Sample records for process variables temperature

  1. Dynamic control of remelting processes

    DOEpatents

    Bertram, Lee A.; Williamson, Rodney L.; Melgaard, David K.; Beaman, Joseph J.; Evans, David G.

    2000-01-01

    An apparatus and method of controlling a remelting process by providing measured process variable values to a process controller; estimating process variable values using a process model of a remelting process; and outputting estimated process variable values from the process controller. Feedback and feedforward control devices receive the estimated process variable values and adjust inputs to the remelting process. Electrode weight, electrode mass, electrode gap, process current, process voltage, electrode position, electrode temperature, electrode thermal boundary layer thickness, electrode velocity, electrode acceleration, slag temperature, melting efficiency, cooling water temperature, cooling water flow rate, crucible temperature profile, slag skin temperature, and/or drip short events are employed, as are parameters representing physical constraints of electroslag remelting or vacuum arc remelting, as applicable.

  2. Collaborative Research: Process-Resolving Decomposition of the Global Temperature Response to Modes of Low Frequency Variability in a Changing Climate

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Deng, Yi

    2014-11-24

    DOE-GTRC-05596 11/24/2104 Collaborative Research: Process-Resolving Decomposition of the Global Temperature Response to Modes of Low Frequency Variability in a Changing Climate PI: Dr. Yi Deng (PI) School of Earth and Atmospheric Sciences Georgia Institute of Technology 404-385-1821, yi.deng@eas.gatech.edu El Niño-Southern Oscillation (ENSO) and Annular Modes (AMs) represent respectively the most important modes of low frequency variability in the tropical and extratropical circulations. The projection of future changes in the ENSO and AM variability, however, remains highly uncertain with the state-of-the-science climate models. This project conducted a process-resolving, quantitative evaluations of the ENSO and AM variability in the modern reanalysis observationsmore » and in climate model simulations. The goal is to identify and understand the sources of uncertainty and biases in models’ representation of ENSO and AM variability. Using a feedback analysis method originally formulated by one of the collaborative PIs, we partitioned the 3D atmospheric temperature anomalies and surface temperature anomalies associated with ENSO and AM variability into components linked to 1) radiation-related thermodynamic processes such as cloud and water vapor feedbacks, 2) local dynamical processes including convection and turbulent/diffusive energy transfer and 3) non-local dynamical processes such as the horizontal energy transport in the oceans and atmosphere. In the past 4 years, the research conducted at Georgia Tech under the support of this project has led to 15 peer-reviewed publications and 9 conference/workshop presentations. Two graduate students and one postdoctoral fellow also received research training through participating the project activities. This final technical report summarizes key scientific discoveries we made and provides also a list of all publications and conference presentations resulted from research activities at Georgia Tech. The main findings include: 1) the distinctly different roles played by atmospheric dynamical processes in establishing surface temperature response to ENSO at tropics and extratropics (i.e., atmospheric dynamics disperses energy out of tropics during ENSO warm events and modulate surface temperature at mid-, high-latitudes through controlling downward longwave radiation); 2) the representations of ENSO-related temperature response in climate models fail to converge at the process-level particularly over extratropics (i.e., models produce the right temperature responses to ENSO but with wrong reasons); 3) water vapor feedback contributes substantially to the temperature anomalies found over U.S. during different phases of the Northern Annular Mode (NAM), which adds new insight to the traditional picture that cold/warm advective processes are the main drivers of local temperature responses to the NAM; 4) the overall land surface temperature biases in the latest NCAR model (CESM1) are caused by biases in surface albedo while the surface temperature biases over ocean are related to multiple factors including biases in model albedo, cloud and oceanic dynamics, and the temperature biases over different ocean basins are also induced by different process biases. These results provide a detailed guidance for process-level model turning and improvement, and thus contribute directly to the overall goal of reducing model uncertainty in projecting future changes in the Earth’s climate system, especially in the ENSO and AM variability.« less

  3. Collaborative Research: Process-resolving Decomposition of the Global Temperature Response to Modes of Low Frequency Variability in a Changing Climate

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cai, Ming; Deng, Yi

    2015-02-06

    El Niño-Southern Oscillation (ENSO) and Annular Modes (AMs) represent respectively the most important modes of low frequency variability in the tropical and extratropical circulations. The future projection of the ENSO and AM variability, however, remains highly uncertain with the state-of-the-art coupled general circulation models. A comprehensive understanding of the factors responsible for the inter-model discrepancies in projecting future changes in the ENSO and AM variability, in terms of multiple feedback processes involved, has yet to be achieved. The proposed research aims to identify sources of such uncertainty and establish a set of process-resolving quantitative evaluations of the existing predictions ofmore » the future ENSO and AM variability. The proposed process-resolving evaluations are based on a feedback analysis method formulated in Lu and Cai (2009), which is capable of partitioning 3D temperature anomalies/perturbations into components linked to 1) radiation-related thermodynamic processes such as cloud and water vapor feedbacks, 2) local dynamical processes including convection and turbulent/diffusive energy transfer and 3) non-local dynamical processes such as the horizontal energy transport in the oceans and atmosphere. Taking advantage of the high-resolution, multi-model ensemble products from the Coupled Model Intercomparison Project Phase 5 (CMIP5) soon to be available at the Lawrence Livermore National Lab, we will conduct a process-resolving decomposition of the global three-dimensional (3D) temperature (including SST) response to the ENSO and AM variability in the preindustrial, historical and future climate simulated by these models. Specific research tasks include 1) identifying the model-observation discrepancies in the global temperature response to ENSO and AM variability and attributing such discrepancies to specific feedback processes, 2) delineating the influence of anthropogenic radiative forcing on the key feedback processes operating on ENSO and AM variability and quantifying their relative contributions to the changes in the temperature anomalies associated with different phases of ENSO and AMs, and 3) investigating the linkages between model feedback processes that lead to inter-model differences in time-mean temperature projection and model feedback processes that cause inter-model differences in the simulated ENSO and AM temperature response. Through a thorough model-observation and inter-model comparison of the multiple energetic processes associated with ENSO and AM variability, the proposed research serves to identify key uncertainties in model representation of ENSO and AM variability, and investigate how the model uncertainty in predicting time-mean response is related to the uncertainty in predicting response of the low-frequency modes. The proposal is thus a direct response to the first topical area of the solicitation: Interaction of Climate Change and Low Frequency Modes of Natural Climate Variability. It ultimately supports the accomplishment of the BER climate science activity Long Term Measure (LTM): "Deliver improved scientific data and models about the potential response of the Earth's climate and terrestrial biosphere to increased greenhouse gas levels for policy makers to determine safe levels of greenhouse gases in the atmosphere."« less

  4. Soil temperature variability in complex terrain measured using fiber-optic distributed temperature sensing

    USDA-ARS?s Scientific Manuscript database

    Soil temperature (Ts) exerts critical controls on hydrologic and biogeochemical processes but magnitude and nature of Ts variability in a landscape setting are rarely documented. Fiber optic distributed temperature sensing systems (FO-DTS) potentially measure Ts at high density over a large extent. ...

  5. Temperature-Robust Neural Function from Activity-Dependent Ion Channel Regulation.

    PubMed

    O'Leary, Timothy; Marder, Eve

    2016-11-07

    Many species of cold-blooded animals experience substantial and rapid fluctuations in body temperature. Because biological processes are differentially temperature dependent, it is difficult to understand how physiological processes in such animals can be temperature robust [1-8]. Experiments have shown that core neural circuits, such as the pyloric circuit of the crab stomatogastric ganglion (STG), exhibit robust neural activity in spite of large (20°C) temperature fluctuations [3, 5, 7, 8]. This robustness is surprising because (1) each neuron has many different kinds of ion channels with different temperature dependencies (Q 10 s) that interact in a highly nonlinear way to produce firing patterns and (2) across animals there is substantial variability in conductance densities that nonetheless produce almost identical firing properties. The high variability in conductance densities in these neurons [9, 10] appears to contradict the possibility that robustness is achieved through precise tuning of key temperature-dependent processes. In this paper, we develop a theoretical explanation for how temperature robustness can emerge from a simple regulatory control mechanism that is compatible with highly variable conductance densities [11-13]. The resulting model suggests a general mechanism for how nervous systems and excitable tissues can exploit degenerate relationships among temperature-sensitive processes to achieve robust function. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Isolation of fish skin and bone gelatin from tilapia (Oreochromis niloticus): Response surface approach

    NASA Astrophysics Data System (ADS)

    Arpi, N.; Fahrizal; Novita, M.

    2018-03-01

    In this study, gelatin from fish collagen, as one of halal sources, was extracted from tilapia (Oreochromis niloticus) skin and bone, by using Response Surface Methodology to optimize gelatin extraction conditions. Concentrations of alkaline NaOH and acid HCl, in the pretreatment process, and temperatures in extraction process were chosen as independent variables, while dependent variables were yield, gel strength, and emulsion activity index (EAI). The result of investigation showed that lower NaOH pretreatment concentrations provided proper pH extraction conditions which combine with higher extraction temperatures resulted in high gelatin yield. However, gelatin emulsion activity index increased proportionally to the decreased in NaOH concentrations and extraction temperatures. No significant effect of the three independent variables on the gelatin gel strength. RSM optimization process resulted in optimum gelatin extraction process conditions using alkaline NaOH concentration of 0.77 N, acid HCl of 0.59 N, and extraction temperature of 66.80 °C. The optimal solution formula had optimization targets of 94.38%.

  7. Temperature and relative humidity estimation and prediction in the tobacco drying process using Artificial Neural Networks.

    PubMed

    Martínez-Martínez, Víctor; Baladrón, Carlos; Gomez-Gil, Jaime; Ruiz-Ruiz, Gonzalo; Navas-Gracia, Luis M; Aguiar, Javier M; Carro, Belén

    2012-10-17

    This paper presents a system based on an Artificial Neural Network (ANN) for estimating and predicting environmental variables related to tobacco drying processes. This system has been validated with temperature and relative humidity data obtained from a real tobacco dryer with a Wireless Sensor Network (WSN). A fitting ANN was used to estimate temperature and relative humidity in different locations inside the tobacco dryer and to predict them with different time horizons. An error under 2% can be achieved when estimating temperature as a function of temperature and relative humidity in other locations. Moreover, an error around 1.5 times lower than that obtained with an interpolation method can be achieved when predicting the temperature inside the tobacco mass as a function of its present and past values with time horizons over 150 minutes. These results show that the tobacco drying process can be improved taking into account the predicted future value of the monitored variables and the estimated actual value of other variables using a fitting ANN as proposed.

  8. Temperature and Relative Humidity Estimation and Prediction in the Tobacco Drying Process Using Artificial Neural Networks

    PubMed Central

    Martínez-Martínez, Víctor; Baladrón, Carlos; Gomez-Gil, Jaime; Ruiz-Ruiz, Gonzalo; Navas-Gracia, Luis M.; Aguiar, Javier M.; Carro, Belén

    2012-01-01

    This paper presents a system based on an Artificial Neural Network (ANN) for estimating and predicting environmental variables related to tobacco drying processes. This system has been validated with temperature and relative humidity data obtained from a real tobacco dryer with a Wireless Sensor Network (WSN). A fitting ANN was used to estimate temperature and relative humidity in different locations inside the tobacco dryer and to predict them with different time horizons. An error under 2% can be achieved when estimating temperature as a function of temperature and relative humidity in other locations. Moreover, an error around 1.5 times lower than that obtained with an interpolation method can be achieved when predicting the temperature inside the tobacco mass as a function of its present and past values with time horizons over 150 minutes. These results show that the tobacco drying process can be improved taking into account the predicted future value of the monitored variables and the estimated actual value of other variables using a fitting ANN as proposed. PMID:23202032

  9. Study of process variables associated with manufacturing hermetically-sealed nickel-cadmium cells

    NASA Technical Reports Server (NTRS)

    Miller, L.

    1974-01-01

    A two year study of the major process variables associated with the manufacturing process for sealed, nickel-cadmium, areospace cells is summarized. Effort was directed toward identifying the major process variables associated with a manufacturing process, experimentally assessing each variable's effect, and imposing the necessary changes (optimization) and controls for the critical process variables to improve results and uniformity. A critical process variable associated with the sintered nickel plaque manufacturing process was identified as the manual forming operation. Critical process variables identified with the positive electrode impregnation/polarization process were impregnation solution temperature, free acid content, vacuum impregnation, and sintered plaque strength. Positive and negative electrodes were identified as a major source of carbonate contamination in sealed cells.

  10. Thermal Management in Friction-Stir Welding of Precipitation-Hardening Aluminum Alloys

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Upadhyay, Piyush; Reynolds, Anthony

    2015-05-25

    Process design and implementation in FSW is mostly dependent on empirical information gathered through experience. Basic science of friction stir welding and processing can only be complete when fundamental interrelationships between process control parameters and response variables and resulting weld microstructure and properties are established to a reasonable extent. It is known that primary process control parameters like tool rotation and translation rate and forge axis force have complicated and interactive relationships to the process response variables such as peak temperature, time at temperature etc. Of primary influence to the other process response parameters are temperature and its gradient atmore » the deformation and heat affected zones. Through review of pertinent works in the literature and some experimental results from boundary condition work performed in precipitation hardening aluminum alloys this paper will partially elucidate the nature and effects of temperature transients caused by variation of thermal boundaries in Friction Stir Welding.« less

  11. Thermal Management in Friction-Stir Welding of Precipitation-Hardened Aluminum Alloys

    NASA Astrophysics Data System (ADS)

    Upadhyay, Piyush; Reynolds, Anthony P.

    2015-05-01

    Process design and implementation in friction-stir welding (FSW) is mostly dependent on empirical information. Basic science of FSW and processing can only be complete when fundamental interrelationships between the process control parameters and response variables and the resulting weld microstructure and properties are established to a reasonable extent. It is known that primary process control parameters such as tool rotation, translation rates, and forge axis force have complicated and interactive relationships to process-response variables such as peak temperature and time at temperature. Of primary influence on the other process-response parameters are temperature and its gradient in the deformation and heat-affected zones. Through a review of pertinent works in the literature and results from boundary condition experiments performed in precipitation-hardening aluminum alloys, this article partially elucidates the nature and effects of temperature transients caused by variation of thermal boundaries in FSW.

  12. Selecting the process variables for filament winding

    NASA Technical Reports Server (NTRS)

    Calius, E.; Springer, G. S.

    1986-01-01

    A model is described which can be used to determine the appropriate values of the process variables for filament winding cylinders. The process variables which can be selected by the model include the winding speed, fiber tension, initial resin degree of cure, and the temperatures applied during winding, curing, and post-curing. The effects of these process variables on the properties of the cylinder during and after manufacture are illustrated by a numerical example.

  13. Analysis of the temperature of the hot tool in the cut of woven fabric using infrared images

    NASA Astrophysics Data System (ADS)

    Borelli, Joao E.; Verderio, Leonardo A.; Gonzaga, Adilson; Ruffino, Rosalvo T.

    2001-03-01

    Textile manufacture occupies a prominence place in the national economy. By virtue of its importance researches have been made on the development of new materials, equipment and methods used in the production process. The cutting of textiles starts in the basic stage, to be followed within the process of the making of clothes and other articles. In the hot cutting of fabric, one of the variables of great importance in the control of the process is the contact temperature between the tool and the fabric. The work presents a technique for the measurement of the temperature based on the processing of infrared images. For this a system was developed composed of an infrared camera, a framegrabber PC board and software that analyzes the punctual temperature in the cut area enabling the operator to achieve the necessary control of the other variables involved in the process.

  14. Effects of short-term variability of meteorological variables on soil temperature in permafrost regions

    NASA Astrophysics Data System (ADS)

    Beer, Christian; Porada, Philipp; Ekici, Altug; Brakebusch, Matthias

    2018-03-01

    Effects of the short-term temporal variability of meteorological variables on soil temperature in northern high-latitude regions have been investigated. For this, a process-oriented land surface model has been driven using an artificially manipulated climate dataset. Short-term climate variability mainly impacts snow depth, and the thermal diffusivity of lichens and bryophytes. These impacts of climate variability on insulating surface layers together substantially alter the heat exchange between atmosphere and soil. As a result, soil temperature is 0.1 to 0.8 °C higher when climate variability is reduced. Earth system models project warming of the Arctic region but also increasing variability of meteorological variables and more often extreme meteorological events. Therefore, our results show that projected future increases in permafrost temperature and active-layer thickness in response to climate change will be lower (i) when taking into account future changes in short-term variability of meteorological variables and (ii) when representing dynamic snow and lichen and bryophyte functions in land surface models.

  15. Closing the Seasonal Ocean Surface Temperature Balance in the Eastern Tropical Oceans from Remote Sensing and Model Reanalyses

    NASA Technical Reports Server (NTRS)

    Roberts, J. Brent; Clayson, Carol A.

    2012-01-01

    The Eastern tropical ocean basins are regions of significant atmosphere-ocean interaction and are important to variability across subseasonal to decadal time scales. The numerous physical processes at play in these areas strain the abilities of coupled general circulation models to accurately reproduce observed upper ocean variability. Furthermore, limitations in the observing system of important terms in the surface temperature balance (e.g., turbulent and radiative heat fluxes, advection) introduce uncertainty into the analyses of processes controlling sea surface temperature variability. This study presents recent efforts to close the surface temperature balance through estimation of the terms in the mixed layer temperature budget using state-of-the-art remotely sensed and model-reanalysis derived products. A set of twelve net heat flux estimates constructed using combinations of radiative and turbulent heat flux products - including GEWEX-SRB, ISCCP-SRF, OAFlux, SeaFlux, among several others - are used with estimates of oceanic advection, entrainment, and mixed layer depth variability to investigate the seasonal variability of ocean surface temperatures. Particular emphasis is placed on how well the upper ocean temperature balance is, or is not, closed on these scales using the current generation of observational and model reanalysis products. That is, the magnitudes and spatial variability of residual imbalances are addressed. These residuals are placed into context within the current uncertainties of the surface net heat fluxes and the role of the mixed layer depth variability in scaling the impact of those uncertainties, particularly in the shallow mixed layers of the Eastern tropical ocean basins.

  16. Ground-based thermography of fluvial systems at low and high discharge reveals potential complex thermal heterogeneity driven by flow variation and bioroughness

    USGS Publications Warehouse

    Cardenas, M.B.; Harvey, J.W.; Packman, A.I.; Scott, D.T.

    2008-01-01

    Temperature is a primary physical and biogeochemical variable in aquatic systems. Field-based measurement of temperature at discrete sampling points has revealed temperature variability in fluvial systems, but traditional techniques do not readily allow for synoptic sampling schemes that can address temperature-related questions with broad, yet detailed, coverage. We present results of thermal infrared imaging at different stream discharge (base flow and peak flood) conditions using a handheld IR camera. Remotely sensed temperatures compare well with those measured with a digital thermometer. The thermal images show that periphyton, wood, and sandbars induce significant thermal heterogeneity during low stages. Moreover, the images indicate temperature variability within the periphyton community and within the partially submerged bars. The thermal heterogeneity was diminished during flood inundation, when the areas of more slowly moving water to the side of the stream differed in their temperature. The results have consequences for thermally sensitive hydroelogical processes and implications for models of those processes, especially those that assume an effective stream temperature. Copyright ?? 2008 John Wiley & Sons, Ltd.

  17. Variable-temperature Fourier transform near-infrared imaging spectroscopy of the deuterium/hydrogen exchange in liquid D₂O.

    PubMed

    Unger, Miriam; Ozaki, Yukihiro; Siesler, Heinz W

    2014-01-01

    In the present publication, the deuterium/hydrogen (D/H) exchange of liquid D2O exposed to water vapor of the surrounding atmosphere has been studied by variable-temperature Fourier transform near-infrared (FT-NIR) imaging spectroscopy. Apart from the visualization of the exchange process in the time-resolved FT-NIR images, kinetic parameters and the activation energy for this D/H exchange reaction have been derived from the Arrhenius plot of the variable-temperature spectroscopic data.

  18. Influence of Processing Parameters on the Flow Path in Friction Stir Welding

    NASA Technical Reports Server (NTRS)

    Schneider, J. A.; Nunes, A. C., Jr.

    2006-01-01

    Friction stir welding (FSW) is a solid phase welding process that unites thermal and mechanical aspects to produce a high quality joint. The process variables are rpm, translational weld speed, and downward plunge force. The strain-temperature history of a metal element at each point on the cross-section of the weld is determined by the individual flow path taken by the particular filament of metal flowing around the tool as influenced by the process variables. The resulting properties of the weld are determined by the strain-temperature history. Thus to control FSW properties, improved understanding of the processing parameters on the metal flow path is necessary.

  19. Effects of processing variables on the sensitometric properties of Eastman Kodak film type 2445

    NASA Technical Reports Server (NTRS)

    Weinstein, M. S.

    1972-01-01

    The sensitometric characteristics of Kodak color negative film Type 2445 with processing in a 1411 versamat with Kodak aero-neg. color process chemicals are described. These characteristics were determined for various combinations of machine speed, prehardener temperature, and first developer temperature.

  20. On the Design of a Fuzzy Logic-Based Control System for Freeze-Drying Processes.

    PubMed

    Fissore, Davide

    2016-12-01

    This article is focused on the design of a fuzzy logic-based control system to optimize a drug freeze-drying process. The goal of the system is to keep product temperature as close as possible to the threshold value of the formulation being processed, without trespassing it, in such a way that product quality is not jeopardized and the sublimation flux is maximized. The method involves the measurement of product temperature and a set of rules that have been obtained through process simulation with the goal to obtain a unique set of rules for products with very different characteristics. Input variables are the difference between the temperature of the product and the threshold value, the difference between the temperature of the heating fluid and that of the product, and the rate of change of product temperature. The output variables are the variation of the temperature of the heating fluid and the pressure in the drying chamber. The effect of the starting value of the input variables and of the control interval has been investigated, thus resulting in the optimal configuration of the control system. Experimental investigation carried out in a pilot-scale freeze-dryer has been carried out to validate the proposed system. Copyright © 2016 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

  1. The Nature of Antarctic Temperature Change

    NASA Astrophysics Data System (ADS)

    Markle, B. R.; Steig, E. J.

    2017-12-01

    The Antarctic is an important component of global climate. While the Arctic has warmed significantly in the last century, the Antarctic as a whole has shown considerably less variability. There is, however, a pronounced spatial pattern to modern Antarctic temperature change. The high East Antarctic Ice Sheet shows little to no warming over recent decades while West Antarctica and the Peninsula shows some of the largest rates of warming on the globe. Examining past climate variability can help reveal the physical processes governing this spatial pattern of Antarctic temperature change. Modern Antarctic temperature variability is known from satellite and weather station observations. Understanding changes in the past, however, requires paleoclimate-proxies such as ice-core water-isotope records. Here we assess the spatial pattern of Antarctic temperature changes across a range of timescales, from modern decadal changes to millennial and orbital-scale variability. We reconstruct past changes in absolute temperatures from a suite of deep ice core records and an improved isotope-temperature reconstruction method. We use δ18O and deuterium excess records to reconstruct both evaporation source and condensation site temperatures. In contrast to previous studies we use a novel method that accounts for nonlinearities in the water-isotope distillation process. We quantify past temperature changes over the Southern Ocean and Antarctic Continent and the magnitude of polar amplification. We identify patterns of Antarctic temperature change that are common across a wide range of timescales and independent of the source of forcing. We examine the nature of these changes and their relationship to atmospheric thermodynamics.

  2. Stochastic investigation of temperature process for climatic variability identification

    NASA Astrophysics Data System (ADS)

    Lerias, Eleutherios; Kalamioti, Anna; Dimitriadis, Panayiotis; Markonis, Yannis; Iliopoulou, Theano; Koutsoyiannis, Demetris

    2016-04-01

    The temperature process is considered as the most characteristic hydrometeorological process and has been thoroughly examined in the climate-change framework. We use a dataset comprising hourly temperature and dew point records to identify statistical variability with emphasis on the last period. Specifically, we investigate the occurrence of mean, maximum and minimum values and we estimate statistical properties such as marginal probability distribution function and the type of decay of the climacogram (i.e., mean process variance vs. scale) for various time periods. Acknowledgement: This research is conducted within the frame of the undergraduate course "Stochastic Methods in Water Resources" of the National Technical University of Athens (NTUA). The School of Civil Engineering of NTUA provided moral support for the participation of the students in the Assembly.

  3. Long-memory and the sea level-temperature relationship: a fractional cointegration approach.

    PubMed

    Ventosa-Santaulària, Daniel; Heres, David R; Martínez-Hernández, L Catalina

    2014-01-01

    Through thermal expansion of oceans and melting of land-based ice, global warming is very likely contributing to the sea level rise observed during the 20th century. The amount by which further increases in global average temperature could affect sea level is only known with large uncertainties due to the limited capacity of physics-based models to predict sea levels from global surface temperatures. Semi-empirical approaches have been implemented to estimate the statistical relationship between these two variables providing an alternative measure on which to base potentially disrupting impacts on coastal communities and ecosystems. However, only a few of these semi-empirical applications had addressed the spurious inference that is likely to be drawn when one nonstationary process is regressed on another. Furthermore, it has been shown that spurious effects are not eliminated by stationary processes when these possess strong long memory. Our results indicate that both global temperature and sea level indeed present the characteristics of long memory processes. Nevertheless, we find that these variables are fractionally cointegrated when sea-ice extent is incorporated as an instrumental variable for temperature which in our estimations has a statistically significant positive impact on global sea level.

  4. Process optimization for osmo-dehydrated carambola (Averrhoa carambola L) slices and its storage studies.

    PubMed

    Roopa, N; Chauhan, O P; Raju, P S; Das Gupta, D K; Singh, R K R; Bawa, A S

    2014-10-01

    An osmotic-dehydration process protocol for Carambola (Averrhoacarambola L.,), an exotic star shaped tropical fruit, was developed. The process was optimized using Response Surface Methodology (RSM) following Central Composite Rotatable Design (CCRD). The experimental variables selected for the optimization were soak solution concentration (°Brix), soaking temperature (°C) and soaking time (min) with 6 experiments at central point. The effect of process variables was studied on solid gain and water loss during osmotic dehydration process. The data obtained were analyzed employing multiple regression technique to generate suitable mathematical models. Quadratic models were found to fit well (R(2), 95.58 - 98.64 %) in describing the effect of variables on the responses studied. The optimized levels of the process variables were achieved at 70°Brix, 48 °C and 144 min for soak solution concentration, soaking temperature and soaking time, respectively. The predicted and experimental results at optimized levels of variables showed high correlation. The osmo-dehydrated product prepared at optimized conditions showed a shelf-life of 10, 8 and 6 months at 5 °C, ambient (30 ± 2 °C) and 37 °C, respectively.

  5. Chapter 6: Temperature

    USGS Publications Warehouse

    Jones, Leslie A.; Muhlfeld, Clint C.; Hauer, F. Richard; F. Richard Hauer,; Lamberti, G.A.

    2017-01-01

    Stream temperature has direct and indirect effects on stream ecology and is critical in determining both abiotic and biotic system responses across a hierarchy of spatial and temporal scales. Temperature variation is primarily driven by solar radiation, while landscape topography, geology, and stream reach scale ecosystem processes contribute to local variability. Spatiotemporal heterogeneity in freshwater ecosystems influences habitat distributions, physiological functions, and phenology of all aquatic organisms. In this chapter we provide an overview of methods for monitoring stream temperature, characterization of thermal profiles, and modeling approaches to stream temperature prediction. Recent advances in temperature monitoring allow for more comprehensive studies of the underlying processes influencing annual variation of temperatures and how thermal variability may impact aquatic organisms at individual, population, and community based scales. Likewise, the development of spatially explicit predictive models provide a framework for simulating natural and anthropogenic effects on thermal regimes which is integral for sustainable management of freshwater systems.

  6. A review of precipitation and temperature control on seedling emergence and establishment for ponderosa and lodgepole pine forest regeneration

    USGS Publications Warehouse

    Petrie, Matthew; Wildeman, A.M.; Bradford, John B.; Hubbard, R.M.; Lauenroth, W.K.

    2016-01-01

    The persistence of ponderosa pine and lodgepole pine forests in the 21st century depends to a large extent on how seedling emergence and establishment are influenced by driving climate and environmental variables, which largely govern forest regeneration. We surveyed the literature, and identified 96 publications that reported data on dependent variables of seedling emergence and/or establishment and one or more independent variables of air temperature, soil temperature, precipitation and moisture availability. Our review suggests that seedling emergence and establishment for both species is highest at intermediate temperatures (20 to 25 °C), and higher precipitation and higher moisture availability support a higher percentage of seedling emergence and establishment at daily, monthly and annual timescales. We found that ponderosa pine seedlings may be more sensitive to temperature fluctuations whereas lodgepole pine seedlings may be more sensitive to moisture fluctuations. In a changing climate, increasing temperatures and declining moisture availability may hinder forest persistence by limiting seedling processes. Yet, only 23 studies in our review investigated the effects of driving climate and environmental variables directly. Furthermore, 74 studies occurred in a laboratory or greenhouse, which do not often replicate the conditions experienced by tree seedlings in a field setting. It is therefore difficult to provide strong conclusions on how sensitive emergence and establishment in ponderosa and lodgepole pine are to these specific driving variables, or to investigate their potential aggregate effects. Thus, the effects of many driving variables on seedling processes remain largely inconclusive. Our review stresses the need for additional field and laboratory studies to better elucidate the effects of driving climate and environmental variables on seedling emergence and establishment for ponderosa and lodgepole pine.

  7. Inter-Annual Variability in Stream Water Temperature, Microclimate and Heat Exchanges: a Comparison of Forest and Moorland Environments

    NASA Astrophysics Data System (ADS)

    Garner, G.; Hannah, D. M.; Malcolm, I.; Sadler, J. P.

    2012-12-01

    Riparian forest is recognised as important for moderating stream temperature variability and has the potential to mitigate thermal extremes in a changing climate. Previous research on the heat exchanges controlling water column temperature has often been short-term or seasonally-constrained, with the few multi-year studies limited to a maximum of two years. This study advances previous work by providing a longer-term perspective which allows assessment of inter-annual variability in stream temperature, microclimate and heat exchange dynamics between a semi-natural woodland and a moorland (no trees) reach of the Girnock Burn, a tributary of the Scottish Dee. Automatic weather stations collected 15-minute data over seven consecutive years, which to our knowledge is a unique data set in providing the longest term perspective to date on stream temperature, microclimate and heat exchange processes. Results for spring-summer indicate that the presence of a riparian canopy has a consistent effect between years in reducing the magnitude and variability of mean daily water column temperature and daily net energy totals. Differences in the magnitude and variability in net energy fluxes between the study reaches were driven primarily by fluctuations in net radiation and latent heat fluxes in response to between- and within-year variability in growth of the riparian forest canopy at the forest and prevailing weather conditions at both the forest and moorland. This research provides new insights on the inter-annual variability of stream energy exchanges for moorland and forested reaches under a wide range of climatological and hydrological conditions. The findings therefore provide a more robust process basis for modelling the impact of changes in forest practice and climate change on river thermal dynamics.

  8. Supercritical fluid extraction of ginger (Zingiber Officinale Var. Amarum) : Global yield and composition study

    NASA Astrophysics Data System (ADS)

    Fitriady, Muhammad Arifuddin; Sulaswatty, Anny; Agustian, Egi; Salahuddin, Aditama, Deska Prayoga Fauzi

    2017-11-01

    An experiment to observe the effect of temperature and time process in ginger rhizome-Supercritical Fluid Extraction (SFE) using CO2 as the solvent has been conducted. The ginger rhizome (Zingiber Officinale Var. Amarum) was washed, drained, sliced, sun-dried, and then stored in a sealed bag prior to usage. The temperature and time process variables are each 35, 40, 45°C and 2, 4, 6 hours respectively with the pressure variable are 3500, 4000, and 4500 psi. It is found that the highest yield (2.9%) was achieved using temperature of 40°C and pressure of 4500 psiwith the process time of 4 hours. However, using the curve-fitting method, it is suggested to use 42°C as the temperature and 5 hours, 7 minutes, and 30 seconds (5.125 Hours) as the time process to obtain the highest yield. The temperature changes will affect both solvent and vapor pressure of diluted compounds of the ginger which will influence the global yield and the composition of the extract. The three major components of the extract are curcumene, zingiberene, and β - sesquipellandrene,

  9. Advanced Ceramic Technology for Space Applications at NASA MSFC

    NASA Technical Reports Server (NTRS)

    Alim, Mohammad A.

    2003-01-01

    The ceramic processing technology using conventional methods is applied to the making of the state-of-the-art ceramics known as smart ceramics or intelligent ceramics or electroceramics. The sol-gel and wet chemical processing routes are excluded in this investigation considering economic aspect and proportionate benefit of the resulting product. The use of ceramic ingredients in making coatings or devices employing vacuum coating unit is also excluded in this investigation. Based on the present information it is anticipated that the conventional processing methods provide identical performing ceramics when compared to that processed by the chemical routes. This is possible when sintering temperature, heating and cooling ramps, peak temperature (sintering temperature), soak-time (hold-time), etc. are considered as variable parameters. In addition, optional calcination step prior to the sintering operation remains as a vital variable parameter. These variable parameters constitute a sintering profile to obtain a sintered product. Also it is possible to obtain identical products for more than one sintering profile attributing to the calcination step in conjunction with the variables of the sintering profile. Overall, the state-of-the-art ceramic technology is evaluated for potential thermal and electrical insulation coatings, microelectronics and integrated circuits, discrete and integrated devices, etc. applications in the space program.

  10. Spray-drying nanocapsules in presence of colloidal silica as drying auxiliary agent: formulation and process variables optimization using experimental designs.

    PubMed

    Tewa-Tagne, Patrice; Degobert, Ghania; Briançon, Stéphanie; Bordes, Claire; Gauvrit, Jean-Yves; Lanteri, Pierre; Fessi, Hatem

    2007-04-01

    Spray-drying process was used for the development of dried polymeric nanocapsules. The purpose of this research was to investigate the effects of formulation and process variables on the resulting powder characteristics in order to optimize them. Experimental designs were used in order to estimate the influence of formulation parameters (nanocapsules and silica concentrations) and process variables (inlet temperature, spray-flow air, feed flow rate and drying air flow rate) on spray-dried nanocapsules when using silica as drying auxiliary agent. The interactions among the formulation parameters and process variables were also studied. Responses analyzed for computing these effects and interactions were outlet temperature, moisture content, operation yield, particles size, and particulate density. Additional qualitative responses (particles morphology, powder behavior) were also considered. Nanocapsules and silica concentrations were the main factors influencing the yield, particulate density and particle size. In addition, they were concerned for the only significant interactions occurring among two different variables. None of the studied variables had major effect on the moisture content while the interaction between nanocapsules and silica in the feed was of first interest and determinant for both the qualitative and quantitative responses. The particles morphology depended on the feed formulation but was unaffected by the process conditions. This study demonstrated that drying nanocapsules using silica as auxiliary agent by spray drying process enables the obtaining of dried micronic particle size. The optimization of the process and the formulation variables resulted in a considerable improvement of product yield while minimizing the moisture content.

  11. Disentangling Global Warming, Multidecadal Variability, and El Niño in Pacific Temperatures

    NASA Astrophysics Data System (ADS)

    Wills, Robert C.; Schneider, Tapio; Wallace, John M.; Battisti, David S.; Hartmann, Dennis L.

    2018-03-01

    A key challenge in climate science is to separate observed temperature changes into components due to internal variability and responses to external forcing. Extended integrations of forced and unforced climate models are often used for this purpose. Here we demonstrate a novel method to separate modes of internal variability from global warming based on differences in time scale and spatial pattern, without relying on climate models. We identify uncorrelated components of Pacific sea surface temperature variability due to global warming, the Pacific Decadal Oscillation (PDO), and the El Niño-Southern Oscillation (ENSO). Our results give statistical representations of PDO and ENSO that are consistent with their being separate processes, operating on different time scales, but are otherwise consistent with canonical definitions. We isolate the multidecadal variability of the PDO and find that it is confined to midlatitudes; tropical sea surface temperatures and their teleconnections mix in higher-frequency variability. This implies that midlatitude PDO anomalies are more persistent than previously thought.

  12. Determination of the dried product resistance variability and its influence on the product temperature in pharmaceutical freeze-drying.

    PubMed

    Scutellà, Bernadette; Trelea, Ioan Cristian; Bourlès, Erwan; Fonseca, Fernanda; Passot, Stephanie

    2018-07-01

    During the primary drying step of the freeze-drying process, mass transfer resistance strongly affects the product temperature, and consequently the final product quality. The main objective of this study was to evaluate the variability of the mass transfer resistance resulting from the dried product layer (R p ) in a manufacturing batch of vials, and its potential effect on the product temperature, from data obtained in a pilot scale freeze-dryer. Sublimation experiments were run at -25 °C and 10 Pa using two different freezing protocols: with spontaneous or controlled ice nucleation. Five repetitions of each condition were performed. Global (pressure rise test) and local (gravimetric) methods were applied as complementary approaches to estimate R p . The global method allowed to assess variability of the evolution of R p with the dried layer thickness between different experiments whereas the local method informed about R p variability at a fixed time within the vial batch. A product temperature variability of approximately ±4.4 °C was defined for a product dried layer thickness of 5 mm. The present approach can be used to estimate the risk of failure of the process due to mass transfer variability when designing freeze-drying cycle. Copyright © 2018 Elsevier B.V. All rights reserved.

  13. Effects of process variables on the properties of YBa2Cu3O(7-x) ceramics formed by investment casting

    NASA Technical Reports Server (NTRS)

    Hooker, M. W.; Taylor, T. D.; Leigh, H. D.; Wise, S. A.; Buckley, J. D.; Vasquez, P.; Buck, G. M.; Hicks, L. P.

    1993-01-01

    An investment casting process has been developed to produce net-shape, superconducting ceramics. In this work, a factorial experiment was performed to determine the critical process parameters for producing cast YBa2Cu3O7 ceramics with optimum properties. An analysis of variance procedure indicated that the key variables in casting superconductive ceramics are the particle size distribution and sintering temperature. Additionally, the interactions between the sintering temperature and the other process parameters (e.g., particle size distribution and the use of silver dopants) were also found to influence the density, porosity, and critical current density of the fired ceramics.

  14. Quality by Design approach for studying the impact of formulation and process variables on product quality of oral disintegrating films.

    PubMed

    Mazumder, Sonal; Pavurala, Naresh; Manda, Prashanth; Xu, Xiaoming; Cruz, Celia N; Krishnaiah, Yellela S R

    2017-07-15

    The present investigation was carried out to understand the impact of formulation and process variables on the quality of oral disintegrating films (ODF) using Quality by Design (QbD) approach. Lamotrigine (LMT) was used as a model drug. Formulation variable was plasticizer to film former ratio and process variables were drying temperature, air flow rate in the drying chamber, drying time and wet coat thickness of the film. A Definitive Screening Design of Experiments (DoE) was used to identify and classify the critical formulation and process variables impacting critical quality attributes (CQA). A total of 14 laboratory-scale DoE formulations were prepared and evaluated for mechanical properties (%elongation at break, yield stress, Young's modulus, folding endurance) and other CQA (dry thickness, disintegration time, dissolution rate, moisture content, moisture uptake, drug assay and drug content uniformity). The main factors affecting mechanical properties were plasticizer to film former ratio and drying temperature. Dissolution rate was found to be sensitive to air flow rate during drying and plasticizer to film former ratio. Data were analyzed for elucidating interactions between different variables, rank ordering the critical materials attributes (CMA) and critical process parameters (CPP), and for providing a predictive model for the process. Results suggested that plasticizer to film former ratio and process controls on drying are critical to manufacture LMT ODF with the desired CQA. Published by Elsevier B.V.

  15. Interactions Between Mineral Surfaces, Substrates, Enzymes, and Microbes Result in Hysteretic Temperature Sensitivities and Microbial Carbon Use Efficiencies and Weaker Predicted Carbon-Climate Feedbacks

    NASA Astrophysics Data System (ADS)

    Riley, W. J.; Tang, J.

    2014-12-01

    We hypothesize that the large observed variability in decomposition temperature sensitivity and carbon use efficiency arises from interactions between temperature, microbial biogeochemistry, and mineral surface sorptive reactions. To test this hypothesis, we developed a numerical model that integrates the Dynamic Energy Budget concept for microbial physiology, microbial trait-based community structure and competition, process-specific thermodynamically ­­based temperature sensitivity, a non-linear mineral sorption isotherm, and enzyme dynamics. We show, because mineral surfaces interact with substrates, enzymes, and microbes, both temperature sensitivity and microbial carbon use efficiency are hysteretic and highly variable. Further, by mimicking the traditional approach to interpreting soil incubation observations, we demonstrate that the conventional labile and recalcitrant substrate characterization for temperature sensitivity is flawed. In a 4 K temperature perturbation experiment, our fully dynamic model predicted more variable but weaker carbon-climate feedbacks than did the static temperature sensitivity and carbon use efficiency model when forced with yearly, daily, and hourly variable temperatures. These results imply that current earth system models likely over-estimate the response of soil carbon stocks to global warming.

  16. The Role of Auxiliary Variables in Deterministic and Deterministic-Stochastic Spatial Models of Air Temperature in Poland

    NASA Astrophysics Data System (ADS)

    Szymanowski, Mariusz; Kryza, Maciej

    2017-02-01

    Our study examines the role of auxiliary variables in the process of spatial modelling and mapping of climatological elements, with air temperature in Poland used as an example. The multivariable algorithms are the most frequently applied for spatialization of air temperature, and their results in many studies are proved to be better in comparison to those obtained by various one-dimensional techniques. In most of the previous studies, two main strategies were used to perform multidimensional spatial interpolation of air temperature. First, it was accepted that all variables significantly correlated with air temperature should be incorporated into the model. Second, it was assumed that the more spatial variation of air temperature was deterministically explained, the better was the quality of spatial interpolation. The main goal of the paper was to examine both above-mentioned assumptions. The analysis was performed using data from 250 meteorological stations and for 69 air temperature cases aggregated on different levels: from daily means to 10-year annual mean. Two cases were considered for detailed analysis. The set of potential auxiliary variables covered 11 environmental predictors of air temperature. Another purpose of the study was to compare the results of interpolation given by various multivariable methods using the same set of explanatory variables. Two regression models: multiple linear (MLR) and geographically weighted (GWR) method, as well as their extensions to the regression-kriging form, MLRK and GWRK, respectively, were examined. Stepwise regression was used to select variables for the individual models and the cross-validation method was used to validate the results with a special attention paid to statistically significant improvement of the model using the mean absolute error (MAE) criterion. The main results of this study led to rejection of both assumptions considered. Usually, including more than two or three of the most significantly correlated auxiliary variables does not improve the quality of the spatial model. The effects of introduction of certain variables into the model were not climatologically justified and were seen on maps as unexpected and undesired artefacts. The results confirm, in accordance with previous studies, that in the case of air temperature distribution, the spatial process is non-stationary; thus, the local GWR model performs better than the global MLR if they are specified using the same set of auxiliary variables. If only GWR residuals are autocorrelated, the geographically weighted regression-kriging (GWRK) model seems to be optimal for air temperature spatial interpolation.

  17. Disturbance Impacts on Thermal Hot Spots and Hot Moments at the Peatland-Atmosphere Interface

    NASA Astrophysics Data System (ADS)

    Leonard, R. M.; Kettridge, N.; Devito, K. J.; Petrone, R. M.; Mendoza, C. A.; Waddington, J. M.; Krause, S.

    2018-01-01

    Soil-surface temperature acts as a master variable driving nonlinear terrestrial ecohydrological, biogeochemical, and micrometeorological processes, inducing short-lived or spatially isolated extremes across heterogeneous landscape surfaces. However, subcanopy soil-surface temperatures have been, to date, characterized through isolated, spatially discrete measurements. Using spatially complex forested northern peatlands as an exemplar ecosystem, we explore the high-resolution spatiotemporal thermal behavior of this critical interface and its response to disturbances by using Fiber-Optic Distributed Temperature Sensing. Soil-surface thermal patterning was identified from 1.9 million temperature measurements under undisturbed, trees removed and vascular subcanopy removed conditions. Removing layers of the structurally diverse vegetation canopy not only increased mean temperatures but it shifted the spatial and temporal distribution, range, and longevity of thermal hot spots and hot moments. We argue that linking hot spots and/or hot moments with spatially variable ecosystem processes and feedbacks is key for predicting ecosystem function and resilience.

  18. A temperature rise reduces trial-to-trial variability of locust auditory neuron responses.

    PubMed

    Eberhard, Monika J B; Schleimer, Jan-Hendrik; Schreiber, Susanne; Ronacher, Bernhard

    2015-09-01

    The neurophysiology of ectothermic animals, such as insects, is affected by environmental temperature, as their body temperature fluctuates with ambient conditions. Changes in temperature alter properties of neurons and, consequently, have an impact on the processing of information. Nevertheless, nervous system function is often maintained over a broad temperature range, exhibiting a surprising robustness to variations in temperature. A special problem arises for acoustically communicating insects, as in these animals mate recognition and mate localization typically rely on the decoding of fast amplitude modulations in calling and courtship songs. In the auditory periphery, however, temporal resolution is constrained by intrinsic neuronal noise. Such noise predominantly arises from the stochasticity of ion channel gating and potentially impairs the processing of sensory signals. On the basis of intracellular recordings of locust auditory neurons, we show that intrinsic neuronal variability on the level of spikes is reduced with increasing temperature. We use a detailed mathematical model including stochastic ion channel gating to shed light on the underlying biophysical mechanisms in auditory receptor neurons: because of a redistribution of channel-induced current noise toward higher frequencies and specifics of the temperature dependence of the membrane impedance, membrane potential noise is indeed reduced at higher temperatures. This finding holds under generic conditions and physiologically plausible assumptions on the temperature dependence of the channels' kinetics and peak conductances. We demonstrate that the identified mechanism also can explain the experimentally observed reduction of spike timing variability at higher temperatures. Copyright © 2015 the American Physiological Society.

  19. A temperature rise reduces trial-to-trial variability of locust auditory neuron responses

    PubMed Central

    Schleimer, Jan-Hendrik; Schreiber, Susanne; Ronacher, Bernhard

    2015-01-01

    The neurophysiology of ectothermic animals, such as insects, is affected by environmental temperature, as their body temperature fluctuates with ambient conditions. Changes in temperature alter properties of neurons and, consequently, have an impact on the processing of information. Nevertheless, nervous system function is often maintained over a broad temperature range, exhibiting a surprising robustness to variations in temperature. A special problem arises for acoustically communicating insects, as in these animals mate recognition and mate localization typically rely on the decoding of fast amplitude modulations in calling and courtship songs. In the auditory periphery, however, temporal resolution is constrained by intrinsic neuronal noise. Such noise predominantly arises from the stochasticity of ion channel gating and potentially impairs the processing of sensory signals. On the basis of intracellular recordings of locust auditory neurons, we show that intrinsic neuronal variability on the level of spikes is reduced with increasing temperature. We use a detailed mathematical model including stochastic ion channel gating to shed light on the underlying biophysical mechanisms in auditory receptor neurons: because of a redistribution of channel-induced current noise toward higher frequencies and specifics of the temperature dependence of the membrane impedance, membrane potential noise is indeed reduced at higher temperatures. This finding holds under generic conditions and physiologically plausible assumptions on the temperature dependence of the channels' kinetics and peak conductances. We demonstrate that the identified mechanism also can explain the experimentally observed reduction of spike timing variability at higher temperatures. PMID:26041833

  20. Statistical modelling for precision agriculture: A case study in optimal environmental schedules for Agaricus Bisporus production via variable domain functional regression.

    PubMed

    Panayi, Efstathios; Peters, Gareth W; Kyriakides, George

    2017-01-01

    Quantifying the effects of environmental factors over the duration of the growing process on Agaricus Bisporus (button mushroom) yields has been difficult, as common functional data analysis approaches require fixed length functional data. The data available from commercial growers, however, is of variable duration, due to commercial considerations. We employ a recently proposed regression technique termed Variable-Domain Functional Regression in order to be able to accommodate these irregular-length datasets. In this way, we are able to quantify the contribution of covariates such as temperature, humidity and water spraying volumes across the growing process, and for different lengths of growing processes. Our results indicate that optimal oxygen and temperature levels vary across the growing cycle and we propose environmental schedules for these covariates to optimise overall yields.

  1. Ampicillin Nanoparticles Production via Supercritical CO2 Gas Antisolvent Process.

    PubMed

    Esfandiari, Nadia; Ghoreishi, Seyyed M

    2015-12-01

    The micronization of ampicillin via supercritical gas antisolvent (GAS) process was studied. The particle size distribution was significantly controlled with effective GAS variables such as initial solute concentration, temperature, pressure, and antisolvent addition rate. The effect of each variable in three levels was investigated. The precipitated particles were analyzed with scanning electron microscopy (SEM) and Zetasizer Nano ZS. The results indicated that decreasing the temperature and initial solute concentration while increasing the antisolvent rate and pressure led to a decrease in ampicillin particle size. The mean particle size of ampicillin was obtained in the range of 220-430 nm by varying the GAS effective variables. The purity of GAS-synthesized ampicillin nanoparticles was analyzed in contrast to unprocessed ampicillin by FTIR and HPLC. The results indicated that the structure of the ampicillin nanoparticles remained unchanged during the GAS process.

  2. Statistical modelling for precision agriculture: A case study in optimal environmental schedules for Agaricus Bisporus production via variable domain functional regression

    PubMed Central

    Panayi, Efstathios; Kyriakides, George

    2017-01-01

    Quantifying the effects of environmental factors over the duration of the growing process on Agaricus Bisporus (button mushroom) yields has been difficult, as common functional data analysis approaches require fixed length functional data. The data available from commercial growers, however, is of variable duration, due to commercial considerations. We employ a recently proposed regression technique termed Variable-Domain Functional Regression in order to be able to accommodate these irregular-length datasets. In this way, we are able to quantify the contribution of covariates such as temperature, humidity and water spraying volumes across the growing process, and for different lengths of growing processes. Our results indicate that optimal oxygen and temperature levels vary across the growing cycle and we propose environmental schedules for these covariates to optimise overall yields. PMID:28961254

  3. Electronic Thermometer Readings

    NASA Technical Reports Server (NTRS)

    2001-01-01

    NASA Stennis' adaptive predictive algorithm for electronic thermometers uses sample readings during the initial rise in temperature and applies an algorithm that accurately and rapidly predicts the steady state temperature. The final steady state temperature of an object can be calculated based on the second-order logarithm of the temperature signals acquired by the sensor and predetermined variables from the sensor characteristics. These variables are calculated during tests of the sensor. Once the variables are determined, relatively little data acquisition and data processing time by the algorithm is required to provide a near-accurate approximation of the final temperature. This reduces the delay in the steady state response time of a temperature sensor. This advanced algorithm can be implemented in existing software or hardware with an erasable programmable read-only memory (EPROM). The capability for easy integration eliminates the expense of developing a whole new system that offers the benefits provided by NASA Stennis' technology.

  4. System properties, feedback control and effector coordination of human temperature regulation.

    PubMed

    Werner, Jürgen

    2010-05-01

    The aim of human temperature regulation is to protect body processes by establishing a relative constancy of deep body temperature (regulated variable), in spite of external and internal influences on it. This is basically achieved by a distributed multi-sensor, multi-processor, multi-effector proportional feedback control system. The paper explains why proportional control implies inherent deviations of the regulated variable from the value in the thermoneutral zone. The concept of feedback of the thermal state of the body, conveniently represented by a high-weighted core temperature (T (c)) and low-weighted peripheral temperatures (T (s)) is equivalent to the control concept of "auxiliary feedback control", using a main (regulated) variable (T (c)), supported by an auxiliary variable (T (s)). This concept implies neither regulation of T (s) nor feedforward control. Steady-states result in the closed control-loop, when the open-loop properties of the (heat transfer) process are compatible with those of the thermoregulatory processors. They are called operating points or balance points and are achieved due to the inherent property of dynamical stability of the thermoregulatory feedback loop. No set-point and no comparison of signals (e.g. actual-set value) are necessary. Metabolic heat production and sweat production, though receiving the same information about the thermal state of the body, are independent effectors with different thresholds and gains. Coordination between one of these effectors and the vasomotor effector is achieved by the fact that changes in the (heat transfer) process evoked by vasomotor control are taken into account by the metabolic/sweat processor.

  5. Response of water temperatures and stratification to changing climate in three lakes with different morphometry

    NASA Astrophysics Data System (ADS)

    Magee, Madeline R.; Wu, Chin H.

    2017-12-01

    Water temperatures and stratification are important drivers for ecological and water quality processes within lake systems, and changes in these with increases in air temperature and changes to wind speeds may have significant ecological consequences. To properly manage these systems under changing climate, it is important to understand the effects of increasing air temperatures and wind speed changes in lakes of different depths and surface areas. In this study, we simulate three lakes that vary in depth and surface area to elucidate the effects of the observed increasing air temperatures and decreasing wind speeds on lake thermal variables (water temperature, stratification dates, strength of stratification, and surface heat fluxes) over a century (1911-2014). For all three lakes, simulations showed that epilimnetic temperatures increased, hypolimnetic temperatures decreased, the length of the stratified season increased due to earlier stratification onset and later fall overturn, stability increased, and longwave and sensible heat fluxes at the surface increased. Overall, lake depth influences the presence of stratification, Schmidt stability, and differences in surface heat flux, while lake surface area influences differences in hypolimnion temperature, hypolimnetic heating, variability of Schmidt stability, and stratification onset and fall overturn dates. Larger surface area lakes have greater wind mixing due to increased surface momentum. Climate perturbations indicate that our larger study lakes have more variability in temperature and stratification variables than the smaller lakes, and this variability increases with larger wind speeds. For all study lakes, Pearson correlations and climate perturbation scenarios indicate that wind speed has a large effect on temperature and stratification variables, sometimes greater than changes in air temperature, and wind can act to either amplify or mitigate the effect of warmer air temperatures on lake thermal structure depending on the direction of local wind speed changes.

  6. Effect of feed moisture, extrusion temperature and screw speed on properties of soy white flakes based aquafeed: a response surface analysis.

    PubMed

    Singh, Sushil K; Muthukumarappan, Kasiviswanathan

    2016-04-01

    Soy white flakes (SWF) is an intermediate product during soy bean processing. It is an untoasted inexpensive product and contains around 51% of crude protein. It can be a potential source of protein to replace fish meal for developing aquafeed. The extrusion process is versatile and is used for the development of aquafeed. Our objective was to study the effects of inclusion of SWF (up to 50%) and other extrusion processing parameters such as barrel temperature and screw speed on the properties of aquafeed extrudates using a single-screw extruder. Extrudate properties, including pellet durability index, bulk density, water absorption and solubility indices and mass flow rate, were significantly (P < 0.05) affected by the process variables. SWF was the most significant variable with quadratic effects on most of the properties. Increasing temperature and screw speed resulted in increase in durability and mass flow rate of extrudates. Response surface regression models were established to correlate the properties of extrudates to the process variables. SWF was used as an alternative protein source of fish meal. Our study shows that aquafeed with high durability, lower bulk density and lower water absorption and higher solubility indices can be obtained by adding SWF up to 40%. © 2015 Society of Chemical Industry.

  7. A quality by design approach to understand formulation and process variability in pharmaceutical melt extrusion processes.

    PubMed

    Patwardhan, Ketaki; Asgarzadeh, Firouz; Dassinger, Thomas; Albers, Jessica; Repka, Michael A

    2015-05-01

    In this study, the principles of quality by design (QbD) have been uniquely applied to a pharmaceutical melt extrusion process for an immediate release formulation with a low melting model drug, ibuprofen. Two qualitative risk assessment tools - Fishbone diagram and failure mode effect analysis - were utilized to strategically narrow down the most influential parameters. Selected variables were further assessed using a Plackett-Burman screening study, which was upgraded to a response surface design consisting of the critical factors to study the interactions between the study variables. In process torque, glass transition temperature (Tg ) of the extrudates, assay, dissolution and phase change were measured as responses to evaluate the critical quality attributes (CQAs) of the extrudates. The effect of each study variable on the measured responses was analysed using multiple regression for the screening design and partial least squares for the optimization design. Experimental limits for formulation and process parameters to attain optimum processing have been outlined. A design space plot describing the domain of experimental variables within which the CQAs remained unchanged was developed. A comprehensive approach for melt extrusion product development based on the QbD methodology has been demonstrated. Drug loading concentrations between 40- 48%w/w and extrusion temperature in the range of 90-130°C were found to be the most optimum. © 2015 Royal Pharmaceutical Society.

  8. GRCop-84 Rolling Parameter Study

    NASA Technical Reports Server (NTRS)

    Loewenthal, William S.; Ellis, David L.

    2008-01-01

    This report is a section of the final report on the GRCop-84 task of the Constellation Program and incorporates the results obtained between October 2000 and September 2005, when the program ended. NASA Glenn Research Center (GRC) has developed a new copper alloy, GRCop-84 (Cu-8 at.% Cr-4 at.% Nb), for rocket engine main combustion chamber components that will improve rocket engine life and performance. This work examines the sensitivity of GRCop-84 mechanical properties to rolling parameters as a means to better define rolling parameters for commercial warm rolling. Experiment variables studied were total reduction, rolling temperature, rolling speed, and post rolling annealing heat treatment. The responses were tensile properties measured at 23 and 500 C, hardness, and creep at three stress-temperature combinations. Understanding these relationships will better define boundaries for a robust commercial warm rolling process. The four processing parameters were varied within limits consistent with typical commercial production processes. Testing revealed that the rolling-related variables selected have a minimal influence on tensile, hardness, and creep properties over the range of values tested. Annealing had the expected result of lowering room temperature hardness and strength while increasing room temperature elongations with 600 C (1112 F) having the most effect. These results indicate that the process conditions to warm roll plate and sheet for these variables can range over wide levels without negatively impacting mechanical properties. Incorporating broader process ranges in future rolling campaigns should lower commercial rolling costs through increased productivity.

  9. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kim, J.; Moon, T.J.; Howell, J.R.

    This paper presents an analysis of the heat transfer occurring during an in-situ curing process for which infrared energy is provided on the surface of polymer composite during winding. The material system is Hercules prepreg AS4/3501-6. Thermoset composites have an exothermic chemical reaction during the curing process. An Eulerian thermochemical model is developed for the heat transfer analysis of helical winding. The model incorporates heat generation due to the chemical reaction. Several assumptions are made leading to a two-dimensional, thermochemical model. For simplicity, 360{degree} heating around the mandrel is considered. In order to generate the appropriate process windows, the developedmore » heat transfer model is combined with a simple winding time model. The process windows allow for a proper selection of process variables such as infrared energy input and winding velocity to give a desired end-product state. Steady-state temperatures are found for each combination of the process variables. A regression analysis is carried out to relate the process variables to the resulting steady-state temperatures. Using regression equations, process windows for a wide range of cylinder diameters are found. A general procedure to find process windows for Hercules AS4/3501-6 prepreg tape is coded in a FORTRAN program.« less

  10. Tropical cloud feedbacks and natural variability of climate

    NASA Technical Reports Server (NTRS)

    Miller, R. L.; Del Genio, A. D.

    1994-01-01

    Simulations of natural variability by two general circulation models (GCMs) are examined. One GCM is a sector model, allowing relatively rapid integration without simplification of the model physics, which would potentially exclude mechanisms of variability. Two mechanisms are found in which tropical surface temperature and sea surface temperature (SST) vary on interannual and longer timescales. Both are related to changes in cloud cover that modulate SST through the surface radiative flux. Over the equatorial ocean, SST and surface temperature vary on an interannual timescale, which is determined by the magnitude of the associated cloud cover anomalies. Over the subtropical ocean, variations in low cloud cover drive SST variations. In the sector model, the variability has no preferred timescale, but instead is characterized by a 'red' spectrum with increasing power at longer periods. In the terrestrial GCM, SST variability associated with low cloud anomalies has a decadal timescale and is the dominant form of global temperature variability. Both GCMs are coupled to a mixed layer ocean model, where dynamical heat transports are prescribed, thus filtering out El Nino-Southern Oscillation (ENSO) and thermohaline circulation variability. The occurrence of variability in the absence of dynamical ocean feedbacks suggests that climatic variability on long timescales can arise from atmospheric processes alone.

  11. Stochastic state-space temperature regulation of biochar production. Part I: Theoretical development.

    PubMed

    Cantrell, Keri B; Martin, Jerry H

    2012-02-01

    The concept of a designer biochar that targets the improvement of a specific soil property imposes the need for production processes to generate biochars with both high consistency and quality. These important production parameters can be affected by variations in process temperature that must be taken into account when controlling the pyrolysis of agricultural residues such as manures and other feedstocks. A novel stochastic state-space temperature regulator was developed to accurately match biochar batch production to a defined temperature input schedule. This was accomplished by describing the system's state-space with five temperature variables--four directly measured and one change in temperature. Relationships were derived between the observed state and the desired, controlled state. When testing the unit at two different temperatures, the actual pyrolytic temperature was within 3 °C of the control with no overshoot. This state-space regulator simultaneously controlled the indirect heat source and sample temperature by employing difficult-to-measure variables such as temperature stability in the description of the pyrolysis system's state-space. These attributes make a state-space controller an optimum control scheme for the production of a predictable, repeatable designer biochar. Published 2011 by John Wiley & Sons, Ltd.

  12. Factors influencing spatial variability in nitrogen processing in nitrogen-saturated soils

    Treesearch

    Frank S. Gilliam; Charles C. Somerville; Nikki L. Lyttle; Mary Beth Adams

    2001-01-01

    Nitrogen (N) saturation is an environmental concern for forests in the eastern U.S. Although several watersheds of the Fernow Experimental Forest (FEF), West Virginia exhibit symptoms of N saturation, many watersheds display a high degree of spatial variability in soil N processing. This study examined the effects of temperature on net N mineralization and...

  13. Effect of input data variability on estimations of the equivalent constant temperature time for microbial inactivation by HTST and retort thermal processing.

    PubMed

    Salgado, Diana; Torres, J Antonio; Welti-Chanes, Jorge; Velazquez, Gonzalo

    2011-08-01

    Consumer demand for food safety and quality improvements, combined with new regulations, requires determining the processor's confidence level that processes lowering safety risks while retaining quality will meet consumer expectations and regulatory requirements. Monte Carlo calculation procedures incorporate input data variability to obtain the statistical distribution of the output of prediction models. This advantage was used to analyze the survival risk of Mycobacterium avium subspecies paratuberculosis (M. paratuberculosis) and Clostridium botulinum spores in high-temperature short-time (HTST) milk and canned mushrooms, respectively. The results showed an estimated 68.4% probability that the 15 sec HTST process would not achieve at least 5 decimal reductions in M. paratuberculosis counts. Although estimates of the raw milk load of this pathogen are not available to estimate the probability of finding it in pasteurized milk, the wide range of the estimated decimal reductions, reflecting the variability of the experimental data available, should be a concern to dairy processors. Knowledge of the C. botulinum initial load and decimal thermal time variability was used to estimate an 8.5 min thermal process time at 110 °C for canned mushrooms reducing the risk to 10⁻⁹ spores/container with a 95% confidence. This value was substantially higher than the one estimated using average values (6.0 min) with an unacceptable 68.6% probability of missing the desired processing objective. Finally, the benefit of reducing the variability in initial load and decimal thermal time was confirmed, achieving a 26.3% reduction in processing time when standard deviation values were lowered by 90%. In spite of novel technologies, commercialized or under development, thermal processing continues to be the most reliable and cost-effective alternative to deliver safe foods. However, the severity of the process should be assessed to avoid under- and over-processing and determine opportunities for improvement. This should include a systematic approach to consider variability in the parameters for the models used by food process engineers when designing a thermal process. The Monte Carlo procedure here presented is a tool to facilitate this task for the determination of process time at a constant lethal temperature. © 2011 Institute of Food Technologists®

  14. Optimization of tocopherol concentration process from soybean oil deodorized distillate using response surface methodology.

    PubMed

    Ito, Vanessa Mayumi; Batistella, César Benedito; Maciel, Maria Regina Wolf; Maciel Filho, Rubens

    2007-04-01

    Soybean oil deodorized distillate is a product derived from the refining process and it is rich in high value-added products. The recovery of these unsaponifiable fractions is of great commercial interest, because of the fact that in many cases, the "valuable products" have vitamin activities such as tocopherols (vitamin E), as well as anticarcinogenic properties such as sterols. Molecular distillation has large potential to be used in order to concentrate tocopherols, as it uses very low temperatures owing to the high vacuum and short operating time for separation, and also, it does not use solvents. Then, it can be used to separate and to purify thermosensitive material such as vitamins. In this work, the molecular distillation process was applied for tocopherol concentration, and the response surface methodology was used to optimize free fatty acids (FFA) elimination and tocopherol concentration in the residue and in the distillate streams, both of which are the products of the molecular distiller. The independent variables studied were feed flow rate (F) and evaporator temperature (T) because they are the very important process variables according to previous experience. The experimental range was 4-12 mL/min for F and 130-200 degrees C for T. It can be noted that feed flow rate and evaporator temperature are important operating variables in the FFA elimination. For decreasing the loss of FFA, in the residue stream, the operating range should be changed, increasing the evaporator temperature and decreasing the feed flow rate; D/F ratio increases, increasing evaporator temperature and decreasing feed flow rate. High concentration of tocopherols was obtained in the residue stream at low values of feed flow rate and high evaporator temperature. These results were obtained through experimental results based on experimental design.

  15. On the use of internal state variables in thermoviscoplastic constitutive equations

    NASA Technical Reports Server (NTRS)

    Allen, D. H.; Beek, J. M.

    1985-01-01

    The general theory of internal state variables are reviewed to apply it to inelastic metals in use in high temperature environments. In this process, certain constraints and clarifications will be made regarding internal state variables. It is shown that the Helmholtz free energy can be utilized to construct constitutive equations which are appropriate for metallic superalloys. Internal state variables are shown to represent locally averaged measures of dislocation arrangement, dislocation density, and intergranular fracture. The internal state variable model is demonstrated to be a suitable framework for comparison of several currently proposed models for metals and can therefore be used to exhibit history dependence, nonlinearity, and rate as well as temperature sensitivity.

  16. Understanding Hydrological Processes in Variable Source Areas in the Glaciated Northeastern US Watersheds under Variable Climate Conditions

    NASA Astrophysics Data System (ADS)

    Steenhuis, T. S.; Azzaino, Z.; Hoang, L.; Pacenka, S.; Worqlul, A. W.; Mukundan, R.; Stoof, C.; Owens, E. M.; Richards, B. K.

    2017-12-01

    The New York City source watersheds in the Catskill Mountains' humid, temperate climate has long-term hydrological and water quality monitoring data It is one of the few catchments where implementation of source and landscape management practices has led to decreased phosphorus concentration in the receiving surface waters. One of the reasons is that landscape measures correctly targeted the saturated variable source runoff areas (VSA) in the valley bottoms as the location where most of the runoff and other nonpoint pollutants originated. Measures targeting these areas were instrumental in lowering phosphorus concentration. Further improvements in water quality can be made based on a better understanding of the flow processes and water table fluctuations in the VSA. For that reason, we instrumented a self-contained upland variable source watershed with a landscape characteristic of a soil underlain by glacial till at shallow depth similar to the Catskill watersheds. In this presentation, we will discuss our experimental findings and present a mathematical model. Variable source areas have a small slope making gravity the driving force for the flow, greatly simplifying the simulation of the flow processes. The experimental data and the model simulations agreed for both outflow and water table fluctuations. We found that while the flows to the outlet were similar throughout the year, the discharge of the VSA varies greatly. This was due to transpiration by the plants which became active when soil temperatures were above 10oC. We found that shortly after the temperature increased above 10oC the baseflow stopped and only surface runoff occurred when rainstorms exceeded the storage capacity of the soil in at least a portion of the variable source area. Since plant growth in the variable source area was a major variable determining the base flow behavior, changes in temperature in the future - affecting the duration of the growing season - will affect baseflow and related transport of nutrient and other chemicals many times more than small temperature related increases in potential evaporation rate. This in turn will directly change the water availability and pollutant transport in the many surface source watersheds with variable source area hydrology.

  17. The design of control system of livestock feeding processing

    NASA Astrophysics Data System (ADS)

    Sihombing, Juna; Napitupulu, Humala L.; Hidayati, Juliza

    2018-03-01

    PT. XYZ is a company that produces animal feed. One type of animal feed produced is 105 ISA P. In carrying out its production process, PT. XYZ faces the problem of rejected feed amounts during 2014 to June 2015 due to the amount of animal feed that exceeds the standard feed quality of 13% of moisture content and 3% for ash content. Therefore, the researchers analyzed the relationship between factors affecting the quality and extent of damage by using regression and correlation and determine the optimum value of each processing process. Analysis results found that variables affecting product quality are mixing time, steam conditioning temperature and cooling time. The most dominant variable affecting the product moisture content is mixing time with the correlation coefficient of (0.7959) and the most dominant variable affecting the ash content of the product during the processing is mixing time with the correlation coefficient of (0.8541). The design of the proposed product processing control is to run the product processing process with mixing time 235 seconds, steam conditioning temperature 87 0C and cooling time 192 seconds. Product quality 105 ISA P obtained by using this design is with 12.16% moisture content and ash content of 2.59%.

  18. Variable intertidal temperature explains why disease endangers black abalone

    USGS Publications Warehouse

    Ben-Horin, Tal; Lenihan, Hunter S.; Lafferty, Kevin D.

    2013-01-01

    Epidemiological theory suggests that pathogens will not cause host extinctions because agents of disease should fade out when the host population is driven below a threshold density. Nevertheless, infectious diseases have threatened species with extinction on local scales by maintaining high incidence and the ability to spread efficiently even as host populations decline. Intertidal black abalone (Haliotis cracherodii), but not other abalone species, went extinct locally throughout much of southern California following the emergence of a Rickettsiales-like pathogen in the mid-1980s. The rickettsial disease, a condition known as withering syndrome (WS), and associated mortality occur at elevated water temperatures. We measured abalone body temperatures in the field and experimentally manipulated intertidal environmental conditions in the laboratory, testing the influence of mean temperature and daily temperature variability on key epizootiological processes of WS. Daily temperature variability increased the susceptibility of black abalone to infection, but disease expression occurred only at warm water temperatures and was independent of temperature variability. These results imply that high thermal variation of the marine intertidal zone allows the pathogen to readily infect black abalone, but infected individuals remain asymptomatic until water temperatures periodically exceed thresholds modulating WS. Mass mortalities can therefore occur before pathogen transmission is limited by density-dependent factors.

  19. The Development of a High-Throughput/Combinatorial Workflow for the Study of Porous Polymer Networks

    DTIC Science & Technology

    2012-04-05

    poragen composition , poragen level, and cure temperature. A total of 216 unique compositions were prepared. Changes in opacity of the blends as they cured...allowed for the identification of compositional variables and process variables that enabled the production of porous networks. Keywords: high...in polymer network cross-link density,poragen composition , poragen level, and cure temperature. A total of 216 unique compositions were prepared

  20. Variability in, variability out: best practice recommendations to standardize pre-analytical variables in the detection of circulating and tissue microRNAs.

    PubMed

    Khan, Jenna; Lieberman, Joshua A; Lockwood, Christina M

    2017-05-01

    microRNAs (miRNAs) hold promise as biomarkers for a variety of disease processes and for determining cell differentiation. These short RNA species are robust, survive harsh treatment and storage conditions and may be extracted from blood and tissue. Pre-analytical variables are critical confounders in the analysis of miRNAs: we elucidate these and identify best practices for minimizing sample variation in blood and tissue specimens. Pre-analytical variables addressed include patient-intrinsic variation, time and temperature from sample collection to storage or processing, processing methods, contamination by cells and blood components, RNA extraction method, normalization, and storage time/conditions. For circulating miRNAs, hemolysis and blood cell contamination significantly affect profiles; samples should be processed within 2 h of collection; ethylene diamine tetraacetic acid (EDTA) is preferred while heparin should be avoided; samples should be "double spun" or filtered; room temperature or 4 °C storage for up to 24 h is preferred; miRNAs are stable for at least 1 year at -20 °C or -80 °C. For tissue-based analysis, warm ischemic time should be <1 h; cold ischemic time (4 °C) <24 h; common fixative used for all specimens; formalin fix up to 72 h prior to processing; enrich for cells of interest; validate candidate biomarkers with in situ visualization. Most importantly, all specimen types should have standard and common workflows with careful documentation of relevant pre-analytical variables.

  1. A new approach used to explore associations of current Ambrosia pollen levels with current and past meteorological elements

    NASA Astrophysics Data System (ADS)

    Matyasovszky, István; Makra, László; Csépe, Zoltán; Deák, Áron József; Pál-Molnár, Elemér; Fülöp, Andrea; Tusnády, Gábor

    2015-09-01

    The paper examines the sensitivity of daily airborne Ambrosia (ragweed) pollen levels of a current pollen season not only on daily values of meteorological variables during this season but also on the past meteorological conditions. The results obtained from a 19-year data set including daily ragweed pollen counts and ten daily meteorological variables are evaluated with special focus on the interactions between the phyto-physiological processes and the meteorological elements. Instead of a Pearson correlation measuring the strength of the linear relationship between two random variables, a generalised correlation that measures every kind of relationship between random vectors was used. These latter correlations between arrays of daily values of the ten meteorological elements and the array of daily ragweed pollen concentrations during the current pollen season were calculated. For the current pollen season, the six most important variables are two temperature variables (mean and minimum temperatures), two humidity variables (dew point depression and rainfall) and two variables characterising the mixing of the air (wind speed and the height of the planetary boundary layer). The six most important meteorological variables before the current pollen season contain four temperature variables (mean, maximum, minimum temperatures and soil temperature) and two variables that characterise large-scale weather patterns (sea level pressure and the height of the planetary boundary layer). Key periods of the past meteorological variables before the current pollen season have been identified. The importance of this kind of analysis is that a knowledge of the past meteorological conditions may contribute to a better prediction of the upcoming pollen season.

  2. A new approach used to explore associations of current Ambrosia pollen levels with current and past meteorological elements.

    PubMed

    Matyasovszky, István; Makra, László; Csépe, Zoltán; Deák, Áron József; Pál-Molnár, Elemér; Fülöp, Andrea; Tusnády, Gábor

    2015-09-01

    The paper examines the sensitivity of daily airborne Ambrosia (ragweed) pollen levels of a current pollen season not only on daily values of meteorological variables during this season but also on the past meteorological conditions. The results obtained from a 19-year data set including daily ragweed pollen counts and ten daily meteorological variables are evaluated with special focus on the interactions between the phyto-physiological processes and the meteorological elements. Instead of a Pearson correlation measuring the strength of the linear relationship between two random variables, a generalised correlation that measures every kind of relationship between random vectors was used. These latter correlations between arrays of daily values of the ten meteorological elements and the array of daily ragweed pollen concentrations during the current pollen season were calculated. For the current pollen season, the six most important variables are two temperature variables (mean and minimum temperatures), two humidity variables (dew point depression and rainfall) and two variables characterising the mixing of the air (wind speed and the height of the planetary boundary layer). The six most important meteorological variables before the current pollen season contain four temperature variables (mean, maximum, minimum temperatures and soil temperature) and two variables that characterise large-scale weather patterns (sea level pressure and the height of the planetary boundary layer). Key periods of the past meteorological variables before the current pollen season have been identified. The importance of this kind of analysis is that a knowledge of the past meteorological conditions may contribute to a better prediction of the upcoming pollen season.

  3. Drivers of annual to decadal streamflow variability in the lower Colorado River Basin

    NASA Astrophysics Data System (ADS)

    Lambeth-Beagles, R. S.; Troch, P. A.

    2010-12-01

    The Colorado River is the main water supply to the southwest region. As demand reaches the limit of supply in the southwest it becomes increasingly important to understand the dynamics of streamflow in the Colorado River and in particular the tributaries to the lower Colorado River. Climate change may pose an additional threat to the already-scarce water supply in the southwest. Due to the narrowing margin for error, water managers are keen on extending their ability to predict streamflow volumes on a mid-range to decadal scale. Before a predictive streamflow model can be developed, an understanding of the physical drivers of annual to decadal streamflow variability in the lower Colorado River Basin is needed. This research addresses this need by applying multiple statistical methods to identify trends, patterns and relationships present in streamflow, precipitation and temperature over the past century in four contributing watersheds to the lower Colorado River. The four watersheds selected were the Paria, Little Colorado, Virgin/Muddy, and Bill Williams. Time series data over a common period from 1906-2007 for streamflow, precipitation and temperature were used for the initial analysis. Through statistical analysis the following questions were addressed: 1) are there observable trends and patterns in these variables during the past century and 2) if there are trends or patterns, how are they related to each other? The Mann-Kendall test was used to identify trends in the three variables. Assumptions regarding autocorrelation and persistence in the data were taken into consideration. Kendall’s tau-b test was used to establish association between any found trends in the data. Initial results suggest there are two primary processes occurring. First, statistical analysis reveals significant upward trends in temperatures and downward trends in streamflow. However, there appears to be no trend in precipitation data. These trends in streamflow and temperature speak to increasing evaporation and transpiration processes. Second, annual variability in streamflow is not statistically correlated with annual temperature variability but appears to be highly correlated with annual precipitation variability. This implies that on a year-to-year basis, changes in streamflow volumes are directly affected by precipitation and not temperature. Future development of a predictive streamflow model will need to take into consideration these two processes to obtain accurate results. In order to extend predictive skill to the multi-year scale relationships between precipitation, temperature and persistent climate indices such as the Pacific Decadal Oscillation, Atlantic Multidecadal Oscillation and El Nino/Southern Oscillation will need to be examined.

  4. The paradox of cooling streams in a warming world: Regional climate trends do not parallel variable local trends in stream temperature in the Pacific continental United States

    USGS Publications Warehouse

    Arismendi, Ivan; Johnson, Sherri; Dunham, Jason B.; Haggerty, Roy; Hockman-Wert, David

    2012-01-01

    Temperature is a fundamentally important driver of ecosystem processes in streams. Recent warming of terrestrial climates around the globe has motivated concern about consequent increases in stream temperature. More specifically, observed trends of increasing air temperature and declining stream flow are widely believed to result in corresponding increases in stream temperature. Here, we examined the evidence for this using long-term stream temperature data from minimally and highly human-impacted sites located across the Pacific continental United States. Based on hypothesized climate impacts, we predicted that we should find warming trends in the maximum, mean and minimum temperatures, as well as increasing variability over time. These predictions were not fully realized. Warming trends were most prevalent in a small subset of locations with longer time series beginning in the 1950s. More recent series of observations (1987-2009) exhibited fewer warming trends and more cooling trends in both minimally and highly human-influenced systems. Trends in variability were much less evident, regardless of the length of time series. Based on these findings, we conclude that our perspective of climate impacts on stream temperatures is clouded considerably by a lack of long-termdata on minimally impacted streams, and biased spatio-temporal representation of existing time series. Overall our results highlight the need to develop more mechanistic, process-based understanding of linkages between climate change, other human impacts and stream temperature, and to deploy sensor networks that will provide better information on trends in stream temperatures in the future.

  5. Modelling Pseudocalanus elongatus stage-structured population dynamics embedded in a water column ecosystem model for the northern North Sea

    NASA Astrophysics Data System (ADS)

    Moll, Andreas; Stegert, Christoph

    2007-01-01

    This paper outlines an approach to couple a structured zooplankton population model with state variables for eggs, nauplii, two copepodites stages and adults adapted to Pseudocalanus elongatus into the complex marine ecosystem model ECOHAM2 with 13 state variables resolving the carbon and nitrogen cycle. Different temperature and food scenarios derived from laboratory culture studies were examined to improve the process parameterisation for copepod stage dependent development processes. To study annual cycles under realistic weather and hydrographic conditions, the coupled ecosystem-zooplankton model is applied to a water column in the northern North Sea. The main ecosystem state variables were validated against observed monthly mean values. Then vertical profiles of selected state variables were compared to the physical forcing to study differences between zooplankton as one biomass state variable or partitioned into five population state variables. Simulated generation times are more affected by temperature than food conditions except during the spring phytoplankton bloom. Up to six generations within the annual cycle can be discerned in the simulation.

  6. Valorisation of waste tyre by pyrolysis in a moving bed reactor.

    PubMed

    Aylón, E; Fernández-Colino, A; Murillo, R; Navarro, M V; García, T; Mastral, A M

    2010-07-01

    The aim of this work is to assess the behaviour of a moving bed reactor, based on a screw transporter design, in waste tyre pyrolysis under several experimental conditions. Waste tyre represents a significant problem in developed countries and it is necessary to develop new technology that could easily process big amounts of this potentially raw material. In this work, the influence of the main pyrolysis process variables (temperature, solid residence time, mass flow rate and inert gas flow) has been studied by a thorough analysis of product yields and properties. It has been found that regardless the process operational parameters, a total waste tyre devolatilisation is achieved, producing a pyrolytic carbon black with a volatile matter content under 5 wt.%. In addition, it has been proven that, in the range studied, the most influencing process variables are temperature and solid mass flow rate, mainly because both variables modify the gas residence time inside the reactor. In addition, it has been found that the modification of these variables affects to the chemical properties of the products. This fact is mainly associated to the different cracking reaction of the primary pyrolysis products. Copyright (c) 2009 Elsevier Ltd. All rights reserved.

  7. Valorisation of waste tyre by pyrolysis in a moving bed reactor

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aylon, E.; Fernandez-Colino, A.; Murillo, R., E-mail: ramonm@icb.csic.e

    2010-07-15

    The aim of this work is to assess the behaviour of a moving bed reactor, based on a screw transporter design, in waste tyre pyrolysis under several experimental conditions. Waste tyre represents a significant problem in developed countries and it is necessary to develop new technology that could easily process big amounts of this potentially raw material. In this work, the influence of the main pyrolysis process variables (temperature, solid residence time, mass flow rate and inert gas flow) has been studied by a thorough analysis of product yields and properties. It has been found that regardless the process operationalmore » parameters, a total waste tyre devolatilisation is achieved, producing a pyrolytic carbon black with a volatile matter content under 5 wt.%. In addition, it has been proven that, in the range studied, the most influencing process variables are temperature and solid mass flow rate, mainly because both variables modify the gas residence time inside the reactor. In addition, it has been found that the modification of these variables affects to the chemical properties of the products. This fact is mainly associated to the different cracking reaction of the primary pyrolysis products.« less

  8. Analysis of monthly, winter, and annual temperatures in Zagreb, Croatia, from 1864 to 2010: the 7.7-year cycle and the North Atlantic Oscillation

    NASA Astrophysics Data System (ADS)

    Sen, Asok K.; Ogrin, Darko

    2016-02-01

    Long instrumental records of meteorological variables such as temperature and precipitation are very useful for studying regional climate in the past, present, and future. They can also be useful for understanding the influence of large-scale atmospheric circulation processes on the regional climate. This paper investigates the monthly, winter, and annual temperature time series obtained from the instrumental records in Zagreb, Croatia, for the period 1864-2010. Using wavelet analysis, the dominant modes of variability in these temperature series are identified, and the time intervals over which these modes may persist are delineated. The results reveal that all three temperature records exhibit low-frequency variability with a dominant periodicity at around 7.7 years. The 7.7-year cycle has also been observed in the temperature data recorded at several other stations in Europe, especially in Northern and Western Europe, and may be linked to the North Atlantic Oscillation (NAO) and/or solar/geomagnetic activity.

  9. Development and validation of a predictive model for the influences of selected product and process variables on ascorbic acid degradation in simulated fruit juice.

    PubMed

    Gabriel, Alonzo A; Cayabyab, Jochelle Elysse C; Tan, Athalie Kaye L; Corook, Mark Lester F; Ables, Errol John O; Tiangson-Bayaga, Cecile Leah P

    2015-06-15

    A predictive response surface model for the influences of product (soluble solids and titratable acidity) and process (temperature and heating time) parameters on the degradation of ascorbic acid (AA) in heated simulated fruit juices (SFJs) was established. Physicochemical property ranges of freshly squeezed and processed juices, and a previously established decimal reduction times of Escherichiacoli O157:H7 at different heating temperatures were used in establishing a Central Composite Design of Experiment that determined the combinations of product and process variable used in the model building. Only the individual linear effects of temperature and heating time significantly (P<0.05) affected AA reduction (%AAr). Validating systems either over- or underestimated actual %AAr with bias factors 0.80-1.20. However, all validating systems still resulted in acceptable predictive efficacy, with accuracy factor 1.00-1.26. The model may be useful in establishing unique process schedules for specific products, for the simultaneous control and improvement of food safety and quality. Copyright © 2015 Elsevier Ltd. All rights reserved.

  10. Multivariate statistical process control of a continuous pharmaceutical twin-screw granulation and fluid bed drying process.

    PubMed

    Silva, A F; Sarraguça, M C; Fonteyne, M; Vercruysse, J; De Leersnyder, F; Vanhoorne, V; Bostijn, N; Verstraeten, M; Vervaet, C; Remon, J P; De Beer, T; Lopes, J A

    2017-08-07

    A multivariate statistical process control (MSPC) strategy was developed for the monitoring of the ConsiGma™-25 continuous tablet manufacturing line. Thirty-five logged variables encompassing three major units, being a twin screw high shear granulator, a fluid bed dryer and a product control unit, were used to monitor the process. The MSPC strategy was based on principal component analysis of data acquired under normal operating conditions using a series of four process runs. Runs with imposed disturbances in the dryer air flow and temperature, in the granulator barrel temperature, speed and liquid mass flow and in the powder dosing unit mass flow were utilized to evaluate the model's monitoring performance. The impact of the imposed deviations to the process continuity was also evaluated using Hotelling's T 2 and Q residuals statistics control charts. The influence of the individual process variables was assessed by analyzing contribution plots at specific time points. Results show that the imposed disturbances were all detected in both control charts. Overall, the MSPC strategy was successfully developed and applied. Additionally, deviations not associated with the imposed changes were detected, mainly in the granulator barrel temperature control. Copyright © 2017 Elsevier B.V. All rights reserved.

  11. Statistical Study to Evaluate the Effect of Processing Variables on Shrinkage Incidence During Solidification of Nodular Cast Irons

    NASA Astrophysics Data System (ADS)

    Gutiérrez, J. M.; Natxiondo, A.; Nieves, J.; Zabala, A.; Sertucha, J.

    2017-04-01

    The study of shrinkage incidence variations in nodular cast irons is an important aspect of manufacturing processes. These variations change the feeding requirements on castings and the optimization of risers' size is consequently affected when avoiding the formation of shrinkage defects. The effect of a number of processing variables on the shrinkage size has been studied using a layout specifically designed for this purpose. The β parameter has been defined as the relative volume reduction from the pouring temperature up to the room temperature. It is observed that shrinkage size and β decrease as effective carbon content increases and when inoculant is added in the pouring stream. A similar effect is found when the parameters selected from cooling curves show high graphite nucleation during solidification of cast irons for a given inoculation level. Pearson statistical analysis has been used to analyze the correlations among all involved variables and a group of Bayesian networks have been subsequently built so as to get the best accurate model for predicting β as a function of the input processing variables. The developed models can be used in foundry plants to study the shrinkage incidence variations in the manufacturing process and to optimize the related costs.

  12. Empirical modeling of spatial and temporal variation in warm season nocturnal air temperatures in two North Idaho mountain ranges, USA

    Treesearch

    Zachery A. Holden; Michael A. Crimmins; Samuel A. Cushman; Jeremy S. Littell

    2010-01-01

    Accurate, fine spatial resolution predictions of surface air temperatures are critical for understanding many hydrologic and ecological processes. This study examines the spatial and temporal variability in nocturnal air temperatures across a mountainous region of Northern Idaho. Principal components analysis (PCA) was applied to a network of 70 Hobo temperature...

  13. Snow-atmosphere coupling and its impact on temperature variability and extremes over North America

    NASA Astrophysics Data System (ADS)

    Diro, G. T.; Sushama, L.; Huziy, O.

    2018-04-01

    The impact of snow-atmosphere coupling on climate variability and extremes over North America is investigated using modeling experiments with the fifth generation Canadian Regional Climate Model (CRCM5). To this end, two CRCM5 simulations driven by ERA-Interim reanalysis for the 1981-2010 period are performed, where snow cover and depth are prescribed (uncoupled) in one simulation while they evolve interactively (coupled) during model integration in the second one. Results indicate systematic influence of snow cover and snow depth variability on the inter-annual variability of soil and air temperatures during winter and spring seasons. Inter-annual variability of air temperature is larger in the coupled simulation, with snow cover and depth variability accounting for 40-60% of winter temperature variability over the Mid-west, Northern Great Plains and over the Canadian Prairies. The contribution of snow variability reaches even more than 70% during spring and the regions of high snow-temperature coupling extend north of the boreal forests. The dominant process contributing to the snow-atmosphere coupling is the albedo effect in winter, while the hydrological effect controls the coupling in spring. Snow cover/depth variability at different locations is also found to affect extremes. For instance, variability of cold-spell characteristics is sensitive to snow cover/depth variation over the Mid-west and Northern Great Plains, whereas, warm-spell variability is sensitive to snow variation primarily in regions with climatologically extensive snow cover such as northeast Canada and the Rockies. Furthermore, snow-atmosphere interactions appear to have contributed to enhancing the number of cold spell days during the 2002 spring, which is the coldest recorded during the study period, by over 50%, over western North America. Additional results also provide useful information on the importance of the interactions of snow with large-scale mode of variability in modulating temperature extreme characteristics.

  14. Medieval Warm Period, Little Ice Age and 20th century temperature variability from Chesapeake Bay

    USGS Publications Warehouse

    Cronin, T. M.; Dwyer, G.S.; Kamiya, T.; Schwede, S.; Willard, D.A.

    2003-01-01

    We present paleoclimate evidence for rapid (< 100 years) shifts of ~2-4oC in Chesapeake Bay (CB) temperature ~2100, 1600, 950, 650, 400 and 150 years before present (years BP) reconstructed from magnesium/calcium (Mg/Ca) paleothermometry. These include large temperature excursions during the Little Ice Age (~1400-1900 AD) and the Medieval Warm Period (~800-1300 AD) possibly related to changes in the strength of North Atlantic thermohaline circulation (THC). Evidence is presented for a long period of sustained regional and North Atlantic-wide warmth with low-amplitude temperature variability between ~450 and 1000 AD. In addition to centennial-scale temperature shifts, the existence of numerous temperature maxima between 2200 and 250 years BP (average ~70 years) suggests that multi-decadal processes typical of the North Atlantic Oscillation (NAO) are an inherent feature of late Holocene climate. However, late 19th and 20th century temperature extremes in Chesapeake Bay associated with NAO climate variability exceeded those of the prior 2000 years, including the interval 450-1000 AD, by 2-3oC, suggesting anomalous recent behavior of the climate system.

  15. Linking interannual variability in shelf bottom water properties to the California Undercurrent and local processes in the Pacific Northwest

    NASA Astrophysics Data System (ADS)

    Stone, H. B.; Banas, N. S.; Hickey, B. M.; MacCready, P.

    2016-02-01

    The Pacific Northwest coast is an unusually productive area with a strong river influence and highly variable upwelling-favorable and downwelling-favorable winds, but recent trends in hypoxia and ocean acidification in this region are troubling to both scientists and the general public. A new ROMS hindcast model of this region makes possible a study of interannual variability. This study of the interannual temperature and salinity variability on the Pacific Northwest coast is conducted using a coastal hindcast model (43°N - 50°N) spanning 2002-2009 from the University of Washington Coastal Modeling Group, with a resolution of 1.5 km over the shelf and slope. Analysis of hindcast model results was used to assess the relative importance of source water variability, including the poleward California Undercurrent, local and remote wind forcing, winter wind-driven mixing, and river influence in explaining the interannual variations in the shelf bottom layer (40 - 80 m depth, 10 m thick) and over the slope (150 - 250 m depth, <100 km from shelf break) at each latitude within the model domain. Characterized through tracking of the fraction of Pacific Equatorial Water (PEW) relative to Pacific Subarctic Upper Water (PSUW) present on the slope, slope water properties at all latitudes varied little throughout the time series, with the largest variability due to patterns of large north-south advection of water masses over the slope. Over the time series, the standard deviation of slope temperature was 0.09 ˚C, while slope salinity standard deviation was 0.02 psu. Results suggest that shelf bottom water interannual variability is not driven primarily by interannual variability in slope water as shelf bottom water temperature and salinity vary nearly 10 times more than those over the slope. Instead, interannual variability in shelf bottom water properties is likely driven by other processes, such as local and remote wind forcing, and winter wind-driven mixing. The relative contributions of these processes to interannual variability in shelf bottom water properties will be addressed. Overall, these results highlight the importance of shelf processes relative to large-scale influences on the interannual timescale in particular. Implications for variability in hypoxia and ocean acidification impacts will be discussed.

  16. Liquid Jets in Crossflow at Elevated Temperatures and Pressures

    NASA Astrophysics Data System (ADS)

    Amighi, Amirreza

    An experimental study on the characterization of liquid jets injected into subsonic air crossflows is conducted. The aim of the study is to relate the droplet size and other attributes of the spray, such as breakup length, position, plume width, and time to flow parameters, including jet and air velocities, pressure and temperature as well as non-dimensional variables. Furthermore, multiple expressions are defined that would summarize the general behavior of the spray. For this purpose, an experimental setup is developed, which could withstand high temperatures and pressures to simulate conditions close to those experienced inside gas turbine engines. Images are captured using a laser based shadowgraphy system similar to a 2D PIV system. Image processing is extensively used to measure droplet size and boundaries of the spray. In total 209 different conditions are tested and over 72,000 images are captured and processed. The crossflow air temperatures are 25°C, 200°C, and 300°C; absolute crossflow air pressures are 2.1, 3.8, and 5.2 bars. Various liquid and gas velocities are tested for each given temperature and pressure in order to study the breakup mechanisms and regimes. Effects of dimensional and non-dimensional variables on droplet size are presented in detail. Several correlations for the mean droplet size, which are generated in this process, are presented. In addition, the influence of non-dimensional variables on the breakup length, time, plume area, angle, width and mean jet surface thickness are discussed and individual correlations are provided for each parameter. The influence of each individual parameter on the droplet sizes is discussed for a better understanding of the fragmentation process. Finally, new correlations for the centerline, windward and leeward trajectories are presented and compared to the previously reported correlations.

  17. Epitaxial gallium arsenide wafers

    NASA Technical Reports Server (NTRS)

    Black, J. F.; Robinson, L. B.

    1971-01-01

    The preparation of GaAs epitaxial layers by a vapor transport process using AsCl3, Ga and H2 was pursued to provide epitaxial wafers suitable for the fabrication of transferred electron oscillators and amplifiers operating in the subcritical region. Both n-n(+) structures, and n(++)-n-n(+) sandwich structures were grown using n(+) (Si-doped) GaAs substrates. Process variables such as the input AsCl3 concentration, gallium temperature, and substrate temperature and temperature gradient and their effects on properties are presented and discussed.

  18. Comparing interpolation techniques for annual temperature mapping across Xinjiang region

    NASA Astrophysics Data System (ADS)

    Ren-ping, Zhang; Jing, Guo; Tian-gang, Liang; Qi-sheng, Feng; Aimaiti, Yusupujiang

    2016-11-01

    Interpolating climatic variables such as temperature is challenging due to the highly variable nature of meteorological processes and the difficulty in establishing a representative network of stations. In this paper, based on the monthly temperature data which obtained from the 154 official meteorological stations in the Xinjiang region and surrounding areas, we compared five spatial interpolation techniques: Inverse distance weighting (IDW), Ordinary kriging, Cokriging, thin-plate smoothing splines (ANUSPLIN) and Empirical Bayesian kriging(EBK). Error metrics were used to validate interpolations against independent data. Results indicated that, the ANUSPLIN performed best than the other four interpolation methods.

  19. Regression Analysis and Calibration Recommendations for the Characterization of Balance Temperature Effects

    NASA Technical Reports Server (NTRS)

    Ulbrich, N.; Volden, T.

    2018-01-01

    Analysis and use of temperature-dependent wind tunnel strain-gage balance calibration data are discussed in the paper. First, three different methods are presented and compared that may be used to process temperature-dependent strain-gage balance data. The first method uses an extended set of independent variables in order to process the data and predict balance loads. The second method applies an extended load iteration equation during the analysis of balance calibration data. The third method uses temperature-dependent sensitivities for the data analysis. Physical interpretations of the most important temperature-dependent regression model terms are provided that relate temperature compensation imperfections and the temperature-dependent nature of the gage factor to sets of regression model terms. Finally, balance calibration recommendations are listed so that temperature-dependent calibration data can be obtained and successfully processed using the reviewed analysis methods.

  20. Consequences of Part Temperature Variability in Electron Beam Melting of Ti-6Al-4V

    NASA Astrophysics Data System (ADS)

    Fisher, Brian A.; Mireles, Jorge; Ridwan, Shakerur; Wicker, Ryan B.; Beuth, Jack

    2017-12-01

    To facilitate adoption of Ti-6Al-4V (Ti64) parts produced via additive manufacturing (AM), the ability to ensure part quality is critical. Measuring temperatures is an important component of part quality monitoring in all direct metal AM processes. In this work, surface temperatures were monitored using a custom infrared camera system attached to an Arcam electron beam melting (EBM®) machine. These temperatures were analyzed to understand their possible effect on solidification microstructure based on solidification cooling rates extracted from finite element simulations. Complicated thermal histories were seen during part builds, and temperature changes occurring during typical Ti64 builds may be large enough to affect solidification microstructure. There is, however, enough time between fusion of individual layers for spatial temperature variations (i.e., hot spots) to dissipate. This means that an effective thermal control strategy for EBM® can be based on average measured surface temperatures, ignoring temperature variability.

  1. Large deviation probabilities for correlated Gaussian stochastic processes and daily temperature anomalies

    NASA Astrophysics Data System (ADS)

    Massah, Mozhdeh; Kantz, Holger

    2016-04-01

    As we have one and only one earth and no replicas, climate characteristics are usually computed as time averages from a single time series. For understanding climate variability, it is essential to understand how close a single time average will typically be to an ensemble average. To answer this question, we study large deviation probabilities (LDP) of stochastic processes and characterize them by their dependence on the time window. In contrast to iid variables for which there exists an analytical expression for the rate function, the correlated variables such as auto-regressive (short memory) and auto-regressive fractionally integrated moving average (long memory) processes, have not an analytical LDP. We study LDP for these processes, in order to see how correlation affects this probability in comparison to iid data. Although short range correlations lead to a simple correction of sample size, long range correlations lead to a sub-exponential decay of LDP and hence to a very slow convergence of time averages. This effect is demonstrated for a 120 year long time series of daily temperature anomalies measured in Potsdam (Germany).

  2. Validation of the SEPHIS Program for the Modeling of the HM Process

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kyser, E.A.

    The SEPHIS computer program is currently being used to evaluate the effect of all process variables on the criticality safety of the HM 1st Uranium Cycle process in H Canyon. The objective of its use has three main purposes. (1) To provide a better technical basis for those process variables that do not have any realistic effect on the criticality safety of the process. (2) To qualitatively study those conditions that have been previously recognized to affect the nuclear safety of the process or additional conditions that modeling has indicated may pose a criticality safety issue. (3) To judge themore » adequacy of existing or future neutron monitors locations in the detection of the initial stages of reflux for specific scenarios.Although SEPHIS generally over-predicts the distribution of uranium to the organic phase, it is a capable simulation tool as long as the user recognizes its biases and takes special care when using the program for scenarios where the prediction bias is non-conservative. The temperature coefficient used by SEPHIS is poor at predicting effect of temperature on uranium extraction for the 7.5 percent TBP used in the HM process. Therefore, SEPHIS should not be used to study temperature related scenarios. However, within normal operating temperatures when other process variables are being studied, it may be used. Care must be is given to understanding the prediction bias and its effect on any conclusion for the particular scenario that is under consideration. Uranium extraction with aluminum nitrate is over-predicted worse than for nitric acid systems. However, the extraction section of the 1A bank has sufficient excess capability that these errors, while relatively large, still allow SEPHIS to be used to develop reasonable qualitative assessments for reflux scenarios. However, high losses to the 1AW stream cannot be modeled by SEPHIS.« less

  3. Aerosols implicated as a prime driver of twentieth-century North Atlantic climate variability.

    PubMed

    Booth, Ben B B; Dunstone, Nick J; Halloran, Paul R; Andrews, Timothy; Bellouin, Nicolas

    2012-04-04

    Systematic climate shifts have been linked to multidecadal variability in observed sea surface temperatures in the North Atlantic Ocean. These links are extensive, influencing a range of climate processes such as hurricane activity and African Sahel and Amazonian droughts. The variability is distinct from historical global-mean temperature changes and is commonly attributed to natural ocean oscillations. A number of studies have provided evidence that aerosols can influence long-term changes in sea surface temperatures, but climate models have so far failed to reproduce these interactions and the role of aerosols in decadal variability remains unclear. Here we use a state-of-the-art Earth system climate model to show that aerosol emissions and periods of volcanic activity explain 76 per cent of the simulated multidecadal variance in detrended 1860-2005 North Atlantic sea surface temperatures. After 1950, simulated variability is within observational estimates; our estimates for 1910-1940 capture twice the warming of previous generation models but do not explain the entire observed trend. Other processes, such as ocean circulation, may also have contributed to variability in the early twentieth century. Mechanistically, we find that inclusion of aerosol-cloud microphysical effects, which were included in few previous multimodel ensembles, dominates the magnitude (80 per cent) and the spatial pattern of the total surface aerosol forcing in the North Atlantic. Our findings suggest that anthropogenic aerosol emissions influenced a range of societally important historical climate events such as peaks in hurricane activity and Sahel drought. Decadal-scale model predictions of regional Atlantic climate will probably be improved by incorporating aerosol-cloud microphysical interactions and estimates of future concentrations of aerosols, emissions of which are directly addressable by policy actions.

  4. A Case Study on Maximizing Aqua Feed Pellet Properties Using Response Surface Methodology and Genetic Algorithm

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tumuluru, Jaya

    Aims: The present case study is on maximizing the aqua feed properties using response surface methodology and genetic algorithm. Study Design: Effect of extrusion process variables like screw speed, L/D ratio, barrel temperature, and feed moisture content were analyzed to maximize the aqua feed properties like water stability, true density, and expansion ratio. Place and Duration of Study: This study was carried out in the Department of Agricultural and Food Engineering, Indian Institute of Technology, Kharagpur, India. Methodology: A variable length single screw extruder was used in the study. The process variables selected were screw speed (rpm), length-to-diameter (L/D) ratio,more » barrel temperature (degrees C), and feed moisture content (%). The pelletized aqua feed was analyzed for physical properties like water stability (WS), true density (TD), and expansion ratio (ER). Extrusion experimental data was collected by based on central composite design. The experimental data was further analyzed using response surface methodology (RSM) and genetic algorithm (GA) for maximizing feed properties. Results: Regression equations developed for the experimental data has adequately described the effect of process variables on the physical properties with coefficient of determination values (R2) of > 0.95. RSM analysis indicated WS, ER, and TD were maximized at L/D ratio of 12-13, screw speed of 60-80 rpm, feed moisture content of 30-40%, and barrel temperature of = 80 degrees C for ER and TD and > 90 degrees C for WS. Based on GA analysis, a maxium WS of 98.10% was predicted at a screw speed of 96.71 rpm, L/D radio of 13.67, barrel temperature of 96.26 degrees C, and feed moisture content of 33.55%. Maximum ER and TD of 0.99 and 1346.9 kg/m3 was also predicted at screw speed of 60.37 and 90.24 rpm, L/D ratio of 12.18 and 13.52, barrel temperature of 68.50 and 64.88 degrees C, and medium feed moisture content of 33.61 and 38.36%. Conclusion: The present data analysis indicated that WS is mainly governed by barrel temperature and feed moisture content, which might have resulted in formation of starch-protein complexes due to denaturation of protein and gelatinization of starch. Screw speed coupled with temperature and feed moisture content controlled the ER and TD values. Higher screw speeds might have reduced the viscosity of the feed dough resulting in higher TD and lower ER values. Based on RSM and GA analysis screw speed, barrel temperature and feed moisture content were the interacting process variables influencing maximum WS followed by ER and TD.« less

  5. Near-surface temperature lapse rates in a mountainous catchment in the Chilean Andes

    NASA Astrophysics Data System (ADS)

    Ayala; Schauwecker, S.; Pellicciotti, F.; McPhee, J. P.

    2011-12-01

    In mountainous areas, and in the Chilean Andes in particular, the irregular and sparse distribution of recording stations resolves insufficiently the variability of climatic factors such as precipitation, temperature and relative humidity. Assumptions about air temperature variability in space and time have a strong effect on the performance of hydrologic models that represent snow processes such as accumulation and ablation. These processes have large diurnal variations, and assumptions that average over longer time periods (days, weeks or months) may reduce the predictive capacity of these models under different climatic conditions from those for which they were calibrated. They also introduce large uncertainties when such models are used to predict processes with strong subdiurnal variability such as snowmelt dynamics. In many applications and modeling exercises, temperature is assumed to decrease linearly with elevation, using the free-air moist adiabatic lapse rate (MALR: 0.0065°C/m). Little evidence is provided for this assumption, however, and recent studies have shown that use of lapse rates that are uniform in space and constant in time is not appropriate. To explore the validity of this approach, near-surface (2 m) lapse rates were calculated and analyzed at different temporal resolution, based on a new data set of spatially distributed temperature sensors setup in a high elevation catchment of the dry Andes of Central Chile (approx. 33°S). Five minutes temperature data were collected between January 2011 and April 2011 in the Ojos de Agua catchment, using two Automatic Weather Stations (AWSs) and 13 T-loggers (Hobo H8 Pro Temp with external data logger), ranging in altitude from 2230 to 3590 m.s.l.. The entire catchment was snow free during our experiment. We use this unique data set to understand the main controls over temperature variability in time and space, and test whether lapse rates can be used to describe the spatial variations of air temperature in a high elevation catchment. Our main result is that the assumption of a MALR is appropriate to describe the average variability of temperature over the entire measurement period (and possibly for daily scales), but that hourly near-surface lapse rates vary considerably and can deviate strongly from the MALR. This diurnal variability in lapse rates is associated with changes in wind direction and variations in wind velocity. Shallow lapse rates, in particular, occur during the morning, in correspondence to low wind speeds and change in wind direction from katabatic wind to valley wind and are associated with a weaker correlation between air temperature and elevation, while steeper lapse rates (meaning by this that temperature decreases more with elevation) closer to the MALR are typical of the afternoon hours from 13.00 on (and correspond to high wind speed), and are representative of a more linear dependency between air temperature and elevation. The steepest LRs, however, occur in the evening at 20.00-21.00, when wind velocity drops again and wind direction changes from valley wind to katabatic wind. It is clear that the wind regime is the main controls on LRs variability, and it is important to validate these findings with data sets from a second season.

  6. Ultrasonic determination of recrystallization

    NASA Technical Reports Server (NTRS)

    Generazio, E. R.

    1986-01-01

    Ultrasonic attenuation was measured for cold worked Nickel 200 samples annealed at increasing temperatures. Localized dislocation density variations, crystalline order and colume percent of recrystallized phase were determined over the anneal temperature range using transmission electron microscopy, X-ray diffraction, and metallurgy. The exponent of the frequency dependence of the attenuation was found to be a key variable relating ultrasonic attenuation to the thermal kinetics of the recrystallization process. Identification of this key variable allows for the ultrasonic determination of onset, degree, and completion of recrystallization.

  7. Spatial variability of heating profiles in windrowed poultry litter

    USDA-ARS?s Scientific Manuscript database

    In-house windrow composting of broiler litter has been suggested as a means to reduce microbial populations between flocks. Published time-temperature goals are used to determine the success of the composting process for microbial reductions. Spatial and temporal density of temperature measurement ...

  8. Development of functional extruded snacks by utilizing paste shrimp (Acetes spp.): process optimization and quality evaluation.

    PubMed

    Kumar, Raushan; Xavier, Ka Martin; Lekshmi, Manjusha; Dhanabalan, Vignaesh; Thachil, Madonna T; Balange, Amjad K; Gudipati, Venkateshwarlu

    2018-04-01

    Functional extruded snacks were prepared using paste shrimp powder (Acetes spp.), which is rich in protein. The process variables required for the preparation of extruded snacks was optimized using response surface methodology. Extrusion temperature (130-144 °C), level of Acetes powder (100-200 g kg -1 ) and feed moisture (140-200 g kg -1 ) were selected as design variables, and expansion ratio, porosity, hardness, crispness and thiobarbituric acid reactive substance value were taken as the response variables. Extrusion temperature significantly influenced all the response variables, while Acetes inclusion influenced all variables except porosity. Feed moisture content showed a significant quadratic effect on all responses and an interactive effect on expansion ratio and hardness. Shrimp powder incorporation increased the protein and mineral content of the final product. The extruded snack made with the combination of extrusion temperature 144.59 °C, feed moisture 178.5 g kg -1 and Acetes inclusion level 146.7 g kg -1 was found to be the best one based on sensory evaluation. The study suggests that use of Acetes species for the development of extruded snacks will serve as a means of utilization of Acetes as well as being a rich source of proteins for human consumption, which would otherwise remain unexploited as a by-catch. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  9. Hot mill process parameters impacting on hot mill tertiary scale formation

    NASA Astrophysics Data System (ADS)

    Kennedy, Jonathan Ian

    For high end steel applications surface quality is paramount to deliver a suitable product. A major cause of surface quality issues is from the formation of tertiary scale. The scale formation depends on numerous factors such as thermo-mechanical processing routes, chemical composition, thickness and rolls used. This thesis utilises a collection of data mining techniques to better understand the influence of Hot Mill process parameters on scale formation at Port Talbot Hot Strip Mill in South Wales. The dataset to which these data mining techniques were applied was carefully chosen to reduce process variation. There are several main factors that were considered to minimise this variability including time period, grade and gauge investigated. The following data mining techniques were chosen to investigate this dataset: Partial Least Squares (PLS); Logit Analysis; Principle Component Analysis (PCA); Multinomial Logistical Regression (MLR); Adaptive Neuro Inference Fuzzy Systems (ANFIS). The analysis indicated that the most significant variable for scale formation is the temperature entering the finishing mill. If the temperature is controlled on entering the finishing mill scale will not be formed. Values greater than 1070 °C for the average Roughing Mill and above 1050 °C for the average Crop Shear temperature are considered high, with values greater than this increasing the chance of scale formation. As the temperature increases more scale suppression measures are required to limit scale formation, with high temperatures more likely to generate a greater amount of scale even with fully functional scale suppression systems in place. Chemistry is also a significant factor in scale formation, with Phosphorus being the most significant of the chemistry variables. It is recommended that the chemistry specification for Phosphorus be limited to a maximum value of 0.015 % rather than 0.020 % to limit scale formation. Slabs with higher values should be treated with particular care when being processed through the Hot Mill to limit scale formation.

  10. Modeling and validation of heat and mass transfer in individual coffee beans during the coffee roasting process using computational fluid dynamics (CFD).

    PubMed

    Alonso-Torres, Beatriz; Hernández-Pérez, José Alfredo; Sierra-Espinoza, Fernando; Schenker, Stefan; Yeretzian, Chahan

    2013-01-01

    Heat and mass transfer in individual coffee beans during roasting were simulated using computational fluid dynamics (CFD). Numerical equations for heat and mass transfer inside the coffee bean were solved using the finite volume technique in the commercial CFD code Fluent; the software was complemented with specific user-defined functions (UDFs). To experimentally validate the numerical model, a single coffee bean was placed in a cylindrical glass tube and roasted by a hot air flow, using the identical geometrical 3D configuration and hot air flow conditions as the ones used for numerical simulations. Temperature and humidity calculations obtained with the model were compared with experimental data. The model predicts the actual process quite accurately and represents a useful approach to monitor the coffee roasting process in real time. It provides valuable information on time-resolved process variables that are otherwise difficult to obtain experimentally, but critical to a better understanding of the coffee roasting process at the individual bean level. This includes variables such as time-resolved 3D profiles of bean temperature and moisture content, and temperature profiles of the roasting air in the vicinity of the coffee bean.

  11. Weaker soil carbon-climate feedbacks resulting from microbial and abiotic interactions

    NASA Astrophysics Data System (ADS)

    Tang, Jinyun; Riley, William J.

    2015-01-01

    The large uncertainty in soil carbon-climate feedback predictions has been attributed to the incorrect parameterization of decomposition temperature sensitivity (Q10; ref. ) and microbial carbon use efficiency. Empirical experiments have found that these parameters vary spatiotemporally, but such variability is not included in current ecosystem models. Here we use a thermodynamically based decomposition model to test the hypothesis that this observed variability arises from interactions between temperature, microbial biogeochemistry, and mineral surface sorptive reactions. We show that because mineral surfaces interact with substrates, enzymes and microbes, both Q10 and microbial carbon use efficiency are hysteretic (so that neither can be represented by a single static function) and the conventional labile and recalcitrant substrate characterization with static temperature sensitivity is flawed. In a 4-K temperature perturbation experiment, our fully dynamic model predicted more variable but weaker soil carbon-climate feedbacks than did the static Q10 and static carbon use efficiency model when forced with yearly, daily and hourly variable temperatures. These results imply that current Earth system models probably overestimate the response of soil carbon stocks to global warming. Future ecosystem models should therefore consider the dynamic interactions between sorptive mineral surfaces, substrates and microbial processes.

  12. The paradox of cooling streams in a warming world: regional climate trends do not parallel variable local trends in stream temperature in the Pacific continental United States

    Treesearch

    Ivan Arismendi; Sherri L. Johnson; Jason B. Dunham; Roy Haggerty

    2012-01-01

    Temperature is a fundamentally important driver of ecosystem processes in streams. Recent warming of terrestrial climates around the globe has motivated concern about consequent increases in stream temperature. More specifically, observed trends of increasing air temperature and declining stream flow are widely believed to result in corresponding increases in stream...

  13. Soil Temperature Variability in Complex Terrain measured using Distributed a Fiber-Optic Distributed Temperature Sensing

    NASA Astrophysics Data System (ADS)

    Seyfried, M. S.; Link, T. E.

    2013-12-01

    Soil temperature (Ts) exerts critical environmental controls on hydrologic and biogeochemical processes. Rates of carbon cycling, mineral weathering, infiltration and snow melt are all influenced by Ts. Although broadly reflective of the climate, Ts is sensitive to local variations in cover (vegetative, litter, snow), topography (slope, aspect, position), and soil properties (texture, water content), resulting in a spatially and temporally complex distribution of Ts across the landscape. Understanding and quantifying the processes controlled by Ts requires an understanding of that distribution. Relatively few spatially distributed field Ts data exist, partly because traditional Ts data are point measurements. A relatively new technology, fiber optic distributed temperature system (FO-DTS), has the potential to provide such data but has not been rigorously evaluated in the context of remote, long term field research. We installed FO-DTS in a small experimental watershed in the Reynolds Creek Experimental Watershed (RCEW) in the Owyhee Mountains of SW Idaho. The watershed is characterized by complex terrain and a seasonal snow cover. Our objectives are to: (i) evaluate the applicability of fiber optic DTS to remote field environments and (ii) to describe the spatial and temporal variability of soil temperature in complex terrain influenced by a variable snow cover. We installed fiber optic cable at a depth of 10 cm in contrasting snow accumulation and topographic environments and monitored temperature along 750 m with DTS. We found that the DTS can provide accurate Ts data (+/- .4°C) that resolves Ts changes of about 0.03°C at a spatial scale of 1 m with occasional calibration under conditions with an ambient temperature range of 50°C. We note that there are site-specific limitations related cable installation and destruction by local fauna. The FO-DTS provide unique insight into the spatial and temporal variability of Ts in a landscape. We found strong seasonal trends in Ts variability controlled by snow cover and solar radiation as modified by topography. During periods of spatially continuous snow cover Ts was practically homogeneous throughout. In the absence of snow cover, Ts is highly variable, with most of the variability attributable to different topographic units defined by slope and aspect. During transition periods when snow melts out, Ts is highly variable within the watershed and within topographic units. The importance of accounting for these relatively small scale effects is underscored by the fact that the overall range of Ts in study area 600 m long is similar to that of the much large RCEW with 900 m elevation gradient.

  14. Recommended direct simulation Monte Carlo collision model parameters for modeling ionized air transport processes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Swaminathan-Gopalan, Krishnan; Stephani, Kelly A., E-mail: ksteph@illinois.edu

    2016-02-15

    A systematic approach for calibrating the direct simulation Monte Carlo (DSMC) collision model parameters to achieve consistency in the transport processes is presented. The DSMC collision cross section model parameters are calibrated for high temperature atmospheric conditions by matching the collision integrals from DSMC against ab initio based collision integrals that are currently employed in the Langley Aerothermodynamic Upwind Relaxation Algorithm (LAURA) and Data Parallel Line Relaxation (DPLR) high temperature computational fluid dynamics solvers. The DSMC parameter values are computed for the widely used Variable Hard Sphere (VHS) and the Variable Soft Sphere (VSS) models using the collision-specific pairing approach.more » The recommended best-fit VHS/VSS parameter values are provided over a temperature range of 1000-20 000 K for a thirteen-species ionized air mixture. Use of the VSS model is necessary to achieve consistency in transport processes of ionized gases. The agreement of the VSS model transport properties with the transport properties as determined by the ab initio collision integral fits was found to be within 6% in the entire temperature range, regardless of the composition of the mixture. The recommended model parameter values can be readily applied to any gas mixture involving binary collisional interactions between the chemical species presented for the specified temperature range.« less

  15. Evaluation of factors influencing the enantioselective enzymatic esterification of lactic acid in ionic liquid.

    PubMed

    Findrik, Zvjezdana; Németh, Gergely; Gubicza, László; Bélafi-Bakó, Katalin; Vasić-Rački, Durđa

    2012-05-01

    In this paper esterification of ethanol and lactic acid catalyzed by Candida antarctica B (Novozyme 435) in ionic liquid (Cyphos 104) was studied. The influence of different variables on lipase enantioselectivity and lactic acid conversion was investigated. The variables investigated were ionic liquid mass/lipase mass ratio, water content, alcohol excess and temperature. Using the Design Expert software 2(3) factorial experimental plan (two levels, three factors) was performed to ascertain the effect of selected variables and their interactions on the ethyl lactate enantiomeric excess and lactic acid conversion. The results of the experiments and statistical processing suggest that temperature and alcohol excess have the highest effect on the ethyl lactate enantiomeric excess, while temperature and water content have the highest influence on the lactic acid conversion. The statistical mathematical model developed on the basis of the experimental data showed that the highest enantiomeric excess achieved in the investigated variable range is 34.3%, and the highest conversion is 63.8% at the initial conditions of water content at 8%; 11-fold molar excess of alcohol and temperature at 30 °C.

  16. Influence of rice straw cooking conditions in the soda-ethanol-water pulping on the mechanical properties of produced paper sheets.

    PubMed

    Navaee-Ardeh, S; Mohammadi-Rovshandeh, J; Pourjoozi, M

    2004-03-01

    A normalized design was used to examine the influence of independent variables (alcohol concentration, cooking time and temperature) in the catalytic soda-ethanol pulping of rice straw on various mechanical properties (breaking length, burst, tear index and folding endurance) of paper sheets obtained from each pulping process. An equation of each dependent variable as a function of cooking variables (independent variables) was obtained by multiple non-linear regression using the least square method by MATLAB software for developing of empirical models. The ranges of alcohol concentration, cooking time and temperature were 40-65% (w/w), 150-180 min and 195-210 degrees C, respectively. Three-dimensional graphs of dependent variables were also plotted versus independent variables. The optimum values of breaking length, burst and tear index and folding endurance were 4683.7 (m), 30.99 (kN/g), 376.93 (mN m2/g) and 27.31, respectively. However, short cooking time (150 min), high ethanol concentration (65%) and high temperature (210 degrees C) could be used to produce papers with suitable burst and tear index. However, for papers with best breaking length and folding endurance low temperature (195 degrees C) was desirable. Differences between optimum values of dependent variables obtained by normalized design and experimental data were less than 20%.

  17. Optimization of a thermal hydrolysis process for sludge pre-treatment.

    PubMed

    Sapkaite, I; Barrado, E; Fdz-Polanco, F; Pérez-Elvira, S I

    2017-05-01

    At industrial scale, thermal hydrolysis is the most used process to enhance biodegradability of the sludge produced in wastewater treatment plants. Through statistically guided Box-Behnken experimental design, the present study analyses the effect of TH as pre-treatment applied to activated sludge. The selected process variables were temperature (130-180 °C), time (5-50 min) and decompression mode (slow or steam-explosion effect), and the parameters evaluated were sludge solubilisation and methane production by anaerobic digestion. A quadratic polynomial model was generated to compare the process performance for the 15 different combinations of operation conditions by modifying the process variables evaluated. The statistical analysis performed exhibited that methane production and solubility were significantly affected by pre-treatment time and temperature. During high intensity pre-treatment (high temperature and long times), the solubility increased sharply while the methane production exhibited the opposite behaviour, indicating the formation of some soluble but non-biodegradable materials. Therefore, solubilisation is not a reliable parameter to quantify the efficiency of a thermal hydrolysis pre-treatment, since it is not directly related to methane production. Based on the operational parameters optimization, the estimated optimal thermal hydrolysis conditions to enhance of sewage sludge digestion were: 140-170 °C heating temperature, 5-35min residence time, and one sudden decompression. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Can temperature explain the latitudinal gradient of ulcerative colitis? Cohort of Norway

    PubMed Central

    2013-01-01

    Background Incidence and prevalence of ulcerative colitis follow a north–south (latitudinal) gradient and increases northwards at the northern hemisphere or southwards at the southern hemisphere. The disease has increased during the last decades. The temporal trend has been explained by the hygiene hypothesis, but few parallel explanations exist for the spatial variability. Many factors are linked to latitude such as climate. Our purpose was to investigate the association between variables governing the climate and prospectively identified patients. Methods In this study, we used a subset of the population-based Cohort of Norway (n = 80412) where 370 prevalent cases of ulcerative colitis were identified through self-reported medication. The meteorological and climatic variables temperature, precipitation, and altitude were recorded from weather stations of the Norwegian Meteorological Institute. Summer temperature was used to capture environmental temperature. Results Summer temperature was significantly related to the prevalence of ulcerative colitis. For each one-degree increase in temperature the odds for ulcerative colitis decreased with about 9% (95% CI: 3%-15%). None of the other climatic factors were significantly associated to the risk of ulcerative colitis. Contextual variables did not change the association to the prevalence of ulcerative colitis. Conclusions The present results show that the prevalence of ulcerative colitis is associated to summer temperature. Our speculation is that summer temperature works as an instrumental variable for the effect of microbial species richness on the development of ulcerative colitis. Environmental temperature is one of the main forces governing microbial species richness and the microbial composition of the commensal gut flora is known to be an important part in the process leading to ulcerative colitis. PMID:23724802

  19. An experimental test of the role of environmental temperature variability on ectotherm molecular, physiological and life-history traits: implications for global warming.

    PubMed

    Folguera, Guillermo; Bastías, Daniel A; Caers, Jelle; Rojas, José M; Piulachs, Maria-Dolors; Bellés, Xavier; Bozinovic, Francisco

    2011-07-01

    Global climate change is one of the greatest threats to biodiversity; one of the most important effects is the increase in the mean earth surface temperature. However, another but poorly studied main characteristic of global change appears to be an increase in temperature variability. Most of the current analyses of global change have focused on mean values, paying less attention to the role of the fluctuations of environmental variables. We experimentally tested the effects of environmental temperature variability on characteristics associated to the fitness (body mass balance, growth rate, and survival), metabolic rate (VCO(2)) and molecular traits (heat shock protein expression, Hsp70), in an ectotherm, the terrestrial woodlouse Porcellio laevis. Our general hypotheses are that higher values of thermal amplitude may directly affect life-history traits, increasing metabolic cost and stress responses. At first, results supported our hypotheses showing a diversity of responses among characters to the experimental thermal treatments. We emphasize that knowledge about the cellular and physiological mechanisms by which animals cope with environmental changes is essential to understand the impact of mean climatic change and variability. Also, we consider that the studies that only incorporate only mean temperatures to predict the life-history, ecological and evolutionary impact of global temperature changes present important problems to predict the diversity of responses of the organism. This is because the analysis ignores the complexity and details of the molecular and physiological processes by which animals cope with environmental variability, as well as the life-history and demographic consequences of such variability. Copyright © 2011 Elsevier Inc. All rights reserved.

  20. Separating the influence of temperature, drought, and fire on interannual variability in atmospheric CO2

    PubMed Central

    Keppel-Aleks, Gretchen; Wolf, Aaron S; Mu, Mingquan; Doney, Scott C; Morton, Douglas C; Kasibhatla, Prasad S; Miller, John B; Dlugokencky, Edward J; Randerson, James T

    2014-01-01

    The response of the carbon cycle in prognostic Earth system models (ESMs) contributes significant uncertainty to projections of global climate change. Quantifying contributions of known drivers of interannual variability in the growth rate of atmospheric carbon dioxide (CO2) is important for improving the representation of terrestrial ecosystem processes in these ESMs. Several recent studies have identified the temperature dependence of tropical net ecosystem exchange (NEE) as a primary driver of this variability by analyzing a single, globally averaged time series of CO2 anomalies. Here we examined how the temporal evolution of CO2 in different latitude bands may be used to separate contributions from temperature stress, drought stress, and fire emissions to CO2 variability. We developed atmospheric CO2 patterns from each of these mechanisms during 1997–2011 using an atmospheric transport model. NEE responses to temperature, NEE responses to drought, and fire emissions all contributed significantly to CO2 variability in each latitude band, suggesting that no single mechanism was the dominant driver. We found that the sum of drought and fire contributions to CO2 variability exceeded direct NEE responses to temperature in both the Northern and Southern Hemispheres. Additional sensitivity tests revealed that these contributions are masked by temporal and spatial smoothing of CO2 observations. Accounting for fires, the sensitivity of tropical NEE to temperature stress decreased by 25% to 2.9 ± 0.4 Pg C yr−1 K−1. These results underscore the need for accurate attribution of the drivers of CO2 variability prior to using contemporary observations to constrain long-term ESM responses. PMID:26074665

  1. Separating the influence of temperature, drought, and fire on interannual variability in atmospheric CO2.

    PubMed

    Keppel-Aleks, Gretchen; Wolf, Aaron S; Mu, Mingquan; Doney, Scott C; Morton, Douglas C; Kasibhatla, Prasad S; Miller, John B; Dlugokencky, Edward J; Randerson, James T

    2014-11-01

    The response of the carbon cycle in prognostic Earth system models (ESMs) contributes significant uncertainty to projections of global climate change. Quantifying contributions of known drivers of interannual variability in the growth rate of atmospheric carbon dioxide (CO 2 ) is important for improving the representation of terrestrial ecosystem processes in these ESMs. Several recent studies have identified the temperature dependence of tropical net ecosystem exchange (NEE) as a primary driver of this variability by analyzing a single, globally averaged time series of CO 2 anomalies. Here we examined how the temporal evolution of CO 2 in different latitude bands may be used to separate contributions from temperature stress, drought stress, and fire emissions to CO 2 variability. We developed atmospheric CO 2 patterns from each of these mechanisms during 1997-2011 using an atmospheric transport model. NEE responses to temperature, NEE responses to drought, and fire emissions all contributed significantly to CO 2 variability in each latitude band, suggesting that no single mechanism was the dominant driver. We found that the sum of drought and fire contributions to CO 2 variability exceeded direct NEE responses to temperature in both the Northern and Southern Hemispheres. Additional sensitivity tests revealed that these contributions are masked by temporal and spatial smoothing of CO 2 observations. Accounting for fires, the sensitivity of tropical NEE to temperature stress decreased by 25% to 2.9 ± 0.4 Pg C yr -1  K -1 . These results underscore the need for accurate attribution of the drivers of CO 2 variability prior to using contemporary observations to constrain long-term ESM responses.

  2. Global Changes In Relative Humidity: Moisture Recycling, Transport Processes And Implications For Drought Severity

    NASA Astrophysics Data System (ADS)

    Vicente-Serrano, S. M.; Gimeno, L.; Nieto, R. O.; Azorin-Molina, C.

    2016-12-01

    Climate models and observations suggest that atmospheric humidity is increasing as a consequence of warmer air temperatures according to the Classius-Clapeyron relationship. In addition, given unlimited water availability in oceans it is suggested that relative humidity (RH) would remain constant. Nevertheless, recent global and regional studies have pointed out that RH may be decreasing in large areas of the world, and there are different hypotheses that could explain the possible decrease in RH as related to changes in: (i) the atmospheric circulation and moisture transport processes; (ii) precipitation; (iii) air vapour saturation given different warming in lands and oceans; etc. These trends have strong implications for the atmospheric evaporative demand (AED) and drought severity. We analysed changes in RH observed at the global scale for 1979-2014. For this purpose we have used 3462 stations across the world from the HadISDH data set. RH data have been also calculated from daily records of specific humidity, air pressure and air temperature from the ERA-Interim Reanalysis data set. The comparison results between observations and ERA-Interim show a strong agreement in the spatio-temporal variability and magnitude of trends of RH. We have analysed the relationship between the variability and changes in RH, precipitation, air temperature and evaporation at the global scale, concluding that the observed spatial patterns of RH are not well explained by the observed changes in the variability of precipitation and temperature. To improve the knowledge of the possible drivers of the observed trends in RH, we have selected 15 representative areas that showed a different temporal behaviour and applied a Lagrangian model (Flexpart). This has served to identify the humidity sources corresponding to each region, and to know the behaviour showed by Sea Surface Temperature (SST) and the evolution of oceanic and continental evaporation processes on the RH variability and trends. The effect of observed RH trends on AED and drought severity has been evaluated by means of the Standardized Precipitation Evapotranspiration Index (SPEI).

  3. A Study on the Relationships among Surface Variables to Adjust the Height of Surface Temperature for Data Assimilation.

    NASA Astrophysics Data System (ADS)

    Kang, J. H.; Song, H. J.; Han, H. J.; Ha, J. H.

    2016-12-01

    The observation processing system, KPOP (KIAPS - Korea Institute of Atmospheric Prediction Systems - Package for Observation Processing) have developed to provide optimal observations to the data assimilation system for the KIAPS Integrated Model (KIM). Currently, the KPOP has capable of processing almost all of observations for the KMA (Korea Meteorological Administration) operational global data assimilation system. The height adjustment of SURFACE observations are essential for the quality control due to the difference in height between observation station and model topography. For the SURFACE observation, it is usual to adjust the height using lapse rate or hypsometric equation, which decides values mainly depending on the difference of height. We have a question of whether the height can be properly adjusted following to the linear or exponential relationship solely with regard to the difference of height, with disregard the atmospheric conditions. In this study, firstly we analyse the change of surface variables such as temperature (T2m), pressure (Psfc), humidity (RH2m and Q2m), and wind components (U and V) according to the height difference. Additionally, we look further into the relationships among surface variables . The difference of pressure shows a strong linear relationship with difference of height. But the difference of temperature according to the height shows a significant correlation with difference of relative humidity than with the height difference. A development of reliable model for the height-adjustment of surface temperature is being undertaken based on the preliminary results.

  4. FHR Process Instruments

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Holcomb, David Eugene

    2015-01-01

    Fluoride salt-cooled High temperature Reactors (FHRs) are entering into early phase engineering development. Initial candidate technologies have been identified to measure all of the required process variables. The purpose of this paper is to describe the proposed measurement techniques in sufficient detail to enable assessment of the proposed instrumentation suite and to support development of the component technologies. This paper builds upon the instrumentation chapter of the recently published FHR technology development roadmap. Locating instruments outside of the intense core radiation and high-temperature fluoride salt environment significantly decreases their environmental tolerance requirements. Under operating conditions, FHR primary coolant salt ismore » a transparent, low-vapor-pressure liquid. Consequently, FHRs can employ standoff optical measurements from above the salt pool to assess in-vessel conditions. For example, the core outlet temperature can be measured by observing the fuel s blackbody emission. Similarly, the intensity of the core s Cerenkov glow indicates the fission power level. Short-lived activation of the primary coolant provides another means for standoff measurements of process variables. The primary coolant flow and neutron flux can be measured using gamma spectroscopy along the primary coolant piping. FHR operation entails a number of process measurements. Reactor thermal power and core reactivity are the most significant variables for process control. Thermal power can be determined by measuring the primary coolant mass flow rate and temperature rise across the core. The leading candidate technologies for primary coolant temperature measurement are Au-Pt thermocouples and Johnson noise thermometry. Clamp-on ultrasonic flow measurement, that includes high-temperature tolerant standoffs, is a potential coolant flow measurement technique. Also, the salt redox condition will be monitored as an indicator of its corrosiveness. Both electrochemical techniques and optical spectroscopy are candidate fluoride salt redox measurement methods. Coolant level measurement can be performed using radar-level gauges located in standpipes above the reactor vessel. While substantial technical development remains for most of the instruments, industrially compatible instruments based upon proven technology can be reasonably extrapolated from the current state of the art.« less

  5. Stability of mycotoxins during food processing.

    PubMed

    Bullerman, Lloyd B; Bianchini, Andreia

    2007-10-20

    The mycotoxins that commonly occur in cereal grains and other products are not completely destroyed during food processing operations and can contaminate finished processed foods. The mycotoxins most commonly associated with cereal grains are aflatoxins, ochratoxin A, fumonisins, deoxynivalenol and zearalenone. The various food processes that may have effects on mycotoxins include sorting, trimming, cleaning, milling, brewing, cooking, baking, frying, roasting, canning, flaking, alkaline cooking, nixtamalization, and extrusion. Most of the food processes have variable effects on mycotoxins, with those that utilize the highest temperatures having greatest effects. In general the processes reduce mycotoxin concentrations significantly, but do not eliminate them completely. However, roasting and extrusion processing show promise for lowering mycotoxin concentrations, though very high temperatures are needed to bring about much of a reduction in mycotoxin concentrations. Extrusion processing at temperatures greater than 150 degrees C are needed to give good reduction of zearalenone, moderate reduction of alfatoxins, variable to low reduction of deoxynivalenol and good reduction of fumonisins. The greatest reductions of fumonisins occur at extrusion temperatures of 160 degrees C or higher and in the presence of glucose. Extrusion of fumonisin contaminated corn grits with 10% added glucose resulted in 75-85% reduction in Fumonisin B(1) levels. Some fumonisin degredation products are formed during extrusion, including small amounts of hydrolyzed Fumonisin B(1) and N-(Carboxymethyl) - Fumonisin B(1) and somewhat higher amounts of N-(1-deoxy-d-fructos-1-yl) Fumonisin B(1) in extruded grits containing added glucose. Feeding trial toxicity tests in rats with extruded fumonisin contaminated corn grits show some reduction in toxicity of grits extruded with glucose.

  6. Quality-by-Design (QbD): An integrated process analytical technology (PAT) approach for a dynamic pharmaceutical co-precipitation process characterization and process design space development.

    PubMed

    Wu, Huiquan; White, Maury; Khan, Mansoor A

    2011-02-28

    The aim of this work was to develop an integrated process analytical technology (PAT) approach for a dynamic pharmaceutical co-precipitation process characterization and design space development. A dynamic co-precipitation process by gradually introducing water to the ternary system of naproxen-Eudragit L100-alcohol was monitored at real-time in situ via Lasentec FBRM and PVM. 3D map of count-time-chord length revealed three distinguishable process stages: incubation, transition, and steady-state. The effects of high risk process variables (slurry temperature, stirring rate, and water addition rate) on both derived co-precipitation process rates and final chord-length-distribution were evaluated systematically using a 3(3) full factorial design. Critical process variables were identified via ANOVA for both transition and steady state. General linear models (GLM) were then used for parameter estimation for each critical variable. Clear trends about effects of each critical variable during transition and steady state were found by GLM and were interpreted using fundamental process principles and Nyvlt's transfer model. Neural network models were able to link process variables with response variables at transition and steady state with R(2) of 0.88-0.98. PVM images evidenced nucleation and crystal growth. Contour plots illustrated design space via critical process variables' ranges. It demonstrated the utility of integrated PAT approach for QbD development. Published by Elsevier B.V.

  7. Diffusion-Controlled Recrystallization of Water Sorbed into Poly(meth)acrylates Revealed by Variable-Temperature Mid-Infrared Spectroscopy and Molecular Dynamics Simulation.

    PubMed

    Yasoshima, Nobuhiro; Fukuoka, Mizuki; Kitano, Hiromi; Kagaya, Shigehiro; Ishiyama, Tatsuya; Gemmei-Ide, Makoto

    2017-05-18

    Recrystallization behaviors of water sorbed into four poly(meth)acrylates, poly(2-methoxyethyl acrylate), poly(tetrahydrofurfuryl acrylate), poly(methyl acrylate), and poly(methyl methacrylate), are investigated by variable-temperature mid-infrared (VT-MIR) spectroscopy and molecular dynamics (MD) simulation. VT-MIR spectra demonstrate that recrystallization temperatures of water sorbed into the polymers are positively correlated with their glass-transition temperatures reported previously. The present MD simulation shows that a lower-limit temperature of the diffusion for the sorbed water and the glass-transition temperatures of the polymers also have a positive correlation, indicating that the recrystallization is controlled by diffusion mechanism rather than reorientation mechanism. Detailed molecular processes of not only recrystallization during rewarming but also crystallization during cooling and hydrogen-bonding states of water in the polymers are systematically analyzed and discussed.

  8. Uncertainty analysis as essential step in the establishment of the dynamic Design Space of primary drying during freeze-drying.

    PubMed

    Mortier, Séverine Thérèse F C; Van Bockstal, Pieter-Jan; Corver, Jos; Nopens, Ingmar; Gernaey, Krist V; De Beer, Thomas

    2016-06-01

    Large molecules, such as biopharmaceuticals, are considered the key driver of growth for the pharmaceutical industry. Freeze-drying is the preferred way to stabilise these products when needed. However, it is an expensive, inefficient, time- and energy-consuming process. During freeze-drying, there are only two main process variables to be set, i.e. the shelf temperature and the chamber pressure, however preferably in a dynamic way. This manuscript focuses on the essential use of uncertainty analysis for the determination and experimental verification of the dynamic primary drying Design Space for pharmaceutical freeze-drying. Traditionally, the chamber pressure and shelf temperature are kept constant during primary drying, leading to less optimal process conditions. In this paper it is demonstrated how a mechanistic model of the primary drying step gives the opportunity to determine the optimal dynamic values for both process variables during processing, resulting in a dynamic Design Space with a well-known risk of failure. This allows running the primary drying process step as time efficient as possible, hereby guaranteeing that the temperature at the sublimation front does not exceed the collapse temperature. The Design Space is the multidimensional combination and interaction of input variables and process parameters leading to the expected product specifications with a controlled (i.e., high) probability. Therefore, inclusion of parameter uncertainty is an essential part in the definition of the Design Space, although it is often neglected. To quantitatively assess the inherent uncertainty on the parameters of the mechanistic model, an uncertainty analysis was performed to establish the borders of the dynamic Design Space, i.e. a time-varying shelf temperature and chamber pressure, associated with a specific risk of failure. A risk of failure acceptance level of 0.01%, i.e. a 'zero-failure' situation, results in an increased primary drying process time compared to the deterministic dynamic Design Space; however, the risk of failure is under control. Experimental verification revealed that only a risk of failure acceptance level of 0.01% yielded a guaranteed zero-defect quality end-product. The computed process settings with a risk of failure acceptance level of 0.01% resulted in a decrease of more than half of the primary drying time in comparison with a regular, conservative cycle with fixed settings. Copyright © 2016. Published by Elsevier B.V.

  9. Seasonal-to-Interannual Precipitation Variability and Predictability in a Coupled Land-Atmosphere System

    NASA Technical Reports Server (NTRS)

    Koster, Randal D.; Suarez, M. J.; Heiser, M.

    1998-01-01

    In an earlier GCM study, we showed that interactive land surface processes generally contribute more to continental precipitation variance than do variable sea surface temperatures (SSTs). A new study extends this result through an analysis of 16-member ensembles of multi-decade GCM simulations. We can now show that in many regions, although land processes determine the amplitude of the interannual precipitation anomalies, variable SSTs nevertheless control their timing. The GCM data can be processed into indices that describe geographical variations in (1) the potential for seasonal-to-interannual prediction, and (2) the extent to which the predictability relies on the proper representation of land-atmosphere feedback.

  10. Modeling critical zone processes in intensively managed environments

    NASA Astrophysics Data System (ADS)

    Kumar, Praveen; Le, Phong; Woo, Dong; Yan, Qina

    2017-04-01

    Processes in the Critical Zone (CZ), which sustain terrestrial life, are tightly coupled across hydrological, physical, biochemical, and many other domains over both short and long timescales. In addition, vegetation acclimation resulting from elevated atmospheric CO2 concentration, along with response to increased temperature and altered rainfall pattern, is expected to result in emergent behaviors in ecologic and hydrologic functions, subsequently controlling CZ processes. We hypothesize that the interplay between micro-topographic variability and these emergent behaviors will shape complex responses of a range of ecosystem dynamics within the CZ. Here, we develop a modeling framework ('Dhara') that explicitly incorporates micro-topographic variability based on lidar topographic data with coupling of multi-layer modeling of the soil-vegetation continuum and 3-D surface-subsurface transport processes to study ecological and biogeochemical dynamics. We further couple a C-N model with a physically based hydro-geomorphologic model to quantify (i) how topographic variability controls the spatial distribution of soil moisture, temperature, and biogeochemical processes, and (ii) how farming activities modify the interaction between soil erosion and soil organic carbon (SOC) dynamics. To address the intensive computational demand from high-resolution modeling at lidar data scale, we use a hybrid CPU-GPU parallel computing architecture run over large supercomputing systems for simulations. Our findings indicate that rising CO2 concentration and air temperature have opposing effects on soil moisture, surface water and ponding in topographic depressions. Further, the relatively higher soil moisture and lower soil temperature contribute to decreased soil microbial activities in the low-lying areas due to anaerobic conditions and reduced temperatures. The decreased microbial relevant processes cause the reduction of nitrification rates, resulting in relatively lower nitrate concentration. Results from geomorphologic model also suggest that soil erosion and deposition plays a dominant role in SOC both above- and below-ground. In addition, tillage can change the amplitude and frequency of C-N oscillation. This work sheds light in developing practical means for reducing soil erosion and carbon loss when the landscape is affected by human activities.

  11. Effect of process variables on the density and durability of the pellets made from high moisture corn stover

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jaya Shankar Tumuluru

    2014-03-01

    A flat die pellet mill was used to understand the effect of high levels of feedstock moisture content in the range of 28–38% (w.b.), with die rotational speeds of 40–60 Hz, and preheating temperatures of 30–110 °C on the pelleting characteristics of 4.8 mm screen size ground corn stover using an 8 mm pellet die. The physical properties of the pelletised biomass studied are: (a) pellet moisture content, (b) unit, bulk and tapped density, and (c) durability. Pelletisation experiments were conducted based on central composite design. Analysis of variance (ANOVA) indicated that feedstock moisture content influenced all of the physicalmore » properties at P < 0.001. Pellet moisture content decreased with increase in preheating temperature to about 110 °C and decreasing the feedstock moisture content to about 28% (w.b.). Response surface models developed for quality attributes with respect to process variables has adequately described the process with coefficient of determination (R2) values of >0.88. The other pellet quality attributes such as unit, bulk, tapped density, were maximised at feedstock moisture content of 30–33% (w.b.), die speeds of >50 Hz and preheating temperature of >90 °C. In case of durability a medium moisture content of 33–34% (w.b.) and preheating temperatures of >70 °C and higher die speeds >50 Hz resulted in high durable pellets. It can be concluded from the present study that feedstock moisture content, followed by preheating, and die rotational speed are the interacting process variables influencing pellet moisture content, unit, bulk and tapped density and durability.« less

  12. Variability of the Martian thermospheric temperatures during the last 7 Martian Years

    NASA Astrophysics Data System (ADS)

    Gonzalez-Galindo, Francisco; Lopez-Valverde, Miguel Angel; Millour, Ehouarn; Forget, François

    2014-05-01

    The temperatures and densities in the Martian upper atmosphere have a significant influence over the different processes producing atmospheric escape. A good knowledge of the thermosphere and its variability is thus necessary in order to better understand and quantify the atmospheric loss to space and the evolution of the planet. Different global models have been used to study the seasonal and interannual variability of the Martian thermosphere, usually considering three solar scenarios (solar minimum, solar medium and solar maximum conditions) to take into account the solar cycle variability. However, the variability of the solar activity within the simulated period of time is not usually considered in these models. We have improved the description of the UV solar flux included on the General Circulation Model for Mars developed at the Laboratoire de Météorologie Dynamique (LMD-MGCM) in order to include its observed day-to-day variability. We have used the model to simulate the thermospheric variability during Martian Years 24 to 30, using realistic UV solar fluxes and dust opacities. The model predicts and interannual variability of the temperatures in the upper thermosphere that ranges from about 50 K during the aphelion to up to 150 K during perihelion. The seasonal variability of temperatures due to the eccentricity of the Martian orbit is modified by the variability of the solar flux within a given Martian year. The solar rotation cycle produces temperature oscillations of up to 30 K. We have also studied the response of the modeled thermosphere to the global dust storms in Martian Year 25 and Martian Year 28. The atmospheric dynamics are significantly modified by the global dust storms, which induces significant changes in the thermospheric temperatures. The response of the model to the presence of both global dust storms is in good agreement with previous modeling results (Medvedev et al., Journal of Geophysical Research, 2013). As expected, the simulated ionosphere is also sensitive to the variability of the solar activity. Acknowledgemnt: Francisco González-Galindo is funded by a CSIC JAE-Doc contract financed by the European Social Fund

  13. The effects of temperature and frequencies in ultrasound assisted extraction of phycocyanin from microalgae Spirulina sp

    NASA Astrophysics Data System (ADS)

    Hadiyanto, Suttrisnorhadi, Sutanto, Heri; Suzery, Meiny; Soetrisnanto, Danny; Azizah, Nur

    2015-12-01

    Microalgae Spirulina sp has been identified as source of protein and other high added value compounds. One of the compounds is phycocyanin as also known for antioxidant use. The extraction of this compound by using conventional method (soxhlet extraction) resulted low yield and longer processing time. This research was aimed to extract phycocyanin by using an extraction assisted by ultrasound irradiation. The extraction was performed by using variable of ultrasound frequency and extraction temperature and ethanol was used as a solvent. The result showed that yield of phycocyanin extracted by conventional method was 11.13% while the ultrasound irradiation could increase the yield up to 15.61% at constant frequency of 42 kHz, while the optimum temperature was obtained at 45°C. The analysis of variable interactions showed that both temperature and time has an interaction and temperature was the highest variable in increasing the yield. The conclusion of this research was the ultrasound could improve significantly the efficiency of extraction as well as activity of phycocyanin extracted from microalgae.

  14. The effects of temperature and frequencies in ultrasound assisted extraction of phycocyanin from microalgae Spirulina sp

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hadiyanto,, E-mail: hadiyanto@live.undip.ac.id; Suttrisnorhadi,; Soetrisnanto, Danny

    Microalgae Spirulina sp has been identified as source of protein and other high added value compounds. One of the compounds is phycocyanin as also known for antioxidant use. The extraction of this compound by using conventional method (soxhlet extraction) resulted low yield and longer processing time. This research was aimed to extract phycocyanin by using an extraction assisted by ultrasound irradiation. The extraction was performed by using variable of ultrasound frequency and extraction temperature and ethanol was used as a solvent. The result showed that yield of phycocyanin extracted by conventional method was 11.13% while the ultrasound irradiation could increasemore » the yield up to 15.61% at constant frequency of 42 kHz, while the optimum temperature was obtained at 45°C. The analysis of variable interactions showed that both temperature and time has an interaction and temperature was the highest variable in increasing the yield. The conclusion of this research was the ultrasound could improve significantly the efficiency of extraction as well as activity of phycocyanin extracted from microalgae.« less

  15. Ultrasonic attenuation measurements determine onset, degree, and completion of recrystallization

    NASA Technical Reports Server (NTRS)

    Generazio, E. R.

    1988-01-01

    Ultrasonic attenuation was measured for cold worked Nickel 200 samples annealed at increasing temperatures. Localized dislocation density variations, crystalline order and volume percent of recrystallized phase were determined over the anneal temperature range using transmission electron microscopy, X-ray diffraction, and metallurgy. The exponent of the frequency dependence of the attenuation was found to be a key variable relating ultrasonic attenuation to the thermal kinetics of the recrystallization process. Identification of this key variable allows for the ultrasonic determination of onset, degree, and completion of recrystallization.

  16. Time-division multiplexer uses digital gates

    NASA Technical Reports Server (NTRS)

    Myers, C. E.; Vreeland, A. E.

    1977-01-01

    Device eliminates errors caused by analog gates in multiplexing a large number of channels at high frequency. System was designed for use in aerospace work to multiplex signals for monitoring such variables as fuel consumption, pressure, temperature, strain, and stress. Circuit may be useful in monitoring variables in process control and medicine as well.

  17. Laser welding process in PP moulding parts: Evaluation of seam performance

    NASA Astrophysics Data System (ADS)

    Oliveira, N.; Pontes, A. J.

    2015-12-01

    The Polypropylene is one of the most versatile polymer materials used in the industry. Due to this versatility, it is possible to use it in different products. This material can also be mixed with several additives namely glass fiber, carbon nanotubes, etc. This compatibility with different additives allows also obtaining products with characteristics that goes from an impact absorber to an electricity conductor. When is necessary to join components in PP they could be welded through hot plate, ultrasonic weld and also by laser. This study had the objective of study the influence of several variables, capable of influence the final quality of the seam. In this case were studied variables of the injection molding process as mold temperature and cooling time. Was also studied laser welding variables and different materials. The results showed that the variables that have the most influence were mould temperature, laser velocity and laser diameter. The seams were analyzed using Optical Microscopy technique. The seams showed perfect contact between the materials analyzed, despite the high standard variation presented in the mechanical testes.

  18. Global Sensitivity Analysis as Good Modelling Practices tool for the identification of the most influential process parameters of the primary drying step during freeze-drying.

    PubMed

    Van Bockstal, Pieter-Jan; Mortier, Séverine Thérèse F C; Corver, Jos; Nopens, Ingmar; Gernaey, Krist V; De Beer, Thomas

    2018-02-01

    Pharmaceutical batch freeze-drying is commonly used to improve the stability of biological therapeutics. The primary drying step is regulated by the dynamic settings of the adaptable process variables, shelf temperature T s and chamber pressure P c . Mechanistic modelling of the primary drying step leads to the optimal dynamic combination of these adaptable process variables in function of time. According to Good Modelling Practices, a Global Sensitivity Analysis (GSA) is essential for appropriate model building. In this study, both a regression-based and variance-based GSA were conducted on a validated mechanistic primary drying model to estimate the impact of several model input parameters on two output variables, the product temperature at the sublimation front T i and the sublimation rate ṁ sub . T s was identified as most influential parameter on both T i and ṁ sub , followed by P c and the dried product mass transfer resistance α Rp for T i and ṁ sub , respectively. The GSA findings were experimentally validated for ṁ sub via a Design of Experiments (DoE) approach. The results indicated that GSA is a very useful tool for the evaluation of the impact of different process variables on the model outcome, leading to essential process knowledge, without the need for time-consuming experiments (e.g., DoE). Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Variable Temperature Infrared Spectroscopy Investigations of Benzoic Acid Desorption from Sodium and Calcium Montmorillonite Clays.

    PubMed

    Nickels, Tara M; Ingram, Audrey L; Maraoulaite, Dalia K; White, Robert L

    2015-12-01

    Processes involved in thermal desorption of benzoic acid from sodium and calcium montmorillonite clays are investigated by using variable temperature diffuse reflection Fourier transform infrared spectroscopy (DRIFTS). By monitoring the temperature dependence of infrared absorbance bands while heating samples, subtle changes in molecular vibrations are detected and employed to characterize specific benzoic acid adsorption sites. Abrupt changes in benzoic acid adsorption site properties occur for both clay samples at about 125 °C. Difference spectra absorbance band frequency variations indicate that adsorbed benzoic acid interacts with interlayer cations through water bridges and that these interactions can be disrupted by the presence of organic anions, in particular, benzoate.

  20. Compensatory Water Effects Link Yearly Global Land CO2 Sink Changes to Temperature

    NASA Technical Reports Server (NTRS)

    Jung, Martin; Reichstein, Markus; Tramontana, Gianluca; Viovy, Nicolas; Schwalm, Christopher R.; Wang, Ying-Ping; Weber, Ulrich; Weber, Ulrich; Zaehle, Soenke; Zeng, Ning; hide

    2017-01-01

    Large interannual variations in the measured growth rate of atmospheric carbon dioxide (CO2) originate primarily from fluctuations in carbon uptake by land ecosystems13. It remains uncertain, however, to what extent temperature and water availability control the carbon balance of land ecosystems across spatial and temporal scales314. Here we use empirical models based on eddy covariance data15 and process-based models16,17 to investigate the effect of changes in temperature and water availability on gross primary productivity (GPP), terrestrial ecosystem respiration (TER) and net ecosystem exchange (NEE) at local and global scales. We find that water availability is the dominant driver of the local interannual variability in GPP and TER. To a lesser extent this is true also for NEE at the local scale, but when integrated globally, temporal NEE variability is mostly driven by temperature fluctuations. We suggest that this apparent paradox can be explained by two compensatory water effects. Temporal water-driven GPP and TER variations compensate locally, dampening water-driven NEE variability. Spatial water availability anomalies also compensate, leaving a dominant temperature signal in the year-to-year fluctuations of the land carbon sink. These findings help to reconcile seemingly contradictory reports regarding the importance of temperature and water in controlling the interannual variability of the terrestrial carbon balance36,9,11,12,14. Our study indicates that spatial climate covariation drives the global carbon cycle response.

  1. Patterns in Temporal Variability of Temperature, Oxygen and pH along an Environmental Gradient in a Coral Reef

    PubMed Central

    Guadayol, Òscar; Silbiger, Nyssa J.; Donahue, Megan J.; Thomas, Florence I. M.

    2014-01-01

    Spatial and temporal environmental variability are important drivers of ecological processes at all scales. As new tools allow the in situ exploration of individual responses to fluctuations, ecologically meaningful ways of characterizing environmental variability at organism scales are needed. We investigated the fine-scale spatial heterogeneity of high-frequency temporal variability in temperature, dissolved oxygen concentration, and pH experienced by benthic organisms in a shallow coastal coral reef. We used a spatio-temporal sampling design, consisting of 21 short-term time-series located along a reef flat-to-reef slope transect, coupled to a long-term station monitoring water column changes. Spectral analyses revealed sharp gradients in variance decomposed by frequency, as well as differences between physically-driven and biologically-reactive parameters. These results highlight the importance of environmental variance at organismal scales and present a new sampling scheme for exploring this variability in situ. PMID:24416364

  2. Multi-Wheat-Model Ensemble Responses to Interannual Climate Variability

    NASA Technical Reports Server (NTRS)

    Ruane, Alex C.; Hudson, Nicholas I.; Asseng, Senthold; Camarrano, Davide; Ewert, Frank; Martre, Pierre; Boote, Kenneth J.; Thorburn, Peter J.; Aggarwal, Pramod K.; Angulo, Carlos

    2016-01-01

    We compare 27 wheat models' yield responses to interannual climate variability, analyzed at locations in Argentina, Australia, India, and The Netherlands as part of the Agricultural Model Intercomparison and Improvement Project (AgMIP) Wheat Pilot. Each model simulated 1981e2010 grain yield, and we evaluate results against the interannual variability of growing season temperature, precipitation, and solar radiation. The amount of information used for calibration has only a minor effect on most models' climate response, and even small multi-model ensembles prove beneficial. Wheat model clusters reveal common characteristics of yield response to climate; however models rarely share the same cluster at all four sites indicating substantial independence. Only a weak relationship (R2 0.24) was found between the models' sensitivities to interannual temperature variability and their response to long-termwarming, suggesting that additional processes differentiate climate change impacts from observed climate variability analogs and motivating continuing analysis and model development efforts.

  3. Remote sensing and avian influenza: A review of image processing methods for extracting key variables affecting avian influenza virus survival in water from Earth Observation satellites

    NASA Astrophysics Data System (ADS)

    Tran, Annelise; Goutard, Flavie; Chamaillé, Lise; Baghdadi, Nicolas; Lo Seen, Danny

    2010-02-01

    Recent studies have highlighted the potential role of water in the transmission of avian influenza (AI) viruses and the existence of often interacting variables that determine the survival rate of these viruses in water; the two main variables are temperature and salinity. Remote sensing has been used to map and monitor water bodies for several decades. In this paper, we review satellite image analysis methods used for water detection and characterization, focusing on the main variables that influence AI virus survival in water. Optical and radar imagery are useful for detecting water bodies at different spatial and temporal scales. Methods to monitor the temperature of large water surfaces are also available. Current methods for estimating other relevant water variables such as salinity, pH, turbidity and water depth are not presently considered to be effective.

  4. An improved model for soil surface temperature from air temperature in permafrost regions of Qinghai-Xizang (Tibet) Plateau of China

    NASA Astrophysics Data System (ADS)

    Hu, Guojie; Wu, Xiaodong; Zhao, Lin; Li, Ren; Wu, Tonghua; Xie, Changwei; Pang, Qiangqiang; Cheng, Guodong

    2017-08-01

    Soil temperature plays a key role in hydro-thermal processes in environments and is a critical variable linking surface structure to soil processes. There is a need for more accurate temperature simulation models, particularly in Qinghai-Xizang (Tibet) Plateau (QXP). In this study, a model was developed for the simulation of hourly soil surface temperatures with air temperatures. The model incorporated the thermal properties of the soil, vegetation cover, solar radiation, and water flux density and utilized field data collected from Qinghai-Xizang (Tibet) Plateau (QXP). The model was used to simulate the thermal regime at soil depths of 5 cm, 10 cm and 20 cm and results were compared with those from previous models and with experimental measurements of ground temperature at two different locations. The analysis showed that the newly developed model provided better estimates of observed field temperatures, with an average mean absolute error (MAE), root mean square error (RMSE), and the normalized standard error (NSEE) of 1.17 °C, 1.30 °C and 13.84 %, 0.41 °C, 0.49 °C and 5.45 %, 0.13 °C, 0.18 °C and 2.23 % at 5 cm, 10 cm and 20 cm depths, respectively. These findings provide a useful reference for simulating soil temperature and may be incorporated into other ecosystem models requiring soil temperature as an input variable for modeling permafrost changes under global warming.

  5. A comparison of sea surface salinity in the equatorial Pacific Ocean during the 1997-1998, 2012-2013, and 2014-2015 ENSO events

    NASA Astrophysics Data System (ADS)

    Corbett, Caroline M.; Subrahmanyam, Bulusu; Giese, Benjamin S.

    2017-11-01

    Sea surface salinity (SSS) variability during the 1997-1998 El Niño event and the failed 2012-2013 and 2014-2015 El Niño events is explored using a combination of observations and ocean reanalyses. Previously, studies have mainly focused on the sea surface temperature (SST) and sea surface height (SSH) variability. This analysis utilizes salinity data from Argo and the Simple Ocean Data Assimilation (SODA) reanalysis to examine the SSS variability. Advective processes and evaporation minus precipitation (E-P) variability is understood to influence SSS variability. Using surface wind, surface current, evaporation, and precipitation data, we analyze the causes for the observed SSS variability during each event. Barrier layer thickness and upper level salt content are also examined in connection to subsurface salinity variability. Both advective processes and E-P variability are important during the generation and onset of a successful El Niño, while a lack of one or both of these processes leads to a failed ENSO event.

  6. Major and trace element modeling of mid-ocean ridge mantle melting from the garnet to the plagioclase stability fields: Generating local and global compositional variability

    NASA Astrophysics Data System (ADS)

    Brown, S. M.; Behn, M. D.; Grove, T. L.

    2017-12-01

    We present results of a combined petrologic - geochemical (major and trace element) - geodynamical forward model for mantle melting and subsequent melt modification. The model advances Behn & Grove (2015), and is calibrated using experimental petrology. Our model allows for melting in the plagioclase, spinel, and garnet fields with a flexible retained melt fraction (from pure batch to pure fractional), tracks residual mantle composition, and includes melting with water, variable melt productivity, and mantle mode calculations. This approach is valuable for understanding oceanic crustal accretion, which involves mantle melting and melt modification by migration and aggregation. These igneous processes result in mid-ocean ridge basalts that vary in composition at the local (segment) and global scale. The important variables are geophysical and geochemical and include mantle composition, potential temperature, mantle flow, and spreading rate. Accordingly, our model allows us to systematically quantify the importance of each of these external variables. In addition to discriminating melt generation effects, we are able to discriminate the effects of different melt modification processes (inefficient pooling, melt-rock reaction, and fractional crystallization) in generating both local, segment-scale and global-scale compositional variability. We quantify the influence of a specific igneous process on the generation of oceanic crust as a function of variations in the external variables. We also find that it is unlikely that garnet lherzolite melting produces a signature in either major or trace element compositions formed from aggregated melts, because when melting does occur in the garnet field at high mantle temperature, it contributes a relatively small, uniform fraction (< 10%) of the pooled melt compositions at all spreading rates. Additionally, while increasing water content and/or temperature promote garnet melting, they also increase melt extent, pushing the pooled composition to lower Sm/Yb and higher Lu/Hf.

  7. 40 CFR 63.1439 - General recordkeeping and reporting provisions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... for 6 hours, then the daily average is the average of the temperature measurements taken during those... operating conditions, considering typical variability of the specific process and combustion, recovery, or... temperature reading of −200 °C on a boiler), and will alert the operator by alarm or other means. The owner or...

  8. PILOT-SCALE PARAMETRIC TESTING OF SPRAY DRYER SO2 SCRUBBER FOR LOW-TO-MODERATE SULFUR COAL UTILITY APPLICATIONS

    EPA Science Inventory

    The report gives results of a comprehensive, pilot, dry, SO2 scrubbing test program to determine the effects of process variables on SO2 removal. In the spray dryer, stoichiometric ratio, flue gas temperature approach to adiabatic saturation, and temperature drop across the spray...

  9. Enrichment of wheat chips with omega-3 fatty acid by flaxseed addition: textural and some physicochemical properties.

    PubMed

    Yuksel, Ferhat; Karaman, Safa; Kayacier, Ahmed

    2014-02-15

    In the present study, wheat chips enriched with flaxseed flour were produced and response surface methodology was used for the studying the simultaneous effects of flaxseed level (10-20%), frying temperature (160-180 °C) and frying time (40-60 s) on some physicochemical, textural and sensorial properties and fatty acid composition of wheat chips. Ridge analysis was conducted to determine the optimum levels of processing variables. Predictive regression equations with adequate coefficients of determination (R² ≥ 0.705) to explain the effect of processing variables were constructed. Addition of flaxseed flour increased the dry matter and protein content of samples and increase of frying temperature decreased the hardness values of wheat chips samples. Increment in flaxseed level provided an increase in unsaturated fatty acid content namely omega-3 fatty acids of wheat chips samples. Overall acceptability of chips increased with the increase of frying temperature. Ridge analysis showed that maximum taste score would be at flaxseed level = 10%, frying temperature = 180 °C and frying time = 50 s. Copyright © 2013 Elsevier Ltd. All rights reserved.

  10. A simple method to measure the complex permittivity of materials at variable temperatures

    NASA Astrophysics Data System (ADS)

    Yang, Xiaoqing; Yin, Yang; Liu, Zhanwei; Zhang, Di; Wu, Shiyue; Yuan, Jianping; Li, Lixin

    2017-10-01

    Measurement of the complex permittivity (CP) of a material at different temperatures in microwave heating applications is difficult and complicated. In this paper a simple and convenient method is employed to measure the CP of a material over variable temperature. In this method the temperature of a sample is increased experimentally to obtain the formula for the relationship between CP and temperature by a genetic algorithm. We chose agar solution (sample) and a Yangshao reactor (microwave heating system) to validate the reliability and feasibility of this method. The physical parameters (the heat capacity, C p , density, ρ, and thermal conductivity, k) of the sample are set as constants in the process of simulation and inversion. We analyze the influence of the variation of physical parameters with temperature on the accuracy of the inversion results. It is demonstrated that the variation of these physical parameters has little effect on the inversion results in a certain temperature range.

  11. Investigation of the Process Conditions for Hydrogen Production by Steam Reforming of Glycerol over Ni/Al₂O₃ Catalyst Using Response Surface Methodology (RSM).

    PubMed

    Ebshish, Ali; Yaakob, Zahira; Taufiq-Yap, Yun Hin; Bshish, Ahmed

    2014-03-19

    In this work; a response surface methodology (RSM) was implemented to investigate the process variables in a hydrogen production system. The effects of five independent variables; namely the temperature (X₁); the flow rate (X₂); the catalyst weight (X₃); the catalyst loading (X₄) and the glycerol-water molar ratio (X₅) on the H₂ yield (Y₁) and the conversion of glycerol to gaseous products (Y₂) were explored. Using multiple regression analysis; the experimental results of the H₂ yield and the glycerol conversion to gases were fit to quadratic polynomial models. The proposed mathematical models have correlated the dependent factors well within the limits that were being examined. The best values of the process variables were a temperature of approximately 600 °C; a feed flow rate of 0.05 mL/min; a catalyst weight of 0.2 g; a catalyst loading of 20% and a glycerol-water molar ratio of approximately 12; where the H₂ yield was predicted to be 57.6% and the conversion of glycerol was predicted to be 75%. To validate the proposed models; statistical analysis using a two-sample t -test was performed; and the results showed that the models could predict the responses satisfactorily within the limits of the variables that were studied.

  12. Ethanol-acetone pulping of wheat straw. Influence of the cooking and the beating of the pulps on the properties of the resulting paper sheets.

    PubMed

    Jiménez, L; Pérez, I; López, F; Ariza, J; Rodríguez, A

    2002-06-01

    The influence of independent variables in the pulping of wheat straw by use of an ethanol-acetone-water mixture [processing temperature and time, ethanol/(ethanol + acetone) value and (ethanol + acetone)/(ethanol + acetone + water) value] and of the number of PFI beating revolutions to which the pulp was subjected, on the properties of the resulting pulp (yield and Shopper-Riegler index) and of the paper sheets obtained from it (breaking length, stretch, burst index and tear index) was examined. By using a central composite factor design and the BMDP software suite, equations that relate each dependent variable to the different independent variables were obtained that reproduced the experimental results for the dependent variables with errors less than 30% at temperatures, times, ethanol/(ethanol + acetone) value, (ethanol + acetone)/(ethanol + acetone + water) value and numbers of PFI beating revolutions in the ranges 140-180 degrees C, 60-120 min, 25-75%, 35-75% and 0-1750, respectively. Using values of the independent variables over the variation ranges considered provided the following optimum values of the dependent variables: 78.17% (yield), 15.21 degrees SR (Shopper-Riegler index), 5265 m (breaking length), 1.94% (stretch), 2.53 kN/g (burst index) and 4.26 mN m2/g (tear index). Obtaining reasonably good paper sheets (with properties that differed by less than 15% from their optimum values except for the burst index, which was 28% lower) entailed using a temperature of 180 degrees C, an ethanol/(ethanol + acetone) value of 50%, an (ethanol + acetone)/(ethanol + acetone + water) value of 75%, a processing time of 60 min and a number of PFI beating revolutions of 1750. The yield was 32% lower under these conditions, however. A comparison of the results provided by ethanol, acetone and ethanol-acetone pulping revealed that the second and third process-which provided an increased yield were the best choices. On the other hand, if the pulp is to be refined, ethanol pulping is the process of choice.

  13. Late Holocene sea level variability and Atlantic Meridional Overturning Circulation

    USGS Publications Warehouse

    Cronin, Thomas M.; Farmer, Jesse R.; Marzen, R. E.; Thomas, E.; Varekamp, J.C.

    2014-01-01

    Pre-twentieth century sea level (SL) variability remains poorly understood due to limits of tide gauge records, low temporal resolution of tidal marsh records, and regional anomalies caused by dynamic ocean processes, notably multidecadal changes in Atlantic Meridional Overturning Circulation (AMOC). We examined SL and AMOC variability along the eastern United States over the last 2000 years, using a SL curve constructed from proxy sea surface temperature (SST) records from Chesapeake Bay, and twentieth century SL-sea surface temperature (SST) relations derived from tide gauges and instrumental SST. The SL curve shows multidecadal-scale variability (20–30 years) during the Medieval Climate Anomaly (MCA) and Little Ice Age (LIA), as well as the twentieth century. During these SL oscillations, short-term rates ranged from 2 to 4 mm yr−1, roughly similar to those of the last few decades. These oscillations likely represent internal modes of climate variability related to AMOC variability and originating at high latitudes, although the exact mechanisms remain unclear. Results imply that dynamic ocean changes, in addition to thermosteric, glacio-eustatic, or glacio-isostatic processes are an inherent part of SL variability in coastal regions, even during millennial-scale climate oscillations such as the MCA and LIA and should be factored into efforts that use tide gauges and tidal marsh sediments to understand global sea level rise.

  14. An improved hindcast approach for evaluation and diagnosis of physical processes in global climate models

    DOE PAGES

    Ma, H. -Y.; Chuang, C. C.; Klein, S. A.; ...

    2015-11-06

    Here, we present an improved procedure of generating initial conditions (ICs) for climate model hindcast experiments with specified sea surface temperature and sea ice. The motivation is to minimize errors in the ICs and lead to a better evaluation of atmospheric parameterizations' performance in the hindcast mode. We apply state variables (horizontal velocities, temperature and specific humidity) from the operational analysis/reanalysis for the atmospheric initial states. Without a data assimilation system, we apply a two-step process to obtain other necessary variables to initialize both the atmospheric (e.g., aerosols and clouds) and land models (e.g., soil moisture). First, we nudge onlymore » the model horizontal velocities towards operational analysis/reanalysis values, given a 6-hour relaxation time scale, to obtain all necessary variables. Compared to the original strategy in which horizontal velocities, temperature and specific humidity are nudged, the revised approach produces a better representation of initial aerosols and cloud fields which are more consistent and closer to observations and model's preferred climatology. Second, we obtain land ICs from an offline land model simulation forced with observed precipitation, winds, and surface fluxes. This approach produces more realistic soil moisture in the land ICs. With this refined procedure, the simulated precipitation, clouds, radiation, and surface air temperature over land are improved in the Day 2 mean hindcasts. Following this procedure, we propose a “Core” integration suite which provides an easily repeatable test allowing model developers to rapidly assess the impacts of various parameterization changes on the fidelity of modelled cloud-associated processes relative to observations.« less

  15. An improved hindcast approach for evaluation and diagnosis of physical processes in global climate models

    NASA Astrophysics Data System (ADS)

    Ma, H.-Y.; Chuang, C. C.; Klein, S. A.; Lo, M.-H.; Zhang, Y.; Xie, S.; Zheng, X.; Ma, P.-L.; Zhang, Y.; Phillips, T. J.

    2015-12-01

    We present an improved procedure of generating initial conditions (ICs) for climate model hindcast experiments with specified sea surface temperature and sea ice. The motivation is to minimize errors in the ICs and lead to a better evaluation of atmospheric parameterizations' performance in the hindcast mode. We apply state variables (horizontal velocities, temperature, and specific humidity) from the operational analysis/reanalysis for the atmospheric initial states. Without a data assimilation system, we apply a two-step process to obtain other necessary variables to initialize both the atmospheric (e.g., aerosols and clouds) and land models (e.g., soil moisture). First, we nudge only the model horizontal velocities toward operational analysis/reanalysis values, given a 6 h relaxation time scale, to obtain all necessary variables. Compared to the original strategy in which horizontal velocities, temperature, and specific humidity are nudged, the revised approach produces a better representation of initial aerosols and cloud fields which are more consistent and closer to observations and model's preferred climatology. Second, we obtain land ICs from an off-line land model simulation forced with observed precipitation, winds, and surface fluxes. This approach produces more realistic soil moisture in the land ICs. With this refined procedure, the simulated precipitation, clouds, radiation, and surface air temperature over land are improved in the Day 2 mean hindcasts. Following this procedure, we propose a "Core" integration suite which provides an easily repeatable test allowing model developers to rapidly assess the impacts of various parameterization changes on the fidelity of modeled cloud-associated processes relative to observations.

  16. Robustness of a rhythmic circuit to short- and long-term temperature changes.

    PubMed

    Tang, Lamont S; Taylor, Adam L; Rinberg, Anatoly; Marder, Eve

    2012-07-18

    Recent computational and experimental work has shown that similar network performance can result from variable sets of synaptic and intrinsic properties. Because temperature is a global perturbation that differentially influences every biological process within the nervous system, one might therefore expect that individual animals would respond differently to temperature. Nonetheless, the phase relationships of the pyloric rhythm of the stomatogastric ganglion (STG) of the crab, Cancer borealis, are remarkably invariant between 7 and 23°C (Tang et al., 2010). Here, we report that, when isolated STG preparations were exposed to more extreme temperature ranges, their networks became nonrhythmic, or "crashed", in a reversible fashion. Animals were acclimated for at least 3 weeks at 7, 11, or 19°C. When networks from the acclimated animals were perturbed by acute physiologically relevant temperature ramps (11-23°C), the network frequency and phase relationships were independent of the acclimation group. At high acute temperatures (>23°C), circuits from the cold-acclimated animals produced less-regular pyloric rhythms than those from warm-acclimated animals. At high acute temperatures, phase relationships between pyloric neurons were more variable from animal to animal than at moderate acute temperatures, suggesting that individual differences across animals in intrinsic circuit parameters are revealed at high temperatures. This shows that individual and variable neuronal circuits can behave similarly in normal conditions, but their behavior may diverge when confronted with extreme external perturbations.

  17. Drivers of River Water Temperature Space-time Variability in Northeast Greenland

    NASA Astrophysics Data System (ADS)

    Hannah, D. M.; Docherty, C.; Milner, A.

    2015-12-01

    Water temperature plays an important role in stream ecosystem functioning; however, water temperature dynamics in high Arctic environments have received relatively little attention. Given that global climate is predicted to change most at high latitudes, it is vital we broaden our knowledge of space-time variability in Arctic river temperature to understand controlling processes and potential consequences of climate change. To address this gap, our research aims: (1) to characterise seasonal and diel patterns of variability over three summer and two winter seasons with contrasting hydrometeorological conditions, (2) to unravel the key drivers influencing thermal regimes and (3) to place these results in the context of other snow/ glacier-melt dominated environments. Fieldwork was undertaken in July-September 2013, 2014 and 2015 close to the Zackenberg Research Station in Northeast Greenland - an area of continuous permafrost with a mean July air temperature of 6 °C. Five streams were chosen that drain different water source contributions (glacier melt, snow melt, groundwater). Data were collected at 30 minute intervals using micro-dataloggers. Air temperature data were collected within 7km by the Greenland Survey. Weather conditions were highly variable between field campaigns, with 2013 experiencing below average, and 2014 and 2015 above average, snowfall. Summer water temperatures appear to be high in comparison to some Arctic streams in Alaska and in Svalbard. Winter snowfall extent decreases stream water temperature; and water temperature increases with atmospheric exposure time (distance from source) - illustrating the intertwined controls of water and heat fluxes. These Greenland streams are most strongly influenced by snowmelt, but groundwater contributions could increase with a changing climate due to increased active layer thickness, which may result in increased river temperature with implications for aquatic biodiversity and ecosystem functioning.

  18. Noctilucent cloud formation and the effects of water vapor variability on temperatures in the middle atmosphere

    NASA Technical Reports Server (NTRS)

    Mckay, C. P.

    1985-01-01

    To investigate the occurrence of low temperatures and the formation of noctilucent clouds in the summer mesosphere, a one-dimensional time-dependent photochemical-thermal numerical model of the atmosphere between 50 and 120 km has been constructed. The model self-consistently solves the coupled photochemical and thermal equations as perturbation equations from a reference state assumed to be in equilibrium and is used to consider the effect of variability in water vapor in the lower mesosphere on the temperature in the region of noctilucent cloud formation. It is found that change in water vapor from an equilibrium value of 5 ppm at 50 km to a value of 10 ppm, a variation consistent with observations, can produce a roughly 15 K drop in temperature at 82 km. It is suggested that this process may produce weeks of cold temperatures and influence noctilucent cloud formation.

  19. Texturing by cooling a metallic melt in a magnetic field.

    PubMed

    Tournier, Robert F; Beaugnon, Eric

    2009-02-01

    Processing in a magnetic field leads to the texturing of materials along an easy-magnetization axis when a minimum anisotropy energy exists at the processing temperature; the magnetic field can be applied to a particle assembly embedded into a liquid, or to a solid at a high diffusion temperature close to the melting temperature or between the liquidus and the solidus temperatures in a region of partial melting. It has been shown in many experiments that texturing is easy to achieve in congruent and noncongruent compounds by applying the field above the melting temperature T m or above the liquidus temperature of alloys. Texturing from a melt is successful when the overheating temperature is just a few degrees above T m and fails when the processing time above T m is too long or when the overheating temperature is too high; these observations indicate the presence of unmelted crystals above T m with a size depending on these two variables that act as growth nuclei. A recent model that predicts the existence of unmelted crystals above the melting temperature is used to calculate their radius in a bismuth melt.

  20. Evaluation of the HadGEM3-A simulations in view of detection and attribution of human influence on extreme events in Europe

    NASA Astrophysics Data System (ADS)

    Vautard, Robert; Christidis, Nikolaos; Ciavarella, Andrew; Alvarez-Castro, Carmen; Bellprat, Omar; Christiansen, Bo; Colfescu, Ioana; Cowan, Tim; Doblas-Reyes, Francisco; Eden, Jonathan; Hauser, Mathias; Hegerl, Gabriele; Hempelmann, Nils; Klehmet, Katharina; Lott, Fraser; Nangini, Cathy; Orth, René; Radanovics, Sabine; Seneviratne, Sonia I.; van Oldenborgh, Geert Jan; Stott, Peter; Tett, Simon; Wilcox, Laura; Yiou, Pascal

    2018-04-01

    A detailed analysis is carried out to assess the HadGEM3-A global atmospheric model skill in simulating extreme temperatures, precipitation and storm surges in Europe in the view of their attribution to human influence. The analysis is performed based on an ensemble of 15 atmospheric simulations forced with observed sea surface temperature of the 54 year period 1960-2013. These simulations, together with dual simulations without human influence in the forcing, are intended to be used in weather and climate event attribution. The analysis investigates the main processes leading to extreme events, including atmospheric circulation patterns, their links with temperature extremes, land-atmosphere and troposphere-stratosphere interactions. It also compares observed and simulated variability, trends and generalized extreme value theory parameters for temperature and precipitation. One of the most striking findings is the ability of the model to capture North-Atlantic atmospheric weather regimes as obtained from a cluster analysis of sea level pressure fields. The model also reproduces the main observed weather patterns responsible for temperature and precipitation extreme events. However, biases are found in many physical processes. Slightly excessive drying may be the cause of an overestimated summer interannual variability and too intense heat waves, especially in central/northern Europe. However, this does not seem to hinder proper simulation of summer temperature trends. Cold extremes appear well simulated, as well as the underlying blocking frequency and stratosphere-troposphere interactions. Extreme precipitation amounts are overestimated and too variable. The atmospheric conditions leading to storm surges were also examined in the Baltics region. There, simulated weather conditions appear not to be leading to strong enough storm surges, but winds were found in very good agreement with reanalyses. The performance in reproducing atmospheric weather patterns indicates that biases mainly originate from local and regional physical processes. This makes local bias adjustment meaningful for climate change attribution.

  1. Polymer performance in cooling water: The influence of process variables

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Amjad, Z.; Pugh, J.; Zibrida, J.

    1997-01-01

    The key to the efficacy of phosphate and phosphonates in stabilized phosphate and all-organic cooling water treatment (CWT) programs is the presence and performance of polymeric inhibitors/dispersants. The performance of polymeric additives used in CWT programs can be adversely impacted by the presence of iron, phosphonate, or cationic polymer and influenced by a variety of process variables including system pH and temperature. In this article, the performance of several polymeric additives is evaluated under a variety of stressed conditions.

  2. Polymer performance in cooling water: The influence of process variables

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Amjad, Z.; Pugh, J.; Zibrida, J.

    1996-12-01

    The key to the efficacy of phosphate and phosphonates in stabilized phosphate and all-organic cooling water treatment (CWT) programs is the presence and performance of polymeric inhibitors/dispersants. The performance of polymeric additives used in CWT programs can be adversely impacted by the presence of iron, phosphonate, or cationic polymer and influenced by a variety of process variables including system pH and temperature. In this paper, the performance of several polymeric additives is evaluated under a variety of stressed conditions.

  3. Cross-scale modeling of surface temperature and tree seedling establishment inmountain landscapes

    USGS Publications Warehouse

    Dingman, John; Sweet, Lynn C.; McCullough, Ian M.; Davis, Frank W.; Flint, Alan L.; Franklin, Janet; Flint, Lorraine E.

    2013-01-01

    Abstract: Introduction: Estimating surface temperature from above-ground field measurements is important for understanding the complex landscape patterns of plant seedling survival and establishment, processes which occur at heights of only several centimeters. Currently, future climate models predict temperature at 2 m above ground, leaving ground-surface microclimate not well characterized. Methods: Using a network of field temperature sensors and climate models, a ground-surface temperature method was used to estimate microclimate variability of minimum and maximum temperature. Temperature lapse rates were derived from field temperature sensors and distributed across the landscape capturing differences in solar radiation and cold air drainages modeled at a 30-m spatial resolution. Results: The surface temperature estimation method used for this analysis successfully estimated minimum surface temperatures on north-facing, south-facing, valley, and ridgeline topographic settings, and when compared to measured temperatures yielded an R2 of 0.88, 0.80, 0.88, and 0.80, respectively. Maximum surface temperatures generally had slightly more spatial variability than minimum surface temperatures, resulting in R2 values of 0.86, 0.77, 0.72, and 0.79 for north-facing, south-facing, valley, and ridgeline topographic settings. Quasi-Poisson regressions predicting recruitment of Quercus kelloggii (black oak) seedlings from temperature variables were significantly improved using these estimates of surface temperature compared to air temperature modeled at 2 m. Conclusion: Predicting minimum and maximum ground-surface temperatures using a downscaled climate model coupled with temperature lapse rates estimated from field measurements provides a method for modeling temperature effects on plant recruitment. Such methods could be applied to improve projections of species’ range shifts under climate change. Areas of complex topography can provide intricate microclimates that may allow species to redistribute locally as climate changes.

  4. Effects of process variables on the yield stress of rheologically modified biomass

    Treesearch

    Joseph R. Samaniuk; C Tim Scott; Thatcher W. Root; Daniel J. Klingenberg

    2015-01-01

    Additives that alter the rheology of lignocellulosic biomass suspensions were tested under conditions of variable pH, temperature, and solid concentration. The effects of certain ions, biomass type, after the addition of rheological modifier were also examined. Torque and vane rheometry were used to measure the yield stress of samples. It was found that the...

  5. Thermal control system. [removing waste heat from industrial process spacecraft

    NASA Technical Reports Server (NTRS)

    Hewitt, D. R. (Inventor)

    1983-01-01

    The temperature of an exothermic process plant carried aboard an Earth orbiting spacecraft is regulated using a number of curved radiator panels accurately positioned in a circular arrangement to form an open receptacle. A module containing the process is insertable into the receptacle. Heat exchangers having broad exterior surfaces extending axially above the circumference of the module fit within arcuate spacings between adjacent radiator panels. Banks of variable conductance heat pipes partially embedded within and thermally coupled to the radiator panels extend across the spacings and are thermally coupled to broad exterior surfaces of the heat exchangers by flanges. Temperature sensors monitor the temperature of process fluid flowing from the module through the heat exchanges. Thermal conduction between the heat exchangers and the radiator panels is regulated by heating a control fluid within the heat pipes to vary the effective thermal length of the heat pipes in inverse proportion to changes in the temperature of the process fluid.

  6. [Elaboration of instant corn flour by hydrothermal process I].

    PubMed

    Martínez B, F; el-Dahs, A A

    1993-12-01

    The objective of this research was to investigate a simplified hydrothermal process for the production of instant corn flour and evaluate some variables that affected the degree of gelatinization of corn flour, and evaluate some technological characteristics of the flour. The use of grits of lesser particle diameter and increasing temperature of the soaking water resulted in an increase in the rate of absorption of water of grits, permitting a reduction of soaking time necessary for the process. The instant corn flour prepared by the hydrothermal process using corn grits soaked in water at room temperature (28-30 degrees C) for 5 hours and steaming for 1 minute at 118 degrees C presented characteristics of viscosity, water absorption index and water solubility index similar to that of flours prepared with grits soaked in water at a temperature higher tan room temperature and different steaming time (5 and 15 minutes). The characteristics of color and shelf life of corn flour were improved with the hydrothermal process.

  7. An extended Kalman-Bucy filter for atmospheric temperature profile retrieval with a passive microwave sounder

    NASA Technical Reports Server (NTRS)

    Ledsham, W. H.; Staelin, D. H.

    1978-01-01

    An extended Kalman-Bucy filter has been implemented for atmospheric temperature profile retrievals from observations made using the Scanned Microwave Spectrometer (SCAMS) instrument carried on the Nimbus 6 satellite. This filter has the advantage that it requires neither stationary statistics in the underlying processes nor linear production of the observed variables from the variables to be estimated. This extended Kalman-Bucy filter has yielded significant performance improvement relative to multiple regression retrieval methods. A multi-spot extended Kalman-Bucy filter has also been developed in which the temperature profiles at a number of scan angles in a scanning instrument are retrieved simultaneously. These multi-spot retrievals are shown to outperform the single-spot Kalman retrievals.

  8. High-temperature optical fiber instrumentation for gas flow monitoring in gas turbine engines

    NASA Astrophysics Data System (ADS)

    Roberts, Adrian; May, Russell G.; Pickrell, Gary R.; Wang, Anbo

    2002-02-01

    In the design and testing of gas turbine engines, real-time data about such physical variables as temperature, pressure and acoustics are of critical importance. The high temperature environment experienced in the engines makes conventional electronic sensors devices difficult to apply. Therefore, there is a need for innovative sensors that can reliably operate under the high temperature conditions and with the desirable resolution and frequency response. A fiber optic high temperature sensor system for dynamic pressure measurement is presented in this paper. This sensor is based on a new sensor technology - the self-calibrated interferometric/intensity-based (SCIIB) sensor, recently developed at Virginia Tech. State-of-the-art digital signal processing (DSP) methods are applied to process the signal from the sensor to acquire high-speed frequency response.

  9. Submesoscale Sea Surface Temperature Variability from UAV and Satellite Measurements

    NASA Astrophysics Data System (ADS)

    Castro, S. L.; Emery, W. J.; Tandy, W., Jr.; Good, W. S.

    2017-12-01

    Technological advances in spatial resolution of observations have revealed the importance of short-lived ocean processes with scales of O(1km). These submesoscale processes play an important role for the transfer of energy from the meso- to small scales and for generating significant spatial and temporal intermittency in the upper ocean, critical for the mixing of the oceanic boundary layer. Submesoscales have been observed in sea surface temperatures (SST) from satellites. Satellite SST measurements are spatial averages over the footprint of the satellite. When the variance of the SST distribution within the footprint is small, the average value is representative of the SST over the whole pixel. If the variance is large, the spatial heterogeneity is a source of uncertainty in satellite derived SSTs. Here we show evidence that the submesoscale variability in SSTs at spatial scales of 1km is responsible for the spatial variability within satellite footprints. Previous studies of the spatial variability in SST, using ship-based radiometric data suggested that variability at scales smaller than 1 km is significant and affects the uncertainty of satellite-derived skin SSTs. We examine data collected by a calibrated thermal infrared radiometer, the Ball Experimental Sea Surface Temperature (BESST), flown on a UAV over the Arctic Ocean and compare them with coincident measurements from the MODIS spaceborne radiometer to assess the spatial variability of SST within 1 km pixels. By taking the standard deviation of all the BESST measurements within individual MODIS pixels we show that significant spatial variability exists within the footprints. The distribution of the surface variability measured by BESST shows a peak value of O(0.1K) with 95% of the pixels showing σ < 0.45K. More importantly, high-variability pixels are located at density fronts in the marginal ice zone, which are a primary source of submesoscale intermittency near the surface in the Arctic Ocean. Wavenumber spectra of the BESST SSTs indicate a spectral slope of -2, consistent with the presence of submesoscale processes. Furthermore, not only is the BESST wavenumber spectra able to match the MODIS SST spectra well, but also extends the spectral slope of -2 by 2 decades relative to MODIS, from wavelengths of 8km to 0.08km.

  10. Numerical Simulation and Optimization of Directional Solidification Process of Single Crystal Superalloy Casting

    PubMed Central

    Zhang, Hang; Xu, Qingyan; Liu, Baicheng

    2014-01-01

    The rapid development of numerical modeling techniques has led to more accurate results in modeling metal solidification processes. In this study, the cellular automaton-finite difference (CA-FD) method was used to simulate the directional solidification (DS) process of single crystal (SX) superalloy blade samples. Experiments were carried out to validate the simulation results. Meanwhile, an intelligent model based on fuzzy control theory was built to optimize the complicate DS process. Several key parameters, such as mushy zone width and temperature difference at the cast-mold interface, were recognized as the input variables. The input variables were functioned with the multivariable fuzzy rule to get the output adjustment of withdrawal rate (v) (a key technological parameter). The multivariable fuzzy rule was built, based on the structure feature of casting, such as the relationship between section area, and the delay time of the temperature change response by changing v, and the professional experience of the operator as well. Then, the fuzzy controlling model coupled with CA-FD method could be used to optimize v in real-time during the manufacturing process. The optimized process was proven to be more flexible and adaptive for a steady and stray-grain free DS process. PMID:28788535

  11. Model-Data Fusion to Test Hypothesized Drivers of Lake Carbon Cycling Reveals Importance of Physical Controls

    NASA Astrophysics Data System (ADS)

    Hararuk, Oleksandra; Zwart, Jacob A.; Jones, Stuart E.; Prairie, Yves; Solomon, Christopher T.

    2018-03-01

    Formal integration of models and data to test hypotheses about the processes controlling carbon dynamics in lakes is rare, despite the importance of lakes in the carbon cycle. We built a suite of models (n = 102) representing different hypotheses about lake carbon processing, fit these models to data from a north-temperate lake using data assimilation, and identified which processes were essential for adequately describing the observations. The hypotheses that we tested concerned organic matter lability and its variability through time, temperature dependence of biological decay, photooxidation, microbial dynamics, and vertical transport of water via hypolimnetic entrainment and inflowing density currents. The data included epilimnetic and hypolimnetic CO2 and dissolved organic carbon, hydrologic fluxes, carbon loads, gross primary production, temperature, and light conditions at high frequency for one calibration and one validation year. The best models explained 76-81% and 64-67% of the variability in observed epilimnetic CO2 and dissolved organic carbon content in the validation data. Accurately describing C dynamics required accounting for hypolimnetic entrainment and inflowing density currents, in addition to accounting for biological transformations. In contrast, neither photooxidation nor variable organic matter lability improved model performance. The temperature dependence of biological decay (Q10) was estimated at 1.45, significantly lower than the commonly assumed Q10 of 2. By confronting multiple models of lake C dynamics with observations, we identified processes essential for describing C dynamics in a temperate lake at daily to annual scales, while also providing a methodological roadmap for using data assimilation to further improve understanding of lake C cycling.

  12. Soil moisture and soil temperature variability among three plant communities in a High Arctic Lake Basin

    NASA Astrophysics Data System (ADS)

    Davis, M. L.; Konkel, J.; Welker, J. M.; Schaeffer, S. M.

    2017-12-01

    Soil moisture and soil temperature are critical to plant community distribution and soil carbon cycle processes in High Arctic tundra. As environmental drivers of soil biochemical processes, the predictability of soil moisture and soil temperature by vegetation zone in High Arctic landscapes has significant implications for the use of satellite imagery and vegetation distribution maps to estimate of soil gas flux rates. During the 2017 growing season, we monitored soil moisture and soil temperature weekly at 48 sites in dry tundra, moist tundra, and wet grassland vegetation zones in a High Arctic lake basin. Soil temperature in all three communities reflected fluctuations in air temperature throughout the season. Mean soil temperature was highest in the dry tundra community at 10.5±0.6ºC, however, did not differ between moist tundra and wet grassland communities (2.7±0.6 and 3.1±0.5ºC, respectively). Mean volumetric soil moisture differed significantly among all three plant communities with the lowest and highest soil moisture measured in the dry tundra and wet grassland (30±1.2 and 65±2.7%), respectively. For all three communities, soil moisture was highest during the early season snow melt. Soil moisture in wet grassland remained high with no significant change throughout the season, while significant drying occurred in dry tundra. The most significant change in soil moisture was measured in moist tundra, ranging from 61 to 35%. Our results show different gradients in soil moisture variability within each plant community where: 1) soil moisture was lowest in dry tundra with little change, 2) highest in wet grassland with negligible change, and 3) variable in moist tundra which slowly dried but remained moist. Consistently high soil moisture in wet grassland restricts this plant community to areas with no significant drying during summer. The moist tundra occupies the intermediary areas between wet grassland and dry tundra and experiences the widest range of soil moisture variability. As climate projections predict wetter summers in the High Arctic, expansion of areas with seasonally inundated soils and increased soil moisture variability could result in an expansion of wet grassland and moist tundra communities with a commensurate decrease in dry tundra area.

  13. Body temperature variability (Part 2): masking influences of body temperature variability and a review of body temperature variability in disease.

    PubMed

    Kelly, Gregory S

    2007-03-01

    This is the second of a two-part review on body temperature variability. Part 1 discussed historical and modern findings on average body temperatures. It also discussed endogenous sources of temperature variability, including variations caused by site of measurement; circadian, menstrual, and annual biological rhythms; fitness; and aging. Part 2 reviews the effects of exogenous masking agents - external factors in the environment, diet, or lifestyle that can be a significant source of body temperature variability. Body temperature variability findings in disease states are also reviewed.

  14. Design of forging process variables under uncertainties

    NASA Astrophysics Data System (ADS)

    Repalle, Jalaja; Grandhi, Ramana V.

    2005-02-01

    Forging is a complex nonlinear process that is vulnerable to various manufacturing anomalies, such as variations in billet geometry, billet/die temperatures, material properties, and workpiece and forging equipment positional errors. A combination of these uncertainties could induce heavy manufacturing losses through premature die failure, final part geometric distortion, and reduced productivity. Identifying, quantifying, and controlling the uncertainties will reduce variability risk in a manufacturing environment, which will minimize the overall production cost. In this article, various uncertainties that affect the forging process are identified, and their cumulative effect on the forging tool life is evaluated. Because the forging process simulation is time-consuming, a response surface model is used to reduce computation time by establishing a relationship between the process performance and the critical process variables. A robust design methodology is developed by incorporating reliability-based optimization techniques to obtain sound forging components. A case study of an automotive-component forging-process design is presented to demonstrate the applicability of the method.

  15. 40 CFR 63.121 - Storage vessel provisions-alternative means of emission limitation.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Organic Chemical Manufacturing Industry for Process Vents, Storage Vessels, Transfer Operations, and... account for other emission variables such as temperature and barometric pressure, or (2) An engineering...

  16. 40 CFR 63.121 - Storage vessel provisions-alternative means of emission limitation.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Organic Chemical Manufacturing Industry for Process Vents, Storage Vessels, Transfer Operations, and... account for other emission variables such as temperature and barometric pressure, or (2) An engineering...

  17. 40 CFR 63.121 - Storage vessel provisions-alternative means of emission limitation.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Organic Chemical Manufacturing Industry for Process Vents, Storage Vessels, Transfer Operations, and... account for other emission variables such as temperature and barometric pressure, or (2) An engineering...

  18. 40 CFR 63.121 - Storage vessel provisions-alternative means of emission limitation.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Organic Chemical Manufacturing Industry for Process Vents, Storage Vessels, Transfer Operations, and... account for other emission variables such as temperature and barometric pressure, or (2) An engineering...

  19. 40 CFR 63.121 - Storage vessel provisions-alternative means of emission limitation.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Organic Chemical Manufacturing Industry for Process Vents, Storage Vessels, Transfer Operations, and... account for other emission variables such as temperature and barometric pressure, or (2) An engineering...

  20. Modeling of laser transmission contour welding process using FEA and DoE

    NASA Astrophysics Data System (ADS)

    Acherjee, Bappa; Kuar, Arunanshu S.; Mitra, Souren; Misra, Dipten

    2012-07-01

    In this research, a systematic investigation on laser transmission contour welding process is carried out using finite element analysis (FEA) and design of experiments (DoE) techniques. First of all, a three-dimensional thermal model is developed to simulate the laser transmission contour welding process with a moving heat source. The commercial finite element code ANSYS® multi-physics is used to obtain the numerical results by implementing a volumetric Gaussian heat source, and combined convection-radiation boundary conditions. Design of experiments together with regression analysis is then employed to plan the experiments and to develop mathematical models based on simulation results. Four key process parameters, namely power, welding speed, beam diameter, and carbon black content in absorbing polymer, are considered as independent variables, while maximum temperature at weld interface, weld width, and weld depths in transparent and absorbing polymers are considered as dependent variables. Sensitivity analysis is performed to determine how different values of an independent variable affect a particular dependent variable.

  1. Nonlinear Internal Waves on the Inner Shelf: Observations Using a Distributed Temperature Sensing (DTS) System.

    NASA Astrophysics Data System (ADS)

    Davis, K. A.; Reid, E. C.; Cohen, A. L.

    2016-02-01

    Internal waves propagating across the continental slope and shelf are transformed by the competing effects of nonlinear steepening and dispersive spreading, forming nonlinear internal waves (NLIWs) that can penetrate onto the shallow inner shelf, often appearing in the form of bottom-propagating nonlinear internal bores or boluses. NLIWs play a significant role in nearshore dynamics with baroclinic current amplitudes on the order of that of wind- and surface wave-driven flows and rapid temperature changes on the order of annual ranges. In June 2014 we used a Distributed Temperature Sensing (DTS) system to give a continuous cross-shelf view of nonlinear internal wave dynamics on the forereef of Dongsha Atoll, a coral reef in the northern South China Sea. A DTS system measures temperature continuously along the length of an optical fiber, resolving meter-to-kilometer spatial scales. This unique view of cross-shelf temperature structure made it possible to observe internal wave reflection, variable propagation speed across the shelf, bolus formation and dissipation. Additionally, we used the DTS data to track internal waves across the shallow fore reef and onto the reef flat and to quantify spatial patterns in temperature variability. Shoaling internal waves are an important process affecting physical variability and water properties on the reef.

  2. Below room temperature: How the photocatalytic activity of dense and mesoporous TiO2 coatings is affected

    NASA Astrophysics Data System (ADS)

    Cedillo-González, Erika Iveth; Riccò, Raffaele; Costacurta, Stefano; Siligardi, Cristina; Falcaro, Paolo

    2018-03-01

    Different parameters such as morphology, porosity, crystalline phase or doping agents affect the self-cleaning performance of photocatalytic TiO2-based coatings. However, also environmental conditions have been found to play a major role on the photocatalytic self-cleaning property. Substrate temperature is a significant environmental variable that can drastically affect this process. This variable becomes of great importance especially for outdoor applications: many self-cleaning photocatalytic materials have been designed to be exposed to outdoor environments and consequently, can be exposed to variable temperatures depending on the season of the year and the typical weather of the geographical zone. Thus, understanding the influence of the most common outdoor temperatures on the self-cleaning performance of TiO2-based coatings is essential for the fabrication of any kind of photocatalytic self-cleaning materials (fabricated by coating technology) that is expected to be subjected to outdoor environments. In this work, the photocatalytic activity was studied by Fourier Transformed Infrared (FTIR) Spectroscopy varying the temperature in the 0 to 30 °C range for dense and mesoporous TiO2 coatings. The temperature conditions at which these coatings present better performances were identified, providing a deeper insight for the practical application of TiO2-based self-cleaning coatings.

  3. Quantifying Tropical Glacier Mass Balance Sensitivity to Climate Change Through Regional-Scale Modeling and The Randolph Glacier Inventory

    NASA Astrophysics Data System (ADS)

    Malone, A.

    2017-12-01

    Quantifying mass balance sensitivity to climate change is essential for forecasting glacier evolution and deciphering climate signals embedded in archives of past glacier changes. Ideally, these quantifications result from decades of field measurement, remote sensing, and a hierarchy modeling approach, but in data-sparse regions, such as the Himalayas and tropical Andes, regional-scale modeling rooted in first principles provides a first-order picture. Previous regional-scaling modeling studies have applied a surface energy and mass balance approach in order to quantify equilibrium line altitude sensitivity to climate change. In this study, an expanded regional-scale surface energy and mass balance model is implemented to quantify glacier-wide mass balance sensitivity to climate change for tropical Andean glaciers. Data from the Randolph Glacier Inventory are incorporated, and additional physical processes are included, such as a dynamic albedo and cloud-dependent atmospheric emissivity. The model output agrees well with the limited mass balance records for tropical Andean glaciers. The dominant climate variables driving interannual mass balance variability differ depending on the climate setting. For wet tropical glaciers (annual precipitation >0.75 m y-1), temperature is the dominant climate variable. Different hypotheses for the processes linking wet tropical glacier mass balance variability to temperature are evaluated. The results support the hypothesis that glacier-wide mass balance on wet tropical glaciers is largely dominated by processes at the lowest elevation where temperature plays a leading role in energy exchanges. This research also highlights the transient nature of wet tropical glaciers - the vast majority of tropical glaciers and a vital regional water resource - in an anthropogenic warming world.

  4. Optimization of process variables for decolorization of Disperse Yellow 211 by Bacillus subtilis using Box-Behnken design.

    PubMed

    Sharma, Praveen; Singh, Lakhvinder; Dilbaghi, Neeraj

    2009-05-30

    Decolorization of textile azo dye Disperse Yellow 211 (DY 211) was carried out from simulated aqueous solution by bacterial strain Bacillus subtilis. Response surface methodology (RSM), involving Box-Behnken design matrix in three most important operating variables; temperature, pH and initial dye concentration was successfully employed for the study and optimization of decolorization process. The total 17 experiments were conducted in the study towards the construction of a quadratic model. According to analysis of variance (ANOVA) results, the proposed model can be used to navigate the design space. Under optimized conditions the bacterial strain was able to decolorize DY 211 up to 80%. Model indicated that initial dye concentration of 100 mgl(-1), pH 7 and a temperature of 32.5 degrees C were found optimum for maximum % decolorization. Very high regression coefficient between the variables and the response (R(2)=0.9930) indicated excellent evaluation of experimental data by polynomial regression model. The combination of the three variables predicted through RSM was confirmed through confirmatory experiments, hence the bacterial strain holds a great potential for the treatment of colored textile effluents.

  5. Global patterns in the poleward expansion of mangrove forests

    NASA Astrophysics Data System (ADS)

    Cavanaugh, K. C.; Feller, I. C.

    2016-12-01

    Understanding the processes that limit the geographic ranges of species is one of the central goals of ecology and biogeography. This issue is particularly relevant for coastal wetlands given that climate change is expected to lead to a `tropicalization' of temperate coastal and marine ecosystems. In coastal wetlands around the world, there have already been observations of mangroves expanding into salt marshes near the current poleward range limits of mangroves. However, there is still uncertainty regarding regional variability in the factors that control mangrove range limits. Here we used time series of Landsat satellite imagery to characterize patterns of mangrove abundance near their poleward range limits around the world. We tested the commonly held assumption that temporal variation in abundance should increase towards the edge of the range. We also compared variability in mangrove abundance to climate factors thought to set mangrove range limits (air temperature, water temperature, and aridity). In general, variability in mangrove abundance at range edges was high relative to range centers and this variability was correlated to one or more climate factors. However, the strength of these relationships varied among poleward range limits, suggesting that some mangrove range limits are control by processes other than climate, such as dispersal limitation.

  6. ROBUSTNESS OF A RYTHMIC CIRCUIT TO SHORT AND LONG-TERM TEMPERATURE CHANGES

    PubMed Central

    TANG, LAMONT S.; TAYLOR, ADAM L.; RINBERG, ANATOLY; MARDER, EVE

    2012-01-01

    Recent computational and experimental work has shown that similar network performance can result from variable sets of synaptic and intrinsic properties. Because temperature is a global perturbation that differentially influences every biological process within the nervous system, one might therefore expect that individual animals would respond differently to temperature. Nonetheless, the phase relationships of the pyloric rhythm of the stomatogastric ganglion (STG) of the crab, Cancer borealis, are remarkably invariant between 7 and 23 °C (Tang et al., 2010). Here, we report that when isolated STG preparations were exposed to more extreme temperature ranges, their networks became non-rhythmic, or “crashed”, in a reversible fashion. Animals were acclimated for at least 3 weeks at 7 °C, 11 °C, or 19 °C. When networks from the acclimated animals were perturbed by acute physiologically relevant temperature ramps (11–23 °C), the network frequency and phase relationships were independent of the acclimation group. At high acute temperatures (>23 °C), circuits from the cold-acclimated animals produced less-regular pyloric rhythms than those from warm-acclimated animals. At high acute temperatures, phase relationships between pyloric neurons were more variable from animal to animal than at moderate acute temperatures, suggesting that individual differences across animals in intrinsic circuit parameters are revealed at high temperatures. This shows that individual and variable neuronal circuits can behave similarly in normal conditions, but their behavior may diverge when confronted with extreme external perturbations. PMID:22815521

  7. Influence of long-range atmospheric transport pathways and climate teleconnection patterns on the variability of surface 210Pb and 7Be concentrations in southwestern Europe.

    PubMed

    Grossi, C; Ballester, J; Serrano, I; Galmarini, S; Camacho, A; Curcoll, R; Morguí, J A; Rodò, X; Duch, M A

    2016-12-01

    The variability of the atmospheric concentration of the 7 Be and 210 Pb radionuclides is strongly linked to the origin of air masses, the strength of their sources and the processes of wet and dry deposition. It has been shown how these processes and their variability are strongly affected by climate change. Thus, a deeper knowledge of the relationship between the atmospheric radionuclides variability measured close to the ground and these atmospheric processes could help in the analysis of climate scenarios. In the present study, we analyze the atmospheric variability of a 14-year time series of 7 Be and 210 Pb in a Mediterranean coastal city using a synergy of different indicators and tools such as: the local meteorological conditions, global and regional climate indexes and a lagrangian atmospheric transport model. We particularly focus on the relationships between the main pathways of air masses and sun spots occurrence, the variability of the local relative humidity and temperature conditions, and the main modes of regional climate variability, such as the North Atlantic Oscillation (NAO) and the Western Mediterranean Oscillation (WeMO). The variability of the observed atmospheric concentrations of both 7 Be and 210 Pb radionuclides was found to be mainly positively associated to the local climate conditions of temperature and to the pathways of air masses arriving at the station. Measured radionuclide concentrations significantly increase when air masses travel at low tropospheric levels from central Europe and the western part of the Iberian Peninsula, while low concentrations are associated with westerly air masses. We found a significant negative correlation between the WeMO index and the atmospheric variability of both radionuclides and no significant association was observed for the NAO index. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Controls on seasonal patterns of maximum ecosystem carbon uptake and canopy-scale photosynthetic light response: contributions from both temperature and photoperiod.

    PubMed

    Stoy, Paul C; Trowbridge, Amy M; Bauerle, William L

    2014-02-01

    Most models of photosynthetic activity assume that temperature is the dominant control over physiological processes. Recent studies have found, however, that photoperiod is a better descriptor than temperature of the seasonal variability of photosynthetic physiology at the leaf scale. Incorporating photoperiodic control into global models consequently improves their representation of the seasonality and magnitude of atmospheric CO2 concentration. The role of photoperiod versus that of temperature in controlling the seasonal variability of photosynthetic function at the canopy scale remains unexplored. We quantified the seasonal variability of ecosystem-level light response curves using nearly 400 site years of eddy covariance data from over eighty Free Fair-Use sites in the FLUXNET database. Model parameters describing maximum canopy CO2 uptake and the initial slope of the light response curve peaked after peak temperature in about 2/3 of site years examined, emphasizing the important role of temperature in controlling seasonal photosynthetic function. Akaike's Information Criterion analyses indicated that photoperiod should be included in models of seasonal parameter variability in over 90% of the site years investigated here, demonstrating that photoperiod also plays an important role in controlling seasonal photosynthetic function. We also performed a Granger causality analysis on both gross ecosystem productivity (GEP) and GEP normalized by photosynthetic photon flux density (GEP n ). While photoperiod Granger-caused GEP and GEP n in 99 and 92% of all site years, respectively, air temperature Granger-caused GEP in a mere 32% of site years but Granger-caused GEP n in 81% of all site years. Results demonstrate that incorporating photoperiod may be a logical step toward improving models of ecosystem carbon uptake, but not at the expense of including enzyme kinetic-based temperature constraints on canopy-scale photosynthesis.

  9. Development of a dynamic growth-death model for Escherichia coli O157:H7 in minimally processed leafy green vegetables.

    PubMed

    McKellar, Robin C; Delaquis, Pascal

    2011-11-15

    Escherichia coli O157:H7, an occasional contaminant of fresh produce, can present a serious health risk in minimally processed leafy green vegetables. A good predictive model is needed for Quantitative Risk Assessment (QRA) purposes, which adequately describes the growth or die-off of this pathogen under variable temperature conditions experienced during processing, storage and shipping. Literature data on behaviour of this pathogen on fresh-cut lettuce and spinach was taken from published graphs by digitization, published tables or from personal communications. A three-phase growth function was fitted to the data from 13 studies, and a square root model for growth rate (μ) as a function of temperature was derived: μ=(0.023*(Temperature-1.20))(2). Variability in the published data was incorporated into the growth model by the use of weighted regression and the 95% prediction limits. A log-linear die-off function was fitted to the data from 13 studies, and the resulting rate constants were fitted to a shifted lognormal distribution (Mean: 0.013; Standard Deviation, 0.010; Shift, 0.001). The combined growth-death model successfully predicted pathogen behaviour under both isothermal and non-isothermal conditions when compared to new published data. By incorporating variability, the resulting model is an improvement over existing ones, and is suitable for QRA applications. Crown Copyright © 2011. Published by Elsevier B.V. All rights reserved.

  10. Investigation of the Process Conditions for Hydrogen Production by Steam Reforming of Glycerol over Ni/Al2O3 Catalyst Using Response Surface Methodology (RSM)

    PubMed Central

    Ebshish, Ali; Yaakob, Zahira; Taufiq-Yap, Yun Hin; Bshish, Ahmed

    2014-01-01

    In this work; a response surface methodology (RSM) was implemented to investigate the process variables in a hydrogen production system. The effects of five independent variables; namely the temperature (X1); the flow rate (X2); the catalyst weight (X3); the catalyst loading (X4) and the glycerol-water molar ratio (X5) on the H2 yield (Y1) and the conversion of glycerol to gaseous products (Y2) were explored. Using multiple regression analysis; the experimental results of the H2 yield and the glycerol conversion to gases were fit to quadratic polynomial models. The proposed mathematical models have correlated the dependent factors well within the limits that were being examined. The best values of the process variables were a temperature of approximately 600 °C; a feed flow rate of 0.05 mL/min; a catalyst weight of 0.2 g; a catalyst loading of 20% and a glycerol-water molar ratio of approximately 12; where the H2 yield was predicted to be 57.6% and the conversion of glycerol was predicted to be 75%. To validate the proposed models; statistical analysis using a two-sample t-test was performed; and the results showed that the models could predict the responses satisfactorily within the limits of the variables that were studied. PMID:28788567

  11. Scheduling the blended solution as industrial CO2 absorber in separation process by back-propagation artificial neural networks.

    PubMed

    Abdollahi, Yadollah; Sairi, Nor Asrina; Said, Suhana Binti Mohd; Abouzari-lotf, Ebrahim; Zakaria, Azmi; Sabri, Mohd Faizul Bin Mohd; Islam, Aminul; Alias, Yatimah

    2015-11-05

    It is believe that 80% industrial of carbon dioxide can be controlled by separation and storage technologies which use the blended ionic liquids absorber. Among the blended absorbers, the mixture of water, N-methyldiethanolamine (MDEA) and guanidinium trifluoromethane sulfonate (gua) has presented the superior stripping qualities. However, the blended solution has illustrated high viscosity that affects the cost of separation process. In this work, the blended fabrication was scheduled with is the process arranging, controlling and optimizing. Therefore, the blend's components and operating temperature were modeled and optimized as input effective variables to minimize its viscosity as the final output by using back-propagation artificial neural network (ANN). The modeling was carried out by four mathematical algorithms with individual experimental design to obtain the optimum topology using root mean squared error (RMSE), R-squared (R(2)) and absolute average deviation (AAD). As a result, the final model (QP-4-8-1) with minimum RMSE and AAD as well as the highest R(2) was selected to navigate the fabrication of the blended solution. Therefore, the model was applied to obtain the optimum initial level of the input variables which were included temperature 303-323 K, x[gua], 0-0.033, x[MDAE], 0.3-0.4, and x[H2O], 0.7-1.0. Moreover, the model has obtained the relative importance ordered of the variables which included x[gua]>temperature>x[MDEA]>x[H2O]. Therefore, none of the variables was negligible in the fabrication. Furthermore, the model predicted the optimum points of the variables to minimize the viscosity which was validated by further experiments. The validated results confirmed the model schedulability. Accordingly, ANN succeeds to model the initial components of the blended solutions as absorber of CO2 capture in separation technologies that is able to industries scale up. Copyright © 2015 Elsevier B.V. All rights reserved.

  12. Kilometric Scale Modeling of the North West European Shelf Seas: Exploring the Spatial and Temporal Variability of Internal Tides

    NASA Astrophysics Data System (ADS)

    Guihou, K.; Polton, J.; Harle, J.; Wakelin, S.; O'Dea, E.; Holt, J.

    2018-01-01

    The North West European Shelf break acts as a barrier to the transport and exchange between the open ocean and the shelf seas. The strong spatial variability of these exchange processes is hard to fully explore using observations, and simulations generally are too coarse to simulate the fine-scale processes over the whole region. In this context, under the FASTNEt program, a new NEMO configuration of the North West European Shelf and Atlantic Margin at 1/60° (˜1.8 km) has been developed, with the objective to better understand and quantify the seasonal and interannual variability of shelf break processes. The capability of this configuration to reproduce the seasonal cycle in SST, the barotropic tide, and fine-resolution temperature profiles is assessed against a basin-scale (1/12°, ˜9 km) configuration and a standard regional configuration (7 km resolution). The seasonal cycle is well reproduced in all configurations though the fine-resolution allows the simulation of smaller scale processes. Time series of temperature at various locations on the shelf show the presence of internal waves with a strong spatiotemporal variability. Spectral analysis of the internal waves reveals peaks at the diurnal, semidiurnal, inertial, and quarter-diurnal bands, which are only realistically reproduced in the new configuration. Tidally induced pycnocline variability is diagnosed in the model and shown to vary with the spring neap cycle with mean displacement amplitudes in excess of 2 m for 30% of the stratified domain. With sufficiently fine resolution, internal tides are shown to be generated at numerous bathymetric features resulting in a complex pycnocline displacement superposition pattern.

  13. Towards a More Biologically-meaningful Climate Characterization: Variability in Space and Time at Multiple Scales

    NASA Astrophysics Data System (ADS)

    Christianson, D. S.; Kaufman, C. G.; Kueppers, L. M.; Harte, J.

    2013-12-01

    Sampling limitations and current modeling capacity justify the common use of mean temperature values in summaries of historical climate and future projections. However, a monthly mean temperature representing a 1-km2 area on the landscape is often unable to capture the climate complexity driving organismal and ecological processes. Estimates of variability in addition to mean values are more biologically meaningful and have been shown to improve projections of range shifts for certain species. Historical analyses of variance and extreme events at coarse spatial scales, as well as coarse-scale projections, show increasing temporal variability in temperature with warmer means. Few studies have considered how spatial variance changes with warming, and analysis for both temporal and spatial variability across scales is lacking. It is unclear how the spatial variability of fine-scale conditions relevant to plant and animal individuals may change given warmer coarse-scale mean values. A change in spatial variability will affect the availability of suitable habitat on the landscape and thus, will influence future species ranges. By characterizing variability across both temporal and spatial scales, we can account for potential bias in species range projections that use coarse climate data and enable improvements to current models. In this study, we use temperature data at multiple spatial and temporal scales to characterize spatial and temporal variability under a warmer climate, i.e., increased mean temperatures. Observational data from the Sierra Nevada (California, USA), experimental climate manipulation data from the eastern and western slopes of the Rocky Mountains (Colorado, USA), projected CMIP5 data for California (USA) and observed PRISM data (USA) allow us to compare characteristics of a mean-variance relationship across spatial scales ranging from sub-meter2 to 10,000 km2 and across temporal scales ranging from hours to decades. Preliminary spatial analysis at fine-spatial scales (sub-meter to 10-meter) shows greater temperature variability with warmer mean temperatures. This is inconsistent with the inherent assumption made in current species distribution models that fine-scale variability is static, implying that current projections of future species ranges may be biased -- the direction and magnitude requiring further study. While we focus our findings on the cross-scaling characteristics of temporal and spatial variability, we also compare the mean-variance relationship between 1) experimental climate manipulations and observed conditions and 2) temporal versus spatial variance, i.e., variability in a time-series at one location vs. variability across a landscape at a single time. The former informs the rich debate concerning the ability to experimentally mimic a warmer future. The latter informs space-for-time study design and analyses, as well as species persistence via a combined spatiotemporal probability of suitable future habitat.

  14. Estimating the urban bias of surface shelter temperatures using upper-air and satellite data. Part 1: Development of models predicting surface shelter temperatures

    NASA Technical Reports Server (NTRS)

    Epperson, David L.; Davis, Jerry M.; Bloomfield, Peter; Karl, Thomas R.; Mcnab, Alan L.; Gallo, Kevin P.

    1995-01-01

    Multiple regression techniques were used to predict surface shelter temperatures based on the time period 1986-89 using upper-air data from the European Centre for Medium-Range Weather Forecasts (ECMWF) to represent the background climate and site-specific data to represent the local landscape. Global monthly mean temperature models were developed using data from over 5000 stations available in the Global Historical Climate Network (GHCN). Monthly maximum, mean, and minimum temperature models for the United States were also developed using data from over 1000 stations available in the U.S. Cooperative (COOP) Network and comparative monthly mean temperature models were developed using over 1150 U.S. stations in the GHCN. Three-, six-, and full-variable models were developed for comparative purposes. Inferences about the variables selected for the various models were easier for the GHCN models, which displayed month-to-month consistency in which variables were selected, than for the COOP models, which were assigned a different list of variables for nearly every month. These and other results suggest that global calibration is preferred because data from the global spectrum of physical processes that control surface temperatures are incorporated in a global model. All of the models that were developed in this study validated relatively well, especially the global models. Recalibration of the models with validation data resulted in only slightly poorer regression statistics, indicating that the calibration list of variables was valid. Predictions using data from the validation dataset in the calibrated equation were better for the GHCN models, and the globally calibrated GHCN models generally provided better U.S. predictions than the U.S.-calibrated COOP models. Overall, the GHCN and COOP models explained approximately 64%-95% of the total variance of surface shelter temperatures, depending on the month and the number of model variables. In addition, root-mean-square errors (rmse's) were over 3 C for GHCN models and over 2 C for COOP models for winter months, and near 2 C for GHCN models and near 1.5 C for COOP models for summer months.

  15. An optics-based variable-temperature assay system for characterizing thermodynamics of biomolecular reactions on solid support

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fei, Yiyan; Landry, James P.; Zhu, X. D., E-mail: xdzhu@physics.ucdavis.edu

    A biological state is equilibrium of multiple concurrent biomolecular reactions. The relative importance of these reactions depends on physiological temperature typically between 10 °C and 50 °C. Experimentally the temperature dependence of binding reaction constants reveals thermodynamics and thus details of these biomolecular processes. We developed a variable-temperature opto-fluidic system for real-time measurement of multiple (400–10 000) biomolecular binding reactions on solid supports from 10 °C to 60 °C within ±0.1 °C. We illustrate the performance of this system with investigation of binding reactions of plant lectins (carbohydrate-binding proteins) with 24 synthetic glycans (i.e., carbohydrates). We found that the lectin-glycan reactions in general can be enthalpy-driven,more » entropy-driven, or both, and water molecules play critical roles in the thermodynamics of these reactions.« less

  16. An optics-based variable-temperature assay system for characterizing thermodynamics of biomolecular reactions on solid support

    NASA Astrophysics Data System (ADS)

    Fei, Yiyan; Landry, James P.; Li, Yanhong; Yu, Hai; Lau, Kam; Huang, Shengshu; Chokhawala, Harshal A.; Chen, Xi; Zhu, X. D.

    2013-11-01

    A biological state is equilibrium of multiple concurrent biomolecular reactions. The relative importance of these reactions depends on physiological temperature typically between 10 °C and 50 °C. Experimentally the temperature dependence of binding reaction constants reveals thermodynamics and thus details of these biomolecular processes. We developed a variable-temperature opto-fluidic system for real-time measurement of multiple (400-10 000) biomolecular binding reactions on solid supports from 10 °C to 60 °C within ±0.1 °C. We illustrate the performance of this system with investigation of binding reactions of plant lectins (carbohydrate-binding proteins) with 24 synthetic glycans (i.e., carbohydrates). We found that the lectin-glycan reactions in general can be enthalpy-driven, entropy-driven, or both, and water molecules play critical roles in the thermodynamics of these reactions.

  17. Integration of thermocouple microelectrode in the scanning electrochemical microscope at variable temperatures: simultaneous temperature and electrochemical imaging and its kinetic studies.

    PubMed

    Pan, He; Zhang, Hailing; Lai, Junhui; Gu, Xiaoxin; Sun, Jianjun; Tang, Jing; Jin, Tao

    2017-03-24

    We describe herein a method for the simultaneous measurement of temperature and electrochemical signal with a new type of thermocouple microelectrode. The thermocouple microelectrode can be used not only as a thermometer but also as a scanning electrochemical microscope (SECM) tip in the reaction between tip-generated bromine and a heated Cu sample. The influence of temperature on the SECM imaging process and the related kinetic parameters have been studied, such as kinetic constant and activation energy.

  18. Integration of thermocouple microelectrode in the scanning electrochemical microscope at variable temperatures: simultaneous temperature and electrochemical imaging and its kinetic studies

    PubMed Central

    Pan, He; Zhang, Hailing; Lai, Junhui; Gu, Xiaoxin; Sun, Jianjun; Tang, Jing; Jin, Tao

    2017-01-01

    We describe herein a method for the simultaneous measurement of temperature and electrochemical signal with a new type of thermocouple microelectrode. The thermocouple microelectrode can be used not only as a thermometer but also as a scanning electrochemical microscope (SECM) tip in the reaction between tip-generated bromine and a heated Cu sample. The influence of temperature on the SECM imaging process and the related kinetic parameters have been studied, such as kinetic constant and activation energy. PMID:28338002

  19. Predictive models of lyophilization process for development, scale-up/tech transfer and manufacturing.

    PubMed

    Zhu, Tong; Moussa, Ehab M; Witting, Madeleine; Zhou, Deliang; Sinha, Kushal; Hirth, Mario; Gastens, Martin; Shang, Sherwin; Nere, Nandkishor; Somashekar, Shubha Chetan; Alexeenko, Alina; Jameel, Feroz

    2018-07-01

    Scale-up and technology transfer of lyophilization processes remains a challenge that requires thorough characterization of the laboratory and larger scale lyophilizers. In this study, computational fluid dynamics (CFD) was employed to develop computer-based models of both laboratory and manufacturing scale lyophilizers in order to understand the differences in equipment performance arising from distinct designs. CFD coupled with steady state heat and mass transfer modeling of the vial were then utilized to study and predict independent variables such as shelf temperature and chamber pressure, and response variables such as product resistance, product temperature and primary drying time for a given formulation. The models were then verified experimentally for the different lyophilizers. Additionally, the models were applied to create and evaluate a design space for a lyophilized product in order to provide justification for the flexibility to operate within a certain range of process parameters without the need for validation. Published by Elsevier B.V.

  20. Properties of Rolled AZ31 Magnesium Alloy Sheet Fabricated by Continuous Variable Cross-Section Direct Extrusion

    NASA Astrophysics Data System (ADS)

    Liu, Yang; Li, Feng; Li, Xue Wen; Shi, Wen Yong

    2018-03-01

    Rolling is currently a widely used method for manufacturing and processing high-performance magnesium alloy sheets and has received widespread attention in recent years. Here, we combined continuous variable cross-section direct extrusion (CVCDE) and rolling processes. The microstructure and mechanical properties of the resulting sheets rolled at different temperatures from CVCDE extrudate were investigated by optical microscopy, scanning electron microscope, transmission electron microscopy and electron backscatter diffraction. The results showed that a fine-grained microstructure was present with an average grain size of 3.62 μm in sheets rolled from CVCDE extrudate at 623 K. Dynamic recrystallization and a large strain were induced by the multi-pass rolling, which resulted in grain refinement. In the 573-673 K range, the yield strength, tensile strength and elongation initially increased and then declined as the CVCDE temperature increased. The above results provide an important scientific basis of processing, manufacturing and the active control on microstructure and property for high-performance magnesium alloy sheet.

  1. Critical shear stress for erosion of cohesive soils subjected to temperatures typical of wildfires

    USGS Publications Warehouse

    Moody, J.A.; Dungan, Smith J.; Ragan, B.W.

    2005-01-01

    [1] Increased erosion is a well-known response after wildfire. To predict and to model erosion on a landscape scale requires knowledge of the critical shear stress for the initiation of motion of soil particles. As this soil property is temperature-dependent, a quantitative relation between critical shear stress and the temperatures to which the soils have been subjected during a wildfire is required. In this study the critical shear stress was measured in a recirculating flume using samples of forest soil exposed to different temperatures (40??-550??C) for 1 hour. Results were obtained for four replicates of soils derived from three different types of parent material (granitic bedrock, sandstone, and volcanic tuffs). In general, the relation between critical shear stress and temperature can be separated into three different temperature ranges (275??C), which are similar to those for water repellency and temperature. The critical shear stress was most variable (1.0-2.0 N m-2) for temperatures 2.0 N m-2) between 175?? and 275??C, and was essentially constant (0.5-0.8 N m-2) for temperatures >275??C. The changes in critical shear stress with temperature were found to be essentially independent of soil type and suggest that erosion processes in burned watersheds can be modeled more simply than erosion processes in unburned watersheds. Wildfire reduces the spatial variability of soil erodibility associated with unburned watersheds by eliminating the complex effects of vegetation in protecting soils and by reducing the range of cohesion associated with different types of unburned soils. Our results indicate that modeling the erosional response after a wildfire depends primarily on determining the spatial distribution of the maximum soil temperatures that were reached during the wildfire. Copyright 2005 by the American Geophysical Union.

  2. Using a 3D profiler and infrared camera to monitor oven loading in fully cooked meat operations

    NASA Astrophysics Data System (ADS)

    Stewart, John; Giorges, Aklilu

    2009-05-01

    Ensuring meat is fully cooked is an important food safety issue for operations that produce "ready to eat" products. In order to kill harmful pathogens like Salmonella, all of the product must reach a minimum threshold temperature. Producers typically overcook the majority of the product to ensure meat in the most difficult scenario reaches the desired temperature. A difficult scenario can be caused by an especially thick piece of meat or by a surge of product into the process. Overcooking wastes energy, degrades product quality, lowers the maximum throughput rate of the production line and decreases product yield. At typical production rates of 6000lbs/hour, these losses from overcooking can have a significant cost impact on producers. A wide area 3D camera coupled with a thermal camera was used to measure the thermal mass variability of chicken breasts in a cooking process. Several types of variability are considered including time varying thermal mass (mass x temperature / time), variation in individual product geometry and variation in product temperature. The automatic identification of product arrangement issues that affect cooking such as overlapping product and folded products is also addressed. A thermal model is used along with individual product geometry and oven cook profiles to predict the percentage of product that will be overcooked and to identify products that may not fully cook in a given process.

  3. Finite Element Simulation of Temperature and Strain Distribution during Friction Stir Welding of AA2024 Aluminum Alloy

    NASA Astrophysics Data System (ADS)

    Jain, Rahul; Pal, Surjya Kanta; Singh, Shiv Brat

    2017-02-01

    Friction Stir Welding (FSW) is a solid state joining process and is handy for welding aluminum alloys. Finite Element Method (FEM) is an important tool to predict state variables of the process but numerical simulation of FSW is highly complex due to non-linear contact interactions between tool and work piece and interdependency of displacement and temperature. In the present work, a three dimensional coupled thermo-mechanical method based on Lagrangian implicit method is proposed to study the thermal history, strain distribution and thermo-mechanical process in butt welding of Aluminum alloy 2024 using DEFORM-3D software. Workpiece is defined as rigid-visco plastic material and sticking condition between tool and work piece is defined. Adaptive re-meshing is used to tackle high mesh distortion. Effect of tool rotational and welding speed on plastic strain is studied and insight is given on asymmetric nature of FSW process. Temperature distribution on the workpiece and tool is predicted and maximum temperature is found in workpiece top surface.

  4. Finding Relevant Parameters for the Thin-film Photovoltaic Cells Production Process with the Application of Data Mining Methods.

    PubMed

    Ulaczyk, Jan; Morawiec, Krzysztof; Zabierowski, Paweł; Drobiazg, Tomasz; Barreau, Nicolas

    2017-09-01

    A data mining approach is proposed as a useful tool for the control parameters analysis of the 3-stage CIGSe photovoltaic cell production process, in order to find variables that are the most relevant for cell electric parameters and efficiency. The analysed data set consists of stage duration times, heater power values as well as temperatures for the element sources and the substrate - there are 14 variables per sample in total. The most relevant variables of the process have been found based on the so-called random forest analysis with the application of the Boruta algorithm. 118 CIGSe samples, prepared at Institut des Matériaux Jean Rouxel, were analysed. The results are close to experimental knowledge on the CIGSe cells production process. They bring new evidence to production parameters of new cells and further research. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Tannase production by Paecilomyces variotii.

    PubMed

    Battestin, Vania; Macedo, Gabriela Alves

    2007-07-01

    Surface response methodology was applied to the optimization of the laboratory scale production of tannase using a lineage of Paecilomyces variotii. A preliminary study was conducted to evaluate the effects of variables, including temperature ( degrees C), residue (%) (coffee husk:wheat bran), tannic acid (%) and salt solutions (%) on the production of tannase during 3, 5 and 7 days of fermentation. Among these variables, temperature, residues and tannic acid had significant effects on tannase production. The variables were optimized using surface response methodology. The best conditions for tannase production were: temperature (29-34 degrees C); tannic acid (8.5-14%); % residue (coffee husk:wheat bran 50:50) and incubation time of 5 days. The supplementation of external nitrogen and carbon sources at 0.4%, 0.8% and 1.2% concentration on tannase production were studied in the optimized medium. Three different nitrogen sources included yeast extract, ammonia nitrate and sodium nitrate along with carbon source (starch) were studied. Only ammonia nitrate showed a significant effect on tannase production. After the optimization process, the tannase activity increased 8.6-fold.

  6. ATAD control goals through the analysis of process variables and evaluation of quality, production and cost.

    PubMed

    Nájera, S; Gil-Martínez, M; Zambrano, J A

    2015-01-01

    The aim of this paper is to establish and quantify different operational goals and control strategies in autothermal thermophilic aerobic digestion (ATAD). This technology appears as an alternative to conventional sludge digestion systems. During the batch-mode reaction, high temperatures promote sludge stabilization and pasteurization. The digester temperature is usually the only online, robust, measurable variable. The average temperature can be regulated by manipulating both the air injection and the sludge retention time. An improved performance of diverse biochemical variables can be achieved through proper manipulation of these inputs. However, a better quality of treated sludge usually implies major operating costs or a lower production rate. Thus, quality, production and cost indices are defined to quantify the outcomes of the treatment. Based on these, tradeoff control strategies are proposed and illustrated through some examples. This paper's results are relevant to guide plant operators, to design automatic control systems and to compare or evaluate the control performance on ATAD systems.

  7. Soft-sensing model of temperature for aluminum reduction cell on improved twin support vector regression

    NASA Astrophysics Data System (ADS)

    Li, Tao

    2018-06-01

    The complexity of aluminum electrolysis process leads the temperature for aluminum reduction cells hard to measure directly. However, temperature is the control center of aluminum production. To solve this problem, combining some aluminum plant's practice data, this paper presents a Soft-sensing model of temperature for aluminum electrolysis process on Improved Twin Support Vector Regression (ITSVR). ITSVR eliminates the slow learning speed of Support Vector Regression (SVR) and the over-fit risk of Twin Support Vector Regression (TSVR) by introducing a regularization term into the objective function of TSVR, which ensures the structural risk minimization principle and lower computational complexity. Finally, the model with some other parameters as auxiliary variable, predicts the temperature by ITSVR. The simulation result shows Soft-sensing model based on ITSVR has short time-consuming and better generalization.

  8. Potential solar radiation and land cover contributions to digital climate surface modeling

    NASA Astrophysics Data System (ADS)

    Puig, Pol; Batalla, Meritxell; Pesquer, Lluís; Ninyerola, Miquel

    2016-04-01

    Overview: We have designed a series of ad-hoc experiments to study the role of factors that a priori have a strong weight in developing digital models of temperature and precipitation, such as solar radiation and land cover. Empirical test beds have been designed to improve climate (mean air temperature and total precipitation) digital models using statistical general techniques (multiple regression) with residual correction (interpolated with inverse weighting distance). Aim: Understand what roles these two factors (solar radiation and land cover) play to incorporate them into the process of generating mapping of temperature and rainfall. Study area: The Iberian Peninsula and supported in this, Catalonia and the Catalan Pyrenees. Data: The dependent variables used in all experiments relate to data from meteorological stations precipitation (PL), mean temperature (MT), average temperature minimum (MN) and maximum average temperature (MX). These data were obtained monthly from the AEMET (Agencia Estatal de Meteorología). Data series of stations covers the period between 1950 to 2010. Methodology: The idea is to design ad hoc, based on a sample of more equitable space statistician, to detect the role of radiation. Based on the influence of solar radiation on the temperature of the air from a quantitative point of view, the difficulty in answering this lies in the fact that there are lots of weather stations located in areas where solar radiation is similar. This suggests that the role of the radiation variable remains "off" when, instead, we intuitively think that would strongly influence the temperature. We have developed a multiple regression analysis between these meteorological variables as the dependent ones (Temperature and rainfall), and some geographical variables: altitude (ALT), latitude (LAT), continentality (CON) and solar radiation (RAD) as the independent ones. In case of the experiment with land covers, we have used the NDVI index as a proxy of land covers and added this variable in to the independents to improve the models. Results: The role of solar radiation does not improve models only under certain conditions and areas, especially in the Pyrennes. The vegetation index NDVI and therefore the land cover on which the station is located, helps improve rainfall and temperature patterns, obtaining various degrees of improvement in terms of molded variables and months.

  9. Impact of Subsurface Temperature Variability on Meteorological Variability: An AGCM Study

    NASA Astrophysics Data System (ADS)

    Mahanama, S. P.; Koster, R. D.; Liu, P.

    2006-05-01

    Anomalous atmospheric conditions can lead to surface temperature anomalies, which in turn can lead to temperature anomalies deep in the soil. The deep soil temperature (and the associated ground heat content) has significant memory -- the dissipation of a temperature anomaly may take weeks to months -- and thus deep soil temperature may contribute to the low frequency variability of energy and water variables elsewhere in the system. The memory may even provide some skill to subseasonal and seasonal forecasts. This study uses two long-term AGCM experiments to isolate the contribution of deep soil temperature variability to variability elsewhere in the climate system. The first experiment consists of a standard ensemble of AMIP-type simulations, simulations in which the deep soil temperature variable is allowed to interact with the rest of the system. In the second experiment, the coupling of the deep soil temperature to the rest of the climate system is disabled -- at each grid cell, the local climatological seasonal cycle of deep soil temperature (as determined from the first experiment) is prescribed. By comparing the variability of various atmospheric quantities as generated in the two experiments, we isolate the contribution of interactive deep soil temperature to that variability. The results show that interactive deep soil temperature contributes significantly to surface temperature variability. Interactive deep soil temperature, however, reduces the variability of the hydrological cycle (evaporation and precipitation), largely because it allows for a negative feedback between evaporation and temperature.

  10. Elevated temperature deformation of thoria dispersed nickel-chromium

    NASA Technical Reports Server (NTRS)

    Kane, R. D.; Ebert, L. J.

    1974-01-01

    The deformation behavior of thoria nickel-chromium (TD-NiCr) was examined over the temperature range 593 C (1100 F) to 1260 C (2300 F) in tension and compression and at 1093 C (2000 F) in creep. Major emphasis was placed on: (1) the effects of the material and test related variables (grain size, temperature, stress and strain rate) on the deformation process; and (2) the evaluation of single crystal TD-NiCr material produced by a directional recrystallization process. Elevated temperature yield strength levels and creep activation enthalpies were found to increase with increasing grain size reaching maximum values for the single crystal TD-NiCr. Stress exponent of the steady state creep rate was also significantly higher for the single crystal TD-NiCr as compared to that determined for the polycrystalline materials. The elevated temperature deformation of TD-NiCr was analyzed in terms of two concurrent, parallel processes: diffusion controlled grain boundary sliding, and dislocation motion.

  11. Key process parameters to modify the porosity of cerium dioxide microspheres formed in the internal gelation process

    DOE PAGES

    Hunt, Rodney Dale; Collins, Jack Lee; Reif, Tyler J.; ...

    2017-08-04

    Recently, an internal gelation study demonstrated that the use of heated urea and hexamethylenetetramine can have a pronounced impact on the porosity and sintering characteristics of cerium dioxide (CeO 2) microspheres. This effort has identified process variables that can significantly change the initial porosity of the CeO 2 microspheres with slight modifications. A relatively small difference in the sample preparation of cerium ammonium nitrate and ammonium hydroxide solution had a large reproducible impact on the porosity and slow pour density of the produced microspheres. Increases in the gelation temperature as small as 0.5 K also produced a noticeable increase inmore » the slow pour density. If the gelation temperature was increased too high, the use of the heated hexamethylenetetramine and urea was no longer observed to be effective in increasing the porosity of the CeO 2 microspheres. In conclusion, the final process variable was the amount of dispersing agent, Span™ 80, which can increase the slow pour density and produce significantly smaller microspheres.« less

  12. Key process parameters to modify the porosity of cerium dioxide microspheres formed in the internal gelation process

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hunt, Rodney Dale; Collins, Jack Lee; Reif, Tyler J.

    Recently, an internal gelation study demonstrated that the use of heated urea and hexamethylenetetramine can have a pronounced impact on the porosity and sintering characteristics of cerium dioxide (CeO 2) microspheres. This effort has identified process variables that can significantly change the initial porosity of the CeO 2 microspheres with slight modifications. A relatively small difference in the sample preparation of cerium ammonium nitrate and ammonium hydroxide solution had a large reproducible impact on the porosity and slow pour density of the produced microspheres. Increases in the gelation temperature as small as 0.5 K also produced a noticeable increase inmore » the slow pour density. If the gelation temperature was increased too high, the use of the heated hexamethylenetetramine and urea was no longer observed to be effective in increasing the porosity of the CeO 2 microspheres. In conclusion, the final process variable was the amount of dispersing agent, Span™ 80, which can increase the slow pour density and produce significantly smaller microspheres.« less

  13. Modeling temperature variations in a pilot plant thermophilic anaerobic digester.

    PubMed

    Valle-Guadarrama, Salvador; Espinosa-Solares, Teodoro; López-Cruz, Irineo L; Domaschko, Max

    2011-05-01

    A model that predicts temperature changes in a pilot plant thermophilic anaerobic digester was developed based on fundamental thermodynamic laws. The methodology utilized two simulation strategies. In the first, model equations were solved through a searching routine based on a minimal square optimization criterion, from which the overall heat transfer coefficient values, for both biodigester and heat exchanger, were determined. In the second, the simulation was performed with variable values of these overall coefficients. The prediction with both strategies allowed reproducing experimental data within 5% of the temperature span permitted in the equipment by the system control, which validated the model. The temperature variation was affected by the heterogeneity of the feeding and extraction processes, by the heterogeneity of the digestate recirculation through the heating system and by the lack of a perfect mixing inside the biodigester tank. The use of variable overall heat transfer coefficients improved the temperature change prediction and reduced the effect of a non-ideal performance of the pilot plant modeled.

  14. Contribution of Modis Satellite Image to Estimate the Daily Air Temperature in the Casablanca City, Morocco

    NASA Astrophysics Data System (ADS)

    Bahi, Hicham; Rhinane, Hassan; Bensalmia, Ahmed

    2016-10-01

    Air temperature is considered to be an essential variable for the study and analysis of meteorological regimes and chronics. However, the implementation of a daily monitoring of this variable is very difficult to achieve. It requires sufficient of measurements stations density, meteorological parks and favourable logistics. The present work aims to establish relationship between day and night land surface temperatures from MODIS data and the daily measurements of air temperature acquired between [2011-20112] and provided by the Department of National Meteorology [DMN] of Casablanca, Morocco. The results of the statistical analysis show significant interdependence during night observations with correlation coefficient of R2=0.921 and Root Mean Square Error RMSE=1.503 for Tmin while the physical magnitude estimated from daytime MODIS observation shows a relatively coarse error with R2=0.775 and RMSE=2.037 for Tmax. A method based on Gaussian process regression was applied to compute the spatial distribution of air temperature from MODIS throughout the city of Casablanca.

  15. Effect of thermal and mechanical parameter’s damage numerical simulation cycling effects on defects in hot metal forming processes

    NASA Astrophysics Data System (ADS)

    El Amri, Abdelouahid; el yakhloufi Haddou, Mounir; Khamlichi, Abdellatif

    2017-10-01

    Damage mechanisms in hot metal forming processes are accelerated by mechanical stresses arising during Thermal and mechanical properties variations, because it consists of the materials with different thermal and mechanical loadings and swelling coefficients. In this work, 3D finite element models (FEM) are developed to simulate the effect of Temperature and the stresses on the model development, using a general purpose FE software ABAQUS. Explicit dynamic analysis with coupled Temperature displacement procedure is used for a model. The purpose of this research was to study the thermomechanical damage mechanics in hot forming processes. The important process variables and the main characteristics of various hot forming processes will also be discussed.

  16. Studies of Hot Photoluminescence in Plasmonically Coupled Silicon via Variable Energy Excitation and Temperature-Dependent Spectroscopy

    PubMed Central

    2015-01-01

    By integrating silicon nanowires (∼150 nm diameter, 20 μm length) with an Ω-shaped plasmonic nanocavity, we are able to generate broadband visible luminescence, which is induced by high order hybrid nanocavity-surface plasmon modes. The nature of this super bandgap emission is explored via photoluminescence spectroscopy studies performed with variable laser excitation energies (1.959 to 2.708 eV) and finite difference time domain simulations. Furthermore, temperature-dependent photoluminescence spectroscopy shows that the observed emission corresponds to radiative recombination of unthermalized (hot) carriers as opposed to a resonant Raman process. PMID:25120156

  17. A longitudinal study of mortality and air pollution for São Paulo, Brazil.

    PubMed

    Botter, Denise A; Jørgensen, Bent; Peres, Antonieta A Q

    2002-09-01

    We study the effects of various air-pollution variables on the daily death counts for people over 65 years in São Paulo, Brazil, from 1991 to 1993, controlling for meteorological variables. We use a state space model where the air-pollution variables enter via the latent process, and the meteorological variables via the observation equation. The latent process represents the potential mortality due to air pollution, and is estimated by Kalman filter techniques. The effect of air pollution on mortality is found to be a function of the variation in the sulphur dioxide level for the previous 3 days, whereas the other air-pollution variables (total suspended particulates, nitrogen dioxide, carbon monoxide, ozone) are not significant when sulphur dioxide is in the equation. There are significant effects of humidity and up to lag 3 of temperature, and a significant seasonal variation.

  18. [Optimization of Formulation and Process of Paclitaxel PEGylated Liposomes by Box-Behnken Response Surface Methodology].

    PubMed

    Shi, Ya-jun; Zhang, Xiao-feil; Guo, Qiu-ting

    2015-12-01

    To develop a procedure for preparing paclitaxel encapsulated PEGylated liposomes. The membrane hydration followed extraction method was used to prepare PEGylated liposomes. The process and formulation variables were optimized by "Box-Behnken Design (BBD)" of response surface methodology (RSM) with the amount of Soya phosphotidylcholine (SPC) and PEG2000-DSPE as well as the rate of SPC to drug as independent variables and entrapment efficiency as dependent variables for optimization of formulation variables while temperature, pressure and cycle times as independent variables and particle size and polydispersion index as dependent variables for process variables. The optimized liposomal formulation was characterized for particle size, Zeta potential, morphology and in vitro drug release. For entrapment efficiency, particle size, polydispersion index, Zeta potential, and in vitro drug release of PEGylated liposomes was found to be 80.3%, (97.15 ± 14.9) nm, 0.117 ± 0.019, (-30.3 ± 3.7) mV, and 37.4% in 24 h, respectively. The liposomes were found to be small, unilamellar and spherical with smooth surface as seen in transmission electron microscopy. The Box-Behnken response surface methodology facilitates the formulation and optimization of paclitaxel PEGylated liposomes.

  19. Coupling of snow and permafrost processes using the Basic Modeling Interface (BMI)

    NASA Astrophysics Data System (ADS)

    Wang, K.; Overeem, I.; Jafarov, E. E.; Piper, M.; Stewart, S.; Clow, G. D.; Schaefer, K. M.

    2017-12-01

    We developed a permafrost modeling tool based by implementing the Kudryavtsev empirical permafrost active layer depth model (the so-called "Ku" component). The model is specifically set up to have a basic model interface (BMI), which enhances the potential coupling to other earth surface processes model components. This model is accessible through the Web Modeling Tool in Community Surface Dynamics Modeling System (CSDMS). The Kudryavtsev model has been applied for entire Alaska to model permafrost distribution at high spatial resolution and model predictions have been verified by Circumpolar Active Layer Monitoring (CALM) in-situ observations. The Ku component uses monthly meteorological forcing, including air temperature, snow depth, and snow density, and predicts active layer thickness (ALT) and temperature on the top of permafrost (TTOP), which are important factors in snow-hydrological processes. BMI provides an easy approach to couple the models with each other. Here, we provide a case of coupling the Ku component to snow process components, including the Snow-Degree-Day (SDD) method and Snow-Energy-Balance (SEB) method, which are existing components in the hydrological model TOPOFLOW. The work flow is (1) get variables from meteorology component, set the values to snow process component, and advance the snow process component, (2) get variables from meteorology and snow component, provide these to the Ku component and advance, (3) get variables from snow process component, set the values to meteorology component, and advance the meteorology component. The next phase is to couple the permafrost component with fully BMI-compliant TOPOFLOW hydrological model, which could provide a useful tool to investigate the permafrost hydrological effect.

  20. The mortality burden of hourly temperature variability in five capital cities, Australia: Time-series and meta-regression analysis.

    PubMed

    Cheng, Jian; Xu, Zhiwei; Bambrick, Hilary; Su, Hong; Tong, Shilu; Hu, Wenbiao

    2017-12-01

    Unstable weather, such as intra- and inter-day temperature variability, can impair the health and shorten the survival time of population around the world. Climate change will cause Earth's surface temperature rise, but has unclear effects on temperature variability, making it urgent to understand the characteristics of the burden of temperature variability on mortality, regionally and nationally. This paper aims to quantify the mortality risk of exposure to short-term temperature variability, estimate the resulting death toll and explore how the strength of temperature variability effects will vary as a function of city-level characteristics. Ten-year (2000-2009) time-series data on temperature and mortality were collected for five largest Australia's cities (Sydney, Melbourne, Brisbane, Perth and Adelaide), collectively registering 708,751 deaths in different climates. Short-term temperature variability was captured and represented as the hourly temperature standard deviation within two days. Three-stage analyses were used to assess the burden of temperature variability on mortality. First, we modelled temperature variability-mortality relation and estimated the relative risk of death for each city, using a time-series quasi-Poisson regression model. Second, we used meta-analysis to pool the city-specific estimates, and meta-regression to explore if some city-level factors will modify the population vulnerability to temperature variability. Finally, we calculated the city-specific deaths attributable to temperature variability, and applied such estimates to the whole of Australia as a reflection of the nation-wide death burden associated with temperature variability. We found evidence of significant associations between temperature variability and mortality in all cities assessed. Deaths associated with each 1°C rise in temperature variability elevated by 0.28% (95% confidence interval (CI): 0.05%, 0.52%) in Melbourne to 1.00% (95%CI: 0.52%, 1.48%) in Brisbane, with a pooled estimate of 0.51% (95%CI: 0.33%, 0.69%) for Australia. Subtropical and temperate regions showed no apparent difference in temperature variability impacts. Meta-regression analyses indicated that the mortality risk could be influenced by city-specific factors: latitude, mean temperature, population density and the prevalence of several chronic diseases. Taking account of contributions from the entire time-series, temperature variability was estimated to account for 0.99% to 3.24% of deaths across cities, with a nation-wide attributable fraction of 1.67% (9.59 deaths per 100, 000 population per year). Hourly temperature variability may be an important risk factor of weather-related deaths and led to a sizeable mortality burden. This study underscores the need for developing specific and effective interventions in Australia to lessen the health consequences of temperature variability. Copyright © 2017. Published by Elsevier Ltd.

  1. Effect of electron-beam deposition process variables on the film characteristics of the CrOx films

    NASA Astrophysics Data System (ADS)

    Chiu, Po-kai; Liao, Yi-Ting; Tsai, Hung-Yin; Chiang, Donyau

    2018-02-01

    The film characteristics and optical properties of the chromium oxide films on the glass substrates prepared by electron-beam deposition with different process variables were investigated. The process variables included are the various oxygen flow rates, the different applied substrate temperatures, and the preparation process in Ar or O2 surrounding environment with and without ion-assisted deposition. The optical constants of the deposited films are determined from the reflectance and transmittance measurements obtained using a spectrophotometer with wavelengths ranging from 350 nm to 2000 nm. The microstructures of the films were examined by the XRD, SEM, and XPS. The electrical conductivity was measured by a four-point probe instrument. The resulting microstructures of all the prepared films are amorphous and the features of the films are dense, uniform and no pillar structure is observed. The refractive index of deposited films decrease with oxygen flow rate increase within studied wavelengths and the extinction coefficients have the same trend in wavelengths of UV/Vis ranges. Increasing substrate temperature to 200 oC results in increase of both refractive index and extinction coefficient, but substrate temperatures below 150 oC show negligible effect on optical constants. The optical and electrical properties in the prepared CrOx films are illustrated by the analyzed XPS results, which decompose the enveloped curve of chromium electron energy status into the constituents of metal Cr, oxides CrO2 and Cr2O3. The relative occupied area contributed from metal Cr and area contributed from the other oxides can express the concentration ratio of free electron to covalent bonds in deposited films and the ratio is applied to explain the film characteristics, including the optical constants and sheet resistance.

  2. Neighbouring populations, opposite dynamics: influence of body size and environmental variation on the demography of stream-resident brown trout (Salmo trutta).

    PubMed

    Fernández-Chacón, Albert; Genovart, Meritxell; Álvarez, David; Cano, José M; Ojanguren, Alfredo F; Rodriguez-Muñoz, Rolando; Nicieza, Alfredo G

    2015-06-01

    In organisms such as fish, where body size is considered an important state variable for the study of their population dynamics, size-specific growth and survival rates can be influenced by local variation in both biotic and abiotic factors, but few studies have evaluated the complex relationships between environmental variability and size-dependent processes. We analysed a 6-year capture-recapture dataset of brown trout (Salmo trutta) collected at 3 neighbouring but heterogeneous mountain streams in northern Spain with the aim of investigating the factors shaping the dynamics of local populations. The influence of body size and water temperature on survival and individual growth was assessed under a multi-state modelling framework, an extension of classical capture-recapture models that considers the state (i.e. body size) of the individual in each capture occasion and allows us to obtain state-specific demographic rates and link them to continuous environmental variables. Individual survival and growth patterns varied over space and time, and evidence of size-dependent survival was found in all but the smallest stream. At this stream, the probability of reaching larger sizes was lower compared to the other wider and deeper streams. Water temperature variables performed better in the modelling of the highest-altitude population, explaining over a 99 % of the variability in maturation transitions and survival of large fish. The relationships between body size, temperature and fitness components found in this study highlight the utility of multi-state approaches to investigate small-scale demographic processes in heterogeneous environments, and to provide reliable ecological knowledge for management purposes.

  3. Enhancing Degradation of Low Density Polyethylene Films by Curvularia lunata SG1 Using Particle Swarm Optimization Strategy.

    PubMed

    Raut, Sangeeta; Raut, Smita; Sharma, Manisha; Srivastav, Chaitanya; Adhikari, Basudam; Sen, Sudip Kumar

    2015-09-01

    In the present study, artificial neural network (ANN) modelling coupled with particle swarm optimization (PSO) algorithm was used to optimize the process variables for enhanced low density polyethylene (LDPE) degradation by Curvularia lunata SG1. In the non-linear ANN model, temperature, pH, contact time and agitation were used as input variables and polyethylene bio-degradation as the output variable. Further, on application of PSO to the ANN model, the optimum values of the process parameters were as follows: pH = 7.6, temperature = 37.97 °C, agitation rate = 190.48 rpm and incubation time = 261.95 days. A comparison between the model results and experimental data gave a high correlation coefficient ([Formula: see text]). Significant enhancement of LDPE bio-degradation using C. lunata SG1by about 48 % was achieved under optimum conditions. Thus, the novelty of the work lies in the application of combination of ANN-PSO as optimization strategy to enhance the bio-degradation of LDPE.

  4. Variable-Range Hopping through Marginally Localized Phonons

    NASA Astrophysics Data System (ADS)

    Banerjee, Sumilan; Altman, Ehud

    2016-03-01

    We investigate the effect of coupling Anderson localized particles in one dimension to a system of marginally localized phonons having a symmetry protected delocalized mode at zero frequency. This situation is naturally realized for electrons coupled to phonons in a disordered nanowire as well as for ultracold fermions coupled to phonons of a superfluid in a one-dimensional disordered trap. To determine if the coupled system can be many-body localized we analyze the phonon-mediated hopping transport for both the weak and strong coupling regimes. We show that the usual variable-range hopping mechanism involving a low-order phonon process is ineffective at low temperature due to discreteness of the bath at the required energy. Instead, the system thermalizes through a many-body process involving exchange of a diverging number n ∝-log T of phonons in the low temperature limit. This effect leads to a highly singular prefactor to Mott's well-known formula and strongly suppresses the variable range hopping rate. Finally, we comment on possible implications of this physics in higher dimensional electron-phonon coupled systems.

  5. Mechanisms Controlling Global Mean Sea Surface Temperature Determined From a State Estimate

    NASA Astrophysics Data System (ADS)

    Ponte, R. M.; Piecuch, C. G.

    2018-04-01

    Global mean sea surface temperature (T¯) is a variable of primary interest in studies of climate variability and change. The temporal evolution of T¯ can be influenced by surface heat fluxes (F¯) and by diffusion (D¯) and advection (A¯) processes internal to the ocean, but quantifying the contribution of these different factors from data alone is prone to substantial uncertainties. Here we derive a closed T¯ budget for the period 1993-2015 based on a global ocean state estimate, which is an exact solution of a general circulation model constrained to most extant ocean observations through advanced optimization methods. The estimated average temperature of the top (10-m thick) level in the model, taken to represent T¯, shows relatively small variability at most time scales compared to F¯, D¯, or A¯, reflecting the tendency for largely balancing effects from all the latter terms. The seasonal cycle in T¯ is mostly determined by small imbalances between F¯ and D¯, with negligible contributions from A¯. While D¯ seems to simply damp F¯ at the annual period, a different dynamical role for D¯ at semiannual period is suggested by it being larger than F¯. At periods longer than annual, A¯ contributes importantly to T¯ variability, pointing to the direct influence of the variable ocean circulation on T¯ and mean surface climate.

  6. Multiproxy evidence of Holocene climate variability from estuarine sediments, eastern North America

    USGS Publications Warehouse

    Cronin, T. M.; Thunell, R.; Dwyer, G.S.; Saenger, C.; Mann, M.E.; Vann, C.; Seal, R.R.

    2005-01-01

    We reconstructed paleoclimate patterns from oxygen and carbon isotope records from the fossil estuarine benthic foraminifera Elphidium and Mg/ Ca ratios from the ostracode Loxoconcha from sediment cores from Chesapeake Bay to examine the Holocene evolution of North Atlantic Oscillation (NAO)-type climate variability. Precipitation-driven river discharge and regional temperature variability are the primary influences on Chesapeake Bay salinity and water temperature, respectively. We first calibrated modern ??18 Owater to salinity and applied this relationship to calculate trends in paleosalinity from the ??18 Oforam, correcting for changes in water temperature estimated from ostracode Mg /Ca ratios. The results indicate a much drier early Holocene in which mean paleosalinity was ???28 ppt in the northern bay, falling ???25% to ???20 ppt during the late Holocene. Early Holocene Mg/Ca-derived temperatures varied in a relatively narrow range of 13?? to 16??C with a mean temperature of 14.2??C and excursions above 16??C; the late Holocene was on average cooler (mean temperature of 12.8??C). In addition to the large contrast between early and late Holocene regional climate conditions, multidecadal (20-40 years) salinity and temperature variability is an inherent part of the region's climate during both the early and late Holocene, including the Medieval Warm Period and Little Ice Age. These patterns are similar to those observed during the twentieth century caused by NAO-related processes. Comparison of the midlatitude Chesapeake Bay salinity record with tropical climate records of Intertropical Convergence Zone fluctuations inferred from the Cariaco Basin titanium record suggests an anticorrelation between precipitation in the two regions at both millennial and centennial timescales. Copyright 2005 by the American Geophysical Union.

  7. Characterization of the Temperature Capabilities of Advanced Disk Alloy ME3

    NASA Technical Reports Server (NTRS)

    Gabb, Timothy P.; Telesman, Jack; Kantzos, Peter T.; OConnor, Kenneth

    2002-01-01

    The successful development of an advanced powder metallurgy disk alloy, ME3, was initiated in the NASA High Speed Research/Enabling Propulsion Materials (HSR/EPM) Compressor/Turbine Disk program in cooperation with General Electric Engine Company and Pratt & Whitney Aircraft Engines. This alloy was designed using statistical screening and optimization of composition and processing variables to have extended durability at 1200 F in large disks. Disks of this alloy were produced at the conclusion of the program using a realistic scaled-up disk shape and processing to enable demonstration of these properties. The objective of the Ultra-Efficient Engine Technologies disk program was to assess the mechanical properties of these ME3 disks as functions of temperature in order to estimate the maximum temperature capabilities of this advanced alloy. These disks were sectioned, machined into specimens, and extensively tested. Additional sub-scale disks and blanks were processed and selectively tested to explore the effects of several processing variations on mechanical properties. Results indicate the baseline ME3 alloy and process can produce 1300 to 1350 F temperature capabilities, dependent on detailed disk and engine design property requirements.

  8. The optimization of phenolic compounds extraction from cactus pear (Opuntia ficus-indica) skin in a reflux system using response surface methodology.

    PubMed

    Jorge, Aguirre Joya; Heliodoro, De La Garza Toledo; Alejandro, Zugasti Cruz; Ruth, Belmares Cerda; Noé, Aguilar Cristóbal

    2013-06-01

    To extract, quantify, and evaluate the phenolic content in Opuntia ficus-indica skin for their antioxidant capacity with three different methods (ABTS, DPPH, and lipid oxidation) and to optimize the extraction conditions (time, temperature and ethanol concentration) in a reflux system. The extraction process was done using a reflux system. A San Cristobal II experimental design with three variables and three levels was used. The variables evaluated were time of extraction (h), concentration of ethanol (%, v/v) and temperature (°C). The extraction process was optimized using a response surface methodology. It was observed that at higher temperature more phenolic compounds were extracted, but the antioxidant capacity was decreased. The optimum conditions for phenolic compounds extraction and antioxidant capacity mixing the three methods were as follows: 45% of ethanol, 80 °C and 2 hours of extraction. Values obtained in our results are little higher that other previously reported. It can be concluded the by-products of Opuntia ficus-indica represent a good source of natural antioxidants with possible applications in food, cosmetics or drugs industries.

  9. Effect of fire-retardant treatment on plywood pH and the relationship of pH to strength properties

    Treesearch

    S. T. Lebow; J. E. Winandy

    1999-01-01

    This paper investigates the relationship between wood pH and the strength properties of fire-retardant-treated (FRT) plywood, as it is affected by fire-retardant (FR) formulations, processing variables, and extended high temperature exposure conditions. The objectives of this study were to (1) identify the effect of post-treatment kiln-drying temperature, followed by...

  10. Heat treatment of wet wood fiber: A study of the effect of reaction conditions on the formation of furfurals

    Treesearch

    Mandla A. Tshabalala; James D. McSweeny; Roger M. Rowell

    2012-01-01

    Furan monomers are produced when wood is heated at high temperatures. To understand the process conditions for production of furfural (FF) and hydroxymethylfurfural (HMF) from wood, samples of milled aspen wood were subjected to autohydrolyzis by microwave heating in a sealed Teflon reactor. The experiments were designed to simulate temperature and pressure variables...

  11. NAO and its relationship with the Northern Hemisphere mean surface temperature in CMIP5 simulations

    NASA Astrophysics Data System (ADS)

    Wang, Xiaofan; Li, Jianping; Sun, Cheng; Liu, Ting

    2017-04-01

    The North Atlantic Oscillation (NAO) is one of the most prominent teleconnection patterns in the Northern Hemisphere and has recently been found to be both an internal source and useful predictor of the multidecadal variability of the Northern Hemisphere mean surface temperature (NHT). In this study, we examine how well the variability of the NAO and NHT are reproduced in historical simulations generated by the 40 models that constitute Phase 5 of the Coupled Model Intercomparison Project (CMIP5). All of the models are able to capture the basic characteristics of the interannual NAO pattern reasonably well, whereas the simulated decadal NAO patterns show less consistency with the observations. The NAO fluctuations over multidecadal time scales are underestimated by almost all models. Regarding the NHT multidecadal variability, the models generally represent the externally forced variations well but tend to underestimate the internal NHT. With respect to the performance of the models in reproducing the NAO-NHT relationship, 14 models capture the observed decadal lead of the NAO, and model discrepancies in the representation of this linkage are derived mainly from their different interpretation of the underlying physical processes associated with the Atlantic Multidecadal Oscillation (AMO) and the Atlantic meridional overturning circulation (AMOC). This study suggests that one way to improve the simulation of the multidecadal variability of the internal NHT lies in better simulation of the multidecadal variability of the NAO and its delayed effect on the NHT variability via slow ocean processes.

  12. The Produce of Methyl Ester from Crude Palm Oil (CPO) Using Heterogene Catalyst Ash of Chicken Bone (CaO) using Ethanol as Solvent

    NASA Astrophysics Data System (ADS)

    Sinaga, M. S.; Fauzi, R.; Turnip, J. R.

    2017-03-01

    Methyl Ester (methyl ester) is generally made by trans esterification using heterogeneous base catalyst. To simplify the separation, the heterogeneous catalyst is used, such as CaO, which in this case was isolated from chicken bones made by softening chicken bones and do calcination process. Some other important variables other than the selection of the catalyst is the catalyst dosage, molar ratio of ethanol to the CPO and the reaction temperature. The best result from this observe is at the molar ratio of ethanol to the CPO is 17: 1, the reaction temperature is 70 ° C and 7% catalyst (w.t) with reaction time for 7 hours at 500 rpm as a constant variable, got 90,052 % purity, so that this result does not get the standard requirements of biodiesel, because of the purity of the biodiesel standard temporary must be achieve > 96.5 %. This study aims to produce methyl ester yield with the influence of the reaction temperature, percent of catalyst and molar ratio of ethanol and CPO. The most influential variable is the temperature of the reaction that gives a significant yield difference of methyl ester produced. It’s been proven by the increasing temperature used will also significantly increase the yield of methyl ester.

  13. Response surface modeling of boron adsorption from aqueous solution by vermiculite using different adsorption agents: Box-Behnken experimental design.

    PubMed

    Demirçivi, Pelin; Saygılı, Gülhayat Nasün

    2017-07-01

    In this study, a different method was applied for boron removal by using vermiculite as the adsorbent. Vermiculite, which was used in the experiments, was not modified with adsorption agents before boron adsorption using a separate process. Hexadecyltrimethylammonium bromide (HDTMA) and Gallic acid (GA) were used as adsorption agents for vermiculite by maintaining the solid/liquid ratio at 12.5 g/L. HDTMA/GA concentration, contact time, pH, initial boron concentration, inert electrolyte and temperature effects on boron adsorption were analyzed. A three-factor, three-level Box-Behnken design model combined with response surface method (RSM) was employed to examine and optimize process variables for boron adsorption from aqueous solution by vermiculite using HDTMA and GA. Solution pH (2-12), temperature (25-60 °C) and initial boron concentration (50-8,000 mg/L) were chosen as independent variables and coded x 1 , x 2 and x 3 at three levels (-1, 0 and 1). Analysis of variance was used to test the significance of variables and their interactions with 95% confidence limit (α = 0.05). According to the regression coefficients, a second-order empirical equation was evaluated between the adsorption capacity (q i ) and the coded variables tested (x i ). Optimum values of the variables were also evaluated for maximum boron adsorption by vermiculite-HDTMA (HDTMA-Verm) and vermiculite-GA (GA-Verm).

  14. Towards a Stochastic Predictive Understanding of Ecosystem Functioning and Resilience to Environmental Changes

    NASA Astrophysics Data System (ADS)

    Pappas, C.

    2017-12-01

    Terrestrial ecosystem processes respond differently to hydrometeorological variability across timescales, and so does our scientific understanding of the underlying mechanisms. Process-based modeling of ecosystem functioning is therefore challenging, especially when long-term predictions are envisioned. Here we analyze the statistical properties of hydrometeorological and ecosystem variability, i.e., the variability of ecosystem process related to vegetation carbon dynamics, from hourly to decadal timescales. 23 extra-tropical forest sites, covering different climatic zones and vegetation characteristics, are examined. Micrometeorological and reanalysis data of precipitation, air temperature, shortwave radiation and vapor pressure deficit are used to describe hydrometeorological variability. Ecosystem variability is quantified using long-term eddy covariance flux data of hourly net ecosystem exchange of CO2 between land surface and atmosphere, monthly remote sensing vegetation indices, annual tree-ring widths and above-ground biomass increment estimates. We find that across sites and timescales ecosystem variability is confined within a hydrometeorological envelope that describes the range of variability of the available resources, i.e., water and energy. Furthermore, ecosystem variability demonstrates long-term persistence, highlighting ecological memory and slow ecosystem recovery rates after disturbances. We derive an analytical model, combining deterministic harmonics and stochastic processes, that represents major mechanisms and uncertainties and mimics the observed pattern of hydrometeorological and ecosystem variability. This stochastic framework offers a parsimonious and mathematically tractable approach for modelling ecosystem functioning and for understanding its response and resilience to environmental changes. Furthermore, this framework reflects well the observed ecological memory, an inherent property of ecosystem functioning that is currently not captured by simulation results with process-based models. Our analysis offers a perspective for terrestrial ecosystem modelling, combining current process understanding with stochastic methods, and paves the way for new model-data integration opportunities in Earth system sciences.

  15. Impacts of Model Bias on the Climate Change Signal and Effects of Weighted Ensembles of Regional Climate Model Simulations: A Case Study over Southern Québec, Canada

    DOE PAGES

    Eum, Hyung-Il; Gachon, Philippe; Laprise, René

    2016-01-01

    This study examined the impact of model biases on climate change signals for daily precipitation and for minimum and maximum temperatures. Through the use of multiple climate scenarios from 12 regional climate model simulations, the ensemble mean, and three synthetic simulations generated by a weighting procedure, we investigated intermodel seasonal climate change signals between current and future periods, for both median and extreme precipitation/temperature values. A significant dependence of seasonal climate change signals on the model biases over southern Québec in Canada was detected for temperatures, but not for precipitation. This suggests that the regional temperature change signal is affectedmore » by local processes. Seasonally, model bias affects future mean and extreme values in winter and summer. In addition, potentially large increases in future extremes of temperature and precipitation values were projected. For three synthetic scenarios, systematically less bias and a narrow range of mean change for all variables were projected compared to those of climate model simulations. In addition, synthetic scenarios were found to better capture the spatial variability of extreme cold temperatures than the ensemble mean scenario. Finally, these results indicate that the synthetic scenarios have greater potential to reduce the uncertainty of future climate projections and capture the spatial variability of extreme climate events.« less

  16. Impacts of Model Bias on the Climate Change Signal and Effects of Weighted Ensembles of Regional Climate Model Simulations: A Case Study over Southern Québec, Canada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Eum, Hyung-Il; Gachon, Philippe; Laprise, René

    This study examined the impact of model biases on climate change signals for daily precipitation and for minimum and maximum temperatures. Through the use of multiple climate scenarios from 12 regional climate model simulations, the ensemble mean, and three synthetic simulations generated by a weighting procedure, we investigated intermodel seasonal climate change signals between current and future periods, for both median and extreme precipitation/temperature values. A significant dependence of seasonal climate change signals on the model biases over southern Québec in Canada was detected for temperatures, but not for precipitation. This suggests that the regional temperature change signal is affectedmore » by local processes. Seasonally, model bias affects future mean and extreme values in winter and summer. In addition, potentially large increases in future extremes of temperature and precipitation values were projected. For three synthetic scenarios, systematically less bias and a narrow range of mean change for all variables were projected compared to those of climate model simulations. In addition, synthetic scenarios were found to better capture the spatial variability of extreme cold temperatures than the ensemble mean scenario. Finally, these results indicate that the synthetic scenarios have greater potential to reduce the uncertainty of future climate projections and capture the spatial variability of extreme climate events.« less

  17. Genetic variability and phenotypic plasticity of metric thoracic traits in an invasive drosophilid in America.

    PubMed

    Bitner-Mathé, Blanche Christine; David, Jean Robert

    2015-08-01

    Thermal phenotypic plasticity of 5 metric thoracic traits (3 related to size and 2 to pigmentation) was investigated in Zaprionus indianus with an isofemale line design. Three of these traits are investigated for the first time in a drosophilid, i.e. thorax width and width of pigmented longitudinal white and black stripes. The reaction norms of white and black stripes were completely different: white stripes were insensitive to growth temperature while the black stripes exhibited a strong linear decrease with increasing temperatures. Thorax width exhibited a concave reaction norm, analogous but not identical to those of wing length and thorax length: the temperatures of maximum value were different, the highest being for thorax width. All traits exhibited a significant heritable variability and a low evolvability. Sexual dimorphism was very variable among traits, being nil for white stripes and thorax width, and around 1.13 for black stripes. The ratio thorax length to thorax width (an elongation index) was always >1, showing that males have a more rounded thorax at all temperatures. Black stripes revealed a significant increase of sexual dimorphism with increasing temperature. Shape indices, i.e. ratios between size traits all exhibited a linear decrease with temperature, the least sensitive being the elongation index. All these results illustrate the complexity of developmental processes but also the analytical strength of biometrical plasticity studies in an eco-devo perspective.

  18. Variability and change of sea level and its components in the Indo-Pacific region during the altimetry era

    NASA Astrophysics Data System (ADS)

    Wu, Quran; Zhang, Xuebin; Church, John A.; Hu, Jianyu

    2017-03-01

    Previous studies have shown that regional sea level exhibits interannual and decadal variations associated with the modes of climate variability. A better understanding of those low-frequency sea level variations benefits the detection and attribution of climate change signals. Nonetheless, the contributions of thermosteric, halosteric, and mass sea level components to sea level variability and trend patterns remain unclear. By focusing on signals associated with dominant climate modes in the Indo-Pacific region, we estimate the interannual and decadal fingerprints and trend of each sea level component utilizing a multivariate linear regression of two adjoint-based ocean reanalyses. Sea level interannual, decadal, and trend patterns primarily come from thermosteric sea level (TSSL). Halosteric sea level (HSSL) is of regional importance in the Pacific Ocean on decadal time scale and dominates sea level trends in the northeast subtropical Pacific. The compensation between TSSL and HSSL is identified in their decadal variability and trends. The interannual and decadal variability of temperature generally peak at subsurface around 100 m but that of salinity tend to be surface-intensified. Decadal temperature and salinity signals extend deeper into the ocean in some regions than their interannual equivalents. Mass sea level (MassSL) is critical for the interannual and decadal variability of sea level over shelf seas. Inconsistencies exist in MassSL trend patterns among various estimates. This study highlights regions where multiple processes work together to control sea level variability and change. Further work is required to better understand the interaction of different processes in those regions.

  19. [Optimization of vacuum belt drying process of Gardeniae Fructus in Reduning injection by Box-Behnken design-response surface methodology].

    PubMed

    Huang, Dao-sheng; Shi, Wei; Han, Lei; Sun, Ke; Chen, Guang-bo; Wu Jian-xiong; Xu, Gui-hong; Bi, Yu-an; Wang, Zhen-zhong; Xiao, Wei

    2015-06-01

    To optimize the belt drying process conditions optimization of Gardeniae Fructus extract from Reduning injection by Box-Behnken design-response surface methodology, on the basis of single factor experiment, a three-factor and three-level Box-Behnken experimental design was employed to optimize the drying technology of Gardeniae Fructus extract from Reduning injection. With drying temperature, drying time, feeding speed as independent variables and the content of geniposide as dependent variable, the experimental data were fitted to a second order polynomial equation, establishing the mathematical relationship between the content of geniposide and respective variables. With the experimental data analyzed by Design-Expert 8. 0. 6, the optimal drying parameter was as follows: the drying temperature was 98.5 degrees C , the drying time was 89 min, the feeding speed was 99.8 r x min(-1). Three verification experiments were taked under this technology and the measured average content of geniposide was 564. 108 mg x g(-1), which was close to the model prediction: 563. 307 mg x g(-1). According to the verification test, the Gardeniae Fructus belt drying process is steady and feasible. So single factor experiments combined with response surface method (RSM) could be used to optimize the drying technology of Reduning injection Gardenia extract.

  20. Optimization of ultrasound-assisted extraction of crude oil from winter melon (Benincasa hispida) seed using response surface methodology and evaluation of its antioxidant activity, total phenolic content and fatty acid composition.

    PubMed

    Bimakr, Mandana; Rahman, Russly Abdul; Taip, Farah Saleena; Adzahan, Noranizan Mohd; Sarker, Md Zaidul Islam; Ganjloo, Ali

    2012-10-08

    In the present study, ultrasound-assisted extraction of crude oil from winter melon seeds was investigated through response surface methodology (RSM). Process variables were power level (25-75%), temperature (45-55 °C) and sonication time (20-40 min). It was found that all process variables have significant (p < 0.05) effects on the response variable. A central composite design (CCD) was used to determine the optimum process conditions. Optimal conditions were identified as 65% power level, 52 °C temperature and 36 min sonication time for maximum crude yield (108.62 mg-extract/g-dried matter). The antioxidant activity, total phenolic content and fatty acid composition of extract obtained under optimized conditions were determined and compared with those of oil obtained by the Soxhlet method. It was found that crude extract yield (CEY) of ultrasound-assisted extraction was lower than that of the Soxhlet method, whereas antioxidant activity and total phenolic content of the extract obtained by ultrasound-assisted extraction were clearly higher than those of the Soxhlet extract. Furthermore, both extracts were rich in unsaturated fatty acids. The major fatty acids of the both extracts were linoleic acid and oleic acid.

  1. Effect of temperature, time, and milling process on yield, flavonoid, and total phenolic content of Zingiber officinale water extract

    NASA Astrophysics Data System (ADS)

    Andriyani, R.; Kosasih, W.; Ningrum, D. R.; Pudjiraharti, S.

    2017-03-01

    Several parameters such as temperature, time of extraction, and size of simplicia play significant role in medicinal herb extraction. This study aimed to investigate the effect of those parameters on yield extract, flavonoid, and total phenolic content in water extract of Zingiber officinale. The temperatures used were 50, 70 and 90°C and the extraction times were 30, 60 and 90 min. Z. officinale in the form of powder and chips were used to study the effect of milling treatment. The correlation among those variables was analysed using ANOVA two-way factors without replication. The result showed that time and temperature did not influence the yield of extract of Powder simplicia. However, time of extraction influenced the extract of simplicia treated without milling process. On the other hand, flavonoid and total phenolic content were not influenced by temperature, time, and milling treatment.

  2. Detection and attribution of temperature changes in the mountainous Western United States

    USGS Publications Warehouse

    Bonfils, Celine; Santer, B.D.; Pierce, D.W.; Hidalgo, H.G.; Bala, G.; Das, T.; Barnett, T.P.; Cayan, D.R.; Doutriaux, C.; Wood, A.W.; Mirin, A.; Nozawa, T.

    2008-01-01

    Large changes in the hydrology of the western United States have been observed since the mid-twentieth century. These include a reduction in the amount of precipitation arriving as snow, a decline in snowpack at low and midelevations, and a shift toward earlier arrival of both snowmelt and the centroid (center of mass) of streamflows. To project future water supply reliability, it is crucial to obtain a better understanding of the underlying cause or causes for these changes. A regional warming is often posited as the cause of these changes without formal testing of different competitive explanations for the warming. In this study, a rigorous detection and attribution analysis is performed to determine the causes of the late winter/early spring changes in hydrologically relevant temperature variables over mountain ranges of the western United States. Natural internal climate variability, as estimated from two long control climate model simulations, is insufficient to explain the rapid increase in daily minimum and maximum temperatures, the sharp decline in frost days, and the rise in degree-days above 0??C (a simple proxy for temperature driven snowmelt). These observed changes are also inconsistent with the model-predicted responses to variability in solar irradiance and volcanic activity. The observations are consistent with climite simulations that include the combined effects of anthropogenic greenhouse gases and aerosols. It is found that, for each temperature variable considered, an anthropogenic signal is identifiable in observational fields. The results are robust to uncertainties in model-estimated fingerprints and natural variability noise, to the choice of statistical down-scaling method, and to various processing options in the detection and attribution method. ?? 2008 American Meteorological Society.

  3. Hot spots of Io

    NASA Technical Reports Server (NTRS)

    Pearl, J. C.; Sinton, W. M.

    1982-01-01

    The size and temperature, morphology and distribution, variability, possible absorption features, and processes of hot spots on Io are discussed, and an estimate of the global heat flux is made. Size and temperature information is deconvolved to obtain equivalent radius and temperature of hot spots, and simultaneously obtained Voyager thermal and imaging data is used to match hot sources with specific geologic features. In addition to their thermal output, it is possible that hot spots are also characterized by production of various gases and particulate materials; the spectral signature of SO2 has been seen. Origins for relatively stable, low temperature sources, transient high temperature sources, and relatively stable, high-tmperature sources are discussed.

  4. Mathematical Model of Solidification During Electroslag Casting of Pilger Roll

    NASA Astrophysics Data System (ADS)

    Liu, Fubin; Li, Huabing; Jiang, Zhouhua; Dong, Yanwu; Chen, Xu; Geng, Xin; Zang, Ximin

    A mathematical model for describing the interaction of multiple physical fields in slag bath and solidification process in ingot during pilger roll casting with variable cross-section which is produced by the electroslag casting (ESC) process was developed. The commercial software ANSYS was applied to calculate the electromagnetic field, magnetic driven fluid flow, buoyancy-driven flow and heat transfer. The transportation phenomenon in slag bath and solidification characteristic of ingots are analyzed for variable cross-section with variable input power under the conditions of 9Cr3NiMo steel and 70%CaF2 - 30%Al2O3 slag system. The calculated results show that characteristic of current density distribution, velocity patterns and temperature profiles in the slag bath and metal pool profiles in ingot have distinct difference at variable cross-sections due to difference of input power and cooling condition. The pool shape and the local solidification time (LST) during Pilger roll ESC process are analyzed.

  5. Production of biodiesel from Jatropha curcas L. oil catalyzed by SO₄²⁻/ZrO₂ catalyst: effect of interaction between process variables.

    PubMed

    Yee, Kian Fei; Lee, Keat Teong; Ceccato, Riccardo; Abdullah, Ahmad Zuhairi

    2011-03-01

    This study reports the conversion of Jatrophacurcas L. oil to biodiesel catalyzed by sulfated zirconia loaded on alumina catalyst using response surface methodology (RSM), specifically to study the effect of interaction between process variables on the yield of biodiesel. The transesterification process variables studied were reaction temperature, reaction duration, molar ratio of methanol to oil and catalyst loading. Results from this study revealed that individual as well as interaction between variables significantly affect the yield of biodiesel. With this information, it was found that 4h of reaction at 150°C, methanol to oil molar ratio of 9.88 mol/mol and 7.61 wt.% for catalyst loading gave an optimum biodiesel yield of 90.32 wt.%. The fuel properties of Jatropha biodiesel were characterized and it indeed met the specification for biodiesel according to ASTM D6751. Copyright © 2010 Elsevier Ltd. All rights reserved.

  6. Forcing and Responses of the Surface Energy Budget at Summit, Greenland

    NASA Astrophysics Data System (ADS)

    Miller, Nathaniel B.

    Energy exchange at the Greenland Ice Sheet surface governs surface temperature variability, a factor critical for representing increasing surface melt extent, which portends a rise in global sea level. A comprehensive set of cloud, tropospheric, near-surface and sub-surface measurements at Summit Station is utilized to determine the driving forces and subsequent responses of the surface energy budget (SEB). This budget includes radiative, turbulent, and ground heat fluxes, and ultimately controls the evolution of surface temperature. At Summit Station, clouds radiatively warm the surface in all months with an annual average cloud radiative forcing value of 33 W m -2, largely driven by the occurrence of liquid-bearing clouds. The magnitude of the surface temperature response is dependent on how turbulent and ground heat fluxes modulate changes to radiative forcing. Relationships between forcing terms and responding surface fluxes show that changes in the upwelling longwave radiation compensate for 65-85% (50- 60%) of the total change in radiative forcing in the winter (summer). The ground heat flux is the second largest response term (16% annually), especially during winter. Throughout the annual cycle, the sensible heat flux response is comparatively constant (9%) and latent heat flux response is only 1.5%, becoming more of a factor in modulating surface temperature responses during the summer. Combining annual cycles of these responses with cloud radiative forcing results, clouds warm the surface by an estimated 7.8°C annually. A reanalysis product (ERA-I), operational model (CFSv2), and climate model (CESM) are evaluated utilizing the comprehensive set of SEB observations and process-based relationships. Annually, surface temperatures in each model are warmer than observed with overall poor representation of the coldest surface temperatures. Process-based relationships between different SEB flux terms offer insight into how well a modeling framework represents physical processes and the ability to distinguish errors in forcing versus those in physical representation. Such relationships convey that all three models underestimate the response of surface temperatures to changes in radiative forcing. These results provide a method to expose model deficiencies and indicate the importance of representing surface, sub-surface and boundary-layer processes when portraying cloud impacts on surface temperature variability.

  7. Optimization of non-thermal plasma efficiency in the simultaneous elimination of benzene, toluene, ethyl-benzene, and xylene from polluted airstreams using response surface methodology.

    PubMed

    Najafpoor, Ali Asghar; Jonidi Jafari, Ahmad; Hosseinzadeh, Ahmad; Khani Jazani, Reza; Bargozin, Hasan

    2018-01-01

    Treatment with a non-thermal plasma (NTP) is a new and effective technology applied recently for conversion of gases for air pollution control. This research was initiated to optimize the efficient application of the NTP process in benzene, toluene, ethyl-benzene, and xylene (BTEX) removal. The effects of four variables including temperature, initial BTEX concentration, voltage, and flow rate on the BTEX elimination efficiency were investigated using response surface methodology (RSM). The constructed model was evaluated by analysis of variance (ANOVA). The model goodness-of-fit and statistical significance was assessed using determination coefficients (R 2 and R 2 adj ) and the F-test. The results revealed that the R 2 proportion was greater than 0.96 for BTEX removal efficiency. The statistical analysis demonstrated that the BTEX removal efficiency was significantly correlated with the temperature, BTEX concentration, voltage, and flow rate. Voltage was the most influential variable affecting the dependent variable as it exerted a significant effect (p < 0.0001) on the response variable. According to the achieved results, NTP can be applied as a progressive, cost-effective, and practical process for treatment of airstreams polluted with BTEX in conditions of low residence time and high concentrations of pollutants.

  8. Optimization of torrefaction conditions of coffee industry residues using desirability function approach.

    PubMed

    Buratti, C; Barbanera, M; Lascaro, E; Cotana, F

    2018-03-01

    The aim of the present study is to analyze the influence of independent process variables such as temperature, residence time, and heating rate on the torrefaction process of coffee chaff (CC) and spent coffee grounds (SCGs). Response surface methodology and a three-factor and three-level Box-Behnken design were used in order to evaluate the effects of the process variables on the weight loss (W L ) and the Higher Heating Value (HHV) of the torrefied materials. Results showed that the effects of the three factors on both responses were sequenced as follows: temperature>residence time>heating rate. Data obtained from the experiments were analyzed by analysis of variance (ANOVA) and fitted to second-order polynomial models by using multiple regression analysis. Predictive models were determined, able to obtain satisfactory fittings of the experimental data, with coefficient of determination (R 2 ) values higher than 0.95. An optimization study using Derringer's desired function methodology was also carried out and the optimal torrefaction conditions were found: temperature 271.7°C, residence time 20min, heating rate 5°C/min for CC and 256.0°C, 20min, 25°C/min for SCGs. The experimental values closely agree with the corresponding predicted values. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Nutrient status: a missing factor in phenological and pollen research?

    PubMed Central

    Jochner, Susanne; Höfler, Josef; Beck, Isabelle; Göttlein, Axel; Ankerst, Donna Pauler; Traidl-Hoffmann, Claudia; Menzel, Annette

    2013-01-01

    Phenology ranks among the best ecosystem processes for fingerprinting climate change since temperature explains a high percentage of the interannual or spatial variation in phenological onset dates. However, roles of other environmental variables, such as foliar nutrient concentrations, are far from adequately understood. This observational study examined the effects of air temperature and 11 nutrients on spring phenology of Betula pendula Roth (birch) along an urban–rural gradient in Munich, Germany, during the years 2010/2011. Moreover, the influence of temperature, nutrients, and air pollutants (NO2 and O3) on the amounts of pollen and catkin biomass in 2010 was evaluated. In addition to the influence of higher temperatures advancing phenological onset dates, higher foliar concentrations of potassium, boron, zinc, and calcium were statistically significantly linked to earlier onset dates. Since flushing of leaves is a turgor-driven process and all the influential nutrients are involved in cell extension, membrane function, and stability, there might be a reasonable physiological interpretation of the observed association. The amounts of pollen were negatively correlated with temperature, atmospheric NO2, and foliar iron concentration, suggesting that these variables restrict pollen production. The results of this study suggested an influence of nutritional status on both phenology and pollen production. The interaction of urbanization and climate change should be considered in the assessment of the impact of global warming on ecosystems and human health. PMID:23630329

  10. Sorption-desorption of fipronil in some soils, as influenced by ionic strength, pH and temperature.

    PubMed

    Singh, Anand; Srivastava, Anjana; Srivastava, Prakash C

    2016-08-01

    The sorption-desorpion of fipronil insecticide is influenced by soil properties and variables such as pH, ionic strength, temperature, etc. A better understanding of soil properties and these variables in sorption-desorption processes by quantification of fipronil using liquid chromatography may help to optimise suitable soil management to reduce contamination of surface and groundwaters. In the present investigation, the sorption-desorption of fipronil was studied in some soils at varying concentrations, ionic strengths, temperatures and pH values, and IR specta of fipronil sorbed onto soils were studied. The sorption of fipronil onto soils conformed to the Freundlich isotherm model. The sorption-desorption of fipronil varied with ionic strength in each of the soils. Sorption decreased but desorption increased with temperature. Sorption did not change with increasing pH, but for desorption there was no correlation. The cumulative desorption of fipronil from soil was significantly and inversely related to soil organic carbon content. IR spectra of sorbed fipronil showed the involvement of amino, nitrile, sulfone, chloro and fluoro groups and the pyrazole nucleus of the fipronil molecule. The sorption of fipronil onto soils appeared to be a physical process with the involvement of hydrogen bonding. An increase in soil organic carbon may help to reduce desorption of fipronil. High-temperature regimes are more conducive to the desorption. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

  11. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hammond, Glenn Edward; Yang, Xiaofan; Song, Xuehang

    The groundwater-surface water interaction zone (GSIZ) plays an important role in riverine and watershed ecosystems as the exchange of waters of variable composition and temperature (hydrologic exchange flows) stimulate microbial activity and associated biogeochemical reactions. Variable temporal and spatial scales of hydrologic exchange flows, heterogeneity of the subsurface environment, and complexity of biogeochemical reaction networks in the GSIZ present challenges to incorporation of fundamental process representations and model parameterization across a range of spatial scales (e.g. from pore-scale to field scale). This paper presents a novel hybrid multiscale simulation approach that couples hydrologic-biogeochemical (HBGC) processes between two distinct length scalesmore » of interest.« less

  12. Estuary-ocean connectivity: Fast physics, slow biology

    USGS Publications Warehouse

    Raimonet, Mélanie; Cloern, James E.

    2017-01-01

    Estuaries are connected to both land and ocean so their physical, chemical, and biological dynamics are influenced by climate patterns over watersheds and ocean basins. We explored climate-driven oceanic variability as a source of estuarine variability by comparing monthly time series of temperature and chlorophyll-a inside San Francisco Bay with those in adjacent shelf waters of the California Current System (CCS) that are strongly responsive to wind-driven upwelling. Monthly temperature fluctuations inside and outside the Bay were synchronous, but their correlations weakened with distance from the ocean. These results illustrate how variability of coastal water temperature (and associated properties such as nitrate and oxygen) propagates into estuaries through fast water exchanges that dissipate along the estuary. Unexpectedly, there was no correlation between monthly chlorophyll-a variability inside and outside the Bay. However, at the annual scale Bay chlorophyll-a was significantly correlated with the Spring Transition Index (STI) that sets biological production supporting fish recruitment in the CCS. Wind forcing of the CCS shifted in the late 1990s when the STI advanced 40 days. This shift was followed, with lags of 1–3 years, by 3- to 19-fold increased abundances of five ocean-produced demersal fish and crustaceans and 2.5-fold increase of summer chlorophyll-a in the Bay. These changes reflect a slow biological process of estuary–ocean connectivity operating through the immigration of fish and crustaceans that prey on bivalves, reduce their grazing pressure, and allow phytoplankton biomass to build. We identified clear signals of climate-mediated oceanic variability in this estuary and discovered that the response patterns vary with the process of connectivity and the timescale of ocean variability. This result has important implications for managing nutrient inputs to estuaries connected to upwelling systems, and for assessing their responses to changing patterns of upwelling timing and intensity as the planet continues to warm.

  13. Parameterization of typhoon-induced ocean cooling using temperature equation and machine learning algorithms: an example of typhoon Soulik (2013)

    NASA Astrophysics Data System (ADS)

    Wei, Jun; Jiang, Guo-Qing; Liu, Xin

    2017-09-01

    This study proposed three algorithms that can potentially be used to provide sea surface temperature (SST) conditions for typhoon prediction models. Different from traditional data assimilation approaches, which provide prescribed initial/boundary conditions, our proposed algorithms aim to resolve a flow-dependent SST feedback between growing typhoons and oceans in the future time. Two of these algorithms are based on linear temperature equations (TE-based), and the other is based on an innovative technique involving machine learning (ML-based). The algorithms are then implemented into a Weather Research and Forecasting model for the simulation of typhoon to assess their effectiveness, and the results show significant improvement in simulated storm intensities by including ocean cooling feedback. The TE-based algorithm I considers wind-induced ocean vertical mixing and upwelling processes only, and thus obtained a synoptic and relatively smooth sea surface temperature cooling. The TE-based algorithm II incorporates not only typhoon winds but also ocean information, and thus resolves more cooling features. The ML-based algorithm is based on a neural network, consisting of multiple layers of input variables and neurons, and produces the best estimate of the cooling structure, in terms of its amplitude and position. Sensitivity analysis indicated that the typhoon-induced ocean cooling is a nonlinear process involving interactions of multiple atmospheric and oceanic variables. Therefore, with an appropriate selection of input variables and neuron sizes, the ML-based algorithm appears to be more efficient in prognosing the typhoon-induced ocean cooling and in predicting typhoon intensity than those algorithms based on linear regression methods.

  14. Performance of an ultrafiltration membrane bioreactor (UF-MBR) as a processing strategy for the synthesis of galacto-oligosaccharides at high substrate concentrations.

    PubMed

    Córdova, Andrés; Astudillo, Carolina; Vera, Carlos; Guerrero, Cecilia; Illanes, Andrés

    2016-04-10

    The performance of an ultrafiltration membrane bioreactor for galacto-oligosaccharides (GOS) synthesis using high lactose concentrations (470 g/L) and β-galactosidase from Aspergillus oryzae was assessed. Tested processing variables were: transmembrane-pressure (PT), crossflow-velocity (CFV) and temperature. Results showed that processing variables had significant effect on the yield, the enzyme productivity and the flux but did not on GOS concentration and reaction conversion obtained. As expected, the use of high turbulences improved mass transfer and reduced the membrane fouling, but the use of very high crossflow-velocities caused operational instability due to vortex formation and lactose precipitation. The use of a desirability function allowed determining optimal conditions which were: PT (4.38 bar), CFV (7.35 m/s) and temperature (53.1 °C), optimizing simultaneously flux and specific enzyme productivity Under these optimal processing conditions, shear-stress and temperature did not affect the enzyme but long-term operation was limited by flux decay. In comparison to a conventional batch system, at 12.5h of processing time, the continuous GOS synthesis in the UF-MBR increased significantly the amount of processed substrate and a 2.44-fold increase in the amount of GOS produced per unit mass of catalyst was obtained with respect to a conventional batch system. Furthermore, these results can be improved by far by tuning the membranearea/reactionvolume ratio, showing that the use of an UF-MBR is an attractive alternative for the GOS synthesis at very high lactose concentrations. Copyright © 2016 Elsevier B.V. All rights reserved.

  15. Impacts of temperature and lunar day on gene expression profiles during a monthly reproductive cycle in the brooding coral Pocillopora damicornis.

    PubMed

    Crowder, Camerron M; Meyer, Eli; Fan, Tung-Yung; Weis, Virginia M

    2017-08-01

    Reproductive timing in brooding corals has been correlated to temperature and lunar irradiance, but the mechanisms by which corals transduce these environmental variables into molecular signals are unknown. To gain insight into these processes, global gene expression profiles in the coral Pocillopora damicornis were examined (via RNA-Seq) across lunar phases and between temperature treatments, during a monthly planulation cycle. The interaction of temperature and lunar day together had the largest influence on gene expression. Mean timing of planulation, which occurred at lunar days 7.4 and 12.5 for 28- and 23°C-treated corals, respectively, was associated with an upregulation of transcripts in individual temperature treatments. Expression profiles of planulation-associated genes were compared between temperature treatments, revealing that elevated temperatures disrupted expression profiles associated with planulation. Gene functions inferred from homologous matches to online databases suggest complex neuropeptide signalling, with calcium as a central mediator, acting through tyrosine kinase and G protein-coupled receptor pathways. This work contributes to our understanding of coral reproductive physiology and the impacts of environmental variables on coral reproductive pathways. © 2017 John Wiley & Sons Ltd.

  16. Temperature-driven decoupling of key phases of organic matter degradation in marine sediments.

    PubMed

    Weston, Nathaniel B; Joye, Samantha B

    2005-11-22

    The long-term burial of organic carbon in sediments results in the net accumulation of oxygen in the atmosphere, thereby mediating the redox state of the Earth's biosphere and atmosphere. Sediment microbial activity plays a major role in determining whether particulate organic carbon is recycled or buried. A diverse consortium of microorganisms that hydrolyze, ferment, and terminally oxidize organic compounds mediates anaerobic organic matter mineralization in anoxic sediments. Variable temperature regulation of the sequential processes, leading from the breakdown of complex particulate organic carbon to the production and subsequent consumption of labile, low-molecular weight, dissolved intermediates, could play a key role in controlling rates of overall organic carbon mineralization. We examined sediment organic carbon cycling in a sediment slurry and in flow through bioreactor experiments. The data show a variable temperature response of the microbial functional groups mediating organic matter mineralization in anoxic marine sediments, resulting in the temperature-driven decoupling of the production and consumption of organic intermediates. This temperature-driven decoupling leads to the accumulation of labile, low-molecular weight, dissolved organic carbon at low temperatures and low-molecular weight dissolved organic carbon limitation of terminal metabolism at higher temperatures.

  17. Secular temperature trends for the southern Rocky Mountains over the last five centuries

    NASA Astrophysics Data System (ADS)

    Berkelhammer, M.; Stott, L. D.

    2012-09-01

    Pre-instrumental surface temperature variability in the Southwestern United States has traditionally been reconstructed using variations in the annual ring widths of high altitude trees that live near a growth-limiting isotherm. A number of studies have suggested that the response of some trees to temperature variations is non-stationary, warranting the development of alternative approaches towards reconstructing past regional temperature variability. Here we present a five-century temperature reconstruction for a high-altitude site in the Rocky Mountains derived from the oxygen isotopic composition of cellulose (δ18Oc) from Bristlecone Pine trees. The record is independent of the co-located growth-based reconstruction while providing the same temporal resolution and absolute age constraints. The empirical correlation between δ18Oc and instrumental temperatures is used to produce a temperature transfer function. A forward-model for cellulose isotope variations, driven by meteorological data and output from an isotope-enabled General Circulation Model, is used to evaluate the processes that propagate the temperature signal to the proxy. The cellulose record documents persistent multidecadal variations in δ18Oc that are attributable to temperature shifts on the order of 1°C but no sustained monotonic rise in temperature or a step-like increase since the late 19th century. The isotope-based temperature history is consistent with both regional wood density-based temperature estimates and some sparse early instrumental records.

  18. Heat recovery system employing a temperature controlled variable speed fan

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jones, W.T.

    1986-05-20

    A heat recovery system is described for use in recovering heat from an industrial process producing a heated fluid comprising: a source of inlet air; a housing coupled to the source and including a heat exchanger; means for passing the heated fluid through the heat exchanger; the housing including means for moving a variable volume of air adjustable over a continuous range from the source through the heat exchanger; air discharge means communicating with the housing for discharging air which has passed through the heat exchanger; a control system including first temperature sensing means for sensing the discharge temperature ofmore » the discharge air moving through the discharge means and a control circuit coupled to the first temperature sensing means and to the moving means for varying the volume of air moved in response to the sensed discharge temperature to control the temperature of discharge air passing through the discharge means at a first predetermined value; and the control system including second temperature sensing means for sensing the temperature of the source of inlet air and valve means coupled to and controlled by the control circuit to cause liquid to bypass the heat exchanger when the inlet air temperature rises above a second predetermined value.« less

  19. Mathematical modeling as a tool to investigate the design and operation of the zymotis packed-bed bioreactor for solid-state fermentation.

    PubMed

    Mitchell, D A; von Meien, O F

    2000-04-20

    Zymotis bioreactors for solid-state fermentation (SSF) are packed-bed bioreactors with internal cooling plates. This design has potential to overcome the problem of heat removal, which is one of the main challenges in SSF. In ordinary packed-bed bioreactors, which lack internal plates, large axial temperature gradients arise, leading to poor microbial growth in the end of the bed near the air outlet. The Zymotis design is suitable for SSF processes in which the substrate bed must be maintained static, but little is known about how to design and operate Zymotis bioreactors. We use a two-dimensional heat transfer model, describing the growth of Aspergillus niger on a starchy substrate, to provide guidelines for the optimum design and operation of Zymotis bioreactors. As for ordinary packed-beds, the superficial velocity of the process air is a key variable. However, the Zymotis design introduces other important variables, namely, the spacing between the internal cooling plates and the temperature of the cooling water. High productivities can be achieved at large scale, but only if small spacings between the cooling plates are used, and if the cooling water temperature is varied during the fermentation in response to bed temperatures. Copyright 2000 John Wiley & Sons, Inc.

  20. Variable Temperature Nuclear Magnetic Resonance and Magnetic Resonance Imaging System as a Novel Technique for In Situ Monitoring of Food Phase Transition.

    PubMed

    Song, Yukun; Cheng, Shasha; Wang, Huihui; Zhu, Bei-Wei; Zhou, Dayong; Yang, Peiqiang; Tan, Mingqian

    2018-01-24

    A nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) system with a 45 mm variable temperature (VT) sample probe (VT-NMR-MRI) was developed as an innovative technique for in situ monitoring of food phase transition. The system was designed to allow for dual deployment in either a freezing (-37 °C) or high temperature (150 °C) environment. The major breakthrough of the developed VT-NMR-MRI system is that it is able to measure the water states simultaneously in situ during food processing. The performance of the VT-NMR-MRI system was evaluated by measuring the phase transition for salmon flesh and hen egg samples. The NMR relaxometry results demonstrated that the freezing point of salmon flesh was -8.08 °C, and the salmon flesh denaturation temperature was 42.16 °C. The protein denaturation of egg was 70.61 °C, and the protein denaturation occurred at 24.12 min. Meanwhile, the use of MRI in phase transition of food was also investigated to gain internal structural information. All these results showed that the VT-NMR-MRI system provided an effective means for in situ monitoring of phase transition in food processing.

  1. "Intelligent Ensemble" Projections of Precipitation and Surface Radiation in Support of Agricultural Climate Change Adaptation

    NASA Technical Reports Server (NTRS)

    Taylor, Patrick C.; Baker, Noel C.

    2015-01-01

    Earth's climate is changing and will continue to change into the foreseeable future. Expected changes in the climatological distribution of precipitation, surface temperature, and surface solar radiation will significantly impact agriculture. Adaptation strategies are, therefore, required to reduce the agricultural impacts of climate change. Climate change projections of precipitation, surface temperature, and surface solar radiation distributions are necessary input for adaption planning studies. These projections are conventionally constructed from an ensemble of climate model simulations (e.g., the Coupled Model Intercomparison Project 5 (CMIP5)) as an equal weighted average, one model one vote. Each climate model, however, represents the array of climate-relevant physical processes with varying degrees of fidelity influencing the projection of individual climate variables differently. Presented here is a new approach, termed the "Intelligent Ensemble, that constructs climate variable projections by weighting each model according to its ability to represent key physical processes, e.g., precipitation probability distribution. This approach provides added value over the equal weighted average method. Physical process metrics applied in the "Intelligent Ensemble" method are created using a combination of NASA and NOAA satellite and surface-based cloud, radiation, temperature, and precipitation data sets. The "Intelligent Ensemble" method is applied to the RCP4.5 and RCP8.5 anthropogenic climate forcing simulations within the CMIP5 archive to develop a set of climate change scenarios for precipitation, temperature, and surface solar radiation in each USDA Farm Resource Region for use in climate change adaptation studies.

  2. A priori and a posteriori analyses of the flamelet/progress variable approach for supersonic combustion

    NASA Astrophysics Data System (ADS)

    Saghafian, Amirreza; Pitsch, Heinz

    2012-11-01

    A compressible flamelet/progress variable approach (CFPV) has been devised for high-speed flows. Temperature is computed from the transported total energy and tabulated species mass fractions and the source term of the progress variable is rescaled with pressure and temperature. The combustion is thus modeled by three additional scalar equations and a chemistry table that is computed in a pre-processing step. Three-dimensional direct numerical simulation (DNS) databases of reacting supersonic turbulent mixing layer with detailed chemistry are analyzed to assess the underlying assumptions of CFPV. Large eddy simulations (LES) of the same configuration using the CFPV method have been performed and compared with the DNS results. The LES computations are based on the presumed subgrid PDFs of mixture fraction and progress variable, beta function and delta function respectively, which are assessed using DNS databases. The flamelet equation budget is also computed to verify the validity of CFPV method for high-speed flows.

  3. Rare Central Pacific El Niño Events Caused by Interdecadal Tropical Pacific Variability

    NASA Astrophysics Data System (ADS)

    Zhong, Wenxiu; Zheng, Xiaotong; Cai, Wenju

    2017-04-01

    The frequency of Central Pacific (CP) El Niño events displays strong decadal-variability but the associated dynamics is still not clear. The Inter-decadal Pacific Oscillation (IPO) and the Tropical Pacific Decadal Variability (TPDV) are two dominant modes of the Pacific low-frequency variability that can modify high-frequency behaviors. Using a 500-year control integration of Geophysical Fluid Dynamics Laboratory Earth System Model simulation, we find that the mean state, determined by the two independent modes of tropical Pacific decadal variability, strongly affects CP El Niño frequency and the associated developing processes. A positive TPDV features a shallow thermocline and cool sea surface temperature anomalies (SSTAs) across the central-to-western tropical Pacific, and a negative IPO features cool SSTAs and strong trade winds along the equatorial Pacific. The combination of a positive TPDV and a negative IPO generates a decadal mean state, in which the climatological zonal temperature gradient is reduced, equatorward and westward current anomalies are harder to be generated over the central-to-western tropical Pacific, resulting in the lack of CP El Niño.

  4. Effect of processing parameters on FDM process

    NASA Astrophysics Data System (ADS)

    Chari, V. Srinivasa; Venkatesh, P. R.; Krupashankar, Dinesh, Veena

    2018-04-01

    This paper focused on the process parameters on fused deposition modeling (FDM). Infill, resolution, temperature are the process variables considered for experimental studies. Compression strength, Hardness test microstructure are the outcome parameters, this experimental study done based on the taguchi's L9 orthogonal array is used. Taguchi array used to build the 9 different models and also to get the effective output results on the under taken parameters. The material used for this experimental study is Polylactic Acid (PLA).

  5. Quality by Design approach to spray drying processing of crystalline nanosuspensions.

    PubMed

    Kumar, Sumit; Gokhale, Rajeev; Burgess, Diane J

    2014-04-10

    Quality by Design (QbD) principles were explored to understand spray drying process for the conversion of liquid nanosuspensions into solid nano-crystalline dry powders using indomethacin as a model drug. The effects of critical process variables: inlet temperature, flow and aspiration rates on critical quality attributes (CQAs): particle size, moisture content, percent yield and crystallinity were investigated employing a full factorial design. A central cubic design was employed to generate the response surface for particle size and percent yield. Multiple linear regression analysis and ANOVA were employed to identify and estimate the effect of critical parameters, establish their relationship with CQAs, create design space and model the spray drying process. Inlet temperature was identified as the only significant factor (p value <0.05) to affect dry powder particle size. Higher inlet temperatures caused drug surface melting and hence aggregation of the dried nano-crystalline powders. Aspiration and flow rates were identified as significant factors affecting yield (p value <0.05). Higher yields were obtained at higher aspiration and lower flow rates. All formulations had less than 3% (w/w) moisture content. Formulations dried at higher inlet temperatures had lower moisture compared to those dried at lower inlet temperatures. Published by Elsevier B.V.

  6. Investigation of the adhesion properties of direct 3D printing of polymers and nanocomposites on textiles: Effect of FDM printing process parameters

    NASA Astrophysics Data System (ADS)

    Hashemi Sanatgar, Razieh; Campagne, Christine; Nierstrasz, Vincent

    2017-05-01

    In this paper, 3D printing as a novel printing process was considered for deposition of polymers on synthetic fabrics to introduce more flexible, resource-efficient and cost effective textile functionalization processes than conventional printing process like screen and inkjet printing. The aim is to develop an integrated or tailored production process for smart and functional textiles which avoid unnecessary use of water, energy, chemicals and minimize the waste to improve ecological footprint and productivity. Adhesion of polymer and nanocomposite layers which were 3D printed directly onto the textile fabrics using fused deposition modeling (FDM) technique was investigated. Different variables which may affect the adhesion properties including 3D printing process parameters, fabric type and filler type incorporated in polymer were considered. A rectangular shape according to the peeling standard was designed as 3D computer-aided design (CAD) to find out the effect of the different variables. The polymers were printed in different series of experimental design: nylon on polyamide 66 (PA66) fabrics, polylactic acid (PLA) on PA66 fabric, PLA on PLA fabric, and finally nanosize carbon black/PLA (CB/PLA) and multi-wall carbon nanotubes/PLA (CNT/PLA) nanocomposites on PLA fabrics. The adhesion forces were quantified using the innovative sample preparing method combining with the peeling standard method. Results showed that different variables of 3D printing process like extruder temperature, platform temperature and printing speed can have significant effect on adhesion force of polymers to fabrics while direct 3D printing. A model was proposed specifically for deposition of a commercial 3D printer Nylon filament on PA66 fabrics. In the following, among the printed polymers, PLA and its composites had high adhesion force to PLA fabrics.

  7. Influence of North Atlantic modes on European climate extremes

    NASA Astrophysics Data System (ADS)

    Proemmel, K.; Cubasch, U.

    2017-12-01

    It is well known that the North Atlantic strongly influences European climate. Only few studies exist that focus on its impact on climate extremes. We are interested in these extremes and the processes and mechanisms behind it. For the analysis of the North Atlantic Oscillation (NAO) we use simulations performed with the Max Planck Institute for Meteorology Earth System Model (MPI-ESM). The NAO has a strong impact especially on European winter and the changes in minimum temperature are even larger than in maximum temperature. The impact of the Atlantic Multi-decadal Variability (AMV) on climate extremes is analyzed in ECHAM6 simulations forced with AMV warm and AMV cold sea surface temperature patterns. We analyze different extreme indices and try to understand the processes.

  8. Terrestrial cooling and solar variability

    NASA Technical Reports Server (NTRS)

    Agee, E. M.

    1982-01-01

    Observational evidence from surface temperature records is presented and discussed which suggests a significant cooling trend over the Northern Hemisphere from 1940 to the present. This cooling trend is associated with an increase of the latitudinal gradient of temperature and the lapse rate, as predicted by climate models with decreased solar input and feedback mechanisms. Evidence suggests that four of these 80- to 100-year cycles of global surface temperature fluctuation may have occurred, and in succession, from 1600 to the present. Interpretation of sunspot activity were used to infer a direct thermal response of terrestrial temperature to solar variability on the time scale of the Gleissberg cycle (90 years, an amplitude of the 11-year cycles). A physical link between the sunspot activity and the solar parameter is hypothesized. Observations of sensible heat flux by stationary planetary waves and transient eddies, as well as general circulation modeling results of these processes, were examined from the viewpoint of the hypothesis of cooling due to reduced insolation.

  9. Seasonal temperature variability and emergency hospital admissions for respiratory diseases: a population-based cohort study.

    PubMed

    Sun, Shengzhi; Laden, Francine; Hart, Jaime E; Qiu, Hong; Wang, Yan; Wong, Chit Ming; Lee, Ruby Siu-Yin; Tian, Linwei

    2018-04-05

    Climate change increases global mean temperature and changes short-term (eg, diurnal) and long-term (eg, intraseasonal) temperature variability. Numerous studies have shown that mean temperature and short-term temperature variability are both associated with increased respiratory morbidity or mortality. However, data on the impact of long-term temperature variability are sparse. We aimed to assess the association of intraseasonal temperature variability with respiratory disease hospitalisations among elders. We ascertained the first occurrence of emergency hospital admissions for respiratory diseases in a prospective Chinese elderly cohort of 66 820 older people (≥65 years) with 10-13 years of follow-up. We used an ordinary kriging method based on 22 weather monitoring stations in Hong Kong to spatially interpolate daily ambient temperature for each participant's residential address. Seasonal temperature variability was defined as the SD of daily mean summer (June-August) or winter (December-February) temperatures. We applied Cox proportional hazards regression with time-varying exposure of seasonal temperature variability to respiratory admissions. During the follow-up time, we ascertained 12 689 cases of incident respiratory diseases, of which 6672 were pneumonia and 3075 were COPD. The HRs per 1°C increase in wintertime temperature variability were 1.20 (95% CI 1.08 to 1.32), 1.15 (1.01 to 1.31) and 1.41 (1.15 to 1.71) for total respiratory diseases, pneumonia and COPD, respectively. The associations were not statistically significant for summertime temperature variability. Wintertime temperature variability was associated with higher risk of incident respiratory diseases. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2018. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

  10. Global patterns of declining temperature variability from the Last Glacial Maximum to the Holocene

    NASA Astrophysics Data System (ADS)

    Rehfeld, Kira; Münch, Thomas; Ho, Sze Ling; Laepple, Thomas

    2018-02-01

    Changes in climate variability are as important for society to address as are changes in mean climate. Contrasting temperature variability during the Last Glacial Maximum and the Holocene can provide insights into the relationship between the mean state of the climate and its variability. However, although glacial-interglacial changes in variability have been quantified for Greenland, a global view remains elusive. Here we use a network of marine and terrestrial temperature proxies to show that temperature variability decreased globally by a factor of four as the climate warmed by 3-8 degrees Celsius from the Last Glacial Maximum (around 21,000 years ago) to the Holocene epoch (the past 11,500 years). This decrease had a clear zonal pattern, with little change in the tropics (by a factor of only 1.6-2.8) and greater change in the mid-latitudes of both hemispheres (by a factor of 3.3-14). By contrast, Greenland ice-core records show a reduction in temperature variability by a factor of 73, suggesting influences beyond local temperature or a decoupling of atmospheric and global surface temperature variability for Greenland. The overall pattern of reduced variability can be explained by changes in the meridional temperature gradient, a mechanism that points to further decreases in temperature variability in a warmer future.

  11. Global patterns of declining temperature variability from the Last Glacial Maximum to the Holocene.

    PubMed

    Rehfeld, Kira; Münch, Thomas; Ho, Sze Ling; Laepple, Thomas

    2018-02-15

    Changes in climate variability are as important for society to address as are changes in mean climate. Contrasting temperature variability during the Last Glacial Maximum and the Holocene can provide insights into the relationship between the mean state of the climate and its variability. However, although glacial-interglacial changes in variability have been quantified for Greenland, a global view remains elusive. Here we use a network of marine and terrestrial temperature proxies to show that temperature variability decreased globally by a factor of four as the climate warmed by 3-8 degrees Celsius from the Last Glacial Maximum (around 21,000 years ago) to the Holocene epoch (the past 11,500 years). This decrease had a clear zonal pattern, with little change in the tropics (by a factor of only 1.6-2.8) and greater change in the mid-latitudes of both hemispheres (by a factor of 3.3-14). By contrast, Greenland ice-core records show a reduction in temperature variability by a factor of 73, suggesting influences beyond local temperature or a decoupling of atmospheric and global surface temperature variability for Greenland. The overall pattern of reduced variability can be explained by changes in the meridional temperature gradient, a mechanism that points to further decreases in temperature variability in a warmer future.

  12. Unabated global surface temperature warming: evaluating the evidence

    NASA Astrophysics Data System (ADS)

    Karl, T. R.; Arguez, A.

    2015-12-01

    New insights related to time-dependent bias corrections in global surface temperatures have led to higher rates of warming over the past few decades than previously reported in the IPCC Fifth Assessment Report (2014). Record high global temperatures in the past few years have also contributed to larger trends. The combination of these factors and new analyses of the rate of temperature change show unabated global warming since at least the mid-Twentieth Century. New time-dependent bias corrections account for: (1) differences in temperatures measured from ships and drifting buoys; (2) improved corrections to ship measured temperatures; and (3) the larger rates of warming in polar regions (particularly the Arctic). Since 1951, the period over which IPCC (2014) attributes over half of the observed global warming to human causes, it is shown that there has been a remarkably robust and sustained warming, punctuated with inter-annual and decadal variability. This finding is confirmed through simple trend analysis and Empirical Mode Decomposition (EMD). Trend analysis however, especially for decadal trends, is sensitive to selection bias of beginning and ending dates. EMD has no selection bias. Additionally, it can highlight both short- and long-term processes affecting the global temperature times series since it addresses both non-linear and non-stationary processes. For the new NOAA global temperature data set, our analyses do not support the notion of a hiatus or slowing of long-term global warming. However, sub-decadal periods of little (or no warming) and rapid warming can also be found, clearly showing the impact of inter-annual and decadal variability that previously has been attributed to both natural and human-induced non-greenhouse forcings.

  13. Application of Response Surface Methodology on Leaching of Iron from Partially Laterised Khondalite Rocks: A Bauxite Mining Waste

    NASA Astrophysics Data System (ADS)

    Swain, Ranjita; Bhima Rao, R.

    2018-04-01

    In the present investigation, response surface methodology (RSM) is used for a quadratic model that continuously controls the process parameters. This model is used to optimize the removal of iron oxide from Partially Laterised Khondalite (PLK) rocks which is influenced by several independent variables namely acid concentration, time and temperature. Second order response functions are produced for leaching of iron oxide from PLK rocks-a bauxite mining waste. In RSM, Box-Behnken design is used for the process optimization to achieve maximum removal of iron oxide. The influence of the process variables of leaching of iron oxide is presented in the form of 3-D response graphs. The results of this investigation reveals that 3 M hydrochloric acid concentration, 240 min time and 373 K temperature are found to be the best conditions for removal of 99% Fe2O3. The product obtain at this condition contain 80% brightness which is suitable for ceramic and filler industry applications. The novelity of the work is that the waste can be a value added product after suitable physical beneficiation and chemical treatment.

  14. Chemochromic detector for sensing gas leakage and process for producing the same

    NASA Technical Reports Server (NTRS)

    Roberson, Luke B. (Inventor); Williams, Martha K. (Inventor); Captain, Janine E. (Inventor); Smith, Trent M. (Inventor); Tate, LaNetra Clayton (Inventor)

    2012-01-01

    A chemochromic sensor for detecting a combustible gas, such as hydrogen, includes a chemochromic pigment mechanically mixed with a polymer and formed into a rigid or pliable material. In a preferred embodiment, the chemochromic detector includes aerogel material. The detector is robust and easily modifiable for a variety of applications and environmental conditions, such as atmospheres of inert gas, hydrogen gas, or mixtures of gases, or in environments that have variable temperature, including high temperatures such as above 100.degree. C. and low temperatures such as below -196.degree. C.

  15. Corrosion of Ceramic Materials

    NASA Technical Reports Server (NTRS)

    Opila, Elizabeth J.; Jacobson, Nathan S.

    1999-01-01

    Non-oxide ceramics are promising materials for a range of high temperature applications. Selected current and future applications are listed. In all such applications, the ceramics are exposed to high temperature gases. Therefore it is critical to understand the response of these materials to their environment. The variables to be considered here include both the type of ceramic and the environment to which it is exposed. Non-oxide ceramics include borides, nitrides, and carbides. Most high temperature corrosion environments contain oxygen and hence the emphasis of this chapter will be on oxidation processes.

  16. Interannual variability of the atmospheric CO2 growth rate: relative contribution from precipitation and temperature

    NASA Astrophysics Data System (ADS)

    Wang, J.; Zeng, N.; Wang, M. R.

    2015-12-01

    The interannual variability (IAV) in atmospheric CO2 growth rate (CGR) is closely connected with the El Niño-Southern Oscillation. However, sensitivities of CGR to temperature and precipitation remain largely uncertain. This paper analyzed the relationship between Mauna Loa CGR and tropical land climatic elements. We find that Mauna Loa CGR lags precipitation by 4 months with a correlation coefficient of -0.63, leads temperature by 1 month (0.77), and correlates with soil moisture (-0.65) with zero lag. Additionally, precipitation and temperature are highly correlated (-0.66), with precipitation leading by 4-5 months. Regression analysis shows that sensitivities of Mauna Loa CGR to temperature and precipitation are 2.92 ± 0.20 Pg C yr-1 K-1 and -0.46 ± 0.07 Pg C yr-1 100 mm-1, respectively. Unlike some recent suggestions, these empirical relationships favor neither temperature nor precipitation as the dominant factor of CGR IAV. We further analyzed seven terrestrial carbon cycle models, from the TRENDY project, to study the processes underlying CGR IAV. All models capture well the IAV of tropical land-atmosphere carbon flux (CFTA). Sensitivities of the ensemble mean CFTA to temperature and precipitation are 3.18 ± 0.11 Pg C yr-1 K-1 and -0.67 ± 0.04 Pg C yr-1 100 mm-1, close to Mauna Loa CGR. Importantly, the models consistently show the variability in net primary productivity (NPP) dominates CGR, rather than soil respiration. Because NPP is largely driven by precipitation, this suggests a key role of precipitation in CGR IAV despite the higher CGR correlation with temperature. Understanding the relative contribution of CO2 sensitivity to precipitation and temperature has important implications for future carbon-climate feedback using such "emergent constraint".

  17. Application of Temperature Sensitivities During Iterative Strain-Gage Balance Calibration Analysis

    NASA Technical Reports Server (NTRS)

    Ulbrich, N.

    2011-01-01

    A new method is discussed that may be used to correct wind tunnel strain-gage balance load predictions for the influence of residual temperature effects at the location of the strain-gages. The method was designed for the iterative analysis technique that is used in the aerospace testing community to predict balance loads from strain-gage outputs during a wind tunnel test. The new method implicitly applies temperature corrections to the gage outputs during the load iteration process. Therefore, it can use uncorrected gage outputs directly as input for the load calculations. The new method is applied in several steps. First, balance calibration data is analyzed in the usual manner assuming that the balance temperature was kept constant during the calibration. Then, the temperature difference relative to the calibration temperature is introduced as a new independent variable for each strain--gage output. Therefore, sensors must exist near the strain--gages so that the required temperature differences can be measured during the wind tunnel test. In addition, the format of the regression coefficient matrix needs to be extended so that it can support the new independent variables. In the next step, the extended regression coefficient matrix of the original calibration data is modified by using the manufacturer specified temperature sensitivity of each strain--gage as the regression coefficient of the corresponding temperature difference variable. Finally, the modified regression coefficient matrix is converted to a data reduction matrix that the iterative analysis technique needs for the calculation of balance loads. Original calibration data and modified check load data of NASA's MC60D balance are used to illustrate the new method.

  18. Crop responses to climatic variation

    PubMed Central

    Porter, John R; Semenov, Mikhail A

    2005-01-01

    The yield and quality of food crops is central to the well being of humans and is directly affected by climate and weather. Initial studies of climate change on crops focussed on effects of increased carbon dioxide (CO2) level and/or global mean temperature and/or rainfall and nutrition on crop production. However, crops can respond nonlinearly to changes in their growing conditions, exhibit threshold responses and are subject to combinations of stress factors that affect their growth, development and yield. Thus, climate variability and changes in the frequency of extreme events are important for yield, its stability and quality. In this context, threshold temperatures for crop processes are found not to differ greatly for different crops and are important to define for the major food crops, to assist climate modellers predict the occurrence of crop critical temperatures and their temporal resolution. This paper demonstrates the impacts of climate variability for crop production in a number of crops. Increasing temperature and precipitation variability increases the risks to yield, as shown via computer simulation and experimental studies. The issue of food quality has not been given sufficient importance when assessing the impact of climate change for food and this is addressed. Using simulation models of wheat, the concentration of grain protein is shown to respond to changes in the mean and variability of temperature and precipitation events. The paper concludes with discussion of adaptation possibilities for crops in response to drought and argues that characters that enable better exploration of the soil and slower leaf canopy expansion could lead to crop higher transpiration efficiency. PMID:16433091

  19. Variability in Cell Response of Cronobacter sakazakii after Mild-Heat Treatments and Its Impact on Food Safety

    PubMed Central

    Parra-Flores, Julio; Juneja, Vijay; Garcia de Fernando, Gonzalo; Aguirre, Juan

    2016-01-01

    Cronobacter spp. have been responsible for severe infections in infants associated with consumption of powdered infant formula and follow-up formulae. Despite several risk assessments described in published studies, few approaches have considered the tremendous variability in cell response that small micropopulations or single cells can have in infant formula during storage, preparation or post process/preparation before the feeding of infants. Stochastic approaches can better describe microbial single cell response than deterministic models as we prove in this study. A large variability of lag phase was observed in single cell and micropopulations of ≤50 cells. This variability increased as the heat shock increased and growth temperature decreased. Obviously, variability of growth of individual Cronobacter sakazakii cell is affected by inoculum size, growth temperature and the probability of cells able to grow at the conditions imposed by the experimental conditions should be taken into account, especially when errors in bottle-preparation practices, such as improper holding temperatures, or manipulation, may lead to growth of the pathogen to a critical cell level. The mean probability of illness from initial inoculum size of 1 cell was below 0.2 in all the cases and for inoculum size of 50 cells the mean probability of illness, in most of the cases, was above 0.7. PMID:27148223

  20. Identify the dominant variables to predict stream water temperature

    NASA Astrophysics Data System (ADS)

    Chien, H.; Flagler, J.

    2016-12-01

    Stream water temperature is a critical variable controlling water quality and the health of aquatic ecosystems. Accurate prediction of water temperature and the assessment of the impacts of environmental variables on water temperature variation are critical for water resources management, particularly in the context of water quality and aquatic ecosystem sustainability. The objective of this study is to measure stream water temperature and air temperature and to examine the importance of streamflow on stream water temperature prediction. The measured stream water temperature and air temperature will be used to test two hypotheses: 1) streamflow is a relatively more important factor than air temperature in regulating water temperature, and 2) by combining air temperature and streamflow data stream water temperature can be more accurately estimated. Water and air temperature data loggers are placed at two USGS stream gauge stations #01362357and #01362370, located in the upper Esopus Creek watershed in Phonecia, NY. The ARIMA (autoregressive integrated moving average) time series model is used to analyze the measured water temperature data, identify the dominant environmental variables, and predict the water temperature with identified dominant variable. The preliminary results show that streamflow is not a significant variable in predicting stream water temperature at both USGS gauge stations. Daily mean air temperature is sufficient to predict stream water temperature at this site scale.

  1. Performance analysis of the incremental sheet forming on PMMA using a combined chemical and mechanical approach

    NASA Astrophysics Data System (ADS)

    Conte, R.; Gagliardi, F.; Ambrogio, G.; Filice, F.; Russo, P.

    2017-10-01

    Single Point Incremental Forming (SPIF) has been widely investigated highlighting advantages as low-cost, higher formability and greater process flexibility if compared to traditional processes [1]. Recent works have proven the SPIF feasibility for polymers processing. Experimental researches have been carried out with the aim to investigate the influence of several working variables, i.e. spindle speed, tool diameter, step depth, etc., on the final quality of the formed parts [2, 3]. The processed thermoplastic materials are characterized by glass temperatures close to the room temperature and, therefore, SPIF has been performed without external thermal source, exploiting mostly the friction heat generated during the forming phases. In the proposed work, the attention has been focused on extruded poly(methyl methacrylate) (PMMA) sheets, which are characterized by a glass temperature of more than 100 °C. Because of that, an experimental equipment has been designed and the PMMA sheets have been placed on the top of chamber with controlled temperature before SPIF beginning. The temperature on the upper face of the sheets has been monitored by thermocamera, which has been properly set by matching its readings with the ones extracted by a thermocouple in contact with the sheets. SPIF at different temperatures has been carried out by changing both the heater temperature and the process parameters which have an influence on the workpiece heating. The influence of the highlighted process conditions on the worked parts and on the process feasibility has been investigated. Furthermore, examinations on the quality of the formed parts have been performed pointing out the effects that different process conditions have on surface integrity.

  2. An internal variable constitutive model for the large deformation of metals at high temperatures

    NASA Technical Reports Server (NTRS)

    Brown, Stuart; Anand, Lallit

    1988-01-01

    The advent of large deformation finite element methodologies is beginning to permit the numerical simulation of hot working processes whose design until recently has been based on prior industrial experience. Proper application of such finite element techniques requires realistic constitutive equations which more accurately model material behavior during hot working. A simple constitutive model for hot working is the single scalar internal variable model for isotropic thermal elastoplasticity proposed by Anand. The model is recalled and the specific scalar functions, for the equivalent plastic strain rate and the evolution equation for the internal variable, presented are slight modifications of those proposed by Anand. The modified functions are better able to represent high temperature material behavior. The monotonic constant true strain rate and strain rate jump compression experiments on a 2 percent silicon iron is briefly described. The model is implemented in the general purpose finite element program ABAQUS.

  3. Genome scanning for detecting adaptive genes along environmental gradients in the Japanese conifer, Cryptomeria japonica.

    PubMed

    Tsumura, Y; Uchiyama, K; Moriguchi, Y; Ueno, S; Ihara-Ujino, T

    2012-12-01

    Local adaptation is important in evolutionary processes and speciation. We used multiple tests to identify several candidate genes that may be involved in local adaptation from 1026 loci in 14 natural populations of Cryptomeria japonica, the most economically important forestry tree in Japan. We also studied the relationships between genotypes and environmental variables to obtain information on the selective pressures acting on individual populations. Outlier loci were mapped onto a linkage map, and the positions of loci associated with specific environmental variables are considered. The outlier loci were not randomly distributed on the linkage map; linkage group 11 was identified as a genomic island of divergence. Three loci in this region were also associated with environmental variables such as mean annual temperature, daily maximum temperature, maximum snow depth, and so on. Outlier loci identified with high significance levels will be essential for conservation purposes and for future work on molecular breeding.

  4. Separate and combined effects of temperature and precipitation change on maize yields in sub-Saharan Africa for mid- to late-21st century

    NASA Astrophysics Data System (ADS)

    Waha, K.; Müller, C.; Rolinski, S.

    2013-07-01

    Maize (Zea mays L.) is one of the most important food crops and very common in all parts of sub-Saharan Africa. In 2010 53 million tons of maize were produced in sub-Saharan Africa on about one third of the total harvested cropland area (~ 33 million ha). Our aim is to identify the limiting agroclimatic variable for maize growth and development in sub-Saharan Africa by analyzing the separated and combined effects of temperature and precipitation. Under changing climate, both climate variables are projected to change severely, and their impacts on crop yields are frequently assessed using process-based crop models. However it is often unclear which agroclimatic variable will have the strongest influence on crop growth and development under climate change and previous studies disagree over this question.

  5. Combinatorial techniques to efficiently investigate and optimize organic thin film processing and properties.

    PubMed

    Wieberger, Florian; Kolb, Tristan; Neuber, Christian; Ober, Christopher K; Schmidt, Hans-Werner

    2013-04-08

    In this article we present several developed and improved combinatorial techniques to optimize processing conditions and material properties of organic thin films. The combinatorial approach allows investigations of multi-variable dependencies and is the perfect tool to investigate organic thin films regarding their high performance purposes. In this context we develop and establish the reliable preparation of gradients of material composition, temperature, exposure, and immersion time. Furthermore we demonstrate the smart application of combinations of composition and processing gradients to create combinatorial libraries. First a binary combinatorial library is created by applying two gradients perpendicular to each other. A third gradient is carried out in very small areas and arranged matrix-like over the entire binary combinatorial library resulting in a ternary combinatorial library. Ternary combinatorial libraries allow identifying precise trends for the optimization of multi-variable dependent processes which is demonstrated on the lithographic patterning process. Here we verify conclusively the strong interaction and thus the interdependency of variables in the preparation and properties of complex organic thin film systems. The established gradient preparation techniques are not limited to lithographic patterning. It is possible to utilize and transfer the reported combinatorial techniques to other multi-variable dependent processes and to investigate and optimize thin film layers and devices for optical, electro-optical, and electronic applications.

  6. A plant’s perspective of extremes: Terrestrial plant responses to changing climatic variability

    PubMed Central

    Reyer, C.; Leuzinger, S.; Rammig, A.; Wolf, A.; Bartholomeus, R. P.; Bonfante, A.; de Lorenzi, F.; Dury, M.; Gloning, P.; Abou Jaoudé, R.; Klein, T.; Kuster, T. M.; Martins, M.; Niedrist, G.; Riccardi, M.; Wohlfahrt, G.; de Angelis, P.; de Dato, G.; François, L.; Menzel, A.; Pereira, M.

    2013-01-01

    We review observational, experimental and model results on how plants respond to extreme climatic conditions induced by changing climatic variability. Distinguishing between impacts of changing mean climatic conditions and changing climatic variability on terrestrial ecosystems is generally underrated in current studies. The goals of our review are thus (1) to identify plant processes that are vulnerable to changes in the variability of climatic variables rather than to changes in their mean, and (2) to depict/evaluate available study designs to quantify responses of plants to changing climatic variability. We find that phenology is largely affected by changing mean climate but also that impacts of climatic variability are much less studied but potentially damaging. We note that plant water relations seem to be very vulnerable to extremes driven by changes in temperature and precipitation and that heatwaves and flooding have stronger impacts on physiological processes than changing mean climate. Moreover, interacting phenological and physiological processes are likely to further complicate plant responses to changing climatic variability. Phenological and physiological processes and their interactions culminate in even more sophisticated responses to changing mean climate and climatic variability at the species and community level. Generally, observational studies are well suited to study plant responses to changing mean climate, but less suitable to gain a mechanistic understanding of plant responses to climatic variability. Experiments seem best suited to simulate extreme events. In models, temporal resolution and model structure are crucial to capture plant responses to changing climatic variability. We highlight that a combination of experimental, observational and /or modeling studies have the potential to overcome important caveats of the respective individual approaches. PMID:23504722

  7. Variations in Upper-Tropospheric Humidity and Convective Processes as Seen from SSM/T-2

    NASA Technical Reports Server (NTRS)

    Robertson, Franklin R.; Fitzjarrald, Dan E.

    2007-01-01

    Water vapor feedback, particularly involving water vapor in the upper troposphere (UTH), is widely regarded as the process with the most potential to amplify anthropogenic greenhouse forcing. Yet, our ability to quantify observationally water vapor variations in the current climate and the relationships to convective processes remains rather crude. Remote sensing from polar orbiting instruments has played a major role in documenting UTH variability, supplementing highly undersampled and poorly calibrated rawinsonde measurements. Most of our observational understanding of UTH has come from the 6.7 micrometer channel measurements which are subject to cloud contamination uncertainties. In this work we examine UTH variations present in the Special Sensor Microwave Temperature Sounder 2 (SSM/T-2) sensors flying aboard Defense Military Satellite Program (DMSP) polar orbiting satellites during the period 1993 through 2001. We employ data from the the 183.3 +/- 1 GHz channel which is far less sensitive to cirrus than IR methods. Our primary focus is on obtaining more reliable statistics of interannual behavior; i.e. How close to constant RH are interannual variations in T2 UTH over the tropics? How do temperature and moisture variations contribute regionally? The 1997/1998 strong ENS0 warming event and adjacent cool periods provide a strong signal to study, albeit a perturbation of natural climate variability. Modeling the 183.3 GHz channel using reanalysis temperature data, but with climatological water vapor, allows us to infer the separate contribution by water vapor in the observations. In addition, frozen hydrometeors produced by deep convection are also captured in the 150 GHz oxygen channel, providing an opportUnity to relate the incidence of deep convection to water vapor variability. Our results indicate a much larger variation of 183.3 GHz brightness temperatures would be observed were it not for water vapor variations positively correlated with tropical SSTs. Comparisons are made with previous studies using both IR and microwave observations to characterize UTH response to tropical SSTs.

  8. Multivariate Models of Adult Pacific Salmon Returns

    PubMed Central

    Burke, Brian J.; Peterson, William T.; Beckman, Brian R.; Morgan, Cheryl; Daly, Elizabeth A.; Litz, Marisa

    2013-01-01

    Most modeling and statistical approaches encourage simplicity, yet ecological processes are often complex, as they are influenced by numerous dynamic environmental and biological factors. Pacific salmon abundance has been highly variable over the last few decades and most forecasting models have proven inadequate, primarily because of a lack of understanding of the processes affecting variability in survival. Better methods and data for predicting the abundance of returning adults are therefore required to effectively manage the species. We combined 31 distinct indicators of the marine environment collected over an 11-year period into a multivariate analysis to summarize and predict adult spring Chinook salmon returns to the Columbia River in 2012. In addition to forecasts, this tool quantifies the strength of the relationship between various ecological indicators and salmon returns, allowing interpretation of ecosystem processes. The relative importance of indicators varied, but a few trends emerged. Adult returns of spring Chinook salmon were best described using indicators of bottom-up ecological processes such as composition and abundance of zooplankton and fish prey as well as measures of individual fish, such as growth and condition. Local indicators of temperature or coastal upwelling did not contribute as much as large-scale indicators of temperature variability, matching the spatial scale over which salmon spend the majority of their ocean residence. Results suggest that effective management of Pacific salmon requires multiple types of data and that no single indicator can represent the complex early-ocean ecology of salmon. PMID:23326586

  9. Optimization of a pharmaceutical freeze-dried product and its process using an experimental design approach and innovative process analyzers.

    PubMed

    De Beer, T R M; Wiggenhorn, M; Hawe, A; Kasper, J C; Almeida, A; Quinten, T; Friess, W; Winter, G; Vervaet, C; Remon, J P

    2011-02-15

    The aim of the present study was to examine the possibilities/advantages of using recently introduced in-line spectroscopic process analyzers (Raman, NIR and plasma emission spectroscopy), within well-designed experiments, for the optimization of a pharmaceutical formulation and its freeze-drying process. The formulation under investigation was a mannitol (crystalline bulking agent)-sucrose (lyo- and cryoprotector) excipient system. The effects of two formulation variables (mannitol/sucrose ratio and amount of NaCl) and three process variables (freezing rate, annealing temperature and secondary drying temperature) upon several critical process and product responses (onset and duration of ice crystallization, onset and duration of mannitol crystallization, duration of primary drying, residual moisture content and amount of mannitol hemi-hydrate in end product) were examined using a design of experiments (DOE) methodology. A 2-level fractional factorial design (2(5-1)=16 experiments+3 center points=19 experiments) was employed. All experiments were monitored in-line using Raman, NIR and plasma emission spectroscopy, which supply continuous process and product information during freeze-drying. Off-line X-ray powder diffraction analysis and Karl-Fisher titration were performed to determine the morphology and residual moisture content of the end product, respectively. In first instance, the results showed that - besides the previous described findings in De Beer et al., Anal. Chem. 81 (2009) 7639-7649 - Raman and NIR spectroscopy are able to monitor the product behavior throughout the complete annealing step during freeze-drying. The DOE approach allowed predicting the optimum combination of process and formulation parameters leading to the desired responses. Applying a mannitol/sucrose ratio of 4, without adding NaCl and processing the formulation without an annealing step, using a freezing rate of 0.9°C/min and a secondary drying temperature of 40°C resulted in efficient freeze-drying supplying end products with a residual moisture content below 2% and a mannitol hemi-hydrate content below 20%. Finally, using Monte Carlo simulations it became possible to determine how varying the factor settings around their optimum still leads to fulfilled response criteria, herewith having an idea about the probability to exceed the acceptable response limits. This multi-dimensional combination and interaction of input variables (factor ranges) leading to acceptable response criteria with an acceptable probability reflects the process design space. Copyright © 2010 Elsevier B.V. All rights reserved.

  10. Interaction Between Ecohydrologic Dynamics and Microtopographic Variability Under Climate Change

    NASA Astrophysics Data System (ADS)

    Le, Phong V. V.; Kumar, Praveen

    2017-10-01

    Vegetation acclimation resulting from elevated atmospheric CO2 concentration, along with response to increased temperature and altered rainfall pattern, is expected to result in emergent behavior in ecologic and hydrologic functions. We hypothesize that microtopographic variability, which are landscape features typically of the length scale of the order of meters, such as topographic depressions, will play an important role in determining this dynamics by altering the persistence and variability of moisture. To investigate these emergent ecohydrologic dynamics, we develop a modeling framework, Dhara, which explicitly incorporates the control of microtopographic variability on vegetation, moisture, and energy dynamics. The intensive computational demand from such a modeling framework that allows coupling of multilayer modeling of the soil-vegetation continuum with 3-D surface-subsurface flow processes is addressed using hybrid CPU-GPU parallel computing framework. The study is performed for different climate change scenarios for an intensively managed agricultural landscape in central Illinois, USA, which is dominated by row-crop agriculture, primarily soybean (Glycine max) and maize (Zea mays). We show that rising CO2 concentration will decrease evapotranspiration, thus increasing soil moisture and surface water ponding in topographic depressions. However, increased atmospheric demand from higher air temperature overcomes this conservative behavior resulting in a net increase of evapotranspiration, leading to reduction in both soil moisture storage and persistence of ponding. These results shed light on the linkage between vegetation acclimation under climate change and microtopography variability controls on ecohydrologic processes.

  11. Current understanding of the effects of enviromental and irradiation variables on RPV embrittlement

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Odette, G.R.; Lucas, G.E.; Wirth, B.

    1997-02-01

    Radiation enhanced diffusion at RPV operating temperatures around 290{degrees}C leads to the formation of various ultrafine scale hardening phases, including copper-rich and copper-catalyzed manganese-nickel rich precipitates. In addition, defect cluster or cluster-solute complexes, manifesting a range of thermal stability, develop under irradiation. These features contribute directly to hardening which in turn is related to embrittlement, manifested as shifts in Charpy V-notch transition temperature. Models based on the thermodynamics, kinetics and micromechanics of the embrittlement processes have been developed; these are broadly consistent with experiment and rationalize the highly synergistic effects of most important irradiation (temperature, flux, fluence) and metallurgical (copper,more » nickel, manganese, phosphorous and heat treatment) variables on both irradiation hardening and recovery during post-irradiation annealing. A number of open questions remain which can be addressed with a hierarchy of new theoretical and experimental tools.« less

  12. Annually and monthly resolved solar irradiance and atmospheric temperature data across the Hawaiian archipelago from 1998 to 2015 with interannual summary statistics.

    PubMed

    Bryce, Richard; Losada Carreño, Ignacio; Kumler, Andrew; Hodge, Bri-Mathias; Roberts, Billy; Brancucci Martinez-Anido, Carlo

    2018-08-01

    This article contains data and summary statistics of solar irradiance and dry bulb temperature across the Hawaiian archipelago resolved on a monthly basis and spanning years 1998-2015. This data was derived in association with an article titled "Consequences of Neglecting the Interannual Variability of the Solar Resource: A Case Study of Photovoltaic Power Among the Hawaiian Islands" (Bryce et al., 2018 [7]). The solar irradiance data is presented in terms of Direct Normal Irradiance (DNI), Diffuse Horizontal Irradiance (DHI), and Global Horizontal Irradiance (GHI) and was obtained from the satellite-derived data contained in the National Solar Radiation Database (NSRDB). The temperature data is also obtained from this source. We have processed the NSRDB data and compiled these monthly resolved data sets, along with interannual summary statistics including the interannual coefficient of variability.

  13. Effects of convective ice evaporation on interannual variability of tropical tropopause layer water vapor

    NASA Astrophysics Data System (ADS)

    Ye, Hao; Dessler, Andrew E.; Yu, Wandi

    2018-04-01

    Water vapor interannual variability in the tropical tropopause layer (TTL) is investigated using satellite observations and model simulations. We break down the influences of the Brewer-Dobson circulation (BDC), the quasi-biennial oscillation (QBO), and the tropospheric temperature (ΔT) on TTL water vapor as a function of latitude and longitude using a two-dimensional multivariate linear regression. This allows us to examine the spatial distribution of the impact of each process on TTL water vapor. In agreement with expectations, we find that the impacts from the BDC and QBO act on TTL water vapor by changing TTL temperature. For ΔT, we find that TTL temperatures alone cannot explain the influence. We hypothesize a moistening role for the evaporation of convective ice from increased deep convection as the troposphere warms. Tests using a chemistry-climate model, the Goddard Earth Observing System Chemistry Climate Model (GEOSCCM), support this hypothesis.

  14. Understanding Climate Variability of Urban Ecosystems Through the Lens of Citizen Science

    NASA Astrophysics Data System (ADS)

    Ripplinger, J.; Jenerette, D.; Wang, J.; Chandler, M.; Ge, C.; Koutzoukis, S.

    2017-12-01

    The Los Angeles megacity is vulnerable to climate warming - a process that locally exacerbates the urban heat island effect as it intensifies with size and density of the built-up area. We know that large-scale drivers play a role, but in order to understand local-scale climate variation, more research is needed on the biophysical and sociocultural processes driving the urban climate system. In this study, we work with citizen scientists to deploy a high-density network of microsensors across a climate gradient to characterize geographic variation in neighborhood meso- and micro-climates. This research asks: How do urbanization, global climate, and vegetation interact across multiple scales to affect local-scale experiences of temperature? Additionally, citizen scientist-led efforts generated research questions focused on examining microclimatic differences among yard groundcover types (rock mulch vs. lawn vs. artificial turf) and also on variation in temperature related to tree cover. Combining sensor measurements with Weather Research and Forecasting (WRF) spatial models and satellite-based temperature, we estimate spatially-explicit maps of land surface temperature and air temperature to illustrate the substantial difference between surface and air urban heat island intensities and the variable degree of coupling between land surface and air temperature in urban areas. Our results show a strong coupling between air temperature variation and landcover for neighborhoods, with significant detectable signatures from tree cover and impervious surface. Temperature covaried most strongly with urbanization intensity at nighttime during peak summer season, when daily mean air temperature ranged from 12.8C to 30.4C across all groundcover types. The combined effects of neighborhood geography and vegetation determine where and how temperature and tree canopy vary within a city. This citizen science-enabled research shows how large-scale climate drivers and urbanization intensity jointly influence the nature and magnitude of coupling between air temperature and tree cover, and demonstrate how urban vegetation provides an important ecosystem service in cities by decreasing the intensity of local urban heat islands.

  15. Modeling temperature and humidity profiles within forest canopies

    USDA-ARS?s Scientific Manuscript database

    Physically-based models are a powerful tool to help understand interactions of vegetation, atmospheric dynamics, and hydrology, and to test hypotheses regarding the effects of land cover, management, hydrometeorology, and climate variability on ecosystem processes. The purpose of this paper is to f...

  16. Residue decomposition of submodel of WEPS

    USDA-ARS?s Scientific Manuscript database

    The Residue Decomposition submodel of the Wind Erosion Prediction System (WEPS) simulates the decrease in crop residue biomass due to microbial activity. The decomposition process is modeled as a first-order reaction with temperature and moisture as driving variables. Decomposition is a function of ...

  17. Relationship between the Arctic oscillation and surface air temperature in multi-decadal time-scale

    NASA Astrophysics Data System (ADS)

    Tanaka, Hiroshi L.; Tamura, Mina

    2016-09-01

    In this study, a simple energy balance model (EBM) was integrated in time, considering a hypothetical long-term variability in ice-albedo feedback mimicking the observed multi-decadal temperature variability. A natural variability was superimposed on a linear warming trend due to the increasing radiative forcing of CO2. The result demonstrates that the superposition of the natural variability and the background linear trend can offset with each other to show the warming hiatus for some period. It is also stressed that the rapid warming during 1970-2000 can be explained by the superposition of the natural variability and the background linear trend at least within the simple model. The key process of the fluctuating planetary albedo in multi-decadal time scale is investigated using the JRA-55 reanalysis data. It is found that the planetary albedo increased for 1958-1970, decreased for 1970-2000, and increased for 2000-2012, as expected by the simple EBM experiments. The multi-decadal variability in the planetary albedo is compared with the time series of the AO mode and Barents Sea mode of surface air temperature. It is shown that the recent AO negative pattern showing warm Arctic and cold mid-latitudes is in good agreement with planetary albedo change indicating negative anomaly in high latitudes and positive anomaly in mid-latitudes. Moreover, the Barents Sea mode with the warm Barents Sea and cold mid-latitudes shows long-term variability similar to planetary albedo change. Although further studies are needed, the natural variabilities of both the AO mode and Barents Sea mode indicate some possible link to the planetary albedo as suggested by the simple EBM to cause the warming hiatus in recent years.

  18. Influence of temperature on the single-stage ATAD process predicted by a thermal equilibrium model.

    PubMed

    Cheng, Jiehong; Zhu, Jun; Kong, Feng; Zhang, Chunyong

    2015-06-01

    Autothermal thermophilic aerobic digestion (ATAD) is a promising biological process that will produce an effluent satisfying the Class A requirements on pathogen control and land application. The thermophilic temperature in an ATAD reactor is one of the critical factors that can affect the satisfactory operation of the ATAD process. This paper established a thermal equilibrium model to predict the effect of variables on the auto-rising temperature in an ATAD system. The reactors with volumes smaller than 10 m(3) could not achieve temperatures higher than 45 °C under ambient temperature of -5 °C. The results showed that for small reactors, the reactor volume played a key role in promoting auto-rising temperature in the winter. Thermophilic temperature achieved in small ATAD reactors did not entirely depend on the heat release from biological activities during degrading organic matters in sludges, but was related to the ambient temperature. The ratios of surface area-to-effective volume less than 2.0 had less impact on the auto-rising temperature of an ATAD reactor. The influence of ambient temperature on the auto-rising reactor temperature decreased with increasing reactor volumes. High oxygen transfer efficiency had a significant influence on the internal temperature rise in an ATAD system, indicating that improving the oxygen transfer efficiency of aeration devices was a key factor to achieve a higher removal rate of volatile solids (VS) during the ATAD process operation. Compared with aeration using cold air, hot air demonstrated a significant effect on maintaining the internal temperature (usually 4-5 °C higher). Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. Global lake response to the recent warming hiatus

    NASA Astrophysics Data System (ADS)

    Winslow, Luke A.; Leach, Taylor H.; Rose, Kevin C.

    2018-05-01

    Understanding temporal variability in lake warming rates over decadal scales is important for understanding observed change in aquatic systems. We analyzed a global dataset of lake surface water temperature observations (1985‑2009) to examine how lake temperatures responded to a recent global air temperature warming hiatus (1998‑2012). Prior to the hiatus (1985‑1998), surface water temperatures significantly increased at an average rate of 0.532 °C decade‑1 (±0.214). In contrast, water temperatures did not change significantly during the hiatus (average rate ‑0.087 °C decade‑1 ±0.223). Overall, 83% of lakes in our dataset (129 of 155) had faster warming rates during the pre-hiatus period than during the hiatus period. These results demonstrate that lakes have exhibited decadal-scale variability in warming rates coherent with global air temperatures and represent an independent line of evidence for the recent warming hiatus. Our analyses provide evidence that lakes are sentinels of broader climatological processes and indicate that warming rates based on datasets where a large proportion of observations were collected during the hiatus period may underestimate longer-term trends.

  20. Broad timescale forcing and geomorphic mediation of tidal marsh flow and temperature dynamics

    USGS Publications Warehouse

    Enwright, Christopher; Culberson, Steven; Burau, Jon R.

    2013-01-01

    Tidal marsh functions are driven by interactions between tides, landscape morphology, and emergent vegetation. Less often considered are the diurnal pattern of tide extremes and seasonal variation of solar insolation in the mix of tidal marsh driver interactions. This work demonstrates how high-frequency hydroperiod and water temperature variability emerges from disparate timescale interactions between tidal marsh morphology, tidal harmonics, and meteorology in the San Francisco Estuary. We compare the tidal and residual flow and temperature response of neighboring tidal sloughs, one possessing natural tidal marsh morphology, and one that is modified for water control. We show that the natural tidal marsh is tuned to lunar phase and produces tidal and fortnight water temperature variability through interacting tide, meteorology, and geomorphic linkages. In contrast, temperature variability is dampened in the modified slough where overbank marsh plain connection is severed by levees. Despite geomorphic differences, a key finding is that both sloughs are heat sinks in summer by latent heat flux-driven residual upstream water advection and sensible and long-wave heat transfer. The precession of a 335-year tidal harmonic assures that these dynamics will shift in the future. Water temperature regulation appears to be a key function of natural tidal sloughs that depends critically on geomorphic mediation. We investigate approaches to untangling the relative influence of sun versus tide on residual water and temperature transport as a function of system morphology. The findings of this study likely have ecological consequences and suggest physical process metrics for tidal marsh restoration performance.

  1. Means and extremes: building variability into community-level climate change experiments.

    PubMed

    Thompson, Ross M; Beardall, John; Beringer, Jason; Grace, Mike; Sardina, Paula

    2013-06-01

    Experimental studies assessing climatic effects on ecological communities have typically applied static warming treatments. Although these studies have been informative, they have usually failed to incorporate either current or predicted future, patterns of variability. Future climates are likely to include extreme events which have greater impacts on ecological systems than changes in means alone. Here, we review the studies which have used experiments to assess impacts of temperature on marine, freshwater and terrestrial communities, and classify them into a set of 'generations' based on how they incorporate variability. The majority of studies have failed to incorporate extreme events. In terrestrial ecosystems in particular, experimental treatments have reduced temperature variability, when most climate models predict increased variability. Marine studies have tended to not concentrate on changes in variability, likely in part because the thermal mass of oceans will moderate variation. In freshwaters, climate change experiments have a much shorter history than in the other ecosystems, and have tended to take a relatively simple approach. We propose a new 'generation' of climate change experiments using down-scaled climate models which incorporate predicted changes in climatic variability, and describe a process for generating data which can be applied as experimental climate change treatments. © 2013 John Wiley & Sons Ltd/CNRS.

  2. The optimization of phenolic compounds extraction from cactus pear (Opuntia ficus-indica) skin in a reflux system using response surface methodology

    PubMed Central

    Jorge, Aguirre Joya; Heliodoro, De La Garza Toledo; Alejandro, Zugasti Cruz; Ruth, Belmares Cerda; Noé, Aguilar Cristóbal

    2013-01-01

    Objective To extract, quantify, and evaluate the phenolic content in Opuntia ficus-indica skin for their antioxidant capacity with three different methods (ABTS, DPPH, and lipid oxidation) and to optimize the extraction conditions (time, temperature and ethanol concentration) in a reflux system. Methods The extraction process was done using a reflux system. A San Cristobal II experimental design with three variables and three levels was used. The variables evaluated were time of extraction (h), concentration of ethanol (%, v/v) and temperature (°C). The extraction process was optimized using a response surface methodology. Results It was observed that at higher temperature more phenolic compounds were extracted, but the antioxidant capacity was decreased. The optimum conditions for phenolic compounds extraction and antioxidant capacity mixing the three methods were as follows: 45% of ethanol, 80 °C and 2 hours of extraction. Values obtained in our results are little higher that other previously reported. Conclusions It can be concluded the by-products of Opuntia ficus-indica represent a good source of natural antioxidants with possible applications in food, cosmetics or drugs industries. PMID:23730555

  3. A Numerical Evaluation on the Viability of Heap Thermophilic Bioleaching of Chalcopyrite

    NASA Astrophysics Data System (ADS)

    Vilcaez, J.; Suto, K.; Inoue, C.

    2007-03-01

    The present numerical evaluation explores into the interactions among the many variables governing the mass and heat transport processes that take place in a heap thermophilic bioleaching system. The necessity of using mesophiles together with thermophiles is proved by tracing the activity of both microorganisms individually at each point throughout the heap. The role of key variables such as the fraction of FeS2 per CuFeS2 leached was quantified and its importance highlighted. In this evaluation, the heat transfer process plays the main role because of the heat accumulation required to maintain the heap temperature within the range of 60 °C to 80 °C where thermophilic microorganisms are capable of completing the unfinished dissolution of copper started by mesophilic microorganisms at 30 °C. The evaluation was done taking into consideration: biological activity as function of the temperature in the heap, heat loss due to conduction and advection from the top and bottom of the heap, and mass transfer between the gas and liquid phases as a function of temperature. The exothermic nature of the leaching reactions of CuFeS2 and FeS2 makes the system auto-thermal.

  4. Ecological determinants of mean family age of angiosperm trees in forest communities in China

    NASA Astrophysics Data System (ADS)

    Qian, Hong; Chen, Shengbin

    2016-06-01

    Species assemblage in a local community is determined by the interplay of evolutionary and ecological processes. The Tropical Niche Conservatism hypothesis proposes mechanisms underlying patterns of biodiversity in biological communities along environmental gradients. This hypothesis predicts that, among other things, clades in areas with warm or wet environments are, on average, older than those in areas with cold or dry environments. Focusing on angiosperm trees in forests, this study tested the age-related prediction of the Tropical Niche Conservatism hypothesis. We related the mean family age of angiosperm trees in 57 local forests from across China with 23 current and paleo-environmental variables, which included all major temperature- and precipitation-related variables. Our study shows that the mean family age of angiosperm trees in local forests was positively correlated with temperature and precipitation. This finding is consistent with the age-related prediction of the Tropical Niche Conservatism hypothesis. Approximately 85% of the variance in the mean family age of angiosperm trees was explained by temperature-related variables, and 81% of the variance in the mean family age of angiosperm trees was explained by precipitation-related variables. Climatic conditions at the Last Glacial Maximum did not explain additional variation in mean family age after accounting for current environmental conditions.

  5. Landscape genomics of Sphaeralcea ambigua in the Mojave Desert: a multivariate, spatially-explicit approach to guide ecological restoration

    USGS Publications Warehouse

    Shryock, Daniel F.; Havrilla, Caroline A.; DeFalco, Lesley; Esque, Todd C.; Custer, Nathan; Wood, Troy E.

    2015-01-01

    Local adaptation influences plant species’ responses to climate change and their performance in ecological restoration. Fine-scale physiological or phenological adaptations that direct demographic processes may drive intraspecific variability when baseline environmental conditions change. Landscape genomics characterize adaptive differentiation by identifying environmental drivers of adaptive genetic variability and mapping the associated landscape patterns. We applied such an approach to Sphaeralcea ambigua, an important restoration plant in the arid southwestern United States, by analyzing variation at 153 amplified fragment length polymorphism loci in the context of environmental gradients separating 47 Mojave Desert populations. We identified 37 potentially adaptive loci through a combination of genome scan approaches. We then used a generalized dissimilarity model (GDM) to relate variability in potentially adaptive loci with spatial gradients in temperature, precipitation, and topography. We identified non-linear thresholds in loci frequencies driven by summer maximum temperature and water stress, along with continuous variation corresponding to temperature seasonality. Two GDM-based approaches for mapping predicted patterns of local adaptation are compared. Additionally, we assess uncertainty in spatial interpolations through a novel spatial bootstrapping approach. Our study presents robust, accessible methods for deriving spatially-explicit models of adaptive genetic variability in non-model species that will inform climate change modelling and ecological restoration.

  6. Effects of Northern Hemisphere Sea Surface Temperature Changes on the Global Air Quality

    NASA Astrophysics Data System (ADS)

    Yi, K.; Liu, J.

    2017-12-01

    The roles of regional sea surface temperature (SST) variability on modulating the climate system and consequently the air quality are investigated using the Community Earth System Model (CESM). Idealized, spatially uniform SST anomalies of +/- 1 °C are superimposed onto the North Pacific, North Atlantic, and North Indian Oceans individually. Ignoring the response of natural emissions, our simulations suggest large seasonal and regional variability of surface O3 and PM2.5 concentrations in response to SST anomalies, especially during boreal summers. Increasing the SST by 1 °C in one of the oceans generally decreases the surface O3 concentrations from 1 to 5 ppbv while increases the anthropogenic PM2.5 concentrations from 0.5 to 3 µg m-3. We implement the integrated process rate (IPR) analysis in CESM and find that meteorological transport in response to SST changes is the key process causing air pollutant perturbations in most cases. During boreal summers, the increase in tropical SST over different ocean basins enhances deep convection, which significantly increases the air temperature over the upper troposphere and trigger large-scale subsidence over nearby and remote regions. These processes tend to increase tropospheric stability and suppress rainfall at lower mid-latitudes. Consequently, it reduces the vertical transport of O3 to the surface while facilitating the accumulation of PM2.5 concentrations over most regions. In addition, this regional SST warming may also considerably suppress intercontinental transport of air pollution as confirmed with idealized CO-like tracers. Our findings indicate a robust linkage between basin-scale SST variability and regional air quality, which can help local air quality management.

  7. Global land-atmosphere coupling associated with cold climate processes

    NASA Astrophysics Data System (ADS)

    Dutra, Emanuel

    This dissertation constitutes an assessment of the role of cold processes, associated with snow cover, in controlling the land-atmosphere coupling. The work was based on model simulations, including offline simulations with the land surface model HTESSEL, and coupled atmosphere simulations with the EC-EARTH climate model. A revised snow scheme was developed and tested in HTESSEL and EC-EARTH. The snow scheme is currently operational at the European Centre for Medium-Range Weather Forecasts integrated forecast system, and in the default configuration of EC-EARTH. The improved representation of the snowpack dynamics in HTESSEL resulted in improvements in the near surface temperature simulations of EC-EARTH. The new snow scheme development was complemented with the option of multi-layer version that showed its potential in modeling thick snowpacks. A key process was the snow thermal insulation that led to significant improvements of the surface water and energy balance components. Similar findings were observed when coupling the snow scheme to lake ice, where lake ice duration was significantly improved. An assessment on the snow cover sensitivity to horizontal resolution, parameterizations and atmospheric forcing within HTESSEL highlighted the role of the atmospheric forcing accuracy and snowpack parameterizations in detriment of horizontal resolution over flat regions. A set of experiments with and without free snow evolution was carried out with EC-EARTH to assess the impact of the interannual variability of snow cover on near surface and soil temperatures. It was found that snow cover interannual variability explained up to 60% of the total interannual variability of near surface temperature over snow covered regions. Although these findings are model dependent, the results showed consistency with previously published work. Furthermore, the detailed validation of the snow dynamics simulations in HTESSEL and EC-EARTH guarantees consistency of the results.

  8. Multiscale Model Simulations of Temperature and Relative Humidity for the License Application of the Proposed Yucca Mountain Repository

    NASA Astrophysics Data System (ADS)

    Buscheck, T.; Glascoe, L.; Sun, Y.; Gansemer, J.; Lee, K.

    2003-12-01

    For the proposed Yucca Mountain geologic repository for high-level nuclear waste, the planned method of disposal involves the emplacement of cylindrical packages containing the waste inside horizontal tunnels, called emplacement drifts, bored several hundred meters below the ground surface. The emplacement drifts reside in highly fractured, partially saturated volcanic tuff. An important phenomenological consideration for the licensing of the proposed repository at Yucca Mountain is the generation of decay heat by the emplaced waste and the consequences of this decay heat. Changes in temperature will affect the hydrologic and chemical environment at Yucca Mountain. A thermohydrologic-modeling tool is necessary to support the performance assessment of the Engineered Barrier System (EBS) of the proposed repository. This modeling tool must simultaneously account for processes occurring at a scale of a few tens of centimeters around individual waste packages, for processes occurring around the emplacement drifts themselves, and for processes occurring at the multi-kilometer scale of the mountain. Additionally, many other features must be considered including non-isothermal, multiphase-flow in fractured porous rock of variable liquid-phase saturation and thermal radiation and convection in open cavities. The Multiscale Thermohydrologic Model (MSTHM) calculates the following thermohydrologic (TH) variables: temperature, relative humidity, liquid-phase saturation, evaporation rate, air-mass fraction, gas-phase pressure, capillary pressure, and liquid- and gas-phase fluxes. The TH variables are determined as a function of position along each of the emplacement drifts in the repository and as a function of waste-package (WP) type. These variables are determined at various generic locations within the emplacement drifts, including the waste package and drip-shield surfaces and in the invert; they are also determined at various generic locations in the adjoining host rock; these variables are determined every 20 m for each emplacement drift in the repository. The MSTHM accounts for 3-D drift-scale and mountain-scale heat flow and captures the influence of the key engineering-design variables and natural-system factors affecting TH conditions in the emplacement drifts and adjoining host rock. Presented is a synopsis of recent MSTHM calculations conducted to support the Total System Performance Assessment for the License Application (TSPA-LA). This work was performed under the auspices of the U.S. Department of Energy by University of California Lawrence Livermore National Laboratory under contract No. W-7405-Eng-48.

  9. Formulation characteristics and in vitro release testing of cyclosporine ophthalmic ointments.

    PubMed

    Dong, Yixuan; Qu, Haiou; Pavurala, Naresh; Wang, Jiang; Sekar, Vasanthakumar; Martinez, Marilyn N; Fahmy, Raafat; Ashraf, Muhammad; Cruz, Celia N; Xu, Xiaoming

    2018-06-10

    The aim of the present study was to investigate the relationship between formulation/process variables versus the critical quality attributes (CQAs) of cyclosporine ophthalmic ointments and to explore the feasibility of using an in vitro approach to assess product sameness. A definitive screening design (DSD) was used to evaluate the impact of formulation and process variables. The formulation variables included drug percentage, percentage of corn oil and lanolin alcohol. The process variables studied were mixing temperature, mixing time and the method of mixing. The quality and performance attributes examined included drug assay, content uniformity, image analysis, rheology (storage modulus, shear viscosity) and in vitro drug release. Of the formulation variables evaluated, the percentage of the drug substance and the percentage of corn oil in the matrix were the most influential factors with respect to in vitro drug release. Conversely, the process parameters tested were observed to have minimal impact. An evaluation of the release mechanism of cyclosporine from the ointment revealed an interplay between formulation (e.g. physicochemical properties of the drug and ointment matrix type) and the release medium. These data provide a scientific basis to guide method development for in vitro drug release testing of ointment dosage forms. These results demonstrate that the in vitro methods used in this investigation were fit-for-purpose for detecting formulation and process changes and therefore amenable to assessment of product sameness. Published by Elsevier B.V.

  10. Quantifying the processes controlling intraseasonal mixed-layer temperature variability in the tropical Indian Ocean

    NASA Astrophysics Data System (ADS)

    Halkides, D. J.; Waliser, Duane E.; Lee, Tong; Menemenlis, Dimitris; Guan, Bin

    2015-02-01

    Spatial and temporal variation of processes that determine ocean mixed-layer (ML) temperature (MLT) variability on the timescale of the Madden-Julian Oscillation (MJO) in the Tropical Indian Ocean (TIO) are examined in a heat-conserving ocean state estimate for years 1993-2011. We introduce a new metric for representing spatial variability of the relative importance of processes. In general, horizontal advection is most important at the Equator. Subsurface processes and surface heat flux are more important away from the Equator, with surface heat flux being the more dominant factor. Analyses at key sites are discussed in the context of local dynamics and literature. At 0°, 80.5°E, for MLT events > 2 standard deviations, ocean dynamics account for more than two thirds of the net tendency during cooling and warming phases. Zonal advection alone accounts for ˜40% of the net tendency. Moderate events (1-2 standard deviations) show more differences between events, and some are dominated by surface heat flux. At 8°S, 67°E in the Seychelles-Chagos Thermocline Ridge (SCTR) area, surface heat flux accounts for ˜70% of the tendency during strong cooling and warming phases; subsurface processes linked to ML depth (MLD) deepening (shoaling) during cooling (warming) account for ˜30%. MLT is more sensitive to subsurface processes in the SCTR, due to the thin MLD, thin barrier layer and raised thermocline. Results for 8°S, 67°E support assertions by Vialard et al. (2008) not previously confirmed due to measurement error that prevented budget closure and the small number of events studied. The roles of MLD, barrier layer thickness, and thermocline depth on different timescales are examined.

  11. Modeling and Validation of a Three-Stage Solidification Model for Sprays

    NASA Astrophysics Data System (ADS)

    Tanner, Franz X.; Feigl, Kathleen; Windhab, Erich J.

    2010-09-01

    A three-stage freezing model and its validation are presented. In the first stage, the cooling of the droplet down to the freezing temperature is described as a convective heat transfer process in turbulent flow. In the second stage, when the droplet has reached the freezing temperature, the solidification process is initiated via nucleation and crystal growth. The latent heat release is related to the amount of heat convected away from the droplet and the rate of solidification is expressed with a freezing progress variable. After completion of the solidification process, in stage three, the cooling of the solidified droplet (particle) is described again by a convective heat transfer process until the particle approaches the temperature of the gaseous environment. The model has been validated by experimental data of a single cocoa butter droplet suspended in air. The subsequent spray validations have been performed with data obtained from a cocoa butter melt in an experimental spray tower using the open-source computational fluid dynamics code KIVA-3.

  12. A stepwise-cluster microbial biomass inference model in food waste composting

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sun Wei; Huang, Guo H., E-mail: huangg@iseis.or; Chinese Research Academy of Environmental Science, North China Electric Power University, Beijing 100012-102206

    2009-12-15

    A stepwise-cluster microbial biomass inference (SMI) model was developed through introducing stepwise-cluster analysis (SCA) into composting process modeling to tackle the nonlinear relationships among state variables and microbial activities. The essence of SCA is to form a classification tree based on a series of cutting or mergence processes according to given statistical criteria. Eight runs of designed experiments in bench-scale reactors in a laboratory were constructed to demonstrate the feasibility of the proposed method. The results indicated that SMI could help establish a statistical relationship between state variables and composting microbial characteristics, where discrete and nonlinear complexities exist. Significance levelsmore » of cutting/merging were provided such that the accuracies of the developed forecasting trees were controllable. Through an attempted definition of input effects on the output in SMI, the effects of the state variables on thermophilic bacteria were ranged in a descending order as: Time (day) > moisture content (%) > ash content (%, dry) > Lower Temperature (deg. C) > pH > NH{sub 4}{sup +}-N (mg/Kg, dry) > Total N (%, dry) > Total C (%, dry); the effects on mesophilic bacteria were ordered as: Time > Upper Temperature (deg. C) > Total N > moisture content > NH{sub 4}{sup +}-N > Total C > pH. This study made the first attempt in applying SCA to mapping the nonlinear and discrete relationships in composting processes.« less

  13. Cation disorder and gas phase equilibrium in an YBa 2Cu 3O 7- x superconducting thin film

    NASA Astrophysics Data System (ADS)

    Shin, Dong Chan; Ki Park, Yong; Park, Jong-Chul; Kang, Suk-Joong L.; Yong Yoon, Duk

    1997-02-01

    YBa 2Cu 3O 7- x superconducting thin films have been grown by in situ off-axis rf sputtering with varying oxygen pressure, Ba/Y ratio in a target, and deposition temperature. With decreasing oxygen pressure, increasing Ba/Y ratio, increasing deposition temperature, the critical temperature of the thin films decreased and the c-axis length increased. The property change of films with the variation of deposition variables has been explained by a gas phase equilibrium of the oxidation reaction of Ba and Y. Applying Le Chatelier's principle to the oxidation reaction, we were able to predict the relation of deposition variables and the resultant properties of thin films; the prediction was in good agreement with the experimental results. From the relation between the three deposition variables and gas phase equilibrium, a 3-dimensional processing diagram was introduced. This diagram has shown that the optimum deposition condition of YBa 2Cu 3O 7- x thin films is not a fixed point but can be varied. The gas phase equilibrium can also be applied to the explanation of previous results that good quality films were obtained at low deposition temperature using active species, such as O, O 3, and O 2+.

  14. Temperature Anomalies from the AIRS Product in Giovanni for the Climate Community

    NASA Technical Reports Server (NTRS)

    Ding, Feng; Hearty, Thomas J.; Wei, Jennifer; Theobald, Michael; Vollmer, Bruce; Seiler, Edward; Meyer, David

    2018-01-01

    The Atmospheric Infrared Sounder (AIRS) mission began with the launch of Aqua in 2002. Over 15 years of AIRS products have been used by the climate research and application communities. The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC), in collaboration with NASA Sounder Team at JPL, provides processing, archiving, and distribution services for NASA sounders: the present Aqua AIRS mission and the succeeding Suomi National Polar-Orbiting Partnership (SNPP) Cross-track Infrared Sounder (CrIS) mission. We generated a Multi-year Monthly Mean and Anomaly product using 14 years of AIRS standard monthly product. The product includes Air Temperature at the Surface and Surface Skin Temperature, both in Ascending/Daytime and Descending/Nighttime mode. The temperature variables and their anomalies are deployed to Giovanni, a Web-based application developed by the GES DISC. Giovanni provides a simple and intuitive way to visualize, analyze, and access vast amounts of Earth science remote sensing data without having to download the data. It is also a powerful tool that stakeholders can use for decision support in planning and preparing for increased climate variability. In this presentation, we demonstrate the functions in Giovanni with use cases employing AIRS Multi-year Monthly Mean and Anomaly variables.

  15. Steroid Signaling and Temperature-Dependent Sex Determination – Reviewing the Evidence for Early Action of Estrogen during Ovarian Determination in the Red-Eared Slider Turtle (Trachemys scripta elegans)

    PubMed Central

    Ramsey, Mary; Crews, David

    2009-01-01

    The developmental processes underlying gonadal differentiation are conserved across vertebrates, but the triggers initiating these trajectories are extremely variable. The red-eared slider turtle (Trachemys scripta elegans) exhibits temperature-dependent sex determination (TSD), a system where incubation temperature during a temperature-sensitive period of development determines offspring sex. However, gonadal sex is sensitive to both temperature and hormones during this period – particularly estrogen. We present a model for temperature-based differences in aromatase expression as a critical step in ovarian determination. Localized estrogen production facilitates ovarian development while inhibiting male-specific gene expression. At male-producing temperatures aromatase is not upregulated, thereby allowing testis development. PMID:18992835

  16. Sometimes processes don't matter: the general effect of short term climate variability on erosional systems.

    NASA Astrophysics Data System (ADS)

    Deal, Eric; Braun, Jean

    2017-04-01

    Climatic forcing undoubtedly plays an important role in shaping the Earth's surface. However, precisely how climate affects erosion rates, landscape morphology and the sedimentary record is highly debated. Recently there has been a focus on the influence of short-term variability in rainfall and river discharge on the relationship between climate and erosion rates. Here, we present a simple probabilistic argument, backed by modelling, that demonstrates that the way the Earth's surface responds to short-term climatic forcing variability is primarily determined by the existence and magnitude of erosional thresholds. We find that it is the ratio between the threshold magnitude and the mean magnitude of climatic forcing that determines whether variability matters or not and in which way. This is a fundamental result that applies regardless of the nature of the erosional process. This means, for example, that we can understand the role that discharge variability plays in determining fluvial erosion efficiency despite doubts about the processes involved in fluvial erosion. We can use this finding to reproduce the main conclusions of previous studies on the role of discharge variability in determining long-term fluvial erosion efficiency. Many aspects of the landscape known to influence discharge variability are affected by human activity, such as land use and river damming. Another important control on discharge variability, rainfall intensity, is also expected to increase with warmer temperatures. Among many other implications, our findings help provide a general framework to understand and predict the response of the Earth's surface to changes in mean and variability of rainfall and river discharge associated with the anthropogenic activity. In addition, the process independent nature of our findings suggest that previous work on river discharge variability and erosion thresholds can be applied to other erosional systems.

  17. Observing continuous change in heart rate variability and photoplethysmography-derived parameters during the process of pain production/relief with thermal stimuli.

    PubMed

    Ye, Jing-Jhao; Lee, Kuan-Ting; Lin, Jing-Siang; Chuang, Chiung-Cheng

    2017-01-01

    Continuously monitoring and efficiently managing pain has become an important issue. However, no study has investigated a change in physiological parameters during the process of pain production/relief. This study modeled the process of pain production/relief using ramped thermal stimulation (no pain: 37°C water, process of pain production: a heating rate of 1°C/min, and subject feels pain: water kept at the painful temperature for each subject, with each segment lasting 10 min). In this duration, the variation of the heat rate variability and photoplethysmography-derived parameters was observed. A total of 40 healthy individuals participated: 30 in the trial group (14 males and 16 females with a mean age of 22.5±1.9 years) and 10 in the control group (7 males and 3 females with a mean age of 22.5±1.3 years). The results showed that the numeric rating scale value was 5.03±1.99 when the subjects felt pain, with a temperature of 43.54±1.70°C. Heart rate, R-R interval, low frequency, high frequency, photoplethysmography amplitude, baseline, and autonomic nervous system state showed significant changes during the pain production process, but these changes differed during the period Segment D (painful temperature 10: min). In summary, the study observed that physiological parameters changed qualitatively during the process of pain production and relief and found that the high frequency, low frequency, and photoplethysmography parameters seemed to have different responses in four situations (no pain, pain production, pain experienced, and pain relief). The trends of these variations may be used as references in the clinical setting for continuously observing pain intensity.

  18. Evaluation of an improved intermediate complexity snow scheme in the ORCHIDEE land surface model

    NASA Astrophysics Data System (ADS)

    Wang, Tao; Ottlé, Catherine; Boone, Aaron; Ciais, Philippe; Brun, Eric; Morin, Samuel; Krinner, Gerhard; Piao, Shilong; Peng, Shushi

    2013-06-01

    Snow plays an important role in land surface models (LSM) for climate and model applied over Fran studies, but its current treatment as a single layer of constant density and thermal conductivity in ORCHIDEE (Organizing Carbon and Hydrology in Dynamic Ecosystems) induces significant deficiencies. The intermediate complexity snow scheme ISBA-ES (Interaction between Soil, Biosphere and Atmosphere-Explicit Snow) that includes key snow processes has been adapted and implemented into ORCHIDEE, referred to here as ORCHIDEE-ES. In this study, the adapted scheme is evaluated against the observations from the alpine site Col de Porte (CDP) with a continuous 18 year data set and from sites distributed in northern Eurasia. At CDP, the comparisons of snow depth, snow water equivalent, surface temperature, snow albedo, and snowmelt runoff reveal that the improved scheme in ORCHIDEE is capable of simulating the internal snow processes better than the original one. Preliminary sensitivity tests indicate that snow albedo parameterization is the main cause for the large difference in snow-related variables but not for soil temperature simulated by the two models. The ability of the ORCHIDEE-ES to better simulate snow thermal conductivity mainly results in differences in soil temperatures. These are confirmed by performing sensitivity analysis of ORCHIDEE-ES parameters using the Morris method. These features can enable us to more realistically investigate interactions between snow and soil thermal regimes (and related soil carbon decomposition). When the two models are compared over sites located in northern Eurasia from 1979 to 1993, snow-related variables and 20 cm soil temperature are better reproduced by ORCHIDEE-ES than ORCHIDEE, revealing a more accurate representation of spatio-temporal variability.

  19. Evolving Nonthermal Electron Distributions in Simulations of Sgr A*

    NASA Astrophysics Data System (ADS)

    Chael, Andrew; Narayan, Ramesh

    2018-01-01

    The accretion flow around Sagittarius A* (Sgr A*), the black hole at the Galactic Center, produces strong variability from the radio to X-rays on timescales of minutes to hours. This rapid, powerful variability is thought to be powered by energetic particle acceleration by plasma processes like magnetic reconnection and shocks. These processes can accelerate particles into non-thermal distributions which do not quickly isothermal in the low densities found around hot accretion flows. Current state-of-the-art simulations of accretion flows around black holes assume either a single-temperature gas or, at best, a two-temperature gas with thermal ions and electrons. We present results from incorporating the self-consistent evolution of a non-thermal electron population in a GRRMHD simulation of Sgr A*. The electron distribution is evolved across space, time, and Lorentz factor in parallel with background thermal ion, electron, and radiation fluids. Energy injection into the non-thermal distribution is modeled with a sub-grid prescription based on results from particle-in-cell simulations of magnetic reconnection. The energy distribution of the non-thermal electrons shows strong variability, and the spectral shape traces the complex interplay between the local viscous heating rate, magnetic field strength, and fluid velocity. Results from these simulations will be used in interpreting forthcoming data from the Event Horizon Telescope that resolves Sgr A*'s sub-mm variability in both time and space.

  20. Greyscale Photolithography for Multilayer PZT Microelectromechanical Systems (MEMS) Device Applications

    DTIC Science & Technology

    We present development of a process to perform greyscale photolithography on a 2.55-m thick photoresist in order to transfer tiered and sloped...platinum or iridium oxide (IrO2) electrodes above and below each layer. Process variables including resist rehydration , focus of the exposure, and UV cure...bake temperature were optimized to produce the best greyscale profile through the thickness of the resist.

  1. Temperature variability is integrated by a spatially embedded decision-making center to break dormancy in Arabidopsis seeds.

    PubMed

    Topham, Alexander T; Taylor, Rachel E; Yan, Dawei; Nambara, Eiji; Johnston, Iain G; Bassel, George W

    2017-06-20

    Plants perceive and integrate information from the environment to time critical transitions in their life cycle. Some mechanisms underlying this quantitative signal processing have been described, whereas others await discovery. Seeds have evolved a mechanism to integrate environmental information by regulating the abundance of the antagonistically acting hormones abscisic acid (ABA) and gibberellin (GA). Here, we show that hormone metabolic interactions and their feedbacks are sufficient to create a bistable developmental fate switch in Arabidopsis seeds. A digital single-cell atlas mapping the distribution of hormone metabolic and response components revealed their enrichment within the embryonic radicle, identifying the presence of a decision-making center within dormant seeds. The responses to both GA and ABA were found to occur within distinct cell types, suggesting cross-talk occurs at the level of hormone transport between these signaling centers. We describe theoretically, and demonstrate experimentally, that this spatial separation within the decision-making center is required to process variable temperature inputs from the environment to promote the breaking of dormancy. In contrast to other noise-filtering systems, including human neurons, the functional role of this spatial embedding is to leverage variability in temperature to transduce a fate-switching signal within this biological system. Fluctuating inputs therefore act as an instructive signal for seeds, enhancing the accuracy with which plants are established in ecosystems, and distributed computation within the radicle underlies this signal integration mechanism.

  2. Norwegian fjord sediments reveal NAO related winter temperature and precipitation changes of the past 2800 years

    NASA Astrophysics Data System (ADS)

    Faust, Johan; Fabian, Karl; Giraudeau, Jacques; Knies, Jochen

    2016-04-01

    The North Atlantic Oscillation (NAO) is the leading mode of atmospheric circulation variability in the North Atlantic region. Associated shifts of storm tracks, precipitation and temperature patterns affect energy supply and demand, fisheries and agricultural, as well as marine and terrestrial ecological dynamics. Long-term NAO reconstructions are crucial to better understand NAO variability in its response to climate forcing factors, and assess predictability and possible shifts associated with ongoing climate change. Fjord deposits have a great potential for providing high-resolution sedimentary records that reflect local terrestrial and marine processes and, therefore, offer unique opportunities for the investigation of sedimentological and geochemical climatically induced processes. A recent study of instrumental time series revealed NAO as main factor for a strong relation between winter temperature, precipitation and river discharge in central Norway over the past 50 years. Here we use the gained knowledge to establish the first high resolution NAO proxy record from marine sediments. By comparing geochemical measurements from a short sediment core with instrumental data we show that marine primary productivity proxies are sensitive to NAO changes. Conditioned on a stationary relation between our climate proxy and the NAO we establish the first high resolution NAO proxy record (NAO-TFJ) from marine sediments covering the past 2,800 years. The NAO-TFJ shows distinct co-variability with climate changes over Greenland, solar activity and Northern Hemisphere glacier dynamics as well as climatically associated paleo-demographic trends.

  3. Temperature variability is integrated by a spatially embedded decision-making center to break dormancy in Arabidopsis seeds

    PubMed Central

    Topham, Alexander T.; Taylor, Rachel E.; Yan, Dawei; Nambara, Eiji; Johnston, Iain G.

    2017-01-01

    Plants perceive and integrate information from the environment to time critical transitions in their life cycle. Some mechanisms underlying this quantitative signal processing have been described, whereas others await discovery. Seeds have evolved a mechanism to integrate environmental information by regulating the abundance of the antagonistically acting hormones abscisic acid (ABA) and gibberellin (GA). Here, we show that hormone metabolic interactions and their feedbacks are sufficient to create a bistable developmental fate switch in Arabidopsis seeds. A digital single-cell atlas mapping the distribution of hormone metabolic and response components revealed their enrichment within the embryonic radicle, identifying the presence of a decision-making center within dormant seeds. The responses to both GA and ABA were found to occur within distinct cell types, suggesting cross-talk occurs at the level of hormone transport between these signaling centers. We describe theoretically, and demonstrate experimentally, that this spatial separation within the decision-making center is required to process variable temperature inputs from the environment to promote the breaking of dormancy. In contrast to other noise-filtering systems, including human neurons, the functional role of this spatial embedding is to leverage variability in temperature to transduce a fate-switching signal within this biological system. Fluctuating inputs therefore act as an instructive signal for seeds, enhancing the accuracy with which plants are established in ecosystems, and distributed computation within the radicle underlies this signal integration mechanism. PMID:28584126

  4. Effects of diurnal temperature range and drought on wheat yield in Spain

    NASA Astrophysics Data System (ADS)

    Hernandez-Barrera, S.; Rodriguez-Puebla, C.; Challinor, A. J.

    2017-07-01

    This study aims to provide new insight on the wheat yield historical response to climate processes throughout Spain by using statistical methods. Our data includes observed wheat yield, pseudo-observations E-OBS for the period 1979 to 2014, and outputs of general circulation models in phase 5 of the Coupled Models Inter-comparison Project (CMIP5) for the period 1901 to 2099. In investigating the relationship between climate and wheat variability, we have applied the approach known as the partial least-square regression, which captures the relevant climate drivers accounting for variations in wheat yield. We found that drought occurring in autumn and spring and the diurnal range of temperature experienced during the winter are major processes to characterize the wheat yield variability in Spain. These observable climate processes are used for an empirical model that is utilized in assessing the wheat yield trends in Spain under different climate conditions. To isolate the trend within the wheat time series, we implemented the adaptive approach known as Ensemble Empirical Mode Decomposition. Wheat yields in the twenty-first century are experiencing a downward trend that we claim is a consequence of widespread drought over the Iberian Peninsula and an increase in the diurnal range of temperature. These results are important to inform about the wheat vulnerability in this region to coming changes and to develop adaptation strategies.

  5. A study on the performance and emission characteristics of esterified pinnai oil tested in VCR engine.

    PubMed

    Ashok Kumar, T; Chandramouli, R; Mohanraj, T

    2015-11-01

    Biodiesel is a clean renewable fuel derived from vegetable oils and animal fats. It is biodegradable, oxygenated, non toxic and free from sulfur and aromatics. The biodiesel prepared from pinnai oil undergoes acid esterification followed by alkaline transesterification process. The fatty acid methyl esters components were identified using gas chromatography and compared with the standard properties. The properties of biodiesel are comparable with diesel. The yield of the biodiesel production depends upon the process parameters such as reaction temperature, pH, time duration and amount of catalyst. The yield of biodiesel by transesterification process was 73% at 55°C. This fuel was tested in a variable compression ratio engine with blend ratios of B10 and B20. During the test runs the compression ratio of the engine was varied from 15:1 to 18:1 and the torque is adjusted from zero to maximum value of 22Nm. The performance characteristics such as the brake thermal efficiency, brake specific energy consumption and exhaust gas temperature of the engine are analyzed. The combustion characteristics of biodiesel like ignition delay, combustion duration and maximum gas temperature and the emission characteristics are also analyzed. The performance characteristics, combustion characteristics and engine emission are effective in the variable compression ratio engine with biodiesel and it is compared with diesel. Copyright © 2015 Elsevier Inc. All rights reserved.

  6. Statistical Methods for Quality Control of Steel Coils Manufacturing Process using Generalized Linear Models

    NASA Astrophysics Data System (ADS)

    García-Díaz, J. Carlos

    2009-11-01

    Fault detection and diagnosis is an important problem in process engineering. Process equipments are subject to malfunctions during operation. Galvanized steel is a value added product, furnishing effective performance by combining the corrosion resistance of zinc with the strength and formability of steel. Fault detection and diagnosis is an important problem in continuous hot dip galvanizing and the increasingly stringent quality requirements in automotive industry has also demanded ongoing efforts in process control to make the process more robust. When faults occur, they change the relationship among these observed variables. This work compares different statistical regression models proposed in the literature for estimating the quality of galvanized steel coils on the basis of short time histories. Data for 26 batches were available. Five variables were selected for monitoring the process: the steel strip velocity, four bath temperatures and bath level. The entire data consisting of 48 galvanized steel coils was divided into sets. The first training data set was 25 conforming coils and the second data set was 23 nonconforming coils. Logistic regression is a modeling tool in which the dependent variable is categorical. In most applications, the dependent variable is binary. The results show that the logistic generalized linear models do provide good estimates of quality coils and can be useful for quality control in manufacturing process.

  7. Optimization of extraction process by response surface methodology and preliminary structural analysis of polysaccharides from defatted peanut (Arachis hypogaea) cakes.

    PubMed

    Song, Yi; Du, Bingjian; Zhou, Ting; Han, Bing; Yu, Fei; Yang, Rui; Hu, Xiaosong; Ni, Yuanying; Li, Quanhong

    2011-02-01

    In this work, response surface methodology was used to determine optimum conditions for extraction of polysaccharides from defatted peanut cake. A central composite design including independent variables, such as extraction temperature (x(1)), extraction time (x(2)), and ethanol concentration (x(3)) was used. Selected response which evaluates the extraction process was polysaccharide yield, and the second-order model obtained for polysaccharide yield revealed coefficient of determination of 97.81%. The independent variable with the largest effect on response was ethanol concentration (x(3)). The optimum extraction conditions were found to be extraction temperature 48.7°C, extraction time 1.52 h, and ethanol concentration of 61.9% (v/v), respectively. Under these conditions, the extraction efficiency of polysaccharide can increase to 25.89%. The results of structural analysis showed that the main composition of defatted peanut cake polysaccharide was α-galactose. 2010 Elsevier Ltd. All rights reserved.

  8. Preparation and Characterization of a Small Library of Thermally-Labile End-Caps for Variable-Temperature Triggering of Self-Immolative Polymers.

    PubMed

    Taimoory, S Maryamdokht; Sadraei, S Iraj; Fayoumi, Rose Anne; Nasri, Sarah; Revington, Matthew; Trant, John F

    2018-04-20

    The reaction between furans and maleimides has increasingly become a method of interest as its reversibility makes it a useful tool for applications ranging from self-healing materials, to self-immolative polymers, to hydrogels for cell culture and for the preparation of bone repair. However, most of these applications have relied on simple monosubstituted furans and simple maleimides and have not extensively evaluated the potential thermal variability inherent in the process that is achievable through simple substrate modification. A small library of cycloadducts suitable for the above applications was prepared, and the temperature dependence of the retro-Diels-Alder processes was determined through in situ 1 H NMR analyses complemented by computational calculations. The practical range of the reported systems ranges from 40 to >110 °C. The cycloreversion reactions are more complex than would be expected based on simple trends expected based on frontier molecular orbital analyses of the materials.

  9. Tailored metal matrix composites for high-temperature performance

    NASA Technical Reports Server (NTRS)

    Morel, M. R.; Saravanos, D. A.; Chamis, C. C.

    1992-01-01

    A multi-objective tailoring methodology is presented to maximize stiffness and load carrying capacity of a metal matrix cross-ply laminated at elevated temperatures. The fabrication process and fiber volume ratio are used as the design variables. A unique feature is the concurrent effects from fabrication, residual stresses, material nonlinearity, and thermo-mechanical loading on the laminate properties at the post-fabrication phase. For a (0/90)(sub s) graphite/copper laminate, strong coupling was observed between the fabrication process, laminate characteristics, and thermo-mechanical loading. The multi-objective tailoring was found to be more effective than single objective tailoring. Results indicate the potential to increase laminate stiffness and load carrying capacity by controlling the critical parameters of the fabrication process and the laminate.

  10. Analysis of Influence of Heat Insulation on the Thermal Regime of Storage Tanks with Liquefied Natural Gas

    NASA Astrophysics Data System (ADS)

    Maksimov, Vyacheslav I.; Nagornova, Tatiana A.; Glazyrin, Viktor P.; Shestakov, Igor A.

    2016-02-01

    Is numerically investigated the process of convective heat transfer in the reservoirs of liquefied natural gas (LNG). The regimes of natural convection in a closed rectangular region with different intensity of heat exchange at the external borders are investigated. Is solved the time-dependent system of energy and Navier-Stokes equations in the dimensionless variables "vorticity - the stream function". Are obtained distributions of the hydrodynamic parameters and temperatures, that characterize basic regularities of the processes. The special features of the formation of circulation flows are isolated and the analysis of the temperature distribution in the solution region is carried out. Is shown the influence of geometric characteristics and intensity of heat exchange on the outer boundaries of reservoir on the temperature field in the LNG storage.

  11. Stress effect of different temperatures and air exposure during transport on physiological profiles in the American lobster Homarus americanus.

    PubMed

    Lorenzon, S; Giulianini, P G; Martinis, M; Ferrero, E A

    2007-05-01

    Homarus americanus is an important commercial species that can survive 2-3 days out of water if kept cool and humid. Once caught for commercial purpose and shipped around the world, a lobster is likely to be subjected to a number of stressors, including emersion and air exposure, hypoxia, temperature changes and handling. This study focused on the effect of transport stress and specifically at different animal body temperature (6 and 15 degrees C) and air exposure during commercial transport and recovery process in water. Animals were monitored, by hemolymph bleeding, at different times: 0 h (arrival time at plant) 3 h, 12 h, 24 h and 96 h after immersion in the stocking tank with a water temperature of 6.5+/-1.5 degrees C. We analysed the effects by testing some physiological variables of the hemolymph: glucose, cHH, lactate, total protein, cholesterol, triglycerides, chloride and calcium concentration, pH and density. All these variables appeared to be influenced negatively by high temperature both in average of alteration from the physiological value and in recovering time. Blood glucose, lactate, total protein, cholesterol were significantly higher in the group with high body temperature compared to those with low temperature until 96 h after immersion in the recovery tank.

  12. Thermal anomalies of the transmitter experiment package on the communications technology satellite

    NASA Technical Reports Server (NTRS)

    Alexovich, R. E.; Curren, A. N.

    1979-01-01

    The causes of four temporary thermal-control-system malfunctions that gave rise to unexpected temperature excursions in the 12-gigahertz, 200-watt transmitter experiment package (TEP) on the Communications Technology Satellite were investigated. The TEP consists of a nominal 200-watt output stage tube (OST), a supporting power-processing system (PPS), and a variable-conductance heat-pipe system (VCHPS). The VCHPS, which uses three heat pipes to conduct heat from the body of the OST to a radiator fin, was designed to maintain the TEP at safe operating temperatures at all operating conditions. On four occasions during 1977, all near the spring and fall equinoxes, the OST body temperature and related temperatures displayed sudden, rapid, and unexpected rises above normal levels while the TEP was operating at essentially constant, normal conditions. The temperature excursions were terminated without TEP damage by reducing the radio frequency (RF) output power of the OST. Between the anomalies and since the fourth, the thermal control system has apparently functioned as designed. The results indicate the most probable cause of the temperature anomalies is depriming of the arteries in the variable-conductance heat pipes. A mode was identified in which the TEP, as presently configured, may operate with stable temperatures and with minimum change in performance level.

  13. Novel Materials through Non-Hydrolytic Sol-Gel Processing: Negative Thermal Expansion Oxides and Beyond

    PubMed Central

    Lind, Cora; Gates, Stacy D.; Pedoussaut, Nathalie M.; Baiz, Tamam I.

    2010-01-01

    Low temperature methods have been applied to the synthesis of many advanced materials. Non-hydrolytic sol-gel (NHSG) processes offer an elegant route to stable and metastable phases at low temperatures. Excellent atomic level homogeneity gives access to polymorphs that are difficult or impossible to obtain by other methods. The NHSG approach is most commonly applied to the preparation of metal oxides, but can be easily extended to metal sulfides. Exploration of experimental variables allows control over product stoichiometry and crystal structure. This paper reviews the application of NHSG chemistry to the synthesis of negative thermal expansion oxides and selected metal sulfides.

  14. Development of Pangasius steaks by improved sous-vide technology and its process optimization.

    PubMed

    Kumari, Namita; Singh, Chongtham Baru; Kumar, Raushan; Martin Xavier, K A; Lekshmi, Manjusha; Venkateshwarlu, Gudipati; Balange, Amjad K

    2016-11-01

    The present study embarked on the objective of optimizing improved sous - vide processing condition for development of ready-to-cook Pangasius steaks with extended shelf-life using response surface methodology. For the development of improved sous - vide cooked product, Pangasius steaks were treated with additional hurdles in various combinations for optimization. Based on the study, suitable combination of chitosan and spices was selected which enhanced antimicrobial and oxidative stability of the product. The Box-Behnken experimental design with 15 trials per model was adopted for designing the experiment to know the effect of independent variables, namely chitosan concentration (X 1 ), cooking time (X 2 ) and cooking temperature (X 3 ) on dependent variable i.e. TBARS value (Y 1 ). From RSM generated model, the optimum condition for sous - vide processing of Pangasius steaks were 1.08% chitosan concentration, 70.93 °C of cooking temperature and 16.48 min for cooking time and predicted minimum value of multiple response optimal condition was Y = 0.855 mg MDA/Kg of fish. The high correlation coefficient (R 2  = 0.975) between the model and the experimental data showed that the model was able to efficiently predict processing condition for development of sous - vide processed Pangasius steaks. This research may help the processing industries and Pangasius fish farmer as it provides an alternative low cost technology for the proper utilization of Pangasius .

  15. Process for hydrocracking carbonaceous material to provide fuels or chemical feed stock

    DOEpatents

    Duncan, Dennis A.

    1980-01-01

    A process is disclosed for hydrocracking coal or other carbonaceous material to produce various aromatic hydrocarbons including benzene, toluene, xylene, ethylbenzene, phenol and cresols in variable relative concentrations while maintaining a near constant maximum temperature. Variations in relative aromatic concentrations are achieved by changing the kinetic severity of the hydrocracking reaction by altering the temperature profile up to and quenching from the final hydrocracking temperature. The relative concentration of benzene to the alkyl and hydroxyl aromatics is increased by imposing increased kinetic severity above that corresponding to constant heating rate followed by immediate quenching at about the same rate to below the temperature at which dehydroxylation and dealkylation reactions appreciably occur. Similarly phenols, cresols and xylenes are produced in enhanced concentrations by adjusting the temperature profile to provide a reduced kinetic severity relative to that employed when high benzene concentrations are desired. These variations in concentrations can be used to produce desired materials for chemical feed stocks or for fuels.

  16. Role of the Soil Thermal Inertia in the short term variability of the surface temperature and consequences for the soil-moisture temperature feedback

    NASA Astrophysics Data System (ADS)

    Cheruy, Frederique; Dufresne, Jean-Louis; Ait Mesbah, Sonia; Grandpeix, Jean-Yves; Wang, Fuxing

    2017-04-01

    A simple model based on the surface energy budget at equilibrium is developed to compute the sensitivity of the climatological mean daily temperature and diurnal amplitude to the soil thermal inertia. It gives a conceptual framework to quantity the role of the atmospheric and land surface processes in the surface temperature variability and relies on the diurnal amplitude of the net surface radiation, the sensitivity of the turbulent fluxes to the surface temperature and the thermal inertia. The performances of the model are first evaluated with 3D numerical simulations performed with the atmospheric (LMDZ) and land surface (ORCHIDEE) modules of the Institut Pierre Simon Laplace (IPSL) climate model. A nudging approach is adopted, it prevents from using time-consuming long-term simulations required to account for the natural variability of the climate and allow to draw conclusion based on short-term (several years) simulations. In the moist regions the diurnal amplitude and the mean surface temperature are controlled by the latent heat flux. In the dry areas, the relevant role of the stability of the boundary layer and of the soil thermal inertia is demonstrated. In these regions, the sensitivity of the surface temperature to the thermal inertia is high, due to the high contribution of the thermal flux to the energy budget. At high latitudes, when the sensitivity of turbulent fluxes is dominated by the day-time sensitivity of the sensible heat flux to the surface temperature and when this later is comparable to the thermal inertia term of the sensitivity equation, the surface temperature is also partially controlled by the thermal inertia which can rely on the snow properties; In the regions where the latent heat flux exhibits a high day-to-day variability, such as transition regions, the thermal inertia has also significant impact on the surface temperature variability . In these not too wet (energy limited) and not too dry (moisture-limited) soil moisture (SM) ''hot spots'', it is generally admitted that the variability of the surface temperature is explained by the soil moisture trough its control on the evaporation. This work suggests that the impact of the soil moisture on the temperature through its impact on the thermal inertia can be as important as its direct impact on the evaporation. Contrarily to the evaporation related soil-moisture temperature negative feedback, the thermal inertia soil-moisture related feedback newly identified by this work is a positive feedback which limits the cooling when the soil moisture increases. These results suggest that uncertainties in the representation of the soil and snow thermal properties can be responsible of significant biases in numerical simulations and emphasize the need to carefully document and evaluate these quantities in the Land Surface Modules implemented in the climate models.

  17. Hot-wire calibration in subsonic/transonic flow regimes

    NASA Technical Reports Server (NTRS)

    Nagabushana, K. A.; Ash, Robert L.

    1995-01-01

    A different approach for calibrating hot-wires, which simplifies the calibration procedure and reduces the tunnel run-time by an order of magnitude was sought. In general, it is accepted that the directly measurable quantities in any flow are velocity, density, and total temperature. Very few facilities have the capability of varying the total temperature over an adequate range. However, if the overheat temperature parameter, a(sub w), is used to calibrate the hot-wire then the directly measurable quantity, voltage, will be a function of the flow variables and the overheat parameter i.e., E = f(u,p,a(sub w), T(sub w)) where a(sub w) will contain the needed total temperature information. In this report, various methods of evaluating sensitivities with different dependent and independent variables to calibrate a 3-Wire hot-wire probe using a constant temperature anemometer (CTA) in subsonic/transonic flow regimes is presented. The advantage of using a(sub w) as the independent variable instead of total temperature, t(sub o), or overheat temperature parameter, tau, is that while running a calibration test it is not necessary to know the recovery factor, the coefficients in a wire resistance to temperature relationship for a given probe. It was deduced that the method employing the relationship E = f (u,p,a(sub w)) should result in the most accurate calibration of hot wire probes. Any other method would require additional measurements. Also this method will allow calibration and determination of accurate temperature fluctuation information even in atmospheric wind tunnels where there is no ability to obtain any temperature sensitivity information at present. This technique greatly simplifies the calibration process for hot-wires, provides the required calibration information needed in obtaining temperature fluctuations, and reduces both the tunnel run-time and the test matrix required to calibrate hotwires. Some of the results using the above techniques are presented in an appendix.

  18. Internal evaporation and condensation characteristics in the shallow soil layer of an oasis

    NASA Astrophysics Data System (ADS)

    Ao, Yinhuan; Han, Bo; Lu, Shihua; Li, Zhaoguo

    2016-07-01

    The surface energy balance was analyzed using observations from the Jinta oasis experiment in the summer of 2005. A negative imbalance energy flux was found during daytime that could not be attributed to the soil heat storage process. Rather, the imbalance was related to the evaporation within the soil. The soil heat storage rate and the soil moisture variability always showed similar variations at a depth of 0.05 m between 0800 and 1000 (local standard time), while the observed imbalanced energy flux was very small, which implied that water vapor condensation occurred within the soil. Therefore, the distillation in shallow soil can be derived using reliable surface energy flux observations. In order to show that the importance of internal evaporation and condensation in the shallow soil layer, the soil temperatures at the depths of 0.05, 0.10, and 0.20 m were reproduced using a one-dimensional thermal diffusion equation, with the observed soil temperature at the surface and at 0.40 m as the boundary conditions. It was found that the simulated soil temperature improves substantially in the shallow layer when the water distillation is added as a sink/source term, even after the soil effective thermal conductivity has been optimized. This result demonstrates that the process of water distillation may be a dominant cause of both the temperature and moisture variability in the shallow soil layer.

  19. Mars Thermospheric Temperature Sensitivity to Solar EUV Forcing from the MAVEN EUV Monitor

    NASA Astrophysics Data System (ADS)

    Thiemann, Ed; Eparvier, Francis; Andersson, Laila; Pilinski, Marcin; Chamberlin, Phillip; Fowler, Christopher; MAVEN Extreme Ultraviolet Monitor Team, MAVEN Langmuir Probe and Waves Team

    2017-10-01

    Solar extreme ultraviolet (EUV) radiation is the primary heat source for the Mars thermosphere, and the primary source of long-term temperature variability. The Mars obliquity, dust cycle, tides and waves also drive thermospheric temperature variability; and it is important to quantify the role of each in order to understand processes in the upper atmosphere today and, ultimately, the evolution of Mars climate over time. Although EUV radiation is the dominant heating mechanism, accurately measuring the thermospheric temperature sensitivity to EUV forcing has remained elusive, in part, because Mars thermospheric temperature varies dramatically with latitude and local time (LT), ranging from 150K on the nightside to 300K on the dayside. It follows that studies of thermospheric variability must control for location.Instruments onboard the Mars Atmosphere and Volatile EvolutioN (MAVEN) orbiter have begun to characterize thermospheric temperature sensitivity to EUV forcing. Bougher et al. [2017] used measurements from the Imaging Ultraviolet Spectrograph (IUVS) and the Neutral Gas and Ion Mass Spectrometer (NGIMS) to characterize solar activity trends in the thermosphere with some success. However, aside from restricting measurements to solar zenith angles (SZAs) below 75 degrees, they were unable to control for latitude and LT because repeat-track observations from either instrument were limited or unavailable.The MAVEN EUV Monitor (EUVM) has recently demonstrated the capability to measure thermospheric density from 100 to 200 km with solar occultations of its 17-22 nm channel. These new density measurements are ideal for tracking the long-term thermospheric temperature variability because they are inherently constrained to either 06:00 or 18:00 LT, and the orbit has precessed to include a range of ecliptic latitudes, a number of which have been revisited multiple times over 2.5 years. In this study we present, for the first-time, measurements of thermospheric temperature sensitivity to EUV forcing derived from the EUVM measurements. These results include sensitives measured at the poles and near the equator for both terminators; therefore, we will also discuss the role of latitude on EUV temperature sensitivity.

  20. Decadal trend of precipitation and temperature patterns and impacts on snow-related variables in a semiarid region, Sierra Nevada, Spain.

    NASA Astrophysics Data System (ADS)

    José Pérez-Palazón, María; Pimentel, Rafael; Herrero, Javier; José Polo, María

    2016-04-01

    In the current context of global change, mountainous areas constitute singular locations in which these changes can be traced. Early detection of significant shifts of snow state variables in semiarid regions can help assess climate variability impacts and future snow dynamics in northern latitudes. The Sierra Nevada mountain range, in southern Spain, is a representative example of snow areas in Mediterranean-climate regions and both monitoring and modelling efforts have been performed to assess this variability and its significant scales. This work presents a decadal trend analysis throughout the 50-yr period 1960-2010 performed on some snow-related variables over Sierra Nevada, in Spain, which is included in the global climate change observatories network around the world. The study area comprises 4583 km2 distributed throughout the five head basins influenced by these mountains, with altitude values ranging from 140 to 3479 m.a.s.l., just 40 km from the Mediterranean coastline. Meteorological variables obtained from 44 weather stations from the National Meteorological Agency were studied and further used as input to the distributed hydrological model WiMMed (Polo et al., 2010), operational at the study area, to obtain selected snow variables. Decadal trends were obtained, together with their statistical significance, over the following variables, averaged over the whole study area: (1) annual precipitation; (2) annual snowfall; annual (3) mean, (4) maximum and (5) minimum daily temperature; annual (6) mean and (7) maximum daily fraction of snow covered areas; (8) annual number of days with snow cover; (9) mean and (10) maximum daily snow water equivalent; (11) annual number of extreme precipitation events; and (12) mean intensity of the annual extreme precipitation events. These variables were also studied over each of the five regions associated to each basin in the range. Globally decreasing decadal trends were obtained for all the meteorological variables, with the exception of the average annual mean and maximum daily temperature. In the case of the snow-related variables, no significant trends are observed at this time scale; nonetheless, a global decreasing rate is predominant in most of the variables. The torrential events are more frequent in the last decades of the study period, with an apparently increasing associated dispersion. This study constitutes a first sound analysis of the long-term observed trends of the snow regime in this area under the context of increasing temperature and decreasing precipitation regimes. The results highlight the complexity of non-linearity in environmental processes in Mediterranean regions, and point out to a significant shift in the precipitation and temperature regime, and thus on the snow-affected hydrological variables in the study area.

  1. Evaluation of continuous oxydesulfurization processes. Final technical report, September 1979-July 1981

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jones, J.F.; Wever, D.M.

    1981-07-01

    Three processes developed by Pittsburgh Energy Technology Center (PETC), Ledgemont Laboratories, and Ames Laboratories for the oxydesulfurization of coal were evaluated in continuous processing equipment designed, built, and/or adapted for the purpose at the DOE-owned Multi-Use Fuels and Energy Processes Test Plant (MEP) located at TRW's Capistrano Test Site in California. The three processes differed primarily in the chemical additives (none, sodium carbonate, or ammonia), fed to the 20% to 40% coal/water slurries, and in the oxygen content of the feed gas stream. Temperature, pressure, residence time, flow rates, slurry concentration and stirrer speed were the other primary independent variables.more » The amount of organic sulfur removed, total sulfur removed and the Btu recovery were the primary dependent variables. Evaluation of the data presented was not part of the test effort.« less

  2. Study of Variable Frequency Induction Heating in Steel Making Process

    NASA Astrophysics Data System (ADS)

    Fukutani, Kazuhiko; Umetsu, Kenji; Itou, Takeo; Isobe, Takanori; Kitahara, Tadayuki; Shimada, Ryuichi

    Induction heating technologies have been the standard technologies employed in steel making processes because they are clean, they have a high energy density, they are highly the controllable, etc. However, there is a problem in using them; in general, frequencies of the electric circuits have to be kept fixed to improve their power factors, and this constraint makes the processes inflexible. In order to overcome this problem, we have developed a new heating technique-variable frequency power supply with magnetic energy recovery switching. This technique helps us in improving the quality of steel products as well as the productivity. We have also performed numerical calculations and experiments to evaluate its effect on temperature distributions on heated steel plates. The obtained results indicate that the application of the technique in steel making processes would be advantageous.

  3. Torrefaction of oil palm frond: The effect of process condition to calorific value and proximate analysis

    NASA Astrophysics Data System (ADS)

    Susanty, W.; Helwani, Z.; Zulfansyah

    2018-04-01

    Oil palm frond can be used as alternative energy source by torrefaction process. Torrefaction is a treatment process of biomass into solid fuel by heating within temperature range of 200-300°C in an inert environment. This research aims to result solid fuel through torrefaction and to study the effect of process variable interaction. Torrefaction of oil palm frond was using fixed bed horizontal reactor with operation condition of temperature (225-275 °C), time (15-45 minutes) and nitrogen flow rate (50-150 ml/min). Responses resulted were calorific value and proximate (moisture, ash, volatile matter and fixed carbon). Analysis result was processed by using Design Expert v7.0.0. Result obtained for calorific value was 17.700-19.600 kJ/kg and for the proximate were moisture range of 3-4%; ash range of 1.5-4%; volatile matter of 45-55% and fixed carbon of 37-46%. The most affecting factor signficantly towards the responses was temperature then followed by time and nitrogen flow rate.

  4. Relative Role of Horizontal and Vertical Processes in Arctic Amplification

    NASA Astrophysics Data System (ADS)

    Kim, K. Y.

    2017-12-01

    The physical mechanism of Arctic amplification is still controversial. Specifically, relative role of vertical processes resulting from the reduction of sea ice in the Barents-Kara Seas is not clearly understood in comparison with the horizontal advection of heat and moisture. Using daily data, heat and moisture budgets are analyzed during winter (Dec. 1-Feb. 28) over the region of sea ice reduction in order to delineate the relative roles of horizontal and vertical processes. Detailed heat and moisture budgets in the atmospheric column indicate that the vertical processes, release of turbulent heat fluxes and evaporation, are a major contributor to the increased temperature and specific humidity over the Barents-Kara Seas. In addition, greenhouse effect caused by the increased specific humidity, also plays an important role in Arctic amplification. Horizontal processes such as advection of heat and moisture are the primary source of variability (fluctuations) in temperature and specific humidity in the atmospheric column. Advection of heat and moisture, on the other hand, is little responsible for the net increase in temperature and specific humidity over the Barents-Kara Seas.

  5. Statistical methods and regression analysis of stratospheric ozone and meteorological variables in Isfahan

    NASA Astrophysics Data System (ADS)

    Hassanzadeh, S.; Hosseinibalam, F.; Omidvari, M.

    2008-04-01

    Data of seven meteorological variables (relative humidity, wet temperature, dry temperature, maximum temperature, minimum temperature, ground temperature and sun radiation time) and ozone values have been used for statistical analysis. Meteorological variables and ozone values were analyzed using both multiple linear regression and principal component methods. Data for the period 1999-2004 are analyzed jointly using both methods. For all periods, temperature dependent variables were highly correlated, but were all negatively correlated with relative humidity. Multiple regression analysis was used to fit the meteorological variables using the meteorological variables as predictors. A variable selection method based on high loading of varimax rotated principal components was used to obtain subsets of the predictor variables to be included in the linear regression model of the meteorological variables. In 1999, 2001 and 2002 one of the meteorological variables was weakly influenced predominantly by the ozone concentrations. However, the model did not predict that the meteorological variables for the year 2000 were not influenced predominantly by the ozone concentrations that point to variation in sun radiation. This could be due to other factors that were not explicitly considered in this study.

  6. Commercially sterilized mussel meats (Mytilus chilensis): a study on process yield.

    PubMed

    Almonacid, S; Bustamante, J; Simpson, R; Urtubia, A; Pinto, M; Teixeira, A

    2012-06-01

    The processing steps most responsible for yield loss in the manufacture of canned mussel meats are the thermal treatments of precooking to remove meats from shells, and thermal processing (retorting) to render the final canned product commercially sterile for long-term shelf stability. The objective of this study was to investigate and evaluate the impact of different combinations of process variables on the ultimate drained weight in the final mussel product (Mytilu chilensis), while verifying that any differences found were statistically and economically significant. The process variables selected for this study were precooking time, brine salt concentration, and retort temperature. Results indicated 2 combinations of process variables producing the widest difference in final drained weight, designated best combination and worst combination with 35% and 29% yield, respectively. Significance of this difference was determined by employing a Bootstrap methodology, which assumes an empirical distribution of statistical error. A difference of nearly 6 percentage points in total yield was found. This represents a 20% increase in annual sales from the same quantity of raw material, in addition to increase in yield, the conditions for the best process included a retort process time 65% shorter than that for the worst process, this difference in yield could have significant economic impact, important to the mussel canning industry. © 2012 Institute of Food Technologists®

  7. An assessment of global climate model-simulated climate for the western cordillera of Canada (1961-90)

    NASA Astrophysics Data System (ADS)

    Bonsal, Barrie R.; Prowse, Terry D.; Pietroniro, Alain

    2003-12-01

    Climate change is projected to significantly affect future hydrologic processes over many regions of the world. This is of particular importance for alpine systems that provide critical water supplies to lower-elevation regions. The western cordillera of Canada is a prime example where changes to temperature and precipitation could have profound hydro-climatic impacts not only for the cordillera itself, but also for downstream river systems and the drought-prone Canadian Prairies. At present, impact researchers primarily rely on global climate models (GCMs) for future climate projections. The main objective of this study is to assess several GCMs in their ability to simulate the magnitude and spatial variability of current (1961-90) temperature and precipitation over the western cordillera of Canada. In addition, several gridded data sets of observed climate for the study region are evaluated.Results reveal a close correspondence among the four gridded data sets of observed climate, particularly for temperature. There is, however, considerable variability regarding the various GCM simulations of this observed climate. The British, Canadian, German, Australian, and US GFDL models are superior at simulating the magnitude and spatial variability of mean temperature. The Japanese GCM is of intermediate ability, and the US NCAR model is least representative of temperature in this region. Nearly all the models substantially overestimate the magnitude of total precipitation, both annually and on a seasonal basis. An exception involves the British (Hadley) model, which best represents the observed magnitude and spatial variability of precipitation. This study improves our understanding regarding the accuracy of GCM climate simulations over the western cordillera of Canada. The findings may assist in producing more reliable future scenarios of hydro-climatic conditions over various regions of the country. Copyright

  8. Spatially-Resolved Influence of Temperature and Salinity on Stock and Recruitment Variability of Commercially Important Fishes in the North Sea

    PubMed Central

    Akimova, Anna; Núñez-Riboni, Ismael; Kempf, Alexander; Taylor, Marc H.

    2016-01-01

    Understanding of the processes affecting recruitment of commercially important fish species is one of the major challenges in fisheries science. Towards this aim, we investigated the relation between North Sea hydrography (temperature and salinity) and fish stock variables (recruitment, spawning stock biomass and pre-recruitment survival index) for 9 commercially important fishes using spatially-resolved cross-correlation analysis. We used high-resolution (0.2° × 0.2°) hydrographic data fields matching the maximal temporal extent of the fish population assessments (1948–2013). Our approach allowed for the identification of regions in the North Sea where environmental variables seem to be more influential on the fish stocks, as well as the regions of a lesser or nil influence. Our results confirmed previously demonstrated negative correlations between temperature and recruitment of cod and plaice and identified regions of the strongest correlations (German Bight for plaice and north-western North Sea for cod). We also revealed a positive correlation between herring spawning stock biomass and temperature in the Orkney-Shetland area, as well as a negative correlation between sole pre-recruitment survival index and temperature in the German Bight. A strong positive correlation between sprat stock variables and salinity in the central North Sea was also found. To our knowledge the results concerning correlations between North Sea hydrography and stocks’ dynamics of herring, sole and sprat are novel. The new information about spatial distribution of the correlation provides an additional help to identify mechanisms underlying these correlations. As an illustration of the utility of these results for fishery management, an example is provided that incorporates the identified environmental covariates in stock-recruitment models. PMID:27584155

  9. Computational design of the basic dynamical processes of the UCLA general circulation model

    NASA Technical Reports Server (NTRS)

    Arakawa, A.; Lamb, V. R.

    1977-01-01

    The 12-layer UCLA general circulation model encompassing troposphere and stratosphere (and superjacent 'sponge layer') is described. Prognostic variables are: surface pressure, horizontal velocity, temperature, water vapor and ozone in each layer, planetary boundary layer (PBL) depth, temperature, moisture and momentum discontinuities at PBL top, ground temperature and water storage, and mass of snow on ground. Selection of space finite-difference schemes for homogeneous incompressible flow, with/without a free surface, nonlinear two-dimensional nondivergent flow, enstrophy conserving schemes, momentum advection schemes, vertical and horizontal difference schemes, and time differencing schemes are discussed.

  10. Seasonality of change: Summer warming rates do not fully represent effects of climate change on lake temperatures

    USGS Publications Warehouse

    Winslow, Luke; Read, Jordan S.; Hansen, Gretchen J. A.; Rose, Kevin C.; Robertson, Dale M.

    2017-01-01

    Responses in lake temperatures to climate warming have primarily been characterized using seasonal metrics of surface-water temperatures such as summertime or stratified period average temperatures. However, climate warming may not affect water temperatures equally across seasons or depths. We analyzed a long-term dataset (1981–2015) of biweekly water temperature data in six temperate lakes in Wisconsin, U.S.A. to understand (1) variability in monthly rates of surface- and deep-water warming, (2) how those rates compared to summertime average trends, and (3) if monthly heterogeneity in water temperature trends can be predicted by heterogeneity in air temperature trends. Monthly surface-water temperature warming rates varied across the open-water season, ranging from 0.013 in August to 0.073°C yr−1 in September (standard deviation [SD]: 0.025°C yr−1). Deep-water trends during summer varied less among months (SD: 0.006°C yr−1), but varied broadly among lakes (–0.056°C yr−1 to 0.035°C yr−1, SD: 0.034°C yr−1). Trends in monthly surface-water temperatures were well correlated with air temperature trends, suggesting monthly air temperature trends, for which data exist at broad scales, may be a proxy for seasonal patterns in surface-water temperature trends during the open water season in lakes similar to those studied here. Seasonally variable warming has broad implications for how ecological processes respond to climate change, because phenological events such as fish spawning and phytoplankton succession respond to specific, seasonal temperature cues.

  11. Modeling sea-surface temperature and its variability

    NASA Technical Reports Server (NTRS)

    Sarachik, E. S.

    1985-01-01

    A brief review is presented of the temporal scales of sea surface temperature variability. Progress in modeling sea surface temperature, and remaining obstacles to the understanding of the variability is discussed.

  12. Development and Testing of a Coupled Ocean-atmosphere Mesoscale Ensemble Prediction System

    DTIC Science & Technology

    2011-06-28

    wind, temperature, and moisture variables, while the oceanographic ET is derived from ocean current, temperature, and salinity variables. Estimates of...wind, temperature, and moisture variables while the oceanographic ET is derived from ocean current temperature, and salinity variables. Estimates of...uncertainty in the model. Rigorously accurate ensemble methods for describing the distribution of future states given past information include particle

  13. Quantitative effects of composting state variables on C/N ratio through GA-aided multivariate analysis.

    PubMed

    Sun, Wei; Huang, Guo H; Zeng, Guangming; Qin, Xiaosheng; Yu, Hui

    2011-03-01

    It is widely known that variation of the C/N ratio is dependent on many state variables during composting processes. This study attempted to develop a genetic algorithm aided stepwise cluster analysis (GASCA) method to describe the nonlinear relationships between the selected state variables and the C/N ratio in food waste composting. The experimental data from six bench-scale composting reactors were used to demonstrate the applicability of GASCA. Within the GASCA framework, GA searched optimal sets of both specified state variables and SCA's internal parameters; SCA established statistical nonlinear relationships between state variables and the C/N ratio; to avoid unnecessary and time-consuming calculation, a proxy table was introduced to save around 70% computational efforts. The obtained GASCA cluster trees had smaller sizes and higher prediction accuracy than the conventional SCA trees. Based on the optimal GASCA tree, the effects of the GA-selected state variables on the C/N ratio were ranged in a descending order as: NH₄+-N concentration>Moisture content>Ash Content>Mean Temperature>Mesophilic bacteria biomass. Such a rank implied that the variation of ammonium nitrogen concentration, the associated temperature and the moisture conditions, the total loss of both organic matters and available mineral constituents, and the mesophilic bacteria activity, were critical factors affecting the C/N ratio during the investigated food waste composting. This first application of GASCA to composting modelling indicated that more direct search algorithms could be coupled with SCA or other multivariate analysis methods to analyze complicated relationships during composting and many other environmental processes. Copyright © 2010 Elsevier B.V. All rights reserved.

  14. Monolith electroplating process

    DOEpatents

    Agarrwal, Rajev R.

    2001-01-01

    An electroplating process for preparing a monolith metal layer over a polycrystalline base metal and the plated monolith product. A monolith layer has a variable thickness of one crystal. The process is typically carried in molten salts electrolytes, such as the halide salts under an inert atmosphere at an elevated temperature, and over deposition time periods and film thickness sufficient to sinter and recrystallize completely the nucleating metal particles into one single crystal or crystals having very large grains. In the process, a close-packed film of submicron particle (20) is formed on a suitable substrate at an elevated temperature. The temperature has the significance of annealing particles as they are formed, and substrates on which the particles can populate are desirable. As the packed bed thickens, the submicron particles develop necks (21) and as they merge into each other shrinkage (22) occurs. Then as micropores also close (23) by surface tension, metal density is reached and the film consists of unstable metal grain (24) that at high enough temperature recrystallize (25) and recrystallized grains grow into an annealed single crystal over the electroplating time span. While cadmium was used in the experimental work, other soft metals may be used.

  15. Broad-scale adaptive genetic variation in alpine plants is driven by temperature and precipitation

    PubMed Central

    MANEL, STÉPHANIE; GUGERLI, FELIX; THUILLER, WILFRIED; ALVAREZ, NADIR; LEGENDRE, PIERRE; HOLDEREGGER, ROLF; GIELLY, LUDOVIC; TABERLET, PIERRE

    2014-01-01

    Identifying adaptive genetic variation is a challenging task, in particular in non-model species for which genomic information is still limited or absent. Here, we studied distribution patterns of amplified fragment length polymorphisms (AFLPs) in response to environmental variation, in 13 alpine plant species consistently sampled across the entire European Alps. Multiple linear regressions were performed between AFLP allele frequencies per site as dependent variables and two categories of independent variables, namely Moran’s eigenvector map MEM variables (to account for spatial and unaccounted environmental variation, and historical demographic processes) and environmental variables. These associations allowed the identification of 153 loci of ecological relevance. Univariate regressions between allele frequency and each environmental factor further showed that loci of ecological relevance were mainly correlated with MEM variables. We found that precipitation and temperature were the best environmental predictors, whereas topographic factors were rarely involved in environmental associations. Climatic factors, subject to rapid variation as a result of the current global warming, are known to strongly influence the fate of alpine plants. Our study shows, for the first time for a large number of species, that the same environmental variables are drivers of plant adaptation at the scale of a whole biome, here the European Alps. PMID:22680783

  16. Spatiotemporal correlation structure of the Earth's surface temperature

    NASA Astrophysics Data System (ADS)

    Fredriksen, Hege-Beate; Rypdal, Kristoffer; Rypdal, Martin

    2015-04-01

    We investigate the spatiotemporal temperature variability for several gridded instrumental and climate model data sets. The temporal variability is analysed by estimating the power spectral density and studying the differences between local and global temperatures, land and sea, and among local temperature records at different locations. The spatiotemporal correlation structure is analysed through cross-spectra that allow us to compute frequency-dependent spatial autocorrelation functions (ACFs). Our results are then compared to theoretical spectra and frequency-dependent spatial ACFs derived from a fractional stochastic-diffusive energy balance model (FEBM). From the FEBM we expect both local and global temperatures to have a long-range persistent temporal behaviour, and the spectral exponent (β) is expected to increase by a factor of two when going from local to global scales. Our comparison of the average local spectrum and the global spectrum shows good agreement with this model, although the FEBM has so far only been studied for a pure land planet and a pure ocean planet, respectively, with no seasonal forcing. Hence it cannot capture the substantial variability among the local spectra, in particular between the spectra for land and sea, and for equatorial and non-equatorial temperatures. Both models and observation data show that land temperatures in general have a low persistence, while sea surface temperatures show a higher, and also more variable degree of persistence. Near the equator the spectra deviate from the power-law shape expected from the FEBM. Instead we observe large variability at time scales of a few years due to ENSO, and a flat spectrum at longer time scales, making the spectrum more reminiscent of that of a red noise process. From the frequency-dependent spatial ACFs we observe that the spatial correlation length increases with increasing time scale, which is also consistent with the FEBM. One consequence of this is that longer-lasting structures must also be wider in space. The spatial correlation length is also observed to be longer for land than for sea. The climate model simulations studied are mainly CMIP5 control runs of length 500-1000 yr. On time scales up to several centuries we do not observe that the difference between the local and global spectral exponents vanish. This also follows from the FEBM and shows that the dynamics is spatiotemporal (not just temporal) even on these time scales.

  17. Model evaluation of temperature dependency for carbon and nitrogen removal in a full-scale activated sludge plant treating leather-tanning wastewater.

    PubMed

    Görgün, Erdem; Insel, Güçlü; Artan, Nazik; Orhon, Derin

    2007-05-01

    Organic carbon and nitrogen removal performance of a full-scale activated sludge plant treating pre-settled leather tanning wastewater was evaluated under dynamic process temperatures. Emphasis was placed upon observed nitrogen removal depicting a highly variable magnitude with changing process temperatures. As the plant was not specifically designed for this purpose, observed nitrogen removal could be largely attributed to simultaneous nitrification and denitrification presumably occurring at increased process temperatures (T>25 degrees C) and resulting low dissolved oxygen levels (DO<0.5 mgO2/L). Model evaluation using long-term data revealed that the yearly performance of activated sludge reactor could be successfully calibrated by means of temperature dependent parameters associated with nitrification, hydrolysis, ammonification and endogenous decay parameters. In this context, the Arrhenius coefficients of (i) for the maximum autotrophic growth rate, [image omitted]A, (ii) maximum hydrolysis rate, khs and (iii) endogenous heterotrophic decay rate, bH were found to be 1.045, 1.070 and 1.035, respectively. The ammonification rate (ka) defining the degradation of soluble organic nitrogen could not be characterized however via an Arrhenius-type equation.

  18. Optimization of thermal processing of canned mussels.

    PubMed

    Ansorena, M R; Salvadori, V O

    2011-10-01

    The design and optimization of thermal processing of solid-liquid food mixtures, such as canned mussels, requires the knowledge of the thermal history at the slowest heating point. In general, this point does not coincide with the geometrical center of the can, and the results show that it is located along the axial axis at a height that depends on the brine content. In this study, a mathematical model for the prediction of the temperature at this point was developed using the discrete transfer function approach. Transfer function coefficients were experimentally obtained, and prediction equations fitted to consider other can dimensions and sampling interval. This model was coupled with an optimization routine in order to search for different retort temperature profiles to maximize a quality index. Both constant retort temperature (CRT) and variable retort temperature (VRT; discrete step-wise and exponential) were considered. In the CRT process, the optimal retort temperature was always between 134 °C and 137 °C, and high values of thiamine retention were achieved. A significant improvement in surface quality index was obtained for optimal VRT profiles compared to optimal CRT. The optimization procedure shown in this study produces results that justify its utilization in the industry.

  19. Investigation of JP-8 Autoignition Under Vitiated Combustion Conditions

    DTIC Science & Technology

    2011-01-01

    no less than 1.5 times the dew point temperature of the mixture for all test cases that involved H2O. The flow path and apparatus for the steam...Variable m Interaction Effect of Design Variables m and n R Universal Gas Constant [cal/mol-K] E Activation Energy of Ignition Process [cal/mol] T...combustion including CO2, CO, H2O, and NOX. Vitiated conditions are often the result of flue or exhaust gas recirculation (EGR) into a fresh air stream

  20. Study of flexural rigidity of weavable powder-coated towpreg

    NASA Technical Reports Server (NTRS)

    Hirt, Douglas E.; Marchello, Joseph M.; Baucom, Robert M.

    1990-01-01

    An effort has been made to weave powder-impregnated tow into a two-dimensional preform, controlling process variables to obtain high flexural rigidity in the warp direction and greater flexibility in the fill direction. The resulting prepregs have been consolidated into laminates with LaRC-TPI matrices. Complementary SEM and DSC studies have been performed to deepen understanding of the relationship between tow flexibility and heat treatment. Attention is also given to the oven temperature and residence time variables' effects on power/fiber fusion.

  1. Trends and Variability in Temperature Sensitivity of Lilac Flowering Phenology

    NASA Astrophysics Data System (ADS)

    Wang, Huanjiong; Dai, Junhu; Rutishauser, This; Gonsamo, Alemu; Wu, Chaoyang; Ge, Quansheng

    2018-03-01

    The responses of plant phenology to temperature variability have many consequences for ecological processes, agriculture, forestry, and human health. Temperature sensitivity (ST) of phenology could measure how and to what degree plant could phenologically track climate change. The long-term trends and spatial patterns in ST have been well studied for vegetative phenology such as leaf unfolding, but trends to be expected for reproductive phenology in the future remain unknown. Here we investigate trends and factors driving the temporal variation of ST of first bloom date (FBD). Using the long-term FBD records during 1963-2013 for common lilac (Syringa vulgaris) from 613 stations in Europe, we compared changes in ST from the beginning to the end of the study period. The Spearman partial correlations were used to assess the importance of four influencing factors. The results showed that the temporal changes in ST of FBD varied considerably among time scales. Mean ST decreased significantly by 0.92 days °C-1 from 1963-1972 to 2004-2013 (P < 0.01), but remained stable from 1963-1987 to 1989-2013. The strength of FBD and temperature relationship, the spring temperature variance, and winter chill all impact ST in an expected way at most stations. No consistent responses of ST on photoperiod were found. Our results imply that the trends and variability in ST of flowering phenology are driving by multiple factors and impacted by time scales. Continued efforts are still needed to further examine the flowering-temperature relationship for other plant species in other climates and environments using similar methods to our study.

  2. Thermal acclimation of photosynthesis: on the importance of adjusting our definitions and accounting for thermal acclimation of respiration.

    PubMed

    Way, Danielle A; Yamori, Wataru

    2014-02-01

    While interest in photosynthetic thermal acclimation has been stimulated by climate warming, comparing results across studies requires consistent terminology. We identify five types of photosynthetic adjustments in warming experiments: photosynthesis as measured at the high growth temperature, the growth temperature, and the thermal optimum; the photosynthetic thermal optimum; and leaf-level photosynthetic capacity. Adjustments of any one of these variables need not mean a concurrent adjustment in others, which may resolve apparently contradictory results in papers using different indicators of photosynthetic acclimation. We argue that photosynthetic thermal acclimation (i.e., that benefits a plant in its new growth environment) should include adjustments of both the photosynthetic thermal optimum (T opt) and photosynthetic rates at the growth temperature (A growth), a combination termed constructive adjustment. However, many species show reduced photosynthesis when grown at elevated temperatures, despite adjustment of some photosynthetic variables, a phenomenon we term detractive adjustment. An analysis of 70 studies on 103 species shows that adjustment of T opt and A growth are more common than adjustment of other photosynthetic variables, but only half of the data demonstrate constructive adjustment. No systematic differences in these patterns were found between different plant functional groups. We also discuss the importance of thermal acclimation of respiration for net photosynthesis measurements, as respiratory temperature acclimation can generate apparent acclimation of photosynthetic processes, even if photosynthesis is unaltered. We show that while dark respiration is often used to estimate light respiration, the ratio of light to dark respiration shifts in a non-predictable manner with a change in leaf temperature.

  3. Impact of the Dominant Large-scale Teleconnections on Winter Temperature Variability over East Asia

    NASA Technical Reports Server (NTRS)

    Lim, Young-Kwon; Kim, Hae-Dong

    2013-01-01

    Monthly mean geopotential height for the past 33 DJF seasons archived in Modern Era Retrospective analysis for Research and Applications reanalysis is decomposed into the large-scale teleconnection patterns to explain their impacts on winter temperature variability over East Asia. Following Arctic Oscillation (AO) that explains the largest variance, East Atlantic/West Russia (EA/WR), West Pacific (WP) and El Nino-Southern Oscillation (ENSO) are identified as the first four leading modes that significantly explain East Asian winter temperature variation. While the northern part of East Asia north of 50N is prevailed by AO and EA/WR impacts, temperature in the midlatitudes (30N-50N), which include Mongolia, northeastern China, Shandong area, Korea, and Japan, is influenced by combined effect of the four leading teleconnections. ENSO impact on average over 33 winters is relatively weaker than the impact of the other three teleconnections. WP impact, which has received less attention than ENSO in earlier studies, characterizes winter temperatures over Korea, Japan, and central to southern China region south of 30N mainly by advective process from the Pacific. Upper level wave activity fluxes reveal that, for the AO case, the height and circulation anomalies affecting midlatitude East Asian winter temperature is mainly located at higher latitudes north of East Asia. Distribution of the fluxes also explains that the stationary wave train associated with EA/WR propagates southeastward from the western Russia, affecting the East Asian winter temperature. Investigation on the impact of each teleconnection for the selected years reveals that the most dominant teleconnection over East Asia is not the same at all years, indicating a great deal of interannual variability. Comparison in temperature anomaly distributions between observation and temperature anomaly constructed using the combined effect of four leading teleconnections clearly show a reasonable consistency between them, demonstrating that the seasonal winter temperature distributions over East Asia are substantially explained by these four large-scale circulation impacts.

  4. Consolidation and Warpage Deformation Finite Element Analysis of Filament Wound Tubes

    NASA Astrophysics Data System (ADS)

    Li, Jun; Dong, Chensong; Chen, Shenshen

    2009-10-01

    This paper presents a process model for simulating the manufacturing process of prepreg filament wound composite tubes developed based on the finite element analysis. The model relates the process variables, such as degree of cure, viscosity, material property and temperature etc., to the parameters characterizing (residual stresses, warpage deformation) the composite tube and the mandrel. From the simulating results, several important trends in both the data and model are observed (1) Low temperature will go with low reaction rate and the reaction starts under low temperature will later compared with high temperature; (2) The results using CHILE model after demolding will smaller than the one using linear elasticity which assumes a stress-free prior to cool-down. After the mandrel (mold) is removed, some residual stresses, especially hoop stress will be released. (3) Remarkable stress concentration appeared in the transition zone between the boss and cylinder. In order to prevent the structural failure due to interlaminar shear or delamination, both the outer surface of the cylinder and the inner of the boss should have the same ply orientation angle.

  5. Assessment of infant formula quality and composition using Vis-NIR, MIR and Raman process analytical technologies.

    PubMed

    Wang, Xiao; Esquerre, Carlos; Downey, Gerard; Henihan, Lisa; O'Callaghan, Donal; O'Donnell, Colm

    2018-06-01

    In this study, visible and near-infrared (Vis-NIR), mid-infrared (MIR) and Raman process analytical technologies were investigated for assessment of infant formula quality and compositional parameters namely preheat temperature, storage temperature, storage time, fluorescence of advanced Maillard products and soluble tryptophan (FAST) index, soluble protein, fat and surface free fat (SFF) content. PLS-DA models developed using spectral data with appropriate data pre-treatment and significant variables selected using Martens' uncertainty test had good accuracy for the discrimination of preheat temperature (92.3-100%) and storage temperature (91.7-100%). The best PLS regression models developed yielded values for the ratio of prediction error to deviation (RPD) of 3.6-6.1, 2.1-2.7, 1.7-2.9, 1.6-2.6 and 2.5-3.0 for storage time, FAST index, soluble protein, fat and SFF content prediction respectively. Vis-NIR, MIR and Raman were demonstrated to be potential PAT tools for process control and quality assurance applications in infant formula and dairy ingredient manufacture. Copyright © 2018 Elsevier B.V. All rights reserved.

  6. Numerical modelling of biomass combustion: Solid conversion processes in a fixed bed furnace

    NASA Astrophysics Data System (ADS)

    Karim, Md. Rezwanul; Naser, Jamal

    2017-06-01

    Increasing demand for energy and rising concerns over global warming has urged the use of renewable energy sources to carry a sustainable development of the world. Bio mass is a renewable energy which has become an important fuel to produce thermal energy or electricity. It is an eco-friendly source of energy as it reduces carbon dioxide emissions. Combustion of solid biomass is a complex phenomenon due to its large varieties and physical structures. Among various systems, fixed bed combustion is the most commonly used technique for thermal conversion of solid biomass. But inadequate knowledge on complex solid conversion processes has limited the development of such combustion system. Numerical modelling of this combustion system has some advantages over experimental analysis. Many important system parameters (e.g. temperature, density, solid fraction) can be estimated inside the entire domain under different working conditions. In this work, a complete numerical model is used for solid conversion processes of biomass combustion in a fixed bed furnace. The combustion system is divided in to solid and gas phase. This model includes several sub models to characterize the solid phase of the combustion with several variables. User defined subroutines are used to introduce solid phase variables in commercial CFD code. Gas phase of combustion is resolved using built-in module of CFD code. Heat transfer model is modified to predict the temperature of solid and gas phases with special radiation heat transfer solution for considering the high absorptivity of the medium. Considering all solid conversion processes the solid phase variables are evaluated. Results obtained are discussed with reference from an experimental burner.

  7. Estuary-ocean connectivity: fast physics, slow biology.

    PubMed

    Raimonet, Mélanie; Cloern, James E

    2017-06-01

    Estuaries are connected to both land and ocean so their physical, chemical, and biological dynamics are influenced by climate patterns over watersheds and ocean basins. We explored climate-driven oceanic variability as a source of estuarine variability by comparing monthly time series of temperature and chlorophyll-a inside San Francisco Bay with those in adjacent shelf waters of the California Current System (CCS) that are strongly responsive to wind-driven upwelling. Monthly temperature fluctuations inside and outside the Bay were synchronous, but their correlations weakened with distance from the ocean. These results illustrate how variability of coastal water temperature (and associated properties such as nitrate and oxygen) propagates into estuaries through fast water exchanges that dissipate along the estuary. Unexpectedly, there was no correlation between monthly chlorophyll-a variability inside and outside the Bay. However, at the annual scale Bay chlorophyll-a was significantly correlated with the Spring Transition Index (STI) that sets biological production supporting fish recruitment in the CCS. Wind forcing of the CCS shifted in the late 1990s when the STI advanced 40 days. This shift was followed, with lags of 1-3 years, by 3- to 19-fold increased abundances of five ocean-produced demersal fish and crustaceans and 2.5-fold increase of summer chlorophyll-a in the Bay. These changes reflect a slow biological process of estuary-ocean connectivity operating through the immigration of fish and crustaceans that prey on bivalves, reduce their grazing pressure, and allow phytoplankton biomass to build. We identified clear signals of climate-mediated oceanic variability in this estuary and discovered that the response patterns vary with the process of connectivity and the timescale of ocean variability. This result has important implications for managing nutrient inputs to estuaries connected to upwelling systems, and for assessing their responses to changing patterns of upwelling timing and intensity as the planet continues to warm. © 2016 Published by John Wiley & Sons Ltd This article has been contributed to by US Government employees and their work is in the public domain in the USA.

  8. Interannual variation of carbon fluxes from three contrasting evergreen forests: the role of forest dynamics and climate.

    PubMed

    Sierra, Carlos A; Loescher, Henry W; Harmon, Mark E; Richardson, Andrew D; Hollinger, David Y; Perakis, Steven S

    2009-10-01

    Interannual variation of carbon fluxes can be attributed to a number of biotic and abiotic controls that operate at different spatial and temporal scales. Type and frequency of disturbance, forest dynamics, and climate regimes are important sources of variability. Assessing the variability of carbon fluxes from these specific sources can enhance the interpretation of past and current observations. Being able to separate the variability caused by forest dynamics from that induced by climate will also give us the ability to determine if the current observed carbon fluxes are within an expected range or whether the ecosystem is undergoing unexpected change. Sources of interannual variation in ecosystem carbon fluxes from three evergreen ecosystems, a tropical, a temperate coniferous, and a boreal forest, were explored using the simulation model STANDCARB. We identified key processes that introduced variation in annual fluxes, but their relative importance differed among the ecosystems studied. In the tropical site, intrinsic forest dynamics contributed approximately 30% of the total variation in annual carbon fluxes. In the temperate and boreal sites, where many forest processes occur over longer temporal scales than those at the tropical site, climate controlled more of the variation among annual fluxes. These results suggest that climate-related variability affects the rates of carbon exchange differently among sites. Simulations in which temperature, precipitation, and radiation varied from year to year (based on historical records of climate variation) had less net carbon stores than simulations in which these variables were held constant (based on historical records of monthly average climate), a result caused by the functional relationship between temperature and respiration. This suggests that, under a more variable temperature regime, large respiratory pulses may become more frequent and high enough to cause a reduction in ecosystem carbon stores. Our results also show that the variation of annual carbon fluxes poses an important challenge in our ability to determine whether an ecosystem is a source, a sink, or is neutral in regard to CO2 at longer timescales. In simulations where climate change negatively affected ecosystem carbon stores, there was a 20% chance of committing Type II error, even with 20 years of sequential data.

  9. The effects of sampling frequency on the climate statistics of the European Centre for Medium-Range Weather Forecasts

    NASA Astrophysics Data System (ADS)

    Phillips, Thomas J.; Gates, W. Lawrence; Arpe, Klaus

    1992-12-01

    The effects of sampling frequency on the first- and second-moment statistics of selected European Centre for Medium-Range Weather Forecasts (ECMWF) model variables are investigated in a simulation of "perpetual July" with a diurnal cycle included and with surface and atmospheric fields saved at hourly intervals. The shortest characteristic time scales (as determined by the e-folding time of lagged autocorrelation functions) are those of ground heat fluxes and temperatures, precipitation and runoff, convective processes, cloud properties, and atmospheric vertical motion, while the longest time scales are exhibited by soil temperature and moisture, surface pressure, and atmospheric specific humidity, temperature, and wind. The time scales of surface heat and momentum fluxes and of convective processes are substantially shorter over land than over oceans. An appropriate sampling frequency for each model variable is obtained by comparing the estimates of first- and second-moment statistics determined at intervals ranging from 2 to 24 hours with the "best" estimates obtained from hourly sampling. Relatively accurate estimation of first- and second-moment climate statistics (10% errors in means, 20% errors in variances) can be achieved by sampling a model variable at intervals that usually are longer than the bandwidth of its time series but that often are shorter than its characteristic time scale. For the surface variables, sampling at intervals that are nonintegral divisors of a 24-hour day yields relatively more accurate time-mean statistics because of a reduction in errors associated with aliasing of the diurnal cycle and higher-frequency harmonics. The superior estimates of first-moment statistics are accompanied by inferior estimates of the variance of the daily means due to the presence of systematic biases, but these probably can be avoided by defining a different measure of low-frequency variability. Estimates of the intradiurnal variance of accumulated precipitation and surface runoff also are strongly impacted by the length of the storage interval. In light of these results, several alternative strategies for storage of the EMWF model variables are recommended.

  10. Characterizing Temperature Variability and Associated Large Scale Meteorological Patterns Across South America

    NASA Astrophysics Data System (ADS)

    Detzer, J.; Loikith, P. C.; Mechoso, C. R.; Barkhordarian, A.; Lee, H.

    2017-12-01

    South America's climate varies considerably owing to its large geographic range and diverse topographical features. Spanning the tropics to the mid-latitudes and from high peaks to tropical rainforest, the continent experiences an array of climate and weather patterns. Due to this considerable spatial extent, assessing temperature variability at the continent scale is particularly challenging. It is well documented in the literature that temperatures have been increasing across portions of South America in recent decades, and while there have been many studies that have focused on precipitation variability and change, temperature has received less scientific attention. Therefore, a more thorough understanding of the drivers of temperature variability is critical for interpreting future change. First, k-means cluster analysis is used to identify four primary modes of temperature variability across the continent, stratified by season. Next, composites of large scale meteorological patterns (LSMPs) are calculated for months assigned to each cluster. Initial results suggest that LSMPs, defined using meteorological variables such as sea level pressure (SLP), geopotential height, and wind, are able to identify synoptic scale mechanisms important for driving temperature variability at the monthly scale. Some LSMPs indicate a relationship with known recurrent modes of climate variability. For example, composites of geopotential height suggest that the Southern Annular Mode is an important, but not necessarily dominant, component of temperature variability over southern South America. This work will be extended to assess the drivers of temperature extremes across South America.

  11. Fuzzy logic control of rotating drum bioreactor for improved production of amylase and protease enzymes by Aspergillus oryzae in solid-state fermentation.

    PubMed

    Sukumprasertsri, Monton; Unrean, Pornkamol; Pimsamarn, Jindarat; Kitsubun, Panit; Tongta, Anan

    2013-03-01

    In this study, we compared the performance of two control systems, fuzzy logic control (FLC) and conventional control (CC). The control systems were applied for controlling temperature and substrate moisture content in a solidstate fermentation for the biosynthesis of amylase and protease enzymes by Aspergillus oryzae. The fermentation process was achieved in a 200 L rotating drum bioreactor. Three factors affecting temperature and moisture content in the solid-state fermentation were considered. They were inlet air velocity, speed of the rotating drum bioreactor, and spray water addition. The fuzzy logic control system was designed using four input variables: air velocity, substrate temperature, fermentation time, and rotation speed. The temperature was controlled by two variables, inlet air velocity and rotational speed of bioreactor, while the moisture content was controlled by spray water. Experimental results confirmed that the FLC system could effectively control the temperature and moisture content of substrate better than the CC system, resulting in an increased enzyme production by A. oryzae. Thus, the fuzzy logic control is a promising control system that can be applied for enhanced production of enzymes in solidstate fermentation.

  12. Photothermal waves for two temperature with a semiconducting medium under using a dual-phase-lag model and hydrostatic initial stress

    NASA Astrophysics Data System (ADS)

    Lotfy, Kh.

    2017-07-01

    The dual-phase-lag (DPL) model with two different time translations and Lord-Shulman (LS) theory with one relaxation time are applied to study the effect of hydrostatic initial stress on medium under the influence of two temperature parameter(a new model will be introduced using two temperature theory) and photothermal theory. We solved the thermal loading at the free surface in the semi-infinite semiconducting medium-coupled plasma waves with the effect of mechanical force during a photothermal process. The exact expressions of the considered variables are obtained using normal mode analysis also the two temperature coefficient ratios were obtained analytically. Numerical results for the field quantities are given in the physical domain and illustrated graphically under the effects of several parameters. Comparisons are made between the results of the two different models with and without two temperature parameter, and for two different values of the hydrostatic initial stress. A comparison is carried out between the considered variables as calculated from the generalized thermoelasticity based on the DPL model and the LS theory in the absence and presence of the thermoelastic and thermoelectric coupling parameters.

  13. Amplification and dampening of soil respiration by changes in temperature variability

    USGS Publications Warehouse

    Sierra, C.A.; Harmon, M.E.; Thomann, E.; Perakis, S.S.; Loescher, H.W.

    2011-01-01

    Accelerated release of carbon from soils is one of the most important feed backs related to anthropogenically induced climate change. Studies addressing the mechanisms for soil carbon release through organic matter decomposition have focused on the effect of changes in the average temperature, with little attention to changes in temperature vari-ability. Anthropogenic activities are likely to modify both the average state and the variability of the climatic system; therefore, the effects of future warming on decomposition should not only focus on trends in the average temperature, but also variability expressed as a change of the probability distribution of temperature.Using analytical and numerical analyses we tested common relationships between temperature and respiration and found that the variability of temperature plays an important role determining respiration rates of soil organic matter. Changes in temperature variability, without changes in the average temperature, can affect the amount of carbon released through respiration over the long term. Furthermore, simultaneous changes in the average and variance of temperature can either amplify or dampen there release of carbon through soil respiration as climate regimes change. The effects depend on the degree of convexity of the relationship between temperature and respiration and the magnitude of the change in temperature variance. A potential consequence of this effect of variability would be higher respiration in regions where both the mean and variance of temperature are expected to increase, such as in some low latitude regions; and lower amounts of respiration where the average temperature is expected to increase and the variance to decrease, such as in northern high latitudes.

  14. Fine-Scale Variability in Temperature, Salinity, and pH in the Upper-Ocean and the Effects on Acoustic Transmission Loss in the Western Arctic Ocean.

    DTIC Science & Technology

    2010-03-01

    28  V.  ANALYTIC METHOD AND DATA ANALYSIS ..................................................29  A.  DATA PROCESSING ...your help getting ready for the Arctic and with the data processing back at NPS. Thank you to Professor John Colosi and LCDR Ben Jones for your help...light. Acoustic energy, however, can propagate for very long ranges (Kinsler et al. 2000). This energy can be passively received and processed , and

  15. Processes of 30-90 days sea surface temperature variability in the northern Indian Ocean during boreal summer

    NASA Astrophysics Data System (ADS)

    Vialard, J.; Jayakumar, A.; Gnanaseelan, C.; Lengaigne, M.; Sengupta, D.; Goswami, B. N.

    2012-05-01

    During summer, the northern Indian Ocean exhibits significant atmospheric intraseasonal variability associated with active and break phases of the monsoon in the 30-90 days band. In this paper, we investigate mechanisms of the Sea Surface Temperature (SST) signature of this atmospheric variability, using a combination of observational datasets and Ocean General Circulation Model sensitivity experiments. In addition to the previously-reported intraseasonal SST signature in the Bay of Bengal, observations show clear SST signals in the Arabian Sea related to the active/break cycle of the monsoon. As the atmospheric intraseasonal oscillation moves northward, SST variations appear first at the southern tip of India (day 0), then in the Somali upwelling region (day 10), northern Bay of Bengal (day 19) and finally in the Oman upwelling region (day 23). The Bay of Bengal and Oman signals are most clearly associated with the monsoon active/break index, whereas the relationship with signals near Somali upwelling and the southern tip of India is weaker. In agreement with previous studies, we find that heat flux variations drive most of the intraseasonal SST variability in the Bay of Bengal, both in our model (regression coefficient, 0.9, against ~0.25 for wind stress) and in observations (0.8 regression coefficient); ~60% of the heat flux variation is due do shortwave radiation and ~40% due to latent heat flux. On the other hand, both observations and model results indicate a prominent role of dynamical oceanic processes in the Arabian Sea. Wind-stress variations force about 70-100% of SST intraseasonal variations in the Arabian Sea, through modulation of oceanic processes (entrainment, mixing, Ekman pumping, lateral advection). Our ~100 km resolution model suggests that internal oceanic variability (i.e. eddies) contributes substantially to intraseasonal variability at small-scale in the Somali upwelling region, but does not contribute to large-scale intraseasonal SST variability due to its small spatial scale and random phase relation to the active-break monsoon cycle. The effect of oceanic eddies; however, remains to be explored at a higher spatial resolution.

  16. Climate Impact of Solar Variability

    NASA Technical Reports Server (NTRS)

    Schatten, Kenneth H. (Editor); Arking, Albert (Editor)

    1990-01-01

    The conference on The Climate Impact of Solar Variability, was held at Goddard Space Flight Center from April 24 to 27, 1990. In recent years they developed a renewed interest in the potential effects of increasing greenhouse gases on climate. Carbon dioxide, methane, nitrous oxide, and the chlorofluorocarbons have been increasing at rates that could significantly change climate. There is considerable uncertainty over the magnitude of this anthropogenic change. The climate system is very complex, with feedback processes that are not fully understood. Moreover, there are two sources of natural climate variability (volcanic aerosols and solar variability) added to the anthropogenic changes which may confuse our interpretation of the observed temperature record. Thus, if we could understand the climatic impact of the natural variability, it would aid our interpretation and understanding of man-made climate changes.

  17. Experimental assessment of the purity of α-cellulose produced by variations of the Brendel method: Implications for stable isotope (δ13C, δ18O) dendroclimatology

    NASA Astrophysics Data System (ADS)

    Brookman, Tom; Whittaker, Thomas

    2012-09-01

    Stable isotope dendroclimatology using α-cellulose has unique potential to deliver multimillennial-scale, sub-annually resolved, terrestrial climate records. However, lengthy processing and analytical methods often preclude such reconstructions. Variants of the Brendel extraction method have reduced these limitations, providing fast, easy methods of isolating α-cellulose in some species. Here, we investigate application of Standard Brendel (SBrendel) variants to resinous soft-woods by treating samples of kauri (Agathis australis), ponderosa pine (Pinus ponderosa) and huon pine (Lagarastrobus franklinii), varying reaction vessel, temperature, boiling time and reagent volume. Numerous samples were visibly `under-processed' and Fourier Transform infrared spectroscopic (FTIR) investigation showed absorption peaks at 1520 cm-1 and ˜1600 cm-1 in those fibers suggesting residual lignin and retained resin respectively. Replicate analyses of all samples processed at high temperature yielded consistent δ13C and δ18O despite color and spectral variations. Spectra and isotopic data revealed that α-cellulose δ13C can be altered during processing, most likely due to chemical contamination from insufficient acetone removal, but is not systematically affected by methodological variation. Reagent amount, temperature and extraction time all influence δ18O, however, and our results demonstrate that different species may require different processing methods. FTIR prior to isotopic analysis is a fast and cost effective way to determine α-cellulose extract purity. Furthermore, a systematic isotopic test such as we present here can also determine sensitivity of isotopic values to methodological variables. Without these tests, isotopic variability introduced by the method could obscure or `create' climatic signals within a data set.

  18. The contribution of carotid rete variability to brain temperature variability in sheep in a thermoneutral environment.

    PubMed

    Maloney, Shane K; Mitchell, Duncan; Blache, Dominique

    2007-03-01

    The degree of variability in the temperature difference between the brain and carotid arterial blood is greater than expected from the presumed tight coupling between brain heat production and brain blood flow. In animals with a carotid rete, some of that variability arises in the rete. Using thermometric data loggers in five sheep, we have measured the temperature of arterial blood before it enters the carotid rete and after it has perfused the carotid rete, as well as hypothalamic temperature, every 2 min for between 6 and 12 days. The sheep were conscious, unrestrained, and maintained at an ambient temperature of 20-22 degrees C. On average, carotid arterial blood and brain temperatures were the same, with a decrease in blood temperature of 0.35 degrees C across the rete and then an increase in temperature of the same magnitude between blood leaving the rete and the brain. Rete cooling of arterial blood took place at temperatures below the threshold for selective brain cooling. All of the variability in the temperature difference between carotid artery and brain was attributable statistically to variability in the temperature difference across the rete. The temperature difference between arterial blood leaving the rete and the brain varied from -0.1 to 0.9 degrees C. Some of this variability was related to a thermal inertia of the brain, but the majority we attribute to instability in the relationship between brain blood flow and brain heat production.

  19. CHIP MORPHOLOGY AND HOLE SURFACE TEXTURE IN THE DRILLING OF CAST ALUMINUM ALLOYS. (R825370C057)

    EPA Science Inventory

    The effects of cutting fluid and other process variables on chip morphology when drilling cast aluminium alloys are investigated. The effects of workpiece material, speed, feed, hole depth, cutting-fluid presence and percentage oil concentration, workpiece temperature, drill t...

  20. Evaluation of thermal processing variables for reducing acrylamide in canned black ripe olives

    USDA-ARS?s Scientific Manuscript database

    Acrylamide formed in plant foods at elevated cooking temperatures has been identified as a probable carcinogen. A wide variation and high acrylamide concentration in commercial canned black ripe olives has been reported. The objective of this study was to determine if different safe sterilization co...

  1. 40 CFR 63.137 - Process wastewater provisions-oil-water separators.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... separators. 63.137 Section 63.137 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... for other emission variables such as temperature and barometric pressure, or (ii) An engineering...)(1) and the schedule specified in paragraphs (c)(1) and (c)(2) of this section. (1) Measurement of...

  2. An Investigation into the Effects of Sprue Attachment Design on Porosity and Castability

    DTIC Science & Technology

    1990-12-01

    of a dental alloy: sprue design, mold temperature, fusing and casting temperature of the alloy, type of casting machine, casting force, burnout time... Student at: University of Texas, San Antonio AFIT/CI/CIA-90-119 AFIT/CI Wright-Patterson AFB OH 45433-6583 Approved for Public Release IAW AFR 190-1...Supervising Professor: E. Steven Duke, D.D.S., M.S.D. Many variables are involved in the process of fabricating a dense dental casting which accurately

  3. Warpage analysis on thin shell part using glowworm swarm optimisation (GSO)

    NASA Astrophysics Data System (ADS)

    Zulhasif, Z.; Shayfull, Z.; Nasir, S. M.; Fathullah, M.; Hazwan, M. H. M.

    2017-09-01

    The Autodesk Moldflow Insight (AMI) software was used in this study to focuses on the analysis in plastic injection moulding process associate the input parameter and output parameter. The material used in this study is Acrylonitrile Butadiene Styrene (ABS) as the moulded material to produced the plastic part. The MATLAB sortware is a method was used to find the best setting parameter. The variables was selected in this study were melt temperature, packing pressure, coolant temperature and cooling time.

  4. A critique of assumptions about selecting chemical-resistant gloves: a case for workplace evaluation of glove efficacy.

    PubMed

    Klingner, Thomas D; Boeniger, Mark F

    2002-05-01

    Wearing chemical-resistant gloves and clothing is the primary method used to prevent skin exposure to toxic chemicals in the workplace. The process for selecting gloves is usually based on manufacturers' laboratory-generated chemical permeation data. However, such data may not reflect conditions in the workplace where many variables are encountered (e.g., elevated temperature, flexing, pressure, and product variation between suppliers). Thus, the reliance on this selection process is questionable. Variables that may influence the performance of chemical-resistant gloves are identified and discussed. Passive dermal monitoring is recommended to evaluate glove performance under actual-use conditions and can bridge the gap between laboratory data and real-world performance.

  5. Spatiotemporal investigation of long-term seasonal temperature variability in Libya

    NASA Astrophysics Data System (ADS)

    Elsharkawy, S. G.; Elmallah, E. S.

    2016-09-01

    Throughout this work, spatial and temporal variations of seasonal surface air temperature have been investigated. Moreover, the effects of relative internal (teleconnection) and external (solar) forcing on surface air temperature variability have been examined. Seasonal temperature time series covering 30 different meteorological locations and lasting over the last century are considered. These locations are classified into two groups based on their spatial distribution. One represents Coast Libya Surface Air Temperature (CLSAT), contains 19 locations, and the other represents Desert Libya Surface Air Temperature (DLSAT), contains 11 locations. Average temperature departure test is applied to investigate the nature of temperature variations. Temperature trends are analyzed using the nonparametric Mann-Kendall test and their coefficients are calculated using Sen's slope estimate. Cross-correlation and spectral analysis techniques are also applied. Our results showed temperature deviation from average within a band of ± 2°C at coast region, while ± 4°C at desert region. Extreme behavior intensions between summer and winter temperatures at coast region are noticed. Segmentation process declared reversal cooling/warming behavior within temperature records for all seasons. Desert region shows warming trend for all seasons with higher coefficients than obtained at coast region. Results obtained for spectral analysis show different short and medium signals and concluded that not only the spectral properties are different for different geographical regions but also different for different climatic seasons on regional scale as well. Cross-correlation results showed that highest influence for Rz upon coastal temperature is always in conjunction with highest influence of NAO upon coastal temperature during the period 1981-2010. Desert region does not obey this phenomenon, where highest temperature-NAO correlations at desert during autumn and winter seasons are not accompanied with highest correlations for temperature-Rz.

  6. Temperature-dependent growth of Botrytis cinerea isolates from potted plants.

    PubMed

    Martínez, J A; Gómez-Bellot, M J; Bañón, S

    2009-01-01

    Botrytis cinereo is a common aggressive saprophyte fungus which also invades injured plant tissues, causing Botrytis blight (Grey mould) in many ornamental plants, including potted flowering plants. Several B. cinerea isolates from potted plants (Pelargonium x hortorum, Lantana camara, Lonicera japonica, Hydrangea macrophylla, and Cyclamen persicum) affected by Botrytis blight in the south of Spain were studied and identified by PCR. The isolates showed phenotypic differences between them, as previously reported by the authors. In this work we demonstrate that these isolates show different temperature-dependent growth phenomena, expressed as mycelial growth rates, conidiation (measured as the number of conidia per colony and time of appearance), mass of both aerial and submerged mycelia, and sclerotia production. Growth rates were assessed from differences in colony area and mass of both aerial and submerged mycelium growing in potato dextrose agar culture medium (PDA). Three temperatures were used to measure these variables (6, 16, and 26 degrees C) and to establish the differences among isolates by modelling the effects of temperature on the growth variables. B. cinerea showed a high degree of phenotypic variability and differences in its growth kinetics, depending on temperature and isolate in question. The isolate from P. x hortorum showed the greatest conidiation although this process did not depend on the temperatures assayed. The growth rate of the isolates from P. x hortorum was the highest. The growth rates in all the isolates were determined and the growth kinetics could be fitted to a typical equation of fungi growing on solid culture medium. The isolate from P. x hortorum was the most vigorous, while the least vigorous was the isolate from L. japonica. A relationship between mycelial growth rate, conidiation and aerial mycelium could be established. A temperature of 26 degrees C accelerated sclerotia production, but only in the isolate from C. persicum. Such phenotypical variability and differences in growth rates may result in a differential response in plant-pathogen interactions when isolates attack hosts at different temperatures, meaning that a variety of plant protection strategies should be considered when B. cinerea attacks these potted plants.

  7. People as sensors: mass media and local temperature influence climate change discussion on Twitter

    NASA Astrophysics Data System (ADS)

    Kirilenko, A.; Molodtsova, T.; Stepchenkova, S.

    2014-12-01

    We examined whether people living under significant temperature anomalies connect their sensory experiences to climate change and the role that media plays in this process. We used Twitter messages containing words "climate change" and "global warming" as the indicator of attention that public pays to the issue. Specifically, the goals were: (1) to investigate whether people immediately notice significant local weather anomalies and connect them to climate change and (2) to examine the role of mass media in this process. Over 2 million tweets were collected for a two-year period (2012 - 2013) and were assigned to 157 urban areas in the continental USA (Figure 1). Geographical locations of the tweets were identified with a geolocation resolving algorithm based the profile of the users. Daily number of tweets (tweeting rate) was computed for 157 conterminous USA urban areas and adjusted for data acquisition errors. The USHCN daily minimum and maximum temperatures were obtained for the station locations closest to the centers of the urban areas and the 1981-2010 30-year temperature mean and standard deviation were used as the climate normals. For the analysis, we computed the following indices for each day of 2012 - 2013 period: standardized temperature anomaly, absolute standardized temperature anomaly, and extreme cold and hot temperature anomalies for each urban zone. The extreme cold and hot temperature anomalies were then transformed into country-level values that represent the number of people living in extreme temperature conditions. The rate of tweeting on climate change was regressed on the time variables, number of climate change publications in the mass media, and temperature. In the majority of regression models, the mass media and temperature variables were significant at the p<0.001 level. Additionally, we did not find convincing evidence that the media acts as a mediator in the relationship between local weather and climate change discourse intensity. Our analysis of Twitter data confirmed that the public is able to recognize extreme temperature anomalies and connects these anomalies to climate change. Finally, we demonstrated the utility of social network data for research on public climate change perception.

  8. Immersion-scanning-tunneling-microscope for long-term variable-temperature experiments at liquid-solid interfaces

    NASA Astrophysics Data System (ADS)

    Ochs, Oliver; Heckl, Wolfgang M.; Lackinger, Markus

    2018-05-01

    Fundamental insights into the kinetics and thermodynamics of supramolecular self-assembly on surfaces are uniquely gained by variable-temperature high-resolution Scanning-Tunneling-Microscopy (STM). Conventionally, these experiments are performed with standard ambient microscopes extended with heatable sample stages for local heating. However, unavoidable solvent evaporation sets a technical limit on the duration of these experiments, hence prohibiting long-term experiments. These, however, would be highly desirable to provide enough time for temperature stabilization and settling of drift but also to study processes with inherently slow kinetics. To overcome this dilemma, we propose a STM that can operate fully immersed in solution. The instrument is mounted onto the lid of a hermetically sealed heatable container that is filled with the respective solution. By closing the container, both the sample and microscope are immersed in solution. Thereby solvent evaporation is eliminated and an environment for long-term experiments with utmost stable and controllable temperatures between room-temperature and 100 °C is provided. Important experimental requirements for the immersion-STM and resulting design criteria are discussed, the strategy for protection against corrosive media is described, the temperature stability and drift behavior are thoroughly characterized, and first long-term high resolution experiments at liquid-solid interfaces are presented.

  9. Kiloampere, Variable-Temperature, Critical-Current Measurements of High-Field Superconductors

    PubMed Central

    Goodrich, LF; Cheggour, N; Stauffer, TC; Filla, BJ; Lu, XF

    2013-01-01

    We review variable-temperature, transport critical-current (Ic) measurements made on commercial superconductors over a range of critical currents from less than 0.1 A to about 1 kA. We have developed and used a number of systems to make these measurements over the last 15 years. Two exemplary variable-temperature systems with coil sample geometries will be described: a probe that is only variable-temperature and a probe that is variable-temperature and variable-strain. The most significant challenge for these measurements is temperature stability, since large amounts of heat can be generated by the flow of high current through the resistive sample fixture. Therefore, a significant portion of this review is focused on the reduction of temperature errors to less than ±0.05 K in such measurements. A key feature of our system is a pre-regulator that converts a flow of liquid helium to gas and heats the gas to a temperature close to the target sample temperature. The pre-regulator is not in close proximity to the sample and it is controlled independently of the sample temperature. This allows us to independently control the total cooling power, and thereby fine tune the sample cooling power at any sample temperature. The same general temperature-control philosophy is used in all of our variable-temperature systems, but the addition of another variable, such as strain, forces compromises in design and results in some differences in operation and protocol. These aspects are analyzed to assess the extent to which the protocols for our systems might be generalized to other systems at other laboratories. Our approach to variable-temperature measurements is also placed in the general context of measurement-system design, and the perceived advantages and disadvantages of design choices are presented. To verify the accuracy of the variable-temperature measurements, we compared critical-current values obtained on a specimen immersed in liquid helium (“liquid” or Ic liq) at 5 K to those measured on the same specimen in flowing helium gas (“gas” or Ic gas) at the same temperature. These comparisons indicate the temperature control is effective over the superconducting wire length between the voltage taps, and this condition is valid for all types of sample investigated, including Nb-Ti, Nb3Sn, and MgB2 wires. The liquid/gas comparisons are used to study the variable-temperature measurement protocol that was necessary to obtain the “correct” critical current, which was assumed to be the Ic liq. We also calibrated the magnetoresistance effect of resistive thermometers for temperatures from 4 K to 35 K and magnetic fields from 0 T to 16 T. This calibration reduces systematic errors in the variable-temperature data, but it does not affect the liquid/gas comparison since the same thermometers are used in both cases. PMID:26401435

  10. Temperature Trends in the White Mountains of New Hampshire

    NASA Astrophysics Data System (ADS)

    Murray, G.; Kelsey, E. P.; Raudzens Bailey, A.

    2014-12-01

    Located at the summit of Mount Washington (1917 m asl; ~800 hPa), the highest peak in the northeastern United States, the Mount Washington Observatory has meticulously recorded hourly temperature, humidity, cloud-cover, and other atmospheric variables for over 80 years using the same standard procedures to ensure high-quality, homogeneous data. Nearby Hubbard Brook Experimental Forest (253 m asl; ~980 hPa), a Long-Term Ecological Research site, has recorded atmospheric and environmental data since 1956. Together, these two sites provide a unique opportunity to evaluate elevation-dependent climate changes. Using Sen's slope and the Mann Kendall non-parameteric test we examine annual and seasonal trends in minimum, maximum, and mean temperatures. Both Mount Washington and Hubbard Brook exhibit 56-yr warming trends for most seasons, however, the magnitudes and statistical significances are variable, suggesting the processes controlling these trends likely differ with elevation. Since 1957, for instance, spring maximum temperatures at Hubbard Brook have warmed 0.32 °C dec-1 and winter minimums have increased 0.54 °C dec-1, both well within the range reported for six neighboring low elevation stations from 1970-2012 (Wake et al, 2014a,b). In comparison, Mount Washington summit seasonal minimum temperature trends are typically weaker, with changes in winter minimums (the largest of the seasons) reaching only 0.33 °C dec-1. In this presentation, we highlight differences between these two long-term records and discuss possible role of moist processes and boundary layer/free troposphere exposure in causing their divergence. Authors are planning to study the effects of humidity and cloud-cover on summit temperatures and to investigate how changes in the frequency with which the summit is exposed to boundary layer and free tropospheric air masses influences these relationships.

  11. Quantum interference magnetoconductance of polycrystalline germanium films in the variable-range hopping regime

    NASA Astrophysics Data System (ADS)

    Li, Zhaoguo; Peng, Liping; Zhang, Jicheng; Li, Jia; Zeng, Yong; Zhan, Zhiqiang; Wu, Weidong

    2018-06-01

    Direct evidence of quantum interference magnetotransport in polycrystalline germanium films in the variable-range hopping (VRH) regime is reported. The temperature dependence of the conductivity of germanium films fulfilled the Mott VRH mechanism with the form of ? in the low-temperature regime (?). For the magnetotransport behaviour of our germanium films in the VRH regime, a crossover, from negative magnetoconductance at the low-field to positive magnetoconductance at the high-field, is observed while the zero-field conductivity is higher than the critical value (?). In the regime of ?, the magnetoconductance is positive and quadratic in the field for some germanium films. These features are in agreement with the VRH magnetotransport theory based on the quantum interference effect among random paths in the hopping process.

  12. New thermodynamics of entropy generation minimization with nonlinear thermal radiation and nanomaterials

    NASA Astrophysics Data System (ADS)

    Hayat, T.; Khan, M. Ijaz; Qayyum, Sumaira; Alsaedi, A.; Khan, M. Imran

    2018-03-01

    This research addressed entropy generation for MHD stagnation point flow of viscous nanofluid over a stretching surface. Characteristics of heat transport are analyzed through nonlinear radiation and heat generation/absorption. Nanoliquid features for Brownian moment and thermophoresis have been considered. Fluid in the presence of constant applied inclined magnetic field is considered. Flow problem is mathematically modeled and governing expressions are changed into nonlinear ordinary ones by utilizing appropriate transformations. The effects of pertinent variables on velocity, nanoparticle concentration and temperature are discussed graphically. Furthermore Brownian motion and thermophoresis effects on entropy generation and Bejan number have been examined. Total entropy generation is inspected through various flow variables. Consideration is mainly given to the convergence process. Velocity, temperature and mass gradients at the surface of sheet are calculated numerically.

  13. Probing Gas Adsorption in Zeolites by Variable-Temperature IR Spectroscopy: An Overview of Current Research.

    PubMed

    Garrone, Edoardo; Delgado, Montserrat R; Bonelli, Barbara; Arean, Carlos O

    2017-09-15

    The current state of the art in the application of variable-temperature IR (VTIR) spectroscopy to the study of (i) adsorption sites in zeolites, including dual cation sites; (ii) the structure of adsorption complexes and (iii) gas-solid interaction energy is reviewed. The main focus is placed on the potential use of zeolites for gas separation, purification and transport, but possible extension to the field of heterogeneous catalysis is also envisaged. A critical comparison with classical IR spectroscopy and adsorption calorimetry shows that the main merits of VTIR spectroscopy are (i) its ability to provide simultaneously the spectroscopic signature of the adsorption complex and the standard enthalpy change involved in the adsorption process; and (ii) the enhanced potential of VTIR to be site specific in favorable cases.

  14. Process-based quality for thermal spray via feedback control

    NASA Astrophysics Data System (ADS)

    Dykhuizen, R. C.; Neiser, R. A.

    2006-09-01

    Quality control of a thermal spray system manufacturing process is difficult due to the many input variables that need to be controlled. Great care must be taken to ensure that the process remains constant to obtain a consistent quality of the parts. Control is greatly complicated by the fact that measurement of particle velocities and temperatures is a noisy stochastic process. This article illustrates the application of quality control concepts to a wire flame spray process. A central feature of the real-time control system is an automatic feedback control scheme that provides fine adjustments to ensure that uncontrolled variations are accommodated. It is shown how the control vectors can be constructed from simple process maps to independently control particle velocity and temperature. This control scheme is shown to perform well in a real production environment. We also demonstrate that slight variations in the feed wire curvature can greatly influence the process. Finally, the geometry of the spray system and sensor must remain constant for the best reproducibility.

  15. Preparation and Physicochemical Properties of Vinblastine Microparticles by Supercritical Antisolvent Process

    PubMed Central

    Zhang, Xiaonan; Zhao, Xiuhua; Zu, Yuangang; Chen, Xiaoqiang; Lu, Qi; Ma, Yuliang; Yang, Lei

    2012-01-01

    The objective of the study was to prepare vinblastine microparticles by supercritical antisolvent process using N-methyl-2-pyrrolidone as solvent and carbon dioxide as antisolvent and evaluate its physicochemical properties. The effects of four process variables, pressure, temperature, drug concentration and drug solution flow rate, on drug particle formation during the supercritical antisolvent process, were investigated. Particles with a mean particle size of 121 ± 5.3 nm were obtained under the optimized process conditions (precipitation temperature 60 °C, precipitation pressure 25 MPa, vinblastine concentration 2.50 mg/mL and vinblastine solution flow rate 6.7 mL/min). The vinblastine was characterized by scanning electron microscopy, X-ray diffraction, Fourier-transform infrared spectroscopy, mass spectrometry and dissolution test. It was concluded that physicochemical properties of crystalline vinblastine could be improved by physical modification, such as particle size reduction and generation of amorphous state using the supercritical antisolvent process. Furthermore, the supercritical antisolvent process was a powerful methodology for improving the physicochemical properties of vinblastine. PMID:23202916

  16. Effect of process variables on the quality attributes of briquettes from wheat, oat, canola and barley

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jaya Shankar Tumuluru

    2011-08-01

    Effect of process variables on the quality attributes of briquettes from wheat, oat, canola and barley straw Jaya Shankar Tumuluru*, L. G. Tabil, Y. Song, K. L. Iroba and V. Meda Biomass is a renewable energy source and environmentally friendly substitute for fossil fuels such as coal and petroleum products. Major limitation of biomass for successful energy application is its low bulk density, which makes it very difficult and costly to transport and handle. To overcome this limitation, biomass has to be densified. The commonly used technologies for densification of biomass are pelletization and briquetting. Briquetting offers many advantages atmore » it can densify larger particles sizes of biomass at higher moisture contents. Briquetting is influenced by a number of feedstock and process variables such as moisture content, particle size distribution, and some operating variables such as temperature and densification pressure. In the present study, experiments were designed and conducted based on Box-Behnken design to produce briquettes using barley, wheat, canola and barley straws. A laboratory scale hydraulic briquette press was used for the present study. The experimental process variables and their levels used in the present study were pressure levels (7.5, 10, 12.5 MPa), three levels of temperature (90, 110, 130 C), at three moisture content levels (9, 12, 15% w.b.), and three levels of particle size (19.1, 25.04, 31.75 mm). The quality variables studied includes moisture content, initial density and final briquette density after two weeks of storage, size distribution index and durability. The raw biomass was initially chopped and size reduced using a hammer mill. The ground biomass was conditioned at different moisture contents and was further densified using laboratory hydraulic press. For each treatment combination, ten briquettes were manufactured at a residence time of about 30 s after compression pressure setpoint was achieved. After compression, the initial dimensions and the final dimensions after 2 weeks of storage in controlled environment of all the samples were measured. Durability, dimensional stability, and moisture content tests were conducted after two weeks of storage of the briquettes produced. Initial results indicated that moisture content played a significant role on briquettes durability, stability, and density. Low moisture content of the straws (7-12%) gave more durable briquettes. Briquette density increased with increasing pressure depending on the moisture content value. The axial expansion was more significant than the lateral expansion, which in some cases tended to be nil depending on the material and operating variables. Further data analysis is in progress in order to understand the significance of the process variables based on ANOVA. Regression models were developed to predict the changes in quality of briquettes with respect of the process variables under study. Keywords: Herbaceous biomass, densification, briquettes, density, durability, dimensional stability, ANOVA and regression equations« less

  17. Optimization of process variables by response surface methodology for malachite green dye removal using lime peel activated carbon

    NASA Astrophysics Data System (ADS)

    Ahmad, Mohd Azmier; Afandi, Nur Syahidah; Bello, Olugbenga Solomon

    2017-05-01

    This study investigates the adsorptive removal of malachite green (MG) dye from aqueous solutions using chemically modified lime-peel-based activated carbon (LPAC). The adsorbent prepared was characterized using FTIR, SEM, Proximate analysis and BET techniques, respectively. Central composite design (CCD) in response surface methodology (RSM) was used to optimize the adsorption process. The effects of three variables: activation temperature, activation time and chemical impregnation ratio (IR) using KOH and their effects on percentage of dye removal and LPAC yield were investigated. Based on CCD design, quadratic models and two factor interactions (2FI) were developed correlating the adsorption variables to the two responses. Analysis of variance (ANOVA) was used to judge the adequacy of the model. The optimum conditions of MG dye removal using LPAC are: activation temperature (796 °C), activation time (1.0 h) and impregnation ratio (2.6), respectively. The percentage of MG dye removal obtained was 94.68 % resulting in 17.88 % LPAC yield. The percentage of error between predicted and experimental results for the removal of MG dye is 0.4 %. Model prediction was in good agreement with experimental results and LPAC was found to be effective in removing MG dye from aqueous solution.

  18. Simulating and explaining passive air sampling rates for semi-volatile compounds on polyurethane foam passive samplers

    PubMed Central

    Petrich, Nicholas T.; Spak, Scott N.; Carmichael, Gregory R.; Hu, Dingfei; Martinez, Andres; Hornbuckle, Keri C.

    2013-01-01

    Passive air samplers (PAS) including polyurethane foam (PUF) are widely deployed as an inexpensive and practical way to sample semi-volatile pollutants. However, concentration estimates from PAS rely on constant empirical mass transfer rates, which add unquantified uncertainties to concentrations. Here we present a method for modeling hourly sampling rates for semi-volatile compounds from hourly meteorology using first-principle chemistry, physics, and fluid dynamics, calibrated from depuration experiments. This approach quantifies and explains observed effects of meteorology on variability in compound-specific sampling rates and analyte concentrations; simulates nonlinear PUF uptake; and recovers synthetic hourly concentrations at a reference temperature. Sampling rates are evaluated for polychlorinated biphenyl congeners at a network of Harner model samplers in Chicago, Illinois during 2008, finding simulated average sampling rates within analytical uncertainty of those determined from loss of depuration compounds, and confirming quasi-linear uptake. Results indicate hourly, daily and interannual variability in sampling rates, sensitivity to temporal resolution in meteorology, and predictable volatility-based relationships between congeners. We quantify importance of each simulated process to sampling rates and mass transfer and assess uncertainty contributed by advection, molecular diffusion, volatilization, and flow regime within the PAS, finding PAS chamber temperature contributes the greatest variability to total process uncertainty (7.3%). PMID:23837599

  19. Development of uniform and predictable battery materials for nickel-cadmium aerospace cells

    NASA Technical Reports Server (NTRS)

    1971-01-01

    Battery materials and manufacturing methods were analyzed with the aim of developing uniform and predictable battery plates for nickel cadmium aerospace cells. A study is presented for the high temperature electrochemical impregnation process for the preparation of nickel cadmium battery plates. This comparative study is set up as a factorially designed experiment to examine both manufacturing and operational variables and any interaction that might exist between them. The manufacturing variables in the factorial design include plaque preparative method, plaque porosity and thickness, impregnation method, and loading, The operational variables are type of duty cycle, charge and discharge rate, extent of overcharge, and depth of discharge.

  20. The Statistical Differences Between the Gridded Temperature Datasets, and its Implications for Stochastic Modelling

    NASA Astrophysics Data System (ADS)

    Fredriksen, H. B.; Løvsletten, O.; Rypdal, M.; Rypdal, K.

    2014-12-01

    Several research groups around the world collect instrumental temperature data and combine them in different ways to obtain global gridded temperature fields. The three most well known datasets are HadCRUT4 produced by the Climatic Research Unit and the Met Office Hadley Centre in UK, one produced by NASA GISS, and one produced by NOAA. Recently Berkeley Earth has also developed a gridded dataset. All these four will be compared in our analysis. The statistical properties we will focus on are the standard deviation and the Hurst exponent. These two parameters are sufficient to describe the temperatures as long-range memory stochastic processes; the standard deviation describes the general fluctuation level, while the Hurst exponent relates the strength of the long-term variability to the strength of the short-term variability. A higher Hurst exponent means that the slow variations are stronger compared to the fast, and that the autocovariance function will have a stronger tail. Hence the Hurst exponent gives us information about the persistence or memory of the process. We make use of these data to show that data averaged over a larger area exhibit higher Hurst exponents and lower variance than data averaged over a smaller area, which provides information about the relationship between temporal and spatial correlations of the temperature fluctuations. Interpolation in space has some similarities with averaging over space, although interpolation is more weighted towards the measurement locations. We demonstrate that the degree of spatial interpolation used can explain some differences observed between the variances and memory exponents computed from the various datasets.

  1. The theory, direction, and magnitude of ecosystem fire probability as constrained by precipitation and temperature.

    PubMed

    Guyette, Richard; Stambaugh, Michael C; Dey, Daniel; Muzika, Rose Marie

    2017-01-01

    The effects of climate on wildland fire confronts society across a range of different ecosystems. Water and temperature affect the combustion dynamics, irrespective of whether those are associated with carbon fueled motors or ecosystems, but through different chemical, physical, and biological processes. We use an ecosystem combustion equation developed with the physical chemistry of atmospheric variables to estimate and simulate fire probability and mean fire interval (MFI). The calibration of ecosystem fire probability with basic combustion chemistry and physics offers a quantitative method to address wildland fire in addition to the well-studied forcing factors such as topography, ignition, and vegetation. We develop a graphic analysis tool for estimating climate forced fire probability with temperature and precipitation based on an empirical assessment of combustion theory and fire prediction in ecosystems. Climate-affected fire probability for any period, past or future, is estimated with given temperature and precipitation. A graphic analyses of wildland fire dynamics driven by climate supports a dialectic in hydrologic processes that affect ecosystem combustion: 1) the water needed by plants to produce carbon bonds (fuel) and 2) the inhibition of successful reactant collisions by water molecules (humidity and fuel moisture). These two postulates enable a classification scheme for ecosystems into three or more climate categories using their position relative to change points defined by precipitation in combustion dynamics equations. Three classifications of combustion dynamics in ecosystems fire probability include: 1) precipitation insensitive, 2) precipitation unstable, and 3) precipitation sensitive. All three classifications interact in different ways with variable levels of temperature.

  2. Investigating the Impacts of Surface Temperature Anomalies due to Burned Area Albedo in Northern sub-Saharan Africa

    NASA Astrophysics Data System (ADS)

    Gabbert, T.; Matsui, T.; Capehart, W. J.; Ichoku, C. M.; Gatebe, C. K.

    2015-12-01

    The northern Sub-Saharan African region (NSSA) is an area of intense focus due to periodic severe droughts that have dire consequences on the growing population, which relies mostly on rain fed agriculture for its food supply. This region's weather and hydrologic cycle are very complex and are dependent on the West African Monsoon. Different regional processes affect the West African Monsoon cycle and variability. One of the areas of current investigation is the water cycle response to the variability of land surface characteristics. Land surface characteristics are often altered in NSSA due to agricultural practices, grazing, and the fires that occur during the dry season. To better understand the effects of biomass burning on the hydrologic cycle of the sub-Saharan environment, an interdisciplinary team sponsored by NASA is analyzing potential feedback mechanisms due to the fires. As part of this research, this study focuses on the effects of land surface changes, particularly albedo and skin temperature, that are influenced by biomass burning. Surface temperature anomalies can influence the initiation of convective rainfall and surface albedo is linked to the absorption of solar radiation. To capture the effects of fire perturbations on the land surface, NASA's Unified Weather and Research Forecasting (NU-WRF) model coupled with NASA's Land Information System (LIS) is being used to simulate burned area surface albedo inducing surface temperature anomalies and other potential effects to environmental processes. Preliminary sensitivity results suggest an altered surface radiation budget, regional warming of the surface temperature, slight increase in average rainfall, and a change in precipitation locations.

  3. The theory, direction, and magnitude of ecosystem fire probability as constrained by precipitation and temperature

    PubMed Central

    Guyette, Richard; Stambaugh, Michael C.; Dey, Daniel

    2017-01-01

    The effects of climate on wildland fire confronts society across a range of different ecosystems. Water and temperature affect the combustion dynamics, irrespective of whether those are associated with carbon fueled motors or ecosystems, but through different chemical, physical, and biological processes. We use an ecosystem combustion equation developed with the physical chemistry of atmospheric variables to estimate and simulate fire probability and mean fire interval (MFI). The calibration of ecosystem fire probability with basic combustion chemistry and physics offers a quantitative method to address wildland fire in addition to the well-studied forcing factors such as topography, ignition, and vegetation. We develop a graphic analysis tool for estimating climate forced fire probability with temperature and precipitation based on an empirical assessment of combustion theory and fire prediction in ecosystems. Climate-affected fire probability for any period, past or future, is estimated with given temperature and precipitation. A graphic analyses of wildland fire dynamics driven by climate supports a dialectic in hydrologic processes that affect ecosystem combustion: 1) the water needed by plants to produce carbon bonds (fuel) and 2) the inhibition of successful reactant collisions by water molecules (humidity and fuel moisture). These two postulates enable a classification scheme for ecosystems into three or more climate categories using their position relative to change points defined by precipitation in combustion dynamics equations. Three classifications of combustion dynamics in ecosystems fire probability include: 1) precipitation insensitive, 2) precipitation unstable, and 3) precipitation sensitive. All three classifications interact in different ways with variable levels of temperature. PMID:28704457

  4. Optimization of mucilage extraction from chia seeds (Salvia hispanica L.) using response surface methodology.

    PubMed

    Orifici, Stefania C; Capitani, Marianela I; Tomás, Mabel C; Nolasco, Susana M

    2018-02-25

    Chia mucilage has potential application as a functional ingredient; advances on maximizing its extraction yield could represent a significant technological and economic impact for the food industry. Thus, first, the effect of mechanical agitation time (1-3 h) on the exudation of chia mucilage was analyzed. Then, response surface methodology was used to determine the optimal combination of the independent variables temperature (15-85 °C) and seed: water ratio (1: 12-1: 40.8 w/v) for the 2 h exudation that give maximum chia mucilage yield. Experiments were designed according to central composite rotatable design. A second-order polynomial model predicted the variation in extraction mucilage yield with the variables temperature and seed: water ratio. The optimal operating conditions were found to be temperature 85 °C and a seed: water ratio of 1: 31 (w/v), reaching an experimental extraction yield of 116 ± 0.21 g kg -1 (dry basis). The mucilage obtained exhibited good functional properties, mainly in terms of water-holding capacity, emulsifying activity, and emulsion stability. The results obtained show that temperature, seed: water ratio, and exudation time are important variables of the process that affect the extraction yield and the quality of the chia mucilage, determined according to its physicochemical and functional properties. © 2018 Society of Chemical Industry. © 2018 Society of Chemical Industry.

  5. Age of oil palm plantations causes a strong change in surface biophysical variables

    NASA Astrophysics Data System (ADS)

    Sabajo, Clifton; le Maire, Guerric; Knohl, Alexander

    2016-04-01

    Over the last decades, Indonesia has experienced dramatic land transformations with an expansion of oil palm plantations at the expense of tropical forests. As vegetation is a modifier of the climate near the ground these large-scale land transformations are expected to have major impacts on the surface biophysical variables i.e. surface temperature, albedo, and vegetation indices, e.g. the NDVI. Remote sensing data are needed to assess such changes at regional scale. We used 2 Landsat images from Jambi Province in Sumatra/Indonesia covering a chronosequence of oil palm plantations to study the 20 - 25 years life cycle of oil palm plantations and its relation with biophysical variables. Our results show large differences between the surface temperature of young oil palm plantations and forest (up to 9.5 ± 1.5 °C) indicating that the surface temperature is raised substantially after the establishment of oil palm plantations following the removal of forests. During the oil palm plantation lifecycle the surface temperature differences gradually decreases and approaches zero around an oil palm plantation age of 10 years. Similarly, NDVI increases and the albedo decreases approaching typical values of forests. Our results show that in order to assess the full climate effects of oil palm expansion biophysical processes play an important role and the full life cycle of oil palm plantations need to be considered.

  6. Zn/Cd ratios and cadmium isotope evidence for the classification of lead-zinc deposits

    PubMed Central

    Wen, Hanjie; Zhu, Chuanwei; Zhang, Yuxu; Cloquet, Christophe; Fan, Haifeng; Fu, Shaohong

    2016-01-01

    Lead-zinc deposits are often difficult to classify because clear criteria are lacking. In recent years, new tools, such as Cd and Zn isotopes, have been used to better understand the ore-formation processes and to classify Pb-Zn deposits. Herein, we investigate Cd concentrations, Cd isotope systematics and Zn/Cd ratios in sphalerite from nine Pb-Zn deposits divided into high-temperature systems (e.g., porphyry), low-temperature systems (e.g., Mississippi Valley type [MVT]) and exhalative systems (e.g., sedimentary exhalative [SEDEX]). Our results showed little evidence of fractionation in the high-temperature systems. In the low-temperature systems, Cd concentrations were the highest, but were also highly variable, a result consistent with the higher fractionation of Cd at low temperatures. The δ114/110Cd values in low-temperature systems were enriched in heavier isotopes (mean of 0.32 ± 0.31‰). Exhalative systems had the lowest Cd concentrations, with a mean δ114/110Cd value of 0.12 ± 0.50‰. We thus conclude that different ore-formation systems result in different characteristic Cd concentrations and fraction levels and that low-temperature processes lead to the most significant fractionation of Cd. Therefore, Cd distribution and isotopic studies can support better understanding of the geochemistry of ore-formation processes and the classification of Pb-Zn deposits. PMID:27121538

  7. Isolation and characterization of hydrophobic compounds from carbohydrate matrix of Pistacia atlantica.

    PubMed

    Samavati, Vahid; Adeli, Mostafa

    2014-01-30

    The present work is focused on the optimization of hydrophobic compounds extraction process from the carbohydrate matrix of Iranian Pistacia atlantica seed at laboratory level using ultrasonic-assisted extraction. Response surface methodology (RSM) was used to optimize oil seed extraction yield. Independent variables were extraction temperature (30, 45, 60, 75 and 90°C), extraction time (10, 15, 20, 25, 30 and 35 min) and power of ultrasonic (20, 40, 60, 80 and 100 W). A second order polynomial equation was used to express the oil extraction yield as a function of independent variables. The responses and variables were fitted well to each other by multiple regressions. The optimum extraction conditions were as follows: extraction temperature of 75°C, extraction time of 25 min, and power of ultrasonic of 80 W. A comparison between seed oil composition extracted by ultrasonic waves under the optimum operating conditions determined by RSM for oil yield and by organic solvent was reported. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. Cross-scale impact of climate temporal variability on ecosystem water and carbon fluxes

    DOE PAGES

    Paschalis, Athanasios; Fatichi, Simone; Katul, Gabriel G.; ...

    2015-08-07

    While the importance of ecosystem functioning is undisputed in the context of climate change and Earth system modeling, the role of short-scale temporal variability of hydrometeorological forcing (~1 h) on the related ecosystem processes remains to be fully understood. Additionally, various impacts of meteorological forcing variability on water and carbon fluxes across a range of scales are explored here using numerical simulations. Synthetic meteorological drivers that highlight dynamic features of the short temporal scale in series of precipitation, temperature, and radiation are constructed. These drivers force a mechanistic ecohydrological model that propagates information content into the dynamics of water andmore » carbon fluxes for an ensemble of representative ecosystems. The focus of the analysis is on a cross-scale effect of the short-scale forcing variability on the modeled evapotranspiration and ecosystem carbon assimilation. Interannual variability of water and carbon fluxes is emphasized in the analysis. The main study inferences are summarized as follows: (a) short-scale variability of meteorological input does affect water and carbon fluxes across a wide range of time scales, spanning from the hourly to the annual and longer scales; (b) different ecosystems respond to the various characteristics of the short-scale variability of the climate forcing in various ways, depending on dominant factors limiting system productivity; (c) whenever short-scale variability of meteorological forcing influences primarily fast processes such as photosynthesis, its impact on the slow-scale variability of water and carbon fluxes is small; and (d) whenever short-scale variability of the meteorological forcing impacts slow processes such as movement and storage of water in the soil, the effects of the variability can propagate to annual and longer time scales.« less

  9. Cross-scale impact of climate temporal variability on ecosystem water and carbon fluxes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Paschalis, Athanasios; Fatichi, Simone; Katul, Gabriel G.

    While the importance of ecosystem functioning is undisputed in the context of climate change and Earth system modeling, the role of short-scale temporal variability of hydrometeorological forcing (~1 h) on the related ecosystem processes remains to be fully understood. Additionally, various impacts of meteorological forcing variability on water and carbon fluxes across a range of scales are explored here using numerical simulations. Synthetic meteorological drivers that highlight dynamic features of the short temporal scale in series of precipitation, temperature, and radiation are constructed. These drivers force a mechanistic ecohydrological model that propagates information content into the dynamics of water andmore » carbon fluxes for an ensemble of representative ecosystems. The focus of the analysis is on a cross-scale effect of the short-scale forcing variability on the modeled evapotranspiration and ecosystem carbon assimilation. Interannual variability of water and carbon fluxes is emphasized in the analysis. The main study inferences are summarized as follows: (a) short-scale variability of meteorological input does affect water and carbon fluxes across a wide range of time scales, spanning from the hourly to the annual and longer scales; (b) different ecosystems respond to the various characteristics of the short-scale variability of the climate forcing in various ways, depending on dominant factors limiting system productivity; (c) whenever short-scale variability of meteorological forcing influences primarily fast processes such as photosynthesis, its impact on the slow-scale variability of water and carbon fluxes is small; and (d) whenever short-scale variability of the meteorological forcing impacts slow processes such as movement and storage of water in the soil, the effects of the variability can propagate to annual and longer time scales.« less

  10. An inter-decadal increase in summer sea level pressure over the Mongolian region around the early 1990s

    NASA Astrophysics Data System (ADS)

    Zhang, Haiyan; Wen, Zhiping; Wu, Renguang; Li, Xiuzhen; Chen, Ruidan

    2018-05-01

    The East Asian summer monsoon is affected by processes in the mid-high latitudes in addition to various tropical and subtropical systems. The present study investigates the summer sea level pressure (SLP) variability over northern East Asia (NEA) and emphasizes the closed active center over the Mongolian region. It is found that the seasonal mean Mongolian SLP (MSLP) anomaly is closely connected with the variability of summertime regional synoptic extra-tropical cyclones on longer time scales. A significant inter-decadal increase in the MSLP around the early 1990s has been detected, which is accompanied by a weakening in the activity of regional extra-tropical cyclones. Recent warming over NEA may have a contribution to the inter-decadal change, which features evidently meridional inhomogeneity around 45°N. The inhomogeneous air temperature anomaly distribution results in decreased vertical wind shear, reduced atmospheric baroclinicity over the Mongolian region, and thus inactive regional cyclones and increased MSLP in the latter decade. The associated temperature anomaly distribution may be partly attributed to regional inhomogeneity in cloud and radiation anomalies, and it is further maintained by two positive feedback mechanisms associated with atmospheric internal processes: one via adiabatic heating and the other via horizontal temperature advection.

  11. Comparison of polynomial and neural fuzzy models as applied to the ethanolamine pulping of vine shoots.

    PubMed

    Jiménez, L; Angulo, V; Caparrós, S; Ariza, J

    2007-12-01

    The influence of operational variables in the pulping of vine shoots by use of ethanolamine [viz. temperature (155-185 degrees C), cooking time (30-90min) and ethanolamine concentration (50-70% v/v)] on the properties of the resulting pulp (viz. yield, kappa index, viscosity and drainability) was studied. A central composite factorial design was used in conjunction with the software BMDP and ANFIS Edit Matlab 6.5 to develop polynomial and fuzzy neural models that reproduced the experimental results of the dependent variables with errors less than 10%. Both types of models are therefore effective with a view to simulating the ethanolamine pulping process. Based on the proposed equations, the best choice is to use values of the operational valuables resulting in near-optimal pulp properties while saving energy and immobilized capital on industrial facilities by using lower temperatures and shorter processing times. One combination leading to near-optimal properties with reduced costs is using a temperature of 180 degrees C and an ethanolamine concentration of 60% for 60min, to obtain pulp with a viscosity of 6.13% lower than the maximum value (932.8ml/g) and a drainability of 5.49% lower than the maximum value (71 (o)SR).

  12. Selection of process conditions by risk assessment for apple juice pasteurization by UV-heat treatments at moderate temperatures.

    PubMed

    Gayán, E; Torres, J A; Alvarez, I; Condón, S

    2014-02-01

    The effect of bactericidal UV-C treatments (254 nm) on Escherichia coli O157:H7 suspended in apple juice increased synergistically with temperature up to a threshold value. The optimum UV-C treatment temperature was 55 °C, yielding a 58.9% synergistic lethal effect. Under these treatment conditions, the UV-heat (UV-H55 °C) lethal variability achieving 5-log reductions had a logistic distribution (α = 37.92, β = 1.10). Using this distribution, UV-H55 °C doses to achieve the required juice safety goal with 95, 99, and 99.9% confidence were 41.17, 42.97, and 46.00 J/ml, respectively, i.e., doses higher than the 37.58 J/ml estimated by a deterministic procedure. The public health impact of these results is that the larger UV-H55 °C dose required for achieving 5-log reductions with 95, 99, and 99.9% confidence would reduce the probability of hemolytic uremic syndrome in children by 76.3, 88.6, and 96.9%, respectively. This study illustrates the importance of including the effect of data variability when selecting operational parameters for novel and conventional preservation processes to achieve high food safety standards with the desired confidence level.

  13. Seasonal changes in the body size of two rotifer species living in activated sludge follow the Temperature-Size Rule.

    PubMed

    Kiełbasa, Anna; Walczyńska, Aleksandra; Fiałkowska, Edyta; Pajdak-Stós, Agnieszka; Kozłowski, Jan

    2014-12-01

    Temperature-Size Rule (TSR) is a phenotypic body size response of ectotherms to changing temperature. It is known from the laboratory studies, but seasonal patterns in the field were not studied so far. We examined the body size changes in time of rotifers inhabiting activated sludge. We hypothesize that temperature is the most influencing parameter in sludge environment, leading sludge rotifers to seasonally change their body size according to TSR, and that oxygen content also induces the size response. The presence of TSR in Lecane inermis rotifer was tested in a laboratory study with two temperature and two food-type treatments. The effect of interaction between temperature and food was significant; L. inermis followed TSR in one food type only. The seasonal variability in the body sizes of the rotifers L. inermis and Cephalodella gracilis was estimated by monthly sampling and analyzed by multiple regression, in relation to the sludge parameters selected as the most influential by multivariate analysis, and predicted to alter rotifer body size (temperature and oxygen). L. inermis varied significantly in size throughout the year, and this variability is explained by temperature as predicted by the TSR, but not by oxygen availability. C. gracilis also varied in size, though this variability was explained by both temperature and oxygen. We suggest that sludge age acts as a mortality factor in activated sludge. It may have a seasonal effect on the body size of L. inermis and modify a possible effect of oxygen. Activated sludge habitat is driven by both biological processes and human regulation, yet its resident organisms follow general evolutionary rule as they do in other biological systems. The interspecific response patterns differ, revealing the importance of taking species-specific properties into account. Our findings are applicable to sludge properties enhancement through optimizing the conditions for its biological component.

  14. Interannual variability of the atmospheric CO2 growth rate: roles of precipitation and temperature

    NASA Astrophysics Data System (ADS)

    Wang, Jun; Zeng, Ning; Wang, Meirong

    2016-04-01

    The interannual variability (IAV) in atmospheric CO2 growth rate (CGR) is closely connected with the El Niño-Southern Oscillation. However, sensitivities of CGR to temperature and precipitation remain largely uncertain. This paper analyzed the relationship between Mauna Loa CGR and tropical land climatic elements. We find that Mauna Loa CGR lags precipitation by 4 months with a correlation coefficient of -0.63, leads temperature by 1 month (0.77), and correlates with soil moisture (-0.65) with zero lag. Additionally, precipitation and temperature are highly correlated (-0.66), with precipitation leading by 4-5 months. Regression analysis shows that sensitivities of Mauna Loa CGR to temperature and precipitation are 2.92 ± 0.20 PgC yr-1 K-1 and -0.46 ± 0.07 PgC yr-1 100 mm-1, respectively. Unlike some recent suggestions, these empirical relationships favor neither temperature nor precipitation as the dominant factor of CGR IAV. We further analyzed seven terrestrial carbon cycle models, from the TRENDY project, to study the processes underlying CGR IAV. All models capture well the IAV of tropical land-atmosphere carbon flux (CFTA). Sensitivities of the ensemble mean CFTA to temperature and precipitation are 3.18 ± 0.11 PgC yr-1 K-1 and -0.67 ± 0.04 PgC yr-1 100 mm-1, close to Mauna Loa CGR. Importantly, the models consistently show the variability in net primary productivity (NPP) dominates CGR, rather than heterotrophic respiration. Because previous studies have proved that NPP is largely driven by precipitation in tropics, it suggests a key role of precipitation in CGR IAV despite the higher CGR correlation with temperature. Understanding the relative contribution of CO2 sensitivity to precipitation and temperature has important implications for future carbon-climate feedback using such ''emergent constraint''.

  15. An analysis of the impact of pre-analytical factors on the urine proteome: Sample processing time, temperature, and proteolysis.

    PubMed

    Hepburn, Sophie; Cairns, David A; Jackson, David; Craven, Rachel A; Riley, Beverley; Hutchinson, Michelle; Wood, Steven; Smith, Matthew Welberry; Thompson, Douglas; Banks, Rosamonde E

    2015-06-01

    We have examined the impact of sample processing time delay, temperature, and the addition of protease inhibitors (PIs) on the urinary proteome and peptidome, an important aspect of biomarker studies. Ten urine samples from patients with varying pathologies were each divided and PIs added to one-half, with aliquots of each then processed and frozen immediately, or after a delay of 6 h at 4°C or room temperature (20-22°C), effectively yielding 60 samples in total. Samples were then analyzed by 2D-PAGE, SELDI-TOF-MS, and immunoassay. Interindividual variability in profiles was the dominant feature in all analyses. Minimal changes were observed by 2D-PAGE as a result of delay in processing, temperature, or PIs and no changes were seen in IgG, albumin, β2 -microglobulin, or α1 -microglobulin measured by immunoassay. Analysis of peptides showed clustering of some samples by presence/absence of PIs but the extent was very patient-dependent with most samples showing minimal effects. The extent of processing-induced changes and the benefit of PI addition are patient- and sample-dependent. A consistent processing methodology is essential within a study to avoid any confounding of the results. © 2014 The Authors PROTEOMICS Clinical Applications Published by Wiley-VCH Verlag GmbH & Co. KGaA.

  16. The role of environmental variables on Aedes albopictus biology and chikungunya epidemiology

    PubMed Central

    Waldock, Joanna; Chandra, Nastassya L; Lelieveld, Jos; Proestos, Yiannis; Michael, Edwin; Christophides, George; Parham, Paul E

    2013-01-01

    Aedes albopictus is a vector of dengue and chikungunya viruses in the field, along with around 24 additional arboviruses under laboratory conditions. As an invasive mosquito species, Ae. albopictus has been expanding in geographical range over the past 20 years, although the poleward extent of mosquito populations is limited by winter temperatures. Nonetheless, population densities depend on environmental conditions and since global climate change projections indicate increasing temperatures and altered patterns of rainfall, geographic distributions of previously tropical mosquito species may change. Although mathematical models can provide explanatory insight into observed patterns of disease prevalence in terms of epidemiological and entomological processes, understanding how environmental variables affect transmission is possible only with reliable model parameterisation, which, in turn, is obtained only through a thorough understanding of the relationship between mosquito biology and environmental variables. Thus, in order to assess the impact of climate change on mosquito population distribution and regions threatened by vector-borne disease, a detailed understanding (through a synthesis of current knowledge) of the relationship between climate, mosquito biology, and disease transmission is required, but this process has not yet been undertaken for Ae. albopictus. In this review, the impact of temperature, rainfall, and relative humidity on Ae. albopictus development and survival are considered. Existing Ae. albopictus populations across Europe are mapped with current climatic conditions, considering whether estimates of climatic cutoffs for Ae. albopictus are accurate, and suggesting that environmental thresholds must be calibrated according to the scale and resolution of climate model outputs and mosquito presence data. PMID:23916332

  17. [Bioacoustic of the advertisement call of Ceratophrys cranwelli (Anura: Ceratophryidae)].

    PubMed

    Valetti, Julián Alonso; Salas, Nancy Edith; Martino, Adolfo Ludovico

    2013-03-01

    The advertisement call plays an important role in the life history of anuran amphibians, mainly during the breeding season. Call features represent an important character to discriminate species, and sound emissions are very effective to assure or reinforce genetic incompatibility, especially in the case of sibling species. Since frogs are ectotherms, acoustic properties of their calls will vary with temperature. In this study, we described the advertisement call of C. cranwelli, quantifying the temperature effect on its components. The acoustic emissions were recorded during 2007 using a DAT record Sony TCD-100 with stereo microphone ECM-MS907 Sony and tape TDK DAT-RGX 60. As males emit their calls floating in temporary ponds, water temperatures were registered after recording the advertisement calls with a digital thermometer TES 1300+/-0.1 degreeC. Altogether, 54 calls from 18 males were analyzed. The temporal variables of each advertisement call were measured using oscillograms and sonograms and the analyses of dominant frequency were performed using a spectrogram. Multiple correlation analysis was used to identify the temperature-dependent acoustic variables and the temperature effect on these variables was quantified using linear regression models. The advertisement call of C. cranwelli consists of a single pulse group. Call duration, Pulse duration and Pulse interval decreased with the temperature, whereas the Pulse rate increased with temperature. The temperature-dependent variables were standardized at 25 degreeC according to the linear regression model obtained. The acoustic variables that were correlated with the temperature are the variables which emissions depend on laryngeal muscles and the temperature constraints the contractile properties of muscles. Our results indicated that temperature explains an important fraction of the variability in some acoustic variables (79% in the Pulse rate), and demonstrated the importance of considering the effect of temperature in acoustic components. The results suggest that acoustic variables show geographic variation to compare data with previous works.

  18. Multivariate statistical analysis of a high rate biofilm process treating kraft mill bleach plant effluent.

    PubMed

    Goode, C; LeRoy, J; Allen, D G

    2007-01-01

    This study reports on a multivariate analysis of the moving bed biofilm reactor (MBBR) wastewater treatment system at a Canadian pulp mill. The modelling approach involved a data overview by principal component analysis (PCA) followed by partial least squares (PLS) modelling with the objective of explaining and predicting changes in the BOD output of the reactor. Over two years of data with 87 process measurements were used to build the models. Variables were collected from the MBBR control scheme as well as upstream in the bleach plant and in digestion. To account for process dynamics, a variable lagging approach was used for variables with significant temporal correlations. It was found that wood type pulped at the mill was a significant variable governing reactor performance. Other important variables included flow parameters, faults in the temperature or pH control of the reactor, and some potential indirect indicators of biomass activity (residual nitrogen and pH out). The most predictive model was found to have an RMSEP value of 606 kgBOD/d, representing a 14.5% average error. This was a good fit, given the measurement error of the BOD test. Overall, the statistical approach was effective in describing and predicting MBBR treatment performance.

  19. Psychophysics of a Nociceptive Test in the Mouse: Ambient Temperature as a Key Factor for Variation

    PubMed Central

    Pincedé, Ivanne; Pollin, Bernard; Meert, Theo; Plaghki, Léon; Le Bars, Daniel

    2012-01-01

    Background The mouse is increasingly used in biomedical research, notably in behavioral neurosciences for the development of tests or models of pain. Our goal was to provide the scientific community with an outstanding tool that allows the determination of psychophysical descriptors of a nociceptive reaction, which are inaccessible with conventional methods: namely the true threshold, true latency, conduction velocity of the peripheral fibers that trigger the response and latency of the central decision-making process. Methodology/Principal Findings Basically, the procedures involved heating of the tail with a CO2 laser, recording of tail temperature with an infrared camera and stopping the heating when the animal reacted. The method is based mainly on the measurement of three observable variables, namely the initial temperature, the heating rate and the temperature reached at the actual moment of the reaction following random variations in noxious radiant heat. The initial temperature of the tail, which itself depends on the ambient temperature, very markedly influenced the behavioral threshold, the behavioral latency and the conduction velocity of the peripheral fibers but not the latency of the central decision-making. Conclusions/Significance We have validated a psychophysical approach to nociceptive reactions for the mouse, which has already been described for rats and Humans. It enables the determination of four variables, which contribute to the overall latency of the response. The usefulness of such an approach was demonstrated by providing new fundamental findings regarding the influence of ambient temperature on nociceptive processes. We conclude by challenging the validity of using as “pain index" the reaction time of a behavioral response to an increasing heat stimulus and emphasize the need for a very careful control of the ambient temperature, as a prevailing environmental source of variation, during any behavioral testing of mice. PMID:22629325

  20. Evaluation of the effect of physical variables on in vitro release of diclofenac pellets using Box-Behnken design

    PubMed Central

    Enayatifard, Reza; Mahjoob, Aiding; Ebrahimi, Pouneh; Ebrahimnejad, Pedram

    2015-01-01

    Objective(s): A Box-Behnken design was used for evaluation of Eudragit coated diclofenac pellets. The purpose of this work was to optimize diclofenac pellets to improve the physicochemical properties using experimental design. Materials and Methods: Diclofenac was loaded onto the non-pareil beads using conventional coating pan. Film coating of pellets was done at the same pan. The effect of plasticizer level, curing temperature and curing time was determined on the release of diclofenac from pellets coated with polymethacrylates. Results: Increasing the plasticizer in the coating formula led to decrease in drug release and increasing the curing temperature and time resulted in higher drug release. The optimization process generated an optimum of 35% drug release at 3 hr. The level of plasticizer concentration, curing temperature and time were 20% w/w, 55 °C and 24 hr, respectively. Conclusion: This study showed that by controllinig the physical variables optimum drug release were obtained. PMID:26351563

  1. Climate change hampers endangered species through intensified moisture-related plant stresses

    NASA Astrophysics Data System (ADS)

    (Ruud) Bartholomeus, R. P.; (Flip) Witte, J. P. M.; (Peter) van Bodegom, P. M.; (Jos) van Dam, J. C.; (Rien) Aerts, R.

    2010-05-01

    With recent climate change, extremes in meteorological conditions are forecast and observed to increase globally, and to affect vegetation composition. More prolonged dry periods will alternate with more intensive rainfall events, both within and between years, which will change soil moisture dynamics. In temperate climates, soil moisture, in concert with nutrient availability and soil acidity, is the most important environmental filter in determining local plant species composition, as it determines the availability of both oxygen and water to plant roots. These resources are indispensable for meeting the physiological demands of plants. The consequences of climate change for our natural environment are among the most pressing issues of our time. The international research community is beginning to realise that climate extremes may be more powerful drivers of vegetation change and species extinctions than slow-and-steady climatic changes, but the causal mechanisms of such changes are presently unknown. The roles of amplitudes in water availability as drivers of vegetation change have been particularly elusive owing to the lack of integration of the key variables involved. Here we show that the combined effect of increased rainfall variability, temperature and atmospheric CO2-concentration will lead to an increased variability in both wet and dry extremes in stresses faced by plants (oxygen and water stress, respectively). We simulated these plant stresses with a novel, process-based approach, incorporating in detail the interacting processes in the soil-plant-atmosphere interface. In order to quantify oxygen and water stress with causal measures, we focused on interacting meteorological, soil physical, microbial, and plant physiological processes in the soil-plant-atmosphere system. The first physiological process inhibited at high soil moisture contents is plant root respiration, i.e. oxygen consumption in the roots, which responds to increased temperatures. High soil moisture contents hamper oxygen transport from the atmosphere, through the soil - where part of the oxygen additionally disappears by soil microbial oxygen consumption - and to the root cells. Reduced respiration negatively affects the energy supply to plant metabolism. Plant transpiration, which responds to increased temperatures and atmospheric CO2-concentrations, is the first physiological process that will be inhibited by low soil moisture contents, negatively affecting both photosynthesis and cooling. As both the supply and demand of oxygen and water depend strongly on the prevailing meteorological conditions, both oxygen and water stress were calculated dynamically in time to capture climate change effects. We demonstrate that increased rainfall variability in interaction with predicted changes in temperature and CO2, affects soil moisture conditions and plant oxygen and water demands such, that both oxygen stress and water stress will intensify due to climate change. Moreover, these stresses will increasingly coincide, causing variable stress conditions. These variable stress conditions were found to decrease future habitat suitability, especially for plant species that are presently endangered. The future existence of such species is thus at risk by climate change, which has direct implications for policies to maintain endangered species, as applied by international nature management organisations (e.g. IUCN). Our integrated mechanistic analysis of two stresses combined, which has never been done so far, reveals large impacts of climate change on species extinctions and thereby on biodiversity.

  2. Pan-Arctic patterns of planktonic heterotrophic microbial abundance and processes: Controlling factors and potential impacts of warming

    NASA Astrophysics Data System (ADS)

    Maranger, Roxane; Vaqué, Dolors; Nguyen, Dan; Hébert, Marie-Pier; Lara, Elena

    2015-12-01

    The Arctic Ocean is rapidly changing where increasing water temperatures and rapid loss of summer sea-ice will likely influence the structure and functioning of the entire ecosystem. The aim of this study was to synthesize the current state of knowledge on microbial abundances and processes from a regional Pan-Arctic perspective, characterize regulating factors and attempt to predict how patterns may change under a warming scenario. Here we identify some generalized patterns of different microbial variables between the Pacific-fed and the Atlantic-fed sectors of the Arctic Ocean. Bacterial production (BP), abundance and grazing rates by protists (GT) were all higher in the Atlantic-fed region. Bacterial loss by viral lyses (VL) was proportionally more important in the Pacific-fed sector, suggesting a reduced C transfer efficiency within the microbial loop of that region. Using a cross-comparative approach and all available data to build Arrhenius plots, we found a differential response to warming temperatures among various microbial processes. BP and GT responded similarly and more strongly to increases in temperature than VL did, suggesting a shift in the overall influence of viral mortality under a warming scenario. However, together with temperature, resource-related factors also exerted an influence in regulating these rates. We identified large information gaps for more classically studied microbial variable from several Arctic seas. Furthermore, there is limited information on less conventional pathways such as grazing by mixotrophic species, which may be playing a significant role in Arctic microbial trophodynamics. Although generalized patterns could be elucidated, more information is needed to predict and understand how a changing Arctic will alter microbial C pathways and major biogeochemical cycles on regional and seasonal scales.

  3. An 'Observational Large Ensemble' to compare observed and modeled temperature trend uncertainty due to internal variability.

    NASA Astrophysics Data System (ADS)

    Poppick, A. N.; McKinnon, K. A.; Dunn-Sigouin, E.; Deser, C.

    2017-12-01

    Initial condition climate model ensembles suggest that regional temperature trends can be highly variable on decadal timescales due to characteristics of internal climate variability. Accounting for trend uncertainty due to internal variability is therefore necessary to contextualize recent observed temperature changes. However, while the variability of trends in a climate model ensemble can be evaluated directly (as the spread across ensemble members), internal variability simulated by a climate model may be inconsistent with observations. Observation-based methods for assessing the role of internal variability on trend uncertainty are therefore required. Here, we use a statistical resampling approach to assess trend uncertainty due to internal variability in historical 50-year (1966-2015) winter near-surface air temperature trends over North America. We compare this estimate of trend uncertainty to simulated trend variability in the NCAR CESM1 Large Ensemble (LENS), finding that uncertainty in wintertime temperature trends over North America due to internal variability is largely overestimated by CESM1, on average by a factor of 32%. Our observation-based resampling approach is combined with the forced signal from LENS to produce an 'Observational Large Ensemble' (OLENS). The members of OLENS indicate a range of spatially coherent fields of temperature trends resulting from different sequences of internal variability consistent with observations. The smaller trend variability in OLENS suggests that uncertainty in the historical climate change signal in observations due to internal variability is less than suggested by LENS.

  4. Climate and weather influences on spatial temporal patterns of mountain pine beetle populations in Washington and Oregon.

    PubMed

    Preisler, Haiganoush K; Hicke, Jeffrey A; Ager, Alan A; Hayes, Jane L

    2012-11-01

    Widespread outbreaks of mountain pine beetle in North America have drawn the attention of scientists, forest managers, and the public. There is strong evidence that climate change has contributed to the extent and severity of recent outbreaks. Scientists are interested in quantifying relationships between bark beetle population dynamics and trends in climate. Process models that simulate climate suitability for mountain pine beetle outbreaks have advanced our understanding of beetle population dynamics; however, there are few studies that have assessed their accuracy across multiple outbreaks or at larger spatial scales. This study used the observed number of trees killed by mountain pine beetles per square kilometer in Oregon and Washington, USA, over the past three decades to quantify and assess the influence of climate and weather variables on beetle activity over longer time periods and larger scales than previously studied. Influences of temperature and precipitation in addition to process model output variables were assessed at annual and climatological time scales. The statistical analysis showed that new attacks are more likely to occur at locations with climatological mean August temperatures >15 degrees C. After controlling for beetle pressure, the variables with the largest effect on the odds of an outbreak exceeding a certain size were minimum winter temperature (positive relationship) and drought conditions in current and previous years. Precipitation levels in the year prior to the outbreak had a positive effect, possibly an indication of the influence of this driver on brood size. Two-year cumulative precipitation had a negative effect, a possible indication of the influence of drought on tree stress. Among the process model variables, cold tolerance was the strongest indicator of an outbreak increasing to epidemic size. A weather suitability index developed from the regression analysis indicated a 2.5x increase in the odds of outbreak at locations with highly suitable weather vs. locations with low suitability. The models were useful for estimating expected amounts of damage (total area with outbreaks) and for quantifying the contribution of climate to total damage. Overall, the results confirm the importance of climate and weather on the spatial expansion of bark beetle outbreaks over time.

  5. Plasticity of Performance Curves Can Buffer Reaction Rates from Body Temperature Variation in Active Endotherms.

    PubMed

    Seebacher, Frank; Little, Alexander G

    2017-01-01

    Endotherms regulate their core body temperature by adjusting metabolic heat production and insulation. Endothermic body temperatures are therefore relatively stable compared to external temperatures. The thermal sensitivity of biochemical reaction rates is thought to have co-evolved with body temperature regulation so that optimal reaction rates occur at the regulated body temperature. However, recent data show that core body temperatures even of non-torpid endotherms fluctuate considerably. Additionally, peripheral temperatures can be considerably lower and more variable than core body temperatures. Here we discuss whether published data support the hypothesis that thermal performance curves of physiological reaction rates are plastic so that performance is maintained despite variable body temperatures within active (non-torpid) endotherms, and we explore mechanisms that confer plasticity. There is evidence that thermal performance curves in tissues that experience thermal fluctuations can be plastic, although this question remains relatively unexplored for endotherms. Mechanisms that alter thermal responses locally at the tissue level include transient potential receptor ion channels (TRPV and TRPM) and the AMP-activated protein kinase (AMPK) both of which can influence metabolism and energy expenditure. Additionally, the thermal sensitivity of processes that cause post-transcriptional RNA degradation can promote the relative expression of cold-responsive genes. Endotherms can respond to environmental fluctuations similarly to ectotherms, and thermal plasticity complements core body temperature regulation to increase whole-organism performance. Thermal plasticity is ancestral to endothermic thermoregulation, but it has not lost its selective advantage so that modern endotherms are a physiological composite of ancestral ectothermic and derived endothermic traits.

  6. Plasticity of Performance Curves Can Buffer Reaction Rates from Body Temperature Variation in Active Endotherms

    PubMed Central

    Seebacher, Frank; Little, Alexander G.

    2017-01-01

    Endotherms regulate their core body temperature by adjusting metabolic heat production and insulation. Endothermic body temperatures are therefore relatively stable compared to external temperatures. The thermal sensitivity of biochemical reaction rates is thought to have co-evolved with body temperature regulation so that optimal reaction rates occur at the regulated body temperature. However, recent data show that core body temperatures even of non-torpid endotherms fluctuate considerably. Additionally, peripheral temperatures can be considerably lower and more variable than core body temperatures. Here we discuss whether published data support the hypothesis that thermal performance curves of physiological reaction rates are plastic so that performance is maintained despite variable body temperatures within active (non-torpid) endotherms, and we explore mechanisms that confer plasticity. There is evidence that thermal performance curves in tissues that experience thermal fluctuations can be plastic, although this question remains relatively unexplored for endotherms. Mechanisms that alter thermal responses locally at the tissue level include transient potential receptor ion channels (TRPV and TRPM) and the AMP-activated protein kinase (AMPK) both of which can influence metabolism and energy expenditure. Additionally, the thermal sensitivity of processes that cause post-transcriptional RNA degradation can promote the relative expression of cold-responsive genes. Endotherms can respond to environmental fluctuations similarly to ectotherms, and thermal plasticity complements core body temperature regulation to increase whole-organism performance. Thermal plasticity is ancestral to endothermic thermoregulation, but it has not lost its selective advantage so that modern endotherms are a physiological composite of ancestral ectothermic and derived endothermic traits. PMID:28824463

  7. Effects of processing conditions on mammographic image quality.

    PubMed

    Braeuning, M P; Cooper, H W; O'Brien, S; Burns, C B; Washburn, D B; Schell, M J; Pisano, E D

    1999-08-01

    Any given mammographic film will exhibit changes in sensitometric response and image resolution as processing variables are altered. Developer type, immersion time, and temperature have been shown to affect the contrast of the mammographic image and thus lesion visibility. The authors evaluated the effect of altering processing variables, including film type, developer type, and immersion time, on the visibility of masses, fibrils, and speaks in a standard mammographic phantom. Images of a phantom obtained with two screen types (Kodak Min-R and Fuji) and five film types (Kodak Min-R M, Min-R E, Min-R H; Fuji UM-MA HC, and DuPont Microvision-C) were processed with five different developer chemicals (Autex SE, DuPont HSD, Kodak RP, Picker 3-7-90, and White Mountain) at four different immersion times (24, 30, 36, and 46 seconds). Processor chemical activity was monitored with sensitometric strips, and developer temperatures were continuously measured. The film images were reviewed by two board-certified radiologists and two physicists with expertise in mammography quality control and were scored based on the visibility of calcifications, masses, and fibrils. Although the differences in the absolute scores were not large, the Kodak Min-R M and Fuji films exhibited the highest scores, and images developed in White Mountain and Autex chemicals exhibited the highest scores. For any film, several processing chemicals may be used to produce images of similar quality. Extended processing may no longer be necessary.

  8. Real-time laser cladding control with variable spot size

    NASA Astrophysics Data System (ADS)

    Arias, J. L.; Montealegre, M. A.; Vidal, F.; Rodríguez, J.; Mann, S.; Abels, P.; Motmans, F.

    2014-03-01

    Laser cladding processing has been used in different industries to improve the surface properties or to reconstruct damaged pieces. In order to cover areas considerably larger than the diameter of the laser beam, successive partially overlapping tracks are deposited. With no control over the process variables this conduces to an increase of the temperature, which could decrease mechanical properties of the laser cladded material. Commonly, the process is monitored and controlled by a PC using cameras, but this control suffers from a lack of speed caused by the image processing step. The aim of this work is to design and develop a FPGA-based laser cladding control system. This system is intended to modify the laser beam power according to the melt pool width, which is measured using a CMOS camera. All the control and monitoring tasks are carried out by a FPGA, taking advantage of its abundance of resources and speed of operation. The robustness of the image processing algorithm is assessed, as well as the control system performance. Laser power is decreased as substrate temperature increases, thus maintaining a constant clad width. This FPGA-based control system is integrated in an adaptive laser cladding system, which also includes an adaptive optical system that will control the laser focus distance on the fly. The whole system will constitute an efficient instrument for part repair with complex geometries and coating selective surfaces. This will be a significant step forward into the total industrial implementation of an automated industrial laser cladding process.

  9. Future hotspots of increasing temperature variability in tropical countries

    NASA Astrophysics Data System (ADS)

    Bathiany, S.; Dakos, V.; Scheffer, M.; Lenton, T. M.

    2017-12-01

    Resolving how climate variability will change in future is crucial to determining how challenging it will be for societies and ecosystems to adapt to climate change. We show that the largest increases in temperature variability - that are robust between state-of-the art climate models - are concentrated in tropical countries. On average, temperature variability increases by 15% per degree of global warming in Amazonia and Southern Africa during austral summer, and by up to 10% °C-1 in the Sahel, India and South East Asia. Southern hemisphere changes can be explained by drying soils, whereas shifts in atmospheric structure play a more important role in the Northern hemisphere. These robust regional changes in variability are associated with monthly timescale events, whereas uncertain changes in inter-annual modes of variability make the response of global temperature variability uncertain. Our results suggest that regional changes in temperature variability will create new inequalities in climate change impacts between rich and poor nations.

  10. Optimization of L-asparaginase production from novel Enterobacter sp., by submerged fermentation using response surface methodology.

    PubMed

    Erva, Rajeswara Reddy; Goswami, Ajgebi Nath; Suman, Priyanka; Vedanabhatla, Ravali; Rajulapati, Satish Babu

    2017-03-16

    The culture conditions and nutritional rations influencing the production of extra cellular antileukemic enzyme by novel Enterobacter aerogenes KCTC2190/MTCC111 were optimized in shake-flask culture. Process variables like pH, temperature, incubation time, carbon and nitrogen sources, inducer concentration, and inoculum size were taken into account. In the present study, finest enzyme activity achieved by traditional one variable at a time method was 7.6 IU/mL which was a 2.6-fold increase compared to the initial value. Further, the L-asparaginase production was optimized using response surface methodology, and validated experimental result at optimized process variables gave 18.35 IU/mL of L-asparaginase activity, which is 2.4-times higher than the traditional optimization approach. The study explored the E. aerogenes MTCC111 as a potent and potential bacterial source for high yield of antileukemic drug.

  11. Mathematical modeling of the temperature distribution under the cathode spot of the vacuum arc

    NASA Astrophysics Data System (ADS)

    Kuznetsov, V. G.; Babushkina, E. S.

    2016-07-01

    We present a solution to the problem of the temperature distribution under the cathode spot of taking into account melting and spare deposits of metal, brought to boiling temperature on the surface of the cathode spot. The process of heat transfer in the metal is described by the unsteady three dimensional heat conduction equation in Cartesian coordinate system. Similarly, we present a solution to the problem of the temperature distribution in the presence of the pores in the surface layer of the metal. To solve this task we used a numerical method to finite differences and variable directions. We present the calculated data on the distribution of temperature under the cathode spot for different values of spot diameters and speeds its movement.

  12. Effects of Known Determinants on Methylene Bisphenyl Isocyanate (MDI) Concentration During Spray-On Truck Bed-Lining Processes.

    PubMed

    Schaal, Nicholas C; Brazile, William J; Finnie, Katie L; Tiger, James P

    2017-08-01

    Occupational exposure to methylene bisphenyl isocyanate (MDI) presents serious worker health concerns as it may lead to short- and long-term health effects such as asthma, airway irritation, hypersensitivity pneumonitis, and irritation of skin and mucous membranes. While studies of worker isocyanate exposures during vehicle painting activities are widespread, few studies have investigated the spray-on truck bed-liner (STBL) industry. The purpose of this study was to determine the effectiveness of several ventilation system variables and process characteristics in controlling MDI concentrations in the STBL industry. A total of 47 personal air samples were collected for MDI during 18 site visits at nine STBL companies in Colorado and Wyoming. Ventilation system and process characteristics that were assessed included: ventilation system face velocity, airflow, air changes per minute (AC/M), capture velocity, percent of MDI in bed-liner product, application temperature, application pressure, paint booth temperature, paint booth relative humidity, paint booth volume, and quantity of bed-liner product applied. Pearson correlation revealed percentage of MDI in bed-liner product (r = 0.557, n = 14, P < 0.05) and process temperature (r = 0.677, n = 14, P < 0.05) had high positive correlation with MDI concentration. Ventilation system face velocity (r = -0.578, n = 14, P < 0.05) and AC/M (r = -0.657, n = 14, P < 0.05) had high negative correlation with MDI concentration while airflow (r = -0.475, n = 14, P < 0.05) and capture velocity (r = -0.415, n = 14, P = 0.07) had moderate negative correlation with MDI concentration. Multiple linear regression revealed process temperature and capture velocity made a statistically significant and unique contribution in estimating MDI concentration (F (2, 11) = 10.99, P < 0.05) with an adjusted R2 of 0.61, explaining 61% of the variability in MDI concentration. This investigation contributed to an understudied STBL industry by targeting determinants germane to MDI exposures during STBL application processes. Increasing ventilation performance for AC/M, airflow, face velocity, and capture velocity while also decreasing bed-liner application temperature and bed-liner product MDI content may have the greatest effect on reducing worker MDI exposures during STBL activities. Published by Oxford University Press on behalf of the British Occupational Hygiene Society 2017.

  13. Decadal variability of the Tropical Atlantic Ocean Surface Temperature in shipboard measurements and in a Global Ocean-Atmosphere model

    NASA Technical Reports Server (NTRS)

    Mehta, Vikram M.; Delworth, Thomas

    1995-01-01

    Sea surface temperature (SST) variability was investigated in a 200-yr integration of a global model of the coupled oceanic and atmospheric general circulations developed at the Geophysical Fluid Dynamics Laboratory (GFDL). The second 100 yr of SST in the coupled model's tropical Atlantic region were analyzed with a variety of techniques. Analyses of SST time series, averaged over approximately the same subregions as the Global Ocean Surface Temperature Atlas (GOSTA) time series, showed that the GFDL SST anomalies also undergo pronounced quasi-oscillatory decadal and multidecadal variability but at somewhat shorter timescales than the GOSTA SST anomalies. Further analyses of the horizontal structures of the decadal timescale variability in the GFDL coupled model showed the existence of two types of variability in general agreement with results of the GOSTA SST time series analyses. One type, characterized by timescales between 8 and 11 yr, has high spatial coherence within each hemisphere but not between the two hemispheres of the tropical Atlantic. A second type, characterized by timescales between 12 and 20 yr, has high spatial coherence between the two hemispheres. The second type of variability is considerably weaker than the first. As in the GOSTA time series, the multidecadal variability in the GFDL SST time series has approximately opposite phases between the tropical North and South Atlantic Oceans. Empirical orthogonal function analyses of the tropical Atlantic SST anomalies revealed a north-south bipolar pattern as the dominant pattern of decadal variability. It is suggested that the bipolar pattern can be interpreted as decadal variability of the interhemispheric gradient of SST anomalies. The decadal and multidecadal timescale variability of the tropical Atlantic SST, both in the actual and in the GFDL model, stands out significantly above the background 'red noise' and is coherent within each of the time series, suggesting that specific sets of processes may be responsible for the choice of the decadal and multidecadal timescales. Finally, it must be emphasized that the GFDL coupled ocean-atmosphere model generates the decadal and multidecadal timescale variability without any externally applied force, solar or lunar, at those timescales.

  14. Studies on Hot-Melt Prepregging on PRM-II-50 Polyimide Resin with Graphite Fibers

    NASA Technical Reports Server (NTRS)

    Shin, E. Eugene; Sutter, James K.; Juhas, John; Veverka, Adrienne; Klans, Ojars; Inghram, Linda; Scheiman, Dan; Papadopoulos, Demetrios; Zoha, John; Bubnick, Jim

    2004-01-01

    A second generation PMR (in situ Polymerization of Monomer Reactants) polyimide resin PMR-II-50, has been considered for high temperature and high stiffness space propulsion composites applications for its improved high temperature performance. As part of composite processing optimization, two commercial prepregging methods: solution vs. hot-melt processes were investigated with M40J fabrics from Toray. In a previous study a systematic chemical, physical, thermal and mechanical characterization of these composites indicated the poor resin-fiber interfacial wetting, especially for the hot-melt process, resulted in poor composite quality. In order to improve the interfacial wetting, optimization of the resin viscosity and process variables were attempted in a commercial hot-melt prepregging line. In addition to presenting the results from the prepreg quality optimization trials, the combined effects of the prepregging method and two different composite cure methods, i.e. hot press vs. autoclave on composite quality and properties are discussed.

  15. Studies on Hot-Melt Prepregging of PMR-II-50 Polyimide Resin with Graphite Fibers

    NASA Technical Reports Server (NTRS)

    Shin, E. Eugene; Sutter, James K.; Juhas, John; Veverka, Adrienne; Klans, Ojars; Inghram, Linda; Scheiman, Dan; Papadopoulos, Demetrios; Zoha, John; Bubnick, Jim

    2003-01-01

    A Second generation PMR (in situ Polymerization of Monomer Reactants) polyimide resin, PMR-II-50, has been considered for high temperature and high stiffness space propulsion composites applications for its improved high temperature performance. As part of composite processing optimization, two commercial prepregging methods: solution vs. hot-melt processes were investigated with M40J fabrics from Toray. In a previous study a systematic chemical, physical, thermal and mechanical characterization of these composites indicated that poor resin-fiber interfacial wetting, especially for the hot-melt process, resulted in poor composite quality. In order to improve the interfacial wetting, optimization of the resin viscosity and process variables were attempted in a commercial hot-melt prepregging line. In addition to presenting the results from the prepreg quality optimization trials, the combined effects of the prepregging method and two different composite cure methods, i.e., hot press vs. autoclave on composite quality and properties are discussed.

  16. Sources and Impacts of Modeled and Observed Low-Frequency Climate Variability

    NASA Astrophysics Data System (ADS)

    Parsons, Luke Alexander

    Here we analyze climate variability using instrumental, paleoclimate (proxy), and the latest climate model data to understand more about the sources and impacts of low-frequency climate variability. Understanding the drivers of climate variability at interannual to century timescales is important for studies of climate change, including analyses of detection and attribution of climate change impacts. Additionally, correctly modeling the sources and impacts of variability is key to the simulation of abrupt change (Alley et al., 2003) and extended drought (Seager et al., 2005; Pelletier and Turcotte, 1997; Ault et al., 2014). In Appendix A, we employ an Earth system model (GFDL-ESM2M) simulation to study the impacts of a weakening of the Atlantic meridional overturning circulation (AMOC) on the climate of the American Tropics. The AMOC drives some degree of local and global internal low-frequency climate variability (Manabe and Stouffer, 1995; Thornalley et al., 2009) and helps control the position of the tropical rainfall belt (Zhang and Delworth, 2005). We find that a major weakening of the AMOC can cause large-scale temperature, precipitation, and carbon storage changes in Central and South America. Our results suggest that possible future changes in AMOC strength alone will not be sufficient to drive a large-scale dieback of the Amazonian forest, but this key natural ecosystem is sensitive to dry-season length and timing of rainfall (Parsons et al., 2014). In Appendix B, we compare a paleoclimate record of precipitation variability in the Peruvian Amazon to climate model precipitation variability. The paleoclimate (Lake Limon) record indicates that precipitation variability in western Amazonia is 'red' (i.e., increasing variability with timescale). By contrast, most state-of-the-art climate models indicate precipitation variability in this region is nearly 'white' (i.e., equally variability across timescales). This paleo-model disagreement in the overall structure of the variance spectrum has important consequences for the probability of multi-year drought. Our lake record suggests there is a significant background threat of multi-year, and even decade-length, drought in western Amazonia, whereas climate model simulations indicate most droughts likely last no longer than one to three years. These findings suggest climate models may underestimate the future risk of extended drought in this important region. In Appendix C, we expand our analysis of climate variability beyond South America. We use observations, well-constrained tropical paleoclimate, and Earth system model data to examine the overall shape of the climate spectrum across interannual to century frequencies. We find a general agreement among observations and models that temperature variability increases with timescale across most of the globe outside the tropics. However, as compared to paleoclimate records, climate models generate too little low-frequency variability in the tropics (e.g., Laepple and Huybers, 2014). When we compare the shape of the simulated climate spectrum to the spectrum of a simple autoregressive process, we find much of the modeled surface temperature variability in the tropics could be explained by ocean smoothing of weather noise. Importantly, modeled precipitation tends to be similar to white noise across much of the globe. By contrast, paleoclimate records of various types from around the globe indicate that both temperature and precipitation variability should experience much more low-frequency variability than a simple autoregressive or white-noise process. In summary, state-of-the-art climate models generate some degree of dynamically driven low-frequency climate variability, especially at high latitudes. However, the latest climate models, observations, and paleoclimate data provide us with drastically different pictures of the background climate system and its associated risks. This research has important consequences for improving how we simulate climate extremes as we enter a warmer (and often drier) world in the coming centuries; if climate models underestimate low-frequency variability, we will underestimate the risk of future abrupt change and extreme events, such as megadroughts.

  17. Diel Surface Temperature Range Scales with Lake Size

    PubMed Central

    Woolway, R. Iestyn; Jones, Ian D.; Maberly, Stephen C.; French, Jon R.; Livingstone, David M.; Monteith, Donald T.; Simpson, Gavin L.; Thackeray, Stephen J.; Andersen, Mikkel R.; Battarbee, Richard W.; DeGasperi, Curtis L.; Evans, Christopher D.; de Eyto, Elvira; Feuchtmayr, Heidrun; Hamilton, David P.; Kernan, Martin; Krokowski, Jan; Rimmer, Alon; Rose, Kevin C.; Rusak, James A.; Ryves, David B.; Scott, Daniel R.; Shilland, Ewan M.; Smyth, Robyn L.; Staehr, Peter A.; Thomas, Rhian; Waldron, Susan; Weyhenmeyer, Gesa A.

    2016-01-01

    Ecological and biogeochemical processes in lakes are strongly dependent upon water temperature. Long-term surface warming of many lakes is unequivocal, but little is known about the comparative magnitude of temperature variation at diel timescales, due to a lack of appropriately resolved data. Here we quantify the pattern and magnitude of diel temperature variability of surface waters using high-frequency data from 100 lakes. We show that the near-surface diel temperature range can be substantial in summer relative to long-term change and, for lakes smaller than 3 km2, increases sharply and predictably with decreasing lake area. Most small lakes included in this study experience average summer diel ranges in their near-surface temperatures of between 4 and 7°C. Large diel temperature fluctuations in the majority of lakes undoubtedly influence their structure, function and role in biogeochemical cycles, but the full implications remain largely unexplored. PMID:27023200

  18. High quality factor single-crystal diamond mechanical resonators

    NASA Astrophysics Data System (ADS)

    Ovartchaiyapong, P.; Pascal, L. M. A.; Myers, B. A.; Lauria, P.; Bleszynski Jayich, A. C.

    2012-10-01

    Single-crystal diamond is a promising material for microelectromechanical systems (MEMs) because of its low mechanical loss, compatibility with extreme environments, and built-in interface to high-quality spin centers. But its use has been limited by challenges in processing and growth. We demonstrate a wafer bonding-based technique to form diamond on insulator, from which we make single-crystal diamond micromechanical resonators with mechanical quality factors as high as 338 000 at room temperature. Variable temperature measurements down to 10 K reveal a nonmonotonic dependence of quality factor on temperature. These resonators enable integration of single-crystal diamond into MEMs technology for classical and quantum applications.

  19. Chemochromic Detector for Sensing Gas Leakage and Process for Producing the Same

    NASA Technical Reports Server (NTRS)

    Williams, Martha K. (Inventor); Roberson, Luke B. (Inventor); Smith, Trent M. (Inventor); Tate, LaNetra Clayton (Inventor); Captain, Janine E. (Inventor)

    2014-01-01

    A chemochromic sensor for detecting a combustible gas, such as hydrogen, includes a chemochromic pigment mechanically mixed with a polymer and molded into a rigid or pliable shape. In a preferred embodiment, the chemochromic detector is within the material which is molded into a manufactured part, said part becoming the detector itself. The detector is robust and easily modifiable for a variety of applications and environmental conditions, such as atmospheres of inert gas, hydrogen gas, or mixtures of gases, or in environments that have variable temperature, including high temperatures such as above 100 C. and low temperatures such as below -196 C.

  20. Effect of process parameters on hardness, temperature profile and solidification of different layers processed by direct metal laser sintering (DMLS)

    NASA Astrophysics Data System (ADS)

    Ahmed, Sazzad Hossain; Mian, Ahsan; Srinivasan, Raghavan

    2016-07-01

    In DMLS process objects are fabricated layer by layer from powdered material by melting induced by a controlled laser beam. Metallic powder melts and solidifies to form a single layer. Solidification map during layer formation is an important route to characterize micro-structure and grain morphology of sintered layer. Generally, solidification leads to columnar, equiaxed or mixture of these two types grain morphology depending on solidification rate and thermal gradient. Eutectic or dendritic structure can be formed in fully equiaxed zone. This dendritic growth has a large effect on material properties. Smaller dendrites generally increase ductility of the layer. Thus, materials can be designed by creating desired grain morphology in certain regions using DMLS process. To accomplish this, hardness, temperature distribution, thermal gradient and solidification cooling rate in processed layers will be studied under change of process variables by using finite element analysis, with specific application to Ti-6Al-4V.

  1. New Ultrasonic Controller and Characterization System for Low Temperature Drying Process Intensification

    NASA Astrophysics Data System (ADS)

    Andrés, R. R.; Blanco, A.; Acosta, V. M.; Riera, E.; Martínez, I.; Pinto, A.

    Process intensification constitutes a high interesting and promising industrial area. It aims to modify conventional processes or develop new technologies in order to reduce energy needs, increase yields and improve product quality. It has been demonstrated by this research group (CSIC) that power ultrasound have a great potential in food drying processes. The effects associated with the application of power ultrasound can enhance heat and mass transfer and may constitute a way for process intensification. The objective of this work has been the design and development of a new ultrasonic system for the power characterization of piezoelectric plate-transducers, as excitation, monitoring, analysis, control and characterization of their nonlinear response. For this purpose, the system proposes a new, efficient and economic approach that separates the effect of different parameters of the process like excitation, medium and transducer parameters and variables (voltage, current, frequency, impedance, vibration velocity, acoustic pressure and temperature) by observing the electrical, mechanical, acoustical and thermal behavior, and controlling the vibrational state.

  2. Modeling and investigation of submerged fermentation process to produce extracellular polysaccharide using Lactobacillus confusus.

    PubMed

    Thirugnanasambandham, K; Sivakumar, V; Prakash Maran, J

    2014-12-19

    The main objective of the present study is to investigate and optimize the Submerged fermentation (SMF) process parameters such as addition of coconut water, NaCl dose, incubation time and temperature on the production of extracellular polysaccharide (EPS) and biomass production using Lactobacillus confuses. Response surface methodology (RSM) coupled with four factors three level Box-Behnken design (BBD) was employed to model the SMF process. RSM analysis indicated good correspondence between experimental and predicted values. Three dimentional (3D) response surface plots were used to study the interactive effects of process variables on SMF process. The optimum process conditions for the maximum production of EPS and biomass were found to be as follows; addition of coconut water of 40%, NaCl dose of 15%, incubation time of 24h and temperature of 35°C. Under these conditions, 10.57 g/L of EPS and 3.9 g/L of biomass were produced. Copyright © 2014 Elsevier Ltd. All rights reserved.

  3. Neural and Neural Gray-Box Modeling for Entry Temperature Prediction in a Hot Strip Mill

    NASA Astrophysics Data System (ADS)

    Barrios, José Angel; Torres-Alvarado, Miguel; Cavazos, Alberto; Leduc, Luis

    2011-10-01

    In hot strip mills, initial controller set points have to be calculated before the steel bar enters the mill. Calculations rely on the good knowledge of rolling variables. Measurements are available only after the bar has entered the mill, and therefore they have to be estimated. Estimation of process variables, particularly that of temperature, is of crucial importance for the bar front section to fulfill quality requirements, and the same must be performed in the shortest possible time to preserve heat. Currently, temperature estimation is performed by physical modeling; however, it is highly affected by measurement uncertainties, variations in the incoming bar conditions, and final product changes. In order to overcome these problems, artificial intelligence techniques such as artificial neural networks and fuzzy logic have been proposed. In this article, neural network-based systems, including neural-based Gray-Box models, are applied to estimate scale breaker entry temperature, given its importance, and their performance is compared to that of the physical model used in plant. Several neural systems and several neural-based Gray-Box models are designed and tested with real data. Taking advantage of the flexibility of neural networks for input incorporation, several factors which are believed to have influence on the process are also tested. The systems proposed in this study were proven to have better performance indexes and hence better prediction capabilities than the physical models currently used in plant.

  4. Optimisation of low temperature extraction of banana juice using commercial pectinase.

    PubMed

    Sagu, Sorel Tchewonpi; Nso, Emmanuel Jong; Karmakar, Sankha; De, Sirshendu

    2014-05-15

    The objective of this work was to develop a process with optimum conditions for banana juice. The procedure involves hydrolyzing the banana pulp by commercial pectinase followed by cloth filtration. Response surface methodology with Doehlert design was utilised to optimize the process parameters. The temperature of incubation (30-60 °C), time of reaction (20-120 min) and concentration of pectinase (0.01-0.05% v/w) were the independent variables and viscosity, clarity, alcohol insoluble solids (AIS), total polyphenol and protein concentration were the responses. Total soluble sugar, pH, conductivity, calcium, sodium and potassium concentration in the juice were also evaluated. The results showed reduction of AIS and viscosity with reaction time and pectinase concentration and reduction of polyphenol and protein concentration with temperature. Using numerical optimization, the optimum conditions for the enzymatic extraction of banana juice were estimated. Depectinization kinetics was also studied at optimum temperature and variation of kinetic constants with enzyme dose was evaluated. Copyright © 2013 Elsevier Ltd. All rights reserved.

  5. Characterization of turbulent processes by the Raman lidar system BASIL during the HD(CP)2 observational prototype experiment - HOPE

    NASA Astrophysics Data System (ADS)

    Di Girolamo, Paolo; Summa, Donato; Stelitano, Dario; Cacciani, Marco; Scoccione, Andrea; Behrendt, Andreas; Wulfmeyer, Volker

    2017-02-01

    Measurements carried out by the Raman lidar system BASIL are reported to demonstrate the capability of this instrument to characterize turbulent processes within the Convective Boundary Layer (CBL). In order to resolve the vertical profiles of turbulent variables, high resolution water vapour and temperature measurements, with a temporal resolution of 10 sec and a vertical resolution of 90 and 30 m, respectively, are considered. Measurements of higher-order moments of the turbulent fluctuations of water vapour mixing ratio and temperature are obtained based on the application of spectral and auto-covariance analyses to the water vapour mixing ratio and temperature time series. The algorithms are applied to a case study (IOP 5, 20 April 2013) from the HD(CP)2 Observational Prototype Experiment (HOPE), held in Central Germany in the spring 2013. The noise errors are demonstrated to be small enough to allow the derivation of up to fourth-order moments for both water vapour mixing ratio and temperature fluctuations with sufficient accuracy.

  6. Measurement and modeling of diel variability of polybrominated diphenyl ethers and chlordanes in air.

    PubMed

    Moeckel, Claudia; Macleod, Matthew; Hungerbühler, Konrad; Jones, Kevin C

    2008-05-01

    Short-term variability of concentrations of polybrominated diphenyl ethers (PBDEs) and chlordanes in air at a semirural site in England over a 5 day period is reported. Four-hour air samples were collected during a period dominated by a high pressure system that produced stable diel (24-h) patterns of meteorological conditions such as temperature and atmospheric boundary layer height. PBDE and chlordane concentrations showed clear diel variability with concentrations in the afternoon and evening being 1.9 - 2.7 times higher than in the early morning. The measurements are interpreted using a multimedia mass balance model parametrized with forcing functions representing local temperature, atmospheric boundary layer height, wind speed and hydroxyl radical concentrations. Model results indicate that reversible, temperature-controlled air-surface exchange is the primary driver of the diel concentration pattern observed for chlordanes and PBDE 28. For higher brominated PBDE congeners (47, 99 and 100), the effect of variable atmospheric mixing height in combination with irreversible deposition on aerosol particles is dominant and explains the diel patterns almost entirely. Higher concentrations of chlordanes and PBDEs in air observed at the end of the study period could be related to likely source areas using back trajectory analysis. This is the first study to clearly document diel variability in concentrations of PBDEs in air over a period of several days. Our model analysis indicates that high daytime and low nighttime concentrations of semivolatile organic chemicals can arise from different underlying driving processes, and are not necessarily evidence of reversible air-surface exchange on a 24-h time scale.

  7. Ecosystem responses to recent oceanographic variability in high-latitude Northern Hemisphere ecosystems

    NASA Astrophysics Data System (ADS)

    Mueter, Franz J.; Broms, Cecilie; Drinkwater, Kenneth F.; Friedland, Kevin D.; Hare, Jonathan A.; Hunt, George L., Jr.; Melle, Webjørn; Taylor, Maureen

    2009-04-01

    As part of the international MENU collaboration, we compared and contrasted ecosystem responses to climate-forced oceanographic variability across several high latitude regions of the North Pacific (Eastern Bering Sea (EBS) and Gulf of Alaska (GOA)) and North Atlantic Oceans (Gulf of Maine/Georges Bank (GOM/GB) and the Norwegian/Barents Seas (NOR/BAR)). Differences in the nitrate content of deep source waters and incoming solar radiation largely explain differences in average primary productivity among these ecosystems. We compared trends in productivity and abundance at various trophic levels and their relationships with sea-surface temperature. Annual net primary production generally increases with annual mean sea-surface temperature between systems and within the EBS, BAR, and GOM/GB. Zooplankton biomass appears to be controlled by both top-down (predation by fish) and bottom-up forcing (advection, SST) in the BAR and NOR regions. In contrast, zooplankton in the GOM/GB region showed no evidence of top-down forcing but appeared to control production of major fish populations through bottom-up processes that are independent of temperature variability. Recruitment of several fish stocks is significantly and positively correlated with temperature in the EBS and BAR, but cod and pollock recruitment in the EBS has been negatively correlated with temperature since the 1977 shift to generally warmer conditions. In each of the ecosystems, fish species showed a general poleward movement in response to warming. In addition, the distribution of groundfish in the EBS has shown a more complex, non-linear response to warming resulting from internal community dynamics. Responses to recent warming differ across systems and appear to be more direct and more pronounced in the higher latitude systems where food webs and trophic interactions are simpler and where both zooplankton and fish species are often limited by cold temperatures.

  8. Effects of extrusion variables on the properties of waxy hulless barley extrudates.

    PubMed

    Köksel, Hamit; Ryu, Gy-Hyung; Başman, Arzu; Demiralp, Hande; Ng, Perry K W

    2004-02-01

    The objective of this research was to investigate the extrudability of waxy hulless barley flour under various extrusion conditions. Waxy hulless barley flour was processed in a laboratory-scale corotating twin-screw extruder with different levels of feed moisture content (22.3, 26.8, and 30.7%) and die temperature (130, 150, and 170 degrees C) to develop a snack food with high beta-glucan content. The effects of extrusion condition variables (screw configuration, moisture, and temperature) on the system variables (pressure and specific mechanical energy), the extrudate physical properties (sectional expansion index, bulk density), starch gelatinization, pasting properties (cold peak viscosity, trough viscosity, and final viscosity), and beta-glucan contents were determined. Results were evaluated by using response surface methodology. Increased extrusion temperature and feed moisture content resulted in decreases in exit die pressure and specific mechanical energy values. For extrudates extruded under low shear screw configuration (LS), increased barrel temperature decreased sectional expansion index (SEI) values at both low and high moisture contents. The feed moisture seems to have an inverse relationship with SEI over the range studied. Bulk density was higher at higher moisture contents, for both low and high barrel temperatures, for samples extruded under high shear screw configuration (HS) and LS. Cold peak viscosities (CV) were observed in all samples. The CV increased with the increase in extrusion temperature and feed moisture content. Although beta-glucan contents of the LS extrudates were comparable to that of barley flour sample, HS samples had generally lower beta-glucan contents. The extrusion cooking technique seems to be promising for the production of snack foods with high beta-glucan content, especially using LS conditions.

  9. Trends and variability in streamflow and snowmelt runoff timing in the southern Tianshan Mountains

    NASA Astrophysics Data System (ADS)

    Shen, Yan-Jun; Shen, Yanjun; Fink, Manfred; Kralisch, Sven; Chen, Yaning; Brenning, Alexander

    2018-02-01

    Streamflow and snowmelt runoff timing of mountain rivers are susceptible to climate change. Trends and variability in streamflow and snowmelt runoff timing in four mountain basins in the southern Tianshan were analyzed in this study. Streamflow trends were detected by Mann-Kendall tests and changes in snowmelt runoff timing were analyzed based on the winter/spring snowmelt runoff center time (WSCT). Pearson's correlation coefficient was further calculated to analyze the relationships between climate variables, streamflow and WSCT. Annual streamflow increased significantly in past decades in the southern Tianshan, especially in spring and winter months. However, the relations between streamflow and temperature/precipitation depend on the different streamflow generation processes. Annual precipitation plays a vital role in controlling recharge in the Toxkon basin, while the Kaidu and Huangshuigou basins are governed by both precipitation and temperature. Seasonally, temperature has a strong effect on streamflow in autumn and winter, while summer streamflow appears more sensitive to changes in precipitation. However, temperature is the dominant factor for streamflow in the glacierized Kunmalik basin at annual and seasonal scales. An uptrend in streamflow begins in the 1990s at both annual and seasonal scales, which is generally consistent with temperature and precipitation fluctuations. Average WSCT dates in the Kaidu and Huangshuigou basins are earlier than in the Toxkon and Kunmalik basins, and shifted towards earlier dates since the mid-1980s in all the basins. It is plausible that WSCT dates are more sensitive to warmer temperature in spring period compared to precipitation, except for the Huangshuigou basin. Taken together, these findings are useful for applications in flood risk regulation, future hydropower projects and integrated water resources management.

  10. Surface temperature dataset for North America obtained by application of optimal interpolation algorithm merging tree-ring chronologies and climate model output

    NASA Astrophysics Data System (ADS)

    Chen, Xin; Xing, Pei; Luo, Yong; Nie, Suping; Zhao, Zongci; Huang, Jianbin; Wang, Shaowu; Tian, Qinhua

    2017-02-01

    A new dataset of surface temperature over North America has been constructed by merging climate model results and empirical tree-ring data through the application of an optimal interpolation algorithm. Errors of both the Community Climate System Model version 4 (CCSM4) simulation and the tree-ring reconstruction were considered to optimize the combination of the two elements. Variance matching was used to reconstruct the surface temperature series. The model simulation provided the background field, and the error covariance matrix was estimated statistically using samples from the simulation results with a running 31-year window for each grid. Thus, the merging process could continue with a time-varying gain matrix. This merging method (MM) was tested using two types of experiment, and the results indicated that the standard deviation of errors was about 0.4 °C lower than the tree-ring reconstructions and about 0.5 °C lower than the model simulation. Because of internal variabilities and uncertainties in the external forcing data, the simulated decadal warm-cool periods were readjusted by the MM such that the decadal variability was more reliable (e.g., the 1940-1960s cooling). During the two centuries (1601-1800 AD) of the preindustrial period, the MM results revealed a compromised spatial pattern of the linear trend of surface temperature, which is in accordance with the phase transition of the Pacific decadal oscillation and Atlantic multidecadal oscillation. Compared with pure CCSM4 simulations, it was demonstrated that the MM brought a significant improvement to the decadal variability of the gridded temperature via the merging of temperature-sensitive tree-ring records.

  11. Ground and surface temperature variability for remote sensing of soil moisture in a heterogeneous landscape

    USDA-ARS?s Scientific Manuscript database

    At the Little River Watershed (LRW) heterogeneous landscape near Tifton Georgia US an in situ network of stations operated by the US Department of Agriculture-Agriculture Research Service (USDA-ARS-SEWRL) was established in 2003 for the long term study of climatic and soil biophysical processes. To ...

  12. Ecosystem dynamics and disturbance in mountain wildernesses: assessing vulnerability of natural resources to change

    Treesearch

    Daniel B. Fagre; David L. Peterson

    2000-01-01

    An integrated program of ecosystem modeling and extensive field studies at Glacier and Olympic National Parks has quantified many of the ecological processes affected by climatic variability and disturbance. Models have successfully estimated snow distribution, annual watershed discharge, and stream temperature variation based on seven years of monitoring. Various...

  13. Temperature variability during targeted temperature management is not associated with neurological outcomes following cardiac arrest.

    PubMed

    Nayeri, Arash; Bhatia, Nirmanmoh; Holmes, Benjamin; Borges, Nyal; Armstrong, William; Xu, Meng; Farber-Eger, Eric; Wells, Quinn S; McPherson, John A

    2017-06-01

    Recent studies on comatose survivors of cardiac arrest undergoing targeted temperature management (TTM) have shown similar outcomes at multiple target temperatures. However, details regarding core temperature variability during TTM and its prognostic implications remain largely unknown. We sought to assess the association between core temperature variability and neurological outcomes in patients undergoing TTM following cardiac arrest. We analyzed a prospectively collected cohort of 242 patients treated with TTM following cardiac arrest at a tertiary care hospital between 2007 and 2014. Core temperature variability was defined as the statistical variance (i.e. standard deviation squared) amongst all core temperature recordings during the maintenance phase of TTM. Poor neurological outcome at hospital discharge, defined as a Cerebral Performance Category (CPC) score>2, was the primary outcome. Death prior to hospital discharge was assessed as the secondary outcome. Multivariable logistic regression was used to examine the association between temperature variability and neurological outcome or death at hospital discharge. A poor neurological outcome was observed in 147 (61%) patients and 136 (56%) patients died prior to hospital discharge. In multivariable logistic regression, increased core temperature variability was not associated with increased odds of poor neurological outcomes (OR 0.38, 95% CI 0.11-1.38, p=0.142) or death (OR 0.43, 95% CI 0.12-1.53, p=0.193) at hospital discharge. In this study, individual core temperature variability during TTM was not associated with poor neurological outcomes or death at hospital discharge. Copyright © 2017 Elsevier Inc. All rights reserved.

  14. Optimization of furfural and 5-hydroxymethylfurfural production from wheat straw by a microwave-assisted process.

    PubMed

    Yemiş, Oktay; Mazza, Giuseppe

    2012-04-01

    Optimization of acid-catalyzed conversion conditions of wheat straw into furfural, 5-hydroxymethylfurfural (HMF), glucose, and xylose was studied by response surface methodology (RSM). A central composite design (CCD) was used to determine the effects of independent variables, including reaction temperature (140-200 °C), residence time (1-41 min), pH (0.1-2.1), and liquid:solid ratio (15-195 mL/g) on furan and sugar production. The surface response analysis revealed that temperature, time and pH had a strong influence on the furfural, HMF, xylose and glucose yield, whereas liquid to solid ratio was found not to be significant. The initial pH of solution was the most important variable in acid-catalyzed conversion of wheat straw to furans. The maximum predicted furfural, HMF, xylose and glucose yields were 66%, 3.4%, 100%, and 65%, respectively. This study demonstrated that the microwave-assisted process was a very effective method for the xylose production from wheat straw by diluted acid catalysis. Crown Copyright © 2012. Published by Elsevier Ltd. All rights reserved.

  15. Winter climate change affects growing-season soil microbial biomass and activity in northern hardwood forests.

    PubMed

    Durán, Jorge; Morse, Jennifer L; Groffman, Peter M; Campbell, John L; Christenson, Lynn M; Driscoll, Charles T; Fahey, Timothy J; Fisk, Melany C; Mitchell, Myron J; Templer, Pamela H

    2014-11-01

    Understanding the responses of terrestrial ecosystems to global change remains a major challenge of ecological research. We exploited a natural elevation gradient in a northern hardwood forest to determine how reductions in snow accumulation, expected with climate change, directly affect dynamics of soil winter frost, and indirectly soil microbial biomass and activity during the growing season. Soils from lower elevation plots, which accumulated less snow and experienced more soil temperature variability during the winter (and likely more freeze/thaw events), had less extractable inorganic nitrogen (N), lower rates of microbial N production via potential net N mineralization and nitrification, and higher potential microbial respiration during the growing season. Potential nitrate production rates during the growing season were particularly sensitive to changes in winter snow pack accumulation and winter soil temperature variability, especially in spring. Effects of elevation and winter conditions on N transformation rates differed from those on potential microbial respiration, suggesting that N-related processes might respond differently to winter climate change in northern hardwood forests than C-related processes. © 2014 John Wiley & Sons Ltd.

  16. Modeling Coupled Movement of Water, Vapor, and Energy in Soils and at the Soil-Atmosphere Interface Using HYDRUS

    NASA Astrophysics Data System (ADS)

    Simunek, Jiri; Brunetti, Giuseppe; Saito, Hirotaka; Bristow, Keith

    2017-04-01

    Mass and energy fluxes in the subsurface are closely coupled and cannot be evaluated without considering their mutual interactions. However, only a few numerical models consider coupled water, vapor and energy transport in both the subsurface and at the soil-atmosphere interface. While hydrological and thermal processes in the subsurface are commonly implemented in existing models, which often consider both isothermally and thermally induced water and vapor flow, the interactions at the soil-atmosphere interface are often simplified, and the effects of slope inclination, slope azimuth, variable surface albedo and plant shading on incoming radiation and spatially variable surface mass and energy balance, and consequently on soil moisture and temperature distributions, are rarely considered. In this presentation we discuss these missing elements and our attempts to implement them into the HYDRUS model. We demonstrate implications of some of these interactions and their impact on the spatial distributions of soil temperature and water content, and their effect on soil evaporation. Additionally, we will demonstrate the use of the HYDRUS model to simulate processes relevant to the ground source heat pump systems.

  17. Influence of operating conditions on the air gasification of dry refinery sludge in updraft gasifier

    NASA Astrophysics Data System (ADS)

    Ahmed, R.; Sinnathambi, C. M.

    2013-06-01

    In the present work, details of the equilibrium modeling of dry refinery sludge (DRS) are presented using ASPEN PLUS Simulator in updraft gasifier. Due to lack of available information in the open journal on refinery sludge gasification using updraft gasifier, an evaluate for its optimum conditions on gasification is presented in this paper. For this purpose a Taguchi Orthogonal array design, statistical software is applied to find optimum conditions for DRS gasification. The goal is to identify the most significant process variable in DRS gasification conditions. The process variables include; oxidation zone temperature, equivalent ratio, operating pressure will be simulated and examined. Attention was focused on the effect of optimum operating conditions on the gas composition of H2 and CO (desirable) and CO2 (undesirable) in terms of mass fraction. From our results and finding it can be concluded that the syngas (H2 & CO) yield in term of mass fraction favors high oxidation zone temperature and at atmospheric pressure while CO2 acid gas favor at a high level of equivalent ratio as well as air flow rate favoring towards complete combustion.

  18. Optimization of extraction of high purity all-trans-lycopene from tomato pulp waste.

    PubMed

    Poojary, Mahesha M; Passamonti, Paolo

    2015-12-01

    The aim of this work was to optimize the extraction of pure all-trans-lycopene from the pulp fractions of tomato processing waste. A full factorial design (FFD) consisting of four independent variables including extraction temperature (30-50 °C), time (1-60 min), percentage of acetone in n-hexane (25-75%, v/v) and solvent volume (10-30 ml) was used to investigate the effects of process variables on the extraction. The absolute amount of lycopene present in the pulp waste was found to be 0.038 mg/g. The optimal conditions for extraction were as follows: extraction temperature 20 °C, time 40 min, a solvent composition of 25% acetone in n-hexane (v/v) and solvent volume 40 ml. Under these conditions, the maximal recovery of lycopene was 94.7%. The HPLC-DAD analysis demonstrated that, lycopene was obtained in the all-trans-configuration at a very high purity grade of 98.3% while the amount of cis-isomers and other carotenoids were limited. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. Evaluation of Container Closure System Integrity for Storage of Frozen Drug Products: Impact of Capping Force and Transportation.

    PubMed

    Nieto, Alejandra; Roehl, Holger; Adler, Michael; Mohl, Silke

    2018-05-31

    Frozen-state storage and cold-chain transport are key operations in the development and commercialization of biopharmaceuticals. Nowadays, a few marketed drug products are stored (and/or) shipped under frozen conditions to ensure sufficient stability, particularly for live viral vaccines. When these products are stored in glass vials with stoppers, the elastomer of the stopper needs to be flexible enough to seal the vial at the target's lowest temperature to ensure container closure integrity and hence both sterility and safety of the drug product. The container closure integrity assessment in the frozen state (e.g., -20°C, -80°C) should include: Container Closure Integrity (CCI) of the Container Closure System (CCS) itself, impact of processing, e.g. capping process on CCI and impact of shipment and movement on CCI in the frozen state. The objective of this work was an evaluation of the impact of processing and shipment on CCI of a CCS in the frozen state. The impact on other quality attributes was not investigated. In this light, the ThermCCI method was applied to evaluate the impact of shipping stress and variable capping force on CCI of frozen vials and to evaluate the temperature limits of rubber stoppers. In conclusion, retaining CCI during cold storage is mostly a function of vial-stopper combination and temperatures below -40°C may pose a risk to the CCI of a frozen drug product. Variable capping force may have an influence on the CCI of a frozen drug product if not appropriately assessed. Regarding the impact of shipment on the CCI of glass vials, no indication was given either at room temperature, -20°C or -75°C when compared to static storage at such temperatures. Copyright © 2018, Parenteral Drug Association.

  20. Spatial Variability of Dissolved Organic Carbon in Headwater Wetlands in Central Pennsylvania

    NASA Astrophysics Data System (ADS)

    Reichert-Eberhardt, A. J.; Wardrop, D.; Boyer, E. W.

    2011-12-01

    Dissolved organic carbon (DOC) is known to be of an important factor in many microbially mediated biochemical processes, such as denitrification, that occur in wetlands. The spatial variability of DOC within a wetland could impact the microbes that fuel these processes, which in turn can affect the ecosystem services provided by wetlands. However, the amount of spatial variability of DOC in wetlands is generally unknown. Furthermore, it is unknown how disturbance to wetlands can affect spatial variability of DOC. Previous research in central Pennsylvania headwater wetland soils has shown that wetlands with increased human disturbance had decreased heterogeneity in soil biochemistry. To address groundwater chemical variability 20 monitoring wells were installed in a random pattern in a 400 meter squared plot in a low-disturbance headwater wetland and a high-disturbance headwater wetland in central Pennsylvania. Water samples from these wells will be analyzed for DOC, dissolved inorganic carbon, nitrate, ammonia, and sulfate concentrations, as well as pH, conductivity, and temperature on a seasonal basis. It is hypothesized that there will be greater spatial variability of groundwater chemistry in the low disturbance wetland than the high disturbance wetland. This poster will present the initial data concerning DOC spatial variability in both the low and high impact headwater wetlands.

  1. Characteristics of temperature rise in variable inductor employing magnetorheological fluid driven by a high-frequency pulsed voltage source

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, Ho-Young; Kang, In Man, E-mail: imkang@ee.knu.ac.kr; Shon, Chae-Hwa

    2015-05-07

    A variable inductor with magnetorheological (MR) fluid has been successfully applied to power electronics applications; however, its thermal characteristics have not been investigated. To evaluate the performance of the variable inductor with respect to temperature, we measured the characteristics of temperature rise and developed a numerical analysis technique. The characteristics of temperature rise were determined experimentally and verified numerically by adopting a multiphysics analysis technique. In order to accurately estimate the temperature distribution in a variable inductor with an MR fluid-gap, the thermal solver should import the heat source from the electromagnetic solver to solve the eddy current problem. Tomore » improve accuracy, the B–H curves of the MR fluid under operating temperature were obtained using the magnetic property measurement system. In addition, the Steinmetz equation was applied to evaluate the core loss in a ferrite core. The predicted temperature rise for a variable inductor showed good agreement with the experimental data and the developed numerical technique can be employed to design a variable inductor with a high-frequency pulsed voltage source.« less

  2. First-principles modeling of laser-matter interaction and plasma dynamics in nanosecond pulsed laser shock processing

    NASA Astrophysics Data System (ADS)

    Zhang, Zhongyang; Nian, Qiong; Doumanidis, Charalabos C.; Liao, Yiliang

    2018-02-01

    Nanosecond pulsed laser shock processing (LSP) techniques, including laser shock peening, laser peen forming, and laser shock imprinting, have been employed for widespread industrial applications. In these processes, the main beneficial characteristic is the laser-induced shockwave with a high pressure (in the order of GPa), which leads to the plastic deformation with an ultrahigh strain rate (105-106/s) on the surface of target materials. Although LSP processes have been extensively studied by experiments, few efforts have been put on elucidating underlying process mechanisms through developing a physics-based process model. In particular, development of a first-principles model is critical for process optimization and novel process design. This work aims at introducing such a theoretical model for a fundamental understanding of process mechanisms in LSP. Emphasis is placed on the laser-matter interaction and plasma dynamics. This model is found to offer capabilities in predicting key parameters including electron and ion temperatures, plasma state variables (temperature, density, and pressure), and the propagation of the laser shockwave. The modeling results were validated by experimental data.

  3. Kinetic Modeling of Corn Fermentation with S. cerevisiae Using a Variable Temperature Strategy.

    PubMed

    Souza, Augusto C M; Mousaviraad, Mohammad; Mapoka, Kenneth O M; Rosentrater, Kurt A

    2018-04-24

    While fermentation is usually done at a fixed temperature, in this study, the effect of having a controlled variable temperature was analyzed. A nonlinear system was used to model batch ethanol fermentation, using corn as substrate and the yeast Saccharomyces cerevisiae , at five different fixed and controlled variable temperatures. The lower temperatures presented higher ethanol yields but took a longer time to reach equilibrium. Higher temperatures had higher initial growth rates, but the decay of yeast cells was faster compared to the lower temperatures. However, in a controlled variable temperature model, the temperature decreased with time with the initial value of 40 ∘ C. When analyzing a time window of 60 h, the ethanol production increased 20% compared to the batch with the highest temperature; however, the yield was still 12% lower compared to the 20 ∘ C batch. When the 24 h’ simulation was analyzed, the controlled model had a higher ethanol concentration compared to both fixed temperature batches.

  4. Bioreactor process parameter screening utilizing a Plackett-Burman design for a model monoclonal antibody.

    PubMed

    Agarabi, Cyrus D; Schiel, John E; Lute, Scott C; Chavez, Brittany K; Boyne, Michael T; Brorson, Kurt A; Khan, Mansoora; Read, Erik K

    2015-06-01

    Consistent high-quality antibody yield is a key goal for cell culture bioprocessing. This endpoint is typically achieved in commercial settings through product and process engineering of bioreactor parameters during development. When the process is complex and not optimized, small changes in composition and control may yield a finished product of less desirable quality. Therefore, changes proposed to currently validated processes usually require justification and are reported to the US FDA for approval. Recently, design-of-experiments-based approaches have been explored to rapidly and efficiently achieve this goal of optimized yield with a better understanding of product and process variables that affect a product's critical quality attributes. Here, we present a laboratory-scale model culture where we apply a Plackett-Burman screening design to parallel cultures to study the main effects of 11 process variables. This exercise allowed us to determine the relative importance of these variables and identify the most important factors to be further optimized in order to control both desirable and undesirable glycan profiles. We found engineering changes relating to culture temperature and nonessential amino acid supplementation significantly impacted glycan profiles associated with fucosylation, β-galactosylation, and sialylation. All of these are important for monoclonal antibody product quality. © 2015 Wiley Periodicals, Inc. and the American Pharmacists Association.

  5. Food Legumes and Rising Temperatures: Effects, Adaptive Functional Mechanisms Specific to Reproductive Growth Stage and Strategies to Improve Heat Tolerance

    PubMed Central

    Sita, Kumari; Sehgal, Akanksha; HanumanthaRao, Bindumadhava; Nair, Ramakrishnan M.; Vara Prasad, P. V.; Kumar, Shiv; Gaur, Pooran M.; Farooq, Muhammad; Siddique, Kadambot H. M.; Varshney, Rajeev K.; Nayyar, Harsh

    2017-01-01

    Ambient temperatures are predicted to rise in the future owing to several reasons associated with global climate changes. These temperature increases can result in heat stress- a severe threat to crop production in most countries. Legumes are well-known for their impact on agricultural sustainability as well as their nutritional and health benefits. Heat stress imposes challenges for legume crops and has deleterious effects on the morphology, physiology, and reproductive growth of plants. High-temperature stress at the time of the reproductive stage is becoming a severe limitation for production of grain legumes as their cultivation expands to warmer environments and temperature variability increases due to climate change. The reproductive period is vital in the life cycle of all plants and is susceptible to high-temperature stress as various metabolic processes are adversely impacted during this phase, which reduces crop yield. Food legumes exposed to high-temperature stress during reproduction show flower abortion, pollen and ovule infertility, impaired fertilization, and reduced seed filling, leading to smaller seeds and poor yields. Through various breeding techniques, heat tolerance in major legumes can be enhanced to improve performance in the field. Omics approaches unravel different mechanisms underlying thermotolerance, which is imperative to understand the processes of molecular responses toward high-temperature stress. PMID:29123532

  6. Food Legumes and Rising Temperatures: Effects, Adaptive Functional Mechanisms Specific to Reproductive Growth Stage and Strategies to Improve Heat Tolerance.

    PubMed

    Sita, Kumari; Sehgal, Akanksha; HanumanthaRao, Bindumadhava; Nair, Ramakrishnan M; Vara Prasad, P V; Kumar, Shiv; Gaur, Pooran M; Farooq, Muhammad; Siddique, Kadambot H M; Varshney, Rajeev K; Nayyar, Harsh

    2017-01-01

    Ambient temperatures are predicted to rise in the future owing to several reasons associated with global climate changes. These temperature increases can result in heat stress- a severe threat to crop production in most countries. Legumes are well-known for their impact on agricultural sustainability as well as their nutritional and health benefits. Heat stress imposes challenges for legume crops and has deleterious effects on the morphology, physiology, and reproductive growth of plants. High-temperature stress at the time of the reproductive stage is becoming a severe limitation for production of grain legumes as their cultivation expands to warmer environments and temperature variability increases due to climate change. The reproductive period is vital in the life cycle of all plants and is susceptible to high-temperature stress as various metabolic processes are adversely impacted during this phase, which reduces crop yield. Food legumes exposed to high-temperature stress during reproduction show flower abortion, pollen and ovule infertility, impaired fertilization, and reduced seed filling, leading to smaller seeds and poor yields. Through various breeding techniques, heat tolerance in major legumes can be enhanced to improve performance in the field. Omics approaches unravel different mechanisms underlying thermotolerance, which is imperative to understand the processes of molecular responses toward high-temperature stress.

  7. Process- and controller-adaptations determine the physiological effects of cold acclimation.

    PubMed

    Werner, Jürgen

    2008-09-01

    Experimental results on physiological effects of cold adaptation seem confusing and apparently incompatible with one another. This paper will explain that a substantial part of such a variety of results may be deduced from a common functional concept. A core/shell treatment ("model") of the thermoregulatory system is used with mean body temperature as the controlled variable. Adaptation, as a higher control level, is introduced into the system. Due to persistent stressors, either the (heat transfer) process or the controller properties (parameters) are adjusted (or both). It is convenient to call the one "process adaptation" and the other "controller adaptation". The most commonly demonstrated effect of autonomic cold acclimation is a change in the controller threshold. The analysis shows that this necessarily means a lowering of body temperature because of a lowered metabolic rate. This explains experimental results on both Europeans in the climatic chamber and Australian Aborigines in a natural environment. Exclusive autonomic process adaptation occurs in the form of a better insulation. The analysis explains why the post-adaptive steady-state can only be achieved, if the controller system reduces metabolism and why in spite of this the new state is inevitably characterized by a rise in body temperature. If both process and controller adaptations are simultaneously present, there may be not any change of body temperature at all, e.g., as demonstrated in animal experiments. Whether this kind of adaptation delivers a decrease, an increase or no change of mean body temperature, depends on the proportion of process and controller adaptation.

  8. Demonstration of a Variable Phase Turbine Power System for Low Temperature Geothermal Resources

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hays, Lance G

    2014-07-07

    A variable phase turbine assembly will be designed and manufactured having a turbine, operable with transcritical, two-phase or vapor flow, and a generator – on the same shaft supported by process lubricated bearings. The assembly will be hermetically sealed and the generator cooled by the refrigerant. A compact plate-fin heat exchanger or tube and shell heat exchanger will be used to transfer heat from the geothermal fluid to the refrigerant. The demonstration turbine will be operated separately with two-phase flow and with vapor flow to demonstrate performance and applicability to the entire range of low temperature geothermal resources. The vapormore » leaving the turbine is condensed in a plate-fin refrigerant condenser. The heat exchanger, variable phase turbine assembly and condenser are all mounted on single skids to enable factory assembly and checkout and minimize installation costs. The system will be demonstrated using low temperature (237F) well flow from an existing large geothermal field. The net power generated, 1 megawatt, will be fed into the existing power system at the demonstration site. The system will demonstrate reliable generation of inexpensive power from low temperature resources. The system will be designed for mass manufacturing and factory assembly and should cost less than $1,200/kWe installed, when manufactured in large quantities. The estimated cost of power for 300F resources is predicted to be less than 5 cents/kWh. This should enable a substantial increase in power generated from low temperature geothermal resources.« less

  9. Reduction of verotoxigenic Escherichia coli by process and recipe optimisation in dry-fermented sausages.

    PubMed

    Heir, E; Holck, A L; Omer, M K; Alvseike, O; Høy, M; Måge, I; Axelsson, L

    2010-07-15

    Outbreaks of verotoxigenic Escherichia coli (VTEC) linked to dry-fermented sausages (DFSs) have emphasized the need for DFS manufacturers to introduce measures to obtain enhanced safety and still maintain the sensory qualities of their products. To our knowledge no data have yet been reported on non-O157:H7 VTEC survival in DFS. Here, the importance of recipe and process variables on VTEC (O157:H7 and O103:H25) reductions in two types of DFS, morr and salami, was determined through three statistically designed experiments. Linear regression and ANOVA analyses showed that no single variable had a dominant effect on VTEC reductions. High levels of NaCl, NaNO(2), glucose (low pH) and fermentation temperature gave enhanced VTEC reduction, while high fat and large casing diameter (a(w)) gave the opposite effect. Interaction effects were small. The process and recipe variables showed similar effects in morr and salami. In general, recipes combining high batter levels of salt (NaCl and NaNO(2)) and glucose along with high fermentation temperature that gave DFS with low final pH and a(w), provided approximately 3 log(10) reductions compared to approximately 1.5 log(10) reductions obtained for standard recipe DFS. Storage at 4 degrees C for 2 months provided log(10) 0.33-0.95 additional VTEC reductions and were only marginally affected by recipe type. Sensory tests revealed only small differences between the various recipes of morr and salami. By optimisation of recipe and process parameters, it is possible to obtain increased microbial safety of DFS while maintaining the sensory qualities of the sausages. 2010 Elsevier B.V. All rights reserved.

  10. Monitoring Climate Variability and Change in Northern Alaska: Updates to the U.S. Geological Survey (USGS) Climate and Permafrost Monitoring Network

    NASA Astrophysics Data System (ADS)

    Urban, F. E.; Clow, G. D.; Meares, D. C.

    2004-12-01

    Observations of long-term climate and surficial geological processes are sparse in most of the Arctic, despite the fact that this region is highly sensitive to climate change. Instrumental networks that monitor the interplay of climatic variability and geological/cryospheric processes are a necessity for documenting and understanding climate change. Improvements to the spatial coverage and temporal scale of Arctic climate data are in progress. The USGS, in collaboration with The Bureau of Land Management (BLM) and The Fish and Wildlife Service (FWS) currently maintains two types of monitoring networks in northern Alaska: (1) A 15 site network of continuously operating active-layer and climate monitoring stations, and (2) a 21 element array of deep bore-holes in which the thermal state of deep permafrost is monitored. Here, we focus on the USGS Alaska Active Layer and Climate Monitoring Network (AK-CLIM). These 15 stations are deployed in longitudinal transects that span Alaska north of the Brooks Range, (11 in The National Petroleum Reserve Alaska, (NPRA), and 4 in The Arctic National Wildlife Refuge (ANWR)). An informative overview and update of the USGS AK-CLIM network is presented, including insight to current data, processing and analysis software, and plans for data telemetry. Data collection began in 1998 and parameters currently measured include air temperature, soil temperatures (5-120 cm), snow depth, incoming and reflected short-wave radiation, soil moisture (15 cm), wind speed and direction. Custom processing and analysis software has been written that calculates additional parameters such as active layer thaw depth, thawing-degree-days, albedo, cloudiness, and duration of seasonal snow cover. Data from selected AK-CLIM stations are now temporally sufficient to begin identifying trends, anomalies, and inter-annual variability in the climate of northern Alaska.

  11. An oxide dispersion strengthened Ni-W-Al alloy with superior high temperature strength

    NASA Technical Reports Server (NTRS)

    Glasgow, T. K.

    1976-01-01

    An experimental oxide dispersion strengthened (ODS) alloy, WAZ-D, derived from the WAZ-20 composition was produced by the mechanical alloying process. Cast WAZ-20 is strengthened by both a high refractory metal content, and 70 volume percent of gamma prime. The ODS alloy WAZ-D was responsive to variables of alloy content, of attritor processing, of consolidation by extrusion, and of heat treatment. The best material produced had large highly elongated grains. It exhibited tensile strengths generally superior to a comparable cast alloy. The ODS alloy exhibited high temperature stress rupture life considerably superior to any known cast superalloy. Tensile and rupture ductility were low, as was intermediate temperature rupture life. Very low creep rates were noted and some specimens failed with essentially no third stage creep. Also the benefit derived from the oxide dispersion, far out-weighed that from the elongated microstructure alone.

  12. The hydrological effects of varying vegetation characteristics in a temperate water-limited basin: Development of the dynamic Budyko-Choudhury-Porporato (dBCP) model

    NASA Astrophysics Data System (ADS)

    Liu, Qiang; McVicar, Tim R.; Yang, Zhifeng; Donohue, Randall J.; Liang, Liqiao; Yang, Yuting

    2016-12-01

    Vegetation patterns are affected by water availability, which, in turn, influences the hydrological partitioning and regional water balance, especially in water-limited regions. Considering the important role of vegetation in partitioning the catchment water yield, the recently developed Budyko-Choudhury-Porporato (or BCP) model incorporated Porporato's model of key ecohydrological processes into Choudury's form of the Budyko hydroclimatic framework. Here we extend the steady state BCP model by incorporating dynamic ecohydrological processes into it and combining it with a typical bucket soil water balance model (resulting in the dynamic BCP, or dBCP, model). The dBCP model is used here to assess the impacts of vegetation on the water balance in a temperate water-limited basin (i.e., the Yellow River Basin (YRB) in north China), where growing season phenology is primarily constrained by low temperatures. The results show that: (i) the incorporation of dynamic growing season (fs) and dynamic effective rooting depth (Ze) conditions into the dBCP model improves results when compared to the original BCP model; (ii) dBCP model's results vary depending on time-step used (i.e., we tested mean-annual to monthly), which reflected the influence of catchment variables, e.g., catchment area, catchment-average air temperature, dryness index and Ze; and (iii) actual evapotranspiration (E) is more sensitive to changes in mean storm depth (α), followed by P, Ze, and Ep. When taking into account observed variability of each of four ecohydrological variables, changes in Ze cause the greatest variability in E, generally followed by variability in P and α, and then Ep. The dBCP results indicate that incorporating dynamic ecohydrological processes into the Budyko framework can improve the estimation of inter-annual variability of the regional water balance. This can help to understand the water requirement and to establish suitable water management strategies to adapt to climate change in the YRB. The dBCP model has modest forcing data requirements and can be applied to other basins globally.

  13. Quantitative Analysis of Relevant Soil, Land-use and Climate Characteristics on Landscape Degradation in Hungary

    NASA Astrophysics Data System (ADS)

    Kertesz, Adam; Mika, Janos; Jakab, Gergely; Palinkas, Melinda

    2017-04-01

    The objective of our research is to survey degradation processes acting in each micro-region of Hungary in connection with geographical and climatic characteristics. A survey of land degradation processes has been carried out at medium scale (1:50 000) to identify the affected areas of the region. Over 18,000 rectangles of Hungary have been digitally characterised for several types of land degradation. Water-flow type gully erosion and soil-loss (RUSLE, 2015: Esdac-data) are studied for dependent variables in this study. USDA textural classes, available water capacity, bulk density, clay content, coarse fragments, silt content, sand content, soil parent material, soil texture, land-use type (Corine, 2012) are used for non-climatic variables. Some of these characteristics are quantified in a non-scalable way, so the first step was to arrange these qualitative codes or pseudo-numbers into monotonous order for including them into the following multi-regression analyses. Data available from the CarpatClim Project (www.carpatclim-eu.org/pages/home) for 1961-2010 are also used in their 50 years averages is seasonal and annual resolution. The selected variables from this gridded data set are global radiation, daily mean temperature, maximum and minimum temperature, number of extreme cold days (< 20 C), precipitation, extreme wet days (>20 mm), days with utilizable precipitation (>1mm/d), potential evapotranspiration, Palmer Index (PDSI), Palfai Index (PAI), relative humidity and wind speed at 10 m height. The gully erosion processes strongly depend on the investigated non-climatic variables, mostly on parent material and slope. The group of further climatic factors is formed by winter relative humidity, wind speed and all-year round Palmer index. Besides leading role of the above non-climatic factors, additional effects of the significant climate variables are difficult to interpret. Nevertheless, the partial effects of these climate variables are combined with future climate scenarios available from GCM and RCM studies for Hungary. The real climate change effects may likely be stronger, than those obtained by this combination, due to inter-dependences between the non-climatic factors and climate variations. The study has been supported by the OTKA-K108755 project.

  14. How Close Are We to the Temperature Tipping Point of the Biosphere?

    NASA Astrophysics Data System (ADS)

    Duffy, K. H.

    2017-12-01

    All biological processes accelerate rapidly with increasing temperature (Tinf); reaching a maximum rate (Tmax), after which they decline. However different biological processes may not be synchronised in their response to increasing temperatures resulting in major dis-equilibria of ecosystem processes. Particularly, the linked processes of photosynthesis and respiration have different curvature that is determined by their inherent sensitivity to temperature. Constraining the difference in temperature curves between photosynthesis and respiration allows us to quantify changes to global carbon metabolism and the land sink of carbon as a whole. During the last century the biosphere has acted as a sink of carbon from the atmosphere partly mitigating accumulation of CO2 derived from burning of fossil fuels Here we ask the following questions: As global temperature increases will photosynthesis and respiration become de-coupled and when? What is Tmax for the land sink, and where is current mean temperature range in regard to this important threshold? At what global and regional temperatures do we expect the biosphere to become a source of carbon to the atmosphere? To address these questions we used the recently released FLUXNET2015 dataset comprised of 212 eddy covariance flux tower sites which concurrently measure land-atmosphere carbon exchange along with micro-meteorological variables. Here, we illustrate our results for Tinf and Tmax of the land sink by biome and for the biosphere as a whole. Our results suggest that recent warming has already pushed us past the inflection point of photosynthesis, and that any additional warming will increase the cumulative annual dose of time spent past Tmax for the land sink. Even under moderate climate projections, we expect to see a slowing of the terrestrial carbon sink by as early as 2040.

  15. Application of automated measurement stations for continuous water quality monitoring of the Dender river in Flanders, Belgium.

    PubMed

    Vandenberghe, V; Goethals, P L M; Van Griensven, A; Meirlaen, J; De Pauw, N; Vanrolleghem, P; Bauwens, W

    2005-09-01

    During the summer of 1999, two automated water quality measurement stations were installed along the Dender river in Belgium. The variables dissolved oxygen, temperature, conductivity, pH, rain-intensity, flow and solar radiation were measured continuously. In this paper these on-line measurement series are presented and interpreted using also additional measurements and ecological expert-knowledge. The purpose was to demonstrate the variability in time and space of the aquatic processes and the consequences of conducting and interpreting discrete measurements for river quality assessment and management. The large fluctuations of the data illustrated the importance of continuous measurements for the complete description and modelling of the biological processes in the river.

  16. Variable self-powered light detection CMOS chip with real-time adaptive tracking digital output based on a novel on-chip sensor.

    PubMed

    Wang, HongYi; Fan, Youyou; Lu, Zhijian; Luo, Tao; Fu, Houqiang; Song, Hongjiang; Zhao, Yuji; Christen, Jennifer Blain

    2017-10-02

    This paper provides a solution for a self-powered light direction detection with digitized output. Light direction sensors, energy harvesting photodiodes, real-time adaptive tracking digital output unit and other necessary circuits are integrated on a single chip based on a standard 0.18 µm CMOS process. Light direction sensors proposed have an accuracy of 1.8 degree over a 120 degree range. In order to improve the accuracy, a compensation circuit is presented for photodiodes' forward currents. The actual measurement precision of output is approximately 7 ENOB. Besides that, an adaptive under voltage protection circuit is designed for variable supply power which may undulate with temperature and process.

  17. Process optimization and analysis of microwave assisted extraction of pectin from dragon fruit peel.

    PubMed

    Thirugnanasambandham, K; Sivakumar, V; Prakash Maran, J

    2014-11-04

    Microwave assisted extraction (MAE) technique was employed for the extraction of pectin from dragon fruit peel. The extracting parameters were optimized by using four-variable-three-level Box-Behnken design (BBD) coupled with response surface methodology (RSM). RSM analysis indicated good correspondence between experimental and predicted values. 3D response surface plots were used to study the interactive effects of process variables on extraction of pectin. The optimum extraction conditions for the maximum yield of pectin were power of 400 W, temperature of 45 °C, extracting time of 20 min and solid-liquid ratio of 24 g/mL. Under these conditions, 7.5% of pectin was extracted. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. Optimization of Bread Enriched with Garcinia mangostana Pericarp Powder

    NASA Astrophysics Data System (ADS)

    Ibrahim, U. K.; Salleh, R. Mohd; Maqsood-ul-Hague, S. N. S.; Hashib, S. Abd; Karim, S. F. Abd

    2018-05-01

    The aim of present work is to optimize the formulation of bread enhanced with Garcinia mangostana pericarp powder with the combination of baking process conditions. The independent variables used were baking time (15 - 30 minutes), baking temperature (180 - 220°C) and pericarp powder concentration (0.5 - 2.0%). The physical and chemical properties of bread sample such as antioxidant activity, phenolic content, moisture analysis and colour parameters were studied. Bread dough without fortification of pericarp powder was used as control. Data obtained were analyzed by multiple regressions and the significant model such as linear and quadratic with variables interactions were used. As a conclusion, the optimum baking conditions were found at 213°C baking temperature with 23 minutes baking time and addition of 0.87% for Garcinia mangostana pericarp powder to the bread formulation.

  19. A critical assessment of the Burning Index in Los Angeles County, California

    USGS Publications Warehouse

    Schoenberg, F.P.; Chang, H.-C.; Keeley, J.E.; Pompa, J.; Woods, J.; Xu, H.

    2007-01-01

    The Burning Index (BI) is commonly used as a predictor of wildfire activity. An examination of data on the BI and wildfires in Los Angeles County, California, from January 1976 to December 2000 reveals that although the BI is positively associated with wildfire occurrence, its predictive value is quite limited. Wind speed alone has a higher correlation with burn area than BI, for instance, and a simple alternative point process model using wind speed, relative humidity, precipitation and temperature well outperforms the BI in terms of predictive power. The BI is generally far too high in winter and too low in fall, and may exaggerate the impact of individual variables such as wind speed or temperature during times when other variables, such as precipitation or relative humidity, render the environment ill suited for wildfires. ?? IAWF 2007.

  20. Turning up the heat: temperature influences the relative importance of top-down and bottom-up effects.

    PubMed

    Hoekman, David

    2010-10-01

    Understanding how communities respond to changes in temperature is a major challenge for community ecology. Temperature influences the relative degree to which top-down and bottom-up forces structure ecological communities. In greenhouse experiments using the aquatic community found in pitcher plants (Sarracenia purpurea), I tested how temperature affected the relative importance of top-down (mosquito predation) and bottom-up (ant carcasses) forces on protozoa and bacteria populations. While bottom-up effects did not vary consistently with temperature, the top-down effects of predators on protozoa increased at higher temperatures. These results suggest that temperature could change the relative importance of top-down and bottom-up effects in ecological communities. Specifically, higher temperature may increase the strength of top-down effects by raising predator metabolic rate and concomitant processes (e.g., activity, foraging, digestion, growth) relative to cooler temperatures. These findings apply broadly to an understanding of trophic interactions in a variable environment and are especially relevant in the context of ongoing climate change.

  1. Automated Temperature Control with Adjusting Outlet Valve of Fuel in the Process of Cooking Palm Sugar

    NASA Astrophysics Data System (ADS)

    Aripin, H.; Hiron, Nurul; Priatna, Edvin; Busaeri, Nundang; Andang, Asep; Suhartono; Sabchevski, Svilen

    2018-04-01

    In this paper, a real-time temperature control system for coconut sugar cooking is presented. It is based on a thermocouple temperature sensor. The temperature in the closed evaporator is used as a control variable of the DC servo control system for opening and closing of a valve embedded in a gas burner. The output power level, which is necessary in order to reach the target temperature is controlled by the microcontroller ATMega328P. A circuit module for control of the valve and temperature sensors as well as software for data acquisition have been implemented. The test results show that the system properly stabilizes the temperature in the closed evaporator for coconut sugar cooking in the range from room temperature to 110°C. A set point can be reached and held with an accuracy of ±0.75°C at a temperature of 110°C for 60 minutes.

  2. Time Scales and Sources of European Temperature Variability

    NASA Astrophysics Data System (ADS)

    Årthun, Marius; Kolstad, Erik W.; Eldevik, Tor; Keenlyside, Noel S.

    2018-04-01

    Skillful predictions of continental climate would be of great practical benefit for society and stakeholders. It nevertheless remains fundamentally unresolved to what extent climate is predictable, for what features, at what time scales, and by which mechanisms. Here we identify the dominant time scales and sources of European surface air temperature (SAT) variability during the cold season using a coupled climate reanalysis, and a statistical method that estimates SAT variability due to atmospheric circulation anomalies. We find that eastern Europe is dominated by subdecadal SAT variability associated with the North Atlantic Oscillation, whereas interdecadal and multidecadal SAT variability over northern and southern Europe are thermodynamically driven by ocean temperature anomalies. Our results provide evidence that temperature anomalies in the North Atlantic Ocean are advected over land by the mean westerly winds and, hence, provide a mechanism through which ocean temperature controls the variability and provides predictability of European SAT.

  3. An analysis of the impact of pre‐analytical factors on the urine proteome: Sample processing time, temperature, and proteolysis

    PubMed Central

    Hepburn, Sophie; Cairns, David A.; Jackson, David; Craven, Rachel A.; Riley, Beverley; Hutchinson, Michelle; Wood, Steven; Smith, Matthew Welberry; Thompson, Douglas

    2015-01-01

    Purpose We have examined the impact of sample processing time delay, temperature, and the addition of protease inhibitors (PIs) on the urinary proteome and peptidome, an important aspect of biomarker studies. Experimental design Ten urine samples from patients with varying pathologies were each divided and PIs added to one‐half, with aliquots of each then processed and frozen immediately, or after a delay of 6 h at 4°C or room temperature (20–22°C), effectively yielding 60 samples in total. Samples were then analyzed by 2D‐PAGE, SELDI‐TOF‐MS, and immunoassay. Results Interindividual variability in profiles was the dominant feature in all analyses. Minimal changes were observed by 2D‐PAGE as a result of delay in processing, temperature, or PIs and no changes were seen in IgG, albumin, β2‐microglobulin, or α1‐microglobulin measured by immunoassay. Analysis of peptides showed clustering of some samples by presence/absence of PIs but the extent was very patient‐dependent with most samples showing minimal effects. Conclusions and clinical relevance The extent of processing‐induced changes and the benefit of PI addition are patient‐ and sample‐dependent. A consistent processing methodology is essential within a study to avoid any confounding of the results. PMID:25400092

  4. Braze Process Optimization Involving Conventional Metal/Ceramic Brazing with 50Au-50Cu Alloy

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    MALIZIA JR.,LOUIS A.; MEREDITH,KEITH W.; APPEL,DANIEL B.

    1999-12-15

    Numerous process variables can influence the robustness of conventional metal/ceramic brazing processes. Experience with brazing of hermetic vacuum components has identified the following parameters as influencing the outcome of hydrogen furnace brazed Kovar{trademark} to metallized alumina braze joints: (a) Mo-Mn metallization thickness, sinter fire temperature and porosity (b) Nil plate purity, thickness, and sinter firing conditions (c) peak process temperature, time above liquidus and (d) braze alloy washer thickness. ASTM F19 tensile buttons are being used to investigate the above parameters. The F19 geometry permits determination of both joint hermeticity and tensile strength. This presentation will focus on important lessonsmore » learned from the tensile button study: (A) the position of the Kovar{trademark} interlayer can influence the joint tensile strength achieved--namely, off-center interlayers can lead to residual stress development in the ceramic and degrade tensile strength values. Finite element analysis has been used to demonstrate the expected magnitude in strength degradation as a function of misalignment. (B) Time above liquidus (TAL) and peak temperature can influence the strength and alloying level of the resulting braze joint. Excessive TAL or peak temperatures can lead to overbraze conditions where all of the Ni plate is dissolved. (C) Metallize sinter fire processes can influence the morphology and strength obtained from the braze joints.« less

  5. Spatial and Temporal Variabilities of Solar and Longwave Radiation Fluxes below a Coniferous Forest in the French Alps

    NASA Astrophysics Data System (ADS)

    Sicart, J. E.; Ramseyer, V.; Lejeune, Y.; Essery, R.; Webster, C.; Rutter, N.

    2017-12-01

    At high altitudes and latitudes, snow has a large influence on hydrological processes. Large fractions of these regions are covered by forests, which have a strong influence on snow accumulation and melting processes. Trees absorb a large part of the incoming shortwave radiation and this heat load is mostly dissipated as longwave radiation. Trees shelter the snow surface from wind, so sub-canopy snowmelt depends mainly on the radiative fluxes: vegetation attenuates the transmission of shortwave radiation but enhances longwave irradiance to the surface. An array of 13 pyranometers and 11 pyrgeometers was deployed on the snow surface below a coniferous forest at the CEN-MeteoFrance Col de Porte station in the French Alps (1325 m asl) during the 2017 winter in order to investigate spatial and temporal variabilities of solar and infrared irradiances in different meteorological conditions. Sky view factors measured with hemispherical photographs at each radiometer location were in a narrow range from 0.2 to 0.3. The temperature of the vegetation was measured with IR thermocouples and an IR camera. In clear sky conditions, the attenuation of solar radiation by the canopy reached 96% and its spatial variability exceeded 100 W m-2. Longwave irradiance varied by 30 W m-2 from dense canopy to gap areas. In overcast conditions, the spatial variabilities of solar and infrared irradiances were reduced and remained closely related to the sky view factor. A simple radiative model taking into account the penetration through the canopy of the direct and diffuse solar radiation, and isotropic infrared emission of the vegetation as a blackbody emitter, accurately reproduced the dynamics of the radiation fluxes at the snow surface. Model results show that solar transmissivity of the canopy in overcast conditions is an excellent proxy of the sky view factor and the emitting temperature of the vegetation remained close to the air temperature in this typically dense Alpine forest.

  6. Drought and Snow: Analysis of Drivers, Processes and Impacts of Streamflow Droughts in Snow-Dominated Regions

    NASA Astrophysics Data System (ADS)

    Van Loon, Anne; Laaha, Gregor; Van Lanen, Henny; Parajka, Juraj; Fleig, Anne; Ploum, Stefan

    2016-04-01

    Around the world, drought events with severe socio-economic impacts seem to have a link with winter snowpack. That is the case for the current California drought, but analysing historical archives and drought impact databases for the US and Europe we found many impacts that can be attributed to snowpack anomalies. Agriculture and electricity production (hydropower) were found to be the sectors that are most affected by drought related to snow. In this study, we investigated the processes underlying hydrological drought in snow-dominated regions. We found that drought drivers are different in different regions. In Norway, more than 90% of spring streamflow droughts were preceded by below-average winter precipitation, while both winter air temperature and spring weather were indifferent. In Austria, however, spring streamflow droughts could only be explained by a combination of factors. For most events, winter and spring air temperatures were above average (70% and 65% of events, respectively), and winter and spring precipitation was below average (75% and 80%). Because snow storage results from complex interactions between precipitation and temperature and these variables vary strongly with altitude, snow-related drought drivers have a large spatial variability. The weather input is subsequently modified by land properties. Multiple linear regression between drought severity variables and a large number of catchment characteristics for 44 catchments in Austria showed that storage influences both drought duration and deficit volume. The seasonal storage of water in snow and glaciers was found to be a statistically important variable explaining streamflow drought deficit. Our drought impact analysis in Europe also showed that 40% of the selected drought impacts was caused by a combination of snow-related and other drought types. For example, the combination of a winter drought with a preceding or subsequent summer drought was reported to have a large effect on reservoir levels and, consequently, on drinking water and electricity production. Snow storage therefore, is an important factor to consider in drought monitoring, prediction and management.

  7. Drought and Snow: Analysis of Drivers, Processes and Impacts of Streamflow Droughts in Snow-Dominated Regions

    NASA Astrophysics Data System (ADS)

    Van Loon, A.; Laaha, G.; Van Lanen, H.; Parajka, J.; Fleig, A. K.; Ploum, S.

    2015-12-01

    Around the world, drought events with severe socio-economic impacts seem to have a link with winter snowpack. That is the case for the current California drought, but analysing historical archives and drought impact databases for the US and Europe we found many impacts that can be attributed to snowpack anomalies. Agriculture and electricity production (hydropower) were found to be the sectors that are most affected by drought related to snow. In this study, we investigated the processes underlying hydrological drought in snow-dominated regions. We found that drought drivers are different in different regions. In Norway, more than 90% of spring streamflow droughts were preceded by below-average winter precipitation, while both winter air temperature and spring weather were indifferent. In Austria, however, spring streamflow droughts could only be explained by a combination of factors. For most events, winter and spring air temperatures were above average (70% and 65% of events, respectively), and winter and spring precipitation was below average (75% and 80%). Because snow storage results from complex interactions between precipitation and temperature and these variables vary strongly with altitude, snow-related drought drivers have a large spatial variability. The weather input is subsequently modified by land properties. Multiple linear regression between drought severity variables and a large number of catchment characteristics for 44 catchments in Austria showed that storage influences both drought duration and deficit volume. The seasonal storage of water in snow and glaciers was found to be a statistically important variable explaining streamflow drought deficit. Our drought impact analysis in Europe also showed that 40% of the selected drought impacts was caused by a combination of snow-related and other drought types. For example, the combination of a winter drought with a preceding or subsequent summer drought was reported to have a large effect on reservoir levels and, consequently, on drinking water and electricity production. Snow storage therefore, is an important factor to consider in drought monitoring, prediction and management.

  8. Internal Physical Features of a Land Surface Model Employing a Tangent Linear Model

    NASA Technical Reports Server (NTRS)

    Yang, Runhua; Cohn, Stephen E.; daSilva, Arlindo; Joiner, Joanna; Houser, Paul R.

    1997-01-01

    The Earth's land surface, including its biomass, is an integral part of the Earth's weather and climate system. Land surface heterogeneity, such as the type and amount of vegetative covering., has a profound effect on local weather variability and therefore on regional variations of the global climate. Surface conditions affect local weather and climate through a number of mechanisms. First, they determine the re-distribution of the net radiative energy received at the surface, through the atmosphere, from the sun. A certain fraction of this energy increases the surface ground temperature, another warms the near-surface atmosphere, and the rest evaporates surface water, which in turn creates clouds and causes precipitation. Second, they determine how much rainfall and snowmelt can be stored in the soil and how much instead runs off into waterways. Finally, surface conditions influence the near-surface concentration and distribution of greenhouse gases such as carbon dioxide. The processes through which these mechanisms interact with the atmosphere can be modeled mathematically, to within some degree of uncertainty, on the basis of underlying physical principles. Such a land surface model provides predictive capability for surface variables including ground temperature, surface humidity, and soil moisture and temperature. This information is important for agriculture and industry, as well as for addressing fundamental scientific questions concerning global and local climate change. In this study we apply a methodology known as tangent linear modeling to help us understand more deeply, the behavior of the Mosaic land surface model, a model that has been developed over the past several years at NASA/GSFC. This methodology allows us to examine, directly and quantitatively, the dependence of prediction errors in land surface variables upon different vegetation conditions. The work also highlights the importance of accurate soil moisture information. Although surface variables are predicted imperfectly due to inherent uncertainties in the modeling process, our study suggests how satellite observations can be combined with the model, through land surface data assimilation, to improve their prediction.

  9. Analyte stability during the total testing process: studies of vitamins A, D and E by LC-MS/MS.

    PubMed

    Albahrani, Ali A; Rotarou, Victor; Roche, Peter J; Greaves, Ronda F

    2016-10-01

    There are limited evidence based studies demonstrating the stability of fat-soluble vitamins (FSV) measured in blood. This study aimed to examine the effects of light, temperature and time on vitamins A, D and E throughout the total testing process. Four experiments were conducted. Three investigated the sample matrix, of whole blood, serum and the extracted sample, against the variables of temperature and light; and the fourth experiment investigated the sample during the extraction process against the variable of light. All samples were analysed via our simultaneous FSV method using liquid chromatography-tandem mass spectrometry technology. The allowable clinical percentage change was calculated based on biological variation and desirable method imprecision for each analyte. The total change limit was ±7.3% for 25-OH-vitamin D3, ±11.8% for retinol and ±10.8% for α-tocopherol. Vitamins D and E were stable in the investigated conditions (concentration changes <4%) in the pre-analytical and analytical stages. Vitamin A showed photosensitivity in times >48 h with concentration changes of -6.8% (blood) and -6.5% (serum), both are within the allowable clinical percentage change. By contrast, the extracted retinol sample demonstrated a concentration change of -18.4% after 48 h of light exposure. However, vitamin A in the serum and extracted solution was stable for one month when stored at -20°C. Blood samples for vitamins D and E analyses can be processed in normal laboratory conditions of lighting and temperature. The required conditions for vitamin A analysis are similar when performed within 48 h. For longer-term storage, serum and vitamin A extracts should be stored at -20°C.

  10. Effect of Temperature on Heart Rate Variability in Neonatal ICU Patients With Hypoxic-Ischemic Encephalopathy.

    PubMed

    Massaro, An N; Campbell, Heather E; Metzler, Marina; Al-Shargabi, Tareq; Wang, Yunfei; du Plessis, Adre; Govindan, Rathinaswamy B

    2017-04-01

    To determine whether measures of heart rate variability are related to changes in temperature during rewarming after therapeutic hypothermia for hypoxic-ischemic encephalopathy. Prospective observational study. Level 4 neonatal ICU in a free-standing academic children's hospital. Forty-four infants with moderate to severe hypoxic-ischemic encephalopathy treated with therapeutic hypothermia. Continuous electrocardiogram data from 2 hours prior to rewarming through 2 hours after completion of rewarming (up to 10 hr) were analyzed. Median beat-to-beat interval and measures of heart rate variability were quantified including beat-to-beat interval SD, low and high frequency relative spectral power, detrended fluctuation analysis short and long α exponents (αS and αL), and root mean square short and long time scales. The relationships between heart rate variability measures and esophageal/axillary temperatures were evaluated. Heart rate variability measures low frequency, αS, and root mean square short and long time scales were negatively associated, whereas αL was positively associated, with temperature (p < 0.01). These findings signify an overall decrease in heart rate variability as temperature increased toward normothermia. Measures of heart rate variability are temperature dependent in the range of therapeutic hypothermia to normothermia. Core body temperature needs to be considered when evaluating heart rate variability metrics as potential physiologic biomarkers of illness severity in hypoxic-ischemic encephalopathy infants undergoing therapeutic hypothermia.

  11. Spatial variability in plankton biomass and hydrographic variables along an axial transect in Chesapeake Bay

    NASA Astrophysics Data System (ADS)

    Zhang, X.; Roman, M.; Kimmel, D.; McGilliard, C.; Boicourt, W.

    2006-05-01

    High-resolution, axial sampling surveys were conducted in Chesapeake Bay during April, July, and October from 1996 to 2000 using a towed sampling device equipped with sensors for depth, temperature, conductivity, oxygen, fluorescence, and an optical plankton counter (OPC). The results suggest that the axial distribution and variability of hydrographic and biological parameters in Chesapeake Bay were primarily influenced by the source and magnitude of freshwater input. Bay-wide spatial trends in the water column-averaged values of salinity were linear functions of distance from the main source of freshwater, the Susquehanna River, at the head of the bay. However, spatial trends in the water column-averaged values of temperature, dissolved oxygen, chlorophyll-a and zooplankton biomass were nonlinear along the axis of the bay. Autocorrelation analysis and the residuals of linear and quadratic regressions between each variable and latitude were used to quantify the patch sizes for each axial transect. The patch sizes of each variable depended on whether the data were detrended, and the detrending techniques applied. However, the patch size of each variable was generally larger using the original data compared to the detrended data. The patch sizes of salinity were larger than those for dissolved oxygen, chlorophyll-a and zooplankton biomass, suggesting that more localized processes influence the production and consumption of plankton. This high-resolution quantification of the zooplankton spatial variability and patch size can be used for more realistic assessments of the zooplankton forage base for larval fish species.

  12. The effect of temperature on amount and structure of motor variability during 2-minute maximum voluntary contraction.

    PubMed

    Brazaitis, Marius; Skurvydas, Albertas; Pukėnas, Kazimieras; Daniuseviciūtė, Laura; Mickevicienė, Dalia; Solianik, Rima

    2012-11-01

    In this study, we questioned whether local cooling of muscle or heating involving core and muscle temperatures are the main indicators for force variability. Ten volunteers performed a 2-min maximum voluntary contraction (MVC) of the knee extensors under control (CON) conditions after passive heating (HT) and cooling (CL) of the lower body. HT increased muscle and rectal temperatures, whereas CL lowered muscle temperature but did not affect rectal temperature. During 2-min MVC, peak force decreased to a lower level in HT compared with CON and CL experiments. Greater central fatigue was found in the HT experiment, and there was less in the CL experiment than in the CON experiment. Increased core and muscle temperature increased physiological tremor and the amount and structural complexity of force variability of the exercising muscles, whereas local muscle cooling decreased all force variability variables measured. Copyright © 2012 Wiley Periodicals, Inc.

  13. Tannat grape composition responses to spatial variability of temperature in an Uruguay's coastal wine region

    NASA Astrophysics Data System (ADS)

    Fourment, Mercedes; Ferrer, Milka; González-Neves, Gustavo; Barbeau, Gérard; Bonnardot, Valérie; Quénol, Hervé

    2017-09-01

    Spatial variability of temperature was studied in relation to the berry basic composition and secondary compounds of the Tannat cultivar at harvest from vineyards located in Canelones and Montevideo, the most important wine region of Uruguay. Monitoring of berries and recording of temperature were performed in 10 commercial vineyards of Tannat situated in the southern coastal wine region of the country for three vintages (2012, 2013, and 2014). Results from a multivariate correlation analysis between berry composition and temperature over the three vintages showed that (1) Tannat responses to spatial variability of temperature were different over the vintages, (2) correlations between secondary metabolites and temperature were higher than those between primary metabolites, and (3) correlation values between berry composition and climate variables increased when ripening occurred under dry conditions (below average rainfall). For a particular studied vintage (2013), temperatures explained 82.5% of the spatial variability of the berry composition. Daily thermal amplitude was found to be the most important spatial mode of variability with lower values recorded at plots nearest to the sea and more exposed to La Plata River. The highest levels in secondary compounds were found in berries issued from plots situated as far as 18.3 km from La Plata River. The increasing knowledge of temperature spatial variability and its impact on grape berry composition contributes to providing possible issues to adapt grapevine to climate change.

  14. Thermo-Mechanical Processing in Friction Stir Welds

    NASA Technical Reports Server (NTRS)

    Schneider, Judy

    2003-01-01

    Friction stir welding is a solid-phase joining, or welding process that was invented in 1991 at The Welding Institute (TWI). The process is potentially capable of joining a wide variety of aluminum alloys that are traditionally difficult to fusion weld. The friction stir welding (FSW) process produces welds by moving a non-consumable rotating pin tool along a seam between work pieces that are firmly clamped to an anvil. At the start of the process, the rotating pin is plunged into the material to a pre-determined load. The required heat is produced by a combination of frictional and deformation heating. The shape of the tool shoulder and supporting anvil promotes a high hydrostatic pressure along the joint line as the tool shears and literally stirs the metal together. To produce a defect free weld, process variables (RPM, transverse speed, and downward force) and tool pin design must be chosen carefully. An accurate model of the material flow during the process is necessary to guide process variable selection. At MSFC a plastic slip line model of the process has been synthesized based on macroscopic images of the resulting weld material. Although this model appears to have captured the main features of the process, material specific interactions are not understood. The objective of the present research was to develop a basic understanding of the evolution of the microstructure to be able to relate it to the deformation process variables of strain, strain rate, and temperature.

  15. Analysis of close-contact melting with inner wall temperature variation in a horizontal cylindrical capsule

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Saitoh, T.S.; Hoshi, Akira

    1997-12-31

    Melting and solidification of a phase change material (PCM) in a capsule is of practical importance in latent heat thermal energy storage (LHTES) systems which are considered to be very promising to reduce a peak demand of electricity in the summer season. Two melting modes are involved in melting in capsules. One is close-contact melting between the solid bulk and the capsule wall, and another is natural convection melting in the liquid region. In recent years, close-contact melting processes for a single enclosure have been solved using several numerical methods (e.g., Saitoh and Kato (1994)). However, there is no theoreticalmore » solution considering the inner wall temperature variation within cylindrical or spherical capsules. In this report close-contact melting heat transfer characteristics including melt flow in the liquid film under inner wall temperature distribution were analyzed and simple approximate equations are presented, which facilitates designing of the practical capsule bed LHTES systems. The effects of Stefan number and variable temperature profile etc. were clarified in detail. And the melting velocity of the solid bulk under various conditions was also studied theoretically. In addition, the effects of variable inner wall temperature on molten mass fraction were investigated.« less

  16. A self-organized criticality model for ion temperature gradient mode driven turbulence in confined plasma

    NASA Astrophysics Data System (ADS)

    Isliker, H.; Pisokas, Th.; Strintzi, D.; Vlahos, L.

    2010-08-01

    A new self-organized criticality (SOC) model is introduced in the form of a cellular automaton (CA) for ion temperature gradient (ITG) mode driven turbulence in fusion plasmas. Main characteristics of the model are that it is constructed in terms of the actual physical variable, the ion temperature, and that the temporal evolution of the CA, which necessarily is in the form of rules, mimics actual physical processes as they are considered to be active in the system, i.e., a heating process and a local diffusive process that sets on if a threshold in the normalized ITG R /LT is exceeded. The model reaches the SOC state and yields ion temperature profiles of exponential shape, which exhibit very high stiffness, in that they basically are independent of the loading pattern applied. This implies that there is anomalous heat transport present in the system, despite the fact that diffusion at the local level is imposed to be of a normal kind. The distributions of the heat fluxes in the system and of the heat out-fluxes are of power-law shape. The basic properties of the model are in good qualitative agreement with experimental results.

  17. Thermochemical recovery of heat contained in flue gases by means of bioethanol conversion

    NASA Astrophysics Data System (ADS)

    Pashchenko, D. I.

    2013-06-01

    In the present paper consideration is being given to the use of bioethanol in the schemes of thermochemical recovery of heat contained in exit flue gases. Schematic diagrams illustrate the realization of thermochemical heat recovery by implementing ethanol steam conversion and conversion of ethanol by means of products of its complete combustion. The feasibility of attaining a high degree of recovery of heat contained in flue gases at the moderate temperature (up to 450°C) of combustion components is demonstrated in the example of the energy balance of the system for thermochemical heat recovery. The simplified thermodynamic analysis of the process of ethanol steam conversion was carried out in order to determine possible ranges of variation of process variables (temperature, pressure, composition) of a reaction mixture providing the efficient heat utilization. It was found that at the temperature above 600 K the degree of ethanol conversion is near unity. The equilibrium composition of products of reaction of ethanol steam conversion has been identified for different temperatures at which the process occurs at the ratio H2O/EtOH = 1 and at the pressure of 0.1 MPa. The obtained results of calculation agree well with the experimental data.

  18. Enzyme reactor design under thermal inactivation.

    PubMed

    Illanes, Andrés; Wilson, Lorena

    2003-01-01

    Temperature is a very relevant variable for any bioprocess. Temperature optimization of bioreactor operation is a key aspect for process economics. This is especially true for enzyme-catalyzed processes, because enzymes are complex, unstable catalysts whose technological potential relies on their operational stability. Enzyme reactor design is presented with a special emphasis on the effect of thermal inactivation. Enzyme thermal inactivation is a very complex process from a mechanistic point of view. However, for the purpose of enzyme reactor design, it has been oversimplified frequently, considering one-stage first-order kinetics of inactivation and data gathered under nonreactive conditions that poorly represent the actual conditions within the reactor. More complex mechanisms are frequent, especially in the case of immobilized enzymes, and most important is the effect of catalytic modulators (substrates and products) on enzyme stability under operation conditions. This review focuses primarily on reactor design and operation under modulated thermal inactivation. It also presents a scheme for bioreactor temperature optimization, based on validated temperature-explicit functions for all the kinetic and inactivation parameters involved. More conventional enzyme reactor design is presented merely as a background for the purpose of highlighting the need for a deeper insight into enzyme inactivation for proper bioreactor design.

  19. Temporal changes in climatic variables and their impact on crop yields in southwestern China

    NASA Astrophysics Data System (ADS)

    Liu, Hong-Bin; Gou, Yu; Wang, Hong-Ye; Li, Hong-Mei; Wu, Wei

    2014-08-01

    Knowledge of variability in climatic variables changes and its impact on crop yields is important for farmers and policy makers, especially in southwestern China where rainfed agriculture is dominant. In the current study, six climatic parameters (mean temperature, rainfall, relative humidity, sunshine hours, temperature difference, and rainy days) and aggregated yields of three main crops (rice: Oryza sativa L., oilseed rape: Brassica napus L., and tobacco: Nicotiana tabacum L.) during 1985-2010 were collected and analyzed for Chongqing—a large agricultural municipality of China. Climatic variables changes were detected by Mann-Kendall test. Increased mean temperature and temperature difference and decreased relative humidity were found in annual and oilseed rape growth time series ( P < 0.05). Increased sunshine hours were observed during the oilseed rape growth period ( P < 0.05). Rainy days decreased slightly in annual and oilseed rape growth time series ( P < 0.10). Correlation analysis showed that yields of all three crops could benefit from changes in climatic variables in this region. Yield of rice increased with rainfall ( P < 0.10). Yield of oilseed rape increased with mean temperature and temperature difference but decreased with relative humidity ( P < 0.01). Tobacco yield increased with mean temperature ( P < 0.05). Path analysis provided additional information about the importance and contribution paths of climatic variables to crop yields. Temperature difference and sunshine hours had higher direct and indirect effects via other climatic variables on yields of rice and tobacco. Mean temperature, relative humidity, rainy days, and temperature difference had higher direct and indirect effects via others on yield of oilseed rape.

  20. Temporal changes in climatic variables and their impact on crop yields in southwestern China.

    PubMed

    Liu, Hong-Bin; Gou, Yu; Wang, Hong-Ye; Li, Hong-Mei; Wu, Wei

    2014-08-01

    Knowledge of variability in climatic variables changes and its impact on crop yields is important for farmers and policy makers, especially in southwestern China where rainfed agriculture is dominant. In the current study, six climatic parameters (mean temperature, rainfall, relative humidity, sunshine hours, temperature difference, and rainy days) and aggregated yields of three main crops (rice: Oryza sativa L., oilseed rape: Brassica napus L., and tobacco: Nicotiana tabacum L.) during 1985-2010 were collected and analyzed for Chongqing-a large agricultural municipality of China. Climatic variables changes were detected by Mann-Kendall test. Increased mean temperature and temperature difference and decreased relative humidity were found in annual and oilseed rape growth time series (P<0.05). Increased sunshine hours were observed during the oilseed rape growth period (P<0.05). Rainy days decreased slightly in annual and oilseed rape growth time series (P<0.10). Correlation analysis showed that yields of all three crops could benefit from changes in climatic variables in this region. Yield of rice increased with rainfall (P<0.10). Yield of oilseed rape increased with mean temperature and temperature difference but decreased with relative humidity (P<0.01). Tobacco yield increased with mean temperature (P<0.05). Path analysis provided additional information about the importance and contribution paths of climatic variables to crop yields. Temperature difference and sunshine hours had higher direct and indirect effects via other climatic variables on yields of rice and tobacco. Mean temperature, relative humidity, rainy days, and temperature difference had higher direct and indirect effects via others on yield of oilseed rape.

  1. Application of Plackett-Burman experimental design in the development of muffin using adlay flour

    NASA Astrophysics Data System (ADS)

    Valmorida, J. S.; Castillo-Israel, K. A. T.

    2018-01-01

    The application of Plackett-Burman experimental design was made to identify significant formulation and process variables in the development of muffin using adlay flour. Out of the seven screened variables, levels of sugar, levels of butter and baking temperature had the most significant influence on the product model in terms of physicochemical and sensory acceptability. Results of the experiment further demonstrate the effectiveness of Plackett-Burman design in choosing the best adlay variety for muffin production. Hence, the statistical method used in the study permits an efficient selection of important variables needed in the development of muffin from adlay which can be optimized using response surface methodology.

  2. Temperature variability during delirium in ICU patients: an observational study.

    PubMed

    van der Kooi, Arendina W; Kappen, Teus H; Raijmakers, Rosa J; Zaal, Irene J; Slooter, Arjen J C

    2013-01-01

    Delirium is an acute disturbance of consciousness and cognition. It is a common disorder in the intensive care unit (ICU) and associated with impaired long-term outcome. Despite its frequency and impact, delirium is poorly recognized by ICU-physicians and -nurses using delirium screening tools. A completely new approach to detect delirium is to use monitoring of physiological alterations. Temperature variability, a measure for temperature regulation, could be an interesting component to monitor delirium, but whether temperature regulation is different during ICU delirium has not yet been investigated. The aim of this study was to investigate whether ICU delirium is related to temperature variability. Furthermore, we investigated whether ICU delirium is related to absolute body temperature. We included patients who experienced both delirium and delirium free days during ICU stay, based on the Confusion Assessment method for the ICU conducted by a research- physician or -nurse, in combination with inspection of medical records. We excluded patients with conditions affecting thermal regulation or therapies affecting body temperature. Daily temperature variability was determined by computing the mean absolute second derivative of the temperature signal. Temperature variability (primary outcome) and absolute body temperature (secondary outcome) were compared between delirium- and non-delirium days with a linear mixed model and adjusted for daily mean Richmond Agitation and Sedation Scale scores and daily maximum Sequential Organ Failure Assessment scores. Temperature variability was increased during delirium-days compared to days without delirium (β(unadjuste)d=0.007, 95% confidence interval (CI)=0.004 to 0.011, p<0.001). Adjustment for confounders did not alter this result (β(adjusted)=0.005, 95% CI=0.002 to 0.008, p<0.001). Delirium was not associated with absolute body temperature (β(unadjusted)=-0.03, 95% CI=-0.17 to 0.10, p=0.61). This did not change after adjusting for confounders (β(adjusted)=-0.03, 95% CI=-0.17 to 0.10, p=0.63). Our study suggests that temperature variability is increased during ICU delirium.

  3. Challenges in Melt Furnace Tests

    NASA Astrophysics Data System (ADS)

    Belt, Cynthia

    2014-09-01

    Measurement is a critical part of running a cast house. Key performance indicators such as energy intensity, production (or melt rate), downtime (or OEE), and melt loss must all be understood and monitored on a weekly or monthly basis. Continuous process variables such as bath temperature, flue temperature, and furnace pressure should be used to control the furnace systems along with storing the values in databases for later analysis. While using measurement to track furnace performance over time is important, there is also a time and place for short-term tests.

  4. Satellite based assessment of recent permafrost extent and active layer trends over Alaska and Northwest Canada

    NASA Astrophysics Data System (ADS)

    Kim, Y.; Kimball, J. S.; PARK, H.; Yi, Y.

    2017-12-01

    Climate change in the Boreal-Arctic region has experienced greater surface air temperature (SAT) warming than the global average in recent decades, which is promoting permafrost thawing and active layer deepening. Permafrost extent (PE) and active layer thickness (ALT) are key environmental indicators of recent climate change, and strongly impact other eco-hydrological processes including land-atmosphere carbon exchange. We developed a new approach for regional estimation and monitoring of PE using daily landscape freeze-thaw (FT) records derived from satellite microwave (37 GHz) brightness temperature (Tb) observations. ALT was estimated within the PE domain using empirical modeling of land cover dependent edaphic factors and an annual thawing index derived from MODIS land surface temperature (LST) observations and reanalysis based surface air temperatures (SAT). The PE and ALT estimates were derived over the 1980-2016 satellite record and NASA ABoVE (Arctic Boreal Vulnerability Experiment) domain encompassing Alaska and Northwest Canada. The baseline model estimates were derived at 25-km resolution consistent with the satellite FT global record. Our results show recent widespread PE decline and deepening ALT trends, with larger spatial variability and model uncertainty along the southern PE boundary. Larger PE and ALT variability occurs over heterogeneous permafrost subzones characterized by dense vegetation, and variable snow cover and organic layer conditions. We also tested alternative PE and ALT estimates derived using finer (6-km) scale satellite Tb (36.5 GHz) and FT retrievals from a calibrated AMSR-E and AMSR2 sensor record. The PE and ALT results were compared against other independent observations, including process model simulations, in situ measurements, and permafrost inventory records. A model sensitivity analysis was conducted to evaluate snow cover, soil organic layer, and vegetation composition impacts to ALT. The finer delineation of permafrost and active layer conditions provides enhanced regional monitoring of PE and ALT changes over the ABoVE domain, including heterogeneous permafrost subzones.

  5. Meteorological and snow distribution data in the Izas Experimental Catchment (Spanish Pyrenees) from 2011 to 2017

    NASA Astrophysics Data System (ADS)

    Revuelto, Jesús; Azorin-Molina, Cesar; Alonso-González, Esteban; Sanmiguel-Vallelado, Alba; Navarro-Serrano, Francisco; Rico, Ibai; López-Moreno, Juan Ignacio

    2017-12-01

    This work describes the snow and meteorological data set available for the Izas Experimental Catchment in the Central Spanish Pyrenees, from the 2011 to 2017 snow seasons. The experimental site is located on the southern side of the Pyrenees between 2000 and 2300 m above sea level, covering an area of 55 ha. The site is a good example of a subalpine environment in which the evolution of snow accumulation and melt are of major importance in many mountain processes. The climatic data set consists of (i) continuous meteorological variables acquired from an automatic weather station (AWS), (ii) detailed information on snow depth distribution collected with a terrestrial laser scanner (TLS, lidar technology) for certain dates across the snow season (between three and six TLS surveys per snow season) and (iii) time-lapse images showing the evolution of the snow-covered area (SCA). The meteorological variables acquired at the AWS are precipitation, air temperature, incoming and reflected solar radiation, infrared surface temperature, relative humidity, wind speed and direction, atmospheric air pressure, surface temperature (snow or soil surface), and soil temperature; all were taken at 10 min intervals. Snow depth distribution was measured during 23 field campaigns using a TLS, and daily information on the SCA was also retrieved from time-lapse photography. The data set (https://doi.org/10.5281/zenodo.848277) is valuable since it provides high-spatial-resolution information on the snow depth and snow cover, which is particularly useful when combined with meteorological variables to simulate snow energy and mass balance. This information has already been analyzed in various scientific studies on snow pack dynamics and its interaction with the local climatology or topographical characteristics. However, the database generated has great potential for understanding other environmental processes from a hydrometeorological or ecological perspective in which snow dynamics play a determinant role.

  6. Distributed snow modeling suitable for use with operational data for the American River watershed.

    NASA Astrophysics Data System (ADS)

    Shamir, E.; Georgakakos, K. P.

    2004-12-01

    The mountainous terrain of the American River watershed (~4300 km2) at the Western slope of the Northern Sierra Nevada is subject to significant variability in the atmospheric forcing that controls the snow accumulation and ablations processes (i.e., precipitation, surface temperature, and radiation). For a hydrologic model that attempts to predict both short- and long-term streamflow discharges, a plausible description of the seasonal and intermittent winter snow pack accumulation and ablation is crucial. At present the NWS-CNRFC operational snow model is implemented in a semi distributed manner (modeling unit of about 100-1000 km2) and therefore lump distinct spatial variability of snow processes. In this study we attempt to account for the precipitation, temperature, and radiation spatial variability by constructing a distributed snow accumulation and melting model suitable for use with commonly available sparse data. An adaptation of the NWS-Snow17 energy and mass balance that is used operationally at the NWS River Forecast Centers is implemented at 1 km2 grid cells with distributed input and model parameters. The input to the model (i.e., precipitation and surface temperature) is interpolated from observed point data. The surface temperature was interpolated over the basin based on adiabatic lapse rates using topographic information whereas the precipitation was interpolated based on maps of climatic mean annual rainfall distribution acquired from PRISM. The model parameters that control the melting rate due to radiation were interpolated based on aspect. The study was conducted for the entire American basin for the snow seasons of 1999-2000. Validation of the Snow Water Equivalent (SWE) prediction is done by comparing to observation from 12 snow Sensors. The Snow Cover Area (SCA) prediction was evaluated by comparing to remotely sensed 500m daily snow cover derived from MODIS. The results that the distribution of snow over the area is well captured and the quantity compared to the snow gauges are well estimated in the high elevation.

  7. Infrared Sensor-Based Temperature Control for Domestic Induction Cooktops

    PubMed Central

    Lasobras, Javier; Alonso, Rafael; Carretero, Claudio; Carretero, Enrique; Imaz, Eduardo

    2014-01-01

    In this paper, a precise real-time temperature control system based on infrared (IR) thermometry for domestic induction cooking is presented. The temperature in the vessel constitutes the control variable of the closed-loop power control system implemented in a commercial induction cooker. A proportional-integral controller is applied to establish the output power level in order to reach the target temperature. An optical system and a signal conditioning circuit have been implemented. For the signal processing a microprocessor with 12-bit ADC and a sampling rate of 1 Ksps has been used. The analysis of the contributions to the infrared radiation permits the definition of a procedure to estimate the temperature of the vessel with a maximum temperature error of 5 °C in the range between 60 and 250 °C for a known cookware emissivity. A simple and necessary calibration procedure with a black-body sample is presented. PMID:24638125

  8. Infrared sensor-based temperature control for domestic induction cooktops.

    PubMed

    Lasobras, Javier; Alonso, Rafael; Carretero, Claudio; Carretero, Enrique; Imaz, Eduardo

    2014-03-14

    In this paper, a precise real-time temperature control system based on infrared (IR) thermometry for domestic induction cooking is presented. The temperature in the vessel constitutes the control variable of the closed-loop power control system implemented in a commercial induction cooker. A proportional-integral controller is applied to establish the output power level in order to reach the target temperature. An optical system and a signal conditioning circuit have been implemented. For the signal processing a microprocessor with 12-bit ADC and a sampling rate of 1 Ksps has been used. The analysis of the contributions to the infrared radiation permits the definition of a procedure to estimate the temperature of the vessel with a maximum temperature error of 5 °C in the range between 60 and 250 °C for a known cookware emissivity. A simple and necessary calibration procedure with a black-body sample is presented.

  9. Processing-Structure-Property Relationships for Lignin-Based Carbonaceous Materials Used in Energy-Storage Applications

    DOE PAGES

    García-Negrón, Valerie; Phillip, Nathan D.; Li, Jianlin; ...

    2016-11-18

    Lignin, an abundant organic polymer and a byproduct of pulp and biofuel production, has potential applications owing to its high carbon content and aromatic structure. Processing structure relationships are difficult to predict because of the heterogeneity of lignin. Here, this work discusses the roles of unit operations in the carbonization process of softwood lignin, and their resulting impacts on the material structure and electrochemical properties in application as the anode in lithium-ion cells. The processing variables include the lignin source, temperature, and duration of thermal stabilization, pyrolysis, and reduction. Materials are characterized at the atomic and microscales. High-temperature carbonization, atmore » 2000 °C, produces larger graphitic domains than at 1050 °C, but results in a reduced capacity. Coulombic efficiencies over 98 % are achieved for extended galvanostatic cycling. Consequently, a properly designed carbonization process for lignin is well suited for the generation of low-cost, high-efficiency electrodes.« less

  10. Absence of 21st century warming on Antarctic Peninsula consistent with natural variability.

    PubMed

    Turner, John; Lu, Hua; White, Ian; King, John C; Phillips, Tony; Hosking, J Scott; Bracegirdle, Thomas J; Marshall, Gareth J; Mulvaney, Robert; Deb, Pranab

    2016-07-21

    Since the 1950s, research stations on the Antarctic Peninsula have recorded some of the largest increases in near-surface air temperature in the Southern Hemisphere. This warming has contributed to the regional retreat of glaciers, disintegration of floating ice shelves and a 'greening' through the expansion in range of various flora. Several interlinked processes have been suggested as contributing to the warming, including stratospheric ozone depletion, local sea-ice loss, an increase in westerly winds, and changes in the strength and location of low-high-latitude atmospheric teleconnections. Here we use a stacked temperature record to show an absence of regional warming since the late 1990s. The annual mean temperature has decreased at a statistically significant rate, with the most rapid cooling during the Austral summer. Temperatures have decreased as a consequence of a greater frequency of cold, east-to-southeasterly winds, resulting from more cyclonic conditions in the northern Weddell Sea associated with a strengthening mid-latitude jet. These circulation changes have also increased the advection of sea ice towards the east coast of the peninsula, amplifying their effects. Our findings cover only 1% of the Antarctic continent and emphasize that decadal temperature changes in this region are not primarily associated with the drivers of global temperature change but, rather, reflect the extreme natural internal variability of the regional atmospheric circulation.

  11. Extremophiles in Mineral Sulphide Heaps: Some Bacterial Responses to Variable Temperature, Acidity and Solution Composition

    PubMed Central

    Watling, Helen R.; Shiers, Denis W.; Collinson, David M.

    2015-01-01

    In heap bioleaching, acidophilic extremophiles contribute to enhanced metal extraction from mineral sulphides through the oxidation of Fe(II) and/or reduced inorganic sulphur compounds (RISC), such as elemental sulphur or mineral sulphides, or the degradation of organic compounds derived from the ore, biota or reagents used during mineral processing. The impacts of variable solution acidity and composition, as well as temperature on the three microbiological functions have been examined for up to four bacterial species found in mineral sulphide heaps. The results indicate that bacteria adapt to sufficiently high metal concentrations (Cu, Ni, Co, Zn, As) to allow them to function in mineral sulphide heaps and, by engaging alternative metabolic pathways, to extend the solution pH range over which growth is sustained. Fluctuating temperatures during start up in sulphide heaps pose the greatest threat to efficient bacterial colonisation. The large masses of ores in bioleaching heaps mean that high temperatures arising from sulphide oxidation are hard to control initially, when the sulphide content of the ore is greatest. During that period, mesophilic and moderately thermophilic bacteria are markedly reduced in both numbers and activity. PMID:27682094

  12. A STATE-VARIABLE APPROACH FOR PREDICTING THE TIME REQUIRED FOR 50% RECRYSTALLIZATION

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    M. STOUT; ET AL

    2000-08-01

    It is important to be able to model the recrystallization kinetics in aluminum alloys during hot deformation. The industrial relevant process of hot rolling is an example of where the knowledge of whether or not a material recrystallizes is critical to making a product with the correct properties. Classically, the equations that describe the kinetics of recrystallization predict the time to 50% recrystallization. These equations are largely empirical; they are based on the free energy for recrystallization, a Zener-Holloman parameter, and have several adjustable exponents to fit the equation to engineering data. We have modified this form of classical theorymore » replacing the Zener-Hollomon parameter with a deformation energy increment, a free energy available to drive recrystallization. The advantage of this formulation is that the deformation energy increment is calculated based on the previously determined temperature and strain-rate sensitivity of the constitutive response. We modeled the constitutive response of the AA5182 aluminum using a state variable approach, the value of the state variable is a function of the temperature and strain-rate history of deformation. Thus, the recrystallization kinetics is a function of only the state variable and free energy for recrystallization. There are no adjustable exponents as in classical theory. Using this approach combined with engineering recrystallization data we have been able to predict the kinetics of recrystallization in AA5182 as a function of deformation strain rate and temperature.« less

  13. Comparing maps of mean monthly surface temperature and precipitation for Alaska and adjacent areas of Canada produced by two different methods

    USGS Publications Warehouse

    Simpson, James J.; Hufford, Gary L.; Daly, Christopher; Berg, Jared S.; Fleming, Michael D.

    2005-01-01

    Maps of mean monthly surface temperature and precipitation for Alaska and adjacent areas of Canada, produced by Oregon State University's Spatial Climate Analysis Service (SCAS) and the Alaska Geospatial Data Clearinghouse (AGDC), were analyzed. Because both sets of maps are generally available and in use by the community, there is a need to document differences between the processes and input data sets used by the two groups to produce their respective set of maps and to identify similarities and differences between the two sets of maps and possible reasons for the differences. These differences do not affect the observed large-scale patterns of seasonal and annual variability. Alaska is divided into interior and coastal zones, with consistent but different variability, separated by a transition region. The transition region has high interannual variability but low long-term mean variability. Both data sets support the four major ecosystems and ecosystem transition zone identified in our earlier work. Differences between the two sets of maps do occur, however, on the regional scale; they reflect differences in physiographic domains and in the treatment of these domains by the two groups (AGDC, SCAS). These differences also provide guidance for an improved observational network for Alaska. On the basis of validation with independent in situ data, we conclude that the data set produced by SCAS provides the best spatial coverage of Alaskan long-term mean monthly surface temperature and precipitation currently available. ?? The Arctic Institute of North America.

  14. NASA/MSFC FY92 Earth Science and Applications Program Research Review

    NASA Technical Reports Server (NTRS)

    Arnold, James E. (Editor); Leslie, Fred W. (Editor)

    1993-01-01

    A large amount of attention has recently been given to global issues such as the ozone hole, tropospheric temperature variability, etc. A scientific challenge is to better understand atmospheric processes on a variety of spatial and temporal scales in order to predict environmental changes. Measurement of geophysical parameters such as wind, temperature, and moisture are needed to validate theories, provide analyzed data sets, and initialize or constrain numerical models. One of NASA's initiatives is the Mission to Planet Earth Program comprised of an Earth Observation System (EOS) and the scientific strategy to analyze these data. This work describes these efforts in the context of satellite data analysis and fundamental studies of atmospheric dynamics which examine selected processes important to the global circulation.

  15. Application of response surface methodology (RSM) and genetic algorithm in minimizing warpage on side arm

    NASA Astrophysics Data System (ADS)

    Raimee, N. A.; Fathullah, M.; Shayfull, Z.; Nasir, S. M.; Hazwan, M. H. M.

    2017-09-01

    The plastic injection moulding process produces large numbers of parts of high quality with great accuracy and quickly. It has widely used for production of plastic part with various shapes and geometries. Side arm is one of the product using injection moulding to manufacture it. However, there are some difficulties in adjusting the parameter variables which are mould temperature, melt temperature, packing pressure, packing time and cooling time as there are warpage happen at the tip part of side arm. Therefore, the work reported herein is about minimizing warpage on side arm product by optimizing the process parameter using Response Surface Methodology (RSM) and with additional artificial intelligence (AI) method which is Genetic Algorithm (GA).

  16. Formability analysis of austenitic stainless steel-304 under warm conditions

    NASA Astrophysics Data System (ADS)

    Lade, Jayahari; Singh, Swadesh Kumar; Banoth, Balu Naik; Gupta, Amit Kumar

    2013-12-01

    A warm deep drawing process of austenitic stainless steel-304 (ASS-304) of circular blanks with coupled ther mal analysis is studied in this article. 65 mm blanks were deep drawn at different temperatures and thickness distribution is experimentally measured after cutting the drawn component into two halves. The process is simulated using explicit fin ite element code LS-DYNA. A Barlat 3 parameter model is used in the simulation, as the material is anisotropic up to 30 0°C. Material properties for the simulation are determined at different temperatures using a 5 T UTM coupled with a furn ace. In this analysis constant punch speed and variable blank holder force (BHF) is applied to draw cups without wrinkle.

  17. Constraining the thermal history of the North American Midcontinent Rift System using carbonate clumped isotopes and organic thermal maturity indices

    USGS Publications Warehouse

    Gallagher, Timothy M.; Sheldon, Nathan D.; Mauk, Jeffrey L.; Petersen, Sierra V.; Gueneli, Nur; Brocks, Jochen J.

    2017-01-01

    The Midcontinent Rift System (MRS) is a Late Mesoproterozoic (∼1.1 Ga) sequence of volcanic and sedimentary rocks exposed in the Lake Superior Region of North America. The MRS continues to be the focus of much research due to its economic mineral deposits as well as its archive of Precambrian life and tectonic processes. In order to constrain the post-depositional thermal history of the MRS, samples were analyzed for carbonate clumped isotope composition and organic thermal maturity. Clumped isotope values from sedimentary/early-diagenetic samples were partially reset during burial to temperatures between 68 and 75 °C. Solid-state reordering models indicate that maximum burial temperatures of 125–155 °C would reset the clumped isotope values to the observed temperature range prior to the onset of regional cooling and uplift. Clumped isotope results from late-stage veins in the White Pine Mine encompass a greater temperature range (49–116 °C), indicative of spatially variable hydrothermal activity and vein emplacement after burial temperatures fell below 100 °C during regional cooling and uplift. Clumped isotope and organic thermal maturity data do not indicate significant spatial differences in thermal history along the MRS. Observed variability in bulk organic matter composition and biomarker indices are therefore more likely a result of shifts in primary productivity or early-degradation processes. These results demonstrate that the MRS experienced a spatially consistent, relatively mild thermal history (125–155 °C) and is therefore a valuable archive for understanding the Late Mesoproterozoic environment.

  18. Impacts of beaver dams on hydrologic and temperature regimes in a mountain stream

    NASA Astrophysics Data System (ADS)

    Majerova, M.; Neilson, B. T.; Schmadel, N. M.; Wheaton, J. M.; Snow, C. J.

    2015-08-01

    Beaver dams affect hydrologic processes, channel complexity, and stream temperature in part by inundating riparian areas, influencing groundwater-surface water interactions, and changing fluvial processes within stream systems. We explored the impacts of beaver dams on hydrologic and temperature regimes at different spatial and temporal scales within a mountain stream in northern Utah over a 3-year period spanning pre- and post-beaver colonization. Using continuous stream discharge, stream temperature, synoptic tracer experiments, and groundwater elevation measurements, we documented pre-beaver conditions in the first year of the study. In the second year, we captured the initial effects of three beaver dams, while the third year included the effects of ten dams. After beaver colonization, reach-scale (~ 750 m in length) discharge observations showed a shift from slightly losing to gaining. However, at the smaller sub-reach scale (ranging from 56 to 185 m in length), the discharge gains and losses increased in variability due to more complex flow pathways with beaver dams forcing overland flow, increasing surface and subsurface storage, and increasing groundwater elevations. At the reach scale, temperatures were found to increase by 0.38 °C (3.8 %), which in part is explained by a 230 % increase in mean reach residence time. At the smallest, beaver dam scale (including upstream ponded area, beaver dam structure, and immediate downstream section), there were notable increases in the thermal heterogeneity where warmer and cooler niches were created. Through the quantification of hydrologic and thermal changes at different spatial and temporal scales, we document increased variability during post-beaver colonization and highlight the need to understand the impacts of beaver dams on stream ecosystems and their potential role in stream restoration.

  19. Statistical Analysis of CMC Constituent and Processing Data

    NASA Technical Reports Server (NTRS)

    Fornuff, Jonathan

    2004-01-01

    Ceramic Matrix Composites (CMCs) are the next "big thing" in high-temperature structural materials. In the case of jet engines, it is widely believed that the metallic superalloys currently being utilized for hot structures (combustors, shrouds, turbine vanes and blades) are nearing their potential limits of improvement. In order to allow for increased turbine temperatures to increase engine efficiency, material scientists have begun looking toward advanced CMCs and SiC/SiC composites in particular. Ceramic composites provide greater strength-to-weight ratios at higher temperatures than metallic alloys, but at the same time require greater challenges in micro-structural optimization that in turn increases the cost of the material as well as increases the risk of variability in the material s thermo-structural behavior. to model various potential CMC engine materials and examines the current variability in these properties due to variability in component processing conditions and constituent materials; then, to see how processing and constituent variations effect key strength, stiffness, and thermal properties of the finished components. Basically, this means trying to model variations in the component s behavior by knowing what went into creating it. inter-phase and manufactured by chemical vapor infiltration (CVI) and melt infiltration (MI) were considered. Examinations of: (1) the percent constituents by volume, (2) the inter-phase thickness, (3) variations in the total porosity, and (4) variations in the chemical composition of the Sic fiber are carried out and modeled using various codes used here at NASA-Glenn (PCGina, NASALife, CEMCAN, etc...). The effects of these variations and the ranking of their respective influences on the various thermo-mechanical material properties are studied and compared to available test data. The properties of the materials as well as minor changes to geometry are then made to the computer model and the detrimental effects observed using statistical analysis software. The ultimate purpose of this study is to determine what variations in material processing can lead to the most critical changes in the materials property. The work I have taken part in this summer explores, in general, the key properties needed In this study SiC/SiC composites of varying architectures, utilizing a boron-nitride (BN)

  20. Study of Natural Fiber Breakage during Composite Processing

    NASA Astrophysics Data System (ADS)

    Quijano-Solis, Carlos Jafet

    Biofiber-thermoplastic composites have gained considerable importance in the last century. To provide mechanical reinforcement to the polymer, fibers must be larger than a critical aspect ratio (length-to-width ratio). However, biofibers undergo breakage in length or width during processing, affecting their final aspect ratio in the composites. In this study, influence on biofiber breakage by factors related to processing conditions, fiber morphology and the flow type was investigated through: a) experiments using an internal mixer, a twin-screw extruder (TSE) or a capillary rheometer; and b) a Monte Carlo computer simulation. Composites of thermomechanical fibers of aspen or wheat straw mixed with polypropylene were studied. Internal mixer experiments analyzed wheat straw and two batches of aspen fibers, named AL and AS. AL fibers had longer average length. Processing variables included the temperature, rotors speed and fiber concentration. TSE experiments studied AL and AS fiber composites under various screws speeds, temperatures and feeding rates of the polymer and fibers. Capillary rheometers experiments determined AL fiber breakage in shear and elongational flows for composites processed at different concentrations, temperatures, and strain rates. Finally, the internal mixer experimental results where compared to Monte Carlo simulation predictions. The simulation focused on fiber length breakage due to fiber-polymer interactions. Internal mixer results showed that final fiber average length depended almost solely on processing conditions while final fiber average width depended on both processing conditions and initial fiber morphology. In the TSE, processing conditions as well as initial fiber length influenced final average length. TSE results showed that the fiber concentration regime seems to influence the effect of processing variables on fiber breakage. Capillary rheometer experiments demonstrated that biofiber breakage happens in both elongational and shear flows. In some cases, percentage of biofiber breakage in elongational flow is higher. In general, simulation predictions of final average lengths were in good agreement with experiments, indicating the importance of fiber-polymer interactions on fiber breakage. The largest discrepancies were obtained at higher fiber concentration composites; these differences might be resolved, in future simulations, by including the effect of fiber-fiber interactions.

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