Sample records for pressure total temperature

  1. Pressure and temperature effects on degradation kinetics and storage stability of total anthocyanins in blueberry juice.

    PubMed

    Buckow, Roman; Kastell, Anja; Terefe, Netsanet Shiferaw; Versteeg, Cornelis

    2010-09-22

    The degradation kinetics of total anthocyanins in blueberry (Vaccinium myrtillus) juice were studied during thermal processing by treatment at selected temperatures (60-121 °C) and combined high pressure-temperature processing (100-700 MPa, 40-121 °C). Anthocyanin stability was also studied for several of these treatments during storage at 4, 25, and 40 °C. Both pressure and temperature increased d, the degradation rate of total anthocyanins in blueberry juice, meaning that at constant temperature, anthocyanins were more rapidly degraded with increasing pressure. For example, 32% degradation of anthocyanins was observed after 20 min heating at 100 °C and atmospheric pressure, whereas at 100 °C and 600 MPa, approximately 50% of total anthocyanins were lost. Degradation of anthocyanins was significantly accelerated with increasing storage temperatures. Combined pressure-temperature treatment of pasteurized juice led to a slightly faster degradation of total anthocyanins during storage compared to heat treatments at ambient pressure. Degradation of anthocyanins was best described by a 1.4th-order reaction at all conditions investigated. A mathematical model describing the degradation of blueberry anthocyanins in juice as a function of pressure, temperature, and treatment time is presented.

  2. T700 Blisk and Impeller Manufacturing Process Development Program.

    DTIC Science & Technology

    1979-11-01

    700(40) Reworked Media Temperature - 790 F Average Media Pressure - 200 psi Total Cycles (Test No. 1) - 40 Total Cycles (Test No. 2) - 20 Total Time...36A(73), - 700(40" Media Temperature - 80F Average Media Pressure - 150 psi Total Cycles - 52 Total Time - 95 Minutes Some difficulty was...61)-36A(73)-700( 4O)Media Temperature - 79OF average Media Pressure - 200 psi Time - 40 cycles - 72 minutes Time - 60 cycles - 109 minutes Time - 80

  3. Evaluation of water cooled supersonic temperature and pressure probes for application to 1366 K flows

    NASA Technical Reports Server (NTRS)

    Lagen, Nicholas; Seiner, John M.

    1990-01-01

    Water cooled supersonic probes are developed to investigate total pressure, static pressure, and total temperature in high-temperature jet plumes and thereby determine the mean flow properties. Two probe concepts, designed for operation at up to 1366 K in a Mach 2 flow, are tested on a water cooled nozzle. The two probe designs - the unsymmetric four-tube cooling configuration and the symmetric annular cooling design - take measurements at 755, 1089, and 1366 K of the three parameters. The cooled total and static pressure readings are found to agree with previous test results with uncooled configurations. The total-temperature probe, however, is affected by the introduction of water coolant, and effect which is explained by the increased heat transfer across the thermocouple-bead surface. Further investigation of the effect of coolant on the temperature probe is proposed to mitigate the effect and calculate more accurate temperatures in jet plumes.

  4. Evaluation of water cooled supersonic temperature and pressure probes for application to 2000 F flows

    NASA Technical Reports Server (NTRS)

    Lagen, Nicholas T.; Seiner, John M.

    1990-01-01

    The development of water cooled supersonic probes used to study high temperature jet plumes is addressed. These probes are: total pressure, static pressure, and total temperature. The motivation for these experiments is the determination of high temperature supersonic jet mean flow properties. A 3.54 inch exit diameter water cooled nozzle was used in the tests. It is designed for exit Mach 2 at 2000 F exit total temperature. Tests were conducted using water cooled probes capable of operating in Mach 2 flow, up to 2000 F total temperature. Of the two designs tested, an annular cooling method was chosen as superior. Data at the jet exit planes, and along the jet centerline, were obtained for total temperatures of 900 F, 1500 F, and 2000 F, for each of the probes. The data obtained from the total and static pressure probes are consistent with prior low temperature results. However, the data obtained from the total temperature probe was affected by the water coolant. The total temperature probe was tested up to 2000 F with, and without, the cooling system turned on to better understand the heat transfer process at the thermocouple bead. The rate of heat transfer across the thermocouple bead was greater when the coolant was turned on than when the coolant was turned off. This accounted for the lower temperature measurement by the cooled probe. The velocity and Mach number at the exit plane and centerline locations were determined from the Rayleigh-Pitot tube formula.

  5. An analysis of data related to the minimum temperatures for valid testing in cryogenic wind tunnels using nitrogen as the test gas

    NASA Technical Reports Server (NTRS)

    Hall, R. M.

    1976-01-01

    The minimum operating temperature which avoids adverse low temperature effects, such as condensation, has been determined at a free stream Mach number of 0.85 for flow over a 0.137 meter airfoil mounted at zero incidence in the Langley 1/3 meter transonic cryogenic tunnel. The onset of low temperature effects is established by comparing the pressure coefficient measured at a given orifice for a particular temperature with those measured at temperatures sufficiently above where low temperature effects might be expected to occur. The pressure distributions over the airfoil are presented in tabular form. In addition, the comparisons of the pressure coefficient as a function of total temperature are presented graphically for chord locations of 0, 25, 50, and 75 percent. Over the 1.2 to 4.5 atmosphere total pressure range investigated, low temperature effects are not detected until total temperatures are 2 K, or more, below free stream saturation temperatures.

  6. Performance of a hydrogen burner to simulate air entering scramjet combustors. [simulation of total temperature, total pressure, and volume fraction of oxygen of air at flight conditions

    NASA Technical Reports Server (NTRS)

    Russin, W. R.

    1974-01-01

    Tests were conducted to determine the performance of a hydrogen burner used to produce a test gas that simulates air entering a scramjet combustor at various flight conditions. The test gas simulates air in that it duplicates the total temperature, total pressure, and the volume fraction of oxygen of air at flight conditions. The main objective of the tests was to determine the performance of the burner as a function of the effective exhaust port area. The conclusions were: (1) pressure oscillations of the chugging type were reduced in amplitude to plus or minus 2 percent of the mean pressure level by proper sizing of hydrogen, oxygen, and air injector flow areas; (2) combustion efficiency remained essentially constant as the exhaust port area was increased by a factor of 3.4; (3) the mean total temperature determined from integrating the exit radial gas property profiles was within plus or minus 5 percent of the theoretical bulk total temperature; (4) the measured exit total temperature profile had a local peak temperature more than 30 percent greater than the theoretical bulk total temperature; and (5) measured heat transfer to the burner liner was 75 percent of that predicted by theory based on a flat radial temperature profile.

  7. Unsteady Loss in the Stator Due to the Incoming Rotor Wake in a Highly-Loaded Transonic Compressor

    NASA Technical Reports Server (NTRS)

    Hah, Chunill

    2015-01-01

    The present paper reports an investigation of unsteady loss generation in the stator due to the incoming rotor wake in an advanced GE transonic compressor design with a high-fidelity numerical method. This advanced compressor with high reaction and high stage loading has been investigated both experimentally and analytically in the past. The measured efficiency in this advanced compressor is significantly lower than the design intention/goal. The general understanding is that the current generation of compressor design/analysis tools miss some important flow physics in this modern compressor design. To pinpoint the source of the efficiency miss, an advanced test with a detailed flow traverse was performed for the front one and a half stage at the NASA Glenn Research Center. Detailed data-match analysis by GE identified an unexpected high loss generation in the pressure side of the stator passage. Higher total temperature and lower total pressure are measured near the pressure side of the stator. Various analyses based on the RANS and URANS of the compressor stage do not calculate the measured higher total temperature and lower total pressure on the pressure side of the stator. In the present paper, a Large Eddy Simulation (LES) is applied to find the fundamental mechanism of this unsteady loss generation in the stator due to the incoming rotor wake. The results from the LES were first compared with the NASA test results and the GE interpretation of the test data. LES calculates lower total pressure and higher total temperature on the pressure side of the stator, as the measured data showed, resulting in large loss generation on the pressure side of the stator. Detailed examination of the unsteady flow field from LES shows that the rotor wake, which has higher total temperature and higher total pressure relative to the free stream, interacts quite differently with the pressure side of the blade compared to the suction side of the blade. The higher temperature in the wake remains high as the wake passes through the pressure side of the blade. On the other hand, the total temperature diffuses as it passes through near the suction surface. For the presently investigated compressor, the classical intra-stator wake transport to the pressure side of the blade by the slip velocity in the wake seems to be minor. The main causes of this phenomenon are three-dimensional unsteady vortex interactions near the blade surface. The stabilizing effect of the concave curvature on the suction side keeps the rotor wake thin. On the other hand, the destabilizing effect of the convex curvature of the pressure side makes the rotor wake thicker, which results in a higher total temperature measurement at the stator exit. Additionally, wake stretching through the stator seems to contribute to the redistribution of the total temperature and the loss generation.

  8. Internal flow characteristics of a multistage compressor with inlet pressure distortion. [J85-13 turbojet engine studies

    NASA Technical Reports Server (NTRS)

    Debogdan, C. E.; Moss, J. E., Jr.; Braithwaite, W. M.

    1977-01-01

    The measured distribution of compressor interstage pressures and temperatures resulting from a 180 deg inlet-total-pressure distortion for a J85-13 turbojet engine is reported. Extensive inner stage instrumentation combined with stepwise rotation of the inlet distortion gave data of high circumferential resolution. The steady-state pressures and temperatures along with the amplitude, extent, and location of the distorted areas are given. Data for 80, 90, and 100 percent of rotor design speed are compared with clean (undistorted) inlet flow conditions to show pressure and temperature behavior within the compressor. Both overall and stagewise compressor performances vary only slightly when clean and distorted inlet conditions are compared. Total and static pressure distortions increase in amplitude in the first few stages of the compressor and then attenuate fairly uniformly to zero at the discharge. Total-temperature distortion induced by the pressure distortion reached a maximum amplitude by the first two stages and decayed only a little through the rest of the compressor. Distortion amplitude tended to peak in line with the screen edges, and, except for total and static pressure in the tip zone, there was little swirl in the axial direction.

  9. Tables of isentropic expansions of parahydrogen and related transport properties for total temperatures from 25 K to 300 K and for total pressures from 1 ATM to 10 ATM

    NASA Technical Reports Server (NTRS)

    Haut, R. C.; Adcock, J. B.

    1976-01-01

    The isentropic expansions of parahydrogen at various total pressures and total temperatures were numerically determined by iterating Mach number and by using a modified interval halving method. The calculated isentropic values and related properties are presented in tabulated form.

  10. Prandtl-Meyer flow tables for parahydrogen at total temperatures from 30K to 290K and for nitrogen at total temperatures from 100K to 300K at total pressures from 1 ATM to 10 ATM

    NASA Technical Reports Server (NTRS)

    Haut, R. C.; Adcock, J. B.

    1976-01-01

    The dependency of Mach number on the Prandtl-Meyer function was numerically determined by iterating the Prandtl-Meyer function and applying the Muller method to converge on the Mach number for flows in cryogenic parahydrogen and nitrogen at various total pressures and total temperatures. The results are compared with the ideal diatomic gas values and are presented in tabular form.

  11. Effect of ultra high pressure homogenization treatment on the bioactive compounds of soya milk.

    PubMed

    Toro-Funes, N; Bosch-Fusté, J; Veciana-Nogués, M T; Vidal-Carou, M C

    2014-01-01

    Ultra high pressure homogenization (UHPH) is a useful novel technology to obtain safe and high-quality liquid foods. The effect of UHPH at 200 and 300 MPa in combination with different inlet temperatures (Tin) (55, 65 and 75 °C) on the bioactive compounds of soya milk was studied. Total phytosterols increased with the higher combination of pressure and temperature. The main phytosterol was β-sitosterol, followed by stigmasterol and campesterol. Total tocopherols in UHPH-treated soya milks decreased as the temperature and pressure increased. UHPH treatment also affected the different chemical forms of tocopherols. No biogenic amines were detected in any of the analyzed soya milks. Meanwhile, the polyamines SPD and SPM were found in all soya milks, being stable to the UHPH treatment. Total isoflavones increased with the higher combination of pressure and temperature. No differences in the isoflavone profile were found, with β-glucoside conjugates being the predominant form. Copyright © 2013 Elsevier Ltd. All rights reserved.

  12. Steady normal shock wave solution tables of parahydrogen for total temperatures from 30 K to 290 K and for total pressure from 1 ATM to 10 ATM

    NASA Technical Reports Server (NTRS)

    Haut, R. C.; Adcock, J. B.

    1976-01-01

    The steady normal shock wave solutions of parahydrogen at various total pressures and total temperatures were numerically determined by iterating the upstream Mach number and by using a modified interval halving technique. The results obtained are compared with the ideal diatomic gas values and are presented in tabulated form.

  13. The emission characteristics of uranium hexafluoride at high temperatures

    NASA Technical Reports Server (NTRS)

    Krascella, N. L.

    1976-01-01

    Relative emission measurements were made for UF6/Argon mixtures heated in a plasma torch over a range of temperatures from 800 to about 3600 K over a wavelength range from 80 to 600 nm. Total pressures were varied from 1 to approximately 1.7 atm. Similarly absorption measurements were carried out in the visible region from 420 to 580 nm over a temperature range from about 1000 to 1800 K. Total pressure for these measurements was 1.0 atm. The emission results exhibited relatively no emission at wavelengths below 250 nm over the range of temperatures investigated. At temperatures in excess of 1800 K an additional emission band centered at 310 nm appears and becomes more well defined at higher temperatures. Essentially no pressure effect was observed with respect to emission at pressures up to 1.7 atm.

  14. Evaluation of Federal Aviation Administration Engine Exhaust Sampling Rake.

    DTIC Science & Technology

    1977-06-01

    Engine exit total pressure - Pt7 " High turbine discharge temperature - Tt65,6 . Engine exit total temperature - Tt7 - Burner pressure - Ps4 0 Total...illustrated by Figure 22, a plot of Ps4 /Pt7 (expansion thru the turbine) vs. EPR (Pt7/Pt2). This plot indicates that the ECCP rake has no measurable effect on

  15. Total dissolved gas, barometric pressure, and water temperature data, lower Columbia River, Oregon and Washington, 1996

    USGS Publications Warehouse

    Tanner, Dwight Q.; Harrison, Howard E.; McKenzie, Stuart W.

    1996-01-01

    Increased levels of total dissolved gas pressure can cause gas-bubble trauma in fish downstream from dams on the Columbia River. In cooperation with the U.S. Army Corps of Engineers, the U.S. Geological Survey collected data on total dissolved gas pressure, barometric pressure, water temperature, and dissolved oxygen pressure at 11 stations on the lower Columbia River from the John Day forebay (river mile 215.6) to Wauna Mill (river mile 41.9) from March to September 1996. Methods of data collection, review, and processing are described in this report. Summaries of daily minimum, maximum, and mean hourly values are presented for total dissolved gas pressure, barometric pressure, and water temperature. Hourly values for these parameters are presented graphically. Dissolved oxygen data are not presented in this report because the quality-control data show that the data have poor precision and high bias. Suggested changes to monitoring procedures for future studies include (1) improved calibration procedures for total dissolved gas and dissolved oxygen to better define accuracy at elevated levels of supersaturation and (2) equipping dissolved oxygen sensors with stirrers because river velocities at the shoreline monitoring stations probably cannot maintain an adequate flow of water across the membrane surface of the dissolved oxygen sensor.

  16. Pressure and temperature fields associated with aero-optics tests. [transonic wind tunnel tests

    NASA Technical Reports Server (NTRS)

    Raman, K. R.

    1980-01-01

    The experimental investigation carried out in a 6 x 6 ft wind tunnel on four model configurations in the aero-optics series of tests are described. The data obtained on the random pressures (static and total pressures) and total temperatures are presented. In addition, the data for static pressure fluctuations on the Coelostat turret model are presented. The measurements indicate that the random pressures and temperature are negligible compared to their own mean (or steady state) values for the four models considered, thus allowing considerable simplification in the calculations to obtain the statistical properties of the density field. In the case of the Coelostat model tests these simplifications cannot be assumed a priori and require further investigation.

  17. 40 CFR Table 4 to Subpart Ffff of... - Emission Limits for Storage Tanks

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... applies to your storage tanks: For each . . . For which . . . Then you must . . . 1. Group 1 storage tank a. The maximum true vapor pressure of total HAP at the storage temperature is ≥76.6 kilopascals i... maximum true vapor pressure of total HAP at the storage temperature is <76.6 kilopascals i. Comply with...

  18. 40 CFR Table 4 to Subpart Ffff of... - Emission Limits for Storage Tanks

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... applies to your storage tanks: For each . . . For which . . . Then you must . . . 1. Group 1 storage tank a. The maximum true vapor pressure of total HAP at the storage temperature is ≥76.6 kilopascals i... maximum true vapor pressure of total HAP at the storage temperature is <76.6 kilopascals i. Comply with...

  19. Absorption of infrared radiation by carbon monoxide at elevated temperatures and pressures: Part B. Total emissivity charts and correlations

    NASA Astrophysics Data System (ADS)

    Alberti, Michael; Weber, Roman; Mancini, Marco

    2017-10-01

    The line-by-line procedure developed in the associated paper (Part A ) has been used to generate the total emissivity chart for pure CO and CO -N2 /air mixtures at 1 bar total pressure, in the 300 to 3000 K temperature and 0.01 to 3000 bar cm pressure path length range. Methods of scaling the emissivity to pressures different to 1 bar, in the range 0.1 to 40 bar, are provided through pressure correction graphs and EXCEL interpolator (Supplementary Material). The interpolated emissivities are within ± 2% margin from the line-by-line calculated values. The newly developed emissivity graphs are substantially more accurate than the existing Ulrich (1936) & Hottel (1954) and Abu-Romia & Tien (1966) charts.

  20. Calibration of sonic valves for the laminar flow control, leading-edge flight test

    NASA Technical Reports Server (NTRS)

    Petley, D. H.; Alexander, W., Jr.; Wright, A. S., Jr.; Vallas, M.

    1985-01-01

    Sonic needle valves were calibrated to measure and control airflow in the suction system for the leading-edge flight test. The procedure and results for the calibration flow test of 4:41 flight valves are given. Mass-flow rates, which ranged from 0.001 to 0.012 lbm/sec, and maximum back pressure were measured for total temperatures from -30 F to 75 F and total pressures from 120 to 540 psf. Correlating equations are obtained for mass-flow rate as a function of total pressure, total temperature, and valve opening length. The most important aspect of flow measurement and control is found to be the measurement of valve opening length.

  1. Comparative Measurements of Total Temperature in a Supersonic Turbulent Boundary Layer Using a Conical Equilibrium and Combined Temperature-Pressure Probe

    DTIC Science & Technology

    1974-07-01

    AD/A-002 982 COMPARATIVE MEASUREMENTS CF TOTAL TEMPERATURE IN A SUPERSONIC TURBULENT BOUNDARY LAYER USING A CONICAL EQUILIB- RIUM AND COMBINED...SUPERSONIC TURBULENT BOUNDARY LAYER USING A CONICAL EQUILIORIUM AND COMBINED TEMPERATURE-PRESSURE PROBE H.L.P. Vowt R.E. L" 0H.U. M.i July 1974 NAVAL...1 ~~o iotaPRO eig ature In A Supersonic Turbulent Boundary ____________ Layer Using A Conical Equilibrium and 6. 111111ORWING OR. 0111001117,~t

  2. Measurement of recovery temperature on an airfoil in the Langley 0.3-m transonic cryogenic tunnel

    NASA Technical Reports Server (NTRS)

    Johnson, C. B.; Adcock, J. B.

    1981-01-01

    Experimental measurements of recovery temperature were made on an airfoil in the Langley 0.3-m Transonic Cryogenic Tunnel at Mach numbers of 0.60 and 0.84 over a Reynolds number per meter range from about 15,000,000 to about 335,000,000. The measured recovery temperatures were considerably below those associated with ideal-gas ambient temperature wind tunnels. This difference was accentuated as the stagnation pressure increased and the total temperature decreased. A boundary-layer code modified for use with cryogenic nitrogen adequately predicted the measured adiabatic wall temperature at all conditions. A quantitative, on-line assessment of the nonadiabatic condition of a model can be made during the operation of a cryogenic wind tunnel by using a correlation for the adiabatic wall temperature which is only a function of total temperature, total pressure, and local Mach number on the model.

  3. NASA Glenn 1-by 1-Foot Supersonic Wind Tunnel User Manual

    NASA Technical Reports Server (NTRS)

    Seablom, Kirk D.; Soeder, Ronald H.; Stark, David E.; Leone, John F. X.; Henry, Michael W.

    1999-01-01

    This manual describes the NASA Glenn Research Center's 1 - by 1 -Foot Supersonic Wind Tunnel and provides information for customers who wish to conduct experiments in this facility. Tunnel performance envelopes of total pressure, total temperature, and dynamic pressure as a function of test section Mach number are presented. For each Mach number, maps are presented of Reynolds number per foot as a function of the total air temperature at the test section inlet for constant total air pressure at the inlet. General support systems-such as the service air, combustion air, altitude exhaust system, auxiliary bleed system, model hydraulic system, schlieren system, model pressure-sensitive paint, and laser sheet system are discussed. In addition, instrumentation and data processing, acquisition systems are described, pretest meeting formats and schedules are outlined, and customer responsibilities and personnel safety are addressed.

  4. Experimental investigation on pressurization performance of cryogenic tank during high-temperature helium pressurization process

    NASA Astrophysics Data System (ADS)

    Lei, Wang; Yanzhong, Li; Yonghua, Jin; Yuan, Ma

    2015-03-01

    Sufficient knowledge of thermal performance and pressurization behaviors in cryogenic tanks during rocket launching period is of importance to the design and optimization of a pressurization system. In this paper, ground experiments with liquid oxygen (LO2) as the cryogenic propellant, high-temperature helium exceeding 600 K as the pressurant gas, and radial diffuser and anti-cone diffuser respectively at the tank inlet were performed. The pressurant gas requirements, axial and radial temperature distributions, and energy distributions inside the propellant tank were obtained and analyzed to evaluate the comprehensive performance of the pressurization system. It was found that the pressurization system with high-temperature helium as the pressurant gas could work well that the tank pressure was controlled within a specified range and a stable discharging liquid rate was achieved. For the radial diffuser case, the injected gas had a direct impact on the tank inner wall. The severe gas-wall heat transfer resulted in about 59% of the total input energy absorbed by the tank wall. For the pressurization case with anti-cone diffuser, the direct impact of high-temperature gas flowing toward the liquid surface resulted in a greater deal of energy transferred to the liquid propellant, and the percentage even reached up to 38%. Moreover, both of the two cases showed that the proportion of energy left in ullage to the total input energy was quite small, and the percentage was only about 22-24%. This may indicate that a more efficient diffuser should be developed to improve the pressurization effect. Generally, the present experimental results are beneficial to the design and optimization of the pressurization system with high-temperature gas supplying the pressurization effect.

  5. Investigation of Differences Between Measured and Predicted Pressures in AEDC/VKF Hypersonic Tunnel B

    DTIC Science & Technology

    1997-01-01

    coordinates are presented in Fig. 4b. The primary calibration data used in this paper is derived from the rake . The 42 pitot probes cov- ered a range...the lateral (YT) direction. Figures 5 and 6 show examples of the pitot pressure and total temperature rake data from a lateral survey and American...Figure 5. Rake pitot measurements, XT = 16 in. 0 10 YT, in. b. Local Mach number 20 Total Temperature Contours, R Static Temperature Contours, R

  6. Temperature and pressure influence on explosion pressures of closed vessel propane-air deflagrations.

    PubMed

    Razus, Domnina; Brinzea, Venera; Mitu, Maria; Oancea, Dumitru

    2010-02-15

    An experimental study on pressure evolution during closed vessel explosions of propane-air mixtures was performed, for systems with various initial concentrations and pressures ([C(3)H(8)]=2.50-6.20 vol.%, p(0)=0.3-1.2 bar). The explosion pressures and explosion times were measured in a spherical vessel (Phi=10 cm), at various initial temperatures (T(0)=298-423 K) and in a cylindrical vessel (Phi=10 cm; h=15 cm), at ambient initial temperature. The experimental values of explosion pressures are examined against literature values and compared to adiabatic explosion pressures, computed by assuming chemical equilibrium within the flame front. The influence of initial pressure, initial temperature and fuel concentration on explosion pressures and explosion times are discussed. At constant temperature and fuel/oxygen ratio, the explosion pressures are linear functions of total initial pressure, as reported for other fuel-air mixtures. At constant initial pressure and composition, both the measured and calculated (adiabatic) explosion pressures are linear functions of reciprocal value of initial temperature. Such correlations are extremely useful for predicting the explosion pressures of flammable mixtures at elevated temperatures and/or pressures, when direct measurements are not available.

  7. 40 CFR Table 4 to Subpart Ooo of... - Operating Parameter Levels

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... temperature Maximum temperature Carbon absorber Total regeneration steam or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15 minutes of completing any cooling cycle(s)) Maximum flow or pressure; and maximum...

  8. High-sensitivity cryogenic temperature sensors using pressurized fiber Bragg gratings

    NASA Technical Reports Server (NTRS)

    Wu, Meng-Chou; DeHaven, Stanton L.

    2006-01-01

    Cryogenic temperature sensing was studied using a pressurized fiber Bragg grating (PFBG). The PFBG was obtained by simply applying a small diametric load to a regular fiber Bragg grating (FBG), which was coated with polyimide of a thickness of 11 micrometers. The Bragg wavelength of the PFBG was measured at temperatures from 295 to 4.2 K. A pressure-induced transition occurred at 200 K during the cooling cycle. As a result the temperature sensitivity of the PFBG was found to be nonlinear but reach 24 pm/K below 200 K, more than three times the regular FBG. For the temperature change from 80 K to 10 K, the PFBG has a total Bragg wavelength shift of about 470 pm, 10 times more than the regular FBG. From room temperature to liquid helium temperature the PFBG gives a total wavelength shift of 3.78 nm, compared to the FBG of 1.51 nm. The effect of the coating thickness on the temperature sensitivity of the gratings is also discussed.

  9. High-sensitivity Cryogenic Temperature Sensors using Pressurized Fiber Bragg Gratings

    NASA Technical Reports Server (NTRS)

    Wu, Meng-Chou; DeHaven, Stanton L.

    2006-01-01

    Cryogenic temperature sensing was studied using a pressurized fiber Bragg grating (PFBG). The PFBG was obtained by simply applying a small diametric load to a regular fiber Bragg grating (FBG), which was coated with polyimide of a thickness of 11 micrometers. The Bragg wavelength of the PFBG was measured at temperatures from 295 to 4.2 K. A pressure-induced transition occurred at 200 K during the cooling cycle. As a result the temperature sensitivity of the PFBG was found to be nonlinear but reach 24 pm/K below 200 K, more than three times the regular FBG. For the temperature change from 80 K to 10 K, the PFBG has a total Bragg wavelength shift of about 470 pm, 10 times more than the regular FBG. From room temperature to liquid helium temperature the PFBG gives a total wavelength shift of 3.78 nm, compared to the FBG of 1.51 nm. The effect of the coating thickness on the temperature sensitivity of the gratings is also discussed.

  10. Optimisation of phenolics recovery from Vitex agnus-castus Linn. leaves by high-pressure and temperature extraction.

    PubMed

    Lataoui, Mohammed; Seffen, Mongi; Aliakbarian, Bahar; Casazza, Alessandro Alberto; Converti, Attilio; Perego, Patrizia

    2014-01-01

    To optimise recovery of phenolics from Vitex agnus-castus Linn., a non-conventional high-pressure (2-24 bar) and temperature (100-180°C) extraction method was used under nitrogen atmosphere with methanol as a solvent. Optimal temperature was between 100 and 140°C, and optimal extraction time was about one half that of conventional solid/liquid extraction at room temperature. Final yields of total polyphenols, total flavonoids, o-diphenols and anthocyanins extraction were 2.0, 3.0, 2.5 and 11-fold those obtained by conventional extraction.

  11. Heat transfer and pressure measurements for the SSME fuel turbine

    NASA Technical Reports Server (NTRS)

    Dunn, Michael G.; Kim, Jungho

    1991-01-01

    A measurement program is underway using the Rocketdyne two-stage Space Shuttle Main Engine (SSME) fuel turbine. The measurements use a very large shock tunnel to produce a short-duration source of heated and pressurized gas which is subsequently passed through the turbine. Within this environment, the turbine is operated at the design values of flow function, stage pressure ratio, stage temperature ratio, and corrected speed. The first stage vane row and the first stage blade row are instrumented in both the spanwise and chordwise directions with pressure transducers and heat flux gages. The specific measurements to be taken include time averaged surface pressure and heat flux distributions on the vane and blade, flow passage static pressure, flow passage total pressure and total temperature distributions, and phase resolved surface pressure and heat flux on the blade.

  12. Exhaust-Gas Pressure and Temperature Survey of F404-GE-400 Turbofan Engine

    NASA Technical Reports Server (NTRS)

    Walton, James T.; Burcham, Frank W., Jr.

    1986-01-01

    An exhaust-gas pressure and temperature survey of the General Electric F404-GE-400 turbofan engine was conducted in the altitude test facility of the NASA Lewis Propulsion System Laboratory. Traversals by a survey rake were made across the exhaust-nozzle exit to measure the pitot pressure and total temperature. Tests were performed at Mach 0.87 and a 24,000-ft altitude and at Mach 0.30 and a 30,000-ft altitude with various power settings from intermediate to maximum afterburning. Data yielded smooth pressure and temperature profiles with maximum jet temperatures approximately 1.4 in. inside the nozzle edge and maximum jet temperatures from 1 to 3 in. inside the edge. A low-pressure region located exactly at engine center was noted. The maximum temperature encountered was 3800 R.

  13. Pitot-Pressure Measurements in Flow Fields Behind a Rectangular Nozzle with Exhaust Jet for Free-Stream Mach Numbers of 0.00, 0.60, and 1.20

    NASA Technical Reports Server (NTRS)

    Putnam, L. E.; Mercer, C. E.

    1986-01-01

    An investigation has been conducted in the Langley 16-Foot Transonic Tunnel to measure the flow field in and around the jet exhaust from a nonaxisymmetric nozzle configuration. The nozzle had a rectangular exit with a width-to-height ratio of 2.38. Pitot-pressure measurements were made at five longitudinal locations downstream of the nozzle exit. The maximum distance downstream of the exit was about 5 nozzle heights. These measurements were made at free-stream Mach numbers of 0.00, 0.60, and 1.20 with the nozzle operating at a ratio of nozzle total pressure to free-stream static pressure of 4.0. The jet exhaust was simulated with high-pressure air that had an exit total temperature essentially equal to the free-stream total temperature.

  14. Relation of Total and Cardiovascular Death Rates to Climate System, Temperature, Barometric Pressure, and Respiratory Infection.

    PubMed

    Schwartz, Bryan G; Qualls, Clifford; Kloner, Robert A; Laskey, Warren K

    2015-10-15

    A distinct seasonal pattern in total and cardiovascular death rates has been reported. The factors contributing to this pattern have not been fully explored. Seven locations (average total population 71,354,000) were selected where data were available including relatively warm, cold, and moderate temperatures. Over the period 2004 to 2009, there were 2,526,123 all-cause deaths, 838,264 circulatory deaths, 255,273 coronary heart disease deaths, and 135,801 ST-elevation myocardial infarction (STEMI) deaths. We used time series and multivariate regression modeling to explore the association between death rates and climatic factors (temperature, dew point, precipitation, barometric pressure), influenza levels, air pollution levels, hours of daylight, and day of week. Average seasonal patterns for all-cause and cardiovascular deaths were very similar across the 7 locations despite differences in climate. After adjusting for multiple covariates and potential confounders, there was a 0.49% increase in all-cause death rate for every 1°C decrease. In general, all-cause, circulatory, coronary heart disease and STEMI death rates increased linearly with decreasing temperatures. The temperature effect varied by location, including temperature's linear slope, cubic fit, positional shift on the temperature axis, and the presence of circulatory death increases in locally hot temperatures. The variable effect of temperature by location suggests that people acclimatize to local temperature cycles. All-cause and circulatory death rates also demonstrated sizable associations with influenza levels, dew point temperature, and barometric pressure. A greater understanding of how climate, temperature, and barometric pressure influence cardiovascular responses would enhance our understanding of circulatory and STEMI deaths. Copyright © 2015 Elsevier Inc. All rights reserved.

  15. Study of VTOL in ground-effect flow field including temperature effect

    NASA Technical Reports Server (NTRS)

    Hill, W. G.; Jenkins, R. C.; Kalemaris, S. G.; Siclari, M. J.

    1982-01-01

    Detailed pressure, temperature, and velocity data were obtained for twin-fan configurations in-ground-effect and flow models to aid in predicting pressures and upwash forces on aircraft surfaces were developed. For the basic experiments, 49.5 mm-diameter jets were used, oriented normal to a simulated round plane, with pressurized, heated air providing a jet. The experimental data consisted of: (1) the effect of jet height and temperature on the ground, model, and upwash pressures, and temperatures, (2) the effect of simulated aircraft surfaces on the isolated flow field, (3) the jet-induced forces on a three-dimensional body with various strakes, (4) the effects of non-uniform coannular jets. For the uniform circular jets, temperature was varied from room temperature (24 C) to 232 C. Jet total pressure was varied between 9,300 Pascals and 31,500 Pascals. For the coannular jets, intended to represent turbofan engines, fan temperature was maintained at room temperature while core temperature was varied from room temperature to 437 C. Results are presented.

  16. Hyperbaric storage of melon juice at and above room temperature and comparison with storage at atmospheric pressure and refrigeration.

    PubMed

    Queirós, Rui P; Santos, Mauro D; Fidalgo, Liliana G; Mota, Maria J; Lopes, Rita P; Inácio, Rita S; Delgadillo, Ivonne; Saraiva, Jorge A

    2014-03-15

    Hyperbaric storage (8h) of melon juice (a highly perishable food) at 25, 30 and 37°C, under pressure at 25-150 MPa was compared with atmospheric pressure storage (0.1 MPa) at the same temperatures and under refrigeration (4°C). Comparatively to the refrigerated condition, hyperbaric storage at 50/75 MPa resulted in similar or lower microbial counts (total aerobic mesophiles, enterobacteriaceae, and yeasts/moulds) while at 100/150 MPa, the counts were lower for all the tested temperatures, indicating in the latter case, in addition to microbial growth inhibition, a microbial inactivation effect. At 25 MPa no microbial inhibition was observed. Physicochemical parameters of all samples stored under pressure (pH, titratable acidity, total soluble solids, browning degree and cloudiness) did not show a clear variation trend with pressure, being the results globally similar to refrigeration storage. These results show the potential of hyperbaric storage, at and above room temperature and with potential energy savings, comparatively to refrigeration. Copyright © 2013 Elsevier Ltd. All rights reserved.

  17. The carrier gas pressure effect in a laminar flow diffusion chamber, homogeneous nucleation of n-butanol in helium.

    PubMed

    Hyvärinen, Antti-Pekka; Brus, David; Zdímal, Vladimír; Smolík, Jiri; Kulmala, Markku; Viisanen, Yrjö; Lihavainen, Heikki

    2006-06-14

    Homogeneous nucleation rate isotherms of n-butanol+helium were measured in a laminar flow diffusion chamber at total pressures ranging from 50 to 210 kPa to investigate the effect of carrier gas pressure on nucleation. Nucleation temperatures ranged from 265 to 280 K and the measured nucleation rates were between 10(2) and 10(6) cm(-3) s(-1). The measured nucleation rates decreased as a function of increasing pressure. The pressure effect was strongest at pressures below 100 kPa. This negative carrier gas effect was also temperature dependent. At nucleation temperature of 280 K and at the same saturation ratio, the maximum deviation between nucleation rates measured at 50 and 210 kPa was about three orders of magnitude. At nucleation temperature of 265 K, the effect was negligible. Qualitatively the results resemble those measured in a thermal diffusion cloud chamber. Also the slopes of the isothermal nucleation rates as a function of saturation ratio were different as a function of total pressure, 50 kPa isotherms yielded the steepest slopes, and 210 kPa isotherms the shallowest slopes. Several sources of inaccuracies were considered in the interpretation of the results: uncertainties in the transport properties, nonideal behavior of the vapor-carrier gas mixture, and shortcomings of the used mathematical model. Operation characteristics of the laminar flow diffusion chamber at both under-and over-pressure were determined to verify a correct and stable operation of the device. We conclude that a negative carrier gas pressure effect is seen in the laminar flow diffusion chamber and it cannot be totally explained with the aforementioned reasons.

  18. Determination of total carbonates in soil archaeometry using a new pressure method with temperature compensation

    NASA Astrophysics Data System (ADS)

    Barouchas, Pantelis; Koulos, Vasilios; Melfos, Vasilios

    2017-04-01

    For the determination of total carbonates in soil archaeometry a new technique was applied using a multi-sensor philosophy, which combines simultaneous measurement of pressure and temperature. This technology is innovative and complies with EN ISO 10693:2013, ASTM D4373-02(2007) and Soil Science Society of America standard test methods for calcium carbonate content in soils and sediments. The total carbonates analysis is based on a pressure method that utilizes the FOGII Digital Soil CalcimeterTM, which is a portable apparatus. The total carbonate content determined by treating a 1.000 g (+/- 0.001 g) dried sample specimens with 6N hydrochloric acid (HCL) reagent grade, in an enclosed reaction vessel. Carbon dioxide gas evolved during the reaction between the acid and carbonate fraction of the specimen, was measured by the resulting pressure generated, taking in account the temperature conditions during the reaction. Prior to analysis the procedure was validated with Sand/Soil mixtures from BIPEA proficiency testing program with soils of different origins. For applying this new method in archaeometry a total number of ten samples were used from various rocks which are related with cultural constructions and implements in Greece. They represent a large range of periods since the Neolithic times, and were selected because there was an uncertainty about their accurate mineralogical composition especially regarding the presence of carbonate minerals. The results were compared to the results from ELTRA CS580 inorganic carbon analyzer using an infrared cell. The determination of total carbonates for 10 samples from different ancient sites indicated a very good correlation (R2 >0.97) between the pressure method with temperature compensation and the infrared method. The proposed method is quickly and accurate in archaeometry and can replace easily other techniques for total carbonates testing. The FOGII Digital Soil CalcimeterTM is portable and easily can be carried for field work in archaeology.

  19. An analysis of the viscous flow through a compact radial turbine by the average passage approach

    NASA Technical Reports Server (NTRS)

    Heidmann, James D.; Beach, Timothy A.

    1990-01-01

    A steady, three-dimensional viscous average passage computer code is used to analyze the flow through a compact radial turbine rotor. The code models the flow as spatially periodic from blade passage to blade passage. Results from the code using varying computational models are compared with each other and with experimental data. These results include blade surface velocities and pressures, exit vorticity and entropy contour plots, shroud pressures, and spanwise exit total temperature, total pressure, and swirl distributions. The three computational models used are inviscid, viscous with no blade clearance, and viscous with blade clearance. It is found that modeling viscous effects improves correlation with experimental data, while modeling hub and tip clearances further improves some comparisons. Experimental results such as a local maximum of exit swirl, reduced exit total pressures at the walls, and exit total temperature magnitudes are explained by interpretation of the flow physics and computed secondary flows. Trends in the computed blade loading diagrams are similarly explained.

  20. Evaluation of the Environmental Bias on Accelerometer-Measured Total Daily Activity Counts and Owner Survey Responses in Dogs with Osteoarthritis.

    PubMed

    Katz, Erin M; Scott, Ruth M; Thomson, Christopher B; Mesa, Eileen; Evans, Richard; Conzemius, Michael G

    2017-11-01

    Objective  To determine if environmental variables affect the average daily activity counts (AC) of dogs with osteoarthritis (OA) and/or owners' perception of their dog's clinical signs or quality of life. Methods  The AC and Canine Brief Pain Inventory (CBPI) owner questionnaires of 62 dogs with OA were compared with daily environmental variables including the following: average temperature (°C), high temperature (°C), low temperature (°C), relative humidity (%), total precipitation (mm), average barometric pressure (hPa) and total daylight hours. Results  Daily AC significantly correlated with average temperature and total daylight hours, but average temperature and total daylight hours accounted for less than 1% of variation in AC. No other significant relationships were found between daily AC and daily high temperature, low temperature, relative humidity, total precipitation or average barometric pressure. No statistical relationship was found between daily AC and the CBPI, nor between environmental variables and the CBPI. Canine Brief Pain Inventory scores for pain severity and pain interference decreased significantly over the test period. Clinical Significance  The relationship between daily AC and average temperature and total daylight hours was significant, but unlikely to be clinically significant. Thus, environmental variables do not appear to have a clinically relevant bias on AC or owner CBPI questionnaires. The decrease over time in CBPI pain severity and pain interference values suggests owners completing the CBPI in this study were influenced by a caregiver placebo effect. Schattauer GmbH Stuttgart.

  1. Temperature and pressure influence on maximum rates of pressure rise during explosions of propane-air mixtures in a spherical vessel.

    PubMed

    Razus, D; Brinzea, V; Mitu, M; Movileanu, C; Oancea, D

    2011-06-15

    The maximum rates of pressure rise during closed vessel explosions of propane-air mixtures are reported, for systems with various initial concentrations, pressures and temperatures ([C(3)H(8)]=2.50-6.20 vol.%, p(0)=0.3-1.3 bar; T(0)=298-423 K). Experiments were performed in a spherical vessel (Φ=10 cm) with central ignition. The deflagration (severity) index K(G), calculated from experimental values of maximum rates of pressure rise is examined against the adiabatic deflagration index, K(G, ad), computed from normal burning velocities and peak explosion pressures. At constant temperature and fuel/oxygen ratio, both the maximum rates of pressure rise and the deflagration indices are linear functions of total initial pressure, as reported for other fuel-air mixtures. At constant initial pressure and composition, the maximum rates of pressure rise and deflagration indices are slightly influenced by the initial temperature; some influence of the initial temperature on maximum rates of pressure rise is observed only for propane-air mixtures far from stoichiometric composition. The differentiated temperature influence on the normal burning velocities and the peak explosion pressures might explain this behaviour. Copyright © 2011 Elsevier B.V. All rights reserved.

  2. Heat-Transfer Characteristics of Partially Film Cooled Plug Nozzle on a J-85 Afterburning Turbojet Engine

    NASA Technical Reports Server (NTRS)

    Nosek, S. M.; Straight, D. M.

    1976-01-01

    Plug nozzle film cooling data were obtained downstream of a slot located at 42 percent of the total plug length on a J-85 engine. Film cooling reduced the aft end wall temperature as much as 150 K, reduced total pressure loss in the upstream convection cooling passages by 50 percent, and reduced estimated compressor bleed flow requirement by 14 percent compared to an all convectively cooled nozzle. Shock waves along the plug surface strongly influenced temperature distributions on both convection and film cooled portions. The effect was most severe at nozzle pressure ratios below 10 where adverse pressure gradients were most severe.

  3. Blade row dynamic digital compressor program. Volume 1: J85 clean inlet flow and parallel compressor models

    NASA Technical Reports Server (NTRS)

    Tesch, W. A.; Steenken, W. G.

    1976-01-01

    The results are presented of a one-dimensional dynamic digital blade row compressor model study of a J85-13 engine operating with uniform and with circumferentially distorted inlet flow. Details of the geometry and the derived blade row characteristics used to simulate the clean inlet performance are given. A stability criterion based upon the self developing unsteady internal flows near surge provided an accurate determination of the clean inlet surge line. The basic model was modified to include an arbitrary extent multi-sector parallel compressor configuration for investigating 180 deg 1/rev total pressure, total temperature, and combined total pressure and total temperature distortions. The combined distortions included opposed, coincident, and 90 deg overlapped patterns. The predicted losses in surge pressure ratio matched the measured data trends at all speeds and gave accurate predictions at high corrected speeds where the slope of the speed lines approached the vertical.

  4. Static and Wind Tunnel Aero-Performance Tests of NASA AST Separate Flow Nozzle Noise Reduction Configurations

    NASA Technical Reports Server (NTRS)

    Mikkelsen, Kevin L.; McDonald, Timothy J.; Saiyed, Naseem (Technical Monitor)

    2001-01-01

    This report presents the results of cold flow model tests to determine the static and wind tunnel performance of several NASA AST separate flow nozzle noise reduction configurations. The tests were conducted by Aero Systems Engineering, Inc., for NASA Glenn Research Center. The tests were performed in the Channels 14 and 6 static thrust stands and the Channel 10 transonic wind tunnel at the FluiDyne Aerodynamics Laboratory in Plymouth, Minnesota. Facility checkout tests were made using standard ASME long-radius metering nozzles. These tests demonstrated facility data accuracy at flow conditions similar to the model tests. Channel 14 static tests reported here consisted of 21 ASME nozzle facility checkout tests and 57 static model performance tests (including 22 at no charge). Fan nozzle pressure ratio varied from 1.4 to 2.0, and fan to core total pressure ratio varied from 1.0 to 1.19. Core to fan total temperature ratio was 1.0. Channel 10 wind tunnel tests consisted of 15 tests at Mach number 0.28 and 31 tests at Mach 0.8. The sting was checked out statically in Channel 6 before the wind tunnel tests. In the Channel 6 facility, 12 ASME nozzle data points were taken and 7 model data points were taken. In the wind tunnel, fan nozzle pressure ratio varied from 1.73 to 2.8, and fan to core total pressure ratio varied from 1.0 to 1.19. Core to fan total temperature ratio was 1.0. Test results include thrust coefficients, thrust vector angle, core and fan nozzle discharge coefficients, total pressure and temperature charging station profiles, and boat-tail static pressure distributions in the wind tunnel.

  5. Effect of Substrate and Process Parameters on the Gas-Substrate Convective Heat Transfer Coefficient During Cold Spraying

    NASA Astrophysics Data System (ADS)

    Mahdavi, Amirhossein; McDonald, André

    2018-02-01

    The final quality of cold-sprayed coatings can be significantly influenced by gas-substrate heat exchange, due to the dependence of the deposition efficiency of the particles on the substrate temperature distribution. In this study, the effect of the air temperature and pressure, as process parameters, and surface roughness and thickness, as substrate parameters, on the convective heat transfer coefficient of the impinging air jet was investigated. A low-pressure cold spraying unit was used to generate a compressed air jet that impinged on a flat substrate. A comprehensive mathematical model was developed and coupled with experimental data to estimate the heat transfer coefficient and the surface temperature of the substrate. The effect of the air total temperature and pressure on the heat transfer coefficient was studied. It was found that increasing the total pressure would increase the Nusselt number of the impinging air jet, while total temperature of the air jet had negligible effect on the Nusslet number. It was further found that increasing the roughness of the substrate enhanced the heat exchange between the impinging air jet and the substrate. As a result, higher surface temperatures on the rough substrate were measured. The study of the effect of the substrate thickness on the heat transfer coefficient showed that the Nusselt number that was predicted by the model was independent of the thickness of the substrate. The surface temperature profile, however, decreased in increasing radial distances from the stagnation point of the impinging jet as the thickness of the substrate increased. The results of the current study were aimed to inform on the influence and effect of substrate and process parameters on the gas-substrate heat exchange and the surface temperature of the substrate on the final quality of cold-sprayed coatings.

  6. Alumina Volatility in Water Vapor at Elevated Temperatures: Application to Combustion Environments

    NASA Technical Reports Server (NTRS)

    Opila, Elizabeth J.; Myers, Dwight L.

    2003-01-01

    The volatility of alumina in high temperature water vapor was determined by measuring weight loss of sapphire coupons at temperatures between 1250 and 1500 C, water vapor partial pressures between 0.15 and 0.68 atm in oxygen, at one atmosphere total pressure, and a gas velocity of 4.4 centimeters per second. The variation of the volatility with water vapor partial pressure was consistent with Al(OH)3(g) formation. The enthalpy of reaction to form Al(OH)3(g) from alumina and water vapor was found to be 210 plus or minus 20 kJ/mol. Surface rearrangement of ground sapphire surfaces increased with water vapor partial pressure, temperature and volatility rate. Recession rates of alumina due to volatility were determined as a function of water vapor partial pressure and temperature to evaluate limits for use of alumina in long term applications in combustion environments.

  7. Elastic Properties across the y→α Volume Collapse in Cerium versus Pressure and Temperature

    DOE PAGES

    Lipp, M. J.; Jenei, Zs.; Cynn, H.; ...

    2017-10-31

    Here, the longitudinal and transverse sound speeds, c L and c T, of polycrystalline cerium were measured isothermally vs pressure up to the critical temperature across the iso-structural γ-α volume collapse (VC) phase transition. We deduce values for the adiabatic bulk modulus BS, the shear modulus G = ρc T 2, the Poisson’s ratio ν and the Debye temperature, θ D(p). We find that the elastic constant C 12 is solely responsible for the decrease of B S with pressure towards the VC at RT. With increasing temperature, the lattice contribution ΔS vib(γ→α) to the total entropy change across themore » VC decreases more rapidly to zero than the total entropy itself suggesting that another mechanism, possibly disorder, assists in stabilizing the γ-phase entropically against the α-phase. Also, with increasing temperature, the Poisson’s ratio becomes negative near the VC transition, meaning that cerium metal takes on auxetic characteristics over a small pressure range. At the critical point the Poisson’s ratio ought to be -1, since the isothermal bulk modulus vanishes and the shear modulus remains nonzero.« less

  8. Elastic Properties across the y→α Volume Collapse in Cerium versus Pressure and Temperature

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lipp, M. J.; Jenei, Zs.; Cynn, H.

    Here, the longitudinal and transverse sound speeds, c L and c T, of polycrystalline cerium were measured isothermally vs pressure up to the critical temperature across the iso-structural γ-α volume collapse (VC) phase transition. We deduce values for the adiabatic bulk modulus BS, the shear modulus G = ρc T 2, the Poisson’s ratio ν and the Debye temperature, θ D(p). We find that the elastic constant C 12 is solely responsible for the decrease of B S with pressure towards the VC at RT. With increasing temperature, the lattice contribution ΔS vib(γ→α) to the total entropy change across themore » VC decreases more rapidly to zero than the total entropy itself suggesting that another mechanism, possibly disorder, assists in stabilizing the γ-phase entropically against the α-phase. Also, with increasing temperature, the Poisson’s ratio becomes negative near the VC transition, meaning that cerium metal takes on auxetic characteristics over a small pressure range. At the critical point the Poisson’s ratio ought to be -1, since the isothermal bulk modulus vanishes and the shear modulus remains nonzero.« less

  9. Dynamic void behavior in polymerizing polymethyl methacrylate cement.

    PubMed

    Muller, Scott D; McCaskie, Andrew W

    2006-02-01

    Cement mantle voids remain controversial with respect to survival of total hip arthroplasty. Void evolution is poorly understood, and attempts at void manipulation can only be empirical. We induced voids in a cement model simulating the constraints of the proximal femur. Intravoid pressure and temperature were recorded throughout polymerization, and the initial and final void volumes were measured. Temperature-dependent peak intravoid pressures and void volume increases were observed. After solidification, subatmospheric intravoid pressures were observed. The magnitude of these observations could not be explained by the ideal gas law. Partial pressures of the void gas at peak pressures demonstrated a dominant effect of gaseous monomer, thereby suggesting that void growth is a pressure-driven phenomenon resulting from temperature-dependent evaporation of monomer into existing trapped air voids.

  10. 40 CFR Table 3 to Subpart Ooo of... - Batch Process Vent Monitoring Requirements

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) temperature Continuous records as specified in § 63.1416(d). a Carbon adsorber a Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle...

  11. 40 CFR Table 3 to Subpart Ooo of... - Batch Process Vent Monitoring Requirements

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) temperature Continuous records as specified in § 63.1416(d). a Carbon adsorber a Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle...

  12. Effects of living at two ambient temperatures on 24-h blood pressure and neuroendocrine function among obese and non-obese humans: a pilot study

    NASA Astrophysics Data System (ADS)

    Kanikowska, Dominika; Sato, Maki; Iwase, Satoshi; Shimizu, Yuuki; Nishimura, Naoki; Inukai, Yoko; Sugenoya, Junichi

    2013-05-01

    The effects of environmental temperature on blood pressure and hormones in obese subjects in Japan were compared in two seasons: summer vs winter. Five obese (BMI, 32 ± 5 kg/m2) and five non-obese (BMI, 23 ±3 kg/m2) men participated in this experiment at latitude 35°10' N and longitude 136°57.9' E. The average environmental temperature was 29 ± 1 °C in summer and 3 ± 1 °C in winter. Blood samples were analyzed for leptin, ghrelin, catecholamines, thyroid stimulating hormone (TSH), free thyroxine (fT4), free triiodothyronine (fT3), total cholesterol, triglycerides, insulin and glucose. Blood pressure was measured over the course of 24 h in summer and winter. A Japanese version of the Profile of Mood States (POMS) questionnaire was also administered each season. Systolic and diastolic blood pressures in obese men were significantly higher in winter (lower environmental temperatures) than in summer (higher environmental temperatures). Noradrenaline and dopamine concentrations were also significantly higher at lower environmental temperatures in obese subjects, but ghrelin, TSH, fT3, fT4, insulin and glucose were not significantly different in summer and winter between obese and non-obese subjects. Leptin, total cholesterol and triglyceride concentrations were significantly higher in winter in obese than non-obese men. Results from the POMS questionnaire showed a significant rise in Confusion at lower environmental temperatures (winter) in obese subjects. In this pilot study, increased blood pressure may have been due to increased secretion of noradrenaline in obese men in winter, and the results suggest that blood pressure control in obese men is particularly important in winter.

  13. Vapor Pressure Measurements in a Closed System

    ERIC Educational Resources Information Center

    Iannone, Mark

    2006-01-01

    An alternative method that uses a simple apparatus to measure vapor pressure versus temperature in a closed system, in which the total pressure is the vapor pressure of the liquid sample, is described. The use of this apparatus gives students a more direct picture of vapor pressure than the isoteniscope method and results have generally been quite…

  14. Correlation between the season, temperature and atmospheric pressure with incidence and pathogenesis of acute appendicitis.

    PubMed

    Karanikolić, Aleksandar; Karanikolić, Vesna; Djordjević, Lidija; Pešić, Ivan

    2016-01-01

    There is very little literature data on the correlation between the seasons, temperature and atmospheric pressure, and pathogenesis of acute appendicitis (AA). The aim of this research is to investigate the association between the seasons, changes in atmospheric temperature and pressure, and patients’ age and severity of the clinical form of AA in the city of Niš This study included 395 patients diagnosed with AA, who, during the two-year period, from July 1st 2011 to June 30th 2013, were hospitalized and operated on at the Department of General Surgery, Clinical Center in Niš, Serbia. The increased average daily values of barometric pressure by 1 millibar on the day when the event took place was associated (p < 0.05) with the decrease of total risk of the occurrence of appendicitis by 2.2% (0.2–4.1%). In all observed patients, each increase of the mean daily temperature by 1°C three days before the event took place (Lag 3) was associated (p < 0.05) with the increase of total risk of the occurrence of appendicitis by 1.3% (0.1–2.5%). According to the results of this research, we can conclude that patients’ sex, age and severity of the clinical form of AA are not in connection with the seasons, while there are certain connections between appendicitis occurrence and atmospheric temperature and pressure.

  15. Simulation of ideal-gas flow by nitrogen and other selected gases at cryogenic temperatures. [transonic flow in cryogenic wind tunnels

    NASA Technical Reports Server (NTRS)

    Hall, R. M.; Adcock, J. B.

    1981-01-01

    The real gas behavior of nitrogen, the gas normally used in transonic cryogenic tunnels, is reported for the following flow processes: isentropic expansion, normal shocks, boundary layers, and interactions between shock waves and boundary layers. The only difference in predicted pressure ratio between nitrogen and an ideal gas which may limit the minimum operating temperature of transonic cryogenic wind tunnels occur at total pressures approaching 9 atm and total temperatures 10 K below the corresponding saturation temperature. These pressure differences approach 1 percent for both isentropic expansions and normal shocks. Alternative cryogenic test gases were also analyzed. Differences between air and an ideal diatomic gas are similar in magnitude to those for nitrogen and should present no difficulty. However, differences for helium and hydrogen are over an order of magnitude greater than those for nitrogen or air. It is concluded that helium and cryogenic hydrogen would not approximate the compressible flow of an ideal diatomic gas.

  16. Boiling regimes of impacting drops on a heated substrate under reduced pressure

    NASA Astrophysics Data System (ADS)

    van Limbeek, Michiel A. J.; Hoefnagels, Paul B. J.; Shirota, Minori; Sun, Chao; Lohse, Detlef

    2018-05-01

    We experimentally investigate the boiling behavior of impacting ethanol drops on a heated smooth sapphire substrate at pressures ranging from P =0.13 bar to atmospheric pressure. We employ frustrated total internal reflection imaging to study the wetting dynamics of the contact between the drop and the substrate. The spreading drop can be in full contact (contact boiling), it can partially touch (transition boiling), or the drop can be fully levitated (Leidenfrost boiling). We show that the temperature of the boundary between contact and transition boiling shows at most a weak dependence on the impact velocity, but a significant decrease with decreasing ambient gas pressure. A striking correspondence is found between the temperature of this boundary and the static Leidenfrost temperature for all pressures. We therefore conclude that both phenomena share the same mechanism and are dominated by the dynamics taking place at the contact line. On the other hand, the boundary between transition boiling and Leidenfrost boiling, i.e., the dynamic Leidenfrost temperature, increases for increasing impact velocity for all ambient gas pressures. Moreover, the dynamic Leidenfrost temperature coincides for pressures between P =0.13 and 0.54 bar, whereas for atmospheric pressure the dynamic Leidenfrost temperature is slightly elevated. This indicates that the dynamic Leidenfrost temperature is at most weakly dependent on the enhanced evaporation by the lower saturation temperature of the liquid.

  17. Stability of echogenic liposomes as a blood pool ultrasound contrast agent in a physiologic flow phantom

    PubMed Central

    Radhakrishnan, Kirthi; Haworth, Kevin J.; Huang, Shao-Ling; Klegerman, Melvin E.; McPherson, David D.; Holland, Christy K.

    2016-01-01

    Echogenic liposomes (ELIP) are multifunctional ultrasound contrast agents (UCAs) with a lipid shell encapsulating both air and an aqueous core. ELIP are being developed for molecular imaging and image-guided therapeutic delivery. Stability of the echogenicity of ELIP in physiologic conditions is crucial to their successful translation to clinical use. In this study we determined the effects of the surrounding media’s dissolved air concentration, temperature transition and hydrodynamic pressure on the echogenicity of a chemically modified formulation of ELIP to promote stability and echogenicity. ELIP samples were diluted in porcine plasma or whole blood and pumped through a pulsatile flow system with adjustable hydrodynamic pressures and temperature. B-mode images were acquired using a clinical diagnostic scanner every 5 s for a total duration of 75 s. Echogenicity in porcine plasma was assessed as a function of total dissolved gas saturation. ELIP were added to plasma at room temperature (22 °C) or body temperature (37 °C) and pumped through a system maintained at 22 °C or 37 °C to study the effect of temperature transitions on ELIP echogenicity. Echogenicity at normotensive (120/80 mmHg) and hypertensive pressures (145/90 mmHg) was measured. ELIP were echogenic in plasma and whole blood at body temperature under normotensive to hypertensive pressures. Warming of samples from room temperature to body temperature did not alter echogenicity. However, in plasma cooled rapidly from body temperature to room temperature or in degassed plasma, ELIP lost echogenicity within 20 s at 120/80 mmHg. The stability of echogenicity of a modified ELIP formulation was determined in vitro at body temperature, physiologic gas concentration and throughout the physiologic pressure range. However, proper care should be taken to ensure that ELIP are not cooled rapidly from body temperature to room temperature as they will lose their acoustic properties. Further in vivo investigations will be needed to evaluate the optimal usage of ELIP as blood pool contrast agents. PMID:22929652

  18. Water Ingestion into Axial Flow Compressors. Part III. Experimental Results and Discussion

    DTIC Science & Technology

    1981-10-01

    total pressure, static pressure, and temperature at both compressor inlet and outlet. A United Sensor model PDC-12-G-l0-KL pitot-static pressure probe...Test Compressor inlet and outlet temperatures during water injection tests: United Sensor and Control Corp. type TK-8-CiA-36’-F Aspirate...ured utilizing standard aspirated thermocouples, namely an United Sensor and Control Corp. type TK-8-C/A-36-F. The Test Compressor out- let

  19. Spectral Line Parameters Including Temperature Dependences of Self- and Air-Broadening in the 2 (left arrow) 0 Band of CO at 2.3 micrometers

    NASA Technical Reports Server (NTRS)

    Devi, V. Malathy; Benner, D. Chris; Smith, M. A. H.; Mantz, A. W.; Sung, K.; Brown, L. R.; Predoi-Cross, A.

    2012-01-01

    Temperature dependences of pressure-broadened half-width and pressure-induced shift coefficients along with accurate positions and intensities have been determined for transitions in the 2<--0 band of C-12 O-16 from analyzing high-resolution and high signal-to-noise spectra recorded with two different Fourier transform spectrometers. A total of 28 spectra, 16 self-broadened and 12 air-broadened, recorded using high- purity (greater than or equal to 99.5% C-12-enriched) CO samples and CO diluted with dry air(research grade) at different temperatures and pressures, were analyzed simultaneously to maximize the accuracy of the retrieved parameters. The sample temperatures ranged from 150 to 298K and the total pressures varied between 5 and 700 Torr. A multispectrum nonlinear least squares spectrum fitting technique was used to adjust the rovibrational constants (G, B, D, etc.) and intensity parameters (including Herman-Wallis coefficients), rather than determining individual line positions and intensities. Self-and air-broadened Lorentz half-width coefficients, their temperature dependence exponents, self- and air-pressure-induced shift coefficients, their temperature dependences, self- and air-line mixing coefficients, their temperature dependences and speed dependence have been retrieved from the analysis. Speed-dependent line shapes with line mixing employing off-diagonal relaxation matrix element formalism were needed to minimize the fit residuals. This study presents a precise and complete set of spectral line parameters that consistently reproduce the spectrum of carbon monoxide over terrestrial atmospheric conditions.

  20. A Performance Map for Ideal Air Breathing Pulse Detonation Engines

    NASA Technical Reports Server (NTRS)

    Paxson, Daniel E.

    2001-01-01

    The performance of an ideal, air breathing Pulse Detonation Engine is described in a manner that is useful for application studies (e.g., as a stand-alone, propulsion system, in combined cycles, or in hybrid turbomachinery cycles). It is shown that the Pulse Detonation Engine may be characterized by an averaged total pressure ratio, which is a unique function of the inlet temperature, the fraction of the inlet flow containing a reacting mixture, and the stoichiometry of the mixture. The inlet temperature and stoichiometry (equivalence ratio) may in turn be combined to form a nondimensional heat addition parameter. For each value of this parameter, the average total enthalpy ratio and total pressure ratio across the device are functions of only the reactant fill fraction. Performance over the entire operating envelope can thus be presented on a single plot of total pressure ratio versus total enthalpy ratio for families of the heat addition parameter. Total pressure ratios are derived from thrust calculations obtained from an experimentally validated, reactive Euler code capable of computing complete Pulse Detonation Engine limit cycles. Results are presented which demonstrate the utility of the described method for assessing performance of the Pulse Detonation Engine in several potential applications. Limitations and assumptions of the analysis are discussed. Details of the particular detonative cycle used for the computations are described.

  1. Preliminary tests of an advanced high-temperature combustion system

    NASA Technical Reports Server (NTRS)

    Wear, J. D.; Trout, A. M.; Smith, J. M.; Jacobs, R. E.

    1983-01-01

    A combustion system has been developed to operate efficiently and with good durability at inlet pressures to 4.05 MPa (40 atm), inlet air temperatures to 900 K, and exhaust gas temperatures to 2480 K. A preliminary investigation of this system was conducted at inlet pressures to 0.94 MPa (9 atm), a nominal inlet air temperature of 560 K, and exhaust gas temperatures to 2135 K. A maximum combustion efficiency of 98.5 percent was attained at a fuel-air ratio of 0.033; the combustion efficiency decreased to about 90 percent as the fuel-air ratio was increased to 0.058. An average liner metal temperature of 915 K, 355 kelvins greater than the nominal inlet air temperature, was reached with an average exhaust gas temperature of 2090 K. The maximum local metal temperature at this condition was about 565 kelvins above the nominal inlet air temperature and decreased to 505 kelvins above with increasing combustor pressure. Tests to determine the isothermal total pressure loss of the combustor showed a liner loss of 1.1 percent and a system loss of 6.5 percent.

  2. 40 CFR Table 3 to Subpart Ooo of... - Batch Process Vent Monitoring Requirements

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... specified in § 63.1416(d). a Carbon adsorber a Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. Temperature of the carbon bed...

  3. 40 CFR Table 3 to Subpart Ooo of... - Batch Process Vent Monitoring Requirements

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... specified in § 63.1416(d). a Carbon adsorber a Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. Temperature of the carbon bed...

  4. 40 CFR Table 3 to Subpart Ooo of... - Batch Process Vent Monitoring Requirements

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... specified in § 63.1416(d). a Carbon adsorber a Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) during carbon bed regeneration cycle(s), and Record the total regeneration steam flow or nitrogen flow, or pressure for each carbon bed regeneration cycle. Temperature of the carbon bed...

  5. Atmospheric pressure atomic layer deposition of Al₂O₃ using trimethyl aluminum and ozone.

    PubMed

    Mousa, Moataz Bellah M; Oldham, Christopher J; Parsons, Gregory N

    2014-04-08

    High throughput spatial atomic layer deposition (ALD) often uses higher reactor pressure than typical batch processes, but the specific effects of pressure on species transport and reaction rates are not fully understood. For aluminum oxide (Al2O3) ALD, water or ozone can be used as oxygen sources, but how reaction pressure influences deposition using ozone has not previously been reported. This work describes the effect of deposition pressure, between ∼2 and 760 Torr, on ALD Al2O3 using TMA and ozone. Similar to reports for pressure dependence during TMA/water ALD, surface reaction saturation studies show self-limiting growth at low and high pressure across a reasonable temperature range. Higher pressure tends to increase the growth per cycle, especially at lower gas velocities and temperatures. However, growth saturation at high pressure requires longer O3 dose times per cycle. Results are consistent with a model of ozone decomposition kinetics versus pressure and temperature. Quartz crystal microbalance (QCM) results confirm the trends in growth rate and indicate that the surface reaction mechanisms for Al2O3 growth using ozone are similar under low and high total pressure, including expected trends in the reaction mechanism at different temperatures.

  6. Global exospheric temperatures and densities under active solar conditions. [measured by OGO-6

    NASA Technical Reports Server (NTRS)

    Wydra, B. J.

    1975-01-01

    Temperatures measured by the OGO-6 satellite using the 6300 A airglow spectrum are compared with temperatures derived from total densities and N2 densities. It is shown that while the variation of the total densities with latitude and magnetic activity agree well with values used for CIRA (1972), the temperature behavior is very different. While the temperatures derived from the N2 density were in much better agreement there were several important differences which radically affect the pressure gradients. The variation of temperature with magnetic activity indicated a seasonal and local time effect and also a latitude and delay time variation different from previous density derived temperatures. A new magnetic index is proposed that is better correlated with the observed temperatures. The temperature variations at high latitudes were examined for three levels of magnetic activity for both solstices and equinox conditions. A temperature maximum in the pre-midnight sector and a minimum in the noon sector were noted and seasonal and geomagnetic time and latitude effects discussed. Neutral temperature, density, pressure and boundary oxygen variations for the great storm of March 8, 1970 are presented.

  7. An empirical equation with tables of smoothed solubilities of methane in water and aqueous sodium chloride solutions up to 25 weight percent, 360 degrees C, and 138 MPa

    USGS Publications Warehouse

    Haas, John L.

    1978-01-01

    The total pressure for the system H2O-CH 4 is given by p(total) = P(H2O,t) + exp10[log x(CH 4) - a - b x(CH4)], where P(H2O,t) is the vapor pressure of H2O liquid at the temperature t (?C) and x(CH 4) is the molal concentration of methane in the solution. The terms a and b are functions of temperature only. Where the total pressure and temperature are known, the concentration of methane, x(CH4), is found by iteration. The concentration of methane in a sodium chloride brine, y(CH4), is estimated using the function log y(CH4) = log x(CH4) - A I, where A is the salting out constant and I is the ionic strength. For sodium chloride solutions, the ionic strength is equal to the molality of the salt. The equations are valid to 360?C, 138 MPa, and 25 weight percent sodium chloride.

  8. Aerothermal tests of quilted dome models on a flat plate at a Mach number of 6.5

    NASA Technical Reports Server (NTRS)

    Glass, Christopher E.; Hunt, L. Roane

    1988-01-01

    Aerothermal tests were conducted in the NASA Langley 8 Foot High Temperature Tunnel (8'HTT) at a Mach number of 6.5 on simulated arrays of thermally bowed metallic thermal protection system (TPS) tiles at an angle of attack of 5 deg. Detailed surface pressures and heating rates were obtained for arrays aligned with the flow and skewed 45 deg diagonally to the flow with nominal bowed heights of 0.1, 0.2, and 0.4 inch submerged in both laminar and turbulent boundary layers. Aerothermal tests were made at a nominal total temperature of 3300 R, a total pressure of 400 psia, a total enthalpy of 950 Btu/lbm, a dynamic pressure of 2.7 psi, and a unit Reynolds number of 400,000 per foot. The experimental results form a data base that can be used to help protect aerothermal load increases from bowed arrays of TPS tiles.

  9. Effects of tritium gas exposure on the dynamic mechanical properties of EPDM elastomer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Clark, E. A.; Staack, G. C.

    2008-07-15

    Samples of ethylene propylene diene monomer (EPDM) elastomer were exposed to tritium gas in closed containers at 101 kPa (1 atmosphere) pressure and ambient temperature for about one week. Tritium exposure effects on the samples were characterized by dynamic mechanical analysis (DMA) and radiolysis products were characterized by measuring the total final pressure and composition in the exposure containers at the end of exposure period. There was no effect of one week tritium exposure on the glass transition temperature, Tg, of the samples tested. Impurity gases produced in the closed containers included HT and lesser amounts of H{sub 2}, DTO,more » and CT{sub 4}. The total pressure remained the same during exposure. (authors)« less

  10. EFFECTS OF TRITIUM GAS EXPOSURE ON THE DYNAMIC MECHANICAL PROPERTIES OF EPDM ELASTOMER

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Clark, E; Gregory Staack, G

    2007-08-13

    Samples of ethylene propylene diene monomer (EPDM) elastomer were exposed to tritium gas in closed containers initially at 101 kPa (1 atmosphere) pressure and ambient temperature for about one week. Tritium exposure effects on the samples were characterized by dynamic mechanical analysis (DMA) and radiolysis products were characterized by measuring the total final pressure and composition in the exposure containers at the end of exposure period. There was no effect of one week tritium exposure on the glass transition temperature, Tg, of the samples tested. Impurity gases produced in the closed containers included HT and lesser amounts of H{sub 2},more » DTO, and CT{sub 4}. The total pressure remained the same during exposure.« less

  11. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Oktamuliani, Sri, E-mail: srioktamuliani@ymail.com; Su’ud, Zaki, E-mail: szaki@fi.itb.ac.id

    A preliminary study designs SPINNOR (Small Power Reactor, Indonesia, No On-Site Refueling) liquid metal Pb-Bi cooled fast reactors, fuel (U, Pu)N, 150 MWth have been performed. Neutronic calculation uses SRAC which is designed cylindrical core 2D (R-Z) 90 × 135 cm, on the core fuel composed of heterogeneous with percentage difference of PuN 10, 12, 13% and the result of calculation is effective neutron multiplication 1.0488. Power density distribution of the output SRAC is generated for thermal hydraulic calculation using Delphi based on Pascal language that have been developed. The research designed a reactor that is capable of natural circulation atmore » inlet temperature 300 °C with variation of total mass flow rate. Total mass flow rate affect pressure drop and temperature outlet of the reactor core. The greater the total mass flow rate, the smaller the outlet temperature, but increase the pressure drop so that the chimney needed more higher to achieve natural circulation or condition of the system does not require a pump. Optimization of the total mass flow rate produces optimal reactor design on the total mass flow rate of 5000 kg/s with outlet temperature 524,843 °C but require a chimney of 6,69 meters.« less

  12. Vapor pressure and vapor fractionation of silicate melts of tektite composition

    USGS Publications Warehouse

    Walter, Louis S.; Carron, M.K.

    1964-01-01

    The total vapor pressure of Philippine tektite melts of approximately 70 per cent silica has been determined at temperatures ranging from 1500 to 2100??C. This pressure is 190 ?? 40 mm Hg at 1500??C, 450 ?? 50 mm at 1800??C and 850 ?? 70 mm at 2100?? C. Determinations were made by visually observing the temperature at which bubbles began to form at a constant low ambient pressure. By varying the ambient pressure, a boiling point curve was constructed. This curve differs from the equilibrium vapor pressure curve due to surface tension effects. This difference was evaluated by determining the equilibrium bubble size in the melt and calculating the pressure due to surface tension, assuming the latter to be 380 dyn/cm. The relative volatility from tektite melts of the oxides of Na, K, Fe, Al and Si has been determined as a function of temperature, total pressure arid roughly, of oxygen fugacity. The volatility of SiO2 is decreased and that of Na2O and K2O is increased in an oxygen-poor environment. Preliminary results indicate that volatilization at 2100??C under atmospheric pressure caused little or no change in the percentage Na2O and K2O. The ratio Fe3 Fe2 of the tektite is increased in ambient air at a pressure of 9 ?? 10-4 mm Hg (= 106.5 atm O2, partial pressure) at 2000??C. This suggests that tektites were formed either at lower oxygen pressures or that they are a product of incomplete oxidation of parent material with a still lower ferricferrous ratio. ?? 1964.

  13. An experimental and computational investigation of film cooling effects on an interceptor forebody at Mach 10

    NASA Astrophysics Data System (ADS)

    Majeski, J. A.; Morris, H. W.

    1990-01-01

    An experiment using a full-scale model of an interceptor forebody configuration was conducted to determine the effectiveness of transpiration and film cooling on temperature control of an IR window during hypersonic flight. This experiment was conducted at a freestream Mach number of 10. The test total temperature was nominally 1100 K, and the test total pressure was nominally 50,000 KPa. The Reynolds number associated with these test conditions was 34.1 million/m. Results encompass pressure data, heat-transfer data, effect of upstream transpiration cooling, and film cooling effectiveness.

  14. Measurement of density and temperature in a hypersonic turbulent boundary layer using the electron beam fluorescence technique. Ph.D. Thesis. Final Report, 1 Oct. 1969 - 1 Sep. 1972

    NASA Technical Reports Server (NTRS)

    Mcronald, A. D.

    1975-01-01

    Mean density and temperature fluctuations were measured across the turbulent, cooled-wall boundary layer in a continuous hypersonic (Mach 9.4) wind tunnel in air, using the nitrogen fluorescence excited by a 50 kV electron beam. Data were taken at three values of the tunnel stagnation pressure, the corresponding free stream densities being equivalent to 1.2, 4.0, and 7.4 torr at room temperature, and the boundary layer thicknesses about 4.0, 4.5, and 6.0 inches. The mean temperature and density profiles were similar to those previously determined in the same facility by conventional probes (static and pitot pressure, total temperature). A static pressure variation of about 50% across the boundary layer was found, the shape of the variation changing somewhat for the three stagnation pressure levels. The quadrupole model for rotational temperature spectra gave closer agreement with the free stream isentropic level (approximately 44 K) than the dipole model.

  15. Control of differential strain during heating and cooling of mixed conducting metal oxide membranes

    DOEpatents

    Carolan, Michael Francis

    2007-12-25

    Method of operating an oxygen-permeable mixed conducting membrane having an oxidant feed side and a permeate side, which method comprises controlling the differential strain between the oxidant feed side and the permeate side by varying either or both of the oxygen partial pressure and the total gas pressure on either or both of the oxidant feed side and the permeate side of the membrane while changing the temperature of the membrane from a first temperature to a second temperature.

  16. Characterizing the Chemical Stability of High Temperature Materials for Application in Extreme Environments

    NASA Technical Reports Server (NTRS)

    Opila, Elizabeth

    2005-01-01

    The chemical stability of high temperature materials must be known for use in the extreme environments of combustion applications. The characterization techniques available at NASA Glenn Research Center vary from fundamental thermodynamic property determination to material durability testing in actual engine environments. In this paper some of the unique techniques and facilities available at NASA Glenn will be reviewed. Multiple cell Knudsen effusion mass spectrometry is used to determine thermodynamic data by sampling gas species formed by reaction or equilibration in a Knudsen cell held in a vacuum. The transpiration technique can also be used to determine thermodynamic data of volatile species but at atmospheric pressures. Thermodynamic data in the Si-O-H(g) system were determined with this technique. Free Jet Sampling Mass Spectrometry can be used to study gas-solid interactions at a pressure of one atmosphere. Volatile Si(OH)4(g) was identified by this mass spectrometry technique. A High Pressure Burner Rig is used to expose high temperature materials in hydrocarbon-fueled combustion environments. Silicon carbide (SiC) volatility rates were measured in the burner rig as a function of total pressure, gas velocity and temperature. Finally, the Research Combustion Lab Rocket Test Cell is used to expose high temperature materials in hydrogen/oxygen rocket engine environments to assess material durability. SiC recession due to rocket engine exposures was measured as a function of oxidant/fuel ratio, temperature, and total pressure. The emphasis of the discussion for all techniques will be placed on experimental factors that must be controlled for accurate acquisition of results and reliable prediction of high temperature material chemical stability.

  17. User's Manual for Aerofcn: a FORTRAN Program to Compute Aerodynamic Parameters

    NASA Technical Reports Server (NTRS)

    Conley, Joseph L.

    1992-01-01

    The computer program AeroFcn is discussed. AeroFcn is a utility program that computes the following aerodynamic parameters: geopotential altitude, Mach number, true velocity, dynamic pressure, calibrated airspeed, equivalent airspeed, impact pressure, total pressure, total temperature, Reynolds number, speed of sound, static density, static pressure, static temperature, coefficient of dynamic viscosity, kinematic viscosity, geometric altitude, and specific energy for a standard- or a modified standard-day atmosphere using compressible flow and normal shock relations. Any two parameters that define a unique flight condition are selected, and their values are entered interactively. The remaining parameters are computed, and the solutions are stored in an output file. Multiple cases can be run, and the multiple case solutions can be stored in another output file for plotting. Parameter units, the output format, and primary constants in the atmospheric and aerodynamic equations can also be changed.

  18. Core body temperature, skin temperature, and interface pressure. Relationship to skin integrity in nursing home residents.

    PubMed

    Knox, D M

    1999-06-01

    To ascertain the effects of 1-, 1 1/2-, and 2-hour turning intervals on nursing home residents' skin over the sacrum and trochanters. (1) the higher the core body temperature, the higher the skin surface temperature; (2) the 2-hour turning interval would have significantly higher skin surface temperature; (3) there would be no relationship between skin surface temperature and interface pressure; and (4) the sacrum would have the lowest skin surface temperature. Modified Latin-square. For-profit nursing home. Convenience sample of 26 residents who scored < 3 on the Short Portable Mini-Mental Status Questionnaire and did not have (1) open wounds; (2) albumin levels < 3.3 mg/dL; (3) severe arthritis; (4) cortisone, anticoagulation, insulin therapy or 3 medications for hypertension; and/or (5) were totally bedridden. First Temp measured core temperature; a disposable thermistor temperature probe, skin temperature; and a digital interface pressure evaluator, the interface pressure. Negative correlation (r = -.33, P = .003) occurred between core body temperature and skin surface temperature. Skin surface temperature rose at the end of the 2-hour turning interval but was not significant (F = (2.68) = .73, P = .49). Weak negative relationship (r = -12, P = .29) occurred between skin surface temperature and interface pressure, and sacral skin surface temperature was significantly lower for the left trochanter only (F = (8.68) = 7.05, P = .002). Although hypotheses were not supported, more research is needed to understand how time in position and multiple chronic illnesses interact to affect skin pressure tolerance.

  19. Performance Charts for a Turbojet System

    NASA Technical Reports Server (NTRS)

    Karp, Irving M.

    1947-01-01

    Convenient charts are presented for computing the thrust, fuel consumption, and other performance values of a turbojet system. These charts take into account the effects of ram pressure, compressor pressure ratio, ratio of combustion-chamber-outlet temperature to atmospheric temperature, compressor efficiency, turbine efficiency, combustion efficiency, discharge-nozzle coefficient, losses in total pressure in the inlet to the jet-propulsion unit and in the combustion chamber, and variation in specific heats with temperature. The principal performance charts show clearly the effects of the primary variables and correction charts provide the effects of the secondary variables. The performance of illustrative cases of turbojet systems is given. It is shown that maximum thrust per unit mass rate of air flow occurs at a lower compressor pressure ratio than minimum specific fuel consumption. The thrust per unit mass rate of air flow increases as the combustion-chamber discharge temperature increases. For minimum specific fuel consumption, however, an optimum combustion-chamber discharge temperature exists, which in some cases may be less than the limiting temperature imposed by the strength temperature characteristics of present materials.

  20. Shock temperatures in anorthite glass

    NASA Technical Reports Server (NTRS)

    Boslough, M. B.; Ahrens, T. J.; Mitchell, A. C.

    1983-01-01

    Temperatures of CaAl2Si2O8 (anorthite glass) shocked to pressures between 48 and 117 GPa were measured in the range from 2500 to 5600 K, using optical pyrometry techniques. The pressure dependence of the shock temperatures deviates significantly from predictions based on a single high pressure phase. At least three phase transitions, at pressures of about 55, 85, and 100 GPa and with transition energies of about 0.5 MJ/kg each (approximately 1.5 MJ/kg total) are required to explain the shock temperature data. The phase transition at 100 GPa can possibly be identified with the stishovite melting transition. Theoretical models of the time dependence of the thermal radiation from the shocked anorthite based on the geometry of the experiment and the absorptive properties of the shocked material yields good agreement with observations, indicating that it is not necessary to invoke intrinsic time dependences to explain the data in many cases.

  1. Stability of echogenic liposomes as a blood pool ultrasound contrast agent in a physiologic flow phantom.

    PubMed

    Radhakrishnan, Kirthi; Haworth, Kevin J; Huang, Shao-Ling; Klegerman, Melvin E; McPherson, David D; Holland, Christy K

    2012-11-01

    Echogenic liposomes (ELIP) are multifunctional ultrasound contrast agents (UCAs) with a lipid shell encapsulating both air and an aqueous core. ELIP are being developed for molecular imaging and image-guided therapeutic delivery. Stability of the echogenicity of ELIP in physiologic conditions is crucial to their successful translation to clinical use. In this study, we determined the effects of the surrounding media's dissolved air concentration, temperature transition and hydrodynamic pressure on the echogenicity of a chemically modified formulation of ELIP to promote stability and echogenicity. ELIP samples were diluted in porcine plasma or whole blood and pumped through a pulsatile flow system with adjustable hydrodynamic pressures and temperature. B-mode images were acquired using a clinical diagnostic scanner every 5 s for a total duration of 75 s. Echogenicity in porcine plasma was assessed as a function of total dissolved gas saturation. ELIP were added to plasma at room temperature (22 °C) or body temperature (37 °C) and pumped through a system maintained at 22 °C or 37 °C to study the effect of temperature transitions on ELIP echogenicity. Echogenicity at normotensive (120/80 mmHg) and hypertensive pressures (145/90 mmHg) was measured. ELIP were echogenic in plasma and whole blood at body temperature under normotensive to hypertensive pressures. Warming of samples from room temperature to body temperature did not alter echogenicity. However, in plasma cooled rapidly from body temperature to room temperature or in degassed plasma, ELIP lost echogenicity within 20 s at 120/80 mmHg. The stability of echogenicity of a modified ELIP formulation was determined in vitro at body temperature, physiologic gas concentration and throughout the physiologic pressure range. However, proper care should be taken to ensure that ELIP are not cooled rapidly from body temperature to room temperature as they will lose their echogenic properties. Further in vivo investigations will be needed to evaluate the optimal usage of ELIP as blood pool contrast agents. Copyright © 2012 World Federation for Ultrasound in Medicine & Biology. Published by Elsevier Inc. All rights reserved.

  2. Electronic structure and thermoelectric transport properties of the golden Th{sub 2}S{sub 3}-type Ti{sub 2}O{sub 3} under pressure

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Xu, Bin, E-mail: hnsqxubin@163.com; Gao, Changzheng; Zhang, Jing

    2016-05-15

    A lot of physical properties of Th{sub 2}S{sub 3}-type Ti{sub 2}O{sub 3} have investigated experimentally, hence, we calculated electronic structure and thermoelectric transport properties by the first-principles calculation under pressure. The increase of the band gaps is very fast from 30 GPa to 35 GPa, which is mainly because of the rapid change of the lattice constants. The total density of states becomes smaller with increasing pressure, which shows that Seebeck coefficient gradually decreases. Two main peaks of Seebeck coefficients always decrease and shift to the high doping area with increasing temperature under pressure. The electrical conductivities always decrease withmore » increasing temperature under pressure. The electrical conductivity can be improved by increasing pressure. Electronic thermal conductivity increases with increasing pressure. It is noted that the thermoelectric properties is reduced with increasing temperature.« less

  3. Importance of Ambipolar Electric Field in the Ion Loss from Mars- Results from a Multi-fluid MHD Model with the Electron Pressure Equation Included

    NASA Astrophysics Data System (ADS)

    Ma, Y.; Dong, C.; van der Holst, B.; Nagy, A. F.; Bougher, S. W.; Toth, G.; Cravens, T.; Yelle, R. V.; Jakosky, B. M.

    2017-12-01

    The multi-fluid (MF) magnetohydrodynamic (MHD) model of Mars is further improved by solving an additional electron pressure equation. Through the electron pressure equation, the electron temperature is calculated based on the effects from various electrons related heating and cooling processes (e.g. photo-electron heating, electron-neutral collision and electron-ion collision), and thus the improved model is able to calculate the electron temperature and the electron pressure force self-consistently. Electron thermal conductivity is also considered in the calculation. Model results of a normal case with electron pressure equation included (MFPe) are compared in detail to an identical case using the regular MF model to identify the effect of the improved physics. We found that when the electron pressure equation is included, the general interaction patterns are similar to that of the case with no electron pressure equation. The model with electron pressure equation predicts that electron temperature is much larger than the ion temperature in the ionosphere, consistent with both Viking and MAVEN observations. The inclusion of electron pressure equation significantly increases the total escape fluxes predicted by the model, indicating the importance of the ambipolar electric field(electron pressure gradient) in driving the ion loss from Mars.

  4. Experimental Investigation of Reacting Flow Characteristics in a Dual-Mode Scramjet Combustor

    NASA Astrophysics Data System (ADS)

    Shi, Deyong; Song, Wenyan; Ye, Jingfeng; Tao, Bo; Wang, Yanhua

    2016-06-01

    In this work, a hydrogen-fueled dual-mode scramjet combustor was investigated experimentally. Clean and dry air was supplied to the combustor through a Mach 2 nozzle with a total temperature of 800 K and a total pressure of 800 kPa. The high enthalpy air was provided by an electricity resistance heater. Room temperature hydrogen was injected with sonic speed from injector orifices vertically, and downstream the injector a tandem cavity flame holder was mounted. Except wall pressure profiles, velocity and temperature profiles in and at exit of the combustor were also measured using hydroxyl tagging velocimetry (HTV) and tunable diode laser absorption spectroscopy (TDLAS), respectively. Results showed that combustion occurred mainly at the bottom side of the combustor. And there were also an extreme disparity of the velocity and temperature profiles along the Y-direction, i.e. the transverse direction.

  5. Pollutant emissions from flat-flame burners at high pressures

    NASA Technical Reports Server (NTRS)

    Maahs, H. G.; Miller, I. M.

    1980-01-01

    Maximum flame temperatures and pollutant emission measurements for NOx, CO, and UHC (unburned hydrocarbons) are reported for premixed methane air flat flames at constant total mass flow rate over the pressure range from 1.9 to 30 atm and for equivalence ratios from 0.84 to 1.12. For any given pressure, maxima typically occur in both the temperature and NOx emissions curves slightly to the lean side of stoichiometric conditions. The UHC emissions show minima at roughly the same equivalence ratios. The CO emissions, however, increase continually with increasing equivalence ratio. Flame temperature and NOx emissions decrease with increasing pressure, while the opposite is true for the CO and UHC emissions. The NOx data correlate reasonably well as a function of flame temperature only. Four flameholders, differing only slightly, were used. In general, the temperature and emissions data from these four flameholders are similar, but some differences also exist. These differences appear to be related to minor variations in the condition of the flameholder surfaces.

  6. Environmental Resistance in the Mars Atmosphere

    NASA Astrophysics Data System (ADS)

    Pint, Bruce A.; Tortorelli, Peter F.

    2005-02-01

    The atmosphere of Mars is ~6mbar of total pressure (compared to ~1 bar on Earth) and 95%CO2. Thermodynamic calculations have been made of the partial pressure of oxygen as a function of temperature assuming various impurities in the remaining 5%. These oxygen pressures are sufficient to oxidize most common metals in the 900-1300K range. Therefore, oxidation resistance will be a concern for materials of construction in a high temperature fission reactor on Mars. An additional environmental resistance consideration is internal carburization during exposures in CO2. The effect of low pressure CO2 exposures on the mechanical properties of austenitic alloys is being investigated.

  7. Extraction of ewe's milk cream with supercritical carbon dioxide.

    PubMed

    González Hierro, M T; Ruiz-Sala, P; Alonso, L; Santa-María, G

    1995-04-01

    The extraction of ewe's milk cream by supercritical carbon dioxide in the pressure range 9-30 MPa (90-300 bar) and at temperatures of 40 degrees C and 50 degrees C was studied. The solubility of total fat increased with pressure at both temperatures until a plateau was reached. The extraction of cholesterol also increased with pressure until a plateau was reached and it was higher at 50 degrees C than at 40 degrees C when the pressure was > or = 15 MPa (150 bar). The triglyceride composition of each extract, determined by GC, showed that extracts obtained at lower pressures were enriched in short-chain triglycerides and their concentration decreased as the pressure increased. In the other hand, long-chain triglycerides were enriched in the extracts obtained at higher pressures and their concentration rose with increasing pressure.

  8. 40 CFR Table 4 to Subpart Ooo of... - Operating Parameter Levels

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... specific gravity Condenser Exit temperature Maximum temperature Carbon absorber Total regeneration steam or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15 minutes of completing any cooling cycle(s)) Maximum...

  9. 40 CFR Table 4 to Subpart Ooo of... - Operating Parameter Levels

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... specific gravity Condenser Exit temperature Maximum temperature Carbon absorber Total regeneration steam or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15 minutes of completing any cooling cycle(s)) Maximum...

  10. 40 CFR Table 4 to Subpart Ooo of... - Operating Parameter Levels

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... specific gravity Condenser Exit temperature Maximum temperature Carbon absorber Total regeneration steam or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15 minutes of completing any cooling cycle(s)) Maximum...

  11. Experimental evaluation of a TF30-P-3 turbofan engine in an altitude facility: Effect of steady-state temperature distortion

    NASA Technical Reports Server (NTRS)

    Braithwaite, W. M.

    1973-01-01

    The effects of circumferential distortion of the total temperature entering 25, 50, and 75 percent of the inlet circumferential annulus of a turbofan engine were determined. Complete compressor stall resulted from distortions of from 14 to 20 percent of the face averaged temperature. Increasing the temperature level in one sector resulted in that sector moving toward stall by decreasing the equivalent rotor speeds while the pressure ratio remained approximately constant. Stall originated as a rotating zone in the low-pressure compressor which resulted as a terminal stall in the high-pressure compressor. Decreasing the Reynolds number index to 0.25 from 0.5 reduced the required distortion for stall by 50 percent for the conditions investigated.

  12. Effect of cathode cooling efficiency and oxygen plasma gas pressure on the hafnium cathode wall temperature

    NASA Astrophysics Data System (ADS)

    Ashtekar, Koustubh; Diehl, Gregory; Hamer, John

    2012-10-01

    The hafnium cathode is widely used in DC plasma arc cutting (PAC) under an oxygen gas environment to cut iron and iron alloys. The hafnium erosion is always a concern which is controlled by the surface temperature. In this study, the effect of cathode cooling efficiency and oxygen gas pressure on the hafnium surface temperature are quantified. The two layer cathode sheath model is applied on the refractive hafnium surface while oxygen species (O2, O, O+, O++, e-) are considered within the thermal dis-equilibrium regime. The system of non-linear equations comprising of current density balance, heat flux balance at both the cathode surface and the sheath-ionization layer is coupled with the plasma gas composition solver. Using cooling heat flux, gas pressure and current density as inputs; the cathode wall temperature, electron temperature, and sheath voltage drop are calculated. Additionally, contribution of emitted electron current (Je) and ions current (Ji) to the total current flux are estimated. Higher gas pressure usually reduces Ji and increases Je that reduces the surface temperature by thermionic cooling.

  13. Computer programs for pressurization (RAMP) and pressurized expulsion from a cryogenic liquid propellant tank

    NASA Technical Reports Server (NTRS)

    Masters, P. A.

    1974-01-01

    An analysis to predict the pressurant gas requirements for the discharge of cryogenic liquid propellants from storage tanks is presented, along with an algorithm and two computer programs. One program deals with the pressurization (ramp) phase of bringing the propellant tank up to its operating pressure. The method of analysis involves a numerical solution of the temperature and velocity functions for the tank ullage at a discrete set of points in time and space. The input requirements of the program are the initial ullage conditions, the initial temperature and pressure of the pressurant gas, and the time for the expulsion or the ramp. Computations are performed which determine the heat transfer between the ullage gas and the tank wall. Heat transfer to the liquid interface and to the hardware components may be included in the analysis. The program output includes predictions of mass of pressurant required, total energy transfer, and wall and ullage temperatures. The analysis, the algorithm, a complete description of input and output, and the FORTRAN 4 program listings are presented. Sample cases are included to illustrate use of the programs.

  14. Effect of flame stabilizer design on performance and exhaust pollutants of a two-row 72-module swirl-can combustor

    NASA Technical Reports Server (NTRS)

    Biaglow, J. A.; Trout, A. M.

    1976-01-01

    A test program was conducted to evaluate the effects of four flame stabilizer designs on the performance and gaseous pollutant levels of an experimental full-annular swirl-can combustor. Combustor operating parameters, including inlet-air temperature, reference velocity, and fuel-air ratio, were set to simulate conditions in a 30:1 pressure ratio engine. Combustor inlet total pressure was held constant at 6 atm due to the facility limit. Combustor performance and gaseous pollutant levels were strongly affected by the geometry and resulting total pressure loss of the four flame stabilizer designs investigated. The addition of shrouds to two designs produced an 18 to 22% decrease in the combustion chamber pressure loss and thus resulted in doubling the exit temperature pattern factor and up to 42% higher levels of oxides of nitrogen. A previously developed oxides of nitrogen correlating parameter agreed with each model within an emission index of plus or minus 1 but was not capable of correlating all models together.

  15. The Ames 12-Foot Pressure Tunnel: Tunnel Empty Flow Calibration Results and Discussion

    NASA Technical Reports Server (NTRS)

    Zell, Peter T.; Banducci, David E. (Technical Monitor)

    1996-01-01

    An empty test section flow calibration of the refurbished NASA Ames 12-Foot Pressure Tunnel was recently completed. Distributions of total pressure, dynamic pressure, Mach number, flow angularity temperature, and turbulence are presented along with results obtained prior to facility demolition. Axial static pressure distributions along tunnel centerline are also compared. Test section model support geometric configurations will be presented along with a discussion of the issues involved with different model mounting schemes.

  16. SSME Turbopump Turbine Computations

    NASA Technical Reports Server (NTRS)

    Jorgenson, P. G. E.

    1985-01-01

    A two-dimensional viscous code was developed to be used in the prediction of the flow in the SSME high-pressure turbopump blade passages. The rotor viscous code (RVC) employs a four-step Runge-Kutta scheme to solve the two-dimensional, thin-layer Navier-Stokes equations. The Baldwin-Lomax eddy-viscosity model is used for these turbulent flow calculations. A viable method was developed to use the relative exit conditions from an upstream blade row as the inlet conditions to the next blade row. The blade loading diagrams are compared with the meridional values obtained from an in-house quasithree-dimensional inviscid code. Periodic boundary conditions are imposed on a body-fitted C-grid computed by using the GRAPE GRids about Airfoils using Poisson's Equation (GRAPE) code. Total pressure, total temperature, and flow angle are specified at the inlet. The upstream-running Riemann invariant is extrapolated from the interior. Static pressure is specified at the exit such that mass flow is conserved from blade row to blade row, and the conservative variables are extrapolated from the interior. For viscous flows the noslip condition is imposed at the wall. The normal momentum equation gives the pressure at the wall. The density at the wall is obtained from the wall total temperature.

  17. Computer program for preliminary design analysis of axial-flow turbines

    NASA Technical Reports Server (NTRS)

    Glassman, A. J.

    1972-01-01

    The program method is based on a mean-diameter flow analysis. Input design requirements include power or pressure ratio, flow, temperature, pressure, and speed. Turbine designs are generated for any specified number of stages and for any of three types of velocity diagrams (symmetrical, zero exit swirl, or impulse). Exit turning vanes can be included in the design. Program output includes inlet and exit annulus dimensions, exit temperature and pressure, total and static efficiencies, blading angles, and last-stage critical velocity ratios. The report presents the analysis method, a description of input and output with sample cases, and the program listing.

  18. Direct high-pressure NMR observation of dipicolinic acid leaking from bacterial spore: A crucial step for thermal inactivation.

    PubMed

    Akasaka, Kazuyuki; Maeno, Akihiro; Yamazaki, Akira

    2017-12-01

    A bacterial spore protects itself with an unusually high concentration (~10% in dry weight of spore) of dipicolinic acid (DPA), the release of which is considered the crucial step for inactivating it under mild pressure and temperature conditions. However, the process of how the spore releases DPA in response to pressure remains obscure. Here we apply 1 H high-resolution high-pressure NMR spectroscopy, for the first time, to the spore suspension of Bacillus subtilis natto and monitor directly and in real-time the leaking process of DPA in response to pressure of 200MPa at 20°C. We find that about one third of the total DPA leaks immediately upon applying pressure, but that the rest leaks slowly in hrs upon decreasing the pressure. Once DPA is fully released from the spore, the proteins of the spore become easily denatured at a mild temperature, e.g., 80°C, much below the temperature commonly used to inactivate spores (121°C). The success of the present experiment opens a new avenue for studying bacterial spores and cells at the molecular level in response to pressure, temperature and other perturbations. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Measurement of Turbulent Pressure and Temperature Fluctuations in a Gas Turbine Combustor

    NASA Technical Reports Server (NTRS)

    Povinelli, Louis (Technical Monitor); LaGraff, John E.; Bramanti, Cristina; Pldfield, Martin; Passaro, Andrea; Biagioni, Leonardo

    2004-01-01

    The report summarizes the results of the redesign efforts directed towards the gas-turbine combustor rapid-injector flow diagnostic probe developed under sponsorship of NASA-GRC and earlier reported in NASA-CR-2003-212540. Lessons learned during the theoretical development, developmental testing and field-testing in the previous phase of this research were applied to redesign of both the probe sensing elements and of the rapid injection device. This redesigned probe (referred to herein as Turboprobe) has been fabricated and is ready, along with the new rapid injector, for field-testing. The probe is now designed to capture both time-resolved and mean total temperatures, total pressures and, indirectly, one component of turbulent fluctuations.

  20. Heat transfer rate and film cooling effectiveness measurements in a transient cascade

    NASA Astrophysics Data System (ADS)

    Schultz, D. L.; Oldfield, M. L. G.; Jones, T. V.

    1980-09-01

    A transient cascade useful for heat transfer rate measurements is briefly described. The facility employs a free piston which compresses the test gas to temperatures around 450 K and pressures of about 3.5 to 7.5 Atm. The model is initially at room temperature and it is necessary to attain the correct gas to wall temperature ratio. The exit Mach number is set by the inlet total pressure and the pressure in the exit dump tank. Thin film heat transfer gauges are used for the measurement of heat transfer rate, deposited on machineable glass ceramic blades. The inherently fast response of these transducers makes them useful for the investigation of boundary layer transition on blade surfaces and some typical results are included.

  1. Optical surface pressure measurements: Accuracy and application field evaluation

    NASA Astrophysics Data System (ADS)

    Bukov, A.; Mosharov, V.; Orlov, A.; Pesetsky, V.; Radchenko, V.; Phonov, S.; Matyash, S.; Kuzmin, M.; Sadovskii, N.

    1994-07-01

    Optical pressure measurement (OPM) is a new pressure measurement method rapidly developed in several aerodynamic research centers: TsAGI (Russia), Boeing, NASA, McDonnell Douglas (all USA), and DLR (Germany). Present level of OPM-method provides its practice as standard experimental method of aerodynamic investigations in definite application fields. Applications of OPM-method are determined mainly by its accuracy. The accuracy of OPM-method is determined by the errors of three following groups: (1) errors of the luminescent pressure sensor (LPS) itself, such as uncompensated temperature influence, photo degradation, temperature and pressure hysteresis, variation of the LPS parameters from point to point on the model surface, etc.; (2) errors of the measurement system, such as noise of the photodetector, nonlinearity and nonuniformity of the photodetector, time and temperature offsets, etc.; and (3) methodological errors, owing to displacement and deformation of the model in an airflow, a contamination of the model surface, scattering of the excitation and luminescent light from the model surface and test section walls, etc. OPM-method allows getting total error of measured pressure not less than 1 percent. This accuracy is enough to visualize the pressure field and allows determining total and distributed aerodynamic loads and solving some problems of local aerodynamic investigations at transonic and supersonic velocities. OPM is less effective at low subsonic velocities (M less than 0.4), and for precise measurements, for example, an airfoil optimization. Current limitations of the OPM-method are discussed on an example of the surface pressure measurements and calculations of the integral loads on the wings of canard-aircraft model. The pressure measurement system and data reduction methods used on these tests are also described.

  2. Reports of investigations on: Derivation of an infinite-dilution activity coefficient model and application to two-component vapor/liquid equilibria data: Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Roper, V.P.; Kobayashi, R.

    1988-02-01

    Infinite-dilution fugacity coefficients were obtained for the system fluorene/phenanthrene at thirteen temperatures by fitting total pressure across the entire mole fraction range by a computer routine. A thermodynamically consistent routine, that allowed for both positive and negative pressure deviations from the ideal values, was used to correlate data over the full mole fraction range from 0 to 1. The four-suffix Margules activity coefficient model without modification essentially served this purpose since total pressures and total pressure derivatives with respect to mole fraction were negligible compared to pressure measurement precision. The water/ethanol system and binary systems comprised of aniline, chlorobenzene, acetonitrilemore » and other polar compounds were fit for total pressure across the entire mole fraction range for binary Vapor-Liquid-Equilbria (VLE) using the rigorous, thermodynamically consistent Gibbs-Duhem Relation derived by Ibl and Dodge. Data correlation was performed using a computer least squares procedure. Infinite-dilution fugacity coefficients were obtained using a modified Margules activity coefficient model.« less

  3. Supercritical fluid extraction of phenolic compounds and antioxidants from grape (Vitis labrusca B.) seeds.

    PubMed

    Ghafoor, Kashif; Al-Juhaimi, Fahad Y; Choi, Yong Hee

    2012-12-01

    Supercritical fluid extraction (SFE) technique was applied and optimized for temperature, CO₂ pressure and ethanol (modifier) concentration using orthogonal array design and response surface methodology for the extract yield, total phenols and antioxidants from grape (Vitis labrusca B.) seeds. Effects of extraction temperature and pressure were found to be significant for all these response variables in SFE process. Optimum SFE conditions (44 ~ 46 °C temperature and 153 ~ 161 bar CO₂ pressure) along with ethanol (<7 %) as modifier, for the maximum predicted values of extract yield (12.09 %), total phenols (2.41 mg GAE/ml) and antioxidants (7.08 mg AAE/ml), were used to obtain extracts from grape seeds. The predicted values matched well with the experimental values (12.32 % extract yield, 2.45 mg GAE/ml total phenols and 7.08 mg AAE/ml antioxidants) obtained at optimum SFE conditions. The antiradical assay showed that SFE extracts of grape seeds can scavenge more than 85 % of 1, 1-diphenyl-2-picrylhydrazyl (DPPH) radicals. The grape seeds extracts were also analyzed for hydroxybenzoic acids which included gallic acid (1.21 ~ 3.84 μg/ml), protocatechuic acid (3.57 ~ 11.78 μg/ml) and p-hydroxybenzoic acid (206.72 ~ 688.18 μg/ml).

  4. Stressed Oxidation Life Prediction for C/SiC Composites

    NASA Technical Reports Server (NTRS)

    Levine, Stanley R.

    2004-01-01

    The residual strength and life of C/SiC is dominated by carbon interface and fiber oxidation if seal coat and matrix cracks are open to allow oxygen ingress. Crack opening is determined by the combination of thermal, mechanical and thermal expansion mismatch induced stresses. When cracks are open, life can be predicted by simple oxidation based models with reaction controlled kinetics at low temperature, and by gas phase diffusion controlled kinetics at high temperatures. Key life governing variables in these models include temperature, stress, initial strength, oxygen partial pressure, and total pressure. These models are described in this paper.

  5. The effect of pressure on the structural, electronic, magnetic, and thermodynamic properties of the Mn2RuGe inverse Heusler alloy

    NASA Astrophysics Data System (ADS)

    Song, Ting; Sun, Xiao-Wei; Tian, Jun-Hong; Wei, Xiao-Ping; Wan, Gui-Xin; Ma, Qin

    2017-04-01

    In the frame of density functional theory, first-principles calculations based on generalized gradient approximation and quasi-harmonic Debye approximation model in which the phononic effects are taken into account have been carried out to investigate the structural, electronic, magnetic, and thermodynamic properties of full-Heusler alloy Mn2RuGe in CuHg2Ti-type structure in the pressure range of 0-50 GPa. Present calculations predict that Mn2RuGe is a ferrimagnet with an optimized lattice parameter of 5.854 Å. The calculated total magnetic moment of 2.01 μB per formula unit is very close to integer value and agree well with the Slater-Pauling rule, where the partial spin moments of Mn (A) and Mn (B) which mainly contribute to the total magnetic moment are 2.66 μB and -0.90 μB, respectively. In the study of the energy band structures and density of states, Mn2RuGe exhibits half-metallicity with an indirect gap of 0.235 eV in the spin-down channels, and the shifting of bands towards higher energies in spin-down channel under high pressure. Meanwhile, the high-pressure thermodynamic properties of Mn2RuGe, such as the pressure-volume-temperature relationship, bulk modulus, thermal expansivity, heat capacity, Debye temperature, and Grüneisen parameter are evaluated systematically in the temperature range of 0-900 K. This set of data is considered as the useful information to understand the high-pressure and high-temperature properties for the Mn2RuZ-type Heusler alloy family.

  6. Conventional freezing plus high pressure-low temperature treatment: Physical properties, microbial quality and storage stability of beef meat.

    PubMed

    Fernández, Pedro P; Sanz, Pedro D; Molina-García, Antonio D; Otero, Laura; Guignon, Bérengère; Vaudagna, Sergio R

    2007-12-01

    Meat high-hydrostatic pressure treatment causes severe decolouration, preventing its commercialisation due to consumer rejection. Novel procedures involving product freezing plus low-temperature pressure processing are here investigated. Room temperature (20°C) pressurisation (650MPa/10min) and air blast freezing (-30°C) are compared to air blast freezing plus high pressure at subzero temperature (-35°C) in terms of drip loss, expressible moisture, shear force, colour, microbial quality and storage stability of fresh and salt-added beef samples (Longissimus dorsi muscle). The latter treatment induced solid water transitions among ice phases. Fresh beef high pressure treatment (650MPa/20°C/10min) increased significantly expressible moisture while it decreased in pressurised (650MPa/-35°C/10min) frozen beef. Salt addition reduced high pressure-induced water loss. Treatments studied did not change fresh or salt-added samples shear force. Frozen beef pressurised at low temperature showed L, a and b values after thawing close to fresh samples. However, these samples in frozen state, presented chromatic parameters similar to unfrozen beef pressurised at room temperature. Apparently, freezing protects meat against pressure colour deterioration, fresh colour being recovered after thawing. High pressure processing (20°C or -35°C) was very effective reducing aerobic total (2-log(10) cycles) and lactic acid bacteria counts (2.4-log(10) cycles), in fresh and salt-added samples. Frozen+pressurised beef stored at -18°C during 45 days recovered its original colour after thawing, similarly to just-treated samples while their counts remain below detection limits during storage.

  7. Effect of Air Cooling of Turbine Disk on Power and Efficiency of Turbine from Turbo Engineering Corporation TT13-18 Turbosupercharger.

    NASA Technical Reports Server (NTRS)

    Berkey, William E.

    1949-01-01

    An investigation was conducted to determine the effect of turbine-disk cooling with air on the efficiency and the power output of the radial-flow turbine from the Turbo Engineering Corporation TT13-18 turbosupercharger. The turbine was operated at a constant range of ratios of turbine-inlet total pressure to turbine-outlet static pressure of 1,5 and 2.0, turbine-inlet total pressure of 30 inches mercury absolute, turbine-inlet total temperature of 12000 to 20000 R, and rotor speeds of 6000 to 22,000 rpm, Over the normal operating range of the turbine, varying the corrected cooling-air weight flow from approximately 0,30 to 0.75 pound per second produced no measurable effect on the corrected turbine shaft horsepower or the turbine shaft adiabatic efficiency. Varying the turbine-inlet total temperature from 12000 to 20000 R caused no measurable change in the corrected cooling-air weight flow. Calculations indicated that the cooling-air pumping power in the disk passages was small and was within the limits of the accuracy of the power measurements. For high turbine power output, the power loss to the compressor for compressing the cooling air was approximately 3 percent of the total turbine shaft horsepower.

  8. Meteorological and constituent data for January and February 1981

    NASA Technical Reports Server (NTRS)

    1981-01-01

    Balloon data consisting of a plot showing the mixing ratio of ozone partial pressure in micromillibors and temperature in degrees centigrade versus pressure altitude in millibars is presented. An accompanying tabulation of meteorological and constituent data is also presented. The total overburden was aquired by Dobson Spectrophotometer 72.

  9. 40 CFR Table 7 to Subpart U of... - Operating Parameters for Which Monitoring Levels Are Required To Be Established for Continuous...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    .... Condenser Exit temperature Maximum temperature. Carbon adsorber Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15 minutes of completing any cooling cycle(s)) Maximum flow or...

  10. 40 CFR Table 7 to Subpart U of... - Operating Parameters for Which Monitoring Levels Are Required To Be Established for Continuous...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    .... Condenser Exit temperature Maximum temperature. Carbon adsorber Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15 minutes of completing any cooling cycle(s)) Maximum flow or...

  11. 40 CFR Table 7 to Subpart U of... - Operating Parameters for Which Monitoring Levels Are Required To Be Established for Continuous...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    .... Condenser Exit temperature Maximum temperature. Carbon adsorber Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15 minutes of completing any cooling cycle(s)) Maximum flow or...

  12. 40 CFR Table 7 to Subpart U of... - Operating Parameters for Which Monitoring Levels Are Required To Be Established for Continuous...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    .... Condenser Exit temperature Maximum temperature. Carbon adsorber Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15 minutes of completing any cooling cycle(s)) Maximum flow or...

  13. 40 CFR Table 7 to Subpart U of... - Operating Parameters for Which Monitoring Levels Are Required To Be Established for Continuous...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    .... Condenser Exit temperature Maximum temperature. Carbon adsorber Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15 minutes of completing any cooling cycle(s)) Maximum flow or...

  14. Characterization of a novel micro-pressure swirl reactor for removal of chemical oxygen demand and total nitrogen from domestic wastewater at low temperature.

    PubMed

    Ren, Qingkai; Yu, Yang; Zhu, Suiyi; Bian, Dejun; Huo, Mingxin; Zhou, Dandan; Huo, Hongliang

    2017-06-01

    A novel micro-pressure swirl reactor (MPSR) was designed and applied to treat domestic wastewater at low temperature by acclimating microbial biomass with steadily decreasing temperature from 15 to 3 °C. Chemical oxygen demand (COD) was constantly removed by 85% and maintained below 50 mg L -1 in the effluent during the process. When the air flow was controlled at 0.2 m 3  h -1 , a swirl circulation was formed in the reactor, which created a dissolved oxygen (DO) gradient with a low DO zone in the center and a high DO zone in the periphery for denitrification and nitrification. 81% of total nitrogen was removed by this reactor, in which ammonium was reduced by over 90%. However, denitrification was less effective because of the presence of low levels of oxygen. The progressively decreasing temperature favored acclimation of psychrophilic bacteria in the reactor, which replaced mesophilic bacteria in the process of treatment.

  15. Instability of a shear layer between multicomponent fluids at supercritical pressure

    NASA Astrophysics Data System (ADS)

    Fu, Qing-fei; Zhang, Yun-xiao; Mo, Chao-jie; Yang, Li-jun

    2018-04-01

    The temporal instability of a thin shear layer lying between streams of two components of fluids has been studied. The effects of density profile of the layer on the instability behavior were mainly considered. The detailed density profile was obtained through Linear Gradient Theory. The eigenvalue problem was calculated, and the temporal instability curves were obtained for the thermodynamic parameters, e.g. pressure and temperature. The results show that, increase of pressure leads to the increase of the maximum growth rate. However, increasing pressure has opposite effects on the disturbances with small and large wave length. The increase of temperature causes the decrease of disturbance growth rate. The instability behavior of the shear layers was determined mainly by the interval between the inflections of the velocity and density profiles, and the maximum density gradient. The total effects, determined by coupling density stratification, and interval between the inflections of the velocity and density profiles, were quite distinct for different ranges of temperature and pressure.

  16. Computer program determines gas flow rates in piping systems

    NASA Technical Reports Server (NTRS)

    Franke, R.

    1966-01-01

    Computer program calculates the steady state flow characteristics of an ideal compressible gas in a complex piping system. The program calculates the stagnation and total temperature, static and total pressure, loss factor, and forces on each element in the piping system.

  17. Comparison of two total energy systems for a diesel power generation plant. [deep space network

    NASA Technical Reports Server (NTRS)

    Chai, V. W.

    1979-01-01

    The capabilities and limitations, as well as the associated costs for two total energy systems for a diesel power generation plant are compared. Both systems utilize waste heat from engine cooling water and waste heat from exhaust gases. Pressurized water heat recovery system is simple in nature and requires no engine modifications, but operates at lower temperature ranges. On the other hand, a two-phase ebullient system operates the engine at constant temperature, provides higher temperature water or steam to the load, but is more expensive.

  18. Hydro-isomerization of n-hexane on bi-functional catalyst: Effect of total and hydrogen partial pressures

    NASA Astrophysics Data System (ADS)

    Thoa, Dao Thi Kim; Loc, Luu Cam

    2017-09-01

    The effect of both total pressure and hydrogen partial pressure during n-hexane hydro-isomerization over platinum impregnated on HZSM-5 was studied. n-Hexane hydro-isomerization was conducted at atmospheric pressure and 0.7 MPa to observe the influence of total pressure. In order to see the effect of hydrogen partial pressure, the reaction was taken place at different partial pressure of hydrogen varied from 307 hPa to 718 hPa by dilution with nitrogen to keep the total pressure at 0.1 MPa. Physico-chemical characteristics of catalyst were determined by the methods of nitrogen physi-sorption BET, SEM, XRD, TEM, NH3-TPD, TPR, and Hydrogen Pulse Chemi-sorption. Activity of catalyst in the hydro-isomerization of n-hexane was studied in a micro-flow reactor in the temperature range of 225-325 °C; the molar ratio H2/ hydrocarbon: 5.92, concentration of n-hexane: 9.2 mol.%, GHSV 2698 h-1. The obtained catalyst expressed high acid density, good reducing property, high metal dispersion, and good balance between metallic and acidic sites. It is excellent contact for n-hexane hydro-isomerization. At 250 °C, n-hexane conversion and selectivity were as high as 59-76 % and 85-99 %, respectively. It was found that catalytic activity was promoted either by total pressure or hydrogen partial pressure. At total pressure of 0.7 MPa while hydrogen partial pressure of 718 hPa, catalyst produced 63 RON liquid product containing friendly environmental iso-paraffins which is superior blending stock for green gasoline. Hydrogen did not only preserve catalyst actives by depressing hydrocracking and removing coke precursors but also facilitated hydride transfer step in the bi-functional bi-molecular mechanism.

  19. Performance of chromia- and alumina-forming Fe- and Ni-base alloys exposed to metal dusting environments: The effect of water vapor and temperature

    DOE PAGES

    Rouaix-Vande Put, Aurelie; Unocic, Kinga A.; Brady, Michael P.; ...

    2015-11-18

    Fe- and Ni-base alloys including an alumina-forming austenitic alloy were exposed for 500 h under metal dusting environments with varying temperature, gas composition and total pressure. For one H 2–CO–CO 2–H 2O environment, the increase in temperature from 550 to 750 °C generally decreased metal dusting. When H 2O was added to a H 2–CO–CO 2 environment at 650 °C, the metal dusting attack was reduced. Even after 5000 h at a total pressure of 9.1 atm with 20%H 2O, the higher alloyed specimens retained a thin protective oxide. Lastly, for gas mixtures containing little or no H 2O, themore » Fe-base alloys were less resistant to metal dusting than Ni-base alloys.« less

  20. Altitude-Wind-Tunnel Investigation of R-4360-18 Power-Plant Installation for XR60 Airplane. 3; Performance of Induction and Exhaust Systems

    NASA Technical Reports Server (NTRS)

    Dupree, David T.; Hawkins, W. Kent

    1947-01-01

    A study has been made of the performance of the induction and the exhaust systems on the XR60 power-plant installation as part of an investigation conducted in the Cleveland altitude wind tunnel. Altitude flight conditions from 5000 to 30,000 feet were simulated for a range of engine powers from 750 to 3000 brake horsepower. Slipstream rotation prevented normal pressure recoveries in the right side of the main duct in the region of the right intercooler cooling-air duct inlet. Total-pressure losses in the charge-air flow between the turbosupercharger and the intercoolers were as high as 2.1 inches of mercury. The total-pressure distribution of the charge air at the intercooler inlets was irregular and varied as much as 1.0 inch of mercury from the average value at extreme conditions, Total-pressure surveys at the carburetor top deck showed a variation from the average value of 0.3 inch of mercury at take-off power and 0.05 inch of mercury at maximum cruising power, The carburetor preheater system increased the temperature of the engine charge air a maximum of about 82 F at an average cowl-inlet air temperature of 9 F, a pressure altitude of 5000 feet, and a brake horsepower of 1240.

  1. Hydrothermal ore-forming processes in the light of studies in rock- buffered systems: I. Iron-copper-zinc-lead sulfide solubility relations

    USGS Publications Warehouse

    Hemley, J.J.; Cygan, G.L.; Fein, J.B.; Robinson, G.R.; d'Angelo, W. M.

    1992-01-01

    Experimental studies, using cold-seal and extraction vessel techniques, were conducted on Fe, Pb, Zn, and Cu sulfide solubilities in chloride soultions at temperatures from 300?? to 700??C and pressures from 0.5 to 2 kbars. The solutions were buffered in pH by quartz monzonite and the pure potassium feldspar-muscovite-quartz assemblage and in fS2-fO2 largely by the assemblage pyrite-pyrrhotite-magnetite. Solubilities increase with increasing temperature and total chloride, and decrease with increasing pressure. The effect of increasing chloride concentration on solubility reflects primarily a shift to lower pH via the silicate buffer reactions. Similarity in behaviour with respect to the temperature and pressure of Fe, Zn, and Pb sulfide solubilities points to similarity in chloride speciation, and the neutral species appear to be dominant in the high-temperature region. -from Authors

  2. Measurement and Empirical Correlation of Transpiration-Cooling Parameters on a 25 degree Cone in a Turbulent Boundary Layer in Both Free Flight and a Hot-Gas Jet

    NASA Technical Reports Server (NTRS)

    Walton, Thomas E., Jr.; Rashis, Bernard

    1961-01-01

    Transpiration-cooling parameters are presented for a turbulent boundary layer on a cone configuration with a total angle of 250 which was tested in both free flight and in an ethylene-heated high-temperature jet at a Mach number of 2.0. The flight-tested cone was flown to a maximum Mach number of 4.08 and the jet tests were conducted at stagnation temperatures ranging from 937 R to 1,850 R. In general, the experimental heat transfer was in good agreement with the theoretical values. Inclusion of the ratio of local stream temperature to wall temperature in the nondimensional flow rate parameter enabled good correlation of both sets of transpiration data. The measured pressure at the forward station coincided with the theoretical pressure over a sharp cone; however, the measured pressure increased with distance from the nose tip.

  3. Vapor pressures and calculated heats of vaporization of concentrated nitric acid solutions in the composition range 71 to 89 percent nitrogen dioxide, 1 to 10 percent water, and in the temperature range 10 to 60 degrees C

    NASA Technical Reports Server (NTRS)

    Mckeown, A B; Belles, Frank E

    1954-01-01

    Total vapor pressures were measured for 16 acid mixtures of the ternary system nitric acid, nitrogen dioxide, and water within the temperature range 10 degrees to 60 degrees Celsius, and with the composition range 71 to 89 weight percent nitric acid, 7 to 20 weight percent nitrogen dioxide, and 1 to 10 weight percent water. Heats of vaporization were calculated from the vapor pressure measurements for each sample for the temperatures 25, 40, and 60 degrees Celsius. The ullage of the apparatus used for the measurements was 0.46. Ternary diagrams showing isobars as a function of composition of the system were constructed from experimental and interpolated data for the temperatures 25, 40, 45, and 60 degrees C and are presented herein.

  4. A large volume 2000 MPA air source for the radiatively driven hypersonic wind tunnel

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Constantino, M

    1999-07-14

    An ultra-high pressure air source for a hypersonic wind tunnel for fluid dynamics and combustion physics and chemistry research and development must provide a 10 kg/s pure air flow for more than 1 s at a specific enthalpy of more than 3000 kJ/kg. The nominal operating pressure and temperature condition for the air source is 2000 MPa and 900 K. A radial array of variable radial support intensifiers connected to an axial manifold provides an arbitrarily large total high pressure volume. This configuration also provides solutions to cross bore stress concentrations and the decrease in material strength with temperature. [hypersonic,more » high pressure, air, wind tunnel, ground testing]« less

  5. The Global Historical Climatology Network: Long-Term Monthly Temperature, Precipitation, Sea Level Pressure, and Station Pressure Data (NDP-041)

    DOE Data Explorer

    Vose, Russell S. [Carbon Dioxide Information Analysis Center (CDIAC),; Schmoyer, Richard L.; Steurer, Peter M. [National Oceanic and Atmospheric Administration (NOAA), National Climatic Data Center, Asheville, NC (USA); Peterson, Thomas C. [National Oceanic and Atmospheric Administration (NOAA), National Climatic Data Center, Asheville, NC (USA); Heim, Richard [National Oceanic and Atmospheric Administration (NOAA), National Climatic Data Center, Asheville, NC (USA); Karl, Thomas R. [National Oceanic and Atmospheric Administration (NOAA), National Climatic Data Center, Asheville, NC (USA); Eischeid, Jon K. [Cooperative Institute for Research in Environmental Sciences, Boulder, CO (USA)

    1992-01-01

    The GHCN data base contains mean monthly temperature data (in tenths of degrees celsius) for 6039 stations throughout the world. The majority (61%) have records for fewer than 50 years, but a significant proportion (10%) have records in excess of 100 years. It also contains total monthly precipitation data (in tenths of millimeters) for 7533 stations throughout the world. A slight majority (55%) have records in excess of 50 years, and a significant proportion (13%) have records in excess of 100 years. Also in this content is mean monthly sea level pressure data (in tenths of millibars) for 1883 stations throughout the world. The monthly station pressure data from those stations is also available here.

  6. 40 CFR Table 8 to Subpart Jjj of... - Operating Parameters for Which Levels Are Required To Be Established for Continuous and Batch...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... temperature. Carbon adsorber Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15...

  7. 40 CFR Table 8 to Subpart Jjj of... - Operating Parameters for Which Levels Are Required To Be Established for Continuous and Batch...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... temperature. Carbon adsorber Total regeneration steam flow or nitrogen flow, or pressure (gauge or absolute) a during carbon bed regeneration cycle; and temperature of the carbon bed after regeneration (and within 15...

  8. Influence of Pressure on Physical Property of Ammonia Borane and its Re-hydrogenation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chen, Jiuhua

    The project systematically studied the high pressure behavior of ammonia borane and its derivative lithium amidoborane. Phase transitions in these materials are investigated in the pressure range up to 20 GPa and temperature range from 80 K to 400K. A number of new phase transitions are discovered in this pressure and temperature range including a second order transformation at 5 GPa and a first order transformation at 12 GPa at room temperature, and four new transitions at high pressure and low temperatures. The Clapeyron slopes for both pressure-induce tetragonal (I4mm) phase to orthorhombic (Cmc21) phase and temperature-induce tetragonal (I4mm) phasemore » to orthorhombic (Pmn21) phase are determined to be positive, indicating these phase transitions are exothermic. This result demonstrates that the high pressure orthorhombic phase of ammonia borane has lower enthalpy than that of tetragonal phase at ambient conditions. If we assume decomposition from the orthorhombic phase yields the same products as that from the tetragonal phase, the decomposition of the orthorhombic phase will be less exothermic. Therefore rehydrogenation from the decomposed product into the orthorhombic phase at high pressure may become easier. The project also studied the influences of nanoconfinement on the phase transitions. Comparative study using Raman spectroscopy indicates that the temperature induced I4mm to Pmn21 transition is suppressed from 217 K to 195 K when the sample is confined in SBA15 (7-9 nm pore size). When the pore size is reduced from 7-9 nm to 3-4 nm, this transition is totally suppressed in the temperature down to 80 K. A similar influence of the nanoconfiement on pressure induced phase transitions is also observed using Raman spectroscopy. The phase boundary between the I4mm phase and high pressure Cmc21 phase at ambient temperature shifts from 0.9 GPa to 0.5 GPa; and that between the Cmc21 phase and higher pressure P21 phase shifts from 10.2 GPa to 9.7 GPa.« less

  9. Saturation curve of SiO{sub 2} component in rutile-type GeO{sub 2}: A recoverable high-temperature pressure standard from 3 GPa to 10 GPa

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Leinenweber, Kurt, E-mail: kurtl@asu.edu; Gullikson, Amber L.; Stoyanov, Emil

    2015-09-15

    The accuracy and precision of pressure measurements and the pursuit of reliable and readily available pressure scales at simultaneous high temperatures and pressures are still topics in development in high pressure research despite many years of work. In situ pressure scales based on x-ray diffraction are widely used but require x-ray access, which is lacking outside of x-ray beam lines. Other methods such as fixed points require several experiments to bracket a pressure calibration point. In this study, a recoverable high-temperature pressure gauge for pressures ranging from 3 GPa to 10 GPa is presented. The gauge is based on themore » pressure-dependent solubility of an SiO{sub 2} component in the rutile-structured phase of GeO{sub 2} (argutite), and is valid when the argutite solid solution coexists with coesite. The solid solution varies strongly in composition, mainly in pressure but also somewhat in temperature, and the compositional variations are easily detected by x-ray diffraction of the recovered products because of significant changes in the lattice parameters. The solid solution is measured here on two isotherms, one at 1200 °C and the other at 1500 °C, and is developed as a pressure gauge by calibrating it against three fixed points for each temperature and against the lattice parameter of MgO measured in situ at a total of three additional points. A somewhat detailed thermodynamic analysis is then presented that allows the pressure gauge to be used at other temperatures. This provides a way to accurately and reproducibly evaluate the pressure in high pressure experiments and applications in this pressure-temperature range, and could potentially be used as a benchmark to compare various other pressure scales under high temperature conditions. - Graphical abstract: The saturation curve of SiO{sub 2} in TiO{sub 2} shows a strong pressure dependence and a strong dependence of unit cell volume on composition. This provides an opportunity to use this saturation curve as a measurement of pressure during a high-pressure experiment. The curve is a sensitive measure of pressure from 3 GPa to 10 GPa at high temperatures. The pressure is derived from lattice parameter measurements on the recovered solid solution, meaning that in-situ measurements are not necessary to evaluate the pressure of the experiment. - Highlights: • The unit cell of a saturated GeO{sub 2}–SiO{sub 2} solid solution is used as a pressure sensor. • We measure nine bracketed pressure points on the GeO{sub 2}–SiO{sub 2} saturation surface. • We provide a pressure calibrant from 3 GPa to 10 GPa at two temperatures. • Four points are measured at 1200 °C and five points at 1500 °C. • A thermodynamic model is developed for use of the calibrant at other temperatures.« less

  10. Novel monorail infusion catheter for volumetric coronary blood flow measurement in humans: in vitro validation.

    PubMed

    van 't Veer, Marcel; Adjedj, Julien; Wijnbergen, Inge; Tóth, Gabor G; Rutten, Marcel C M; Barbato, Emanuele; van Nunen, Lokien X; Pijls, Nico H J; De Bruyne, Bernard

    2016-08-20

    The aim of this study is to validate a novel monorail infusion catheter for thermodilution-based quantitative coronary flow measurements. Based on the principles of thermodilution, volumetric coronary flow can be determined from the flow rate of a continuous saline infusion, the temperature of saline when it enters the coronary artery, and the temperature of the blood mixed with the saline in the distal part of the coronary artery. In an in vitro set-up of the systemic and coronary circulation at body temperature, coronary flow values were varied from 50-300 ml/min in steps of 50 ml/min. At each coronary flow value, thermodilution-based measurements were performed at infusion rates of 15, 20, and 30 ml/min. Temperatures and pressures were simultaneously measured with a pressure/temperature sensor-tipped guidewire. Agreement of the calculated flow and the measured flow as well as repeatability were assessed. A total of five catheters were tested, with a total of 180 measurements. A strong correlation (ρ=0.976, p<0.0001) and a difference of -6.5±15.5 ml/min were found between measured and calculated flow. The difference between two repeated measures was 0.2%±8.0%. This novel infusion catheter used in combination with a pressure/temperature sensor-tipped guidewire allows accurate and repeatable absolute coronary flow measurements. This opens a window to a better understanding of the coronary microcirculation.

  11. Performance of a high-work, low-aspect-ratio turbine stator tested with a realistic inlet radial temperature gradient

    NASA Technical Reports Server (NTRS)

    Stabe, Roy G.; Schwab, John R.

    1991-01-01

    A 0.767-scale model of a turbine stator designed for the core of a high-bypass-ratio aircraft engine was tested with uniform inlet conditions and with an inlet radial temperature profile simulating engine conditions. The principal measurements were radial and circumferential surveys of stator-exit total temperature, total pressure, and flow angle. The stator-exit flow field was also computed by using a three-dimensional Navier-Stokes solver. Other than temperature, there were no apparent differences in performance due to the inlet conditions. The computed results compared quite well with the experimental results.

  12. High temperature- and high pressure-processed garlic improves lipid profiles in rats fed high cholesterol diets.

    PubMed

    Sohn, Chan Wok; Kim, Hyunae; You, Bo Ram; Kim, Min Jee; Kim, Hyo Jin; Lee, Ji Yeon; Sok, Dai-Eun; Kim, Jin Hee; Lee, Kun Jong; Kim, Mee Ree

    2012-05-01

    Garlic protects against degenerative diseases such as hyperlipidemia and cardiovascular diseases. However, raw garlic has a strong pungency, which is unpleasant. In this study, we examined the effect of high temperature/high pressure-processed garlic on plasma lipid profiles in rats. Sprague-Dawley rats were fed a normal control diet, a high cholesterol (0.5% cholesterol) diet (HCD) only, or a high cholesterol diet supplemented with 0.5% high temperature/high pressure-processed garlic (HCP) or raw garlic (HCR) for 10 weeks. The body weights of the rats fed the garlic-supplemented diets decreased, mostly because of reduced fat pad weights. Plasma levels of total cholesterol (TC), low-density lipoprotein cholesterol, and triglyceride (TG) in the HCP and HCR groups decreased significantly compared with those in the HCD group. Additionally, fecal TC and TG increased significantly in the HCP and HCR groups. It is notable that no significant differences in plasma or fecal lipid profiles were observed between the HCP and HCR groups. High temperature/high pressure-processed garlic contained a higher amount of S-allyl cysteine than raw garlic (P<.05). The results suggest that high temperature/high pressure-processed garlic may be useful as a functional food to improve lipid profiles.

  13. High Temperature- and High Pressure-Processed Garlic Improves Lipid Profiles in Rats Fed High Cholesterol Diets

    PubMed Central

    Sohn, Chan Wok; Kim, Hyunae; You, Bo Ram; Kim, Min Jee; Kim, Hyo Jin; Lee, Ji Yeon; Sok, Dai-Eun; Kim, Jin Hee; Lee, Kun Jong

    2012-01-01

    Abstract Garlic protects against degenerative diseases such as hyperlipidemia and cardiovascular diseases. However, raw garlic has a strong pungency, which is unpleasant. In this study, we examined the effect of high temperature/high pressure-processed garlic on plasma lipid profiles in rats. Sprague–Dawley rats were fed a normal control diet, a high cholesterol (0.5% cholesterol) diet (HCD) only, or a high cholesterol diet supplemented with 0.5% high temperature/high pressure-processed garlic (HCP) or raw garlic (HCR) for 10 weeks. The body weights of the rats fed the garlic-supplemented diets decreased, mostly because of reduced fat pad weights. Plasma levels of total cholesterol (TC), low-density lipoprotein cholesterol, and triglyceride (TG) in the HCP and HCR groups decreased significantly compared with those in the HCD group. Additionally, fecal TC and TG increased significantly in the HCP and HCR groups. It is notable that no significant differences in plasma or fecal lipid profiles were observed between the HCP and HCR groups. High temperature/high pressure-processed garlic contained a higher amount of S-allyl cysteine than raw garlic (P<.05). The results suggest that high temperature/high pressure-processed garlic may be useful as a functional food to improve lipid profiles. PMID:22404600

  14. 21 CFR 177.1620 - Polyethylene, oxidized.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... temperature vapor pressure osmometry, contains a maximum of 5 percent by weight of total oxygen, and has an acid value of 9 to 19. (b) The finished food-contact article, when extracted with the solvent or solvents characterizing the type of food and under the conditions of time and temperature characterizing...

  15. Experimental study of catalytic hydrogenation by using an in-situ hydrogen measuring technique. Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chiang, S.H.; Klinzing, G.E.; Cheng, Y.S.

    1984-12-01

    An in-situ technique for measuring hydrogen concentration (partial pressure) had been previously used to measure static properties (hydrogen solubilities, vapor pressures of hydrocarbons, etc.). Because of its good precision (2% relative error) and relatively short respond time (9.7 to 2.0 seconds at 589 to 728K), the technique was successfully applied to a dynamic study of hydrogenation reactions in this work. Furthermore, the technique is to be tested for industrial uses. Hydrogen/1-methylnaphthalene system was experimentally investigated in a one-liter autoclave equipped with a magnetically driven stirrer and temperature controlling devices. Catalytic hydrogenation of 1-methylnaphthalene was studied in the presence of sulfidedmore » Co-Mo-Al2O3 catalyst. In addition, the vapor/liquid equilibrium relationship was determined by using this technique. Hydrogenation reaction runs were performed at temperatures of 644.1, 658.0 and 672.0K and pressures up to 9.0 MPa. The ring hydrogenation, resulting in 1- and 5-methyltetralin, was found to be the dominant reaction. This is in agreement with cited literature. Effects of hydrogen partial pressure, operating temperature, as well as presulfided catalyst are also investigated and discussed in this work. The vapor pressure of 1-methylnaphthalene was measured over a temperature range of 555.2 to 672.0K. The results are in good agreement with literature data. Measurements for hydrogen solubility in 1-methylnaphthalene were conducted over temperature and pressure range of 598 to 670K and 5.2 to 8.8 MPa, respectively. Similar to previously reported results, the hydrogen solubility increases with increasing temperature when total pressure is held constant. A linear relation is found between the hydrogen solubility and hydrogen partial pressure. 21 refs., 13 figs., 10 tabs.« less

  16. Microsecond simulations of the folding/unfolding thermodynamics of the Trp-cage mini protein

    PubMed Central

    Day, Ryan; Paschek, Dietmar; Garcia, Angel E.

    2012-01-01

    We study the unbiased folding/unfolding thermodynamics of the Trp-cage miniprotein using detailed molecular dynamics simulations of an all-atom model of the protein in explicit solvent, using the Amberff99SB force field. Replica-exchange molecular dynamics (REMD) simulations are used to sample the protein ensembles over a broad range of temperatures covering the folded and unfolded states, and at two densities. The obtained ensembles are shown to reach equilibrium in the 1 μs per replica timescale. The total simulation time employed in the calculations exceeds 100 μs. Ensemble averages of the fraction folded, pressure, and energy differences between the folded and unfolded states as a function of temperature are used to model the free energy of the folding transition, ΔG(P,T), over the whole region of temperature and pressures sampled in the simulations. The ΔG(P,T) diagram describes an ellipse over the range of temperatures and pressures sampled, predicting that the system can undergo pressure induced unfolding and cold denaturation at low temperatures and high pressures, and unfolding at low pressures and high temperatures. The calculated free energy function exhibits remarkably good agreement with the experimental folding transition temperature (Tf = 321 K), free energy and specific heat changes. However, changes in enthalpy and entropy are significantly different than the experimental values. We speculate that these differences may be due to the simplicity of the semi-empirical force field used in the simulations and that more elaborate force fields may be required to describe appropriately the thermodynamics of proteins. PMID:20408169

  17. Frictional heating processes during laboratory earthquakes

    NASA Astrophysics Data System (ADS)

    Aubry, J.; Passelegue, F. X.; Deldicque, D.; Lahfid, A.; Girault, F.; Pinquier, Y.; Escartin, J.; Schubnel, A.

    2017-12-01

    Frictional heating during seismic slip plays a crucial role in the dynamic of earthquakes because it controls fault weakening. This study proposes (i) to image frictional heating combining an in-situ carbon thermometer and Raman microspectrometric mapping, (ii) to combine these observations with fault surface roughness and heat production, (iii) to estimate the mechanical energy dissipated during laboratory earthquakes. Laboratory earthquakes were performed in a triaxial oil loading press, at 45, 90 and 180 MPa of confining pressure by using saw-cut samples of Westerly granite. Initial topography of the fault surface was +/- 30 microns. We use a carbon layer as a local temperature tracer on the fault plane and a type K thermocouple to measure temperature approximately 6mm away from the fault surface. The thermocouple measures the bulk temperature of the fault plane while the in-situ carbon thermometer images the temperature production heterogeneity at the micro-scale. Raman microspectrometry on amorphous carbon patch allowed mapping the temperature heterogeneities on the fault surface after sliding overlaid over a few micrometers to the final fault roughness. The maximum temperature achieved during laboratory earthquakes remains high for all experiments but generally increases with the confining pressure. In addition, the melted surface of fault during seismic slip increases drastically with confining pressure. While melting is systematically observed, the strength drop increases with confining pressure. These results suggest that the dynamic friction coefficient is a function of the area of the fault melted during stick-slip. Using the thermocouple, we inverted the heat dissipated during each event. We show that for rough faults under low confining pressure, less than 20% of the total mechanical work is dissipated into heat. The ratio of frictional heating vs. total mechanical work decreases with cumulated slip (i.e. number of events), and decreases with increasing confining pressure and normal stress. Our results suggest that earthquakes are less dispersive under large normal stress. We linked this observation with fault roughness heterogeneity, which also decreases with applied normal stress. Keywords: Frictional heating, stick-slip, carbon, dynamic rupture, fault weakening.

  18. Effect of chemical composition on the electrical conductivity of gneiss at high temperatures and pressures

    NASA Astrophysics Data System (ADS)

    Dai, Lidong; Sun, Wenqing; Li, Heping; Hu, Haiying; Wu, Lei; Jiang, Jianjun

    2018-03-01

    The electrical conductivity of gneiss samples with different chemical compositions (WA = Na2O + K2O + CaO = 7.12, 7.27 and 7.64 % weight percent) was measured using a complex impedance spectroscopic technique at 623-1073 K and 1.5 GPa and a frequency range of 10-1 to 106 Hz. Simultaneously, a pressure effect on the electrical conductivity was also determined for the WA = 7.12 % gneiss. The results indicated that the gneiss conductivities markedly increase with total alkali and calcium ion content. The sample conductivity and temperature conform to an Arrhenius relationship within a certain temperature range. The influence of pressure on gneiss conductivity is weaker than temperature, although conductivity still increases with pressure. According to various ranges of activation enthalpy (0.35-0.52 and 0.76-0.87 eV) at 1.5 GPa, two main conduction mechanisms are suggested that dominate the electrical conductivity of gneiss: impurity conduction in the lower-temperature region and ionic conduction (charge carriers are K+, Na+ and Ca2+) in the higher-temperature region. The electrical conductivity of gneiss with various chemical compositions cannot be used to interpret the high conductivity anomalies in the Dabie-Sulu ultrahigh-pressure metamorphic belt. However, the conductivity-depth profiles for gneiss may provide an important constraint on the interpretation of field magnetotelluric conductivity results in the regional metamorphic belt.

  19. Pressure effect on magnetic susceptibility of LaCoO3

    NASA Astrophysics Data System (ADS)

    Panfilov, A. S.; Grechnev, G. E.; Zhuravleva, I. P.; Lyogenkaya, A. A.; Pashchenko, V. A.; Savenko, B. N.; Novoselov, D.; Prabhakaran, D.; Troyanchuk, I. O.

    2018-04-01

    The effect of pressure on magnetic properties of LaCoO3 is studied experimentally and theoretically. The pressure dependence of magnetic susceptibility χ of LaCoO3 is obtained by precise measurements of χ as a function of the hydrostatic pressure P up to 2 kbar in the temperature range from 78 K to 300 K. A pronounced magnitude of the pressure effect is found to be negative in sign and strongly temperature dependent. The obtained experimental data are analysed by using a two-level model and DFT+U calculations of the electronic structure of LaCoO3. In particular, the fixed spin moment method was employed to obtain a volume dependence of the total energy difference Δ between the low spin and the intermediate spin states of LaCoO3. Analysis of the obtained experimental χ(P) dependence within the two-level model, as well as our DFT+U calculations, have revealed the anomalous large decrease in the energy difference Δ with increasing of the unit cell volume. This effect, taking into account a thermal expansion, can be responsible for the temperatures dependence of Δ, predicting its vanishing near room temperature.

  20. Thermal/Pyrolysis Gas Flow Analysis of Carbon Phenolic Material

    NASA Technical Reports Server (NTRS)

    Clayton, J. Louie

    2001-01-01

    Provided in this study are predicted in-depth temperature and pyrolysis gas pressure distributions for carbon phenolic materials that are externally heated with a laser source. Governing equations, numerical techniques and comparisons to measured temperature data are also presented. Surface thermochemical conditions were determined using the Aerotherm Chemical Equilibrium (ACE) program. Surface heating simulation used facility calibrated radiative and convective flux levels. Temperatures and pyrolysis gas pressures are predicted using an upgraded form of the SINDA/CMA program that was developed by NASA during the Solid Propulsion Integrity Program (SPIP). Multispecie mass balance, tracking of condensable vapors, high heat rate kinetics, real gas compressibility and reduced mixture viscosity's have been added to the algorithm. In general, surface and in-depth temperature comparisons are very good. Specie partial pressures calculations show that a saturated water-vapor mixture is the main contributor to peak in-depth total pressure. Further, for most of the cases studied, the water-vapor mixture is driven near the critical point and is believed to significantly increase the local heat capacity of the composite material. This phenomenon if not accounted for in analysis models may lead to an over prediction in temperature response in charring regions of the material.

  1. Computer Programs for Calculating the Isentropic Flow Properties for Mixtures of R-134a and Air

    NASA Technical Reports Server (NTRS)

    Kvaternik, Raymond G.

    2000-01-01

    Three computer programs for calculating the isentropic flow properties of R-134a/air mixtures which were developed in support of the heavy gas conversion of the Langley Transonic Dynamics Tunnel (TDT) from dichlorodifluoromethane (R-12) to 1,1,1,2 tetrafluoroethane (R-134a) are described. The first program calculates the Mach number and the corresponding flow properties when the total temperature, total pressure, static pressure, and mole fraction of R-134a in the mixture are given. The second program calculates tables of isentropic flow properties for a specified set of free-stream Mach numbers given the total pressure, total temperature, and mole fraction of R-134a. Real-gas effects are accounted for in these programs by treating the gases comprising the mixture as both thermally and calorically imperfect. The third program is a specialized version of the first program in which the gases are thermally perfect. It was written to provide a simpler computational alternative to the first program in those cases where real-gas effects are not important. The theory and computational procedures underlying the programs are summarized, the equations used to compute the flow quantities of interest are given, and sample calculated results that encompass the operating conditions of the TDT are shown.

  2. Mass Spectrometric Identification of Si-O-H(g) Species from the Reaction of Silica with Water Vapor at Atmospheric Pressure

    NASA Technical Reports Server (NTRS)

    Opila, Elizabeth J.; Fox, Dennis S.; Jacobson, Nathan S.

    1997-01-01

    A high-pressure sampling mass spectrometer was used to detect the volatile species formed from SiO2 at temperatures between 1200C and 1400C in a flowing water vapor/oxygen gas mixture at 1 bar total pressure. The primary vapor species identified was Si(OH)4. The fragment ion Si(OH)3+,' was observed in quantities 3 to 5 times larger than the parent ion Si(OH)4+. The Si(OH)3+ intensity was found to have a small temperature dependence and to increase with the water vapor partial pressure as expected. In addition, SiO(OH)+ believed to be a fragment of SiO(OH)2, was observed. These mass spectral results were compared to the behavior of silicon halides.

  3. Solubility of single gases carbon dioxide and hydrogen sulfide in aqueous solutions of N-methyldiethanolamine in the temperature range 313--413 K at pressures up to 5 MPa

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuranov, G.; Smirnova, N.A.; Rumpf, B.

    1996-06-01

    Experimental results for the solubility of the single gases carbon dioxide and hydrogen sulfide in aqueous solutions of 2,2{prime}-methyliminodiethanol (N-methyldiethanolamine (MDEA)) at temperatures between 313 and 413 K and total pressures up to 5 MPa are reported. A model taking into account chemical reactions as well as physical interactions is used to correlate the new data. The correlation is also used to compare the new experimental data with literature data.

  4. Measurements of the structure and circulation of the stratosphere and mesosphere, 1971-2

    NASA Technical Reports Server (NTRS)

    Smith, W. S.; Theon, J. S.; Wright, D. U., Jr.; Ramsdale, D. J.; Horvath, J. J.

    1974-01-01

    Complete data from a total of 43 meteorological rocket soundings of the stratosphere and mesosphere conducted from Barrow, Alaska; Churchill, Canada; Wallops Island Va.; and Kourou, French Guiana are presented. These data consist of temperature, pressure, density, and wind profiles from 35 acoustic grenade soundings that cover the 30 to 90 km altitude range, and temperature, pressure, and density profiles from 8 pitot probe soundings that cover the 25 to 120 km altitude range. Errors for each of the 35 acoustic grenade soundings are also included.

  5. Elevated-Temperature Tensile-Testing of Foil-Gage Metals

    NASA Technical Reports Server (NTRS)

    Blackburn, L. B.; Ellingsworth, J. R.

    1986-01-01

    Automated system for measuring strain in metal foils at temperatures above 500 degrees F (260 degrees C) uses mechanical extensometer and displacement transducer. System includes counterbalance feature, which eliminates weight contribution of extensometer and reduces grip pressure required for attachment to specimen. Counterbalancing feature overcomes two major difficulties in using extensometers with foil-gage specimens: (1) Weight of extensometer and transducer represents significant fraction of total load applied to specimen and may actually damage it; and (2) grip pressure required for attachment of extensometer to specimens may induce bending stresses in foil-gage materials.

  6. An infiltration/cure model for manufacture of fabric composites by the resin infusion process

    NASA Technical Reports Server (NTRS)

    Weideman, Mark H.; Loos, Alfred C.; Dexter, H. Benson; Hasko, Gregory H.

    1992-01-01

    A 1-D infiltration/cure model was developed to simulate fabrication of advanced textile composites by the resin film infusion process. The simulation model relates the applied temperature and pressure processing cycles, along with the experimentally measured compaction and permeability characteristics of the fabric preforms, to the temperature distribution, the resin degree of cure and viscosity, and the infiltration flow front position as a function of time. The model also predicts the final panel thickness, fiber volume fraction, and resin mass for full saturation as a function of compaction pressure. Composite panels were fabricated using the RTM (Resin Transfer Molding) film infusion technique from knitted, knitted/stitched, and 2-D woven carbon preforms and Hercules 3501-6 resin. Fabric composites were fabricated at different compaction pressures and temperature cycles to determine the effects of the processing on the properties. The composites were C-scanned and micrographed to determine the quality of each panel. Advanced cure cycles, developed from the RTM simulation model, were used to reduce the total cure cycle times by a factor of 3 and the total infiltration times by a factor of 2.

  7. Serpentine Diffuser Performance with Emphasis on Future Introduction to a Transonic Fan (Postprint)

    DTIC Science & Technology

    2013-01-01

    conditioning barrel . The velocity distribution across the flow conditioning barrel was measured at the same axial location of inlet temperature and...rakes at the same axial plane (AIP) of the total pressure probe tips. The probes were constructed from stainless steel tubing with 0.027 inch inside...numbers with 195 axial and circumferential static pressure measurements within the diffuser flow path. Pressure distortion at the diffuser discharge

  8. Autonomic control of body temperature and blood pressure: influences of female sex hormones.

    PubMed

    Charkoudian, Nisha; Hart, Emma C J; Barnes, Jill N; Joyner, Michael J

    2017-06-01

    Female reproductive hormones exert important non-reproductive influences on autonomic regulation of body temperature and blood pressure. Estradiol and progesterone influence thermoregulation both centrally and peripherally, where estradiol tends to promote heat dissipation, and progesterone tends to promote heat conservation and higher body temperatures. Changes in thermoregulation over the course of the menstrual cycle and with hot flashes at menopause are mediated by hormonal influences on neural control of skin blood flow and sweating. The influence of estradiol is to promote vasodilation, which, in the skin, results in greater heat dissipation. In the context of blood pressure regulation, both central and peripheral hormonal influences are important as well. Peripherally, the vasodilator influence of estradiol contributes to the lower blood pressures and smaller risk of hypertension seen in young women compared to young men. This is in part due to a mechanism by which estradiol augments beta-adrenergic receptor mediated vasodilation, offsetting alpha-adrenergic vasoconstriction, and resulting in a weak relationship between muscle sympathetic nerve activity and total peripheral resistance, and between muscle sympathetic nerve activity and blood pressure. After menopause, with the loss of reproductive hormones, sympathetic nerve activity, peripheral resistance and blood pressure become more strongly related, and sympathetic nerve activity (which increases with age) becomes a more important contributor to the prevailing level of blood pressure. Continuing to increase our understanding of sex hormone influences on body temperature and blood pressure regulation will provide important insight for optimization of individualized health care for future generations of women.

  9. Wind tunnel tests of Space Shuttle external tank insulation material in the aerothermal tunnel at elevated (1440 deg F) total temperatures

    NASA Technical Reports Server (NTRS)

    Hartman, A. S.; Nutt, K. W.

    1982-01-01

    Tests of the space shuttle external tank foam insulation were conducted in the von Karman Gas Dynamics Facility Tunnel C. For these tests, Tunnel C was run at Mach 4 with a total temperature of 1440 F and a total pressure which varied from 30-100 psia. Cold wall heating rates were changed by varying the test article support wedge angle and by adding and removing a shock generator or a cylindrical protuberance. Selected results are presented to illustrate the test techniques and typical data obtained.

  10. Variation in skin biology to climate in Shanghai, China.

    PubMed

    Liu, Xiaoping; Gao, Yanrui; Zhang, Yiyi; Wang, Xuemin

    2017-09-01

    To explore the relationship between climate and skin condition, and to investigate the variation of skin biology to climatic change. In total, 2005 healthy Chinese volunteers living in Shanghai (aged 13-69 years) were recruited. Transepidermal water loss (TEWL) and SCH were tested on six sites (forehead, cheek, nasolabial, inner forearm, dorsal hand, and palm) by noninvasive devices between January 2005 and December 2012. The corresponding climate data were recorded by local Weather Bureau. TEWL was increased with atmospheric pressure and decreased with temperature, steam pressure, and relative humidity (p < 0.05). SCH was increased with steam pressure and decreased with atmospheric pressure (p < 0.05); there was no obvious trend between SCH and temperature and SCH and relative humidity. To investigate the climate parameters together, we introduced these correlated factors into the multivariate linear regression model which demonstrated that temperature and steam pressure were main factors related to skin biological parameters. At different sites, the effect of climatic factors on skin biology was diverse. Skin biological parameters are associated with climatic factors. Different sites have different sensitivity to climate factors.

  11. Performance of Metal and Polymeric O-Ring Seals during Beyond-Design-Basis Thermal Conditions.

    PubMed

    Yang, Jiann C; Hnetkovsky, Edward; Rinehart, Doris; Fernandez, Marco; Gonzalez, Felix; Borowsky, Joseph

    2017-04-01

    This paper summarizes the small scale thermal exposure test results of the performance of metallic and polymeric O-ring seals typically used in radioactive material transportation packages. Five different O-ring materials were evaluated: Inconel/silver, ethylene-propylene diene monomer (EPDM), polytetrafluoroethylene (PTFE), silicone, butyl, and Viton. The overall objective of this study is to provide test data and insights to the performance of these Oring seals when exposed to beyond-design-basis temperature conditions due to a severe fire. Tests were conducted using a small-scale stainless steel pressure vessel pressurized with helium to 2 bar or 5 bar at room temperature. The vessel was then heated in an electric furnace to temperatures up to 900 °C for a pre-determined period (typically 8 h to 9 h). The pressure drop technique was used to determine if leakage occurred during thermal exposure. Out of a total of 46 tests performed, leakage (loss of vessel pressure) was detected in 13 tests.

  12. Measurements and Correlations of cis-1,3,3,3-Tetrafluoroprop-1-ene (R1234ze(Z)) Saturation Pressure

    NASA Astrophysics Data System (ADS)

    Fedele, Laura; Di Nicola, Giovanni; Brown, J. Steven; Bobbo, Sergio; Zilio, Claudio

    2014-01-01

    cis-1,3,3,3-Tetrafluoroprop-1-ene (R1234ze(Z)) is being investigated as a working fluid possessing a low global warming potential (GWP) for high-temperature heat pumping applications, organic Rankine cycles, and air-conditioning and refrigeration applications, and as a potential solvent, propellant, and foam blowing agent. Its GWP is less than one. The open literature contains a total of 79 vapor-pressure data from three sources and the critical state properties from a single source. The current paper provides 64 vapor-pressure data from two different laboratories over the temperature range from 238.13 K to 372.61 K. These data are regressed using Wagner and extended Antoine vapor-pressure correlations and then compared to the existing open literature data and correlations. The normal-boiling-point temperature and acentric factor for R1234ze(Z) are estimated to be 282.73 K and 0.3257, respectively.

  13. Performance of Metal and Polymeric O-Ring Seals during Beyond-Design-Basis Thermal Conditions*

    PubMed Central

    Yang, Jiann C.; Hnetkovsky, Edward; Rinehart, Doris; Fernandez, Marco; Gonzalez, Felix; Borowsky, Joseph

    2017-01-01

    This paper summarizes the small scale thermal exposure test results of the performance of metallic and polymeric O-ring seals typically used in radioactive material transportation packages. Five different O-ring materials were evaluated: Inconel/silver, ethylene-propylene diene monomer (EPDM), polytetrafluoroethylene (PTFE), silicone, butyl, and Viton. The overall objective of this study is to provide test data and insights to the performance of these Oring seals when exposed to beyond-design-basis temperature conditions due to a severe fire. Tests were conducted using a small-scale stainless steel pressure vessel pressurized with helium to 2 bar or 5 bar at room temperature. The vessel was then heated in an electric furnace to temperatures up to 900 °C for a pre-determined period (typically 8 h to 9 h). The pressure drop technique was used to determine if leakage occurred during thermal exposure. Out of a total of 46 tests performed, leakage (loss of vessel pressure) was detected in 13 tests. PMID:28503009

  14. The power of vertical geolocation of atmospheric profiles from GNSS radio occultation.

    PubMed

    Scherllin-Pirscher, Barbara; Steiner, Andrea K; Kirchengast, Gottfried; Schwärz, Marc; Leroy, Stephen S

    2017-02-16

    High-resolution measurements from Global Navigation Satellite System (GNSS) radio occultation (RO) provide atmospheric profiles with independent information on altitude and pressure. This unique property is of crucial advantage when analyzing atmospheric characteristics that require joint knowledge of altitude and pressure or other thermodynamic atmospheric variables. Here we introduce and demonstrate the utility of this independent information from RO and discuss the computation, uncertainty, and use of RO atmospheric profiles on isohypsic coordinates-mean sea level altitude and geopotential height-as well as on thermodynamic coordinates (pressure and potential temperature). Using geopotential height as vertical grid, we give information on errors of RO-derived temperature, pressure, and potential temperature profiles and provide an empirical error model which accounts for seasonal and latitudinal variations. The observational uncertainty of individual temperature/pressure/potential temperature profiles is about 0.7 K/0.15%/1.4 K in the tropopause region. It gradually increases into the stratosphere and decreases toward the lower troposphere. This decrease is due to the increasing influence of background information. The total climatological error of mean atmospheric fields is, in general, dominated by the systematic error component. We use sampling error-corrected climatological fields to demonstrate the power of having different and accurate vertical coordinates available. As examples we analyze characteristics of the location of the tropopause for geopotential height, pressure, and potential temperature coordinates as well as seasonal variations of the midlatitude jet stream core. This highlights the broad applicability of RO and the utility of its versatile vertical geolocation for investigating the vertical structure of the troposphere and stratosphere.

  15. Bacterial and Archaeal Communities Variability Associated with Upwelling and Anthropogenic Pressures in the Protection Area of Arraial do Cabo (Cabo Frio region - RJ).

    PubMed

    Coelho-Souza, Sergio A; Araújo, Fábio V; Cury, Juliano C; Jesus, Hugo E; Pereira, Gilberto C; Guimarães, Jean R D; Peixoto, Raquel S; Dávila, Alberto M R; Rosado, Alexandre S

    2015-09-01

    Upwelling systems contain a high diversity of pelagic microorganisms and their composition and activity are defined by factors like temperature and nutrient concentration. Denaturing gradient gel electrophoresis (DGGE) technique was used to verify the spatial and temporal genetic variability of Bacteria and Archaea in two stations of the Arraial do Cabo coastal region, one under upwelling pressure and another under anthropogenic pressure. In addition, biotic and abiotic variables were measured in surface and deep waters from three other stations between these stations. Six samplings were done during a year and adequately represented the degrees of upwelling and anthropogenic pressures to the system. Principal Component Analysis (PCA) showed negative correlations between the concentrations of ammonia and phosphorous with prokaryotic secondary production and the total heterotrophic bacteria. PCA also showed negative correlation between temperature and the abundance of prokaryotic cells. Bacterial and archaeal compositions were changeable as were the oceanographic conditions, and upwelling had a regional pressure while anthropogenic pressure was punctual. We suggest that the measurement of prokaryotic secondary production was associated with both Bacteria and Archaea activities, and that substrate availability and temperature determine nutrients cycling.

  16. Investigation on Active Thermal Control Method with Pool Boiling Heat Transfer at Low Pressure

    NASA Astrophysics Data System (ADS)

    Sun, Chuang; Guo, Dong; Wang, Zhengyu; Sun, Fengxian

    2018-06-01

    In order to maintain a desirable temperature level of electronic equipment at low pressure, the thermal control performance with pool boiling heat transfer of water was examined based on experimental measurement. The total setup was designed and performed to accomplish the experiment with the pressure range from 4.5 kPa to 20 kPa and the heat flux between 6 kW/m2 and 20 kW/m2. The chosen material of the heat surface was aluminium alloy and the test cavity had the capability of varying the direction for the heat surface from vertical to horizontal directions. Through this study, the steady and transient temperature of the heat surface at different pressures and directions were obtained. Although the temperature non-uniformity of the heat surface from the centre to the edge could reach 10°C for the aluminium alloy due to the varying pressures, the whole temperature results successfully satisfied with the thermal control requirements for electronic equipment, and the temperature control effect of the vertically oriented direction was better than that of the horizontally oriented direction. Moreover, the behaviour of bubbles generating and detaching from the heat surface was recorded by a high-resolution camera, so as to understand the pool boiling heat transfer mechanism at low-load heat flux. These pictures showed that the bubbles departure diameter becomes larger, and departure frequency was slower at low pressure, in contrast to 1.0 atm.

  17. USGS Coal Desorption Equipment and a Spreadsheet for Analysis of Lost and Total Gas from Canister Desorption Measurements

    USGS Publications Warehouse

    Barker, Charles E.; Dallegge, Todd A.; Clark, Arthur C.

    2002-01-01

    We have updated a simple polyvinyl chloride plastic canister design by adding internal headspace temperature measurement, and redesigned it so it is made with mostly off-the-shelf components for ease of construction. Using self-closing quick connects, this basic canister is mated to a zero-head manometer to make a simple coalbed methane desorption system that is easily transported in small aircraft to remote localities. This equipment is used to gather timed measurements of pressure, volume and temperature data that are corrected to standard pressure and temperature (STP) and graphically analyzed using an Excel(tm)-based spreadsheet. Used together these elements form an effective, practical canister desorption method.

  18. In-flight boundary-layer measurements on a hollow cylinder at a Mach number of 3.0

    NASA Technical Reports Server (NTRS)

    Quinn, R. D.; Gong, L.

    1980-01-01

    Skin temperatures, shear forces, surface static pressures, boundary layer pitot pressures, and boundary layer total temperatures were measured on the external surface of a hollow cylinder that was 3.04 meters long and 0.437 meter in diameter and was mounted beneath the fuselage of the YF-12A airplane. The data were obtained at a nominal free stream Mach number of 3.0 (a local Mach number of 2.9) and at wall to recovery temperature ratios of 0.66 to 0.91. The local Reynolds number had a nominal value of 4,300,000 per meter. Heat transfer coefficients and skin friction coefficients were derived from skin temperature time histories and shear force measurements, respectively. In addition, boundary layer velocity profiles were derived from pitot pressure measurements, and a Reynolds analogy factor was obtained from the heat transfer and skin friction measurements. The measured data are compared with several boundary layer prediction methods.

  19. Terminal energy distribution of blast waves from bursting spheres

    NASA Technical Reports Server (NTRS)

    Adamczyk, A. A.; Strehlow, R. A.

    1977-01-01

    The calculation results for the total energy delivered to the surroundings by the burst of an idealized massless sphere containing an ideal gas are presented. The logic development of various formulas for sphere energy is also presented. For all types of sphere bursts the fraction of the total initial energy available in the sphere that is delivered to the surroundings is shown to lie between that delivered for the constant pressure addition of energy to a source region and that delivered by isentropic expansion of the sphere. The relative value of E sub/Q increases at fixed sphere pressure/surrounding pressure as sphere temperature increases because the velocity of sound increases.

  20. Radial and circumferential flow surveys at the inlet and exit of the Space Shuttle Main Engine High Pressure Fuel Turbine Model

    NASA Technical Reports Server (NTRS)

    Hudson, S. T.; Bordelon, W. J., Jr.; Smith, A. W.; Ramachandran, N.

    1995-01-01

    The main objective of this test was to obtain detailed radial and circumferential flow surveys at the inlet and exit of the SSME High Pressure Fuel Turbine model using three-hole cobra probes, hot-film probes, and a laser velocimeter. The test was designed to meet several objectives. First, the techniques for making laser velocimeter, hot-film probe, and cobra probe measurements in turbine flows were developed and demonstrated. The ability to use the cobra probes to obtain static pressure and, therefore, velocity had to be verified; insertion techniques had to be established for the fragile hot-film probes; and a seeding method had to be established for the laser velocimetry. Once the measurement techniques were established, turbine inlet and exit velocity profiles, temperature profiles, pressure profiles, turbulence intensities, and boundary layer thicknesses were measured at the turbine design point. The blockage effect due to the model inlet and exit total pressure and total temperature rakes on the turbine performance was also studied. A small range of off-design points were run to obtain the profiles and to verify the rake blockage effects off-design. Finally, a range of different Reynolds numbers were run to study the effect of Reynolds number on the various measurements.

  1. A generalized one-dimensional computer code for turbomachinery cooling passage flow calculations

    NASA Technical Reports Server (NTRS)

    Kumar, Ganesh N.; Roelke, Richard J.; Meitner, Peter L.

    1989-01-01

    A generalized one-dimensional computer code for analyzing the flow and heat transfer in the turbomachinery cooling passages was developed. This code is capable of handling rotating cooling passages with turbulators, 180 degree turns, pin fins, finned passages, by-pass flows, tip cap impingement flows, and flow branching. The code is an extension of a one-dimensional code developed by P. Meitner. In the subject code, correlations for both heat transfer coefficient and pressure loss computations were developed to model each of the above mentioned type of coolant passages. The code has the capability of independently computing the friction factor and heat transfer coefficient on each side of a rectangular passage. Either the mass flow at the inlet to the channel or the exit plane pressure can be specified. For a specified inlet total temperature, inlet total pressure, and exit static pressure, the code computers the flow rates through the main branch and the subbranches, flow through tip cap for impingement cooling, in addition to computing the coolant pressure, temperature, and heat transfer coefficient distribution in each coolant flow branch. Predictions from the subject code for both nonrotating and rotating passages agree well with experimental data. The code was used to analyze the cooling passage of a research cooled radial rotor.

  2. Chemical fractionation in the solar nebula

    NASA Technical Reports Server (NTRS)

    Grossman, L.

    1977-01-01

    The sequence of condensation of minerals from a cooling gas of solar composition has been calculated from thermodynamic data over the pressure range 0.001-0.00001 atm, assuming that complete chemical equilibrium is maintained. The results suggest that the Ca-Al-rich inclusions Allende and other carbonaceous chondrites are aggregates of the highest temperature condensates. Complete condensation of these elements is followed, 100 deg later, by the onset of the crystallization of nickel-iron, forsterite and enstatite. Transport of Ca-Al-rich refractory condensates from one part of the nebula to another before the condensation of these lower-temperature phases may have been responsible for the refractory element fractionations between the different classes of chondrites and possibly for the inferred refractory element enrichment of the Moon. The temperature gap between the condensation temperatures of nickel-iron and forsterite increases with increasing total pressure. Because pressure and temperature probably increased with decreasing heliocentric distance in the solar nebula, Mercury may have accreted from a condensate assemblage having a higher metal/silicate ratio than Venus or Earth which may, in turn, have formed from less oxidized material than Mars.

  3. Modelling of nectarine drying under near infrared - Vacuum conditions.

    PubMed

    Alaei, Behnam; Chayjan, Reza Amiri

    2015-01-01

    Drying of nectarine slices was performed to determine the thermal and physical properties in order to reduce product deterioration due to chemical reactions, facilitate storage and lower transportation costs. Because nectarine slices are sensitive to heat with long drying period, the selection of a suitable drying approach is a challenging task. Infrared-vacuum drying can be used as an appropriate method for susceptible materials with high moisture content such as nectarine slices. Modelling of nectarine slices drying was carried out in a thin layer near infraredvacuum conditions. Drying of the samples was implemented at the absolute pressures of 20, 40 and 60 kPa and drying temperatures of 50, 60 and 70°C. Drying behaviour of nectarine slices, as well as the effect of drying conditions on moisture loss trend, drying rate, effective diffusion coefficient, activation energy, shrinkage, colour and energy consumption of nectarine slices, dried in near infrared-vacuum dryer are discussed in this study. Six mathematical models were used to predict the moisture ratio of the samples in thin layer drying. The Midilli model had supremacy in prediction of nectarine slices drying behaviour. The maximum drying rates of the samples were between 0.014-0.047 gwater/gdry material·min. Effective moisture diffusivity of the samples was estimated in the ranges of 2.46·10-10 to 6.48·10-10 m2/s. Activation energy were computed between 31.28 and 35.23 kJ/mol. Minimum shrinkage (48.4%) and total colour difference (15.1) were achieved at temperature of 50°C and absolute pressure of 20 kPa. Energy consumption of the tests was estimated in the ranges of 0.129 to 0.247 kWh. Effective moisture diffusivity was increased with decrease of vacuum pressure and increase of drying temperature but effect of drying temperature on effective moisture diffusivity of nectarine slices was more than vacuum pressure. Activation energy was decreased with decrease in absolute pressure. Total colour difference and shrinkage of nectarine slices on near infrared-vacuum drying was decreased with decrease of vacuum pressure and decrease of drying temperature.

  4. Conductance enhancement due to interface magnons in electron-beam evaporated MgO magnetic tunnel junctions with CoFeB free layer deposited at different pressure

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Guo, P.; Yu, G. Q.; Wei, H. X.

    Electron-beam evaporated MgO-based magnetic tunnel junctions have been fabricated with the CoFeB free layer deposited at Ar pressure from 1 to 4 mTorr, and their tunneling process has been studied as a function of temperature and bias voltage. By changing the growth pressure, the junction dynamic conductance dI/dV, inelastic electron tunneling spectrum d²I/dV², and tunneling magnetoresistance vary with temperature. Moreover, the low-energy magnon cutoff energy E {sub C} derived from the conductance versus temperature curve agrees with interface magnon energy obtained directly from the inelastic electron tunneling spectrum, which demonstrates that interface magnons are involved in the electron tunneling process,more » opening an additional conductance channel and thus enhancing the total conductance.« less

  5. High-pressure liquid-monopropellant strand combustion.

    NASA Technical Reports Server (NTRS)

    Faeth, G. M.

    1972-01-01

    Examination of the influence of dissolved gases on the state of the liquid surface during high-pressure liquid-monopropellant combustion through the use of a strand burning experiment. Liquid surface temperatures were measured, using fine-wire thermocouples, during the strand combustion of ethyl nitrate, normal propyl nitrate, and propylene glycol dinitrate at pressures up to 81 atm. These measurements were compared with the predictions of a variable-property gas-phase analysis assuming an infinite activation energy for the decomposition reaction. The state of the liquid surface was estimated using a conventional low-pressure phase equilibrium model, as well as a high-pressure version that considered the presence of dissolved combustion-product gases in the liquid phase. The high-pressure model was found to give a superior prediction of measured liquid surface temperatures. Computed total pressures required for the surface to reach its critical mixing point during strand combustion were found to be in the range from 2.15 to 4.62 times the critical pressure of the pure propellant. Computed dissolved gas concentrations at the liquid surface were in the range from 35 to 50% near the critical combustion condition.

  6. Oxidation of C/SiC Composites at Reduced Oxygen Partial Pressures

    NASA Technical Reports Server (NTRS)

    Opila, E. J.; Serra, J. L.

    2007-01-01

    T-300 carbon fibers and T-300 carbon fiber reinforced silicon carbide composites (C/SiC) were oxidized in flowing reduced oxygen partial pressure environments at a total pressure of one atmosphere (0.5 atm O2, 0.05 atm O2 and 0.005 atm O2, balance argon). Experiments were conducted at four temperatures (816deg, 1149deg, 1343deg, and 1538 C). The oxidation kinetics were monitored using thermogravimetric analysis. T-300 fibers were oxidized to completion for times between 0.6 and 90 h. Results indicated that fiber oxidation kinetics were gas phase diffusion controlled. Oxidation rates had an oxygen partial pressure dependence with a power law exponent close to one. In addition, oxidation rates were only weakly dependent on temperature. The C/SiC coupon oxidation kinetics showed some variability, attributed to differences in the number and width of cracks in the SiC seal coat. In general, weight losses were observed indicating oxidation of the carbon fibers dominated the oxidation behavior. Low temperatures and high oxygen pressures resulted in the most rapid consumption of the carbon fibers. At higher temperatures, the lower oxidation rates were primarily attributed to crack closure due to SiC thermal expansion, rather than oxidation of SiC since these reduced rates were observed even at the lowest oxygen partial pressures where SiC oxidation is minimal.

  7. PPI/HASI Pressure Measurements in the Atmosphere of Titan

    NASA Astrophysics Data System (ADS)

    M'akinen, J. T. T.; Harri, A.-M.; Siili, T.; Lehto, A.; Kahanp'a'a, H.; Genzer, M.; Leppelmeier, G. W.; Leinonen, J.

    2005-08-01

    The Huygens probe descended through the atmosphere of Titan on January 14, 2005, providing an excellent set of observations. As a part of the Huygens Atmospheric Structure Instrument (HASI) measuring several variables, including acceleration, pressure, temperature and atmospheric electricity, the Pressure Profile Instrument (PPI) provided by FMI commenced operations after the deployment of the main parachute and jettisoning of the heat shield at an altitude of about 160 km. Based on aerodynamic considerations, PPI measured the total pressure with a Kiel probe at the end of a boom, connected to the sensor electronics inside the probe through an inlet tube. The instrument performed flawlessly during the 2.5 hour descent and the 0.5 hour surface phase before the termination of radio link between Huygens and the Cassini orbiter. We present an analysis of the pressure data including recreation of the pressure, temperature, altitude, velocity and acceleration profiles as well as an estimate for the level of atmospheric activity on the surface of Titan.

  8. Measurements of the Ice Water Content of Cirrus in the Tropics and Subtropics. I; Instrument Details and Validation

    NASA Technical Reports Server (NTRS)

    Weinstock, E. M.; Smith, J. B.; Sayres, D.; Pittman, J. V.; Allen, N.; Demusz, J.; Greenberg, M.; Rivero, M.; Anderson, J. G.

    2003-01-01

    We describe an instrument mounted in a pallet on the NASA WB-57 aircraft that is designed to measure the sum of gas phase and solid phase water, or total water, in cirrus clouds. Using an isokinetic inlet, a 600-watt heater mounted directly in the flow, and Lyman-alpha photofragment fluorescence technique for detection, accurate measurements of total water have been made over almost three orders of magnitude. Isokinetic flow is achieved with an actively controlled roots pump by referencing aircraft pressure, temperature, and true air speed, together with instrument flow velocity, temperature, and pressure. During CRYSTAL FACE, the instrument operated at duct temperatures sufficiently warm to completely evaporate particles up to 150 microns diameter. In flight diagnostics, intercomparison with water measured by absorption in flight, as well as intercomparisons in clear air with water vapor measured by the Harvard water vapor instrument and the JPL infrared tunable diode laser hygrometer validate the detection sensitivity of the instrument and illustrate minimal hysteresis from instrument surfaces. The simultaneous measurement of total water and water vapor in cirrus clouds yields their ice water content.

  9. 40 CFR 90.424 - Dilute sampling procedures-CVS calibration.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    .... Air temperature at CVS pump inlet PTI °C ±1.11 °C. Pressure depression at CVS pump inlet PPI kPa ±0... pump inlet depression that will yield a minimum of six data points for the total calibration. Allow the...: PB = barometric pressure, kPa PPI = Pump inlet depression, kPa. (iii) The correlation function at...

  10. 40 CFR 90.424 - Dilute sampling procedures-CVS calibration.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    .... Air temperature at CVS pump inlet PTI °C ±1.11 °C. Pressure depression at CVS pump inlet PPI kPa ±0... pump inlet depression that will yield a minimum of six data points for the total calibration. Allow the...: PB = barometric pressure, kPa PPI = Pump inlet depression, kPa. (iii) The correlation function at...

  11. 40 CFR 90.424 - Dilute sampling procedures-CVS calibration.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    .... Air temperature at CVS pump inlet PTI °C ±1.11 °C. Pressure depression at CVS pump inlet PPI kPa ±0... pump inlet depression that will yield a minimum of six data points for the total calibration. Allow the...: PB = barometric pressure, kPa PPI = Pump inlet depression, kPa. (iii) The correlation function at...

  12. 40 CFR 90.424 - Dilute sampling procedures-CVS calibration.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    .... Air temperature at CVS pump inlet PTI °C ±1.11 °C. Pressure depression at CVS pump inlet PPI kPa ±0... pump inlet depression that will yield a minimum of six data points for the total calibration. Allow the...: PB = barometric pressure, kPa PPI = Pump inlet depression, kPa. (iii) The correlation function at...

  13. 40 CFR 90.424 - Dilute sampling procedures-CVS calibration.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    .... Air temperature at CVS pump inlet PTI °C ±1.11 °C. Pressure depression at CVS pump inlet PPI kPa ±0... pump inlet depression that will yield a minimum of six data points for the total calibration. Allow the...: PB = barometric pressure, kPa PPI = Pump inlet depression, kPa. (iii) The correlation function at...

  14. Gravitational pressure, apparent horizon and thermodynamics of FLRW universe in the teleparallel gravity

    NASA Astrophysics Data System (ADS)

    da Rocha-Neto, J. F.; Morais, B. R.

    2018-04-01

    In the context of the teleparallel equivalent of general relativity the concept of gravitational pressure and gravitational energy-momentum arisen in a natural way. In the case of a Friedmann-Lemaitre-Robertson-Walker space FLRW we obtain the total energy contained inside the apparent horizon and the radial pressure over the apparent horizon area. We use these definitions to written a thermodynamics relation TAdSA = dEA+PAdVA at the apparent horizon, where EA is the total energy inside the apparent horizon, VA is the areal volume of the apparent horizon, PA is the radial pressure over the apparent horizon area, SA is the entropy which can be assumed as one quarter of the apparent horizon area only for a non stationary apparent horizon. We identify TA as the temperature at the surface of the apparent horizon. We shown that for all expanding accelerated FLRW model of universe the radial pressure is positive.

  15. Modeling and optimization of red currants vacuum drying process by response surface methodology (RSM).

    PubMed

    Šumić, Zdravko; Vakula, Anita; Tepić, Aleksandra; Čakarević, Jelena; Vitas, Jasmina; Pavlić, Branimir

    2016-07-15

    Fresh red currants were dried by vacuum drying process under different drying conditions. Box-Behnken experimental design with response surface methodology was used for optimization of drying process in terms of physical (moisture content, water activity, total color change, firmness and rehydratation power) and chemical (total phenols, total flavonoids, monomeric anthocyanins and ascorbic acid content and antioxidant activity) properties of dried samples. Temperature (48-78 °C), pressure (30-330 mbar) and drying time (8-16 h) were investigated as independent variables. Experimental results were fitted to a second-order polynomial model where regression analysis and analysis of variance were used to determine model fitness and optimal drying conditions. The optimal conditions of simultaneously optimized responses were temperature of 70.2 °C, pressure of 39 mbar and drying time of 8 h. It could be concluded that vacuum drying provides samples with good physico-chemical properties, similar to lyophilized sample and better than conventionally dried sample. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. Selective epitaxial growth of Ge1-xSnx on Si by using metal-organic chemical vapor deposition

    NASA Astrophysics Data System (ADS)

    Washizu, Tomoya; Ike, Shinichi; Inuzuka, Yuki; Takeuchi, Wakana; Nakatsuka, Osamu; Zaima, Shigeaki

    2017-06-01

    Selective epitaxial growth of Ge and Ge1-xSnx layers on Si substrates was performed by using metal-organic chemical vapor deposition (MOCVD) with precursors of tertiary-butyl-germane (t-BGe) and tri-butyl-vinyl-tin (TBVSn). We investigated the effects of growth temperature and total pressure during growth on the selectivity and the crystallinity of the Ge and Ge1-xSnx epitaxial layers. Under low total pressure growth conditions, the dominant mechanism of the selective growth of Ge epitaxial layers is the desorption of the Ge precursors. At a high total pressure case, it is needed to control the surface migration of precursors to realize the selectivity because the desorption of Ge precursors was suppressed. The selectivity of Ge growth was improved by diffusion of the Ge precursors on the SiO2 surfaces when patterned substrates were used at a high total pressure. The selective epitaxial growth of Ge1-xSnx layer was also realized using MOCVD. We found that the Sn precursors less likely to desorb from the SiO2 surfaces than the Ge precursors.

  17. Experimental investigation of supersonic combustion in a strut-cavity based combustor

    NASA Astrophysics Data System (ADS)

    Sathiyamoorthy, K.; Danish, Tahzeeb Hassan; Srinivas, J.; Manjunath, P.

    2018-07-01

    Supersonic combustion was experimentally investigated in a strut-cavity based scramjet combustor with kerosene and pilot hydrogen as fuels. Strut-cavity is the space between two tandem struts in streamwise direction. The occurrence of cavity induced pressure oscillations in the strut-cavity was confirmed through cold flow experiments. The dominant modes of pressure oscillations were strongly influenced by the cavity aspect ratio. A ventilated rear wall (VRW), which is a new passive control device, was adopted in the strut-cavity. The strut-cavity with the VRW attenuated pressure oscillations better than the 'ramp rear wall' configuration. A scramjet combustor was realized with two strut-cavities in tandem for mixing enhancement and a strut-cavity with the VRW for flame stabilization. The combustor was tested at the following inlet conditions: total pressure of 4.89 bar, total temperature of 1517 K, and Mach number of 2. Supersonic combustion was observed. Steep increase in static pressure in the region of the strut-cavity with the VRW indicated that the flame was stabilized. The combustor was operated at a wide range of equivalence ratios (0.3-0.7) without inlet interactions. The total pressure at the combustor exit plane indicated that the flow was uniform, except at the central region. The total pressure loss and combustion efficiency of the combustor were evaluated for various equivalence ratios.

  18. Effects of Brass (Cu3Zn2) as High Thermal Expansion Material on Shrink Disc Performance During High Thermal Loading

    NASA Astrophysics Data System (ADS)

    Mazlan, MIS; Mohd, SA; Bahar, ND; Aziz, SAA

    2018-03-01

    This research work is focused on shrink disc operation at high temperature. Geometrical and material design selections have been done by taking into consideration the existing shrink disc operating at high temperature condition. The existing shrink disc confronted slip between shaft and shaft sleeve during thermal loading condition. The assessment has been obtained through virtual experiment by using Finite Element Analysis (FEA) -Thermal Transient Stress for 900 seconds with 300 °C of thermal loading. This investigation consists of the current and improved version of shrink disc, where identical geometries and material properties were utilized. High Thermal Expansion (HTE) material has been introduced to overcome the current design of the shrink disc. Brass (Cu3Zn2) has been selected as the HTE material in the improved shrink disc design due to its high thermal expansion properties. The HTE has shown a significant improvement on the total contact area and contact pressure on the shaft and the shaft sleeve. The improved shrink disc embedded with HTE during thermal loading exhibit a minimum of 1244.1 mm2 of the total area on shaft and shaft sleeve which uninfluenced the total contact area at normal condition which is 1254.3 mm2. Meanwhile, the total pressure of improved shrink disc had an increment of 108.1 MPa while existing shrink disc total pressure has lost 17.2 MPa during thermal loading.

  19. The changes on physical characteristics of lightning discharge plasma during individual return stroke process

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Xu, He; Yuan, Ping; Cen, Jian-Yong

    2014-03-15

    A cloud-to-ground lightning with six return strokes has been recorded with a slit-less spectrograph in Qinghai province. According to the spectra of return strokes without continuous current, the electron density, the channel temperature, and the gas pressure have been calculated. Then, the correlativity of these parameters has been analyzed. The results indicate that the total intensity of spectra is positive correlated to the intensity of spectral line, they both decrease with time rapidly; furthermore, the channel temperature and the gas pressure decrease with time slowly in the similar trends.

  20. Measurements of the structure and circulation of the stratosphere and mesosphere, 1970

    NASA Technical Reports Server (NTRS)

    Smith, W. S.; Theon, J. S.; Wright, D. U., Jr.; Casey, J. F.; Horvath, J. J.

    1972-01-01

    Complete data from a total of 26 meteorological rocket soundings of the stratosphere and mesosphere conducted from Barrow, Alaska; Churchill, Canada; and Wallops Island, Va., are presented. These data consist of temperature, pressure, density, and wind profiles from 16 acoustic grenade soundings that cover the 30- to 90-km altitude range, and temperature, pressure, and density profiles from 10 pitot probe soundings that cover the 25- to 120-km altitude range. Errors for each of the 16 grenade soundings are also included. No analysis of the meteorological significance of the data is attempted.

  1. Development of techniques and associated instrumentation for high temperature emissivity measurements

    NASA Technical Reports Server (NTRS)

    Cunnington, G. R.; Funai, A. I.

    1972-01-01

    The progress during the sixth quarterly period is reported on construction and assembly of a test facility to determine the high temperature emittance properties of candidate thermal protection system materials for the space shuttle. This facility will provide simulation of such reentry environment parameters as temperature, pressure, and gas flow rate to permit studies of the effects of these parameters on the emittance stability of the materials. Also reported are the completed results for emittance tests on a set of eight Rene 41 samples and one anodized titanium alloy sample which were tested at temperatures up to 1600 F in vacuum. The data includes calorimetric determinations of total hemispherical emittance, radiometric determinations of total and spectral normal emittance, and pre- and post-test room temperature reflectance measurements.

  2. Atmospheric Pressure and Onset of Episodes of Menière's Disease - A Repeated Measures Study.

    PubMed

    Gürkov, Robert; Strobl, Ralf; Heinlin, Nina; Krause, Eike; Olzowy, Bernhard; Koppe, Christina; Grill, Eva

    2016-01-01

    External changes of air pressure are transmitted to the middle and inner ear and may be used therapeutically in Menière's disease, one of the most common vertigo disorders. We analyzed the possible relationship of atmospheric pressure and other meteorological parameters with the onset of MD vertigo episodes in order to determine whether atmospheric pressure changes play a role in the occurrence of MD episodes. Patients of a tertiary outpatient dizziness clinic diagnosed with MD were asked to keep a daily vertigo diary to document MD episodes (2004-2009). Local air pressure, absolute temperature and dew point temperature were acquired on an hourly basis. Change in meteorological parameters was conceptualized as the maximum difference in a 24 hour time frame preceding each day. Effects were estimated using additive mixed models with a random participant effect. We included lagged air parameters, age, sex, weekday and season in the model. A total of 56 persons (59% female) with mean age 54 years were included. Mean follow-up time was 267 days. Persons experienced on average 10.3 episodes during the observation period (median 8). Age and change in air pressure were significantly associated with vertigo onset risk (Odds Ratio = 0.979 and 1.010). We could not show an effect of sex, weekday, season, air temperature, and dew point temperature. Change in air pressure was significantly associated with onset of MD episodes, suggesting a potential triggering mechanism in the inner ear. MD patients may possibly use air pressure changes as an early warning system for vertigo attacks in the future.

  3. The effects of increasing levels of dietary garlic bulb on growth performance, systolic blood pressure, hematology, and ascites syndrome in broiler chickens.

    PubMed

    Varmaghany, Saifali; Karimi Torshizi, Mohammad Amir; Rahimi, Shaban; Lotfollahian, Houshang; Hassanzadeh, Mohammad

    2015-08-01

    The effects of dietary garlic bulb were studied separately on hematological parameters, ascites incidence, and growth performance of an ascites susceptible broiler hybrid under both standard temperature conditions ( STC: ) and cold temperature conditions ( CTC: ). A total of 336 one-day-old male broiler chickens were allocated to 4 experimental groups with 4 replicates of 21 birds each under STC. In addition, the same grouping with another 336 birds was used for CTC. Under CTC, the birds were exposed to cold temperatures for induction of ascites. Experimental groups were defined by the inclusion of 0 (control), 5, 10 or 15 g/kg garlic bulbs in the diets under both STC and CTC. Growth performance, systolic blood pressure (as a measure of systemic arterial blood pressure), physiological and biochemical parameters, as well as ascites indices (right ventricle [ RV: ], total ventricle [ TV: ] weights, and RV/TV: ) were evaluated. Systolic blood pressure was determined using an indirect method with a sphygmomanometer, a pediatric cuff, and a Doppler device. The final body weight decreased quadratically (P = 0.003), with increasing garlic bulb levels in the diets under STC. The feed conversion ratio showed no significant differences among all groups under both STC and CTC. No significant differences were observed in total mortality and ascites-related mortality in all groups under STC, although total mortality (L: P = 0.01; Q: P = 0.001) and ascites-related mortality (L: P = 0.007; Q: P = 0.001) were significantly different among the diets under CTC. Under STC, the systolic blood pressure, packed cell volume, hemoglobin, RV, TV, and RV/TV did not vary significantly among the diets. However, red blood cell count and erythrocyte osmotic fragility decreased linearly (P < 0.005) with increasing garlic bulb levels in the diets under STC. Under CTC, the systolic blood pressure, packed cell volume, red blood cell count, and erythrocyte osmotic fragility decreased (P < 0.05) with increasing garlic levels. It is concluded that the inclusion of 5 g/kg garlic bulb in susceptible broiler chicken diets has a systemic anti-hypertensive effect and could decrease ascites incidence without impairing broiler chicken performance. © 2015 Poultry Science Association Inc.

  4. Aero-Thermal Calibration of the NASA Glenn Icing Research Tunnel (2012 Test)

    NASA Technical Reports Server (NTRS)

    Pastor-Barsi, Christine M.; Arrington, E. Allen; VanZante, Judith Foss

    2012-01-01

    A major modification of the refrigeration plant and heat exchanger at the NASA Glenn Icing Research Tunnel (IRT) occurred in autumn of 2011. It is standard practice at NASA Glenn to perform a full aero-thermal calibration of the test section of a wind tunnel facility upon completion of major modifications. This paper will discuss the tools and techniques used to complete an aero-thermal calibration of the IRT and the results that were acquired. The goal of this test entry was to complete a flow quality survey and aero-thermal calibration measurements in the test section of the IRT. Test hardware that was used includes the 2D Resistive Temperature Detector (RTD) array, 9-ft pressure survey rake, hot wire survey rake, and the quick check survey rake. This test hardware provides a map of the velocity, Mach number, total and static pressure, total temperature, flow angle and turbulence intensity. The data acquired were then reduced to examine pressure, temperature, velocity, flow angle, and turbulence intensity. Reduced data has been evaluated to assess how the facility meets flow quality goals. No icing conditions were tested as part of the aero-thermal calibration. However, the effects of the spray bar air injections on the flow quality and aero-thermal calibration measurements were examined as part of this calibration.

  5. Carbon Allotrope Dependence on Temperature and Pressure During Thermal Decomposition of Silicon Carbide

    DTIC Science & Technology

    2014-03-27

    temperature, to its electrical conductivity, while considering its dopant concentration ( or ) [2]. (1-2) As previously stated, temperature effects...electrons [2]. Equations (1-3) and (1-4) are used to calculate electron (or hole) mobility in Si based on total dopant concentration (N) at a given...nickel, or cobalt . The metal catalyst breaks down the carbon feedstock to produce CNTs. As shown in Figure 53 below, 83 gaseous carbon feedstock

  6. An organic cosmo-barometer: Distinct pressure and temperature effects for methyl substituted polycyclic aromatic hydrocarbons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Montgomery, Wren; Watson, Jonathan S.; Sephton, Mark A., E-mail: w.montgomery@imperial.ac.uk

    2014-04-01

    There are a number of key structures that can be used to reveal the formation and modification history of organic matter in the cosmos. For instance, the susceptibility of organic matter to heat is well documented and the relative thermal stabilities of different isomers can be used as cosmothermometers. Yet despite being an important variable, no previously recognized organic marker of pressure exists. The absence of a pressure marker is unfortunate considering our ability to effectively recognize extraterrestrial organic structures both remotely and in the laboratory. There are a wide variety of pressures in cosmic settings that could potentially bemore » reflected by organic structures. Therefore, to develop an organic cosmic pressure marker, we have used state-of-the-art diamond anvil cell (DAC) and synchrotron-source Fourier transform infrared (FTIR) spectroscopy to reveal the effects of pressure on the substitution patterns for representatives of the commonly encountered methyl substituted naphthalenes, specifically the dimethylnaphthalenes. Interestingly, although temperature and pressure effects are concordant for many isomers, pressure appears to have the opposite effect to heat on the final molecular architecture of the 1,5-dimethylnaphthalene isomer. Our data suggest the possibility of the first pressure parameter or 'cosmo-barometer' (1,5-dimethylnaphthalene/total dimethylnaphthalenes) that can distinguish pressure from thermal effects. Information can be obtained from the new pressure marker either remotely by instrumentation on landers or rovers or directly by laboratory measurement, and its use has relevance for all cases where organic matter, temperature, and pressure interplay in the cosmos.« less

  7. Development of techniques and associated instrumentation for high temperature emissivity measurements

    NASA Technical Reports Server (NTRS)

    Cunnington, G. R.; Funaa, A. I.; Cassady, P. E.

    1973-01-01

    Studies were made to develop a test apparatus for the measurement of total emittance of materials under repeated exposure to simulated earth entry conditions. As no existing test facility met the emittance measurement and entry simulation goals, a new apparatus was designed, fabricated and checked out. This apparatus has the capability of performing total and spectral emittance measurements during cyclic temperature and pressure exposure under sonic and supersonic flow conditions. Emittance measurements were performed on a series of oxidized superalloys, silicide coated columbium alloys and ceramic coatings.

  8. Preliminary Results of Altitude-Wind-Tunnel Investigation of X24C-4B Turbojet Engine. I - Pressure and Temperature Distributions

    NASA Technical Reports Server (NTRS)

    Prince, William R.; Hawkins, W. Kent

    1947-01-01

    Pressures and temperatures throughout the X24C-4B turbojet engine are presented in both tabular and graphical forms to show the effect of altitude, flight Mach number, and engine speed on the internal operation of the engine. These data were obtained in the NACA Cleveland altitude wind tunnel at simulated altitudes from 5000 to 45,000 feet, simulated flight Mach numbers from 0.25 to 1.08, and engine speeds from 4000 to 12,500 rpm. Location and detail drawings of the instrumentation installed at seven survey stations in the engine are shown. Application of generalization factors to pressures and temperatures at each measuring station for the range of altitudes investigated showed that the data did not generalize above an altitude of 25,000 feet. Total-pressure distribution at the compressor outlet varied only with change in engine speed. At altitudes above 35,000 feet and engine speeds above 11,000 rpm, the peak temperature at the turbine-outlet annulus moved inward toward the root of the blade, which is undesirable from blade-stress considerations. The temperature levels at the turbine outlet and the exhaust-nozzle outlet were lowered as the Mach number was increased. The static-pressure measurements obtained at each stator stage of the compressor showed a pressure drop through the inlet guide vanes and the first-stage rotor at high engine speeds. The average values measured by the manufacturer's instrumentation werein close agreement with the average values obtained with NACA instrumentation.

  9. 40 CFR 98.124 - Monitoring and QA/QC requirements.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... in paragraph (b)(8) of this section only if the total annual CO2-equivalent fluorinated GHG... terms of total CO2 equivalents. For fluorinated GHGs whose GWPs are not listed in Table A-1 to subpart A... control purposes and may include but are not limited to yields, pressures, temperatures, etc. (e.g., of...

  10. 40 CFR 98.124 - Monitoring and QA/QC requirements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... in paragraph (b)(8) of this section only if the total annual CO2-equivalent fluorinated GHG... terms of total CO2 equivalents. For fluorinated GHGs whose GWPs are not listed in Table A-1 to subpart A... control purposes and may include but are not limited to yields, pressures, temperatures, etc. (e.g., of...

  11. Effect of aviation fuel type and fuel injection conditions on the spray characteristics of pressure swirl and hybrid air blast fuel injectors

    NASA Astrophysics Data System (ADS)

    Feddema, Rick

    Feddema, Rick T. M.S.M.E., Purdue University, December 2013. Effect of Aviation Fuel Type and Fuel Injection Conditions on the Spray Characteristics of Pressure Swirl and Hybrid Air Blast Fuel Injectors. Major Professor: Dr. Paul E. Sojka, School of Mechanical Engineering Spray performance of pressure swirl and hybrid air blast fuel injectors are central to combustion stability, combustor heat management, and pollutant formation in aviation gas turbine engines. Next generation aviation gas turbine engines will optimize spray atomization characteristics of the fuel injector in order to achieve engine efficiency and emissions requirements. Fuel injector spray atomization performance is affected by the type of fuel injector, fuel liquid properties, fuel injection pressure, fuel injection temperature, and ambient pressure. Performance of pressure swirl atomizer and hybrid air blast nozzle type fuel injectors are compared in this study. Aviation jet fuels, JP-8, Jet A, JP-5, and JP-10 and their effect on fuel injector performance is investigated. Fuel injector set conditions involving fuel injector pressure, fuel temperature and ambient pressure are varied in order to compare each fuel type. One objective of this thesis is to contribute spray patternation measurements to the body of existing drop size data in the literature. Fuel droplet size tends to increase with decreasing fuel injection pressure, decreasing fuel injection temperature and increasing ambient injection pressure. The differences between fuel types at particular set conditions occur due to differences in liquid properties between fuels. Liquid viscosity and surface tension are identified to be fuel-specific properties that affect the drop size of the fuel. An open aspect of current research that this paper addresses is how much the type of aviation jet fuel affects spray atomization characteristics. Conventional aviation fuel specifications are becoming more important with new interest in alternative fuels. Optical patternation data and line of sight laser diffraction data show that there is significant difference between jet fuels. Particularly at low fuel injection pressures (0.345 MPa) and cold temperatures (-40 C), the patternation data shows that the total surface area in the spray at 38.1 mm from the pressure swirl injector for the JP-10 fuel type is one-sixth the amount of the JP-8. Finally, this study compares the atomizer performance of a pressure swirl nozzle to a hybrid air blast nozzle. The total surface area for both the hybrid air blast nozzle and the pressure swirl nozzle show a similar decline in atomization performance at low fuel injection pressures and cold temperatures. However, the optical patternator radial profile data and the line of sight laser diffraction data show that the droplet size and spray distribution data are less affected by injection conditions and fuel type in the hybrid air blast nozzle, than they are in the pressure swirl nozzle. One explanation is that the aerodynamic forces associated with the swirler on the hybrid air blast nozzle control the distribution droplets in the spray. This is in contrast to the pressure swirl nozzle droplet distribution that is controlled by internal geometry and droplet ballistics.

  12. Development of a low frost-point generator operating at sub-atmospheric pressure

    NASA Astrophysics Data System (ADS)

    Cuccaro, R.; Rosso, L.; Smorgon, D.; Beltramino, G.; Tabandeh, S.; Fernicola, V.

    2018-05-01

    A low frost-point generator (INRIM 03) operating at sub-atmospheric pressure has been designed and constructed at the Istituto Nazionale di Ricerca Metrologica (INRIM) as part of a calibration facility for upper-air sounding instruments. This new humidity generator covers the frost-point temperature range between  ‑99 °C and  ‑20 °C and works at any controlled pressure between 200 hPa and 1100 hPa, achieving a complete saturation of the carrier gas (nitrogen) in a single passage through a stainless steel isothermal saturator. The generated humid gas contains a water vapour amount fraction between 14  ×  10‑9 mol mol‑1 and 5  ×  10‑3 mol mol‑1. In this work the design of the generator is reported together with characterisation and performance evaluation tests. A preliminary validation of the INRIM 03 against one of the INRIM humidity standards in the common region is also included. Based on experimental test results, an initial uncertainty evaluation of the generated frost-point temperature, T fp, and water vapour amount fraction, x w, in the limited range down to  ‑75 °C at atmospheric pressure is reported. For the frost-point temperature, the uncertainty budget yields a total expanded uncertainty (k  =  2) of less than 0.028 °C, while for the mole fraction the budget yields a total expanded uncertainty of less than 10‑6 mol mol‑1.

  13. Optimization of supercritical carbon dioxide extraction of Piper Betel Linn leaves oil and total phenolic content

    NASA Astrophysics Data System (ADS)

    Aziz, A. H. A.; Yunus, M. A. C.; Arsad, N. H.; Lee, N. Y.; Idham, Z.; Razak, A. Q. A.

    2016-11-01

    Supercritical Carbon Dioxide (SC-CO2) Extraction was applied to extract piper betel linn leaves. The piper betel leaves oil was used antioxidant, anti-diabetic, anticancer and antistroke. The aim of this study was to optimize the conditions of pressure, temperature and flowrate for oil yield and total phenolic content. The operational conditions of SC-CO2 studied were pressure (10, 20, 30 MPa), temperature (40, 60, 80 °C) and flowrate carbon dioxide (4, 6, 8 mL/min). The constant parameters were average particle size and extraction regime, 355pm and 3.5 hours respectively. First order polynomial expression was used to express the extracted oil while second order polynomial expression was used to express the total phenolic content and the both results were satisfactory. The best conditions to maximize the total extraction oil yields and total phenolic content were 30 MPa, 80 °C and 4.42 mL/min leading to 7.32% of oil and 29.72 MPa, 67.53 °C and 7.98 mL/min leading to 845.085 mg GAE/g sample. In terms of optimum condition with high extraction yield and high total phenolic content in the extracts, the best operating conditions were 30 MPa, 78 °C and 8 mL/min with 7.05% yield and 791.709 mg gallic acid equivalent (GAE)/g sample. The most dominant condition for extraction of oil yield and phenolic content were pressure and CO2 flowrate. The results show a good fit to the proposed model and the optimal conditions obtained were within the experimental range with the value of R2 was 96.13% for percentage yield and 98.52% for total phenolic content.

  14. Use of an approximate similarity principle for the thermal scaling of a full-scale thrust augmenting ejector

    NASA Technical Reports Server (NTRS)

    Barankiewicz, Wendy S.; Perusek, Gail P.; Ibrahim, Mounir B.

    1992-01-01

    Full temperature ejector model simulations are expensive, and difficult to implement experimentally. If an approximate similarity principle could be established, properly chosen performance parameters should be similar for both hot and cold flow tests if the initial Mach number and total pressures of the flow field are held constant. Existing ejector data is used to explore the utility of one particular similarity principle; the Munk and Prim similarity principle for isentropic flows. Static performance test data for a full-scale thrust augmenting ejector are analyzed for primary flow temperatures up to 1560 R. At different primary temperatures, exit pressure contours are compared for similarity. A nondimensional flow parameter is then used to eliminate primary nozzle temperature dependence and verify similarity between the hot and cold flow experiments.

  15. Use of an approximate similarity principle for the thermal scaling of a full-scale thrust augmenting ejector

    NASA Technical Reports Server (NTRS)

    Barankiewicz, Wendy; Perusek, Gail P.; Ibrahim, Mounir

    1992-01-01

    Full temperature ejector model simulations are expensive, and difficult to implement experimentally. If an approximate similarity principle could be established, properly chosen performance parameters should be similar for both hot and cold flow tests if the initial Mach number and total pressures of the flow field are held constant. Existing ejector data is used to explore the utility of one particular similarity principle; the Munk and Prim similarity principle for isentropic flows. Static performance test data for a full-scale thrust augmenting ejector are analyzed for primary flow temperatures up to 1560 R. At different primary temperatures, exit pressure contours are compared for similarity. A nondimensional flow paramenter is then used to eliminate primary nozzle temperature dependence and verify similarity between the hot and cold flow experiments.

  16. Dynamic Leidenfrost temperature on micro-textured surfaces: Acoustic wave absorption into thin vapor layer

    NASA Astrophysics Data System (ADS)

    Jerng, Dong Wook; Kim, Dong Eok

    2018-01-01

    The dynamic Leidenfrost phenomenon is governed by three types of pressure potentials induced via vapor hydrodynamics, liquid dynamic pressure, and the water hammer effect resulting from the generation of acoustic waves at the liquid-vapor interface. The prediction of the Leidenfrost temperature for a dynamic droplet needs quantitative evaluation and definition for each of the pressure fields. In particular, the textures on a heated surface can significantly affect the vapor hydrodynamics and the water hammer pressure. We present a quantitative model for evaluating the water hammer pressure on micro-textured surfaces taking into account the absorption of acoustic waves into the thin vapor layer. The model demonstrates that the strength of the acoustic flow into the liquid droplet, which directly contributes to the water hammer pressure, depends on the magnitude of the acoustic resistance (impedance) in the droplet and the vapor region. In consequence, the micro-textures of the surface and the increased spacing between them reduce the water hammer coefficient ( kh ) defined as the ratio of the acoustic flow into the droplet to total generated flow. Aided by numerical calculations that solve the laminar Navier-Stokes equation for the vapor flow, we also predict the dynamic Leidenfrost temperature on a micro-textured surface with reliable accuracy consistent with the experimental data.

  17. Kinetics and Thermochemistry of Reversible Adduct Formation in the Reaction of Cl((sup 2)P(sub J)) with CS2

    NASA Technical Reports Server (NTRS)

    Nicovich, J. M.; Shackelford, C. J.; Wine, P. H.

    1997-01-01

    Reversible adduct formation in the reaction of Cl((sup 2)P(sub J)) with CS2 has been observed over the temperature range 193-258 K by use of time-resolved resonance fluorescence spectroscopy to follow the decay of pulsed-laser-generated Cl((sup 2)P(sub J)) into equilbrium with CS2Cl. Rate coefficients for CS2Cl formation and decomposition have been determined as a function of temperature and pressure; hence, the equilbrium constant has been determined as a function of temperature. A second-law analysis of the temperature dependence of Kp and heat capacity corrections calculated with use of an assumed CS2Cl structure yields the following thermodynamic parameters for the association reaction: Delta-H(sub 298) = -10.5 +/- 0.5 kcal/mol, Delta-H(sub 0) = -9.5 +/- 0.7 kcal/mol, Delta-S(sub 298) = -26.8 +/- 2.4 cal/mol.deg., and Delta-H(sub f,298)(CS2Cl) = 46.4 +/- 0.6 kcal/mol. The resonance fluorescence detection scheme has been adapted to allow detection of Cl((sup 2)P(sub J)) in the presence of large concentrations of O2, thus allowing the CS2Cl + Cl + O2 reaction to be investigated. We find that the rate coefficient for CS2Cl + O2 reaction via all channels that do not generate Cl((sup 2)P(sub J)) is less than 2.5 x 10(exp-16) cu cm/(molecule.s) at 293 K and 300-Torr total pressure and that the total rate coefficient is less than 2 x 10 (exp -15) cu cm/(molecule.s) at 230 K and 30-Torr total pressure. Evidence for reversible adduct formation in the reaction of Cl((sup 2)P(sub J)) with COS was sought but not observed, even at temperatures as low as 194 K.

  18. Prediction of ice content in biological model solutions when frozen under high pressure.

    PubMed

    Guignon, B; Aparicio, C; Otero, L; Sanz, P D

    2009-01-01

    High pressure is, at least, as effective as cryoprotective agents (CPAs) and are used for decreasing both homogenous nucleation and freezing temperatures. This fact gives rise to a great variety of possible cryopreservation processes under high pressure. They have not been optimized yet, since they are relatively recent and are mainly based on the pressure-temperature phase diagram of pure water. Very few phase diagrams of biological material are available under pressure. This is owing to the lack of suitable equipment and to the difficulties encountered in carrying out the measurements. Different aqueous solutions of salt and CPAs as biological models are studied in the range of 0 degrees C down to -35 degrees C, 0.1 up to 250 MPa, and 0-20% w/w total solute concentration. The phase transition curves of glycerol and of sodium chloride with either glycerol or sucrose in aqueous solutions are determined in a high hydrostatic pressure vessel. The experimental phase diagrams of binary solutions were well described by a third-degree polynomial equation. It was also shown that Robinson and Stokes' equation at high pressure succeeds in predicting the phase diagrams of both binary and ternary solutions. The solute cryoconcentration and the ice content were calculated as a function of temperature and pressure conditions during the freezing of a binary solution. This information should provide a basis upon which high-pressure cryopreservation processes may be performed and the damages derived from ice formation evaluated. (c) 2009 American Institute of Chemical Engineers Biotechnol.

  19. Tropospheric- Stratospheric Measurement Studies Summary

    NASA Technical Reports Server (NTRS)

    Browen, Stuart W.

    1998-01-01

    The two high altitude aircraft, ER-2 NASA #706 and 709 and the DC-8 NASA #717 are in active use in several programs of upper atmospheric research to study polar ozone changes, stratospheric-tropospheric exchange processes and atmospheric effects of aviation aircraft. The ER-2 has participated in seven major missions which mainly concentrated on vortex dynamics and the large losses of Ozone in the Polar regions (Ozone hole) observed in the spring. One mission verified the complex dynamical chemical and physical processes that occur during sunrise and sunset. Stratospheric Tracers of Atmospheric Transport (STRAT) obtained background measurements using the full ER-2 suite of instruments. Photochemistry of Ozone Loss in the Arctic Region in Summer (POLARIS) in 1997 assisted in understanding the mid-latitude and Arctic Ozone losses during the Northern Summer. The DC-8 with the Meteorological Measurement System (MMS) has participated in the Subsonic Aircraft: Cloud and Contrail Effects Special Study (SUCCESS), in 1996 and the Subsonic assessment Ozone and Nitrogen oxide experiment (SONEX) in 1997 missions. The MMS with its sophisticated software accurately measures ground speed and attitude, in-situ static and dynamic pressure total temperature, which are used to calculate the three dimensional wind fields, static pressure, temperature and turbulence values to meteorological accuracy. The meteorological data is not only of interest for its own sake in atmospheric dynamical processes such as mountain waves and flux measurements; but is also required by other ER-2 experiments that simultaneously measure water vapor, O3, aerosols, NO, HCl, CH4, N2O, ClO, BrO, CO2, NOy, HOx and temperature gradients. MMS products are extensively used to assist in the interpretation of their results in understanding the importance of convective effects relative to in-situ chemical changes, as may be noted by examining the list of references attached. The MMS consists of three subsystems: (a) aircraft instrumentation, inertial navigation system (INS), static and dynamic pressure taps, (b) additional dedicated instrumentation measuring angle of attack, yaw, total temperature, and a GPS which on the DC-8 measures position, velocity and attitude (c) an on board data, storage and computing acquisition system. This instrumentation and the associated software requires both an on-going laboratory ground calibration procedure for the total air temperature, static and total pressure inputs, verification of the INS dynamic response and also extensive air measurements and intercomparisons which ultimately verify and calibrate the complete system and its software. More than the usual accuracy is required because of the near cancellation occurring in the difference between the ground speed and true airspeed vectors used to give the wind vector. In the past year we have redesigned, recalibrated and used the MMS system on the NASA DC-8 that was previously used in the SUCCESS mission for the SONEX mission. Two papers were co-authored based on SUCCESS flights. Several reports and handouts were written for SONEX. Calibrations of the DC-8 pressure transducer temperature measuring thermistors was completed and an extensive analysis spanning several years of data files of the DC-8 Rosemount pressure transducer calibrations was done.

  20. Force Measurement Improvements to the National Transonic Facility Sidewall Model Support System

    NASA Technical Reports Server (NTRS)

    Goodliff, Scott L.; Balakrishna, Sundareswara; Butler, David; Cagle, C. Mark; Chan, David; Jones, Gregory S.; Milholen, William E., II

    2016-01-01

    The National Transonic Facility is a transonic pressurized cryogenic facility. The development of the high Reynolds number semi-span capability has advanced over the years to include transonic active flow control and powered testing using the sidewall model support system. While this system can be used in total temperatures down to -250Â F for conventional unpowered configurations, it is limited to temperatures above -60Â F when used with powered models that require the use of the high-pressure air delivery system. Thermal instabilities and non-repeatable mechanical arrangements revealed several data quality shortfalls by the force and moment measurement system. Recent modifications to the balance cavity recirculation system have improved the temperature stability of the balance and metric model-to-balance hardware. Changes to the mechanical assembly of the high-pressure air delivery system, particularly hardware that interfaces directly with the model and balance, have improved the repeatability of the force and moment measurement system. Drag comparisons with the high-pressure air system removed will also be presented in this paper.

  1. Real-gas effects 1: Simulation of ideal gas flow by cryogenic nitrogen and other selected gases

    NASA Technical Reports Server (NTRS)

    Hall, R. M.

    1980-01-01

    The thermodynamic properties of nitrogen gas do not thermodynamically approximate an ideal, diatomic gas at cryogenic temperatures. Choice of a suitable equation of state to model its behavior is discussed and the equation of Beattie and Bridgeman is selected as best meeting the needs for cryogenic wind tunnel use. The real gas behavior of nitrogen gas is compared to an ideal, diatomic gas for the following flow processes: isentropic expansion; normal shocks; boundary layers; and shock wave boundary layer interactions. The only differences in predicted pressure ratio between nitrogen and an ideal gas that may limit the minimum operating temperatures of transonic cryogenic wind tunnels seem to occur at total pressures approaching 9atmospheres and total temperatures 10 K below the corresponding saturation temperature, where the differences approach 1 percent for both isentropic expansions and normal shocks. Several alternative cryogenic test gases - air, helium, and hydrogen - are also analyzed. Differences in air from an ideal, diatomic gas are similar in magnitude to those of nitrogen. Differences for helium and hydrogen are over an order of magnitude greater than those for nitrogen or air. Helium and hydrogen do not approximate the compressible flow of an ideal, diatomic gas.

  2. USAF bioenvironmental noise data handbook. Volume 168: MB-3 tester, pressurized cabin leakage, aircraft

    NASA Astrophysics Data System (ADS)

    Rau, T. H.

    1982-06-01

    The MB-3 Tester is an electric motor-driven cabin leakage tester designed to furnish pressurized air to the aircraft at controlled pressures and temperatures during ground pressurization of aircraft cockpits and pressurized compartments. This report provides measured data defining the bioacoustic environments produced by this unit operating at a normal rated/load condition. Near-field data are reported for 37 locations in a wide variety of physical and psychoacoustic measures: overall and band sound pressure levels, C-weighted and A-weighted sound levels, preferred speech interference level, perceived noise level, and limiting times for total daily exposure of personnel with and without standard Air Force ear protectors.

  3. Acoustic temperature measurement in a rocket noise field.

    PubMed

    Giraud, Jarom H; Gee, Kent L; Ellsworth, John E

    2010-05-01

    A 1 μm diameter platinum wire resistance thermometer has been used to measure temperature fluctuations generated during a static GEM-60 rocket motor test. Exact and small-signal relationships between acoustic pressure and acoustic temperature are derived in order to compare the temperature probe output with that of a 3.18 mm diameter condenser microphone. After preliminary plane wave tests yielded good agreement between the transducers within the temperature probe's ∼2 kHz bandwidth, comparison between the temperature probe and microphone data during the motor firing show that the ±∼3 K acoustic temperature fluctuations are a significant contributor to the total temperature variations.

  4. The Effect of Pressure and Temperature on Mid-Infrared Sensing of Dissolved Hydrocarbons in Water.

    PubMed

    Heath, Charles; Myers, Matthew; Pejcic, Bobby

    2017-12-19

    Attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy using a polymer coated internal reflection element/waveguide is an established sensor platform for the detection of a range of organic and hydrocarbon molecules dissolved in water. The polymer coating serves two purposes: to concentrate hydrocarbons from the aqueous phase and to exclude water along with other interfering molecules from the surface of the internal reflection element. Crucial to reliable quantification and analytical performance is the calibration of the ATR-FTIR sensor which is commonly performed in water under mild ambient conditions (i.e., 25 °C and 1 atm). However, there is a pressing need to monitor environmental and industrial processes/events that may occur at high pressures and temperatures where this calibration approach is unsuitable. Using a ruggedized optical fiber probe with a diamond-based ATR, we have conducted mid-infrared sensor experiments to understand the influence of high pressure (up to 207 bar) and temperature (up to 80 °C) on the detection of toluene and naphthalene dissolved in water. Using a poly(isobutylene) film, we have shown that the IR spectroscopic response is relatively unaffected by changes in pressure; however, a diminished response was observed with increasing temperature. We reveal that changes in the refractive index of the polymer film with temperature have only a minor effect on sensitivity. A more plausible explanation for the observed significant change in sensor response with temperature is that the partitioning process is exothermic and becomes less favorable with increasing temperature. This Article shows that the sensitivity is relatively invariant to pressure; however, the thermal variations are significant and need to be considered when quantifying the concentration of hydrocarbons in water.

  5. Heat-transfer and pressure measurements on a simulated elevon deflected 30 deg near flight conditions at Mach 7

    NASA Technical Reports Server (NTRS)

    Johnson, C. B.; Taylor, A. H.; Weinstein, I.

    1977-01-01

    Heat transfer rates and pressures were obtained on an elevon plate (deflected 30 deg) and a flat plate upstream of the elevon in an 8 foot high-temperature structures tunnel. The flight Reynolds number and flight total enthalpy for altitudes of 26.8 km and 28.7 km at Mach seven were duplicated. The heat transfer and pressure data were used to establish heating and pressure loads. The measured heating was compared with several theoretical predictions, and the closest agreement obtained with a Schultz-Grunow reference enthalpy method of calculation.

  6. Brady's Geothermal Field - Analysis of Pressure Data

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lim, David

    *This submission provides corrections to GDR Submissions 844 and 845* Poroelastic Tomography (PoroTomo) by Adjoint Inverse Modeling of Data from Hydrology. The 3 *csv files containing pressure data are the corrected versions of the pressure dataset found in Submission 844. The dataset has been corrected in the sense that the atmospheric pressure has been subtracted from the total pressure measured in the well. Also, the transducers used at wells 56A-1 and SP-2 are sensitive to surface temperature fluctuations. These temperature effects have been removed from the corrected datasets. The 4th *csv file contains corrected version of the pumping data foundmore » in Submission 845. The data has been corrected in the sense that the data from several wells that were used during the PoroTomo deployment pumping tests that were not included in the original dataset has been added. In addition, several other minor changes have been made to the pumping records due to flow rate instrument calibration issues that were discovered.« less

  7. Solubility of crude oil in methane as a function of pressure and temperature

    USGS Publications Warehouse

    Price, L.C.; Wenger, L.M.; Ging, T.; Blount, C.W.

    1983-01-01

    The solubility of a 44?? API (0.806 sp. gr.) whole crude oil has been measured in methane with water present at temperatures of 50 to 250??C and pressures of 740 to 14,852 psi, as have the solubilities of two high molecular weight petroleum distillation fractions at temperatures of 50 to 250??C and pressures of 4482 to 25,266 psi. Both increases in pressure and temperature increase the solubility of crude oil and petroleum distillation fractions in methane, the effect of pressure being greater than that of temperature. Unexpectedly high solubility levels (0.5-1.5 grams of oil per liter of methane-at laboratory temperature and pressure) were measured at moderate conditions (50-200??C and 5076-14504 psi). Similar results were found for the petroleum distillation fractions, one of which was the highest molecular weight material of petroleum (material boiling above 266??C at 6 microns pressure). Unexpectedly mild conditions (100??C and 15,200 psi; 200??C and 7513 psi) resulted in cosolubility of crude oil and methane. Under these conditions, samples of the gas-rich phase gave solubility values of 4 to 5 g/l, or greater. Qualitative analyses of the crude-oil solute samples showed that at low pressure and temperature equilibration conditions, the solute condensate would be enriched in C5-C15 range hydrocarbons and in saturated hydrocarbons in the C15+ fraction. With increases in temperature and especially pressure, these tendencies were reversed, and the solute condensate became identical to the starting crude oil. The data of this study, compared to that of previous studies, shows that methane, with water present, has a much greater carrying capacity for crude oil than in dry systems. The presence of water also drastically lowers the temperature and pressure conditions required for cosolubility. The data of this and/or previous studies demonstrate that the addition of carbon dioxide, ethane, propane, or butane to methane also has a strong positive effect on crude oil solubility, as does the presence of fine grained rocks. The n-paraffin distributions (as well as the overall composition) of the solute condensates are controlled by the temperature and pressure of solution and exsolution, as well as by the composition of the original starting material. It appears quite possible that primary migration by gaseous solution could 'strip' a source rock of crude-oil like components leaving behind a bitumen totally unlike the migrated crude oil. The data of this study demonstrate previous criticisms of primary petroleum migration by gas solution are invalid; that primary migration by gaseous solution cannot occur because methane cannot dissolve sufficient volumes of crude oil or cannot dissolve the highest molecular weight components of petroleum (tars and asphaltenes). ?? 1983.

  8. Application of FLEET Velocimetry in the NASA Langley 0.3-meter Transonic Cryogenic Tunnel

    NASA Technical Reports Server (NTRS)

    Burns, Ross A.; Danehy, Paul M.; Halls, Benjamin R.; Jiang, Naibo

    2015-01-01

    Femtosecond laser electronic excitation and tagging (FLEET) velocimetry is demonstrated in a large-scale transonic cryogenic wind tunnel. Test conditions include total pressures, total temperatures, and Mach numbers ranging from 15 to 58 psia, 200 to 295 K, and 0.2 to 0.75, respectively. Freestream velocity measurements exhibit accuracies within 1 percent and precisions better than 1 m/s. The measured velocities adhere closely to isentropic flow theory over the domain of temperatures and pressures that were tested. Additional velocity measurements are made within the tunnel boundary layer; virtual trajectories traced out by the FLEET signal are indicative of the characteristic turbulent behavior in this region of the flow, where the unsteadiness increases demonstrably as the wall is approached. Mean velocities taken within the boundary layer are in agreement with theoretical velocity profiles, though the fluctuating velocities exhibit a greater deviation from theoretical predictions.

  9. Investigation of the hydrochlorination of SiCl4

    NASA Technical Reports Server (NTRS)

    Mui, J. Y. P.

    1982-01-01

    A research and development program on the hydrochlorination of silicon tetrachloride and metallurgical grade (m.g.) silicon metal to trichlorosilane was carried out as scheduled. Effects of pressure and temperature on this reaction are reported. The presence of HCl in the reaction product mixture was successfully analyzed. Approximately 0.1% to 0.5% HCl based on total chlorosilanes were produced by the hydrochlorination reaction. Experiments on the corrosion study were carried out to evaluate a variety of metals and alloys as the material of construction for the hydrochlorination reactor. Material includes carbon steel, nickel, copper, Alloy 400 (Monel), stainless steel (Type 304), Incoloy 800H and Hastelloy B-2. The corrosion test was carried out at reaction temperature of 500 C, pressure of 300 psig and H2/SiCl4 feed ratio of 2.0 for a total of 87 hours. Results of the corrosion test show that all the test samples achieved a weigh gain.

  10. Performance and Operational Characteristics of a Python Turbine-propeller Engine at Simulated Altitude Conditions / Carl L. Meyer and Lavern A. Johnson

    NASA Technical Reports Server (NTRS)

    Meyer, Carl L; Johnson, Lavern A

    1952-01-01

    The performance and operational characteristics of a Python turbine-propeller engine were investigated at simulated altitude conditions in the NACA Lewis altitude wind tunnel. In the performance phase, data were obtained over a range of engine speeds and exhaust nozzle areas at altitudes from 10,000 to 40,000 feet at a single cowl-inlet ram pressure ratio; independent control of engine speed and fuel flow was used to obtain a range of powers at each engine speed. Engine performance data obtained at a given altitude could not be used to predict performance accurately at other altitudes by use of the standard air pressure and temperature generalizing factors. At a given engine speed and turbine-inlet total temperature, a greater portion of the total available energy was converted to propulsive power as the altitude increased.

  11. Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Thomas G. Thompson Cruise in the Pacific Ocean

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sabine, C.L.; Key, R.M.; Hall, M.

    1999-08-01

    This data documentation discusses the procedures and methods used to measure total carbon dioxide (TCO2), total alkalinity (TALK), and radiocarbon (delta 14C), at hydrographic stations, as well as the underway partial pressure of CO2 (pCO2) during the R/V Thomas G. Thompson oceanographic cruise in the Pacific Ocean (Section P10). Conducted as part of the World Ocean Circulation Experiment (WOCE), the cruise began in Suva, Fiji, on October 5, 1993, and ended in Yokohama, Japan, on November 10, 1993. Measurements made along WOCE Section P10 included pressure, temperature, salinity [measured by conductivity temperature, and depth sensor (CTD)], bottle salinity, bottle oxygen,more » phosphate, nitrate, silicate, chlorofluorocarbons (CFC-11, CFC-12), TCO2, TALK, delta 14C, and underway pCO2.« less

  12. High pressure, temperature and time-dependent effects on enzymatic and microbial properties of fresh sugarcane juice.

    PubMed

    Chauhan, O P; Ravi, N; Roopa, N; Kumar, Sumeet; Raju, P S

    2017-11-01

    Efficacy of variable high pressure, temperature and time on the browning causing enzymes and microbial activities, which are major spoilage factors during preservation of sugarcane juice, was studied. The juice was processed at 200-600 MPa pressure for 2-8 min at 40 and 60 °C and their effect on polyphenol oxidase and peroxidase as well as microbiological quality in terms of total plate count, yeast and molds and total coliforms was studied. Application of high pressures were found to cause significant decrease in enzymatic and microbial activities. The effects were found to be significantly more pronounced at 60 °C as compared to 40 °C. Process time also caused significant ( p  < 0.05) negative effect on microbial and enzyme activities. The sugarcane juice treated at 600 MPa for 6 min at 60 °C was found sufficient to inactivate the microbial counts completely. Whereas, enzymes were found to be completely inactivated in the samples processed at 600 MPa for 8 min at 60 °C. A pressure of 600 MPa at 60 °C for 8 min could be applied during commercial preservation of sugarcane juice for getting complete inactivation of browning causing enzymes and spoilage causing microorganisms.

  13. Optimisation of shock absorber process parameters using failure mode and effect analysis and genetic algorithm

    NASA Astrophysics Data System (ADS)

    Mariajayaprakash, Arokiasamy; Senthilvelan, Thiyagarajan; Vivekananthan, Krishnapillai Ponnambal

    2013-07-01

    The various process parameters affecting the quality characteristics of the shock absorber during the process were identified using the Ishikawa diagram and by failure mode and effect analysis. The identified process parameters are welding process parameters (squeeze, heat control, wheel speed, and air pressure), damper sealing process parameters (load, hydraulic pressure, air pressure, and fixture height), washing process parameters (total alkalinity, temperature, pH value of rinsing water, and timing), and painting process parameters (flowability, coating thickness, pointage, and temperature). In this paper, the process parameters, namely, painting and washing process parameters, are optimized by Taguchi method. Though the defects are reasonably minimized by Taguchi method, in order to achieve zero defects during the processes, genetic algorithm technique is applied on the optimized parameters obtained by Taguchi method.

  14. Flammability limits of hydrated and anhydrous ethanol at reduced pressures in aeronautical applications.

    PubMed

    Coronado, Christian J R; Carvalho, João A; Andrade, José C; Mendiburu, Andrés Z; Cortez, Ely V; Carvalho, Felipe S; Gonçalves, Beatriz; Quintero, Juan C; Velásquez, Elkin I Gutiérrez; Silva, Marcos H; Santos, José C; Nascimento, Marco A R

    2014-09-15

    There is interest in finding the flammability limits of ethanol at reduced pressures for the future use of this biofuel in aeronautical applications taking into account typical commercial aviation altitude (<40,000 ft). The lower and upper flammability limits (LFL and UFL, respectively) for hydrated ethanol and anhydrous ethanol (92.6% and 99.5% p/p, respectively) were determined for a pressure of 101.3 kPa at temperatures between 0 and 200°C. A heating chamber with a spherical 20-l vessel was used. First, LFL and the UFL were determined as functions of temperature and atmospheric pressure to compare results with data published in the scientific literature. Second, after checking the veracity of the data obtained for standard atmospheric pressure, the work proceeded with reduced pressures in the same temperature range. 295 experiments were carried out in total; the first 80 were to calibrate the heating chamber and compare the results with those given in the published scientific literature. 215 experiments were performed both at atmospheric and reduced pressures. The results had a correlation with the values obtained for the LFL, but values for the UFL had some differences. With respect to the water content in ethanol, it was shown that the water vapor contained in the fuel can act as an inert substance, narrowing flammability. Copyright © 2014 Elsevier B.V. All rights reserved.

  15. Analysis and interpretation of variabilities in ozone and temperature fields

    NASA Technical Reports Server (NTRS)

    Chandra, S.

    1990-01-01

    The temporal and spatial variabilities were studied of short and long term fluctuations in stratospheric ozone and temperature at various pressure levels using several years of ozone, temperature, and solar flux data from Nimbus 4, Nimbus 7, and SME satellites. Some results are as follows: (1) the solar UV flux and various indices of solar activity indicate a strong period at about 5 months; (2) satellite total ozone observations were analyzed using 17 years of data from the Nimbus 4 BUV and the Nimbus 7 SBUV experiments, which show very similar seasonal variations and quasibiennial oscillation (QBO) with some indication of a 4 year component; and (3) the zonal characteristics of both the ozone and temperature trends were derived from ten years of total ozone and 50 mb temperature based on the Nimbus 7 TOMS measurements and the NMC analyses respectively.

  16. Spectral properties of gaseous uranium hexafluoride at high temperature

    NASA Technical Reports Server (NTRS)

    Krascella, N. L.

    1980-01-01

    A study to determine relative spectral emission and spectral absorption data for UF6-argon mixtures at elevated temperatures is discussed. These spectral data are required to assist in the theoretical analysis of radiation transport in the nuclear fuel-buffer gas region of a plasma core reactor. Relative emission measurements were made for UF6-argon mixtures over a range of temperatures from 650 to 1900 K and in the wavelength range from 600 to 5000 nanometers. All emission results were determined for a total pressure of 1.0 atm. Uranium hexafluoride partial pressures varied from about 3.5 to 12.7 mm Hg. Absorption measurements were attempted at 600, 625, 650 and 675 nanometers for a temperature of 1000 K. The uranium partial pressure for these determinations was 25 mm Hg. The results exhibit appreciable emission for hot UF6-argon mixtures at wavelengths between 600 and 1800 nanometers and no measurable absorption. The equipment used to evaluate the spectral properties of the UF6-argon mixtures included a plasma torch-optical plenum assembly, the monochromator, and the UF6 transfer system. Each is described.

  17. Expansion of high-temperature; high-pressure data set for coal gasification. Fifth quarterly report, September 28-December 28, 1985

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.

    1985-01-01

    During the fifth quarter, the gas mixing station for the high pressure reactor (HPR) system was completed. This station allows us to make reproducible binary mixtures of any two gases. It will be used for pyrolysis experiments in helium/nitrogen or oxygen/nitrogen and gasification experiments in helium/nitrogen or oxygen/nitrogen and gasification experiments in carbon dioxide/nitrogen. In addition, work began on modifications of the HPR system for high pressure (600 psig) operation. A limited amount of data was taken with the HPR system due to the modifications for the mixing station. However, the test plan experiments for pyrolysis in mixtures of heliummore » and nitrogen were completed. In general, there is a slightly higher yield of volatiles and lower yield of char as the helium content (heating rate) increases. A new technique for measuring char reactivity resulted from an Army SBIR program and was further developed under our other METC Contract. It has also been used to characterize chars generated under the current program. It was evident that the severity of the thermal treatment had a direct effect on char reactivity. In this regard, rapid heating to a relatively low temperature was most favorable while slow heating to a high temperature was least favorable. With regard to pressure effects on reactivity, our preliminary data indicated that higher pressures produce chars lower initial reactivity. A total of four experiments were done in the heated tube reactor (HTR) at 60 psig, 800/sup 0/C maximum tube temperature. The trends are the same as observed in the atmospheric pressure experiments for the same tube temperature and cold gas velocity. During the past quarter, a particle temperature (PT) model was under development for the high pressure entrained flow reactor (HPR). 5 refs., 5 figs.« less

  18. Microclimate and development of pressure ulcers and superficial skin changes.

    PubMed

    Yusuf, Saldy; Okuwa, Mayumi; Shigeta, Yoshie; Dai, Misako; Iuchi, Terumi; Rahman, Sulaiman; Usman, Awaluddin; Kasim, Sukmawati; Sugama, Junko; Nakatani, Toshio; Sanada, Hiromi

    2015-02-01

    This study aims to evaluate the microclimate and development of pressure ulcers and superficial skin changes. A prospective cohort study was conducted in an acute care ward in Indonesia. Risk factors for pressure ulcers and superficial skin changes were identified based on the Bergstrom Braden conceptual model. Microclimate data were collected every 3 days for 15 days while the development of pressure ulcers and superficial skin changes was observed every day. Pressure ulcers and superficial skin changes were developed in 20 of the 71 participants. Total mean difference in skin temperature was higher for patients with pressure ulcers and superficial skin changes (0·9 ± 0·6°C) compared with controls (0·6 ± 0·8°C) (P = 0·071). Binary logistic regression predictor values for pressure ulcers and superficial skin changes were 0·111 for type of sheet and 0·347 for Braden Scale results. In conclusion, difference in skin temperature seems to be a predictor for pressure ulcer development and superficial skin changes, while synthetic fibre sheets are able to maintain a beneficial microclimate. © 2013 The Authors. International Wound Journal © 2013 Medicalhelplines.com Inc and John Wiley & Sons Ltd.

  19. Stability of rhombohedral phases in vanadium at high-pressure and high-temperature: first-principles investigations

    NASA Astrophysics Data System (ADS)

    Wang, Yi X.; Wu, Q.; Chen, Xiang R.; Geng, Hua Y.

    2016-09-01

    The pressure-induced transition of vanadium from BCC to rhombohedral structures is unique and intriguing among transition metals. In this work, the stability of these phases is revisited by using density functional theory. At finite temperatures, a novel transition of rhombohedral phases back to BCC phase induced by thermal electrons is discovered. This reentrant transition is found not driven by phonons, instead it is the electronic entropy that stabilizes the latter phase, which is totally out of expectation. Parallel to this transition, we find a peculiar and strong increase of the shear modulus C44 with increasing temperature. It is counter-intuitive in the sense that it suggests an unusual harding mechanism of vanadium by temperature. With these stability analyses, the high-pressure and finite-temperature phase diagram of vanadium is proposed. Furthermore, the dependence of the stability of RH phases on the Fermi energy and chemical environment is investigated. The results demonstrate that the position of the Fermi level has a significant impact on the phase stability, and follows the band-filling argument. Besides the Fermi surface nesting, we find that the localization/delocalization of the d orbitals also contributes to the instability of rhombohedral distortions in vanadium.

  20. Microscale and nanoscale strain mapping techniques applied to creep of rocks

    NASA Astrophysics Data System (ADS)

    Quintanilla-Terminel, Alejandra; Zimmerman, Mark E.; Evans, Brian; Kohlstedt, David L.

    2017-07-01

    Usually several deformation mechanisms interact to accommodate plastic deformation. Quantifying the contribution of each to the total strain is necessary to bridge the gaps from observations of microstructures, to geomechanical descriptions, to extrapolating from laboratory data to field observations. Here, we describe the experimental and computational techniques involved in microscale strain mapping (MSSM), which allows strain produced during high-pressure, high-temperature deformation experiments to be tracked with high resolution. MSSM relies on the analysis of the relative displacement of initially regularly spaced markers after deformation. We present two lithography techniques used to pattern rock substrates at different scales: photolithography and electron-beam lithography. Further, we discuss the challenges of applying the MSSM technique to samples used in high-temperature and high-pressure experiments. We applied the MSSM technique to a study of strain partitioning during creep of Carrara marble and grain boundary sliding in San Carlos olivine, synthetic forsterite, and Solnhofen limestone at a confining pressure, Pc, of 300 MPa and homologous temperatures, T/Tm, of 0.3 to 0.6. The MSSM technique works very well up to temperatures of 700 °C. The experimental developments described here show promising results for higher-temperature applications.

  1. Modification of a liquid hydrogen tank for integrated refrigeration and storage

    NASA Astrophysics Data System (ADS)

    Swanger, A. M.; Jumper, K. M.; Fesmire, J. E.; Notardonato, W. U.

    2015-12-01

    The modification and outfitting of a 125,000-liter liquid hydrogen tank was performed to provide integrated refrigeration and storage capability. These functions include zero boil-off, liquefaction, and densification and therefore require provisions for sub-atmospheric tank pressures within the vacuum-jacketed, multilayer insulated tank. The primary structural modification was to add stiffening rings inside the inner vessel. The internal stiffening rings were designed, built, and installed per the ASME Boiler and Pressure Vessel Code, Section VIII, to prevent collapse in the case of vacuum jacket failure in combination with sub-atmospheric pressure within the tank. For the integrated refrigeration loop, a modular, skeleton-type heat exchanger, with refrigerant temperature instrumentation, was constructed using the stiffening rings as supports. To support the system thermal performance testing, three custom temperature rakes were designed and installed along the 21-meter length of the tank, once again using rings as supports. The temperature rakes included a total of 20 silicon diode temperature sensors mounted both vertically and radially to map the bulk liquid temperature within the tank. The tank modifications were successful and the system is now operational for the research and development of integrated refrigeration technology.

  2. Atmospheric Pressure and Onset of Episodes of Menière’s Disease - A Repeated Measures Study

    PubMed Central

    Strobl, Ralf; Heinlin, Nina; Krause, Eike; Olzowy, Bernhard; Koppe, Christina; Grill, Eva

    2016-01-01

    Background External changes of air pressure are transmitted to the middle and inner ear and may be used therapeutically in Menière’s disease, one of the most common vertigo disorders. We analyzed the possible relationship of atmospheric pressure and other meteorological parameters with the onset of MD vertigo episodes in order to determine whether atmospheric pressure changes play a role in the occurrence of MD episodes. Methods Patients of a tertiary outpatient dizziness clinic diagnosed with MD were asked to keep a daily vertigo diary to document MD episodes (2004–2009). Local air pressure, absolute temperature and dew point temperature were acquired on an hourly basis. Change in meteorological parameters was conceptualized as the maximum difference in a 24 hour time frame preceding each day. Effects were estimated using additive mixed models with a random participant effect. We included lagged air parameters, age, sex, weekday and season in the model. Results A total of 56 persons (59% female) with mean age 54 years were included. Mean follow-up time was 267 days. Persons experienced on average 10.3 episodes during the observation period (median 8). Age and change in air pressure were significantly associated with vertigo onset risk (Odds Ratio = 0.979 and 1.010). We could not show an effect of sex, weekday, season, air temperature, and dew point temperature. Conclusions Change in air pressure was significantly associated with onset of MD episodes, suggesting a potential triggering mechanism in the inner ear. MD patients may possibly use air pressure changes as an early warning system for vertigo attacks in the future. PMID:27096752

  3. Time-dependent local and average structural evolution of δ-phase 239Pu-Ga alloys

    DOE PAGES

    Smith, Alice I.; Page, Katharine L.; Siewenie, Joan E.; ...

    2016-08-05

    Here, plutonium metal is a very unusual element, exhibiting six allotropes at ambient pressure, between room temperature and its melting point, a complicated phase diagram, and a complex electronic structure. Many phases of plutonium metal are unstable with changes in temperature, pressure, chemical additions, or time. This strongly affects structure and properties, and becomes of high importance, particularly when considering effects on structural integrity over long periods of time [1]. This paper presents a time-dependent neutron total scattering study of the local and average structure of naturally aging δ-phase 239Pu-Ga alloys, together with preliminary results on neutron tomography characterization.

  4. Oxidation kinetics of a continuous carbon phase in a nonreactive matrix

    NASA Technical Reports Server (NTRS)

    Eckel, Andrew J.; Cawley, James D.; Parthasarathy, Triplicane A.

    1995-01-01

    Analytical solutions of and experimental results on the oxidation kinetics of carbon in a pore are presented. Reaction rate, reaction sequence, oxidant partial pressure, total system pressure, pore/crack dimensions, and temperature are analyzed with respect to the influence of each on an overall linear-parabolic rate relationship. Direct measurement of carbon recession is performed using two microcomposite model systems oxidized in the temperature range of 700 to 1200 C, and for times to 35 h. Experimental results are evaluated using the derived analytical solutions. Implications on the oxidation resistance of continuous-fiber-reinforced ceramic-matrix composites containing a carbon constituent are discussed.

  5. Conversion of laser energy to gas kinetic energy

    NASA Technical Reports Server (NTRS)

    Caledonia, G. E.

    1976-01-01

    Techniques for the gas phase absorption of laser radiation for ultimate conversion to gas kinetic energy are discussed. Particular emphasis is placed on absorption by the vibration rotation bands of diatomic molecules at high pressures. This high pressure absorption appears to offer efficient conversion of laser energy to gas translational energy. Bleaching and chemical effects are minimized and the variation of the total absorption coefficient with temperature is minimal.

  6. Hot gas ingestion test results of a two-poster vectored thrust concept with flow visualization in the NASA Lewis 9- by 15-foot low speed wind tunnel

    NASA Technical Reports Server (NTRS)

    Johns, Albert L.; Neiner, George; Bencic, Timothy J.; Flood, Joseph D.; Amuedo, Kurt C.

    1990-01-01

    A 9.2 percent scale STOVL hot gas ingestion model was tested in the NASA Lewis 9 x 15-foot Low-Speed Wind Tunnel. Flow visualization from the Phase 1 test program, which evaluated the hot ingestion phenomena and control techniques, is covered. The Phase 2 test program evaluated the hot gas ingestion phenomena at higher temperatures and used a laser sheet to investigate the flow field. Hot gas ingestion levels were measured for the several forward nozzle splay configurations and with flow control/life improvement devices (LIDs) which reduced the hot gas ingestion. The test was conducted at full scale nozzle pressure ratios and inlet Mach numbers. Results are presented over a range of nozzle pressure ratios at a 10 kn headwind velocity. The Phase 2 program was conducted at exhaust nozzle temperatures up to 1460 R and utilized a sheet laser system for flow visualization of the model flow field in and out of ground effects. The results reported are for nozzle exhaust temperatures up to 1160 R and contain the compressor face pressure and temperature distortions, the total pressure recovery, the inlet temperature rise, and the environmental effects of the hot gas. The environmental effects include the ground plane contours, the model airframe heating, and the location of the ground flow separation.

  7. Magnetism of Amorphous and Nano-Crystallized Dc-Sputter-Deposited MgO Thin Films

    PubMed Central

    Mahadeva, Sreekanth K.; Fan, Jincheng; Biswas, Anis; Sreelatha, K.S.; Belova, Lyubov; Rao, K.V.

    2013-01-01

    We report a systematic study of room-temperature ferromagnetism (RTFM) in pristine MgO thin films in their amorphous and nano-crystalline states. The as deposited dc-sputtered films of pristine MgO on Si substrates using a metallic Mg target in an O2 containing working gas atmosphere of (N2 + O2) are found to be X-ray amorphous. All these films obtained with oxygen partial pressure (PO2) ~10% to 80% while maintaining the same total pressure of the working gas are found to be ferromagnetic at room temperature. The room temperature saturation magnetization (MS) value of 2.68 emu/cm3 obtained for the MgO film deposited in PO2 of 10% increases to 9.62 emu/cm3 for film deposited at PO2 of 40%. However, the MS values decrease steadily for further increase of oxygen partial pressure during deposition. On thermal annealing at temperatures in the range 600 to 800 °C, the films become nanocrystalline and as the crystallite size grows with longer annealing times and higher temperature, MS decreases. Our study clearly points out that it is possible to tailor the magnetic properties of thin films of MgO. The room temperature ferromagnetism in MgO films is attributed to the presence of Mg cation vacancies. PMID:28348346

  8. Preparation and Dynamic Mechanical Properties at Elevated Temperatures of a Tungsten/Glass Composite

    NASA Astrophysics Data System (ADS)

    Gao, Chong; Wang, Yingchun; Ma, Xueya; Liu, Keyi; Wang, Yubing; Li, Shukui; Cheng, Xingwang

    2018-03-01

    Experiments were conducted to prepare a borosilicate glass matrix composite containing 50 vol.% tungsten and examine its dynamic compressive behavior at elevated temperatures in the range of 450-775 °C. The results show that the homogenous microstructure of the tungsten/glass composite with relative density of 97% can be obtained by hot-pressing sintering at 800 °C for 1 h under pressure of 30 MPa. Dynamic compressive testing was carried out by a separate Hopkinson pressure bar system with a synchronous device. The results show that the peak stress decreases and the composite transforms from brittle to ductile in nature with testing temperature increasing from 450 to 750 °C. The brittle-ductile transition temperature is about 500 °C. Over 775 °C, the composite loses load-bearing capacity totally because of the excessive softening of the glass phase. In addition, the deformation and failure mechanism were analyzed.

  9. Inter-annual dynamics of the Barents Sea red king crab (Paralithodes camtschaticus) stock indices in relation to environmental factors

    NASA Astrophysics Data System (ADS)

    Dvoretsky, Alexander G.; Dvoretsky, Vladimir G.

    2016-12-01

    Knowledge of relationships between environmental variables and biological processes can greatly improve fisheries assessment and management in commercially important species. We analyzed the effects of environmental factors (climatic indices and water temperature) on the stock characteristics (total population number, number of pre-recruits and number of legal males) of the red king crab (Paralithodes camtschaticus), an introduced species in the Barents Sea. Stock trends in red king crab appear to be related to decadal climate shifts. Abundances were negatively related to the North Atlantic Oscillation index (NAO) in August and positively related to water temperature in late winter-early summer. Total and commercial stock abundance were negatively correlated with the lag-1 Arctic Oscillation index (AO) in August and the lag-2 winter NAO index. The total number of P. camtschaticus was most strongly associated with water temperature in spring and summer and NAO/AO indices in April and May. Lagged NAO indices in February and August (9 or 10 yr) had a positive relationship to the commercial stock of P. camtschaticus. These findings suggest that temperature conditions of current and previous year affect natural mortality of larvae and juvenile red king crabs. Warmer temperature conditions lead to increased biomass of red king crab food items. Negative correlations between climatic indices and the red king crab stocks may be associated with predator pressure on juvenile red king crabs or higher mortality because of predator or parasite pressure and diseases. The associations between stock indices and environmental variables could help better predict recruitment patterns of P. camtschaticus.

  10. Effects of ambient temperature and water vapor on chamber pressure and oxygen level during low atmospheric pressure stunning of poultry.

    PubMed

    Holloway, Paul H; Pritchard, David G

    2017-08-01

    The characteristics of the vacuum used in a low atmospheric pressure stunning system to stun (render unconscious) poultry prior to slaughter are described. A vacuum chamber is pumped by a wet screw compressor. The vacuum pressure is reduced from ambient atmospheric pressure to an absolute vacuum pressure of ∼250 Torr (∼33 kPa) in ∼67 sec with the vacuum gate valve fully open. At ∼250 Torr, the sliding gate valve is partially closed to reduce effective pumping speed, resulting in a slower rate of decreasing pressure. Ambient temperature affects air density and water vapor pressure and thereby oxygen levels and the time at the minimum total pressure of ∼160 Torr (∼21 kPa) is varied from ∼120 to ∼220 sec to ensure an effective stun within the 280 seconds of each cycle. The reduction in total pressure results in a gradual reduction of oxygen partial pressure that was measured by a solid-state electrochemical oxygen sensor. The reduced oxygen pressure leads to hypoxia, which is recognized as a humane method of stunning poultry. The system maintains an oxygen concentration of <5% for at least 2 minutes, which ensures that birds are irreversibly stunned. Calculated pump down (pressure versus time) data match experimental data very closely because the programmable logic controller and the human machine interface enable precise and accurate control. The vacuum system operates in the turbulent viscous flow regime, and is best characterized by absolute vacuum pressure rather than gauge pressure. Neither the presence of broiler chickens nor different fore-line pipe designs of four parallel commercial systems affected the pressure-time data. Water in wet air always reduces the oxygen concentrations to a value lower than in dry air. The partial pressure of water and oxygen were found to depend on the pump down parameters due to the formation of fog in the chamber and desorption of water from the birds and the walls of the vacuum chamber. © The Author 2017. Published by Oxford University Press on behalf of Poultry Science Association.

  11. Effects of ambient temperature and water vapor on chamber pressure and oxygen level during low atmospheric pressure stunning of poultry

    PubMed Central

    Holloway, Paul H.; Pritchard, David G.

    2017-01-01

    Abstract The characteristics of the vacuum used in a low atmospheric pressure stunning system to stun (render unconscious) poultry prior to slaughter are described. A vacuum chamber is pumped by a wet screw compressor. The vacuum pressure is reduced from ambient atmospheric pressure to an absolute vacuum pressure of ∼250 Torr (∼33 kPa) in ∼67 sec with the vacuum gate valve fully open. At ∼250 Torr, the sliding gate valve is partially closed to reduce effective pumping speed, resulting in a slower rate of decreasing pressure. Ambient temperature affects air density and water vapor pressure and thereby oxygen levels and the time at the minimum total pressure of ∼160 Torr (∼21 kPa) is varied from ∼120 to ∼220 sec to ensure an effective stun within the 280 seconds of each cycle. The reduction in total pressure results in a gradual reduction of oxygen partial pressure that was measured by a solid-state electrochemical oxygen sensor. The reduced oxygen pressure leads to hypoxia, which is recognized as a humane method of stunning poultry. The system maintains an oxygen concentration of <5% for at least 2 minutes, which ensures that birds are irreversibly stunned. Calculated pump down (pressure versus time) data match experimental data very closely because the programmable logic controller and the human machine interface enable precise and accurate control. The vacuum system operates in the turbulent viscous flow regime, and is best characterized by absolute vacuum pressure rather than gauge pressure. Neither the presence of broiler chickens nor different fore-line pipe designs of four parallel commercial systems affected the pressure-time data. Water in wet air always reduces the oxygen concentrations to a value lower than in dry air. The partial pressure of water and oxygen were found to depend on the pump down parameters due to the formation of fog in the chamber and desorption of water from the birds and the walls of the vacuum chamber. PMID:28521045

  12. Total fluid pressure imbalance in the scrape-off layer of tokamak plasmas

    NASA Astrophysics Data System (ADS)

    Churchill, R. M.; Canik, J. M.; Chang, C. S.; Hager, R.; Leonard, A. W.; Maingi, R.; Nazikian, R.; Stotler, D. P.

    2017-04-01

    Simulations using the fully kinetic neoclassical code XGCa (X-point included guiding- center axisymmetric) were undertaken to explore the impact of kinetic effects on scrape-off layer (SOL) physics in DIII-D H-mode plasmas. XGCa is a total-f, gyrokinetic code which self-consistently calculates the axisymmetric electrostatic potential and plasma dynamics, and includes modules for Monte Carlo neutral transport. Previously presented XGCa results showed several noteworthy features, including large variations of ion density and pressure along field lines in the SOL, experimentally relevant levels of SOL parallel ion flow (Mach number  ˜ 0.5), skewed ion distributions near the sheath entrance leading to subsonic flow there, and elevated sheath potentials (Churchill 2016 Nucl. Mater. Energy 1-6). In this paper, we explore in detail the question of pressure balance in the SOL, as it was observed in the simulation that there was a large deviation from a simple total pressure balance (the sum of ion and electron static pressure plus ion inertia). It will be shown that both the contributions from the ion viscosity (driven by ion temperature anisotropy) and neutral source terms can be substantial, and should be retained in the parallel momentum equation in the SOL, but still falls short of accounting for the observed fluid pressure imbalance in the XGCa simulation results.

  13. Numerical prediction of micro-channel LD heat sink operated with antifreeze based on CFD method

    NASA Astrophysics Data System (ADS)

    Liu, Gang; Liu, Yang; Wang, Chao; Wang, Wentao; Wang, Gang; Tang, Xiaojun

    2014-12-01

    To theoretically study the feasibility of antifreeze coolants applied as cooling fluids for high power LD heat sink, detailed Computational Fluid Dynamics (CFD) analysis of liquid cooled micro-channels heat sinks is presented. The performance operated with antifreeze coolant (ethylene glycol aqueous solution) compared with pure water are numerical calculated for the heat sinks with the same micro-channels structures. The maximum thermal resistance, total pressure loss (flow resistance), thermal resistance vs. flow-rate, and pressure loss vs. flow-rate etc. characteristics are numerical calculated. The results indicate that the type and temperature of coolants plays an important role on the performance of heat sinks. The whole thermal resistance and pressure loss of heat sinks increase significantly with antifreeze coolants compared with pure water mainly due to its relatively lower thermal conductivity and higher fluid viscosity. The thermal resistance and pressure loss are functions of the flow rate and operation temperature. Increasing of the coolant flow rate can reduce the thermal resistance of heat sinks; meanwhile increase the pressure loss significantly. The thermal resistance tends to a limit with increasing flow rate, while the pressure loss tends to increase exponentially with increasing flow rate. Low operation temperature chiefly increases the pressure loss rather than thermal resistance due to the remarkable increasing of fluid viscosity. The actual working point of the cooling circulation system can be determined on the basis of the pressure drop vs. flow rate curve for the micro-channel heat sink and that for the circulation system. In the same system, if the type or/and temperature of the coolant is changed, the working point is accordingly influenced, that is, working flow rate and pressure is changed simultaneously, due to which the heat sink performance is influenced. According to the numerical simulation results, if ethylene glycol aqueous solution is applied instead of pure water as the coolant under the same or a higher working temperature, the available output of optical power will decrease due to the worse heat sink performance; if applied under a lower working temperature(0 °C, -20 °C), although the heat sink performance become worse, however the temperature difference of heat transfer rises more significantly, the available output of optical power will increase on the contrary.

  14. The effect of catalyst length and downstream reactor distance on catalytic combustor performance

    NASA Technical Reports Server (NTRS)

    Anderson, D.

    1980-01-01

    A study was made to determine the effects on catalytic combustor performance which resulted from independently varying the length of a catalytic reactor and the length available for gas-phase reactions downstream of the catalyst. Monolithic combustion catalysts from three manufacturers were tested in a combustion test rig with no. 2 diesel fuel. Catalytic reactor lengths of 2.5 and 5.4 cm, and downstream gas-phase reaction distances of 7.3, 12.4, 17.5, and 22.5 cm were evaluated. Measurements of carbon monoxide, unburned hydrocarbons, nitrogen oxides, and pressure drop were made. The catalytic-reactor pressure drop was less than 1 percent of the upstream total pressure for all test configurations and test conditions. Nitrogen oxides and unburned hydrocarbons emissions were less than 0.25 g NO2/kg fuel and 0.6 g HC/kg fuel, respectively. The minimum operating temperature (defined as the adiabatic combustion temperature required to obtain carbon monoxide emissions below a reference level of 13.6 g CO/kg fuel) ranged from 1230 K to 1500 K for the various conditions and configurations tested. The minimum operating temperature decreased with increasing total (catalytic-reactor-plus-downstream-gas-phase-reactor-zone) residence time but was independent of the relative times spent in each region when the catalytic-reactor residence time was greater than or equal to 1.4 ms.

  15. Pressure Profiles in a Loop Heat Pipe Under Gravity Influence

    NASA Technical Reports Server (NTRS)

    Ku, Jentung

    2015-01-01

    During the operation of a loop heat pipe (LHP), the viscous flow induces pressure drops in various elements of the loop. The total pressure drop is equal to the sum of pressure drops in vapor grooves, vapor line, condenser, liquid line and primary wick, and is sustained by menisci at liquid and vapor interfaces on the outer surface of the primary wick in the evaporator. The menisci will curve naturally so that the resulting capillary pressure matches the total pressure drop. In ground testing, an additional gravitational pressure head may be present and must be included in the total pressure drop when LHP components are placed in a non-planar configuration. Under gravity-neutral and anti-gravity conditions, the fluid circulation in the LHP is driven solely by the capillary force. With gravity assist, however, the flow circulation can be driven by the combination of capillary and gravitational forces, or by the gravitational force alone. For a gravity-assist LHP at a given elevation between the horizontal condenser and evaporator, there exists a threshold heat load below which the LHP operation is gravity driven and above which the LHP operation is capillary force and gravity co-driven. The gravitational pressure head can have profound effects on the LHP operation, and such effects depend on the elevation, evaporator heat load, and condenser sink temperature. This paper presents a theoretical study on LHP operations under gravity neutral, anti-gravity, and gravity-assist modes using pressure diagrams to help understand the underlying physical processes. Effects of the condenser configuration on the gravitational pressure head and LHP operation are also discussed.

  16. Pressure Profiles in a Loop Heat Pipe under Gravity Influence

    NASA Technical Reports Server (NTRS)

    Ku, Jentung

    2015-01-01

    During the operation of a loop heat pipe (LHP), the viscous flow induces pressure drops in various elements of the loop. The total pressure drop is equal to the sum of pressure drops in vapor grooves, vapor line, condenser, liquid line and primary wick, and is sustained by menisci at liquid and vapor interfaces on the outer surface of the primary wick in the evaporator. The menisci will curve naturally so that the resulting capillary pressure matches the total pressure drop. In ground testing, an additional gravitational pressure head may be present and must be included in the total pressure drop when LHP components are placed in a non-planar configuration. Under gravity-neutral and anti-gravity conditions, the fluid circulation in the LHP is driven solely by the capillary force. With gravity assist, however, the flow circulation can be driven by the combination of capillary and gravitational forces, or by the gravitational force alone. For a gravity-assist LHP at a given elevation between the horizontal condenser and evaporator, there exists a threshold heat load below which the LHP operation is gravity driven and above which the LHP operation is capillary force and gravity co-driven. The gravitational pressure head can have profound effects on the LHP operation, and such effects depend on the elevation, evaporator heat load, and condenser sink temperature. This paper presents a theoretical study on LHP operations under gravity-neutral, anti-gravity, and gravity-assist modes using pressure diagrams to help understand the underlying physical processes. Effects of the condenser configuration on the gravitational pressure head and LHP operation are also discussed.

  17. Measurements of Tc (Q,P): Depression of the Superfluid Transition Temperature by a Heat Current Along the Lambda Line

    NASA Technical Reports Server (NTRS)

    Liu, Yuan-Ming; Larson, Melora; Israelsson, Ulf

    1999-01-01

    We report experimental measurements of Tc (Q,P) for heat currents (Q) between I1and 100 micro W/sq cm and pressure (P) between SVP and 15 bar. The measurements were performed in a normal gravity environment, using the low-gravity simulator facility at JPL without the magnet being energized. The sample pressure was controlled to 0.1 micro bar using a hot volume, and a Straty-Adams capacitive pressure gauge. The total volume of helium in the sample cell and the hot volume was held constant using a pneumatic low temperature valve. A melting curve thermometer (MCT) measured the transition temperature (Tc) with a resolution of about 10 nK through a sidewall probe of the thermal conductivity sample cell. We employed the same measurement technique and procedure described by DAS. Preliminary results indicate that Tc (Q,P) depends very little on the pressure in the pressure range between SVP and 15 bar with a variation in the amplitude of Tc(Q,P) of less than about 5% observable in this pressure range. According to the Renormalization-group theory calculation by Haussmann and Dohm, the amplitude of Tc (Q,P) has a leading pressure-dependence term proportional to xi(sub 0) (sup (1/nu)), where xi(sub 0) is the correlation-length amplitude and nu is the correlation-length exponent. Thus, a small pressure dependence of the amplitude of Tc (Q,P) is expected since xi(sub 0) is very weakly dependent on pressure between SVP and 15 bar, consistent with our measurements.

  18. Application of Pressure Sensitive Paint to Confined Flow at Mach Number 2.5

    NASA Technical Reports Server (NTRS)

    Lepicovsky, J.; Bencic, T. J.; Bruckner, R. J.

    1998-01-01

    Pressure sensitive paint (PSP) is a novel technology that is being used frequently in external aerodynamics. For internal flows in narrow channels, and applications at elevated nonuniform temperatures, however, there are still unresolved problems that complicate the procedures for calibrating PSP signals. To address some of these problems, investigations were carried out in a narrow channel with supersonic flows of Mach 2.5. The first set of tests focused on the distribution of the wall pressure in the diverging section of the test channel downstream of the nozzle throat. The second set dealt with the distribution of wall static pressure due to the shock/wall interaction caused by a 25 deg. wedge in the constant Mach number part of the test section. In addition, the total temperature of the flow was varied to assess the effects of temperature on the PSP signal. Finally, contamination of the pressure field data, caused by internal reflection of the PSP signal in a narrow channel, was demonstrated. The local wall pressures were measured with static taps, and the wall pressure distributions were acquired by using PSP. The PSP results gave excellent qualitative impressions of the pressure field investigated. However, the quantitative results, specifically the accuracy of the PSP data in narrow channels, show that improvements need to be made in the calibration procedures, particularly for heated flows. In the cases investigated, the experimental error had a standard deviation of +/- 8.0% for the unheated flow, and +/- 16.0% for the heated flow, at an average pressure of 11 kpa.

  19. Experimental short-duration techniques. [gas turbine engine tests

    NASA Technical Reports Server (NTRS)

    Dunn, Michael G.

    1986-01-01

    Short-duration facilities used for gas turbine studies are described. Data recording techniques; and instruments (thin-film heat flux gages, high-frequency response pressure measurements, total temperature probes, measurement of rotor tip speed, active measurement of tip clearance) are presented.

  20. Flow Quality Surveys in the Settling Chamber of the NASA Glenn Icing Research Tunnel (2011 Tests)

    NASA Technical Reports Server (NTRS)

    Steen, Laura E.; Van Zante, Judith Foss; Broeren, Andy P.; Kubiak, Mark J.

    2012-01-01

    In 2011, the heat exchanger and refrigeration plant for NASA Glenn Research Center's Icing Research Tunnel (IRT) were upgraded. Flow quality surveys were performed in the settling chamber of the IRT in order to understand the effect that the new heat exchanger had on the flow quality upstream of the spray bars. Measurements were made of the total pressure, static pressure, total temperature, airspeed, and ow angle (pitch and yaw). These measurements were directly compared to measurements taken in 2000, after the previous heat exchanger was installed. In general, the flow quality appears to have improved with the new heat exchanger.

  1. Flow Quality Surveys in the Settling Chamber of the NASA Glenn Icing Research Tunnel (2011 Tests)

    NASA Technical Reports Server (NTRS)

    Steen, Laura E.; VanZante, Judith Foss; Broeren, Andy P.; Kubiak, Mark J.

    2012-01-01

    In 2011, the heat exchanger and refrigeration plant for NASA Glenn Research Center's Icing Research Tunnel (IRT) were upgraded. Flow quality surveys were performed in the settling chamber of the IRT in order to understand the effect that the new heat exchanger had on the flow quality upstream of the spray bars. Measurements were made of the total pressure, static pressure, total temperature, airspeed, and flow angle (pitch and yaw). These measurements were directly compared to measurements taken in 2000, after the previous heat exchanger was installed. In general, the flow quality appears to have improved with the new heat exchanger.

  2. Flow Quality Surveys in the Settling Chamber of the NASA Glenn Icing Research Tunnel (2011 Tests)

    NASA Technical Reports Server (NTRS)

    Steen, Laura E.; VanZante, Judith Foss; Broeren, Andy P.; Kubiak, Mark J.

    2014-01-01

    In 2011, the heat exchanger and refrigeration plant for NASA Glenn Research Centers Icing Research Tunnel (IRT) were upgraded. Flow quality surveys were performed in the settling chamber of the IRT in order to understand the effect that the new heat exchanger had on the flow quality upstream of the spray bars. Measurements were made of the total pressure, static pressure, total temperature, airspeed, and flow angle (pitch and yaw). These measurements were directly compared to measurements taken in 2000, after the previous heat exchanger was installed. In general, the flow quality appears to have improved with the new heat exchanger.

  3. Heat and mass transfer of a low-pressure Mars greenhouse: Simulation and experimental analysis

    NASA Astrophysics Data System (ADS)

    Hublitz, Inka

    Biological life support systems based on plant growth offer the advantage of producing fresh food for the crew during a long surface stay on Mars. Greenhouses on Mars are also used for air and water regeneration and waste treatment. A major challenge in developing a Mars greenhouse is its interaction with the thin and cold Mars environment. Operating a Mars greenhouse at low interior pressure reduces the pressure differential across the structure and therefore saves structural mass as well as reduces leakage. Experiments were conducted to analyze the heating requirements as well as the temperature and humidity distribution within a small-scale greenhouse that was placed in a chamber simulating the temperatures, pressure and light conditions on Mars. Lettuce plants were successfully grown inside of the Mars greenhouse for up to seven days. The greenhouse atmosphere parameters, including temperature, total pressure, oxygen and carbon dioxide concentration were controlled tightly; radiation level, relative humidity and plant evapo-transpiration rates were measured. A vertical stratification of temperature and humidity across the greenhouse atmosphere was observed. Condensation formed on the inside of the greenhouse when the shell temperature dropped below the dew-point. During the night cycles frost built up on the greenhouse base plate and the lower part of the shell. Heat loss increased significantly during the night cycle. Due to the placement of the heating system and the fan blowing warm air directly on the upper greenhouse shell, condensation above the plants was avoided and therefore the photosynthetically active radiation at plant level was kept constant. Plant growth was not affected by the temperature stratification due to the tight temperature control of the warmer upper section of the greenhouse, where the lettuce plants were placed. A steady state and a transient heat transfer model of the low pressure greenhouse were developed for the day and the night cycle. Furthermore, low pressure psychrometric relations for closed systems and modified atmospheres were generated to calculate the properties of the moist air in order to predict condensate formation. The results of this study improve the design of the environmental control system leading to an optimization of plant growth conditions.

  4. Experimental study of iron-chloride complexing in hydrothermal fluids

    USGS Publications Warehouse

    Fein, J.B.; Hemley, J.J.; d'Angelo, W. M.; Komninou, A.; Sverjensky, D.A.

    1992-01-01

    Mineral assemblage solubilities were measured in cold-seal pressure vessels as a function of pressure, temperature, and potassium chloride concentration in order to determine the nature and thermodynamic properties of iron-chloride complexes under hydrothermal conditions. The assemblage pyritepyrrhotite-magnetite was used to buffer f{hook}S2 and f{hook}O2, and K+ H+ ratios were buffered at reasonable geologic values using the assemblage potassium feldspar-muscovite (or andalusite)-quartz. The pressure-temperature ranges were 0.5-2.0 kbar and 300-600??C, and initial fluid compositions ranged from 0.01-2.0 molal KCl. With all other factors constant, the concentration of iron in solution increases with increasing temperature, with decreasing pressure, and with increasing total potassium chloride concentration. Changes in iron concentrations as a function of KCl concentration, in conjunction with charge balance, mass action, and mass balance constraints on the system, place constraints on the stoichiometry of the important iron-chloride complexes under each of the experimental conditions. Using least-squared linear regression fits to determine these slopes, the calculations yield values for the average ligand numbers that are in the range 1.2-1.9, with uncertainties ranging from ??0.1-0.6 at the several PT conditions considered. The slopes of the regressed fits to the data suggest that both FeCl+ and FeCl20 are important in the experimental fluids, with FeCl20 becoming dominant at the higher temperatures. Theoretical calculations, however, indicate that FeCl+ does not contribute significantly to the solubility. Because of the large uncertainties associated with some of the calculated average ligand numbers, we base our data analysis on the theoretical calculations. A statistical analysis is applied to the solubility data in order to determine the values and uncertainties of the dissociation constant for FeCl20 that best fit the data at each of the experimental pressures and temperatures. The calculated stability of FeCl20 increases with increasing temperature and total chloride concentration, and with decreasing pressure. The values of the dissociation constant of FeCl20that are calculated in this study are in moderately good agreement with FeCl20dissociation constants from other studies of iron-chloride complexing in supercritical fluids. Differences are likely due to different assumptions made concerning activity coefficients of aqueous species. Log kd values for full dissociation of FeCl20 at 0.5 kbar-300??C-and at 1 kbar-400, 500, and 600??C, respectively-are -3.75 ?? 0.40, -6.25 ?? 0.10, -9.19 ?? 0.44, and -13.29 ?? 0.09. ?? 1992.

  5. Excess air during aquifer storage and recovery in an arid basin (Las Vegas Valley, USA)

    NASA Astrophysics Data System (ADS)

    Solomon, D. Kip; Cole, Erin; Leising, Joseph F.

    2011-02-01

    The Las Vegas Valley Water District in Nevada, USA, has operated an artificial recharge (AR) program since 1989. In summer 2001, observations of gas exsolving from tap water prompted a study that revealed total dissolved gas (TDG) pressures approaching 2 atm with a gas composition that it is predominantly air. Measurements of TDG pressure at well heads and in the distribution system indicated two potential mechanisms for elevated TDG pressures: (1) air entrainment during AR operations, and (2) temperature changes between the winter recharge season and the summer withdrawal season. Air entrainment during pumping was investigated by intentionally allowing the forebay (upstream reservoir) of a large pumping station to drawdown to the point of vortex formation. This resulted in up to a 0.7 atm increase in TDG pressure. In general, the solubility of gases in water decreases as the temperature increases. In the Las Vegas Valley, water that acquired a modest amount of dissolved gas during winter artificial recharge operations experienced an increase in dissolved gas pressure (0.04 atm/°C) as the water warmed in the subsurface. A combination of air entrainment during AR operations and its amplification by temperature increase after recharge can account for most of the observed amounts of excess gas at this site.

  6. Finite-temperature H behaviors in tungsten and molybdenum: first-principles total energy and vibration spectrum calculations

    NASA Astrophysics Data System (ADS)

    Liu, Yue-Lin; Ding, Fang; Luo, G.-N.; Chen, Chang-An

    2017-12-01

    We have carried out systematic first-principles total energy and vibration spectrum calculations to investigate the finite-temperature H dissolution behaviors in tungsten and molybdenum, which are considered promising candidates for the first wall in nuclear fusion reactors. The temperature effect is considered by the lattice expansion and phonon vibration. We demonstrate that the H Gibbs energy of formation in both tetrahedral and octahedral interstitial positions depends strongly on the temperature. The H Gibbs energy of formation under one atmosphere of pressure increases significantly with increasing temperature. The phonon vibration contribution plays a decisive role in the H Gibbs energy of formation with the increasing temperature. Using the predicted H Gibbs energy of formation, our calculated H concentrations in both metals are about one or two orders of magnitude lower than the experimental data at temperature range from 900 to 2400 K. Such a discrepancy can be reasonably explained by the defect-capturing effect.

  7. Flow-field measurements in the windward surface shock layer of space shuttle orbiter configurations at Mach number 8. [wind tunnel tests of scale models

    NASA Technical Reports Server (NTRS)

    Martindale, W. R.; Carter, L. D.

    1975-01-01

    Pitot pressure and total-temperature measurements were made in the windward surface shock layer of two 0.0175-scale space shuttle orbiter models at simulated re-entry conditions. Corresponding surface static pressure measurements were also made. Flow properties at the edge of the model boundary layer were derived from these measurements and compared with values calculated using conventional methods.

  8. The Atmospheric Pressure and Temperature Seem to Have No Effect on the Incidence of Rupture of Abdominal Aortic Aneurysm in a Mid-European Region.

    PubMed

    Majd, Payman; Ahmad, Wael; Luebke, Thomas; Brunkwall, Jan Sigge

    2017-07-01

    This study aims to examine the relationship between weather changes (atmospheric pressure and temperature) and incidence of rupture of abdominal aortic aneurysm (AAA). All patients with ruptured infrarenal AAA and who were referred to our institution between August 1998 and August 2015 were prospectively entered into a database of which a retrospective review of a ruptured AAA was performed. The needed information about the daily atmospheric pressure and air temperature could be extracted from the meteorological unit in Cologne. During the study period (6,225 days), a total number of 154 patients with confirmed ruptured AAA were identified. Basic patients' characteristics are tabulated. The mean daily atmospheric pressure during the study was 1,004.04 ± 8.79 mBar ranging from 965.40-1031.80 mBar. The mean atmospheric pressure on the days of rupture was 1,004.03 vs. 1,004.68 on those days when no rupture occurred (P = 0.34). The mean atmospheric pressure on the day of rupture and that on the preceding day was not significantly different (1,004.78 vs. 1,005.44 with P = 0.13). The air temperature (10.62 ± 6.25 vs. 10.77 ± 6.83°C, P = 0.787) was equally distributed between days of rupture events and control days. The present study could not show a significant association between the monthly and seasonal difference in atmospheric pressure and the prevalence of AAA rupture as it has been supposed by previous studies. Copyright © 2017 Elsevier Inc. All rights reserved.

  9. THERMAL DECOMPOSITION OF PEROXYACETYL NITRATE AND REACTIONS OF ACETYL PEROXY RADICALS WITH NO AND NO2 OVER THE TEMPERATURE RANGE 283-313K

    EPA Science Inventory

    The thermal decomposition of peroxyacetyl nitrate (PAN) in NO-NO2-air (or N2) mixtures has been studied at 740 torr total pressure over the temperature range 283-313 K. he experimental data obtained yield a rate constant for the thermal decomposition of PAN of k3 = 2.52 x 1016 e-...

  10. On vertical profile of ozone at Syowa

    NASA Technical Reports Server (NTRS)

    Chubachi, Shigeru

    1994-01-01

    The difference in the vertical ozone profile at Syowa between 1966-1981 and 1982-1988 is shown. The month-height cross section of the slope of the linear regressions between ozone partial pressure and 100-mb temperature is also shown. The vertically integrated values of the slopes are in close agreement with the slopes calculated by linear regression of Dobson total ozone on 100-mb temperature in the period of 1982-1988.

  11. Characterization of Arab medium crude fractions with emphasis on kinematic viscosity - temperature behavior

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Beg, S.A.; Amin, M.B.; Hussain, I.

    1986-01-01

    Characterization of Arab medium Crude Oil, has been carried out in terms of API gravity, debutanized crude gravity, total sulfur content, Reid vapour pressure ash content, heating value, salt content, viscosity SUS, vanadium content as V/sub 2/O/sub 5/, pour point and analysis of various metals. Further, six true boiling point (TBP) fractions (IBP-95/sup 0/C, 95-205/sup 0/C, 205-260/sup 0/C, 260-345/sup 0/C, 345-455/sup 0/C and 455/sup 0/C+) of this crude were characterized in terms of API gravity, total sulfur contents H/sub 2/S content, mercaptons content, molecular weight, elemental analyses for total carbon, hydrogen and nitrogen, analyses of various metals and paraffin, aromaticmore » and naphthene contents of lighter fractions. The kinematic viscosity-temperature data have been obtained for 95/sup 0/C+ TBP fractions for a wide range of temperatures.« less

  12. Effect of high-pressure treatment at various temperatures on indigenous proteolytic enzymes and whey protein denaturation in bovine milk.

    PubMed

    Moatsou, Golfo; Bakopanos, Constantinos; Katharios, Dimitis; Katsaros, George; Kandarakis, Ioannis; Taoukis, Petros; Politis, Ioannis

    2008-08-01

    The objective of the present study was to determine the effect of high pressure (HP) processing (200, 450 and 650 MPa) at various temperatures (20, 40 and 55 degrees C) on the total plasmin plus plasminogen-derived activity (PL), plasminogen activator(s) (PA) and cathepsin D activities and on denaturation of major whey proteins in bovine milk. Data indicated that transfer of both PL and PA from the casein micelles to milk serum occurred at all pressures utilized at room temperature (20 degrees C). In addition to the transfer of PL and PA from micelles, there were reductions in activities of PL (16-18%) and PA (38-62%) for the pressures 450 and 650 MPa, at room temperature. There were synergistic negative effects between pressure and temperature on residual PL activity at 450 and 650 MPa and on residual PA activity only at 450 MPa. Cathepsin D activity in the acid whey from HP-treated milk was in general baroresistant at room temperature. The residual activity of cathepsin D decreased significantly at 650 MPa and 40 degrees C and at the pressures 450 and 650 MPa at 55 degrees C. Synergistic negative effects on the amount of native beta-lactoglobulin were observed at 450 and 650 MPa and on the amount of native alpha-lactalbumin at 650 MPa. There were significant correlations between enzymatic activities (PL, PA and cathepsin D) and the residual native beta-lactoglobulin and alpha-lactalbumin in bovine milk. In conclusion, HP significantly affected the activity of indigenous proteolytic enzymes and whey protein denaturation in bovine milk. Reduction in activity of indigenous enzymes (PL, PA and cathepsin D) and transfer of PL and PA from the casein to milk serum induced by HP is expected to have a profound effect on cheese yield, proteolysis during cheese ripening and quality of UHT milk during storage.

  13. 21 CFR 172.260 - Oxidized polyethylene.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... FOR HUMAN CONSUMPTION (CONTINUED) FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Coatings, Films and Related Substances § 172.260 Oxidized polyethylene. Oxidized polyethylene may... by high temperature vapor pressure osmometry; contains a maximum of 5 percent by weight of total...

  14. 21 CFR 172.260 - Oxidized polyethylene.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... FOR HUMAN CONSUMPTION (CONTINUED) FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Coatings, Films and Related Substances § 172.260 Oxidized polyethylene. Oxidized polyethylene may... by high temperature vapor pressure osmometry; contains a maximum of 5 percent by weight of total...

  15. 21 CFR 172.260 - Oxidized polyethylene.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... FOR HUMAN CONSUMPTION (CONTINUED) FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Coatings, Films and Related Substances § 172.260 Oxidized polyethylene. Oxidized polyethylene may... by high temperature vapor pressure osmometry; contains a maximum of 5 percent by weight of total...

  16. Unsteady Flow Field in a Multistage Axial Flow Compressor

    NASA Technical Reports Server (NTRS)

    Suryavamshi, N.; Lakshminarayana, B.; Prato, J.

    1997-01-01

    The flow field in a multistage compressor is three-dimensional, unsteady, and turbulent with substantial viscous effects. Some of the specific phenomena that has eluded designers include the effects of rotor-stator and rotor-rotor interactions and the physics of mixing of velocity, pressure, temperature and velocity fields. An attempt was made, to resolve experimentally, the unsteady pressure and temperature fields downstream of the second stator of a multistage axial flow compressor which will provide information on rotor-stator interaction effects and the nature of the unsteadiness in an embedded stator of a three stage axial flow compressor. Detailed area traverse measurements using pneumatic five hole probe, thermocouple probe, semi-conductor total pressure probe (Kulite) and an aspirating probe downstream of the second stator were conducted at the peak efficiency operating condition. The unsteady data was then reduced through an ensemble averaging technique which splits the signal into deterministic and unresolved components. Auto and cross correlation techniques were used to correlate the deterministic total temperature and velocity components (acquired using a slanted hot-film probe at the same measurement locations) and the gradients, distributions and relative weights of each of the terms of the average passage equation were then determined. Based on these measurements it was observed that the stator wakes, hub leakage flow region, casing endwall suction surface corner region, and the casing endwall region away from the blade surfaces were the regions of highest losses in total pressure, lowest efficiency and highest levels of unresolved unsteadiness. The deterministic unsteadiness was found to be high in the hub and casing endwall regions as well as on the pressure side of the stator wake. The spectral distribution of hot-wire and kulite voltages shows that at least eight harmonics of all three rotor blade passing frequencies are present at this measurement location. In addition to the basic three rotor blade passing frequencies (R1, R2 and R3) and their harmonics, various difference frequencies such as (2R1 -R2) and (2R3-R2) and their harmonics are also observed. These difference frequencies are due to viscous and potential interactions between rotors 1, 2 and 3 which are sensed by both the total pressure and aspirating probes at this location. Significant changes occur to the stator exit flow features with passage of the rotor upstream of the stator. Because of higher convection speeds of the rotor wake on the suction surface of the downstream stator than on the pressure side, the chopped rotor wake was found to be arriving at different times on either side of the stator wake. As the rotor passes across the stator.

  17. Simultaneous film and convection cooling of a plate inserted in the exhaust stream of a gas turbine combustor

    NASA Technical Reports Server (NTRS)

    Marek, C. J.; Juhasz, A. J.

    1973-01-01

    Data were obtained on a parallel-flow film- and convection-cooled test section placed in the exhaust stream of a rectangular-sector combustor. The combustor was operated at atmospheric pressure and at exhaust temperatures of 589 and 1033 K (600 and 1400 F). The cooling air was at ambient pressure and temperature. Test results indicate that it is better to use combined film and convection cooling rather than either film or convection cooling alone for a fixed total coolant flow. An optimum ratio of film to convection cooling flow rates was determined for the particular geometry tested. The experimental results compared well with calculated results.

  18. A comparative study of several compressibility corrections to turbulence models applied to high-speed shear layers

    NASA Technical Reports Server (NTRS)

    Viegas, John R.; Rubesin, Morris W.

    1991-01-01

    Several recently published compressibility corrections to the standard k-epsilon turbulence model are used with the Navier-Stokes equations to compute the mixing region of a large variety of high speed flows. These corrections, specifically developed to address the weakness of higher order turbulence models to accurately predict the spread rate of compressible free shear flows, are applied to two stream flows of the same gas mixing under a large variety of free stream conditions. Results are presented for two types of flows: unconfined streams with either (1) matched total temperatures and static pressures, or (2) matched static temperatures and pressures, and a confined stream.

  19. Absorption spectra of deuterated water at DF laser wavelengths.

    PubMed

    Bruce, C W; Jelinek, A V

    1982-11-15

    Absorption coefficients for deuterated water have been measured at twenty-two deuterium fluoride (DF) laser wavelengths and presented for atmospheric conditions classified as midlatitude-summer (14.3 T water vapor, standard temperature, and pressure). The HDO vapor was produced from a liquid mixture of H(2)O and D(2)O. The proportions of the resulting equilibrium mixture involving these constituents and HDO were calculated using previously measured constants and produced strong HDO absorption at the 3.5-4.1-microm DF laser wavelengths relative to those of the H(2)O and D(2)O vapors. Predicted and measured pressure dependencies at constant mixing ratios are compared for several laser wavelengths having strong HDO absorption. Absorption coefficients are in fairly close agreement with those of the current Air Force Geophysical Laboratory line-by-line model for standard temperature and pressure conditions. At lower total pressures, the comparison is less satisfactory and suggests inaccurate line parameters in the predictive data base.

  20. Magnetic properties of solid oxygen under pressure (Review Article)

    NASA Astrophysics Data System (ADS)

    Freiman, Yu. A.

    2015-11-01

    Solid oxygen is a unique crystal combining properties of a simple molecular solid and a magnet. Unlike ordinary magnets, the exchange interaction in solid oxygen acts on a background of weak Van der Waals forces, providing a significant part of the total lattice energy. Therefore, the magnetic and lattice properties of solid oxygen are very closely related. This manifests itself in a very rich phase diagram and numerous anomalies of thermal, magnetic and optical properties. Low-temperature low-pressure α-O2 is a two-sublattice collinear Neel antiferromagnet. At a pressure of ˜6 GPa, α-O2 is transformed into δ-O2, in which three different magnetic structures are realized upon increasing temperature. At ˜8 GPa δ-O2 is transformed into ɛ-O2. In this transition, O2 molecules combine into four-molecule clusters (O2)4. This transformation is accompanied by a magnetic collapse. This review describes the evolution of the magnetic structure with increasing pressure, and analyzes the causes behind this behavior.

  1. Vibration Sensitivity of a Wide-Temperature Electronically Scanned Pressure Measurement (ESP) Module

    NASA Technical Reports Server (NTRS)

    Zuckerwar, Allan J.; Garza, Frederico R.

    2001-01-01

    A vibration sensitivity test was conducted on a Wide-Temperature ESP module. The test object was Module "M4," a 16-channel, 4 psi unit scheduled for installation in the Arc Sector of NTF. The module was installed on a vibration exciter and loaded to positive then negative full-scale pressures (+/-2.5 psid). Test variables were the following: Vibration frequencies: 20, 55, 75 Hz. Vibration level: 1 g. Vibration axes: X, Y, Z. The pressure response was measured on each channel, first without and then with the vibration turned on, and the difference analyzed by means of the statistical t-test. The results show that the vibration sensitivity does not exceed 0.01% Full Scale Output per g (with the exception of one channel on one axis) to a 95 percent confidence level. This specification, limited by the resolution of the pressure source, lies well below the total uncertainty specification of 0.1 percent Full Scale Output.

  2. First-principles study of high-pressure structural phase transitions of magnesium

    NASA Astrophysics Data System (ADS)

    Liu, Qiuxiang; Fan, Changzeng; Zhang, Ruijun

    2009-06-01

    The structural phase transitions for the hcp, bcc, dhcp, and fcc of magnesium at hydrostatic pressures larger than about 200 GPa at zero temperature are studied by first-principles total energy calculations. The plane-wave basis pseudopotential method has been adopted, in which the generalized gradient approximation implanted in the CASTEP code is employed. By comparing the enthalpy differences of the hcp structure with other three structures under different pressures, it can be seen that when the pressure becomes higher than about 65, 130, and 190 GPa, the bcc, dhcp, and fcc structures become more stable relative to the hcp structure, respectively. Due to the lowest enthalpy value of the bcc structure above 65 GPa, it can be deduced that magnesium may transform to the bcc structure from the ground state hcp structure around 65 GPa, but no further phase transitions occur without additionally applying high temperature. In addition, the equation of state of magnesium is calculated, indicating that bcc structure is the softest phase.

  3. In situ hydrostatic pressure induced improvement of critical current density and suppression of magnetic relaxation in Y(Dy0.5)Ba2Cu3O7‑δ coated conductors

    NASA Astrophysics Data System (ADS)

    Sang, Lina; Gutiérrez, Joffre; Cai, Chuanbing; Dou, Shixue; Wang, Xiaolin

    2018-07-01

    We report on the effect of in situ hydrostatic pressure on the enhancement of the in-magnetic-field critical current density parallel to the crystallographic c-axis and vortex pinning in epitaxial Y(Dy0.5)Ba2Cu3O7‑δ coated conductors prepared by metal organic deposition. Our results show that in situ hydrostatic pressure greatly enhances the critical current density at high fields and high temperatures. At 80 K and 5 T we observe a ten-fold increase in the critical current density under the pressure of 1.2 GPa, and the irreversibility line is shifted to higher fields without changing the critical temperature. The normalized magnetic relaxation rate shows that vortex creep rates are strongly suppressed due to applied pressure, and the pinning energy is significantly increased based on the collective creep theory. After releasing the pressure, we recover the original superconducting properties. Therefore, we speculate that the in situ hydrostatic pressure exerted on the coated conductor enhances the pinning of existing extended defects. This is totally different from what has been observed in REBa2Cu3O7‑δ melt-textured crystals, where the effect of pressure generates point-like defects.

  4. The transition mechanisms of the E to H mode and the H to E mode in an inductively coupled argon-mercury mixture discharge

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhang, Xiao; Yu, Peng-Cheng; Liu, Yu

    2015-10-15

    In our experiment, the transition points between the two operational modes of capacitive coupling (E mode) and inductive coupling (H mode) were investigated at a wide range of mercury vapor pressures in an inductively coupled plasma, varying with the input radio-frequency powers and the total filling pressures (10 Pa–30 Pa). The electron temperatures were calculated versus with the mercury vapor pressures for different values of the total filling pressures. The transition power points and electron density also were measured in this study. It is shown that the transition powers, whether the E to H mode transition or the H to E modemore » transition, are lower than that of the argon discharge, and these powers almost increase with the mercury vapor pressure rising. However, the transition electron density follows an inverse relationship with the mercury vapor pressures compared with the transition powers. In addition, at the lower pressures and higher mercury vapor pressures, an inverse hysteresis was observed clearly, which did not appear in the argon gas plasma. We suggest that all these results are attributed to the electron-neutral collision frequency changed with the additional mercury vapor pressures.« less

  5. Practical development of continuous supercritical fluid process using high pressure and high temperature micromixer

    NASA Astrophysics Data System (ADS)

    Kawasaki, Shin-Ichiro; Sue, Kiwamu; Ookawara, Ryuto; Wakashima, Yuichiro; Suzuki, Akira

    2015-12-01

    In the synthesis of metal oxide fine particles by continuous supercritical hydrothermal method, the particle characteristics are greatly affected by not only the reaction conditions (temperature, pressure, residence time, concentration, etc.), but also the heating rate from ambient to reaction temperature. Therefore, the heating method by direct mixing of starting solution at room temperature with supercritical water is a key technology for the particle production having smaller size and narrow distribution. In this paper, mixing engineering study through comparison between conventional T-shaped mixers and recently developed swirl mixers was carried out in the hydrothermal synthesis of NiO nanoparticles from Ni(NO3)2 aqueous solution at 400 °C and 30 MPa. Inner diameter in the mixers and total flow rates were varied. Furthermore, the heating rate was calculated by computational fluid dynamics (CFD) simulation. Relationship between the heating rate and the average particle size were discussed. It was clarified that the miniaturization of mixer inner diameter and the use of the swirl flow were effective for improving mixing performance and contributed to produce small and narrow distribution particle under same experimental condition of flow rate, temperature, pressure, residence time, and concentration of the starting materials. We have focused the mixer optimization due to a difference in fluid viscosity.

  6. Stability of rhombohedral phases in vanadium at high-pressure and high-temperature: first-principles investigations

    PubMed Central

    Wang, Yi X.; Wu, Q.; Chen, Xiang R.; Geng, Hua Y.

    2016-01-01

    The pressure-induced transition of vanadium from BCC to rhombohedral structures is unique and intriguing among transition metals. In this work, the stability of these phases is revisited by using density functional theory. At finite temperatures, a novel transition of rhombohedral phases back to BCC phase induced by thermal electrons is discovered. This reentrant transition is found not driven by phonons, instead it is the electronic entropy that stabilizes the latter phase, which is totally out of expectation. Parallel to this transition, we find a peculiar and strong increase of the shear modulus C44 with increasing temperature. It is counter-intuitive in the sense that it suggests an unusual harding mechanism of vanadium by temperature. With these stability analyses, the high-pressure and finite-temperature phase diagram of vanadium is proposed. Furthermore, the dependence of the stability of RH phases on the Fermi energy and chemical environment is investigated. The results demonstrate that the position of the Fermi level has a significant impact on the phase stability, and follows the band-filling argument. Besides the Fermi surface nesting, we find that the localization/delocalization of the d orbitals also contributes to the instability of rhombohedral distortions in vanadium. PMID:27581551

  7. NASA Lewis 8- by 6-foot supersonic wind tunnel user manual

    NASA Technical Reports Server (NTRS)

    Soeder, Ronald H.

    1993-01-01

    The 8- by 6-Foot Supersonic Wind Tunnel (SWT) at Lewis Research Center is available for use by qualified researchers. This manual contains tunnel performance maps which show the range of total temperature, total pressure, static pressure, dynamic pressure, altitude, Reynolds number, and mass flow as a function of test section Mach number. These maps are applicable for both the aerodynamic and propulsion cycle. The 8- by 6-Foot Supersonic Wind Tunnel is an atmospheric facility with a test section Mach number range from 0.36 to 2.0. General support systems (air systems, hydraulic system, hydrogen system, infrared system, laser system, laser sheet system, and schlieren system are also described as are instrumentation and data processing and acquisition systems. Pretest meeting formats are outlined. Tunnel user responsibility and personal safety requirements are also stated.

  8. In-flight Compressible Turbulent Boundary Layer Measurements on a Hollow Cylinder at a Mach Number of 3.0

    NASA Technical Reports Server (NTRS)

    Quinn, R. D.; Gong, L.

    1978-01-01

    Skin temperatures, shearing forces, surface static pressures, and boundary layer pitot pressures and total temperatures were measured on a hollow cylinder 3.04 meters long and 0.437 meter in diameter mounted beneath the fuselage of the YF-12A airplane. The data were obtained at a nominal free stream Mach number of 3.0 and at wall-to-recovery temperature ratios of 0.66 to 0.91. The free stream Reynolds number had a minimal value of 4.2 million per meter. Heat transfer coefficients and skin friction coefficients were derived from skin temperature time histories and shear force measurements, respectively. Boundary layer velocity profiles were derived from pitot pressure measurements, and a Reynolds analogy factor of 1.11 was obtained from the measured heat transfer and skin friction data. The skin friction coefficients predicted by the theory of van Driest were in excellent agreement with the measurements. Theoretical heat transfer coefficients, in the form of Stanton numbers calculated by using a modified Reynolds analogy between skin friction and heat transfer, were compared with measured values. The measured velocity profiles were compared to Coles' incompressible law-of-the-wall profile.

  9. Effect of lamp type and temperature on development, carbon partitioning and yield of soybean

    NASA Astrophysics Data System (ADS)

    Dougher, T. A. O.; Bugbee, B.

    1997-01-01

    Soybeans grown in controlled environments are commonly taller than field-grown plants. In controlled environments, including liquid hydroponics, height of the dwarf cultivar ``Hoyt'' was reduced from 46 to 33 cm when plants were grown under metal halide lamps compared to high pressure sodium lamps at the same photosynthetic photon flux. Metal halide lamps reduced total biomass 14% but did not significantly reduce seed yield. Neither increasing temperature nor altering the difference between day/night temperature affected plant height. Increasing temperature from 21 to 27 degC increased yield 32%. High temperature significantly increased carbon partitioning to stems and increased harvest index.

  10. Explosion characteristics of LPG-air mixtures in closed vessels.

    PubMed

    Razus, Domnina; Brinzea, Venera; Mitu, Maria; Oancea, D

    2009-06-15

    The experimental study of explosive combustion of LPG (liquefied petroleum gas)-air mixtures at ambient initial temperature was performed in two closed vessels with central ignition, at various total initial pressures within 0.3-1.3bar and various fuel/air ratios, within the flammability limits. The transient pressure-time records were used to determine several explosion characteristics of LPG-air: the peak explosion pressure, the explosion time (the time necessary to reach the peak pressure), the maximum rate of pressure rise and the severity factor. All explosion parameters are strongly dependent on initial pressure of fuel-air mixture and on fuel/air ratio. The explosion characteristics of LPG-air mixtures are discussed in comparison with data referring to the main components of LPG: propane and butane, obtained in identical conditions.

  11. Flow Visualization of a Rotating Detonation Engine

    DTIC Science & Technology

    2016-10-05

    2[b]), and a 3-dimensional (3-D) view around the injectors (2[c]). In this study, ethylene and oxygen were used as propellants. These gases were fed...1.0-mm radius; the ethylene injectors had a 0.8-mm radius. A total of 100 sets of injectors were installed at even intervals. The gases were injected...detonation wave, was filled with high-pressure, high-temperature burned gas. This high-pressure burned gas stopped the injection of ethylene and

  12. High temperature pyrolysis of vinylacetylene

    NASA Astrophysics Data System (ADS)

    Braun-Unkhoff, M.; Kurz, A.; Frank, P.

    1990-07-01

    The thermal decomposition of vinylacetylene has been studied behind reflected shock waves in the temperature range 1350-1870 K at total pressures between 1.7 and 7.4 bar. Initial concentrations of the hydrogen in argon ranged between 1 to 300 ppm. The following species were measured: H-atoms by ARAS, C2H2, C4H2 and C4H4 by molecular vuv-absorption. The combination of very low initial concentrations with a sensitive detection technique allowed to perform the experiments under conditions where only very few elementary reaction steps determine the progress of reaction. It was found that C4H4 decomposes simultaneously into different product channels: C4H4→C2H2+C2H2 k1a=3.4ṡ1013 exp(-38820/T) s-1 C4H4+Ar→C4H3+H+Ar k1b=1.1ṡ1020exp(-49990/T) cm3 mol-1 s-1 C4H4→C4H2+H2 k1c=1.3ṡ1015exp(-47670/T) s-1. From variation of the total pressure it has been deduced that reaction pathways R1a and R1c proceed with rates not far from the high-pressure limiting values and that reaction R1b proceeds close to the low-pressure limiting rate constant values.

  13. Development of pressure-sensitive dosage forms with a core liquefying at body temperature.

    PubMed

    Wilde, Lisa; Bock, Mona; Wolf, Marieke; Glöckl, Gunnar; Garbacz, Grzegorz; Weitschies, Werner

    2014-04-01

    Pressure-sensitive dosage forms have been developed that are intended for pulsatile delivery of drugs to the proximal small intestine. The novel dosage forms are composed of insoluble shell and either a hard fat W32 or polyethylene glycol (PEG) 1000 core that are both liquidizing at body temperature. The release is triggered by predominant pressure waves such as contractions of the pylorus causing rupture of the shell and an immediate emptying of the liquefied filling containing the active ingredient. In consequence immediately after the trigger has been effective the total amount of the drug is intended to be available for absorption in the upper small intestine. Both core types were coated with a cellulose acetate film that creates a pressure-sensitive shell in which mechanical resistance is depending on the coating thickness. Results of the texture analysis confirmed a correlation between the polymer load of the coating and the mechanical resistance. The dissolution test performed under conditions of physiological meaningful mechanical stress showed that the drug release is triggered by pressure waves of ⩾300 mbar which are representing the maximal pressure occurring during the gastric emptying. Copyright © 2013 Elsevier B.V. All rights reserved.

  14. [Study on supercritical CO2 extraction of xiaoyaosan and its GC-MS fingerprint].

    PubMed

    Zuo, Ya-Mei; Tian, Jun-Sheng; Guo, Xiao-Qing; Zhou, Yu-Zhi; Gao, Xiao-Xia; Qin, Xue-Mei

    2014-02-01

    To determine the optimum conditions of supercritical CO2 extraction of Xiaoyaosan, and establish its fingerprint by gas chromatography-mass spectrometry (GC-MS), the yield of extract were investigated, an orthogonal test was used to quantify the effects of extraction temperature, pressure, CO2 flow rate and time, and fingerprint analysis of different batches of extracts were by GC-MS. The optimal extraction conditions were determined as follows: extraction pressure 20 MPa, extraction temperature 50 degrees C, CO2 flow rate 25 kg x h(-1), extraction time 3 h, and average yield 2.2%. The GC-MS fingerprint was established and 27 common peaks were found, whose contents add up to 81.89% of the total peak area. Among them, 21 compounds were identified, accounting for 53.20% of the total extract. The extraction process is reasonable and favorable for industrial production. The GC-MS method is accurate, reliable, reproducible, and can be used for quality control of supercritical CO2 extract from Xiaoyaosan.

  15. High methane natural gas/air explosion characteristics in confined vessel.

    PubMed

    Tang, Chenglong; Zhang, Shuang; Si, Zhanbo; Huang, Zuohua; Zhang, Kongming; Jin, Zebing

    2014-08-15

    The explosion characteristics of high methane fraction natural gas were investigated in a constant volume combustion vessel at different initial conditions. Results show that with the increase of initial pressure, the peak explosion pressure, the maximum rate of pressure rise increase due to a higher amount (mass) of flammable mixture, which delivers an increased amount of heat. The increased total flame duration and flame development time result as a consequence of the higher amount of flammable mixture. With the increase of the initial temperature, the peak explosion pressures decrease, but the pressure increase during combustion is accelerated, which indicates a faster flame speed and heat release rate. The maximum value of the explosion pressure, the maximum rate of pressure rise, the minimum total combustion duration and the minimum flame development time is observed when the equivalence ratio of the mixture is 1.1. Additionally, for higher methane fraction natural gas, the explosion pressure and the maximum rate of pressure rise are slightly decreased, while the combustion duration is postponed. The combustion phasing is empirically correlated with the experimental parameters with good fitting performance. Furthermore, the addition of dilute gas significantly reduces the explosion pressure, the maximum rate of pressure rise and postpones the flame development and this flame retarding effect of carbon dioxide is stronger than that of nitrogen. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. Variations of Thermal Pressure for Solids along the Principal Hugoniot

    NASA Astrophysics Data System (ADS)

    Gong, Zizheng; Yu, Hui; Deng, Liwei; Zhang, Li; Yang, Jinke

    2006-07-01

    The behavior of thermal pressure PTH for all kinds of solid materials was investigated using the lattice dynamics theory up to 500GPa. The results show that for most metals, ionic crystal and minerals, the thermal pressure is approximately independent on volume, whereas the thermal pressure of a few solids has strong dependence on volume. The volume dependence of thermal pressure has no relation with the chemical bonding type and crystal structure of materials, but is correlated with the Debye temperature ΘD and the second Grüneisen parameter q. The ratio of the thermal pressure to the total pressure (PTH /PTotal) along the Hugoniot keeps constant over a wide compression range, not only for non-porous materials but also for porous materials within certain porosity, which could explain the existence of material constant parameter β along solid Hugoniot.

  17. An experimental and modeling study investigating the ignition delay in a military diesel engine running hexadecane (cetane) fuel

    DOE PAGES

    Cowart, Jim S.; Fischer, Warren P.; Hamilton, Leonard J.; ...

    2013-02-01

    In an effort aimed at predicting the combustion behavior of a new fuel in a conventional diesel engine, cetane (n-hexadecane) fuel was used in a military engine across the entire speed–load operating range. The ignition delay was characterized for this fuel at each operating condition. A chemical ignition delay was also predicted across the speed–load range using a detailed chemical kinetic mechanism with a constant pressure reactor model. At each operating condition, the measured in-cylinder pressure and predicted temperature at the start of injection were applied to the detailed n-hexadecane kinetic mechanism, and the chemical ignition delay was predicted withoutmore » any kinetic mechanism calibration. The modeling results show that fuel–air parcels developed from the diesel spray with an equivalence ratio of 4 are the first to ignite. The chemical ignition delay results also showed decreasing igntion delays with increasing engine load and speed, just as the experimental data revealed. At lower engine speeds and loads, the kinetic modeling results show the characteristic two-stage negative temperature coefficient behavior of hydrocarbon fuels. However, at high engine speeds and loads, the reactions do not display negative temperature coefficient behavior, as the reactions proceed directly into high-temperature pathways due to higher temperatures and pressure at injection. A moderate difference between the total and chemical ignition delays was then characterized as a phyical delay period that scales inversely with engine speed. This physical delay time is representative of the diesel spray development time and is seen to become a minority fraction of the total igntion delay at higher engine speeds. In addition, the approach used in this study suggests that the ignition delay and thus start of combustion may be predicted with reasonable accuracy using kinetic modeling to determine the chemical igntion delay. Then, in conjunction with the physical delay time (experimental or modeling based), a new fuel’s acceptability in a conventional engine could be assessed by determining that the total ignition delay is not too short or too long.« less

  18. Pressure and Temperature Dependence of the Reaction of Vinyl Radical with Ethylene

    NASA Technical Reports Server (NTRS)

    Ismail, Huzeifa; Goldsmith, C. Franklin; Abel, Paul R.; Howe, Pui-Teng; Fahr, Askar; Halpern, Joshua B.; Jusinski, Leonard E.; Georgievskii, Yuri; Taatjes, Craig A.; Green, William H.

    2007-01-01

    This work reports measurements of absolute rate coefficients and Rice-Ramsperger-Kassel-Marcus (RRKM) master equation simulations of the C2H3 + C2H4 reaction. Direct kinetic studies were performed over a temperature range of 300-700 K and pressures of 20 and 133 mbar. Vinyl radicals (H2C=CH) were generated by laser photolysis of vinyl iodide (C2H31) at 266 nm, and time-resolved absorption spectroscopy was used to probe vinyl radicals through absorption at 423.2 nm. Measurements at 20 mbar are in good agreement with previous determinations at higher temperature. A weighted three-parameter Arrhenius fit to the experimental rate constant at 133 mbar, with the temperature exponent fixed, gives k = (7 +/- 1) x 10(exp -l4) cu cm/molecule/s (T/298 K)(exp 2) exp[-(1430 +/- 70) K/T]. RRKM master equation simulations, based on G3 calculations of stationary points on the C4H7 potential energy surface, were carried out to predict rate coefficients and product branching fractions. The predicted branching to 1-methylallyl product is relatively small under the conditions of the present experiments but increases as the pressure is lowered. Analysis of end products of 248 nm photolysis of vinyl iodide/ethylene mixtures at total pressures between 27 and 933 mbar provides no direct evidence for participation of I -methylallyl.

  19. Temperature dependence of Lorentz air-broadening and pressure-shift coefficients of (12)CH4 lines in the 2.3-micron spectral region

    NASA Technical Reports Server (NTRS)

    Devi, V. Malathy; Benner, D. Chris; Smith, M. A. H.; Rinsland, C. P.

    1994-01-01

    High-resolution (0.01/cm) absorption spectra of lean mixtures of CH4 in dry air were recorded with the McMath-Pierce Fourier transform spectrometer (FTS) of the National Solar Observatory on Kitt Peak at various temperatures between 24 and -61 C. The spectra have been analyzed to determine the values at room temperature of pressure-broadened widths and pressure-induced shifts of more than 740 transitions. The temperature dependence of air-broadened widths and pressure-induced shifts was deduced for approx. 370 transitions in the nu(sub 1) + nu(sub 4), nu(sub 3) + nu(sub 4), and nu(sub 2) + nu(sub 3) bands of (12)CH4 located between 4118 and 4615/cm. These results were obtained by analyzing a total of 29 spectra simultaneously using a multi-spectral non-linear least-squares fitting technique. This new technique allowed the determination of correlated spectral line parameters (e.g. intensity and broadening coefficient) better than the procedure of averaging values obtained by fitting the spectra individually. This method also provided a direct determination of the uncertainties in the retrieved parameters due to random errors. For each band analysed in this study the dependence of the various spectral line parameters upon the tetrahedral symmetry species and the rotational quantum numbers of the transitions is also presented.

  20. Computer code for preliminary sizing analysis of axial-flow turbines

    NASA Technical Reports Server (NTRS)

    Glassman, Arthur J.

    1992-01-01

    This mean diameter flow analysis uses a stage average velocity diagram as the basis for the computational efficiency. Input design requirements include power or pressure ratio, flow rate, temperature, pressure, and rotative speed. Turbine designs are generated for any specified number of stages and for any of three types of velocity diagrams (symmetrical, zero exit swirl, or impulse) or for any specified stage swirl split. Exit turning vanes can be included in the design. The program output includes inlet and exit annulus dimensions, exit temperature and pressure, total and static efficiencies, flow angles, and last stage absolute and relative Mach numbers. An analysis is presented along with a description of the computer program input and output with sample cases. The analysis and code presented herein are modifications of those described in NASA-TN-D-6702. These modifications improve modeling rigor and extend code applicability.

  1. Liquid Jets in Crossflow at Elevated Temperatures and Pressures

    NASA Astrophysics Data System (ADS)

    Amighi, Amirreza

    An experimental study on the characterization of liquid jets injected into subsonic air crossflows is conducted. The aim of the study is to relate the droplet size and other attributes of the spray, such as breakup length, position, plume width, and time to flow parameters, including jet and air velocities, pressure and temperature as well as non-dimensional variables. Furthermore, multiple expressions are defined that would summarize the general behavior of the spray. For this purpose, an experimental setup is developed, which could withstand high temperatures and pressures to simulate conditions close to those experienced inside gas turbine engines. Images are captured using a laser based shadowgraphy system similar to a 2D PIV system. Image processing is extensively used to measure droplet size and boundaries of the spray. In total 209 different conditions are tested and over 72,000 images are captured and processed. The crossflow air temperatures are 25°C, 200°C, and 300°C; absolute crossflow air pressures are 2.1, 3.8, and 5.2 bars. Various liquid and gas velocities are tested for each given temperature and pressure in order to study the breakup mechanisms and regimes. Effects of dimensional and non-dimensional variables on droplet size are presented in detail. Several correlations for the mean droplet size, which are generated in this process, are presented. In addition, the influence of non-dimensional variables on the breakup length, time, plume area, angle, width and mean jet surface thickness are discussed and individual correlations are provided for each parameter. The influence of each individual parameter on the droplet sizes is discussed for a better understanding of the fragmentation process. Finally, new correlations for the centerline, windward and leeward trajectories are presented and compared to the previously reported correlations.

  2. Total fluid pressure imbalance in the scrape-off layer of tokamak plasmas

    DOE PAGES

    Churchill, Randy M.; Canik, John M.; Chang, C. S.; ...

    2017-03-10

    Simulations using the fully kinetic neoclassical code XGCa (X-point included guiding-center axisymmetric) were undertaken to explore the impact of kinetic effects on scrape-off layer (SOL) physics in DIII-D H-mode plasmas. XGCa is a total-f, gyrokinetic code which self-consistently calculates the axisymmetric electrostatic potential and plasma dynamics, and includes modules for Monte Carlo neutral transport. Previously presented XGCa results showed several noteworthy features, including large variations of ion density and pressure along field lines in the SOL, experimentally relevant levels of SOL parallel ion flow (Mach number similar to 0.5), skewed ion distributions near the sheath entrance leading to subsonic flowmore » there, and elevated sheath potentials (Churchill 2016 Nucl. Mater. Energy 1-6). In this paper, we explore in detail the question of pressure balance in the SOL, as it was observed in the simulation that there was a large deviation from a simple total pressure balance (the sum of ion and electron static pressure plus ion inertia). It will be shown that both the contributions from the ion viscosity (driven by ion temperature anisotropy) and neutral source terms can be substantial, and should be retained in the parallel momentum equation in the SOL, but still falls short of accounting for the observed fluid pressure imbalance in the XGCa simulation results.« less

  3. The measurement of shear stress and total heat flux in a nonadiabatic turbulent hypersonic boundary layer

    NASA Technical Reports Server (NTRS)

    Mikulla, V.; Horstman, C. C.

    1975-01-01

    Turbulent shear stress and direct turbulent total heat-flux measurements have been made across a nonadiabatic, zero pressure gradient, hypersonic boundary layer by using specially designed hot-wire probes free of strain-gauging and wire oscillation. Heat-flux measurements were in reasonably good agreement with values obtained by integrating the energy equation using measured profiles of velocity and temperature. The shear-stress values deduced from the measurements, by assuming zero correlation of velocity and pressure fluctuations, were lower than the values obtained by integrating the momentum equation. Statistical properties of the cross-correlations are similar to corresponding incompressible measurements at approximately the same momentum-thickness Reynolds number.

  4. [Research of the essential oil of Plumeria rubra var. actifolia from Laos by supercritical carbon dioxide extraction].

    PubMed

    Xiao, Xin-Yu; Cui, Long-Hai; Zhou, Xin-Xin; Wu, Yan; Ge, Fa-Huan

    2011-05-01

    The orthogonal test and the supercritical carbon dioxide fluid extraction were used for optimizing the extraction of the essential oil from Plumeria rubra var. actifolia for the first time. Compared with the steam distillation, the optimal operation parameter of extraction was as follows: extraction pressure 25 MPa, extraction temperature 45 degrees C; separator I pressure 12 MPa, separator I temperature 55 degrees C; separator II pressure 6 MPa, separator II temperature 30 degrees C. Under this condition the yield of the essential oil was 5.8927%. The components were separated and identified by GC-MS. 53 components of Plumeria rubra var. actifolia measured by SFE method were identified and determined by normalization method. The main components were 1, 6, 10-dodecatrien-3-ol, 3, 7, 11-trimethyl, benzoic acid, 2-hydroxy-, phenylmethyl ester, 1, 2-benzenedicarboxylic acid, bis(2-methylpropyl) ester,etc.. 1, 2-Benzenedicarboxylic acid, bis (2-methylpropyl) este. took up 66.11% of the total amount, and there was much difference of the results from SD method.

  5. A pilot study: sodium urate synovitis as an acute model of inflammatory response using objective and subjective criteria to evaluate arthritic pain in cats.

    PubMed

    Carroll, G L; Narbe, R; Peterson, K; Kerwin, S C; Taylor, L; DeBoer, M

    2008-10-01

    Sodium urate (SU) synovitis was evaluated as a model for feline arthritic pain using a placebo- and positive-controlled (meloxicam) randomized blinded controlled single crossover design. Monosodium urate crystals [20 mg (1 mL) rod-shaped] were injected into alternate stifles of trained anesthetized cats (n = 3) with a 28 day washout. During the first trial phase, two cats received meloxicam (0.1 mg/kg, PO), a nonsteroidal anti-inflammatory drug (NSAID), for three days before and on the day of SU injection; the third cat received placebo. Treatments and stifles were switched for the second trial. Total force, contact pressure and area of the fore and hind limbs were measured using a pressure mat one day and 0.5 h before, and 2, 4, 6, 8, 10, 24, and 30 h post-SU injection. Skin temperature, joint circumference, analgesia, lameness, and visual analogue scale (VAS) pain scores, were measured at the same times. Comparisons were made for each time and for areas under the curve (AUC) using original and change from baseline; P < 0.05 was significant. Significant differences in force mat data and subjective data were found for the hind limb data (total force and total contact pressure at 6, 10, and 30 h; analgesia and VAS for pain at 4 h; lameness at 10, 24, and 30 h) and for AUC(0)-->(24h) and AUC(0)-->(30 h) (total force, total contact pressure, and mean lameness score) and for differences from BL AUC(0)-->(10h) (total contact area) and AUC(0)-->(24h) (total contact area and mean lameness score) and AUC(0)-->(30 h) (total force, total contact area, and mean lameness). No cats required rescue analgesia. Injection of 1 mL of monosodium urate into the stifle of a cat causes moderate transitory pain and was suitable for assessing analgesic efficacy of an NSAID with a pressure mat and subjective criteria.

  6. Heat transfer from cylinders in subsonic slip flows

    NASA Technical Reports Server (NTRS)

    Nagabushana, K. A.; Stainback, P. C.

    1992-01-01

    The heat transfer in heated wires was measured using a constant temperature anemometer over a Mach number range from 0.05 to 0.4 and pressures from 0.5 to 8.0 atmospheres. The total temperature ranged from 80 to 120 F and the wire diameters were 0.00015, 0.00032, and 0.00050 inch. The heat transfer data is presented in the form of a corrected Nusselt number. Based on suggested criteria, much of the data was obtained in the slip flow regime. Therefore, the data is compared with data having comparable flow conditions. The possible application of the heat transfer data to hot wire anemometry is discussed. To this end, the sensitivity of the wires to velocity, density, and total temperature is computed and compared using two different types of correlations.

  7. Modeling and multi-response optimization of pervaporation of organic aqueous solutions using desirability function approach.

    PubMed

    Cojocaru, C; Khayet, M; Zakrzewska-Trznadel, G; Jaworska, A

    2009-08-15

    The factorial design of experiments and desirability function approach has been applied for multi-response optimization in pervaporation separation process. Two organic aqueous solutions were considered as model mixtures, water/acetonitrile and water/ethanol mixtures. Two responses have been employed in multi-response optimization of pervaporation, total permeate flux and organic selectivity. The effects of three experimental factors (feed temperature, initial concentration of organic compound in feed solution, and downstream pressure) on the pervaporation responses have been investigated. The experiments were performed according to a 2(3) full factorial experimental design. The factorial models have been obtained from experimental design and validated statistically by analysis of variance (ANOVA). The spatial representations of the response functions were drawn together with the corresponding contour line plots. Factorial models have been used to develop the overall desirability function. In addition, the overlap contour plots were presented to identify the desirability zone and to determine the optimum point. The optimal operating conditions were found to be, in the case of water/acetonitrile mixture, a feed temperature of 55 degrees C, an initial concentration of 6.58% and a downstream pressure of 13.99 kPa, while for water/ethanol mixture a feed temperature of 55 degrees C, an initial concentration of 4.53% and a downstream pressure of 9.57 kPa. Under such optimum conditions it was observed experimentally an improvement of both the total permeate flux and selectivity.

  8. Density of biogas digestate depending on temperature and composition.

    PubMed

    Gerber, Mandy; Schneider, Nico

    2015-09-01

    Density is one of the most important physical properties of biogas digestate to ensure an optimal dimensioning and a precise design of biogas plant components like stirring devices, pumps and heat exchangers. In this study the density of biogas digestates with different compositions was measured using pycnometers at ambient pressure in a temperature range from 293.15 to 313.15K. The biogas digestates were taken from semi-continuous experiments, in which the marine microalga Nannochloropsis salina, corn silage and a mixture of both were used as feedstocks. The results show an increase of density with increasing total solid content and a decrease with increasing temperature. Three equations to calculate the density of biogas digestate were set up depending on temperature as well as on the total solid content, organic composition and elemental composition, respectively. All correlations show a relative deviation below 1% compared to experimental data. Copyright © 2015. Published by Elsevier Ltd.

  9. 21 CFR 177.1620 - Polyethylene, oxidized.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... FOR HUMAN CONSUMPTION (CONTINUED) INDIRECT FOOD ADDITIVES: POLYMERS Substances for Use as Basic...,200, as determined by high temperature vapor pressure osmometry, contains a maximum of 5 percent by weight of total oxygen, and has an acid value of 9 to 19. (b) The finished food-contact article, when...

  10. 21 CFR 177.1620 - Polyethylene, oxidized.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... FOR HUMAN CONSUMPTION (CONTINUED) INDIRECT FOOD ADDITIVES: POLYMERS Substances for Use as Basic...,200, as determined by high temperature vapor pressure osmometry, contains a maximum of 5 percent by weight of total oxygen, and has an acid value of 9 to 19. (b) The finished food-contact article, when...

  11. 21 CFR 177.1620 - Polyethylene, oxidized.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... FOR HUMAN CONSUMPTION (CONTINUED) INDIRECT FOOD ADDITIVES: POLYMERS Substances for Use as Basic...,200, as determined by high temperature vapor pressure osmometry, contains a maximum of 5 percent by weight of total oxygen, and has an acid value of 9 to 19. (b) The finished food-contact article, when...

  12. 21 CFR 177.1620 - Polyethylene, oxidized.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... FOR HUMAN CONSUMPTION (CONTINUED) INDIRECT FOOD ADDITIVES: POLYMERS Substances for Use as Basic...,200, as determined by high temperature vapor pressure osmometry, contains a maximum of 5 percent by weight of total oxygen, and has an acid value of 9 to 19. (b) The finished food-contact article, when...

  13. Enzymatic and phytochemical stabilization of orange-strawberry-banana beverages by high hydrostatic pressure and mild heat.

    PubMed

    Escobedo-Avellaneda, Zamantha; Pérez-Simón, Izaskun; Lavilla-Martín, María; Baranda-González, Ana; Welti-Chanes, Jorge

    2017-03-01

    A new approach to the use of high hydrostatic pressure is its combination with high and intermediate temperatures applied to obtain safe foods of high quality. The effect of high hydrostatic pressure on color, residual polyphenol oxidase and pectin methylesterase activity, and total phenolic and l-ascorbic acid contents of orange-strawberry-banana beverages was evaluated. Beverages were treated at 500 and 600 MPa at 19-64 ℃ during 2-10 min. The effect of the come up time was also evaluated and results were compared with the untreated and the thermally processed (80 ℃/7 min) products. Untreated beverages had total phenolic content of 210.2±12.3 mg gallic acid/100 g and 19.1 ± 0.6 mg l-ascorbic acid/100 g. For most high hydrostatic pressure treatment conditions, total phenolic content, l-ascorbic acid, and color did not change significantly. Maximum levels of inactivation of polyphenol oxidase and pectin methylesterase were 96.2 and 48% at 600 MPa/64 ℃/10 min, while the thermal treatment led to inactivation of 99.6 and 94.1% of both enzymes, but with negative color changes. l-ascorbic acid content was slightly decreased with the thermal treatment while total phenolic content was not affected. High hydrostatic pressure treatments of beverages at 600 MPa/64 ℃/10 min are recommended to retain maximal total phenolic content and l-ascorbic acid and achieve an acceptable polyphenol oxidase inactivation level.

  14. Post-combustion CO2 capture with activated carbons using fixed bed adsorption

    NASA Astrophysics Data System (ADS)

    Al Mesfer, Mohammed K.; Danish, Mohd; Fahmy, Yasser M.; Rashid, Md. Mamoon

    2018-03-01

    In the current work, the capturing of carbon dioxide from flue gases of post combustion emission using fixed bed adsorption has been carried out. Two grades of commercial activated carbon (sorbent-1 and sorbent-2) were used as adsorbent. Feed consisting of CO2 and N2 mixture was used for carrying out the adsorption. The influence of bed temperature, feed rate, equilibrium partial pressure and initial % CO2 in feed were considered for analyzing adsorption-desorption process. It was found that the total adsorption-desorption cycle time decreases with increased column temperature and feed rates. The time required to achieve the condition of bed saturation decreases with increased bed temperature and feed rates. The amount of CO2 adsorbed/Kg of the adsorbent declines with increased bed temperature with in studied range for sorbent-1 and sorbent-2. It was suggested that the adsorption capacity of the both the sorbents increases with increased partial pressure of the gas.

  15. Performance of LI-1542 reusable surface insulation system in a hypersonic stream

    NASA Technical Reports Server (NTRS)

    Hunt, L. R.; Bohon, H. L.

    1974-01-01

    The thermal and structural performance of a large panel of LI-1542 reusable surface insulation tiles was determined by a series of cyclic heating tests using radiant lamps and aerothemal tests in the Langley 8-foot high-temperature structures tunnel. Aerothermal tests were conducted at a free-stream Mach number of 6.6, a total temperature of 1830 K, Reynolds numbers of 2.0 and 4,900,000 per meter, and dynamic pressures of 29 and 65 kPa. The results suggest that pressure gradients in gaps and flow impingement on the header walls at the end of longitudinal gaps are sources for increased gap heating. Temperatures higher than surface radiation equilibrium temperature were measured deep in gaps and at the header walls. Also, the damage tolerance of the LI-1542 tiles appears to be very high. Tile edge erosion rate was slow; could not be tolerated in a shuttle application. Tiles soaked with water and subjected to rapid depressurization and aerodynamic heating showed no visible evidence of damage.

  16. The transition from frictional sliding to shear melting in laboratory experiments and the implications for scale dependent earthquake source properties

    NASA Astrophysics Data System (ADS)

    Beeler, N. M.; Lockner, D. A.; Kilgore, B. D.; Moore, D. E.

    2011-12-01

    Localized slip during earthquakes, e.g., at 1 m/s for a few seconds, should produce enough thermal energy to melt rock or pressurize pore fluid and drastically reduce fault strength (Sibson, Nature Phys. Sci., 1973. Sibson, Geophys. J. R. Astr. Soc., 1975). Expected changes in earthquake source properties for events with large enough temperature change to induce melting or fluid pressurization include an increase in stress drop, a possible increase in low frequency content of the radiated energy and an increase in the ratio of radiated energy to seismic moment. Such changes with increasing moment, while expected, are not observed seismologically and the role of thermal weakening during large earthquakes remains unknown. To investigate the effect of the onset of thermal weakening on earthquake source properties such as stress drop, slip velocity, weakening distance, and apparent stress, we have conducted stick-slip experiments at confining pressures between 50 and 400 MPa on initially bare rock surfaces of Westerly granite (Lockner et al., Eos Trans. Am. Geophys. Un. T23A-2245, 2010). These conditions span a transition from frictional sliding, producing dry comminuted fault gouge and fractional stress drops at lower confining pressure, to shear induced melting with complete stress drop at the highest pressures. The confining pressure, axial stress and displacement, are measured as in standard faulting tests. Temperature is monitored with a thermocouple ~2.5 mm from the fault. Rapid motions of the fault are inferred from independent recordings of the acceleration and velocity of the loading piston using an accelerometer and a laser Doppler vibrometer. Slip velocity, and event duration increase with stress drop. Stress drops vary from less than 10 to greater than 400 MPa. Durations are between 0.1 and 0.5 ms and average sliding velocities range from <1 to > 10 m/s. Total stress drop is associated with slip and shear stress sufficient to increase the entire shear zone temperature to the melting point of feldspar, but melt is also found in samples subjected to smaller stress drops, suggesting heating to somewhat lower temperature. Stress and slip constrain the total energy; the temperature measurements constrain the energy associated with frictional heating and the heat of fusion, while the velocity measurements allow an estimate of the radiated energy. Using these constraints and models of shear-induced melting we examine changes in event source properties across the transition to shear melting.

  17. Preliminary characterization of an expanding flow of siloxane vapor MDM

    NASA Astrophysics Data System (ADS)

    Spinelli, A.; Cozzi, F.; Cammi, G.; Zocca, M.; Gaetani, P.; Dossena, V.; Guardone, A.

    2017-03-01

    The early experimental results on the characterization of expanding flows of siloxane vapor MDM (C8H24O2Si3, octamethyltrisiloxane) are presented. The measurements were performed on the Test Rig for Organic VApors (TROVA) at the CREA Laboratory of Politecnico di Milano. The TROVA test-rig was built in order to investigate the non-ideal compressible-fluid behavior of typical expanding flows occurring within organic Rankine cycles (ORC) turbine passages. The test rig implements a batch Rankine cycle where a planar converging-diverging nozzle replaces the turbine and represents a test section. Investigations related to both fields of non-ideal compressible-fluid dynamics fundamentals and turbomachinery are allowed. The nozzle can be operated with different working fluids and operating conditions aiming at measuring independently the pressure, the temperature and the velocity field and thus providing data to verify the thermo-fluid dynamic models adopted to predict the behavior of these flows. The limiting values of pressure and temperature are 50 bar and 400 °C respectively. The early measurements are performed along the nozzle axis, where an isentropic process is expected to occur. In particular, the results reported here refer to the nozzle operated in adapted conditions using the siloxane vapor MDM as working fluid in thermodynamic regions where mild to medium non-ideal compressible-fluid effects are present. Both total temperature and total pressure of the nozzle are measured upstream of the test section, while static pressure are measured along the nozzle axis. Schlieren visualizations are also carried out in order to complement the pressure measurement with information about the 2D density gradient field. The Laser Doppler Velocimetry technique is planned to be used in the future for velocity measurements. The measured flow field has also been interpreted by resorting to the quasi-one-dimensional theory and two dimensional CFD viscous calculation. In both cases state-of-the-art thermodynamic models were applied.

  18. Calculating High Speed Centrifugal Compressor Performance from Averaged Measurements

    NASA Astrophysics Data System (ADS)

    Lou, Fangyuan; Fleming, Ryan; Key, Nicole L.

    2012-12-01

    To improve the understanding of high performance centrifugal compressors found in modern aircraft engines, the aerodynamics through these machines must be experimentally studied. To accurately capture the complex flow phenomena through these devices, research facilities that can accurately simulate these flows are necessary. One such facility has been recently developed, and it is used in this paper to explore the effects of averaging total pressure and total temperature measurements to calculate compressor performance. Different averaging techniques (including area averaging, mass averaging, and work averaging) have been applied to the data. Results show that there is a negligible difference in both the calculated total pressure ratio and efficiency for the different techniques employed. However, the uncertainty in the performance parameters calculated with the different averaging techniques is significantly different, with area averaging providing the least uncertainty.

  19. Low Temperature Irradiation Embrittlement of Reactor Pressure Vessel Steels

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wang, Jy-An John

    2015-08-01

    The embrittlement trend curve development project for HFIR reactor pressure vessel (RPV) steels was carried out with three major tasks. Which are (1) data collection to match that used in HFIR steel embrittlement trend published in 1994 Journal Nuclear Material by Remec et. al, (2) new embrittlement data of A212B steel that are not included in earlier HFIR RPV trend curve, and (3) the adjustment of nil-ductility-transition temperature (NDTT) shift data with the consideration of the irradiation temperature effect. An updated HFIR RPV steel embrittlement trend curve was developed, as described below. NDTT( C) = 23.85 log(x) + 203.3 logmore » (x) + 434.7, with 2- uncertainty of 34.6 C, where parameter x is referred to total dpa. The developed update HFIR RPV embrittlement trend curve has higher embrittlement rate compared to that of the trend curve developed in 1994.« less

  20. Atomization, drop size, and penetration for cross-stream water injection at high-altitude reentry conditions with application to the RAM C-1 and C-3 flights

    NASA Technical Reports Server (NTRS)

    Gooderum, P. B.; Bushnell, D. M.

    1972-01-01

    Atomization, drop size, and penetration data are presented for cross stream water injection at conditions simulating high altitude reentry (low Weber number, high static temperature, high Knudsen number, and low static pressure). These results are applied to the RAM C-1 and C-3 flights. Two primary breakup modes are considered, vapor pressure or flashing and aerodynamic atomization. Results are given for breakup boundaries and mean drop size for each of these atomization mechanisms. Both standard and flight orifice geometries are investigated. The data were obtained in both a static environment and in conventional aerodynamic facilities at Mach numbers of 4.5 and 8. The high temperature aspects of reentry were simulated in a Mach 5.5 cyanogen-oxygen tunnel with total temperature of 4500 K.

  1. Experimental evaluation of two premixing-prevaporizing fuel injection concepts for a gas turbine catalytic combustor

    NASA Technical Reports Server (NTRS)

    Tacina, R.

    1976-01-01

    A premixing-prevaporizing fuel system for a gas turbine catalytic combustor has been developed and evaluated. Spatial fuel distribution and degree of vaporization were measured at inlet temperatures up to 800 K and fuel-air ratios of 0.01 and 0.025. The test pressure was 0.5 MPa; velocity was 20 m/sec. Both a multiple-jet cross-stream injector and a splash-groove injector with a 30 deg air swirler exhibited a uniform fuel distribution and a high degree of vaporization with little total pressure drop. Fuel oxidation reactions were observed at the 800 K inlet air temperature, indicating that a different design concept is necessary for application with an automotive gas turbine.

  2. Simulated Altitude Performance of Combustor of Westinghouse 19XB-1 Jet-Propulsion Engine

    NASA Technical Reports Server (NTRS)

    Childs, J. Howard; McCafferty, Richard J.

    1948-01-01

    A 19XB-1 combustor was operated under conditions simulating zero-ram operation of the 19XB-1 turbojet engine at various altitudes and engine speeds. The combustion efficiencies and the altitude operational limits were determined; data were also obtained on the character of the combustion, the pressure drop through the combustor, and the combustor-outlet temperature and velocity profiles. At altitudes about 10,000 feet below the operational limits, the flames were yellow and steady and the temperature rise through the combustor increased with fuel-air ratio throughout the range of fuel-air ratios investigated. At altitudes near the operational limits, the flames were blue and flickering and the combustor was sluggish in its response to changes in fuel flow. At these high altitudes, the temperature rise through the combustor increased very slowly as the fuel flow was increased and attained a maximum at a fuel-air ratio much leaner than the over-all stoichiometric; further increases in fuel flow resulted in decreased values of combustor temperature rise and increased resonance until a rich-limit blow-out occurred. The approximate operational ceiling of the engine as determined by the combustor, using AN-F-28, Amendment-3, fuel, was 30,400 feet at a simulated engine speed of 7500 rpm and increased as the engine speed was increased. At an engine speed of 16,000 rpm, the operational ceiling was approximately 48,000 feet. Throughout the range of simulated altitudes and engine speeds investigated, the combustion efficiency increased with increasing engine speed and with decreasing altitude. The combustion efficiency varied from over 99 percent at operating conditions simulating high engine speed and low altitude operation to less than 50 percent at conditions simulating operation at altitudes near the operational limits. The isothermal total pressure drop through the combustor was 1.82 times as great as the inlet dynamic pressure. As expected from theoretical considerations, a straight-line correlation was obtained when the ratio of the combustor total pressure drop to the combustor-inlet dynamic pressure was plotted as a function of the ratio of the combustor-inlet air density to the combustor-outlet gas density. The combustor-outlet temperature profiles were, in general, more uniform for runs in which the temperature rise was low and the combustion efficiency was high. Inspection of the combustor basket after 36 hours of operation showed very little deterioration and no appreciable carbon deposits.

  3. Near Space Lab-Rat Experimentation using Stratospheric Balloon

    NASA Astrophysics Data System (ADS)

    Buduru, Suneel Kumar; Reddy Vizapur, Anmi; Rao Tanneeru, Venkateswara; Trivedi, Dharmesh; Devarajan, Anand; Pandit Manikrao Kulkarni, MR..; Ojha, Devendra; Korra, Sakram; Neerudu, Nagendra; Seng, Lim; Godi, Stalin Peter

    2016-07-01

    First ever balloon borne lab-rat experiment up to near space stratospheric altitude levels carried out at TIFR Balloon Facility, Hydeabad using zero pressure balloons for the purpose of validating the life support system. A series of two balloon experiments conducted under joint collaboration with IN.Genius, Singapore in the year 2015. In these experiments, three lab-rats sent to stratosphere in a pressurized capsule designed to reach an altitude of 30 km by keeping constant pressure, temperature and maintained at a precise rate of oxygen supply inside the capsule. The first experiment conducted on 1 ^{st} February, 2015 with a total suspended weight of 225 kg. During the balloon ascent stage at 18 km altitude, sensors inside the capsule reported drastic drop in internal pressure while oxygen and temperatures maintained at correct levels resulted in premature fligt termination at 20.1 km. All the three lab-rats recovered without life due to the collapse of their lungs caused by the depressurization inside the capsule. The second experiment conducted on 14th March, 2015 using a newly developed capsule with rectification of depressurization fault by using improved sealing gaskets and hermitically sealed connectors for sending lab-rats again to stratosphere comprising a total suspended load of 122.3 kg. The balloon flight was terminated after reaching 29.5 km in 110 minutes and succesfully recovered all the three lab-rats alive. This paper focuses on lessons learnt of the development of the life support system as an integral pressurized vessel, flight control instrumentation, flight simulation tests using thermo-vaccum chamber with pre-flight operations.

  4. Ultrasonic techniques for measuring physical properties of fluids in harsh environments

    NASA Astrophysics Data System (ADS)

    Pantea, Cristian

    Ultrasonic-based measurement techniques, either in the time domain or in the frequency domain, include a wide range of experimental methods for investigating physical properties of materials. This discussion is specifically focused on ultrasonic methods and instrumentation development for the determination of liquid properties at conditions typically found in subsurface environments (in the U.S., more than 80% of total energy needs are provided by subsurface energy sources). Such sensors require materials that can withstand harsh conditions of high pressure, high temperature and corrosiveness. These include the piezoelectric material, electrically conductive adhesives, sensor housings/enclosures, and the signal carrying cables, to name a few. A complete sensor package was developed for operation at high temperatures and pressures characteristic to geothermal/oil-industry reservoirs. This package is designed to provide real-time, simultaneous measurements of multiple physical parameters, such as temperature, pressure, salinity and sound speed. The basic principle for this sensor's operation is an ultrasonic frequency domain technique, combined with transducer resonance tracking. This multipurpose acoustic sensor can be used at depths of several thousand meters, temperatures up to 250 °C, and in a very corrosive environment. In the context of high precision measurement of sound speed, the determination of acoustic nonlinearity of liquids will also be discussed, using two different approaches: (i) the thermodynamic method, in which precise and accurate frequency domain sound speed measurements are performed at high pressure and high temperature, and (ii) a modified finite amplitude method, requiring time domain measurements of the second harmonic at room temperature. Efforts toward the development of an acoustic source of collimated low-frequency (10-150 kHz) beam, with applications in imaging, will also be presented.

  5. 21 CFR 172.260 - Oxidized polyethylene.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... HUMAN CONSUMPTION (CONTINUED) FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION... polyethylene has a minimum number average molecular weight of 1,200, as determined by high temperature vapor pressure osmometry; contains a maximum of 5 percent by weight of total oxygen; and has an acid value of 9...

  6. A field study of the ventilatory response to ambient temperature and pressure in sport diving.

    PubMed Central

    Muller, F L

    1995-01-01

    This study reports on the relationship between minute ventilation (VE) and environmental variables of temperature (T) and pressure (P) during open water diving. The author conducted a total of 38 dives involving either a light (20 dives) or a moderate (18 dives) level of physical activity. Within each of these groups, P and T taken together accounted for about two thirds of the variance in the VE data. A very significant increase in VE was observed as T decreased (1 < T(degrees C) < 22), and the magnitude of this increase at a given pressure level was similar in the 'light' and the 'moderate' data sets. A second order observation, particularly notable at lower temperature, was the decrease in VE with increasing pressure under conditions of light work. Empirical functions of the from VE = A+B/P n[1 + exp(T - 8)/10], where A, B, and n are adjustable variables, could accommodate both data sets over the whole range of T and P. These results are the first obtained under actual diving conditions to provide evidence for interactions between P, T, and VE. Understanding the physiological mechanisms by which these interactions occur would assist in appreciation of the limitations imposed on scuba divers by the environmental conditions as they affect their ventilatory responses. PMID:8800853

  7. FAST TRACK COMMUNICATION: Finite-temperature magnetism in bcc Fe under compression

    NASA Astrophysics Data System (ADS)

    Sha, Xianwei; Cohen, R. E.

    2010-09-01

    We investigate the contributions of finite-temperature magnetic fluctuations to the thermodynamic properties of bcc Fe as functions of pressure. First, we apply a tight-binding total-energy model parameterized to first-principles linearized augmented plane-wave computations to examine various ferromagnetic, anti-ferromagnetic, and noncollinear spin spiral states at zero temperature. The tight-binding data are fit to a generalized Heisenberg Hamiltonian to describe the magnetic energy functional based on local moments. We then use Monte Carlo simulations to compute the magnetic susceptibility, the Curie temperature, heat capacity, and magnetic free energy. Including the finite-temperature magnetism improves the agreement with experiment for the calculated thermal expansion coefficients.

  8. Low-Temperature Collisional Broadening in the Far-Infrared Centrifugal Distortion Spectrum of CH_4

    NASA Astrophysics Data System (ADS)

    Boudon, Vincent; Vander Auwera, Jean; Manceron, Laurent; Kwabia Tchana, F.; Gabard, Tony; Amyay, Badr; Faye, Mbaye

    2015-06-01

    Previously, we could record on the AILES Beamline at the SOLEIL Synchrotron facility the first resolved centrifugal distorsion spectrum of methane (CH_4) in the THz region, which led to a precise determination of line intensities Later, we could measure collisional self- and N_2-broadening coefficients at room temperature. This time, we reinvestigated this topic by measuring these broadening coefficients at low temperature (between 120~K and 160~K) for J=5 to 12, thanks to a cryogenic multipass cell. We used a 93~m total optical path length. Five pure methane pressures (from 10 to 100 mbar) and four CH_4/N_2 mixtures (20~% of methane with a total pressure from 100 to 800 mbar) were used. These measurements allow us to obtain data for physical conditions approaching those of Titan's atmosphere and to estimate temperature exponents. V. Boudon, O. Pirali, P. Roy, J.-B. Brubach, L. Manceron and J. Vander Auwera, J. Quant. Spectrosc. Radiate. Transfer, 111, 1117--1129 (2010). M. Sanzharov, J. Vander Auwera, O. Pirali, P. Roy, J.-B. Brubach, L. Manceron, T. Gabard and V. Boudon, J. Quant. Spectrosc. Radiate. Transfer, 113, 1874--1886 (2012). F. Kwabia Tchana, F. Willaert, X. Landshere, J.-M. Flaud, L. Lago, M. Chapuis, C. Herbeaux, P. Roy and L. Manceron, Rev. Sci. Instrum., 84, 093101 (2013).

  9. Laser Probes of Propellant Combustion Chemistry.

    DTIC Science & Technology

    1987-08-01

    fluorescence. The temperature was 1250 4 et tojr total pressure, and kQ(C02 ) - 1.9 x 10 cm s . 80 -For various gases, several such experiments were done, the...Sections 1100 K (A2) Gas SF NH1 CO C4 H H N N0 02 C02 H0 C M 2 N 3 0 a0. 4 0.7 13 2 20 15 10 39 11 2 a/theory 0.002 0.14 .20 .29 .35 .32 .28 .45 .27...In contrast, the 10 high-pressure Arrhenius plots are only slightly curved upward; thus, high-pressure activation Sk, n energies between 1000 and 2500K

  10. Low-pressure chemical vapor deposition of low in situ phosphorus doped silicon thin films

    NASA Astrophysics Data System (ADS)

    Sarret, M.; Liba, A.; Bonnaud, O.

    1991-09-01

    In situ low phosphorus doped silicon films are deposited onto glass substrates by low-pressure chemical vapor deposition method. The deposition parameters, temperature, total pressure, and pure silane gas flow are, respectively, fixed at 550 °C, 0.08 Torr, and 50 sccm. The varying deposition parameter is phosphine/silane mole ratio; when this ratio varies from 2×10-6 to 4×10-4, the phosphorus concentration and the resistivity after annealing, respectively, vary from 2×1018 to 3×1020 atoms cm-3 and from 1.5 Ω cm to 2.5×10-3 Ω cm.

  11. Study of methods of improving the performance of the Langley Research Center Transonic Dynamics Tunnel (TDT)

    NASA Technical Reports Server (NTRS)

    1973-01-01

    A study has been made of possible ways to improve the performance of the Langley Research Center's Transonic Dynamics Tunnel (TDT). The major effort was directed toward obtaining increased dynamic pressure in the Mach number range from 0.8 to 1.2, but methods to increase Mach number capability were also considered. Methods studied for increasing dynamic pressure capability were higher total pressure, auxiliary suction, reducing circuit losses, reduced test medium temperature, smaller test section and higher molecular weight test medium. Increased Mach number methods investigated were nozzle block inserts, variable geometry nozzle, changes in test section wall configuration, and auxiliary suction.

  12. Selected meteorological data for an arid site near Beatty, Nye County, Nevada, calendar years 1990 and 1991

    USGS Publications Warehouse

    Wood, James L.; Andraski, Brian J.

    1995-01-01

    Selected meteorological data were collected at a study site adjacent to a low-level radioactive-waste burial facility near Beatty, Nevada, for calendar years 1990 and 1991. Data were collected in support of ongoing studies to estimate the potential for downward movement of radionuclides into the unsaturated sediments beneath waste-burial trenches at the facility. The data include air temperature, relative humidity, vapor pressure, incident solar radiation, windspeed, wind direction, barometric pressure, and precipitation. The data are summarized in tables and graphs.Instrumentation used at the site is discussed. The discussion includes the type, reported accuracy, and mounting height of each sensor.In 1990, the average hourly air temperatures ranged from -16.2 degrees Celsius, in December, to 44.2 degrees Celsius, in July. Hourly averaged relative humidity ranged from 6 percent to more than 90 percent. Hourly vapor pressures ranged from 0.08 to 1.84 kilopascals. Daily maximum incident solar radiation values ranged from 192 to 1,028 watts per square meter. Daily mean windspeed ranged from less than 1 to 8.7 meters per second. Wind direction was primarily from the northwest in fall, winter, and spring and varied from southeast, southwest, or northwest during the summer. Hourly barometric pressures ranged from 99.47 to 103.12 kilopascals. Total precipitation for 1990 was 32.4 millimeters; almost 45 percent was in September.In 1991, the average hourly air temperatures ranged from -9.2 degrees Celsius, in January, to 43.7 degrees Celsius, in July. Hourly averaged relative humidity ranged from 3 percent to more than 95 percent. Hourly vapor pressures ranged from 0.07 to 2.22 kilopascals. Daily maximum incident solar radiation values ranged from 143 to 1,041 watts per square meter. Daily mean windspeed ranged from 1.2 to 8.4 meters per second. Wind direction was primarily from the northwest in fall, winter, and spring and varied from southeast, southwest, or northwest during the summer. Hourly barometric pressures ranged from 99.52 to 103.40 kilopascals. Total precipitation for 1991 was 103.6 millimeters; almost 60 percent was in March.

  13. Experimental investigation of a Mach 6 fixed-geometry inlet featuring a swept external-internal compression flow field

    NASA Technical Reports Server (NTRS)

    Torrence, M. G.

    1975-01-01

    An investigation of a fixed-geometry, swept external-internal compression inlet was conducted at a Mach number of 6.0 and a test-section Reynolds number of 1.55 x 10 to the 7th power per meter. The test conditions was constant for all runs with stagnation pressure and temperature at 20 atmospheres and 500 K, respectively. Tests were made at angles of attack of -5 deg, 0 deg, 3 deg, and 5 deg. Measurements consisted of pitot- and static-pressure surveys in inlet throat, wall static pressures, and surface temperatures. Boundary-layer bleed was provided on the centerbody and on the cowl internal surface. The inlet performance was consistently high over the range of the angle of attack tested, with an overall average total pressure recovery of 78 percent and corresponding adiabatic kinetic-energy efficiency of 99 percent. The inlet throat flow distribution was uniform and the Mach number and pressure level were of the correct magnitude for efficient combustor design. The utilization of a swept compression field to meet the starting requirements of a fixed-geometry inlet produced neither flow instability nor a tendency to unstart.

  14. Is atmospheric pressure change an Independent risk factor for hemoptysis?

    PubMed

    Araz, Omer; Ucar, Elif Yilmazel; Akgun, Metin; Aydin, Yener; Meral, Mehmet; Saglam, Leyla; Kaynar, Hasan; Gorguner, Ali Metin

    2014-05-01

    Hemoptysis is one of the most important and challenging symptoms in pulmonary medicine. Because of the increased number of patients with hemoptysis in certain periods of the year, we aimed to investigate whether atmospheric changes have an effect on the development of hemoptysis with or without a secondary cause. The data of patients presenting with hemoptysis between January 2006 and December 2011 were analyzed. Data on the daily atmospheric pressure (hectopascal, hPa), relative humidity (%), and temperature ((o) C) during that time were obtained. A total of 232 patients with hemoptysis, 145 male (62.5%) and 87 female (37.5%) with an average age of 48.1(±17.6), were admitted to our hospital between 2006 and 2011. The highest admission rates were in the spring season, the highest in May (n=37, 15.9%), and the lowest admission rates were in December (n=10, 4.3%). A statistically significant negative correlation was found between the number of hemoptysis cases and mean atmospheric pressure but no relative humidity or outdoor temperature. Hemoptysis is very much influenced by weather factors; in particular, low atmospheric pressures significantly affect the development of hemoptysis. Fluctuations in atmospheric pressure may also play a role in hemoptysis.

  15. Potential efficiencies of open- and closed-cycle CO, supersonic, electric-discharge lasers

    NASA Technical Reports Server (NTRS)

    Monson, D. J.

    1976-01-01

    Computed open- and closed-cycle system efficiencies (laser power output divided by electrical power input) are presented for a CW carbon monoxide, supersonic, electric-discharge laser. Closed-system results include the compressor power required to overcome stagnation pressure losses due to supersonic heat addition and a supersonic diffuser. The paper shows the effect on the system efficiencies of varying several important parameters. These parameters include: gas mixture, gas temperature, gas total temperature, gas density, total discharge energy loading, discharge efficiency, saturated gain coefficient, optical cavity size and location with respect to the discharge, and supersonic diffuser efficiency. Maximum open-cycle efficiency of 80-90% is predicted; the best closed-cycle result is 60-70%.

  16. MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc-MOF for CH4, O2, and CO2 Storage

    PubMed Central

    2015-01-01

    The molecular building block approach was employed effectively to construct a series of novel isoreticular, highly porous and stable, aluminum-based metal–organic frameworks with soc topology. From this platform, three compounds were experimentally isolated and fully characterized: namely, the parent Al-soc-MOF-1 and its naphthalene and anthracene analogues. Al-soc-MOF-1 exhibits outstanding gravimetric methane uptake (total and working capacity). It is shown experimentally, for the first time, that the Al-soc-MOF platform can address the challenging Department of Energy dual target of 0.5 g/g (gravimetric) and 264 cm3 (STP)/cm3 (volumetric) methane storage. Furthermore, Al-soc-MOF exhibited the highest total gravimetric and volumetric uptake for carbon dioxide and the utmost total and deliverable uptake for oxygen at relatively high pressures among all microporous MOFs. In order to correlate the MOF pore structure and functionality to the gas storage properties, to better understand the structure–property relationship, we performed a molecular simulation study and evaluated the methane storage performance of the Al-soc-MOF platform using diverse organic linkers. It was found that shortening the parent Al-soc-MOF-1 linker resulted in a noticeable enhancement in the working volumetric capacity at specific temperatures and pressures with amply conserved gravimetric uptake/working capacity. In contrast, further expansion of the organic linker (branches and/or core) led to isostructural Al-soc-MOFs with enhanced gravimetric uptake but noticeably lower volumetric capacity. The collective experimental and simulation studies indicated that the parent Al-soc-MOF-1 exhibits the best compromise between the volumetric and gravimetric total and working uptakes under a wide range of pressure and temperature conditions. PMID:26364990

  17. RP-1 Thermal Stability and Copper Based Materials Compatibility Study

    NASA Technical Reports Server (NTRS)

    Stiegemeier, B. R.; Meyer, M. L.; Driscoll, E.

    2005-01-01

    A series of electrically heated tube tests was performed at the NASA Glenn Research Center s Heated Tube Facility to investigate the effect that sulfur content, test duration, and tube material play in the overall thermal stability and materials compatibility characteristics of RP-1. Scanning-electron microscopic (SEM) analysis in conjunction with energy dispersive spectroscopy (EDS) were used to characterize the condition of the tube inner wall surface and any carbon deposition or corrosion formed during these runs. Results of the parametric study indicate that tests with standard RP-1 (total sulfur -23 ppm) and pure copper tubing are characterized by a depostion/deposit shedding process producing local wall temperature swings as high as 500 F. The effect of this shedding is to keep total carbon deposition levels relatively constant for run times from 20 minutes up to 5 hours, though increasing tube pressure drops were observed in all runs. Reduction in the total sulfur content of the fuel from 23 ppm to less than 0.1 ppm resulted in the elimination of deposit shedding, local wall temperature variation, and the tube pressure drop increases that were observed in standard sulfur level RP-1 tests. The copper alloy GRCop-84, a copper alloy developed specifically for high heat flux applications, was found to exhibit higher carbon deposition levels compared to identical tests performed in pure copper tubes. Results of the study are consistent with previously published heated tube data which indicates that small changes in fuel total sulfur content can lead to significant differences in the thermal stability of kerosene type fuels and their compatibility with copper based materials. In conjunction with the existing thermal stability database, these findings give insight into the feasibility of cooling a long life, high performance, high-pressure liquid rocket combustor and nozzle with RP-1.

  18. MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc-MOF for CH4, O2, and CO2 Storage.

    PubMed

    Alezi, Dalal; Belmabkhout, Youssef; Suyetin, Mikhail; Bhatt, Prashant M; Weseliński, Łukasz J; Solovyeva, Vera; Adil, Karim; Spanopoulos, Ioannis; Trikalitis, Pantelis N; Emwas, Abdul-Hamid; Eddaoudi, Mohamed

    2015-10-21

    The molecular building block approach was employed effectively to construct a series of novel isoreticular, highly porous and stable, aluminum-based metal-organic frameworks with soc topology. From this platform, three compounds were experimentally isolated and fully characterized: namely, the parent Al-soc-MOF-1 and its naphthalene and anthracene analogues. Al-soc-MOF-1 exhibits outstanding gravimetric methane uptake (total and working capacity). It is shown experimentally, for the first time, that the Al-soc-MOF platform can address the challenging Department of Energy dual target of 0.5 g/g (gravimetric) and 264 cm(3) (STP)/cm(3) (volumetric) methane storage. Furthermore, Al-soc-MOF exhibited the highest total gravimetric and volumetric uptake for carbon dioxide and the utmost total and deliverable uptake for oxygen at relatively high pressures among all microporous MOFs. In order to correlate the MOF pore structure and functionality to the gas storage properties, to better understand the structure-property relationship, we performed a molecular simulation study and evaluated the methane storage performance of the Al-soc-MOF platform using diverse organic linkers. It was found that shortening the parent Al-soc-MOF-1 linker resulted in a noticeable enhancement in the working volumetric capacity at specific temperatures and pressures with amply conserved gravimetric uptake/working capacity. In contrast, further expansion of the organic linker (branches and/or core) led to isostructural Al-soc-MOFs with enhanced gravimetric uptake but noticeably lower volumetric capacity. The collective experimental and simulation studies indicated that the parent Al-soc-MOF-1 exhibits the best compromise between the volumetric and gravimetric total and working uptakes under a wide range of pressure and temperature conditions.

  19. Diode-Laser Absorption Sensor for Line-of-Sight Gas Temperature Distributions

    NASA Astrophysics Data System (ADS)

    Sanders, Scott T.; Wang, Jian; Jeffries, Jay B.; Hanson, Ronald K.

    2001-08-01

    Line-of-sight diode-laser absorption techniques have been extended to enable temperature measurements in nonuniform-property flows. The sensing strategy for such flows exploits the broad wavelength-scanning abilities ( >1.7 nm ~ 30 cm-1 ) of a vertical cavity surface-emitting laser (VCSEL) to interrogate multiple absorption transitions along a single line of sight. To demonstrate the strategy, a VCSEL-based sensor for oxygen gas temperature distributions was developed. A VCSEL beam was directed through paths containing atmospheric-pressure air with known (and relatively simple) temperature distributions in the 200 -700 K range. The VCSEL was scanned over ten transitions in the R branch of the oxygen A band near 760 nm and optionally over six transitions in the P branch. Temperature distribution information can be inferred from these scans because the line strength of each probed transition has a unique temperature dependence; the measurement accuracy and resolution depend on the details of this temperature dependence and on the total number of lines scanned. The performance of the sensing strategy can be optimized and predicted theoretically. Because the sensor exhibits a fast time response ( ~30 ms) and can be adapted to probe a variety of species over a range of temperatures and pressures, it shows promise for industrial application.

  20. Fundamental phenomena on fuel decomposition and boundary-layer combustion processes with applications to hybrid rocket motors

    NASA Technical Reports Server (NTRS)

    Kuo, Kenneth K.; Lu, Yeu-Cherng; Chiaverini, Martin J.; Harting, George C.; Johnson, David K.; Serin, Nadir

    1995-01-01

    The experimental study on the fundamental processes involved in fuel decomposition and boundary-layer combustion in hybrid rocket motors is continuously being conducted at the High Pressure Combustion Laboratory of The Pennsylvania State University. This research will provide a useful engineering technology base in the development of hybrid rocket motors as well as a fundamental understanding of the complex processes involved in hybrid propulsion. A high-pressure, 2-D slab motor has been designed, manufactured, and utilized for conducting seven test firings using HTPB fuel processed at PSU. A total of 20 fuel slabs have been received from the Mcdonnell Douglas Aerospace Corporation. Ten of these fuel slabs contain an array of fine-wire thermocouples for measuring solid fuel surface and subsurface temperatures. Diagnostic instrumentation used in the test include high-frequency pressure transducers for measuring static and dynamic motor pressures and fine-wire thermocouples for measuring solid fuel surface and subsurface temperatures. The ultrasonic pulse-echo technique as well as a real-time x-ray radiography system have been used to obtain independent measurements of instantaneous solid fuel regression rates.

  1. The Combined Influence of Hydrostatic Pressure and Temperature on Nonlinear Optical Properties of GaAs/Ga0.7Al0.3As Morse Quantum Well in the Presence of an Applied Magnetic Field.

    PubMed

    Zhang, Zhi-Hai; Yuan, Jian-Hui; Guo, Kang-Xian

    2018-04-25

    Studies aimed at understanding the nonlinear optical (NLO) properties of GaAs/Ga 0.7 Al 0.3 As morse quantum well (QW) have focused on the intersubband optical absorption coefficients (OACs) and refractive index changes (RICs). These studies have taken two complimentary approaches: (1) The compact-density-matrix approach and iterative method have been used to obtain the expressions of OACs and RICs in morse QW. (2) Finite difference techniques have been used to obtain energy eigenvalues and their corresponding eigenfunctions of GaAs/Ga 0.7 Al 0.3 As morse QW under an applied magnetic field, hydrostatic pressure, and temperature. Our results show that the hydrostatic pressure and magnetic field have a significant influence on the position and the magnitude of the resonant peaks of the nonlinear OACs and RICs. Simultaneously, a saturation case is observed on the total absorption spectrum, which is modulated by the hydrostatic pressure and magnetic field. Physical reasons have been analyzed in depth.

  2. Fundamental phenomena on fuel decomposition and boundary-layer combustion processes with applications to hybrid rocket motors

    NASA Astrophysics Data System (ADS)

    Kuo, Kenneth K.; Lu, Yeu-Cherng; Chiaverini, Martin J.; Harting, George C.; Johnson, David K.; Serin, Nadir

    The experimental study on the fundamental processes involved in fuel decomposition and boundary-layer combustion in hybrid rocket motors is continuously being conducted at the High Pressure Combustion Laboratory of The Pennsylvania State University. This research will provide a useful engineering technology base in the development of hybrid rocket motors as well as a fundamental understanding of the complex processes involved in hybrid propulsion. A high-pressure, 2-D slab motor has been designed, manufactured, and utilized for conducting seven test firings using HTPB fuel processed at PSU. A total of 20 fuel slabs have been received from the Mcdonnell Douglas Aerospace Corporation. Ten of these fuel slabs contain an array of fine-wire thermocouples for measuring solid fuel surface and subsurface temperatures. Diagnostic instrumentation used in the test include high-frequency pressure transducers for measuring static and dynamic motor pressures and fine-wire thermocouples for measuring solid fuel surface and subsurface temperatures. The ultrasonic pulse-echo technique as well as a real-time x-ray radiography system have been used to obtain independent measurements of instantaneous solid fuel regression rates.

  3. Investigations on the Influence of the In-Stream Pylon and Strut on the Performance of a Scramjet Combustor

    PubMed Central

    Liu, Weidong; Sun, Mingbo

    2014-01-01

    The influence of the in-stream pylon and strut on the performance of scramjet combustor was experimentally and numerically investigated. The experiments were conducted with a direct-connect supersonic model combustor equipped with multiple cavities. The entrance parameter of combustor corresponds to scramjet flight Mach number 4.0 with a total temperature of 947 K. The research results show that, compared with the scramjet combustor without pylon and strut, the wall pressure and the thrust of the scramjet increase due to the improvement of mixing and combustion effect due to the pylon and strut. The total pressure loss caused by the strut is considerable whereas pylon influence is slight. PMID:25254234

  4. Modeling of a deep-seated geothermal system near Tianjin, China.

    PubMed

    Xun, Z; Mingyou, C; Weiming, Z; Minglang, L

    2001-01-01

    A geothermal field is located in deep-seated basement aquifers in the northeastern part of the North China Plain near Tianjin, China. Carbonate rocks of Ordovician and Middle and Upper Proterozoic age on the Cangxian Uplift are capable of yielding 960 to 4200 m3/d of 57 degrees C to 96 degrees C water to wells from a depth of more than 1000 m. A three-dimensional nonisothermal numerical model was used to simulate and predict the spatial and temporal evolution of pressure and temperature in the geothermal system. The density of the geothermal water, which appears in the governing equations, can be expressed as a linear function of pressure, temperature, and total dissolved solids. A term describing the exchange of heat between water and rock is incorporated in the governing heat transport equation. Conductive heat flow from surrounding formations can be considered among the boundary conditions. Recent data of geothermal water production from the system were used for a first calibration of the numerical model. The calibrated model was used to predict the future changes in pressure and temperature of the geothermal water caused by two pumping schemes. The modeling results indicate that both pressure and temperature have a tendency to decrease with time and pumping. The current withdrawal rates and a pumping period of five months followed by a shut-off period of seven months are helpful in minimizing the degradation of the geothermal resource potential in the area.

  5. Affect of Brush Seals on Wave Rotor Performance Assessed

    NASA Technical Reports Server (NTRS)

    1995-01-01

    The NASA Lewis Research Center's experimental and theoretical research shows that wave rotor topping can significantly enhance gas turbine engine performance levels. Engine-specific fuel consumption and specific power are potentially enhanced by 15 and 20 percent, respectively, in small (e.g., 400 to 700 hp) and intermediate (e.g., 3000 to 5000 hp) turboshaft engines. Furthermore, there is potential for a 3- to 6-percent specific fuel consumption enhancement in large (e.g., 80,000 to 100,000 lbf) turbofan engines. This wave-rotor-enhanced engine performance is accomplished within current material-limited temperature constraints. The completed first phase of experimental testing involved a three-port wave rotor cycle in which medium total pressure inlet air was divided into two outlet streams, one of higher total pressure and one of lower total pressure. The experiment successfully provided the data needed to characterize viscous, partial admission, and leakage loss mechanisms. Statistical analysis indicated that wave rotor product efficiency decreases linearly with the rotor to end-wall gap, the square of the friction factor, and the square of the passage of nondimensional opening time. Brush seals were installed to further minimize rotor passage-to-cavity leakage. The graph shows the effect of brush seals on wave rotor product efficiency. For the second-phase experiment, which involves a four-port wave rotor cycle in which heat is added to the Brayton cycle in an external burner, a one-dimensional design/analysis code is used in conjunction with a wave rotor performance optimization scheme and a two-dimensional Navier-Stokes code. The purpose of the four-port experiment is to demonstrate and validate the numerically predicted four-port pressure ratio versus temperature ratio at pressures and temperatures lower than those that would be encountered in a future wave rotor/demonstrator engine test. Lewis and the Allison Engine Company are collaborating to investigate wave rotor integration in an existing turboshaft engine. Recent theoretical efforts include simulating wave rotor dynamics (e.g., startup and load-change transient analysis), modifying the one-dimensional wave rotor code to simulate combustion internal to the wave rotor, and developing an analytical wave rotor design/analysis tool based on macroscopic balances for parametric wave rotor/engine analysis.

  6. Effect of high hydrostatic pressure on the polyphenols and antioxidant activity of plantain pulp (Musa paradisiaca AAB).

    PubMed

    Jiménez-Martínez, Miriam C; Montalvo-González, Efigenia; Sáyago-Ayerdi, Sonia G; Mercado-Mercado, Gilberto; Ramírez-de León, José A; Paz-Gamboa, Ernestina; Vivar-Vera, Maria A

    2017-06-01

    The impact of high-pressure processing (HPP) on the polyphenol (PP) content and antioxidant activity (AOX) of plantain pulp was evaluated. Pressures of 400, 500 and 600 MPa were applied to plantain pulp for 90 and 180 s at room temperature (25 °C). Polyphenoloxidase activity, extractable (EPP) and non-extractable PP (NEPP) contents, flavonoid content and AOX (FRAP, ABTS •+ ) were evaluated. In addition, PP identification was performed using high-performance liquid chromatography. Polyphenoloxidase activity was inhibited after HPP under all of the conditions studied. Increases of 110.80% and 137.40% in EPP content under conditions of 500 MPa/180 s and 600 MPa/90 s were observed with a simultaneous improvement in the AOX with increments of up to 128.71%. The treatment under conditions of 500 MPa/90 s had the highest total PP content, including the highest content of flavonoids (0.22 g ellagic acid equivalents kg -1  dry weight) and the proportion of NEPP that contained hydrolysable PPs (91.12 g gallic acid equivalents kg -1  dry weight with high AOX. The identified PPs included catechin, quercetin, gallic and hydroxybenzoic acids. HPP performed at a room temperature can be used for improving the total content of PP compounds in plantain pulp under specific pressure and time conditions. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

  7. Characterization of fuels for second-generation PFBC

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zevenhoven, C.A.P.; Hupa, M.

    1997-12-31

    In second-generation PFBC technology a solid fuel is partly converted in a devolatilization step (in a carbonizer) to produce a char and a pressurized fuel gas, followed by PFB combustion of the char. The fuel gas is led to the combustion chamber of a gas turbine after it is mixed with the PFBC off-gas, thus increasing the temperature at the inlet of the expansion turbine. Clearly, the optimization of the carbonizer design and operation is essential to the process. Detailed information on the behavior of solid fuels under pressurized conditions is, however, largely limited to steam and/or carbon dioxide gasificationmore » reactivities, obtained at a different combination of process parameters, such as temperature, pressure, heating rate, particle size and gas atmosphere. In the present work, the effect of temperature, pressure and heating rates on the yields of volatiles and char residue reactivity has been measured for a set of fuels ranging from bituminous coal to wood. Laboratory conditions were typical for the carbonizer and combustion reactors in a second-generation PFBC system. A pressurized thermogravimetric reactor (PTGR) operated at heating rates of around 250 K/s and a pressurized grid heater (PGH) operated at heating rates up to 3,000 K/s were used to analyze fuel devolatilization and char reactivity against carbon dioxide or steam at temperatures between 800 and 1,100 C, and 1, 10 or 25 bar total pressure. For comparison, a few experiments were repeated without a separate devolatilization step. The behavior of the various fuels were compared and related to proximate and ultimate fuel analysis. Several empirical, engineering equations are given. A simple 2-parameter model which separates intrinsic surface reactivity and physical, structure effects, very well describes the time-conversion data of the char. It was found that the fuel O/C molar ratio is a very good index for char reactivity, when the char O/C ratio itself is unknown.« less

  8. Effects of temperature and pressure on the performance of a solid oxide fuel cell running on steam reformate of kerosene

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chick, Lawrence A.; Marina, Olga A.; Coyle, Christopher A.

    2013-08-15

    A button solid oxide fuel cell with a La0.6Sr0.4Co0.2Fe0.8O3 cathode and a nickel-YSZ anode was tested over a range of temperatures from 650 to 800°C and a range of pressures from 101 to 724 kPa. The fuel was simulated steam-reformed kerosene and the oxidant was air. The observed increases in open circuit voltages (OCV) were accurately predicted by the Nernst equation. Kinetics also increased, although the power boost due to kinetics was about two thirds as large as the boost due to OCV. The total power boost in going from 101 to 724 kPa at 750°C and 0.8 volts wasmore » 66%. Impedance spectroscopy demonstrated a significant decrease in electrodic losses at elevated pressures. Complex impedance spectra were dominated by a combination of low frequency processes that decreased markedly with increasing pressure. A composite of high-frequency processes also decreased with pressure, but to a lesser extent. An empirical algorithm that accurately predicts the increased fuel cell performance at elevated pressures was developed for our results and was also suitable for some, but not all, data reported in the literature.« less

  9. Diagnostics of N2 Ar plasma mixture excited in a 13.56 MHz hollow cathode discharge system: application to remote plasma treatment of polyamide surface

    NASA Astrophysics Data System (ADS)

    Saloum, S.; Naddaf, M.; Alkhaled, B.

    2008-02-01

    N2-x% Ar plasma gas mixture, generated in a hollow cathode RF discharge system, has been characterized by both optical emission spectroscopy (OES) and double Langmuir probe, as a function of experimental parameters: total pressure (5-33 Pa), and different fractions of argon (7 <= x <= 80), at a constant applied RF power of 300 W. N2 dissociation degree has been investigated qualitatively by both the actinometry method and the ratio I_N/I_{N_2} of the atomic nitrogen line emission intensity at 672.3 nm to the vibrational band (0-0) of the N2 second positive system at 337.1 nm. Both methods showed that the increase in argon fraction enhances the dissociation of N2, with a maximum at x = 50 for the pressure of 5 Pa, although the two methods give two opposite trends as a function of total pressure. Spectroscopic measurements showed that the vibrational temperature of the N2 second positive system increases with both argon fraction and total pressure increase, it lies between 4900 and 12 300 K. Langmuir probe measurements showed that, in the remote zone, the electron temperature falls in the range 1.57-1.75 eV, the N_{2}^{+} density varies between 5 × 109 and 1.4 × 1010 cm-3 and that both the plasma ionization degree and electron temperature increase towards the source. In addition, the process of plasma-polyamide (PA) surface interaction, in the remote plasma zone, has been studied through OES analysis during plasma treatment of PA to monitor the possible emissions due to the polymer etching. An increase in atomic nitrogen line (672.3 nm) intensity is obtained, atomic carbon line (833.52 nm) and the band emission (0-0) from the CN (B 2Σ+-X 2Σ+) violet system were observed. The PA surface modification has been confirmed through the improvement of its hydrophilic character as the water contact angle measured after the plasma treatment significantly decreased.

  10. Heat and moisture flow in concrete as a function of temperature

    NASA Technical Reports Server (NTRS)

    Hundt, J.

    1978-01-01

    Due to temperature, reactors in operation cause heat and moisture flows in the thick walled prestressed pressure vessels. These flows were studied in three beams of concrete made with crushed limestone aggregate, and in three beams made of crushed gravel/sand aggregate. The flow phenomena were related to the structural development of the concrete by determining the amount of non-evaporatable water, the total porosity, and the pore size distribution. Local temperature and moisture conditions also influenced the technical properties. Compressive strength, changes in length due to shrinkage and contraction, thermal expansion, and thermal conductivity were determined.

  11. Thermodynamic Vent System Performance Testing with Subcooled Liquid Methane and Gaseous Helium Pressurant

    NASA Technical Reports Server (NTRS)

    Flachbart, R. H.; Hastings, L. J.; Hedayat, A.; Nelson, S. L.; Tucker, S. P.

    2007-01-01

    Due to its high specific impulse and favorable thermal properties for storage, liquid methane (LCH4) is being considered as a candidate propellant for exploration architectures. In order to gain an -understanding of any unique considerations involving micro-gravity pressure control with LCH4, testing was conducted at the Marshall Space Flight Center using the Multipurpose Hydrogen Test Bed (MHTB) to evaluate the performance of a spray-bar thermodynamic vent system (TVS) with subcooled LCH4 and gaseous helium (GHe) pressurant. Thirteen days of testing were performed in November 2006, with total tank heat leak conditions of about 715 W and 420 W at a fill level of approximately 90%. The TVS system was used to subcool the LCH4 to a liquid saturation pressure of approximately 55.2 kPa before the tank was pressurized with GHe to a total pressure of 165.5 kPa. A total of 23 TVS cycles were completed. The TVS successfully controlled the ullage pressure within a prescribed control band but did not maintain a stable liquid saturation pressure. This was likely. due to a TVS design not optimized for this particular propellant and test conditions, and possibly due to a large artificially induced heat input directly into the liquid. The capability to reduce liquid saturation pressure as well as maintain it within a prescribed control band, demonstrated that the TVS could be used to seek and maintain a desired liquid inlet temperature for an engine (at a cost of propellant lost through the TVS vent). One special test was conducted at the conclusion of the planned test activities. Reduction of the tank ullage pressure by opening the Joule-Thomson valve (JT) without operating the pump was attempted. The JT remained open for over 9300 seconds, resulting in an ullage pressure reduction of 30 kPa. The special test demonstrated the feasibility of using the JT valve for limited ullage pressure reduction in the event of a pump failure.

  12. Uncertainty analysis of thermal quantities measurement in a centrifugal compressor

    NASA Astrophysics Data System (ADS)

    Hurda, Lukáš; Matas, Richard

    2017-09-01

    Compressor performance characteristics evaluation process based on the measurement of pressure, temperature and other quantities is examined to find uncertainties for directly measured and derived quantities. CFD is used as a tool to quantify the influences of different sources of uncertainty of measurements for single- and multi-thermocouple total temperature probes. The heat conduction through the body of the thermocouple probe and the heat-up of the air in the intake piping are the main phenomena of interest.

  13. Experimental evidence regarding the pressure dependence of fission track annealing in apatite

    NASA Astrophysics Data System (ADS)

    Schmidt, J. S.; Lelarge, M. L. M. V.; Conceicao, R. V.; Balzaretti, N. M.

    2014-03-01

    The main purposes of fission track thermochronology are unravelling the thermal histories of sedimentary basins, determining uplift and denudation rates, identifying the structural evolution of orogenic belts, determining sedimentary provenance, and dating volcanic rocks. The effect of temperature on fission tracks is well known and is used to determine the thermal history; however, the effect of pressure on the stability of tracks is still under debate. The present work aims to understand the role of pressure on the annealing kinetics of apatite fission tracks. The samples of Durango apatite used in our experiments were chosen for their international recognition as a calibration standard for geological dating. Neutron irradiation of the samples, after total annealing of their spontaneous tracks, produced induced tracks with homogeneous densities and lengths. The effect of pressure associated with temperature on fission track annealing was verified by experimental procedures using a hydraulic press of 1000 t with a toroidal chamber profile. The experiments consisted of a combination of applying 2 and 4 GPa with 20,150,190,235, and 290 °C for 1 and 10 h. The annealing rate was analysed by measuring the lengths of the fission tracks after each experiment using optical microscopy. The results demonstrate that the annealing of apatite fission tracks has a pressure dependence for samples subjected to 2 and 4 GPa. However, when extrapolated to pressures of ⩽150 MPa, compatible with the normal geological context in which apatite fission track methodology is broadly used, this dependence becomes insignificant compared to the temperature effect.

  14. Heat transfer, velocity-temperature correlation, and turbulent shear stress from Navier-Stokes computations of shock wave/turbulent boundary layer interaction flows

    NASA Technical Reports Server (NTRS)

    Wang, C. R.; Hingst, W. R.; Porro, A. R.

    1991-01-01

    The properties of 2-D shock wave/turbulent boundary layer interaction flows were calculated by using a compressible turbulent Navier-Stokes numerical computational code. Interaction flows caused by oblique shock wave impingement on the turbulent boundary layer flow were considered. The oblique shock waves were induced with shock generators at angles of attack less than 10 degs in supersonic flows. The surface temperatures were kept at near-adiabatic (ratio of wall static temperature to free stream total temperature) and cold wall (ratio of wall static temperature to free stream total temperature) conditions. The computational results were studied for the surface heat transfer, velocity temperature correlation, and turbulent shear stress in the interaction flow fields. Comparisons of the computational results with existing measurements indicated that (1) the surface heat transfer rates and surface pressures could be correlated with Holden's relationship, (2) the mean flow streamwise velocity components and static temperatures could be correlated with Crocco's relationship if flow separation did not occur, and (3) the Baldwin-Lomax turbulence model should be modified for turbulent shear stress computations in the interaction flows.

  15. Poloidal asymmetries in edge transport barriersa)

    NASA Astrophysics Data System (ADS)

    Churchill, R. M.; Theiler, C.; Lipschultz, B.; Hutchinson, I. H.; Reinke, M. L.; Whyte, D.; Hughes, J. W.; Catto, P.; Landreman, M.; Ernst, D.; Chang, C. S.; Hager, R.; Hubbard, A.; Ennever, P.; Walk, J. R.

    2015-05-01

    Measurements of impurities in Alcator C-Mod indicate that in the pedestal region, significant poloidal asymmetries can exist in the impurity density, ion temperature, and main ion density. In light of the observation that ion temperature and electrostatic potential are not constant on a flux surface [Theiler et al., Nucl. Fusion 54, 083017 (2014)], a technique based on total pressure conservation to align profiles measured at separate poloidal locations is presented and applied. Gyrokinetic neoclassical simulations with XGCa support the observed large poloidal variations in ion temperature and density, and that the total pressure is approximately constant on a flux surface. With the updated alignment technique, the observed in-out asymmetry in impurity density is reduced from previous publishing [Churchill et al., Nucl. Fusion 53, 122002 (2013)], but remains substantial ( n z , H / n z , L ˜ 6 ). Candidate asymmetry drivers are explored, showing that neither non-uniform impurity sources nor localized fluctuation-driven transport are able to explain satisfactorily the impurity density asymmetry. Since impurity density asymmetries are only present in plasmas with strong electron density gradients, and radial transport timescales become comparable to parallel transport timescales in the pedestal region, it is suggested that global transport effects relating to the strong electron density gradients in the pedestal are the main driver for the pedestal in-out impurity density asymmetry.

  16. First-principles theory of iron up to earth-core pressures: Structural, vibrational, and elastic properties

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Soederlind, P.; Moriarty, J.A.; Wills, J.M.

    1996-06-01

    {ital Ab} {ital initio} electronic-structure calculations, based on density-functional theory and a full-potential linear-muffin-tin-orbital method, have been used to predict crystal-structure phase stabilities, elastic constants, and Brillouin-zone-boundary phonons for iron under compression. Total energies for five crystal structures, bcc, fcc, bct, hcp, and dhcp, have been calculated over a wide volume range. In agreement with experiment and previous theoretical calculations, a magnetic bcc ground state is obtained at ambient pressure and a nonmagnetic hcp ground state is found at high pressure, with a predicted bcc {r_arrow} hcp phase transition at about 10 GPa. Also in agreement with very recent diamond-anvil-cellmore » experiments, a metastable dhcp phase is found at high pressure, which remains magnetic and consequently accessible at high temperature up to about 50 GPa. In addition, the bcc structure becomes mechanically unstable at pressures above 2 Mbar (200 GPa) and a metastable, but still magnetic, bct phase ({ital c}/{ital a} {approx_equal} 0.875) develops. For high-pressure nonmagnetic iron, fcc and hcp elastic constants and fcc phonon frequencies have been calculated to above 4 Mbar. These quantities rise smoothly with pressure, but an increasing tendency towards elastic anisotropy as a function of compression is observed, and this has important implications for the solid inner-core of the earth. The fcc elastic-constant and phonon data have also been used in combination with generalized pseudopotential theory to develop many-body interatomic potentials, from which high-temperature thermodynamic properties and melting can be obtained. In this paper, these potentials have been used to calculate full fcc and hcp phonon spectra and corresponding Debye temperatures as a function of compression. {copyright} {ital 1996 The American Physical Society.}« less

  17. Digibaro pressure instrument onboard the Phoenix Lander

    NASA Astrophysics Data System (ADS)

    Harri, A.-M.; Polkko, J.; Kahanpää, H. H.; Schmidt, W.; Genzer, M. M.; Haukka, H.; Savijarv1, H.; Kauhanen, J.

    2009-04-01

    The Phoenix Lander landed successfully on the Martian northern polar region. The mission is part of the National Aeronautics and Space Administration's (NASA's) Scout program. Pressure observations onboard the Phoenix lander were performed by an FMI (Finnish Meteorological Institute) instrument, based on a silicon diaphragm sensor head manufactured by Vaisala Inc., combined with MDA data processing electronics. The pressure instrument performed successfully throughout the Phoenix mission. The pressure instrument had 3 pressure sensor heads. One of these was the primary sensor head and the other two were used for monitoring the condition of the primary sensor head during the mission. During the mission the primary sensor was read with a sampling interval of 2 s and the other two were read less frequently as a check of instrument health. The pressure sensor system had a real-time data-processing and calibration algorithm that allowed the removal of temperature dependent calibration effects. In the same manner as the temperature sensor, a total of 256 data records (8.53 min) were buffered and they could either be stored at full resolution, or processed to provide mean, standard deviation, maximum and minimum values for storage on the Phoenix Lander's Meteorological (MET) unit.The time constant was approximately 3s due to locational constraints and dust filtering requirements. Using algorithms compensating for the time constant effect the temporal resolution was good enough to detect pressure drops associated with the passage of nearby dust devils.

  18. The temperature dependence of the reactions of HO2 with NO and NO2

    NASA Technical Reports Server (NTRS)

    Simonaitis, R.; Heicklen, J.

    1977-01-01

    Mixtures of N2O, H2, O2 and trace amounts of NO and NO2 were photolyzed at 213.9 nm at 245-328 K and about 1 atm total pressure (mostly H2). HO2 radicals are produced from the photolysis, and their reactions are reported.

  19. 21 CFR 172.260 - Oxidized polyethylene.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Coatings, Films and Related Substances... average molecular weight of 1,200, as determined by high temperature vapor pressure osmometry; contains a maximum of 5 percent by weight of total oxygen; and has an acid value of 9 to 19. (b) The additive is used...

  20. Growth Of Oriented Crystals At Polymerized Membranes

    DOEpatents

    Charych, Deborah H. , Berman, Amir

    2000-01-25

    The present invention relates to methods and compositions for the growth and alignment of crystals at biopolymeric films. The methods and compositions of the present invention provide means to generate a variety of dense crystalline ceramic films, with totally aligned crystals, at low temperatures and pressures, suitable for use with polymer and plastic substrates.

  1. [Optimization of supercritical fluid extraction of bioactive components in Ligusticum chuanxiong by orthogonal array design].

    PubMed

    Hu, Li-Cui; Wu, Xun; Yang, Xue-Dong

    2013-10-01

    With the yields of ferulic acid, coniferylferulate, Z-ligustilide, senkyunolide A, butylidenephthalide, butylphthalide, senkyunolide I, senkyunolide H, riligustilide, levistolide A, and total pharmacologically active ingredient as evaluation indexes, the extraction of Ligusticum chuanxiong by supercritical fluid technology was investigated through an orthogonal experiment L9 (3(4)). Four factors, namely temperature, pressure, flow rate of carbon dioxide, co-solvent concentration of the supercritical fluid, were investigated and optimized. Under the optimized conditions, namely 65 degrees C of temperature, 35 MPa of pressure, 1 L x min(-1) of CO2 flow rate, 8% of co-solvent concetration, supercritical fluid extraction could achieve a better yield than the conventional reflux extraction using methanol. And the supercritical fluid extraction process was validated to be stable and reliable.

  2. Solubility of carbon dioxide in aqueous solutions of 2-amino-2-methyl-1-propanol and N-methyldiethanolamine and their mixtures in the temperature range of 313 to 353 K and pressures up to 2.7 MPa

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Silkenbaeumer, D.; Lichtenthaler, R.N.; Rumpf, B.

    1998-08-01

    The solubility of carbon dioxide in aqueous solutions containing 2-amino-2-methyl-1-propanol (AMP) was measured in the temperature range from 313 to 353 K at total pressures up to 2.7 MPa using an analytical method. A model taking into account chemical reactions in the liquid phase as well as physical interactions is used to correlate the new data. To test the predictive capability of the model, the solubility of carbon dioxide in an aqueous solution containing AMP and N-methyldiethanolamine (MDEA) was measured at 313 K. Experimental results are reported and compared to literature data and calculations.

  3. Subcritical water extractor for Mars analog soil analysis.

    PubMed

    Amashukeli, Xenia; Grunthaner, Frank J; Patrick, Steven B; Yung, Pun To

    2008-06-01

    Abstract Technologies that enable rapid and efficient extraction of biomarker compounds from various solid matrices are a critical requirement for the successful implementation of in situ chemical analysis of the martian regolith. Here, we describe a portable subcritical water extractor that mimics multiple organic solvent polarities by tuning the dielectric constant of liquid water through adjustment of temperature and pressure. Soil samples, collected from the Yungay region of the Atacama Desert (martian regolith analogue) in the summer of 2005, were used to test the instrument's performance. The total organic carbon was extracted from the samples at concentrations of 0.2-55.4 parts per million. The extraction data were compared to the total organic carbon content in the bulk soil, which was determined via a standard analytical procedure. The instrument's performance was examined over the temperature range of 25-250 degrees C at a fixed pressure of 20.7 MPa. Under these conditions, water remains in a subcritical fluid state with a dielectric constant varying between approximately 80 (at 25 degrees C) and approximately 30 (at 250 degrees C).

  4. Application of response surface methodology to optimize pressurized liquid extraction of antioxidant compounds from sage (Salvia officinalis L.), basil (Ocimum basilicum L.) and thyme (Thymus vulgaris L.).

    PubMed

    Hossain, M B; Brunton, N P; Martin-Diana, A B; Barry-Ryan, C

    2010-12-01

    The present study optimized pressurized liquid extraction (PLE) conditions using Dionex ASE® 200, USA to maximize the antioxidant activity [Ferric ion Reducing Antioxidant Power (FRAP)] and total polyphenol content (TP) of the extracts from three spices of Lamiaceae family (sage, basil and thyme). Optimal conditions with regard to extraction temperature (66-129 °C) and solvent concentration (32-88% methanol) were identified using response surface methodology (RSM). For all three spices, results showed that 129 °C was the optimum temperature with regard to antioxidant activity. Optimal methanol concentrations with respect to the antioxidant activity of sage and basil extracts were 58% and 60% respectively. Thyme showed a different trend with regard to methanol concentration and was optimally extracted at 33%. Antioxidant activity yields of the optimal PLE were significantly (p < 0.05) higher than solid/liquid extracts. Predicted models were highly significant (p < 0.05) for both total phenol (TP) and FRAP values in all the spices with high regression coefficients (R(2)) ranging from 0.651 to 0.999.

  5. Determination of mass and heat transfer parameters during freeze-drying cycles of pharmaceutical products.

    PubMed

    Hottot, A; Vessot, S; Andrieu, J

    2005-01-01

    The principal aim of this study was to evaluate the water vapour mass transfer resistance of the dried layer and the vial heat transfer coefficient values of a pharmaceutical product during the primary drying period. First, overall vial heat transfer coefficient values, Kv, were determined by a gravimetric method based on pure ice sublimation experiments. Thus, it was possible to set up a map of the total heat flux received by each vial throughout the plate surface of our pilot scale freeze-dryer. Important heterogeneities were observed for the vials placed at the plate edges and for the vials placed at the center of the plate. As well, the same gravimetric method was also used to precisely determine the influence of main lyophilization operating parameters (shelf temperature and gas total pressure) or the vial types and sizes on these overall heat transfer coefficient values. A semi-empirical relationship as a function of total gas pressure was proposed. The transient method by pressure rise analysis (PRA method) after interrupting the water vapour flow between the sublimation chamber and the condenser, previously set up and validated in our laboratory, was then extensively used with an amorphous BSA-based formulation to identify the dried layer mass transfer resistance values, Rp, the ice front temperature, and the total heat transfer coefficient values, Kv, with or without annealing treatment. It was proved that this method gave accurate and coherent data only during the first half of the sublimation period when the totality of the vials of the set was still sublimating. Thus, this rapid method allowed estimation of, on line and in situ, the sublimation front temperature and the characterization of the morphology and structure of the freeze-dried layer, all along the first part of the sublimation period. The estimated sublimation temperatures shown by the PRA model were about 2 degrees C lower than the experimental values obtained using thermocouples inserted inside the vial, in accordance with previous data given by this method for similar freeze-drying conditions. As well, by using this method we could confirm the homogenization of the dried layer porous structure by annealing treatment after the freezing step. Furthermore, frozen matrix structure analysis (mean pore diameter) using optical microscopy and mass transfer modelling of water vapour by molecular diffusion (Knudsen regime) allowed, in some cases, to predict the experimental values of this overall mass transfer resistance directly related to the freeze-dried cake permeability.

  6. The flow field of an underexpanded H2 jet coaxially injected into a hot free or ducted supersonic jet of air or nitrogen

    NASA Technical Reports Server (NTRS)

    Jenkins, R. V.

    1977-01-01

    Experimental data obtained in an investigation of the mixing of an underexpanded hydrogen jet in a supersonic flow both with and without combustion are presented. Tests were conducted in a Mach 2 test stream with both air and nitrogen as test media. Total temperature of the test stream was 2170 K, and static exit pressure was about one atmosphere. The static pressure at the exit of the hydrogen injector's Mach 2 nozzle was about two atmospheres. Primary measurements included shadowgraphs and pitot pressure surveys of the flow field. Pitot surveys and wall static pressures were measured for the case where the entire flow was shrouded. The results are compared to similar experimental data and theoretical predictions for the matched pressure case.

  7. Mechanical behavior, electronic and phonon properties of ZrB12 under pressure

    NASA Astrophysics Data System (ADS)

    Li, Xiao-Hong; Yong, Yong-Liang; Cui, Hong-Ling; Zhang, Rui-Zhou

    2018-06-01

    The mechanical, phonon and electronic properties of ZrB12 under pressure are investigated by first-principles calculations. The research shows that ZrB12 is mechanically and dynamically stable up to 100 GPa. The elastic constants, bulk modulus B, shear modulus G, hardness Hv, B/G ratio, Debye temperature under different pressures are systematically investigated. The calculation of electronic properties shows that ZrB12 has metallic character. The Zr-d states dominate the DOS at the Fermi level, and the total DOS and PDOS change slightly with the increasing pressure. DOS (Ef) first decreases, then increases with the increasing pressure. At 50 GPa, ZrB12 has less electron carriers. The analysis of electron localization function shows that the strong B-B and Zr-B covalent bonds may be responsible for the high hardness and stability.

  8. Frictional Properties of the Nankai Trough Accretionary Mud Samples Collected from 1000-3000 mbsf at IODP Site C0002

    NASA Astrophysics Data System (ADS)

    Kanagawa, K.; Hoshino, K.; Abe, K.; Sawai, M.

    2016-12-01

    We conducted triaxial friction experiments on the Nankai Trough accretionary mud samples collected from 1000-3000 mbsf (meters below seafloor) at IODP Site C0002 off Kii Peninsula, at confining pressures of 44-83 MPa, pore water pressures of 32-50 MPa and temperatures of 51-98°C equivalent to their in situ conditions, and at axial displacement rates changed stepwise among 0.1, 1 and 10 µm/s, in order to investigate their frictional properties changing with depth. XRD analyses of tested mud samples revealed that the content of total clay minerals tends to increase with depth from 30 to 60 wt%, while the smectite fraction in total clay minerals decreases with depth from 0.75 to 0.3. Because the temperature at 3000 mbsf reaches 100°C, this decrease in smectite fraction with depth is likely due to the progress of smectite dehydration with increasing temperature. Friction experiments on tested mud samples revealed that the steady-state friction coefficient at an axial displacement rate of 1 µm/s tends to decrease with depth from 0.5 to 0.3, according to the increasing content of total clay minerals with depth. Velocity dependence of steady-state friction also tends to decrease with depth, likely reflecting a decrease in smectite fraction in total clay minerals. Although velocity dependence of steady-state friction is mostly positive at depths down to 3000 mbsf, it is locally neutral or negative at depths deeper than 2000 mbsf, implying that faulting at these depths is conditionally stable and possibly accompanied by slow slip events.

  9. Issues of intergranular embrittlement of VVER-type nuclear reactors pressure vessel materials

    NASA Astrophysics Data System (ADS)

    Zabusov, O.

    2016-04-01

    In light of worldwide tendency to extension of service life of operating nuclear power plants - VVER-type in the first place - recently a special attention is concentrated on phenomena taking place in reactor pressure vessel materials that are able to lead to increased level of mechanical characteristics degradation (resistibility to brittle fracture) during long term of operation. Formerly the hardening mechanism of degradation (increase in the yield strength under influence of irradiation) mainly had been taken into consideration to assess pressure vessel service life limitations, but when extending the service life up to 60 years and more the non-hardening mechanism (intergranular embrittlement of the steels) must be taken into account as well. In this connection NRC “Kurchatov Institute” has initiated a number of works on investigations of this mechanism contribution to the total embrittlement of reactor pressure vessel steels. The main results of these investigations are described in this article. Results of grain boundary phosphorus concentration measurements in specimens made of first generation of VVER-type pressure vessels materials as well as VVER-1000 surveillance specimens are presented. An assessment of non-hardening mechanism contribution to the total ductile-to- brittle transition temperature shift is given.

  10. Investigations on structural, elastic, thermodynamic and electronic properties of TiN, Ti2N and Ti3N2 under high pressure by first-principles

    NASA Astrophysics Data System (ADS)

    Yang, Ruike; Zhu, Chuanshuai; Wei, Qun; Du, Zheng

    2016-11-01

    The lattice parameters, cell volume, elastic constants, bulk modulus, shear modulus, Young's modulus and Poisson's ratio are calculated at zero pressure, and their values are in excellent agreement with the available data, for TiN, Ti2N and Ti3N2. By using the elastic stability criteria, it is shown that the three structures are all stable. The brittle/ductile behaviors are assessed in the pressures from 0 GPa to 50 GPa. Our calculations present that the performances for TiN, Ti2N and Ti3N2 become from brittle to ductile with pressure rise. The Debye temperature rises as pressure increase. With increasing N content, the enhancement of covalent interactions and decline of metallicity lead to the increase of the micro-hardness. Their constant volume heat capacities increase rapidly in the lower temperature, at a given pressure. At higher temperature, the heat capacities are close to the Dulong-Petit limit, and the heat capacities of TiN and Ti2N are larger than that of c-BN. The thermal expansion coefficients of titanium nitrides are slightly larger than that of c-BN. The band structure and the total Density of States (DOS) are calculated at 0 GPa and 50 GPa. The results show that TiN and Ti2N present metallic character. Ti3N2 present semiconducting character. The band structures have some discrepancies between 0 GPa and 50 GPa. The extent of energy dispersion increases slightly at 50 GPa, which means that the itinerant character of electrons becomes stronger at 50 GPa. The main bonding peaks of TiN, Ti2N and Ti3N2 locate in the range from -10 to 10 eV, which originate from the contribution of valance electron numbers of Ti s, Ti p, Ti d, N s and N p orbits. We can also find that the pressure makes that the total DOS decrease at the Fermi level for Ti2N. The bonding behavior of N-Ti compounds is a combination of covalent and ionic nature. As N content increases, valence band broadens, valence electron concentration increases, and covalent interactions become stronger. This is reflected in shortening of Ti-N bonds.

  11. Electrocatalytic Synthesis of Ammonia at Room Temperature and Atmospheric Pressure from Water and Nitrogen on a Carbon-Nanotube-Based Electrocatalyst.

    PubMed

    Chen, Shiming; Perathoner, Siglinda; Ampelli, Claudio; Mebrahtu, Chalachew; Su, Dangsheng; Centi, Gabriele

    2017-03-01

    Ammonia is synthesized directly from water and N 2 at room temperature and atmospheric pressure in a flow electrochemical cell operating in gas phase (half-cell for the NH 3 synthesis). Iron supported on carbon nanotubes (CNTs) was used as the electrocatalyst in this half-cell. A rate of ammonia formation of 2.2×10 -3  gNH3  m -2  h -1 was obtained at room temperature and atmospheric pressure in a flow of N 2 , with stable behavior for at least 60 h of reaction, under an applied potential of -2.0 V. This value is higher than the rate of ammonia formation obtained using noble metals (Ru/C) under comparable reaction conditions. Furthermore, hydrogen gas with a total Faraday efficiency as high as 95.1 % was obtained. Data also indicate that the active sites in NH 3 electrocatalytic synthesis may be associated to specific carbon sites formed at the interface between iron particles and CNT and able to activate N 2 , making it more reactive towards hydrogenation. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Scaling up of High-Pressure Sliding (HPS) for Grain Refinement and Superplasticity

    NASA Astrophysics Data System (ADS)

    Takizawa, Yoichi; Masuda, Takahiro; Fujimitsu, Kazushige; Kajita, Takahiro; Watanabe, Kyohei; Yumoto, Manabu; Otagiri, Yoshiharu; Horita, Zenji

    2016-09-01

    The process of high-pressure sliding (HPS) is a method of severe plastic deformation developed recently for grain refinement of metallic materials under high pressure. The sample for HPS is used with a form of sheet or rod. In this study, an HPS facility with capacities of 500 tonnes for vertical pressing and of 500 and 300 tonnes for horizontal forward and backward pressings, respectively, was newly built and applied for grain refinement of a Mg alloy as AZ61, Al alloys such as Al-Mg-Sc, A2024 and A7075 alloys, a Ti alloy as ASTM-F1295, and a Ni-based superalloy as Inconel 718. Sheet samples with dimensions of 10 to 30 mm width, 100 mm length, and 1 mm thickness were processed at room temperature and ultrafine grains with sizes of ~200 to 300 nm were successfully produced in the alloys. Tensile testing at elevated temperatures confirmed the advent of superplasticity with total elongations of more than 400 pct in all the alloys. It is demonstrated that the HPS can make all the alloys superplastic through processing at room temperature with a form of rectangular sheets.

  13. Thermodynamic Behavior in Decaying Compressible Turbulence with Initially Dominant Temperature Fluctuations

    NASA Astrophysics Data System (ADS)

    Cai, X. D.; O'Brien, Edward E.; Ladeinde, Foluso

    1996-11-01

    Direct numerical simulation of decaying, isotropic, compressible turbulence in three dimensions is used to examine the behavior of fluctuations in density, temperature, and pressure when the initial conditions include temperature fluctuations larger than pressure fluctuations. The numerical procedure is described elsewhere (Ladeinde, F. et al.,) Phys. Fluids 7(11), pp. 2848 (1995), the initial turbulence Mach number range is subsonic, 0.3 to 0.7, and, following Ghosh and Matthaeus(Ghosh, S. and Matthaeus, W. H. Phys. Fluids A, pp. 148 (1991)), the initial compressible turbulence is characterized as a: mostly solenoidal, b: random, or c: longitudinal. These cases represent, respectively, ratios of initial kinetic energy in the compressible modes to total initial kinetic energy, say \\chi_0, which are either a: very small, b: about 0.6, or c: near unity. Thermodynamic scalings at the lowest values of initial Mach number and \\chi0 follow the predictions of Zank and Matthaeus (Zank, G. P. and Matthaeus, W. H. Phys. Fluids A(3), pp. 69 (1991)), but not otherwise. The relationship between \\chi, Mach number, and compressible pressure predicted by Sarkar et al.(Sarkar, S. et al.,) J. Fluid Mech. 227, pp. 473 (1991) applies, on average, to all cases computed.

  14. Measurements of spectral parameters of water-vapour transitions near 1388 and 1345 nm for accurate simulation of high-pressure absorption spectra

    NASA Astrophysics Data System (ADS)

    Liu, Xiang; Jeffries, Jay B.; Hanson, Ronald K.

    2007-05-01

    Quantitative near-infrared absorption spectroscopy of water-vapour overtone and combination bands at high pressures is complicated by pressure broadening and shifting of individual lines and the blending of neighbouring transitions. An experimental and computational methodology is developed to determine accurate high-pressure absorption spectra. This case study investigates two water-vapour transitions, one near 1388 nm (7203.9 cm-1) and the other near 1345 nm (7435.6 cm-1), for potential two-line absorption measurements of temperature in the range of 400-1050 K with a pressure varying from 5-25 atm. The required quantitative spectroscopy data (line strength, collisional broadening, and pressure-induced frequency shift) of the target transitions and their neighbours (a total of four H2O vapour transitions near 1388 nm and six transitions near 1345 nm) are measured in neat H2O vapour, H2O-air and H2O-CO2 mixtures as a function of temperature (296-1000 K) at low pressures (<800 Torr). Precise values of the line strength S(T), pressure-broadening coefficients γair(T) and \\gamma _{CO_2 } (T), and pressure-shift coefficients δair(T) and \\delta _{CO_2 } (T) for the ten transitions were inferred from the measured spectra and compared with data from HITRAN 2004. A hybrid spectroscopic database was constructed by modifying HITRAN 2004 to incorporate these values for simulation of water-vapour-absorption spectra at high pressures. Simulations using this hybrid database are in good agreement with high pressure experiments and demonstrate that data collected at modest pressures can be used to simulate high-pressure absorption spectra.

  15. Low temperature photochemical vapor deposition of alloy and mixed metal oxide films

    DOEpatents

    Liu, David K.

    1992-01-01

    Method and apparatus for formation of an alloy thin film, or a mixed metal oxide thin film, on a substrate at relatively low temperatures. Precursor vapor(s) containing the desired thin film constituents is positioned adjacent to the substrate and irradiated by light having wavelengths in a selected wavelength range, to dissociate the gas(es) and provide atoms or molecules containing only the desired constituents. These gases then deposit at relatively low temperatures as a thin film on the substrate. The precursor vapor(s) is formed by vaporization of one or more precursor materials, where the vaporization temperature(s) is selected to control the ratio of concentration of metals present in the precursor vapor(s) and/or the total precursor vapor pressure.

  16. Direct thermal water splitting by concentrated solar radiation for hydrogen production. Phase O: Proof of concept experiment

    NASA Technical Reports Server (NTRS)

    Genequand, P.

    1980-01-01

    The direct production of hydrogen from water and solar energy concentrated into a high temperature aperture is described. A solar powered reactor able to dissociate water vapor and to separate the reaction product at high temperature was developed, and direct water splitting has been achieved in a laboratory reactor. Water vapor and radiative heating from a carbon dioxide laser are fed into the reactor, and water vapor enriched in hydrogen and water vapor enriched in oxygen are produced. The enriched water vapors are separated through a separation membrane, a small disc of zirconium dioxide heated to a range of 1800 k to 2800 k. To avoid water vapor condensation within the reactor, the total pressure within the reactor was limited to 0.15 torr. A few modifications would enable the reactor to be operated at an increased pressure of a few torrs. More substantial modifications would allow for a reaction pressure of 0.1 atmosphere.

  17. Space shuttle main engine: Interactive design challenges

    NASA Technical Reports Server (NTRS)

    Mccarty, J. P.; Wood, B. K.

    1985-01-01

    The operating requirements established by NASA for the SSME were considerably more demanding than those for earlier rocket engines used in the military launch vehicles or Apollo program. The SSME, in order to achieve the high performance, low weight, long life, reusable objectives, embodied technical demands far in excess of its predecessor rocket engines. The requirements dictated the use of high combustion pressure and the staged combustion cycle which maximizes performance through total use of all propellants in the main combustion process. This approach presented a myriad of technical challenges for maximization of performance within attainable state of the art capabilities for operating pressures, operating temperatures and rotating machinery efficiencies. Controlling uniformity of the high pressure turbomachinery turbine temperature environment was a key challenge for thrust level and life capability demanding innovative engineering. New approaches in the design of the components were necessary to accommodate the multiple use, minimum maintenance objectives. Included were the use of line replaceable units to facilitate field maintenance automatic checkout and internal inspection capabilities.

  18. Mass Flux of ZnSe by Physical Vapor Transport

    NASA Technical Reports Server (NTRS)

    Sha, Yi-Gao; Su, Ching-Hua; Palosz, W.; Volz, M. P.; Gillies, D. C.; Szofran, F. R.; Lehoczky, S. L.; Liu, Hao-Chieh; Brebrick, R. F.

    1995-01-01

    Mass fluxes of ZnSe by physical vapor transport (PVT) were measured in the temperature range of 1050 to 1160 C using an in-situ dynamic technique. The starting materials were either baked out or distilled under vacuum to obtain near-congruently subliming compositions. Using an optical absorption technique Zn and Se, were found to be the dominant vapor species. Partial pressures of Zn and Se, over the starting materials at temperatures between 960 and 1140 C were obtained by measuring the optical densities of the vapor phase at the wavelengths of 2138, 3405, 3508, 3613, and 3792 A. The amount and composition of the residual gas inside the experimental ampoules were measured after the run using a total pressure gauge. For the first time, the experimentally determined partial pressures of Zn and Se, and the amount and composition of the residual gas were used in a one-dimensional diffusion limited analysis of the mass transport rates for a PVT system. Reasonable agreement between the experimental and theoretical results was observed.

  19. Effect of Oxygen addition on altitude blowout and relight of an experimental combustor segment

    NASA Technical Reports Server (NTRS)

    Norgren, C. T.; Ingebo, R. D.

    1974-01-01

    The effect of oxygen addition on the low pressure altitude blowout limits of an experimental combustor segment was investigated. Data were obtained for two inlet-air temperatures, two inlet-airflow rates, and a constant fuel-air ratio of 0.020 with Jet A fuel. It was shown that the pressure at blowout could be reduced to correspond to an increase in altitude of 4.6 kilometers with oxygen flow rates of 8 to 16 percent by weight of the total fuel flow.

  20. CO.sub.2 Pretreatment prevents calcium carbonate formation

    DOEpatents

    Neavel, Richard C.; Brunson, Roy J.; Chaback, Joseph J.

    1980-01-01

    Scale formation during the liquefaction of lower ranking coals and similar carbonaceous materials is significantly reduced and/or prevented by pretreatment with carbon dioxide. The carbon dioxide pretreatment is believed to convert the scale-forming components to the corresponding carbonate prior to liquefaction. The pretreatment is accomplished at a total pressure within the range from about 14 to about 68 atmospheres and a carbon dioxide partial pressure within the range from about 14 to about 34 atmospheres. Temperature during pretreatment will generally be within the range from about 100.degree. to about 200.degree. C.

  1. Fundamental Studies of Subsonic and Transonic Flow Separation. Part I. First Phase Summary Report

    DTIC Science & Technology

    1975-09-01

    Axial Mach Number Distributions for M> 1.•..•.•. 119 A-8 Total Pressure Profile at X = 66.25 Inch Station. 120 A-9 Surface Temperature Distribution... designed wind tunnel wall as the testing model for achieving high Reynolds number flows. The other is to em- ploy a sufficiently long model such that a...external pressure field can be studied in detail. 3.1 UTSI TRANSONIC TUNNEL In general, most wind tunnels have been designed to have a ’uniform flow in

  2. Proceedings of the Navy Symposium on Aeroballistics (10th) Held at the Sheraton Motor Inn Fredericksburg, Virginia on 15-16-17 July 1975. Volume 3

    DTIC Science & Technology

    1975-07-17

    CDPHR OUPU DATAATRI - - - - - - - - -- - - - - - - - - - - - - - - - - - - U(2 ;8’ RN~ RNa ) IM,30 (hi M,,,7 Figur 6. De2,g Da,24 Sytess... circular arc throat section and a 150 conical divergent section. The throat radius is 0.746 in., and the stagnation pressure and temperature were 300 psia...an automatically KI movable total pressure probe which surveyed a circular area at the desig- nated inlet location, a stationary 15 deg half-angle

  3. Fundamental Ice Crystal Accretion Physics Studies

    NASA Technical Reports Server (NTRS)

    Struk, Peter M.; Broeren, Andy P.; Tsao, Jen-Ching; Vargas, Mario; Wright, William B.; Currie, Tom; Knezevici, Danny; Fuleki, Dan

    2012-01-01

    Due to numerous engine power-loss events associated with high-altitude convective weather, ice accretion within an engine due to ice crystal ingestion is being investigated. The National Aeronautics and Space Administration (NASA) and the National Research Council (NRC) of Canada are starting to examine the physical mechanisms of ice accretion on surfaces exposed to ice-crystal and mixed-phase conditions. In November 2010, two weeks of testing occurred at the NRC Research Altitude Facility utilizing a single wedge-type airfoil designed to facilitate fundamental studies while retaining critical features of a compressor stator blade or guide vane. The airfoil was placed in the NRC cascade wind tunnel for both aerodynamic and icing tests. Aerodynamic testing showed excellent agreement compared with CFD data on the icing pressure surface and allowed calculation of heat transfer coefficients at various airfoil locations. Icing tests were performed at Mach numbers of 0.2 to 0.3, total pressures from 93 to 45 kPa, and total temperatures from 5 to 15 C. Ice and liquid water contents ranged up to 20 and 3 g/m3, respectively. The ice appeared well adhered to the surface in the lowest pressure tests (45 kPa) and, in a particular case, showed continuous leading-edge ice growth to a thickness greater than 15 mm in 3 min. Such widespread deposits were not observed in the highest pressure tests, where the accretions were limited to a small area around the leading edge. The suction surface was typically ice-free in the tests at high pressure, but not at low pressure. The icing behavior at high and low pressure appeared to be correlated with the wet-bulb temperature, which was estimated to be above 0 C in tests at 93 kPa and below 0 C in tests at lower pressure, the latter enhanced by more evaporative cooling of water. The authors believe that the large ice accretions observed in the low pressure tests would undoubtedly cause the aerodynamic performance of a compressor component such as a stator blade to degrade significantly, and could damage downstream components if shed.

  4. Fundamental Ice Crystal Accretion Physics Studies

    NASA Technical Reports Server (NTRS)

    Currie, Tom; Knezevici, Danny; Fuleki, Dan; Struk, Peter M.; Broeren, Andy P.; Tsao, Jen-ching; Vargas, Mario; Wright, William

    2011-01-01

    Due to numerous engine power-loss events associated with high-altitude convective weather, ice accretion within an engine due to ice-crystal ingestion is being investigated. The National Aeronautics and Space Administration (NASA) and the National Research Council (NRC) of Canada are starting to examine the physical mechanisms of ice accretion on surfaces exposed to ice-crystal and mixed-phase conditions. In November 2010, two weeks of testing occurred at the NRC Research Altitude Facility utilizing a single wedge-type airfoil designed to facilitate fundamental studies while retaining critical features of a compressor stator blade or guide vane. The airfoil was placed in the NRC cascade wind tunnel for both aerodynamic and icing tests. Aerodynamic testing showed excellent agreement compared with CFD data on the icing pressure surface and allowed calculation of heat transfer coefficients at various airfoil locations. Icing tests were performed at Mach numbers of 0.2 to 0.3, total pressures from 93 to 45 kPa, and total temperatures from 5 to 15 C. Ice and liquid water contents ranged up to 20 and 3 grams per cubic meter, respectively. The ice appeared well adhered to the surface in the lowest pressure tests (45 kPa) and, in a particular case, showed continuous leading-edge ice growth to a thickness greater than 15 millimeters in 3 minutes. Such widespread deposits were not observed in the highest pressure tests, where the accretions were limited to a small area around the leading edge. The suction surface was typically ice-free in the tests at high pressure, but not at low pressure. The icing behavior at high and low pressure appeared to be correlated with the wet-bulb temperature, which was estimated to be above 0 C in tests at 93 kPa and below 0 C in tests at lower pressure, the latter enhanced by more evaporative cooling of water. The authors believe that the large ice accretions observed in the low pressure tests would undoubtedly cause the aerodynamic performance of a compressor component such as a stator blade to degrade significantly, and could damage downstream components if shed.

  5. Development of a low pressure microwave excited plasma and its application to the formation of microcrystalline silicon films

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kikukawa, Daisuke; Hori, Masaru; Honma, Koichiro

    2006-11-15

    Microwave excited plasma source operating at a low pressure of 1.5 Pa was newly developed. This plasma source was successfully applied to the formation of hydrogenated microcrystalline silicon films in a glass substrate with a mixture gas of silane (SiH{sub 4}), hydrogen (H{sub 2}), and xenon (Xe). It was found that the crystallinity of films was dramatically improved with decreasing pressure. The crystalline fraction was evaluated to be 82% at a substrate temperature of 400 deg. C, a mixture gas of SiH{sub 4}/H{sub 2}/Xe: 5/200/30 SCCM, and a total pressure of 1.5 Pa by Raman spectroscopy. The absolute density ofmore » hydrogen atoms and the behavior of higher radicals and molecules in the mixture gas were evaluated using vacuum ultraviolet absorption spectroscopy and quadrupole mass spectrometer, respectively. H atom densities were of the order of 10{sup 11} cm{sup -3}. The fraction of H atom density increased, while higher radicals and molecules decreased with decrease in the total pressure. The increase in H atom density and decrease in higher radicals and molecules improved the crystallinity of films in low pressures below 10 Pa.« less

  6. Anesthetic complications in dogs undergoing hepatic surgery: cholecystectomy versus non-cholecystectomy.

    PubMed

    Burns, Brigid R; Hofmeister, Erik H; Brainard, Benjamin M

    2014-03-01

    To determine if dogs that undergo laparotomy for cholecystectomy suffer from a greater number or magnitude of perianesthetic complications, including hypotension, hypothermia, longer recovery time, and lower survival rate, than dogs that undergo laparotomy for hepatic surgery without cholecystectomy. Retrospective cohort study. One hundred and three dogs, anesthetised between January 2007 and October 2011. The variables collected from the medical record included age, weight, gender, surgical procedure, pre-operative bloodwork, American Society of Anesthesiologists (ASA) status, emergency status, total bilirubin concentration, anesthetic agents administered, body temperature nadir, final body temperature, hypotension, duration of hypotension, blood pressure nadir, intraoperative drugs, anesthesia duration, surgery duration, time to extubation, final diagnosis, days spent in the intensive care unit (ICU), total bill, survival to discharge, and survival to follow-up. No significant difference in body temperature nadir, final temperature, presence of hypotension, duration of hypotension, blood pressure nadir, the use of inotropes, or final outcome was found between dogs undergoing cholecystectomy and dogs undergoing exploratory laparotomy for other hepatic disease. Dogs that had cholecystectomy had longer anesthesia durations and longer surgery durations than dogs that did not have cholecystectomy. No significant differences existed for temperature nadir (34.8 versus 35.3°C; non-cholecystectomy versus cholecystectomy), final temperature (35.6 versus 35.9°C), time to extubation (30 versus 49 minutes), duration of hypotension (27 versus 21 minutes), or MAP nadir (56 versus 55 mmHg). Hypotension occurred in 66% and 74% and inotropes were used in 64% and 53%, for non-cholecystectomy and cholecystectomy patients, respectively. Dogs that underwent cholecystectomies did not suffer a greater number of anesthesia complications than did dogs undergoing hepatic surgery without cholecystectomies. © 2013 Association of Veterinary Anaesthetists and the American College of Veterinary Anesthesia and Analgesia.

  7. Temperature and pressure dependent thermodynamic behavior of 2H-CuInO2

    NASA Astrophysics Data System (ADS)

    Bhamu, K. C.

    2018-05-01

    Density functional theory and quasi-harmonic Debye model has been used to study the thermodynamic properties of 2H-CuInO2. At the optimized structural parameters, pressure (0 to 80 GPa) dependent variation in the various thermodynamic properties, i.e. unit cell volume (V), bulk modulus (B), specific heat (Cv), Debye temperature (θD), Grüneisen parameter (γ) and thermal expansion coefficient (α) are calculated for various temperature values. The results predict that the pressure has significant effect on unit cell volume and bulk modulus while the temperature shows negligible effect on both parameters. With increasing temperature thermal expansion coefficient increase while with increasing pressure it decreases. The specific heat remains close to zero for ambient pressure and temperature values and it increases with increasing temperature. It is observed that the pressure has high impact on Debye temperature and Grüneisen parameter instead of temperature. Debye temperature and Grüneisen parameter both remains almost constant for the temperature range (0-300K) while Grüneisen parameter decrease with increasing pressure at constant temperature and Debye temperature increases rapidly with increasing pressure. An increase in Debye temperature with respect to pressure shows that the thermal vibration frequency changes rapidly.

  8. Study of pressure variation effect on structural, opto-electronic, elastic, mechanical, and thermodynamic properties of SrLiF3

    NASA Astrophysics Data System (ADS)

    Erum, Nazia; Iqbal, Muhammad Azhar

    2017-11-01

    The structural, electronic, elastic, optical and thermodynamic properties of cubic fluoroperovskite SrLiF3 at ambient and high-pressure are investigated by using first-principles total energy calculations within the framework of Generalized Gradient Approximation (GGA), combined with Quasi-harmonic Debye model in which the phonon effects are considered. The pressure effects are determined in the range of 0-50 GPa, in which cubic stability of SrLiF3 fluoroperovskite remains valid. The computed lattice parameters agree well with experimental and previous theoretical results. Decrease in lattice constant and bonds length is observed with the increase in pressure from 0 to 50 GPa. The effect of increase in pressure on electronic band structure calculations with GGA and GGA plus Tran-Blaha modified Becke-Johnson (TB-mBJ) potential reveals a predominant characteristic associated with widening of bandgap. The influence of pressure on elastic constants and their related mechanical parameters have been discussed in detail. All the calculated optical properties such as the complex dielectric function Ԑ(ω), optical conductivity σ(ω), energy loss function L(ω), absorption coefficient α(w), refractive index n (ω), reflectivity R (ω), and effective number of electrons neff, via sum rules shift towards the higher energies under the application of pressure. Moreover, important thermodynamic properties heat capacities (Cp and Cv), volume expansion coefficient (α), and Debye temperature (θD) are predicted successfully in the wide temperature and pressure ranges.

  9. Air Circulation and Heat Exchange under Reduced Pressures

    NASA Astrophysics Data System (ADS)

    Rygalov, Vadim; Wheeler, Raymond; Dixon, Mike; Hillhouse, Len; Fowler, Philip

    Low pressure atmospheres were suggested for Space Greenhouses (SG) design to minimize sys-tem construction and re-supply materials, as well as system manufacturing and deployment costs. But rarified atmospheres modify heat exchange mechanisms what finally leads to alter-ations in thermal control for low pressure closed environments. Under low atmospheric pressures (e.g., lower than 25 kPa compare to 101.3 kPa for normal Earth atmosphere), convection is becoming replaced by diffusion and rate of heat exchange reduces significantly. During a period from 2001 to 2009, a series of hypobaric experiments were conducted at Space Life Sciences Lab (SLSLab) NASA's Kennedy Space Center and the Department of Space Studies, University of North Dakota. Findings from these experiments showed: -air circulation rate decreases non-linearly with lowering of total atmospheric pressure; -heat exchange slows down with pressure decrease creating risk of thermal stress (elevated leaf tem-peratures) for plants in closed environments; -low pressure-induced thermal stress could be reduced by either lowering system temperature set point or increasing forced convection rates (circulation fan power) within certain limits; Air circulation is an important constituent of controlled environments and plays crucial role in material and heat exchange. Theoretical schematics and mathematical models are developed from a series of observations. These models can be used to establish optimal control algorithms for low pressure environments, such as a space greenhouse, as well as assist in fundamental design concept developments for these or similar habitable structures.

  10. Influence of gaseous hydrogen on the mechanical properties of high temperature alloys

    NASA Technical Reports Server (NTRS)

    1976-01-01

    Tensile tests of six nickel-base and one cobalt-base alloy were conducted in 34.5 MN/sq m helium and hydrogen environments at temperatures from 297 K to 1,088 K. Mechanical properties tests of the nickel-base alloy MAR M-246 (Hf modified), in two cast conditions, were conducted in gaseous environments at temperatures from 297 K to 1,144 K and pressures from one atmosphere to 34.5 MN/sq m. The objective of this program was to obtain the mechanical properties of the various alloys proposed for use in space propulsion systems in a pure hydrogen environment at different temperatures and to compare with the mechanical properties in helium at the same conditions. All testing was conducted on solid specimens exposed to external gaseous pressure. Smooth and notched tensile properties were determined using ASTM tensile testing techniques, and creep-rupture life was determined using ASTM creep-rupture techniques. Low-cycle fatigue life was established by constant total strain and constant stress testing using smooth specimens and a closed-loop test machine.

  11. Extension of thermophysical and thermodynamic property measurements by laser pulse heating up to 10,000 K. I. Under pressure

    NASA Astrophysics Data System (ADS)

    Ohse, R. W.

    1990-07-01

    The necessity for increased high-temperature data reliability and extension of thermophysical property measurements up to 5000 K and above are discussed. A new transient-type laser-autoclave technique (LAT) has been developed to extend density and heat capacity measurements of high-temperature multicomponent systems far beyond their melting and boiling points. Pulsed multibeam laser heating is performed in an autoclave under high inert gas pressure to eliminate evaporation. The spherical samples are positioned by containment-free acoustic levitation regardless of their conductive or magnetic properties. Temperature, spectral and total emittances are determined by a new microsecond six-wavelength pyrometer coupled to a fast digital data acquisition system. The density is determined by high resolution microfocus X-ray shadow technique. The heat capacity is obtained from the cooling rate. Further applications are a combination of the laser-autoclave with splat cooling techniques for metastable structure synthesis and amorphous metals research and an extension of the LAT for the study of critical phenomena and the measurement of critical-point temperatures.

  12. Development of a Pressure Sensitive Paint System with Correction for Temperature Variation

    NASA Technical Reports Server (NTRS)

    Simmons, Kantis A.

    1995-01-01

    Pressure Sensitive Paint (PSP) is known to provide a global image of pressure over a model surface. However, improvements in its accuracy and reliability are needed. Several factors contribute to the inaccuracy of PSP. One major factor is that luminescence is temperature dependent. To correct the luminescence of the pressure sensing component for changes in temperature, a temperature sensitive luminophore incorporated in the paint allows the user to measure both pressure and temperature simultaneously on the surface of a model. Magnesium Octaethylporphine (MgOEP) was used as a temperature sensing luminophore, with the pressure sensing luminophore, Platinum Octaethylporphine (PtOEP), to correct for temperature variations in model surface pressure measurements.

  13. Simultaneous Luminescence Pressure and Temperature Mapping

    NASA Technical Reports Server (NTRS)

    Buck, Gregory M. (Inventor)

    1998-01-01

    A simultaneous luminescence pressure and temperature mapping system is developed including improved dye application techniques for surface temperature and pressure measurements from 5 torr to 1000 torr with possible upgrade to from 0.5 torr to several atmospheres with improved camera resolution. Adsorbed perylene dye on slip-cast silica is pressure (oxygen) sensitive and reusable to relatively high temperatures (-150 C). Adsorbed luminescence has an approximately linear color shift with temperature, which can be used for independent temperature mapping and brightness pressure calibration with temperature.

  14. Simultaneous Luminescence Pressure and Temperature Mapping System

    NASA Technical Reports Server (NTRS)

    Buck, Gregory M. (Inventor)

    1995-01-01

    A simultaneous luminescence pressure and temperature mapping system is developed including improved dye application techniques for surface temperature and pressure measurements from 5 torr to 1000 torr with possible upgrade to from 0.5 torr to several atmospheres with improved camera resolution. Adsorbed perylene dye on slip-cast silica is pressure (oxygen) sensitive and reusable to relatively high temperatures (approximately 150 C). Adsorbed luminescence has an approximately linear color shift with temperature, which can be used for independent temperature mapping and brightness pressure calibration with temperature.

  15. Combustion Noise at Elevated Pressures in a Liquid-Fueled Premixed Combustor

    NASA Technical Reports Server (NTRS)

    Darling, Douglas; Radhakrishnan, Krishnan; Oyediran, Ayo

    1997-01-01

    Noise generated in gas turbine combustors can exist in several forms-broadband noise, sharp resonant peaks, and regular or intermittent nonlinear pulsing. In the present study, dynamic pressure measurements were made in several JP-5-fueled combustor configurations, at various mean pressures and temperatures. The fluctuating pressure was measured at mean pressures from 6 to 14 atm and inlet temperatures from 550 K to 850 K. The goal of the present work was to study the effect of changes in mean flow conditions on combustor noise: both broadband noise and sharp tones were considered. In general, the shape of the broadband noise spectrum was consistent from one configuration to another. The shape of the spectrum was influenced by the acoustic filtering of the combustion zone. This filtering ensured the basic consistency of the spectra. In general, the trends in broadband noise observed at low mean pressures were also seen at high mean pressures; that is, the total sound level decreased with both increasing equivalence ratio and increasing inlet temperature. The combustor configurations without a central pilot experienced higher broadband noise levels and were more susceptible to narrow peak resonances than configurations with a central pilot. The sharp peaks were more sensitive to the mean flow than was the broadband noise, and the effects were not always the same. In some situations, increasing the equivalence ratio made the sharp peaks grow, while at other conditions, increasing the equivalence ratio made the sharp peaks shrink. Thus, it was difficult to predict when resonances would occur; however, they were reproducible. Acoustic coupling between the upstream and downstream regions of the combustor may play a role in the sharp-peaked oscillations. Noise was also observed near lean blow out. As with other types of noise, lean blow out noise was affected by the combustion chamber acoustics, which apparently maintains the fluctuations at a uniform frequency. However, the actual conditions when this type of noise was experienced appeared to simply follow the lean blow out limit as it varied with mean temperature and pressure.

  16. Empirically assessing the potential release of rare earth elements from black shale under simulated hydraulic fracturing conditions

    DOE PAGES

    Yang, Jon; Verba, Circe; Torres, Marta; ...

    2018-02-01

    Rare earth elements (REEs) are economically important to modern society and the rapid growth of technologies dependent on REEs has placed considerable economic pressure on their sourcing. This study addresses whether REEs could be released as a byproduct of natural gas extraction from a series of experiments that were designed to simulate hydraulic fracturing of black shale under various pressure (25 and 27.5 MPa) and temperature (50, 90, 130 °C) conditions. The dissolved REEs in the reacted fluids displayed no propensity for the REEs to be released from black shale under high pressure and temperature conditions, a result that ismore » consistent across the different types of fluids investigated. Overall, there was a net loss of REEs from the fluid. These changes in dissolved REEs were greatest at the moment the fluids first contacted the shale and before the high temperature and high pressure conditions were imposed, although the magnitude of these changes (10 -4 μg/g) were small compared to the magnitude of the total REE content present in the solid shale samples (10 2 μg/g). These results highlight the variability and complexity of hydraulic fracturing systems and indicate that REE may not serve as robust tracers for fracturing fluid-shale reactions. Additionally, the results suggest that significant quantities of REEs may not be byproducts of hydraulically fractured shales.« less

  17. Empirically assessing the potential release of rare earth elements from black shale under simulated hydraulic fracturing conditions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yang, Jon; Verba, Circe; Torres, Marta

    Rare earth elements (REEs) are economically important to modern society and the rapid growth of technologies dependent on REEs has placed considerable economic pressure on their sourcing. This study addresses whether REEs could be released as a byproduct of natural gas extraction from a series of experiments that were designed to simulate hydraulic fracturing of black shale under various pressure (25 and 27.5 MPa) and temperature (50, 90, 130 °C) conditions. The dissolved REEs in the reacted fluids displayed no propensity for the REEs to be released from black shale under high pressure and temperature conditions, a result that ismore » consistent across the different types of fluids investigated. Overall, there was a net loss of REEs from the fluid. These changes in dissolved REEs were greatest at the moment the fluids first contacted the shale and before the high temperature and high pressure conditions were imposed, although the magnitude of these changes (10 -4 μg/g) were small compared to the magnitude of the total REE content present in the solid shale samples (10 2 μg/g). These results highlight the variability and complexity of hydraulic fracturing systems and indicate that REE may not serve as robust tracers for fracturing fluid-shale reactions. Additionally, the results suggest that significant quantities of REEs may not be byproducts of hydraulically fractured shales.« less

  18. Carotenoids concentration of Gac (Momordica cochinchinensis Spreng.) fruit oil using cross-flow filtration technology.

    PubMed

    Mai, Huỳnh Cang; Truong, Vinh; Debaste, Frédéric

    2014-11-01

    Gac (Momordica cochinchinensis Spreng.) fruit, a traditional fruit in Vietnam and other countries of eastern Asia, contains an oil rich in carotenoids, especially lycopene and β-carotene. Carotenoids in gac fruit oil were concentrated using cross-flow filtration. In total recycle mode, effect of membrane pore size, temperature, and transmembrane pressure (TMP) on permeate flux and on retention coefficients has been exploited. Resistance of membrane, polarization concentration, and fouling were also analyzed. Optimum conditions for a high permeate flux and a good carotenoids retention are 5 nm, 2 bars, and 40 °C of membrane pore size, TMP, and temperature, respectively. In batch mode, retentate was analyzed through index of acid, phospholipids, total carotenoids content (TCC), total antioxidant activity, total soluble solids, total solid content, color measurement, and viscosity. TCC in retentate is higher 8.6 times than that in feeding oil. Lipophilic antioxidant activities increase 6.8 times, while hydrophilic antioxidant activities reduce 40%. The major part of total resistance is due to polarization (55%) while fouling and intrinsic membrane contribute about 30% and 24%, respectively. © 2014 Institute of Food Technologists®

  19. Development of fused slurry silicide coatings for tantalum reentry heat shields

    NASA Technical Reports Server (NTRS)

    Warnock, R. V.; Stetson, A. R.

    1972-01-01

    A fused slurry silicide coating was developed to provide atmospheric reentry protection for the 90Ta-lOW alloy. Overlaying the silicide with a highly refractory glass greatly improved total lifetime and reliability of the coating system. Low pressure, slow cycle lifetimes in excess of 100 cycles were consistently recorded for 1700 K - 13 and 1300 N/sq m test conditions. A minimum of 25 cycles was obtained for 1810 K - 1300 N/sq m conditions. About 50 simulated reentry cycles (variable temperature, pressure, and stress) were endured by coated 1-inch miniature heat shield panels when exposed to a maximum of 1700 K and either internal or external pressure conditions.

  20. Hot spaghetti: Viscous gravitational collapse

    NASA Astrophysics Data System (ADS)

    Müller, Berndt; Schäfer, Andreas

    2018-02-01

    We explore the fate of matter falling into a macroscopic Schwarzschild black hole for the simplified case of a radially collapsing thin spherical shell for which the back reaction of the geometry can be neglected. We treat the internal dynamics of the in-falling matter in the framework of viscous relativistic hydrodynamics and calculate how the internal temperature of the collapsing matter evolves as it falls toward the Schwarzschild singularity. We find that viscous hydrodynamics fails when either the dissipative radial pressure exceeds the thermal pressure and the total radial pressure becomes negative, or the time scale of variation of the tidal forces acting on the collapsing matter becomes shorter than the characteristic hydrodynamic response time.

  1. Effect of design over-all compressor pressure ratio division on acceleration characteristics of three hypothetical two-spool turbojet engines

    NASA Technical Reports Server (NTRS)

    Filippi, Richard E; Dugan, James F , Jr

    1956-01-01

    The engines, each with a compressor overall total-pressure ratio of 12 and a design inner-turbine-inlet temperature of 2500 degrees R, were investigated at static sea-level conditions to determine the effect on transient performance of varying the desitn pressure ratio divisions 2-6, 3-4, and 4-3 between the outer and inner compressors. The transient considered was an acceleration from 40 to 100 percent design thrust. When the outer compressor of each engine reached design speed, the inner compressors were overspeeding, the maximum being only 1.7 over design mechanical speed. Acceleration times for the three engines were equal.

  2. Partitioning of water between surface and mantle on terrestrial exoplanets: effect of surface-mantle water exchange parameterizations on ocean depth

    NASA Astrophysics Data System (ADS)

    Komacek, T. D.; Abbot, D. S.

    2016-12-01

    Terrestrial exoplanets in the canonical habitable zone may have a variety of initial water fractions due to their volatile delivery rate via planetesimals. If the total planetary water complement is high, the entire surface may be covered in water, forming a "waterworld". The habitable zone for waterworlds is likely smaller than that for planets with partial land coverage because waterworlds lack the stabilizing silicate-weathering feedback. On a planet with active tectonics, competing mechanisms act to regulate the abundance of water on the surface by determining the partitioning of water between interior and surface. We have explored how the incorporation of different mechanisms for the outgassing and regassing of water changes the volatile evolution of a planet. Specifically, we have examined three models for volatile cycling: a model with degassing and regassing both determined by the seafloor pressure, one with mantle temperature-dependent degassing and regassing rates, and a hybrid model that has the degassing rate driven by seafloor pressure and the regassing rate determined by the mantle temperature. We find that the volatile cycling in all three of these scenarios reaches a steady-state after a few billion years. Using these steady-states, we can make predictions from each model for how much water is needed to flood the surface and make a waterworld. We find that if volatile cycling is either solely temperature-dependent or pressure-dependent, exoplanets require a high abundance (more than 0.3% by mass) of water to have fully inundated surfaces. This is because the waterworld boundary for these models is regulated by how much water can be stuffed into the mantle. However, if degassing is more dependent on the seafloor pressure and regassing mainly dependent on mantle temperature, super-Earth mass planets with a total water fraction similar to that of the Earth (approximately 0.05% by mass) can become waterworlds. As a result, further understanding of the processes that drive volatile cycling on terrestrial planets is needed to determine the water fraction at which they are likely to become waterworlds.

  3. Pressure, temperature and density drops along supercritical fluid chromatography columns. I. Experimental results for neat carbon dioxide and columns packed with 3- and 5-micron particles.

    PubMed

    Poe, Donald P; Veit, Devon; Ranger, Megan; Kaczmarski, Krzysztof; Tarafder, Abhijit; Guiochon, Georges

    2012-08-10

    The pressure drop and temperature drop on columns packed with 3- and 5-micron particles were measured using neat CO(2) at a flow rate of 5 mL/min, at temperatures from 20°C to 100°C, and outlet pressures from 80 to 300 bar. The density drop was calculated based on the temperature and pressure at the column inlet and outlet. The columns were suspended in a circulating air bath either bare or covered with foam insulation. The results show that the pressure drop depends on the outlet pressure, the operating temperature, and the thermal environment. A temperature drop was observed for all conditions studied. The temperature drop was relatively small (less than 3°C) for combinations of low temperature and high pressure. Larger temperature drops and density drops occurred at higher temperatures and low to moderate pressures. Covering the column with thermal insulation resulted in larger temperature drops and corresponding smaller density drops. At 20°C the temperature drop was never more than a few degrees. The largest temperature drops occurred for both columns when insulated at 80°C and 80 bar, reaching a maximum value of 21°C for the 5-micron column, and 26°C for the 3-micron column. For an adiabatic column, the temperature drop depends on the pressure drop, the thermal expansion coefficient, and the density and the heat capacity of the mobile phase fluid, and can be described by a simple mathematical relationship. For a fixed operating temperature and outlet pressure, the temperature drop increases monotonically with the pressure drop. Copyright © 2012 Elsevier B.V. All rights reserved.

  4. Inactivation of Staphylococcus aureus and Salmonella enteritidis in tryptic soy broth and caviar samples by high pressure processing.

    PubMed

    Fioretto, F; Cruz, C; Largeteau, A; Sarli, T A; Demazeau, G; El Moueffak, A

    2005-08-01

    We studied the action of high pressure processing on the inactivation of two foodborne pathogens, Staphylococcus aureus ATCC 6538 and Salmonella enteritidis ATCC 13076, suspended in a culture medium and inoculated into caviar samples. The baroresistance of the two pathogens in a tryptic soy broth suspension at a concentration of 10(8)-10(9) colony-forming units/ml was tested for continuous and cycled pressurization in the 150- to 550-MPa range and for 15-min treatments at room temperature. The increase of cycle number permitted the reduction of the pressure level able to totally inactivate both microorganisms in the tryptic soy broth suspension, whereas the effect of different procedure times on complete inactivation of the microorganisms inoculated into caviar was similar.

  5. Effect of coolant flow ejection on aerodynamic performance of low-aspect-ratio vanes. 2: Performance with coolant flow ejection at temperature ratios up to 2

    NASA Technical Reports Server (NTRS)

    Hass, J. E.; Kofskey, M. G.

    1977-01-01

    The aerodynamic performance of a 0.5 aspect ratio turbine vane configuration with coolant flow ejection was experimentally determined in a full annular cascade. The vanes were tested at a nominal mean section ideal critical velocity ratio of 0.890 over a range of primary to coolant total temperature ratio from 1.0 to 2.08 and a range of coolant to primary total pressure ratio from 1.0 to 1.4 which corresponded to coolant flows from 3.0 to 10.7 percent of the primary flow. The variations in primary and thermodynamic efficiency and exit flow conditions with circumferential and radial position were obtained.

  6. User manual for NASA Lewis 10 by 10 foot supersonic wind tunnel. Revised

    NASA Technical Reports Server (NTRS)

    Soeder, Ronald H.

    1995-01-01

    This manual describes the 10- by 10-Foot Supersonic Wind Tunnel at the NASA Lewis Research Center and provides information for users who wish to conduct experiments in this facility. Tunnel performance operating envelopes of altitude, dynamic pressure, Reynolds number, total pressure, and total temperature as a function of test section Mach number are presented. Operating envelopes are shown for both the aerodynamic (closed) cycle and the propulsion (open) cycle. The tunnel test section Mach number range is 2.0 to 3.5. General support systems, such as air systems, hydraulic system, hydrogen system, fuel system, and Schlieren system, are described. Instrumentation and data processing and acquisition systems are also described. Pretest meeting formats and schedules are outlined. Tunnel user responsibility and personnel safety are also discussed.

  7. Association between weather conditions and the number of patients at the emergency room in an Argentine hospital

    NASA Astrophysics Data System (ADS)

    Rusticucci, Matilde; Bettolli, Laura M.; de los Angeles Harris, M.

    2002-02-01

    The aim of this paper is to study the relationships between hospital emergencies and weather conditions by analysing summer and winter cases of patients requiring attention at the emergency room of a hospital in the city of Buenos Aires, Argentina. Hospital data have been sorted into seven different diagnostic groups as follows: (1) respiratory, cardiovascular and chest-pain complaints; (2) digestive, genitourinary and abdominal complaints; (3) neurological and psychopathological disorders; (4) infections; (5) contusion and crushing, bone and muscle complaints; (6) skin and allergies and (7) miscellaneous complaints. In general, there is an increase of 16.7% in winter while, for group 2 and group 6, there are more patients in summer, 54% and 75% respectively. In summer, the total number of patients for group 6 shows a significant positive correlation with temperature and dew-point temperature, and a negative correlation with the sea-level pressure for the same day. In winter, the same relationship exists, however its correlation is not as strong. The lags observed between these three variables: maximum dew-point temperature, maximum temperature, minimum air pressure and the peaks in admissions are 1, 2 and 4 days respectively. In winter, increases in temperature and dew point and decreases in pressure are followed by a peak in admissions for group 2. In winter, there are significantly more cases in group 5 on warm, dry days and on warm, wet days in the summer.

  8. Sensitivity of Mission Energy Consumption to Turboelectric Distributed Propulsion Design Assumptions on the N3-X Hybrid Wing Body Aircraft

    NASA Technical Reports Server (NTRS)

    Felder, James L.; Tong, Michael T.; Chu, Julio

    2012-01-01

    In a previous study by the authors it was shown that the N3-X, a 300 passenger hybrid wing body (HWB) aircraft with a turboelectric distributed propulsion (TeDP) system, was able to meet the NASA Subsonic Fixed Wing (SFW) project goal for N+3 generation aircraft of at least a 60% reduction in total energy consumption as compared to the best in class current generation aircraft. This previous study combined technology assumptions that represented the highest anticipated values that could be matured to technology readiness level (TRL) 4-6 by 2030. This paper presents the results of a sensitivity analysis of the total mission energy consumption to reductions in each key technology assumption. Of the parameters examined, the mission total energy consumption was most sensitive to changes to total pressure loss in the propulsor inlet. The baseline inlet internal pressure loss is assumed to be an optimistic 0.5%. An inlet pressure loss of 3% increases the total energy consumption 9%. However changes to reduce inlet pressure loss can result in additional distortion to the fan which can reduce fan efficiency or vice versa. It is very important that the inlet and fan be analyzed and optimized as a single unit. The turboshaft hot section is assumed to be made of ceramic matrix composite (CMC) with a 3000 F maximum material temperature. Reducing the maximum material temperature to 2700 F increases the mission energy consumption by only 1.5%. Thus achieving a 3000 F temperature in CMCs is important but not central to achieving the energy consumption objective of the N3-X/TeDP. A key parameter in the efficiency of superconducting motors and generators is the size of the superconducting filaments in the stator. The size of the superconducting filaments in the baseline model is assumed to be 10 microns. A 40 micron filament, which represents current technology, results in a 200% increase in AC losses in the motor and generator stators. This analysis shows that for a system with 40 micron filaments the higher stator losses plus the added weight and power of larger cryocoolers results in a 4% increase in mission energy consumption. If liquid hydrogen is used to cool the superconductors the 40 micron fibers results in a 200% increase in hydrogen required for cooling. Each pound of hydrogen used as fuel displaces 3 pounds of jet fuel. For the N3-X on the reference mission the additional hydrogen due to the increase stator losses reduces the total fuel weight 10%. The lighter fuel load and attendant vehicle resizing reduces the total energy consumption more than the higher stator losses increase it. As a result with hydrogen cooling there is a slight reduction in mission energy consumption with increasing stator losses. This counter intuitive result highlights the need to consider the full system impact of changes rather than just at the component or subsystem level.

  9. Atomic oxygen recombination on the ODS PM 1000 at high temperature under air plasma

    NASA Astrophysics Data System (ADS)

    Balat-Pichelin, M.; Bêche, E.

    2010-06-01

    High temperature materials are necessary for the design of primary heat shields for future reusable space vehicles re-entering atmospheric planet at hypersonic velocity. During the re-entry phase on earth, one of the most important phenomena occurring on the heat shield is the recombination of atomic oxygen and this phenomenon is more or less catalyzed by the material of the heat shield. PM 1000 is planned to be use on the EXPERT capsule to study in real conditions its catalycity. Before the flight, it is necessary to perform measurements on ground test facility. Experimental data of the recombination coefficient of atomic oxygen under air plasma flow were obtained in the diffusion reactor MESOX on pre-oxidized PM 1000, for two total pressures 300 and 1000 Pa in the temperature range (850-1650 K) using actinometry and optical emission spectroscopy. In this investigation, the evolution of the recombination coefficient is dependent of temperature, pressure level and also of the chemical composition of the surface leading to one order of magnitude for a given temperature. The recombination coefficient is increasing with temperature and also dependent on the static pressure. The surface change due to the plasma exposure is inspected with SEM, XRD and XPS. As chromium oxide is the main part of the oxide layer formed during the oxidation in air plasma conditions, a sintered Cr 2O 3 sample was elaborated from powders to compare the data of the recombination coefficient obtained on PM 1000. Pre- and post-test analyses on the several materials were carried out using SEM, WDS, XRD and XPS.

  10. Hemodynamic and thermoregulatory responses to lower body water immersion.

    PubMed

    Muller, Matthew D; Kim, Cihul-Ho; Seo, Yongsuk; Ryan, Edward J; Glickman, Ellen L

    2012-10-01

    Lower body water immersion (LBWI) is experienced in the marine industry but the physiological responses to LBWI are unclear. The purpose of the current experiment was to test the effects of water temperature and immersion duration on rectal temperature, heart rate, stroke volume, blood pressure, metabolic rate, and thermal sensation in healthy subjects. Nine young men underwent two 60-min trials of seated LBWI to the iliac crest in a counterbalanced fashion. On one occasion, the water was 35 degrees C (LBWI-Neutral) and on the other it was 13 degrees C (LBWI-Cold); the upper body remained thermoneutral and dry throughout. As expected, exposure to cold water reduced mean skin temperature and individuals reported cold thermal sensation. Mean arterial pressure was significantly higher at 60 min of LBWI-Cold (86 +/- 7 mmHg) compared to LBWI-Neutral (76 +/- 5 mmHg) while heart rate tended to be lower. The change in rectal temperature from baseline to 30 min of LBWI-Cold (delta = -0.01 +/- 0.21degrees C) was significantly smaller than the change in T(re) from 30 to 60 min of LBWI-Cold (delta = -0.46 +/- 0.16 degrees C). Despite this accelerated drop in core temperature during minutes 30-60, metabolic rate did not increase significantly. LBWI-Cold reduces core temperature and increases arterial blood pressure via an increase in total peripheral resistance. This experimental model may help scientists better understand the body during cold stress. Further, people who are occupationally exposed to cold water (when the torso, hands, and arms remain thermoneutral) may be at increased risk for hypothermia.

  11. Temperature and pressure dependent structural and thermo-physical properties of quaternary CoVTiAl alloy

    NASA Astrophysics Data System (ADS)

    Yousuf, Saleem; Gupta, Dinesh C.

    2017-09-01

    Investigation of band structure and thermo-physical response of new quaternary CoVTiAl Heusler alloy within the frame work of density functional theory has been analyzed. 100% spin polarization with ferromagnetic stable ground state at the optimized lattice parameter of 6.01 Å is predicted for the compound. Slater-Pauling rule for the total magnetic moment of 3 μB and an indirect semiconducting behavior is also seen for the compound. In order to perfectly analyze the thermo-physical response, the lattice thermal conductivity and thermodynamic properties have been calculated. Thermal effects on some macroscopic properties of CoVTiAl are predicted using the quasi-harmonic Debye model, in which the lattice vibrations are taken into account. The variations of the lattice constant, volume expansion coefficient, heat capacities, and Debye temperature with pressure and temperature in the ranges of 0 GPa to 15 GPa and 0 K to 800 K have been obtained.

  12. Fluctuating pressures measured beneath a high-temperature, turbulent boundary layer on a flat plate at Mach number of 5

    NASA Technical Reports Server (NTRS)

    Parrott, Tony L.; Jones, Michael G.; Albertson, Cindy W.

    1989-01-01

    Fluctuating pressures were measured beneath a Mach 5, turbulent boundary layer on a flat plate with an array of piezoresistive sensors. The data were obtained with a digital signal acquisition system during a test run of 4 seconds. Data sampling rate was such that frequency analysis up to 62.5 kHz could be performed. To assess in situ frequency response of the sensors, a specially designed waveguide calibration system was employed to measure transfer functions of all sensors and related instrumentation. Pressure time histories were approximated well by a Gaussian prohibiting distribution. Pressure spectra were very repeatable over the array span of 76 mm. Total rms pressures ranged from 0.0017 to 0.0046 of the freestream dynamic pressure. Streamwise, space-time correlations exhibited expected decaying behavior of a turbulence generated pressure field. Average convection speed was 0.87 of freestream velocity. The trendless behavior with sensor separation indicated possible systematic errors.

  13. Adsorption of Ions on Zirconium Oxide Surfaces from Aqueous Solutions at High Temperatures.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Palmer, Donald; Machesky, Michael L.; Benezeth, Pascale

    2009-07-01

    Surface titrations were carried out on suspensions of monoclinic ZrO{sub 2} from 25 to 290 C slightly above saturation vapor pressure at ionic strengths of 0.03, 0.1 and 1.0 mol {center_dot} kg{sup -1}(NaCl). A typical increase in surface charge was observed with increasing temperature. There was no correlation between the radius of the cations, Li{sup +}, Na{sup +}, K{sup +} and (CH{sub 3}){sub 4}N{sup +}, and the magnitude of their association with the surface. The combined results were treated with a 1-pK{sub a} MUSIC model, which yielded association constants for the cations (and chloride ion at low pH) at eachmore » temperature. The pH of zero-point-charge, pH{sub zpc}, decreased with increasing temperature as found for other metal oxides, reaching an apparent minimum value of 4.1 by 250 C. Batch experiments were performed to monitor the concentration of LiOH in solutions containing suspended ZrO{sub 2} particles from 200 to 360 C. At 350 and 360 C, Li{sup +} and OH{sup -} ions were almost totally adsorbed when the pressure was lowered to near saturation vapor pressure. This reversible trend has implications not only to pressure-water reactor, PWR, operations, but is also of general scientific and other applied interest. Additional experiments probed the feasibility that boric acid/borate ions adsorb reversibly onto ZrO{sub 2} surfaces at near-neutral pH conditions as indicated in earlier publications.« less

  14. Flow Disturbance Characterization Measurements in the National Transonic Facility

    NASA Technical Reports Server (NTRS)

    King, Rudolph A.; Andino, Marlyn Y.; Melton, Latunia; Eppink, Jenna; Kegerise, Michael A.; Tsoi, Andrew

    2012-01-01

    Recent flow measurements have been acquired in the National Transonic Facility (NTF) to assess the unsteady flow environment in the test section. The primary purpose of the test is to determine the feasibility of the NTF to conduct laminar-flow-control testing and boundary-layer transition sensitive testing. The NTF can operate in two modes, warm (air) and cold/cryogenic (nitrogen) test conditions for testing full and semispan scaled models. The warm-air mode enables low to moderately high Reynolds numbers through the use of high tunnel pressure, and the nitrogen mode enables high Reynolds numbers up to flight conditions, depending on aircraft type and size, utilizing high tunnel pressure and cryogenic temperatures. NASA's Environmentally Responsible Aviation (ERA) project is interested in demonstrating different laminar-flow technologies at flight-relevant operating conditions throughout the transonic Mach number range and the NTF is well suited for the initial ground-based demonstrations. Roll polar data at selected test conditions were obtained to look at the uniformity of the flow disturbance field in the test section. Data acquired from the rake probes included mean total temperatures, mean and fluctuating static/total pressures, and mean and fluctuating hot-wire measurements. . Based on the current measurements and previous data, an assessment was made that the NTF is a suitable facility for ground-based demonstrations of laminar-flow technologies at flight-relevant conditions in the cryogenic mode.

  15. Raspberry Pi Eclipse Experiments

    NASA Astrophysics Data System (ADS)

    Chizek Frouard, Malynda

    2018-01-01

    The 21 August 2017 solar eclipse was an excellent opportunity for electronics and science enthusiasts to collect data during a fascinating phenomenon. With my recent personal interest in Raspberry Pis, I thought measuring how much the temperature and illuminance changes during a total solar eclipse would be fun and informational.Previous observations of total solar eclipses have remarked on the temperature drop during totality. Illuminance (ambient light) varies over 7 orders of magnitude from day to night and is highly dependent on relative positions of Sun, Earth, and Moon. I wondered whether totality was really as dark as night.Using a Raspberry Pi Zero W, a Pimoroni Enviro pHAT, and a portable USB charger, I collected environmental temperature; CPU temperature (because the environmental temperature sensor sat very near the CPU on the Raspberry Pi); barometric pressure; ambient light; R, G, and B colors; and x, y, and z acceleration (for marking times when I moved the sensor) data at a ~15 second cadence starting at about 5 am until 1:30 pm from my eclipse observation site in Glendo, WY. Totality occurred from 11:45 to 11:47 am, lasting about 2 minutes and 30 seconds.The Raspberry Pi recorded a >20 degree F drop in temperature during the eclipse, and the illuminance during totality was equivalent to twilight measurements earlier in the day. A limitation in the ambient light sensor prevented accurate measurements of broad daylight and most of the partial phase of the eclipse, but an alternate ambient light sensor combined with the Raspberry Pi setup would make this a cost-efficient set-up for illuminance studies.I will present data from the ambient light sensor, temperature sensor, and color sensor, noting caveats from my experiments, lessons learned for next time, and suggestions for anyone who wants to perform similar experiments for themselves or with a classroom.

  16. Thermodynamic analysis of chemical stability of ceramic materials in hydrogen-containing atmospheres at high temperatures

    NASA Technical Reports Server (NTRS)

    Misra, Ajay K.

    1990-01-01

    The chemical stability of several ceramic materials in hydrogen-containing environments was analyzed with thermodynamic considerations in mind. Equilibrium calculations were made as a function of temperature, moisture content, and total system pressure. The following ceramic materials were considered in this study: SiC, Si3N4, SiO2, Al2O3, mullite, ZrO2, Y2O3, CaO, MgO, BeO, TiB2, TiC, HfC, and ZrC. On the basis of purely thermodynamic arguments, upper temperature limits are suggested for each material for long-term use in H2-containing atmospheres.

  17. Spin Diffusion Coefficient of A1-PHASE of Superfluid 3He at Low Temperatures

    NASA Astrophysics Data System (ADS)

    Afzali, R.; Pashaee, F.

    The spin diffusion coefficient tensor of the A1-phase of superfluid 3He at low temperatures and melting pressure is calculated using the Boltzmann equation approach and Pfitzner procedure. Then considering Bogoliubov-normal interaction, we show that the total spin diffusion is proportional to 1/T2, the spin diffusion coefficient of superfluid component D\\uparrowxzxz is proportional to T-2, and the spin diffusion coefficient of super-fluid component D\\uparrowxxxx (=D\\uarrowxyxy) is independent of temperature. Furthermore, it is seen that superfluid components play an important role in spin diffusion of the A1-phase.

  18. Pressure Infusion Cuff and Blood Warmer during Massive Transfusion: An Experimental Study About Hemolysis and Hypothermia.

    PubMed

    Poder, Thomas G; Pruneau, Denise; Dorval, Josée; Thibault, Louis; Fisette, Jean-François; Bédard, Suzanne K; Jacques, Annie; Beauregard, Patrice

    2016-01-01

    Blood warmers were developed to reduce the risk of hypothermia associated with the infusion of cold blood products. During massive transfusion, these devices are used with compression sleeve, which induce a major stress to red blood cells. In this setting, the combination of blood warmer and compression sleeve could generate hemolysis and harm the patient. We conducted this study to compare the impact of different pressure rates on the hemolysis of packed red blood cells and on the outlet temperature when a blood warmer set at 41.5°C is used. Pressure rates tested were 150 and 300 mmHg. Ten packed red blood cells units were provided by Héma-Québec and each unit was sequentially tested. We found no increase in hemolysis either at 150 or 300 mmHg. By cons, we found that the blood warmer was not effective at warming the red blood cells at the specified temperature. At 150 mmHg, the outlet temperature reached 37.1°C and at 300 mmHg, the temperature was 33.7°C. To use a blood warmer set at 41.5°C in conjunction with a compression sleeve at 150 or 300 mmHg does not generate hemolysis. At 300 mmHg a blood warmer set at 41.5°C does not totally avoid a risk of hypothermia.

  19. Thermomechanical stability and integrability of an embedded ceramic antenna with an integrated sensor element for wireless reading in harsh environments

    NASA Astrophysics Data System (ADS)

    Sturesson, P.; Khaji, Z.; Knaust, S.; Sundqvist, J.; Klintberg, L.; Thornell, G.

    2013-12-01

    This paper reports on the design, manufacturing and evaluation of a small, wirelessly powered and read resonating antenna circuit with an integrated pressure sensor. The work aims at developing miniature devices suitable for harsh environments, where high temperature prevents the use of conventional, silicon-based microdevices. Here, the device is made of alumina with platinum as conducting material. Ceramic green tapes were structured using high-precision milling, metallized using screen printing, and subsequently laminated to form stacks before they were sintered. The device's frequency shift as a function of temperature was studied up to 900°C. The contributions to the shift both from the thermomechanical deformation of the device at large, and from the integrated and, so far, self-pressurized sensor were sorted out. A total frequency shift of 3200 ppm was observed for the pressure sensor for heating over the whole range. Negligible levels of thermally induced radius of curvature were observed. With three-point bending, a frequency shift of 180 ppm was possible to induce with a curvature of radius of 220 m at a 10 N load. The results indicate that a robust pressure sensor node, which can register pressure changes of a few bars at 900°C and wirelessly transmit the signal, is viable.

  20. Compressor Performance Scaling in the Presence of Non-Uniform Flow

    NASA Astrophysics Data System (ADS)

    Hill, David Jarrod

    Fuselage-embedded engines in future aircraft will see increased flow distortions due to the ingestion of airframe boundary layers. This reduces the required propulsive power compared to podded engines. Inlet flow distortions mean that localized regions of flow within the fan and first stage compressor are operating at off-design conditions. It is important to weigh the benefit of increased vehicle propulsive efficiency against the resultant reduction in engine efficiency. High computational cost has limited most past research to single distortion studies. The objective of this thesis is to extract scaling laws for transonic compressor performance in the presence of various distortion patterns and intensities. The machine studied is the NASA R67 transonic compressor. Volumetric source terms are used to model rotor and stator blade rows. The modelling approach is an innovative combination of existing flow turning and loss models, combined with a compressible flow correction. This approach allows for a steady calculation to capture distortion transfer; as a result, the computational cost is reduced by two orders of magnitude. At peak efficiency, the rotor work coefficient and isentropic efficiency are matched within 1.4% of previously published experimental results. A key finding of this thesis is that, in non-uniform flow, the state-of-the-art loss model employed is unable to capture the impact of variations in local flow coefficient, limiting the analysis of local entropy generation. New insight explains the mechanism governing the interaction between a total temperature distortion and a compressor rotor. A parametric study comprising 16 inlet distortions reveals that for total temperature distortions, upstream flow redistribution and rotor diffusion factor changes are shown to scale linearly with distortion severity. Linear diffusion factor scaling does not hold true for total pressure distortions. For combined total temperature and total pressure distortions, the changes in rotor diffusion factor are predicted by the summation of the individual distortions, within 3.65%.

  1. Fluctuation Pressure Assisted Ejection of DNA From Bacteriophage

    NASA Astrophysics Data System (ADS)

    Harrison, Michael J.

    2011-03-01

    The role of thermal pressure fluctuations excited within tightly packaged DNA while it is ejected from protein capsid shells is discussed in a model calculation. At equilibrium before ejection we assume the DNA is folded many times into a bundle of parallel segments that forms an equilibrium conformation at minimum free energy, which presses tightly against capsid walls. Using a canonical ensemble at temperature T we calculate internal pressure fluctuations against a slowly moving or static capsid mantle for an elastic continuum model of the folded DNA bundle. It is found that fluctuating pressures on the capsid from thermal excitation of longitudinal acoustic vibrations in the bundle whose wavelengths are exceeded by the bend persistence length may have root-mean-square values that are several tens of atmospheres for typically small phage dimensions. Comparisons are given with measured data on three mutants of lambda phage with different base pair lengths and total genome ejection pressures.

  2. Empirical model based on Weibull distribution describing the destruction kinetics of natural microbiota in pineapple (Ananas comosus L.) puree during high-pressure processing.

    PubMed

    Chakraborty, Snehasis; Rao, Pavuluri Srinivasa; Mishra, Hari Niwas

    2015-10-15

    High pressure inactivation of natural microbiota viz. aerobic mesophiles (AM), psychrotrophs (PC), yeasts and molds (YM), total coliforms (TC) and lactic acid bacteria (LAB) in pineapple puree was studied within the experimental domain of 0.1-600 MPa and 30-50 °C with a treatment time up to 20 min. A complete destruction of yeasts and molds was obtained at 500 MPa/50 °C/15 min; whereas no counts were detected for TC and LAB at 300 MPa/30 °C/15 min. A maximum of two log cycle reductions was obtained for YM during pulse pressurization at the severe process intensity of 600 MPa/50 °C/20 min. The Weibull model clearly described the non-linearity of the survival curves during the isobaric period. The tailing effect, as confirmed by the shape parameter (β) of the survival curve, was obtained in case of YM (β<1); whereas a shouldering effect (β>1) was observed for the other microbial groups. Analogous to thermal death kinetics, the activation energy (Ea, kJ·mol(-1)) and the activation volume (Va, mL·mol(-1)) values were computed further to describe the temperature and pressure dependencies of the scale parameter (δ, min), respectively. A higher δ value was obtained for each microbe at a lower temperature and it decreased with an increase in pressure. A secondary kinetic model was developed describing the inactivation rate (k, min(-1)) as a function of pressure (P, MPa) and temperature (T, K) including the dependencies of Ea and Va on P and T, respectively. Copyright © 2015 Elsevier B.V. All rights reserved.

  3. Ambient iron-mediated aeration (IMA) for water reuse.

    PubMed

    Deng, Yang; Englehardt, James D; Abdul-Aziz, Samer; Bataille, Tristan; Cueto, Josenrique; De Leon, Omar; Wright, Mary E; Gardinali, Piero; Narayanan, Aarthi; Polar, Jose; Tomoyuki, Shibata

    2013-02-01

    Global water shortages caused by rapidly expanding population, escalating water consumption, and dwindling water reserves have rendered water reuse a strategically significant approach to meet current and future water demand. This study is the first to our knowledge to evaluate the technical feasibility of iron-mediated aeration (IMA), an innovative, potentially economical, holistic, oxidizing co-precipitation process operating at room temperature, atmospheric pressure, and neutral pH, for water reuse. In the IMA process, dissolved oxygen (O₂) was continuously activated by zero-valent iron (Fe⁰) to produce reactive oxygen species (ROS) at ambient pH, temperature, and pressure. Concurrently, iron sludge was generated as a result of iron corrosion. Bench-scale tests were conducted to study the performance of IMA for treatment of secondary effluent, natural surface water, and simulated contaminated water. The following removal efficiencies were achieved: 82.2% glyoxylic acid, ~100% formaldehyde as an oxidation product of glyoxylic acid, 94% of Ca²⁺ and associated alkalinity, 44% of chemical oxygen demand (COD), 26% of electrical conductivity (EC), 98% of di-n-butyl phthalate (DBP), 80% of 17β-estradiol (E2), 45% of total nitrogen (TN), 96% of total phosphorus (TP), 99.8% of total Cr, >90% of total Ni, 99% of color, 3.2 log removal of total coliform, and 2.4 log removal of E. Coli. Removal was attributed principally to chemical oxidation, precipitation, co-precipitation, coagulation, adsorption, and air stripping concurrently occurring during the IMA treatment. Results suggest that IMA is a promising treatment technology for water reuse. Copyright © 2012 Elsevier Ltd. All rights reserved.

  4. The Baryonic and Dark Matter Distributions in Abell 401

    NASA Astrophysics Data System (ADS)

    Nevalainen, J.; Markevitch, M.; Forman, W.

    1999-11-01

    We combine spatially resolved ASCA temperature data with ROSAT imaging data to constrain the total mass distribution in the cluster A401, assuming that the cluster is in hydrostatic equilibrium, but without the assumption of gas isothermality. We obtain a total mass within the X-ray core (290 h-150 kpc) of 1.2+0.1-0.5×1014 h-150 Msolar at the 90% confidence level, 1.3 times larger than the isothermal estimate. The total mass within r500 (1.7 h-150 Mpc) is M500=0.9+0.3-0.2×1015 h-150 Msolar at 90% confidence, in agreement with the optical virial mass estimate, and 1.2 times smaller than the isothermal estimate. Our M500 value is 1.7 times smaller than that estimated using the mass-temperature scaling law predicted by simulations. The best-fit dark matter density profile scales as r-3.1 at large radii, which is consistent with the Navarro, Frenk & White (NFW) ``universal profile'' as well as the King profile of the galaxy density in A401. From the imaging data, the gas density profile is shallower than the dark matter profile, scaling as r-2.1 at large radii, leading to a monotonically increasing gas mass fraction with radius. Within r500 the gas mass fraction reaches a value of fgas=0.21+0.06-0.05 h-3/250 (90% confidence errors). Assuming that fgas (plus an estimate of the stellar mass) is the universal value of the baryon fraction, we estimate the 90% confidence upper limit of the cosmological matter density to be Ωm<0.31, in conflict with an Einstein-deSitter universe. Even though the NFW dark matter density profile is statistically consistent with the temperature data, its central temperature cusp would lead to convective instability at the center, because the gas density does not have a corresponding peak. One way to reconcile a cusp-shaped total mass profile with the observed gas density profile, regardless of the temperature data, is to introduce a significant nonthermal pressure in the center. Such a pressure must satisfy the hydrostatic equilibrium condition without inducing turbulence. Alternately, significant mass drop-out from the cooling flow would make the temperature less peaked and the NFW profile acceptable. However, the quality of data is not adequate to test this possibility.

  5. An Annular Mechanical Temperature Compensation Structure for Gas-Sealed Capacitive Pressure Sensor

    PubMed Central

    Hao, Xiuchun; Jiang, Yonggang; Takao, Hidekuni; Maenaka, Kazusuke; Higuchi, Kohei

    2012-01-01

    A novel gas-sealed capacitive pressure sensor with a temperature compensation structure is reported. The pressure sensor is sealed by Au-Au diffusion bonding under a nitrogen ambient with a pressure of 100 kPa and integrated with a platinum resistor-based temperature sensor for human activity monitoring applications. The capacitance-pressure and capacitance-temperature characteristics of the gas-sealed capacitive pressure sensor without temperature compensation structure are calculated. It is found by simulation that a ring-shaped structure on the diaphragm of the pressure sensor can mechanically suppress the thermal expansion effect of the sealed gas in the cavity. Pressure sensors without/with temperature compensation structures are fabricated and measured. Through measured results, it is verified that the calculation model is accurate. Using the compensation structures with a 900 μm inner radius, the measured temperature coefficient is much reduced as compared to that of the pressure sensor without compensation. The sensitivities of the pressure sensor before and after compensation are almost the same in the pressure range from 80 kPa to 100 kPa. PMID:22969385

  6. How strong is the impact of the Indo-ocean dipole on the surface air temperature/sea level pressure anomalies in the Mediterranean region?

    NASA Astrophysics Data System (ADS)

    Polonsky, Alexander B.; Basharin, Dmitry V.

    2017-04-01

    The aim of this paper is to study the interannual climate variability over the Mediterranean region related to the Indo-ocean dipole (IOD) using the data of re-analyses, archival data and specialized numerical experiments. It is shown that the IOD does not impact essentially the anomalies of surface air temperature (SAT) and sea level pressure (SLP) in the Mediterranean region. On average, the IOD-induced share of the SAT/SLP variance in the total variance of these fields in the Mediterranean region is smaller than 10% even in summer when it is at a maximum. However, the statistically significant IOD-induced SAT/SLP anomalies in the Mediterranean region are detectable. For definite IOD events the associated Mediterranean SAT anomalies can reach about 1 °C.

  7. Ambient temperature and volume of perihematomal edema in acute intracerebral haemorrhage: the INTERACT1 study.

    PubMed

    Zheng, Danni; Arima, Hisatomi; Heeley, Emma; Karpin, Anne; Yang, Jie; Chalmers, John; Anderson, Craig S

    2015-01-01

    As no human data exist, we aimed to determine the relation between ambient temperature and volume of perihematomal 'cerebral' edema in acute spontaneous intracerebral haemorrhage (ICH) among Chinese participants of the pilot phase, Intensive Blood Pressure Reduction in Acute Cerebral Haemorrhage Trial (INTERACT1). INTERACT1 was a multicenter, open, blind outcome assessed, randomized controlled trial of intensive (systolic target <140 mmHg) vs. guideline-recommended (systolic target <180 mmHg) blood pressure (BP) lowering in 404 patients with acute ICH. Data on ambient temperature (mean, minimum, maximum, and range) on the day of each participant's ICH obtained from China Meteorological Data Sharing Service System were linked to other data including edema volumes. Multivariable regression analyses were performed to evaluate association between ambient temperature and edema volumes. A generalized linear regression model with a generalized estimating equations approach (GEE) was used to assess any association of ambient temperature and change in edema volume over 72 h. A total of 250 of all 384 Chinese participants had complete data that showed positive associations between ambient temperature (mean and minimum temperatures) and edema volumes at each time point over 72 h after hospital admission (all P < 0·05). All temperature parameters except diurnal temperature range were positively associated with edema volume after adjustment for confounding variables (all P < 0·02). An apparent positive association exists between ambient temperature and perihematomal edema volume in acute spontaneous ICH. © 2014 World Stroke Organization.

  8. Impact of pH and Total Soluble Solids on Enzyme Inactivation Kinetics during High Pressure Processing of Mango (Mangifera indica) Pulp.

    PubMed

    Kaushik, Neelima; Nadella, Tejaswi; Rao, P Srinivasa

    2015-11-01

    This study was undertaken with an aim to enhance the enzyme inactivation during high pressure processing (HPP) with pH and total soluble solids (TSS) as additional hurdles. Impact of mango pulp pH (3.5, 4.0, 4.5) and TSS (15, 20, 25 °Brix) variations on the inactivation of pectin methylesterase (PME), polyphenol oxidase (PPO), and peroxidase (POD) enzymes were studied during HPP at 400 to 600 MPa pressure (P), 40 to 70 °C temperature (T), and 6- to 20-min pressure-hold time (t). The enzyme inactivation (%) was modeled using second order polynomial equations with a good fit that revealed that all the enzymes were significantly affected by HPP. Response surface and contour models predicted the kinetic behavior of mango pulp enzymes adequately as indicated by the small error between predicted and experimental data. The predicted kinetics indicated that for a fixed P and T, higher pulse pressure effect and increased isobaric inactivation rates were possible at lower levels of pH and TSS. In contrast, at a fixed pH or TSS level, an increase in P or T led to enhanced inactivation rates, irrespective of the type of enzyme. PPO and POD were found to have similar barosensitivity, whereas PME was found to be most resistant to HPP. Furthermore, simultaneous variation in pH and TSS levels of mango pulp resulted in higher enzyme inactivation at lower pH and TSS during HPP, where the effect of pH was found to be predominant than TSS within the experimental domain. Exploration of additional hurdles such as pH, TSS, and temperature for enzyme inactivation during high pressure processing of fruits is useful from industrial point of view, as these parameters play key role in preservation process design. © 2015 Institute of Food Technologists®

  9. Comparison of Mixing Characteristics for Several Fuel Injectors on an Open Plate and in a Ducted Flowpath Configuration at Hypervelocity Flow Conditions

    NASA Technical Reports Server (NTRS)

    Drozda, Tomasz G.; Shenoy, Rajiv R.; Passe, Bradley J.; Baurle, Robert A.; Drummond, J. Philip

    2017-01-01

    In order to reduce the cost and complexity associated with fuel injection and mixing experiments for high-speed flows, and to further enable optical access to the test section for nonintrusive diagnostics, the Enhanced Injection and Mixing Project (EIMP) utilizes an open flat plate configuration to characterize inert mixing properties of various fuel injectors for hypervelocity applications. The experiments also utilize reduced total temperature conditions to alleviate the need for hardware cooling. The use of "cold" flows and non-reacting mixtures for mixing experiments is not new, and has been extensively utilized as a screening technique for scramjet fuel injectors. The impact of reduced facility-air total temperature, and the use of inert fuel simulants, such as helium, on the mixing character of the flow has been assessed in previous numerical studies by the authors. Mixing performance was characterized for three different injectors: a strut, a ramp, and a flushwall. The present study focuses on the impact of using an open plate to approximate mixing in the duct. Toward this end, Reynolds-averaged simulations (RAS) were performed for the three fuel injectors in an open plate configuration and in a duct. The mixing parameters of interest, such as mixing efficiency and total pressure recovery, are then computed and compared for the two configurations. In addition to mixing efficiency and total pressure recovery, the combustion efficiency and thrust potential are also computed for the reacting simulations.

  10. Low temperature photochemical vapor deposition of alloy and mixed metal oxide films

    DOEpatents

    Liu, D.K.

    1992-12-15

    Method and apparatus are described for formation of an alloy thin film, or a mixed metal oxide thin film, on a substrate at relatively low temperatures. Precursor vapor(s) containing the desired thin film constituents is positioned adjacent to the substrate and irradiated by light having wavelengths in a selected wavelength range, to dissociate the gas(es) and provide atoms or molecules containing only the desired constituents. These gases then deposit at relatively low temperatures as a thin film on the substrate. The precursor vapor(s) is formed by vaporization of one or more precursor materials, where the vaporization temperature(s) is selected to control the ratio of concentration of metals present in the precursor vapor(s) and/or the total precursor vapor pressure. 7 figs.

  11. Turbulent boundary-layer velocity profiles on a nonadiabatic at Mach number 6.5

    NASA Technical Reports Server (NTRS)

    Keener, E. R.; Hopkins, E. J.

    1972-01-01

    Velocity profiles were obtained from pitot-pressure and total-temperature measurements within a turbulent boundary layer on a large sharp-edged flat plate. Momentum-thickness Reynolds number ranged from 2590 to 8860 and wall-to-adiabatic-wall temperature ratios ranged from 0.3 to 0.5. Measurements were made both with and without boundary layer trips. Five methods are evaluated for correlating the measured velocity profiles with the incompressible law-of-the-wall and the velocity defect law. The mixing-length generalization of Van Driest gives the best correlation.

  12. Liquid-Vapor Equilibrium of Multicomponent Cryogenic Systems

    NASA Technical Reports Server (NTRS)

    Thompson, W. Reid; Calado, Jorge C. G.; Zollweg, John A.

    1990-01-01

    Liquid-vapor and solid-vapor equilibria at low to moderate pressures and low temperatures are important in many solar system environments, including the surface and clouds of Titan, the clouds of Uranus and Neptune, and the surfaces of Mars and Triton. The familiar cases of ideal behavior are limiting cases of a general thermodynamic representation for the vapor pressure of each component in a homogeneous multicomponent system. The fundamental connections of laboratory measurements to thermodynamic models are through the Gibbs-Duhem relation and the Gibbs-Helmholtz relation. Using laboratory measurements of the total pressure, temperature, and compositions of the liquid and vapor phases at equilibrium, the values of these parameters can be determined. The resulting model for vapor-liquid equilibrium can then conveniently and accurately be used to calculate pressures, compositions, condensation altitudes, and their dependencies on changing climatic conditions. A specific system being investigated is CH4-C2H6-N2, at conditions relevant to Titan's surface and atmosphere. Discussed are: the modeling of existing data on CH4-N2, with applications to the composition of Titan's condensate clouds; some new measurements on the CH4-C2H6 binary, using a high-precision static/volumetric system, and on the C2H6-N2 binary, using the volumetric system and a sensitive cryogenic flow calorimeter; and describe a new cryogenic phase-equilibrium vessel with which we are beginning a detailed, systematic study of the three constituent binaries and the ternary CH4-C2H6-N2 system at temperatures ranging from 80 to 105 K and pressures from 0.1 to 7 bar.

  13. Performance of a Model Rich Burn-quick Mix-lean Burn Combustor at Elevated Temperature and Pressure

    NASA Technical Reports Server (NTRS)

    Peterson, Christopher O.; Sowa, William A.; Samuelsen, G. S.

    2002-01-01

    As interest in pollutant emission from stationary and aero-engine gas turbines increases, combustor engineers must consider various configurations. One configuration of increasing interest is the staged, rich burn - quick mix - lean burn (RQL) combustor. This report summarizes an investigation conducted in a recently developed high pressure gas turbine combustor facility. The model RQL combustor was plenum fed and modular in design. The fuel used for this study is Jet-A which was injected from a simplex atomizer. Emission (CO2, CO, O2, UHC, NOx) measurements were obtained using a stationary exit plane water-cooled probe and a traversing water-cooled probe which sampled from the rich zone exit and the lean zone entrance. The RQL combustor was operated at inlet temperatures ranging from 367 to 700 K, pressures ranging from 200 to 1000 kPa, and combustor reference velocities ranging from 10 to 20 m/s. Variations were also made in the rich zone and lean zone equivalence ratios. Several significant trends were observed. NOx production increased with reaction temperature, lean zone equivalence ratio and residence time and decreased with increased rich zone equivalence ratio. NOx production in the model RQL combustor increased to the 0.4 power with increased pressure. This correlation, compared to those obtained for non-staged combustors (0.5 to 0.7), suggests a reduced dependence on NOx on pressure for staged combustors. Emissions profiles suggest that rich zone mixing is not uniform and that the rich zone contributes on the order of 16 percent to the total NOx produced.

  14. Non-thermal pressure in the outskirts of Abell 2142

    NASA Astrophysics Data System (ADS)

    Fusco-Femiano, Roberto; Lapi, Andrea

    2018-03-01

    Clumping and turbulence are expected to affect the matter accreted on to the outskirts of galaxy clusters. To determine their impact on the thermodynamic properties of Abell 2142, we perform an analysis of the X-ray temperature data from XMM-Newton via our SuperModel, a state-of-the-art tool for investigating the astrophysics of the intracluster medium already tested on many individual clusters (since Cavaliere, Lapi & Fusco-Femiano 2009). Using the gas density profile corrected for clumpiness derived by Tchernin et al. (2016), we find evidence for the presence of a non-thermal pressure component required to sustain gravity in the cluster outskirts of Abell 2142, that amounts to about 30 per cent of the total pressure at the virial radius. The presence of the non-thermal component implies the gas fraction to be consistent with the universal value at the virial radius and the electron thermal pressure profile to be in good agreement with that inferred from the SZ data. Our results indicate that the presence of gas clumping and of a non-thermal pressure component are both necessary to recover the observed physical properties in the cluster outskirts. Moreover, we stress that an alternative method often exploited in the literature (included Abell 2142) to determine the temperature profile kBT = Pe/ne basing on a combination of the Sunyaev-Zel'dovich (SZ) pressure Pe and of the X-ray electron density ne does not allow us to highlight the presence of non-thermal pressure support in the cluster outskirts.

  15. Expansion and evolution of fractures in coal-rock mass for coalfield fires with the conditions of temperatures and pressures in China

    NASA Astrophysics Data System (ADS)

    Xiao, Yang; Zhou, Yi-Feng; Deng, Jun; Yi, Xin

    2017-04-01

    The process of coalfield fire is a complicated result of physical and chemical action, which is attributed to uncontrolled continuously combustion. The fire holds the ceaselessly expansion which dues to the oxygen supply constantly. The fractures play a key role to provide passageway for oxygen supply, and heat discharge and gases emission. In this article, we chose the samples of coal and rock in coalfields of Qinshui and Zhunnan, China, and the conditions: (1) single affection of temperature from 25 °C (room temperature) to 500 °C, (2) effect of temperatures (room temperature, 80 °C, 140 °C, 200 °C), and total process of stress and strain. The MTS 880, and industrial CT employed to do the experimental tests. For given heating at 5 °C/min, the length and width of fractures are increased as raising the temperature, and the threshold of temperature at 300 °C is determined at the range of 25-500 °C. As rising the temperature, the total amounts of fractures are augmented in samples, which shapes are converted from slightness to ellipse. The compression strength occurs first increase and then decrease, which reached the maximal value at 140 °C.

  16. Dependence of N-polar GaN rod morphology on growth parameters during selective area growth by MOVPE

    NASA Astrophysics Data System (ADS)

    Li, Shunfeng; Wang, Xue; Mohajerani, Matin Sadat; Fündling, Sönke; Erenburg, Milena; Wei, Jiandong; Wehmann, Hergo-Heinrich; Waag, Andreas; Mandl, Martin; Bergbauer, Werner; Strassburg, Martin

    2013-02-01

    Selective area growth of GaN rods by metalorganic vapor phase epitaxy has attracted great interest due to its novel applications in optoelectronic and photonics. In this work, we will present the dependence of GaN rod morphology on various growth parameters i.e. growth temperature, H2/N2 carrier gas concentration, V/III ratio, total carrier gas flow and reactor pressure. It is found that higher growth temperature helps to increase the aspect ratio of the rods, but reduces the height homogeneity. Furthermore, H2/N2 carrier gas concentration is found to be a critical factor to obtain vertical rod growth. Pure nitrogen carrier gas leads to irregular growth of GaN structure, while an increase of hydrogen carrier gas results in vertical GaN rod growth. Higher hydrogen carrier gas concentration also reduces the diameter and enhances the aspect of the GaN rods. Besides, increase of V/III ratio causes reduction of the aspect ratio of N-polar GaN rods, which could be explained by the relatively lower growth rate on (000-1) N-polar top surface when supplying more ammonia. In addition, an increase of the total carrier gas flow leads to a decrease in the diameter and the average volume of GaN rods. These phenomena are tentatively explained by the change of partial pressure of the source materials and boundary layer thickness in the reactor. Finally, it is shown that the average volume of the N-polar GaN rods keeps a similar value for a reactor pressure PR of 66 and 125 mbar, while an incomplete filling of the pattern opening is observed with PR of 250 mbar. Room temperature photoluminescence spectrum of the rods is also briefly discussed.

  17. Pressure in isochoric systems containing aqueous solutions at subzero Centigrade temperatures.

    PubMed

    Ukpai, Gideon; Năstase, Gabriel; Șerban, Alexandru; Rubinsky, Boris

    2017-01-01

    Preservation of biological materials at subzero Centigrade temperatures, cryopreservation, is important for the field of tissue engineering and organ transplantation. Our group is studying the use of isochoric (constant volume) systems of aqueous solution for cryopreservation. Previous studies measured the pressure-temperature relations in aqueous isochoric systems in the temperature range from 0°C to - 20°C. The goal of this study is to expand the pressure-temperature measurement beyond the range reported in previous publications. To expand the pressure-temperature measurements beyond the previous range, we have developed a new isochoric device capable of withstanding liquid nitrogen temperatures and pressures of up to 413 MPa. The device is instrumented with a pressure transducer than can monitor and record the pressures in the isochoric chamber in real time. Measurements were made in a temperature range from - 5°C to liquid nitrogen temperatures for various solutions of pure water and Me2SO (a chemical additive used for protection of biological materials in a frozen state and for vitrification (glass formation) of biological matter). Undissolved gaseous are is carefully removed from the system. Temperature-pressure data from - 5°C to liquid nitrogen temperature for pure water and other solutions are presented in this study. Following are examples of some, temperature-pressure values, that were measured in an isochoric system containing pure water: (- 20°C, 187 MPa); (-25°C, 216 MPa); (- 30°C, 242.3 MPa); (-180°C, 124 MPa). The data is consistent with the literature, which reports that the pressure and temperature at the triple point, between ice I, ice III and water is, - 21.993°C and 209.9 MPa, respectively. It was surprising to find that the pressure in the isochoric system increases at temperatures below the triple point and remains high to liquid nitrogen temperatures. Measurements of pressure-temperature relations in solutions of pure water and Me2SO in different concentrations show that, for concentrations in which vitrification is predicted, no increase in pressure was measured during rapid cooling to liquid nitrogen temperatures. However, ice formation either during cooling or warming to and from liquid nitrogen temperatures produced an increase in pressure. The data obtained in this study can be used to aid in the design of isochoric cryopreservation protocols. The results suggest that the pressure measurement is important in the design of "constant volume" systems and can provide a simple means to gain information on the occurrence of vitrification and devitrification during cryopreservation processes of aqueous solutions in an isochoric system.

  18. Influence of contrast media viscosity and temperature on injection pressure in computed tomographic angiography: a phantom study.

    PubMed

    Kok, Madeleine; Mihl, Casper; Mingels, Alma A; Kietselaer, Bas L; Mühlenbruch, Georg; Seehofnerova, Anna; Wildberger, Joachim E; Das, Marco

    2014-04-01

    Iodinated contrast media (CM) in computed tomographic angiography is characterized by its concentration and, consecutively, by its viscosity. Viscosity itself is directly influenced by temperature, which will furthermore affect injection pressure. Therefore, the purposes of this study were to systematically evaluate the viscosity of different CM at different temperatures and to assess their impact on injection pressure in a circulation phantom. Initially, viscosity of different contrast media concentrations (240, 300, 370, and 400 mgI/mL) was measured at different temperatures (20°C-40°C) with a commercially available viscosimeter. In the next step, a circulation phantom with physical conditions was used. Contrast media were prepared at different temperatures (20°C, 30°C, 37°C) and injected through a standard 18-gauge needle. All other relevant parameters were kept constant (iodine delivery rate, 1.9 g I/s; total amount of iodine, 15 g I). Peak flow rate (in milliliter per second) and injection pressure (psi) were monitored. Differences in significance were tested using the Kruskal-Wallis test (Statistical Package for the Social Sciences). Viscosities for iodinated CM of 240, 300, 370, and 400 mg I/mL at 20°C were 5.1, 9.1, 21.2, and 28.8 mPa.s, respectively, whereas, at 40°C, these were substantially lower (2.8, 4.4, 8.7, and 11.2 mPa.s). In the circulation phantom, mean (SD) peak pressures for CM of 240 mg I/mL at 20°C, 30°C, and 37°C were 107 (1.5), 95 (0.6), and 92 (2.1) psi; for CM of 300 mg I/mL, 119 (1.5), 104 (0.6), and 100 (3.6) psi; for CM of 370 mg I/mL, 150 (0.6), 133 (4.4), and 120 (3.5) psi; and for CM of 400 mg I/mL, 169 (1.0), 140 (2.1), and 135 (2.9) psi, respectively, with all P values less than 0.05. Low concentration, low viscosity, and high temperatures of CM are beneficial in terms of injection pressure. This should also be considered for individually tailored contrast protocols in daily routine scanning.

  19. High-Area-Ratio Rocket Nozzle at High Combustion Chamber Pressure: Experimental and Analytical Validation

    NASA Technical Reports Server (NTRS)

    Jankovsky, Robert S.; Smith, Timothy D.; Pavli, Albert J.

    1999-01-01

    Experimental data were obtained on an optimally contoured nozzle with an area ratio of 1025:1 and on a truncated version of this nozzle with an area ratio of 440:1. The nozzles were tested with gaseous hydrogen and liquid oxygen propellants at combustion chamber pressures of 1800 to 2400 psia and mixture ratios of 3.89 to 6.15. This report compares the experimental performance, heat transfer, and boundary layer total pressure measurements with theoretical predictions of the current Joint Army, Navy, NASA, Air Force (JANNAF) developed methodology. This methodology makes use of the Two-Dimensional Kinetics (TDK) nozzle performance code. Comparisons of the TDK-predicted performance to experimentally attained thrust performance indicated that both the vacuum thrust coefficient and the vacuum specific impulse values were approximately 2.0-percent higher than the turbulent prediction for the 1025:1 configurations, and approximately 0.25-percent higher than the turbulent prediction for the 440:1 configuration. Nozzle wall temperatures were measured on the outside of a thin-walled heat sink nozzle during the test fittings. Nozzle heat fluxes were calculated front the time histories of these temperatures and compared with predictions made with the TDK code. The heat flux values were overpredicted for all cases. The results range from nearly 100 percent at an area ratio of 50 to only approximately 3 percent at an area ratio of 975. Values of the integral of the heat flux as a function of nozzle surface area were also calculated. Comparisons of the experiment with analyses of the heat flux and the heat rate per axial length also show that the experimental values were lower than the predicted value. Three boundary layer rakes mounted on the nozzle exit were used for boundary layer measurements. This arrangement allowed total pressure measurements to be obtained at 14 different distances from the nozzle wall. A comparison of boundary layer total pressure profiles and analytical predictions show good agreement for the first 0.5 in. from the nozzle wall; but the further into the core flow that measurements were taken, the more that TDK overpredicted the boundary layer thickness.

  20. EFFECTS OF TRITIUM GAS EXPOSURE ON EPDM ELASTOMER

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Clark, E.

    2009-12-11

    Samples of four formulations of ethylene-propylene diene monomer (EPDM) elastomer were exposed to initially pure tritium gas at one atmosphere and ambient temperature for various times up to about 420 days in closed containers. Two formulations were carbon-black-filled commercial formulations, and two were the equivalent formulations without filler synthesized for this work. Tritium effects on the samples were characterized by measuring the sample volume, mass, flexibility, and dynamic mechanical properties and by noting changes in appearance. The glass transition temperature was determined by analysis of the dynamic mechanical properties. The glass transition temperature increased significantly with tritium exposure, and themore » unfilled formulations ceased to behave as elastomers after the longest tritium exposure. The filled formulations were more resistant to tritium exposure. Tritium exposure made all samples significantly stiffer and therefore much less able to form a reliable seal when employed as O-rings. No consistent change of volume or density was observed; there was a systematic lowering of sample mass with tritium exposure. In addition, the significant radiolytic production of gas, mainly protium (H{sub 2}) and HT, by the samples when exposed to tritium was characterized by measuring total pressure in the container at the end of each exposure and by mass spectroscopy of a gas sample at the end of each exposure. The total pressure in the containers more than doubled after {approx}420 days tritium exposure.« less

  1. Laser-machined microcavities for simultaneous measurement of high-temperature and high-pressure.

    PubMed

    Ran, Zengling; Liu, Shan; Liu, Qin; Huang, Ya; Bao, Haihong; Wang, Yanjun; Luo, Shucheng; Yang, Huiqin; Rao, Yunjiang

    2014-08-07

    Laser-machined microcavities for simultaneous measurement of high-temperature and high-pressure are demonstrated. These two cascaded microcavities are an air cavity and a composite cavity including a section of fiber and an air cavity. They are both placed into a pressure chamber inside a furnace to perform simultaneous pressure and high-temperature tests. The thermal and pressure coefficients of the short air cavity are ~0.0779 nm/°C and ~1.14 nm/MPa, respectively. The thermal and pressure coefficients of the composite cavity are ~32.3 nm/°C and ~24.4 nm/MPa, respectively. The sensor could be used to separate temperature and pressure due to their different thermal and pressure coefficients. The excellent feature of such a sensor head is that it can withstand high temperatures of up to 400 °C and achieve precise measurement of high-pressure under high temperature conditions.

  2. Cross spectra between temperature and pressure in a constant area duct downstream of a combustor

    NASA Technical Reports Server (NTRS)

    Miles, J. H.; Wasserbauer, C. A.; Krejsa, E. A.

    1983-01-01

    The feasibility of measuring pressure temperature cross spectra and coherence and temperature-temperature cross spectra and coherence at spatially separated points along with pressure and temperature auto-spectra in a combustion rig was investigated. The measurements were made near the inlet and exit of a 6.44 m long duct attached to a J-47 combustor. The fuel used was Jet A. The cross spectra and coherence measurements show the pressure and temperature fluctuations correlate best at low frequencies. At the inlet the phenomena controlling the phase relationship between pressure and temperature could not be identified. However, at the duct exit the phase angle of the pressure is related to the phase angle of the temperature by the convected flow time delay.

  3. Pressure and temperature interactions on cellular respiration: a review.

    PubMed

    Sebert, P; Theron, M; Vettier, A

    2004-06-01

    Thermodynamic equations show that pressure and temperature can, theoretically, act in synergy or in opposite directions depending on their respective variations. Hence, they interact to establish rates of biological processes (pressure/temperature interactions, PTI). For such studies, it is interesting to use aquatic ectotherms, in particular fish, because it is easy to submit them to temperature and/or pressure changes. This review focuses on the effects of temperature and pressure changes on the energy metabolism of fish, mitochondrial oxygen consumption and functioning, showing that the observed effects do not always match the predictions made by equations or models. Unpublished results concerning the mitochondrial function of eels acclimatised at two temperatures and two pressures show that the mitochondrial targets of pressure and temperature are probably not the same. The possible mechanisms and consequences of PTI are discussed.

  4. Polymerization Experiment Of Amino Acids Under High Pressure And Temperature Conditions Simulating The Deep Lithosphere

    NASA Astrophysics Data System (ADS)

    Ohara, S.; Kakegawa, T.; Nakazawa, H.

    2005-12-01

    Chemical evolution in deep sea or deep lithosphere is one of the popular hypotheses for the origin of life on the early Earth. In such hypothesis, effects of pressure and temperature on polymerization (and/or stability) of amino acids needed to be evaluated. In this study, high temperature and pressure experiments were performed using of a test-tube-type autoclave for polymerization of amino acids. Approximately 100 mg of Glycine powder were placed into sterilized gold capsule. Multiple experiments were done at 150 degrees for 1 to 8 days at variable pressures (25MPa, 50MPa, 75MPa and 100MPa). Glycine peptides were identified and quantified by high performance liquid chromatography (HPLC). Each capsule was opened carefully and 1 ml of mobile phase was added to release the amino acids and oligopeptide from the solid phase. Liquid phases were separated by the cetrifugal method. Peptides were identified by retention times of authentic reference substances. The reaction yields were determined as percentage of the reactant converted to the reaction product. Pligopeptides more than hexamer were additionally identified by the detection of the molecular ion by liquid chromatography mass spectrometry (LC / MS). A HPLC chromatogram of the products indicated at least seven oligomers: diketopiperazine (cyc(Gly)2), di-glycine (Gly2), tri-glycine (Gly3), tetra-glycine (Gly4), penta-glycine (Gly5) and hexa-glycine (Gly6). We also identified hepta-glycine (Gly7), octa-glycine (Gly8) and nona-glycine (Gly9) with LC/MS. This is the first report that up to nona-glycine was synthesized under high temperature and pressure conditions. In addition, our experiments indicate that polymerization occurs wide range of pressure from 25 to 100 MPa. On the other hand, yields of total amounts of peptide did not change with pressure, suggesting that an unknown process in the autoclave is limiting the yield. We speculate the activity of water vapor, generated by peptide formation reaction, controlled the yield in the autoclave. The results from this study support the theory that chemical evolution could happen in deep Earth environments, such as inside of lithosphere.

  5. Barometric pressure forcing on radon-222 and temperature in fumarolic gases: a tool to describe flow-rate dynamics

    NASA Astrophysics Data System (ADS)

    Richon, P.; Salaun, A.; Boudon, G.; Villemant, B.; Crispi, O.; Sabroux, J.

    2010-12-01

    We propose two conceptual models for the dynamics of fumarolic gases, during their ascent through the volcano plumbing, based on radon-222 and temperature data collected on fumaroles of La Soufrière volcano (Guadeloupe,FWI) together with local barometric pressure, and on a new interpretation of older data collected on Merapi volcano (1), Indonesia. All these in-situ measurements prove that the diurnal (24h, S1 barometric wave) and semidiurnal (12h, S2 barometric wave) variations in radon concentration are clearly observable, and positively or negatively correlated with barometric pressure variation. Two models are used to interpret this correlation. The first model, called “Accumulation mode”, is characterized by an initial and negligible deep radon-222 source and by a major contribution of radon-222 from conduit walls and connected fractures (emanation and exhalation mechanisms) during the gas ascent through the fumarolic system. This model is substantiated by a positive correlation between radon and pressure in the Merapi fumaroles. The second model, or “Decay mode”, is exemplified by a negative correlation between radon and pressure as measured in fumaroles at La Soufrière volcano. It is characterized by radioactive decay of a strong initial radon-222 source generated by a deeper reservoir (hydrothermal system or magmatic chamber) whereas contribution by conduit walls and connected fractures to the total radon-222 activity in the fumarole is comparatively minor during the transit time of the gas. In these two modes, it is possible to infer that, for transit times longer than ca. 21 days, the barometric pressure does not modulate the radon signal. Thus, the simultaneous monitoring of radon-222, temperature and barometric pressure provides a precise fumarole flowmeter. In addition, it is a tool to decipher shallow versus deep feeding of volcanic fumaroles that should prove useful for volcano monitoring. (1)Zimmer, M. & Erzinger, J. Continuous H2O, CO2, 222Rn and temperature measurements on Merapi Volcano, Indonesia. J. Volcanol. Geoth. Res. 125, 25-38 (2003).

  6. Artificial maturation of oil shale: The Irati Formation from the Parana Basin, Brazil

    NASA Astrophysics Data System (ADS)

    Gayer, James L.

    Oil shale samples from the Irati Formation in Brazil were evaluated from an outcrop block, denoted Block 003. The goals of this thesis include: 1) Characterizing the Irati Formation, 2) Comparing the effects of two different types of pyrolysis, anhydrous and hydrous, and 3) Utilizing a variety of geophysical experiments to determine the changes associated with each type of pyrolysis. Primary work included determining total organic carbon, source rock analysis, mineralogy, computer tomography x-ray scans, and scanning electron microscope images before and after pyrolysis, as well as acoustic properties of the samples during pyrolysis. Two types of pyrolysis (hydrous and anhydrous) were performed on samples cored at three different orientations (0°, 45°, and 90°) with respect to the axis of symmetry, requiring six total experiments. During pyrolysis, the overall effective pressure was maintained at 800 psi, and the holding temperature was 365°C. The changes and deformation in the hydrous pyrolysis samples were greater compared to the anhydrous pyrolysis. The velocities gave the best indication of changes occurring during pyrolysis, but it was difficult to maintain the same amplitude and quality of waveforms at higher temperatures. The velocity changes were due to a combination of factors, including thermal deformation of the samples, fracture porosity development, and the release of adsorbed water and bitumen from the sample. Anhydrous pyrolysis in this study did not reduce TOC, while TOC was reduced due to hydrous pyrolysis by 5%, and velocities in the hydrous pyrolysis decreased by up to 30% at 365°C compared to room temperature. Data from this study and future data that can be acquired with the improved high-temperature, high-pressure experiment will assist in future economic production from oil shale at lower temperatures under hydrous pyrolysis conditions.

  7. Results of tests on a Rockwell International space shuttle orbiter (-139 configuration) 0.0175-scale model (no. 29-0) in AEDC tunnel B to determine boundary layer characteristics

    NASA Technical Reports Server (NTRS)

    Quan, M.

    1975-01-01

    Results of wind tunnel tests were conducted to determine boundary layer characteristics on the lower surface of a space shuttle orbiter. Total pressure and temperature profile data at various model stations were obtained using a movable, four-degree-of-freedom probe mechanism and static pressure taps on the model surface. During a typical run, the probe was located over a preselected model location, then driven down through the bondary layer until contact was made with the model surface.

  8. Environmental Constraints in Earth-Space Propagaton.

    DTIC Science & Technology

    1980-11-20

    medium. The earth-space refractivity may be written N(s) - (n-l) x 106 - Nt + NJ 77.6 [p(s) + 81O e (s) 1 - 4o.28 x o-6 Ne(s) () T(s) [" T(s) f- 2 where...T(s) is the aIr temperature (OK), p(s) is the atmospheric pressure (mb), e (s) is the partial vapor pressure (mb , f is the radiofrequency (MHz), Ne is...to Predict the Total Atmospheric Bending of Radiowaves at Small Angles", Proc. IRE 45, 145-6. BEAN B. R. and R. E . MCGAVIN, 1965, "A Review of

  9. Design and cold-air test of single-stage uncooled turbine with high work output

    NASA Technical Reports Server (NTRS)

    Moffitt, T. P.; Szanca, E. M.; Whitney, W. J.; Behning, F. P.

    1980-01-01

    A solid version of a 50.8 cm single stage core turbine designed for high temperature was tested in cold air over a range of speed and pressure ratio. Design equivalent specific work was 76.84 J/g at an engine turbine tip speed of 579.1 m/sec. At design speed and pressure ratio, the total efficiency of the turbine was 88.6 percent, which is 0.6 point lower than the design value of 89.2 percent. The corresponding mass flow was 4.0 percent greater than design.

  10. Scale model performance test investigation of exhaust system mixers for an Energy Efficient Engine /E3/ propulsion system

    NASA Technical Reports Server (NTRS)

    Kuchar, A. P.; Chamberlin, R.

    1980-01-01

    A scale model performance test was conducted as part of the NASA Energy Efficient Engine (E3) Program, to investigate the geometric variables that influence the aerodynamic design of exhaust system mixers for high-bypass, mixed-flow engines. Mixer configuration variables included lobe number, penetration and perimeter, as well as several cutback mixer geometries. Mixing effectiveness and mixer pressure loss were determined using measured thrust and nozzle exit total pressure and temperature surveys. Results provide a data base to aid the analysis and design development of the E3 mixed-flow exhaust system.

  11. Operating Characteristics of the Multiple Critical Venturi System and Secondary Calibration Nozzles Used for Weight-Flow Measurements in the Langley 16-Foot Transonic Tunnel

    NASA Technical Reports Server (NTRS)

    Berrier, B. L.; Leavitt, L. D.; Bangert, L. S.

    1985-01-01

    An investigation has been conducted in the Langley 16 Foot Transonic Tunnel to determine the weight flow measurement characteristics of a multiple critical Venturi system and the nozzle discharge coefficient characteristics of a series of convergent calibration nozzles. The effects on model discharge coefficient of nozzle throat area, model choke plate open area, nozzle pressure ratio, jet total temperature, and number and combination of operating Venturis were investigated. Tests were conducted at static conditions (tunnel wind off) at nozzle pressure ratios from 1.3 to 7.0.

  12. Wake-shock interaction at a Mach number of 6

    NASA Technical Reports Server (NTRS)

    Walsh, M. J.

    1978-01-01

    Measurements of mean pitot pressure, static pressure, and total temperature were made in the two dimensional turbulent mixing region of a wake downstream of an interaction with a shock-expansion wave system. The results indicated that: (1) the shock increased the mixing, and (2) the expansion field that followed the shock decreased the turbulent mixing. The overall effect of the shock-expansion wave interaction was dependent on the orientation of the expansion wave with respect to the intersecting shock wave. These data could be used to validate nonequilibrium turbulence modeling and numerical solution of the time averaged Navier-Stokes equations.

  13. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Churchill, Randy M.; Canik, John M.; Chang, C. S.

    Simulations using the fully kinetic neoclassical code XGCa (X-point included guiding-center axisymmetric) were undertaken to explore the impact of kinetic effects on scrape-off layer (SOL) physics in DIII-D H-mode plasmas. XGCa is a total-f, gyrokinetic code which self-consistently calculates the axisymmetric electrostatic potential and plasma dynamics, and includes modules for Monte Carlo neutral transport. Previously presented XGCa results showed several noteworthy features, including large variations of ion density and pressure along field lines in the SOL, experimentally relevant levels of SOL parallel ion flow (Mach number similar to 0.5), skewed ion distributions near the sheath entrance leading to subsonic flowmore » there, and elevated sheath potentials (Churchill 2016 Nucl. Mater. Energy 1-6). In this paper, we explore in detail the question of pressure balance in the SOL, as it was observed in the simulation that there was a large deviation from a simple total pressure balance (the sum of ion and electron static pressure plus ion inertia). It will be shown that both the contributions from the ion viscosity (driven by ion temperature anisotropy) and neutral source terms can be substantial, and should be retained in the parallel momentum equation in the SOL, but still falls short of accounting for the observed fluid pressure imbalance in the XGCa simulation results.« less

  14. Hydraulic Diagnostic Monitoring System.

    DTIC Science & Technology

    1981-03-02

    devices were utilized. In one pneumatic circuit, a temperature-compensated pressure switch performed as predicted over a broad tempera- ture range. In...installation ...... ................. 41 9 NADC 81073-60 ILLUSTRATIONS (Cont) Fig. No. Page 28 Temperature-compensated pressure switch .... ................. .42...29 Plot of pressure vs temperature for nitrogen .... ................ .. 43 30 Temperature-compensated pressure switch : diagrammatic circuit

  15. 46 CFR 154.701 - Cargo pressure and temperature control: General.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Cargo pressure and temperature control: General. 154.701... CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Cargo Pressure and Temperature Control § 154.701 Cargo pressure and temperature control: General...

  16. 46 CFR 154.701 - Cargo pressure and temperature control: General.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Cargo pressure and temperature control: General. 154.701... CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Cargo Pressure and Temperature Control § 154.701 Cargo pressure and temperature control: General...

  17. 46 CFR 154.701 - Cargo pressure and temperature control: General.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Cargo pressure and temperature control: General. 154.701... CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Cargo Pressure and Temperature Control § 154.701 Cargo pressure and temperature control: General...

  18. 46 CFR 154.701 - Cargo pressure and temperature control: General.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo pressure and temperature control: General. 154.701... CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Cargo Pressure and Temperature Control § 154.701 Cargo pressure and temperature control: General...

  19. 46 CFR 154.701 - Cargo pressure and temperature control: General.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Cargo pressure and temperature control: General. 154.701... CARGOES SAFETY STANDARDS FOR SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Cargo Pressure and Temperature Control § 154.701 Cargo pressure and temperature control: General...

  20. CO2-H2O based pretreatment and enzyme hydrolysis of soybean hulls.

    PubMed

    Islam, S M Mahfuzul; Li, Qian; Loman, Abdullah Al; Ju, Lu-Kwang

    2017-11-01

    The high carbohydrate content of soybean hull makes it an attractive biorefinery resource. But hydrolyzing its complex structure requires concerted enzyme activities, at least cellulase, xylanase, pectinase and α-galactosidase. Effective pretreatment that generates minimal inhibitory products is important to facilitate enzymatic hydrolysis. Combined CO 2 -H 2 O pretreatment and enzymatic hydrolysis by Aspergillus niger and Trichoderma reesei enzyme broths was studied here. The pretreatment was evaluated at 80°C-180°C temperature and 750psi-1800psi pressure, with fixed moisture content (66.7%) and pretreatment time (30min). Ground hulls without and with different pretreatments were hydrolyzed by enzyme at 50°C and pH 4.8 and compared for glucose, xylose, galactose, arabinose, mannose and total reducing sugar release. CO 2 -H 2 O pretreatment at 1250psi and 130°C was found to be optimal. Compared to the unpretreated hulls hydrolyzed with 2.5-fold more enzyme, this pretreatment improved glucose, xylose, galactose, arabinose and mannose releases by 55%, 35%, 105%, 683% and 52%, respectively. Conversions of 97% for glucose, 98% for xylose, 41% for galactose, 59% for arabinose, 87% for mannose and 89% for total reducing sugar were achieved with Spezyme CP at 18FPU/g hull. Monomerization of all carbohydrate types was demonstrated. At the optimum pretreatment condition, generation of inhibitors acetic acid, furfural and hydroxymethylfurfural (HMF) was negligible, 1.5mg/g hull in total. The results confirmed the effective CO 2 -H 2 O pretreatment of soybean hulls at much lower pressure and temperature than those reported for biomass of higher lignin contents. The lower pressure requirement reduces the reactor cost and makes this new pretreatment method more practical and economical. Copyright © 2017 Elsevier Inc. All rights reserved.

  1. Low-pressure oxidation of Cb-1Zr alloy.

    NASA Technical Reports Server (NTRS)

    Lyon, T. F.

    1971-01-01

    Resistively heated strip specimens of Cb-1Zr alloy were exposed at 927 C in a vacuum chamber at various levels of total pressure in the 1-microtorr range and at various oxygen partial pressures in the .1-microtorr range. Oxygen reaction rates (sticking probabilities) were found to depend on whether or not the specimens were annealed immediately before the test exposure. It is shown that a normally undetectable oxide film exists on the Cb-1Zr surface as a result of oxidation by ambient air, and this film reduces the sticking probability as compared with a clean metal surface. The alloy is considerably strengthened by addition of oxygen to a level of about 6000 ppm, while still maintaining reasonably good room temperature ductility.

  2. The effects of compressor seventh-stage bleed air extraction on performance of the F100-PW-220 afterburning turbofan engine

    NASA Technical Reports Server (NTRS)

    Evans, Alison B.

    1991-01-01

    A study was conducted to determine the effects of seventh-stage compressor bleed on the performance of the F100 afterburning turbofan engine. The effects of bleed on thrust, specific fuel consumption, fan turbine inlet temperature, bleed total pressure, and bleed total temperature were obtained from the engine manufacturer's status deck computer simulation. These effects were determined for power settings of intermediate, partial afterburning, and maximum afterburning for Mach numbers between 0.6 and 2.2 and for altitudes of 30,000, 40,000, and 50,000 ft. It was found that thrust loss and specific fuel consumption increase were approximately linear functions of bleed flow and, based on a percent-thrust change basis, were approximately independent of power setting.

  3. Three dimensional investigation of the shock train structure in a convergent-divergent nozzle

    NASA Astrophysics Data System (ADS)

    Mousavi, Seyed Mahmood; Roohi, Ehsan

    2014-12-01

    Three-dimensional computational fluid dynamics analyses have been employed to study the compressible and turbulent flow of the shock train in a convergent-divergent nozzle. The primary goal is to determine the behavior, location, and number of shocks. In this context, full multi-grid initialization, Reynolds stress turbulence model (RSM), and the grid adaption techniques in the Fluent software are utilized under the 3D investigation. The results showed that RSM solution matches with the experimental data suitably. The effects of applying heat generation sources and changing inlet flow total temperature have been investigated. Our simulations showed that changes in the heat generation rate and total temperature of the intake flow influence on the starting point of shock, shock strength, minimum pressure, as well as the maximum flow Mach number.

  4. Analysis of the temperature and pressure dependence of the 129Xe NMR chemical shift and signal intensity for the derivation of basic parameters of adsorption as applied to zeolite ZSM-5.

    PubMed

    Kawata, Yoko; Adachi, Yuko; Haga, Saori; Fukutomi, Junko; Imai, Hirohiko; Kimura, Atsuomi; Fujiwara, Hideaki

    2007-12-01

    Temperature and pressure dependences of the 129Xe NMR chemical shift and the signal intensity have been investigated using ZSM-5 as an adsorbent under routine conditions without using any high-pressure or especially high-temperature facilities. The use of a rigorously shielded system and a calibration sample for the signal intensity was found to be valuable to obtain reliable data about the chemical shift and the signal intensity. The 129Xe NMR data obtained between 0.05 and 1.5 atm and from 24 to 80 degrees C were analyzed based on the Dubinin-Radushkevich equation as well as the Langmuir type equation. In both analyses, chemical shift data succeeded only partially in providing the profile of adsorption, such as energetic aspects, surface area, saturated amount of Xe adsorption and specific parameters of 129Xe chemical shift. It was shown that the reliable total analysis was achieved when the chemical shift data were used together with the intensity data. Such an analysis of the chemical shift data, aided by the intensity data, will be useful in performing nano-material analysis on 129Xe NMR without invoking the traditional methodology of gravimetric or volumetric adsorption experiments.

  5. Transformations of fluxes and forces describing the simultaneous transport of water and heat in unsaturated porous media

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Raats, P.A.C.

    1975-12-01

    Balances of mass for the water in N distinct phases and a balance of heat for the medium as a whole were formulated. Following Philip and de Vries, it was assumed that the flux of water in each phase is proportional to the gradient of the pressure in that phase and that the diffusive component of the flux of heat is proportional to the gradient of the temperature. Clapeyron equations were used to express the gradient of the pressure in any phase in terms of the gradient of the pressure in a reference state and of the temperature. The referencemore » state may be the water in one of the phases or the water in some measuring device such as a tensiometer or a psychrometer. Expressions for the total flux of water and for the diffusive flux of heat plus the convective flux of heat associated with the conversion from any phase to the reference state were shown to satisfy the onsager reciprocal relations. A theorem due to Meixner was used to delineate the class of fluxes and forces that preserves these relations. In particular, it was shown that if the gradients of water content and temperature are used as the driving forces, the onsager relations are no longer satisfied.« less

  6. CO2 sequestration by mineral carbonation of steel slags under ambient temperature: parameters influence, and optimization.

    PubMed

    Ghacham, Alia Ben; Pasquier, Louis-César; Cecchi, Emmanuelle; Blais, Jean-François; Mercier, Guy

    2016-09-01

    This work focuses on the influence of different parameters on the efficiency of steel slag carbonation in slurry phase under ambient temperature. In the first part, a response surface methodology was used to identify the effect and the interactions of the gas pressure, liquid/solid (L/S) ratio, gas/liquid ratio (G/L), and reaction time on the CO2 removed/sample and to optimize the parameters. In the second part, the parameters' effect on the dissolution of CO2 and its conversion into carbonates were studied more in detail. The results show that the pressure and the G/L ratio have a positive effect on both the dissolution and the conversion of CO2. These results have been correlated with the higher CO2 mass introduced in the reactor. On the other hand, an important effect of the L/S ratio on the overall CO2 removal and more specifically on the carbonate precipitation has been identified. The best results were obtained L/S ratios of 4:1 and 10:1 with respectively 0.046 and 0.052 gCO2 carbonated/g sample. These yields were achieved after 10 min reaction, at ambient temperature, and 10.68 bar of total gas pressure following direct gas treatment.

  7. Carbon nanotube temperature and pressure sensors

    DOEpatents

    Ivanov, Ilia N.; Geohegan, David B.

    2016-11-15

    The present invention, in one embodiment, provides a method of measuring pressure or temperature using a sensor including a sensor element composed of a plurality of carbon nanotubes. In one example, the resistance of the plurality of carbon nanotubes is measured in response to the application of temperature or pressure. The changes in resistance are then recorded and correlated to temperature or pressure. In one embodiment, the present invention provides for independent measurement of pressure or temperature using the sensors disclosed herein.

  8. Carbon nanotube temperature and pressure sensors

    DOEpatents

    Ivanov, Ilia N.; Geohegan, David B.

    2016-12-13

    The present invention, in one embodiment, provides a method of measuring pressure or temperature using a sensor including a sensor element composed of a plurality of carbon nanotubes. In one example, the resistance of the plurality of carbon nanotubes is measured in response to the application of temperature or pressure. The changes in resistance are then recorded and correlated to temperature or pressure. In one embodiment, the present invention provides for independent measurement of pressure or temperature using the sensors disclosed herein.

  9. Carbon nanotube temperature and pressure sensors

    DOEpatents

    Ivanov, Ilia N; Geohegan, David Bruce

    2013-10-29

    The present invention, in one embodiment, provides a method of measuring pressure or temperature using a sensor including a sensor element composed of a plurality of carbon nanotubes. In one example, the resistance of the plurality of carbon nanotubes is measured in response to the application of temperature or pressure. The changes in resistance are then recorded and correlated to temperature or pressure. In one embodiment, the present invention provides for independent measurement of pressure or temperature using the sensors disclosed herein.

  10. Carbon nanotube temperature and pressure sensors

    DOEpatents

    Ivanov, Ilia N.; Geohegan, David B.

    2016-10-25

    The present invention, in one embodiment, provides a method of measuring pressure or temperature using a sensor including a sensor element composed of a plurality of carbon nanotubes. In one example, the resistance of the plurality of carbon nanotubes is measured in response to the application of temperature or pressure. The changes in resistance are then recorded and correlated to temperature or pressure. In one embodiment, the present invention provides for independent measurement of pressure or temperature using the sensors disclosed herein.

  11. Carbon nanotube temperature and pressure sensors

    DOEpatents

    Ivanov, Ilia N.; Geohegan, David B.

    2017-09-12

    The present invention, in one embodiment, provides a method of measuring pressure or temperature using a sensor including a sensor element composed of a plurality of carbon nanotubes. In one example, the resistance of the plurality of carbon nanotubes is measured in response to the application of temperature or pressure. The changes in resistance are then recorded and correlated to temperature or pressure. In one embodiment, the present invention provides for independent measurement of pressure or temperature using the sensors disclosed herein.

  12. Performance of high-area-ratio annular dump diffuser using suction-stabilized-vortex flow control

    NASA Technical Reports Server (NTRS)

    Juhasz, A. J.; Smith, J. M.

    1977-01-01

    A short annular dump diffuser having a geometry conductive to formation of suction stabilized toroidal vortices in the region of abrupt area change was tested. The overall diffuser area ratio was 4.0 and the length to inlet height ratio was 2.0. Performance data were obtained at near ambient temperature and pressure for inlet Mach numbers of 0.18 and 0.30 with suction rates ranging from 0 to 18 percent of total inlet mass flowrate. Results show that the exit velocity profile could be readily biased toward either wall by adjustment of inner and outer wall suction rates. Symmetric exit velocity profiles were inherently unstable with a tendency to revert to a hub or tip bias. Diffuser effectiveness was increased from about 38 percent without suction to over 85 percent at a total suction rate of 10 to 12 percent. At the same time diffuser total pressure loss was reduced from 3.1 percent to 1.1 percent at an inlet Mach number of 0.3.

  13. Thermal properties and phase transition in the fluoride, (NH{sub 4}){sub 3}SnF{sub 7}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kartashev, A.V.; Astafijev Krasnoyarsk State Pedagogical University, 660049 Krasnoyarsk; Gorev, M.V.

    2016-05-15

    Calorimetric, dilatometric and differential thermal analysis studies were performed on (NH{sub 4}){sub 3}SnF{sub 7} for a wide range of temperatures and pressures. Large entropy (δS{sub 0}=22 J/mol K) and elastic deformation (δ(ΔV/V){sub 0}=0.89%) jumps have proven that the Pa-3↔Pm-3m phase transition is a strong first order structural transformation. A total entropy change of ΔS{sub 0}=32.5 J/mol K is characteristic for the order–disorder phase transition, and is equal to the sum of entropy changes in the related material, (NH{sub 4}){sub 3}TiF{sub 7}, undergoing transformation between the two cubic phases through the intermediate phases. Hydrostatic pressure decreases the stability of the highmore » temperature Pm-3m phase in (NH{sub 4}){sub 3}SnF{sub 7}, contrary to (NH{sub 4}){sub 3}TiF{sub 7}, characterised by a negative baric coefficient. The effect of experimental conditions on the chemical stability of (NH{sub 4}){sub 3}SnF{sub 7} was observed. - Graphical abstract: Strong first order structural transformation Pa-3↔Pm-3m in (NH{sub 4}){sub 3}SnF{sub 7} is associated with very large total entropy change of ΔS{sub 0}=32.5 J/mol K characteristic for the ordering processes and equal to the sum of entropy changes in the related (NH{sub 4}){sub 3}TiF{sub 7} undergoing transformation between the same two cubic phases through the intermediate phases. - Highlights: • (NH{sub 4}){sub 3}SnF{sub 7} undergoes strong first order Pa-3↔Pm-3m phase transition. • Anomalous behaviour of ΔC{sub p} and ΔV/V exists far below phase transition temperature. • Structural distortions are accompanied by huge total entropy change ΔS≈Rln50. • High pressure strongly increases the stability of Pa-3 phase in (NH{sub 4}){sub 3}SnF{sub 7}. • Entropy of the Pa-3↔Pm-3m phase transition does not depend on pressure.« less

  14. Passive Resistor Temperature Compensation for a High-Temperature Piezoresistive Pressure Sensor.

    PubMed

    Yao, Zong; Liang, Ting; Jia, Pinggang; Hong, Yingping; Qi, Lei; Lei, Cheng; Zhang, Bin; Li, Wangwang; Zhang, Diya; Xiong, Jijun

    2016-07-22

    The main limitation of high-temperature piezoresistive pressure sensors is the variation of output voltage with operating temperature, which seriously reduces their measurement accuracy. This paper presents a passive resistor temperature compensation technique whose parameters are calculated using differential equations. Unlike traditional experiential arithmetic, the differential equations are independent of the parameter deviation among the piezoresistors of the microelectromechanical pressure sensor and the residual stress caused by the fabrication process or a mismatch in the thermal expansion coefficients. The differential equations are solved using calibration data from uncompensated high-temperature piezoresistive pressure sensors. Tests conducted on the calibrated equipment at various temperatures and pressures show that the passive resistor temperature compensation produces a remarkable effect. Additionally, a high-temperature signal-conditioning circuit is used to improve the output sensitivity of the sensor, which can be reduced by the temperature compensation. Compared to traditional experiential arithmetic, the proposed passive resistor temperature compensation technique exhibits less temperature drift and is expected to be highly applicable for pressure measurements in harsh environments with large temperature variations.

  15. Passive Resistor Temperature Compensation for a High-Temperature Piezoresistive Pressure Sensor

    PubMed Central

    Yao, Zong; Liang, Ting; Jia, Pinggang; Hong, Yingping; Qi, Lei; Lei, Cheng; Zhang, Bin; Li, Wangwang; Zhang, Diya; Xiong, Jijun

    2016-01-01

    The main limitation of high-temperature piezoresistive pressure sensors is the variation of output voltage with operating temperature, which seriously reduces their measurement accuracy. This paper presents a passive resistor temperature compensation technique whose parameters are calculated using differential equations. Unlike traditional experiential arithmetic, the differential equations are independent of the parameter deviation among the piezoresistors of the microelectromechanical pressure sensor and the residual stress caused by the fabrication process or a mismatch in the thermal expansion coefficients. The differential equations are solved using calibration data from uncompensated high-temperature piezoresistive pressure sensors. Tests conducted on the calibrated equipment at various temperatures and pressures show that the passive resistor temperature compensation produces a remarkable effect. Additionally, a high-temperature signal-conditioning circuit is used to improve the output sensitivity of the sensor, which can be reduced by the temperature compensation. Compared to traditional experiential arithmetic, the proposed passive resistor temperature compensation technique exhibits less temperature drift and is expected to be highly applicable for pressure measurements in harsh environments with large temperature variations. PMID:27455271

  16. 40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... monitor and record the fuel consumption and the ratio of water or steam to fuel being fired in the turbine... continuous emission monitoring system (CEMS) consisting of a NOX monitor and a diluent gas (oxygen (O2) or... rate, temperature, and pressure, to continuously measure the total thermal energy output in British...

  17. 40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... monitor and record the fuel consumption and the ratio of water or steam to fuel being fired in the turbine... continuous emission monitoring system (CEMS) consisting of a NOX monitor and a diluent gas (oxygen (O2) or... rate, temperature, and pressure, to continuously measure the total thermal energy output in British...

  18. 40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... monitor and record the fuel consumption and the ratio of water or steam to fuel being fired in the turbine... continuous emission monitoring system (CEMS) consisting of a NOX monitor and a diluent gas (oxygen (O2) or... rate, temperature, and pressure, to continuously measure the total thermal energy output in British...

  19. 40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... monitor and record the fuel consumption and the ratio of water or steam to fuel being fired in the turbine... continuous emission monitoring system (CEMS) consisting of a NOX monitor and a diluent gas (oxygen (O2) or... rate, temperature, and pressure, to continuously measure the total thermal energy output in British...

  20. 40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... monitor and record the fuel consumption and the ratio of water or steam to fuel being fired in the turbine... continuous emission monitoring system (CEMS) consisting of a NOX monitor and a diluent gas (oxygen (O2) or... rate, temperature, and pressure, to continuously measure the total thermal energy output in British...

  1. Nonlinear synthesis of infrasound propagation through an inhomogeneous, absorbing atmosphere.

    PubMed

    de Groot-Hedlin, C D

    2012-08-01

    An accurate and efficient method to predict infrasound amplitudes from large explosions in the atmosphere is required for diverse source types, including bolides, volcanic eruptions, and nuclear and chemical explosions. A finite-difference, time-domain approach is developed to solve a set of nonlinear fluid dynamic equations for total pressure, temperature, and density fields rather than acoustic perturbations. Three key features for the purpose of synthesizing nonlinear infrasound propagation in realistic media are that it includes gravitational terms, it allows for acoustic absorption, including molecular vibration losses at frequencies well below the molecular vibration frequencies, and the environmental models are constrained to have axial symmetry, allowing a three-dimensional simulation to be reduced to two dimensions. Numerical experiments are performed to assess the algorithm's accuracy and the effect of source amplitudes and atmospheric variability on infrasound waveforms and shock formation. Results show that infrasound waveforms steepen and their associated spectra are shifted to higher frequencies for nonlinear sources, leading to enhanced infrasound attenuation. Results also indicate that nonlinear infrasound amplitudes depend strongly on atmospheric temperature and pressure variations. The solution for total field variables and insertion of gravitational terms also allows for the computation of other disturbances generated by explosions, including gravity waves.

  2. Experimental evaluation of two premixing-prevaporizing fuel injection concepts for a gas turbine catalytic combustor

    NASA Technical Reports Server (NTRS)

    Tacina, R.

    1976-01-01

    A premixing-prevaporizing fuel system to be used with a catalytic combustor was evaluated for possible application in an automotive gas turbine. Spatial fuel distribution and degree of vaporization were measured using jet A fuel. Two types of air blast injectors were tested, a splash groove injector and a multiple jet cross stream injector. Air swirlers with vane angles of 15 deg and 30 deg were used to improve the spatial fuel distribution in a 12 cm diameter tubular rig. Distribution and vaporization measurements were made 35.5 cm downstream of the injector. The spatial fuel distribution was nearly uniform with the multiple jet contrastream injector and the splash-groove injector with a 30 deg air swirler. The vaporization was nearly 100 percent at an inlet air temperature of 600 K, and at 800 K inlet air temperature fuel oxidation reactions were observed. The total pressure loss was less than 0.5 percent of the total pressure for the multiple jet cross stream injector and the splash groove injector (without air swirler) and less than 1 percent for the splash groove with a 30 deg air swirler.

  3. HEAT TRANSFER FROM SURFACES OF NON-UNIFORM TEMPERATURE DISTRIBUTION. PART II. TURBULENT TRANSFER FROM ISOTHERMAL SPANWISE STRIPS ON A FLAT PLATE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sogin, H.H.; Goldstein, R.J.

    1960-02-01

    Experiments were performed on mass transfer by forced convection from naphthalene strips on a flat plate to an air stream at ordinary temperature and pressure. Turbulence was induced in the boundary layer by means of a wire strip. In all cases there was a hydrodynamic starting length upstream of the strips. The ratio of this inert length to the total length was varied from about 0.80 to 0.96. The flow was practically incompressible with Reynolds number, based on the total length, varying from 175,000 to 486,000. The Schmidt number was 2.5. The experimental results fell in proximity to the Sebanmore » step function factor when they were reduced after the massmomentum analysis of Deissler and Loeffler for a surface of uniform vapor pressure. When Karman's formulation of the mass- momentum analogy was assumed, the data fell between the values predicted by the Seban and by the Rubesin expression for the step function factor. The results were well correlated by the Colburn analogy in conjunction with the Rubesin step function factor. (auth)« less

  4. Treatment method for emulsified petroleum wastes

    DOEpatents

    Sealock, Jr., L. John; Baker, Eddie G.; Elliott, Douglas C.

    1990-01-01

    An improved reclamation process for treating petroleum oil and water emulsions derived from producing or processing crude oil is disclosed. The process comprises heating the emulsion to a predetermined temperature at or above about 300.degree. C. and pressurizing the emulsion to a predetermined pressure above the vapor pressure of water at the predetermined temperature. The emulsion is broken by containing the heated and pressurized fluid within a vessel at the predetermined temperature and pressure for a predetermined period of time to effectively separate the emulsion into substantially distinct first, second and third phases. The three phases are then separately withdrawn from the vessel, preferably without any appreciable reduction in temperature and pressure, and at least above a withdraw temperature of about 300.degree. and above the vapor pressure of water at the withdraw temperature.

  5. Cryogenic wind tunnels: Unique capabilities for the aerodynamicist

    NASA Technical Reports Server (NTRS)

    Hall, R. M.

    1976-01-01

    The cryogenic wind-tunnel concept as a practical means for improving ground simulation of transonic flight conditions. The Langley 1/3-meter transonic cryogenic tunnel is operational, and the design of a cryogenic National Transonic Facility is undertaken. A review of some of the unique capabilities of cryogenic wind tunnels is presented. In particular, the advantages of having independent control of tunnel Mach number, total pressure, and total temperature are highlighted. This separate control over the three tunnel parameters will open new frontiers in Mach number, Reynolds number, aeroelastic, and model-tunnel interaction studies.

  6. Structural and magnetic phase transitions in gadolinium under high pressures and low temperatures

    NASA Astrophysics Data System (ADS)

    Samudrala, Gopi K.; Tsoi, Georgiy M.; Weir, Samuel T.; Vohra, Yogesh K.

    2014-10-01

    High pressure structural transition studies have been carried out on rare earth metal gadolinium in a diamond anvil cell at room temperature to 169 GPa. Gadolinium has been compressed to 38% of its initial volume at this pressure. With increasing pressure, a crystal structure sequence of hcp → Sm-type → dhcp → fcc → dfcc → monoclinic has been observed in our studies on gadolinium. The measured equation of state of gadolinium is presented to 169 GPa at ambient temperature. Magnetic ordering temperature of gadolinium has been studied using designer diamond anvils to a pressure of 25 GPa and a temperature of 10 K. The magnetic ordering temperature has been determined from the four-point electrical resistivity measurements carried out on gadolinium. Our experiments show that the magnetic transition temperature decreases with increasing pressure to 19 GPa and then increases when gadolinium is subjected to higher pressures.

  7. Raman scattering of 2H-MoS2 at simultaneous high temperature and high pressure (up to 600 K and 18.5 GPa)

    NASA Astrophysics Data System (ADS)

    Jiang, JianJun; Li, HePing; Dai, LiDong; Hu, HaiYing; Zhao, ChaoShuai

    2016-03-01

    The Raman spectroscopy of natural molybdenite powder was investigated at simultaneous conditions of high temperature and high pressure in a heatable diamond anvil cell (DAC), to obtain the temperature and pressure dependence of the main Raman vibrational modes (E1g, E2 g 1 ,A1g, and 2LA(M)). Over our experimental temperature and pressure range (300-600 K and 1 atm-18.5 GPa), the Raman modes follow a systematic blue shift with increasing pressure, and red shift with increasing temperature. The results were calculated by three-variable linear fitting. The mutual correlation index of temperature and pressure indicates that the pressure may reduce the temperature dependence of Raman modes. New Raman bands due to structural changes emerged at about 3-4 GPa lower than seen in previous studies; this may be caused by differences in the pressure hydrostaticity and shear stress in the sample cell that promote the interlayer sliding.

  8. Flexible and self-powered temperature-pressure dual-parameter sensors using microstructure-frame-supported organic thermoelectric materials.

    PubMed

    Zhang, Fengjiao; Zang, Yaping; Huang, Dazhen; Di, Chong-an; Zhu, Daoben

    2015-09-21

    Skin-like temperature- and pressure-sensing capabilities are essential features for the next generation of artificial intelligent products. Previous studies of e-skin and smart elements have focused on flexible pressure sensors, whereas the simultaneous and sensitive detection of temperature and pressure with a single device remains a challenge. Here we report developing flexible dual-parameter temperature-pressure sensors based on microstructure-frame-supported organic thermoelectric (MFSOTE) materials. The effective transduction of temperature and pressure stimuli into two independent electrical signals permits the instantaneous sensing of temperature and pressure with an accurate temperature resolution of <0.1 K and a high-pressure-sensing sensitivity of up to 28.9 kPa(-1). More importantly, these dual-parameter sensors can be self-powered with outstanding sensing performance. The excellent sensing properties of MFSOTE-based devices, together with their unique advantages of low cost and large-area fabrication, make MFSOTE materials possess promising applications in e-skin and health-monitoring elements.

  9. Flexible and self-powered temperature-pressure dual-parameter sensors using microstructure-frame-supported organic thermoelectric materials

    NASA Astrophysics Data System (ADS)

    Zhang, Fengjiao; Zang, Yaping; Huang, Dazhen; di, Chong-An; Zhu, Daoben

    2015-09-01

    Skin-like temperature- and pressure-sensing capabilities are essential features for the next generation of artificial intelligent products. Previous studies of e-skin and smart elements have focused on flexible pressure sensors, whereas the simultaneous and sensitive detection of temperature and pressure with a single device remains a challenge. Here we report developing flexible dual-parameter temperature-pressure sensors based on microstructure-frame-supported organic thermoelectric (MFSOTE) materials. The effective transduction of temperature and pressure stimuli into two independent electrical signals permits the instantaneous sensing of temperature and pressure with an accurate temperature resolution of <0.1 K and a high-pressure-sensing sensitivity of up to 28.9 kPa-1. More importantly, these dual-parameter sensors can be self-powered with outstanding sensing performance. The excellent sensing properties of MFSOTE-based devices, together with their unique advantages of low cost and large-area fabrication, make MFSOTE materials possess promising applications in e-skin and health-monitoring elements.

  10. Design of a high-pressure circulating pump for viscous liquids.

    PubMed

    Seifried, Bernhard; Temelli, Feral

    2009-07-01

    The design of a reciprocating dual action piston pump capable of circulating viscous fluids at pressures of up to 34 MPa (5000 psi) and temperatures up to 80 degrees C is described. The piston of this pump is driven by a pair of solenoids energized alternatively by a 12 V direct current power supply controlled by an electronic controller facilitating continuously adjustable flow rates. The body of this seal-less pump is constructed using off-the-shelf parts eliminating the need for custom made parts. Both the electronic controller and the pump can be assembled relatively easily. Pump performance has been evaluated at room temperature (22 degrees C) and atmospheric pressure using liquids with low and moderately high viscosities, such as ethanol and corn oil, respectively. At ambient conditions, the pump delivered continuous flow of ethanol and corn oil at a flow rate of up to 170 and 17 cm3/min, respectively. For pumping viscous fluids comparable to corn oil, an optimum reciprocation frequency was ascertained to maximize flow rate. For low viscosity liquids such as ethanol, a linear relationship between the flow rate and reciprocation frequency was determined up to the maximum reciprocation frequency of the pump. Since its fabrication, the pump has been used in our laboratory for circulating triglycerides in contact with supercritical carbon dioxide at pressures of up to 25 MPa (3600 psi) and temperatures up to 70 degrees C on a daily basis for a total of more than 1500 h of operation functioning trouble free.

  11. Synchrotron x-ray high energy PDF and tomography studies for gallium melts under high-pressure conditions

    NASA Astrophysics Data System (ADS)

    Liu, H.; Liu, L. L.; Li, R.; Li, L.

    2015-12-01

    Liquid gallium exhibits unusual and unique physical properties. A rich polymorphism and metastable modifications of solid Ga have been discovered and a number of studies of liquid gallium under high pressure conditions were reported. However, some fundamental properties, such as the equation of state (EoS) of Ga melt under extreme conditions remain unclear. To compare to the previous reports, we performed the pair distribution function (PDF) study using diamond anvil cell, in which synchrotron high-energy x-ray total scattering data, combined with reverse Monte Carlo simulation, was used to study the microstructure and EoS of liquid gallium under high pressure at room temperature conditions. The EoS of Ga melt, which was measured from synchrotron x-ray tomography method at room temperature, was used to avoid the potential relatively big errors for the density estimation from the reverse Monte Carlo simulation with the mathematical fit to the measured structure factor data. The volume change of liquid gallium have been studied as a function of pressure and temperature up to 5 GPa at 370 K using synchrotron x-ray microtomography combined with energy dispersive x-ray diffraction (EDXRD) techniques using Drickamer press. The directly measured P-V-T curves were obtained from 3D tomography reconstruction data. The existence of possible liquid-liquid phase transition regions is proposed based on the abnormal compressibility and local structure change in Ga melts.

  12. Pressure in isochoric systems containing aqueous solutions at subzero Centigrade temperatures

    PubMed Central

    Șerban, Alexandru; Rubinsky, Boris

    2017-01-01

    Objective Preservation of biological materials at subzero Centigrade temperatures, cryopreservation, is important for the field of tissue engineering and organ transplantation. Our group is studying the use of isochoric (constant volume) systems of aqueous solution for cryopreservation. Previous studies measured the pressure-temperature relations in aqueous isochoric systems in the temperature range from 0°C to – 20°C. The goal of this study is to expand the pressure-temperature measurement beyond the range reported in previous publications. Materials and methods To expand the pressure-temperature measurements beyond the previous range, we have developed a new isochoric device capable of withstanding liquid nitrogen temperatures and pressures of up to 413 MPa. The device is instrumented with a pressure transducer than can monitor and record the pressures in the isochoric chamber in real time. Measurements were made in a temperature range from – 5°C to liquid nitrogen temperatures for various solutions of pure water and Me2SO (a chemical additive used for protection of biological materials in a frozen state and for vitrification (glass formation) of biological matter). Undissolved gaseous are is carefully removed from the system. Results Temperature-pressure data from – 5°C to liquid nitrogen temperature for pure water and other solutions are presented in this study. Following are examples of some, temperature-pressure values, that were measured in an isochoric system containing pure water: (- 20°C, 187 MPa); (-25°C, 216 MPa); (- 30°C, 242.3 MPa); (-180°C, 124 MPa). The data is consistent with the literature, which reports that the pressure and temperature at the triple point, between ice I, ice III and water is, - 21.993°C and 209.9 MPa, respectively. It was surprising to find that the pressure in the isochoric system increases at temperatures below the triple point and remains high to liquid nitrogen temperatures. Measurements of pressure-temperature relations in solutions of pure water and Me2SO in different concentrations show that, for concentrations in which vitrification is predicted, no increase in pressure was measured during rapid cooling to liquid nitrogen temperatures. However, ice formation either during cooling or warming to and from liquid nitrogen temperatures produced an increase in pressure. Conclusions The data obtained in this study can be used to aid in the design of isochoric cryopreservation protocols. The results suggest that the pressure measurement is important in the design of “constant volume” systems and can provide a simple means to gain information on the occurrence of vitrification and devitrification during cryopreservation processes of aqueous solutions in an isochoric system. PMID:28817681

  13. Diaphragm-Free Fiber-Optic Fabry-Perot Interferometric Gas Pressure Sensor for High Temperature Application.

    PubMed

    Liang, Hao; Jia, Pinggang; Liu, Jia; Fang, Guocheng; Li, Zhe; Hong, Yingping; Liang, Ting; Xiong, Jijun

    2018-03-28

    A diaphragm-free fiber-optic Fabry-Perot (FP) interferometric gas pressure sensor is designed and experimentally verified in this paper. The FP cavity was fabricated by inserting a well-cut fiber Bragg grating (FBG) and hollow silica tube (HST) from both sides into a silica casing. The FP cavity length between the ends of the SMF and HST changes with the gas density. Using temperature decoupling method to improve the accuracy of the pressure sensor in high temperature environments. An experimental system for measuring the pressure under different temperatures was established to verify the performance of the sensor. The pressure sensitivity of the FP gas pressure sensor is 4.28 nm/MPa with a high linear pressure response over the range of 0.1-0.7 MPa, and the temperature sensitivity is 14.8 pm/°C under the range of 20-800 °C. The sensor has less than 1.5% non-linearity at different temperatures by using temperature decoupling method. The simple fabrication and low-cost will help sensor to maintain the excellent features required by pressure measurement in high temperature applications.

  14. Cross spectra between pressure and temperature in a constant-area duct downstream of a hydrogen-fueled combustor

    NASA Technical Reports Server (NTRS)

    Miles, J. H.; Wasserbauer, C. A.; Krejsa, E. A.

    1983-01-01

    Pressure temperature cross spectra are necessary in predicting noise propagation in regions of velocity gradients downstream of combustors if the effect of convective entropy disturbances is included. Pressure temperature cross spectra and coherences were measured at spatially separated points in a combustion rig fueled with hydrogen. Temperature-temperature and pressure-pressure cross spectra and coherences between the spatially separated points as well as temperature and pressure autospectra were measured. These test results were compared with previous results obtained in the same combustion rig using Jet A fuel in order to investigate their dependence on the type of combustion process. The phase relationships are not consistent with a simple source model that assumes that pressure and temperature are in phase at a point in the combustor and at all other points downstream are related to one another by only a time delay due to convection of temperature disturbances. Thus these test results indicate that a more complex model of the source is required.

  15. Pressurized hot water extraction (PHWE) for the green recovery of bioactive compounds and steviol glycosides from Stevia rebaudiana Bertoni leaves.

    PubMed

    Bursać Kovačević, Danijela; Barba, Francisco J; Granato, Daniel; Galanakis, Charis M; Herceg, Zoran; Dragović-Uzelac, Verica; Putnik, Predrag

    2018-07-15

    Stevia rebaudiana Bertoni leaves are a natural source of diterpenic glycosides, and various bioactive compounds. The objectives were to characterize antioxidants and steviol glycosides in the extracts obtained from Stevia after "green" pressurized hot water extraction (PHWE). PHWE extracts were obtained at different temperatures (100, 130, 160 °C); static extraction times (5 and 10 min), and cycle numbers (1, 2, 3) using a constant pressure of 10.34 MPa. Temperature was the most important parameter for extraction, where the highest recoveries of all bioactive compounds (except for carotenoids) were at 160 °C. Extracts obtained at longer static times had more steviol glycosides, condensed tannins, and chlorophyll A. Higher amounts of total phenols, condensed tannins, and steviol glycosides were obtained under higher cycle numbers. This study indicated that PHWE is useful for recovering polar and nonpolar antioxidants and steviol glycosides. PHWE may be a suitable technique for scale-up to industrial applications. Copyright © 2018 Elsevier Ltd. All rights reserved.

  16. First-principles study of the structural, electronic and thermal properties of CaLiF3

    NASA Astrophysics Data System (ADS)

    Chouit, N.; Amara Korba, S.; Slimani, M.; Meradji, H.; Ghemid, S.; Khenata, R.

    2013-09-01

    Density functional theory calculations have been performed to study the structural, electronic and optical properties of CaLiF3 cubic fluoroperovskite. Our calculations were carried out by means of the full-potential linearized augmented plane-wave method. The exchange-correlation potential is treated by the local density approximation and the generalized gradient approximation (GGA) (Perdew, Burke and Ernzerhof). Moreover, the alternative form of GGA proposed by Engel and Vosko is also used for band structure calculations. The calculated total energy versus volume allows us to obtain structural properties such as the lattice constant (a0), bulk modulus (B0) and pressure derivative of the bulk modulus (B'0 ). Band structure, density of states and band gap pressure coefficients are also given. Our calculations show that CaLiF3 has an indirect band gap (R-Γ). Following the quasi-harmonic Debye model, in which the phononic effects are considered, the temperature and pressure effects on the lattice constant, bulk modulus, thermal expansion coefficient, Debye temperature and heat capacities are calculated.

  17. STME Hydrogen Mixer Study

    NASA Technical Reports Server (NTRS)

    Blumenthal, Rob; Kim, Dongmoon; Bache, George

    1992-01-01

    The hydrogen mixer for the Space Transportation Main Engine is used to mix cold hydrogen bypass flow with warm hydrogen coolant chamber gas, which is then fed to the injectors. It is very important to have a uniform fuel temperature at the injectors in order to minimize mixture ratio problems due to the fuel density variations. In addition, the fuel at the injector has certain total pressure requirements. In order to achieve these objectives, the hydrogen mixer must provide a thoroughly mixed fluid with a minimum pressure loss. The AEROVISC computational fluid dynamics (CFD) code was used to analyze the STME hydrogen mixer, and proved to be an effective tool in optimizing the mixer design. AEROVISC, which solves the Reynolds Stress-Averaged Navier-Stokes equations in primitive variable form, was used to assess the effectiveness of different mixer designs. Through a parametric study of mixer design variables, an optimal design was selected which minimized mixed fuel temperature variation and fuel mixer pressure loss. The use of CFD in the design process of the STME hydrogen mixer was effective in achieving an optimal mixer design while reducing the amount of hardware testing.

  18. Acceleration of high-pressure-ratio single-spool turbojet engine as determined from component performance characteristics I : effect of air bleed at compressor outlet

    NASA Technical Reports Server (NTRS)

    Rebeske, John J , Jr; Rohlik, Harold E

    1953-01-01

    An analytical investigation was made to determine from component performance characteristics the effect of air bleed at the compressor outlet on the acceleration characteristics of a typical high-pressure-ratio single-spool turbojet engine. Consideration of several operating lines on the compressor performance map with two turbine-inlet temperatures showed that for a minimum acceleration time the turbine-inlet temperature should be the maximum allowable, and the operating line on the compressor map should be as close to the surge region as possible throughout the speed range. Operation along such a line would require a continuously varying bleed area. A relatively simple two-step area bleed gives only a small increase in acceleration time over a corresponding variable-area bleed. For the modes of operation considered, over 84 percent of the total acceleration time was required to accelerate through the low-speed range ; therefore, better low-speed compressor performance (higher pressure ratios and efficiencies) would give a significant reduction in acceleration time.

  19. Semiempirical models for description of shear modulus in wide ranges of temperatures and pressures of shock compression

    NASA Astrophysics Data System (ADS)

    El'Kin, V. M.; Mikhailov, V. N.; Mikhailova, T. Yu.

    2011-12-01

    In this paper, we discuss the potentials of the Steinberg-Cochran-Guinan (SCG) and Burakovsky-Preston (BP) models for the description of the shear-modulus behavior at temperatures and pressures that arise behind the shock-wave front. A modernized variant of the SCG model is suggested, which reduces to the introduction of a free parameter and the representation of the model in the volume-temperature coordinates (( V, T) model). A systematic comparison is performed of all three models of shear modulus with experimental data and data of ab initio calculations for metals such as Al, Be, Cu, K, Na, Mg, Mo, W, and Ta in a wide range of pressures. In addition, for Al, Cu, Mo, W, and Ta there is performed a comparison with the known temperature dependences of the shear modulus and with the results of measurements of the velocities of longitudinal sound behind the shock-wave front. It is shown that in the original form the SCG and BP models give overestimated values of the shear modulus as compared to the data of ab initio calculations and shock-wave experiments. The ( V, T) model, due to the use of a free parameter, makes it possible to optimally describe the totality of experimental and calculated data. The same result is achieved in the case of the BP model after a redefining of its initial parameters. The adequate description of the shear modulus in the range of high intermediate pressures characteristic of the solid-phase states behind the shock-wave front is accompanied in both cases by the violation of the correct asymptotic behavior of the shear modulus at ultrahigh compressions which is originally laid into the SCG and BP models.

  20. Temperature- and pressure-dependent infrared spectroscopy of 1-butyl-3-methylimidazolium trifluoromethanesulfonate: A dipolar coupling theory analysis

    NASA Astrophysics Data System (ADS)

    Burba, Christopher M.; Chang, Hai-Chou

    2018-03-01

    Continued growth and development of ionic liquids requires a thorough understanding of how cation and anion molecular structure defines the liquid structure of the materials as well as the various properties that make them technologically useful. Infrared spectroscopy is frequently used to assess molecular-level interactions among the cations and anions of ionic liquids because the intramolecular vibrational modes of the ions are sensitive to the local potential energy environments in which they reside. Thus, different interaction modes among the ions may lead to different spectroscopic signatures in the vibrational spectra. Charge organization present in ionic liquids, such as 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([C4mim]CF3SO3), is frequently modeled in terms of a quasicrystalline structure. Highly structured quasilattices enable the dynamic coupling of vibrationally-induced dipole moments to produce optical dispersion and transverse optical-longitudinal optical (TO-LO) splitting of vibrational modes of the ionic liquid. According to dipolar coupling theory, the degree of TO-LO splitting is predicted to have a linear dependence on the number density of the ionic liquid. Both temperature and pressure will affect the number density of the ionic liquid and, therefore, the amount of TO-LO splitting for this mode. Therefore, we test these relationships through temperature- and pressure-dependent FT-IR spectroscopic studies of [C4mim]CF3SO3, focusing on the totally symmetric Ssbnd O stretching mode for the anion, νs(SO3). Increased temperature decreases the amount of TO-LO splitting for νs(SO3), whereas elevated pressure is found to increase the amount of band splitting. In both cases, the experimental observations follow the general predictions of dipolar coupling theory, thereby supporting the quasilattice model for this ionic liquid.

  1. SteamTablesGrid: An ActiveX control for thermodynamic properties of pure water

    NASA Astrophysics Data System (ADS)

    Verma, Mahendra P.

    2011-04-01

    An ActiveX control, steam tables grid ( StmTblGrd) to speed up the calculation of the thermodynamic properties of pure water is developed. First, it creates a grid (matrix) for a specified range of temperature (e.g. 400-600 K with 40 segments) and pressure (e.g. 100,000-20,000,000 Pa with 40 segments). Using the ActiveX component SteamTables, the values of selected properties of water for each element (nodal point) of the 41×41 matrix are calculated. The created grid can be saved in a file for its reuse. A linear interpolation within an individual phase, vapor or liquid is implemented to calculate the properties at a given value of temperature and pressure. A demonstration program to illustrate the functionality of StmTblGrd is written in Visual Basic 6.0. Similarly, a methodology is presented to explain the use of StmTblGrd in MS-Excel 2007. In an Excel worksheet, the enthalpy of 1000 random datasets for temperature and pressure is calculated using StmTblGrd and SteamTables. The uncertainty in the enthalpy calculated with StmTblGrd is within ±0.03%. The calculations were performed on a personal computer that has a "Pentium(R) 4 CPU 3.2 GHz, RAM 1.0 GB" processor and Windows XP. The total execution time for the calculation with StmTblGrd was 0.3 s, while it was 60.0 s for SteamTables. Thus, the ActiveX control approach is reliable, accurate and efficient for the numerical simulation of complex systems that demand the thermodynamic properties of water at several values of temperature and pressure like steam flow in a geothermal pipeline network.

  2. Effect of pressure variation on structural, elastic, mechanical, optoelectronic and thermodynamic properties of SrNaF3 fluoroperovskite

    NASA Astrophysics Data System (ADS)

    Erum, Nazia; Azhar Iqbal, Muhammad

    2017-12-01

    The effect of pressure variation on structural, electronic, elastic, mechanical, optical and thermodynamic characteristics of cubic SrNaF3 fluoroperovskite have been investigated by employing first-principles method within the framework of gradient approximation (GGA). For the total energy calculations, we have used the full-potential linearized augmented plane wave (FP-LAPW) method. Thermodynamic properties are computed in terms of quasi-harmonic Debye model. The pressure effects are determined in the range of 0-25 GPa, in which mechanical stability of SrNaF3 fluoroperovskite remains valid. A prominent decrease in lattice constant and bonds length is observed with the increase in pressure from 0 to 25 GPa. The effect of increase in pressure on band structure calculations with GGA and GGA plus Tran-Blaha modified Becke-Johnson (TB-mBJ) potential reveals a predominant characteristic associated with widening of bandgap. The influence of pressure on set of isotropic elastic parameters and their related properties are numerically estimated for SrNaF3 polycrystalline aggregate. Apart of linear dependence of elastic coefficients, transition from brittle to ductile behavior is observed as pressure is increased from 0 to 25 GPa. We have successfully obtained variation of lattice constant, volume expansion, bulk modulus, Debye temperature and specific heat capacities with pressure and temperature in the range of 0-25 GPa and 0-600 K. All the calculated optical properties such as the complex dielectric function ɛ(ω), optical conductivity σ(ω), energy loss function L(ω), absorption coefficient α(w), refractive index n(ω), reflectivity R(ω), and effective number of electrons n eff, via sum rules shift towards the higher energies under the application of pressure.

  3. Arsenic species determination in human scalp hair by pressurized hot water extraction and high performance liquid chromatography-inductively coupled plasma-mass spectrometry.

    PubMed

    Morado Piñeiro, Andrés; Moreda-Piñeiro, Jorge; Alonso-Rodríguez, Elia; López-Mahía, Purificación; Muniategui-Lorenzo, Soledad; Prada-Rodríguez, Darío

    2013-02-15

    Analytical methods for the determination of total arsenic and arsenic species (mainly As(III) and As(V)) in human scalp hair have been developed. Inductively coupled plasma-mass spectrometry (ICP-MS) and high performance liquid chromatography (HPLC) coupled to ICP-MS have been used for total arsenic and arsenic species determination, respectively. The proposed methods include a "green", fast, high efficient and automated species leaching procedure by pressurized hot water extraction (PHWE). The operating parameters for PHWE including modifier concentration, extraction temperature, static time, extraction steps, pressure, mean particle size, diatomaceous earth (DE) mass/sample mass ratio and flush volume were studied using design of experiments (Plackett-Burman design PBD). Optimum condition implies a modifier concentration (acetic acid) of 150 mM and powdered hair samples fully mixed with diatomaceous earth (DE) as a dispersing agent at a DE mass/sample mass ratio of 5. The extraction has been carried out at 100°C and at an extraction pressure of 1500 psi for 5 min in four extraction step. Under optimised conditions, limits of quantification of 7.0, 6.3 and 50.3 ng g(-1) for total As, As(III) and As(V), respectively were achieved. Repeatability of the overall procedure (4.4, 7.2 and 2.1% for total As, As(III) and As(V), respectively) was achieved. The analysis of GBW-07601 (human hair) certified reference material was used for validation. The optimised method has been finally applied to several human scalp hair samples. Copyright © 2012 Elsevier B.V. All rights reserved.

  4. DBD Plasma Actuators for Flow Control in Air Vehicles and Jet Engines - Simulation of Flight Conditions in Test Chambers by Density Matching

    NASA Technical Reports Server (NTRS)

    Ashpis, David E.; Thurman, Douglas R.

    2011-01-01

    Dielectric Barrier Discharge (DBD) Plasma actuators for active flow control in aircraft and jet engines need to be tested in the laboratory to characterize their performance at flight operating conditions. DBD plasma actuators generate a wall-jet electronically by creating weakly ionized plasma, therefore their performance is affected by gas discharge properties, which, in turn, depend on the pressure and temperature at the actuator placement location. Characterization of actuators is initially performed in a laboratory chamber without external flow. The pressure and temperature at the actuator flight operation conditions need to be simultaneously set in the chamber. A simplified approach is desired. It is assumed that the plasma discharge depends only on the gas density, while other temperature effects are assumed to be negligible. Therefore, tests can be performed at room temperature with chamber pressure set to yield the same density as in operating flight conditions. The needed chamber pressures are shown for altitude flight of an air vehicle and for jet engines at sea-level takeoff and altitude cruise conditions. Atmospheric flight conditions are calculated from standard atmosphere with and without shock waves. The engine data was obtained from four generic engine models; 300-, 150-, and 50-passenger (PAX) aircraft engines, and a military jet-fighter engine. The static and total pressure, temperature, and density distributions along the engine were calculated for sea-level takeoff and for altitude cruise conditions. The corresponding chamber pressures needed to test the actuators were calculated. The results show that, to simulate engine component flows at in-flight conditions, plasma actuator should be tested over a wide range of pressures. For the four model engines the range is from 12.4 to 0.03 atm, depending on the placement of the actuator in the engine. For example, if a DBD plasma actuator is to be placed at the compressor exit of a 300 PAX engine, it has to be tested at 12.4 atm for takeoff, and 6 atm for cruise conditions. If it is to be placed at the low-pressure turbine, it has to be tested at 0.5 and 0.2 atm, respectively. These results have implications for the feasibility and design of DBD plasma actuators for jet engine flow control applications. In addition, the distributions of unit Reynolds number, Mach number, and velocity along the engine are provided. The engine models are non-proprietary and this information can be used for evaluation of other types of actuators and for other purposes.

  5. Temperature Histories in Ceramic-Insulated Heat-Sink Nozzle

    NASA Technical Reports Server (NTRS)

    Ciepluch, Carl C.

    1960-01-01

    Temperature histories were calculated for a composite nozzle wall by a simplified numerical integration calculation procedure. These calculations indicated that there is a unique ratio of insulation and metal heat-sink thickness that will minimize total wall thickness for a given operating condition and required running time. The optimum insulation and metal thickness will vary throughout the nozzle as a result of the variation in heat-transfer rate. The use of low chamber pressure results in a significant increase in the maximum running time of a given weight nozzle. Experimentally measured wall temperatures were lower than those calculated. This was due in part to the assumption of one-dimensional or slab heat flow in the calculation procedure.

  6. Calculation and synthesis of ZrC by CVD from ZrCl4-C3H6-H2-Ar system with high H2 percentage

    NASA Astrophysics Data System (ADS)

    Zhu, Yan; Cheng, Laifei; Ma, Baisheng; Gao, Shuang; Feng, Wei; Liu, Yongsheng; Zhang, Litong

    2015-03-01

    A thermodynamic calculation about the synthesis of ZrC from the ZrCl4-C3H6-H2-Ar system with high percentage of H2 was performed using the FactSage thermochemical software. According to the calculation, ZrC coating was synthesized on graphite substrates and carbon fibers by a low pressure chemical vapor deposition (LPCVD) process, and growth rate of the ZrC coating as a function of temperature was investigated. The surface diagrams of condensed-phases in this system were expressed as the functions of the deposition temperature, total pressure and reactant ratios of ZrCl4/(ZrCl4 + C3H6), H2/(ZrCl4 + C3H6), and the yield of the products was determined by the diagrams. A smooth and dense ZrC coating could be synthesized under the instruction of the calculated parameters. The morphologies of the ZrC coatings were significantly affected by temperature and gases flux. The deposition temperature is much lower than that from the ZrCl4-CH4-H2-Ar system.

  7. Defect chemistry and characterization of (Hg, Cd)Te

    NASA Technical Reports Server (NTRS)

    Vydyanath, H. R.

    1981-01-01

    Single crystal samples of phosphorus doped Hg sub 0.8 Cd sub 0.2 Te were anneald at temperatures varying from 450 C to 600 C in various Hg atmospheres. The samples were quenched to room temperature from the annealing temperatures. Hall effect and mobility measurements were performed at 77 K on all these samples. The results indicate the crystals to be p type for a total phosphorus concentration of 10 to the 19th power/cu cm in all the samples. The hole concentration at 77 K increases with increasing Hg pressures at 450 C and 500 C contrary to the observation in undoped crystals. Also, at low Hg pressures the concentration of holes in the phosphorus doped crystals is lower than in the undoped crystals. The hole concentration in all the samples is lower than the intrinsic carrier concentration at the annealing temperatures. The hole mobility in the doped crystals is similar to that in the undoped crystals. A defect model according to which phosphorus behaves as a single acceptor interstitially, occupying Te lattice sites while it acts as a single donor occupying Hg lattice sites was established. Equilibrum constants established for the incorporation of all the phosphorus species explain the experimental results

  8. Experimental clean combustor program: Noise study

    NASA Technical Reports Server (NTRS)

    Sofrin, T. G.; Riloff, N., Jr.

    1976-01-01

    Under a Noise Addendum to the NASA Experimental Clean Combustor Program (ECCP) internal pressure fluctuations were measured during tests of JT9D combustor designs conducted in a burner test rig. Measurements were correlated with burner operating parameters using an expression relating farfield noise to these parameters. For a given combustor, variation of internal noise with operating parameters was reasonably well predicted by this expression but the levels were higher than farfield predictions and differed significantly among several combustors. For two burners, discharge stream temperature fluctuations were obtained with fast-response thermocouples to allow calculation of indirect combustion noise which would be generated by passage of the temperature inhomogeneities through the high pressure turbine stages of a JT9D turbofan engine. Using a previously developed analysis, the computed indirect combustion noise was significantly lower than total low frequency core noise observed on this and several other engines.

  9. Chemical equilibrium. [maximizing entropy of gas system to derive relations between thermodynamic variables

    NASA Technical Reports Server (NTRS)

    1976-01-01

    The entropy of a gas system with the number of particles subject to external control is maximized to derive relations between the thermodynamic variables that obtain at equilibrium. These relations are described in terms of the chemical potential, defined as equivalent partial derivatives of entropy, energy, enthalpy, free energy, or free enthalpy. At equilibrium, the change in total chemical potential must vanish. This fact is used to derive the equilibrium constants for chemical reactions in terms of the partition functions of the species involved in the reaction. Thus the equilibrium constants can be determined accurately, just as other thermodynamic properties, from a knowledge of the energy levels and degeneracies for the gas species involved. These equilibrium constants permit one to calculate the equilibrium concentrations or partial pressures of chemically reacting species that occur in gas mixtures at any given condition of pressure and temperature or volume and temperature.

  10. Recovery of oil components of okara by ethanol-modified supercritical carbon dioxide extraction.

    PubMed

    Quitain, Armando T; Oro, Kazuyuki; Katoh, Shunsaku; Moriyoshi, Takashi

    2006-09-01

    Recovery of the oil components of okara by ethanol-modified supercritical carbon dioxide extraction was investigated at 40-80 degrees C temperature and 12-30 MPa pressure. In a typical run (holding period of 2 h, continuous flow extraction of 5 h), results indicated that the oil component could be best obtained with a recovery of 63.5% at relatively low temperature of 40 degrees C and mild pressure of 20 MPa in the presence of 10 mol% EtOH as entrainer. Based on gas chromatography-mass spectrometry (GC-MS) analysis, the extracts consisted mainly of fatty acids and phytosterols, and traces of decadienal. Folin-Ciocalteau estimates of total phenols showed that addition of EtOH as entrainer increased the yield and the amount of phenolic compounds in the extracts. The amounts of two primary soy isoflavones, genistein and daidzein, in the extracts also increased with increasing amount of EtOH.

  11. Effect of External Pressure Drop on Loop Heat Pipe Operating Temperature

    NASA Technical Reports Server (NTRS)

    Jentung, Ku; Ottenstein, Laura; Rogers, Paul; Cheung, Kwok; Obenschain, Arthur F. (Technical Monitor)

    2002-01-01

    This paper discusses the effect of the pressure drop on the operating temperature in a loop heat pipe (LHP). Because the evaporator and the compensation chamber (CC) both contain two-phase fluid, a thermodynamic constraint exists between the temperature difference and the pressure drop for these two components. As the pressure drop increases, so will the temperature difference. The temperature difference in turn causes an increase of the heat leak from the evaporator to the CC, resulting in a higher CC temperature. Furthermore, the heat leak strongly depends on the vapor void fraction inside the evaporator core. Tests were conducted by installing a valve on the vapor line so as to vary the pressure drop, and by charging the LHP with various amounts of fluid. Test results verify that the LHP operating temperature increases with an increasing differential pressure, and the temperature increase is a strong function of the fluid inventory in the loop.

  12. Magma chamber cooling by episodic volatile expulsion as constrained by mineral vein distributions in the Butte, Montana Cu-Mo porphyry deposit

    NASA Astrophysics Data System (ADS)

    Daly, K.; Karlstrom, L.; Reed, M. H.

    2016-12-01

    The role of hydrothermal systems in the thermal evolution of magma chambers is poorly constrained yet likely significant. We analyze trends in mineral composition, vein thickness and overall volumetric fluid flux of the Butte, Montana porphyry Cu-Mo deposit to constrain the role of episodic volatile discharge in the crystallization of the source magma chamber ( 300 km3of silicic magma). An aqueous fluid sourced from injection of porphyritic dikes formed the Butte porphyry Cu network of veins. At least three separate pulses of fluid through the system are defined by alteration envelopes of [1] gray sericite (GS); [2] early-dark micaceous (EDM), pale-green sericite (PGS), and dark-green sericite (DGS); and [3] quartz-molybdenite (Qmb) and barren-quartz. Previous research using geothermometers and geobarometers has found that vein mineral composition, inferred temperatures and inferred pressures vary systematically with depth. Later fluid pulses are characterized by lower temperatures, consistent with progressive cooling of the source. We have digitized previously unused structural data from Butte area drill cores, and applied thermomechanical modeling of fluid release from the source magma chamber through time. Vein number density and vein thickness increase with depth as a clear function of mineralogy and thus primary temperature and pressure. We identify structural trends in the three fluid pulses which seem to imply time evolution of average vein characteristics. Pulses of Qmb-barren quartz and EDM-PGS-DGS (1st and 2nd in time) exhibit increasing vein number density (157 & 95 veins/50m, respectively) and thickness (300mm & 120mm, respectively) as a function of depth. EDM-PGS-DGS has a shallower peak in vein density (800m) than Qmb-barren quartz (>1600m). These data provide the basis for idealized mechanical models of hydrofractures, to predict driving pressures and to compare with existing source temperatures and total fluid volumes in order to estimate the total enthalpy of each fluid pulse. We then compare with models for conductive cooling and crystallization of the source magma chamber to estimate the importance of hydrothermal fluid expulsion in the total heat budget. Such models should also provide constraints on the timing and ultimately the origin of pulsed volatile release at Butte.

  13. Explicit finite-volume time-marching calculations of total temperature distributions in turbulent flow

    NASA Technical Reports Server (NTRS)

    Nicholson, Stephen; Moore, Joan G.; Moore, John

    1987-01-01

    A method was developed which calculates two-dimensional, transonic, viscous flow in ducts. The finite volume, time-marching formulation is used to obtain steady flow solutions of the Reynolds-averaged form of the Navier-Stokes equations. The entire calculation is performed in the physical domain. This paper investigates the introduction of a new formulation of the energy equation which gives improved transient behavior as the calculation converges. The effect of variable Prandtl number on the temperature distribution through the boundary layer is also investigated. A turbulent boundary layer in an adverse pressure gradient (M = 0.55) is used to demonstrate the improved transient temperature distribution obtained when the new formulation of the energy equation is used. A flat plate turbulent boundary layer with a supersonic free-stream Mach number of 2.8 is used to investigate the effect of Prandtl number on the distribution of properties through the boundary layer. The computed total temperature distribution and recovery factor agree well with the measurements when a variable Prandtl number is used through the boundary layer.

  14. Explicit finite-volume time-marching calculations of total temperature distributions in turbulent flow

    NASA Technical Reports Server (NTRS)

    Nicholson, Stephen; Moore, Joan G.; Moore, John

    1986-01-01

    A method was developed which calculates two-dimensional, transonic, viscous flow in ducts. The finite volume, time-marching formulation is used to obtain steady flow solutions of the Reynolds-averaged form of the Navier-Stokes equations. The entire calculation is performed in the physical domain. This paper investigates the introduction of a new formulation of the energy equation which gives improved transient behavior as the calculation converges. The effect of variable Prandtl number on the temperature distribution through the boundary layer is also investigated. A turbulent boundary layer in an adverse pressure gradient (M = 0.55) is used to demonstrate the improved transient temperature distribution obtained when the new formulation of the energy equation is used. A flat plate turbulent boundary layer with a supersonic free-stream Mach number of 2.8 is used to investigate the effect of Prandtl number on the distribution of properties through the boundary layer. The computed total temperature distribution and recovery factor agree well with the measurements when a variable Prandtl number is used through the boundary layer.

  15. Effect of spatial inlet temperature and pressure distortion on turbofan engine stability

    NASA Technical Reports Server (NTRS)

    Mehalic, Charles M.

    1988-01-01

    The effects of circumferential and radial inlet temperature distortion, circumferential pressure distortion, and combined temperature and pressure distortion on the stability of an advanced turbofan engine were investigated experimentally at simulated altitude conditions. With circumferential and radial inlet temperature distortion, a flow instability generated by the fan operating near stall caused the high-pressure compressor to surge at, or near, the same time as the fan. The effect of combined distortion was dependent on the relative location of the high-temperature and low-pressure regions; high-pressure compressor stalls occurred when the regions coincided, and fan stalls occurred with the regions separated.

  16. The effects of pressure, temperature, and pore water on velocities in Westerly granite. [for seismic wave propagation

    NASA Technical Reports Server (NTRS)

    Spencer, J. W., Jr.; Nur, A. M.

    1976-01-01

    A description is presented of an experimental assembly which has been developed to conduct concurrent measurements of compressional and shear wave velocities in rocks at high temperatures and confining pressures and with independent control of the pore pressure. The apparatus was used in studies of the joint effects of temperature, external confining pressure, and internal pore water on sonic velocities in Westerly granite. It was found that at a given temperature, confining pressure has a larger accelerating effect on compressional waves in dry rock, whereas at a given confining pressure, temperature has a larger retarding effect on shear waves.

  17. Energy consumption analysis and simulation of waste heat recovery technology of ceramic rotary kiln

    NASA Astrophysics Data System (ADS)

    Chen, Zhiguang; Zhou, Yu; Qin, Chaokui; Zhang, Xuemei

    2018-03-01

    Ceramsite is widely used in the construction industry, insulation works and oil industry in China, and the manufacture equipment is mainly industrial kiln. In this paper, energy consumption analysis had been carried out through experimental test of a Ceramsite kiln in Henan province. Results showed that the discharge temperature of Ceramsite was about 1393K, and the waste heat accounted for 22.1% of the total energy consumption. A structure of cyclone preheater which recovered waste heat of the high temperature Ceramsite by blast cooling was designed. Then, using Fluent software, performance of the unit was simulated. The minimum temperature that Ceramsite could reach, heat dissipating capacity of Ceramsite, temperature at air outlet, wall temperature of the unit and pressure loss were analyzed. Performance of the designed unit under different inlet velocity was analyzed as well.

  18. Plasticity of preferred body temperatures as means of coping with climate change?

    PubMed Central

    Gvoždík, Lumír

    2012-01-01

    Thermoregulatory behaviour represents an important component of ectotherm non-genetic adaptive capacity that mitigates the impact of ongoing climate change. The buffering role of behavioural thermoregulation has been attributed solely to the ability to maintain near optimal body temperature for sufficiently extended periods under altered thermal conditions. The widespread occurrence of plastic modification of target temperatures that an ectotherm aims to achieve (preferred body temperatures) has been largely overlooked. I argue that plasticity of target temperatures may significantly contribute to an ectotherm's adaptive capacity. Its contribution to population persistence depends on both the effectiveness of acute thermoregulatory adjustments (reactivity) in buffering selection pressures in a changing thermal environment, and the total costs of thermoregulation (i.e. reactivity and plasticity) in a given environment. The direction and magnitude of plastic shifts in preferred body temperatures can be incorporated into mechanistic models, to improve predictions of the impact of global climate change on ectotherm populations. PMID:22072284

  19. Plasticity of preferred body temperatures as means of coping with climate change?

    PubMed

    Gvozdík, Lumír

    2012-04-23

    Thermoregulatory behaviour represents an important component of ectotherm non-genetic adaptive capacity that mitigates the impact of ongoing climate change. The buffering role of behavioural thermoregulation has been attributed solely to the ability to maintain near optimal body temperature for sufficiently extended periods under altered thermal conditions. The widespread occurrence of plastic modification of target temperatures that an ectotherm aims to achieve (preferred body temperatures) has been largely overlooked. I argue that plasticity of target temperatures may significantly contribute to an ectotherm's adaptive capacity. Its contribution to population persistence depends on both the effectiveness of acute thermoregulatory adjustments (reactivity) in buffering selection pressures in a changing thermal environment, and the total costs of thermoregulation (i.e. reactivity and plasticity) in a given environment. The direction and magnitude of plastic shifts in preferred body temperatures can be incorporated into mechanistic models, to improve predictions of the impact of global climate change on ectotherm populations.

  20. In situ Low-temperature Pair Distribution Function (PDF) Analysis of CH4 and CO2 Hydrates

    NASA Astrophysics Data System (ADS)

    Cladek, B.; Everett, M.; McDonnell, M.; Tucker, M.; Keffer, D.; Rawn, C.

    2017-12-01

    Gas hydrates occur in ocean floor and sub-surface permafrost deposits and are stable at moderate to high pressures and low temperatures. They are a clathrate structure composed of hydrogen bonded water cages that accommodate a wide variety of guest molecules. CO2 and CH4 hydrates both crystallize as the cubic sI hydrate and can form a solid solution. Natural gas hydrates are interesting as a potential methane source and for CO2 sequestration. Long-range diffraction studies on gas hydrates give valuable structural information but do not provide a detailed understanding of the disordered gas molecule interactions with the host lattice. In-situ low temperature total scattering experiments combined with pair distribution function (PDF) analysis are used to investigate the gas molecule motions and guest-cage interactions. CO2 and methane hydrates exhibit different decomposition behavior, and CO2 hydrate has a smaller lattice parameter despite it being a relatively larger molecule. Total scattering studies characterizing both the short- and long-range order simultaneously help to elucidate the structural source of these phenomena. Low temperature neutron total scattering data were collected using the Nanoscale Ordered MAterials Diffractometer (NOMAD) beamline at the Spallation Neutron Source (SNS) on CO2 and CH4 hydrates synthesized with D2O. Guest molecule motion within cages and interactions between gases and cages are investigated through the hydrate stability and decomposition regions. Data were collected from 2-80 K at a pressure of 55 mbar on CO2 and CH4 hydrates, and from 80-270 K at 25 bar on CH4 hydrate. The hydrate systems were modeled with classical molecular dynamic (MD) simulations to provide an analysis of the total energy into guest-guest, guest-host and host-host contributions. Combined Reitveld and Reverse Monte Carlo (RMC) structure refinement were used to fit models of the data. This combined modeling and simulation characterizes the effects of CO2 and CH4 as guest molecules on the structure and decomposition of gas hydrates. Structure and thermodynamic studies will provide a more comprehensive understanding of CO2-CH4 solid solutions, exchange kinetics, and implications on hydrate structure.

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