbach, Michael Todd

    2010-10-01

    Erbium is known to effectively load with hydrogen when held at high temperature in a hydrogen atmosphere. To make the storage of hydrogen kinetically feasible, a thermal activation step is required. Activation is a routine practice, but very little is known about the physical, chemical, and/or electronic processes that occur during Activation. This work presents in situ characterization of erbium Activation using variable energy photoelectron spectroscopy at various stages of the Activation process. Modification of the passive surface oxide plays a significant role in Activation. The chemical and electronic changes observed from core-level and valence band spectra will be discussed along with corroborating ion scattering spectroscopy measurements.

  2. Holmium:YAG laser coronary angioplasty: quantitative angiography and clinical results in a large experience of a single medical center

    NASA Astrophysics Data System (ADS)

    Topaz, On; Luxenberg, Michael; Schumacher, Audrey

    1994-07-01

    Clinical experience with the mid IR holmium:YAG laser in a single medical center (St. Paul Ramsey Medical Center, University of Minnesota Medical School, St. Paul, MN) includes 112 patients who underwent holmium laser coronary angioplasty. Utilizing a unique lasing technique; `pulse and retreat,' we applied this laser to thrombotic and nonthrombotic lesions in patients presenting with unstable angina, stable angina, and acute myocardial infarction. A very high clinical success and very low complication rates were achieved. Holmium:YAG laser is effective and safe therapy for patients with symptomatic coronary artery disease. Unlike excimer lasers, the clinical success, efficacy and safety of holmium laser angioplasty is not compromised when thrombus is present.

  3. Comparative studies of praseodymium(III) selective sensors based on newly synthesized Schiff's bases.

    PubMed

    Gupta, Vinod K; Goyal, Rajendra N; Pal, Manoj K; Sharma, Ram A

    2009-10-27

    Praseodymium ion selective polyvinyl chloride (PVC) membrane sensors, based on two new Schiff's bases 1,3-diphenylpropane-1,3-diylidenebis(azan-1-ylidene)diphenol (M(1)) and N,N'-bis(pyridoxylideneiminato) ethylene (M(2)) have been developed and studied. The sensor having membrane composition of PVC: o-NPOE: ionophore (M(1)): NaTPB (w/w; mg) of 150: 300: 8: 5 showed best performances in comparison to M(2) based membranes. The sensor based on (M(1)) exhibits the working concentration range 1.0x10(-8) to 1.0x10(-2) M with a detection limit of 5.0x10(-9) M and a Nernstian slope 20.0+/-0.3 mV decade(-1) of activity. It exhibited a quick response time as <8 s and its potential responses were pH independent across the range of 3.5-8.5. The influence of the membrane composition and possible interfering ions have also been investigated on the response properties of the electrode. The sensor has been found to work satisfactorily in partially non-aqueous media up to 15% (v/v) content of methanol, ethanol or acetonitrile and could be used for a period of 3 months. The selectivity coefficients determined by using fixed interference method (FIM) indicate high selectivity for praseodymium(III) ions over wide variety of other cations. To asses its analytical applicability the prepared sensor was successfully applied for determination of praseodymium(III) in spiked water samples.

  4. Growth of praseodymium oxide on Si(111) under oxygen-deficient conditions

    SciTech Connect

    Schaefer, A.; Zielasek, V.; Baeumer, M.; Schmidt, Th.; Schowalter, M.; Schulz, Ch.; Rosenauer, A.; Falta, J.; Sandell, A.; Seifarth, O.; Schroeder, T.; Wollschlaeger, J.

    2009-07-15

    Surface science studies of thin praseodymium oxide films grown on silicon substrates are of high interest in view of applications in such different fields as microelectronics and heterogeneous catalysis. In particular, a detailed characterization of the growth and the final structure of the films are mandatory to achieve a fundamental understanding of such topics as oxygen mobility and defect structure, and their role for the electronic and chemical properties. In this paper, the MBE growth of praseodymium oxide films on Si(111) substrates was investigated at low-deposition rates (0.06 nm/min) and low-oxygen partial pressures (p(O{sub 2})<1x10{sup -10} mbar). To obtain insight into the structure and chemical composition of the growing film, spot profile analyzing low-energy electron diffraction (SPA-LEED), transmission electron microscopy, and synchrotron radiation-based x-ray photoelectron spectroscopy (XPS) and x-ray absorption spectroscopy (XAS) were applied. SPA-LEED reveals the formation of an initial closed layer followed by continuous roughening and formation of ordered three-dimensional structures. This result is in contrast to observations at higher-deposition rates, were a layer-by-layer growth was reported. XAS and XPS provide evidence that a continuous reaction takes place in the growing Pr{sub 2}O{sub 3} film leading to the formation of silicate and silicide structures within the film. Combining all data, a consistent picture of the deposition of praseodymium oxide on Si(111) emerges which clearly shows that in contrast to higher-throughput molecular beam epitaxy conditions the reactivity of the growing film strongly influences the growth behavior at low-deposition rates and low pressures.

  5. COEXISTENCE OF DIFFERENT TYPES OF TRANSVERSE CONDUCTIVITY IN Y1-xPrxBa2Cu3 O7-δ SINGLE CRYSTALS WITH DIFFERENT PRASEODYMIUM CONCENTRATIONS

    NASA Astrophysics Data System (ADS)

    Vovk, R. V.; Vovk, N. R.; Goulatis, I. L.; Chroneos, A.

    2013-10-01

    In this paper, the influence of praseodymium doping on the conductivity across (transverse) the basal plane of high-temperature superconducting Y1-xPrxBa2Cu3O7-δ single crystals is investigated. It is determined that an increase of praseodymium doping leads to increased localization effects and the implementation of a metal-insulator transition Y1-xPrxBa2Cu3O7-δ, which always precedes the superconducting transition. The increase of the praseodymium concentration also leads to a significant displacement of the point of the metal-insulator transition to the low temperature region.

  6. Praseodymium methanesulfonate catalyzed one-pot synthesis of 3,4-dihydropyrimidin-2-(1H)-ones.

    PubMed

    Wang, Min; Song, Zhiguo; Gong, Hong; Jiang, Heng

    2008-01-01

    A series of 3,4-dihydropyrimidin-2-(1H)-ones compounds was synthesized efficiently by a one-pot cyclocondensation of an aldehyde, 1,3-dicarbonyl compound, and urea in absolute ethanol under refluxing temperature using praseodymium methanesulfonate as catalyst. After the reaction, the catalyst can be easily recovered and reused several times without distinct decrease in reaction yields.

  7. Quantitative Monte Carlo-based holmium-166 SPECT reconstruction

    SciTech Connect

    Elschot, Mattijs; Smits, Maarten L. J.; Nijsen, Johannes F. W.; Lam, Marnix G. E. H.; Zonnenberg, Bernard A.; Bosch, Maurice A. A. J. van den; Jong, Hugo W. A. M. de; Viergever, Max A.

    2013-11-15

    Purpose: Quantitative imaging of the radionuclide distribution is of increasing interest for microsphere radioembolization (RE) of liver malignancies, to aid treatment planning and dosimetry. For this purpose, holmium-166 ({sup 166}Ho) microspheres have been developed, which can be visualized with a gamma camera. The objective of this work is to develop and evaluate a new reconstruction method for quantitative {sup 166}Ho SPECT, including Monte Carlo-based modeling of photon contributions from the full energy spectrum.Methods: A fast Monte Carlo (MC) simulator was developed for simulation of {sup 166}Ho projection images and incorporated in a statistical reconstruction algorithm (SPECT-fMC). Photon scatter and attenuation for all photons sampled from the full {sup 166}Ho energy spectrum were modeled during reconstruction by Monte Carlo simulations. The energy- and distance-dependent collimator-detector response was modeled using precalculated convolution kernels. Phantom experiments were performed to quantitatively evaluate image contrast, image noise, count errors, and activity recovery coefficients (ARCs) of SPECT-fMC in comparison with those of an energy window-based method for correction of down-scattered high-energy photons (SPECT-DSW) and a previously presented hybrid method that combines MC simulation of photopeak scatter with energy window-based estimation of down-scattered high-energy contributions (SPECT-ppMC+DSW). Additionally, the impact of SPECT-fMC on whole-body recovered activities (A{sup est}) and estimated radiation absorbed doses was evaluated using clinical SPECT data of six {sup 166}Ho RE patients.Results: At the same noise level, SPECT-fMC images showed substantially higher contrast than SPECT-DSW and SPECT-ppMC+DSW in spheres ≥17 mm in diameter. The count error was reduced from 29% (SPECT-DSW) and 25% (SPECT-ppMC+DSW) to 12% (SPECT-fMC). ARCs in five spherical volumes of 1.96–106.21 ml were improved from 32%–63% (SPECT-DSW) and 50%–80

  8. Praseodymium incorporated AIPO-5 molecular sieves for aerobic oxidation of ethylbenzene.

    PubMed

    Sundaravel, B; Babu, C M; Palanisamy, B; Palanichamy, M; Shanthi, K; Murugesan, V

    2013-04-01

    PrAlPO-5 with (Al + P)/Pr ratios of 25, 50, 75 and 100 molecular sieves were successfully synthesized by hydrothermal method. These molecular sieves were characterised using XPS, TPD-NH3, ex-situ pyridine adsorbed IR, TPR, TGA, 27Al and 31P MAS-NMR and ESR studies. The incorporation of praseodymium in the framework of AlPO-5 was confirmed by XRD, DRS UV-vis and 27Al and 31P MAS-NMR analysis. ESR spectrum showed the presence of adsorbed oxygen. The nature and strength of acid sites were identified by ex-situ pyridine adsorbed IR and TPD-NH3. The BET surface area was found to be in the range of 238-272 m2 g(-1). The catalytic activity of the molecular sieves was tested for the liquid phase aerobic oxidation of ethylbenzene. Acetophenone was found to be the major product with more than 90% ethylbenzene conversion. ICP-OES analysis revealed the presence of praseodymium intact in the framework of AlPO-5 up to five cycles.

  9. Controlling the physics and chemistry of binary and ternary praseodymium and cerium oxide systems.

    PubMed

    Niu, Gang; Zoellner, Marvin Hartwig; Schroeder, Thomas; Schaefer, Andreas; Jhang, Jin-Hao; Zielasek, Volkmar; Bäumer, Marcus; Wilkens, Henrik; Wollschläger, Joachim; Olbrich, Reinhard; Lammers, Christian; Reichling, Michael

    2015-10-14

    Rare earth praseodymium and cerium oxides have attracted intense research interest in the last few decades, due to their intriguing chemical and physical characteristics. An understanding of the correlation between structure and properties, in particular the surface chemistry, is urgently required for their application in microelectronics, catalysis, optics and other fields. Such an understanding is, however, hampered by the complexity of rare earth oxide materials and experimental methods for their characterisation. Here, we report recent progress in studying high-quality, single crystalline, praseodymium and cerium oxide films as well as ternary alloys grown on Si(111) substrates. Using these well-defined systems and based on a systematic multi-technique surface science approach, the corresponding physical and chemical properties, such as the surface structure, the surface morphology, the bulk-surface interaction and the oxygen storage/release capability, are explored in detail. We show that specifically the crystalline structure and the oxygen stoichiometry of the oxide thin films can be well controlled by the film preparation method. This work leads to a comprehensive understanding of the properties of rare earth oxides and highlights the applications of these versatile materials. Furthermore, methanol adsorption studies are performed on binary and ternary rare earth oxide thin films, demonstrating the feasibility of employing such systems for model catalytic studies. Specifically for ceria systems, we find considerable stability against normal environmental conditions so that they can be considered as a "materials bridge" between surface science models and real catalysts.

  10. Controlling the physics and chemistry of binary and ternary praseodymium and cerium oxide systems.

    PubMed

    Niu, Gang; Zoellner, Marvin Hartwig; Schroeder, Thomas; Schaefer, Andreas; Jhang, Jin-Hao; Zielasek, Volkmar; Bäumer, Marcus; Wilkens, Henrik; Wollschläger, Joachim; Olbrich, Reinhard; Lammers, Christian; Reichling, Michael

    2015-10-14

    Rare earth praseodymium and cerium oxides have attracted intense research interest in the last few decades, due to their intriguing chemical and physical characteristics. An understanding of the correlation between structure and properties, in particular the surface chemistry, is urgently required for their application in microelectronics, catalysis, optics and other fields. Such an understanding is, however, hampered by the complexity of rare earth oxide materials and experimental methods for their characterisation. Here, we report recent progress in studying high-quality, single crystalline, praseodymium and cerium oxide films as well as ternary alloys grown on Si(111) substrates. Using these well-defined systems and based on a systematic multi-technique surface science approach, the corresponding physical and chemical properties, such as the surface structure, the surface morphology, the bulk-surface interaction and the oxygen storage/release capability, are explored in detail. We show that specifically the crystalline structure and the oxygen stoichiometry of the oxide thin films can be well controlled by the film preparation method. This work leads to a comprehensive understanding of the properties of rare earth oxides and highlights the applications of these versatile materials. Furthermore, methanol adsorption studies are performed on binary and ternary rare earth oxide thin films, demonstrating the feasibility of employing such systems for model catalytic studies. Specifically for ceria systems, we find considerable stability against normal environmental conditions so that they can be considered as a "materials bridge" between surface science models and real catalysts. PMID:26355535

  11. Influence of water environment on holmium laser ablation performance for hard tissues.

    PubMed

    Lü, Tao; Xiao, Qing; Li, Zhengjia

    2012-05-01

    This study clarifies the ablation differences in air and in water for hard biological tissues, which are irradiated by fiber-guided long-pulsed holmium lasers. High-speed photography is used to record the dynamic characteristics of ablation plumes and vaporization bubbles induced by pulsed holmium lasers. The ablation morphologies and depth of hard tissues are quantitatively measured by optical coherence microscopy. Explosive vaporization effects in water play a positive role in the contact ablation process and are directly responsible for significant ablation enhancement. Furthermore, water layer depth can also contribute to ablation performance. Under the same laser parameters for fiber-tissue contact ablation in air and water, ablation performances are comparable for a single-laser pulse, but for more laser pulses the ablation performances in water are better than those in air. Comprehensive knowledge of ablation differences under various environments is important, especially in medical procedures that are performed in a liquid environment.

  12. Effect of temperature on the active properties of erbium-doped optical fibres

    NASA Astrophysics Data System (ADS)

    Kotov, L. V.; Ignat'ev, A. D.; Bubnov, M. M.; Likhachev, M. E.

    2016-03-01

    We have studied the effect of heating on the performance of erbium-doped fibre based devices and determined temperaturedependent absorption and emission cross sections of the erbium ion in silica glass. The results demonstrate that heating of fibres in claddingpumped high-power (~100 W) erbium-doped fibre lasers causes no significant decrease in their efficiency. In contrast, superluminescent sources operating in the long-wavelength region (1565 – 1610 nm) are extremely sensitive to temperature changes.

  13. Optical constants determination of samarium, holmium, and erbium in the 1.5-850 eV spectral range using a transmittance method

    SciTech Connect

    Kjornrattanawanich, Benjawan; Windt, David L.; Seely, John F.

    2010-11-01

    The optical constants {beta} and {delta} of the complex refractive index n{approx}=1-{delta}+i{beta} of Sm, Ho, and Er were obtained in the 1.5-850eV energy range using a transmittance method. Thin films of Sm, Ho, and Er were deposited by magnetron sputtering, and transmittance was measured using synchrotron radiation under a high vacuum condition. All films were directly coated on Si photodiodes, which were used as coating substrates, as well as photon detectors. Si was used as capping layer while a thin W layer was used as barrier against interface diffusion between Si and the highly reactive rare earth elements. The constants {beta} were extracted from transmittance results, and the constants {delta} were calculated based on measured {beta} values using the Kramers-Kronig formalism. Small deficiencies determined from the present data using the partial sum rules were partly attributed to the sputtered film densities that could be slightly lower than the bulk values.

  14. Optical Constants Determination of Samarium Holmium and Erbium in the 1.5-850 eV Spectral Range using a Transmittance Method

    SciTech Connect

    B Kjornrattanawanich; D Windt; J Seely

    2011-12-31

    The optical constants {beta} and {sigma} of the complex refractive index {tilde n} = 1 - {delta} + i{beta} of Sm, Ho, and Er were obtained in the 1.5-850 eV energy range using a transmittance method. Thin films of Sm, Ho, and Dr were deposited by magnetron sputtering, and transmittance was measured using synchrotron radiation using a high vacuum condition. All films were directly coated on Si photodiodes, which were used as coating substrates, as well as photon detectors. Si was used as capping layer while a thin W layer was used as barrier against interface diffusion between Si and the highly reactive rare earth elements. The constants {beta} were extracted from transmittance results, and the constants {sigma} were calculated based on measured {beta} values using the Kramers-Kronig formalism. Small deficiencies determined from the present data using the partial sum rules were partially attributed to the sputtered film densities that could be slightly lower than the bulk values.

  15. Holmium:YAG laser-assisted otolaryngologic surgery: Lahey Clinic experience

    NASA Astrophysics Data System (ADS)

    Shapshay, Stanley M.; Rebeiz, Elie E.; Pankratov, Michail M.

    1993-07-01

    The Holmium:YAG laser was used to assist in 36 rhinologic procedures including surgery for chronic sinus disease, chronic dacryocystitis, recurrent choanal stenosis, and a sphenoid sinus mucocele. There were no laser related complications. The laser permitted controlled ablation of bone and soft tissue in all cases with satisfactory results. The Ho:YAG laser can be used in otolaryngology to assist in cases where surgical access is difficult or when controlled, precise bone and soft tissue ablation is necessary.

  16. Laser Prostatectomy: Holmium Laser Enucleation and Photoselective Laser Vaporization of the Prostate

    PubMed Central

    Bostanci, Yakup; Kazzazi, Amir; Djavan, Bob

    2013-01-01

    Historically, transurethral resection of the prostate has been the gold standard for the treatment of benign prostatic hyperplasia (BPH). Laser technology has been used to treat BPH for > 15 years. Over the past decade, it has gained wide acceptance by experienced urologists. This review provides an evidence-based update on laser surgery for BPH with a focus on photoselective laser vaporization and holmium laser enucleation of the prostate surgeries and assesses the safety, efficacy, and durability of these techniques. PMID:23671400

  17. Mathematical modelling of dispersion-managed thulium/holmium fibre lasers

    SciTech Connect

    Yarutkina, I A; Shtyrina, O V

    2013-11-30

    The mathematical model of a dispersion-managed thulium/holmium fibre laser is described; the results of numerical calculations and their comparison with the experimental data are presented. Qualitative agreement of the results of the mathematical modelling with those of the experiment is obtained. Using the methods of mathematical modelling, the variation in the characteristics of the optical pulses due to the change in the average cavity dispersion is analysed. (control of laser radiation parameters)

  18. Long-term toxicity of holmium-loaded poly(L-lactic acid) microspheres in rats.

    PubMed

    Zielhuis, Sander W; Nijsen, J Frank W; Seppenwoolde, Jan-Henry; Bakker, Chris J G; Krijger, Gerard C; Dullens, Hub F J; Zonnenberg, Bernard A; van Rijk, Peter P; Hennink, Wim E; van het Schip, Alfred D

    2007-11-01

    The aim of this study was to get insight into the toxic effects of holmium-166-loaded poly(L-lactic acid) microspheres (Ho-PLLA-MS) which have very interesting features for treatment of liver malignancies. Acute, mid- and long-term effects were studied in healthy Wistar rats by evaluating clinical, biochemical and tissue response. Rats were divided into four treatment groups: sham, decayed neutron-irradiated Ho-PLLA-MS, non-irradiated Ho-PLLA-MS and PLLA-MS. After implantation of the microspheres into the liver of the rats, the animals were monitored (body weight, temperature and liver enzymes) for a period of 14-18 months. Some of the rats that received previously neutron-irradiated Ho-PLLA-MS were periodically scanned with magnetic resonance imaging (MRI) to see if holmium was released from the microspheres. After sacrifice, the liver tissue was histologically evaluated. Bone tissue was subjected to neutron-activation analysis in order to examine whether accumulation of released holmium in the bone had occurred. No measurable clinical and biochemical toxic effects were observed in any of the treatment groups. Furthermore, histological analyses of liver tissue samples only showed signs of a slight chronic inflammation and no significant differences in the tissue reaction between rats of the different treatment groups could be observed. The non-irradiated PLLA-MS and Ho-PLLA-MS stayed intact during the study. In contrast, 14 months after administration, the neutron-irradiated Ho-PLLA-MS was not completely spherical anymore, indicating that degradation had started. However, the holmium loading had not been released as was illustrated with MRI and affirmed by neutron-activation analysis of bone tissue. In conclusion, neutron-irradiated Ho-PLLA-MS does not provoke any toxic reaction and can be applied safely in vivo.

  19. Efficient holmium:yttrium lithium fluoride laser longitudinally pumped by a semiconductor laser array

    NASA Technical Reports Server (NTRS)

    Hemmati, H.

    1987-01-01

    Optical pumping of a holmium:yttrium lithium floride (Ho:YLF) crystal with a 790-nm continuous-wave diode-laser array has generated 56 mW of 2.1-micron laser radiation with an optical-to-optical conversion slope efficiency of 33 percent while the crystal temperature is held at 77 K. The lasing threshold occurs at 7 mW of input power, and laser operation continues up to a crystal temperature of 124 K.

  20. Preparation of neutron-activatable holmium nanoparticles for the treatment of ovarian cancer metastases.

    PubMed

    Di Pasqua, Anthony J; Huckle, James E; Kim, Jin-Ki; Chung, Younjee; Wang, Andrew Z; Jay, Michael; Lu, Xiuling

    2012-04-10

    Nanoparticles containing stable holmium ((165) Ho) are prepared by nanotemplate engineering and subsequently irradiated in a neutron flux to yield (166) Ho, a beta-emitting radiotherapeutic isotope. After intraperitoneal injection to mice bearing SKOV-3 ovarian tumors, significant tumor accumulation of the (166) Ho-nanoparticles is observed by SPECT imaging indicating the potential of these neutron activatable nanoparticles for internal radiation therapy of ovarian cancer metastases.

  1. Photophysical properties of praseodymium complexes with aromatic carboxylic acids: double light conversion both in ultraviolet and visible region.

    PubMed

    Yan, Bing; Wang, Weijing; Song, Yishan

    2007-04-01

    A series of luminescent praseodymium complexes with different aromatic carboxylic acids have been synthesized and characterized. The photophysical properties of these complexes have been studied with ultraviolet spectra, phosphorescence spectra and fluorescence spectra. Ultraviolet absorption spectra show that the praseodymium complexes systems with aromatic carboxylate form the more extensive conjugated systems to be suitable for the distribution of electron in the whole coordination environment, resulting in the energy decrease and red-shifts of ultraviolet spectral bands. Phosphorescence spectra suggest that excited triplet state of aromatic carboxylic acids, which can indicate the energy match and intermolecular energy transfer process between the excited triplet state of ligands and the resonant emissive energy level of Pr ions. The emission spectra of all praseodymium complexes show two emission peaks under the excitation band of 245 nm at about 395 and 595 nm, respectively, while one peak at about 595 nm under 415 nm excitation, which attributed to be 1S0-->1I6 (395 nm) transition and the characteristic emission 1D2-->3H4 (595 nm) transition of Pr3+ ion. The 1S0-->1I6 transition can be speculated to belong to the transition of charge transfer state, and the 1D2-->3H4 can be further proved that there exists an antenna effect in the luminescence of praseodymium with aromatic carboxylic acids. In conclusion, the praseodymium complexes systems can realize the double proton light conversion both in the ultraviolet and visible region, which can be further studied to have potential application.

  2. Effects of the holmium laser on the human cornea: a preliminary study

    NASA Astrophysics Data System (ADS)

    Mueller, Linda J.; Tassignon, Marie J.; Trau, Rene; Pels, Liesbeth; Vrensen, Gijs F.

    1996-12-01

    Treatment of peripheral post-mortem human corneas with the Holmium laser in a ring pattern resulted in opaque spots. One pair of treated eyes was immediately processed for light and electron microscopy and three other treated eyes were preserved for 4 days in medium in order to compare direct and short-term effects of the Holmium laser. Cross as well as frontal light microscopical sections of all eyes revealed interconnecting bands between the spots. At the ultrastructural level the anterior corneal tissue within these spots was characterized by coagulation of cells and collagen and shoed either a dramatic distorting effect on the epithelium in the eyes processed immediately or a single layer of flattened multi-nucleolated epithelial cells having more than one nucleolus per nucleus in the eyes stored in medium. Furthermore, the spots showed disturbed Bowman's layer, destroyed keratocytes and collagen fibrils which were either coagulated or organized chaotically. The interconnecting bands contained alternating normal and coagulated collagen fibers. The rest of the cornea outside the spots had a normal appearance. In corneas stored in medium, both keratocytes and epithelial cells over the entire cornea exhibited accumulations of cytoplasmic fibrils and glycogen particles. These phenomena were not observed in non-preserved corneas, suggesting that the differences are due to preservation and not due to the laser treatment. It is concluded that morphological changes occur mainly in the treated peripheral cornea whereas the central untreated cornea remains unaffected,indicating that the Holmium laser is a reliable instrument to treat hypermetropic patients.

  3. Soft-tissue applications of the holmium:YAG laser in urology

    NASA Astrophysics Data System (ADS)

    Denstedt, John D.; Razvi, Hassan A.; Chun, Samuel S.; Sales, Jack L.

    1995-05-01

    The ideal surgical laser for the treatment of soft tissue pathology should possess both ablative and hemostatic abilities. As well, for use in urologic conditions the laser must also be suitable for endoscopic use. The Holmium:YAG laser possesses these qualities and in preliminary clinical use has demonstrated a variety of potential urologic applications. In this study we review our initial experience with the Holmium:YAG laser over a 18 month period. A total of 51 patients underwent 53 procedures for a variety of soft tissue conditions including: bladder tumor ablation (25), incision of ureteral stricture (15), incision of urethral stricture (6), treatment of ureteropelvic junction obstruction (3), incision of bladder neck contracture (2), and ablation of a ureteral tumor (2). Satisfactory hemostasis was achieved in all cases. Procedures were considered successful (no further intervention being required to treat the condition) in 81% of the cases. Two patients with dense bladder neck contractures required electroincision under the same anesthetic for completion of the procedure. A single complication, that of urinary extravasation following incision of a urethral stricture resolved with conservative management. In summary, the Holmium:YAG laser has demonstrated safety and proficiency in the treatment of a variety of urologic soft tissue conditions.

  4. Adaptive dynamic FBG interrogation utilising erbium-doped fibre

    NASA Astrophysics Data System (ADS)

    John, R. N.; Read, I.; MacPherson, W. N.

    2013-04-01

    A dynamic fibre Bragg grating interrogation scheme is investigated using two-wave mixing in erbium-doped fibre, capable of adapting to quasistatic strain and temperature drifts. An interference pattern set up in the erbium-doped fibre creates, due to the photorefractive effect, a dynamic grating capable of wavelength demodulating the FBG signal. The presence of a dynamic grating was verified and then dynamic strain signals from a fibre stretcher were measured. The adaptive nature of the technique was successfully demonstrated by heating the FBG while it underwent dynamic straining leading to detection unlike an alternative arrayed waveguide grating system which simultaneously failed detection. Two gratings were then wavelength division multiplexed with the signal grating receiving approximately 30dB greater signal showing that there was little cross talk in the system.

  5. Low erosion behavior of polystyrene films under erbium ion implantation

    SciTech Connect

    Bhattacharya, M.; Sanyal, M.K.; Chini, T.K.; Chakraborty, P.

    2006-02-13

    Erbium ion implantation in polystyrene (PS) thin films has been performed with 40 and 60 keV ions to a dose range between 1x10{sup 14} and 1x10{sup 16} ions/cm{sup 2}. The x-ray reflectivity technique was applied to determine the ion-induced eroded layer thickness and interestingly, the erosion rate is found to decrease with increasing ion doses exhibiting simple power law behavior of the form {approx}(dose){sup -b}. We propose the formation of a carbonaceous network at the top surface, which seems to prevent further erosion of the polymer with increasing the duration of implantation time. These findings may open up a possibility of loading a large amount of erbium in a polymer matrix by the implantation technique to make it suitable for various optoelectronic applications.

  6. Urbach absorption edge in epitaxial erbium-doped silicon

    SciTech Connect

    Shmagin, V. B. Kudryavtsev, K. E.; Shengurov, D. V.; Krasilnik, Z. F.

    2015-02-07

    We investigate the dependencies of the photocurrent in Si:Er p-n junctions on the energy of the incident photons. The exponential absorption edge (Urbach edge) just below fundamental edge of silicon was observed in the absorption spectra of epitaxial Si:Er layers grown at 400–600 C. It is shown that the introduction of erbium significantly enhances the structural disorder in the silicon crystal which was estimated from the slope of the Urbach edge. We discuss the possible nature of the structural disorder in Si:Er and a new mechanism of erbium excitation, which does not require the presence of deep levels in the band gap of silicon.

  7. Selective determination of the holmium in rare earth mixtures by second derivative spectrophotometry with 2-isobutylformyl-1,3-dione-indan and octylphenol poly-(ethyleneglycol)ether

    SciTech Connect

    Wang Naixing; Si Zhikun; Jiang Wei

    1996-09-01

    In this paper the absorption spectra of 4f electron transitions of the system of holmium with 2-isobutylformyl-1,3-dione-indan and TX-100 have been studied by normal and derivative spectrophotometry. The molar absorptivities are 98 (at 450 nm) and 21 (at 460 nm) 1 {center_dot} mol{sup -1} {center_dot} cm{sup -1}, respectively. The use of the second derivative spectra, eliminates the interference by other lanthanides and improves the sensitivity for holmium determination. The derivative molar absorptivity is 558 1 {center_dot} mol{sup -1} {center_dot} cm{sup -1}. The calibration graph was linear up to 25{mu}g/ml of holmium. The relative standard deviation evaluated from ten independent determinations of 8.0 {mu}g/ml holmium is 1.0%. The detection limit, obtained from the sensitivity of the calibration graph and for 3 S{sub b} (S{sub b} = standard deviation of a blank without holmium, n = 11), was found to be 0.31 {mu}g/ml of holmium. The quantification limit, obtained for 10 S{sub b}, was 1.0 {mu}g/ml of holmium. A method has been developed for determining holmium in a mixture of lanthanides by means of the second derivative spectra and the analytical results obtained are satisfactory.

  8. Laser isotope separation of erbium and other isotopes

    DOEpatents

    Haynam, C.A.; Worden, E.F.

    1995-08-22

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of {sup 167}Er. The hyperfine structure of {sup 167}Er was used to find two three-step photoionization pathways having a common upper energy level. 3 figs.

  9. Laser isotope separation of erbium and other isotopes

    DOEpatents

    Haynam, Christopher A.; Worden, Earl F.

    1995-01-01

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of .sup.167 Er. The hyperfine structure of .sup.167 Er was used to find two three-step photoionization pathways having a common upper energy level.

  10. Spectroscopic characterisation of the erbium impurity in crystalline semiconductors

    NASA Astrophysics Data System (ADS)

    Ammerlaan, C. A. J.

    2001-12-01

    A scheme for the numerical calculation of energy levels of rare-earth ions in a crystalline solid is presented. Stark fields of cubic, trigonal, tetragonal, orthorhombic and monoclinic symmetry are considered. As examples, optical luminescence spectra of erbium in the semiconductors zinc selenide and silicon are analysed. Based on the optical characterisation, the g tensors for Zeeman splitting in an applied magnetic field are predicted for the crystal-field ground states of these centres.

  11. Method for measuring deuterium in erbium deuteride films

    SciTech Connect

    Brangan, J.R.; Thornberg, S.M.; Keenan, M.R.

    1997-09-01

    Determining the quantity of deuterium in an erbium deuteride (ErD{sub 2}) film is essential for assessing the quality of the hydriding process but is a challenging measurement to make. First, the ideal gas law cannot be applied directly due to high temperature (950{degrees}C) and low temperature (25{degrees}C) regions in the same manifold. Additionally, the metal hydride does not release all of the deuterium rapidly upon heating and metal evaporation occurs during extended heating periods. Therefore, the method developed must provide a means to compensate for temperature inhomogeneities and the amount of deuterium retained in the metal film while heating for a minimal duration. This paper presents two thermal desorption methods used to evaluate the kinetics and equilibria of the deuterium desorption process at high temperatures (950{degrees}C). Of primary concern is the evaluation of the quantity of deuterium remaining in these films at the high temperature. A multiple volume expansion technique provided insight into the kinetics of the deuterium evolution and metal evaporation from the film. Finally a repeated pump-down approach yielded data that indicated approximately 10% of the deuterium is retained in the metal film at 950{degrees}C and approximately 1 Torr pressure. When the total moles of deuterium determined by this method were divided by the moles of erbium determined by ICP/AES, nearly stochiometric values of 2:1 were obtained for several erbium dideuteride films. Although this work presents data for erbium and deuterium, these methods are applicable to other metal hydrides as well.

  12. Method for measuring deuterium in erbium deuteride films

    SciTech Connect

    Brangan, J.R.; Thornberg, S.M.; Keenan, M.R.

    1999-07-01

    Determining the quantity of deuterium in an erbium deuteride film is essential for assessing the quality of the hydriding process but is a challenging measurement to make. First, the ideal gas law cannot be applied directly due to high temperature (950&hthinsp;{degree}C) and low temperature (25&hthinsp;{degree}C) regions in the same manifold. Additionally, the metal hydride does not release all of the deuterium rapidly upon heating and metal evaporation occurs during extended heating periods. Therefore, the method developed must provide a means to compensate for temperature inhomogeneities and the amount of deuterium retained in the metal film while heating for a minimal duration. This article presents two thermal desorption methods used to evaluate the kinetics and equilibria of the deuterium desorption process at high temperatures (950&hthinsp;{degree}C). Of primary concern is the evaluation of the quantity of deuterium remaining in these films at the high temperature. A multiple volume expansion technique provided insight into the kinetics of the deuterium evolution and metal evaporation from the film. Finally, a repeated pump-down approach yielded data that indicated approximately 10{percent} of the deuterium is retained in the metal film at 950&hthinsp;{degree}C and approximately 1 Torr pressure. When the total moles of deuterium determined by this method were divided by the moles of erbium determined by inductively coupled argon plasma atomic emission spectroscopy, nearly stochiometric values of 2:1 were obtained for several erbium dideuteride films. Although this work presents data for erbium and deuterium, these methods are applicable to other metal hydrides as well. {copyright} {ital 1999 American Vacuum Society.}

  13. Ureteroscopy and holmium:YAG laser lithotripsy: an emerging definitive management strategy for symptomatic ureteral calculi in pregnancy

    NASA Astrophysics Data System (ADS)

    Watterson, James D.; Girvan, Andrew R.; Beiko, Darren T.; Nott, Linda; Wollin, Timothy A.; Razvi, Hassan A.; Denstedt, John D.

    2003-06-01

    Objectives: Symptomatic urolithiasis in pregnancy that does not respond to conservative measures has traditionally been managed with ureteral stent insertion or percutaneous nephrostomy (PCN). Holmium:yttrium-aluminum-garnet (YAG) laser lithotripsy using state-of-the-art ureteroscopes represents an emerging strategy for definitive stone management in pregnancy. The purpose of this study was to review the results of holmium laser lithotripsy in a cohort of patients who presented with symptomatic urolithiasis in pregnancy. Methods: A retrospective analysis was conducted at 2 tertiary stone centers from January 1996 to August 2001 to identify pregnant patients who were treated with ureteroscopic holmium laser lithotripsy for symptomatic urolithiasis or encrusted stents. Eight patients with a total of 10 symptomatic ureteral calculi and 2 encrusted ureteral stents were treated. Mean gestational age at presentation was 22 weeks. Mean stone size was 8.1 mm. Stones were located in the proximal ureter/ureteropelvic junction (UPJ) (3), mid ureter (1), and distal ureter (6). Results: Complete stone fragmentation and/or removal of encrusted ureteral stents were achieved in all patients using the holmium:YAG laser. The overall procedural success rate was 91%. The overall stone-free rate was 89%. No obstetrical or urological complications were encountered. Conclusions: Ureteroscopy and holmium laser lithotripsy can be performed safely in all stages of pregnancy providing definitive management of symptomatic ureteral calculi. The procedure can be done with minimal or no fluoroscopy and avoids the undesirable features of stents or nephrostomy tubes.

  14. Pressure-dependent resistivity and magnetoresistivity of erbium

    NASA Astrophysics Data System (ADS)

    Ellerby, Mark; McEwen, Keith A.; Bauer, Ernst; Hauser, Robert; Jensen, Jens

    2000-03-01

    A comprehensive resistance study of erbium subjected to a hydrostatic pressure is presented. From the experimental results we derive a p-T phase diagram for the magnetic phases in erbium. In the zero-temperature limit, the conical structure is predicted to transform into the cycloidal one at a pressure of about 1.3 kbar. Experimentally, the transition is found to occur between 1 and 3 kbar at 4.5 K. The experimental results are analyzed in terms of a variational calculation of the resistivity using the model developed for erbium from previous experiments. The theory of Elliott and Wedgwood is utilized in the account of the superzone effects. The analysis indicates that the a-axis resistivity is slightly affected by the superzones. In the c-axis case the superzone effects do not simply scale with the magnetization, but also reflect the 20% change of the ordering wave vector. This occurs between TN and TC at ambient pressure, and at 4.5 K when the pressure is increased from 1 to 3 kbar. It is tentatively proposed that the tilted cycloidal structure exists in Er, just above TC at ambient pressure and in the interval between 1.3 and 9 kbar at zero temperature.

  15. High-performace cladding-pumped erbium-doped fibre laser and amplifier

    SciTech Connect

    Kotov, L V; Likhachev, M E; Bubnov, M M; Medvedkov, O I; Lipatov, D S; Vechkanov, N N; Guryanov, Aleksei N

    2012-05-31

    We report cladding-pumped erbium-doped fibre laser and amplifier configurations. Through fibre design optimisation, we have achieved a record-high laser slope efficiency, 40 % with respect to absorbed pump power ({lambda} = 976 nm), and an output power of 7.5 W. The erbium-doped fibre amplifier efficiency reaches 32 %.

  16. DRIFTS study of CO adsorption on praseodymium modified Pt/Al2O3

    NASA Astrophysics Data System (ADS)

    Tankov, I.; Cassinelli, W. H.; Bueno, J. M. C.; Arishtirova, K.; Damyanova, S.

    2012-10-01

    The effect of PrO2 content (1-20 wt.%) and temperature pretreatment on the structure and surface properties of PrO2-Al2O3-supported Pt catalysts was studied by XRD, XPS and DRIFTS of carbon monoxide adsorption. XRD analysis showed that platinum particle size decreases with the increase of PrO2 content for samples calcined at high temperature of 1023 K. The intensity and position of the infrared bands were strongly dependent on the praseodymium oxide content and reduction temperature. Two kinds of Pt sites (Pt0 and Ptδ+) were recorded in reduced PrO2-containing samples. A better thermal stability of the Ptsbnd CO bond in PrO2-containing samples compared to Pt/Al2O3 was observed.

  17. Superbroadband near-IR emission from praseodymium-doped bismuth gallate glasses.

    PubMed

    Zhou, Bo; Pun, Edwin Yue-Bun

    2011-08-01

    Superbroadband near-infrared (NIR) emission covering 1250 to 1680 nm wavelength has been obtained in praseodymium (Pr(3+)) singly doped bismuth gallate glasses. The emission originates from the (1)G(4)→(3)H(5) and (1)D(2)→(1)G(4) transitions at 1330 and 1490 nm wavelengths, respectively, and is due to the extremely low phonon energy (∼690 cm(-1)) and the unique ligand field of the glasses. It is shown that the emission line shape can be modified by adjusting the Pr(3+) concentration and the energy transfers involved. The results confirm that other than bismuth (Bi), chromium (Cr), nickel (Ni), and other chemical elements, Pr(3+) singly doped system is a promising alternative in achieving superbroadband NIR emission.

  18. Amphoteric Doping of Praseodymium Pr3+ in SrTiO3 Grain Boundaries

    SciTech Connect

    Yang, Hao; Lee, H. S.; Kotula, Paul G.; Sato, Yukio; Ikuhara, Yuichi; Browning, Nigel D.

    2015-03-23

    Charge Compensation in rare-earth Praseodymium (Pr3+) doped SrTiO3 plays an important role in determining the overall photoluminescence properties of the system. Here, the Pr3+ doping behavior in SrTiO3 grain boundaries (GBs) is analyzed using aberration corrected scanning transmission electron microscopy (STEM). The presence of Pr3+ induces structure variations and changes the statistical prevalence of GB structures. In contrast to the assumption that Pr3+ substitutes for A site as expected in the bulk, Pr3+ is found to substitute both Sr and Ti sites inside GBs with the highest concentration in the Ti sites. This amphoteric doping behavior in the boundary plane is further confirmed by first principles theoretical calculations.

  19. Amphoteric doping of praseodymium Pr3+ in SrTiO3 grain boundaries

    DOE PAGES

    Yang, H.; Lee, H. S.; Kotula, P. G.; Sato, Y.; Ikuhara, Y.; Browning, N. D.

    2015-03-26

    Charge Compensation in rare-earth Praseodymium (Pr3+) doped SrTiO3 plays an important role in determining the overall photoluminescence properties of the system. Here, the Pr3+ doping behavior in SrTiO3 grain boundaries (GBs) is analyzed using aberration corrected scanning transmission electron microscopy (STEM). The presence of Pr3+ induces structure variations and changes the statistical prevalence of GB structures. In contrast to the assumption that Pr3+ substitutes for A site as expected in the bulk, Pr3+ is found to substitute both Sr and Ti sites inside GBs with the highest concentration in the Ti sites. As a result, this amphoteric doping behavior inmore » the boundary plane is further confirmed by first principles theoretical calculations.« less

  20. Spectroscopic detection and state preparation of a single praseodymium ion in a crystal.

    PubMed

    Utikal, T; Eichhammer, E; Petersen, L; Renn, A; Götzinger, S; Sandoghdar, V

    2014-04-11

    The narrow optical transitions and long spin coherence times of rare earth ions in crystals make them desirable for a number of applications ranging from solid-state spectroscopy and laser physics to quantum information processing. However, investigations of these features have not been possible at the single-ion level. Here we show that the combination of cryogenic high-resolution laser spectroscopy with optical microscopy allows one to spectrally select individual praseodymium ions in yttrium orthosilicate. Furthermore, this spectral selectivity makes it possible to resolve neighbouring ions with a spatial precision of the order of 10 nm. In addition to elaborating on the essential experimental steps for achieving this long-sought goal, we demonstrate state preparation and read out of the three ground-state hyperfine levels, which are known to have lifetimes of the order of hundred seconds.

  1. The matlockite-type praseodymium(III) oxide bromide PrOBr.

    PubMed

    Talmon-Gros, Pia; Schurz, Christian M; Schleid, Thomas

    2011-12-01

    The crystal structure of the praseodymium(III) oxide bromide, PrOBr, can be best described with layers of agglomerated square anti-prisms [PrO(4)Br(4)](9-). These slabs are stacked along the c axis and linked via two different secondary contacts between Pr(3+) and Br(-). The Pr(3+) cations occupy the Wyckoff site 2c with 4mm symmetry and carry four O(2-) anions as well as four primary Br(-) anions, yielding a coordination number of 8. While the Br(-) anions exhibit the same site symmetry as the Pr(3+) cations, the oxide anions are located at the Wyckoff position 2a with site symmetry [Formula: see text]m2 and have four Pr(3+) cations as neighbours, defining a tetra-hedron.

  2. Site selectivity in praseodymium- and bismuth-substituted gadolinium gallium garnet epilayers

    SciTech Connect

    Klages, C.P.

    1984-05-01

    Praseodymium- and bismuth-substituted gadolinium gallium garnet (GGG) layers have been prepared by liquid-phase epitaxy on (111)- and (110)-oriented GGG substrates. By an investigation of linear dichroism of Pr/sup 3 +/ -transitions, the supercooling dependence of dodecahedral site selectivity in Pr-substituted GGG can be shown to differ considerably for (110)- and (111)-epitaxial layers. An increase insite selectivity with supercooling is found in (111) layers while it is constant in (110) layers. The long-wavelength /sup 1/S /sub 0/ ..-->.. /sup 3/ P/sub 1/-transition of the B/sub 1/ /sup 3 +/ ion has been utilized to detect site selectivity in (110)oriented Bi-substituted GGG layers.

  3. Spectroscopic detection and state preparation of a single praseodymium ion in a crystal.

    PubMed

    Utikal, T; Eichhammer, E; Petersen, L; Renn, A; Götzinger, S; Sandoghdar, V

    2014-01-01

    The narrow optical transitions and long spin coherence times of rare earth ions in crystals make them desirable for a number of applications ranging from solid-state spectroscopy and laser physics to quantum information processing. However, investigations of these features have not been possible at the single-ion level. Here we show that the combination of cryogenic high-resolution laser spectroscopy with optical microscopy allows one to spectrally select individual praseodymium ions in yttrium orthosilicate. Furthermore, this spectral selectivity makes it possible to resolve neighbouring ions with a spatial precision of the order of 10 nm. In addition to elaborating on the essential experimental steps for achieving this long-sought goal, we demonstrate state preparation and read out of the three ground-state hyperfine levels, which are known to have lifetimes of the order of hundred seconds. PMID:24722142

  4. Spectroscopic detection and state preparation of a single praseodymium ion in a crystal

    NASA Astrophysics Data System (ADS)

    Utikal, T.; Eichhammer, E.; Petersen, L.; Renn, A.; Götzinger, S.; Sandoghdar, V.

    2014-04-01

    The narrow optical transitions and long spin coherence times of rare earth ions in crystals make them desirable for a number of applications ranging from solid-state spectroscopy and laser physics to quantum information processing. However, investigations of these features have not been possible at the single-ion level. Here we show that the combination of cryogenic high-resolution laser spectroscopy with optical microscopy allows one to spectrally select individual praseodymium ions in yttrium orthosilicate. Furthermore, this spectral selectivity makes it possible to resolve neighbouring ions with a spatial precision of the order of 10 nm. In addition to elaborating on the essential experimental steps for achieving this long-sought goal, we demonstrate state preparation and read out of the three ground-state hyperfine levels, which are known to have lifetimes of the order of hundred seconds.

  5. Performance analysis of a concatenated erbium-doped fiber amplifier supporting four mode groups

    NASA Astrophysics Data System (ADS)

    Qin, Zujun; Fan, Di; Zhang, Wentao; Xiong, Xianming

    2016-05-01

    An erbium-doped fiber amplifier (EDFA) supporting four mode groups has been theoretically designed by concatenating two sections of erbium-doped fibers (EDFs). Each EDF has a simple erbium doping profile for the purpose of reducing its fabrication complexity. We propose a modified genetic algorithm (GA) to provide detailed investigations on the concatenated amplifier. Both the optimal fiber length and erbium doping radius in each EDF have been found to minimize the gain difference between signal modes. Results show that the parameters of the central-doped EDF have a greater impact on the amplifier performance compared to those of the annular-doped one. We then investigate the influence of the small deviations of the erbium fiber length, doping radius and doping concentration of each EDF from their optimal values upon the amplifier performance, and discuss their design tolerances in obtaining a desirable amplification characteristics.

  6. Nonstented versus routine stented ureteroscopic holmium laser lithotripsy: a prospective randomized trial.

    PubMed

    Shao, Yi; Zhuo, Jian; Sun, Xiao-Wen; Wen, Wei; Liu, Hai-Tao; Xia, Shu-Jie

    2008-10-01

    We conducted a prospective, randomized study to evaluate whether postoperative ureteral stenting is necessary after ureteroscopic holmium laser lithotripsy. A total of 115 consecutive patients with distal or middle ureteral calculi amenable to ureteroscopic holmium laser lithotripsy were prospectively randomized into stented group (n = 58) and nonstented group (n = 57). The stent was routinely placed in the treated ureter for 2 weeks. The outcomes were measured with postoperative patient symptoms, stone-free rates, early and late postoperative complications, and cost-effectiveness. The postoperative symptoms were measured with Ureteral Stent Symptom Questionnaire (USSQ). All patients completed a 12-week follow-up. There was no significant difference between two groups with respect to the patient age, stone size, stone location and mean operative time. According to the USSQ, the symptoms of the stented group were significantly worse compared to the nonstented group (P = 0.0001). In the stented group, two patients had high fever for 1 week after the operation, stent migration was found in two patients, and the stents had to be removed earlier in five patients because of severe pain or hematuria. The cost of the stented group was significantly higher than the nonstented group. The stone-free rate was 100% in both groups. No hydronephrosis or ureteral stricture was detected by intravenous pyelogram in the 12th week postoperative follow-up. In conclusion, we believe that routine stenting after ureteroscopic intracorporeal lithotripsy with the holmium laser is not necessary as long as the procedure is uncomplicated for distal or middle ureteral calculis less than 2 cm.

  7. Percutaneous Endoscopic Holmium Laser Lithotripsy for Management of Complicated Biliary Calculi

    PubMed Central

    Healy, Kelly; Chamsuddin, Abbas; Spivey, James; Martin, Louis; Nieh, Peter

    2009-01-01

    Background and Objectives: Advances in endoscopic techniques have transformed the management of urolithiasis. We sought to evaluate the role of such urological interventions for the treatment of complex biliary calculi. Methods: We conducted a retrospective review of all patients (n=9) undergoing percutaneous holmium laser lithotripsy for complicated biliary calculi over a 4-year period (12/2003 to 12/2007). All previously failed standard techniques include ERCP with sphincterotomy (n=6), PTHC (n=7), or both of these. Access to the biliary system was obtained via an existing percutaneous transhepatic catheter or T-tube tracts. Endoscopic holmium laser lithotripsy was performed via a flexible cystoscope or ureteroscope. Stone clearance was confirmed intra- and postoperatively. A percutaneous transhepatic drain was left indwelling for follow-up imaging. Results: Mean patient age was 65.6 years (range, 38 to 92). Total stone burden ranged from 1.7 cm to 5 cm. All 9 patients had stones located in the CBD, with 2 patients also having additional stones within the hepatic ducts. All 9 patients (100%) were visually stone-free after one endoscopic procedure. No major perioperative complications occurred. Mean length of stay was 2.4 days. At a mean radiological follow-up of 5.4 months (range, 0.5 to 21), no stone recurrence was noted. Conclusions: Percutaneous endoscopic holmium laser lithotripsy is a minimally invasive alternative to open salvage surgery for complex biliary calculi refractory to standard approaches. This treatment is both safe and efficacious. Success depends on a multidisciplinary approach. PMID:19660213

  8. Transurethral holmium-YAG laser lithotripsy for large symptomatic prostatic calculi: initial experience.

    PubMed

    Goyal, Neeraj Kumar; Goel, Apul; Sankhwar, Satyanarayan

    2013-08-01

    Symptomatic prostatic calculi are a rare clinical entity with wide range of management options, however, there is no agreement about the preferred method for treating these symptomatic calculi. In this study we describe our experience of transurethral management of symptomatic prostatic calculi using holmium-YAG laser lithotripsy. Patients with large, symptomatic prostatic stones managed by transurethral lithotripsy using holmium-YAG laser over 3-year duration were included in this retrospective study. Patients were evaluated for any underlying pathological condition and calculus load was determined by preoperative X-ray KUB film/CT scan. Urethrocystoscopy was performed using 30° cystoscope in lithotomy position under spinal anesthesia, followed by transurethral lithotripsy of prostatic calculi using a 550 μm laser fiber. Stone fragments were disintegrated using 100 W laser generators (VersaPulse PowerSuite 100 W, LUMENIS Surgical, CA). Larger stone fragments were retreived using Ellik's evacuator while smaller fragments got flushed under continuous irrigation. Five patients (median age 42 years) with large symptomatic prostatic calculi were operated using the described technique. Three patients had idiopathic stones while rest two had bulbar urethral stricture and neurogenic bladder, respectively. Median operative time was 62 min. All the patients were stone free at the end of procedure. Median duration of catheterization was 2 days. Significant improvement was observed in symptoms score and peak urinary flow and none of the patient had any complication. Transurethral management using holmium-YAG laser lithotripsy is a safe and highly effective, minimally invasive technique for managing symptomatic prostatic calculi of all sizes with no associated morbidity.

  9. Optimization of dosimetry and safety using the holmium laser for urology

    NASA Astrophysics Data System (ADS)

    van Swol, Christiaan F. P.; Verdaasdonck, Rudolf M.; Zeijlemaker, Bram Y. W.; Grimbergen, Matthijs C. M.; Boon, Tom A.

    1998-07-01

    The holmium laser has become accepted as a versatile instrument for urological applications, such as prostate resection, urethrotomy, tumor coagulation and lithotripsy. Presently, more powerful lasers have become available generating pulses up to 4 J at 80 W. The necessity of these high power systems in urology is ambiguous. In this study, the dosimetry as to efficacy and especially safety was investigated for various applications. The holmium laser ((lambda) equals 2.1 micrometer) emits its energy in 350 microsecond pulses which instantly turn water into vapor. Using high-speed photography explosive vapor bubbles with diameters over 10 mm were captured. The mechanical force of these bubbles, effectively fragments stones but may dilate and rupture a small lumen like the ureter. After implosion of the bubble, the energy of vaporization turns into heat. Depending on pulse energy and pulse repetition rate, tissue can be thermally affected up to 5 mm. For soft tissue applications, e.g., urethrotomy, prostatectomy or tumor coagulation, pulse energies of 0.5 - 1.5 J were applied at a high repetition rate (20 - 40 Hz) to provide sufficient coagulative and hemostatic effects. At higher pulse energies, the fiber tip was vibrating vigorously and the tissue was ripped to pieces decreasing hemostasis and visibility. For hard tissue applications, bursts of 0.5 J pulses at 5 Hz, proved to be sufficient to fragment all types of stones (including cystine) in the ureter and the bladder without mechanical or thermal damage to surrounding tissue. At higher settings, targeting the stone was less controlled and effective due to 'jumping' of the fiber tip with resulting mechanical and thermal trauma to the surrounding tissue. The holmium laser can be used effectively to coagulate and cut soft tissue and fragment stones at relatively low energy and power settings, thus minimizing the risk of complications.

  10. Syntheses, crystal structures, and gas storage studies in new three-dimensional 5-aminoisophthalate praseodymium polymeric complexes.

    PubMed

    Qiu, Yongcai; Deng, Hong; Yang, Shihe; Mou, Jixia; Daiguebonne, Carole; Kerbellec, Nicolas; Guillou, Olivier; Batten, Stuart R

    2009-05-01

    The hydrothermal reaction of 5-aminoisophthalic acid and praseodymium oxide in different acids results in two new praseodymium coordination polymers, {Pr(2)(aip)(3)(H(2)O)(2) x 3 H(2)O}(n) (1) and {Pr(2)(Haip)(2)(aip)(NO(3))(2) x 8 H(2)O}(n) (2) (aip = 5-aminoisophthalate). Complexes 1 and 2 are two distinct three-dimensional metal-organic frameworks constructed from the linkage of rod-shaped praseodymium carboxylate secondary building units and phenyl rings. Both dehydrated coordination frameworks are estimated using a computational method based on Connolly's algorithm, indicating that dehydrated compound 1 cannot host molecules other than water molecules or He, whereas dehydrated compound 2 is able to host molecules with kinetic radii as big as 2.3 A. The potential specific accessible surface of this compound is 792 m(2) g(-1). Meanwhile, N(2) sorption measurements reveal that dehydrated compound 2 having a high 230 cm(3)/g (287 mg/g) N(2) storage capacity at 77 K and 1 atm is in fairly good agreement with our calculation results. Moreover, powder X-ray diffraction measurement results demonstrated that the stable channels of dehydrated compound 2 can reversibly host other small solvent molecules (e.g., water, methanol, and ethanol) and grand canonical Monte Carlo simulation is applied to predict its hydrogen storage capacity.

  11. Holmium-lipiodol-alginate microspheres for fluoroscopy-guided embolotherapy and multimodality imaging.

    PubMed

    Oerlemans, Chris; Seevinck, Peter R; Smits, Maarten L; Hennink, Wim E; Bakker, Chris J G; van den Bosch, Maurice A A J; Nijsen, J Frank W

    2015-03-30

    Embolotherapy is a minimally invasive transcatheter technique aiming at reduction or complete obstruction of the blood flow by infusion of micro-sized particles in order to induce tumor regression. A major drawback of the current commercially available and clinically used microspheres is that they cannot be detected in vivo with medical imaging techniques, impeding intra- and post-procedural feedback. It can be expected that real-time monitoring of microsphere infusion and post-procedural imaging will result in better predictability and higher efficacy of the treatment. In this study, a novel microsphere formulation has been developed that can be visualized with fluoroscopy, X-ray computed tomography (CT) and magnetic resonance imaging (MRI). The microspheres were prepared with the JetCutter technique and consist of alginate (matrix-forming polymer), holmium (cross-linking and MRI contrast agent), lipiodol (radiopaque contrast agent) and Pluronic F-68 (surfactant). The mean size (±SEM) of the hydrated holmium-lipiodol-alginate microspheres (Ho-lip-ams) was 570±12 μm with a holmium content of 0.38±0.01% (w/w). Stability studies showed that the microspheres remained intact during incubation for two weeks in fetal calf serum (FCS) at 37 °C. The inclusion of lipiodol in the microspheres rendered excellent visualization capabilities for fluoroscopy and CT, whereas the holmium ions, which keep the alginate network together, also allow MR imaging. In this study it was shown that single sphere detection was possible by fluoroscopy, CT and MRI. The Ho-lip-ams were visualized in real-time, during infusion in a porcine kidney using fluoroscopy, and post-procedural, the deposition of the microspheres was examined with fluoroscopy, (cone beam rotational) CT and MRI. The different imaging modalities showed similar deposition patterns of the microspheres within the organ. The combination of intra-procedural visualization, multimodality imaging for patient follow-up and the

  12. Holmium Laser Enucleation of the Prostate and Iatrogenic Arteriovenous Fistula Treated by Superselective Arterial Embolization.

    PubMed

    Asimakopoulos, Anastasios D; Dutto, Lorenzo; Preziosi, Paolo; Spera, Enrico; Micali, Francesco; De Carolis, Andrea; Iorio, Beniamino

    2016-01-01

    Iatrogenic pelvic pseudoaneurysm with concomitant arteriovenous fistula has been described as a rare and challenging complication, which may occur during transurethral resection of the prostate. We provide the first report of this complication after holmium laser enucleation of the prostate for the treatment of benign prostatic hyperplasia. The attempt to control the bleeding by conversion to open surgery and placement of haemostatic stitches into the prostatic fossa failed. Angiography with superselective arterial embolization proved to be a modern, quick, safe, and efficient treatment of this uncommon complication. PMID:27022498

  13. Erbium-doped fiber amplifier elements for structural analysis sensors

    NASA Technical Reports Server (NTRS)

    Hanna-Hawver, P.; Kamdar, K. D.; Mehta, S.; Nagarajan, S.; Nasta, M. H.; Claus, R. O.

    1992-01-01

    The use of erbium-doped fiber amplifiers (EDFA's) in optical fiber sensor systems for structural analysis is described. EDFA's were developed for primary applications as periodic regenerator amplifiers in long-distance fiber-based communication systems. Their in-line amplification performance also makes them attractive for optical fiber sensor systems which require long effective lengths or the synthesis of special length-dependent signal processing functions. Sensor geometries incorporating EDFA's in recirculating and multiple loop sensors are discussed. Noise and polarization birefringence are also considered, and the experimental development of system components is discussed.

  14. Evaluation of holmium laser versus cold knife in optical internal urethrotomy for the management of short segment urethral stricture

    PubMed Central

    Jain, Sudhir Kumar; Kaza, Ram Chandra Murthy; Singh, Bipin Kumar

    2014-01-01

    Objectives: Sachse cold knife is conventionally used for optical internal urethrotomy intended to manage urethral strictures and Ho: YAG laser is an alternative to it. The aim of this study was to evaluate the role of urethral stricture treatment outcomes, efficacy, and complications using cold knife and Ho: YAG (Holmium laser) for optical internal urethrotomy Materials and Methods: In this prospective study included, 90 male patients age >18 years, with diagnosis of urethral stricture admitted for internal optical urethrotomy during April 2010 to March 2012. The patients were randomized into two groups containing 45 patients each using computer generated random number. In group A (Holmium group), internal urethrotomy was done with Holmium laser and in group B (Cold knife group) Sachse cold knife was used. Patients were followed up for 6 months after surgery in Out Patient Department on 15, 30 and 180 post-operative days. At each follow up visit physical examination, and uroflowmetry was performed along with noting complaints, if any. Results: The peak flow rates (PFR) were compared between the two groups on each follow up. At 180 days (6 month interval) the difference between mean of PFR for Holmium and Cold knife group was statistically highly significant (P < 0.001). Complications were seen in 12.22% of cases. Conclusion: Both modalities are effective in providing immediate relief to patients with single and short segment (<2 cm long) urethral strictures but more sustained response was attained with Cold knife urethrotomy. PMID:25371611

  15. Holmium:YAG laser: effects of various treatments on root surface topography and acid resistance

    NASA Astrophysics Data System (ADS)

    Holt, Raleigh A.; Nordquist, Robert E.

    1996-04-01

    The effects of Holmium:YAG laser energy with and without a topical fluoride mixture (resin to NaF) was compared with two types of topical fluorides on surface topography and resistance to acid destruction of root surfaces. Scanning electron microscopy (SEM) was used to evaluate the effects of the selected treatments on surface topography before acid exposure. Toluidine blue dye was used to test the permeability of root surfaces after acid exposures. SEM examinations of the dentinal root surfaces showed consistently smooth surfaces with tubule closures when using topical resin to fluoride and HO:YAG laser treatment; in contrast, HO:YAG laser energy treatment alone exhibited increased roughness of root surfaces. Topical fluoride applications alone presented surfaces similar to untreated control sites. Toluidine blue dye penetration into root surfaces of the fluoride/laser-treated root surfaces showed significantly less dye penetration after acid exposures than controls and other treatment protocols. The results of this study indicate that the resin-fluoride application and holmium:YAG irradiation effectively produced increased smoothness and increased resistance to destruction of root surfaces in human extracted teeth under these in vitro conditions.

  16. Treatment of Parapelvic Cyst by Internal Drainage Technology Using Ureteroscope and Holmium Laser

    PubMed Central

    Zhao, Q; Huang, S; Li, Q; Xu, L; Wei, X; Huang, S; Li, S; Liu, Z

    2015-01-01

    ABSTRACT Background: The aim of parapelvic cyst treatment is to have complete drainage of cyst fluid and prevent its further compression of the kidney and collective system. This study explores the efficacy and safety of surgical approaches with holmium laser ureteroscopic internal drainage in the treatment of parapelvic cyst. Methods: The compression effect of parapelvic cyst on the renal collective system was observed by rigid ureteroscope using retrograde ureteroscopic technology. With direct vision, the cyst wall on the obvious parapelvic compression site was cut. The diameter of the cyst wall cut was about 1 cm. The internal drainage was obtained by double-J tubes. When the cyst was in the inferior pole of kidney or where the rigid ureteroscope could not reach, a flexible ureteroscope was used. Results: In 28 cases of operation, 27 cases were successful. The cyst treatment time was eight to 40 minutes (average 26 minutes). During the operation, no massive haemorrhage, damage of nearby organ and ureter, or other complications happened. Time of follow-up was 10–72 months (average 39 months). The results of follow-up showed that in 22 cases, the cyst disappeared; the diameter of the cyst in four cases was reduced by more than half, and one case recurred. Conclusion: The treatment of parapelvic cyst by internal drainage operation using holmium laser and ureteroscopy was effective. The operation was safe with few complications. PMID:26426175

  17. Posterior Urethral Polyp: First Holmium-YAG Laser Ablation on a 3-Month-Old Infant

    PubMed Central

    Keskin, Ercument; Yapanoglu, Turgut; Adanur, Senol; Ziypak, Tevfik; Altay, Mehmet Sefa; Aksoy, Yılmaz

    2016-01-01

    Abstract Background: Urethral polyps are rare benign pathologies seen in the male posterior urethra, more frequently originating from verumontanum. In this article, we aimed to discuss diagnosis and treatment of a urethral polyp causing hematuria and urinary infection in a 3-month-old male infant. This is the first case in the literature in which a urethral polyp is treated with Holmium yttrium-aluminum-garnet (YAG) laser. Case Presentation: The patient was a 3-month-old male infant, and complains were hematuria and crying during micturition. Ultrasonography and voiding cystourethrogram were used for diagnosis. Urethral polyp was observed on urethrocystoscopy. Ablation was performed with a newborn cystoscope. Conclusion: Urethral polyp can cause hematuria and urinary obstruction and should be considered in the differential diagnosis of pathologies such as posterior urethral valve and cecoureterocele that could cause infravesical obstruction. Holmium-YAG laser is a good choice of treatment with easy application possibilities using a newborn cystoscope, especially for newborns and infants who have thin urethra. PMID:27579428

  18. Evaluating United States and world consumption of neodymium, dysprosium, terbium, and praseodymium in final products

    NASA Astrophysics Data System (ADS)

    Hart, Matthew

    This paper develops scenarios of future rare-earth-magnet metal (neodymium, dysprosium, terbium, and praseodymium) consumption in the permanent magnets used in wind turbines and hybrid electric vehicles. The scenarios start with naive base-case scenarios for growth in wind-turbine and hybrid-electric-vehicle sales over the period 2011 to 2020, using historical data for each good. These naive scenarios assume that future growth follows time trends in historical data and does not depend on any exogenous variable. Specifically, growth of each technological market follows historical time trends, and the amount of rare earths used per unit of technology remains fixed. The chosen reference year is 2010. Implied consumptions of the rare earth magnet metals are calculated from these scenarios. Assumptions are made for the material composition of permanent magnets, the market share of permanent-magnet wind turbines and vehicles, and magnet weight per unit of technology. Different scenarios estimate how changes in factors like the material composition of magnets, growth of the economy, and the price of a substitute could affect future consumption. Each scenario presents a different method for reducing rare earth consumption and could be interpreted as potential policy choices. In 2010, the consumption (metric tons, rare-earth-oxide equivalent) of each rare-earth-magnet metal was as follows. Total neodymium consumption in the world for both technologies was 995 tons; dysprosium consumption was 133 tons; terbium consumption was 50 tons; praseodymium consumption was zero tons. The base scenario for wind turbines shows there could be strong, exponential growth in the global wind turbine market. New U.S. sales of hybrid vehicles would decline (in line with the current economic recession) while non-U.S. sales increase through 2020. There would be an overall increase in the total amount of magnetic rare earths consumed in the world. Total consumption of each rare earth in the short

  19. Numerical simulation and optimization of passively q-switched erbium microchip lasers

    NASA Astrophysics Data System (ADS)

    Belghachem, Nabil; Mlynczak, Jarslow

    2015-08-01

    In this article we present a procedure of optimization of passively q-switched erbium microchip lasers. The procedure is based on the rate equation model, validated by comparing the numerical results to the experimental results of pulse generation in different types of erbium/ytterbium glass microchips q-switched by Co2+ : MgAl2O4 saturable absorber. Some Degnan’s optimization limitations in case of microchip lasers were also shown and the reabsorbtion cross section of erbium glass was also estimated.

  20. Vapor bubble formation during erbium:YAG laser vitrectomy

    NASA Astrophysics Data System (ADS)

    Mrochen, Michael; Donitzky, Christof; Riedel, Peter; Wenig, Micaela; Reindl, Max; Seiler, Theo

    1999-06-01

    Background: The formation of evaporation bubbles and pressure waves during Erbium:YAG laser vitrectomy might cause intraocular damages. Methods: In water, the formation of the evaporation bubbles was observed by high-speed photography. The output energy of the quartz tip ranges from 5 to 50 mJ and the laser pulse duration from 50 μsec to 300 μsec. The dynamic of the evaporation bubbles were investigated for different diameters, various angles and radii of the quartz fiber tip. Furthermore, the spread out of the evaporation bubbles was observed for various geometries of the microsurgery probe. The induced stress waves were measured with a PVDF-hydrophone. Results: The evaporation bubble size increases semi-logarithmic with the pulse energy and reduces with the increase of the pulse duration. The diameter of the tip has no significant influence in the vapor bubble size. The expansion of the vapor bubble can be controlled by the geometry of the tip. The spread out of the vapor bubble can reduced by a slit geometry of the aspiration hole. The maximum pressure amplitude as found to be < 2 MPa. Conclusions: The evolution of evaporation bubbles and the induced pressure amplitudes from the microsurgery probe can be minimized for Erbium:YAG laser vitrectomy.

  1. Generalized rate-equation analysis of excitation exchange between silicon nanoclusters and erbium ions

    SciTech Connect

    Kenyon, A. J.; Wojdak, M.; Ahmad, I.; Loh, W. H.; Oton, C. J.

    2008-01-15

    We discuss the use of rate equations to analyze the sensitization of erbium luminescence by silicon nanoclusters. In applying the general form of second-order coupled rate-equations to the Si nanocluster-erbium system, we find that the photoluminescence dynamics cannot be described using a simple rate equation model. Both rise and fall times exhibit a stretched exponential behavior, which we propose arises from a combination of a strongly distance-dependent nanocluster-erbium interaction, along with the finite size distribution and indirect band gap of the silicon nanoclusters. Furthermore, the low fraction of erbium ions that can be excited nonresonantly is a result of the small number of ions coupled to nanoclusters.

  2. Radiation-resistant erbium-doped-nanoparticles optical fiber for space applications.

    PubMed

    Thomas, Jérémie; Myara, Mikhaël; Troussellier, Laurent; Burov, Ekaterina; Pastouret, Alain; Boivin, David; Mélin, Gilles; Gilard, Olivier; Sotom, Michel; Signoret, Philippe

    2012-01-30

    We demonstrate for the first time a radiation-resistant Erbium-Doped Fiber exhibiting performances that can fill the requirements of Erbium-Doped Fiber Amplifiers for space applications. This is based on an Aluminum co-doping atom reduction enabled by Nanoparticules Doping-Process. For this purpose, we developed several fibers containing very different erbium and aluminum concentrations, and tested them in the same optical amplifier configuration. This work allows to bring to the fore a highly radiation resistant Erbium-doped pure silica optical fiber exhibiting a low quenching level. This result is an important step as the EDFA is increasingly recognized as an enabling technology for the extensive use of photonic sub-systems in future satellites.

  3. Lanthanum(III) and praseodymium(III) complexes with isatin thiosemicarbazones

    NASA Astrophysics Data System (ADS)

    Rai, Anita; Sengupta, Soumitra K.; Pandey, Om P.

    2005-09-01

    Ten new lanthanum(III) and praseodymium(III) complexes of the general formula Na[La(L) 2H 2O] (Ln = La(III) or Pr(III); LH 2 = thiosemicarbazones) derived from the condensation of isatin with 4-phenyl thiosemicarbazide, 4-(4-chlorophenyl) thiosemicarbazide, 4-(2-nitrophenyl) thiosemicarbazide, 4-(2-bromophenyl) thiosemicarbazide and 4-(2-methylphenyl) thiosemicarbazide, have been synthesized in methanol in presence of sodium hydroxide. The XRD spectra of the complexes were monitored to verify complex formation. The complexes have also been characterized by elemental analysis, molar conductance, electronic absorption and fluorescence, infrared, far infrared, 1H and 13C NMR spectral studies. Thermal studies of these complexes have been carried out in the temperature range 25-800 °C using TG, DTG and DTA techniques. All these complexes decompose gradually with the formation of Ln 2O 3 as the end product. The Judd-ofelt intensity parameter, oscillator strength, transition probability, stimulated emission cross section for different transitions of Pr 3+ for 4-phenyl thiosemicarbazones have been calculated.

  4. Interactions of praseodymium and neodymium with nucleosides and nucleotides: absorption difference and comparative absorption spectral study.

    PubMed

    Misra, S N; Anjaiah, K; Joseph, G; Abdi, S H

    1992-02-01

    The interactions of praseodymium(III) and neodymium(III) with nucleosides and nucleotides have been studied in different stoichiometry in water and water-DMF mixtures by employing absorption difference and comparative absorption spectrophotometry. The 4f-4f bands were analysed by linear curve analysis followed by gaussian curve analysis, and various spectral parameters were computed, using partial and multiple regression method. The magnitude of changes in both energy interaction and intensity were used to explore the degree of outer and inner sphere coordination, incidence of covalency and the extent of metal 4f-orbital involvement in chemical bonding. Crystalline complexes of the type [Ln(nucleotide)2(H2O)2]- (where nucleotide--GMP or IMP) were characterized by IR, 1H NMR, 31P NMR data. These studies indicated that the binding of the nucleotide is through phosphate oxygen in a bidentate manner and the complexes undergo substantial ionisation in aqueous medium, thereby supporting the observed weak 4f-4f bands and lower values for nephelauxetic effect (1-beta), bonding (b) and covalency (delta) parameters derived from coulombic and spin orbit interaction parameters.

  5. Valence of praseodymium in superconducting Pr(O,F)BiS2 single crystals

    NASA Astrophysics Data System (ADS)

    Ishii, Satoshi; Hongu, Yasuaki; Miura, Akira; Nagao, Masanori

    2016-06-01

    The praseodymium (Pr) valence in superconducting PrO1- x F x BiS2 (x = 0.13,0.23) single crystals was evaluated by X-ray photoelectron spectroscopy. The Pr 3d core level is split into 3d3/2 and 3d5/2 levels. Both PrO1- x F x BiS2 and Pr2S3, which contain only Pr3+, showed 3d spectra at a lower binding energy than Pr6O11, which contains both Pr3+ and Pr4+. Neither PrO1- x F x BiS2 nor Pr2S3 showed the characteristic satellites of Pr4+ in 3d5/2 spectra. The valence fluctuation between the Pr3+ and Pr4+ states was not confirmed, suggesting that Pr3+ is dominant in PrO1- x F x BiS2 (x = 0.13,0.23) single crystals.

  6. RM1 Semiempirical Quantum Chemistry: Parameters for Trivalent Lanthanum, Cerium and Praseodymium

    PubMed Central

    Dutra, José Diogo L.; Filho, Manoel A. M.; Rocha, Gerd B.; Simas, Alfredo M.; Freire, Ricardo O.

    2015-01-01

    The RM1 model for the lanthanides is parameterized for complexes of the trications of lanthanum, cerium, and praseodymium. The semiempirical quantum chemical model core stands for the [Xe]4fn electronic configuration, with n =0,1,2 for La(III), Ce(III), and Pr(III), respectively. In addition, the valence shell is described by three electrons in a set of 5d, 6s, and 6p orbitals. Results indicate that the present model is more accurate than the previous sparkle models, although these are still very good methods provided the ligands only possess oxygen or nitrogen atoms directly coordinated to the lanthanide ion. For all other different types of coordination, the present RM1 model for the lanthanides is much superior and must definitely be used. Overall, the accuracy of the model is of the order of 0.07Å for La(III) and Pr(III), and 0.08Å for Ce(III) for lanthanide-ligand atom distances which lie mostly around the 2.3Å to 2.6Å interval, implying an error around 3% only. PMID:26132289

  7. Internal radiotherapy techniques using radiolanthanide praseodymium-142: a review of production routes, brachytherapy, unsealed source therapy.

    PubMed

    Bakht, Mohamadreza K; Sadeghi, Mahdi

    2011-10-01

    Radionuclides of rare earth elements are gaining importance as emerging therapeutic agents in nuclear medicine. β(-)-particle emitter 142Pr [T (1/2) = 19.12 h, E(-)β = 2.162 MeV (96.3%), Eγ = 1575 keV (3.7%)] is one of the praseodymium-141 (100% abundant) radioisotopes. Production routes and therapy aspects of 142Pr will be reviewed in this paper. However, 142Pr produces via 141Pr(n, γ) 142Pr reaction by irradiation in a low-fluence reactor; 142Pr cyclotron produced, could be achievable. 142Pr due to its high β(-)-emission and low specific gamma γ-emission could not only be a therapeutic radionuclide, but also a suitable radionuclide in order for biodistribution studies. Internal radiotherapy using 142Pr can be classified into two sub-categories: (1) unsealed source therapy (UST), (2) brachytherapy. UST via 142Pr-HA and 142Pr-DTPA in order for radiosynovectomy have been proposed. In addition, 142Pr Glass seeds and 142Pr microspheres have been utilized for interstitial brachytherapy of prostate cancer and intraarterial brachytherapy of arteriovenous malformation, respectively.

  8. RM1 Semiempirical Quantum Chemistry: Parameters for Trivalent Lanthanum, Cerium and Praseodymium.

    PubMed

    Dutra, José Diogo L; Filho, Manoel A M; Rocha, Gerd B; Simas, Alfredo M; Freire, Ricardo O

    2015-01-01

    The RM1 model for the lanthanides is parameterized for complexes of the trications of lanthanum, cerium, and praseodymium. The semiempirical quantum chemical model core stands for the [Xe]4fn electronic configuration, with n =0,1,2 for La(III), Ce(III), and Pr(III), respectively. In addition, the valence shell is described by three electrons in a set of 5d, 6s, and 6p orbitals. Results indicate that the present model is more accurate than the previous sparkle models, although these are still very good methods provided the ligands only possess oxygen or nitrogen atoms directly coordinated to the lanthanide ion. For all other different types of coordination, the present RM1 model for the lanthanides is much superior and must definitely be used. Overall, the accuracy of the model is of the order of 0.07Å for La(III) and Pr(III), and 0.08Å for Ce(III) for lanthanide-ligand atom distances which lie mostly around the 2.3Å to 2.6Å interval, implying an error around 3% only.

  9. Structural studies of lithium boro tellurite glasses doped with praseodymium and samarium oxides

    SciTech Connect

    Damas, Pedro; Coelho, João; Hungerford, Graham; Hussain, N. Sooraj

    2012-11-15

    Graphical abstract: [TeO{sub 4}] trigonal bipyramid structural unit, which is formed by two unequivalent pair of oxygen atoms: two equatorial oxygens (O{sub eq}) and two axial oxygens (O{sub ax}). Highlights: ► Pr{sup 3+} and Sm{sup 3+} doped LBT glasses have been prepared and characterized. ► LBT glasses present normal surfaces without metallic clusters. ► Raman spectra revealed the network modifying behaviour of dopant ions. -- Abstract: This paper reports the preparation and structural studies of praseodymium and samarium (0.5, 2 and 4 mol%) oxide doped lithium boro tellurite glasses. These materials were prepared by the quenching technique in a ceramic crucible at 950 °C. Structural characterization was performed by Raman spectroscopy, Scanning Electron Microscopy and Energy Dispersive X-ray spectroscopy techniques. Results from Raman analysis are in good agreement with those reported in the literature, revealing a normal glass structure for the host material. Understanding on how the glasses internal structure changed when the doping concentration increases was also assessed.

  10. Lanthanum(III) and praseodymium(III) complexes with isatin thiosemicarbazones.

    PubMed

    Rai, Anita; Sengupta, Soumitra K; Pandey, Om P

    2005-09-01

    Ten new lanthanum(III) and praseodymium(III) complexes of the general formula Na[La(L)2H2O] (Ln=La(III) or Pr(III); LH2=thiosemicarbazones) derived from the condensation of isatin with 4-phenyl thiosemicarbazide, 4-(4-chlorophenyl) thiosemicarbazide, 4-(2-nitrophenyl) thiosemicarbazide, 4-(2-bromophenyl) thiosemicarbazide and 4-(2-methylphenyl) thiosemicarbazide, have been synthesized in methanol in presence of sodium hydroxide. The XRD spectra of the complexes were monitored to verify complex formation. The complexes have also been characterized by elemental analysis, molar conductance, electronic absorption and fluorescence, infrared, far infrared, 1H and 13C NMR spectral studies. Thermal studies of these complexes have been carried out in the temperature range 25-800 degrees C using TG, DTG and DTA techniques. All these complexes decompose gradually with the formation of Ln2O3 as the end product. The Judd-ofelt intensity parameter, oscillator strength, transition probability, stimulated emission cross section for different transitions of Pr3+ for 4-phenyl thiosemicarbazones have been calculated.

  11. Electronic-structure calculations of praseodymium metal by means of modified density-functional theory

    SciTech Connect

    Svane, A.; Trygg, J.; Johansson, B.; Eriksson, O. |

    1997-09-01

    Electronic-structure calculations of elemental praseodymium are presented. Several approximations are used to describe the Pr f electrons. It is found that the low-pressure, trivalent phase is well described using either the self-interaction corrected (SIC) local-spin-density (LSD) approximation or the generalized-gradient approximation (GGA) with spin and orbital polarization (OP). In the SIC-LSD approach the Pr f electrons are treated explicitly as localized with a localization energy given by the self-interaction of the f orbital. In the GGA+OP scheme the f-electron localization is described by the onset of spin and orbital polarization, the energetics of which is described by spin-moment formation energy and a term proportional to the total orbital moment, L{sub z}{sup 2}. The high-pressure phase is well described with the f electrons treated as band electrons, in either the LSD or the GGA approximations, of which the latter describes more accurately the experimental equation of state. The calculated pressure of the transition from localized to delocalized behavior is 280 kbar in the SIC-LSD approximation and 156 kbar in the GGA+OP approach, both comparing favorably with the experimentally observed transition pressure of 210 kbar. {copyright} {ital 1997} {ital The American Physical Society}

  12. RM1 Semiempirical Quantum Chemistry: Parameters for Trivalent Lanthanum, Cerium and Praseodymium.

    PubMed

    Dutra, José Diogo L; Filho, Manoel A M; Rocha, Gerd B; Simas, Alfredo M; Freire, Ricardo O

    2015-01-01

    The RM1 model for the lanthanides is parameterized for complexes of the trications of lanthanum, cerium, and praseodymium. The semiempirical quantum chemical model core stands for the [Xe]4fn electronic configuration, with n =0,1,2 for La(III), Ce(III), and Pr(III), respectively. In addition, the valence shell is described by three electrons in a set of 5d, 6s, and 6p orbitals. Results indicate that the present model is more accurate than the previous sparkle models, although these are still very good methods provided the ligands only possess oxygen or nitrogen atoms directly coordinated to the lanthanide ion. For all other different types of coordination, the present RM1 model for the lanthanides is much superior and must definitely be used. Overall, the accuracy of the model is of the order of 0.07Å for La(III) and Pr(III), and 0.08Å for Ce(III) for lanthanide-ligand atom distances which lie mostly around the 2.3Å to 2.6Å interval, implying an error around 3% only. PMID:26132289

  13. Resonantly photo-pumped nickel-like erbium X-ray laser

    DOEpatents

    Nilsen, Joseph

    1990-01-01

    A resonantly photo-pumped X-ray laser (10) that enhances the gain of seve laser lines that also lase because of collisional excitations and recombination processes, is described. The laser comprises an aluminum (12) and erbium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state nickel-like erbium ions (34) are resonantly photo-pumped by line emission from hydrogen-like aluminum ions (32).

  14. Multiwavelength erbium fiber ring laser using Sagnac loop and Fabry-Perot laser diode

    NASA Astrophysics Data System (ADS)

    Yeh, C.-H.; Shih, F.-Y.; Chen, C.-T.; Lee, C.-N.; Chi, S.

    2008-03-01

    We propose and demonstrate experimentally a simply multiple-wavelength erbium compound ring fiber laser employing a Sagnac interferometer with erbium-doped fiber amplifier (EDFA) and Fabry-Perot laser diode (FP-LD). The proposed laser has the advantage of simply structure and easy fabrication, lower insertion loss and cost-effective. Based on the Sagnac fiber laser scheme, the proposed laser can lase eight wavelengths simultaneously. Moreover, the optical output stability of the ring laser has been also discussed.

  15. Kinetic lattice Monte Carlo model for oxygen vacancy diffusion in praseodymium doped ceria: Applications to materials design

    SciTech Connect

    Dholabhai, Pratik P.; Anwar, Shahriar; Adams, James B.; Crozier, Peter; Sharma, Renu

    2011-04-15

    Kinetic lattice Monte Carlo (KLMC) model is developed for investigating oxygen vacancy diffusion in praseodymium-doped ceria. The current approach uses a database of activation energies for oxygen vacancy migration, calculated using first-principles, for various migration pathways in praseodymium-doped ceria. Since the first-principles calculations revealed significant vacancy-vacancy repulsion, we investigate the importance of that effect by conducting simulations with and without a repulsive interaction. Initially, as dopant concentrations increase, vacancy concentration and thus conductivity increases. However, at higher concentrations, vacancies interfere and repel one another, and dopants trap vacancies, creating a 'traffic jam' that decreases conductivity, which is consistent with the experimental findings. The modeled effective activation energy for vacancy migration slightly increased with increasing dopant concentration in qualitative agreement with the experiment. The current methodology comprising a blend of first-principle calculations and KLMC model provides a very powerful fundamental tool for predicting the optimal dopant concentration in ceria related materials. -- graphical abstract: Ionic conductivity in praseodymium doped ceria as a function of dopant concentration calculated using the kinetic lattice Monte Carlo vacancy-repelling model, which predicts the optimal composition for achieving maximum conductivity. Display Omitted Research highlights: {yields} KLMC method calculates the accurate time-dependent diffusion of oxygen vacancies. {yields} KLMC-VR model predicts a dopant concentration of {approx}15-20% to be optimal in PDC. {yields} At higher dopant concentration, vacancies interfere and repel one another, and dopants trap vacancies. {yields} Activation energy for vacancy migration increases as a function of dopant content

  16. Synthesis and properties of erbium oxide single crystals

    SciTech Connect

    Petrovic, J.J.; Romero, R.S.; Mendoza, D.; Kukla, A.M.; Hoover, R.C.; McClellan, K.J.

    1999-04-01

    Erbium oxide (Er{sub 2}O{sub 3}, erbia) is a highly stable cubic rare earth oxide with a high melting point of 2,430 C. Because of this, it may have potential applications where high temperature stability and corrosion resistance are required. However, relatively little is known about the properties of this oxide ceramic. The authors have employed a xenon optical floating zone unit with a temperature capability of 3,000 C to grow high quality single crystals of erbia. The conditions for single crystal growth of erbia have been established. The mechanical properties of erbia single crystals have been initially examined using microhardness indentation as a function of temperature.

  17. Nanoscale nonlinear effects in Erbium-implanted Yttrium Orthosilicate

    NASA Astrophysics Data System (ADS)

    Kukharchyk, Nadezhda; Shvarkov, Stepan; Probst, Sebastian; Xia, Kangwei; Becker, Hans-Werner; Pal, Shovon; Markmann, Sergej; Kolesov, Roman; Siyushev, Petr; Wrachtrup, Jörg; Ludwig, Arne; Ustinov, Alexey V.; Wieck, Andreas D.; Bushev, Pavel

    2016-09-01

    Doping of substrates at desired locations is a key technology for spin-based quantum memory devices. Focused ion beam implantation is well-suited for this task due to its high spacial resolution. In this work, we investigate ion-beam implanted erbium ensembles in Yttrium Orthosilicate crystals by means of confocal photoluminescence spectroscopy. The sample temperature and the post-implantation annealing step strongly reverberate in the properties of the implanted ions. We find that hot implantation leads to a higher activation rate of the ions. At high enough fluences, the relation between the fluence and final concentration of ions becomes non-linear. Two models are developed explaining the observed behaviour.

  18. Organo-erbium systems for optical amplification at telecommunications wavelengths.

    PubMed

    Ye, H Q; Li, Z; Peng, Y; Wang, C C; Li, T Y; Zheng, Y X; Sapelkin, A; Adamopoulos, G; Hernández, I; Wyatt, P B; Gillin, W P

    2014-04-01

    Modern telecommunications rely on the transmission and manipulation of optical signals. Optical amplification plays a vital part in this technology, as all components in a real telecommunications system produce some loss. The two main issues with present amplifiers, which rely on erbium ions in a glass matrix, are the difficulty in integration onto a single substrate and the need of high pump power densities to produce gain. Here we show a potential organic optical amplifier material that demonstrates population inversion when pumped from above using low-power visible light. This system is integrated into an organic light-emitting diode demonstrating that electrical pumping can be achieved. This opens the possibility of direct electrically driven optical amplifiers and optical circuits. Our results provide an alternative approach to producing low-cost integrated optics that is compatible with existing silicon photonics and a different route to an effective integrated optics technology.

  19. Ion implantation of erbium into polycrystalline cadmium telluride

    SciTech Connect

    Ushakov, V. V. Klevkov, Yu. V.; Dravin, V. A.

    2015-05-15

    The specific features of the ion implantation of polycrystalline cadmium telluride with grains 20–1000 μm in dimensions are studied. The choice of erbium is motivated by the possibility of using rare-earth elements as luminescent “probes” in studies of the defect and impurity composition of materials and modification of the composition by various technological treatments. From the microphotoluminescence data, it is found that, with decreasing crystal-grain dimensions, the degree of radiation stability of the material is increased. Microphotoluminescence topography of the samples shows the efficiency of the rare-earth probe in detecting regions with higher impurity and defect concentrations, including regions of intergrain boundaries.

  20. Lower lip mucocele treated with an erbium laser.

    PubMed

    Boj, Juan R; Poirier, Clervie; Espasa, Enrique; Hernandez, Miguel; Espanya, Antonio

    2009-01-01

    Mucoceles are benign lesions of the minor salivary glands that are common in children. The most frequent localizations of these lesions include the lower lip and the cheek mucosa. Such mucoceles are caused by traumas, the rubbing of orthodontic devices, or biting habits. The purpose of this article was to describe the case of a 4-mm extravasation mucocele located on the lower lip of a 9-year-old girl. This mucocele was removed with an erbium loser after perilesional infiltration with 12 mg of 2% lidocaine and epinephrine 1:100,000. The histopathological report confirmed the presurgical diagnosis. The wound healed excellently and rapidly without sutures. No relapse was observed a year ofter the surgery. Lasers apply modern technology and are useful for soft tissue surgery in pediatric dentistry, as operations are rapid and wounds heal well without sutures. PMID:19552230

  1. Dual-kind Q-switching of erbium fiber laser

    SciTech Connect

    Barmenkov, Yuri O. Kir'yanov, Alexander V.; Cruz, Jose L.; Andres, Miguel V.

    2014-03-03

    Two different regimes of Q-switching in the same implementation of an actively Q-switched erbium-doped fiber laser are demonstrated. Depending on the active fiber length and repetition rate of an intracavity Q-cell (acousto-optic modulator), the laser operates either in the regime of common, rather long and low-power, pulses composed of several sub-pulses or in the one of very short and powerful stimulated Brillouin scattering-induced pulses. The basic physical reason of the laser system to oscillate in one of these two regimes is the existence or absence of CW narrow-line “bad-cavity” lasing in the intervals when the Q-cell is blocked.

  2. An Erbium Quantum Gas Microscope with a Reflective Objective

    NASA Astrophysics Data System (ADS)

    Krahn, Aaron; Phelps, Gregory; Hebert, Anne; Dickerson, Susannah; Greiner, Markus; Erbium Lab Team

    2016-05-01

    Dipolar atoms present an exciting opportunity to extend previous quantum gas microscope (QGM) experiments to more complex systems influenced by long range, anisotropic interactions. We present on current progress toward the construction of a QGM for ultracold Erbium atoms in an optical lattice, including the development of a novel imaging system for single-site resolution. While most QGMs until now have typically utilized a high numerical aperture microscope objective, we discuss a reflective mirror alternative that offers an equally high NA (.9-.95), a comparable field of view (34 micrometers radial), and a larger working distance (25 millimeters) that keeps the atoms far from any surfaces. By operating in a Schmidt telescope configuration, this imaging system is well-suited both for collecting 401 nm imaging fluorescence and for the creation of an expandable lattice with a variety of associated lattice geometries.

  3. A higher-order-mode erbium-doped-fiber amplifier.

    PubMed

    Nicholson, J W; Fini, J M; DeSantolo, A M; Monberg, E; DiMarcello, F; Fleming, J; Headley, C; DiGiovanni, D J; Ghalmi, S; Ramachandran, S

    2010-08-16

    We demonstrate the first erbium-doped fiber amplifier operating in a single, large-mode area, higher-order mode. A high-power, fundamental-mode, Raman fiber laser operating at 1480 nm was used as a pump source. Using a UV-written, long-period grating, both pump and 1564 nm signal were converted to the LP(0,10) mode, which had an effective area of 2700 microm(2) at 1550 nm. A maximum output power of 5.8 W at 1564 nm with more than 20 dB of gain in a 2.68 m long amplifier was obtained. The mode profile was undistorted at the highest output power.

  4. Characteristics of the Brillouin spectra in Erbium-Ytterbium fibers.

    PubMed

    Canat, G; Durécu, A; Lesueur, G; Lombard, L; Bourdon, P; Jolivet, V; Jaouën, Y

    2008-03-01

    This paper reports the main characteristics of the Stokes spectra for typical pumped and unpumped Erbium-Ytterbium doped fibers. Doped fibers show shorter Brillouin shifts and their spectra are up to 1.6 times broader than undoped fibers. Those spectra are composed of several peaks originating from several longitudinal acoustic modes. The effective Brillouin gain of the secondary modes can be as large as 20% of the main peak gain. They can merge into a more complex structure for the largest cores. Simulations allow to relate these characteristics to the influence of codoping and index profile inhomogeneity. An additional broadening of the Stokes spectrum in pumped fibers is reported and attributed to thermal effects.

  5. Lower lip mucocele treated with an erbium laser.

    PubMed

    Boj, Juan R; Poirier, Clervie; Espasa, Enrique; Hernandez, Miguel; Espanya, Antonio

    2009-01-01

    Mucoceles are benign lesions of the minor salivary glands that are common in children. The most frequent localizations of these lesions include the lower lip and the cheek mucosa. Such mucoceles are caused by traumas, the rubbing of orthodontic devices, or biting habits. The purpose of this article was to describe the case of a 4-mm extravasation mucocele located on the lower lip of a 9-year-old girl. This mucocele was removed with an erbium loser after perilesional infiltration with 12 mg of 2% lidocaine and epinephrine 1:100,000. The histopathological report confirmed the presurgical diagnosis. The wound healed excellently and rapidly without sutures. No relapse was observed a year ofter the surgery. Lasers apply modern technology and are useful for soft tissue surgery in pediatric dentistry, as operations are rapid and wounds heal well without sutures.

  6. Microscopic analysis of laser-induced proximal fiber tip damage during holmium:YAG and thulium fiber laser lithotripsy

    NASA Astrophysics Data System (ADS)

    Wilson, Christopher R.; Hardy, Luke A.; Irby, Pierce B.; Fried, Nathaniel M.

    2016-04-01

    The thulium fiber laser (TFL) is being studied as an alternative to the standard holmium:YAG laser for lithotripsy. The TFL beam originates within an 18-μm-core thulium-doped silica fiber, and its near single mode, Gaussian beam profile enables transmission of higher laser power through smaller (e.g., 50- to 150-μm core) fibers than possible during holmium laser lithotripsy. This study examines whether the more uniform TFL beam profile also reduces proximal fiber tip damage compared with the holmium laser multimodal beam. Light and confocal microscopy images were taken of the proximal surface of each fiber to inspect for possible laser-induced damage. A TFL beam at a wavelength of 1908 nm was coupled into 105-μm-core silica fibers, with 35-mJ energy, and 500-μs pulse duration, and 100,000 pulses were delivered at each pulse rate setting of 50, 100, 200, 300, and 400 Hz. For comparison, single use, 270-μm-core fibers were collected after clinical holmium laser lithotripsy procedures performed with standard settings (600 mJ, 350 μs, 6 Hz). Total laser energy, number of laser pulses, and laser irradiation time were recorded, and fibers were rated for damage. For TFL studies, output pulse energy and average power were stable, and no proximal fiber damage was observed at settings up to 35 mJ, 400 Hz, and 14 W average power (n=5). In contrast, confocal microscopy images of fiber tips after holmium lithotripsy showed proximal fiber tip degradation, indicated by small ablation craters on the scale of several micrometers in all fibers (n=20). In summary, the proximal fiber tip of a 105-μm-core fiber transmitted up to 14 W of TFL power without degradation, compared to degradation of 270-μm-core fibers after transmission of 3.6 W of holmium laser power. The smaller and more uniform TFL beam profile may improve fiber lifetime, and potentially translate into lower costs for the surgical disposables as well.

  7. Chaotic dynamics in erbium-doped fiber ring lasers

    SciTech Connect

    Abarbanel, H.D.; Kennel, M.B.; Buhl, M.; Lewis, C.T. )

    1999-09-01

    Chaotically oscillating rare-earth-doped fiber ring lasers (DFRLs) may provide an attractive way to exploit the broad bandwidth available in an optical communications system. Recent theoretical and experimental investigations have successfully shown techniques to modulate information onto the wide-band chaotic oscillations, transmit that signal along an optical fiber, and demodulate the information at the receiver. We develop a theoretical model of a DFRL and discuss an efficient numerical simulation which includes intrinsic linear and nonlinear induced birefringence, both transverse polarizations, group velocity dispersion, and a finite gain bandwidth. We analyze first a configuration with a single loop of optical fiber containing the doped fiber amplifier, and then, as suggested by Roy and VanWiggeren, we investigate a system with two rings of optical fiber[emdash]one made of passive fiber alone. The typical round-trip time for the passive optical ring connecting the erbium-doped amplifier to itself is 200 ns, so [approx]10[sup 5] round-trips are required to see the slow effects of the population inversion dynamics in this laser system. Over this large number of round-trips, physical effects like GVD and the Kerr nonlinearity, which may appear small at our frequencies and laser powers via conventional estimates, may accumulate and dominate the dynamics. We demonstrate from our model that chaotic oscillations of the ring laser with parameters relevant to erbium-doped fibers arises from the nonlinear Kerr effect and not from interplay between the atomic population inversion and radiation dynamics. thinsp [copyright] [ital 1999] [ital The American Physical Society

  8. Use of the holmium:YAG (Ho:YAG) laser for treatment of superficial bladder carcinoma.

    PubMed

    Johnson, D E

    1994-01-01

    This is the first North American report describing the use of the holmium:YAG (Ho:YAG) laser to treat patients with superficial bladder carcinoma. Fifteen patients, with a total of 52 recurrent superficial bladder tumors, underwent endoscopic laser photoablation of their lesions. No intraoperative or delayed complications occurred. At follow-up cystoscopy performed 3 months after lasing, four patients (27%) were without disease; eight patients (53%) had out-of-field recurrences; and three patients (20%) were classified as having in-field recurrences. We conclude that using the Ho:YAG for endoscopic treatment of patients with superficial bladder tumors is both feasible and clinically useful and that the lack of perceived pain or discomfort during lasing, as well as the lack of need for an in-dwelling urethral catheter, makes it advantageous for selected patients over conventional electroresection techniques.

  9. Operation of the nose using Nd-YAG and holmium laser

    NASA Astrophysics Data System (ADS)

    Kukwa, Andrzej; Tulibacki, Marek P.; Zajac, Andrzej; Dudziec, Katarzyna

    2000-06-01

    During more than 5 years Nd:YAG and Holmium laser has been used in our ENT Department for the treatment of varies pathological changes. Most of our cases were previously treated many times because of recurrences of the nasal polyps. As a rule the treatment was given in one to three sessions. Each patient was very closely monitored. The time period between the session was 2-4 weeks. The consequent application of laser was dependent on healing process. All adults' patients were treated in local anesthesia using 1,5 percent of Cocaine and 10 percent Xylocaine applied in a spray; no other anesthetics were needed, although in some patients 10 mg Valium was administered before first session of laser application. We do not observe a severe bleeding needed sponge or a nose package. Among advantages we have to concentrate on two: the recurrences of nasal polyps are definitely much rare and patient may appear at work at the same day.

  10. Application of 2-um wavelength holmium lasers for treatment of skin diseases

    NASA Astrophysics Data System (ADS)

    Shcherbakov, Ivan A.; Klimov, Igor V.; Tsvetkov, Vladimir B.; Nerobeev, Alexander I.; Sadovnikova, Lija B.; Eliseenko, Vladimir I.

    1994-09-01

    Theoretical and experimental analysis of the efficiency of application of 2 micrometers pulsed holmium laser for cosmetic and plastic surgery and dermatology is carried out. Preliminary experiments were carried out on rats. Solid state 2 micrometers pulsed laser was allowed to operate in free running mode with pulse energy up to 1.5 J and pulse repetition rate up to 5 Hz. To deliver emission to the object a flexible quartz fiber without further focusing of 2.5 m in length and 400 micrometers of the core diameter was used. The effect of the different power density emission on the skin was studied. The second stage was the study of the influence of 2 micrometers emission on human skin. The results of the removal of hemangioma, papilloma, telangiectasia, nevus, nevus acantholytic, xanthelasma palpebral, verruca, chloasma, pigmental spots, tattoos, etc. are presented. Precision, simplicity, efficiency, and the high cosmetic effect of these operations is noted.

  11. Magnetization process in holmium: easy axis spin reorientation induced by the magnetostrictive basal plane distortion.

    PubMed

    Benito, L; Ciria, M; de la Fuente, C; Arnaudas, J I; Ward, R C C; Wells, M R

    2005-06-10

    We report on the change of the easy axis direction in holmium, from the a to the b axis, under the application of a magnetic field in the basal plane. This spin reorientation is observed by measuring the magnetic torque in Ho(n)/Lu(15) superlattices (n and 15 are the number of atomic planes in the Ho and Lu blocks). We also observe that, at the field H0 and temperature at which the reorientation occurs, both axes are easy directions. Based on the fact that the field H0 depends on n in the same way as the field-induced magnetoelastic distortion does, we propose that this spin reorientation originates from the strong field-induced magnetoelastic deformation within the basal plane. The modulation of the alpha strains with sixfold symmetry originates a 12-fold term in the magnetic anisotropy energy.

  12. Holmium-doped fluorotellurite microstructured fibers for 2.1 μm lasing.

    PubMed

    Yao, Chuanfei; He, Chunfeng; Jia, Zhixu; Wang, Shunbin; Qin, Guanshi; Ohishi, Yasutake; Qin, Weiping

    2015-10-15

    Holmium (Ho3+)-doped fluorotellurite microstructured fibers based on TeO2-BaF2-Y2O3 glasses are fabricated by using a rod-in-tube method. By using a 1.992 μm fiber laser as the pump source, lasing at 2.077 μm is obtained from a 27 cm long Ho3+-doped fluorotellurite microstructured fiber. The maximum unsaturated power is about 161 mW and the corresponding slope efficiency is up to 67.4%. The influence of fiber length on lasing at 2.1 μm is also investigated. Our results show that Ho3+-doped fluorotellurite microstructured fibers are promising gain media for 2.1 μm laser applications.

  13. High power operation of cladding pumped holmium-doped silica fibre lasers.

    PubMed

    Hemming, Alexander; Bennetts, Shayne; Simakov, Nikita; Davidson, Alan; Haub, John; Carter, Adrian

    2013-02-25

    We report the highest power operation of a resonantly cladding-pumped, holmium-doped silica fibre laser. The cladding pumped all-glass fibre utilises a fluorine doped glass layer to provide low loss cladding guidance of the 1.95 µm pump radiation. The operation of both single mode and large-mode area fibre lasers was demonstrated, with up to 140 W of output power achieved. A slope efficiency of 59% versus launched pump power was demonstrated. The free running emission was measured to be 2.12-2.15 µm demonstrating the potential of this architecture to address the long wavelength operation of silica based fibre lasers with high efficiency.

  14. Holmium Laser Enucleation of the Prostate in a 400 cc Prostate: Case Report

    PubMed Central

    Hong, Matthew K.H.; Pham, Trung

    2016-01-01

    Abstract The modality of choice in the surgical management of benign prostatic hyperplasia for large prostates has traditionally been open prostatectomy. Advances in minimally invasive techniques have begun to challenge this notion with advantages such as lower bleeding and transfusion rates and shorter hospital stay. In this case report, we illustrate the use of holmium laser enucleation of the prostate (HoLEP) in a gland measuring more than 400 cc. We describe the case of a 71-year-old man with persistent voiding urinary symptoms despite two previous transurethral resections of his prostate. With greater experience in HoLEP and declining experience in open prostatectomy, there may be a shift toward HoLEP as the preferred treatment choice for large prostate glands. PMID:27579406

  15. Holmium Laser Enucleation of the Prostate in a 400 cc Prostate: Case Report.

    PubMed

    Gopee, Esha L; Hong, Matthew K H; Pham, Trung

    2016-01-01

    The modality of choice in the surgical management of benign prostatic hyperplasia for large prostates has traditionally been open prostatectomy. Advances in minimally invasive techniques have begun to challenge this notion with advantages such as lower bleeding and transfusion rates and shorter hospital stay. In this case report, we illustrate the use of holmium laser enucleation of the prostate (HoLEP) in a gland measuring more than 400 cc. We describe the case of a 71-year-old man with persistent voiding urinary symptoms despite two previous transurethral resections of his prostate. With greater experience in HoLEP and declining experience in open prostatectomy, there may be a shift toward HoLEP as the preferred treatment choice for large prostate glands. PMID:27579406

  16. Acute and chronic response of meniscal fibrocartilage to holmium:YAG laser irradiation

    NASA Astrophysics Data System (ADS)

    Horan, Patrick J.; Popovic, Neven A.; Islinger, Richard B.; Kuklo, Timothy R.; Dick, Edward J.

    1997-05-01

    The acute and chronic (10 week) histological effects of the holmium:YAG laser during partial meniscectomy in an in vivo rabbit model were investigated. Twenty-four adult male New Zealand rabbits underwent bilateral parapatellar medial knee arthrotomies. In the right knee, a partial medial meniscectomy was done through the avascular zone using a standard surgical blade. In the left knee, an anatomically similar partial medial meniscectomy was performed using a Ho:YAG laser (Coherent, USA). This study indicates that the laser creates two zones of damage in the meniscal fibrocartilage and that the zone of thermal change may act as a barrier to healing. The zone of thermal change which is eventually debrided was thought at the time of surgery to be viable. In the laser cut menisci, the synovium appears to have greater inflammation early and to be equivalent with the scalpel cut after three weeks. At all time periods there appeared more cellular damage in the laser specimens.

  17. Percutaneous Transhepatic Endoscopic Holmium Laser Lithotripsy for Intrahepatic and Choledochal Biliary Stones

    SciTech Connect

    Rimon, Uri; Kleinmann, Nir; Bensaid, Paul; Golan, Gil; Garniek, Alexander; Khaitovich, Boris; Winkler, Harry

    2011-12-15

    Purpose: To report our approach for treating complicated biliary calculi by percutaneous transhepatic endoscopic biliary holmium laser lithotripsy (PTBL). Patients and Methods: Twenty-two symptomatic patients (11 men and 11 women, age range 51 to 88 years) with intrahepatic or common bile duct calculi underwent PTBL. Nine patients had undergone previous gastrectomy and small-bowel anastomosis, thus precluding endoscopic retrograde cholangiopancreatography. In the other 13 patients, stone removal attempts by ERCP failed due to failed access or very large calculi. We used a 7.5F flexible ureteroscope and a 200-{mu}m holmium laser fiber by way of a percutaneous transhepatic tract, with graded fluoroscopy, to fragment the calculi with direct vision. Balloon dilatation was added when a stricture was seen. The procedure was performed with the patient under general anaesthesia. A biliary drainage tube was left at the end of the procedure. Results: All stones were completely fragmented and flushed into the small bowel under direct vision except for one patient in whom the procedure was aborted. In 18 patients, 1 session sufficed, and in 3 patients, 2 sessions were needed. In 7 patients, balloon dilatation was performed for benign stricture after Whipple operation (n = 3), for choledochalenteric anastomosis (n = 3), and for recurrent cholangitis (n = 1). Adjunctive 'balloon push' (n = 4) and 'rendezvous' (n = 1) procedures were needed to completely clean the biliary tree. None of these patients needed surgery. Conclusion: Complicated or large biliary calculi can be treated successfully using PTBL. We suggest that this approach should become the first choice of treatment before laparoscopic or open surgery is considered.

  18. Efficacy of retrograde ureteropyeloscopic holmium laser lithotripsy for intrarenal calculi >2 cm.

    PubMed

    Bader, M J; Gratzke, C; Walther, S; Weidlich, P; Staehler, M; Seitz, M; Sroka, R; Reich, O; Stief, C G; Schlenker, B

    2010-10-01

    The objectives of this study are to assess the efficacy and safety of retrograde ureteroscopic holmium laser lithotripsy for intrarenal calculi greater than 2 cm in diameter. A total of 24 patients with a stone burden >2 cm were treated with retrograde ureteroscopic laser lithotripsy. Primary study endpoints were number of treatments until the patient was stone free and perioperative complications with a follow-up of at least 3 months after intervention. In 24 patients (11 women and 13 men, 20-78 years of age), a total of 40 intrarenal calculi were treated with retrograde endoscopic procedures. At the time of the initial procedure, calculi had an average total linear diameter of 29.75 ± 1.57 mm and an average stone volume of 739.52 ± 82.12 mm(3). The mean number of procedures per patient was 1.7 ± 0.8 (range 1-3 procedures). The overall stone-free rate was 92%. After 1, 2 and 3 procedures 54, 79 and 92% of patients were stone free, respectively. There were no major complications. Minor postoperative complications included pyelonephritis in three cases (7.5%), of whom all responded immediately to parenteral antibiotics. In one patient the development of steinstrasse in the distal ureter required ureteroscopic fragment disruption and basketing. Ureteroscopy with holmium laser lithotripsy represents an efficient treatment option and allows the treatment of large intrarenal calculi of all compositions and throughout the whole collecting system even for patients with a stone burden of more than 2 cm size. PMID:20204341

  19. Correlation of thermal and mechanical effects of the holmium laser for various clinical applications

    NASA Astrophysics Data System (ADS)

    Grimbergen, Matthijs C. M.; Verdaasdonck, Rudolf M.; van Swol, Christiaan F. P.

    1998-05-01

    The Holmium laser has become established in orthopedic surgery and urology due to its unique combination of mechanical and thermal properties induced by explosive vapor bubbles. In a specialized setup, real-time high-speed and thermal images of dynamic vapor bubbles and thermal relaxation at a water tissue interface were obtained simultaneously. The thermal effects in the tissue model were correlated to the characteristics of the bubbles dependent on pulse energy (0.2 - 4 J), pulse repetition frequency (5 - 40 Hz), distance and angle of fiber delivery system (diameter 365 micrometer) to the tissue surface. Up to a fiber-to-tissue distance of 50% of the radius of the bubble, only a superficial tissue layer was heated. During bubble implosion, the tissue surface was attracted to the fiber, ripping of irregularities, and was effectively cooled by turbulence. In case of hard tissues, the bubble detached from the fiber imploding towards the hard surface. At closer distances (less than 50% of bubble radius), the tissue itself was vaporized resulting in mechanical damage and thermal relaxation into the tissue, especially above repetition rates of 5 Hz. There is a strong correlation between the path length of the free beam within the bubble and the degree of mechanical and thermal damage in the tissue directly irradiated by this beam. During clinical applications the surgeon should be aware of the size of the vapor bubble in relation to the distance and angle with the tissue for safe optimal use of the mechanical and thermal properties of the Holmium laser.

  20. Intracavitary Radiation Therapy for Recurrent Cystic Brain Tumors with Holmium-166-Chico : A Pilot Study

    PubMed Central

    Ha, Eun Jin; Rhee, Chang Hun; Youn, Sang Min; Choi, Chang-Woon; Cheon, Gi Jeong

    2013-01-01

    Objective Intracavitary injection of beta-emitting radiation source for control of cystic tumors has been tried with a benefit of localized internal radiation. The authors treated cystic brain tumor patients with Holmium-166-chitosan complex (Ho-166-chico), composed of a beta-emitting radionuclide Holmium-166 and biodegradable chit polymer, and evaluated the safety and effective measurement for response. Methods Twenty-two patients with recurrent cystic brain tumor and/or located in a deep or eloquent area were enrolled in this pilot study. The cyst volume and wall thickness were determined on CT or MRI to assess radiological response. The activity of Ho-166-chico injected via Ommaya reservoir was prescribed to be 10-25 Gy to the cyst wall in a depth of 4 mm. Results There was neither complications related to systemic absorption nor leakage of Ho-166-chico in all 22 patients. But, two cases of oculomotor paresis were observed in patients with recurrent craniopharyngioma. Radiological response was seen in 14 of 20 available follow-up images (70%). Seven patients of 'evident' radiological response experienced more than 25% decrease of both cyst volume and wall thickness. Another 7 patients with 'suggestive' response showed decrease of cyst volume without definitive change of the wall thickness or vice versa. All patients with benign tumors or low grade gliomas experienced symptomatic improvement. Conclusion Ho-166-chico intracavitary radiation therapy for cystic tumor is a safe method of palliation without serious complications. The determination of both minimal effective dosage and time interval of repeated injection through phase 1 trial could improve the results in the future. PMID:24278644

  1. Holmium-loaded PLLA nanoparticles for intratumoral radiotherapy via the TMT technique: preparation, characterization, and stability evaluation after neutron irradiation.

    PubMed

    Hamoudeh, Misara; Fessi, Hatem; Salim, Hani; Barbos, Dumitru

    2008-08-01

    This article describes the preparation of biocompatible radioactive holmium-loaded particles with appropriate nanoscale size for radionuclide intratumoral administration by the targeted multitherapy (TMT) technique. For this objective, holmium acetylacetonate has been encapsulated in poly-L-lactide (PLLA)-based nanoparticles (NP) by oil-in-water emulsion-solvent evaporation method. NP sizes ranged between 100 and 1,100 m being suitable for the TMT administration method. Elemental holmium loading was found to be around 18% wt/wt and the holmium acetylacetonate trihydrate (HoAcAc) encapsulation efficacy was about 90%. Different experiments demonstrated an amorphous state of HoAcAc after incorporation in NPs. The NPs were irradiated in a nuclear reactor with a neutron flux of 1.1 x 10(13) n/cm(2)/s for 1 h, which yielded a specific activity of about 27.4 GBq/g of NPs being sufficient for our desired application. Microscopic analysis of irradiated NPs showed some alteration after neutron irradiation as some NPs looked partially coagglomerated and a few pores appeared at their surface because of the locally released heat in the irradiation vials. Furthermore, differential scanning calorimetry (DSC) results indicated a clear decrease in PLLA melting point and melting enthalpy reflecting a decrease in polymer crystallinity. This was accompanied by a clear decrease in polymer molecular weights, which can be ascribed to a radiation-induced chain scission mechanism. However, interestingly, other experiments confirmed the chemical identity retention of both HoAcAc and PLLA in irradiated NPs despite this detected decrease in the polymer crystallinity and molecular weight. Although neutron irradiation has induced some NPs damage, these NPs kept out their overall chemical composition, and their size distribution remained suitable for the TMT administration technique. Coupled with the TMT technique, these NPs may represent a novel potential radiopharmaceutical agent for

  2. Holmium laser vs. conventional (cold knife) direct visual internal urethrotomy for short-segment bulbar urethral stricture: Outcome analysis

    PubMed Central

    Jhanwar, Ankur; Kumar, Manoj; Sankhwar, Satya Narayan; Prakash, Gaurav

    2016-01-01

    Introduction: Our goal was to analyze the outcome between holmium laser and cold knife direct visual internal urethrotomy (DVIU) for short-segment bulbar urethral stricture. Methods: We conducted a prospective study comprised of 112 male patients seen from June 2013 to December 2014. Inclusion criterion was short-segment bulbar urethral stricture (≤1.5cm). Exclusion criteria were prior intervention/urethroplasty, pan-anterior urethral strictures, posterior stenosis, urinary tract infection, and those who lost to followup. Patients were divided into two groups; Group A (n=58) included cold knife DVIU and group B (n=54) included holmium laser endourethrotomy patients. Patient followup included uroflowmetry at postoperative Day 3, as well as at three months and six months. Results: Baseline demographics were comparable in both groups. A total of 107 patients met the inclusion criteria and five patients were excluded due to inadequate followup. Mean stricture length was 1.31 ± 0.252 cm (p=0.53) and 1.34 ± 0.251 cm in Groups A and B, respectively. Mean operating time in Group A was 16.3 ± 1.78 min and in Group B was 20.96 ± 2.23 min (p=0.0001). Five patients in Group A had bleeding after the procedure that was managed conservatively by applying perineal compression. Three patients in Group B had fluid extravasation postoperatively. Qmax (ml/s) was found to be statistically insignificant between the two groups at all followups. Conclusions: Both holmium laser and cold knife urethrotomy are safe and equally effective in treating short-segment bulbar urethral strictures in terms of outcome and complication rate. However, holmium laser requires more expertise and is a costly alternative. PMID:27790296

  3. Q-switching of a thulium-doped fibre laser using a holmium-doped fibre saturable absorber

    SciTech Connect

    Sadovnikova, Ya E; Kamynin, V A; Kurkov, A S; Medvedkov, O I; Marakulin, A V; Minashina, L A

    2014-01-31

    We have proposed and demonstrated a new passively Q-switched thulium-doped fibre laser configuration. A distinctive feature of this configuration is the use of a heavily holmium-doped fibre for Q-switching. Lasing was obtained at 1.96 μm, with a pulse energy of 3 μJ and pulse duration of 600 ns. The highest pulse repetition rate was 80 kHz. (control of laser radiation parameters)

  4. Radiation-resistant erbium-doped optical fiber for space applications

    NASA Astrophysics Data System (ADS)

    Thomas, Jérémie; Myara, Mikha"l.; Signoret, Philippe; Pastouret, Alain; Burov, Ekaterina; Boivin, David; Cavani, Olivier; Sotom, Michel; Maignan, Michel; Gilard, Olivier

    2012-01-01

    In the last decade, there has been increased interest in photonic technology for new satellite applications. One critical issue is the high sensitivity to radiative environments of the Erbium Doped Fiber (EDF). It leads to a radiation-induced absorption (RIA) that is not due to erbium content but mainly to the aluminium that ensures the erbium inclusion in glass. As the radiation induced losses grow as an exponential function of fiber length, the principal way so far to reduce EDFA degradation has consisted in increasing erbium concentration using conventional doping techniques. However, this is limited by the quenching effect, which impacts the fiber length needed to reach high gain, but also by the Aluminium-induced RIA. It has been recently proposed an original nanoparticle (NP) doping approach, which allows codopant content decrease with reduced quenching impact, while keeping EDF amplifying performances. A radiation-resistant amplifier can thus be designed as a "quenching-free", heavily-erbium-doped amplifier with low RIA. We demonstrate for the first time an aluminium-free EDF, exhibiting low quenching and low RIA. Despite the lack of aluminium, using silica NPs allows an erbium concentration close to the one of standard EDFs (200 ppm). This fiber is compared to a 1400 ppm Erbium-doped optical fiber with a strong aluminium concentration. Whereas the two fibers exhibit similar initial optical gain (15 dB under saturation conditions), the NP doped Al-free EDF shows only 2 dB gain reduction after a 600 Gy gamma deposit, while the Al/Er EDF incurs more than 10 dB gain degradation.

  5. Characterization of holmium fibers with various concentrations for fiber laser applications around 2.1 μm

    NASA Astrophysics Data System (ADS)

    Aubrecht, Jan; Peterka, Pavel; Honzatko, Pavel; Baravets, Yauhen; Jelinek, Michal; Kubecek, Vaclav; Pawliszewska, Maria; Sotor, Jaroslaw; Sobon, Grzegorz; Abramski, Krzysztof M.; Kasik, Ivan

    2016-04-01

    In this work, we present experimental results of characterization of the developed holmium-doped silica-based optical fibers with holmium ions concentrations in the range from 1000 to 10000 ppm. The fibers were fabricated by the modified chemical vapor deposition and solution doping method. They were characterized in terms of their spectral attenuation, refractive index profile, and especially performance in fiber laser. Simultaneously, two different fiber laser setups were tested. In the first one, holmium-doped fiber in Fabry-Perot configuration was pumping by in house developed thulium-doped fiber laser in ring arrangement. In the second one, bulk-optic pump-coupling configuration, consisted of a commercially available thulium fiber laser emitting at 1940 nm and system of lenses and mirrors was used. We have focused on comparison of laser output powers, slope efficiencies, and laser thresholds for individual holmiumdoped fiber in these different laser arrangements. Finally, the application of the developed fiber in subpicosecond fiber laser with graphene-based saturable absorber for mode-locking operation was investigated.

  6. Root Surface Bio-modification with Erbium Lasers- A Myth or a Reality??

    PubMed

    Lavu, Vamsi; Sundaram, Subramoniam; Sabarish, Ram; Rao, Suresh Ranga

    2015-01-01

    The objective of this literature review was to critically review the evidence available in the literature regarding the expediency of erbium family of lasers for root bio modification as a part of periodontal therapy. The literature search was performed on the Pubmed using MeSH words such as "lasers/therapeutic use, scaling, dental calculus, tooth root/anatomy and histology, ultrasonic therapy". The studies were screened and were grouped as follows: those evaluating a) efficacy for calculus removal with the Erbium family of laser b) root surface changes following Er YAG and Er Cr YSGG application c) comparative studies of the Er YAG, Er Cr YSGG lasers versus conventional methods of root surface modification d) Bio compatibility of root surface following Erbium laser treatment e) Studies on the combined efficacy of laser root modification with conventional methods towards root surface bio-modification f) Studies on effectiveness of root surface bio-modification prior to root coverage procedures. In conclusion, the erbium family has a proven anti-bacterial action, predictable calculus removal, minimal root substance removal, and appears to favor cell attachment. The Erbium family of lasers appears to be a useful adjunct for the management of periodontal disease. PMID:25713635

  7. Defect-free erbium silicide formation using an ultrathin Ni interlayer.

    PubMed

    Choi, Juyun; Choi, Seongheum; Kang, Yu-Seon; Na, Sekwon; Lee, Hoo-Jeong; Cho, Mann-Ho; Kim, Hyoungsub

    2014-08-27

    An ultrathin Ni interlayer (∼1 nm) was introduced between a TaN-capped Er film and a Si substrate to prevent the formation of surface defects during thermal Er silicidation. A nickel silicide interfacial layer formed at low temperatures and incurred uniform nucleation and the growth of a subsequently formed erbium silicide film, effectively inhibiting the generation of recessed-type surface defects and improving the surface roughness. As a side effect, the complete transformation of Er to erbium silicide was somewhat delayed, and the electrical contact property at low annealing temperatures was dominated by the nickel silicide phase with a high Schottky barrier height. After high-temperature annealing, the early-formed interfacial layer interacted with the growing erbium silicide, presumably forming an erbium silicide-rich Er-Si-Ni mixture. As a result, the electrical contact property reverted to that of the low-resistive erbium silicide/Si contact case, which warrants a promising source/drain contact application for future high-performance metal-oxide-semiconductor field-effect transistors.

  8. Root Surface Bio-modification with Erbium Lasers- A Myth or a Reality??

    PubMed

    Lavu, Vamsi; Sundaram, Subramoniam; Sabarish, Ram; Rao, Suresh Ranga

    2015-01-01

    The objective of this literature review was to critically review the evidence available in the literature regarding the expediency of erbium family of lasers for root bio modification as a part of periodontal therapy. The literature search was performed on the Pubmed using MeSH words such as "lasers/therapeutic use, scaling, dental calculus, tooth root/anatomy and histology, ultrasonic therapy". The studies were screened and were grouped as follows: those evaluating a) efficacy for calculus removal with the Erbium family of laser b) root surface changes following Er YAG and Er Cr YSGG application c) comparative studies of the Er YAG, Er Cr YSGG lasers versus conventional methods of root surface modification d) Bio compatibility of root surface following Erbium laser treatment e) Studies on the combined efficacy of laser root modification with conventional methods towards root surface bio-modification f) Studies on effectiveness of root surface bio-modification prior to root coverage procedures. In conclusion, the erbium family has a proven anti-bacterial action, predictable calculus removal, minimal root substance removal, and appears to favor cell attachment. The Erbium family of lasers appears to be a useful adjunct for the management of periodontal disease.

  9. Evaluation of retropulsion caused by holmium:YAG laser with various power settings and fibers.

    PubMed

    White, M D; Moran, M E; Calvano, C J; Borhan-Manesh, A; Mehlhaff, B A

    1998-04-01

    The ideal intracorporeal lithotriper would comminute all types of calculi into small readily excreted particles. It would be small and flexible with an energy source safe for the uroepithelium. It should not break, should be inexpensive, and should not retropulse the stone up the urinary tract. This investigation was designed to quantify the last quality for the holmium:YAG laser. The mechanism of action of the pulsed Ho:YAG laser (wavelength 2100 nm) is the generation of a gas plasma at the stone-fluid interface causing a shockwave. The holmium laser was employed for lithotripsy of model stones composed of silicate with a ferrous coating. Stones were selected with a mass of 2 mg +/- 0.1 mg. We sequentially investigated three variables: energy (0.6, 0.8, and 1.0 J), frequency (10, 16, and 20 Hz), and fiber diameter (200, 365, 550, and 1000 microm). Ten stone trials were performed with each of the 36 possible combinations of energy, pulse frequency, and fiber diameter. Our model ureter consisted of a clear rigid polymer tube filled with 0.9% saline. The system was closed and permitted intertrial flushing of generated air bubbles. The laser fiber was maintained at constant extension from the ureteroscope, with stones positioned at the fiber tip before each trial. Laser energy was applied for 2 seconds, with maximum and net retropulsion recorded in millimeters. Each measurement series was recorded in a database for paired Student t-tests. Net retropulsion was then compared by statistically holding each of the three variables constant (fiber size constant with power and frequency varying; frequency constant with power and fiber size varying; and power constant with fiber size and frequency varying). Most retropulsion occurred with the 365-microm and 550-microm fibers. Most comminution was also noted with these fiber sizes. There was no statistical correlation between observed retropulsion and efficiency of comminution. This self-contained model for laser lithotripsy

  10. Evaluation of retropulsion caused by holmium:YAG laser with various power settings and fibers.

    PubMed

    White, M D; Moran, M E; Calvano, C J; Borhan-Manesh, A; Mehlhaff, B A

    1998-04-01

    The ideal intracorporeal lithotriper would comminute all types of calculi into small readily excreted particles. It would be small and flexible with an energy source safe for the uroepithelium. It should not break, should be inexpensive, and should not retropulse the stone up the urinary tract. This investigation was designed to quantify the last quality for the holmium:YAG laser. The mechanism of action of the pulsed Ho:YAG laser (wavelength 2100 nm) is the generation of a gas plasma at the stone-fluid interface causing a shockwave. The holmium laser was employed for lithotripsy of model stones composed of silicate with a ferrous coating. Stones were selected with a mass of 2 mg +/- 0.1 mg. We sequentially investigated three variables: energy (0.6, 0.8, and 1.0 J), frequency (10, 16, and 20 Hz), and fiber diameter (200, 365, 550, and 1000 microm). Ten stone trials were performed with each of the 36 possible combinations of energy, pulse frequency, and fiber diameter. Our model ureter consisted of a clear rigid polymer tube filled with 0.9% saline. The system was closed and permitted intertrial flushing of generated air bubbles. The laser fiber was maintained at constant extension from the ureteroscope, with stones positioned at the fiber tip before each trial. Laser energy was applied for 2 seconds, with maximum and net retropulsion recorded in millimeters. Each measurement series was recorded in a database for paired Student t-tests. Net retropulsion was then compared by statistically holding each of the three variables constant (fiber size constant with power and frequency varying; frequency constant with power and fiber size varying; and power constant with fiber size and frequency varying). Most retropulsion occurred with the 365-microm and 550-microm fibers. Most comminution was also noted with these fiber sizes. There was no statistical correlation between observed retropulsion and efficiency of comminution. This self-contained model for laser lithotripsy

  11. Advanced experiments with an erbium-doped fiber laser

    NASA Astrophysics Data System (ADS)

    Marques, Paulo V. S.; Marques, Manuel B.; Rosa, Carla C.

    2014-07-01

    This communication describes an optical hands-on fiber laser experiment aimed at advanced college courses. Optical amplifiers and laser sources represent very important optical devices in numerous applications ranging from telecommunications to medicine. The study of advanced photonics experiments is particularly relevant at undergraduate and master level. This paper discusses the implementation of an optical fiber laser made with a cavity built with two tunable Bragg gratings. This scheme allows the students to understand the laser working principles as a function of the laser cavity set-up. One or both of the gratings can be finely tuned in wavelength through applied stress; therefore, the degree of spectral mismatch of the two gratings can be adjusted, effectively changing the cavity feedback. The impact of the cavity conditions on the laser threshold, spectrum and efficiency is analyzed. This experiment assumes that in a previous practice, the students should had already characterized the erbium doped fiber in terms of absorption and fluorescent spectra, and the spectral gain as a function of pump power.

  12. Refractive index of erbium doped GaN thin films

    SciTech Connect

    Alajlouni, S.; Sun, Z. Y.; Li, J.; Lin, J. Y.; Jiang, H. X.; Zavada, J. M.

    2014-08-25

    GaN is an excellent host for erbium (Er) to provide optical emission in the technologically important as well as eye-safe 1540 nm wavelength window. Er doped GaN (GaN:Er) epilayers were synthesized on c-plane sapphire substrates using metal organic chemical vapor deposition. By employing a pulsed growth scheme, the crystalline quality of GaN:Er epilayers was significantly improved over those obtained by conventional growth method of continuous flow of reaction precursors. X-ray diffraction rocking curve linewidths of less than 300 arc sec were achieved for the GaN (0002) diffraction peak, which is comparable to the typical results of undoped high quality GaN epilayers and represents a major improvement over previously reported results for GaN:Er. Spectroscopic ellipsometry was used to determine the refractive index of the GaN:Er epilayers in the 1540 nm wavelength window and a linear dependence on Er concentration was found. The observed refractive index increase with Er incorporation and the improved crystalline quality of the GaN:Er epilayers indicate that low loss GaN:Er optical waveguiding structures are feasible.

  13. Cavitation bubbles induced by Erbium lasers: implications for dentistry

    NASA Astrophysics Data System (ADS)

    Verleng, Marja; Verdaasdonk, Rudolf; van der Veen, Albert; Lemberg, Vladimir; Boutoussov, Dmitri

    2014-02-01

    With new fiber systems available for 3 μm, Erbium lasers become more interesting for precise tissue ablation in a water environment enabling new application in e.g. dentistry. The dynamics of explosive bubble formation was investigated at 2.78 μm (Er,Cr;YSGG) and 2.94 μm (Er:YAG), in relation to energy (10-50 mJ), pulse length (20-150 μs) and fiber tip shape (flat or taper). The dynamics of exploding and imploding vapor bubbles were captured with high speed imaging (10 - 300 μs range). Increasing the pulse length and energy, the vapor bubble became more elongated with an opaque surface for flat tip fibers. Tapered fibers produced spherical vapor bubbles with an optically transparent surface expected to be more forceful for creating mechanical effects in both hard and soft tissues. There was no significant difference between bubbles formed at 2.78 μm (Er,Cr;YSGG) and 2.94 μm (Er:YAG).

  14. Ablation characteristics of quantum square pulse mode dental erbium laser

    NASA Astrophysics Data System (ADS)

    Lukač, Nejc; Suhovršnik, Tomaž; Lukač, Matjaž; Jezeršek, Matija

    2016-01-01

    Erbium lasers are by now an accepted tool for performing ablative medical procedures, especially when minimal invasiveness is desired. Ideally, a minimally invasive laser cutting procedure should be fast and precise, and with minimal pain and thermal side effects. All these characteristics are significantly influenced by laser pulse duration, albeit not in the same manner. For example, high cutting efficacy and low heat deposition are characteristics of short pulses, while vibrations and ejected debris screening are less pronounced at longer pulse durations. We report on a study of ablation characteristics on dental enamel and cementum, of a chopped-pulse Er:YAG [quantum square pulse (QSP)] mode, which was designed to reduce debris screening during an ablation process. It is shown that in comparison to other studied standard Er:YAG and Er,Cr:YSGG laser pulse duration modes, the QSP mode exhibits the highest ablation drilling efficacy with lowest heat deposition and reduced vibrations, demonstrating that debris screening has a considerable influence on the ablation process. By measuring single-pulse ablation depths, we also show that tissue desiccation during the consecutive delivery of laser pulses leads to a significant reduction of the intrinsic ablation efficacy that cannot be fully restored under clinical settings by rehydrating the tooth using an external water spray.

  15. Clinical application of erbium:YAG laser in periodontology.

    PubMed

    Ishikawa, Isao; Aoki, Akira; Takasaki, Aristeo Atsushi

    2008-01-01

    Various lasers have been introduced for the treatment of oral diseases and their applications in dental clinics have become a topic of much interest among practitioners. Technological advances and improvements have increased the choices of the available laser systems for oral use. Among them, a recently developed erbium-doped:yttrium aluminum garnet (Er:YAG) laser system possesses suitable characteristics for oral soft and hard tissue ablation. Due to its high absorption in water, an effective ablation with a very thin surface interaction occurs on the irradiated tissues without any major thermal damage to the irradiated and surrounding tissues. In the field of periodontics, the application of Er:YAG laser for periodontal hard tissue has begun with studies from Japanese and German researchers. Several in vitro and clinical studies have already demonstrated an effective application of the Er:YAG laser for calculus removal and decontamination of the diseased root surface in periodontal non-surgical and surgical procedures. However, further studies are required to better understand the various effects of Er:YAG laser irradiation on biological tissues for its safe and effective application during periodontal and implant therapy. Randomized controlled clinical trials and more basic studies have to be encouraged and performed to confirm the status of Er:YAG laser treatment as an adjunct or alternative to conventional mechanical periodontal therapy. In this paper, the advantages and current clinical applications of this laser in periodontics and implant dentistry are summarized based on current scientific evidence.

  16. Electroluminescence efficiencies of erbium in silicon-based hosts

    SciTech Connect

    Cueff, Sébastien E-mail: christophe.labbe@ensicaen.fr; Manel Ramírez, Joan; Berencén, Yonder; Garrido, Blas; Kurvits, Jonathan A.; Zia, Rashid; Rizk, Richard; Labbé, Christophe E-mail: christophe.labbe@ensicaen.fr

    2013-11-04

    We report on room-temperature 1.5 μm electroluminescence from trivalent erbium (Er{sup 3+}) ions embedded in three different CMOS-compatible silicon-based hosts: SiO{sub 2}, Si{sub 3}N{sub 4}, and SiN{sub x}. We show that although the insertion of either nitrogen or excess silicon helps enhance electrical conduction and reduce the onset voltage for electroluminescence, it drastically decreases the external quantum efficiency of Er{sup 3+} ions from 2% in SiO{sub 2} to 0.001% and 0.0004% in SiN{sub x} and Si{sub 3}N{sub 4}, respectively. Furthermore, we present strong evidence that hot carrier injection is significantly more efficient than defect-assisted conduction for the electrical excitation of Er{sup 3+} ions. These results suggest strategies to optimize the engineering of on-chip electrically excited silicon-based nanophotonic light sources.

  17. Assignments of the Raman modes of monoclinic erbium oxide

    SciTech Connect

    Yan, D.; Wu, P. Zhang, S. P.; Liang, L.; Yang, F.; Pei, Y. L.; Chen, S.

    2013-11-21

    As a heavy rare earth oxide, erbium oxide (Er{sub 2}O{sub 3}) has many attractive properties. Monoclinic Er{sub 2}O{sub 3} has useful properties not found in stable cubic Er{sub 2}O{sub 3}, such as unique optical properties and high radiation damage tolerance. In this study, cubic Er{sub 2}O{sub 3} coating and Er{sub 2}O{sub 3} coating with mixed phases were prepared. The Raman scattering spectra of these coatings were investigated by using a confocal micro-Raman spectrometer equipped with 325, 473, 514, 532, 633, and 784 nm lasers. A total of 17 first-order Raman modes of monoclinic Er{sub 2}O{sub 3} were identified and assigned. The modes at 83, 112, 152, 170, 278, 290, 409, 446, 478, 521, 603, and 622 cm{sup −1} are of A{sub g} symmetry, whereas modes at 71, 98, 333, 409, 446, and 468 cm{sup −1} are of B{sub g} symmetry. This research provides basic data necessary for the characterization of monoclinic Er{sub 2}O{sub 3} by Raman spectroscopy.

  18. Upconversion in erbium-doped transparent glass ceramics

    NASA Astrophysics Data System (ADS)

    Jones, Gina Christine

    2005-11-01

    Transparent glass ceramics (TGCs) are a class of materials that are composed of a robust glass matrix which is densely embedded with nanometer-sized fluoride crystals: In bulk, fluoride materials tend to have poor handling and mechanical properties, and can be expensive to produce. In contrast, the forming and handling properties of the TGC are similar to those of the precursor, glass, and are engineered to be robust and mechanically stable. Rare earth ions can be incorporated into the TGC during manufacture and can become partially segregated into the crystalline phase. There they experience the low-phonon energy environment of the fluoride nanocrystallite, which induces long energy level lifetimes and enhanced frequency upconversion. Therefore, rare earth doped TGCs can have the spectroscopic properties of a crystal with the durability of an aluminosilicate glass. Upconversion fluorescence is studied for an aluminosilicate TGC containing LaF3 nanocrystallites and doped with an erbium density of 1.7 x 1020 CM-3. Time gated fluorescence and excitation spectra as well as photoluminescence decays are used to find the nature and origin of this fluorescence. It is determined that energy transfer upconversion occurs only in the nanocrystallite phase and sequential two-photon absorption upconversion occurs in both glass and crystal phases.

  19. Photoluminescence in silicon implanted with erbium ions at an elevated temperature

    SciTech Connect

    Sobolev, N. A. Kalyadin, A. E.; Shek, E. I.; Sakharov, V. I.; Serenkov, I. T.; Vdovin, V. I.; Parshin, E. O.; Makoviichuk, M. I.

    2011-08-15

    Photoluminescence spectra of n-type silicon upon implantation with erbium ions at 600 Degree-Sign C and oxygen ions at room temperature and subsequent annealings at 1100 Degree-Sign C in a chlorine-containing atmosphere have been studied. Depending on the annealing duration, photoluminescence spectra at 80 K are dominated by lines of the Er{sup 3+} ion or dislocation-related luminescence. The short-wavelength shift of the dislocation-related luminescence line observed at this temperature is due to implantation of erbium ions at an elevated temperature. At room temperature, lines of erbium and dislocation-related luminescence are observed in the spectra, but lines of near-band-edge luminescence predominate.

  20. Low-temperature growth of silicon epitaxial layers codoped with erbium and oxygen atoms

    SciTech Connect

    Shengurov, D. V.; Chalkov, V. Yu.; Denisov, S. A.; Shengurov, V. G.; Stepikhova, M. V.; Drozdov, M. N.; Krasilnik, Z. F.

    2013-03-15

    The fabrication technology and properties of light-emitting Si structures codoped with erbium and oxygen are reported. The layers are deposited onto (100) Si by molecular beam epitaxy (MBE) using an Er-doped silicon sublimation source. The partial pressure of the oxygen-containing gases in the growth chamber of the MBE facility before layer growth is lower than 5 Multiplication-Sign 10{sup -10} Torr. The oxygen and erbium concentrations in the Si layers grown at 450 Degree-Sign C is {approx}1 Multiplication-Sign 10{sup 19} and 10{sup 18} cm{sup -3}, respectively. The silicon epitaxial layers codoped with erbium and oxygen have high crystal quality and yield effective photoluminescence and electroluminescence signals with the dominant optically active Er-1 center forming upon postgrowth annealing at a temperature of 800 Degree-Sign C.

  1. Enhancement of photoluminescence intensity of erbium doped silica containing Ge nanocrystals: distance dependent interactions

    NASA Astrophysics Data System (ADS)

    Manna, S.; Aluguri, R.; Bar, R.; Das, S.; Prtljaga, N.; Pavesi, L.; Ray, S. K.

    2015-01-01

    Photo-physical processes in Er-doped silica glass matrix containing Ge nanocrystals prepared by the sol-gel method are presented in this article. Strong photoluminescence at 1.54 μm, important for fiber optics telecommunication systems, is observed from the different sol-gel derived glasses at room temperature. We demonstrate that Ge nanocrystals act as strong sensitizers for Er3+ ions emission and the effective Er excitation cross section increases by almost four orders of magnitude with respect to the one without Ge nanocrystals. Rate equations are considered to demonstrate the sensitization of erbium luminescence by Ge nanocrystals. Analyzing the erbium effective excitation cross section, extracted from the flux dependent rise and decay times, a Dexter type of short range energy transfer from a Ge nanocrystal to erbium ion is established.

  2. Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs.

    PubMed

    Bernini, María C; Snejko, Natalia; Gutierrez-Puebla, Enrique; Brusau, Elena V; Narda, Griselda E; Monge, M Ángeles

    2011-07-01

    Two new holmium-succinate frameworks have been synthesized by hydrolysis in situ of the succinylsalicylic acid under different hydrothermal conditions. Compound 1, [Ho(2)(C(4)H(4)O(4))(3)(H(2)O)(2)]·0.33(C(7)H(6)O(3)), P ̅i space group, has a novel structure composed by 1D-SBUs consisting of [HoO(9)] chains of polyhedra linked by the succinate ligands giving a 3D framework. Compound 2, [Ho(2)(C(4)H(4)O(4))(3)(H(2)O)(2)], also belonging to the P ̅i space group, has a denser structure. The role of the in-situ-generated salicylic acid on formation of both structures is studied by means of a synthesis design methodology. A topological study of the new holmium succinate compounds in comparison with the previously reported 3D holmium-succinate framework is performed here.

  3. Optical bistability in erbium-doped yttrium aluminum garnet crystal combined with a laser diode.

    PubMed

    Maeda, Y

    1994-01-10

    Optical bistability was observed in a simple structure of an injection laser diode combined with an erbium-doped yttrium aluminum garnet crystal. Since a hysteresis characteristic exists in the relationship between the wavelength and the injection current of a laser diode, an optical memory function capable of holding the output status is confirmed. In addition, an optical signal inversion was caused by the decrease of transmission of the erbium-doped yttrium aluminum garnet crystal against the red shift (principally mode hopping) of the laser diode. It is suggested that the switching time of this phenomenon is the time necessary for a mode hopping by current injection.

  4. Erbium oxide thin films on Si(100) obtained by laser ablation and electron beam evaporation

    NASA Astrophysics Data System (ADS)

    Queralt, X.; Ferrater, C.; Sánchez, F.; Aguiar, R.; Palau, J.; Varela, M.

    1995-02-01

    Erbium oxide thin films have been obtained by laser ablation and electron beam evaporation techniques on Si(100) substrates. The samples were grown under different conditions of oxygen atmosphere and substrate temperature without any oxidation process after deposition. The crystal structure has been studied by X-ray diffraction. Films obtained by laser ablation are highly textured in the [ hhh] direction, although this depends on the conditions of oxygen pressure and substrate temperature. In order to study the depth composition profile of the thin films and the interdiffusion of erbium metal and oxygen towards the silicon substrates, X-ray photoelectron spectroscopy analyses have been carried out.

  5. Pump absorption and temperature distribution in erbium-doped double-clad fluoride-glass fibers.

    PubMed

    Gorjan, Martin; Marincek, Marko; Copic, Martin

    2009-10-26

    We investigate diode pump absorption and temperature distribution in three erbium-doped double-clad fluoride fibers. Absorption is measured via fluorescence intensity and temperature distribution is measured with thermal imaging. Ray-tracing calculations of absorption and heat-equation modeling of temperature distribution are also conducted. We found excellent agreement between measurements and calculations for all fibers. Results indicate that erbium-doped fluoride fiber lasers have already reached maximum output powers allowed under natural convection cooling, with fiber end being the most critical. We propose cooling and fiber design optimizations that may allow an order-of-magnitude further power-scaling.

  6. Widely tunable erbium-doped fiber laser based on multimode interference effect.

    PubMed

    Castillo-Guzman, A; Antonio-Lopez, J E; Selvas-Aguilar, R; May-Arrioja, D A; Estudillo-Ayala, J; LiKamWa, P

    2010-01-18

    A widely tunable erbium-doped all-fiber laser has been demonstrated. The tunable mechanism is based on a novel tunable filter using multimode interference effects (MMI). The tunable MMI filter was applied to fabricate a tunable erbium-doped fiber laser via a standard ring cavity. A tuning range of 60 nm was obtained, ranging from 1549 nm to 1609 nm, with a signal to noise ratio of 40 dB. The tunable MMI filter mechanism is very simple and inexpensive, but also quite efficient as a wavelength tunable filter.

  7. Influence of erbium doping on phase transition and optical properties of strontium barium niobate

    NASA Astrophysics Data System (ADS)

    Oprea, Isabella-Ioana; Voelker, Uwe; Niemer, Alexander; Pankrath, Rainer; Podlozhenov, Sergey; Betzler, Klaus

    2009-11-01

    The optical properties of erbium impurities in strontium barium niobate are investigated measuring optical absorption and emission in the visible and near infrared spectral region. For the main fluorescence band at 1.55 μm, an anomalous dependence of the fluorescence decay time on dopant concentration is found which, however, can be consistently explained by reabsorption effects. A Judd-Ofelt analysis of the absorption spectra together with an appropriate analysis of the reabsorption yields a radiative quantum efficiency of approximately 60%. In addition, erbium dopants are shown to efficiently influence the phase transition temperature of strontium barium niobate.

  8. Multi-wavelength erbium-doped fiber laser based on random distributed feedback

    NASA Astrophysics Data System (ADS)

    Liu, Yuanyang; Dong, Xinyong; Jiang, Meng; Yu, Xia; Shum, Ping

    2016-09-01

    We experimentally demonstrated a multi-wavelength erbium-doped fiber laser based on random distributed feedback via a 20-km-long single-mode fiber together with a Sagnac loop mirror. The number of channels can be modulated from 2 to 8 at room temperature when the pump power is changed from 30 to 180 mW, indicating that wavelength competition caused by homogenous gain broadening of erbium-doped fiber is significantly suppressed. Other advantages of the laser include low cost, low-threshold pump power and simple fabrication.

  9. Infrared luminescence from spark-processed silicon and erbium-doped spark-processed silicon

    NASA Astrophysics Data System (ADS)

    Kim, Kwanghoon

    Spark-processed silicon has substantial potential as an optical material. In the past 15 years, our group has investigated a multitude of properties of this unique material, concentrating mostly on the visible and near UV spectral region. The present study expands our endeavors to infrared photoluminescence (PL) of undoped spark-processed silicon. A broad infrared photoluminescence peak at around 945 nm under Ar ion laser excitation was observed at room temperature when investigating a spark-processed layer on a silicon wafer. This light emission is interpreted to be the result of energy transfers between certain energy levels involving the spark-processed silicon matrix. The infrared PL intensity of spark-processed silicon was found to be proportional to the excitation energy. However, telecommunication requires presently a light emission near 1.54 mum (because fiber-optics "conductors" have a minimum in absorption at this wavelength). This cannot be achieved with pure spark-processed silicon. Therefore spark-processed silicon needs to be doped with a rare-earth element such as erbium to shift the emission to longer wavelengths. It is known that erbium has a light emission from intrashell energy transition, that is, from 4I13/2 →4I15/2. Erbium was deposited on a silicon wafer followed by spark-processing, which enables diffusion of some erbium into the SiOx matrix, thus achieving opto-electronically active spark-processed silicon. Rapid thermal annealing enhances the 1.54 mum wavelength intensity from erbium-doped spark-processed silicon. The processing conditions that result in the most efficient photoluminescence have been established and will be presented in this dissertation. In contrast to erbium-doped crystalline silicon, whose light emission is highly affected by temperature (103 times reduction in intensity when heating from 12 K to 150 K), the intensity of erbium-doped spark-processed silicon decreases by only a factor of 4 when heated from 15 K to room

  10. Nanostructuring an erbium local environment inside sol-gel silica glasses: toward efficient erbium optical fiber lasers

    NASA Astrophysics Data System (ADS)

    Savelii, Inna; El Hamzaoui, Hicham; Bigot, Laurent; Bouwmans, Géraud; Fsaifes, Ihsan; Capoen, Bruno; Bouazaoui, Mohamed

    2016-02-01

    To extend the use of erbium- (Er-)/aluminum- (Al-) codoped optical fibers in hostile environments, the reduction of the Al amount has been identified as a serious way to harden them against harsh radiation. In this work, sol-gel monolithic Er3+-doped and Er3+/Al3+-codoped silica glasses were prepared from nanoporous silica xerogels soaked in a solution containing an Er salt together or not with an Al salt. After sintering, these glasses were used as the core material of microstructured optical fibers made by the stack-and-draw method. The influence of Al incorporation on the optical properties of Er3+-doped silica glasses and fibers is investigated. This approach enabled the preparation of silica glasses containing dispersed Er3+ ions with low Al content. The obtained fibers have been tested in an all-fibered cavity laser architecture. The Er3+/Al3+-codoped fiber laser presents a maximum efficiency of 27% at 1530 nm. We show that without Al doping, the laser exhibits lower performances that depend on Er content inside the doped fiber core. The effect of Er pair-induced quenching also has been investigated through nonsaturable absorption experiments, which clearly indicate that the fraction of Er ion pairs is significantly reduced in the Al-codoped fiber.

  11. Changes in corneal collagen induced by holmium:YAG laser irradiation

    NASA Astrophysics Data System (ADS)

    Timberlake, George T.; Reinke, Martin H.; Miller, Alvin

    1996-05-01

    Holmium:YAG laser thermokeratoplasty corrects hyperopia (farsightedness) by producing small areas of corneal collagen shrinkage that cause the central cornea to bulge outward, increasing optical power. Collagen shrinkage is probably caused by laser-heated corneal water, but details of the shrinkage mechanism are not known. We investigated the shrinkage mechanism by measuring changes in corneal ultrastructure, surface shrinkage, water content, and strength following Ho:YAG laser exposures. Morphological changes in collagen were documented by measurements from electron micrographs. Corneal adhesive strength was determined by measuring tearing force in a plane parallel to the corneal surface. Laser-induced water loss was measured by weighing corneal samples before and after exposure. Corneal surface shrinkage was assessed by photographing the movement of particles on the cornea. Lasered collagen fibrils increased in diameter, lost their orderly arrangement, and appeared `frayed.' The corneal surface contracted toward lasered areas with a maximal shift of approximately 190 micrometers , more than could be explained by a model based on collagen fibril changes. Water loss plays a minor role in corneal shrinkage since corneal samples lost about only about 1.4% of their weight after massive laser exposure. Despite marked changes in collagen structure, corneal adhesive force was unchanged.

  12. Effectiveness and Safety of Ureteroscopic Holmium Laser Lithotripsy for Upper Urinary Tract Calculi in Elderly Patients.

    PubMed

    Yoshioka, Takashi; Otsuki, Hideo; Uehara, Shinya; Shimizu, Toshihiro; Murao, Wataru; Fujio, Koji; Fujio, Kei; Wada, Koichiro; Araki, Motoo; Nasu, Yasutomo

    2016-06-01

    Upper urinary tract calculi are common; however, there is no recommended treatment selection for elderly patients. Ureteroscopic holmium laser lithotripsy (URS lithotripsy) is minimally invasive, and it provides a high stone-free rate (SFR) treatment for upper urinary tract calculi. Here, we retrospectively evaluated the surgical outcomes of URS lithotripsy after dividing the 189 cases into 3 groups by patient age: the '<65 group' (<65 years old, n=108), the '65-74 group' (65-74 years old, n=42), and the ' 75 group' ( 75 years old, n=39). The patients' characteristics, stone status, and perioperative outcomes were assessed. The 65-74 group and the 75 group had a significantly higher prevalence of hypertension compared to the<65 group. Compared to the<65 group, the 65-74 group had a significantly higher prevalence of hyperlipidemia, and the 75 group had significantly higher the American Society of Anesthesiologists (ASA) scores. Despite these preoperative risk factors, SFR and postoperative pyelonephritis in the 65-74 group and the 75 group were similar to those of the<65 group. In conclusion, URS lithotripsy is the preferred treatment for upper urinary tract calculi, even for elderly patients who have multiple preoperative risk factors. PMID:27339204

  13. Laboratory investigation of the efficacy of holmium:YAG laser irradiation in removing intracanal debris

    NASA Astrophysics Data System (ADS)

    Nuebler-Moritz, Michael; Gutknecht, Norbert; Sailer, Hermann F.; Hering, Peter; Prettl, Wilhelm

    1997-05-01

    Current endodontic therapy involves debridement and disinfection of the root canal by means of mechanical instrumentation and chemical irrigation. However, several studies have shown that these techniques fail to achieve complete cleansing. Recently, lasers have been suggested for use within root canals. This study was conducted to determine the efficacy of Holmium:YAG laser irradiation in removing intracanal debris and smear layer. Root canal surfaces of freshly-extracted human teeth were exposed to pulsed Ho:YAG laser radiation. Subsequently, laser induced structural changes were investigated using scanning electron microscopy. Temperature measurements during irradiation were performed by means of thermocouples. The result of this survey give a preliminary indication of the ability of the Ho:YAG laser to improve current endodontic treatment survey give a preliminary indication of the ability of the Ho:YAG laser to improve current endodontic treatment modalities. However, limitations exist with regard to circumscribed and well-quantified irradiation of root canal surfaces, due to the lack of perpendicular delivery of the laser beam. Additional studies will be required to develop suitable optical transmission systems, in order to achieve complete cleansing and to avoid damage to the periradicular tissues, respectively.

  14. Kidney stone ablation times and peak saline temperatures during Holmium:YAG and Thulium fiber laser lithotripsy, in vitro, in a ureteral model

    NASA Astrophysics Data System (ADS)

    Hardy, Luke A.; Wilson, Christopher R.; Irby, Pierce B.; Fried, Nathaniel M.

    2015-02-01

    Using a validated in vitro ureter model for laser lithotripsy, the performance of an experimental Thulium fiber laser (TFL) was studied and compared to clinical gold standard Holmium:YAG laser. The Holmium laser (λ = 2120 nm) was operated with standard parameters of 600 mJ, 350 μs, 6 Hz, and 270-μm-core optical fiber. TFL (λ = 1908 nm) was operated with 35 mJ, 500 μs, 150-500 Hz, and 100-μm-core fiber. Urinary stones (60% calcium oxalate monohydrate / 40% calcium phosphate), of uniform mass and diameter (4-5 mm) were laser ablated with fibers through a flexible video-ureteroscope under saline irrigation with flow rates of 22.7 ml/min and 13.7 ml/min for the TFL and Holmium laser, respectively. The temperature 3 mm from tube's center and 1 mm above mesh sieve was measured by a thermocouple and recorded during experiments. Total laser and operation times were recorded once all stone fragments passed through a 1.5-mm sieve. Holmium laser time measured 167 +/- 41 s (n = 12). TFL times measured 111 +/- 49 s, 39 +/- 11 s, and 23 +/- 4 s, for pulse rates of 150, 300, and 500 Hz (n = 12 each). Mean peak saline irrigation temperatures reached 24 +/- 1 °C for Holmium, and 33 +/- 3 °C, 33 +/- 7 °C, and 39 +/- 6 °C, for TFL at pulse rates of 150, 300, and 500 Hz. To avoid thermal buildup and provide a sufficient safety margin, TFL lithotripsy should be performed with pulse rates below 500 Hz and/or increased saline irrigation rates. The TFL rapidly fragmented kidney stones due in part to its high pulse rate, high power density, high average power, and reduced stone retropulsion, and may provide a clinical alternative to the conventional Holmium laser for lithotripsy.

  15. Amphoteric doping of praseodymium Pr3+ in SrTiO3 grain boundaries

    SciTech Connect

    Yang, H.; Lee, H. S.; Kotula, P. G.; Sato, Y.; Ikuhara, Y.; Browning, N. D.

    2015-03-26

    Charge Compensation in rare-earth Praseodymium (Pr3+) doped SrTiO3 plays an important role in determining the overall photoluminescence properties of the system. Here, the Pr3+ doping behavior in SrTiO3 grain boundaries (GBs) is analyzed using aberration corrected scanning transmission electron microscopy (STEM). The presence of Pr3+ induces structure variations and changes the statistical prevalence of GB structures. In contrast to the assumption that Pr3+ substitutes for A site as expected in the bulk, Pr3+ is found to substitute both Sr and Ti sites inside GBs with the highest concentration in the Ti sites. As a result, this amphoteric doping behavior in the boundary plane is further confirmed by first principles theoretical calculations.

  16. Study on fluorescence and DNA-binding of praseodymium(III) complex containing 2,2'-bipyridine.

    PubMed

    Khorasani-Motlagh, Mozhgan; Noroozifar, Meissam; Khmmarnia, Sommaieh

    2011-01-01

    The fluorescence of praseodymium(III) complex containing 2,2'-bipyridine, [Pr(bpy)2Cl3·OH2] has been investigated in details. Also, the biological activity of [Pr(bpy)2Cl3·OH2] has been evaluated by examining its ability to bind to DNA with UV-vis, fluorescence as well as viscosity measurement. The fluorescence of [Pr(bpy)2Cl3·OH2] is strongly quenched through static mechanism in the presence of DNA. DNA intrinsic binding constant, Kb the binding site number, n the Stern-Volmer quenching constant, KSV and the thermodynamic parameters have been determined by fluorescence spectroscopy. For characterization of bonding mode, the effect of various experimental parameters were investigated on the interaction of [Pr(bpy)2Cl3·OH2] with DNA.

  17. Amphoteric doping of praseodymium Pr{sup 3+} in SrTiO{sub 3} grain boundaries

    SciTech Connect

    Yang, H.; Lee, H. S.; Kotula, P. G.; Sato, Y.; Ikuhara, Y.; Browning, N. D.

    2015-03-23

    Charge compensation in rare-earth Praseodymium (Pr{sup 3+}) doped SrTiO{sub 3} plays an important role in determining the overall photoluminescence properties of the system. Here, the Pr{sup 3+} doping behavior in SrTiO{sub 3} grain boundaries (GBs) is analyzed using aberration corrected scanning transmission electron microscopy. The presence of Pr{sup 3+} induces structural variations and changes the statistical prevalence of the GB structures. In contrast to the assumption that Pr{sup 3+} substitutes on the Sr site in the bulk, Pr{sup 3+} is found to substitute on both Sr and Ti sites inside the GBs, with the highest concentration at the Ti sites. This amphoteric doping behavior in the boundary plane is further confirmed by first principles theoretical calculations.

  18. Non-destructive analysis of didymium and praseodymium molybdate crystals using energy dispersive X-ray fluorescence technique

    NASA Astrophysics Data System (ADS)

    Bhat, C. K.; Joseph, Daisy; Pandita, Sanjay; Kotru, P. N.

    2016-08-01

    Analysis of didymium (Di) and praseodymium molybdate crystals were carried out using energy dispersive X-ray fluorescence (EDXRF). The assigned empirical chemical formulae of the composites were tested and verified by the EDXRF technique by estimating experimental major elemental concentration ratios. On the Basis of these ratios, the established formulae for some of the composite materials have been verified and suggestions made for their refinement. Non-destructive technique used in this analysis enables to retain the original crystal samples and makes rapid simultaneous scan of major elements such as La, Pr, Ned and Mo as well as impurities such as Ce. Absence of samarium(Sm) in the spectrum during analysis of didymium molybdate crystals indicated an incomplete growth of mixed rare earth single crystal. These crystals (e.g.,Di) are shown to be of modified stoichiometry with Ce as trace impurity.

  19. Growth studies of erbium-doped GaAs deposited by metalorganic vapor phase epitaxy using noval cyclopentadienyl-based erbium sources

    NASA Technical Reports Server (NTRS)

    Redwing, J. M.; Kuech, T. F.; Gordon, D. C.; Vaartstra, B. A.; Lau, S. S.

    1994-01-01

    Erbium-doped GaAS layers were grown by metalorganic vapor phase epitaxy using two new sources, bis(i-propylcyclopentadienyl)cyclopentadienyl erbium and tris(t-butylcyclopentadienyl) erbium. Controlled Er doping in the range of 10(exp 17) - 10(exp 18)/cu cm was achieved using a relatively low source temperature of 90 C. The doping exhibits a second-order dependence on inlet source partial pressure, similar to behavior obtained with cyclopentadienyl Mg dopant sources. Equivalent amounts of oxygen and Er are present in 'as-grown' films indicating that the majority of Er dopants probably exist as Er-O complexes in the material. Er(+3) luminescence at 1.54 micrometers was measured from the as-grown films, but ion implantation of additional oxygen decreases the emission intensity. Electrical compensation of n-type GaAs layers codoped with Er and Si is directly correlated to the Er concentration is proposed to arise from the deep centers associated with Er which are responsible for a broad emission band near 0.90 micrometers present in the photoluminescence spectra of GaAs:Si, Er films.

  20. Bipolar, Monopolar, Photovaporization of the Prostate, or Holmium Laser Enucleation of the Prostate: How to Choose What's Best?

    PubMed

    Cornu, Jean-Nicolas

    2016-08-01

    Endoscopic management of benign prostatic obstruction is based on resection, vaporization, or enucleation. Enucleation provides the best efficacy and long-term outcome. Lasers have advantages in patients at high risk of bleeding. Holmium enucleation is the best evaluated technique, but has a steep learning curve. Greenlight photovaporization is a safe alternative to transurethral resection of the prostate (TURP) in prostates of less than 100 mL, especially in patients at high risk of bleeding. Bipolar devices can be used for resection, vaporization, and enucleation and provides efficacy results similar to TURP in the short term with better safety. PMID:27476130

  1. Hybrid method of transurethral resection of ejaculatory ducts using holmium:yttriumaluminium garnet laser on complete ejaculatory duct obstruction.

    PubMed

    Lee, Joo Yong; Diaz, Richilda Red; Choi, Young Deuk; Cho, Kang Su

    2013-07-01

    A 32-year old single man presented with azoospermia and low semen volume which was noted one and half a year ago. Transrectal ultrasonography and seminal vesiculography were performed to evaluate ejaculatory duct obstruction, and transurethral resection of the ejaculatory duct was performed using a hybrid technique of holmium:yttriumaluminium garnet laser with monopolar transurethral resection to overcome the narrow prostatic urethra. To our knowledge, this is the first report on the successful outcome of a hybrid technique applied for transurethral resection of the ejaculatory duct.

  2. Novel Thermal Effects at the First Order Magnetic Phase Transition in Erbium, and a Comparison with Dysprosium

    SciTech Connect

    Gschneidner, K.A. Jr.; Pecharsky, V.K.; Fort, D.

    1997-06-01

    In low temperature studies of ultrapure erbium (and dysprosium) we have discovered unusual thermal effects at the first order magnetic transformation of erbium ({congruent} 19K). These include (1)superheating (i.e., {ital the metal is colder after heat has been added to it than before the heat pulse }), (2)supercooling, and (3)the existence of metastable intermediate phases during this phase transformation in erbium (four on heating and two on cooling). In comparison, dysprosium exhibits both superheating and supercooling, but no intermediate metastable phases are observed. Furthermore, none of these effects are observed in less pure metals. {copyright} {ital 1997} {ital The American Physical Society}

  3. Microwave photonic filter using multiwavelength Brillouin-erbium fiber laser with double-Brillouin-frequency shift

    SciTech Connect

    Loh, K. K.; Yeo, K. S.; Shee, Y. G.

    2015-04-24

    A microwave photonic filter based on double-Brillouin-frequency spaced multiwavelength Brillouin-erbium fiber laser (BEFL) is experimentally demonstrated. The filter selectivity can be easily adjusted by tuning and apodizing the optical taps generated from the multiwavelength BEFL. Reconfiguration of different frequency responses are demonstrated.

  4. Ultrasonic approach for formation of erbium oxide nanoparticles with variable geometries.

    PubMed

    Radziuk, Darya; Skirtach, André; Gessner, Andre; Kumke, Michael U; Zhang, Wei; Möhwald, Helmuth; Shchukin, Dmitry

    2011-12-01

    Ultrasound (20 kHz, 29 W·cm(-2)) is employed to form three types of erbium oxide nanoparticles in the presence of multiwalled carbon nanotubes as a template material in water. The nanoparticles are (i) erbium carboxioxide nanoparticles deposited on the external walls of multiwalled carbon nanotubes and Er(2)O(3) in the bulk with (ii) hexagonal and (iii) spherical geometries. Each type of ultrasonically formed nanoparticle reveals Er(3+) photoluminescence from crystal lattice. The main advantage of the erbium carboxioxide nanoparticles on the carbon nanotubes is the electromagnetic emission in the visible region, which is new and not examined up to the present date. On the other hand, the photoluminescence of hexagonal erbium oxide nanoparticles is long-lived (μs) and enables the higher energy transition ((4)S(3/2)-(4)I(15/2)), which is not observed for spherical nanoparticles. Our work is unique because it combines for the first time spectroscopy of Er(3+) electronic transitions in the host crystal lattices of nanoparticles with the geometry established by ultrasound in aqueous solution of carbon nanotubes employed as a template material. The work can be of great interest for "green" chemistry synthesis of photoluminescent nanoparticles in water.

  5. Performance of a High-Concentration Erbium-Doped Fiber Amplifier with 100 nm Amplification Bandwidth

    SciTech Connect

    Hajireza, P.; Shahabuddin, N. S.; Abbasi-Zargaleh, S.; Emami, S. D.; Abdul-Rashid, H. A.; Yusoff, Z.

    2010-07-07

    Increasing demand for higher bandwidth has driven the need for higher Wavelength Division Multiplexing (WDM) channels. One of the requirements to achieve this is a broadband amplifier. This paper reports the performance of a broadband, compact, high-concentration and silica-based erbium-doped fiber amplifier. The amplifier optimized to a 2.15 m long erbium-doped fiber with erbium ion concentration of 2000 ppm. The gain spectrum of the amplifier has a measured amplification bandwidth of 100 nm using a 980 nm laser diode with power of 150 mW. This silica-based EDFA shows lower noise figure, higher gain and wider bandwidth in shorter wavelengths compared to Bismuth-based EDFA with higher erbium ion concentration of 3250 ppm at equivalent EDF length. The silica-based EDF shows peak gain at 22 dB and amplification bandwidth between 1520 nm and 1620 nm. The lowest noise figure is 5 dB. The gain is further improved with the implementation of enhanced EDFA configurations.

  6. Perfluorinated nitrosopyrazolone-based erbium chelates: a new efficient solution processable NIR emitter.

    PubMed

    Beverina, Luca; Crippa, Maurizio; Sassi, Mauro; Monguzzi, Angelo; Meinardi, Francesco; Tubino, Riccardo; Pagani, Giorgio A

    2009-09-14

    We show the design and synthesis of new perfluorinated nitrosopyrazolone-based ligands and the original method employed for their complexation of erbium ions in the presence of the co-ligand perfluorotriphenylphosphine oxide; the resulting chelate is non-hygroscopic, solution processable and possesses a NIR emission with lifetimes as long as 16 micros.

  7. Quenching investigation on new erbium doped fibers using MCVD nanoparticle doping process

    NASA Astrophysics Data System (ADS)

    Boivin, David; Föhn, Thomas; Burov, Ekaterina; Pastouret, Alain; Gonnet, Cédric; Cavani, Olivier; Collet, Christine; Lempereur, Simon

    2010-02-01

    Ever demanding network implementations brought new requirements to be addressed to offer cost effective and power efficient solutions with smaller footprints. This general trend together with the constant need to improve L-band optical amplification efficiency account for the renewed interest on highly doped Erbium fibers. Erbium doped fiber amplifiers (EDFAs) performance degradation with Er3+ concentration increase has extensively been studied1 and is attributed to additional losses due to energy transfers between neighbouring ions. Experimental observations have been interpreted by the homogeneous up-conversion (HUC) and pair-induced quenching (PIQ) models, which account for pump power penalty and unsaturable absorption respectively. For a given Er3+ concentration, studies have also showed that both fiber manufacturing process and core matrix composition have a strong impact on quenching parameters. In 2009, we introduced a new doping concept involving Al2O3Er nanoparticles (NP) in a MCVD-compatible process showing improved performances in terms of erbium homogeneity along the fiber length for standard doping levels.2 In this paper, we address our most recent work on concentration quenching encountered in both standard and NP Erbium doped fibers.

  8. A review of technology and safety aspects of erbium lasers in dentistry.

    PubMed

    Clarkson, D M

    2001-01-01

    This article reviews aspects of the probable mechanisms used by erbium dental lasers for cutting dentine and enamel, describes key issues of the risk of temperature elevation and speed of cutting relative to conventional techniques and looks at issues concerned with the safety of lasers.

  9. Results of a retrospective single institution analysis of targeted skeletal radiotherapy with (166)Holmium-DOTMP as conditioning regimen for autologous stem cell transplant for patients with multiple myeloma. Impact on transplant outcomes.

    PubMed

    Christoforidou, Anna V; Saliba, Rima M; Williams, Patricia; Qazilbash, Muzaffar; Roden, Linda; Aleman, Ana; Weber, Donna; Mendoza, Floralyn; Podoloff, Donald; Wendt, Richard; Breitz, Hazel; Alexanian, Raymond; Champlin, Richard; Giralt, Sergio

    2007-05-01

    (166)Holmium-DOTMP is a beta-emitting radiophosphonate that localizes specifically to the bone surfaces and can deliver high-dose radiation to the bone marrow. Phase I/II trials showed feasibility and tolerability when combined with high-dose melphalan with or without total-body irradiation (TBI) in patients with multiple myeloma (MM) undergoing autologous stem cell transplantation (ASCT). The purpose of this study was to define the potential impact of (166)Holmium-DOTMP on outcomes in patients with MM undergoing ASCT. Retrospective review of transplant outcomes among patients with MM who received an ASCT between January 1998 to December 2001 with either melphalan 200 mg/m(2) or a (166)Holmium-DOTMP containing regimen as part of their initial therapy. Univariate analysis was performed for response, overall survival (OS), and event free survival (EFS). One hundred four patients were identified, of which 41 received a (166)Holmium-DOTMP containing regimen and 63 received melphalan alone. The (166)Holmium-DOTMP patients were divided into 2 groups according to the dose received (<2400 mCi versus > or = 2400 mCi). The (166)Holmium-DOTMP group had a trend towards a higher complete remission (CR) rate compared to patients receiving melphalan alone (51% versus 32%). The median EFS for the low-dose (166)Holmium-DOTMP, the high-dose (166)Holmium-DOTMP, and melphalan alone was 30, 23, and 19 months, respectively; the OS rate at 5 years for the 3 groups was 61%, 40%, and 43%, respectively. (166)Holmium-DOTMP, in combination with high-dose melphalan, can result in higher CR rates when given in optimal doses (<2400 mCi) when compared to melphalan alone, and should be further tested in phase III trials in patients with MM undergoing ASCT.

  10. Erythrocyte alterations in praseodymium-induced lecithin:cholesterol acyltransferase (LCAT) deficiency in the rat: comparison with familial LCAT deficiency in man.

    PubMed

    Godin, D V; Frohlich, J

    1981-03-01

    The intravenous administration of praseodymium nitrate (PrN) to rats was associated with parallel decreases in plasma lecithin: cholesterol acyltransferase (LCAT) activity and erythrocyte osmotic fragility at low doses (20 and 40 mg/kg) while higher doses (80 mg/kg) resulted in increases in both. Erythrocyte membranes from rats with PrN-induced LCAT deficiency exhibited small increases in cholesterol content, but not other alterations (e.g., in phospholipid profiles and sulfhydryl group latency) which characterize erythrocytes in familial LCAT deficiency in man. The administration of PrN caused a time- and dose-dependent accumulation of praseodymium in liver with hepatic levels being substantially greater in animals given the high (protective) as compared with the low (toxic) doses of PrN. Hepatic levels of glutathione were not altered by PrN administration, but hexobarbital sleeping time was markedly prolonged in animals receiving a toxic dose of PrN. It is suggested that dose-dependent alterations in the subcellular distribution of praseodymium may explain the paradoxical pathophysiological effects of high and low doses of PrN.

  11. Crystal structure of new complexes of praseodymium(III) nitrate and ytterbium(III) nitrate with 2,2': 6,2''-terpyridine

    SciTech Connect

    Charushnikova, I. A. Auwer, C. Den

    2006-12-15

    The crystal structure of new complexes of praseodymium(III) and ytterbium(III) (elements from the initial and final parts of the lanthanide series), namely, [Pr(NO{sub 3}){sub 3} (Terpy)((CH{sub 3}){sub 2}CO)] (I) and [Yb(NO{sub 3}){sub 2}(Terpy)(H{sub 2}O){sub 2}]NO{sub 3} . 2H{sub 2}O (II), is investigated. The structure of compound I consists of [Pr(NO{sub 3}){sub 3}(Terpy)((CH{sub 3}){sub 2}CO)] neutral complexes. The coordination number of the praseodymium atom is 10. The coordination polyhedron of the praseodymium atom can be described as a distorted bicapped tetragonal antiprism. The structure of compound II is composed of [Yb(NO{sub 3}){sub 2}(Terpy)(H{sub 2}O){sub 2}]{sup +} cationic complexes, nitrate anions, and molecules of crystallization water. The structural components are joined together via a three-dimensional system of hydrogen bonds. The coordination polyhedron of the ytterbium atom can be represented as a distorted tricapped trigonal prism. The coordination number of the ytterbium atom is 9.

  12. A dual-wavelength erbium-doped fiber laser based on fiber grating pair

    NASA Astrophysics Data System (ADS)

    Sun, Hongwei; Wang, Tianshu; Jia, Qingsong; Zhang, Peng; Jiang, Huilin

    2014-12-01

    A dual-wavelength linear cavity erbium-doped fiber (EDF) laser based on a fiber grating pair is demonstrated experimentally. A circulator, a 980nm/1550nm wavelength division multiplexing (WDM) coupler, a 1×2 coupler, a polarization controller, a 6m long erbium-doped fiber and a fiber grating pair for wavelength interval of 0.3nm are included in the structure. A circulator connected at two ports as reflecting mirror structure. A 980nm pump source pump an erbium-doped fiber with a length of 6m consist of an erbium doped fiber amplifier. Through adjusting the state of the polarization controller, the transmission characteristic of cavity is changed. In both polarization and wavelength, the feedback from the fiber grating pair results in the laser operating on two longitudinal modes that are separated. The birefringence induced by the fiber grating pair is beneficial to diversify the polarization states of different wavelength in the erbium-doped fiber. So it is enhanced the polarization hole burning effect. This polarization hole burning effect greatly reduced the wavelength competition. Then, it was possible to achieve stable dual-wavelength. It turns out the structure generated the stable dual-wavelength with the 0.3nm wavelength interval and the output power is 0.13dBm in the end. The whole system have a simple and compact structure, it can work stably and laid a foundation for microwave/millimeter wave generator. It has a good application performance in the future for scientific research and daily life.

  13. Analysis of lapine cartilage matrix after radiosynovectomy with holmium-166 ferric hydroxide macroaggregate

    PubMed Central

    Makela, O; Lammi, M; Uusitalo, H; Hyttinen, M; Vuorio, E; Helminen, H; Tulamo, R

    2003-01-01

    Objective: To study the short and long term effects of radiosynovectomy on articular cartilage in growing and mature rabbits. Methods: The articular cartilage of the distal femurs of rabbits was examined four days, two months, and one year after radiosynovectomy with holmium-166 ferric hydroxide macroaggregate ([166Ho]FHMA). Arthritic changes were evaluated from histological sections by conventional and polarised light microscopy, and glycosaminoglycan measurements using safranin O staining, digital densitometry, and uronic acid determination. Proteoglycan synthesis was studied by metabolic [35]sulphate labelling followed by autoradiography, and electrophoretic analysis of extracted proteoglycans. Northern analyses were performed to determine the mRNA levels of type II collagen, aggrecan, and Sox9 in cartilage samples. Results: Radiosynovectomy had no major effect on the histological appearance of articular cartilage in mature rabbits, whereas more fibrillation was seen in [166Ho]FHMA radiosynovectomised knee joints of growing rabbits two months after treatment, but not after one year. Radiosynovectomy did not cause changes in the glycosaminoglycan content of cartilage or in the synthesis or chemical structure of proteoglycans. No radiosynovectomy related changes were seen in the mRNA levels of type II collagen, whereas a transient down regulation of aggrecan and Sox9 mRNA levels was seen in young rabbits two months after [166Ho]FHMA radiosynovectomy. Conclusions: [166Ho]FHMA radiosynovectomy caused no obvious chondrocyte damage or osteoarthritic changes in mature rabbits, but in growing rabbits some transient radiation induced effects were seen—for example, mild cartilage fibrillation and down regulation of cartilage-specific genes. PMID:12480668

  14. Effects of Intraluminal Irradiation with Holmium-166 for TIPS Stenosis: Experimental Study in a Swine Model

    PubMed Central

    Park, Ji Seon; Kim, Deog Yoon; Park, Yong Koo; Park, Sang Joon; Kim, Soo Joong

    2007-01-01

    Objective We wanted to evaluate the effectiveness of intraluminal irradiation with Holmium-166 (166Ho) for reducing the pseudointimal hyperplasia (PIH) in the transjugular intrahepatic portosystemic shunt (TIPS) tract in a swine model. Materials and Methods TIPS was performed in 12 domestic pigs, after the creation of portal hypertension by intraportal injection of a mixture of N-butyl-2-cyanoacrylate (NBCA) and lipiodol. Five pigs first underwent intraluminal irradiation (30 Gy) in the parenchymal tract with using a 166Ho solution-filled balloon catheter, and this was followed by the placement of a nitinol stent in the TIPS tract. For the seven control pigs, the balloon was filled with saline and contrast media mixture. Two weeks later, follow-up portography and histological analysis were performed. Results TIPS was successfully performed in all twelve pigs with achieving artificially induced portal hypertension. Portography performed two weeks after TIPS showed the patent tracts in the TIPS tracts that were irradiated with 166Ho (5/5, 100%), whereas either completely (5/6, 83.3%) or partially (1/6, 16.7%) occluded TIPS were seen in the seven pigs of the nonirradiated control group, except in one pig that experienced periprocedural death due to bleeding. Histological analysis showed a statistically significant difference for the maximal PIH (irradiated: 32.8%, nonirradiated: 76.0%, p < 0.001) between the two groups. Conclusion Intraluminal irradiation with 30 Gy of 166Ho for TIPS significantly improved the TIPS patency in a swine model of portal hypertension during a 2-week period of follow-up. PMID:17420630

  15. Enhanced magnetization with unusual low temperature magnetic ordering behaviour and spin reorientation in holmium-modified multiferroic BiFeO3 perovskite ceramics

    NASA Astrophysics Data System (ADS)

    Singh, Hemant; Yadav, K. L.

    2015-05-01

    Holmium-doped Bi1-xHoxFeO3 (x = 0, 0.025, 0.05, 0.075 and 0.10) perovskite ceramics were synthesized by a rapid liquid phase quenching process. The structural analysis performed using x-ray diffraction suggested phase formation with distorted rhombohedral structure in all the synthesized ceramic samples. Rietveld analysis of x-ray diffraction patterns and Raman spectroscopy also confirmed the distorted perovskite structure with R3c symmetry. Optical studies showed characteristic bending vibrations of O - Fe - O, Fe - O stretching and visible range PL emissions in modified BiFeO3 ceramics. Ferromagnetic characteristics were shown by all the holmium-doped samples at room temperature and 5 K. Very high saturation magnetization (at 7 T), four to six times higher at 5 K than at 300 K, is observed for holmium-doped ceramic samples. A complex temperature dependence of magnetization behaviour is observed for holmium-doped samples, which is indicative of a spin reorientation in doped ceramics.

  16. Comparison of the erbium-yttrium aluminum garnet and carbon dioxide lasers for in vitro bone and cartilage ablation

    SciTech Connect

    Gonzalez, C.; van de Merwe, W.P.; Smith, M.; Reinisch, L. )

    1990-01-01

    The in vitro bone- and cartilage-ablation characteristics of the solid-state erbium:yttrium aluminum garnet laser were compared to those of the carbon dioxide laser. Ablations of fresh, frozen cadaver septal cartilage and maxillary sinus bone were performed using total energies between 1 and 6 J. Specimens were studied using hematoxylin and eosin stain and digitized, computer-assisted measurements of 35-mm photographs. Erbium-yttrium aluminum garnet-ablated bone averaged 5 microns of adjacent tissue thermal injury, compared with 67 microns with carbon dioxide-ablated bone. Erbium-yttrium aluminum garnet-ablated cartilage averaged 2 microns of adjacent tissue thermal injury, compared with 21 microns with the carbon dioxide-ablated cartilage. The tissue-ablation characteristics of the erbium-yttrium aluminum garnet laser are promising for future otolaryngologic applications.

  17. Gamma spectrometry and chemical characterization of ceramic seeds with samarium-153 and holmium-166 for brachytherapy proposal.

    PubMed

    Valente, Eduardo S; Campos, Tarcísio P R

    2010-12-01

    Ceramic seeds were synthesized by the sol-gel technique with Si:Sm:Ca and Si:Ho:Ca. One set of seeds was irradiated in the TRIGA type nuclear reactor IPR-R1 and submitted to instrumental neutron activation analysis (INAA), K(0) method, to determine mass percentage concentration of natural samarium and holmium in the seed as well as to determine all existing radionuclides and their activities. Attention was paid to discrimination of Si-31, Ca-40, Ca-45, Ca-47, Ca-49, Sm-145, Sm-155, Sm-153 and Ho-166. A second sample was submitted to atomic emission spectrometry (ICP-AES) also to determine samarium and holmium concentrations in weight. A third sample was submitted to X-ray fluorescence spectrometry to qualitatively determine chemical composition. The measured activity was due to Sm-153 and Ho-166 with a well-characterized gamma spectrum. The X-ray fluorescence spectrum demonstrated that there is no discrepancy in seed composition. The maximum ranges in the water of beta particles from Sm-153 and Ho-166 decay were evaluated, as well as the dose rate and total dose delivered within the volume delimited by the range of the beta particles. The results are relevant for investigation of the viability of producing Sm-153 and Ho-166 radioactive seeds for use in brachytherapy.

  18. Large Dumbbell Shaped Vesicovaginal Calculus Managed with Holmium Laser Cystolithotripsy Followed by Staged Repair of Vesicovaginal Fistula

    PubMed Central

    Sawant, Ajit; Pawar, Prakash; Kasat, Gaurav Vinod; Kapadnis, Lomesh

    2016-01-01

    Complicated Vesicovaginal Fistulae (VVF) is prevalent in developing countries following obstetric injury. We report a rare case of a large dumbbell shaped vesicovaginal calculus measuring 7x 4.6cm in a patient with recurrent, complicated VVF managed successfully in two stages 6 weeks apart. Holmium laser (30 Watt) cystolithotripsy was used to break the vesical portion of the stone at the waist of the dumbbell, followed by delivery of vaginal part of the stone. Trans-abdominal VVF repair (O’Connor method) with omental interposition flap with right side ureteric reimplant was done after six weeks. Our case was unique because of occurrence of a larger sized fistula after a gynaecological surgery. She had developed larger stone (weight more than190gm- vaginal component) into the fistula tract. Also she had undergone multiple failed VVF repair attempts before. Use of holmium laser energy to break the stone was unique which minimized the morbidity of the first procedure leading to early recovery followed by staged repair of fistula after six weeks. PMID:27790520

  19. Determination of some trace elements in food and soil samples by atomic absorption spectrometry after coprecipitation with holmium hydroxide.

    PubMed

    Saracoglu, Sibel; Soylak, Mustafa; Cabuk, Dilek; Topalak, Zeynep; Karagozlu, Yasemin

    2012-01-01

    The determination of trace elements in food and soil samples by atomic absorption spectrometry was investigated. A coprecipitation procedure with holmium hydroxide was used for separation-preconcentration of trace elements. Trace amounts of copper(II), manganese(II), cobalt(II), nickel(ll), chromium(lll), iron(Ill), cadmium(ll), and lead(ll) ions were coprecipitated with holmium hydroxide in 2.0 M NaOH medium. The optimum conditions for the coprecipitation process were investigated for several commonly tested experimental parameters, such as amount of coprecipitant, effect of standing time, centrifugation rate and time, and sample volume. The precision, based on replicate analysis, was lower than 10% for the analytes. In order to verify the accuracy of the method, the certified reference materials BCR 141 R calcareous loam soil and CRM 025-050 soil were analyzed. The procedure was successfully applied for separation and preconcentration of the investigated ions in various food and soil samples. An amount of the solid samples was decomposed with 15 mL concentrated hydrochloric acid-concentrated nitric acid (3 + 1). The preconcentration procedure was then applied to the final solutions. The concentration of trace elements in samples was determined by atomic absorption spectrometry.

  20. Use of the holmium:YAG laser for percutaneous photothermal ablation of cervical invertebral disks in dogs

    NASA Astrophysics Data System (ADS)

    Rochat, Mark; Henry, George A.; Campbell, Gregory A.; Stair, Ernest L.; Bartels, Kenneth E.; Dickey, Tom

    1999-06-01

    Holmium:YAG laser ablation of thoracolumbar disks in dogs has been shown to be an effective alternative to standard surgical fenestration techniques. Our hypothesis was the Holmium:YAG laser could be equally effective and safe when used to ablate cervical intervertebral disks. Six normal chondrodystrophoid breed dogs were used. A sterile, cleaved, 320 micrometers , low-OH quartz optical fiber was inserted into each needle and the laser activated for 40 s at 2 W mean power and a 15 Hz pulse repetition rate for a total of 80 J. Dogs were observed in pain, neurological deficits, or other complications for 24 weeks. At 24 weeks, dogs were euthanatized and cervical disks collected and placed in 10 percent neutral buffered formalin. Disks were decalcified, sectioned at 5 micrometers , and stained with H and E. No problems were encountered during the procedure except occasional difficulties passing the needle by the shoulder to enter the C6-7 disk space. No complications, including neurologic deficits or pain were observe during the 24 weeks. Histologic examination revealed varying degrees of necrosis and defects created in the nucleus pulposus by laser irradiation. In some instances there was evidence of mild adjacent annular and bony thermal injury. On the basis of these result, the Ho:YAG laser appears to be a safe and efficacious method for ablation of canine cervical disks.

  1. Superconducting composite with multilayer patterns and multiple buffer layers

    DOEpatents

    Wu, X.D.; Muenchausen, R.E.

    1993-10-12

    An article of manufacture is described including a substrate, a patterned interlayer of a material selected from the group consisting of magnesium oxide, barium-titanium oxide or barium-zirconium oxide, the patterned interlayer material overcoated with a secondary interlayer material of yttria-stabilized zirconia or magnesium-aluminum oxide, upon the surface of the substrate whereby an intermediate article with an exposed surface of both the overcoated patterned interlayer and the substrate is formed, a coating of a buffer layer selected from the group consisting of cerium oxide, yttrium oxide, curium oxide, dysprosium oxide, erbium oxide, europium oxide, iron oxide, gadolinium oxide, holmium oxide, indium oxide, lanthanum oxide, manganese oxide, lutetium oxide, neodymium oxide, praseodymium oxide, plutonium oxide, samarium oxide, terbium oxide, thallium oxide, thulium oxide, yttrium oxide and ytterbium oxide over the entire exposed surface of the intermediate article, and, a ceramic superconductor. 5 figures.

  2. Development of erbium phosphate doped poly(glycidyl methacrylate/ethylene dimethacrylate) spin columns for selective enrichment of phosphopeptides.

    PubMed

    Güzel, Yüksel; Rainer, Matthias; Messner, Christoph B; Hussain, Shah; Meischl, Florian; Sasse, Michael; Tessadri, Richard; Bonn, Günther K

    2015-05-01

    In this study, a novel method for the highly selective enrichment of phosphopeptides using erbium phosphate doped poly(glycidyl methacrylate/ethylene dimethacrylate) spin columns is presented. Erbium phosphate was synthesized by precipitation from boiling phosphoric acid and incubated overnight in erbium chloride solutions. The resulting powder was embedded in a monolithic poly(glycidyl methacrylate/ethylene dimethacrylate) polymer. The monolith was synthesized in a spin column by radical polymerization. Erbium phosphate demonstrated a high affinity and selectivity for phosphopeptides due to the strong interaction of trivalent erbium ions with the phosphate groups of phosphopeptides. The high selectivity and performance of the designed spin columns were demonstrated by successfully enriching phosphopeptides from tryptically digested protein mixtures containing the model phosphoproteins α- and β-casein, bovine milk, and human saliva. By the implementation of several washing steps, unspecific components were removed and the enriched phosphopeptides were effectively eluted from the spin columns under alkaline conditions. The selective performance of the presented method was further demonstrated by the enrichment of two synthetic phosphopeptides, which were spiked in tryptically digested and dephosphorylated HeLa cell lysates at low ratios. Finally, the presented approach was compared to conventional phosphopeptide enrichment by titanium oxide and revealed higher recoveries for the erbium phosphate doped monoliths.

  3. Real-time synchrotoron radiation X-ray diffraction and abnormal temperature dependence of photoluminescence from erbium silicates on SiO{sub 2}/Si substrates

    SciTech Connect

    Omi, H.; Tawara, T.; Tateishi, M.

    2012-03-15

    The erbium silicate formation processes during annealing in Ar gas were monitored by synchrotron radiation grazing incidence X-ray diffraction (GIXD) in real time and the optical properties of the silicates were investigated by photoluminescence measurements in spectral and time-resolved domains. The GIXD measurements show that erbium silicates and erbium oxide are formed by interface reactions between silicon oxide and erbium oxides deposited on silicon oxide by reactive sputtering in Ar gas and O{sub 2}/Ar mixture gas ambiences. The erbium silicates are formed above 1060 degree sign C in Ar gas ambience and above 1010 degree sign C in O{sub 2}/Ar gas ambience, and erbium silicides are dominantly formed above 1250 degree sign C. The I{sub 15/2}-I{sub 13/2} Er{sup 3+} photoluminescence from the erbium oxide and erbium silicate exhibits abnormal temperature dependence, which can be explained by the phonon-assisted resonant absorption of the 532-nm excitation photons into the {sup 2}H{sub 11/2} levels of Er{sup 3+} ions of the erbium compounds.

  4. Histological changes and wound healing response following noncontact holmium: YAG laser thermal keratoplasty.

    PubMed Central

    Koch, D D

    1996-01-01

    PURPOSE: To evaluate acute histological changes and the induced wound healing response in corneal tissue following noncontact holmium:YAG laser thermal keratoplasty (LTK). METHODS: LTK using 10 pulses and a range of radiant energies was performed on 3 human corneas one day prior ro their removal at penetrating keratoplasty. Rabbit corneas were treated with 10-pulse and 5-pulse LTK and followed for up to 3 months. Tissues were studies with light and transmission electron microscopy and immunohistochemistry. RESULTS: The amount of acute tissue injury increased with increasing pulse radiant energy. In human corneas, changes in the irradiated zones included epithelial cell injury and death loss of fine filamentous structure in Bowman's layer, disruption of stromal lamallae, and keratocyte injury and death. In the rabbit corneas, similar acute changes were noted. By 3 weeks, epithelial hyperplasia and stromal contraction were present. Wound healing in the rabbit corneas included repair of the epithelial attachment complex, keratocyte activation, synthesis of type I collagen, partial restoration of stromal keratan sulfate and type VI collagen, and retrocorneal membrane formation. Compared to 10-pulse treatments, 5-pulse treatments produced less acute tissue injury and had more rapid restoration of normal stromal architecture. CONCLUSION: Noncontact LTK produces acute epithelial and stromal tissue changes and in rabbit corneas stimulates a brisk wound healing response. These changes could contribute to postoperative regression of induced refractive correction. Further work is required to determine if reductions in the magnitude of acute tissue injury and induced wound healing response will enhance the efficacy and stability of LTK. Images FIGURE 1A FIGURE 1B FIGURE 2A FIGURE 2B FIGURE 3A FIGURE 3B FIGURE 4A FIGURE 4B FIGURE 4C FIGURE 4D FIGURE 5A FIGURE 5B FIGURE 5C FIGURE 5D FIGURE 6A FIGURE 6B FIGURE 6C FIGURE 6D FIGURE 7A FIGURE 7B FIGURE 8A FIGURE 8B FIGURE 8C FIGURE

  5. Single-frequency, single-polarization holmium-doped ZBLAN fiber laser

    NASA Astrophysics Data System (ADS)

    Zhu, X.; Zong, J.; Miller, A.; Wiersma, K.; Norwood, R. A.; Prasad, N. S.; Chavez-Pirson, A.; Peyghambarian, N.

    2013-02-01

    We present the performance of a single frequency, single-polarization holmium (Ho3+)-doped ZBLAN (ZrF4-BaF2-LaF3- AlF3-NaF) fiber laser at 1200 nm. This distributed Bragg reflector (DBR) fiber laser was developed by splicing a 22 mm long highly Ho3+-doped ZBLAN fiber to a pair of silica fiber Bragg gratings (FBG). The successful fusion splicing of silica fiber to ZBLAN fiber, with their very different melting temperatures, was accomplished by using NP Photonics proprietary splicing technique. The 3 mol% Ho3+-doped ZBLAN fiber had a core diameter of 6.5 μm and a cladding diameter of 125 μm. The threshold of this laser was seen to be about 260 mW, and when the pump power was 520 mW, the output power was about 10 mW. The efficiency of the 1200 nm single-frequency fiber laser, i.e. the ratio of the output power to the launched pump power, was about 3.8%. The linewidth of the 1200 nm single-frequency fiber laser was estimated to be about 100 kHz by comparing the measured frequency noise of the 1200 nm single-frequency fiber laser with that of 1 μm NP Photonics single-frequency fiber lasers whose linewidths have been measured to be in the 1- 10 kHz range. The relative intensity noise of this DBR all-fiber laser was measured to be < 110 dB/Hz at the relaxation oscillation peak and the polarization extinction ratio was measured to be > 19 dB. Due to its low phonon energy and long radiative lifetimes, rare-earth-doped ZBLAN allows various transitions that are typically terminated in silica glass, resulting in ultraviolet, visible, and infrared rare-earth doped ZBLAN lasers. Therefore, our results highlight the exciting prospect that the accessible wavelength range of single-frequency DBR fiber lasers can be expanded significantly by using rare-earth-doped ZBLAN fibers.

  6. Holmium Laser Enucleation of the Prostate is Safe for Patients Above 80 Years: A Prospective Study

    PubMed Central

    2016-01-01

    Purpose: To evaluate the effect of age on the efficacy and safety of holmium laser enucleation of the prostate (HoLEP) for the treatment of symptomatic benign prostatic hyperplasia (BPH). Methods: A total of 579 patients underwent HoLEP procedure performed by a single surgeon (SJO) between December 2009 and May 2013. The perioperative and functional outcomes of patients in the age groups of 50–59 (group A, n=44), 60–69 (group B, n=253), 70–79 (group C, n=244), and ≥80 years (group D, n=38) were compared. The Clavien-Dindo system was used to evaluate clinical outcomes. The International Prostate Symptom Score (IPSS), maximum urinary flow rate (Qmax), postvoid residual (PVR) urine volume, and urinary continence were used to assess functional outcomes. Results: In this study, the patients ≥80 years had significantly higher presence of hypertension (P=0.007), total prostate volumes (P=0.024), transitional zone volume (P=0.002), American Society of Anesthesiologists scores (P=0.006), urinary retention (P=0.032), and anticoagulation use (P=0.008) at preoperative period. Moreover, the mean values of operation time, enucleation time, morcellation time, and enucleation weight were higher in group D compared with other group patients (P=0.002, P=0.010, P<0.01, and P=0.009, respectively). Patients aged ≥80 years had a longer hospital stay time (2.9±1.8 days) than other groups (group A, 2.3±0.7 days; group B, 2.3±0.7 days vs. group C, 2.4±0.7 days; P=0.001). All groups were similar in regard to the incidence of complications (Clavien-Dindo grade) post operatively (P>0.05). All the patients in the present study showed improvement in functional outcomes after HoLEP. By the sixth month, there were no significant differences in IPSS, quality of life, Qmax, and PVR among the groups (P>0.05). Conclusions: Compared with younger patients, the patients aged ≥80 years had a similar overall morbidity and 6-month functional outcomes of HoLEP. HoLEP is a safe and

  7. Erbium-doped spiral amplifiers with 20 dB of net gain on silicon.

    PubMed

    Vázquez-Córdova, Sergio A; Dijkstra, Meindert; Bernhardi, Edward H; Ay, Feridun; Wörhoff, Kerstin; Herek, Jennifer L; García-Blanco, Sonia M; Pollnau, Markus

    2014-10-20

    Spiral-waveguide amplifiers in erbium-doped aluminum oxide on a silicon wafer are fabricated and characterized. Spirals of several lengths and four different erbium concentrations are studied experimentally and theoretically. A maximum internal net gain of 20 dB in the small-signal-gain regime is measured at the peak emission wavelength of 1532 nm for two sample configurations with waveguide lengths of 12.9 cm and 24.4 cm and concentrations of 1.92 × 10(20) cm(-3) and 0.95 × 10(20) cm(-3), respectively. The noise figures of these samples are reported. Gain saturation as a result of increasing signal power and the temperature dependence of gain are studied.

  8. Erbium-ytterbium-yttrium compounds for light emission at 1.54microm

    NASA Astrophysics Data System (ADS)

    Vanhoutte, Michiel

    Silicon microphotonics˙ has emerged as the leading technology to overcome the interconnect bottleneck that limits a further increase of computation power following Moore's law. Optical interconnects between different electronic microprocessors in an electronic-photonic integrated circuit (EPIC) can provide a fast, low-loss and highbandwidth alternative to electrical interconnects, which suffer from issues such as resistive heating, RC delays and channel crosstalk at an increasing device density. A crucial device in such an electronic-photonic integrated circuit is a compact, highgain and low power optical amplifier to compensate for signal attenuation due to propagation losses and to recover signal strength after subsequent 3dB splits during fanout of the optical signal to different microprocessors. Erbium ions (Er3+) are an excellent candidate to provide amplification around .. = 1.54pm for optical telecommunications. Erbium-doped fiber amplifiers (EDFAs) have already enabled long-haul optical data. transmission through silica optical fibers, but scaling down a fiber amplifier to an on-chip erbium-doped waveguide amplifier (EDWA) brings along significant materials and device design challenges. In this thesis, erbium-ytterbium oxide (Erx Yb2-xO 3) and erbium-ytterbium-yttrium silicate (ErxYhyY 2-x-ySi2O7) compounds are investigated as novel materials systems for the development of EDWAs. The high erbium and ytterbium solubility (>1022 cm-3) and refractive index (1.71 < n < 1.92) make these materials excellent candidates for compact, low-power optical amplifiers. Erx Yb2-xO 3 and ErxYhyY2-x-ySi2O 7 thin films were deposited on SiO2 and analyzed structurally and optically. The role of ytterbium in these compounds is twofold. First, ytterbium can be used as an alternative to yttrium for dilution of the erbium concentration in order to mitigate parasitic concentration quenching effects. Second, ytterbium acts as a sensitizer for erbium during optical pumping at lambda

  9. Coupling erbium spins to a three-dimensional superconducting cavity at zero magnetic field

    NASA Astrophysics Data System (ADS)

    Chen, Yu-Hui; Fernandez-Gonzalvo, Xavier; Longdell, Jevon J.

    2016-08-01

    We experimentally demonstrate the coupling at zero magnetic field of an isotopically pure erbium-doped yttrium orthosilicate crystal (167Er:YSO ) to a three-dimensional superconducting cavity with a Q factor of 105. A tunable loop-gap resonator is used and its resonance frequency is tuned to observe the hyperfine transitions of the erbium sample. The observed spectrum differs from what is predicted by the published spin Hamiltonian parameters. The narrow cavity linewidth also enables the observation of asymmetric line shapes for these hyperfine transitions. Such a broadly tunable superconducting cavity (from 1.6 to 4.0 GHz in the current design) is a promising device for building hybrid quantum systems.

  10. Few-mode erbium-doped fiber amplifier with photonic lantern for pump spatial mode control.

    PubMed

    Lopez-Galmiche, G; Sanjabi Eznaveh, Z; Antonio-Lopez, J E; Velazquez Benitez, A M; Rodriguez Asomoza, J; Sanchez Mondragon, J J; Gonnet, C; Sillard, P; Li, G; Schülzgen, A; Okonkwo, C M; Amezcua Correa, R

    2016-06-01

    We demonstrate a few-mode erbium-doped fiber amplifier employing a mode-selective photonic lantern for controlling the modal content of the pump light. Amplification of six spatial modes in a 5 m long erbium-doped fiber to ∼6.2  dBm average power is obtained while maintaining high modal fidelity. Through mode-selective forward pumping of the two degenerate LP21 modes operating at 976 nm, differential modal gains of <1  dB between all modes and signal gains of ∼16  dB at 1550 nm are achieved. In addition, low differential modal gain for near-full C-band operation is demonstrated. PMID:27244421

  11. Opportunities for Low Cost Processing of Erbium 8-Quinolinolates for Active Integrated Photonic Applications.

    PubMed

    Penna, Stefano; Mattiello, Leonardo; Di Bartolo, Silvia; Pizzoleo, Angelo; Attanasio, Vincenzo; Beleffi, Giorgio Maria Tosi; Otomo, Akira

    2016-04-01

    Erbium-doped organic emitters are promising active materials for Photonic Integrated Circuits (PICs) due to their emission shown at 1550 nm combined to the potential low cost processing. In particular, Erbium Quinoline (ErQ) gained a strong interest in the last decade for the good emission efficiency. This contribution reports the results derived from the application of ErQ as active core material within a buried optical waveguide, following the development of a purposed optical process to control the refractive index of ErQ and then to define a patterned structure from a single thin film deposition step. The reported results show the potential of Er-doped organic materials for low cost processing and application to planar PICs. PMID:27451632

  12. Reflection L-band erbium-doped fiber-amplifier-based fiber loop mirror

    NASA Astrophysics Data System (ADS)

    Meng, Hongyun; Liu, Songhao; Dong, Xiaoyi

    2005-01-01

    We constructed a reflection L-band erbium-doped fiber amplifier based on fiber loop mirror, which reflects the backward ASE to the EDF as a secondary pumping source. A gain of 30 dB increased 6 dB compared to the forward end-pumped EDFA has been achieved in the wavelength region from 1570 to 1603 nm. In order to improve the gain and NF further, we constructed a novel configuration for reflection L-band erbium-doped fiber amplifier via inserting a 980 nm LD in the input part. Adjusting the ratio of power of the two LDs, the gain and NF are greatly improved in different degree in the region from 1565 to 1615 nm. Compared to the configuration pumped by only 1480 nm LD with given power, the gain enhanced 1.5-9.9 dB and the NF decreases 1.3-9.4 dB.

  13. Double Brillouin frequency spaced multiwavelength Brillouin-erbium fiber laser with 50 nm tuning range

    NASA Astrophysics Data System (ADS)

    Zhao, J. F.; Liao, T. Q.; Zhang, C.; Zhang, R. X.; Miao, C. Y.; Tong, Z. R.

    2012-09-01

    A 50 nm tuning range multiwavelength Brillouin-erbium fiber laser (MWBEFL) with double Brillouin frequency spacing is presented. Two separated gain blocks with symmetrical architecture, consisted by erbium-doped fiber amplifiers (EDFAs) and Brillouin gain media, are used to generate double Brillouin frequency spacing. The wider tuning range is realized by eliminating the self-lasing cavity modes existing in conventional MWBEFLs because of the absence of the physical mirrors at the ends of the linear cavity. The Brillouin pump (BP) is preamplified by the EDFA before entering the single-mode fiber (SMF), which leads to the reduction of threshold power and the generation enhancement of Brillouin Stokes (BS) signals. Four channels with 0.176 nm spacing are achieved at 2 mW BP power and 280 mW 980 nm pump power which can be tuned from 1525 to 1575 nm.

  14. 1.54 micron Emission from Erbium implanted GaN for Photonic Applications

    NASA Technical Reports Server (NTRS)

    Thaik, Myo; Hommerich, U.; Schwartz, R. N.; Wilson, R. G.; Zavada, J. M.

    1998-01-01

    The development of efficient and compact light sources operating at 1.54 micron is of enormous importance for the advancement of new optical communication systems. Erbium (1%) doped fiber amplifiers (EDFA's) or semiconductor lasers are currently being employed as near infrared light sources. Both devices, however, have inherent limitations due to their mode of operation. EDFA's employ an elaborate optical pumping scheme, whereas diode lasers have a strongly temperature dependent lasing wavelength. Novel light emitters based on erbium doped III-V semiconductors could overcome these limitations. Er doped semiconductors combine the convenience of electrical excitation with the excellent luminescence properties of Er(3+) ions. Electrically pumped, compact, and temperature stable optoelectronic devices are envisioned from this new class of luminescent materials. In this paper we discuss the potential of Er doped GaN for optoelectronic applications based on temperature dependent photoluminescence excitation studies.

  15. Invariant bandwidth of erbium in ZnO-PbO-tellurite glasses: Local probe/model

    SciTech Connect

    Ramamoorthy, Raj Kumar; Bhatnagar, Anil K.

    2014-04-24

    A series of [(70TeO{sub 2}−(30−x)ZnO−xPbO){sub 0.99}−(Er{sub 2}O{sub 3}){sub 0.01}; where x = 5, 10, 15 and 20] tellurite glasses, were prepared using the melt quenching technique. Crucial emission bandwidth of erbium at 1.5 μm has been derived and found to be the same for all the glasses, irrespective of PbO content. This identical bandwidth in all tellurite glasses is attributed to the presence of erbium in tellurium rich disordered environments. This result has been complemented through XANES spectra and the obtained invariant first shell of 6.5 oxygen atoms, confirm the unchanged environment in these glasses for all PbO content.

  16. Simulation of an erbium-doped chalcogenide micro-disk mid-infrared laser source.

    PubMed

    Al Tal, Faleh; Dimas, Clara; Hu, Juejun; Agarwal, Anu; Kimerling, Lionel C

    2011-06-20

    The feasibility of mid-infrared (MIR) lasing in erbium-doped gallium lanthanum sulfide (GLS) micro-disks was examined. Lasing condition at 4.5 µm signal using 800 nm pump source was simulated using rate equations, mode propagation and transfer matrix formulation. Cavity quality (Q) factors of 1.48 × 10(4) and 1.53 × 10(6) were assumed at the pump and signal wavelengths, respectively, based on state-of-the-art chalcogenide micro-disk resonator parameters. With an 80 µm disk diameter and an active erbium concentration of 2.8 × 10(20) cm(-3), lasing was shown to be possible with a maximum slope efficiency of 1.26 × 10(-4) and associated pump threshold of 0.5 mW.

  17. Opportunities for Low Cost Processing of Erbium 8-Quinolinolates for Active Integrated Photonic Applications.

    PubMed

    Penna, Stefano; Mattiello, Leonardo; Di Bartolo, Silvia; Pizzoleo, Angelo; Attanasio, Vincenzo; Beleffi, Giorgio Maria Tosi; Otomo, Akira

    2016-04-01

    Erbium-doped organic emitters are promising active materials for Photonic Integrated Circuits (PICs) due to their emission shown at 1550 nm combined to the potential low cost processing. In particular, Erbium Quinoline (ErQ) gained a strong interest in the last decade for the good emission efficiency. This contribution reports the results derived from the application of ErQ as active core material within a buried optical waveguide, following the development of a purposed optical process to control the refractive index of ErQ and then to define a patterned structure from a single thin film deposition step. The reported results show the potential of Er-doped organic materials for low cost processing and application to planar PICs.

  18. Biomimetic synthesis of chiral erbium-doped silver/peptide/silica core-shell nanoparticles (ESPN).

    PubMed

    Mantion, Alexandre; Graf, Philipp; Florea, Ileana; Haase, Andrea; Thünemann, Andreas F; Mašić, Admir; Ersen, Ovidiu; Rabu, Pierre; Meier, Wolfgang; Luch, Andreas; Taubert, Andreas

    2011-12-01

    Peptide-modified silver nanoparticles have been coated with an erbium-doped silica layer using a method inspired by silica biomineralization. Electron microscopy and small-angle X-ray scattering confirm the presence of an Ag/peptide core and silica shell. The erbium is present as small Er(2)O(3) particles in and on the silica shell. Raman, IR, UV-Vis, and circular dichroism spectroscopies show that the peptide is still present after shell formation and the nanoparticles conserve a chiral plasmon resonance. Magnetic measurements find a paramagnetic behavior. In vitro tests using a macrophage cell line model show that the resulting multicomponent nanoparticles have a low toxicity for macrophages, even on partial dissolution of the silica shell.

  19. Cavity-dumped 2.70 microm erbium laser using optomechanical shutter.

    PubMed

    Park, Young Ho; Won Lee, Dong; Kong, Hong Jin; Kim, Yeong Sik

    2008-12-01

    A cavity-dumped 2.70 microm erbium laser with a frustrated total internal reflection (FTIR) shutter was investigated and compared with a Q-switched erbium laser using the FTIR shutter. The Q-switched and the cavity-dumped 2.70 microm laser outputs were obtained with a dichroic coated mirror with high reflectance at 2.70 microm and high transmittance at 2.79 microm. For the Q-switched operation, a maximum peak power of 33.5 kW was achieved, and its pulse width was 1.3 mus. For the cavity-dumped operation, the laser pulse energy was optimized by changing the switching time of the FTIR shutter. When the pulse width is reduced to 210 ns, the peak power increases to 154 kW.

  20. Healing of bone in the rat following surgery with the erbium-YAG laser

    NASA Astrophysics Data System (ADS)

    Dickinson, Mark R.; Devlin, Hugh; El Montaser, Monsour A.; Sloan, Philip

    1996-12-01

    Background and objectives: the aim of this study was to examine the pattern of healing in rat calvarial defects prepared with the erbium-YAG laser, using the 'guided tissue regeneration' technique. Materials and method: PTFE membranes were placed over lased skull defects, and the skin wounds sutured. Rats were killed humanely at intervals after surgery, and the skulls processed for paraffin wax histology. A further group of mature rats were also killed humanely and the calvariae removed. Slots were prepared using the erbium-YAG laser and immediately examined under the environmental scanning electron microscope (ESEM) in hydrated conditions, which avoided drying artifacts. Results: An amorphous, mineral-rich carbon layer surrounds the lased bone defect, which in the in vivo experiments was seen as a basophilic zone which was resistant to resorption.

  1. Erbium:YAG laser incision of urethral strictures: early clinical results

    NASA Astrophysics Data System (ADS)

    Munoz, John A.; Riemer, Jennifer D.; Hayes, Gary B.; Negus, Dan; Fried, Nathaniel M.

    2007-02-01

    Two cases involving Erbium:YAG laser incision of proximal bulbar urethral strictures are described. Erbium:YAG laser radiation with a wavelength of 2.94 μm, pulse energy of 10 mJ, and a pulse repetition rate of 15 Hz, was delivered through a 2-m-long, 250-μm-core sapphire optical fiber in contact with tissue. Total laser irradiation time was 5 min. The first patient suffering from a virgin urethral stricture was treated and is stricture-free. The second patient suffering from a recurrent urethral stricture required further treatment. This case report describes the first clinical application of the Er:YAG laser in urology.

  2. Few-mode erbium-doped fiber amplifier with photonic lantern for pump spatial mode control.

    PubMed

    Lopez-Galmiche, G; Sanjabi Eznaveh, Z; Antonio-Lopez, J E; Velazquez Benitez, A M; Rodriguez Asomoza, J; Sanchez Mondragon, J J; Gonnet, C; Sillard, P; Li, G; Schülzgen, A; Okonkwo, C M; Amezcua Correa, R

    2016-06-01

    We demonstrate a few-mode erbium-doped fiber amplifier employing a mode-selective photonic lantern for controlling the modal content of the pump light. Amplification of six spatial modes in a 5 m long erbium-doped fiber to ∼6.2  dBm average power is obtained while maintaining high modal fidelity. Through mode-selective forward pumping of the two degenerate LP21 modes operating at 976 nm, differential modal gains of <1  dB between all modes and signal gains of ∼16  dB at 1550 nm are achieved. In addition, low differential modal gain for near-full C-band operation is demonstrated.

  3. 2-LP mode few-mode fiber amplifier employing ring-core erbium-doped fiber.

    PubMed

    Ono, Hirotaka; Hosokawa, Tsukasa; Ichii, Kentaro; Matsuo, Shoichiro; Nasu, Hitoshi; Yamada, Makoto

    2015-10-19

    A fiber amplifier supporting 2 LP modes that employs a ring-core erbium-doped fiber (RC-EDF) is investigated to reduce differential modal gain (DMG). The inner and outer radii of the ring-core of the RC-EDF are clarified for 2-LP mode operation of the amplifier, and are optimized to reduce the DMG. It is shown that using the overlap integral between the erbium-doped core area and the signal power mode distribution is a good way to optimize the inner and outer radii of the ring-core of the RC-EDF and thus minimize the DMG. A fabricated RC-EDF and a constructed 2-LP mode EDFA are described and a small DMG of around 1 dB is realized for LP01, LP11 and LP21 pumping.

  4. Tunable Brillouin-erbium fiber laser incorporating a low-cost biconic tapered fiber

    NASA Astrophysics Data System (ADS)

    Lin, H. S.; Mansoor, A.; Phua, Y. N.; Mokhtar, M. R.; Abdul-Rashid, H. A.; Yusoff, Z.

    2014-02-01

    A new method of tuning a multi-wavelength Brillouin-erbium fiber laser (BEFL) within a Fabry-Perot cavity by incorporating a low-cost biconic tapered fiber is reported. The biconic tapered fiber was fabricated using a flame elongation technique and it was incorporated into the BEFL system to position the self-lasing cavity modes over a tuning range of 5.5 nm within the erbium-doped fiber gain profile. By injecting the Brillouin pump near to the tunable self-lasing cavity modes, it suppresses the modes and generates stable cascaded Brillouin-Stokes lines with more than 20 dB signal-to-noise ratio.

  5. Modelling of micromachining of human tooth enamel by erbium laser radiation

    SciTech Connect

    Belikov, A V; Skrypnik, A V; Shatilova, K V

    2014-08-31

    We consider a 3D cellular model of human tooth enamel and a photomechanical cellular model of enamel ablation by erbium laser radiation, taking into account the structural peculiarities of enamel, energy distribution in the laser beam cross section and attenuation of laser energy in biological tissue. The surface area of the texture in enamel is calculated after its micromachining by erbium laser radiation. The influence of the surface area on the bond strength of enamel with dental filling materials is discussed. A good correlation between the computer simulation of the total work of adhesion and experimentally measured bond strength between the dental filling material and the tooth enamel after its micromachining by means of YAG : Er laser radiation is attained. (laser biophotonics)

  6. Synthesis mechanism of low-voltage praseodymium oxide doped zinc oxide varistor ceramics prepared through modified citrate gel coating.

    PubMed

    Abdullah, Wan Rafizah Wan; Zakaria, Azmi; Ghazali, Mohd Sabri Mohd

    2012-01-01

    High demands on low-voltage electronics have increased the need for zinc oxide (ZnO) varistors with fast response, highly non-linear current-voltage characteristics and energy absorption capabilities at low breakdown voltage. However, trade-off between breakdown voltage and grain size poses a critical bottle-neck in the production of low-voltage varistors. The present study highlights the synthesis mechanism for obtaining praseodymium oxide (Pr(6)O(11)) based ZnO varistor ceramics having breakdown voltages of 2.8 to 13.3 V/mm through employment of direct modified citrate gel coating technique. Precursor powder and its ceramics were examined by means of TG/DTG, FTIR, XRD and FESEM analyses. The electrical properties as a function of Pr(6)O(11) addition were analyzed on the basis of I-V characteristic measurement. The breakdown voltage could be adjusted from 0.01 to 0.06 V per grain boundary by controlling the amount of Pr(6)O(11) from 0.2 to 0.8 mol%, without alteration of the grain size. The non-linearity coefficient, α, varied from 3.0 to 3.5 and the barrier height ranged from 0.56 to 0.64 eV. Breakdown voltage and α lowering with increasing Pr(6)O(11) content were associated to reduction in the barrier height caused by variation in O vacancies at grain boundary. PMID:22606043

  7. Fluorescence and DNA-binding properties of neodymium(III) and praseodymium(III) complexes containing 1,10-phenanthroline

    NASA Astrophysics Data System (ADS)

    Khorasani-Motlagh, Mozhgan; Noroozifar, Meissam; Mirkazehi-Rigi, Sohaila

    2011-09-01

    The binding of neodymium(III) and praseodymium(III) complexes containing 1,10-phenanthroline, [M(phen) 2Cl 3·OH 2] (M = Nd ( 1), Pr ( 2)), to DNA has been investigated by absorption, emission, and viscosity measurements. The complexes show absorption decreasing in charge transfer band, fluorescence decrement when bound to DNA. The binding constant Kb has been determined by absorption measurement for both complexes and found to be (6.76 ± 0.12) × 10 4 for 1 and (1.83 ± 0.15) × 10 4 M -1, for 2. The fluorescence of [M(phen) 2Cl 3·OH 2] (M = Nd ( 1), Pr ( 2)) has been studied in detail. The results of fluorescence titration reveal that DNA has the strong ability to quenching the intrinsic fluorescence of Nd(III) and Pr(III) complexes through the static quenching procedure. The binding site number n, apparent binding constant Kb and the Stern-Volmer constant kSV are determined. Thermodynamic parameters, enthalpy change (Δ H°) and entropy change (Δ S°), are calculated according to relevant fluorescent data and Van't Hoff equation. The experimental data suggest that the complexes bind to DNA by non-intercalative mode. Major groove binding is the preferred mode of interaction for [M(phen) 2Cl 3·OH 2] (M = Nd ( 1), Pr ( 2)) with DNA.

  8. Synthesis Mechanism of Low-Voltage Praseodymium Oxide Doped Zinc Oxide Varistor Ceramics Prepared Through Modified Citrate Gel Coating

    PubMed Central

    Abdullah, Wan Rafizah Wan; Zakaria, Azmi; Ghazali, Mohd Sabri Mohd

    2012-01-01

    High demands on low-voltage electronics have increased the need for zinc oxide (ZnO) varistors with fast response, highly non-linear current-voltage characteristics and energy absorption capabilities at low breakdown voltage. However, trade-off between breakdown voltage and grain size poses a critical bottle-neck in the production of low-voltage varistors. The present study highlights the synthesis mechanism for obtaining praseodymium oxide (Pr6O11) based ZnO varistor ceramics having breakdown voltages of 2.8 to 13.3 V/mm through employment of direct modified citrate gel coating technique. Precursor powder and its ceramics were examined by means of TG/DTG, FTIR, XRD and FESEM analyses. The electrical properties as a function of Pr6O11 addition were analyzed on the basis of I-V characteristic measurement. The breakdown voltage could be adjusted from 0.01 to 0.06 V per grain boundary by controlling the amount of Pr6O11 from 0.2 to 0.8 mol%, without alteration of the grain size. The non-linearity coefficient, α, varied from 3.0 to 3.5 and the barrier height ranged from 0.56 to 0.64 eV. Breakdown voltage and α lowering with increasing Pr6O11 content were associated to reduction in the barrier height caused by variation in O vacancies at grain boundary. PMID:22606043

  9. The permanent electric dipole moments and magnetic g(e)-factors of praseodymium monoxide (PrO).

    PubMed

    Wang, Hailing; Linton, Colan; Ma, Tongmei; Steimle, Timothy C

    2009-11-26

    The R(4.5) and P(6.5) branch features of the XX (0, 0) band of praseodymium monoxide (PrO) have been studied at a resolution of approximately 50 MHz field free and in the presence of static electric and magnetic fields. The permanent electric dipole moments, mu(el), of 3.01(6) D and 4.72(5) D for the X(2) (Omega = 4.5) and [18.1] (Omega = 5.5) states, respectively, were determined from the analysis of the Stark spectra. The magnetic g(e)-factors of 4.48(8) and 5.73(6) for the X(2) (Omega = 4.5) and [18.1] (Omega = 5.5) states, respectively, were determined from the analysis of the Zeeman spectra. The g(e)-factors are compared with those computed using wave functions predicted from ligand field theory and ab initio calculations. The mu(el) value for the X(2) (Omega = 4.5) state is compared to ab initio and density functional predicted values and with the experimental values of other lanthanide monoxides.

  10. Concentration quenching of praseodymium ions Pr(3+) in BaGd2(MoO4)4 crystals.

    PubMed

    Guan, Ying; Tsuboi, Taiju; Huang, Yanlin; Huang, Wei

    2014-03-01

    The concentration effect on the photoluminescence (PL) of the praseodymium Pr(3+) ion is studied at 298-12 K for barium gadolinium molybdate (BaGd2(MoO4)4, called BGM) crystals with a wide Pr(3+) concentration range of 0.05-25.0 mol%. Three types of concentration dependences are observed for the emissions although all types show PL quenching at high concentrations. The first type (Type A) has the maximum PL intensity at about 10 mol% with a non-zero intensity at high concentrations, which is observed for the (3)P0 emissions except for emission at 621 nm. The second and third types (Type B-1 and B-2) have the maximum at about 1 mol% with a finite residual intensity and nearly zero intensity at high concentrations, respectively, which are observed for the 621 nm emission and all the (1)D2 emissions. It is suggested that the energy migration mechanism is responsible for Type A, while the non-resonant cross-relaxation is responsible for Type B-1 and the resonant cross-relaxation for Type B-2.

  11. Laser-diode pumped self-mode-locked praseodymium visible lasers with multi-gigahertz repetition rate.

    PubMed

    Zhang, Yuxia; Yu, Haohai; Zhang, Huaijin; Di Lieto, Alberto; Tonelli, Mauro; Wang, Jiyang

    2016-06-15

    We demonstrate efficient laser-diode pumped multi-gigahertz (GHz) self-mode-locked praseodymium (Pr3+) visible lasers with broadband spectra from green to deep red for the first time to our knowledge. With a Pr3+-doped GdLiF4 crystal, stable self-mode-locked visible pulsed lasers at the wavelengths of 522 nm, 607 nm, 639 nm, and 720 nm have been obtained with the repetition rates of 2.8 GHz, 3.1 GHz, 3.1 GHz, and 3.0 GHz, respectively. The maximum output power was 612 mW with the slope efficiency of 46.9% at 639 nm. The mode-locking mechanism was theoretically analyzed. The stable second-harmonic mode-locking with doubled repetition frequency was also realized based on the Fabry-Perot effect formed in the laser cavity. In addition, we find that the polarization directions were turned with lasing wavelengths. This work may provide a new way for generating efficient ultrafast pulses with high- and changeable-repetition rates in the visible range.

  12. Influence of praseodymium and nitrogen co-doping on the photocatalytic activity of TiO{sub 2}

    SciTech Connect

    Wu, Jing; Liu, Qingju; Gao, Pan; Zhu, Zhongqi

    2011-11-15

    Highlights: {yields} The praseodymium and nitrogen co-doped TiO{sub 2} (Pr-N-TiO{sub 2}) powders were prepared and characterized. {yields} The effects on the photocatalytic activity were studied. {yields} The results exhibit that the spectrum absorption region of the co-doped sample is red-shifted to visible light and the recombination of the photo-generated pairs is inhibited. {yields} The photocatalytic activity is greatly improved. -- Abstract: TiO{sub 2} nanoparticles co-doped with different doping concentration of Pr and N were prepared by sol-gel method combined with microwave chemical method. The samples were characterized by XRD, FT-IR, UV-vis, TEM, XPS, PL, and the photocatalytic activity were investigated by photocatalytic degradation of methylene blue (MB). The results indicate that Pr and N ions incorporate into the lattice of TiO{sub 2}, co-doping restrains the increase of grain size, broadens the absorption region to visible light, and inhibits the recombination of the photo-generated electrons and holes. Moreover, the photocatalytic activity of Pr-N-TiO{sub 2} is remarkable improved due to the synergistic effect of the co-doped ions. The degradation rate of MB in 6 h is 92.81%, which is much higher than that of Degussa P25 (45.01%).

  13. Fluorescence and DNA-binding properties of neodymium(III) and praseodymium(III) complexes containing 1,10-phenanthroline.

    PubMed

    Khorasani-Motlagh, Mozhgan; Noroozifar, Meissam; Mirkazehi-Rigi, Sohaila

    2011-09-01

    The binding of neodymium(III) and praseodymium(III) complexes containing 1,10-phenanthroline, [M(phen)2Cl3·OH2] (M=Nd (1), Pr (2)), to DNA has been investigated by absorption, emission, and viscosity measurements. The complexes show absorption decreasing in charge transfer band, fluorescence decrement when bound to DNA. The binding constant Kb has been determined by absorption measurement for both complexes and found to be (6.76±0.12)×10(4) for 1 and (1.83±0.15)×10(4)M(-1), for 2. The fluorescence of [M(phen)2Cl3·OH2] (M=Nd (1), Pr (2)) has been studied in detail. The results of fluorescence titration reveal that DNA has the strong ability to quenching the intrinsic fluorescence of Nd(III) and Pr(III) complexes through the static quenching procedure. The binding site number n, apparent binding constant Kb and the Stern-Volmer constant kSV are determined. Thermodynamic parameters, enthalpy change (ΔH°) and entropy change (ΔS°), are calculated according to relevant fluorescent data and Van't Hoff equation. The experimental data suggest that the complexes bind to DNA by non-intercalative mode. Major groove binding is the preferred mode of interaction for [M(phen)2Cl3·OH2] (M=Nd (1), Pr (2)) with DNA.

  14. Synthesis mechanism of low-voltage praseodymium oxide doped zinc oxide varistor ceramics prepared through modified citrate gel coating.

    PubMed

    Abdullah, Wan Rafizah Wan; Zakaria, Azmi; Ghazali, Mohd Sabri Mohd

    2012-01-01

    High demands on low-voltage electronics have increased the need for zinc oxide (ZnO) varistors with fast response, highly non-linear current-voltage characteristics and energy absorption capabilities at low breakdown voltage. However, trade-off between breakdown voltage and grain size poses a critical bottle-neck in the production of low-voltage varistors. The present study highlights the synthesis mechanism for obtaining praseodymium oxide (Pr(6)O(11)) based ZnO varistor ceramics having breakdown voltages of 2.8 to 13.3 V/mm through employment of direct modified citrate gel coating technique. Precursor powder and its ceramics were examined by means of TG/DTG, FTIR, XRD and FESEM analyses. The electrical properties as a function of Pr(6)O(11) addition were analyzed on the basis of I-V characteristic measurement. The breakdown voltage could be adjusted from 0.01 to 0.06 V per grain boundary by controlling the amount of Pr(6)O(11) from 0.2 to 0.8 mol%, without alteration of the grain size. The non-linearity coefficient, α, varied from 3.0 to 3.5 and the barrier height ranged from 0.56 to 0.64 eV. Breakdown voltage and α lowering with increasing Pr(6)O(11) content were associated to reduction in the barrier height caused by variation in O vacancies at grain boundary.

  15. Laser-diode pumped self-mode-locked praseodymium visible lasers with multi-gigahertz repetition rate.

    PubMed

    Zhang, Yuxia; Yu, Haohai; Zhang, Huaijin; Di Lieto, Alberto; Tonelli, Mauro; Wang, Jiyang

    2016-06-15

    We demonstrate efficient laser-diode pumped multi-gigahertz (GHz) self-mode-locked praseodymium (Pr3+) visible lasers with broadband spectra from green to deep red for the first time to our knowledge. With a Pr3+-doped GdLiF4 crystal, stable self-mode-locked visible pulsed lasers at the wavelengths of 522 nm, 607 nm, 639 nm, and 720 nm have been obtained with the repetition rates of 2.8 GHz, 3.1 GHz, 3.1 GHz, and 3.0 GHz, respectively. The maximum output power was 612 mW with the slope efficiency of 46.9% at 639 nm. The mode-locking mechanism was theoretically analyzed. The stable second-harmonic mode-locking with doubled repetition frequency was also realized based on the Fabry-Perot effect formed in the laser cavity. In addition, we find that the polarization directions were turned with lasing wavelengths. This work may provide a new way for generating efficient ultrafast pulses with high- and changeable-repetition rates in the visible range. PMID:27304265

  16. Concentration quenching of praseodymium ions Pr(3+) in BaGd2(MoO4)4 crystals.

    PubMed

    Guan, Ying; Tsuboi, Taiju; Huang, Yanlin; Huang, Wei

    2014-03-01

    The concentration effect on the photoluminescence (PL) of the praseodymium Pr(3+) ion is studied at 298-12 K for barium gadolinium molybdate (BaGd2(MoO4)4, called BGM) crystals with a wide Pr(3+) concentration range of 0.05-25.0 mol%. Three types of concentration dependences are observed for the emissions although all types show PL quenching at high concentrations. The first type (Type A) has the maximum PL intensity at about 10 mol% with a non-zero intensity at high concentrations, which is observed for the (3)P0 emissions except for emission at 621 nm. The second and third types (Type B-1 and B-2) have the maximum at about 1 mol% with a finite residual intensity and nearly zero intensity at high concentrations, respectively, which are observed for the 621 nm emission and all the (1)D2 emissions. It is suggested that the energy migration mechanism is responsible for Type A, while the non-resonant cross-relaxation is responsible for Type B-1 and the resonant cross-relaxation for Type B-2. PMID:24429706

  17. Near-IR imaging of Erbium Laser Ablation with a Water Spray.

    PubMed

    Darling, Cynthia L; Maffei, Marie E; Fried, William A; Fried, Daniel

    2008-01-20

    Near-IR (NIR) imaging can be used to view the formation of ablation craters during laser ablation since the enamel of the tooth is almost completely transparent near 1310-nm(1). Laser ablation craters can be monitored under varying irradiation conditions to assess peripheral thermal and transient-stress induced damage, measure the rate and efficiency of ablation and provide insight into the ablation mechanism. There are fundamental differences in the mechanism of enamel ablation using erbium lasers versus carbon dioxide laser systems due to the nature of the primary absorber and it is necessary to have water present on the tooth surface for efficient ablation at erbium laser wavelengths. In this study, sound human tooth sections of approximately 2-3-mm thickness were irradiated by free running and Q-switched Er:YAG & Er:YSGG lasers under varying conditions with and without a water spray. The incision area in the interior of each sample was imaged using a tungsten-halogen lamp with a band-pass filter centered at 1310-nm combined with an InGaAs area camera with a NIR zoom microscope. Obvious differences in the crater evolution were observed between CO(2) and erbium lasers. Ablation stalled after a few laser pulses without a water spray as anticipated. Efficient ablation was re-initiated by resuming the water spray. Micro-fractures were continuously produced apparently driven along prism lines during multi-pulse ablation. These fractures or fissures appeared to merge together as the crater evolved to form the leading edge of the ablation crater. These observations support the proposed thermo-mechanical mechanisms of erbium laser involving the strong mechanical forces generated by selective absorption by water. PMID:21892255

  18. Imaging of Bloch oscillations in erbium-doped curved waveguide arrays.

    PubMed

    Chiodo, N; Della Valle, G; Osellame, R; Longhi, S; Cerullo, G; Ramponi, R; Laporta, P; Morgner, U

    2006-06-01

    We report a direct observation of Bloch-like dynamics of light in curved waveguide arrays manufactured in Er:Yb-doped phosphate glass by femtosecond laser writing. The green upconversion fluorescence emitted by excited erbium ions is exploited to image the flow of the guided pump light at approximately 980 nm along the array. Direct and clear evidence of periodic light breathing for single-waveguide excitation, closely related to Bloch oscillations, is reported.

  19. Bandwidth optimization of a Carbon Nanotubes mode-locked Erbium-doped fiber laser

    NASA Astrophysics Data System (ADS)

    Rosa, H. G.; De Souza, E. A.

    2012-03-01

    We present a new method to fabricate thin films using single-walled Carbon Nanotubes (SWCNT) and a urethane-based transparent polymer. We construct an Erbium-doped fiber laser to test our films as saturable absorbers to work as passive mode-locker. As results, pulse-trains were achieved and we carried on an optimization study involving total cavity dispersion, absorption strength of thin films incorporating SWCNT and laser bandwidth to produce broad bandwidths in passive mode-locking regime.

  20. Synthesis and characterization of erbium-doped YAlO3 phosphor.

    PubMed

    Baig, Huma Nazli; Saluja, Jagjeet Kaur; Dhoble, S J

    2016-03-01

    In the yttrium aluminium system, the YAlO3 phosphor is a prominent host because of the yttrium aluminium ratio (1:1). Phosphor was synthesized by the solid-state reaction method at variable concentrations of erbium (0.1-2.5 mol%). This method is suitable for large-scale production and is a less time-consuming method when compared with the soft synthesis method. The prepared sample was characterized by X-ray diffraction technique and the crystallite size was calculated by Scherer's formula. Vibrational and bending analysis of prepared phosphor for optimized concentration of erbium ion is described based on the Fourier transform infrared spectroscopic technique. The photoluminescence (PL) emission spectra of prepared phosphor for variable concentrations of erbium ion were recorded and the excitation spectrum was found to be at 291 nm with three shoulder peaks at 305, 270 and 242 nm. For 291 nm excitation, the emission spectrum was found at 546 nm and 552 nm. PL intensity increased with increasing concentrations of erbium and after 2 mol% emission intensity decreased due to concentration quenching. Spectrophotometric determination of YAlO3:Er(3+) is described by CIE co-ordinates and shows an intense emission in the green region such that the prepared phosphor can act as a single host for green light emission. Thermoluminescence glow curve analysis of the YAlO3:Er(3+) phosphor was recorded for different ultraviolet (UV) light exposures and gamma exposure. Different gamma doses 0.5-2 kGy show a linear response. Kinetic parameters were calculated by the peak shape method. PMID:26455914

  1. Dynamic Fano-like resonances in erbium-doped whispering-gallery-mode microresonators

    SciTech Connect

    Lei, Fuchuan; Peng, Bo; Özdemir, Şahin Kaya Yang, Lan; Long, Gui Lu

    2014-09-08

    We report Fano-like asymmetric resonances modulated by optical gain in a whispering-gallery-mode resonator fabricated from erbium-doped silica. A time-dependent gain profile leads to dynamically varying sharp asymmetric resonances with features similar to Fano resonances. Depending on the scan speed of the frequency of the probe laser and the pump-probe power ratio, transmission spectra of the active microcavity exhibit a resonance dip, a resonance peak, or a Fano-like resonance.

  2. Resonantly pumped high power flat L-band erbium-doped superfluorescent fiber source.

    PubMed

    Chen, Sheng-Ping; Liu, Ze-Jin; Li, Yi-Gang; Lu, Ke-Cheng; Zhou, Shou-Huan

    2008-01-01

    An all-single-mode-fiber L-band superfluorescent fiber source (SFS) with 1 W output power, 34.3 nm bandwidth (FWHM) and 54% optical conversion efficiency is constructed by seeding a high power erbium-doped fiber amplifier (EDFA) with a low power L-band ASE seed source to avoid parasitic lasing. The source is resonantly pumped by a high power C-band SFS peaked at 1545 nm.

  3. Observation of central wavelength dynamics in erbium-doped fiber ring laser.

    PubMed

    Xu, Huiwen; Lei, Dajun; Wen, Shuangchun; Fu, Xiquan; Zhang, Jinggui; Shao, Yufeng; Zhang, Lifu; Zhang, Hua; Fan, Dianyuan

    2008-05-12

    We report on the observation of central wavelength dynamics in an erbium-doped fiber ring laser by using the nonlinear polarization rotating technique. The evolution of central wavelength with the laser operation state was observed experimentally. Numerical simulations confirmed the experimental observation and further demonstrated that the dynamics of wavelength evolution is due to the combined effects of fiber birefringence, fiber nonlinearity, and cavity filter.

  4. Active waveguides written by femtosecond laser irradiation in an erbium-doped phospho-tellurite glass.

    PubMed

    Fernandez, T Toney; Della Valle, G; Osellame, R; Jose, G; Chiodo, N; Jha, A; Laporta, P

    2008-09-15

    We report on fs-laser micromachining of active waveguides in a new erbium-doped phospho-tellurite glass by means of a compact cavity-dumped Yb-based writing system. The spectroscopic properties of the glass were investigated, and the fs-laser written waveguides were characterized in terms of passive as well as active performance. In particular, internal gain was demonstrated in the whole C+L band of optical communications (1530- 1610 nm).

  5. Self-similar erbium-doped fiber laser with large normal dispersion.

    PubMed

    Liu, Hui; Liu, Zhanwei; Lamb, Erin S; Wise, Frank

    2014-02-15

    We report a large normal dispersion erbium-doped fiber laser with self-similar pulse evolution in the gain fiber. The cavity is stabilized by the local nonlinear attractor in the gain fiber through the use of a narrow filter. Experimental results are accounted for by numerical simulations. This laser produces 3.5 nJ pulses, which can be dechirped to 70 fs with an external grating pair.

  6. Synthesis and characterization of erbium-doped YAlO3 phosphor.

    PubMed

    Baig, Huma Nazli; Saluja, Jagjeet Kaur; Dhoble, S J

    2016-03-01

    In the yttrium aluminium system, the YAlO3 phosphor is a prominent host because of the yttrium aluminium ratio (1:1). Phosphor was synthesized by the solid-state reaction method at variable concentrations of erbium (0.1-2.5 mol%). This method is suitable for large-scale production and is a less time-consuming method when compared with the soft synthesis method. The prepared sample was characterized by X-ray diffraction technique and the crystallite size was calculated by Scherer's formula. Vibrational and bending analysis of prepared phosphor for optimized concentration of erbium ion is described based on the Fourier transform infrared spectroscopic technique. The photoluminescence (PL) emission spectra of prepared phosphor for variable concentrations of erbium ion were recorded and the excitation spectrum was found to be at 291 nm with three shoulder peaks at 305, 270 and 242 nm. For 291 nm excitation, the emission spectrum was found at 546 nm and 552 nm. PL intensity increased with increasing concentrations of erbium and after 2 mol% emission intensity decreased due to concentration quenching. Spectrophotometric determination of YAlO3:Er(3+) is described by CIE co-ordinates and shows an intense emission in the green region such that the prepared phosphor can act as a single host for green light emission. Thermoluminescence glow curve analysis of the YAlO3:Er(3+) phosphor was recorded for different ultraviolet (UV) light exposures and gamma exposure. Different gamma doses 0.5-2 kGy show a linear response. Kinetic parameters were calculated by the peak shape method.

  7. Investigation on the effect of EDFA location in ring cavity Brillouin-Erbium fiber laser.

    PubMed

    Hambali, Nor Azura Malini A; Mahdi, Mohd Adzir; Al-Mansoori, Mohammed Hayder; Abas, Ahmad Fauzi; Saripan, M Iqbal

    2009-07-01

    We have investigated the characteristics of Brillouin-Erbium fiber laser (BEFL) with variation of Erbium-doped fiber amplifier (EDFA) locations in a ring cavity configuration. Three possible locations of the EDFA in the laser cavity have been studied. The experimental results show that the location of EDFA plays vital role in determining the output power and the tuning range. Besides the Erbium gain, Brillouin gain also contributes to the performance of the BEFL. By placing the EDFA next to the Brillouin gain medium (dispersion compensating fiber), the Brillouin pump signal is amplified thereby generating higher intensities of Brillouin Stokes line. This efficient process suppresses the free running self-lasing cavity modes from oscillating in cavity as a result of higher Stokes laser power and thus provide a wider tuning range. At the injected Brillouin pump power of 1.6 mW and the maximum 1480 nm pump power of 135 mW, the maximum Stokes laser power of 25.1 mW was measured and a tuning range of 50 nm without any self-lasing cavity modes was obtained.

  8. Core-shell nanoparticle erbium-doped fibers for next generation amplifiers

    NASA Astrophysics Data System (ADS)

    Boivin, David; Pastouret, Alain; Burov, Ekaterina; Gonnet, Cédric; Cavani, Olivier; Lempereur, Simon; Sillard, Pierre; Goldmann, Claire; Saudry, Elodie; Chanéac, Corinne; Shlifer, Alex; Ghera, Uri

    2012-02-01

    New generation systems are expected to include more intelligent amplifiers able to adapt to many conditions including different gains, channel load, temperature, aging and transient events.1 To face the challenge and meet these new requirements, having an accurate control on the Er environment within the fiber core matrix has never appeared to be so necessary and predominant as it is the case now. Unlike conventional solution doping techniques where Erbium ions are randomly incorporated in the fiber core, our process makes use of a soft chemical synthesis to initially produce Erbium-doped nanoparticles (NPs). Erbium ions are therefore incorporated in the fiber core together with their local environment. So far, our investigations2 first showed that, from the material point of view, quenching levels are intimately linked to the design of the NPs through their chemical composition. Then, from the system perspective, we evidenced the higher power conversion efficiencies exhibited by NP fibers when compared to their conventional counterparts in high power amplifier configurations. In this paper, we address our most recent work focusing on the NP optimisation towards quenching-free Erbiumdoped fibers with a particular focus on core-shell alumino-silicate NPs. Completing our first amplifier results obtained in high power configurations, we also explore new NP fiber profiles that extend the range of their applications. Gain and noise characteristics of typical WDM operating points serve as key indicators on the benefits our NP doping process could provide.

  9. Efficiency of macroporous poly(vinylphosphoramidic acid) resin adsorbing of selected elements and determination of trace dysprosium, holmium, erbium, and ytterbium in waste water by inductively coupled plasma optical emission spectrometry

    SciTech Connect

    Zhan Guangyao; Su Zhixing; Lou Xingyin; Chang Xijun )

    1992-03-01

    A macroporous poly(vinylphosphoramidic acid) resin is synthesized through the reaction of macroporous poly(vinylethylenediamine) resin with formaldehyde and phosphorus acid. The adsorption efficiency of the resin to selected elements is determined. An ICP-OES method has been established for the resin enrichment and separation of trace Dy, Ho, Er and Yb ions in waste water. The ability of the Na-form resin to adsorb Dy, Ho, Er, and Yb ions is far better than the H-form resin. The IR spectra of the resin before and after adsorbing Dy are shown. The mechanism of resin adsorption of Dy is explored. The results of resin enriched waste water analysis from a smelter plant are 31.0 ng/ml for dy, 41.1 ng/ml for Hl, 20.6 ng/ml for Er and 20.2 ng/ml for Yb ions. The recovery of standard additions of Dy, Ho, Er, and Yb to the waste water is in the range of 97.0-98.5%.

  10. Holmium YLF amplifier performance and the prospects for multi-Joule energies using diode-laser pumping

    NASA Technical Reports Server (NTRS)

    Storm, Mark E.

    1993-01-01

    Laser studies were performed to examine the amplifier characteristics of holmium-doped yttrium lithium fluoride (YLF) at 300 K. An inversion ratio of 0.37 was reached resulting in a measured small-signal gain coefficient of 0.50/cm. In a flashlamp pumping experiment, an output energy of 240 mJ was achieved for 38.5 mJ of input energy resulting in a large gain of 6.2. An amplifier model was developed for diode laser pumping and adapted to consider this flashlamp-pumped case. There is good agreement between the theory and experiment. Multipass amplifier calculations using the model suggest that the Ho: Tm: YLF laser crystal can support a 12 percent electrical to optical efficiency at 300 K even in the presence of upconversion.

  11. Neutron diffraction and electrical transport studies on the incommensurate magnetic phase transition in holmium at high pressures

    SciTech Connect

    Thomas, Sarah; Uhoya, Walter; Tsoi, Georgiy; Wenger, Lowell E; Vohra, Yogesh; Chesnut, Gary Neal; Weir, S. T.; Tulk, Christopher A; Moreira Dos Santos, Antonio F

    2012-01-01

    Neutron diffraction and electrical transport measurements have been made on the heavy rare earth metal holmium at high pressures and low temperatures in order to elucidate its transition from a paramagnetic (PM) to a helical antiferromagnetic (AFM) ordered phase as a function of pressure. The electrical resistance measurements show a change in the resistance slope as the temperature is lowered through the antiferromagnetic Neel temperature. The temperature of this antiferromagnetic transition decreases from approximately 122 K at ambient pressure at a rate of -4.9 K GPa(-1) up to a pressure of 9 GPa, whereupon the PM-to-AFM transition vanishes for higher pressures. Neutron diffraction measurements as a function of pressure at 89 and 110 K confirm the incommensurate nature of the phase transition associated with the antiferromagnetic ordering of the magnetic moments in a helical arrangement and that the ordering occurs at similar pressures as determined from the resistance results for these temperatures.

  12. Neutron diffraction and electrical transport studies on the incommensurate magnetic phase transition in holmium at high pressures.

    PubMed

    Thomas, Sarah A; Uhoya, Walter O; Tsoi, Georgiy M; Wenger, Lowell E; Vohra, Yogesh K; Chesnut, Gary N; Weir, Samuel T; Tulk, Christopher A; dos Santos, Antonio M

    2012-05-30

    Neutron diffraction and electrical transport measurements have been made on the heavy rare earth metal holmium at high pressures and low temperatures in order to elucidate its transition from a paramagnetic (PM) to a helical antiferromagnetic (AFM) ordered phase as a function of pressure. The electrical resistance measurements show a change in the resistance slope as the temperature is lowered through the antiferromagnetic Néel temperature. The temperature of this antiferromagnetic transition decreases from approximately 122 K at ambient pressure at a rate of -4.9 K GPa(-1) up to a pressure of 9 GPa, whereupon the PM-to-AFM transition vanishes for higher pressures. Neutron diffraction measurements as a function of pressure at 89 and 110 K confirm the incommensurate nature of the phase transition associated with the antiferromagnetic ordering of the magnetic moments in a helical arrangement and that the ordering occurs at similar pressures as determined from the resistance results for these temperatures.

  13. Holmium-doped 2.1 μm waveguide chip laser with an output power > 1 W.

    PubMed

    Lancaster, D G; Stevens, V J; Michaud-Belleau, V; Gross, S; Fuerbach, A; Monro, T M

    2015-12-14

    We demonstrate the increasing applicability of compact ultra-fast laser inscribed glass guided-wave lasers and report the highest-power glass waveguide laser with over 1.1 W of output power in monolithic operation in the short-infrared near 2070 nm achieved (51% incident slope efficiency). The holmium doped ZBLAN chip laser is in-band pumped by a 1945 nm thulium fiber laser. When operated in an extended-cavity configuration, over 1 W of output power is realized in a linearly polarized beam. Broad and continuous tunability of the extended-cavity laser is demonstrated from 2004 nm to 2099 nm. Considering its excellent beam quality of M² = 1.08, this laser shows potential as a flexible master oscillator for single frequency and mode-locking applications. PMID:26699055

  14. Thulium/holmium-doped fiber laser passively mode locked by black phosphorus nanoplatelets-based saturable absorber.

    PubMed

    Yu, Hao; Zheng, Xin; Yin, Ke; Cheng, Xiang'ai; Jiang, Tian

    2015-12-01

    By coupling black phosphorus (BP) nanoplatelets (NPs) with a fiber-taper evanescent light field, a saturable absorber (SA) based on the BP NPs has been successfully fabricated and used in a thulium/holmium-doped fiber laser as the mode locker. The SA had a modulation depth of ∼9.8% measured at 1.93 μm. A stable mode-locking operation at 1898 nm was achieved with a pulse width of 1.58 ps and a fundamental mode-lock repetition rate of 19.2 MHz. By increasing the pump intensity, phenomena of multi-pulsing operations, including harmonic mode-locked states and soliton bunches, were obtained in the experiment, showing that the BP NPs possess an ultrafast optical response time. This work suggests that the BP NPs-based SA is potentially useful for ultrashort, pulsed laser operations in the eye-safe region of 2 μm. PMID:26836690

  15. [Endoscopic lithotripsy of a urinary bladder calculus with the aid of a holmium-YAG-laser in a gelding].

    PubMed

    Simhofer, H; Riedelberger, K

    2002-09-01

    A 6 year old Haflinger gelding was presented to the reporting clinics with a history of chronic dysuria. A large cystic calculus (12 x 9 x 9 cm) was diagnosed cystoscopically. Lithotripsy was carried out endoscopically in the standing, sedated patient with a Holmium:YAG surgical laser (2100 nm, 0.5-3.5 J/pulse, 3-60 pulses/sec.). The endoscope was inserted into the bladder via perineal urethrostomy. Fragmentation of the urolith was carried out with a laser fiber (core diameter 600 microns) in contact mode. Healing proceeded uneventfully. On follow up examination 8 weeks post surgery, no signs of recurrence, cystitis or strictures of the urethra were present. PMID:12395576

  16. Holmium YLF amplifier performance and the prospects for multi-Joule energies using diode-laser pumping

    SciTech Connect

    Storm, M.E. )

    1993-02-01

    Laser studies were performed that examined the amplifier characteristics of holmium-doped yttrium lithium fluoride (YLF) at 300 K. An inversion ratio n[sup 5]I[sub 7]/n[sub H0] of 0.37 was reached resulting in a measured small-signal gain coefficient of 0.50 cm[sub [minus]1]. In a flashlamp pumping experiment, an output energy of 240 mJ was achieved for 38.5 Mj of input energy resulting in a large gain of 6.2. An amplifier model was developed for diode laser pumping and adapted to consider this flashlamp-pumped case. There is good agreement between the theory and experiment. Multipass amplifier calculations using the model suggest that the Ho:Tm:YLF laser crystal can support a 12% electrical to optical efficiency at 300 K even in the presence of upconversion.

  17. Effects of a high-power high-energy holmium:YAG laser on human meniscal ablation rates

    NASA Astrophysics Data System (ADS)

    Saadatmanesh, Vahid; Vangsness, C. Thomas; Ghaderi, Bahram; Gong, Naomi F.

    1994-09-01

    Using a pulsed Holmium:YAG laser at a wavelength of 2.1 microns, the ablation rates and thermal effects were measured on human meniscal cartilage. The penetration rate of a fiber under saline was measured as well as the mass loss in an air environment. Fluences were varied between 167 - 927 J/cm2/pulse for the penetration rate experiment and between 38 - 490 J/cm2/pulse for the mass loss experiment. Ablation threshold was found to be 10.6 J/cm2 in air. A double pulsing scheme used to reduce acoustic effects showed equivalent tissue ablation effects. The increases in ablation rates were directly proportional to the increases in pulse fluence for both methods. Histologic examination showed the lateral thermal change to be a maximum of 600 microns in air at 24 pulses per second.

  18. Penetration and mass loss rates with different energy levels in the human meniscus for the holmium:YAG laser

    NASA Astrophysics Data System (ADS)

    Vangsness, C. Thomas; Ghaderi, Bahram; Brustein, Marshall; Sadettmanesh, Vahid; Hawver, Joan

    1993-07-01

    Using a pulsed Holmium:YAG laser, wavelength 2.1 micrometers , the ablation rate and thermal effect were measured on human meniscal cartilage. Holding the pulsewidth and repetition rate constant, fluences per pulse were varied between 167 - 927 J/cm2/pulse for the penetration rate and between 1.7 - 100 J/cm2/pulse for the mass loss rate. The fastest ablation rate was found at 927 J/cm2/pulse for the penetration rate and at 100 J/cm2/pulse for the mass loss rate. The thresholds were 53 J/cm2/pulse and 1.36 J/cm2/pulse, respectively. The increases in ablation rate were directly proportional to increases in fluences for both methods. Histological examination showed the average lateral thermal change to be 400 - 500 micrometers and 400 - 460 micrometers , respectively, with no relation to level of fluence.

  19. Neutron diffraction and electrical transport studies on the incommensurate magnetic phase transition in holmium at high pressures

    NASA Astrophysics Data System (ADS)

    Thomas, Sarah A.; Uhoya, Walter O.; Tsoi, Georgiy M.; Wenger, Lowell E.; Vohra, Yogesh K.; Chesnut, Gary N.; Weir, Samuel T.; Tulk, Christopher A.; dos Santos, Antonio M.

    2012-05-01

    Neutron diffraction and electrical transport measurements have been made on the heavy rare earth metal holmium at high pressures and low temperatures in order to elucidate its transition from a paramagnetic (PM) to a helical antiferromagnetic (AFM) ordered phase as a function of pressure. The electrical resistance measurements show a change in the resistance slope as the temperature is lowered through the antiferromagnetic Néel temperature. The temperature of this antiferromagnetic transition decreases from approximately 122 K at ambient pressure at a rate of -4.9 K GPa-1 up to a pressure of 9 GPa, whereupon the PM-to-AFM transition vanishes for higher pressures. Neutron diffraction measurements as a function of pressure at 89 and 110 K confirm the incommensurate nature of the phase transition associated with the antiferromagnetic ordering of the magnetic moments in a helical arrangement and that the ordering occurs at similar pressures as determined from the resistance results for these temperatures.

  20. Radiotherapeutic bandage based on electrospun polyacrylonitrile containing holmium-166 iron garnet nanoparticles for the treatment of skin cancer.

    PubMed

    Munaweera, Imalka; Levesque-Bishop, Daniel; Shi, Yi; Di Pasqua, Anthony J; Balkus, Kenneth J

    2014-12-24

    Radiation therapy is used as a primary treatment for inoperable tumors and in patients that cannot or will not undergo surgery. Radioactive holmium-166 ((166)Ho) is a viable candidate for use against skin cancer. Nonradioactive holmium-165 ((165)Ho) iron garnet nanoparticles have been incorporated into a bandage, which, after neutron-activation to (166)Ho, can be applied to a tumor lesion. The (165)Ho iron garnet nanoparticles ((165)HoIG) were synthesized and introduced into polyacrylonitrile (PAN) polymer solutions. The polymer solutions were then electrospun to produce flexible nonwoven bandages, which are stable to neutron-activation. The fiber mats were characterized using scanning electron microscopy, transmission electron microscopy, powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis and inductively coupled plasma mass spectrometry. The bandages are stable after neutron-activation at a thermal neutron-flux of approximately 3.5 × 10(12) neutrons/cm(2)·s for at least 4 h and 100 °C. Different amounts of radioactivity can be produced by changing the amount of the (165)HoIG nanoparticles inside the bandage and the duration of neutron-activation, which is important for different stages of skin cancer. Furthermore, the radioactive bandage can be easily manipulated to irradiate only the tumor site by cutting the bandage into specific shapes and sizes that cover the tumor prior to neutron-activation. Thus, exposure of healthy cells to high energy β-particles can be avoided. Moreover, there is no leakage of radioactive material after neutron activation, which is critical for safe handling by healthcare professionals treating skin cancer patients.

  1. Radiotherapeutic bandage based on electrospun polyacrylonitrile containing holmium-166 iron garnet nanoparticles for the treatment of skin cancer.

    PubMed

    Munaweera, Imalka; Levesque-Bishop, Daniel; Shi, Yi; Di Pasqua, Anthony J; Balkus, Kenneth J

    2014-12-24

    Radiation therapy is used as a primary treatment for inoperable tumors and in patients that cannot or will not undergo surgery. Radioactive holmium-166 ((166)Ho) is a viable candidate for use against skin cancer. Nonradioactive holmium-165 ((165)Ho) iron garnet nanoparticles have been incorporated into a bandage, which, after neutron-activation to (166)Ho, can be applied to a tumor lesion. The (165)Ho iron garnet nanoparticles ((165)HoIG) were synthesized and introduced into polyacrylonitrile (PAN) polymer solutions. The polymer solutions were then electrospun to produce flexible nonwoven bandages, which are stable to neutron-activation. The fiber mats were characterized using scanning electron microscopy, transmission electron microscopy, powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis and inductively coupled plasma mass spectrometry. The bandages are stable after neutron-activation at a thermal neutron-flux of approximately 3.5 × 10(12) neutrons/cm(2)·s for at least 4 h and 100 °C. Different amounts of radioactivity can be produced by changing the amount of the (165)HoIG nanoparticles inside the bandage and the duration of neutron-activation, which is important for different stages of skin cancer. Furthermore, the radioactive bandage can be easily manipulated to irradiate only the tumor site by cutting the bandage into specific shapes and sizes that cover the tumor prior to neutron-activation. Thus, exposure of healthy cells to high energy β-particles can be avoided. Moreover, there is no leakage of radioactive material after neutron activation, which is critical for safe handling by healthcare professionals treating skin cancer patients. PMID:25396281

  2. Optimizing the pumping configuration for the power scaling of in-band pumped erbium doped fiber amplifiers.

    PubMed

    Lim, Ee-Leong; Alam, Shaif-ul; Richardson, David J

    2012-06-18

    A highly efficient (~80%), high power (18.45 W) in-band, core pumped erbium/ytterbium co-doped fiber laser is demonstrated. To the best of our knowledge, this is the highest reported efficiency from an in-band pumped 1.5 µm fiber laser operating in the tens of watts regime. Using a fitted simulation model, we show that the significantly sub-quantum limit conversion efficiency of in-band pumped erbium doped fiber amplifiers observed experimentally can be explained by concentration quenching. We then numerically study and experimentally validate the optimum pumping configuration for power scaling of in-band, cladding pumped erbium doped fiber amplifiers. Our simulation results indicate that a ~77% power conversion efficiency with high output power should be possible through cladding pumping of current commercially available pure Erbium doped active fibers providing the loss experienced by the cladding guided 1535 nm pump due to the coating absorption can be reduced to an acceptable level by better coating material choice. The power conversion efficiency has the potential to exceed 90% if concentration quenching of erbium ions can be reduced via improvements in fiber design and fabrication.

  3. Sintering effects on structure, morphology, and electrical properties of sol-gel synthesized, nano-crystalline erbium oxide

    NASA Astrophysics Data System (ADS)

    Bakhsh, Allah; Maqsood, Asghari

    2012-12-01

    The nano-crystalline erbium oxide powder was synthesized through the sol-gel technique. The effect of sintering temperature from 250°C to 1400°C on structure, morphology, and electrical properties was studied. The results were compared with the microcrystalline erbium oxide purchased from the market. The synthesized erbium oxide showed fiber like nanostructures. Dielectric properties at different sintering temperatures were measured in the frequency range 100 Hz to 5MHz. The synthesized erbium oxide had the highest dielectric constant at 650°C. The behavior of the dissipation factor tan δ for sol-gel synthesized material was distinct from that of the purchased material; it was higher at low frequencies and then decreased with the increase in frequency. The synthesized material sintered at different temperatures exhibited a similar sort of frequency-dependent response for permittivity (ɛ) and resistivity ( ρ). This was in accordance with Koop's theory of dielectrics. For the microcrystalline material, frequency dependence of permittivity and resistivity was not uniform. The results showed that sol-gel synthesized erbium oxide could be a good candidate for high-k applications.

  4. Surface segregation effects of erbium in GaAs growth and their implications for optical devices containing ErAs nanostructures

    SciTech Connect

    Crook, Adam M.; Nair, Hari P.; Bank, Seth R.

    2011-03-21

    We report on the integration of semimetallic ErAs nanoparticles with high optical quality GaAs-based semiconductors, grown by molecular beam epitaxy. Secondary ion mass spectrometry and photoluminescence measurements provide evidence of surface segregation and incorporation of erbium into layers grown with the erbium cell hot, despite the closed erbium source shutter. We establish the existence of a critical areal density of the surface erbium layer, below which the formation of ErAs precipitates is suppressed. Based upon these findings, we demonstrate a method for overgrowing ErAs nanoparticles with III-V layers of high optical quality, using subsurface ErAs nanoparticles as a sink to deplete the surface erbium concentration. This approach provides a path toward realizing optical devices based on plasmonic effects in an epitaxially-compatible semimetal/semiconductor system.

  5. Structures and spectroscopic characterization of calcium chloride-nicotinamide, -isonicotinamide, -picolinamide and praseodymium bromide-nicotinamide complexes

    NASA Astrophysics Data System (ADS)

    Xue, Junhui; Jiang, Ye; Li, Weihong; Yang, Limin; Xu, Yizhuang; Zhao, Guozhong; Zhang, Gaohui; Bu, Xiaoxia; Liu, Kexin; Chen, Jia'er; Wu, Jinguang

    2015-02-01

    The coordination structures formed by calcium complexes with nicotinamide (na), isonicotinamide (ina) and picolinamide (pa) and praseodymium bromide-na are reported. The structures of CaCl2·(C6H6N2O)2·2H2O (Ca-na), CaCl2·(C6H6N2O)2·4H2O (Ca-ina), CaCl2·(C6H6N2O)2·5H2O (Ca-pa) and PrBr3·(C6H6N2O)2·6H2O (PrBr-na) in the solid state have been characterized by X-ray single crystal diffraction, FTIR, FIR, THz and Raman spectroscopies. Carbonyl oxygen of nicotinamide is coordinated to Ca2+, but it is O-monodentate (carbonyl oxygen) and N,O-bidentate ligand (pyridyl nitrogen and carbonyl oxygen) for Pr3+ to form a chain structure in PrBr-na. For isonicotinamide, only carbonyl oxygen atom is coordinated to Ca2+. Pyridyl nitrogen and carbonyl oxygen of picolinamide are coordinated to Ca2+ to form a five-membered ring structure. The crystal structure and spectroscopic results indicate the differences of the coordination of Ca and Pr ions, the changes of hydrogen bonds and conformation of the ligands induced by complexation. Unlike transition metal ions, Sr2+ or lanthanide ions, Ca2+ is inclined to coordinate to carbonyl oxygen atoms of the ligands.

  6. NMR study of the interaction of beta-blockers with sonicated dimyristoylphosphatidylcholine liposomes in the presence of praseodymium cation.

    PubMed

    Betageri, G V; Theriault, Y; Rogers, J A

    1989-01-01

    The interaction of a series of beta-adrenoreceptor blocking agents with unilamellar dimyristoylphosphatidylcholine (DMPC) liposomes has been studied by proton nuclear magnetic resonance (1H-NMR) in the presence of praseodymium cation (Pr3+) at 30 degrees C. Addition of Pr3+ increased the splitting of the trimethylammonium group signals arising from the phospholipid molecules located at the internal and external surfaces of the bilayers. Adding Pr3+ caused a considerable downfield shift of the external peak but only a slight upfield shift of the internal peak (approximately 3%). The difference in chemical shift of the external and internal peaks (delta Hz) increased linearly as a function of Pr3+ concentration up to 10 mM. The addition of beta-blockers reversed the effect of Pr3+, and propranolol exerted the most pronounced effect, causing complete reversal of the splitting at a concentration of 5 mM. Much higher concentrations of other beta-blockers were required to displace Pr3+. A linear correlation between Pr3+ displacement (P) and logarithm of the apparent partition coefficient (K'm) in DMPC liposomes was obtained for hydrophobic beta-blockers, but hydrophilic beta-blockers did not fit this correlation. It appears that beta-blockers that have ortho or meta substitution require penetration of the liposome bilayers before significant polar group interaction can occur. On the other hand, beta-blockers that have para substitution and low K'm values are able to interact with the polar surfaces of the liposomes without penetration to cause displacement of Pr3+.

  7. Structures and spectroscopic characterization of calcium chloride-nicotinamide, -isonicotinamide, -picolinamide and praseodymium bromide-nicotinamide complexes.

    PubMed

    Xue, Junhui; Jiang, Ye; Li, Weihong; Yang, Limin; Xu, Yizhuang; Zhao, Guozhong; Zhang, Gaohui; Bu, Xiaoxia; Liu, Kexin; Chen, Jia'er; Wu, Jinguang

    2015-02-25

    The coordination structures formed by calcium complexes with nicotinamide (na), isonicotinamide (ina) and picolinamide (pa) and praseodymium bromide-na are reported. The structures of CaCl2·(C6H6N2O)2·2H2O (Ca-na), CaCl2·(C6H6N2O)2·4H2O (Ca-ina), CaCl2·(C6H6N2O)2·5H2O (Ca-pa) and PrBr3·(C6H6N2O)2·6H2O (PrBr-na) in the solid state have been characterized by X-ray single crystal diffraction, FTIR, FIR, THz and Raman spectroscopies. Carbonyl oxygen of nicotinamide is coordinated to Ca(2+), but it is O-monodentate (carbonyl oxygen) and N,O-bidentate ligand (pyridyl nitrogen and carbonyl oxygen) for Pr(3+) to form a chain structure in PrBr-na. For isonicotinamide, only carbonyl oxygen atom is coordinated to Ca(2+). Pyridyl nitrogen and carbonyl oxygen of picolinamide are coordinated to Ca(2+) to form a five-membered ring structure. The crystal structure and spectroscopic results indicate the differences of the coordination of Ca and Pr ions, the changes of hydrogen bonds and conformation of the ligands induced by complexation. Unlike transition metal ions, Sr(2+) or lanthanide ions, Ca(2+) is inclined to coordinate to carbonyl oxygen atoms of the ligands.

  8. Lanthanum, cerium, praseodymium and yttrium in waters in an upland acidic and acid sensitive environment, mid-Wales

    NASA Astrophysics Data System (ADS)

    Nea, C.

    2005-12-01

    The less than 0.45 mm filterable lanthanum (La), cerium (Ce), praseodymium (Pr) and yttrium (Y) concentrations in rainfall, cloud water, stream and groundwater in the upper River Severn catchments of mid-Wales are presented, based on up to ten years of weekly data. Results show that for rainfall, there is enrichment in the rare earth (RE) elements, especially under conditions of small volume of catch. However, within the correlations, there is a 'forked' relationship, with one line of high La, Ce and Pr with low Y, corresponding to clear pollutant events and the other with relatively low La, Ce and Pr and higher Y to background conditions. Cloud water and stream waters show a simpler relationship indicating two types of source. Cloud, stream and ground water show no split in pattern, with singular linear relationships between the rare La, Ce, Pr and Y. However, in many cases the monitoring of the streams and groundwaters post-dates the rainfall period with high pollutant Ce inputs. RE element concentrations vary systematically, in general decreasing with increasing volume of catch for cloud-water. For the streams, occasionally, there are relatively high Ce and La concentrations (up to about a tenth the maximum in rainfall), which occur in the same year as the corresponding high values in rainfall. Apart from these anomalous periods, RE element concentrations increase with decreasing pH and increasing aluminium concentrations; RE elements are mobilised under acidic conditions. The river waters are particularly enriched in Y relative to La, Ce and Pr, both in terms of average concentrations and values normalised to standard continental shales. The RE element level in the streams is variable and seems to be linked to the main soil types within the catchment; gleys in particular show higher concentrations than their peat and podzolic counterparts. On average, groundwaters are enriched in the RE elements relative to the stream but the link with pH and aluminium observed

  9. Structures and spectroscopic characterization of calcium chloride-nicotinamide, -isonicotinamide, -picolinamide and praseodymium bromide-nicotinamide complexes.

    PubMed

    Xue, Junhui; Jiang, Ye; Li, Weihong; Yang, Limin; Xu, Yizhuang; Zhao, Guozhong; Zhang, Gaohui; Bu, Xiaoxia; Liu, Kexin; Chen, Jia'er; Wu, Jinguang

    2015-02-25

    The coordination structures formed by calcium complexes with nicotinamide (na), isonicotinamide (ina) and picolinamide (pa) and praseodymium bromide-na are reported. The structures of CaCl2·(C6H6N2O)2·2H2O (Ca-na), CaCl2·(C6H6N2O)2·4H2O (Ca-ina), CaCl2·(C6H6N2O)2·5H2O (Ca-pa) and PrBr3·(C6H6N2O)2·6H2O (PrBr-na) in the solid state have been characterized by X-ray single crystal diffraction, FTIR, FIR, THz and Raman spectroscopies. Carbonyl oxygen of nicotinamide is coordinated to Ca(2+), but it is O-monodentate (carbonyl oxygen) and N,O-bidentate ligand (pyridyl nitrogen and carbonyl oxygen) for Pr(3+) to form a chain structure in PrBr-na. For isonicotinamide, only carbonyl oxygen atom is coordinated to Ca(2+). Pyridyl nitrogen and carbonyl oxygen of picolinamide are coordinated to Ca(2+) to form a five-membered ring structure. The crystal structure and spectroscopic results indicate the differences of the coordination of Ca and Pr ions, the changes of hydrogen bonds and conformation of the ligands induced by complexation. Unlike transition metal ions, Sr(2+) or lanthanide ions, Ca(2+) is inclined to coordinate to carbonyl oxygen atoms of the ligands. PMID:25280333

  10. Specific features of the mechanisms of excitation of erbium photoluminescence in epitaxial Si:Er/Si structures

    SciTech Connect

    Yablonskiy, A. N. Andreev, B. A.; Krasilnikova, L. V.; Kryzhkov, D. I.; Kuznetsov, V. P.; Krasilnik, Z. F.

    2010-11-15

    The excitation spectra and kinetics of erbium photoluminescence and silicon interband photoluminescence in Si:Er/Si structures under conditions of high-intensity pulse optical excitation are studied. It is shown that, in the interband photoluminescence spectra of the Si:Er/Si structures, both the luminescence of free excitons and the emission associated with the electron-hole plasma can be observed, depending on the excitation power and wavelength. It is found that the formation of a peak in the erbium photoluminescence excitation spectra at high pumping powers correlates with the Mott transition from the exciton gas to the electron-hole plasma. It is demonstrated that, in the Si:Er/Si structures, the characteristic rise times of erbium photoluminescence substantially depend on the concentration of charge carriers.

  11. C- and L-band erbium-doped waveguide lasers with wafer-scale silicon nitride cavities.

    PubMed

    Purnawirman; Sun, J; Adam, T N; Leake, G; Coolbaugh, D; Bradley, J D B; Shah Hosseini, E; Watts, M R

    2013-06-01

    We report on integrated erbium-doped waveguide lasers designed for silicon photonic systems. The distributed Bragg reflector laser cavities consist of silicon nitride waveguide and grating features defined by wafer-scale immersion lithography and a top erbium-doped aluminum oxide layer deposited as the final step in the fabrication process. The resulting inverted ridge waveguide yields high optical intensity overlap with the active medium for both the 0.98 μm pump (89%) and 1.5 μm laser (87%) wavelengths with a pump-laser intensity overlap of >93%. We obtain output powers of up to 5 mW and show lasing at widely spaced wavelengths within both the C and L bands of the erbium gain spectrum (1536, 1561, and 1596 nm).

  12. Effect of praseodymium on the electrical resistance of YВа2Сu3О7-δ single crystals

    NASA Astrophysics Data System (ADS)

    Vovk, R. V.; Vovk, N. R.; Khadzhai, G. Ya.; Goulatis, I. L.; Chroneos, A.

    2014-07-01

    The electrical resistivity in the ab-plane of the Y1-yPryВа2Сu3О7-δ single crystals with high degree of perfection in the interval of Тc - 300 K was investigated. The increasing of praseodymium content leads to the reduction of the critical temperature (Tc) from 92 to 30 K. The experimental results can be approximated by the expression, taking into account the scattering of electrons by phonons, defects, the fluctuation conductivity in the 3D Aslamazov-Larkin model, as well as the transition to a "semiconductor" type behavior of the resistivity at the high praseodymium concentrations. The concentration dependences of all fitting parameters indicate a structural transition in the region 0.35≤у≤0.43. In particular, the Debye temperature changes in this range from 350 to 550 K, and the transverse coherence length passes through a maximum ξС(0)≈5 Å. The concentration dependence of the critical temperature testifies the d-pairing of the BCS model.

  13. Widely ultra-narrow linewidth 104 nm tunable all-fiber compact erbium-doped ring laser

    NASA Astrophysics Data System (ADS)

    Zhong, F. F.; Xu, Y.; Zhang, Y. J.; Ju, Y.

    2011-01-01

    A widely tunable narrow linewidth compact erbium-doped all-fiber ring laser with 104 nm tuning range was reported. An all-fiber Fabry-Perot filter (FFP-TF) was used to realize the laser tuning output, and the wavelength at constant voltage had high time stability. With the 8 m length erbium-doped fiber as gain medium, we realized widely tunable laser from 1513 to 1617 nm with the linewidth less than 40 pm at any wavelength. Pumped by the 976 nm laser diode, the fiber laser worked with slope efficiency of above 10% and threshold of less than 21 mW.

  14. Luminescent amino-functionalized or erbium-doped silica spheres for biological applications.

    PubMed

    Enrichi, Francesco

    2008-01-01

    This work presents the morphological and optical properties of luminescent silica spheres, discussing applications in bioimaging and biosensing. The spheres are obtained by the hydrolysis and condensation of tetraethylorthosilicate (TEOS) and can be synthesized by following either a basic or an acidic route. Luminescence emission is induced after incorporation of aminopropyltriethoxysilane (APTES) during synthesis or by introducing an optically active element, such as erbium, or other rare-earth elements. The luminescence properties of APTES-functionalized silica spheres have been investigated and optimized by varying the annealing temperature. On the other hand, erbium incorporation in silica spheres was also studied and the corresponding Er(3+) luminescence emission at 1.54 microm was evaluated for intensity and lifetime. The basic pH environment in the synthesis allows good control of the size of the spheres (approximately 200 nm in diameter), whereas the acidic route produces a wide dispersion in particle size (200-5000 nm). Both these approaches, however, can be followed to obtain an efficient photoluminescence (PL) emission for the APTES-functionalized silica spheres after 400-600 degrees C thermal treatment. If Er(NO(3))(3) is introduced in the basic solution, a rapid precipitation of Er(OH)(3) occurs, but erbium can be easily and efficiently incorporated in the acid-synthesized spheres, showing high PL intensity at 1.54 microm with lifetime of 3.9 ms. Finally, I discuss perspectives for the applications of these luminescent silica spheres, in particular as biological markers for bioimaging and biosensing.

  15. Performance characterization of new erbium-doped fibers using MCVD nanoparticle doping process

    NASA Astrophysics Data System (ADS)

    Boivin, David; Pastouret, Alain; Burov, Ekaterina; Gonnet, Cédric; Cavani, Olivier; Lempereur, Simon; Sillard, Pierre

    2011-02-01

    In 2009, we introduced a new doping concept involving Al2O3/rare-earth nanoparticles (NP) in a MCVD-compatible process finding potential applications in Erbium-, Ytterbium- or Erbium-Ytterbium-doped fiber amplifiers and lasers.1 This approach, motivated by the need for increased efficiencies and improved attributes, is characterized by the ability to control the rare-earth ion environment independently from the core composition. The NP matrix can therefore be viewed as an optimized sub-micronic amplifying medium for the embedded rareearth ion. The first experimental evidence to support this idea is reported in a comparative study with a standard process2 where homogeneous up-conversion (HUC) and pair-induced quenching (PIQ) levels are extracted from Er3+ unsaturable absorption measurements. NP-based fibers are found to mitigate the effects of the Er3+ concentration increase seen in standard heavily-doped fibers. This conclusion is particularly clear when focusing on the HUC coefficient evolution since, for a given type of NP, its level is independent from the Er3+ concentration in the doped zone. In this paper, we address our most recent work completing these preliminary results. First, we investigate the quenching signature of a new NP design and its behavior when incorporated in different core matrices. The interplay is further analysed by relating this set of measurements to practical EDFA performances. Gain and noise characteristics of typical WDM amplifiers operating points serve as key benchmarking indicators to identify the benefits of NP Erbium-doped fibers in the wide variety of EDFAs implementations.

  16. Implementation of Lean System on Erbium Doped Fibre Amplifier Manufacturing Process to Reduce Production Time

    NASA Astrophysics Data System (ADS)

    Maneechote, T.; Luangpaiboon, P.

    2010-10-01

    A manufacturing process of erbium doped fibre amplifiers is complicated. It needs to meet the customers' requirements under a present economic status that products need to be shipped to customers as soon as possible after purchasing orders. This research aims to study and improve processes and production lines of erbium doped fibre amplifiers using lean manufacturing systems via an application of computer simulation. Three scenarios of lean tooled box systems are selected via the expert system. Firstly, the production schedule based on shipment date is combined with a first in first out control system. The second scenario focuses on a designed flow process plant layout. Finally, the previous flow process plant layout combines with production schedule based on shipment date including the first in first out control systems. The computer simulation with the limited data via an expected value is used to observe the performance of all scenarios. The most preferable resulted lean tooled box systems from a computer simulation are selected to implement in the real process of a production of erbium doped fibre amplifiers. A comparison is carried out to determine the actual performance measures via an analysis of variance of the response or the production time per unit achieved in each scenario. The goodness of an adequacy of the linear statistical model via experimental errors or residuals is also performed to check the normality, constant variance and independence of the residuals. The results show that a hybrid scenario of lean manufacturing system with the first in first out control and flow process plant lay out statistically leads to better performance in terms of the mean and variance of production times.

  17. Investigation of dynamic properties of erbium fiber laser for ultrasonic sensing.

    PubMed

    Wu, Qi; Okabe, Yoji; Sun, Junqiang

    2014-04-01

    Dynamic properties of an erbium fiber laser (EFL) is researched and demonstrated for ultrasonic sensing in this research. The EFL has ring cavity incorporated with a phase-shifted fiber Bragg grating. A numerical model is used to analyze its dynamic responses to quasi-static change, continuous wave and burst wave. The ultrasonic behavior of the EFL resembles the forced single degree of freedom vibration with damping. Corresponding experimental results fit the simulation results well, showing some interesting ultrasonic properties of this EFL. After certain data process method, this EFL can be used in practical ultrasonic nondestructive testing.

  18. Waveform reconstruction for an ultrasonic fiber Bragg grating sensor demodulated by an erbium fiber laser.

    PubMed

    Wu, Qi; Okabe, Yoji

    2015-02-01

    Fiber Bragg grating (FBG) demodulated by an erbium fiber laser (EFL) has been used for ultrasonic detection recently. However, due to the inherent relaxation oscillation (RO) of the EFL, the detected ultrasonic signals have large deformations, especially in the low-frequency range. We proposed a novel data processing method to reconstruct an actual ultrasonic waveform. The noise spectrum was smoothed first; the actual ultrasonic spectrum was then obtained by deconvolution in order to mitigate the influence of the RO of the EFL. We proved by experiment that this waveform reconstruction method has high precision, and demonstrated that the FBG sensor demodulated by the EFL will have large practical applications in nondestructive testing.

  19. Pulpal response to cavity preparation by an erbium, chromium:YSGG laser-powered hydrokinetic system.

    PubMed

    Eversole, L R; Rizoiu, I; Kimmel, A I

    1997-08-01

    The near red-pulsed erbium, chromium:yttrium-scandium-gallium-garnet laser hydrokinetic system, or Er,Cr:YSGG laser HKS, is effective in cutting dental hard tissues. In this longitudinal study, the authors studied the continuously erupting open-apex incisors of New Zealand albino rabbits and the constricted apex teeth of beagles to determine the effects of HKS-produced lesions at various energy levels and of preparations produced by a tapered fissure bur on dental pulp. No pulpal inflammatory responses could be identified either immediately or 30 days after surgery in HKS preparations that removed enamel and dentin without pulp exposure.

  20. Preparative scale separation of thulium from erbium for neutron capture cross section measurements - Part: Preparative scale

    DOE PAGES

    Birnbaum, Eva R.; Bene, Balazs J.; Taylor, Wayne Allen; Sudowe, Ralf

    2016-06-04

    Here, this paper discusses the development of a separation method for isolation of 171Tm from a half-gram irradiated erbium target in support of stockpile stewardship and astrophysics research. The developed procedure is based on cation exchange separation using alpha-hydroxyisobutyric acid (α-HIBA) as chelating agent. It is able to achieve either a decontamination factor of 1.4(4) × 105 with 68.9(3) % recovery or 95.4(3) % recovery with a decontamination factor of 5.82(7) × 103 for a mock 500-mg target containing 17.9 mg thulium in a single pass-through at room temperature.

  1. Transient gain and cross talk in erbium-doped fiber amplifiers.

    PubMed

    Giles, C R; Desurvire, E; Simpson, J R

    1989-08-15

    Transient gain saturation and recovery with 110-340-microsec time constants were observed in erbium-doped fiber amplifiers. This slow response reduces the effects of saturation-induced cross talk and intermodulation distortion associated with multichannel signal amplification. In a two-channel amplification experiment, negligible saturation-induced cross talk was measured at signal modulation frequencies >5 kHz. Increased suppression of saturation-induced cross talk was achieved through feed-forward compensation to reduce low-frequency gain fluctuations. PMID:19752999

  2. S- plus C-band erbium-doped fiber amplifier in parallel structure

    NASA Astrophysics Data System (ADS)

    Yeh, Chien-Hung; Lee, Chien-Chung; Chi, Sien

    2004-11-01

    A new S- plus C-band erbium-doped fiber amplifier (EDFA) module with coupled structure over 96 nm gain bandwidth of 1480-1576 nm has been experimentally investigated and demonstrated. For this proposed configuration, 30 and 36.2 dB peak gains are observed at 1506 and 1532 nm, respectively, when the input signal power is -25 dBm. In addition, this proposed amplifier module also can provide a broadband amplified spontaneous emission (ASE) light source from 1480 to 1572 nm.

  3. Visible continuum generation using a femtosecond erbium-doped fiber laser and a silica nonlinear fiber.

    PubMed

    Nicholson, J W; Bise, R; Alonzo, J; Stockert, T; Trevor, D J; Dimarcello, F; Monberg, E; Fini, J M; Westbrook, P S; Feder, K; Grüner-Nielsen, L

    2008-01-01

    Supercontinuum extending to visible wavelengths is generated in a hybrid silica nonlinear fiber pumped at 1560 nm by a femtosecond, erbium-doped fiber laser. The hybrid nonlinear fiber consists of a short length of highly nonlinear, germano-silicate fiber (HNLF) spliced to a length of photonic crystal fiber (PCF). A 2 cm length of HNLF provides an initial stage of continuum generation due to higher-order soliton compression and dispersive wave generation before launching into the PCF. The visible radiation is generated in the fundamental mode of the PCF. PMID:18157247

  4. Microprocessing of human hard tooth tissues surface by mid-infrared erbium lasers radiation

    NASA Astrophysics Data System (ADS)

    Belikov, Andrey V.; Shatilova, Ksenia V.; Skrypnik, Alexei V.

    2015-03-01

    A new method of hard tooth tissues laser treatment is described. The method consists in formation of regular microdefects on tissue surface by mid-infrared erbium laser radiation with propagation ratio M2<2 (Er-laser microprocessing). Proposed method was used for preparation of hard tooth tissues surface before filling for improvement of bond strength between tissues surface and restorative materials, microleakage reduction between tissues surface and restorative materials, and for caries prevention as a result of increasing microhardness and acid resistance of tooth enamel.

  5. Erbium-doped yttrium aluminium garnet ablative laser treatment for endogenous ochronosis.

    PubMed

    Chaptini, Cassandra; Huilgol, Shyamala C

    2015-08-01

    Ochronosis is a rare disease characterised clinically by bluish-grey skin discolouration and histologically by yellow-brown pigment deposits in the dermis. It occurs in endogenous and exogenous forms. Endogenous ochronosis, also known as alkaptonuria, is an autosomal recessive disease of tyrosine metabolism, resulting in the accumulation and deposition of homogentisic acid in connective tissue. We report a case of facial endogenous ochronosis and coexistent photodamage, which was successfully treated with erbium-doped yttrium aluminium garnet laser resurfacing and deep focal point treatment to remove areas of residual deep pigment.

  6. Gain-controlled erbium-doped fiber amplifier using mode-selective photonic lantern

    NASA Astrophysics Data System (ADS)

    Lopez-Galmiche, G.; Sanjabi Eznaveh, Z.; Antonio-Lopez, J. E.; Velazquez-Benitez, A. M.; Rodriguez-Asomoza, J.; Herrera-Piad, L. A.; Sanchez-Mondragon, J. J.; Gonent, C.; Sillard, P.; Li, G.; SchuÌlzgen, A.; Okonkwo, C.; Amezcua Correa, R.

    2016-02-01

    For the first time, we demonstrate the implementation of a core pumped few mode erbium amplifier utilizing a mode selective photonic lantern for spatial modal control of the pump light. This device is able to individually amplify the first six fiber modes with low differential modal gain. In addition, we obtained differential modal gain lower than 1 dB and signal gain of approximately 16.17 dB at λs = 1550 nm through forward pumping the LP21 modes at λp = 976 nm.

  7. Investigation of dynamic properties of erbium fiber laser for ultrasonic sensing.

    PubMed

    Wu, Qi; Okabe, Yoji; Sun, Junqiang

    2014-04-01

    Dynamic properties of an erbium fiber laser (EFL) is researched and demonstrated for ultrasonic sensing in this research. The EFL has ring cavity incorporated with a phase-shifted fiber Bragg grating. A numerical model is used to analyze its dynamic responses to quasi-static change, continuous wave and burst wave. The ultrasonic behavior of the EFL resembles the forced single degree of freedom vibration with damping. Corresponding experimental results fit the simulation results well, showing some interesting ultrasonic properties of this EFL. After certain data process method, this EFL can be used in practical ultrasonic nondestructive testing. PMID:24718214

  8. Erbium nanoparticle doped fibers for efficient, resonantly-pumped Er-doped fiber lasers

    NASA Astrophysics Data System (ADS)

    Friebele, E. Joseph; Baker, Colin C.; Askins, Charles G.; Fontana, Jake P.; Hunt, Michael P.; Peele, John R.; Marcheschi, Barbara A.; Oh, Euneku; Kim, Woohong; Sanghera, Jasbinder; Zhang, Jun; Pattnaik, Radha K.; Merkle, Larry D.; Dubinskii, Mark

    2015-03-01

    Nanoparticle (NP) doping is a new technique for making erbium-doped fibers (EDFs); the Er ions are surrounded by a cage of aluminum and oxygen ions, substantially reducing Er3+ ion-ion energy exchange and its deleterious effects on laser performance. Er-Al-doped NPs have been synthesized and doped in-situ into the silica soot of the preform core. We report the first known measurements of NP-doped EDFs in a resonantly-core pumped master oscillator-power amplifier (MOPA) configuration; the optical-to-optical slope efficiency was 80.4%, which we believe is a record for this type of fiber.

  9. Performance analysis of bi-directional broadband passive optical network using erbium-doped fiber amplifier

    NASA Astrophysics Data System (ADS)

    Almalaq, Yasser; Matin, Mohammad A.

    2014-09-01

    The broadband passive optical network (BPON) has the ability to support high-speed data, voice, and video services to home and small businesses customers. In this work, the performance of bi-directional BPON is analyzed for both down and up streams traffic cases by the help of erbium doped fiber amplifier (EDFA). The importance of BPON is reduced cost. Because PBON uses a splitter the cost of the maintenance between the providers and the customers side is suitable. In the proposed research, BPON has been tested by the use of bit error rate (BER) analyzer. BER analyzer realizes maximum Q factor, minimum bit error rate, and eye height.

  10. Effects of erbium doping of indium tin oxide electrode in resistive random access memory

    NASA Astrophysics Data System (ADS)

    Chen, Po-Hsun; Chang, Kuan-Chang; Chang, Ting-Chang; Tsai, Tsung-Ming; Pan, Chih-Hung; Lin, Chih-Yang; Jin, Fu-Yuan; Chen, Min-Chen; Huang, Hui-Chun; Lo, Ikai; Zheng, Jin-Cheng; Sze, Simon M.

    2016-03-01

    Identical insulators and bottom electrodes were fabricated and capped by an indium tin oxide (ITO) film, either undoped or doped with erbium (Er), as a top electrode. This distinctive top electrode dramatically altered the resistive random access memory (RRAM) characteristics, for example, lowering the operation current and enlarging the memory window. In addition, the RESET voltage increased, whereas the SET voltage remained almost the same. A conduction model of Er-doped ITO is proposed through current-voltage (I-V) measurement and current fitting to explain the resistance switching mechanism of Er-doped ITO RRAM and is confirmed by material analysis and reliability tests.

  11. Pulpal response to cavity preparation by an erbium, chromium:YSGG laser-powered hydrokinetic system.

    PubMed

    Eversole, L R; Rizoiu, I; Kimmel, A I

    1997-08-01

    The near red-pulsed erbium, chromium:yttrium-scandium-gallium-garnet laser hydrokinetic system, or Er,Cr:YSGG laser HKS, is effective in cutting dental hard tissues. In this longitudinal study, the authors studied the continuously erupting open-apex incisors of New Zealand albino rabbits and the constricted apex teeth of beagles to determine the effects of HKS-produced lesions at various energy levels and of preparations produced by a tapered fissure bur on dental pulp. No pulpal inflammatory responses could be identified either immediately or 30 days after surgery in HKS preparations that removed enamel and dentin without pulp exposure. PMID:9260419

  12. Poor fluorinated graphene sheets carboxymethylcellulose polymer composite mode locker for erbium doped fiber laser

    SciTech Connect

    Mou, Chengbo E-mail: a.rozhin@aston.ac.uk; Turitsyn, Sergei; Rozhin, Aleksey E-mail: a.rozhin@aston.ac.uk; Arif, Raz; Lobach, Anatoly S.; Spitsina, Nataliya G.; Khudyakov, Dmitry V.; Kazakov, Valery A.

    2015-02-09

    We report poor fluorinated graphene sheets produced by thermal exfoliation embedding in carboxymethylcellulose polymer composite (GCMC) as an efficient mode locker for erbium doped fiber laser. Two GCMC mode lockers with different concentration have been fabricated. The GCMC based mode locked fiber laser shows stable soliton output pulse shaping with repetition rate of 28.5 MHz and output power of 5.5 mW was achieved with the high concentration GCMC, while a slightly higher output power of 6.9 mW was obtained using the low concentration GCMC mode locker.

  13. Erbium Doping Effects on the Conduction Band Edge in Germanium Nanocrystals

    SciTech Connect

    Meulenberg, Robert W.; Willey, Trevor M.; Lee, Jonathan R.; Terminello, Louis J.; Van Buren, T.

    2011-05-16

    We have produced erbium-doped germanium nanocrystals (NCs) using a new two cell physical vapor deposition system. Using element specific x-ray techniques (absorption and photoemission), we are able to probe the chemical environment of Er in the Ge NCs. Evidence for the optically active Er3+ state is seen at low Er concentrations, with a disruption of NC formation at high Er concentrations. The x-ray absorption measurements suggest that the Er occupies lattice sites near the surface of the NC. Analysis of the quantum confinement effect with Er doping suggests that the native quantum properties of the Ge NC are maintained at low Er concentrations.

  14. Multi-wavelength laser generation with Bismuthbased Erbium-doped fiber.

    PubMed

    Ahmad, H; Shahi, S; Harun, S W

    2009-01-01

    A multi-wavelength laser comb is demonstrated using a nonlinear effect in a backward pumped Bismuth-based Erbium-doped fiber (Bi-EDF) for the first time. It uses a ring cavity resonator scheme containing a 215 cm long highly nonlinear Bi-EDF, optical isolators, polarisation controller and 10 dB output coupler. The laser generates more than 10 lines of optical comb with a line spacing of approximately 0.41 nm at 1615.5 nm region using 146 mW of 1480 nm pump power.

  15. A tunable erbium-doped fiber ring laser with power-equalized output

    NASA Astrophysics Data System (ADS)

    Yeh, Chien-Hung; Lin, Ming-Ching; Chi, Sien

    2006-12-01

    We propose and demonstrate a tunable erbium-based fiber ring laser with power-equalized output. When a mode-restricting intracavity fiber Fabry-Perot tunable filter (FFP-TF) is combined, the proposed resonator can guarantee a tunable laser oscillation. This proposed laser can obtain the flatter lasing wavelength in an effectively operating range of 1533.3 to 1574.6 nm without any other operating mechanism. Moreover, the performances of the output power, wavelength tuning range, and side-mode suppression ratio (SMSR) were studied.

  16. Fibercore AstroGain fiber: multichannel erbium doped fibers for optical space communications

    NASA Astrophysics Data System (ADS)

    Hill, Mark; Gray, Rebecca; Hankey, Judith; Gillooly, Andy

    2014-03-01

    Fibercore have developed AstroGainTM fiber optimized for multichannel amplifiers used in optical satellite communications and control. The fiber has been designed to take full advantage of the photo-annealing effect that results from pumping in the 980nm region. The proprietary trivalent structure of the core matrix allows optimum recovery following radiation damage to the fiber, whilst also providing a market leading Erbium Doped Fiber Amplifier (EDFA) efficiency. Direct measurements have been taken of amplifier efficiency in a multichannel assembly, which show an effective photo-annealing recovery of up to 100% of the radiation induced attenuation through excitation of point defects.

  17. Photoluminescence of porous silicon stain etched and doped with erbium and ytterbium

    NASA Astrophysics Data System (ADS)

    Díaz-Herrera, B.; González-Díaz, B.; Guerrero-Lemus, R.; Hernández-Rodríguez, C.; Méndez-Ramos, J.; Rodríguez, V. D.

    2009-02-01

    A novel low cost process has been developed for application in porous silicon-based photodetectors and solar cells, where conventional doping processes are not affordable because of the high processing cost and technical difficulties. Ytterbium and erbium (Yb 3+-Er 3+) ions were introduced into luminescent porous silicon stain etched by thermal diffusion. Doping profiles were evaluated by energy-dispersive spectroscopy analysis. The visible and near-infrared photoluminescence of Yb 3+-Er 3+ co-doped stain-etched porous silicon layers is observed and evaluated under 980 nm pumping. Up-conversion processes that could improve the efficiency of silicon-based solar cells are detected.

  18. 120 nm Bandwidth noise-like pulse generation in an erbium-doped fiber laser

    NASA Astrophysics Data System (ADS)

    Zhao, L. M.; Tang, D. Y.; Cheng, T. H.; Tam, H. Y.; Lu, C.

    2008-01-01

    We report on the generation of noise-like pulses with up to 120 nm bandwidth in a passively mode-locked erbium-doped fiber ring laser. By inserting a segment of slightly normal dispersion fiber in a mode-locked fiber laser cavity, we found that the spectrum of the noise-like pulse emission of the laser can be significantly broadened as a result of the four-wave-mixing and the soliton self-frequency shift effects in the inserted fiber.

  19. Surface-directed synthesis of erbium-doped yttrium oxide nanoparticles within organosilane zeptoliter containers.

    PubMed

    Englade-Franklin, Lauren E; Morrison, Gregory; Verberne-Sutton, Susan D; Francis, Asenath L; Chan, Julia Y; Garno, Jayne C

    2014-09-24

    We introduce an approach to synthesize rare earth oxide nanoparticles using high temperature without aggregation of the nanoparticles. The dispersity of the nanoparticles is controlled at the nanoscale by using small organosilane molds as reaction containers. Zeptoliter reaction vessels prepared from organosilane self-assembled monolayers (SAMs) were used for the surface-directed synthesis of rare earth oxide (REO) nanoparticles. Nanopores of octadecyltrichlorosilane were prepared on Si(111) using particle lithography with immersion steps. The nanopores were filled with a precursor solution of erbium and yttrium salts to confine the crystallization step to occur within individual zeptoliter-sized organosilane reaction vessels. Areas between the nanopores were separated by a matrix film of octadecyltrichlorosilane. With heating, the organosilane template was removed by calcination to generate a surface array of erbium-doped yttria nanoparticles. Nanoparticles synthesized by the surface-directed approach retain the periodic arrangement of the nanopores formed from mesoparticle masks. While bulk rare earth oxides can be readily prepared by solid state methods at high temperature (>900 °C), approaches for preparing REO nanoparticles are limited. Conventional wet chemistry methods are limited to low temperatures according to the boiling points of the solvents used for synthesis. To achieve crystallinity of REO nanoparticles requires steps for high-temperature processing of samples, which can cause self-aggregation and dispersity in sample diameters. The facile steps for particle lithography address the problems of aggregation and the requirement for high-temperature synthesis.

  20. Noise in adaptive interferometric fiber sensor based on population dynamic grating in erbium-doped fiber.

    PubMed

    Stepanov, Serguei; Sánchez, Marcos Plata; Hernández, Eliseo Hernández

    2016-09-10

    Experimental investigations of the main noise sources that limit the sensitivity of the adaptive interferometric all-fiber sensors operating in the communication wavelength region are reported. Adaptive properties (i.e., the autostabilization of an optimal operation point of the interferometer) are enabled by the dynamic population grating recorded in a segment of the erbium-doped fiber (EDF) at milliwatt-scale cw power in the 1480-1560 nm spectral range. The utilized symmetric Sagnac configuration with low light internal reflections ensures reduced sensitivity of the sensor to phase noise of the laser, while intensity noise is reduced to an insignificant level by the balanced detection scheme. It is shown that the fluorescence from the erbium ions, excited by the counterpropagating waves recording the grating, increases the noise level from the fundamental shot noise approximately by a factor of 2-3 only. It is also shown that conventional communication distributed feedback (DFB) semiconductor lasers with megahertz linewidth are not suitable for high-sensitivity applications of such sensors. Because of inevitable backreflections from the output terminal devices (photodiodes, insulators, circulator), the above-mentioned fundamental noise level is increased by 2 orders of magnitude due to high phase noise of the DFB laser. PMID:27661369

  1. Surface-directed synthesis of erbium-doped yttrium oxide nanoparticles within organosilane zeptoliter containers.

    PubMed

    Englade-Franklin, Lauren E; Morrison, Gregory; Verberne-Sutton, Susan D; Francis, Asenath L; Chan, Julia Y; Garno, Jayne C

    2014-09-24

    We introduce an approach to synthesize rare earth oxide nanoparticles using high temperature without aggregation of the nanoparticles. The dispersity of the nanoparticles is controlled at the nanoscale by using small organosilane molds as reaction containers. Zeptoliter reaction vessels prepared from organosilane self-assembled monolayers (SAMs) were used for the surface-directed synthesis of rare earth oxide (REO) nanoparticles. Nanopores of octadecyltrichlorosilane were prepared on Si(111) using particle lithography with immersion steps. The nanopores were filled with a precursor solution of erbium and yttrium salts to confine the crystallization step to occur within individual zeptoliter-sized organosilane reaction vessels. Areas between the nanopores were separated by a matrix film of octadecyltrichlorosilane. With heating, the organosilane template was removed by calcination to generate a surface array of erbium-doped yttria nanoparticles. Nanoparticles synthesized by the surface-directed approach retain the periodic arrangement of the nanopores formed from mesoparticle masks. While bulk rare earth oxides can be readily prepared by solid state methods at high temperature (>900 °C), approaches for preparing REO nanoparticles are limited. Conventional wet chemistry methods are limited to low temperatures according to the boiling points of the solvents used for synthesis. To achieve crystallinity of REO nanoparticles requires steps for high-temperature processing of samples, which can cause self-aggregation and dispersity in sample diameters. The facile steps for particle lithography address the problems of aggregation and the requirement for high-temperature synthesis. PMID:25163977

  2. Observations of proton beam enhancement due to erbium hydride on gold foil targets

    SciTech Connect

    Offermann, D. T.; Van Woerkom, L. D.; Freeman, R. R.; Foord, M. E.; Hey, D.; Key, M. H.; Mackinnon, A. J.; MacPhee, A. G.; Patel, P. K.; Ping, Y.; Sanchez, J. J.; Shen, N.; Bartal, T.; Beg, F. N.; Espada, L.; Chen, C. D.

    2009-09-15

    Recent theoretical work suggests that the conversion efficiency from laser to protons in laser irradiated thin foil experiments increases if the atomic mass of nonhydrogen atoms on the foil rear surface increases. Experiments were performed at the Lawrence Livermore National Laboratory Jupiter Laser Facility to observe the effect of thin foils coated with erbium hydride on the conversion efficiency from laser to protons. Gold foils with and without the rear surface coated with ErH{sub 3} were irradiated using the ultrashort pulse, 40 TW Callisto laser. An argon-ion etching system was used to remove naturally occurring nanometer thick surface layer contaminants from the hydride. With the etcher, gold with ErH{sub 3} showed a 25% increase in the conversion efficiency to protons above 3.4 MeV relative to contaminants, where C{sup +4} and H{sup +} were the dominant ion species. No difference in the ion signal was observed without first cleaning the hydrides. Simulations using the hybrid PIC code, LSP, revealed that the increase due to erbium hydride versus contaminants is 37% for protons above 3 MeV.

  3. Acid synthesis of luminescent amine-functionalized or erbium-doped silica spheres for biological applications.

    PubMed

    Enrichi, Francesco; Trave, Enrico; Bersani, Marco

    2008-03-01

    In this work we discuss and investigate the morphological and optical properties of luminescent silica spheres which can have interesting applications in bioimaging and biosensing. The spheres are synthesized following an acid route by the hydrolysis and condensation of tetraethylortosilicate (TEOS) and can be functionalized by incorporation of aminopropyl-triethoxysilane (APTES) during the synthesis, inducing a significant luminescence that can be attributed to a recombination mechanism from localized organic defects related to -NH(2) groups. It is shown that the acid synthesis route produces very regular spherical particles, but their diameter vary in the range of 200-4,000 nm. The luminescence properties have been investigated and optimized by variation of the annealing temperature for the functionalized spheres, obtaining the most efficient PL emission after a thermal treatment of 1 h at 600 degrees C in air. Moreover, the possibility to introduce rare earths like erbium in the spheres was also studied and the corresponding Er(3) luminescence emission at 1.53 microm is reported in terms of intensity and lifetime, pointing out that erbium can be easily and efficiently incorporated during the acid synthesis giving high PL intensity with a good lifetime of 3.9 ms.

  4. Experimental and numerical study of high order Stokes lines in Brillouin-erbium fiber laser

    SciTech Connect

    Yuan, Yijun; Yao, Yong Xiao, Jun Jun; Yang, Yanfu; Tian, Jiajun; Liu, Chao

    2014-01-28

    We experimentally study the dependences of high-order Stokes lines on the erbium-doped fiber (EDF) pump power P{sub EDF}, the Brillouin pump (BP) power P{sub BP}, and its working wavelength in a multiwavelength Brillouin erbium-doped fiber laser (MBEFL). By using the rate and propagation equations, and the coupled wave equations of stimulated Brillouin scattering, we establish a lumped model to describe the MBEFL. Numerical simulations show that the number of Stokes lines can be increased by decreasing the spacing between the BP wavelength and the EDF peak gain or P{sub BP} as long as it is larger than a critical value P{sub BP}{sup (cr)}=1.7 mW, or by increasing P{sub EDF} without reaching a saturation value P{sub EDF}{sup (cr)}=250 mW. However, when P{sub BP} and P{sub EDF} are varied beyond P{sub BP}{sup (cr)} and P{sub EDF}{sup (cr)}, respectively, the number of Stokes lines is reduced, accompanied by some self-lasing cavity modes. These results by numerical simulation are consistent with experimental observations from the MBEFL.

  5. Treatment of dilated pores with 1410-nm fractional erbium-doped fiber laser.

    PubMed

    Suh, Dong-Hye; Chang, Ka-Yeun; Lee, Sang-Jun; Song, Kye-Yong; Choi, Jeong Hwee; Shin, Min Kyung; Jeong, Ki-Heon

    2015-04-01

    Dilated pores can be an early sign of skin aging and are a significant cosmetic concern. The 1410-nm wavelength is optimal for superficial dermal treatments up to 650 μm deep. The aim of the present study was to evaluate the clinical effectiveness and safety of the fractional erbium-doped fiber 1410-nm laser in the treatment of dilated pores. Fifteen patients with dilated facial pores underwent three laser treatments at 3-week intervals. Posttreatment skin responses and side effects were assessed at treatment and follow-up visits by study physicians. Clinical effectiveness of treatment was assessed by both study physicians and patients 3 months after the final laser treatment using a quartile grading scale. Histological examination was performed using biopsy samples taken at baseline (pretreatment) and 3 months after the last treatment. This study showed that greater than 51 % improvement in dilated pores was demonstrated in 14 of 15 patients after three sessions of laser treatments. Improvements in skin texture, tone, and smoothness were reported in all patients. Treatment was well tolerated in all patients, with no unanticipated side effects. This study demonstrates that the 1410-nm fractional erbium fiber laser is effective and safe for treatment of dilated facial pores in Fitzpatrick skin types III-IV.

  6. The impact of erbium incorporation on the structure and photophysics of silicon-germanium nanowires.

    PubMed

    Wu, Ji; Wieligor, Monika; Zerda, T Waldek; Coffer, Jeffery L

    2010-12-01

    In this paper, we report multi-step processes for the fabrication of Er3+-doped SiGe nanowires (NWs) and characterization of their emissive properties. Three different alloyed architectures are obtained by altering the deposition sequences of Si and Er3+ on a Ge core NW, each involving a fixed concentration of these three elements. The deposition of Si onto the Ge NW core, followed by an Er3+-rich layer on the outermost surface, permits facile formation of a SiGe alloy given the lack of an erbium diffusion barrier; yet clustering of the erbium centers on the NW surface produces the weakest emitter. For nanowires prepared by co-depositing Si and Er3+ on top of the Ge core, the presence of impurity Er3+ ions greatly reduces the alloying rate of Si and Ge such that less Si can diffuse into the Ge core. For this structure, the reduction of Er-Er interactions by a polycrystalline Si shell results in the strongest emission at 1540 nm. If an Er3+ layer is inserted between the Ge and Si layers (a sandwich structure), it is found that Er3+ ions diffuse preferentially into the SiGe core instead of the silicon-rich shell, with a correspondingly weaker luminescence intensity. A combination of high resolution transmission electron microscopy, energy dispersive X-ray mapping, micro-Raman spectroscopy, and photoluminescence spectroscopy are employed to derive these conclusions.

  7. Erbium ions in congruent and stoichiometric lithium niobate. Searching for a clue

    NASA Astrophysics Data System (ADS)

    Vrable, Ian; Grachev, Valentin; Meyer, Martin; Kokanyan, Edward; Malovichko, Galina

    2011-10-01

    Lithium Niobate (LN) doped with Er^3+ ions is of great interest for both fundamental science and advanced applications: lasers with frequency conversion, elements of all-optical telecommunication network and quantum cryptography. According to the EXAFS and RBS data, trivalent ions substitute for Li^+ and should create similar centers with charge compensation by lithium vacancies. The EPR studies confirmed this conclusion for Cr, Fe, Nd, and Yb Their most intense lines belong to axial centers with C3 symmetry. Distant lithium vacancies cause a line broadening, but do not change the C3 symmetry of observed spectra. Our EPR study of Er^3+ in stoichiometric LN has unexpectedly shown that all observed Er^3+ centers have C1 symmetry. Therefore, models with cation vacancies cannot describe our experimental data for LN:Er, and we have to consider complexes which excludes the existence of axial centers: erbium substituted for lithium or incorporated in octahedral or tetrahedral structural vacancy plus interstitial oxygen ion as a charge compensator, erbium substituted for niobium and oxygen vacancy as compensator of excessive negative charges. Re-investigating congruent samples of LN:Er, we did not find undisputable evidences of the existence of axial Er^3+ centers.

  8. Acoustical measurements during Erbium:YAG laser ablation of porcine calcified tissues

    NASA Astrophysics Data System (ADS)

    Saaf, Randall R.; Wong, Brian J.; Milner, Thomas E.; Peavy, George M.; Anvari, Bahman

    1998-07-01

    The Erbium:YAG laser ((lambda) equals 2.94 micrometer) has been suggested for use in dental, orthopedic, and middle ear surgery due to decreased thermal trauma, precise ablation characteristics, and potential fiber optic delivery. While there has been much focus on the thermal and photoacoustic events that occur during pulsed laser ablation of hard tissue, there are few studies that examine the acoustic energy generated by these devices during ablation from an audiologic standpoint. In this study, the porcine otic capsule, nasal bone, and teeth were irradiated with an Erbium:YAG laser. Frequencies of 5 and 10 Hz shot repetition rate were used with .5 to 4 W average power. Additionally, a burst mode consisting of three pulses was used with .2 to 1.4 J total energy. During ablation, acoustic measurements were made using a sound level meter held 20 mm away from the target site. A constant spot size of 500 micrometer was maintained for each laser blast. With each set of laser parameters, the sound intensity (dB SPL) exceeded 70 dB. Peak intensity measurements of 95 dB were measured. The clinical significance of these findings is discussed and the acoustical aspects of middle ear function and noise trauma are reviewed.

  9. Surface-Directed Synthesis of Erbium-Doped Yttrium Oxide Nanoparticles within Organosilane Zeptoliter Containers

    PubMed Central

    2015-01-01

    We introduce an approach to synthesize rare earth oxide nanoparticles using high temperature without aggregation of the nanoparticles. The dispersity of the nanoparticles is controlled at the nanoscale by using small organosilane molds as reaction containers. Zeptoliter reaction vessels prepared from organosilane self-assembled monolayers (SAMs) were used for the surface-directed synthesis of rare earth oxide (REO) nanoparticles. Nanopores of octadecyltrichlorosilane were prepared on Si(111) using particle lithography with immersion steps. The nanopores were filled with a precursor solution of erbium and yttrium salts to confine the crystallization step to occur within individual zeptoliter-sized organosilane reaction vessels. Areas between the nanopores were separated by a matrix film of octadecyltrichlorosilane. With heating, the organosilane template was removed by calcination to generate a surface array of erbium-doped yttria nanoparticles. Nanoparticles synthesized by the surface-directed approach retain the periodic arrangement of the nanopores formed from mesoparticle masks. While bulk rare earth oxides can be readily prepared by solid state methods at high temperature (>900 °C), approaches for preparing REO nanoparticles are limited. Conventional wet chemistry methods are limited to low temperatures according to the boiling points of the solvents used for synthesis. To achieve crystallinity of REO nanoparticles requires steps for high-temperature processing of samples, which can cause self-aggregation and dispersity in sample diameters. The facile steps for particle lithography address the problems of aggregation and the requirement for high-temperature synthesis. PMID:25163977

  10. Noise in adaptive interferometric fiber sensor based on population dynamic grating in erbium-doped fiber.

    PubMed

    Stepanov, Serguei; Sánchez, Marcos Plata; Hernández, Eliseo Hernández

    2016-09-10

    Experimental investigations of the main noise sources that limit the sensitivity of the adaptive interferometric all-fiber sensors operating in the communication wavelength region are reported. Adaptive properties (i.e., the autostabilization of an optimal operation point of the interferometer) are enabled by the dynamic population grating recorded in a segment of the erbium-doped fiber (EDF) at milliwatt-scale cw power in the 1480-1560 nm spectral range. The utilized symmetric Sagnac configuration with low light internal reflections ensures reduced sensitivity of the sensor to phase noise of the laser, while intensity noise is reduced to an insignificant level by the balanced detection scheme. It is shown that the fluorescence from the erbium ions, excited by the counterpropagating waves recording the grating, increases the noise level from the fundamental shot noise approximately by a factor of 2-3 only. It is also shown that conventional communication distributed feedback (DFB) semiconductor lasers with megahertz linewidth are not suitable for high-sensitivity applications of such sensors. Because of inevitable backreflections from the output terminal devices (photodiodes, insulators, circulator), the above-mentioned fundamental noise level is increased by 2 orders of magnitude due to high phase noise of the DFB laser.

  11. Crystal structure and magnetic properties of potassium erbium double tungstate KEr(WO4)2

    NASA Astrophysics Data System (ADS)

    Borowiec, M. T.; Dyakonov, V. P.; Wozniak, K.; Dobrzycki, L.; Berkowski, M.; Zubov, E. E.; Michalski, E.; Szewczyk, A.; Gutowska, M. U.; Zayarnyuk, T.; Szymczak, H.

    2007-02-01

    Results of structural, magnetic and specific heat investigations of the potassium erbium double tungstate, KEr(WO4)2, are presented. Potassium erbium double-tungstate KEr(WO4)2 single crystals have been grown by the top-seeded solution growth method (TSSG) and modified Czochralski techniques. It crystallizes in the monoclinic crystal structure (C 2/c space group). The unit cell contains four formula units and is described by parameters a = 10.615(2) Å, b = 10.316(2) Å, c = 7.534(2) Å, β = 130.73(3)°. From the x-ray diffraction measurements the fractional atomic coordinates, displacement parameters and interatomic distances have been determined. The specific heat C(T) of the KEr(WO4)2 crystal has been measured over a temperature range of 0.6-300 K. The susceptibility has been studied at T = 0.25-4.0 K. The magnetic phase transition was observed at a temperature of 0.48 K. The magnetization has been measured in the temperature region from 4.2 to 60 K and in magnetic field up to 1.6 T. A strong anisotropy of magnetic properties was found. The temperature and field dependences of susceptibility and magnetization data were used for both elucidation of character of the magnetic ordering and calculation of the exchange and dipole-dipole interaction energies as well as for determination of the possible magnetic structure of KEr(WO4)2.

  12. Evaluation of the Removal Bacteria on Failed Titanium Implants After Irradiation With Erbium-Doped Yttrium Aluminium Garnet Laser.

    PubMed

    Scarano, Antonio; Nardi, Gianna; Murmura, Giovanna; Rapani, Manuela; Mortellaro, Carmen

    2016-07-01

    Peri-implantitis may occur because of biologic or mechanical factors. It can be treated by a variety of methods. The aim of the present study is to evaluate implant surface of failed oral titanium implants after being irradiated with erbium laser. PMID:27391491

  13. Microstructure and Optical Properties of Erbium Doped Silica-Based Films via Flame Hydrolysis Deposition and Aerosol Doping

    NASA Astrophysics Data System (ADS)

    Sui, Jiehe; Wang, Haibo; Cai, Wei

    Silica-based films on Si fabricated by flame hydrolysis deposition were doped with erbium ions using an aerosol doping technique, and co-doped with GeO2, P2O5 and B2O3. The erbium solution concentration was varied from 4 to 8wt%. The results show that the refractive index of the films is not changed with erbium addition and no OH group is detected for erbium doped silica-based films. An obvious peak was observed at 1.542 µm with the FWHM of 65 nm, which corresponds to the 4I13/2 → 4I15/2 transition. With the increase of Er solution concentration, the photoluminescence (PL) intensity first increases, then decreases above 6wt% Er solution concentration. The decrease in PL intensity with concentration is attributed to concentration quenching caused by Er-Er interaction. The dependence of PL intensity on pump power intensity further confirms the concentration quenching is cooperative upconversion.

  14. Gain enhanced L-band optical fiber amplifiers and tunable fiber lasers with erbium-doped fibers

    NASA Astrophysics Data System (ADS)

    Chen, H.; Leblanc, M.; Schinn, G. W.

    2003-02-01

    We report on the experimental investigation of gain enhanced L-band erbium-doped fiber amplifiers (EDFA) by either recycling residual ASE or using a second C-band wavelength pump laser and on the experimental demonstration of L-band tunable erbium-doped fiber ring lasers. We observed that by reflecting ASE from pumped erbium-doped fiber (EDF) the L-band EDFA gain can be enhanced of 2-15 dB depending on amplifier designs. We also studied wavelength and power dependence of second pump laser on the gain enhanced L-band EDFA and found that an optimum wavelength for second pump laser was between 1550 and 1560 nm. Finally, a L-band tunable erbium-doped fiber laser was also constructed in which lazing oscillation was observed closed to 1624 nm by recycling residual ASE. This L-band tunable laser has a line-width of about 300 MHz, an output power of 1 mW, and a signal to source spontaneous emission ratio of 60 dB.

  15. The efficacy of autologous platelet-rich plasma combined with erbium fractional laser therapy for facial acne scars or acne.

    PubMed

    Zhu, Jiang-Ting; Xuan, Min; Zhang, Ya-Ni; Liu, Hong-Wei; Cai, Jin-Hui; Wu, Yan-Hong; Xiang, Xiao-Fei; Shan, Gui-Qiu; Cheng, Biao

    2013-07-01

    The aim of this study was to evaluate the efficacy of autologous platelet-rich plasma (PRP) combined with erbium fractional laser therapy for facial acne or acne scars. PRP combined with erbium fractional laser therapy was used for the treatment of 22 patients, including 16 patients who suffered from facial acne scars and 6 patients who suffered from acne scars concomitant with acne. Whole blood (40 ml) was collected from each patient, and following differential centrifugation, PRP was harvested. After using an erbium fractional laser, we applied PRP to the entire face of every patient. Digital photos were taken before and after the treatment for evaluation by dermatologists and the patients rated the efficacy on a 5-point scale. The erythema was moderate or mild, while its total duration was <3 days; after receiving the treatment three times, 90.9% of the patients showed an improvement of >50%, and 91% of the patients were satisfied; no acne inflammation was observed after treatment. PRP combined with erbium fractional laser therapy is an effective and safe approach for treating acne scars or acne, with minimal side-effects, and it simultaneously enhanced the recovery of laser-damaged skin.

  16. Evaluation of the Removal Bacteria on Failed Titanium Implants After Irradiation With Erbium-Doped Yttrium Aluminium Garnet Laser.

    PubMed

    Scarano, Antonio; Nardi, Gianna; Murmura, Giovanna; Rapani, Manuela; Mortellaro, Carmen

    2016-07-01

    Peri-implantitis may occur because of biologic or mechanical factors. It can be treated by a variety of methods. The aim of the present study is to evaluate implant surface of failed oral titanium implants after being irradiated with erbium laser.

  17. The Impact of Increased Bladder Blood Flow on Storage Symptoms after Holmium Laser Enucleation of the Prostate.

    PubMed

    Saito, Keisuke; Hisasue, Shin-ichi; Ide, Hisamitsu; Aoki, Hiroaki; Muto, Satoru; Yamaguchi, Raizo; Tsujimura, Akira; Horie, Shigeo

    2015-01-01

    In order to investigate how holmium laser enucleation of the prostate (HoLEP) improves urinary storage symptoms, we assessed blood flow in the urinary bladder mucosa of patients with benign prostatic hyperplasia (BPH) before and after laser surgery. Seventy-four consecutive patients with BPH (median age 69 years, range; 53-88) underwent HoLEP at our institution and are included in this study. We prospectively assessed the International Prostate Symptom Score (IPSS), IPSS-QOL Score, the Overactive Bladder Symptom Score (OABSS), uroflowmetry, and blood flow in the urinary bladder, before and after surgery. Blood flow in the bladder mucosa was measured using the OMEGA FLOW (OMEGAWAVE, Tokyo, Japan) laser Doppler flowmeter. The median volume of the enucleated adenomas was 45.0 g (range: 25.0 to 83.2). The median IPSS improved significantly from 20 (range: 6-35) to 3 (0-22) (p < 0.001; Wilcoxon signed-rank test), as did the storage symptoms score, which decreased from 13 (2-20) to 3 (1-8) (p < 0.001). Median bladder blood flow increased at the trigone from 9.57 ± 0.83 ml/sec to 17.60 ± 1.08 ml/sec. Multiple regression analysis for the improved storage symptom score eliminated all explanatory variables except increased bladder perfusion. The data suggest that HoLEP improves blood flow in the bladder mucosa, which independently leads to the improvement of storage symptoms. PMID:26090819

  18. Predictive risk factors of postoperative urinary incontinence following holmium laser enucleation of the prostate during the initial learning period

    PubMed Central

    Kobayashi, Shuichiro; Yano, Masataka; Nakayama, Takayuki; Kitahara, Satoshi

    2016-01-01

    ABSTRACT Purpose: To determine the predictive factors for postoperative urinary incontinence (UI) following holmium laser enucleation of the prostate (HoLEP) during the initial learning period. Patients and Methods: We evaluated 127 patients with benign prostatic hyperplasia who underwent HoLEP between January 2011 and December 2013. We recorded clinical variables, including blood loss, serum prostate-specific antigen levels, and the presence or absence of UI. Blood loss was estimated as a decline in postoperative hemoglobin levels. The predictive factors for postoperative UI were determined using a multivariable logistic regression analysis. Results: Postoperative UI occurred in 31 patients (24.4%), but it cured in 29 patients (93.5%) after a mean duration of 12 weeks. Enucleation time >100 min (p=0.043) and blood loss >2.5g/dL (p=0.032) were identified as significant and independent risk factors for postoperative UI. Conclusions: Longer enucleation time and increased blood loss were independent predictors of postoperative UI in patients who underwent HoLEP during the initial learning period. Surgeons in training should take care to perform speedy enucleation maneuver with hemostasis. PMID:27564285

  19. Neutron activation of holmium poly(L-lactic acid) microspheres for hepatic arterial radio-embolization: a validation study.

    PubMed

    Vente, M A D; Nijsen, J F W; de Roos, R; van Steenbergen, M J; Kaaijk, C N J; Koster-Ammerlaan, M J J; de Leege, P F A; Hennink, W E; van Het Schip, A D; Krijger, G C

    2009-08-01

    Poly(L-lactic acid) microspheres loaded with holmium-166 acetylacetonate (166Ho-PLLA-MS) are a novel microdevice for intra-arterial radio-embolization in patients with unresectable liver malignancies. The neutron activation in a nuclear reactor, in particular the gamma heating, damages the 166Ho-PLLA-MS. The degree of damage is dependent on the irradiation characteristics and irradiation time in a particular reactor facility. The aim of this study was to standardize and objectively validate the activation procedure in a particular reactor. The methods included light- and scanning electron microscopy (SEM), particle size analysis, differential scanning calorimetry, viscometry, thermal neutron flux measurements and energy deposition calculations. Seven hours-neutron irradiation results in sufficient specific activity of the 166Ho-PLLA-MS while structural integrity is preserved. Neutron flux measurements and energy deposition calculations are required in the screening of other nuclear reactors. For the evaluation of microsphere quality, light microscopy, SEM and particle size analysis are appropriate techniques.

  20. The Impact of Increased Bladder Blood Flow on Storage Symptoms after Holmium Laser Enucleation of the Prostate.

    PubMed

    Saito, Keisuke; Hisasue, Shin-ichi; Ide, Hisamitsu; Aoki, Hiroaki; Muto, Satoru; Yamaguchi, Raizo; Tsujimura, Akira; Horie, Shigeo

    2015-01-01

    In order to investigate how holmium laser enucleation of the prostate (HoLEP) improves urinary storage symptoms, we assessed blood flow in the urinary bladder mucosa of patients with benign prostatic hyperplasia (BPH) before and after laser surgery. Seventy-four consecutive patients with BPH (median age 69 years, range; 53-88) underwent HoLEP at our institution and are included in this study. We prospectively assessed the International Prostate Symptom Score (IPSS), IPSS-QOL Score, the Overactive Bladder Symptom Score (OABSS), uroflowmetry, and blood flow in the urinary bladder, before and after surgery. Blood flow in the bladder mucosa was measured using the OMEGA FLOW (OMEGAWAVE, Tokyo, Japan) laser Doppler flowmeter. The median volume of the enucleated adenomas was 45.0 g (range: 25.0 to 83.2). The median IPSS improved significantly from 20 (range: 6-35) to 3 (0-22) (p < 0.001; Wilcoxon signed-rank test), as did the storage symptoms score, which decreased from 13 (2-20) to 3 (1-8) (p < 0.001). Median bladder blood flow increased at the trigone from 9.57 ± 0.83 ml/sec to 17.60 ± 1.08 ml/sec. Multiple regression analysis for the improved storage symptom score eliminated all explanatory variables except increased bladder perfusion. The data suggest that HoLEP improves blood flow in the bladder mucosa, which independently leads to the improvement of storage symptoms.

  1. Holmium:YAG laser lithotripsy for the management of urolithiasis in small ruminants and pot-bellied pigs

    NASA Astrophysics Data System (ADS)

    Halland, Spring K.; House, John K.; George, Lisle

    2001-05-01

    Obstructive urolithiasis is a common problem in small ruminants and pot-bellied pigs. The most common site of urinary tract obstruction in these species is the urethra. Surgical procedures developed to relieve obstructions, in our experience have been effective in approximately 75% of cases. Urethral stricture is a common complication if the mucosa of the urethra is disrupted. The objective of this project was to evaluate endoscopy guided laser lithotripsy as a therapeutic modality to relieve urethral obstructions in small ruminants and pot-bellied pigs. The study population consisted of patients presented to the Veterinary Medical Teaching Hospital at the University of California Davis with obstructive urolithiasis. Lithotripsy was performed using a Holmium:YAG laser via a 200-micron low water quartz fiber passed through a flexible mini-endoscope. Two types of urinary calculi were managed with this technique, calcium carbonate and calcium hydroxyphosphate. Laser lithotripsy was effective at relieving obstructions caused by both types of calculi when conventional methods had failed. Laser lithotripsy performed via urethral endoscopy is a safe and effective therapeutic modality for management of obstructive urolithiasis in small ruminants and pot-bellied pigs and reduces the risk of post procedural urethral stricture.

  2. The Impact of Increased Bladder Blood Flow on Storage Symptoms after Holmium Laser Enucleation of the Prostate

    PubMed Central

    Ide, Hisamitsu; Aoki, Hiroaki; Muto, Satoru; Yamaguchi, Raizo; Tsujimura, Akira; Horie, Shigeo

    2015-01-01

    In order to investigate how holmium laser enucleation of the prostate (HoLEP) improves urinary storage symptoms, we assessed blood flow in the urinary bladder mucosa of patients with benign prostatic hyperplasia (BPH) before and after laser surgery. Seventy-four consecutive patients with BPH (median age 69 years, range; 53–88) underwent HoLEP at our institution and are included in this study. We prospectively assessed the International Prostate Symptom Score (IPSS), IPSS-QOL Score, the Overactive Bladder Symptom Score (OABSS), uroflowmetry, and blood flow in the urinary bladder, before and after surgery. Blood flow in the bladder mucosa was measured using the OMEGA FLOW (OMEGAWAVE, Tokyo, Japan) laser Doppler flowmeter. The median volume of the enucleated adenomas was 45.0 g (range: 25.0 to 83.2). The median IPSS improved significantly from 20 (range: 6–35) to 3 (0–22) (p<0.001; Wilcoxon signed-rank test), as did the storage symptoms score, which decreased from 13 (2–20) to 3 (1–8) (p<0.001). Median bladder blood flow increased at the trigone from 9.57±0.83 ml/sec to 17.60±1.08 ml/sec. Multiple regression analysis for the improved storage symptom score eliminated all explanatory variables except increased bladder perfusion. The data suggest that HoLEP improves blood flow in the bladder mucosa, which independently leads to the improvement of storage symptoms. PMID:26090819

  3. Efficient green continuous-wave lasing of blue-diode-pumped solid-state lasers based on praseodymium-doped LiYF4.

    PubMed

    Hansen, Nils-Owe; Bellancourt, Aude-Reine; Weichmann, Ulrich; Huber, Günter

    2010-07-10

    We report highly efficient laser operation of praseodymium-doped LiYF(4) in the green spectral range. The influence of the crystal length and pump light focusing on the laser performance has been studied. The pump radiation was delivered by InGaN laser diodes. Optimizing the setup for a 2.9 mm long crystal with a doping concentration of 0.5% led to an electric to green laser power conversion efficiency as high as 7.4%. With 500 and 1000 mW of pump light power, output powers of 179 and 358 mW have been reached, respectively. With respect to absorbed power, slope efficiencies of up to approximately 60% have been achieved.

  4. Effect of praseodymium doping on the structural, magnetic and magnetocaloric properties of Sm0.55Sr0.45MnO3 manganite

    NASA Astrophysics Data System (ADS)

    Mleiki, A.; Othmani, S.; Cheikhrouhou-Koubaa, W.; Koubaa, M.; Cheikhrouhou, A.; Hlil, E. K.

    2015-12-01

    The effect of praseodymium doping on the microstructure, magnetic and magnetocaloric effects in Sm0.55-xPrxSr0.45MnO3 (x=0.0 and x=0.1) has been investigated. Our compounds have been elaborated using the conventional solid-state reaction at high temperature. X-Ray diffraction study reveals that our samples crystallize in the distorted orthorhombic system with Pbnm space group. Magnetization measurements M (T) at H=0.05 T were performed and show a paramagnetic (PM) to ferromagnetic (FM) transition with decreasing temperature. Praseodymium doping leads to an increase of the Curie temperature TC from 95 K (x=0.0) to 132 K (x=0.1). Moreover, we observe a small anomaly in the M (T) behavior around 30 K. It has been shown that x=0.1 sample exhibit first order FM-PM phase transition under low magnetic field accompanied by a thermal hysteresis in the field cooled cooling and warming protocols. However, the phase transition from PM to FM is modified from first order to second order above a critical field HC. A metamagnetic behavior has been observed in the M (H) curves around 110 K for x=0.0 and 160 K for x=0.1. The maximum of the magnetic entropy change (- ΔSMmax) was calculated using the isothermal magnetization curves M (H) under magnetic field change of 5 T and is found to be 6.56 J kg-1 K-1 for x=0.0 and 7.14 J kg-1 K-1 for x=0.1. The relative cooling power (RCP) is found to be 222.6 J/Kg and 258.8 J/Kg for x=0.0 and x=0.1, respectively. This suggests that these compounds may be suitable candidates for magnetic refrigeration.

  5. Impact of holmium fibre laser radiation (λ = 2.1 μm) on the spinal cord dura mater and adipose tissue

    NASA Astrophysics Data System (ADS)

    Filatova, S. A.; Kamynin, V. A.; Ryabova, A. V.; Loshchenov, V. B.; Zelenkov, P. V.; Zolotovskii, I. O.; Tsvetkov, V. B.; Kurkov, A. S.

    2015-08-01

    The impact of holmium fibre laser radiation on the samples of biologic tissues (dura mater of spinal cord and adipose tissue with interlayers of muscle) is studied. The experimental results are evaluated by the size of carbonisation and coagulation necrosis zones. The experiment shows that in the case of irradiation of the spinal cord dura mater samples the size of carbonisation and coagulation necrosis zones is insignificant. In the adipose tissue the carbonisation zone is also insignificant, but the region of cellular structure disturbance is large. In the muscle tissue the situation is opposite. The cw laser operation provides clinically acceptable degree of destruction in tissue samples with a minimal carbonisation zone.

  6. Wideband thulium-holmium-doped fiber source with combined forward and backward amplified spontaneous emission at 1600-2300  nm spectral band.

    PubMed

    Honzatko, Pavel; Baravets, Yauhen; Kasik, Ivan; Podrazky, Ondrej

    2014-06-15

    We have experimentally demonstrated two extremely wideband amplified spontaneous emission (ASE) sources. High bandwidth is achieved by combining the backward and forward ASEs generated in thulium-holmium-doped fiber using appropriate wideband couplers. The ASE source optimized for flat spectral power density covers a spectral range from 1527 to 2171 nm at a -10  dB level. The ASE source optimized for spectroscopy features an enhancement with respect to single-mode fiber (SMF) coupled halogen lamps within the spectral range from 1540 nm to more than 2340 nm covering the 800 nm bandwidth.

  7. Dual-wavelength single-longitudinal-mode erbium-doped fiber laser based on inverse-Gaussian apodized fiber Bragg grating and its application in microwave generation

    NASA Astrophysics Data System (ADS)

    Lin, Bo; Tjin, Swee Chuan; Zhang, Han; Tang, Dingyuan; Liang, Sheng; Hao, Jianzhong; Dong, Bo

    2011-03-01

    We propose a simple erbium-doped fiber ring laser. It consists of an inverse-Gaussian apodized fiber Bragg grating filter which has two ultra-narrow transmission bands, and an unpumped erbium-doped fiber as a saturable absorber. Stable dual-wavelength single-longitudinal-mode lasing with a wavelength separation of approximately 0.082 nm is achieved. A microwave signal at 10.502 GHz is demonstrated by beating the dual wavelengths at a photodetector.

  8. Comparison of Photoselective Vaporization versus Holmium Laser Enucleation for Treatment of Benign Prostate Hyperplasia in a Small Prostate Volume

    PubMed Central

    Kim, Kang Sup; Choi, Jin Bong; Bae, Woong Jin; Kim, Su Jin; Cho, Hyuk Jin; Hong, Sung-Hoo; Lee, Ji Youl; Kim, Sang Hoon; Kim, Hyun Woo; Cho, Su Yeon; Kim, Sae Woong

    2016-01-01

    Objective Photoselective vaporization of the prostate (PVP) using GreenLight and Holmium laser enucleation of the prostate (HoLEP) is an important surgical technique for management of benign prostate hyperplasia (BPH). We aimed to compare the effectiveness and safety of PVP using a 120 W GreenLight laser with HoLEP in a small prostate volume. Methods Patients who underwent PVP or HoLEP surgery for BPH at our institutions were reviewed from May 2009 to December 2014 in this retrospective study. Among them, patients with prostate volumes < 40 mL based on preoperative trans-rectal ultrasonography were included in this study. Peri-operative and post-operative parameters—such as International Prostate Symptom Score (IPSS), quality of life (QoL), maximum urinary flow rate (Qmax), post-void residual urine volume (PVR), and complications—were compared between the groups. Results PVP was performed in 176 patients and HoLEP in162 patients. Preoperative demographic data were similar in both groups, with the exception of PVR. Operative time and catheter duration did not show significant difference. Significant improvements compared to preoperative values were verified at the postoperative evaluation in both groups in terms of IPSS, QoL, Qmax, and PVR. Comparison of the postoperative parameters between the PVP and HoLEP groups demonstrated no significant difference, with the exception of IPSS voiding subscore at 1 month postoperatively (5.9 vs. 3.8, P< 0.001). There was no significant difference in postoperative complications between the two groups. Conclusion Our data suggest that PVP and HoLEP are efficient and safe surgical treatment options for patients with small prostate volume. PMID:27227564

  9. Comparison of holmium:YAG and thulium fiber laser lithotripsy: ablation thresholds, ablation rates, and retropulsion effects

    NASA Astrophysics Data System (ADS)

    Blackmon, Richard L.; Irby, Pierce B.; Fried, Nathaniel M.

    2011-07-01

    The holmium:YAG (Ho:YAG) laser lithotriptor is capable of operating at high pulse energies, but efficient operation is limited to low pulse rates (~10 Hz) during lithotripsy. On the contrary, the thulium fiber laser (TFL) is limited to low pulse energies, but can operate efficiently at high pulse rates (up to 1000 Hz). This study compares stone ablation threshold, ablation rate, and retropulsion for the two different Ho:YAG and TFL operation modes. The TFL (λ = 1908 nm) was operated with pulse energies of 5 to 35 mJ, 500-μs pulse duration, and pulse rates of 10 to 400 Hz. The Ho:YAG laser (λ = 2120 nm) was operated with pulse energies of 30 to 550 mJ, 350-μs pulse duration, and a pulse rate of 10 Hz. Laser energy was delivered through 200- and 270-μm-core optical fibers in contact mode with human calcium oxalate monohydrate (COM) stones for ablation studies and plaster-of-Paris stone phantoms for retropulsion studies. The COM stone ablation threshold for Ho:YAG and TFL measured 82.6 and 20.8 J/cm2, respectively. Stone retropulsion with the Ho:YAG laser linearly increased with pulse energy. Retropulsion with TFL was minimal at pulse rates less than 150 Hz, then rapidly increased at higher pulse rates. For minimal stone retropulsion, Ho:YAG operation at pulse energies less than 175 mJ at 10 Hz and TFL operation at 35 mJ at 100 Hz is recommended, with both lasers producing comparable ablation rates. Further development of a TFL operating with both high pulse energies of 100 to 200 mJ and high pulse rates of 100 to 150 Hz may also provide an alternative to the Ho:YAG laser for higher ablation rates, when retropulsion is not a primary concern.

  10. Holmium laser enucleation of the prostate: surgical, functional, and quality-of-life outcomes upon extended follow-up

    PubMed Central

    Alkan, Ilter; Ozveri, Hakan; Akin, Yigit; Ipekci, Tumay; Alican, Yusuf

    2016-01-01

    ABSTRACT Objectives: To evaluate the long-term surgical, functional, and quality-of-life (QoL) outcomes after Holmium laser enucleation of the prostate (HoLEP) in patients with symptomatic benign prostatic hyperplasia (BPH). Materials and Methods: We retrospectively reviewed recorded data on patients who underwent HoLEP between June 2002 and February 2005. Ninety-six patients were enrolled. Demographic, perioperative, and postoperative data were recorded. On follow-up, International Prostate Symptom Scores (IPSSs), prostate-specific antigen (PSA) levels, QoL scores, peak uroflowmetric data (Qmax values), and post-voiding residual urine volumes (PVR volumes), were recorded. Complications were scored using the Clavien system. Statistical significance was set at p<0.05. Results: The mean follow-up time was 41.8±34.6 months and the mean patient age 73.2±8.7 years. The mean prostate volume was 74.6±34.3mL. Significant improvements in Qmax values, QoL, and IPSSs and decreases in PSA levels and PVR volumes were noted during follow-up (all p values=0.001). The most common complication was a requirement for re-catheterisation because of urinary retention. Two patients had concomitant bladder tumours that did not invade the muscles. Eight patients (8.3%) required re-operations; three had residual adenoma, three urethral strictures, and two residual prostate tissue in the bladder. Stress incontinence occurred in one patient (1%). All complications were of Clavien Grade 3a. We noted no Clavien 3b, 4, or 5 complications during follow-up. Conclusions: HoLEP improved IPSSs, Qmax values, PVR volumes, and QoL and was associated with a low complication rate, during extended follow-up. Thus, HoLEP can be a viable option to transurethral resection of the prostate. PMID:27256184

  11. Stability of short, single-mode erbium-doped fiber lasers

    SciTech Connect

    Svalgaard, M.; Gilbert, S.L.

    1997-07-01

    We conducted a detailed study of the stability of short, erbium-doped fiber lasers fabricated with two UV-induced Bragg gratings written into the doped fiber. We find that the relative intensity noise of single-longitudinal-mode fiber grating lasers is approximately 3 orders of magnitude lower than that of a single-frequency 1.523-{mu}m helium-neon laser. The frequency noise spectrum contains few resonances, none of which exceeds 0.6 kHz/Hz{sup 1/2} rms; the integrated rms frequency noise from 50 Hz to 63 kHz is 36 kHz. We also demonstrate a simple method for monitoring the laser power and number of oscillating modes during laser fabrication. {copyright} 1997 Optical Society of America

  12. Magnetic behavior of erbium-zinc-borate glasses and glass ceramics

    SciTech Connect

    Borodi, G.; Pascuta, P.; Bosca, M.; Pop, V.; Stefan, R.; Tetean, R.; Radulescu, D.

    2013-11-13

    Glasses of the system (Er{sub 2}O{sub 3}){sub x}⋅(B{sub 2}O{sub 3}){sub (60−x)}⋅(ZnO){sub 40} (3 ≤ x ≤ 15 mol%) were prepared by conventional melt quenching and subsequently converted to glass ceramics by heat treatment of glass samples at 860 °C for 2 h. The magnetic behaviour of the studied glasses and glass ceramics were investigated using a vibrating sample magnetometer (VSM) and a Faraday-type magnetic balance. Magnetic data show that erbium ions are involved in negative superexchange interactions in all the investigated samples, being antiferromagnetically coupled. For all studied samples the experimental values obtained for the effective magnetic moments are lower than the value corresponding to free Er{sup 3+} ions and decrease with the increasing of Er{sub 2}O{sub 3} content. The decrease is more pronounced in heat treated samples than untreated ones.

  13. Submicrojoule femtosecond erbium-doped fibre laser for the generation of dispersive waves at submicron wavelengths

    SciTech Connect

    Kotov, L V; Koptev, M Yu; Anashkina, E A; Muravyev, S V; Andrianov, A V; Kim, A V; Bubnov, M M; Likhachev, M E; Ignat'ev, A D; Lipatov, D S; Gur'yanov, A N

    2014-05-30

    We have demonstrated a femtosecond erbium-doped fibre laser system built in the master oscillator/power amplifier (MOPA) approach. The final amplifier stage utilises a specially designed large mode area active fibre cladding-pumped by multimode laser diodes. The system is capable of generating submicrojoule pulses at a wavelength near 1.6 μm. We have obtained 530-fs pulses with an energy of 400 nJ. The output of the system can be converted to wavelengths shorter than 1 μm through the generation of dispersive waves in passive nonlinear fibre. We have obtained ultra-short 7-nJ pulses with a spectral width of ∼100 nm and a centre wavelength of 0.9 μm, which can be used as a seed signal in parametric amplifiers in designing petawatt laser systems. (lasers)

  14. Theoretical study on erbium ytterbium co-doped super-fluorescent fiber source

    NASA Astrophysics Data System (ADS)

    Wentao, Guo; Feng, Du; Manqing, Tan; Jian, Jiao; Xiaofeng, Guo

    2016-01-01

    Erbium ytterbium co-doped super-fluorescent fiber source (EYD-SFS) has been simulated by a theoretical model based on rate equations and power transfer equations. The output performances of four basic structures of EYD-SFS have been expressed, and it indicated that the DPF structure is a preferable structure. The dependence of output power, mean wavelength and bandwidth stability on the pump fiber length and the concentration of Er3+ and Yb3+ have also been studied. The results indicated with a proper doping concentration of Er3+ and Yb3+ of 6.0 × 1026 ions/m3 and 1.0 × 1027 ions/m3, the optimal gain fiber length is 3.6 cm. In this condition, good performances of DPF structure of EYD-SFS have been achieved.

  15. 70-fs mode-locked erbium-doped fiber laser with topological insulator.

    PubMed

    Liu, Wenjun; Pang, Lihui; Han, Hainian; Tian, Wenlong; Chen, Hao; Lei, Ming; Yan, Peiguang; Wei, Zhiyi

    2016-01-01

    Femtosecond optical pulses have applications in optical communication, astronomical frequency combs, and laser spectroscopy. Here, a hybrid mode-locked erbium-doped fiber (EDF) laser with topological insulator (TI) is proposed, for the first time to our best knowledge. The pulsed laser deposition (PLD) method is employed to fabricate the fiber-taper TI saturable absorber (TISA). By virtue of the fiber-taper TISA, the hybrid EDF laser is passively mode-locked using the nonlinear polarization evolution (NPE), and emits 70 fs pulses at 1542 nm, whose 3 dB spectral width is 63 nm with a repetition rate and transfer efficiency of 95.4 MHz and 14.12%, respectively. Our experiments indicate that the proposed hybrid mode-locked EDF lasers have better performance to achieve shorter pulses with higher power and lower mode-locking threshold in the future. PMID:26813439

  16. Accelerated two-wave mixing response in erbium-doped fibers with saturable optical absorption

    NASA Astrophysics Data System (ADS)

    Hernandez, Eliseo; Stepanov, Serguei; Plata Sanchez, Marcos

    2016-08-01

    The contribution of the spatially uniform variation of average optical absorption to the dynamics of the transient two-wave mixing (TWM) response is considered. It is shown theoretically and confirmed experimentally that this transient effect, via dynamic population gratings in erbium-doped fibers (EDFs) can ensure a response nearly two times faster in such gratings as compared to the growth rate of fluorescence uniformly excited under similar conditions, and can also result in an additional overshot in the tail of the TWM response. This additional ‘accelerating’ contribution is of even type, and does not influence the odd transient TWM response for the refractive index component of such gratings in the EDFs reported earlier. It is also shown that this effect can be utilized to monitor the formation of the dynamic grating with an auxiliary probe wave of the essentially different non-Bragg wavelength.

  17. Effect of ion concentration on slow light propagation in highly doped erbium fibers

    NASA Astrophysics Data System (ADS)

    Melle, Sonia; Calderón, Oscar G.; Carreño, F.; Cabrera, Eduardo; Antón, M. A.; Jarabo, S.

    2007-11-01

    The effect of ion density on slow light propagation enabled by coherent population oscillations has been experimentally investigated for highly doped erbium fibers at room temperature. We found that fractional delay increases with ion density. A saturation effect in the fractional delay has been observed for doping levels above ˜3150 ppm. Ultra-high ion concentration can simultaneously increase the fractional delay and the bandwidth of the signals. We have studied the propagation of Gaussian pulses along the fibers obtaining fractional delays up to 0.7 for the highest doping levels used. It is shown that pulse power can be used as a control parameter to reduce distortion at different pulse bandwidths.

  18. N-order bright and dark rogue waves in a resonant erbium-doped fiber system.

    PubMed

    He, Jingsong; Xu, Shuwei; Porsezian, K; Porseizan, K

    2012-12-01

    The rogue waves in a resonant erbium-doped fiber system governed by a coupled system of the nonlinear Schrödinger equation and the Maxwell-Bloch equation (NLS-MB equations) are given explicitly by a Taylor series expansion about the breather solutions of the normalized slowly varying amplitude of the complex field envelope E, polarization p, and population inversion η. The n-order breather solutions of the three fields are constructed using a Darboux transformation (DT) by assuming periodic seed solutions. Moreover, the n-order rogue waves are given by determinant forms with n+3 free parameters. Furthermore, the possible connection between our rouge waves and the generation of supercontinuum generation is discussed. PMID:23368068

  19. Suppression of thermal frequency noise in erbium-doped fiber random lasers.

    PubMed

    Saxena, Bhavaye; Bao, Xiaoyi; Chen, Liang

    2014-02-15

    Frequency and intensity noise are characterized for erbium-doped fiber (EDF) random lasers based on Rayleigh distributed feedback mechanism. We propose a theoretical model for the frequency noise of such random lasers using the property of random phase modulations from multiple scattering points in ultralong fibers. We find that the Rayleigh feedback suppresses the noise at higher frequencies by introducing a Lorentzian envelope over the thermal frequency noise of a long fiber cavity. The theoretical model and measured frequency noise agree quantitatively with two fitting parameters. The random laser exhibits a noise level of 6  Hz²/Hz at 2 kHz, which is lower than what is found in conventional narrow-linewidth EDF fiber lasers and nonplanar ring laser oscillators (NPROs) by a factor of 166 and 2, respectively. The frequency noise has a minimum value for an optimum length of the Rayleigh scattering fiber.

  20. High dispersive mirrors for erbium-doped fiber chirped pulse amplification system.

    PubMed

    Chen, Yu; Wang, Yanzhi; Wang, Linjun; Zhu, Meiping; Qi, Hongji; Shao, Jianda; Huang, Xiaojun; Yang, Sheng; Li, Chao; Zhou, Kainan; Zhu, Qihua

    2016-08-22

    We report on the development of near-infrared high dispersive mirrors (HDM) with a group delay dispersion (GDD) of -2000 fs2. A HDM pair based on one optimized result at two reference wavelengths (1550 nm and 1560 nm) can reduce the total oscillation of the GDD effectively in the wavelength range of 1530-1575 nm. This HDM pair is designed and fabricated in a single coating run by means of the nonuniformity in film deposition. For the first time, near-infrared HDMs with two different reference wavelengths have been successfully applied in an erbium-doped fiber chirped pulse amplification system for the compression of 4.73 ps laser pulses to 380 fs. PMID:27557259

  1. Frequency spacing switchable multiwavelength Brillouin erbium fiber laser utilizing cascaded Brillouin gain fibers.

    PubMed

    Wang, Xiaorui; Yang, Yanfu; Liu, Meng; Yuan, Yijun; Sun, Yunxu; Gu, Yinglong; Yao, Yong

    2016-08-10

    A new hybrid Brillouin erbium fiber laser scheme that employs cascaded multiple Brillouin gain fibers in a ring cavity to realize multiwavelength laser output with switchable frequency spacing is proposed and experimentally investigated. The multiple frequency downshifting processes introduced by multiple stimulated Brillouin scattering (SBS) effects in one round-trip of the cavity make it possible to realize multiwavelength output with frequency spacing that is an integer multiple of the SBS frequency shifting. With two cascaded SBS fibers, the frequency spacing can be switched between single and double SBS frequency shifting by properly adjusting the Brillouin pump power. Multiwavelength outputs with triple or quadruple SBS frequency spacing are also demonstrated by employing three or four SBS gain fibers, respectively. PMID:27534498

  2. [INVITED] Multiwavelength operation of erbium-doped fiber-ring laser for temperature measurements

    NASA Astrophysics Data System (ADS)

    Diaz, S.; Lopez-Amo, M.

    2016-04-01

    In this work, simultaneous lasing at up to eight wavelengths is demonstrated in a multi-wavelength erbium-doped fiber ring laser previously reported. This is achieved by introducing a feedback fiber loop in a fiber ring cavity. Eight-wavelength laser emission lines were obtained simultaneously in single-longitudinal mode operation showing a power instability lower than 0.8 dB, and an optical signal-to-noise ratio higher than 42 dB for all the emitted wavelengths. The fiber Bragg gratings give this source the possibility to be also used as sensor-network multiplexing scheme. The application of this system for remote temperature measurements has been demonstrated obtaining good time stability results.

  3. Quantum storage of entangled telecom-wavelength photons in an erbium-doped optical fibre

    NASA Astrophysics Data System (ADS)

    Saglamyurek, Erhan; Jin, Jeongwan; Verma, Varun B.; Shaw, Matthew D.; Marsili, Francesco; Nam, Sae Woo; Oblak, Daniel; Tittel, Wolfgang

    2015-02-01

    The realization of a future quantum Internet requires the processing and storage of quantum information at local nodes and interconnecting distant nodes using free-space and fibre-optic links. Quantum memories for light are key elements of such quantum networks. However, to date, neither an atomic quantum memory for non-classical states of light operating at a wavelength compatible with standard telecom fibre infrastructure, nor a fibre-based implementation of a quantum memory, has been reported. Here, we demonstrate the storage and faithful recall of the state of a 1,532 nm wavelength photon entangled with a 795 nm photon, in an ensemble of cryogenically cooled erbium ions doped into a 20-m-long silica fibre, using a photon-echo quantum memory protocol. Despite its currently limited efficiency and storage time, our broadband light-matter interface brings fibre-based quantum networks one step closer to reality.

  4. Q-switched Erbium-doped fiber laser using MoSe2 as saturable absorber

    NASA Astrophysics Data System (ADS)

    Ahmad, H.; Suthaskumar, M.; Tiu, Z. C.; Zarei, A.; Harun, S. W.

    2016-05-01

    A Q-switched Erbium-doped fiber laser by using MoSe2 thin film as saturable absorber is experimentally demonstrated. The bulk MoSe2 is processed into few layer MoSe2 based on liquid phase exfoliation technique, and further fabricated into thin film by using polyvinyl alcohol polymer. Q-switching operation is obtained from pump power range of 22.4-102.0 mW. The pulse repetition rate shows an increasing trend from 16.9 kHz to 32.8 kHz, whereas the pulse width exhibits a decreasing trend from 59.1 μs to 30.4 μs. The highest pulse energy of 57.9 nJ is obtained at pump power of 102.0 mW.

  5. High dispersive mirrors for erbium-doped fiber chirped pulse amplification system.

    PubMed

    Chen, Yu; Wang, Yanzhi; Wang, Linjun; Zhu, Meiping; Qi, Hongji; Shao, Jianda; Huang, Xiaojun; Yang, Sheng; Li, Chao; Zhou, Kainan; Zhu, Qihua

    2016-08-22

    We report on the development of near-infrared high dispersive mirrors (HDM) with a group delay dispersion (GDD) of -2000 fs2. A HDM pair based on one optimized result at two reference wavelengths (1550 nm and 1560 nm) can reduce the total oscillation of the GDD effectively in the wavelength range of 1530-1575 nm. This HDM pair is designed and fabricated in a single coating run by means of the nonuniformity in film deposition. For the first time, near-infrared HDMs with two different reference wavelengths have been successfully applied in an erbium-doped fiber chirped pulse amplification system for the compression of 4.73 ps laser pulses to 380 fs.

  6. Broadly tunable multiwavelength Brillouin-erbium fiber laser using a twin-core fiber coupler

    NASA Astrophysics Data System (ADS)

    Peng, Wanjing; Yan, Fengping; Li, Qi; Liu, Shuo; Tan, Siyu; Feng, Suchun; Feng, Ting

    2014-07-01

    A tunable multiwavelength Brillouin-erbium fiber laser (MW-BEFL) using a twin-core fiber (TCF) coupler is proposed and demonstrated. The TCF coupler is formed by splicing a section of TCF between two single-mode fibers. By simply applying bending curvature on the TCF coupler, the peak net gain is shifted close to the Brillouin pump (BP), which has advantage for suppressing self-lasing cavity modes with low-BP-power injection. In this work, the dependency of the Stokes signals tuning range on the free spectral range (FSR) of TCF coupler is studied. It is also found that the tuning range of MW-BEFL can exceed the FSR of TCF coupler by adopting proper BP power and 980-nm pump power. Up to 40 nm tuning range of MW-BEFL in the absence of self-lasing cavity modes is achieved.

  7. Timing stability enhancement of an Erbium Doped mode locked Fiber Laser using SESAM mirror

    NASA Astrophysics Data System (ADS)

    Afifi, G.; Khedr, M. Atta; Badr, Y.; Danailov, M.; Sigalotti, P.; Cinquegrana, P.; Alsous, M. B.; Galaly, A. R.

    2016-05-01

    We report on an examination of pulse timing stability of a home built Erbium Doped Fiber Laser (EDFL) passively mode locked via nonlinear polarization rotation by inserting semiconductor saturable absorber mirror (SESAM) in laser cavity. A very low root mean square (RMS) timing jitter (less than 27 fsec) and faster self-starting mode locking have been established. In order to get clear, low noise signal for time resolving measurements, synchronization of EDFL laser with an external high precision electronic oscillator have been established. Subsequently, it is synchronized and optically cross-correlated with a Ti:Sapphire laser source (Micra). The measured relative timing jitter was found to be less than 65 fsec. In this way, the two, well synchronized Ti:Sapphire and EDFL laser pulses prove to be a powerful tool for time resolving measurements.

  8. Waveform reconstruction for an ultrasonic fiber Bragg grating sensor demodulated by an erbium fiber laser.

    PubMed

    Wu, Qi; Okabe, Yoji

    2015-02-01

    Fiber Bragg grating (FBG) demodulated by an erbium fiber laser (EFL) has been used for ultrasonic detection recently. However, due to the inherent relaxation oscillation (RO) of the EFL, the detected ultrasonic signals have large deformations, especially in the low-frequency range. We proposed a novel data processing method to reconstruct an actual ultrasonic waveform. The noise spectrum was smoothed first; the actual ultrasonic spectrum was then obtained by deconvolution in order to mitigate the influence of the RO of the EFL. We proved by experiment that this waveform reconstruction method has high precision, and demonstrated that the FBG sensor demodulated by the EFL will have large practical applications in nondestructive testing. PMID:25967776

  9. 70-fs mode-locked erbium-doped fiber laser with topological insulator

    PubMed Central

    Liu, Wenjun; Pang, Lihui; Han, Hainian; Tian, Wenlong; Chen, Hao; Lei, Ming; Yan, Peiguang; Wei, Zhiyi

    2016-01-01

    Femtosecond optical pulses have applications in optical communication, astronomical frequency combs, and laser spectroscopy. Here, a hybrid mode-locked erbium-doped fiber (EDF) laser with topological insulator (TI) is proposed, for the first time to our best knowledge. The pulsed laser deposition (PLD) method is employed to fabricate the fiber-taper TI saturable absorber (TISA). By virtue of the fiber-taper TISA, the hybrid EDF laser is passively mode-locked using the nonlinear polarization evolution (NPE), and emits 70 fs pulses at 1542 nm, whose 3 dB spectral width is 63 nm with a repetition rate and transfer efficiency of 95.4 MHz and 14.12%, respectively. Our experiments indicate that the proposed hybrid mode-locked EDF lasers have better performance to achieve shorter pulses with higher power and lower mode-locking threshold in the future. PMID:26813439

  10. Radiation tests on erbium-doped garnet crystals for spaceborne CH4-Lidar applications

    NASA Astrophysics Data System (ADS)

    Meissner, Ansgar; Kreitler, Martin; Cubera, Miroslaw; Kucirek, Philipp; Gronloh, Bastian; Esser, Dominik; Höfer, Marco; Hoffmann, Hans-Dieter

    2015-02-01

    A test campaign for assessing the radiation hardness of different Erbium-doped garnet crystals including Er:YAG and a compositionally tuned Er:YAG/Er:LuAG mixed garnet is reported. Tests with proton and gamma radiation have been performed with parameters mimicking a 3-year low-earth-orbit satellite mission like MERLIN or ADM-Aeolus. For each test sample broadband transmission spectra in the wavelength range of 500 nm - 1700 nm and characteristic laser curves from a test laser oscillator have been measured. Radiation-induced losses have been calculated from the obtained data. The results indicate that gamma radiation is the dominant loss source with about 0.5 %/cm radiation-induced losses for the nominal dose of the chosen mission scenario.

  11. Broadband supercontinuum generation with femtosecond pulse width in erbium-doped fiber laser (EDFL)

    NASA Astrophysics Data System (ADS)

    Rifin, S. N. M.; Zulkifli, M. Z.; Hassan, S. N. M.; Munajat, Y.; Ahmad, H.

    2016-11-01

    We demonstrate two flat plateaus and the low-noise spectrum of supercontinuum generation (SCG) in a highly nonlinear fiber (HNLF), injected by an amplified picosecond pulse seed of a carbon nanotube-based passively mode locked erbium-doped fiber laser. A broad spectrum of width approximately 1090 nm spanning the range 1130-2220 nm is obtained and the pulse width is compressed to the shorter duration of 70 fs. Variations of the injected peak power up to 33.78 kW into the HNLF are compared and the broad spectrum SCG profiles slightly expand for each of the injected peak powers. This straightforward configuration of SCG offers low output power and ultra-narrow femtosecond pulse width. The results facilitate the development of all fiber time-domain spectroscopy systems based on the photoconductive antenna technique.

  12. 70-fs mode-locked erbium-doped fiber laser with topological insulator.

    PubMed

    Liu, Wenjun; Pang, Lihui; Han, Hainian; Tian, Wenlong; Chen, Hao; Lei, Ming; Yan, Peiguang; Wei, Zhiyi

    2016-01-27

    Femtosecond optical pulses have applications in optical communication, astronomical frequency combs, and laser spectroscopy. Here, a hybrid mode-locked erbium-doped fiber (EDF) laser with topological insulator (TI) is proposed, for the first time to our best knowledge. The pulsed laser deposition (PLD) method is employed to fabricate the fiber-taper TI saturable absorber (TISA). By virtue of the fiber-taper TISA, the hybrid EDF laser is passively mode-locked using the nonlinear polarization evolution (NPE), and emits 70 fs pulses at 1542 nm, whose 3 dB spectral width is 63 nm with a repetition rate and transfer efficiency of 95.4 MHz and 14.12%, respectively. Our experiments indicate that the proposed hybrid mode-locked EDF lasers have better performance to achieve shorter pulses with higher power and lower mode-locking threshold in the future.

  13. Hybrid mode-locked erbium-doped all-fiber soliton laser with a distributed polarizer.

    PubMed

    Chernykh, D S; Krylov, A A; Levchenko, A E; Grebenyukov, V V; Arutunyan, N R; Pozharov, A S; Obraztsova, E D; Dianov, E M

    2014-10-10

    A soliton-type erbium-doped all-fiber ring laser hybrid mode-locked with a co-action of arc-discharge single-walled carbon nanotubes (SWCNTs) and nonlinear polarization evolution (NPE) is demonstrated. For the first time, to the best of our knowledge, boron nitride-doped SWCNTs were used as a saturable absorber for passive mode-locking initiation. Moreover, the NPE was introduced through the implementation of the short-segment polarizing fiber. Owing to the NPE action in the laser cavity, significant pulse length shortening as well as pulse stability improvement were observed as compared with a SWCNTs-only mode-locked laser. The shortest achieved pulse width of near transform-limited solitons was 222 fs at the output average power of 9.1 mW and 45.5 MHz repetition frequency, corresponding to the 0.17 nJ pulse energy.

  14. Isotope shift in erbium I by laser-atomic-beam spectroscopy

    NASA Astrophysics Data System (ADS)

    Okamura, H.; Matsuki, S.

    1987-04-01

    High-resolution laser spectroscopy has been performed on an atomic beam of natural erbium isotopes. The isotope shift in the 582.7 nm transitions [4f126s2( 3H6)-->4f12( 3H6)66( 3P01)J=7] for the pairs of 162,164,166,167,168,170Er I was obtained with an accuracy of about 4 MHz. Relative changes of mean-square nuclear charge radii δ for these isotopes were thus deduced. The isotope shift in 167Er, obtained from the well-resolved hyperfine components, shows similar even-odd staggering effect in δ found in the nearby elements.

  15. Simplified ASE correction algorithm for variable gain-flattened erbium-doped fiber amplifier.

    PubMed

    Mahdi, Mohd Adzir; Sheih, Shou-Jong; Adikan, Faisal Rafiq Mahamd

    2009-06-01

    We demonstrate a simplified algorithm to manifest the contribution of amplified spontaneous emission in variable gain-flattened Erbium-doped fiber amplifier (EDFA). The detected signal power at the input and output ports of EDFA comprises of both signal and noise. The generated amplified spontaneous emission from EDFA cannot be differentiated by photodetector which leads to underestimation of the targeted gain value. This gain penalty must be taken into consideration in order to obtain the accurate gain level. By taking the average gain penalty within the dynamic gain range, the targeted output power is set higher than the desired level. Thus, the errors are significantly reduced to less than 0.15 dB from 15 dB to 30 dB desired gain values.

  16. Magnetic and structural phase transitions in erbium at low temperatures and high pressures

    SciTech Connect

    Thomas, Sarah A.; Tsoi, Georgiy M.; Wenger, Lowell E.; Vohra, Yogesh K.

    2012-02-07

    Electrical resistance and crystal structure measurements have been carried out on polycrystalline erbium (Er) at temperatures down to 10 K and pressures up to 20 GPa. An abrupt change in the slope of the resistance is observed with decreasing temperature below 84 K, which is associated with the c-axis modulated (CAM) antiferromagnetic (AFM) ordering of the Er moments. With increasing pressure the temperature of the resistance slope change and the corresponding AFM ordering temperature decrease until vanishing above 10.6 GPa. The disappearance of the slope change in the resistance occurs at similar pressures where the hcp structural phase of Er is transformed to a nine-layer {alpha}-Sm structural phase, as confirmed by our high-pressure synchrotron x-ray diffraction studies. These results suggest that the disappearance in the AFM ordering of Er moments is strongly correlated to the structural phase transition at high pressures and low temperatures.

  17. Temperature dependences of the photoluminescence intensities of centers in silicon implanted with erbium and oxygen ions

    SciTech Connect

    Sobolev, N. A. Shtel’makh, K. F.; Kalyadin, A. E.; Shek, E. I.

    2015-12-15

    Low-temperature photoluminescence in n-Cz-Si after the implantation of erbium ions at an elevated temperature and subsequent implantation of oxygen ions at room temperature is studied. So-called X and W centers formed from self-interstitial silicon atoms, H and P centers containing oxygen atoms, and Er centers containing Er{sup 3+} ions are observed in the photoluminescence spectra. The energies of enhancing and quenching of photoluminescence for these centers are determined. These energies are determined for the first time for X and H centers. In the case of P and Er centers, the values of the energies practically coincide with previously published data. For W centers, the energies of the enhancing and quenching of photoluminescence depend on the conditions of the formation of these centers.

  18. Glassy behavior in a one-dimensional continuous-wave erbium-doped random fiber laser

    NASA Astrophysics Data System (ADS)

    Gomes, Anderson S. L.; Lima, Bismarck C.; Pincheira, Pablo I. R.; Moura, André L.; Gagné, Mathieu; Raposo, Ernesto P.; de Araújo, Cid B.; Kashyap, Raman

    2016-07-01

    The photonic analog of the paramagnetic to spin-glass phase transition in disordered magnetic systems, signaled by the phenomenon of replica symmetry breaking, has been reported using random lasers as the photonic platform. We report here a demonstration of replica symmetry breaking in a one-dimensional photonic system consisting of an erbium-doped random fiber laser operating in the continuous-wave regime. The system is based on a unique random fiber grating system which plays the role of random scattering, providing the disordered feedback mechanism. The clear transition from a photonic paramagnetic to a photonic spin-glass phase, characterized by the Parisi overlap parameter, was verified and indicates the glassy random-fiber-laser behavior.

  19. Tunable erbium-doped fiber ring laser for applications of infrared absorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Ryu, Han Young; Lee, Won-Kyu; Moon, Han Seb; Suh, Ho Suhng

    2007-07-01

    We fabricate a low noise erbium-doped fiber ring laser that can be continuously tuned over 102 nm by insertion of the fiber Fabry-Perot tunable filter (FFP-TF) in the ring cavity with a novel cavity structure and the optimal gain medium length. As an application of this fiber ring laser, we performed the absorption spectroscopy of acetylene (13C2H2) and hydrogen cyanide (H13C14N) and measure the absorption spectra of more than 50 transition lines of these gases with an excellent signal to noise ratio (SNR). The pressure broadening coefficients of four acetylene transition lines are obtained using this fiber ring laser and an external cavity laser diode.

  20. Exploring Few- and Many-Body Dipolar Quantum Phenomena with Ultracold Erbium Atoms

    NASA Astrophysics Data System (ADS)

    Ferlaino, Francesca

    2016-05-01

    Given their strong magnetic moment and exotic electronic configuration, rare-earth atoms disclose a plethora of intriguing phenomena in ultracold quantum physics with dipole-dipole interaction. Here, we report on the first degenerate Fermi gas of erbium atoms, based on direct cooling of identical fermions via dipolar collisions. We reveal universal scattering laws between identical dipolar fermions close to zero temperature, and we demonstrate the long-standing prediction of a deformed Fermi surface in dipolar gas. Finally, we present the first experimental study of an extended Bose-Hubbard model using bosonic Er atoms in a three-dimensional optical lattice and we report on the first observation of nearest-neighbor interactions.

  1. Amplification and noise properties of an erbium-doped multicore fiber amplifier.

    PubMed

    Abedin, K S; Taunay, T F; Fishteyn, M; Yan, M F; Zhu, B; Fini, J M; Monberg, E M; Dimarcello, F V; Wisk, P W

    2011-08-15

    A multicore erbium-doped fiber (MC-EDF) amplifier for simultaneous amplification in the 7-cores has been developed, and the gain and noise properties of individual cores have been studied. The pump and signal radiation were coupled to individual cores of MC-EDF using two tapered fiber bundled (TFB) couplers with low insertion loss. For a pump power of 146 mW, the average gain achieved in the MC-EDF fiber was 30 dB, and noise figure was less than 4 dB. The net useful gain from the multicore-amplifier, after taking into consideration of all the passive losses, was about 23-27 dB. Pump induced ASE noise transfer between the neighboring channel was negligible. PMID:21935033

  2. Stable single-longitudinal-mode erbium-doped fiber laser with dual-ring structure

    NASA Astrophysics Data System (ADS)

    Yeh, Chien-Hung; Chen, Jhih-Yu; Chen, Hone-Zhang; Chow, Chi-Wai

    2016-01-01

    In this paper, we propose and demonstrate experimentally a stable erbium-doped fiber (EDF) laser with single-longitudinal-mode (SLM) output by employing dual-ring structure. By using the multiple ring architecture, the densely spaced longitudinal modes would be suppressed and generated a SLM lasing output. In the measurement, the wavelength can be tuned in the wavelengths of 1530.0-1560.0 nm. And the measured output powers and side-mode suppression ratios (SMSRs) are between 5.2 and 14.1 dBm and 30.4 and 39.8 dB, respectively. In addition, the output stabilities of wavelength and power in proposed fiber laser have also been discussed.

  3. Frequency spacing switchable multiwavelength Brillouin erbium fiber laser utilizing cascaded Brillouin gain fibers.

    PubMed

    Wang, Xiaorui; Yang, Yanfu; Liu, Meng; Yuan, Yijun; Sun, Yunxu; Gu, Yinglong; Yao, Yong

    2016-08-10

    A new hybrid Brillouin erbium fiber laser scheme that employs cascaded multiple Brillouin gain fibers in a ring cavity to realize multiwavelength laser output with switchable frequency spacing is proposed and experimentally investigated. The multiple frequency downshifting processes introduced by multiple stimulated Brillouin scattering (SBS) effects in one round-trip of the cavity make it possible to realize multiwavelength output with frequency spacing that is an integer multiple of the SBS frequency shifting. With two cascaded SBS fibers, the frequency spacing can be switched between single and double SBS frequency shifting by properly adjusting the Brillouin pump power. Multiwavelength outputs with triple or quadruple SBS frequency spacing are also demonstrated by employing three or four SBS gain fibers, respectively.

  4. Stable and tunable self-seeded multiwavelength Brillouin-erbium fiber laser with higher OSNR

    NASA Astrophysics Data System (ADS)

    Zou, Hui; Yang, Ruilan; Shen, Xiao; Wei, Wei

    2016-07-01

    A stable and tunable self-seeded multiwavelength Brillouin-erbium fiber laser (BEFL) is designed and demonstrated based on a Single-Mode-Multimode-Single-Mode (SMS) fiber filter. The SMS filter is fabricated by splicing a 15 cm long multimode fiber between two single mode fibers. The self-excited Brillouin pump is internally achieved by cascaded stimulated Brillouin scattering (SBS) in the single mode fiber. By applying axial strain (from 0 to 466.7 μɛ) to the SMS filter with the same step of 66.7 μɛ , the multiwavelength of the output laser is tuned from 1553.58 to 1559.79 nm correspondingly, and the tunable range is 6.21 nm. The generation of up to 16 Brillouin Stokes wavelengths with 30 dB optical signal to noise ratio (OSNR) are obtained.

  5. Simple and efficient L-band erbium-doped fiber amplifiers for WDM networks

    NASA Astrophysics Data System (ADS)

    Choi, H. B.; Oh, J. M.; Lee, D.; Ahn, S. J.; Park, B. S.; Lee, S. B.

    2002-11-01

    The performance of L-band erbium-doped fiber amplifier (EDFA) of a simple structure with a fiber Bragg grating (FBG) was investigated. The injected C-band ASE by the FBG offers low-cost amplification and greatly improves the efficiency of the EDFA. There are 9 and 4 dB improvements with the FBG at 1587 nm, at low and high input, respectively. The flat gain of 18 dB, up to a total input of -5 dBm at 150 mW of 980 nm pump, is obtained over 30 nm with less than ±0.5 dB gain variations without any gain equalizer. The proposed EDFA provides a cost-effective solution for wavelength division multiplexing systems.

  6. Different operation states of soliton pulses in an erbium-doped fibre ring laser

    NASA Astrophysics Data System (ADS)

    Zhang, Shu-Min; Lü, Fu-Yun; Gong, Yan-Dong; Yang, Xiu-Feng

    2007-07-01

    We report on the experimental observation of soliton pulses in an erbium doped fibre ring laser. The passive mode-locking is achieved using the nonlinear polarization rotation technique. By adjusting the pump power and the intracavity polarization controllers, a normal soliton, a stable 8th harmonic mode-locked pulse and a noise-like pulse have been observed in our laser. The experimental results revealed that the noise-like pulse is not suitable for the optical telecommunication, and in order to obtain the stable harmonic mode-locked soliton, a strong unstable CW laser field is necessary to mediate global soliton interaction. The formation mechanism of the harmonic mode-locked pulse has also been analysed.

  7. Measurements of erbium laser-ablation efficiency in hard dental tissues under different water cooling conditions.

    PubMed

    Kuščer, Lovro; Diaci, Janez

    2013-10-01

    Laser triangulation measurements of Er:YAG and Er,Cr:YSGG laser-ablated volumes in hard dental tissues are made, in order to verify the possible existence of a "hydrokinetic" effect that has been proposed as an alternative to the "subsurface water expansion" mechanism for hard-tissue laser ablation. No evidence of the hydrokinetic effect could be observed under a broad range of tested laser parameters and water cooling conditions. On the contrary, the application of water spray during laser exposure of hard dental material is observed to diminish the laser-ablation efficiency (AE) in comparison with laser exposure under the absence of water spray. Our findings are in agreement with the generally accepted principle of action for erbium laser ablation, which is based on fast subsurface expansion of laser-heated water trapped within the interstitial structure of hard dental tissues. Our measurements also show that the well-known phenomenon of ablation stalling, during a series of consecutive laser pulses, can primarily be attributed to the blocking of laser light by the loosely bound and recondensed desiccated minerals that collect on the tooth surface during and following laser ablation. In addition to the prevention of tooth bulk temperature buildup, a positive function of the water spray that is typically used with erbium dental lasers is to rehydrate these minerals, and thus sustaining the subsurface expansion ablation process. A negative side effect of using a continuous water spray is that the AE gets reduced due to the laser light being partially absorbed in the water-spray particles above the tooth and in the collected water pool on the tooth surface. Finally, no evidence of the influence of the water absorption shift on the hypothesized increase in the AE of the Er,Cr:YSGG wavelength is observed.

  8. Influence of Bi on the Er luminescence in yttrium-erbium disilicate thin films

    SciTech Connect

    Scarangella, Adriana; Miritello, Maria; Priolo, Francesco

    2014-09-28

    The influence of bismuth on erbium optical properties at 1.54 μm has been investigated in yttrium-erbium disilicate thin films synthesized by magnetron co-sputtering and implanted with two Bi different doses. The Bi depth distribution and the evolution of its oxidation states after annealing treatments at 1000 °C in two atmospheres, O₂ and N₂, have been investigated. It was found that only in O₂ the Bi³⁺ valence state is prevalent, thanks to the enhanced Bi mobility in the oxidizing ambient, as demonstrated by Rutherford backscattering spectrometry. At lower Bi content, although the formation of Bi⁰ metallic nanoparticles that are deleterious non radiative channels for Er luminescence, efficient energy transfer from Bi to Er has been obtained only in O₂. It is due to the excitation of ultraviolet broad Bi₃⁺ absorption band and the energy transfer to Er ions. We have evaluated that in this case, Er effective excitation cross section increased by a factor of 5 in respect with the one for direct Er absorption at 488 nm. At higher Bi dose, this mechanism is absent, but an increased Er optical efficiency at 1.54 μm has been observed under resonant excitation. It is due to the contribution of a fraction of Er ions having an increased lifetime. This phenomenon is associated with the formation of Bi agglomerates, induced at higher Bi doses, which well isolate Er from non-radiative quenching centers. The increased decay time assures higher optical efficiency at 1.54 μm.

  9. Experimental erbium: YAG laser photoablation of trabecular meshwork in rabbits: an in-vivo study.

    PubMed

    Dietlein, T S; Jacobi, P C; Schröder, R; Krieglstein, G K

    1997-05-01

    Photoablative laser trabecular surgery has been proposed as an outflow-enhancing treatment for open-angle glaucoma. The aim of the study was to investigate the time course of repair response following low-thermal Erbium: YAG laser trabecular ablation. In 20 anaesthetized rabbits gonioscopically controlled ab-interno photoablation of the ligamenta pectinata and underlying trabecular meshwork (TM) was performed with a single-pulsed (200 microseconds) Erbium: YAG (2.94 microns) laser. The right eye received 12-15 single laser pulses (2 mJ) delivered through an articulated zirconium fluoride fiberoptic and a 200 microns (core diameter) quartz fiber tip, the left unoperated eye served as control. At time intervals of 30 minutes, 2, 10, 30, and 60 days after laser treatment, eyes were processed for light- and scanning electron microscopy. The applied energy density of 6-4 J cm-2 resulted in visible dissection of the ligamenta pectinata and reproducible microperforations of the TM exposing scleral tissue accompanied by blood reflux from the aqueous plexus. The initial ablation zones measured 154 +/- 36 microns in depth and 45 +/- 6 microns in width. Collateral thermal damage zones were 22 +/- 8 microns. At two days post-operative, ablation craters were still blood- and fibrin-filled. The inner surface of the craters were covered with granulocytes. No cellular infiltration of the collateral thermal damage zone was observed. At 10 days post-operative, progressive fibroblastic proliferation was observed, resulting in dense scar tissue formation with anterior synechiae, proliferating capillaries and loss of intertrabecular spaces inside the range of former laser treatment at 60 days post-operative. Trabecular microperforations were closed 60 days after laser treatment in all rabbits. IOP in treated and contralateral eyes did not significantly change its level during whole period of observation. Low-thermal infrared laser energy with minimal thermal damage to collateral

  10. Corneal photoablation in vivo with the erbium:YAG laser: first report

    NASA Astrophysics Data System (ADS)

    Jean, Benedikt J.; Bende, Thomas; Matallana, Michael; Kriegerowski, Martin

    1995-05-01

    As an alternative to far-UV lasers for corneal refractive surgery, the Erbium:YAG laser may be used in TEM00 mode. The resulting gaussian beam profile leads to a certain amount of myopic correction per laser pulse. Although animal data suggest that the clinical outcome should be comparable to the UV-lasers, no human data were available until now. We performed Erbium:YAG laser areal ablation in 5 blind human eyes. In TEM00 mode, the laser parameters were: effective diameter of laser spot equals 3.4 mm, fluence equals 380 mJ/cm2, pulse duration equals 250 microsecond(s) , Repetition rate equals 4 Hz, Number of applied laser pulses equals 15. Four patients with no light perception, one with intact light projection on one eye (some of them scheduled for enucleation) were treated under topical anaesthesia. Patient selection and informed consent were agreed to by the University's independent Ethics Committee. Prior to laser irradiation, corneal epithelium was removed. A postoperative silicone cast of the cornea was analyzed with a confocal laser micro-topometer for the ablation profile. The eyes were treated with antibiotic ointment until the epithelium was closed. Clinical appearance and, where possible, profilometry of the ablated area was observed. The ablation profile in cornea was gaussian shaped with a maximal depth of 30 micrometers . During laser treatment, the corneal surface becomes opaque, clearing in a matter of seconds. Epithelial healing and clinical appearance was similar to excimer laser treatment. However, during the first week, the irradiated area shows subepithelial irregularities, resembling small bubbles, disappearing thereafter.

  11. Measurements of erbium laser-ablation efficiency in hard dental tissues under different water cooling conditions.

    PubMed

    Kuščer, Lovro; Diaci, Janez

    2013-10-01

    Laser triangulation measurements of Er:YAG and Er,Cr:YSGG laser-ablated volumes in hard dental tissues are made, in order to verify the possible existence of a "hydrokinetic" effect that has been proposed as an alternative to the "subsurface water expansion" mechanism for hard-tissue laser ablation. No evidence of the hydrokinetic effect could be observed under a broad range of tested laser parameters and water cooling conditions. On the contrary, the application of water spray during laser exposure of hard dental material is observed to diminish the laser-ablation efficiency (AE) in comparison with laser exposure under the absence of water spray. Our findings are in agreement with the generally accepted principle of action for erbium laser ablation, which is based on fast subsurface expansion of laser-heated water trapped within the interstitial structure of hard dental tissues. Our measurements also show that the well-known phenomenon of ablation stalling, during a series of consecutive laser pulses, can primarily be attributed to the blocking of laser light by the loosely bound and recondensed desiccated minerals that collect on the tooth surface during and following laser ablation. In addition to the prevention of tooth bulk temperature buildup, a positive function of the water spray that is typically used with erbium dental lasers is to rehydrate these minerals, and thus sustaining the subsurface expansion ablation process. A negative side effect of using a continuous water spray is that the AE gets reduced due to the laser light being partially absorbed in the water-spray particles above the tooth and in the collected water pool on the tooth surface. Finally, no evidence of the influence of the water absorption shift on the hypothesized increase in the AE of the Er,Cr:YSGG wavelength is observed. PMID:24105399

  12. Broadband erbium-doped fiber sources for the fiber-optic gyroscope

    SciTech Connect

    Wysocki, P.F.

    1992-01-01

    The sensitivity of early fiber-optic gyroscopes (FOG) fell short of the theoretical limit. The use of certain configurations, fiber components, and well designed optical sources can help the FOG reach this limit. Sources for the FOG must be broadband, spatially coherent and high power. They must produce a mean wavelength which is stable with respect to temperature and feedback from system components. Additionally, they must emit at long wavelengths, where silica fibers are insensitive to radiation induced losses. Two approaches to broadband, 1.55 [mu]m, erbium-doped fiber sources for the FOG are considered. The most promising approach is the superfluorescent fiber source (SFS), which utilizes amplification of spontaneous emission in a single pass or in two passes through the fiber, without a resonant cavity. Such sources have produced more than 50% conversion of pump photons near 980 nm or 1.48 [mu]m to source photons. Laser diode pumping in these pump bands is explored in detail. Depending on fiber length, pump power, pump wavelength, and SFS configuration, emission bandwidths between 8 and 27 nm are measured. The thermal coefficient of the mean wavelength of the SFS is consistently below 10 ppm/[degrees]C, and near 0 ppm/[degrees]C for certain design choices. The detrimental effects of feedback are reduced through optical isolation and the proper choice of FOG configuration. Issues such as the effect of multiple pump modes and loss mechanisms are treated by use of computer simulations. The broadband Er-doped wavelength-swept fiber laser (WSFL) is presented as an alternative to the SFS. This source utilizes an intracavity acousto-optic modulator to sweep the emission of an Er-doped laser across the gain curve of erbium. Theoretical and measured characteristics of such sources are discussed. The dynamic response of the WSFL and its coherence in an integrating system has been measured.

  13. All-optical logical gates based on pump-induced resonant nonlinearity in an erbium-doped fiber coupler.

    PubMed

    Li, Qiliang; Zhang, Zhen; Li, Dongqiang; Zhu, Mengyun; Tang, Xianghong; Li, Shuqin

    2014-12-01

    In this paper, we theoretically investigate all-optical logical gates based on the pump-induced resonant nonlinearity in an erbium-doped fiber coupler. The resonant nonlinearity yielded by the optical transitions between the (4)I(15/2) states and (4)I(13/2) states in Er(3+) induces the refractive index to change, which leads to switching between two output ports. First, we do a study on the switching performance, and calculate the extinction ratio (Xratio) of the device. Second, using the Xratio, we obtain the truth tables of the device. The results reveal that compared with other undoped nonlinear couplers, the erbium-doped fiber coupler can drop the switching threshold power. We also obtain different logic gates and logic operations in the cases of the same phase and different phase of two initial signals by changing the pump power.

  14. Switchable dual-wavelength erbium-doped fibre laser utilizing two-channel fibre Bragg grating fabricated by femtosecond laser

    NASA Astrophysics Data System (ADS)

    Shen, Fangcheng; Zhou, Kaiming; Zhang, Lin; Shu, Xuewen

    2016-10-01

    We propose and demonstrate a switchable dual-wavelength erbium-doped fibre ring laser. Competition between the lasing wavelengths in erbium-doped fibre laser at room temperature is suppressed by incorporating a two-channel fibre Bragg grating (TC-FBG), which consists of two highly localized sub-gratings fabricated by femtosecond laser in single mode fibre. Wavelengths and polarization states of the lasing lines are selected by the TC-FBG. Laser output can be switched between single- and dual-wavelength operations by simply adjusting the polarization controller. Stable dual-wavelength output is verified at room temperature with a power fluctuation less than 0.27 dB, and wavelength fluctuation less than 0.004 nm.

  15. Simultaneous measurement of strain and temperature using a high birefringence fiber loop mirror and an erbium-doped fiber

    NASA Astrophysics Data System (ADS)

    Shi, Jie; Xiao, Shilin; Chen, He; Zhu, Min; Bi, Meihua

    2010-12-01

    A fiber sensor configuration suitable for simultaneous measurement of temperature and strain is investigated. The sensor consists of a high-birefringence fiber loop mirror concatenating with an erbium-doped fiber. The high-birefringence fiber used in the configuration is capsule shaped polarization maintaining fiber, which serves as the sensor element. While the erbium-doped fiber acts as the temperature compensation module. By monitoring the peak power variation and peak wavelength shift, it is feasible to simultaneously measure temperature and strain. The experimental results show that the mean square errors for temperature and stain are 0.35°C and 13.34μɛ, respectively. The proposed sensor configuration shows several merits, including simple in structure, easy fabrication, low cost and high sensitivity.

  16. Performance Comparison of Mode-Locked Erbium-Doped Fiber Laser with Nonlinear Polarization Rotation and Saturable Absorber Approaches

    NASA Astrophysics Data System (ADS)

    A. Ismail, M.; J. Tan, S.; S. Shahabuddin, N.; W. Harun, S.; Arof, H.; H., Ahmad

    2012-05-01

    A mode-locked erbium-doped fiber laser (EDFL) is demonstrated using a highly concentrated erbium-doped fiber (EDF) as the gain medium in a ring configuration with and without a saturable absorber (SA). Without the SA, the proposed laser generates soliton pulses with a repetition rate of 12 MHz, pulse width of 1.11 ps and energy pulse of 1.6 pJ. By incorporating SA in the ring cavity, the optical output of the laser changes from soliton to stretched pulses due to the slight change in the group velocity dispersion. With the SA, a cleaner pulse is obtained with a repetition rate of 11.3 MHz, a pulse width of 0.58 ps and a pulse energy of 2.3 pJ.

  17. Investigation on stimulated Brillouin scattering characteristics in a highly doped Bismuth-based Erbium-doped fiber

    NASA Astrophysics Data System (ADS)

    Parvizi, R.; Harun, S. W.; Ali, N. M.; Ahmad, H.

    2010-11-01

    Stimulated Brillouin scattering (SBS) characteristics in a 49 cm long highly doped Bismuth-based Erbium doped fiber (Bi-EDF) is investigated in the ring and linear cavity configurations. At Brillouin pump (BP) power of 6 dBm, the Brillouin laser peak power of the optimized ring Brillouin Erbium fiber laser (BEFL) is obtained at 23 dB higher than the peak power of the conventional linear cavity at an up shifted wavelength of 0.08 nm. This Bi-EDF ring cavity operates at nearly 1563 nm wavelength region, which is up-shifted by 0.08 nm from the Brillouin pump wavelength with the side mode suppression ratios (SMSR) of 29 and 23 dB in the forward and backward directions, respectively.

  18. Operation of erbium-doped fiber amplifiers and lasers pumped with frequency-doubled Nd:YAG lasers

    SciTech Connect

    Farries, M.C. Ltd., Towcester, Northants, NN 12 8EQ ); Morkel, P.R.; Laming, R.I.; Birks, T.A.; Payne, D.N. ); Tarbox, E.J. )

    1989-10-01

    An optical amplifier consisting of an erbium-doped germanosilicate fiber optically pumped at 532 nm is described. Negligible excited-state absorption at 532 nm allows efficient pumping, enabling a gain of 34 dB at 1536 nm to be obtained for only 25 mW of pump power. The pulsed pump source produces negligible noise on the small signal if the pump repetition rate is above 10 kHz. Pulsed laser operation is achieved by pumping a Fabry-Perot erbium doped fiber laser with a frequency doubled Q-switch Nd-YAG laser. Pulses of 0.9-W peak power and 280-ns duration at 1.538{mu}m were obtained.

  19. The use of the erbium yttrium aluminium garnet (2,940 nm) in a laser-assisted apicectomy procedure.

    PubMed

    Reyhanian, A; Parker, S; Moshonov, J

    2008-09-27

    If conventional endodontic treatment is not possible or not successful, apical endodontic surgery may be indicated. New techniques, materials and technologies have been used to increase the already high success rate of root canal treatment. The purpose of this article is to describe the use of the Erbium:YAG (2,940 nm) laser in treatment of apicectomy as a central tool, with the advantages of enhanced patient comfort, better bactericidal and decontamination effects.

  20. Interactions between metal ions and carbohydrates. The coordination behavior of neutral erythritol to lanthanum and erbium ions.

    PubMed

    Yang, Limin; Xu, Yizhuang; Wang, Yalei; Zhang, Shiwei; Weng, Shifu; Zhao, Kui; Wu, Jinguang

    2005-12-30

    Lanthanide ions and erythritol form metal-alditol complexes with various structures. Lanthanum nitrate and erbium chloride coordinate to erythritol to give new coordination structures. The lanthanum nitrate-erythritol complex (LaEN), 2La(NO3)3.C4H10O(4).8H2O, La3+ exhibits the coordination number of 11 (namely 11 polar atoms bound to one lanthanum) and is 11-coordinated to two hydroxyl groups from one erythritol molecule, six oxygen atoms from three nitrate ions and three water molecules. One erythritol molecule is coordinated to two La3+ ions and links the two metal ions together. The ratio of M:L is 2:1. The erbium chloride-erythritol complex (ErE), ErCl2.C4H9O(4).2C2H5OH was obtained from ErCl3 and erythritol in aqueous ethanol solution and the structure shows that deprotonation reaction occurs in the reaction process. The Er3+ cation is 8-coordinated with three hydroxyl groups of one erythritol molecule, two hydroxyl groups from another erythritol molecule, two ethanol molecules, and one chloride ion. Erythritol provides its three hydroxyl groups to one erbium cation and two hydroxyl groups to another erbium cation, that is, one hydroxyl group is coordinated to two metal ions and therefore loses its hydrogen atom and becomes a oxygen bridge. Another chloride ion is hydrogen bonded in the structure. The results indicate the complexity of metal-sugar coordination.