The 1998-2000 SHADOZ (Southern Hemisphere ADditional OZonesondes) Tropical Ozone Climatology: Ozonesonde Precision, Accuracy and Station-to-Station Variability

NASA Technical Reports Server (NTRS)

Witte, J. C.; Thompson, Anne M.; McPeters, R. D.; Oltmans, S. J.; Schmidlin, F. J.; Bhartia, P. K. (Technical Monitor)

2001-01-01

As part of the SAFARI-2000 campaign, additional launches of ozonesondes were made at Irene, South Africa and at Lusaka, Zambia. These represent campaign augmentations to the SHADOZ database described in this paper. This network of 10 southern hemisphere tropical and subtropical stations, designated the Southern Hemisphere ADditional OZonesondes (SHADOZ) project and established from operational sites, provided over 1000 profiles from ozonesondes and radiosondes during the period 1998-2000. (Since that time, two more stations, one in southern Africa, have joined SHADOZ). Archived data are available at: http://code9l6.gsfc.nasa.gov/Data-services/shadoz>. Uncertainties and accuracies within the SHADOZ ozone data set are evaluated by analyzing: (1) imprecisions in stratospheric ozone profiles and in methods of extrapolating ozone above balloon burst; (2) comparisons of column-integrated total ozone from sondes with total ozone from the Earth-Probe/TOMS (Total Ozone Mapping Spectrometer) satellite and ground-based instruments; (3) possible biases from station-to-station due to variations in ozonesonde characteristics. The key results are: (1) Ozonesonde precision is 5%; (2) Integrated total ozone column amounts from the sondes are in good agreement (2-10%) with independent measurements from ground-based instruments at five SHADOZ sites and with overpass measurements from the TOMS satellite (version 7 data). (3) Systematic variations in TOMS-sonde offsets and in groundbased-sonde offsets from station to station reflect biases in sonde technique as well as in satellite retrieval. Discrepancies are present in both stratospheric and tropospheric ozone. (4) There is evidence for a zonal wave-one pattern in total and tropospheric ozone, but not in stratospheric ozone.

Implications of Version 8 TOMS and SBUV Data for Long-Term Trend Analysis

NASA Technical Reports Server (NTRS)

Frith, Stacey M.

2004-01-01

Total ozone data from the Total Ozone Mapping Spectrometer (TOMS) and profile/total ozone data from the Solar Backscatter Ultraviolet (SBUV; SBW/2) series of instruments have recently been reprocessed using new retrieval algorithms (referred to as Version 8 for both) and updated calibrations. In this paper, we incorporate the Version 8 data into a TOMS/SBW merged total ozone data set and an S B W merged profile ozone data set. The Total Merged Ozone Data (Total MOD) combines data from multiple TOMS and SBW instruments to form an internally consistent global data set with virtually complete time coverage from October 1978 through December 2003. Calibration differences between instruments are accounted for using external adjustments based on instrument intercomparisons during overlap periods. Previous results showed errors due to aerosol loading and sea glint are significantly reduced in the V8 TOMS retrievals. Using SBW as a transfer standard, calibration differences between V8 Nimbus 7 and Earth Probe TOMS data are approx. 1.3%, suggesting small errors in calibration remain. We will present updated total ozone long-term trends based on the Version 8 data. The Profile Merged Ozone Data (Profile MOD) data set is constructed using data from the SBUV series of instruments. In previous versions, SAGE data were used to establish the long-term external calibration of the combined data set. The SBW Version 8 we assess the V8 profile data through comparisons with SAGE and between SBW instruments in overlap periods. We then construct a consistently-calibrated long term time series. Updated zonal mean trends as a function of altitude and season from the new profile data set will be shown, and uncertainties in determining the best long-term calibration will be discussed.

Using the World Primary Standard Dobson Spectrometer to Monitor the Stability of a Multi-Instrument Satellite Ozone Dataset

NASA Technical Reports Server (NTRS)

McPeters, R.D.; Oltmans, Samuel J.

2000-01-01

NASA is creating a long term satellite ozone time series by combining data from multiple instruments: Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) (1978 - 1993), Meteor 3 TOMS (1991 - 1994), Earth Probe TOMS (1996 - present), Nimbus 7 SB-JV (1978 - 1990), NOAA-9 Solar Backscatter UV Spectrometer (SBUV/2) (1984 - 1997), NOAA-11 SBUV/2 (1989 - 1994), and NOAA-14 SBUV/2 (1995 - present). The stability of individual data sets and possible instrument-to-instrument differences are best checked by comparison with ground-based measurements. We have examined the time dependence of the calibrations of these instruments by comparing satellite derived ozone with that measured by the world primary standard Dobson spectrometer No. 83. This instrument has been maintained since 1962 as a standard for total ozone to an uncertainty of plus or minus 0.5%. Measurements of AD pair ozone made with instrument No. 83 at Mauna Loa observatory most summers since 1979 were compared with coincident TOMS and SBUV(/2) ozone measurements. The comparison shows that the various instruments were stable relative to instrument No. 83 to within about plus or minus 1%, but that there are instrument-to-instrument biases of as much as 3%. Earth Probe TOMS, for example, is 1% to 2% high relative to Nimbus 7 TOMS when the world standard instrument is used as a transfer standard. Similar results are seen when comparisons are made with an ensemble of 41 Dobson stations throughout the world, demonstrating that the ensemble as a whole is stable despite the fact that many instruments within the ensemble have clear calibration changes.

Management of Chronic Periodontitis Using Subgingival Irrigation of Ozonized Water: A Clinical and Microbiological Study.

PubMed

Issac, Annie V; Mathew, Jayan Jacob; Ambooken, Majo; Kachappilly, Arun Jose; Pk, Ajithkumar; Johny, Thomas; Vk, Linith; Samuel, Anju

2015-08-01

Adjunctive use of professional subgingival irrigation with scaling and root planing (SRP) has been found to be beneficial in eradicating the residual microorganisms in the pocket. To evaluate the effect of ozonized water subgingival irrigation on microbiologic parameters and clinical parameters namely Gingival index, probing pocket depth, and clinical attachment level. Thirty chronic periodontitis patients with probing pocket depth ≥6mm on at least one tooth on contra lateral sides of opposite arches were included in the study. The test sites were subjected to ozonized water subgingival irrigation with subgingival irrigation device fitted with a modified subgingival tip. Control sites were subjected to scaling and root planing only. The following clinical parameters were recorded initially and after 4 weeks at the test sites and control sites. Plaque Index, Gingival Index, probing pocket depth, clinical attachment level. Microbiologic sampling was done for the test at the baseline, after scaling, immediately after ozonized water subgingival irrigation and after 4 weeks. In control sites microbiologic sampling was done at the baseline, after scaling and after 4 weeks. The following observations were made after 4 weeks. The results were statistically analysed using independent t-test and paired t-test. Test sites showed a greater reduction in pocket depth and gain in clinical attachment compared to control sites. The total anaerobic counts were significantly reduced by ozonized water subgingival irrigation along with SRP compared to SRP alone. Ozonized water subgingival irrigation can improve the clinical and microbiological parameters in patients with chronic periodontitis when used as an adjunct to scaling and root planing.

Global validation of empirically corrected EP-Total Ozone Mapping Spectrometer (TOMS) total ozone columns using Brewer and Dobson ground-based measurements

NASA Astrophysics Data System (ADS)

Antón, M.; Koukouli, M. E.; Kroon, M.; McPeters, R. D.; Labow, G. J.; Balis, D.; Serrano, A.

2010-10-01

This article focuses on the global-scale validation of the empirically corrected Version 8 total ozone column data set acquired by the NASA Total Ozone Mapping Spectrometer (TOMS) during the period 1996-2004 when this instrument was flying aboard the Earth Probe (EP) satellite platform. This analysis is based on the use of spatially co-located, ground-based measurements from Dobson and Brewer spectrophotometers. The original EP-TOMS V8 total ozone column data set was also validated with these ground-based measurements to quantify the improvements made by the empirical correction that was necessary as a result of instrumental degradation issues occurring from the year 2000 onward that were uncorrectable by normal calibration techniques. EP-TOMS V8-corrected total ozone data present a remarkable improvement concerning the significant negative bias of around ˜3% detected in the original EP-TOMS V8 observations after the year 2000. Neither the original nor the corrected EP-TOMS satellite total ozone data sets show a significant dependence on latitude. In addition, both EP-TOMS satellite data sets overestimate the Brewer measurements for small solar zenith angles (SZA) and underestimate for large SZA, explaining a significant seasonality (˜1.5%) for cloud-free and cloudy conditions. Conversely, relative differences between EP-TOMS and Dobson present almost no dependence on SZA for cloud-free conditions and a strong dependence for cloudy conditions (from +2% for small SZA to -1% for high SZA). The dependence of the satellite ground-based relative differences on total ozone shows good agreement for column values above 250 Dobson units. Our main conclusion is that the upgrade to TOMS V8-corrected total ozone data presents a remarkable improvement. Nevertheless, despite its quality, the EP-TOMS data for the period 2000-2004 should not be used as a source for trend analysis since EP-TOMS ozone trends are empirically corrected using NOAA-16 and NOAA-17 solar backscatter ultraviolet/2 data as external references, and therefore, they are no longer considered as independent observations.

NARSTO PAC2001 CONVAIR PM OZONE MET DATA

Atmospheric Science Data Center

2018-04-09

NARSTO PAC2001 CONVAIR PM OZONE MET DATA Project Title:  NARSTO Discipline:  Tropospheric Composition Field Campaigns Aerosols ... Temperature Probe Humidity Probe Wind Sensor UV Ozone Detector Optical Counter Location:  Lower Fraser ...

NARSTO PAC2001 CESSNA VOC PM OZONE MET DATA

Atmospheric Science Data Center

2018-04-09

NARSTO PAC2001 CESSNA VOC PM OZONE MET DATA Project Title:  NARSTO Discipline:  Tropospheric Composition Field Campaigns Aerosols ... Temperature Probe Humidity Probe Wind Sensor UV Ozone Detector Optical Counter GC Location:  Lower Fraser ...

Management of Chronic Periodontitis Using Subgingival Irrigation of Ozonized Water: A Clinical and Microbiological Study

PubMed Central

Mathew, Jayan Jacob; Ambooken, Majo; Kachappilly, Arun Jose; PK, Ajithkumar; Johny, Thomas; VK, Linith; Samuel, Anju

2015-01-01

Introduction Adjunctive use of professional subgingival irrigation with scaling and root planing (SRP) has been found to be beneficial in eradicating the residual microorganisms in the pocket. Objective To evaluate the effect of ozonized water subgingival irrigation on microbiologic parameters and clinical parameters namely Gingival index, probing pocket depth, and clinical attachment level. Materials and Methods Thirty chronic periodontitis patients with probing pocket depth ≥6mm on at least one tooth on contra lateral sides of opposite arches were included in the study. The test sites were subjected to ozonized water subgingival irrigation with subgingival irrigation device fitted with a modified subgingival tip. Control sites were subjected to scaling and root planing only. The following clinical parameters were recorded initially and after 4 weeks at the test sites and control sites. Plaque Index, Gingival Index, probing pocket depth, clinical attachment level. Microbiologic sampling was done for the test at the baseline, after scaling, immediately after ozonized water subgingival irrigation and after 4 weeks. In control sites microbiologic sampling was done at the baseline, after scaling and after 4 weeks. The following observations were made after 4 weeks. The results were statistically analysed using independent t-test and paired t-test. Result Test sites showed a greater reduction in pocket depth and gain in clinical attachment compared to control sites. The total anaerobic counts were significantly reduced by ozonized water subgingival irrigation along with SRP compared to SRP alone. Conclusion Ozonized water subgingival irrigation can improve the clinical and microbiological parameters in patients with chronic periodontitis when used as an adjunct to scaling and root planing. PMID:26436042

Determination of oxidant exposure during ozonation of secondary effluent to predict contaminant removal.

PubMed

Zucker, Ines; Avisar, Dror; Mamane, Hadas; Jekel, Martin; Hübner, Uwe

2016-09-01

The use of kinetic models to predict oxidation performance in wastewater is limited due to fast ozone depletion during the first milliseconds of the reaction. This paper introduces the Quench Flow Module (QFM), a bench-scale experimental technique developed to measure the first 5-500 milliseconds of ozone depletion for accurate determination of ozone exposure in wastewater-ozonation processes. Calculated ozone exposure in QFM experiments was up to 24% lower than in standard batch experiments, strongly depending on the initial sampling point for measurement in batch experiments. However, oxidation rates of slowly- and moderately-reacting trace organic compounds (TrOCs) were accurately predicted from batch experiments based on integration of ozone depletion and removal of an ozone-resistant probe compound to calculate oxidant exposures. An alternative concept, where ozone and hydroxyl radical exposures are back-calculated from the removal of two probe compounds, was tested as well. Although the QFM was suggested to be an efficient mixing reactor, ozone exposure ranged over three orders of magnitude when different probe compounds reacting moderately with ozone were used for the calculation. These effects were beyond uncertainty ranges for apparent second order rate constants and consistently observed with different ozone-injection techniques, i.e. QFM, batch experiments, bubble columns and venturi injection. This indicates that previously suggested mixing effects are not responsible for the difference and other still unknown factors might be relevant. Results furthermore suggest that ozone exposure calculations from the relative residual concentration of a probe compound are not a promising option for evaluation of ozonation of secondary effluents. Copyright © 2016 Elsevier Ltd. All rights reserved.

Tropospheric Ozone Pollution from Space: New Views from the TOMS (Total Ozone Mapping Spectrometer) Instrument

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Hudson, Robert D.; Frolov, Alexander D.; Witte, Jacquelyn C.; Kucsera, Tom L.; Einaudi, Franco (Technical Monitor)

2000-01-01

New products from the TOMS (Total Ozone Mapping Spectrometer) >satellite instrument can resolve pollution events in tropical and mid-latitudes, Over the past several years, we have developed tropospheric ozone data sets by two methods. The modified-residual technique [Hudson and Thompson, 1998; Thompson and Hudson, 1999] uses v. 7 TOMS total ozone and is applicable to tropical regimes in which the wave-one pattern in total ozone is observed. The TOMSdirect method [Hudson et at., 2000] represents a new algorithm that uses TOMS radiances to extract tropospheric ozone in regions of constant stratospheric ozone and tropospheric ozone displaying high mixing ratios and variability characteristic of pollution, Absorbing aerosols (dust and smoke; Herman et at., 1997 Hsu et al., 1999), a standard TOMS product, provide transport and/or source marker information to interpret tropospheric ozone. For the Nimbus 7/TOMS observing period (1979-1992), modified-residual TTO (tropical tropospheric ozone) appears as two maps/month at I-degree latitude 2-degree longitude resolution at a homepage and digital data are available (20S to 20N) by ftp at http://metosrv2. umd.edu/tropo/ 14y_data.d. Preliminary modified-residual TTO data from the operational Earth-Probe/TOMS (1996- present) are posted in near-real-time at the same website. Analyses with the new tropospheric ozone and aerosol data are illustrated by the following (I)Signals in tropical tropospheric ozone column and smoke amount during ENSO (El Nino-Southern Oscillation) events, e.g. 1982-1983 and the intense ENSO induced biomass fires of 1997-1998 over the Indonesian region [Thompson et a[, 2000a, Thompson and Hudson, 1999]. (2) Trends in tropospheric ozone and smoke aerosols in various tropical regions (Atlantic, Pacific, Africa, Brazil). No significant trends were found for ozone from1980-1990 [Thompson and Hudson, 19991 although smoke aerosols increased during the period [Hsu et al.,1999]. (3) Temporal and spatial offsets ("paradoxes") in tropical tropospheric ozone and smoke aerosol in regions of greatest tropical biomass burning [Thompson et at., 1996;2000b]. (4) Trans-boundary pollution tracking. With an air parcel (trajectory) model, smoke aerosol and ozone and dust plumes can be tracked across oceans (e.g., Asia to North America; North America to Europe) and national boundaries, e.g. Indonesia to Singapore and Malaysia during the 1997 ENSO fires.

The Contribution of TOMS and UARS Data to Our Understanding of Ozone Change

NASA Technical Reports Server (NTRS)

Bhartia, Pawan K.; Einaudi, Franco (Technical Monitor)

2001-01-01

Both TOMS (Total Ozone Mapping Spectrometer) and UARS (Upper Atmosphere Research Satellite) have operated over an extended period, and generated data sets of sufficient accuracy to be of use in determining ozone change (TOMS) and some of the underlying causes (UARS). The basic scientific products have been used for model validation and assimilation to extend our understanding of stratospheric processes. TOMS on Nimbus-7, Earth-Probe, and QuikTOMS, and UARS have led to the next generation of instruments onboard the EOS platforms. Algorithms used for TOMS and UARS are being applied to the new data sets and extended to analysis of European satellite data (e.g., GOME)

Southern Hemisphere Additional Ozonesondes (SHADOZ) Ozone Climatology (2005-2009): Tropospheric and Tropical Tropopause Layer (TTL) Profiles with Comparisons to Omi-based Ozone Products

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Miller, Sonya K.; Tilmes, Simone; Kollonige, Debra W.; Witte, Jacquelyn C.; Oltmans, Samuel J.; Johnson, Brian J.; Fujiwara, Masatomo; Schmidlin, F. J.; Coetzee, G. J. R.;

Southern Hemisphere Additional Ozonesondes (SHADOZ) ozone climatology (2005-2009): Tropospheric and tropical tropopause layer (TTL) profiles with comparisons to OMI-based ozone products

NASA Astrophysics Data System (ADS)

Thompson, Anne M.; Miller, Sonya K.; Tilmes, Simone; Kollonige, Debra W.; Witte, Jacquelyn C.; Oltmans, Samuel J.; Johnson, Bryan J.; Fujiwara, Masatomo; Schmidlin, F. J.; Coetzee, G. J. R.; Komala, Ninong; Maata, Matakite; Bt Mohamad, Maznorizan; Nguyo, J.; Mutai, C.; Ogino, S.-Y.; da Silva, F. Raimundo; Leme, N. M. Paes; Posny, Francoise; Scheele, Rinus; Selkirk, Henry B.; Shiotani, Masato; Stübi, René; Levrat, Gilbert; Calpini, Bertrand; Thouret, ValéRie; Tsuruta, Haruo; Canossa, Jessica Valverde; VöMel, Holger; Yonemura, S.; Diaz, Jorge AndréS.; Tan Thanh, Nguyen T.; Thuy Ha, Hoang T.

2012-12-01

We present a regional and seasonal climatology of SHADOZ ozone profiles in the troposphere and tropical tropopause layer (TTL) based on measurements taken during the first five years of Aura, 2005-2009, when new stations joined the network at Hanoi, Vietnam; Hilo, Hawaii; Alajuela/Heredia, Costa Rica; Cotonou, Benin. In all, 15 stations operated during that period. A west-to-east progression of decreasing convective influence and increasing pollution leads to distinct tropospheric ozone profiles in three regions: (1) western Pacific/eastern Indian Ocean; (2) equatorial Americas (San Cristóbal, Alajuela, Paramaribo); (3) Atlantic and Africa. Comparisons in total ozone column from soundings, the Ozone Monitoring Instrument (OMI, on Aura, 2004-) satellite and ground-based instrumentation are presented. Most stations show better agreement with OMI than they did for EP/TOMS comparisons (1998-2004; Earth-Probe/Total Ozone Mapping Spectrometer), partly due to a revised above-burst ozone climatology. Possible station biases in the stratospheric segment of the ozone measurement noted in the first 7 years of SHADOZ ozone profiles are re-examined. High stratospheric bias observed during the TOMS period appears to persist at one station. Comparisons of SHADOZ tropospheric ozone and the daily Trajectory-enhanced Tropospheric Ozone Residual (TTOR) product (based on OMI/MLS) show that the satellite-derived column amount averages 25% low. Correlations between TTOR and the SHADOZ sondes are quite good (typical r2= 0.5-0.8), however, which may account for why some published residual-based OMI products capture tropospheric interannual variability fairly realistically. On the other hand, no clear explanations emerge for why TTOR-sonde discrepancies vary over a wide range at most SHADOZ sites.

Discoveries about Tropospheric Ozone Pollution from Satellite and Soundings

NASA Technical Reports Server (NTRS)

Thompson, Anne M.

2004-01-01

We have been producing near-red time tropospheric ozone satellite maps from the TOMS (Total Ozone Mapping Spectrometer) sensor since 1997. Maps for 1996-2000 for the operational Earth-Probe instrument are at:. Pollution in the tropics is influenced by biomass burning and by transport patterns that favor recirculation and in other cases reflect climate variability like the El-Nino-Southern Oscillation [Thompson et al., 2001]. The satellite view of chemical-dynamical interactions in tropospheric ozone is not adequate to capture vertical gradients in pollution. Thus, in 1998, NASA's Goddard Space Flight Center and a team of international sponsors established the SHADOZ (Southern Hemisphere ADditional OZonesondes) project to address the gap in tropical ozone soundings. SHADOZ augments launches and provides a public archive of ozonesonde data from twelve tropical stations at http://croc.gsfc.nasa.gov/shadoz. Further insights into the role of chemical and dynamical influences have emerged from the first 4-5 years of SHADOZ data (more than 2000 ozone profiles). Highly variable tropospheric ozone and a zonal wave-one pattern in tropospheric ozone suggest that dynamics is as important as pollution in determining tropical ozone distributions.

Tropical Tropospheric Ozone: New Insights from Remote Sensing, Sondes and Field Studies

NASA Technical Reports Server (NTRS)

Thompson, Anne M.

1999-01-01

This talk will summarize our recent research in tropical tropospheric ozone studies in the field and from space. New tropospheric ozone and aerosol products from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument will be highlighted (Hudson and Thompson, 1998; Thompson and Hudson, 1999). These are suitable for studying processes like ozone pollution resulting from biomass fires, seasonal and interannual variations and trends. Archived maps of tropospheric ozone over the tropics, from the Nimbus 7 observing period (1979-1992) are available in digital form at our website: http://metosrv2.umd.edu/-tropo. Real-time processing of TOMS data has produced images of tropical tropospheric ozone (TTO) since early 1997, using Earth-Probe TOMS; these maps are also available on the homepage. The need for validation data for TTO maps has led to establishment of the NASA/NOAA-sponsored SHADOZ (Southern Hemisphere Additional Ozonesondes) network, from which a 2-year record of high-quality ozonesonde data can be obtained: (http://hyperion.gsfc.nasa.gov/Data-services/Shadoz/shadoz-hmpg2.htrnl). Examples will be shown, along with ozonesondes from the January-February 1999 Aerosols-99 cruise of the R/V Ronald H Brown from Virginia to Cape Town, South Africa.

Discoveries about Tropospheric Ozone Pollution from Satellite and Sounding

NASA Technical Reports Server (NTRS)

Thompson, Anne M.

2004-01-01

We have been producing near-real time tropospheric ozone satellite maps from the TOMS (Total Ozone Mapping Spectrometer) sensor since 1997. This is most readily done for the tropics, where the stratospheric and tropospheric ozone column amounts can be discriminated readily. Maps for 1996-2000 for the operational Earth-Probe instrument reside at: chttp://www.atmos.umd.edu/-trope>. Pollution in the tropics is influenced by biomass burning and by transport patterns that favor recirculation and in other cases reflect climate variability like the El-Nino-Southern Oscillation [Thompson et al., 2001]. Time permitting, examples of mid-latitude, intercontinental transport of ozone pollution sensed by TOMS will be shown. The satellite view of chemical-dynamical interactions in tropospheric ozone is not adequate to capture vertical variability. Thus, in 1998, NASA's Goddard Space Flight Center and a team of international sponsors established the SHADOZ (Southern Hemisphere ADditional OZonesondes) project to address the gap in tropical ozone soundings. SHADOZ augments launches and provides a public archive of ozonesonde data from twelve tropical stations at http://croc.gsfc.nasa.gov/shadoz. Further insights into the role of chemical and dynamical influences have emerged from the first 4-5 years of SHADOZ data (less than 2000 ozone profiles): (a) highly variable tropospheric ozone; (b) a zonal wave-one pattern in tropospheric column ozone; (c) convective variability affects tropospheric ozone over the Indian and Pacific Ocean; (d) a "tropical Atlantic Paradox" appears in December-January-February.

HYDROXYL RADICAL/OZONE RATIOS DURING OZONATION PROCESSES. I. THE RCT CONCEPT

EPA Science Inventory

The ozonation of model systems and several natural waters was examined in bench-scale batch experiments. In addition to measuring the concentration of ozone (03), the rate of depletion of an in situ hydroxyl radical probe compound was monitored, thus providing information on the ...

Contingency maneuver strategies for the Total Ozone Mapping Spectrometer-Earth Probe (TOMS-EP)

NASA Technical Reports Server (NTRS)

Kestler, James; Walls, Donna

1995-01-01

The Total Ozone Mapping Spectrometer-Earth Probe (TOMS-EP) is a polar-orbiting spacecraft designed to measure total ozone levels in the Earth's atmosphere. The nominal mission orbit is a 955-kilometer circular Sun-synchronous orbit with an ascending node mean local crossing time (MLT) between 11:02 a.m. and 11:25 a.m. These two mean local ascending node times constitute the boundaries of the MLT box for this mission. The MLT boundaries were chosen to maintain the Sun-to-Earth-to-vehicle orbit-normal (SVN) angle within a preselected set of seasonally independent boundaries. Because the SVN angle is seasonally dependent, but the MLT is not, contingency options for correcting the MLT of orbital states that fall outside of the required MLT range become time dependent. This paper focuses on contingency orbit adjustment strategies developed at the Goddard Space Flight Center (GSFC) Flight Dynamics Division (FDD) during the mission planning phase of TOMS-EP. Time-dependent delta-V strategies are presented for correcting mission orbit states lying outside of the MLT range. Typically, passive control of the MLT drift rate can be used to restore the orbit state to the required MLT before a seasonal violation of SVN angle constraints can occur. Passive control of the MLT drift rate is obtained through adjustment of the semimajor axis and/or the inclination. The time between initial arrival on orbit at an 'out-of-the box' MLT state and violation of the SVN angle constraints is always less than or equal to 1 year. The choice of which parameter(s) to adjust is dictated by the duration of this time period, the desired mission lifetime, the delta-V cost, and operational constraints.

Numerical modeling of particle generation from ozone reactions with human-worn clothing in indoor environments

NASA Astrophysics Data System (ADS)

Rai, Aakash C.; Lin, Chao-Hsin; Chen, Qingyan

2015-02-01

Ozone-terpene reactions are important sources of indoor ultrafine particles (UFPs), a potential health hazard for human beings. Humans themselves act as possible sites for ozone-initiated particle generation through reactions with squalene (a terpene) that is present in their skin, hair, and clothing. This investigation developed a numerical model to probe particle generation from ozone reactions with clothing worn by humans. The model was based on particle generation measured in an environmental chamber as well as physical formulations of particle nucleation, condensational growth, and deposition. In five out of the six test cases, the model was able to predict particle size distributions reasonably well. The failure in the remaining case demonstrated the fundamental limitations of nucleation models. The model that was developed was used to predict particle generation under various building and airliner cabin conditions. These predictions indicate that ozone reactions with human-worn clothing could be an important source of UFPs in densely occupied classrooms and airliner cabins. Those reactions could account for about 40% of the total UFPs measured on a Boeing 737-700 flight. The model predictions at this stage are indicative and should be improved further.

A Total Ozone Dependent Ozone Profile Climatology Based on Ozone-Sondes and Aura MLS Data

NASA Astrophysics Data System (ADS)

Labow, G. J.; McPeters, R. D.; Ziemke, J. R.

2014-12-01

A new total ozone-based ozone profile climatology has been created for use in satellite and/or ground based ozone retrievals. This climatology was formed by combining data from the Microwave Limb Sounder (MLS) with data from balloon sondes and binned by zone and total ozone. Because profile shape varies with total column ozone, this climatology better captures the ozone variations than the previously used seasonal climatologies, especially near the tropopause. This is significantly different than ozone climatologies used in the past as there is no time component. The MLS instrument on Aura has excellent latitude coverage and measures ozone profiles daily from the upper troposphere to the lower mesosphere at ~3.5 km resolution. Almost a million individual MLS ozone measurements are merged with data from over 55,000 ozonesondes which are then binned as a function of total ozone. The climatology consists of average ozone profiles as a function of total ozone for six 30 degree latitude bands covering altitudes from 0-75 km (in Z* pressure altitude coordinates). This new climatology better represents the profile shape as a function of total ozone than previous climatologies and shows some remarkable and somewhat unexpected correlations between total ozone and ozone in the lower altitudes, particularly in the lower and middle troposphere. These data can also be used to infer biases and errors in either the MLS retrievals or ozone sondes.

Plasma Assisted Combustion: Flame Regimes and Kinetic Studies

DTIC Science & Technology

2015-01-05

Kinetic model Fuel: Dimethyl ether Oxidizer= (1-x)O2 + xO3, x=0 - 0.1, p=1 atm Ozone chemistry & Dimethyl ether model ...diffusional cool flames • A heated counterflow burner integrated with vaporization system1 • n-heptane/nitrogen vs. oxygen/ ozone • Ozone generator...micro-DBD) produces 2- 5 % of ozone in oxygen stream, depending on oxygen flow rate • Speciation profiles by using a micro-probe sampling with a

Detection and quantification of reactive oxygen species (ROS) in indoor air.

PubMed

Montesinos, V Nahuel; Sleiman, Mohamad; Cohn, Sebastian; Litter, Marta I; Destaillats, Hugo

2015-06-01

Reactive oxygen species (ROS), such as free radicals and peroxides, are environmental trace pollutants potentially associated with asthma and airways inflammation. These compounds are often not detected in indoor air due to sampling and analytical limitations. This study developed and validated an experimental method to sample, identify and quantify ROS in indoor air using fluorescent probes. Tests were carried out simultaneously using three different probes: 2',7'-dichlorofluorescin (DCFH) to detect a broad range of ROS, Amplex ultra Red® (AuR) to detect peroxides, and terephthalic acid (TPA) to detect hydroxyl radicals (HO(•)). For each test, air samples were collected using two impingers in series kept in an ice bath, containing each 10 mL of 50 mM phosphate buffer at pH 7.2. In tests with TPA, that probe was also added to the buffer prior to sampling; in the other two tests, probes and additional reactants were added immediately after sampling. The concentration of fluorescent byproducts was determined fluorometrically. Calibration curves were developed by reacting DCFH and AuR with known amounts of H2O2, and using known amounts of 2-hydroxyterephthalic acid (HTPA) for TPA. Low detection limits (9-13 nM) and quantification limits (18-22 nM) were determined for all three probes, which presented a linear response in the range 10-500 nM for AuR and TPA, and 100-2000 nM for DCFH. High collection efficiency (CE) and recovery efficiency (RE) were observed for DCFH (CE=RE=100%) and AuR (CE=100%; RE=73%) by sampling from a laboratory-developed gas phase H2O2 generator. Interference of co-occurring ozone was evaluated and quantified for the three probes by sampling from the outlet of an ozone generator. The method was demonstrated by sampling air emitted by two portable air cleaners: a strong ozone generator (AC1) and a plasma generator (AC2). High ozone levels emitted by AC1 did not allow for simultaneous determination of ROS levels due to high background levels associated with ozone decomposition in the buffer. However, emitted ROS were quantified at the outlet of AC2 using two of the three probes. With AuR, the concentration of peroxides in air emitted by the air cleaner was 300 ppt of H2O2 equivalents. With TPA, the HO(•) concentration was 47 ppt. This method is best suited to quantify ROS in the presence of low ozone levels. Published by Elsevier B.V.

Annual and Seasonal Global Variation in Total Ozone and Layer-Mean Ozone, 1958-1987 (1991)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Angell, J. K.; Korshover, J.; Planet, W. G.

For 1958 through 1987, this data base presents total ozone variations and layer mean ozone variations expressed as percent deviations from the 1958 to 1977 mean. The total ozone variations were derived from mean monthly ozone values published in Ozone Data for the World by the Atmospheric Environment Service in cooperation with the World Meteorological Organization. The layer mean ozone variations are derived from ozonesonde and Umkehr observations. The data records include year, seasonal and annual total ozone variations, and seasonal and annual layer mean ozone variations. The total ozone data are for four regions (Soviet Union, Europe, North America,more » and Asia); five climatic zones (north and south polar, north and south temperate, and tropical); both hemispheres; and the world. Layer mean ozone data are for four climatic zones (north and south temperate and north and south polar) and for the stratosphere, troposphere, and tropopause layers. The data are in two files [seasonal and year-average total ozone (13.4 kB) and layer mean ozone variations (24.2 kB)].« less

A reanalysis of ozone on Mars from assimilation of SPICAM observations

NASA Astrophysics Data System (ADS)

Holmes, James A.; Lewis, Stephen R.; Patel, Manish R.; Lefèvre, Franck

2018-03-01

We have assimilated for the first time SPICAM retrievals of total ozone into a Martian global circulation model to provide a global reanalysis of the ozone cycle. Disagreement in total ozone between model prediction and assimilation is observed between 45°S-10°S from LS = 135-180° and at northern polar (60°N-90°N) latitudes during northern fall (LS = 150-195°). Large percentage differences in total ozone at northern fall polar latitudes identified through the assimilation process are linked with excessive northward transport of water vapour west of Tharsis and over Arabia Terra. Modelling biases in water vapour can also explain the underestimation of total ozone between 45°S-10°S from LS = 135-180°. Heterogeneous uptake of odd hydrogen radicals are unable to explain the outstanding underestimation of northern polar total ozone in late northern fall. Assimilation of total ozone retrievals results in alterations of the modelled spatial distribution of ozone in the southern polar winter high altitude ozone layer. This illustrates the potential use of assimilation methods in constraining total ozone where SPICAM cannot observe, in a region where total ozone is especially important for potential investigations of the polar dynamics.

NARSTO ICARTT NEAX 2004 DOE G-1 DATA

Atmospheric Science Data Center

2018-04-09

... Probe Chemiluminescence UV Ozone Detector Pulsed Fluorescence HPLC Aerosol Spectrometer Probe Pyranometer Photometer ... Carbon Monixide Hydrogen Peroxide Sulfate Particles Nitrate Particles Crustal Particles Order Data:  ...

Derivation of Tropospheric Column Ozone from the EPTOMS/GOES Co-Located Data Sets using the Cloud Slicing Technique

NASA Technical Reports Server (NTRS)

Ahn, C.; Ziemke, J. R.; Chandra, S.; Bhartia, P. K.

2002-01-01

A recently developed technique called cloud slicing used for deriving upper tropospheric ozone from the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) instrument combined together with temperature-humidity and infrared radiometer (THIR) is no longer applicable to the Earth Probe TOMS (EPTOMS) because EPTOMS does not have an instrument to measure cloud top temperatures. For continuing monitoring of tropospheric ozone between 200-500hPa and testing the feasibility of this technique across spacecrafts, EPTOMS data are co-located in time and space with the Geostationary Operational Environmental Satellite (GOES)-8 infrared data for 2001 and early 2002, covering most of North and South America (45S-45N and 120W-30W). The maximum column amounts for the mid-latitudinal sites of the northern hemisphere are found in the March-May season. For the mid-latitudinal sites of the southern hemisphere, the highest column amounts are found in the September-November season, although overall seasonal variability is smaller than those of the northern hemisphere. The tropical sites show the weakest seasonal variability compared to higher latitudes. The derived results for selected sites are cross validated qualitatively with the seasonality of ozonesonde observations and the results from THIR analyses over the 1979-1984 time period due to the lack of available ozonesonde measurements to study sites for 2001. These comparisons show a reasonably good agreement among THIR, ozonesonde observations, and cloud slicing-derived column ozone. With very limited co-located EPTOMS/GOES data sets, the cloud slicing technique is still viable to derive the upper tropospheric column ozone. Two new variant approaches, High-Low (HL) cloud slicing and ozone profile derivation from cloud slicing are introduced to estimate column ozone amounts using the entire cloud information in the troposphere.

Climatology of equatorial stratosphere over Lagos, Nigeria

NASA Astrophysics Data System (ADS)

Oyekola, Oyedemi Samuel

We have used 12 complete calendar years (January 1993-December 2004) of monthly averages of measurements made by the Dobson spectrophotometer instrument over an urban site, Lagos (6.6oN, 3.3oE), southwest Nigeria, to study equatorial stratospheric column ozone variations and trends. Our results indicate that the time-averaged total column ozone has a seasonal cy-cle, which maximizes in June and July with a value of 259 Dobson units (DU) and minimizes in February with a magnitude of 250 DU. Statistical analysis of the climatological mean monthly total Dobson O3 record for 1993-2004 show that the local trend is approximately +0.041±0.0011 DU/year (+0.49±0.013% per decade). Spectral analysis was applied to the monthly averages series. The significant periodicity at 95% confidence level demonstrate prominent spectra peaks near 1.9 and 3.6 years, representative of quasi-biennial oscillation (QBO) and quasi-triennial oscillation (QTO), respectively. Signal due to semiannual variation is also identified at Lagos sounding site. Comparison with the ozone observations from Total Ozone Mapping Spectrom-eter (TOMS) on board the Earth-Probe (EP) satellite for the period from 1997 to 2002 reveal that EP/TOMS instrument consistently larger than the ground-based measurement from Dob-son station. Percentage mean relative disparity ranges from -11% to 15%. The root mean square error (RMSE) between satellite and ground-based observations over Lagos ranges be-tween ˜35-83 DU with largest and lowest variability occurring during the ascending phase of solar activity (1999, 10.7 cm radio flux, F10.7 equals 154 flux units) and during the peak phase of solar activity (2001, F10.7 equals 181), respectively.

Trends in total column ozone measurements

NASA Technical Reports Server (NTRS)

Rowland, F. S.; Angell, J.; Attmannspacher, W.; Bloomfield, P.; Bojkov, R. D.; Harris, N.; Komhyr, W.; Mcfarland, M.; Mcpeters, R.; Stolarski, R. S.

1989-01-01

It is important to ensure the best available data are used in any determination of possible trends in total ozone in order to have the most accurate estimates of any trends and the associated uncertainties. Accordingly, the existing total ozone records were examined in considerable detail. Once the best data set has been produced, the statistical analysis must examine the data for any effects that might indicate changes in the behavior of global total ozone. The changes at any individual measuring station could be local in nature, and herein, particular attention was paid to the seasonal and latitudinal variations of total ozone, because two dimensional photochemical models indicate that any changes in total ozone would be most pronounced at high latitudes during the winter months. The conclusions derived from this detailed examination of available total ozone can be split into two categories, one concerning the quality and the other the statistical analysis of the total ozone record.

Total ozone derived from UV spectrophotometer measurements on the NASA CV-990 aircraft for the fall 1976 latitude survey flights

NASA Technical Reports Server (NTRS)

Hanser, F. A.

1977-01-01

An ultraviolet interference filter spectrophotometer was modified to use a photodiode and was flown on latitude survey flights in the fall of 1976. Comparison with Dobson station total ozone values shows agreement between UVS and Dobson total ozone of + or - 2 percent. The procedure used to convert UVS measured ozone above the aircraft altitude to total ozone above ground level introduces an additional 2 percent deviation for very high altitude UVS ozone data. Under stable aircraft operating conditions, the UVS derived ozone values have a variability, or reproducibility, of better than + or -1 percent. The UVS data from the latitude survey flights yield a detailed latitude profile of total ozone over the Pacific Ocean during November 1976. Significant latitudinal structure in total ozone is found at the middle latitudes (30 deg to 40 deg N and S).

NASA satellite helps airliners avoid ozone concentrations

NASA Technical Reports Server (NTRS)

1981-01-01

Results from a test to determine the effectiveness of satellite data for helping airlines avoid heavy concentrations of ozone are reported. Information from the Total Ozone Mapping Spectrometer, aboard the Nimbus-7 was transmitted, for use in meteorological forecast activities. The results show: (1) Total Ozone Mapping Spectrometer profile of total ozone in the atmosphere accurately represents upper air patterns and can be used to locate meteorological activity; (2) route forecasting of highly concentrated ozone is feasible; (3) five research aircraft flights were flown in jet stream regions located by the Total Ozone Mapping Spectrometer to determine winds, temperatures, and air composition. It is shown that the jet stream is coincides with the area of highest total ozone gradient, and low total ozone amounts are found where tropospheric air has been carried along above the tropopause on the anticyclonic side of the subtropical jet stream.

Selected Measurements of Total Arctic Column Ozone Amounts from Aura Ozone Monitoring Instrument, 2004-2005 Arctic Winter

NASA Image and Video Library

2005-06-02

Images from the Ozone Monitoring Instrument onboard NASA Aura spacecraft shows the average total column ozone during the months of January and March, and the total column ozone on the single day of 11 March, 2005.

User's guide for SBUV/TOMS ozone derivative products

NASA Technical Reports Server (NTRS)

Fleig, A. J.; Wellemeyer, C.; Oslik, N.; Lee, D.; Miller, J.; Magatani, R.

1984-01-01

A series of products are available derived from the total-ozone and ozone vertical profile results for the Solar Backscattered Ultraviolet/Total-Ozone Mapping Spectrometer (SBUV/TOMS) Nimbus-7 operation. Products available are (1) orbital height-latitude cross sections of the SBUV profile data, (2) daily global total ozone contours in polar coordinates, (3) daily averages of total ozone in global 5x5 degree latitude-longitude grid, (4) daily, monthly and quarterly averages of total ozone and profile data in 10 degree latitude zones, (5) tabular presentation of zonal means, (6) daily global total ozone and profile contours in polar coordinates. The ""Derivative Products User's Guide'' describes each of these products in detail, including their derivation and presentation format. Information is provided on how to order the tapes and microfilm from the National Space Science Data Center.

Largest-ever Ozone Hole over Antarctica

NASA Technical Reports Server (NTRS)

2002-01-01

A NASA instrument has detected an Antarctic ozone 'hole' (what scientists call an 'ozone depletion area') that is three times larger than the entire land mass of the United States-the largest such area ever observed. The 'hole' expanded to a record size of approximately 11 million square miles (28.3 million square kilometers) on Sept. 3, 2000. The previous record was approximately 10.5 million square miles (27.2 million square km) on Sept. 19, 1998. The ozone hole's size currently has stabilized, but the low levels in its interior continue to fall. The lowest readings in the ozone hole are typically observed in late September or early October each year. 'These observations reinforce concerns about the frailty of Earth's ozone layer. Although production of ozone-destroying gases has been curtailed under international agreements, concentrations of the gases in the stratosphere are only now reaching their peak. Due to their long persistence in the atmosphere, it will be many decades before the ozone hole is no longer an annual occurrence,' said Dr. Michael J. Kurylo, manager of the Upper Atmosphere Research Program, NASA Headquarters, Washington, DC. Ozone molecules, made up of three atoms of oxygen, comprise a thin layer of the atmosphere that absorbs harmful ultraviolet radiation from the Sun. Most atmospheric ozone is found between approximately six miles (9.5 km) and 18 miles (29 km) above the Earth's surface. Scientists continuing to investigate this enormous hole are somewhat surprised by its size. The reasons behind the dimensions involve both early-spring conditions, and an extremely intense Antarctic vortex. The Antarctic vortex is an upper-altitude stratospheric air current that sweeps around the Antarctic continent, confining the Antarctic ozone hole. 'Variations in the size of the ozone hole and of ozone depletion accompanying it from one year to the next are not unexpected,' said Dr. Jack Kaye, Office of Earth Sciences Research Director, NASA Headquarters. 'At this point we can only wait to see how the ozone hole will evolve in the coming few months and see how the year's hole compares in all respects to those of previous years.' 'Discoveries like these demonstrate the value of our long-term commitment to providing key observations to the scientific community,' said Dr. Ghassem Asrar, Associate Administrator for NASA's Office of Earth Sciences at Headquarters. 'We will soon launch QuickTOMS and Aura, two spacecraft that will continue to gather these important data.' The measurements released today were obtained using the Total Ozone Mapping Spectrometer (TOMS) instrument aboard NASA's Earth Probe (TOMS-EP) satellite. NASA instruments have been measuring Antarctic ozone levels since the early 1970s. Since the discovery of the ozone 'hole' in 1985, TOMS has been a key instrument for monitoring ozone levels over the Earth. TOMS ozone data and more pictures are available at: http://toms.gsfc.nasa.gov/ TOMS-EP and other ozone-measurement programs are important parts of a global environmental effort of NASA's Earth Science enterprise, a long-term research program designed to study Earth's land, oceans, atmosphere, ice and life as a total integrated system. For more information about ozone and ozone loss, visit: Ozone in the Stratosphere. Image courtesy the TOMS science team and and the Scientific Visualization Studio, NASA GSFC

The Transition of Atmospheric Infrared Sounder Total Ozone Products to Operations

NASA Technical Reports Server (NTRS)

Berndt, E. B.; Zavodsky, B. T.; Jedlovec, G. J.

2014-01-01

The National Aeronautics and Space Administration Short-term Prediction Research and Transition Center (NASA SPoRT) has transitioned a total column ozone product from the Atmospheric Infrared Sounder (AIRS) retrievals to the Weather Prediction Center and Ocean Prediction Center. The total column ozone product is used to diagnose regions of warm, dry, ozone-rich, stratospheric air capable of descending to the surface to create high-impact non-convective winds. Over the past year, forecasters have analyzed the Red, Green, Blue (RGB) Air Mass imagery in conjunction with the AIRS total column ozone to aid high wind forecasts. One of the limitations of the total ozone product is that it is difficult for forecasters to determine whether elevated ozone concentrations are related to stratospheric air or climatologically high values of ozone in certain regions. During the summer of 2013, SPoRT created an AIRS ozone anomaly product which calculates the percent of normal ozone based on a global stratospheric ozone mean climatology. With the knowledge that ozone values 125 percent of normal and greater typically represent stratospheric air; the anomaly product can be used with the total column ozone product to confirm regions of stratospheric air. This paper describes the generation of these products along with forecaster feedback concerning the use of the AIRS ozone products in conjunction with the RGB Air Mass product to access the utility and transition of the products.

The characterization of an air pollution episode using satellite total ozone measurements

NASA Technical Reports Server (NTRS)

Fishman, Jack; Shipham, Mark C.; Vukovich, Fred M.; Cahoon, Donald R.

1987-01-01

A case study is presented which demonstrates that measurements of total ozone from a space-based platform can be used to study a widespread air pollution episode over the southeastern U.S. In particular, the synoptic-scale distribution of surface-level ozone obtained from an independent analysis of ground-based monitoring stations appears to be captured by the synoptic-scale distribution of total ozone, even though about 90 percent of the total ozone is in the stratosphere. Additional analyses of upper air meteorological data, other satellite imagery, and in situ aircraft measurements of ozone likewise support the fact that synoptic-scale variability of tropospheric ozone is primarily responsible for the observed variability in total ozone under certain conditions. The use of the type of analysis discussed in this study may provide an important technique for understanding the global budget of tropospheric ozone.

Convective Distribution of Tropospheric Ozone and Tracers in the Central American ITCZ Region: Evidence from Observations During TC4

NASA Technical Reports Server (NTRS)

Avery, Melody; Twohy, Cynthia; MCabe, David; Joiner, Joanna; Severance, Kurt; Atlas, Eliot; Blake, Donald; Bui, T. P.; Crounse, John; Dibb, Jack;

An intercomparison of multidecadal observational and reanalysis data sets for global total ozone trends and variability analysis

NASA Astrophysics Data System (ADS)

Bai, Kaixu; Chang, Ni-Bin; Shi, Runhe; Yu, Huijia; Gao, Wei

2017-07-01

A four-step adaptive ozone trend estimation scheme is proposed by integrating multivariate linear regression (MLR) and ensemble empirical mode decomposition (EEMD) to analyze the long-term variability of total column ozone from a set of four observational and reanalysis total ozone data sets, including the rarely explored ERA-Interim total ozone reanalysis, from 1979 to 2009. Consistency among the four data sets was first assessed, indicating a mean relative difference of 1% and root-mean-square error around 2% on average, with respect to collocated ground-based total ozone observations. Nevertheless, large drifts with significant spatiotemporal inhomogeneity were diagnosed in ERA-Interim after 1995. To emphasize long-term trends, natural ozone variations associated with the solar cycle, quasi-biennial oscillation, volcanic aerosols, and El Niño-Southern Oscillation were modeled with MLR and then removed from each total ozone record, respectively, before performing EEMD analyses. The resulting rates of change estimated from the proposed scheme captured the long-term ozone variability well, with an inflection time of 2000 clearly detected. The positive rates of change after 2000 suggest that the ozone layer seems to be on a healing path, but the results are still inadequate to conclude an actual recovery of the ozone layer, and more observational evidence is needed. Further investigations suggest that biases embedded in total ozone records may significantly impact ozone trend estimations by resulting in large uncertainty or even negative rates of change after 2000.

Vertical distribution of ozone and the variation of tropopause heights based on ozonesonde and satellite observations. [Contract title: Internal Wave Motion

NASA Technical Reports Server (NTRS)

Hung, R. J.; Liu, J. M.

1986-01-01

The distribution of atmospheric ozone is nonuniform both in space and time. Local ozone concentration vary with altitude, latitude, longitude, and season. Two year ozonesonde data, January 1981 to December 1982, observed at four Canadian stations and 2.5 year backscattered ultraviolet experiment data on the Nimbus-4 satellite, April 1970 to August 1972, observed over five American stations were used to study the relationship between the total ozone, vertical height distribution of the ozone mixing ratio, vertical height distribution of half total ozone, and the local tropopause height. The results show that there is a postive correlation between total ozone in Dobson Units and the tropopause height in terms of atmospheric pressure. This result suggests that local intrusion of the statosphere into the troposphere, or the local decreasing of tropopause height could occur if there is a local increasing of total ozone. A comparison of the vertical height distribution of the ozone mixing ratio, the modified pressure height of half total ozone and the tropopause height shows that the pressure height of an ozone mixing ratio of 0.3 micrograms/g, and the modified pressure height of half total ozone are very well correlated with the tropopause pressure height.

Total ozone influence on the surface UV-B radiation in the late spring-summer 1963-1997: An analysis of multiple timescales

NASA Astrophysics Data System (ADS)

KrzyśCin, Janusz W.

2000-02-01

Monthly means and minima of total ozone for the late springs and summers (May-August) of 1963-1997 have been examined for the European Dobson stations (Arosa, Belsk, Hohenpeissenberg, Hradec Kralove, Uccle). It is shown that long-term tendencies in total ozone means were almost similar to those in the total ozone minima. Analyses of the late spring/summer means of UV daily doses, total ozone, and global solar radiation (proxy for the overall atmospheric transparency), measured at Belsk (52°N, 21°E) for the period 1976-1996, show that an importance of the total ozone changes for the UV-B level increases with the timescale. Decadal variations in total ozone are the main source of the UV trend at Belsk. Frequency of appearance of extreme daily total ozone values in the selected late spring/summer season seems to be important for analyses of the ozone forcing in the interannual timescale. Regional and temporal differences in the number of days with extreme low ozone values are discussed using the total ozone extrema taken at Arosa, Belsk, and Hradec Kralove in the 1963-1997 period. A statistical model is developed for diagnosis of the next day value of the UV-B level. The changes in the overall atmospheric transparency are essential for the UV-B level when the day-to-day variations in the UV forcing factors are examined.

On the link between martian total ozone and potential vorticity

NASA Astrophysics Data System (ADS)

Lewis, S.; Holmes, J.; Patel, M.

2016-12-01

We demonstrate for the first time that total ozone in the martian atmosphere is highly correlated with the dynamical tracer, potential vorticity, under certain conditions. The degree of correlation is investigated using a Mars global circulation model including a photochemical model. Potential vorticity is the quantity of choice to explore the dynamical nature of polar vortices because it contains information on winds and temperature in a single scalar variable.The correlation is found to display a distinct seasonal variation, with a strong positive correlation in both northern and southern winter at poleward latitudes in the northern and southern hemisphere respectively. The identified strong correlation implies variations in polar total ozone during winter are predominantly controlled by dynamical processes in these spatio-temporal regions. The weak correlation in northern and southern summer is due to the dominance of photochemical reactions resulting from extended exposure to sunlight. The total ozone/potential vorticity correlation is slightly weaker in southern winter due to topographical variations and the preference for ozone to accumulate in Hellas basin. In northern winter, total ozone can be used to track the polar vortex edge. The ozone/potential vorticity ratio is calculated for both northern and southern winter on Mars for the first time. Using the strong correlation in total ozone and potential vorticity in northern winter inside the polar vortex, it is shown that potential vorticity can be used as a proxy to deduce the distribution of total ozone where satellites cannot observe for the majority of northern winter. Where total ozone observations are available on the fringes of northern winter at poleward latitudes, the strong relationship of total ozone and potential vorticity implies that total ozone anomalies in the surf zone can be of use to investigate the origin of potential vorticity filaments.

On the link between martian total ozone and potential vorticity

NASA Astrophysics Data System (ADS)

Holmes, James A.; Lewis, Stephen R.; Patel, Manish R.

2017-01-01

We demonstrate for the first time that total ozone in the martian atmosphere is highly correlated with the dynamical tracer, potential vorticity, under certain conditions. The degree of correlation is investigated using a Mars global circulation model including a photochemical model. Potential vorticity is the quantity of choice to explore the dynamical nature of polar vortices because it contains information on winds and temperature in a single scalar variable. The correlation is found to display a distinct seasonal variation, with a strong positive correlation in both northern and southern winter at poleward latitudes in the northern and southern hemisphere respectively. The identified strong correlation implies variations in polar total ozone during winter are predominantly controlled by dynamical processes in these spatio-temporal regions. The weak correlation in northern and southern summer is due to the dominance of photochemical reactions resulting from extended exposure to sunlight. The total ozone/potential vorticity correlation is slightly weaker in southern winter due to topographical variations and the preference for ozone to accumulate in Hellas basin. In northern winter, total ozone can be used to track the polar vortex edge. The ozone/potential vorticity ratio is calculated for both northern and southern winter on Mars for the first time. Using the strong correlation in total ozone and potential vorticity in northern winter inside the polar vortex, it is shown that potential vorticity can be used as a proxy to deduce the distribution of total ozone where satellites cannot observe for the majority of northern winter. Where total ozone observations are available on the fringes of northern winter at poleward latitudes, the strong relationship of total ozone and potential vorticity implies that total ozone anomalies in the surf zone of the northern polar vortex can potentially be used to determine the origin of potential vorticity filaments.

The nature of the data

NASA Technical Reports Server (NTRS)

1981-01-01

The locations of total ozone stations and of stratospheric ozone samplings were presented. The samplings are concentrated in three areas: Japan, Europe, and India. Approximately 75% of the total ozone measurements are made with Dobson instruments which offer the best international measurements. When well calibrated their accuracy is on the order of a few percent. It is found that although the total ozone percent is similar in both hemispheres, the northern hemisphere has 3 to 10% more ozone than the southern hemisphere. The close association between total ozone distribution and pressure distribution in the atmosphere is noted.

Trend analysis of the homogenized total ozone series of Arosa (Switzerland), 1926-1996

NASA Astrophysics Data System (ADS)

Staehelin, Johannes; Kegel, Rainer; Harris, Neil R. P.

1998-04-01

Total ozone measurements have been made at Arosa, Switzerland (47°N), from 1926 through the present day, forming the longest total ozone series in the world. The record has been recently homogenized. Ozone trends are calculated to be -(2.3±0.6)% per decade for annual means (larger losses are found in winter and spring, approximately -4% per decade for trends in January, February, and March) when a simple linear change from 1970 to 1996 is assumed. In addition, total ozone trends are calculated using multiple regression models involving combinations of explanatory variables for the 11-year solar cycle, local meteorological conditions (the Mount Säntis high-altitude temperature record), stratospheric aerosol loading from volcanoes, and stratospheric chlorine loading. When the terms for the solar cycle, the stratospheric aerosol loading and the high mountain temperature record were included, the annually averaged ozone trends were found to be -(1.9±0.6)% per decade. While a statistically significant relation is found between total ozone and indices of aerosol loadings of the stratosphere, the recent decrease in total ozone cannot be accounted for by the higher average aerosol content in the second half of the century. Finally, the decrease in ozone in the stratosphere is estimated to be approximately 30% larger than that found for total ozone, when a crude estimate of the increase in tropospheric ozone is included. The acceleration observed in total ozone trends between the 1970s and the 1980s over northern midlatitudes [e.g., Harris et al., 1997] might be partially attributed to the larger increase in tropospheric ozone in the 1970s.

Standard Gibbs free energies of reactions of ozone with free radicals in aqueous solution: quantum-chemical calculations.

PubMed

Naumov, Sergej; von Sonntag, Clemens

2011-11-01

Free radicals are common intermediates in the chemistry of ozone in aqueous solution. Their reactions with ozone have been probed by calculating the standard Gibbs free energies of such reactions using density functional theory (Jaguar 7.6 program). O(2) reacts fast and irreversibly only with simple carbon-centered radicals. In contrast, ozone also reacts irreversibly with conjugated carbon-centered radicals such as bisallylic (hydroxycylohexadienyl) radicals, with conjugated carbon/oxygen-centered radicals such as phenoxyl radicals, and even with nitrogen- oxygen-, sulfur-, and halogen-centered radicals. In these reactions, further ozone-reactive radicals are generated. Chain reactions may destroy ozone without giving rise to products other than O(2). This may be of importance when ozonation is used in pollution control, and reactions of free radicals with ozone have to be taken into account in modeling such processes.

Global spectral UV-radiometer with automatic shadow band.

PubMed

Rosales, Alejandro; Pedroni, Jorge V; Tocho, Jorge O

2006-01-01

A solar radiometer (GUV-511 C, Biospherical Instruments Inc., San Diego, CA) with four UV channels has been operating at Trelew (43.2 degrees S, 65.3 degrees W), Argentina, since the austral spring of 1997. The instrument provides global (direct + diffuse) irradiance on the horizontal plane year-round, with a 1 min period. On 1 January 1999, an automatic shadow band was added to calculate diffuse and direct radiation. The period of the measurements was increased to 2 min to keep the same signal to noise (S:N) ratio. Once the direct radiation values were available for the 305 nm and 320 nm spectral bands, the total ozone value was calculated and results were compared with data provided by the U.S. National Aeronautics and Space Administration for the Total Ozone Mapping Spectrometer (TOMS) on the Earth Probe satellite. Results show a root-mean-square (RMS) deviation within 4% compared with that of TOMS, so the quality of results is considered to be quite good. The importance of regular calibration to maintain long-term accuracy is stressed.

Elevated Ozone in the Troposphere over the Atlantic and Pacific Oceans in the Northern Hemisphere

NASA Technical Reports Server (NTRS)

Chandra, S.; Ziemke, J. R.; Tie, Xuexi

2003-01-01

Tropospheric column ozone (TCO) is derived from differential measurements of total column ozone from Nimus-7 and Earth Probe TOMS, and stratospheric column ozone from the Microwave Limb Sounder instrument on the Upper Atmospheric Research Satellite. It is shown that TCO during summer months over the Atlantic and Pacific Oceans at northern mid-latitudes is about the same (50-60 Dobson Units) as over the continents of North America, Europe and Asia, where surface emissions of nitrogen oxides from industrial sources, biomass and biofuel burning and biogenic emissions are significantly larger. This nearly uniform zonal variation in TCO is modulated by surface topography of the Rocky and Himalayan mountains and Tibetan Plateau where TCO is reduced by 20-30 Dobson Units. The zonal characteristics of TCO derived from satellite measurements are well simulated by a global chemical transport model called MOZART-2 (Model of Ozone and Related Chemical Tracers, version 2). The model results are analyzed to delineate the relative importance of various processes contributing to observed zonal characteristics of TCO, and they are shown that the surface emission of NOx contributes about 50% of the TCO at northern mid-latitudes, especially over the continents of North America, Europe and Asia. The result of TCO derived from TOMS and the analysis from MOZART-2 indicate that TCO is a very useful tool to study tropospheric O3 pollution resulting from surface emissions of pollutants.

On the interannual oscillations in the northern temperate total ozone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krzyscin, J.W.

1994-07-01

The interannual variations in total ozone are studied using revised Dobson total ozone records (1961-1990) from 17 stations located within the latitude band 30 deg N - 60 deg N. To obtain the quasi-biennial oscillation (QBO), El Nino-Southern Oscillation (ENSO), and 11-year solar cycle manifestation in the `northern temperate` total ozone data, various multiple regression models are constructed by the least squares fitting to the observed ozone. The statistical relationships between the selected indices of the atmospheric variabilities and total ozone are described in the linear and nonlinear regression models. Nonlinear relationships to the predictor variables are found. That is,more » the total ozone variations are statistically modeled by nonlinear terms accounting for the coupling between QBO and ENSO, QBO and solar activity, and ENSO and solar activity. It is suggested that large reduction of total ozone values over the `northern temperate` region occurs in cold season when a strong ENSO warm event meets the west phase of the QBO during the period of high solar activity.« less

The Total Ozone Series of Arosa: History, Homogenization and new results using statistical extreme value theory

NASA Astrophysics Data System (ADS)

Staehelin, J.; Rieder, H. E.; Maeder, J. A.; Ribatet, M.; Davison, A. C.; Stübi, R.

2009-04-01

Atmospheric ozone protects the biota living at the Earth's surface from harmful solar UV-B and UV-C radiation. The global ozone shield is expected to gradually recover from the anthropogenic disturbance of ozone depleting substances (ODS) in the coming decades. The stratospheric ozone layer at extratropics might significantly increase above the thickness of the chemically undisturbed atmosphere which might enhance ozone concentrations at the tropopause altitude where ozone is an important greenhouse gas. At Arosa, a resort village in the Swiss Alps, total ozone measurements started in 1926 leading to the longest total ozone series of the world. One Fery spectrograph and seven Dobson spectrophotometers were operated at Arosa and the method used to homogenize the series will be presented. Due to its unique length the series allows studying total ozone in the chemically undisturbed as well as in the ODS loaded stratosphere. The series is particularly valuable to study natural variability in the period prior to 1970, when ODS started to affect stratospheric ozone. Concepts developed by extreme value statistics allow objective definitions of "ozone extreme high" and "ozone extreme low" values by fitting the (daily mean) time series using the Generalized Pareto Distribution (GPD). Extreme high ozone events can be attributed to effects of ElNino and/or NAO, whereas in the chemically disturbed stratosphere high frequencies of extreme low total ozone values simultaneously occur with periods of strong polar ozone depletion (identified by statistical modeling with Equivalent Stratospheric Chlorine times Volume of Stratospheric Polar Clouds) and volcanic eruptions (such as El Chichon and Pinatubo).

Analysis of the breakdown of the Antarctic circumpolar vortex using TOMS ozone data

NASA Technical Reports Server (NTRS)

Bowman, Kenneth P.

1987-01-01

Climatological analysis of data from the Total Ozone Mapping Spectrometer (TOMS) on the Nimbus 7 satellite has shown that the annual cycles of ozone are very different in the Arctic and Antarctic. The annual cycle in the Arctic is a relatively smooth annual sine wave; but in the Antarctic the circumpolar vortex breaks down rapidly during the Southern Hemisphere spring (September through November), producing a rapid rise in total ozone and a sawtooth-shaped annual cycle. The evolution of the Antarctic total ozone field during the vortex breakdown was studied by computing areally-integrated ozone amounts from the TOMS data. This technique avoids substantial difficulties with using zonally-averaged ozone amounts to study the asymmetric breakdown phenomenon. Variability of total ozone is found to be large both within an individual year and between different years. During the last decade monthly-mean total ozone values in the Antarctic during the springtime vortex breakdown period have decreased dramatically. The ozone-area statistics indicate that the decrease has resulted in part from changes in the timing of the vortex breakdown and resultant ozone increase, which have occurred later during recent years. Analysis of the spatial scales involved in the ozone transport and mixing that occur during the vortex breakdown is now underway. Reliable calculation of diagnostic quantities like areally-integrated ozone is possible only with the high-resolution, two-dimensional, daily coverage provided by the TOMS instrument.

Ionizing radiation environment for the TOMS mission

NASA Technical Reports Server (NTRS)

Lauriente, M.; Maloy, J. O.; Vampola, A. L.

1992-01-01

The Total Ozone Mapping Spectrometer (TOMS) will fly on several different spacecraft, each having an orbit which is approximately polar and 800-980 km in altitude. A description is given of the computer-based tools used for characterizing the spacecraft interactions with the ionizing radiation environment in orbit and the susceptibility requirements for ionizing radiation compatibility. The peak flux from the model was used to derive the expected radiation-induced noise in the South Atlantic Anomaly for the new TOMS instruments intended to fly on Advanced Earth Observatory System and Earth Probe.

Highlights from a Decade of OMI-TOMS Total Ozone Observations on EOS Aura

NASA Technical Reports Server (NTRS)

Haffner, David P.; Bhartia, Pawan K.; McPeters, Richard D.; Joiner, Joanna; Ziemke, Jerald R.; Vassilkov, Alexander; Labow, Gordon J.; Chiou, Er-Woon

2014-01-01

Total ozone measurements from OMI have been instrumental in meeting Aura science objectives. In the last decade, OMI has extended the length of the TOMS total ozone record to over 35 years to monitor stratospheric ozone recovery. OMI-TOMS total ozone measurements have also been combined synergistically with measurements from other Aura instruments and MLS in particular, which provides vertically resolved information that complements the total O3 mapping capability of OMI. With this combined approach, the EOS Aura platform has produced more accurate and detailed measurements of tropospheric ozone. This has led in turn to greater understanding of the sources and transport of tropospheric ozone as well as its radiative forcing effect. The combined use of OMI and MLS data was also vital to the analysis of the severe Arctic ozone depletion event of 2011. The quality of OMI-TOMS total O3 data used in these studies is the result of several factors: a mature and well-validated algorithm, the striking stability of the OMI instrument, and OMI's hyperspectral capabilities used to derive cloud pressures. The latter has changed how we think about the effects of clouds on total ozone retrievals. We will discuss the evolution of the operational V8.5 algorithm and provide an overview and motivation for V9. After reviewing results and developments of the past decade, we finally highlight how ozone observations from EOS Aura are playing an important role in new ozone mapping missions.

An extreme anomaly in stratospheric ozone over Europe in 1940-1942

NASA Astrophysics Data System (ADS)

Brönnimann, S.; Luterbacher, J.; Staehelin, J.; Svendby, T. M.

2004-04-01

Reevaluated historical total ozone data reveal extraordinarily high values over several European sites in 1940-1942, concurrent with extreme climatic anomalies at the Earth's surface. Using historical radiosonde data, reconstructed upper-level fields, and total ozone data from Arosa (Switzerland), Dombås, and Tromsø (Norway), this unusual case of stratosphere-troposphere coupling is analyzed. At Arosa, numerous strong total ozone peaks in all seasons were due to unusually frequent upper troughs over central Europe and related ozone redistribution in the lower stratosphere. At the Norwegian sites, high winter total ozone was most likely caused by major stratospheric warmings in Jan./Feb. 1940, Feb./Mar. 1941, and Feb. 1942. Results demonstrate that the dynamically driven interannual variability of total ozone can be much larger than that estimated based on the past 25-40 years.

Ozone Trend Detectability

NASA Technical Reports Server (NTRS)

Campbell, J. W. (Editor)

1981-01-01

The detection of anthropogenic disturbances in the Earth's ozone layer was studied. Two topics were addressed: (1) the level at which a trend in total ozoning is detected by existing data sources; and (2) empirical evidence in the prediction of the depletion in total ozone. Error sources are identified. The predictability of climatological series, whether empirical models can be trusted, and how errors in the Dobson total ozone data impact trend detectability, are discussed.

Aircraft cabin ozone measurements on B747-100 and B747-SP aircraft: Correlations with atmospheric ozone and ozone encounter statistics

NASA Technical Reports Server (NTRS)

Perkins, P. J.; Holdeman, J. D.; Gauntner, D. J.

1978-01-01

Simultaneous measurements of atmospheric (outside) ozone concentration and ozone levels in the cabin of the B747-100 and B747-SP airliners were made by NASA to evaluate the aircraft cabin ozone contamination problem. Instrumentation on these aircraft measured ozone from an outside probe and at one point in the cabin. Average ozone in the cabin of the B747-100 was 39 percent of the outside. Ozone in the cabin of the B747-SP measured 82 percent of the outside, before corrective measures. Procedures to reduce the ozone in this aircraft included changes in the cabin air circulation system, use of the high-temperature 15th stage compressor bleed, and charcoal filters in the inlet cabin air ducting, which as separate actions reduced the ozone to 58, 19 and 5 percent, respectively. The potential for the NASA instrumented B747 aircraft to encounter high levels of cabin ozone was derived from atmospheric oxone measurements on these aircraft. Encounter frequencies for two B747-100's were comparable even though the route structures were different. The B747-SP encountered high ozone than did the B747-100's.

The 1988 Antarctic ozone monitoring Nimbus-7 TOMS data atlas

NASA Technical Reports Server (NTRS)

Krueger, Arlin J.; Penn, Lanning M.; Larko, David E.; Doiron, Scott D.; Guimaraes, Patricia T.

1989-01-01

Because of the great environmental significance of ozone and to support continuing research at McMurdo, Syowa, and other Southern Hemisphere stations, the development of the 1988 ozone hole was monitored using data from the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) instrument, produced in near-real-time. This Atlas provides a complete set of daily polar orthographic projections of the TOMS total ozone measurements over the Southern Hemisphere for the period August 1 through November 17, 1988. Although total ozone in mini-holes briefly dropped below 150 DU in late August, the main ozone hole is seen to be much less pronounced than in 1987. Minimum values, observed in late September and early October 1988, were seldom less than 175 DU. Compared with the same period in 1987, when a pronounced ozone hole whose minimum value of 109 Dobson Units (DU) was the lowest total ozone ever observed, the 1988 ozone hole is displaced from the South Pole, opposing a persistent maximum with values consistently above 500 DU. Daily ozone values above selected Southern Hemisphere stations are presented, along with comparisons of the 1988 ozone distribution to that of other years.

Observations over Hurricanes from the Ozone Monitoring Instrument

NASA Technical Reports Server (NTRS)

Joiner, J.; Vasilkov, A.; Yang, K.; Bhartia, P. K.

2006-01-01

There is an apparent inconsistency between the total column ozone derived from the total ozone mapping spectrometer (TOMS) and aircraft observations within the eye region of tropical cyclones. The higher spectral resolution, coverage, and sampling of the ozone monitoring instrument (OMI) on NASA s Aura satellite as compared with TOMS allows for improved ozone retrievals by including estimates of cloud pressure derived simultaneously using the effects of rotational Raman scattering. The retrieved cloud pressures from OM1 are more appropriate than the climatological cloud-top pressures based on infrared measurements used in the TOMS and initial OM1 algorithms. We find that total ozone within the eye of hurricane Katrina is significantly overestimated when we use climatological cloud pressures. Using OMI-retrieved cloud pressures, total ozone in the eye is similar to that in the surrounding area. The corrected total ozone is in better agreement with aircraft measurements that imply relatively small or negligible amounts of stratospheric intrusion into the eye region of tropical cyclones.

Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) Data Products User's Guide

NASA Technical Reports Server (NTRS)

McPeters, Richard D.; Bhartia, P. K.; Krueger, Arlin J.; Herman, Jay R.; Schlesinger, Barry M.; Wellemeyer, Charles G.; Seftor, Colin J.; Jaross, Glen; Taylor, Steven L.; Swissler, Tom;

Evaluation of the clinical and antimicrobial effects of the Er:YAG laser or topical gaseous ozone as adjuncts to initial periodontal therapy.

PubMed

Yılmaz, Selçuk; Algan, Serdar; Gursoy, Hare; Noyan, Ulku; Kuru, Bahar Eren; Kadir, Tanju

2013-06-01

The aim of this study was to evaluate the clinical and microbiological results of treatment with the Er:YAG laser and topical gaseous ozone application as adjuncts to initial periodontal therapy in chronic periodontitis (CP) patients. Although many studies have evaluated the effectiveness of the Er:YAG laser as an adjunct to initial periodontal therapy, few studies have focused on the use of gaseous ozone as an adjunct. Thirty patients with CP were randomly divided into three parallel groups, each composed of 10 individuals with at least four teeth having at least one approximal site with a probing depth (PD) of ≥5 mm and a sulcus bleeding index (SBI) ≥2 in each quadrant. Groups of patients received: (1) Scaling and root planing (SRP)+Er:YAG laser; (2) SRP+topical gaseous ozone; or (3) SRP alone. The microbiological and clinical parameters were monitored at day 0 and day 90. At the end of the observation period, statistically significant improvements in clinical parameters were observed within each group. Parallel to the clinical changes, all treatments reduced the number of total bacteria and the proportion of obligately anaerobic microorganisms. Although intergroup comparisons of microbiological parameters showed no significant differences, clinical findings, including attachment gain and PD reduction, were found to be statistically significant in favor of the SRP+Er:YAG laser group. Although statistically nonsignificant, the fact that the obligate anaerobic change was mostly observed in the SRP+Er:YAG laser group, and a similar decrease was noted in the SRP+topical gaseous ozone group, shows that ozone has an antimicrobial effect equivalent to that of the Er:YAG laser.

Ozone column density determination from direct irradiance measurements in the ultraviolet performed by a four-channel precision filter radiometer.

PubMed

Ingold, T; Mätzler, C; Wehrli, C; Heimo, A; Kämpfer, N; Philipona, R

2001-04-20

Ultraviolet light was measured at four channels (305, 311, 318, and 332 nm) with a precision filter radiometer (UV-PFR) at Arosa, Switzerland (46.78 degrees , 9.68 degrees , 1850 m above sea level), within the instrument trial phase of a cooperative venture of the Swiss Meteorological Institute (MeteoSwiss) and the Physikalisch-Meteorologisches Observatorium Davos/World Radiation Center. We retrieved ozone-column density data from these direct relative irradiance measurements by adapting the Dobson standard method for all possible single-difference wavelength pairs and one double-difference pair (305/311 and 305/318) under conditions of cloud-free sky and of thin clouds (cloud optical depth <2.5 at 500 nm). All UV-PFR retrievals exhibited excellent agreement with those of collocated Dobson and Brewer spectrophotometers for data obtained during two months in 1999. Combining the results of the error analysis and the findings of the validation, we propose to retrieve ozone-column density by using the 305/311 single difference pair and the double-difference pair. Furthermore, combining both retrievals by building the ratio of ozone-column density yields information that is relevant to data quality control. Estimates of the 305/311 pair agree with measurements by the Dobson and Brewer instruments within 1% for both the mean and the standard deviation of the differences. For the double pair these values are in a range up to 1.6%. However, this pair is less sensitive to model errors. The retrieval performance is also consistent with satellite-based data from the Earth Probe Total Ozone Mapping Spectrometer (EP-TOMS) and the Global Ozone Monitoring Experiment instrument (GOME).

Ozone Column Density Determination From Direct Irradiance Measurements in the Ultraviolet Performed by a Four-Channel Precision Filter Radiometer

NASA Astrophysics Data System (ADS)

Ingold, Thomas; Mätzler, Christian; Wehrli, Christoph; Heimo, Alain; Kämpfer, Niklaus; Philipona, Rolf

2001-04-01

Ultraviolet light was measured at four channels (305, 311, 318, and 332 nm) with a precision filter radiometer (UV-PFR) at Arosa, Switzerland (46.78 , 9.68 , 1850 m above sea level), within the instrument trial phase of a cooperative venture of the Swiss Meteorological Institute (MeteoSwiss) and the Physikalisch-Meteorologisches Observatorium Davos /World Radiation Center. We retrieved ozone-column density data from these direct relative irradiance measurements by adapting the Dobson standard method for all possible single-difference wavelength pairs and one double-difference pair (305 /311 and 305 /318) under conditions of cloud-free sky and of thin clouds (cloud optical depth <2.5 at 500 nm). All UV-PFR retrievals exhibited excellent agreement with those of collocated Dobson and Brewer spectrophotometers for data obtained during two months in 1999. Combining the results of the error analysis and the findings of the validation, we propose to retrieve ozone-column density by using the 305 /311 single difference pair and the double-difference pair. Furthermore, combining both retrievals by building the ratio of ozone-column density yields information that is relevant to data quality control. Estimates of the 305 /311 pair agree with measurements by the Dobson and Brewer instruments within 1% for both the mean and the standard deviation of the differences. For the double pair these values are in a range up to 1.6%. However, this pair is less sensitive to model errors. The retrieval performance is also consistent with satellite-based data from the Earth Probe Total Ozone Mapping Spectrometer (EP-TOMS) and the Global Ozone Monitoring Experiment instrument (GOME).

External comparisons of reprocessed SBUV/TOMS ozone data

NASA Technical Reports Server (NTRS)

Wellemeyer, C. G.; Taylor, S. L.; Singh, R. R.; Mcpeters, R. D.

1994-01-01

Ozone Retrievals from the Solar Backscatter Ultraviolet (SBUV) Instrument on-board the Nimbus-7 Satellite have been reprocessed using an improved internal calibration. The resulting data set covering November, 1978 through January, 1987 has been archived at the National Space Science Data Center in Greenbelt, Maryland. The reprocessed SBUV total ozone data as well as recalibrated Total Ozone Mapping Spectrometer (TOMS) data are compared with total ozone measurements from a network of ground based Dobson spectrophotometers. The SBUV also measures the vertical distribution of ozone, and these measurements are compared with external measurements made by SAGE II, Umkehr, and Ozonesondes. Special attention is paid to long-term changes in ozone bias.

Artificial neural network with backpropagation learning to predict mean monthly total ozone in Arosa, Switzerland

NASA Astrophysics Data System (ADS)

Chattopadhyay, Surajit; Bandyopadhyay, Goutami

2007-01-01

Present study deals with the mean monthly total ozone time series over Arosa, Switzerland. The study period is 1932-1971. First of all, the total ozone time series has been identified as a complex system and then Artificial Neural Networks models in the form of Multilayer Perceptron with back propagation learning have been developed. The models are Single-hidden-layer and Two-hidden-layer Perceptrons with sigmoid activation function. After sequential learning with learning rate 0.9 the peak total ozone period (February-May) concentrations of mean monthly total ozone have been predicted by the two neural net models. After training and validation, both of the models are found skillful. But, Two-hidden-layer Perceptron is found to be more adroit in predicting the mean monthly total ozone concentrations over the aforesaid period.

DOAS-based total column ozone retrieval from Phaethon system

NASA Astrophysics Data System (ADS)

Gkertsi, F.; Bais, A. F.; Kouremeti, N.; Drosoglou, Th; Fountoulakis, I.; Fragkos, K.

2018-05-01

This study introduces the measurement of the total ozone column using Differential Optical Absorption Spectroscopy (DOAS) analysis of direct-sun spectra recorded by the Phaethon system. This methodology is based on the analysis of spectra relative to a reference spectrum that has been recorded by the same instrument. The slant column density of ozone associated with the reference spectrum is derived by Langley extrapolation. Total ozone data derived by Phaethon over two years in Thessaloniki are compared with those of a collocated, well-maintained and calibrated, Brewer spectrophotometer. When the retrieval of total ozone is based on the absorption cross sections of (Paur and Bass, 1984) at 228 K, Phaethon shows an average overestimation of 1.85 ± 1.86%. Taking into account the effect of the day-to-day variability of stratospheric temperature on total ozone derived by both systems, the bias is reduced to 0.94 ± 1.26%. The sensitivity of the total ozone retrieval to changes in temperature is larger for Phaethon than for Brewer.

[Radiance Simulation of BUV Hyperspectral Sensor on Multi Angle Observation, and Improvement to Initial Total Ozone Estimating Model of TOMS V8 Total Ozone Algorithm].

PubMed

Lü, Chun-guang; Wang, Wei-he; Yang, Wen-bo; Tian, Qing-iju; Lu, Shan; Chen, Yun

2015-11-01

New hyperspectral sensor to detect total ozone is considered to be carried on geostationary orbit platform in the future, because local troposphere ozone pollution and diurnal variation of ozone receive more and more attention. Sensors carried on geostationary satellites frequently obtain images on the condition of larger observation angles so that it has higher requirements of total ozone retrieval on these observation geometries. TOMS V8 algorithm is developing and widely used in low orbit ozone detecting sensors, but it still lack of accuracy on big observation geometry, therefore, how to improve the accuracy of total ozone retrieval is still an urgent problem that demands immediate solution. Using moderate resolution atmospheric transmission, MODT-RAN, synthetic UV backscatter radiance in the spectra region from 305 to 360 nm is simulated, which refers to clear sky, multi angles (12 solar zenith angles and view zenith angles) and 26 standard profiles, moreover, the correlation and trends between atmospheric total ozone and backward scattering of the earth UV radiation are analyzed based on the result data. According to these result data, a new modified initial total ozone estimation model in TOMS V8 algorithm is considered to be constructed in order to improve the initial total ozone estimating accuracy on big observation geometries. The analysis results about total ozone and simulated UV backscatter radiance shows: Radiance in 317.5 nm (R₃₁₇.₅) decreased as the total ozone rise. Under the small solar zenith Angle (SZA) and the same total ozone, R₃₁₇.₅ decreased with the increase of view zenith Angle (VZA) but increased on the large SZA. Comparison of two fit models shows: without the condition that both SZA and VZA are large (> 80°), exponential fitting model and logarithm fitting model all show high fitting precision (R² > 0.90), and precision of the two decreased as the SZA and VZA rise. In most cases, the precision of logarithm fitting mode is about 0.9% higher than exponential fitting model. With the increasing of VZA or SZA, the fitting precision gradually lower, and the fall is more in the larger VZA or SZA. In addition, the precision of fitting mode exist a plateau in the small SZA range. The modified initial total ozone estimating model (ln(I) vs. Ω) is established based on logarithm fitting mode, and compared with traditional estimating model (I vs. ln(Ω)), that shows: the RMSE of ln(I) vs. Ω and I vs. ln(Ω) all have the down trend with the rise of total ozone. In the low region of total ozone (175-275 DU), the RMSE is obvious higher than high region (425-525 DU), moreover, a RMSE peak and a trough exist in 225 and 475 DU respectively. With the increase of VZA and SZA, the RMSE of two initial estimating models are overall rise, and the upraising degree is ln(I) vs. Ω obvious with the growing of SZA and VZA. The estimating result by modified model is better than traditional model on the whole total ozone range (RMSE is 0.087%-0.537% lower than traditional model), especially on lower total ozone region and large observation geometries. Traditional estimating model relies on the precision of exponential fitting model, and modified estimating model relies on the precision of logarithm fitting model. The improvement of the estimation accuracy by modified initial total ozone estimating model expand the application range of TOMS V8 algorithm. For sensor carried on geostationary orbit platform, there is no doubt that the modified estimating model can help improve the inversion accuracy on wide spatial and time range This modified model could give support and reference to TOMS algorithm update in the future.

Insights into Tropical Tropospheric Ozone from Satellite and Sonde Data

NASA Technical Reports Server (NTRS)

Thompson, Anne M.

2003-01-01

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. The data reside at: http://code916.gsfc.nasa.gov/Data_services/shadoz. SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone. Prominent features are highly variable tropospheric ozone and a zonal wave-one pattern in total (and tropospheric) column ozone. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this. In addition to leading the SHADOZ network, we have been producing near-real tropical tropospheric ozone ('TTO') data from the Total Ozone Mapping Spectrometer (TOMS) since 1997 with Prof. Hudson and students at the University of Maryland: http://metosrv2.umd.edu/tropo. Further perspective on the complexity of tropospheric ozone variability is shown using satellite observations.

Long-term total ozone observations at Arosa (Switzerland) with Dobson and Brewer instruments (1988-2007)

NASA Astrophysics Data System (ADS)

Scarnato, B.; Staehelin, J.; Stübi, R.; Schill, H.

2010-07-01

Dobson and Brewer spectrophotometers are the standard instruments for ground-based total ozone monitoring under the World Meteorological Organization's Global Atmosphere Watch program. Both types of instruments have been simultaneously used at Arosa station (Switzerland) since 1988; presently two Dobson and three Brewer instruments (one of which is type Mark III) are in operation. The large data set of quasi-simultaneous measurements (defined here as observations performed less than 10 min apart) allows for the determination of both inter- and intrainstrumental precision. The results for one standard deviation of total ozone are ±0.5% for Dobson standard wavelength pair observations and ±0.15% for Brewer total ozone measurements. To transform Dobson data into Brewer total ozone observations, empirical transfer functions are used to describe the observed difference in seasonal variations of total ozone data derived from the two types of instruments (amounting to a seasonal amplitude of approximately 2% with maximum deviation in winter). The statistical model (applied to quasi-simultaneous measurements) includes the ozone effective temperature and the air mass multiplied by total ozone (ozone slant path) as explanatory variables; it removes the seasonal cycle in the difference and it allows the significance of the proxies introduced and systematic errors in the data to be determined. However, even when these transfer functions are applied, a 3% drift over about a 10 year period (1988-1997) between Arosa's Dobson and Brewer derived total ozone data series remains unexplained, adding to the model an aerosol proxy for which only part of the drift can be removed (related to the period 1992-1996).

Reconciliation of Halogen-Induced Ozone Loss with the Total-Column Ozone Record

NASA Technical Reports Server (NTRS)

Shepherd, T. G.; Plummer, D. A.; Scinocca, J. F.; Hegglin, M. I.; Fioletov, V. E.; Reader, M. C.; Remsberg, E.; von Clarmann, T.; Wang, H. J.

2014-01-01

The observed depletion of the ozone layer from the 1980s onwards is attributed to halogen source gases emitted by human activities. However, the precision of this attribution is complicated by year-to-year variations in meteorology, that is, dynamical variability, and by changes in tropospheric ozone concentrations. As such, key aspects of the total-column ozone record, which combines changes in both tropospheric and stratospheric ozone, remain unexplained, such as the apparent absence of a decline in total-column ozone levels before 1980, and of any long-term decline in total-column ozone levels in the tropics. Here we use a chemistry-climate model to estimate changes in halogen-induced ozone loss between 1960 and 2010; the model is constrained by observed meteorology to remove the eects of dynamical variability, and driven by emissions of tropospheric ozone precursors to separate out changes in tropospheric ozone. We show that halogen-induced ozone loss closely followed stratospheric halogen loading over the studied period. Pronounced enhancements in ozone loss were apparent in both hemispheres following the volcanic eruptions of El Chichon and, in particular, Mount Pinatubo, which significantly enhanced stratospheric aerosol loads. We further show that approximately 40% of the long-term non-volcanic ozone loss occurred before 1980, and that long-term ozone loss also occurred in the tropical stratosphere. Finally, we show that halogeninduced ozone loss has declined by over 10% since stratospheric halogen loading peaked in the late 1990s, indicating that the recovery of the ozone layer is well underway.

Nimbus 7 solar backscatter ultraviolet (SBUV) ozone products user's guide

NASA Technical Reports Server (NTRS)

Fleig, Albert J.; Mcpeters, R. D.; Bhartia, P. K.; Schlesinger, Barry M.; Cebula, Richard P.; Klenk, K. F.; Taylor, Steven L.; Heath, Donald F.

1990-01-01

Three ozone tape products from the Solar Backscatter Ultraviolet (SBUV) experiment aboard Nimbus 7 were archived at the National Space Science Data Center. The experiment measures the fraction of incoming radiation backscattered by the Earth's atmosphere at 12 wavelengths. In-flight measurements were used to monitor changes in the instrument sensitivity. Total column ozone is derived by comparing the measurements with calculations of what would be measured for different total ozone amounts. The altitude distribution is retrieved using an optimum statistical technique for the inversion. The estimated initial error in the absolute scale for total ozone is 2 percent, with a 3 percent drift over 8 years. The profile error depends on latitude and height, smallest at 3 to 10 mbar; the drift increases with increasing altitude. Three tape products are described. The High Density SBUV (HDSBUV) tape contains the final derived products - the total ozone and the vertical ozone profile - as well as much detailed diagnostic information generated during the retrieval process. The Compressed Ozone (CPOZ) tape contains only that subset of HDSBUV information, including total ozone and ozone profiles, considered most useful for scientific studies. The Zonal Means Tape (ZMT) contains daily, weekly, monthly and quarterly averages of the derived quantities over 10 deg latitude zones.

The role of polar stratospheric clouds on total ozone minihole events

NASA Technical Reports Server (NTRS)

Sabutis, Joseph L.

1989-01-01

Using seven years of data from tha SAM 2 (Stratospheric Aerosol Measurement 2) and TOMS (Total Ozone Mapping Spectrometer) instruments, along with 70 mbar temperatures extracted from an NMC analysis, the effect of the austral spring polar stratospheric clouds (PSC) on the formation of total ozone miniholes is investigated. A total ozone minihole event is designated as the rapid decrease of more than 20 DU of total ozone over a time period of a day and a spatial extent of approximately 1000 by 1000 km. The severe decrease of total ozone during these minihole events could be explained in part by PSC being formed at altitudes of 10 to 24 km and preventing scattered UV radiation from ozone below the cloud from reaching the TOMS instrument. A result of the cloud's opaqueness is that the total ozone retrieval from TOMS data would underestimate the ozone column in the vicinity of the PSC. The approach to investigate the effect of PSC on total ozone was to use SAM 2 aerosol extinction values in conjunction with NMC stratospheric temperatures to determine if PSC are present during total ozone minihole events occurring during August and September, 1979 to 1986. The minihole events during these seven years were divided into two types: type 1, where the minihole region of 24 hour darkness from regions exposed to sunlight, and type 2, where the minihole occurred 5 to 10 degrees north of the terminator. The presence of PSC in a given region was ascertained by a maximum aerosol extinction greater than .006/km occurring with a temperature less than 189 K. It is found that PSC are consistently present with type 2 minihole events. This is contrasted with PSC rarely occurring in the same vicinity of type 2 miniholes. Also observed of that type 1 minihole events have minimum total ozone values which are on the average 3 to 10 DU smaller than type 2 miniholes. It can be concluded that care must be taken when trying to deduce a dynamical explanation of minihole events near the polar terminator and the role of PSC must be accounted for in type 1 minihole formation.

Discussion of the 60 year total ozone record at Arosa based on measurements of the vertical distribution and a meteorological parameter

NASA Astrophysics Data System (ADS)

Duetsch, H. U.; Staehelin, J.

1989-12-01

This paper discusses the longest total ozone record in the world, started by Goetz (using a simple cadmium cell) at Arosa, Switzerland, in 1926 and supplemented by later measurements at Arosa with modern instruments and by ozone soundings at Payerne, Switzerland. These data yield the concurrent vertical distribution which makes it possible to distinguish between regional and hemispheric scale processes influencing total ozone. These measurements also make it possible to derive the height distribution of the ozone loss since 1970 and to derive indications of the extent of anthropogenic contribution to the changes. The most intense negative trends are found around the level of the ozone peak and in the upper stratosphere, whereby the former yields the dominant contribution to the total ozone loss.

Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) data products user's guide

NASA Technical Reports Server (NTRS)

Mcpeters, Richard D.; Krueger, Arlin J.; Bhartia, P. K.; Herman, Jay R.; Oaks, Arnold; Ahmad, Ziuddin; Cebula, Richard P.; Schlesinger, Barry M.; Swissler, Tom; Taylor, Steven L.

1993-01-01

Two tape products from the Total Ozone Mapping Spectrometer (TOMS) aboard the Nimbus-7 have been archived at the National Space Science Data Center. The instrument measures backscattered Earth radiance and incoming solar irradiance; their ratio -- the albedo -- is used in ozone retrievals. In-flight measurements are used to monitor changes in the instrument sensitivity. The algorithm to retrieve total column ozone compares the observed ratios of albedos at pairs of wavelengths with pair ratios calculated for different ozone values, solar zenith angles, and optical paths. The initial error in the absolute scale for TOMS total ozone is 3 percent, the one standard-deviation random error is 2 percent, and the drift is +/- 1.5 percent over 14.5 years. The High Density TOMS (HDTOMS) tape contains the measured albedos, the derived total ozone amount, reflectivity, and cloud-height information for each scan position. It also contains an index of SO2 contamination for each position. The Gridded TOMS (GRIDTOMS) tape contains daily total ozone and reflectivity in roughly equal area grids (110 km in latitude by about 100-150 km in longitude). Detailed descriptions of the tape structure and record formats are provided.

Fine-Scale Comparison of TOMS Total Ozone Data with Model Analysis of an Intense Midwestern Cyclone

NASA Technical Reports Server (NTRS)

Olsen, Mark A.; Gallus, William A., Jr.; Stanford, John L.; Brown, John M.

2000-01-01

High-resolution (approx. 40 km) along-track total column ozone data from the Total Ozone Mapping Spectrometer (TOMS) instrument are compared with a high-resolution mesoscale numerical model analysis of an intense cyclone in the Midwestern United States. Total ozone increased by 100 DU (nearly 38%) as the TOMS instrument passed over the associated tropopause fold region. Complex structure is seen in the meteorological fields and compares well with the total ozone observations. Ozone data support the meteorological analysis showing that stratospheric descent was confined to levels above approx. 600 hPa; significant positive potential vorticity at lower levels is attributable to diabetic processes. Likewise, meteorological fields show that two pronounced ozone streamers extending north and northeastward into Canada at high levels are not bands of stratospheric air feeding into the cyclone; one is a channel of exhaust downstream from the system, and the other apparently previously connected the main cyclonic circulation to a southward intrusion of polar stratospheric air and advected eastward as the cut-off cyclone evolved. Good agreement between small-scale features in the model output and total ozone data underscores the latter's potential usefulness in diagnosing upper tropospheric/lower stratospheric dynamics and kinematics.

Differences between recalculated and original Dobson total ozone data from Hradec Kralove, Czechoslovakia, 1962-1990

NASA Technical Reports Server (NTRS)

Vanicek, Karel

1994-01-01

Backward reevaluation of long-term total ozone measurements from the Solar and Ozone Observatory of Czech Hydrometeorological Institute at Hradec Kralove, Czechoslovakia, was performed for the period 1962-1990. The homogenization was carried out with respect to the calibration level of the World Primary Standard Spectrophotometer No. 83 - WPSS by means of day-by-day recalculations of more than 25,000 individual measurements using the R-N tables reconstructed after international comparisons and regular standard lamp tests of the Dobson spectrophotometer No. 74. The results showed significant differences among the recalculated data and those original ones published in the bulletins Ozone Data for the World. In the period 1962-1979 they reached 10-19 D.U. (3.0-5.5%) for annual averages and even 26 D.U. (7.0%) for monthly averages of total ozone. Such differences exceed several times accuracy of measuring and can significantly influence character of trends of total ozone in Central Europe. Therefore the results from Hradec Kralove support the calls for reevaluation of all historical Dobson total ozone data sets at individual stations of Global Ozone Observing System.

The 1987 Airborne Antarctic Ozone Experiment: the Nimbus-7 TOMS Data Atlas

NASA Technical Reports Server (NTRS)

Krueger, Arlin J.; Ardanuy, Philip E.; Sechrist, Frank S.; Penn, Lanning M.; Larko, David E.; Doiron, Scott D.; Galimore, Reginald N.

1988-01-01

Total ozone data taken by the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) played a central role in the successful outcome of the 1987 Airborne Antarctic Ozone Experiment. The near-real-time TOMS total ozone observations were suppled within hours of real time to the operations center in Punta Arenas, Chile, over a telecommunications network designed specifically for this purpose. The TOMS data preparation and method of transfer over the telecommunications links are reviewed. This atlas includes a complete set of the near-real-time TOMS orbital overpass data over regions around the Palmer Peninsula of Antarctica for the period of August 8 through September 29, 1987. Also provided are daily polar orthographic projections of TOMS total ozone measurements over the Southern Hemisphere from August through November 1987. In addition, a chronology of the salient points of the experiment, along with some latitudinal cross sections and time series at locations of interest of the TOMS total ozone observations are presented. The TOMS total ozone measurements are evaluated along the flight tracks of each of the ER-2 and DC-8 missions during the experiment. The ozone hole is shown here to develop in a monotonic progression throughout late August and September. The minimum total ozone amount was found on 5 October, when its all-time lowest value of 109 DU is recorded. The hole remains well defined, but fills gradually from mid-October through mid-November. The hole's dissolution is observed here to begin in mid-November, when it elongates and begins to rotate. By the end of November, the south pole is no longer located within the ozone hole.

Retrieval of Total Ozone Amounts from Zenith-Sky Intensities in the Ultraviolet Region

NASA Technical Reports Server (NTRS)

Bojkov, B. R.; Bhartia, P. K.; Hilsenrath, E.; Labow, G. J.

2004-01-01

A new method to determine the total ozone column from zenith-sky intensities in the ultraviolet region has been developed for the Shuttle Solar Backscatter Ultraviolet Spectrometer (SSBUV) operating at the NASA Goddard Space Flight Center. The total ozone column amounts are derived by comparing the ratio of measured intensities from three wavelengths with the equivalent ratios calculated by a radiative transfer model. The differences between the retrieved ozone column amounts and the collocated Brewer double monochromator are within 2% for the measurement period beginning in April 2001. The methodology, as well as the influences of the ozone profiles, aerosols, surface albedo, and the solar zenith angle on the retrieved total ozone amounts will be presented.

On the Long-Term Calibration of the TOMS Total Ozone Record

NASA Technical Reports Server (NTRS)

Stolarski, Richard S.; McPeters, Richard; Labow, Gordon J.; Hollandsworth, Stacey; Flynn, Larry; Einaudi, Franco (Technical Monitor)

2000-01-01

Comparison of Total Ozone Mapping Spectrometer (TOMS) data to the network of ground-based Dobson/Brewer measurements reveals difference in the time dependence of the calibration of the two systems. We have been searching for a method to determine the time dependence of the TOMS calibrations that is independent of the Dobson/Brewer network. In a separate paper by DeLand et al., calibrations of the Solar Backscatter UV Spectrometer (SBUV) instruments have been rederived using the D-pair (306/313 nm wavelengths) data at the equator. These calibrations have been applied to the data from the Nimbus 7 SBUV and the NOAA 9 and 11 SBUV/2 data to derive a new version 7 data set for each instrument. We have used these data to do a detailed comparison to the Nimbus 7 and Earth Probe TOMS data. Assuming that the D-pair establishes the correct calibration, these comparisons reveal some small calibration drifts (approximately 1%) in the TOMS data. They also reveal an offset in the D-pair calibration with respect to the Dobson network of approximately 8 Dobson units with the Dobson being lower than the D-pair. The D-pair calibration offsets have been used to create a merged ozone data set from TOMS with a calibration that has been determined independent of the Dobson/Brewer network. Trend analyses of these data will be presented and compared to trend analyses using the ground-based data.

Long-term ozone and temperature correlations above SANAE, Antarctica

NASA Technical Reports Server (NTRS)

Bodeker, Gregory E.; Scourfield, Malcolm W. J.

1994-01-01

A significant decline in Antarctic total column ozone and upper air temperatures has been observed in recent years. Furthermore, high correlations between monthly mean values of ozone and stratospheric temperature have been measured above Syowa, Antarctica. For the observations reported here, data from TOMS (Total Ozone Mapping Spectrometer) aboard the Nimbus 7 satellite have been used to examine the 1980 to 1990 decrease in total column ozone above the South African Antarctic base of SANAE (70 deg 18 min S, 2 deg 21 min W). The cooling of the Antarctic stratosphere above SANAE during this period has been investigated by examining upper air temperatures at the 150, 100, 70, 50, and 30 hPa levels obtained from daily radiosonde balloon launches. Furthermore, these two data sets have been used to examine long-term, medium-term, and short-term correlations between total column ozone and the temperatures at each of the five levels. The trend in SANAE total column ozone has been found to be -4.9 DU/year, while upper air temperatures have been found to decrease at around 0.3 C/year. An analysis of monthly average SANAE total column ozone has shown the decrease to be most severe during the month of September with a trend of -7.7 DU/year. A strong correlation (r(exp 2) = 0.92) has been found between yearly average total column ozone and temperature at the 100 hPa level. Daily ozone and temperature correlations show high values from September to November, at a time when the polar vortex is breaking down.

Influence of equatorial QBO (quasi-biennial oscillation) and SST (sea-surface temperature) on polar total ozone, and the 1990 Antarctic ozone hole

DOE Office of Scientific and Technical Information (OSTI.GOV)

Angell, J.K.

1990-09-01

Based on data through 1989, comparisons are made between the variation of total ozone at Resolute, Canada (75{degree}N) and South Pole, and the variation of low-stratospheric temperature at Singapore (reflecting the equatorial QBO) and SST in eastern equatorial Pacific (reflecting the ENSO phenomenon). Total-ozone variations at Resolute have been more closely related to the QBO, whereas the total-ozone variations at South Pole appear to have been almost equally related to QBO and SST. When the average of 50 mb and 30 mb June-July-August (JJA) values of Singapore temperature ({bar T}) increased from one year to the next, the decrease inmore » South Pole springtime total ozone for the same years averaged 21 {plus minus} 14% greater than when {bar T} decreased. When the JJA values of equatorial SST increased from one year to the next, the decrease in South Pole springtime total ozone for the same years averaged 18 {plus minus} 12% greater than when SST decreased. In the 6 cases when JJA values of both Singapore {bar T} and equatorial SST increased from one year to the next, the spring values of South Pole total ozone have decreased, whereas in the 6 cases when both {bar T} and SST decreased from one year to the next, South Pole total ozone has increased. Both Singapore {bar T} and equatorial SST will probably be warmer in JJA of 1990 than they were in JJA of 1989 suggesting, based on these previous relations, an even deeper Antarctic ozone hole in 1990 than in 1989 and ending the biennial variation in depth of the hole of the last 6 years.« less

Ozone climatology series. Volume 1: Atlas of total ozone, April 1970 - December 1976

NASA Technical Reports Server (NTRS)

Heath, D. F.; Fleig, A. J.; Miller, A. J.; Rogers, T. G.; Nagatani, R. M.; Bowman, H. D., II; Kaveeshwar, V. G.; Klenk, K. F.; Bhartia, P. K.; Lee, K. D.

1982-01-01

Contours and gridded values are given for seven years of monthly mean total ozone data derived from observations with the Backscattered Ultraviolet instrument on Nimbus-4 for the Northern and Southern Hemispheres. The instrument, algorithm, uncertainties in derived ozone and systematic changes in the bias with respect to the international groundbased ozone network of Dobson instruments, are discussed.

Variability in total ozone associated with baroclinic waves

NASA Technical Reports Server (NTRS)

Mote, Philip W.; Holton, James R.; Wallace, John M.

1991-01-01

One-point regression maps of total ozone formed by regressing the time series of bandpass-filtered geopotential height data have been analyzed against Total Ozone Mapping Spectrometer data. Results obtained reveal a strong signature of baroclinic waves in the ozone variability. The regressed patterns are found to be similar in extent and behavior to the relative vorticity patterns reported by Lim and Wallace (1991).

On the Relation between Atmospheric Ozone and Sunspot Number.

NASA Astrophysics Data System (ADS)

Angell, J. K.

1989-11-01

Based on data from the Dobson network, between 1960 and 1987 there has been a zero-lag correlation of 0.48 between the 112 unsmoothed seasonal values of sunspot number and global total ozone, significant at the 1% level taking into account the considerable serial correlation in these data. The maximum correlation of 0.54 is found when sunspot number lags total ozone by two seasons, the result mainly of a phase difference early in the record. On the basis of only 2 1/2 solar cycles, the global total ozone has increased by 1.4% for an increase in sunspot number of 100. The correlation between sunspot number and total ozone has been significant at the 5% level in north temperate and tropical zones-the zones with the most representative data. In the north temperate zone, the correlation between sunspot number and total ozone has been much higher in the west-wind phase of the 50 mb equatorial QBO than in the east-wind phase, but in the tropics the correlation has been much higher in the east-wind phase. Umkehr measurements between 1966 and 1987 in the north temperate zone indicate that the correlation between sunspot number and ozone amount has been higher (0.35, almost significant at the 5% level) in the low stratosphere where transport processes dominate than in the high stratosphere where photochemical processes dominate. During 1932-60 there was a significant correlation of 0.35 between sunspot number and Arosa total ozone 14 seasons later, very different from the nearly in-phase relation found after 1960. Considered is the possible impact of long-term change in transport processes in the low stratosphere on the total-ozone record at a single station such as Arosa.Between 1966 and 1985 there has been very good agreement between observed global total ozone, and global total ozone calculated from three 2-D stratospheric models that take into account the solar cycle, the time variation in trace gases, and nuclear tests; both observed and calculated variations are closely related to the variation in sunspot number. Between 1960 and 1966, however, the agreement between observation and calculation is poor, the models indicating a pronounced minimum in global total ozone in 1963 due to the nuclear tests of the early 1960s-a minimum not found in this analysis. The observed variation in global total ozone has been compared with the variation predicted by one of the models up to the sunspot maximum in 1990, and the agreement is shown to be good through the northern summer of 1988 if the impact of the QBO on global total ozone is taken into account. On the basis of the present analysis, there has been a 1.0 ± 0.9% decrease in global total ozone between solar cycles 20 and 21, a decrease 70% larger than that indicated by the three stratospheric models.

Comparison of Tropical Ozone from SHADOZ with Remote Sensing Retrievals from Suomi-npp Ozone Mapping Profile Suite (OMPS)

NASA Technical Reports Server (NTRS)

Witte, Jacquelyn C.; Thompson, Anne M.; Ziemke, Jerald R.; Wargan, Krzysztof

2014-01-01

The Ozone Mapping Profile Suite (OMPS) was launched October 28, 2011 on-board the Suomi NPP satellite (http://npp.gsfc.nasa.gov). OMPS is the next generation total column ozone mapping instrument for monitoring the global distribution of stratospheric ozone. OMPS includes a limb profiler to measure the vertical structure of stratosphere ozone down to the mid-troposphere. This study uses tropical ozonesonde profile measurements from the Southern Hemisphere Additional Ozonesondes (SHADOZ, http://croc.gsfc.nasa.gov/shadoz) archive to evaluate total column ozone retrievals from OMPS and concurrent measurements from the Aura Ozone Monitoring Instrument (OMI), the predecessor of OMPS with a data record going back to 2004. We include ten SHADOZ stations that contain data overlapping the OMPS time period (2012-2013). This study capitalizes on the ozone profile measurements from SHADOZ to evaluate OMPS limb profile retrievals. Finally, we use SHADOZ sondes and OMPS retrievals to examine the agreement with the GEOS-5 Ozone Assimilation System (GOAS). The GOAS uses data from the OMI and the Microwave Limb Sounder (MLS) to constrain the total column and stratospheric profiles of ozone. The most recent version of the assimilation system is well constrained to the total column compared with SHADOZ ozonesonde data.

[The two ozone problems: too much in the troposphere, too little in the stratosphere].

PubMed

Staehelin, J

1992-03-10

Trends analysis based on the long-term Swiss ozone measurements from Arosa and Payerne operationally performed by the Swiss Meteorological Institute are presented. These measurement include stratospheric ozone (approximately 90% of total ozone) and tropospheric ozone. The total ozone measurements from Arosa, the world longest series started at 1926, indicate, that total ozone has declined since about 1970 by approximately 5%. The ozone balloon soundings, operationally performed at Payerne since 1969 (2-3 ascents per week) show, that stratospheric ozone has decreased strongly in the last 20 years, whereas tropospheric ozone, remarkably has increased during this period. The relative change was strongest in the troposphere (more than 10% per decade, 3-4% increase per year during 1982-1988). However, on an absolute scale, changes in the stratosphere were strongest (relative decrease: 6 to 7% per decade at 20-22 km). The present scientific theories of the two ozone problems are reviewed: stratospheric ozone decrease was caused by the anthropogenic emissions of fluorochlorocarbons and other compounds mainly released from the earth surface. Tropospheric ozone has increased due to photochemical production of mainly anthropogenically emitted nitrogen oxides, volatile organic compounds and CO.

Absolute determination of the cross sections of ozone in the wavelength region 339-355 nm at temperatures 220-293 K

NASA Astrophysics Data System (ADS)

Cacciani, Marco; di Sarra, Alcide; Fiocco, Giorgio; Amoruso, Antonella

1989-06-01

Absolute measurements of the ozone absorption coefficient in the Huggins bands at different temperatures have been carried out. Ozone is produced by an electrical discharge and stored cryogenically; differential absorption measurements are subsequently obtained in a slowly evolving mixture of ozone and molecular oxygen. High resolution (to 0.012 nm) measurements cover a spectral range (339-355 nm) where the ozone absorption shows a strong dependence on temperature. Results at 293 and 220 K are reported; they are particularly interesting in view of the utilization of this spectral region as a low-absorption reference channel for the observation of atmospheric ozone profiles by active probing techniques. Coherent radiation at two wavelengths, around 355 and 353 nm, respectively, can be obtained as third harmonic of the fundamental output of an Nd:YAG laser and by H2 Raman shifting of an XeCl excimer laser output.

User's guide to the Nimbus-4 backscatter ultraviolet experiment data sets

NASA Technical Reports Server (NTRS)

Lowrey, B. E.

1978-01-01

The first year's data from the Nimbus 4 backscatter ultraviolet (BUV) experiment have been archived in the National Space Science Data Center (NSSDC). Backscattered radiances in the ultraviolet measured by the satellite were used to compute the global total ozone for the period April 1970 - April 1971. The data sets now in the NSSDC are the results obtained by the Ozone Processing Team, which has processed the data with the purpose of determining the best quality of the data. There are four basic sets of data available in the NSSDC representing various stages in processing. The primary data base contains organized and cleaned data in telemetry units. The radiance data has had most of the engineering calibrations performed. The detailed total ozone data is the result of computations to obtain the total ozone; the Compressed Total Ozone data is a convenient condensation of the detailed total ozone. Product data sets are also included.

Tropospheric Ozone Pollution Transport Traced from the TOMS (Total Ozone Mapping Spectrometer) Instrument During the Nashville-1999 Campaign

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Frolov, A. D.; Hudson, R. D.; Witte, J. C.; Einaudi, Franco (Technical Monitor)

2000-01-01

Over the past several years, we have developed two new tropospheric ozone retrievals from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument that are of sufficient resolution to follow pollution episodes. The modified-residual technique [Hudson and Thompson, 1998; Thompson and Hudson, 1999] uses v. 7 TOMS total ozone and is applicable to tropical regimes in which the wave-one pattern in total ozone is observed. The TOMS-direct method [("TDOT" = TOMS Direct Ozone in the Troposphere; Frolov et al., 2000] represents a new algorithm that uses TOMS radiances directly (i.e., not previously processed for TOMS ozone) to extract tropospheric ozone in regions of constant stratospheric ozone and tropospheric ozone displaying high mixing ratios and variability characteristic of pollution. These events tend to occur in certain meteorological regimes. For example, mid-latitude pollution usually occurs on the backside of subtropical fronts, as low pv, usually moist air intrudes to the extra-tropics. July 1999 was a month characterized by robust pollution in the eastern US, with high ozone, as detected by TOMS, originating over south central states and moving up the Atlantic seaboard. This corresponds to 50-80 DU in tropospheric ozone column depth. In most cases, further transport occurred to the North Atlantic, with ozone plumes traveling to western Europe in 4-5 days. Examples of high ozone and transit across boundaries within the US, as well as US->Europe, give a regional context for model results and field measurements taken in the SE US during the Nashville-1999 campaign period. Validation of the TDOT maps is made with ozonesondes taken during that time. TDOT maps also show ozone pollution from Asia traveling to the western US in July 1999.

Total ozone series at Arosa (Switzerland): Homogenization and data comparison

NASA Astrophysics Data System (ADS)

Staehelin, Johannes; Renaud, Anne; Bader, Jürg; McPeters, Richard; Viatte, Pierre; Hoegger, Bruno; Bugnion, Veronique; Giroud, Marianne; Schill, Herbert

1998-03-01

Five Dobson and two Brewer spectrophotometers were used for total ozone observations at Arosa, beginning in 1926 and providing the world's longest series. In this paper we present the results of our attempts to provide a homogeneous series and discuss the data quality problems of the record. From the mid-1950s to 1992, Dobson instrument D15 was calibrated by the statistical Langley plot method. In 1986 the calibration of another Dobson spectrometer at Arosa (D101) was changed by the intercomparison with the primary world Dobson instrument (D83). A statistical model based on simultaneous measurements of D101 and D15 of the period from 1987 to 1990 was used to obtain a total ozone series in line with the primary Dobson spectrophotometer, including a correction for an optical disalignment problem of D15. The series of Dl0l from 1990 to 1995 was corrected on the basis of data from the Dobson intercomparisons of 1990 and 1995 and comparisons with other total ozone measurements of Brewer and Dobson spectrophotometers at Arosa. A transfer function between Dobson and Brewer spectrophotometric measurements of Arosa is presented, and total ozone measurements of Arosa are compared with version 7 daily overpass data of the satellite instrument the total ozone mapping spectrometer (TOMS) which operated on board Nimbus 7 from autumn 1978 to spring 1993. Available information allowing us to track back the total ozone measurements of Arosa to the measurements of the primary Dobson spectrometer reveal that the total ozone series of Arosa fluctuated no more than approximately 1% against D83 in the period from 1978 to 1995. Average shift of Arosa total ozone data against the TOMS instrument was -1.12 (±0.1)% over the lifetime of the TOMS instrument.

Instantaneous imaging of ozone in a gliding arc discharge using photofragmentation laser-induced fluorescence

NASA Astrophysics Data System (ADS)

Larsson, Kajsa; Hot, Dina; Gao, Jinlong; Kong, Chengdong; Li, Zhongshan; Aldén, Marcus; Bood, Joakim; Ehn, Andreas

2018-04-01

Ozone vapor, O3, is here visualized in a gliding arc discharge using photofragmentation laser-induced fluorescence. Ozone is imaged by first photodissociating the O3 molecule into an O radical and a vibrationally hot O2 fragment by a pump photon. Thereafter, the vibrationally excited O2 molecule absorbs a second (probe) photon that further transits the O2-molecule to an excited electronic state, and hence, fluorescence from the deexcitation process in the molecule can be detected. Both the photodissociation and excitation processes are achieved within one 248 nm KrF excimer laser pulse that is formed into a laser sheet and the fluorescence is imaged using an intensified CCD camera. The laser-induced signal in the vicinity of the plasma column formed by the gliding arc is confirmed to stem from O3 rather than plasma produced vibrationally hot O2. While both these products can be produced in plasmas a second laser pulse at 266 nm was utilized to separate the pump- from the probe-processes. Such arrangement allowed lifetime studies of vibrationally hot O2, which under these conditions were several orders of magnitude shorter than the lifetime of plasma-produced ozone.

ADEOS Total Ozone Mapping Spectrometer (TOMS) Data Products User's Guide

NASA Technical Reports Server (NTRS)

Krueger, A.; Bhartia, P. K.; McPeters, R.; Herman, J.; Wellemeyer, C.; Jaross, G.; Seftor, C.; Torres, O.; Labow, G.; Byerly, W.;

Inactivation characteristics of ozone and electrolysis process for ballast water treatment using B. subtilis spores as a probe.

PubMed

Jung, Youmi; Yoon, Yeojoon; Hong, Eunkyung; Kwon, Minhwan; Kang, Joon-Wun

2013-07-15

Since ballast water affects the ocean ecosystem, the International Maritime Organization (IMO) sets a standard for ballast water management and might impose much tighter regulations in the future. The aim of this study is to evaluate the inactivation efficiency of ozonation, electrolysis, and an ozonation-electrolysis combined process, using B. subtilis spores. In seawater ozonation, HOBr is the key active substance for inactivation, because of rapid reactivity of ozone with Br(-) in seawater. In seawater electrolysis, it is also HOBr, but not HOCl, because of the rapid reaction of HOCl with Br(-), which has not been recognized carefully, even though many electrolysis technologies have been approved by the IMO. Inactivation pattern was different in ozonation and electrolysis, which has some limitations with the tailing or lag-phase, respectively. However, each deficiency can be overcome with a combined process, which is most effective as a sequential application of ozonation followed by electrolysis. Copyright © 2013 Elsevier Ltd. All rights reserved.

Attempts to probe the ozone layer and the ultraviolet-B levels of the past.

PubMed

Björn, Lars Olof; McKenzie, Richard L

2007-07-01

To get a proper perspective on the current status of atmospheric ozone, which protects the biosphere from ultraviolet-B (UV-B; 280-315 nm) radiation, it would be of value to know how ozone and UV-B radiation have varied in the past. The record of worldwide ozone monitoring goes back only a few decades, and the record of reliable UV-B measurements is even shorter. Here we review indirect methods to assess their status further back in time. These include variations in the Sun's emission and how these affect the atmosphere, changes in the Earth's orbit, geologic imprints of atmospheric ozone, effects of catastrophic events such as volcanic eruptions, biological proxies of UV-B radiation, the spectral signature of terrestrial ozone in old recordings of star spectra, and the modeling of UV-B irradiance from ozone data and meteorological recordings. Although reliable reconstructions do not yet extend far into the past, there is some hope for future progress.

An assessment of the stray light in 25 years of Dobson total ozone data at Athens, Greece

NASA Astrophysics Data System (ADS)

Christodoulakis, J.; Varotsos, C.; Cracknell, A. P.; Tzanis, C.; Neofytos, A.

2015-07-01

In this study, we investigated the susceptibility of the Dobson spectrophotometer No. 118 to stray light interference. In this regard, a series of total ozone content measurements were carried out in Athens, Greece for air-mass values (μ) extending up to μ = 5. The monochromatic-heterochromatic stray light derived by Basher's model was used in order to evaluate the specific instrumental parameters which determine if this instrument suffers from this problem or not. The results obtained indicate that the measurements made by the Dobson instrument of the Athens station for air mass values up to 2.5, underestimates the total ozone content by 3.5 DU in average, or about 1 % of the station's mean total ozone content (TOC). The comparison of the values of the same parameters measured 15 years ago with the present ones indicates the good maintenance of the Dobson spectrophotometer No. 118. This fact is of crucial importance because the variability of the daily total ozone observations collected by the Athens Dobson Station since 1989 has proved to be representative to the variability of the mean total ozone observed over the whole mid-latitude zone of the Northern Hemisphere. This stresses the point that the Athens total ozone station, being the unique Dobson station in south-eastern Europe, may be assumed as a ground truth station for the reliable conversion of the satellite radiance observations to total ozone measurements.

Long-term changes in ozone mini-hole event frequency over the Northern Hemisphere derived from ground-based measurements

NASA Astrophysics Data System (ADS)

Krzycin, Janusz W.

2002-10-01

Decadal changes of ozone mini-hole event appearance over the Northern Hemisphere midlatitudes are examined based on daily total ozone data from seven stations having long records (four decades or more) of ozone observations. The various threshold methods for accepting and rejecting the ozone minima as mini-holes are examined. Mini-hole event activity is seen to be rather stable when averaged over a decadal time scale if the mini-holes are selected as large negative departures (exceeding 20%) relative to the moving long-term total ozone reference. The results are compared with a previous ozone mini-hole climatology derived from satellite data (TOMS measurements on board the Nimbus-7 satellite for the period 1978-93). A nonlinear statistical model (MARS), which takes into account various total ozone dynamical proxies (from NCEP-NCAR reanalysis), is used to study dynamical factors responsible for the ozone extremes over Arosa in the period 1950-99. The model explains as much as 95% of the total variance of the ozone extremes. The model-observation differences averaged over the decadal intervals are rather smooth throughout the whole period analysed. It is suggested that the short-term dynamical processes controlling the appearance of ozone extremes influenced the ozone field in a similar way before and after the onset of abrupt ozone depletion in the early 1980s. The analysis of the ozone profile and the tropopause pressure (from the ozonesondings over Hohenpeissenberg, 1966-99) during mini-hole events shows 60% ozone reduction in the lower stratosphere and an approximately 50 hPa upward shift of the thermal tropopause there.

Highlights from the 1998-2000 SHADOZ (Southern Hemisphere Additional Ozonesondes) Satellite Validation Project

NASA Technical Reports Server (NTRS)

Witte, J. C.; Thompson, A. M.; Fortuin, P.; Einsudi, Franco (Technical Monitor)

2001-01-01

There are three years of data (more than 1000 individual ozone profiles) available from a network of 10 southern hemisphere tropical and subtropical stations, designated the Southern Hemisphere ADditional OZonesondes (SHADOZ) project. Since late 1999, a tropical station in the northern hemisphere (Paramaribo, Surinam; lat/long) joined SHADOZ, providing coordinated weekly ozone and radiosonde data from the surface to approx. 7 hPa for satellite validation, process studies, and model evaluation. Profiles are also collected at: Ascension Island; Nairobi, Kenya; Irene, South Africa; R (union Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. The archive, station characteristics and photos are available at http://code9l6.gsfc.nasa.gov/Data_ services/shadoz>. SHADOZ ozone time-series and profiles in 1998-2000 display highly variable tropospheric ozone, a zonal wave-one pattern in total (and tropospheric) column ozone, and signatures of the Quasi-Biennial Oscillation (QBO) in stratospheric ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Integrated total ozone column amounts from the sondes are lower than independent measurements from a ground-based network and from the TOMS (Total Ozone Mapping Spectrometer) satellite (version 7 data).

A comprehensive mission to planet Earth: Woods Hole Space Science and Applications Advisory Committee Planning Workshop

NASA Technical Reports Server (NTRS)

1991-01-01

The NASA program Mission to Planet Earth (MTPE) is described in this set of visuals presented in Massachusetts on July 29, 1991. The problem presented in this document is that the earth system is changing and that human activity accelerates the rate of change resulting in increased greenhouse gases, decreasing levels of stratospheric ozone, acid rain, deforestation, decreasing biodiversity, and overpopulation. Various national and international organizations are coordinating global change research. The complementary space observations for this activity are sun-synchronous polar orbits, low-inclination, low altitude orbits, geostationary orbits, and ground measurements. The Geostationary Earth Observatory is the major proposed mission of MTPE. Other proposed missions are EOS Synthetic Aperture Radar, ARISTOTELES Magnetic Field Experiment, and the Global Topography Mission. Use of the NASA DC-8 aircraft is outlined as carrying out the Airborne Science and Applications Program. Approved Earth Probes Program include the Total Ozone Mapping Spectrometer (TOMS). Other packages for earth observation are described.

Tropospheric Ozone from the TOMS TDOT (TOMS-Direct-Ozone-in-Troposphere) Technique During SAFARI-2000

NASA Technical Reports Server (NTRS)

Stone, J. B.; Thompson, A. M.; Frolov, A. D.; Hudson, R. D.; Bhartia, P. K. (Technical Monitor)

2002-01-01

There are a number of published residual-type methods for deriving tropospheric ozone from TOMS (Total Ozone Mapping Spectrometer). The basic concept of these methods is that within a zone of constant stratospheric ozone, the tropospheric ozone column can be computed by subtracting stratospheric ozone from the TOMS Level 2 total ozone column, We used the modified-residual method for retrieving tropospheric ozone during SAFARI-2000 and found disagreements with in-situ ozone data over Africa in September 2000. Using the newly developed TDOT (TOMS-Direct-Ozone-in-Troposphere) method that uses TOMS radiances and a modified lookup table based on actual profiles during high ozone pollution periods, new maps were prepared and found to compare better to soundings over Lusaka, Zambia (15.5 S, 28 E), Nairobi and several African cities where MOZAIC aircraft operated in September 2000. The TDOT technique and comparisons are described in detail.

Extreme events in total ozone over Arosa - Part 1: Application of extreme value theory

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Peter, T.; Ribatet, M.; Davison, A. C.; Stübi, R.; Weihs, P.; Holawe, F.

2010-10-01

In this study ideas from extreme value theory are for the first time applied in the field of stratospheric ozone research, because statistical analysis showed that previously used concepts assuming a Gaussian distribution (e.g. fixed deviations from mean values) of total ozone data do not adequately address the structure of the extremes. We show that statistical extreme value methods are appropriate to identify ozone extremes and to describe the tails of the Arosa (Switzerland) total ozone time series. In order to accommodate the seasonal cycle in total ozone, a daily moving threshold was determined and used, with tools from extreme value theory, to analyse the frequency of days with extreme low (termed ELOs) and high (termed EHOs) total ozone at Arosa. The analysis shows that the Generalized Pareto Distribution (GPD) provides an appropriate model for the frequency distribution of total ozone above or below a mathematically well-defined threshold, thus providing a statistical description of ELOs and EHOs. The results show an increase in ELOs and a decrease in EHOs during the last decades. The fitted model represents the tails of the total ozone data set with high accuracy over the entire range (including absolute monthly minima and maxima), and enables a precise computation of the frequency distribution of ozone mini-holes (using constant thresholds). Analyzing the tails instead of a small fraction of days below constant thresholds provides deeper insight into the time series properties. Fingerprints of dynamical (e.g. ENSO, NAO) and chemical features (e.g. strong polar vortex ozone loss), and major volcanic eruptions, can be identified in the observed frequency of extreme events throughout the time series. Overall the new approach to analysis of extremes provides more information on time series properties and variability than previous approaches that use only monthly averages and/or mini-holes and mini-highs.

Extreme events in total ozone over Arosa - Part 1: Application of extreme value theory

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Peter, T.; Ribatet, M.; Davison, A. C.; Stübi, R.; Weihs, P.; Holawe, F.

2010-05-01

In this study ideas from extreme value theory are for the first time applied in the field of stratospheric ozone research, because statistical analysis showed that previously used concepts assuming a Gaussian distribution (e.g. fixed deviations from mean values) of total ozone data do not adequately address the structure of the extremes. We show that statistical extreme value methods are appropriate to identify ozone extremes and to describe the tails of the Arosa (Switzerland) total ozone time series. In order to accommodate the seasonal cycle in total ozone, a daily moving threshold was determined and used, with tools from extreme value theory, to analyse the frequency of days with extreme low (termed ELOs) and high (termed EHOs) total ozone at Arosa. The analysis shows that the Generalized Pareto Distribution (GPD) provides an appropriate model for the frequency distribution of total ozone above or below a mathematically well-defined threshold, thus providing a statistical description of ELOs and EHOs. The results show an increase in ELOs and a decrease in EHOs during the last decades. The fitted model represents the tails of the total ozone data set with high accuracy over the entire range (including absolute monthly minima and maxima), and enables a precise computation of the frequency distribution of ozone mini-holes (using constant thresholds). Analyzing the tails instead of a small fraction of days below constant thresholds provides deeper insight into the time series properties. Fingerprints of dynamical (e.g. ENSO, NAO) and chemical features (e.g. strong polar vortex ozone loss), and major volcanic eruptions, can be identified in the observed frequency of extreme events throughout the time series. Overall the new approach to analysis of extremes provides more information on time series properties and variability than previous approaches that use only monthly averages and/or mini-holes and mini-highs.

Impact of interannual variability (1979-1986) of transport and temperature on ozone as computed using a two-dimensional photochemical model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jackman, C.H.; Douglass, A.R., Chandra, S.; Stolarski, R.S.

1991-03-20

Eight years of NMC (National Meteorological Center) temperature and SBUV (solar backscattered ultraviolet) ozone data were used to calculate the monthly mean heating rates and residual circulation for use in a two-dimensional photochemical model in order to examine the interannual variability of modeled ozone. Fairly good correlations were found in the interannual behavior of modeled and measured SBUV ozone in the upper stratosphere at middle to low latitudes, where temperature dependent photochemistry is thought to dominate ozone behavior. The calculated total ozone is found to be more sensitive to the interannual residual circulation changes than to the interannual temperature changes.more » The magnitude of the modeled ozone variability is similar to the observed variability, but the observed and modeled year to year deviations are mostly uncorrelated. The large component of the observed total ozone variability at low latitudes due to the quasi-biennial oscillation (QBO) is not seen in the modeled total ozone, as only a small QBO signal is present in the heating rates, temperatures, and monthly mean residual circulation. Large interanual changes in tropospheric dynamics are believed to influence the interannual variability in the total ozone, especially at middle and high latitudes. Since these tropospheric changes and most of the QBO forcing are not included in the model formulation, it is not surprising that the interannual variability in total ozione is not well represented in the model computations.« less

Tropospheric Ozone during the TRACE-P Mission: Comparison between TOMS Satellite Retrievals and Aircraft Lidar Data, March 2001

NASA Technical Reports Server (NTRS)

Frolov, A. D.; Thompson, A. M.; Hudson, R. D.; Browell, E. V.; Oltmans, S. J.; Witte, J. C.; Bhartia, P. K. (Technical Monitor)

2002-01-01

Over the past several years, we have developed two new tropospheric ozone retrievals from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument that are of sufficient resolution to follow pollution episodes. The modified-residual technique uses v. 7 TOMS total ozone and is applicable to tropical regimes in which the wave-one pattern in total ozone is observed. The TOMS-direct method ('TDOT' = TOMS Direct Ozone in the Troposphere) represents a new algorithm that uses TOMS radiances directly to extract tropospheric ozone in regions of constant stratospheric ozone. It is not geographically restricted, using meteorological regimes as the basis for classifying TOMS radiances and for selecting appropriate comparison data. TDOT is useful where tropospheric ozone displays high mixing ratios and variability characteristic of pollution. Some of these episodes were observed downwind of Asian biomass burning during the TRACE-P (Transport and Atmospheric Chemical Evolution-Pacific) field experiment in March 2001. This paper features comparisons among TDOT tropospheric ozone column depth, integrated uv-DIAL measurements made from NASA's DC-8, and ozonesonde data.

Total ozone and surface temperature correlations during 1972 - 1981

NASA Technical Reports Server (NTRS)

Parsons, C. L.

1983-01-01

Ten years of Dobson spectrophotometer total ozone measurements and surface temperature observations were used to construct monthly mean values of the two parameters. The variability of both parameters is greatest in the months of January and February. Indeed, in January there is an apparent correlation between high total ozone values and abnormally low surface temperatures. However, the correlation does not hold in February. By reviewing the history of stratospheric warmings during this period, it is argued that the ozone and surface temperature correlation is influenced by the advection or lack of advection of ozone rich arctic air resulting from sudden stratospheric warmings.

Comparison of GOME-2/MetOp total ozone data with Brewer spectroradiometer data over the Iberian Peninsula

NASA Astrophysics Data System (ADS)

Antón, M.; Loyola, D.; López, M.; Vilaplana, J. M.; Bañón, M.; Zimmer, W.; Serrano, A.

2009-04-01

The main objective of this article is to compare the total ozone data from the new Global Ozone Monitoring Experiment instrument (GOME-2/MetOp) with reliable ground-based measurement recorded by five Brewer spectroradiometers in the Iberian Peninsula. In addition, a similar comparison for the predecessor instrument GOME/ERS-2 is described. The period of study is a whole year from May 2007 to April 2008. The results show that GOME-2/MetOp ozone data already has a very good quality, total ozone columns are on average 3.05% lower than Brewer measurements. This underestimation is higher than that obtained for GOME/ERS-2 (1.46%). However, the relative differences between GOME-2/MetOp and Brewer measurements show significantly lower variability than the differences between GOME/ERS-2 and Brewer data. Dependencies of these relative differences with respect to the satellite solar zenith angle (SZA), the satellite scan angle, the satellite cloud cover fraction (CF), and the ground-based total ozone measurements are analyzed. For both GOME instruments, differences show no significant dependence on SZA. However, GOME-2/MetOp data show a significant dependence on the satellite scan angle (+1.5%). In addition, GOME/ERS-2 differences present a clear dependence with respect to the CF and ground-based total ozone; such differences are minimized for GOME-2/MetOp. The comparison between the daily total ozone values provided by both GOME instruments shows that GOME-2/MetOp ozone data are on average 1.46% lower than GOME/ERS-2 data without any seasonal dependence. Finally, deviations of a priori climatological ozone profile used by the satellite retrieval algorithm from the true ozone profile are analyzed. Although excellent agreement between a priori climatological and measured partial ozone values is found for the middle and high stratosphere, relative differences greater than 15% are common for the troposphere and lower stratosphere.

Evaluating a New Homogeneous Total Ozone Climate Data Record from GOME/ERS-2, SCIAMACHY/Envisat, and GOME-2/MetOp-A

NASA Technical Reports Server (NTRS)

Koukouli, M.E.; Lerot, C.; Granville, J.; Goutail, F.; Lambert, J.-C.; Pommereau, J.-P.; Balis, D.; Zyrichidou, I.; Van Roozendael, M.; Coldewey-Egbers, M.;

Antarctic Ozone Hole, 2000

NASA Technical Reports Server (NTRS)

2002-01-01

Each spring the ozone layer over Antarctica nearly disappears, forming a 'hole' over the entire continent. The hole is created by the interaction of some man-made chemicals-freon, for example-with Antarctica's unique weather patterns and extremely cold temperatures. Ozone in the stratosphere absorbs ultraviolet radiation from the sun, thereby protecting living things. Since the ozone hole was discovered many of the chemicals that destroy ozone have been banned, but they will remain in the atmosphere for decades. In 2000, the ozone hole grew quicker than usual and exceptionally large. By the first week in September the hole was the largest ever-11.4 million square miles. The top image shows the average total column ozone values over Antarctica for September 2000. (Total column ozone is the amount of ozone from the ground to the top of the atmosphere. A relatively typical measurement of 300 Dobson Units is equivalent to a layer of ozone 0.12 inches thick on the Earth's surface. Levels below 220 Dobson Units are considered to be significant ozone depletion.) The record-breaking hole is likely the result of lower than average ozone levels during the Antarctic fall and winter, and exceptionally cold temperatures. In October, however (bottom image), the hole shrank dramatically, much more quickly than usual. By the end of October, the hole was only one-third of it's previous size. In a typical year, the ozone hole does not collapse until the end of November. NASA scientists were surprised by this early shrinking and speculate it is related to the region's weather. Global ozone levels are measured by the Total Ozone Mapping Spectrometer (TOMS). For more information about ozone, read the Earth Observatory's ozone fact sheet, view global ozone data and see these ozone images. Images by Greg Shirah, NASA GSFC Scientific Visualization Studio.

Fiber-Optic Coupled Lidar Receiver System to Measure Stratospheric Ozone

NASA Technical Reports Server (NTRS)

Harper, David Brent; Elsayed-Ali, Hani

1998-01-01

The measurement of ozone in the atmosphere has become increasingly important over the past two decades. Significant increases of ozone concentrations in the lower atmosphere, or troposphere, and decreases in the upper atmosphere, or stratosphere, have been attributed to man-made causes. High ozone concentrations in the troposphere pose a health hazard to plants and animals and can add to global warming. On the other hand, ozone in the stratosphere serves as a protective barrier against strong ultraviolet (UV) radiation from the sun. Man-made CFC's (chlorofluorocarbons) act as a catalyst with a free oxygen atom and an ozone molecule to produce two oxygen molecules therefore depleting the protective layer of ozone in the stratosphere. The beneficial and harmful effects of ozone require the study of ozone creation and destruction processes in the atmosphere. Therefore, to provide an accurate model of these processes, an ozone lidar system must be able to be used frequently with as large a measurement range as possible. Various methods can be used to measure atmospheric ozone concentrations. These include different airborne and balloon measurements, solar occulation satellite techniques, and the use of lasers in lidar (high detection and ranging,) systems to probe the atmosphere. Typical devices such as weather balloons can only measure within the direct vicinity of the instrument and are therefore used infrequently. Satellites use solar occulation techniques that yield low horizontal and vertical resolution column densities of ozone.

Total Ozone from the Ozone Monitoring System (OMI) using TOMS and DOAS Methods

NASA Technical Reports Server (NTRS)

Veefkind, J. P.; Bhartia, P. K.; Gleason, J.; deHaan, J. F.; Wellemeyer, C.; Levelt, P. F.

2003-01-01

The Ozone Monitoring Instrument (OMI) is the Dutch-Finnish contribution to NASA's EOS-Aura satellite scheduled for launch in January 2004. OMI is an imaging spectrometer that will measure the back-scattered Solar radiance in the wavelength range of 270 to 500 nm. The instrument provides near global coverage in one day with a spatial resolution of 13x24 square kilometers. OMI is a new instrument, with a heritage from TOMS, SBW, GOME, GOMOS and SCIAMACHY. OMI'S unique capabilities for measuring important trace gases and aerosols with a small footprint and daily global coverage, in conjunction with the other Aura instruments, will make a major contribution to our understanding of stratospheric and tropospheric chemistry and climate change. OMI will provide data continuity with the 23-year ozone record of TOMS. There are three ozone products planned for OMI: total column ozone, ozone profile and tropospheric column ozone. We are developing two different algorithms for total column ozone: one similar to the algorithm currently being used to process the TOMS data, and the other an improved version of the differential optical absorption spectroscopy (DOAS) method, which has been applied to GOME and SCIAMACHY data. The main reasons for starting with two algorithms for total ozone have to do with heritage and past experience; our long-term goal is to combine the two to develop a more accurate and reliable total ozone product for OMI. We will compare the performance of these two algorithms by applying both of them to the GOME data. We will examine where and how the results differ, and use the extensive TOMS-Dobson comparison studies to assess the performance of the DOAS algorithm.

Extreme events in total ozone over the Northern mid-latitudes: an analysis based on long-term data sets from five European ground-based stations

NASA Astrophysics Data System (ADS)

Rieder, Harald E.; Jancso, Leonhardt M.; Rocco, Stefania Di; Staehelin, Johannes; Maeder, Joerg A.; Peter, Thomas; Ribatet, Mathieu; Davison, Anthony C.; de Backer, Hugo; Koehler, Ulf; Krzyścin, Janusz; Vaníček, Karel

2011-11-01

We apply methods from extreme value theory to identify extreme events in high (termed EHOs) and low (termed ELOs) total ozone and to describe the distribution tails (i.e. very high and very low values) of five long-term European ground-based total ozone time series. The influence of these extreme events on observed mean values, long-term trends and changes is analysed. The results show a decrease in EHOs and an increase in ELOs during the last decades, and establish that the observed downward trend in column ozone during the 1970-1990s is strongly dominated by changes in the frequency of extreme events. Furthermore, it is shown that clear ‘fingerprints’ of atmospheric dynamics (NAO, ENSO) and chemistry [ozone depleting substances (ODSs), polar vortex ozone loss] can be found in the frequency distribution of ozone extremes, even if no attribution is possible from standard metrics (e.g. annual mean values). The analysis complements earlier analysis for the world's longest total ozone record at Arosa, Switzerland, confirming and revealing the strong influence of atmospheric dynamics on observed ozone changes. The results provide clear evidence that in addition to ODS, volcanic eruptions and strong/moderate ENSO and NAO events had significant influence on column ozone in the European sector.

Atmospheric Chemistry Insights from the SHADOZ Data: An IGAC Paradigm

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Bhartia, P. K. (Technical Monitor)

2002-01-01

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from ten sites comprising the Southern Hemisphere Additional Ozonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on a Trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at: http://code9l6.gsfc.nasa.gov/ Data-services/shadoz. SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone in 1998-2000. Prominent features are highly variable tropospheric ozone, a zonal wave-one pattern in total (and tropospheric) column ozone, and signatures of the Quasi-Biennial Oscillation (QBO) in stratospheric ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole, and convective mixing. Pollution transport from Africa, South American and the Maritime Continent is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

Tropical Tropospheric Ozone from SHADOZ (Southern Hemisphere ADditional Ozonesondes) Network: A Project for Satellite Research, Process Studies, Education

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Witte, Jacquelyn C.; Oltmans, Samuel J.; Schmidlin, Francis J.; Coetzee, G. J. R.; Hoegger, Bruno; Kirchhoff, V. W. J. H.; Ogawa, Toshihiro; Kawakami, Shuji; Posny, Francoise

2002-01-01

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on a trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at: . SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone. Prominent features are highly variable tropospheric ozone and a zonal wave-one pattern in total (and tropospheric) column ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole and convective mixing. Pollution transport from Africa and South America is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

Copernicus atmospheric service for stratospheric ozone: validation and intercomparison of four near real-time analyses, 2009-2012

NASA Astrophysics Data System (ADS)

Lefever, K.; van der A, R.; Baier, F.; Christophe, Y.; Errera, Q.; Eskes, H.; Flemming, J.; Inness, A.; Jones, L.; Lambert, J.-C.; Langerock, B.; Schultz, M. G.; Stein, O.; Wagner, A.; Chabrillat, S.

2014-05-01

This paper evaluates the performance of the stratospheric ozone analyses delivered in near real time by the MACC (Monitoring Atmospheric Composition and Climate) project during the 3 year period between September 2009 and September 2012. Ozone analyses produced by four different chemistry transport models and data assimilation techniques are examined: the ECMWF Integrated Forecast System (IFS) coupled to MOZART-3 (IFS-MOZART), the BIRA-IASB Belgian Assimilation System for Chemical ObsErvations (BASCOE), the DLR/RIU Synoptic Analysis of Chemical Constituents by Advanced Data Assimilation (SACADA), and the KNMI Data Assimilation Model based on Transport Model version 3 (TM3DAM). The assimilated satellite ozone retrievals differed for each system: SACADA and TM3DAM assimilated only total ozone observations, BASCOE assimilated profiles for ozone and some related species, while IFS-MOZART assimilated both types of ozone observations. The stratospheric ozone analyses are compared to independent ozone observations from ground-based instruments, ozone sondes and the ACE-FTS (Atmospheric Chemistry Experiment - Fourier Transform Spectrometer) satellite instrument. All analyses show total column values which are generally in good agreement with groundbased observations (biases <5%) and a realistic seasonal cycle. The only exceptions are found for BASCOE which systematically underestimates total ozone in the Tropics with about 7-10% at Chengkung (Taiwan, 23.1° N/121.365° E), resulting from the fact that BASCOE does not include any tropospheric processes, and for SACADA which overestimates total ozone in the absence of UV observations for the assimilation. Due to the large weight given to column observations in the assimilation procedure, IFS-MOZART is able to reproduce total column observations very well, but alternating positive and negative biases compared to ozonesonde and ACE-FTS satellite data are found in the vertical as well as an overestimation of 30 to 60% in the polar lower stratosphere during ozone depletion events. The assimilation of near real-time (NRT) Microwave Limb Sounder (MLS) profiles which only go down to 68 hPa is not able to correct for the deficiency of the underlying MOZART model, which may be related to the applied meteorological fields. Biases of BASCOE compared to ozonesonde or ACE-FTS ozone profiles do not exceed 10% over the entire vertical stratospheric range, thanks to the good performance of the model in ozone hole conditions and the assimilation of offline MLS profiles going down to 215 hPa. TM3DAM provides very realistic total ozone columns, but is not designed to provide information on the vertical distribution of ozone. Compared to ozonesondes and ACE-FTS satellite data, SACADA performs best in the Arctic, but shows large biases (>50%) for ozone in the lower stratosphere in the Tropics and in the Antarctic, especially during ozone hole conditions. This study shows that ozone analyses with realistic total ozone column densities do not necessarily yield good agreement with the observed ozone profiles. It also shows the large benefit obtained from the assimilation of a single limb-scanning instrument (Aura MLS) with a high density of observations. Hence even state-of-the-art models of stratospheric chemistry still require the assimilation of limb observations for a correct representation of the vertical distribution of ozone in the stratosphere.

Total ozone trend significance from space time variability of daily Dobson data

NASA Technical Reports Server (NTRS)

Wilcox, R. W.

1981-01-01

Estimates of standard errors of total ozone time and area means, as derived from ozone's natural temporal and spatial variability and autocorrelation in middle latitudes determined from daily Dobson data are presented. Assessing the significance of apparent total ozone trends is equivalent to assessing the standard error of the means. Standard errors of time averages depend on the temporal variability and correlation of the averaged parameter. Trend detectability is discussed, both for the present network and for satellite measurements.

SHADOZ (Southern Hemisphere ADditional Ozonesondes): A Look at the First Three Years' (1998-2000) Tropospheric Ozone Data

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Bhartia, Pawan K. (Technical Monitor)

2001-01-01

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere ADditional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; RCunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natai, Brazil. Campaign data were collected on a trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at an open archive: . SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone in 1998-2000. Prominent features are highly variable tropospheric ozone, a zonal wave-one pattern in total (and tropospheric) column ozone, and signatures of the Quasi-Biennial Oscillation (QBO) in stratospheric ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole, ENSO, and Madden-Julian circulation on convective mixing. Pollution transport from Africa, South American and the Maritime Continent is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude.

SHADOZ (Southern Hemisphere ADditional Ozonesondes}: What Have We Learned About Tropical Tropospheric Ozone from the First Three Years (1998-2000) Data

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Bhartia, P. K. (Technical Monitor)

2002-01-01

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on an Trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approximately 7 hPa and relative humidity to approximately 200 hPa, reside at: . SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone in 1998-2000. Prominent features are highly variable tropospheric ozone, a zonal wave-one pattern in total (and tropospheric) column ozone, and signatures of the Quasi-Biennial Oscillation (QBO) in stratospheric ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole, and convective mixing. Pollution transport from Africa, South American and the Maritime Continent is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

SHADOZ (Southern Hemisphere ADditional Ozonesondes): What Have We Learned About Tropical Tropospheric Ozone from the First Three Years' (1998-2000) Data?

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Bhartia, Pawan (Technical Monitor)

2002-01-01

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; RCunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on a trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at: . SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone in 1998-2000. Prominent features are highly variable tropospheric ozone, a zonal wave-one pattern in total (and tropospheric) column ozone, and signatures of the Quasi-Biennial Oscillation (QBO) in stratospheric ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole, and convective mixing. Pollution transport from Africa, South American and the Maritime Continent is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

The effect of bandwidth on filter instrument total ozone accuracy

NASA Technical Reports Server (NTRS)

Basher, R. E.

1977-01-01

The effect of the width and shape of the New Zealand filter instrument's passbands on measured total-ozone accuracy is determined using a numerical model of the spectral measurement process. The model enables the calculation of corrections for the 'bandwidth-effect' error and shows that highly attenuating passband skirts and well-suppressed leakage bands are at least as important as narrow half-bandwidths. Over typical ranges of airmass and total ozone, the range in the bandwidth-effect correction is about 2% in total ozone for the filter instrument, compared with about 1% for the Dobson instrument.

Ozone profile measurements at McMurdo Station Antarctica during the spring of 1987

NASA Technical Reports Server (NTRS)

Hofmann, D. J.; Harder, J. W.; Rosen, J. M.; Hereford, J.; Carpenter, J. R.

1988-01-01

During the Antarctic spring of 1986, 33 ozone soundings were conducted from McMurdo Station. These data indicated that the springtime decrease in ozone occurred rapidly between the altitudes of 12 and 20 km. During 1987, these measurements were repeated with 50 soundings between 29 August and 9 November. Digital conversions of standard electrochemical cell ozonesondes were again employed. The ozonesonde pumps were individually calibrated for flow rate as the high altitude performance of these pumps have been in question. While these uncertainties are not large in the region of the ozone hole, they are significant at high altitude and apparently resulted in an underestimate of total ozone of about 7 percent (average) as compared to the Total Ozone Mapping Spectrometer (TOMS) in 1986, when the flow rate recommended by the manufacturer was used. At the upper altitudes (approx. 30 km) the flow rate may be overestimated by as much as 15 percent using recommended values (see Harder et al., The UW Digital Ozonesonde: Characteristics and Flow Rate Calibration, poster paper, this workshop). These upper level values are used in the extrapolation, at constant mixing ratio, required to complete the sounding for total ozone. The first sounding was on 29 August, prior to major ozone depletion, when 274 DU total ozone (25 DU extrapolated) was observed. By early October total ozone had decreased to the 150 DU range; it then increased during mid-October owing to motion of the vortex and returned to a value of 148 DU (29 DU extrapolated) on 27 October.

Wave activity (planetary, tidal) throughout the middle atmosphere (20-100km) over the CUJO network: Satellite (TOMS) and Medium Frequency (MF) radar observations

NASA Astrophysics Data System (ADS)

Manson, A. H.; Meek, C. E.; Chshyolkova, T.; Avery, S. K.; Thorsen, D.; MacDougall, J. W.; Hocking, W.; Murayama, Y.; Igarashi, K.

2005-02-01

Planetary and tidal wave activity in the tropopause-lower stratosphere and mesosphere-lower thermosphere (MLT) is studied using combinations of ground-based (GB) and satellite instruments (2000-2002). The relatively new MFR (medium frequency radar) at Platteville (40° N, 105° W) has provided the opportunity to create an operational network of middle-latitude MFRs, stretching from 81° W-142° E, which provides winds and tides 70-100km. CUJO (Canada U.S. Japan Opportunity) comprises systems at London (43° N, 81° W), Platteville (40° N, 105° W), Saskatoon (52° N, 107° W), Wakkanai (45° N, 142° E) and Yamagawa (31° N, 131° E). It offers a significant 7000-km longitudinal sector in the North American-Pacific region, and a useful range of latitudes (12-14°) at two longitudes. Satellite data mainly involve the daily values of the total ozone column measured by the Earth Probe (EP) TOMS (Total Ozone Mapping Spectrometer) and provide a measure of tropopause-lower stratospheric planetary wave activity, as well as ozone variability. Climatologies of ozone and winds/tides involving frequency versus time (wavelet) contour plots for periods from 2-d to 30-d and the interval from mid 2000 to 2002, show that the changes with altitude, longitude and latitude are very significant and distinctive. Geometric-mean wavelets for the region of the 40° N MFRs demonstrate occasions during the autumn, winter and spring months when there are similarities in the spectral features of the lower atmosphere and at mesopause (85km) heights. Both direct planetary wave (PW) propagation into the MLT, nonlinear PW-tide interactions, and disturbances in MLT tides associated with fluctuations in the ozone forcing are considered to be possible coupling processes. The complex horizontal wave numbers of the longer period oscillations are provided in frequency contour plots for the TOMS satellite data to demonstrate the differences between lower atmospheric and MLT wave motions and their directions of propagation.

Wave Activity (Planetary, Tidal) throughout the Middle Atmoshere (25-100 km) over the CUJO Network: Satellite and Medium Frequency (MF) Radar Observations

NASA Astrophysics Data System (ADS)

Manson, A.; Meek, C.; Chshyolkova, T.; Avery, S.; Thorsen, D.; MacDougall, J.; Hocking, W.; Murayama, Y.; Igarashi, K.

Planetary and tidal wave activity in the mesosphere-lower thermosphere (MLT), and assessment of wave activity sources in the lower atmosphere, are studied using combinations of ground based (GB) and satellite instruments (2000-2002). CUJO (Canada U.S. Japan Opportunity) comprises MF radar (MFR) systems at London (43°N, 81°W), Platteville (40°N, 105°W), Saskatoon (52°N, 107°W), Wakkanai (45°N, 142°E) and Yamagawa (31°N, 131°E). It offers a significant mid-latitude 7,000 km longitudinal sector in the North American-Pacific region, and a useful range of latitudes (12-14°) at two longitudes. CUJO provides winds and tides 70-100km. Satellite data include the daily values of the total ozone column measured by the Earth Probe (EP) TOMS (Total Ozone Mapping Spectrometer) and provides a measure of tropopause-lower stratospheric planetary wave activity as well as ozone variability. The so-called UKMO data (an assimilation system) are used for correlative purposes with the TOMS data. Climatologies of ozone and winds/tides involving frequency versus time (wavelet) contour plots for periods from 2-d to 30-d and the interval from mid 2000 to 2002, show that the changes with altitude, longitude and latitude are very significant and distinctive. Geometric-mean wavelets for the region of the 40°N MFRs demonstrate occasions during the autumn, winter and spring months when there are similarities in the spectral features of the lower atmosphere and at mesopause (85km) heights. Both direct planetary wave (PW) propagation into the MLT, non-linear PW-tide interactions, and disturbances in MLT tides associated with fluctuations in the ozone forcing are considered to be possible coupling processes. The complex horizontal wave numbers of the longer period oscillations are provided in frequency contour plots for the TOMS and UKMO data to demonstrate the differences between lower atmospheric and MLT wave motions and their directions of propagation.

Extreme Events: low and high total ozone over Arosa, Switzerland

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Ribatet, M.; Stübi, R.; Weihs, P.; Holawe, F.; Peter, T.; Davison, A. C.

2009-04-01

The frequency distribution of days with extreme low (termed ELOs) and high (termed EHOs) total ozone is analyzed for the world's longest total ozone record (Arosa, Switzerland - for details see Staehelin et al.,1998a,b), with new tools from extreme value theory (e.g. Coles, 2001; Ribatet, 2007). A heavy-tail focused approach is used through the fitting of the Generalized Pareto Distribution (GPD) to the Arosa time series. Asymptotic arguments (Pickands, 1975) justify the use of the GPD for modeling exceedances over a high (or below a low) enough threshold (Coles, 2001). The analysis shows that the GPD is appropriate for modeling the frequency distribution in total ozone above or below a mathematically well-defined threshold. While previous studies focused on so termed ozone mini-holes and mini-highs (e.g. Bojkov and Balis, 2001, Koch et al., 2005), this study is the first to present a mathematical description of extreme events in low and high total ozone for a northern mid-latitudes site (Rieder et al., 2009). The results show (a) an increase in days with extreme low (ELOs) and (b) a decrease in days with extreme high total ozone (EHOs) during the last decades, (c) that the general trend in total ozone is strongly determined by these extreme events and (d) that fitting the GPD is an appropriate method for the estimation of the frequency distribution of so-called ozone mini-holes. Furthermore, this concept allows one to separate the effect of Arctic ozone depletion from that of in situ mid-latitude ozone loss. As shown by this study, ELOs and EHOs have a strong influence on mean values in total ozone and the "extremes concept" could be further used also for validation of Chemistry-Climate-Models (CCMs) within the scientific community. References: Bojkov, R. D., and Balis, D.S.: Characteristics of episodes with extremely low ozone values in the northern middle latitudes 1975-2000, Ann. Geophys., 19, 797-807, 2001. Coles, S.: An Introduction to Statistical Modeling of Extreme Values, Springer Series in Statistics, ISBN:1852334592, Springer, Berlin, 2001. Koch, G., H. Wernli, C. Schwierz, J. Staehelin, and T. Peter (2005), A composite study on the structure and formation of ozone miniholes and minihighs over central Europe, Geophys. Res. Lett., 32, L12810, doi:10.1029/2004GL022062. Pickands, J.: Statistical-Inference using extreme order Statistics, Ann. Stat., 3, 1, 119-131, 1975. Ribatet, M.: POT: Modelling peaks over a threshold, R News, 7, 34-36, 2007. Rieder, H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and Davison, A.C.: From ozone mini holes and mini highs towards extreme value theory: New insights from extreme events and non stationarity, submitted to J. Geophys. Res., 2009. Staehelin, J., Kegel, R., and Harris, N. R.: Trend analysis of the homogenized total ozone series of Arosa (Switzerland), 1929-1996, J. Geophys. Res., 103(D7), 8389-8400, doi:10.1029/97JD03650, 1998a. Staehelin, J., Renaud, A., Bader, J., McPeters, R., Viatte, P., Hoegger, B., Bugnion, V., Giroud, M., and Schill, H.: Total ozone series at Arosa (Switzerland): Homogenization and data comparison, J. Geophys. Res., 103(D5), 5827-5842, doi:10.1029/97JD02402, 1998b.

Use of Ozone to Treat Ileostomy Dermatitis in an Experimental Rat Model.

PubMed

Biçer, Şenol; Sayar, İlyas; Gürsul, Cebrail; Işık, Arda; Aydın, Merve; Peker, Kemal; Demiryilmaz, İsmail

2016-03-07

Dermatitis associated with ileostomy is an important problem that affects many people, especially children. The aim of this study was to investigate the therapeutic effects of ozone on dermatitis due to ileostomy, and to develop an alternative treatment option. A total of 28 rats were divided into 4 groups: control, ileostomy, ozone, and zinc oxide. Ileostomy was performed in all rats except the control group. After a 1-week waiting time, the ozone group was administered ozone therapy and the zinc oxide group was administered zinc oxide cream locally once a day for a total of 7 days. All rats were sacrificed at the end of this period. The efficacy of treatment was examined by biochemical, histopathological, and immunohistochemical parameters. The levels of malondialdehyde (MDA), total glutathione (tGSH), total antioxidant capacity (TAC), and total oxidant status (TOS) were measured from tissue. Vascular endothelial growth factor (VEGF) and proliferating cell nuclear antigen (PCNA) were examined immunohistochemically. Dermatitis occurred pathologically in all rats that underwent ileostomy surgery. The lowest dermatitis score was in the ozone treatment group (p<0.05). Ileostomy dermatitis caused increased levels of MDA and TOS. Ozone treatment resulted in reduced MDA and TOS levels, while the levels of tGSH and TAC were increased (p<0.05). Both VEGF and PCNA immunostaining were augmented in the ozone treatment group (p<0.05). Local ozone application may be a good alternative compared to the conventional treatment methods for the prevention of skin lesions that develop after ileostomy.

Atmospheric Ozone Response to the Disrupted 2015-2016 Quasi-Biennial Oscillation

NASA Technical Reports Server (NTRS)

Kramarova, N. A.; Tweedy, O. V.; Strahan, S. E.; Newman, P. A.; Coy, L.; Randel, W. J.; Park, M.; Waugh, D. W.; Frith, S.

2017-01-01

The quasi-biennial oscillation (QBO) - a quasi-periodic alternation between easterly and westerly zonal winds in the tropical stratosphere - is a main driver of inter-annual ozone variability in the stratosphere. During the late-2015 through 2016 time period, the QBO experienced a major disruption unlike any observed since wind measurements began in 1953. We examined the ozone response to this QBO disruption using profile ozone measurements from the Aura Microwave Limb Sounder (MLS) and Ozone Mapping and Profiler Suite Limb Profiler and total column measurements from the Solar Backscatter Ultraviolet (SBUV) Merged Ozone Data Set (MOD). Positive anomalies in stratospheric equatorial O3 developed between 50 and 30 hPa in May-September of 2016, and negative ozone anomalies were observed in the subtropics of both hemispheres. As a consequence of this QBO disruption, extratropical total ozone values during the spring-summer 2016 were at or near seasonal record lows over the more than 40 years of the total ozone record, resulting in an increase of surface UV index during northern hemisphere summer. We found very consistent responses in all considered ozone observations in terms of time, amplitude and spatial patterns. We will show the ozone changes associated with this disrupted QBO throughout the winter and spring 2017.

An observational study of the ozone dilution effect: Ozone transport in the austral spring stratosphere

NASA Technical Reports Server (NTRS)

Atkinson, Roger J.; Plumb, R. Alan

1994-01-01

In a previous observational analysis, Atkinson et al (1989) ascribed a sudden decrease in Southern Hemisphere midlatitude total ozone during December 1987 to an 'ozone dilution effect' brought about by the breakup of the polar stratospheric vortex at that time. A question alluded to but unanswered by that study was the degree to which the observed total ozone decrease might have been caused by the quasi-horizontal equatorward transport of 'ozone hold' air from within the vortex, and to what degree by the vertical advection from lower levels of air naturally low in ozone, a dynamical adjustment process which must accompany the equatorward outbreak of a discrete high-latitude airmass. In the present study, analyses of Ertel potential vorticity, TOMS total ozone, and SAGE and ozone sonde vertical profile data are employed using a novel technique to examine the 1987 event in greater detail, to answer this question. Recent progress is then reported in refining the technique and extending the investigation to examine the dynamical evolution of the austral spring stratosphere during other recent years, to shed more light on the precise nature, frequency, and severity of such 'ozone dilution' events, and the effect that this process may have on long term ozone behavior in the Southern Hemisphere.

Variability of total ozone at Arosa, Switzerland, since 1931 related to atmospheric circulation indices

NASA Astrophysics Data System (ADS)

Brönnimann, S.; Luterbacher, J.; Schmutz, C.; Wanner, H.; Staehelin, J.

2000-08-01

Atmospheric circulation determines to a considerable extent the variability of lower stratospheric ozone and can modulate its long-term trends in Europe and the North Atlantic Region. Due to dynamical stratosphere-troposphere coupling, important features of the variability of the surface pressure field are reflected in the long-term total ozone record from Arosa, Switzerland. Significant (p<0.01) correlations between total ozone and different atmospheric circulation indices (NAOI, AOI, EU1, EU2) are found in all months except for April, June, July, and November for the period 1931 to 1997. An analysis of geopotential heights for the period 1958 to 1997 shows that these circulation anomaly patterns have upper tropospheric features over the North Atlantic-European sector that are consistent with a dynamical influence on total ozone.

Extreme events in total ozone over Arosa: Application of extreme value theory and fingerprints of atmospheric dynamics and chemistry and their effects on mean values and long-term changes

NASA Astrophysics Data System (ADS)

Rieder, Harald E.; Staehelin, Johannes; Maeder, Jörg A.; Peter, Thomas; Ribatet, Mathieu; Davison, Anthony C.; Stübi, Rene; Weihs, Philipp; Holawe, Franz

2010-05-01

In this study tools from extreme value theory (e.g. Coles, 2001; Ribatet, 2007) are applied for the first time in the field of stratospheric ozone research, as statistical analysis showed that previously used concepts assuming a Gaussian distribution (e.g. fixed deviations from mean values) of total ozone data do not address the internal data structure concerning extremes adequately. The study illustrates that tools based on extreme value theory are appropriate to identify ozone extremes and to describe the tails of the world's longest total ozone record (Arosa, Switzerland - for details see Staehelin et al., 1998a,b) (Rieder et al., 2010a). A daily moving threshold was implemented for consideration of the seasonal cycle in total ozone. The frequency of days with extreme low (termed ELOs) and extreme high (termed EHOs) total ozone and the influence of those on mean values and trends is analyzed for Arosa total ozone time series. The results show (a) an increase in ELOs and (b) a decrease in EHOs during the last decades and (c) that the overall trend during the 1970s and 1980s in total ozone is strongly dominated by changes in these extreme events. After removing the extremes, the time series shows a strongly reduced trend (reduction by a factor of 2.5 for trend in annual mean). Furthermore, it is shown that the fitted model represents the tails of the total ozone data set with very high accuracy over the entire range (including absolute monthly minima and maxima). Also the frequency distribution of ozone mini-holes (using constant thresholds) can be calculated with high accuracy. Analyzing the tails instead of a small fraction of days below constant thresholds provides deeper insight in time series properties. Excursions in the frequency of extreme events reveal "fingerprints" of dynamical factors such as ENSO or NAO, and chemical factors, such as cold Arctic vortex ozone losses, as well as major volcanic eruptions of the 20th century (e.g. Gunung Agung, El Chichón, Mt. Pinatubo). Furthermore, atmospheric loading in ozone depleting substances lead to a continuous modification of column ozone in the northern hemisphere also with respect to extreme values (partly again in connection with polar vortex contributions). It is shown that application of extreme value theory allows the identification of many more such fingerprints than conventional time series analysis of annual and seasonal mean values. Especially, the analysis shows the strong influence of dynamics, revealing that even moderate ENSO and NAO events have a discernible effect on total ozone (Rieder et al., 2010b). Overall the presented new extremes concept provides new information on time series properties, variability, trends and the influence of dynamics and chemistry, complementing earlier analyses focusing only on monthly (or annual) mean values. References: Coles, S.: An Introduction to Statistical Modeling of Extreme Values, Springer Series in Statistics, ISBN:1852334592, Springer, Berlin, 2001. Ribatet, M.: POT: Modelling peaks over a threshold, R News, 7, 34-36, 2007. Rieder ,H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and A.D., Davison (2010): Extreme events in total ozone over Arosa - Part I: Application of extreme value theory, to be submitted to ACPD. Rieder, H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and A.D., Davison (2010): Extreme events in total ozone over Arosa - Part II: Fingerprints of atmospheric dynamics and chemistry and effects on mean values and long-term changes, to be submitted to ACPD. Staehelin, J., Renaud, A., Bader, J., McPeters, R., Viatte, P., Hoegger, B., Bugnion, V., Giroud, M., and Schill, H.: Total ozone series at Arosa (Switzerland): Homogenization and data comparison, J. Geophys. Res., 103(D5), 5827-5842, doi:10.1029/97JD02402, 1998a. Staehelin, J., Kegel, R., and Harris, N. R.: Trend analysis of the homogenized total ozone series of Arosa (Switzerland), 1929-1996, J. Geophys. Res., 103(D7), 8389-8400, doi:10.1029/97JD03650, 1998b.

Spectral analyses, climatology, and interannual variability of Nimbus-7 TOMS version 6 total column ozone

NASA Technical Reports Server (NTRS)

Stanford, J. L.; Ziemke, J. R.; Mcpeters, R. D.; Krueger, A. J.; Bhartia, P. K.

1995-01-01

This reference publication presents selected results from space-time spectral analyses of 13 years of version 6 daily global ozone fields from the Total Ozone Mapping Spectrometer (TOMS). One purpose is to illustrate more quantitatively the well-known richness of structure and variation in total ozone. A second purpose is to provide, for use by modelers and for comparison with other analysts' work, quantitative measures of zonal waves 1, 2, 3, and medium-scale waves 4-7 in total ozone. Their variations throughout the year and at a variety of latitudes are presented, from equatorial to polar regions. The 13-year averages are given, along with selected individual years which illustrate year-to-year variability. The largest long wave amplitudes occur in the polar winters and early springs of each hemisphere, and are related to strong wave amplification during major warning events. In low attitudes total ozone wave amplitudes are an order of magnitude smaller than at high latitudes. However, TOMS fields contain a number of equatorial dynamical features, including Rossby-gravity and Kelvin waves.

Operational Production of the Total Ozone Essential Climate Variable as Part of the Copernicus Climate Change Service (C3S)

NASA Astrophysics Data System (ADS)

Lerot, C.; Danckaert, T.; van Gent, J.; Coldewey-Egbers, M.; Loyola, D. G.; Errera, Q.; Spurr, R. J. D.; Garane, K.; Koukouli, M.; Balis, D.; Verhoelst, T.; Granville, J.; Lambert, J. C.; Van Roozendael, M.

2017-12-01

Total ozone is one of the Essential Climate Variables (ECV) operationally produced within the European Copernicus Climate Change Service (C3S), which aims at providing the geophysical information needed to monitor and study our climate system. The C3S total ozone processing chain relies on algorithmic developments realized for the last six years as part of the ESA's Ozone Climate Change Initiative (Ozone_cci) project. The C3S Climate Data Store currently contains a total ozone record based on observations from the nadir UV-Vis hyperspectral spectrometers GOME/ERS-2, SCIAMACHY/Envisat, GOME-2/Metop-A, GOME-2/Metop-B and OMI/Aura, spanning more than 23 years.Individual level-2 datasets were generated with the retrieval algorithm GODFIT (GOME-type Direct FITting). The retrievals are based on a non-linear least squares adjustment of reflectances simulated with radiative transfer tools from the LIDORT suite, to the measured spectra in the Huggins bands (325-335 nm). The inter-sensor consistency and the time stability of those data sets is significantly enhanced with the application of a soft-calibration procedure to the level-1 reflectances, in which GOME and OMI are used together as a long-term reference. Level-2 data sets are then combined to produce the level-3 GOME-type Total Ozone (GTO-ECV) record consisting of homogenized 1°x1° monthly mean grids. The merging procedure corrects for subsisting inter-satellite biases and temporal drifts. Some developments for minimizing sampling errors have also been recently investigated and will be discussed. Total ozone level-2 and level-3 data sets are regularly verified and validated by independent measurements both from space (independent algorithms and/or instruments) and ground (Brewer/Dobson/SAOZ) and their excellent quality and stability, as well as their consistency with other long-term total ozone data sets will be illustrated here. In future, in addition to be continuously extended in time, the C3S total ozone record will also incorporate new sensors such as OMPS aboard Suomi NPP or TROPOMI/S5p.

The Application of TOMS Ozone, Aerosol and UV-B Data to Madagascar Air Quality Determination

NASA Technical Reports Server (NTRS)

Aikin, A.C.; Einaudi, Franco (Technical Monitor)

2000-01-01

Total Ozone Mapping Spectrometer (TOMS) data products for the area of Madagascar are presented. In addition to total ozone, aerosols and UV-B tropospheric ozone results are shown from 1979 to the present. Tropospheric ozone over Africa and Madagascar is enhanced by 10 to 15 DU in October. This maximum coincides with the time of maximum biomass area burning in Africa and Madagascar. Ozone observations were made from 1979 to 1999 using the TOMS tropospheric ozone convective cloud differential method. As a result of easterly trade winds, ozone originating on Madagascar is transported to the west over the Mozambique Channel. In El Nino years higher level westerly winds descend to transport low level ozone easterly. This results in African continental ozone being transported east of Madagascar. Long range transport of African ozone is observed during El Nino periods. The potential of TOMS and other space data for use in public education and research on Madagascar air quality is demonstrated.

Comparison of recalculated Dobson and TOMS total ozone at Hradec Kralove, Czechoslovakia, 1978-1990

NASA Technical Reports Server (NTRS)

Stanek, Martin; Vanicek, Karel

1994-01-01

The reevaluated Dobson total ozone data from Hradec Kralove, Czechoslovakia were compared with independent Total Ozone Mapping Spectrophotometer (TOMS) 'version 6' data set. The comparison was performed by means of the parallel daily averages of ground-based and satellite total ozone pairs of the period November 1978 to December 1990. The comparison showed slight differences between both data series. Their average relative difference is 0.48 percent. The similar results have been reached for subsets of direct sun and zenith types of measurements as well. Their relative differences are 0.61 percent and 0.11 percent respectively. These facts indicate not only good mutual relation of both data sources but also reliability and accuracy of the zenith charts of the spectrophotometer No. 74 used at Hradec Kralove. Preliminary assessment of seasonal MU-dependence of the differences between Dobson and TOMS data was made while using total ozones of winter and summer months representing values of MU=2.70-5.20 and MU = 1.12-1.30 respectively. The results did not show systematic underestimation or overestimation of total ozone due to MU-dependence of the instrument at Hradec Kralove in both seasons.

Trends in total ozone over southern African stations between 1979 and 1991

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kalicharran, S.; Diab, R.D.; Sokolic, F.

1993-12-01

Trends in total ozone for the period 1979 to 1991 over the southern African subcontinent and the southern ocean islands of Marion and Gough and the South African Antarctic base of SANAE are examined. Version 6 Total Ozone Mapping Spectrometer (TOMS) data are used. With the exception of the low latitude stations (Nairobi and Harare), where a marginally increasing trend (+0.2% and +0.3%, respectively) was observed, the other stations all exhibited a decreasing trend in total ozone over the 13 year period, ranging between -1.1 and -2.6% over most of South Africa, increasing with latitude to reach -20.6% at SANAE.more » Inter-annual fluctuations at Nairobi are dominated by a Quasi-Biennial Oscillation (QBO), with maximum ozone occurring during the westerly phase of the QBO. At the extratropical locations, ozone peaks and troughs are anti-correlated with those at Nairobi and the QBO signal is less well developed and modulated by the seasonal cycle.« less

Total ozone determination by spectroradiometry in the middle ultraviolet

NASA Technical Reports Server (NTRS)

Garrison, L. M.; Doda, D. D.; Green, A. E. S.

1979-01-01

A method has been developed to determine total ozone from multispectral measurements of the direct solar irradiance. The total ozone is determined by a least squares fit to the spectrum between 290 nm and 380 nm. The aerosol extinction is accounted for by expanding it in a power series in wavelength; use of the linear term proved adequate. A mobile laboratory incorporating a sky scanner has been developed and used to obtain data to verify the method. Sun tracking, wavelength setting of the double monochromator, and data acquisition are under control of a minicomputer. Results obtained at Wallops Island, Virginia, and Palestine, Texas, agree well with simultaneous Dobson and Canterbury spectrometer and balloon ECC ozonesonde values. The wavelength calibration of the monochromator and the values for the normalized ozone absorption are the most important factors in an accurate determination of total ozone.

Use of Ozone to Treat Ileostomy Dermatitis in an Experimental Rat Model

PubMed Central

Biçer, Şenol; Sayar, İlyas; Gürsul, Cebrail; Işık, Arda; Aydın, Merve; Peker, Kemal; Demiryilmaz, İsmail

2016-01-01

Background Dermatitis associated with ileostomy is an important problem that affects many people, especially children. The aim of this study was to investigate the therapeutic effects of ozone on dermatitis due to ileostomy, and to develop an alternative treatment option. Material/Methods A total of 28 rats were divided into 4 groups: control, ileostomy, ozone, and zinc oxide. Ileostomy was performed in all rats except the control group. After a 1-week waiting time, the ozone group was administered ozone therapy and the zinc oxide group was administered zinc oxide cream locally once a day for a total of 7 days. All rats were sacrificed at the end of this period. The efficacy of treatment was examined by biochemical, histopathological, and immunohistochemical parameters. The levels of malondialdehyde (MDA), total glutathione (tGSH), total antioxidant capacity (TAC), and total oxidant status (TOS) were measured from tissue. Vascular endothelial growth factor (VEGF) and proliferating cell nuclear antigen (PCNA) were examined immunohistochemically. Results Dermatitis occurred pathologically in all rats that underwent ileostomy surgery. The lowest dermatitis score was in the ozone treatment group (p<0.05). Ileostomy dermatitis caused increased levels of MDA and TOS. Ozone treatment resulted in reduced MDA and TOS levels, while the levels of tGSH and TAC were increased (p<0.05). Both VEGF and PCNA immunostaining were augmented in the ozone treatment group (p<0.05). Conclusions Local ozone application may be a good alternative compared to the conventional treatment methods for the prevention of skin lesions that develop after ileostomy. PMID:26947591

The QBO and interannual variation in total ozone

NASA Technical Reports Server (NTRS)

Lait, Leslie R.; Schoeberl, Mark R.; Newman, Paul A.; Stolarski, Richard S.

1988-01-01

Garcia and Soloman (1987) have noted that the October monthly mean minimum total ozone amounts south of 30 S were modulated by a quasibiennial oscillation (QBO) signal. The precise mechanism behind this effect, however, is unclear. Is the modulation brought about by the circulation-produced QBO signal in the ozone concentration itself, or does the temperature QBO modulate the formation of polar stratospheric clouds (PSCs), leading to changes in the chemically induced Antarctic spring ozone decline rate. Or is some other phenomenon involved. To investigate the means through which the QBO effect occurs, a series of correlation studies has been made between polar ozone and QBO signal in ozone and temperature.

Total ozone patterns over the southern mid-latitudes: spatial correlations, extreme events and dynamical contributions

NASA Astrophysics Data System (ADS)

Rieder, Harald E.; di Rocco, Stefania; Staehelin, Johannes; Maeder, Jörg A.; Ribatet, Mathieu; Peter, Thomas; Davison, Anthony C.

2010-05-01

Tools from geostatistics and extreme value theory are applied to analyze spatial correlations in total ozone for the southern mid-latitudes. The dataset used in this study is the NIWA-assimilated total ozone dataset (Bodeker et al., 2001; Müller et al., 2008). Recently new tools from extreme value theory (Coles, 2001; Ribatet, 2007) have been applied to the world's longest total ozone record from Arosa, Switzerland (e.g. Staehelin 1998a,b) and 5 other long-term ground based stations to describe extreme events in low and high total ozone (Rieder et al., 2010a,b,c). Excursions in the frequency of extreme events reveal "fingerprints" of dynamical factors such as ENSO or NAO, and chemical factors, such as cold Arctic vortex ozone losses, as well as major volcanic eruptions of the 20th century (e.g. Gunung Agung, El Chichón, Mt. Pinatubo). Furthermore, atmospheric loading in ozone depleting substances lead to a continuous modification of column ozone in the northern hemisphere also with respect to extreme values (partly again in connection with polar vortex contributions). It is shown that application of extreme value theory allows the identification of many more of such fingerprints than conventional time series analysis on basis of annual and seasonal mean values. Especially, the analysis shows the strong influence of dynamics, revealing that even moderate ENSO and NAO events have a discernible effect on total ozone (Rieder et al., 2010b,c). Within the current study patterns in spatial correlation and frequency distributions of extreme events (e.g. ELOs and EHOs) are studied for the southern mid-latitudes. It is analyzed if "fingerprints"found for features in the northern hemisphere occur also in the southern mid-latitudes. New insights in spatial patterns of total ozone for the southern mid-latitudes are presented. Within this study the influence of changes in atmospheric dynamics (e.g. tropospheric and lower stratospheric pressure systems, ENSO) as well as influence of major volcanic eruptions (e.g. Mt. Pinatubo) and ozone depleting substances (ODS) on column ozone over the southern mid-latitudes is analyzed for the time period 1979-2007. References: Bodeker, G.E., J.C. Scott, K. Kreher, and R.L. McKenzie, Global ozone trends in potential vorticity coordinates using TOMS and GOME intercompared against the Dobson network: 1978-1998, J. Geophys. Res., 106 (D19), 23029-23042, 2001. Coles, S.: An Introduction to Statistical Modeling of Extreme Values, Springer Series in Statistics, ISBN:1852334592, Springer, Berlin, 2001. Müller, R., Grooß, J.-U., Lemmen, C., Heinze, D., Dameris, M., and Bodeker, G.: Simple measures of ozone depletion in the polar stratosphere, Atmos. Chem. Phys., 8, 251-264, 2008. Ribatet, M.: POT: Modelling peaks over a threshold, R News, 7, 34-36, 2007. Rieder ,H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and A.D., Davison (2010): Extreme events in total ozone over Arosa - Part I: Application of extreme value theory, to be submitted to ACPD. Rieder, H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and A.D., Davison (2010): Extreme events in total ozone over Arosa - Part II: Fingerprints of atmospheric dynamics and chemistry and effects on mean values and long-term changes, to be submitted to ACPD. Rieder, H.E., Jancso, L.M., Staehelin, J., Maeder, J.A., Ribatet, Peter, T., and A.D., Davison (2010): Extreme events in total ozone over the northern mid-latitudes: A case study based on long-term data sets from 5 ground-based stations, in preparation. Staehelin, J., Kegel, R., and Harris, N. R.: Trend analysis of the homogenized total ozone series of Arosa (Switzerland), 1929-1996, J. Geophys. Res., 103(D7), 8389-8400, doi:10.1029/97JD03650, 1998a. Staehelin, J., Renaud, A., Bader, J., McPeters, R., Viatte, P., Hoegger, B., Bugnion, V., Giroud, M., and Schill, H.: Total ozone series at Arosa (Switzerland): Homogenization and data comparison, J. Geophys. Res., 103(D5), 5827-5842, doi:10.1029/97JD02402, 1998b.

Large scale variability, long-term trends and extreme events in total ozone over the northern mid-latitudes based on satellite time series

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Ribatet, M.; Davison, A. C.

2009-04-01

Various generations of satellites (e.g. TOMS, GOME, OMI) made spatial datasets of column ozone available to the scientific community. This study has a special focus on column ozone over the northern mid-latitudes. Tools from geostatistics and extreme value theory are applied to analyze variability, long-term trends and frequency distributions of extreme events in total ozone. In a recent case study (Rieder et al., 2009) new tools from extreme value theory (Coles, 2001; Ribatet, 2007) have been applied to the world's longest total ozone record from Arosa, Switzerland (e.g. Staehelin 1998a,b), in order to describe extreme events in low and high total ozone. Within the current study this analysis is extended to satellite datasets for the northern mid-latitudes. Further special emphasis is given on patterns and spatial correlations and the influence of changes in atmospheric dynamics (e.g. tropospheric and lower stratospheric pressure systems) on column ozone. References: Coles, S.: An Introduction to Statistical Modeling of Extreme Values, Springer Series in Statistics, ISBN:1852334592, Springer, Berlin, 2001. Ribatet, M.: POT: Modelling peaks over a threshold, R News, 7, 34-36, 2007. Rieder, H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and Davison, A.C.: From ozone mini holes and mini highs towards extreme value theory: New insights from extreme events and non stationarity, submitted to J. Geophys. Res., 2009. Staehelin, J., Kegel, R., and Harris, N. R.: Trend analysis of the homogenized total ozone series of Arosa (Switzerland), 1929-1996, J. Geophys. Res., 103(D7), 8389-8400, doi:10.1029/97JD03650, 1998a. Staehelin, J., Renaud, A., Bader, J., McPeters, R., Viatte, P., Hoegger, B., Bugnion, V., Giroud, M., and Schill, H.: Total ozone series at Arosa (Switzerland): Homogenization and data comparison, J. Geophys. Res., 103(D5), 5827-5842, doi:10.1029/97JD02402, 1998b.

Total ozone trend over Cairo

NASA Technical Reports Server (NTRS)

Hassan, G. K. Y.

1994-01-01

A world wide interest in protecting ozone layer against manmade effects is now increasing. Assessment of the ozone depletion due to these activities depends on how successfully we can separate the natural variabilities from the data. The monthly mean values of total ozone over Cairo (30 05N) for the period 1968-1988, have been analyzed using the power spectral analysis technique. The technique used in this analysis does not depend on a pre-understanding of the natural fluctuations in the ozone data. The method depends on increasing the resolution of the spectral peaks in order to obtain the more accurate sinusoidal fluctuations with wavelength equal to or less than record length. Also it handles the possible sinusoidal fluctuations with wavelength equal to or less than record length. The results show that it is possible to detect some of the well known national fluctuations in the ozone record such as annual, semiannual, quasi-biennial and quasi-quadrennial oscillations. After separating the natural fluctuations from the ozone record, the trend analysis of total ozone over Cairo showed that a decrease of about -1.2% per decade has occurred since 1979.

Highlights of TOMS Version 9 Total Ozone Algorithm

NASA Technical Reports Server (NTRS)

Bhartia, Pawan; Haffner, David

2012-01-01

The fundamental basis of TOMS total ozone algorithm was developed some 45 years ago by Dave and Mateer. It was designed to estimate total ozone from satellite measurements of the backscattered UV radiances at few discrete wavelengths in the Huggins ozone absorption band (310-340 nm). Over the years, as the need for higher accuracy in measuring total ozone from space has increased, several improvements to the basic algorithms have been made. They include: better correction for the effects of aerosols and clouds, an improved method to account for the variation in shape of ozone profiles with season, latitude, and total ozone, and a multi-wavelength correction for remaining profile shape errors. These improvements have made it possible to retrieve total ozone with just 3 spectral channels of moderate spectral resolution (approx. 1 nm) with accuracy comparable to state-of-the-art spectral fitting algorithms like DOAS that require high spectral resolution measurements at large number of wavelengths. One of the deficiencies of the TOMS algorithm has been that it doesn't provide an error estimate. This is a particular problem in high latitudes when the profile shape errors become significant and vary with latitude, season, total ozone, and instrument viewing geometry. The primary objective of the TOMS V9 algorithm is to account for these effects in estimating the error bars. This is done by a straightforward implementation of the Rodgers optimum estimation method using a priori ozone profiles and their error covariances matrices constructed using Aura MLS and ozonesonde data. The algorithm produces a vertical ozone profile that contains 1-2.5 pieces of information (degrees of freedom of signal) depending upon solar zenith angle (SZA). The profile is integrated to obtain the total column. We provide information that shows the altitude range in which the profile is best determined by the measurements. One can use this information in data assimilation and analysis. A side benefit of this algorithm is that it is considerably simpler than the present algorithm that uses a database of 1512 profiles to retrieve total ozone. These profiles are tedious to construct and modify. Though conceptually similar to the SBUV V8 algorithm that was developed about a decade ago, the SBUV and TOMS V9 algorithms differ in detail. The TOMS algorithm uses 3 wavelengths to retrieve the profile while the SBUV algorithm uses 6-9 wavelengths, so TOMS provides less profile information. However both algorithms have comparable total ozone information and TOMS V9 can be easily adapted to use additional wavelengths from instruments like GOME, OMI and OMPS to provide better profile information at smaller SZAs. The other significant difference between the two algorithms is that while the SBUV algorithm has been optimized for deriving monthly zonal means by making an appropriate choice of the a priori error covariance matrix, the TOMS algorithm has been optimized for tracking short-term variability using month and latitude dependent covariance matrices.

Observed and theoretical variations of atmospheric ozone

NASA Technical Reports Server (NTRS)

London, J.

1976-01-01

Results are summarized from three areas of ozone research: (1) continued analysis of the global distribution of total ozone to extend the global ozone atlas to summarize 15 years (1957-72) of ground based observations; (2) analysis of balloon borne ozonesonde observations for Arosa, Switzerland, and Hohenpeissenberg, Germany (GFR); (3) contined processing of the (Orbiting Geophysical Observatory-4) satellite data to complete the analysis of the stratospheric ozone distribution from the available OGO-4 data. Results of the analysis of the total ozone observations indicated that the long term ozone variation have marked regional patterns and tend to alternate with season and hemisphere. It is becoming increasingly clear that these long period changes are associated with large scale variations in the general upper atmosphere circulation patterns.

Extreme events in total ozone: Spatio-temporal analysis from local to global scale

NASA Astrophysics Data System (ADS)

Rieder, Harald E.; Staehelin, Johannes; Maeder, Jörg A.; Ribatet, Mathieu; di Rocco, Stefania; Jancso, Leonhardt M.; Peter, Thomas; Davison, Anthony C.

2010-05-01

Recently tools from extreme value theory (e.g. Coles, 2001; Ribatet, 2007) have been applied for the first time in the field of stratospheric ozone research, as statistical analysis showed that previously used concepts assuming a Gaussian distribution (e.g. fixed deviations from mean values) of total ozone data do not address the internal data structure concerning extremes adequately (Rieder et al., 2010a,b). A case study the world's longest total ozone record (Arosa, Switzerland - for details see Staehelin et al., 1998a,b) illustrates that tools based on extreme value theory are appropriate to identify ozone extremes and to describe the tails of the total ozone record. Excursions in the frequency of extreme events reveal "fingerprints" of dynamical factors such as ENSO or NAO, and chemical factors, such as cold Arctic vortex ozone losses, as well as major volcanic eruptions of the 20th century (e.g. Gunung Agung, El Chichón, Mt. Pinatubo). Furthermore, atmospheric loading in ozone depleting substances led to a continuous modification of column ozone in the northern hemisphere also with respect to extreme values (partly again in connection with polar vortex contributions). It is shown that application of extreme value theory allows the identification of many more such fingerprints than conventional time series analysis of annual and seasonal mean values. Especially, the extremal analysis shows the strong influence of dynamics, revealing that even moderate ENSO and NAO events have a discernible effect on total ozone (Rieder et al., 2010b). Overall the extremes concept provides new information on time series properties, variability, trends and the influence of dynamics and chemistry, complementing earlier analyses focusing only on monthly (or annual) mean values. Findings described above could be proven also for the total ozone records of 5 other long-term series (Belsk, Hohenpeissenberg, Hradec Kralove, Potsdam, Uccle) showing that strong influence of atmospheric dynamics (NAO, ENSO) on total ozone is a global feature in the northern mid-latitudes (Rieder et al., 2010c). In a next step frequency distributions of extreme events are analyzed on global scale (northern and southern mid-latitudes). A specific focus here is whether findings gained through analysis of long-term European ground based stations can be clearly identified as a global phenomenon. By showing results from these three types of studies an overview of extreme events in total ozone (and the dynamical and chemical features leading to those) will be presented from local to global scales. References: Coles, S.: An Introduction to Statistical Modeling of Extreme Values, Springer Series in Statistics, ISBN:1852334592, Springer, Berlin, 2001. Ribatet, M.: POT: Modelling peaks over a threshold, R News, 7, 34-36, 2007. Rieder, H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and A.D., Davison (2010): Extreme events in total ozone over Arosa - Part I: Application of extreme value theory, to be submitted to ACPD. Rieder, H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and A.D., Davison (2010): Extreme events in total ozone over Arosa - Part II: Fingerprints of atmospheric dynamics and chemistry and effects on mean values and long-term changes, to be submitted to ACPD. Rieder, H.E., Jancso, L., Staehelin, J., Maeder, J.A., Ribatet, Peter, T., and A.D., Davison (2010): Extreme events in total ozone over the northern mid-latitudes: A case study based on long-term data sets from 5 ground-based stations, in preparation. Staehelin, J., Renaud, A., Bader, J., McPeters, R., Viatte, P., Hoegger, B., Bugnion, V., Giroud, M., and Schill, H.: Total ozone series at Arosa (Switzerland): Homogenization and data comparison, J. Geophys. Res., 103(D5), 5827-5842, doi:10.1029/97JD02402, 1998a. Staehelin, J., Kegel, R., and Harris, N. R.: Trend analysis of the homogenized total ozone series of Arosa (Switzerland), 1929-1996, J. Geophys. Res., 103(D7), 8389-8400, doi:10.1029/97JD03650, 1998b.

Total ozone variations at Reykjavik since 1957

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bjarnason, G.G.; Rognvaldsson, O.E.; Sigfusson, T.I.

1993-12-01

Total ozone measurements using a Dobson spectrophotometer have been performed on a regular basis at Reykjavik (65 deg 08 min N, 21 deg 54 min W), Iceland, since 1957. The data set for the entire period of observations has been critically examined. Due to problems related to the calibration of the instrument the data record of ozone observations is divided into two periods in the following analysis (1957-1977 and 1977-1990). A statistical model was developed to fit the data and estimate long-term changes in total ozone. The model includes seasonal variations, solar cycle influences, quasi-biennial oscillation (QBO) effects, and linearmore » trends. Some variants of the model are applied to investigate to what extent the estimated trends depend on the form of the model. Trend analysis of the revised data reveals a statistically significant linear decrease of 0.11 +/- 0.07% per year in the annual total ozone amount during the earlier period and 0.30 +/- 0.11% during the latter. The annual total ozone decline since 1977 is caused by a 0.47 +/- 0.14% decrease per year during the summer with no significant change during the winter or fall. On an annual basis, ozone varies by 3.5 +/- 0.8% over a solar cycle and by 2.1 +/- 0.6% over a QBO for the whole observation period. The effect of the 11-year solar cycle is particularly strong in the data during the early months of the year and in the westerly phase of the QBO. The data also suggest a strong response of total ozone to major solar proton events.« less

FIRE_CI2_CITATN_1HZ

Atmospheric Science Data Center

2015-11-25

... Flow Angle Sensors Hot-Wire Icing Rate Detector Pressure Transducer Reverse Flow Temperature Probes Spatial ... Condensation Nuclei Dew/Frost Point Temperature Liquid Water Content Nitrogen Dioxide Ozone Pressure Supercooled ...

On Relations Between the Ozonosphere and the General Atmospheric Circulation in Tropics

NASA Astrophysics Data System (ADS)

Kuznetsov, G. I.; Kramarova, N. A.

2006-05-01

The main features of temporal and spatial ozone distribution over tropics and their relations with peculiarities of the general atmospheric circulation are obtained using the total ozone data for the tropical region (Ozone Data for the World and TOMS (version 8)). Among the factors influencing ozone regime in tropics the properties of the region, like intertropical convergence zone and a structure of tropical tropopause, and processes such as stratosphere-troposphere exchange, migration of ozone equator, Quasi Biennial Oscillation are analyzed. To investigate the long term variability of tropical ozone detrended and de-seasonalized fields of TOMS observations are analyzed by means of EOF method. The first four EOFs explain about 75% of residual total ozone variability in tropical region. Spatial patterns of EOFs and corresponding time coefficients are closely connected with the Quasi-Biennial Oscillation (EOF-1), the 11-years Solar Cycle (EOF-2), the QBO-annual beat (EOF-3) and with the South Oscillation (EOF-4) correspondingly. The detailed analyses of temporal and spatial distribution of ozone EOF patterns reveals a distinct change of ozone fields to the both sides of equator at 10-15 latitude as well as at the zones of tropical tropopause break. A time delay of ozone QBO phase is observed while moving towards higher latitudes. Some features of the tropical ozone regime manifest themselves in the peculiarities of Antarctic Ozone Anomalies. A time variability of ozone QBO passes three months ahead of the Singapore 30 mbar zonal wind. Obtained relations let us to construct a linear regression model based on EOF decomposition to estimate total ozone monthly means over tropics. This model is successfully applied to predict 30 mbar zonal wind in dependence on tropical ozone behavior.

Report of the International Ozone Trends Panel 1988, volume 1

NASA Technical Reports Server (NTRS)

1989-01-01

Chapters on the following topics are presented: spacecraft instrument calibration and stability; information content of ozone retrieval algorithms; trends in total column ozone measurements; and trends in ozone profile measurement.

A Madden-Julian Oscillation in Tropospheric Ozone

NASA Technical Reports Server (NTRS)

Ziemke, J. R.; Chandra, S.

2003-01-01

This is the first study to indicate a Madden-Julian Oscillation (MJO) in tropospheric ozone. Tropospheric ozone is derived using differential measurements of total column ozone and stratospheric column ozone measured from total ozone mapping spectrometer (TOMS) and microwave limb sounder (MLS) instruments. Two broad regions of significant MJO signal are identified in the tropics, one in the western Pacific and the other in the eastern Pacific. Over both regions, MJO variations in tropospheric ozone represent 5-10 Dobson Unit (DU) peak-to-peak anomalies. These variations are significant compared to mean background amounts of 20 DU or less over most of the tropical Pacific. MJO signals of this magnitude would need to be considered when investigating and interpreting particular pollution events since ozone is a precursor of the hydroxyl (OH) radical, the main oxidizing agent of pollutants in the lower atmosphere.

Ozone maxima over Southern Africa: A mid-latitude link

NASA Technical Reports Server (NTRS)

Barsby, Jane; Diab, Roseanne D.

1994-01-01

The relationship between patterns of total ozone and day-to-day weather was explored over South Africa for the period 1987 to 1988. Generally, there was a fairly poor relationship (variance less than 20 percent) between total ozone and the heights of the 100, 300 and 500 hPa geopotential heights at 5 South African stations. However, over a shorter period, October to December 1988, fluctuations in the height of the 300 hPa surface accounted for 53 percent of the variance in total ozone at Cape Town. High ozone amounts are associated with the lowering of the 300 hPa surface in the presence of an upper-air trough. The role of the mid-latitude westerly waves in this respect is discussed.

Ozone and UV-B variations at Ispra from 1993 to 1997

NASA Astrophysics Data System (ADS)

Cappellani, F.; Kochler, C.

An analysis of the variability of the total ozone column at Ispra (Italy) has been performed to ascertain if, even in a short-time interval of 5 years (1993-1997), a decline of the monthly mean ozone values could be demonstrated. A linear fit of the data displays a decrease of 0.21% per year with a mean value equal to 319±2 D.U. and an amplitude of the annual cycle of about 10% of the mean. A linear regression of the surface monthly mean ozone values has also been performed showing a decreasing trend (-1% per year) that could contribute, even if for a very small amount, to the decline of the total ozone values. Ispra monthly mean total ozone data have been compared with those of three stations located within 2° latitude and 3° longitude from Ispra (Haute Provence, Hohenpeissenberg and Arosa). A linear fit of the data shows some discrepancies in the ozone changes, which can be attributed to the limited length of the observational period. An analysis has been performed to verify if the variation of ozone at Ispra is in agreement with that of the solar UV measured at a wavelength (305 nm) where the ozone absorption is still remarkable. The results, taken at a fixed solar zenith angle of 68°, show a clear anticorrelation between the monthly mean values of UV and the corresponding values of the total ozone column; the linear fit of the UV data displays an increase of 2.0% per year, much higher than expected from the ozone decrease, and a mean value of 1.4±0.1 mW m -2 nm -1.

Error in total ozone measurements arising from aerosol attenuation

NASA Technical Reports Server (NTRS)

Thomas, R. W. L.; Basher, R. E.

1979-01-01

A generalized least squares method for deducing both total ozone and aerosol extinction spectrum parameters from Dobson spectrophotometer measurements was developed. An error analysis applied to this system indicates that there is little advantage to additional measurements once a sufficient number of line pairs have been employed to solve for the selected detail in the attenuation model. It is shown that when there is a predominance of small particles (less than about 0.35 microns in diameter) the total ozone from the standard AD system is too high by about one percent. When larger particles are present the derived total ozone may be an overestimate or an underestimate but serious errors occur only for narrow polydispersions.

Dobson spectrophotometer ozone measurements during international ozone rocketsonde intercomparison

NASA Technical Reports Server (NTRS)

Parsons, C. L.

1980-01-01

Measurements of the total ozone content of the atmosphere, made with seven ground based instruments at a site near Wallops Island, Virginia, are discussed in terms for serving as control values with which the rocketborne sensor data products can be compared. These products are profiles of O3 concentration with altitude. By integrating over the range of altitudes from the surface to the rocket apogee and by appropriately estimating the residual ozone amount from apogee to the top of the atmosphere, a total ozone amount can be computed from the profiles that can be directly compared with the ground based instrumentation results. Dobson spectrophotometers were used for two of the ground-based instruments. Preliminary data collected during the IORI from Dobson spectrophotometers 72 and 38 are presented. The agreement between the two and the variability of total ozone overburden through the experiment period are discussed.

On ozone trend detection: using coupled chemistry-climate simulations to investigate early signs of total column ozone recovery

NASA Astrophysics Data System (ADS)

Keeble, James; Brown, Hannah; Abraham, N. Luke; Harris, Neil R. P.; Pyle, John A.

2018-06-01

Total column ozone values from an ensemble of UM-UKCA model simulations are examined to investigate different definitions of progress on the road to ozone recovery. The impacts of modelled internal atmospheric variability are accounted for by applying a multiple linear regression model to modelled total column ozone values, and ozone trend analysis is performed on the resulting ozone residuals. Three definitions of recovery are investigated: (i) a slowed rate of decline and the date of minimum column ozone, (ii) the identification of significant positive trends and (iii) a return to historic values. A return to past thresholds is the last state to be achieved. Minimum column ozone values, averaged from 60° S to 60° N, occur between 1990 and 1995 for each ensemble member, driven in part by the solar minimum conditions during the 1990s. When natural cycles are accounted for, identification of the year of minimum ozone in the resulting ozone residuals is uncertain, with minimum values for each ensemble member occurring at different times between 1992 and 2000. As a result of this large variability, identification of the date of minimum ozone constitutes a poor measure of ozone recovery. Trends for the 2000-2017 period are positive at most latitudes and are statistically significant in the mid-latitudes in both hemispheres when natural cycles are accounted for. This significance results largely from the large sample size of the multi-member ensemble. Significant trends cannot be identified by 2017 at the highest latitudes, due to the large interannual variability in the data, nor in the tropics, due to the small trend magnitude, although it is projected that significant trends may be identified in these regions soon thereafter. While significant positive trends in total column ozone could be identified at all latitudes by ˜ 2030, column ozone values which are lower than the 1980 annual mean can occur in the mid-latitudes until ˜ 2050, and in the tropics and high latitudes deep into the second half of the 21st century.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lovill, J.E.; Sullivan, T.J.; Weichel, R.L.

A total ozone retrieval model has been developed to process radiance data gathered by a satellite-mounted multichannel filter radiometer (MFR). Extensive effort went into theoretical radiative transfer modeling, a retrieval scheme was developed, and the technique was applied to the MFR radiance measurements. The high quality of the total ozone retrieval results was determined through comparisons with Dobson measurements. Included in the report are global total ozone maps for 20 days between May 12 and July 5, 1977. A comparison of MFR results for 13 days in June 1977 with Dobson spectrophotometer measurements of ozone for the same period showedmore » good agreement: there was a root-mean-square difference of 6.2% (equivalent to 20.2 m.atm.cm). The estimated global total ozone value for June 1977 (296 m.atm.cm) was in good agreement with satellite backscatter ultraviolet data for June 1970 (304 m.atm.cm) and June 1971 (preliminary data--299 m.atm.cm).« less

Total ozone patterns over the northern mid-latitudes: spatial correlations, extreme events and dynamical contributions

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Ribatet, M.; Bodeker, G. E.; Davison, A. C.

2009-04-01

Tools from geostatistics and extreme value theory are applied to analyze spatial correlations in total ozone for the northern mid-latitudes. The dataset used in this study is the NIWA combined total ozone dataset (Bodeker et al., 2001; Müller et al., 2008). New tools from extreme value theory (Coles, 2001; Ribatet, 2007) have recently been applied to the world's longest total ozone record from Arosa, Switzerland (e.g. Staehelin 1998a,b), in order to describe extreme events in low and high total ozone (Rieder et al., 200x). Within the current study, patterns in spatial correlation and frequency distributions of extreme events (e.g. ELOs and EHOs) are studied for the northern mid-latitudes. New insights in spatial patterns of total ozone for the northern mid-latitudes are presented. Koch et al. (2005) found that the increase in fast isentropic transport of tropical air to northern mid-latitudes contributed significantly to ozone changes between 1980 and 1989. Within this study the influence of changes in atmospheric dynamics (e.g. tropospheric and lower stratospheric pressure systems) on column ozone over the northern mid-latitudes is analyzed for the time period 1979-2007. References: Bodeker, G.E., J.C. Scott, K. Kreher, and R.L. McKenzie, Global ozone trends in potential vorticity coordinates using TOMS and GOME intercompared against the Dobson network: 1978-1998, J. Geophys. Res., 106 (D19), 23029-23042, 2001. Coles, S.: An Introduction to Statistical Modeling of Extreme Values, Springer Series in Statistics, ISBN:1852334592, Springer, Berlin, 2001. Koch, G., H. Wernli, C. Schwierz, J. Staehelin, and T. Peter (2005), A composite study on the structure and formation of ozone miniholes and minihighs over central Europe, Geophys. Res. Lett., 32, L12810, doi:10.1029/2004GL022062. Müller, R., Grooß, J.-U., Lemmen, C., Heinze, D., Dameris, M., and Bodeker, G.: Simple measures of ozone depletion in the polar stratosphere, Atmos. Chem. Phys., 8, 251-264, 2008. Ribatet, M.: POT: Modelling peaks over a threshold, R News, 7, 34-36, 2007. Rieder, H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and Davison, A.C.: From ozone mini holes and mini highs towards extreme value theory: New insights from extreme events and non stationarity, submitted to J. Geophys. Res., 200x. Staehelin, J., Kegel, R., and Harris, N. R.: Trend analysis of the homogenized total ozone series of Arosa (Switzerland), 1929-1996, J. Geophys. Res., 103(D7), 8389-8400, doi:10.1029/97JD03650, 1998a. Staehelin, J., Renaud, A., Bader, J., McPeters, R., Viatte, P., Hoegger, B., Bugnion, V., Giroud, M., and Schill, H.: Total ozone series at Arosa (Switzerland): Homogenization and data comparison, J. Geophys. Res., 103(D5), 5827-5842, doi:10.1029/97JD02402, 1998b.

The long-term changes in total ozone, as derived from Dobson measurements at Arosa (1948-2001)

NASA Astrophysics Data System (ADS)

Krzyscin, J. W.

2003-04-01

The longest possible total ozone time series (Arosa, Switzerland) is examined for a detection of trends. Two-step procedure is proposed to estimate the long-term (decadal) variations in the ozone time series. The first step consists of a standard least-squares multiple regression applied to the total ozone monthly means to parameterize "natural" (related to the oscillations in the atmospheric dynamics) variations in the analyzed time series. The standard proxies for the dynamical ozone variations are used including; the 11-year solar activity cycle, and indices of QBO, ENSO and NAO. We use the detrended time series of temperature at 100 hPa and 500 hPa over Arosa to parameterize short-term variations (with time periods<1 year) in total ozone related to local changes in the meteorological conditions over the station. The second step consists of a smooth-curve fitting to the total ozone residuals (original minus modeled "natural" time series), the time derivation applied to this curve to obtain local trends, and bootstrapping of the residual time series to estimate the standard error of local trends. Locally weighted regression and the wavelet analysis methodology are used to extract the smooth component out of the residual time series. The time integral over the local trend values provides the cumulative long-term change since the data beginning. Examining the pattern of the cumulative change we see the periods with total ozone loss (the end of 50s up to early 60s - probably the effect of the nuclear bomb tests), recovery (mid 60s up to beginning of 70s), apparent decrease (beginning of 70s lasting to mid 90s - probably the effect of the atmosphere contamination by anthropogenic substances containing chlorine), and with a kind of stabilization or recovery (starting in the mid of 90s - probably the effect of the Montreal protocol to eliminate substances reducing the ozone layer). We can also estimate that a full ozone recovery (return to the undisturbed total ozone level from the beginning of 70s) is expected around 2050. We propose to calculate both time series of local trends and the cumulative long-term change instead single trend value derived as a slope of straight line fit to the data.

An assessment of the stray-light in 25 years Dobson total ozone data at Athens, Greece

NASA Astrophysics Data System (ADS)

Christodoulakis, J.; Varotsos, C.; Cracknell, A. P.; Tzanis, C.; Neofytos, A.

2015-02-01

In this study, we investigated the susceptibility of the Dobson spectrophotometer No. 118 to stray-light interference. In this regard, a series of total ozone content measurements were carried out in Athens, Greece for airmass values (μ) extending up to μ = 5. The monochromatic-heterochromatic stray-light derived by Basher's model was used in order to evaluate the specific instrumental parameters which determine if this instrument suffers from this problem or not. The results obtained indicate that the Athens Dobson instrument appears to have an insignificant stray-light error. The comparison of the values of the same parameters measured 15 years ago with the present ones indicates the good maintenance of the Dobson spectrophotometer No. 118. This fact is of crucial importance because the variability of the daily total ozone observations collected by the Athens Dobson Station since 1989 has proved to be representative to the variability of the mean total ozone observed over the whole mid-latitude zone of the Northern Hemisphere. This stresses the point that the Athens total ozone station, being the unique Dobson station in south eastern Europe, may be assumed as a ground-truth station for the reliable conversion of the satellite radiance observations to total ozone measurements.

User's guide for the Solar Backscattered Ultraviolet (SBUV) instrument first year ozone-S data set

NASA Technical Reports Server (NTRS)

Fleig, A. J.; Klenk, K. F.; Bhartia, P. K.; Gordon, D.; Schneider, W. H.

1982-01-01

Total-ozone and ozone vertical profile results for Solar Backscattered Ultraviolet/Total Ozone Mapping Spectrometer (SBUV/TOMS) Nimbus 7 operation from November 1978 to November 1979 are available. The algorithm used have been thoroughly tested, the instrument performance has been examined in details, and the ozone results have been compared with Dobson, Umkehr, balloon, and rocket observations. The accuracy and precision of the satellite ozone data are good to at least within the ability of the ground truth to check and are self-consistent to within the specifications of the instrument. The 'SBUV User's Guide' describes the SBUV experiment and algorithms used. Detailed information on the data available on computer tape is provided including how to order tapes from the National Space Science Data Center.

Global distribution of ozone for various seasons

NASA Technical Reports Server (NTRS)

Koprova, L. I.

1979-01-01

A technique which was used to obtain a catalog of the seasonal global distribution of ozone is presented. The technique is based on the simultaneous use of 1964-1975 data on the total ozone content from a worldwide network of ozonometric stations and on the vertical ozone profile from ozone sounding stations.

Antimicrobial Effect of Ozone Made by KP Syringe of High-Frequency Ozone Generator

PubMed Central

Prebeg, Domagoj; Katunarić, Marina; Budimir, Ana; Šegović, Sanja; Anić, Ivica

2016-01-01

Aim The aim of this study was to evaluate in vitro the antibacterial effect of ozone on suspension of three different bacteria inoculated in prepared canals of extracted human teeth. Material and methods Ozone was produced by special KP syringe of high frequency ozone generator Ozonytron (Biozonix, München, Germany) from aspirated atmospheric air by dielectric barrier discharge and applied through the tip of the syringe to the prepared root canal. The microorganisms used were Enterococcus faecalis, Staphylococcus aureus and Staphylococcus epidermidis. Results However, none of the methods was 100% effective against the three bacterial types in suspension. Application of ozone significantly decreased the absolute count of microorganisms (89.3%), as well as the count of each type of bacteria separately (Staphylococcus aureus 94.0%; Staphylococcus epidermidis 88.6% and Enterococcus faecalis 79.7%). Ozone generated by KP syringe was statistically more effective compared to NaOCl as positive control, for Staphylococcus aureus and Staphylococcus epidermidis. Conclusion The absolute count of Enterococcus faecalis was statistically decreased without a statistically significant difference between the tested group and positive control, respectively. Among the three types of bacteria in suspension, KP probe had the lowest antimicrobial effect against Enterococcus faecalis. PMID:27789911

Effects of local meteorology and aerosols on ozone and nitrogen dioxide retrievals from OMI and pandora spectrometers in Maryland, USA during DISCOVER-AQ 2011.

PubMed

Reed, Andra J; Thompson, Anne M; Kollonige, Debra E; Martins, Douglas K; Tzortziou, Maria A; Herman, Jay R; Berkoff, Timothy A; Abuhassan, Nader K; Cede, Alexander

An analysis is presented for both ground- and satellite-based retrievals of total column ozone and nitrogen dioxide levels from the Washington, D.C., and Baltimore, Maryland, metropolitan area during the NASA-sponsored July 2011 campaign of D eriving I nformation on S urface CO nditions from Column and VER tically Resolved Observations Relevant to A ir Q uality (DISCOVER-AQ). Satellite retrievals of total column ozone and nitrogen dioxide from the Ozone Monitoring Instrument (OMI) on the Aura satellite are used, while Pandora spectrometers provide total column ozone and nitrogen dioxide amounts from the ground. We found that OMI and Pandora agree well (residuals within ±25 % for nitrogen dioxide, and ±4.5 % for ozone) for a majority of coincident observations during July 2011. Comparisons with surface nitrogen dioxide from a Teledyne API 200 EU NO x Analyzer showed nitrogen dioxide diurnal variability that was consistent with measurements by Pandora. However, the wide OMI field of view, clouds, and aerosols affected retrievals on certain days, resulting in differences between Pandora and OMI of up to ±65 % for total column nitrogen dioxide, and ±23 % for total column ozone. As expected, significant cloud cover (cloud fraction >0.2) was the most important parameter affecting comparisons of ozone retrievals; however, small, passing cumulus clouds that do not coincide with a high (>0.2) cloud fraction, or low aerosol layers which cause significant backscatter near the ground affected the comparisons of total column nitrogen dioxide retrievals. Our results will impact post-processing satellite retrieval algorithms and quality control procedures.

An Extended View of Mars Ozone

NASA Technical Reports Server (NTRS)

Fast, Kelly

2011-01-01

We present an ongoing effort to characterize chemistry in Mars' atmosphere in multiple seasons on timescales longer than flight missions through coordinated efforts by GSFC's HIPWAC spectrometer and Mars Express SPICAM, archival measurements, and tests/application of photochemical models. The trace species ozone (O3) is an effective probe of atmospheric chemistry because it is destroyed by chemically active odd hydrogen species (HO(sub x)) that result from water vapor photolysis. Observed ozone abundance on Mars is a critical test for three-dimensional photochemistry coupled general circulation models (GCM) that make specific predictions for the spatial, diurnal, and seasonal behavior of ozone and related chemistry and climatological conditions. Coordinated measurements by HIPWAC and SPICAM quantitatively linked mission data to the 23-year GSFC ozone data record and also revealed unanticipated inter-decadal variability of same-season ozone abundances, a possible indicator of changing cloud activity (heterogeneous sink for HO(sub x)). A detailed study of long-term conditions is critical to characterizing the predictability of Mars' seasonal chemical behavior, particularly in light of the implications of and the lack of explanation for reported methane behavior.

Long-term changes (1980-2003) in total ozone time series over Northern Hemisphere midlatitudes

NASA Astrophysics Data System (ADS)

Białek, Małgorzata

2006-03-01

Long-term changes in total ozone time series for Arosa, Belsk, Boulder and Sapporo stations are examined. For each station we analyze time series of the following statistical characteristics of the distribution of daily ozone data: seasonal mean, standard deviation, maximum and minimum of total daily ozone values for all seasons. The iterative statistical model is proposed to estimate trends and long-term changes in the statistical distribution of the daily total ozone data. The trends are calculated for the period 1980-2003. We observe lessening of negative trends in the seasonal means as compared to those calculated by WMO for 1980-2000. We discuss a possibility of a change of the distribution shape of ozone daily data using the Kolmogorov-Smirnov test and comparing trend values in the seasonal mean, standard deviation, maximum and minimum time series for the selected stations and seasons. The distribution shift toward lower values without a change in the distribution shape is suggested with the following exceptions: the spreading of the distribution toward lower values for Belsk during winter and no decisive result for Sapporo and Boulder in summer.

Atmospheric soundings by SPICAM occultation observations: aerosol and ozone vertical profiles

NASA Astrophysics Data System (ADS)

Montmessin, F.

2005-12-01

The SPICAM instrument is a highly versatile, dual spectrometer probing both the UV and the NIR spectral region and is currently flying around Mars onboard Mars Express. Since the beginning of MEx operations, SPICAM has collected about thousand atmospheric profiles while observing in a solar or a stellar occultation mode. UV spectra bear the signatures of several species; i.e carbon dioxide, ozone and aerosols, while infrared spectra potentially bring information on atmospheric condensates and on water vapor. This presentation will focus on the measured aerosol, ozone and water vapor profiles. For the aerosol, we will emphasize the numerous observations made in the polar night and will also discuss some high altitude clouds discovered in the southern hemisphere. Ozone and water vapor profiles will be presented along with some General Circulation Model comparisons. This work has been supported by CNES.

Characterization of Vertical Ozonesonde Measurements in Equatorial Regions Utilizing the Cooperative Enterprise SHADOZ

NASA Technical Reports Server (NTRS)

Schmidlin, F. J.; Thompson, A. M.; Holdren, D. H.; Northam, E. T.; Witte, J. C.; Oltmans, S. J.; Hoegger, B.; Levrat, G. M.; Kirchhoff, V.

2000-01-01

Vertical ozone profiles between the Equator and 10 S latitude available from the Southern Hemisphere Additional Ozone (SHADOZ) program provide consistent data Ozone sets from up to 10 sounding locations. SHADOZ designed to provide independent ozone profiles in the tropics for evaluation of satellite ozone data and models has made available over 600 soundings over the period 1998-1999. These observations provide an ideal data base for the detailed description of ozone and afford differential comparison between sites. TOMS total ozone when compared with correlative integrated total ozone overburden from the sondes is found to be negatively biased when using the classical constant mixing ratio procedure to determine residual ozone. On the other hand, the climatological method proposed by McPeters and Labow appears to give consistent results but is positively biased. The longer then two years series of measurements also was subjected to harmonic analysis to examine data cycles. These will be discussed as well.

Nimbus-7 TOMS Antarctic ozone atlas: August through November, 1989

NASA Technical Reports Server (NTRS)

Krueger, Arlin J.; Penn, Lanning M.; Larko, David E.; Doiron, Scott D.; Guimaraes, Patricia T.

1990-01-01

Because of the great environmental significance of ozone and to support continuing research at the Antarctic and other Southern Hemisphere stations, the development of the 1989 ozone hole was monitored using data from the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) instrument, produced in near-real-time. This Atlas provides a complete set of daily polar orthographic projections of the TOMS total ozone measurements over the Southern Hemisphere for the period August 1 through November 30, 1989. The 1989 ozone hole developed in a manner similar to that of 1987, reaching a comparable depth in early October. This was in sharp contrast to the much weaker hole of 1988. The 1989 ozone hole remained at polar latitudes as it filled in November, in contrast to other recent years when the hole drifted to mid-latitudes before disappearing. Daily ozone values above selected Southern Hemisphere stations are presented, along with comparisons of the 1989 ozone distribution to that of other years.

From ozone mini-holes and mini-highs towards extreme value theory: New insights from extreme events and non-stationarity

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Ribatet, M.; Stübi, R.; Weihs, P.; Holawe, F.; Peter, T.; Davison, A. C.

2009-04-01

Over the last few decades negative trends in stratospheric ozone have been studied because of the direct link between decreasing stratospheric ozone and increasing surface UV-radiation. Recently a discussion on ozone recovery has begun. Long-term measurements of total ozone extending back earlier than 1958 are limited and only available from a few stations in the northern hemisphere. The world's longest total ozone record is available from Arosa, Switzerland (Staehelin et al., 1998a,b). At this site total ozone measurements have been made since late 1926 through the present day. Within this study (Rieder et al., 2009) new tools from extreme value theory (e.g. Coles, 2001; Ribatet, 2007) are applied to select mathematically well-defined thresholds for extreme low and extreme high total ozone. A heavy-tail focused approach is used by fitting the Generalized Pareto Distribution (GPD) to the Arosa time series. Asymptotic arguments (Pickands, 1975) justify the use of the GPD for modeling exceedances over a sufficiently high (or below a sufficiently low) threshold (Coles, 2001). More precisely, the GPD is the limiting distribution of normalized excesses over a threshold, as the threshold approaches the endpoint of the distribution. In practice, GPD parameters are fitted, to exceedances by maximum likelihood or other methods - such as the probability weighted moments. A preliminary step consists in defining an appropriate threshold for which the asymptotic GPD approximation holds. Suitable tools for threshold selection as the MRL-plot (mean residual life plot) and TC-plot (stability plot) from the POT-package (Ribatet, 2007) are presented. The frequency distribution of extremes in low (termed ELOs) and high (termed EHOs) total ozone and their influence on the long-term changes in total ozone are analyzed. Further it is shown that from the GPD-model the distribution of so-called ozone mini holes (e.g. Bojkov and Balis, 2001) can be precisely estimated and that the "extremes concept" provides new information on the data distribution and variability within the Arosa record as well as on the influence of ELOs and EHOs on the long-term trends of the ozone time series. References: Bojkov, R. D., and Balis, D.S.: Characteristics of episodes with extremely low ozone values in the northern middle latitudes 1975-2000, Ann. Geophys., 19, 797-807, 2001. Coles, S.: An Introduction to Statistical Modeling of Extreme Values, Springer Series in Statistics, ISBN:1852334592, Springer, Berlin, 2001. Pickands, J.: Statistical inference using extreme order statistics, Ann. Stat., 3, 1, 119-131, 1975. Ribatet, M.: POT: Modelling peaks over a threshold, R News, 7, 34-36, 2007. Rieder, H.E., Staehelin, J., Maeder, J.A., Stübi, R., Weihs, P., Holawe, F., and M. Ribatet: From ozone mini holes and mini highs towards extreme value theory: New insights from extreme events and non stationarity, submitted to J. Geophys. Res., 2009. Staehelin, J., Kegel, R., and Harris, N. R.: Trend analysis of the homogenized total ozone series of Arosa (Switzerland), 1929-1996, J. Geophys. Res., 103(D7), 8389-8400, doi:10.1029/97JD03650, 1998a. Staehelin, J., Renaud, A., Bader, J., McPeters, R., Viatte, P., Hoegger, B., Bugnion, V., Giroud, M., and Schill, H.: Total ozone series at Arosa (Switzerland): Homogenization and data comparison, J. Geophys. Res., 103(D5), 5827-5842, doi:10.1029/97JD02402, 1998b.

Total ozone observation by sun photometry at Arosa, Switzerland

NASA Astrophysics Data System (ADS)

Staehelin, Johannes; Schill, Herbert; Hoegger, Bruno; Viatte, Pierre; Levrat, Gilbert; Gamma, Adrian

1995-07-01

The method used for ground-based total ozone observations and the design of two instruments used to monitor atmospheric total ozone at Arosa (Dobson spectrophotometer and Brewer spectrometer) are briefly described. Two different procedures of the calibration of the Dobson spectrometer, both based on the Langley plot method, are presented. Data quality problems that occured in recent years in the measurements of one Dobson instrument at Arosa are discussed, and two different methods to reassess total ozone observations are compared. Two partially automated Dobson spectrophotometers and two completely automated Brewer spectrometers are currently in operation at Arosa. Careful comparison of the results of the measurements of the different instruments yields valuable information of possible small long- term drifts of the instruments involved in the operational measurements.

Application of infrared techniques to the study of atmospheric ozone

NASA Astrophysics Data System (ADS)

Secroun, C.; Barbe, A.; Marche, P.; Jouve, P.

The present investigation is concerned with the utilization of the infrared wavelength region for the study of the ozone in the atmosphere, taking into account three atmospheric windows including the wavelength ranges near 10, 5, and 3 micrometers. More than 3200 spectral lines could be assigned to different bands of the ozone spectrum. Laboratory studies formed one part of the investigation. Spectral frequencies, absorption line intensities, and linewidths were determined for ozone. Some of the obtained results were employed in connection with data provided by the radiometric probe LIMS on board the Nimbus-7 satellite. The second part of the investigation involved a study of the atmosphere. The same spectrometer as in the laboratory study was utilized, and the sun was employed as radiation source. The obtained results were compared with data provided by a Dobson spectrophotometer. Attention is also given to vertical concentration profiles. It is concluded that infrared absorption spectroscopy represents a suitable technique for studies of atmospheric ozone.

An Extended View of Ozone and Chemistry in the Atmosphere of Mars

NASA Technical Reports Server (NTRS)

Smith, Ramsey L.; Fast, Kelly E.; Kostiuk, T.; Lefevre, Frank; Hewagama, Tilak; Livengood, Timothy A.

2011-01-01

We present an ongoing effort to characterize chemistry in Mars' atmosphere in multiple seasons on timescales longer than spaceflight missions through coordinated efforts by GSFC's HIPWAC spectrometer and Mars Express SPICAM, archival measurements, and tests/application of photochemical models. The trace species ozone (03) is an effective probe of Mars' atmospheric chemistry because it is destroyed by odd-hydrogen species (HOx, from water vapor photolysis). Observed ozone is a critical test for specific predictions by 3-D photochemical models (spatial, diurnal, seasonal). Coordinated measurements by HIPWAC and SPICAM quantitatively linked mission data to the 23-year GSFC ozone data record and also revealed unanticipated inter-decadal variability of same-season ozone abundances, a possible indicator of changing cloud activity (heterogeneous sink for HOx). A detailed study of long-term conditions is critical to characterizing the predictability of Mars' seasonal chemical behavior, particularly in light of the implications of and the lack of explanation for reported methane behavior.

Ozone fumigation for safety and quality of wine grapes in postharvest dehydration.

PubMed

Botondi, Rinaldo; De Sanctis, Federica; Moscatelli, Niccolò; Vettraino, Anna Maria; Catelli, Cesare; Mencarelli, Fabio

2015-12-01

This paper proposes postharvest ozone fumigation (as a method) to control microorganisms and evaluate the effect on polyphenols, anthocyanins, carotenoids and cell wall enzymes during the grape dehydration for wine production. Pignola grapes were ozone-treated (1.5 g/h) for 18 h (A=shock treatment), then dehydrated or ozone-treated (1.5 g/h) for 18 h and at 0.5 g/h for 4 h each day (B=long-term treatment) during dehydration. Treatment and dehydration were performed at 10 °C. No significant difference was found for total carotenoid, total phenolic and total anthocyanin contents after 18 h of O3 treatment. A significant decrease in phenolic and anthocyanin contents occurred during treatment B. Also carotenoids were affected by B ozone treatment. Pectin methylesterase (PME) and polygalacturonase (PG) activities were higher in A-treated grapes during dehydration. Finally, ozone reduced fungi and yeasts by 50%. Shock ozone fumigation (A treatment) before dehydration can be used to reduce the microbial count during dehydration without affecting polyphenol and carotenoid contents. Copyright © 2015 Elsevier Ltd. All rights reserved.

A technique for evaluating the influence of spatial sampling on the determination of global mean total columnar ozone

NASA Technical Reports Server (NTRS)

Tolson, R. H.

1981-01-01

A technique is described for providing a means of evaluating the influence of spatial sampling on the determination of global mean total columnar ozone. A finite number of coefficients in the expansion are determined, and the truncated part of the expansion is shown to contribute an error to the estimate, which depends strongly on the spatial sampling and is relatively insensitive to data noise. First and second order statistics are derived for each term in a spherical harmonic expansion which represents the ozone field, and the statistics are used to estimate systematic and random errors in the estimates of total ozone.

The use of visible-channel data from NOAA satellites to measure total ozone amount over Antarctica

NASA Technical Reports Server (NTRS)

Boime, Robert D.; Warren, Steven G.; Gruber, Arnold

1994-01-01

Accurate, detailed maps of total ozone were not available until the launch of the Total Ozone Mapping Spectrometer (TOMS) in late 1978. However, the Scanning Radiometer (SR), an instrument on board the NOAA series satellites during the 1970s, had a visible channel that overlapped closely with the Chappuis absorption band of ozone. We are investigating whether data from the SR can be used to map Antarctic ozone prior to 1978. The method is being developed with 1980s data from the Advanced Very High Resolution Radiometer (AVHRR), which succeeded the SR on the NOAA polar-orbiting satellites. Visible-derived total ozone maps can then be compared able on the NOAA satellites, which precludes the use of a differential absorption technique to measure ozone. Consequently, our method works exclusively over scenes whose albedos are large and unvarying, i.e. scenes that contain ice sheets and/or uniform cloud-cover. Initial comparisons of time series for October-December 1987 at locations in East Antarctica show that the visible absorption by ozone in measurable and that the technique may be usable for the 1970s, but with much less accuracy than TOMS. This initial test assumes that clouds, snow, and ice all reflect the same percentage of visible light towards the satellite, regardless of satellite position or environmental conditions. This assumption is our greatest source of error. To improve the accuracy of ozone retrievals, realistic anisotropic reflectance factors are needed, which are strongly influenced by cloud and snow surface features.

Modeling and Prediction of Monthly Total Ozone Concentrations by Use of an Artificial Neural Network Based on Principal Component Analysis

NASA Astrophysics Data System (ADS)

Chattopadhyay, Surajit; Chattopadhyay, Goutami

2012-10-01

In the work discussed in this paper we considered total ozone time series over Kolkata (22°34'10.92″N, 88°22'10.92″E), an urban area in eastern India. Using cloud cover, average temperature, and rainfall as the predictors, we developed an artificial neural network, in the form of a multilayer perceptron with sigmoid non-linearity, for prediction of monthly total ozone concentrations from values of the predictors in previous months. We also estimated total ozone from values of the predictors in the same month. Before development of the neural network model we removed multicollinearity by means of principal component analysis. On the basis of the variables extracted by principal component analysis, we developed three artificial neural network models. By rigorous statistical assessment it was found that cloud cover and rainfall can act as good predictors for monthly total ozone when they are considered as the set of input variables for the neural network model constructed in the form of a multilayer perceptron. In general, the artificial neural network has good potential for predicting and estimating monthly total ozone on the basis of the meteorological predictors. It was further observed that during pre-monsoon and winter seasons, the proposed models perform better than during and after the monsoon.

Some observations on the role of planetary waves in determining the spring time ozone distribution in the Antarctic

NASA Technical Reports Server (NTRS)

Chandra, S.; Mcpeters, R. D.

1986-01-01

Ozone measurements from 1970 to 1984 from the Nimbus 4 backscattered ultraviolet and the Nimbus 7 solar backscattered ultraviolet spectrometers show significant decrease in total ozone only after 1979. The downward trend is most apparent in October south of 70 deg S in the longitude zone 0 to 30 deg W where planetary wave activity is weak. Outside this longitude region, the trend in total ozone is much smaller due to strong interannual variability of wave activity. This paper gives a phenomenological description of ozone depletion in the Antarctic region based on vertical advection and transient planetary waves.

Column NO2-total ozone-stratospheric temperature relationships associated with the Arctic and Antarctic ozone holes

NASA Astrophysics Data System (ADS)

Aheyeva, Viktoryia; Gruzdev, Aleksandr; Grishaev, Mikhail

Data of ground-based measurements of NO2 column contents are analyzed to study winter-spring NO2 anomalies associated with negative anomalies in column ozone and stratospheric temperature. Episodes of significant decrease in column NO2 contents in the winter-spring period of 2011 in the northern hemisphere (NH) were detected at European and Siberian stations of Zvenigorod (55.7°N, Moscow Region) and Tomsk (56.5°N, West Siberia) in the middle latitudes, Harestua (60.2°N), Sodankyla (67.4°N, both in North Europe), and Zhigansk (66.8°N, East Siberia) in the high latitudes, and at the Arctic station of Scoresbysund (70.5°N, Greenland). All the stations, except Tomsk, are a part of the Network of the Detection of Atmospheric Composition Change (NDACC), and the data are accesses at http://ndacc.org. The decrease in NO2 is generally accompanied by total ozone and stratospheric temperature decrease and is shown to be caused by the transport of stratospheric air from the region of the ozone hole observed that season in the Arctic. Overpass total ozone data from Giovanni service and radiosonde data were used for the analysis. Although negative NO2 anomalies due to the transport from the Arctic were also observed in some other years, the anomalies in 2011 reached record magnitudes. A significant positive correlation has been found between variations in NO2 and ozone columns as well as NO2 column and stratospheric temperature during the winter-spring period of 2011, whereas the correlation is much weaker in years without Arctic ozone depletion. The correlation becomes even stronger if only episodes with significant NO2 decrease are considered. For example the correlation coefficients between NO2 and ozone columns deviations are about 0.9 for Zvenigorod and Scoresbysund. Correlation coefficients between variations in column NO2 and total ozone and stratospheric temperature as well as coefficients of regression of NO2 on ozone and temperature in the winter-spring period of 2011 for the Siberian stations are less than those for European stations. For comparison analysis, data of column NO2, total ozone and stratospheric temperature at the southern hemisphere (SH) stations of Dumont D’Urville (66.7°S, the Antarctic), Macquarie Island (54.5°S) and Kerguelen Island (49.3°S) (all stations are NDACC stations) were used. Correlation and regression coefficients between variations in column NO2 and total ozone as well as in column NO2 and stratospheric temperature for the winter-spring periods at the SH stations depend on the phase of the quasi-biennial oscillation (QBO) in the 30 hPa equatorial wind velocity. The correlation coefficients and the coefficients of regression of NO2 on ozone and temperature for the west QBO phase are large compared to those for the east phase. The 2011 Arctic ozone hole was observed during the west phase of the 30 hPa QBO. The calculated correlation coefficients at the NH stations for the winter-spring period of 2011 associated with the Arctic ozone hole are close to similar coefficients at the SH stations in winter-spring periods for the west QBO phase. The regression coefficients at the NH stations are less than those at the SH stations for the west QBO phase but greater than similar coefficients for the east phase. We can conclude that physico-chemical processes specific for ozone hole conditions cause spatial correlation between distribution of stratospheric NO2 and distributions of total ozone and temperature in polar and adjacent regions, which is generally stronger for stronger ozone deficit in a polar region. This results in significant time correlation between NO2, ozone and temperature at observation sites due to transport processes.

Assimilation of MLS and OMI Ozone Data

NASA Technical Reports Server (NTRS)

Stajner, I.; Wargan, K.; Chang, L.-P.; Hayashi, H.; Pawson, S.; Froidevaux, L.; Livesey, N.

2005-01-01

Ozone data from Aura Microwave Limb Sounder (MLS) and Ozone Monitoring Instrument (OMI) were assimilated into the ozone model at NASA's Global Modeling and Assimilation Office (GMAO). This assimilation produces ozone fields that are superior to those from the operational GMAO assimilation of Solar Backscatter Ultraviolet (SBUV/2) instrument data. Assimilation of Aura data improves the representation of the "ozone hole" and the agreement with independent Stratospheric Aerosol and Gas Experiment (SAGE) III and ozone sonde data. Ozone in the lower stratosphere is captured better: mean state, vertical gradients, spatial and temporal variability are all improved. Inclusion of OMI and MLS data together, or separately, in the assimilation system provides a way of checking how consistent OMI and MLS data are with each other, and with the ozone model. We found that differences between OMI total ozone column data and model forecasts decrease after MLS data are assimilated. This indicates that MLS stratospheric ozone profiles are consistent with OMI total ozone columns. The evaluation of error characteristics of OMI and MLS ozone will continue as data from newer versions of retrievals becomes available. We report on the initial step in obtaining global assimilated ozone fields that combine measurements from different Aura instruments, the ozone model at the GMAO, and their respective error characteristics. We plan to use assimilated ozone fields in estimation of tropospheric ozone. We also plan to investigate impacts of assimilated ozone fields on numerical weather prediction through their use in radiative models and in the assimilation of infrared nadir radiance data from NASA's Advanced Infrared Sounder (AIRS).

"Cloud Slicing" : A New Technique to Derive Tropospheric Ozone Profile Information from Satellite Measurements

NASA Technical Reports Server (NTRS)

Ziemke, J. R.; Chandra, S.; Bhartia, P. K.; Einaudi, Franco (Technical Monitor)

2000-01-01

A new technique denoted cloud slicing has been developed for estimating tropospheric ozone profile information. All previous methods using satellite data were only capable of estimating the total column of ozone in the troposphere. Cloud slicing takes advantage of the opaque property of water vapor clouds to ultraviolet wavelength radiation. Measurements of above-cloud column ozone from the Nimbus 7 total ozone mapping spectrometer (TOMS) instrument are combined together with Nimbus 7 temperature humidity and infrared radiometer (THIR) cloud-top pressure data to derive ozone column amounts in the upper troposphere. In this study tropical TOMS and THIR data for the period 1979-1984 are analyzed. By combining total tropospheric column ozone (denoted TCO) measurements from the convective cloud differential (CCD) method with 100-400 hPa upper tropospheric column ozone amounts from cloud slicing, it is possible to estimate 400-1000 hPa lower tropospheric column ozone and evaluate its spatial and temporal variability. Results for both the upper and lower tropical troposphere show a year-round zonal wavenumber 1 pattern in column ozone with largest amounts in the Atlantic region (up to approx. 15 DU in the 100-400 hPa pressure band and approx. 25-30 DU in the 400-1000 hPa pressure band). Upper tropospheric ozone derived from cloud slicing shows maximum column amounts in the Atlantic region in the June-August and September-November seasons which is similar to the seasonal variability of CCD derived TCO in the region. For the lower troposphere, largest column amounts occur in the September-November season over Brazil in South America and also southern Africa. Localized increases in the tropics in lower tropospheric ozone are found over the northern region of South America around August and off the west coast of equatorial Africa in the March-May season. Time series analysis for several regions in South America and Africa show an anomalous increase in ozone in the lower troposphere around the month of March which is not observed in the upper troposphere. The eastern Pacific indicates weak seasonal variability of upper, lower, and total tropospheric ozone compared to the western Pacific which shows largest TCO amounts in both hemispheres around spring months. Ozone variability in the western Pacific is expected to have greater variability caused by strong convection, pollution and biomass burning, land/sea contrast and monsoon developments.

Multimodel Assessment of the Factors Driving Stratospheric Ozone Evolution over the 21st Century

NASA Technical Reports Server (NTRS)

Oman, L. D.; Plummer, D. A.; Waugh, D. W.; Austin, J.; Scinocca, J. F.; Douglass, A. R.; Salawitch, R. J.; Canty, T.; Akiyoshi, H.; Bekki, S.;

Effect of ozone oxidative preconditioning in preventing early radiation-induced lung injury in rats

PubMed Central

Bakkal, B.H.; Gultekin, F.A.; Guven, B.; Turkcu, U.O.; Bektas, S.; Can, M.

2013-01-01

Ionizing radiation causes its biological effects mainly through oxidative damage induced by reactive oxygen species. Previous studies showed that ozone oxidative preconditioning attenuated pathophysiological events mediated by reactive oxygen species. As inhalation of ozone induces lung injury, the aim of this study was to examine whether ozone oxidative preconditioning potentiates or attenuates the effects of irradiation on the lung. Rats were subjected to total body irradiation, with or without treatment with ozone oxidative preconditioning (0.72 mg/kg). Serum proinflammatory cytokine levels, oxidative damage markers, and histopathological analysis were compared at 6 and 72 h after total body irradiation. Irradiation significantly increased lung malondialdehyde levels as an end-product of lipoperoxidation. Irradiation also significantly decreased lung superoxide dismutase activity, which is an indicator of the generation of oxidative stress and an early protective response to oxidative damage. Ozone oxidative preconditioning plus irradiation significantly decreased malondialdehyde levels and increased the activity of superoxide dismutase, which might indicate protection of the lung from radiation-induced lung injury. Serum tumor necrosis factor alpha and interleukin-1 beta levels, which increased significantly following total body irradiation, were decreased with ozone oxidative preconditioning. Moreover, ozone oxidative preconditioning was able to ameliorate radiation-induced lung injury assessed by histopathological evaluation. In conclusion, ozone oxidative preconditioning, repeated low-dose intraperitoneal administration of ozone, did not exacerbate radiation-induced lung injury, and, on the contrary, it provided protection against radiation-induced lung damage. PMID:23969972

Stratospheric ozone variations in the equatorial region as seen in Stratiospheric Aerosol and Gas Experiment data

NASA Technical Reports Server (NTRS)

Shiotani, Masato; Hasebe, Fumio

1994-01-01

An analysis is made of equatorial ozone variations for 5 years, 1984-1989, using the ozone profile data derived from the Stratospheric Aerosol and Gas Experiment II (SAGE II) instrument. Attention is focused on the annual cycle and also on interannual variability, particularly the quasi-biennial oscillation (QBO) and El Nino-Southern Oscillation (ENSO) variations in the lower stratosphere, where the largest contribution to total column ozone takes place. The annual variation in zonal mean total ozone around the equator is composed of symmetric and asymmetric modes with respect to the equator, with maximum contributions being around 19 km for the symmetric mode and around 25 km for the asymmetric mode. The persistent zonal wavenumber 1 structure observed by the total ozone mapping spectrometer over the equator is almost missing in the SAGE-derived column amounts integrated in the stratosphere, suggesting a significant contribution from tropospheric ozone. Interannual variations in the equatorial ozone are dominated by the QBO above 20 km and the ENSO-related variation below 20 km. The ozone QBO is characterized by zonally uniform phase changes in association with the zonal wind QBO in the equatorial lower stratosphere. The ENSO-related ozone variation consists of both the east-west vacillation and the zonally uniform phase variation. During the El Nino event, the east-west contrast with positive (negative) deviations in the eastern (western) hemisphere is conspicuous, while the decreasing tendency of the zonal mean values is maximum at the same time.

Retrieval of Surface Ozone from UV-MFRSR Irradiances using Deep Learning

NASA Astrophysics Data System (ADS)

Chen, M.; Sun, Z.; Davis, J.; Zempila, M.; Liu, C.; Gao, W.

2017-12-01

High concentration of surface ozone is harmful to humans and plants. USDA UV-B Monitoring and Research Program (UVMRP) uses Ultraviolet (UV) version of Multi-Filter Rotating Shadowband Radiometer (UV-MFRSR) to measure direct, diffuse, and total irradiances every three minutes at seven UV channels (i.e. 300, 305, 311, 317, 325, 332, and 368 nm channels with 2 nm full width at half maximum). Based on the wavelength dependency of aerosol optical depths, there have been plenty of literatures exploring retrieval methods of total column ozone from UV-MFRSR measurements. However, few has explored the retrieval of surface ozone. The total column ozone is the integral of the multiplication of ozone concentration (varying by height and time) and cross section (varying by wavelength and temperature) over height. Because of the distinctive values of ozone cross section in the UV region, the irradiances at seven UV channels have the potential to resolve the ozone concentration at multiple vertical layers. If the UV irradiances at multiple time points are considered together, the uncertainty or the vertical resolution of ozone concentrations can be further improved. In this study, the surface ozone amounts at the UVMRP station located at Billings, Oklahoma are estimated from the adjacent (i.e. within 200 miles) US Environmental Protection Agency (EPA) surface ozone observations using the spatial analysis technique. Then, the (direct normal) irradiances of UVMRP at one or more time points as inputs and the corresponding estimated surface ozone from EPA as outputs are fed into a pre-trained (dense) deep neural network (DNN) to explore the hidden non-linear relationship between them. This process could improve our understanding of their physical/mathematical relationship. Finally, the optimized DNN is tested with the preserved 5% of the dataset, which are not used during training, to verify the relationship.

Rossby-gravity waves in tropical total ozone data

NASA Technical Reports Server (NTRS)

Stanford, J. L.; Ziemke, J. R.

1993-01-01

Evidence for Rossby-gravity waves in tropical data fields produced by the European Center for Medium Range Weather Forecasts (ECMWF) was recently reported. Similar features are observable in fields of total column ozone from the Total Ozone Mapping Spectrometer (TOMS) satellite instrument. The observed features are episodic, have zonal (east-west) wavelengths of 6,000-10,000 km, and oscillate with periods of 5-10 days. In accord with simple linear theory, the modes exhibit westward phase progression and eastward group velocity. The significance of finding Rossby-gravity waves in total ozone fields is that (1) the report of similar features in ECMWF tropical fields is corroborated with an independent data set and (2) the TOMS data set is demonstrated to possess surprising versatility and sensitivity to relatively smaller scale tropical phenomena.

Solar UV-B irradiance and total ozone in Italy: Fluctuations and trends

NASA Astrophysics Data System (ADS)

Casale, G. R.; Meloni, D.; Miano, S.; Palmieri, S.; Siani, A. M.; Cappellani, F.

2000-02-01

Solar UV irradiance spectra (290-325 nm) together with daily total ozone column observations have been collected since 1992 by means of Brewer spectrophotometers at two Italian stations (Rome and Ispra). The available Brewer irradiance data, recorded around noon and at fixed solar zenith angles, together with the output of a radiative transfer model (the STAR model) are presented and analyzed. The Brewer irradiance measurements and total ozone fluctuations and anomalies are investigated, pointing out the correlation between the high-frequency O3 components and irradiance at 305 nm. In addition, the total ozone long time series of Arosa (170 km apart from Ispra) and Vigna di Valle (very close to Rome) are analyzed to illustrate evidence of temporal variations and a possible trend.

Assimilation of Satellite Ozone Observations

NASA Technical Reports Server (NTRS)

Stajner, I.; Winslow, N.; Wargan, K.; Hayashi, H.; Pawson, S.; Rood, R.

2003-01-01

This talk will discuss assimilation of ozone data from satellite-borne instruments. Satellite observations of ozone total columns and profiles have been measured by a series of Total Ozone Mapping Spectrometer (TOMS), Solar Backscatter Ultraviolet (SBUV) instruments, and more recently by the Global Ozone Monitoring Experiment. Additional profile data are provided by instruments on NASA's Upper Atmosphere Research Satellite and by occultation instruments on other platforms. Instruments on Envisat' and future EOS Aura satellite will supply even more comprehensive data about the ozone distribution. Satellite data contain a wealth of information, but they do not provide synoptic global maps of ozone fields. These maps can be obtained through assimilation of satellite data into global chemistry and transport models. In the ozone system at NASA's Data Assimilation Office (DAO) any combination of TOMS, SBUV, and Microwave Limb sounder (MLS) data can be assimilated. We found that the addition of MLS to SBUV and TOMS data in the system helps to constrain the ozone distribution, especially in the polar night region and in the tropics. The assimilated ozone distribution in the troposphere and lower stratosphere is sensitive also to finer changes in the SBUV and TOMS data selection and to changes in error covariance models. All results are established by comparisons of assimilated ozone with independent profiles from ozone sondes and occultation instruments.

Effects of 1997-1998 El Nino on Tropospheric Ozone and Water Vapor

NASA Technical Reports Server (NTRS)

Chandra, S.; Ziemke, J. R.; Min, W.; Read, W. G.

1998-01-01

This paper analyzes the impact of the 1997-1998 El Nino on tropospheric column ozone and tropospheric water vapor derived respectively from the Total Ozone Mapping Spectrometer (TOMS) on Earth Probe and the Microwave Limb Scanning instrument on the Upper Atmosphere Research Satellite. The 1997-1998 El Nino, characterized by an anomalous increase in sea-surface temperature (SST) across the eastern and central tropical Pacific Ocean, is one of the strongest El Nino Southern Oscillation (ENSO) events of the century, comparable in magnitude to the 1982-1983 episode. The major impact of the SST change has been the shift in the convection pattern from the western to the eastern Pacific affecting the response of rain-producing cumulonimbus. As a result, there has been a significant increase in rainfall over the eastern Pacific and a decrease over the western Pacific and Indonesia. The dryness in the Indonesian region has contributed to large-scale burning by uncontrolled wildfires in the tropical rainforests of Sumatra and Borneo. Our study shows that tropospheric column ozone decreased by 4-8 Dobson units (DU) in the eastern Pacific and increased by about 10-20 DU in the western Pacific largely as a result of the eastward shift of the tropical convective activity as inferred from National Oceanic and Atmospheric Administration (NOAA) outgoing longwave radiation (OLR) data. The effect of this shift is also evident in the upper tropospheric water vapor mixing ratio which varies inversely as ozone (O3). These conclusions are qualitatively consistent with the changes in atmospheric circulation derived from zonal and vertical wind data obtained from the Goddard Earth Observing System data assimilation analyses. The changes in tropospheric column O3 during the course of the 1997-1998 El Nino appear to be caused by a combination of large-scale circulation processes associated with the shift in the tropical convection pattern and surface/boundary layer processes associated with forest fires in the Indonesian region.

Ozone Pollution, Transport and Variability: Examples from Satellite and In-Situ Observations

NASA Technical Reports Server (NTRS)

Thompson, Anne

2003-01-01

Regional and intercontinental transport of ozone has been observed from satellite, aircraft and sounding data. Over the past several years, we have developed new tropospheric ozone retrieval techniques from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument that are of sufficient resolution to follow pollution episodes. The modified-residual technique uses Level 2 total ozone and was used to follow the 1997 fires in the wake of the El-Nino-related fires in southeast Asia and the Indonesian maritime continent. The TOMS-direct method ('TDOT' = TOMS Direct Ozone in the Troposphere) is a newer algorithm that uses TOMS radiances directly to extract tropospheric ozone. Ozonesonde data that have been taken in campaigns (e.g. TRACE-P) and more consistently in the SHADOZ (Southern Hemisphere Additional Ozonesondes) project, reveal layers of pollution traceable with trajectories. Examples will be shown of long-range transport and recirculation over Africa during SAFARI-2000.

Ozone pretreatment of olive mill wastewaters (OMW) and its effect on OMW biochemical methane potential (BMP).

PubMed

Tsintavi, E; Pontillo, N; Dareioti, M A; Kornaros, M

2013-01-01

The possibility of coupling a physicochemical pretreatment (ozonation) with a biological treatment (anaerobic digestion) was investigated for the case of olive mill wastewaters (OMW). Batch ozonation experiments were performed in a glass bubble reactor. The parameters which were tested included the ozone concentration in the inlet gas stream, the reactor temperature and the composition of the liquid medium in terms of raw or fractionated OMW used. In the sequel, ozone-pretreated OMW samples were tested for their biochemical methane potential (BMP) under mesophilic conditions and these results were compared to the BMP of untreated OMW. The ozonation process alone resulted in a 57-76% decrease of total phenols and a 5-18% decrease of total carbohydrates contained in OMW, depending on the experimental conditions. Nevertheless, the ozone-pretreated OMW exhibited lower chemical oxygen demand removal and methane production during BMP testing compared to the untreated OMW.

The total ozone and UV solar radiation over Stara Zagora, Bulgaria

NASA Astrophysics Data System (ADS)

Mendeva, B. D.; Gogosheva, Ts. N.; Petkov, B. H.; Krastev, D. G.

The results from direct ground-based solar UV irradiance measurements and the total ozone content (TOC) over Stara Zagora (42° 25'N, 25° 37'E), Bulgaria are presented. During the period 1999-2003 the TOC data show seasonal variations, typical for the middle latitudes - maximum in the spring and minimum in the autumn. The comparison between TOC ground-based data and Global Ozone Monitoring Experiment (GOME) satellite-borne ones shows a seasonal dependence of the differences between them. A strong negative relationship between the total ozone and the 305 nm wavelength irradiance was found. The dependence between the two variables is significant ( r = -0.62 ± 0.18) at 98% confidence level. The direct sun UV doses for some specific biological effects (erythema and eyes) are obtained. The estimation of the radiation amplification factor RAF shows that the ozone reduction by 1% increases the erythemal dose by 2.3%. The eye-damaging doses are more influenced by the TOC changes and in this case RAF = -2.7%. The amount of these biological doses depended on the solar altitude over the horizon. This dependence was not so strong when the total ozone content in the atmosphere was lower.

Multipurpose Spectroradiometer for Satellite Instrument Calibration and Zenith Sky Remote Sensing Measurements

NASA Technical Reports Server (NTRS)

Heath, Donald F.; Ahmad, Zia

2001-01-01

In the early 1990s a series of surface-based direct sun and zenith sky measurements of total column ozone were made with SBUV/2 flight models and the SSBUV Space Shuttle instrument in Boulder, Colorado which were compared with NOAA Dobson Instrument direct sun observations and TOMS instrument overpass observations of column ozone. These early measurements led to the investigation of the accuracy of derived total column ozone amounts and aerosol optical depths from zenith sky observations. Following the development and availability of radiometrically stable IAD narrow band interference filter and nitrided silicon photodiodes a simple compact multifilter spectroradiometer was developed which can be used as a calibration transfer standard spectroradiometer (CTSS) or as a surface based instrument remote sensing instruments for measurements of total column ozone and aerosol optical depths. The total column ozone derived from zenith sky observations agrees with Dobson direct sun AD double wavelength pair measurements and with TOMS overpass ozone amounts within uncertainties of about 1%. When used as a calibration transfer standard spectroradiometer the multifilter spectroradiometer appears to be capable of establishing instrument radiometric calibration uncertainties of the order of 1% or less relative to national standards laboratory radiometric standards.

Periodic analysis of total ozone and its vertical distribution

NASA Technical Reports Server (NTRS)

Wilcox, R. W.; Nastrom, G. D.; Belmont, A. D.

1975-01-01

Both total ozone and vertical distribution ozone data from the period 1957 to 1972 are analyzed. For total ozone, improved monthly zonal means for both hemispheres are computed by weighting individual station monthly means by a factor which compensates for the close grouping of stations in certain regions of latitude bands. Longitudinal variability show maxima in summer in both hemispheres, but, in winter, only in the Northern Hemisphere. The geographical distributions of the long term mean, and the annual, quasibiennial and semiannual waves in total ozone over the Northern Hemisphere are presented. The extratropical amplitude of the annual wave is by far the largest of the three, as much as 120 m atm cm over northern Siberia. There is a tendency for all three waves to have maxima in high latitudes. Monthly means of the vertical distribution of ozone determined from 3 to 8 years of ozonesonde data over North America are presented. Number density is highest in the Arctic near 18 km. The region of maximum number density slopes upward toward 10 N, where the long term mean is 45 x 10 to the 11th power molecules cm/3 near 26 km.

Ozone Layer Observations

NASA Technical Reports Server (NTRS)

McPeters, Richard; Bhartia, P. K. (Technical Monitor)

2002-01-01

The US National Aeronautics and Space Administration (NASA) has been monitoring the ozone layer from space using optical remote sensing techniques since 1970. With concern over catalytic destruction of ozone (mid-1970s) and the development of the Antarctic ozone hole (mid-1980s), long term ozone monitoring has become the primary focus of NASA's series of ozone measuring instruments. A series of TOMS (Total Ozone Mapping Spectrometer) and SBUV (Solar Backscatter Ultraviolet) instruments has produced a nearly continuous record of global ozone from 1979 to the present. These instruments infer ozone by measuring sunlight backscattered from the atmosphere in the ultraviolet through differential absorption. These measurements have documented a 15 Dobson Unit drop in global average ozone since 1980, and the declines in ozone in the antarctic each October have been far more dramatic. Instruments that measure the ozone vertical distribution, the SBUV and SAGE (Stratospheric Aerosol and Gas Experiment) instruments for example, show that the largest changes are occurring in the lower stratosphere and upper troposphere. The goal of ozone measurement in the next decades will be to document the predicted recovery of the ozone layer as CFC (chlorofluorocarbon) levels decline. This will require a continuation of global measurements of total column ozone on a global basis, but using data from successor instruments to TOMS. Hyperspectral instruments capable of measuring in the UV will be needed for this purpose. Establishing the relative roles of chemistry and dynamics will require instruments to measure ozone in the troposphere and in the stratosphere with good vertical resolution. Instruments that can measure other chemicals important to ozone formation and destruction will also be needed.

Extreme events in total ozone over Arosa - Part 2: Fingerprints of atmospheric dynamics and chemistry and effects on mean values and long-term changes

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Peter, T.; Ribatet, M.; Davison, A. C.; Stübi, R.; Weihs, P.; Holawe, F.

2010-10-01

In this study the frequency of days with extreme low (termed ELOs) and extreme high (termed EHOs) total ozone values and their influence on mean values and trends are analyzed for the world's longest total ozone record (Arosa, Switzerland). The results show (i) an increase in ELOs and (ii) a decrease in EHOs during the last decades and (iii) that the overall trend during the 1970s and 1980s in total ozone is strongly dominated by changes in these extreme events. After removing the extremes, the time series shows a strongly reduced trend (reduction by a factor of 2.5 for trend in annual mean). Excursions in the frequency of extreme events reveal "fingerprints" of dynamical factors such as ENSO or NAO, and chemical factors, such as cold Arctic vortex ozone losses, as well as major volcanic eruptions of the 20th century (Gunung Agung, El Chichón, Mt. Pinatubo). Furthermore, atmospheric loading of ozone depleting substances leads to a continuous modification of column ozone in the Northern Hemisphere also with respect to extreme values (partly again in connection with polar vortex contributions). Application of extreme value theory allows the identification of many more such "fingerprints" than conventional time series analysis of annual and seasonal mean values. The analysis shows in particular the strong influence of dynamics, revealing that even moderate ENSO and NAO events have a discernible effect on total ozone. Overall the approach to extremal modelling provides new information on time series properties, variability, trends and the influence of dynamics and chemistry, complementing earlier analyses focusing only on monthly (or annual) mean values.

Extreme events in total ozone over Arosa - Part 2: Fingerprints of atmospheric dynamics and chemistry and effects on mean values and long-term changes

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Peter, T.; Ribatet, M.; Davison, A. C.; Stübi, R.; Weihs, P.; Holawe, F.

2010-05-01

In this study the frequency of days with extreme low (termed ELOs) and extreme high (termed EHOs) total ozone values and their influence on mean values and trends are analyzed for the world's longest total ozone record (Arosa, Switzerland). The results show (a) an increase in ELOs and (b) a decrease in EHOs during the last decades and (c) that the overall trend during the 1970s and 1980s in total ozone is strongly dominated by changes in these extreme events. After removing the extremes, the time series shows a strongly reduced trend (reduction by a factor of 2.5 for trend in annual mean). Excursions in the frequency of extreme events reveal "fingerprints" of dynamical factors such as ENSO or NAO, and chemical factors, such as cold Arctic vortex ozone losses, as well as major volcanic eruptions of the 20th century (Gunung Agung, El Chichón, Mt. Pinatubo). Furthermore, atmospheric loading of ozone depleting substances leads to a continuous modification of column ozone in the Northern Hemisphere also with respect to extreme values (partly again in connection with polar vortex contributions). Application of extreme value theory allows the identification of many more such "fingerprints" than conventional time series analysis of annual and seasonal mean values. The analysis shows in particular the strong influence of dynamics, revealing that even moderate ENSO and NAO events have a discernible effect on total ozone. Overall the approach to extremal modelling provides new information on time series properties, variability, trends and the influence of dynamics and chemistry, complementing earlier analyses focusing only on monthly (or annual) mean values.

A Madden-Julian Oscillation in Tropospheric Ozone

NASA Technical Reports Server (NTRS)

Ziemke, J. R.; Chandra, S.

2004-01-01

This is the first study to indicate a Madden-Julian Oscillation (MJO) in tropospheric ozone. Tropospheric ozone is derived using differential measurements of total column ozone and stratospheric column ozone measured from total ozone mapping spectrometer (TOMS) and microwave limb sounder (MLS) instruments. Two broad regions of significant MJO signal are identified in the tropics, one in the western Pacific and the other in the eastern Pacific. Over both regions, MJO variations in tropospheric ozone represent 5- 10 DU peak-to-peak anomalies. These variations are significant compared to mean background amounts of 20 DU or less over most of the tropical Pacific. The implications of these results are: (1) model values of TCO in the tropical Pacific region, when accounted for the MJO may be highly variable depending upon the phase of the MJO, and (2) MJO signals of this magnitude would need to be considered when investigating and interpreting particular pollution events since ozone is a precursor of the hydroxyl (OH) radical, the main oxidizing agent of pollutants in the lower atmosphere.

Perspectives on African Ozone from Sondes, Dobson and Aircraft Measurements

NASA Technical Reports Server (NTRS)

Thompson, A. M.; Witte, J. C.; Chatfield, R. B.; Diab, R. D.; Thouret, V.; Sauvage, B.

2004-01-01

We have been studying variability in ozone over Africa using data from ozonesondes (vertical profiles from surface to stratosphere), aircraft (the MOZAIC dataset with cruise altitude and landing/takeoff profiles) and the ground (Dobson spectrophotometer total ozone column measurement). The following may give context for ozone investigations during AMMA: 1. Total ozone measurements since 1989 show considerable variability in mean value among the African stations in Algeria, Kenya, Egypt, South Africa, as well as in seasonal cycles and year-to-year. Trends are not evident. 2. The impacts of convection, stratospheric injection, biomass burning and lightning appear in ozone sounding profile data. Time-series analysis and case studies point to periodic influences of long-range interactions with the Atlantic ("ozone paradox," wave-one") and Indian Oceans. 3. Tropospheric ozone variations, observed in tropospheric profiles and integrated column amount, follow general seasonal patterns but short- term variability is so strong that simple averages are inadequate for describing "climatology" and statistical classification approaches may be required.

A preliminary comparison between TOVS and GOME level 2 ozone data

NASA Astrophysics Data System (ADS)

Rathman, William; Monks, Paul S.; Llewellyn-Jones, David; Burrows, John P.

1997-09-01

A preliminary comparison between total column ozone concentration values derived from TIROS Operational Vertical Sounder (TOVS) and Global Ozone Monitoring Experiment (GOME) has been carried out. Two comparisons of ozone datasets have been made: a) TOVS ozone analysis maps vs. GOME level 2 data; b) TOVS data located at Northern Hemisphere Ground Ozone Stations (NHGOS) vs. GOME data. Both analyses consistently showed an offset in the value of the total column ozone between the datasets [for analyses a) 35 Dobson Units (DU); and for analyses b) 10 DU], despite a good correlation between the spatial and temporal features of the datasets. A noticeably poor correlation in the latitudinal bands 10°/20° North and 10°/20° South was observed—the reasons for which are discussed. The smallest region which was statistically representative of the ozone value correlation dataset of TOVS data at NHGOS and GOME level-2 data was determined to be a region that was enclosed by effective radius of 0.75 arc-degrees (83.5km).

A two-dimensional photochemical model of the atmosphere. I Chlorocarbon emissions and their effect on stratospheric ozone

NASA Technical Reports Server (NTRS)

Gidel, L. T.; Crutzen, P. J.; Fishman, J.

1983-01-01

A two-dimensional photochemical model is used to examine changes to the ozone layer caused by emissions of CFCl3, CF2Cl2, CH3CCl3 and CCl4. The influence of a possible secular increase in tropospheric methane up to 2 percent per year was found to be small, although it acts to mask decreases in total ozone caused by the chlorocarbons. Increasing NO(x) emissions caused by industralization also tend to mask decreases in total ozone and may have caused total ozone to increase by about 1 percent. The model-calculated ozone decreases are estimated to be about 3 percent by 1980. This estimate is higher than estimates by similar models, although it is noted that CCl4 and CH3CCl3 emissions are included in the model in addition to CFCl3 and CF2Cl2. This is significant because the model indicates that CCl4 has dominated the ozone depletions so far, and knowledge of the historical emission rate of CCl4 to the atmosphere is incomplete. There remain sufficient significant disagreements between theoretical and observed concentrations and variabilities, particularly for odd nitrogen and ClO, to caution against assigning too much confidence in the calculated ozone depletion.

Links between extreme UV-radiation, total ozone, surface albedo and cloudiness: An analysis of 30 years of data from Switzerland and Austria

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Weihs, P.; Vuilleumier, L.; Blumthaler, M.; Holawe, F.; Lindfors, A.; Maeder, J. A.; Simic, S.; Wagner, J. E.; Walker, D.; Ribatet, M.

2009-04-01

Since the discovery of anthropogenic ozone depletion in the early 1970s (e.g. Molina and Rowland, 1974; Farman et al., 1985) the interest in stratospheric ozone trends and solar UV-B increased within the scientific community and the general public because of the link between reduced total column ozone and increased UV-radiation doses. Stratospheric ozone (e.g. Koch et al., 2005) and erythemal UV-radiation (e.g. Rieder et al., 2008) in the northern mid-latitudes are characterized by strong temporal variability. Long-term measurements of UV-B radiation are rare and datasets are only available for few locations and most of these measurements do not provide spectral information on the UV part of the spectra. During strong efforts in the reconstruction of erythemal UV, datasets of past UV-radiation doses became available for several measurement sites all over the globe. For Switzerland and Austria reconstructed UV datasets are available for 3 measurement sites (Davos, Sonnblick and Vienna) (Lindfors and Vuilleumier, 2005; Rieder et al., 2008). The world's longest ozone time series dating back to 1926 is available from Arosa, Switzerland, and is discussed in detail by Staehelin et al. (1998a,b). Recently new tools from extreme value theory have been applied to the Arosa time series to describe extreme events in low and high total ozone (Rieder et al., 2009). In our study we address the question of how much of the extremes in UV-radiation can be attributed to extremes in total ozone, high surface albedo and cloudiness. An analysis of the frequency distributions of such extreme events for the last decades is presented to gain a better understanding of the links between extreme erythemal UV-radiation, total ozone, surface albedo and clouds. References: Farman, J. C., Gardiner, B. G., and Shanklin, J. D.: Large losses of total ozone in Antarctica reveal seasonal ClOx/NOx interaction, Nature, 315, 207-210, 1985. Koch, G., Wernli, H., Schwierz, C., Staehelin, J., and Peter, T.: A composite study on the structure and formation of ozone miniholes and minihights over central Europe, J. Geophys. Res., 32, doi:10.1029/2004GL022062, 2005. Lindfors, A., and Vuilleumier, L.: Erythemal UV at Davos (Switzerland), 1926-2003, estimated using total ozone, sunshine duration, and snow depth, J. Geophys. Res., 110, D02104, doi:10.1029/2004JD005231, 2005. Molina, M. J., and Rowland, F. S.: Stratospheric sink for chlorofluoromethans: Chlorine atom-catalysed destruction of ozone, Nature, 249, 810-812, 1974. Rieder, H.E., Holawe, F., Simic, S., Blumthaler, M., Krzyscin, J.W., Wagner J.E., Schmalwieser A.W., and Weihs, P.: Reconstruction of erythemal UV-doses for two stations in Austria: A comparison between alpine and urban regions, Atmos. Chem. Phys., 8, 6309-6323, 2008. Rieder, H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and Davison, A.C.: From ozone mini holes and mini highs towards extreme value theory: New insights from extreme events and non stationarity, submitted to J. Geophys. Res., 2009. Staehelin, J., Kegel, R., and Harris, N. R.: Trend analysis of the homogenized total ozone series of Arosa (Switzerland), 1929-1996, J. Geophys. Res., 103(D7), 8389-8400, doi:10.1029/97JD03650, 1998a. Staehelin, J., Renaud, A., Bader, J., McPeters, R., Viatte, P., Hoegger, B., Bugnion, V., Giroud, M., and Schill, H.: Total ozone series at Arosa (Switzerland): Homogenization and data comparison, J. Geophys. Res., 103(D5), 5827-5842, doi:10.1029/97JD02402, 1998b.

Status of the Dobson total ozone data set

NASA Technical Reports Server (NTRS)

Planet, Walter G.; Hudson, Robert D.

1994-01-01

During deliberations of the International Ozone Trends Panel (IOTP) it became obvious that satellite determinations of global ozone amounts by themselves could not provide the necessary confidence in the measured trends. During the time of the deliberations of the IOTP, Bojkov re-examined the records of serveral North American Dobson stations and Degorska re-examined the records of the Belsk station. They were able to improve the quality of the data sets, thus improving the precision of their total ozone data sets. These improvements showed the greater potential of the world-wide Dobson total ozone data set in two primary areas. Firstly, the improvements showed that the existing data set when evaluated will become more valuable for comparisons with satellite determinations of total ozone. Secondly, the Dobson data set covers a greater period of time than the satellite data sets thus offering the possibility of extending improved information on ozone trends further back in time. An International Dobson Workshop was convened in September, 1991, under the auspices of the NOAA Climate and Global Change Program. It was part of the Information Management element of the C&GC Program. Further, it was considered as a 'data archaeology' project under the above. Clearly if the existing Dobson data set can be improved by re-evaluating all data records, we will be able to uncover the 'true' or 'best' data and fulfill the role of archaeologists.

Analysis of Ozone And CO2 Profiles Measured At A Diary Facility

NASA Astrophysics Data System (ADS)

Ogunjemiyo, S. O.; Hasson, A. S.; Ashkan, S.; Steele, J.; Shelton, T.

2015-12-01

Ozone and carbon dioxide are both greenhouse gasses in the planetary boundary layer. Ozone is a harmful secondary pollutant in the troposphere produced mostly during the day when there is a photochemical reaction in which primary pollutant precursors such as nitrous oxide (NOx) or volatile organic compounds (VOC's) mix with sunlight. As with most pollutants in the lower troposphere, both ozone and carbon dioxide vary in spatial and temporal scale depending on sources of pollution, environmental conditions and the boundary layer dynamics. Among the several factors that influence ozone variation, the seasonal changes in meteorological parameters and availability of ozone precursors are crucial because they control ozone formation and decay. Understanding how the difference in emission sources affect vertical transport of ozone and carbon dioxide is considered crucial to the improvement of their regional inventory sources. The purpose of this study is to characterize vertical transport of ozone and carbon at a diary facility. The study was conducted in the summer of 2011 and 2012 at a commercial dairy facility in Central California and involved profile measurements of ozone and CO2 using electrochemical ozonesondes, meteorological sondes and CO2 probe tethered to a 9 cubic meters helium balloon. On each day of the data collection, multiple balloon launches were made over a period representing different stages of the boundary layer development. The results show ozone and CO2 profiles display different characteristics. Regardless of the time of the day, the CO2 concentration decreases with height with a sharp gradient near the surface that is strengthened by a stable atmospheric condition, a feature suggesting the surface as the source. On the other hand, ozone profiles show greater link to the evolution of the lower boundary layer. Ozone profiles display unique features indicating ozone destruction near the surface. This unusual near the surface, observed even in the afternoon when the boundary layer is fully developed, greatly contrast ozone profiles are typical of urban environment

Ozone Climatological Profiles for Version 8 TOMS and SBUV Retrievals

NASA Technical Reports Server (NTRS)

McPeters, R. D.; Logan, J. A.; Labow, G. J.

2003-01-01

A new altitude dependent ozone climatology has been produced for use with the latest Total Ozone Mapping Spectrometer (TOMS) and Solar Backscatter Ultraviolet (SBUV) retrieval algorithms. The climatology consists of monthly average profiles for ten degree latitude zones covering from 0 to 60 km. The climatology was formed by combining data from SAGE II (1988 to 2000) and MLS (1991-1999) with data from balloon sondes (1988-2002). Ozone below about 20 km is based on balloons sondes, while ozone above 30 km is based on satellite measurements. The profiles join smoothly between 20 and 30 km. The ozone climatology in the southern hemisphere and tropics has been greatly enhanced in recent years by the addition of balloon sonde stations under the SHADOZ (Southern Hemisphere Additional Ozonesondes) program. A major source of error in the TOMS and SBUV retrieval of total column ozone comes from their reduced sensitivity to ozone in the lower troposphere. An accurate climatology for the retrieval a priori is important for reducing this error on the average. The new climatology follows the seasonal behavior of tropospheric ozone and reflects its hemispheric asymmetry. Comparisons of TOMS version 8 ozone with ground stations show an improvement due in part to the new climatology.

Estimating Uncertainty in Long Term Total Ozone Records from Multiple Sources

NASA Technical Reports Server (NTRS)

Frith, Stacey M.; Stolarski, Richard S.; Kramarova, Natalya; McPeters, Richard D.

2014-01-01

Total ozone measurements derived from the TOMS and SBUV backscattered solar UV instrument series cover the period from late 1978 to the present. As the SBUV series of instruments comes to an end, we look to the 10 years of data from the AURA Ozone Monitoring Instrument (OMI) and two years of data from the Ozone Mapping Profiler Suite (OMPS) on board the Suomi National Polar-orbiting Partnership satellite to continue the record. When combining these records to construct a single long-term data set for analysis we must estimate the uncertainty in the record resulting from potential biases and drifts in the individual measurement records. In this study we present a Monte Carlo analysis used to estimate uncertainties in the Merged Ozone Dataset (MOD), constructed from the Version 8.6 SBUV2 series of instruments. We extend this analysis to incorporate OMI and OMPS total ozone data into the record and investigate the impact of multiple overlapping measurements on the estimated error. We also present an updated column ozone trend analysis and compare the size of statistical error (error from variability not explained by our linear regression model) to that from instrument uncertainty.

Condition of The Stratospheric and Mesospheric Ozone Layer Over Bulgaria for the Period 1996-2012

NASA Astrophysics Data System (ADS)

Kaleyna, Petya; Mukhtarov, Plamen; Miloshev, Nikolay

2014-05-01

A detailed analysis of the variations of the stratospheric and mesospheric ozone over Bulgaria, in the period 1996-2012, is presented in the article on the basis of ground and satellite measurements of the Total Ozone Content (TOC). The move of the most important components: yearly running mean values, amplitudes and phases of the first four harmonics of the seasonal cycle. Their mean values for the period and the existing long term trends have been found. An evaluation of the general characteristics of the short term variability of the Total Ozone Content (TOC) over Bulgaria also has been made in the article. The impact of the planetary wave activity of the stratosphere on the total ozone has been studied and the climatology of the oscillation amplitudes with periods of 4, 7, 11 and 25 days has been defined.

Brewer spectrometer total ozone column measurements in Sodankylä

NASA Astrophysics Data System (ADS)

Karppinen, Tomi; Lakkala, Kaisa; Karhu, Juha M.; Heikkinen, Pauli; Kivi, Rigel; Kyrö, Esko

2016-06-01

Brewer total ozone column measurements started in Sodankylä in May 1988, 9 months after the signing of The Montreal Protocol. The Brewer instrument has been well maintained and frequently calibrated since then to produce a high-quality ozone time series now spanning more than 25 years. The data have now been uniformly reprocessed between 1988 and 2014. The quality of the data has been assured by automatic data rejection rules as well as by manual checking. Daily mean values calculated from the highest-quality direct sun measurements are available 77 % of time with up to 75 measurements per day on clear days. Zenith sky measurements fill another 14 % of the time series and winter months are sparsely covered by moon measurements. The time series provides information to survey the evolution of Arctic ozone layer and can be used as a reference point for assessing other total ozone column measurement practices.

Changes in respiration, photosynthesis, adenosine 5'-triphosphate, and total adenylate content of ozonated pinto bean foliage as they relate to symptom expression.

PubMed

Pell, E J; Brennan, E

1973-02-01

The effect of 0.25 to 0.30 microliter per liter ozone on photosynthesis and respiration and on the ATP and total adenylate content of the primary leaves of pinto beans (Phaseolus vulgaris L.) was examined. Changes in these parameters over a 72-hour time period were correlated with the development of symptoms of ozone toxicity. Toxicity symptoms normally appeared within 24 hours. The content of ATP and total adenylates increased immediately following a 3-hour exposure to ozone. Photosynthesis was depressed initially, but returned to normal within 24 hours. Respiration was not always altered initially, but it was significantly stimulated within 24 hours. We interpret the results to mean that the changes in adenylate content and photosynthesis are early events in the initiation of ozone damage and that the change in respiration is a consequence rather than a cause of cellular injury.

Carrot injury and yield response to ozone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bennett, J.P.; Oshima, R.J.

1976-11-01

Container-grown plants of carrot (Daucus carota L.) exposed intermittently to 0.19 or 0.25 ppm ozone throughout their growth increased in plant height and total number of leaves in spite of the development of chlorotic leaves. Leaf dry weight was unaffected by ozone, but root dry matter decreased 32 to 46%. As a result, the root weight/total dry weight ration and root/shoot ratio declined significantly in the presence of ozone. A regression of root dry weight on chlorotic lead dry weight explained 35% of the root loss and predicted that 1.5 g of root tissue is lost for every g ofmore » chlorotic leaf dry weight casued by ozone injury.« less

Airborne Measurements of Nitric Oxide, Nitrogen Dioxide, Ozone, and Total Reactive Nitrogen During the NASA Global Tropospheric Experiment

NASA Technical Reports Server (NTRS)

Carroll, Mary Anne

2000-01-01

Fabrication of the University of Michigan Multichannel Chemiluminescence Instrument (UMMCI) was completed in early 1996 and the instrument participated in test flights on the NASA P3B at Wallops Island prior to integration and deployment for the PEM- Tropics A Mission. The UMMCI consists of 4 channels for simultaneous measurements of ozone and NO with the option for measurements of NO2 and NOy (total reactive nitrogen) when converters are placed upstream of the NO channels. Each NO channel consists of a zeroing volume and reaction vessel, while the ozone channel consists of an ozone catalyst (or scrubber) trap that is not in line with the reaction vessel. The detectors in all for channels are Hamamatsu photomultiplier tubes, which are followed by pulse amplifier discriminators on the NO channels and an electrometer on the ozone channel. Schematics of the Detector Module and NOx/03 Probe Insert and Diagrams of the Control and Data System, the Power and Ground System, the Gas Flow System, and the Calibration System Flow are attached. Intercomparisons were conducted with G. Gregory, NASA/Langley, during the test flights (following prior calibration of the ozone generator/calibrators at the Wallops Long-Path Absorption facility). Initial test results appeared to be reasonable, and instrument characterization studies proceeded for the ozone channel and the 3 NO channels until deployment for integration for the PEM-Tropics Mission. Ozone data was obtained for Flights #4, and 6-2 1, and finalized data was submitted to the PEM-Tropics Data Archive and to the Science Team during the April 1997 Data Workshop. Although it initially appeared that the instrument sensitivity varied, subsequent tests showed that this was the fault of a leak in the ozone calibrator. In fact; the instrument sensitivity has not been observed to vary in a large number of tests over the years since the PEM-Tropics mission. We have, therefore, a very high degree of confidence in the O3 data that we submitted. NO data was obtained for all flights except the mission out of Christmas Island and the subsequent return to Hawaii, during which time the NO channels were contaminated with back-flushing pure NO from the O3 channel. The NO channels were found to suffer from a varying artifact (7 - 22 pptv) which made the instrument's results unreliable for the marine boundary layer portions of the missions (where conditions were extremely clean with NO typically < 2 pptv and O3 only 8 ppbv). Nonetheless, the NO values were an upper limit and were quite useful in identifying pollution layers and outflow from the Latin American Continent. NO data was submitted to the archive for all flights during which data was obtained. Ozone data from the P3B was among the results presented in several peer-reviewed publications. Notably, the ozone data supported the first published finding of evidence for the occurrence of aerosol nucleation in the marine boundary layer. As well, the ozone data was utilized in a treatment of the wavenumber spectra of winds, temperature and trace gases and to demonstrate the occurrence of layering as observed by the P3B during PEM-Tropics A . O3 and NO data were used in an assessment of the impact of southern hemispheric biomass burning, and in the role of NOx and O3 in HOx photochemistry during the PEM Tropics A mission. These data, along with other species measured during PEM-Tropics A, have also been employed in the generation of climatologies for tropospheric ozone and its precursors by the PI's research group.

Depletions in winter total ozone values over southern England

NASA Technical Reports Server (NTRS)

Lapworth, A.

1994-01-01

A study has been made of the recently re-evaluated time series of daily total ozone values for the period 1979 to 1992 for southern England. The series consists of measurements made at two stations, Bracknell and Camborne. The series shows a steady decline in ozone values in the spring months over the period, and this is consistent with data from an earlier decade that has been published but not re-evaluated. Of exceptional note is the monthly mean for January 1992 which was very significantly reduced from the normal value, and was the lowest so far measured for this month. This winter was also noteworthy for a prolonged period during which a blocking anticyclone dominated the region, and the possibility existed that this was related to the ozone anomaly. It was possible to determine whether the origin of the low ozone value lay in ascending stratospheric motions. A linear regression analysis of ozone value deviation against 100hPa temperature deviations was used to reduce ozone values to those expected in the absence of high pressure. The assumption was made that the normal regression relation was not affected by atmospheric anomalies during the winter. This showed that vertical motions in the stratosphere only accounted for part of the ozone anomaly and that the main cause of the ozone deficit lay either in a reduced stratospheric circulation to which the anticyclone may be related or in chemical effects in the reduced stratospheric temperatures above the high pressure area. A study of the ozone time series adjusted to remove variations correlated with meteorological quantities, showed that during the period since 1979, one other winter, that of 1982/3, showed a similar although less well defined deficit in total ozone values.

Total ozone changes in the 1987 Antarctic ozone hole

NASA Technical Reports Server (NTRS)

Krueger, Arlin J.; Schoeberl, Mark R.; Doiron, Scott D.; Sechrist, Frank; Galimore, Reginald

1988-01-01

The development of the Antarctic ozone minimum was observed in 1987 with the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) instrument. In the first half of August the near-polar (60 and 70 deg S) ozone levels were similar to those of recent years. By September, however, the ozone at 70 and 80 deg S was clearly lower than any previous year including 1985, the prior record low year. The levels continued to decrease throughout September until October 5 when a new record low of 109 DU was established at a point near the South Pole. This value is 29 DU less than the lowest observed in 1985 and 48 DU less than the 1986 low. The zonal mean total ozone at 60 deg S remained constant throughout the time of ozone hole formation. The ozone decline was punctuated by local minima formed away from the polar night boundary at about 75 deg S. The first of these, on August 15 to 17, formed just east of the Palmer Peninsula and appears to be a mountain wave. The second major minimum formed on September 5 to 7 again downwind of the Palmer Peninsula. This event was larger in scale than the August minimum and initiated the decline of ozone across the polar region. The 1987 ozone hole was nearly circular and pole centered for its entire life. In previous years the hole was perturbed by intrusions of the circumpolar maximum into the polar regions, thus causing the hole to be elliptical. The 1987 hole also remained in place until the end of November, a few days longer than in 1985, and this persistence resulted in the latest time for recovery to normal values yet observed.

Total Ozone Observations at Arosa (Switzerland) by Dobson and Brewer: Temperature and Ozone Slant Path Effect

NASA Astrophysics Data System (ADS)

Scarnato, B.; Staehelin, J.; Groebner, J.

2008-12-01

Dobson and Brewer spectrophotometers are the main ground based instruments used to monitor the ozone layer. Early total ozone (TOZ) measurements were made primarily with Dobson instruments; however, there has been a trend over the last years to replace them by the newer, more advanced Brewer spectrophotometer. Given this transition, it is of utmost importance to assure the homogeneity of the data taken with these two distinct instruments types if total ozone (TOZ) changes over long time periods are to be diagnosed accurately. Previous studies have identified a seasonal bias of few percentage from Brewer and Dobson spectrophotometers measurements at mid-latitudes. At Arosa (Switzerland), two Dobson and three Brewers instruments have been co-located since 1998, producing a unique dataset of quasi-simultaneous observations valuable for the study of systematic differences between these measurements. The differences can be at least partially attributed to seasonal variability in the atmospheric temperature and the ozone slant path. The effective temperature sensitivity of the ozone cross section has been calculated using different reference spectra, at high and low resolution, weighting of the slit functions for each operational Brewer and for the primary standard Dobson spectrophotometers. If one takes into account the temperature dependence of the [Bass, 1985] ozone absorption spectra (current remote sensing standard) and the ozone slant path effect, the seasonal bias between Dobson and Brewer TOZ measurements is reduced from an amplitude of about 2% to less than 0.5%. The use of different ozone laboratory spectra yields different results in retrieved TOZ, because of the sensitivity of the retrieval algorithms and uncertainties in the experimental ozone cross section measurements.

Temperature And Bandwidth Effect in Brewer and Dobson Direct Sun Observations

NASA Astrophysics Data System (ADS)

Scarnato, B.; Staehelin, J.; Stuebi, R.

2007-12-01

Dobson and Brewer spectrophotometer are the main instruments to monitor the ozone shield by ground based observations, and they have an important role for validation of ozone satellite data. Ground based total ozone observations from Brewer and Dobson spectrophotometers, operated at mid-latitudes stations, typically show a seasonal bias in the residual with a amplitude of a few percent. Mid-latitude total ozone trends caused by ozone depleting substances are on the order of few percents per decade. Therefore, only a maximum instrumental shift of 1% over the measured period can be tolerated for measurements to derive reliable trends. At Arosa two Dobson and three Brewers instruments have been co-located since 1992, producing a unique data set of quasi-simultaneous observations that is valuable for the study of systematic differences within the measurements. The differences can be at least partially attributed to the different sensitivities of the wavelengths used in the retrieval algorithms. This might explain different column ozone as a consequence of seasonal variability, mainly, in temperature in the lower stratosphere and in ozone slant path. The temperature dependence has been calculated using three different absorption spectra (Bass and Paur, Daumont and those used in the GOME satellite), weighing of the slit functions for each operational Brewer and for the primary standard Dobson spectrophotometers. The seasonal bias between Dobson and Brewer total ozone measurements is reduced from 3% to 1%, if one takes into account the temperature dependence of the Bass and Paur absorptions spectra and the ozone slant path effect. The accuracy and the resolution step of the experimental data of ozone cross sections have an important role. The ozone cross section must be convoluted for the slits functions that can vary from one instrument to an other, therefore the different spectra yield different results.

Reconstruction of erythemal UV irradiance at Hohenpeissenberg (1968-2001) considering trends of total ozone, cloudiness, and turbidity

NASA Astrophysics Data System (ADS)

Trepte, S.; Winkler, P.

2003-04-01

The global mean total column ozone amount for the period 1997-2001 was approximately 3% below the 1964-1980 average. The largest ozone decreases in the northern hemisphere midlatitudes are observed during winter-spring (˜4%), with summer-autumn decreases approximately half as large. Total ozone measured at Hohenpeissenberg, Germany (48^oN, 11^oE) shows a strong decrease by about 10% since 1968, representing the long-term downward trend over Central Europe. The main consequence of this phenomenon is the expected increase of solar ultraviolet irradiation (UV-B) reaching the Earth's surface with the known harmful effects on the biosphere. Global data records of reliable routine observations of UV irradiance are still too short for accurate estimation of long-term UV variations and trends. While direct UV mesaurements at Hohenpeissenberg are available only since 1990, the long-term development of UV-B have to be reconstructed. Besides on the amount of total ozone the UV irradiation at the ground depends also on atmospheric turbidity and cloudiness. The reconstruction method is based on statistical correlations of measured UV-B data with the influencing parameters total ozone, turbidity and cloud modification factors derived from eye-observations in connection with total solar irradiance data. These observed data allow a realistic reconstruction of the UV-B time series, since no assumption on these influencing data have to be made. A model is presented, using hourly observed spectral UV-B irradiance (1990-1998), total solar irradiance, total ozone amount (daily mean) and clouds to derive erythemal UV irradiance and daily doses at Hohenpeissenberg in the period 1968-2001. A comparison with recorded UV data shows good agreement. Due to long-term total ozone loss, peak values of erythemal UV irradiance in spring and summer at clear-sky conditions have strongly increased (+4.2%/decade in June). Mean daily doses have also increased in this season (+5.4%/decade in May) but meteorological changes like reduced sunshine duration and increased cloudiness lead to a partly compensation of the ozone-loss effect in spring and to an overcompensation in autumn, where we found a long-term decrease of the daily dose (-3.0%/decade in September). Model calculations also demonstrate large year-to-year fluctuations of UV doses induced by meteorological variability, which exceed the long-term trend of the various months significantly. Nevertheless, this investigation has shown that on a long-term time scale the daily doses develop in a different way as compared to the peak values because the reasons for ozone decline (anthropogenic CFC's) and the cloud cover (hydrological cycle changes due to greenhouse effect) are caused by different phenomena.

Stratospheric ozone variations in the equatorial region as seen in Stratiospheric Aerosol and Gas Experiment data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shiotani, M.; Hasebe, F.

1994-07-01

An analysis is made of equatorial ozone variations for 5 years, 1984-1989, using the ozone profile data derived from the Stratospheric Aerosol and Gas Experiment II (SAGE II) instrument. Attention is focused on the annual cycle and also on interannual variability, particularly the quasi-biennial oscillation (QBO) and El Nino-Southern Oscillation (ENSO) variations in the lower stratosphere, where the largest contribution to total column ozone takes place. The annual variation in zonal mean total ozone around the equator is composed of symmetric and asymmetric modes with respect to the equator, with maximum contributions being around 19 km for the symmetric modemore » and around 25 km for the asymmetric mode. The persistent zonal wavenumber 1 structure observed by the total ozone mapping spectrometer over the equator is almost missing in the SAGE-derived column amounts integrated in the stratosphere, suggesting a significant contribution from tropospheric ozone. Interannual variations in the equatorial ozone are dominated by the QBO above 20 km and the ENSO-related variation below 20 km. The ozone QBO is characterized by zonally uniform phase changes in association with the zonal wind QBO in the equatorial lower stratosphere. The ENSO-related ozone variation consists of both the east-west vacillation and the zonally uniform phase variation. During the El Nino event, the east-west contrast with positive (negative) deviations in the eastern (western) hemisphere is conspicuous, while the decreasing tendency of the zonal mean values is maximum at the same time.« less

Stratospheric ozone variations in the equatorial region as seen in Stratospheric and Gas Experiment data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Masato Shiotani; Fumio Hasebe

1994-07-20

An analysis is made of equatorial ozone variations for 5 years, 1984-1989, using the ozone profile data derived from the Stratospheric Aerosol and Gas Experiment II (SAGE II) instrument. Attention is focused on the annual cycle and also on interannual variability, particularly the quasi-biennial oscillation (QBO) and El Nino-Southern Oscillation (ENSO) variations in the lower stratosphere, where the largest contribution to total column ozone takes place. The annual variation in zonal mean total ozone around the equator is composed of symmetric and asymmetric modes with respect to the equator, with maximum contributions being around 19 km for the symmetric modemore » and around 25 km for the asymmetric mode. The persistent zonal wavenumber 1 structure observed by the total ozone mapping spectrometer over the equator is almost missing in the SAGE-derived column amounts integrated in the stratosphere, suggesting a significant contribution from tropospheric ozone. Interannual variations in the equatorial ozone are dominated by the QBO above 20 km and the ENSO-related variation below 20 km. The ozone QBO is characterized by zonally uniform phase changes in association with the zonal wind QBO in the equatorial lower stratosphere. The ENSO-related ozone variation consists of both the east-west vacillation and the zonally uniform phase variation. During the El Nino event, the east-west contrast with positive (negative) deviations in the eastern (western) hemisphere is conspicuous, while the decreasing tendency of the zonal mean values is maximum at the same time. 28 refs., 13 figs.« less

The Impact of Withholding Observations from TOMS or SBUV Instruments on the GEOS Ozone Data Assimilation System

NASA Technical Reports Server (NTRS)

Stajner, Ovanka; Riishojgaard, Lars Peter; Rood, Richard B.

2000-01-01

In a data assimilation system (DAS), model forecast atmospheric fields, observations and their respective statistics are combined in an attempt to produce the best estimate of these fields. Ozone observations from two instruments are assimilated in the Goddard Earth Observing System (GEOS) ozone DAS: the Total Ozone Mapping Spectrometer (TOMS) and the Solar Backscatter Ultraviolet (SBUV) instrument. The assimilated observations are complementary; TOMS provides a global daily coverage of total column ozone, without profile information, while SBUV measures ozone profiles and total column ozone at nadir only. The purpose of this paper is to examine the performance of the ozone assimilation system in the absence of observations from one of the instruments as it can happen in the event of a failure of an instrument or when there are problems with an instrument for a limited time. Our primary concern is for the performance of the GEOS ozone DAS when it is used in the operational mode to provide near real time analyzed ozone fields in support of instruments on the Terra satellite. In addition, we are planning to produce a longer term ozone record by assimilating historical data. We want to quantify the differences in the assimilated ozone fields that are caused by the changes in the TOMS or SBUV observing network. Our primary interest is in long term and large scale features visible in global statistics of analysis fields, such as differences in the zonal mean of assimilated ozone fields or comparisons with independent observations, While some drifts in assimilated fields occur immediately, after assimilating just one day of different observations, the others develop slowly over several months. Thus, we are also interested in the length of time, which is determined from time series, that is needed for significant changes to take place.

Characterization of natural organic matter treated by iron oxide nanoparticle incorporated ceramic membrane-ozonation process.

PubMed

Park, Hosik; Kim, Yohan; An, Byungryul; Choi, Heechul

2012-11-15

In this study, changes in the physical and structural properties of natural organic matter (NOM) were observed during hybrid ceramic membrane processes that combined ozonation with ultrafiltration ceramic membrane (CM) or with a reactive ceramic membrane (RM), namely, an iron oxide nanoparticles (IONs) incorporated-CM. NOM from feed water and NOM from permeate treated with hybrid ceramic membrane processes were analyzed by employing several NOM characterization techniques. Specific ultraviolet absorbance (SUVA), high-performance size exclusion chromatography (HPSEC) and fractionation analyses showed that the hybrid ceramic membrane process effectively removed and transformed relatively high contents of aromatic, high molecular weight and hydrophobic NOM fractions. Fourier transform infrared spectroscopy (FTIR) and 3-dimensional excitation-emission matrix (EEM) fluorescence spectroscopy revealed that this process caused a significant decrease of the aromaticity of humic-like structures and an increase in electron withdrawing groups. The highest removal efficiency (46%) of hydroxyl radical probe compound (i.e., para-Chlorobenzoic acid (pCBA)) in RM-ozonation process compared with that in CM without ozonation process (8%) revealed the hydroxyl radical formation by the surface-catalyzed reaction between ozone and IONs on the surface of RM. In addition, experimental results on flux decline showed that fouling of RM-ozonation process (15%) was reduced compared with that of CM without ozonation process (30%). These results indicated that the RM-ozonation process enhanced the destruction of NOM and reduced the fouling by generating hydroxyl radicals from the catalytic ozonation in the RM-ozonation process. Copyright © 2012 Elsevier Ltd. All rights reserved.

Spectroscopy of Solid State Laser Materials

NASA Technical Reports Server (NTRS)

Buoncristiani, A. M.

1994-01-01

We retrieved the vertical distribution of ozone from a series 0.005-0.013/cm resolution infrared solar spectra recorded with the McMath Fourier Transform spectrometer at the Kitt Peak National Solar Observatory. The analysis is based on a multi-layer line-by-line forward model and a semi-empirical version of the optimal estimation inversion method by Rodgers. The 1002.6-1003.2/cm spectral interval has been selected for the analysis on the basis of synthetic spectrum calculations. The characterization and error analysis of the method have been performed. It was shown that for the Kitt Peak spectral resolution and typical signal-to-noise ratio (greater than or equal to 100) the retrieval is stable, with the vertical resolution of approximately 5 km attainable near the surface degrading to approximately 10 km in the stratosphere. Spectra recorded from 1980 through 1993 have been analyzed. The retrieved total ozone and vertical profiles have been compared with total ozone mapping spectrometer (TOMS) satellite total columns for the location and dates of the Kitt Peak Measurements and about 100 ozone ozonesoundings and Brewer total column measurements from Palestine, Texas, from 1979 to 1985. The total ozone measurements agree to +/- 2%. The retrieved profiles reproduce the seasonally averaged variations with altitude, including the ozone spring maximum and fall minimum measured by Palestine sondes, but up to 15% differences in the absolute values are obtained.

Effects of cloud, aerosol, and ozone on surface spectral Ultraviolet and total irradiance observed in Seoul, Korea

NASA Astrophysics Data System (ADS)

Lee, Hana; Kim, Jhoon; Kim, Woogyung; Lee, Yun Gon; Cho, Hi Ku

2015-04-01

In recent years, there have been substantial attempts to model the radiative transfer for climatological and biological purposes. However, the incorporation of clouds, aerosols and ozone into the modeling process is one of the difficult tasks due to their variable transmission in both temporal and space domains. In this study we quantify the atmospheric transmissions by clouds, aerosol optical depth (AOD at 320 nm) and total ozone (Ozone) together with all skies in three solar radiation components of the global solar (GS 305-2800nm), total ultraviolet (TUV 290-363nm) and the erythemal weighted ultraviolet (EUV 290-325nm) irradiances with statistical methods using the data at Seoul. The purpose of this study also is to clarify the different characteristics between cloud, AOD and Ozone in the wavelength-dependent solar radiation components. The ozone, EUV and TUV used in this study (March 2003 - February 2014) have been measured with Dobson Spectrophotometer (Beck #124) and Brewer Spectrophotometer (SCI-TEC#148) at Yonsei University, respectively. GS, Cloud Cover (CC) are available from the Korean Meteorological Agency. The measured total (effect of cloud, aerosol, and ozone) transmissions on annual average showed 74%, 76% and 80% of GS, TUV and EUV irradiance, respectively. For the comparison of the measured values with modeled, we have also constructed a multiple linear regression model for the total transmission. The average ratio of measured to modeled total transmission were 0.94, 0.96 and 0.96 with higher measured than modeled value in the three components, respectively, The individual transmission by clouds under the constant AOD and Ozone atmosphere on average showed 68%, 71% and 76% and further the overcast clouds reduced the transmissions to the 45%, 54% and 59% of the clear sky irradiance in the GS, TUV and EUV, respectively. The annual transmissions by AOD showed on average 67%, 70% and 74% and further the high loadings 2.5-4.0 AOD reduced the transmission to 50%, 52% and 55% of clear sky irradiance under the contact cloud and ozone atmosphere in the GS, TUV and EUV, respectively. And annual average EUV transmission by Ozone was 75 % of the clear-sky value under the constant CC and AOD. In future study, we are compare OMI data with ground-based instruments in order to use measured data for scientific studies.

Comparison of Profile Total Ozone from SBUV (v8.6) with GOME-Type and Ground-Based Total Ozone for a 16-Year Period (1996 to 2011)

NASA Technical Reports Server (NTRS)

Chiou, E. W.; Bhartia, P. K.; McPeters, R. D.; Loyola, D. G.; Coldewey-Egbers, M.; Fioletov, V. E.; Van Roozendael, M.; Spurr, R.; Lerot, C.; Frith, S. M.

2014-01-01

This paper describes the comparison of the variability of total column ozone inferred from the three independent multi-year data records, namely, (i) Solar Backscatter Ultraviolet Instrument (SBUV) v8.6 profile total ozone, (ii) GTO (GOME-type total ozone), and (iii) ground-based total ozone data records covering the 16-year overlap period (March 1996 through June 2011). Analyses are conducted based on area-weighted zonal means for 0-30degS, 0-30degN, 50-30degS, and 30-60degN. It has been found that, on average, the differences in monthly zonal mean total ozone vary between -0.3 and 0.8% and are well within 1 %. For GTO minus SBUV, the standard deviations and ranges (maximum minus minimum) of the differences regarding monthly zonal mean total ozone vary between 0.6-0.7% and 2.8-3.8% respectively, depending on the latitude band. The corresponding standard deviations and ranges regarding the differences in monthly zonal mean anomalies show values between 0.4-0.6% and 2.2-3.5 %. The standard deviations and ranges of the differences ground-based minus SBUV regarding both monthly zonal means and anomalies are larger by a factor of 1.4-2.9 in comparison to GTO minus SBUV. The ground-based zonal means demonstrate larger scattering of monthly data compared to satellite-based records. The differences in the scattering are significantly reduced if seasonal zonal averages are analyzed. The trends of the differences GTO minus SBUV and ground-based minus SBUV are found to vary between -0.04 and 0.1%/yr (-0.1 and 0.3DU/yr). These negligibly small trends have provided strong evidence that there are no significant time-dependent differences among these multiyear total ozone data records. Analyses of the annual deviations from pre-1980 level indicate that, for the 15-year period of 1996 to 2010, all three data records show a gradual increase at 30-60degN from -5% in 1996 to -2% in 2010. In contrast, at 50-30degS and 30degS- 30degN there has been a leveling off in the 15 years after 1996. The deviations inferred from GTO and SBUV show agreement within 1 %, but a slight increase has been found in the differences during the period 1996-2010.

Analysis and interpretation of variabilities in ozone and temperature fields

NASA Technical Reports Server (NTRS)

Chandra, S.

1990-01-01

The temporal and spatial variabilities were studied of short and long term fluctuations in stratospheric ozone and temperature at various pressure levels using several years of ozone, temperature, and solar flux data from Nimbus 4, Nimbus 7, and SME satellites. Some results are as follows: (1) the solar UV flux and various indices of solar activity indicate a strong period at about 5 months; (2) satellite total ozone observations were analyzed using 17 years of data from the Nimbus 4 BUV and the Nimbus 7 SBUV experiments, which show very similar seasonal variations and quasibiennial oscillation (QBO) with some indication of a 4 year component; and (3) the zonal characteristics of both the ozone and temperature trends were derived from ten years of total ozone and 50 mb temperature based on the Nimbus 7 TOMS measurements and the NMC analyses respectively.

Reduction of Environmental Listeria Using Gaseous Ozone in a Cheese Processing Facility.

PubMed

Eglezos, Sofroni; Dykes, Gary A

2018-05-01

A cheese processing facility seeking to reduce environmental Listeria colonization initiated a regime of ozonation across all production areas as an adjunct to its sanitation regimes. A total of 360 environmental samples from the facility were tested for Listeria over a 12-month period. A total of 15 areas before and 15 areas after ozonation were tested. Listeria isolations were significantly ( P < 0.001) reduced from 15.0% in the preozonation samples to 1.67% in the postozonation samples in all areas. No deleterious effects of ozonation were noted on the wall paneling, seals, synthetic floors, or cheese processing equipment. The ozonation regime was readily incorporated by sanitation staff into the existing good manufacturing practice program. The application of ozone may result in a significant reduction in the prevalence of Listeria in food processing facilities.

20 Years of Total and Tropical Ozone Time Series Based on European Satellite Observations

NASA Astrophysics Data System (ADS)

Loyola, D. G.; Heue, K. P.; Coldewey-Egbers, M.

2016-12-01

Ozone is an important trace gas in the atmosphere, while the stratospheric ozone layer protects the earth surface from the incident UV radiation, the tropospheric ozone acts as green house gas and causes health damages as well as crop loss. The total ozone column is dominated by the stratospheric column, the tropospheric columns only contributes about 10% to the total column.The ozone column data from the European satellite instruments GOME, SCIAMACHY, OMI, GOME-2A and GOME-2B are available within the ESA Climate Change Initiative project with a high degree of inter-sensor consistency. The tropospheric ozone columns are based on the convective cloud differential algorithm. The datasets encompass a period of more than 20 years between 1995 and 2015, for the trend analysis the data sets were harmonized relative to one of the instruments. For the tropics we found an increase in the tropospheric ozone column of 0.75 ± 0.12 DU decade^{-1} with local variations between 1.8 and -0.8. The largest trends were observed over southern Africa and the Atlantic Ocean. A seasonal trend analysis led to the assumption that the increase is caused by additional forest fires.The trend for the total column was not that certain, based on model predicted trend data and the measurement uncertainty we estimated that another 10 to 15 years of observations will be required to observe a statistical significant trend. In the mid latitudes the trends are currently hidden in the large variability and for the tropics the modelled trends are low. Also the possibility of diverging trends at different altitudes must be considered; an increase in the tropospheric ozone might be accompanied by decreasing stratospheric ozone.The European satellite data record will be extended over the next two decades with the atmospheric satellite missions Sentinel 5 Precursor (launch end of 2016), Sentinel 4 and Sentinel 5.

Formation and emissions of carbonyls during and following gas-phase ozonation of indoor materials

NASA Astrophysics Data System (ADS)

Poppendieck, D. G.; Hubbard, H. F.; Weschler, C. J.; Corsi, R. L.

Ozone concentrations that are several orders of magnitude greater than typical urban ambient concentrations are necessary for gas-phase ozonation of buildings, either for deodorization or for disinfection of biological agents. However, there is currently no published literature on the interaction of building materials and ozone under such extreme conditions. It would be useful to understand, for example in the case of building re-occupation planning, what types and amounts of reaction products may form and persist in a building after ozonation. In this study, 24 materials were exposed to ozone at concentrations of 1000 ppm in the inlet stream of experimental chambers. Fifteen target carbonyls were selected and measured as building ozonation by-products (BOBPs). During the 36 h that include the 16 h ozonation and 20 h persistence phase, the total BOBP mass released from flooring and wall coverings ranged from 1 to 20 mg m -2, with most of the carbonyls being of lower molecular weight (C 1-C 4). In contrast, total BOBP mass released from wood-based products ranged from 20 to 100 mg m -2, with a greater fraction of the BOBPs being heavier carbonyls (C 5-C 9). The total BOBP mass released during an ozonation event is a function of both the total surface area of the material and the BOBP emission rate per unit area of material. Ceiling tile, carpet, office partition, and gypsum wallboard with flat latex paint often have large surface areas in commercial buildings and these same materials exhibited relatively high BOBP releases. The greatest overall BOBP mass releases were observed for three materials that building occupants might have significant contact with: paper, office partition, and medium density fiberboard, e.g., often used in office furniture. These materials also exhibited extended BOBP persistence following ozonation; some BOBPs (e.g., nonanal) persist for months or more at emission rates large enough to result in indoor concentrations that exceed their odor threshold.

Evidence for a Continuous Decline in Lower Stratospheric Ozone Offsetting Ozone Layer Recovery

NASA Technical Reports Server (NTRS)

Ball, William T.; Alsing, Justin; Mortlock, Daniel J.; Staehelin, Johannes; Haigh, Joanna D.; Peter, Thomas; Tummon, Fiona; Stuebi, Rene; Stenke, Andrea; Anderson, John;

Evidence for a continuous decline in lower stratospheric ozone offsetting ozone layer recovery

NASA Astrophysics Data System (ADS)

Ball, William T.; Alsing, Justin; Mortlock, Daniel J.; Staehelin, Johannes; Haigh, Joanna D.; Peter, Thomas; Tummon, Fiona; Stübi, Rene; Stenke, Andrea; Anderson, John; Bourassa, Adam; Davis, Sean M.; Degenstein, Doug; Frith, Stacey; Froidevaux, Lucien; Roth, Chris; Sofieva, Viktoria; Wang, Ray; Wild, Jeannette; Yu, Pengfei; Ziemke, Jerald R.; Rozanov, Eugene V.

2018-02-01

Ozone forms in the Earth's atmosphere from the photodissociation of molecular oxygen, primarily in the tropical stratosphere. It is then transported to the extratropics by the Brewer-Dobson circulation (BDC), forming a protective ozone layer around the globe. Human emissions of halogen-containing ozone-depleting substances (hODSs) led to a decline in stratospheric ozone until they were banned by the Montreal Protocol, and since 1998 ozone in the upper stratosphere is rising again, likely the recovery from halogen-induced losses. Total column measurements of ozone between the Earth's surface and the top of the atmosphere indicate that the ozone layer has stopped declining across the globe, but no clear increase has been observed at latitudes between 60° S and 60° N outside the polar regions (60-90°). Here we report evidence from multiple satellite measurements that ozone in the lower stratosphere between 60° S and 60° N has indeed continued to decline since 1998. We find that, even though upper stratospheric ozone is recovering, the continuing downward trend in the lower stratosphere prevails, resulting in a downward trend in stratospheric column ozone between 60° S and 60° N. We find that total column ozone between 60° S and 60° N appears not to have decreased only because of increases in tropospheric column ozone that compensate for the stratospheric decreases. The reasons for the continued reduction of lower stratospheric ozone are not clear; models do not reproduce these trends, and thus the causes now urgently need to be established.

Low frequency oscillations in total ozone measurements

NASA Technical Reports Server (NTRS)

Gao, X. H.; Stanford, J. L.

1989-01-01

Low frequency oscillations with periods of approximately one to two months are found in eight years of global grids of total ozone data from the Total Ozone Mapping Spectrometer (TOMS) satellite instrument. The low frequency oscillations corroborate earlier analyses based on four years of data. In addition, both annual and seasonal one-point correlation maps based on the 8-year TOMS data are presented. The results clearly show a standing dipole in ozone perturbations, oscillating with 35 to 50 day periods over the equatorial Indian Ocean-west Pacific region. This contrasts with the eastward moving dipole reported in other data sets. The standing ozone dipole appears to be a dynamical feature associated with vertical atmospheric motions. Consistent with prior analyses based on lower stratospheric temperature fields, large-scale standing patterns are also found in the extratropics of both hemispheres, correlated with ozone fluctuations over the equatorial west Pacific. In the Northern Hemisphere, a standing pattern is observed extending from the tropical Indian Ocean to the north Pacific, across North America, and down to the equatorial Atlantic Ocean region. This feature is most pronounced in the NH summer.

Measurements of historical total ozone from the Chalonge-Divan stellar spectrum program: A reanalysis of the 1953-1972 data and a comparison with simultaneous Dobson Arosa measurements

NASA Astrophysics Data System (ADS)

Griffin, R. E. M.; Fioletov, V.; McConnell, J. C.

2006-06-01

We report new determinations of total ozone obtained by reanalyzing a unique set of astronomical observations that were made in the mid-20th century at observatories in France (Haute-Provence) and Switzerland (Jungfraujoch) for the purpose of calculating nightly atmospheric extinction coefficients in the UV (Rayleigh scattering and total ozone) as part of a program to measure absolute stellar fluxes. Only a small fraction of the original ozone results, corresponding to data obtained during 1958-1959, are in the public domain at the World Ozone and Ultraviolet Data Centre; the rest were on handwritten sheets and were stored at Haute-Provence. Both astronomical sites are close enough geographically to Arosa (Switzerland) that the respective ozone values can be compared directly. The comparison reveals a generally very close resemblance, even down to the pattern of daily variations, with a correlation coefficient of 0.78, but an overall negative bias of 6-7% in the stellar results. The bias appears to be slightly larger prior to 1958.

Spatial regression analysis on 32 years of total column ozone data

NASA Astrophysics Data System (ADS)

Knibbe, J. S.; van der A, R. J.; de Laat, A. T. J.

2014-08-01

Multiple-regression analyses have been performed on 32 years of total ozone column data that was spatially gridded with a 1 × 1.5° resolution. The total ozone data consist of the MSR (Multi Sensor Reanalysis; 1979-2008) and 2 years of assimilated SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY) ozone data (2009-2010). The two-dimensionality in this data set allows us to perform the regressions locally and investigate spatial patterns of regression coefficients and their explanatory power. Seasonal dependencies of ozone on regressors are included in the analysis. A new physically oriented model is developed to parameterize stratospheric ozone. Ozone variations on nonseasonal timescales are parameterized by explanatory variables describing the solar cycle, stratospheric aerosols, the quasi-biennial oscillation (QBO), El Niño-Southern Oscillation (ENSO) and stratospheric alternative halogens which are parameterized by the effective equivalent stratospheric chlorine (EESC). For several explanatory variables, seasonally adjusted versions of these explanatory variables are constructed to account for the difference in their effect on ozone throughout the year. To account for seasonal variation in ozone, explanatory variables describing the polar vortex, geopotential height, potential vorticity and average day length are included. Results of this regression model are compared to that of a similar analysis based on a more commonly applied statistically oriented model. The physically oriented model provides spatial patterns in the regression results for each explanatory variable. The EESC has a significant depleting effect on ozone at mid- and high latitudes, the solar cycle affects ozone positively mostly in the Southern Hemisphere, stratospheric aerosols affect ozone negatively at high northern latitudes, the effect of QBO is positive and negative in the tropics and mid- to high latitudes, respectively, and ENSO affects ozone negatively between 30° N and 30° S, particularly over the Pacific. The contribution of explanatory variables describing seasonal ozone variation is generally large at mid- to high latitudes. We observe ozone increases with potential vorticity and day length and ozone decreases with geopotential height and variable ozone effects due to the polar vortex in regions to the north and south of the polar vortices. Recovery of ozone is identified globally. However, recovery rates and uncertainties strongly depend on choices that can be made in defining the explanatory variables. The application of several trend models, each with their own pros and cons, yields a large range of recovery rate estimates. Overall these results suggest that care has to be taken in determining ozone recovery rates, in particular for the Antarctic ozone hole.

Ozone-induced foliar damage and release of stress volatiles is highly dependent on stomatal openness and priming by low-level ozone exposure in Phaseolus vulgaris.

PubMed

Li, Shuai; Harley, Peter C; Niinemets, Ülo

2017-09-01

Acute ozone exposure triggers major emissions of volatile organic compounds (VOCs), but quantitatively, it is unclear how different ozone doses alter the start and the total amount of these emissions, and the induction rate of different stress volatiles. It is also unclear whether priming (i.e. pre-exposure to lower O 3 concentrations) can modify the magnitude and kinetics of volatile emissions. We investigated photosynthetic characteristics and VOC emissions in Phaseolus vulgaris following acute ozone exposure (600 nmol mol -1 for 30 min) under illumination and in darkness and after priming with 200 nmol mol -1 O 3 for 30 min. Methanol and lipoxygenase (LOX) pathway product emissions were induced rapidly, followed by moderate emissions of methyl salicylate (MeSA). Stomatal conductance prior to acute exposure was lower in darkness and after low O 3 priming than in light and without priming. After low O 3 priming, no MeSA and lower LOX emissions were detected under acute exposure. Overall, maximum emission rates and the total amount of emitted LOX products and methanol were quantitatively correlated with total stomatal ozone uptake. These results indicate that different stress volatiles scale differently with ozone dose and highlight the key role of stomatal conductance in controlling ozone uptake, leaf injury and volatile release. © 2017 John Wiley & Sons Ltd.

The Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998-2002 Tropical Ozone Climatology. 3; Instrumentation and Station-to-Station Variability

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Witte, Jacqueline C.; Smit, Herman G. J.; Oltmans, Samuel J.; Johnson, Bryan J.; Kirchhoff, Volker W. J. H.; Schmidlin, Francis J.

2004-01-01

Abstract: Since 1998 the Southern Hemisphere ADditional OZonesondes (SHADOZ) project has collected more than 2000 ozone profiles from a dozen tropical and subtropical sites using balloon-borne electrochemical concentration cell (ECC) ozonesondes. The data (with accompanying pressure-temperature-humidity soundings) are archived. Analysis of ozonesonde imprecision within the SHADOZ dataset revealed that variations in ozonesonde technique could lead to station-to-station biases in the measurements. In this paper imprecisions and accuracy in the SHADOZ dataset are examined in light of new data. When SHADOZ total ozone column amounts are compared to version 8 TOMS (2004 release), discrepancies between sonde and satellite datasets decline 1-2 percentage points on average, compared to version 7 TOMS. Variability among stations is evaluated using total ozone normalized to TOMS and results of laboratory tests on ozonesondes (JOSE-2O00, Julich Ozonesonde Intercomparison Experiment). Ozone deviations from a standard instrument in the JOSE flight simulation chamber resemble those of SHADOZ station data relative to a SHADOZ-defined climatological reference. Certain systematic variations in SHADOZ ozone profiles are accounted for by differences in solution composition, data processing and instrument (manufacturer). Instrument bias leads to a greater ozone measurement above 25 km over Nairobi and to lower total column ozone at three Pacific sites compared to other SHADOZ stations at 0-20 deg.S.

Comparison of ozone retrievals from the Pandora spectrometer system and Dobson spectrophotometer in Boulder, Colorado

NASA Astrophysics Data System (ADS)

Herman, J.; Evans, R.; Cede, A.; Abuhassan, N.; Petropavlovskikh, I.; McConville, G.

2015-03-01

A comparison of retrieved total column ozone amounts TCO between the Pandora #34 spectrometer system and the Dobson #061 spectrophotometer from direct-sun observations was performed on the roof of the Boulder, Colorado NOAA building. This paper, part of an ongoing study, covers a one-year period starting on 17 December 2013. Both the standard Dobson and Pandora total column ozone TCO retrievals required a correction TCOcorr = TCO (1+C(T)) using the effective climatology derived ozone temperature T to remove a seasonal difference caused by using a fixed temperature in each retrieval algorithm. The respective corrections C(T) are CPandora = 0.00333(T-225) and CDobson = -0.0013 (T-226.7) per K. After the applied corrections removed the seasonal retrieval dependence on ozone temperature, TCO agreement between the instruments was within 1% for clear-sky conditions. For clear-sky observations, both co-located instruments tracked the day-to-day variation in total column ozone amounts with a correlation of r2 = 0.97 and an average offset of 1.1 ± 5.8 DU. In addition, the Pandora data showed 0.3% annual average agreement with satellite overpass data from AURA/OMI (Ozone Monitoring Instrument) and 1% annual average offset with Suomi-NPP/OMPS (Suomi National Polar-orbiting Partnership, the nadir viewing portion of the Ozone Mapper Profiler Suite).

Ozone-induced foliar damage and release of stress volatiles is highly dependent on stomatal openness and priming by low-level ozone exposure in Phaseolus vulgaris

PubMed Central

Li, Shuai; Harley, Peter C.; Niinemets, Ülo

2018-01-01

Acute ozone exposure triggers major emissions of volatile organic compounds (VOC), but quantitatively, it is unclear how different ozone doses alter the start and the total amount of these emissions, and the induction rate of different stress volatiles. It is also unclear whether priming (i.e., pre-exposure to lower O3 concentrations) can modify the magnitude and kinetics of volatile emissions. We investigated photosynthetic characteristics and VOC emissions in Phaseolus vulgaris following acute ozone exposure (600 nmol mol-1 for 30 min) under illumination and in darkness and after priming with 200 nmol mol-1 O3 for 30 min. Methanol and lipoxygenase (LOX) pathway product emissions were induced rapidly, followed by moderate emissions of methyl salicylate (MeSA). Stomatal conductance prior to acute exposure was lower in darkness and after low O3 priming than in light and without priming. After low O3 priming, no MeSA and lower LOX emissions were detected under acute exposure. Overall, maximum emission rates and the total amount of emitted LOX products and methanol were quantitatively correlated with total stomatal ozone uptake. These results indicate that different stress volatiles scale differently with ozone dose and highlight the key role of stomatal conductance in controlling ozone uptake, leaf injury and volatile release. PMID:28623868

Initial estimate of NOAA-9 SBUV/2 total ozone drift: Based on comparison with re-calibrated TOMS measurements and pair justification of SBUV/2

NASA Technical Reports Server (NTRS)

Wellemeyer, C. G.; Taylor, S. L.; Gu, X. U.; Mcpeters, Richard D.; Hudson, R. D.

1990-01-01

Newly recalibrated version 6 Total Ozone Mapping Spectrometer (TOMS) data are used as a reference measurement in a comparison of monthly means of total ozone in 10 degree latitude zones from SBUV/2 and the nadir measurements from TOMS. These comparisons indicate a roughly linear long-term drift in SBUV/2 total ozone relative to TOMS of about 2.5 Dobson units per year at the equator over the first three years of SBUV/2. The pari justification technique is also applied to the SBUV/2 measurements in a manner similar to that used for SBUV and TOMS. The higher solar zenith angles associated with the afternoon orbit of NOAA-9 and the large changes in solar zenith angle associated with its changing equator crossing time degrade the accuracy of the pair justification method relative to its application to SBUV and TOMS, but the results are consistent with the SBUV/2-TOMS comparisons, and show a roughly linear drift in SBUV/2 of 2.5 to 4.5 Dobson units per year in equatorial ozone.

Total atmospheric ozone determined from spectral measurements of direct solar UV irradiance

NASA Astrophysics Data System (ADS)

Huber, Martin; Blumthaler, Mario; Ambach, Walter; Staehelin, Johannes

1995-01-01

With a double monochromator, high resolution spectral measurements of direct solar UV-irradiance were performed in Arosa during February and March, 1993. Total atmospheric ozone amount is determined by fitting model calculations to the measured spectra. The results are compared with the operationally performed measurements of a Dobson and a Brewer spectrometer. The total ozone amount determined from spectral measurements differs from the results of the Dobson instrument by -1.1±0.9% and from those of the Brewer instrument by -0.4±0.7%.

Ozone density measurements in the troposphere and stratosphere of Natal

NASA Technical Reports Server (NTRS)

Kirchhoff, V. W. J. H.; Motta, A. G.

1983-01-01

Ozone densitities were measured in the troposphere and stratosphere of Natal using ECC sondes launches on balloons. The data analyzed so far show tropospheric densities and total ozone contents larger than expected.

The effect of surface anisotropy on the accuracy of total ozone estimates from satellite observations

NASA Technical Reports Server (NTRS)

Fraser, R. S.; Ahmad, Z.

1978-01-01

The total amount of ozone in a vertical column of the earth's atmosphere is being derived from satellite measurements of the intensity of ultraviolet sunlight scattered by the earth-atmosphere system. The algorithm for deriving the ozone amount utilizes the assumption that the earth's surface reflects the incident light isotropically according to Lambert's law. Natural surface reflection deviates more or less from this law. Two extreme examples of anisotropic reflection from dark ocean and from bright snow are analyzed by means of models for their effects on the derived values of ozone.

Total ozone measurement: Intercomparison of prototype New Zealand filter instrument and Dobson spectrophotometer

NASA Technical Reports Server (NTRS)

Basher, R. E.

1978-01-01

A five month intercomparison showed that the total ozone amounts of a prototype narrowband interference filter instrument were 7% less than those of a Dobson instrument for an ozone range of 0.300 to 0.500 atm cm and for airmasses less than two. The 7% bias was within the intercomparison calibration uncertainty. An airmass dependence in the Dobson instrument made the bias relationship airmass-dependent but the filter instrument's ozone values were generally constant to 2% up to an airmass of four. Long term drift in the bias was negligible.

SHADOZ in the Aura Era

NASA Technical Reports Server (NTRS)

Witte, J. C.; Thompson, A. M.; Oltmans, S. J.; Schoeberl, M. R.; Bhartia, P. K.; Froidevaux, L.; Schmidlin, F.; Calpini, B.; Shiotani, M.; Fujiwara, M.;

A comparison of SAGE 1, SBUV, and Umkehr ozone profiles including a search for Umkehr aerosol effects

NASA Technical Reports Server (NTRS)

Newchurch, M. J.; Grams, G. W.; Cunnold, D. M.; Deluisi, J. J.

1987-01-01

Using a spatially weighted average for the stratospheric aerosol and gas experiment 1 (SAGE 1) events derived from an autocorrelation analysis, 337 colocated SAGE 1 and Umkehr ozone profiles are found. The total column ozone in layers two through nine measured by SAGE 1 is found to be 4.6 + or - 1.3 percent higher at the 95 percent confidence level than the approximate total column ozone measured by Umkehr. Average layer ozone differences indicate that most of this discrepancy resides in the lower layers. Intercomparison of SAGE 1, Nimbus 7 solar backscattered ultraviolet (SBUV), and Umkehr ozone at stations north of 30 deg indicates that, in layer six, Umkehr values are consistently higher than both SAGE 1 and SBUV by about 10 percent. In layer eight, SBUV ozone is higher than both SAGE 1 and SBUV by about 10 percent. In the upper stratosphere, the SAGE 1-Umkehr ozone differences are small for low stratospheric aerosol optical depth cases, but vary from -3 percent in layer six to -8 percent in layer nine for high optical depth cases.

Historical Tropospheric and Stratospheric Ozone Radiative Forcing Using the CMIP6 Database

NASA Astrophysics Data System (ADS)

Checa-Garcia, Ramiro; Hegglin, Michaela I.; Kinnison, Douglas; Plummer, David A.; Shine, Keith P.

2018-04-01

We calculate ozone radiative forcing (RF) and stratospheric temperature adjustments for the period 1850-2014 using the newly available Coupled Model Intercomparison Project phase 6 (CMIP6) ozone data set. The CMIP6 total ozone RF (1850s to 2000s) is 0.28 ± 0.17 W m-2 (which is 80% higher than our CMIP5 estimation), and 0.30 ± 0.17 W m-2 out to the present day (2014). The total ozone RF grows rapidly until the 1970s, slows toward the 2000s, and shows a renewed growth thereafter. Since the 1990s the shortwave RF exceeds the longwave RF. Global stratospheric ozone RF is positive between 1930 and 1970 and then turns negative but remains positive in the Northern Hemisphere throughout. Derived stratospheric temperature changes show a localized cooling in the subtropical lower stratosphere due to tropospheric ozone increases and cooling in the upper stratosphere due to ozone depletion by more than 1 K already prior to the satellite era (1980) and by more than 2 K out to the present day (2014).

The 1998-2000 SHADOZ (Southern Hemisphere ADditional OZonesondes) Tropical Ozone Climatology. 2; Stratospheric and Tropospheric Ozone Variability and the Zonal Wave-One

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Witte, Jacquelyn C.; Oltmans, Samuel J.; Schmidlin, Francis J.; Logan, Jennifer A.; Fujiwara, Masatomo; Kirchhoff, Volker W. J. H.; Posny, Francoise; Coetzee, Gert J. R.; Hoegger, Bruno;

Satellite remote sensing and ozonesonde observation of ozone vertical profile and severe storm development

NASA Technical Reports Server (NTRS)

Hung, R. J.; Liu, J. M.

1988-01-01

Two year ozonesonde data, January 1981 to December 1982, observed at four Canadian stations, and two-and-a-half year backscattered ultraviolet experiment data on the Nimbus-4 satellite, April 1970 to August 1972, observed over five U.S. stations, were used to study the relationship between the total ozone, vertical distribution of the ozone mixing ratio, height of half the total ozone, and the variation of local tropopause height. In view of the correlation between the variation of the tropopause height and the possible development of severe storms, a better understanding of the effect of the vertical distribution of the local ozone profile on the variation of the tropopause height can give considerable insight into the development of severe storms.

Dobson total ozone series of Oxford: Reevaluation and applications

NASA Astrophysics Data System (ADS)

Vogler, C.; BröNnimann, S.; Staehelin, J.; Griffin, R. E. M.

2007-10-01

We have reevaluated the original total ozone measurements made in Oxford between 1924 and 1957, with a view to extending backward in time the existing total ozone series from 1957 to 1975. The Oxford measurements are the oldest Dobson observations in the world. Their prime importance, when coupled with the series from Arosa (since 1926) and Tromsø (since 1935), is for increasing basic understanding of stratospheric ozone and dynamics, while in relation to studies of the recent ozone depletion they constitute a baseline of considerable (and unique) significance and value. However, the reevaluation was made difficult on account of changes to the instruments and wavelengths as the early data collection methods evolved, while unknowns due to the influence of aerosols and the possible presence of dioxides of sulphur and nitrogen created additional problems. Our reevaluation was based on statistical procedures (comparisons with meteorological upper air data and ozone series from Arosa) and also on corrections suggested by Dobson himself. The comparisons demonstrate that the data are internally consistent and of good quality. Nevertheless, as post-1957 data were not assessed in this study, the series cannot be recommended at present for trend analysis, though the series can be used for climatological studies. By supplementing the Oxford data with other existing series, we present a European total ozone climatology for 1924-1939, 1950-1965, and 1988-2000 and analyze the data with respect to variables measuring the strength and the temperature of the polar vortex.

Elevated tropospheric ozone increased grain protein and amino acid content of a hybrid rice without manipulation by planting density.

PubMed

Zhou, Xiaodong; Zhou, Juan; Wang, Yunxia; Peng, Bin; Zhu, Jianguo; Yang, Lianxin; Wang, Yulong

2015-01-01

Rising tropospheric ozone affects crop yield and quality. Rice protein concentration, which is closely associated with eating/cooking quality, is of critical importance to nutritional quality. The ozone effect on amino acids of rice grains was little known, especially grown under different cultivation conditions. A hybrid rice cultivar Shanyou 63 was grown in 2010 and 2011 to investigate the interactive effect of ozone exposure and planting density on rice protein quality in a free-air ozone enrichment system. The content of protein, total amino acids (TAA), total essential (TEAA) and non-essential amino acids (TNEAA) in rice grain was increased by 12-14% with elevated ozone. A similar significant response to ozone was observed for concentrations of the seven essential and eight non-essential amino acids. In contrast, elevated ozone caused a small but significant decrease in percentage of TEAA to TAA. The year effect was significant for all measured traits; however, interactions of ozone with year or planting density were not detected. The study suggested that season-long elevation of ozone concentration to projected 2050 levels will increase protein and amino acids of Shanyou 63, and crop management such as changing planting density might not alter the impact. © 2014 Society of Chemical Industry.

The Ecophysiology Of A Pinus Ponderosa Ecosystem Exposed To High Tropospheric Ozone: Implications For Stomatal And Non-Stomatal Ozone Fluxes

NASA Astrophysics Data System (ADS)

Fares, S.; McKay, M.; Goldstein, A.

2008-12-01

Ecosystems remove ozone from the troposphere through both stomatal and non-stomatal deposition. The portion of ozone taken up through stomata has an oxidative effect causing damage. We used a multi-year dataset to assess the physiological controls over ozone deposition. Environmental parameters, CO2 and ozone fluxes were measured continuously from January 2001 to December 2006 above a ponderosa pine plantation near Blodgett Forest, Georgetown, California. We studied the dynamic of NEE (Net Ecosystem Exchange, -838 g C m-2 yr-1) and water evapotranspiration on an annual and daily basis. These processes are tightly coupled to stomatal aperture which also controlled ozone fluxes. High levels of ozone concentrations (~ 100 ppb) were observed during the spring-summer period, with corresponding high levels of ozone fluxes (~ 30 μmol m-2 h-1). During the summer season, a large portion of the total ozone flux was due to non-stomatal processes, and we propose that a plant physiological control, releasing BVOC (Biogenic Volatile Organic Compounds), is mainly responsible. We analyzed the correlations of common ozone exposure metrics based on accumulation of concentrations (AOT40 and SUM0) with ozone fluxes (total, stomatal and non-stomatal). Stomatal flux showed poorer correlation with ozone concentrations than non-stomatal flux during summer and fall seasons, which largely corresponded to the growing period. We therefore suggest that AOT40 and SUM0 are poor predictors of ozone damage and that a physiologically based metric would be more effective.

Copernicus stratospheric ozone service, 2009-2012: validation, system intercomparison and roles of input data sets

NASA Astrophysics Data System (ADS)

Lefever, K.; van der A, R.; Baier, F.; Christophe, Y.; Errera, Q.; Eskes, H.; Flemming, J.; Inness, A.; Jones, L.; Lambert, J.-C.; Langerock, B.; Schultz, M. G.; Stein, O.; Wagner, A.; Chabrillat, S.

2015-03-01

This paper evaluates and discusses the quality of the stratospheric ozone analyses delivered in near real time by the MACC (Monitoring Atmospheric Composition and Climate) project during the 3-year period between September 2009 and September 2012. Ozone analyses produced by four different chemical data assimilation (CDA) systems are examined and compared: the Integrated Forecast System coupled to the Model for OZone And Related chemical Tracers (IFS-MOZART); the Belgian Assimilation System for Chemical ObsErvations (BASCOE); the Synoptic Analysis of Chemical Constituents by Advanced Data Assimilation (SACADA); and the Data Assimilation Model based on Transport Model version 3 (TM3DAM). The assimilated satellite ozone retrievals differed for each system; SACADA and TM3DAM assimilated only total ozone observations, BASCOE assimilated profiles for ozone and some related species, while IFS-MOZART assimilated both types of ozone observations. All analyses deliver total column values that agree well with ground-based observations (biases < 5%) and have a realistic seasonal cycle, except for BASCOE analyses, which underestimate total ozone in the tropics all year long by 7 to 10%, and SACADA analyses, which overestimate total ozone in polar night regions by up to 30%. The validation of the vertical distribution is based on independent observations from ozonesondes and the ACE-FTS (Atmospheric Chemistry Experiment - Fourier Transform Spectrometer) satellite instrument. It cannot be performed with TM3DAM, which is designed only to deliver analyses of total ozone columns. Vertically alternating positive and negative biases are found in the IFS-MOZART analyses as well as an overestimation of 30 to 60% in the polar lower stratosphere during polar ozone depletion events. SACADA underestimates lower stratospheric ozone by up to 50% during these events above the South Pole and overestimates it by approximately the same amount in the tropics. The three-dimensional (3-D) analyses delivered by BASCOE are found to have the best quality among the three systems resolving the vertical dimension, with biases not exceeding 10% all year long, at all stratospheric levels and in all latitude bands, except in the tropical lowermost stratosphere. The northern spring 2011 period is studied in more detail to evaluate the ability of the analyses to represent the exceptional ozone depletion event, which happened above the Arctic in March 2011. Offline sensitivity tests are performed during this month and indicate that the differences between the forward models or the assimilation algorithms are much less important than the characteristics of the assimilated data sets. They also show that IFS-MOZART is able to deliver realistic analyses of ozone both in the troposphere and in the stratosphere, but this requires the assimilation of observations from nadir-looking instruments as well as the assimilation of profiles, which are well resolved vertically and extend into the lowermost stratosphere.

Monitoring Intracellular Redox Changes in Ozone-exposed airway epithelial cells

EPA Science Inventory

Background: The toxicity of many compounds involves oxidative injury to cells. Direct assessment of mechanistic events involved in xenobiotic-induced oxidative stress is not easily achievable. Development of genetically-encoded probes designed for monitoring intracellular redox s...

Near-real-time TOMS, telecommunications and meteorological support for the 1987 Airborne Antarctic Ozone Experiment

NASA Technical Reports Server (NTRS)

Ardanuy, P.; Victorine, J.; Sechrist, F.; Feiner, A.; Penn, L.

1988-01-01

The goal of the 1987 Airborne Antarctic Ozone Experiment was to improve the understanding of the mechanisms involved in the formation of the Antarctic ozone hole. Total ozone data taken by the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) played a central role in the successful outcome of the experiment. During the experiment, the near-real-time TOMS total ozone observations were supplied within hours of real time to the operations center in Punta Arenas, Chile. The final report summarizes the role which Research and Data Systems (RDS) Corporation played in the support of the experiment. The RDS provided telecommunications to support the science and operations efforts for the Airborne Antarctic Ozone Experiment, and supplied near real-time weather information to ensure flight and crew safety; designed and installed the telecommunications network to link NASA-GSFC, the United Kingdom Meteorological Office (UKMO), Palmer Station, the European Center for Medium-Range Weather Forecasts (ECMWF) to the operation at Punta Arenas; engineered and installed stations and other stand-alone systems to collect data from designated low-orbiting polar satellites and beacons; provided analyses of Nimbus-7 TOMS data and backup data products to Punta Arenas; and provided synoptic meteorological data analysis and reduction.

Chemical transport model ozone simulations for spring 2001 over the western Pacific: Comparisons with TRACE-P lidar, ozonesondes, and Total Ozone Mapping Spectrometer columns

NASA Astrophysics Data System (ADS)

Wild, Oliver; Sundet, Jostein K.; Prather, Michael J.; Isaksen, Ivar S. A.; Akimoto, Hajime; Browell, Edward V.; Oltmans, Samuel J.

2003-11-01

Two closely related chemical transport models (CTMs) employing the same high-resolution meteorological data (˜180 km × ˜180 km × ˜600 m) from the European Centre for Medium-Range Weather Forecasts are used to simulate the ozone total column and tropospheric distribution over the western Pacific region that was explored by the NASA Transport and Chemical Evolution over the Pacific (TRACE-P) measurement campaign in February-April 2001. We make extensive comparisons with ozone measurements from the lidar instrument on the NASA DC-8, with ozonesondes taken during the period around the Pacific Rim, and with TOMS total column ozone. These demonstrate that within the uncertainties of the meteorological data and the constraints of model resolution, the two CTMs (FRSGC/UCI and Oslo CTM2) can simulate the observed tropospheric ozone and do particularly well when realistic stratospheric ozone photochemistry is included. The greatest differences between the models and observations occur in the polluted boundary layer, where problems related to the simplified chemical mechanism and inadequate horizontal resolution are likely to have caused the net overestimation of about 10 ppb mole fraction. In the upper troposphere, the large variability driven by stratospheric intrusions makes agreement very sensitive to the timing of meteorological features.

The unusual persistence of an ozone hole over a southern mid-latitude station during the Antarctic spring 2009: a multi-instrument study

NASA Astrophysics Data System (ADS)

Wolfram, E. A.; Salvador, J.; Orte, F.; D'Elia, R.; Godin-Beekmann, S.; Kuttippurath, J.; Pazmiño, A.; Goutail, F.; Casiccia, C.; Zamorano, F.; Paes Leme, N.; Quel, E. J.

2012-10-01

Record-low ozone column densities (with a minimum of 212 DU) persisted over three weeks at the Río Gallegos NDACC (Network for the Detection of Atmospheric Composition Change) station (51.5° S, 69.3° W) in November 2009. Total ozone remained two standard deviations below the climatological mean for five consecutive days during this period. The statistical analysis of 30 years of satellite data from the Multi Sensor Reanalysis (MSR) database for Río Gallegos revealed that such a long-lasting low-ozone episode is a rare occurrence. The event is examined using height-resolved ozone lidar measurements at Río Gallegos, and observations from satellite and ground-based instruments. The computed relative difference between the measured total ozone and the climatological monthly mean shows reductions varying between 10 and 30% with an average decrease of 25%. The mean absolute difference of total ozone column with respect to climatological monthly mean ozone column is around 75 DU. Extreme values of the UV index (UVI) were measured at the ground for this period, with the daily maximum UVI of around 13 on 15 and 28 November. The high-resolution MIMOSA-CHIM (Modélisation Isentrope du transport Méso-échelle de l'Ozone Stratosphérique par Advection) model was used to interpret the ozone depletion event. An ozone decrease of about 2 ppmv was observed in mid-November at the 550 K isentropic level (~22 km). The position of Río Gallegos relative to the polar vortex was classified using equivalent latitude maps. During the second week of November, the vortex was over the station at all isentropic levels, but after 20 November and until the end of the month, only the 10 lower levels in the stratosphere were affected by vortex overpasses with ozone poor air masses. A rapid recovery of the ozone column density was observed later, due to an ozone rich filament moving over Río Gallegos between 18 and 24 km in the first two weeks of December 2009.

Ozone and photocatalytic processes to remove the antibiotic sulfamethoxazole from water.

PubMed

Beltrán, Fernando J; Aguinaco, Almudena; García-Araya, Juan F; Oropesa, Ana

2008-08-01

In this study, water containing the pharmaceutical compound sulfamethoxazole (SMT) was subjected to the various treatments of different oxidation processes involving ozonation, and photolysis and catalysis under different experimental conditions. Removal rates of SMT and total organic carbon (TOC), from experiments of simple UVA radiation, ozonation (O(3)), catalytic ozonation (O(3)/TiO(2)), ozone photolysis (O(3)/UVA), photocatalytic oxidation (O(2)/TiO(2)/UVA) and photocatalytic ozonation (O(3)/UVA/TiO(2)), have been compared. Photocatalytic ozonation leads to the highest SMT removal rate (pH 7 in buffered systems, complete removal is achieved in less than 5min) and total organic carbon (in unbuffered systems, with initial pH=4, 93% TOC removal is reached). Also, lowest ozone consumption per TOC removed and toxicity was achieved with the O(3)/UVA/TiO(2) process. Direct ozone and free radical reactions were found to be the principal mechanisms for SMT and TOC removal, respectively. In photocatalytic ozonation, with buffered (pH 7) aqueous solutions phosphates (buffering salts) and accumulation of bicarbonate scavengers inhibit the reactions completely on the TiO(2) surface. As a consequence, TOC removal diminishes. In all cases, hydrogen peroxide plays a key role in TOC mineralization. According to the results obtained in this work the use of photocatalytic ozonation is recommended to achieve a high mineralization degree of water containing SMT type compounds.

Evolution of the eastward shift in the quasi-stationary minimum of the Antarctic total ozone column

NASA Astrophysics Data System (ADS)

Grytsai, Asen; Klekociuk, Andrew; Milinevsky, Gennadi; Evtushevsky, Oleksandr; Stone, Kane

2017-02-01

The quasi-stationary pattern of the Antarctic total ozone has changed during the last 4 decades, showing an eastward shift in the zonal ozone minimum. In this work, the association between the longitudinal shift of the zonal ozone minimum and changes in meteorological fields in austral spring (September-November) for 1979-2014 is analyzed using ERA-Interim and NCEP-NCAR reanalyses. Regressive, correlative and anomaly composite analyses are applied to reanalysis data. Patterns of the Southern Annular Mode and quasi-stationary zonal waves 1 and 3 in the meteorological fields show relationships with interannual variability in the longitude of the zonal ozone minimum. On decadal timescales, consistent longitudinal shifts of the zonal ozone minimum and zonal wave 3 pattern in the middle-troposphere temperature at the southern midlatitudes are shown. Attribution runs of the chemistry-climate version of the Australian Community Climate and Earth System Simulator (ACCESS-CCM) model suggest that long-term shifts of the zonal ozone minimum are separately contributed by changes in ozone-depleting substances and greenhouse gases. As is known, Antarctic ozone depletion in spring is strongly projected on the Southern Annular Mode in summer and impacts summertime surface climate across the Southern Hemisphere. The results of this study suggest that changes in zonal ozone asymmetry accompanying ozone depletion could be associated with regional climate changes in the Southern Hemisphere in spring.

Ozone and the stratosphere

NASA Technical Reports Server (NTRS)

Shimazaki, Tatsuo

1987-01-01

It is shown that the stratospheric ozone is effective in absorbing almost all radiation below 300 nm at heights below 300 km. The distribution of global ozone in the troposphere and the lower stratosphere, and the latitudinal variations of the total ozone column over four seasons are considered. The theory of the ozone layer production is discussed together with catalytic reactions for ozone loss and the mechanisms of ozone transport. Special attention is given to the anthropogenic perturbations, such as SST exhaust gases and freon gas from aerosol cans and refrigerators, that may cause an extensive destruction of the stratospheric ozone layer and thus have a profound impact on the world climate and on life.

Transcriptomic Analysis of Grape (Vitis vinifera L.) Leaves after Exposure to Ultraviolet C Irradiation

PubMed Central

Xi, Huifen; Ma, Ling; Liu, Guotian; Wang, Nian; Wang, Junfang; Wang, Lina; Dai, Zhanwu; Li, Shaohua; Wang, Lijun

2014-01-01

Background Only a small amount of solar ultraviolet C (UV-C) radiation reaches the Earth's surface. This is because of the filtering effects of the stratospheric ozone layer. Artificial UV-C irradiation is used on leaves and fruits to stimulate different biological processes in plants. Grapes are a major fruit crop and are grown in many parts of the world. Research has shown that UV-C irradiation induces the biosynthesis of phenols in grape leaves. However, few studies have analyzed the overall changes in gene expression in grape leaves exposed to UV-C. Methodology/Principal Findings In the present study, transcriptional responses were investigated in grape (Vitis vinifera L.) leaves before and after exposure to UV-C irradiation (6 W·m−2 for 10 min) using an Affymetrix Vitis vinifera (Grape) Genome Array (15,700 transcripts). A total of 5274 differentially expressed probe sets were defined, including 3564 (67.58%) probe sets that appeared at both 6 and 12 h after exposure to UV-C irradiation but not before exposure. A total of 468 (8.87%) probe sets and 1242 (23.55%) probe sets were specifically expressed at these times. The probe sets were associated with a large number of important traits and biological pathways, including cell rescue (i.e., antioxidant enzymes), protein fate (i.e., HSPs), primary and secondary metabolism, and transcription factors. Interestingly, some of the genes involved in secondary metabolism, such as stilbene synthase, responded intensely to irradiation. Some of the MYB and WRKY family transcription factors, such as VvMYBPA1, VvMYB14, VvMYB4, WRKY57-like, and WRKY 65, were also strongly up-regulated (about 100 to 200 fold). Conclusions UV-C irridiation has an important role in some biology processes, especially cell rescue, protein fate, secondary metabolism, and regulation of transcription.These results opened up ways of exploring the molecular mechanisms underlying the effects of UV-C irradiation on grape leaves and have great implications for further studies. PMID:25464056

Transcriptomic analysis of grape (Vitis vinifera L.) leaves after exposure to ultraviolet C irradiation.

PubMed

Xi, Huifen; Ma, Ling; Liu, Guotian; Wang, Nian; Wang, Junfang; Wang, Lina; Dai, Zhanwu; Li, Shaohua; Wang, Lijun

2014-01-01

Only a small amount of solar ultraviolet C (UV-C) radiation reaches the Earth's surface. This is because of the filtering effects of the stratospheric ozone layer. Artificial UV-C irradiation is used on leaves and fruits to stimulate different biological processes in plants. Grapes are a major fruit crop and are grown in many parts of the world. Research has shown that UV-C irradiation induces the biosynthesis of phenols in grape leaves. However, few studies have analyzed the overall changes in gene expression in grape leaves exposed to UV-C. In the present study, transcriptional responses were investigated in grape (Vitis vinifera L.) leaves before and after exposure to UV-C irradiation (6 W·m-2 for 10 min) using an Affymetrix Vitis vinifera (Grape) Genome Array (15,700 transcripts). A total of 5274 differentially expressed probe sets were defined, including 3564 (67.58%) probe sets that appeared at both 6 and 12 h after exposure to UV-C irradiation but not before exposure. A total of 468 (8.87%) probe sets and 1242 (23.55%) probe sets were specifically expressed at these times. The probe sets were associated with a large number of important traits and biological pathways, including cell rescue (i.e., antioxidant enzymes), protein fate (i.e., HSPs), primary and secondary metabolism, and transcription factors. Interestingly, some of the genes involved in secondary metabolism, such as stilbene synthase, responded intensely to irradiation. Some of the MYB and WRKY family transcription factors, such as VvMYBPA1, VvMYB14, VvMYB4, WRKY57-like, and WRKY 65, were also strongly up-regulated (about 100 to 200 fold). UV-C irridiation has an important role in some biology processes, especially cell rescue, protein fate, secondary metabolism, and regulation of transcription.These results opened up ways of exploring the molecular mechanisms underlying the effects of UV-C irradiation on grape leaves and have great implications for further studies.

Control of the red tide dinoflagellate Cochlodinium polykrikoides by ozone in seawater.

PubMed

Shin, Minjung; Lee, Hye-Jin; Kim, Min Sik; Park, Noh-Back; Lee, Changha

2017-02-01

The inactivation of C. polykrikoides, a red tide dinoflagellate, by ozonation was investigated in seawater by monitoring numbers of viable and total cells. Parameters affecting the inactivation efficacy of C. polykrikoides such as the ozone dose, initial cell concentration, pH, and temperature were examined. The viable cell number rapidly decreased in the initial stage of the reaction (mostly in 1-2 min), whereas the decrease in total cell number was relatively slow and steady. Increasing ozone dose and decreasing initial cell concentration increased the inactivation efficacy of C. polykrikoides, while increasing pH and temperature decreased the cell inactivation efficacy. The addition of humic acid (a promoter for the ozone decomposition) inhibited the inactivation of C. polykrikoides, whereas bicarbonate ion (an inhibitor for the ozone decomposition) accelerated the C. polykrikoides inactivation. Observations regarding the effects of pH, temperature, humic acid, and bicarbonate ion collectively indicate that the inactivation of C. polykrikoides by ozonation is mainly attributed to oxidative cell damages by molecular ozone, rather than by hydroxyl radical, produced during the ozone decomposition. At high ozone dose (e.g., 5 mg/L), hypobromous acid formed by the reaction of bromide with ozone may partially contribute to cell inactivation. The use of ozone of less than 1 mg/L produced 0.75-2.03 μg/L bromate. Copyright © 2016 Elsevier Ltd. All rights reserved.

Acute effect of ozone exposure on daily mortality in seven cities of Jiangsu Province, China: No clear evidence for threshold.

PubMed

Chen, Kai; Zhou, Lian; Chen, Xiaodong; Bi, Jun; Kinney, Patrick L

2017-05-01

Few multicity studies have addressed the health effects of ozone in China due to the scarcity of ozone monitoring data. A critical scientific and policy-relevant question is whether a threshold exists in the ozone-mortality relationship. Using a generalized additive model and a univariate random-effects meta-analysis, this research evaluated the relationship between short-term ozone exposure and daily total mortality in seven cities of Jiangsu Province, China during 2013-2014. Spline, subset, and threshold models were applied to further evaluate whether a safe threshold level exists. This study found strong evidence that short-term ozone exposure is significantly associated with premature total mortality. A 10μg/m 3 increase in the average of the current and previous days' maximum 8-h average ozone concentration was associated with a 0.55% (95% posterior interval: 0.34%, 0.76%) increase of total mortality. This finding is robust when considering the confounding effect of PM 2.5 , PM 10 , NO 2 , and SO 2 . No consistent evidence was found for a threshold in the ozone-mortality concentration-response relationship down to concentrations well below the current Chinese Ambient Air Quality Standard (CAAQS) level 2 standard (160μg/m 3 ). Our findings suggest that ozone concentrations below the current CAAQS level 2 standard could still induce increased mortality risks in Jiangsu Province, China. Continuous air pollution control measures could yield important health benefits in Jiangsu Province, China, even in cities that meet the current CAAQS level 2 standard. Copyright © 2017 Elsevier Inc. All rights reserved.

Acute effect of ozone exposure on daily mortality in seven cities of Jiangsu Province, China: No clear evidence for threshold

PubMed Central

Chen, Kai; Zhou, Lian; Chen, Xiaodong; Bi, Jun; Kinney, Patrick L.

2017-01-01

Background Few multicity studies have addressed the health effects of ozone in China due to the scarcity of ozone monitoring data. A critical scientific and policy-relevant question is whether a threshold exists in the ozone-mortality relationship. Methods Using a generalized additive model and a univariate random-effects meta-analysis, this research evaluated the relationship between short-term ozone exposure and daily total mortality in seven cities of Jiangsu Province, China during 2013–2014. Spline, subset, and threshold models were applied to further evaluate whether a safe threshold level exists. Results This study found strong evidence that short-term ozone exposure is significantly associated with premature total mortality. A 10 μg/m3 increase in the average of the current and previous days’ maximum 8-h average ozone concentration was associated with a 0.55% (95% posterior interval: 0.34%, 0.76%) increase of total mortality. This finding is robust when considering the confounding effect of PM2.5, PM10, NO2, and SO2. No consistent evidence was found for a threshold in the ozone-mortality concentration-response relationship down to concentrations well below the current Chinese Ambient Air Quality Standard (CAAQS) level 2 standard (160 μg/m3). Conclusions Our findings suggest that ozone concentrations below the current CAAQS level 2 standard could still induce increased mortality risks in Jiangsu Province, China. Continuous air pollution control measures could yield important health benefits in Jiangsu Province, China, even in cities that meet the current CAAQS level 2 standard. PMID:28231551

Impact of asymmetry in the total ozone distribution in Antarctic region to the South Ocean ecosystem

NASA Astrophysics Data System (ADS)

Kovalenok, S.; Evtushevsky, A.; Grytsai, A.; Milinevsky, G.

2009-04-01

Impact of asymmetry in the total ozone distribution in Antarctic region to South Ocean ecosystem is studied. The existence of the considerable zonal asymmetry in total ozone distribution over Antarctica observed last decades based on the satellite TOMS measurements in 1979-2005 due to existence of quasi-stationary planetary waves in a polar stratosphere. As was shown by authors earlier in the latitudinal interval of 55-75°S in Antarctic spring months (Sep-Nov) the region of zonal total ozone minimum experienced the systematic spatial drift to the east. In the same period a minimum and maximum of quasi-stationary wave in TOC distribution are located: minimum over the Antarctic Peninsula and Weddell Sea area, and maximum in the Ross Sea area. We expect that zonal asymmetry in total ozone distribution and its long-term spatial changes should impact to South Ocean ecosystem food chain, especially in primary level. The systematic eastern shift of the quasi-stationary minimum in ozone distribution over north Weddell Sea area should cause the increased UV radiation on sea surface in comparison to Ross Sea area, where the lack of UVR should exist in spring month. To study this influence the available data of phytoplankton distribution in South Ocean in 1997-2007 were analyzed. The results of analysis in connections with Antarctic Peninsula regional climate warming are discussed. The research was partly supported by project 06BF051-12 of the National Taras Shevchenko University of Kyiv.

Derivation of Tropospheric Ozone Climatology and Trends from TOMS Data

NASA Technical Reports Server (NTRS)

Newchurch, Michael J.; McPeters, Rich; Logan, Jennifer; Kim, Jae-Hwan

2002-01-01

This research addresses the following three objectives: (1) Derive tropospheric ozone columns from the TOMS instruments by computing the difference between total-ozone columns over cloudy areas and over clear areas in the tropics; (2) Compute secular trends in Nimbus-7 derived tropospheric Ozone column amounts and associated potential trends in the decadal-scale tropical cloud climatology; (3) Explain the occurrence of anomalously high ozone retrievals over high ice clouds.

Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lushington, Andrew; Liu, Jian; Tang, Yongji

The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10 wt. % ozone at temperatures of 150, 250, and 300 °C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTsmore » was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.« less

Discoveries about Tropical Tropospheric Ozone from Satellite and SHADOZ (Southern Hemisphere Additional Ozonesondes) and a Future Perspective on NASA's Ozone Sensors

NASA Technical Reports Server (NTRS)

Thompson, Anne

2003-01-01

We have been producing near-real tropical tropospheric ozone ('TTO') data from TOMS since 1997 with Prof. Hudson and students at the University of Maryland. Maps for 1996-2000 for the operational Earth-Probe instrument reside at: . We also have archived 'TTO' data from the Nimbus 7/TOMS satellite (1979-1992). The tropics is a region strongly influenced by natural variability and anthropogenic activity and the satellite data have been used to track biomass burning pollution and to detect interannual variability and climate signals in ozone. We look forward to future ozone sensors from NASA; four will be launched in 2004 as part of the EOS AURA Mission. The satellite view of chemical-dynamical interactions in tropospheric ozone is not adequate to capture vertical variability. Thus, in 1998, NASA's Goddard Space Flight Center, NOAA's Climate Monitoring and Diagnostics Laboratory (CMDL) and a team of international sponsors established the SHADOZ (Southern Hemisphere ADditional OZonesondes) project to address the gap in tropical ozone soundings. SHADOZ augments launches at selected sites and provides a public archive of ozonesonde data from twelve tropical and subtropical stations at http://croc.nsfc.nasa.gov/shadoz. The stations are: Ascension Island; Nairobi, Kenya; Irene, South Africa; R,union Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil, Malindi, Kenya; Paramaribo, Surinam. From the first 3-4 years of data (presently greater than 1700 sondes), the following features emerge: (a) highly variable tropospheric ozone; (b) a zonal wave-one pattern in tropospheric column ozone; (c) tropospheric ozone variability over the Indian and Pacific Ocean displays strong convective signatures.

Chemical Data Assimilation Estimates of Continental US Ozone and Nitrogen Budgets during INTEX-A

NASA Technical Reports Server (NTRS)

Pierce, Robert B.; Schaack, Todd K.; Al-Saadi, Jassim A.; Fairlie, T. Duncan; Kittaka, Chieko; Lingenfelser, Gretchen; Natarajan, Murali; Olson, Jennifer; Soja, Amber; Zapotocny, Tom;

Bromide's effect on DBP formation, speciation, and control; Part 1: Ozonation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shukairy, H.M.; Summers, R.S.; Miltner, R.J.

1994-06-01

The effect of variable ozone dosage and bromide concentration on the formation of organic disinfection by-products (DBPs) and bromate were evaluated. Low ozone dosages resulted in oxidation of organic precursors, yielding decreases in the formation potential for total trihalomethanes (THMs), six haloacetic acids (HAAs), and total organic halide (TOX). Increasing the ozone dosage oxidized bromide to bromate, decreasing the bromide for incorporation into DBPs. Bromate concentrations were linearly correlated with ozone residuals. Changes in the bromine incorporation factors n and n[prime] reflected differences in the resulting speciation of THMs and HAAs, respectively. Because TOX measurements based on chloride equivalence maymore » underestimate the halogenated DBP yield for high-bromide waters, a procedure is described whereby bromide and bromate concentrations were used to correct the TOX measurement.« less

UV controlling factors and trends derived from the ground-based measurements taken at Belsk, Poland, 1976-1994

NASA Astrophysics Data System (ADS)

KrzyśCin, Janusz W.

1996-07-01

Monthly means of UV erythemal dose at ground level from the Robertson-Berger (RB) sunburn meter (1976-1992) and the UV-Biometer model 501 MED meter (1993-1994) located at Belsk (21°E, 52°N), Poland, are examined. The monthly means are calculated from all-sky daily means of UV erythemal dose. Ancillary measurements of column ozone (by Dobson spectrophotometer), sunshine duration (by Campbell-Stokes heliograph), and total (sun and sky) radiation (by a pyranometer) are considered to explain variations in the UV data. A multiple regression model is proposed to study trends in the UV data. The model accounts for the UV erythemal dose changes induced by total ozone, sunshine duration (surrogate for cloud cover variations), or total solar radiation (surrogate for combined cloud cover and atmospheric turbidity impact on the UV radiation), trends due to instrument drift, step changes in the data, and serial correlations. A strong relationship between monthly all-sky UV erythemal dose changes and total ozone (and total solar radiation) is found. Calculations show that an erythemal radiative amplification factor (RAF) due to ozone under all skies is close to its clear-sky value (about 1). However, the model gives evidence that the RAF due to ozone is smaller for cloudier (and/or more turbid) atmospheres than long-term reference. Total solar radiation change of 1% is associated with a change of 0.7% in the UV erythemal dose. Modeled trends in the Belsk's UV data, inferred from the model using ozone and total solar radiation as the UV forcing factors, are 2.3% ± 0.4% (1σ) per decade in the period 1976-1994. The large increase in the UV erythemal dose, of the order of 4% per decade due to ozone depletion (-3.2% per decade), is partially compensated by a decreasing tendency (-2.8% per decade) in total solar radiation. The model estimates the trend in the UV data of the order of 0.1% per decade (not statistically significant) due to superposition of the instrument drift and long-term effects related to other UV influencing factors (not parameterized by the model).

Improvement of the basic knowledge of the climatology of the vertical ozone layer by enhanced balloon sounding

NASA Technical Reports Server (NTRS)

Attmannspacher, W.; Hartmannsgrubber, R.; Lang, P.

1984-01-01

Balloon sounding of the ozone in the Earth atmosphere was performed in order to determine the natural behavior of ozone and its recognizable deviations. The importance of ozone in the Earth atmosphere and the orographic situation of observatories and ozone sounding statistics since 1966 are explained. The physical processes governing the total amount of ozone, and the behavior of stratospheric ozone are described. Measurements in the upper stratosphere show a decrease of the ozone partial pressure above 26 km altitude since 1977. The behavior of tropospheric ozone is discussed. Data since 1977 show increasing ozone values in the troposphere, up to 50% to 70%. This increase is independent of the solar radiation intensity and the reinforced transport of stratospheric ozone into the troposphere. The increase in the troposphere cannot compensate the stratospheric decrease.

Adrenal-derived stress hormones modulate ozone-induced lung injury and inflammation

EPA Science Inventory

Ozone-induced systemic effects are modulated through activation of the neuro-hormonal stress response pathway. Adrenal demedullation (DEMED)or bilateral total adrenalectomy (ADREX) inhibits systemic and pulmonary effect of acute ozone exposure. To understand the influence of adre...

Extended and refined multi sensor reanalysis of total ozone for the period 1970-2012

NASA Astrophysics Data System (ADS)

van der A, R. J.; Allaart, M. A. F.; Eskes, H. J.

2015-07-01

The ozone multi-sensor reanalysis (MSR) is a multi-decadal ozone column data record constructed using all available ozone column satellite data sets, surface Brewer and Dobson observations and a data assimilation technique with detailed error modelling. The result is a high-resolution time series of 6-hourly global ozone column fields and forecast error fields that may be used for ozone trend analyses as well as detailed case studies. The ozone MSR is produced in two steps. First, the latest reprocessed versions of all available ozone column satellite data sets are collected and then are corrected for biases as a function of solar zenith angle (SZA), viewing zenith angle (VZA), time (trend), and stratospheric temperature using surface observations of the ozone column from Brewer and Dobson spectrophotometers from the World Ozone and Ultraviolet Radiation Data Centre (WOUDC). Subsequently the de-biased satellite observations are assimilated within the ozone chemistry and data assimilation model TMDAM. The MSR2 (MSR version 2) reanalysis upgrade described in this paper consists of an ozone record for the 43-year period 1970-2012. The chemistry transport model and data assimilation system have been adapted to improve the resolution, error modelling and processing speed. Backscatter ultraviolet (BUV) satellite observations have been included for the period 1970-1977. The total record is extended by 13 years compared to the first version of the ozone multi sensor reanalysis, the MSR1. The latest total ozone retrievals of 15 satellite instruments are used: BUV-Nimbus4, TOMS-Nimbus7, TOMS-EP, SBUV-7, -9, -11, -14, -16, -17, -18, -19, GOME, SCIAMACHY, OMI and GOME-2. The resolution of the model runs, assimilation and output is increased from 2° × 3° to 1° × 1°. The analysis is driven by 3-hourly meteorology from the ERA-Interim reanalysis of the European Centre for Medium-Range Weather Forecasts (ECMWF) starting from 1979, and ERA-40 before that date. The chemistry parameterization has been updated. The performance of the MSR2 analysis is studied with the help of observation-minus-forecast (OmF) departures from the data assimilation, by comparisons with the individual station observations and with ozone sondes. The OmF statistics show that the mean bias of the MSR2 analyses is less than 1 % with respect to de-biased satellite observations after 1979.

SHADOZ (Southern Hemisphere Additional Ozonesondes): A Project Overview and New Insights on Tropical Tropospheric Ozone

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Witte, Jacquelyn C.; Oltmans, S. J.; Schmidlin, F. J.

2004-01-01

The SHADOZ (Southern Hemisphere Additional Ozonesondes) ozone sounding network was initiated in 1998 to improve the coverage of tropical in-situ ozone measurements for satellite validation, algorithm development and related process studies. Over 2000 soundings have been archived at the website, http://croc.gsfc.nasa.gov/shadoz, for 12 stations: Ascension Island; Nairobi and Malindi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil; Paramaribo, Surinam. Key results from SHADOZ will be described from among the following: 1) By using ECC sondes with similar procedures, 5-10% accuracy and precision (1-sigma) of the sonde total ozone measurement is achieved; 2) Week-to-week variability in tropospheric ozone is so great that statistics are frequently not Gaussian; most stations vary up to a factor of 3 in tropospheric column over the course of a year; 3) Longitudinal variability in tropospheric ozone profiles is a consistent feature, with a 10-15 DU column-integrated difference between Atlantic and Pacific sites; this causes a "zonal wave-one" feature in total ozone; 4) The ozone record from Paramaribo, Surinam (6N, 55W) is a marked contrast to southern tropical ozone because Surinam is often north of the Intertropical Convergence Zone.

Ground-based intercomparisons of SBUV/2 flight instruments the world standard Dobson spectrophotometer 83 and overpass observations from Nimbus-7 TOMS and NOAA-11 SBUV/2

NASA Technical Reports Server (NTRS)

Heath, D. F.; Ahmad, Z.; Torres, O.; Evans, R. D.; Grass, R. D.; Komhyr, W. A.; Nelson, W.

1994-01-01

Total ozone data obtained during summers at Mauna Loa Observatory, Hawaii, with Dobson Spectrophotometer 83 are routinely compared with overpass total ozone data from the Total Ozone Mapping Spectrometer (TOMS) and the Solar Backscatter Ultraviolet (SBUV) spectrometer launched aboard the Nimbus 7 satellite in 1978. Results from the TOMS/Dobson instrument comparisons through 1990 have been presented by McPeters and Komhyr (1991). Dobson spectrophotometer 83 was established as the standard instrument for the U.S.A. Dobson instrument station network in 1962. In 1980, the instrument was designated by the World Meteorological Organization (WMO) as the Standard Dobson Spectrophotometer for the World. Long-term ozone measurement precision of the instrument has been maintained at plus or minus 0.5 percent (Komhyr et al., 1989). On an absolute scale, the ozone measurement accuracy of the instrument is estimated to plus or minus 3 percent. In early April, 1990, comparison of total ozone and vertical distribution (Umkehr) observations were made for the first time with Dobson spectrophotometer 8.3. The work was conducted at the NOAA Climate Monitoring and Diagnostics Laboratory (CMDL) in Boulder, Colorado, and at the research and instrument manufacturing facility of the Ball Aerospace System Division located about 2 km east of Boulder. (The SBUV-2 S/N-2 instrument, built by Ball Aerospace Systems Division, is scheduled for launch aboard the NOAA-13 satellite). We present results of the comparisons which include ozone vertical distribution data obtained with a balloon-borne electrochemical concentration cell (ECC) ozonesonde (Komhyr, 1969).

The GEOS Ozone Data Assimilation System: Specification of Error Statistics

NASA Technical Reports Server (NTRS)

Stajner, Ivanka; Riishojgaard, Lars Peter; Rood, Richard B.

2000-01-01

A global three-dimensional ozone data assimilation system has been developed at the Data Assimilation Office of the NASA/Goddard Space Flight Center. The Total Ozone Mapping Spectrometer (TOMS) total ozone and the Solar Backscatter Ultraviolet (SBUV) or (SBUV/2) partial ozone profile observations are assimilated. The assimilation, into an off-line ozone transport model, is done using the global Physical-space Statistical Analysis Scheme (PSAS). This system became operational in December 1999. A detailed description of the statistical analysis scheme, and in particular, the forecast and observation error covariance models is given. A new global anisotropic horizontal forecast error correlation model accounts for a varying distribution of observations with latitude. Correlations are largest in the zonal direction in the tropics where data is sparse. Forecast error variance model is proportional to the ozone field. The forecast error covariance parameters were determined by maximum likelihood estimation. The error covariance models are validated using x squared statistics. The analyzed ozone fields in the winter 1992 are validated against independent observations from ozone sondes and HALOE. There is better than 10% agreement between mean Halogen Occultation Experiment (HALOE) and analysis fields between 70 and 0.2 hPa. The global root-mean-square (RMS) difference between TOMS observed and forecast values is less than 4%. The global RMS difference between SBUV observed and analyzed ozone between 50 and 3 hPa is less than 15%.

Demonstration of AIRS Total Ozone Products to Operations to Enhance User Readiness

NASA Technical Reports Server (NTRS)

Berndt, Emily; Zavodsky, Bradley; Jedlovec, Gary

2014-01-01

Cyclogenesis is a key forecast challenge at operational forecasting centers such as WPC and OPC, so these centers have a particular interest in unique products that can identify key storm features. In some cases, explosively developing extratropical cyclones can produce hurricane force, non-convective winds along the East Coast and north Atlantic as well as the Pacific Ocean, with the potential to cause significant damage to life and property. Therefore, anticipating cyclogenesis for these types of storms is crucial for furthering the NOAA goal of a "Weather Ready Nation". Over the last few years, multispectral imagery (i.e. RGB) products have gained popularity among forecasters. The GOES-R satellite champion at WPC/OPC has regularly evaluated the Air Mass RGB products from GOES Sounder, MODIS, and SEVIRI to aid in forecasting cyclogenesis as part of ongoing collaborations with SPoRT within the framework of the GOES-R Proving Ground. WPC/OPC has used these products to identify regions of stratospheric air associated with tropopause folds that can lead to cyclogenesis and hurricane force winds. RGB products combine multiple channels or channel differences into multi-color imagery in which different colors represent a particular cloud or air mass type. Initial interaction and feedback from forecasters evaluating the legacy Air Mass RGBs revealed some uncertainty regarding what physical processes the qualitative RGB products represent and color interpretation. To enhance forecaster confidence and interpretation of the Air Mass RGB, NASA SPoRT has transitioned a total column ozone product from AIRS retrievals to the WPC/OPC. The use of legacy AIRS demonstrates future JPSS capabilities possible with CrIS or OMPS. Since stratospheric air can be identified by anomalous potential vorticity and warm, dry, ozone-rich air, hyperspectral infrared sounder ozone products can be used in conjunction with the Air Mass RGB for identifying the role of stratospheric air in explosive cyclogenesis and hurricane force wind events. Currently, forecasters at WPC/OPC are evaluating the Air Mass RGB imagery in conjunction with the AIRS total column ozone to aid forecasting cyclogenesis and high wind forecasts. One of the limitations of the total ozone product is that it is difficult for forecasters to determine whether elevated ozone concentrations are related to stratospheric air or climatologically high values of ozone in certain regions. To address this limitation, SPoRT created an AIRS ozone anomaly product which calculates the percent of normal ozone based on a global stratospheric ozone mean climatology. With the knowledge that ozone values 125 percent of normal and greater typically represent stratospheric air; the anomaly product can be used with the total column ozone product to confirm regions of stratospheric air on the Air Mass RGB. This presentation describes the generation of these products along with forecaster feedback concerning the use of the AIRS ozone products in conjunction with the Air Mass RGB product for the unique forecast challenges WPC/OPC face. Additionally examples of CrIS ozone and anomaly products will be shown to further demonstrate the utility and capability of JPSS in forecasting unique events.

BROMIDE'S EFFECT ON DBP FORMATION, SPECIATION, AND CONTROL: PART 1, OZONATION

EPA Science Inventory

The effect of variable ozone dosage and bromide concentration on the formation of organic disinfection byproducts (DBPs) and bromate were evaluated. Low ozone dosages resulted in oxidation of organic precursors, yielding decreases in the formation potential for total trihalometha...

Effect of Gaseous Ozone Exposure on the Bacteria Counts and Oxidative Properties of Ground Hanwoo Beef at Refrigeration Temperature.

PubMed

Cho, Youngjae; Muhlisin; Choi, Ji Hye; Hahn, Tae-Wook; Lee, Sung Ki

2014-01-01

This study was designed to elucidate the effect of ozone exposure on the bacteria counts and oxidative properties of ground Hanwoo beef contaminated with Escherichia coli O157:H7 at refrigeration temperature. Ground beef was inoculated with 7 Log CFU/g of E. coli O157:H7 isolated from domestic pigs and was then subjected to ozone exposure (10×10(-6) kg O3 h(-1)) at 4℃ for 3 d. E. coli O157:H7, total aerobic and anaerobic bacterial growth and oxidative properties including instrumental color changes, TBARS, catalase (CAT) and glutathione peroxidase (GPx) activity were evaluated. Ozone exposure significantly prohibited (p<0.05) the growths of E. coli O157:H7, total aerobic and anaerobic bacteria in ground beef samples during storage. Ozone exposure reduced (p<0.05) the CIE a* value of samples over storage time. The CIE L* and CIE b* values of the samples fluctuated over storage time, and ozone had no clear effect. Ozone exposure increased the TBARS values during 1 to 3 d of storage (p<0.05). The CAT and GPx enzyme activities were not affected by ozone exposure until 2 and 3 d of storage, respectively. This study provides information about the use of ozone exposure as an antimicrobial agent for meat under refrigerated storage. The results of this study provide a foundation for the further application of ozone exposure by integrating an ozone generator inside a refrigerator. Further studies regarding the ozone concentrations and exposure times are needed.

Removal of total and antibiotic resistant bacteria in advanced wastewater treatment by ozonation in combination with different filtering techniques.

PubMed

Lüddeke, Frauke; Heß, Stefanie; Gallert, Claudia; Winter, Josef; Güde, Hans; Löffler, Herbert

2015-02-01

Elimination of bacteria by ozonation in combination with charcoal or slow sand filtration for advanced sewage treatment to improve the quality of treated sewage and to reduce the potential risk for human health of receiving surface waters was investigated in pilot scale at the sewage treatment plant Eriskirch, Baden-Wuerttemberg/Germany. To determine the elimination of sewage bacteria, inflowing and leaving wastewater of different treatment processes was analysed in a culture-based approach for its content of Escherichia coli, enterococci and staphylococci and their resistance against selected antibiotics over a period of 17 month. For enterococci, single species and their antibiotic resistances were identified. In comparison to the established flocculation filtration at Eriskirch, ozonation plus charcoal or sand filtration (pilot-scale) reduced the concentrations of total and antibiotic resistant E. coli, enterococci and staphylococci. However, antibiotic resistant E. coli and staphylococci apparently survived ozone treatment better than antibiotic sensitive strains. Neither vancomycin resistant enterococci nor methicillin resistant Staphylococcus aureus (MRSA) were detected. The decreased percentage of antibiotic resistant enterococci after ozonation may be explained by a different ozone sensitivity of species: Enterococcus faecium and Enterococcus faecalis, which determined the resistance-level, seemed to be more sensitive for ozone than other Enterococcus-species. Overall, ozonation followed by charcoal or sand filtration led to 0.8-1.1 log-units less total and antibiotic resistant E. coli, enterococci and staphylococci, as compared to the respective concentrations in treated sewage by only flocculation filtration. Thus, advanced wastewater treatment by ozonation plus charcoal or sand filtration after common sewage treatment is an effective tool for further elimination of microorganisms from sewage before discharge in surface waters. Copyright © 2014 Elsevier Ltd. All rights reserved.

Treatment of raw and ozonated oil sands process-affected water under decoupled denitrifying anoxic and nitrifying aerobic conditions: a comparative study.

PubMed

Xue, Jinkai; Zhang, Yanyan; Liu, Yang; Gamal El-Din, Mohamed

2016-11-01

Batch experiments were performed to evaluate biodegradation of raw and ozonated oil sands process-affected water (OSPW) under denitrifying anoxic and nitrifying aerobic conditions for 33 days. The results showed both the anoxic and aerobic conditions are effective in degrading OSPW classical and oxidized naphthenic acids (NAs) with the aerobic conditions demonstrating higher removal efficiency. The reactors under nitrifying aerobic condition reduced the total classical NAs of raw OSPW by 69.1 %, with better efficiency for species of higher hydrophobicity. Compared with conventional aerobic reactor, nitrifying aerobic condition substantially shortened the NA degradation half-life to 16 days. The mild-dose ozonation remarkably accelerated the subsequent aerobic biodegradation of classical NAs within the first 14 days, especially for those with long carbon chains. Moreover, the ozone pretreatment enhanced the biological removal of OSPW classical NAs by leaving a considerably lower final residual concentration of 10.4 mg/L under anoxic conditions, and 5.7 mg/L under aerobic conditions. The combination of ozonation and nitrifying aerobic biodegradation removed total classical NAs by 76.5 % and total oxy-NAs (O3-O6) by 23.6 %. 454 Pyrosequencing revealed that microbial species capable of degrading recalcitrant hydrocarbons were dominant in all reactors. The most abundant genus in the raw and ozonated anoxic reactors was Thauera (~56 % in the raw OSPW anoxic reactor, and ~65 % in the ozonated OSPW anoxic reactor); whereas Rhodanobacter (~40 %) and Pseudomonas (~40 %) dominated the raw and ozonated aerobic reactors, respectively. Therefore, the combination of mild-dose ozone pretreatment and subsequent biological process could be a competent choice for OSPW treatment.

Long-term erythemal UV doses at Sodankylä estimated using total ozone, sunshine duration, and snow depth

NASA Astrophysics Data System (ADS)

Lindfors, A. V.; Arola, A.; Kaurola, J.; Taalas, P.; SvenøE, T.

2003-08-01

A method for estimating daily erythemal UV doses using total ozone, sunshine duration, and snow depth has been developed. The method consists of three steps: (1) daily clear-sky UV doses were simulated using the UVSPEC radiative transfer program, with daily values of total ozone as input data, (2) an empirical relationship was sought between the simulated clear-sky UV doses, the measured UV doses, and the duration of bright sunshine, and (3) daily erythemal UV doses were estimated using this relationship. The method accounts for the varying surface albedo by dividing the period of interest into winter and summer days, depending on the snow depth. Using this method, the daily erythemal UV doses at Sodankylä were estimated for the period 1950-1999. This was done using Tromsø's total ozone together with Sodankylä's own sunshine duration and snow depth as input data. Although the method is fairly simple, the results are in good agreement, even on the daily scale, with the UV radiation measured with the Brewer spectrophotometer at Sodankylä. Over the period 1950-1999 a statistically significant increasing trend of 3.9% per decade in erythemal UV doses was found for March. The fact that this trend is much more pronounced during the latter part of the period, which is also the case for April, suggests a connection to the stratospheric ozone depletion. For July, on the other hand, a significant decreasing trend of 3.3% per decade, supported by the changes in both total ozone and sunshine duration, was found.

Long-term erythemal UV doses at Sodankylä estimated using total ozone, sunshine duration and snow depth

NASA Astrophysics Data System (ADS)

Lindfors, A. V.; Arola, A.; Kaurola, J.; Taalas, P.; Svenøe, T.

2003-04-01

A method for estimating daily erythemal UV doses using total ozone, sunshine duration and snow depth has been developed. The method consists of three steps: (1) daily clear-sky UV doses were simulated using the UVSPEC radiative transfer program, with daily values of total ozone as input data, (2) an empirical relationship was sought between the simulated clear-sky UV doses, the measured UV doses and the duration of bright sunshine, (3) daily erythemal UV doses were estimated using this relationship. The method accounts for the varying surface albedo by dividing the period of interest into winter and summer days, depending on the snow depth. Using this method, the daily erythemal UV doses at Sodankylä were estimated for the period 1950--99. This was done using Tromsø's total ozone together with Sodankylä's own sunshine duration and snow depth as input data. Although the method is fairly simple, the results are in good agreement, even on the daily scale, with the UV radiation measured with the Brewer spectrophotometer at Sodankylä. Statistically significant increasing trends in erythemal UV doses of a few percents per decade over the period 1950--99 were found for March and April, suggesting a connection to the stratospheric ozone depletion. For July, on the other hand, a significant decreasing trend of about 3% per decade, supported by the changes in both total ozone and sunshine duration, was found. The produced data set of erythemal UV doses is the longest time series of estimated UV known to the authors.

Northern hemisphere total ozone values from 1989-1993 determined with the NOAA-11 Solar Backscatter Ultraviolet (SBUV/2) instrument

NASA Technical Reports Server (NTRS)

Planet, W. G.; Lienesch, J. H.; Miller, A. J.; Nagatani, R.; Mcpeters, R. D.; Hilsenrath, E.; Cebula, R. P.; Deland, M. T.; Wellemeyer, C. G.; Horvath, K.

1994-01-01

Determinations of global total ozone amounts have been made from recently reprocessed measurements with the SBUV/2 on the NOAA-11 environmental satellite since January 1989. This data set employs a new algorithm and an updated calibration. Comparisons with total ozone amounts derived from a significant subset of the global network of Dobson spectrophotometers shows a 0.3% bias between the satellite and ground measurements for the period January 1989-May 1993. Comparisons with the data from individual stations exhibit differing degrees of agreement which could be due to the matchup procedures and also to the uncertainties in the Dobson data. The SBUV/2 data set discussed here traces the Northern Hemisphere total ozone from 1989 to the present, showing a marked decrease from the average of those years starting in the summer of 1992 and continuing into 1993, with an apparent returning to more normal levels in late 1993.

Interrelation of changes in the total content of ozone in the northern hemisphere with the velocity of the stratosphere circumpolar vortex

NASA Astrophysics Data System (ADS)

Kolyada, Maria N.; Kashkin, Valentin B.

2004-12-01

Considering the high significance of the ozone for preservation and maintenance of the biosphere and the temperature balance of the atmosphere the investigation of the ozone layer is a very important part of the investigation of the planet"s atmosphere. In this work results of investigations of TOC variability in the Northern Hemisphere and the influence of variability of the circumpolar vortex rotation velocity on the ozone layer are presented. Mean values of total ozone concentration in the Northern Hemisphere (by satellite data) and rotation velocities of the circumpolar vortex are calculated for each month from February to April during 1998-2004. Also in this work the mechanism of the influence of the natural factors on TOC variability solar activity during the spring is suggested.

The roles of ozone and zeolite on reactive dye degradation in electrical discharge reactors.

PubMed

Peternel, L; Kusic, H; Koprivanac, N; Locke, B R

2006-05-01

In this study high voltage pulsed corona electrical discharge advanced oxidation processes (AOPs) were applied to bleach and degrade C.I. Reactive Green 8 and C.I. Reactive Red 45 organic dyes in water solutions. Two types of hybrid gas/liquid high voltage electrical discharge (corona) reactors, known as hybrid series and hybrid parallel were studied. The difference between these reactors relates to electrode configuration, which affects the amounts of ozone, hydrogen peroxide and hydroxyl radicals produced. Experiments were conducted using dye concentrations of 20 mgl(-1) and 75 mgl(-1), with and without NH4ZSM5 zeolite addition in order to determine possible effects of added solid particles to total process efficiency. The role of ozone in combination with zeolites was assessed through comparative direct ozonation experiments with ozone supplied by an ozone generator. UV/VIS spectrophotometric measurements and measurements of total organic carbon (TOC) were used for the determination of decolorization and mineralization rates.

Seasonal and species-specific response of VOC emissions by Mediterranean woody plant to elevated ozone concentrations

NASA Astrophysics Data System (ADS)

Llusià, J.; Peñuelas, J.; Gimeno, B. S.

Although certain factors controlling plant emission rates of volatile organic compounds (VOCs) are reasonably well understood, the influence of elevated ozone concentrations as abiotic stress is mostly unknown. Therefore, we studied the effects of ozone concentrations on seasonal biogenic volatile organic compound (BVOC) emissions by different Mediterranean plant species in open top chambers (OTC). Three ozone treatments were established: filtered air (F), non-filtered air (NF), and fumigated air (NF+) adding 40 nl l -1 of ozone over NF. We studied the response of VOC emission in saplings of four Mediterranean woody plant species and subspecies: Ceratonia siliqua L., Olea europaea L., Quercus ilex spp. ilex L., and Quercus ilex spp. rotundifolia L. as representative of natural Mediterranean vegetation. No visible symptoms were detected on the leaves. No significant effect was found on net photosynthetic rates or stomatal conductance except for an increase in net photosynthetic rates in Quercus ilex ilex in spring and summer and an overall slight increase in Quercus ilex rotundifolia. Emissions of the total VOCs from Ceratonia siliqua in summer, and from Olea europaea and Quercus ilex rotundifolia in spring increased in ozone fumigated OTC in comparison with F or NF OTC. Decreased emissions were found in Quercus ilex rotundifolia in summer. There were no significant differences between ozone fumigation treatments for the other plant species and seasons. When considering particular VOCs, the results were also variable among species and time of the year. While α-pinene emissions decreased with ozone fumigation in Olea europaea, α-pinene and limonene emissions increased in Quercus ilex ilex. The responses of these particular VOCs did not always match the responses of total VOCs. In spite of this strong variability, when considering overall annual data for all species and seasons, there were increased net photosynthetic rates (37%) and limonene (95%) and total VOC (45%) emission rates in ozone-fumigated plants, whereas stomatal conductance did not change. Since VOCs are precursors of ozone, the increase in BVOC emission as a consequence of elevated tropospheric ozone concentrations may lead to positive feedback mechanisms in ozone formation.

Stratospheric ozone as viewed from the Chappuis band. [long term pollution monitoring

NASA Technical Reports Server (NTRS)

Angione, R. J.; Medeiros, E. J.; Roosen, R. G.

1976-01-01

Total stratospheric ozone values above high-altitude stations in southern California from 1912 to 1950 and northern Chile from 1918 to 1948 are determined using data obtained by the Smithsonian Astrophysical Observatory, including transmission measurements made in the Chappuis band (0.5 to 0.7 micron). The results show that at both sites, total ozone amounts commonly exhibit variations of as much as 20% to 30% on time scales ranging from months to decades. Consideration of the amount of incident solar energy absorbed by the Chappuis band suggests that ozone acts as a shutter on the incoming solar radiation and provides a trigger mechanism between solar activity and climatic change.

Direct measurements of tropospheric ozone from TOMS data

NASA Technical Reports Server (NTRS)

Hudson, Robert D.

1993-01-01

In the past year, we have made measurements of the tropospheric total column of ozone during the biomass burning season in Africa (August to October). Fishman et. al. had reported previously that by taking a time average of the low spatial resolution data from TOMS (Total Ozone Mapping Spectrometer) on Nimbus-7 (referred to as the Grid-T data set), during the biomass burning season in Africa, a plume of ozone extends from the East coast of Africa into the Atlantic. In this report, we present an analysis that we have made using the measured TOMS radiances taken from the High Density TOMS data set (referred as the HDT data set), which examines this plume in more detail.

First comparison of simultaneous IRIS, BUV, and ground-based measurements of total ozone

NASA Technical Reports Server (NTRS)

Prior, E. J.; Oza, B. J.

1978-01-01

In the present paper, the zonally-averaged global distribution of total ozone obtained simultaneously from different measurements are compared with respect to differences in the measured latitudinal and seasonal variations of total ozone. Emphasis is placed on systematic discrepancies that appear to be related to differences in the sensing methodologies or instruments. While the zonal averages of the IRIS and BUV satellite techniques agree quite well at low latitudes, the results are consistently higher for IRIS than for BUV above mid-latitudes in both the Northern and Southern Hemispheres. The BUV and ground-based ultraviolet averages agree better with each other than with infrared IRIS measurements.

Retrieval of Ozone Column Content from Airborne Sun Photometer Measurements During SOLVE II: Comparison with SAGE III, POAM III,THOMAS and GOME Measurements. Comparison with SAGE 111, POAM 111, TOMS and GOME Measurements

NASA Technical Reports Server (NTRS)

Livingston, J.; Schmid, B.; Russell, P.; Eilers, J.; Kolyer, R.; Redemann, J.; Yee, J.-H.; Trepte, C.; Thomason, L.; Pitts, M.

2003-01-01

During the Second SAGE 111 Ozone Loss and Validation Experiment (SOLVE II), the 14- channel NASA Ames Airborne Trackmg Sunphotometer (AATS-14) was mounted on the NASA DC-8 and successfully measured spectra of total and aerosol optical depth (TOD and AOD) during the sunlit portions of eight science flights. Values of ozone column content above the aircraft have been derived from the AATS-14 data by using a linear least squares method. For each AATS-14 measured TOD spectrum, this method iteratively finds the ozone column content that yields the best match between measured and calculated TOD. The calculations assume the known Chappuis ozone band shape and a three-parameter AOD shape (quadratic in log-log space). Seven of the AATS-14 channels (each employing an interference filter with a nominal full-width at half maximum bandpass of -5 nm) are within the Chappuis band, with center wavelengths between 452.9 nm and 864.5 nm. One channel (604.4 nm) is near the peak, and three channels (499.4, 519.4 and 675.1 nm) have ozone absorption within 30-40% of that at the peak. For the typical DC-8 SOLVE II cruising altitudes of approx. 8-12 km and the background stratospheric aerosol conditions that prevailed during SOLVE 11, absorption of incoming solar radiation by ozone comprised a significant fraction of the aerosol-plus-ozone optical depth measured in the four AATS-14 channels centered between 499.4 and 675.1 nm. Typical AODs above the DC-8 ranged from 0.003-0.008 in these channels. For comparison, an ozone overburden of 0.3 atm-cm (300 DU) translates to ozone optical depths of 0.009,0.014, 0.041, and 0.012, respectively, at these same wavelengths. In this paper, we compare AATS-14 values of ozone column content with temporally and spatially near-coincident values derived from measurements acquired by the Stratospheric Aerosol and Gas Experiment III (SAGE III) and the Polar Ozone and Aerosol Measurement 111 (POAM III) satellite sensors. We also compare AATS-14 ozone retrievals during selected DC-8 latitudinal and longitudinal transects with total column ozone data acquired by the Total Ozone Mapping Spectrometer (TOMS) and the Global Ozone Monitoring Experiment (GOME) satellite sensors. To enable this comparison, the amount of ozone in the column below the aircraft is estimated by combining SAGE and/or POAM data with high resolution, fast response in-situ ozone measurements acquired during the DC-8 ascent at the start of each science flight.

A simple and sensitive fluorescence method for the determination of trace ozone in air using acridine red as a probe.

PubMed

Liu, Qingye; Lin, Chenyin; Zhang, Xinghui; Wen, Guiqing; Liang, Aihui

2014-12-01

The ozone in an air sample was trapped by H3 BO3 -LK solution to produce iodine (I2) that interacted with excess I(-) to form I3(-). In pH 4.0 acetate buffer solutions, the I3(-) reacted with acridine red to form acridine red-I3 ion association particles that resulted in the fluorescence peak decreased at 553 nm. The decreased value ΔF553 nm is linear to the O3 concentration in the range 0.08-53.3 × 10(-6) mol/L, with a detection limit of 4 × 10(-8) mol/L. This fluorescence method was used to determine ozone in air samples, and the results were in agreement with that of indigo carmine spectrophotometry. Copyright © 2014 John Wiley & Sons, Ltd.

Tropical tropospheric ozone: Implications for dynamics and biomass burning

NASA Astrophysics Data System (ADS)

Chandra, S.; Ziemke, J. R.; Bhartia, P. K.; Martin, R. V.

2002-07-01

This paper studies the significance of large-scale transport and pyrogenic (i.e., biomass burning) emissions in the production of tropospheric ozone in the tropics. Using aerosol index (AI) and tropospheric column ozone (TCO) time series from 1979 to 2000 derived from the Nimbus-7 and Earth Probe Total Ozone Mapping Spectrometer measurements, our study shows significant differences in the seasonal and spatial characteristics of pyrogenic emissions north and south of the equator in the African region and Brazil in South America. Notwithstanding these differences, most of the observed seasonal characteristics are well simulated by the GEOS-CHEM global model of tropospheric chemistry. The only exception is the northern African region where modeled and observed TCO differ significantly. In the Indonesian region the most significant increase in TCO occurred during September-December 1997, following large-scale forest and savanna fires associated with the El Niño induced dry condition. The increase in TCO extended over most of the western Pacific well outside the burning region and was accompanied by a decrease in the eastern Pacific resembling a west-to-east dipole about the dateline. These features are well simulated in the GEOS-CHEM model which suggests that both the biomass burning and changes in meteorological conditions during the El Niño period contributed almost equally to the observed increase in TCO in the Indonesian region. During 1997 the net increase in TCO integrated over the tropical region between 15°N and 15°S was about 6-8 Tg (1 Tg = 1012 g) over the mean climatological value of about 77 Tg. The GEOS-CHEM model suggests that most of this increase may have been caused by biomass burning in the Indonesian region since dynamical components of El Niño induced changes in TCO tend to cancel out in the area-averaged data. In addition to biomass burning, the interannual variability in the area-averaged column ozone in the tropics is influenced by a number of factors including the quasi-biennial oscillation and solar cycle.

Nimbus-7 TOMS Version 7 Calibration

NASA Technical Reports Server (NTRS)

Wellemeyer, C. G.; Taylor, S. L.; Jaross, G.; DeLand, M. T.; Seftor, C. J.; Labow, G.; Swissler, T. J.; Cebula, R. P.

1996-01-01

This report describes an improved instrument characterization used for the Version 7 processing of the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) data record. An improved internal calibration technique referred to as spectral discrimination is used to provide long-term calibration precision of +/- 1%/decade in total column ozone amount. A revised wavelength scale results in a day one calibration that agrees with other satellite and ground-based measurements of total ozone, while a wavelength independent adjustment of the initial radiometric calibration constants provides good agreement with surface reflectivity measured by other satellite-borne ultraviolet measurements. The impact of other aspects of the Nimbus-7 TOMS instrument performance are also discussed. The Version 7 data should be used in all future studies involving the Nimbus-7 TOMS measurements of ozone. The data are available through the NASA Goddard Space Flight Center's Distributive Active Archive Center (DAAC).

Ozone and stratospheric height waves for opposite phases of the QBO

NASA Technical Reports Server (NTRS)

Mo, Kingtse C.; Nogues-Paegle, Julia

1994-01-01

The stratospheric quasi-biennial oscillation (QBO) provides an important source of interannual variations in the Northern Hemisphere. O'sullivan and Salby (1990) related extra-tropical eddy transport with the phase of the tropical QBO. When the tropical wind is easterly, the zero wind line is shifted into the winter hemisphere. Enhanced wave activity in middle latitudes acts to weaken the polar vortex. When the tropical wind is in the westerly phase the situation reverses. Heights at 30 mb and ozone configurations are contrasted in this paper for these two QBO phases. When the winter vortex deforms due to the amplification of planetary waves 1 and 2, extends westward and equatorward, the complementary band of low vorticity air spirals in toward the pole from lower latitudes. Sometimes, these planetary waves break (Juckes and McIntyre, 1987) and an irreversible mixing of air takes place between high and mid-latitudes. Global ozone patterns, as obtained form satellite observations, appear to be affected by planetary wave breaking (Leovy et al. 1985). This mixing results on regions with uniform ozone and potential vorticity. In the Southern Hemisphere (SH), Newman and Randel (1988) using Total Ozone Mapping Spectrometer (TOMS) data and the NMC analyses have found strong spatial correlation between the October mean temperature in the lower stratosphere and total ozone for the 1979 through 1986 years. Recently Nogues-Paegle et al.(1992) analyzed SH ozone and height data from 1986 to 1989. They found that leading empirical orthogonal functions (EOFs) for both ozone and 50 mb heights exhibit zonal wave 1 and 2 and that the correlations between ozone and 50 mb principal components (PCs) are high. The results were found to be consistent with a linear planetary wave advecting a passive tracer. In this paper, the dominant patterns of variability for 30 mb NMC heights and TOMS total ozone are obtained for the winter to summer transition (January to May) in the Northern Hemisphere (NH) for the years 1987-1990.

First Reprocessing of Southern Hemisphere ADditional OZonesondes Profile Records: 3. Uncertainty in Ozone Profile and Total Column

NASA Astrophysics Data System (ADS)

Witte, Jacquelyn C.; Thompson, Anne M.; Smit, Herman G. J.; Vömel, Holger; Posny, Françoise; Stübi, Rene

2018-03-01

Reprocessed ozonesonde data from eight SHADOZ (Southern Hemisphere ADditional OZonesondes) sites have been used to derive the first analysis of uncertainty estimates for both profile and total column ozone (TCO). The ozone uncertainty is a composite of the uncertainties of the individual terms in the ozone partial pressure (PO3) equation, those being the ozone sensor current, background current, internal pump temperature, pump efficiency factors, conversion efficiency, and flow rate. Overall, PO3 uncertainties (ΔPO3) are within 15% and peak around the tropopause (15 ± 3 km) where ozone is a minimum and ΔPO3 approaches the measured signal. The uncertainty in the background and sensor currents dominates the overall ΔPO3 in the troposphere including the tropopause region, while the uncertainties in the conversion efficiency and flow rate dominate in the stratosphere. Seasonally, ΔPO3 is generally a maximum in the March-May, with the exception of SHADOZ sites in Asia, for which the highest ΔPO3 occurs in September-February. As a first approach, we calculate sonde TCO uncertainty (ΔTCO) by integrating the profile ΔPO3 and adding the ozone residual uncertainty, derived from the McPeters and Labow (2012, doi:10.1029/2011JD017006) 1σ ozone mixing ratios. Overall, ΔTCO are within ±15 Dobson units (DU), representing 5-6% of the TCO. Total Ozone Mapping Spectrometer and Ozone Monitoring Instrument (TOMS and OMI) satellite overpasses are generally within the sonde ΔTCO. However, there is a discontinuity between TOMS v8.6 (1998 to September 2004) and OMI (October 2004-2016) TCO on the order of 10 DU that accounts for the significant 16 DU overall difference observed between sonde and TOMS. By comparison, the sonde-OMI absolute difference for the eight stations is only 4 DU.

Investigations of Stratosphere-Troposphere Exchange of Ozone Derived From MLS Observations

NASA Technical Reports Server (NTRS)

Olsen, Mark A.; Schoeberl, Mark R.; Ziemke, Jerry R.

2006-01-01

Daily high-resolution maps of stratospheric ozone have been constructed using observations by MLS combined with trajectory information. These fields are used to determine the extratropical stratosphere-troposphere exchange (STE) of ozone for the year 2005 using two diagnostic methods. The resulting two annual estimates compare well with past model- and observational-based estimates. Initial analyses of the seasonal characteristics indicate that significant STE of ozone in the polar regions occurs only during spring and early summer. We also examine evidence that the Antarctic ozone hole is responsible for a rapid decrease in the rate of ozone STE during the SH spring. Subtracting the high-resolution stratospheric ozone fiom OMI total column measurements creates a high-resolution tropospheric ozone residual (HTOR) product. The HTOR fields are compared to the spatial distribution of the ozone STE. We show that the mean tropospheric ozone maxima tend to occur near locations of significant ozone STE. This suggests that STE may be responsible for a significant fraction of many mean tropospheric ozone anomalies.

Total ozone column derived from GOME and SCIAMACHY using KNMI retrieval algorithms: Validation against Brewer measurements at the Iberian Peninsula

NASA Astrophysics Data System (ADS)

Antón, M.; Kroon, M.; López, M.; Vilaplana, J. M.; Bañón, M.; van der A, R.; Veefkind, J. P.; Stammes, P.; Alados-Arboledas, L.

2011-11-01

This article focuses on the validation of the total ozone column (TOC) data set acquired by the Global Ozone Monitoring Experiment (GOME) and the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) satellite remote sensing instruments using the Total Ozone Retrieval Scheme for the GOME Instrument Based on the Ozone Monitoring Instrument (TOGOMI) and Total Ozone Retrieval Scheme for the SCIAMACHY Instrument Based on the Ozone Monitoring Instrument (TOSOMI) retrieval algorithms developed by the Royal Netherlands Meteorological Institute. In this analysis, spatially colocated, daily averaged ground-based observations performed by five well-calibrated Brewer spectrophotometers at the Iberian Peninsula are used. The period of study runs from January 2004 to December 2009. The agreement between satellite and ground-based TOC data is excellent (R2 higher than 0.94). Nevertheless, the TOC data derived from both satellite instruments underestimate the ground-based data. On average, this underestimation is 1.1% for GOME and 1.3% for SCIAMACHY. The SCIAMACHY-Brewer TOC differences show a significant solar zenith angle (SZA) dependence which causes a systematic seasonal dependence. By contrast, GOME-Brewer TOC differences show no significant SZA dependence and hence no seasonality although processed with exactly the same algorithm. The satellite-Brewer TOC differences for the two satellite instruments show a clear and similar dependence on the viewing zenith angle under cloudy conditions. In addition, both the GOME-Brewer and SCIAMACHY-Brewer TOC differences reveal a very similar behavior with respect to the satellite cloud properties, being cloud fraction and cloud top pressure, which originate from the same cloud algorithm (Fast Retrieval Scheme for Clouds from the Oxygen A-Band (FRESCO+)) in both the TOSOMI and TOGOMI retrieval algorithms.

Variability in Tropical Tropospheric Ozone as Observed by SHADOZ

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Witte, Jacquelyn C.; Coetzee, Geert J. R.; Chatfield, Robert B.; Hudson, Robert D.

2004-01-01

The SHADOZ (Southern Hemisphere Additional Ozonesondes) ozone sounding network was initiated in 1998 to improve the coverage of tropical in-situ ozone measurements for satellite validation, algorithm development and related process studies. Over 2000 soundings have been archived at the central website, , for 12 stations: Ascension Island; Nairobi and Malindi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil; Paramaribo, Surinam. Some results to date indicate reliability of the measurement and highly variable interactions between ozone and tropical meteorology. For example: 1. By using ECC sondes with similar procedures, 5-10% accuracy and precision (1-sigma) of the sonde total ozone measurement was achieved [Thompson et al., 2003al; 2. Week-to-week variability in tropospheric ozone is so great that statistics are frequently not Gaussian and most stations vary up to a factor of 3 in column amount over the course of a year [Thompson et al., 2002b]. 3. Longitudinal variability in tropospheric ozone profiles is a consistent feature, with a 10- 15 DU column-integrated difference between Atlantic and Pacific sites; this is the cause of the zonal wave-one feature in total ozone [Shiotani, 1992]. The ozone record from Paramaribo, Surinam (6N, 55W) is a marked contrast to southern tropical ozone because Surinam is often north of the Intertropical Convergence Zone. Interpretations of SHADOZ time-series and approaches to classification suggested by SHADOZ data over Africa and the Indian Ocean will be described.

Attribution of Recovery in Lower-Stratospheric Ozone

NASA Technical Reports Server (NTRS)

Yang, Eun-Su; Cunnold, Derek M.; Salawitch, Ross J.; McCormick, M. Patrick; Russell, James, III; Zawodny, Joseph M.; Oltmans, Samuel; Newchurch, Michael J.

2005-01-01

Multiple satellite and ground-based observations provide consistent evidence that the thickness of Earth's protective ozone layer has stopped declining since 1997, close to the time of peak stratospheric halogen loading. Regression analyses with Effective Equivalent Stratospheric Chlorine (EESC) in conjunction with further analyses using more sophisticated photochemical model calculations constrained by satellite data demonstrate that the cessation of ozone depletion between 18-25 km altitude is consistent with a leveling off of stratospheric abundances of chlorine and bromine, due to the Montreal Protocol and its amendments. However, ozone increases in the lowest part of the stratosphere, from the tropopause to 18 km, account for about half of the improvement in total column ozone during the past 9 years at northern hemisphere mid-latitudes. The increase in ozone for altitudes below 18 km is most likely driven by changes in transport, rather than driven by declining chlorine and bromine. Even with this evidence that the Montreal Protocol and its amendments are having the desired, positive effect on ozone above 18 km, total column ozone is recovering faster than expected due to the apparent transport driven changes at lower altitudes. Accurate prediction of future levels of stratospheric ozone will require comprehensive understanding of the factors that drive temporal changes at various altitudes, and partitioning of the recent transport-driven increases between natural variability and changes in atmospheric structure perhaps related to anthropogenic climate change.

Attribution of Recovery in Lower-stratospheric Ozone

NASA Technical Reports Server (NTRS)

Yang, Eun-Su; Cunnold, Derek M.; Salawitch, Ross J.; McCormick, M. Patrick; Russell, James, III; Zawodny, Joseph M.; Oltmans, Samuel; Newchurch, Michael J.

2006-01-01

Multiple satellite and ground-based observations provide consistent evidence that the thickness of Earth's protective ozone layer has stopped declining since 1997, close to the time of peak stratospheric halogen loading. Regression analyses with Effective Equivalent Stratospheric Chlorine (EESC) in conjunction with further analyses using more sophisticated photochemical model calculations constrained by satellite data demonstrate that the cessation of ozone depletion between 18-25 km altitude is consistent with a leveling off of stratospheric abundances of chlorine and bromine, due to the Montreal Protocol and its amendments. However, ozone increases in the lowest part of the stratosphere, from the tropopause to 18 km, account for about half of the improvement in total column ozone during the past 9 years at northern hemisphere mid-latitudes. The increase in ozone for altitudes below 18 km is most likely driven by changes in transport, rather than driven by declining chlorine and bromine. Even with this evidence that the Montreal Protocol and its amendments are having the desired, positive effect on ozone above 18 km, total column ozone is recovering faster than expected due to the apparent transport driven changes at lower altitudes. Accurate prediction of future levels of stratospheric ozone will require comprehensive understanding of the factors that drive temporal changes at various altitudes, and partitioning of the recent transport-driven increases between natural variability and changes in atmospheric structure perhaps related to anthropogenic climate change.

Multi-Model Assessment of the Factors Driving Stratospheric Ozone Evolution Over the 21st Century

NASA Technical Reports Server (NTRS)

Oman, L. D.; Plummer, D. A.; Waugh, D. W.; Austin, J.; Scinocca, J.; Douglass, A. R.; Salawitch, R. J.; Canty, T.; Akiyoshi, H.; Bekki, S.;

Temporal and Spatial Variation in, and Population Exposure to, Summertime Ground-Level Ozone in Beijing

PubMed Central

Zheng, Youfei; Li, Ting; Wei, Li; Guan, Qing

2018-01-01

Ground-level ozone pollution in Beijing has been causing concern among the public due to the risks posed to human health. This study analyzed the temporal and spatial distribution of, and investigated population exposure to, ground-level ozone. We analyzed hourly ground-level ozone data from 35 ambient air quality monitoring sites, including urban, suburban, background, and traffic monitoring sites, during the summer in Beijing from 2014 to 2017. The results showed that the four-year mean ozone concentrations for urban, suburban, background, and traffic monitoring sites were 95.1, 99.8, 95.9, and 74.2 μg/m3, respectively. A total of 44, 43, 45, and 43 days exceeded the Chinese National Ambient Air Quality Standards (NAAQS) threshold for ground-level ozone in 2014, 2015, 2016, and 2017, respectively. The mean ozone concentration was higher in suburban sites than in urban sites, and the traffic monitoring sites had the lowest concentration. The diurnal variation in ground-level ozone concentration at the four types of monitoring sites displayed a single-peak curve. The peak and valley values occurred at 3:00–4:00 p.m. and 7:00 a.m., respectively. Spatially, ground-level ozone concentrations decreased in gradient from the north to the south. Population exposure levels were calculated based on ground-level ozone concentrations and population data. Approximately 50.38%, 44.85%, and 48.49% of the total population of Beijing were exposed to ground-level ozone concentrations exceeding the Chinese NAAQS threshold in 2014, 2015, and 2016, respectively. PMID:29596366

Temporal and Spatial Variation in, and Population Exposure to, Summertime Ground-Level Ozone in Beijing.

PubMed

Zhao, Hui; Zheng, Youfei; Li, Ting; Wei, Li; Guan, Qing

2018-03-29

Ground-level ozone pollution in Beijing has been causing concern among the public due to the risks posed to human health. This study analyzed the temporal and spatial distribution of, and investigated population exposure to, ground-level ozone. We analyzed hourly ground-level ozone data from 35 ambient air quality monitoring sites, including urban, suburban, background, and traffic monitoring sites, during the summer in Beijing from 2014 to 2017. The results showed that the four-year mean ozone concentrations for urban, suburban, background, and traffic monitoring sites were 95.1, 99.8, 95.9, and 74.2 μg/m³, respectively. A total of 44, 43, 45, and 43 days exceeded the Chinese National Ambient Air Quality Standards (NAAQS) threshold for ground-level ozone in 2014, 2015, 2016, and 2017, respectively. The mean ozone concentration was higher in suburban sites than in urban sites, and the traffic monitoring sites had the lowest concentration. The diurnal variation in ground-level ozone concentration at the four types of monitoring sites displayed a single-peak curve. The peak and valley values occurred at 3:00-4:00 p.m. and 7:00 a.m., respectively. Spatially, ground-level ozone concentrations decreased in gradient from the north to the south. Population exposure levels were calculated based on ground-level ozone concentrations and population data. Approximately 50.38%, 44.85%, and 48.49% of the total population of Beijing were exposed to ground-level ozone concentrations exceeding the Chinese NAAQS threshold in 2014, 2015, and 2016, respectively.

A major event of Antarctic ozone hole influence in southern Brazil in October 2016: an analysis of tropospheric and stratospheric dynamics

NASA Astrophysics Data System (ADS)

Dornelles Bittencourt, Gabriela; Bresciani, Caroline; Kirsch Pinheiro, Damaris; Valentin Bageston, José; Schuch, Nelson Jorge; Bencherif, Hassan; Paes Leme, Neusa; Vaz Peres, Lucas

2018-03-01

The Antarctic ozone hole is a cyclical phenomenon that occurs during the austral spring where there is a large decrease in ozone content in the Antarctic region. Ozone-poor air mass can be released and leave through the Antarctic ozone hole, thus reaching midlatitude regions. This phenomenon is known as the secondary effect of the Antarctic ozone hole. The objective of this study is to show how tropospheric and stratospheric dynamics behaved during the occurrence of this event. The ozone-poor air mass began to operate in the region on 20 October 2016. A reduction of ozone content of approximately 23 % was observed in relation to the climatology average recorded between 1992 and 2016. The same air mass persisted over the region and a drop of 19.8 % ozone content was observed on 21 October. Evidence of the 2016 event occurred through daily mean measurements of the total ozone column made with a surface instrument (Brewer MkIII no. 167 Spectrophotometer) located at the Southern Space Observatory (29.42° S, 53.87° W) in São Martinho da Serra, Rio Grande do Sul. Tropospheric dynamic analysis showed a post-frontal high pressure system on 20 and 21 October 2016, with pressure levels at sea level and thickness between 1000 and 500 hPa. Horizontal wind cuts at 250 hPa and omega values at 500 hPa revealed the presence of subtropical jet streams. When these streams were allied with positive omega values at 500 hPa and a high pressure system in southern Brazil and Uruguay, the advance of the ozone-poor air mass that caused intense reductions in total ozone content could be explained.

Results of the measurement of atmospheric ozone and hydrocarbons in Baden-Wurttemburg

NASA Technical Reports Server (NTRS)

Blander, W.; Siegel, D.

1978-01-01

Data are presented on the diurnal variations of the levels of ozone, ethylene, ethane, and acetylene. The measurement procedures used are described. Variations in monthly ozone levels are given, and measurements from different stations are compared. Data on the total monthly concentrations of NO and NO2 are compared with similar data for ozone. Problems in determining interrelationships among the concentrations of the various substances are discussed.

On vertical profile of ozone at Syowa

NASA Technical Reports Server (NTRS)

Chubachi, Shigeru

1994-01-01

The difference in the vertical ozone profile at Syowa between 1966-1981 and 1982-1988 is shown. The month-height cross section of the slope of the linear regressions between ozone partial pressure and 100-mb temperature is also shown. The vertically integrated values of the slopes are in close agreement with the slopes calculated by linear regression of Dobson total ozone on 100-mb temperature in the period of 1982-1988.

The total ozone and UV solar radiation over Stara Zagora, Bulgaria

NASA Astrophysics Data System (ADS)

Mendeva, B.; Gogosheva, Ts.; Petkov, B.; Krastev, D.

Direct ground-based UV measurements and the total ozone content (TOC) over Stara Zagora, Bulgaria are presented. The observations are conducted by a scanning spectrophotometer, which measures the direct solar radiation in the range 290 - 360 nm with 1 nm resolution. For the time period 1998 -- 2003 the TOC data show seasonal variations, typical for the middle latitudes -- maximum in the spring and minimum in the autumn. The comparison of these TOC ground-based data to TOC satellite-borne data from the Global Ozone Monitoring Experiment (GOME) shows a seasonal dependence of the differences between the ground-based and satellite data. The relation between the UV radiation and TOC is investigated. Clear negative relationship is recognized between the total ozone and the irradiance of the wavelength 305 nm. The opposition of the two variables is significant ( r = - 0,62 ± 0,18) at 98 % confidence level. Yet, for 325 nm it is almost independent with the total ozone. The dependence of the UV-B radiation on the solar zenith angle at given TOC is also analyzed. A decrease of all wavelengths intensities with increase of the solar zenith angle is obtained but with different rate for each of them. The direct sun UV doses for some specific biological effects (erythema and eyes) are obtained as the integral in the wavelength interval 290-330 nm of the measured UV solar spectrum, weighted with an action spectrum, typical for each effect. The estimation of the radiation amplification factor RAF shows that the ozone reduction by 1% increases the erythemal dose by 2,3 %.The eye-damaging doses are more influenced by the TOC changes and in this case RAF=-2,7%. The amount of these biological doses is in a direct ratio with the solar altitude over the horizon. This dependence is more markedly expressed at lower total ozone content in the atmosphere.

Deformation of the total ozone content field in the tropical zone

NASA Technical Reports Server (NTRS)

Vasilyev, Victor I.

1994-01-01

Presented are the ozone investigation results obtained in the tropical zone. Measurements of the total ozone content (TOC) were carried out by the ozonometer M-124. The ozonometer was automated to investigate the ozone intradiurnal variations and to increase precision of the TOC measurements. Obtained results allowed us to follow the effect of tropical cyclones (TC) on the TOC field. Several days before the TC formation the TOC increase is observed in daily mean course compared with the background one. Three types of trend can be singled out in the TOC intradiurnal course: zero, parabolic, quasi-linear. Maximum velocities of a trend are observed some days before the TC formation. Analogous harmonic constituents are mainly presented as spectrum of daily means of ozone, mean and absolute velocities of trend and dispersion as well as spectra of meteorological, hydrometeorological and actinometric values. Revealed is a number of day-to-day ozone variations concerned with large-scale circulations; moisture content in the atmosphere. Obtained are the data about short-period ozone waves (period less than a day). Thin-film silver sensors were used to measure the vertical ozone distribution (VOD). Atmospheric aerosol and VOD measurements were carried out simultaneously, they gave data of the VOD layered structure, where the VOD local minima coincided with the position of aerosol layers' maxima.

Deposition velocities and impact of physical properties on ozone removal for building materials

NASA Astrophysics Data System (ADS)

Lin, Chi-Chi; Hsu, Shu-Chen

2015-01-01

This study aims to estimate the ozone deposition velocities of eight commonly used building materials (BMs) which include calcium silicate board (CSB), green calcium silicate board (GCSB), mineral fiber ceiling (MFC), green mineral fiber ceiling (GMFC), gypsum board (GB), green gypsum board (GGB), wooden flooring (WF) and green wooden flooring (GWF). In addition, the impact of physical properties (specific surface area and total pore volume of BM) on ozone removal ability was also explored and discussed. Studies were conducted in a small-scale environmental stainless steel chamber. CSB and GCSB showed the highest ozone deposition velocities, while WF and GWF showed the lowest ozone deposition velocities among test BMs materials. All reaction probabilities were estimated to fall within the order of magnitude of 10-6. Green BMs showed lower reaction probabilities with ozone comparing with non-green BMs except for GGB. Consistent with the trends for deposition velocity, fleecy and porous materials exhibit higher reaction probabilities than smooth, non-porous surfaces. Specific surface area of BM is more closely related to ozone removal than total pore volume of BM with R2 of 0.93 vs. R2 of 0.84. Discussion of Thiele modulus for all test BMs indicates surface reactions are occurring quickly relative to internal diffusion and ozone removal is internal diffusion-limited.

Recent Advances in Ozone Data Assimilation at the GMAO - Towards a New Reanalysis

NASA Technical Reports Server (NTRS)

Krzysztof, Wargan; Pawson, S.; Nielsen, J. E.; Witte, J.; Douglass, A.; Strahan, S.; Joiner, J.; Bhartia, P. K.; Livesey, N.; Read, W.;

Space observations of aerosols and ozone; Proceedings of the Topical Meeting, Ottawa, Canada, May 16-June 2, 1982

NASA Technical Reports Server (NTRS)

Mccormick, M. P. (Editor); Lovill, J. E.

1982-01-01

The measurement of aerosols from space is discussed, taking into account the role of aerosols in climate, instrumentation and further measurement systems, retrieval procedures, measurements and observations, ground truth measurements, and effects on remote sensing and on climate. Aspects of ozone variability in the middle atmosphere are explored, giving attention to the quasi-biennial oscillation in equatorial stratospheric temperatures and total ozone, global pictures on the ozone field from high altitudes from DE-1, measurements of atmospheric ozone from aircraft and from balloons, a mesospheric ozone profile at sunset, periodic and aperiodic ozone variations in the middle and upper stratosphere, solar eclipse induced variations in mesospheric ozone concentrations, and solar UV and ozone balloon measurements. The determination of aerosol optical depth is considered along with a method for estimating cross radiance.

Volcanoes drive climate variability by emitting ozone weeks before eruptions, by forming lower stratospheric aerosols, by causing sustained ozone depletion, and by causing rapid changes in regional ozone concentrations affecting temperature and pressure differences driving atmospheric oscillations

NASA Astrophysics Data System (ADS)

Ward, P. L.

2016-12-01

Total column ozone observed by satellite on February 19, 2010, increased 75% in a plume from Eyjafjallajökull volcano in southern Iceland eastward past Novaya Zemlya, extending laterally from northern Greenland to southern Norway (http://youtu.be/wJFZcPEfoR4). Contemporaneous ground deformation and rapidly increasing numbers of earthquakes imply magma began rising from a sill 4-6 km below the volcano, erupting a month later. Whether the ozone formed from the magma or from very hot gases rising through cracks in the ground is unclear. On February 20-22, 1991, similar increases in ozone were observed north of Pinatubo volcano before its initial eruption on April 2 (http://youtu.be/5y1PU2Qu3ag). Annual average total column ozone during the year of most moderate to large explosive volcanic eruptions since routine observations of ozone began in 1927 has been substantially higher than normal. Increased total column ozone absorbs more solar ultraviolet-B radiation, warming the ozone layer and cooling Earth. Most major volcanic eruptions form sulfuric-acid aerosols in the lower part of the ozone layer providing aqueous surfaces on which heterogeneous chemical reactions enhance ozone depletion. Within a year, aerosol droplets grew large enough to reflect and scatter high-frequency solar radiation, cooling Earth 0.5oC for 2-3 years. Temperature anomalies in the northern hemisphere rose 0.7oC in 28 years from 1970 to 1998 (HadCRUT4), while annual average ozone at Arosa dropped 27 DU because of manufactured CFC gases. Beginning in August 2014, temperature anomalies in the northern hemisphere rose another 0.6oC in less than two years apparently because of the 6-month eruption of Bárðarbunga volcano in central Iceland, the highest rate of basaltic lava extrusion since 1783. Large extrusions of basaltic lava are typically contemporaneous with the greatest periods of warming throughout Earth history. Ozone concentrations at Arosa change by season typically from 370 DU during March and April to 285 DU in October. Removing this seasonal change to calculate ozone anomaly and plotting against temperature anomaly, and climate oscillation indices such as NAM, NAO, ENSO, and SAM gives insight into the influence of volcanic eruptions on regional temperatures, pressures, winds, weather, and climate. WhyClimateChanges.com

Ozone photochemical production in urban Shanghai, China: Analysis based on ground level observations

NASA Astrophysics Data System (ADS)

Ran, Liang; Zhao, Chunsheng; Geng, Fuhai; Tie, Xuexi; Tang, Xu; Peng, Li; Zhou, Guangqiang; Yu, Qiong; Xu, Jianmin; Guenther, Alex

2009-08-01

Ozone and its precursors were measured from 15 June 2006 to 14 June 2007 at an urban site in Shanghai and used to characterize photochemical oxidant production in this region. During the observation period, ozone displays a seasonal variation with a maximum in spring. Observed nitrogen oxides (NOx) and carbon monoxide (CO) reached a maximum in winter and a minimum in summer. NOx and CO has a similar double-peak diurnal cycle, implying that they are largely of motor vehicle origin. Total nonmethane organic compounds (NMOC) concentrations averaged over the morning, and the 24-hour periods have a large day-to-day variation with no apparent seasonal cycle. Aromatics play a dominant role in contributing to total NMOC reactivity and ozone-forming potential. Anthropogenic NMOC of diverse sources are major components of total NMOC and consist mainly of moderate and low reactivity species. In contrast, relatively low levels of biogenic NMOC concentrations were observed in urban Shanghai. The early morning NMOC/NOx ratios are typically below 8:1 with an average of around 4:1, indicating that the sampling location is situated in a NMOC-limited regime. Model simulations confirm that potential photochemical ozone production in Shanghai is NMOC-sensitive. It is presently difficult to predict the impact of future human activities, such as the increase of automobiles and vegetation-covered landscapes and the reduction of aerosol on ozone pollution in the fast developing megacities of China, and additional studies are needed to better understand the highly nonlinear ozone problem.

Extreme events in total ozone over the northern mid-latitudes: A case study based on long-term data sets from 5 ground-based stations

NASA Astrophysics Data System (ADS)

Rieder, Harald E.; Jancso, Leonhardt M.; Staehelin, Johannes; Maeder, Jörg A.; Ribatet, Mathieu; Peter, Thomas; Davison, Anthony C.

2010-05-01

In this study we analyze the frequency distribution of extreme events in low and high total ozone (termed ELOs and EHOs) for 5 long-term stations in the northern mid-latitudes in Europe (Belsk, Poland; Hradec Kralove, Czech Republic; Hohenpeissenberg and Potsdam, Germany; and Uccle, Belgium). Further, the influence of these extreme events on annual and seasonal mean values and trends is analysed. The applied method follows the new "ozone extreme concept", which is based on tools from extreme value theory [Coles, 2001; Ribatet, 2007], recently developed by Rieder et al. [2010a, b]. Mathematically seen the decisive feature within the extreme concept is the Generalized Pareto Distribution (GPD). In this analysis, the long-term trends needed to be removed first, differently to the treatment of Rieder et al. [2010a, b], in which the time series of Arosa was analysed, covering many decades of measurements in the anthropogenically undisturbed stratosphere. In contrast to previous studies only focusing on so called ozone mini-holes and mini-highs the "ozone extreme concept" provides a statistical description of the tails in total ozone distributions (i.e. extreme low and high values). It is shown that this concept is not only an appropriate method to describe the frequency and distribution of extreme events, it also provides new information on time series properties and internal variability. Furthermore it allows detection of fingerprints of physical (e.g. El Niño, NAO) and chemical (e.g. polar vortex ozone loss) features in the Earth's atmosphere as well as major volcanic eruptions (e.g. El Chichón, Mt. Pinatubo). It is shown that mean values and trends in total ozone are strongly influenced by extreme events. Trend calculations (for the period 1970-1990) are performed for the entire as well as the extremes-removed time series. The results after excluding extremes show that annual trends are most reduced at Hradec Kralove (about a factor of 3), followed by Potsdam (factor of 2.5), and Hohenpeissenberg and Belsk (both about a factor of 2). In general the reduction of trend is strongest during winter and spring. Throughout all stations the influence of ELOs on observed trends is larger than those of EHOs. Especially from the 1990s on ELOs dominate the picture as only a relatively small fraction of EHOs can be observed in the records (due to strong influence of Mt. Pinatubo eruption and polar vortex ozone loss contributions). Additionally it is evidenced that the number of observed mini-holes can be estimated highly accurate by the GPD-model. Overall the results of this thesis show that extreme events play a major role in total ozone and the "ozone extremes concept" provides deeper insight in the influence of chemical and physical features on column ozone. References: Coles, S.: An Introduction to Statistical Modeling of Extreme Values, Springer Series in Statistics, ISBN:1852334592, Springer, Berlin, 2001. Ribatet, M.: POT: Modelling peaks over a threshold, R News, 7, 34-36, 2007. Rieder ,H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and A.D., Davison (2010): Extreme events in total ozone over Arosa - Part I: Application of extreme value theory, to be submitted to ACPD. Rieder, H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and A.D., Davison (2010): Extreme events in total ozone over Arosa - Part II: Fingerprints of atmospheric dynamics and chemistry and effects on mean values and long-term changes, to be submitted to ACPD.

An unusual stratospheric ozone decrease in the Southern Hemisphere subtropics linked to isentropic air-mass transport as observed over Irene (25.5° S, 28.1° E) in mid-May 2002

NASA Astrophysics Data System (ADS)

Semane, N.; Bencherif, H.; Morel, B.; Hauchecorne, A.; Diab, R. D.

2006-06-01

A prominent ozone minimum of less than 240 Dobson Units (DU) was observed over Irene (25.5° S, 28.1° E), a subtropical site in the Southern Hemisphere, by the Total Ozone Mapping Spectrometer (TOMS) during May 2002 with an extremely low ozone value of less than 219 DU recorded on 12 May, as compared to the climatological mean value of 249 DU for May between 1999 and 2005. In this study, the vertical structure of this ozone minimum is examined using ozonesonde measurements performed over Irene on 15 May 2002, when the total ozone (as given by TOMS) was about 226 DU. It is shown that this ozone minimum is of Antarctic polar origin with a low-ozone layer in the middle stratosphere above 625 K (where the climatological ozone gradient points equatorward), and is of tropical origin with a low-ozone layer in the lower stratosphere between the 400-K and 450-K isentropic levels (where the climatological ozone gradient is reversed). The upper and lower depleted parts of the ozonesonde profile for 15 May are then respectively attributed to equatorward and poleward transport of low-ozone air toward the subtropics in the Southern Hemisphere. The tropical air moving over Irene and the polar one passing over the same area associated with enhanced planetary-wave activity are successfully simulated using the high-resolution advection contour model of Ertel's potential vorticity MIMOSA. The unusual distribution of ozone over Irene during May 2002 in the middle stratosphere is connected to the anomalously pre-conditioned structure of the polar vortex at that time of the year. The winter stratospheric wave driving leading to the ozone minimum is investigated by means of the Eliassen-Palm flux computed from the European Center for Medium-range Weather Forecasts (ECMWF) ERA40 re-analyses.

Accuracy and Precision in the Southern Hemisphere Additional Ozonesondes (SHADOZ) Dataset 1998-2000 in Light of the JOSIE-2000 Results

NASA Technical Reports Server (NTRS)

Witte, J. C.; Thompson, A. M.; Schmidlin, F. J.; Oltmans, S. J.; McPeters, R. D.; Smit, H. G. J.

2003-01-01

A network of 12 southern hemisphere tropical and subtropical stations in the Southern Hemisphere ADditional OZonesondes (SHADOZ) project has provided over 2000 profiles of stratospheric and tropospheric ozone since 1998. Balloon-borne electrochemical concentration cell (ECC) ozonesondes are used with standard radiosondes for pressure, temperature and relative humidity measurements. The archived data are available at:http: //croc.gsfc.nasa.gov/shadoz. In Thompson et al., accuracies and imprecisions in the SHADOZ 1998- 2000 dataset were examined using ground-based instruments and the TOMS total ozone measurement (version 7) as references. Small variations in ozonesonde technique introduced possible biases from station-to-station. SHADOZ total ozone column amounts are now compared to version 8 TOMS; discrepancies between the two datasets are reduced 2\\% on average. An evaluation of ozone variations among the stations is made using the results of a series of chamber simulations of ozone launches (JOSIE-2000, Juelich Ozonesonde Intercomparison Experiment) in which a standard reference ozone instrument was employed with the various sonde techniques used in SHADOZ. A number of variations in SHADOZ ozone data are explained when differences in solution strength, data processing and instrument type (manufacturer) are taken into account.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Landry, L.G.; Pell, E.J.

Hybrid poplar clones exposed to ozone exhibit symptoms of accelerated senescence, including early decline in activity of ribulose-1,5-bisphosphate carboxylase/oxygenase (rubisco). The authors examined the hypothesis that ozone-induced reduction in rubisco occurred as a result of increased protease activity. To test this hypothesis, saplings of Populus maximowizii x trichocarpa were exposed to 0.08 {mu}l/l ozone, 4 h/day, from initiation of sample leaf expansion to foliar abscission. Periodically throughout the treatment the sample leaf was analyzed for chlorophyll content, total protein content, rubisco activity, and proteolytic activity at pH 4.5 and 7.8. At the time of peak rubisco activity, protein was subjectmore » to SDS-PAGE to quantify rubisco. Total protein content of sample leaves was unaffected by ozone treatment. Proteolysis measured under acidic conditions was lower in ozone-treated than control plants throughout the exposure. Proteolysis determined under alkaline conditions only revealed decreases in the second half of the experiment. Ozone induced a more rapid decline in rubisco activity than occurred in control tissue. Quantitative effects of rubisco reflected results of activity assays. It did not appear that enhanced proteolysis could explain the ozone-induced accelerated decline in rubisco.« less

Efficacy of ozone as a fungicidal and detoxifying agent of aflatoxins in peanuts.

PubMed

de Alencar, Ernandes Rodrigues; Faroni, Lêda Rita D'Antonino; Soares, Nilda de Fátima Ferreira; da Silva, Washington Azevedo; Carvalho, Marta Cristina da Silva

2012-03-15

Peanut contamination by fungi is a concern of processors and consumers owing to the association of these micro-organisms with quality deterioration and aflatoxin production. In this study the fungicidal and detoxifying effects of ozone on aflatoxins in peanuts was investigated. Peanut kernels were ozonated at concentrations of 13 and 21 mg L⁻¹ for periods of 0, 24, 48, 72 and 96 h. Ozone was effective in controlling total fungi and potentially aflatoxigenic species in peanuts, with a reduction in colony-forming units per gram greater than 3 log cycles at the concentration of 21 mg L⁻¹ after 96 h of exposure. A reduction in the percentage of peanuts with internal fungal populations was also observed, particularly after exposure to ozone at 21 mg L⁻¹. A reduction in the concentrations of total aflatoxins and aflatoxin B1 of approximately 30 and 25% respectively was observed for kernels exposed to ozone at 21 mg L⁻¹ for 96 h. It was concluded that ozone is an important alternative for peanut detoxification because it is effective in controlling potentially aflatoxigenic fungi and also acts in the reduction of aflatoxin levels in kernels. Copyright © 2011 Society of Chemical Industry.

Ozone-induced changes in host-plant suitability: interactions of Keiferia lycopersicella and Lycopersicon esculentum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trumble, J.T.; Hare, J.D.; Musselman, R.C.

Tomato pinworms, Keiferia lycopersicella (Walsingham), survived better and developed faster on tomato plants, Lycopersicon esculentum Mill., damaged by ozone than on plants not subjected to ozone fumigation. Other measures of fitness, including survival during pupation, sex ratio of adults, female longevity, and fecundity, were not affected. Analyses of ozonated foliage at zero, two and seven days following fumigation demonstrated a transient but significant increase (18-24%) in soluble protein concentration. Although the concentration of the total free amino acids in ozonated foliage did not increase significantly, significant changes were observed in at least 10 specific amino acids, some of which aremore » critical for either insect development or the production of plant defensive chemicals. A reduction in total nitrogen in ozonated foliage at seven days postfumigation indicated that nitrogen was being translocated to other portions of the plant. The implications of increases in assimilable forms of nitrogen in ozonated foliage, which lead to improved host-plant suitability for insect herbivores, are discussed both in relation to some current ecological theories and in regard to pest-management strategies. 59 references, 1 figure, 4 tables.« less

Study of the lower stratospheric thermal structure and total ozone from Nimbus-4 IRIS

NASA Technical Reports Server (NTRS)

Prabhakara, C.

1976-01-01

The global distribution of temperature in the stratosphere from 100 to 10 mbar and the total ozone in the atmosphere are remotely sensed from the Nimbus-4 IRIS measurements for a period of about one year. The temperature and ozone data are presented in the form of monthly mean global maps. The standard deviations of temperature and ozone with respect to zonal averages are calculated. The mean and the variable state of the stratosphere are discussed with the help of these observations. The lower stratosphere in the tropical regions reveals a significant wave number one pattern in the circulation. The Arctic and Antarctic stratospheric winter circulation regimes display a different behavior apparently due to the ocean and orographic differences.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Komhyr, W.D.; Quincy, D.M.; Grass, R.D.

This report describes work to improve the quality of total ozone and Umkehr data obtained in the past at the NOAA Climate Monitoring and Diagnostics Laboratory and the Dobson spectrophotometer ozone observatories. The authors present results of total ozone data re-evaluations for ten stations: Byrd, Antarctica; Fairbanks, Alaska; Hallett, Antarctica; Huancayo, Peru; Haute Provence, France; Lauder, New Zealand; Perth, Australia; Poker Flat, Alaska; Puerto Montt, Chile; and South Pole, Antarctica. The improved data will be submitted in early 1996 to the World Meteorological Organization (WMO) World Ozone Data Center (WODC), and the Atmospheric Environment Service for archiving. Considerable work hasmore » been accomplished, also, in reevaluating Umkehr data from seven of the stations, viz., Huancayo, Haute Provence, Lauder, Perth, Poker Flat, Boulder, Colorado; and Mauna Loa, Hawaii.« less

SSTs, nitrogen fertiliser and stratospheric ozone

NASA Technical Reports Server (NTRS)

Turco, R. P.; Whitten, R. C.; Poppoff, I. G.; Capone, L. A.

1978-01-01

A recently revised model of the stratosphere is used to show that a substantial enhancement in the ozone layer could accompany worldwide SST fleet operations and that water vapor may be an important factor in SST assessments. Revised rate coefficients for various ozone-destroying reactions are employed in calculations which indicate a slight increase in the total content of stratospheric ozone for modest-sized fleets of SSTs flying below about 25 km. It is found that water-vapor chemical reactions can negate in large part the NOx-induced ozone gains computed below 25 km and that increased use of nitrogen fertilizer might also enhance the ozone layer.

Airmass dependence of the Dobson total ozone measurements

NASA Technical Reports Server (NTRS)

Degorska, M.; Rajewska-Wiech, B.

1994-01-01

For many years the airmass dependence of total ozone measurements at Belsk has been observed to vary noticeably from one day to another. Series of AD wavelength pairs measurements taken out to high airmass were analyzed and compared with the two parameter stray light model presented by Basher. The analysis extended to the series of CD measurements indicates the role of atmospheric attenuation in appearing the airmass dependence. The minor noon decline of total ozone has been observed in the CD measurement series similarly as in those of the AD wavelength pairs. Such errors may seriously affect the accuracy of CD measurements at high latitude stations and the observations derived in winter at middle latitude stations.

Evidence for slowdown in stratospheric ozone loss: First stage of ozone recovery

NASA Technical Reports Server (NTRS)

Newchurch, M. J.; Yang, Eun-Su; Cunnold, D. M.; Reinsel, C.; Zawodny, J. M.; Russell, James M., III

2003-01-01

Global ozone trends derived from the Stratospheric Aerosol and Gas Experiment I and II (SAGE I/II) combined with the more recent Halogen Occultation Experiment (HALOE) observations provide evidence of a slowdown in stratospheric ozone losses since 1997. This evidence is quantified by the cumulative sum of residual differences from the predicted linear trend. The cumulative residuals indicate that the rate of ozone loss at 35- 45 km altitudes globally has diminished. These changes in loss rates are consistent with the slowdown of total stratospheric chlorine increases characterized by HALOE HCI measurements. These changes in the ozone loss rates in the upper stratosphere are significant and constitute the first stage of a recovery of the ozone layer.

Literature review of some selected types of results and statistical analyses of total-ozone data. [for the ozonosphere

NASA Technical Reports Server (NTRS)

Myers, R. H.

1976-01-01

The depletion of ozone in the stratosphere is examined, and causes for the depletion are cited. Ground station and satellite measurements of ozone, which are taken on a worldwide basis, are discussed. Instruments used in ozone measurement are discussed, such as the Dobson spectrophotometer, which is credited with providing the longest and most extensive series of observations for ground based observation of stratospheric ozone. Other ground based instruments used to measure ozone are also discussed. The statistical differences of ground based measurements of ozone from these different instruments are compared to each other, and to satellite measurements. Mathematical methods (i.e., trend analysis or linear regression analysis) of analyzing the variability of ozone concentration with respect to time and lattitude are described. Various time series models which can be employed in accounting for ozone concentration variability are examined.

Probing the Martian atmosphere in the ultraviolet

NASA Technical Reports Server (NTRS)

Lindner, Bernhard Lee

1994-01-01

Ozone is a key to understanding atmospheric chemistry on Mars. The O3 abundance has been inferred from UV spectra by several spacecraft, with the most complete coverage provided by Mariner 9. The Mariner 9 UV spectrometer scanned from 2100 to 3500 Angstroms in one of its two spectral channels every 3 seconds with a spectral resolution of 15 Angstroms and an effective field-of-view of approximately 300 sq km. The only atmospheric absorption in the 2000 to 3000 Angstrom region was assumed to come from the Hardey band system of ozone, which has an opacity of order unity. Therefore, the amount of ozone was inferred by fitting this absorption feature with laboratory data of ozone absorption, as shown in Fig 1. Mars O3 shows strong seasonal and latitudinal variation, with column abundances ranging from 0.2 micron-atm at equatorial latitudes to 60 micron-atm over the northern winter polar latitudes (1 micron-atm is a column abundance of 2.689 x 10(exp 15) molecules cm(exp -2). However, the O3 abundance is never great enough to significantly affect atmospheric temperatures or surface temperatures and frost budgets.

Characterising the three-dimensional ozone distribution of a tidally locked Earth-like planet

NASA Astrophysics Data System (ADS)

Proedrou, Elisavet; Hocke, Klemens

2016-06-01

We simulate the 3D ozone distribution of a tidally locked Earth-like exoplanet using the high-resolution, 3D chemistry-climate model CESM1(WACCM) and study how the ozone layer of a tidally locked Earth (TLE) (Ω _{TLE}= 1/365 days) differs from that of our present-day Earth (PDE) (Ω _{PDE}= 1/1 day). The middle atmosphere reaches a steady state asymptotically within the first 80 days of the simulation. An upwelling, centred on the subsolar point, is present on the day side while a downwelling, centred on the antisolar point, is present on the night side. In the mesosphere, we find similar global ozone distributions for the TLE and the PDE, with decreased ozone on the day side and enhanced ozone on the night side. In the lower mesosphere, a jet stream transitions into a large-scale vortex around a low-pressure system, located at low latitudes of the TLE night side. In the middle stratosphere, the concentration of odd oxygen is approximately equal to that of the ozone [({O}x) ≈ ({O}3)]. At these altitudes, the lifetime of odd oxygen is ˜16 h and the transport processes significantly contribute to the global distribution of stratospheric ozone. Compared to the PDE, where the strong Coriolis force acts as a mixing barrier between low and high latitudes, the transport processes of the TLE are governed by jet streams variable in the zonal and meridional directions. In the middle stratosphere of the TLE, we find high ozone values on the day side, due to the increased production of atomic oxygen on the day side, where it immediately recombines with molecular oxygen to form ozone. In contrast, the ozone is depleted on the night side, due to changes in the solar radiation distribution and the presence of a downwelling. As a result of the reduced Coriolis force, the tropical and extratropical air masses are well mixed and the global temperature distribution of the TLE stratosphere has smaller horizontal gradients than the PDE. Compared to the PDE, the total ozone column global mean is reduced by ˜19.3 %. The day side and the night side total ozone column means are reduced by 23.21 and 15.52 %, respectively. Finally, we present the total ozone column (TOC) maps as viewed by a remote observer for four phases of the TLE during its revolution around the star. The mean TOC values of the four phases of the TLE vary by up to 23 %.

Ozone Variations over Central Tien-Shan in Central Asia and Implications for Regional Emissions Reduction Strategies

EPA Science Inventory

The variability of total column ozone (TCO) and tropospheric column ozone (TrCO) was examined in Central Asia. Measurements were conducted at the Lidar Station Teplokluchenka in eastern Kyrgyzstan for one year, July 2008–July 2009. TCO was obtained using a handheld Microtops II ...

Ozone and nitrogen dioxide above the northern Tien Shan

NASA Technical Reports Server (NTRS)

Arefev, Vladimir N.; Volkovitsky, Oleg A.; Kamenogradsky, Nikita E.; Semyonov, Vladimir K.; Sinyakov, Valery P.

1994-01-01

The results of systematic perennial measurements of the total ozone (since 1979) and nitrogen dioxide column (since 1983) in the atmosphere in the European-Asian continent center above the mountainmass of the Tien Shan are given. This region is distinguished by a great number of sunny days during a year. The observation station is at the Northern shore of Issyk Kul Lake (42.56 N 77.04 E 1650 m above the sea level). The measurement results are presented as the monthly averaged atmospheric total ozone and NO2 stratospheric column abundances (morning and evening). The peculiarities of seasonal variations of ozone and nitrogen dioxide atmospheric contents, their regular variances with a quasi-biennial cycles and trends have been noticed. Irregular variances of ozone and nitrogen dioxide atmospheric contents, i.e. their positive and negative anomalies in the monthly averaged contents relative to the perennial averaged monthly means, have been analyzed. The synchronous and opposite in phase anomalies in variations of ozone and nitrogen dioxide atmospheric contents were explained by the transport and zonal circulation in the stratosphere (Kamenogradsky et al., 1990).

Ozone Therapy Enhances Osseous Healing in Rats With Diabetes With Calvarial Defects: A Morphometric and Immunohistochemical Study.

PubMed

Alpan, Aysan Lektemur; Toker, Hülya; Ozer, Hatice

2016-08-01

Bone healing is impaired in diabetes mellitus (DM) cases. The aim of this study is to investigate, both morphometrically and immunohistochemically, the effect of gaseous ozone on bone healing in diabetic rat calvarial defects treated with xenografts. DM was induced with 50 mg/kg intraperitoneal streptozotocin in 56 male Wistar rats. Study groups were as follows: 1) empty defect (control, n = 14); 2) xenograft (XG, n = 14); 3) empty defect treated with ozone therapy (control + ozone, n = 14); and 4) xenograft and ozone application (XG + ozone, n = 14). Critical-size defects were created in all rats. Bovine-derived xenograft was applied to XG groups. Gaseous ozone was applied on the operation day and daily for 2 weeks (140 ppm at 2 L/d, 2.24 mg). Rats were sacrificed at 4 or 8 weeks post-surgery. Total bone area, newly formed bone, and residual graft material were measured histomorphometrically. Osteocalcin and bone morphogenic protein (BMP)-2 expression was evaluated immunohistochemically. Osteoclast numbers in the XG + ozone group were higher than the other groups at week 4 (P <0.05). XG + ozone group revealed more total bone area and new bone area than the XG group at weeks 4 (P <0.05) and 8 (P >0.05). Residual graft materials were decreased in the XG + ozone group and the same group revealed more BMP-2 positivity compared with other groups. Osteocalcin positivity in XG groups was higher than in control groups. Within the limitations of this DM animal study, gaseous ozone application accelerates xenograft resorption and enhances bone regeneration, especially in the early stages of bone healing.

Clinical antibacterial effectiveness and biocompatibility of gaseous ozone after incomplete caries removal.

PubMed

Krunić, Jelena; Stojanović, Nikola; Đukić, Ljiljana; Roganović, Jelena; Popović, Branka; Simić, Ivana; Stojić, Dragica

2018-06-01

To evaluate local effect of gaseous ozone on bacteria in deep carious lesions after incomplete caries removal, using chlorhexidine as control, and to investigate its effect on pulp vascular endothelial growth factor (VEGF), neuronal nitric oxide synthase (nNOS), and superoxide dismutase (SOD). Antibacterial effect was evaluated in 48 teeth with diagnosed deep carious lesion. After incomplete caries removal, teeth were randomly allocated into two groups regarding the cavity disinfectant used: ozone (open system) or 2% chlorhexidine. Dentin samples were analyzed for the presence of total bacteria and Lactobacillus spp. by real-time quantitative polymerase chain reaction. For evaluation of ozone effect on dental pulp, 38 intact permanent teeth indicated for pulp removal/tooth extraction were included. After cavity preparation, teeth were randomly allocated into two groups: ozone group and control group. VEGF/nNOS level and SOD activity in dental pulp were determined by enzyme-linked immunosorbent assay and spectrophotometric method, respectively. Ozone application decreased number of total bacteria (p = 0.001) and Lactobacillus spp. (p < 0.001), similarly to chlorhexidine. The VEGF (p < 0.001) and nNOS (p = 0.012) levels in dental pulp after ozone application were higher, while SOD activity was lower (p = 0.001) comparing to those in control pulp. Antibacterial effect of ozone on residual bacteria after incomplete caries removal was similar to that of 2% chlorhexidine. Effect of ozone on pulp VEGF, nNOS, and SOD indicated its biocompatibility. Ozone appears as effective and biocompatible cavity disinfectant in treatment of deep carious lesions by incomplete caries removal technique.

Standoff Spectroscopy via Remote Generation of a Backward-Propagating Laser Beam

DTIC Science & Technology

2011-02-04

nighttime probing of stratospheric ozone and measurements in polar and equatorial regions. Appl Opt 28:3616–3624. 2. Bisson SE, Goldsmith JEM, Mitchell...MG (1999) Narrow-band, narrow-field-of-view Raman Lidar with combined day and night capability for tropospheric water-vapor profile measurements. Appl

Statistic analysis of annual total ozone extremes for the period 1964-1988

NASA Technical Reports Server (NTRS)

Krzyscin, Janusz W.

1994-01-01

Annual extremes of total column amount of ozone (in the period 1964-1988) from a network of 29 Dobson stations have been examined using the extreme value analysis. The extremes have been calculated as the highest deviation of daily mean total ozone from its long-term monthly mean, normalized by the monthly standard deviations. The extremes have been selected from the direct-Sun total ozone observations only. The extremes resulting from abrupt changes in ozone (day to day changes greater than 20 percent) have not been considered. The ordered extremes (maxima in ascending way, minima in descending way) have been fitted to one of three forms of the Fisher-Tippet extreme value distribution by the nonlinear least square method (Levenberg-Marguard method). We have found that the ordered extremes from a majority of Dobson stations lie close to Fisher-Tippet type III. The extreme value analysis of the composite annual extremes (combined from averages of the annual extremes selected at individual stations) has shown that the composite maxima are fitted by the Fisher-Tippet type III and the composite minima by the Fisher-Tippet type I. The difference between the Fisher-Tippet types of the composite extremes seems to be related to the ozone downward trend. Extreme value prognoses for the period 1964-2014 (derived from the data taken at: all analyzed stations, the North American, and the European stations) have revealed that the prognostic extremes are close to the largest annual extremes in the period 1964-1988 and there are only small regional differences in the prognoses.

Total ozone column, aerosol optical depth and precipitable water effects on solar erythemal ultraviolet radiation recorded in Malta.

NASA Astrophysics Data System (ADS)

Bilbao, Julia; Román, Roberto; Yousif, Charles; Mateos, David; Miguel, Argimiro

2013-04-01

The Universities of Malta and Valladolid (Spain) developed a measurement campaign, which took place in the Institute for Energy Technology in Marsaxlokk (Southern Malta) between May and October 2012, and it was supported by the Spanish government through the Project titled "Measurement campaign about Solar Radiation, Ozone, and Aerosol in the Mediterranean area" (with reference CGL2010-12140-E). This campaign provided the first ground-based measurements in Malta of erythemal radiation and UV index, which indicate the effectiveness of the sun exposure to produce sunburn on human skin. A wide variety of instruments was involved in the campaign, providing a complete atmospheric characterization. Data of erythemal radiation and UV index (from UVB-1 pyranometer), total shortwave radiaton (global and diffuse components from CM-6B pyranometers), and total ozone column, aerosol optical thickness, and precitable water column (from a Microtops-II sunphotometer) were available in the campaign. Ground-based and satellite instruments were used in the analysis, and several intercomparisons were carried out to validate remote sensing data. OMI, GOME, GOME-2, and MODIS instruments, which provide data of ozone, aerosol load and optical properties, were used to this end. The effects on solar radiation, ultraviolet and total shortwave ranges, of total ozone column, aerosol optical thickness and precipitable water column were obtained using radiation measurements at different fixed solar zenith angles. The empirical results shown a determinant role of the solar position, a negligible effect of ozone on total shortwave radiation, and a stronger attenuation provided by aerosol particles in the erythemal radiation. A variety of aerosol types from different sources (desert dust, biomass burning, continental, and maritime) reach Malta, in this campaign several dust events from the Sahara desert occurred and were analyzed establishing the air mass back-trajectories ending at Malta at several heights calculated by means of the HYSPLIT model. Hence, changes in the UV index due to atmospheric aerosol were characterized.

Total ozone trends and variability during 1979-2012 from merged data sets of various satellites

NASA Astrophysics Data System (ADS)

Chehade, W.; Weber, M.; Burrows, J. P.

2014-07-01

The study presents a long-term statistical trend analysis of total ozone data sets obtained from various satellites. A multi-variate linear regression was applied to annual mean zonal mean data using various natural and anthropogenic explanatory variables that represent dynamical and chemical processes which modify global ozone distributions in a changing climate. The study investigated the magnitude and zonal distribution of the different atmospheric chemical and dynamical factors contributing to long-term total ozone changes. The regression model included the equivalent effective stratospheric chlorine (EESC), the 11-year solar cycle, the quasi-biennial oscillation (QBO), stratospheric aerosol loading describing the effects from major volcanic eruptions, the El Niño-Southern Oscillation (ENSO), the Arctic and Antarctic oscillation (AO/AAO), and accumulated eddy heat flux (EHF), the latter representing changes due to the Brewer-Dobson circulation. The total ozone column data set used here comprises the Solar Backscater Ultraviolet SBUV/SBUV-2 merged ozone data set (MOD) V8.6, the merged data set of the Solar Backscaterr Ultraviolet, the Total Ozone Mapping Spectrometer and the Ozone Monitoring Instrument SBUV/TOMS/OMI (1979-2012) MOD V8.0 and the merged data set of the Global Ozone Monitoring Experiment, the Scanning Imaging Absorption spectroMeter for Atmospheric ChartograpHY and the Global Ozone Monitoring Experiment 2 GOME/SCIAMACHY/GOME-2 (GSG) (1995-2012). The trend analysis was performed for twenty-six 5° wide latitude bands from 65° S to 65° N, and the analysis explained most of the ozone variability to within 70 to 90%. The results show that QBO dominates the ozone variability in the tropics (±7 DU) while at higher latitudes, the dynamical indices, AO/AAO and eddy heat flux, have substantial influence on total ozone variations by up to ±10 DU. The contribution from volcanic aerosols is only prominent during the major eruption periods (El Chichón and Mt. Pinatubo), and together with the ENSO signal, is more evident in the Northern Hemisphere. The signature of the solar cycle covers all latitudes and contributes about 10 DU from solar maximum to solar minimum. EESC is found to be a main contributor to the long-term ozone decline and the trend changes after the end of the 1990s. From the EESC fits, statistically significant upward trends after 1997 were found in the extratropics, which points at the slowing of ozone decline and the onset of ozone recovery. The EESC based trends are compared with the trends obtained from the statistical piecewise linear trend (PWLT) model (known as hockey stick) with a turnaround in 1997 to examine the differences between both approaches. In case of the SBUV merged V8.6 data the EESC and PWLT trends before and after 1997 are in good agreement (within 2 σ), however, the positive post-1997 linear trends from the PWLT regression are not significant within 2 σ. A sensitivity study is carried out by comparing the regression results, using SBUV/SBUV-2 MOD V8.6 merged time series (1979-2012) and a merged data set combining SBUV/SBUV-2 (1979-June 1995) and GOME/SCIAMACHY/GOME-2 ("GSG") WFDOAS (Weighting Function DOAS) (July 1995-2012) as well as SBUV/TOMS/OMI MOD V8.0 (1979-2012) in the regression analysis in order to investigate the uncertainty in the long-term trends due to different ozone data sets and data versions. Replacing the late SBUV/SBUV-2 merged data record with GSG data (unscaled and adjusted) leads to very similar results demonstrating the high consistency between satellite data sets. However, the comparison of the new SBUV/SBUV-2 MOD V8.6 with the MOD V8.0 and MOD8.6/GSG data showed somewhat smaller sensitivities with regard to several proxies as well as the linear EESC trends. On the other hand, the PWLT trends after 1997 show some differences, however, within the 2 σ error bars the PWLT trends agree with each other for all three data sets.

Development and Application of Hyperspectral Infrared Ozone Retrieval Products for Operational Meteorology

NASA Technical Reports Server (NTRS)

Berndt, Emily; Zavodsky, Bradley; Jedlovec, Gary

2015-01-01

Cyclogenesis is a key forecast challenge at operational forecasting centers such as WPC and OPC, so these centers have a particular interest in unique products that can identify key storm features. In some cases, explosively developing extratropical cyclones can produce hurricane force, non-convective winds along the East Coast and north Atlantic as well as the Pacific Ocean, with the potential to cause significant damage to life and property. Therefore, anticipating cyclogenesis for these types of storms is crucial for furthering the NOAA goal of a "Weather Ready Nation". Over the last few years, multispectral imagery (i.e. RGB) products have gained popularity among forecasters. The GOES-R satellite champion at WPC/OPC has regularly evaluated the Air Mass RGB products from GOES Sounder, MODIS, and SEVIRI to aid in forecasting cyclogenesis as part of ongoing collaborations with SPoRT within the framework of the GOES-R Proving Ground. WPC/OPC has used these products to identify regions of stratospheric air associated with tropopause folds that can lead to cyclogenesis and hurricane force winds. RGB products combine multiple channels or channel differences into multi-color imagery in which different colors represent a particular cloud or air mass type. Initial interaction and feedback from forecasters evaluating the legacy Air Mass RGBs revealed some uncertainty regarding what physical processes the qualitative RGB products represent and color interpretation. To enhance forecaster confidence and interpretation of the Air Mass RGB, NASA SPoRT has transitioned a total column ozone product from AIRS retrievals to the WPC/OPC. The use of legacy AIRS demonstrates future JPSS capabilities possible with CrIS or OMPS. Since stratospheric air can be identified by anomalous potential vorticity and warm, dry, ozone-rich air, hyperspectral infrared sounder ozone products can be used in conjunction with the Air Mass RGB for identifying the role of stratospheric air in explosive cyclogenesis and hurricane force wind events. Currently, forecasters at WPC/OPC are evaluating the Air Mass RGB imagery in conjunction with the AIRS total column ozone to aid forecasting cyclogenesis and high wind forecasts. One of the limitations of the total ozone product is that it is difficult for forecasters to determine whether elevated ozone concentrations are related to stratospheric air or climatologically high values of ozone in certain regions. To address this limitation, SPoRT created an AIRS ozone anomaly product which calculates the percent of normal ozone based on a global stratospheric ozone mean climatology. With the knowledge that ozone values 125 percent of normal and greater typically represent stratospheric air; the anomaly product can be used with the total column ozone product to confirm regions of stratospheric air on the Air Mass RGB. This presentation describes the generation of these products along with forecaster feedback concerning the use of the AIRS ozone products in conjunction with the Air Mass RGB product for the unique forecast challenges WPC/OPC face. Additionally examples of CrIS ozone and anomaly products will be shown to further demonstrate the utility and capability of JPSS in forecasting unique events.

Changes in surface solar UV irradiances and total ozone during the solar eclipse of August 11, 1999

NASA Astrophysics Data System (ADS)

Zerefos, C. S.; Balis, D. S.; Meleti, C.; Bais, A. F.; Tourpali, K.; Kourtidis, K.; Vanicek, K.; Cappellani, F.; Kaminski, U.; Colombo, T.; Stübi, R.; Manea, L.; Formenti, P.; Andreae, M. O.

2000-11-01

During the solar eclipse of August 11, 1999, intensive measurements of UV solar irradiance and total ozone were performed at a number of observatories located near the path of the Moon's shadow. At the Laboratory of Atmospheric Physics (LAP) of the Aristotle University of Thessaloniki, Greece, global and direct spectra of UV solar irradiances (285-365 nm) were recorded with a double monochromator, and erythemal irradiances were measured with broadband pyranometers. In addition, higher-frequency measurements of global and direct irradiances at six UV wavelengths were performed with a single Brewer spectrophotometer. Total ozone measurements were also performed with Dobson and Brewer spectrophotometers at Hradec Kralove (Czech Republic), Ispra (Italy), Sestola (Italy), Hohenpeissenberg (Germany), Bucharest (Romania), Arosa (Switzerland), and Thessaloniki (Greece). From the spectral UV measurements the limb darkening effect of the solar disk was tentatively quantified from differences of measured solar spectral irradiances at the peak of the eclipse (near to limb conditions) and before the eclipse. Two blackbody curves were fit to the preeclipse and peak eclipse spectra, which have shown a difference in effective temperatures of about 165°K between the limb and the whole of the solar disk. The limb darkening effect is larger at the shorter UV wavelengths. The ratio of the diffuse to direct solar irradiances during the eclipse shows that the diffuse component is reduced much less compared to the decline of the direct solar irradiance at the shorter wavelengths. Moreover, a 20-min oscillation of erythemal UV-B solar irradiance was observed before and after the time of the eclipse maximum under clear skies, indicating a possible 20-min fluctuation in total ozone, presumably caused by the eclipse-induced gravity waves. This work also shows that routine total ozone measurements with a Brewer or a Dobson spectrophotometer should be used with caution during a solar eclipse. This is because the diffuse light increases by more than 30% with respect to the direct solar radiation, increasing more at the shorter wavelength side of the UV spectrum. This plausible mechanism introduces an artificial decrease in total ozone during solar eclipse of more than 30 Dobson units (DU), which is confirmed by all Brewer and Dobson measurements. Changes in total ozone cited earlier in the refereed literature have not been confirmed in the present study.

Arctic Haze: Natural or Pollution

DTIC Science & Technology

1978-08-01

rn wavelength, rs0o; precipitable water in g cm - , iv; Angstrom ~wavelength coefficient, a and column ozone in column cm (STP), 03. Left - Barrow...maximum of total ozone in the Arctic, but there is evidence at the same time of a depletion of surface ozone . 6. Spring is the time when the sun’s...chemical reactions due to high ozone concentrations. d. Association with dynamics of stratospheric warmings (that occur in mid-winter and spring). 6. Cosmic

Techno-economic evaluation of the application of ozone-oxidation in a full-scale aerobic digestion plant.

PubMed

Chiavola, Agostina; D'Amato, Emilio; Gori, Riccardo; Lubello, Claudio; Sirini, Piero

2013-04-01

This paper deals with the application of the ozone-oxidation in a full scale aerobic sludge digester. Ozonation was applied continuously to a fraction of the biological sludge extracted from the digestion unit; the ozonated sludge was then recirculated to the same digester. Three different ozone flow rates were tested (60,500 and 670g O3 h(-1)) and their effects evaluated in terms of variation of the total and soluble fractions of COD, nitrogen and phosphorous, of total and volatile suspended solids concentrations and Sludge Volume Index in the aerobic digestion unit. During the 7-month operation of the ozonation process, it was observed an appreciable improvement of the aerobic digestion efficiency (up to about 20% under the optimal conditions) and of the sludge settleability properties. These results determined an average reduction of about 60% in the biological sludge extracted from the plant and delivered to final disposal. A thorough economic analysis showed that this reduction allowed to achieve a significant cost saving for the plant with respect to the previous years operated without ozonation. Furthermore, it was determined the threshold disposal cost above which implementation of the ozone oxidation in the aerobic digestion units of similar WWTPs becomes economically convenient (about 60€t(-1) of sludge). Copyright © 2013 Elsevier Ltd. All rights reserved.

Changes in stratospheric ozone and temperature due to the eruptions of Mt. Pinatubo

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chandra, S.

1993-01-08

The impact of the Mt. Pinatubo eruptions on the total column ozone measured from the Nimbus 7 TOMS and the NOAA-11 SBUV/2 spectrometers has been studied. The ozone anomalies inferred from the two instruments agree within 1-2% in the presence of large volcanic clouds produced by Pinatubo. The Pinatubo eruptions took place on June 15-16, 1991 during the easterly phase of the quasi biennial oscillations (QBO) and as such present a different dynamical scenario for the changes in stratospheric ozone compared to the El Chichon eruptions which took place during the westerly phase of the QBO. Within a few monthsmore » after the eruptions, the total column ozone decreased by 5-6% in the tropics, 3 to 4% at mid-latitudes and 6-9% at high latitudes in the northern hemisphere. However, after the effects of QBO and interannual variability are taken into account, the decrease in the column ozone attributed to volcanic eruptions at these latitudes may not be more than 2-4% - a conclusion in general agreement with a similar study of the El Chichon effects on the stratospheric ozone. The most noticeable effect of the Pinatubo eruptions, as observed during the El Chichon period, is the breakdown of the phase relation between ozone and temperature. This is attributed to additional heating in the lower stratosphere caused by volcanic aerosols. 19 refs., 4 figs.« less

Oxidative stress responses of Daphnia magna exposed to effluents spiked with emerging contaminants under ozonation and advanced oxidation processes.

PubMed

Oropesa, Ana Lourdes; Novais, Sara C; Lemos, Marco F L; Espejo, Azahara; Gravato, Carlos; Beltrán, Fernando

2017-01-01

Integration of conventional wastewater treatments with advanced oxidation processes (AOPs) has become of great interest to remove pharmaceuticals and their metabolites from wastewater. However, application of these technologies generates reactive oxygen species (ROS) that may reach superficial waters through effluents from sewage treatment plants. The main objective of the present study was to elucidate if ROS present in real effluents after biological and then chemical (single ozonation, solar photolytic ozonation, solar photocatalytic ozonation (TiO 2 , Fe 3 O 4 ) and solar photocatalytic oxidation (TiO 2 )) treatments induce oxidative stress in Daphnia magna. For this, the activity of two antioxidant enzymes (superoxide dismutase and catalase) and the level of lipid peroxidation were determined in Daphnia. The results of oxidative stress biomarkers studied suggest that D. magna is able to cope with the superoxide ion radical (O 2 · - ) present in the treated effluent due to single ozonation by mainly inducing the antioxidant activity superoxide dismutase, thus preventing lipid peroxidation. Lethal effects (measured in terms of immobility) were not observed in these organisms after exposure to any solution. Therefore, in order to probe the ecological efficiency of urban wastewater treatments, studies on lethal and sublethal effects in D. magna would be advisable.

Modelling trends in tropical column ozone with the UKCA chemistry-climate model

NASA Astrophysics Data System (ADS)

Keeble, James; Bednarz, Ewa; Banerjee, Antara; Abraham, Luke; Harris, Neil; Maycock, Amanda; Pyle, John

2016-04-01

Trends in tropical column ozone under a number of different emissions scenarios are explored with the UM-UKCA coupled chemistry climate model. A transient 1960-2100 simulation was run following the RCP6 scenario. Tropical averaged (10S-10N) total column ozone values decrease from the 1970s, reaching a minimum around 2000, and return to their 1980 values around 2040, consistent with the use and emission of ozone depleting substances, and their later controls under the Montreal Protocol. However, when the total column is subdivided into three partial columns, extending from the surface to the tropopause, the tropopause to 30km, and 30km to 50km, significant differences to the total column trend are seen. Modelled tropospheric column values increase from 1960-2000 before remaining steady throughout the 21st Century. Lower stratospheric column values decrease rapidly from 1960-2000, remain steady until 2050 before slowly decreasing to 2100, never recovering to their 1980s values. Upper stratospheric values decrease from 1960-2000, before rapidly increasing throughout the 21st Century, recovering to 1980s values by ~2020 and are significantly increased above the 1980s values by 2100. Using a series of idealised model simulations with varying concentrations of greenhouse gases and ozone depleting substances, we assess the physical processes driving the partial column response in the troposphere, lower stratosphere and upper stratosphere, and assess how these processes change under different emissions scenarios. Finally, we present a simple, linearised model for predicting tropical column ozone values based on greenhouse gas and ozone depleting substance scenarios.

Potential of multispectral synergism for observing ozone pollution by combining IASI-NG and UVNS measurements from the EPS-SG satellite

NASA Astrophysics Data System (ADS)

Costantino, Lorenzo; Cuesta, Juan; Emili, Emanuele; Coman, Adriana; Foret, Gilles; Dufour, Gaëlle; Eremenko, Maxim; Chailleux, Yohann; Beekmann, Matthias; Flaud, Jean-Marie

2017-04-01

Present and future satellite observations offer great potential for monitoring air quality on a daily and global basis. However, measurements from currently orbiting satellites do not allow a single sensor to accurately probe surface concentrations of gaseous pollutants such as tropospheric ozone. Combining information from IASI (Infrared Atmospheric Sounding Interferometer) and GOME-2 (Global Ozone Monitoring Experiment-2) respectively in the TIR and UV spectra, a recent multispectral method (referred to as IASI+GOME-2) has shown enhanced sensitivity for probing ozone in the lowermost troposphere (LMT, below 3 km altitude) with maximum sensitivity down to 2.20 km a.s.l. over land, while sensitivity for IASI or GOME-2 alone only peaks at 3 to 4 km at the lowest.In this work we develop a pseudo-observation simulator and evaluate the potential of future EPS-SG (EUMETSAT Polar System - Second Generation) satellite observations, from new-generation sensors IASI-NG (Infrared Atmospheric Sounding Interferometer - New Generation) and UVNS (Ultraviolet Visible Near-infrared Shortwave-infrared), to observe near-surface O3 through the IASI-NG+UVNS multispectral method. The pseudo-real state of the atmosphere is provided by the MOCAGE (MOdèle de Chimie Atmosphérique à Grande Échelle) chemical transport model. We perform full and accurate forward and inverse radiative transfer calculations for a period of 4 days (8-11 July 2010) over Europe.In the LMT, there is a remarkable agreement in the geographical distribution of O3 partial columns between IASI-NG+UVNS pseudo-observations and the corresponding MOCAGE pseudo-reality. With respect to synthetic IASI+GOME-2 products, IASI-NG+UVNS shows a higher correlation between pseudo-observations and pseudo-reality, which is enhanced by about 12 %. The bias on high ozone retrieval is reduced and the average accuracy increases by 22 %. The sensitivity to LMT ozone is also enhanced. On average, the degree of freedom for signal is higher by 159 % over land (from 0.29 to 0.75) and 214 % over ocean (from 0.21 to 0.66). The mean height of maximum sensitivity for the LMT peaks at 1.43 km over land and 2.02 km over ocean, respectively 1.03 and 1.30 km below that of IASI+GOME-2. IASI-NG+UVNS also shows good retrieval skill in the surface-2 km altitude range. It is one of a kind for retrieving ozone layers of 2-3 km thickness, in the first 2-3 km of the atmosphere. IASI-NG+UVNS is expected to largely enhance the capacity to observe ozone pollution from space.

North Atlantic Oscillation modulates total ozone winter trends

NASA Astrophysics Data System (ADS)

Appenzeller, Christof; Weiss, Andrea K.; Staehelin, Johannes

2000-04-01

The North Atlantic Oscillation (NAO) is modulating the Earth's ozone shield such that the calculated anthropogenic total ozone decrease is enhanced over Europe whereas over the North Atlantic region it is reduced (for the last 30 years). Including the NAO in a statistical model suggests a more uniform chemical winter trend compared to the strong longitudinal variation reported earlier. At Arosa (Switzerland) the trend is reduced to -2.4% per decade compared to -3.2% and at Reykjavik (Iceland) it is enhanced to -3.8% compared to 0%. The revised trend is slightly below the predictions by 2D chemical models. Decadal ozone variability is linked to variations in the dynamical structure of the atmosphere, as reflected in the tropopause pressure. The latter varies in concert with the NAO index with a distinct geographical pattern.

The benefit of modeled ozone data for the reconstruction of a 99-year UV radiation time series

NASA Astrophysics Data System (ADS)

Junk, J.; Feister, U.; Helbig, A.; GöRgen, K.; Rozanov, E.; KrzyśCin, J. W.; Hoffmann, L.

2012-08-01

Solar erythemal UV radiation (UVER) is highly relevant for numerous biological processes that affect plants, animals, and human health. Nevertheless, long-term UVER records are scarce. As significant declines in the column ozone concentration were observed in the past and a recovery of the stratospheric ozone layer is anticipated by the middle of the 21st century, there is a strong interest in the temporal variation of UVERtime series. Therefore, we combined ground-based measurements of different meteorological variables with modeled ozone data sets to reconstruct time series of daily totals of UVER at the Meteorological Observatory, Potsdam, Germany. Artificial neural networks were trained with measured UVER, sunshine duration, the day of year, measured and modeled total column ozone, as well as the minimum solar zenith angle. This allows for the reconstruction of daily totals of UVERfor the period from 1901 to 1999. Additionally, analyses of the long-term variations from 1901 until 1999 of the reconstructed, new UVER data set are presented. The time series of monthly and annual totals of UVERprovide a long-term meteorological basis for epidemiological investigations in human health and occupational medicine for the region of Potsdam and Berlin. A strong benefit of our ANN-approach is the fact that it can be easily adapted to different geographical locations, as successfully tested in the framework of the COSTAction 726.

Reconstruction of daily erythemal UV radiation values for the last century - The benefit of modelled ozone

NASA Astrophysics Data System (ADS)

Junk, J.; Feister, U.; Rozanov, E.; Krzyścin, J. W.

2013-05-01

Solar erythemal UV radiation (UVER) is highly relevant for numerous biological processes that affect plants, animals, and human health. Nevertheless, long-term UVER records are scarce. As significant declines in the column ozone concentration were observed in the past and a recovery of the stratospheric ozone layer is anticipated by the middle of the 21st century, there is a strong interest in the temporal variation of UVER time series. Therefore, we combined groundbased measurements of different meteorological variables with modeled ozone data sets to reconstruct time series of daily totals of UVER at the Meteorological Observatory Potsdam, Germany. Artificial neural networks were trained with measured UVER, sunshine duration, the day of year, measured and modeled total column ozone, as well as the minimum solar zenith angle. This allows for the reconstruction of daily totals of UVER for the period from 1901 to 1999. Additionally, analyses of the long-term variations from 1901 until 1999 of the reconstructed, new UVER data set are presented. The time series of monthly and annual totals of UVER provide a long-term meteorological basis for epidemiological investigations in human health and occupational medicine for the region of Potsdam and Berlin. A strong benefit of our ANN-approach is the fact that it can be easily adapted to different geographical locations, as successfully tested in the framework of the COSTAction 726.

Evidence of Stratosphere-to-Troposphere Transport Within a Mesoscale Model and Total Ozone Mapping Spectrometer Total Ozone

NASA Technical Reports Server (NTRS)

Olsen, Mark A.; Stanford, John L.

2001-01-01

We evaluate evidence for stratospheric mass transport into, and mass remaining in, the troposphere during an intense midlatitude cyclone. Mesoscale forecast model analysis fields from the Mesoscale Analysis and Prediction System were matched with total ozone observations from the Total Ozone Measurement Spectrometer. Combined with parcel back trajectory calculations, the analyses imply that two mechanisms contributed to the mass exchange: (1) An area of dynamically induced exchange was observed on the cyclone's southern edge. Parcels originally in the stratosphere crossed the jet core and were diluted through turbulent mixing with tropospheric air; (2) Diabetic effects reduced parcel potential vorticity (PC) for trajectories traversing precipitation regions, creating a 'PV hole' signature in the center of the cyclone. Air with characteristics of ozone and water vapor found in the lower stratosphere remained in the troposphere. The strength of the latter process may be unusual. Combined with other research, these results suggest that precipitation-induced diabetic effects can significantly modify (either decreasing or increasing) parcel potential vorticity, depending on parcel trajectory configuration with respect to maximum heating regions and jet core. The diabetic heating effect on stratosphere-troposphere exchange (STE) is more important to tropopause erosion than to altering parcel trajectories. In addition, these results underline the importance of using not only PC but also chemical constituents for diagnoses of STE.

ROCOZ-A (improved rocket launched ozone sensor) for middle atmosphere ozone measurements

NASA Technical Reports Server (NTRS)

Lee, H. S.; Parsons, C. L.

1987-01-01

An improved interference filter based ultraviolet photometer (ROCOZ-A) for measuring stratospheric ozone is discussed. The payload is launched aboard a Super-Loki to a typical apogee of 70 km. The instrument measures the solar ultraviolet irradiance as it descends on a parachute. The total cumulative ozone is then calculated based on the Beer-Lambert law. The cumulative ozone precision measured in this way is 2.0% to 2.5% over an altitude range of 20 and 55 km. Results of the intercomparison with the SBUV overpass data and ROCOZ-A data are also discussed.

Application of ozonated piggery wastewater for cultivation of oil-rich Chlorella pyrenoidosa.

PubMed

Gan, Ke; Mou, Xiaoqing; Xu, Yan; Wang, Haiying

2014-11-01

Ozonated and autoclaved piggery wastewaters were compared for cultivation of oil-rich Chlorella pyrenoidosa by measuring nutrient removal from the medium and growth rate and lipid production of the microalgae. The removal rates of chemical oxygen demand, NH4(+)-N, total nitrogen and total phosphorus by C. pyrenoidosa were not influenced by both sterilisation methods. The specific growth rate and biomass of C. pyrenoidosa were determined by analysing the chlorophyll concentration for eliminating the disturbance of bacteria growth in culture system. Bacteria raised from the residue in the ozonated medium achieved 30% of the total microorganisms at the end of cultivation. They reduced the growth of C. pyrenoidosa by 10.4%, but contributed to a faster decline of the nutrient content on the first day. Lipid production and fatty acid profile did not change markedly in both sterilisation methods. The results suggest that ozonation is acceptable for piggery wastewater treatment for C. pyrenoidosa cultivation. Copyright © 2014 Elsevier Ltd. All rights reserved.

Fate of return activated sludge after ozonation: an optimization study for sludge disintegration.

PubMed

Demir, Ozlem; Filibeli, Ayse

2012-09-01

The effects of ozonation on sludge disintegration should be investigated before the application of ozone during biological treatment, in order to minimize excess sludge production. In this study, changes in sludge and supernatant after ozonation of return activated sludge were investigated for seven different ozone doses. The optimum ozone dose to avoid inhibition of ozonation and high ozone cost was determined in terms of disintegration degree as 0.05 g O3/gTS. Suspended solid and volatile suspended solid concentrations of sludge decreased by 77.8% and 71.6%, respectively, at the optimum ozone dose. Ozonation significantly decomposed sludge flocs. The release of cell contents was proved by the increase of supernatant total nitrogen (TN) and phosphorus (TP). While TN increased from 7 mg/L to 151 mg/L, TP increased from 8.8 to 33 mg/L at the optimum ozone dose. The dewaterability and filterability characteristics of the ozonated sludge were also examined. Capillary suction time increased with increasing ozone dosage, but specific resistance to filtration increased to a specific value and then decreased dramatically. The particle size distribution changed significantly as a result of floc disruption at an optimum dose of 0.05 gO3/gTS.

The signs of Antarctic ozone hole recovery.

PubMed

Kuttippurath, Jayanarayanan; Nair, Prijitha J

2017-04-03

Absorption of solar radiation by stratospheric ozone affects atmospheric dynamics and chemistry, and sustains life on Earth by preventing harmful radiation from reaching the surface. Significant ozone losses due to increases in the abundances of ozone depleting substances (ODSs) were first observed in Antarctica in the 1980s. Losses deepened in following years but became nearly flat by around 2000, reflecting changes in global ODS emissions. Here we show robust evidence that Antarctic ozone has started to recover in both spring and summer, with a recovery signal identified in springtime ozone profile and total column measurements at 99% confidence for the first time. Continuing recovery is expected to impact the future climate of that region. Our results demonstrate that the Montreal Protocol has indeed begun to save the Antarctic ozone layer.

An investigation into the causes of stratospheric ozone loss in the southern Australasian region

NASA Astrophysics Data System (ADS)

Lehmann, P.; Karoly, D. J.; Newmann, P. A.; Clarkson, T. S.; Matthews, W. A.

1992-07-01

Measurements of total ozone at Macquarie Island (55 deg S, 159 deg E) reveal statistically significant reductions of approximately twelve percent during July to September when comparing the mean levels for 1987-90 with those in the seventies. In order to investigate the possibility that these ozone changes may not be a result of dynamic variability of the stratosphere, a simple linear model of ozone was created from statistical analysis of tropopause height and isentropic transient eddy heat flux, which were assumed representative of the dominant dynamic influences. Comparison of measured and modeled ozone indicates that the recent downward trend in ozone at Macquarie Island is not related to stratospheric dynamic variability and therefore suggests another mechanism, possibly changes in photochemical destruction of ozone.

A multivariate auto-regressive combined-harmonics analysis and its application to ozone time series data

NASA Astrophysics Data System (ADS)

Yang, Eun-Su

2001-07-01

A new statistical approach is used to analyze Dobson Umkehr layer-ozone measurements at Arosa for 1979-1996 and Total Ozone Mapping Spectrometer (TOMS) Version 7 zonal mean ozone for 1979-1993, accounting for stratospheric aerosol optical depth (SAOD), quasi-biennial oscillation (QBO), and solar flux effects. A stepwise regression scheme selects statistically significant periodicities caused by season, SAOD, QBO, and solar variations and filters them out. Auto-regressive (AR) terms are included in ozone residuals and time lags are assumed for the residuals of exogenous variables. Then, the magnitudes of responses of ozone to the SAOD, QBO, and solar index (SI) series are derived from the stationary time series of the residuals. These Multivariate Auto-Regressive Combined Harmonics (MARCH) processes possess the following significant advantages: (1)the ozone trends are estimated more precisely than the previous methods; (2)the influences of the exogenous SAOD, QBO, and solar variations are clearly separated at various time lags; (3)the collinearity of the exogenous variables in the regression is significantly reduced; and (4)the probability of obtaining misleading correlations between ozone and exogenous times series is reduced. The MARCH results indicate that the Umkehr ozone response to SAOD (not a real ozone response but rather an optical interference effect), QBO, and solar effects is driven by combined dynamical radiative-chemical processes. These results are independently confirmed using the revised Standard models that include aerosol and solar forcing mechanisms with all possible time lags but not by the Standard model when restricted to a zero time lag in aerosol and solar ozone forcings. As for Dobson Umkehr ozone measurements at Arosa, the aerosol effects are most significant in layers 8, 7, and 6 with no time lag, as is to be expected due to the optical contamination of Umkehr measurements by SAOD. The QBO and solar UV effects appear in all layers 4-8, and in total ozone. In order to account for annual modulation of the equatorial winds that affects ozone at midlatitudes, a new QBO proxy is selected and applied to the Dobson Umkehr measurements at Arosa. The QBO proxy turns out to be more effective to filter the modulated ozone signals at midlatitudes than the mostly used QBO proxy, the Singapore winds at 30 mb. A statistically significant negative phase relationship is found between solar UV variation and ozone response, especially in layer 4, implying dynamical effects of solar variations on ozone at midlatitudes. Linear negative trends in ozone of -7.8 +/- 1.1 and -5.2 +/- 1.4 [%/decade +/- 2σ] are calculated in layers 7 (~35 km) and 8 (~40 km), respectively, for the period of 1979-1996, with smaller trends of -2.2 +/- 1.0, 1.8 +/- 0.9, and -1.4 +/- 1.1 in layers 6 (~30 km), 5 (~25 km), and 4 (~20 km), respectively. A trend in total ozone (layers 1 through 10) of -2.9 +/- 1.2 [%/decade +/- 2σ] is found over this same period. The aerosol effects obtained from the TOMS zonal means become significant at midlatitudes. QBO ozone contributes to the TOMS zonal means by +/-2 to 4% of their means. The negative solar ozone responses are also found at midlatitudes from the TOMS measurements. The most negative trends from TOMS zonal means are about -6.3 +/- 0.6%/decade at 40-50°N.

Ambient ozone effects on gas exchange and total non-structural carbohydrate levels in cutleaf coneflower (Rudbeckia laciniata L.) growing in Great Smoky Mountains National Park

USDA-ARS?s Scientific Manuscript database

Ozone-sensitive and -tolerant individuals of the perennial herbaceous cutleaf coneflower (Rudbeckia laciniata L.) were compared for their gas exchange characteristics and total non-structural carbohydrates in the Great Smoky Mountains National Park USA. Net photosynthesis decreased with increased f...

Impacts of rising tropospheric ozone on photosynthesis and metabolite levels on field grown soybean

USDA-ARS?s Scientific Manuscript database

The response of leaf photosynthesis and metabolite profiles to ozone (O3) exposure ranging from 37 to 116 nL L-1 was investigated in two soybean cultivars Dwight and IA3010 in the field under fully open-air conditions. Leaf photosynthesis, total non-structural carbohydrates (TNC) and total free amin...

The interaction of ozone and nitrogen dioxide in the stratosphere of East Antarctica

NASA Astrophysics Data System (ADS)

Bruchkouski, Ilya; Krasouski, Aliaksandr; Dziomin, Victar; Svetashev, Alexander

2016-04-01

At the Russian Antarctic station "Progress" (S69°23´, E76°23´) simultaneous measurements of trace gases using the MARS-B (Multi-Axis Recorder of Spectra) instrument and PION-UV spectro-radiometer for the time period from 05.01.2014 to 28.02.2014 have been performed. Both instruments were located outdoors. The aim of the measurements was to retrieve the vertical distribution of ozone and nitrogen dioxide in the atmosphere and to study their variability during the period of measurements. The MARS-B instrument, developed at the National Ozone Monitoring Research and Education Centre of the Belarusian State University (NOMREC BSU), successfully passed the procedure of international inter-comparison campaign MAD-CAT 2013 in Mainz, Germany. The instrument is able to record the spectra of scattered sunlight at different elevation angles within a maximum aperture of 1.3°. 12 elevation angles have been used in this study, including the zenith direction. Approximately 7000 spectra per day were registered in the range of 403-486 nm, which were then processed by DOAS technique aiming to retrieve differential slant columns of ozone, nitrogen dioxide and oxygen dimer. Furthermore, total nitrogen dioxide column values have been retrieved employing the Libradtran radiative transfer model. The PION-UV spectro-radiometer, also developed at NOMREC BSU, is able to record the spectra of scattered sunlight from the hemisphere in the range of 280-430 nm. The registered spectra have been used to retrieve the total ozone column values employing the Stamnes method. In this study observational data from both instruments is presented and analyzed. Furthermore, by combining analysis of this data with model simulations it is shown that decreases in nitrogen dioxide content in the upper atmosphere can be associated with increases in total ozone column values and rising of the ozone layer upper boundary. Finally, the time delay between changes in nitrogen dioxide and ozone values is calculated from the observed time series, demonstrating that changes in nitrogen dioxide content cause subsequent changes in the ozone layer. Attempt to explain this phenomenon as influence upper atmosphere on ozone layer is under discussed.

Interannual variability of the Antarctic ozone hole in a GCM. Part 2: A comparison of unforced and QBO-induced variability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shindell, D.T.; Rind, D.; Balachandran, N.

1999-06-15

Simulations were performed with the Goddard Institute for Space Studies GCM including a prescribed quasi-biennial oscillation (QBO), applied at a constant maximum value, and a physically realistic parameterization of the heterogeneous chemistry responsible for severe polar ozone loss. While the QBO is primarily a stratospheric phenomenon, in this model the QBO modulates the amount and propagation of planetary wave energy in the troposphere as well as in the stratosphere. Dynamical activity is greater in the easterly than in the unforced case, while westerly years are dynamically more quiescent. By altering zonal winds and potential vorticity, the QBO forcing changes themore » refraction of planetary waves beginning in midwinter, causing the lower-stratospheric zonal average temperatures at Southern Hemisphere high latitudes to be [approximately]3--5 K warmer in the easterly phase than in the westerly during the late winter and early spring. Ozone loss varies nonlinearly with temperature, due to the sharp threshold for formation of heterogeneous chemistry surfaces, so that the mean daily total mass of ozone depleted in this region during September was 8.7 [times] 10[sup 10] kg in the QBO easterly maximum, as compared with 12.0 [times] 10[sup 10] kg in the westerly maximum and 10.3 [times] 10[sup 10] kg in the unforced case. Through this mechanism, the midwinter divergence of the Eliassen-Palm flux is well correlated with the subsequent springtime total ozone loss (R[sup 2] = 0.6). The chemical ozone loss differences are much larger than QBO-induced transport differences in the authors' model. Inclusion of the QBO forcing also increased the maximum variability in total ozone loss from the [approximately]20% value found in the unforced runs to [approximately]50%. These large variations in ozone depletion are very similar in size to the largest observed variations in the severity of the ozone hole. The results suggest that both random variability and periodic QBO forcing are important components, perhaps explaining some of the difficulties encountered in previous attempts to correlate the severity of the ozone hole with the QBO phase.« less

Modulations of stratospheric ozone by volcanic eruptions

NASA Technical Reports Server (NTRS)

Blanchette, Christian; Mcconnell, John C.

1994-01-01

We have used a time series of aerosol surface based on the measurements of Hofmann to investigate the modulation of total column ozone caused by the perturbation to gas phase chemistry by the reaction N2O5(gas) + H2O(aero) yields 2HNO3(gas) on the surface of stratospheric aerosols. We have tested a range of values for its reaction probability, gamma = 0.02, 0.13, and 0.26 which we compared to unperturbed homogeneous chemistry. Our analysis spans a period from Jan. 1974 to Oct. 1994. The results suggest that if lower values of gamma are the norm then we would expect larger ozone losses for highly enhanced aerosol content that for larger values of gamma. The ozone layer is more sensitive to the magnitude of the reaction probability under background conditions than during volcanically active periods. For most conditions, the conversion of NO2 to HNO3 is saturated for reaction probability in the range of laboratory measurements, but is only absolutely saturated following major volcanic eruptions when the heterogeneous loss dominates the losses of N2O5. The ozone loss due to this heterogeneous reaction increases with the increasing chlorine load. Total ozone losses calculated are comparable to ozone losses reported from TOMS and Dobson data.

Variational Assimilation of GOME Total-Column Ozone Satellite Data in a 2D Latitude-Longitude Tracer-Transport Model.

NASA Astrophysics Data System (ADS)

Eskes, H. J.; Piters, A. J. M.; Levelt, P. F.; Allaart, M. A. F.; Kelder, H. M.

1999-10-01

A four-dimensional data-assimilation method is described to derive synoptic ozone fields from total-column ozone satellite measurements. The ozone columns are advected by a 2D tracer-transport model, using ECMWF wind fields at a single pressure level. Special attention is paid to the modeling of the forecast error covariance and quality control. The temporal and spatial dependence of the forecast error is taken into account, resulting in a global error field at any instant in time that provides a local estimate of the accuracy of the assimilated field. The authors discuss the advantages of the 4D-variational (4D-Var) approach over sequential assimilation schemes. One of the attractive features of the 4D-Var technique is its ability to incorporate measurements at later times t > t0 in the analysis at time t0, in a way consistent with the time evolution as described by the model. This significantly improves the offline analyzed ozone fields.

Identification of Stratospheric Waves in Ozone in the Tropics from OMI High Spectral Resolution Measurements

NASA Technical Reports Server (NTRS)

Ziemke, J. R.; Liu, X.; Bhartia, P. K.

2007-01-01

Previous studies using Total Ozone Mapping Spectrometer (TOMS) measurements have identified several types of tropical waves in the stratosphere. These waves include Kelvin waves, mixed Rossby-gravity waves, equatorial Rossby waves, and global normal modes. All of these detected waves occur when their zonal phase speeds are opposite the zonal winds in the low-mid stratosphere associated with the Quasi-biennial Oscillation (QBO). Peak-to-peak amplitudes in all cases are typically 5 DU. While total ozone data from TOMS is sensitive in detecting these tropical waves, they provide each day only a single horizontal cross-sectional map. The high spatial and spectral resolution of the Aura Ozone Monitoring Instrument (OMI) provides a unique means to evaluate 3D structure in these waves including their propagation characteristics. Ozone profiles retrieved from OMI radiances for wavelengths 270-310 nm are utilized to examine the nature of these wave disturbances extending from the lower to upper stratosphere.

Ozone depletion following future volcanic eruptions

NASA Astrophysics Data System (ADS)

Eric Klobas, J.; Wilmouth, David M.; Weisenstein, Debra K.; Anderson, James G.; Salawitch, Ross J.

2017-07-01

While explosive volcanic eruptions cause ozone loss in the current atmosphere due to an enhancement in the availability of reactive chlorine following the stratospheric injection of sulfur, future eruptions are expected to increase total column ozone as halogen loading approaches preindustrial levels. The timing of this shift in the impact of major volcanic eruptions on the thickness of the ozone layer is poorly known. Modeling four possible climate futures, we show that scenarios with the smallest increase in greenhouse gas concentrations lead to the greatest risk to ozone from heterogeneous chemical processing following future eruptions. We also show that the presence in the stratosphere of bromine from natural, very short-lived biogenic compounds is critically important for determining whether future eruptions will lead to ozone depletion. If volcanic eruptions inject hydrogen halides into the stratosphere, an effect not considered in current ozone assessments, potentially profound reductions in column ozone would result.

Atlas of TOMS ozone data collected during the Genesis of Atlantic Lows Experiment (GALE), 1986

NASA Technical Reports Server (NTRS)

Larko, David E.; Uccellini, Louis W.; Krueger, Arlin J.

1986-01-01

Data from the TOMS (Total Ozone Mapping Spectrometer) instrument aboard the Nimbus-7 satellite were collected daily in real time during the GALE (Genesis of Atlantic Lows Experiment) from January 15 through March 15, l986. The TOMS ozone data values were processed into GEMPAK format and transferred from the Goddard Space Flight Center to GALE operations in Raleigh-Durham, NC, in as little as three hours for use, in part, to direct aircraft research flights recording in situ measurements of ozone and water vapor in areas of interest. Once in GEMPAK format, the ozone values were processed into gridded form using the Barnes objective analysis scheme and contour plots of the ozone created. This atlas provides objectively analyzed contour plots of the ozone for each of the sixty days of GALE as well as four-panel presentations of the ozone analysis combined on the basis of GALE Intensive Observing Periods (IOP's).

Two-dimensional model studies of the effect of supersonic aircraft operations on the stratospheric ozone content

NASA Technical Reports Server (NTRS)

Whitten, R. C.; Borucki, W. J.; Poppoff, I. G.; Latt, L.; Widhopf, G. F.; Capone, L. A.; Reigel, C. A.

1981-01-01

For a fleet of 250 aircraft, the change in the ozone column is predicted to be very close to zero; in fact, the ozone overburden may actually increase as a result of show that above 25 to 30 km the ozone abundance decreases via catalytic destruction, but at lower heights it increases, mainly as a result of coupling with odd hydrogen species. Water vapor released in the engine exhaust is predicted to cause ozone decreases; for the hypothetical engines used in the study, the total column ozone changes due to water vapor emission largely offset the predicted ozone increases due to NOx emission. The actual effect of water vapor may be less than calculated because present models do not include thermal feedback. Feedback refers to the cooling effect of additional water vapor that would tend to slow the NOx reactions which destroy ozone.

Lightweight ozonizer for field and airborne use

NASA Astrophysics Data System (ADS)

Stone, E. J.; Caldwell, J. R.; de Waal, C.; Horvath, J. J.; Pearson, R., Jr.; Stedman, D. H.

1982-12-01

An efficient, lightweight apparatus for the production of ozone in flowing oxygen or air has been constructed and tested. The exciter is an automotive electronic ignition running from a 28-V dc power source. The discharge tube consists of coaxial conductive-coated flint glass tubing fitting into Teflon end pieces. A single such unit will produce 4% ozone in oxygen flowing at 0.2 l/min, or a maximum of 0.020 l of ozone per minute in a total flow of 1.0 l/min.

Error analysis of Dobson spectrophotometer measurements of the total ozone content

NASA Technical Reports Server (NTRS)

Holland, A. C.; Thomas, R. W. L.

1975-01-01

A study of techniques for measuring atmospheric ozone is reported. This study represents the second phase of a program designed to improve techniques for the measurement of atmospheric ozone. This phase of the program studied the sensitivity of Dobson direct sun measurements and the ozone amounts inferred from those measurements to variation in the atmospheric temperature profile. The study used the plane - parallel Monte-Carlo model developed and tested under the initial phase of this program, and a series of standard model atmospheres.

A Long Data Record (1979-2003) of Stratospheric Ozone Derived from TOMS Cloud Slicing: Comparison with SAGE and Implications for Ozone Recovery

NASA Technical Reports Server (NTRS)

Ziemke, Jerry R.; Chandra, Sushil; Bhartia, Pawan K.

2004-01-01

It is generally recognized that Stratospheric Aerosols and Gas Experiment (SAGE) stratospheric ozone data have become a standard long-record reference field for comparison with other stratospheric ozone measurements. This study demonstrates that stratospheric column ozone (SCO) derived from total ozone mapping spectrometer (TOMS) Cloud Slicing may be used to supplement SAGE data as a stand-alone long- record reference field in the tropics extending to middle and high latitudes over the Pacific. Comparisons of SAGE I1 version 6.2 SCO and TOMS version 8 Cloud Slicing SCO for 1984-2003 exhibit remarkable agreement in monthly ensemble means to within 1-3 DU (1 - 1.5% of SCO) despite being independently-calibrated measurements. An important component of our study is to incorporate these column ozone measurements to investigate long-term trends for the period 1979-2003. Our study includes Solar Backscatter Ultraviolet (SBW) version 8 measurements of upper stratospheric column ozone (i.e., zero to 32 hPa column ozone) to characterize seasonal cycles and seasonal trends in this region, as well as the lower stratosphere and troposphere when combined with TOMS SCO and total column ozone. The trend analyses suggest that most ozone reduction in the atmosphere since 1979 in mid-to-high latitudes has occurred in the Lower stratosphere below approx. 25 km. The delineation of upper and lower stratospheric column ozone indicate that trends in the upper stratosphere during the latter half of the 1979-2003 period have reduced to near zero globally, while trends in the lower stratosphere have become larger by approx. 5 DU decade%om the tropics extending to mid-latitudes in both hemispheres. For TCO, the trend analyses suggest moderate increases over the 25-year time record in the extra-tropics of both hemispheres of around 4-6 DU (Northern Hemisphere) and 6-8 DU (Southern Hemisphere).

Influence of Ar addition on ozone generation in a non-thermal plasma—a numerical investigation

NASA Astrophysics Data System (ADS)

Chen, Hsin Liang; Lee, How Ming; Chen, Shiaw Huei; Wei, Ta Chin; Been Chang, Moo

2010-10-01

A numerical model based on a dielectric barrier discharge is developed in this study to investigate the influence of Ar addition on ozone generation. The simulation results show good agreement with the experimental data, confirming the validity of the numerical model. The mechanisms regarding how the Ar addition affects ozone generation are investigated with the assistance of a numerical simulation by probing into the following two questions, (1) why the ozone concentration just slightly decreases in the low specific input energy (SIE, the ratio of discharge power to gas flow rate) region even if the inlet O2 concentration is substantially decreased and (2) why the variation of the increased rate of ozone concentration with SIE (i.e. the variation in the slope of ozone concentration versus SIE) is more significant for an O2/Ar mixture plasma. As SIE is relatively low, ozone decomposition through electron-impact and radical attack reactions is less significant because of low ozone concentration and gas temperature. Therefore, the ozone concentration depends mainly on the amount of oxygen atoms generated. The simulation results indicate that the amount of oxygen atoms generated per electronvolt for Ar concentrations of 0%, 10%, 30%, 50% and 80% are 0.178, 0.174, 0.169, 0.165 and 0.166, respectively, explaining why the ozone concentration does not decrease linearly with the inlet O2 concentration in the low SIE region. On the other hand, the simulation results show that increasing Ar concentration would lead to a lower reduced field and a higher gas temperature. The former would lead to an increase in the rate constant of e + O3 → e + O + O2 while the latter would result in a decrease in the rate constant of O + O2 + M → O3 + M and an increase in that of O3 + O → 2O2. The changes in the rate constants of these reactions would have a negative effect on ozone generation, which is the rationale for the second question.

Interannual Variability and Trends of Extratropical Ozone. Part 1; Northern Hemisphere

NASA Technical Reports Server (NTRS)

Yung, Yuk L.

2008-01-01

The authors apply principal component analysis (PCA) to the extratropical total column ozone from the combined merged ozone data product and the European Centre for Medium-Range Weather Forecasts assimilated ozone from January 1979 to August 2002. The interannual variability (IAV) of extratropical O-3 in the Northern Hemisphere (NH) is characterized by four main modes. Attributable to dominant dynamical effects, these four modes account for nearly 60% of the total ozone variance in the NH. The patterns of variability are distinctly different from those derived for total O-3 in the tropics. To relate the derived patterns of O-3 to atmospheric dynamics, similar decompositions are performed for the 30 100-Wa geopotential thickness. The results reveal intimate connections between the IAV of total ozone and the atmospheric circulation. The first two leading modes are nearly zonally symmetric and represent the connections to the annular modes and the quasi-biennial oscillation. The other two modes exhibit in-quadrature, wavenumber-1 structures that, when combined, describe the displacement of the polar vortices in response to planetary waves. In the NH, the extrema of these combined modes have preferred locations that suggest fixed topographical and land-sea thermal forcing of the involved planetary waves. Similar spatial patterns and trends in extratropical column ozone are simulated by the Goddard Earth Observation System chemistryclimate model (GEOS-CCM). The decreasing O-3 trend is captured in the first mode. The largest trend occurs at the North Pole, with values similar to-1 Dobson Unit (DU) yr(-1). There is almost no trend in tropical O-3. The trends derived from PCA are confirmed using a completely independent method, empirical mode decomposition, for zonally averaged O-3 data. The O-3 trend is also captured by mode 1 in the GEOS-CCM, but the decrease is substantially larger than that in the real atmosphere.

Global ozone observations from the UARS MLS: An overview of zonal-mean results

DOE Office of Scientific and Technical Information (OSTI.GOV)

Froidevaux, L.; Waters, J.W.; Read, W.G.

1994-10-15

Global ozone observations from the Microwave Limb Sounder (MLS) aboard the Upper Atmosphere Research Satellite (UARS) are presented, in both vertically resolved and column abundance formats. The authors review the zonal-mean ozone variations measured over the two and a half years since launch in September 1991. Well-known features such as the annual and semiannual variations are ubiquitous. In the equatorial regions, longer-term changes are believed to be related to the quasi-biennial oscillation (QBO), with a strong semiannual signal above 20 hPa. Ozone values near 50 hPa exhibit an equatorial low from October 1991 to June 1992, after which the lowmore » ozone pattern splits into two subtropical lows (possibly in connection with residual circulation changes tied to the QBO) and returns to an equatorial low in September 1993. The ozone hole development at high southern latitudes is apparent in MLS column data integrated down to 100 hPa, with a pattern generally consistent with Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) measurements of total column; the MLS data reinforce current knowledge of this lower-stratospheric phenomenon by providing a height-dependent view of the variations. The region from 30{degrees}S to 30{degrees}N (an area equal to half the global area) shows very little change in the ozone column from year to year and within each year. Finally, residual ozone values extracted from TOMS-minus-MLS column data are briefly presented as a preliminary view into the potential usefulness of such studies, with information on tropospheric ozone as an ultimate goal. 99 refs., 13 figs.« less

Ozone and allergen exposure during postnatal development alters the frequency and airway distribution of CD25+ cells in infant rhesus monkeys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miller, Lisa A.; California National Primate Research Center, University of California, Davis, CA 95616; Gerriets, Joan E.

2009-04-01

The epidemiologic link between air pollutant exposure and asthma has been supported by experimental findings, but the mechanisms are not understood. In this study, we evaluated the impact of combined ozone and house dust mite (HDM) exposure on the immunophenotype of peripheral blood and airway lymphocytes from rhesus macaque monkeys during the postnatal period of development. Starting at 30 days of age, monkeys were exposed to 11 cycles of filtered air, ozone, HDM aerosol, or ozone + HDM aerosol. Each cycle consisted of ozone delivered at 0.5 ppm for 5 days (8 h/day), followed by 9 days of filtered air;more » animals received HDM aerosol during the last 3 days of each ozone exposure period. Between 2-3 months of age, animals co-exposed to ozone + HDM exhibited a decline in total circulating leukocyte numbers and increased total circulating lymphocyte frequency. At 3 months of age, blood CD4+/CD25+ lymphocytes were increased with ozone + HDM. At 6 months of age, CD4+/CD25+ and CD8+/CD25+ lymphocyte populations increased in both blood and lavage of ozone + HDM animals. Overall volume of CD25+ cells within airway mucosa increased with HDM exposure. Ozone did not have an additive effect on volume of mucosal CD25+ cells in HDM-exposed animals, but did alter the anatomical distribution of this cell type throughout the proximal and distal airways. We conclude that a window of postnatal development is sensitive to air pollutant and allergen exposure, resulting in immunomodulation of peripheral blood and airway lymphocyte frequency and trafficking.« less

Prophylactic Ozone Administration Reduces Intestinal Mucosa Injury Induced by Intestinal Ischemia-Reperfusion in the Rat

PubMed Central

Onal, Ozkan; Yetisir, Fahri; Sarer, A. Ebru Salman; Zeybek, N. Dilara; Onal, C. Oztug; Yurekli, Banu; Celik, H. Tugrul; Sirma, Ayse; Kılıc, Mehmet

2015-01-01

Objectives. Intestinal ischemia-reperfusion injury is associated with mucosal damage and has a high rate of mortality. Various beneficial effects of ozone have been shown. The aim of the present study was to show the effects of ozone in ischemia reperfusion model in intestine. Material and Method. Twenty eight Wistar rats were randomized into four groups with seven rats in each group. Control group was administered serum physiologic (SF) intraperitoneally (ip) for five days. Ozone group was administered 1 mg/kg ozone ip for five days. Ischemia Reperfusion (IR) group underwent superior mesenteric artery occlusion for one hour and then reperfusion for two hours. Ozone + IR group was administered 1 mg/kg ozone ip for five days and at sixth day IR model was applied. Rats were anesthetized with ketamine∖xyzlazine and their intracardiac blood was drawn completely and they were sacrificed. Intestinal tissue samples were examined under light microscope. Levels of superoxide dismutase (SOD), catalase (CAT), glutathioneperoxidase (GSH-Px), malondyaldehide (MDA), and protein carbonyl (PCO) were analyzed in tissue samples. Total oxidant status (TOS), and total antioxidant capacity (TAC) were analyzed in blood samples. Data were evaluated statistically by Kruskal Wallis test. Results. In the ozone administered group, degree of intestinal injury was not different from the control group. IR caused an increase in intestinal injury score. The intestinal epithelium maintained its integrity and decrease in intestinal injury score was detected in Ozone + IR group. SOD, GSH-Px, and CAT values were high in ozone group and low in IR. TOS parameter was highest in the IR group and the TAC parameter was highest in the ozone group and lowest in the IR group. Conclusion. In the present study, IR model caused an increase in intestinal injury.In the present study, ozone administration had an effect improving IR associated tissue injury. In the present study, ozone therapy prevented intestine from ischemia reperfusion injury. It is thought that the therapeutic effect of ozone is associated with increase in antioxidant enzymes and protection of cells from oxidation and inflammation. PMID:26161005

Long-term changes in the statistical distribution of Dobson total ozone in selected Northern Hemisphere geographical regions

NASA Technical Reports Server (NTRS)

Krzyscin, Janusz W.

1994-01-01

The daily averages of total column amount of ozone taken in the period 1964-1988 at a network of 24 Dobson stations have been analyzed. Year-round data as well as summer data (May - Aug.) and winter data (Dec. - March) have been examined in the following regions: latitude bands (30 deg N - 39 deg N, 40 deg N - 52 deg N, 30 deg N - 60 deg N), North America, Europe, and Japan. To find year-to-year changes in the shape of the annual statistical distribution of total ozone (ASDTO) for these regions, we analyze trends in the following statistic characteristics of ASDTO: mean, standard deviation, median, and 10 and 90 percentiles. Time series of the statistical characteristics for the selected regions have been combined by averaging the individual stations values of these characteristics. The trends have been calculated by the multiple regression model adjusted for: the 11-year solar cycle, the Southern Oscillations effects, and for serial correlations. We have found that: a) in all regions (excluding Japan, North America), the shape of ASDTO has been drifting towards low ozone values. The drift seems to be not accompanied with a transformation in the shape of ASDTO. The drift speed (the rate of decrease in the annual means of total ozone) is of order 1-3 percent per decade (in the period 1970-1988). b) In Japan, the interannual changes in the shape of ASDTO have not been revealed. c) In North America, the drift of the year-round ASDTO (the year-round ASDTO comprises all the daily means of total ozone in a given year) has been accompanied with a transformation in the shape. The shape of the year round ASDTO becomes narrower. d) In all regions, except Japan and the band 30 deg - 39 deg N, the winter ASDTO (the winter ASDTO comprises the data taken in the period December in a given year through March next year) moves faster towards low ozone values than the summer ASDTO (the summer ASDTO comprises the data taken in the period May through August in a given year).

Studies on Stratospheric Moistening and Its Effect on Ozone Depletion in Global Perspective

NASA Astrophysics Data System (ADS)

Saha, Upal; Maitra, Animesh; Adhikari, Arpita

2012-07-01

Stratospheric moistening is the water vapor intrusion in the stratosphere which affects ozone, surface climate and stratospheric temperatures. Increased stratospheric water vapor can be an important cause of global warming as it acts to cool the stratosphere but warms the underlying troposphere. Stratospheric moistening is controlled by the transport through the tropopause region and the oxidation of methane within the stratosphere. In this article, variations of stratospheric moistening and stratospheric ozone over the whole Globe, equatorial region, mid latitudinal region, polar region are reported during the years from 2004 to 2011 using the Aura's Microwave Limb Sounder (MLS) water vapor data and Earth Probe TOMS ozone data. Maximum stratospheric moistening over the Globe is found to occur during boreal summer months although it is high during boreal winter months. The stratospheric ozone over Globe remains high during the pre-boreal summer months and decreases during the boreal winter. The mid latitudinal region has the maximum contribution of stratospheric moistening and stratospheric ozone over the Globe. Northern and southern poles have somewhat less contribution of stratospheric moistening. Stratospheric moistening over North Polar and mid latitudinal region is high during boreal summer months but over South Polar and mid latitudinal region it is high during boreal winter months. It is also found that stratospheric moistening has increased since 2004 and correspondingly stratospheric ozone concentration also decreased. This shows an anti-correlation between stratospheric moistening and stratospheric ozone, which indicates the dominance of prevailing photochemical reactions occurring in the stratosphere. Stratospheric moistening over the Indian and South Asian Monsoon regions has a global contribution of about 0.46% and 0.78% respectively. Latitudinal variation of stratospheric moistening and stratospheric ozone shows a good global inter-relation between them with a significant correlation. Atomic and molecular oxygen are produced due to photo-dissociation of the H2O molecule in the stratosphere. The stratospheric hydroxyl free radicals are responsible to deplete stratospheric ozone into oxygen via combination-recombination reaction. A decrease in stratospheric ozone concentration caused by the OH radical is predominant in the lower stratosphere but this process also extends to troposphere. Thus a decrease of ozone concentration is expected in Indian and South Asian Monsoon region, which will indicate an overview of ozone depletion in global perspective due to stratospheric moistening.

Improvements in Total Column Ozone in GEOSCCM and Comparisons with a New Ozone-Depleting Substances Scenario

NASA Technical Reports Server (NTRS)

Oman, Luke D.; Douglass, Anne R.

2014-01-01

The evolution of ozone is examined in the latest version of the Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM) using old and new ozone-depleting substances (ODS) scenarios. This version of GEOSCCM includes a representation of the quasi-biennial oscillation, a more realistic implementation of ozone chemistry at high solar zenith angles, an improved air/sea roughness parameterization, and an extra 5 parts per trillion of CH3Br to account for brominated very short-lived substances. Together these additions improve the representation of ozone compared to observations. This improved version of GEOSCCM was used to simulate the ozone evolution for the A1 2010 and the newStratosphere-troposphere Processes and their Role in Climate (SPARC) 2013 ODS scenario derived using the SPARC Lifetimes Report 2013. This new ODS scenario results in a maximum Cltot increase of 65 parts per trillion by volume (pptv), decreasing slightly to 60 pptv by 2100. Approximately 72% of the increase is due to the longer lifetime of CFC-11. The quasi-global (60degS-60degN) total column ozone difference is relatively small and less than 1Dobson unit on average and consistent with the 3-4% larger 2050-2080 average Cly in the new SPARC 2013 scenario. Over high latitudes, this small change in Cly compared to the relatively large natural variabilitymakes it not possible to discern a significant impact on ozone in the second half of the 21st century in a single set of simulations.

Naphthenic acids speciation and removal during petroleum-coke adsorption and ozonation of oil sands process-affected water.

PubMed

Gamal El-Din, Mohamed; Fu, Hongjing; Wang, Nan; Chelme-Ayala, Pamela; Pérez-Estrada, Leonidas; Drzewicz, Przemysław; Martin, Jonathan W; Zubot, Warren; Smith, Daniel W

2011-11-01

The Athabasca Oil Sands industry produces large volumes of oil sands process-affected water (OSPW) as a result of bitumen extraction and upgrading processes. Constituents of OSPW include chloride, naphthenic acids (NAs), aromatic hydrocarbons, and trace heavy metals, among other inorganic and organic compounds. To address the environmental issues associated with the recycling and/or safe return of OSPW into the environment, water treatment technologies are required. This study examined, for the first time, the impacts of pretreatment steps, including filtration and petroleum-coke adsorption, on ozonation requirements and performance. The effect of the initial OSPW pH on treatment performance, and the evolution of ozonation and its impact on OSPW toxicity and biodegradability were also examined. The degradation of more than 76% of total acid-extractable organics was achieved using a semi-batch ozonation system at a utilized ozone dose of 150 mg/L. With a utilized ozone dose of 100 mg/L, the treated OSPW became more biodegradable and showed no toxicity towards Vibrio fischeri. Changes in the NA profiles in terms of carbon number and number of rings were observed after ozonation. The filtration of the OSPW did not improve the ozonation performance. Petroleum-coke adsorption was found to be effective in reducing total acid-extractable organics by a 91%, NA content by an 84%, and OSPW toxicity from 4.3 to 1.1 toxicity units. The results of this study indicate that the combination of petroleum-coke adsorption and ozonation is a promising treatment approach to treat OSPW. Copyright © 2011 Elsevier B.V. All rights reserved.

The search for signs of recovery of the ozone layer.

PubMed

Weatherhead, Elizabeth C; Andersen, Signe Bech

2006-05-04

Evidence of mid-latitude ozone depletion and proof that the Antarctic ozone hole was caused by humans spurred policy makers from the late 1980s onwards to ratify the Montreal Protocol and subsequent treaties, legislating for reduced production of ozone-depleting substances. The case of anthropogenic ozone loss has often been cited since as a success story of international agreements in the regulation of environmental pollution. Although recent data suggest that total column ozone abundances have at least not decreased over the past eight years for most of the world, it is still uncertain whether this improvement is actually attributable to the observed decline in the amount of ozone-depleting substances in the Earth's atmosphere. The high natural variability in ozone abundances, due in part to the solar cycle as well as changes in transport and temperature, could override the relatively small changes expected from the recent decrease in ozone-depleting substances. Whatever the benefits of the Montreal agreement, recovery of ozone is likely to occur in a different atmospheric environment, with changes expected in atmospheric transport, temperature and important trace gases. It is therefore unlikely that ozone will stabilize at levels observed before 1980, when a decline in ozone concentrations was first observed.

Ozone profiles over McMurdo Station, Antarctica, during August, September, and October of 1986 - 1991

NASA Technical Reports Server (NTRS)

Deshler, Terry; Hofmann, David J.

1994-01-01

Vertical profiles of ozone and temperature have been measured at McMurdo Station, Antarctica, during the springs of 1986 to 1991, roughly every two days from 25 August to 31 October. Comparisons of temporal histories and average vertical structure for these years reveals some striking consistency in the ozone depletion process. Ozone depletion generally begins in early September, and with a half-life of 20-30 days, reaches its maximum in mid-October. The depletion occurs almost exclusively between 12 and 20 km. At the time of maximum depletion total ozone has been decreased roughly 40 percent while ozone between 12 and 20 km has been reduced 80 percent. Recovery generally begins in late October with the influx, above 20 km, of ozone rich air from the lower latitudes. From this record the worst years for ozone depletion were 1987, 1989, and 1990. A new region of ozone depletion, below 12 km, was observed in 1991, coinciding with the entrainment of a volcanic cloud into the polar vortex.

Quasi-biennial oscillation and tropical waves in total ozone

NASA Technical Reports Server (NTRS)

Ziemke, J. R.; Stanford, J. L.

1994-01-01

Westward and eastward propagating tropical waves in total ozone are investigated in 13 years (1979-1991) of version 6 total column ozone data from the Nimbus 7 total ozone mapping spectrometer (TOMS) satellite instrument. A clear synchronization between the stratospheric quasi-biennial osciallation (QBO) zonal winds and the fast (periods less than 15 days) propagating waves in tropical TOMS data is detailed. Largest total ozone wave amplitudes (about 3-6 Dobson units) occur when their phase propagation direction is primarily opposite the Singapore QBO lower-stratospheric winds. This effect is most apparent in meridionally symmetric components. Examination of specific episodes, including cross-spectral calculations with Singapore rawinsonde wind data (10-70 hPa), reveals signatures of tropically confined eastward propagating Kelvin waves of zonal wavenumbers 1-2 during the descending eastward QBO phase, consistent with acceleration of that QBO phase by Kelvin waves. The TOMS results are also consistent with possible forcing of the westward QBO wind phase by episodes of both meridionally symmetric and asymmetric westward waves. However, in contrast to the case of eastward (Kelvin) waves the strongest westward events appear to be filtered by, rather than forcing, the westward phase of the stratospheric QBO wind. These dominant westward episodes are interpreted as meridionally symmetric westward global normal modes and tropically confined equatorial-Rossby waves 2-6. The events exhibit phase and group speeds characteristic of wave dynamics rather than simple wind advection. These results underscore the utility of the long time series and excellent horizontal coverage of TOMS data for dynamical investigations in the relatively observation-poor tropical stratosphere.

Quasi-biennial oscillation and tropical waves in total ozone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ziemke, J.R.; Stanford, J.L.

1994-11-01

Westward and eastward propagating tropical waves in total ozone are investigated in 13 years (1979-1991) of version 6 total column ozone data from the Nimbus 7 total ozone mapping spectrometer (TOMS) satellite instrument. A clear synchronization between the stratospheric quasi-biennial osciallation (QBO) zonal winds and the fast (periods less than 15 days) propagating waves in tropical TOMS data is detailed. Largest total ozone wave amplitudes (about 3-6 Dobson units) occur when their phase propagation direction is primarily opposite the Singapore QBO lower-stratospheric winds. This effect is most apparent in meridionally symmetric components. Examination of specific episodes, including cross-spectral calculations withmore » Singapore rawinsonde wind data (10-70 hPa), reveals signatures of tropically confined eastward propagating Kelvin waves of zonal wavenumbers 1-2 during the descending eastward QBO phase, consistent with acceleration of that QBO phase by Kelvin waves. The TOMS results are also consistent with possible forcing of the westward QBO wind phase by episodes of both meridionally symmetric and asymmetric westward waves. However, in contrast to the case of eastward (Kelvin) waves the strongest westward events appear to be filtered by, rather than forcing, the westward phase of the stratospheric QBO wind. These dominant westward episodes are interpreted as meridionally symmetric westward global normal modes and tropically confined equatorial-Rossby waves 2-6. The events exhibit phase and group speeds characteristic of wave dynamics rather than simple wind advection. These results underscore the utility of the long time series and excellent horizontal coverage of TOMS data for dynamical investigations in the relatively observation-poor tropical stratosphere.« less

Equatorial ozone characteristics as measured at Natal (5.9 deg S, 35.2 deg W)

NASA Technical Reports Server (NTRS)

Kirchhoff, V. W. J. H.; Hilsenrath, E.; Motta, A. G.; Sahai, Y.; Medrano-B, R. A.

1982-01-01

Ozone density profiles obtained through electrochemical concentration cell (ECC) sonde measurements at Natal were analyzed. Time variations, as expected, are small. Outstanding features of the data are tropospheric densities substantially higher than those measured at other stations, and also a total ozone content that is higher than the averages given by satellite measurements.

Scientific Studies in Association with the Halogen Occultation Experiment

NASA Technical Reports Server (NTRS)

Mickley, Lorretta J.; Frederick, John E.

1996-01-01

This work examines measurements of ozone, NO, NO2, and HCl made by the Halogen Occultation Experiment (HALOE) to track chemical change in the stratosphere. In addition, HALOE observations of two long-lived species, HF and CH4, are used as tracers to distinguish between change due to transport processes and change due to chemistry. The first study investigates the response of NO(x), (NO and NO2) and ozone to the presence of large amounts of sulfate aerosol in the stratosphere following the 1991 eruption of Mount Pinatubo. As the Pinatubo aerosol cleared the atmosphere at 17 mb (about 27-28 km), the partitioning of total reactive nitrogen shifted more toward NO(x), and ozone amounts declined. This trend is opposite that observed at lower altitudes. The second study examines the chemical aftermath of severe ozone depletion over Antarctica in spring. When ozone levels drop to a threshold amount (about 1 ppm near 20 km), the partitioning of the total chlorine family shifts rapidly from reactive species to the reservoir molecule HCl. This sudden repartitioning shuts down further ozone loss and may be significant as filaments of air peel off the polar vortex and mix with mid-latitude air.

OMPS TC EDR Algorithm: Improvement and Verification

NASA Astrophysics Data System (ADS)

Novicki, M.; Sen, B.; Hao, X.; Qu, J. J.

2009-12-01

The Ozone Mapper and Profiler Suite (OMPS) is scheduled to be launched on the NPOESS Preparatory Project (NPP) platform in early 2011. The OMPS will continue monitoring ozone from space, using three instruments, namely the Total Column Mapper (heritage: TOMS), the Nadir Profiler (heritage: SBUV) and the Limb Profiler (heritage: SOLSE/LORE). The Total Column Mapper (TC) sensor images the Earth through a slit, nadir-cell horizontally spaced at 49.5 km cross-track with an along-track reporting interval of 50 km. The total field of view (FOV) cross track is 110 degrees to provide daily global coverage. The TC sensor, a grating spectrometer, provides 0.45 nm spectral sampling across the wavelength range of 300-380 nm. The calibration stability, which is essential to enable long-term ozone monitoring, is maintained by periodic observations of the Sun, using a diffuser to redirect the solar irradiance into the sensor. We describe the data analysis method being presently implemented to retrieve the total column ozone Earth Data Record (EDR) from the radiance data measured by the TC sensor. We discuss the software changes, the test data used to verify the functional performance and the test results.

Combined biodegradation and ozonation for removal of tannins and dyes for the reduction of pollution loads.

PubMed

Kanagaraj, James; Mandal, Asit Baran

2012-01-01

Tannins and dyes pose major threat to the environment by generating huge pollution problem. Biodegradation of wattle extract, chrome tannin and dye compounds using suitable fungal culture namely Aspergillus niger, Penicillium sp. were carried out. In addition to these, ozone treatment was carried out to get higher degradation rate. The results were monitored by carrying out chemical oxygen demand (COD), total organic carbon (TOC), and UV-Vis analysis. The results showed that wattle extract (vegetable tannin) gave better biodegradation rate than dye and chromium compounds. Biodegradation plus ozone showed degradation rates of 92-95%, 94-95%, and 85-87% for the wattle extract, dyes, chromium compounds, respectively. UV-Vis showed that there were no peaks observed for biodegraded samples indicating better degradation rates as compared to the control samples. FT-IR spectra analysis suggested that the formation of flavanoid derivatives, chromic oxide and NH(2) compounds during degradation of wattle extract, chromium and dye compounds, respectively, at the peaks of 1,601-1,629 cm(-1), 1,647 cm(-1), and 1,610-1,680 cm(-1). The present investigation shows that combination of biodegradation with ozone is the effective method for the removal of dyes and tannins. The biodegradation of the said compounds in combination with ozonation showed better rate of degradation than by chemical methods. The combination of biodegradation with ozone helps to reduce pollution problems in terms of COD, TOC, total dissolved solids and total suspended solids.

The impact of ozone treatment on changes in biologically active substances of cardamom seeds.

PubMed

Joanna Brodowska, Agnieszka; Śmigielski, Krzysztof; Nowak, Agnieszka; Brodowska, Katarzyna; Catthoor, Rik; Czyżowska, Agata

2014-09-01

The overall objective of this study was to develop a decontamination method against microorganisms in cardamom (Elettaria cardamomum (L.) Maton) seeds using ozone as a decontaminating agent. Ozone treatment was conducted 3 times, at 24-h intervals, and the parameters of the process were determined assuring the least possible losses of biologically active substances (essential oils and polyphenols): ozone concentration 160 to 165.0 g/m(3) ; flow rate 0.1 L/min; pressure 0.5 atm; time 30 min. After each step of decontamination, the microbiological profile of the cardamom seeds was studied, and the contaminating microflora was identified. Next to the microbiological profile, the total polyphenol content (TPC), composition of essential oils, free radical-scavenging capacity, total antioxidant capacity, ferric-reducing antioxidant power (FRAP), and LC-MS polyphenol analysis were determined. This study shows that extract from cardamom seeds after ozone treatment is characterized by a better radical scavenging activity (IC(50) = 24.18 ± 0.04 mg/mL) than the control sample (IC(50) = 31.94 ± 0.05 mg/mL). The extract from cardamom seeds after ozone treatment showed an improved FRAP activity as well (613.64 ± 49.79 mmol TE/g compared to 480.29 ± 30.91 mmol TE/g of control sample). The TPC and the total antioxidant capacity were negatively affected, respectively, 41.2% and 16.2%, compared to the control sample. © 2014 Institute of Food Technologists®

TOMS total ozone data compared with northern latitude Dobson ground stations

NASA Technical Reports Server (NTRS)

Heese, B.; Barthel, K.; Hov, O.

1994-01-01

Ozone measurements from the Total Ozone Mapping Spectrometer on the Nimbus 7 satellite are compared with ground-based measurements from five Dobson stations at northern latitudes to evaluate the accuracy of the TOMS data, particularly in regions north of 50 deg N. The measurements from the individual stations show mean differences from -2.5 percent up to plus 8.3 percent relative to TOMS measurements and two of the ground stations, Oslo and Longyearbyen, show a significant drift of plus 1.2 percent and plus 3.7 percent per year, respectively. It can be shown from nearly simultaneous measurements in two different wavelength double pairs at Oslo that at least 2 percent of the differences result from the use of the CC' wavelength double pair instead of the standard AD wavelength double pair. Since all Norwegian stations used the CC' wavelength double pair exclusively a similar error can be assumed for Tromso and Longyearbyren. A comparison between the tropospheric ozone content in TOMS data and from ECC ozonesonde measurements at Ny-Alesund and Bear Island shows that the amount of tropospheric ozone in the standard profiles used in the TOMS algorithm is too low, which leads to an error of about 2 percent in total ozone. Particularly at high solar zenith angles (greater than 80 deg), Dobson measurements become unreliable. They are up to 20 percent lower than TOMS measurements averaged over solar zenith angles of 88 deg to 89 deg.

Attenuation by clouds of UV radiation for low stratospheric ozone conditions

NASA Astrophysics Data System (ADS)

Orte, Facundo; Wolfram, Elian; Salvador, Jacobo; D'Elia, Raúl; Quiroga, Jonathan; Quel, Eduardo; Mizuno, Akira

2017-02-01

Stratospheric poor ozone air masses related to the polar ozone hole overpass subpolar regions in the Southern Hemisphere during spring and summer seasons, resulting in increases of surface Ultraviolet Index (UVI). The impact of these abnormal increases in the ultraviolet radiation could be overestimated if clouds are not taking into account. The aim of this work is to determine the percentage of cases in which cloudiness attenuates the high UV radiation that would reach the surface in low total ozone column situations and in clear sky hypothetical condition for Río Gallegos, Argentina. For this purpose, we analysed UVI data obtained from a multiband filter radiometer GUV-541 (Biospherical Inc.) installed in the Observatorio Atmosférico de la Patagonia Austral (OAPA-UNIDEF (MINDEF - CONICET)) (51 ° 33' S, 69 ° 19' W), Río Gallegos, since 2005. The database used covers the period 2005-2012 for spring seasons. Measured UVI values are compared with UVI calculated using a parametric UV model proposed by Madronich (2007), which is an approximation for the UVI for clear sky, unpolluted atmosphere and low surface albedo condition, using the total ozone column amount, obtained from the OMI database for our case, and the solar zenith angle. It is observed that ˜76% of the total low ozone amount cases, which would result in high and very high UVI categories for a hypothetical (modeled) clear sky condition, are attenuated by clouds, while 91% of hypothetical extremely high UVI category are also attenuated.

Combined System of Activated Sludge and Ozonation for the Treatment of Kraft E1 Effluent

PubMed Central

Assalin, Marcia Regina; dos Santos Almeida, Edna; Durán, Nelson

2009-01-01

The treatment of paper mill effluent for COD, TOC, total phenols and color removal was investigated using combined activated sludge-ozonation processes and single processes. The combined activated sludge-O3/pH 10 treatment was able to remove around 80% of COD, TOC and color from Kraft E1 effluent. For the total phenols, the efficiency removal was around 70%. The ozonation post treatment carried out at pH 8.3 also showed better results than the single process. The COD, TOC, color and total phenols removal efficiency obtained were 75.5, 59.1, 77 and 52.3%, respectively. The difference in the concentrations of free radical produced by activated sludge-O3/pH 10 and activated sludge-O3/pH 8.3 affected mainly the TOC and total phenol removal values. PMID:19440438

Comparison of Ozone Retrievals from the Pandora Spectrometer System and Dobson Spectrophotometer in Boulder, Colorado

NASA Technical Reports Server (NTRS)

Herman, J.; Evans, R.; Cede, A.; Abuhassan, N.; Petropavlovskikh, I.; McConville, G.

2015-01-01

A comparison of retrieved total column ozone (TCO) amounts between the Pandora #34 spectrometer system and the Dobson #061 spectrophotometer from direct-sun observations was performed on the roof of the Boulder, Colorado, NOAA building. This paper, part of an ongoing study, covers a 1-year period starting on 17 December 2013. Both the standard Dobson and Pandora TCO retrievals required a correction, TCO(sub corr) = TCO (1 + C(T)), using a monthly varying effective ozone temperature, T(sub E), derived from a temperature and ozone profile climatology. The correction is used to remove a seasonal difference caused by using a fixed temperature in each retrieval algorithm. The respective corrections C(T(sub E)) are C(sub Pandora) = 0.00333(T(sub E) - 225) and C(sub Dobson) = -0.0013(T(sub E) - 226.7) per degree K. After the applied corrections removed most of the seasonal retrieval dependence on ozone temperature, TCO agreement between the instruments was within 1% for clear-sky conditions. For clear-sky observations, both co-located instruments tracked the day-to-day variation in total column ozone amounts with a correlation of r(exp 2) = 0.97 and an average offset of 1.1 +/- 5.8 DU. In addition, the Pandora TCO data showed 0.3% annual average agreement with satellite overpass data from AURA/OMI (Ozone Monitoring Instrument) and 1% annual average offset with Suomi-NPP/OMPS (Suomi National Polar-orbiting Partnership, the nadir viewing portion of the Ozone Mapper Profiler Suite).

Comparison of ozone retrievals from the Pandora spectrometer system and Dobson spectrophotometer in Boulder, Colorado

NASA Astrophysics Data System (ADS)

Herman, J.; Evans, R.; Cede, A.; Abuhassan, N.; Petropavlovskikh, I.; McConville, G.

2015-08-01

A comparison of retrieved total column ozone (TCO) amounts between the Pandora #34 spectrometer system and the Dobson #061 spectrophotometer from direct-sun observations was performed on the roof of the Boulder, Colorado, NOAA building. This paper, part of an ongoing study, covers a 1-year period starting on 17 December 2013. Both the standard Dobson and Pandora TCO retrievals required a correction, TCOcorr = TCO (1 + C(T)), using a monthly varying effective ozone temperature, TE, derived from a temperature and ozone profile climatology. The correction is used to remove a seasonal difference caused by using a fixed temperature in each retrieval algorithm. The respective corrections C(TE) are CPandora = 0.00333(TE-225) and CDobson = -0.0013(TE-226.7) per degree K. After the applied corrections removed most of the seasonal retrieval dependence on ozone temperature, TCO agreement between the instruments was within 1 % for clear-sky conditions. For clear-sky observations, both co-located instruments tracked the day-to-day variation in total column ozone amounts with a correlation of r2 = 0.97 and an average offset of 1.1 ± 5.8 DU. In addition, the Pandora TCO data showed 0.3 % annual average agreement with satellite overpass data from AURA/OMI (Ozone Monitoring Instrument) and 1 % annual average offset with Suomi-NPP/OMPS (Suomi National Polar-orbiting Partnership, the nadir viewing portion of the Ozone Mapper Profiler Suite).

Use of ozone-biofiltration for bulk organic removal and disinfection byproduct mitigation in potable reuse applications.

PubMed

Arnold, Mayara; Batista, Jacimaria; Dickenson, Eric; Gerrity, Daniel

2018-07-01

The purpose of this research was to investigate the impacts of ozone dose and empty bed contact time (EBCT) in ozone-biofiltration systems on disinfection byproduct (DBP) formation potential. The data were used to evaluate the possibility of using DBP formation potential as an alternative guideline for total organic carbon (TOC) removal in potable reuse applications. A pilot-scale ozone-biofiltration system was operated with O 3 /TOC ratios ranging from 0.1 to 2.25 and EBCTs ranging from 2 to 20 min. The biofiltration columns contained anthracite or biological activated carbon (BAC). Bench-scale chlorination was performed using the uniform formation conditions (UFC) approach, and quenched samples were analyzed for total trihalomethanes (TTHMs) and regulated haloacetic acids (HAA5s). The data demonstrated that ozone-biofiltration achieved TOC removals ranging from ∼10 to 30%, depending on operational conditions, but biofiltration without ozone generally achieved <10% TOC removal. UFC testing demonstrated that ozone alone was efficient in transforming bulk organic matter and reducing DBP formation potential by 10-30%. The synergistic combination of ozone and biofiltration achieved average overall reductions in TTHM and HAA5 formation potential of 26% and 51%, respectively. Finally, a maximum TOC concentration of 2.0 mg/L was identified as a recommended treatment target for reliable compliance with TTHM and HAA5 regulations for potable reuse systems in the United States. Copyright © 2018 Elsevier Ltd. All rights reserved.

Effective utilization of ozone in plasma-based advanced oxidation process

NASA Astrophysics Data System (ADS)

Takeuchi, Nozomi; Ishibashi, Naoto; Sugiyama, Tsuyoshi; Kim, Hyun-Ha

2018-05-01

Decomposition of acetic acid in water was conducted using multiple plasmas generated within oxygen bubbles. Ballast capacitors were used to control the plasma input power, allowing hydrogen peroxide and ozone to be produced at different rates in each plasma by adjusting the capacitance. By using an ozone absorber connected to the plasma reactor, OH radicals, both generated by the plasmas directly and reproduced from hydrogen peroxide through reactions with ozone, could be effectively utilized for the reduction of total organic carbon (TOC). Under the condition with the highest ozone production rate, higher processing speed and energy efficiency for the TOC reduction were achieved compared with other plasma methods.

A New Method of Deriving Time-Averaged Tropospheric Column Ozone over the Tropics Using Total Ozone Mapping Spectrometer (TOMS) Radiances: Intercomparison and Analysis Using TRACE A Data

NASA Technical Reports Server (NTRS)

Kim, J. H.; Hudson, R. D.; Thompson, A. M.

1996-01-01

Error analysis of archived total 03 from total ozone mapping spectrometer (TOMS) (version 6) presented. Daily total 03 maps for the tropics, from the period October 6-21, 1992, are derived from TOMS radiances following correction for these errors. These daily maps, averaged together, show a wavelike feature, which is observed in all latitude bands, underlying sharp peaks which occur at different longitudes depending on the latitude. The wave pattern is used to derive both time-averaged stratospheric and tropospheric 03 fields. The nature of the wave pattern (stratospheric or tropospheric) cannot be determined with certainty due to missing data (no Pacific sondes, no lower stratospheric Stratospheric Aerosol and Gas Experiment (SAGE) ozone for 18 months after the Mt. Pinatubo eruption) and significant uncertainties in the corroborative satellite record in the lower stratosphere (solar backscattered ultraviolet (SBUV), microwave limb sounder (MLS)). However, the time- averaged tropospheric ozone field, based on the assumption that the wave feature is stratospheric, agrees within 10% with ultraviolet differential absorption laser Transport and Atmospheric Chemistry near the Equator-Atlantic) (TRACE A) 03 measurements from the DC-8 and with ozonesonde measurements over Brazzaville, Congo, Ascension Island, and Natal, Brazil, for the period October 6-21, 1992. The derived background (nonpolluted) Indian Ocean tropospheric ozone amount, 26 Dobson units (DU), agrees with the cleanest African ozonesonde profiles for September-October 1992. The assumption of a totally tropospheric wave (flat stratosphere) gives 38 DU above the western Indian Ocean and 15-40% disagreements with the sondes. Tropospheric column 03 is high from South America to Africa, owing to interaction of dynamics with biomass burning emissions. Comparison with fire distributions from advanced very high resolution radiometer (AVHHR) during October 1992 suggests that tropospheric 03 produced from biomass burning in South America and Africa dominates the 03 budget in the tropical southern hemisphere during the study period.

Vertical ozone characteristics in urban boundary layer in Beijing.

PubMed

Ma, Zhiqiang; Xu, Honghui; Meng, Wei; Zhang, Xiaoling; Xu, Jing; Liu, Quan; Wang, Yuesi

2013-07-01

Vertical ozone and meteorological parameters were measured by tethered balloon in the boundary layer in the summer of 2009 in Beijing, China. A total of 77 tethersonde soundings were taken during the 27-day campaign. The surface ozone concentrations measured by ozonesondes and TEI 49C showed good agreement, albeit with temporal difference between the two instruments. Two case studies of nocturnal secondary ozone maxima are discussed in detail. The development of the low-level jet played a critical role leading to the observed ozone peak concentrations in nocturnal boundary layer (NBL). The maximum of surface ozone was 161.7 ppbv during the campaign, which could be attributed to abundant precursors storage near surface layer at nighttime. Vertical distribution of ozone was also measured utilizing conventional continuous analyzers on 325-m meteorological observation tower. The results showed the NBL height was between 47 and 280 m, which were consistent with the balloon data. Southerly air flow could bring ozone-rich air to Beijing, and the ozone concentrations exceeded the China's hourly ozone standard (approximately 100 ppb) above 600 m for more than 12 h.

Inter-Annual and Decadal Changes in Tropospheric and Stratospheric Ozone

NASA Technical Reports Server (NTRS)

Ziemke, Jr. R.; Chandra, S.

2011-01-01

Ozone data beginning October 2004 from the Aura Ozone Monitoring Instrument (OMI) and Aura Microwave Limb Sounder (MLS) are used to evaluate the accuracy of the Cloud slicing technique in effort to develop long data records of tropospheric and stratospheric ozone and studying their long-term changes. Using this technique, we have produced a 32-year (1979-2010) long record of tropospheric and stratospheric ozone from the combined Total Ozone Mapping Spectrometer (Toms) and OMI. The analyses of these time series suggest that the quasi-biennial oscillation (QBO) is the dominant source of inter-annual changes of 30-40 Dobson Units (DU). Tropospheric ozone also indicates a QBO signal in the peak to peak changes varying from 2 to 7 DU. Decadal changes in global stratospheric ozone indicate a turnaround in ozone loss around mid 1990's with most of these changes occurring in the Northern Hemisphere from the subtropics to high latitudes. The trend results are generally consistent with the prediction of chemistry climate models which include the reduction of ozone destroying substances beginning in the late 1980's mandated by the Montreal Protocol.

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

NASA Astrophysics Data System (ADS)

Fernandez, Rafael Pedro; Kinnison, Douglas E.; Lamarque, Jean-Francois; Tilmes, Simone; Saiz-Lopez, Alfonso

2017-04-01

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSLBr) enhances stratospheric ozone depletion. Based on a dual set of 1960-2100 coupled chemistry-climate simulations (i.e. with and without VSLBr), we show that the maximum Antarctic ozone hole depletion increases by up to 14% when natural VSLBr are considered, in better agreement with ozone observations. The impact of the additional 5 pptv VSLBr on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of 5 million km2, which is equivalent in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSLBr in CAM-Chem does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affect the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by year 2070, and indicates that natural VSLBr chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. This work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.

Temporal Variability of Total Ozone in the Asian Region Inferred from Ground-Based and Satellite Measurement Data

NASA Astrophysics Data System (ADS)

Visheratin, K. N.; Nerushev, A. F.; Orozaliev, M. D.; Zheng, Xiangdong; Sun, Shumen; Liu, Li

2017-12-01

This paper reports investigation data on the temporal variability of total ozone content (TOC) in the Central Asian and Tibet Plateau mountain regions obtained by conventional methods, as well as by spectral, cross-wavelet, and composite analyses. The data of ground-based observation stations located at Huang He, Kunming, and Lake Issyk-Kul, along with the satellite data obtained at SBUV/SBUV2 (SBUV merged total and profile ozone data, Version 8.6) for 1980-2013 and OMI (Ozone Monitoring Instrument) and TOU (Total Ozone Unit) for 2009-2013 have been used. The average relative deviation from the SBUV/SBUV2 data is less than 1% in Kunming and Issyk-Kul for the period of 1980-2013, while the Huang He Station is characterized by an excess of the satellite data over the ground-based information at an average deviation of 2%. According to the Fourier analysis results, the distribution of amplitudes and the periods of TOC oscillations within a range of over 14 months is similar for all series analyzed. Meanwhile, according to the cross-wavelet and composite analyses results, the phase relationships between the series may considerably differ, especially in the periods of 5-7 years. The phase of quasi-decennial oscillations in the Kunming Station is close to the 11-year oscillations of the solar cycle, while in the Huang He and Issyk-Kul stations the TOC variations go ahead of the solar cycle.

The Ultraviolet Total Ozone Unit (TOU) IN-ORBIT PERFORMANCE AND CALIBRATION

NASA Astrophysics Data System (ADS)

Wang, Yongmei; Fu, Liping; Zhang, Zhongmou

The Ultraviolet Total Ozone Unit (TOU) was launched on 27 May 2008 on FY-3 meteorological satellite. The main purpose of TOU is to measure the incident solar radiation and backscattered ultraviolet radiance for retrieving daily global map of atmospheric ozone. TOU is a fixed grating and slit-array Ebert-Fastie grating spectrograph system. It has the multi-wavelengths detecting and two-dimensional scanning which enables global daily ground coverage. This paper discusses the recent working status of the instrument, including the sensitivity, measuring precision of solar irradiance, diffuser degradation and wavelength drift, and then presents the in-flight calibration and performance results.

Flight of a UV spectrophotometer aboard Galileo 2, the NASA Convair 990 aircraft

NASA Technical Reports Server (NTRS)

Sellers, B.; Hunderwadel, J. L.; Hanser, F. A.

1976-01-01

An ultraviolet interference-filter spectrophotometer (UVS) fabricated for aircraft-borne use on the DOT Climatic Impact Assessment Program (CIAP) has been successfully tested in a series of flights on the NASA Convair 990, Galileo II. UV flux data and the calculated total ozone above the flight path are reported for several of the flights. Good agreement is obtained with the total ozone as deducted by integration of an ozone sonde vertical profile obtained at Wallops Island, Virginia near the time of a CV-990 underpass. Possible advantages of use of the UVS in the NASA Global Atmospheric Sampling Program are discussed.

Towards reducing DBP formation potential of drinking water by favouring direct ozone over hydroxyl radical reactions during ozonation.

PubMed

De Vera, Glen Andrew; Stalter, Daniel; Gernjak, Wolfgang; Weinberg, Howard S; Keller, Jurg; Farré, Maria José

2015-12-15

When ozonation is employed in advanced water treatment plants to produce drinking water, dissolved organic matter reacts with ozone (O3) and/or hydroxyl radicals (OH) affecting disinfection byproduct (DBP) formation with subsequently used chlorine-based disinfectants. This study presents the effects of varying exposures of O3 and •OH on DBP concentrations and their associated toxicity generated after subsequent chlorination. DBP formation potential tests and in vitro bioassays were conducted after batch ozonation experiments of coagulated surface water with and without addition of tertiary butanol (t-BuOH, 10 mM) and hydrogen peroxide (H2O2, 1 mg/mg O3), and at different pH (6-8) and transferred ozone doses (0-1 mg/mg TOC). Although ozonation led to a 24-37% decrease in formation of total trihalomethanes, haloacetic acids, haloacetonitriles, and trihaloacetamides, an increase in formation of total trihalonitromethanes, chloral hydrate, and haloketones was observed. This effect however was less pronounced for samples ozonated at conditions favoring molecular ozone (e.g., pH 6 and in the presence of t-BuOH) over •OH reactions (e.g., pH 8 and in the presence of H2O2). Compared to ozonation only, addition of H2O2 consistently enhanced formation of all DBP groups (20-61%) except trihalonitromethanes. This proves that •OH-transformed organic matter is more susceptible to halogen incorporation. Analogously, adsorbable organic halogen (AOX) concentrations increased under conditions that favor •OH reactions. The ratio of unknown to known AOX, however, was greater at conditions that promote direct O3 reactions. Although significant correlation was found between AOX and genotoxicity with the p53 bioassay, toxicity tests using 4 in vitro bioassays showed relatively low absolute differences between various ozonation conditions. Copyright © 2015 Elsevier Ltd. All rights reserved.

A revised linear ozone photochemistry parameterization for use in transport and general circulation models: multi-annual simulations

NASA Astrophysics Data System (ADS)

Cariolle, D.; Teyssèdre, H.

2007-01-01

This article describes the validation of a linear parameterization of the ozone photochemistry for use in upper tropospheric and stratospheric studies. The present work extends a previously developed scheme by improving the 2D model used to derive the coefficients of the parameterization. The chemical reaction rates are updated from a compilation that includes recent laboratory works. Furthermore, the polar ozone destruction due to heterogeneous reactions at the surface of the polar stratospheric clouds is taken into account as a function of the stratospheric temperature and the total chlorine content. Two versions of the parameterization are tested. The first one only requires the resolution of a continuity equation for the time evolution of the ozone mixing ratio, the second one uses one additional equation for a cold tracer. The parameterization has been introduced into the chemical transport model MOCAGE. The model is integrated with wind and temperature fields from the ECMWF operational analyses over the period 2000-2004. Overall, the results show a very good agreement between the modelled ozone distribution and the Total Ozone Mapping Spectrometer (TOMS) satellite data and the "in-situ" vertical soundings. During the course of the integration the model does not show any drift and the biases are generally small. The model also reproduces fairly well the polar ozone variability, with notably the formation of "ozone holes" in the southern hemisphere with amplitudes and seasonal evolutions that follow the dynamics and time evolution of the polar vortex. The introduction of the cold tracer further improves the model simulation by allowing additional ozone destruction inside air masses exported from the high to the mid-latitudes, and by maintaining low ozone contents inside the polar vortex of the southern hemisphere over longer periods in spring time. It is concluded that for the study of climatic scenarios or the assimilation of ozone data, the present parameterization gives an interesting alternative to the introduction of detailed and computationally costly chemical schemes into general circulation models.

Iron-based catalysts for photocatalytic ozonation of some emerging pollutants of wastewater.

PubMed

Espejo, Azahara; Beltrán, Fernando J; Rivas, Francisco J; García-Araya, Juan F; Gimeno, Olga

2015-01-01

A synthetic secondary effluent containing an aqueous mixture of emerging contaminants (ECs) has been treated by photocatalytic ozonation using Fe(3+) or Fe3O4 as catalysts and black light lamps as the radiation source. For comparative purposes, ECs have also been treated by ultraviolet radiation (UVA radiation, black light) and ozonation (pH 3 and 7). With the exception of UVA radiation, O3-based processes lead to the total removal of ECs in the mixture. The time taken to achieve complete degradation depends on the oxidation process applied. Ozonation at pH 3 is the most effective technique. The addition of iron based catalysts results in a slight inhibition of the parent compounds degradation rate. However, a positive effect is experienced when measuring the total organic carbon (TOC) and the chemical oxygen demand (COD) removals. Photocatalytic oxidation in the presence of Fe(3+) leads to 81% and 88% of TOC and COD elimination, respectively, compared to only 23% and 29% of TOC and COD removals achieved by single ozonation. The RCT concept has been used to predict the theoretical ECs profiles in the homogeneous photocatalytic oxidation process studied. Treated wastewater effluent was toxic to Daphnia magna when Fe(3+) was used in photocatalytic ozonation. In this case, toxicity was likely due to the ferryoxalate formed in the process. Single ozonation significantly reduced the toxicity of the treated wastewater.

The Impact of Warm Pool El Nino Events on Antarctic Ozone

NASA Technical Reports Server (NTRS)

Hurwitz, Margaret M.; Newman, P. A.; Song, In-Sun; Frith, Stacey M.

2011-01-01

Warm pool El Nino (WPEN) events are characterized by positive sea surface temperature (SST) anomalies in the central equatorial Pacific in austral spring and summer. Previous work found an enhancement in planetary wave activity in the South Pacific in austral spring, and a warming of 3-5 K in the Antarctic lower stratosphere during austral summer, in WPEN events as compared with ENSO neutral. In this presentation, we show that weakening of the Antarctic vortex during WPEN affects the structure and magnitude of high-latitude total ozone. We use total ozone data from TOMS and OMI, as well as station data from Argentina and Antarctica, to identify shifts in the longitudinal location of the springtime ozone minimum from its climatological position. In addition, we examine the sensitivity of the WPEN-related ozone response to the phase of the quasi-biennial oscillation (QBO). We then compare the observed response to WPEN events with Goddard Earth Observing System chemistry-climate model, version 2 (GEOS V2 CCM) simulations. Two, 50-year time-slice simulations are forced by annually repeating SST and sea ice climatologies, one set representing observed WPEN events and the second set representing neutral ENSO events, in a present-day climate. By comparing the two simulations, we isolate the impact of WPEN events on lower stratospheric ozone, and furthermore, examine the sensitivity of the WPEN ozone response to the phase of the QBO.

Ambient Ozone and Emergency Department Visits for Cellulitis

PubMed Central

Szyszkowicz, Mieczysław; Porada, Eugeniusz; Kaplan, Gilaad G.; Rowe, Brian H.

2010-01-01

Objectives were to assess and estimate an association between exposure to ground-level ozone and emergency department (ED) visits for cellulitis. All ED visits for cellulitis in Edmonton, Canada, in the period April 1992–March 2002 (N = 69,547) were examined. Case-crossover design was applied to estimate odds ratio (OR, and 95% confidence interval) per one interquartile range (IQR) increase in ozone concentration (IQR = 14.0 ppb). Delay of ED visit relating to exposure was probed using 0- to 5-day exposure lags. For all patients in the all months (January–December) and lags 0 to 2 days, OR = 1.05 (1.02, 1.07). For male patients during the cold months (October–March): OR = 1.05 (1.02, 1.09) for lags 0 and 2 and OR = 1.06 (1.02, 1.10) for lag 3. For female patients in the warm months (April–September): OR = 1.12 (1.06, 1.18) for lags 1 and 2. Cellulitis developing on uncovered (more exposed) skin was analyzed separately, observed effects being stronger. Cellulitis may be associated with exposure to ambient ground level ozone; the exposure may facilitate cellulitis infection and aggravate acute symptoms. PMID:21139878

Tropical intercontinental optical measurement network of aerosol, precipitable water and total column ozone

NASA Technical Reports Server (NTRS)

Holben, B. N.; Tanre, D.; Reagan, J. A.; Eck, T. F.; Setzer, A.; Kaufman, Y. A.; Vermote, E.; Vassiliou, G. D.; Lavenu, F.

1992-01-01

A new generation of automatic sunphotometers is used to systematically monitor clear sky total column aerosol concentration and optical properties, precipitable water and total column ozone diurnally and annually in West Africa and South America. The instruments are designed to measure direct beam sun, solar aureole and sky radiances in nine narrow spectral bands from the UV to the near infrared on an hourly basis. The instrumentation and the algorithms required to reduce the data for subsequent analysis are described.

Tunable Diode Laser Heterodyne Spectrophotometry of Ozone

NASA Technical Reports Server (NTRS)

Fogal, P. F.; McElroy, C. T.; Goldman, A.; Murcray, D. G.

1988-01-01

Tunable diode laser heterodyne spectrophotometry (TDLHS) has been used to make extremely high resolution (less than 0.0005/ cm) solar spectra in the 9.6 micron ozone band. Observations have shown that a signal-to-noise ratio of 95 : 1 (35% of theoretical) for an integration time of 1/8 second can be achieved at a resolution of 0.0005 wavenumbers. The spectral data have been inverted to yield a total column amount of ozone, in good agreement with that. measured at the nearby National Oceanographic and Atmospheric Administration (NOAA) ozone monitoring facility in Boulder, Colorado.

Trends of ozone total columns and vertical distribution from FTIR observations at 8 NDACC stations around the globe

NASA Astrophysics Data System (ADS)

Vigouroux, C.; Blumenstock, T.; Coffey, M.; Errera, Q.; García, O.; Jones, N. B.; Hannigan, J. W.; Hase, F.; Liley, B.; Mahieu, E.; Mellqvist, J.; Notholt, J.; Palm, M.; Persson, G.; Schneider, M.; Servais, C.; Smale, D.; Thölix, L.; De Mazière, M.

2014-09-01

Ground-based Fourier transform infrared (FTIR) measurements of solar absorption spectra can provide ozone total columns with a precision of 2%, but also independent partial column amounts in about four vertical layers, one in the troposphere and three in the stratosphere up to about 45 km, with a precision of 5-6%. We use eight of the Network for the Detection of Atmospheric Compososition Change (NDACC) stations having a long-term time series of FTIR ozone measurements to study the total and vertical ozone trends and variability, namely: Ny-Alesund (79° N), Thule (77° N), Kiruna (68° N), Harestua (60° N), Jungfraujoch (47° N), Izaña (28° N), Wollongong (34° S) and Lauder (45° S). The length of the FTIR time-series varies by station, but is typically from about 1995 to present. We applied to the monthly means of the ozone total and four partial columns a stepwise multiple regression model including the following proxies: solar cycle, Quasi-Biennial Oscillation (QBO), El Niño-Southern Oscillation (ENSO), Arctic and Antarctic Oscillation (AO/AAO), tropopause pressure (TP), equivalent latitude (EL), Eliassen-Palm flux (EPF), and volume of polar stratospheric clouds (VPSC). At the Arctic stations, the trends are found mostly negative in the troposphere and lower stratosphere, very mixed in the middle stratosphere, positive in the upper stratosphere due to a large increase in the 1995-2003 period, and non-significant when considering the total columns. The trends for mid-latitude and subtropical stations are all non-significant, except at Lauder in the troposphere and upper stratosphere, and at Wollongong for the total columns and the lower and middle stratospheric columns; at Jungfraujoch, the upper stratospheric trend is close to significance (+0.9 ± 1.0 % decade-1). Therefore, some signs of the onset of ozone mid-latitude recovery are observed only in the Southern Hemisphere, while a few more years seems to be needed to observe it at the northern mid-latitude station.

Trends of ozone total columns and vertical distribution from FTIR observations at eight NDACC stations around the globe

NASA Astrophysics Data System (ADS)

Vigouroux, C.; Blumenstock, T.; Coffey, M.; Errera, Q.; García, O.; Jones, N. B.; Hannigan, J. W.; Hase, F.; Liley, B.; Mahieu, E.; Mellqvist, J.; Notholt, J.; Palm, M.; Persson, G.; Schneider, M.; Servais, C.; Smale, D.; Thölix, L.; De Mazière, M.

2015-03-01

Ground-based Fourier transform infrared (FTIR) measurements of solar absorption spectra can provide ozone total columns with a precision of 2% but also independent partial column amounts in about four vertical layers, one in the troposphere and three in the stratosphere up to about 45km, with a precision of 5-6%. We use eight of the Network for the Detection of Atmospheric Composition Change (NDACC) stations having a long-term time series of FTIR ozone measurements to study the total and vertical ozone trends and variability, namely, Ny-Ålesund (79° N), Thule (77° N), Kiruna (68° N), Harestua (60° N), Jungfraujoch (47° N), Izaña (28° N), Wollongong (34° S) and Lauder (45° S). The length of the FTIR time series varies by station but is typically from about 1995 to present. We applied to the monthly means of the ozone total and four partial columns a stepwise multiple regression model including the following proxies: solar cycle, quasi-biennial oscillation (QBO), El Niño-Southern Oscillation (ENSO), Arctic and Antarctic Oscillation (AO/AAO), tropopause pressure (TP), equivalent latitude (EL), Eliassen-Palm flux (EPF), and volume of polar stratospheric clouds (VPSC). At the Arctic stations, the trends are found mostly negative in the troposphere and lower stratosphere, very mixed in the middle stratosphere, positive in the upper stratosphere due to a large increase in the 1995-2003 period, and non-significant when considering the total columns. The trends for mid-latitude and subtropical stations are all non-significant, except at Lauder in the troposphere and upper stratosphere and at Wollongong for the total columns and the lower and middle stratospheric columns where they are found positive. At Jungfraujoch, the upper stratospheric trend is close to significance (+0.9 ± 1.0% decade-1). Therefore, some signs of the onset of ozone mid-latitude recovery are observed only in the Southern Hemisphere, while a few more years seem to be needed to observe it at the northern mid-latitude station.

Radical production from the interaction of ozone and PUFA as demonstrated by electron spin resonance spin-trapping techniques

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pryor, W.A.; Prier, D.G.; Church, D.F.

1981-02-01

There is considerable evidence that indicates that a fraction of the damage caused by ozone to cellular systems involves radical-mediated reactions. The most direct method for probing the mechanism by which ozone reacts with target molecules such as polyunsaturated fatty acids involves the use of electron spin resonance. In 1968, Goldstein et al. reported that ESR signals were observed when 40 ppM ozone in air is bubbled through linoleic acid. We have repeated this experiment and have performed several experiments modified from this design; in none of these do we observe ESR signals. We have studied the reaction of ozonemore » with PUFA at -78/sup 0/C using spin traps. Spin traps themselves react with ozone, but the following protocol avoids that reaction. (1) Ozone in air or oxygen-free ozone is allowed to bubble through the sample in Freon-11 in an ESR tube at -78/sup 0/C; no ESR absorption is observed. (2) Unreacted ozone is flushed out with argon or nitrogen. (3) The spin trap in Freon-11 is added to give a 0.1 M solution, still at -78/sup 0/C; no ESR signal is observed. (4) The tube is allowed to warm slowly. At about -45/sup 0/C, the ESR spectra of spin adducts appear. Using this method with methyl linoleate we observe spin adducts of alkoxy radicals and also a signal that is consistent with a carbon radical with one ..cap alpha..-H. We hypothesize that an intermediate is formed from the reaction of ozone with PUFA that is stable at -78/sup 0/Cbut decomposes to form radicals at about -45/sup 0/C. We tentatively identify the intermediate as a trioxide on the basis of analogies and its temperature profile for decomposition to radicals. It appears reasonable to suggest that the reaction(s) responsible for the production of radicals under these low-temperature conditions also occurs at room temperature. Although the low-temperature intermediate cannot be observed at ambient temperatures, radicals from it could be responsible for the effects on autoxidation that are induced by ozone.« less

The Effect of Intermittent Noise Stress on Ozone-Induced ...

EPA Pesticide Factsheets

Previous studies have established that acute exposure to air pollution increases the risk of cardiovascular dysfunction. Intrinsic factors are likely the most important determinants of how the body responds to an exposure. But data also suggests that non-environmental stressors like noise, which is a common urban public health problem, can modify and indeed worsen the response. Noise can cause obvious psychological disturbances typical of non-specific stress, but also changes that can increase the number of cardiovascular disease related mortalities. Therefore, we hypothesized that short-term exposure to noise would worsen the cardiovascular response to ozone. Male Wistar-Kyoto rats were implanted with radiotelemeters for the measurement of heart rate (HR), blood pressure (BP) and electrocardiogram (ECG) and exposed to intermittent noise (85-90 dB) for one week after which they were exposed to either ozone (0.8 ppm) or filtered air. Left ventricular functional responses to dobutamine were measured using a Millar probe as well as arrhythmic sensitivity to aconitine in a separate set of untelemetered rats 24 hours after exposure. HR and BP decreased in all telemetered animals during ozone exposure; noise caused BP and HR to increase. Baseline left ventricular pressure (LVP) was significantly higher in animals exposed to both noise and ozone when compared to no noise; furthermore those animals had the least amount of change in LVP, dP/dT max and min with increasi

Balloon-borne observations of the development and vertical structure of the Antarctic ozone hole in 1986

NASA Technical Reports Server (NTRS)

Hofmann, D. J.; Harder, J. W.; Rolf, S. R.; Rosen, J. M.

1987-01-01

The vertical distribution of ozone measured at McMurdo Station, Antarctica using balloon-borne sensors on 33 occasions during November 6, 1986 - August 25, 1986 is described. These observations suggest a highly structured cavity confined to the 12-20 km altitude region. In the 17-19 km altitude range, the ozone volume mixing ratio declined from about 2 ppm at the end of August to about 0.5 ppm by mid-October. The average decay in this region can be described as exponential with a half life of about 25 days. While total ozone, as obtained from profile integration, declined only about 35 percent, the integrated ozone between 14 and 18 km declined more than 70 percent. Vertical ozone profiles in the vortex revealed unusual structure with major features from 1 to 5 km thick which had suffered ozone depletions as great as 90 percent.

Historical Analysis and Charaterization of Ground Level Ozone for Canada and United State

NASA Astrophysics Data System (ADS)

Lin, H.; Li, H.; Auld, H.

2003-12-01

Ground-level ozone has long been recognized as an important health and ecosystem-related air quality concern in Canada and the United States. In this work we seek to understand the characteristics of ground level ozone conditions for Canada and United States to support the Ozone Annex under the Canada-U.S. Air Quality Agreement. Our analyses are based upon the data collected by Canadian National Air Pollution Surveillance (NAPS, the NAPS database has also been expanded to include U.S. EPA ground level ozone data) network. Historical ozone data from 1974 to 2002 at a total of 538 stations (253 Canadian stations and 285 U.S. stations) were statistically analyzed using several methodologies including the Canada Wide Standard (CWS). A more detailed analysis including hourly, daily, monthly, seasonally and yearly ozone concentration distributions and trends was undertaken for 54 stations.

Long-term response of total ozone content at different latitudes of the Northern and Southern Hemispheres caused by solar activity during 1958-2006 (results of regression analysis)

NASA Astrophysics Data System (ADS)

Krivolutsky, Alexei A.; Nazarova, Margarita; Knyazeva, Galina

Solar activity influences on atmospheric photochemical system via its changebale electromag-netic flux with eleven-year period and also by energetic particles during solar proton event (SPE). Energetic particles penetrate mostly into polar regions and induce additional produc-tion of NOx and HOx chemical compounds, which can destroy ozone in photochemical catalytic cycles. Solar irradiance variations cause in-phase variability of ozone in accordance with photo-chemical theory. However, real ozone response caused by these two factors, which has different physical nature, is not so clear on long-term time scale. In order to understand the situation multiply linear regression statistical method was used. Three data series, which covered the period 1958-2006, have been used to realize such analysis: yearly averaged total ozone at dif-ferent latitudes (World Ozone Data Centre, Canada, WMO); yearly averaged proton fluxes with E¿ 10 MeV ( IMP, GOES, METEOR satellites); yearly averaged numbers of solar spots (Solar Data). Then, before the analysis, the data sets of ozone deviations from the mean values for whole period (1958-2006) at each latitudinal belt were prepared. The results of multiply regression analysis (two factors) revealed rather complicated time-dependent behavior of ozone response with clear negative peaks for the years of strong SPEs. The magnitudes of such peaks on annual mean basis are not greater than 10 DU. The unusual effect -positive response of ozone to solar proton activity near both poles-was discovered by statistical analysis. The pos-sible photochemical nature of found effect is discussed. This work was supported by Russian Science Foundation for Basic Research (grant 09-05-009949) and by the contract 1-6-08 under Russian Sub-Program "Research and Investigation of Antarctica".

Reprocessed Southern Hemisphere Additional Ozonesondes (SHADOZ) Profiles (1998-2016): Method, Uncertainties and Comparisons with Satellite Total Ozone

NASA Astrophysics Data System (ADS)

Stauffer, R. M.; Thompson, A. M.; Witte, J. C.; Johnson, B.; Smit, H. G. J.

2017-12-01

The SHADOZ network was assembled to validate a new generation of ozone-monitoring satellites and to better characterize the vertical structure of tropical stratospheric and tropospheric ozone. Beginning with nine stations in 1998, more than 7000 ozone and P-T-U profiles are available from 14 stations that have operated for at least a decade. In the past two years the SHADOZ records have been reprocessed to adjust for inconsistencies caused by varying ozonesonde instruments and operating techniques. We have followed consensus-based guidelines given by the international ozonesonde community and will release new records that include first estimates of uncertainties in the ozonesonde instrument system. The ozone uncertainty is a composite of uncertainties of the individual terms in the ozone partial pressure (PO3) equation, i.e., ozone sensor current, background current, internal pump temperature, pump efficiency factors, conversion efficiency, and flow-rate. Overall, SHADOZ PO3 uncertainties are 15% or less and peak around the tropopause (15±3km) where the ozone current can approach the detection limit of the sensor. The sonde total column ozone (TCO) uncertainty is estimated at ±15 DU or 5% of typical tropical TCO. When sonde-derived TCO is compared to overpasses from the EP/TOMS, OMI and OMPS satellites that cover 1998-2016, sonde-satellite offsets at 12 stations are 2% or less (Figure), well within the uncertainty of both satellite and sonde. This agreement is much improved over our earlier SHADOZ evaluations (2003, 2007 and 2012). Reprocessing has also led to more uniform stratospheric column amounts across sites within +19 degrees latitude and reduced profile bias.

Ozone reactivity of biogenic volatile organic compound (BVOC) emissions during the Southeast Oxidant and Aerosol Study (SOAS)

NASA Astrophysics Data System (ADS)

Park, J.; Guenther, A. B.; Helmig, D.

2013-12-01

Recent studies on atmospheric chemistry in the forest environment showed that the total reactivity by biogenic volatile organic compound (BVOC) emission is still not well understood. During summer 2013, an intensive field campaign (Southeast Oxidant and Aerosol Study - SOAS) took place in Alabama, U.S.A. In this study, an ozone reactivity measurement system (ORMS) was deployed for the direct determination of the reactivity of foliage emissions. The ORMS is a newly developed measurement approach, in which a known amount of ozone is added to the ozone-free air sample stream, with the ORMS measuring ozone concentration difference between before and after a glass flask flow tube reaction vessel (2-3 minutes of residence time). Emissions were also collected onto adsorbent cartridges to investigate the discrepancy between total ozone reactivity observation and reactivity calculated from identified BVOC. Leaf and canopy level experiments were conducted by deploying branch enclosures on the three dominant tree species at the site (i.e. liquidambar, white oak, loblolly pine) and by sampling ambient air above the forest canopy. For the branch enclosure experiments, BVOC emissions were sampled from a 70 L Teflon bag enclosure, purged with air scrubbed for ozone, nitrogen oxides. Each branch experiment was performed for 3-5 days to collect at least two full diurnal cycle data. In addition, BVOCs were sampled using glass tube cartridges for 2 hours during daytime and 3 - 4 hours at night. During the last week of campaign, the inlet for the ORMS was installed on the top of scaffolding tower (~30m height). The ozone loss in the reactor showed distinct diurnal cycle for all three tree species investigated, and ozone reactivity followed patterns of temperature and light intensity.

Meteorology-induced variations in the spatial behavior of summer ozone pollution in Central California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jin, Ling; Harley, Robert A.; Brown, Nancy J.

Cluster analysis was applied to daily 8 h ozone maxima modeled for a summer season to characterize meteorology-induced variations in the spatial distribution of ozone. Principal component analysis is employed to form a reduced dimension set to describe and interpret ozone spatial patterns. The first three principal components (PCs) capture {approx}85% of total variance, with PC1 describing a general spatial trend, and PC2 and PC3 each describing a spatial contrast. Six clusters were identified for California's San Joaquin Valley (SJV) with two low, three moderate, and one high-ozone cluster. The moderate ozone clusters are distinguished by elevated ozone levels inmore » different parts of the valley: northern, western, and eastern, respectively. The SJV ozone clusters have stronger coupling with the San Francisco Bay area (SFB) than with the Sacramento Valley (SV). Variations in ozone spatial distributions induced by anthropogenic emission changes are small relative to the overall variations in ozone amomalies observed for the whole summer. Ozone regimes identified here are mostly determined by the direct and indirect meteorological effects. Existing measurement sites are sufficiently representative to capture ozone spatial patterns in the SFB and SV, but the western side of the SJV is under-sampled.« less

Ozone kinetics in low-pressure discharges: vibrationally excited ozone and molecule formation on surfaces

NASA Astrophysics Data System (ADS)

Marinov, Daniil; Guerra, Vasco; Guaitella, Olivier; Booth, Jean-Paul; Rousseau, Antoine

2013-10-01

A combined experimental and modeling investigation of the ozone kinetics in the afterglow of pulsed direct current discharges in oxygen is carried out. The discharge is generated in a cylindrical silica tube of radius 1 cm, with short pulse durations between 0.5 and 2 ms, pressures in the range 1-5 Torr and discharge currents ˜40-120 mA. Time-resolved absolute concentrations of ground-state atoms and ozone molecules were measured simultaneously in situ, by two-photon absorption laser-induced fluorescence and ultraviolet absorption, respectively. The experiments were complemented by a self-consistent model developed to interpret the results and, in particular, to evaluate the roles of vibrationally excited ozone and of ozone formation on surfaces. It is found that vibrationally excited ozone, O_3^{*} , plays an important role in the ozone kinetics, leading to a decrease in the ozone concentration and an increase in its formation time. In turn, the kinetics of O_3^{*} is strongly coupled with those of atomic oxygen and O2(a 1Δg) metastables. Ozone formation at the wall does not contribute significantly to the total ozone production under the present conditions. Upper limits for the effective heterogeneous recombination probability of O atoms into ozone are established.

Removal of the 2-mercaptobenotiazole from model wastewater by ozonation.

PubMed

Derco, Jan; Kassai, Angelika; Melicher, Michal; Dudas, Jozef

2014-01-01

The feasibility of ozonation process for 2-mercaptobenzothiazole (2-MBT) removal follows from results of ozonation of the model wastewater. Total removal of 2-MBT was observed after 20 minutes of ozonation. Very good reproducibility of repeated ozonation trials including sampling and analysis was observed. However, the majority of dissolved organic carbon (DOC) and chemical oxygen demand (COD) remained in the reaction mixture. Benzothiazole (BT) and 2-hydroxybenzothiazole (OBT) intermediates were identified during degradation of 2-MBT with ozone. In addition to the above benzothiazole derivatives, the creation of some other organic compounds follows from results of mass balance. The best fits of experimental data were obtained using the first kinetic model for 2-MBT and zero-order kinetic model for COD and DOC. The reaction time of 60 minutes can be considered as effective with regard to controlled oxidation in order to increase a portion of partially oxidized substances. Higher biodegradability and lower toxicity of ozonation products on respiration activity of activated sludge microorganisms was observed at higher ozonation time.

Removal of the 2-Mercaptobenotiazole from Model Wastewater by Ozonation

PubMed Central

Kassai, Angelika

2014-01-01

The feasibility of ozonation process for 2-mercaptobenzothiazole (2-MBT) removal follows from results of ozonation of the model wastewater. Total removal of 2-MBT was observed after 20 minutes of ozonation. Very good reproducibility of repeated ozonation trials including sampling and analysis was observed. However, the majority of dissolved organic carbon (DOC) and chemical oxygen demand (COD) remained in the reaction mixture. Benzothiazole (BT) and 2-hydroxybenzothiazole (OBT) intermediates were identified during degradation of 2-MBT with ozone. In addition to the above benzothiazole derivatives, the creation of some other organic compounds follows from results of mass balance. The best fits of experimental data were obtained using the first kinetic model for 2-MBT and zero-order kinetic model for COD and DOC. The reaction time of 60 minutes can be considered as effective with regard to controlled oxidation in order to increase a portion of partially oxidized substances. Higher biodegradability and lower toxicity of ozonation products on respiration activity of activated sludge microorganisms was observed at higher ozonation time. PMID:24578619

Ground-based microwave radiometry to determine stratospheric and mesospheric ozone profiles

NASA Astrophysics Data System (ADS)

Lobsiger, E.

1987-05-01

From April 1984 to April 1985 a microwave radiometer was operated at Bern measuring the thermal emission of the rotational ozone transition at 142.2 GHz to determine stratospheric and mesospheric ozone abundances in the range 25-75 km altitude. From a total of 334 retrieved daytime profiles, monthly mean ozone partial pressures for Umkehr layers 6-10 were calculated. On this basis ozone variations compare favorably with Umkehr data from the nearby Arosa station and with a monthly zonal mean model compiled from satellite data by Keating and Young (1985). From the microwave data, an annual mean ozone distribution was determined. The method retrieves somewhat larger ozone volume mixing ratios between 25 and 30 km altitude. For the rest of the measurement range of the sensor there is good agreement with 20-year annual mean ozone values from Arosa, with the Krueger and Minzner profile and with the respective annual mean data given by Keating and Young.

Creating a Satellite-Based Record of Tropospheric Ozone

NASA Technical Reports Server (NTRS)

Oetjen, Hilke; Payne, Vivienne H.; Kulawik, Susan S.; Eldering, Annmarie; Worden, John; Edwards, David P.; Francis, Gene L.; Worden, Helen M.

2013-01-01

The TES retrieval algorithm has been applied to IASI radiances. We compare the retrieved ozone profiles with ozone sonde profiles for mid-latitudes for the year 2008. We find a positive bias in the IASI ozone profiles in the UTLS region of up to 22 %. The spatial coverage of the IASI instrument allows sampling of effectively the same air mass with several IASI scenes simultaneously. Comparisons of the root-mean-square of an ensemble of IASI profiles to theoretical errors indicate that the measurement noise and the interference of temperature and water vapour on the retrieval together mostly explain the empirically derived random errors. The total degrees of freedom for signal of the retrieval for ozone are 3.1 +/- 0.2 and the tropospheric degrees of freedom are 1.0 +/- 0.2 for the described cases. IASI ozone profiles agree within the error bars with coincident ozone profiles derived from a TES stare sequence for the ozone sonde station at Bratt's Lake (50.2 deg N, 104.7 deg W).

Diverse policy implications for future ozone and surface UV in a changing climate

NASA Astrophysics Data System (ADS)

Butler, A. H.; Daniel, J. S.; Portmann, R. W.; Ravishankara, A. R.; Young, P. J.; Fahey, D. W.; Rosenlof, K. H.

2016-06-01

Due to the success of the Montreal Protocol in limiting emissions of ozone-depleting substances, concentrations of atmospheric carbon dioxide, nitrous oxide, and methane will control the evolution of total column and stratospheric ozone by the latter half of the 21st century. As the world proceeds down the path of reducing climate forcing set forth by the 2015 Conference of the Parties to the United Nations Framework Convention on Climate Change (COP 21), a broad range of ozone changes are possible depending on future policies enacted. While decreases in tropical stratospheric ozone will likely persist regardless of the future emissions scenario, extratropical ozone could either remain weakly depleted or even increase well above historical levels, with diverse implication for ultraviolet (UV) radiation. The ozone layer’s dependence on future emissions of these gases creates a complex policy decision space for protecting humans and ecosystems, which includes unexpected options such as accepting nitrous oxide emissions in order to maintain historical column ozone and surface UV levels.

Ozone decrease outside Arctic polar vortex due to polar vortex processing in 1997

NASA Astrophysics Data System (ADS)

Akiyoshi, H.; Sugata, S.; Yoshiki, M.; Sugita, T.

2006-11-01

We examine the effect of polar vortex processing on ozone concentrations outside the 1997 Arctic polar vortex. The Arctic vortex in this year was well isolated, cold, and circumpolar, and it broke up unusually late. However, time threshold diagnostics (TTD) analysis using a middle vortex boundary defined by the first derivative of the equivalent latitude gradient of potential vorticity and calculations using the nudging chemical transport model (CTM) of the Center for Climate System Research/National Institute for Environmental Studies (CCSR/NIES) show that there were intermittently several relatively large transport events from the vortex to the outside region in the lower stratosphere, with timescales and spatial scales that can be resolved at T42 CTM horizontal resolution (2.8° by 2.8° grid). These intermittent outflow events of polar air are also identified in TTD analysis using an outer vortex boundary defined by the second derivative of potential vorticity and a boundary defined by the N2O concentration. These intermittent events had a significant effect on the ozone concentration outside the vortex near the boundary in this year. A CTM calculation with a polar chemical ozone tracer shows that the effect on the ozone concentration outside the polar vortex near the vortex boundary in the equivalent latitude band of 55°-65°N and 450 K is 0.3 ppmv (15-20% of the ozone concentration at this height) and that on the total ozone is 12-15 Dobson units (1 DU = 0.001 atm cm) (3-4% of the total ozone) by the end of April just before the final vortex breakup. The effect in the equivalent latitude band of 30°-60°N is much smaller, with a reduction of 2 DU at the end of March and 4 DU by the end of April (less than 1% of the total ozone). The effect is about the half if we use the inner boundary or a boundary of 73°N equivalent latitude for the polar tracer calculations. The CTM calculations also show that these polar vortex processing effects might be masked at midlatitudes by the local gas phase chemical ozone production/loss reactions after mid-April at 450 K and earlier than those at 500 K.

Distribution and urban-suburban differences in ground-level ozone and its precursors over Shenyang, China

NASA Astrophysics Data System (ADS)

Liu, Ningwei; Ren, Wanhui; Li, Xiaolan; Ma, Xiaogang; Zhang, Yunhai; Li, Bingkun

2018-03-01

Hourly mixing ratio data of ground-level ozone and its main precursors at ambient air quality monitoring sites in Shenyang during 2013-2015 were used to survey spatiotemporal variations in ozone. Then, the transport of ozone and its precursors among urban, suburban, and rural sites was examined. The correlations between ozone and some key meteorological factors were also investigated. Ozone and O x mixing ratios in Shenyang were higher during warm seasons and lower during cold ones, while ozone precursors followed the opposite cycle. Ozone mixing ratios reached maximum and minimum values in the afternoon and morning, respectively, reflecting the significant influence of photochemical production during daytime and depletion via titration during nighttime. Compared to those in downtown Shenyang, ozone mixing ratios were higher and the occurrence of peak values were later in suburban and rural areas downwind of the prevailing wind. The differences were most significant in summer, when the ozone mixing ratios at one suburban downwind site reached a maximum value of 35.6 ppb higher than those at the downtown site. This suggests that photochemical production processes were significant during the transport of ozone precursors, particularly in warm seasons with sufficient sunlight. Temperature, total radiation, and wind speed all displayed positive correlations with ozone concentration, reflecting their important role in accelerating ozone formation. Generally, the correlations between ozone and meteorological factors were slightly stronger at suburban sites than in urban areas, indicating that ozone levels in suburban areas were more sensitive to these meteorological factors.

Oxidation and ozonation of waste activated sludge.

PubMed

Mines, Richard O; Northenor, C Brett; Murchison, Mitchell

2008-05-01

In this bench-scale study, the treatment of waste activated sludge (WAS) was evaluated using aerobic digestion and ozonation. Two, 2-L batch digesters, one aerated and the other one ozonated, were operated for 30 days in each phase of the study. The aerated digester simulated the aerobic digestion process and served as control to the ozonated digester. In Phase I, the aerated digester was supplied 810 mg O(2) min(- 1), whereas, the ozonated digester was supplied 0.88 mg O(3) min(- 1). In Phase II, the oxygenation rate to the aerobic digester was increased to 1,200 mg O(2) min(- 1) while the ozonation rate was reduced to 0.44 mg O(3) min(- 1). Ozone was more effective than air at oxidizing and reducing both total solids (TS) and volatile solids (VS) in the WAS. TS removals of 50% and 56% were observed for the ozonated digester versus TS removals of 23% and 35% for the aerated digester. VS removals of 40% and 42% were observed for the aerobic digester versus 57% and 74% for the ozonated digester. Aerobic digestion barely met the 38% reduction in VS required by the U.S. Environmental Protection Agency (EPA). The degradation rate constant (K(d)) based on degradable TS for the ozonated digester varied from 0.082 to 0.11 days(- 1) and from 0.067 to 0.09 days(- 1) for the aerobic digester. Total chemical oxygen demand (TCOD) removal in the aerobic digester increased from 30% to 40% from Phase I to Phase II. TCOD removal increased slightly from 57% to 58% in the ozonated digester from Phase I to Phase II. Soluble chemical oxygen demand (SCOD) concentrations in the sludge supernatant increased with digestion time, especially in the ozonated digester. Approximately 0.12 to 0.22 mg SCOD was produced per mg of TS destroyed during ozonation. The specific oxygen uptake rate (SOUR) was consistently below the EPA standard of 1.5 mg O(2) per hr per g TS, indicating that the sludge was well stabilized. The average quantity of oxygen required during aerobic digestion was 1.53 g O(2) per g of TS destroyed. Actual ozone consumption rates were 0.57 mg O(3) per mg TS destroyed and 1.09 mg O(3) per mg TS destroyed for Phase II and Phase I, respectively.

Discoloration and detoxicification of a Congo red dye solution by means of ozone treatment for a possible water reuse.

PubMed

Khadhraoui, M; Trabelsi, H; Ksibi, M; Bouguerra, S; Elleuch, B

2009-01-30

The objective of this study was to investigate the degradation and mineralization of an azo-dye, the Congo red, in aqueous solutions using ozone. Phytotoxicity and the inhibitory effects on the microbial activity of the raw and the ozonated solutions were also carried out with the aim of water reuse and environment protection. Decolorization of the aqueous solutions, disappearance of the parent compound, chemical oxygen demand (COD) and total organic carbon (TOC) removal were the main parameters monitored in this study. To control the mineralization of the Congo red, pH of the ozonated solution and heteroatoms released from the mother molecule such NH(4)(+), NO(3)(-) and SO(4)(2-) were determined. It was concluded that ozone by itself is strong enough to decolorize these aqueous solutions in the early stage of the oxidation process. Nonetheless, efficient mineralization had not been achieved. Significant drops in COD (54%) were registered. The extent of TOC removal was about 32%. Sulfur heteroatom was totally oxidized to SO(4)(2-) ions while the central -NN- azo ring was partially converted to NH(4)(+) and NO(3)(-). Results of the kinetic studies showed that ozonation of the selected molecule was a pseudo-first-order reaction with respect to dye concentration. The obtained results also demonstrate that ozone process reduced the phytotoxicity of the raw solution and enhanced the biodegradability of the treated azo-dyes-wastewater. Hence, this show that ozone remains one of the effective technologies for the discoloration and the detoxification of organic dyes in wastewater.

Total ozone changes over Eurasia since 1973 based on reevaluated filter ozonometer data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bojkov, R.D.; Fioletov, V.E.; Shalamjansky, A.M.

1994-11-01

Since the early 1960s, on the vast territory of the former USSR, 45 stations have been in continuous operation, utilizing the broadband filter M-83 ozonometer. The quality of the ozone data during the first decade was unsatisfactory. After 1972 an improved version of the ozonometer was introduced together with improved quality control practices, including methodology of observations. The more reliable data of 1973 through March 1994 have been rigorously reexamined by applying variability analysis, comparison with lower-stratosphere temperatures and/or nearby Dobson stations, and overpassing Total Ozone Mapping Spectrometer (TOMS) for identifying concurrence or discrepancies. These control procedures together with themore » information on instrument relocation and calibrations made it possible to reevaluate the record of all 45 stations. The accuracy of the improved ozonometer data is about 3% for direct Sun measurements and approximately 5% for zenith sky observations; although not so good as that of the Dobson, in the long run it provides consistent ozone data sets. This data set is now made available to the World Ozone Data Center (WO3DC), Toronto. Thus for the first time, based on a 21-year long record, information is deduced on the differences in the ozone annual cycle between Eastern Siberia and the European part, on the strong appearance of quasi-biennial oscillation (QBO) signals especially pronounced as ozone deficiency during the western phase of the QBO, on the ozone variability, and on the long-term changes over the huge territory from Central Europe to the Far East.« less

Decadal changes in summertime reactive oxidized nitrogen and surface ozone over the Southeast United States

NASA Astrophysics Data System (ADS)

Li, Jingyi; Mao, Jingqiu; Fiore, Arlene M.; Cohen, Ronald C.; Crounse, John D.; Teng, Alex P.; Wennberg, Paul O.; Lee, Ben H.; Lopez-Hilfiker, Felipe D.; Thornton, Joel A.; Peischl, Jeff; Pollack, Ilana B.; Ryerson, Thomas B.; Veres, Patrick; Roberts, James M.; Neuman, J. Andrew; Nowak, John B.; Wolfe, Glenn M.; Hanisco, Thomas F.; Fried, Alan; Singh, Hanwant B.; Dibb, Jack; Paulot, Fabien; Horowitz, Larry W.

2018-02-01

Widespread efforts to abate ozone (O3) smog have significantly reduced emissions of nitrogen oxides (NOx) over the past 2 decades in the Southeast US, a place heavily influenced by both anthropogenic and biogenic emissions. How reactive nitrogen speciation responds to the reduction in NOx emissions in this region remains to be elucidated. Here we exploit aircraft measurements from ICARTT (July-August 2004), SENEX (June-July 2013), and SEAC4RS (August-September 2013) and long-term ground measurement networks alongside a global chemistry-climate model to examine decadal changes in summertime reactive oxidized nitrogen (RON) and ozone over the Southeast US. We show that our model can reproduce the mean vertical profiles of major RON species and the total (NOy) in both 2004 and 2013. Among the major RON species, nitric acid (HNO3) is dominant (˜ 42-45 %), followed by NOx (31 %), total peroxy nitrates (ΣPNs; 14 %), and total alkyl nitrates (ΣANs; 9-12 %) on a regional scale. We find that most RON species, including NOx, ΣPNs, and HNO3, decline proportionally with decreasing NOx emissions in this region, leading to a similar decline in NOy. This linear response might be in part due to the nearly constant summertime supply of biogenic VOC emissions in this region. Our model captures the observed relative change in RON and surface ozone from 2004 to 2013. Model sensitivity tests indicate that further reductions of NOx emissions will lead to a continued decline in surface ozone and less frequent high-ozone events.

Ozone and sulfur dioxide effects on tall fescue. II. Alteration of quality constituents. [Festuca arundinacea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flagler, R.B.; Youngner, V.B.

A greenhouse study was conducted to determine whether ozone (O/sub 3/) and sulfur dioxide (SO/sub 2/) might alter forage quality parameters of tall fescue (Festuca arundinacea Schreb. Alta). Plants were exposed weekly to four O/sub 3/ treatments, 0, 0.10, 0.20, and 0.30 ..mu..L L/sup -1/; with or without 0.10 ..mu..L L/sup -1/ SO/sub 2/, 6 h d/sup -1/ for 12 weeks. Ozone had a much greater impact on forage quality than did SO/sub 2/. Ozone increased protein content on a g kg/sup -1/ basis and decreased protein on a weight per plant basis. Ozone reduced crude fat, crude fiber, andmore » total nonstructural carbohydrate contents of the forage. Crude ash content increased due to O/sub 3/ exposure. On a weight per plant basis, O/sub 3/ decreased the forage concentration of Ca, Mg, and P. Ozone increased Ca concentration of herbage. Sulfur dioxide increased ash content of the forage. Phosphorus concentration and weight per plant of Mg and P were all reduced by SO/sub 2/ Significant pollutant interactions occurred for crude fiber, crude ash, total Mg, and total P contents of forage. While treatments resulted in some apparent increases in forage quality, these were at the expense of yield. The most adverse effects on forage quality were an increase in ash content which resulted from an interaction of SO/sub 2/ with O/sub 3/, and a reduction in soluble carbohydrate content of shoots due to O/sub 3/.« less

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

NASA Astrophysics Data System (ADS)

Fernandez, Rafael P.; Kinnison, Douglas E.; Lamarque, Jean-Francois; Tilmes, Simone; Saiz-Lopez, Alfonso

2017-02-01

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSLBr) enhances stratospheric ozone depletion. Based on a dual set of 1960-2100 coupled chemistry-climate simulations (i.e. with and without VSLBr), we show that the maximum Antarctic ozone hole depletion increases by up to 14 % when natural VSLBr are considered, which is in better agreement with ozone observations. The impact of the additional 5 pptv VSLBr on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of ˜ 5 million km2, which is equivalent in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSLBr in CAM-Chem (Community Atmosphere Model with Chemistry, version 4.0) does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affects the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by the year 2070 and indicates that natural VSLBr chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. This work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.

Recent Changes in Tropospheric Ozone in the Tropics

NASA Technical Reports Server (NTRS)

Chandra, S.; Ziemke, J. R.; Einaudi, Franco (Technical Monitor)

2000-01-01

This paper presents a detailed characterization of tropical tropospheric column ozone variability on time scales varying from a few days to a solar cycle. The study is based on more than 20 years (1979 to the present) of tropospheric column ozone time series derived from the convective cloud differential (CCD) method using total ozone mapping spectrometer (TOMS) data. Results indicate three distinct regions in the tropics with distinctly three different zonal characteristics related to seasonal, interannual and solar variabilities. These three regions are the eastern Pacific, Atlantic, and western Pacific. Tropospheric column ozone in the Atlantic region peaks at about the same time (September-October) from 20 N to 20 S. The amplitude of the annual cycle, however, varies from about 3 to 6 Dobson unit (DU) from north to south of the equator. In comparison, the annual cycle in both the eastern and western Pacific is generally week and the phase varies from peak values in March and April in the northern hemisphere to September and October in the southern hemisphere. The interannual pattern in the three regions are also very different. The Atlantic region indicates a quasi biennial oscillation in the tropospheric column ozone which is out of phase with the stratospheric ozone. This is consistent with the photochemical control of this region caused by high pollution and high concentration of ozone producing precursors. The observed pattern, however, does not seem to be related to the interannual variability in ozone precursors related to biomass burning. Instead, it appears to be a manifestation of the UV modulation of upper tropospheric chemistry on a QBO time scale caused by stratospheric ozone. During El Nino events, there is anomalously low ozone in the eastern Pacific and high values in the western Pacific indicating the effects of convectively driven transport. The observed increase of 10-20 DU in tropospheric column ozone in the Indonesian region in the western Pacific during the recent 1997-1998 El Nino was associated with large-scale forest fires which may have contributed 5-10 DU of the total increase.

Potential of the multispectral synergism for observing ozone pollution combining measurements of IASI-NG and UVNS onboard EPS-SG

NASA Astrophysics Data System (ADS)

Costantino, Lorenzo; Cuesta, Juan; Emili, Emanuele; Foret, Gilles; Dufour, Gaëlle; Eremenko, Maxim; Chailleux, Yohann; Beekmann, Matthias; Flaud, Jean-Marie

2016-04-01

Current and future satellite observations offer a great potential for monitoring air quality on daily and global basis. However, measurements from currently in orbit sensors offer a limited capacity to probe surface concentrations of gaseous pollutants such as tropospheric ozone. Using single-band approaches based on IASI spaceborne thermal infrared measurements, only ozone down to the lower troposphere (3-4 km of altitude at lowest) may be observed (Eremenko et al., 2008). A recent multispectral method combining IASI and GOME-2 (both onboard MetOp satellites) spectra, respectively from the IR and UV, has shown enhanced sensitivity for probing ozone at the lowermost troposphere, but with maximum sensitivity around 2 km at lowest (Cuesta et al., 2013). Future spatial missions will be launched in the upcoming years, such as EPS-SG, carrying new generation sensors like IASI-NG and UVNS that will enhance the capacity to observe ozone pollution, and particularly when combining them through a multispectral synergism. This work presents an analysis of the potential of the multispectral synergism of IASI-NG and UVNS future spaceborne measurements for observing ozone pollution, performed in the framework of SURVEYOZON project (funded by the French Space Agency, CNES). For this, we develop a simulator of synthetic multispectral retrievals or pseudo-observations (referred as OSSE, Observing System Simulation Experiment) derived from IASI-NG+UVNS that will be compared to those from IASI+GOME2. In the first step of the OSSE, we create a pseudo-reality with simulations from the chemical-transport model MOCAGE (provided by CERFACS laboratory), where real O3 data from IASI and surface network stations have been assimilated for a realistic representation of ozone variability at the surface and the free troposphere. We focus on the high pollution event occurred in Europe on 10 July 2010. We use the coupled algorithms KOPRA+VLIDORT to simulate the spectra emitted, scattered and absorbed by the surface and atmospheric components and simulate the spectral measurements of IASI and GOME2. These spectra as used to retrieve O3 profiles that are then compared with the pseudo-reality. These pseudo-observations enable us to estimate the performances and associated errors of the innovative multispectral methodology implemented with IASI-NG (with finer spectral resolution and lower noise than IASI) and UVNS (with lower noise and finer horizontal resolution than GOME-2). In a second step, these pseudo-observations will be used to quantify the improvement in regional air pollution forecasts, when assimilating this new multispectral O3 product in a second chemical transport model (CHIMERE) independent from MOCAGE.

Detection and measurement of total ozone from stellar spectra: Paper 2. Historic data from 1935 1942

NASA Astrophysics Data System (ADS)

Griffin, R. E. M.

2005-10-01

Atmospheric ozone columns are derived from historic stellar spectra observed between 1935 and 1942 at Mount Wilson Observatory, California. Comparisons with contemporary measurements in the Arosa database show a generally close correspondence. The results of the analysis indicate that astronomy's archives command considerable potential for investigating the natural levels of ozone and its variability during the decades prior to anthropogenic interference.

[Effects of elevated ozone concentrations on enzyme activities and organic acids content in wheat rhizospheric soil.

PubMed

Yin, Wei Qin; Jing, Hao Qi; Wang, Ya Bo; Wei, Si Yu; Sun, Yue; Wang, Sheng Sen; Wang, Xuai Zhi

2018-02-01

The elevated concentration of tropospheric ozone (O 3 ) is an important global climate change driver, with adverse impacts on soil ecological environment and crop growth. In this study, a pot experiment was carried out in an open top chamber (OTC), to investigate the effects of elevated ozone concentration on soil enzyme activities (catalase, polyphenol oxidase, dehydrogenase and invertase), organic acids contents (oxalic acid, citric acid and malic acid) at different growth stages (tillering, jointing, heading and ripening stages) of wheat, and combined with the rhizospheric soil physicochemical properties and plant root characteristics to analyze the underlying reasons. The results showed that, elevated ozone concentration increased soil catalase, polyphenol oxidase, dehydrogenase and invertase activities at wheat ripening period to different degrees, with the effects on the activities of catalase and polyphenol oxidase being statistically significant. At the heading stage, activities of dehydrogenase and invertase were significantly increased by up to 76.7%. At the ripening stage, elevated ozone concentration significantly increased the content of citric acid and malic acid and redox potential (Eh) in rhizospheric soil, but reduced soil pH, electrical conductivity, total carbon and nitrogen. For root characteristics, elevated ozone concentrations significantly reduced the wheat root biomass, total root length and root surface area but increased the average root diameter.

Trend analysis of the long-term Swiss ozone measurements

NASA Technical Reports Server (NTRS)

Staehelin, Johannes; Bader, Juerg; Gelpke, Verena

1994-01-01

Trend analyses, assuming a linear trend which started at 1970, were performed from total ozone measurements from Arosa (Switzerland, 1926-1991). Decreases in monthly mean values were statistically significant for October through April showing decreases of about 2.0-4 percent per decade. For the period 1947-91, total ozone trends were further investigated using a multiple regression model. Temperature of a mountain peak in Switzerland (Mt. Santis), the F10.7 solar flux series, the QBO series (quasi biennial oscillation), and the southern oscillation index (SOI) were included as explanatory variables. Trends in the monthly mean values were statistically significant for December through April. The same multiple regression model was applied to investigate the ozone trends at various altitudes using the ozone balloon soundings from Payerne (1967-1989) and the Umkehr measurements from Arosa (1947-1989). The results show four different vertical trend regimes: On a relative scale changes were largest in the troposphere (increase of about 10 percent per decade). On an absolute scale the largest trends were obtained in the lower stratosphere (decrease of approximately 6 per decade at an altitude of about 18 to 22 km). No significant trends were observed at approximately 30 km, whereas stratospheric ozone decreased in the upper stratosphere.

Molecular and Immunological Characterization of Ragweed (Ambrosia artemisiifolia L.) Pollen after Exposure of the Plants to Elevated Ozone over a Whole Growing Season

PubMed Central

Kanter, Ulrike; Heller, Werner; Durner, Jörg; Winkler, J. Barbro; Engel, Marion; Behrendt, Heidrun; Holzinger, Andreas; Braun, Paula; Hauser, Michael; Ferreira, Fatima; Mayer, Klaus; Pfeifer, Matthias; Ernst, Dieter

2013-01-01

Climate change and air pollution, including ozone is known to affect plants and might also influence the ragweed pollen, known to carry strong allergens. We compared the transcriptome of ragweed pollen produced under ambient and elevated ozone by 454-sequencing. An enzyme-linked immunosorbent assay (ELISA) was carried out for the major ragweed allergen Amb a 1. Pollen surface was examined by scanning electron microscopy and attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR), and phenolics were analysed by high-performance liquid chromatography. Elevated ozone had no influence on the pollen size, shape, surface structure or amount of phenolics. ATR-FTIR indicated increased pectin-like material in the exine. Transcriptomic analyses showed changes in expressed-sequence tags (ESTs), including allergens. However, ELISA indicated no significantly increased amounts of Amb a 1 under elevated ozone concentrations. The data highlight a direct influence of ozone on the exine components and transcript level of allergens. As the total protein amount of Amb a 1 was not altered, a direct correlation to an increased risk to human health could not be derived. Additional, the 454-sequencing contributes to the identification of stress-related transcripts in mature pollen that could be grouped into distinct gene ontology terms. PMID:23637846

Aerosol and ozone changes as forcing for climate evolution between 1850 and 2100

NASA Astrophysics Data System (ADS)

Szopa, Sophie; Balkanski, Y.; Schulz, M.; Bekki, S.; Cugnet, D.; Fortems-Cheiney, A.; Turquety, S.; Cozic, A.; Déandreis, C.; Hauglustaine, D.; Idelkadi, A.; Lathière, J.; Lefevre, F.; Marchand, M.; Vuolo, R.; Yan, N.; Dufresne, J.-L.

2013-05-01

Global aerosol and ozone distributions and their associated radiative forcings were simulated between 1850 and 2100 following a recent historical emission dataset and under the representative concentration pathways (RCP) for the future. These simulations were used in an Earth System Model to account for the changes in both radiatively and chemically active compounds, when simulating the climate evolution. The past negative stratospheric ozone trends result in a negative climate forcing culminating at -0.15 W m-2 in the 1990s. In the meantime, the tropospheric ozone burden increase generates a positive climate forcing peaking at 0.41 W m-2. The future evolution of ozone strongly depends on the RCP scenario considered. In RCP4.5 and RCP6.0, the evolution of both stratospheric and tropospheric ozone generate relatively weak radiative forcing changes until 2060-2070 followed by a relative 30 % decrease in radiative forcing by 2100. In contrast, RCP8.5 and RCP2.6 model projections exhibit strongly different ozone radiative forcing trajectories. In the RCP2.6 scenario, both effects (stratospheric ozone, a negative forcing, and tropospheric ozone, a positive forcing) decline towards 1950s values while they both get stronger in the RCP8.5 scenario. Over the twentieth century, the evolution of the total aerosol burden is characterized by a strong increase after World War II until the middle of the 1980s followed by a stabilization during the last decade due to the strong decrease in sulfates in OECD countries since the 1970s. The cooling effects reach their maximal values in 1980, with -0.34 and -0.28 W m-2 respectively for direct and indirect total radiative forcings. According to the RCP scenarios, the aerosol content, after peaking around 2010, is projected to decline strongly and monotonically during the twenty-first century for the RCP8.5, 4.5 and 2.6 scenarios. While for RCP6.0 the decline occurs later, after peaking around 2050. As a consequence the relative importance of the total cooling effect of aerosols becomes weaker throughout the twenty-first century compared with the positive forcing of greenhouse gases. Nevertheless, both surface ozone and aerosol content show very different regional features depending on the future scenario considered. Hence, in 2050, surface ozone changes vary between -12 and +12 ppbv over Asia depending on the RCP projection, whereas the regional direct aerosol radiative forcing can locally exceed -3 W m-2.

Dust storms and their impact on ocean and human health: dust in Earth's atmosphere

USGS Publications Warehouse

Griffin, Dale W.; Kellog, Christina A.

2004-01-01

Satellite imagery has greatly influenced our understanding of dust activity on a global scale. A number of different satellites such as NASA's Earth-Probe Total Ozone Mapping Spectrometer (TOMS) and Se-viewing Field-of-view Sensor (SeaWiFS) acquire daily global-scale data used to produce imagery for monitoring dust storm formation and movement. This global-scale imagery has documented the frequent transmission of dust storm-derived soils through Earth's atmosphere and the magnitude of many of these events. While various research projects have been undertaken to understand this normal planetary process, little has been done to address its impact on ocean and human health. This review will address the ability of dust storms to influence marine microbial population densities and transport of soil-associated toxins and pathogenic microorganisms to marine environments. The implications of dust on ocean and human health in this emerging scientific field will be discussed.

Comparing and evaluating model estimates of background ozone in surface air over North America

NASA Astrophysics Data System (ADS)

Oberman, J.; Fiore, A. M.; Lin, M.; Zhang, L.; Jacob, D. J.; Naik, V.; Horowitz, L. W.

2011-12-01

Tropospheric ozone adversely affects human health and vegetation, and is thus a criteria pollutant regulated by the U.S. Environmental Protection Agency (EPA) under the National Ambient Air Quality Standard (NAAQS). Ozone is produced in the atmosphere via photo-oxidation of volatile organic compounds (VOCs) and carbon monoxide (CO) in the presence of nitrogen oxides (NOx). The present EPA approach considers health risks associated with exposure to ozone enhancement above the policy-relevant background (PRB), which is currently defined as the surface concentration of ozone that would exist without North American anthropogenic emissions. PRB thus includes production by natural precursors, production by precursors emitted on foreign continents, and transport of stratospheric ozone into surface air. As PRB is not an observable quantity, it must be estimated using numerical models. We compare PRB estimates for the year 2006 from the GFDL Atmospheric Model 3 (AM3) chemistry-climate model (CCM) and the GEOS-Chem (GC) chemical transport model (CTM). We evaluate the skill of the models in reproducing total surface ozone observed at the U.S. Clean Air Status and Trends Network (CASTNet), dividing the stations into low-elevation (< 1.5 km in altitude, primarily eastern) and high-elevation (> 1.5 km in altitude, all western) subgroups. At the low-elevation sites AM3 estimates of PRB (38±9 ppbv in spring, 27±9 ppbv in summer) are higher than GC (27±7 ppbv in spring, 21±8 ppbv in summer) in both seasons. Analysis at these sites is complicated by a positive bias in AM3 total ozone with respect to the observed total ozone, the source of which is yet unclear. At high-elevation sites, AM3 PRB is higher in the spring (47±8 ppbv) than in the summer (33±8 ppbv). In contrast, GC simulates little seasonal variation at high elevation sites (39±5 ppbv in spring vs. 38±7 ppbv in summer). Seasonal average total ozone at these sites was within 4 ppbv of the observations for both spring and summer in both models. The high elevation springtime maximum in PRB predicted by AM3 likely reflects stronger exchange between the surface and the free troposphere relative to GC, including a larger influence of stratospheric ozone. Higher summertime PRB in GC may be associated with differences in how the models treat the lightning NOx source (~10 times higher in GC over the Southwest U.S.). Biomass burning emissions (treated differently in the two models) contribute to episodic PRB enhancements in AM3 over the Midwest and East Coast. We conclude that further multi-model studies, including additional models, could provide the EPA with a more robust estimate of PRB, particularly if designed to isolate the relative roles of emissions, chemistry and transport, and evaluated with observation-based constraints wherever possible.

Development of an instrument for direct ozone production rate measurements: measurement reliability and current limitations

NASA Astrophysics Data System (ADS)

Sklaveniti, Sofia; Locoge, Nadine; Stevens, Philip S.; Wood, Ezra; Kundu, Shuvashish; Dusanter, Sébastien

2018-02-01

Ground-level ozone (O3) is an important pollutant that affects both global climate change and regional air quality, with the latter linked to detrimental effects on both human health and ecosystems. Ozone is not directly emitted in the atmosphere but is formed from chemical reactions involving volatile organic compounds (VOCs), nitrogen oxides (NOx = NO + NO2) and sunlight. The photochemical nature of ozone makes the implementation of reduction strategies challenging and a good understanding of its formation chemistry is fundamental in order to develop efficient strategies of ozone reduction from mitigation measures of primary VOCs and NOx emissions. An instrument for direct measurements of ozone production rates (OPRs) was developed and deployed in the field as part of the IRRONIC (Indiana Radical, Reactivity and Ozone Production Intercomparison) field campaign. The OPR instrument is based on the principle of the previously published MOPS instrument (Measurement of Ozone Production Sensor) but using a different sampling design made of quartz flow tubes and a different Ox (O3 and NO2) conversion-detection scheme composed of an O3-to-NO2 conversion unit and a cavity attenuated phase shift spectroscopy (CAPS) NO2 monitor. Tests performed in the laboratory and in the field, together with model simulations of the radical chemistry occurring inside the flow tubes, were used to assess (i) the reliability of the measurement principle and (ii) potential biases associated with OPR measurements. This publication reports the first field measurements made using this instrument to illustrate its performance. The results showed that a photo-enhanced loss of ozone inside the sampling flow tubes disturbs the measurements. This issue needs to be solved to be able to perform accurate ambient measurements of ozone production rates with the instrument described in this study. However, an attempt was made to investigate the OPR sensitivity to NOx by adding NO inside the instrument. This type of investigations allows checking whether our understanding of the turnover point between NOx-limited and NOx-saturated regimes of ozone production is well understood and does not require measuring ambient OPR but instead only probing the change in ozone production when NO is added. During IRRONIC, changes in ozone production rates ranging from the limit of detection (3σ) of 6.2 ppbv h-1 up to 20 ppbv h-1 were observed when 6 ppbv of NO was added into the flow tubes.

Comparison of the optical depth of total ozone and atmospheric aerosols in Poprad-Gánovce, Slovakia

NASA Astrophysics Data System (ADS)

Hrabčák, Peter

2018-06-01

The amount of ultraviolet solar radiation reaching the Earth's surface is significantly affected by atmospheric ozone along with aerosols. The present paper is focused on a comparison of the total ozone and atmospheric aerosol optical depth in the area of Poprad-Gánovce, which is situated at the altitude of 706 m a. s. l. in the vicinity of the highest mountain in the Carpathian mountains. The direct solar ultraviolet radiation has been measured here continuously since August 1993 using a Brewer MKIV ozone spectrophotometer. These measurements have been used to calculate the total amount of atmospheric ozone and, subsequently, its optical depth. They have also been used to determine the atmospheric aerosol optical depth (AOD) using the Langley plot method. Results obtained by this method were verified by means of comparison with a method that is part of the Brewer operating software, as well as with measurements made by a Cimel sun photometer. Diffuse radiation, the stray-light effect and polarization corrections were applied to calculate the AOD using the Langley plot method. In this paper, two factors that substantially attenuate the flow of direct ultraviolet solar radiation to the Earth's surface are compared. The paper presents results for 23 years of measurements, namely from 1994 to 2016. Values of optical depth were determined for the wavelengths of 306.3, 310, 313.5, 316.8 and 320 nm. A statistically significant decrease in the total optical depth of the atmosphere was observed with all examined wavelengths. Its root cause is the statistically significant decline in the optical depth of aerosols.

Spatial distribution of tropospheric ozone in western Washington, USA

USGS Publications Warehouse

Cooper, S.M.; Peterson, D.L.

2000-01-01

We quantified the distribution of tropospheric ozone in topographically complex western Washington state, USA (total area a??6000 km2), using passive ozone samplers along nine river drainages to measure ozone exposure from near sea level to high-elevation mountain sites. Weekly average ozone concentrations were higher with increasing distance from the urban core and at higher elevations, increasing a mean of 1.3 ppbv per 100 m elevation gain for all mountain transects. Weekly average ozone concentrations were generally highest in Cascade Mountains drainages east and southeast of Seattle (maximum=55a??67 pbv) and in the Columbia River Gorge east of Portland (maximum=59 ppbv), and lowest in the western Olympic Peninsula (maximum=34 ppbv). Higher ozone concentrations in the Cascade Mountains and Columbia River locations downwind of large cities indicate that significant quantities of ozone and ozone precursors are being transported eastward toward rural wildland areas by prevailing westerly winds. In addition, temporal (week to week) variation in ozone distribution is synchronous within and between all drainages sampled, which indicates that there is regional coherence in air pollution detectable with weekly averages. These data provide insight on large-scale spatial variation of ozone distribution in western Washington, and will help regulatory agencies optimize future monitoring networks and identify locations where human health and natural resources could be at risk.

Ozone loss in the lower stratosphere over the United States in 1992-1993: Evidence for heterogeneous chemistry on the Pinatubo aerosol

NASA Technical Reports Server (NTRS)

Hofmann, D. J.; Oltmans, S. J.; Komhyr, W. D.; Harris, J. M.; Lathrop, J. A.; Langford, A. O.; Deshler, T.; Johnson, B. J.; Torres, A.; Matthews, W. A.

1994-01-01

Ozone profiles obtained at Boulder, Colorado and Wallops Island, Virginia indicate that ozone was about 25% below normal during the winter and spring of 1992-93 in the 12-22 km region. This large ozone reduction in the lower stratosphere, though sometimes partially compensated by higher than normal ozone above 24 km, was responsible for the low total column ozone values observed across the United States during this period. Normal temperatures throughout the low ozone region suggest that transport-related effects are probably not the most important cause of the ozone deficits. This region of low ozone at Boulder corresponds closely with the location of the enhanced H2SO4/H2O aerosol from the Pinatubo eruption of 1991 as measured near Boulder and at Laramie, Wyoming. Trajectory analyses suggest that except at low altitudes in spring, air parcels on the days of the ozone measurements generally arrived at Boulder from higher latitude, although seldom higher than 60 deg N, and hence may have been subjected to heterogeneous chemical processing on the surface of Pinatubo aerosol droplets resulting in chlorine-catalyzed ozone destruction, a process which is believed to be more effective under the lower winter temperatures and sunlight levels of higher latitudes.

Ozone reaction with clothing and its initiated VOC emissions in an environmental chamber.

PubMed

Rai, A C; Guo, B; Lin, C-H; Zhang, J; Pei, J; Chen, Q

2014-02-01

Human health is adversely affected by ozone and the volatile organic compounds (VOCs) produced from its reactions in the indoor environment. Hence, it is important to characterize the ozone-initiated reactive chemistry under indoor conditions and study the influence of different factors on these reactions. This investigation studied the ozone reactions with clothing through a series of experiments conducted in an environmental chamber under various conditions. The study found that the ozone reactions with a soiled (human-worn) T-shirt consumed ozone and generated VOCs. The ozone removal rate and deposition velocity for the T-shirt increased with the increasing soiling level and air change rate, decreased at high ozone concentrations, and were relatively unaffected by the humidity. The deposition velocity for the soiled T-shirt ranged from 0.15 to 0.29 cm/s. The ozone-initiated VOC emissions included C6-C10 straight-chain saturated aldehydes, acetone, and 4-OPA (4-oxopentanal). The VOC emissions were generally higher at higher ozone, humidity, soiling of T-shirt, and air change rate. The total molar yield was approximately 0.5 in most cases, which means that for every two moles of ozone removed by the T-shirt surface, one mole of VOCs was produced. © 2013 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

Unequivocal detection of ozone recovery in the Antarctic Ozone Hole through significant increases in atmospheric layers with minimum ozone

NASA Astrophysics Data System (ADS)

de Laat, Jos; van Weele, Michiel; van der A, Ronald

2015-04-01

An important new landmark in present day ozone research is presented through MLS satellite observations of significant ozone increases during the ozone hole season that are attributed unequivocally to declining ozone depleting substances. For many decades the Antarctic ozone hole has been the prime example of both the detrimental effects of human activities on our environment as well as how to construct effective and successful environmental policies. Nowadays atmospheric concentrations of ozone depleting substances are on the decline and first signs of recovery of stratospheric ozone and ozone in the Antarctic ozone hole have been observed. The claimed detection of significant recovery, however, is still subject of debate. In this talk we will discuss first current uncertainties in the assessment of ozone recovery in the Antarctic ozone hole by using multi-variate regression methods, and, secondly present an alternative approach to identify ozone hole recovery unequivocally. Even though multi-variate regression methods help to reduce uncertainties in estimates of ozone recovery, great care has to be taken in their application due to the existence of uncertainties and degrees of freedom in the choice of independent variables. We show that taking all uncertainties into account in the regressions the formal recovery of ozone in the Antarctic ozone hole cannot be established yet, though is likely before the end of the decade (before 2020). Rather than focusing on time and area averages of total ozone columns or ozone profiles, we argue that the time evolution of the probability distribution of vertically resolved ozone in the Antarctic ozone hole contains a better fingerprint for the detection of ozone recovery in the Antarctic ozone hole. The advantages of this method over more tradition methods of trend analyses based on spatio-temporal average ozone are discussed. The 10-year record of MLS satellite measurements of ozone in the Antarctic ozone hole shows a significant change in the distribution of ozone. The occurrence of extremely low ozone (near 100% ozone depletion) has been declining significantly in favor of the occurrence of low ozone (80-90% ozone depletion). Finally the potential for continuation of this attribution method in the light of the currently available and future planned satellite remote sensing capacity will be shortly addressed.

Diagnostic studies of the Antarctic vortex during the 1987 Airborne Antarctic Ozone Experiment - Ozone miniholes

NASA Technical Reports Server (NTRS)

Mckenna, D. S.; Jones, R. L.; Austin, J.; Browell, E. V.; Mccormick, M. P.; Krueger, A. J.

1989-01-01

Localized rapid reductions in total ozone (miniholes), which were observed during the Airborne Antarctic Ozone Experiment, are studied with particular attention given to meteorological aspects. It is suggested that miniholes are forced by tropospheric weather features and that they are largely reversible distortions to the airflow around the vortex. The relationship between the miniholes and upper tropospheric and lower stratospheric synoptic-scale disturbances is studied. Trajectory calculations are presented which demonstrate the exchange of air from low latitudes with air from within the vortex, with the vortex air subsequently moving to lower latitudes.

The Impact of Ozone Treatment in Dynamic Bed Parameters on Changes in Biologically Active Substances of Juniper Berries

PubMed Central

Brodowska, Agnieszka Joanna; Śmigielski, Krzysztof; Nowak, Agnieszka; Czyżowska, Agata; Otlewska, Anna

2015-01-01

The development of the parameters of ozone decontamination method assuring the least possible losses of biologically active substances (essential oils and polyphenols) and their activity in common juniper (Juniperus communis (L.)) berries was studied. Ozone treatment in dynamic bed was conducted 9 times. The process was conducted under different ozone concentrations (100.0; 130.0; 160.0 g O3/m3) and times (30, 60, 90 min). After each decontamination, the microbiological profile of the juniper berries was studied, and the contaminating microflora was identified. Next to the microbiological profile, the phenolic profile, as well as antioxidant activity of extracts and essential oils were determined. The total polyphenol content (TPC), composition of essential oils, free radical-scavenging capacity, total antioxidant capacity, ferric-reducing antioxidant power (FRAP), beta-carotene bleaching test (BCB) and LC-MS polyphenol analysis were carried out. The study reveals that during short ozone contact times, higher amounts of TPC, 15.47 and 12.91 mg CE/g of extract, for samples 100/30 and 130/30, respectively, were demonstrated. Whereas samples 100/60, 130/60, 100/90, and 160/90 exhibited the lowest amount of phenolics. The highest antioxidant activity was found in the methanol extract obtained from ozonated berries which exhibited the lowest IC50 in all the antioxidant assays, such as DPPH, FRAP, and BCB assays. Ozone treatment showed noteworthy potential and its usage in food manufacturing and as an alternative decontamination method should be considered. PMID:26659905

The Impact of Ozone Treatment in Dynamic Bed Parameters on Changes in Biologically Active Substances of Juniper Berries.

PubMed

Brodowska, Agnieszka Joanna; Śmigielski, Krzysztof; Nowak, Agnieszka; Czyżowska, Agata; Otlewska, Anna

2015-01-01

The development of the parameters of ozone decontamination method assuring the least possible losses of biologically active substances (essential oils and polyphenols) and their activity in common juniper (Juniperus communis (L.)) berries was studied. Ozone treatment in dynamic bed was conducted 9 times. The process was conducted under different ozone concentrations (100.0; 130.0; 160.0 g O3/m3) and times (30, 60, 90 min). After each decontamination, the microbiological profile of the juniper berries was studied, and the contaminating microflora was identified. Next to the microbiological profile, the phenolic profile, as well as antioxidant activity of extracts and essential oils were determined. The total polyphenol content (TPC), composition of essential oils, free radical-scavenging capacity, total antioxidant capacity, ferric-reducing antioxidant power (FRAP), beta-carotene bleaching test (BCB) and LC-MS polyphenol analysis were carried out. The study reveals that during short ozone contact times, higher amounts of TPC, 15.47 and 12.91 mg CE/g of extract, for samples 100/30 and 130/30, respectively, were demonstrated. Whereas samples 100/60, 130/60, 100/90, and 160/90 exhibited the lowest amount of phenolics. The highest antioxidant activity was found in the methanol extract obtained from ozonated berries which exhibited the lowest IC50 in all the antioxidant assays, such as DPPH, FRAP, and BCB assays. Ozone treatment showed noteworthy potential and its usage in food manufacturing and as an alternative decontamination method should be considered.

Quality of tomato slices disinfected with ozonated water.

PubMed

Aguayo, Encarna; Escalona, Víctor; Silveira, Ana Cecilia; Artés, Francisco

2014-04-01

Fresh-cut industry needs novel disinfectant to replace the use of chlorine. Ozone is one of the most powerful oxidizing agents and is applied in gaseous or aqueous form for sanitation purposes. However, the strong oxidative effect could affect the nutritional and sensorial quality, in particular, when time of washing is extended. For that reason, the overall impact of ozonated water (0.4 mg/L) dipping applied during 1, 3 and 5 min compared to control washed in water during 5 min was studied in tomato slices stored during 14 days at 5 . According to the results, ozonated water treatment of 3 min achieved the best firmness retention, microbial quality (mesophilic, psychrotrophic and yeas load) and reduced the consumption of fructose and glucose. The use of ozonated water did not affect the total acidity, pH, total solid soluble, organic acid as ascorbic, fumaric or succinic acid and the sensorial parameters, which were only affected by storage time. However, the poor appearance, aroma and overall quality obtained in all treatments prevented shelf life of 14 days and the quality at acceptable levels was established in 10 days at 5 . It is recommended to wash tomato slices with 0.4 mg/L ozonated water for 3 min only. Extending treatment duration did not improve the microbiological quality, possibly due to the extra time permitting the ozone to react with other components of the fruit tissue, undermining the antimicrobial benefits.

"OZONE SOURCE APPORTIONMENT IN CMAQ' | Science ...

EPA Pesticide Factsheets

Ozone source attribution has been used to support various policy purposes including interstate transport (Cross State Air Pollution Rule) by U.S. EPA and ozone nonattainment area designations by State agencies. Common scientific applications include tracking intercontinental transport of ozone and ozone precursors and delineating anthropogenic and non-anthropogenic contribution to ozone in North America. As in the public release due in September 2013, CMAQ’s Integrated Source Apportionment Method (ISAM) attributes PM EC/OC, sulfate, nitrate, ammonium, ozone and its precursors NOx and VOC, to sectors/regions of users’ interest. Although the peroxide-to-nitric acid productions ratio has been the most common indicator to distinguish NOx-limited ozone production from VOC-limited one, other indicators are implemented in addition to allowing for an ensemble decision based on a total of 9 available indicator ratios. Moreover, an alternative approach of ozone attribution based on the idea of chemical sensitivity in a linearized system that has formed the basis of chemical treatment in forward DDM/backward adjoint tools has been implemented in CMAQ. This method does not require categorization into either ozone regime. In this study, ISAM will simulate the 2010 North America ozone using all of the above gas-phase attribution methods. The results are to be compared with zero-out difference out of those sectors in the host model runs. In addition, ozone contribution wil

Urban and Rural Ozone Pollution Over Lusaka (Zambia, 15.5S, 25E) During SAFARI-2000 (September 2000)

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Herman, J. R.; Witte, J. C.; Phahlane, A.; Coetzee, G. J. R.; Mukula, C.; Hudson, R. D.; Frolov, A. D.; Bhartia, P. K. (Technical Monitor)

2001-01-01

In early September, throughout south central Africa, seasonal clearing of dry vegetation and the production of charcoal for cooking leads to intense smoke haze and ozone formation. Ozone soundings made over Lusaka during a six-day period in early September 2000 recorded layers of high ozone (greater than 125 ppbv at 5 km) during two stagnant periods, interspersed by a frontal passage that reduced boundary layer ozone by 30 percent. Smoke aerosol column variations aloft and total ozone were monitored by a sun photometer. During the 6-day measurement period, surface ozone concentrations ranged from 50-95 ppbv and integrated tropospheric ozone from the soundings was 39- 54 Dobson Units (note 1.3 km elevation at the launch site). High ozone concentrations above the mixed and inversion layers were advected from rural burning regions in western Zambia where SAFARI aircraft and ground-based instruments observed intense biomass fires and elevated aerosol and trace gas amounts. TOMS tropospheric ozone and smoke aerosols products show the distribution of biomass burning and associated pollution throughout southern Africa in September 2000. Animations of satellite images and trajectories confirm pollutant recirculation over south central African fires, exit of ozone from Mozambique and Tanzania to the Indian Ocean and the characteristic buildup of tropospheric ozone over the Atlantic from western African outflow.

The photochemical pollution episode of 5-16 July 1983 in North-West England

NASA Astrophysics Data System (ADS)

Colbeck, I.; Harrison, Roy M.

Ground level ozone, NO x and specific C 2-C 6 hydrocarbon measurements from a rural site in N-W England during a photochemical pollution episode are presented. Maximum hourly ozone concentrations exceeded 80 ppb for ten consecutive days with a maximum of 156 ppb. Mid-morning ozone concentrations were found to be indicative of the amount of ozone from continental sources. The air mass trajectories, total NMHC and alkane : alkene ratios all indicate that in the early to middle stages of the episode the air had been exposed to recent precursor emissions relative to more aged air before and after this period. The measurements are compared with the predictions of recent theoretical models of ozone formation over England.

Ozone measurement system for NASA global air sampling program

NASA Technical Reports Server (NTRS)

Tiefermann, M. W.

1979-01-01

The ozone measurement system used in the NASA Global Air Sampling Program is described. The system uses a commercially available ozone concentration monitor that was modified and repackaged so as to operate unattended in an aircraft environment. The modifications required for aircraft use are described along with the calibration techniques, the measurement of ozone loss in the sample lines, and the operating procedures that were developed for use in the program. Based on calibrations with JPL's 5-meter ultraviolet photometer, all previously published GASP ozone data are biased high by 9 percent. A system error analysis showed that the total system measurement random error is from 3 to 8 percent of reading (depending on the pump diaphragm material) or 3 ppbv, whichever are greater.

New Insights in Tropospheric Ozone and its Variability

NASA Technical Reports Server (NTRS)

Oman, Luke D.; Douglass, Anne R.; Ziemke, Jerry R.; Rodriquez, Jose M.

2011-01-01

We have produced time-slice simulations using the Goddard Earth Observing System Version 5 (GEOS-5) coupled to a comprehensive stratospheric and tropospheric chemical mechanism. These simulations are forced with observed sea surface temperatures over the past 25 years and use constant specified surface emissions, thereby providing a measure of the dynamically controlled ozone response. We examine the model performance in simulating tropospheric ozone and its variability. Here we show targeted comparisons results from our simulations with a multi-decadal tropical tropospheric column ozone dataset obtained from satellite observations of total column ozone. We use SHADOZ ozonesondes to gain insight into the observed vertical response and compare with the simulated vertical structure. This work includes but is not limited to ENSO related variability.

Solar activated ozonation of phenol and malic acid.

PubMed

Sánchez, Laura; Domènech, Xavier; Casado, Juan; Peral, José

2003-03-01

The effect that sunlight has on the degradation rate of two model organic compounds, phenol and malic acid, by ozone is studied. The effect seems to be due to both direct light absorption (300-320 nm photons) by ozone, which produces the pollutant degradation, and light absorption by reaction intermediates. The presence of such a light notably improves the reactivity of ozone toward the organic species, leading to a faster and complete mineralization even at large initial total organic carbon values. The use of artificial sunlight (Xe lamp) is also explored. Finally, the simultaneous presence of sunlight and other ozone degradation catalyst like transition metal ions is studied, showing the beneficial effect of such a combination. Copyright 2002 Elsevier Science Ltd.

Wastewater disinfection alternatives: chlorine, ozone, peracetic acid, and UV light.

PubMed

Mezzanotte, V; Antonelli, M; Citterio, S; Nurizzo, C

2007-11-01

Disinfection tests were carried out at pilot scale to compare the disinfection efficiency of ozone, sodium hypochlorite (NaOCl), peracetic acid (PAA), and UV irradiation. Total coliforms, fecal coliforms, and Escherichia coli were monitored as reference microorganisms. Total heterotrophic bacteria (THB) were also enumerated by cytometry. At similar doses, NaOCl was more effective than PAA, and its action was less affected by contact time. The results obtained by ozonation were comparable for total coliforms, fecal coliforms, and E. coli. On the contrary, some differences among the three indicators were observed for NaOCl, PAA, and UV. Differences increased with increasing values of the disinfectant concentration times contact time (C x t) and were probably the result of different initial counts, as total coliforms include fecal coliforms, which include E. coli. The UV irradiation lead to complete E. coli removals, even at low doses (10 to 20 mJ/cm2). Total heterotrophic bacteria appeared to be too wide a group to be a good disinfection indicator; no correlation was found among THB inactivation, dose, and contact time.

Ground-based total ozone column measurements and their diurnal variability

NASA Astrophysics Data System (ADS)

Silva, Abel A.

2013-07-01

Brewer spectrophotometers were set up in three tropical sites of South America (in the Bolivian Altiplano and seashore and biomass burning areas of Brazil) to measure the total ozone column (TOC). Only TOC measurements with uncertainties ≤1% (1σ) were considered. Typically, the standard deviation for the diurnal sets of measurements was predominantly ≤1% for two of these sites. The average variability in TOC ranged from 6.3 Dobson units (DU) to 16.8 DU, and the largest variability reached 54.3 DU. Comparisons between ground-based and satellite (Total Ozone Mapping Spectrometer (TOMS)) data showed good agreement with coefficients of determination ≤0.83. However, the quality of the ground-based measurements was affected by the weather condition, especially for one of the sites. Visual observation of the sky from the ground during the measurements with one of the Brewers added to the satellite data of reflectivity and aerosol index supports that statement.

Certain Results of Measurements of Characteristics of Stratospheric Aerosol Layer and Total Ozone Content at Siberian Lidar Station in Tomsk

NASA Astrophysics Data System (ADS)

Nevzorov, Aleksey; Bazhenov, Oleg; Burlakov, Vladimir; Dolgii, Sergey

2016-06-01

We consider the results of long-term remote optical monitoring, obtained at the Siberian Lidar Station of Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences in Tomsk (56.5°N, 85.0°E). The scattering characteristics of stratospheric aerosol layer, obtained according to data of lidar measurements since 1986, are presented. We analyze the trends of changes in the total ozone (TO) content over Tomsk for the period 1996-2013 according to data of spectrophotometric measurements with employment of Total Ozone Mapping Spectrometer (TOMS) data for the period 1979-1994. We determined the periods of elevated content of stratospheric aerosol over Tomsk aftera series of explosive eruptions of volcanoes of Pacific Ring of Fire and Iceland in 2006-2011. Since the second half of 1990s, we record an increasing TO trend, equaling 0.65 DU/yr for the period 1996-2013.

Identifying and forecasting deep stratospheric ozone intrusions over the western United States from space

NASA Astrophysics Data System (ADS)

Lin, M.; Fiore, A. M.; Horowitz, L. W.; Cooper, O. R.; Langford, A. O.; Pan, L.; Liu, X.; Reddy, P. J.

2012-12-01

Recent studies have shown that deep stratospheric ozone intrusions can episodically enhance ground-level ozone above the health-based standard over the western U.S. in spring. Advanced warning of incoming intrusions could be used by state agencies to inform the public about poor air quality days. Here we explore the potential for using total ozone retrievals (version 5.2, level 3) at twice daily near global coverage from the AIRS instrument aboard the NASA Aqua satellite to identify stratospheric intrusions and forecast the eventual surface destination of transported stratospheric ozone. The method involves the correlation of AIRS daily total ozone columns at each 1ox1o grid box ~1-3 days prior to stratospheric enhancements to daily maximum 8-hour average ozone at a selected surface site using datasets from April to June in 2003-2011. The surface stratospheric enhancements are estimated by the GFDL AM3 chemistry-climate model which includes full stratospheric and tropospheric chemistry and is nudged to reanalysis winds. Our earlier work shows that the model presents deep stratospheric intrusions over the Western U.S. consistently with observations from AIRS, surface networks, daily ozone sondes, and aircraft lidar available in spring of 2010 during the NOAA CalNex field campaign. For the 15 surface sites in the U.S. Mountain West considered, a correlation coefficient of 0.4-0.7 emerges with AIRS ozone columns over 30o-50oN latitudes and 125o-105oW longitudes - variability in the AIRS column within this spatial domain indicates incoming intrusions. For each "surface receptor site", the spatial domain can narrow to an area ~5ox5o northwest of the individual site, with the strong correlation (0.5-0.7) occurring when the AIRS data is lagged by 1 day from the AM3 stratospheric enhancements in surface air. The spatial pattern of correlations is consistent with our process-oriented understanding developed from case studies of extreme intrusions. Surface observations during these events show that the sites experiencing elevated ozone levels are typically located over the southeastern side of the enhanced ozone columns captured by AIRS ~12 hours to 1 day prior. This first scoping study suggests there is potential to use near-daily global coverage of ozone in total column or in UT/LS levels from the space-based instruments (e.g. AIRS, OMI, MLS) to serve as a qualitative early-warning indicator of incoming stratospheric intrusions with a lead time of ~1-3 days. There is more skill in ~12 hours to 1 day as to where the intrusion will reach the surface, particularly during the ENSO years (i.e. 2003, 2008, 2010, 2011) when deep intrusions are more likely to occur as compared to other years. These space-based ozone products can also provide some indication of whether a historic exceedance was caused by an intrusion.

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fernandez, Rafael P.; Kinnison, Douglas E.; Lamarque, Jean -Francois

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSL Br) enhances stratospheric ozone depletion. Based on a dual set of 1960–2100 coupled chemistry–climate simulations (i.e. with and without VSL Br), we show that the maximum Antarctic ozone hole depletion increases by up to 14 % when natural VSL Br are considered, which is in better agreement with ozone observations. The impact of the additional 5 pptv VSL Br on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of ~5 million km 2, which is equivalentmore » in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSL Br in CAM-Chem (Community Atmosphere Model with Chemistry, version 4.0) does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affects the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by the year 2070 and indicates that natural VSL Br chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. As a result, this work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.« less

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

DOE PAGES

Fernandez, Rafael P.; Kinnison, Douglas E.; Lamarque, Jean -Francois; ...

2017-02-03

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSL Br) enhances stratospheric ozone depletion. Based on a dual set of 1960–2100 coupled chemistry–climate simulations (i.e. with and without VSL Br), we show that the maximum Antarctic ozone hole depletion increases by up to 14 % when natural VSL Br are considered, which is in better agreement with ozone observations. The impact of the additional 5 pptv VSL Br on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of ~5 million km 2, which is equivalentmore » in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSL Br in CAM-Chem (Community Atmosphere Model with Chemistry, version 4.0) does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affects the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by the year 2070 and indicates that natural VSL Br chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. As a result, this work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.« less

Impact of parameterization choices on the restitution of ozone deposition over vegetation

NASA Astrophysics Data System (ADS)

Le Morvan-Quéméner, Aurélie; Coll, Isabelle; Kammer, Julien; Lamaud, Eric; Loubet, Benjamin; Personne, Erwan; Stella, Patrick

2018-04-01

Ozone is a potentially phyto-toxic air pollutant, which can cause leaf damage and drastically alter crop yields, causing serious economic losses around the world. The VULNOZ (VULNerability to OZone in Anthropised Ecosystems) project is a biology and modeling project that aims to understand how plants respond to the stress of high ozone concentrations, then use a set of models to (i) predict the impact of ozone on plant growth, (ii) represent ozone deposition fluxes to vegetation, and finally (iii) estimate the economic consequences of an increasing ozone background the future. In this work, as part of the VULNOZ project, an innovative representation of ozone deposition to vegetation was developed and implemented in the CHIMERE regional chemistry-transport model. This type of model calculates the average amount of ozone deposited on a parcel each hour, as well as the integrated amount of ozone deposited to the surface at the regional or country level. Our new approach was based on a refinement of the representation of crop types in the model and the use of empirical parameters specific to each crop category. The results obtained were compared with a conventional ozone deposition modeling approach, and evaluated against observations from several agricultural areas in France. They showed that a better representation of the distribution between stomatal and non-stomatal ozone fluxes was obtained in the empirical approach, and they allowed us to produce a new estimate of the total amount of ozone deposited on the subtypes of vegetation at the national level.

Upper Tropospheric Ozone Between Latitudes 60S and 60N Derived from Nimbus 7 TOMS/THIR Cloud Slicing

NASA Technical Reports Server (NTRS)

Ziemke, Jerald R.; Chandra, Sushil; Bhartia, P. K.

2002-01-01

This study evaluates the spatial distributions and seasonal cycles in upper tropospheric ozone (pressure range 200-500 hPa) from low to high latitudes (60S to 60N) derived from the satellite retrieval method called "Cloud Slicing." Cloud Slicing is a unique technique for determining ozone profile information in the troposphere by combining co-located measurements of cloud-top, pressure and above-cloud column ozone. For upper tropospheric ozone, co-located measurements of Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) above-cloud column ozone, and Nimbus 7 Temperature Humidity Infrared Radiometer (THIR) cloud-top pressure during 1979-1984 were incorporated. In the tropics, upper tropospheric ozone shows year-round enhancement in the Atlantic region and evidence of a possible semiannual variability. Upper tropospheric ozone outside the tropics shows greatest abundance in winter and spring seasons in both hemispheres with largest seasonal and largest amounts in the NH. These characteristics are similar to lower stratospheric ozone. Comparisons of upper tropospheric column ozone with both stratospheric ozone and a proxy of lower stratospheric air mass (i.e., tropopause pressure) from National Centers for Environmental Prediction (NCEP) suggest that stratosphere-troposphere exchange (STE) may be a significant source for the seasonal variability of upper tropospheric ozone almost everywhere between 60S and 60N except in low latitudes around 10S to 25N where other sources (e.g., tropospheric transport, biomass burning, aerosol effects, lightning, etc.) may have a greater role.

A revised linear ozone photochemistry parameterization for use in transport and general circulation models: multi-annual simulations

NASA Astrophysics Data System (ADS)

Cariolle, D.; Teyssèdre, H.

2007-05-01

This article describes the validation of a linear parameterization of the ozone photochemistry for use in upper tropospheric and stratospheric studies. The present work extends a previously developed scheme by improving the 2-D model used to derive the coefficients of the parameterization. The chemical reaction rates are updated from a compilation that includes recent laboratory work. Furthermore, the polar ozone destruction due to heterogeneous reactions at the surface of the polar stratospheric clouds is taken into account as a function of the stratospheric temperature and the total chlorine content. Two versions of the parameterization are tested. The first one only requires the solution of a continuity equation for the time evolution of the ozone mixing ratio, the second one uses one additional equation for a cold tracer. The parameterization has been introduced into the chemical transport model MOCAGE. The model is integrated with wind and temperature fields from the ECMWF operational analyses over the period 2000-2004. Overall, the results from the two versions show a very good agreement between the modelled ozone distribution and the Total Ozone Mapping Spectrometer (TOMS) satellite data and the "in-situ" vertical soundings. During the course of the integration the model does not show any drift and the biases are generally small, of the order of 10%. The model also reproduces fairly well the polar ozone variability, notably the formation of "ozone holes" in the Southern Hemisphere with amplitudes and a seasonal evolution that follow the dynamics and time evolution of the polar vortex. The introduction of the cold tracer further improves the model simulation by allowing additional ozone destruction inside air masses exported from the high to the mid-latitudes, and by maintaining low ozone content inside the polar vortex of the Southern Hemisphere over longer periods in spring time. It is concluded that for the study of climate scenarios or the assimilation of ozone data, the present parameterization gives a valuable alternative to the introduction of detailed and computationally costly chemical schemes into general circulation models.

Spatial distribution of ozone over Indonesia (Study case: Forest fire event 2015)

NASA Astrophysics Data System (ADS)

Muslimah, Sri; Buce Saleh, Muhamad; Hidayat, Rahmat

2018-05-01

Tropospheric ozone is known as surface ozone and caused several health impact. The objective of this study was to analysis spatial distribution of tropospheric ozone over Indonesia case study forest fire event in 2015. Monthly observation measured by Ozone Monitoring Instrument (OMI) have been analysed from January – December 2015 to study spatial distribution of tropospheric ozone related to forest fire event 2015. The study discovered high level of tropospheric column ozone (TCO) from October to November 2015. The result shows increasing average of TCO from September to October almost 6 DU. Meanwhile, monthly number of hotspot is higher in September 2015 with total number 257 hotspot which is acquired by Moderate Resolution Imaging Spectrometer (MODIS) Terra version 6.1 with confidence level same or more than 90%. The hotspot distribution compared with spatial TCO distribution and shows interesting time lag with respect to hotspot distribution, one month. Further study for daily comparison of TCO and forest fire event needed. This result suggested that the tropospheric ozone over the Indonesian region increases in 2015 were remarkable and corresponded to forest fire event.

The Effect of New Ozone Cross Sections Applied to SBUV and TOMS Retrievals

NASA Technical Reports Server (NTRS)

McPeters, Richard D.; Labow, Gordon J.

2010-01-01

The ozone cross sections as measured by Bass and Paur have been used for processing of SBUV and TOMS data since 1986. While these cross sections were a big improvement over those previously available, there were known minor problems with accuracy for wavelengths longward of 330 nm and with the temperature dependance. Today's requirements to separate stratospheric ozone from tropospheric ozone and for the derivation of minor species such as BrO and N02 place stringent new requirements on the accuracy needed. The ozone cross section measurements of Brion, Daumont, and Malicet (BDM) are being considered for use in UV-based ozone retrievals. They have much better resolution, an extended wavelength range, and a more consistent temperature dependance. Tests show that BDM retrievals exhibit lower retrieval residuals in the satellite data; i.e., they explain our measured atmospheric radiances more accurately. Total column ozone retrieved by the TOMS instruments is about 1.5% higher than before. Ozone profiles retrieved from SBUV using the new cross sections are lower in the upper stratosphere and higher in the lower stratosphere and troposphere.

Ozone disintegration of excess biomass and application to nitrogen removal.

PubMed

Park, Ki Young; Lee, Jae Woo; Ahn, Kyu-Hong; Maeng, Sung Kyu; Hwang, Jong Hyuk; Song, Kyung-Guen

2004-01-01

A pilot-scale facility integrated with an ozonation unit was built to investigate the feasibility of using ozone-disintegration byproducts of wasted biomass as a carbon source for denitrification. Ozonation of biomass resulted in mass reduction by mineralization as well as by ozone-disintegrated biosolids recycling. Approximately 50% of wasted solids were recovered as available organic matter (ozonolysate), which included nonsettleable microparticles and soluble fractions. Microparticles were observed in abundance at relatively low levels of ozone doses, while soluble fractions became dominant at higher levels of ozone doses in ozone-disintegrated organics. Batch denitrification experiments showed that the ozonolysate could be used as a carbon source with a maximum denitrification rate of 3.66 mg nitrogen (N)/g volatile suspended solids (VSS) x h. Ozonolysate was also proven to enhance total nitrogen removal efficiency in the pilot-scale treatment facility. An optimal chemical oxygen demand (COD)-to-nitrogen ratio for complete denitrification was estimated as 5.13 g COD/g N. The nitrogen-removal performance of the modified intermittently decanted extended aeration process dependent on an external carbon supply could be described as a function of solids retention time.

Understanding Differences in Chemistry Climate Model Projections of Stratospheric Ozone

NASA Technical Reports Server (NTRS)

Douglass, A. R.; Strahan, S. E.; Oman, L. D.; Stolarski, R. S.

2014-01-01

Chemistry climate models (CCMs) are used to project future evolution of stratospheric ozone as concentrations of ozone-depleting substances (ODSs) decrease and greenhouse gases increase, cooling the stratosphere. CCM projections exhibit not only many common features but also a broad range of values for quantities such as year of ozone return to 1980 and global ozone level at the end of the 21st century. Multiple linear regression is applied to each of 14 CCMs to separate ozone response to ODS concentration change from that due to climate change. We show that the sensitivity of lower stratospheric ozone to chlorine change Delta Ozone/Delta inorganic chlorine is a near-linear function of partitioning of total inorganic chlorine into its reservoirs; both inorganic chlorine and its partitioning are largely controlled by lower stratospheric transport. CCMs with best performance on transport diagnostics agree with observations for chlorine reservoirs and produce similar ozone responses to chlorine change. After 2035, differences in Delta Ozone/Delta inorganic chlorine contribute little to the spread in CCM projections as the anthropogenic contribution to inorganic chlorine becomes unimportant. Differences among upper stratospheric ozone increases due to temperature decreases are explained by differences in ozone sensitivity to temperature change Delta Ozone/Delta T due to different contributions from various ozone loss processes, each with its own temperature dependence. Ozone decrease in the tropical lower stratosphere caused by a projected speedup in the Brewer-Dobson circulation may or may not be balanced by ozone increases in the middle- and high-latitude lower stratosphere and upper troposphere. This balance, or lack thereof, contributes most to the spread in late 21st century projections.

The Effect of Representing Bromine from VSLS on the Simulation and Evolution of Antarctic Ozone

NASA Technical Reports Server (NTRS)

Oman, Luke D.; Douglass, Anne R.; Salawitch, Ross J.; Canty, Timothy P.; Ziemke, Jerald R.; Manyin, Michael

2016-01-01

We use the Goddard Earth Observing System Chemistry Climate Model (GEOSCCM), a contributor to both the 2010 and 2014 WMO Ozone Assessment Reports, to show that inclusion of 5 parts per trillion (ppt) of stratospheric bromine(Br(sub y)) from very short lived substances (VSLS) is responsible for about a decade delay in ozone hole recovery. These results partially explain the significantly later recovery of Antarctic ozone noted in the 2014 report, as bromine from VSLS was not included in the 2010 Assessment. We show multiple lines of evidence that simulations that account for VSLS Br(sub y) are in better agreement with both total column BrO and the seasonal evolution of Antarctic ozone reported by the Ozone Monitoring Instrument (OMI) on NASAs Aura satellite. In addition, the near zero ozone levels observed in the deep Antarctic lower stratospheric polar vortex are only reproduced in a simulation that includes this Br(sub y) source from VSLS.

Total ozone trends over the USA during 1979-1991 from Dobson spectrophotometer observations

NASA Technical Reports Server (NTRS)

Komhyr, Walter D.; Grass, Robert D.; Koenig, Gloria L.; Quincy, Dorothy M.; Evans, Robert D.; Leonard, R. Kent

1994-01-01

Ozone trends for 1979-1991, determined from Dobson spectrophotometer observations made at eight stations in the United States, are augmented with trend data from four foreign cooperative stations operated by NOAA/CMDL. Results are based on provisional data archived routinely throughout the years at the World Ozone Data Center in Toronto, Canada, with calibration corrections applied to some of the data. Trends through 1990 exhibit values of minus 0.3 percent to minus 0.5 percent yr(exp -1) at mid-to-high latitudes in the northern hemisphere. With the addition of 1991 data, however, the trends become less negative, indicating that ozone increased in many parts of the world during 1991. Stations located within the plus or minus 20 deg N-S latitude band exhibit no ozone trends. Early 1992 data show decreased ozone values at some of the stations. At South Pole, Antarctica, October ozone values have remained low during the past 3 years.

The Effect of Representing Bromine from VSLS on the Simulation and Evolution of Antarctic Ozone

PubMed Central

Oman, Luke D.; Douglass, Anne R.; Salawitch, Ross J.; Canty, Timothy P.; Ziemke, Jerald R.; Manyin, Michael

2018-01-01

We use the Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM), a contributor to both the 2010 and 2014 WMO Ozone Assessment Reports, to show that inclusion of 5 parts per trillion (ppt) of stratospheric bromine (Bry) from very short-lived substances (VSLS) is responsible for about a decade delay in ozone hole recovery. These results partially explain the significantly later recovery of Antarctic ozone noted in the 2014 report, as bromine from VSLS was not included in the 2010 Assessment. We show multiple lines of evidence that simulations that account for VSLS Bry are in better agreement with both total column BrO and the seasonal evolution of Antarctic ozone reported by the Ozone Monitoring Instrument (OMI) on NASA’s Aura satellite. In addition, the near zero ozone levels observed in the deep Antarctic lower stratospheric polar vortex are only reproduced in a simulation that includes this Bry source from VSLS. PMID:29551840

Ozone exposure thresholds and foliar injury on forest plants in Switzerland.

PubMed

VanderHeyden, D; Skelly, J; Innes, J; Hug, C; Zhang, J; Landolt, W; Bleuler, P

2001-01-01

Canton Ticino in southern Switzerland is exposed to some of the highest concentrations of tropospheric ozone in Europe. During recent field surveys in Canton Ticino, foliar symptoms identical to those caused by ozone have been documented on native tree and shrub species. In Europe, the critical ozone level for forest trees has been defined at an AOT40 of 10 ppm.h O3 (10 ppm.h accumulated exposure of ozone over a threshold of 40 ppb) during daylight hours over a six-month growing season. The objective of this study was to determine the amount of ambient ozone required to induce visible foliar symptoms on various forest plant species in southern Switzerland. Species were grown within eight open-top chambers and four open plots at the Vivaio Lattecaldo Cantonal Forest Nursery in Ticino, Switzerland. Species differed significantly in terms of the ppb.h exposures needed to cause visible symptoms. The most to least symptomatic species grown within open-plots in this study rank as Prunus serotina, Salix viminalis, Vibrnum lantana, Rhamnus cathartica, Betula pendula, Rumex obtusifolius, Sambucus racemosa, Morus nigra, Prunus avium, Fraxinus excelsior, Rhamnus frangula, Alnus viridis, Fagus sylvatica and Acer pseudoplatanus. Similar rankings were obtained in the non-filtered chamber plots. The ranking of species sensitivity closely follows AOT values for the occurrence of initial symptoms and symptom progression across the remainder of the exposure season. Species that first showed evidence of foliar injury also demonstrated the most sensitivity throughout the growing season, with symptoms rapidly advancing over ca. 25-30% of the total plant leaf surfaces by the end of the observation period. Conversely, those species that developed symptoms later in the season had far less total injury to plant foliage by the end of the observation period (1.5 to < 5% total leaf area injured). The current European ambient ozone standard may be insufficient to protect native plant species from visible foliar injury, and many more native species may be sensitive to ozone-induced foliar injury than are currently known.

A comparison of flame ionization and ozone chemiluminescence for the determination of atmospheric hydrocarbons.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marley, N. A.; Gaffney, J. S.; Environmental Research

A reactive hydrocarbon analyzer has been constructed on the basis of chemiluminescence reaction with ozone. This detector is designed to operate at varying temperatures which take advantage of the different rates of reaction of the hydrocarbon classes with ozone to yield a measure of their atmospheric reactivity. When operated at high temperatures (170 C), all hydrocarbons will give a chemiluminescence signal. Reported here is a direct comparison of the ozone chemiluminescent detector (operated at a temperature of 170 C) with a flame ionization detector. This comparison was accomplished by connecting a capillary gas chromatograph to each of the two detectorsmore » by means of a switching valve. Twenty-seven compounds representing alkanes, alkenes, aromatics, and oxygenated hydrocarbons (aldehydes, ketones, alcohols, and ethers) were studied. For the compounds studied, analytical sensitivities were 10-1000 times better for the chemiluminescence detector. The results of this comparison indicate that the response of the chemiluminescent detector at 170 C correlates with a total carbon detector (flame ionization detection) and that total response is a measure of total carbon in the sample. The chemiluminescent system will be very useful for gas chromatographic detection of atmospheric hydrocarbons, particularly of oxygenates in complex mixtures.« less

Temporal evolution of total ozone and circulation patterns over European mid-latitudes

NASA Astrophysics Data System (ADS)

Monge Sanz, B. M.; Casale, G. R.; Palmieri, S.; Siani, A. M.

2003-04-01

Linear correlation analysis and the running correlation technique are used to investigate the interannual and interdecadal variations of total ozone (TO) over several mid-latitude European locations. The study includes the longest series of ozone data, that of the Swiss station of Arosa. TO series have been related to time series of two circulation indices, the North Atlantic Oscillation Index (NAOI) and the Arctic Oscillation Index (AOI). The analysis has been performed with monthly data, and both series containing all the months of the year and winter (DJFM) series have been used. Special attention has been given to winter series, which exhibit very high correlation coefficients with NAOI and AOI; interannual variations of this relationship are studied by applying the running correlation technique. TO and circulation indices data series have been also partitioned into their different time-scale components with the Kolmogorov-Zurbenko method. Long-term components indicate the existence of strong opposite connection between total ozone and circulation patterns over the studied region during the last three decades. However, it is also observed that this relation has not always been so, and in previous times differences in the correlation amplitude and sign have been detected.

Evidence of Stratosphere-to-Troposphere Transport Within a Mesoscale Model and TOMS Total Ozone

NASA Technical Reports Server (NTRS)

Olsen, Mark A.; Stanford, John L.; Einaudi, Franco (Technical Monitor)

2001-01-01

We present evidence for stratospheric mass transport into, and remaining in, the troposphere in an intense midlatitude cyclone. Mesoscale forecast model analysis fields from the Mesoscale Analysis and Prediction System (MAPS) were compared with total ozone observations from the Total Ozone Measurement Spectrometer (TOMS). Coupled with parcel back-trajectory calculations, the analyses suggest two mechanisms contributed to the mass exchange: (1) A region of dynamical ly-induced exchange occurred on the cyclone's southern edge. Parcels originally in the stratosphere crossed the jet core and experienced dilution by turbulent mixing with tropospheric air. (2) Diabatic effects reduced parcel potential vorticity (PV) for trajectories traversing precipitation regions, resulting in a "PV-hole" signature in the cyclone center. Air with lower-stratospheric values of ozone and water vapor was left in the troposphere. The strength of the latter process may be atypical. These results, combined with other research, suggest that precipitation-induced diabatic effects can significantly modify, (either decreasing or increasing) parcel potential vorticity, depending on parcel trajectory configuration with respect to jet core and maximum heating regions. In addition, these results underscore the importance of using not only PV but also chemical constituents for diagnoses of stratosphere-troposphere exchange (STE).

Investigation of the structure and dynamics of the ozone layer in the Eastern Arctic region during EASOE Campaign

NASA Technical Reports Server (NTRS)

Khattatov, V.; Yushkov, V.; Rudakov, V.; Zaitsev, I.; Rosen, J.; Kjome, N.

1994-01-01

Balloon measurements of the vertical distribution of ozone and aerosol were made at Dickson Island (73 deg N, 81 deg E), Kiruna (68 deg N, 20 deg E) and Heiss Island (81 deg N, 58 deg E) from December 1991 to March 1992. To acquire data on the seasonal variability of the vertical ozone distribution, electrochemical ozonesondes ECC-4A were flown three times a week. With ozonesondes on the same balloons, backscattersondes were flown on the average of two or three times per month. Using these instruments, altitude profiles of backscatter ratio were measured at two wavelengths centered at 490 nm and 940 nm. Additionally, at Heiss Island, Dickson, and Yakutsk (63 deg N, 130 deg E) regular total ozone measurements were obtained using Brewer spectrophotometers. Based on measurements of backscatter ratio it was found that after the Pinatubo eruption in June 1991 significant amount of stratospheric aerosols were formed and transported to the Arctic before the polar vortex was well developed. Analysis of ozone data has shown a deep decrease of ozone concentration in the lower stratosphere in times of intensive transportation of air masses from low latitudes to the polar region in the second half of January and also for some periods in February and March of 1992. When the values of backscatter ratio beta were more than 8-10 at a wavelength of 940 nm strong anticorrelation occurred between aerosol loading and ozone concentration in the lower stratosphere. At 50-70 deg N, the mean monthly values of total ozone in winter-spring 1992 proved to be much lower than the climatic mean values.

Genetic dissection of ozone tolerance in rice (Oryza sativa L.) by a genome-wide association study

PubMed Central

Ueda, Yoshiaki; Frimpong, Felix; Qi, Yitao; Matthus, Elsa; Wu, Linbo; Höller, Stefanie; Kraska, Thorsten; Frei, Michael

2015-01-01

Tropospheric ozone causes various negative effects on plants and affects the yield and quality of agricultural crops. Here, we report a genome-wide association study (GWAS) in rice (Oryza sativa L.) to determine candidate loci associated with ozone tolerance. A diversity panel consisting of 328 accessions representing all subgroups of O. sativa was exposed to ozone stress at 60 nl l–1 for 7h every day throughout the growth season, or to control conditions. Averaged over all genotypes, ozone significantly affected biomass-related traits (plant height –1.0%, shoot dry weight –15.9%, tiller number –8.3%, grain weight –9.3%, total panicle weight –19.7%, single panicle weight –5.5%) and biochemical/physiological traits (symptom formation, SPAD value –4.4%, foliar lignin content +3.4%). A wide range of genotypic variance in response to ozone stress were observed in all phenotypes. Association mapping based on more than 30 000 single-nucleotide polymorphism (SNP) markers yielded 16 significant markers throughout the genome by applying a significance threshold of P<0.0001. Furthermore, by determining linkage disequilibrium blocks associated with significant SNPs, we gained a total of 195 candidate genes for these traits. The following sequence analysis revealed a number of novel polymorphisms in two candidate genes for the formation of visible leaf symptoms, a RING and an EREBP gene, both of which are involved in cell death and stress defence reactions. This study demonstrated substantial natural variation of responses to ozone in rice and the possibility of using GWAS in elucidating the genetic factors underlying ozone tolerance. PMID:25371505

Advanced oxidation-based treatment of furniture industry wastewater.

PubMed

Tichonovas, Martynas; Krugly, Edvinas; Grybauskas, Arturas; Jankūnaitė, Dalia; Račys, Viktoras; Martuzevičius, Dainius

2017-07-16

The paper presents a study on the treatment of the furniture industry wastewater in a bench scale advanced oxidation reactor. The researched technology utilized a simultaneous application of ozone, ultraviolet radiation and surface-immobilized TiO 2 nanoparticle catalyst. Various combinations of processes were tested, including photolysis, photocatalysis, ozonation, catalytic ozonation, photolytic ozonation and photocatalytic ozonation were tested against the efficiency of degradation. The efficiency of the processes was primarily characterized by the total organic carbon (TOC) analysis, indicating the remaining organic material in the wastewater after the treatment, while the toxicity changes in wastewater were researched by Daphnia magna toxicity tests. Photocatalytic ozonation was confirmed as the most effective combination of processes (99.3% of TOC reduction during 180 min of treatment), also being the most energy efficient (4.49-7.83 MJ/g). Photocatalytic ozonation and photolytic ozonation remained efficient across a wide range of pH (3-9), but the pH was an important factor in photocatalysis. The toxicity of wastewater depended on the duration of the treatment: half treated water was highly toxic, while fully treated water did not possess any toxicity. Our results indicate that photocatalytic ozonation has a high potential for the upscaling and application in industrial settings.

Estimating when the Antarctic Ozone Hole will Recover

NASA Technical Reports Server (NTRS)

Newman, Paul A.; Nash, Eric R.; Douglass, Anne R.; Nielsen, J. Eric; Pawson, Steven; Stolarski, Richard S.

2007-01-01

The Antarctic ozone hole develops each year and culminates by early spring (late September - early October). The severity of the hole has been assessed from satellites using the minimum total ozone value from the October monthly mean (depth of the hole) and by calculating the average area coverage during this September-October period. Profile information shows that ozone is completely destroyed in the 14-2 1 km layer by early October. Ozone is mainly destroyed by halogen (chlorine and bromine) catalytic cycles, and these losses are modulated by temperature variations. Because atmospheric halogen levels are responding to international a'greements that limit or phase out production, the amount of halogens in the stratosphere should decrease over the next few decades. Using projections of halogen levels combined with age-of-air estimates, we find that the ozone hole is recovering at an extremely slow rate and that large ozone holes will regularly recur over the next 2 decades. We estimate that the ozone hole will begin to show first signs of size decrease in about 2023, and the hole will fully recover to pre-1980 levels in approximately 2070. Estimates of the ozone hole's recovery from models reveal important differences that will be discussed.

Estimating When the Antarctic Ozone Hole Will Recover

NASA Technical Reports Server (NTRS)

Newman, Paul A.; Nash, Eric R.; Douglass, Anne R.; Nielsen, J. Eric; Pawson, Steven; Stolarski, Richard S.

2007-01-01

The Antarctic ozone hole develops each year and culminates by early spring (late September - early October). The severity of the hole has been assessed from satellites using the minimum total ozone value from the October monthly mean (depth of the hole) and by calculating the average area coverage during this September-October period. Profile information shows that ozone is completely destroyed in the 14-21 km layer by early October. Ozone is mainly destroyed by halogen (chlorine and bromine) catalytic cycles, and these losses are modulated by temperature variations. Because atmospheric halogen levels are responding to international agreements that limit or phase out production, the amount of halogens in the stratosphere should decrease over the next few decades. Using projections of halogen levels combined with age-of-air estimates, we find that the ozone hole is recovering at an extremely slow rate and that large ozone holes will regularly recur over the next 2 decades. We estimate that the ozone hole will begin to show first signs of size decrease in about 2023, and the hole will fully recover to pre-1980 levels in approximately 2070. Estimates of the ozone hole's recovery from models reveal important differences that will be discussed.

Balloon-Borne Measurements of Stratospheric Radicals and their Precursors: Implications for the Production and Loss of Ozone

NASA Technical Reports Server (NTRS)

Osterman, G. B.; Salawitch, R. J.; Sen, B.; Toon, G. C.; Stachnik, R. A.; Pickett, H. M.; Margitan, J. J.; Blavier, J.-F.; Peterson, D. B.

1997-01-01

Measurements of hydrogen, nitrogen and chlorine radicals from a balloon flight on 25 September 1993 from Ft. Sumner, NM provide an opportunity to quantify photochemical production and loss of stratospheric ozone. Ozone loss rates determined using measured radical concentrations agree fairly well with loss rates calculated using a photochemical model. Catalytic cycles involving OH and HO2 are shown to dominate photochemical loss of ozone for altitudes between 44 and 50 km. Reactions involving NO and NO2 are the dominant sink for ozone between 25 and 38 km. The total ozone loss rate determined from the measurements balances calculated production rates for altitudes between 30 and 40 km. However, loss of ozone exceeds production by -35% between 42 and 50 km. The imbalance between production and loss of ozone above 42 km is larger than the uncertainty of any one of the critical kinetic parameters or species concentrations. No single adjustment to any of these parameters can simultaneously resolve the imbalance and satisfy constraints imposed by measured OH, HO2, NO2 and ClO. Our results are consistent with an additional mechanism for ozone production above 40 km other than photolysis of ground state O2.

Ozone adsorption on carbon nanoparticles

NASA Astrophysics Data System (ADS)

Chassard, Guillaume; Gosselin, Sylvie; Visez, Nicolas; Petitprez, Denis

2014-05-01

Carbonaceous particles produced by incomplete combustion or thermal decomposition of hydrocarbons are ubiquitous in the atmosphere. On these particles are adsorbed hundreds of chemical species. Those of great concern to health are polycyclic aromatic hydrocarbons (PAHs). During atmospheric transport, particulate PAHs react with gaseous oxidants. The induced chemical transformations may change toxicity and hygroscopicity of these potentially inhalable particles. The interaction between ozone and carbon particles has been extensively investigated in literature. However ozone adsorption and surface reaction mechanisms are still ambiguous. Some studies described a fast catalytic decomposition of ozone initiated by an atomic oxygen chemisorption followed by a molecular oxygen release [1-3]. Others suggested a reversible ozone adsorption according to Langmuir-type behaviour [4,5]. The aim of this present study is a better understanding of ozone interaction with carbon surfaces. An aerosol of carbon nanoparticles was generated by flowing synthetic air in a glass tube containing pure carbon (primary particles < 50 nm), under magnetic stirring. The aerosol was then mixed with ozone in an aerosol flow tube. Ozone uptake experiments were performed with different particles concentrations with a fixed ozone concentration. The influence of several factors on kinetics was examined: initial ozone concentration, particle size (50 nm ≤ Dp ≤ 200 nm) and competitive adsorption (with probe molecule and water). The effect of initial ozone concentration was first studied. Accordingly to literature, it has been observed that the number of gas-phase ozone molecules lost per unit particle surface area tends towards a plateau for high ozone concentration suggesting a reversible ozone adsorption according to a Langmuir mechanism. We calculated the initial reaction probability between O3 and carbon particles.An initial uptake coefficient of 1.10-4 was obtained. Similar experiments were realized by selecting the particles size with a differential mobility analyser. We observed a strong size-dependent increase in reactivity with the decrease of particles size. This result is relevant for the health issues. Indeed the smallest particles are most likely to penetrate deep into the lungs. Competitive reactions between ozone and other species like H2O or atomic oxygen were also considered. Oxygen atoms were generated by photolysis of O3 (or O2) and were chosen because it is believed to form the same reactive oxygen intermediates than ozone. A weak water physisorption on soot was observed revealing hydrophobic properties of particles. Oxygen atoms were found to be strongly reactive. A Langmuir behavior was observed for oxygen atoms adsorption on carbon particles and we were able to determine an initial uptake coefficient of approximately 2.10-2. [1] Fenidel, W., et al., Interaction between carbon or iron aerosol particles and ozone. Atmospheric Environment, 1995. 29(9): p. 967-973. [2] Smith, D. and A. Chughtai, Reaction kinetics of ozone at low concentrations with n-hexane soot. Journal of geophysical research, 1996. 101(D14): p. 19607-19,620. [3] Kamm, S., et al., The heterogeneous reaction of ozone with soot aerosol. Atmospheric Environment, 1999. 33(28): p. 4651-4661. [4] Stephens, S., M.J. Rossi, and D.M. Golden, The heterogeneous reaction of ozone on carbonaceous surfaces. International journal of chemical kinetics, 1986. 18(10): p. 1133-1149. [5] Pöschl, U., et al., Interaction of ozone and water vapor with spark discharge soot aerosol particles coated with benzo [a] pyrene: O3 and H2O adsorption, benzo [a] pyrene degradation, and atmospheric implications. The Journal of Physical Chemistry A, 2001. 105(16): p. 4029-4041.

An assessment of the effect of supersonic aircraft operations on the stratospheric ozone content

NASA Technical Reports Server (NTRS)

Poppoff, I. G.; Whitten, R. C.; Turco, R. P.; Capone, L. A.

1978-01-01

An assessment of the potential effect on stratospheric ozone of an advanced supersonic transport operations is presented. This assessment, which was undertaken because of NASA's desire for an up-to-date evaluation to guide programs for the development of supersonic technology and improved aircraft engine designs, uses the most recent chemical reaction rate data. From the results of the present assessment it would appear that realistic fleet sizes should not cause concern with regard to the depletion of the total ozone overburden. For example, the NOx emission of one type designed to cruise at 20 km altitude will cause the ozone overburden to increase by 0.03% to 0.12%, depending upon which vertical transport is used. These ozone changes can be compared with the predictions of a 1.74% ozone decrease (for 100 Large SST's flying at 20 km) made in 1974 by the FAA's Climatic Impact Assessment Program.

The evolution of synoptic ozone anomalies during the European Arctic Stratospheric Ozone Experiment in winter 1991/1992

NASA Technical Reports Server (NTRS)

Zerefos, Christos S.; Balis, Dimitrios S.; Bais, Alkiviadis F.; Ziomas, Ioannis C.; Tourpali, Kleareti; Meleti, Chariklea; Tzoumaka, Paraskevi; Mantis, Homer T.; Repapis, Christos C.; Fioletov, Vitali E.

1994-01-01

The evolution of ozone anomalies over the middle and high latitudes of the Northern Hemisphere during the winter 1991-1992 is studied in this work. The largest monthly mean negative deviations in the middle latitudes of the Northern Hemisphere were about 10 percent in November and December, and up to 20 percent in January, February, and March over Eurasian territories, and much smaller over the Canadian sector. At the end of January, on individual days, total ozone values of 190-210 D.U. were observed over Eastern Europe and European part of Russia, that is 40-45 percent below normal. On the whole, the 1991-1992 winter was one of the most anomalous over all the period of ozone observations. Finally, an attempt is made to quantify the contribution of transport in the ozone layer changes over Europe during this period.

Ozone response to a CO2 doubling - Results from a stratospheric circulation model with heterogeneous chemistry

NASA Technical Reports Server (NTRS)

Pitari, G.; Palermi, S.; Visconti, G.; Prinn, R. G.

1992-01-01

A spectral 3D model of the stratosphere has been used to study the sensitivity of polar ozone with respect to a carbon dioxide increase. The lower stratospheric cooling associated with an imposed CO2 doubling may increase the probability of polar stratospheric cloud (PSC) formation and this affect ozone. The ozone perturbation obtained with the inclusion of a simple parameterization for heterogeneous chemistry on PSCs is compared to that relative to a pure homogeneous chemistry. In both cases the temperature perturbation is determined by a CO2 doubling, while the total chlorine content is kept at the present level. It is shown that the lower temperature may increase the depth and the extension of the ozone hole by extending the area amenable to PSC formation. It may be argued that this effect, coupled with an increasing amount of chlorine, may produce a positive feedback on the ozone destruction.

Development of a Climate Record of Tropospheric and Stratospheric Column Ozone from Satellite Remote Sensing: Evidence of an Early Recovery of Global Stratospheric Ozone

NASA Technical Reports Server (NTRS)

Ziemke, Jerald R.; Chandra, Sushil

2012-01-01

Ozone data beginning October 2004 from the Aura Ozone Monitoring Instrument (OMI) and Aura Microwave Limb Sounder (MLS) are used to evaluate the accuracy of the Cloud Slicing technique in effort to develop long data records of tropospheric and stratospheric ozone and for studying their long-term changes. Using this technique, we have produced a 32-yr (1979-2010) long record of tropospheric and stratospheric column ozone from the combined Total Ozone Mapping Spectrometer (TOMS) and OMI. Analyses of these time series suggest that the quasi-biennial oscillation (QBO) is the dominant source of inter-annual variability of stratospheric ozone and is clearest in the Southern Hemisphere during the Aura time record with related inter-annual changes of 30- 40 Dobson Units. Tropospheric ozone for the long record also indicates a QBO signal in the tropics with peak-to-peak changes varying from 2 to 7 DU. The most important result from our study is that global stratospheric ozone indicates signature of a recovery occurring with ozone abundance now approaching the levels of year 1980 and earlier. The negative trends in stratospheric ozone in both hemispheres during the first 15 yr of the record are now positive over the last 15 yr and with nearly equal magnitudes. This turnaround in stratospheric ozone loss is occurring about 20 yr earlier than predicted by many chemistry climate models. This suggests that the Montreal Protocol which was first signed in 1987 as an international agreement to reduce ozone destroying substances is working well and perhaps better than anticipated.

Detection and Attribution of the Recovery of Polar Ozone

NASA Technical Reports Server (NTRS)

Newman, Paul A.; Nash, E. R.; Douglass, A. R.; Nielsen, J. E.; Pawson, S.; Stolarski, R. S.

2008-01-01

The Antarctic ozone hole develops each year and culminates by early spring (late September - early October). The severity of the hole has been assessed from satellites using the minimum total ozone value from the October monthly mean (depth of the hole), calculating the average area coverage during this September-October period, and by estimating ozone mass deficit. Profile information shows that ozone is completely destroyed in the 14-2 1 km layer by early October. Ozone is mainly destroyed by halogen (chlorine and bromine) catalytic cycles, and these losses are modulated by temperature variations. Because atmospheric halogen levels are responding to international agreements that limit or phase out production, the amount of halogens in the stratosphere should decrease over the next few decades. Both models and projections of ozone depleting substances (ODSs) into the 21St century reveal that polar ozone levels should recover in the 2060- 2070 period. In this talk, we will review current projections of polar ozone recovery. Using models and ODs projections, we explore both the past, near future (2008-2025), and far future (> 2025) levels of polar ozone. Finally, we will discuss various factors that complicate recovery such as greenhouse gas changes (e.g., cooling in the upper stratosphere) and the acceleration of the Brewer-Dobson circulation.

Impact of ozonation on naphthenic acids speciation and toxicity of oil sands process-affected water to Vibrio fischeri and mammalian immune system.

PubMed

Wang, Nan; Chelme-Ayala, Pamela; Perez-Estrada, Leonidas; Garcia-Garcia, Erick; Pun, Jonathan; Martin, Jonathan W; Belosevic, Miodrag; Gamal El-Din, Mohamed

2013-06-18

Oil sands process-affected water (OSPW) is the water contained in tailings impoundment structures in oil sands operations. There are concerns about the environmental impacts of the release of OSPW because of its toxicity. In this study, ozonation followed by biodegradation was used to remediate OSPW. The impacts of the ozone process evolution on the naphthenic acids (NAs) speciation and acute toxicity were evaluated. Ion-mobility spectrometry (IMS) was used to preliminarily separate isomeric and homologous species. The results showed limited effects of the ozone reactor size on the treatment performance in terms of contaminant removal. In terms of NAs speciation, high reactivity of NAs with higher number of carbons and rings was only observed in a region of high reactivity (i.e., utilized ozone dose lower than 50 mg/L). It was also found that nearly 0.5 mg/L total NAs was oxidized per mg/L of utilized ozone dose, at utilized ozone doses lower than 50 mg/L. IMS showed that ozonation was able to degrade NAs, oxidized NAs, and sulfur/nitrogenated NAs. Complete removal of toxicity toward Vibrio fischeri was achieved after ozonation followed by 28-day biodegradation period. In vitro and in vivo assays indicated that ozonation reduced the OSPW toxicity to mice.

UV-B radiation amplification factor determined based on the simultaneous observation of total ozone and global spectral irradiance

NASA Technical Reports Server (NTRS)

Ito, T.; Sakoda, Y.; Matsubara, K.; Kajihara, R.; Uekubo, T.; Kobayashi, M.; Shitamichi, M.; Ueno, T.; Ito, M.

1994-01-01

The Japan Meteorological Agency started the spectral observation of solar ultraviolet (UV) irradiance on 1 January 1990 at Tateno, Aerological Observatory in Tsukuba (35 deg N, 140 deg E). The observation has been carried out using the Brewer spectrophotometer for the wavelengths from 290 to 325 nm with a 0.5 nm interval every hour from 30 minutes before sunrise to 30 minutes after sunset throughout a year. Because of remarkable similarity within observed spectra, an observed spectrum can be expressed by a simple combination of a reference spectrum and two parameters expressing the deformation of the observed spectrum from the reference. By use of the relation between one of the deformation parameters and the total ozone simultaneously observed with the Dobson spectrophotometer, the possible increase of UV irradiance due to ozone depletion is estimated. For damaging UV, the irradiance possibly increases about 19 percent with the ozone depletion of 10 percent at noon throughout the year in the northern midlatitudes. DUV at noon on the summer solstice possibly increases about 5.6 percent with the ozone depletion of 10 m atm-cm for all latitudes in the Northern Hemisphere.