Polycyclic aromatic hydrocarbons in caribou, moose, and wolf scat samples from three areas of the Alberta oil sands.

PubMed

Lundin, Jessica I; Riffell, Jeffrey A; Wasser, Samuel K

2015-11-01

Impacts of toxic substances from oil production in the Alberta oil sands (AOS), such as polycyclic aromatic hydrocarbons (PAHs), have been widely debated. Studies have been largely restricted to exposures from surface mining in aquatic species. We measured PAHs in Woodland caribou (Rangifer tarandus caribou), moose (Alces americanus), and Grey wolf (Canis lupus) across three areas that varied in magnitude of in situ oil production. Our results suggest a distinction of PAH level and source profile (petro/pyrogenic) between study areas and species. Caribou samples indicated pyrogenic sourced PAHs in the study area previously devastated by forest fire. Moose and wolf samples from the high oil production area demonstrated PAH ratios indicative of a petrogenic source and increased PAHs, respectively. These findings emphasize the importance of broadening monitoring and research programs in the AOS. Copyright © 2015 Elsevier Ltd. All rights reserved.

75 FR 31317 - National Emission Standards for Hazardous Air Pollutants: Area Source Standards for Paints and...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-03

... National Emission Standards for Hazardous Air Pollutants: Area Source Standards for Paints and Allied... when they should not be covered. This action clarifies text of the National Emission Standards for Hazardous Air Pollutants: Paints and Allied Products Manufacturing Area Source Standards which was published...

Cone and seed yields in white spruce seed production areas

Treesearch

John A. Pitcher

1966-01-01

The source of seed is an important consideration in the reforestation program on the National Forests in the North Central Region. Thirty-five seed production areas have been set up in the Region, along the lines proposed by the North Central Forest Experiment Station, to provide control of seed source. Red pine, white pine, shortleaf and loblolly pine, and white...

Urinary perchlorate exposure and risk in women of reproductive age in a fireworks production area of China.

PubMed

Li, Qin; Yu, Yun-jiang; Wang, Fei-fei; Chen, Shi-wu; Yin, Yan; Lin, Hai-peng; Che, Fei; Sun, Peng; Qin, Juan; Liu, Jie; Wang, Hong-mei

2014-07-01

Perchlorate is used widely in fireworks, and, if ingested, it has the potential to disrupt thyroid function. The concentrations of perchlorate in water and soil samples and in urine samples of women of reproductive age from Liuyang, the largest fireworks production area in China, were investigated. The results showed that the average perchlorate concentrations in groundwater, surface water, farmland soil, and urine samples of women from the fireworks production area were significantly greater than those from the control area. The health risk of perchlorate ingested through drinking water was assessed based on the mode recommended by the United States Environmental Protection Agency. The values of hazard quotient of river water and groundwater in the fireworks production area were much greater than the safe level (=1), which indicates that adverse health effects may result from perchlorate when these sources of water are used as drinking water. These results indicated that the environment of the fireworks production area has been polluted by perchlorate and that residents were and are facing greater exposure doses of perchlorate. Fireworks production enterprises may be a major source of perchlorate contamination.

A stable isotope approach for source apportionment of chlorinated ethene plumes at a complex multi-contamination events urban site

NASA Astrophysics Data System (ADS)

Nijenhuis, Ivonne; Schmidt, Marie; Pellegatti, Eleonora; Paramatti, Enrico; Richnow, Hans Hermann; Gargini, Alessandro

2013-10-01

The stable carbon isotope composition of chlorinated aliphatic compounds such as chlorinated methanes, ethanes and ethenes was examined as an intrinsic fingerprint for apportionment of sources. A complex field site located in Ferrara (Italy), with more than 50 years history of use of chlorinated aliphatic compounds, was investigated in order to assess contamination sources. Several contamination plumes were found in a complex alluvial sandy multi-aquifer system close to the river Po; sources are represented by uncontained former industrial and municipal dump sites as well as by spills at industrial areas. The carbon stable isotope signature allowed distinguishing 2 major sources of contaminants. One source of chlorinated aliphatic contaminants was strongly depleted in 13C (<-60‰) suggesting production lines which have used depleted methane for synthesis. The other source had typical carbon isotope compositions of >-40‰ which is commonly observed in recent production of chlorinated solvents. The degradation processes in the plumes could be traced interpreting the isotope enrichment and depletion of parent and daughter compounds, respectively. We demonstrate that, under specific production conditions, namely when highly chlorinated ethenes are produced as by-product during chloromethanes production, 13C depleted fingerprinting of contaminants can be obtained and this can be used to track sources and address the responsible party of the pollution in urban areas.

A stable isotope approach for source apportionment of chlorinated ethene plumes at a complex multi-contamination events urban site.

PubMed

Nijenhuis, Ivonne; Schmidt, Marie; Pellegatti, Eleonora; Paramatti, Enrico; Richnow, Hans Hermann; Gargini, Alessandro

2013-10-01

The stable carbon isotope composition of chlorinated aliphatic compounds such as chlorinated methanes, ethanes and ethenes was examined as an intrinsic fingerprint for apportionment of sources. A complex field site located in Ferrara (Italy), with more than 50years history of use of chlorinated aliphatic compounds, was investigated in order to assess contamination sources. Several contamination plumes were found in a complex alluvial sandy multi-aquifer system close to the river Po; sources are represented by uncontained former industrial and municipal dump sites as well as by spills at industrial areas. The carbon stable isotope signature allowed distinguishing 2 major sources of contaminants. One source of chlorinated aliphatic contaminants was strongly depleted in ¹³C (<-60‰) suggesting production lines which have used depleted methane for synthesis. The other source had typical carbon isotope compositions of >-40‰ which is commonly observed in recent production of chlorinated solvents. The degradation processes in the plumes could be traced interpreting the isotope enrichment and depletion of parent and daughter compounds, respectively. We demonstrate that, under specific production conditions, namely when highly chlorinated ethenes are produced as by-product during chloromethanes production, ¹³C depleted fingerprinting of contaminants can be obtained and this can be used to track sources and address the responsible party of the pollution in urban areas. © 2013 Elsevier B.V. All rights reserved.

Stochastic industrial source detection using lower cost methods

EPA Science Inventory

Hazardous air pollutants (HAPs) can be emitted from a variety of sources in industrial facilities, energy production, and commercial operations. Stochastic industrial sources (SISs) represent a subcategory of emissions from fugitive leaks, variable area sources, malfunctioning p...

Large area multiarc ion beam source {open_quote}MAIS{close_quote}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Engelko, V.; Giese, H.; Schalk, S.

1996-12-31

A pulsed large area intense ion beam source is described, in which the ion emitting plasma is built up by an array of individual discharge units, homogeneously distributed over the surface of a common discharge electrode. A particularly advantageous feature of the source is that for plasma generation and subsequent acceleration of the ions only one common energy supply is necessary. This allows to simplify the source design and provides inherent synchronization of plasma production and ion extraction. The homogeneity of the plasma density was found to be superior to plasma sources using plasma expanders. Originally conceived for the productionmore » of proton beams, the source can easily be modified for the production of beams composed of carbon and metal ions or mixed ion species. Results of investigations of the source performance for the production of a proton beam are presented. The maximum beam current achieved to date is of the order of 100 A, with a particle kinetic energy of 15 - 30 keV and a pulse length in the range of 10 {mu}s.« less

40 CFR 63.11588 - What definitions apply to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Area Sources: Chemical Preparations Industry Other Requirements and Information § 63.11588 What definitions apply to this subpart? Chemical... by the paints and allied products area source rule (40 CFR part 63, subpart CCCCCCC). Chemical...

40 CFR 63.11588 - What definitions apply to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Area Sources: Chemical Preparations Industry Other Requirements and Information § 63.11588 What definitions apply to this subpart? Chemical... by the paints and allied products area source rule (40 CFR part 63, subpart CCCCCCC). Chemical...

40 CFR 63.11588 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Area Sources: Chemical Preparations Industry Other Requirements and Information § 63.11588 What definitions apply to this subpart? Chemical... by the paints and allied products area source rule (40 CFR part 63, subpart CCCCCCC). Chemical...

NATIONAL INVENTORIES FOR AREA SOURCE FUEL COMBUSTION AND GASOLINE MARKETING IN 1999

EPA Science Inventory

The product will be a set of estimates of county-level 1999 emissions of all relevant air pollutants from gasoline marketing and from the combustion of fuel by "area" sources, i.e., those too small be be required to report their emissions individually.

Volatile Organic Compound Emissions from USAF Wastewater Treatment Plants in Ozone Nonattainment Areas

DTIC Science & Technology

1994-09-01

Wastewater Treatment 39 Industrial Sources 39 Household Products 39 Fate Mechanisms for VOCs in Wastewater 40 Volatilization 40 Gas Stripping 40...industrial sources, and household products (16:33-35; 51:51-53; 52:56; 53:6-7). Water and Wastewater Treatment. Chlorine is typically added to...of tetrachloroethene. Household Products . Cleaners, personal care items (deodorants, cosmetics, deodorizers), lawn and garden products, paints and

40 CFR 63.11640 - Am I subject to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

...) National Emission Standards for Hazardous Air Pollutants: Gold Mine Ore Processing and Production Area... subject to this subpart if you own or operate a gold mine ore processing and production facility as... source. The affected sources are each collection of “ore pretreatment processes” at a gold mine ore...

40 CFR 63.11640 - Am I subject to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

...) National Emission Standards for Hazardous Air Pollutants: Gold Mine Ore Processing and Production Area... subject to this subpart if you own or operate a gold mine ore processing and production facility as... source. The affected sources are each collection of “ore pretreatment processes” at a gold mine ore...

40 CFR 63.11640 - Am I subject to this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

...) National Emission Standards for Hazardous Air Pollutants: Gold Mine Ore Processing and Production Area... subject to this subpart if you own or operate a gold mine ore processing and production facility as... source. The affected sources are each collection of “ore pretreatment processes” at a gold mine ore...

40 CFR 63.11640 - Am I subject to this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

...) National Emission Standards for Hazardous Air Pollutants: Gold Mine Ore Processing and Production Area... subject to this subpart if you own or operate a gold mine ore processing and production facility as... source. The affected sources are each collection of “ore pretreatment processes” at a gold mine ore...

Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

DOE PAGES

Dale, Virginia H.; Parish, Esther S.; Kline, Keith L.

2014-12-02

Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most ofmore » which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Furthermore, energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.« less

Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dale, Virginia H.; Parish, Esther S.; Kline, Keith L.

Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most ofmore » which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Furthermore, energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.« less

The Network Structure Underlying the Earth Observation Assessment

NASA Astrophysics Data System (ADS)

Vitkin, S.; Doane, W. E. J.; Mary, J. C.

2017-12-01

The Earth Observations Assessment (EOA 2016) is a multiyear project designed to assess the effectiveness of civil earth observation data sources (instruments, sensors, models, etc.) on societal benefit areas (SBAs) for the United States. Subject matter experts (SMEs) provided input and scored how data sources inform products, product groups, key objectives, SBA sub-areas, and SBAs in an attempt to quantify the relationships between data sources and SBAs. The resulting data were processed by Integrated Applications Incorporated (IAI) using MITRE's PALMA software to create normalized relative impact scores for each of these relationships. However, PALMA processing obscures the natural network representation of the data. Any network analysis that might identify patterns of interaction among data sources, products, and SBAs is therefore impossible. Collaborating with IAI, we cleaned and recreated a network from the original dataset. Using R and Python we explore the underlying structure of the network and apply frequent itemset mining algorithms to identify groups of data sources and products that interact. We reveal interesting patterns and relationships in the EOA dataset that were not immediately observable from the EOA 2016 report and provide a basis for further exploration of the EOA network dataset.

TREATMENT OF A SATURATED ZONE HEXAVALENT CHROMIUM SOURCE AREA USING A FERROUS SULFATE/SODIUM DITHIONITE MIXTURE: A FIELD PILOT STUDY

EPA Science Inventory

A field pilot study was conducted to evaluate the performance of a combined ferrous sulfate/sodium dithionite solution for in situ treatment of a saturated zone hexavalent chromium source area at a former ferrochromium alloy production facility in Charleston, S.C. The saturate...

40 CFR 63.11452 - What are the performance test requirements for new and existing sources?

Code of Federal Regulations, 2013 CFR

2013-07-01

... production rate for the performance test, kilograms (tons) of glass produced per hour. (v) Calculate the 3... = Average glass production rate for the performance test, kilograms (tons) of glass produced per hour. (v... Glass Manufacturing Area Sources Standards, Compliance, and Monitoring Requirements § 63.11452 What are...

40 CFR 63.11452 - What are the performance test requirements for new and existing sources?

Code of Federal Regulations, 2012 CFR

2012-07-01

... production rate for the performance test, kilograms (tons) of glass produced per hour. (v) Calculate the 3... = Average glass production rate for the performance test, kilograms (tons) of glass produced per hour. (v... Glass Manufacturing Area Sources Standards, Compliance, and Monitoring Requirements § 63.11452 What are...

40 CFR 63.11452 - What are the performance test requirements for new and existing sources?

Code of Federal Regulations, 2014 CFR

2014-07-01

... production rate for the performance test, kilograms (tons) of glass produced per hour. (v) Calculate the 3... = Average glass production rate for the performance test, kilograms (tons) of glass produced per hour. (v... Glass Manufacturing Area Sources Standards, Compliance, and Monitoring Requirements § 63.11452 What are...

40 CFR 63.11452 - What are the performance test requirements for new and existing sources?

Code of Federal Regulations, 2010 CFR

2010-07-01

... production rate for the performance test, kilograms (tons) of glass produced per hour. (v) Calculate the 3... = Average glass production rate for the performance test, kilograms (tons) of glass produced per hour. (v... Glass Manufacturing Area Sources Standards, Compliance, and Monitoring Requirements § 63.11452 What are...

40 CFR 63.11452 - What are the performance test requirements for new and existing sources?

Code of Federal Regulations, 2011 CFR

2011-07-01

... production rate for the performance test, kilograms (tons) of glass produced per hour. (v) Calculate the 3... = Average glass production rate for the performance test, kilograms (tons) of glass produced per hour. (v... Glass Manufacturing Area Sources Standards, Compliance, and Monitoring Requirements § 63.11452 What are...

Fact Sheet: Final Air Toxics Standards for Area Sources in Seven Industry Sectors

EPA Pesticide Factsheets

This fact sheet discusses national emission standards for acrylic and modacrylic fibers production, carbon black production, chemical manufacturing: chromium compounds, flexible polyurethane foam production and fabrication, lead acid battery manufacturing,

Assessing critical source areas in watersheds for conservation buffer planning and riparian restoration.

PubMed

Qiu, Zeyuan

2009-11-01

A science-based geographic information system (GIS) approach is presented to target critical source areas in watersheds for conservation buffer placement. Critical source areas are the intersection of hydrologically sensitive areas and pollutant source areas in watersheds. Hydrologically sensitive areas are areas that actively generate runoff in the watershed and are derived using a modified topographic index approach based on variable source area hydrology. Pollutant source areas are the areas in watersheds that are actively and intensively used for such activities as agricultural production. The method is applied to the Neshanic River watershed in Hunterdon County, New Jersey. The capacity of the topographic index in predicting the spatial pattern of runoff generation and the runoff contribution to stream flow in the watershed is evaluated. A simple cost-effectiveness assessment is conducted to compare the conservation buffer placement scenario based on this GIS method to conventional riparian buffer scenarios for placing conservation buffers in agricultural lands in the watershed. The results show that the topographic index reasonably predicts the runoff generation in the watershed. The GIS-based conservation buffer scenario appears to be more cost-effective than the conventional riparian buffer scenarios.

40 CFR 63.11166 - What General Provisions apply to primary beryllium production facilities?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Primary Nonferrous Metals Area Sources-Zinc, Cadmium, and Beryllium Primary Beryllium Production Facilities § 63.11166 What General Provisions apply to primary beryllium production facilities? (a) You must... primary beryllium production facilities? 63.11166 Section 63.11166 Protection of Environment ENVIRONMENTAL...

Coupling of Algal Biofuel Production with Wastewater

PubMed Central

Panwar, Amit; Bisht, Tara Singh; Tamta, Sushma

2014-01-01

Microalgae have gained enormous consideration from scientific community worldwide emerging as a viable feedstock for a renewable energy source virtually being carbon neutral, high lipid content, and comparatively more advantageous to other sources of biofuels. Although microalgae are seen as a valuable source in majority part of the world for production of biofuels and bioproducts, still they are unable to accomplish sustainable large-scale algal biofuel production. Wastewater has organic and inorganic supplements required for algal growth. The coupling of microalgae with wastewater is an effective way of waste remediation and a cost-effective microalgal biofuel production. In this review article, we will primarily discuss the possibilities and current scenario regarding coupling of microalgal cultivation with biofuel production emphasizing recent progress in this area. PMID:24982930

Thermal-electric numerical simulation of a surface ion source for the production of radioactive ion beams

NASA Astrophysics Data System (ADS)

Manzolaro, Mattia; Meneghetti, Giovanni; Andrighetto, Alberto

2010-11-01

In a facility for the production of radioactive ion beams (RIBs), the target system and the ion source are the most critical objects. In the context of the Selective Production of Exotic Species (SPES) project, a proton beam directly impinges a Uranium Carbide production target, generating approximately 10 13 fissions per second. The radioactive isotopes produced by the 238U fissions are then directed to the ion source to acquire a charge state. After that, the radioactive ions obtained are transported electrostatically to the subsequent areas of the facility. In this work the surface ion source at present adopted for the SPES project is studied by means of both analytical and numerical thermal-electric models. The theoretical results are compared with temperature and electric potential difference measurements.

40 CFR 63.11164 - What General Provisions apply to primary zinc production facilities?

Code of Federal Regulations, 2011 CFR

2011-07-01

... primary zinc production facilities? 63.11164 Section 63.11164 Protection of Environment ENVIRONMENTAL... Primary Nonferrous Metals Area Sources-Zinc, Cadmium, and Beryllium Primary Zinc Production Facilities § 63.11164 What General Provisions apply to primary zinc production facilities? (a) If you own or...

40 CFR 63.11164 - What General Provisions apply to primary zinc production facilities?

Code of Federal Regulations, 2010 CFR

2010-07-01

... primary zinc production facilities? 63.11164 Section 63.11164 Protection of Environment ENVIRONMENTAL... Primary Nonferrous Metals Area Sources-Zinc, Cadmium, and Beryllium Primary Zinc Production Facilities § 63.11164 What General Provisions apply to primary zinc production facilities? (a) If you own or...

Application of satellite products and hydrological modelling for flood early warning

NASA Astrophysics Data System (ADS)

Koriche, Sifan A.; Rientjes, Tom H. M.

2016-06-01

Floods have caused devastating impacts to the environment and society in Awash River Basin, Ethiopia. Since flooding events are frequent, this marks the need to develop tools for flood early warning. In this study, we propose a satellite based flood index to identify the runoff source areas that largely contribute to extreme runoff production and floods in the basin. Satellite based products used for development of the flood index are CMORPH (Climate Prediction Center MORPHing technique: 0.25° by 0.25°, daily) product for calculation of the Standard Precipitation Index (SPI) and a Shuttle Radar Topography Mission (SRTM) digital elevation model (DEM) for calculation of the Topographic Wetness Index (TWI). Other satellite products used in this study are for rainfall-runoff modelling to represent rainfall, potential evapotranspiration, vegetation cover and topography. Results of the study show that assessment of spatial and temporal rainfall variability by satellite products may well serve in flood early warning. Preliminary findings on effectiveness of the flood index developed in this study indicate that the index is well suited for flood early warning. The index combines SPI and TWI, and preliminary results illustrate the spatial distribution of likely runoff source areas that cause floods in flood prone areas.

A multi-source precipitation approach to fill gaps over a radar precipitation field

NASA Astrophysics Data System (ADS)

Tesfagiorgis, K. B.; Mahani, S. E.; Khanbilvardi, R.

2012-12-01

Satellite Precipitation Estimates (SPEs) may be the only available source of information for operational hydrologic and flash flood prediction due to spatial limitations of radar and gauge products. The present work develops an approach to seamlessly blend satellite, radar, climatological and gauge precipitation products to fill gaps over ground-based radar precipitation fields. To mix different precipitation products, the bias of any of the products relative to each other should be removed. For bias correction, the study used an ensemble-based method which aims to estimate spatially varying multiplicative biases in SPEs using a radar rainfall product. Bias factors were calculated for a randomly selected sample of rainy pixels in the study area. Spatial fields of estimated bias were generated taking into account spatial variation and random errors in the sampled values. A weighted Successive Correction Method (SCM) is proposed to make the merging between error corrected satellite and radar rainfall estimates. In addition to SCM, we use a Bayesian spatial method for merging the gap free radar with rain gauges, climatological rainfall sources and SPEs. We demonstrate the method using SPE Hydro-Estimator (HE), radar- based Stage-II, a climatological product PRISM and rain gauge dataset for several rain events from 2006 to 2008 over three different geographical locations of the United States. Results show that: the SCM method in combination with the Bayesian spatial model produced a precipitation product in good agreement with independent measurements. The study implies that using the available radar pixels surrounding the gap area, rain gauge, PRISM and satellite products, a radar like product is achievable over radar gap areas that benefits the scientific community.

Characterization, distribution, and risk assessment of heavy metals in agricultural soil and products around mining and smelting areas of Hezhang, China.

PubMed

Briki, Meryem; Ji, Hongbing; Li, Cai; Ding, Huaijian; Gao, Yang

2015-12-01

Mining and smelting have been releasing huge amount of toxic substances into the environment. In the present study, agricultural soil and different agricultural products (potato, Chinese cabbage, garlic bolt, corn) were analyzed to examine the source, spatial distribution, and risk of 12 elements (As, Be, Bi, Cd, Co, Cr, Cu, Hg, Ni, Pb, Sb, and Zn) in agricultural soil near mine fields, smelting fields, and mountain field around Hezhang County, west of Guizhou Province, China. Multivariate statistical analysis indicated that in mining area, As, Bi, Cd, Cu, Hg, Pb, Sb, and Zn were generated from anthropogenic sources; in smelting area, As, Be, Cd, Co, Cu, Pb, Sb, and Zn were derived from anthropogenic sources through zinc smelting ceased in 2004. The enrichment factors (EFs) and ecological risk index (RI) of soil in mining area are the most harmful, showing extremely high enrichment and very high ecological risk of As, Bi, Cd, Cu, Hg, Pb, Sb, and Zn. Zinc is the most significant enriched in the smelting area; however, mountain area has a moderate enrichment and ecological risk and do not present any ecological risk. According to spatial distribution, the concentrations depend on the nearby mining and smelting activities. Transfer factors (TFs) in the smelting area and mountain are high, implying a threat for human consumption. Therefore, further studies should be carried out taking into account the harm of those heavy metals and potential negative health effects from the consumption of agricultural products in these circumstances.

40 CFR 63.1218 - What are the standards for hydrochloric acid production furnaces that burn hazardous waste?

Code of Federal Regulations, 2013 CFR

2013-07-01

... limits provided by paragraph (a)(5) of this section; (2) For mercury, hydrogen chloride and chlorine gas..., except for an area source as defined under § 63.2, hydrogen chloride and chlorine gas emissions in excess..., except for an area source as defined under § 63.2, hydrogen chloride and chlorine gas emissions in excess...

Energy Sources (Energy/Power). Industrial Arts, Senior High--Level II. North Dakota Senior High Industrial Arts Curriculum Guides.

ERIC Educational Resources Information Center

Lawrence, Allen; And Others

This course guide for an energy sources course is one of four developed for the energy/power area in the North Dakota senior high industrial arts education program. (Eight other guides are available for two other areas of Industrial Arts--graphic communications and production.) Part 1 provides such introductory information as a definition and…

Apparatus for the production of boron nitride nanotubes

DOEpatents

Smith, Michael W; Jordan, Kevin

2014-06-17

An apparatus for the large scale production of boron nitride nanotubes comprising; a pressure chamber containing; a continuously fed boron containing target; a source of thermal energy preferably a focused laser beam; a cooled condenser; a source of pressurized nitrogen gas; and a mechanism for extracting boron nitride nanotubes that are condensed on or in the area of the cooled condenser from the pressure chamber.

Smallholder Information Sources and Communication Pathways for Cashew Production and Marketing in Tanzania: An Ex-Post Study in Tandahimba and Lindi Rural Districts, Southern Tanzania

ERIC Educational Resources Information Center

Nyambo, Brigitte; Ligate, Elly

2013-01-01

Purpose: To identify and review production and marketing information sources and flows for smallholder cashew (Anacardium occidentale L.) growers in Tanzania and recommend systems improvements for better technology uptake. Design/methodology/approach: Two-stage purposive samples were drawn. First, two districts in the main cashew producing areas,…

77 FR 4522 - National Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-30

... Manufacturing, Industrial Organic Chemical Manufacturing, Inorganic Pigments Manufacturing, Miscellaneous Organic Chemical Manufacturing, Plastic Materials and Resins Manufacturing, Pharmaceutical Production and... Intermediate Production, Industrial Inorganic Chemical Manufacturing, Industrial Organic Chemical Manufacturing...

Contamination source review for Building E6891, Edgewood Area, Aberdeen Proving Ground, Maryland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zellmer, S.D.; Draugelis, A.K.; Rueda, J.

1995-09-01

The US Army Aberdeen Proving Ground (APG) commissioned Argonne National Laboratory (ANL) to conduct a contamination source review to identify and define areas of toxic or hazardous contaminants and to assess the physical condition and accessibility of various APG buildings. This report provides the results of the contamination source review for Building E6891. The information obtained from this review may be used to assist the US Army in planning for the future use or disposition of the buildings. The contamination source review consisted of the following tasks: historical records search, physical inspection, photographic documentation, geophysical investigation, and collection of airmore » samples. This building is part of the Lauderick Creek Concrete Slab Test Site, located in the Lauderick Creek Area in the Edgewood Area. Many of the APG facilities constructed between 1917 and the 1960s are no longer used because of obsolescence and their poor state of repair. Because many of these buildings were used for research, development, testing, and/or pilot-scale production of chemical warfare agents and other military substances the potential exists` for portions of the buildings to be contaminated with these substances, their degradation products, and other laboratory or industrial chemicals. These buildings and associated structures or appurtenances may contribute to environmental concerns at APG.« less

Developing a Dynamic SPARROW Water Quality Decision Support System Using NASA Remotely-Sensed Products

NASA Astrophysics Data System (ADS)

Al-Hamdan, M. Z.; Smith, R. A.; Hoos, A.; Schwarz, G. E.; Alexander, R. B.; Crosson, W. L.; Srikishen, J.; Estes, M., Jr.; Cruise, J.; Al-Hamdan, A.; Ellenburg, W. L., II; Flores, A.; Sanford, W. E.; Zell, W.; Reitz, M.; Miller, M. P.; Journey, C. A.; Befus, K. M.; Swann, R.; Herder, T.; Sherwood, E.; Leverone, J.; Shelton, M.; Smith, E. T.; Anastasiou, C. J.; Seachrist, J.; Hughes, A.; Graves, D.

2017-12-01

The USGS Spatially Referenced Regression on Watershed Attributes (SPARROW) surface water quality modeling system has been widely used for long term, steady state water quality analysis. However, users have increasingly requested a dynamic version of SPARROW that can provide seasonal estimates of nutrients and suspended sediment to receiving waters. The goal of this NASA-funded project is to develop a dynamic decision support system to enhance the southeast SPARROW water quality model and finer-scale dynamic models for selected coastal watersheds through the use of remotely-sensed data and other NASA Land Information System (LIS) products. The spatial and temporal scale of satellite remote sensing products and LIS modeling data make these sources ideal for the purposes of development and operation of the dynamic SPARROW model. Remote sensing products including MODIS vegetation indices, SMAP surface soil moisture, and OMI atmospheric chemistry along with LIS-derived evapotranspiration (ET) and soil temperature and moisture products will be included in model development and operation. MODIS data will also be used to map annual land cover/land use in the study areas and in conjunction with Landsat and Sentinel to identify disturbed areas that might be sources of sediment and increased phosphorus loading through exposure of the bare soil. These data and others constitute the independent variables in a regression analysis whose dependent variables are the water quality constituents total nitrogen, total phosphorus, and suspended sediment. Remotely-sensed variables such as vegetation indices and ET can be proxies for nutrient uptake by vegetation; MODIS Leaf Area Index can indicate sources of phosphorus from vegetation; soil moisture and temperature are known to control rates of denitrification; and bare soil areas serve as sources of enhanced nutrient and sediment production. The enhanced SPARROW dynamic models will provide improved tools for end users to manage water quality in near real time and for the formulation of future scenarios to inform strategic planning. Time-varying SPARROW outputs will aid water managers in decision making regarding allocation of resources in protecting aquatic habitats, planning for harmful algal blooms, and restoration of degraded habitats, stream segments, or lakes.

Production of NOx and other precursors of ozone formation in the Uinta Basin

NASA Astrophysics Data System (ADS)

Smith, E.; Lyman, S. N.; Martin, R. S.; Anderson, R.

2012-12-01

The Uinta Basin, located in northeastern Utah, sometimes experiences ozone mixing ratios greater than the EPA NAAQS during specific meteorological conditions that include a combination of snow cover and inversion. We monitored ozone and some of its precursors, including NO, NO2, NOx (NO + NO2), and NOy (sum of reactive nitrogen species), at two sites (Roosevelt and Horse Pool). The Roosevelt site is in a city of about 6,000 people, and the Horse Pool site is in an area of intensive oil and gas production. In February and March 2012, NO, NO2, and NOy mixing ratios were 0.5 ± 0.8, 5.2 ± 2.6, and 6.5 ± 3.9 ppb at Roosevelt and 0 ± 1.3, 2.8 ± 2.7, and 4.1 ± 4.4 ppb at Horse Pool, respectively (mean ± standard deviation). NO, NO2, and NOx were measured at 7 other sites around the Basin by other entities. The spatial and temporal patterns in NOx and NOy indicate the dominance of local source influences on observed mixing ratios. NOx at urban sites and in oil and gas production areas appeared strongly influenced by traffic patterns. At some sites, wind direction analysis and air trajectory analysis indicated that areas of oil and gas production are significant sources of NOx, though pinpointing individual NOx sources proved difficult.

Electrical-thermal-structural finite element simulation and experimental study of a plasma ion source for the production of radioactive ion beams

NASA Astrophysics Data System (ADS)

Manzolaro, M.; Meneghetti, G.; Andrighetto, A.; Vivian, G.

2016-03-01

The production target and the ion source constitute the core of the selective production of exotic species (SPES) facility. In this complex experimental apparatus for the production of radioactive ion beams, a 40 MeV, 200 μA proton beam directly impinges a uranium carbide target, generating approximately 1013 fissions per second. The transfer line enables the unstable isotopes generated by the 238U fissions in the target to reach the ion source, where they can be ionized and finally accelerated to the subsequent areas of the facility. In this work, the plasma ion source currently adopted for the SPES facility is analyzed in detail by means of electrical, thermal, and structural numerical models. Next, theoretical results are compared with the electric potential difference, temperature, and displacement measurements. Experimental tests with stable ion beams are also presented and discussed.

International linkage of two food-borne hepatitis A clusters through traceback of mussels, the Netherlands, 2012.

PubMed

Boxman, Ingeborg L A; Verhoef, Linda; Vennema, Harry; Ngui, Siew-Lin; Friesema, Ingrid H M; Whiteside, Chris; Lees, David; Koopmans, Marion

2016-01-01

This report describes an outbreak investigation starting with two closely related suspected food-borne clusters of Dutch hepatitis A cases, nine primary cases in total, with an unknown source in the Netherlands. The hepatitis A virus (HAV) genotype IA sequences of both clusters were highly similar (459/460 nt) and were not reported earlier. Food questionnaires and a case-control study revealed an association with consumption of mussels. Analysis of mussel supply chains identified the most likely production area. International enquiries led to identification of a cluster of patients near this production area with identical HAV sequences with onsets predating the first Dutch cluster of cases. The most likely source for this cluster was a case who returned from an endemic area in Central America, and a subsequent household cluster from which treated domestic sewage was discharged into the suspected mussel production area. Notably, mussels from this area were also consumed by a separate case in the United Kingdom sharing an identical strain with the second Dutch cluster. In conclusion, a small number of patients in a non-endemic area led to geographically dispersed hepatitis A outbreaks with food as vehicle. This link would have gone unnoticed without sequence analyses and international collaboration.

40 CFR 63.11402 - What are the standards and compliance requirements for new and existing sources?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 14 2010-07-01 2010-07-01 false What are the standards and compliance requirements for new and existing sources? 63.11402 Section 63.11402 Protection of Environment ENVIRONMENTAL... Carbon Black Production Area Sources Standards and Compliance Requirements § 63.11402 What are the...

Comparison of carbohydrate sources in yeast-fermentation CO2 generators for mosquito surveillance

USDA-ARS?s Scientific Manuscript database

Mosquito surveillance in remote areas with limited access to canisters of CO2 or dry ice will benefit from an effective alternative CO2 source, such as the natural production of CO2 from yeast fermentation of several carbohydrate sources. In this study, we document the differences in mosquito and n...

Characterization of Spatial Impact of Particles Emitted from a Cement Material Production Facility on Outdoor Particle Deposition in the Surrounding Community.

PubMed

Yu, Chang Ho; Fan, Zhihua Tina; McCandlish, Elizabeth; Stern, Alan H; Lioy, Paul J

2011-10-01

The objective of this study was to estimate the contribution of a facility that processes steel production slag into raw material for cement production to local outdoor particle deposition in Camden, NJ. A dry deposition sampler that can house four 37-mm quartz fiber filters was developed and used for the collection of atmospheric particle deposits. Two rounds of particle collection (3-4 weeks each) were conducted in 8-11 locations 200-800 m downwind of the facility. Background samples were concurrently collected in a remote area located ∼2 km upwind from the facility. In addition, duplicate surface wipe samples were collected side-by-side from each of the 13 locations within the same sampling area during the first deposition sampling period. One composite source material sample was also collected from a pile stored in the facility. Both the bulk of the source material and the <38 μm fraction subsample were analyzed to obtain the elemental source profile. The particle deposition flux in the study area was higher (24-83 mg/m 2 ·day) than at the background sites (13-17 mg/m 2 ·day). The concentration of Ca, a major element in the cement source production material, was found to exponentially decrease with increasing downwind distance from the facility (P < 0.05). The ratio of Ca/Al, an indicator of Ca enrichment due to anthropogenic sources in a given sample, showed a similar trend. These observations suggest a significant contribution of the facility to the local particle deposition. The contribution of the facility to outdoor deposited particle mass was further estimated by three independent models using the measurements obtained from this study. The estimated contributions to particle deposition in the study area were 1.8-7.4% from the regression analysis of the Ca concentration in particle deposition samples against the distance from the facility, 0-11% from the U.S. Environmental Protection Agency (EPA) Chemical Mass Balance (CMB) source-receptor model, and 7.6-13% from the EPA Industrial Source Complex Short Term (ISCST3) dispersion model using the particle-size-adjusted permit-based emissions estimates. [Box: see text].

International energy annual, 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-05-08

This document presents an overview of key international energy trends for production, consumption, imports, and exports of primary energy commodities in over 200 countries, dependencies, and areas of special sovereignty. Also included are population and gross domestic product data, as well as prices for crude oil and petroleum products in selected countries. Renewable energy includes hydroelectric, geothermal, solar and wind electric power and alcohol for fuel. The data were largely derived from published sources and reports from US Embassy personnel in foreign posts. EIA also used data from reputable secondary sources, industry reports, etc.

Paints and Allied Products Manufacturing: National Emission Standards for Hazardous Air Pollutants (NESHAP) for Area Sources

EPA Pesticide Factsheets

Read the text of this NESHAP regulation on Paints and Allied Products manufacturing. Find the rule summary, and rule history, effective dates, and the federal register citations and fact sheets on the rule.

Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China.

PubMed

Tao, Shu; Li, Xinrong; Yang, Yu; Coveney, Raymond M; Lu, Xiaoxia; Chen, Haitao; Shen, Weiran

2006-08-01

A USEPA, procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo[a]pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from approximately 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from approximately 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 +/- 2.87 ng/m3 on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m3, 41% of the entire population lives within this area.

[Brazilian technological output in the area of nursing: advances and challenges].

PubMed

Koerich, Micheline Henrique Araujo da Luz; Vieira, Raquel Heloisa Guedes; Silva, Daniela Eda; Erdmann, Alacoque Lorenzini; Meirelles, Betina Horner Shlindwein

2011-12-01

This article aims to analyze the patents registered in the nursing area, since these patents may be used as an indicator of the technological development in the area. It presents and discusses national technological productions, tracked through the "nursing" keyword, patented in the period from 1990-2009. This is a retrospective documental research, using, as a source, data from the National Industrial Property Institute (INPI). The information gathered is discussed in relation to the appropriation of the technologies, the incentive to develop them and register them as a source of knowledge in the nursing field, aiming the practice of care. Light and light hard technology productions are increasing in the nursing field. However, these are not registered and patented. The technological advance in the nursing field is emergent and needs policies for its development.

Tidal river sediments in the Washington, D.C. area. 11. Distribution and sources of organic containmants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wade, T.L.; Velinsky, D.J.; Reinharz, E.

1994-06-01

Concentrations of aliphatic, aromatic, and chlorinated hydrocarbons were determined from 33 surface-sediment samples taken from the Tidal Basin, Washington Ship Channel, and the Anacostia and Potomac rivers in Washington, D.C. In conjunction with these samples, selected storm sewers and outfalls also were sampled to help elucidate general sources of contamination to the area. All of the sediments contained detectable concentrations of aliphatic and aromatic hydrocarbons, DDT (total dichlorodiphenytrichloroethande), DDE (dichlorodiphenyldichloroethene), DDD (dichlorodiphenyldichloroethane), PCBx (total polychlorinated biphenyls) and total chlordanes (oxy-, {alpha}-, and {gamma}-chlordane and cis + trans-nonachlor). Sediment concentrations of most contaminants were highest in the Anacostia River just downstreammore » of the Washington Navy Yard, except for total chlordane, which appeared to have upstream sources in addition to storm and combined sewer runoff. This area has the highest number of storm and combined sewer outfalls in the river. Potomac River stations had lower concentrations than other stations. Polycyclic aromatic hydrocarbons, saturated hydrocarbons, and the unresolved complex mixture (UCM) distributions reflect mixtures of combustion products and direct discharges of petroleum products. Sources of PCBs appear to be related to specific outfalls, while hydrocarbon inputs, especially PAHs, are diffuse, and may be related to street runoff. This study indicates that in large urban areas, nonpoint sources deliver substantial amounts of contaminants to ecosystems through storm and combined sewer systems, and control of these inputs must be addressed. 33 refs., 6 figs., 3 tabs.« less

Identification of refined petroleum products in contaminated soils using an identification index for GC chromatograms.

PubMed

Kwon, Dongwook; Ko, Myoung-Soo; Yang, Jung-Seok; Kwon, Man Jae; Lee, Seung-Woo; Lee, Seunghak

2015-08-01

Hydrocarbons found in the environment are typically characterized by gas chromatography (GC). The shape of the GC chromatogram has been used to identify the source of petroleum contamination. However, the conventional practice of simply comparing the peak patterns of source products to those of environmental samples is dependent on the subjective decisions of individual analysts. We have developed and verified a quantitative analytical method for interpreting GC chromatograms to distinguish refined petroleum products in contaminated soils. We found that chromatograms for gasoline, kerosene, and diesel could be divided into three ranges with boundaries at C6, C8, C16, and C26. In addition, the relative peak area (RPA(GC)) of each range, a dimensionless ratio of the peak area within each range to that of the total range (C6-C26), had a unique value for each petroleum product. An identification index for GC chromatograms (ID(GC)), defined as the ratio of RPA(GC) of C8-C16 to that of C16-C26, was able to identify diesel and kerosene sources in samples extracted from artificially contaminated soils even after weathering. Thus, the ID(GC) can be used to effectively distinguish between refined petroleum products in contaminated soils.

Pulpwood Chip Productions and Markets in the Lake States

Treesearch

Eugene W. Fobes

1966-01-01

As a major pulp and paper production area, the Lake States is a potential market for pulpwood chips. As a producer of solid wood products, it has a considerable potential for the production of pulpwood chips from coarse sawmill residues (slabs, edgings, and trim) and other sources. Only a small amount of the available residues, however, is now being utilized. In...

Evaluation of Different Culture Media for Improvement in Bioinsecticides Production by Indigenous Bacillus thuringiensis and Their Application against Larvae of Aedes aegypti

PubMed Central

Devidas, Patil Chandrashekhar; Pandit, Borase Hemant; Vitthalrao, Patil Satish

2014-01-01

Production of indigenous isolate Bacillus thuringiensis sv2 (Bt sv2) was checked on conventional and nonconventional carbon and nitrogen sources in shake flasks. The effects on the production of biomass, toxin production, and spore formation capability of mosquito toxic strain were determined. Toxicity differs within the same strain depending on the growth medium. Bt sv2 produced with pigeon pea and soya bean flour were found highly effective with LC50 < 4 ppm against larvae of Aedes aegypti. These results were comparable with bacteria produced from Luria broth as a reference medium. Cost-effective analyses have revealed that production of biopesticide from test media is highly economical. The cost of production of Bt sv2 with soya bean flour was significantly reduced by 23-fold. The use of nonconventional sources has yielded a new knowledge in this area as the process development aspects of biomass production have been neglected as an area of research. These studies are very important from the point of media optimization for economic production of Bacillus thuringiensis based insecticides in mosquito control programmes. PMID:24592157

Determination of regional relationships among Salmonella spp. isolated from retail pork circulating in the Chiang Mai municipality area using a WGS data approach.

PubMed

Patchanee, Prapas; Eiamsam-Ang, Thanaporn; Vanaseang, Juntakarn; Boonkhot, Phacharaporn; Tadee, Pakpoom

2017-08-02

Salmonella is recognized as a significant zoonotic foodborne pathogen, and pork products are involved in one-fifth of infections. Whole genome sequencing data of Salmonella isolated from retail's pork circulating in the Chiang Mai Municipality area between April 2013 and September 2014, were used to focus on genetic diversity and proven in pig-human transmission based on Multilocus Sequence Typing (MLST). Additionally, WGS data were used to investigate virulence genes, to assess the hazard or pathogenic potential transferred into the food production chain. In this study, all 32 Salmonella strains were classified into 11 Sequence Types (STs). ST469 accounted for the majority (41%). The sequence types of two other strains, 6% of the total, could not be identified. All tested strains carried at least 15 virulence genes. The most frequent gene profile was "sfm-fim-sop-inv.-org-sip-spa-sif-fli-flg-hil-spr-ssa-sse-pag-bss" (47%). Salmonella circulating in the study area demonstrated competence in biofilm production, host cell adhesion, host cell invasion, and host cell survival. Based on the phenotypic and genotypic findings, as well as pathogen source, it appears possible that a common supply chain or common infection source might be presented in the retail pork system in the study area. In addition, an epidemiological comparison of the Salmonella genotypes from the current study with those from other areas such as People's Republic of China (PR China) and the Lao People's Democratic Republic (Lao PDR) was generated by Minimum spanning tree (MST). Identical strains originating from humans, animals and food were found. The findings indicate that contamination can be occured at all levels including pre-harvest, the farm-slaughterhouse-retail chain and consumers over different geographical areas. Acquiring information about infection sources and transmission routes will hopefully motivate all sectors to enforce strict sanitation controls at all production stages including the consumer level. Copyright © 2017 Elsevier B.V. All rights reserved.

The Chandra Source Catalog: Source Properties and Data Products

NASA Astrophysics Data System (ADS)

Rots, Arnold; Evans, Ian N.; Glotfelty, Kenny J.; Primini, Francis A.; Zografou, Panagoula; Anderson, Craig S.; Bonaventura, Nina R.; Chen, Judy C.; Davis, John E.; Doe, Stephen M.; Evans, Janet D.; Fabbiano, Giuseppina; Galle, Elizabeth C.; Gibbs, Danny G., II; Grier, John D.; Hain, Roger; Hall, Diane M.; Harbo, Peter N.; He, Xiang Qun (Helen); Houck, John C.; Karovska, Margarita; Kashyap, Vinay L.; Lauer, Jennifer; McCollough, Michael L.; McDowell, Jonathan C.; Miller, Joseph B.; Mitschang, Arik W.; Morgan, Douglas L.; Mossman, Amy E.; Nichols, Joy S.; Nowak, Michael A.; Plummer, David A.; Refsdal, Brian L.; Siemiginowska, Aneta L.; Sundheim, Beth A.; Tibbetts, Michael S.; van Stone, David W.; Winkelman, Sherry L.

2009-09-01

The Chandra Source Catalog (CSC) is breaking new ground in several areas. There are two aspects that are of particular interest to the users: its evolution and its contents. The CSC will be a living catalog that becomes richer, bigger, and better in time while still remembering its state at each point in time. This means that users will be able to take full advantage of new additions to the catalog, while retaining the ability to back-track and return to what was extracted in the past. The CSC sheds the limitations of flat-table catalogs. Its sources will be characterized by a large number of properties, as usual, but each source will also be associated with its own specific data products, allowing users to perform mini custom analysis on the sources. Source properties fall in the spatial (position, extent), photometric (fluxes, count rates), spectral (hardness ratios, standard spectral fits), and temporal (variability probabilities) domains, and are all accompanied by error estimates. Data products cover the same coordinate space and include event lists, images, spectra, and light curves. In addition, the catalog contains data products covering complete observations: event lists, background images, exposure maps, etc. This work is supported by NASA contract NAS8-03060 (CXC).

The glacial iron cycle from source to export

NASA Astrophysics Data System (ADS)

Hawkings, J.; Wadham, J. L.; Tranter, M.; Raiswell, R.; Benning, L. G.; Statham, P. J.; Tedstone, A. J.; Nienow, P. W.; Telling, J.; Bagshaw, E.; Simmons, S. L.

2014-12-01

Nutrient availability limits primary production in large sectors of the world's oceans. Iron is the major limiting nutrient in around one third of the oceanic euphotic zone, most significantly in the Southern Ocean proximal to Antarctica. In these areas the availability of bioavailable iron can influence the amount of primary production, and thus the strength of the biological pump and associated carbon drawdown from the atmosphere. Despite experiencing widespread iron limitation, the Polar oceans are among the most productive on Earth. Due to the extreme cold, remoteness and their perceived "stasis", ice sheets have previously been though of as insignificant in global biogeochemical cycles. However, large marine algal blooms have been observed in iron-limited areas where glacial influence is large, and it is possible that these areas are stimulated by glacial bioavailable iron input. Here we discuss the importance of the Greenland and Antarctic ice sheets in the global iron cycle. Using field collected trace element data, bulk meltwater chemistry and mineralogical analysis, including photomicrographs, EELS and XANES, we present, for the first time, a conceptual model of the glacial iron cycle from source to export. Using this data we discuss the sources of iron in glacial meltwater, transportation and alteration through the glacial system, and subsequent export to downstream environments. Data collected in 2012 and 2013 from two different Greenlandic glacial catchments are shown, with the most detailed breakdown of iron speciation and concentrations in glacial areas yet reported. Furthermore, the first data from Greenlandic icebergs is presented, allowing meltwater-derived and iceberg-derived iron export to be compared, and the influence of both in marine productivity to be estimated. Using our conceptual model and flux estimates from our dataset, glacial iron delivery in both the northern and southern hemisphere is discussed. Finally, we compare our flux estimates to other major iron sources to the polar regions such as aeolian dust, and discuss potential implications of increased melting of the ice sheets on the global iron cycle in the future.

Unconventional food regeneration in space - Opportunities for microbial food production

NASA Technical Reports Server (NTRS)

Petersen, Gene R.; Schubert, Wayne W.; Seshan, P. K.; Dunlop, Eric H.

1987-01-01

The possible role of microbial species in regenerating food is considered, and three areas where microbial systems can be used in controlled ecological life support systems are discussed. Microbial species can serve as the biological portion of hybrid chemical/biological schemes for primary food products, as a means more fully to utilize waste materials from agronomical food production, and as a source of nutritional supplements to conventional plant foods. Work accomplished in each of these areas is described. The role of microgravity fermenters in this technology is addressed.

Combined Landsat-8 and Sentinel-2 Burned Area Mapping

NASA Astrophysics Data System (ADS)

Huang, H.; Roy, D. P.; Zhang, H.; Boschetti, L.; Yan, L.; Li, Z.

2017-12-01

Fire products derived from coarse spatial resolution satellite data have become an important source of information for the multiple user communities involved in fire science and applications. The advent of the MODIS on NASA's Terra and Aqua satellites enabled systematic production of 500m global burned area maps. There is, however, an unequivocal demand for systematically generated higher spatial resolution burned area products, in particular to examine the role of small-fires for various applications. Moderate spatial resolution contemporaneous satellite data from Landsat-8 and the Sentinel-2A and -2B sensors provide the opportunity for detailed spatial mapping of burned areas. Combined, these polar-orbiting systems provide 10m to 30m multi-spectral global coverage more than once every three days. This NASA funded research presents results to prototype a combined Landsat-8 Sentinel-2 burned area product. The Landsat-8 and Sentinel-2 pre-processing, the time-series burned area mapping algorithm, and preliminary results and validation using high spatial resolution commercial satellite data over Africa are presented.

The Use of Multi-Source Satellite and Geospatial Data to Study the Effect of Urbanization of Primary Productivity in the United States

NASA Technical Reports Server (NTRS)

Imhoff, M. L.; Tucker, C. J.; Lawrence, W. T.; Stutzer, D.; Rusin, Robert

2000-01-01

Data from two different satellites, a digital land cover map, and digital census data were analyzed and combined in a geographic information system to study the effect of urbanization on photosynthetic vegetation productivity in the United States. Results show that urbanization can have a measurable but variable impact on the primary productivity of the land surface. Annual productivity can be reduced by as much as 20 days in some areas, but in resource limited regions, photosynthetic production can be enhanced by human activity. Overall, urban development reduces the productivity of the land surface and those areas with the highest productivity are directly in the path of urban sprawl.

Antibiotic Resistance in Animal and Environmental Samples Associated with Small-Scale Poultry Farming in Northwestern Ecuador.

PubMed

Braykov, Nikolay P; Eisenberg, Joseph N S; Grossman, Marissa; Zhang, Lixin; Vasco, Karla; Cevallos, William; Muñoz, Diana; Acevedo, Andrés; Moser, Kara A; Marrs, Carl F; Foxman, Betsy; Trostle, James; Trueba, Gabriel; Levy, Karen

2016-01-01

The effects of animal agriculture on the spread of antibiotic resistance (AR) are cross-cutting and thus require a multidisciplinary perspective. Here we use ecological, epidemiological, and ethnographic methods to examine populations of Escherichia coli circulating in the production poultry farming environment versus the domestic environment in rural Ecuador, where small-scale poultry production employing nontherapeutic antibiotics is increasingly common. We sampled 262 "production birds" (commercially raised broiler chickens and laying hens) and 455 "household birds" (raised for domestic use) and household and coop environmental samples from 17 villages between 2010 and 2013. We analyzed data on zones of inhibition from Kirby-Bauer tests, rather than established clinical breakpoints for AR, to distinguish between populations of organisms. We saw significantly higher levels of AR in bacteria from production versus household birds; resistance to either amoxicillin-clavulanate, cephalothin, cefotaxime, and gentamicin was found in 52.8% of production bird isolates and 16% of household ones. A strain jointly resistant to the 4 drugs was exclusive to a subset of isolates from production birds (7.6%) and coop surfaces (6.5%) and was associated with a particular purchase site. The prevalence of AR in production birds declined with bird age (P < 0.01 for all antibiotics tested except tetracycline, sulfisoxazole, and trimethoprim-sulfamethoxazole). Farming status did not impact AR in domestic environments at the household or village level. Our results suggest that AR associated with small-scale poultry farming is present in the immediate production environment and likely originates from sources outside the study area. These outside sources might be a better place to target control efforts than local management practices. IMPORTANCE In developing countries, small-scale poultry farming employing antibiotics as growth promoters is being advanced as an inexpensive source of protein and income. Here, we present the results of a large ecoepidemiological study examining patterns of antibiotic resistance (AR) in E. coli isolates from small-scale poultry production environments versus domestic environments in rural Ecuador, where such backyard poultry operations have become established over the past decade. Our previous research in the region suggests that introduction of AR bacteria through travel and commerce may be an important source of AR in villages of this region. This report extends the prior analysis by examining small-scale production chicken farming as a potential source of resistant strains. Our results suggest that AR strains associated with poultry production likely originate from sources outside the study area and that these outside sources might be a better place to target control efforts than local management practices.

50 CFR 260.98 - Premises.

Code of Federal Regulations, 2010 CFR

2010-10-01

... which may result in the contamination of food including, but not limited to, the following: (a) Strong... may constitute a source of contamination in areas where food is exposed; (d) Inadequately drained areas that may contribute contamination to food products through seepage or foot-borne filth and by...

The Use of LiDAR Elevation Data and Satellite Imagery to Locate Critical Source Areas to Diffuse Pollution in Agricultural Watersheds

NASA Astrophysics Data System (ADS)

Drouin, Ariane; Michaud, Aubert; Thériault, Georges; Beaudin, Isabelle; Rodrigue, Jean-François; Denault, Jean-Thomas; Desjardins, Jacques; Côté, Noémi

2013-04-01

In Quebec / Canada, water quality improvement in rural areas greatly depends on the reduction of diffuse pollution. Indeed, point source pollution has been reduced significantly in Canada in recent years by creating circumscribed pits for manure and removing animals from stream. Diffuse pollution differs from point source pollution because it is spread over large areas. In agricultural areas, sediment loss by soil and riverbank erosion along with loss of nutrients (phosphorus, nitrogen, etc.) and pesticides from fields represent the main source of non-point source pollution. The factor mainly responsible for diffuse pollution in agricultural areas is surface runoff occurring in poorly drained areas in fields. The presence of these poorly drained areas is also one of the most limiting factors in crop productivity. Thus, a reconciliation of objectives at the farm (financial concern for farmers) and off-farm concerns (environmental concern) is possible. In short, drainage, runoff, erosion, water quality and crop production are all interconnected issues that need to be tackled together. Two complementary data sources are mainly used in the diagnosis of drainage, surface runoff and erosion : elevation data and multispectral satellite images. In this study of two watersheds located in Québec (Canada), LiDAR elevation data and satellite imagery (QuickBird, Spot and Landsat) were acquired. The studied territories have been partitioned in hydrologic response units (HRUs) according to sub-basins, soils, elevation (topographic index) and land use. These HRUs are afterwards used in a P index software (P-Edit) that calculates the quantities of sediments and phosphorus exported from each HRUs. These exports of sediments and phosphorus are validated with hydrometric and water quality data obtain in two sub-basins and are also compared to soil brightness index derived from multispectral images. This index is sensitive to soil moisture and thus highlights areas where the soil is more humid. A variety of other indices are used to explain the sediments yields. These indices, such as the average percentage of slope, the distance to the stream, the relative position in landscape, the position to the water table, etc. are mainly derived from high precision elevation data. All these data are used to locate critical source areas that generally correspond to a restraint part of the territory but account for the principal amount of sediments exports. Once the critical source areas are identified, best management practices (BMPs) (per example : contaminant source control practices, conservation cropping practices and surface runoff control structures) can be planned. This way, money and energy are used where it really counts. In this presentation, the complete methodology including LiDAR data processing will be explained. The results and the possibility to reproduce the developed method will be discussed.

Submesoscale hotspots of productivity and respiration: Insights from high-resolution oxygen and fluorescence sections

NASA Astrophysics Data System (ADS)

Stanley, Rachel H. R.; McGillicuddy, Dennis J.; Sandwith, Zoe O.; Pleskow, Haley M.

2017-12-01

Modeling studies have shown that mesoscale and submesoscale processes can stimulate phytoplankton productivity and export production. Here, we present observations from an undulating, towed Video Plankton Recorder (VPR-II) in the tropical Atlantic. The VPR-II collected profiles of oxygen, fluorescence, temperature and salinity in the upper 140 m of the water column at a spatial resolution of 1 m in the vertical and <2 km in the horizontal. The data reveal remarkable "hotspots", i.e. locations 5-10 km wide which have elevated fluorescence and decreased oxygen, both of which are likely the result of intense submesoscale upwelling. Based on estimates of source water, estimated from identical temperature and salinity surfaces, hotspots are more often areas of net respiration than areas of net production - although the inferred changes in oxygen are subject to uncertainty in the determination of the source of the upwelled waters since the true source water may not have been sampled. We discuss the spatial distribution of these hotspots and present a conceptual model outlining their possible generation and decline. Simultaneous measurements of O2/Ar in the mixed layer from a shipboard mass spectrometer provide estimates of rates of surface net community production. We find that the subsurface biological hotspots are often expressed as an increase in mixed layer rates of net community production. Overall, the large number of these hotspots support the growing evidence that submesoscale processes are important drivers in upper ocean biological production.

75 FR 28227 - National Emission Standards for Hazardous Air Pollutants: Gold Mine Ore Processing and Production...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-05-20

... published a proposed rule for mercury emissions from the gold mine ore processing and production area source... proposed rule (75 FR 22470). Several parties requested that EPA extend the comment period. EPA has granted...-AP48 National Emission Standards for Hazardous Air Pollutants: Gold Mine Ore Processing and Production...

The North Alabama Lightning Warning Product

NASA Technical Reports Server (NTRS)

Buechler, Dennis E.; Blakeslee, R. J.; Stano, G. T.

2009-01-01

The North Alabama Lightning Mapping Array NALMA has been collecting total lightning data on storms in the Tennessee Valley region since 2001. Forecasters from nearby National Weather Service (NWS) offices have been ingesting this data for display with other AWIPS products. The current lightning product used by the offices is the lightning source density plot. The new product provides a probabalistic, short-term, graphical forecast of the probability of lightning activity occurring at 5 min intervals over the next 30 minutes . One of the uses of the current lightning source density product by the Huntsville National Weather Service Office is to identify areas of potential for cloud-to-ground flashes based on where LMA total lightning is occurring. This product quantifies that observation. The Lightning Warning Product is derived from total lightning observations from the Washington, D.C. (DCLMA) and North Alabama Lightning Mapping Arrays and cloud-to-ground lightning flashes detected by the National Lightning Detection Network (NLDN). Probability predictions are provided for both intracloud and cloud-to-ground flashes. The gridded product can be displayed on AWIPS workstations in a manner similar to that of the lightning source density product.

Developments and potential of radiation processing in the Philippines

NASA Astrophysics Data System (ADS)

Singson, C.; Carmona, C.

This paper describes the research and development activities in three areas of radiation processing, namely: food irradiation, medical product sterilization and wood plastic combination. Plans and efforts exerted to acquire a larger gamma source to augment our present 5,000 curie source are discussed. Cost estimates for a radiation facility is presented on the basis of the market potential of food irradiation and medical product sterilization. Existing local industries that can benefit from the adaptation of irradiation technology in their processing requirements is described.

Sources and management of hazardous waste in Papua New Guinea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, K.

1996-12-31

Papua New Guinea (PNG) has considerable mineral wealth, especially in gold and copper. Large-scale mining takes place, and these activities are the source of most of PNG`s hazardous waste. Most people live in small farming communities throughout the region. Those living adjacent to mining areas have experienced some negative impacts from river ecosystem damage and erosion of their lands. Industry is centered mainly in urban areas and Generates waste composed of various products. Agricultural products, pesticide residues, and chemicals used for preserving timber and other forestry products also produce hazardous waste. Most municipal waste comes from domestic and commercial premises;more » it consists mainly of combustibles, noncombustibles, and other wastes. Hospitals generate pathogenic organisms, radioactive materials, and chemical and pharmaceutical laboratory waste. Little is known about the actual treatment of waste before disposal in PNG. Traditional low-cost waste disposal methods are usually practiced, such as use of landfills; storage in surface impoundments; and disposal in public sewers, rivers, and the sea. Indiscriminate burning of domestic waste in backyards is also commonly practiced in urban and rural areas. 10 refs., 4 tabs.« less

78 FR 15947 - Agency Information Collection Activities; Submission to OMB for Review and Approval; Comment...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-13

... Chloride and Copolymer Production, Primary Copper Smelting, Secondary Copper Smelting, and Primary... www.regulations.gov . Title: NESHAP for Area Sources: Polyvinyl Chloride and Copolymer Production.... Respondents/Affected Entities: Owners or operators of polyvinyl chloride and copolymer, primary copper smelter...

Potential sources of nitrous acid (HONO) and their impacts on ozone: A WRF-Chem study in a polluted subtropical region

NASA Astrophysics Data System (ADS)

Zhang, Li; Wang, Tao; Zhang, Qiang; Zheng, Junyu; Xu, Zheng; Lv, Mengyao

2016-04-01

Current chemical transport models commonly undersimulate the atmospheric concentration of nitrous acid (HONO), which plays an important role in atmospheric chemistry, due to the lack or inappropriate representations of some sources in the models. In the present study, we parameterized up-to-date HONO sources into a state-of-the-art three-dimensional chemical transport model (Weather Research and Forecasting model coupled with Chemistry: WRF-Chem). These sources included (1) heterogeneous reactions on ground surfaces with the photoenhanced effect on HONO production, (2) photoenhanced reactions on aerosol surfaces, (3) direct vehicle and vessel emissions, (4) potential conversion of NO2 at the ocean surface, and (5) emissions from soil bacteria. The revised WRF-Chem was applied to explore the sources of the high HONO concentrations (0.45-2.71 ppb) observed at a suburban site located within complex land types (with artificial land covers, ocean, and forests) in Hong Kong. With the addition of these sources, the revised model substantially reproduced the observed HONO levels. The heterogeneous conversions of NO2 on ground surfaces dominated HONO sources contributing about 42% to the observed HONO mixing ratios, with emissions from soil bacterial contributing around 29%, followed by the oceanic source (~9%), photochemical formation via NO and OH (~6%), conversion on aerosol surfaces (~3%), and traffic emissions (~2%). The results suggest that HONO sources in suburban areas could be more complex and diverse than those in urban or rural areas and that the bacterial and/or ocean processes need to be considered in HONO production in forested and/or coastal areas. Sensitivity tests showed that the simulated HONO was sensitive to the uptake coefficient of NO2 on the surfaces. Incorporation of the aforementioned HONO sources significantly improved the simulations of ozone, resulting in increases of ground-level ozone concentrations by 6-12% over urban areas in Hong Kong and the Pearl River Delta region. This result highlights the importance of accurately representing HONO sources in simulations of secondary pollutants over polluted regions.

Can the source–sink hypothesis explain macrofaunal abundance patterns in the abyss? A modelling test

PubMed Central

Hardy, Sarah M.; Smith, Craig R.; Thurnherr, Andreas M.

2015-01-01

Low food availability is a major structuring force in deep-sea benthic communities, sustaining only very low densities of organisms in parts of the abyss. These low population densities may result in an Allee effect, whereby local reproductive success is inhibited, and populations are maintained by larval dispersal from bathyal slopes. This slope–abyss source–sink (SASS) hypothesis suggests that the abyssal seafloor constitutes a vast sink habitat with macrofaunal populations sustained only by an influx of larval ‘refugees' from source areas on continental slopes, where higher productivity sustains greater population densities. Abyssal macrofaunal population densities would thus be directly related to larval inputs from bathyal source populations. We evaluate three predictions derived from the SASS hypothesis: (i) slope-derived larvae can be passively transported to central abyssal regions within a single larval period, (ii) projected larval export from slopes to the abyss reproduces global patterns of macrofaunal abundance and (iii) macrofaunal abundance decreases with distance from the continental slope. We find that abyssal macrofaunal populations are unlikely to be sustained solely through influx of larvae from slope sources. Rather, local reproduction probably sustains macrofaunal populations in relatively high-productivity abyssal areas, which must also be considered as potential larval source areas for more food-poor abyssal regions. PMID:25948686

Wet deposition of mercury at a New York state rural site: Concentrations, fluxes, and source areas

NASA Astrophysics Data System (ADS)

Lai, Soon-onn; Holsen, Thomas M.; Hopke, Philip K.; Liu, Peng

Event-based mercury (Hg) precipitation samples were collected with a modified MIC-B sampler between September 2003 and April 2005 at Potsdam, NY to investigate Hg in wet deposition and identify potential source areas using the potential source contribution function (PCSF) and residence time weighted concentration (RTWC) models. The volume-weighted mean (VWM) concentration and wet deposition flux were 5.5ngL-1 and 7.6μgm-2 during the study period, and 5.5ngL-1 and 5.9μgm-2 in 2004, respectively, and show seasonal trends with larger values in the spring and summer. The PSCF model results matched known source areas based on an emission inventory better than did the RTWC results based on the spatial correlation index. Both modeling results identified large Hg source areas that contain a number of coal-fired power plants located in the Upper Ohio River Valley and in southeastern Michigan, as well as in Quebec and Ontario where there are metal production facilities, waste incinerators and paper mills. Emissions from the Atlantic Ocean were also determined to be a potential source.

Service area size assessment for evaluating the spatial scale of solid waste recovery chains: A territorial perspective.

PubMed

Tanguy, Audrey; Villot, Jonathan; Glaus, Mathias; Laforest, Valérie; Hausler, Robert

2017-06-01

Waste recovery is an integrated part of municipal solid waste management systems but its strategic planning is still challenging. In particular, the service area size of facilities is a sensitive issue since its calculation depends on various factors related to treatment technologies (output products) and territorial features (sources waste production and location). This work presents a systemic approach for the estimation of a chain's service area size, based on a balance between costs and recovery profits. The model assigns a recovery performance value to each source, which can be positive, neutral or negative. If it is positive, the source should be included in the facility's service area. Applied to the case of Montreal for food waste recovery by anaerobic digestion, the approach showed that at most 23 out of the 30 districts should be included in the service area, depending on the indicator, which represents around 127,000 t of waste recovered/year. Due to the systemic approach, these districts were not necessarily the closest to the facility. Moreover, for the Montreal case, changing the facility's location did not have a great influence on the optimal service area size, showing that the distance to the facility was not a decisive factor at this scale. However, replacing anaerobic digestion by a composting plant reduced the break-even transport distances and, thus, the number of sources worth collecting (around 68,500 t/year). In this way, the methodology, applied to different management strategies, gave a sense of the spatial dynamics involved in the recovery chain's design. The map of optimal supply obtained could be used to further analyse the feasibility of multi-site and/or multi-technology systems for the territory considered. Copyright © 2017 Elsevier Ltd. All rights reserved.

Subsistence Food Production Practices: An Approach to Food Security and Good Health.

PubMed

Rankoana, Sejabaledi A

2017-10-05

Food security is a prerequisite for health. Availability and accessibility of food in rural areas is mainly achieved through subsistence production in which community members use local practices to produce and preserve food. Subsistence food production ensures self-sufficiency and reduction of poverty and hunger. The main emphasis with the present study is examining subsistence farming and collection of edible plant materials to fulfill dietary requirements, thereby ensuring food security and good health. Data collected from a purposive sample show that subsistence crops produced in the home-gardens and fields, and those collected from the wild, are sources of grain, vegetables and legumes. Sources of grain and legumes are produced in the home-gardens and fields, whereas vegetables sources are mostly collected in the wild and fewer in the home-gardens. These food sources have perceived health potential in child and maternal care of primary health care.

Biogas and Hydrogen Systems Market Assessment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Milbrandt, Anelia; Bush, Brian; Melaina, Marc

2016-03-31

This analysis provides an overview of the market for biogas-derived hydrogen and its use in transportation applications. It examines the current hydrogen production technologies from biogas, capacity and production, infrastructure, potential and demand, as well as key market areas. It also estimates the production cost of hydrogen from biogas and provides supply curves at a national level and at point source.

Directory of Assistive Technology: Data Sources.

ERIC Educational Resources Information Center

Council for Exceptional Children, Reston, VA. Center for Special Education Technology.

The annotated directory describes in detail both on-line and print databases in the area of assistive technology for individuals with disabilities. For each database, the directory provides the name, address, and telephone number of the sponsoring organization; disability areas served; number of hardware and software products; types of information…

Genetic improvement of plants for enhanced bio-ethanol production.

PubMed

Saha, Sanghamitra; Ramachandran, Srinivasan

2013-04-01

The present world energy situation urgently requires exploring and developing alternate, sustainable sources for fuel. Biofuels have proven to be an effective energy source but more needs to be produced to meet energy goals. Whereas first generation biofuels derived from mainly corn and sugarcane continue to be used and produced, the contentious debate between "feedstock versus foodstock" continues. The need for sources that can be grown under different environmental conditions has led to exploring newer sources. Lignocellulosic biomass is an attractive source for production of biofuel, but pretreatment costs to remove lignin are high and the process is time consuming. Genetically modified plants that have increased sugar or starch content, modified lignin content, or produce cellulose degrading enzymes are some options that are being explored and tested. This review focuses on current research on increasing production of biofuels by genetic engineering of plants to have desirable characteristics. Recent patents that have been filed in this area are also discussed.

Wind erosion of cropland in the northwestern Tarim Basin

USDA-ARS?s Scientific Manuscript database

The Aksu region within the Tarim Basin is a major source of windblown dust due to aridity and vast areas under intensive irrigated crop production. Despite the importance of crop production to the local economy and sustenance, little is known about the amount of soil eroded by wind from agricultural...

Validation of Assessment Methods for Production Scale Girth Welding of High Strength Steel Pipelines with Multiple Pipe Sources

DOT National Transportation Integrated Search

2012-03-01

There is an increasing need to deliver energy from sources in remote areas to demand centers. For example, in North America, the delivery of gas from Alaska to demand centers in the lower 48 states is of major economic and strategic interest. This wi...

40 CFR 63.11395 - What are the standards and compliance requirements for existing sources?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Modacrylic Fibers Production Area Sources Standards and Compliance Requirements § 63.11395 What are the... enclosure systems that collect the gases and fumes containing acrylonitrile (AN) released from... through a closed vent system to a control device. (b) Except as provided in paragraph (b)(3) of this...

40 CFR 63.11395 - What are the standards and compliance requirements for existing sources?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Modacrylic Fibers Production Area Sources Standards and Compliance Requirements § 63.11395 What are the... enclosure systems that collect the gases and fumes containing acrylonitrile (AN) released from... through a closed vent system to a control device. (b) Except as provided in paragraph (b)(3) of this...

Lead and cadmium content in human milk from the Northern Adriatic area of Croatia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frkovic, A.; Kras, M.; Alebic-Juretic, A.

Though occupational exposure to toxic metals (lead, cadmium) is well documented, harmful effects of environmental exposure to lower levels of these two metals is still under investigation. Most toxic metals are emitted by human activities and the atmosphere is the main transport route for these elements. According to some authors, 332 358 t of lead and 7570 t of cadmium were emitted in the atmosphere from anthropogenic sources in 1983. The principle source of lead is traffic, e.g. leaded petrol, still widely used in Croatia, as well as coal combustion, iron and steal production. Volcanic activity, zinc production and wastemore » incineration are the main sources of cadmium. Recent study indicates that traffic could also be the main source of cadmium found along busy streets. Chronic lead exposure at low levels is associated with adverse health effects especially in fetus and young children. This study examines lead and cadmium levels in breast milk from nursing women living in the Northern Adriatic area of Croatia. 15 refs., 2 tabs.« less

Relative importance of atmospheric and riverine mercury sources to the northern Gulf of Mexico.

PubMed

Rice, Glenn E; Senn, David B; Shine, James P

2009-01-15

A box model was developed to quantify the major sources and dominant fates of inorganic mercury (Hg) in the Mississippi River-influenced area of the northern Gulf of Mexico (nGOM). Riverine (75%) and direct atmospheric deposition (25%) deliver 9.7 t Hg y(-1) to this productive fishery; most (80%) accumulates in bottom sediments where it can be methylated and enter foodwebs. Although riverine inputs dominate atmospheric deposition, 75% of the riverine sediment-associated Hg accumulates in only approximately 8% of the study area. Atmospheric deposition can explain most of the Hg accumulating in sediments of the remaining area. Considering the differences in temporal responsiveness of riverine (centuries) and atmospheric (years) Hg inputs to anthropogenic emissions changes, the spatial limits of the riverine Hg source andthe potential dominance of atmospheric deposition over large areas could have implications for the timing of benefits from policies reducing anthropogenic Hg emissions.

Error Analysis of CM Data Products Sources of Uncertainty

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hunt, Brian D.; Eckert-Gallup, Aubrey Celia; Cochran, Lainy Dromgoole

This goal of this project is to address the current inability to assess the overall error and uncertainty of data products developed and distributed by DOE’s Consequence Management (CM) Program. This is a widely recognized shortfall, the resolution of which would provide a great deal of value and defensibility to the analysis results, data products, and the decision making process that follows this work. A global approach to this problem is necessary because multiple sources of error and uncertainty contribute to the ultimate production of CM data products. Therefore, this project will require collaboration with subject matter experts across amore » wide range of FRMAC skill sets in order to quantify the types of uncertainty that each area of the CM process might contain and to understand how variations in these uncertainty sources contribute to the aggregated uncertainty present in CM data products. The ultimate goal of this project is to quantify the confidence level of CM products to ensure that appropriate public and worker protections decisions are supported by defensible analysis.« less

Impact of emissions from natural gas production facilities on ambient air quality in the Barnett Shale area: a pilot study.

PubMed

Zielinska, Barbara; Campbell, Dave; Samburova, Vera

2014-12-01

Rapid and extensive development of shale gas resources in the Barnett Shale region of Texas in recent years has created concerns about potential environmental impacts on water and air quality. The purpose of this study was to provide a better understanding of the potential contributions of emissions from gas production operations to population exposure to air toxics in the Barnett Shale region. This goal was approached using a combination of chemical characterization of the volatile organic compound (VOC) emissions from active wells, saturation monitoring for gaseous and particulate pollutants in a residential community located near active gas/oil extraction and processing facilities, source apportionment of VOCs measured in the community using the Chemical Mass Balance (CMB) receptor model, and direct measurements of the pollutant gradient downwind of a gas well with high VOC emissions. Overall, the study results indicate that air quality impacts due to individual gas wells and compressor stations are not likely to be discernible beyond a distance of approximately 100 m in the downwind direction. However, source apportionment results indicate a significant contribution to regional VOCs from gas production sources, particularly for lower-molecular-weight alkanes (< C6). Although measured ambient VOC concentrations were well below health-based safe exposure levels, the existence of urban-level mean concentrations of benzene and other mobile source air toxics combined with soot to total carbon ratios that were high for an area with little residential or commercial development may be indicative of the impact of increased heavy-duty vehicle traffic related to gas production. Implications: Rapid and extensive development of shale gas resources in recent years has created concerns about potential environmental impacts on water and air quality. This study focused on directly measuring the ambient air pollutant levels occurring at residential properties located near natural gas extraction and processing facilities, and estimating the relative contributions from gas production and motor vehicle emissions to ambient VOC concentrations. Although only a small-scale case study, the results may be useful for guidance in planning future ambient air quality studies and human exposure estimates in areas of intensive shale gas production.

40 CFR 63.11420 - Who implements and enforces this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production and Fabrication Area Sources Other Requirements and Information § 63.11420 Who...

40 CFR 63.11420 - Who implements and enforces this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production and Fabrication Area Sources Other Requirements and Information § 63.11420 Who...

40 CFR 63.11420 - Who implements and enforces this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production and Fabrication Area Sources Other Requirements and Information § 63.11420 Who...

40 CFR 63.11420 - Who implements and enforces this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production and Fabrication Area Sources Other Requirements and Information § 63.11420 Who...

40 CFR 63.11420 - Who implements and enforces this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production and Fabrication Area Sources Other Requirements and Information § 63.11420 Who...

Real-time continuous nitrate monitoring in Illinois in 2013

USGS Publications Warehouse

Warner, Kelly L.; Terrio, Paul J.; Straub, Timothy D.; Roseboom, Donald; Johnson, Gary P.

2013-01-01

Many sources contribute to the nitrogen found in surface water in Illinois. Illinois is located in the most productive agricultural area in the country, and nitrogen fertilizer is commonly used to maximize corn production in this area. Additionally, septic/wastewater systems, industrial emissions, and lawn fertilizer are common sources of nitrogen in urban areas of Illinois. In agricultural areas, the use of fertilizer has increased grain production to meet the needs of a growing population, but also has resulted in increases in nitrogen concentrations in many streams and aquifers (Dubrovsky and others, 2010). The urban sources can increase nitrogen concentrations, too. The Federal limit for nitrate nitrogen in water that is safe to drink is 10 milligrams per liter (mg/L) (http://water.epa.gov/drink/contaminants/basicinformation/nitrate.cfm, accessed on May 24, 2013). In addition to the concern with nitrate nitrogen in drinking water, nitrogen, along with phosphorus, is an aquatic concern because it feeds the intensive growth of algae that are responsible for the hypoxic zone in the Gulf of Mexico. The largest nitrogen flux to the waters feeding the Gulf of Mexico is from Illinois (Alexander and others, 2008). Most studies of nitrogen in surface water and groundwater include samples for nitrate nitrogen collected weekly or monthly, but nitrate concentrations can change rapidly and these discrete samples may not capture rapid changes in nitrate concentrations that can affect human and aquatic health. Continuous monitoring for nitrate could inform scientists and water-resource managers of these changes and provide information on the transport of nitrate in surface water and groundwater.

Spatio-temporal distribution of perchlorate and its toxicity in Hydrilla verticillata.

PubMed

Vijaya Nadaraja, Anupama; Pushpangadhan Saraswathy, Divya; Cheruvathery Ravindran, Sayana; Mariya, Anie; Godwin Russel, Jasmin; Selvanesan, Pradeep; Pereira, Benno; Bhaskaran, Krishnakumar

2017-10-01

The spatio-temporal distribution of perchlorate in water sources around an ammonium perchlorate production unit and its toxicity response on a dominant aquatic plant, Hydrilla verticillata are reported in this study. Samples (n=453) from ground water (open well) and surface water sources within 5km from the production unit over a period of 12 months (2014, June - 2015, May) were screened for ClO 4 - . During the period, ClO 4 - concentration in ground water samples close to the production unit increased to >40,000μg/L, and ClO 4 - was detected at 1740μg/L in well water 1.6km away from the production unit. A community pond in the area also showed an increase in ClO 4 - level up to 29,000μg/L. In all water sources, ClO 4 - level was maximum during the rainy season (July, monsoon). A natural degradation of ClO 4 - was not observed in the area as evident from its persistent level and spreading to more areas. H. verticillata, the dominant vegetation in the pond exhibited severe toxic response like massive decay and loss of photosynthetic pigments such as chlorophyll and carotene due to ClO 4 - exposure. The plant accumulated ClO 4 - up to 60 ± 0.8mg/kg wet weight with a Bio-Concentration Factor 2.06±0.005. This is the first report on spatio-temporal distribution of ClO 4 - at higher levels in a natural environment and its toxicity response to plants under natural condition. Copyright © 2017 Elsevier Inc. All rights reserved.

Biogeochemical snapshot of an urban water system: The Anacostia River, Washington DC

NASA Astrophysics Data System (ADS)

Macavoy, S.; Ewers, E.; Bushaw-Newton, K.

2007-12-01

Highly urbanized and contaminated with PAHs, heavy metals, and sewage, the Anacostia River flows through Maryland and Washington, DC into the tidal Potomac River. Efforts have been underway to assess the river's ecological integrity and to determine the extent of anthropogenic influences. This study examines the nutrients, bacterial biomarkers, organic material, and carbon, nitrogen and sulfur sources in the Anacostia. High biological oxygen demand and low nitrogen (0.33-0.56 mg /L)/phosphorus (0.014 - 0.021 mg/L) concentrations were observed in three areas of the river. Bacterial activity based on carbon source utilization was higher in sediment samples than in water column samples. While bacterial abundances were decreased in downstream areas of sediment; abundances increased in downstream areas in the water column. Downstream sites had higher nutrient concentrations and dissolved organic carbon (up to 13.7 mg/L). Odd-chain length and branched fatty acids (FAs) in the sediments indicated bacterial sources, but long chain FAs indicative of terrestrial primary production were also abundant in some sediments. Also dominant among methyl esters and ketones in some sediment and water column samples was methyl isobutyl ketone, a common industrial solvent and combustion by-product. Sediment carbon stable isotope analyses show a mix of autochthonous and allochthonous derived materials, but most carbon was derived from terrestrial sources (-23.3 to -31.7°). Sediment nitrogen stable isotopes ranged from -5.4 to. 5.6, showing nitrate uptake by plants and also recycling of nitrogen within the river. Sulfur sources were generally between 3 and -5, reflecting local sulfate sources and anaerobic sulfate reduction.

Selenium content of foods purchased or produced in Ohio.

PubMed

Snook, J T; Kinsey, D; Palmquist, D L; DeLany, J P; Vivian, V M; Moxon, A L

1987-06-01

Approximately 450 samples of about 100 types of foods consumed by rural and urban Ohioans were analyzed for selenium. Meat, dairy products, eggs, and grain products produced in Ohio have considerably lower selenium content than corresponding products produced in high selenium areas, such as South Dakota. Retail Ohio foods with interregional distribution tended to be higher in selenium content than corresponding foods produced in Ohio. Best sources of selenium in Ohio foods commonly consumed were meat and pasta products. Poor sources of selenium were fruits, most vegetables, candies, sweeteners, and alcoholic and nonalcoholic beverages. Establishment of an accurate data base for selenium depends on knowledge of the interregional distribution of foods, the selenium content of foods at their production site, and the selenium content of foods with wide local distribution.

Antibiotic Resistance in Animal and Environmental Samples Associated with Small-Scale Poultry Farming in Northwestern Ecuador

PubMed Central

Braykov, Nikolay P.; Eisenberg, Joseph N. S.; Grossman, Marissa; Zhang, Lixin; Vasco, Karla; Cevallos, William; Muñoz, Diana; Acevedo, Andrés; Moser, Kara A.; Marrs, Carl F.; Trostle, James; Trueba, Gabriel

2016-01-01

ABSTRACT The effects of animal agriculture on the spread of antibiotic resistance (AR) are cross-cutting and thus require a multidisciplinary perspective. Here we use ecological, epidemiological, and ethnographic methods to examine populations of Escherichia coli circulating in the production poultry farming environment versus the domestic environment in rural Ecuador, where small-scale poultry production employing nontherapeutic antibiotics is increasingly common. We sampled 262 “production birds” (commercially raised broiler chickens and laying hens) and 455 “household birds” (raised for domestic use) and household and coop environmental samples from 17 villages between 2010 and 2013. We analyzed data on zones of inhibition from Kirby-Bauer tests, rather than established clinical breakpoints for AR, to distinguish between populations of organisms. We saw significantly higher levels of AR in bacteria from production versus household birds; resistance to either amoxicillin-clavulanate, cephalothin, cefotaxime, and gentamicin was found in 52.8% of production bird isolates and 16% of household ones. A strain jointly resistant to the 4 drugs was exclusive to a subset of isolates from production birds (7.6%) and coop surfaces (6.5%) and was associated with a particular purchase site. The prevalence of AR in production birds declined with bird age (P < 0.01 for all antibiotics tested except tetracycline, sulfisoxazole, and trimethoprim-sulfamethoxazole). Farming status did not impact AR in domestic environments at the household or village level. Our results suggest that AR associated with small-scale poultry farming is present in the immediate production environment and likely originates from sources outside the study area. These outside sources might be a better place to target control efforts than local management practices. IMPORTANCE In developing countries, small-scale poultry farming employing antibiotics as growth promoters is being advanced as an inexpensive source of protein and income. Here, we present the results of a large ecoepidemiological study examining patterns of antibiotic resistance (AR) in E. coli isolates from small-scale poultry production environments versus domestic environments in rural Ecuador, where such backyard poultry operations have become established over the past decade. Our previous research in the region suggests that introduction of AR bacteria through travel and commerce may be an important source of AR in villages of this region. This report extends the prior analysis by examining small-scale production chicken farming as a potential source of resistant strains. Our results suggest that AR strains associated with poultry production likely originate from sources outside the study area and that these outside sources might be a better place to target control efforts than local management practices. PMID:27303705

Overview of the SHARP campaign: Motivation, design, and major outcomes

NASA Astrophysics Data System (ADS)

Olaguer, Eduardo P.; Kolb, Charles E.; Lefer, Barry; Rappenglück, Bernhard; Zhang, Renyi; Pinto, Joseph P.

2014-03-01

The Study of Houston Atmospheric Radical Precursors (SHARP) was a field campaign developed by the Houston Advanced Research Center on behalf of the Texas Environmental Research Consortium. SHARP capitalized on previous research associated with the Second Texas Air Quality Study and the development of the State Implementation Plan (SIP) for the Houston-Galveston-Brazoria (HGB) ozone nonattainment area. These earlier studies pointed to an apparent deficit in ozone production in the SIP attainment demonstration model despite the enhancement of simulated emissions of highly reactive volatile organic compounds in accordance with the findings of the original Texas Air Quality Study in 2000. The scientific hypothesis underlying the SHARP campaign was that there are significant undercounted primary and secondary sources of the radical precursors, formaldehyde, and nitrous acid, in both heavily industrialized and more typical urban areas of Houston. These sources, if properly taken into account, could increase the production of ozone in the SIP model and the simulated efficacy of control strategies designed to bring the HGB area into ozone attainment. This overview summarizes the precursor studies and motivations behind SHARP, as well as the overall experimental design and major findings of the 2009 field campaign. These findings include significant combustion sources of formaldehyde at levels greater than accounted for in current point source emission inventories; the underestimation of formaldehyde and nitrous acid emissions, as well as CO/NOx and NO2/NOx ratios, by mobile source models; and the enhancement of nitrous acid by atmospheric organic aerosol.

Compilation of geospatial data for the mineral industries and related infrastructure of Latin America and the Caribbean

USGS Publications Warehouse

Baker, Michael S.; Buteyn, Spencer D.; Freeman, Philip A.; Trippi, Michael H.; Trimmer III, Loyd M.

2017-07-31

This report describes the U.S. Geological Survey’s (USGS) ongoing commitment to its mission of understanding the nature and distribution of global mineral commodity supply chains by updating and publishing the georeferenced locations of mineral commodity production and processing facilities, mineral exploration and development sites, and mineral commodity exporting ports in Latin America and the Caribbean. The report includes an overview of data sources and an explanation of the geospatial PDF map format.The geodatabase and geospatial data layers described in this report create a new geographic information product in the form of a geospatial portable document format (PDF) map. The geodatabase contains additional data layers from USGS, foreign governmental, and open-source sources as follows: (1) coal occurrence areas, (2) electric power generating facilities, (3) electric power transmission lines, (4) hydrocarbon resource cumulative production data, (5) liquefied natural gas terminals, (6) oil and gas concession leasing areas, (7) oil and gas field center points, (8) oil and gas pipelines, (9) USGS petroleum provinces, (10) railroads, (11) recoverable proven plus probable hydrocarbon resources, (12) major cities, (13) major rivers, and (14) undiscovered porphyry copper tracts.

Solution of multi-element LED light sources development automation problem

NASA Astrophysics Data System (ADS)

Chertov, Aleksandr N.; Gorbunova, Elena V.; Korotaev, Valery V.; Peretyagin, Vladimir S.

2014-09-01

The intensive development of LED technologies resulted in the creation of multicomponent light sources in the form of controlled illumination devices based on usage of mentioned LED technologies. These light sources are used in different areas of production (for example, in the food industry for sorting products or in the textile industry for quality control, etc.). The use of LED lighting products in the devices used in specialized lighting, became possible due to wide range of colors of light, LED structures (which determines the direction of radiation, the spatial distribution and intensity of the radiation, electrical, heat, power and other characteristics), and of course, the possibility of obtaining any shade in a wide dynamic range of brightness values. LED-based lighting devices are notable for the diversity of parameters and characteristics, such as color radiation, location and number of emitters, etc. Although LED technologies have several advantages, however, they require more attention if you need to ensure a certain character of illumination distribution and/or distribution of the color picture at a predetermined distance (for example, at flat surface, work zone, area of analysis or observation). This paper presents software designed for the development of the multicomponent LED light sources. The possibility of obtaining the desired color and energy distribution at the zone of analysis by specifying the spatial parameters of the created multicomponent light source and using of real power, spectral and color parameters and characteristics of the LEDs is shown as well.

Reactive nitrogen oxides in the southeast United States national parks: source identification, origin, and process budget

NASA Astrophysics Data System (ADS)

Tong, Daniel Quansong; Kang, Daiwen; Aneja, Viney P.; Ray, John D.

2005-01-01

We present in this study both measurement-based and modeling analyses for elucidation of source attribution, influence areas, and process budget of reactive nitrogen oxides at two rural southeast United States sites (Great Smoky Mountains national park (GRSM) and Mammoth Cave national park (MACA)). Availability of nitrogen oxides is considered as the limiting factor to ozone production in these areas and the relative source contribution of reactive nitrogen oxides from point or mobile sources is important in understanding why these areas have high ozone. Using two independent observation-based techniques, multiple linear regression analysis and emission inventory analysis, we demonstrate that point sources contribute a minimum of 23% of total NOy at GRSM and 27% at MACA. The influence areas for these two sites, or origins of nitrogen oxides, are investigated using trajectory-cluster analysis. The result shows that air masses from the West and Southwest sweep over GRSM most frequently, while pollutants transported from the eastern half (i.e., East, Northeast, and Southeast) have limited influence (<10% out of all air masses) on air quality at GRSM. The processes responsible for formation and removal of reactive nitrogen oxides are investigated using a comprehensive 3-D air quality model (Multiscale Air Quality SImulation Platform (MAQSIP)). The NOy contribution associated with chemical transformations to NOz and O3, based on process budget analysis, is as follows: 32% and 84% for NOz, and 26% and 80% for O3 at GRSM and MACA, respectively. The similarity between NOz and O3 process budgets suggests a close association between nitrogen oxides and effective O3 production at these rural locations.

40 CFR 63.11619 - Am I subject to this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

... chromium or a material containing manganese and is an area source of emissions of hazardous air pollutants... chromium or a material containing manganese is added, to the point where the finished animal feed product leaves the facility. This includes, but is not limited to, areas where materials containing chromium and...

40 CFR 63.11619 - Am I subject to this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

... chromium or a material containing manganese and is an area source of emissions of hazardous air pollutants... chromium or a material containing manganese is added, to the point where the finished animal feed product leaves the facility. This includes, but is not limited to, areas where materials containing chromium and...

40 CFR 63.11396 - What are the standards and compliance requirements for new sources?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Modacrylic Fibers Production Area Sources Standards and Compliance Requirements § 63.11396 What are the... through a closed vent system to any combination of control devices meeting the requirements for process... (b)(1), (2), or (3) of this section for each fiber spinning line that uses a spin dope produced from...

40 CFR 63.11396 - What are the standards and compliance requirements for new sources?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Modacrylic Fibers Production Area Sources Standards and Compliance Requirements § 63.11396 What are the... through a closed vent system to any combination of control devices meeting the requirements for process... (b)(1), (2), or (3) of this section for each fiber spinning line that uses a spin dope produced from...

Distribution of POPs, pesticides and antibiotic residues in organic honeys from different production areas.

PubMed

Chiesa, Luca Maria; Panseri, Sara; Nobile, Maria; Ceriani, Federica; Arioli, Francesco

2018-06-22

Demand for honey is increasing, especially if it is organic and if its nutritional properties are linked to untreated environments in order to guarantee quality for health. Sources of contamination of honey can be divided into environmental and apicultural. Therefore, the distribution of persistent organic pollutants, pesticides and antibiotic residues from geographical areas with different contamination sources (high anthropic impact, intensive farming, husbandry and low anthropic impact) was investigated in order to confirm the potential transfer of xenobiotics into the supply chain and to give beekeepers tools for the selection of areas dedicated to organic production. The presence of polychlorinated biphenyls, polybrominated diphenyl ether and polycyclic aromatic hydrocarbons was confirmed, not only in proximity to highly urbanised centres, where the concentrations were higher, but in all environment contexts, confirming their ubiquity. No antibiotics or neonicotinoids were detected in 95 organic honeys, demonstrating the absence of apicultural treatments and consequently the good quality of honey of different areas. These results are important due to the undefined regulatory European situation on honey antibiotic limits.[Figure: see text].

ENVIRONMENTAL TECHNOLOGY VERIFICATION REPORT. STORMWATER SOURCE AREA TREATMENT DEVICE. THE TERRE HILL CONCRETE PRODUCTS TERRE KLEEN™ 09

EPA Science Inventory

Verification testing of the Terre Hill Concrete Products Terre Kleen™ 09 was conducted on a 1.27 acre portion of the City of Harrisburg, Pennsylvania Department of Public Works facility. The Terre Kleen™ devices combines primary and secondary chambers, baffles, a screen, and incl...

The effects of tropospheric ozone on net primary production and implications for climate change

USDA-ARS?s Scientific Manuscript database

Tropospheric ozone (O3) is a global air pollutant that causes billions of dollars in lost plant productivity annually. It is an important anthropogenic greenhouse gas, and as a secondary air pollutant, can persist at high concentrations in rural areas far from industrial sources. Ozone reduces plant...

40 CFR 63.5870 - How do I calculate annual uncontrolled and controlled organic HAP emissions from my wet-out area...

Code of Federal Regulations, 2010 CFR

2010-07-01

... SOURCE CATEGORIES National Emissions Standards for Hazardous Air Pollutants: Reinforced Plastic... according to usage within each end product/thickness combination. (3) For each end product/thickness combination being produced, select the formula with the highest usage rate for testing. (4) If not already...

Stressing Out: Connecting Race, Gender, and Stress with Faculty Productivity

ERIC Educational Resources Information Center

Eagan, M. Kevin, Jr.; Garvey, Jason C.

2015-01-01

This study uses multilevel modeling to analyze data from a national sample of full-time, undergraduate faculty at four-year institutions to examine the connections among race, gender, sources of stress, and productivity in the areas of research, teaching, and service. We find that stress due to discrimination has particular negative salience for…

Generation of a U.S. national urban land use product

USGS Publications Warehouse

Falcone, James A.; Homer, Collin G.

2012-01-01

Characterization of urban land uses is essential for many applications. However, differentiating among thematically-detailed urban land uses (residential, commercial, industrial, institutional, recreational, etc.) over broad areas is challenging, in part because image-based solutions are not ideal for establishing the contextual basis for identifying economic function and use. At present no current United States national-scale mapping exists for urban land uses similar to the classical Anderson Level II classification. This paper describes a product that maps urban land uses, and is linked to and corresponds with the National Land Cover Database (NLCD) 2006. In this product, NLCD urban pixels, in addition to their current imperviousness intensity classification, are assigned one of nine urban use classes based on information drawn from multiple data sources. These sources include detailed infrastructure information, population characteristics, and historical land use. The result is a method for creating a 30 m national-scale grid providing thematically-detailed urban land use information which complements the NLCD. Initial results for 10 major metropolitan areas are provided as an on-line link. Accuracy assessment of initial products yielded an overall accuracy of 81.6 percent.

Long-pulse production of high current negative ion beam by using actively temperature controlled plasma grid for JT-60SA negative ion source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kojima, A.; Hanada, M.; Yoshida, M.

2015-04-08

The temperature control system of the large-size plasma grid has been developed to realize the long pulse production of high-current negative ions for JT-60SA. By using this prototype system for the JT-60SA ion source, 15 A negative ions has been sustained for 100 s for the first time, which is three times longer than that obtained in JT-60U. In this system, a high-temperature fluorinated fluid with a high boiling point of 270 degree Celsius is circulated in the cooling channels of the plasma grids (PG) where a cesium (Cs) coverage is formed to enhance the negative ion production. Because themore » PG temperature control had been applied to only 10% of the extraction area previously, the prototype PG with the full extraction area (110 cm × 45 cm) was developed to increase the negative ion current in this time. In the preliminary results of long pulse productions of high-current negative ions at a Cs conditioning phase, the negative ion production was gradually degraded in the last half of 100 s pulse where the temperature of an arc chamber wall was not saturated. From the spectroscopic measurements, it was found that the Cs flux released from the wall might affect to the negative ion production, which implied the wall temperature should be kept low to control the Cs flux to the PG for the long-pulse high-current production. The obtained results of long-pulse production and the PG temperature control method contributes the design of the ITER ion source.« less

40 CFR 63.11418 - What General Provisions apply to this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production and Fabrication Area Sources Other Requirements and Information § 63.11418 What General...

40 CFR 63.11418 - What General Provisions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production and Fabrication Area Sources Other Requirements and Information § 63.11418 What General...

40 CFR 63.11418 - What General Provisions apply to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production and Fabrication Area Sources Other Requirements and Information § 63.11418 What General...

40 CFR 63.11418 - What General Provisions apply to this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production and Fabrication Area Sources Other Requirements and Information § 63.11418 What General...

40 CFR 63.11418 - What General Provisions apply to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Flexible Polyurethane Foam Production and Fabrication Area Sources Other Requirements and Information § 63.11418 What General...

Improved Dust Forecast Products for Southwest Asia Forecasters through Dust Source Database Advancements

NASA Astrophysics Data System (ADS)

Brooks, G. R.

2011-12-01

Dust storm forecasting is a critical part of military theater operations in Afghanistan and Iraq as well as other strategic areas of the globe. The Air Force Weather Agency (AFWA) has been using the Dust Transport Application (DTA) as a forecasting tool since 2001. Initially developed by The Johns Hopkins University Applied Physics Laboratory (JHUAPL), output products include dust concentration and reduction of visibility due to dust. The performance of the products depends on several factors including the underlying dust source database, treatment of soil moisture, parameterization of dust processes, and validity of the input atmospheric model data. Over many years of analysis, seasonal dust forecast biases of the DTA have been observed and documented. As these products are unique and indispensible for U.S. and NATO forces, amendments were required to provide the best forecasts possible. One of the quickest ways to scientifically address the dust concentration biases noted over time was to analyze the weaknesses in, and adjust the dust source database. Dust source database strengths and weaknesses, the satellite analysis and adjustment process, and tests which confirmed the resulting improvements in the final dust concentration and visibility products will be shown.

Estimation of source locations of total gaseous mercury measured in New York State using trajectory-based models

NASA Astrophysics Data System (ADS)

Han, Young-Ji; Holsen, Thomas M.; Hopke, Philip K.

Ambient gaseous phase mercury concentrations (TGM) were measured at three locations in NY State including Potsdam, Stockton, and Sterling from May 2000 to March 2005. Using these data, three hybrid receptor models incorporating backward trajectories were used to identify source areas for TGM. The models used were potential source contribution function (PSCF), residence time weighted concentration (RTWC), and simplified quantitative transport bias analysis (SQTBA). Each model was applied using multi-site measurements to resolve the locations of important mercury sources for New York State. PSCF results showed that southeastern New York, Ohio, Indiana, Tennessee, Louisiana, and Virginia were important TGM source areas for these sites. RTWC identified Canadian sources including the metal production facilities in Ontario and Quebec, but US regional sources including the Ohio River Valley were also resolved. Sources in southeastern NY, Massachusetts, western Pennsylvania, Indiana, and northern Illinois were identified to be significant by SQTBA. The three modeling results were combined to locate the most important probable source locations, and those are Ohio, Indiana, Illinois, and Wisconsin. The Atlantic Ocean was suggested to be a possible source as well.

Sources of sedimentary PAHs in tropical Asian waters: differentiation between pyrogenic and petrogenic sources by alkyl homolog abundance.

PubMed

Saha, Mahua; Togo, Ayako; Mizukawa, Kaoruko; Murakami, Michio; Takada, Hideshige; Zakaria, Mohamad P; Chiem, Nguyen H; Tuyen, Bui Cach; Prudente, Maricar; Boonyatumanond, Ruchaya; Sarkar, Santosh Kumar; Bhattacharya, Badal; Mishra, Pravakar; Tana, Touch Seang

2009-02-01

We collected surface sediment samples from 174 locations in India, Indonesia, Malaysia, Thailand, Vietnam, Cambodia, Laos, and the Philippines and analyzed them for polycyclic aromatic hydrocarbons (PAHs) and hopanes. PAHs were widely distributed in the sediments, with comparatively higher concentrations in urban areas (Sigma PAHs: approximately 1000 to approximately 100,000 ng/g-dry) than in rural areas ( approximately 10 to approximately 100g-dry), indicating large sources of PAHs in urban areas. To distinguish petrogenic and pyrogenic sources of PAHs, we calculated the ratios of alkyl PAHs to parent PAHs: methylphenanthrenes to phenanthrene (MP/P), methylpyrenes+methylfluoranthenes to pyrene+fluoranthene (MPy/Py), and methylchrysenes+methylbenz[a]anthracenes to chrysene+benz[a]anthracene (MC/C). Analysis of source materials (crude oil, automobile exhaust, and coal and wood combustion products) gave thresholds of MP/P=0.4, MPy/Py=0.5, and MC/C=1.0 for exclusive combustion origin. All the combustion product samples had the ratios of alkyl PAHs to parent PAHs below these threshold values. Contributions of petrogenic and pyrogenic sources to the sedimentary PAHs were uneven among the homologs: the phenanthrene series had a greater petrogenic contribution, whereas the chrysene series had a greater pyrogenic contribution. All the Indian sediments showed a strong pyrogenic signature with MP/P approximately 0.5, MPy/Py approximately 0.1, and MC/C approximately 0.2, together with depletion of hopanes indicating intensive inputs of combustion products of coal and/or wood, probably due to the heavy dependence on these fuels as sources of energy. In contrast, sedimentary PAHs from all other tropical Asian cities were abundant in alkylated PAHs with MP/P approximately 1-4, MPy/Py approximately 0.3-1, and MC/C approximately 0.2-1.0, suggesting a ubiquitous input of petrogenic PAHs. Petrogenic contributions to PAH homologs varied among the countries: largest in Malaysia whereas inferior in Laos. The higher abundance of alkylated PAHs together with constant hopane profiles suggests widespread inputs of automobile-derived petrogenic PAHs to Asian waters.

Total petroleum systems of the Bonaparte Gulf Basin area, Australia; Jurassic, Early Cretaceous-Mesozoic; Keyling, Hyland Bay-Permian; Milligans-Carboniferous, Permian

USGS Publications Warehouse

Bishop, M.G.

1999-01-01

The Bonaparte Gulf Basin Province (USGS #3910) of northern Australia contains three important hydrocarbon source-rock intervals. The oldest source-rock interval and associated reservoir rocks is the Milligans-Carboniferous, Permian petroleum system. This petroleum system is located at the southern end of Joseph Bonaparte Gulf and includes both onshore and offshore areas within a northwest to southeast trending Paleozoic rift that was initiated in the Devonian. The Milligans Formation is a Carboniferous marine shale that sources accumulations of both oil and gas in Carboniferous and Permian deltaic, marine shelf carbonate, and shallow to deep marine sandstones. The second petroleum system in the Paleozoic rift is the Keyling, Hyland Bay-Permian. Source rocks include Lower Permian Keyling Formation delta-plain coals and marginal marine shales combined with Upper Permian Hyland Bay Formation prodelta shales. These source-rock intervals provide gas and condensate for fluvial, deltaic, and shallow marine sandstone reservoirs primarily within several members of the Hyland Bay Formation. The Keyling, Hyland Bay-Permian petroleum system is located in the Joseph Bonaparte Gulf, north of the Milligans-Carboniferous, Permian petroleum system, and may extend northwest under the Vulcan graben sub-basin. The third and youngest petroleum system is the Jurassic, Early Cretaceous-Mesozoic system that is located seaward of Joseph Bonaparte Gulf on the Australian continental shelf, and trends southwest-northeast. Source-rock intervals in the Vulcan graben sub-basin include deltaic mudstones of the Middle Jurassic Plover Formation and organic-rich marine shales of the Upper Jurassic Vulcan Formation and Lower Cretaceous Echuca Shoals Formation. These intervals produce gas, oil, and condensate that accumulates in, shallow- to deep-marine sandstone reservoirs of the Challis and Vulcan Formations of Jurassic to Cretaceous age. Organic-rich, marginal marine claystones and coals of the Plover Formation (Lower to Upper Jurassic), combined with marine claystones of the Flamingo Group and Darwin Formation (Upper Jurassic to Lower Cretaceous) comprise the source rocks for the remaining area of the system. These claystones and coals source oil, gas, and condensate accumulations in reservoirs of continental to marine sandstones of the Plover Formation and Flamingo Group. Shales of the regionally distributed Lower Cretaceous Bathurst Island Group and intraformational shales act as seals for hydrocarbons trapped in anticlines and fault blocks, which are the major traps of the province. Production in the Bonaparte Gulf Basin Province began in 1986 using floating production facilities, and had been limited to three offshore fields located in the Vulcan graben sub-basin. Cumulative production from these fields totaled more than 124 million barrels of oil before the facilities were removed after production fell substantially in 1995. Production began in 1998 from three offshore wells in the Zone of Cooperation through floating production facilities. After forty years of exploration, a new infrastructure of pipelines and facilities are planned to tap already discovered offshore reserves and to support additional development.

Assessment of Climate Suitability of Maize in South Korea

NASA Astrophysics Data System (ADS)

Hyun, S.; Choi, D.; Seo, B.

2017-12-01

Assessing suitable areas for crops would be useful to design alternate cropping systems as an adaptation option to climate change adaptation. Although suitable areas could be identified by using a crop growth model, it would require a number of input parameters including cultivar and soil. Instead, a simple climate suitability model, e.g., EcoCrop model, could be used for an assessment of climate suitability for a major grain crop. The objective of this study was to assess of climate suitability for maize using the EcoCrop model under climate change conditions in Korea. A long term climate data from 2000 - 2100 were compiled from weather data source. The EcoCrop model implemented in R was used to determine climate suitability index at each grid cell. Overall, the EcoCrop model tended to identify suitable areas for maize production near the coastal areas whereas the actual major production areas located in inland areas. It is likely that the discrepancy between assessed and actual crop production areas would result from the socioeconomic aspects of maize production. Because the price of maize is considerably low, maize has been grown in an area where moisture and temperature conditions would be less than optimum. In part, a simple algorithm to predict climate suitability for maize would caused a relatively large error in climate suitability assessment under the present climate conditions. In 2050s, the climate suitability for maize increased in a large areas in southern and western part of Korea. In particular, the plain areas near the coastal region had considerably greater suitability index in the future compared with mountainous areas. The expansion of suitable areas for maize would help crop production policy making such as the allocation of rice production area for other crops due to considerably less demand for the rice in Korea.

Effect of calcium hydroxide application to cattle feedlot pens on Escherichia coli O157:H7 and total E. coli in pen surface manure

USDA-ARS?s Scientific Manuscript database

Introduction: Cattle and beef products are sources of the pathogen Escherichia coli O157:H7. Lime products have a long history of use in cattle production as disinfectants for sick pens, calving pens, and muddy areas, to control the spread of diseases. Lime may also be useful as a preharvest trea...

Pesticides residues and metals in plant products from agricultural area of Belgrade, Serbia.

PubMed

Ethorđević, Tijana; Ethurović, Rada

2012-03-01

The objective of study was to assess the levels of selected metals and pesticides in plant products from agricultural area of Belgrade, Serbia in order to indicate their possible sources and risks of contamination and to evaluate their sanitary probity and safety. The concentrations of cadmium, copper, iron, manganese, nickel, lead and zinc were below limits established by national and international regulations (maximum found concentrations were 0.028, 1.91, 11.16, 1.77, 0.605, 0.073 and 1.76 mg kg(-1) respectively). Only residue of one of examined pesticides was found in amount below MRL (bifenthrin 2.46 μg kg(-1)) in only one of analysed samples, while others were below detection limits. Obtained results indicate that crops from examined agricultural areas are unpolluted by contaminants used for plant protection and nutrition, indicating good agricultural practice regarding pesticides and fertilizer usage as well as moderate industrial production within examined areas.

Thermal-electric coupled-field finite element modeling and experimental testing of high-temperature ion sources for the production of radioactive ion beams

NASA Astrophysics Data System (ADS)

Manzolaro, M.; Meneghetti, G.; Andrighetto, A.; Vivian, G.; D'Agostini, F.

2016-02-01

In isotope separation on line facilities the target system and the related ion source are two of the most critical components. In the context of the selective production of exotic species (SPES) project, a 40 MeV 200 μA proton beam directly impinges a uranium carbide target, generating approximately 1013 fissions per second. The radioactive isotopes produced in this way are then directed to the ion source, where they can be ionized and finally accelerated to the subsequent areas of the facility. In this work both the surface ion source and the plasma ion source adopted for the SPES facility are presented and studied by means of numerical thermal-electric models. Then, numerical results are compared with temperature and electric potential difference measurements, and finally the main advantages of the proposed simulation approach are discussed.

Production of biodiesel from Coelastrella sp. microalgae

NASA Astrophysics Data System (ADS)

Mansur, Dieni; Fitriady, Muhammad Arifuddin; Susilaningsih, Dwi; Simanungkalit, Sabar Pangihutan

2017-11-01

Microalgae have a wide area of usage and one of them it can be used for biodiesel production. In biodiesel production, lipids containing triglyceride or free fatty acid are converted into methyl ester through trans/esterification reactions. Lipids from microalgae can be extracted by acetone and dimethyl carbonate using homogenizer. Esterification of the lipids was investigated using various catalysts and source of methyl group. Activity of homogeneous catalyst such as HCl and H2SO4 and heterogeneous catalysts such as montmorillonit K-10 and ledgestone was investigated. Moreover, methanol and dimethyl carbonate as source of methyl group were also studied. Among of catalysts with methanol as source of methyl group, it was found that yield of crude biodiesel derived from Choelestrella Sp. microalgae was high over H2SO4 catalyst. On the other hand, over H2SO4 catalyst using dimethyl carbonate as source of methyl group, yield of crude biodiesel significant increase. However, FAME composition of crude biodiesel was high over HCl catalyst.

Simulation of multispectral multisource for device of consumer and medicine products analysis

NASA Astrophysics Data System (ADS)

Korolev, Timofey K.; Peretyagin, Vladimir S.

2017-06-01

One of the results of intensive development of led technology was the creation of a multi-component, managed devices and illumination/irradiation used in various fields of production (e.g., food industry analysis, food quality). The use of LEDs has become possible due to their structure determining spatial, energy, electrical, thermal and other characteristics. However, the development of the devices for illumination/irradiation require closer attention in the case if you want to provide precise illumination to the area of analysis, located at a specified distance from the radiation source. The present work is devoted to the development and modelling of a specialized source of radiation intended for solving problems of analysis of food products, medicines and water for suitability in drinking. In this work, we provided a mathematical model of spatial and spectral distribution of irridation from the source of infrared radiation ring structure. When you create this kind of source, you address factors such spectral component, the power settings, the spatial and energy components of the diodes.

Beyond imperviousness: A statistical approach to identifying functional differences between development morphologies on variable source area-type response in urbanized watersheds

NASA Astrophysics Data System (ADS)

Lim, T. C.

2016-12-01

Empirical evidence has shown linkages between urbanization, hydrological regime change, and degradation of water quality and aquatic habitat. Percent imperviousness, has long been suggested as the dominant source of these negative changes. However, recent research identifying alternative pathways of runoff production at the watershed scale have called into question percent impervious surface area's primacy in urban runoff production compared to other aspects of urbanization including change in vegetative cover, imported water and water leakages, and the presence of drainage infrastructure. In this research I show how a robust statistical methodology can detect evidence of variable source area (VSA)-type hydrologic response associated with incremental hydraulic connectivity in watersheds. I then use logistic regression to explore how evidence of VSA-type response relates to the physical and meterological characteristics of the watershed. I find that impervious surface area is highly correlated with development, but does not add significant explanatory power beyond percent developed in predicting VSA-type response. Other aspects of development morphology, including percent developed open space and type of drainage infrastructure also do not add to the explanatory power of undeveloped land in predicting VSA-type response. Within only developed areas, the effect of developed open space was found to be more similar to that of total impervious area than to undeveloped land. These findings were consistent when tested across a national cross-section of urbanized watersheds, a higher resolution dataset of Baltimore Metropolitan Area watersheds, and a subsample of watersheds confirmed not to be served by combined sewer systems. These findings suggest that land development policies that focus on lot coverage should be revisited, and more focus should be placed on preserving native vegetation and soil conditions alongside development.

Contamination source review for Building E2370, Edgewood Area, Aberdeen Proving Ground, Maryland

DOE Office of Scientific and Technical Information (OSTI.GOV)

O`Reilly, D.P.; Glennon, M.A.; Draugelis, A.K.

1995-09-01

The US Army Aberdeen Proving Ground (APG) commissioned Argonne National Laboratory (ANL) to conduct a contamination source review to identify and define areas of toxic or hazardous contaminants and to assess the physical condition and accessibility of APG buildings. The information obtained from this review may be used to assist the US Army in planning for the future use or disposition of the buildings. The contamination source review consisted of the following tasks: historical records search, physical inspection, photographic documentation, and geophysical investigation. This report provides the results of the contamination source review for Building E2370. Many of the APGmore » facilities constructed between 1917 and the 1960s are no longer used because of obsolescence and their poor state of repair. Because many of these buildings were used for research, development, testing, and/or pilot-scale production of chemical warfare agents and other military substances, the potential exists for portions of the buildings to be contaminated with these substances, their degradation products, and other laboratory or industrial chemicals. These buildings and associated structures or appurtenances may contribute to environmental concerns at APG.« less

Contamination source review for Building E3236, Edgewood Area, Aberdeen Proving Ground, Maryland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zellmer, S.D.; Smits, M.P.; Draugelis, A.K.

1995-09-01

The US Army Aberdeen Proving Ground (APG) commissioned Argonne National Laboratory (ANL) to conduct a contamination source review to identify and define areas of toxic or hazardous contaminants and to assess the physical condition and accessibility of APG buildings. The information obtained from the review may be used to assist the US Army in planning for the future use or disposition of the buildings. The contamination source review consisted of the following tasks: historical records search, physical inspection, photographic documentation, geophysical investigation, and review of available records regarding underground storage tanks associated with each building. This report provides the resultsmore » of the contamination source review for Building E3236. Many of the APG facilities constructed between 1917 and the 1960s are no longer used because of obsolescence and their poor state of repair. Because many of these buildings were used for research, development, testing, and/or pilot- scale production of chemical warfare agents and other military substances, the potential exists for portions of the buildings to be contaminated with these substances, their degradation products, and other laboratory or industrial chemicals. These buildings and associated structures or appurtenances may contribute to environmental concerns at APG.« less

Pocket Book to Enhance Knowledge and Attitude Regarding Prevention of Soil-Transmitted Helminth

ERIC Educational Resources Information Center

Sofiana, Liena; Ayu, Suci Musvita

2017-01-01

Indonesia, being a tropical area with high humidity, is a source of proliferation of worms. Soil-Transmitted Helminths infection is widespread in all rural and urban areas. Children who are infected usually experience lethargy, pallor or anemia, weight loss and listlessness, as well as decreasing their learning concentration and productivity.…

Silvics and silviculture in the southwestern pinyon-juniper woodlands

Treesearch

Gerald J. Gottfried

2004-01-01

Southwestern pinyon-juniper and juniper woodlands cover large areas of the western United States. The woodlands have been viewed as places of beauty and sources of valuable resource products or as weed-dominated landscapes that hinder the production of forage for livestock. They are special places because of the emotions and controversies that encircle their management...

Water and bed-sediment quality in the vicinity of Berlin Lake, Ohio, 2001

USGS Publications Warehouse

Darner, Robert A.

2002-01-01

Berlin Lake, in northeast Ohio, was created by the U.S. Army Corps of Engineers in 1943 and is used primarily for flood control for the upper reaches of the Mahoning River. The area surrounding and under the lake has been tapped for oil and natural gas production. One of the by-products of oil and gas production is concentrated salt water or brine, which might have an effect on the chemical quality of area potable-water sources. This report presents the results of a U.S. Geological Survey baseline study to collect current (2001) water and sediment-quality data and to characterize water quality in the Berlin Lake watershed. Chloride-to-bromide ratios were used to detect the presence of brine in water samples and to indicate possible adverse effects on water quality. Analyses of ground-water samples from domestic wells in the area indicate a source of chloride and bromide, but defining the source would require more data collection. Analyses of specific conductance and dissolved solids indicate that 78 percent (14 of 18) of the ground-water samples exceeded the Secondary Maximum Contaminant Level for dissolved solids in public water supplies of 500 milligrams per liter (mg/L), compared to 6 percent of samples exceeding 500 mg/L in two nearby studies. Surface water was analyzed twice, once each during low-flow and surface runoff conditions. A comparison of the 2001 data to historical chloride concentrations, accounting for seasonal changes, does not indicate an increase in chloride loads for surface water in the area of Berlin Lake. Polycyclic aromatic hydrocarbons were found in bed-sediment samples collected from the mouths of major tributaries to Berlin Lake. Polycyclic aromatic hydrocarbons are produced during the incomplete combustion of organic carbon materials such as wood and fossil fuels, and they are components of petroleum products.

APPLICATION OF AUDIO-MAGNETOTELLURIC SURVEYS ON SAO MIGUEL ISLAND, AZORES PORTUGAL.

USGS Publications Warehouse

Hoover, Donald; Rodrigues Da Silva, A.; Pierce, Herbert A.; Amaral, Roberto

1984-01-01

Geothermal exploration and development has been under way on Sao Miguel Island, Azores since 1975. This work had been restricted to the Fogo volcano, one of three dormant silicic volcanic centers on the island. The USGS in 1982 and 1983 conducted reconnaissance natural-source audio-magnetotelluric (AMT) surveys of all three silicic centers to evaluate the potential for geothermal systems at each and to demonstrate the utility of the method in areas of difficult terrain. Results on Fogo showed a low resistivity trend extending from the present production area upslope to the caldera boundary. The upper part of this trend is the upwelling zone of a thermal plume which supplies the production area. Further exploration and drilling are now planned for this area.

Trophic segregation of a fish assemblage along lateral depth gradients in a subtropical coastal lagoon revealed by stable isotope analyses.

PubMed

Mont'Alverne, R; Pereyra, P E R; Garcia, A M

2016-07-01

Stable isotopes were used to evaluate the hypothesis that fish assemblages occurring in shallow and deep areas of a large coastal lagoon are structured in partially segregated trophic modules with consumers showing contrasting reliance on benthic or pelagic food sources. The results revealed that fishes in deep areas were mainly dependent on particulate organic matter in the sediment (SOM), whereas emergent macrophytes were as important as SOM to fish consumers in shallow areas. Conceptual trophic diagrams depicting relationships among basal food sources and consumers in different regions of the lagoon highlighted the greater use of multiple basal food sources by more feeding mode functional guilds in shallow water compared with the use of predominantly benthic resources (SOM) in deep areas. The findings appear to corroborate the initial hypothesis and offer complementary perspectives in understanding the role of spatial ecology in structuring coastal ecosystem function and productivity. © 2016 The Fisheries Society of the British Isles.

Starch Product of Wild Plants Species Jalawure (Tacca leontopetaloides L.) Kuntze as The Source of Food Security in The South Coastal West Java

NASA Astrophysics Data System (ADS)

Wardah; Sambas, E. N.; Ridwan; Ariani, D.

2017-04-01

Majority of people of South coast of West Java, from Sukabumi, Cianjur, Garut are fishermen. Natural conditions are very dry and the area of land for agriculture, particularly rice cultivation is minimal. So that the condition of the society is more directed to high enough levels of food insecurity. Because coastal areas tend to have a longer dry season from rainfall. Results of research conducted in the years 2013 - 2016 in the area of Pelabuhan Ratu, Cidaun (Cianjur), Coastal area of Jayanti, Ranca Buaya, Mekar Mukti, and along the coast until Pameungpeuk, Leuweung Sancang, is known that jalawure plant which grows wild at South-coast region of West Java is precisely the alternative solution to address food insecurity. The results of the starch flour is a source of carbohydrate that is high enough to be used as a substitute for rice and wheat. Another potential source of jalawure nutrition is also recommended for diabetics consumption.

Evaluation of carbon fluxes and trends (2000-2008) in the Greater Platte River Basin: a sustainability study on the potential biofuel feedstock development

USGS Publications Warehouse

Gu, Yingxin; Wylie, Bruce K.; Zhang, Li; Gilmanov, Tagir G.

2012-01-01

This study evaluates the carbon fluxes and trends and examines the environmental sustainability (e.g., carbon budget, source or sink) of the potential biofuel feedstock sites identified in the Greater Platte River Basin (GPRB). A 9-year (2000–2008) time series of net ecosystem production (NEP), a measure of net carbon absorption or emission by ecosystems, was used to assess the historical trends and budgets of carbon flux for grasslands in the GPRB. The spatially averaged annual NEP (ANEP) for grassland areas that are possibly suitable for biofuel expansion (productive grasslands) was 71–169 g C m−2 year−1 during 2000–2008, indicating a carbon sink (more carbon is absorbed than released) in these areas. The spatially averaged ANEP for areas not suitable for biofuel feedstock development (less productive or degraded grasslands) was −47 to 69 g C m−2 year−1 during 2000–2008, showing a weak carbon source or a weak carbon sink (carbon emitted is nearly equal to carbon absorbed). The 9-year pre-harvest cumulative ANEP was 1166 g C m−2 for the suitable areas (a strong carbon sink) and 200 g C m−2 for the non-suitable areas (a weak carbon sink). Results demonstrate and confirm that our method of dynamic modeling of ecosystem performance can successfully identify areas desirable and sustainable for future biofuel feedstock development. This study provides useful information for land managers and decision makers to make optimal land use decisions regarding biofuel feedstock development and sustainability.

Chemical quality of tap water in Madrid: multicase control cancer study in Spain (MCC-Spain).

PubMed

Fernández-Navarro, Pablo; Villanueva, Cristina M; García-Pérez, Javier; Boldo, Elena; Goñi-Irigoyen, Fernando; Ulibarrena, Enrique; Rantakokko, Panu; García-Esquinas, Esther; Pérez-Gómez, Beatriz; Pollán, Marina; Aragonés, Nuria

2017-02-01

Chronic consumption of water, which contains contaminants, may give rise to adverse health effects. The Madrid region, covered by the population-based multicase-control (MCC-Spain) study, includes two drinking water supply areas. The different sources of the water, coupled together with the possible differences in water management, mean that there may be differences in drinking water quality. In the context of the MCC study, our aims were to describe contaminant concentrations in tap water drawn from various sampling points distributed around the region, assess these concentrations by reference to guideline values and study possible differences between the two supply areas. Tap water samples were collected from 34 sampling points in 7 towns in the Madrid region (19-29 April 2010), and 23 contaminants (metals, nitrates, disinfection by-product and Mutagen X levels) were quantified. We undertook a descriptive analysis of the contaminant concentrations in the water and compared them between the two water supply areas (Wilcoxon test). We created maps representing the distribution of the concentrations observed at water sampling points and assessed the correlations (Spearman's coefficient) between the different parameters measured. The concentrations of the contaminants were below guideline values. There were differences between the two supply areas in concentration of nitrates (p value = 0.0051) and certain disinfection by-products. While there were positive correlations (rho >0.70) among some disinfection by-products, no correlations were found in metals or nitrates. The differences in nitrate levels could be linked to differences in farming/industrial activities in the catchment areas and in disinfection by-products might be related to the existence of different treatment systems or bromine content in source waters.

Changes in Forest Production, Biomass and Carbon: Results From the 2015 UN FAO Global Forest Resource Assessment

NASA Astrophysics Data System (ADS)

Navar, J.

2015-12-01

Forests are important sources of livelihoods to millions of people and contribute to national economic development of many countries. In addition, they are vital sources and sinks of carbon and contribute to the rate of climate change. The UN Food and Agriculture Organization has been collecting and presenting data on global forest resources and forest cover since 1948. This paper builds on data from FAO's 2015 Global Forest Resource Assessment (FRA) and presents information on growing stock, biomass, carbon stock, wood removals, and changes of forest area primarily designated for production and multiple use of the world's forests. Between 1990 and 2015, the total growing stock volume has increased in East Asia, Caribbean, Western and Central Asia, North America, Europe (including the Russian Federation), and Oceania with the highest relative increase in East Asia and the Caribbean. In all other subregions the total growing stock volume decreased. North and Central America, Europe and Asia report forest C stock increases while South America and Africa report strong decreases and Oceania reports stable forest C stocks. The annual rate of decrease of forest C stock weakened between 1990 and 2015. The total volume of annual wood removals including wood fuel removals increased between 1990 and 2011, but shows a remarkable decline during the 2008-2009 economic crisis. Forest areas designated for production purposes differ considerably between subregions. The percentage of production area out of total forest area ranges between 16 percent in South America and 53 percent in Europe. Globally about one quarter of the forest area is designated to multiple use forestry. The balance between biomass growth and removals shows considerable sub-regional differences and related implications for the sustainable use of forests.

Opportunities for natural products in 21st century antibiotic discovery.

PubMed

Wright, Gerard D

2017-07-01

Natural products and their derivatives are mainstays of our antibiotic drugs, but they are increasingly in peril. The combination of widespread multidrug resistance in once susceptible bacterial pathogens, disenchantment with natural products as sources of new drugs, lack of success using synthetic compounds and target-based discovery methods, along with shifting economic and regulatory issues, conspire to move investment in research and development away from the antibiotics arena. The result is a growing crisis in antibiotic drug discovery that threatens modern medicine. 21 st century natural product research is perfectly positioned to fill the antibiotic discovery gap and bring new drug candidates to the clinic. Innovations in genomics and techniques to explore new sources of antimicrobial chemical matter are revealing new chemistry. Increasing appreciation of the value of narrow-spectrum drugs and re-examination of once discarded chemical scaffolds coupled with synthetic biology methods to generate new compounds and improve yields offer new strategies to revitalize once moribund natural product programs. The increasing awareness that the combination of antibiotics with adjuvants, non-antibiotic compounds that overcome resistance and enhance drug activity, can rescue older chemical scaffolds, and concepts such as blocking pathogen virulence present orthogonal strategies to traditional antibiotics. In all these areas, natural products offer chemical matter, shaped by natural selection, that is privileged in this therapeutic area. Natural product research is poised to regain prominence in delivering new drugs to solve the antibiotic crisis.

Occurrence and sources of natural and anthropogenic lipid tracers in surface soils from arid urban areas of Saudi Arabia.

PubMed

Rushdi, Ahmed I; Al-Mutlaq, Khalid F; El-Mubarak, Aarif H; Al-Saleh, Mohammed A; El-Otaibi, Mubarak T; Ibrahim, Sami M M; Simoneit, Bernd R T

2016-01-01

Soil particles contain a variety of natural and anthropogenic organic components, and in urban areas can be considered as local collectors of pollutants. Surface soil samples were taken from ten urban areas in Riyadh during early winter of 2007. They were extracted with dichloromethane-methanol mixture and the extracts were analyzed by gas chromatography-mass spectrometry. The major compounds were unresolved complex mixture (UCM), plasticizers, n-alkanes, carbohydrates, n-alkanoic acids, hopanes, n-alkanols, and sterols. Vegetation detritus was the major natural source of organic compounds (24.0 ± 15.7%) in samples from areas with less human activities and included n-alkanes, n-alkanoic acids, n-alkanols, sterols and carbohydrates. Vehicular emission products and discarded plastics were the major anthropogenic sources in the soil particles (53.3 ± 21.3% and 22.7 ± 10.7%, respectively). The anthropogenic tracers were UCM, plasticizers, n-alkanes, hopanes and traces of steranes. Vegetation and human activities control the occurrence and distribution of natural and anthropogenic extractable organic matter in this arid urban area. Copyright © 2015 Elsevier Ltd. All rights reserved.

Farmer perceptions on factors influencing water scarcity for goats in resource-limited communal farming environments.

PubMed

Mdletshe, Zwelethu Mfanafuthi; Ndlela, Sithembile Zenith; Nsahlai, Ignatius Verla; Chimonyo, Michael

2018-05-09

The objective of the study was to compare factors influencing water scarcity for goats in areas where there are seasonal and perennial rivers under resource-limited communal farming environments. Data were collected using a structured questionnaire (n = 285) administered randomly to smallholder goat farmers from areas with seasonal and perennial rivers. Ceremonies was ranked as the major reason for keeping goats. Water scarcity was ranked the major constraint to goat production in areas with seasonal rivers when compared to areas with perennial rivers (P < 0.05). Dams and rivers were ranked as the major water source for goat drinking in areas with seasonal and perennial river systems during cool dry and rainy seasons. Rivers were ranked as an important water source for goat drinking where there are seasonal and perennial river systems during the cool dry season. Households located close (≤ 3 km) to the nearest water source reported drinking water for goats a scarce resource. These results show that river systems, season and distance to the nearest water source from a household were factors perceived by farmers to influence water scarcity for goats in resource-limited communal farming environments. Farmers should explore water-saving strategies such as recycling wastewater from kitchens and bathrooms as an alternative water source. The government may assist farmers through sinking boreholes to supply water for both humans and livestock.

Assessing the transfer of risk due to transportation of agricultural products.

PubMed

Li, Pei-Chiun; Shih, Hsiu-Ching; Ma, Hwong-Wen

2015-02-01

Health risk assessment (HRA) is the process used to estimate adverse health effects on humans. The importance and sensitivity of food chains to HRA have been observed, but the impact of the transportation of food has generally been ignored. This study developed an exposure assessment to demonstrate the significance of the transportation of agricultural products in HRA. The associated case study estimated the health risks derived from various sources of arsenic emissions in Taiwan. Two assessment scenarios, self-sufficiency and transportation of agricultural products, were compared to calculate risk transfer ratios that show the impact of agriculture transportation. The risk transfer ratios found by the study range from 0.22 to 42.10, indicating that the quantity of transportation of agricultural products is the critical factor. High air deposition and high agricultural production are the two main contributors to the effect of the transportation of agricultural products on HRA. Risk reduction measures could be applied to high-pollution areas as well as to areas with high agricultural productivity to reduce ingestion risks to residents. Certain areas that are sensitive to the transportation of agricultural products may incur more risks if emissions increase in agriculturally productive counties. Copyright © 2014 Elsevier Ltd. All rights reserved.

Linking state-and-transition simulation and timber supply models for forest biomass production scenarios

USGS Publications Warehouse

Costanza, Jennifer; Abt, Robert C.; McKerrow, Alexa; Collazo, Jaime

2015-01-01

We linked state-and-transition simulation models (STSMs) with an economics-based timber supply model to examine landscape dynamics in North Carolina through 2050 for three scenarios of forest biomass production. Forest biomass could be an important source of renewable energy in the future, but there is currently much uncertainty about how biomass production would impact landscapes. In the southeastern US, if forests become important sources of biomass for bioenergy, we expect increased land-use change and forest management. STSMs are ideal for simulating these landscape changes, but the amounts of change will depend on drivers such as timber prices and demand for forest land, which are best captured with forest economic models. We first developed state-and-transition model pathways in the ST-Sim software platform for 49 vegetation and land-use types that incorporated each expected type of landscape change. Next, for the three biomass production scenarios, the SubRegional Timber Supply Model (SRTS) was used to determine the annual areas of thinning and harvest in five broad forest types, as well as annual areas converted among those forest types, agricultural, and urban lands. The SRTS output was used to define area targets for STSMs in ST-Sim under two scenarios of biomass production and one baseline, business-as-usual scenario. We show that ST-Sim output matched SRTS targets in most cases. Landscape dynamics results indicate that, compared with the baseline scenario, forest biomass production leads to more forest and, specifically, more intensively managed forest on the landscape by 2050. Thus, the STSMs, informed by forest economics models, provide important information about potential landscape effects of bioenergy production.

How phosphorus limitation can control climatic gas sources and sinks

NASA Astrophysics Data System (ADS)

Gypens, Nathalie; Borges, Alberto V.; Ghyoot, Caroline

2017-04-01

Since the 1950's, anthropogenic activities severely increased river nutrient loads in European coastal areas. Subsequent implementation of nutrient reduction policies have considerably reduced phosphorus (P) loads from mid-1980's, while nitrogen (N) loads were maintained, inducing a P limitation of phytoplankton growth in many eutrophied coastal areas such as the Southern Bight of the North Sea (SBNS). When dissolved inorganic phosphorous (DIP) is limiting, most phytoplankton organisms are able to indirectly acquire P from dissolved organic P (DOP). We investigate the impact of DOP use on the importance of phytoplankton production and atmospheric fluxes of CO2 and dimethylsulfide (DMS) in the SBNS from 1951 to 2007 using an extended version of the R-MIRO-BIOGAS model. This model includes a description of the ability of phytoplankton organisms to use DOP as a source of P. Results show that primary production can increase up to 70% due to DOP uptake in limiting DIP conditions. Consequently, simulated DMS emissions double while CO2 emissions to the atmosphere decrease, relative to the reference simulation without DOP uptake. At the end of the simulated period (late 2000's), the net direction of air-sea CO2 annual flux, changed from a source to a sink for atmospheric CO2 in response to use of DOP and increase of primary production.

Egg production patterns of two invertebrate species in rocky subtidal areas under different fishing regimes along the coast of central Chile

PubMed Central

Ospina-Álvarez, Andres; González, Catherine; Fernández, Miriam

2017-01-01

Fishing is a major source of human impact, reducing density and size of a wide range of exploited species in comparison to areas exhibiting strong regulations (no-take and partially protected areas, including Territorial Use Rights for Fisheries, TURFs). Since size and density might have important consequences on reproduction, and therefore natural re-seeding, we monitored adult size, density and potential fecundity of the keyhole limpet (Fissurella latimarginata) and the red sea urchin (Loxechinus albus) in areas under two fishing regimes (TURFs and Open Access Areas, OAAs). Analyzing the distribution of suitable habitats, we predict spatial patterns of potential egg production, to identify reproductive hotspots along the central coast of Chile. The current system of TURFs in central Chile showed higher potential egg production of F. latimarginata and of L. albus than expected under a complete OAAs scenario (67 and 52% respectively). Potential egg production showed more than a twofold reduction when the complete TURFs scenario was compared against complete OAAs condition in both species. Individual size and density explained between 60% and 100% of the variability in potential egg production, suggesting the importance of the enhancement of both biological variables in TURFs in Chile. Potential egg production for both species in the northern part of the studied domain was higher due to the combined effect of (a) suitable habitat and (b) concentration of TURFs. Our results suggest that partially protected areas, such as TURFs can significantly enhance the production of propagules that could seed exploited areas. PMID:28481886

Prospects for using peat and products of its processing in municipal power engineering in rural and remote areas

NASA Astrophysics Data System (ADS)

Medvedeva, E. A.; Zhenikhov, Yu. N.; Urvantsev, I. V.; Tsyba, V. E.

2017-06-01

This article presents a detailed analysis of the economic efficiency of peat utilization for generating electricity and heat in Russian rural areas and decentralized power consumption areas on the basis of the comparison of power tariffs (prices) and full costs of peat-based electricity and heat production. The research was performed using the model-information complex detailed with respect to municipal areas and major peat deposits that was developed at the Energy Institute, National Research University Higher School of Economics. It is shown that the firing of lignin helium fuel (LHF) granules that are made from peat extracted by the excavating method according to the new, patented technology is considered most efficient. In nongasified areas, the total cost of heat power that is generated in new boiler houses on the basis of LHF granules is often lower than the total heat cost for the gasification of the area and construction of gas boiler houses. In some cases, the heat cost in gasified areas is lower when using a boiler house based on LHF granules than that provided by the conversion of a boiler house to gas fuel. It is also shown that the construction of peat-based heat sources with the overall power of up to 27600 GJ/h that generate a heat power of up to 167.5 million GJ/year will be economically efficient in the coming years, provided that the tariffs for energy sources remain the same. Taking into account the supportive measures that were accepted on a legislative basis in July 2016, sources with the total power of up to 70 GW may be effective for peat-based plants with combined heat-andpower generation. To stimulate the utilization of peat in decentralized power consumption areas and rural areas located in the vicinity of deposits of this fuel type, it is also suggested to make amendments in the normative legal base.

40 CFR 63.11601 - What are the standards for new and existing paints and allied products manufacturing facilities?

Code of Federal Regulations, 2012 CFR

2012-07-01

... Hazardous Air Pollutants for Area Sources: Paints and Allied Products Manufacturing Standards, Monitoring... cleaning must be kept in a closed container. The closed container may contain a device that allows pressure relief, but does not allow liquid solvent to drain from the container. [74 FR 63525, Dec. 3, 2009, as...

40 CFR 63.11601 - What are the standards for new and existing paints and allied products manufacturing facilities?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Hazardous Air Pollutants for Area Sources: Paints and Allied Products Manufacturing Standards, Monitoring... cleaning must be kept in a closed container. The closed container may contain a device that allows pressure relief, but does not allow liquid solvent to drain from the container. [74 FR 63525, Dec. 3, 2009, as...

40 CFR 63.11601 - What are the standards for new and existing paints and allied products manufacturing facilities?

Code of Federal Regulations, 2013 CFR

2013-07-01

... Hazardous Air Pollutants for Area Sources: Paints and Allied Products Manufacturing Standards, Monitoring... cleaning must be kept in a closed container. The closed container may contain a device that allows pressure relief, but does not allow liquid solvent to drain from the container. [74 FR 63525, Dec. 3, 2009, as...

Fuel change possibilities in small heat source

NASA Astrophysics Data System (ADS)

Durčanský, Peter; Kapjor, Andrej; Jandačka, Jozef

2017-09-01

Rural areas are characterized by a larger number of older family houses with higher fuel consumption for heating. Some areas are not gasified, which means that the fuel base for heating the buildings is very limited. Heating is mainly covered by solid fuels with high emissions and low efficiency. But at the same time, the amount of energy in the form of biowaste can be evaluated and used further. We will explore the possibilities to convert biogas to heat of using a gas burner in a small heat source. However, the heat produced can be used other than for heating or hot water production. The added value for heat generation can be the production of electricity, in the use of heat energy through cogeneration unit with unconventional heat engine. The proposed solution could economically benefit the entire system, because electricity is a noble form of energy and its use is versatile.

Ozone Production and Its Sensitivity to NOx and VOCs: Results from the DISCOVER-AQ Field Experiment, Houston 2013

NASA Astrophysics Data System (ADS)

Ren, X.; Mazzuca, G.; Loughner, C.; Estes, M. J.; Crawford, J. H.; Weinheimer, A. J.; Pickering, K. E.; Dickerson, R. R.

2016-12-01

An observation-constrained box model based on the Carbon Bond mechanism, Version 5 (CB05), was used to study photochemical processes along the NASA P-3B flight track and spirals over eight surface sites during the September 2013 Houston, Texas deployment of the NASA DISCOVER-AQ campaign. Data from this campaign provided an opportunity to examine and improve our understanding of atmospheric photochemical oxidation processes related to the formation of secondary air pollutants such as ozone (O3). O3 production and its sensitivity to NOx and VOCs were calculated at different locations and times of day. Ozone production efficiency (OPE), defined as the ratio of the ozone production rate to the NOx oxidation rate, was calculated using the observations and the simulation results of the box and Community Multiscale Air Quality (CMAQ) models. Correlation of these results with other parameters, such as radical sources and NOx mixing ratio, was also evaluated. It was generally found that O3 production tends to be more VOC sensitive in the morning along with high ozone production rates, suggesting that control of VOCs may be an effective way to control O3 in Houston. In the afternoon, O3 production was found to be mainly NOx sensitive with some exceptions. O3 production at near major emissions sources such as Deer Park was mostly VOC sensitive for the entire day, other urban areas near Moody Tower and Channelview were VOC sensitive or in the transition regime, and areas farther from downtown Houston such as Smith Point and Conroe were mostly NOx sensitive for the entire day. It was also found that the control of NOx emissions has reduced O3 concentrations over Houston, but led to larger OPE values. The results from this work strengthen our understanding of O3 production; they indicate that controlling NOx emissions will provide air quality benefits over the greater Houston metropolitan area in the long run, but in selected areas controlling VOC emissions will also be beneficial.

Ozone production and its sensitivity to NOx and VOCs: results from the DISCOVER-AQ field experiment, Houston 2013

NASA Astrophysics Data System (ADS)

Mazzuca, Gina M.; Ren, Xinrong; Loughner, Christopher P.; Estes, Mark; Crawford, James H.; Pickering, Kenneth E.; Weinheimer, Andrew J.; Dickerson, Russell R.

2016-11-01

An observation-constrained box model based on the Carbon Bond mechanism, version 5 (CB05), was used to study photochemical processes along the NASA P-3B flight track and spirals over eight surface sites during the September 2013 Houston, Texas deployment of the NASA Deriving Information on Surface Conditions from COlumn and VERtically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) campaign. Data from this campaign provided an opportunity to examine and improve our understanding of atmospheric photochemical oxidation processes related to the formation of secondary air pollutants such as ozone (O3). O3 production and its sensitivity to NOx and volatile organic compounds (VOCs) were calculated at different locations and times of day. Ozone production efficiency (OPE), defined as the ratio of the ozone production rate to the NOx oxidation rate, was calculated using the observations and the simulation results of the box and Community Multiscale Air Quality (CMAQ) models. Correlations of these results with other parameters, such as radical sources and NOx mixing ratio, were also evaluated. It was generally found that O3 production tends to be more VOC-sensitive in the morning along with high ozone production rates, suggesting that control of VOCs may be an effective way to control O3 in Houston. In the afternoon, O3 production was found to be mainly NOx-sensitive with some exceptions. O3 production near major emissions sources such as Deer Park was mostly VOC-sensitive for the entire day, other urban areas near Moody Tower and Channelview were VOC-sensitive or in the transition regime, and areas farther from downtown Houston such as Smith Point and Conroe were mostly NOx-sensitive for the entire day. It was also found that the control of NOx emissions has reduced O3 concentrations over Houston but has led to larger OPE values. The results from this work strengthen our understanding of O3 production; they indicate that controlling NOx emissions will provide air quality benefits over the greater Houston metropolitan area in the long run, but in selected areas controlling VOC emissions will also be beneficial.

Natural Products as Sources of New Drugs over the 30 Years from 1981 to 2010†

PubMed Central

Newman, David J.; Cragg, Gordon M.

2013-01-01

This review is an updated and expanded version of the three prior reviews that were published in this journal in 1997, 2003 and 2007. In the case of all approved therapeutic agents, the time frame has been extended to cover the 30 years from January 1st 1981 to December 31st 2010 for all diseases world-wide, and from 1950 (earliest so far identified) to December 2010 for all approved antitumor drugs world-wide. We have continued to utilize our secondary subdivision of a “natural product mimic” or “NM” to join the original primary divisions, and have added a new designation “natural product botanical” or “NB” to cover those botanical “defined mixtures” that have now been recognized as drug entities by the FDA and similar organizations. From the data presented, the utility of natural products as sources of novel structures, but not necessarily the final drug entity, is still alive and well. Thus, in the area of cancer, over the time frame from around the 1940s to date, of the 175 small molecules, 131 or 74.8% are other than “S” (synthetic), with 85 or 48.6% actually being either natural products or directly derived there from. In other areas, the influence of natural product structures is quite marked with, as expected from prior information, the anti-infective area being dependent on natural products and their structures. Although combinatorial chemistry techniques have succeeded as methods of optimizing structures, and have been used very successfully in the optimization of many recently approved agents, we are only able to identify only one de novo combinatorial compound approved as a drug in this 30-year time frame. We wish to draw the attention of readers to the rapidly evolving recognition that a significant number of natural product drugs/leads are actually produced by microbes and/or microbial interactions with the “host from whence it was isolated”, and therefore we consider that this area of natural product research should be expanded significantly. PMID:22316239

Reducing methylmercury accumulation in the food webs of San Francisco Bay and its local watersheds.

PubMed

Davis, J A; Looker, R E; Yee, D; Marvin-Di Pasquale, M; Grenier, J L; Austin, C M; McKee, L J; Greenfield, B K; Brodberg, R; Blum, J D

2012-11-01

San Francisco Bay (California, USA) and its local watersheds present an interesting case study in estuarine mercury (Hg) contamination. This review focuses on the most promising avenues for attempting to reduce methylmercury (MeHg) contamination in Bay Area aquatic food webs and identifying the scientific information that is most urgently needed to support these efforts. Concern for human exposure to MeHg in the region has led to advisories for consumption of sport fish. Striped bass from the Bay have the highest average Hg concentration measured for this species in USA estuaries, and this degree of contamination has been constant for the past 40 years. Similarly, largemouth bass in some Bay Area reservoirs have some of the highest Hg concentrations observed in the entire US. Bay Area wildlife, particularly birds, face potential impacts to reproduction based on Hg concentrations in the tissues of several Bay species. Source control of Hg is one of the primary possible approaches for reducing MeHg accumulation in Bay Area aquatic food webs. Recent findings (particularly Hg isotope measurements) indicate that the decades-long residence time of particle-associated Hg in the Bay is sufficient to allow significant conversion of even the insoluble forms of Hg into MeHg. Past inputs have been thoroughly mixed throughout this shallow and dynamic estuary. The large pool of Hg already present in the ecosystem dominates the fraction converted to MeHg and accumulating in the food web. Consequently, decreasing external Hg inputs can be expected to reduce MeHg in the food web, but it will likely take many decades to centuries before those reductions are achieved. Extensive efforts to reduce loads from the largest Hg mining source (the historic New Almaden mining district) are underway. Hg is spread widely across the urban landscape, but there are a number of key sources, source areas, and pathways that provide opportunities to capture larger quantities of Hg and reduce loads from urban runoff. Atmospheric deposition is a lower priority for source control in the Bay Area due to a combination of a lack of major local sources. Internal net production of MeHg is the dominant source of MeHg that enters the food web. Controlling internal net production is the second primary management approach, and has the potential to reduce food web MeHg in some habitats more effectively and within a much shorter time-frame. Controlling net MeHg production and accumulation in the food web of upstream reservoirs and ponds is very promising due to the many features of these ecosystems that can be manipulated. The most feasible control options in tidal marshes relate to the design of flow patterns and subhabitats in restoration projects. Options for controlling MeHg production in open Bay habitat are limited due primarily to the highly dispersed distribution of Hg throughout the ecosystem. Other changes in these habitats may also have a large influence on food web MeHg, including temperature changes due to global warming, sea level rise, food web alterations due to introduced species and other causes, and changes in sediment supply. Other options for reducing or mitigating exposure and risk include controlling bioaccumulation, cleanup of contaminated sites, and reducing other factors (e.g., habitat availability) that limit at-risk wildlife populations. Copyright © 2012 Elsevier Inc. All rights reserved.

Reducing methylmercury accumulation in the food webs of San Francisco Bay and its local watersheds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, J.A., E-mail: jay@sfei.org; Looker, R.E.; Yee, D.

San Francisco Bay (California, USA) and its local watersheds present an interesting case study in estuarine mercury (Hg) contamination. This review focuses on the most promising avenues for attempting to reduce methylmercury (MeHg) contamination in Bay Area aquatic food webs and identifying the scientific information that is most urgently needed to support these efforts. Concern for human exposure to MeHg in the region has led to advisories for consumption of sport fish. Striped bass from the Bay have the highest average Hg concentration measured for this species in USA estuaries, and this degree of contamination has been constant for themore » past 40 years. Similarly, largemouth bass in some Bay Area reservoirs have some of the highest Hg concentrations observed in the entire US. Bay Area wildlife, particularly birds, face potential impacts to reproduction based on Hg concentrations in the tissues of several Bay species. Source control of Hg is one of the primary possible approaches for reducing MeHg accumulation in Bay Area aquatic food webs. Recent findings (particularly Hg isotope measurements) indicate that the decades-long residence time of particle-associated Hg in the Bay is sufficient to allow significant conversion of even the insoluble forms of Hg into MeHg. Past inputs have been thoroughly mixed throughout this shallow and dynamic estuary. The large pool of Hg already present in the ecosystem dominates the fraction converted to MeHg and accumulating in the food web. Consequently, decreasing external Hg inputs can be expected to reduce MeHg in the food web, but it will likely take many decades to centuries before those reductions are achieved. Extensive efforts to reduce loads from the largest Hg mining source (the historic New Almaden mining district) are underway. Hg is spread widely across the urban landscape, but there are a number of key sources, source areas, and pathways that provide opportunities to capture larger quantities of Hg and reduce loads from urban runoff. Atmospheric deposition is a lower priority for source control in the Bay Area due to a combination of a lack of major local sources. Internal net production of MeHg is the dominant source of MeHg that enters the food web. Controlling internal net production is the second primary management approach, and has the potential to reduce food web MeHg in some habitats more effectively and within a much shorter time-frame. Controlling net MeHg production and accumulation in the food web of upstream reservoirs and ponds is very promising due to the many features of these ecosystems that can be manipulated. The most feasible control options in tidal marshes relate to the design of flow patterns and subhabitats in restoration projects. Options for controlling MeHg production in open Bay habitat are limited due primarily to the highly dispersed distribution of Hg throughout the ecosystem. Other changes in these habitats may also have a large influence on food web MeHg, including temperature changes due to global warming, sea level rise, food web alterations due to introduced species and other causes, and changes in sediment supply. Other options for reducing or mitigating exposure and risk include controlling bioaccumulation, cleanup of contaminated sites, and reducing other factors (e.g., habitat availability) that limit at-risk wildlife populations.« less

Reducing Methylmercury Accumulation in the Food Webs of San Francisco Bay and Its Local Watersheds

PubMed Central

Davis, J.A.; Looker, R.E.; Yee, D.; Marvin-DiPasquale, M.; Grenier, J.L.; Austin, C.M.; McKee, L.J.; Greenfield, B.K.; Brodberg, R.; Blum, J.D.

2013-01-01

San Francisco Bay (California, USA) and its local watersheds present an interesting case study in estuarine mercury (Hg) contamination. This review focuses on the most promising avenues for attempting to reduce methylmercury (MeHg) contamination in Bay Area aquatic food webs and identifying the scientific information that is most urgently needed to support these efforts. Concern for human exposure to MeHg in the region has led to advisories for consumption of sport fish. Striped bass from the Bay have the highest average Hg concentration measured for this species in USA estuaries, and this degree of contamination has been constant for the past 40 years. Similarly, largemouth bass in some Bay Area reservoirs have some of the highest Hg concentrations observed in the entire US. Bay Area wildlife, particularly birds, face potential impacts to reproduction based on Hg concentrations in the tissues of several Bay species. Source control of Hg is one of the primary possible approaches for reducing MeHg accumulation in Bay Area aquatic food webs. Recent findings (particularly Hg isotope measurements) indicate that the decades-long residence time of particle-associated Hg in the Bay is sufficient to allow significant conversion of even the insoluble forms of Hg into MeHg. Past inputs have been thoroughly mixed throughout this shallow and dynamic estuary. The large pool of Hg already present in the ecosystem dominates the fraction converted to MeHg and accumulating in the food web. Consequently, decreasing external Hg inputs can be expected to reduce MeHg in the food web, but it will likely take many decades to centuries before those reductions are achieved. Extensive efforts to reduce loads from the largest Hg mining source (the historic New Almaden mining district) are underway. Hg is spread widely across the urban landscape, but there are a number of key sources, source areas, and pathways that provide opportunities to capture larger quantities of Hg and reduce loads from urban runoff. Atmospheric deposition is a lower priority for source control in the Bay Area due to a combination of a lack of major local sources and Hg isotope data indicating it is a secondary contributor to food web MeHg. Internal net production of MeHg is the dominant source of MeHg that enters the food web. Controlling internal net production is the second primary management approach, and has the potential to reduce food web MeHg more effectively and within a much shorter time-frame. MeHg cycling and control opportunities vary by habitat. Controlling net MeHg production and accumulation in the food web of upstream reservoirs and ponds is very promising due to the many features of these ecosystems that can be manipulated. The most feasible control options in tidal marshes relate to the design of flow patterns and subhabitats in restoration projects. Options for controlling MeHg production in open Bay habitat are limited due primarily to the highly dispersed distribution of Hg throughout the ecosystem. Other changes in these habitats may also have a large influence on food web MeHg, including temperature changes due to global warming, sea level rise, food web alterations due to introduced species and other causes, and changes in sediment supply. Other options for reducing or mitigating exposure and risk include controlling bioaccumulation, cleanup of contaminated sites, and reducing other factors (e.g., habitat availability) that limit at risk wildlife populations. PMID:23122771

Potential effects of sulfur pollutants on grape production in New York State

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knudson, D.A.; Viessman, S.

1983-01-01

This paper presents the results of a prototype analysis of sulfur pollutants on graph production in New York State. Principal grape production areas for the state are defined and predictions of sulfur dioxide concentrations associated with present and projected sources are computed. Sulfur dioxide concentrations are based on the results of a multi-source dispersion model, whereas concentrations for other pollutants are derived from observations. This information is used in conjunction with results from experiments conducted to identify threshold levels of damage and/or injury to a variety of grape species to pollutants. Determination is then made whether the subject crop ismore » at risk from present and projected concentrations of pollutants.« less

Carbon fluxes in ecosystems of Yellowstone National Park predicted from remote sensing data and simulation modeling

PubMed Central

2011-01-01

Background A simulation model based on remote sensing data for spatial vegetation properties has been used to estimate ecosystem carbon fluxes across Yellowstone National Park (YNP). The CASA (Carnegie Ames Stanford Approach) model was applied at a regional scale to estimate seasonal and annual carbon fluxes as net primary production (NPP) and soil respiration components. Predicted net ecosystem production (NEP) flux of CO2 is estimated from the model for carbon sinks and sources over multi-year periods that varied in climate and (wildfire) disturbance histories. Monthly Enhanced Vegetation Index (EVI) image coverages from the NASA Moderate Resolution Imaging Spectroradiometer (MODIS) instrument (from 2000 to 2006) were direct inputs to the model. New map products have been added to CASA from airborne remote sensing of coarse woody debris (CWD) in areas burned by wildfires over the past two decades. Results Model results indicated that relatively cooler and wetter summer growing seasons were the most favorable for annual plant production and net ecosystem carbon gains in representative landscapes of YNP. When summed across vegetation class areas, the predominance of evergreen forest and shrubland (sagebrush) cover was evident, with these two classes together accounting for 88% of the total annual NPP flux of 2.5 Tg C yr-1 (1 Tg = 1012 g) for the entire Yellowstone study area from 2000-2006. Most vegetation classes were estimated as net ecosystem sinks of atmospheric CO2 on annual basis, making the entire study area a moderate net sink of about +0.13 Tg C yr-1. This average sink value for forested lands nonetheless masks the contribution of areas burned during the 1988 wildfires, which were estimated as net sources of CO2 to the atmosphere, totaling to a NEP flux of -0.04 Tg C yr-1 for the entire burned area. Several areas burned in the 1988 wildfires were estimated to be among the lowest in overall yearly NPP, namely the Hellroaring Fire, Mink Fire, and Falls Fire areas. Conclusions Rates of recovery for burned forest areas to pre-1988 biomass levels were estimated from a unique combination of remote sensing and CASA model predictions. Ecosystem production and carbon fluxes in the Greater Yellowstone Ecosystem (GYE) result from complex interactions between climate, forest age structure, and disturbance-recovery patterns of the landscape. PMID:21835025

Carbon fluxes in ecosystems of Yellowstone National Park predicted from remote sensing data and simulation modeling.

PubMed

Potter, Christopher; Klooster, Steven; Crabtree, Robert; Huang, Shengli; Gross, Peggy; Genovese, Vanessa

2011-08-11

A simulation model based on remote sensing data for spatial vegetation properties has been used to estimate ecosystem carbon fluxes across Yellowstone National Park (YNP). The CASA (Carnegie Ames Stanford Approach) model was applied at a regional scale to estimate seasonal and annual carbon fluxes as net primary production (NPP) and soil respiration components. Predicted net ecosystem production (NEP) flux of CO2 is estimated from the model for carbon sinks and sources over multi-year periods that varied in climate and (wildfire) disturbance histories. Monthly Enhanced Vegetation Index (EVI) image coverages from the NASA Moderate Resolution Imaging Spectroradiometer (MODIS) instrument (from 2000 to 2006) were direct inputs to the model. New map products have been added to CASA from airborne remote sensing of coarse woody debris (CWD) in areas burned by wildfires over the past two decades. Model results indicated that relatively cooler and wetter summer growing seasons were the most favorable for annual plant production and net ecosystem carbon gains in representative landscapes of YNP. When summed across vegetation class areas, the predominance of evergreen forest and shrubland (sagebrush) cover was evident, with these two classes together accounting for 88% of the total annual NPP flux of 2.5 Tg C yr-1 (1 Tg = 1012 g) for the entire Yellowstone study area from 2000-2006. Most vegetation classes were estimated as net ecosystem sinks of atmospheric CO2 on annual basis, making the entire study area a moderate net sink of about +0.13 Tg C yr-1. This average sink value for forested lands nonetheless masks the contribution of areas burned during the 1988 wildfires, which were estimated as net sources of CO2 to the atmosphere, totaling to a NEP flux of -0.04 Tg C yr-1 for the entire burned area. Several areas burned in the 1988 wildfires were estimated to be among the lowest in overall yearly NPP, namely the Hellroaring Fire, Mink Fire, and Falls Fire areas. Rates of recovery for burned forest areas to pre-1988 biomass levels were estimated from a unique combination of remote sensing and CASA model predictions. Ecosystem production and carbon fluxes in the Greater Yellowstone Ecosystem (GYE) result from complex interactions between climate, forest age structure, and disturbance-recovery patterns of the landscape.

Characterization of alluvial dust sources and their temporal development - a multi-sensor approach for the Aïr Massif, Niger

NASA Astrophysics Data System (ADS)

Feuerstein, Stefanie; Schepanski, Kerstin

2017-04-01

One of the world's largest sources of atmospheric dust is the Sahara. It is said that 55% of the total global dust emission can be linked to the desert in northern Africa. Thus, understanding the Saharan dust sources is of great importance to estimate the total global dust load and its variability. Especially one type of dust sources has gained attention in dust research in recent years: The emission of dust from sediments formed by hydrologic processes, so called alluvial dust sources. These sediments were either formed in the past under the influences of a more humid paleoclimate or are deposited recently, e.g. during strong precipitation events when surficial runoff leads to the activation of wadi systems or to the occurrence of flash floods. Especially the latter phenomenon is able to deliver a huge amount of potentially erodible sediments. The research presented here focuses on the characterization of these alluvial dust sources with special attention on their temporal variability in relation to wet and dry phases. A study area covering the Aïr Massif in Niger is analysed over a four years time span from January 2013 to December 2016. The whole cycle from sediment formation to dust emission is illustrated by using data of various satellite sensors that are able to capture the processes taking place at the land surface as well as in the atmosphere: (1) The rainfall distribution for the study area is shown by time series of the TRMM precipitation estimates. A catchment analysis of the area helps to estimate the amount of surficial runoff and to detect areas of potential sediment accumulation. (2) Changes in the sediment structure of the land surface are analysed using atmospherically corrected time series of NASA's Landsat-8 OLI satellite. A land cover classification shows the distribution of alluvial sediments over the area; fresh layers of alluvial deposits are detected. Furthermore, the evolution of the vegetation cover, which inhibits dust emission, is analysed by calculating NDVI time series from the Landsat data. (3) The MSG Dust Product is used to determine the frequency of dust emission from the investigation area. Furthermore, the product allows the precise localization of the sources. Therefore the alluvial sediments can directly be connected to dust emission. By combining the findings of these different satellite sensors, a profound analysis of alluvial dust sources on different levels is possible. The connection between the amount of precipitation and the supply of potentially erodible sediments is shown, which leads to a better understanding of the temporal evolution and importance of this source type.

Engineered and subsequent intrinsic in situ bioremediation of a diesel fuel contaminated aquifer

NASA Astrophysics Data System (ADS)

Hunkeler, Daniel; Höhener, Patrick; Zeyer, Josef

2002-12-01

A diesel fuel contaminated aquifer in Menziken, Switzerland was treated for 4.5 years by injecting aerated groundwater, supplemented with KNO 3 and NH 4H 2PO 4 to stimulate indigenous populations of petroleum hydrocarbon (PHC) degrading microorganisms. After dissolved PHC concentrations had stabilized at a low level, engineered in situ bioremediation was terminated. The main objective of this study was to evaluate the efficacy of intrinsic in situ bioremediation as a follow-up measure to remove PHC remaining in the aquifer after terminating engineered in situ bioremediation. In the first 7 months of intrinsic in situ bioremediation, redox conditions in the source area became more reducing as indicated by lower concentrations of SO 42- and higher concentrations of Fe(II) and CH 4. In the core of the source area, strongly reducing conditions prevailed during the remaining study period (3 years) and dissolved PHC concentrations were higher than during engineered in situ bioremediation. This suggests that biodegradation in the core zone was limited by the availability of oxidants. In lateral zones of the source area, however, gradually more oxidized conditions were reestablished again, suggesting that PHC availability increasingly limited biodegradation. The total DIC production rate in the aquifer decreased within 2 years to about 25% of that during engineered in situ bioremediation and remained at that level. Stable carbon isotope analysis confirmed that the produced DIC mainly originated from PHC mineralization. The total rate of DIC and CH 4 production in the source area was more than 300 times larger than the rate of PHC elution. This indicates that biodegradation coupled to consumption of naturally occurring oxidants was an important process for removal of PHC which remained in the aquifer after terminating engineered measures.

Methane and benzene in drinking-water wells overlying the Eagle Ford, Fayetteville, and Haynesville Shale hydrocarbon production areas

USGS Publications Warehouse

McMahon, Peter B.; Barlow, Jeannie R.; Engle, Mark A.; Belitz, Kenneth; Ging, Patricia B.; Hunt, Andrew G.; Jurgens, Bryant; Kharaka, Yousif K.; Tollett, Roland W.; Kresse, Timothy M.

2017-01-01

Water wells (n = 116) overlying the Eagle Ford, Fayetteville, and Haynesville Shale hydrocarbon production areas were sampled for chemical, isotopic, and groundwater-age tracers to investigate the occurrence and sources of selected hydrocarbons in groundwater. Methane isotopes and hydrocarbon gas compositions indicate most of the methane in the wells was biogenic and produced by the CO2 reduction pathway, not from thermogenic shale gas. Two samples contained methane from the fermentation pathway that could be associated with hydrocarbon degradation based on their co-occurrence with hydrocarbons such as ethylbenzene and butane. Benzene was detected at low concentrations (<0.15 μg/L), but relatively high frequencies (2.4–13.3% of samples), in the study areas. Eight of nine samples containing benzene had groundwater ages >2500 years, indicating the benzene was from subsurface sources such as natural hydrocarbon migration or leaking hydrocarbon wells. One sample contained benzene that could be from a surface release associated with hydrocarbon production activities based on its age (10 ± 2.4 years) and proximity to hydrocarbon wells. Groundwater travel times inferred from the age-data indicate decades or longer may be needed to fully assess the effects of potential subsurface and surface releases of hydrocarbons on the wells.

Methane and Benzene in Drinking-Water Wells Overlying the Eagle Ford, Fayetteville, and Haynesville Shale Hydrocarbon Production Areas.

PubMed

McMahon, Peter B; Barlow, Jeannie R B; Engle, Mark A; Belitz, Kenneth; Ging, Patricia B; Hunt, Andrew G; Jurgens, Bryant C; Kharaka, Yousif K; Tollett, Roland W; Kresse, Timothy M

2017-06-20

Water wells (n = 116) overlying the Eagle Ford, Fayetteville, and Haynesville Shale hydrocarbon production areas were sampled for chemical, isotopic, and groundwater-age tracers to investigate the occurrence and sources of selected hydrocarbons in groundwater. Methane isotopes and hydrocarbon gas compositions indicate most of the methane in the wells was biogenic and produced by the CO 2 reduction pathway, not from thermogenic shale gas. Two samples contained methane from the fermentation pathway that could be associated with hydrocarbon degradation based on their co-occurrence with hydrocarbons such as ethylbenzene and butane. Benzene was detected at low concentrations (<0.15 μg/L), but relatively high frequencies (2.4-13.3% of samples), in the study areas. Eight of nine samples containing benzene had groundwater ages >2500 years, indicating the benzene was from subsurface sources such as natural hydrocarbon migration or leaking hydrocarbon wells. One sample contained benzene that could be from a surface release associated with hydrocarbon production activities based on its age (10 ± 2.4 years) and proximity to hydrocarbon wells. Groundwater travel times inferred from the age-data indicate decades or longer may be needed to fully assess the effects of potential subsurface and surface releases of hydrocarbons on the wells.

Milk cow feed intake and milk production and distribution estimates for Phase 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beck, D.M.; Darwin, R.F.; Erickson, A.R.

1992-04-01

This report provides initial information on milk production and distribution in the Hanford Environmental Dose Reconstruction (HEDR) Project Phase I study area. The Phase I study area consists of eight countries in central Washington and two countries in northern Oregon. The primary objective of the HEDR Project is to develop estimates of the radiation doses populations could have received from Hanford operations. The objective of Phase I of the project was to determine the feasibility of reconstructing data, models, and development of preliminary dose estimates received by people living in the ten countries surrounding Hanford from 1944 to 1947. Onemore » of the most important contributors to radiation doses from Hanford during the period of interest was radioactive iodine. Consumption of milk from cows that ate vegetation contaminated with iodine is likely the dominant pathway of human exposure. To estimate the doses people could have received from this pathway, it is necessary to estimate the amount of milk that the people living in the Phase I area consumed, the source of the milk, and the type of feed that the milk cows ate. The objective of the milk model subtask is to identify the sources of milk supplied to residents of each community in the study area as well as the sources of feeds that were fed to the milk cows. In this report, we focus on Grade A cow's milk (fresh milk used for human consumption).« less

Source attribution of poly- and perfluoroalkyl substances (PFASs) in surface waters from Rhode Island and the New York Metropolitan Area

PubMed Central

Zhang, Xianming; Lohmann, Rainer; Dassuncao, Clifton; Hu, Xindi C.; Weber, Andrea K.; Vecitis, Chad D.; Sunderland, Elsie M.

2017-01-01

Exposure to poly and perfluoroalkyl substances (PFASs) has been associated with adverse health effects in humans and wildlife. Understanding pollution sources is essential for environmental regulation but source attribution for PFASs has been confounded by limited information on industrial releases and rapid changes in chemical production. Here we use principal component analysis (PCA), hierarchical clustering, and geospatial analysis to understand source contributions to 14 PFASs measured across 37 sites in the Northeastern United States in 2014. PFASs are significantly elevated in urban areas compared to rural sites except for perfluorobutane sulfonate (PFBS), N-methyl perfluorooctanesulfonamidoacetic acid (N-MeFOSAA), perfluoroundecanate (PFUnDA) and perfluorododecanate (PFDoDA). The highest PFAS concentrations across sites were for perfluorooctanate (PFOA, 56 ng L−1) and perfluorohexane sulfonate (PFOS, 43 ng L−1) and PFOS levels are lower than earlier measurements of U.S. surface waters. PCA and cluster analysis indicates three main statistical groupings of PFASs. Geospatial analysis of watersheds reveals the first component/cluster originates from a mixture of contemporary point sources such as airports and textile mills. Atmospheric sources from the waste sector are consistent with the second component, and the metal smelting industry plausibly explains the third component. We find this source-attribution technique is effective for better understanding PFAS sources in urban areas. PMID:28217711

Lithology, hydrologic characteristics, and water quality of the Arkansas River Valley alluvial aquifer in the vicinity of Van Buren, Arkansas

USGS Publications Warehouse

Kresse, Timothy M.; Westerman, Drew A.; Hart, Rheannon M.

2015-01-01

The hydrologic and geochemical data gathered for this study provide a qualitative assessment of the potential of the Arkansas River Valley alluvial aquifer as a source of public water supply in the Van Buren area. Results indicate minimal influx of water from the Arkansas River, and recharge to the aquifer appears to be dominantly by infiltration of precipitation through overlying alluvium. If vertical wells are used as a source of public water supply, then several wells will have to be used in combination at relatively low pumping rates and placed in areas with a greater percent sand. Use of a horizontal well configuration near the river to increase production may depend on infiltration of river water to supplement water removed from storage, especially where areas of lower permeability sediments might be encountered within the surrounding alluvium. If a poor hydraulic connection exists between the river and the alluvium, as indicated by this study, then production will depend on ample precipitation and recharge throughout the year and groundwater storage sufficient to prevent declining water levels where pumping rates exceed recharge.

Acrylic and Modacrylic Fibers Production: National Emission Standards for Hazardous Air Pollutants (NESHAP) for Area Sources

EPA Pesticide Factsheets

This NESHAP applies to facilities using pressure or thermal treatment processes involving wood preservatives containing chromium, arsenic, dioxins, or methylene chloride. Page includes rule summary, rule history and additional documents.

Flexible Polyurethane Foam Production and Fabrication: National Emission Standards for Hazardous Air Pollutants (NESHAP) for Area Sources

EPA Pesticide Factsheets

This NESHAP applies to facilities using pressure or thermal treatment processes involving wood preservatives containing chromium, arsenic, dioxins, or methylene chloride. Inlcudes federal register citations, rule history and additional resources.

Photochemical processing of diesel fuel emissions as a large secondary source of isocyanic acid (HNCO)

NASA Astrophysics Data System (ADS)

Link, M. F.; Friedman, B.; Fulgham, R.; Brophy, P.; Galang, A.; Jathar, S. H.; Veres, P.; Roberts, J. M.; Farmer, D. K.

2016-04-01

Isocyanic acid (HNCO) is a well-known air pollutant that affects human health. Biomass burning, smoking, and combustion engines are known HNCO sources, but recent studies suggest that secondary production in the atmosphere may also occur. We directly observed photochemical production of HNCO from the oxidative aging of diesel exhaust during the Diesel Exhaust Fuel and Control experiments at Colorado State University using acetate ionization time-of-flight mass spectrometry. Emission ratios of HNCO were enhanced, after 1.5 days of simulated atmospheric aging, from 50 to 230 mg HNCO/kg fuel at idle engine operating conditions. Engines operated at higher loads resulted in less primary and secondary HNCO formation, with emission ratios increasing from 20 to 40 mg HNCO/kg fuel under 50% load engine operating conditions. These results suggest that photochemical sources of HNCO could be more significant than primary sources in urban areas.

Marine organic geochemistry in industrially affected coastal areas in Greece: Hydrocarbons in surface sediments

NASA Astrophysics Data System (ADS)

Hatzianestis, Ioannis

2015-04-01

Hydrocarbons are abundant components of the organic material in coastal zones. Their sources are mainly anthropogenic, but several natural ones have also been recognized. Among hydrocarbons, the polycyclic aromatic ones (PAHs) have received special attention since they considered as hazardous environmental chemicals and are included in priority pollutant lists. The purpose of this study was to investigate the distribution, sources and transport pathways of hydrocarbons in marine areas in Greece directly influenced from the operation of major industrial units in the coastal zone by using a molecular marker approach, characteristic compositional patterns and related indices and also to evaluate their potential toxicity. Thirty two surface sediment samples were collected from three marine areas: a) Antikyra bay in Korinthiakos gulf, affected from the operation of an alumina and production plant b) Larymna bay in Noth Evoikos, affected from the operation of a nickel production plant and c) Aliveri bay in South Evoikos Gulf, affected from a cement production plant. In all the studied areas aquaculture and fishing activities have been also developed in the coastal zone. High aliphatic hydrocarbon (AHC) concentrations (~500 μg/g), indicating significant petroleum related inputs, were measured only in Antikyra bay. In all the other samples, AHC values were below 100 μg/g. N-alkanes were the most prominent resolved components (R) with an elevated odd to even carbon number preference, revealing the high importance of terrestrial inputs in the study areas. The unresolved complex mixture (UCM) was the major component of the aliphatic fraction (UCM/R > 4), indicating a chronic oil pollution. A series of hopanes were also identified, with patterns characteristic of oil-derived hydrocarbons, further confirming the presence of pollutant inputs from fossil fuel products. Extremely high PAH concentrations (> 100,000 ng/g) were found in the close vicinity of the alumina production plant in Antikyra bay. High levels of PAHs up to 22,000 ng/g were also found in Aliveri bay, whereas lower values up to 7500 ng/g, but still indicating significant pollution, were measured close to the nickel production plant in Larymna bay. The examination of PAH molecular indices revealed that in Antikyra and Larymna bays more than 80% of the PAHs have pyrolytic origin coming from various combustion sources. On the contrary, in Aliveri bay about 60% of the PAHs are related to petrogenic/petroleum inputs. With respect to ecotoxicological effects, mean quotient Effect-Range Median (m-ERM) values, higher than 1.5, were calculated in Antikyra bay, indicating a high probability (76%) of toxicity. In Aliveri and Larymna bays the m-ERM values were between 0.11 and 0.5 bay suggesting a lower probability (21%) of toxicity. Overall, the results of our study reveal that high quantities of PAHs produced from land point sources such as the industrial units can enter into small coastal marine areas supporting activities such as aquaculture and fishing. Thus, desirable and permitted uses must be well defined and regulatory frameworks must be established.

Lateral, Vertical, and Longitudinal Source Area Connectivity Drive Runoff and Carbon Export Across Watershed Scales

NASA Astrophysics Data System (ADS)

Zimmer, Margaret A.; McGlynn, Brian L.

2018-03-01

Watersheds are three-dimensional hydrologic systems where the longitudinal expansion/contraction of stream networks, vertical connection/disconnection between shallow and deep groundwater systems, and lateral connectivity of these water sources to streams mediate runoff production and nutrient export. The connectivity of runoff source areas during both baseflow and stormflow conditions and their combined influence on biogeochemical fluxes remain poorly understood. Here we focused on a set of 3.3 and 48.4 ha nested watersheds (North Carolina, USA). These watersheds comprise ephemeral and intermittent runoff-producing headwaters and perennial runoff-producing lowlands. Within these landscape elements, we characterized the timing and magnitude of precipitation, runoff, and runoff-generating flow paths. The active surface drainage network (ASDN) reflected connectivity to, and contributions from, source areas that differed under baseflow and stormflow conditions. The baseflow-associated ASDN expanded and contracted seasonally, driven by the rise and fall of the seasonal water table. Superimposed on this were event-activated source area contributions driven by connectivity to surficial and shallow subsurface flow paths. Frequently activated shallow flow paths also caused increased in-stream dissolved organic carbon (DOC) concentrations with increases in runoff across both watershed scales. The spread and variability within this DOC-runoff relationship was driven by a seasonal depletion of DOC from continual shallow subsurface flow path activation and subsequent replenishment from autumn litterfall. Our findings suggest that hydrobiogeochemical signals at larger watershed outlets can be driven by the expansion, contraction, and connection of lateral, longitudinal, and vertical source areas with distinct runoff generation processes.

Decomposing the profile of PM in two low polluted German cities--mapping of air mass residence time, focusing on potential long range transport impacts.

PubMed

Dimitriou, Konstantinos; Kassomenos, Pavlos

2014-07-01

This paper aims to decompose the profile of particulates in Karlsruhe and Potsdam (Germany), focusing on the localization of PM potential transboundary sources. An air mass cluster analysis was implemented, followed by a study of air mass residence time on a grid of a 0.5° × 0.5° resolution. Particulate/gaseous daily air pollution and meteorological data were used to indicate PM local sources. Four Principal Component Analysis (PCA) components were produced: traffic, photochemical, industrial/domestic and particulate. PM2.5/PM10 ratio seasonal trends, indicated production of PMCOARSE (PM10-PM2.5) from secondary sources in Potsdam during warm period (WP). The residing areas of incoming slow moving air masses are potential transboundary PM sources. For Karlsruhe those areas were mainly around the city. An air mass residence time secondary peak was observed over Stuttgart. For Potsdam, areas with increased dwelling time of the arriving air parcels were detected particularly above E/SE Germany. Copyright © 2014 Elsevier Ltd. All rights reserved.

Cardioprotective cryptides derived from fish and other food sources: generation, application, and future markets.

PubMed

Mora, Leticia; Hayes, Maria

2015-02-11

The primary function of dietary protein is to provide amino acids for protein synthesis. However, protein is also a source of latent bioactive peptides or cryptides with potential health benefits including the control and regulation of blood pressure. Hypertension or high blood pressure is one of the major, controllable risk factors in the development of cardiovascular disease (CVD), and it is also implicated in the development of myocardial infarction, heart failure, and end-stage diabetes. Cryptides can act on various systems of the body including the circulatory, gastrointestinal (GI), nervous, skeletal, and respiratory systems. A number of studies carried out to date have examined the health benefits of food protein isolates and hydrolysates. This review provides an overview of existing blood pressure regulating peptides and products derived from fish and other protein sources and hydrolysates. It discusses the methods used currently to generate and identify cryptides from these sources and their application in food and pharmaceutical products. It also looks at the current market for protein-derived peptides and peptide-containing products, legislation governing their use, and the future development of research in this area.

Contamination source review for Building E7995, Edgewood Area, Aberdeen Proving Ground, Maryland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Booher, M.N.; Miller, G.A.; Draugelis, A.K.

1995-09-01

The US Army Aberdeen Proving Ground (APG) commissioned Argonne National Laboratory (ANL) to conduct a contamination source review to identify and define areas of toxic or hazardous contaminants and to assess the physical condition and accessibility of APG buildings. The information obtained from the review may be used to assist the US Army in planning for the future use or disposition, of the buildings. The source contamination review consisted of the following tasks: historical records search, physical inspection, photographic documentation, geophysical investigation, investigation of potential hazardous materials facilities (HMFs), and review of available records regarding underground storage tanks. This reportmore » provides the results of the contamination source review for Building E7995. any of the APG facilities constructed between 1917 and the 1960s are no longer used because of obsolescence and their poor state of repair. Because many of these buildings were used for research, development, testing, and/or pilot-scale production of chemical warfare agents and other military substances, the potential exists for portions of the buildings to be contaminated with these substances, their degradation products, and other laboratory or industrial chemicals. These buildings, and associated structures or appurtenances, may contribute to environmental concerns at APG.« less

Accumulation status, sources and phytoavailability of metals in greenhouse vegetable production systems in Beijing, China.

PubMed

Xu, Li; Lu, Anxiang; Wang, Jihua; Ma, Zhihong; Pan, Ligang; Feng, Xiaoyuan; Luan, Yunxia

2015-12-01

The accumulation status, sources and phytoavailability of selected metals in greenhouse vegetable production systems in peri-urban areas of Beijing were investigated. The mean concentrations of As, Cd, Cr, Hg and Pb in greenhouse soils were 8.44, 0.25, 69.0, 0.09 and 22.0 mg kg(-1), dw, respectively. According to principal component analysis, As, Cd, Cr and Hg are mainly from anthropogenic source, but Pb is likely from natural source. Metal concentrations in all vegetable samples were decreased in the order of Cr>As>Pb>Cd>Hg. Compared with root and fruit vegetables, leaf vegetables had relatively high concentrations and transfer factors of heavy metals, except for Cd. By including soil pH, OM and greenhouse soil metals, 10 empirical models were derived using stepwise multiple linear regression analysis to predict heavy metal concentrations in the edible parts of different vegetables. Among the different vegetable groups, the highest intakes of metals occurred through consumption of leaf vegetables for the two age groups, except for Cd. The HI value of the studied metals were all below 1, indicating that consumption of vegetables grown in greenhouse soils was of low risk to consumers in our study area. Copyright © 2015 Elsevier Inc. All rights reserved.

What Air Quality Models Tell Us About Sources and Sinks of Atmospheric Aldehydes

NASA Astrophysics Data System (ADS)

Luecken, D.; Hutzell, W. T.; Phillips, S.

2010-12-01

Atmospheric aldehydes play important roles in several aspects of air quality: they are critical radical sources that drive ozone formation, they are hazardous air pollutants that are national drivers for cancer risk, they participate in aqueous chemistry and potentially aerosol formation, and are key species for evaluating the accuracy of isoprene emissions. For these reasons, it is important to accurately understand their sources and sinks, and the sensitivity of their concentrations to emission controls. While both compounds have been included in air quality modeling for many years, current, state-of-the-science chemical mechanisms have difficulty reproducing measured values of aldehydes, which calls into question the robustness of ozone, HAPs and aerosol predictions. In the past, we have attributed discrepancies to measurement errors, inventory errors, or the focus on high-NOx urban regimes. Despite improvements in all of these areas, the measurements still diverge from model predictions, with formaldehyde often underpredicted by 50% and acetaldehyde showing a large degree of scatter - from 20% overprediction to 50% underprediction. To better examine the sources of aldehydes, we implemented the new SAPRC07T mechanism in the Community Multi-Scale Air Quality (CMAQ) model. This mechanism incorporates current recommendations for kinetic data and has the most detailed representation of product formation under a wide variety of conditions of any mechanism used in regional air quality models. We use model simulations to pinpoint where and when aldehyde concentrations tend to deviate from measurements. We demonstrate the role of secondary production versus primary emissions in aldehdye concentrations and find that secondary sources produce the largest deviations from measurements. We identify which VOCs are most responsible for aldehyde secondary production in the areas of the U.S. where the largest health effects are seen, and discuss how this affects consideration of control strategies.

The cretaceous source rocks in the Zagros Foothills of Iran: An example of a large size intracratonic basin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bordenave, M.L.; Huc, A.Y.

1993-02-01

The Zagros orogenic belt of Iran is one of the world most prolific petroleum producing area. However, most of the oil production is originated from a relatively small area, the 60,000 km[sup 2] wide Dezful Embayment which contains approximately 12% of the proven oil global reserves. The distribution of the oil and gas fields results from the area extent of six identified source rock layers, their thermal history and reservoir, cap rock and trap availability. In this paper, the emphasis is three of the layers of Cretaceous sources rocks. The Garau facies was deposited during the Neocomian to Albian intervalmore » over Lurestan, Northeast Khuzestan and extends over the extreme northeast part of Fars, the Kazhdumi source rock which deposited over the Dezful Embayment, and eventually the Senonian Gurpi Formation which has marginal source rock characteristics in limited areas of Khuzestan and Northern Fars. The deposition environment of these source rock layers corresponds to semipermanent depressions, included in an overall shallow water intracratonic basin communicating with the South Tethys Ocean. These depressions became anoxic when climatic oceanographical and geological conditions were adequate, i.e., humid climate, high stand water, influxes of fine grained clastics and the existence of sills separating the depression from the open sea. Distribution maps of these source rock layers resulting from extensive field work and well control are also given. The maturation history of source rocks is reconstructed from a set of isopachs. It was found that the main contributor to the oil reserves is the Kazhdumi source rock which is associated with excellent calcareous reservoirs.« less

Radiogenic heat production in sedimentary rocks of the Gulf of Mexico Basin, south Texas

USGS Publications Warehouse

McKenna, T.E.; Sharp, J.M.

1998-01-01

Radiogenic heat production within the sedimentary section of the Gulf of Mexico basin is a significant source of heat. Radiogenic heat should be included in thermal models of this basin (and perhaps other sedimentary basins). We calculate that radiogenic heat may contribute up to 26% of the overall surface heat-flow density for an area in south Texas. Based on measurements of the radioactive decay rate of ??-particles, potassium concentration, and bulk density, we calculate radiogenic heat production for Stuart City (Lower Cretaceous) limestones, Wilcox (Eocene) sandstones and mudrocks, and Frio (Oligocene) sandstones and mudrocks from south Texas. Heat production rates range from a low of 0.07 ?? 0.01 ??W/m3 in clean Stuart City limestones to 2.21 ?? 0.24??W/m3 in Frio mudrocks. Mean heat production rates for Wilcox sandstones, Frio sandstones, Wilcox mudrocks, and Frio mudrocks are 0.88, 1.19, 1.50, and 1.72 ??W/m3, respectively. In general, the mudrocks produce about 30-40% more heat than stratigraphically equivalent sandstones. Frio rocks produce about 15% more heat than Wilcox rocks per unit volume of clastic rock (sandstone/mudrock). A one-dimensional heat-conduction model indicates that this radiogenic heat source has a significant effect on subsurface temperatures. If a thermal model were calibrated to observed temperatures by optimizing basal heat-flow density and ignoring sediment heat production, the extrapolated present-day temperature of a deeply buried source rock would be overestimated.Radiogenic heat production within the sedimentary section of the Gulf of Mexico basin is a significant source of heat. Radiogenic heat should be included in thermal models of this basin (and perhaps other sedimentary basins). We calculate that radiogenic heat may contribute up to 26% of the overall surface heat-flow density for an area in south Texas. Based on measurements of the radioactive decay rate of ??-particles, potassium concentration, and bulk density, we calculate radiogenic heat production for Stuart City (Lower Cretaceous) limestones, Wilcox (Eocene) sandstones and mudrocks, and Frio (Oligocene) sandstones and mudrocks from south Texas. Heat production rates range from a low of 0.07??0.01 ??W/m3 in clean Stuart City limestones to 2.21??0.24 ??W/m3 in Frio mudrocks. Mean heat production rates for Wilcox sandstones, Frio sandstones, Wilcox mudrocks, and Frio mudrocks are 0.88, 1.19, 1.50, and 1.72 ??W/m3, respectively. In general, the mudrocks produce about 30-40% more heat than stratigraphically equivalent sandstones. Frio rocks produce about 15% more heat than Wilcox rocks per unit volume of clastic rock (sandstone/mudrock). A one-dimensional heat-conduction model indicates that this radiogenic heat source has a significant effect on subsurface temperatures. If a thermal model were calibrated to observed temperatures by optimizing basal heat-flow density and ignoring sediment heat production, the extrapolated present-day temperature of a deeply buried source rock would be overestimated.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Hongfen, E-mail: wanghongfen11@163.com; Wang, Zhiqi; Chen, Shougang

Molybdenum carbides with surfactants as carbon sources were prepared using the carbothermal reduction of the appropriate precursors (molybdenum oxides deposited on surfactant micelles) at 1023 K under hydrogen gas. The carburized products were characterized using scanning electron microscopy (SEM), X-ray diffraction and BET surface area measurements. From the SEM images, hollow microspherical and rod-like molybdenum carbides were observed. X-ray diffraction patterns showed that the annealing time of carburization had a large effect on the conversion of molybdenum oxides to molybdenum carbides. And BET surface area measurements indicated that the difference of carbon sources brought a big difference in specific surfacemore » areas of molybdenum carbides. - Graphical abstract: Molybdenum carbides having hollow microspherical and hollow rod-like morphologies that are different from the conventional monodipersed platelet-like morphologies. Highlights: Black-Right-Pointing-Pointer Molybdenum carbides were prepared using surfactants as carbon sources. Black-Right-Pointing-Pointer The kinds of surfactants affected the morphologies of molybdenum carbides. Black-Right-Pointing-Pointer The time of heat preservation at 1023 K affected the carburization process. Black-Right-Pointing-Pointer Molybdenum carbides with hollow structures had larger specific surface areas.« less

40 CFR 63.11459 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... or more furnaces that are identical in design, including manufacturer, dimensions, production... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Glass Manufacturing Area Sources.... Continuous furnace means a glass manufacturing furnace that operates continuously except during periods of...

40 CFR 63.11403 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 14 2010-07-01 2010-07-01 false [Reserved] 63.11403 Section 63.11403 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL... Standards for Hazardous Air Pollutants for Carbon Black Production Area Sources Standards and Compliance...

Alkylphenolic compounds and bisphenol A contamination within a heavily urbanized area: case study of Paris.

PubMed

Cladière, Mathieu; Gasperi, Johnny; Lorgeoux, Catherine; Bonhomme, Céline; Rocher, Vincent; Tassin, Bruno

2013-05-01

This study evaluates the influence of a heavily urbanized area (Paris Metropolitan area), on receiving water contamination by both bisphenol A (BPA) and alkylphenol ethoxylate (APE) biodegradation product. The study began by investigating concentrations within urban sources. In addition to the more commonly studied wastewater treatment plant effluent, wet weather urban sources (including combined sewer overflows, urban runoff, and total atmospheric fallout) were considered. The initial results highlight a significant contamination of all urban sources (from a few nanograms per liter in atmospheric fallout to several micrograms per liter in the other sources) with clearly distinguishable distribution patterns. Secondly, concentration changes along the Seine River from upstream of the Paris Metropolitan area to downstream were investigated. While the concentrations of BPA and nonylphenoxy acetic acid (NP₁EC) increase substantially due to urban sources, the 4-nonylphenol concentrations remain homogeneous along the Seine. These results suggest a broad dissemination of 4-nonylphenol at the scale of the Seine River basin. Moreover, the relationship between pollutant concentrations and Seine River flow was assessed both upstream and downstream of the Paris conurbation. Consequently, a sharp decrease in dissolved NP1EC concentrations relative to Seine River flow underscores the influence of single-point urban pollution on Seine River contamination. Conversely, dissolved 4-nonylphenol concentrations serve to reinforce the hypothesis of its widespread presence at the Seine River basin scale.

Drinking water sources, availability, quality, access and utilization for goats in the Karak Governorate, Jordan.

PubMed

Al-Khaza'leh, Ja'far Mansur; Reiber, Christoph; Al Baqain, Raid; Valle Zárate, Anne

2015-01-01

Goat production is an important agricultural activity in Jordan. The country is one of the poorest countries in the world in terms of water scarcity. Provision of sufficient quantity of good quality drinking water is important for goats to maintain feed intake and production. This study aimed to evaluate the seasonal availability and quality of goats' drinking water sources, accessibility, and utilization in different zones in the Karak Governorate in southern Jordan. Data collection methods comprised interviews with purposively selected farmers and quality assessment of water sources. The provision of drinking water was considered as one of the major constraints for goat production, particularly during the dry season (DS). Long travel distances to the water sources, waiting time at watering points, and high fuel and labor costs were the key reasons associated with the problem. All the values of water quality (WQ) parameters were within acceptable limits of the guidelines for livestock drinking WQ with exception of iron, which showed slightly elevated concentration in one borehole source in the DS. These findings show that water shortage is an important problem leading to consequences for goat keepers. To alleviate the water shortage constraint and in view of the depleted groundwater sources, alternative water sources at reasonable distance have to be tapped and monitored for water quality and more efficient use of rainwater harvesting systems in the study area is recommended.

Occurrence and ecological risk assessment of emerging organic chemicals in urban rivers: Guangzhou as a case study in China.

PubMed

Peng, Feng-Jiao; Pan, Chang-Gui; Zhang, Min; Zhang, Nai-Sheng; Windfeld, Ronja; Salvito, Daniel; Selck, Henriette; Van den Brink, Paul J; Ying, Guang-Guo

2017-07-01

Urban rivers may receive contamination from various sources including point sources like domestic sewage and nonpoint sources (e.g., runoff), resulting in contamination with various chemicals. This study investigated the occurrence of emerging organic contaminants (3 endocrine disrupting compounds (EDCs), and 17 pharmaceuticals and personal care products (PPCPs)) in six urban rivers of a representative subtropical city, Guangzhou (southern China). Our results showed that EDCs and personal care products were frequently detected in the water phase and sediment phase. 4-nonylphenol (4-NP) was the most predominant compound with the highest concentration of 5050ng/L in the water phase and 14,400ng/g dry weight (dw) in the sediment. Generally, higher total concentrations of EDCs and PPCPs were detected in the four urban streams compared to the main stream Zhujiang River and the Liuxi River at the suburb area. A screening-level risk assessment showed that 4-nonylphenol and triclosan (TCS) pose potential risks to aquatic organisms in most sampling sites. For individual taxa, 4-NP may pose risks to various groups of aquatic organisms, while TCS only might pose high risks to algae. Higher contamination of EDCs and PPCPs was observed in rivers in urban area; 4-nonylphenol and triclosan showed RQs>1 in >70% of the reported area. Copyright © 2017 Elsevier B.V. All rights reserved.

Herbicides and their transformation products in source-water aquifers tapped by public-supply wells in Illinois, 2001-02

USGS Publications Warehouse

Mills, Patrick C.; McMillan, William D.

2004-01-01

During 2001-02, ground-water samples were collected from 117 public-supply wells distributed throughout Illinois to evaluate the occurrence of herbicides and their transformation products in the State?s source-water aquifers. Wells were selected using a stratified-random method to ensure representation of the major types of source-water aquifers in the State. Samples were analyzed for 18 herbicides and 18 transformation products, including 3 triazine and 14 chloroacetanilide products. Herbicide compounds (field-applied parent herbicides and their transformation products) were detected in 34 percent of samples. A subset of samples was collected unfiltered to determine if analytical results for herbicides in unfiltered samples are similar to those in paired filtered samples and, thus, can be considered equally representative of herbicide concentrations in ground water supplied to the public. The study by the U.S. Geological Survey was done in cooperation with the Illinois Environmental Protection Agency. Parent herbicides were detected in only 4 percent of all samples. The six most frequently detected herbicide compounds (from 5 to 28 percent of samples) were chloroacetanilide transformation products. The frequent occurrence of transformation products and their higher concentrations relative to those of most parent herbicides confirm the importance of obtaining information on transformation products to understand the mobility and fate of herbicides in ground-water systems. No sample concentrations determined during this study exceeded current (2003) Federal or State drinking-water standards; however, standards are established for only seven parent herbicides. Factors related to the occurrence of herbicide compounds in the State?s source-water aquifers include unconsolidated and unconfined conditions, various hydrogeologic characteristics and well-construction aspects at shallow depths, and proximity to streams. Generally, the closer an aquifer (or well location) is to a recharge area and (or) the stronger the hydraulic connection between an aquifer and a recharge area, the younger the ground water and the more vulnerable the aquifer will be to contamination by herbicide compounds. The weak relation between current (2001) statewide application rates of herbicides and current (2001-02) occurrence of herbicide compounds in source-water aquifers indicates that additional factors must be considered when relating herbicide-application rates to occurrence. These factors include historical application rates and the mobility and persistence of the various herbicide compounds in ground-water systems. Frequency of detection and concentrations of herbicides compounds in the State?s source-water aquifers are indicated to be highest during the spring, when crops are planted and herbicides primarily are applied. Excess nitrate (concentrations of nitrate, as nitrogen, higher than 3 milligrams per liter) in ground water strongly indicates the co-occurrence of herbicide compounds. However, nitrate concentrations are not a reliable indicator of herbicide-compound concentrations. The inverse relation found between current use of land for corn and soybean production and current occurrence of herbicide compounds in underlying aquifers indicates that various factors, along with current agricultural land use, contribute to herbicide occurrence. These factors include, among others, land-use history, ground-water age, ground-water-flow patterns, geology, soil microbiology, and chemistry and persistence of the herbicide compounds. Detection of agriculture-specific herbicide compounds in 71 percent of samples from urban areas with no current or recent agricultural land use near the sampled wells indicates that recharge to certain high-capacity supply wells may originate at considerable distances (up to about 10 miles) from the wells. Essentially no difference was found between the analytical results for herbicides in paired unfiltered and filtered samples,

X-ray optics for the LAMAR facility, an overview. [Large Area Modular Array of Reflectors

NASA Technical Reports Server (NTRS)

Gorenstein, P.

1979-01-01

The paper surveys the Large Area Modular Array of Reflectors (LAMAR), the concept of which is based on meeting two major requirements in X-ray astronomy, large collecting area and moderately good or better angular resolution for avoiding source confusion and imaging source fields. It is shown that the LAMAR provides the same sensitivity and signal to noise in imaging as a single large telescope having the same area and angular resolution but is a great deal less costly to develop, construct, and integrate into a space mission. Attention is also given to the LAMAR modular nature which will allow for an evolutionary development from a modest size array on Spacelab to a Shuttle launched free flyer. Finally, consideration is given to manufacturing methods which show promise of making LAMAR meet the criteria of good angular resolution, relatively low cost, and capability for fast volume production.

Methane Emissions from the Inland Waters of Alaska

NASA Astrophysics Data System (ADS)

Striegl, R. G.; Butman, D. E.; Stackpoole, S. M.; Dornblaser, M.

2017-12-01

Inland waters at high latitudes generally emit methane (CH4) continuously to the atmosphere during the open water season and build-up CH4 under ice during winter that is released over a short period following ice melt. Landscape position, stream and river size, water source, and turbulence created by water flow largely control CH4 emissions from streams and rivers. Organic carbon sources for CH4 production in lakes vary widely among lakes and landscapes and include hydrologic inputs from terrestrial sources, releases from permafrost thaw (thermokarst), and autochthonous inputs from aquatic macrophytes and algae. Lake emissions are therefore controlled by the balance between within-lake CH4 production and consumption, surface turbulence at the water-air interface, and CH4 ebullition. This creates a complex range of conditions that are difficult to characterize, where dissolved CH4 concentrations may vary by up to 4 orders of magnitude among lakes and/or within a single lake over an annual seasonal cycle. Moreover, large inputs of organic matter from permafrost thaw or other sources commonly result in high rates of bubble production and ebullition from some lakes, while other lakes have negligible ebullition. We quantified water surface areas and estimated CH4 emission rates for lakes, streams and rivers for the six major hydrologic regions of Alaska and determined that they collectively emit about 0.124 Tg C per year as CH4 to the atmosphere. Lake emissions comprise about 75% of the total. When adjusted for total land surface area in Alaska, our lake emission estimate is substantially smaller than previous global estimates for inland waters north of 50 degrees North latitude. We attribute this to incorporation of results that cover a broad range of lake conditions in interior Alaska and to new data from lakes in southwest Alaska that have very low CH4 concentration but very large surface area.

Aerobiology of Juniperus Pollen in Oklahoma, Texas, and New Mexico

NASA Technical Reports Server (NTRS)

Levetin, Estelle; Bunderson, Landon; VandeWater, Pete; Luvall, Jeff

2014-01-01

Pollen from members of the Cupressaceae are major aeroallergens in many parts of the world. In the south central and southwest United States, Juniperus pollen is the most important member of this family with J. ashei (JA) responsible for severe winter allergy symptoms in Texas and Oklahoma. In New Mexico, pollen from J. monosperma (JM) and other Juniperus species are important contributors to spring allergies, while J. pinchotii (JP) pollinates in the fall affecting sensitive individuals in west Texas, southwest Oklahoma and eastern New Mexico. Throughout this region, JA, JM, and JP occur in dense woodland populations. Generally monitoring for airborne allergens is conducted in urban areas, although the source for tree pollen may be forested areas distant from the sampling sites. Improved pollen forecasts require a better understanding of pollen production at the source. The current study was undertaken to examine the aerobiology of several Juniperus species at their source areas for the development of new pollen forecasting initiatives.

Time evolution of negative ion profile in a large cesiated negative ion source applicable to fusion reactors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yoshida, M., E-mail: yoshida.masafumi@jaea.go.jp; Hanada, M.; Kojima, A.

2016-02-15

To understand the physics of the cesium (Cs) recycling in the large Cs-seeded negative ion sources relevant to ITER and JT-60SA with ion extraction area of 45-60 cm × 110-120 cm, the time evolution of the negative ion profile was precisely measured in JT-60SA where the ion extraction area is longitudinally segmented into 5. The Cs was seeded from the oven at 180 °C to the ion source. After 1 g of Cs input, surface production of the negative ions appeared only in the central segment where a Cs nozzle was located. Up to 2 g of Cs, the negative ionmore » profile was longitudinally expanded over full ion extraction area. The measured time evolution of the negative ion profile has the similar tendency of distribution of the Cs atoms that is calculated. From the results, it is suggested that Cs atom distribution is correlated with the formation of the negative ion profile.« less

Tracing sources of sulfur in the Florida everglades

USGS Publications Warehouse

Bates, A.L.; Orem, W.H.; Harvey, J.W.; Spiker, E. C.

2002-01-01

We examined concentrations and sulfur isotopic ratios (34S/32S, expressed as ??34S in parts per thousand [???] units) of sulfate in surface water, ground water, and rain water from sites throughout the northern Everglades to establish the sources of sulfur to the ecosystem. The geochemistry of sulfur is of particular interest in the Everglades because of its link, through processes mediated by sulfate -reducing bacteria, to the production of toxic methylmercury in this wetland ecosystem. Methylmercury, a neurotoxin that is bioaccumulated, has been found in high concentrations in freshwater fish from the Everglades, and poses a potential threat to fish-eating wildlife and to human health through fish consumption. Results show that surface water in large portions of the Everglades is heavily contaminated with sulfate, with the highest concentrations observed in canals and marsh areas receiving canal discharge. Spatial patterns in the range of concentrations and ??34S values of sulfate in surface water indicate that the major source of sulfate in sulfur-contaminated marshes is water from canals draining the Everglades Agricultural Area. Shallow ground water underlying the Everglades and rain water samples had much lower sulfate concentrations and ??34S values distinct from those found in surface water. The ??34S results implicate agricultural fertilizer as a major contributor to the sulfate contaminating the Everglades, but ground water under the Everglades Agricultural Area (EAA) may also be a contributing source. The contamination of the northern Everglades with sulfate from canal discharge may be a key factor in controlling the distribution and extent of methylmercury production in the Everglades.

Managing agricultural phosphorus for water quality: lessons from the USA and China.

PubMed

Sharpley, Andrew; Wang, Xiaoyan

2014-09-01

The accelerated eutrophication of freshwaters and to a lesser extent some coastal waters is primarily driven by phosphorus (P) inputs. While efforts to identify and limit point source inputs of P to surface waters have seen some success, nonpoint sources remain difficult to identify, target, and remediate. As further improvements in wastewater treatment technologies becomes increasingly costly, attention has focused more on nonpoint source reduction, particularly the role of agriculture. This attention was heightened over the last 10 to 20 years by a number of highly visible cases of nutrient-related water quality degradation; including the Lake Taihu, Baltic Sea, Chesapeake Bay, and Gulf of Mexico. Thus, there has been a shift to targeted management of critical sources of P loss. In both the U.S. and China, there has been an intensification of agricultural production systems in certain areas concentrate large amounts of nutrients in excess of local crop and forage needs, which has increased the potential for P loss from these areas. To address this, innovative technologies are emerging that recycle water P back to land as fertilizer. For example, in the watershed of Lake Taihu, China one of the largest surface fresh waters for drinking water supply in China, local governments have encouraged innovation and various technical trials to harvest harmful algal blooms and use them for bio-gas, agricultural fertilizers, and biofuel production. In any country, however, the economics of remediation will remain a key limitation to substantial changes in agricultural production. Copyright © 2014. Published by Elsevier B.V.

Distribution of agrochemicals in the lower Mississippi River and its tributaries

USGS Publications Warehouse

Pereira, W.E.; Rostad, C.E.; Leiker, T.J.

1990-01-01

The Mississippi River and its tributaries drain extensive agricultural regions of the Mid-Continental United States. Millions of pounds of herbicides are applied annually in these areas to improve crop yields. Many of these compounds are transported into the river from point and nonpoint sources, and eventually are discharged into the Gulf of Mexico. Studies being conducted by the U.S. Geological Survey along the lower Mississippi River and its major tributaries, representing a 2000 km river reach, have confirmed that several triazine and acetanilide herbicides and their degradation products are ubiquitous in this riverine system. These compounds include atrazine and its degradation products desethyl and desisopropylatrazine, cyanazine, simazine, metolachlor, and alachlor and its degradation products 2-chloro-2',6'-diethylacetanilide, 2-hydroxy-2',6-diethylacetanilide and 2,6-diethylaniline. Loads of these compounds were determined at 16 different sampling stations. Stream-load calculations provided information concerning (a) conservative or nonconservative behavior of herbicides; (b) point sources or nonpoint sources; (c) validation of sampling techniques; and (d) transport past each sampling station.

Evidence of Aerosols as a Media for Rapid Daytime HONO Production over China

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Zhen; Wang, Yuhang; Costabile, Francesa

Current knowledge of daytime HONO sources remains incomplete. A large missing daytime HONO source has been found in many places around the world, including polluted regions in China. Conventional understanding and recent studies attributed this missing source mainly to ground surface processes or gas-phase chemistry, while assuming aerosols to be an insignificant media for HONO production. We analyze in situ observations of HONO and its precursors at an urban site in Beijing, China, and report an apparent dependence of the missing HONO source strength on aerosol surface area and solar ultraviolet radiation. Based on extensive correlation analysis and process-modeling, wemore » propose that the rapid daytime HONO production in Beijing can be explained by enhanced hydrolytic disproportionation of NO2 on aqueous aerosol surfaces due to catalysis by dicarboxylic acid anions. The combination of high abundance of NO2, aromatic hydrocarbons, and aerosols over broad regions in China likely leads to elevated HONO levels, rapid OH production, and enhanced oxidizing capacity on a regional basis. Our findings call for attention to aerosols as a media for daytime heterogeneous HONO production in polluted regions like Beijing. This study also highlights the complex and uncertain heterogeneous chemistry in China, which merits future efforts of reconciling regional modeling and laboratory experiments, in order to understand and mitigate the regional particulate and O3 pollutions over China.« less

Improving risk estimates of runoff producing areas: formulating variable source areas as a bivariate process.

PubMed

Cheng, Xiaoya; Shaw, Stephen B; Marjerison, Rebecca D; Yearick, Christopher D; DeGloria, Stephen D; Walter, M Todd

2014-05-01

Predicting runoff producing areas and their corresponding risks of generating storm runoff is important for developing watershed management strategies to mitigate non-point source pollution. However, few methods for making these predictions have been proposed, especially operational approaches that would be useful in areas where variable source area (VSA) hydrology dominates storm runoff. The objective of this study is to develop a simple approach to estimate spatially-distributed risks of runoff production. By considering the development of overland flow as a bivariate process, we incorporated both rainfall and antecedent soil moisture conditions into a method for predicting VSAs based on the Natural Resource Conservation Service-Curve Number equation. We used base-flow immediately preceding storm events as an index of antecedent soil wetness status. Using nine sub-basins of the Upper Susquehanna River Basin, we demonstrated that our estimated runoff volumes and extent of VSAs agreed with observations. We further demonstrated a method for mapping these areas in a Geographic Information System using a Soil Topographic Index. The proposed methodology provides a new tool for watershed planners for quantifying runoff risks across watersheds, which can be used to target water quality protection strategies. Copyright © 2014 Elsevier Ltd. All rights reserved.

Occurrence of organophosphorus flame retardants in indoor dust in multiple microenvironments of southern China and implications for human exposure.

PubMed

He, Chun-Tao; Zheng, Jing; Qiao, Lin; Chen, She-Jun; Yang, Jun-Zhi; Yuan, Jian-Gang; Yang, Zhong-Yi; Mai, Bi-Xian

2015-08-01

Organophosphorus flame retardants (OPFRs) are important alternatives to brominated flame retardants (BFRs), but information on their contamination of the environment in China is rare. We examined the occurrence of 12 OPFRs in indoor dust in four microenvironments of southern China, including a rural electronic waste (e-waste) recycling area, a rural non-e-waste area, urban homes, and urban college dormitory rooms. The OPFR concentrations (with a median of 25.0 μg g(-1)) were highest in the e-waste area, and the concentrations in other three areas were lower and comparable (7.48-11.0 μg g(-1)). The levels of OPFRs in the present study were generally relatively lower than the levels of OPFRs found in Europe, Canada, and Japan because BFRs are still widely used as the major FRs in China. The composition profile of OPFRs in the e-waste area was dominated by tricresyl phosphate (TCP) (accounting for 40.7%, on average), while tris(2-chloroethyl) phosphate (TCEP) was the most abundant OPFR (64.4%) in the urban areas (homes and college dormitories). These two distribution patterns represent two OPFR sources (i.e., emissions from past e-waste and from current household products and building materials). The difference in the OPFR profiles in the rural area relative to the OPFR profiles in the urban and e-waste areas suggests that the occurrence of OPFRs is due mainly to emissions from characteristic household products in rural homes. Although human exposures to all the OPFRs were under the reference doses, the health risk for residents in the e-waste area is a concern, considering the poor sanitary conditions in this area and exposure from other sources. Copyright © 2015 Elsevier Ltd. All rights reserved.

Brominated flame retardants in food and environmental samples from a production area in China: concentrations and human exposure assessment.

PubMed

Li, Peng; Wu, Hui; Li, Qiuxu; Jin, Jun; Wang, Ying

2015-11-01

Human exposure to brominated flame retardants (BFRs: decabromodiphenyl ether (BDE209), decabromodiphenyl ethane (DBDPE), hexabromobenzene (HBB), pentabromoethylbenzene (PBEB), pentabromotoluene (PBT), 1,2,3,4,5-pentabromobenzene (PBBz), and 2,3,5,6-tetrabromo-p-xylene (TBX)) in a brominated flame retardant production area (Weifang, Shandong Province, China) was estimated. Thirty food samples, 14 air samples, and 13 indoor dust samples were analyzed. BDE209 and DBDPE were the dominant BFRs in all samples. Higher alternative brominated flame retardant (including DBDPE, HBB, PBEB, PBT, PBBz, and TBX) concentrations were found in vegetables than in fish and meat; thus, plant-original foods might be important alternative BFR sources in the study area. The BDE209 and alternative BFR concentrations in air were 1.5×10(4) to 2.2×10(5) and 620 to 3.6×10(4) pg/m3, respectively. Mean total BFR exposures through the diet, inhalation, and indoor dust ingestion were 570, 3000, and 69 ng/d, respectively (16, 82, and 2% of total intake, respectively). Inhalation was the dominant BFR source except for DBDPE, for which diet dominated. BDE209 contributed 85% of the total BFR intake in the study area.

Contamination source review for Building E3642, Edgewood Area, Aberdeen Proving Ground, Maryland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Booher, M.N.; O`Reilly, D.P.; Draugelis, A.K.

1995-09-01

Many of the APG facilities constructed between 1917 and the 1960s are no longer used because of obsolescence and their poor state of repair. Because many of these buildings were used for research, development, testing, and/or pilot-scale production of chemical warfare agents and other military substances, the potential exists for portions of these buildings to be contaminated with these substances, their degradation products, and other laboratory or industrial chemicals. These buildings and associated structures or appurtenances may contribute to environmental concerns at APG. The US Army Aberdeen Proving Ground (APG) commissioned Argonne National Laboratory (ANL) to conduct a contamination sourcemore » review to identify and define areas of toxic or hazardous contaminants and to assess the physical condition and accessibility of APG buildings. The information obtained from the review may be used to assist the US Army in planning for the future use or disposition of the buildings. The contamination source review consisted of the following tasks: historical records search, physical inspection, photographic documentation, geophysical investigation and review of available records regarding underground storage tanks associated with the building. This report provides the results of the contamination source review for Building E3642.« less

Assessment of nonpoint-source contamination of the High Plains Aquifer in south-central Kansas, 1987

USGS Publications Warehouse

Helgesen, John O.; Stullken, Lloyd E.; Rutledge, A.T.

1994-01-01

Ground-water quality was assessed in a 5,000-square-mile area of the High Plains aquifer in south-central Kansas that is susceptible to nonpoint-source contamination from agricultural and petroleum-production activities. Of particular interest was the presence of agricultural chemicals and petroleum-derived hydrocarbons that might have been associated with brines that formerly were disposed into unlined ponds. Random sampling of ground water was done within a framework of discrete land-use areas (irrigated cropland, petroleum-production land containing former brine-disposal ponds, and undeveloped rangeland) of 3-10 square miles. Although true baseline water-quality conditions probably are rare, in this region they are represented most closely by ground water in areas of undeveloped rangeland. The sampling design enabled statistical hypothesis testing, using nonparametric procedures, of the effects of land use, unsaturated-zone lithology, and type of well sampled. Results indicate that regional ground-water quality has been affected by prevailing land-use activities, as shown by increased concentrations of several inorganic constituents. Ground water beneath irrigated cropland was characterized by significantly larger concentrations of hardness, alkalinity, calcium, magnesium, potassium, fluofide, and nitrite plus nitrate than was water beneath undeveloped rangeland. Few nondegraded pesticides were detected in the aquifer, probably because of degradation and sorption. Atrazine was the most common, but only in small concentrations. round water beneath petroleum-production land was characterized by significantly larger concentrations of hardness, alkalinity, dissolved solids, sodium, and chloride than was water beneath undeveloped rangeland. Nonpoint-source contamination by oil-derived hydrocarbons was not discernible. The occurrences of trace organic compounds were similar between petroleum-production land and undeveloped rangeland, which indicates a natural origin for these compounds. The unsaturated zone in the study area is lithologically heterogeneous and contains substantial amounts of clay that inhibit the downward movement of water and solutes. Within the aquifer, the rate of lateral regional flow and solute transport is slow enough so that the ground-water quality reflects overlying land use in discrete areas of several square miles, but it is still sufficiently rapid so that the type of well sampled is not important in regional characterizations of water quality beneath irrigated cropland; the seasonal pumping of irrigation wells does not appear to divert regional flow enough to cause substantial local anomalies of more mineralized ground water.

Life-Cycle Cost and Environmental Assessment of Decentralized Nitrogen Recovery Using Ion Exchange from Source-Separated Urine through Spatial Modeling.

PubMed

Kavvada, Olga; Tarpeh, William A; Horvath, Arpad; Nelson, Kara L

2017-11-07

Nitrogen standards for discharge of wastewater effluent into aquatic bodies are becoming more stringent, requiring some treatment plants to reduce effluent nitrogen concentrations. This study aimed to assess, from a life-cycle perspective, an innovative decentralized approach to nitrogen recovery: ion exchange of source-separated urine. We modeled an approach in which nitrogen from urine at individual buildings is sorbed onto resins, then transported by truck to regeneration and fertilizer production facilities. To provide insight into impacts from transportation, we enhanced the traditional economic and environmental assessment approach by combining spatial analysis, system-scale evaluation, and detailed last-mile logistics modeling using the city of San Francisco as an illustrative case study. The major contributor to energy intensity and greenhouse gas (GHG) emissions was the production of sulfuric acid to regenerate resins, rather than transportation. Energy and GHG emissions were not significantly sensitive to the number of regeneration facilities. Cost, however, increased with decentralization as rental costs per unit area are higher for smaller areas. The metrics assessed (unit energy, GHG emissions, and cost) were not significantly influenced by facility location in this high-density urban area. We determined that this decentralized approach has lower cost, unit energy, and GHG emissions than centralized nitrogen management via nitrification-denitrification if fertilizer production offsets are taken into account.

The Geysers-Clear Lake geothermal area, California - an updated geophysical perspective of heat sources

USGS Publications Warehouse

Stanley, W.D.; Blakely, R.J.

1995-01-01

The Geysers-Clear Lake geothermal area encompasses a large dry-steam production area in The Geysers field and a documented high-temperature, high-pressure, water-dominated system in the area largely south of Clear Lake, which has not been developed. An updated view is presented of the geological/geophysical complexities of the crust in this region in order to address key unanswered questions about the heat source and tectonics. Forward modeling, multidimensional inversions, and ideal body analysis of the gravity data, new electromagnetic sounding models, and arguments made from other geophysical data sets suggest that many of the geophysical anomalies have significant contributions from rock property and physical state variations in the upper 7 km and not from "magma' at greater depths. Regional tectonic and magmatic processes are analyzed to develop an updated scenario for pluton emplacement that differs substantially from earlier interpretations. In addition, a rationale is outlined for future exploration for geothermal resources in The Geysers-Clear Lake area. -from Authors

[A study on the true nature of "Chinese jinseng"].

PubMed

Yang, Jeong-pil; Yeo, In-sok

2003-12-01

Studies generally, it is believed that the ancient 'Chinese ginseng' did exist due to the fact that it is clearly recorded in the Chinese historical and medicine-related sources. Although it is hard to deny that such 'ginseng' did exist in ancient China, the re-examination of its true nature is also necessary. In other words, certain refutation can be made against the claim that ancient 'Chinese jinseng' was in fact 'Panax jinseng' (C. A. Mey.), since the Chinese jinseng accounts do not tell that it is such. For example, when looking into its shape based on descriptions, the 'Chinese Jinseng' has black seed, hairy stem, and violet flower. ' Panax jinseng' on the other hand, has opal seed, no-hair stem, and light-green flower. In terms of cultivation centre, most of mainland China is unsuitable for Jinseng production with the exception of the Shangdang area of Shanxi province, which solely had the reputation of being the production centre of ancient 'Chinese jinseng'. However, when looking into the Chinese sources for jinseng-producing areas, they show that Hepei and Liaoning province and Jiangnan (south of the Yangtze river) areas also have had some jinseng-related history. Regardless of such instance, these regions did not cultivate Panax jinseng. As shown above, ancient 'Chinese jinseng' was far from being identical, in respect to its shape or production areas, to Panax jinseng. Hence, this study came to the conclusion that there is indeed very high skepticism about whether the true nature of 'jinseng' in ancient China was in fact Panax jinseng. On the contrary, there is higher possibility that the ancient 'Chinese jinseng' is totally different plant from Panax jinseng which is actually Codonopsis pilosula. When examining the shape and production areas of Codonopsis pilosula, it is closely matched with many parts of ancient 'Chinese jinseng' texts. In short, it is presumed that the 'Chinese jinseng' did indeed exist in ancient China but it was Codonopsis pilosula instead of Panax jinseng.

Who is behind the stocking of energy-dense foods and beverages in small stores? The importance of food and beverage distributors.

PubMed

Ayala, Guadalupe X; D'Angelo, Heather; Gittelsohn, Joel; Horton, Lucy; Ribisl, Kurt; Sindberg, Lesley Schmidt; Olson, Christina; Kharmats, Anna; Laska, Melissa N

2017-12-01

The present study examined food and beverage distributors' sourcing, placement and promotion of obesogenic (energy-dense, nutrient-poor) product categories from the perspective of small food store owners/managers. The obesogenic product categories of interest were savoury snacks, sugary beverages, sweet snacks, confectionery and frozen treats. Specifically, we examined how frequently distributors sourced these products, and the types of agreements and expectations they had for their placement and promotion. Differences were explored by store size and ethnicity. Fresh produce was used as a comparison when examining differences in frequency of sourcing only, with implications for healthy food access. Survey research involving in-person interviews. Four urban areas in the USA: Baltimore, MD; Durham, NC; Minneapolis/St. Paul, MN; and San Diego, CA. Seventy-two small food store owners/managers, 65 % consent rate. Most distributors sourced obesogenic products weekly. Agreements to place products were predominantly informal (e.g. handshake) with sweet snack, confectionery and frozen treat distributors, and formal (e.g. contract) with savoury snack and sugary beverage distributors. Free-standing displays were the most common incentive provided by distributors and they expected some control over their placement and pricing. Free/discounted products and signage were also common incentives but slotting fees were not. Smaller stores and ethnic stores were less likely to receive various incentives, but among sweet snack distributors, they were more likely to control the price in ethnic v. non-ethnic stores. Obesogenic products are ubiquitous. Influencing what is made available to consumers in the retail food environment needs to consider the distributor.

Mercury Sources and Fate in the Gulf of Maine

PubMed Central

Sunderland, Elsie M.; Amirbahman, Aria; Burgess, Neil M.; Dalziel, John; Harding, Gareth; Jones, Stephen H.; Kamai, Elizabeth; Karagas, Margaret R.; Shi, Xun; Chen, Celia Y.

2012-01-01

Most human exposure to mercury (Hg) in the United States is from consuming marine fish and shellfish. The Gulf of Maine is a complex marine ecosystem comprised of twelve physioregions, including the Bay of Fundy, coastal shelf areas and deeper basins that contain highly productive fishing grounds. Here we review available data on spatial and temporal Hg trends to better understand the drivers of human and biological exposures. Atmospheric Hg deposition from U.S. and Canadian sources has declined since the mid-1990s in concert with emissions reductions but deposition from global sources has increased. Oceanographic circulation is the dominant source of total Hg inputs to the entire Gulf of Maine region (59%), followed by atmospheric deposition (28%), wastewater/industrial sources (8%), and rivers (5%). Resuspension of sediments increases MeHg inputs to overlying waters raising concerns about benthic trawling activities in shelf regions. In the near coastal areas, elevated sediment and mussel Hg levels are co-located in urban embayments and near large historical point sources. Temporal patterns in sentinel species (mussels and birds) have in some cases declined in response to localized point source mercury reductions but overall Hg trends do not show consistent declines. For example, levels of Hg have either declined or remained stable in eggs from four seabird species collected in the Bay of Fundy since 1972. Quantitatively linking Hg exposures from fish harvested from the Gulf of Maine to human health risks is challenging at this time because no data are available on the geographic origin of seafood consumed by coastal residents. In addition, there is virtually no information on Hg levels in commercial species for offshore regions of the Gulf of Maine where some of the most productive fisheries are located. Both of these data gaps should be priorities for future research. PMID:22572623

Greenhouse gas and ammonia emissions from an open-freestall dairy in southern idaho.

PubMed

Leytem, April B; Dungan, Robert S; Bjorneberg, David L; Koehn, Anita C

2013-01-01

Concentrated dairy operations emit trace gases such as ammonia (NH), methane (CH), and nitrous oxide (NO) to the atmosphere. The implementation of air quality regulations in livestock-producing states increases the need for accurate on-farm determination of emission rates. Our objective was to determine the emission rates of NH, CH, and NO from the open-freestall and wastewater pond source areas on a commercial dairy in southern Idaho using a flush system with anaerobic digestion. Gas concentrations and wind statistics were measured and used with an inverse dispersion model to calculate emission rates. Average emissions per cow per day from the open-freestall source area were 0.08 kg NH, 0.41 kg CH, and 0.02 kg NO. Average emissions from the wastewater ponds (g m d) were 6.8 NH, 22 CH, and 0.2 NO. The combined emissions on a per cow per day basis from the open-freestall and wastewater pond areas averaged 0.20 kg NH and 0.75 kg CH. Combined NO emissions were not calculated due to limited available data. The wastewater ponds were the greatest source of total farm NH emissions (67%) in spring and summer. The emissions of CH were approximately equal from the two source areas in spring and summer. During the late fall and winter months, the open-freestall area constituted the greatest source area of NH and CH emissions. Data from this study can be used to develop trace gas emissions factors from open-freestall dairies in southern Idaho and other open-freestall production systems in similar climatic regions. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Contribution of Fugitive Emissions for PM10 Concentrations in an Industrial Area of Portugal

NASA Astrophysics Data System (ADS)

Marta Almeida, Susana; Viana Silva, Alexandra; Garcia, Silvia; Miranda, Ana Isabel

2013-04-01

Significant atmospheric dust arises from the mechanical disturbance of granular material exposed to the air. Dust generated from these open sources is termed "fugitive" because it is not discharged to the atmosphere in a confined flow stream. Common sources of fugitive dust include unpaved roads, agricultural tilling operations, aggregate storage piles, heavy construction and harbor operations. The objective of this work was to identify the likeliness and extend of the PM10 limit value exceedences due to fugitive emissions in a particularly zone where PM fugitive emissions are a core of environmental concerns - Mitrena, Portugal. Mitrena, is an industrial area that coexists with a high-density urban region (Setúbal) and areas with an important environmental concern (Sado Estuary and Arrábida which belongs to the protected area Natura 2000 Network). Due to the typology of industry sited in Mitrena (e.g. power plant, paper mill, cement, pesticides and fertilized productions), there are a large uncontrolled PM fugitive emissions, providing from heavy traffic and handling and storage of raw material on uncover stockyards in the harbor and industries. Dispersion modeling was performed with the software TAPM (The Air Pollution Model) and results were mapped over the study area, using GIS (Geographic Information Systems). Results showed that managing local particles concentrations can be a frustrating affair because the weight of fugitive sources is very high comparing with the local anthropogenic stationary sources. In order to ensure that the industry can continue to meet its commitments in protecting air quality, it is essential to warrant that the characteristics of releases from all fugitive sources are fully understood in order to target future investments in those areas where maximum benefit will be achieved.

Turning schedules influence final composition of composted swine manure

USDA-ARS?s Scientific Manuscript database

Liquid swine (Sus scrofa domesticus) manure is a high-moisture, low-nutrient product that limits economical transport to areas in proximity of its source, possibly contributing to localized high soil nutrient levels. Composting swine manure converts liquid slurries to solids at lower moisture conten...

40 CFR 63.11502 - What definitions apply to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

...: process knowledge, an engineering assessment, or test data. Byproduct means a chemical (liquid, gas, or... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Chemical Manufacturing Area Sources...., for chemical value as a product, isolated intermediate, byproduct, or coproduct, or for heat value...

40 CFR 63.11401 - What are my compliance dates?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 14 2010-07-01 2010-07-01 false What are my compliance dates? 63.11401 Section 63.11401 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS...) National Emission Standards for Hazardous Air Pollutants for Carbon Black Production Area Sources...

40 CFR 412.20 - Applicability.

Code of Federal Regulations, 2013 CFR

2013-07-01

... CONCENTRATED ANIMAL FEEDING OPERATIONS (CAFO) POINT SOURCE CATEGORY Ducks § 412.20 Applicability. This subpart applies to discharges resulting from the production areas at dry lot and wet lot duck CAFOs. This subpart does not apply to such CAFOs with less than the following capacities: 5,000 ducks. ...

40 CFR 412.20 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-07-01

... CONCENTRATED ANIMAL FEEDING OPERATIONS (CAFO) POINT SOURCE CATEGORY Ducks § 412.20 Applicability. This subpart applies to discharges resulting from the production areas at dry lot and wet lot duck CAFOs. This subpart does not apply to such CAFOs with less than the following capacities: 5,000 ducks. ...

40 CFR 412.20 - Applicability.

Code of Federal Regulations, 2012 CFR

2012-07-01

... CONCENTRATED ANIMAL FEEDING OPERATIONS (CAFO) POINT SOURCE CATEGORY Ducks § 412.20 Applicability. This subpart applies to discharges resulting from the production areas at dry lot and wet lot duck CAFOs. This subpart does not apply to such CAFOs with less than the following capacities: 5,000 ducks. ...

40 CFR 412.20 - Applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... CONCENTRATED ANIMAL FEEDING OPERATIONS (CAFO) POINT SOURCE CATEGORY Ducks § 412.20 Applicability. This subpart applies to discharges resulting from the production areas at dry lot and wet lot duck CAFOs. This subpart does not apply to such CAFOs with less than the following capacities: 5,000 ducks. ...

40 CFR 412.20 - Applicability.

Code of Federal Regulations, 2014 CFR

2014-07-01

... CONCENTRATED ANIMAL FEEDING OPERATIONS (CAFO) POINT SOURCE CATEGORY Ducks § 412.20 Applicability. This subpart applies to discharges resulting from the production areas at dry lot and wet lot duck CAFOs. This subpart does not apply to such CAFOs with less than the following capacities: 5,000 ducks. ...

Sources and Seasonality of Volatile Organic Compounds in the Northern Front Range Metropolitan Area

NASA Astrophysics Data System (ADS)

Abeleira, A.; Pollack, I. B.; Sive, B. C.; Zaragoza, J.; Lindaas, J.; Fischer, E. V.; Farmer, D.

2016-12-01

The Northern Front Range Metropolitan Area (NFRMA) of Colorado, with a growing population of over 3 million, was deemed an ozone (O3) nonattainment area (NAA) in 2008 despite continued work on NOx reductions. Ground-level O3 is produced from photochemical catalytic cycles initiated by the OH oxidation of volatile organic compounds (VOCs), and propagated through reactions involving peroxy (HO2+RO2) and NOx (NO + NO2) radicals. We measured a suite of speciated VOCs during two 8-week deployments (March-May 2015, July-September 2015) at the Boulder Atmospheric Observatory in Erie, CO. The spring deployment overlapped with the NOAA SONGNEX (Shale Oil and Natural Gas Nexus) campaign. The BAO site lies at an urban-rural interface in the NFRMA with multiple urban centers surrounding the site, a major interstate highway within 2 miles, local suburban development in Erie, agricultural operations in the surrounding counties, and recent rapid expansion of oil and gas development in adjacent Weld County. VOCs were measured hourly with a custom-built online gas chromatography system along with measurements of O3, NOx, PAN, CO, and CH4. VOC measurements included C2-C8 hydrocarbons (NMHCs), C1-C5 alkyl nitrates, C1-C2 halocarbons, and several oxygenated species (OVOCs: methyl ethyl ketone, acetone, acetaldehyde). Using Positive Matrix Factorization (PMF) we have identified four distinct VOC sources in the spring and five in the summer: 1) Oil and Natural Gas (ONG, e.g. C2 - C5 alkanes), 2) Traffic (e.g. ethyne & aromatics), 3) Background species (e.g. long-lived halogenated species), 4) Secondary production (e.g. C3-C5 alkyl nitrates & OVOCs), and for summer 5) Biogenic (e.g. isoprene). Using the source factors generated from the PMF analysis we calculated the VOC reactivity (VOCr) of each source. For both seasons, the ONG factor dominates VOCr in the mornings. In spring afternoons, a combination of background species and secondary products make up a large percentage of VOCr as primary species are photochemically removed. During summer afternoons, the Biogenic factor is a major contributor to VOCr, with an average diurnal peak up to 47% of VOCr in the late (6 - 8 pm) afternoon. This diel cycle of source contribution to VOCr indicates that both anthropogenic and biogenic VOC sources contribute to O3 production in the NFRMA.

Earth mapping - aerial or satellite imagery comparative analysis

NASA Astrophysics Data System (ADS)

Fotev, Svetlin; Jordanov, Dimitar; Lukarski, Hristo

Nowadays, solving the tasks for revision of existing map products and creation of new maps requires making a choice of the land cover image source. The issue of the effectiveness and cost of the usage of aerial mapping systems versus the efficiency and cost of very-high resolution satellite imagery is topical [1, 2, 3, 4]. The price of any remotely sensed image depends on the product (panchromatic or multispectral), resolution, processing level, scale, urgency of task and on whether the needed image is available in the archive or has to be requested. The purpose of the present work is: to make a comparative analysis between the two approaches for mapping the Earth having in mind two parameters: quality and cost. To suggest an approach for selection of the map information sources - airplane-based or spacecraft-based imaging systems with very-high spatial resolution. Two cases are considered: area that equals approximately one satellite scene and area that equals approximately the territory of Bulgaria.

Biosurfactant production through Bacillus sp. MTCC 5877 and its multifarious applications in food industry.

PubMed

Anjum, Farhan; Gautam, Gunjan; Edgard, Gnansounou; Negi, Sangeeta

2016-08-01

In this study Bacillus sp. MTCC5877 was explored for the production of biosurfactant (BSs) and various carbon sources 1% (w/v), 0.5% (w/v) nitrogen sources were tested at different pH, and temperature. Yield was measured in terms of Emulsification index (EI), Oil Displacement Area (ODA) and Drop Collapse Area (DCA) and maximum emulsification activities of BSs were found (E24) 50%, 76% and 46%, respectively, and maximum ODA of 5.0, 6.2 and 4.7cm, were shown respectively. The BS was able to reduce the surface tension of water from 72 to 30mN/m and 72 to 32mN/m. Structural compositions of BS were confirmed by FTIR, GC-MS and NMR. Anti-adhesive property of BS was determined and found effective against biofilm formation. It could remove 73% Cd from vegetable which confirms its application in food industry. Copyright © 2016 Elsevier Ltd. All rights reserved.

Epos TCS Satellite Data

NASA Astrophysics Data System (ADS)

Manunta, Michele; Mandea, Mioara; Fernández-Turiel, José Luis; Stramondo, Salvatore; Wright, Tim; Walter, Thomas; Bally, Philippe; Casu, Francesco; Zeni, Giovanni; Buonanno, Sabatino; Zinno, Ivana; Tizzani, Pietro; Castaldo, Raffaele; Ostanciaux, Emilie; Diament, Michel; Hooper, Andy; Maccaferri, Francesco; Lanari, Riccardo

2016-04-01

TCS Satellite Data is devoted to provide Earth Observation (EO) services, transversal with respect to the large EPOS community, suitable to be used in several application scenarios. In particular, the main goal is to contribute with mature services that have already well demonstrated their effectiveness and relevance in investigating the physical processes controlling earthquakes, volcanic eruptions and unrest episodes as well as those driving tectonics and Earth surface dynamics. The TCS Satellite Data will provide two kinds of services: satellite products/services, and Value-added satellite products/services. The satellite products/services are composed of three (EPOSAR, GDM and COMET) well-identified and partly already operational elements for delivering Level 1 products. Such services will be devoted to the generation of SAR interferograms, DTM and ground displacement maps through the exploitation of different advanced EO techniques for InSAR and optical data analysis. The Value-added satellite products/services are composed of 4 elements (EPOSAR, 3D-Def, Mod and COMET) of Level 2 and 3 products. Such services integrate satellite and in situ measurements and observations to retrieve information on source mechanism, such as the geometry (spatial location, depth, volume changes) and the physical parameters of the deformation sources, through the exploitation of modelling approaches. The TCS Satellite Data will provide products in two different processing and delivery modes: 1- surveillance mode - routinely product generation; 2- on demand mode - product generation performed on demand by the user. Concerning the surveillance mode, the goal is providing continuous satellite measurements in areas of particular interest from a geophysical perspective (supersites). The objective is the detection of displacement patterns changing along time and their geophysical explanation. This is a valid approach for inter-seismic movements and volcanic unrest, post-seismic and post-eruptive displacements, urban subsidence, coastal movements. The on demand mode will allow users to process available satellite data-stack by selecting the scenes and the area of interest, and properly setting some processing parameters or to perform modelling analyses. This processing mode will guarantee the possibility to analyse areas of interest for the users, thus exploiting as much as possible the global coverage strategy of satellites, as well as performing user-driven processing, benefiting from the knowledge of the characteristics of the particular investigated area and/or deformation phenomenon.

Polycyclic aromatic hydrocarbons in the urban atmosphere of Nepal: Distribution, sources, seasonal trends, and cancer risk.

PubMed

Pokhrel, Balram; Gong, Ping; Wang, Xiaoping; Wang, Chuanfei; Gao, Shaoping

2018-03-15

Atmospheric polycyclic aromatic hydrocarbons (PAHs) in urban areas have always been a global concern, as these areas are considered to be the source region. Despite studies on the concentrations of PAHs in water, soils and sediments, knowledge of the distribution patterns, seasonality and sources of PAHs in urban areas of Nepal remains limited. In this study, polyurethane foam passive air samplers were used to measure gas-phase PAH concentrations over different land types in three major cities of Nepal-namely, Kathmandu (the capital) and Pokhara (both densely populated cities), and Hetauda (an agricultural city). The average concentrations of ∑15PAHs in ng/m 3 were 16.1±7.0 (6.4-28.6), 14.1±6.2 (6.8-29.4) and 11.1±9.0 (4.1-38.0) in Kathmandu, Pokhara and Hetauda, respectively. Molecular diagnostic ratio analysis suggested that fossil fuel combustion was a common PAH source for all three cities. In addition to this, coal combustion in Kathmandu, vehicle emissions in Pokhara, and grass/wood combustion in Hetauda were also possible sources of PAHs. In terms of cancer risk from PAH inhalation, a religious site with intense incense burning, a brick production area where extensive coal combustion is common, and a market place with heavy traffic emission, were associated with a higher risk than other areas. There were no clear seasonal trends in atmospheric PAHs. The estimated cancer risk due to inhalation of gas-phase PAHs exceeded the USEPA standard at >90% of the sites. Copyright © 2017 Elsevier B.V. All rights reserved.

Global oceanic production of nitrous oxide.

PubMed

Freing, Alina; Wallace, Douglas W R; Bange, Hermann W

2012-05-05

We use transient time distributions calculated from tracer data together with in situ measurements of nitrous oxide (N(2)O) to estimate the concentration of biologically produced N(2)O and N(2)O production rates in the ocean on a global scale. Our approach to estimate the N(2)O production rates integrates the effects of potentially varying production and decomposition mechanisms along the transport path of a water mass. We estimate that the oceanic N(2)O production is dominated by nitrification with a contribution of only approximately 7 per cent by denitrification. This indicates that previously used approaches have overestimated the contribution by denitrification. Shelf areas may account for only a negligible fraction of the global production; however, estuarine sources and coastal upwelling of N(2)O are not taken into account in our study. The largest amount of subsurface N(2)O is produced in the upper 500 m of the water column. The estimated global annual subsurface N(2)O production ranges from 3.1 ± 0.9 to 3.4 ± 0.9 Tg N yr(-1). This is in agreement with estimates of the global N(2)O emissions to the atmosphere and indicates that a N(2)O source in the mixed layer is unlikely. The potential future development of the oceanic N(2)O source in view of the ongoing changes of the ocean environment (deoxygenation, warming, eutrophication and acidification) is discussed.

Different approaches to overcome uncertainties of production systems

NASA Astrophysics Data System (ADS)

Azizi, Amir; Sorooshian, Shahryar

2015-05-01

This study presented a comprehensive review on the understanding of uncertainty and the current approaches that have been proposed to handle the uncertainties in the production systems. This paper classified proposed approaches into 11 groups. The paper studied 114 scholarly papers through various international journals. The paper added the latest findings to the body of knowledge to the current reservoir of understanding of the production uncertainties. Thus, the paper prepared the needs of researchers and practitioners for easy references in this area. This review also provided an excellent source to continue further studies on how to deal with the uncertainties of production system.

Malachite green and chloramphenicol in aquatic products from regions around Dongting Lake in Hunan, China.

PubMed

He, Jiang; Cui, Jingzhen

2016-01-01

Aquatic products are important sources of animal proteins in human diet, especially in developing countries. As such, the safety of aquatic products is of primary concern. In this study, a standard method is used to detect malachite green (MG) and chloramphenicol (CAP) and to analyse the contents of these banned chemicals in turtle, mandarin fish and grass carp sampled from the region surrounding Dongting Lake area in Hunan, China. Results showed that 10.6% of the samples were MG-positive, most of them turtles. CAP was found in 8.3% of the samples, mostly in mandarin fish. These data indicated that these banned substances are still used in the surveyed area. Hence, adequate strategies must be implemented by the local government to control these banned substances.

Wind-To-Hydrogen Project: Electrolyzer Capital Cost Study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saur, G.

This study is being performed as part of the U.S. Department of Energy and Xcel Energy's Wind-to-Hydrogen Project (Wind2H2) at the National Renewable Energy Laboratory. The general aim of the project is to identify areas for improving the production of hydrogen from renewable energy sources. These areas include both technical development and cost analysis of systems that convert renewable energy to hydrogen via water electrolysis. Increased efficiency and reduced cost will bring about greater market penetration for hydrogen production and application. There are different issues for isolated versus grid-connected systems, however, and these issues must be considered. The manner inmore » which hydrogen production is integrated in the larger energy system will determine its cost feasibility and energy efficiency.« less

Perfluorinated Compounds in Greenhouse and Open Agricultural Producing Areas of Three Provinces of China: Levels, Sources and Risk Assessment

PubMed Central

Zhang, Yanwei; Tan, Dongfei; Geng, Yue; Wang, Lu; Peng, Yi; He, Zeying; Xu, Yaping; Liu, Xiaowei

2016-01-01

Field investigations on perfluoroalkyl acid (PFAA) levels in various environmental matrixes were reported, but there is still a lack of PFAA level data for agricultural environments, especially agricultural producing areas, so we collected soil, irrigation water and agricultural product samples from agricultural producing areas in the provinces of Liaoning, Shandong and Sichuan in China. The background pollution from instruments was removed and C4–C18 PFAAs were detected by LC-MS/MS. The concentrations of PFAAs in the top and deep layers of soil were compared, and the levels of PFAAs in different agricultural environments (greenhouses and open agriculture) were analyzed. We found the order of PFAA levels by province was Shandong > Liaoning > Sichuan. A descending trend of PFAA levels from top to deep soil and open to greenhouse agriculture was shown and perfluorobutanoic acid (PFBA) was considered as a marker for source analysis. Bean vegetables contribute highly to the overall PFAA load in vegetables. A significant correlation was shown between irrigation water and agricultural products. The EDI (estimated daily intake) from vegetables should be of concern in China. PMID:27973400

Spatial optimization of cropping pattern for sustainable food and biofuel production with minimal downstream pollution.

PubMed

Femeena, P V; Sudheer, K P; Cibin, R; Chaubey, I

2018-04-15

Biofuel has emerged as a substantial source of energy in many countries. In order to avoid the 'food versus fuel competition', arising from grain-based ethanol production, the United States has passed regulations that require second generation or cellulosic biofeedstocks to be used for majority of the biofuel production by 2022. Agricultural residue, such as corn stover, is currently the largest source of cellulosic feedstock. However, increased harvesting of crops residue may lead to increased application of fertilizers in order to recover the soil nutrients lost from the residue removal. Alternatively, introduction of less-fertilizer intensive perennial grasses such as switchgrass (Panicum virgatum L.) and Miscanthus (Miscanthus x giganteus Greef et Deu.) can be a viable source for biofuel production. Even though these grasses are shown to reduce nutrient loads to a great extent, high production cost have constrained their wide adoptability to be used as a viable feedstock. Nonetheless, there is an opportunity to optimize feedstock production to meet bioenergy demand while improving water quality. This study presents a multi-objective simulation optimization framework using Soil and Water Assessment Tool (SWAT) and Multi Algorithm Genetically Adaptive Method (AMALGAM) to develop optimal cropping pattern with minimum nutrient delivery and minimum biomass production cost. Computational time required for optimization was significantly reduced by loose coupling SWAT with an external in-stream solute transport model. Optimization was constrained by food security and biofuel production targets that ensured not more than 10% reduction in grain yield and at least 100 million gallons of ethanol production. A case study was carried out in St. Joseph River Watershed that covers 280,000 ha area in the Midwest U.S. Results of the study indicated that introduction of corn stover removal and perennial grass production reduce nitrate and total phosphorus loads without compromising on food and biofuel production. Optimization runs yielded an optimal cropping pattern with 32% of watershed area in stover removal, 15% in switchgrass and 2% in Miscanthus. The optimal scenario resulted in 14% reduction in nitrate and 22% reduction in total phosphorus from the baseline. This framework can be used as an effective tool to take decisions regarding environmentally and economically sustainable strategies to minimize the nutrient delivery at minimal biomass production cost, while simultaneously meeting food and biofuel production targets. Copyright © 2018 Elsevier Ltd. All rights reserved.

Conflict minerals from the Democratic Republic of the Congo—Gold supply chain

USGS Publications Warehouse

George, Micheal W.

2015-11-10

Processing of the 3T mineral concentrates requires substantial infrastructure and capital and generally is done at relatively few specialized facilities that are not located at the mine site; primary and secondary processors typically are at separate locations. Gold, however, can easily be processed into semi-refined products at or near the mine site and has a high unit value in any form, which allows it to be readily exported through undocumented channels, making it more difficult to track to the mine or region of origin. To put this in perspective, 30 kilograms (66 pounds) of 83 percent pure gold (20 carat) would form a cube measuring 12 centimeters per side (about the size of a small tissue box) and, at a price of $1,200 per ounce, would be worth nearly $1 million. By contrast, the equivalent value of tungsten concentrates would weigh about 45 metric tons (t) (100,000 pounds). Once conflict sourced gold has been combined with gold from other mines and scrap at a refiner, there is no feasible way to distinguish the source of the gold. Thus, once the gold leaves the immediate area of production, it is nearly indistinguishable from gold products mined in other areas.

Ion-induced nuclear radiotherapy

DOEpatents

Horn, K.M.; Doyle, B.L.

1996-08-20

Ion-induced Nuclear Radiotherapy (INRT) is a technique for conducting radiosurgery and radiotherapy with a very high degree of control over the spatial extent of the irradiated volume and the delivered dose. Based upon the concept that low energy, ion induced atomic and nuclear reactions can be used to produce highly energetic reaction products at the site of a tumor, the INRT technique is implemented through the use of a conduit-needle or tube which conducts a low energy ion beam to a position above or within the intended treatment area. At the end of the conduit-needle or tube is a specially fabricated target which, only when struck by the ion beam, acts as a source of energetic radiation products. The inherent limitations in the energy, and therefore range, of the resulting reaction products limits the spatial extent of irradiation to a pre-defined volume about the point of reaction. Furthermore, since no damage is done to tissue outside this irradiated volume, the delivered dose may be made arbitrarily large. INRT may be used both as a point-source of radiation at the site of a small tumor, or as a topical bath of radiation to broad areas of diseased tissue. 25 figs.

Ion-induced nuclear radiotherapy

DOEpatents

Horn, Kevin M.; Doyle, Barney L.

1996-01-01

Ion-induced Nuclear Radiotherapy (INRT) is a technique for conducting radiosurgery and radiotherapy with a very high degree of control over the spatial extent of the irradiated volume and the delivered dose. Based upon the concept that low energy, ion induced atomic and nuclear reactions can be used to produce highly energetic reaction products at the site of a tumor, the INRT technique is implemented through the use of a conduit-needle or tube which conducts a low energy ion beam to a position above or within the intended treatment area. At the end of the conduit-needle or tube is a specially fabricated target which, only when struck by the ion beam, acts as a source of energetic radiation products. The inherent limitations in the energy, and therefore range, of the resulting reaction products limits the spatial extent of irradiation to a pre-defined volume about the point of reaction. Furthermore, since no damage is done to tissue outside this irradiated volume, the delivered dose may be made arbitrarily large. INRT may be used both as a point-source of radiation at the site of a small tumor, or as a topical bath of radiation to broad areas of diseased tissue.

Pathway Ranking for In-place Sediment Management (CU1209). Executive Summary and Site 1 Report -- Paleta Creek

DTIC Science & Technology

2006-06-01

to any specific commercial product , process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or...conditions observed at P17 and Southeast Loch are interesting from the standpoint that these areas are generally closer to industrial and non-point...metals that commonly co-occur in both industrial sources and non-point source. An examination of all fluxes suggests that the surface mixed layer may

Vernonia galamensis, potential new crop source of epoxy acid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Perdue, R.E. Jr.; Carlson, K.D.; Gilbert, M.G.

Vernonia galamensis is a good source of seed oil rich in epoxy acid, which can be used to manufacture plastic formulations, protective coatings, and other products. Seed from a natural stand in Ethiopia contained 31% epoxy acid. Under cultivation in Kenya, this unimproved germ plasm produced a substantial yield of seed with 32% epoxy acid. This African species has good natural seed retention and is a promising new crop for semiarid tropical areas. 11 references.

Application of a water quality model in the White Cart water catchment, Glasgow, UK.

PubMed

Liu, S; Tucker, P; Mansell, M; Hursthouse, A

2003-03-01

Water quality models of urban systems have previously focused on point source (sewerage system) inputs. Little attention has been given to diffuse inputs and research into diffuse pollution has been largely confined to agriculture sources. This paper reports on new research that is aimed at integrating diffuse inputs into an urban water quality model. An integrated model is introduced that is made up of four modules: hydrology, contaminant point sources, nutrient cycling and leaching. The hydrology module, T&T consists of a TOPMODEL (a TOPography-based hydrological MODEL), which simulates runoff from pervious areas and a two-tank model, which simulates runoff from impervious urban areas. Linked into the two-tank model, the contaminant point source module simulates the overflow from the sewerage system in heavy rain. The widely known SOILN (SOIL Nitrate model) is the basis of nitrogen cycle module. Finally, the leaching module consists of two functions: the production function and the transfer function. The production function is based on SLIM (Solute Leaching Intermediate Model) while the transfer function is based on the 'flushing hypothesis' which postulates a relationship between contaminant concentrations in the receiving water course and the extent to which the catchment is saturated. This paper outlines the modelling methodology and the model structures that have been developed. An application of this model in the White Cart catchment (Glasgow) is also included.

Rockfall hazard assessment integrating probabilistic physically based rockfall source detection (Norddal municipality, Norway).

NASA Astrophysics Data System (ADS)

Yugsi Molina, F. X.; Oppikofer, T.; Fischer, L.; Hermanns, R. L.; Taurisano, A.

2012-04-01

Traditional techniques to assess rockfall hazard are partially based on probabilistic analysis. Stochastic methods has been used for run-out analysis of rock blocks to estimate the trajectories that a detached block will follow during its fall until it stops due to kinetic energy loss. However, the selection of rockfall source areas is usually defined either by multivariate analysis or by field observations. For either case, a physically based approach is not used for the source area detection. We present an example of rockfall hazard assessment that integrates a probabilistic rockfall run-out analysis with a stochastic assessment of the rockfall source areas using kinematic stability analysis in a GIS environment. The method has been tested for a steep more than 200 m high rock wall, located in the municipality of Norddal (Møre og Romsdal county, Norway), where a large number of people are either exposed to snow avalanches, rockfalls, or debris flows. The area was selected following the recently published hazard mapping plan of Norway. The cliff is formed by medium to coarse-grained quartz-dioritic to granitic gneisses of Proterozoic age. Scree deposits product of recent rockfall activity are found at the bottom of the rock wall. Large blocks can be found several tens of meters away from the cliff in Sylte, the main locality in the Norddal municipality. Structural characterization of the rock wall was done using terrestrial laser scanning (TLS) point clouds in the software Coltop3D (www.terranum.ch), and results were validated with field data. Orientation data sets from the structural characterization were analyzed separately to assess best-fit probability density functions (PDF) for both dip angle and dip direction angle of each discontinuity set. A GIS-based stochastic kinematic analysis was then carried out using the discontinuity set orientations and the friction angle as random variables. An airborne laser scanning digital elevation model (ALS-DEM) with 1 m resolution was used for the analysis. Three failure mechanisms were analyzed: planar and wedge sliding, as well as toppling. Based on this kinematic analysis, areas where failure is feasible were used as source areas for run out analysis using Rockyfor3D v. 4.1 (www.ecorisq.org). The software calculates trajectories of single falling blocks in three dimensions using physically based algorithms developed under a stochastic approach. The ALS-DEM was down-scaled to 5 m resolution to optimize processing time. Results were compared with run-out simulations using Rockyfor3D with the whole rock wall as source area, and with maps of deposits generated from field observations and aerial photo interpretation. The results product of our implementation show a better correlation with field observations, and help to produce more accurate rock fall hazard assessment maps by a better definition of the source areas. It reduces the time processing for the analysis as well. The findings presented in this contribution are part of an effort to produce guidelines for natural hazard mapping in Norway. Guidelines will be used in upcoming years for hazard mapping in areas where larger groups of population are exposed to mass movements from steep slopes.

Area Handbook Series: Saudi Arabia. A Country Study.

DTIC Science & Technology

1992-12-01

diet, domestic production constituted less than half of total demand Egg production also increased rapidly during the 1980s. The numbers of broiler ...Michael Field’s The Merchants. For ongoing coverage of the kingdom’s economy, three sources are recom- mended. Middle East Economic Digest , Middle East...Middle East Economic Digest , up to 200 prisoners might share a single room. Basic food was provided, usually eaten by hand from the floor, although

Report list Arizona's oil, gas potential

USGS Publications Warehouse

Rauzi, S.L.

2001-01-01

This article is a summary of Arizona geological survey circular 29, which addresses the petroleum geology of Arizona, USA. Eight areas have been identified with fair to excellent oil and gas potential, and some Tertiary basins have evidence of source or reservoir rocks. The following are considered here: production history, lands status and services, regulation and permitting, petroleum geology, hydrocarbon indications, and areas with hydrocarbon potential and their petroleum geology and characteristics. The full report contains detailed figures of each of these basin areas, a descriptive tabulation of seeps and petroliferous rocks and extensive references.

Atmospheric toxic metals emission inventory and spatial characteristics from anthropogenic sources of Guangdong province, China

NASA Astrophysics Data System (ADS)

Cher, S.; Menghua, L.; Xiao, X.; Yuqi, W.; Zhuangmin, Z.; Zhijiong, H.; Cheng, L.; Guanglin, J.; Zibing, Y.; Junyu, Z.

2017-12-01

Atmospheric toxic metals (TMs) are part of particulate matters, and may create adverse effects on the environment and human health depending upon their bioavailability and toxicity. Localized emission inventory is fundamental for parsing of toxic metals to identify key sources in order to formulate efficient toxic metals control strategies. With the use of the latest municipal level environment statistical data, this study developed a bottom-up emission inventory of five toxic metals (Hg, As, Pb, Cd, Cr) from anthropogenic activities in Guangdong province for the year of 2014. Major atmospheric toxic metals sources including combustion sources (coal, oil, biomass, municipal solid waste) and industrial process sources (cement production, nonferrous metal smelting, iron and steel industry, battery and fluorescent lamp production) were investigated. Results showed that: (1) The total emissions of Hg, As, Pb, Cd, Cr in Guangdong province were 18.14, 32.59, 411.34, 13.13, 84.16 t, respectively. (2) Different pollutants have obvious characteristics of emission sources. For total Hg emission, 46% comes from combustion sources, of which 32% from coal combustion and 8% from MSW combustion. Other 54% comes from industrial processes, which dominated by the cement (19%), fluorescent lamp (18%) and battery production (13%). Of the total Hg emission, 69% is released as Hg0 , 29% as Hg2+ , and only 2% as Hgp due to strict particulate matters controls policies. For As emissions, coal combustion, nonferrous metal smelting and iron and steel industry contributed approximate 48%, 25% and 24%, respectively. Pb emissions primarily come from battery production (42%), iron and steel industry (21%) and on-road mobile gasoline combustion (17%). Cd and Cr emissions were dominated by nonferrous metal smelting (71%) and iron and steel industry (82%), respectively. (3) In term of the spatial distribution, emissions of atmospheric toxic metals are mainly concentrated in the central region of the Pearl River Delta, such as, Guangzhou, Dongguan, and Foshan et.al. These areas were characterized with large amounts of coal combustion, battery production and fluorescent production. With the implementation of ultra-low emission standards in coal-fired power plant, TMs emissions from industrial process sources should be emphasized.

A failure diagnosis and impact assessment prototype for Space Station Freedom

NASA Technical Reports Server (NTRS)

Baker, Carolyn G.; Marsh, Christopher A.

1991-01-01

NASA is investigating the use of advanced automation to enhance crew productivity for Space Station Freedom in numerous areas, one being failure management. A prototype is described that diagnoses failure sources and assesses the future impacts of those failures on other Freedom entities.

40 CFR 412.10 - Applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... CONCENTRATED ANIMAL FEEDING OPERATIONS (CAFO) POINT SOURCE CATEGORY Horses and Sheep § 412.10 Applicability. This subpart applies to discharges resulting from the production areas at horse and sheep CAFOs. This subpart does not apply to such CAFOs with less than the following capacities: 10,000 sheep or 500 horses. ...

36 CFR 223.190 - Sourcing area application procedures.

Code of Federal Regulations, 2011 CFR

2011-07-01

... AGRICULTURE SALE AND DISPOSAL OF NATIONAL FOREST SYSTEM TIMBER, SPECIAL FOREST PRODUCTS, AND FOREST BOTANICAL... its implementing regulations. I certify that I have not exported unprocessed timber originating from..., et seq.) its implementing regulations, and the False Statements Act (18 U.S.C. 1001), and may subject...

40 CFR 412.2 - General definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... also cites the approved methods of analysis. (d) Process wastewater means water directly or indirectly... facilities; direct contact swimming, washing, or spray cooling of animals; or dust control. Process... process wastewater from the production area is or may be applied. (f) New source is defined at 40 CFR 122...

40 CFR 412.2 - General definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... also cites the approved methods of analysis. (d) Process wastewater means water directly or indirectly... facilities; direct contact swimming, washing, or spray cooling of animals; or dust control. Process... process wastewater from the production area is or may be applied. (f) New source is defined at 40 CFR 122...

40 CFR 412.2 - General definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... also cites the approved methods of analysis. (d) Process wastewater means water directly or indirectly... facilities; direct contact swimming, washing, or spray cooling of animals; or dust control. Process... process wastewater from the production area is or may be applied. (f) New source is defined at 40 CFR 122...

40 CFR 412.46 - New source performance standards (NSPS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... production areas. There must be no discharge of manure, litter, or process wastewater pollutants into waters... practice effluent limitations designed to ensure no discharge of manure, litter, or process wastewater... such effluent limitations, “no discharge of manure, litter, or process wastewater pollutants,” as used...

40 CFR 63.11405 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 14 2010-07-01 2010-07-01 false What definitions apply to this subpart? 63.11405 Section 63.11405 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Carbon Black Production Area Sources...

A multi-tracer approach to assess fingerprints of nitrate in an aquifer under agriculturally used land

NASA Astrophysics Data System (ADS)

Pasten-Zapata, Ernesto; Ledesma-Ruiz, Rogelio; Ramirez, Aldo; Harter, Thomas; Mahlknecht, Jürgen

2014-05-01

To effectively manage groundwater quality it is essential to understand sources of contamination and underground processes. The objective of the study was to identify sources and fate of nitrate pollution occurring in an aquifer underneath a sub-humid to humid region in NE Mexico which provides 10% of national citrus production. Nitrate isotopes and halide ratios were applied to understand nitrate sources and transformations in relation to land use/land cover. It was found that the study area is subject to diverse nitrate sources including organic waste and wastewater, synthetic fertilizers and soil processes. Animal manure and sewage from septic tanks were the causes of groundwater nitrate pollution within orchards and vegetable agriculture. Dairy activities within a radius of 1,000m from a sampling point increased nitrate pollution. Leachates from septic tanks incited nitrate pollution in residential areas. Soil nitrogen and animal waste were the sources of nitrate in groundwater under shrubland and grassland. Partial denitrification processes were evidenced. The denitrification process helped to attenuate nitrate concentration in the agricultural lands and grassland particularly during summer months.

Steady state deformation of the Coso Range, east central California, inferred from satellite radar interferometry

USGS Publications Warehouse

Wicks, C.W.; Thatcher, W.; Monastero, F.C.; Hasting, M.A.

2001-01-01

Observations of deformation from 1992 to 1997 in the southern Coso Range using satellite radar interferometry show deformation rates of up to 35 mm yr-1 in an area ???10 km by 15 km. The deformation is most likely the result of subsidence in an area around the Coso geothermal field. The deformation signal has a short-wavelength component, related to production in the field, and a long-wavelength component, deforming at a constant rate, that may represent a source of deformation deeper than the geothermal reservoir. We have modeled the long-wavelength component of deformation and inferred a deformation source at ???4 km depth. The source depth is near the brittle-ductile transition depth (inferred from seismicity) and ???1.5 km above the top of the rhyolite magma body that was a source for the most recent volcanic eruption in the Coso volcanic field [Manley and Bacon, 2000]. From this evidence and results of other studies in the Coso Range, we interpret the source to be a leaking deep reservoir of magmatic fluids derived from a crystallizing rhyolite magma body.

Pollution of water sources and removal of pollutants by advanced drinking-water treatment in China.

PubMed

Wang, L; Wang, B

2000-01-01

The pollution of water resources and drinking water sources in China is described in this paper with basic data. About 90% of surface waters and over 60% of drinking water sources in urban areas have been polluted to different extents. The main pollutants present in drinking water sources are organic substances, ammonia nitrogen, phenols, pesticides and pathogenic micro-organisms, some of which cannot be removed effectively by the traditional water treatment processes like coagulation, sedimentation, filtration and chlorination, and the product water usually does not meet Chinese national drinking water standards, when polluted source water is treated. In some drinking-water plants in China, advanced treatment processes including activated carbon filtration and adsorption, ozonation, biological activated carbon and membrane separation have been employed for further treatment of the filtrate from a traditional treatment system producing unqualified drinking water, to make final product water meet the WHO guidelines and some developed countries' standards, as well as the Chinese national standards for drinking water. Some case studies of advanced water treatment plants are described in this paper as well.

Current and new developments in transport and regulatory issues concerning radioisotopes: managing change for minimum business impact

NASA Astrophysics Data System (ADS)

Bennett, Neil; Coppell, David; Rogers, David; Schrader, John

2004-09-01

Changes in the regulatory framework governing the Radiation Processing Industry have the potential to make a real business impact on day-to-day profitability. Many areas of the Radiation Processing Industry are affected by changes in the regulatory framework within which these areas are managed. When planning for such changes the transportation element in the shipment of sealed cobalt radiation sources is an area that is often neglected by some parts of the distribution chain. A balance must be struck between the cobalt supplier and the facility operator/customer that rests upon how much the customer needs to know about the intricacies of cobalt shipment. The objective of this paper is to highlight areas of possible business impact and reassure the users of sealed radiation sources that the global suppliers of these products are used to negotiating local variations in regulations governing the physical transportation of radiation sources, changes in regulations governing the design, manufacture and use of transportation containers and changes in the availability of commercial shippers and shipping routes. The major suppliers of industrial quantities of cobalt-60 are well placed to lead their customers through this complex process as a matter of routine.

Isotopic Discrimination of Perchlorate Sources in Ground Water

NASA Astrophysics Data System (ADS)

Bohlke, J.; Hatzinger, P. B.; Sturchio, N. C.; Gu, B.; Jackson, W. A.; Abbene, I. J.

2007-12-01

Perchlorate has been detected in ground water and drinking water in many areas of the U.S. during the past decade. Sources of potential perchlorate enrichment in ground water include releases from past military activities, fireworks manufacture and display, fertilizer applications, discarded road flares, and local atmospheric deposition. Here we present analyses of stable isotopes (δ37Cl, δ18O, and Δ17O) of dissolved perchlorate, along with other supporting environmental tracer data, from selected occurrences in ground water in the U.S. The isotope data indicate that both synthetic and natural perchlorate are present in ground water, and that multiple sources are present locally in some areas. The sampled ground waters generally were oxic and the perchlorate isotopes generally were not affected substantially by biodegradation. In some areas, natural perchlorate, with Δ17O = +7 to +10 ‰, can be attributed to agricultural applications of atmospherically derived natural nitrate fertilizer imported from South America (Atacama Desert, Chile). In at least one agricultural area in New York, concentrations of perchlorate increase with depth and ground-water age, possibly because of decreasing application rates of Atacama nitrate fertilizer and(or) decreasing perchlorate concentrations in the imported fertilizer products in recent years.

Anthropogenic Methane Emissions in California's San Joaquin Valley: Characterizing Large Point Source Emitters

NASA Astrophysics Data System (ADS)

Hopkins, F. M.; Duren, R. M.; Miller, C. E.; Aubrey, A. D.; Falk, M.; Holland, L.; Hook, S. J.; Hulley, G. C.; Johnson, W. R.; Kuai, L.; Kuwayama, T.; Lin, J. C.; Thorpe, A. K.; Worden, J. R.; Lauvaux, T.; Jeong, S.; Fischer, M. L.

2015-12-01

Methane is an important atmospheric pollutant that contributes to global warming and tropospheric ozone production. Methane mitigation could reduce near term climate change and improve air quality, but is hindered by a lack of knowledge of anthropogenic methane sources. Recent work has shown that methane emissions are not evenly distributed in space, or across emission sources, suggesting that a large fraction of anthropogenic methane comes from a few "super-emitters." We studied the distribution of super-emitters in California's southern San Joaquin Valley, where elevated levels of atmospheric CH4 have also been observed from space. Here, we define super-emitters as methane plumes that could be reliably detected (i.e., plume observed more than once in the same location) under varying wind conditions by airborne thermal infrared remote sensing. The detection limit for this technique was determined to be 4.5 kg CH4 h-1 by a controlled release experiment, corresponding to column methane enhancement at the point of emissions greater than 20% above local background levels. We surveyed a major oil production field, and an area with a high concentration of large dairies using a variety of airborne and ground-based measurements. Repeated airborne surveys (n=4) with the Hyperspectral Thermal Emission Spectrometer revealed 28 persistent methane plumes emanating from oil field infrastructure, including tanks, wells, and processing facilities. The likelihood that a given source type was a super-emitter varied from roughly 1/3 for processing facilities to 1/3000 for oil wells. 11 persistent plumes were detected in the dairy area, and all were associated with wet manure management. The majority (11/14) of manure lagoons in the study area were super-emitters. Comparing to a California methane emissions inventory for the surveyed areas, we estimate that super-emitters comprise a minimum of 9% of inventoried dairy emissions, and 13% of inventoried oil emissions in this region.

Sources of Safety Data and Statistical Strategies for Design and Analysis: Transforming Data Into Evidence.

PubMed

Ma, Haijun; Russek-Cohen, Estelle; Izem, Rima; Marchenko, Olga V; Jiang, Qi

2018-03-01

Safety evaluation is a key aspect of medical product development. It is a continual and iterative process requiring thorough thinking, and dedicated time and resources. In this article, we discuss how safety data are transformed into evidence to establish and refine the safety profile of a medical product, and how the focus of safety evaluation, data sources, and statistical methods change throughout a medical product's life cycle. Some challenges and statistical strategies for medical product safety evaluation are discussed. Examples of safety issues identified in different periods, that is, premarketing and postmarketing, are discussed to illustrate how different sources are used in the safety signal identification and the iterative process of safety assessment. The examples highlighted range from commonly used pediatric vaccine given to healthy children to medical products primarily used to treat a medical condition in adults. These case studies illustrate that different products may require different approaches, and once a signal is discovered, it could impact future safety assessments. Many challenges still remain in this area despite advances in methodologies, infrastructure, public awareness, international harmonization, and regulatory enforcement. Innovations in safety assessment methodologies are pressing in order to make the medical product development process more efficient and effective, and the assessment of medical product marketing approval more streamlined and structured. Health care payers, providers, and patients may have different perspectives when weighing in on clinical, financial and personal needs when therapies are being evaluated.

Historic emissions from deforestation and forest degradation in Mato Grosso, Brazil: 1) source data uncertainties

PubMed Central

2011-01-01

Background Historic carbon emissions are an important foundation for proposed efforts to Reduce Emissions from Deforestation and forest Degradation and enhance forest carbon stocks through conservation and sustainable forest management (REDD+). The level of uncertainty in historic carbon emissions estimates is also critical for REDD+, since high uncertainties could limit climate benefits from credited mitigation actions. Here, we analyzed source data uncertainties based on the range of available deforestation, forest degradation, and forest carbon stock estimates for the Brazilian state of Mato Grosso during 1990-2008. Results Deforestation estimates showed good agreement for multi-year periods of increasing and decreasing deforestation during the study period. However, annual deforestation rates differed by > 20% in more than half of the years between 1997-2008, even for products based on similar input data. Tier 2 estimates of average forest carbon stocks varied between 99-192 Mg C ha-1, with greatest differences in northwest Mato Grosso. Carbon stocks in deforested areas increased over the study period, yet this increasing trend in deforested biomass was smaller than the difference among carbon stock datasets for these areas. Conclusions Estimates of source data uncertainties are essential for REDD+. Patterns of spatial and temporal disagreement among available data products provide a roadmap for future efforts to reduce source data uncertainties for estimates of historic forest carbon emissions. Specifically, regions with large discrepancies in available estimates of both deforestation and forest carbon stocks are priority areas for evaluating and improving existing estimates. Full carbon accounting for REDD+ will also require filling data gaps, including forest degradation and secondary forest, with annual data on all forest transitions. PMID:22208947

Crop Surveillance Demonstration Using a Near-Daily MODIS Derived Vegetation Index Time Series

NASA Technical Reports Server (NTRS)

McKellip, Rodney; Ryan, Robert E.; Blonski, Slawomir; Prados, Don

2005-01-01

Effective response to crop disease outbreaks requires rapid identification and diagnosis of an event. A near-daily vegetation index product, such as a Normalized Difference Vegetation Index (NDVI), at moderate spatial resolution may serve as a good method for monitoring quick-acting diseases. NASA s Moderate Resolution Imaging Spectroradiometer (MODIS) instrument flown on the Terra and Aqua satellites has the temporal, spatial, and spectral properties to make it an excellent coarse-resolution data source for rapid, comprehensive surveillance of agricultural areas. A proof-of-concept wide area crop surveillance system using daily MODIS imagery was developed and tested on a set of San Joaquin cotton fields over a growing season. This area was chosen in part because excellent ground truth data were readily available. Preliminary results indicate that, at least in the southwestern part of the United States, near-daily NDVI products can be generated that show the natural variations in the crops as well as specific crop practices. Various filtering methods were evaluated and compared with standard MOD13 NDVI MODIS products. We observed that specific chemical applications that produce defoliation, which would have been missed using the standard 16-day product, were easily detectable with the filtered daily NDVI products.

Shear velocity of the Rotokawa geothermal field using ambient noise

NASA Astrophysics Data System (ADS)

Civilini, F.; Savage, M. K.; Townend, J.

2014-12-01

Ambient noise correlation is an increasingly popular seismological technique that uses the ambient seismic noise recorded at two stations to construct an empirical Green's function. Applications of this technique include determining shear velocity structure and attenuation. An advantage of ambient noise is that it does not rely on external sources of seismic energy such as local or teleseismic earthquakes. This method has been used in the geothermal industry to determine the depths at which magmatic processes occur, to distinguish between production and non-production areas, and to observe seismic velocity perturbations associated with fluid extraction. We will present a velocity model for the Rotokawa geothermal field near Taupo, New Zealand, produced from ambient noise cross correlations. Production at Rotokawa is based on the "Rotokawa A" combined cycle power station established in 1997 and the "Nga Awa Purua" triple flash power plant established in 2010. Rotokawa Joint Venture, a partnership between Mighty River Power and Tauhara North No. 2 Trust currently operates 174 MW of generation at Rotokawa. An array of short period seismometers was installed in 2008 and occupies an area of roughly 5 square kilometers around the site. Although both cultural and natural noise sources are recorded at the stations, the instrument separation distance provides a unique challenge for analyzing cross correlations produced by both signal types. The inter-station spacing is on the order of a few kilometers, so waves from cultural sources generally are not coherent from one station to the other, while the wavelength produced by natural noise is greater than the station separation. Velocity models produced from these two source types will be compared to known geological models of the site. Depending on the amount of data needed to adequately construct cross-correlations, a time-dependent model of velocity will be established and compared with geothermal production processes.

Source identification and trends in concentrations of gaseous and fine particulate principal species in Seoul, South Korea.

PubMed

Kang, Choong-Min; Kang, Byung-Wook; Lee, Hak Sung

2006-07-01

Ambient measurements were made using two sets of annular denuder system during the four seasons (April 2001 to February 2002) and were then compared with the results during the period of 1996-1997 to estimate the trends and seasonal variations in concentrations of gaseous and fine particulate matter (PM2.5) principal species. Annual averages of gaseous HNO3 and NH3 increased by 11% and 6%, respectively, compared with those of the previous study, whereas HONO and SO2 decreased by 11% and 136%, respectively. The PM2.5 concentration decreased by -17%, 35% for SO4(2-), and 29% for NH4+, whereas NO3- increased by 21%. Organic carbon (OC) and elemental carbon (EC) were 12.8 and 5.98 microg/m(-3), accounting for -26 and 12% of PM2.5 concentration, respectively. The species studied accounted for 84% of PM2.5 concentration, ranging from 76% in winter to 97% in summer. Potential source contribution function (PSCF) analysis was used to identify possible source areas affecting air pollution levels at a receptor site in Seoul. High possible source areas in concentrations of PM2.5, NO3-, SO4(2-), NH4+, and K+ were coastal cities of Liaoning province (possibly emissions from oil-fired boilers on ocean liners and fishing vessels and industrial emissions), inland areas of Heibei/Shandong provinces (the highest density areas of agricultural production and population) in China, and typical port cities (Mokpo, Yeosu, and Busan) of South Korea. In the PSCF map for OC, high possible source areas were also coastal cities of Liaoning province and inland areas of Heibei/Shandong provinces in China. In contrast, high possible source areas of EC were highlighted in the south of the Yellow Sea, indicating possible emissions from oil-fired boilers on large ships between South Korea and Southeast Asia. In summary, the PSCF results may suggest that air pollution levels in Seoul are affected considerably by long-range transport from external areas, such as the coastal zone in China and other cities in South Korea, as well as Seoul itself.

Antarctic new particle formation from continental biogenic precursors

NASA Astrophysics Data System (ADS)

Kyrö, E.-M.; Kerminen, V.-M.; Virkkula, A.; Dal Maso, M.; Parshintsev, J.; Ruíz-Jimenez, J.; Forsström, L.; Manninen, H. E.; Riekkola, M.-L.; Heinonen, P.; Kulmala, M.

2012-12-01

Over Antarctica, aerosol particles originate almost entirely from marine areas, with minor contribution from long-range transported dust or anthropogenic material. The Antarctic continent itself, unlike all other continental areas, has been thought to be practically free of aerosol sources. Here we present evidence of local aerosol production associated with melt-water ponds in the continental Antarctica. We show that in air masses passing such ponds, new aerosol particles are efficiently formed and these particles grow up to sizes where they may act as cloud condensation nuclei (CCN). The precursor vapours responsible for aerosol formation and growth originate very likely from highly abundant cyanobacteria Nostoc commune (Vaucher) communities of local ponds. This is the first time when freshwater vegetation has been identified as an aerosol precursor source. The influence of the new source on clouds and climate may increase in future Antarctica, and possibly elsewhere undergoing accelerating summer melting of semi-permanent snow cover.

Antarctic new particle formation from continental biogenic precursors

NASA Astrophysics Data System (ADS)

Kyrö, E.-M.; Kerminen, V.-M.; Virkkula, A.; Dal Maso, M.; Parshintsev, J.; Ruíz-Jimenez, J.; Forsström, L.; Manninen, H. E.; Riekkola, M.-L.; Heinonen, P.; Kulmala, M.

2013-04-01

Over Antarctica, aerosol particles originate almost entirely from marine areas, with minor contribution from long-range transported dust or anthropogenic material. The Antarctic continent itself, unlike all other continental areas, has been thought to be practically free of aerosol sources. Here we present evidence of local aerosol production associated with melt-water ponds in continental Antarctica. We show that in air masses passing such ponds, new aerosol particles are efficiently formed and these particles grow up to sizes where they may act as cloud condensation nuclei (CCN). The precursor vapours responsible for aerosol formation and growth originate very likely from highly abundant cyanobacteria Nostoc commune (Vaucher) communities of local ponds. This is the first time freshwater vegetation has been identified as an aerosol precursor source. The influence of the new source on clouds and climate may increase in future Antarctica, and possibly elsewhere undergoing accelerating summer melting of semi-permanent snow cover.

Validation of the USGS Landsat Burned Area Essential Climate Variable (BAECV) across the conterminous United States

USGS Publications Warehouse

Vanderhoof, Melanie; Fairaux, Nicole; Beal, Yen-Ju G.; Hawbaker, Todd J.

2017-01-01

The Landsat Burned Area Essential Climate Variable (BAECV), developed by the U.S. Geological Survey (USGS), capitalizes on the long temporal availability of Landsat imagery to identify burned areas across the conterminous United States (CONUS) (1984–2015). Adequate validation of such products is critical for their proper usage and interpretation. Validation of coarse-resolution products often relies on independent data derived from moderate-resolution sensors (e.g., Landsat). Validation of Landsat products, in turn, is challenging because there is no corresponding source of high-resolution, multispectral imagery that has been systematically collected in space and time over the entire temporal extent of the Landsat archive. Because of this, comparison between high-resolution images and Landsat science products can help increase user's confidence in the Landsat science products, but may not, alone, be adequate. In this paper, we demonstrate an approach to systematically validate the Landsat-derived BAECV product. Burned area extent was mapped for Landsat image pairs using a manually trained semi-automated algorithm that was manually edited across 28 path/rows and five different years (1988, 1993, 1998, 2003, 2008). Three datasets were independently developed by three analysts and the datasets were integrated on a pixel by pixel basis in which at least one to all three analysts were required to agree a pixel was burned. We found that errors within our Landsat reference dataset could be minimized by using the rendition of the dataset in which pixels were mapped as burned if at least two of the three analysts agreed. BAECV errors of omission and commission for the detection of burned pixels averaged 42% and 33%, respectively for CONUS across all five validation years. Errors of omission and commission were lowest across the western CONUS, for example in the shrub and scrublands of the Arid West (31% and 24%, respectively), and highest in the grasslands and agricultural lands of the Great Plains in central CONUS (62% and 57%, respectively). The BAECV product detected most (> 65%) fire events > 10 ha across the western CONUS (Arid and Mountain West ecoregions). Our approach and results demonstrate that a thorough validation of Landsat science products can be completed with independent Landsat-derived reference data, but could be strengthened by the use of complementary sources of high-resolution data.

Geochemical characterization of critical dust source regions in the American West

NASA Astrophysics Data System (ADS)

Aarons, Sarah M.; Blakowski, Molly A.; Aciego, Sarah M.; Stevenson, Emily I.; Sims, Kenneth W. W.; Scott, Sean R.; Aarons, Charles

2017-10-01

The generation, transport, and deposition of mineral dust are detectable in paleoclimate records from land, ocean, and ice, providing valuable insight into earth surface conditions and cycles on a range of timescales. Dust deposited in marine and terrestrial ecosystems can provide critical nutrients to nutrient-limited ecosystems, and variations in dust provenance can indicate changes in dust production, sources and transport pathways as a function of climate variability and land use change. Thus, temporal changes in locations of dust source areas and transport pathways have implications for understanding interactions between mineral dust, global climate, and biogeochemical cycles. This work characterizes dust from areas in the American West known for dust events and/or affected by increasing human settlement and livestock grazing during the last 150 years. Dust generation and uplift from these dust source areas depends on climate and land use practices, and the relative contribution of dust has likely changed since the expansion of industrialization and agriculture into the western United States. We present elemental and isotopic analysis of 28 potential dust source area samples analyzed using Thermal Ionization Mass Spectrometry (TIMS) for 87Sr/86Sr and 143Nd/144Nd composition and Multi-Collector Inductively Coupled Plasma Mass Spectrometer (MC-ICPMS) for 176Hf/177Hf composition, and ICPMS for major and trace element concentrations. We find significant variability in the Sr, Nd, and Hf isotope compositions of potential source areas of dust throughout western North America, ranging from 87Sr/86Sr = 0.703699 to 0.740236, εNd = -26.6 to 2.4, and εHf = -21.7 to -0.1. We also report differences in the trace metal and phosphorus concentrations in the geologic provinces sampled. This research provides an important resource for the geochemical tracing of dust sources and sinks in western North America, and will aid in modeling the biogeochemical impacts of increased dust generation and deposition caused by higher drought frequency and human activity.

Know Your Enemy - Implementation of Bioremediation within a Suspected DNAPL Source Zone Following High-Resolution Site Characterization at Contractors Road Heavy Equipment Area, Kennedy Space Center, Florida

NASA Technical Reports Server (NTRS)

Chrest, Anne; Daprato, Rebecca; Burcham, Michael; Johnson, Jill

2018-01-01

The National Aeronautics and Space Administration (NASA), Kennedy Space Center (KSC), has adopted high-resolution site characterization (HRSC) sampling techniques during baseline sampling prior to implementation of remedies to confirm and refine the conceptual site model (CSM). HRSC sampling was performed at Contractors Road Heavy Equipment Area (CRHE) prior to bioremediation implementation to verify the extent of the trichloroethene (TCE) dense non-aqueous phase liquid (DNAPL) source area (defined as the area with TCE concentrations above 1% solubility) and its daughter product dissolved plume that had been identified during previous HRSC events. The results of HRSC pre-bioremediation implementation sampling suggested that the TCE source area was larger than originally identified during initial site characterization activities, leading to a design refinement to improve electron donor distribution and increase the likelihood of achieving remedial objectives. Approach/Activities: HRSC was conducted from 2009 through 2014 to delineate the vertical and horizontal extent of chlorinated volatile organic compounds (CVOCs) in the groundwater. Approximately 2,340 samples were collected from 363 locations using direct push technology (DPT) groundwater sampling techniques. Samples were collected from up to 14 depth intervals at each location using a 4-foot sampling screen. This HRSC approach identified a narrow (approx. 5 to 30 feet wide), approximately 3,000 square foot TCE DNAPL source area (maximum detected TCE concentration of 160,000 micrograms per liter [micro-g/L] at DPT sampling location DPT0225). Prior to implementation of a bioremediation interim measure, HRSC baseline sampling was conducted using DPT groundwater sampling techniques. Concentrations of TCE were an order of magnitude lower than previous reported (12,000 micro-g/L maximum at DPT sampling location DPT0225) at locations sampled adjacent to previous sampling locations. To further evaluate the variability in concentrations observed additional sampling was conducted in 2016. The results identified higher concentrations than originally detected within the previously defined source area and the presence of source zone concentrations upgradient of the previously defined source area (maximum concentration observed 570,000 micro-g/L). The HRSC baseline sampling data allowed for a revision of the bioremediation design prior to implementation. Bioremediation was implemented within the eastern portion of the source area in November and December 2016 and quarterly performance monitoring was completed in March and June 2017. Reductions in CVOC concentrations from baseline were observed at all performance monitoring wells in the treatment area, and by June 2017, an approximate 95% CVOC mass reduction was observed based on monitoring well sampling results. Results/Lessons Learned: The results of this project suggest that, due to the complexity of DNAPL source zones, HRSC during pre-implementation baseline sampling in the TCE source zone was an essential strategy for verifying the treatment area and depth prior to remedy implementation. If the upgradient source zone mass was not identified prior to bioremediation implementation, the mass would have served as a long-term source for the dissolved plume.

Hyperspectral retinal imaging with a spectrally tunable light source

NASA Astrophysics Data System (ADS)

Francis, Robert P.; Zuzak, Karel J.; Ufret-Vincenty, Rafael

2011-03-01

Hyperspectral retinal imaging can measure oxygenation and identify areas of ischemia in human patients, but the devices used by current researchers are inflexible in spatial and spectral resolution. We have developed a flexible research prototype consisting of a DLP®-based spectrally tunable light source coupled to a fundus camera to quickly explore the effects of spatial resolution, spectral resolution, and spectral range on hyperspectral imaging of the retina. The goal of this prototype is to (1) identify spectral and spatial regions of interest for early diagnosis of diseases such as glaucoma, age-related macular degeneration (AMD), and diabetic retinopathy (DR); and (2) define required specifications for commercial products. In this paper, we describe the challenges and advantages of using a spectrally tunable light source for hyperspectral retinal imaging, present clinical results of initial imaging sessions, and describe how this research can be leveraged into specifying a commercial product.

Atmospheric Pressure Chemical Ionization Sources Used in The Detection of Explosives by Ion Mobility Spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Waltman, Melanie J.

2010-05-01

Explosives detection is a necessary and wide spread field of research. From large shipping containers to airline luggage, numerous items are tested for explosives every day. In the area of trace explosives detection, ion mobility spectrometry (IMS) is the technique employed most often because it is a quick, simple, and accurate way to test many items in a short amount of time. Detection by IMS is based on the difference in drift times of product ions through the drift region of an IMS instrument. The product ions are created when the explosive compounds, introduced to the instrument, are chemically ionizedmore » through interactions with the reactant ions. The identity of the reactant ions determines the outcomes of the ionization process. This research investigated the reactant ions created by various ionization sources and looked into ways to manipulate the chemistry occurring in the sources.« less

Regulation of nitrogen uptake and assimilation: Effects of nitrogen source, root-zone pH, and aerial CO2 concentration on growth and productivity of soybeans

NASA Technical Reports Server (NTRS)

Raper, C. D.; Tolley-Henry, L.

1989-01-01

An important feature of controlled-environment crop production systems such as those to be used for life support of crews during space exploration is the efficient utilization of nitrogen supplies. Making decisions about the best sources of these supplies requires research into the relationship between nitrogen source and the physiological processes which regulate vegetative and reproductive plant growth. Work done in four areas within this research objective is reported: (1) experiments on the effects of root-zone pH on preferential utilization of NO3(-) versus NH4(+) nitrogen; (2) investigation of processes at the whole-plant level that regulate nitrogen uptake; (3) studies of the effects of atmospheric CO2 and NO3(-) supply on the growth of soybeans; and (4) examination of the role of NO3(-) uptake in enhancement of root respiration.

Evaluating scholarship productivity in COAMFTE-accredited PhD programs.

PubMed

Jared DuPree, W; White, Mark B; Meredith, William H; Ruddick, Lindsay; Anderson, Michael P

2009-04-01

Due to an increasing trend among states to cut higher education funds, many universities are relying more on private donations and federal funding to keep programs afloat. Scholarship productivity in general has become an integral factor in terms of universities granting tenure to faculty, allocating resources, and supporting program goals due to the fact that more research in a particular area tends to increase the likelihood that one will obtain funding from federal, state, and private sources. In the past, ranking systems have also been used to evaluate programs. However, most ranking systems use methodologies that do not quantify research productivity or evaluate factors that match current university trends. The purpose of this article is to explore current scholarship productivity trends among COAMFTE-accredited doctoral programs through the use of several evaluation methods. Specifically, productivity was examined in regard to the following areas: (a) family therapy journal publications; (b) family science journal publications; (c) historic journal publication trends; and (d) recent journal publication trends.

Superfund Record of Decision (EPA Region 4): Sodyeco Site, Charlotte, North Carolina (first remedial action), September 1987. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1987-09-24

The Southern Dyestuff Company (Sodyeco) site, located in Mecklenburg County, North Carolina, consists of approximately 1,300 acres. Approximately 20-30 residents reside within a one-quarter mile radius of the site, while many of the areas 9,137 residents commute daily to the site for employment. The site contains an operating manufacturing facility consisting of production units, a waste-water-treatment area and materials storage areas. Approximately 1040 acres are underdeveloped. Sodyeco began operations at the site in 1936. In 1958, American Marietta (which became Martin Marietta in 1961) purchased the site and expanded the company's liquid sulfur dye production to include the manufacture ofmore » vat and disperse dyes and specialty products for agrochemical, electronic, explosive, lithographic, pigment, plastic, rubber and general chemical industries. The Sandoz Chemical Company purchased the plant in 1983. Five CERCLA facilities, identified as A, B, C, D and E, were identified as probable sources of the ground water and soil contamination.« less

Fabrication of selective-area growth InGaN LED by mixed-source hydride vapor-phase epitaxy

NASA Astrophysics Data System (ADS)

Bae, Sung Geun; Jeon, Injun; Jeon, Hunsoo; Kim, Kyoung Hwa; Yang, Min; Yi, Sam Nyung; Lee, Jae Hak; Ahn, Hyung Soo; Yu, Young Moon; Sawaki, Nobuhiko; Kim, Suck-Whan

2018-01-01

We prepared InGaN light-emitting diodes (LEDs) with the active layers grown from a mixed source of Ga-In-N materials on an n-type GaN substrate by a selective-area growth method and three fabrication steps: photolithography, epitaxial layer growth, and metallization. The preparation followed a previously developed experimental process using apparatus for mixed-source hydride vapor-phase epitaxy (HVPE), which consisted of a multi-graphite boat, for insulating against the high temperature and to control the growth rate of epilayers, filled with the mixed source on the inside and a radio-frequency (RF) heating coil for heating to a high temperature (T > 900 °C) and for easy control of temperature outside the source zone. Two types of LEDs were prepared, with In compositions of 11.0 and 6.0% in the InGaN active layer, and room-temperature electroluminescence measurements exhibited a main peak corresponding to the In composition at either 420 or 390 nm. The consecutive growth of InGaN LEDs by the mixed-source HVPE method provides a technique for the production of LEDs with a wide range of In compositions in the active layer.

A framework for air quality monitoring based on free public data and open source tools

NASA Astrophysics Data System (ADS)

Nikolov, Hristo; Borisova, Denitsa

2014-10-01

In the recent years more and more widely accepted by the Space agencies (e.g. NASA, ESA) is the policy toward provision of Earth observation (EO) data and end products concerning air quality especially in large urban areas without cost to researchers and SMEs. Those EO data are complemented by increasing amount of in-situ data also provided at no cost either from national authorities or having crowdsourced origin. This accessibility together with the increased processing capabilities of the free and open source software is a prerequisite for creation of solid framework for air modeling in support of decision making at medium and large scale. Essential part of this framework is web-based GIS mapping tool responsible for dissemination of the output generated. In this research an attempt is made to establish a running framework based solely on openly accessible data on air quality and on set of freely available software tools for processing and modeling taking into account the present status quo in Bulgaria. Among the primary sources of data, especially for bigger urban areas, for different types of gases and dust particles, noted should be the National Institute of Meteorology and Hydrology of Bulgaria (NIMH) and National System for Environmental Monitoring managed by Bulgarian Executive Environmental Agency (ExEA). Both authorities provide data for concentration of several gases just to mention CO, CO2, NO2, SO2, and fine suspended dust (PM10, PM2.5) on monthly (for some data on daily) basis. In the framework proposed these data will complement the data from satellite-based sensors such as OMI instrument aboard EOS-Aura satellite and from TROPOMI instrument payload for future ESA Sentinel-5P mission. Integral part of the framework is the modern map for the land use/land cover which is provided from EEA by initiative GIO Land CORINE. This map is also a product from EO data distributed at European level. First and above all, our effort is focused on provision to the wider public living in urbanized areas with one reliable source of information on the present conditions concerning the air quality. Also this information might be used as indicator for presence of acid rains in agriculture areas close to industrial or electricity plants. Its availability at regular basis makes such information valuable source in case of manmade industrial disasters or incidents such as forest fires. Key issue in developing this framework is to ensure the delivery of reliable data products related to air quality at larger scale that those available at the moment.

The Trade-Off: Consumer Privacy for Technology Products and Services

ERIC Educational Resources Information Center

Scibelli, David B.

2013-01-01

With the Internet advancements of information systems and social media channels, consumer data has become a valuable source for companies and social networking communities. These Internet businesses are allowed to use and share their customers' information, with minimal regulatory intervention other than in health and financial areas. This…

Ambient ammonia and related amines in and around a mink production facility

USDA-ARS?s Scientific Manuscript database

In areas where ammonia is a significant air pollutant or nuisance concern, knowledge of all potential source locations and strengths is paramount. The USEPA’s 2014 National Emissions Inventory estimates that nearly 80% of the national ammonia emissions are attributable to the agricultural sector an...

Effect of topographic characteristics on compound topographic index for identification of gully channel initiation locations

USDA-ARS?s Scientific Manuscript database

Sediment loads from gully erosion can be a significant sediment source within watershed resulting in major contributions to water quality problems, reduction of crop productivity by removal of nutrient rich top soil, and damaging downstream ecosystems. Areas containing a high probability of forming ...

Targeting critical sediment source areas using SWAT and WEPP roads

USDA-ARS?s Scientific Manuscript database

Several state and federal conservation programs provide financial assistance or benefits for landowners who remove cropland from production or implement soil and water conservation measures. Due to limited funding, only a small fraction of a watershed can be included in such programs. The goals of t...

40 CFR 63.11397 - What General Provisions apply to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Fibers Production Area Sources Other Requirements and Information § 63.11397 What General Provisions... vent system and control device, flare, or recovery device), fiber spinning line, AN storage tank..., your notification of compliance status required by § 63.9(h) must include the following information: (1...

40 CFR 63.11398 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Acrylic and Modacrylic Fibers Production Area Sources Other Requirements and Information § 63.11398 What definitions apply to this subpart? Acrylic fiber means a manufactured synthetic fiber in which the fiber-forming substance is any long-chain...

40 CFR 63.11397 - What General Provisions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Fibers Production Area Sources Other Requirements and Information § 63.11397 What General Provisions... vent system and control device, flare, or recovery device), fiber spinning line, AN storage tank..., your notification of compliance status required by § 63.9(h) must include the following information: (1...

40 CFR 63.11398 - What definitions apply to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Acrylic and Modacrylic Fibers Production Area Sources Other Requirements and Information § 63.11398 What definitions apply to this subpart? Acrylic fiber means a manufactured synthetic fiber in which the fiber-forming substance is any long-chain...

SWAT: Agricultural water and nonpoint source pollution management at a watershed scale - Part II

USDA-ARS?s Scientific Manuscript database

Global change and demographic changes increasingly cause water, food, and health problems in many areas of the world. In addition, the growth in bioenergy production leads to land-use change and associated environmental impacts. The lack of integration in resource assessments and policy-making leads...

SWAT: Agricultural water and nonpoint source pollution management at a watershed scale

USDA-ARS?s Scientific Manuscript database

Global change and demographic changes increasingly cause water, food, and health problems in many areas of the world. In addition, the growth in bioenergy production leads to land-use change and associated environmental impacts. The lack of integration in resource assessments and policy-making leads...

Fiber farming with insecticidal

Treesearch

Leah S. Bauer

1997-01-01

Naturally regenerated forests are the primary source of timber, fiber, and fuel throughout much of the world today. In the United States, however, public outcry over increasing forest fragmentation and habitat loss is reducing timber harvests in many areas. As our demand for forest products exceeds supplies, reliance on international timber resources will escalate,...

Beyond the Farmgate: Factors Related to Agricultural Performance in Two Dairy Communities.

ERIC Educational Resources Information Center

Cruise, James; Lyson, Thomas A.

1991-01-01

In two marginal dairy communities with similar physical environment, ethnic composition, and farm structure, a significant difference in productivity (milk yield per cow) was related to differences in educational attainment of farmers, proximity to an urban area, and availability of marketing outlets and agricultural information sources. Contains…

Deaf-Blindness: National Organizations and Resources. Reference Circular No. 93-1.

ERIC Educational Resources Information Center

Library of Congress, Washington, DC. National Library Service for the Blind and Physically Handicapped.

This circular lists national organizations and print and audiovisual resources on areas of service to persons with deaf blindness, including rehabilitation, education, information and referral, recreation, and sources for adaptive devices and products. Section I is an alphabetical list of 40 national organizations and resources, including…

Development and validation of a lead emission inventory for the Greater Cairo area

PubMed Central

Safar, Zeinab; Labib, Mounir W.; Gertler, Alan W.

2013-01-01

Studies that investigate the environmental health risks to Cairo residents invariably conclude that lead is one of the area’s major health hazards. The Cairo Air Improvement Project (CAIP), which was implemented by a team led by Chemonics International, funded by USAID in partnership with the Egyptian Environmental Affairs Agency (EEAA), started developing a lead emission inventory for the greater Cairo (GC) area in 1998. The inventory contains a list by major source of the annual lead emissions in the GC area. Uses of the inventory and associated database include developing effective regulatory and control strategies, assessing emissions trends, and conducting modeling exercises. This paper describes the development of the current lead emissions inventory (1999–2010), along with an approach to develop site specific emission factors and measurements to validate the inventory. This paper discusses the major sources of lead in the GC area, which include lead smelters, Mazout (heavy fuel oil) combustion, lead manufacturing batteries factories, copper foundries, and cement factories. Included will be the trend in the lead emissions inventory with regard to the production capacity of each source category. In addition, the lead ambient measurements from 1999 through 2010 are described and compared with the results of Source Attribution Studies (SAS) conducted in 1999, 2002, and 2010. Due to EEAA/CAIP efforts, a remarkable decrease in more than 90% in lead emissions was attained for 2007. PMID:25685523

An Assessment of Some Design Constraints on Heat Production of a 3D Conceptual EGS Model Using an Open-Source Geothermal Reservoir Simulation Code

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yidong Xia; Mitch Plummer; Robert Podgorney

2016-02-01

Performance of heat production process over a 30-year period is assessed in a conceptual EGS model with a geothermal gradient of 65K per km depth in the reservoir. Water is circulated through a pair of parallel wells connected by a set of single large wing fractures. The results indicate that the desirable output electric power rate and lifespan could be obtained under suitable material properties and system parameters. A sensitivity analysis on some design constraints and operation parameters indicates that 1) the fracture horizontal spacing has profound effect on the long-term performance of heat production, 2) the downward deviation anglemore » for the parallel doublet wells may help overcome the difficulty of vertical drilling to reach a favorable production temperature, and 3) the thermal energy production rate and lifespan has close dependence on water mass flow rate. The results also indicate that the heat production can be improved when the horizontal fracture spacing, well deviation angle, and production flow rate are under reasonable conditions. To conduct the reservoir modeling and simulations, an open-source, finite element based, fully implicit, fully coupled hydrothermal code, namely FALCON, has been developed and used in this work. Compared with most other existing codes that are either closed-source or commercially available in this area, this new open-source code has demonstrated a code development strategy that aims to provide an unparalleled easiness for user-customization and multi-physics coupling. Test results have shown that the FALCON code is able to complete the long-term tests efficiently and accurately, thanks to the state-of-the-art nonlinear and linear solver algorithms implemented in the code.« less

Hydrogen stable isotopic constraints on methane emissions from oil and gas extraction in the Colorado Front Range, USA

NASA Astrophysics Data System (ADS)

Townsend-Small, A.; Botner, E. C.; Jimenez, K.; Blake, N. J.; Schroeder, J.; Meinardi, S.; Barletta, B.; Simpson, I. J.; Blake, D. R.; Flocke, F. M.; Pfister, G.; Bon, D.; Crawford, J. H.

2015-12-01

The climatic implications of a shift from oil and coal to natural gas depend on the magnitude of fugitive emissions of methane from the natural gas supply chain. Attempts to constrain methane emissions from natural gas production regions can be confounded by other sources of methane. Here we demonstrate the utility of stable isotopes, particularly hydrogen isotopes, for source apportionment of methane emissions. The Denver, Colorado area is home to a large oil and gas field with both conventional oil and gas wells and newer hydraulic fracturing wells. The region also has a large metropolitan area with several landfills and a sizable cattle population. As part of the DISCOVER-AQ and FRAPPE field campaigns in summer 2014, we collected three types of canister samples for analysis of stable isotopic composition of methane: 1), samples from methane sources; 2), samples from two stationary ground sites, one in the Denver foothills, and one in an oil and gas field; and 3), from the NCAR C-130 aircraft in samples upwind and downwind of the region. Our results indicate that hydrogen isotope ratios are excellent tracers of sources of methane in the region, as we have shown previously in California and Texas. Use of carbon isotope ratios is complicated by the similarity of natural gas isotope ratios to that of background methane. Our results indicate that, despite the large amount of natural gas production in the region, biological sources such as cattle feedlots and landfills account for at least 50% of total methane emissions in the Front Range. Future work includes comparison of isotopes and alkane ratios as tracers of methane sources, and calculation of total methane fluxes in the region using continuous measurements of methane concentrations during aircraft flights.

Lineaments and fracture traces, Jennings County and Jefferson Proving Ground, Indiana

USGS Publications Warehouse

Greeman, T.K.

1981-01-01

Well placement is important in this area, as fractures are a principal source of water to wells. In areas of fractured bedrock, the most productive well locations are at the intersections of two or more mapped lineaments or fracture traces and at the lowest local altitude. Use of the lineament and fracture-trace map will not guarantee a sufficent supply of ground water but will minimize the chance of drilling an inadequate well.

Oxidative capacity of the Mexico City atmosphere - Part 1: A radical source perspective

NASA Astrophysics Data System (ADS)

Volkamer, R.; Sheehy, P. M.; Molina, L. T.; Molina, M. J.

2007-04-01

A detailed analysis of OH, HO2 and RO2 radical sources is presented for the near field photochemical regime inside the Mexico City Metropolitan Area (MCMA). During spring of 2003 (MCMA-2003 field campaign) an extensive set of measurements was collected to quantify time resolved ROx (sum of OH, HO2, RO2) radical production rates from day- and nighttime radical sources. The Master Chemical Mechanism (MCMv3.1) was constrained by measurements of (1) concentration time-profiles of photosensitive radical precursors, i.e., nitrous acid (HONO), formaldehyde (HCHO), ozone (O3), glyoxal (CHOCHO), and other oxygenated volatile organic compounds (OVOCs); (2) respective photolysis-frequencies (J-values); (3) concentration time-profiles of alkanes, alkenes, and aromatic VOCs (103 compound are treated) and oxidants, i.e., OH- and NO3 radicals, O3; and (4) NO, NO2, meteorological and other parameters. The ROx production rate was calculated directly from these observations; MCM was used to estimate further ROx production from unconstrained sources, and express overall ROx production as OH-equivalents (i.e., taking into account the propagation efficiencies of RO2 and HO2 radicals into OH radicals). Daytime radical production is found to be about 10-25 times higher than at night; it does not track the abundance of sunlight. 12-h average daytime contributions of individual sources are: HCHO and O3 photolysis, each about 20%; O3/alkene reactions and HONO photolysis, each about 15%; unmeasured sources about 30%. While the direct contribution of O3/alkene reactions appears to be moderately small, source-apportionment of ambient HCHO and HONO identifies O3/alkene reactions as being largely responsible for jump-starting photochemistry about one hour after sunrise. The peak radical production is found to be higher than in any other urban influenced environment studied to date; further, differences exist in the timing of radical production. Our measurements and analysis comprise a database that enables testing of the representation of radical sources in photochemical models. Since the photochemical processing of pollutants is radical-limited in the MCMA, our analysis identifies the drivers for such processing. Three pathways are identified by which reductions in VOC emissions induce reductions in peak concentrations of secondary pollutants, such as O3 and secondary organic aerosol (SOA).

The UKIRT Hemisphere Survey: definition and J-band data release

NASA Astrophysics Data System (ADS)

Dye, S.; Lawrence, A.; Read, M. A.; Fan, X.; Kerr, T.; Varricatt, W.; Furnell, K. E.; Edge, A. C.; Irwin, M.; Hambly, N.; Lucas, P.; Almaini, O.; Chambers, K.; Green, R.; Hewett, P.; Liu, M. C.; McGreer, I.; Best, W.; Zhang, Z.; Sutorius, E.; Froebrich, D.; Magnier, E.; Hasinger, G.; Lederer, S. M.; Bold, M.; Tedds, J. A.

2018-02-01

This paper defines the UK Infra-Red Telescope (UKIRT) Hemisphere Survey (UHS) and release of the remaining ∼12 700 deg2 of J-band survey data products. The UHS will provide continuous J- and K-band coverage in the Northern hemisphere from a declination of 0° to 60° by combining the existing Large Area Survey, Galactic Plane Survey and Galactic Clusters Survey conducted under the UKIRT Infra-red Deep Sky Survey (UKIDSS) programme with this new additional area not covered by UKIDSS. The released data include J-band imaging and source catalogues over the new area, which, together with UKIDSS, completes the J-band UHS coverage over the full ∼17 900 deg2 area. 98 per cent of the data in this release have passed quality control criteria. The remaining 2 per cent have been scheduled for re-observation. The median 5σ point source sensitivity of the released data is 19.6 mag (Vega). The median full width at half-maximum of the point spread function across the data set is 0.75 arcsec. In this paper, we outline the survey management, data acquisition, processing and calibration, quality control and archiving as well as summarizing the characteristics of the released data products. The data are initially available to a limited consortium with a world-wide release scheduled for 2018 August.

The Effect of Price Competition on Weapon System Acquisition costs

DTIC Science & Technology

1979-09-01

barriers to entry into the weapons production indistry. This practice also reduces the scope of price-compcLtive reprocurement. The implicit tying of R&D... removaL . ’For the serrinal work in this area see H. Leibenstein, "Allocative Efficiency vs. ,h-Efficiency," American Econcmic Review (June 1966). I1 3...If the use of price competition to assign production removes any extra-normal returns earned under sole-source pro- curement policies, firms will no

Anthropogenic Organic Compounds in Ground Water and Finished Water of Community Water Systems in the Northern Tampa Bay Area, Florida, 2002-04

USGS Publications Warehouse

Metz, Patricia A.; Delzer, Gregory C.; Berndt, Marian P.; Crandall, Christy A.; Toccalino, Patricia L.

2007-01-01

As part of the U.S. Geological Survey's (USGS's) National Water-Quality Assessment (NAWQA) Program, a Source Water-Quality Assessment (SWQA) was conducted in the unconfined and semiconfined portions of the Upper Floridan aquifer system during 2002-04. SWQAs are two-phased sampling activities, wherein phase 1 was designed to evaluate the occurrence of 258 anthropogenic organic compounds (AOCs) in ground water used as source water for 30 of the largest-producing community water system (CWS) wells in the northern Tampa Bay area, Florida. The 258 AOCs included volatile organic compounds (VOCs), pesticides, and other anthropogenic organic compounds (OAOCs). Phase 2 was designed to monitor concentrations in the source water and also the finished water of CWSs for compounds most frequently detected during phase 1. During phase 1 of the SWQA study, 31 of the 258 AOCs were detected in source-water samples collected from CWS wells at low concentrations (less than 1.0 microgram per liter (ug/L)). Twelve AOCs were detected in at least 10 percent of samples. Concentrations from 16 of the 31 detected AOCs were about 2 to 5 orders of magnitude below human-health benchmarks indicating that concentrations were unlikely to be of potential human-health concern. The potential human-health relevance for the remaining 15 detected unregulated AOCs could not be evaluated because no human-health benchmarks were available for these compounds. Hydrogeology, population, and land use were examined to evaluate the effects of these variables on the source water monitored. Approximately three times as many detections of VOCs (27) and pesticides (34) occurred in unconfined areas than in the semiconfined areas (8 VOCs, 14 pesticides). In contrast, 1 OAOC was detected in unconfined areas, and 13 OAOCs were detected in semiconfined areas with 9 of the OAOC detections occurring in samples from two wells located near septic systems. Analyses of population and land use indicated that the number of compounds detected increased as the population surrounding each well increased. Detection frequencies and concentrations for VOCs (particularly chloroform) and pesticides were highest in residential land-use areas. The results of source-water samples from the 30 CWS wells monitored during phase 1 of this SWQA study were compared to four locally conducted studies. These general comparisons indicate that the occurrence of VOCs in other studies is similar to their occurrence in source water of CWSs monitored as part of this SWQA. However, pesticide compounds, especially atrazine and its breakdown products, occurred more frequently in the SWQA study than in the other four studies. Phase 2 of the SWQA assessed AOCs in samples from 11 of the 30 CWS wells and the associated finished water. Overall, 42 AOCs were detected in either source water or finished water and more compounds were detected in finished water than in source water. Specifically, 22 individual AOCs were detected in source water and 27 AOCs were detected in finished water. The total number of detections was greater in the finished water (80) than in the source water (49); however, this was largely due to the creation of disinfection by-products (DBPs) during water treatment. Excluding DBPs, about the same number of total detections was observed in source water (40) and finished water (44). During phase 2, AOC detected concentrations ranged from E0.003 (estimated) to 1,140 ug/L in the source water and from E0.003 to 36.3 ug/L in the finished water. Concentrations of 24 of the 42 compounds were compared to human-health benchmarks and were about 1 to 5 orders of magnitude below their human-health benchmarks indicating that concentrations are unlikely to be of potential human-health concern, excluding DBPs. Concentrations of carbon tetrachloride, however, were within 10 percent of its human-health benchmark, which is considered a level that may warrant inclusion of the compound in a low-concentration, t

Strategies for the removal of halides from drinking water sources, and their applicability in disinfection by-product minimisation: a critical review.

PubMed

Watson, K; Farré, M J; Knight, N

2012-11-15

The presence of bromide (Br(-)) and iodide (I(-)) in source waters leads to the formation of brominated and iodinated disinfection by-products (DBPs), which are often more toxic than their chlorinated analogues. The increasing scarcity of water resources in Australia is leading to use of impaired and alternative water supplies with high bromide and iodide levels, which may result in the production of more brominated and iodinated DBPs. This review aims to provide a summary of research into bromide and iodide removal from drinking water sources. Bromide and iodide removal techniques have been broadly classified into three categories, namely; membrane, electrochemical and adsorptive techniques. Reverse osmosis, nanofiltration and electrodialysis membrane techniques are reviewed. The electrochemical techniques discussed are electrolysis, capacitive deionization and membrane capacitive deionization. Studies on bromide and iodide removal using adsorptive techniques including; layered double hydroxides, impregnated activated carbons, carbon aerogels, ion exchange resins, aluminium coagulation and soils are also assessed. Halide removal techniques have been compared, and areas for future research have been identified. Copyright © 2012 Elsevier Ltd. All rights reserved.

Habitat Hydrology and Geomorphology Control the Distribution of Malaria Vector Larvae in Rural Africa

PubMed Central

Hardy, Andrew J.; Gamarra, Javier G. P.; Cross, Dónall E.; Macklin, Mark G.; Smith, Mark W.; Kihonda, Japhet; Killeen, Gerry F.; Ling’ala, George N.; Thomas, Chris J.

2013-01-01

Background Larval source management is a promising component of integrated malaria control and elimination. This requires development of a framework to target productive locations through process-based understanding of habitat hydrology and geomorphology. Methods We conducted the first catchment scale study of fine resolution spatial and temporal variation in Anopheles habitat and productivity in relation to rainfall, hydrology and geomorphology for a high malaria transmission area of Tanzania. Results Monthly aggregates of rainfall, river stage and water table were not significantly related to the abundance of vector larvae. However, these metrics showed strong explanatory power to predict mosquito larval abundances after stratification by water body type, with a clear seasonal trend for each, defined on the basis of its geomorphological setting and origin. Conclusion Hydrological and geomorphological processes governing the availability and productivity of Anopheles breeding habitat need to be understood at the local scale for which larval source management is implemented in order to effectively target larval source interventions. Mapping and monitoring these processes is a well-established practice providing a tractable way forward for developing important malaria management tools. PMID:24312606

Habitat hydrology and geomorphology control the distribution of malaria vector larvae in rural Africa.

PubMed

Hardy, Andrew J; Gamarra, Javier G P; Cross, Dónall E; Macklin, Mark G; Smith, Mark W; Kihonda, Japhet; Killeen, Gerry F; Ling'ala, George N; Thomas, Chris J

2013-01-01

Larval source management is a promising component of integrated malaria control and elimination. This requires development of a framework to target productive locations through process-based understanding of habitat hydrology and geomorphology. We conducted the first catchment scale study of fine resolution spatial and temporal variation in Anopheles habitat and productivity in relation to rainfall, hydrology and geomorphology for a high malaria transmission area of Tanzania. Monthly aggregates of rainfall, river stage and water table were not significantly related to the abundance of vector larvae. However, these metrics showed strong explanatory power to predict mosquito larval abundances after stratification by water body type, with a clear seasonal trend for each, defined on the basis of its geomorphological setting and origin. Hydrological and geomorphological processes governing the availability and productivity of Anopheles breeding habitat need to be understood at the local scale for which larval source management is implemented in order to effectively target larval source interventions. Mapping and monitoring these processes is a well-established practice providing a tractable way forward for developing important malaria management tools.

Occupational exposure to acrylamide in closed system production plants: air levels and biomonitoring.

PubMed

Moorman, William J; Reutman, Susan S; Shaw, Peter B; Blade, Leo Michael; Marlow, David; Vesper, Hubert; Clark, John C; Schrader, Steven M

2012-01-01

The aim of this study was to evaluate biomarkers of acrylamide exposure, including hemoglobin adducts and urinary metabolites in acrylamide production workers. Biomarkers are integrated measures of the internal dose, and it is total acrylamide dose from all routes and sources that may present health risks. Workers from three companies were studied. Workers potentially exposed to acrylamide monomer wore personal breathing-zone air samplers. Air samples and surface-wipe samples were collected and analyzed for acrylamide. General-area air samples were collected in chemical processing units and control rooms. Hemoglobin adducts were isolated from ethylenediamine teraacetic acid (EDTA)-whole blood, and adducts of acrylamide and glycidamide, at the N-terminal valines of hemoglobin, were cleaved from the protein chain by use of a modified Edman reaction. Full work-shift, personal breathing zone, and general-area air samples were collected and analyzed for particulate and acrylamide monomer vapor. The highest general-area concentration of acrylamide vapor was 350 μg/cm(3) in monomer production. Personal breathing zone and general-area concentrations of acrylamide vapor were found to be highest in monomer production operations, and lower levels were in the polymer production operations. Adduct levels varied widely among workers, with the highest in workers in the monomer and polymer production areas. The acrylamide adduct range was 15-1884 pmol/g; glycidamide adducts ranged from 17.8 to 1376 p/mol/g. The highest acrylamide and glycidamide adduct levels were found among monomer production process operators. The primary urinary metabolite N-acetyl-S-(2-carbamoylethyl) cysteine (NACEC) ranged from the limit of detection to 15.4 μg/ml. Correlation of workplace exposure and sentinel health effects is needed to determine and control safe levels of exposure for regulatory standards.

Drugs and Cosmetics from the Sea

PubMed Central

Kijjoa, Anake; Sawangwong, Pichan

2004-01-01

The marine environment is a rich source of both biological and chemical diversity. This diversity has been the source of unique chemical compounds with the potential for industrial development as pharmaceuticals, cosmetics, nutritional supplements, molecular probes, fine chemicals and agrochemicals. In recent years, a significant number of novel metabolites with potent pharmacological properties has been discovered from the marine organisms. Although there are only a few marine-derived products currently on the market, several robust new compounds derived from marine natural products are now in the clinical pipeline, with more clinical development. While the marine world offers an extremely rich resource for novel compounds, it also represents a great challenge that requires inputs from various scientific areas to bring the marine chemical diversity up to its therapeutic potential.

Fogwater chemistry in a wood-burning community, western Oregon.

PubMed

Muir, P S

1991-01-01

Fogwater chemistry in Corvallis, Oregon, a wood-burning community (pop. approximately 43,000) was compared with the chemistry of fogwater collected in more remote and in more highly industrialized areas. The fogwater was not acidic (median pH = 5.7) and was usually dominated by SO4=, NO3-, and NH4+ whose concentrations were generally lower than in fogwater in other urban areas but higher than in remote areas. Concentrations of formic and acetic acids (medians = 61 and 52 microN, respectively) were comparable to those in fogwater in Los Angeles, California and were typically much higher than concentrations in fogwater from more remote areas. Formate and acetate concentrations were often comparable to those of SO4= and NO3-. Formaldehyde concentrations (range = 0.4-3.0 mg L-1) were comparable to those in fogwater in some urban areas of southern California, yet lower than concentrations in highly industrialized areas of southern California. Because concentrations of organic compounds in Corvallis fogwater were often comparable to those in larger urban areas, sources in addition to motor vehicles must be important in Corvallis. Additional sources may be natural and anthropogenic, the latter including residential wood burning and wood products industries.

Allergen source materials: state-of-the-art.

PubMed

Esch, Robert E

2009-01-01

A variety of positive outcomes can be realized from validation and risk management activities (see Table 4). They are dependent on the participation of multiple functional groups including the quality unit, regulatory and legal affairs, engineering and production operations, research and development, and sales and marketing. Quality risk management is receiving increased attention in the area of public health, pharmacovigilance, and pharmaceutical manufacturing. Recent examples of its regulatory use in our industry include the assessment of the potential risks of transmissible spongiform encephalopathies (TSE) agents through contaminated products], the risks of precipitates in allergenic extracts, and the revision of the potency limits for standardized dust mite and grass allergen vaccines. Its application to allergen source material process validation activities allowed for a practical strategy, especially in a complex manufacturing environment involving hundreds of products with multiple intended uses. In addition, the use of tools such as FMEA was useful in evaluating proposed changes made to manufacturing procedures and product specifications, new regulatory actions, and customer feedback or complaints. The success of such a quality assurance programs will ultimately be reflected in the elimination or reduction of product failures, improvement in the detection and prediction of potential product failures, and increased confidence in product quality.

Global oceanic production of nitrous oxide

PubMed Central

Freing, Alina; Wallace, Douglas W. R.; Bange, Hermann W.

2012-01-01

We use transient time distributions calculated from tracer data together with in situ measurements of nitrous oxide (N2O) to estimate the concentration of biologically produced N2O and N2O production rates in the ocean on a global scale. Our approach to estimate the N2O production rates integrates the effects of potentially varying production and decomposition mechanisms along the transport path of a water mass. We estimate that the oceanic N2O production is dominated by nitrification with a contribution of only approximately 7 per cent by denitrification. This indicates that previously used approaches have overestimated the contribution by denitrification. Shelf areas may account for only a negligible fraction of the global production; however, estuarine sources and coastal upwelling of N2O are not taken into account in our study. The largest amount of subsurface N2O is produced in the upper 500 m of the water column. The estimated global annual subsurface N2O production ranges from 3.1 ± 0.9 to 3.4 ± 0.9 Tg N yr−1. This is in agreement with estimates of the global N2O emissions to the atmosphere and indicates that a N2O source in the mixed layer is unlikely. The potential future development of the oceanic N2O source in view of the ongoing changes of the ocean environment (deoxygenation, warming, eutrophication and acidification) is discussed. PMID:22451110

Investigation of Biogenic and Non-biogenic Methane Sources in Texas

NASA Astrophysics Data System (ADS)

Yang, S.; Talbot, R. W.; Liu, L.; Lan, X.

2016-12-01

Methane (CH4) is a potent greenhouse gas with its mixing ratio increasing in the global atmosphere. Texas is one of the significant areas where underestimation of CH4 emissions by the U.S. inventories are pronounced. This study focused on two areas of Texas: Houston, the energy capital of the world, and the Barnett Shale area which is one of the largest onshore natural gas fields in the United States. The investigation of background CH4 and the fingerprints of CH4 emissions are critical to understanding potential impacts of extensive nature gas operations in these two areas. One-year of stationary CH4 measurements were studied to deduce the regional background CH4 characteristics and to identify the principle CH4 sources in Houston. Key information concerning CH4 sources can be obtained through the stable carbon isotope δ13CH4 during two field campaigns using a state-of-the-art mobile laboratory. CH4 mixing ratio and δ13C in CH4 were sampled by two cavity ring-down spectrometers (CRDS), one of which is coupled to a custom air core 13C sampling device which can supply more than 600 measurements for each plume analysis. Here, we report results of the overall δ13CH4 values and CH4 emission signatures derived from thirty-three sources in the two studied areas, ranging from oil production and processing, waste managements and landfills, to livestock. δ13CH4 signatures of these sources vary from -76‰ to -23‰. Several repeated measurements were sampled to investigate the variability of source signatures. We investigated a case of unexpected massive CH4 leaking detected near the San Jacinto River Fleet site. At the regional scale, the comparison of background δ13CH4 signatures were conducted to obtain the difference of dominate CH4 sources in two study areas. At the local scale, the combination of tower and mobile lab measurements were used to estimate and characterize CH4 emissions in Houston. The results and findings can supply valuable references for the local emission inventory and atmospheric model inputs.

Nitrogen saturation in the Rocky Mountains: Linking emissions, deposition, and ecosystem effects using stable isotopes of nitrogen compounds

USGS Publications Warehouse

Campbell, D.H.; Nanus, L.; Böhlke, J.K.; Harlin, K.; Collett, J.

2007-01-01

Elevated levels of atmospheric N deposition are affecting terrestrial and aquatic ecosystems at high elevations in Rocky Mountain National Park and adjacent areas of the Front Range of Colorado. Federal and state agencies are now working together to develop cost-effective means for reducing atmospheric N deposition. A discussion on N saturation covers the need for better understanding of N emission source areas and source types that contribute to N deposition in the Rocky Mountains Front Range of Colorado; reductions in NO emissions that resulted from Clean Air Act Amendments, which caused NO3 deposition to decrease between 1984 and 2003; factors contributing to N deposition, e.g., rapid population growth and energy development; origins of NO3, e.g., as NO emissions from fossil fuel combustion, including stationary sources (e.g. emission from coal combustion in electric generating units), and mobile sources (vehicle emissions); disperse stationary sources from energy resource development, e.g., natural gas production; and the importance of incorporating local source characterization and finer spatial and temporal sampling into future studies, which could provide additional insight into N deposition source attribution. This is an abstract of a paper presented at the 100th Annual Conference and Exhibition of the Air and Waste Management Association (Pittsburgh, PA 6/26-29/2007).

Contribution of regional-scale fire events to ozone and PM2.5 ...

EPA Pesticide Factsheets

Two specific fires from 2011 are tracked for local to regional scale contribution to ozone (O3) and fine particulate matter (PM2.5) using a freely available regulatory modeling system that includes the BlueSky wildland fire emissions tool, Spare Matrix Operator Kernel Emissions (SMOKE) model, Weather and Research Forecasting (WRF) meteorological model, and Community Multiscale Air Quality (CMAQ) photochemical grid model. The modeling system was applied to track the contribution from a wildfire (Wallow) and prescribed fire (Flint Hills) using both source sensitivity and source apportionment approaches. The model estimated fire contribution to primary and secondary pollutants are comparable using source sensitivity (brute-force zero out) and source apportionment (Integrated Source Apportionment Method) approaches. Model estimated O3 enhancement relative to CO is similar to values reported in literature indicating the modeling system captures the range of O3 inhibition possible near fires and O3 production both near the fire and downwind. O3 and peroxyacetyl nitrate (PAN) are formed in the fire plume and transported downwind along with highly reactive VOC species such as formaldehyde and acetaldehyde that are both emitted by the fire and rapidly produced in the fire plume by VOC oxidation reactions. PAN and aldehydes contribute to continued downwind O3 production. The transport and thermal decomposition of PAN to nitrogen oxides (NOX) enables O3 production in areas

Natural Products as Sources of New Drugs from 1981 to 2014.

PubMed

Newman, David J; Cragg, Gordon M

2016-03-25

This contribution is a completely updated and expanded version of the four prior analogous reviews that were published in this journal in 1997, 2003, 2007, and 2012. In the case of all approved therapeutic agents, the time frame has been extended to cover the 34 years from January 1, 1981, to December 31, 2014, for all diseases worldwide, and from 1950 (earliest so far identified) to December 2014 for all approved antitumor drugs worldwide. As mentioned in the 2012 review, we have continued to utilize our secondary subdivision of a "natural product mimic", or "NM", to join the original primary divisions and the designation "natural product botanical", or "NB", to cover those botanical "defined mixtures" now recognized as drug entities by the U.S. FDA (and similar organizations). From the data presented in this review, the utilization of natural products and/or their novel structures, in order to discover and develop the final drug entity, is still alive and well. For example, in the area of cancer, over the time frame from around the 1940s to the end of 2014, of the 175 small molecules approved, 131, or 75%, are other than "S" (synthetic), with 85, or 49%, actually being either natural products or directly derived therefrom. In other areas, the influence of natural product structures is quite marked, with, as expected from prior information, the anti-infective area being dependent on natural products and their structures. We wish to draw the attention of readers to the rapidly evolving recognition that a significant number of natural product drugs/leads are actually produced by microbes and/or microbial interactions with the "host from whence it was isolated", and therefore it is considered that this area of natural product research should be expanded significantly.

Microbiological and physicochemical factors affecting Aspergillus section Flavi incidence in Cavendish banana (Musa cavendishii) chips production in Southern Philippines.

PubMed

Sales, A C; Azanza, P V; Yoshizawa, T

2005-01-01

Microbiological and physicochemical factors affecting the incidence of Aspergillus section Flavi in dried Cavendish banana (Musa cavendishii) chips production in Southern Philippines were examined. The average counts of Aspergillus section Flavi (AFC) in fresh and dried Cavendish bananas from 10 production batches of the Philippine Agro-Industrial Development Cooperative in Davao del Norte, Southern Philippines were 1.2 x 10(2) and 1.6 x 10(2) cfu/g, respectively. Isolates from both samples were identified to be Aspergillus flavus based on spore type and conidial structure of isolates. An increasing trend in the AFC of Cavendish bananas was observed during dried banana chips processing. Variability in the AFC between production batches was attributed to differences in aerobic and fungal populations and physicochemical characteristics of the fruits, peel damage of the raw materials, concentration of AFC in the air and food-contact surfaces of the production area, and temperature and relative humidity (RH) conditions of the environment during production and storage. Physicochemical characteristics of Cavendish bananas from the receipt of raw materials up to the first day of drying were within the reported range of values allowing growth and toxin production by aflatoxigenic fungi. Air-borne AFC varied depending on the section of the production area examined. The close proximity of the waste disposal area from the production operation to the preparation, drying and storage areas suggests that cross-contamination, probably air-borne or insect-borne was a likely occurrence. The hands of workers were also identified as AFC sources. Results of this study highlight the need for the development of strategies to control aflatoxigenic fungi and aflatoxin contamination in Philippine dried Cavendish bananas.

Alkenone radiocarbon stratigraphy at high resolution continental marigin sites

NASA Astrophysics Data System (ADS)

Mollenhauer, G.; Eglinton, T.; Freudenthal, T.; Lamy, F.

2003-04-01

Radiocarbon stratigraphy is an essential tool for high resolution Late Quaternary paleoceanographic studies. For this purpose, radiocarbon ages of foraminifera have been extensively measured. Age models based on these measurements are commonly applied to a wide range of sediment proxy information, including the investigation of temporal leads and lags. The critical assumption made in these studies is that temporal coupling between foraminifera and other sediment constituents, including specific biomarkers of marine phytoplankton, e.g. alkenones, is maintained in the sediments. A recent study using coupled foraminifera and alkenone ages was conducted at a high sedimentation rate site situated at the Bermuda Rise sediment drift body. Ages of formanifera and alkenones differed by up to 8000 years. As an interpreation of these data, it was suggested that sediment constituents residing in different grain size fractions may have different current transport properties and may thus originate from different source areas separated by large geographical distances. Sediment retrieved from a site influenced by lateral advection would thus have to be regarded as a mixture of material from different sources. The time span between production and final deposition may be site dependent and remains largely unknown. Continental margins underlying high productivity areas are sites of high sediment accumulation. The major part of this sediment is believed to be biogenic and is produced in the overlying water column. Sediment particles are expected to be deposited rapidly at or near the site of production regardless of their size. To evaluate this premise, we have measured coupled radiocarbon ages of foraminifera, TOC and alkenones in samples taken from sediment cores retreived from three continental margin high accumulation rate sites. Cores from the Benguela upwelling system, the North West African upwelling system and from the Chilean margin high productivity area were chosen. All sites are characterized by high sedimentation rates (>15 cm/kyr). Variable current regimes prevailing at the individual sites may provide insight as to the factors controlling the sedimentation of fine grained particles as well as concerning source areas and residence time in bottom nepheloid layers. Paired foraminifera and alkenone ages provide important constraints on the interpretation of the proxy data obtained from each of the proxy carriers. In the future, alkenone temperatures combined with alkenone ages may thus also contribute to reconstruction of current regimes and trajectories.

The Impact of Financial Incentives on Physician Productivity in Medical Groups

PubMed Central

Conrad, Douglas A; Sales, Anne; Liang, Su-Ying; Chaudhuri, Anoshua; Maynard, Charles; Pieper, Lisa; Weinstein, Laurel; Gans, David; Piland, Neill

2002-01-01

Objective To estimate the effect of financial incentives in medical groups—both at the level of individual physician and collectively—on individual physician productivity. Data Sources/Study Setting Secondary data from 1997 on individual physician and group characteristics from two surveys: Medical Group Management Association (MGMA) Physician Compensation and Production Survey and the Cost Survey; Area Resource File data on market characteristics, and various sources of state regulatory data. Study Design Cross-sectional estimation of individual physician production function models, using ordinary least squares and two-stage least squares regression. Data Collection Data from respondents completing all items required for the two stages of production function estimation on both MGMA surveys (with RBRVS units as production measure: 102 groups, 2,237 physicians; and with charges as the production measure: 383 groups, 6,129 physicians). The 102 groups with complete data represent 1.8 percent of the 5,725 MGMA member groups. Principal Findings Individual production-based physician compensation leads to increased productivity, as expected (elasticity=.07, p<.05). The productivity effects of compensation methods based on equal shares of group net income and incentive bonuses are significantly positive (p<.05) and smaller in magnitude. The group-levelfinancial incentive does not appear to be significantly related to physician productivity. Conclusions Individual physician incentives based on own production do increase physician productivity. PMID:12236389

Syzygies, Pluricanonical Maps, and the Birational Geometry of Varieties of Maximal Albanese Dimension

NASA Astrophysics Data System (ADS)

Tesfagiorgis, Kibrewossen B.

Satellite Precipitation Estimates (SPEs) may be the only available source of information for operational hydrologic and flash flood prediction due to spatial limitations of radar and gauge products in mountainous regions. The present work develops an approach to seamlessly blend satellite, available radar, climatological and gauge precipitation products to fill gaps in ground-based radar precipitation field. To mix different precipitation products, the error of any of the products relative to each other should be removed. For bias correction, the study uses a new ensemble-based method which aims to estimate spatially varying multiplicative biases in SPEs using a radar-gauge precipitation product. Bias factors were calculated for a randomly selected sample of rainy pixels in the study area. Spatial fields of estimated bias were generated taking into account spatial variation and random errors in the sampled values. In addition to biases, sometimes there is also spatial error between the radar and satellite precipitation estimates; one of them has to be geometrically corrected with reference to the other. A set of corresponding raining points between SPE and radar products are selected to apply linear registration using a regularized least square technique to minimize the dislocation error in SPEs with respect to available radar products. A weighted Successive Correction Method (SCM) is used to make the merging between error corrected satellite and radar precipitation estimates. In addition to SCM, we use a combination of SCM and Bayesian spatial method for merging the rain gauges and climatological precipitation sources with radar and SPEs. We demonstrated the method using two satellite-based, CPC Morphing (CMORPH) and Hydro-Estimator (HE), two radar-gauge based, Stage-II and ST-IV, a climatological product PRISM and rain gauge dataset for several rain events from 2006 to 2008 over different geographical locations of the United States. Results show that: (a) the method of ensembles helped reduce biases in SPEs significantly; (b) the SCM method in combination with the Bayesian spatial model produced a precipitation product in good agreement with independent measurements .The study implies that using the available radar pixels surrounding the gap area, rain gauge, PRISM and satellite products, a radar like product is achievable over radar gap areas that benefits the operational meteorology and hydrology community.

4D petroleum system model of the Mississippian System in the Anadarko Basin Province, Oklahoma, Kansas, Texas, and Colorado, U.S.A.

USGS Publications Warehouse

Higley, Debra K.

2013-01-01

The Upper Devonian and Lower Mississippian Woodford Shale is an important petroleum source rock for Mississippian reservoirs in the Anadarko Basin Province of Oklahoma, Kansas, Texas, and Colorado, based on results from a 4D petroleum system model of the basin. The Woodford Shale underlies Mississippian strata over most of the Anadarko Basin portions of Oklahoma and northeastern Texas. The Kansas and Colorado portions of the province are almost entirely thermally immature for oil generation from the Woodford Shale or potential Mississippian source rocks, based mainly on measured vitrinite reflectance and modeled thermal maturation. Thermal maturities of the Woodford Shale range from mature for oil to overmature for gas generation at present-day depths of about 5,000 to 20,000 ft. Oil generation began at burial depths of about 6,000 to 6,500 ft. Modeled onset of Woodford Shale oil generation was about 330 million years ago (Ma); peak oil generation was from 300 to 220 Ma.Mississippian production, including horizontal wells of the informal Mississippi limestone, is concentrated within and north of the Sooner Trend area in the northeast Oklahoma portion of the basin. This large pod of oil and gas production is within the area modeled as thermally mature for oil generation from the Woodford Shale. The southern boundary of the trend approximates the 99% transformation ratio of the Woodford Shale, which marks the end of oil generation. Because most of the Sooner Trend area is thermally mature for oil generation from the Woodford Shale, the trend probably includes short- and longer-distance vertical and lateral migration. The Woodford Shale is absent in the Mocane-Laverne Field area of the eastern Oklahoma panhandle; because of this, associated oil migrated from the south into the field. If the Springer Formation or deeper Mississippian strata generated oil, then the southern field area is within the oil window for associated petroleum source rocks. Mississippian fields along the western boundary of the study area were supplied by oil that flowed northward from the Panhandle Field area and westward from the deep basin.

Climatic and geomorphic drivers of plant organic matter transport in the Arun River, E Nepal

NASA Astrophysics Data System (ADS)

Hoffmann, Bernd; Feakins, Sarah J.; Bookhagen, Bodo; Olen, Stephanie M.; Adhikari, Danda P.; Mainali, Janardan; Sachse, Dirk

2016-10-01

Fixation of atmospheric CO2 in terrestrial vegetation, and subsequent export and deposition of terrestrial plant organic matter in marine sediments is an important component of the global carbon cycle, yet it is difficult to quantify. This is partly due to the lack of understanding of relevant processes and mechanisms responsible for organic-matter transport throughout a landscape. Here we present a new approach to identify terrestrial plant organic matter source areas, quantify contributions and ascertain the role of ecologic, climatic, and geomorphic controls on plant wax export in the Arun River catchment spanning the world's largest elevation gradient from 205 to 8848 m asl, in eastern Nepal. Our approach takes advantage of the distinct stable hydrogen isotopic composition (expressed as δD values) of plant wax n-alkanes produced along this gradient, transported in river waters and deposited in flood deposits alongside the Arun River and its tributaries. In mainstem-flood deposits, we found that plant wax n-alkanes were mostly derived from the lower elevations constituting only a small fraction (15%) of the catchment. Informed by remote sensing data, we tested four differently weighted isotopic mixing models that quantify sourcing of tributary plant-derived organic matter along the Arun and compare it to our field observations. The weighting parameters included catchment area, net primary productivity (NPP) and annual rainfall amount as well as catchment relief as erosion proxy. When weighted by catchment area the isotopic mixing model could not explain field observations on plant wax δD values along the Arun, which is not surprising because the large arid Tibetan Plateau is not expected to be a major source. Weighting areal contributions by annual rainfall and NPP captured field observations within model prediction errors suggesting that plant productivity may influence source strength. However weighting by a combination of rainfall and catchment relief also captured the observed δD value pattern suggesting dominantly erosive control. We conclude that tributaries at the southern Himalayan front with high rainfall, high productivity, high relief and high erosion rates dominate plant wax exports from the catchment.

Assessment of nonpoint-source contamination of the High Plains Aquifer in south-central Kansas, 1987

USGS Publications Warehouse

Helgesen, John O.; Stullken, Lloyd E.; Rutledge, A.T.

1992-01-01

Ground-water quality was assessed in a 5,000-square-mile area of the High Plains aquifer in south-central Kansas that is susceptible to nonpoint-source contamination from agricultural and petroleum-production activities. Of particular interest were agricultural chemicals, mainly atrazine, and oil-derived hydrocarbons, which might occur in association with brines that formerly were disposed into unlined ponds.Random sampling of ground water was done within a framework of discrete land-use areas (irrigated cropland, petroleum-production land containing former brine-disposal ponds, and undeveloped rangeland) of 3 to 10 square miles. Although true baseline water-quality conditions probably are rare, these baseline conditions are represented most closely by ground water beneath the areas of undeveloped rangeland. The sampling design enabled statistical hypothesis testing of the effects of land use, unsaturated-zone lithology, and type of well sampled. Statistical testing was based on nonparametric procedures.Results indicate that regional ground-water quality has been affected by prevailing land-use activities, as shown mainly by increased concentrations of several inorganic constituents. Ground water beneath irrigated cropland is characterized by significantly (95-percent confidence level) larger concentrations of hardness, alkalinity, calcium, magnesium, potassium, fluoride, and nitrite plus nitrate than is water beneath undeveloped rangeland. Nondegraded pesticides generally were not detected in the aquifer, probably because of degradation and sorption. Atrazine is present locally in ground water in small concentrations.Ground water beneath petroleum-production land is characterized by significantly (95-percent confidence level) larger concentrations of hardness, alkalinity, dissolved solids, sodium, and chloride than is water beneath undeveloped rangeland. Nonpoint-source ground-water contamination by oil-derived hydrocarbons was not discernible. The occurrences of trace-organic compounds were similar between petroleum-production land and undeveloped rangeland, which indicates a natural origin for these compounds.The unsaturated zone in the study area is lithologically heterogeneous and contains substantial amounts of clay that inhibit the downward movement of water and solutes. Within the aquifer, the rate of regional lateral flow and solute transport is sufficiently slow so that the ground-water quality reflects overlying land use in discrete areas of several square miles. Regional flow, however, is sufficiently rapid so that the type of well sampled is not important in regional characterization of water quality beneath irrigated cropland; the seasonal pumping of irrigation wells does not appear to divert regional flow enough to cause substantial local anomalies of more mineralized ground water.

Cuminum cyminum and Carum carvi: An update

PubMed Central

Johri, R. K.

2011-01-01

Cuminum cyminum and Carum carvi are the sources of cumin and caraway seeds respectively, which have been used since antiquity for the treatment of various indications in traditional healing systems in wide geographical areas. Cumin and caraway seeds are rich sources of essential oils and have been actively researched for their chemical composition and biological activities. In recent times (especially during the last 3 years) considerable progress has been made regarding validation of their acclaimed medicinal attributes by extensive experimental studies. In this attempt many novel bioactivities have been revealed. This review highlights the significance of cumin and caraway as potential source of diverse natural products and their medicinal applications. PMID:22096320

Primary and secondary sources of formaldehyde in urban atmospheres: Houston Texas region

NASA Astrophysics Data System (ADS)

Parrish, D. D.; Ryerson, T. B.; Mellqvist, J.; Johansson, J.; Fried, A.; Richter, D.; Walega, J. G.; Washenfelder, R. A.; de Gouw, J. A.; Peischl, J.; Aikin, K. C.; McKeen, S. A.; Frost, G. J.; Fehsenfeld, F. C.; Herndon, S. C.

2011-12-01

We evaluate the rates of secondary production and primary emission of formaldehyde (CH2O) from petrochemical industrial facilities and on-road vehicles in the Houston Texas region. This evaluation is based upon ambient measurements collected during field studies in 2000, 2006 and 2009. The predominant CH2O source (92 ± 4% of total) is secondary production formed during the atmospheric oxidation of highly reactive volatile organic compounds (HRVOCs) emitted from the petrochemical facilities. Smaller contributions are primary emissions from these facilities (4 ± 2%), and secondary production (~3%) and primary emissions (~1%) from vehicles. The primary emissions from both sectors are well quantified by current emission inventories. Since secondary production dominates, control efforts directed at primary CH2O emissions cannot address the large majority of CH2O sources in the Houston area, although there may still be a role for such efforts. Ongoing efforts to control alkene emissions from the petrochemical facilities, as well as volatile organic compound emissions from the motor vehicle fleet, will effectively reduce the CH2O concentrations in the Houston region. We have not addressed other emission sectors, such as off-road mobile sources or secondary formation from biogenic hydrocarbons. Previous analyses based on correlations between ambient concentrations of CH2O and various marker species have suggested much larger primary emissions of CH2O, but those results neglect confounding effects of dilution and loss processes, and do not demonstrate the causes of the observed correlations. Similar problems must be suspected in any source apportionment analysis of secondary species based upon correlations of ambient concentrations of pollutants.

Primary and secondary sources of formaldehyde in urban atmospheres: Houston Texas region

NASA Astrophysics Data System (ADS)

Parrish, D. D.; Ryerson, T. B.; Mellqvist, J.; Johansson, J.; Fried, A.; Richter, D.; Walega, J. G.; Washenfelder, R. A.; de Gouw, J. A.; Peischl, J.; Aikin, K. C.; McKeen, S. A.; Frost, G. J.; Fehsenfeld, F. C.; Herndon, S. C.

2012-04-01

We evaluate the rates of secondary production and primary emission of formaldehyde (CH2O) from petrochemical industrial facilities and on-road vehicles in the Houston Texas region. This evaluation is based upon ambient measurements collected during field studies in 2000, 2006 and 2009. The predominant CH2O source (92 ± 4% of total) is secondary production formed during the atmospheric oxidation of highly reactive volatile organic compounds (HRVOCs) emitted from the petrochemical facilities. Smaller contributions are primary emissions from these facilities (4 ± 2%), and secondary production (~3%) and primary emissions (~1%) from vehicles. The primary emissions from both sectors are well quantified by current emission inventories. Since secondary production dominates, control efforts directed at primary CH2O emissions cannot address the large majority of CH2O sources in the Houston area, although there may still be a role for such efforts. Ongoing efforts to control alkene emissions from the petrochemical facilities, as well as volatile organic compound emissions from the motor vehicle fleet, will effectively reduce the CH2O concentrations in the Houston region. We do not address other emission sectors, such as off-road mobile sources or secondary formation from biogenic hydrocarbons. Previous analyses based on correlations between ambient concentrations of CH2O and various marker species have suggested much larger primary emissions of CH2O, but those results neglect confounding effects of dilution and loss processes, and do not demonstrate the causes of the observed correlations. Similar problems must be suspected in any source apportionment analysis of secondary species based upon correlations of ambient concentrations of pollutants.

iss031e143143

NASA Image and Video Library

2012-06-19

ISS031-E-143143 (19 June 2012) --- Al Jubayl, Saudi Arabia at night is featured in this image photographed by an Expedition 31 crew member on the International Space Station. The city of Al Jubayl (or Jubail) is located on the Saudi Arabian coastline of the Persian Gulf. The city has a history extending back more than 7,000 years, but since 1975 it has been associated with the heavy industries of petrochemical refining and production, fertilizer production and steel works. At night, these industrial areas form a brightly lit region (center) to the south of the residential and commercial center of Al Jubayl (characterized by green-gray lighting). An artificial peninsula extending into the Persian Gulf to the northeast hosts supertanker docks and petroleum storage facilities. The Persian Gulf to the north and northeast is devoid of lights; likewise, the open desert to the south-southeast provides a stark contrast to the well-lit urban and industrial areas. A bright circle of light located within the heavy industrial area (center) cannot be resolved in this photograph, but is likely a concentration of lights associated with ongoing processing or construction activities. The approximate scale of the feature ? hundreds of meters in diameter ? is consistent with multiple stationary light sources, particularly if the light from those sources is accentuated due to the camera?s low light settings.

The surficial aquifer in east-central St Johns County, Florida

USGS Publications Warehouse

Hayes, Eugene C.

1981-01-01

The surficial aquifer, a composite of confined and unconfined water-bearing zones overlying the Miocene Hawthorn Formation, is an important source of water in St. Johns County, Fla. The water from wells open to the surficial aquifer generally meets quality standards recommended by the U.S. Environmental Protection Agency for public water supplies, except for concentrations of iron that for most wells are substantially greater than the recommended limit of 0.3 milligrams per liter. Data from 12 test wells drilled to the top of the Hawthorn formation, about 100 feet below land surface, indicate that the productive zones and confining beds in the surficial aquifer are discontinuous. Test well yields from individual zones range from less than 1 to 42 gallons per minute from depths between 20 and 100 feet below land surface. The most productive zones were generally found in the Tillman Ridge area, about 10 square miles in the west-central part of the area of investigation. Analysis of an aquifer test on a well in the Tillman Ridge area indicates a transmissivity of about 6,500 to 7,000 feet squared per day. The best local source of good quality water for development of a relatively large water supply is in the vicinity of Tillman Ridge. (USGS)

The Chandra Source Catalog 2.0: Interfaces

NASA Astrophysics Data System (ADS)

D'Abrusco, Raffaele; Zografou, Panagoula; Tibbetts, Michael; Allen, Christopher E.; Anderson, Craig S.; Budynkiewicz, Jamie A.; Burke, Douglas; Chen, Judy C.; Civano, Francesca Maria; Doe, Stephen M.; Evans, Ian N.; Evans, Janet D.; Fabbiano, Giuseppina; Gibbs, Danny G., II; Glotfelty, Kenny J.; Graessle, Dale E.; Grier, John D.; Hain, Roger; Hall, Diane M.; Harbo, Peter N.; Houck, John C.; Lauer, Jennifer L.; Laurino, Omar; Lee, Nicholas P.; Martínez-Galarza, Rafael; McCollough, Michael L.; McDowell, Jonathan C.; Miller, Joseph; McLaughlin, Warren; Morgan, Douglas L.; Mossman, Amy E.; Nguyen, Dan T.; Nichols, Joy S.; Nowak, Michael A.; Paxson, Charles; Plummer, David A.; Primini, Francis Anthony; Rots, Arnold H.; Siemiginowska, Aneta; Sundheim, Beth A.; Van Stone, David W.

2018-01-01

Easy-to-use, powerful public interfaces to access the wealth of information contained in any modern, complex astronomical catalog are fundamental to encourage its usage. In this poster,I present the public interfaces of the second Chandra Source Catalog (CSC2). CSC2 is the most comprehensive catalog of X-ray sources detected by Chandra, thanks to the inclusion of Chandra observations public through the end of 2014 and to methodological advancements. CSC2 provides measured properties for a large number of sources that sample the X-ray sky at fainter levels than the previous versions of the CSC, thanks to the stacking of single overlapping observations within 1’ before source detection. Sources from stacks are then crossmatched, if multiple stacks cover the same area of the sky, to create a list of unique, optimal CSC2 sources. The properties of sources detected in each single stack and each single observation are also measured. The layered structure of the CSC2 catalog is mirrored in the organization of the CSC2 database, consisting of three tables containing all properties for the unique stacked sources (“Master Source”), single stack sources (“Stack Source”) and sources in any single observation (“Observation Source”). These tables contain estimates of the position, flags, extent, significances, fluxes, spectral properties and variability (and associated errors) for all classes of sources. The CSC2 also includes source region and full-field data products for all master sources, stack sources and observation sources: images, photon event lists, light curves and spectra.CSCview, the main interface to the CSC2 source properties and data products, is a GUI tool that allows to build queries based on the values of all properties contained in CSC2 tables, query the catalog, inspect the returned table of source properties, browse and download the associated data products. I will also introduce the suite of command-line interfaces to CSC2 that can be used in alternative to CSCview, and will present the concept for an additional planned cone-search web-based interface.This work has been supported by NASA under contract NAS 8-03060 to the Smithsonian Astrophysical Observatory for operation of the Chandra X-ray Center.

Wood to energy: using southern interface fuels for bioenergy

Treesearch

C. Staudhammer; L.A. Hermansen; D. Carter; Ed Macie

2011-01-01

This publications aims to increase awareness of potential uses for woody biomass in the southern wildland-urban interface (WUI) and to disseminate knowledge about putting bioenergy production systems in place, while addressing issues unique to WUI areas. Chapter topics include woody biomass sources in the wildland-urban interface; harvesting, preprocessing and delivery...

Alaska: 2002 Economic Census. Educational Services, Geographic Area Series.

ERIC Educational Resources Information Center

US Department of Commerce, 2005

2005-01-01

The economic census is the major source of facts about the structure and functioning of the nation's economy. It provides essential information for government, business, industry, and the general public. The economic census furnishes an important part of the framework for such composite measures as the gross domestic product estimates, input…

New Mexico: 2002 Economic Census. Educational Services, Geographic Area Series.

ERIC Educational Resources Information Center

US Department of Commerce, 2005

2005-01-01

The economic census is the major source of facts about the structure and functioning of the nation's economy. It provides essential information for government, business, industry, and the general public. The economic census furnishes an important part of the framework for such composite measures as the gross domestic product estimates,…

Advancing the Use of Earth Observations to Benefit Global Food Security and Agriculture

USDA-ARS?s Scientific Manuscript database

USDA plays an important role as “fair broker” of information on the status and security of the United States and global food supply. USDA surveys and farmer relationships are the source of much of the “ground-truth” required for statistical assessments of crop area, yield, and production domestical...

Evaluating the influence of wind speed on caryopsis dispersal of Miscanthus sinensis and Miscanthus x. giganteus

USDA-ARS?s Scientific Manuscript database

With the increasing demand for alternative energy sources, perennial grasses are being evaluated for biomass production on large scales. Yet there is concern that some candidate species have the potential to escape cultivation and invade natural areas. Therefore, it is important that components of...

Pilot-scale concept of real-time wind speed-matching wind tunnel for measurements of gaseous emissions

USDA-ARS?s Scientific Manuscript database

Comprehensive control of odors, hydrogen sulfide (H2S), ammonia (NH3) and odorous volatile organic compound (VOC) emissions associated with animal production is a critical need. Current methods utilizing wind tunnels and flux chambers for measurements of gaseous emissions from area sources such as f...

The Use of Television in Adult Education; Research Evidence and Theoretical Considerations.

ERIC Educational Resources Information Center

Zettl, Herbert Lorenz

This study sought to detect major trends and areas in the use of television in adult education and to suggest useful generalizations. Research studies were grouped by program source, educational method, program format, production techniques, program reception, and viewer reaction. These communication categories were then correlated, with the…

Development of soybean with novel sources of resistance to Phomopsis seed decay

USDA-ARS?s Scientific Manuscript database

Phomopsis seed decay (PSD) is an important soybean disease that results in poor seed quality in most soybean production areas of the United States. PSD is caused primarily by the fungal pathogen Phomopsis longicolla. In 2009, due to the prevalence of hot and humid environments from pod fill to harve...

Evaluating soybean germplasm and commercial varieties for resistance to Phomopsis seed decay

USDA-ARS?s Scientific Manuscript database

Soybean Phomopsis seed decay (PSD) is the major cause of poor seed quality in most soybean production areas of the United States. Very few soybean cultivars currently available for planting in the US have resistance to PSD. To identify new sources of resistance to PSD, a multistate and multiyear res...

40 CFR Table 1 to Subpart Llllll... - Applicability of General Provisions to Subpart LLLLLL

Code of Federal Regulations, 2011 CFR

2011-07-01

... Modacrylic Fibers Production Area Sources Pt. 63, Subpt. LLLLLL, Table 1 Table 1 to Subpart LLLLLL of Part 63... not include opacity or visible emissions standards or require a continuous opacity monitoring system... does not require a continuous opacity monitoring system or continuous emissions monitoring system. 63.9...

40 CFR Table 1 to Subpart Llllll... - Applicability of General Provisions to Subpart LLLLLL

Code of Federal Regulations, 2010 CFR

2010-07-01

... Modacrylic Fibers Production Area Sources Pt. 63, Subpt. LLLLLL, Table 1 Table 1 to Subpart LLLLLL of Part 63... not include opacity or visible emissions standards or require a continuous opacity monitoring system... does not require a continuous opacity monitoring system or continuous emissions monitoring system. 63.9...

The effect of photoperiod on tuberization in cultivated x wild potato species hybrids

USDA-ARS?s Scientific Manuscript database

Wild Solanum species offer a valuable source of genetic diversity for potato improvement. Most of these species are found in equatorial South and Central America and they do not tuberize under long day photoperiods typical of those in the major potato production areas of North America, Europe and As...

Population structure of the NPGS Senegalese sorghum collection and its evaluation to identify new disease resistant genes

USDA-ARS?s Scientific Manuscript database

Sorghum germplasm from West and Central Africa is cultivated in rainy and high humidity regions and is an important source of resistance genes to fungal diseases. Mold and anthracnose are two important biotic constraints to sorghum production in wet areas worldwide. Here, 158 National Plant Germplas...

Dioxins, DL-PCB and NDL-PCB accumulation profiles in livers from sheep and cattle reared in North-western Italy.

PubMed

Benedetto, A; Brizio, P; Guaraldo, P; Stella, C; Cappa, C; Baioni, E; Spalenza, V; Nebbia, C; Abete, M C

2016-06-01

Products of animal origin represent the main route of human exposure to dioxins and dioxin-like PCBs (DL-compounds). Recently, concerns have been raised about ovine products, particularly the liver, in which relatively high levels of DL-compounds have been reported. We surveyed ovine and bovine livers in areas with no known sources of dioxin or DL-PCB contamination, in order to assess accumulation patterns for both DL-compounds and non-DL (NDL-) PCBs. None of the ovine and bovine samples exceeded the current Maximum Limits (MLs) for DL-compounds. Liver DL-compound TEQ concentrations were up to 5-fold higher in sheep than in cows. No statistically significant differences in total NDL-PCBs levels were found. The main contributors to TEQ levels were the Penta- and Hexa-chlorinated PCDFs and PCB 126. The results confirm the increased bioaccumulation in ovine liver towards specific DL-compounds even in ewes reared in areas with no known sources of PCDD/Fs or DL-PCBs contamination. Copyright © 2016 Elsevier Ltd. All rights reserved.

Prioritizing Sites for Protection and Restoration for Grizzly Bears (Ursus arctos) in Southwestern Alberta, Canada.

PubMed

Braid, Andrew C R; Nielsen, Scott E

2015-01-01

As the influence of human activities on natural systems continues to expand, there is a growing need to prioritize not only pristine sites for protection, but also degraded sites for restoration. We present an approach for simultaneously prioritizing sites for protection and restoration that considers landscape patterns for a threatened population of grizzly bears (Ursus arctos) in southwestern Alberta, Canada. We considered tradeoffs between bottom-up (food resource supply) and top-down (mortality risk from roads) factors affecting seasonal habitat quality for bears. Simulated annealing was used to prioritize source-like sites (high habitat productivity, low mortality risk) for protection, as well as sink-like sites (high habitat productivity, high mortality risk) for restoration. Priority source-like habitats identified key conservation areas where future developments should be limited, whereas priority sink-like habitats identified key areas for mitigating road-related mortality risk with access management. Systematic conservation planning methods can be used to complement traditional habitat-based methods for individual focal species by identifying habitats where conservation actions (both protection and restoration) have the highest potential utility.

How phosphorus limitation can control climate-active gas sources and sinks

NASA Astrophysics Data System (ADS)

Gypens, Nathalie; Borges, Alberto V.; Ghyoot, Caroline

2017-06-01

Since the 1950's, anthropogenic activities have increased nutrient river loads to European coastal areas. Subsequent implementation of nutrient reduction policies have led to considerably reduction of phosphorus (P) loads from the mid-1980's, while nitrogen (N) loads were maintained, inducing a P limitation of phytoplankton growth in many eutrophied coastal areas such as the Southern Bight of the North Sea (SBNS). When dissolved inorganic phosphorus (DIP) is limiting, most phytoplankton organisms are able to indirectly acquire P from dissolved organic P (DOP). We investigate the impact of DOP use on phytoplankton production and atmospheric fluxes of CO2 and dimethylsulfide (DMS) in the SBNS from 1951 to 2007 using an extended version of the R-MIRO-BIOGAS model. This model includes a description of the ability of phytoplankton organisms to use DOP as a source of P. Results show that primary production can increase up to 30% due to DOP uptake under limiting DIP conditions. Consequently, simulated DMS emissions also increase proportionally while CO2 emissions to the atmosphere decrease, relative to the reference simulation without DOP uptake.

Soybean hulls as an iron source for bread enrichment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, C.D.; Berry, M.F.; Weaver, C.M.

Soybean hulls, a concentrated source of iron, may have potential as a source of iron fortification in baked products. Retention of /sup 59/Fe in rats from white bread containing intrinsically labeled soybean hulls did not differ significantly (p<0.05) from extrinsically labeled white bread fortified with bakery grade ferrous sulfate (70.4 and 63.1%, respectively). Physical and sensory evaluations of bread containing up to 5% soybean hulls did not differ from white bread in loaf volume, cross-sectional area, tenderness or overall acceptance. These results suggest that soybean hulls are a good source of available iron and may be added to bakery productsmore » without deleterious effects in baking performance and sensory acceptability.« less

The foodscape: classification and field validation of secondary data sources.

PubMed

Lake, Amelia A; Burgoine, Thomas; Greenhalgh, Fiona; Stamp, Elaine; Tyrrell, Rachel

2010-07-01

The aims were to: develop a food environment classification tool and to test the acceptability and validity of three secondary sources of food environment data within a defined urban area of Newcastle-Upon-Tyne, using a field validation method. A 21 point (with 77 sub-categories) classification tool was developed. The fieldwork recorded 617 establishments selling food and/or food products. The sensitivity analysis of the secondary sources against fieldwork for the Newcastle City Council data was good (83.6%), while Yell.com and the Yellow Pages were low (51.2% and 50.9%, respectively). To improve the quality of secondary data, multiple sources should be used in order to achieve a realistic picture of the foodscape. 2010 Elsevier Ltd. All rights reserved.

Applications of stochastic models and geostatistical analyses to study sources and spatial patterns of soil heavy metals in a metalliferous industrial district of China.

PubMed

Zhong, Buqing; Liang, Tao; Wang, Lingqing; Li, Kexin

2014-08-15

An extensive soil survey was conducted to study pollution sources and delineate contamination of heavy metals in one of the metalliferous industrial bases, in the karst areas of southwest China. A total of 597 topsoil samples were collected and the concentrations of five heavy metals, namely Cd, As (metalloid), Pb, Hg and Cr were analyzed. Stochastic models including a conditional inference tree (CIT) and a finite mixture distribution model (FMDM) were applied to identify the sources and partition the contribution from natural and anthropogenic sources for heavy metal in topsoils of the study area. Regression trees for Cd, As, Pb and Hg were proved to depend mostly on indicators of anthropogenic activities such as industrial type and distance from urban area, while the regression tree for Cr was found to be mainly influenced by the geogenic characteristics. The FMDM analysis showed that the geometric means of modeled background values for Cd, As, Pb, Hg and Cr were close to their background values previously reported in the study area, while the contamination of Cd and Hg were widespread in the study area, imposing potentially detrimental effects on organisms through the food chain. Finally, the probabilities of single and multiple heavy metals exceeding the threshold values derived from the FMDM were estimated using indicator kriging (IK) and multivariate indicator kriging (MVIK). The high probabilities exceeding the thresholds of heavy metals were associated with metalliferous production and atmospheric deposition of heavy metals transported from the urban and industrial areas. Geostatistics coupled with stochastic models provide an effective way to delineate multiple heavy metal pollution to facilitate improved environmental management. Copyright © 2014 Elsevier B.V. All rights reserved.

Non-Point Source Pollutant Load Variation in Rapid Urbanization Areas by Remote Sensing, Gis and the L-THIA Model: A Case in Bao'an District, Shenzhen, China.

PubMed

Li, Tianhong; Bai, Fengjiao; Han, Peng; Zhang, Yuanyan

2016-11-01

Urban sprawl is a major driving force that alters local and regional hydrology and increases non-point source pollution. Using the Bao'an District in Shenzhen, China, a typical rapid urbanization area, as the study area and land-use change maps from 1988 to 2014 that were obtained by remote sensing, the contributions of different land-use types to NPS pollutant production were assessed with a localized long-term hydrologic impact assessment (L-THIA) model. The results show that the non-point source pollution load changed significantly both in terms of magnitude and spatial distribution. The loads of chemical oxygen demand, total suspended substances, total nitrogen and total phosphorus were affected by the interactions between event mean concentration and the magnitude of changes in land-use acreages and the spatial distribution. From 1988 to 2014, the loads of chemical oxygen demand, suspended substances and total phosphorus showed clearly increasing trends with rates of 132.48 %, 32.52 % and 38.76 %, respectively, while the load of total nitrogen decreased by 71.52 %. The immigrant population ratio was selected as an indicator to represent the level of rapid urbanization and industrialization in the study area, and a comparison analysis of the indicator with the four non-point source loads demonstrated that the chemical oxygen demand, total phosphorus and total nitrogen loads are linearly related to the immigrant population ratio. The results provide useful information for environmental improvement and city management in the study area.

Risk assessment and source analysis of soil heavy metal pollution from lower reaches of Yellow River irrigation in China.

PubMed

Zhang, Pengyan; Qin, Chengzhe; Hong, Xin; Kang, Guohua; Qin, Mingzhou; Yang, Dan; Pang, Bo; Li, Yanyan; He, Jianjian; Dick, Richard P

2018-08-15

The level of concentration of heavy metal in soil is detrimental to soil quality. The Heigangkou-Liuyuankou irrigation area in the lower-reach of Yellow River irrigation, as home to a large population and a major site to agricultural production, is vulnerable to heavy metal pollution. This study examined soil quality in Heigangkou-Liuyuankou irrigation areas of Kaifeng, China. Pollution in soil and potential risks introduced by heavy metal accumulation were assessed using Nemerow, Geoaccumulation, and Hakanson's ecological risk indices. Statistics and Geographic Information Systems (GIS) were used to model and present the spatiotemporal changes of the pollution sources and factors affecting the levels of pollution. The heavy metals found in the sampled soil are Cr, Ni, Cu, Zn, Cd, Pb, As, and Hg. Among them, Cd is more concentrated than the others. The southwestern region of the studied area confronts the most serious heavy metal pollution. There exist spatial disparities of low concentrations of different heavy metals in the study area. Hg and Cd are found to pose the highest potential ecological risks. However, their risk levels are not the same across the study area. Levels concentration of Ni, Cu, Zn, Cd, Pb, As, and Hg in soil are highly correlated. In combination, they post an additional threat to the ecological environment. Transportation, rural settlements, and water bodies are found to be the major sources of Cr, Ni, Cu, Zn, Cd, Pb, and Hg pollution in the soil; among the major sources, transportation is the most significant factor. Copyright © 2018 Elsevier B.V. All rights reserved.

Non-Point Source Pollutant Load Variation in Rapid Urbanization Areas by Remote Sensing, Gis and the L-THIA Model: A Case in Bao'an District, Shenzhen, China

NASA Astrophysics Data System (ADS)

Li, Tianhong; Bai, Fengjiao; Han, Peng; Zhang, Yuanyan

2016-11-01

Urban sprawl is a major driving force that alters local and regional hydrology and increases non-point source pollution. Using the Bao'an District in Shenzhen, China, a typical rapid urbanization area, as the study area and land-use change maps from 1988 to 2014 that were obtained by remote sensing, the contributions of different land-use types to NPS pollutant production were assessed with a localized long-term hydrologic impact assessment (L-THIA) model. The results show that the non-point source pollution load changed significantly both in terms of magnitude and spatial distribution. The loads of chemical oxygen demand, total suspended substances, total nitrogen and total phosphorus were affected by the interactions between event mean concentration and the magnitude of changes in land-use acreages and the spatial distribution. From 1988 to 2014, the loads of chemical oxygen demand, suspended substances and total phosphorus showed clearly increasing trends with rates of 132.48 %, 32.52 % and 38.76 %, respectively, while the load of total nitrogen decreased by 71.52 %. The immigrant population ratio was selected as an indicator to represent the level of rapid urbanization and industrialization in the study area, and a comparison analysis of the indicator with the four non-point source loads demonstrated that the chemical oxygen demand, total phosphorus and total nitrogen loads are linearly related to the immigrant population ratio. The results provide useful information for environmental improvement and city management in the study area.

Source Apportionment of Volatile Organic Compounds in an Urban Environment at the Yangtze River Delta, China.

PubMed

An, Junlin; Wang, Junxiu; Zhang, Yuxin; Zhu, Bin

2017-04-01

Volatile organic compounds (VOCs) were collected continuously during June-August 2013 and December 2013-February 2014 at an urban site in Nanjing in the Yangtze River Delta. The positive matrix factorization receptor model was used to analyse the sources of VOCs in different seasons. Eight and seven sources were identified in summer and winter, respectively. In summer and winter, the dominant sources of VOCs were vehicular emissions, liquefied petroleum gas/natural gas (LPG/NG) usage, solvent usage, biomass/biofuel burning, and industrial production. In summer, vehicular emissions made the most significant contribution to ambient VOCs (38%), followed by LPG/NG usage (20%), solvent usage (19%), biomass/biofuel burning (13%), and industrial production (10%). In winter, LPG/NG usage accounted for 36% of ambient VOCs, whereas vehicular emissions, biomass/biofuel burning, industrial production and solvent usage contributed 30, 18, 9, and 6%, respectively. The contribution of LPG/NG usage in winter was approximately four times that in summer, whereas the contribution from biomass/biofuel burning in winter was more than twice that in summer. The sources related to vehicular emissions and LPG/NG usages were important. Using conditional probability function analysis, the VOC sources were mainly associated with easterly, northeasterly and southeasterly directions, pointing towards the major expressway and industrial area. Using the propylene-equivalent method, paint and varnish (23%) was the highest source of VOCs in summer and biomass/biofuel burning (36%) in winter. Using the ozone formation potential method, the most important source was biomass/biofuel burning (32% in summer and 47% in winter). The result suggests that the biomass/biofuel burning and paint and varnish play important roles in controlling ozone chemical formation in Nanjing.

Fiber fermentability effects on energy and macronutrient digestibility, fecal traits, postprandial metabolite responses, and colon histology of overweight cats.

PubMed

Fischer, M M; Kessler, A M; de Sá, L R M; Vasconcellos, R S; Filho, F O Roberti; Nogueira, S P; Oliveira, M C C; Carciofi, A C

2012-07-01

Considering the different potential benefits of divergent fiber ingredients, the effect of 3 fiber sources on energy and macronutrient digestibility, fermentation product formation, postprandial metabolite responses, and colon histology of overweight cats (Felis catus) fed kibble diets was compared. Twenty-four healthy adult cats were assigned in a complete randomized block design to 2 groups of 12 animals, and 3 animals from each group were fed 1 of 4 of the following kibble diets: control (CO; 11.5% dietary fiber), beet pulp (BP; 26% dietary fiber), wheat bran (WB; 24% dietary fiber), and sugarcane fiber (SF; 28% dietary fiber). Digestibility was measured by the total collection of feces. After 16 d of diet adaptation and an overnight period without food, blood glucose, cholesterol, and triglyceride postprandial responses were evaluated for 16 h after continued exposure to food. On d 20, colon biopsies of the cats were collected under general anesthesia. Fiber addition reduced food energy and nutrient digestibility. Of all the fiber sources, SF had the least dietary fiber digestibility (P < 0.05), causing the largest reduction of dietary energy digestibility (P < 0.05). The greater fermentability of BP resulted in reduced fecal DM and pH, greater fecal production [g/(cat × d); as-is], and greater fecal concentration of acetate, propionate, and lactate (P < 0.05). For most fecal variables, WB was intermediate between BP and SF, and SF was similar to the control diet except for an increased fecal DM and firmer feces production for the SF diet (P < 0.05). Postprandial evaluations indicated reduced mean glucose concentration and area under the glucose curve in cats fed the SF diet (P < 0.05). Colon mucosa thickness, crypt area, lamina propria area, goblet cell area, crypt mean size, and crypt in bifurcation did not vary among the diets. According to the fiber solubility and fermentation rates, fiber sources can induce different physiological responses in cats, reduce energy digestibility, and favor glucose metabolism (SF), or improve gut health (BP).

Livestock feed resources utilization practices in Tanqua-Abergelle district of Tigray, Northern Ethiopia.

PubMed

Gebremariam, Tikabo; Belay, Shumuye

2016-08-01

A study was carried out with the objective to assess the utilization practices of local feed resources. It was implemented in Tanqua-Abergelle district of the Tigray region, Northern Ethiopia. Lemlem and Gera peasant associations (PAs) were selected purposively based on their potentiality in livestock resources and road access for household (HH) interview purpose. Likewise, Sheka-Tekli and Hadinet PAs were chosen for the purpose of focus group discussion (FGD). A total of 60 HHs (30 from each PA) were selected randomly for interview using semi-structured questionnaire. About 16 % of the respondents were female HHs. Two FGDs were held with key informants. The collected data were analyzed using SPSS (2013, version 21) statistical software procedures. The study area is characterized by mixed crop-livestock farming system with high interaction between crop and livestock. Livestock are the mainstay for the farm community with many benefits as sources of draught, meat, milk, income, and manures. Cattle are kept primarily for the purpose of draught power with meat and milk as secondary products, whereas shoats are kept mainly for cash income, manure, meat, and milk. The land holding size per HH was 1.44 ha while the herd size was 4.93 tropical livestock unit (TLU). Almost all the land holding (97 %) is allocated for crop cultivation with lesser for forage production (<1 %) indicating poor attention for fodder harvesting. The cattle herd is composed of local breeds (99 %) with less exotic/crossbred (1 %), indicating that the livestock rearing is practiced using local breed. Crop residues, natural pastures, stubble grazing, hay, and browsing are the main feed resources for animals. The availability and contribution of each feed vary with season and areas. Sorghum stover is the main feed source in the area and followed by maize stover, Eragrostis tef straw, and pulse straws. Crop residues are fed as basal diet with no or less supplementation using local concentrates like Attela and mill by-products. Industrial by-products are rarely used in the livestock feeding system for their high price and less availability. Likewise, improved forages are not widely utilized as feed sources.

Legal harvest and illegal trade: Trends, challenges, and options in khat production in Ethiopia.

PubMed

Cochrane, Logan; O'Regan, Davin

2016-04-01

The production of khat in Ethiopia has boomed over the last two decades, making the country the world's leading source. Khat is now one of Ethiopia's largest crops by area of cultivation, the country's second largest export earner, and an essential source of income for millions of Ethiopian farmers. Consumption has also spread from the traditional khat heartlands in the eastern and southern regions of Ethiopia to most major cities. This steady growth in production and use has unfolded under negligible government support or regulation. Meanwhile, khat, which releases a stimulant when chewed, is considered an illicit drug in an increasing number of countries. Drawing on government data on khat production, trade, and seizures as well as research on the political, socioeconomic, and development effects of plant-based illicit narcotics industries, this commentary identifies possible considerations and scenarios for Ethiopia as the country begins to manage rising khat production, domestic consumption, and criminalization abroad. Deeply embedded in social and cultural practices and a major source of government and agricultural revenue, Ethiopian policymakers have few enviable choices. Criminalization abroad raises a small but not insignificant possibility that previously nonexistent linkages between khat and transnational organized crime and trafficking networks will emerge. Likewise, more stringent regulation of khat in Ethiopia could merge with lingering political cleavages and anti-government sentiments, exacerbating low-level domestic conflicts. Copyright © 2016 Elsevier B.V. All rights reserved.

Noncontact analysis of the fiber weight per unit area in prepreg by near-infrared spectroscopy.

PubMed

Jiang, B; Huang, Y D

2008-05-26

The fiber weight per unit area in prepreg is an important factor to ensure the quality of the composite products. Near-infrared spectroscopy (NIRS) technology together with a noncontact reflectance sources has been applied for quality analysis of the fiber weight per unit area. The range of the unit area fiber weight was 13.39-14.14mgcm(-2). The regression method was employed by partial least squares (PLS) and principal components regression (PCR). The calibration model was developed by 55 samples to determine the fiber weight per unit area in prepreg. The determination coefficient (R(2)), root mean square error of calibration (RMSEC) and root mean square error of prediction (RMSEP) were 0.82, 0.092, 0.099, respectively. The predicted values of the fiber weight per unit area in prepreg measured by NIRS technology were comparable to the values obtained by the reference method. For this technology, the noncontact reflectance sources focused directly on the sample with neither previous treatment nor manipulation. The results of the paired t-test revealed that there was no significant difference between the NIR method and the reference method. Besides, the prepreg could be analyzed one time within 20s without sample destruction.

Effects of harvest, fire, and pest/pathogen disturbances on the West Cascades ecoregion carbon balance.

PubMed

Turner, David P; Ritts, William D; Kennedy, Robert E; Gray, Andrew N; Yang, Zhiqiang

2015-12-01

Disturbance is a key influence on forest carbon dynamics, but the complexity of spatial and temporal patterns in forest disturbance makes it difficult to quantify their impacts on carbon flux over broad spatial domains. Here we used a time series of Landsat remote sensing images and a climate-driven carbon cycle process model to evaluate carbon fluxes at the ecoregion scale in western Oregon. Thirteen percent of total forest area in the West Cascades ecoregion was disturbed during the reference interval (1991-2010). The disturbance regime was dominated by harvesting (59 % of all area disturbed), with lower levels of fire (23 %), and pest/pathogen mortality (18 %). Ecoregion total Net Ecosystem Production was positive (a carbon sink) in all years, with greater carbon uptake in relatively cool years. Localized carbon source areas were associated with recent harvests and fire. Net Ecosystem Exchange (including direct fire emissions) showed greater interannual variation and became negative (a source) in the highest fire years. Net Ecosystem Carbon Balance (i.e. change in carbon stocks) was more positive on public that private forestland, because of a lower disturbance rate, and more positive in the decade of the 1990s than in the warmer and drier 2000s because of lower net ecosystem production and higher direct fire emissions in the 2000s. Despite recurrent disturbances, the West Cascades ecoregion has maintained a positive carbon balance in recent decades. The high degree of spatial and temporal resolution in these simulations permits improved attribution of regional carbon sources and sinks.

Health, safety, and environmental risk assessment of steel production complex in central Iran using TOPSIS.

PubMed

Jozi, S A; Majd, N Moradi

2014-10-01

This research was carried out with the aim of presenting an environmental management plan for steel production complex (SPC) in central Iran. Following precise identification of the plant activities as well as the study area, possible sources of environmental pollution and adverse impacts on the air quality, water, soil, biological environment, socioeconomic and cultural environment, and health and safety of the employees were determined considering the work processes of the steel complex. Afterwards, noise, wastewater, and air pollution sources were measured. Subsequently, factors polluting the steel complex were identified by TOPSIS and then prioritized using Excel Software. Based on the obtained results, the operation of the furnaces in hot rolling process with the score 1, effluent derived from hot rolling process with the score 0.565, nonprincipal disposal and dumping of waste at the plant enclosure with the score 0.335, walking beam process with the score 1.483 respectively allocated themselves the highest priority in terms of air, water, soil and noise pollution. In terms of habitats, land cover and socioeconomic and cultural environment, closeness to the forest area and the existence of four groups of wildlife with the score 1.106 and proximity of villages and residential areas to the plant with the score 3.771 respectively enjoyed the highest priorities while impressibility and occupational accidents with the score 2.725 and cutting and welding operations with score 2.134 had the highest priority among health and safety criteria. Finally, strategies for the control of pollution sources were identified and Training, Monitoring and environmental management plan of the SPC was prepared.

Quality of groundwater resources in Afghanistan.

PubMed

Hayat, Ehsanullah; Baba, Alper

2017-07-01

Water is the main source of energy production and economy in Afghanistan where agriculture accounts for more than 50% of the country's gross domestic product (GDP). Access to safe drinking water is still a problem in the country, which has caused different health issues and even child mortality especially in rural areas. Groundwater is the main source of drinking water in the country. However, little knowledge is available about the quality of groundwater throughout the entire country, and its quality has not been investigated extensively yet like in other countries in the world. While most people think that consuming groundwater is a reliable and safe source of drinking water for health, the United Nations (UN) agencies report various kinds of waterborne diseases and even child mortalities due to drinking water quality in the country. In this article, significant geogenic and anthropogenic factors that play a vital role in groundwater contamination of the country are identified and explained. Different geogenic contaminations such as arsenic, fluoride, sulfate, and boron occur in several areas of Afghanistan that have a direct effect on human health. The water quality mapping for Afghanistan is completed for half of the country, which shows that groundwater is plagued by high levels of fluoride and arsenic in some areas. The water quality mapping of the other half of the country cannot be completed due to security concerns currently. Also, there are different kinds of waterborne diseases such as diarrhea, cholera, and dysentery that can be seen in different parts of the country because of anthropogenic activities which continuously deteriorate groundwater.

Historic Emissions from Deforestation and Forest Degradation in Mato Grosso, Brazil: 1. Source Data Uncertainties

NASA Technical Reports Server (NTRS)

Morton, Douglas C.; Sales, Marcio H.; Souza, Carlos M., Jr.; Griscom, Bronson

2011-01-01

Historic carbon emissions are an important foundation for proposed efforts to Reduce Emissions from Deforestation and forest Degradation and enhance forest carbon stocks through conservation and sustainable forest management (REDD+). The level of uncertainty in historic carbon emissions estimates is also critical for REDD+, since high uncertainties could limit climate benefits from mitigation actions. Here, we analyzed source data uncertainties based on the range of available deforestation, forest degradation, and forest carbon stock estimates for the Brazilian state of Mato Grosso during 1990-2008. Results: Deforestation estimates showed good agreement for multi-year trends of increasing and decreasing deforestation during the study period. However, annual deforestation rates differed by >20% in more than half of the years between 1997-2008, even for products based on similar input data. Tier 2 estimates of average forest carbon stocks varied between 99-192 Mg C/ha, with greatest differences in northwest Mato Grosso. Carbon stocks in deforested areas increased over the study period, yet this increasing trend in deforested biomass was smaller than the difference among carbon stock datasets for these areas. Conclusions: Patterns of spatial and temporal disagreement among available data products provide a roadmap for future efforts to reduce source data uncertainties for estimates of historic forest carbon emissions. Specifically, regions with large discrepancies in available estimates of both deforestation and forest carbon stocks are priority areas for evaluating and improving existing estimates. Full carbon accounting for REDD+ will also require filling data gaps, including forest degradation and secondary forest, with annual data on all forest transitions.

A conceptual framework for the sustainable management of wastewater in Harare, Zimbabwe.

PubMed

Nhapi, I; Gijzen, H J; Siebel, M A

2003-01-01

The aim of this study was to formulate an integrated wastewater management model for Harare, Zimbabwe, based on current thinking. This implies that wastewater is treated/disposed of as close to the source of generation as possible. Resource recovery and reuse in a local thriving urban agriculture are integrated into this model. Intervention strategies were considered for controlling water, nitrogen and phosphorus flows to the lake. In the formulation of strategies, Harare was divided into five major operational areas of high-, medium-, and low-density residential areas, and also commercial and industrial areas. Specific options were then considered to suit landuse, development constraints and socio-economic status for each area, within the overall criteria of limiting nutrient inflows into the downstream Lake Chivero. Flexible and differential solutions were developed in relation to built environment, population density, composition of users, ownership, future environmental demands, and technical, environmental, hygienic, social and organisational factors. Options considered include source control by the users (residents, industries, etc.), using various strategies like implementation of toilets with source separation, and natural methods of wastewater treatment. Other possible strategies are invoking better behaviour through fees and information, incentives for cleaner production, and user responsibility through education, legislative changes and stricter controls over industry.

Disruption of the nitrogen regulatory gene AcareA in Acremonium chrysogenum leads to reduction of cephalosporin production and repression of nitrogen metabolism.

PubMed

Li, Jinyang; Pan, Yuanyuan; Liu, Gang

2013-12-01

AcareA, encoding a homologue of the fungal nitrogen regulatory GATA zinc-finger proteins, was cloned from Acremonium chrysogenum. Gene disruption and genetic complementation revealed that AcareA was required for nitrogen metabolism and cephalosporin production. Disruption of AcareA resulted in growth defect in the medium using nitrate, uric acid and low concentration of ammonium, glutamine or urea as sole nitrogen source. Transcriptional analysis showed that the transcription of niaD/niiA was increased drastically when induced with nitrate in the wild-type and AcareA complemented strains but not in AcareA disruption mutant. Consistent with the reduction of cephalosporin production, the transcription of pcbAB, cefD2, cefEF and cefG encoding the enzymes for cephalosporin production was reduced in AcareA disruption mutant. Band shift assays showed that AcAREA bound to the promoter regions of niaD, niiA and the bidirectional promoter region of pcbAB-pcbC. Sequence analysis showed that all the AcAREA binding sites contain the consensus GATA elements. These results indicated that AcAREA plays an important role both in the regulation of nitrogen metabolism and cephalosporin production in A. chrysogenum. Copyright © 2013 Elsevier Inc. All rights reserved.

Identifying the origins of local atmospheric deposition in the steel industry basin of Luxembourg using the chemical and isotopic composition of the lichen Xanthoria parietina.

PubMed

Hissler, Christophe; Stille, Peter; Krein, Andreas; Geagea, Majdi Lahd; Perrone, Thierry; Probst, Jean-Luc; Hoffmann, Lucien

2008-11-01

Trace metal atmospheric contamination was assessed in one of the oldest European industrial sites of steel production situated in the southern part of the Grand-Duchy of Luxembourg. Using elemental ratios as well as Pb, Sr, and Nd isotopic compositions as tracers, we found preliminary results concerning the trace metal enrichment and the chemical/isotopic signatures of the most important emission sources using the lichen Xanthoria parietina sampled at 15 sites along a SW-NE transect. The concentrations of these elements decreased with increasing distance from the historical and actual steel-work areas. The combination of the different tracers (major elements, Rare Earth Element ratios, Pb, Sr and Nd isotopes) enabled us to distinguish between three principal sources: the historical steel production (old tailings corresponding to blast-furnace residues), the present steel production (industrial sites with arc electric furnace units) and the regional background (baseline) components. Other anthropogenic sources including a waste incinerator and major roads had only weak impacts on lichen chemistry and isotopic ratios. The correlation between the Sr and Nd isotope ratios indicated that the Sr-Nd isotope systems represented useful tools to trace atmospheric emissions of factories using scrap metal for steel production.

Desalination using low grade heat sources

NASA Astrophysics Data System (ADS)

Gude, Veera Gnaneswar

A new, low temperature, energy-efficient and sustainable desalination system has been developed in this research. This system operates under near-vacuum conditions created by exploiting natural means of gravity and barometric pressure head. The system can be driven by low grade heat sources such as solar energy or waste heat streams. Both theoretical and experimental studies were conducted under this research to evaluate and demonstrate the feasibility of the proposed process. Theoretical studies included thermodynamic analysis and process modeling to evaluate the performance of the process using the following alternate energy sources for driving the process: solar thermal energy, solar photovoltaic/thermal energy, geothermal energy, and process waste heat emissions. Experimental studies included prototype scale demonstration of the process using grid power as well as solar photovoltaic/thermal sources. Finally, the feasibility of the process in reclaiming potable-quality water from the effluent of the city wastewater treatment plant was studied. The following results have been obtained from theoretical analysis and modeling: (1) The proposed process can produce up to 8 L/d of freshwater for 1 m2 area of solar collector and evaporation chamber respectively with a specific energy requirement of 3122 kJ for 1 kg of freshwater production. (2) Photovoltaic/thermal (PV/T) energy can produce up to 200 L/d of freshwater with a 25 m2 PV/T module which meets the electricity needs of 21 kWh/d of a typical household as well. This configuration requires a specific energy of 3122 kJ for 1 kg of freshwater production. (3) 100 kg/hr of geothermal water at 60°C as heat source can produce up to 60 L/d of freshwater with a specific energy requirement of 3078 kJ for 1 kg of freshwater production. (4) Waste heat released from an air conditioning system rated at 3.25 kW cooling, can produce up to 125 L/d of freshwater. This configuration requires an additional energy of 208 kJ/kg of freshwater along with the waste heat released from the condenser of air-conditioning system. This additional energy requirement is about 60% of the energy required by a multi stage flash distillation process. The experimental studies were conducted in three phases. In the first phase, electric power from grid as energy source was used to demonstrate the feasibility of the proposed process. These tests showed that freshwater production rate of 0.25 kg/hr can be sustained at evaporation temperatures as low as 40°C with specific energy input of 3,370 kJ/kg, at efficiencies ranging from 65 to 70% during the winter. In the second phase, experiments were conducted utilizing direct solar thermal energy and photovoltaic energy as well. Four different combinations of energy sources were studied. The following results were obtained from these experimental studies: (1) Utilizing direct solar energy produced 4.9 L/d of freshwater with an evaporator area of 1 m2 with an average efficiency of 61%. This yield is two times that can be obtained from a flat solar still. The specific energy requirement for this configuration is 4157 kJ for production of 1 kilogram freshwater; (2) Utilizing direct solar energy with aid of a reflector produced 7.5 L/d of freshwater with an average efficiency more than 80%. The specific energy requirement for this configuration is 3118 kJ for production of 1 kilogram freshwater; (3) Utilizing direct solar energy during sunlight hours and photovoltaic energy during non-sunlight hours produced 12 L/d of freshwater with 1 m2 evaporator area and 6 m2 photovoltaic areas respectively. The specific energy requirement for this configuration is 2926 kJ for production of 1 kilogram freshwater. Finally, the feasibility of this process in reclaiming potable-quality water from the effluent of a domestic wastewater treatment plant was studied. The process was able to achieve the following reductions: total dissolved solids from 727 mg/L to 21 mg/L (97%); nitrates from 2.4 mg/L to <0.1 mg/L (> 95%); ammonia from 23.2 mg/L to < 0.5 mg/L (> 97%); and coliform from 77 to <0 mg/L (100%).

Sensitivities of NOx transformation and the effects on surface ozone and nitrate

NASA Astrophysics Data System (ADS)

Lei, H.; Wang, J. X. L.

2014-02-01

As precursors to tropospheric ozone and nitrate, nitrogen oxide (NOx) in the present atmosphere and its transformation in response to emission and climate perturbations are studied by using the CAM-Chem model and air quality measurements from the National Emissions Inventory (NEI), Clean Air Status and Trends Network (CASTNET), and Environmental Protection Agency Air Quality System (EPA AQS). It is found that NOx transformations in present atmospheric conditions show different sensitivities over industrial and non-industrial regions. As a result, the surface ozone and nitrate formations can be divided into several regimes associated with the dominant emission types and relative levels of NOx and volatile organic compounds (VOC). Ozone production in industrial regions (the main NOx emission source areas) increases in warmer conditions and slightly decreases following an increase in NOx emissions due to NOx titration, which is opposite to the response in non-industrial regions. The ozone decrease following a temperature increase in non-industrial regions indicates that ozone production in regions that lack NOx emission sources may be sensitive to NOx transformation in remote source regions. The increase in NO2 from NOx titration over industrial regions results in an increase rate of total nitrate that remains higher than the increase rate of NOx emissions. The presented findings indicate that a change in the ozone concentration is more directly affected by changes in climate and precursor emissions, while a change in the nitrate concentration is affected by local ozone production types and their seasonal transfer. The sensitivity to temperature perturbations shows that a warmer climate accelerates the decomposition of odd nitrogen (NOy) during the night. As a result, the transformation rate of NOx to nitrate decreases. Examinations of the historical emissions and air quality records of a typical NOx-limited area, such as Atlanta and a VOC-limited area, such as Los Angeles further confirm the conclusions drawn from the modeling experiments.

Chemical and biological tracers to determine groundwater flow in karstic aquifer, Yucatan Peninsula

NASA Astrophysics Data System (ADS)

Lenczewski, M.; Leal-Bautista, R. M.; McLain, J. E.

2013-05-01

Little is known about the extent of pollution in groundwater in the Yucatan Peninsula; however current population growth, both from international tourism and Mexican nationals increases the potential for wastewater release of a vast array of contaminants including personal care products, pharmaceuticals (Rx), and pathogenic microorganisms. Pathogens and Rx in groundwater can persist and can be particularly acute in this region where high permeability of the karst bedrock and the lack of top soil permit the rapid transport of contaminants into groundwater aquifers. The objective of this research is to develop and utilize novel biological and chemical source tracking methods to distinguish between different sources of anthropogenic pollution in degraded groundwater. Although several methods have been used successfully to track fecal contamination sources in small scale studies, little is known about their spatial limitations, as source tracking studies rarely include sample collection over a wide geographical area and with different sources of water. In addition, although source tracking methods to distinguish human from animal fecal contamination are widely available, this work has developed source tracking distinguish between separate human populations is highly unique. To achieve this objective, we collected water samples from a series of drinking wells, cenotes (sinkholes), wastewater treatment plants, and injection wells across the Yucatan Peninsula and examine potential source tracers within the collected water samples. The result suggests that groundwater sources impacted by tourist vs. local populations contain different chemical stressors. This work has developed a more detailed understanding of the presence and persistence of personal care products, pharmaceuticals, and fecal indicators in a karstic system; such understanding will be a vital component for the protection Mexican groundwater and human health. Quantification of different pollution sources within groundwater samples identified point sources of pollution, identify potential remediation strategies, and contribute to an improved understanding of the environmental impact of tourism and tourism-generated waste products on this groundwater-dependent ecosystem.

Bisphenol A emission factors from industrial sources and elimination rates in a sewage treatment plant.

PubMed

Fuerhacker, M

2003-01-01

Bisphenol A (BPA) is widely used for the production of epoxy resins and polycarbonate plastics and is considered an endocrine disruptor. Special in vitro test systems and animal experiments showed a weak estrogenic activity. Aquatic wildlife especially could be endangered by waste water discharges. To manage possible risks arising from BPA emissions the major fluxes need to be investigated and the sources of the contamination of municipal treatment plants need to be determined. In this study, five major industrial point sources, two different household areas and the influent and effluent of the corresponding treatment plant (WWTP) were monitored simultaneously at a plant serving 120,000 population equivalents. A paper producing plant was the major BPA contributor to the influent load of the wastewater treatment plant. All the other emissions from point sources, including the two household areas, were considerably lower. The minimum elimination rate in the WTTP could be determined at 78% with an average of 89% of the total BPA-load. For a possible pollution-forecast, or for a comparison between different point sources, emission factors based on COD-emissions were calculated for industrial and household point sources at BPA/COD-ratios between 1.4 x 10(-8) - 125 x 10(-8) and 1.3 x 10(-6) - 6.3 x 10(-6), respectively.

Case study on combined CO₂ sequestration and low-salinity water production potential in a shallow saline aquifer in Qatar.

PubMed

Ahmed, Tausif Khizar; Nasrabadi, Hadi

2012-10-30

CO₂ is one of the byproducts of natural gas production in Qatar. The high rate of natural gas production from Qatar's North Field (world's largest non-associated gas field) has led to the production of significant amounts of CO₂. The release of CO₂ into the atmosphere may be harmful from the perspective of global warming. In this work, we study the CO₂ sequestration potential in Qatar's Aruma aquifer. The Aruma aquifer is a saline aquifer in the southwest of Qatar. It occupies an area of approximately 1985 km₂ on land (16% of Qatar's total area). We have developed a compositional model for CO₂ sequestration in the Aruma aquifer on the basis of available log and flow test data. We suggest water production at some distance from the CO₂ injection wells as a possible way to control the pore pressure. This method increases the potential for safe sequestration of CO₂ in the aquifer without losing integrity of the caprock and without any CO₂ leakage. The water produced from this aquifer is considerably less saline than seawater and could be a good water source for the desalination process, which is currently the main source of water in Qatar. The outcome of the desalination process is water with higher salinity than the seawater that is currently discharged into the sea. This discharge can have negative long-term environmental effects. The water produced from the Aruma aquifer is considerably less saline than seawater and can be a partial solution to this problem. Copyright © 2012 Elsevier Ltd. All rights reserved.

Improving the environment in urban areas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adamkus, V.V.

1994-12-31

The author discusses the need for improvements to the environment in urban areas, and efforts being made under the direction of the Environmental Protection Agency (EPA) to address these problems. The impact the new Clean Air Act can have on emissions from gasoline powered autos, diesel burning trucks, fixed emission sources ranging from utilities to chemical plants, and consumer products like hair sprays and charcoal starters, will all work together to improve air quality in urban areas. The author also discusses Brownfields Economic Redevelopment Plan efforts being supported by the EPA in a coordinated plan to get municipalities involved inmore » cleaning up areas with pollution, to remove the blight on the urban areas, provide new land for development, and promote additional jobs.« less

The worldwide market for photovoltaics in the rural sector

NASA Technical Reports Server (NTRS)

Brainard, W. A.

1982-01-01

The worldwide market for stand-alone photovoltaic power systems in three specific segments of the rural sector were determined. The worldwide market for photovoltaic power systems for village power, cottage industry, and agricultural applications were addressed. The objectives of these studies were to: The market potential for small stand-alone photovoltaic power system in specific application areas was assessed. Technical, social and institutional barriers to PV utilization were identified. Funding sources available to potential users was also identified and marketing strategies appropriate for each sector were recommended to PV product manufacturers. The studies were prepared on the basis of data gathered from domestic sources and from field trips to representative countries. Both country-specific and sector-specific results are discussed, and broadly applicable barriers pertinent to international marketing of PV products are presented.

Sources, Ages, and Alteration of Organic Matter in Estuaries.

PubMed

Canuel, Elizabeth A; Hardison, Amber K

2016-01-01

Understanding the processes influencing the sources and fate of organic matter (OM) in estuaries is important for quantifying the contributions of carbon from land and rivers to the global carbon budget of the coastal ocean. Estuaries are sites of high OM production and processing, and understanding biogeochemical processes within these regions is key to quantifying organic carbon (Corg) budgets at the land-ocean margin. These regions provide vital ecological services, including nutrient filtration and protection from floods and storm surge, and provide habitat and nursery areas for numerous commercially important species. Human activities have modified estuarine systems over time, resulting in changes in the production, respiration, burial, and export of Corg. Corg in estuaries is derived from aquatic, terrigenous, and anthropogenic sources, with each source exhibiting a spectrum of ages and lability. The complex source and age characteristics of Corg in estuaries complicate our ability to trace OM along the river-estuary-coastal ocean continuum. This review focuses on the application of organic biomarkers and compound-specific isotope analyses to estuarine environments and on how these tools have enhanced our ability to discern natural sources of OM, trace their incorporation into food webs, and enhance understanding of the fate of Corg within estuaries and their adjacent waters.

Small lasers in flow cytometry.

PubMed

Telford, William G

2004-01-01

Laser technology has made tremendous advances in recent years, particularly in the area of diode and diode-pumped solid state sources. Flow cytometry has been a direct beneficiary of these advances, as these small, low-maintenance, inexpensive lasers with reasonable power outputs are integrated into flow cytometers. In this chapter we review the contribution and potential of solid-state lasers to flow cytometry, and show several examples of these novel sources integrated into production flow cytometers. Technical details and critical parameters for successful application of these lasers for biomedical analysis are reviewed.

Global mapping of sea-ice production from the satellite microwaves

NASA Astrophysics Data System (ADS)

Ohshima, K. I.; Nihashi, S.; Iwamoto, K.; Tamaru, N.; Nakata, K.; Tamura, T.

2016-12-01

Global overturning circulation is driven by density differences. Saline water rejected by sea-ice production in coastal polynyas is the main source of dense water, and thus sea-ice production is a key factor in the overturning circulation. However, until recently sea-ice production and its interannual variability have not been well understood due to difficulties of in situ observation. The most effective means of detection of thin-ice area and estimation of sea-ice production on large scales is satellite remote sensing using passive microwave sensors, specifically the Special Sensor Microwave/Imager and Advanced Microwave Scanning Radiometer. This is based upon their ability to gain complete polar coverage on a daily basis irrespective of clouds and darkness. We have estimated sea-ice production globally based on heat flux calculations using the satellite-derived thin ice thickness data. The mapping demonstrates that ice production rate is high in Antarctic coastal polynyas, in contrast to Arctic coastal polynyas. This is consistent with the formation of Antarctic Bottom Water (AABW). The Ross Ice Shelf polynya has by far the highest ice production in the Southern Hemisphere. The mapping has revealed that the Cape Darnley polynya is the second highest production area, leading to the discovery of the missing (fourth) source of AABW in this region. In the region off the Mertz Glacier Tongue, sea-ice production decreased by as much as 40 %, due to the glacier calving in early 2010, resulting in a significant decrease in AABW production. The Okhotsk Northwestern polynya exhibits the highest ice production in the Northern Hemisphere, and the resultant dense water formation leads to overturning in the North Pacific. Estimates of its ice production show a significant decrease over the past 30-50 years, likely causing the weakening of the North Pacific overturning. The mapping also provides surface boundary conditions and validation data of heat- and salt-flux associated with sea-ice formation/melting for various ocean and coupled models. Improvement of thin ice microwave algorithm including the comparison with the polynya mooring data is now being made for higher accuracy estimate of sea-ice production.

Atmospheric inversion of surface carbon flux with consideration of the spatial distribution of US crop production and consumption

DOE PAGES

Chen, J. M.; Fung, J. W.; Mo, G.; ...

2015-01-19

In order to improve quantification of the spatial distribution of carbon sinks and sources in the conterminous US, we conduct a nested global atmospheric inversion with detailed spatial information on crop production and consumption. County-level cropland net primary productivity, harvested biomass, soil carbon change, and human and livestock consumption data over the conterminous US are used for this purpose. Time-dependent Bayesian synthesis inversions are conducted based on CO₂ observations at 210 stations to infer CO₂ fluxes globally at monthly time steps with a nested focus on 30 regions in North America. Prior land surface carbon fluxes are first generated usingmore » a biospheric model, and the inversions are constrained using prior fluxes with and without adjustments for crop production and consumption over the 2002–2007 period. After these adjustments, the inverted regional carbon sink in the US Midwest increases from 0.25 ± 0.03 to 0.42 ± 0.13 Pg C yr⁻¹, whereas the large sink in the US southeast forest region is weakened from 0.41 ± 0.12 to 0.29 ± 0.12 Pg C yr⁻¹. These adjustments also reduce the inverted sink in the west region from 0.066 ± 0.04 to 0.040 ± 0.02 Pg C yr⁻¹ because of high crop consumption and respiration by humans and livestock. The general pattern of sink increases in crop production areas and sink decreases (or source increases) in crop consumption areas highlights the importance of considering the lateral carbon transfer in crop products in atmospheric inverse modeling, which provides a reliable atmospheric perspective of the overall carbon balance at the continental scale but is unreliable for separating fluxes from different ecosystems.« less

Biological research survey for the efficient conversion of biomass to biofuels.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kent, Michael Stuart; Andrews, Katherine M.

2007-01-01

The purpose of this four-week late start LDRD was to assess the current status of science and technology with regard to the production of biofuels. The main focus was on production of biodiesel from nonpetroleum sources, mainly vegetable oils and algae, and production of bioethanol from lignocellulosic biomass. One goal was to assess the major technological hurdles for economic production of biofuels for these two approaches. Another goal was to compare the challenges and potential benefits of the two approaches. A third goal was to determine areas of research where Sandia's unique technical capabilities can have a particularly strong impactmore » in these technologies.« less

Evaluation of available saline water resources in New Mexico for the production of microalgae

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lansford, R.; Hernandez, J.; Enis, P.

Researchers evaluated saline water resources in New Mexico for their suitability as sites for large-scale microalgae production facilities. Production of microalgae could provide a renewable source of fuel, chemicals, and food. In addition, making use of the unused saline water resources would increase the economic activity in the state. After analyzing the 15 billion acre-ft of unused saline water resources in the state, scientists narrowed the locations down to six sites with the most potential. With further analysis, they chose the Tularosa Basin in southern New Mexico as the best-suited area for 100-hectare microalgae production facility. 34 refs., 38 figs.,more » 14 tabs.« less

A Review of Land-Cover Mapping Activities in Coastal Alabama and Mississippi

USGS Publications Warehouse

Smith, Kathryn E.L.; Nayegandhi, Amar; Brock, John C.

2010-01-01

INTRODUCTION Land-use and land-cover (LULC) data provide important information for environmental management. Data pertaining to land-cover and land-management activities are a common requirement for spatial analyses, such as watershed modeling, climate change, and hazard assessment. In coastal areas, land development, storms, and shoreline modification amplify the need for frequent and detailed land-cover datasets. The northern Gulf of Mexico coastal area is no exception. The impact of severe storms, increases in urban area, dramatic changes in land cover, and loss of coastal-wetland habitat all indicate a vital need for reliable and comparable land-cover data. Four main attributes define a land-cover dataset: the date/time of data collection, the spatial resolution, the type of classification, and the source data. The source data are the foundation dataset used to generate LULC classification and are typically remotely sensed data, such as aerial photography or satellite imagery. These source data have a large influence on the final LULC data product, so much so that one can classify LULC datasets into two general groups: LULC data derived from aerial photography and LULC data derived from satellite imagery. The final LULC data can be converted from one format to another (for instance, vector LULC data can be converted into raster data for analysis purposes, and vice versa), but each subsequent dataset maintains the imprint of the source medium within its spatial accuracy and data features. The source data will also influence the spatial and temporal resolution, as well as the type of classification. The intended application of the LULC data typically defines the type of source data and methodology, with satellite imagery being selected for large landscapes (state-wide, national data products) and repeatability (environmental monitoring and change analysis). The coarse spatial scale and lack of refined land-use categories are typical drawbacks to satellite-based land-use classifications. Aerial photography is typically selected for smaller landscapes (watershed-basin scale), for greater definition of the land-use categories, and for increased spatial resolution. Disadvantages of using photography include time-consuming digitization, high costs for imagery collection, and lack of seasonal data. Recently, the availability of high-resolution satellite imagery has generated a new category of LULC data product. These new datasets have similar strengths to the aerial-photo-based LULC in that they possess the potential for refined definition of land-use categories and increased spatial resolution but also have the benefit of satellite-based classifications, such as repeatability for change analysis. LULC classification based on high-resolution satellite imagery is still in the early stages of development but merits greater attention because environmental-monitoring and landscape-modeling programs rely heavily on LULC data. This publication summarizes land-use and land-cover mapping activities for Alabama and Mississippi coastal areas within the U.S. Geological Survey (USGS) Northern Gulf of Mexico (NGOM) Ecosystem Change and Hazard Susceptibility Project boundaries. Existing LULC datasets will be described, as well as imagery data sources and ancillary data that may provide ground-truth or satellite training data for a forthcoming land-cover classification. Finally, potential areas for a high-resolution land-cover classification in the Alabama-Mississippi region will be identified.

A GIS analysis of suitability for construction aggregate recycling sites using regional transportation network and population density features

USGS Publications Warehouse

Robinson, G.R.; Kapo, K.E.

2004-01-01

Aggregate is used in road and building construction to provide bulk, strength, support, and wear resistance. Reclaimed asphalt pavement (RAP) and reclaimed Portland cement concrete (RPCC) are abundant and available sources of recycled aggregate. In this paper, current aggregate production operations in Virginia, Maryland, and the District of Columbia are used to develop spatial association models for the recycled aggregate industry with regional transportation network and population density features. The cost of construction aggregate to the end user is strongly influenced by the cost of transporting processed aggregate from the production site to the construction site. More than 60% of operations recycling aggregate in the mid-Atlantic study area are located within 4.8 km (3 miles) of an interstate highway. Transportation corridors provide both sites of likely road construction where aggregate is used and an efficient means to move both materials and on-site processing equipment back and forth from various work sites to the recycling operations. Urban and developing areas provide a high market demand for aggregate and a ready source of construction debris that may be processed into recycled aggregate. Most aggregate recycling operators in the study area are sited in counties with population densities exceeding 77 people/km2 (200 people/mile 2). No aggregate recycling operations are sited in counties with less than 19 people/km2 (50 people/mile2), reflecting the lack of sufficient long-term sources of construction debris to be used as an aggregate source, as well as the lack of a sufficient market demand for aggregate in most rural areas to locate a recycling operation there or justify the required investment in the equipment to process and produce recycled aggregate. Weights of evidence analyses (WofE), measuring correlation on an area-normalized basis, and weighted logistic regression (WLR), are used to model the distribution of RAP and RPCC operations relative to transportation network and population distribution data. The models can be used on a regional scale to quickly map the relative site suitability for a RAP or RPCC aggregate recycling operation in a particular area based on transportation network and population parameters. The results can be used to identify general areas to be further evaluated on a site-specific basis using more detailed marketplace information. As transportation or population features change due to planning or actual development, the models can be easily revised to reflect these changes. ?? 2004 Elsevier B.V. All rights reserved.

A Systems Framework for Assessing Plumbing Products-Related Water Conservation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Williams, Alison; Dunham Whitehead, Camilla; Lutz, James

2011-12-02

Reducing the water use of plumbing products—toilets, urinals, faucets, and showerheads —has been a popular conservation measure. Improved technologies have created opportunities for additional conservation in this area. However, plumbing products do not operate in a vacuum. This paper reviews the literature related to plumbing products to determine a systems framework for evaluating future conservation measures using these products. The main framework comprises the following categories: water use efficiency, product components, product performance, source water, energy, and plumbing/sewer infrastructure. This framework for analysis provides a starting point for professionals considering future water conservation measures to evaluate the need for additionalmore » research, collaboration with other standards or codes committees, and attachment of additional metrics to water use efficiency (such as performance).« less

Biomarkers in Natural Fish Populations Indicate Adverse Biological Effects of Offshore Oil Production

PubMed Central

Balk, Lennart; Hylland, Ketil; Hansson, Tomas; Berntssen, Marc H. G.; Beyer, Jonny; Jonsson, Grete; Melbye, Alf; Grung, Merete; Torstensen, Bente E.; Børseth, Jan Fredrik; Skarphedinsdottir, Halldora; Klungsøyr, Jarle

2011-01-01

Background Despite the growing awareness of the necessity of a sustainable development, the global economy continues to depend largely on the consumption of non-renewable energy resources. One such energy resource is fossil oil extracted from the seabed at offshore oil platforms. This type of oil production causes continuous environmental pollution from drilling waste, discharge of large amounts of produced water, and accidental spills. Methods and principal findings Samples from natural populations of haddock (Melanogrammus aeglefinus) and Atlantic cod (Gadus morhua) in two North Sea areas with extensive oil production were investigated. Exposure to and uptake of polycyclic aromatic hydrocarbons (PAHs) were demonstrated, and biomarker analyses revealed adverse biological effects, including induction of biotransformation enzymes, oxidative stress, altered fatty acid composition, and genotoxicity. Genotoxicity was reflected by a hepatic DNA adduct pattern typical for exposure to a mixture of PAHs. Control material was collected from a North Sea area without oil production and from remote Icelandic waters. The difference between the two control areas indicates significant background pollution in the North Sea. Conclusion It is most remarkable to obtain biomarker responses in natural fish populations in the open sea that are similar to the biomarker responses in fish from highly polluted areas close to a point source. Risk assessment of various threats to the marine fish populations in the North Sea, such as overfishing, global warming, and eutrophication, should also take into account the ecologically relevant impact of offshore oil production. PMID:21625421

Biomarkers in natural fish populations indicate adverse biological effects of offshore oil production.

PubMed

Balk, Lennart; Hylland, Ketil; Hansson, Tomas; Berntssen, Marc H G; Beyer, Jonny; Jonsson, Grete; Melbye, Alf; Grung, Merete; Torstensen, Bente E; Børseth, Jan Fredrik; Skarphedinsdottir, Halldora; Klungsøyr, Jarle

2011-01-01

Despite the growing awareness of the necessity of a sustainable development, the global economy continues to depend largely on the consumption of non-renewable energy resources. One such energy resource is fossil oil extracted from the seabed at offshore oil platforms. This type of oil production causes continuous environmental pollution from drilling waste, discharge of large amounts of produced water, and accidental spills. Samples from natural populations of haddock (Melanogrammus aeglefinus) and Atlantic cod (Gadus morhua) in two North Sea areas with extensive oil production were investigated. Exposure to and uptake of polycyclic aromatic hydrocarbons (PAHs) were demonstrated, and biomarker analyses revealed adverse biological effects, including induction of biotransformation enzymes, oxidative stress, altered fatty acid composition, and genotoxicity. Genotoxicity was reflected by a hepatic DNA adduct pattern typical for exposure to a mixture of PAHs. Control material was collected from a North Sea area without oil production and from remote Icelandic waters. The difference between the two control areas indicates significant background pollution in the North Sea. It is most remarkable to obtain biomarker responses in natural fish populations in the open sea that are similar to the biomarker responses in fish from highly polluted areas close to a point source. Risk assessment of various threats to the marine fish populations in the North Sea, such as overfishing, global warming, and eutrophication, should also take into account the ecologically relevant impact of offshore oil production.

Geographical Distribution and Sources of Nutrients in Atmospheric Aerosol Over the Pacific Ocean

NASA Astrophysics Data System (ADS)

Uematsu, M.

2016-12-01

The Pacific Ocean, the world's largest (occupying about 30% of the Earth's total surface area) has several distinguishing biogeochemical features. In the western Pacific, dust particles originating from arid and semi-arid regions in Asia and Australia are transported to the north and south, respectively. Biomass burning emissions from Southeast Asia are exported to the tropical Pacific, and anthropogenic substances flowing out of Asia and Eurasia spread both regionally and globally. Over high primary productive areas such as the subarctic North Pacific, the equatorial Pacific and the Southern Ocean, biogenic gasses are released to the atmosphere and transported to other areas. These processes may affect cloud and rainfall patterns, air quality, and the radiative balance of downwind regions. The deposition of atmospheric aerosols containing iron and other essential nutrients is important for biogeochemical cycles in the oceans because this source of nutrients helps sustain primary production and affects food-web structure; these effects in turn influence the chemical properties of marine atmosphere. From an atmospheric chemistry standpoint, sea-salt aerosols produced by strong winds and marine biogenic gases emitted from highly productive waters affect the physicochemical characteristics of marine aerosols. As phytoplankton populations are patchy and atmospheric processes sporadic, the interactions between atmospheric chemical constituents and marine biota vary for different regions as well as seasonally and over longer timescales. To address these and other emerging issues, and more generally to better understand the important biogeochemical processes and interactions occurring over the open oceans, more long-term recurrent research cruises with standardized atmospheric shipboard measurements will be needed in the future.

Competing English, Spanish, and French alabaster trade in Europe over five centuries as evidenced by isotope fingerprinting

PubMed Central

Kloppmann, W.; Leroux, L.; Bromblet, P.; Le Pogam, P.-Y.; Cooper, A. H.; Worley, N.; Guerrot, C.; Montech, A. T.; Gallas, A. M.; Aillaud, R.

2017-01-01

A lack of written sources is a serious obstacle in the reconstruction of the medieval trade of art and art materials, and in the identification of artists, workshop locations, and trade routes. We use the isotopes of sulfur, oxygen, and strontium (S, O, Sr) present in gypsum alabaster to unambiguously link ancient European source quarries and areas to alabaster artworks produced over five centuries (12th–17th) held by the Louvre museum in Paris and other European and American collections. Three principal alabaster production areas are identified, in central England, northern Spain, and a major, long-lived but little-documented alabaster trade radiating from the French Alps. The related trade routes are mostly fluvial, although terrestrial transport crossing the major river basin borders is also confirmed by historical sources. Our study also identifies recent artwork restoration using Italian alabaster and provides a robust geochemical framework for provenancing, including recognition of restoration and forgeries. PMID:29078309

Modeling measured glottal volume velocity waveforms.

PubMed

Verneuil, Andrew; Berry, David A; Kreiman, Jody; Gerratt, Bruce R; Ye, Ming; Berke, Gerald S

2003-02-01

The source-filter theory of speech production describes a glottal energy source (volume velocity waveform) that is filtered by the vocal tract and radiates from the mouth as phonation. The characteristics of the volume velocity waveform, the source that drives phonation, have been estimated, but never directly measured at the glottis. To accomplish this measurement, constant temperature anemometer probes were used in an in vivo canine constant pressure model of phonation. A 3-probe array was positioned supraglottically, and an endoscopic camera was positioned subglottically. Simultaneous recordings of airflow velocity (using anemometry) and glottal area (using stroboscopy) were made in 3 animals. Glottal airflow velocities and areas were combined to produce direct measurements of glottal volume velocity waveforms. The anterior and middle parts of the glottis contributed significantly to the volume velocity waveform, with less contribution from the posterior part of the glottis. The measured volume velocity waveforms were successfully fitted to a well-known laryngeal airflow model. A noninvasive measured volume velocity waveform holds promise for future clinical use.

Competing English, Spanish, and French alabaster trade in Europe over five centuries as evidenced by isotope fingerprinting.

PubMed

Kloppmann, W; Leroux, L; Bromblet, P; Le Pogam, P-Y; Cooper, A H; Worley, N; Guerrot, C; Montech, A T; Gallas, A M; Aillaud, R

2017-11-07

A lack of written sources is a serious obstacle in the reconstruction of the medieval trade of art and art materials, and in the identification of artists, workshop locations, and trade routes. We use the isotopes of sulfur, oxygen, and strontium (S, O, Sr) present in gypsum alabaster to unambiguously link ancient European source quarries and areas to alabaster artworks produced over five centuries (12th-17th) held by the Louvre museum in Paris and other European and American collections. Three principal alabaster production areas are identified, in central England, northern Spain, and a major, long-lived but little-documented alabaster trade radiating from the French Alps. The related trade routes are mostly fluvial, although terrestrial transport crossing the major river basin borders is also confirmed by historical sources. Our study also identifies recent artwork restoration using Italian alabaster and provides a robust geochemical framework for provenancing, including recognition of restoration and forgeries. Copyright © 2017 the Author(s). Published by PNAS.

Competing English, Spanish, and French alabaster trade in Europe over five centuries as evidenced by isotope fingerprinting

NASA Astrophysics Data System (ADS)

Kloppmann, W.; Leroux, L.; Bromblet, P.; Le Pogam, P.-Y.; Cooper, A. H.; Worley, N.; Guerrot, C.; Montech, A. T.; Gallas, A. M.; Aillaud, R.

2017-11-01

A lack of written sources is a serious obstacle in the reconstruction of the medieval trade of art and art materials, and in the identification of artists, workshop locations, and trade routes. We use the isotopes of sulfur, oxygen, and strontium (S, O, Sr) present in gypsum alabaster to unambiguously link ancient European source quarries and areas to alabaster artworks produced over five centuries (12th–17th) held by the Louvre museum in Paris and other European and American collections. Three principal alabaster production areas are identified, in central England, northern Spain, and a major, long-lived but little-documented alabaster trade radiating from the French Alps. The related trade routes are mostly fluvial, although terrestrial transport crossing the major river basin borders is also confirmed by historical sources. Our study also identifies recent artwork restoration using Italian alabaster and provides a robust geochemical framework for provenancing, including recognition of restoration and forgeries.

PM sources in a highly industrialised area in the process of implementing PM abatement technology. Quantification and evolution.

PubMed

Cruz Minguillón, María; Querol, Xavier; Alastuey, Andrés; Monfort, Eliseo; Vicente Miró, José

2007-10-01

Principal component analysis (PCA) coupled with a multilinear regression analysis (MLRA) was applied to PM(10) speciation data series (2002-2005) from four sampling sites in a highly industrialised area (ceramic production) in the process of implementing emission abatement technology. Five common factors with similar chemical profiles were identified at all the sites: mineral, regional background (influenced by the industrial estate located on the coast: an oil refinery and a power plant), sea spray, industrial 1 (manufacture and use of glaze components, including frit fusion) and road traffic. The contribution of the regional background differs slightly from site to site. The mineral factor, attributed to the sum of several sources (mainly the ceramic industry, but also with minor contributions from soil resuspension and African dust outbreaks) contributes between 9 and 11 microg m(-3) at all the sites. Source industrial 1 entails an increase in PM(10) levels between 4 and 5 microg m(-3) at the urban sites and 2 microg m(-3) at the suburban background site. However, after 2004, this source contributed less than 2 microg m(-3) at most sites, whereas the remaining sources did not show an upward or downward trend along the study period. This gradual decrease in the contribution of source industrial 1 coincides with the implementation of PM abatement technology in the frit fusion kilns of the area. This relationship enables us to assess the efficiency of the implementation of environmental technologies in terms of their impact on air quality.

Source Apportionment of VOCs in Edmonton, Alberta

NASA Astrophysics Data System (ADS)

McCarthy, M. C.; Brown, S. G.; Aklilu, Y.; Lyder, D. A.

2012-12-01

Regional emissions at Edmonton, Alberta, are complex, containing emissions from (1) transportation sources, such as cars, trucks, buses, and rail; (2) industrial sources, such as petroleum refining, light manufacturing, and fugitive emissions from holding tanks or petroleum terminals; and (3) miscellaneous sources, such as biogenic emissions and natural gas use and processing. From 2003 to 2009, whole air samples were collected at two sites in Edmonton and analyzed for over 77 volatile organic compounds (VOCs). VOCs were sampled in the downtown area (Central) and the industrial area on the eastern side of the city (East). Concentrations of most VOCs were highest at the East site. The positive matrix factorization (PMF) receptor model was used to apportion ambient concentration measurements of VOCs into eleven factors, which were associated with emissions source categories. Factors of VOCs identified in the final eleven-factor solution include transportation sources (both gasoline and diesel vehicles), industrial sources, a biogenic source, and a natural-gas-related source. Transportation sources accounted for more mass at the Central site than at the East site; this was expected because Central is in a core urban area where transportation emissions are concentrated. Transportation sources accounted for nearly half of the VOC mass at the Central site, but only 6% of the mass at the East site. Encouragingly, mass from transportation sources has declined by about 4% a year in this area; this trend is similar to the decline found throughout the United States, and is likely due to fleet turnover as older, more highly polluting cars are replaced with newer, cleaner cars. In contrast, industrial sources accounted for ten times more VOC mass at the East site than at the Central site and were responsible for most of the total VOC mass observed at the East site. Of the six industrial factors identified at the East site, four were linked to petrochemical industry production and storage. The two largest contributors to VOC mass at the East site were associated with fugitive emissions of volatile species (butanes, pentanes, hexane, and cyclohexane); together, these two factors accounted for more than 50% of the mass at the East site and less than 2% of the mass at the Central site. Natural-gas-related emissions accounted for 10% to 20% of the mass at both sites. Biogenic emissions and VOCs associated with well-mixed global background were less than 10% of the VOC mass at the Central site and less than 3% of the mass at the East site. Controllable emissions sources account for the bulk of the identified VOC mass. Efforts to reduce ozone or particulate matter precursors or exposure to toxic pollutants can now be directed to those sources most important to the Edmonton area.

40 CFR 412.33 - Effluent limitations attainable by the application of the best available technology economically...

Code of Federal Regulations, 2012 CFR

2012-07-01

... application of the best available technology economically achievable (BAT). 412.33 Section 412.33 Protection... economically achievable (BAT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source... BAT: (a) For CAFO production areas: the CAFO shall attain the same limitations and requirements as...

40 CFR 412.33 - Effluent limitations attainable by the application of the best available technology economically...

Code of Federal Regulations, 2014 CFR

2014-07-01

... application of the best available technology economically achievable (BAT). 412.33 Section 412.33 Protection... economically achievable (BAT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source... BAT: (a) For CAFO production areas: the CAFO shall attain the same limitations and requirements as...

40 CFR 412.33 - Effluent limitations attainable by the application of the best available technology economically...

Code of Federal Regulations, 2010 CFR

2010-07-01

... application of the best available technology economically achievable (BAT). 412.33 Section 412.33 Protection... economically achievable (BAT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source... BAT: (a) For CAFO production areas: the CAFO shall attain the same limitations and requirements as...

40 CFR 412.33 - Effluent limitations attainable by the application of the best available technology economically...

Code of Federal Regulations, 2011 CFR

2011-07-01

... application of the best available technology economically achievable (BAT). 412.33 Section 412.33 Protection... economically achievable (BAT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source... BAT: (a) For CAFO production areas: the CAFO shall attain the same limitations and requirements as...

40 CFR 412.33 - Effluent limitations attainable by the application of the best available technology economically...

Code of Federal Regulations, 2013 CFR

2013-07-01

... application of the best available technology economically achievable (BAT). 412.33 Section 412.33 Protection... economically achievable (BAT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source... BAT: (a) For CAFO production areas: the CAFO shall attain the same limitations and requirements as...

Research on the ecology and management of Micronesian mangroves

Treesearch

J.A. Allen

1999-01-01

Mangroves are a vitally important natural resource on the high islands of Micronesia. This importance is especially valid in the Federated States of Micronisa (FSM) and the Republic of Palau, where mangroves cover 10-15% of the total land area and are used heavily by islanders as sources of wood, crabs, fish, thatching material, and other products.

CONFIRMING THE RESULTS: AN ACCURACY ASSESSMENT OF REMOTE PRODUCTS, AN EXAMPLE COMPARING MULTIPLE MID-ATLANTIC SUB-PIXEL IMPERVIOUS SURFACE MAPS

EPA Science Inventory

Anthropogenic impervious surfaces have an important relationship with non-point source pollution (NPS) in urban watersheds. The amount of impervious surface area in a watershed is a key indicator of landscape change. As a single variable, it serves to intcgrate a number of concur...

Physiological and molecular analysis of selected Kenyan maize lines for aluminum tolerance

USDA-ARS?s Scientific Manuscript database

Aluminum (Al) toxicity is an important limitation to maize production in many tropical and sub-tropical acid soil areas. The aim of this study was to survey the variation in Al tolerance in a panel of maize lines adapted for Kenya and look for novel sources of Al tolerance. 112 Kenyan maize accessio...

Evaluating sediment production by activities related to forest uses--a northwest perspective

Treesearch

Robert R. Ziemer; Thomas E. Lisle

1993-01-01

To deal with nonpoint sources of pollution, such as stream sediment produced by erosion from forest management operations, regulations require land managers to reduce onsite erosion to keep the amount of sediment discharged from each project area within acceptable limits. Activities developed to meet these regulations are sometimes referred to as best management...

Carbon footprint of urban source separation for nutrient recovery.

PubMed

Kjerstadius, H; Bernstad Saraiva, A; Spångberg, J; Davidsson, Å

2017-07-15

Source separation systems for the management of domestic wastewater and food waste has been suggested as more sustainable sanitation systems for urban areas. The present study used an attributional life cycle assessment to investigate the carbon footprint and potential for nutrient recovery of two sanitation systems for a hypothetical urban area in Southern Sweden. The systems represented a typical Swedish conventional system and a possible source separation system with increased nutrient recovery. The assessment included the management chain from household collection, transport, treatment and final return of nutrients to agriculture or disposal of the residuals. The results for carbon footprint and nutrient recovery (phosphorus and nitrogen) concluded that the source separation system could increase nutrient recovery (0.30-0.38 kg P capita -1 year -1 and 3.10-3.28 kg N capita -1 year -1 ), while decreasing the carbon footprint (-24 to -58 kg CO 2 -eq. capita -1 year -1 ), compared to the conventional system. The nutrient recovery was increased by the use of struvite precipitation and ammonium stripping at the wastewater treatment plant. The carbon footprint decreased, mainly due to the increased biogas production, increased replacement of mineral fertilizer in agriculture and less emissions of nitrous oxide from wastewater treatment. In conclusion, the study showed that source separation systems could potentially be used to increase nutrient recovery from urban areas, while decreasing the climate impact. Copyright © 2017 Elsevier Ltd. All rights reserved.

Sources of fine sediment stored in agricultural lowland streams, Midwest, USA

NASA Astrophysics Data System (ADS)

Lamba, Jasmeet; Thompson, A. M.; Karthikeyan, K. G.; Fitzpatrick, Faith A.

2015-05-01

Agricultural activities can accelerate the offsite transport of productive soil from fields leading to stream water quality degradation. Identification of the nature and relative contribution of different sources to fine-grained sediment (e.g., silts, clays) in streams is important to effectively focus agricultural best management practices in watersheds. Sediment fingerprinting techniques through the use of geochemical tracers are commonly used to differentiate relative contribution from various sources. Research was conducted in lowland streams in the Pleasant Valley watershed in South Central Wisconsin (USA) to identify provenance of fine-grained sediment deposits and evaluate the impact of land use on relative contributions from the following potential sources: cropland, pasture, woodland, and eroding stream banks. Results show that both agriculture (croplands and pastures) and eroding stream banks are primary sources to fine sediment deposits on the stream bed with contributions ranging from 19 to 100% and 0 to 81%, respectively. The increase in area under agricultural land use within a subwatershed results in greater contribution from agriculture (R2 = 0.846, p = 0.0034). Relative contributions from eroding stream banks increased with increasing area under grasslands and woodlands within a subwatershed (R2 = 0.814, p = 0.0055). Subwatersheds with greater mass of fine sediment deposited on the stream bed per unit area should be prioritized for best management practices. The conservation practices should be targeted to stream banks or croplands depending on the dominant source of fine sediment within a subwatershed. Site specific changes in relative contributions from different sources to fine-grained sediment in this watershed highlights the complexities involved in sediment transport dynamics. The nested sampling sites helped determine that sediment dynamics at the subwatershed scale need to be considered for application of targeted conservation techniques.

Sources of fine sediment stored in agricultural lowland streams, Midwest, USA

USGS Publications Warehouse

Lamba, Jasmeet; Thompson, Anita M.; Karthikeyan, K.G.; Fitzpatrick, Faith A.

2015-01-01

Agricultural activities can accelerate the offsite transport of productive soil from fields leading to stream water quality degradation. Identification of the nature and relative contribution of different sources to fine-grained sediment (e.g., silts, clays) in streams is important to effectively focus agricultural best management practices in watersheds. Sediment fingerprinting techniques through the use of geochemical tracers are commonly used to differentiate relative contribution from various sources. Research was conducted in lowland streams in the Pleasant Valley watershed in South Central Wisconsin (USA) to identify provenance of fine-grained sediment deposits and evaluate the impact of land use on relative contributions from the following potential sources: cropland, pasture, woodland, and eroding stream banks. Results show that both agriculture (croplands and pastures) and eroding stream banks are primary sources to fine sediment deposits on the stream bed with contributions ranging from 19 to 100% and 0 to 81%, respectively. The increase in area under agricultural land use within a subwatershed results in greater contribution from agriculture (R2 = 0.846, p = 0.0034). Relative contributions from eroding stream banks increased with increasing area under grasslands and woodlands within a subwatershed (R2 = 0.814, p = 0.0055). Subwatersheds with greater mass of fine sediment deposited on the stream bed per unit area should be prioritized for best management practices. The conservation practices should be targeted to stream banks or croplands depending on the dominant source of fine sediment within a subwatershed. Site specific changes in relative contributions from different sources to fine-grained sediment in this watershed highlights the complexities involved in sediment transport dynamics. The nested sampling sites helped determine that sediment dynamics at the subwatershed scale need to be considered for application of targeted conservation techniques.

Improvement of a Global High-Resolution Ammonia Emission Inventory for Combustion and Industrial Sources with New Data from the Residential and Transportation Sectors.

PubMed

Meng, Wenjun; Zhong, Qirui; Yun, Xiao; Zhu, Xi; Huang, Tianbo; Shen, Huizhong; Chen, Yilin; Chen, Han; Zhou, Feng; Liu, Junfeng; Wang, Xinming; Zeng, Eddy Y; Tao, Shu

2017-03-07

There is increasing evidence indicating the critical role of ammonia (NH 3 ) in the formation of secondary aerosols. Therefore, high quality NH 3 emission inventory is important for modeling particulate matter in the atmosphere. Unfortunately, without directly measured emission factors (EFs) in developing countries, using data from developed countries could result in an underestimation of these emissions. A series of newly reported EFs for China provide an opportunity to update the NH 3 emission inventory. In addition, a recently released fuel consumption data product has allowed for a multisource, high-resolution inventory to be assembled. In this study, an improved global NH 3 emission inventory for combustion and industrial sources with high sectorial (70 sources), spatial (0.1° × 0.1°), and temporal (monthly) resolutions was compiled for the years 1960 to 2013. The estimated emissions from transportation (1.59 Tg) sectors in 2010 was 2.2 times higher than those of previous reports. The spatial variation of the emissions was associated with population, gross domestic production, and temperature. Unlike other major air pollutants, NH 3 emissions continue to increase, even in developed countries, which is likely caused by an increased use of biomass fuel in the residential sector. The emissions density of NH 3 in urban areas is an order of magnitude higher than in rural areas.

Potential Influence of Climate-Induced Vegetation Shifts on Future Land Use and Associated Land Carbon Fluxes in Northern Eurasia

NASA Astrophysics Data System (ADS)

Kicklighter, D. W.; Cai, Y.; Zhuang, Q.; Parfenova, E. I.; Paltsev, S.; Sokolov, A. P.; Melillo, J. M.; Reilly, J. M.; Tchebakova, N. M.; Lu, X.

2014-12-01

Climate change will alter ecosystem metabolism and may lead to a redistribution of vegetation and changes in fire regimes in Northern Eurasia over the 21st century. Land management decisions will interact with these climate-driven changes to reshape the region's landscape. Here we present an assessment of the potential consequences of climate change on land use and associated land carbon sink activity for Northern Eurasia in the context of climate-induced vegetation shifts. Under a 'business-as-usual' scenario, climate-induced vegetation shifts allow expansion of areas devoted to food crop production (15%) and pastures (39%) over the 21st century. Under a climate stabilization scenario, climate-induced vegetation shifts permit expansion of areas devoted to cellulosic biofuel production (25%) and pastures (21%), but reduce the expansion of areas devoted to food crop production by 10%. In both climate scenarios, vegetation shifts further reduce the areas devoted to timber production by 6-8% over this same time period. Fire associated with climate-induced vegetation shifts causes the region to become more of a carbon source than if no vegetation shifts occur. Consideration of the interactions between climate-induced vegetation shifts and human activities through a modeling framework has provided clues to how humans may be able to adapt to a changing world and identified the tradeoffs, including unintended consequences, associated with proposed climate/energy policies.

Economic effects of immigrants on native and foreign-born workers: complementarity, substitutability, and other channels of influence.

PubMed

Greenwood, M J; Hunt, G L

1995-04-01

The authors use Standard Metropolitan Statistical Area (SMSA) data constructed from 1980 census microdata files and other sources to estimate a structural model of native/foreign-born labor demand and labor supply which distinguishes the effects upon real wages of each type of labor and on the employment of natives. The authors specify, econometrically estimate, and simulate the structural model which incorporates not only a production structure channel through which immigrants influence area real wages and employment, but also demand and native labor supply channels. It is noted that while these are not the only channels through which immigrants may affect native workers, the model nonetheless constitutes a step in the direction of a general equilibrium approach. In the production structure channel, immigrants and natives are found to be substitutes in production. Immigration lowers foreign-born wage rates and leads to lower wages for natives. The negative effects of the production channel usually are ameliorated through the demand channel. Further, immigrants add to local demand through their earnings and potentially through non-labor income, while also lowering unit costs and local prices which enhances real incomes and potentially net exports, and thus the demands for local output and area labor. The author discusses findings of interest from the simulation results based upon an analysis of all areas.

Fusion Geographic Information System Data with State-of-the-art Atmospheric Systems: Application to Methane Source Mapping over the Marcellus Shale formation

NASA Astrophysics Data System (ADS)

Cao, Y.; Barkley, Z.; Cervone, G.; Lauvaux, T.; Deng, A.; Sarmiento, D. P.

2015-12-01

Natural gas production from multiple shale formations has increased significantly in the last decade. More particularly, a growing number of unconventional wells is the result of intense drilling in the Marcellus shale area. The Marcellus shale production represents a third of the production of natural gas in the entire US. This unprecedented increase could lead to additional fugitive methane (CH4) emissions at a level that remains highly uncertain. If natural gas is to replace less energy-efficient fossil fuels, the emissions during the production phase ought to be relatively small. However, the magnitude and the spatial distribution of CH4 emissions from unconventional wells in the Marcellus shale remains poorly documented. The novelty of this research consists in coupling various sources of information to map accurately the methane emissions, combining Geographical Information System (GIS) data, atmospheric measurements of greenhouse gases, and atmospheric modeling tools. We first collected various GIS data to estimate CH4 emissions caused by the shale gas industry, such as wells, facilities, and pipelines, with the other major contributors such as wetlands, farming activities, and soils. We present our projection methods to generate model input in gridded format while preserving the distribution and magnitude of the emissions and assembling a diverse database. The projection tools for GIS data are generalized to the use of GIS data in atmospheric modeling systems. We then present the atmospheric concentrations simulated by the Weather Research and Forecast (WRF) model, used to represent the transport and the dispersion of CH4 emissions. We compare the WRF model results to aircraft measurements collected during a 3-week campaign to identify missing sources in our initial inventory. We finally propose a new approach to identify the area at the surface that could potentially influence the aircraft measurements using spatial analysis of particle footprints. This technique aims at identifying undocumented sources and unreported large emitters to quantify more rigorously the emissions of CH4 over the Marcellus shale.

Denali Ice Core MSA: A Record of North Pacific Primary Productivity

NASA Astrophysics Data System (ADS)

Polashenski, D.; Osterberg, E. C.; Winski, D.; Kreutz, K. J.; Wake, C. P.; Ferris, D. G.; Introne, D.; Campbell, S. W.

2017-12-01

The high nutrient, low chlorophyll region of the North Pacific is one of the most biologically productive marine ecosystems in the world and forms the basis of commercial, sport, and subsistence fisheries worth more than a billion dollars annually. Marine phytoplankton prove to be important both as the primary producers in these ecosystems and as a major source of biogenic sulfur emissions which have long been hypothesized to serve as a biological control on Earth's climate system. Despite their importance, the record of marine phytoplankton abundance and the flux of biogenic sulfur from these regions is not well constrained. In situ measurements of marine phytoplankton from oceanographic cruises over the past several decades are limited in both spatial and temporal resolution. Meanwhile, marine sediment records may provide insight on million year timescales, but lack decadal resolution due to slow sediment deposition rates and bioturbation. In this study, we aim to investigate changes in marine phytoplankton productivity of the northeastern subarctic Pacific Ocean (NSPO) over the twentieth century using the methanesulfonic acid (MSA) record from the Mt. Hunter ice cores drilled in Denali National Park, Alaska. These parallel, 208 meter long ice cores were drilled during the 2013 field season on the Mt. Hunter plateau (63° N, 151° W, 4,000 m above sea level). Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) modeling is used to identify likely source areas in the NSPO for MSA being transported to the core site. SeaWiFS satellite imagery allows for a direct comparison of chlorophyll a concentrations in these source areas with MSA concentrations in the core record through time. Our findings suggest that the Denali ice core MSA record reflects changes in the biological productivity of marine phytoplankton and shows a significant decline in MSA beginning in 1961. We investigate several hypotheses for potential mechanisms driving this MSA decline including iron limitation from windblown dust, copper toxicity, phytoplankton speciation change, and a change in moisture source using additional chemical records from the Denali ice core.

Predators

USGS Publications Warehouse

Young, Donald D.; McCabe, Thomas R.; Ambrose, Robert E.; Garner, Gerald W.; Weiler, Greg J.; Reynolds, Harry V.; Udevitz, Mark S.; Reed, Dan J.; Griffith, Brad; Douglas, David C.; Reynolds, Patricia E.; Rhode, E.B.

2002-01-01

Calving caribou (Rangifer tarandus) of the Central Arctic herd, Alaska, have avoided the infrastructure associated with the complex of petroleum development areas from Prudhoe Bay to Kuparuk (Cameron et al. 1992, Nellemann and Cameron 1998, and Section 4 of this document). Calving females of the Porcupine caribou herd may similarly avoid any oil field roads and pipelines developed in areas traditionally used during the calving and post-calving periods. This may displace the caribou females and calves to areas east and south of the 1002 Area of the Arctic National Wildlife Refuge.Increased calf mortality could occur if calving caribou are displaced into areas that have a higher density of predators, higher rates of predation, or where a higher proportion of the predators regularly use caribou as a food source (Whitten et al. 1992).Our study assessed predation risks to caribou calving in the 1002 Area versus calving in potential displacement areas. Due to funding constraints, our research focused on grizzly bears (Ursus arctos), with wolves (Camus lupus) and golden eagles (Aquila chrysaetos) receiving only cursory attention. Our research objectives were 1) to compare relative abundance of predators within the 1002 Area with that in adjacent peripheral areas, 2) to determine factors affecting predator abundance on the calving grounds, and 3) to quantify the use of caribou as a food source for predators and the importance of caribou to the productivity of predator populations using the coastal plain of the Arctic National Wildlife Refuge.

Organic matter sources and rehabilitation of the Sacramento-San Joaquin Delta (California, USA)

USGS Publications Warehouse

Jassby, A.D.; Cloern, J.E.

2000-01-01

1. The Sacramento San Joaquin River Delta, a complex mosaic of tidal freshwater habitats in California, is the focus of a major ecosystem rehabilitation effort because of significant long-term changes in critical ecosystem functions. One of these functions is the production, transport and transformation of organic matter that constitutes the primary food supply, which may be sub-optimal at trophic levels supporting fish recruitment. A long historical data set is used to define the most important organic matter sources, the factors underlying their variability, and the implications of ecosystem rehabilitation actions for these sources. 2. Tributary-borne loading is the largest organic carbon source on an average annual Delta-wide basis; phytoplankton production and agricultural drainage are secondary; wastewater treatment plant discharge, tidal marsh drainage and possibly aquatic macrophyte production are tertiary; and benthic microalgal production, urban run-off and other sources are negligible. 3. Allochthonous dissolved organic carbon must be converted to particulate form - with losses due to hydraulic flushing and to heterotroph growth inefficiency - before it becomes available to the metazoan food web. When these losses are accounted for, phytoplankton production plays a much larger role than is evident from a simple accounting of bulk organic carbon sources, especially in seasons critical for larval development and recruitment success. Phytoplankton-derived organic matter is also an important component of particulate loading to the Delta. 4. The Delta is a net producer of organic matter in critically dry years but, because of water diversion from the Delta, transport of organic matter from the Delta to important, downstream nursery areas in San Francisco Bay is always less than transport into the Delta from upstream sources. 5. Of proposed rehabilitation measures, increased use of floodplains probably offers the biggest increase in organic matter sources. 6. An isolated diversion facility - channelling water from the Sacramento River around the Delta to the water projects - would result in substantial loading increases during winter and autumn, but little change in spring and summer when food availability probably matters most to developing organisms. 7. Flow and fish barriers in the channel could have significant effects, especially on phytoplankton sources and in dry years, by eliminating 'short-circuits' in the transport of organic matter to diversion points. 8. Finally, productivity of intentionally flooded islands probably would exceed that of adjacent channels because of lower turbidity and shallower mean depth, although vascular plants rather than phytoplankton could dominate if depths were too shallow. Copyright (C) 2000 John Wiley and Sons, Ltd.

Synthetic biology strategies toward heterologous phytochemical production.

PubMed

Kotopka, Benjamin J; Li, Yanran; Smolke, Christina D

2018-06-13

Covering: 2006 to 2018Phytochemicals are important sources for the discovery and development of agricultural and pharmaceutical compounds, such as pesticides and medicines. However, these compounds are typically present in low abundance in nature, and the biosynthetic pathways for most phytochemicals are not fully elucidated. Heterologous production of phytochemicals in plant, bacterial, and yeast hosts has been pursued as a potential approach to address sourcing issues associated with many valuable phytochemicals, and more recently has been utilized as a tool to aid in the elucidation of plant biosynthetic pathways. Due to the structural complexity of certain phytochemicals and the associated biosynthetic pathways, reconstitution of plant pathways in heterologous hosts can encounter numerous challenges. Synthetic biology approaches have been developed to address these challenges in areas such as precise control over heterologous gene expression, improving functional expression of heterologous enzymes, and modifying central metabolism to increase the supply of precursor compounds into the pathway. These strategies have been applied to advance plant pathway reconstitution and phytochemical production in a wide variety of heterologous hosts. Here, we review synthetic biology strategies that have been recently applied to advance complex phytochemical production in heterologous hosts.

Fusarium species-a promising tool box for industrial biotechnology.

PubMed

Pessôa, Marina Gabriel; Paulino, Bruno Nicolau; Mano, Mario Cezar Rodrigues; Neri-Numa, Iramaia Angélica; Molina, Gustavo; Pastore, Glaucia Maria

2017-05-01

Global demand for biotechnological products has increased steadily over the years. Thus, need for optimized processes and reduced costs appear as a key factor in the success of this market. A process tool of high importance is the direct or indirect use of enzymes to catalyze the generation of various substances. Also, obtaining aromas and pigments from natural sources has becoming priority in cosmetic and food industries in order to supply the demand from consumers to substitute synthetic compounds, especially when by-products can be used as starting material for this purpose. Species from Fusarium genera are recognized as promising sources of several enzymes for industrial application as well as biocatalysts in the production of aromas, pigments and second generation biofuels, among others. In addition, secondary metabolites from these strains can present important biological activities for medical field. In this approach, this review brings focus on the use of Fusarium sp. strains in biotechnological production of compounds of industrial interest, showing the most recent researches in this area, results obtained and the best process conditions for each case.

Algal-Based Renewable Energy for Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fritsen, Christian

2017-03-31

To help in the overall evaluation of the potential for growing algal biomass in high productivity systems, we conducted a study that evaluated water from geothermal sources and cultivated mixed consortia from hot springs in Nevada, we evaluated their growth at moderately high varying temperatures and then evaluated potential manipulations that could possibly increase their biomass and oleaginous production. Studies were conducted at scales ranging from the laboratory benchtop to raceways in field settings. Mixed consortia were readily grown at all scales and growth could be maintained in Nevada year round. Moderate productivities were attained even during the shoulder seasons-more » where temperature control was maintained by hot water and seasonally cold temperatures when there was still plentiful solar radiation. The results enhance the prospects for economic feasibility of developing algal based industries in areas with geothermal energy or even other large alternative sources of heat that are not being used for other purposes. The public may benefit from such development as a means for economic development as well as development of industries for alternative energy and products that do not rely on fossil fuels.« less

The SPES surface ionization source

NASA Astrophysics Data System (ADS)

Manzolaro, M.; D'Agostini, F.; Monetti, A.; Andrighetto, A.

2017-09-01

Ion sources and target systems play a crucial role in isotope separation on line facilities, determining the main characteristics of the radioactive ion beams available for experiments. In the context of the selective production of exotic species (SPES) facility, a 40 MeV, 200 μA proton beam directly impinges a uranium carbide target, generating approximately 1013 fissions per second. The radioactive isotopes produced by the 238U fissions are delivered to the 1+ ion source by means of a tubular transfer line. Here they can be ionized and subsequently accelerated toward the experimental areas. In this work, the characterization of the surface ionization source currently adopted for the SPES facility is presented, taking as a reference ionization efficiency and transversal emittance measurements. The effects of long term operation at high temperature are also illustrated and discussed.

Joint Interpretation of Bathymetric and Gravity Anomaly Maps Using Cross and Dot-Products.

NASA Astrophysics Data System (ADS)

Jilinski, Pavel; Fontes, Sergio Luiz

2010-05-01

0.1 Summary We present the results of joint map interpretation technique based on cross and dot-products applied to bathymetric and gravity anomaly gradients maps. According to the theory (Gallardo, Meju, 2004) joint interpretation of different gradient characteristics help to localize and empathize patterns unseen on one image interpretation and gives information about the correlation of different spatial data. Values of angles between gradients and their cross and dot-product were used. This technique helps to map unseen relations between bathymetric and gravity anomaly maps if they are analyzed separately. According to the method applied for the southern segment of Eastern-Brazilian coast bathymetrical and gravity anomaly gradients indicates a strong source-effect relation between them. The details of the method and the obtained results are discussed. 0.2 Introduction We applied this method to investigate the correlation between bathymetric and gravity anomalies at the southern segment of the Eastern-Brazilian coast. Gridded satellite global marine gravity data and bathymetrical data were used. The studied area is located at the Eastern- Brazilian coast between the 20° W and 30° W meridians and 15° S and 25° S parallels. The volcanic events responsible for the uncommon width of the continental shelf at the Abrolhos bank also were responsible for the formation of the Abrolhos islands and seamounts including the major Vitoria-Trindade chain. According to the literature this volcanic structures are expected to have a corresponding gravity anomaly (McKenzie, 1976, Zembruscki, S.G. 1979). The main objective of this study is to develop and test joint image interpretation method to compare spatial data and analyze its relations. 0.3 Theory and Method 0.3.1 Data sources The bathymetrical satellite data were derived bathymetry 2-minute grid of the ETOPO2v2 obtained from NOAA's National Geophysical Data Center (http://www.ngdc.noaa.gov). The satellite marine gravity 1-minute gridded data were obtained from the Satellite Geodesy at the Scripps Institution of Oceanography, Smith & Sandwell (1997; http://topex.ucsd.edu. Gravity anomaly data were re-gridded using the ETOPO2v2 grid. All calculations and maps were made using MatLab 2007 software. 0.3.2 Cross-Product Cross-product is the result of multiplication of bathymetric and gravity anomaly gradient magnitudes by the sine of the angle between them. According to the definition of gradient cross-product minimal values are expected to be found in points where the angle between gradients is close to zero or where one or both of the gradient magnitudes have values close to zero. It creates an ambiguity and a problem for data interpretation since there is no exact correspondence between bathymetric structures and gravity anomalies. 0.3.3 Dot-Product Dot-product is the result of multiplication of bathymetric and gravity anomaly magnitudes by the cosine on the angle between them. According to the definition of dot-product, values close to zero can be generated by near perpendicular orientation of the gradients or small magnitudes of one or both gradients. So, the results are mutually increased in areas with larger magnitudes or smaller angles between gradients. Due to this mutual amplification dot-products are less affected by the ambiguity of cross-product explained above. The same statistical separation of cross-product was used to support the conclusions. 0.3.4 Statistics and Significance Criteria Statistical analysis was made in order to sort the data into two groups to reduce ambiguity effect: first group - data with magnitudes that could be considered anomalous (where the main minimizing source is the angle between the gradients and the second group - data with magnitudes variations that could be considered as (non significant or background (where cross-product value is determined by the small magnitude). It was chosen to use the mean value and standard deviation (std) to sort the data in such two groups. These values were determined for bathymetric and gravity anomaly gradient magnitudes creating two data sets - one where one or both gradient magnitudes are one standard deviation larger than the mean value with a total of 7831 (anomalous) and a second one where both magnitudes differ smaller than one standard deviation from the mean value with 85584 (background ). Statistical analysis of distribution patterns for both groups was made. 0.4 Examples of Method Application 0.4.1 Map of Angles Between Gradients Figure 1 shows the map of angle values. The angle values were divided into 4 equal intervals. The statistical distribution of angles between gradient in the given intervals is the following (percents of the total): 0 to 60° - 51.39% of the values; 60° to 90° -12.08%; 90° to 120° -14.92%; 120° to 180° -21.18%. It can be seen that 51% of the gradients have a small angle between them, 72% of gradients can be considered as parallel (72%) with angles smaller than 60° or bigger than 120° between them. After statistical separation in the anomalous group almost 91% of the gradients have an angle smaller than 60° while in the background group just 48.6%. From these results we can make a conclusion that the majority of the bathymetric and gravity anomaly gradients are related. Regions with higher gradient magnitudes are characterized by cosine values close to 1 (indicating a small angle between them). The size of the areas characterized by small angles between gradients exceed the size of bathymetric and gravity anomaly isolines characterizing the area of influence of the structures and their effects. Regions with no significant anomalies show uncorrelated value spots. 0.4.2 Map of Cross-Product The resulting map shows small spots of higher cross-product magnitudes following magnitude isolines. About 90% of the values are close to minimum. As was mentioned before, we can presume that areas where bathymetry and gravity anomaly gradient cross-products have smallest magnitudes there is a good correspondence between them indicating a good correspondence between shapes. According to these results for the studied area the shapes and positions of bathymetric structures and gravity anomalies are well correlated suggesting strong correlation between source and its effect. 0.4.3 Map of Dot-Product The resulting map resembles bathymetric and gravity anomaly isolines. All the sea mounts, banks, continental slope and other notable geomorphologic structures and gravity anomalies are well delimitated in the dot-product map eliminating uncorrelated areas where gradient orientations can be considered as near perpendicular. The dot-product map of the studied area suggests a strong source-effect between bathymetry and gravity anomaly. 0.5 Conclusions The joint image interpretation technique uses three different criteria that are sensitive to different gradient properties. Angles between gradients are a good indicator of areas where data are related and it is not sensitive to the magnitudes of the gradients. Angles maps can be used to find areas with direct and inverse relation between mapped properties and contour areas of influence of anomalies unseen on gradient magnitude maps alone. Statistical measures of distribution of angles can be an indicator of relation between data sets as show using significance criteria. Cross-product map has a spotted character of contours. To reduce the effects of the ambiguity the separation into two groups proved to be useful. It helps to separate the cross-product values that are minimized due to gradient magnitudes from those that minimize due to sine values which is a measure of correlation between them. Dot-product values contour areas where gradients are correlated. According to joint image interpretation technique applied bathymetric structures especially the volcanic seamounts and banks in the southern part of East-Brazilian Coast are closely related to the observed gravity anomalies and can be interpreted as sources and effect. This technique also helps to evaluate the shape and dispersion of the gravitational effect from a bathymetrical source. 0.6 References Dehlinger P., Marine Gravity, Elsevier, 1978. Gallardo, L. A., and M. A. Meju., Joint 2D cross-gradient imaging of magnetotelluric and seismic travel-time data for structural and lithological classification, Geophys. J. Int., 169, 1261-1272. (2007) Gallardo, L.A., M. A. Meju (2004), Joint two-dimensional dc resistivity and seismic traveltime inversion with cross-gradients constraints, J. Geophys. Res., 109, B03311, doi:10.1029/2003JB002716 Jacoby, W., and Smilde P. L., Gravity Interpretation, Springer, 2009. McKenzie D. & Bowin C. 1976. The relationship between bathymetry and gravity in Atlantic Ocean. Journal of Geophysical Research, 81: 1903-1915. Roy. K. K., Potential Theory in Applied Geophysics, Springer, 2008. Smith, W. H. F., and D. T. Sandwell, Global seafloor topography from satellite altimetry and ship depth soundings, Science, v. 277, p. 1957-1962, 26 Sept., 1997. Sandwell, D. T., and W. H. F. Smith, Global marine gravity from retracked Geosat and ERS-1 altimetry: Ridge Segmentation versus spreading rate, J. Geophys. Res., 114, B01411, doi:10.1029/2008JB006008, 2009. Zembruscki, S.G. 1979. Geomorfologia da Margem Continental Sul Brasileira e das Bacias Oceânicas Adjacentes. In: Geomorfologia da margem continental brasileira e das áreas oceânicas adjacentes. Série Projeto REMAC, N° 7.

Allergen manufacturing and quality aspects for allergen immunotherapy in Europe and the United States: An analysis from the EAACI AIT Guidelines Project.

PubMed

Bonertz, A; Roberts, G; Slater, J E; Bridgewater, J; Rabin, R L; Hoefnagel, M; Timon, M; Pini, C; Pfaar, O; Sheikh, A; Ryan, D; Akdis, C; Goldstein, J; Poulsen, L K; van Ree, R; Rhyner, C; Barber, D; Palomares, O; Pawankar, R; Hamerlijnk, D; Klimek, L; Agache, I; Angier, E; Casale, T; Fernandez-Rivas, M; Halken, S; Jutel, M; Lau, S; Pajno, G; Sturm, G; Varga, E M; Gerth van Wijk, R; Bonini, S; Muraro, A; Vieths, S

2018-04-01

Adequate quality is essential for any medicinal product to be eligible for marketing. Quality includes verification of the identity, content and purity of a medicinal product in combination with a specified production process and its control. Allergen products derived from natural sources require particular considerations to ensure adequate quality. Here, we describe key aspects of the documentation on manufacturing and quality aspects for allergen immunotherapy products in the European Union and the United States. In some key parts, requirements in these areas are harmonized while other fields are regulated separately between both regions. Essential differences are found in the use of Reference Preparations, or the requirement to apply standardized assays for potency determination. As the types of products available are different in specific regions, regulatory guidance for such products may also be available in one specific region only, such as for allergoids in the European Union. Region-specific issues and priorities are a result of this. As allergen products derived from natural sources are inherently variable in their qualitative and quantitative composition, these products present special challenges to balance the variability and ensuring batch-to-batch consistency. Advancements in scientific knowledge on specific allergens and their role in allergic disease will consequentially find representation in future regulatory guidelines. © 2017 EAACI and John Wiley and Sons A/S. Published by John Wiley and Sons Ltd.

SAR/multispectral image fusion for the detection of environmental hazards with a GIS

NASA Astrophysics Data System (ADS)

Errico, Angela; Angelino, Cesario Vincenzo; Cicala, Luca; Podobinski, Dominik P.; Persechino, Giuseppe; Ferrara, Claudia; Lega, Massimiliano; Vallario, Andrea; Parente, Claudio; Masi, Giuseppe; Gaetano, Raffaele; Scarpa, Giuseppe; Amitrano, Donato; Ruello, Giuseppe; Verdoliva, Luisa; Poggi, Giovanni

2014-10-01

In this paper we propose a GIS-based methodology, using optical and SAR remote sensing data, together with more conventional sources, for the detection of small cattle breeding areas, potentially responsible of hazardous littering. This specific environmental problem is very relevant for the Caserta area, in southern Italy, where many small buffalo breeding farms exist which are not even known to the productive activity register, and are not easily monitored and surveyed. Experiments on a test area, with available specific ground truth, prove that the proposed systems is characterized by very large detection probability and negligible false alarm rate.

High-resolution atmospheric emission inventory of the argentine energy sector. Comparison with edgar global emission database.

PubMed

Puliafito, S Enrique; Allende, David G; Castesana, Paula S; Ruggeri, Maria F

2017-12-01

This study presents a 2014 high-resolution spatially disaggregated emission inventory (0.025° × 0.025° horizontal resolution), of the main activities in the energy sector in Argentina. The sub-sectors considered are public generation of electricity, oil refineries, cement production, transport (maritime, air, rail and road), residential and commercial. The following pollutants were included: greenhouse gases (CO 2 , CH 4 , N 2 O), ozone precursors (CO, NOx, VOC) and other specific air quality indicators such as SO 2 , PM10, and PM2.5. This work could contribute to a better geographical allocation of the pollutant sources through census based population maps. Considering the sources of greenhouse gas emissions, the total amount is 144 Tg CO2eq, from which the transportation sector emits 57.8 Tg (40%); followed by electricity generation, with 40.9 Tg (28%); residential + commercial, with 31.24 Tg (22%); and cement and refinery production, with 14.3 Tg (10%). This inventory shows that 49% of the total emissions occur in rural areas: 31% in rural areas of medium population density, 13% in intermediate urban areas and 7% in densely populated urban areas. However, if emissions are analyzed by extension (per square km), the largest impact is observed in medium and densely populated urban areas, reaching more than 20.3 Gg per square km of greenhouse gases, 297 Mg/km 2 of ozone precursors gases and 11.5 Mg/km 2 of other air quality emissions. A comparison with the EDGAR global emission database shows that, although the total country emissions are similar for several sub sectors and pollutants, its spatial distribution is not applicable to Argentina. The road and residential transport emissions represented by EDGAR result in an overestimation of emissions in rural areas and an underestimation in urban areas, especially in more densely populated areas. EDGAR underestimates 60 Gg of methane emissions from road transport sector and fugitive emissions from refining activities.

Vegetation productivity patterns at high northern latitudes: a multi-sensor satellite data assessment.

PubMed

Guay, Kevin C; Beck, Pieter S A; Berner, Logan T; Goetz, Scott J; Baccini, Alessandro; Buermann, Wolfgang

2014-10-01

Satellite-derived indices of photosynthetic activity are the primary data source used to study changes in global vegetation productivity over recent decades. Creating coherent, long-term records of vegetation activity from legacy satellite data sets requires addressing many factors that introduce uncertainties into vegetation index time series. We compared long-term changes in vegetation productivity at high northern latitudes (>50°N), estimated as trends in growing season NDVI derived from the most widely used global NDVI data sets. The comparison included the AVHRR-based GIMMS-NDVI version G (GIMMSg ) series, and its recent successor version 3g (GIMMS3g ), as well as the shorter NDVI records generated from the more modern sensors, SeaWiFS, SPOT-VGT, and MODIS. The data sets from the latter two sensors were provided in a form that reduces the effects of surface reflectance associated with solar and view angles. Our analysis revealed large geographic areas, totaling 40% of the study area, where all data sets indicated similar changes in vegetation productivity over their common temporal record, as well as areas where data sets showed conflicting patterns. The newer, GIMMS3g data set showed statistically significant (α = 0.05) increases in vegetation productivity (greening) in over 15% of the study area, not seen in its predecessor (GIMMSg ), whereas the reverse was rare (<3%). The latter has implications for earlier reports on changes in vegetation activity based on GIMMSg , particularly in Eurasia where greening is especially pronounced in the GIMMS3g data. Our findings highlight both critical uncertainties and areas of confidence in the assessment of ecosystem-response to climate change using satellite-derived indices of photosynthetic activity. Broader efforts are required to evaluate NDVI time series against field measurements of vegetation growth, primary productivity, recruitment, mortality, and other biological processes in order to better understand ecosystem responses to environmental change over large areas. © 2014 The Authors. Global Change Biology Published by John Wiley & Sons Ltd.

Vegetation productivity patterns at high northern latitudes: a multi-sensor satellite data assessment

PubMed Central

Guay, Kevin C; Beck, Pieter S A; Berner, Logan T; Goetz, Scott J; Baccini, Alessandro; Buermann, Wolfgang

2014-01-01

Satellite-derived indices of photosynthetic activity are the primary data source used to study changes in global vegetation productivity over recent decades. Creating coherent, long-term records of vegetation activity from legacy satellite data sets requires addressing many factors that introduce uncertainties into vegetation index time series. We compared long-term changes in vegetation productivity at high northern latitudes (>50°N), estimated as trends in growing season NDVI derived from the most widely used global NDVI data sets. The comparison included the AVHRR-based GIMMS-NDVI version G (GIMMSg) series, and its recent successor version 3g (GIMMS3g), as well as the shorter NDVI records generated from the more modern sensors, SeaWiFS, SPOT-VGT, and MODIS. The data sets from the latter two sensors were provided in a form that reduces the effects of surface reflectance associated with solar and view angles. Our analysis revealed large geographic areas, totaling 40% of the study area, where all data sets indicated similar changes in vegetation productivity over their common temporal record, as well as areas where data sets showed conflicting patterns. The newer, GIMMS3g data set showed statistically significant (α = 0.05) increases in vegetation productivity (greening) in over 15% of the study area, not seen in its predecessor (GIMMSg), whereas the reverse was rare (<3%). The latter has implications for earlier reports on changes in vegetation activity based on GIMMSg, particularly in Eurasia where greening is especially pronounced in the GIMMS3g data. Our findings highlight both critical uncertainties and areas of confidence in the assessment of ecosystem-response to climate change using satellite-derived indices of photosynthetic activity. Broader efforts are required to evaluate NDVI time series against field measurements of vegetation growth, primary productivity, recruitment, mortality, and other biological processes in order to better understand ecosystem responses to environmental change over large areas. PMID:24890614

Microbial quality of irrigation water used in leafy green production in Southern Brazil and its relationship with produce safety.

PubMed

Decol, Luana Tombini; Casarin, Letícia Sopeña; Hessel, Claudia Titze; Batista, Ana Carolina Fösch; Allende, Ana; Tondo, Eduardo César

2017-08-01

Irrigation water has been recognized as an important microbial risk factor for fruits and vegetables in many production areas, but there is still a lack of information about how the microbiological quality of different irrigation water sources and climatic conditions influence the safety of vegetables produced in Brazil. This study evaluated the distribution of generic E. coli and the prevalence of E. coli O157:H7 in two different water sources (ponds and streams bordering farmlands and urban areas) used for irrigation and on commercially produced lettuces in Southern Brazil. We also evaluated the effect of agricultural factors and meteorological conditions in the potential contamination of water and produce samples. A longitudinal study was conducted on four farms during a year (July 2014 to August 2015). The results showed generic E. coli prevalence of 84.8% and 38.3% in irrigation water samples and on lettuces, respectively, indicating irrigation water as an important source of contamination of lettuces. No significant differences were detected in the counts of E. coli between the two different surface water sources. The climatic conditions, particularly rainfall and environmental temperature, have influenced the high concentration of E. coli. The highest loads of E. coli in irrigation water and on lettuces were found during the warmest time of the year. E. coli O157:H7 was detected by qualitative polymerase chain reaction (qPCR) in 13 water samples but only 4 were confirmed by isolation in culture media. Copyright © 2017 Elsevier Ltd. All rights reserved.

Source origin of trace elements in PM from regional background, urban and industrial sites of Spain

NASA Astrophysics Data System (ADS)

Querol, X.; Viana, M.; Alastuey, A.; Amato, F.; Moreno, T.; Castillo, S.; Pey, J.; de la Rosa, J.; Sánchez de la Campa, A.; Artíñano, B.; Salvador, P.; García Dos Santos, S.; Fernández-Patier, R.; Moreno-Grau, S.; Negral, L.; Minguillón, M. C.; Monfort, E.; Gil, J. I.; Inza, A.; Ortega, L. A.; Santamaría, J. M.; Zabalza, J.

Despite their significant role in source apportionment analysis, studies dedicated to the identification of tracer elements of emission sources of atmospheric particulate matter based on air quality data are relatively scarce. The studies describing tracer elements of specific sources currently available in the literature mostly focus on emissions from traffic or large-scale combustion processes (e.g. power plants), but not on specific industrial processes. Furthermore, marker elements are not usually determined at receptor sites, but during emission. In our study, trace element concentrations in PM 10 and PM 2.5 were determined at 33 monitoring stations in Spain throughout the period 1995-2006. Industrial emissions from different forms of metallurgy (steel, stainless steel, copper, zinc), ceramic and petrochemical industries were evaluated. Results obtained at sites with no significant industrial development allowed us to define usual concentration ranges for a number of trace elements in rural and urban background environments. At industrial and traffic hotspots, average trace metal concentrations were highest, exceeding rural background levels by even one order of magnitude in the cases of Cr, Mn, Cu, Zn, As, Sn, W, V, Ni, Cs and Pb. Steel production emissions were linked to high levels of Cr, Mn, Ni, Zn, Mo, Cd, Se and Sn (and probably Pb). Copper metallurgy areas showed high levels of As, Bi, Ga and Cu. Zinc metallurgy was characterised by high levels of Zn and Cd. Glazed ceramic production areas were linked to high levels of Zn, As, Se, Zr, Cs, Tl, Li, Co and Pb. High levels of Ni and V (in association) were tracers of petrochemical plants and/or fuel-oil combustion. At one site under the influence of heavy vessel traffic these elements could be considered tracers (although not exclusively) of shipping emissions. Levels of Zn-Ba and Cu-Sb were relatively high in urban areas when compared with industrialised regions due to tyre and brake abrasion, respectively.

Varieties of sweet sorghum Super-1 and Super-2 and its equipment for bioethanol in Indonesia

NASA Astrophysics Data System (ADS)

Pabendon, M. B.; Efendi, R.; Santoso, S. B.; Prastowo, B.

2017-05-01

The demands for alternative sources of energy are currently growing because people now are more aware of the many negative impacts fossil fuel gives to the environment. Plant based renewable energy provides potential sources of energy with advantages of cleaner fuel effect and capability of integration with food crop production. Sorghum have been considered to be a highly potential source of food, feed and fuel, especially sweet stalk sorghum that posses both functions as source of food from its grain and fuel made from its stalk juice. Sorghum varieties are well known to have excellent adaptability in marginal areas, especially drought prone areas where other food crops are unable to thrive. The current paper aimed to share ongoing research on many functional uses of sweet stalk sorghum varieties released at Indonesian Cereals Research Institute (ICERI). Among many varieties that had been released were two sweet stalk sorghum varieties SUPER-1 and SUPER-2 released in 2013 that stands out in biomass yield and bioethanol production. Based on various researches conducted at different location and planting season, yield potential of biomass ranged at 30 - 40 t/ha with higher yield occurred during dry season. Stalk juice sugar content in brix were found to be higher in dry season ranged at 13.6 % to 18.4 %, and the amount of juice stalk was obtained at about 30-50 % from total biomass yield. Furthermore, bioethanol production from stalk juice after fermentation was at the range of 8 to 10 % from total stalk juice volume. Modification of processing equipment of bioethanol have also been carried out and was able to increased the concentration of ethanol being distilled from 85% -92% to 90% -95%. Another result obtained was able to decreased fermentation time from 14-21 days to 6-10 days. Furthermore, the yield of ethanol from juice was also from an average of 4.95% to 6.75%.

Sources of Nutrients to Nearshore Areas of a Eutrophic Estuary: Implications for Nutrient-Enhanced Acidification in Puget Sound

NASA Astrophysics Data System (ADS)

Pacella, S. R.

2016-02-01

Ocean acidification has recently been highlighted as a major stressor for coastal organisms. Further work is needed to assess the role of anthropogenic nutrient additions in eutrophied systems on local biological processes, and how this interacts with CO2 emission-driven acidification. This study sought to distinguish changes in pH caused by natural versus anthropogenically affected processes. We quantified the variability in water column pH attributable to primary production and respiration fueled by anthropogenically derived nitrogen in a shallow nearshore area. Two study sites were located in shallow subtidal areas of the Snohomish River estuary, a eutrophic system located in central Puget Sound, Washington. These sites were chosen due to the presence of heavy agricultural activity, urbanized areas with associated waste water treatment, as well as influence from deep, high CO2 marine waters transported through the Strait of Juan de Fuca and upwelled into the area during spring and summer. Data was collected from July-December 2015 utilizing continuous moorings and discrete water column sampling. Analysis of stable isotopes, δ15N, δ18O-NO3, δ15N-NH4, was used to estimate the relative contributions of anthropogenic versus upwelled marine nitrogen sources. Continuous monitoring of pH, dissolved oxygen, temperature, and salinity was conducted at both study sites to link changes in nutrient source and availability with changes in pH. We predicted that isotope data would indicate greater contributions of nitrogen from agriculture and wastewater rather than upwelling in the shallow, nearshore study sites. This study seeks to distinguish the relative magnitude of pH change stimulated by anthropogenic versus natural sources of nitrogen to inform public policy decisions in critically important nearshore ecosystems.

Automated strip-mine and reclamation mapping from ERTS

NASA Technical Reports Server (NTRS)

Rogers, R. H. (Principal Investigator); Reed, L. E.; Pettyjohn, W. A.

1974-01-01

The author has identified the following significant results. Computer processing techniques were applied to ERTS-1 computer-compatible tape (CCT) data acquired in August 1972 on the Ohio Power Company's coal mining operation in Muskingum County, Ohio. Processing results succeeded in automatically classifying, with an accuracy greater than 90%: (1) stripped earth and major sources of erosion; (2) partially reclaimed areas and minor sources of erosion; (3) water with sedimentation; (4) water without sedimentation; and (5) vegetation. Computer-generated tables listing the area in acres and square kilometers were produced for each target category. Processing results also included geometrically corrected map overlays, one for each target category, drawn on a transparent material by a pen under computer control. Each target category is assigned a distinctive color on the overlay to facilitate interpretation. The overlays, drawn at a scale of 1:250,000 when placed over an AMS map of the same area, immediately provided map locations for each target. These mapping products were generated at a tenth of the cost of conventional mapping techniques.

Digestate as nutrient source for biomass production of sida, lucerne and maize

NASA Astrophysics Data System (ADS)

Bueno Piaz Barbosa, Daniela; Nabel, Moritz; Horsch, David; Tsay, Gabriela; Jablonowski, Nicolai

2014-05-01

Biogas as a renewable energy source is supported in many countries driven by climate and energy policies. Nowadays, Germany is the largest biogas producer in the European Union. A sustainable resource management has to be considered within this growing scenario of biogas production systems and its environmental impacts. In this respect, studies aiming to enhance the management of biogas residues, which represents a valuable source of nutrients and organic fertilization, are needed. Our objective was to evaluate the digestate (biogas residue after fermentation process) application as nutrient source for biomass production of three different plants: sida (Sida hermaphrodita - Malvaceae), lucerne (Medicago sativa - Fabaceae) and maize (Zea mays - Poaceae). The digestate was collected from an operating biogas facility (fermenter volume 2500m³, ADRW Natur Power GmbH & Co.KG Titz/Ameln, Germany) composed of maize silage as the major feedstock, and minor amounts of chicken manure, with a composition of 3,29% N; 1,07% P; 3,42% K; and 41,2% C. An arable field soil (Endogleyic Stagnosol) was collected from 0-30 cm depth and 5 mm sieved. The fertilizer treatments of the plants were established in five replicates including digestate (application amount equivalent to 40 t ha-1) and NPK fertilizer (application amount equivalent to 200:100:300 kg ha-1) applications, according to the recommended agricultural doses, and a control (no fertilizer application). The digestate and the NPK fertilizer were thoroughly mixed with the soil in a rotatory shaker for 30 min. The 1L pots were filled with the fertilized soil and the seedlings were transplanted and grown for 30 days under greenhouse conditions (16 h day/8 h night: 24ºC/18ºC; 60% air humidity). After harvesting, the leaf area was immediately measured, and the roots were washed to allow above and below-ground biomass determination. Subsequently, shoots and roots were dried at 60ºC for 48 hours. The biomass and leaf area of sida, lucerne and maize presented similar performance for both digestate and the NPK fertilizer applications, which were greater than the control, showing a positive fertilizing effect of the digestate for plant biomass production. Considering the biomass production obtained with the digestate application for sida, lucerne and maize, the results give support for further field experiments which aim to evaluate the fertilizing and conditioning effect of digestates.

Endocrine disrupting chemicals in indoor and outdoor air

NASA Astrophysics Data System (ADS)

Rudel, Ruthann A.; Perovich, Laura J.

The past 50 years have seen rapid development of new building materials, furnishings, and consumer products and a corresponding explosion in new chemicals in the built environment. While exposure levels are largely undocumented, they are likely to have increased as a wider variety of chemicals came into use, people began spending more time indoors, and air exchange rates decreased to improve energy efficiency. As a result of weak regulatory requirements for chemical safety testing, only limited toxicity data are available for these chemicals. Over the past 15 years, some chemical classes commonly used in building materials, furnishings, and consumer products have been shown to be endocrine disrupting chemicals - that is they interfere with the action of endogenous hormones. These include PCBs, used in electrical equipment, caulking, paints and surface coatings; chlorinated and brominated flame retardants, used in electronics, furniture, and textiles; pesticides, used to control insects, weeds, and other pests in agriculture, lawn maintenance, and the built environment; phthalates, used in vinyl, plastics, fragrances, and other products; alkylphenols, used in detergents, pesticide formulations, and polystyrene plastics; and parabens, used to preserve products like lotions and sunscreens. This paper summarizes reported indoor and outdoor air concentrations, chemical use and sources, and toxicity data for each of these chemical classes. While industrial and transportation-related pollutants have been shown to migrate indoors from outdoor sources, it is expected that indoor sources predominate for these consumer product chemicals; and some studies have identified indoor sources as the predominant factor influencing outdoor ambient air concentrations in densely populated areas. Mechanisms of action, adverse effects, and dose-response relationships for many of these chemicals are poorly understood and no systematic screening of common chemicals for endocrine disrupting effects is currently underway, so questions remain as to the health impacts of these exposures.

Endocrine disrupting chemicals in indoor and outdoor air

PubMed Central

Rudel, Ruthann A.; Perovich, Laura J.

2009-01-01

The past 50 years have seen rapid development of new building materials, furnishings, and consumer products and a corresponding explosion in new chemicals in the built environment. While exposure levels are largely undocumented, they are likely to have increased as a wider variety of chemicals came into use, people began spending more time indoors, and air exchange rates decreased to improve energy efficiency. As a result of weak regulatory requirements for chemical safety testing, only limited toxicity data are available for these chemicals. Over the past 15 years, some chemical classes commonly used in building materials, furnishings, and consumer products have been shown to be endocrine disrupting chemicals—that is they interfere with the action of endogenous hormones. These include PCBs, used in electrical equipment, caulking, paints and surface coatings; chlorinated and brominated flame retardants, used in electronics, furniture, and textiles; pesticides, used to control insects, weeds, and other pests in agriculture, lawn maintenance, and the built environment; phthalates, used in vinyl, plastics, fragrances, and other products; alkylphenols, used in detergents, pesticide formulations, and polystyrene plastics; and parabens, used to preserve products like lotions and sunscreens. This paper summarizes reported indoor and outdoor air concentrations, chemical use and sources, and toxicity data for each of these chemical classes. While industrial and transportation-related pollutants have been shown to migrate indoors from outdoor sources, it is expected that indoor sources predominate for these consumer product chemicals; and some studies have identified indoor sources as the predominant factor influencing outdoor ambient air concentrations in densely populated areas. Mechanisms of action, adverse effects, and dose-response relationships for many of these chemicals are poorly understood and no systematic screening of common chemicals for endocrine disrupting effects is currently underway, so questions remain as to the health impacts of these exposures. PMID:20047015

Aerosol Mapping From Space: Strengths, Limitations, and Applications

NASA Technical Reports Server (NTRS)

Kahn, Ralph

2010-01-01

The aerosol data products from the NASA Earth Observing System's MISR and MODIS instruments provide significant advances in regional and global aerosol optical depth (AOD) mapping, aerosol type measurement, and source plume characterization from space. These products have been and are being used for many applications, ranging from regional air quality assessment, to aerosol air mass type identification and evolution, to wildfire smoke injection height and aerosol transport model validation. However, retrieval uncertainties and coverage gaps still limit the quantitative constraints these satellite data place on some important questions, such as global-scale long-term trends and direct aerosol radiative forcing. Major advances in these areas seem to require a different paradigm, involving the integration of satellite with suborbital data and with models. This presentation will briefly summarize where we stand, and what incremental improvements we can expect, with the current MISR and MODIS aerosol products, and will then elaborate on some initial steps aimed at the necessary integration of satellite data with data from other sources and with chemical transport models.

Implications from the Use of Non-timber Forest Products on the Consumption of Wood as a Fuel Source in Human-Dominated Semiarid Landscapes

NASA Astrophysics Data System (ADS)

Cavalcanti, Maria Clara B. T.; Ramos, Marcelo Alves; Araújo, Elcida L.; Albuquerque, Ulysses P.

2015-08-01

Little is known about what possible effects on wood resources might be caused by non-timber forest products (NTFPs). Here, we assessed the patterns of fuelwood consumption related to an NTFP ( Caryocar coriaceum) oil extraction and how this non-domestic activity can indirectly increase the use pressure on fuelwood species in a protected area, semiarid of Brazil. We conducted semi-structured interviews, in situ inventories, phytosociological surveys, and analyses of wood quality to identify the set of woody plants used in oil production. Householders use large volumes of dry wood and a set of woody species, which are highly exploited. Additionally, many preferred species have low fuel potential and suffer much use pressure. The best fuelwood species are underused, what requires management strategies to improve their potential as a source of energy. As a result, we suggest some conservation and management actions of fuelwood resources related to the use of NTFPs.

STRAWBERRY CRATER ROADLESS AREAS, ARIZONA.

USGS Publications Warehouse

Wolfe, Edward W.; Light, Thomas D.

1984-01-01

The results of a mineral survey conducted in the Strawberry Crater Roadless Areas, Arizona, indicate little promise for the occurrence of metallic mineral or fossil fuel resources in the area. The area contains deposits of cinder, useful for the production of aggregate block, and for deposits of decorative stone; however, similar deposits occur in great abundance throughout the San Francisco volcanic field outside the roadless areas. There is a possibility that the Strawberry Crater Roadless Areas may overlie part of a crustal magma chamber or still warm pluton related to the San Francisco Mountain stratovolcano or to basaltic vents of late Pleistocene or Holocene age. Such a magma chamber or pluton beneath the Strawberry Crater Roadless Areas might be an energy source from which a hot-, dry-rock geothermal energy system could be developed, and a probable geothermal resource potential is therefore assigned to these areas. 9 refs.

Strawberry Crater Roadless Areas, Arizona

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wolfe, E.W.; Light, T.D.

1984-01-01

The results of a mineral survey conducted in 1980 in the Strawberry Crater Roadless Areas, Arizona, indicate little promise for the occurrence of metallic mineral or fossil fuel resources in the area. The area contains deposits of cinder, useful for the production of aggregate block, and for deposits of decorative stone; however, similar deposits occur in great abundance throughout the San Francisco volcanic field outside the roadless areas. There is a possibility that the Strawberry Crater Roadless Areas may overlie part of a crustal magma chamber or still warm pluton related to the San Francisco Mountain stratovolcano or to basalticmore » vents of late Pleistocene or Holocene age. Such a magma chamber or pluton beneath the Strawberry Crater Roadless Areas might be an energy source from which a hot-, dry-rock geothermal energy system could be developed, and a probable geothermal resource potential is therefore assigned to these areas.« less

Bulk organic δ 13C and C/N as indicators for sediment sources in the Pearl River delta and estuary, southern China

NASA Astrophysics Data System (ADS)

Yu, Fengling; Zong, Yongqiang; Lloyd, Jeremy M.; Huang, Guangqing; Leng, Melanie J.; Kendrick, Christopher; Lamb, Angela L.; Yim, Wyss W.-S.

2010-05-01

Preservation of organic matter in estuarine and coastal areas is an important process in the global carbon cycle. This paper presents bulk δ 13C and C/N of organic matter from source to sink in the Pearl River catchment, delta and estuary, and discusses the applicability of δ 13C and C/N as indicators for sources of organic matter in deltaic and estuarine sediments. In addition to the 91 surface sediment samples, other materials collected in this study cover the main sources of organic material to estuarine sediment. These are: terrestrial organic matter (TOM), including plants and soil samples from the catchment; estuarine and marine suspended particulate organic carbon (POC) from both summer and winter. Results show that the average δ 13C of estuarine surface sediment increases from -25.0 ± 1.3‰ in the freshwater environment to -21.0 ± 0.2‰ in the marine environment, with C/N decreasing from 15.2 ± 3.3 to 6.8 ± 0.2. In the source areas, C 3 plants have lower δ 13C than C 4 plants (-29.0 ± 1.8‰ and -13.1 ± 0.5‰ respectively). δ 13C increases from -28.3 ± 0.8‰ in the forest soil to around -24.1‰ in both riverbank soil and mangrove soil due to increasing proportion of C 4 grasses. The δ 13C POC increases from -27.6 ± 0.8‰ in the freshwater areas to -22.4 ± 0.5‰ in the marine-brackish-water areas in winter, and ranges between -24.0‰ in freshwater areas and -25.4‰ in brackish-water areas in summer. Comparison of the δ 13C and C/N between the sources and sink indicates a weakening TOM and freshwater POC input in the surface sedimentary organic matter seawards, and a strengthening contribution from the marine organic matter. Thus we suggest that bulk organic δ 13C and C/N analysis can be used to indicate sources of sedimentary organic matter in estuarine environments. Organic carbon in surface sediments derived from anthropogenic sources such as human waste and organic pollutants from industrial and agricultural activities accounts for less than 10% of the total organic carbon (TOC). Although results also indicate elevated δ 13C of sedimentary organic matter due to some agricultural products such as sugarcane, C 3 plants are still the dominant vegetation type in this area, and the bulk organic δ 13C and C/N is still an effective indicator for sources of organic matter in estuarine sediments.

Terrain Analysis Procedural Guide for Railroads (Report Number 10 in the ETL Series on Guides for Army Terrain Analysis).

DTIC Science & Technology

1982-12-01

study was conducted under DA Project 4A762707A855, Task C, Work 6 Unit 21, "Military Geographic Analysis Technology." This study was done under the...supplement to the Terrain Analysis Procedural Guide for Roads and Related Structures (ETL-0205, October 1979). In sparsely inhabited study areas, railroad data... study area. " W, In general, three major sources of information are available that will = be helpful in the production of factor overlays for railroads

Production of biogas from solid organic wastes through anaerobic digestion: a review.

PubMed

Muhammad Nasir, Ismail; Mohd Ghazi, Tinia I; Omar, Rozita

2012-07-01

Anaerobic digestion treatments have often been used for biological stabilization of solid wastes. These treatment processes generate biogas which can be used as a renewable energy sources. Recently, anaerobic digestion of solid wastes has attracted more interest because of current environmental problems, most especially those concerned with global warming. Thus, laboratory-scale research on this area has increased significantly. In this review paper, the summary of the most recent research activities covering production of biogas from solid wastes according to its origin via various anaerobic technologies was presented.

Seasonal behavior of carbonyls and source characterization of formaldehyde (HCHO) in ambient air

NASA Astrophysics Data System (ADS)

Lui, K. H.; Ho, Steven Sai Hang; Louie, Peter K. K.; Chan, C. S.; Lee, S. C.; Hu, Di; Chan, P. W.; Lee, Jeffrey Chi Wai; Ho, K. F.

2017-03-01

Gas-phase formaldehyde (HCHO) is an intermediate and a sensitive indicator for volatile organic compounds (VOCs) oxidation, which drives tropospheric ozone production. Effective photochemical pollution control strategies demand a thorough understanding of photochemical oxidation precursors, making differentiation between sources of primary and secondary generated HCHO inevitable. Spatial and seasonal variations of airborne carbonyls based on two years of measurements (2012-2013), coupled with a correlation-based HCHO source apportionment analysis, were determined for three sampling locations in Hong Kong (denoted HT, TC, and YL). Formaldehyde and acetaldehyde were the two most abundant compounds of the total quantified carbonyls. Pearson's correlation analysis (r > 0.7) implies that formaldehyde and acetaldehyde possibly share similar sources. The total carbonyl concentration trends (HT < TC < YL) reflect location characteristics (urban > rural). A regression analysis further quantifies the relative primary HCHO source contributions at HT (∼13%), TC (∼21%), and YL (∼40%), showing more direct vehicular emissions in urban than rural areas. Relative secondary source contributions at YL (∼36%) and TC (∼31%) resemble each other, implying similar urban source contributions. Relative background source contributions at TC could be due to a closed structure microenvironment that favors the trapping of HCHO. Comparable seasonal differences are observed at all stations. The results of this study will aid in the development of a new regional ozone (O3) control policy, as ambient HCHO can enhance O3 production and also be produced from atmospheric VOCs oxidation (secondary HCHO).

An operational application of satellite snow cover observations, northwest United States. [using LANDSAT 1

NASA Technical Reports Server (NTRS)

Dillard, J. P.

1975-01-01

LANDSAT-1 imagery showing extent of snow cover was collected and is examined for the 1973 and 1974 snowmelt seasons for three Columbia River Basins. Snowlines were mapped and the aerial snow cover was determined using satellite data. Satellite snow mapping products were compared products from conventional information sources (computer programming and aerial photography was used). Available satellite data were successfully analyzed by radiance thresholding to determine snowlines and the attendant snow-covered area. Basin outline masks, contour elevation masks, and grid overlays were utilized as satellite data interpretation aids. Verification of the LANDSAT-1 data was generally good although there were exceptions. A major problem was lack of adequate cloud-free satellite imagery of high resolution and determining snowlines in forested areas.

Satellite-derived methane hotspot emission estimates using a fast data-driven method

NASA Astrophysics Data System (ADS)

Buchwitz, Michael; Schneising, Oliver; Reuter, Maximilian; Heymann, Jens; Krautwurst, Sven; Bovensmann, Heinrich; Burrows, John P.; Boesch, Hartmut; Parker, Robert J.; Somkuti, Peter; Detmers, Rob G.; Hasekamp, Otto P.; Aben, Ilse; Butz, André; Frankenberg, Christian; Turner, Alexander J.

2017-05-01

Methane is an important atmospheric greenhouse gas and an adequate understanding of its emission sources is needed for climate change assessments, predictions, and the development and verification of emission mitigation strategies. Satellite retrievals of near-surface-sensitive column-averaged dry-air mole fractions of atmospheric methane, i.e. XCH4, can be used to quantify methane emissions. Maps of time-averaged satellite-derived XCH4 show regionally elevated methane over several methane source regions. In order to obtain methane emissions of these source regions we use a simple and fast data-driven method to estimate annual methane emissions and corresponding 1σ uncertainties directly from maps of annually averaged satellite XCH4. From theoretical considerations we expect that our method tends to underestimate emissions. When applying our method to high-resolution atmospheric methane simulations, we typically find agreement within the uncertainty range of our method (often 100 %) but also find that our method tends to underestimate emissions by typically about 40 %. To what extent these findings are model dependent needs to be assessed. We apply our method to an ensemble of satellite XCH4 data products consisting of two products from SCIAMACHY/ENVISAT and two products from TANSO-FTS/GOSAT covering the time period 2003-2014. We obtain annual emissions of four source areas: Four Corners in the south-western USA, the southern part of Central Valley, California, Azerbaijan, and Turkmenistan. We find that our estimated emissions are in good agreement with independently derived estimates for Four Corners and Azerbaijan. For the Central Valley and Turkmenistan our estimated annual emissions are higher compared to the EDGAR v4.2 anthropogenic emission inventory. For Turkmenistan we find on average about 50 % higher emissions with our annual emission uncertainty estimates overlapping with the EDGAR emissions. For the region around Bakersfield in the Central Valley we find a factor of 5-8 higher emissions compared to EDGAR, albeit with large uncertainty. Major methane emission sources in this region are oil/gas and livestock. Our findings corroborate recently published studies based on aircraft and satellite measurements and new bottom-up estimates reporting significantly underestimated methane emissions of oil/gas and/or livestock in this area in EDGAR.

Nearshore Phytoplankton Production on the Louisiana Continental Shelf

NASA Astrophysics Data System (ADS)

Fung, M.; Lehrter, J. C.

2017-12-01

Net heterotrophy has been observed across much of the Louisiana continental shelf (LCS) where hypoxic conditions occur. Recent studies suggest that cross-shelf transport of nearshore organic matter derived from phytoplankton production subsidizes this heterotrophy. To investigate this theory, we conducted two cruises in spring and summer of 2017 to assess the spatial and temporal patterns of primary production (PP) and respiration (R). We focused on nearshore waters across the area of the shelf where hypoxia is most frequently observed. Overall, PP rates were highest (median = 35 mmol O2 m-3 d-1) in nearshore surface waters (sites with <15 m depth and riverine plume locations), but temporal and spatial differences were seen in both the magnitude of PP and R. Nearshore waters in spring had the highest production rates (median = 52.3 mmol O2 m-3 d-1) and were an order of magnitude greater than production in offshore waters (>15 m depth), while summer production rates in the nearshore and offshore areas were comparable. Similarly, spring nearshore respiration rates (11.2 mmol O2 m-3 d-1) were an order of magnitude larger than offshore, and summer respiration rates in the nearshore and offshore areas were comparable. P/R was greatest nearshore in the spring (4.7) and lowest offshore in the summer (0.9). These results suggest that nearshore production is potentially a significant source of organic matter for the observed heterotrophy over most of the LCS, supporting the theory that shelf-wide hypoxia may be largely driven by nearshore production.

A novel library-independent approach based on high-throughput cultivation in Bioscreen and fingerprinting by FTIR spectroscopy for microbial source tracking in food industry.

PubMed

Shapaval, V; Møretrø, T; Wold Åsli, A; Suso, H P; Schmitt, J; Lillehaug, D; Kohler, A

2017-05-01

Microbiological source tracking (MST) for food industry is a rapid growing area of research and technology development. In this paper, a new library-independent approach for MST is presented. It is based on a high-throughput liquid microcultivation and FTIR spectroscopy. In this approach, FTIR spectra obtained from micro-organisms isolated along the production line and a product are compared to each other. We tested and evaluated the new source tracking approach by simulating a source tracking situation. In this simulation study, a selection of 20 spoilage mould strains from a total of six genera (Alternaria, Aspergillus, Mucor, Paecilomyces, Peyronellaea and Phoma) was used. The simulation of the source tracking situation showed that 80-100% of the sources could be correctly identified with respect to genus/species level. When performing source tracking simulations, the FTIR identification diverged for Phoma glomerata strain in the reference collection. When reidentifying the strain by sequencing, it turned out that the strain was a Peyronellaea arachidicola. The obtained results demonstrated that the proposed approach is a versatile tool for identifying sources of microbial contamination. Thus, it has a high potential for routine control in the food industry due to low costs and analysis time. The source tracking of fungal contamination in the food industry is an important aspect of food safety. Currently, all available methods are time consuming and require the use of a reference library that may limit the accuracy of the identification. In this study, we report for the first time, a library-independent FTIR spectroscopic approach for MST of fungal contamination along the food production line. It combines high-throughput microcultivation and FTIR spectroscopy and is specific on the genus and species level. Therefore, such an approach possesses great importance for food safety control in food industry. © 2016 The Society for Applied Microbiology.

Characterization of biomass burning from olive grove areas: A major source of organic aerosol in PM10 of Southwest Europe

NASA Astrophysics Data System (ADS)

Sánchez de la Campa, Ana M.; Salvador, Pedro; Fernández-Camacho, Rocío; Artiñano, Begoña; Coz, Esther; Márquez, Gonzalo; Sánchez-Rodas, Daniel; de la Rosa, Jesús

2018-01-01

The inorganic and organic geochemistry of aerosol particulate matter (APM) was studied in a major olive grove area from Southwest Europe (Baena, Spain). The biomass consists of olive tree branches and the solid waste resulting of the olive oil production. Moreover, high PM10 levels were obtained (31.5 μg m- 3), with two days of exceedance of the daily limit of 50 μg m- 3 (2008/50/CE; EU, 2008) during the experimental period. A high mean levoglucosan concentration was obtained representing up 95% of the total mass of the isomers analysed (280 ng m- 3), while galactosan and mannosan mean concentrations were lower (8.64 ng m- 3 and 7.86 ng m- 3, respectively). The contribution of wood smoke in Baena was estimated, representing 19% of OC and 17% of OM total mass. Positive matrix factor (PMF) was applied to the organic and inorganic aerosols data, which has permitted the identification of five source categories: biomass burning, traffic, mineral dust, marine aerosol and SIC (secondary inorganic compounds). The biomass burning category reached the highest mean contribution to the PM10 mass (41%, 17.6 μg m- 3). In light of these results, the use of biomass resulting from the olive oil production for residential heating and industry must be considered the most important aerosol source during the winter months. The results of this paper can be extrapolated to other olive oil producing areas in the Mediterranean basin. Therefore, a fuller understanding of this type of biomass combustion is required in order to be able to establish appropriate polices and reduce the environmental impact on the population.

The importance of plant diversity in maintaining the pollinator bee, Eulaema nigrita (Hymenoptera: Apidae) in sweet passion fruit fields.

PubMed

da Silva, Cláudia Inês; Bordon, Natali Gomes; da Rocha Filho, Léo Correia; Garófalo, Carlos Alberto

2012-12-01

The euglossine bee Eulaema nigrita plays an important role for the pollination of native and economically important plants, such as the sweet passion-fruit Passiflora alata. E. nigrita uniquely collects the nectar from the flowers of P. alata, nevertheless, it needs to visit other plants to collect pollen, nectar and other resources for its survival. There are two methods to identify the species of plants used by bees in their diet: by direct observation of the bees in the flowers, and through identification of pollen grains present in brood cells, feces, or in the bees' body. In order to identify the other plants that E. nigrita visits, we analyzed samples of pollen grains removed from the bee's body in the course of the flowering period of P. alata. Among our results, the flora visited by E. nigrita comprised 40 species from 32 genera and 19 families, some of them used as a pollen source or just nectar. In spite of being a polyletic species, E. nigrita exhibited preference for some plant species with poricidal anthers. P. alata which has high sugar concentration nectar was the main source of nectar for this bee in the studied area. Nonetheless, the pollinic analysis indicated that others nectariferous plant species are necessary to keep the populations of E. nigrita. Studies such as this one are important since they indicate supplementary pollen-nectar sources which must be used for the conservation of the populations of E. nigrita in crops neighbouring areas. In the absence of pollinators, growers are forced to pay for hand pollination, which increases production costs; keeping pollinators in cultivated areas is still more feasible to ensure sweet passion fruit production.

Hydrogen energy systems technology study

NASA Technical Reports Server (NTRS)

Kelley, J. H.

1975-01-01

The paper discusses the objectives of a hydrogen energy systems technology study directed toward determining future demand for hydrogen based on current trends and anticipated new uses and identifying the critical research and technology advancements required to meet this need with allowance for raw material limitations, economics, and environmental effects. Attention is focused on historic production and use of hydrogen, scenarios used as a basis for projections, projections of energy sources and uses, supply options, and technology requirements and needs. The study found more than a billion dollar annual usage of hydrogen, dominated by chemical-industry needs, supplied mostly from natural gas and petroleum feedstocks. Evaluation of the progress in developing nuclear fusion and solar energy sources relative to hydrogen production will be necessary to direct the pace and character of research and technology work in the advanced water-splitting areas.

Occurrence, sources, and potential human health risks of polycyclic aromatic hydrocarbons in agricultural soils of the coal production area surrounding Xinzhou, China.

PubMed

Zhao, Long; Hou, Hong; Shangguan, Yuxian; Cheng, Bin; Xu, Yafei; Zhao, Ruifen; Zhang, Yigong; Hua, Xiaozan; Huo, Xiaolan; Zhao, Xiufeng

2014-10-01

A comprehensive investigation of the levels, distribution patterns, and sources of polycyclic aromatic hydrocarbons (PAHs) in agricultural soils of the coal production area surrounding Xinzhou, China, was conducted, and the potential human health risks associated with the levels observed were addressed. A total of 247 samples collected from agricultural soils from the area were analyzed for sixteen PAHs, including highly carcinogenic isomers. The PAH concentrations had a range of n.d. to 782ngg(-1), with a mean value of 202ngg(-1). The two-three ring PAHs were the dominant species, making up 60 percent of total PAHs. Compared with the pollution levels and carcinogenic potential risks reported in other studies, the soil PAH concentrations in the study area were in the low to intermediate range. A positive matrix factorization model indicates that coal/biomass combustion, coal and oil combustion, and coke ovens are the primary PAH sources, accounting for 33 percent, 26 percent, and 24 percent of total PAHs, respectively. The benzo[a]pyrene equivalent (BaPeq) concentrations had a range of n.d. to 476ngg(-1) for PAH7c, with a mean value of 34ngg(-1). The BaPeq concentrations of PAH7c accounted for more than 99 percent of the ∑PAH16, which suggests that seven PAHs were major carcinogenic contributors of ∑PAH16. According to the Canadian Soil Quality Guidelines, only six of the soil samples had concentrations above the safe BaPeq value of 600ngg(-1); the elevated concentrations observed at these sites can be attributed to coal combustion and industrial activities. Exposure to these soils through direct contact probably poses a significant risk to human health as a result of the carcinogenic effects of PAHs. Copyright © 2014 Elsevier Inc. All rights reserved.

Contamination of surface, ground, and drinking water from pharmaceutical production.

PubMed

Fick, Jerker; Söderström, Hanna; Lindberg, Richard H; Phan, Chau; Tysklind, Mats; Larsson, D G Joakim

2009-12-01

Low levels of pharmaceuticals are detected in surface, ground, and drinking water worldwide. Usage and incorrect disposal have been considered the major environmental sources of these microcontaminants. Recent publications, however, suggest that wastewater from drug production can potentially be a source of much higher concentrations in certain locations. The present study investigated the environmental fate of active pharmaceutical ingredients in a major production area for the global bulk drug market. Water samples were taken from a common effluent treatment plant near Hyderabad, India, which receives process water from approximately 90 bulk drug manufacturers. Surface water was analyzed from the recipient stream and from two lakes that are not contaminated by the treatment plant. Water samples were also taken from wells in six nearby villages. The samples were analyzed for the presence of 12 pharmaceuticals with liquid chromatography-mass spectrometry. All wells were determined to be contaminated with drugs. Ciprofloxacin, enoxacin, cetirizine, terbinafine, and citalopram were detected at more than 1 microg/L in several wells. Very high concentrations of ciprofloxacin (14 mg/L) and cetirizine (2.1 mg/L) were found in the effluent of the treatment plant, together with high concentrations of seven additional pharmaceuticals. Very high concentrations of ciprofloxacin (up to 6.5 mg/L), cetirizine (up to 1.2 mg/L), norfloxacin (up to 0.52 mg/L), and enoxacin (up to 0.16 mg/L) were also detected in the two lakes, which clearly shows that the investigated area has additional environmental sources of insufficiently treated industrial waste. Thus, insufficient wastewater management in one of the world's largest centers for bulk drug production leads to unprecedented drug contamination of surface, ground, and drinking water. This raises serious concerns regarding the development of antibiotic resistance, and it creates a major challenge for producers and regulatory agencies to improve the situation.

Natural Products as a Vital Source for the Discovery of Cancer Chemotherapeutic and Chemopreventive Agents

PubMed Central

Cragg, Gordon M.; Pezzuto, John M.

2016-01-01

Throughout history, natural products have played a dominant role in the treatment of human ailments. For example, the legendary discovery of penicillin transformed global existence. Presently, natural products comprise a large portion of current-day pharmaceutical agents, most notably in the area of cancer therapy. Examples include Taxol, vinblastine, and camptothecin. These structurally unique agents function by novel mechanisms of action; isolation from natural sources is the only plausible method that could have led to their discovery. In addition to terrestrial plants as sources for starting materials, the marine environment (e.g., ecteinascidin 743, halichondrin B, and dolastatins), microbes (e.g., bleomycin, doxorubicin, and staurosporin), and slime molds (e.g., epothilone B) have yielded remarkable cancer chemotherapeutic agents. Irrespective of these advances, cancer remains a leading cause of death worldwide. Undoubtedly, the prevention of human cancer is highly preferable to treatment. Cancer chemoprevention, the use of vaccines or pharmaceutical agents to inhibit, retard, or reverse the process of carcinogenesis, is another important approach for easing this formidable public health burden. Similar to cancer chemotherapeutic agents, natural products play an important role in this field. There are many examples, including dietary phytochemicals such as sulforaphane and phenethyl isothiocyanate (cruciferous vegetables) and resveratrol (grapes and grape products). Overall, natural product research is a powerful approach for discovering biologically active compounds with unique structures and mechanisms of action. Given the unfathomable diversity of nature, it is reasonable to suggest that chemical leads can be generated that are capable of interacting with most or possibly all therapeutic targets. PMID:26679767

Subsurface occurrence and potential source areas of chlorinated ethenes identified using concentrations and concentration ratios, Air Force Plant 4 and Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas

USGS Publications Warehouse

Garcia, C. Amanda

2005-01-01

The U.S. Geological Survey, in cooperation with the U.S. Air Force Aeronautical Systems Center, Environmental Management Directorate, conducted a study during 2003-05 to characterize the subsurface occurrence and identify potential source areas of the volatile organic compounds classified as chlorinated ethenes at U.S. Air Force Plant 4 (AFP4) and adjacent Naval Air Station-Joint Reserve Base Carswell Field (NAS-JRB) at Fort Worth, Texas. The solubilized chlorinated ethenes detected in the alluvial aquifer originated as either released solvents (tetrachloroethene [PCE], trichloroethene [TCE], and trans-1,2-dichloroethene [trans-DCE]) or degradation products of the released solvents (TCE, cis-1,2-dichloroethene [cis-DCE], and trans-DCE). The combined influences of topographic- and bedrock-surface configurations result in a water table that generally slopes away from a ground-water divide approximately coincident with bedrock highs and the 1-mile-long aircraft assembly building at AFP4. Highest TCE concentrations (10,000 to 920,000 micrograms per liter) occur near Building 181, west of Building 12, and at landfill 3. Highest PCE concentrations (500 to 920 micrograms per liter) occur near Buildings 4 and 5. Highest cis-DCE concentrations (5,000 to 710,000 micrograms per liter) occur at landfill 3. Highest trans-DCE concentrations (1,000 to 1,700 micrograms per liter) occur just south of Building 181 and at landfill 3. Ratios of parent-compound to daughter-product concentrations that increase in relatively short distances (tens to 100s of feet) along downgradient ground-water flow paths can indicate a contributing source in the vicinity of the increase. Largest increases in ratio of PCE to TCE concentrations are three orders of magnitude from 0.01 to 2.7 and 7.1 between nearby wells in the northeastern part of NAS-JRB. In the northern part of NAS-JRB, the largest increases in TCE to total DCE concentration ratios relative to ratios at upgradient wells are from 17 to 240 or from 17 to 260. In the southern part of NAS-JRB, the largest ratio increases with respect to those at upgradient wells are from 22 and 24 to 130, and from 0 and 7.2 to 71. Numerous maximum historical ratios of trans-DCE to cis-DCE are greater than 1, which can indicate that trans-DCE likely was released as a solvent and does not occur only as a result of degradation of TCE. High concentrations of TCE, PCE, cis-DCE, and trans-DCE, abrupt increases in ratios of PCE to TCE and TCE to total DCE, and ratios of trans-DCE to cis-DCE greater than 1 were used to identify 16 potential source areas of chlorinated ethenes at NAS-JRB. The evidence for some of the potential source areas is stronger than for others, but each area reflects one or more of the conditions indicative of chlorinated ethenes entering the aquifer. Potential source areas supported by the strongest evidence are Building 181, between buildings 4 and 5, just west of Building 12, and landfills 1 and 3. The highest historical TCE concentration in the study area, 920,000 micrograms per liter, is near Building 181. The potential source area between Buildings 4 and 5 primarily is identified by notably high PCE concentrations (to 920 micrograms per liter). Primary evidence for the potential source are just west of Building 12 is the notably high TCE concentrations (for example, 160,000 micrograms per liter) that appear to originate in the area. Primary evidence for the potential source area at landfills 1 and (primarily) 3 is the magnitudes of TCE concentrations (for example, two in the 100,000-to-920,000-microgram-per-liter range), cis-DCE concentrations (several in the 5,000-to-710,000-microgram-per-liter range), and trans-DCE concentrations (several in the 500-to-1,700-microgram-per-liter range). The ratio of trans-DCE to cis-DCE at one well in landfill 3 (6.7) is appreciably above the threshold that can indicate likely solvent release as opposed to TCE degradation alone.

Investigation of large-area multicoil inductively coupled plasma sources using three-dimensional fluid model

NASA Astrophysics Data System (ADS)

Brcka, Jozef

2016-07-01

A multi inductively coupled plasma (ICP) system can be used to maintain the plasma uniformity and increase the area processed by a high-density plasma. This article presents a source in two different configurations. The distributed planar multi ICP (DM-ICP) source comprises individual ICP sources that are not overlapped and produce plasma independently. Mutual coupling of the ICPs may affect the distribution of the produced plasma. The integrated multicoil ICP (IMC-ICP) source consists of four low-inductance ICP antennas that are superimposed in an azimuthal manner. The identical geometry of the ICP coils was assumed in this work. Both configurations have highly asymmetric components. A three-dimensional (3D) plasma model of the multicoil ICP configurations with asymmetric features is used to investigate the plasma characteristics in a large chamber and the operation of the sources in inert and reactive gases. The feasibility of the computational calculation, the speed, and the computational resources of the coupled multiphysics solver are investigated in the framework of a large realistic geometry and complex reaction processes. It was determined that additional variables can be used to control large-area plasmas. Both configurations can form a plasma, that azimuthally moves in a controlled manner, the so-called “sweeping mode” (SM) or “polyphase mode” (PPM), and thus they have the potential for large-area and high-density plasma applications. The operation in the azimuthal mode has the potential to adjust the plasma distribution, the reaction chemistry, and increase or modulate the production of the radicals. The intrinsic asymmetry of the individual coils and their combined operation were investigated within a source assembly primarily in argon and CO gases. Limited investigations were also performed on operation in CH4 gas. The plasma parameters and the resulting chemistry are affected by the geometrical relation between individual antennas. The aim of this work is to incorporate the technological, computational, dimensional scaling, and reaction chemistry aspects of the plasma under one computational framework. The 3D simulation is utilized to geometrically scale up the reactive plasma that is produced by multiple ICP sources.

"Pruning of biomolecules and natural products (PBNP)": an innovative paradigm in drug discovery.

PubMed

Bathula, Surendar Reddy; Akondi, Srirama Murthy; Mainkar, Prathama S; Chandrasekhar, Srivari

2015-06-21

The source or inspiration of many marketed drugs can be traced back to natural product research. However, the chemical structure of natural products covers a wide spectrum from very simple to complex. With more complex structures it is often desirable to simplify the molecule whilst retaining the desired biological activity. This approach seeks to identify the structural unit or pharmacophore responsible for the desired activity. Such pharmacophores have been the start point for a wide range of lead generation and optimisation programmes using techniques such as Biology Oriented Synthesis, Diversity Oriented Synthesis, Diverted Total Synthesis, and Fragment Based Drug Discovery. This review discusses the literature precedence of simplification strategies in four areas of natural product research: proteins, polysaccharides, nucleic acids, and compounds isolated from natural product extracts, and their impact on identifying therapeutic products.

Summary of: Simulating the Value of Concentrating Solar Power with Thermal Energy Storage in a Production Cost Model (Presentation)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Denholm, P.; Hummon, M.

2013-02-01

Concentrating solar power (CSP) deployed with thermal energy storage (TES) provides a dispatchable source of renewable energy. The value of CSP with TES, as with other potential generation resources, needs to be established using traditional utility planning tools. Production cost models, which simulate the operation of grid, are often used to estimate the operational value of different generation mixes. CSP with TES has historically had limited analysis in commercial production simulations. This document describes the implementation of CSP with TES in a commercial production cost model. It also describes the simulation of grid operations with CSP in a test systemmore » consisting of two balancing areas located primarily in Colorado.« less

Simulating the Value of Concentrating Solar Power with Thermal Energy Storage in a Production Cost Model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Denholm, P.; Hummon, M.

2012-11-01

Concentrating solar power (CSP) deployed with thermal energy storage (TES) provides a dispatchable source of renewable energy. The value of CSP with TES, as with other potential generation resources, needs to be established using traditional utility planning tools. Production cost models, which simulate the operation of grid, are often used to estimate the operational value of different generation mixes. CSP with TES has historically had limited analysis in commercial production simulations. This document describes the implementation of CSP with TES in a commercial production cost model. It also describes the simulation of grid operations with CSP in a test systemmore » consisting of two balancing areas located primarily in Colorado.« less

Hybrid poplars: fast-growing, disease-resistant species has multiple uses

Treesearch

Ronald S., Jr. Zalesny

2004-01-01

The production of alternative fuels as a source of energy is a focus of concern in the United States. Intensively cultured hybrid poplar plantations have been used to supplement industrial fiber supplies in several areas of the United States, and have therefore gained attention in the North Central region. Attention is focused on poplars because they are fast growing...

Department of Defense Partners in Flight Strategic Plan

DTIC Science & Technology

2004-07-28

forests are private industrial timberlands and often are heavily fragmented. Reconciliation of the need for long· term, sustainable timber production...habitats have been set aside as protected areas or incorporated into the existing Parque Nacional Soberania. In addition, the upper Panama Bay...lines present another source of potential mortality, especially for raptors in western states. Several raptor conservation organizations and industry

Physiological and Morphological Effects of High Water Tables on Early Growth of Giant Reed (Arundo donax), Elephant Grass (Pennisetum purpureum), Energycane and Sugarcane (Saccharum spp.)

USDA-ARS?s Scientific Manuscript database

Increasing demand for renewable energy sources has led to interest in high-biomass crops. Species that have been proposed as well-suited for biofuel production in the Everglades Agricultural Area (EAA) of Florida include Giant Reed (Arundo donax), Elephant Grass (Pennisetum purpureum), Energycane (S...

AN ION CORRELATION PROGRAM FOR DECONVOLUTING COMPOSITE MASS SPECTRA ACQUIRED USING A DIRECT SURFACE IONIZATION SOURCE INTERFACED TO A TIME-OF-FLIGHT MASS SPECTROMETER

EPA Science Inventory

The rapid sampling provided by the DART in ambient air will allow rapid delineation of areas of dispersed chemicals after natural or man-made disasters. Exact masses and RIAs of dimer, precursor, and product ions measured by the oa-TOFMS entered dinto the Ion Correlation Program...

Let's talk it over : interagency cooperation facilities success : a case study : the New York, New Jersey, Connecticut metropolitan area TRANSMIT operational test : ensuring integration of intelligent transportation systems products and services

DOT National Transportation Integrated Search

1989-01-01

This manual provides basic background information and step-by-step procedures for conducting traffic conflict surveys at signalized and unsignalized intersections. The manual was prepared as a training aid and reference source for persons who are ass...

Plasmonic Paper as a Highly Efficient SERS Substrate

DTIC Science & Technology

2012-09-01

trinitrotoluene (TNT), which inherently have low vapor pressure (~10 ppbv at room temperature), intentional packaging further lowers the actual vapor...responders and military personal but also to several areas of medical, food analysis, and environmental research. We and others have introduced a...products because its source (cellulose) is abundant in nature, renewable, inexpensively produced and recycled.31 Paper is also biodegradable

Denitrification and potential nitrous oxide and carbon dioxide production in brownfield wetland soils.

PubMed

Palta, Monica M; Ehrenfeld, Joan G; Groffman, Peter M

2013-09-01

Brownfields, previously developed sites that are derelict, vacant, or underused, are ubiquitous in urban areas. Wetlands on brownfields often retain rain and stormwater longer than the surrounding landscape because they are low-lying; this increases the possibility for these areas to process waterborne contaminants from the urban environment. In the northeastern United States, atmospheric deposition of nitrate (NO) is high. Denitrification, a microbial process common in wetlands, is a means of removing excess NO. Nitrogen gas is the desired end product of denitrification, but incomplete denitrification results in the production of NO, a greenhouse gas. The goal of this study was to investigate the potential of brownfield wetlands to serve as sinks for inorganic nitrogen and sources of greenhouse gases. We examined limitations to denitrification and NO production in brownfield wetland soils in New Jersey. Soil C:N ratios were high (18-40) and intact core denitrification (-0.78 to 11.6 μg NO-N kg dry soil d) and N mineralization (0.11-2.97 mg N kg dry soil d) were low for all sites. However, soil NO increased during dry periods. Nitrate additions to soil slurries increased denitrification rates, whereas labile C additions did not, indicating that soil denitrifiers were nitrogen limited. Incubations indicated that the end product of denitrification was primarily NO and not N. These results indicate that brownfield wetlands can develop significant denitrification capacity, potentially causing NO limitation. They might be significant sinks for atmospheric NO but may also become a significant source of NO if NO deposition were to increase. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kenkel, Philip; Holcomb, Rodney B.

In order for the biofuel industry to meet the RFS benchmarks for biofuels, new feedstock sources and production systems will have to be identified and evaluated. The Southern Plains has the potential to produce over a billion gallons of biofuels from regionally produced alternative crops, agricultural residues, and animal fats. While information on biofuel conversion processes is available, it is difficult for entrepreneurs, community planners and other interested individuals to determine the feasibility of biofuel processes or to match production alternatives with feed stock availability and community infrastructure. This project facilitates the development of biofuel production from these regionally availablemore » feed stocks. Project activities are concentrated in five major areas. The first component focused on demonstrating the supply of biofuel feedstocks. This involves modeling the yield and cost of production of dedicated energy crops at the county level. In 1991 the DOE selected switchgrass as a renewable source to produce transportation fuel after extensive evaluations of many plant species in multiple location (Caddel et al,. 2010). However, data on the yield and cost of production of switchgrass are limited. This deficiency in demonstrating the supply of biofuel feedstocks was addressed by modeling the potential supply and geographic variability of switchgrass yields based on relationship of available switchgrass yields to the yields of other forage crops. This model made it possible to create a database of projected switchgrass yields for five different soil types at the county level. A major advantage of this methodology is that the supply projections can be easily updated as improved varieties of switchgrass are developed and additional yield data becomes available. The modeling techniques are illustrated using the geographic area of Oklahoma. A summary of the regional supply is then provided.« less

The formation of light absorbing insoluble organic compounds from the reaction of biomass burning precursors and Fe(III)

NASA Astrophysics Data System (ADS)

Lavi, Avi; Lin, Peng; Bhaduri, Bhaskar; Laskin, Alexander; Rudich, Yinon

2017-04-01

Dust particles and volatile organic compounds from fuel or biomass burning are two major components that affect air quality in urban polluted areas. We characterized the products from the reaction of soluble Fe(III), a reactive transition metal originating from dust particles dissolution processes, with phenolic compounds , namely, guaiacol, syringol, catechol, o- and p- cresol that are known products of incomplete fuel and biomass combustion but also from other natural sources such as humic compounds degradation. We found that under acidic conditions comparable to those expected on a dust particle surface, phenolic compounds readily react with dissolved Fe(III), leading to the formation of insoluble polymeric compounds. We characterized the insoluble products by x-ray photoelectron microscopy, UV-Vis spectroscopy, mass spectrometry, elemental analysis and thermo-gravimetric analysis. We found that the major chromophores formed are oligomers (from dimers to pentamers) of the reaction precursors that efficiently absorb light between 300nm and 500nm. High variability of the mass absorption coefficient of the reaction products was observed with catechol and guaiacol showing high absorption at the 300-500nm range that is comparable to that of brown carbon (BrC) from biomass burning studies. The studied reaction is a potential source for the in-situ production of secondary BrC material under dark conditions. Our results suggest a reaction path for the formation of bio-available iron in coastal polluted areas where dust particles mix with biomass burning pollution plumes. Such mixing can occur, for instance in the coast of West Africa or North Africa during dust and biomass burning seasons

A summary of the results from the DOE advanced gas reactor (AGR) fuel development and qualification program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Petti, David Andrew

2017-04-01

Modular high temperature gas-cooled reactor (HTGR) designs were developed to provide natural safety, which prevents core damage under all licensing basis events. The principle that guides their design concepts is to passively maintain core temperatures below fission product release thresholds under all accident scenarios. The required level of fuel performance and fission product retention reduces the radioactive source term by many orders of magnitude relative to source terms for other reactor types and allows a graded approach to emergency planning and the potential elimination of the need for evacuation and sheltering beyond a small exclusion area. Achieving this level, however,more » is predicated on exceptionally high coated-particle fuel fabrication quality and excellent performance under normal operation and accident conditions. The design goal of modular HTGRs is to meet the Environmental Protection Agency (EPA) Protective Action Guides (PAGs) for offsite dose at the Exclusion Area Boundary (EAB). To achieve this, the reactor design concepts require a level of fuel integrity that is far better than that achieved for all prior U.S.-manufactured tristructural isotropic (TRISO) coated particle fuel.« less

Airborne measurements of biomass burning products over Africa

NASA Technical Reports Server (NTRS)

Helas, Guenter; Lobert, Juergen; Goldammer, Johann; Andreae, Meinrat O.; Lacaux, J. P.; Delmas, R.

1994-01-01

Ozone has been observed in elevated concentrations by satellites over hitherto believed 'background' areas. There is meteorological evidence that these ozone 'plumes' found over the Atlantic ocean originate from biomass fires on the African continent. Therefore we have investigated ozone and assumed precursor compounds over African regions. The measurements revealed large photosmog layers in altitudes between 1.5 and 4 km. Here we will focus on some results of ozone mixing ratios obtained during the DECAFE 91/FOS experiment and estimate the relevance of biomass burning as a source by comparing the strength of this source to stratospheric input.

Tracing Sources and Contamination Assessments of Heavy Metals in Road and Foliar Dusts in a Typical Mining City, China

PubMed Central

Yang, Jie; Teng, Yanguo; Song, Liuting; Zuo, Rui

2016-01-01

Road and foliar dust samples from four land-use districts of Panzhihua City, a famous V-Ti magnetite production area of China, were collected to investigate the sources and distribution characteristics of 9 heavy metals (V, Pb, Cd, Cu, Zn, Ni, Cr, Fe, and Mn). The results suggest that foliar samples had smaller particle size and higher heavy metal contents than road dusts. The contamination assessments of heavy metals were as follows: Pb and V (significant enrichment) > Zn, Ni, Cr, Fe, and Mn (moderate enrichment) > Cd and Ni (minimal enrichment). Statistical analyses showed Pb, as the primary pollution element, originated from waste incineration and lead-fuel combustion. The sources of Zn, Ni, Cr, Fe, V, and Mn were fugitive dust and traffic activities. Potential origins of Cu were corrosion of alloys used in vehicle components, vehicle covers, or other metallic surfaces and materials. The sources of Cd were different from any other heavy metals. Traffic and industrial activities were the main anthropogenic origins of heavy metals in dusts of Panzhihua, and more attention should be paid to heavy metal pollution in agricultural area. PMID:27992518

Tracing Sources and Contamination Assessments of Heavy Metals in Road and Foliar Dusts in a Typical Mining City, China.

PubMed

Yang, Jie; Teng, Yanguo; Song, Liuting; Zuo, Rui

2016-01-01

Road and foliar dust samples from four land-use districts of Panzhihua City, a famous V-Ti magnetite production area of China, were collected to investigate the sources and distribution characteristics of 9 heavy metals (V, Pb, Cd, Cu, Zn, Ni, Cr, Fe, and Mn). The results suggest that foliar samples had smaller particle size and higher heavy metal contents than road dusts. The contamination assessments of heavy metals were as follows: Pb and V (significant enrichment) > Zn, Ni, Cr, Fe, and Mn (moderate enrichment) > Cd and Ni (minimal enrichment). Statistical analyses showed Pb, as the primary pollution element, originated from waste incineration and lead-fuel combustion. The sources of Zn, Ni, Cr, Fe, V, and Mn were fugitive dust and traffic activities. Potential origins of Cu were corrosion of alloys used in vehicle components, vehicle covers, or other metallic surfaces and materials. The sources of Cd were different from any other heavy metals. Traffic and industrial activities were the main anthropogenic origins of heavy metals in dusts of Panzhihua, and more attention should be paid to heavy metal pollution in agricultural area.

Knowledge co-production and boundary work to promote implementation of conservation plans.

PubMed

Nel, Jeanne L; Roux, Dirk J; Driver, Amanda; Hill, Liesl; Maherry, Ashton C; Snaddon, Kate; Petersen, Chantel R; Smith-Adao, Lindie B; Van Deventer, Heidi; Reyers, Belinda

2016-02-01

Knowledge co-production and boundary work offer planners a new frame for critically designing a social process that fosters collaborative implementation of resulting plans. Knowledge co-production involves stakeholders from diverse knowledge systems working iteratively toward common vision and action. Boundary work is a means of creating permeable knowledge boundaries that satisfy the needs of multiple social groups while guarding the functional integrity of contributing knowledge systems. Resulting products are boundary objects of mutual interest that maintain coherence across all knowledge boundaries. We examined how knowledge co-production and boundary work can bridge the gap between planning and implementation and promote cross-sectoral cooperation. We applied these concepts to well-established stages in regional conservation planning within a national scale conservation planning project aimed at identifying areas for conserving rivers and wetlands of South Africa and developing an institutional environment for promoting their conservation. Knowledge co-production occurred iteratively over 4 years in interactive stake-holder workshops that included co-development of national freshwater conservation goals and spatial data on freshwater biodiversity and local conservation feasibility; translation of goals into quantitative inputs that were used in Marxan to select draft priority conservation areas; review of draft priority areas; and packaging of resulting map products into an atlas and implementation manual to promote application of the priority area maps in 37 different decision-making contexts. Knowledge co-production stimulated dialogue and negotiation and built capacity for multi-scale implementation beyond the project. The resulting maps and information integrated diverse knowledge types of over 450 stakeholders and represented >1000 years of collective experience. The maps provided a consistent national source of information on priority conservation areas for rivers and wetlands and have been applied in 25 of the 37 use contexts since their launch just over 3 years ago. When framed as a knowledge co-production process supported by boundary work, regional conservation plans can be developed into valuable boundary objects that offer a tangible tool for multi-agency cooperation around conservation. Our work provides practical guidance for promoting uptake of conservation science and contributes to an evidence base on how conservation efforts can be improved. © 2015 Society for Conservation Biology.

Novel Catalysts and Processing Technologies for Production of Aerospace Fuels from Non-Petroleum Raw Materials

NASA Technical Reports Server (NTRS)

Hepp, Aloysius F.; Kulis, Michael J.; Psarras, Peter C.; Ball, David W.; Timko, Michael T.; Wong, Hsi-Wu; Peck, Jay; Chianelli, Russell R.

2014-01-01

Transportation fuels production (including aerospace propellants) from non-traditional sources (gases, waste materials, and biomass) has been an active area of research and development for decades. Reducing terrestrial waste streams simultaneous with energy conversion, plentiful biomass, new low-cost methane sources, and/or extra-terrestrial resource harvesting and utilization present significant technological and business opportunities being realized by a new generation of visionary entrepreneurs. We examine several new approaches to catalyst fabrication and new processing technologies to enable utilization of these nontraditional raw materials. Two basic processing architectures are considered: a single-stage pyrolysis approach that seeks to basically re-cycle hydrocarbons with minimal net chemistry or a two-step paradigm that involves production of supply or synthesis gas (mainly carbon oxides and H2) followed by production of fuel(s) via Sabatier or methanation reactions and/or Fischer-Tröpsch synthesis. Optimizing the fraction of product stream relevant to targeted aerospace (and other transportation) fuels via modeling, catalyst fabrication and novel reactor design are described. Energy utilization is a concern for production of fuels for either terrestrial or space operations; renewable sources based on solar energy and/or energy efficient processes may be mission enabling. Another important issue is minimizing impurities in the product stream(s), especially those potentially posing risks to personnel or operations through (catalyst) poisoning or (equipment) damage. Technologies being developed to remove (and/or recycle) heteroatom impurities are briefly discussed as well as the development of chemically robust catalysts whose activities are not diminished during operation. The potential impacts on future missions by such new approaches as well as balance of system issues are addressed.

Novel Catalysts and Processing Technologies for Production of Aerospace Fuels from Non-Petroleum Raw Materials

NASA Technical Reports Server (NTRS)

Hepp, A. F.; Kulis, M. J.; Psarras, P. C.; Ball, D. W.; Timko, M. T.; Wong, H.-W.; Peck, J.; Chianelli, R. R.

2014-01-01

Transportation fuels production (including aerospace propellants) from non-traditional sources (gases, waste materials, and biomass) has been an active area of research and development for decades. Reducing terrestrial waste streams simultaneous with energy conversion, plentiful biomass, new low-cost methane sources, and/or extra-terrestrial resource harvesting and utilization present significant technological and business opportunities being realized by a new generation of visionary entrepreneurs. We examine several new approaches to catalyst fabrication and new processing technologies to enable utilization of these non-traditional raw materials. Two basic processing architectures are considered: a single-stage pyrolysis approach that seeks to basically re-cycle hydrocarbons with minimal net chemistry or a two-step paradigm that involves production of supply or synthesis gas (mainly carbon oxides and hydrogen) followed by production of fuel(s) via Sabatier or methanation reactions and/or Fischer-Tropsch synthesis. Optimizing the fraction of product stream relevant to targeted aerospace (and other transportation) fuels via modeling, catalyst fabrication and novel reactor design are described. Energy utilization is a concern for production of fuels for either terrestrial or space operations; renewable sources based on solar energy and/or energy efficient processes may be mission enabling. Another important issue is minimizing impurities in the product stream(s), especially those potentially posing risks to personnel or operations through (catalyst) poisoning or (equipment) damage. Technologies being developed to remove (and/or recycle) heteroatom impurities are briefly discussed as well as the development of chemically robust catalysts whose activity are not diminished during operation. The potential impacts on future missions by such new approaches as well as balance of system issues are addressed.

Micropower Mixed-signal VLSI Independent Component Analysis for Gradient Flow Acoustic Source Separation.

PubMed

Stanaćević, Milutin; Li, Shuo; Cauwenberghs, Gert

2016-07-01

A parallel micro-power mixed-signal VLSI implementation of independent component analysis (ICA) with reconfigurable outer-product learning rules is presented. With the gradient sensing of the acoustic field over a miniature microphone array as a pre-processing method, the proposed ICA implementation can separate and localize up to 3 sources in mild reverberant environment. The ICA processor is implemented in 0.5 µm CMOS technology and occupies 3 mm × 3 mm area. At 16 kHz sampling rate, ASIC consumes 195 µW power from a 3 V supply. The outer-product implementation of natural gradient and Herault-Jutten ICA update rules demonstrates comparable performance to benchmark FastICA algorithm in ideal conditions and more robust performance in noisy and reverberant environment. Experiments demonstrate perceptually clear separation and precise localization over wide range of separation angles of two speech sources presented through speakers positioned at 1.5 m from the array on a conference room table. The presented ASIC leads to a extreme small form factor and low power consumption microsystem for source separation and localization required in applications like intelligent hearing aids and wireless distributed acoustic sensor arrays.

Development of target ion source systems for radioactive beams at GANIL

NASA Astrophysics Data System (ADS)

Bajeat, O.; Delahaye, P.; Couratin, C.; Dubois, M.; Franberg-Delahaye, H.; Henares, J. L.; Huguet, Y.; Jardin, P.; Lecesne, N.; Lecomte, P.; Leroy, R.; Maunoury, L.; Osmond, B.; Sjodin, M.

2013-12-01

The GANIL facility (Caen, France) is dedicated to the acceleration of heavy ion beams including radioactive beams produced by the Isotope Separation On-Line (ISOL) method at the SPIRAL1 facility. To extend the range of radioactive ion beams available at GANIL, using the ISOL method two projects are underway: SPIRAL1 upgrade and the construction of SPIRAL2. For SPIRAL1, a new target ion source system (TISS) using the VADIS FEBIAD ion source coupled to the SPIRAL1 carbon target will be tested on-line by the end of 2013 and installed in the cave of SPIRAL1 for operation in 2015. The SPIRAL2 project is under construction and is being design for using different production methods as fission, fusion or spallation reactions to cover a large area of the chart of nuclei. It will produce among others neutron rich beams obtained by the fission of uranium induced by fast neutrons. The production target made from uranium carbide and heated at 2000 °C will be associated with several types of ion sources. Developments currently in progress at GANIL for each of these projects are presented.

Advancing Methods for Estimating Cropland Area

NASA Astrophysics Data System (ADS)

King, L.; Hansen, M.; Stehman, S. V.; Adusei, B.; Potapov, P.; Krylov, A.

2014-12-01

Measurement and monitoring of complex and dynamic agricultural land systems is essential with increasing demands on food, feed, fuel and fiber production from growing human populations, rising consumption per capita, the expansion of crops oils in industrial products, and the encouraged emphasis on crop biofuels as an alternative energy source. Soybean is an important global commodity crop, and the area of land cultivated for soybean has risen dramatically over the past 60 years, occupying more than 5% of all global croplands (Monfreda et al 2008). Escalating demands for soy over the next twenty years are anticipated to be met by an increase of 1.5 times the current global production, resulting in expansion of soybean cultivated land area by nearly the same amount (Masuda and Goldsmith 2009). Soybean cropland area is estimated with the use of a sampling strategy and supervised non-linear hierarchical decision tree classification for the United States, Argentina and Brazil as the prototype in development of a new methodology for crop specific agricultural area estimation. Comparison of our 30 m2 Landsat soy classification with the National Agricultural Statistical Services Cropland Data Layer (CDL) soy map shows a strong agreement in the United States for 2011, 2012, and 2013. RapidEye 5m2 imagery was also classified for soy presence and absence and used at the field scale for validation and accuracy assessment of the Landsat soy maps, describing a nearly 1 to 1 relationship in the United States, Argentina and Brazil. The strong correlation found between all products suggests high accuracy and precision of the prototype and has proven to be a successful and efficient way to assess soybean cultivated area at the sub-national and national scale for the United States with great potential for application elsewhere.

[Territory and decentralization in the agenda for productive transformation with equity].

PubMed

Sojo, A

1991-08-01

The regional perspective and the decentralization in Latin American and Caribbean countries was examined in light of technological changes and transformation of economic production to boost productivity. National population policies were not the major cause of redistribution of the population, rather such transformation significantly changed the comparative regional and urban advantages in the use of territory affecting the spatial distribution of the population. Hypotheses were advanced using the transformation of production, regional development, and decentralization on the retention, attraction, and migration of population in different areas with varying economic conditions. Spurious competitiveness means global strategies of enterprises that establish foreign operations by means of factor sourcing. Flexible specialization is a company strategy of permanent innovation based on flexible equipment and a qualified work force. The increasing transnationalization of capital is the source of skills and technology that sustain competitive advantages. Decentralization can resolve local demand, facilitate access to information, mobilize resources, and exercise control over local operations. In Japan, Germany, and Italy vs. the US and France there is a social contract among companies, trade unions, universities, and regional administrations in the interest of capital and the work force. There is no direct relationship between technology and region, the industrial cluster exhibits systemic competitiveness in developed countries (the Emilian model in Italy affirms the ability of small enterprises to develop new products), the regional impact is diverse relative to new technologies (some deprived rural economic areas have potential as in central and northern Italy), and population and region are linked (regional and rural-urban differences in the growth of population and migratory flows account for spatial distribution of the population). Decentralization and systemic competitiveness concern productivity and regional policies (spatial diversity for increased productivity) and technology and human resources are interdependent (technical progress is determined by the level of qualification of the population).

Modelling fate and transport of glyphosate and AMPA in the Meuse catchment to assess the contribution of different pollution sources

NASA Astrophysics Data System (ADS)

Desmet, Nele; Seuntjens, Piet

2013-04-01

Large river basins have multiple sources of pesticides and usually the pollution sources are spread over the entire catchment. The cumulative effect of pesticides entering the river system in upstream areas and the formation of persistent degradation products can compromise downstream water use e.g. raw water quality for drinking water abstractions. For assessments at catchment scale pesticide fluxes coming from different sources and sub basins need to be taken into account. To improve management strategies, a sound understanding of the sources, emission routes, transport, environmental fate and conversion of pesticides is needed. In the Netherlands, the Meuse river basin is an important source for drinking water production. The river suffers from elevated concentrations of glyphosate and aminomethylphosphonic acid (AMPA). For AMPA it is rather unclear to what extent the pollution is related to glyphosate degradation and what is the contribution of other sources, especial phosphonates in domestic and industrial waste water. Based on the available monitoring data only it is difficult to distinguish between AMPA sources in such a large river basin. This hampers interpretation and decision making for water quality management in the Meuse catchment. Here, application of water quality models is very useful to obtain complementary information and insights. Modelling allows accounting for temporal and spatial variability in discharge and concentrations as well as distinguishing the contribution from conversion processes. In this study, a model for the river Meuse was developed and applied to assess the contribution of tributary and transnational influxes, glyphosate degradation and other sources to the AMPA pollution.

The Fertile Grounds Initiative: A new way to close nutrient flows at regional level resulting in better agricultural productivity and less environmental losses

NASA Astrophysics Data System (ADS)

van Beek, Christy; van Duivenbooden, Niek; Noij, Gert-Jan

2014-05-01

The threat of declining soil fertility levels is well known. Yet, and despite numerous efforts, we seem incapable of changing the current situation of sink areas in developed countries and depletion areas in developing countries. With negative consequences (i.e. loss in productive capacity and loss in environmental quality) in both areas. Moreover, due to globalization and urbanization nutrient flows become increasingly disconnected. Soil nutrient depletion cannot simply be compensated for with mineral fertilisers, for the following reasons: • mineral fertilisers are often not affordable for smallholders and fertiliser subsidy systems are not always successful • mineral fertilisers do not contain organic matter and therefore do not halt the degradation of the soil • mineral fertilisers work best in combination with organic sources of nutrients (compost, farm yard manure, etc.) • To halt soil degradation an integrated approach is needed, including reducing losses of nutrients and organic matter from soils at risk. Presently, more actors are getting involved in reallocation of nutrients, especially in the energy and waste sector. Time has come for a new approach to bring together demands and supplies for nutrients. We therefore present the Fertile Grounds Initiative: a broker for nutrient supply and demand in the region. The Fertile Grounds Initiative is based on the findings that: • Organic ánd mineral nutrients are required for increased and sustainable production; • Nutrients have a value and should be treated as such; • Due to globalization and urbanization nutrient flows are ever more polarized between depletion and concentration areas; • The demand for energy poses new threats and opportunities for nutrient management. In the Fertile Grounds Initiative nutrient suppliers from the energy sector, waste management, fertilizer companies, etc. and demands for nutrients from farmers are brought together in a dynamic platform. This platform acts as a nutrient bank and integrates different sources of nutrients into high quality crop nutrition products. A capacity building programme ensures proper application of the nutrients and optimal use of on-farm nutrients. To further shape our ideas of the Fertile Grounds Initiative you are cordially invited to become involved.

Impact of intensive agricultural practices on drinking water quality in the Evros region (NE Greece) by GIS analysis.

PubMed

Nikolaidis, C; Mandalos, P; Vantarakis, A

2008-08-01

Chemical fertilizers are used extensively in modern agriculture, in order to improve yield and productivity of agricultural products. However, nutrient leaching from agricultural soil into groundwater resources poses a major environmental and public health concern. The Evros region is one of the largest agricultural areas in Northern Greece, extending over 1.5 million acres of cultivated land. Many of its drinking water resources are of groundwater origin and lie within agricultural areas. In order to assess the impact of agricultural fertilizers on drinking water quality in this region, tap-water samples from 64 different locations were collected and analyzed for the presence of nitrates (NO(3)(-)), nitrites (NO(2)(-)), ammonium (NH(4)(+)), sulfate (SO(4)(-2)) and phosphate (PO(4)(-3)). These chemicals were selected based on the information that ammonium nitrate, ammonium sulfate and inorganic phosphate were the primary fertilizers used in local crop production. NO(3)(-), SO(4)(-2) and PO(4)(-3) levels exceeding accepted values were recorded in 6.25, 4.70 and 9.38% of all sampling points, respectively. NO(2)(-) and NH(4)(+) concentrations, on the other hand, were inside the permitted range. The data generated were introduced into a geographic information system (GIS) program for computer analysis and projection maps representing afflicted areas were created. Our results indicate a profound geographic correlation in the surface distribution of primary contaminants in areas of intensified agricultural production. Thus, drinking water pollution in these areas can be attributed to excessive fertilizer use from agricultural sources.

Projected refined product balances in key Latin American countries: A preliminary examination

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-06-01

Over the years, the East-West Center (EWC) has developed considerable expertise in refinery modeling, especially in the area of forecasting product balances for countries, given planned capacity changes, changes in product demand, changes in crude slates, and changes in product specifications. This expertise has been applied on an ongoing basis to the major refiners in the Middle East and the Asia-Pacific region, along with the US West Coast as region in its own right. Refinery modeling in these three areas has been ongoing for nearly 15 years at the Center, and the tools and information sources are now well developed.more » To date, the EWC has not applied these tools to Latin America. Although research on Latin America has been an ongoing area of concern at the Center in recent years, the information gathered to date is still not of the level of detail nor quality available for other areas. The modeling efforts undertaken in this report are of a ``baseline`` nature, designed to outline the major issues, attempt a first cut at emerging product balances, and, above all, to elicit commentary from those directly involved in the oil industry in the key countries modeled. Our experience in other regions has shown that it takes a few years dialogue with refiners and government planner in individual countries to develop a reliable database, as well as the insights into operational constraints and practices that make accurate modeling possible. This report is no more than a first step down the road.« less

Optimizing the design of vertical seismic profiling (VSP) for imaging fracture zones over hardrock basement geothermal environments

NASA Astrophysics Data System (ADS)

Reiser, Fabienne; Schmelzbach, Cedric; Maurer, Hansruedi; Greenhalgh, Stewart; Hellwig, Olaf

2017-04-01

A primary focus of geothermal seismic imaging is to map dipping faults and fracture zones that control rock permeability and fluid flow. Vertical seismic profiling (VSP) is therefore a most valuable means to image the immediate surroundings of an existing borehole to guide, for example, the placing of new boreholes to optimize production from known faults and fractures. We simulated 2D and 3D acoustic synthetic seismic data and processed it through to pre-stack depth migration to optimize VSP survey layouts for mapping moderately to steeply dipping fracture zones within possible basement geothermal reservoirs. Our VSP survey optimization procedure for sequentially selecting source locations to define the area where source points are best located for optimal imaging makes use of a cross-correlation statistic, by which a subset of migrated shot gathers is compared with a target or reference image from a comprehensive set of source gathers. In geothermal exploration at established sites, it is reasonable to assume that sufficient à priori information is available to construct such a target image. We generally obtained good results with a relatively small number of optimally chosen source positions distributed over an ideal source location area for different fracture zone scenarios (different dips, azimuths, and distances from the surveying borehole). Adding further sources outside the optimal source area did not necessarily improve the results, but rather resulted in image distortions. It was found that fracture zones located at borehole-receiver depths and laterally offset from the borehole by 300 m can be imaged reliably for a range of the different dips, but more source positions and large offsets between sources and the borehole are required for imaging steeply dipping interfaces. When such features cross-cut the borehole, they are particularly difficult to image. For fracture zones with different azimuths, 3D effects are observed. Far offset source positions contribute less to the image quality as fracture zone azimuth increases. Our optimization methodology is best suited for designing future field surveys with a favorable benefit-cost ratio in areas with significant à priori knowledge. Moreover, our optimization workflow is valuable for selecting useful subsets of acquired data for optimum target-oriented processing.

Spatial and temporal variability in desert dust and anthropogenic pollution in Iraq, 1997-2010.

PubMed

Chudnovsky, A Alexandra; Koutrakis, Petros; Kostinski, Alex; Proctor, Susan P; Garshick, Eric

2017-01-01

Satellite imaging has emerged as a method for monitoring regional air pollution and detecting areas of high dust concentrations. Unlike ground observations, continuous data monitoring is available with global coverage of terrestrial and atmospheric components. In this study we test the utility of different sources of satellite data to assess air pollution concentrations in Iraq. SeaWiFS and MODIS Deep Blue (DB) aerosol optical depth (AOD) products were evaluated and used to characterize the spatial and temporal pollution levels from the late 1990s through 2010. The AOD and Ångström exponent (an indicator of particle size, since smaller Ångström exponent values reflect a source that includes larger particles) were correlated on 50 × 50 km spatial resolution. Generally, AOD and Ångström exponent were inversely correlated, suggesting a significant contribution of coarse particles from dust storms to AOD maxima. Although the majority of grid cells exhibited this trend, a weaker relationship in other locations suggested an additional contribution of fine particles from anthropogenic sources. Tropospheric NO 2 densities from the OMI satellite were elevated over cities, also consistent with a contribution from anthropogenic sources. Our analysis demonstrates the use of satellite imaging data to estimate relative pollution levels and source contributions in areas of the world where direct measurements are not available. The authors demonstrated how satellite data can be used to characterize exposures to dust and to anthropogenic pollution for future health related studies. This approach is of a great potential to investigate the associations between subject-specific exposures to different pollution sources and their health effects in inaccessible regions and areas where ground monitoring is unavailable.

Spatial and temporal variability in desert dust and anthropogenic pollution in Iraq, 1997–2010

PubMed Central

Chudnovsky, A. Alexandra; Koutrakis, Petros; Kostinski, Alex; Proctor, Susan P.; Garshick, Eric

2016-01-01

Satellite imaging has emerged as a method for monitoring regional air pollution and detecting areas of high dust concentrations. Unlike ground observations, continuous data monitoring is available with global coverage of terrestrial and atmospheric components. In this study we test the utility of different sources of satellite data to assess air pollution concentrations in Iraq. SeaWiFS and MODIS Deep Blue (DB) aerosol optical depth (AOD) products were evaluated and used to characterize the spatial and temporal pollution levels from the late 1990s through 2010. The AOD and Ångström exponent (an indicator of particle size, since smaller Ångström exponent values reflect a source that includes larger particles) were correlated on 50 × 50 km spatial resolution. Generally, AOD and Ångström exponent were inversely correlated, suggesting a significant contribution of coarse particles from dust storms to AOD maxima. Although the majority of grid cells exhibited this trend, a weaker relationship in other locations suggested an additional contribution of fine particles from anthropogenic sources. Tropospheric NO2 densities from the OMI satellite were elevated over cities, also consistent with a contribution from anthropogenic sources. Our analysis demonstrates the use of satellite imaging data to estimate relative pollution levels and source contributions in areas of the world where direct measurements are not available. Implications The authors demonstrated how satellite data can be used to characterize exposures to dust and to anthropogenic pollution for future health related studies. This approach is of a great potential to investigate the associations between subject-specific exposures to different pollution sources and their health effects in inaccessible regions and areas where ground monitoring is unavailable. PMID:28001122

Geohazard monitoring and modelling using Persistent Scatterer Interferometry in the framework of the European project Terrafirma

NASA Astrophysics Data System (ADS)

Cooksley, Geraint; Arnaud, Alain; Banwell, Marie-Josée

2013-04-01

Increasingly, geohazard risk managers are looking to satellite observations as a promising option for supporting their risk management and mitigation strategies. The Terrafirma project, aimed at supporting civil protection agencies, local authorities in charge of risk assessment and mitigation is a pan-European ground motion information service funded by the European Space Agency's Global Monitoring for Environment and Security initiative. Over 100 services were delivered to organizations over the last ten years. Terrafirma promotes the use of Synthetic Aperture Radar Interferometry (InSAR) and Persistent Scatterer InSAR (PSI) within three thematic areas for terrain motion analysis: Tectonics, Flooding and Hydrogeology (ground water, landslides and inactive mines), as well as the innovative Wide Area mapping service, aimed at measuring land deformation over very large areas. Terrafirma's thematic services are based on advanced satellite interferometry products; however they exploit additional data sources, including non-EO, coupled with expert interpretation specific to each thematic line. Based on the combination of satellite-derived ground-motion information products with expert motion interpretation, a portfolio of services addressing geo-hazard land motion issues was made available to users. Although not a thematic in itself, the Wide Area mapping product constitutes the fourth quarter of the Terrafirma activities. The wide area processing chain is nearly fully automatic and requires only a little operator interaction. The service offers an operational PSI processing for wide-area mapping with mm accuracy of ground-deformation measurement at a scale of 1:250,000 (i.e. one cm in the map corresponds to 2.5 Km on the ground) on a country or continent level. The WAP was demonstrated using stripmap ERS data however it is foreseen to be a standard for the upcoming Sentinel-1 mission that will be operated in Terrain Observation by Progressive Scan (TOPS) mode. Within each theme, a series of products are offered. The Hydrogeology service delivers geo-information for hydrogeological hazards affecting urban areas, mountainous zones and infra-structures. Areas where groundwater has been severely exploited often experience subsidence as a result. Likewise, many European towns and cities built above abandoned and inactive mines experience strong ground deformation. The hydrogeology theme products study these phenomenon as well as slope instability in mountainous areas. The Tectonics service presents information on seismic hazards. The crustal block boundaries service provides users with information on terrain motion related to major and local faults, earthquake cycles, and vertical deformation sources. The vulnerability map service combines radar satellite date with in situ measurements to identify regions that may be vulnerable in the case of an earthquake. Within the Coastal Lowland and Flood Risk service, the flood plain hazard product assesses flood risk in coastal lowland areas and flood-prone river basins. The advanced subsidence mapping service combines PSI with levelling data and GPS to enable users to interpret subsidence maps within their geodetic reference systems. The flood defence monitoring service focuses on flood protection systems such as dykes and dams. Between 2003 and 2013, Terrafirma delivered services to 51 user organizations in over 25 countries. The archive of datasets is available to organisations involved in geohazard risk management and mitigation. Keywords: Persistent Scatterer Interferometry, Synthetic Aperture Radar, ground motion monitoring, Terrafirma project, multi-hazard analysis

Geomorphic and land cover identification of dust sources in the eastern Great Basin of Utah, U.S.A.

NASA Astrophysics Data System (ADS)

Hahnenberger, Maura; Nicoll, Kathleen

2014-01-01

This study identifies anthropogenically disturbed areas and barren playa surfaces as the two primary dust source types that repeatedly contribute to dust storm events in the eastern Great Basin of western Utah, U.S.A. This semi-arid desert region is an important contributor to dust production in North America, with this study being the first to specifically identify and characterize regional dust sources. From 2004 to 2010, a total of 51 dust event days (DEDs) affected the air quality in Salt Lake City, UT. MODIS satellite imagery during 16 of these DEDs was analyzed to identify dust plumes, and assess the characteristics of dust source areas. A total of 168 plumes were identified, and showed mobilization of dust from Quaternary deposits located within the Bonneville Basin. This analysis identifies 4 major and 5 secondary source areas for dust in this region, which produce dust primarily during the spring and fall months and during moderate or greater drought conditions, with a Palmer Drought Index (PDI) of - 2 or less. The largest number of observed dust plumes (~ 60% of all plumes) originated from playas (ephemeral lakes) and are classified as barren land cover with a silty clay soil sediment surface. Playa surfaces in this region undergo numerous recurrent anthropogenic disturbances, including military operations and anthropogenic water withdrawal. Anthropogenic disturbance is necessary to produce dust from the vegetated landscape in the eastern Great Basin, as evidenced by the new dust source active from 2008 to 2010 in the area burned by the 2007 Milford Flat Fire; this fire was the largest in Utah's history due to extensive cover of invasive cheatgrass (Bromus tectorum) along with drought conditions. However, dust mobilization from the Milford Flat Burned Area was limited to regions that had been significantly disturbed by post-fire land management techniques that consisted of seeding, followed by chaining or tilling of the soil. Dust storms in the eastern Great Basin negatively impact air quality and transportation in the populated regions of Utah; this study details an improved forecasting protocol for dust storm events that will benefit transportation planning and improve public health.

A real-time regional adaptive exposure method for saving dose-area product in x-ray fluoroscopy

PubMed Central

Burion, Steve; Speidel, Michael A.; Funk, Tobias

2013-01-01

Purpose: Reduction of radiation dose in x-ray imaging has been recognized as a high priority in the medical community. Here the authors show that a regional adaptive exposure method can reduce dose-area product (DAP) in x-ray fluoroscopy. The authors' method is particularly geared toward providing dose savings for the pediatric population. Methods: The scanning beam digital x-ray system uses a large-area x-ray source with 8000 focal spots in combination with a small photon-counting detector. An imaging frame is obtained by acquiring and reconstructing up to 8000 detector images, each viewing only a small portion of the patient. Regional adaptive exposure was implemented by varying the exposure of the detector images depending on the local opacity of the object. A family of phantoms ranging in size from infant to obese adult was imaged in anteroposterior view with and without adaptive exposure. The DAP delivered to each phantom was measured in each case, and noise performance was compared by generating noise arrays to represent regional noise in the images. These noise arrays were generated by dividing the image into regions of about 6 mm2, calculating the relative noise in each region, and placing the relative noise value of each region in a one-dimensional array (noise array) sorted from highest to lowest. Dose-area product savings were calculated as the difference between the ratio of DAP with adaptive exposure to DAP without adaptive exposure. The authors modified this value by a correction factor that matches the noise arrays where relative noise is the highest to report a final dose-area product savings. Results: The average dose-area product saving across the phantom family was (42 ± 8)% with the highest dose-area product saving in the child-sized phantom (50%) and the lowest in the phantom mimicking an obese adult (23%). Conclusions: Phantom measurements indicate that a regional adaptive exposure method can produce large DAP savings without compromising the noise performance in the image regions with highest noise. PMID:23635281

High Relative Abundance of Biofuel Sourced Ethanol in Precipitation in the US and Brazil Determined Using Compound Specific Stable Carbon Isotopes

NASA Astrophysics Data System (ADS)

Shimizu, M. S.; Felix, J. D. D.; Casas, M.; Avery, G. B., Jr.; Kieber, R. J.; Mead, R. N.; Willey, J. D.; Lane, C.

2017-12-01

Ethanol biofuel production and consumption have increased exponentially over the last two decades to help reduce greenhouse gas emissions. Currently, 85% of global ethanol production and consumption occurs in the US and Brazil. Increasing biofuel ethanol usage in these two countries enhances emissions of uncombusted ethanol to the atmosphere contributing to poor air quality. Although measurements of ethanol in the air and the precipitation reveal elevated ethanol concentrations in densely populated cities, other sources such as natural vegetation can contribute to emission to the atmosphere. Previous modeling studies indicated up to 12% of atmospheric ethanol is from anthropogenic emissions. Only one gas phase study in southern Florida attempted to constrain the two sources through direct isotopic measurements. The current study used a stable carbon isotope method to constrain sources of ethanol in rainwater from the US and Brazil. A method was developed using solid phase microextraction (SPME) with subsequent analysis by gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS). Stable carbon isotope signatures (δ13C) of vehicle ethanol emission sources for both the US (-9.8‰) and Brazil (-12.7‰) represented C4 plants as feedstock (corn and sugarcane) for biofuel production. An isotope mixing model using biofuel from vehicles (C4 plants) and biogenic (C3 plants) end-members was implemented to estimate ethanol source apportionment in the rain. We found that stable carbon isotope ratio of ethanol in the rain ranged between -22.6‰ and -12.7‰. Our results suggest that the contribution of biofuel to atmospheric ethanol can be higher than previously estimated. As biofuel usage increasing globally, it is essential to determine the relative abundance of anthropogenic ethanol in other areas of the world.

Factors affecting reservoir and stream-water quality in the Cambridge, Massachusetts, drinking-water source area and implications for source-water protection

USGS Publications Warehouse

Waldron, Marcus C.; Bent, Gardner C.

2001-01-01

This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the city of Cambridge, Massachusetts, Water Department, to assess reservoir and tributary-stream quality in the Cambridge drinking-water source area, and to use the information gained to help guide the design of a comprehensive water-quality monitoring program for the source area. Assessments of the quality and trophic state of the three primary storage reservoirs, Hobbs Brook Reservoir, Stony Brook Reservoir, and Fresh Pond, were conducted (September 1997-November 1998) to provide baseline information on the state of these resources and to determine the vulnerability of the reservoirs to increased loads of nutrients and other contaminants. The effects of land use, land cover, and other drainage-basin characteristics on sources, transport, and fate of fecal-indicator bacteria, highway deicing chemicals, nutrients, selected metals, and naturally occurring organic compounds in 11 subbasins that contribute water to the reservoirs also was investigated, and the data used to select sampling stations for incorporation into a water-quality monitoring network for the source area. All three reservoirs exhibited thermal and chemical stratification, despite artificial mixing by air hoses in Stony Brook Reservoir and Fresh Pond. The stratification produced anoxic or hypoxic conditions in the deepest parts of the reservoirs and these conditions resulted in the release of ammonia nitrogen orthophosphate phosphorus, and dissolved iron and manganese from the reservoir bed sediments. Concentrations of sodium and chloride in the reservoirs usually were higher than the amounts recommended by the U.S. Environmental Protection agency for drinking-water sources (20 milligrams per liter for sodium and 250 milligrams per liter for chloride). Maximum measured sodium concentrations were highest in Hobbs Brook Reservoir (113 milligrams per liter), intermediate in Stony Brook Reservoir (62 milligrams per liter), and lowest in Fresh Pond (54 milligrams per liter). Bed sediments in Hobbs Brook and Stony Brook Reservoirs were enriched in iron, manganese, and arsenic relative to those in the impounded lower Charles River in Boston, Massachusetts. Trophic state indices, calculated for each reservoir based on nutrient concentrations, water-column transparency, and phytoplankton abundances, indicated that the upper and middle basins of Hobbs Brook Reservoir were moderately to highly productive and likely to produce algal blooms; the lower basin of Hobbs Brook Reservoir and Stony Brook Reservoir were similar and intermediate in productivity, and Fresh Pond was relatively unproductive and unlikely to produce algal blooms. This pattern is likely due to sedimentation of organic and inorganic particles in the three basins of Hobbs Brook Reservoir and in Stony Brook Reservoir. Molar ratios of nitrogen to phosphorus ranged from 55 in Stony Brook Reservoir to 120 in Hobbs Brook Reservoir, indicating that phytoplankton algae in these water bodies may be phosphorus limited and therefore sensitive to small increases in phosphorus loading from the drainage basin. Nitrogen loads were found to be less important than phosphorus to the trophic condition of the reservoirs. Hobbs Brook and Stony Brook, the two principle streams draining the Cambridge drinking-water source area, differed in their relative contributions to many of the estimated constituent loads. The estimated load of fecal coliform bacteria was more than seven times larger for the mainly residential Stony Brook subbasin upstream from Kendal Green, Mass., than it was for the more commercial and industrial Hobbs Brook subbasin, though the drainage areas of the two subbasins differ only by about 20 percent. The State standard for fecal coliform bacteria in streams in the Cambridge drinking-water source area (20 colony forming units per 100 milliliters) was exceeded at all sampling stations. Estimated s

7 CFR 1.412 - Institution of proceedings.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Adjudication of Sourcing Area Applications and Formal Review of Sourcing Areas Pursuant to the Forest Resources...) Sourcing area applications. The proceeding for determining sourcing areas shall be instituted by receipt of a sourcing area application by the Office of Administrative Law Judges, pursuant to 36 CFR 223.190...

7 CFR 1.411 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Sourcing area applicant means a person who submits a sourcing area application pursuant to these rules, or a person who sourcing area is subject to formal review pursuant to 36 CFR 223.191(e). (b) Decision... Sourcing Area Applications and Formal Review of Sourcing Areas Pursuant to the Forest Resources...

The Next Generation of HLA Image Products

NASA Astrophysics Data System (ADS)

Gaffney, N. I.; Casertano, S.; Ferguson, B.

2012-09-01

We present the re-engineered pipeline based on existing and improved algorithms with the aim of improving processing quality, cross-instrument portability, data flow management, and software maintenance. The Hubble Legacy Archive (HLA) is a project to add value to the Hubble Space Telescope data archive by producing and delivering science-ready drizzled data products and source lists derived from these products. Initially, ACS, NICMOS, and WFCP2 data were combined using instrument-specific pipelines based on scripts developed to process the ACS GOODS data and a separate set of scripts to generate source extractor and DAOPhot source lists. The new pipeline, initially designed for WFC3 data, isolates instrument-specific processing and is easily extendable to other instruments and to generating wide-area mosaics. Significant improvements have been made in image combination using improved alignment, source detection, and background equalization routines. It integrates improved alignment procedures, better noise model, and source list generation within a single code base. Wherever practical, PyRAF based routines have been replaced with non-IRAF based python libraries (e.g. NumPy and PyFITS). The data formats have been modified to handle better and more consistent propagation of information from individual exposures to the combined products. A new exposure layer stores the effective exposure time for each pixel in the sky which is key in properly interpreting combined images from diverse data that were not initially planned to be mosaiced. We worked to improve the validity of the metadata within our FITS headers for these products relative to standard IRAF/PyRAF processing. Any keywords that pertain to individual exposures have been removed from the primary and extension headers and placed in a table extension for more direct and efficient perusal. This mechanism also allows for more detailed information on the processing of individual images to be stored and propagated providing a more hierarchical metadata storage system than key value pair FITS headers provide. In this poster we will discuss the changes to the pipeline processing and source list generation and the lessons learned which may be applicable to other archive projects as well as discuss our new metadata curation and preservation process.

Conflict of interest from a Romanian geneticist's perspective.

PubMed

Ispas, Ioana

2002-07-01

This paper examines Romanian bioethics regulations for biomedical sciences, looking in particular at the genetics area as a source for conflict of interest. The analysis is focused on the organizational level, national regulations, the sources for generating conflicts of interest, and management of conflicts. Modern biotechnology and gene technology are among the key technologies of the twenty-first century. The application of gene technology for medical and pharmaceutical purposes is widely accepted by society, but the same cannot be said of the development and application of gene technology in agriculture and food processing. Because the use of a technology in the production and processing of food is regarded more sceptically than in the production of biomedical products, there can be areas of conflict in many cases when communication is undertaken about gene technology in the agro-food sector. Ethical concerns play an important factor in this, but a society's attitude to a developing technology is an amalgam of many effects which are beyond ethics as such. This paper contains a study carried out by the author for the Romanian Association for Consumer Protection about the attitudes of consumers towards genetically modified (GM) foods. This study revealed that in Romania more than 98% of consumers did not know anything about GM foods and frequently were confused about the definitions of these terms. In conclusion, it is necessary to say that there is a low level of knowledge regarding biotechnology in Romania and this is an important reason why there is neither public acceptance of gene technology products nor is there a rejection.

Evaluation of particulate matter emissions from manganese alloy production using life-cycle assessment.

PubMed

Davourie, Julia; Westfall, Luke; Ali, Mohammed; McGough, Doreen

2017-01-01

Life-cycle assessments (LCAs) provide a wealth of industry data to assist in evaluating the environmental impacts of industrial processes and product supply chains. In this investigation, data from a recent LCA covering global manganese alloy production was used to evaluate sources of particulate matter (PM) emissions associated with the manganese alloy supply chain. The analysis is aimed at providing an empirical, industry-averaged breakdown of the contribution that processes and emissions controls have on total emissions, manganese releases and occupational exposure. The assessment shows that 66% of PM emissions associated with manganese production occur beyond manganese facilities. Direct or on-site emissions represent 34% of total PM and occur predominantly as disperse sources during mineral extraction and hauling, and as primary furnace emissions. The largest contribution of manganese-bearing PM at ground-level is associated with fugitive emissions from metal and slag tapping, casting, crushing and screening. The evaluation provides a high-level ranking of emissions by process area, to assist in identifying priority areas for industry-wide initiatives to reduce emissions and occupational exposure of manganese. The range of PM emission levels in industry indicate that further enhancements in PM emissions can be achieved by sharing of best practices in emissions controls, limiting furnace conditions which lead to by-passing of emissions controls and application of secondary emission controls to capture fugitive emissions during tapping and casting. The LCA approach to evaluating PM emissions underscores the important role that process optimization and resource efficiency have on reducing PM emissions throughout the manganese supply chain. Copyright © 2016. Published by Elsevier B.V.

Bentonite chemical features as proxy of late Cretaceous provenance changes: A case study from the Western Interior Basin of Canada

NASA Astrophysics Data System (ADS)

Fanti, Federico

2009-05-01

Bentonite beds are fairly common in both marine and terrestrial Upper Cretaceous (Campanian-Maastrichtian) deposits of the Western Interior Basin of western Canada and northwestern United States. A detailed stratigraphic, sedimentologic, geochemical (X-ray fluorescence), and mineralogical (X-ray diffraction) study of twenty-one bentonites from the Puskwaskau and Wapiti formations in the Grande Prairie area (west-central Alberta, Canada) is here presented. Major and trace-element concentrations from altered volcanic ashes document the presence in the study area of predominantly trachyandesitic and rhyolitic volcanogenic products, resulted from intense volcanic arc to within-plate pyroclastic activity. Concentration values of high field strength elements (HFSE) and selected large ion lithophile elements (LILE) (e.g. Nb, Zr, Th, and Y) obtained by X-ray fluorescence spectroscopy strongly support the presence of multiple volcanic sources. Integrated paleoenvironmental and geochemical criteria for provenance determination indicate a bimodal occurrence of basic and acid volcanic products interpreted as reflection of source areas characterized by different tectonic setting and magmatic composition. A comparative analysis of geochemical compositions between Grande Prairie bentonites and 30 known volcanic beds from central and southern Alberta, Manitoba and Montana 1. documents a trend toward more acidic and alkali-depleted volcanic products during the late Campanian-early Maastrichtian interval, and 2. suggests a well constrained stratigraphic and geographic subdivision of the non-marine successions of the foreland basin on the basis of geochemical characteristic of volcanic ash beds. Furthermore, geochemical "fingerprints" of several decimeter to meter thick bentonite beds have been coupled with volcanic ash subsurface signature in order to investigate their role as marker beds. This multiple-approach provides a reliable tool for basin-scale identification and correlation of non-marine sedimentary successions.

Monitoring African savanna water use and water stress from local to regional scale: supporting rangeland management (pilot experience in Kruger National Park, South Africa).

NASA Astrophysics Data System (ADS)

Andreu, Ana; Dube, Timothy; Nieto, Hector; González-Dugo, Maria P.; Hülsmann, Stephan

2017-04-01

Drought periods and erratic rainfall patterns across large parts of Africa result in water-limited environments like savannas, highly sensitive to land management practices and changes in climate. Over the Southern part of the continent, savannas are key productive landscapes supporting livestock, crops and rural livelihoods. Monitoring water use and the natural vegetation stress over these semi-arid complex ecosystems can support rangeland management, to maintain long-term productivity. However, the precision/resolution/accuracy of the information required for management will differ at each scale: farm-local (e.g. evaluating the effect of management practices, livestock densities, crop production and grazing), to watershed (e.g. evaluating the effect of fire, detection of vulnerable areas) and regional (e.g. early prediction of drought). To overcome these constrains, TIGER project 401 combines two approaches that take advantage of different conceptual and operational capabilities of Earth Observation data sources. Sentinel 2 high spatial (10 m) and temporal ( 5 days) resolution VIS/NIR images are used for a continuous monitoring of vegetation cover and unstressed evapotranspiration (ET - using Kc-FAO56 method). This methodology will provide the required resolution for farm-local scales, tracking separately the seasonal variations of each canopy layer growth (grass and trees). Meanwhile, lower spatial resolution (1 km) MODIS thermal data allow to determine a regional water stress index (ratio between actual ET, estimated using Two Source Energy Balance-TSEB, and potential ET), supporting the detection of vulnerable areas. The model framework was tested and validated over savanna-type experimental areas (Skukuza & Malopeni), and later applied over the whole Kruger National Park during 2015-2016.

Cattle waste tops cars as source of Southern California smog

NASA Astrophysics Data System (ADS)

Schultz, Colin

2012-06-01

A new study shows that cows, not cars, are the more substantial source of ammonia that leads to ammonium nitrate in California's South Coast Air Basin, the smoggiest place in the United States. Within the region, which consists of the area surrounding and downwind of Los Angeles, a large proportion of the fine-grained particulate matter that makes up smog is formed from ammonium nitrate. Nowak et al. found two main sources of ammonium nitrate: small gas-powered vehicles and dairy farms. Catalytic converters designed to stem the emissions of carbon monoxide, nitrogen oxides, and hydrocarbons from the region's 9.9 million vehicles can produce gaseous ammonia as an unwanted by-product. Bacteria decomposing organic wastes from the region's 298,000 dairy cattle, on the other hand, also account for a sizable source of ammonia emissions.

Source apportionment of volatile organic compounds measured near a cold heavy oil production area

NASA Astrophysics Data System (ADS)

Aklilu, Yayne-abeba; Cho, Sunny; Zhang, Qianyu; Taylor, Emily

2018-07-01

This study investigated sources of volatile organic compounds (VOCs) observed during periods of elevated hydrocarbon concentrations adjacent to a cold heavy oil extraction area in Alberta, Canada. Elevated total hydrocarbon (THC) concentrations were observed during the early morning hours and were associated with meteorological conditions indicative of gravitational drainage flows. THC concentrations were higher during the colder months, an occurrence likely promoted by a lower mixing height. On the other hand, other VOCs had higher concentrations in the summer; this is likely due to increased evaporation and atmospheric chemistry during the summer months. Of all investigated VOC compounds, alkanes contributed the greatest in all seasons. A source apportionment method, positive matrix factorization (PMF), was used to identify the potential contribution of various sources to the observed VOC concentrations. A total of five factors were apportioned including Benzene/Hexane, Oil Evaporative, Toluene/Xylene, Acetone and Assorted Local/Regional Air Masses. Three of the five factors (i.e., Benzene/Hexane, Oil Evaporative, and Toluene/Xylene), formed 27% of the reconstructed and unassigned concentration and are likely associated with emissions from heavy oil extraction. The three factors associated with emissions were comparable to the available emission inventory for the area. Potential sources include solution gas venting, combustion exhaust and fugitive emissions from extraction process additives. The remaining two factors (i.e., Acetone and Assorted Local/Regional Air Mass), comprised 49% of the reconstructed and unassigned concentration and contain key VOCs associated with atmospheric chemistry or the local/regional air mass such as acetone, carbonyl sulphide, Freon-11 and butane.

Evaluation of a moderate resolution, satellite-based impervious surface map using an independent, high-resolution validation data set

USGS Publications Warehouse

Jones, J.W.; Jarnagin, T.

2009-01-01

Given the relatively high cost of mapping impervious surfaces at regional scales, substantial effort is being expended in the development of moderate-resolution, satellite-based methods for estimating impervious surface area (ISA). To rigorously assess the accuracy of these data products high quality, independently derived validation data are needed. High-resolution data were collected across a gradient of development within the Mid-Atlantic region to assess the accuracy of National Land Cover Data (NLCD) Landsat-based ISA estimates. Absolute error (satellite predicted area - "reference area") and relative error [satellite (predicted area - "reference area")/ "reference area"] were calculated for each of 240 sample regions that are each more than 15 Landsat pixels on a side. The ability to compile and examine ancillary data in a geographic information system environment provided for evaluation of both validation and NLCD data and afforded efficient exploration of observed errors. In a minority of cases, errors could be explained by temporal discontinuities between the date of satellite image capture and validation source data in rapidly changing places. In others, errors were created by vegetation cover over impervious surfaces and by other factors that bias the satellite processing algorithms. On average in the Mid-Atlantic region, the NLCD product underestimates ISA by approximately 5%. While the error range varies between 2 and 8%, this underestimation occurs regardless of development intensity. Through such analyses the errors, strengths, and weaknesses of particular satellite products can be explored to suggest appropriate uses for regional, satellite-based data in rapidly developing areas of environmental significance. ?? 2009 ASCE.

Implications of salinity pollution hotspots on agricultural production

NASA Astrophysics Data System (ADS)

Floerke, Martina; Fink, Julia; Malsy, Marcus; Voelker, Jeanette; Alcamo, Joseph

2016-04-01

Salinity pollution can have many negative impacts on water resources used for drinking, irrigation, and industrial purposes. Elevated concentrations of salinity in irrigation water can lead to decreased crop production or crop death and, thus, causing an economic problem. Overall, salinity pollution is a global problem but tends to be more severe in arid and semi-arid regions where the dilution capacity of rivers and lakes is lower and the use of irrigation higher. Particularly in these regions agricultural production is exposed to high salinity of irrigation water as insufficient water quality further reduces the available freshwater resources. According to the FAO, irrigated agriculture contributes about 40 percent of the total food production globally, and therefore, high salinity pollution poses a major concern for food production and food security. We use the WaterGAP3 modeling framework to simulate hydrological, water use, and water quality conditions on a global scale for the time period 1990 to 2010. The modeling framework is applied to simulate total dissolved solids (TDS) loadings and in-stream concentrations from different point and diffuse sources to get an insight on potential environmental impacts as well as risks to agricultural food production. The model was tested and calibrated against observed data from GEMStat and literature sources. Although global in scope, the focus of this study is on developing countries, i.e., in Africa, Asia, and Latin America, as these are most threatened by salinity pollution. Furthermore, insufficient water quality for irrigation and therefore restrictions in irrigation water use are examined, indicating limitations to crop production. Our results show that elevated salinity concentrations in surface waters mainly occur in peak irrigation regions as irrigated agriculture is not only the most relevant water use sector contributing to water abstractions, but also the dominant source of salinity pollution. Additionally, large metropolitan regions are initially loading hotspots and pollution, too, and prevention becomes important as point sources are dependent on sewer connection rates and treatment levels. In conclusion, this study provides a detailed picture of the spatial and temporal distribution of salinity pollution and identifies hotspot areas as well as the dominant sources. Furthermore, impacts of water quality degradation on agricultural production and food security are quantified, which aim for a better understanding of the risks for food security caused by water quality impairment.

Fuelwood production and use in rural Swaziland: a case-study of two communities

USGS Publications Warehouse

Allen, J.A.; Pimentel, D.P.; Lasoie, J.P.

1988-01-01

Information of fuelwood consumption and the local production of wood was collected in two small rural communities in Swaziland. Fuelwood consumption was estimated to be 0.77 t persona??1 yeara??1 in one community (Sigombeni), and 0.63 t persona??1 in the other (Bhekinkhosi). Bhekinkhosi was found to be experiencing a significant fuelwood production/consumption deficit and it expected that Sigombeni will also experience fuelwood deficits by 1990. Individual farm woodlots provided the largest proportion of annual woody biomass production in both areas, accounting for 45% of all profuction in Sigombeni and 73% in Bhekinkhosi. Thirty-seven percent of all farms in Sigombeni and 23% in Bhekinkhosi had woodlots. Virtually all these woodlots consisted primarily of black or green wattle and were established by direct seeding. Two types of community woodlots were identified a?? those established when the area was a private farm and those established with government assistance. The first type of community woodlots was found only in Sigombeni, where it accounted for at least 20% of annual fuelwood production. Community wooslots established with government assistance were an insignificant source of fuelwood in both areas. At an estimated cost of nearly US $500 haa??1, community woodlots planted with government assistance are far more expensive to establish than individual farm woodlots which require no monetary expenditure, assuming local collection of seed. The results indicate a need to increase the local production of fuelwood in rural Swaziland and that encouraging the establishment of onfarm woodlots may be the most effective means of increasing production.

Shifting nitrous oxide source/sink behaviour in a subtropical estuary revealed by automated time series observations

NASA Astrophysics Data System (ADS)

Reading, Michael J.; Santos, Isaac R.; Maher, Damien T.; Jeffrey, Luke C.; Tait, Douglas R.

2017-07-01

The oceans are a major source of the potent greenhouse gas nitrous oxide (N2O) to the atmosphere. However, little information is available on how estuaries and the coastal ocean may contribute to N2O budgets, and on the drivers of N2O in aquatic environments. This study utilised five time series stations along the freshwater to marine continuum in a sub-tropical estuary in Australia (Coffs Creek, Australia). Each time series station captured N2O, radon (222Rn, a natural submarine groundwater discharge tracer), dissolved nitrogen, and dissolved organic carbon (DOC) concentrations for a minimum of 25 h. The use of automated time series observations enabled spatial and tidal-scale variability of N2O to be captured. Groundwater was highly enriched in N2O (up to 306 nM) compared to the receiving surface water. Dissolved N2O supersaturation as high as 386% (27.4 nM) was observed in the upstream freshwater and brackish water areas which represented only a small (∼13%) proportion of the total estuary area. A large area of N2O undersaturation (as low as 53% or 3.9 nM) was observed in the mangrove-dominated lower estuary. This undersaturated area likely resulted from N2O consumption due to nitrate/nitrite (NOx) limitation in mangrove sediments subject to shallow porewater exchange. Overall, the estuary was a minor source of N2O to the atmosphere as the lower mangrove-dominated estuary sink of N2O counteracted groundwater-dominated source of N2O in the upper estuary. Average area-weighted N2O fluxes at the water-air interface approached zero (0.2-0.7 μmol m-2 d-1, depending on piston velocity model used), and were much lower than nitrogen-rich Northern Hemisphere estuaries that are considered large sources of N2O to the atmosphere. This study revealed a temporally and spatially diverse estuary, with areas of N2O production and consumption related to oxygen and total dissolved nitrogen availability, submarine groundwater discharge, and uptake within mangroves.

Surface water geochemical and isotopic variations in an area of accelerating Marcellus Shale gas development.

PubMed

Pelak, Adam J; Sharma, Shikha

2014-12-01

Water samples were collected from 50 streams in an area of accelerating shale gas development in the eastern U.S.A. The geochemical/isotopic characteristics show no correlation with the five categories of Marcellus Shale production. The sub-watersheds with the greatest density of Marcellus Shale development have also undergone extensive coal mining. Hence, geochemical/isotopic compositions were used to understand sources of salinity and effects of coal mining and shale gas development in the area. The data indicates that while some streams appear to be impacted by mine drainage; none appear to have received sustained contribution from deep brines or produced waters associated with shale gas production. However, it is important to note that our interpretations are based on one time synoptic base flow sampling of a few sampling stations and hence do account potential intermittent changes in chemistry that may result from major/minor spills or specific mine discharges on the surface water chemistry. Copyright © 2014 Elsevier Ltd. All rights reserved.

Analysis of oil-pipeline distribution of multiple products subject to delivery time-windows

NASA Astrophysics Data System (ADS)

Jittamai, Phongchai

This dissertation defines the operational problems of, and develops solution methodologies for, a distribution of multiple products into oil pipeline subject to delivery time-windows constraints. A multiple-product oil pipeline is a pipeline system composing of pipes, pumps, valves and storage facilities used to transport different types of liquids. Typically, products delivered by pipelines are petroleum of different grades moving either from production facilities to refineries or from refineries to distributors. Time-windows, which are generally used in logistics and scheduling areas, are incorporated in this study. The distribution of multiple products into oil pipeline subject to delivery time-windows is modeled as multicommodity network flow structure and mathematically formulated. The main focus of this dissertation is the investigation of operating issues and problem complexity of single-source pipeline problems and also providing solution methodology to compute input schedule that yields minimum total time violation from due delivery time-windows. The problem is proved to be NP-complete. The heuristic approach, a reversed-flow algorithm, is developed based on pipeline flow reversibility to compute input schedule for the pipeline problem. This algorithm is implemented in no longer than O(T·E) time. This dissertation also extends the study to examine some operating attributes and problem complexity of multiple-source pipelines. The multiple-source pipeline problem is also NP-complete. A heuristic algorithm modified from the one used in single-source pipeline problems is introduced. This algorithm can also be implemented in no longer than O(T·E) time. Computational results are presented for both methodologies on randomly generated problem sets. The computational experience indicates that reversed-flow algorithms provide good solutions in comparison with the optimal solutions. Only 25% of the problems tested were more than 30% greater than optimal values and approximately 40% of the tested problems were solved optimally by the algorithms.

[Comparative study of the level and distribution of polybrominated diphenyl ethers and new brominated flame retardants in the atmosphere of typical urban].

PubMed

Wu, Hui; Jin, Jun; Wang, Ying; Li, Ming-Yuan; He, Song-Jie; Xu, Meng; Sun, Yi-Ming

2014-04-01

Brominated flame retardants (BFRs) are widely used in industrial and commercial products and are frequently detected in various environmental media. It might be potential harm to the environment and the human body. This study reported the levels of 8 kinds of polybrominated diphenyl ethers (PBDEs: BDE-28, -47, -100, -99, -154, -153, -183, -209) and 3 kinds of new brominated flame retardants (NBFRs: PBT, PBEB, HBB) in the atmosphere of Binhai Development Zone, Weifang City, Shandong Province, which was taken as a BFR production source area and of Nanning City, Guangxi Province, which was taken as a contrast area. The results showed that the average concentrations of sigma8 PBDEs in the atmosphere of Weifang and Nanning were 1.4 x 10(5) pg x m(-3) and 323.0 pg x m(-3), respectively, and the average concentrations of sigma3 NBFRs were 4.2 x 10(3) pg x m(-3) and 11.9 pg x m(-3), respectively. Compared with other cities, the concentrations of BFRs in the atmosphere of the production area were at a high level in the globe, and the concentrations of BFRs in Nanning were similar with other cities in China. The distribution characteristics of PBDEs and NBFRs in the atmosphere of the production area were different from those of Nanning, and the correlations between PBEB, PBT, HBB and BDE-209 were different between Weifang and Nanning.