Science.gov

Sample records for production rate calculations

  1. Production rate calculations for a secondary beam facility

    SciTech Connect

    Jiang, C.L.; Back, B.B.; Rehm, K.E.

    1995-08-01

    In order to select the most cost-effective method for the production of secondary ion beams, yield calculations for a variety of primary beams were performed ranging in mass from protons to {sup 18}O with energies of 100-200 MeV/u. For comparison, production yields for 600-1000 MeV protons were also calculated. For light ion-(A < {sup 4}He) induced reactions at energies above 50 MeV/u the LAHET code was used while the low energy calculations were performed with LPACE. Heavy-ion-induced production rates were calculated with the ISAPACE program. The results of these codes were checked against each other and wherever possible a comparison with experimental data was performed. These comparisons extended to very exotic reaction channels, such as the production of {sup 100}Sn from {sup 112}Sn and {sup 124}Xe induced fragmentation reactions. These comparisons indicate that the codes are able to predict production rates to within one order of magnitude.

  2. Calculation of in-target production rates for radioactive isotope beam production at TRIUMF

    NASA Astrophysics Data System (ADS)

    Garcia, Fatima; Andreoiu, Corina; Kunz, Peter; Laxdal, Aurelia

    2016-09-01

    Rare Isotope Beam (RIB) facilities around the world, such as TRIUMF, work towards development of new target materials to generate exotic species. Access to these rare radioactive isotopes is key for applications in nuclear medicine, astrophysics and fundamental nuclear science. To better understand production from these and other materials, we have built a computer simulation of the RIB targets used at the TRIUMF Isotope Separation and ACceleration (ISAC) facility, to support new target material development. Built at Simon Fraser University, the simulation runs in the GEANT4 nuclear transport toolkit, and can simulate the production rate of isotopes from a given set of beam and target characteristics. The simulation models the bombardment of a production target by an incident high-energy proton beam and calculates isotope in-target production rates different nuclear reactions. Results from the simulation will be presented, along with an evaluation of various nuclear reaction models and a experimentally determined RIB yields at the ISAC Yield Station.

  3. 19 CFR 351.525 - Calculation of ad valorem subsidy rate and attribution of subsidy to a product.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 19 Customs Duties 3 2010-04-01 2010-04-01 false Calculation of ad valorem subsidy rate and... Countervailable Subsidies § 351.525 Calculation of ad valorem subsidy rate and attribution of subsidy to a product. (a) Calculation of ad valorem subsidy rate. The Secretary will calculate an ad valorem subsidy...

  4. 19 CFR 351.525 - Calculation of ad valorem subsidy rate and attribution of subsidy to a product.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 19 Customs Duties 3 2011-04-01 2011-04-01 false Calculation of ad valorem subsidy rate and... Countervailable Subsidies § 351.525 Calculation of ad valorem subsidy rate and attribution of subsidy to a product. (a) Calculation of ad valorem subsidy rate. The Secretary will calculate an ad valorem subsidy...

  5. Calculations of cosmogenic nuclide production rates in the Earth's atmosphere and their inventories

    NASA Technical Reports Server (NTRS)

    Obrien, K.

    1986-01-01

    The production rates of cosmogenic isotopes in the Earth's atmosphere and their resulting terrestrial abundances have been calculated, taking into account both geomagnetic and solar-modulatory effects. The local interstellar flux was assumed to be that of Garcia-Munoz, et al. Solar modulation was accounted for using the heliocentric potential model and expressed in terms of the Deep River neutron monitor count rates. The geomagnetic field was presented by vertical cutoffs calculated by Shea and Smart and the non-vertical cutoffs calculated using ANGRI. The local interstellar particle flux was first modulated using the heliocentric potential field. The modulated cosmic-ray fluxes reaching the earth's orbit then interacted with the geomagnetic field as though it were a high-pass filter. The interaction of the cosmic radiation with the Earth's atmosphere was calculated utilizing the Bolztmann transport equation. Spallation cross sections for isotope production were calculated using the formalism of Silberberg and Tsao and other cross sections were taken from standard sources. Inventories were calculated by accounting from the variation in solar modulation and geomagnetic field strength with time. Results for many isotope, including C-14, Be-7 and Be-10 are in generally good agreement with existing data. The C-14 inventory, for instance, amounts to 1.75/sq cm(e)/s, in excellent agreement with direct estimates.

  6. The rating reliability calculator

    PubMed Central

    Solomon, David J

    2004-01-01

    Background Rating scales form an important means of gathering evaluation data. Since important decisions are often based on these evaluations, determining the reliability of rating data can be critical. Most commonly used methods of estimating reliability require a complete set of ratings i.e. every subject being rated must be rated by each judge. Over fifty years ago Ebel described an algorithm for estimating the reliability of ratings based on incomplete data. While his article has been widely cited over the years, software based on the algorithm is not readily available. This paper describes an easy-to-use Web-based utility for estimating the reliability of ratings based on incomplete data using Ebel's algorithm. Methods The program is available public use on our server and the source code is freely available under GNU General Public License. The utility is written in PHP, a common open source imbedded scripting language. The rating data can be entered in a convenient format on the user's personal computer that the program will upload to the server for calculating the reliability and other statistics describing the ratings. Results When the program is run it displays the reliability, number of subject rated, harmonic mean number of judges rating each subject, the mean and standard deviation of the averaged ratings per subject. The program also displays the mean, standard deviation and number of ratings for each subject rated. Additionally the program will estimate the reliability of an average of a number of ratings for each subject via the Spearman-Brown prophecy formula. Conclusion This simple web-based program provides a convenient means of estimating the reliability of rating data without the need to conduct special studies in order to provide complete rating data. I would welcome other researchers revising and enhancing the program. PMID:15117416

  7. Revised Calculations of the Production Rates for Co Isotopes in Meteorites Using New Cross Sections for Neutron-induced Reactions

    NASA Technical Reports Server (NTRS)

    Sisterson, J. M.; Brooks, F. D.; Buffler, A.; Allie, M. S.; Herbert, M. S.; Nchodu, M. R.; Makupula, S.; Ullmann, J.; Reedy, R. C.; Jones, D. T. L.

    2002-01-01

    New cross section measurements for reactions induced by neutrons with energies greater than 70 MeV are used to calculate the production rates for cobalt isotopes in meteorites and these new calculations are compared to previous estimates. Additional information is contained in the original extended abstract.

  8. Small Rayed Crater Ejecta Retention Age Calculated from Current Crater Production Rates on Mars

    NASA Technical Reports Server (NTRS)

    Calef, F. J. III; Herrick, R. R.; Sharpton, V. L.

    2011-01-01

    Ejecta from impact craters, while extant, records erosive and depositional processes on their surfaces. Estimating ejecta retention age (Eret), the time span when ejecta remains recognizable around a crater, can be applied to estimate the timescale that surface processes operate on, thereby obtaining a history of geologic activity. However, the abundance of sub-kilometer diameter (D) craters identifiable in high resolution Mars imagery has led to questions of accuracy in absolute crater dating and hence ejecta retention ages (Eret). This research calculates the maximum Eret for small rayed impact craters (SRC) on Mars using estimates of the Martian impactor flux adjusted for meteorite ablation losses in the atmosphere. In addition, we utilize the diameter-distance relationship of secondary cratering to adjust crater counts in the vicinity of the large primary crater Zunil.

  9. Ca-41 in iron falls, Grant and Estherville - Production rates and related exposure age calculations

    NASA Technical Reports Server (NTRS)

    Fink, D.; Klein, J.; Middleton, R.; Vogt, S.; Herzog, G. F.

    1991-01-01

    Results are presented of the first phase of a Ca-41 cosmogenic studies program aimed at establishing baseline concentrations and trends in selected meteorites and the use of Ca-41 in estimating exposure ages and preatmospheric meteorite radii. The average Ca-41 saturation activity recorded in four small iron falls is 24 +/-1 dpm/kg. This finding, together with measurements at the center and surface of the large iron Grant, indicates that production of Ca-41 from spallation on iron is weakly dependent on shielding to depths as large as 250 g/sq cm. The (K-41)-Ca-41 exposure age of Grant is estimated at 330 +/-50 My, and an upper limit to its terrestrial age of 43 +/-15 ky. A comparison of the Ca-41 contents of stony and metallic material separated from the mesosiderite Estherville identifies low-energy neutron capture on native Ca as a second important channel of production. It is found that the Ca-41 signal in the stone phase from three meteorites correlates with their size, and that the inferred low-energy neutron fluxes vary by a factor of at least 20.

  10. Multi-calculation rate simulations

    NASA Technical Reports Server (NTRS)

    Powell, J. D.; Akhter, M.

    1977-01-01

    It is common in real time simulations of large aerospace systems to separate the high and low frequency subsystems within the simulation and perform the integrations of the subsystems at different calculation rates. This is done to strike a balance between accuracy of calculation and capacity of the digital computer. Questions arising as to the accuracy of this structure compared to single calculation rates were studied using a linear aircraft model. Also investigated were interactions arising to cause errors worse than those expected. Problems are specifically identified and guidelines are given for selection of sample rates for multiple rate simulations.

  11. Calculation of molecular excitation rates

    NASA Technical Reports Server (NTRS)

    Flynn, George

    1993-01-01

    State-to-state collisional excitation rates for interstellar molecules observed by radio astronomers continue to be required to interpret observed line intensities in terms of local temperatures and densities. A problem of particular interest is collisional excitation of water which is important for modeling the observed interstellar masers. In earlier work supported by a different NASA Grant, excitation of water in collisions with He atoms was studied; after many years of successively more refined calculations that problem now seems to be well understood, and discrepancies with earlier experimental data for related (pressure broadening) phenomena are believed to reflect experimental errors. Because of interstellar abundances, excitation by H2, the dominant interstellar species, is much more important than excitation by He, although it has been argued that rates for excitation by these are similar. Under the current grant theoretical study of this problem has begun which is greatly complicated by the additional degrees of freedom which must be included both in determining the interaction potential and also in the molecular scattering calculation. We have now computed the interaction forces for nearly a thousand molecular geometries and are close to having an acceptable global fit to these points which is necessary for the molecular dynamics calculations. Also, extensive modifications have been made to the molecular scattering code, MOLSCAT. These included coding the rotational basis sets and coupling matrix elements required for collisions of an asymmetric top with a linear rotor. A new method for numerical solution of the coupled equations has been incorporated. Because of the long-ranged nature of the water-hydrogen interaction it is necessary to integrate the equations to rather large intermolecular separations, and the integration methods previously available in MOLSCAT are not ideal for such cases. However, the method used by Alexander in his HIBRIDON code is

  12. Calculating transient rates from surveys

    NASA Astrophysics Data System (ADS)

    Carbone, D.; van der Horst, A. J.; Wijers, R. A. M. J.; Rowlinson, A.

    2017-03-01

    We have developed a method to determine the transient surface density and transient rate for any given survey, using Monte Carlo simulations. This method allows us to determine the transient rate as a function of both the flux and the duration of the transients in the whole flux-duration plane rather than one or a few points as currently available methods do. It is applicable to every survey strategy that is monitoring the same part of the sky, regardless the instrument or wavelength of the survey, or the target sources. We have simulated both top-hat and Fast Rise Exponential Decay light curves, highlighting how the shape of the light curve might affect the detectability of transients. Another application for this method is to estimate the number of transients of a given kind that are expected to be detected by a survey, provided that their rate is known.

  13. ACTIVE: a program to calculate and plot reaction rates from ANISN calculated fluxes

    SciTech Connect

    Judd, J.L.

    1981-12-01

    The ACTIVE code calculates spatial heating rates, tritium production rates, neutron reaction rates, and energy spectra from particle fluxes calculated by ANISN. ACTIVE has a variety of input options including the capability to plot all calculated spatial distributions. The code was primarily designed for use with fusion first wall/blanket systems, but could be applied to any one-dimensional problem.

  14. Comparison of calculations of fragment production

    SciTech Connect

    Canavan, G.H.

    1998-01-01

    This note compares estimates of fragment production rates in debris collisions through calculations performed with consistent debris distribution functions implicit in integrated collision frequencies provided by Attachment A. Differences between estimates of fragment production rates in space debris collisions are shown to be due primarily to different choices of the exponent in the fragment production function and the distinction between catastrophic and all collisions. Sensitivity to the fragment production parameter over the range of values consistent with experimental data is discussed.

  15. Tank Z-361 dose rate calculations

    SciTech Connect

    Richard, R.F.

    1998-09-30

    Neutron and gamma ray dose rates were calculated above and around the 6-inch riser of tank Z-361 located at the Plutonium Finishing Plant. Dose rates were also determined off of one side of the tank. The largest dose rate 0.029 mrem/h was a gamma ray dose and occurred 76.2 cm (30 in.) directly above the open riser. All other dose rates were negligible. The ANSI/ANS 1991 flux to dose conversion factor for neutrons and photons were used in this analysis. Dose rates are reported in units of mrem/h with the calculated uncertainty shown within the parentheses.

  16. Historical river flow rates for dose calculations

    SciTech Connect

    Carlton, W.H.

    1991-06-10

    Annual average river flow rates are required input to the LADTAP Computer Code for calculating offsite doses from liquid releases of radioactive materials to the Savannah River. The source of information on annual river flow rates used in dose calculations varies, depending on whether calculations are for retrospective releases or prospective releases. Examples of these types of releases are: Retrospective - releases from routine operations (annual environmental reports) and short term release incidents that have occurred. Prospective - releases that might be expected in the future from routine or abnormal operation of existing or new facilities (EIS`s, EID`S, SAR`S, etc.). This memorandum provides historical flow rates at the downstream gauging station at Highway 301 for use in retrospective dose calculations and derives flow rate data for the Beaufort-Jasper and Port Wentworth water treatment plants.

  17. Calculations of Polar Ozone Loss Rates

    NASA Technical Reports Server (NTRS)

    Dessler, A. E.; Wu, J.

    1999-01-01

    We calculate vortex-averaged ozone loss rates at 465-K potential temperature during the Aug.-Sept. time period in the southern hemisphere and Feb.-Mar. time period in the northern hemisphere. Ozone loss rates are calculated two ways. First, from the time series of measurements of 03. Second, from measurements of ClO, from which ozone loss is inferred based on our theories of Cl-catalyzed ozone destruction. Both measurement sets are from the Upper Atmosphere Research Satellite (UARS) Microwave Limb Sounder (MLS) instrument. We find good agreement between vortex-averaged ozone loss rates calculated from these methods. Our analysis provides no support for recent work suggesting that current theories of Cl-catalyzed ozone loss underestimate the observed decrease in polar ozone during the ozone "hole" period.

  18. Glass dissolution rate measurement and calculation revisited

    NASA Astrophysics Data System (ADS)

    Fournier, Maxime; Ull, Aurélien; Nicoleau, Elodie; Inagaki, Yaohiro; Odorico, Michaël; Frugier, Pierre; Gin, Stéphane

    2016-08-01

    Aqueous dissolution rate measurements of nuclear glasses are a key step in the long-term behavior study of such waste forms. These rates are routinely normalized to the glass surface area in contact with solution, and experiments are very often carried out using crushed materials. Various methods have been implemented to determine the surface area of such glass powders, leading to differing values, with the notion of the reactive surface area of crushed glass remaining vague. In this study, around forty initial dissolution rate measurements were conducted following static and flow rate (SPFT, MCFT) measurement protocols at 90 °C, pH 10. The international reference glass (ISG), in the forms of powders with different particle sizes and polished monoliths, and soda-lime glass beads were examined. Although crushed glass grains clearly cannot be assimilated with spheres, it is when using the samples geometric surface (Sgeo) that the rates measured on powders are closest to those found for monoliths. Overestimation of the reactive surface when using the BET model (SBET) may be due to small physical features at the atomic scale-contributing to BET surface area but not to AFM surface area. Such features are very small compared with the thickness of water ingress in glass (a few hundred nanometers) and should not be considered in rate calculations. With a SBET/Sgeo ratio of 2.5 ± 0.2 for ISG powders, it is shown here that rates measured on powders and normalized to Sgeo should be divided by 1.3 and rates normalized to SBET should be multiplied by 1.9 in order to be compared with rates measured on a monolith. The use of glass beads indicates that the geometric surface gives a good estimation of glass reactive surface if sample geometry can be precisely described. Although data clearly shows the repeatability of measurements, results must be given with a high uncertainty of approximately ±25%.

  19. Quantum mechanical calculation of Rydberg-Rydberg autoionization rates

    NASA Astrophysics Data System (ADS)

    Kiffner, Martin; Ceresoli, Davide; Li, Wenhui; Jaksch, Dieter

    2016-10-01

    We present quantum mechanical calculations of autoionization rates for two rubidium Rydberg atoms with weakly overlapping electron clouds. We neglect exchange effects and consider tensor products of independent atom states forming an approximate basis of the two-electron state space. We consider large sets of two-atom states with randomly chosen quantum numbers and find that the charge overlap between the two Rydberg electrons allows one to characterise the magnitude of the autoionization rates. If the electron clouds overlap by more than one percent, the autoionization rates increase approximately exponentially with the charge overlap. This finding is independent of the energy of the initial state.

  20. Calculating Graduation Rates: We Can Do Better

    ERIC Educational Resources Information Center

    Bracey, Gerald W.

    2009-01-01

    The statistic of choice to prove that U.S. schools are failing has changed over time. First, it was test scores that meant they could not keep up with Japan. More recently it has become graduation rate. Often accompanying the graduation rate in the failure litany is the drop-out rate. NCLB puts additional pressure on dropout counts because it…

  1. Calculations of in-snow NO2 and OH radical photochemical production and photolysis rates: A field and radiative-transfer study of the optical properties of Arctic (Ny-Ålesund, Svalbard) snow

    NASA Astrophysics Data System (ADS)

    France, J. L.; King, M. D.; Lee-Taylor, J.; Beine, H. J.; Ianniello, A.; Domine, F.; MacArthur, A.

    2011-12-01

    Depth-integrated production rates of OH radicals and NO2 molecules from snowpacks in Ny-Ålesund, Svalbard, are calculated from fieldwork investigating the light penetration depth (e-folding depth) and nadir reflectivity of snowpacks during the unusually warm spring of 2006. Light penetration depths of 8.1, 11.3, 5.1, and 8.2 cm were measured for fresh, old, marine-influenced, and glacial snowpacks, respectively (wavelength 400 nm). Radiative-transfer calculations of the light penetration depths with reflectivity measurements produced scattering cross sections of 5.3, 9.5, 20, and 25.5 m2 kg-1 and absorption cross sections of 7.7, 1.4, 3.4, and 0.5 cm2 kg-1 for the fresh, old, marine-influenced, and glacial snowpacks, respectively (wavelength 400 nm). Photolysis rate coefficients, J, are presented as a function of snow depth and solar zenith angle for the four snowpacks for the photolysis of H2O2 and NO3-. Depth-integrated production rates of hydroxyl radicals are 1270, 2130, 950, and 1850 nmol m-2 h-1 (solar zenith angle of 60°) for fresh, old, marine-influenced, and glacial snowpacks, respectively. Depth-integrated production rates of NO2 are 32, 56, 11, and 22 nmol m-2 h-1 (solar zenith angle of 60°) for the fresh, old, marine-influenced, and glacial snowpacks, respectively. The uncertainty of repeated light penetration depth measurement was determined to be ˜20%, which propagates into a 20% error in depth-integrated production rates. A very simple steady state hydroxyl radical calculation demonstrates that a pseudo first-order loss rate of OH radicals of ˜102-104 s-1 is required in snowpack. The snowpacks around Ny-Ålesund are thick enough to be considered optically infinite.

  2. NPP ATMS Snowfall Rate Product

    NASA Technical Reports Server (NTRS)

    Meng, Huan; Ferraro, Ralph; Kongoli, Cezar; Wang, Nai-Yu; Dong, Jun; Zavodsky, Bradley; Yan, Banghua

    2015-01-01

    Passive microwave measurements at certain high frequencies are sensitive to the scattering effect of snow particles and can be utilized to retrieve snowfall properties. Some of the microwave sensors with snowfall sensitive channels are Advanced Microwave Sounding Unit (AMSU), Microwave Humidity Sounder (MHS) and Advance Technology Microwave Sounder (ATMS). ATMS is the follow-on sensor to AMSU and MHS. Currently, an AMSU and MHS based land snowfall rate (SFR) product is running operationally at NOAA/NESDIS. Based on the AMSU/MHS SFR, an ATMS SFR algorithm has been developed recently. The algorithm performs retrieval in three steps: snowfall detection, retrieval of cloud properties, and estimation of snow particle terminal velocity and snowfall rate. The snowfall detection component utilizes principal component analysis and a logistic regression model. The model employs a combination of temperature and water vapor sounding channels to detect the scattering signal from falling snow and derive the probability of snowfall (Kongoli et al., 2015). In addition, a set of NWP model based filters is also employed to improve the accuracy of snowfall detection. Cloud properties are retrieved using an inversion method with an iteration algorithm and a two-stream radiative transfer model (Yan et al., 2008). A method developed by Heymsfield and Westbrook (2010) is adopted to calculate snow particle terminal velocity. Finally, snowfall rate is computed by numerically solving a complex integral. NCEP CMORPH analysis has shown that integration of ATMS SFR has improved the performance of CMORPH-Snow. The ATMS SFR product is also being assessed at several NWS Weather Forecast Offices for its usefulness in weather forecast.

  3. Database crime to crime match rate calculation.

    PubMed

    Buckleton, John; Bright, Jo-Anne; Walsh, Simon J

    2009-06-01

    Guidance exists on how to count matches between samples in a crime sample database but we are unable to locate a definition of how to estimate a match rate. We propose a method that does not proceed from the match counting definition but which has a strong logic.

  4. Calculating lunar retreat rates using tidal rhythmites

    USGS Publications Warehouse

    Kvale, E.P.; Johnson, H.W.; Sonett, C.P.; Archer, A.W.; Zawistoski, A.N.N.

    1999-01-01

    Tidal rhythmites are small-scale sedimenta??r}- structures that can preserve a hierarchy of astronomically induced tidal periods. They can also preserve a record of periodic nontidal sedimentation. If properly interpreted and understood, tidal rhjthmites can be an important component of paleoastronomy and can be used to extract information on ancient lunar orbital dynamics including changes in Earth-Moon distance through geologic time. Herein we present techniques that can be used to calculate ancient Earth-Moon distances. Each of these techniques, when used on a modern high-tide data set, results in calculated estimates of lunar orbital periods and an EarthMoon distance that fall well within 1 percent of the actual values. Comparisons to results from modern tidal data indicate that ancient tidal rhythmite data as short as 4 months can provide suitable estimates of lunar orbital periods if these tidal records are complete. An understanding of basic tidal theory allows for the evaluation of completeness of the ancient tidal record as derived from an analysis of tidal rhythmites. Utilizing the techniques presented herein, it appears from the rock record that lunar orbital retreat slowed sometime during the midPaleozoic. Copyright ??1999, SEPM (Society for Sedimentary Geology).

  5. Shielding calculations for a production target for secondary beams

    SciTech Connect

    Rehm, K.E.; Back, B.B.; Jiang, C.L.

    1995-08-01

    In order to estimate the amount of shielding required for a radioactive beam facility dose rate were performed. The calculations for production targets with different geometries were performed. The calculations were performed with the MSU shielding code assuming a 500-p{mu}A 200-MeV deuteron beam stopped in a thick Al target. The target and the ion-optical elements for beam extraction are located in a 2 m{sup 3} large volume at the center of the production cell. These dose rate calculations show that with a combination of Fe and concrete it is possible to reduce the dose rate expected at the surface of a 7-m-wide cube housing the production target to less than 2 mrem/hr.

  6. 40 CFR 1036.530 - Calculating greenhouse gas emission rates.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 34 2013-07-01 2013-07-01 false Calculating greenhouse gas emission rates. 1036.530 Section 1036.530 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Procedures § 1036.530 Calculating greenhouse gas emission rates. This section describes how to...

  7. Problems in Calculating and Comparing Dropout Rates. ERS Research Digest.

    ERIC Educational Resources Information Center

    Ligon, Glynn; And Others

    1990-01-01

    This paper dramatizes the complexity and the problems involved in calculating the rates of student dropouts from school. To compare the dropout formulas used by various agencies, states, and local school systems, responses from a national survey are presented and used to calculate a range of dropout rates for the Austin (Texas) public schools. By…

  8. Updates to In-Line Calculation of Photolysis Rates

    EPA Science Inventory

    How photolysis rates are calculated affects ozone and aerosol concentrations predicted by the CMAQ model and the model?s run-time. The standard configuration of CMAQ uses the inline option that calculates photolysis rates by solving the radiative transfer equation for the needed ...

  9. Computer Calculation of First-Order Rate Constants

    ERIC Educational Resources Information Center

    Williams, Robert C.; Taylor, James W.

    1970-01-01

    Discusses the computer program used to calculate first-order rate constants. Discussion includes data preparation, weighting options, comparison techniques, infinity point adjustment, least-square fit, Guggenheim calculation, and printed outputs. Exemplifies the utility of the computer program by two experiments: (1) the thermal decomposition of…

  10. Experiences with leak rate calculations methods for LBB application

    SciTech Connect

    Grebner, H.; Kastner, W.; Hoefler, A.; Maussner, G.

    1997-04-01

    In this paper, three leak rate computer programs for the application of leak before break analysis are described and compared. The programs are compared to each other and to results of an HDR Reactor experiment and two real crack cases. The programs analyzed are PIPELEAK, FLORA, and PICEP. Generally, the different leak rate models are in agreement. To obtain reasonable agreement between measured and calculated leak rates, it was necessary to also use data from detailed crack investigations.

  11. Benchmark calculations of thermal reaction rates. I - Quantal scattering theory

    NASA Technical Reports Server (NTRS)

    Chatfield, David C.; Truhlar, Donald G.; Schwenke, David W.

    1991-01-01

    The thermal rate coefficient for the prototype reaction H + H2 yields H2 + H with zero total angular momentum is calculated by summing, averaging, and numerically integrating state-to-state reaction probabilities calculated by time-independent quantum-mechanical scattering theory. The results are very carefully converged with respect to all numerical parameters in order to provide high-precision benchmark results for confirming the accuracy of new methods and testing their efficiency.

  12. Efficient calculation of atomic rate coefficients in dense plasmas

    NASA Astrophysics Data System (ADS)

    Aslanyan, Valentin; Tallents, Greg J.

    2017-03-01

    Modelling electron statistics in a cold, dense plasma by the Fermi-Dirac distribution leads to complications in the calculations of atomic rate coefficients. The Pauli exclusion principle slows down the rate of collisions as electrons must find unoccupied quantum states and adds a further computational cost. Methods to calculate these coefficients by direct numerical integration with a high degree of parallelism are presented. This degree of optimization allows the effects of degeneracy to be incorporated into a time-dependent collisional-radiative model. Example results from such a model are presented.

  13. Calculated emission rates for barium releases in space

    NASA Technical Reports Server (NTRS)

    Stenbaek-Nielsen, H. C.

    1989-01-01

    The optical emissions from barium releases in space are caused by resonance and fluorescent scattering of sunlight. Emission rates for the dominant ion and neutral lines are calculated assuming the release to be optically thin and the barium to be in radiative equilibrium with the solar radiation. The solar spectrum has deep Fraunhofer absorption lines at the primary barium ion resonances. A velocity component toward or away from the sun will Doppler shift the emission lines relative to the absorption lines and the emission rates will increase many-fold over the rest value. The Doppler brightening is important in shaped charge or satellite releases where the barium is injected at high velocities. Emission rates as a function of velocity are calculated for the 4554, 4934, 5854, 6142 and 6497 A ion emission lines and the dominant neutral line at 5535 A. Results are presented for injection parallel to the ambient magnetic field, B, and for injection at an angle to B.

  14. Semiclassical Calculation of Reaction Rate Constants for Homolytical Dissociations

    NASA Technical Reports Server (NTRS)

    Cardelino, Beatriz H.

    2002-01-01

    There is growing interest in extending organometallic chemical vapor deposition (OMCVD) to III-V materials that exhibit large thermal decomposition at their optimum growth temperature, such as indium nitride. The group III nitrides are candidate materials for light-emitting diodes and semiconductor lasers operating into the blue and ultraviolet regions. To overcome decomposition of the deposited compound, the reaction must be conducted at high pressures, which causes problems of uniformity. Microgravity may provide the venue for maintaining conditions of laminar flow under high pressure. Since the selection of optimized parameters becomes crucial when performing experiments in microgravity, efforts are presently geared to the development of computational OMCVD models that will couple the reactor fluid dynamics with its chemical kinetics. In the present study, we developed a method to calculate reaction rate constants for the homolytic dissociation of III-V compounds for modeling OMCVD. The method is validated by comparing calculations with experimental reaction rate constants.

  15. Uncertainties in the calculation of solar-neutrino capture rates

    SciTech Connect

    Filippone, B.W.

    1981-01-01

    A detailed estimate is presented of the possible uncertainty range for the neutrino flux from a standard solar model. Using present estimated errors in the key input parameters, detailed solar models are calculated to give an uncertainty in the theoretical nu/sub e/ capture rate in both the on-going /sup 37/Cl experiment and the proposed experiment using /sup 71/Ga. The uncertainty in capture rate is investigated by considering individual parameter variations about a mean model, by simultaneously varying several key parameters to yield upper and lower limits, and by a Monte Carlo method.

  16. NAC-1 cask dose rate calculations for LWR spent fuel

    SciTech Connect

    CARLSON, A.B.

    1999-02-24

    A Nuclear Assurance Corporation nuclear fuel transport cask, NAC-1, is being considered as a transport and storage option for spent nuclear fuel located in the B-Cell of the 324 Building. The loaded casks will be shipped to the 200 East Area Interim Storage Area for dry interim storage. Several calculations were performed to assess the photon and neutron dose rates. This report describes the analytical methods, models, and results of this investigation.

  17. Calculating Sputter Rate Angular Dependence Using Optical Profilometry (Preprint)

    DTIC Science & Technology

    2007-07-26

    This work attempts to determine angular dependence curves for sputter rates of a material based on a single experimental measurement. An aluminum...angular dependence curve to match the given erosion profile. The calculated profile matched well with the experimental profile; however, neither matched...the optimization routine, the angular dependence curve was input to the COLISEUM plasma modeling code, which generated the same erosion profile as the experimental data.

  18. [Calculating the intrinsic growth rate: comparison of definition and model].

    PubMed

    Voronov, D A

    2005-01-01

    It was shown that well known equation r = ln[N(t2)/N(t1)]/(t2 - t1) is the definition of the average value of intrinsic growth rate of population r within any given interval of time t2-t1 and changing arbitrarity its numbers N(t). The common opinion considering the equation as suitable only for exponentially growing population was found to be incorrect. The fundamentally different approach is based on the calculation of r within the framework of demographic model, realized as Euler - Lotka equation or population projection matrices. However this model requires simultaneous realization of several assumptions improbable for natural populations: exponential change in population size, stable age structure and maintaining constant age-dependent birth and death rates. The calculation of r by definition requires the data on the dynamics of population numbers, whereas calculation on the basis of the model requires the demographic tables of birth and death rate, but not the population numbers. With the example of American ginseng it was shown that evalution of r by definition and model approaches could produce opposite results.

  19. Calculating the Annihilation Rate of Weakly Interacting Massive Particles

    NASA Astrophysics Data System (ADS)

    Baumgart, Matthew; Rothstein, Ira Z.; Vaidya, Varun

    2015-05-01

    We develop a formalism that allows one to systematically calculate the weakly interacting massive particle (WIMP) annihilation rate into gamma rays whose energy far exceeds the weak scale. A factorization theorem is presented which separates the radiative corrections stemming from initial-state potential interactions from loops involving the final state. This separation allows us to go beyond the fixed order calculation, which is polluted by large infrared logarithms. For the case of Majorana WIMPs transforming in the adjoint representation of SU(2), we present the result for the resummed rate at leading double-log accuracy in terms of two initial-state partial-wave matrix elements and one hard matching coefficient. For a given model, one may calculate the cross section by finding the tree level matching coefficient and determining the value of a local four-fermion operator. The effects of resummation can be as large as 100% for a 20 TeV WIMP. However, for lighter WIMP masses relevant for the thermal relic scenario, leading-log resummation modifies the Sudakov factors only at the 10% level. Furthermore, given comparably sized Sommerfeld factors, the total effect of radiative corrections on the semi-inclusive photon annihilation rate is found to be percent level. The generalization of the formalism to other types of WIMPs is discussed.

  20. Divided Saddle Theory: A New Idea for Rate Constant Calculation.

    PubMed

    Daru, János; Stirling, András

    2014-03-11

    We present a theory of rare events and derive an algorithm to obtain rates from postprocessing the numerical data of a free energy calculation and the corresponding committor analysis. The formalism is based on the division of the saddle region of the free energy profile of the rare event into two adjacent segments called saddle domains. The method is built on sampling the dynamics within these regions: auxiliary rate constants are defined for the saddle domains and the absolute forward and backward rates are obtained by proper reweighting. We call our approach divided saddle theory (DST). An important advantage of our approach is that it requires only standard computational techniques which are available in most molecular dynamics codes. We demonstrate the potential of DST numerically on two examples: rearrangement of alanine-dipeptide (CH3CO-Ala-NHCH3) conformers and the intramolecular Cope reaction of the fluxional barbaralane molecule.

  1. Photolysis Rate Coefficient Calculations in Support of SOLVE II

    NASA Technical Reports Server (NTRS)

    Swartz, William H.

    2005-01-01

    A quantitative understanding of photolysis rate coefficients (or "j-values") is essential to determining the photochemical reaction rates that define ozone loss and other crucial processes in the atmosphere. j-Values can be calculated with radiative transfer models, derived from actinic flux observations, or inferred from trace gas measurements. The primary objective of the present effort was the accurate calculation of j-values in the Arctic twilight along NASA DC-8 flight tracks during the second SAGE III Ozone Loss and Validation Experiment (SOLVE II), based in Kiruna, Sweden (68 degrees N, 20 degrees E) during January-February 2003. The JHU/APL radiative transfer model was utilized to produce a large suite of j-values for photolysis processes (over 70 reactions) relevant to the upper troposphere and lower stratosphere. The calculations take into account the actual changes in ozone abundance and apparent albedo of clouds and the Earth surface along the aircraft flight tracks as observed by in situ and remote sensing platforms (e.g., EP-TOMS). A secondary objective was to analyze solar irradiance data from NCAR s Direct beam Irradiance Atmospheric Spectrometer (DIAS) on-board the NASA DC-8 and to start the development of a flexible, multi-species spectral fitting technique for the independent retrieval of O3,O2.02, and aerosol optical properties.

  2. User's guide to SERICPAC: A computer program for calculating electric-utility avoided costs rates

    SciTech Connect

    Wirtshafter, R.; Abrash, M.; Koved, M.; Feldman, S.

    1982-05-01

    SERICPAC is a computer program developed to calculate average avoided cost rates for decentralized power producers and cogenerators that sell electricity to electric utilities. SERICPAC works in tandem with SERICOST, a program to calculate avoided costs, and determines the appropriate rates for buying and selling of electricity from electric utilities to qualifying facilities (QF) as stipulated under Section 210 of PURA. SERICPAC contains simulation models for eight technologies including wind, hydro, biogas, and cogeneration. The simulations are converted in a diversified utility production which can be either gross production or net production, which accounts for an internal electricity usage by the QF. The program allows for adjustments to the production to be made for scheduled and forced outages. The final output of the model is a technology-specific average annual rate. The report contains a description of the technologies and the simulations as well as complete user's guide to SERICPAC.

  3. Calculate bit error rate for digital radio signal transmission

    NASA Astrophysics Data System (ADS)

    Sandberg, Jorgen

    1987-06-01

    A method for estimating symbol error rate caused by imperfect transmission channels is proposed. The method relates the symbol error rate to peak-to-peak amplitude and phase ripple, maximum gain slope, and maximum group delay distortion. The performance degradation of QPSK, offset QPSK (OQPSK), M-ary PSK (MSK) signals transmitted over a wideband channel, exhibiting either sinusoidal amplitude or phase ripples are evaluated using the proposed method. The transmission channel model, which is a single filter with transfer characteristics, for modeling the frequency of response of a system is described. Consideration is given to signal detection and system degradation. The calculations reveal that the QPSK modulated carrier degrades less then the OQPSK and MSK carriers for peak-to-peak amplitude ripple values less than 6 dB and peak-to-peak phase ripple values less than 45 deg.

  4. Calculation of vaporization rates assuming various rate determining steps: Application to the resistojet

    NASA Technical Reports Server (NTRS)

    May, C. E.

    1984-01-01

    The various steps that could control the vaporization rate of a material are discussed. These steps include the actual vaporization, flow rate of matrix gas, chemical reaction, gas diffusion, and solid state diffusion. The applicable equations have been collected from diverse appropriate sources, and their use is explained. Rate equations are derived for conditions where more than one step is rate controlling. Calculations are made for two model materials: rhenium which vaporizes congruently, and tantalum carbide which vaporizes incongruently. The case of vaporization under thermal gradient conditions is also treated. The existence of a thermal gradient in the resistojet means that the vaporization rate of a material may be only one thousandth of that predicted under isothermal conditions. Calculations show that rhenium might have a 100,000 hr lifetime at temperature in a 2500 C resistojet. Tantalum carbide would have a life of only 660 sec under similar conditions.

  5. 30 CFR 250.1632 - Production rates.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 2 2011-07-01 2011-07-01 false Production rates. 250.1632 Section 250.1632 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, REGULATION, AND ENFORCEMENT, DEPARTMENT OF THE... § 250.1632 Production rates. Each sulphur deposit shall be produced at rates that will provide...

  6. Relativistic collision rate calculations for electron-air interactions

    SciTech Connect

    Graham, G.; Roussel-Dupre, R.

    1992-12-16

    The most recent data available on differential cross sections for electron-air interactions are used to calculate the avalanche, momentum transfer, and energy loss rates that enter into the fluid equations. Data for the important elastic, inelastic, and ionizing processes are generally available out to electron energies of 1--10 kev. Prescriptions for extending these cross sections to the relativistic regime are presented. The angular dependence of the cross sections is included where data is available as is the doubly differential cross section for ionizing collisions. The collision rates are computed by taking moments of the Boltzmann collision integrals with the assumption that the electron momentum distribution function is given by the Juettner distribution function which satisfies the relativistic H- theorem and which reduces to the familiar Maxwellian velocity distribution in the nonrelativistic regime. The distribution function is parameterized in terms of the electron density, mean momentum, and thermal energy and the rates are therefore computed on a two-dimensional grid as a function of mean kinetic energy and thermal energy.

  7. Relativistic collision rate calculations for electron-air interactions

    SciTech Connect

    Graham, G.; Roussel-Dupre, R.

    1993-12-01

    The most recent data available on differential cross sections for electron-air interactions are used to calculate the avalanche, momentum transfer, and energy loss rates that enter into the fluid equations. Data for the important elastic, inelastic, and ionizing processes are generally available out to electron energies of 1--10 keV. Prescriptions for extending these cross sections to the relativistic regime are presented. The angular dependence of the cross sections is included where data are available as is the doubly differential cross section for ionizing collisions. The collision rates are computed by taking moments of the Boltzmann collision integrals with the assumption that the electron momentum distribution function is given by the Juettner distribution function which satisfies the relativistic H- theorem and which reduces to the familiar Maxwellian velocity distribution in the nonrelativistic regime. The distribution function is parameterized in terms of the electron density, mean momentum, and thermal energy and the rates are therefore computed on a two dimensional grid as a function of mean kinetic energy and thermal energy.

  8. Reference calculations for subthreshold Ξ production

    NASA Astrophysics Data System (ADS)

    Tomášik, Boris; Kolomeitsev, Evgeni E.

    2016-01-01

    We present a minimal statistical model designed for the description of rare- hadron multiplicities in nucleus-nucleus collisions at energies below the threshold of the particle production in binary elementary collisions. Differences to more conventional canonical statistical model are explained. The minimal statistical model is applied to the description of multiplicity ratios involving Ξ hyperons, which are measured by the HADES collaboration at GSI-SIS. It is argued that the HADES data cannot be reproduced by the model based on the statistical equilibrium and the strangeness conservation. The data remain underpredicted even when inmedium potentials acting on hadrons are taken into account. This hints to non-equilibrium production of the Ξ hyperons and their continuous freeze-out.

  9. A model to calculate the induced dose rate around an 18 MV ELEKTA linear accelerator.

    PubMed

    Perrin, Bruce; Walker, Anne; Mackay, Ranald

    2003-03-07

    The dose rate due to activity induced by (gamma, n) reactions around an ELEKTA Precise accelerator running at 18 MV is reported. A model to calculate the induced dose rate for a variety of working practices has been derived and compared to the measured values. From this model, the dose received by the staff using the machine can be estimated. From measured dose rates at the face of the linear accelerator for a 10 x 10 cm2 jaw setting at 18 MV an activation coefficient per MU was derived for each of the major activation products. The relative dose rates at points around the linac head, for different energy and jaw settings, were measured. Dose rates adjacent to the patient support system and portal imager were also measured. A model to calculate the dose rate at these points was derived, and compared to those measured over a typical working week. The model was then used to estimate the maximum dose to therapists for the current working schedule on this machine. Calculated dose rates at the linac face agreed to within +/- 12% of those measured over a week, with a typical dose rate of 4.5 microSv h(-1) 2 min after the beam has stopped. The estimated maximum annual whole body dose for a treatment therapist, with the machine treating at only 18 MV, for 60000 MUs per week was 2.5 mSv. This compares well with value of 2.9 mSv published for a Clinac 21EX. A model has been derived to calculate the dose from the four dominant activation products of an ELEKTA Precise 18 MV linear accelerator. This model is a useful tool to calculate the induced dose rate around the treatment head. The model can be used to estimate the dose to the staff for typical working patterns.

  10. 30 CFR 250.1632 - Production rates.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Production rates. 250.1632 Section 250.1632 Mineral Resources MINERALS MANAGEMENT SERVICE, DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Sulphur Operations § 250.1632 Production rates. Each...

  11. Examination of the semi-automatic calculation technique of vegetation cover rate by digital camera images.

    NASA Astrophysics Data System (ADS)

    Takemine, S.; Rikimaru, A.; Takahashi, K.

    The rice is one of the staple foods in the world High quality rice production requires periodically collecting rice growth data to control the growth of rice The height of plant the number of stem the color of leaf is well known parameters to indicate rice growth Rice growth diagnosis method based on these parameters is used operationally in Japan although collecting these parameters by field survey needs a lot of labor and time Recently a laborsaving method for rice growth diagnosis is proposed which is based on vegetation cover rate of rice Vegetation cover rate of rice is calculated based on discriminating rice plant areas in a digital camera image which is photographed in nadir direction Discrimination of rice plant areas in the image was done by the automatic binarization processing However in the case of vegetation cover rate calculation method depending on the automatic binarization process there is a possibility to decrease vegetation cover rate against growth of rice In this paper a calculation method of vegetation cover rate was proposed which based on the automatic binarization process and referred to the growth hysteresis information For several images obtained by field survey during rice growing season vegetation cover rate was calculated by the conventional automatic binarization processing and the proposed method respectively And vegetation cover rate of both methods was compared with reference value obtained by visual interpretation As a result of comparison the accuracy of discriminating rice plant areas was increased by the proposed

  12. Robust Biased Brownian Dynamics for Rate Constant Calculation

    PubMed Central

    Zou, Gang; Skeel, Robert D.

    2003-01-01

    A reaction probability is required to calculate the rate constant of a diffusion-dominated reaction. Due to the complicated geometry and potentially high dimension of the reaction probability problem, it is usually solved by a Brownian dynamics simulation, also known as a random walk or path integral method, instead of solving the equivalent partial differential equation by a discretization method. Building on earlier work, this article completes the development of a robust importance sampling algorithm for Brownian dynamics—i.e., biased Brownian dynamics with weight control—to overcome the high energy and entropy barriers in biomolecular association reactions. The biased Brownian dynamics steers sampling by a bias force, and the weight control algorithm controls sampling by a target weight. This algorithm is optimal if the bias force and the target weight are constructed from the solution of the reaction probability problem. In reality, an approximate reaction probability has to be used to construct the bias force and the target weight. Thus, the performance of the algorithm depends on the quality of the approximation. Given here is a method to calculate a good approximation, which is based on the selection of a reaction coordinate and the variational formulation of the reaction probability problem. The numerically approximated reaction probability is shown by computer experiments to give a factor-of-two speedup over the use of a purely heuristic approximation. Also, the fully developed method is compared to unbiased Brownian dynamics. The tests for human superoxide dismutase, Escherichia coli superoxide dismutase, and antisweetener antibody NC6.8, show speedups of 17, 35, and 39, respectively. The test for reactions between two model proteins with orientations shows speedups of 2578 for one set of configurations and 3341 for another set of configurations. PMID:14507681

  13. Calculation of Reactive-evaporation Rates of Chromia

    SciTech Connect

    Holcomb, G.R.

    2008-04-01

    A methodology is developed to calculate Cr-evaporation rates from Cr2O3 with a flat planar geometry. Variables include temperature, total pressure, gas velocity, and gas composition. The methodology was applied to solid-oxide, fuel cell conditions for metallic interconnects and to advanced-steam turbines conditions. The high velocities and pressures of the advanced steam turbine led to evaporation predictions as high as 5.18 9 10-8 kg/m2/s of CrO2(OH)2(g) at 760 °C and 34.5 MPa. This is equivalent to 0.080 mm per year of solid Cr loss. Chromium evaporation is expected to be an important oxidation mechanism with the types of nickel-base alloys proposed for use above 650 °C in advanced-steam boilers and turbines. It is shown that laboratory experiments, with much lower steam velocities and usually much lower total pressure than found in advanced steam turbines, would best reproduce chromium-evaporation behavior with atmospheres that approach either O2 + H2O or air + H2O with 57% H2O.

  14. 42 CFR 413.312 - Methodology for calculating rates.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... SERVICES; OPTIONAL PROSPECTIVELY DETERMINED PAYMENT RATES FOR SKILLED NURSING FACILITIES Prospectively Determined Payment Rates for Low-Volume Skilled Nursing Facilities, for Cost Reporting Periods...

  15. 42 CFR 413.312 - Methodology for calculating rates.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... SERVICES; OPTIONAL PROSPECTIVELY DETERMINED PAYMENT RATES FOR SKILLED NURSING FACILITIES Prospectively Determined Payment Rates for Low-Volume Skilled Nursing Facilities, for Cost Reporting Periods...

  16. 42 CFR 413.312 - Methodology for calculating rates.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... SERVICES; OPTIONAL PROSPECTIVELY DETERMINED PAYMENT RATES FOR SKILLED NURSING FACILITIES Prospectively Determined Payment Rates for Low-Volume Skilled Nursing Facilities, for Cost Reporting Periods...

  17. Code System to Calculate Integral Parameters with Reaction Rates from WIMS Output.

    SciTech Connect

    LESZCZYNSKI, FRANCISCO

    1994-10-25

    Version 00 REACTION calculates different integral parameters related to neutron reactions on reactor lattices, from reaction rates calculated with WIMSD4 code, and comparisons with experimental values.

  18. Effect of seeding rate on organic production

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Increased demand for organic rice (Oryza sativa L.) has incentivized producer conversion from conventional to organically-managed rice production in the U.S. Little is known on the impacts of seeding rate on organic rice production. A completely randomized factorial design with four replications was...

  19. 49 CFR 1141.1 - Procedures to calculate interest rates.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    .... Prime Rate as published by The Wall Street Journal. The rate levels will be determined as follows: (1... by The Wall Street Journal in effect on the day when the unlawful charge is paid. The interest rate in complaint proceedings shall be updated whenever The Wall Street Journal publishes a change to...

  20. 49 CFR 1141.1 - Procedures to calculate interest rates.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    .... Prime Rate as published by The Wall Street Journal. The rate levels will be determined as follows: (1... by The Wall Street Journal in effect on the day when the unlawful charge is paid. The interest rate in complaint proceedings shall be updated whenever The Wall Street Journal publishes a change to...

  1. Ultrasonic energy in liposome production: process modelling and size calculation.

    PubMed

    Barba, A A; Bochicchio, S; Lamberti, G; Dalmoro, A

    2014-04-21

    The use of liposomes in several fields of biotechnology, as well as in pharmaceutical and food sciences is continuously increasing. Liposomes can be used as carriers for drugs and other active molecules. Among other characteristics, one of the main features relevant to their target applications is the liposome size. The size of liposomes, which is determined during the production process, decreases due to the addition of energy. The energy is used to break the lipid bilayer into smaller pieces, then these pieces close themselves in spherical structures. In this work, the mechanisms of rupture of the lipid bilayer and the formation of spheres were modelled, accounting for how the energy, supplied by ultrasonic radiation, is stored within the layers, as the elastic energy due to the curvature and as the tension energy due to the edge, and to account for the kinetics of the bending phenomenon. An algorithm to solve the model equations was designed and the relative calculation code was written. A dedicated preparation protocol, which involves active periods during which the energy is supplied and passive periods during which the energy supply is set to zero, was defined and applied. The model predictions compare well with the experimental results, by using the energy supply rate and the time constant as fitting parameters. Working with liposomes of different sizes as the starting point of the experiments, the key parameter is the ratio between the energy supply rate and the initial surface area.

  2. Calculating coherent pair production with Monte Carlo methods

    SciTech Connect

    Bottcher, C.; Strayer, M.R.

    1989-01-01

    We discuss calculations of the coherent electromagnetic pair production in ultra-relativistic hadron collisions. This type of production, in lowest order, is obtained from three diagrams which contain two virtual photons. We discuss simple Monte Carlo methods for evaluating these classes of diagrams without recourse to involved algebraic reduction schemes. 19 refs., 11 figs.

  3. Comment on mesic-atom Auger-rate calculation

    NASA Astrophysics Data System (ADS)

    Altman, A.; Fried, Z.

    1983-07-01

    Auger rates for a mesic atom consisting of a lithium nucleus and two electrons are presented. It is shown that the results are sensitive to the screening of the initial and final state of the ejected electron by the spectator electron. These results are compared to transition rates one would obtain by following the procedure used by Burbridge and de Borde, which neglect screening of one electron by the others. Our results show a 40% reduction in transition rates.

  4. Calculation of kinetic rate constants from thermodynamic data

    NASA Technical Reports Server (NTRS)

    Marek, C. John

    1995-01-01

    A new scheme for relating the absolute value for the kinetic rate constant k to the thermodynamic constant Kp is developed for gases. In this report the forward and reverse rate constants are individually related to the thermodynamic data. The kinetic rate constants computed from thermodynamics compare well with the current kinetic rate constants. This method is self consistent and does not have extensive rules. It is first demonstrated and calibrated by computing the HBr reaction from H2 and Br2. This method then is used on other reactions.

  5. Production rates of cosmogenic nuclides in stony meteorites

    SciTech Connect

    Divadeenam, M.; Gabriel, T.A.; Lazareth, O.W.; Spergel, M.S.; Ward, T.E.

    1989-01-01

    Monte Carlo calculations of /sup 26/Al and /sup 53/Mn production due to spallation induced by cosmogenic protons in model meteorite composition similar to L Chondrite has yielded predictions which are consistent with the observed decay rates in L Chondrite stony meteorites. The calculated /sup 26/Al production rate (54 dpm/kg) in a 1 m diameter meteorite is within 1/2 S.D. of the mean (49 +- 11 dpm/kg) taken from 100 bulk determinations in L Chondrite samples compiled in Nishiizumi (1987). Similarly calculated average value for /sup 53/Mn (223 dpm/kg) is consistent with one S.D. off the mean in the widely scattered /sup 53/Mn data (362 +- 113 dpm/kg) compiled by Nishiizumi (1987). 9 refs.

  6. Understanding the biological activity of high rate algae ponds through the calculation of oxygen balances.

    PubMed

    Arbib, Zouhayr; de Godos Crespo, Ignacio; Corona, Enrique Lara; Rogalla, Frank

    2017-03-24

    Microalgae culture in high rate algae ponds (HRAP) is an environmentally friendly technology for wastewater treatment. However, for the implementation of these systems, a better understanding of the oxygenation potential and the influence of climate conditions is required. In this work, the rates of oxygen production, consumption, and exchange with the atmosphere were calculated under varying conditions of solar irradiance and dilution rate during six months of operation in a real scale unit. This analysis allowed determining the biological response of these dynamic systems. The rates of oxygen consumption measured were considerably higher than the values calculated based on the organic loading rate. The response to light intensity in terms of oxygen production in the bioreactor was described with one of the models proposed for microalgae culture in dense concentrations. This model is based on the availability of light inside the culture and the specific response of microalgae to this parameter. The specific response to solar radiation intensity showed a reasonable stability in spite of the fluctuations due to meteorological conditions. The methodology developed is a useful tool for optimization and prediction of the performance of these systems.

  7. 49 CFR 1141.1 - Procedures to calculate interest rates.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... (investment rate) of marketable securities of the United States Government having a duration of 91 days (3... all amounts received under the new rates (See 49 U.S.C. 10707(d)(1)). (2) For complaint proceedings... this section, coupon equivalent yields shall be considered “in effect” on the date the securities...

  8. Calculated nuclide compositions and gamma-ray exposure rates for fallout from the HARRY, SMOKY, and ANNIE events

    SciTech Connect

    Hicks, H.G.

    1981-03-03

    The results of computer calculations of the nuclide composition and associated external gamma-ray exposure rates for fallout from the HARRY, SMOKY, and ANNIE events are documented. The fission product distribution is calculated for each event with the appropriate neutron spectrum and the fractions of fissions due to each fissionable material. Also calculated are the total number of microcuries per square meter and the gamma-ray exposure rates (mR/h, 1 meter above ground level) for the 152 fission products and 25 neutron-induced nuclides. The normalized data are presented in 9 Appendices. (DLS)

  9. 42 CFR 413.312 - Methodology for calculating rates.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 413.312 Public Health CENTERS FOR MEDICARE & MEDICAID SERVICES, DEPARTMENT OF HEALTH AND HUMAN SERVICES MEDICARE PROGRAM PRINCIPLES OF REASONABLE COST REIMBURSEMENT; PAYMENT FOR END-STAGE RENAL DISEASE SERVICES; OPTIONAL PROSPECTIVELY DETERMINED PAYMENT RATES FOR SKILLED NURSING FACILITIES...

  10. Rate of nova production in the Galaxy

    SciTech Connect

    Liller, W.; Mayer, B.

    1987-07-01

    The ongoing PROBLICOM program in the Southern Hemisphere now makes it possible to derive a reliable value for the overall production rate of Galactic novae. The results, 73 + or - 24/y, indicates that the Galaxy outproduces M 31 by a factor of two or three. It is estimated that the rate of supernova ejecta is one and a half orders of magnitude greater than that of novae in the Galaxy. 15 references.

  11. Polymer reversal rate calculated via locally scaled diffusion map.

    PubMed

    Zheng, Wenwei; Rohrdanz, Mary A; Maggioni, Mauro; Clementi, Cecilia

    2011-04-14

    A recent study on the dynamics of polymer reversal inside a nanopore by Huang and Makarov [J. Chem. Phys. 128, 114903 (2008)] demonstrated that the reaction rate cannot be reproduced by projecting the dynamics onto a single empirical reaction coordinate, a result suggesting the dynamics of this system cannot be correctly described by using a single collective coordinate. To further investigate this possibility we have applied our recently developed multiscale framework, locally scaled diffusion map (LSDMap), to obtain collective reaction coordinates for this system. Using a single diffusion coordinate, we obtain a reversal rate via Kramers expression that is in good agreement with the exact rate obtained from the simulations. Our mathematically rigorous approach accounts for the local heterogeneity of molecular configuration space in constructing a diffusion map, from which collective coordinates emerge. We believe this approach can be applied in general to characterize complex macromolecular dynamics by providing an accurate definition of the collective coordinates associated with processes at different time scales.

  12. 7 CFR 760.811 - Rates and yields; calculating payments.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... established by the State committee as authorized by the Deputy Administrator, when there is supporting data from NASS or other sources approved by FSA that show there is a significant difference in yield or... average market price times 42 percent, times the loss of production which exceeds 35 percent of...

  13. Calculating the College-to-University Transfer Rate in Ontario

    ERIC Educational Resources Information Center

    Decock, Henry

    2004-01-01

    Measuring transfer is as varied as it is controversial, particularly in an era of increased accountability and in the case of Ontario Colleges, in a time of flux and change. American Community Colleges have been grappling with the definition of a transfer rate, continuing to fail on reaching a consensus. The importance of an acceptable transfer…

  14. Sample size calculation for comparing two negative binomial rates.

    PubMed

    Zhu, Haiyuan; Lakkis, Hassan

    2014-02-10

    Negative binomial model has been increasingly used to model the count data in recent clinical trials. It is frequently chosen over Poisson model in cases of overdispersed count data that are commonly seen in clinical trials. One of the challenges of applying negative binomial model in clinical trial design is the sample size estimation. In practice, simulation methods have been frequently used for sample size estimation. In this paper, an explicit formula is developed to calculate sample size based on the negative binomial model. Depending on different approaches to estimate the variance under null hypothesis, three variations of the sample size formula are proposed and discussed. Important characteristics of the formula include its accuracy and its ability to explicitly incorporate dispersion parameter and exposure time. The performance of the formula with each variation is assessed using simulations.

  15. Influence of sampling rate on the calculated fidelity of an aircraft simulation

    NASA Technical Reports Server (NTRS)

    Howard, J. C.

    1983-01-01

    One of the factors that influences the fidelity of an aircraft digital simulation is the sampling rate. As the sampling rate is increased, the calculated response of the discrete representation tends to coincide with the response of the corresponding continuous system. Because of computer limitations, however, the sampling rate cannot be increased indefinitely. Moreover, real-time simulation requirements demand that a finite sampling rate be adopted. In view of these restrictions, a study was undertaken to determine the influence of sampling rate on the response characteristics of a simulated aircraft describing short-period oscillations. Changes in the calculated response characteristics of the simulated aircraft degrade the fidelity of the simulation. In the present context, fidelity degradation is defined as the percentage change in those characteristics that have the greatest influence on pilot opinion: short period frequency omega, short period damping ratio zeta, and the product omega zeta. To determine the influence of the sampling period on these characteristics, the equations describing the response of a DC-8 aircraft to elevator control inputs were used. The results indicate that if the sampling period is too large, the fidelity of the simulation can be degraded.

  16. Theoretical study and rate constant calculation of the CH2O+CH3 reaction

    NASA Astrophysics Data System (ADS)

    Liu, Jing-yao; Li, Ze-sheng; Wu, Jia-yan; Wei, Zhi-gang; Zhang, Gang; Sun, Chia-chung

    2003-10-01

    The potential energy surface of the CH2O+CH3 reaction is explored at the MP2/6-311++G(d,p), MP4SDQ/6-311G(d,p), and QCISD(T)/6-311+G(3df,2p) (single point) levels of theory. Theoretical calculations suggest that the major product channel (R1) is the hydrogen abstraction leading to the product P1 CHO+CH4 (R1), while the addition process leading to P2H+CH3CHO (R2) appears to be negligibly small. The calculated enthalpies and dissociation activation energies for CH3CH2O and CH3OCH2 radicals involved in the reaction are in line with the experimental values. Dual-level dynamics calculation is carried out for the direct hydrogen abstraction channel. The energy profile of (R1) is refined with the interpolated single-point energies (ISPE) method at the QCISD(T)//MP2 level. The rate constants, which are evaluated by canonical variational transition-state theory (CVT) including small-curvature tunneling (SCT) correction, are in good agreement with the available experimental data. It is shown that tunneling effect plays a significant role in the rate constant calculation; and as a result, the CVT/SCT rate constants exhibit typical non-Arrhenius behavior over a wide temperature range 300-2000 K. The three parameter expression is k=6.35×10-26 T4.4 exp(-2450/T) cm3 molecule-1 s-1.

  17. Technical note: Consistent calculation of aquatic gross production from oxygen triple isotope measurements

    NASA Astrophysics Data System (ADS)

    Kaiser, J.

    2011-07-01

    Oxygen triple isotope measurements can be used to calculate aquatic gross oxygen production rates. Past studies have emphasised the appropriate definition of the 17O excess and often used an approximation to derive production rates from the 17O excess. Here, I show that the calculation can be phrased more consistently and without any approximations using the relative 17O/16O and 18O/16O isotope ratio differences (delta values) directly. I call this the "dual delta method". The 17O excess is merely a mathematical construct and the derived production rate is independent of its definition, provided all calculations are performed with a consistent definition. I focus on the mixed layer, but also show how time series of triple isotope measurements below the mixed layer can be used to derive gross production. In the calculation of mixed layer productivity, I explicitly include isotopic fractionation during gas invasion and evasion, which requires the oxygen supersaturation s to be measured as well. I also suggest how bubble injection could be considered in the same mathematical framework. I distinguish between concentration steady state and isotopic steady state and show that only the latter needs to be assumed in the calculation. It is even possible to derive an estimate of the net production rate in the mixed layer that is independent of the assumption of concentration steady state. I review measurements of the parameters required for the calculation of gross production rates and show how their systematic uncertainties as well as the use of different published calculation methods can cause large variations in the production rates for the same underlying isotope ratios. In particular, the 17O excess of dissolved O2 in equilibrium with atmospheric O2 and the 17O excess of photosynthetic O2 need to be re-measured. Because of these uncertainties, all calculation parameters should always be fully documented and the measured relative isotope ratio differences as well as the

  18. Consistent calculation of aquatic gross production from oxygen triple isotope measurements

    NASA Astrophysics Data System (ADS)

    Kaiser, J.

    2011-04-01

    Oxygen triple isotope measurements can be used to calculate aquatic gross oxygen production rates. Past studies have emphasised the appropriate definition of the 17O excess and often used an approximation to derive production rates from the 17O excess. Here, I show that the calculation can be phrased more consistently and without any approximations using the relative 17O/16O and 18O/16O isotope ratio differences directly. The 17O excess is merely a mathematical construct and the derived production rate is independent of its definition, provided all calculations are performed with a consistent definition. I focus on the mixed layer, but also show how time series of triple oxygen measurements below the mixed layer can be used to derive gross production. In the calculation of mixed layer productivity, I explicitly include isotopic fractionation during gas invasion and evasion, which requires the oxygen supersaturation s to be measured as well. I also suggest how bubble injection could be considered in the same mathematical framework. I distinguish between concentration steady state and isotopic steady state and show that only the latter needs to be assumed in the calculation. It is even possible to derive an estimate of the net production rate in the mixed layer that is independent of the assumption of concentration steady state. I review measurements of the parameters required for the calculation of gross production rates and show how their systematic uncertainties as well as the use of different published calculation methods can cause large variations in the production rates for the same underlying isotope ratios. In particular, the 17O excess of dissolved O2 in equilibrium with atmospheric O2 and the 17O excess of photosynthetic O2 need to be re-measured. Because of these uncertainties, all calculation parameters should always be fully documented and the measured isotope ratio differences as well as the oxygen supersaturation should be permanently archived, so that

  19. Personal computer program and spreadsheet for calculating the coal mine roof rating (CMRR). Information circular/1994

    SciTech Connect

    Riefenberg, J.; Wuest, W.J.

    1994-01-01

    A family of personal computer programs that calculate the Coal Mine Roof Rating (CMRR) have been developed by the U.S. Bureau of Mines. The CMRR, rock mass classification system, was recently developed by Bureau researchers to provide a link between the qualitative geologists' description of coal mine roof and the quantitive mine engineers' needs for mine design, roof support selection, and hazard detection. The program CMRR, is a user-friendly, interactive program into which raw field data are input, and a CMRR is calculated and output along with two graphic displays. The first graphic display is a plan view map with the roof ratings displayed on a color-coded scale, and the second display shows a stratigraphic section of the bolted roof interval and its resultant roof rating. In addition, a Lotus 1-2-3 worksheet, BOM-CMRR.WK3, has been developed for easy storage of field data. The worksheet also includes macros developed for calculation and storage of the CMRR. Production of summary reports for analysis of site-specific information are readily generated using Lotus. These programs help to facilitate the engineer in utilizing the CMRR in ground control studies.

  20. Dose Rate Calculation of TRU Metal Ingot in Pyroprocessing - 12202

    SciTech Connect

    Lee, Yoon Hee; Lee, Kunjai

    2012-07-01

    Spent fuel management has been a main problem to be solved for continuous utilization of nuclear energy. Spent fuel management policy of Korea is 'Wait and See'. It is focused on Pyro-process and SFR (Sodium-cooled Fast Reactor) for closed-fuel cycle research and development in Korea. For peaceful use of nuclear facilities, the proliferation resistance has to be proved. Proliferation resistance is one of key constraints in the deployment of advanced nuclear energy systems. Non-proliferation and safeguard issues have been strengthening internationally. Barriers to proliferation are that reduces desirability or attractiveness as an explosive and makes it difficult to gain access to the materials, or makes it difficult to misuse facilities and/or technologies for weapons applications. Barriers to proliferation are classified into intrinsic and extrinsic barriers. Intrinsic barrier is inherent quality of reactor materials or the fuel cycle that is built into the reactor design and operation such as material and technical barriers. As one of the intrinsic measures, the radiation from the material is considered significantly. Therefore the radiation of TRU metal ingot from the pyro-process was calculated using ORIGEN and MCNP code. (authors)

  1. Calculations on decay rates of various proton emissions

    NASA Astrophysics Data System (ADS)

    Qian, Yibin; Ren, Zhongzhou

    2016-03-01

    Proton radioactivity of neutron-deficient nuclei around the dripline has been systematically studied within the deformed density-dependent model. The crucial proton-nucleus potential is constructed via the single-folding integral of the density distribution of daughter nuclei and the effective M3Y nucleon-nucleon interaction or the proton-proton Coulomb interaction. After the decay width is obtained by the modified two-potential approach, the final decay half-lives can be achieved by involving the spectroscopic factors from the relativistic mean-field (RMF) theory combined with the BCS method. Moreover, a simple formula along with only one adjusted parameter is tentatively proposed to evaluate the half-lives of proton emitters, where the introduction of nuclear deformation is somewhat discussed as well. It is found that the calculated results are in satisfactory agreement with the experimental values and consistent with other theoretical studies, indicating that the present approach can be applied to the case of proton emission. Predictions on half-lives are made for possible proton emitters, which may be useful for future experiments.

  2. 76 FR 5518 - Antidumping Proceedings: Calculation of the Weighted Average Dumping Margin and Assessment Rate...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-02-01

    ... International Trade Administration 19 CFR Part 351 RIN 0625-AA87 Antidumping Proceedings: Calculation of the... regarding the calculation of the weighted average dumping margin and antidumping duty assessment rate in... regarding the calculation of the weighted average dumping margin and antidumping duty assessment rate...

  3. Towards a Model for Protein Production Rates

    NASA Astrophysics Data System (ADS)

    Dong, J. J.; Schmittmann, B.; Zia, R. K. P.

    2007-07-01

    In the process of translation, ribosomes read the genetic code on an mRNA and assemble the corresponding polypeptide chain. The ribosomes perform discrete directed motion which is well modeled by a totally asymmetric simple exclusion process (TASEP) with open boundaries. Using Monte Carlo simulations and a simple mean-field theory, we discuss the effect of one or two "bottlenecks" (i.e., slow codons) on the production rate of the final protein. Confirming and extending previous work by Chou and Lakatos, we find that the location and spacing of the slow codons can affect the production rate quite dramatically. In particular, we observe a novel "edge" effect, i.e., an interaction of a single slow codon with the system boundary. We focus in detail on ribosome density profiles and provide a simple explanation for the length scale which controls the range of these interactions.

  4. Methodology for calculation of carbon balances for biofuel crops production

    NASA Astrophysics Data System (ADS)

    Gerlfand, I.; Hamilton, S. K.; Snapp, S. S.; Robertson, G. P.

    2012-04-01

    Understanding the carbon balance implications for different biofuel crop production systems is important for the development of decision making tools and policies. We present here a detailed methodology for assessing carbon balances in agricultural and natural ecosystems. We use 20 years of data from Long-term Ecological Research (LTER) experiments at the Kellogg Biological Station (KBS), combined with models to produce farm level CO2 balances for different management practices. We compared four grain and one forage systems in the U.S. Midwest: corn (Zea mays) - soybean (Glycine max) - wheat (Triticum aestivum) rotations managed with (1) conventional tillage, (2) no till, (3) low chemical input, and (4) biologically-based (organic) practices; and (5) continuous alfalfa (Medicago sativa). In addition we use an abandoned agricultural field (successionnal ecosystem) as reference system. Measurements include fluxes of N2O and CH4, soil organic carbon change, agricultural yields, and agricultural inputs (e.g. fertilization and farm fuel use). In addition to measurements, we model carbon offsets associated with the use of bioenergy from agriculturally produced crops. Our analysis shows the importance of establishing appropriate system boundaries for carbon balance calculations. We explore how different assumptions regarding production methods and emission factors affect overall conclusions on carbon balances of different agricultural systems. Our results show management practices that have major the most important effects on carbon balances. Overall, agricultural management with conventional tillage was found to be a net CO2 source to the atmosphere, while agricultural management under reduced tillage, low input, or organic management sequestered carbon at rates of 93, -23, -51, and -14 g CO2e m-2 yr-1, respectively for conventionally tilled, no-till, low-input, and organically managed ecosystems. Perennial systems (alfalfa and the successionnal fields) showed net carbon

  5. The effect of direct positron production on relativistic feedback rates

    NASA Astrophysics Data System (ADS)

    Vodopiyanov, I. B.; Dwyer, J. R.; Lucia, R. J.; Cramer, E. S.; Arabshahi, S.; Rassoul, H.

    2013-12-01

    Relativistic feedback produces a self-sustaining runaway electron discharge via the production of backward propagating positrons and back-scattered x-rays. To date, only positrons created from pair-production by gamma-rays interacting with the air have been considered. In contrast, direct pair-production involves the creation of electron-positron pairs directly from the interaction of energetic runaway electrons with nuclei, and so it does not require the generation of bremsstrahlung gamma-rays. For high electric fields, where the runaway electron avalanche length scales are short, pair-production involving bremsstrahlung gamma-rays makes a smaller contribution to the total relativistic feedback rates than at lower fields, since both the bremsstrahlung interaction and the pair-production need to occur over a short length. On the other hand, for high fields, because direct positron production only involves one interaction, it may make a significant contribution to relativistic feedback rates in some cases. In this poster, we shall present the direct positron production cross-sections and calculate the effects on the relativistic feedback rates due to this process.

  6. 42 CFR 413.337 - Methodology for calculating the prospective payment rates.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ...-STAGE RENAL DISEASE SERVICES; OPTIONAL PROSPECTIVELY DETERMINED PAYMENT RATES FOR SKILLED NURSING FACILITIES Prospective Payment for Skilled Nursing Facilities § 413.337 Methodology for calculating...

  7. Predicting the production rates of cosmogenic nuclides in extraterrestrial matter

    SciTech Connect

    Reedy, R.C.

    1987-01-01

    The production rates of nuclides made by the galactic and solar cosmic rays are important in the interpretations of measurements made with lunar samples, meteorites, and cosmic spherules. Production rates of cosmogenic nuclides have been predicted by a variety of methods that are reviewed in this paper, ranging from systematic studies of one or a group of meteorites to purely theoretical calculations. Production rates can vary with the chemical composition and the preatmospheric depth of the sample and with the size and shape of the object. While the production systematics for cosmogenic nuclides are fairly well known, our ability to predict their production rates can be improved, with a corresponding increase in the scientific return. Additional detailed studies of cosmogenic nuclides in extraterrestrial objects are needed, especially for fairly small and very large objects. Nuclides made in simulation experiments and cross sections for many major nuclear reactions should be measured. Such studies are especially needed for the long-lived radionuclides that have only recently become readily measurable by accelerator mass spectrometry. 34 refs., 5 figs.

  8. ATMS Snowfall Rate Product and Its Applications

    NASA Astrophysics Data System (ADS)

    Meng, H.; Kongoli, C.; Dong, J.; Wang, N. Y.; Ferraro, R. R.; Zavodsky, B.; Banghua Yan, B.

    2015-12-01

    A snowfall rate (SFR) algorithm has been developed for the Advanced Technology Microwave Sounder (ATMS) aboard S-NPP and future JPSS satellites. The product is based on the NOAA/NESDIS operational Microwave Humidity Sounder (MHS) SFR but with several key advancements. The algorithm has benefited from continuous development to improve accuracy and snowfall detection efficiency. The enhancements also expand the applicable temperature range for the algorithm and allow significantly more snowfall to be detected than the operational SFR. Another major improvement is the drastically reduced product latency by using Direct Broadcast (DB) data. The new developments have also been implemented in the MHS SFR to ensure product consistency across satellites. Currently, there are five satellites that carry either ATMS or MHS: S-NPP, NOAA-18/-19 and Metop-A/-B. The combined satellites deliver up to ten SFR estimates a day at any location over land in mid-latitudes. The product provides much needed winter precipitation estimates for applications such as weather forecasting and hydrology. Both ATMS and MHS SFR serve as input to a global precipitation analysis product, the NOAA/NCEP CMORPH-Snow. SFR is the sole satellite-based snowfall estimates in the blended product. In addition, ATMS and MHS SFR was assessed at several NWS Weather Forecast Offices (WFOs) and NESDIS/Satellite Analysis Branch (SAB) for its operational values in winter 2015. This is a joint effort among NASA/SPoRT, NOAA/NESDIS, University of Maryland/CICS, and the WFOs. The feedback from the assessment indicated that SFR provides useful information for snowfall forecast. It is especially valuable for areas with poor radar coverage and ground observations. The feedback also identified some limitations of the product such as inadequate detection of shallow snowfall. The algorithm developers will continue to improve product quality as well as developing SFR for new microwave sensors and over ocean in a project

  9. Using a Calculated Pulse Rate with an Artificial Neural Network to Detect Irregular Interbeats.

    PubMed

    Yeh, Bih-Chyun; Lin, Wen-Piao

    2016-03-01

    Heart rate is an important clinical measure that is often used in pathological diagnosis and prognosis. Valid detection of irregular heartbeats is crucial in the clinical practice. We propose an artificial neural network using the calculated pulse rate to detect irregular interbeats. The proposed system measures the calculated pulse rate to determine an "irregular interbeat on" or "irregular interbeat off" event. If an irregular interbeat is detected, the proposed system produces a danger warning, which is helpful for clinicians. If a non-irregular interbeat is detected, the proposed system displays the calculated pulse rate. We include a flow chart of the proposed software. In an experiment, we measure the calculated pulse rates and achieve an error percentage of < 3% in 20 participants with a wide age range. When we use the calculated pulse rates to detect irregular interbeats, we find such irregular interbeats in eight participants.

  10. Approximate Method of Calculating Heating Rates at General Three-Dimensional Stagnation Points During Atmospheric Entry

    NASA Technical Reports Server (NTRS)

    Hamilton, H. H., II

    1982-01-01

    An approximate method for calculating heating rates at general three dimensional stagnation points is presented. The application of the method for making stagnation point heating calculations during atmospheric entry is described. Comparisons with results from boundary layer calculations indicate that the method should provide an accurate method for engineering type design and analysis applications.

  11. 40 CFR 75.83 - Calculation of Hg mass emissions and heat input rate.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Calculation of Hg mass emissions and... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Hg Mass Emission Provisions § 75.83 Calculation of Hg mass emissions and heat input rate. The owner or operator shall calculate Hg mass...

  12. STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE

    SciTech Connect

    HU, T.A.

    2005-10-27

    Assess the steady-state flammability level at normal and off-normal ventilation conditions. The hydrogen generation rate was calculated for 177 tanks using the rate equation model. Flammability calculations based on hydrogen, ammonia, and methane were performed for 177 tanks for various scenarios.

  13. STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE

    SciTech Connect

    HU TA

    2009-10-26

    Assess the steady-state flammability level at normal and off-normal ventilation conditions. The hydrogen generation rate was calculated for 177 tanks using the rate equation model. Flammability calculations based on hydrogen, ammonia, and methane were performed for 177 tanks for various scenarios.

  14. Calculation of the cross section for top quark production

    SciTech Connect

    Berger, E.L.; Contopanagos, H.

    1996-06-21

    The authors summarize calculations of the cross section for top quark production at hadron colliders within the context of perturbative quantum chromodynamics, including resummation of the effects of initial-state soft gluon radiation to all orders in the strong coupling strength. In their approach they resume the universal leading-logarithm contributions, and they restrict the calculation to the region of phase space that is demonstrably perturbative. They compare the approach with other methods. They present predictions of the physical cross section as a function of the top quark mass in proton-antiproton reactions at center-of-mass energies of 1.8 and 2.0 TeV, and they discuss estimated uncertainties.

  15. Maximum entropy production rate in quantum thermodynamics

    NASA Astrophysics Data System (ADS)

    Beretta, Gian Paolo

    2010-06-01

    In the framework of the recent quest for well-behaved nonlinear extensions of the traditional Schrödinger-von Neumann unitary dynamics that could provide fundamental explanations of recent experimental evidence of loss of quantum coherence at the microscopic level, a recent paper [Gheorghiu-Svirschevski 2001 Phys. Rev. A 63 054102] reproposes the nonlinear equation of motion proposed by the present author [see Beretta G P 1987 Found. Phys. 17 365 and references therein] for quantum (thermo)dynamics of a single isolated indivisible constituent system, such as a single particle, qubit, qudit, spin or atomic system, or a Bose-Einstein or Fermi-Dirac field. As already proved, such nonlinear dynamics entails a fundamental unifying microscopic proof and extension of Onsager's reciprocity and Callen's fluctuation-dissipation relations to all nonequilibrium states, close and far from thermodynamic equilibrium. In this paper we propose a brief but self-contained review of the main results already proved, including the explicit geometrical construction of the equation of motion from the steepest-entropy-ascent ansatz and its exact mathematical and conceptual equivalence with the maximal-entropy-generation variational-principle formulation presented in Gheorghiu-Svirschevski S 2001 Phys. Rev. A 63 022105. Moreover, we show how it can be extended to the case of a composite system to obtain the general form of the equation of motion, consistent with the demanding requirements of strong separability and of compatibility with general thermodynamics principles. The irreversible term in the equation of motion describes the spontaneous attraction of the state operator in the direction of steepest entropy ascent, thus implementing the maximum entropy production principle in quantum theory. The time rate at which the path of steepest entropy ascent is followed has so far been left unspecified. As a step towards the identification of such rate, here we propose a possible, well

  16. Calculations of long-lived isomer production in neutron reactions

    SciTech Connect

    Chadwick, M.B.; Young, P.G.

    1991-01-01

    We have carried out theoretical calculations for the production of the long-lived isomers {sup 93m}Nb({1/2}{sup {minus}}, 16y), {sup 121m}Sn(11/2{minus}, 55 yr), {sup 166m}Ho(7-, 1200 yr), {sup 184m}Re(8+, 165 d), {sup 186m}Re(8+, 2{times}10{sup 5} yr), {sup 178m}Hf(16+, 31 yr), {sup 179m}Hf(25/2-, 25 d), {sup 192m}Ir(9+, 241 yr), all of which pose potential radiation activation problems in nuclear fusion reactors. We consider (n, 2n), (n,n{prime}), and (n, {gamma}) production modes and compare our results both with experimental data (where available) and systematic. We also investigate the dependence of the isomeric cross section ratio on incident neutron energy for the isomers under consideration. The statistical Hauser-Feshbach plus preequilibrium code GNASH was used for the calculations. Where discrete state experimental information was lacking, rotational band members above the isomeric state, which can be justified theoretically but have not been experimentally resolved, were reconstructed. 16 refs., 8 figs.

  17. Dynamical coupled channels calculation of pion and omega meson production

    SciTech Connect

    Paris, Mark W.

    2009-02-15

    The dynamical coupled-channels approach developed at the Excited Baryon Analysis Center is extended to include the {omega}N channel to study {pi}- and {omega}-meson production induced by scattering pions and photons from the proton. Six intermediate channels, including {pi}N, {eta}N, {pi}{delta}, {sigma}N, {rho}N, and {omega}N, are employed to describe unpolarized and polarized data. Bare parameters in an effective hadronic Lagrangian are determined in a fit to the data for {pi}N{yields}{pi}N, {gamma}N{yields}{pi}N, {pi}{sup -}p{yields}{omega}n, and {gamma}p{yields}{omega}p reactions at center-of-mass energies from threshold to W<2.0 GeV. The T matrix determined in these fits is used to calculate the photon beam asymmetry for {omega}-meson production and the {omega}N{yields}{omega}N total cross section and {omega}N-scattering lengths. The calculated beam asymmetry is in good agreement with the observed in the range of energies near threshold to W < or approx. 2.0 GeV.

  18. 42 CFR 413.337 - Methodology for calculating the prospective payment rates.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... excluded from the data base used to compute the Federal payment rates. In addition, allowable costs related to exceptions payments under § 413.30(f) are excluded from the data base used to compute the Federal... prospective payment rates. (a) Data used. (1) To calculate the prospective payment rates, CMS uses—...

  19. 42 CFR 413.337 - Methodology for calculating the prospective payment rates.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... excluded from the data base used to compute the Federal payment rates. In addition, allowable costs related to exceptions payments under § 413.30(f) are excluded from the data base used to compute the Federal... prospective payment rates. (a) Data used. (1) To calculate the prospective payment rates, CMS uses—...

  20. 42 CFR 413.337 - Methodology for calculating the prospective payment rates.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... excluded from the data base used to compute the Federal payment rates. In addition, allowable costs related to exceptions payments under § 413.30(f) are excluded from the data base used to compute the Federal... prospective payment rates. (a) Data used. (1) To calculate the prospective payment rates, CMS uses—...

  1. 42 CFR 413.337 - Methodology for calculating the prospective payment rates.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... excluded from the data base used to compute the Federal payment rates. In addition, allowable costs related to exceptions payments under § 413.30(f) are excluded from the data base used to compute the Federal... prospective payment rates. (a) Data used. (1) To calculate the prospective payment rates, CMS uses—...

  2. The Multi-Step CADIS method for shutdown dose rate calculations and uncertainty propagation

    DOE PAGES

    Ibrahim, Ahmad M.; Peplow, Douglas E.; Grove, Robert E.; ...

    2015-12-01

    Shutdown dose rate (SDDR) analysis requires (a) a neutron transport calculation to estimate neutron flux fields, (b) an activation calculation to compute radionuclide inventories and associated photon sources, and (c) a photon transport calculation to estimate final SDDR. In some applications, accurate full-scale Monte Carlo (MC) SDDR simulations are needed for very large systems with massive amounts of shielding materials. However, these simulations are impractical because calculation of space- and energy-dependent neutron fluxes throughout the structural materials is needed to estimate distribution of radioisotopes causing the SDDR. Biasing the neutron MC calculation using an importance function is not simple becausemore » it is difficult to explicitly express the response function, which depends on subsequent computational steps. Furthermore, the typical SDDR calculations do not consider how uncertainties in MC neutron calculation impact SDDR uncertainty, even though MC neutron calculation uncertainties usually dominate SDDR uncertainty.« less

  3. The Multi-Step CADIS method for shutdown dose rate calculations and uncertainty propagation

    SciTech Connect

    Ibrahim, Ahmad M.; Peplow, Douglas E.; Grove, Robert E.; Peterson, Joshua L.; Johnson, Seth R.

    2015-12-01

    Shutdown dose rate (SDDR) analysis requires (a) a neutron transport calculation to estimate neutron flux fields, (b) an activation calculation to compute radionuclide inventories and associated photon sources, and (c) a photon transport calculation to estimate final SDDR. In some applications, accurate full-scale Monte Carlo (MC) SDDR simulations are needed for very large systems with massive amounts of shielding materials. However, these simulations are impractical because calculation of space- and energy-dependent neutron fluxes throughout the structural materials is needed to estimate distribution of radioisotopes causing the SDDR. Biasing the neutron MC calculation using an importance function is not simple because it is difficult to explicitly express the response function, which depends on subsequent computational steps. Furthermore, the typical SDDR calculations do not consider how uncertainties in MC neutron calculation impact SDDR uncertainty, even though MC neutron calculation uncertainties usually dominate SDDR uncertainty.

  4. 76 FR 20220 - New Formulas for Calculating the Basetime, Overtime, Holiday, and Laboratory Services Rates; Rate...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-12

    ... laboratories to conduct analyses of official meat and poultry samples. The Food, Agriculture, Conservation, and..., except on those occasions when demand exceeds supply for their products. In addition, the costs that... inelastic nature of the demand curve facing consumers. Research has shown that consumers are unlikely...

  5. Carbon footprint of Canadian dairy products: calculations and issues.

    PubMed

    Vergé, X P C; Maxime, D; Dyer, J A; Desjardins, R L; Arcand, Y; Vanderzaag, A

    2013-09-01

    The Canadian dairy sector is a major industry with about 1 million cows. This industry emits about 20% of the total greenhouse gas (GHG) emissions from the main livestock sectors (beef, dairy, swine, and poultry). In 2006, the Canadian dairy herd produced about 7.7 Mt of raw milk, resulting in about 4.4 Mt of dairy products (notably 64% fluid milk and 12% cheese). An integrated cradle-to-gate model (field to processing plant) has been developed to estimate the carbon footprint (CF) of 11 Canadian dairy products. The on-farm part of the model is the Unified Livestock Industry and Crop Emissions Estimation System (ULICEES). It considers all GHG emissions associated with livestock production but, for this study, it was run for the dairy sector specifically. Off-farm GHG emissions were estimated using the Canadian Food Carbon Footprint calculator, (cafoo)(2)-milk. It considers GHG emissions from the farm gate to the exit gate of the processing plants. The CF of the raw milk has been found lower in western provinces [0.93 kg of CO2 equivalents (CO2e)/L of milk] than in eastern provinces (1.12 kg of CO2e/L of milk) because of differences in climate conditions and dairy herd management. Most of the CF estimates of dairy products ranged between 1 and 3 kg of CO2e/kg of product. Three products were, however, significantly higher: cheese (5.3 kg of CO2e/kg), butter (7.3 kg of CO2e/kg), and milk powder (10.1 kg of CO2e/kg). The CF results depend on the milk volume needed, the co-product allocation process (based on milk solids content), and the amount of energy used to manufacture each product. The GHG emissions per kilogram of protein ranged from 13 to 40 kg of CO2e. Two products had higher values: cream and sour cream, at 83 and 78 kg of CO2e/kg, respectively. Finally, the highest CF value was for butter, at about 730 kg of CO2e/kg. This extremely high value is due to the fact that the intensity indicator per kilogram of product is high and that butter is almost exclusively

  6. An environmental impact calculator for greenhouse production systems.

    PubMed

    Torrellas, Marta; Antón, Assumpció; Montero, Juan Ignacio

    2013-03-30

    Multiple web-based calculators have come on the market as tools to support sustainable decision making, but few are available to agriculture. Life cycle assessment (LCA) has proved to be an objective, transparent tool for calculating environmental impacts throughout the life cycle of products and services, but can often be too complex for non-specialists. The objective of this study was therefore to develop an environmental support tool to determine the environmental impacts of protected crops. An effort was made to provide an easy-to-use tool in order to reach a wide audience and help horticulture stakeholders choose efficient options to mitigate the environmental impacts of protected crops. Users can estimate the environmental performance of their crops by entering a limited amount of data and following a few easy steps. A questionnaire must be answered with data on the crop, greenhouse dimensions, substrate, waste management, and the consumption of water, energy, fertilisers and pesticides. The calculator was designed as a simplified LCA, based on two scenarios analysed in detail in previous tasks of the EUPHOROS project and used as reference systems in this study. Two spreadsheets were provided based on these reference scenarios: one for a tomato crop in a multi-tunnel greenhouse under Southern European climate conditions and the other for a tomato crop in a Venlo glass greenhouse under Central European climate conditions. The selected functional unit was one tonne of tomatoes. Default data were given for each reference system for users who did not have complete specific data and to provide results for comparison with users' own results. The results were presented for water use as an inventory indicator and for the impact categories abiotic depletion, acidification, eutrophication, global warming, photochemical oxidation and cumulative energy demand. In the multi-tunnel greenhouse, the main contributors based on the default data were the structure, fertilisers

  7. Cosmogenic Ne-21 Production Rates in H-Chondrites Based on Cl-36 - Ar-36 Ages

    NASA Technical Reports Server (NTRS)

    Leya, I.; Graf, Th.; Nishiizumi, K.; Guenther, D.; Wieler, R.

    2000-01-01

    We measured Ne-21 production rates in 14 H-chondrites in good agreement with model calculations. The production rates are based on Ne-21 concentrations measured on bulk samples or the non-magnetic fraction and Cl-36 - Ar-36 ages determined from the metal phase.

  8. Addressing Fission Product Validation in MCNP Burnup Credit Criticality Calculations

    SciTech Connect

    Mueller, Don; Bowen, Douglas G; Marshall, William BJ J

    2015-01-01

    The US Nuclear Regulatory Commission (NRC) Division of Spent Fuel Storage and Transportation issued Interim Staff Guidance (ISG) 8, Revision 3 in September 2012. This ISG provides guidance for NRC staff members’ review of burnup credit (BUC) analyses supporting transport and dry storage of pressurized water reactor spent nuclear fuel (SNF) in casks. The ISG includes guidance for addressing validation of criticality (keff) calculations crediting the presence of a limited set of fission products and minor actinides (FP&MAs). Based on previous work documented in NRC Regulatory Guide (NUREG) Contractor Report (CR)-7109, the ISG recommends that NRC staff members accept the use of either 1.5 or 3% of the FP&MA worth—in addition to bias and bias uncertainty resulting from validation of keff calculations for the major actinides in SNF—to conservatively account for the bias and bias uncertainty associated with the specified unvalidated FP&MAs. The ISG recommends (1) use of 1.5% of the FP&MA worth if a modern version of SCALE and its nuclear data are used and (2) 3% of the FP&MA worth for well qualified, industry standard code systems other than SCALE with the Evaluated Nuclear Data Files, Part B (ENDF/B),-V, ENDF/B-VI, or ENDF/B-VII cross sections libraries. The work presented in this paper provides a basis for extending the use of the 1.5% of the FP&MA worth bias to BUC criticality calculations performed using the Monte Carlo N-Particle (MCNP) code. The extended use of the 1.5% FP&MA worth bias is shown to be acceptable by comparison of FP&MA worths calculated using SCALE and MCNP with ENDF/B-V, -VI, and -VII–based nuclear data. The comparison supports use of the 1.5% FP&MA worth bias when the MCNP code is used for criticality calculations, provided that the cask design is similar to the hypothetical generic BUC-32 cask model and that the credited FP&MA worth is no more than 0.1 Δkeff (ISG-8, Rev. 3, Recommendation 4).

  9. Production Rates of Cosmogenic Nuclides in the Knyahinya L-Chondrite

    NASA Technical Reports Server (NTRS)

    Kim, K. J.; Reedy, R. C.

    2004-01-01

    The production rates of spallogenic radionuclides and stable isotopes in the L-chondrite Knyahinya were investigated using the MCNPX code. Numerous cosmogenic nuclides had been measured in many Knyahinya samples. The pre-atmospheric size and sample locations of Knyahinya are well known, thus Knyahinya is a good test case for cosmogenic-nuclide production-rate calculations. Our calculated profiles were compared to the measurements to determine effective proton fluxes.

  10. 40 CFR 1065.642 - SSV, CFV, and PDP molar flow rate calculations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 32 2010-07-01 2010-07-01 false SSV, CFV, and PDP molar flow rate calculations. 1065.642 Section 1065.642 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.642...

  11. 40 CFR 1065.642 - SSV, CFV, and PDP molar flow rate calculations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 34 2013-07-01 2013-07-01 false SSV, CFV, and PDP molar flow rate calculations. 1065.642 Section 1065.642 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.642...

  12. 40 CFR 1065.642 - SSV, CFV, and PDP molar flow rate calculations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 34 2012-07-01 2012-07-01 false SSV, CFV, and PDP molar flow rate calculations. 1065.642 Section 1065.642 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.642...

  13. 40 CFR 1065.642 - SSV, CFV, and PDP molar flow rate calculations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 33 2011-07-01 2011-07-01 false SSV, CFV, and PDP molar flow rate calculations. 1065.642 Section 1065.642 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.642...

  14. Practical calculator programs. Part 6. Program predicts drilling time, penetration rate

    SciTech Connect

    Chenevert, M.E.; Hollo, R.

    1981-10-05

    Chenevert's program, designed for the TI-59 programmable calculator, can determine the time (hr) needed to drill a new well to a given depth and the expected penetration rate (ft/hr) at that depth. The program bases its calculations on bit records obtained from an offset well. Extrapolation of the results can predict drilling times for deeper wells.

  15. Re-examining the Dissolution of Spent Fuel: A Comparison of Different Methods for Calculating Rates

    SciTech Connect

    Hanson, B D; Stout, R B

    2004-04-09

    Dissolution rates for spent fuel have typically been reported in terms of a rate normalized to the surface area of the specimen. Recent evidence has shown that neither the geometric surface area nor that measured with BET accurately predicts the effective surface area of spent fuel. Dissolution rates calculated from results obtained by flowthrough tests were reexamined comparing the cumulative releases and surface area normalized rates. While initial surface area is important for comparison of different rates, it appears that normalizing to the surface area introduces unnecessary uncertainty compared to using cumulative or fractional release rates. Discrepancies in past data analyses are mitigated using this alternative method.

  16. Calculation of the biological effective dose for piecewise defined dose-rate fits

    SciTech Connect

    Hobbs, Robert F.; Sgouros, George

    2009-03-15

    An algorithmic solution to the biological effective dose (BED) calculation from the Lea-Catcheside formula for a piecewise defined function is presented. Data from patients treated for metastatic thyroid cancer were used to illustrate the solution. The Lea-Catcheside formula for the G-factor of the BED is integrated numerically using a large number of small trapezoidal fits to each integral. The algorithmically calculated BED is compatible with an analytic calculation for a similarly valued exponentially fitted dose-rate plot and is the only resolution for piecewise defined dose-rate functions.

  17. Dose Rate Calculations for the 2-MCO/2-DHLW Waste Package

    SciTech Connect

    G. Radulescu

    2000-10-03

    The objective of this calculation is to determine the dose rates on the external surfaces of the waste package (WP) containing two Hanford defense high-level waste (DHLW) glass canisters and two Hanford multi-canister overpacks (MCO). Each MCO is loaded with the N Reactor spent nuclear fuel (SNF). The information provided by the sketches attached to this calculation is that of the potential design for the WP type considered in this calculation. The scope of this calculation is limited to reporting dose rates averaged over segments of the WP radial and axial surfaces and of surfaces 1 m and 2 m from the WP. The results of this calculation will be used to assess the shielding performance of the 2-MC012-DHLW WP engineering design.

  18. Influences of Response Rate and Distribution on the Calculation of Interobserver Reliability Scores

    ERIC Educational Resources Information Center

    Rolider, Natalie U.; Iwata, Brian A.; Bullock, Christopher E.

    2012-01-01

    We examined the effects of several variations in response rate on the calculation of total, interval, exact-agreement, and proportional reliability indices. Trained observers recorded computer-generated data that appeared on a computer screen. In Study 1, target responses occurred at low, moderate, and high rates during separate sessions so that…

  19. Steady State Flammable Gas Release Rate Calculation and Lower Flammability Level Evaluation for Hanford Tank Waste

    SciTech Connect

    HU, T.A.

    2000-04-27

    This work is to assess the steady-state flammability level at normal and off-normal ventilation conditions in the tank dome space for 177 double-shell and single-shell tanks at Hanford. Hydrogen generation rate was calculated for 177 tanks using rate equation model developed recently.

  20. Incorporation of measured photosynthetic rate in a mathematical model for calculation of non-structural saccharide concentration

    NASA Technical Reports Server (NTRS)

    Lim, J. T.; Raper, C. D. Jr; Gold, H. J.; Wilkerson, G. G.; Raper CD, J. r. (Principal Investigator)

    1989-01-01

    A simple mathematical model for calculating the concentration of mobile carbon skeletons in the shoot of soya bean plants [Glycine max (L.) Merrill cv. Ransom] was built to examine the suitability of measured net photosynthetic rates (PN) for calculation of saccharide flux into the plant. The results suggest that either measurement of instantaneous PN overestimated saccharide influx or respiration rates utilized in the model were underestimated. If neither of these is the case, end-product inhibition of photosynthesis or waste respiration through the alternative pathway should be included in modelling of CH2O influx or efflux; and even if either of these is the case, the model output at a low coefficient of leaf activity indicates that PN still may be controlled by either end-product inhibition or alternative respiration.

  1. Incorporation of measured photosynthetic rate in a mathematical model for calculation of non-structural saccharide concentration.

    PubMed

    Lim, J T; Raper, C D; Gold, H J; Wilkerson, G G

    1989-01-01

    A simple mathematical model for calculating the concentration of mobile carbon skeletons in the shoot of soya bean plants [Glycine max (L.) Merrill cv. Ransom] was built to examine the suitability of measured net photosynthetic rates (PN) for calculation of saccharide flux into the plant. The results suggest that either measurement of instantaneous PN overestimated saccharide influx or respiration rates utilized in the model were underestimated. If neither of these is the case, end-product inhibition of photosynthesis or waste respiration through the alternative pathway should be included in modelling of CH2O influx or efflux; and even if either of these is the case, the model output at a low coefficient of leaf activity indicates that PN still may be controlled by either end-product inhibition or alternative respiration.

  2. Correlation between calculated local stability and hydrogen exchange rates in proteins.

    PubMed

    Rashin, A A

    1987-11-20

    The attempt is made to find new correlations between local structural characteristics of proteins and the hydrogen exchange rates of their individual main-chain amides, and to relate such correlations to possible mechanisms of hydrogen exchange. It is found that in bovine pancreatic trypsin inhibitor (BPTI) the surface area buried by a particular residue and its neighbors correlates with the exchange rate of the main-chain amide of that residue. As the area buried by a particular fragment can be associated with the stabilization of the protein structure by this fragment, the correlation suggests a role for the energetics of the local unfolding in the mechanism of hydrogen exchange. Calculations based on the assumption that the exchange mechanism involves local unfolding lead to quantitative agreement between the calculated and experimentally measured exchange rates for 80% of the amides of BPTI that are buried or hydrogen bonded to the main-chain or to internal water molecules. The same degree of correlation is found between the calculated exchange rates and partial exchange data for ribonuclease S, hen lysozyme and cytochrome c. A similarly strong correlation is found between calculated exchange rates and the exchange rates of ribonuclease A determined by neutron diffraction in the crystal. The criteria of correlation are, however, less stringent in this case because of the experimental errors, which are larger than for solution data. It is suggested that the observed correlation be used for predictions of hydrogen exchange rates in proteins.

  3. Communication: rate coefficients from quasiclassical trajectory calculations from the reverse reaction: The Mu + H2 reaction re-visited.

    PubMed

    Homayoon, Zahra; Jambrina, Pablo G; Aoiz, F Javier; Bowman, Joel M

    2012-07-14

    In a previous paper [P. G. Jambrina et al., J. Chem. Phys. 135, 034310 (2011)] various calculations of the rate coefficient for the Mu + H(2) → MuH + H reaction were presented and compared to experiment. The widely used standard quasiclassical trajectory (QCT) method was shown to overestimate the rate coefficients by several orders of magnitude over the temperature range 200-1000 K. This was attributed to a major failure of that method to describe the correct threshold for the reaction owing to the large difference in zero-point energies (ZPE) of the reactant H(2) and product MuH (∼0.32 eV). In this Communication we show that by performing standard QCT calculations for the reverse reaction and then applying detailed balance, the resulting rate coefficient is in very good agreement with the other computational results that respect the ZPE, (as well as with the experiment) but which are more demanding computationally.

  4. Ab Initio Calculation of Rate Constants for Molecule–Surface Reactions with Chemical Accuracy

    PubMed Central

    Piccini, GiovanniMaria; Alessio, Maristella

    2016-01-01

    Abstract The ab initio prediction of reaction rate constants for systems with hundreds of atoms with an accuracy that is comparable to experiment is a challenge for computational quantum chemistry. We present a divide‐and‐conquer strategy that departs from the potential energy surfaces obtained by standard density functional theory with inclusion of dispersion. The energies of the reactant and transition structures are refined by wavefunction‐type calculations for the reaction site. Thermal effects and entropies are calculated from vibrational partition functions, and the anharmonic frequencies are calculated separately for each vibrational mode. This method is applied to a key reaction of an industrially relevant catalytic process, the methylation of small alkenes over zeolites. The calculated reaction rate constants (free energies), pre‐exponential factors (entropies), and enthalpy barriers show that our computational strategy yields results that agree with experiment within chemical accuracy limits (less than one order of magnitude). PMID:27008460

  5. Calculated ionization rates, ion densities, and airglow emission rates due to precipitating electrons in the nightside ionosphere of Mars

    NASA Technical Reports Server (NTRS)

    Haider, S. A.; Kim, J.; Nagy, A. F.; Keller, C. N.; Verigin, M. I.; Gringauz, K. I.; Shutte, N. M.; Szego, K.; Kiraly, P.

    1992-01-01

    The calculations presented in this paper clearly establish that the electron fluxes measured by the HARP instrument, carried on board Phobos 2, could cause significant electron impact ionization and excitation in the nightside atmosphere of Mars, if these electrons actually do precipitate. The calculated peak electron densities were found to be about a factor of 2 larger than the mean observed nightside densities, indicating that if a significant fraction of the measured electrons actually precipitate, they could be the dominant mechanism responsible for maintaining the nightside ionosphere. The calculated zenith column emission rates of the O I 5577-A and 6300-A and CO Cameron band emissions, due to electron impact and dissociative recombination mechanisms, were found to be significant.

  6. Rate calculations for the simultaneous vibrational relaxation and dissociation of nitrogen

    NASA Technical Reports Server (NTRS)

    Gonzales, David A.; Varghese, Philip L.

    1992-01-01

    Experimental data on vibrational relaxation and dissociation rates in highly nonequilibrium gases are scarce. Recently there have been several attempts at generating these rates by direct calculation of inelastic collision cross-sections. Some issues that need to be considered if such calculations are to be used as a basis for analysis and design are examined. In particular, the following are examined: (1) collinear vs 3D scattering models, (2) accurate intermolecular potentials, (3) closed channels and acceleration schemes, (4) thermal averaging and thermal rates, and (5) code validation. It has been necessary to confront these issues during the course of N2-N2 and N2-N inelastic cross-section calculations.

  7. O₂migration rates in [NiFe] hydrogenases. A joint approach combining free-energy calculations and kinetic modeling.

    PubMed

    Topin, Jérémie; Diharce, Julien; Fiorucci, Sébastien; Antonczak, Serge; Golebiowski, Jérôme

    2014-01-23

    Hydrogenases are promising candidates for the catalytic production of green energy by means of biological ways. The major impediment to such a production is rooted in their inhibition under aerobic conditions. In this work, we model dioxygen migration rates in mutants of a hydrogenase of Desulfovibrio fructusovorans. The approach relies on the calculation of the whole potential of mean force for O2 migration within the wild-type as well as in V74M, V74F, and V74Q mutant channels. The three free-energy barriers along the entire migration pathway are converted into chemical rates through modeling based on Transition State Theory. The use of such a model recovers the trend of O2 migration rates among the series.

  8. Pair production rates in mildly relativistic, magnetized plasmas

    NASA Technical Reports Server (NTRS)

    Burns, M. L.; Harding, A. K.

    1984-01-01

    Electron-positron pairs may be produced by either one or two photons in the presence of a strong magnetic field. In magnetized plasmas with temperatures kT approximately sq mc, both of these processes may be important and could be competitive. The rates of one-photon and two-photon pair production by photons with Maxwellian, thermal bremsstrahlung, thermal synchrotron and power law spectra are calculated as a function of temperature or power law index and field strength. This allows a comparison of the two rates and a determination of the conditions under which each process may be a significant source of pairs in astrophysical plasmas. It is found that for photon densities n(gamma) or = 10 to the 25th power/cu cm and magnetic field strengths B or = 10 to the 12th power G, one-photon pair production dominates at kT approximately sq mc for a Maxwellian, at kT approximately 2 sq mc for a thermal bremsstrahlung spectrum, at all temperatures for a thermal synchrotron spectrum, and for power law spectra with indices s approximately 4.

  9. Calculating the rate of exothermic energy release for catalytic converter efficiency monitoring

    SciTech Connect

    Hepburn, J.S.; Meitzler, A.H.

    1995-12-31

    This paper reports on the development of a new methodology for OBD-II catalyst efficiency monitoring. Temperature measurements taken from the center of the catalyst substrate or near the exterior surface of the catalyst brick were used in conjunction with macroscopic energy balances to calculate the instantaneous rate of exothermic energy generation within the catalyst. The total calculated rate of exothermic energy release over the FTP test cycle was within 10% of the actual or theoretical value and provided a good indicator of catalyst light-off for a variety of aged catalytic converters. Normalization of the rate of exothermic energy release in the front section of the converter by the mass flow rate of air inducted through the engine was found to provide a simple yet practical means of monitoring the converter under both FTP and varying types of road driving.

  10. Fine-grid calculations for stellar electron and positron capture rates on Fe isotopes

    SciTech Connect

    Nabi, Jameel-Un; Tawfik, Abdel Nasser

    2013-03-15

    The acquisition of precise and reliable nuclear data is a prerequisite to success for stellar evolution and nucleosynthesis studies. Core-collapse simulators find it challenging to generate an explosion from the collapse of the core of massive stars. It is believed that a better understanding of the microphysics of core-collapse can lead to successful results. The weak interaction processes are able to trigger the collapse and control the lepton-to-baryon ratio (Y{sub e}) of the corematerial. It is suggested that the temporal variation of Y{sub e} within the core of a massive star has a pivotal role to play in the stellar evolution and a fine-tuning of this parameter at various stages of presupernova evolution is the key to generate an explosion. During the presupernova evolution of massive stars, isotopes of iron, mainly {sup 54-56}Fe, are considered to be key players in controlling Y{sub e} ratio via electron capture on these nuclides. Recently an improved microscopic calculation of weak-interaction-mediated rates for iron isotopes was introduced using the proton-neutron quasiparticle random-phase-approximation (pn-QRPA) theory. The pn-QRPA theory allows a microscopic state-by-state calculation of stellar capture rates which greatly increases the reliability of calculated rates. The results were suggestive of some fine-tuning of the Y{sub e} ratio during various phases of stellar evolution. Here we present for the first time the fine-grid calculation of the electron and positron capture rates on {sup 54-56}Fe. The sensitivity of the pn-QRPA calculated capture rates to the deformation parameter is also studied in this work. Core-collapse simulators may find this calculation suitable for interpolation purposes and for necessary incorporation in the stellar evolution codes.

  11. An ETAS model with varying productivity rates

    NASA Astrophysics Data System (ADS)

    Harte, D. S.

    2014-07-01

    We present an epidemic type aftershock sequenc (ETAS) model where the offspring rates vary both spatially and temporally. This is achieved by distinguishing between those space-time volumes where the interpoint space and time distances are small, and those where they are considerably larger. We also question the nature of the background component in the ETAS model. Is it simply a temporal boundary correction (t = 0) or does it represent an additional tectonic process not described by the aftershock component? The form of these stochastic models should not be considered to be fixed. As we accumulate larger and better earthquake catalogues, GPS data, strain rates, etc., we have the ability to ask more complex questions about the nature of the process. By fitting modified models consistent with such questions, we should gain a better insight into the earthquake process. Hence, we consider a sequence of incrementally modified ETAS type models rather than `the' ETAS model.

  12. MORATE: a program for direct dynamics calculations of chemical reaction rates by semiempirical molecular orbital theory

    NASA Astrophysics Data System (ADS)

    Truong, Thanh N.; Lu, Da-hong; Lynch, Gillian C.; Liu, Yi-Ping; Melissas, Vasilios S.; Stewart, James J. P.; Steckler, Rozeanne; Garrett, Bruce C.; Isaacson, Alan D.; Gonzalez-Lafont, Angels; Rai, Sachchida N.; Hancock, Gene C.; Joseph, Tomi; Truhlar, Donald G.

    1993-04-01

    We present a computer program, MORATE (Molecular Orbital RATE calculations), for direct dynamics calculations of unimolecular and bimolecular rate constants of gas-phase chemical reactions involving atoms, diatoms, or polyatomic species. The potential energies, gradients, and higher derivatives of the potential are calculated whenever needed by semiempirical molecular orbital theory without the intermediary of a global or semiglobal fit. The dynamical methods used are conventional or variational transition state theory and multidimensional semiclassical approximations for tunneling and nonclassical reflection. The computer program is conveniently interfaced package consisting of the POLYRATE program, version 4.5.1, for dynamical rate calculations, and the MOPAC program, version 5.03, for semiempirical electronic structure computations. All semiempirical methods available in MOPAC, in particular MINDO/3, MNDO, AM1, and PM3, can be called on to calculate the potential and gradient. Higher derivatives of the potential are obtained by numerical derivatives of the gradient. Variational transition states are found by a one-dimensional search of generalized-transition-state dividing surfaces perpendicular to the minimum-energy path, and tunneling probabilities are evaluated by numerical quadrature.

  13. Results of Propellant Mixing Variable Study Using Precise Pressure-Based Burn Rate Calculations

    NASA Technical Reports Server (NTRS)

    Stefanski, Philip L.

    2014-01-01

    A designed experiment was conducted in which three mix processing variables (pre-curative addition mix temperature, pre-curative addition mixing time, and mixer speed) were varied to estimate their effects on within-mix propellant burn rate variability. The chosen discriminator for the experiment was the 2-inch diameter by 4-inch long (2x4) Center-Perforated (CP) ballistic evaluation motor. Motor nozzle throat diameters were sized to produce a common targeted chamber pressure. Initial data analysis did not show a statistically significant effect. Because propellant burn rate must be directly related to chamber pressure, a method was developed that showed statistically significant effects on chamber pressure (either maximum or average) by adjustments to the process settings. Burn rates were calculated from chamber pressures and these were then normalized to a common pressure for comparative purposes. The pressure-based method of burn rate determination showed significant reduction in error when compared to results obtained from the Brooks' modification of the propellant web-bisector burn rate determination method. Analysis of effects using burn rates calculated by the pressure-based method showed a significant correlation of within-mix burn rate dispersion to mixing duration and the quadratic of mixing duration. The findings were confirmed in a series of mixes that examined the effects of mixing time on burn rate variation, which yielded the same results.

  14. Comparison of atmospheric stability methods for calculating ammonia and methane emission rates with WindTrax

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Inverse dispersion models are useful tools for estimating emissions from animal feeding operations, waste storage ponds, and manure application fields. Atmospheric stability is an important input parameter to such models. The objective of this study was to compare emission rates calculated with a ba...

  15. Calculating mercury loading to the tidal Hudson River, New York, using rating curve and surrogate methodologies

    USGS Publications Warehouse

    Wall, G.R.; Ingleston, H.H.; Litten, S.

    2005-01-01

    Total mercury (THg) load in rivers is often calculated from a site-specific "rating-curve" based on the relation between THg concentration and river discharge along with a continuous record of river discharge. However, there is no physical explanation as to why river discharge should consistently predict THg or any other suspended analyte. THg loads calculated by the rating-curve method were compared with those calculated by a "continuous surrogate concentration" (CSC) method in which a relation between THg concentration and suspended-sediment concentration (SSC) is constructed; THg loads then can be calculated from the continuous record of SSC and river discharge. The rating-curve and CSC methods, respectively, indicated annual THg loads of 46.4 and 75.1 kg for the Mohawk River, and 52.9 and 33.1 kg for the upper Hudson River. Differences between the results of the two methods are attributed to the inability of the rating-curve method to adequately characterize atypical high flows such as an ice-dam release, or to account for hysteresis, which typically degrades the strength of the relation between stream discharge and concentration of material in suspension. ?? Springer 2005.

  16. 31 CFR 356.21 - How are awards at the high yield or discount rate calculated?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false How are awards at the high yield or discount rate calculated? 356.21 Section 356.21 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT SALE...

  17. 7 CFR 760.705 - Payment rates and calculation of payments.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 7 2013-01-01 2013-01-01 false Payment rates and calculation of payments. 760.705 Section 760.705 Agriculture Regulations of the Department of Agriculture (Continued) FARM SERVICE AGENCY, DEPARTMENT OF AGRICULTURE SPECIAL PROGRAMS INDEMNITY PAYMENT PROGRAMS Crop Assistance Program §...

  18. 7 CFR 760.705 - Payment rates and calculation of payments.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 7 2011-01-01 2011-01-01 false Payment rates and calculation of payments. 760.705 Section 760.705 Agriculture Regulations of the Department of Agriculture (Continued) FARM SERVICE AGENCY, DEPARTMENT OF AGRICULTURE SPECIAL PROGRAMS INDEMNITY PAYMENT PROGRAMS Crop Assistance Program §...

  19. 7 CFR 760.705 - Payment rates and calculation of payments.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 7 2012-01-01 2012-01-01 false Payment rates and calculation of payments. 760.705 Section 760.705 Agriculture Regulations of the Department of Agriculture (Continued) FARM SERVICE AGENCY, DEPARTMENT OF AGRICULTURE SPECIAL PROGRAMS INDEMNITY PAYMENT PROGRAMS Crop Assistance Program §...

  20. 7 CFR 760.705 - Payment rates and calculation of payments.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 7 2014-01-01 2014-01-01 false Payment rates and calculation of payments. 760.705 Section 760.705 Agriculture Regulations of the Department of Agriculture (Continued) FARM SERVICE AGENCY, DEPARTMENT OF AGRICULTURE SPECIAL PROGRAMS INDEMNITY PAYMENT PROGRAMS Crop Assistance Program §...

  1. 40 CFR 1066.630 - PDP, SSV, and CFV flow rate calculations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) AIR POLLUTION CONTROLS VEHICLE-TESTING PROCEDURES Calculations § 1066.630 PDP, SSV, and CFV flow rate....15 K. p in = static absolute pressure at the PDP inlet. T in = absolute temperature at the PDP inlet... cross-sectional area. R = molar gas constant. p in = static absolute pressure at the venturi inlet....

  2. A simple calculation method for heavy ion induced soft error rate in space environment

    NASA Astrophysics Data System (ADS)

    Galimov, A. M.; Elushov, I. V.; Zebrev, G. I.

    2016-12-01

    In this paper based on the new parameterization shape, an alternative heavy ion induced soft errors characterization approach is proposed and validated. The method provides an unambiguous calculation procedure to predict an upset rate in highly-scaled memory in a space environment.

  3. 45 CFR 261.25 - Do we count Tribal families in calculating the work participation rate?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 45 Public Welfare 2 2010-10-01 2010-10-01 false Do we count Tribal families in calculating the work participation rate? 261.25 Section 261.25 Public Welfare Regulations Relating to Public Welfare... OF HEALTH AND HUMAN SERVICES ENSURING THAT RECIPIENTS WORK What Are the Provisions Addressing...

  4. The global joule heat production rate and the AE index

    NASA Technical Reports Server (NTRS)

    Wei, S.; Ahn, B.-H.; Akasofu, S.-I.

    1985-01-01

    The degree of accuracy with which the AE index may be used as a measure of the joule heat production rate is evaluated for a typical substorm event on March 18, 1978, by estimating the global joule heat production rate as a function of time on the basis of data obtained from the IMS's six meridian chains. It is found that, although the AE index is statistically linearly related to the global joule heat production rate, caution is required when one assumes that details of AE index time variations during individual events are representative of those of the joule heat production rate.

  5. Direct measurement of neon production rates by (α,n) reactions in minerals

    NASA Astrophysics Data System (ADS)

    Cox, Stephen E.; Farley, Kenneth A.; Cherniak, Daniele J.

    2015-01-01

    The production of nucleogenic neon from alpha particle capture by 18O and 19F offers a potential chronometer sensitive to temperatures higher than the more widely used (U-Th)/He chronometer. The accuracy depends on the cross sections and the calculated stopping power for alpha particles in the mineral being studied. Published 18O(α,n)21Ne production rates are in poor agreement and were calculated from contradictory cross sections, and therefore demand experimental verification. Similarly, the stopping powers for alpha particles are calculated from SRIM (Stopping Range of Ions in Matter software) based on a limited experimental dataset. To address these issues we used a particle accelerator to implant alpha particles at precisely known energies into slabs of synthetic quartz (SiO2) and barium tungstate (BaWO4) to measure 21Ne production from capture by 18O. Within experimental uncertainties the observed 21Ne production rates compare favorably to our predictions using published cross sections and stopping powers, indicating that ages calculated using these quantities are accurate at the ∼3% level. In addition, we measured the 22Ne/21Ne ratio and (U-Th)/He and (U-Th)/Ne ages of Durango fluorapatite, which is an important model system for this work because it contains both oxygen and fluorine. Finally, we present 21Ne/4He production rate ratios for a variety of minerals of geochemical interest along with software for calculating neon production rates and (U-Th)/Ne ages.

  6. Thermonuclear reaction rate of 18Ne(α ,p ) 21Na from Monte Carlo calculations

    NASA Astrophysics Data System (ADS)

    Mohr, P.; Longland, R.; Iliadis, C.

    2014-12-01

    The 18Ne(α ,p ) 21Na reaction impacts the break-out from the hot CNO cycles to the r p process in type-I x-ray bursts. We present a revised thermonuclear reaction rate, which is based on the latest experimental data. The new rate is derived from Monte Carlo calculations, taking into account the uncertainties of all nuclear physics input quantities. In addition, we present the reaction rate uncertainty and probability density versus temperature. Our results are also consistent with estimates obtained using different indirect approaches.

  7. Infrared cooling rate calculations in operational general circulation models - Comparisons with benchmark computations

    NASA Technical Reports Server (NTRS)

    Kiehl, J. T.; Lacis, A. A.; Schwarzkopf, M. D.; Fels, S. B.

    1991-01-01

    The performance of several parameterized models is described with respect to numerical prediction and climate research at GFDL, NCAR, and GISS. The radiation codes of the models were compared to benchmark calculations and other codes for the intercomparison of radiation codes in climate models (ICRCCM). Cooling rates and fluxes calculated from the models are examined in terms of their application to established general circulation models (GCMs) from the three research institutions. The newest radiation parameterization techniques show the most significant agreement with the benchmark line-by-line (LBL) results. The LBL cooling rates correspond to cooling rate profiles from the models, but the parameterization of the water vapor continuum demonstrates uncertain results. These uncertainties affect the understanding of some lower tropospheric cooling, and therefore more accurate parameterization of the water vapor continuum, as well as the weaker absorption bands of CO2 and O3 is recommended.

  8. CHARADE: A characteristic code for calculating rate-dependent shock-wave response

    SciTech Connect

    Johnson, J.N.; Tonks, D.L.

    1991-01-01

    In this report we apply spatially one-dimensional methods and simple shock-tracking techniques to the solution of rate-dependent material response under flat-plate-impact conditions. This method of solution eliminates potential confusion of material dissipation with artificial dissipative effects inherent in finite-difference codes, and thus lends itself to accurate calculation of elastic-plastic deformation, shock-to-detonation transition in solid explosives, and shock-induced structural phase transformation. Equations are presented for rate-dependent thermoelastic-plastic deformation for (100) planar shock-wave propagation in materials of cubic symmetry (or higher). Specific numerical calculations are presented for polycrystalline copper using the mechanical threshold stress model of Follansbee and Kocks with transition to dislocation drag. A listing of the CHARADE (for characteristic rate dependence) code and sample input deck are given. 26 refs., 11 figs.

  9. Calculated diffusion coefficients and the growth rate of olivine in a basalt magma

    NASA Technical Reports Server (NTRS)

    Donaldson, C. H.

    1975-01-01

    Concentration gradients in glass adjacent to skeletal olivines in a basalt have been examined by electron probe. The glass is depleted in Mg, Fe, and Cr and enriched in Si, Al, Na, and Ca relative to that far from olivine. Ionic diffusion coefficients for the glass compositions are calculated from temperature, ionic radius and melt viscosity, using the Stokes-Einstein relation. At 1170 C, the diffusion coefficient of Mg(2+) ions in the basalt is 4.5 billionths sq cm per sec. Comparison with measured diffusion coefficients in a mugearite suggests this value may be 16 times too small. The concentration gradient data and the diffusion coefficients are used to calculate instantaneous olivine growth rates. Growth necessarily preceded emplacement such that the composition of the crystals plus the enclosing glass need not be that of a melt. The computed olivine growth rates are compatible with the rate of crystallization deduced for the Skaegaard intrusion.

  10. Productivity cost calculations in health economic evaluations: correcting for compensation mechanisms and multiplier effects.

    PubMed

    Krol, Marieke; Brouwer, Werner B F; Severens, Johan L; Kaper, Janneke; Evers, Silvia M A A

    2012-12-01

    Productivity costs related to paid work are commonly calculated in economic evaluations of health technologies by multiplying the relevant number of work days lost with a wage rate estimate. It has been argued that actual productivity costs may either be lower or higher than current estimates due to compensation mechanisms and/or multiplier effects (related to team dependency and problems with finding good substitutes in cases of absenteeism). Empirical evidence on such mechanisms and their impact on productivity costs is scarce, however. This study aims to increase knowledge on how diminished productivity is compensated within firms. Moreover, it aims to explore how compensation and multiplier effects potentially affect productivity cost estimates. Absenteeism and compensation mechanisms were measured in a randomized trial among Dutch citizens examining the cost-effectiveness of reimbursement for smoking cessation treatment. Multiplier effects were extracted from published literature. Productivity costs were calculated applying the Friction Cost Approach. Regular estimates were subsequently adjusted for (i) compensation during regular working hours, (ii) job dependent multipliers and (iii) both compensation and multiplier effects. A total of 187 respondents included in the trial were useful for inclusion in this study, based on being in paid employment, having experienced absenteeism in the preceding six months and completing the questionnaire on absenteeism and compensation mechanisms. Over half of these respondents stated that their absenteeism was compensated during normal working hours by themselves or colleagues. Only counting productivity costs not compensated in regular working hours reduced the traditional estimate by 57%. Correcting for multiplier effects increased regular estimates by a quarter. Combining both impacts decreased traditional estimates by 29%. To conclude, large amounts of lost production are compensated in normal hours. Productivity costs

  11. Development of a New Shielding Model for JB-Line Dose Rate Calculations

    SciTech Connect

    Buckner, M.R.

    2001-08-09

    This report describes the shielding model development for the JB-Line Upgrade project. The product of this effort is a simple-to-use but accurate method of estimating the personnel dose expected for various operating conditions on the line. The current techniques for shielding calculations use transport codes such as ANISN which, while accurate for geometries which can be accurately approximated as one dimensional slabs, cylinders or spheres, fall short in calculating configurations in which two-or three-dimensional effects (e.g., streaming) play a role in the dose received by workers.

  12. Radiolytic hydrogen production from process vessels in HB line - production rates compared to evolution rates and discussion of LASL reviews

    SciTech Connect

    Bibler, N.E.

    1992-11-12

    Hydrogen production from radiolysis of aqueous solutions can create a safety hazard since hydrogen is flammable. At times this production can be significant, especially in HB line where nitric acid solutions containing high concentrations of Pu-238, an intense alpha emitter, are processed. The hydrogen production rates from these solutions are necessary for safety analyses of these process systems. The methods and conclusions of hydrogen production rate tests are provided in this report.

  13. Effects of heterogeneity in aquifer permeability and biomass on biodegradation rate calculations - Results from numerical simulations

    USGS Publications Warehouse

    Scholl, M.A.

    2000-01-01

    Numerical simulations were used to examine the effects of heterogeneity in hydraulic conductivity (K) and intrinsic biodegradation rate on the accuracy of contaminant plume-scale biodegradation rates obtained from field data. The simulations were based on a steady-state BTEX contaminant plume-scale biodegradation under sulfate-reducing conditions, with the electron acceptor in excess. Biomass was either uniform or correlated with K to model spatially variable intrinsic biodegradation rates. A hydraulic conductivity data set from an alluvial aquifer was used to generate three sets of 10 realizations with different degrees of heterogeneity, and contaminant transport with biodegradation was simulated with BIOMOC. Biodegradation rates were calculated from the steady-state contaminant plumes using decreases in concentration with distance downgradient and a single flow velocity estimate, as is commonly done in site characterization to support the interpretation of natural attenuation. The observed rates were found to underestimate the actual rate specified in the heterogeneous model in all cases. The discrepancy between the observed rate and the 'true' rate depended on the ground water flow velocity estimate, and increased with increasing heterogeneity in the aquifer. For a lognormal K distribution with variance of 0.46, the estimate was no more than a factor of 1.4 slower than the true rate. For aquifer with 20% silt/clay lenses, the rate estimate was as much as nine times slower than the true rate. Homogeneous-permeability, uniform-degradation rate simulations were used to generate predictions of remediation time with the rates estimated from heterogeneous models. The homogeneous models were generally overestimated the extent of remediation or underestimated remediation time, due to delayed degradation of contaminants in the low-K areas. Results suggest that aquifer characterization for natural attenuation at contaminated sites should include assessment of the presence

  14. Graduation Rates and Accountability: Regressions versus Production Frontiers

    ERIC Educational Resources Information Center

    Archibald, Robert B.; Feldman, David H.

    2008-01-01

    This paper suggests an alternative to the standard practice of measuring the graduation rate performance using regression analysis. The alternative is production frontier analysis. Production frontier analysis is appealing because it compares an institution's graduation rate to the best performance instead of the average performance. The paper…

  15. Regulation of primary productivity rate in the equatorial Pacific

    SciTech Connect

    Barber, R.T. ); Chavez, F.P. )

    1991-12-01

    Analysis of the Chl-specific rate of primary productivity (P{sup B}) as a function of subsurface nutrient concentration at >300 equatorial stations provides an answer to the question: What processes regulate primary productivity rate in the high-nutrient, low-chlorophyll waters of the equatorial Pacific In the western Pacific where there is a gradient in 60-m (NO{sub 3}) from 0 to {approximately}12 {mu}M, the productivity rate is a linear function of nutrient concentration; in the eastern Pacific where the gradient is from 12 to 28 {mu}M, the productivity rate is independent of nutrient concentration and limited to {approximately}36 mg C(mg Chl){sup {minus}1} d{sup {minus}1}, or a mean euphotic zone C-specific growth rate ({mu}) of 0.47 d{sup {minus}1}. However, rates downstream of the Galapagos Islands are not limited; they are 46.4 mg C(mg Chl){sup {minus}1} d{sup {minus}1} and {mu} = 0.57 d{sup {minus}1}, very close to the predicted nutrient-regulated rates in the absence of other limitation. This pattern of rate regulation can be accounted for by a combination of eolian Fe, subsurface nutrients, and sedimentary Fe derived from the Galapagos platform. In the low-nutrient western Pacific the eolian supply of Fe is adequate to allow productivity rate to be set by subsurface nutrient concentration. In the nutrient-rich easter equatorial region eolian Fe is inadequate to support productivity rates proportional to the higher nutrient concentrations, so in this region eolian Fe is rate limiting. Around the Galapagos Islands productivity rates reach levels consistent with nutrient concentrations; sedimentary Fe from the Galapagos platform seems adequate to support increased nutrient-regulated productivity rates in this region.

  16. An improvement in the calculation of the efficiency of oxidative phosphorylation and rate of energy dissipation in mitochondria

    NASA Astrophysics Data System (ADS)

    Ghafuri, Mohazabeh; Golfar, Bahareh; Nosrati, Mohsen; Hoseinkhani, Saman

    2014-12-01

    The process of ATP production is one of the most vital processes in living cells which happens with a high efficiency. Thermodynamic evaluation of this process and the factors involved in oxidative phosphorylation can provide a valuable guide for increasing the energy production efficiency in research and industry. Although energy transduction has been studied qualitatively in several researches, there are only few brief reviews based on mathematical models on this subject. In our previous work, we suggested a mathematical model for ATP production based on non-equilibrium thermodynamic principles. In the present study, based on the new discoveries on the respiratory chain of animal mitochondria, Golfar's model has been used to generate improved results for the efficiency of oxidative phosphorylation and the rate of energy loss. The results calculated from the modified coefficients for the proton pumps of the respiratory chain enzymes are closer to the experimental results and validate the model.

  17. Calculators, Graphs, Gestures and the Production of Meaning

    ERIC Educational Resources Information Center

    Radford, Luis; Demers, Serge; Guzman, Jose; Cerulli, Michele

    2003-01-01

    In this paper we report an analysis of a teaching sequence in which Grade 11 students were asked to produce some graphs corresponding to the relationship between time and distance of a cylinder moving up and down an inclined plane. The students were also asked to carry out the experience using a TI 83+ graphic calculator equipped with a sensor,…

  18. Approximate method for calculating heating rates on three-dimensional vehicles

    NASA Astrophysics Data System (ADS)

    Hamilton, H. Harris; Greene, Francis A.; Dejarnette, F. R.

    1994-05-01

    An approximate method for calculating heating rates on three-dimensional vehicles at angle of attack is presented. The method is based on the axisymmetric analog for three-dimensional boundary layers and uses a generalized body-fitted coordinate system. Edge conditions for the boundary-layer solution are obtained from an inviscid flowfield solution, and because of the coordinate system used, the method is applicable to any blunt body geometry for which an inviscid flowfield solution can be obtained. The method is validated by comparing with experimental heating data and with thin-layer Navier-Stokes calculations on the shuttle orbiter at both wind-tunnel and flight conditions and with thin-layer Navier-Stokes calculations on the HL-20 at wind-tunnel conditions.

  19. An approximate method for calculating heating rates on three-dimensional vehicles

    NASA Technical Reports Server (NTRS)

    Hamilton, H. H., II; Greene, Francis A.; Dejarnette, Fred R.

    1993-01-01

    An approximate method for calculating heating rates on three-dimensional vehicles at angle of attack is presented. The method is based on the axisymmetric analog for three-dimensional boundary layers and uses a generalized body fitted coordinate system. Edge conditions for the boundary layer solution are obtained from an inviscid flowfield solution, and because of the coordinate system used the method is applicable to any blunt body geometry for which a inviscid flowfield solution can be obtained. It is validated by comparing with experimental heating data and with Navier-Stokes calculations on the Shuttle orbiter at both wind tunnel and flight conditions and with Navier-Stokes calculations on the HL-20 at wind tunnel conditions.

  20. Approximate method for calculating heating rates on three-dimensional vehicles

    NASA Technical Reports Server (NTRS)

    Hamilton, H. Harris; Greene, Francis A.; Dejarnette, F. R.

    1994-01-01

    An approximate method for calculating heating rates on three-dimensional vehicles at angle of attack is presented. The method is based on the axisymmetric analog for three-dimensional boundary layers and uses a generalized body-fitted coordinate system. Edge conditions for the boundary-layer solution are obtained from an inviscid flowfield solution, and because of the coordinate system used, the method is applicable to any blunt body geometry for which an inviscid flowfield solution can be obtained. The method is validated by comparing with experimental heating data and with thin-layer Navier-Stokes calculations on the shuttle orbiter at both wind-tunnel and flight conditions and with thin-layer Navier-Stokes calculations on the HL-20 at wind-tunnel conditions.

  1. External dose-rate conversion factors for calculation of dose to the public

    SciTech Connect

    Not Available

    1988-07-01

    This report presents a tabulation of dose-rate conversion factors for external exposure to photons and electrons emitted by radionuclides in the environment. This report was prepared in conjunction with criteria for limiting dose equivalents to members of the public from operations of the US Department of Energy (DOE). The dose-rate conversion factors are provided for use by the DOE and its contractors in performing calculations of external dose equivalents to members of the public. The dose-rate conversion factors for external exposure to photons and electrons presented in this report are based on a methodology developed at Oak Ridge National Laboratory. However, some adjustments of the previously documented methodology have been made in obtaining the dose-rate conversion factors in this report. 42 refs., 1 fig., 4 tabs.

  2. Selecting an economically justifiable method of calculating ameliorant application rates for solonetzes with different sodium contents

    NASA Astrophysics Data System (ADS)

    Voropaeva, Z. I.

    2010-01-01

    The comparative assessment of methods for the calculation of the gypsum application rates based on the exchangeable sodium (Gedroits, Schollenberger), the estimated sodium (Schoonover), and the soil’s requirement for calcium (the version of the Omsk State Agrarian University) showed that, for the chemical amelioration of solonetzes with different contents of exchangeable sodium in Western Siberia, it is economically and ecologically advisable to calculate the ameliorant application rates from the estimated sodium. It was experimentally shown that the content of displaced magnesium used by Schoonover is a more efficient unified criterion than the value of the calcium adsorption by zonal soils. For improving the method’s accuracy, it was proposed to change the conditions of the soil preparation by regulating the concentration of the displacing solution, the interaction time, and the temperature.

  3. Monte Carlo calculation of artificial radionuclide radiation dose rates for marine species in the Western Pacific.

    PubMed

    Su, Jian; Yu, Wen; Zeng, Zhi; Ma, Hao; Chen, Liqi; Cheng, Jianping

    2014-03-01

    After the Fukushima nuclear accident, there is a widespread concern over the radioactive contamination of the marine environment. To protect non-human species, a radiation dose rate calculation model for Western Pacific marine species was established. Ten kinds of marine species in the Western Pacific were modelled by Geant4 for Monte Carlo simulation. Organisms were modelled with two ellipsoids: one represented organs and the other represented muscle. The enhanced dose rates by 10 main kinds of nuclides were calculated. According to the reported activities of three main nuclides ((134)Cs, (137)Cs and (131)I) in seawater near Fukushima coastal, the radiation risks of marine species were estimated. The results showed that the marine species near the Fukushima accident drain outlets might be at risk. But organisms that were >15 km away from the drain outlets were relatively safe.

  4. Application of a statistical bootstrapping technique to calculate growth rate variance for modelling psychrotrophic pathogen growth.

    PubMed

    Schaffner, D W

    1994-12-01

    The inherent variability or 'variance' of growth rate measurements is critical to the development of accurate predictive models in food microbiology. A large number of measurements are typically needed to estimate variance. To make these measurements requires a significant investment of time and effort. If a single growth rate determination is based on a series of independent measurements, then a statistical bootstrapping technique can be used to simulate multiple growth rate measurements from a single set of experiments. Growth rate variances were calculated for three large datasets (Listeria monocytogenes, Listeria innocua, and Yersinia enterocolitica) from our laboratory using this technique. This analysis revealed that the population of growth rate measurements at any given condition are not normally distributed, but instead follow a distribution that is between normal and Poisson. The relationship between growth rate and temperature was modeled by response surface models using generalized linear regression. It was found that the assumed distribution (i.e. normal, Poisson, gamma or inverse normal) of the growth rates influenced the prediction of each of the models used. This research demonstrates the importance of variance and assumptions about the statistical distribution of growth rates on the results of predictive microbiological models.

  5. Assessments of fluid friction factors for use in leak rate calculations

    SciTech Connect

    Chivers, T.C.

    1997-04-01

    Leak before Break procedures require estimates of leakage, and these in turn need fluid friction to be assessed. In this paper available data on flow rates through idealized and real crack geometries are reviewed in terms of a single friction factor k It is shown that for {lambda} < 1 flow rates can be bounded using correlations in terms of surface R{sub a} values. For {lambda} > 1 the database is less precise, but {lambda} {approx} 4 is an upper bound, hence in this region flow calculations can be assessed using 1 < {lambda} < 4.

  6. Diffusion Rates for Hydrogen on Pd(111) from Molecular Quantum Dynamics Calculations.

    PubMed

    Firmino, Thiago; Marquardt, Roberto; Gatti, Fabien; Dong, Wei

    2014-12-18

    The van Hove formula for the dynamical structure factor (DSF) related to particle scattering at mobile adsorbates is extended to include the relaxation of the adsorbates' vibrational states. The total rate obtained from the DSF is assumed to be the sum of a diffusion and a relaxation rate. A simple kinetic model to support this assumption is presented. To illustrate its potential applicability, the formula is evaluated using wave functions, energies, and lifetimes of vibrational states obtained for H/Pd(111) from first-principle calculations. Results show that quantum effects can be expected to be important even at room temperature.

  7. CASCADE CALCULATION OF EXOTIC HELIUM ATOMS -- s-orbit vs. p-orbit absorption rates

    NASA Astrophysics Data System (ADS)

    Koike, T.; Akaishi, Y.

    2000-09-01

    We construct a new model for the Stark-mixing process of exotic helium atoms using the impact-parameter method, and compared it with a phenomenological one used so far (sliding transition model). It turns out that the sliding transition model is justified only for low-n states and largely overestimates the Stark-mixing transition rate at high-n states. As a result of the atomic-cascade calculation, the s-(p-)orbit absorption rates in our new model are considerably smaller (larger) than those in the phenomenological one, although both our new model and old one well reproduce the experimental x-ray yields.

  8. Entrained liquid fraction calculation in adiabatic disperse-annular flows at low rate in film

    NASA Astrophysics Data System (ADS)

    Yagov, V. V.; Minko, M. V.

    2016-04-01

    In this work, we continue our study [1] and extend further an approach to low reduced pressures. An approximate model of droplets entrainment from the laminar film surface and an equation for calculating entrainment intensity are proposed. To carry out direct verification of this equation using experimental data is extremely difficult because the integral effect—liquid flow rate in a film at a dynamic equilibrium between entrainment and deposition—is usually measured in the experiments. The balance between flows of droplets entrainment and deposition corresponds to the dynamic equilibrium because of turbulent diffusion. The transcendental equation, which was obtained on the basis of this balance, contains one unknown numerical factor and allows one to calculate the liquid rate. Comparing calculation results with the experimental data for the water-air and water-helium flows at low reduced pressures (less than 0.03) has shown their good agreement at the universal value of a numerical constant, if an additional dimensionless parameter, a fourth root of vaporliquid densities ratio, is introduced. The criterion that determines the boundary of using methods of this work and that of [1] in calculations and that reflects effect of pressure and state of film surface on distribution of the liquid in the annular flow is proposed; the numerical value of this criterion has been determined.

  9. Computer program FPIP-REV calculates fission product inventory for U-235 fission

    NASA Technical Reports Server (NTRS)

    Brown, W. S.; Call, D. W.

    1967-01-01

    Computer program calculates fission product inventories and source strengths associated with the operation of U-235 fueled nuclear power reactor. It utilizes a fission-product nuclide library of 254 nuclides, and calculates the time dependent behavior of the fission product nuclides formed by fissioning of U-235.

  10. Production rate of second KK gauge bosons in UED models at LHC

    SciTech Connect

    Matsumoto, Shigeki; Sato, Joe; Yamanaka, Masato; Senami, Masato

    2009-04-17

    We calculate the production rates of the second KK photons and the second KK Z bosons at the LHC in a framework of universal extra dimension models. In the hadron collider experiment, it can be difficult to distinguish the signal of KK particles in universal extra dimension models from that of unknown heavy particles in TeV scale new models. For the discrimination, the second KK gauge bosons play an important role. Thus we calculate the production rates of the second KK gauge bosons at the LHC including all significant processes, and discuss the feasibility to confirm universal extra dimension models at the LHC.

  11. Resolving an ostensible inconsistency in calculating the evaporation rate of sessile drops.

    PubMed

    Chini, S F; Amirfazli, A

    2016-06-04

    This paper resolves an ostensible inconsistency in the literature in calculating the evaporation rate for sessile drops in a quiescent environment. The earlier models in the literature have shown that adapting the evaporation flux model for a suspended spherical drop to calculate the evaporation rate of a sessile drop needs a correction factor; the correction factor was shown to be a function of the drop contact angle, i.e. f(θ). However, there seemed to be a problem as none of the earlier models explicitly or implicitly mentioned the evaporation flux variations along the surface of a sessile drop. The more recent evaporation models include this variation using an electrostatic analogy, i.e. the Laplace equation (steady-state continuity) in a domain with a known boundary condition value, or known as the Dirichlet problem for Laplace's equation. The challenge is that the calculated evaporation rates using the earlier models seemed to differ from that of the recent models (note both types of models were validated in the literature by experiments). We have reinvestigated the recent models and found that the mathematical simplifications in solving the Dirichlet problem in toroidal coordinates have created the inconsistency. We also proposed a closed form approximation for f(θ) which is valid in a wide range, i.e. 8°≤θ≤131°. Using the proposed model in this study, theoretically, it was shown that the evaporation rate in the CWA (constant wetted area) mode is faster than the evaporation rate in the CCA (constant contact angle) mode for a sessile drop.

  12. Comparison of measured and calculated dose rates for the Castor HAW 20/28 CG.

    PubMed

    Ringleb, O; Kühl, H; Scheib, H; Rimpler, A

    2005-01-01

    In January 2003 neutron and gamma dose rate measurements at a CASTOR HAW 20/28 CG were performed by the Bundesamt für Strahlenschutz at Gorleben. First, commercial dose rate measurement devices were used, then spectral measurements with a Bonner sphere system were made to verify the results. Axial and circumferential dose rate profiles were measured near the cask surface and spectral measurements were performed for some locations. A shielding analysis of the cask was performed with the MCNP Monte Carlo Code with ENDF/B-VI cross section libraries. The cask was modelled 'as built', i.e. with its real inventory, dimensions and material densities and with the same configuration and position as in the storage facility. The average C/E-ratios are 1.3 for neutron dose rates and 1.4 for gamma dose rates. Both the measured and calculated dose rates show the same qualitative trends in the axial and circumferential direction. The spectral measurements show a variation in the spectra across the cask surface. This correlates with the variation found in the C/E-ratios. At cask midheight good agreement between the Bonner sphere system and the commercial device (LB 6411) is found with a 7% lower derived H*(10) dose rate from the Bonner sphere system.

  13. Calculation and manipulation of the chirp rates of high-order harmonics

    SciTech Connect

    Murakami, M.; Mauritsson, J.; Schafer, K.J.; Gaarde, M.B.; L'Huillier, A.

    2005-01-01

    We calculate the linear chirp rates of high-order harmonics in argon, generated by intense, 810 nm laser pulses, and explore the dependence of the chirp rate on harmonic order, driving laser intensity, and pulse duration. By using a time-frequency representation of the harmonic fields we can identify several different linear chirp contributions to the plateau harmonics. Our results, which are based on numerical integration of the time-dependent Schroedinger equation, are in good agreement with the adiabatic predictions of the strong field approximation for the chirp rates. Extending the theoretical analysis in the recent paper by Mauritsson et al. [Phys. Rev. A 70, 021801(R) (2004)], we also manipulate the chirp rates of the harmonics by adding a chirp to the driving pulse. We show that the chirp rate for harmonic q is given by the sum of the intrinsic chirp rate, which is determined by the new duration and peak intensity of the chirped driving pulse, and q times the external chirp rate.

  14. Finite Volume Numerical Methods for Aeroheating Rate Calculations from Infrared Thermographic Data

    NASA Technical Reports Server (NTRS)

    Daryabeigi, Kamran; Berry, Scott A.; Horvath, Thomas J.; Nowak, Robert J.

    2006-01-01

    The use of multi-dimensional finite volume heat conduction techniques for calculating aeroheating rates from measured global surface temperatures on hypersonic wind tunnel models was investigated. Both direct and inverse finite volume techniques were investigated and compared with the standard one-dimensional semi-infinite technique. Global transient surface temperatures were measured using an infrared thermographic technique on a 0.333-scale model of the Hyper-X forebody in the NASA Langley Research Center 20-Inch Mach 6 Air tunnel. In these tests the effectiveness of vortices generated via gas injection for initiating hypersonic transition on the Hyper-X forebody was investigated. An array of streamwise-orientated heating striations was generated and visualized downstream of the gas injection sites. In regions without significant spatial temperature gradients, one-dimensional techniques provided accurate aeroheating rates. In regions with sharp temperature gradients caused by striation patterns multi-dimensional heat transfer techniques were necessary to obtain more accurate heating rates. The use of the one-dimensional technique resulted in differences of 20% in the calculated heating rates compared to 2-D analysis because it did not account for lateral heat conduction in the model.

  15. Finite Volume Numerical Methods for Aeroheating Rate Calculations from Infrared Thermographic Data

    NASA Technical Reports Server (NTRS)

    Daryabeigi, Kamran; Berry, Scott A.; Horvath, Thomas J.; Nowak, Robert J.

    2003-01-01

    The use of multi-dimensional finite volume numerical techniques with finite thickness models for calculating aeroheating rates from measured global surface temperatures on hypersonic wind tunnel models was investigated. Both direct and inverse finite volume techniques were investigated and compared with the one-dimensional semi -infinite technique. Global transient surface temperatures were measured using an infrared thermographic technique on a 0.333-scale model of the Hyper-X forebody in the Langley Research Center 20-Inch Mach 6 Air tunnel. In these tests the effectiveness of vortices generated via gas injection for initiating hypersonic transition on the Hyper-X forebody were investigated. An array of streamwise orientated heating striations were generated and visualized downstream of the gas injection sites. In regions without significant spatial temperature gradients, one-dimensional techniques provided accurate aeroheating rates. In regions with sharp temperature gradients due to the striation patterns two-dimensional heat transfer techniques were necessary to obtain accurate heating rates. The use of the one-dimensional technique resulted in differences of 20% in the calculated heating rates because it did not account for lateral heat conduction in the model.

  16. Quantum chemical calculations of tryptophan → heme electron and excitation energy transfer rates in myoglobin.

    PubMed

    Suess, Christian J; Hirst, Jonathan D; Besley, Nicholas A

    2017-04-01

    The development of optical multidimensional spectroscopic techniques has opened up new possibilities for the study of biological processes. Recently, ultrafast two-dimensional ultraviolet spectroscopy experiments have determined the rates of tryptophan → heme electron transfer and excitation energy transfer for the two tryptophan residues in myoglobin (Consani et al., Science, 2013, 339, 1586). Here, we show that accurate prediction of these rates can be achieved using Marcus theory in conjunction with time-dependent density functional theory. Key intermediate residues between the donor and acceptor are identified, and in particular the residues Val68 and Ile75 play a critical role in calculations of the electron coupling matrix elements. Our calculations demonstrate how small changes in structure can have a large effect on the rates, and show that the different rates of electron transfer are dictated by the distance between the heme and tryptophan residues, while for excitation energy transfer the orientation of the tryptophan residues relative to the heme is important. © 2017 The Authors Journal of Computational Chemistry Published by Wiley Periodicals, Inc.

  17. Reduced Equations for Calculating the Combustion Rates of Jet-A and Methane Fuel

    NASA Technical Reports Server (NTRS)

    Molnar, Melissa; Marek, C. John

    2003-01-01

    Simplified kinetic schemes for Jet-A and methane fuels were developed to be used in numerical combustion codes, such as the National Combustor Code (NCC) that is being developed at Glenn. These kinetic schemes presented here result in a correlation that gives the chemical kinetic time as a function of initial overall cell fuel/air ratio, pressure, and temperature. The correlations would then be used with the turbulent mixing times to determine the limiting properties and progress of the reaction. A similar correlation was also developed using data from NASA's Chemical Equilibrium Applications (CEA) code to determine the equilibrium concentration of carbon monoxide as a function of fuel air ratio, pressure, and temperature. The NASA Glenn GLSENS kinetics code calculates the reaction rates and rate constants for each species in a kinetic scheme for finite kinetic rates. These reaction rates and the values obtained from the equilibrium correlations were then used to calculate the necessary chemical kinetic times. Chemical kinetic time equations for fuel, carbon monoxide, and NOx were obtained for both Jet-A fuel and methane.

  18. Mixed Quantum-Classical Liouville Approach for Calculating Proton-Coupled Electron-Transfer Rate Constants.

    PubMed

    Shakib, Farnaz; Hanna, Gabriel

    2016-07-12

    In this work, we derive a general mixed quantum-classical formula for calculating thermal proton-coupled electron-transfer (PCET) rate constants, starting from the time integral of the quantum flux-flux correlation function. This formula allows for the direct simulation of PCET reaction dynamics via the mixed quantum-classical Liouville approach. Owing to the general nature of the derivation, this formula does not rely on any prior mechanistic assumptions and can be applied across a wide range of electronic and protonic coupling regimes. To test the validity of this formula, we applied it to a reduced model of a condensed-phase PCET reaction. Good agreement with the numerically exact rate constant is obtained, demonstrating the accuracy of our formalism. We believe that this approach constitutes a solid foundation for future investigations of the rates and mechanisms of a wide range of PCET reactions.

  19. Quantum three-body calculation of nonresonant triple-{alpha} reaction rate at low temperatures

    SciTech Connect

    Ogata, Kazuyuki; Kan, Masataka; Kamimura, Masayasu

    2010-08-12

    Triple-{alpha} reaction rate is re-evaluated by directly solving the three-body Schroedinger equation. The resonant and nonresonant processes are treated on the same footing using the continuum-discretized coupled-channels method for three-body scattering. An accurate description of the {alpha}-{alpha} nonresonant states significantly quenches the Coulomb barrier between the first two {alpha}-particles and the third {alpha}-particle. Consequently, the{alpha}-{alpha} nonresonant continuum states give a markedly larger contribution at low temperatures than that reported in previous studies. We show that Nomoto's method for three-body nonresonant capture processes, which is adopted in the NACRE compilation and many other studies, is a crude approximation of the accurate quantum three-body model calculation. We find an increase in triple-{alpha} reaction rate by about 20 orders of magnitude around 10{sup 7} K compared with the rate of NACRE.

  20. Quantum three-body calculation of nonresonant triple-alpha reaction rate at low temperatures

    SciTech Connect

    Ogata, Kazuyuki; Kan, Masataka; Kamimura, Masayasu

    2010-06-01

    Triple-alpha reaction rate is re-evaluated by directly solving the three-body Schroedinger equation. The resonant and nonresonant processes are treated on the same footing using the continuum-discretized coupled-channels method for three-body scattering. An accurate description of the alpha-alpha nonresonant states significantly quenches the Coulomb barrier between the first two alpha-particles and the third alpha-particle. Consequently, the alpha-alpha nonresonant continuum states give a markedly larger contribution at low temperatures than that reported in previous studies. We show that Nomoto's method for three-body nonresonant capture processes, which is adopted in the NACRE compilation and many other studies, is a crude approximation of the accurate quantum three-body model calculation. We find an increase in triple-alpha reaction rate by 26 orders of magnitude around 10{sup 7} K compared with the rate of NACRE.

  1. 45 CFR 261.36 - Do welfare reform waivers affect the calculation of a State's participation rates?

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... of a State's participation rates? 261.36 Section 261.36 Public Welfare Regulations Relating to Public... They Count? § 261.36 Do welfare reform waivers affect the calculation of a State's participation rates? A welfare reform waiver could affect the calculation of a State's participation rate, pursuant...

  2. 45 CFR 261.36 - Do welfare reform waivers affect the calculation of a State's participation rates?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... of a State's participation rates? 261.36 Section 261.36 Public Welfare Regulations Relating to Public... They Count? § 261.36 Do welfare reform waivers affect the calculation of a State's participation rates? A welfare reform waiver could affect the calculation of a State's participation rate, pursuant...

  3. 45 CFR 261.36 - Do welfare reform waivers affect the calculation of a State's participation rates?

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... a State's participation rates? 261.36 Section 261.36 Public Welfare Regulations Relating to Public... They Count? § 261.36 Do welfare reform waivers affect the calculation of a State's participation rates? A welfare reform waiver could affect the calculation of a State's participation rate, pursuant...

  4. 45 CFR 261.36 - Do welfare reform waivers affect the calculation of a State's participation rates?

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... a State's participation rates? 261.36 Section 261.36 Public Welfare Regulations Relating to Public... They Count? § 261.36 Do welfare reform waivers affect the calculation of a State's participation rates? A welfare reform waiver could affect the calculation of a State's participation rate, pursuant...

  5. 45 CFR 261.36 - Do welfare reform waivers affect the calculation of a State's participation rates?

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... of a State's participation rates? 261.36 Section 261.36 Public Welfare Regulations Relating to Public... They Count? § 261.36 Do welfare reform waivers affect the calculation of a State's participation rates? A welfare reform waiver could affect the calculation of a State's participation rate, pursuant...

  6. Patient-specific dose calculation methods for high-dose-rate iridium-192 brachytherapy

    NASA Astrophysics Data System (ADS)

    Poon, Emily S.

    In high-dose-rate 192Ir brachytherapy, the radiation dose received by the patient is calculated according to the AAPM Task Group 43 (TG-43) formalism. This table-based dose superposition method uses dosimetry parameters derived with the radioactive 192Ir source centered in a water phantom. It neglects the dose perturbations caused by inhomogeneities, such as the patient anatomy, applicators, shielding, and radiographic contrast solution. In this work, we evaluated the dosimetric characteristics of a shielded rectal applicator with an endocavitary balloon injected with contrast solution. The dose distributions around this applicator were calculated by the GEANT4 Monte Carlo (MC) code and measured by ionization chamber and GAFCHROMIC EBT film. A patient-specific dose calculation study was then carried out for 40 rectal treatment plans. The PTRAN_CT MC code was used to calculate the dose based on computed tomography (CT) images. This study involved the development of BrachyGUI, an integrated treatment planning tool that can process DICOM-RT data and create PTRAN_CT input initialization files. BrachyGUI also comes with dose calculation and evaluation capabilities. We proposed a novel scatter correction method to account for the reduction in backscatter radiation near tissue-air interfaces. The first step requires calculating the doses contributed by primary and scattered photons separately, assuming a full scatter environment. The scatter dose in the patient is subsequently adjusted using a factor derived by MC calculations, which depends on the distances between the point of interest, the 192Ir source, and the body contour. The method was validated for multicatheter breast brachytherapy, in which the target and skin doses for 18 patient plans agreed with PTRAN_CT calculations better than 1%. Finally, we developed a CT-based analytical dose calculation method. It corrects for the photon attenuation and scatter based upon the radiological paths determined by ray tracing

  7. Calculating inspector probability of detection using performance demonstration program pass rates

    NASA Astrophysics Data System (ADS)

    Cumblidge, Stephen; D'Agostino, Amy

    2016-02-01

    The United States Nuclear Regulatory Commission (NRC) staff has been working since the 1970's to ensure that nondestructive testing performed on nuclear power plants in the United States will provide reasonable assurance of structural integrity of the nuclear power plant components. One tool used by the NRC has been the development and implementation of the American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code Section XI Appendix VIII[1] (Appendix VIII) blind testing requirements for ultrasonic procedures, equipment, and personnel. Some concerns have been raised, over the years, by the relatively low pass rates for the Appendix VIII qualification testing. The NRC staff has applied statistical tools and simulations to determine the expected probability of detection (POD) for ultrasonic examinations under ideal conditions based on the pass rates for the Appendix VIII qualification tests for the ultrasonic testing personnel. This work was primarily performed to answer three questions. First, given a test design and pass rate, what is the expected overall POD for inspectors? Second, can we calculate the probability of detection for flaws of different sizes using this information? Finally, if a previously qualified inspector fails a requalification test, does this call their earlier inspections into question? The calculations have shown that one can expect good performance from inspectors who have passed appendix VIII testing in a laboratory-like environment, and the requalification pass rates show that the inspectors have maintained their skills between tests. While these calculations showed that the PODs for the ultrasonic inspections are very good under laboratory conditions, the field inspections are conducted in a very different environment. The NRC staff has initiated a project to systematically analyze the human factors differences between qualification testing and field examinations. This work will be used to evaluate and prioritize

  8. Calculation of doublet capture rate for muon capture in deuterium within chiral effective field theory

    NASA Astrophysics Data System (ADS)

    Adam, J.; Tater, M.; Truhlík, E.; Epelbaum, E.; Machleidt, R.; Ricci, P.

    2012-03-01

    The doublet capture rate Λ1 / 2 of the negative muon capture in deuterium is calculated employing the nuclear wave functions generated from accurate nucleon-nucleon (NN) potentials constructed at next-to-next-to-next-to-leading order of heavy-baryon chiral perturbation theory and the weak meson exchange current operator derived within the same formalism. All but one of the low-energy constants that enter the calculation were fixed from pion-nucleon and nucleon-nucleon scattering data. The low-energy constant dˆR (cD), which cannot be determined from the purely two-nucleon data, was extracted recently from the triton β-decay and the binding energies of the three-nucleon systems. The calculated values of Λ1 / 2 show a rather large spread for the used values of the dˆR. Precise measurement of Λ1 / 2 in the future will not only help to constrain the value of dˆR, but also provide a highly nontrivial test of the nuclear chiral EFT framework. Besides, the precise knowledge of the constant dˆR will allow for consistent calculations of other two-nucleon weak processes, such as proton-proton fusion and solar neutrino scattering on deuterons, which are important for astrophysics.

  9. Quantum Tunneling Rates of Gas-Phase Reactions from On-the-Fly Instanton Calculations.

    PubMed

    Beyer, Adrian N; Richardson, Jeremy O; Knowles, Peter J; Rommel, Judith; Althorpe, Stuart C

    2016-11-03

    The instanton method obtains approximate tunneling rates from the minimum-action path (known as the instanton) linking reactants to the products at a given temperature. An efficient way to find the instanton is to search for saddle-points on the ring-polymer potential surface, which is obtained by expressing the quantum Boltzmann operator as a discrete path-integral. Here we report a practical implementation of this ring-polymer form of instanton theory into the Molpro electronic-structure package, which allows the rates to be computed on-the-fly, without the need for a fitted analytic potential-energy surface. As a test case, we compute tunneling rates for the benchmark H + CH4 reaction, showing how the efficiency of the instanton method allows the user systematically to converge the tunneling rate with respect to the level of electronic-structure theory.

  10. Exergy and Its Efficiency Calculations in Ferrochrome Production

    NASA Astrophysics Data System (ADS)

    Ramakrishna, G.; Kadrolkar, Ameya; Srikakulapu, N. Gurulaxmi

    2015-04-01

    Ferrochrome production is a high energy intensive process consuming around 3000 to 3500 kWh/t of electrical energy. Ferrochrome is produced by smelting of different grades of chromite ore with coke and fluxing agents such as lime, dolomite, and quartz in a submerged arc furnace (SAF). Apart from the production of ferrochrome, co-products that are produced during the process include carbon monoxide rich off-gas and slag. The slag is cooled with high pressure jet water which results in the formation of slag granules. In the present practice, off-gas generated from the SAF is used for ladle preheating, as fuel in sinter plant, while the remaining is unutilized. Approximately 34 to 40 pct of heat from off-gas is utilized, while the remaining 60 to 66 pct of the off-gas can be utilized for generating electricity by gas combustion turbine. The concept of exergy is applied to monitor the existing process and to understand the feasibility of modification. In the present study, comparison of exergy efficiency for existing process and two adapted case studies has been performed, involving utilization of off-gas for sintering and power generation and waste heat utilization from dry slag granulation. It is observed that there was considerable increase in exergy efficiency for waste heat utilization by dry granulation case study when compared with other two case studies.

  11. New reaction rates for improved primordial D /H calculation and the cosmic evolution of deuterium

    NASA Astrophysics Data System (ADS)

    Coc, Alain; Petitjean, Patrick; Uzan, Jean-Philippe; Vangioni, Elisabeth; Descouvemont, Pierre; Iliadis, Christian; Longland, Richard

    2015-12-01

    Primordial or big bang nucleosynthesis (BBN) is one of the three historically strong evidences for the big bang model. Standard BBN is now a parameter-free theory, since the baryonic density of the Universe has been deduced with an unprecedented precision from observations of the anisotropies of the cosmic microwave background radiation. There is a good agreement between the primordial abundances of 4He, D, 3He, and 7Li deduced from observations and from primordial nucleosynthesis calculations. However, the 7Li calculated abundance is significantly higher than the one deduced from spectroscopic observations and remains an open problem. In addition, recent deuterium observations have drastically reduced the uncertainty on D /H , to reach a value of 1.6%. It needs to be matched by BBN predictions whose precision is now limited by thermonuclear reaction rate uncertainties. This is especially important as many attempts to reconcile Li observations with models lead to an increased D prediction. Here, we reevaluate the d (p ,γ )3He, d (d ,n ) 3H3, and d (d ,p ) 3H reaction rates that govern deuterium destruction, incorporating new experimental data and carefully accounting for systematic uncertainties. Contrary to previous evaluations, we use theoretical ab initio models for the energy dependence of the S factors. As a result, these rates increase at BBN temperatures, leading to a reduced value of D /H =(2.45 ±0.10 )×10-5 (2 σ ), in agreement with observations.

  12. Benchmarking of MCNP for calculating dose rates at an interim storage facility for nuclear waste.

    PubMed

    Heuel-Fabianek, Burkhard; Hille, Ralf

    2005-01-01

    During the operation of research facilities at Research Centre Jülich, Germany, nuclear waste is stored in drums and other vessels in an interim storage building on-site, which has a concrete shielding at the side walls. Owing to the lack of a well-defined source, measured gamma spectra were unfolded to determine the photon flux on the surface of the containers. The dose rate simulation, including the effects of skyshine, using the Monte Carlo transport code MCNP is compared with the measured dosimetric data at some locations in the vicinity of the interim storage building. The MCNP data for direct radiation confirm the data calculated using a point-kernel method. However, a comparison of the modelled dose rates for direct radiation and skyshine with the measured data demonstrate the need for a more precise definition of the source. Both the measured and the modelled dose rates verified the fact that the legal limits (<1 mSv a(-1)) are met in the area outside the perimeter fence of the storage building to which members of the public have access. Using container surface data (gamma spectra) to define the source may be a useful tool for practical calculations and additionally for benchmarking of computer codes if the discussed critical aspects with respect to the source can be addressed adequately.

  13. A line rate calculation method for arbitrary directional imaging of an Earth observing satellite

    NASA Astrophysics Data System (ADS)

    Jeon, Moon-Jin; Kim, Eunghyun; Lim, Seong-Bin; Choi, Seok-Weon

    2016-10-01

    For an earth observing satellite, a line rate is the number of lines which the CCD of push broom type camera scans in a second. It can be easily calculated by ground velocity divided by ground sample distance. Accurate calculation of line rate is necessary to obtain high quality image using TDI CCD. The earth observing satellite has four types of imaging missions which are strip imaging, stereo imaging, multi-point imaging, and arbitrary directional imaging. For the first three types of imaging, ground scanning direction is aligned with satellite velocity direction. Therefore, if the orbit propagation and spacecraft attitude information are available, the ground velocity and ground sample distance could be easily calculated. However, the calculation method might not be applicable to the arbitrary directional imaging. In the arbitrary directional imaging mode, the ground velocity is not fixed value which could be directly derived by orbit information. Furthermore, the ground sample distance might not be easily calculated by simple trigonometry which is possible for the other types of imaging. In this paper, we proposed a line rate calculation method for the arbitrary directional imaging. We applied spherical geometry to derive the equation of ground point which is the intersection between the line of sight vector of the camera and earth surface. The derivative of this equation for time is the ground velocity except the factor of earth rotation. By adding this equation and earth rotation factor, the true ground velocity vector could be derived. For the ground sample distance, we applied the equation of circle and ellipse for yaw angle difference. The equation of circle is used for the yaw angle representation on the plane which is orthogonal to the line of sight vector. The equation of ellipse is used for the yaw angle representation on the ground surface. We applied the proposed method to the KOMPSAT-3A (Korea Multi-Purpose Satellite 3A) mission which is the first

  14. Hypotheses of calculation of the water flow rate evaporated in a wet cooling tower

    SciTech Connect

    Bourillot, C.

    1983-08-01

    The method developed by Poppe at the University of Hannover to calculate the thermal performance of a wet cooling tower fill is presented. The formulation of Poppe is then validated using full-scale test data from a wet cooling tower at the power station at Neurath, Federal Republic of Germany. It is shown that the Poppe method predicts the evaporated water flow rate almost perfectly and the condensate content of the warm air with good accuracy over a wide range of ambient conditions. The simplifying assumptions of the Merkel theory are discussed, and the errors linked to these assumptions are systematically described, then illustrated with the test data.

  15. Advanced Fuel Cycle Initiative - Projected Linear Heat Generation Rate and Burnup Calculations

    SciTech Connect

    Richard G. Ambrosek; Gray S. Chang; Debbie J. Utterbeck

    2005-02-01

    This report provides documentation of the physics analysis performed to determine the linear heat generation rate (LHGR) and burnup calculations for the Advanced Fuel Cycle Initiative (AFCI) tests, AFC-1D, AFC-1H, and AFC-1G. The AFC-1D and AFC-1H tests consists of low-fertile metallic fuel compositions and the AFC-1G test consists of non-fertile and low-fertile nitride compositions. These tests will be irradiated in the East Flux Trap (EFT) positions E1, E2, and E3, respectively, during Advanced Test Reactor (ATR) Cycle 135B.

  16. 19 CFR 351.407 - Calculation of constructed value and cost of production.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... ANTIDUMPING AND COUNTERVAILING DUTIES Calculation of Export Price, Constructed Export Price, Fair Value, and Normal Value § 351.407 Calculation of constructed value and cost of production. (a) Introduction. This... 19 Customs Duties 3 2013-04-01 2013-04-01 false Calculation of constructed value and cost...

  17. 19 CFR 351.407 - Calculation of constructed value and cost of production.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... ANTIDUMPING AND COUNTERVAILING DUTIES Calculation of Export Price, Constructed Export Price, Fair Value, and Normal Value § 351.407 Calculation of constructed value and cost of production. (a) Introduction. This... 19 Customs Duties 3 2012-04-01 2012-04-01 false Calculation of constructed value and cost...

  18. 19 CFR 351.407 - Calculation of constructed value and cost of production.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... ANTIDUMPING AND COUNTERVAILING DUTIES Calculation of Export Price, Constructed Export Price, Fair Value, and Normal Value § 351.407 Calculation of constructed value and cost of production. (a) Introduction. This... 19 Customs Duties 3 2014-04-01 2014-04-01 false Calculation of constructed value and cost...

  19. Calculation of Top Squark Production in Proton-Proton Collisions

    SciTech Connect

    Linville, Andrea J.; /Washington U., St. Louis /SLAC

    2010-08-25

    Though the Standard Model of particle physics is an elegant theory which has been studied extensively for decades, it leaves many fundamental questions unanswered and is thus widely believed to be incomplete. Possible extensions to the Standard Model (SM) have been postulated and are in the process of being investigated experimentally. The most promising extension is the Minimal Supersymmetric Model (MSSM) which relates every SM particle to a superpartner that differs by 1/2 unit of spin. The lightest supersymmetric quark, or squark, is expected to be the stop, and the search for this particle is an important experimental task. In this analysis, we use parton-model methods to predict the stop production cross section in proton-proton collisions at LHC energies.

  20. Calculation of energy relaxation rates of fast particles by phonons in crystals

    NASA Astrophysics Data System (ADS)

    Prange, Micah; Campbell, Luke; Wu, Dangxin; Kerisit, Sebastien

    2015-03-01

    We present ab initio calculations of the temperature-dependent exchange of energy between a classical charged point-particle and the phonons of a crystalline material. The phonons, which are computed using density functional perturbation theory (DFPT) methods, interact with the moving particle via the Coulomb interaction between the density induced in the material by phonon excitation and the charge of the classical particle. Energy relaxation rates are computed using time-dependent perturbation theory. The method, which is applicable wherever DFPT is, is illustrated with results for several important scintillators whose performance is affected by electron thermalization. We discuss the influence of the form assumed for quasiparticle dispersion on theoretical estimates of electron cooling rates. This research was supported by the National Nuclear Security Administration, Office of DNN R&D, of the DOE. PNNL is operated by Battelle Memorial Institute under Contract DE-AC0576RL01830.

  1. Sample size calculation for testing differences between cure rates with the optimal log-rank test.

    PubMed

    Wu, Jianrong

    2017-01-01

    In this article, sample size calculations are developed for use when the main interest is in the differences between the cure rates of two groups. Following the work of Ewell and Ibrahim, the asymptotic distribution of the weighted log-rank test is derived under the local alternative. The optimal log-rank test under the proportional distributions alternative is discussed, and sample size formulas for the optimal and standard log-rank tests are derived. Simulation results show that the proposed formulas provide adequate sample size estimation for trial designs and that the optimal log-rank test is more efficient than the standard log-rank test, particularly when both cure rates and percentages of censoring are small.

  2. Carbon Calculator for Land Use Change from Biofuels Production (CCLUB). Users' Manual and Technical Documentation

    SciTech Connect

    Dunn, Jennifer B.; Qin, Zhangcai; Mueller, Steffen; Kwon, Ho-young; Wander, Michelle M.; Wang, Michael

    2014-09-01

    The Carbon Calculator for Land Use Change from Biofuels Production (CCLUB) calculates carbon emissions from land use change (LUC) for four different ethanol production pathways including corn grain ethanol and cellulosic ethanol from corn stover, Miscanthus, and switchgrass. This document discusses the version of CCLUB released September 30, 2014 which includes corn and three cellulosic feedstocks: corn stover, Miscanthus, and switchgrass.

  3. In vitro O 2 fluxes compared with 14C production and other rate terms during the JGOFS Equatorial Pacific experiment

    NASA Astrophysics Data System (ADS)

    Bender, Michael; Orchardo, Joe; Dickson, Mary-Lynn; Barber, Richard; Lindley, Steven

    1999-04-01

    We report rates of gross and net O 2 production measured in vitro during JGOFS cruises in the equatorial Pacific in spring and fall, 1992. We scale O 2 productivities to net and gross C production. We then compare the calculated rates with 14C production and with new/export production measured by various techniques. 14C productivities in samples incubated for 24 h are about 45% of gross carbon production rates calculated from gross O 2 production. The difference is compatible with expected rates of the Mehler reaction, photorespiration, excretion, and community mitochondrial respiration. 14C production rates are similar to net carbon production rates in the upper half of the euphotic zone. At lower irradiances, where net C production can be zero or less, 14C productivities lie between net community production and gross primary production. Net carbon production rates in vitro are a factor of =4-20 times greater than estimates from drifting sediment trap and tracer transport studies. This difference probably reflects anomalous accumulation of POC in bottles because of the exclusion of grazers.

  4. Cosmic-ray-produced stable nuclides: various production rates and their implications

    SciTech Connect

    Reedy, R.C.

    1981-06-15

    The rates for a number of reactions producing certain stable nuclides, such as /sup 3/He and /sup 4/He, and fission in the moon are calculated for galactic-cosmic-ray particles and for solar protons. Solar-proton-induced reactions with bromine usually are not an important source of cosmogenic Kr isotopes. The /sup 130/Ba(n,p) reaction cannot account for the undercalculation of /sup 130/Xe production rates. Calculated production rates of /sup 15/N, /sup 13/C, and /sup 2/H agree fairly well with rates inferred from measured excesses of these isotopes in samples with long exposure ages. Cosmic-ray-induced fission of U and Th can produce significant amounts of fission tracks and of /sup 86/Kr, /sup 134/Xe, and /sup 136/Xe, especially in samples with long exposures to cosmic-ray particles.

  5. Improved calculation of total cross section for pair production by relativistic heavy ions

    NASA Technical Reports Server (NTRS)

    Eby, P. B.

    1989-01-01

    A calculation of the total cross section for direct electron-positron pair production by heavy ions is described. It combines the use of the Weizsaecker-Williams method for low-energy transfers and existing calculations for high-energy transfers. Higher-order corrections to the total cross section are calculated based on the Weizsaecher-Williams method and existing results for pair production by photons.

  6. Path-integral virial estimator for reaction rate calculation basedon the quantum instanton aproximation

    SciTech Connect

    Yang, Sandy; Yamamoto, Takeshi; Miller, William H.

    2005-11-28

    The quantum instanton approximation is a type of quantum transition state theory that calculates the chemical reaction rate using the reactive flux correlation function and its low order derivatives at time zero. Here we present several path-integral estimators for the latter quantities, which characterize the initial decay profile of the flux correlation function. As with the internal energy or heat capacity calculation, different estimators yield different variances (and therefore different convergence properties) in a Monte Carlo calculation. Here we obtain a virial(-type) estimator by using a coordinate scaling procedure rather than integration by parts, which allows more computational benefits. We also consider two different methods for treating the flux operator, i.e., local-path and global-path approaches, in which the latter achieves a smaller variance at the cost of using second-order potential derivatives. Numerical tests are performed for a one-dimensional Eckart barrier and a model proton transfer reaction in a polar solvent, which illustrates the reduced variance of the virial estimator over the corresponding thermodynamic estimator.

  7. Achievable information rates calculation for optical OFDM few-mode fiber long-haul transmission systems.

    PubMed

    Lin, Changyu; Djordjevic, Ivan B; Zou, Ding

    2015-06-29

    We propose a method to estimate the lower bound of achievable information rates (AIRs) of high speed orthogonal frequency-division multiplexing (OFDM) in spatial division multiplexing (SDM) optical long-haul transmission systems. The estimation of AIR is based on the forward recursion of multidimensional super-symbol efficient sliding-window Bahl-Cocke-Jelinek-Raviv (BCJR) algorithm. We consider most of the degradations of fiber links including nonlinear effects in few-mode fiber (FMF). This method does not consider the SDM as a simple multiplexer of independent data streams, but provides a super-symbol version for AIR calculation over spatial channels. This super-symbol version of AIR calculation algorithm, in principle, can be used for arbitrary multiple-input-multiple-output (MIMO)-SDM system with channel memory consideration. We illustrate this method by performing Monte Carlo simulations in a complete FMF model. Both channel model and algorithm for calculation of the AIRs are described in details. We also compare the AIRs results for QPSK/16QAM in both single mode fiber (SMF)- and FMF-based optical OFDM transmission.

  8. Rotation rate measurement and calculation for calcite crystals in a C-point mode

    NASA Astrophysics Data System (ADS)

    Herne, Catherine M.; O'Brien, Ann E.

    2016-09-01

    A polarization singularity mode offers a unique tool for actuating an array of birefringent calcite crystals, and measurement of the rotation rates of these crystals is in turn a way to image modes with varying polarization. In this work, we show the calculated and measured rotation rates of individual calcite crystals in a C-point mode and their dependence on three key factors: polarization, mode intensity profile, and crystal size. The C-point is a polarization singularity mode in which the mode has a circularly polarized center surrounded by elliptically polarized regions, with the orientation of the ellipse varying azimuthally and the degree of ellipticity changing radially. The beam is focused into an optical trapping region, and micron-sized birefringent calcite crystals in solution are positioned at key points in the mode. The crystals experience different torques at each location. The spin angular momentum of the light is proportional to the degree of ellipticity and to the intensity at each point in the mode. Our technique for generating C-point modes results in an intensity profile with a nonlinear radial dependence. Our crystal growth process generates crystals of varying width and thickness; the crystal size and shape affect the drag forces and light torque acting on them. We explain the crystal growth process and estimations of torque, demonstrate the rate and direction of rotation of calcite crystals placed at different points in the laser mode, and discuss the difference between the estimated and measured rotation rates.

  9. Direct calculation of ice homogeneous nucleation rate for a molecular model of water

    PubMed Central

    Haji-Akbari, Amir; Debenedetti, Pablo G.

    2015-01-01

    Ice formation is ubiquitous in nature, with important consequences in a variety of environments, including biological cells, soil, aircraft, transportation infrastructure, and atmospheric clouds. However, its intrinsic kinetics and microscopic mechanism are difficult to discern with current experiments. Molecular simulations of ice nucleation are also challenging, and direct rate calculations have only been performed for coarse-grained models of water. For molecular models, only indirect estimates have been obtained, e.g., by assuming the validity of classical nucleation theory. We use a path sampling approach to perform, to our knowledge, the first direct rate calculation of homogeneous nucleation of ice in a molecular model of water. We use TIP4P/Ice, the most accurate among existing molecular models for studying ice polymorphs. By using a novel topological approach to distinguish different polymorphs, we are able to identify a freezing mechanism that involves a competition between cubic and hexagonal ice in the early stages of nucleation. In this competition, the cubic polymorph takes over because the addition of new topological structural motifs consistent with cubic ice leads to the formation of more compact crystallites. This is not true for topological hexagonal motifs, which give rise to elongated crystallites that are not able to grow. This leads to transition states that are rich in cubic ice, and not the thermodynamically stable hexagonal polymorph. This mechanism provides a molecular explanation for the earlier experimental and computational observations of the preference for cubic ice in the literature. PMID:26240318

  10. Direct Calculation of the Rate of Homogeneous Ice Nucleation for a Molecular Model of Water

    NASA Astrophysics Data System (ADS)

    Haji-Akbari, Amir; Debenedetti, Pablo

    Ice formation is ubiquitous in nature, with important consequences in many systems and environments. However, its intrinsic kinetics and mechanism are difficult to discern with experiments. Molecular simulations of ice nucleation are also challenging due to sluggish structural relaxation and the large nucleation barriers, and direct calculations of homogeneous nucleation rates have only been achieved for mW, a monoatomic coarse-grained model of water. For the more realistic molecular models, only indirect estimates have been obtained by assuming the validity of classical nucleation theory. Here, we use a coarse-grained variant of a path sampling approach known as forward-flux sampling to perform the first direct calculation of the homogeneous nucleation rate for TIP4P/Ice, which is the most accurate water model for studying ice polymorphs. By using a novel topological order parameter, we are able to identify a freezing mechanism that involves a competition between cubic and hexagonal ice polymorphs. In this competition, cubic ice wins as its growth leads to more compact crystallites

  11. Direct calculation of ice homogeneous nucleation rate for a molecular model of water.

    PubMed

    Haji-Akbari, Amir; Debenedetti, Pablo G

    2015-08-25

    Ice formation is ubiquitous in nature, with important consequences in a variety of environments, including biological cells, soil, aircraft, transportation infrastructure, and atmospheric clouds. However, its intrinsic kinetics and microscopic mechanism are difficult to discern with current experiments. Molecular simulations of ice nucleation are also challenging, and direct rate calculations have only been performed for coarse-grained models of water. For molecular models, only indirect estimates have been obtained, e.g., by assuming the validity of classical nucleation theory. We use a path sampling approach to perform, to our knowledge, the first direct rate calculation of homogeneous nucleation of ice in a molecular model of water. We use TIP4P/Ice, the most accurate among existing molecular models for studying ice polymorphs. By using a novel topological approach to distinguish different polymorphs, we are able to identify a freezing mechanism that involves a competition between cubic and hexagonal ice in the early stages of nucleation. In this competition, the cubic polymorph takes over because the addition of new topological structural motifs consistent with cubic ice leads to the formation of more compact crystallites. This is not true for topological hexagonal motifs, which give rise to elongated crystallites that are not able to grow. This leads to transition states that are rich in cubic ice, and not the thermodynamically stable hexagonal polymorph. This mechanism provides a molecular explanation for the earlier experimental and computational observations of the preference for cubic ice in the literature.

  12. Comparison of measured and calculated dose rates near nuclear medicine patients.

    PubMed

    Yi, Y; Stabin, M G; McKaskle, M H; Shone, M D; Johnson, A B

    2013-08-01

    Widely used release criteria for patients receiving radiopharmaceuticals (NUREG-1556, Vol. 9, Rev.1, Appendix U) are known to be overly conservative. The authors measured external exposure rates near patients treated with I, Tc, and F and compared the measurements to calculated values using point and line source models. The external exposure dose rates for 231, 11, and 52 patients scanned or treated with I, Tc, and F, respectively, were measured at 0.3 m and 1.0 m shortly after radiopharmaceutical administration. Calculated values were always higher than measured values and suggested the application of "self-shielding factors," as suggested by Siegel et al. in 2002. The self-shielding factors of point and line source models for I at 1 m were 0.60 ± 0.16 and 0.73 ± 0.20, respectively. For Tc patients, the self-shielding factors for point and line source models were 0.44 ± 0.19 and 0.55 ± 0.23, and the values were 0.50 ± 0.09 and 0.60 ± 0.12, respectively, for F (all FDG) patients. Treating patients as unshielded point sources of radiation is clearly inappropriate. In reality, they are volume sources, but treatment of their exposures using a line source model with appropriate self-shielding factors produces a more realistic, but still conservative, approach for managing patient release.

  13. Very narrow band model calculations of atmospheric fluxes and cooling rates

    SciTech Connect

    Bernstein, L.S.; Berk, A.; Acharya, P.K.; Robertson, D.C.

    1996-10-15

    A new very narrow band model (VNBM) approach has been developed and incorporated into the MODTRAN atmospheric transmittance-radiance code. The VNBM includes a computational spectral resolution of 1 cm{sup {minus}1}, a single-line Voigt equivalent width formalism that is based on the Rodgers-Williams approximation and accounts for the finite spectral width of the interval, explicit consideration of line tails, a statistical line overlap correction, a new sublayer integration approach that treats the effect of the sublayer temperature gradient on the path radiance, and the Curtis-Godson (CG) approximation for inhomogeneous paths. A modified procedure for determining the line density parameter 1/d is introduced, which reduces its magnitude. This results in a partial correction of the VNBM tendency to overestimate the interval equivalent widths. The standard two parameter CG approximation is used for H{sub 2}O and CO{sub 2}, while the Goody three parameter CG approximation is used for O{sub 3}. Atmospheric flux and cooling rate predictions using a research version of MODTRAN, MODR, are presented for H{sub 2}O (with and without the continuum), CO{sub 2}, and O{sub 3} for several model atmospheres. The effect of doubling the CO{sub 2} concentration is also considered. These calculations are compared to line-by-line (LBL) model calculations using the AER, GLA, GFDL, and GISS codes. The MODR predictions fall within the spread of the LBL results. The effects of decreasing the band model spectral resolution are illustrated using CO{sub 2} cooling rate and flux calculations. 36 refs., 18 figs., 1 tab.

  14. Factors Influencing Watershed Average Erosion Rates Calculated from Reservoir Sedimentation in Eastern USA

    NASA Astrophysics Data System (ADS)

    Ahamed, A.; Snyder, N. P.; David, G. C.

    2014-12-01

    The Reservoir Sedimentation Database (ResSed), a catalogue of reservoirs and depositional data that has recently become publically available, allows for rapid calculation of sedimentation rates and rates of capacity loss over short (annual to decadal) timescales. This study is a statistical investigation of factors controlling watershed average erosion rates (E) in eastern United States watersheds. We develop an ArcGIS-based model that delineates watersheds upstream of ResSed dams and calculate drainage areas to determine E for 191 eastern US watersheds. Geomorphic, geologic, regional, climatic, and land use variables are quantified within study watersheds using GIS. Erosion rates exhibit a large amount of scatter, ranging from 0.001 to 1.25 mm/yr. A weak inverse power law relationship between drainage area (A) and E (R2 = 0.09) is evident, similar to other studies (e.g. Milliman and Syvitski, 1992; Koppes and Montgomery, 2009). Linear regressions reveal no relationship between mean watershed slope (S) and E, possibly due to the relatively low relief of the region (mean S for all watersheds is 6°). Analysis of Variance shows that watersheds in formerly glaciated regions exhibit a statistically significant lower mean E (0.06 mm/year) than watersheds in unglaciated regions (0.12 mm/year), but that watersheds with different dam purposes show no significant differences in mean E. Linear regressions reveal no relationships between E and land use parameters like percent agricultural land and percent impervious surfaces (I), but classification and regression trees indicate that watersheds in highly developed regions (I > 34%) exhibit mean E (0.36 mm/year) that is four times higher than watersheds in less developed (I < 34%) regions (0.09 mm/year). Further, interactions between land use variables emerge in formerly glaciated regions, where increased agricultural land results in higher rates of annual capacity loss in reservoirs (R2 = 0.56). Plots of E versus timescale of

  15. Mapping {sup 15}O Production Rate for Proton Therapy Verification

    SciTech Connect

    Grogg, Kira; Alpert, Nathaniel M.; Zhu, Xuping; Min, Chul Hee; Testa, Mauro; Winey, Brian; Normandin, Marc D.; Shih, Helen A.; Paganetti, Harald; Bortfeld, Thomas; El Fakhri, Georges

    2015-06-01

    Purpose: This work was a proof-of-principle study for the evaluation of oxygen-15 ({sup 15}O) production as an imaging target through the use of positron emission tomography (PET), to improve verification of proton treatment plans and to study the effects of perfusion. Methods and Materials: Dynamic PET measurements of irradiation-produced isotopes were made for a phantom and rabbit thigh muscles. The rabbit muscle was irradiated and imaged under both live and dead conditions. A differential equation was fitted to phantom and in vivo data, yielding estimates of {sup 15}O production and clearance rates, which were compared to live versus dead rates for the rabbit and to Monte Carlo predictions. Results: PET clearance rates agreed with decay constants of the dominant radionuclide species in 3 different phantom materials. In 2 oxygen-rich materials, the ratio of {sup 15}O production rates agreed with the expected ratio. In the dead rabbit thighs, the dynamic PET concentration histories were accurately described using {sup 15}O decay constant, whereas the live thigh activity decayed faster. Most importantly, the {sup 15}O production rates agreed within 2% (P>.5) between conditions. Conclusions: We developed a new method for quantitative measurement of {sup 15}O production and clearance rates in the period immediately following proton therapy. Measurements in the phantom and rabbits were well described in terms of {sup 15}O production and clearance rates, plus a correction for other isotopes. These proof-of-principle results support the feasibility of detailed verification of proton therapy treatment delivery. In addition, {sup 15}O clearance rates may be useful in monitoring permeability changes due to therapy.

  16. GROUND WATER ISSUE - CALCULATION AND USE OF FIRST-ORDER RATE CONSTANTS FOR MONITORED NATURAL ATTENUATION STUDIES

    EPA Science Inventory

    This issue paper explains when and how to apply first-order attenuation rate constant calculations in monitored natural attenuation (MNA) studies. First-order attenuation rate constant calculations can be an important tool for evaluating natural attenuation processes at ground-wa...

  17. Computer Program for the Calculation of Multicomponent Convective Diffusion Deposition Rates from Chemically Frozen Boundary Layer Theory

    NASA Technical Reports Server (NTRS)

    Gokoglu, S. A.; Chen, B. K.; Rosner, D. E.

    1984-01-01

    The computer program based on multicomponent chemically frozen boundary layer (CFBL) theory for calculating vapor and/or small particle deposition rates is documented. A specific application to perimter-averaged Na2SO4 deposition rate calculations on a cylindrical collector is demonstrated. The manual includes a typical program input and output for users.

  18. Voxel modeling of rabbits for use in radiological dose rate calculations.

    PubMed

    Caffrey, E A; Johansen, M P; Higley, K A

    2016-01-01

    Radiation dose to biota is generally calculated using Monte Carlo simulations of whole body ellipsoids with homogeneously distributed radioactivity throughout. More complex anatomical phantoms, termed voxel phantoms, have been developed to test the validity of these simplistic geometric models. In most voxel models created to date, human tissue composition and density values have been used in lieu of biologically accurate values for non-human biota. This has raised questions regarding variable tissue composition and density effects on the fraction of radioactive emission energy absorbed within tissues (e.g. the absorbed fraction - AF), along with implications for age-dependent dose rates as organisms mature. The results of this study on rabbits indicates that the variation in composition between two mammalian tissue types (e.g. human vs rabbit bones) made little difference in self-AF (SAF) values (within 5% over most energy ranges). However, variable tissue density (e.g. bone vs liver) can significantly impact SAF values. An examination of differences across life-stages revealed increasing SAF with testis and ovary size of over an order of magnitude for photons and several factors for electrons, indicating the potential for increasing dose rates to these sensitive organs as animals mature. AFs for electron energies of 0.1, 0.2, 0.4, 0.5, 0.7, 1.0, 1.5, 2.0, and 4.0 MeV and photon energies of 0.01, 0.015, 0.02, 0.03, 0.05, 0.1, 0.2, 0.5, 1.0, 1.5, 2.0, and 4.0 MeV are provided for eleven rabbit tissues. The data presented in this study can be used to calculate accurate organ dose rates for rabbits and other small rodents; to aide in extending dose results among different mammal species; and to validate the use of ellipsoidal models for regulatory purposes.

  19. Dose Rate Calculations of Spent MTR-HEU Fuel Elements of the IAN-R1 Research Reactor

    NASA Astrophysics Data System (ADS)

    Sarta Fuentes, Jose Antonio

    2005-04-01

    With cooperation of the International Atomic Energy Agency (IAEA) and the Department of Energy (DOE) of the United States, several tasks related to the waste disposal of spent MTR fuel enriched nominally to 93% were carried out for the conversion of the IAN-R1 Research Reactor from MTR-HEU fuel to TRIGA-LEU fuel. In order to remove the spent MTR-HEU fuel of the core and store it safetly, a program was established at the Instituto de Ciencias Nucleares y Energìas Alternativas (INEA). This program included training, acquisition of hardware and sofware, design and construction of a decay pool, transfer of the spent HEU fuel elements into the decay pool and his final transport to Savanah River in United States. In this paper are presented external dose rates which were calculated for a standard spent MTR-HEU fuel element of the IAN-R1 Research Reactor. The calculations take in consideration the activity due to contributions of fission, activation and actinides products for each relevant radionuclide present in a standard spent MTR-HEU fuel. The datas obtained were the base for the respective dosimetric evaluations in the transfering operations of fuel elements into the decay pool and for shielding calculations in designing of the decay pool.

  20. Estimating the impact of high-production-volume chemicals on remote ecosystems by toxic pressure calculation.

    PubMed

    Harbers, Jasper V; Huijbregts, Mark A J; Posthuma, Leo; Van de Meent, Dik

    2006-03-01

    Although many chemicals are in use, the environmental impacts of only a few have been established, usually on per-chemical basis. Uncertainty remains about the overall impact of chemicals. This paper estimates combined toxic pressure on coastal North Sea ecosystems from 343 high-production-volume chemicals used within the catchment of rivers Rhine, Meuse, and Scheldt. Multimedia fate modeling and species sensitivity distribution-based effects estimation are applied. Calculations start from production volumes and emission rates and use physicochemical substance properties and aquatic ecotoxicity data. Parameter uncertainty is addressed by Monte Carlo simulations. Results suggest that the procedure is technically feasible. Combined toxic pressure of all 343 chemicals in coastal North Seawater is 0.025 (2.5% of the species are exposed to concentration levels above EC50 values), with a wide confidence interval of nearly 0-1. This uncertainty appears to be largely due to uncertainties in interspecies variances of aquatic toxicities and, to a lesser extent, to uncertainties in emissions and degradation rates. Due to these uncertainties, the results support gross ranking of chemicals in categories: negligible and possibly relevant contributions only. With 95% confidence, 283 of the 343 chemicals (83%) contribute negligibly (less than 0.1%) to overall toxic pressure, and only 60 (17%) need further consideration.

  1. 37 CFR 1.779 - Calculation of patent term extension for a veterinary biological product.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... extension for a veterinary biological product. 1.779 Section 1.779 Patents, Trademarks, and Copyrights... Calculation of patent term extension for a veterinary biological product. (a) If a determination is made pursuant to § 1.750 that a patent for a veterinary biological product is eligible for extension, the...

  2. A precise calculation of delayed coincidence selection efficiency and accidental coincidence rate

    NASA Astrophysics Data System (ADS)

    Yu, Jing-Yi; Wang, Zhe; Chen, Shao-Min

    2015-05-01

    A precise background evaluation model is proposed to address the complex data structure of the delayed coincidence method, which is widely used in reactor electron-antineutrino oscillation experiments. In this model, effects from the muon veto, uncorrelated random background, and background are all studied analytically, simplifying the estimation of the systematic uncertainties of signal efficiency and accidental background rate. The results of the calculations are validated numerically with a number of simulation studies and also applied and validated in the recent Daya Bay hydrogen-capture based oscillation measurement. Supported by Ministry of Science and Technology of China (2013CB834302), National Natural Science Foundation of China (11235006, 11475093), Tsinghua University Initiative Scientific Research Program (2012Z02161), and Key Laboratory of Particle & Radiation Imaging (Tsinghua University), Ministry of Education.

  3. Helium release rates and ODH calculations from RHIC magnet cooling line failure

    SciTech Connect

    Liaw, C.J.; Than, Y.; Tuozzolo, J.

    2011-03-28

    A catastrophic failure of the magnet cooling lines, similar to the LHC superconducting bus failure incident, could discharge cold helium into the RHIC tunnel and cause an Oxygen Deficiency Hazard (ODH) problem. A SINDA/FLUINT{reg_sign} model, which simulated the 4.5K/4 atm helium flowing through the magnet cooling system distribution lines, then through a line break into the insulating vacuum volumes and discharging via the reliefs into the RHIC tunnel, had been developed. Arc flash energy deposition and heat load from the ambient temperature cryostat surfaces are included in the simulations. Three typical areas: the sextant arc, the Triplet/DX/D0 magnets, and the injection area, had been analyzed. Results, including helium discharge rates, helium inventory loss, and the resulting oxygen concentration in the RHIC tunnel area, are reported. Good agreement had been achieved when comparing the simulation results, a RHIC sector depressurization test measurement, and some simple analytical calculations.

  4. Enhanced sophorolipid production by feeding-rate-controlled fed-batch culture.

    PubMed

    Kim, Young-Bum; Yun, Hyun Shik; Kim, Eun-Ki

    2009-12-01

    To develop the easier control method for fed-batch culture of sophorolipid production, we chose rapeseed oil as the most productive oil and compared their productivities in relation to different concentrations of glucose. The optimal concentration of glucose was 30 g/L for sophorolipid production. A fed-batch method was conducted using Candida bombicola ATCC 22214 with rapeseed oil as a secondary substrate. The feeding rate of rapeseed oil was dependent on pH and was calculated by the consumption rate of NaOH and rapeseed oil. The glucose concentration was constantly maintained between 30 and 40 g/L. As a result, we have produced a crude sophorolipid up to 365 g/L for 8 days through a feeding-rate-controlled fed-batch process.

  5. Change of Electroweak Nuclear Reaction Rates by CP- and Isospin Symmetry Breaking - A Model Calculation

    NASA Astrophysics Data System (ADS)

    Stumpf, Harald

    2006-09-01

    Based on the assumption that electroweak bosons, leptons and quarks possess a substructure of elementary fermionic constituents, in previous papers the effect of CP-symmetry breaking on the effective dynamics of these particles was calculated. Motivated by the phenomenological procedure in this paper, isospin symmetry breaking will be added and the physical consequences of these calculations will be discussed. The dynamical law of the fermionic constituents is given by a relativistically invariant nonlinear spinor field equation with local interaction, canonical quantization, selfregularization and probability interpretation. The corresponding effective dynamics is derived by algebraic weak mapping theorems. In contrast to the commonly applied modifications of the quark mass matrices, CP-symmetry breaking is introduced into this algebraic formalism by an inequivalent vacuum with respect to the CP-invariant case, represented by a modified spinor field propagator. This leads to an extension of the standard model as effective theory which contains besides the "electric" electroweak bosons additional "magnetic" electroweak bosons and corresponding interactions. If furthermore the isospin invariance of the propagator is broken too, it will be demonstrated in detail that in combination with CP-symmetry breaking this induces a considerable modification of electroweak nuclear reaction rates.

  6. Modeling Atmospheric Emissions and Calculating Mortality Rates Associated with High Volume Hydraulic Fracturing Transportation

    NASA Astrophysics Data System (ADS)

    Mathews, Alyssa

    Emissions from the combustion of fossil fuels are a growing pollution concern throughout the global community, as they have been linked to numerous health issues. The freight transportation sector is a large source of these emissions and is expected to continue growing as globalization persists. Within the US, the expanding development of the natural gas industry is helping to support many industries and leading to increased transportation. The process of High Volume Hydraulic Fracturing (HVHF) is one of the newer advanced extraction techniques that is increasing natural gas and oil reserves dramatically within the US, however the technique is very resource intensive. HVHF requires large volumes of water and sand per well, which is primarily transported by trucks in rural areas. Trucks are also used to transport waste away from HVHF well sites. This study focused on the emissions generated from the transportation of HVHF materials to remote well sites, dispersion, and subsequent health impacts. The Geospatial Intermodal Freight Transport (GIFT) model was used in this analysis within ArcGIS to identify roadways with high volume traffic and emissions. High traffic road segments were used as emissions sources to determine the atmospheric dispersion of particulate matter using AERMOD, an EPA model that calculates geographic dispersion and concentrations of pollutants. Output from AERMOD was overlaid with census data to determine which communities may be impacted by increased emissions from HVHF transport. The anticipated number of mortalities within the impacted communities was calculated, and mortality rates from these additional emissions were computed to be 1 in 10 million people for a simulated truck fleet meeting stricter 2007 emission standards, representing a best case scenario. Mortality rates due to increased truck emissions from average, in-use vehicles, which represent a mixed age truck fleet, are expected to be higher (1 death per 341,000 people annually).

  7. Line-by-line calculations of atmospheric fluxes and cooling rates: Application to water vapor

    SciTech Connect

    Clough, S.A.; Iacono, M.J.; Moncet, J.L.

    1992-10-20

    A model for the accelerated calculation of clear sky fluxes based on the line-by-line radiance model FASCODE has been developed and applied to the calculation of cooling rates for atmospheric water vapor. The model achieves computational accuracies for the longwave upwelling and downwelling fluxes of the order of 0.2%, an accuracy well within current limitations imposed by uncertainties in the spectral parameters, the line shape, and the associated continua. For the same treatment of line shape, the Voigt profile with a 10 cm{sup {minus}1} cutoff and no continuum, the results from the present model are in acceptable agreement with those from two other line-by-line models reported as part of the intercomparison of radiation codes used in climate models (ICRCCM). For this line profile and the mid-latitude summer atmosphere, the largest difference between the results from the authors model and the Goddard Laboratory for Atmospheres (GLA) model occurs for the downwelling flux at the surface, with the present model providing a value greater than that from GLA. The differences are generally consistent with greater atmospheric opacity from the present model, attributable to the inclusion of a self-broadening component for the half width for water and to finer spectral sampling in the lower-pressure regime. In the spectral domain there exists a mapping between the altitude and the molecular absorption strength as weighted by the Planck function. The extremely high correlation between the outgoing spectral radiance at the top of the atmosphere and the spectral cooling rate profile suggests that the measurement of the outgoing spectral radiance can provide important information about atmospheric state that is not available from spectrally integrated quantities. These results also indicate the critical importance of the spectral region from 100 to 600 cm{sup {minus}1} for the radiative transfer associated with atmospheric water vapor. 30 refs., 28 figs., 5 tabs.

  8. [Calculating method for the necessary lamps and sterile rate in a tube-shaped ultraviolet air washer].

    PubMed

    Xu, Z; Chen, C; Shen, J

    1998-05-01

    It has much more advantage to use the cylindric ultraviolet air washer than to use the ordinary ultraviolet lamps. There was a calculation method for determining necessary lamps in a rectangled ultraviolet air washer, but it had a limiting condition. This paper developed two calculating methods for determining necessary lamps and its sterile rate in a tube-shaped ultraviolet air washer. The sterile rate can be extracted with any parameter. Necessary lamps can also be extracted with its sterile rate.

  9. STEADY-STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE

    SciTech Connect

    HU TA

    2007-10-26

    Assess the steady-state flammability level at normal and off-normal ventilation conditions. The methodology of flammability analysis for Hanford tank waste is developed. The hydrogen generation rate model was applied to calculate the gas generation rate for 177 tanks. Flammability concentrations and the time to reach 25% and 100% of the lower flammability limit, and the minimum ventilation rate to keep from 100 of the LFL are calculated for 177 tanks at various scenarios.

  10. Refinement of the Air Force Systems Command Production Rate Model

    DTIC Science & Technology

    1989-09-01

    the recommended modified formulations. The relationship between production rate and production ratio has a definite influence on the model’s ability to...1984 7 36 21.954 370.00 1985 8 48 21.017 412.00 A- 3 Table A.2.8 F-15E Cost/Quantity Data Fiscal Year Lot Quntit Recurring Unit Cost LPP 1986 1 60

  11. 39 CFR 3010.23 - Calculation of percentage change in rates.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ..., 2, ..., N) Ri,n = planned rate of rate cell i Ri,c = current rate of rate cell i Vi = volume of rate...) The term rate cell as applied in the test for compliance with the annual limitation shall apply to... rate cells separate and distinct from the corresponding non-seasonal or permanent rates. (b) For...

  12. 39 CFR 3010.23 - Calculation of percentage change in rates.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... rate cell i Vi = volume of rate cell i (d) The volumes for each rate cell shall be obtained from the... adjustment for rate cell i (for a Type 1-C rate adjustment) Vi = volume of rate cell i (d) Volumes—(1... term rate cell means each and every separate rate identified in any applicable notice of...

  13. 39 CFR 3010.23 - Calculation of percentage change in rates.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ..., 2, ..., N) Ri,n = planned rate of rate cell i Ri,c = current rate of rate cell i Vi = volume of rate...) The term rate cell as applied in the test for compliance with the annual limitation shall apply to... rate cells separate and distinct from the corresponding non-seasonal or permanent rates. (b) For...

  14. 39 CFR 3010.23 - Calculation of percentage change in rates.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ..., 2, ..., N) Ri,n = planned rate of rate cell i Ri,c = current rate of rate cell i Vi = volume of rate...) The term rate cell as applied in the test for compliance with the annual limitation shall apply to... rate cells separate and distinct from the corresponding non-seasonal or permanent rates. (b) For...

  15. 39 CFR 3010.23 - Calculation of percentage change in rates.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., 2, ..., N) Ri,n = planned rate of rate cell i Ri,c = current rate of rate cell i Vi = volume of rate...) The term rate cell as applied in the test for compliance with the annual limitation shall apply to... rate cells separate and distinct from the corresponding non-seasonal or permanent rates. (b) For...

  16. STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE

    SciTech Connect

    MEACHAM JE

    2008-11-17

    This report assesses the steady state flammability level under off normal ventilation conditions in the tank headspace for 28 double-shell tanks (DST) and 149 single shell-tanks (SST) at the Hanford Site. Flammability was calculated using estimated gas release rates, Le Chatelier's rule, and lower flammability limits of fuels in an air mixture. This revision updates the hydrogen generation rate input data for al1 177 tanks using waste composition information from the Best Basis Inventory Detail Report (data effective as of August 4,2008). Assuming only barometric breathing, the shortest time to reach 25% of the lower flammability limit is 13 days for DSTs (i.e., tank 241-AZ-102) and 36 days for SSTs (i.e., tank 241-B-203). Assuming zero ventilation, the shortest time to reach 25% of the lower flammability limit is 12 days for DSTs (i.e., tank 241-AZ-102) and 34 days for SSTs (i.e., tank 241-B-203).

  17. STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE

    SciTech Connect

    MEACHAM JE

    2009-10-26

    This report assesses the steady state flammability level under off normal ventilation conditions in the tank headspace for 28 double-shell tanks (DST) and 149 single shell-tanks (SST) at the Hanford Site. Flammability was calculated using estimated gas release rates, Le Chatelier's rule, and lower flammability limits of fuels in an air mixture. This revision updates the hydrogen generation rate input data for all 177 tanks using waste composition information from the Best Basis Inventory Detail Report (data effective as of August 4,2008). Assuming only barometric breathing, the shortest time to reach 25% of the lower flammability limit is 11 days for DSTs (i.e., tank 241-AZ-10l) and 36 days for SSTs (i.e., tank 241-B-203). Assuming zero ventilation, the shortest time to reach 25% of the lower flammability limit is 10 days for DSTs (i.e., tank 241-AZ-101) and 34 days for SSTs (i.e., tank 241-B-203).

  18. Limitations of the TG-43 formalism for skin high-dose-rate brachytherapy dose calculations

    SciTech Connect

    Granero, Domingo; Perez-Calatayud, Jose; Vijande, Javier; Ballester, Facundo; Rivard, Mark J.

    2014-02-15

    Purpose: In skin high-dose-rate (HDR) brachytherapy, sources are located outside, in contact with, or implanted at some depth below the skin surface. Most treatment planning systems use the TG-43 formalism, which is based on single-source dose superposition within an infinite water medium without accounting for the true geometry in which conditions for scattered radiation are altered by the presence of air. The purpose of this study is to evaluate the dosimetric limitations of the TG-43 formalism in HDR skin brachytherapy and the potential clinical impact. Methods: Dose rate distributions of typical configurations used in skin brachytherapy were obtained: a 5 cm × 5 cm superficial mould; a source inside a catheter located at the skin surface with and without backscatter bolus; and a typical interstitial implant consisting of an HDR source in a catheter located at a depth of 0.5 cm. Commercially available HDR{sup 60}Co and {sup 192}Ir sources and a hypothetical {sup 169}Yb source were considered. The Geant4 Monte Carlo radiation transport code was used to estimate dose rate distributions for the configurations considered. These results were then compared to those obtained with the TG-43 dose calculation formalism. In particular, the influence of adding bolus material over the implant was studied. Results: For a 5 cm × 5 cm{sup 192}Ir superficial mould and 0.5 cm prescription depth, dose differences in comparison to the TG-43 method were about −3%. When the source was positioned at the skin surface, dose differences were smaller than −1% for {sup 60}Co and {sup 192}Ir, yet −3% for {sup 169}Yb. For the interstitial implant, dose differences at the skin surface were −7% for {sup 60}Co, −0.6% for {sup 192}Ir, and −2.5% for {sup 169}Yb. Conclusions: This study indicates the following: (i) for the superficial mould, no bolus is needed; (ii) when the source is in contact with the skin surface, no bolus is needed for either {sup 60}Co and {sup 192}Ir. For

  19. Ensemble Monte Carlo calculation of the hole initiated impact ionization rate in bulk GaAs and silicon using a k-dependent, numerical transition rate formulation

    NASA Technical Reports Server (NTRS)

    Oguzman, Ismail H.; Wang, Yang; Kolnik, Jan; Brennan, Kevin F.

    1995-01-01

    The hole initiated impact ionization rate in bulk silicon and GaAs is calculated using a numerical formulation of the impact ionization transition rate incorporated into an ensemble Monte Carlo simulation. The transition rate is calculated from Fermi's golden rule using a two-body screened Coulomb interaction including a wavevector dependent dielectric function. It is found that the effective threshold for hole initiated ionization is relatively soft in both materials, that the split-off band dominates the ionization process in GaAs. and that no clear dominance by any one band is observed in silicon, though the rate out of the light hole band is greatest.

  20. Wastewater treatment high rate algal ponds for biofuel production.

    PubMed

    Park, J B K; Craggs, R J; Shilton, A N

    2011-01-01

    While research and development of algal biofuels are currently receiving much interest and funding, they are still not commercially viable at today's fossil fuel prices. However, a niche opportunity may exist where algae are grown as a by-product of high rate algal ponds (HRAPs) operated for wastewater treatment. In addition to significantly better economics, algal biofuel production from wastewater treatment HRAPs has a much smaller environmental footprint compared to commercial algal production HRAPs which consume freshwater and fertilisers. In this paper the critical parameters that limit algal cultivation, production and harvest are reviewed and practical options that may enhance the net harvestable algal production from wastewater treatment HRAPs including CO(2) addition, species control, control of grazers and parasites and bioflocculation are discussed.

  1. RADIOLYTIC GAS PRODUCTION RATES OF POLYMERS EXPOSED TO TRITIUM GAS

    SciTech Connect

    Clark, E.

    2013-08-31

    Data from previous reports on studies of polymers exposed to tritium gas is further analyzed to estimate rates of radiolytic gas production. Also, graphs of gas release during tritium exposure from ultrahigh molecular weight polyethylene (UHMW-PE), polytetrafluoroethylene (PTFE, a trade name is Teflon®), and Vespel® polyimide are re-plotted as moles of gas as a function of time, which is consistent with a later study of tritium effects on various formulations of the elastomer ethylene-propylene-diene monomer (EPDM). These gas production rate estimates may be useful while considering using these polymers in tritium processing systems. These rates are valid at least for the longest exposure times for each material, two years for UHMW-PE, PTFE, and Vespel®, and fourteen months for filled and unfilled EPDM. Note that the production “rate” for Vespel® is a quantity of H{sub 2} produced during a single exposure to tritium, independent of length of time. The larger production rate per unit mass for unfilled EPDM results from the lack of filler- the carbon black in filled EPDM does not produce H{sub 2} or HT. This is one aspect of how inert fillers reduce the effects of ionizing radiation on polymers.

  2. Proceedings of a Workshop on Cosmogenic Nuclide Production Rates

    NASA Technical Reports Server (NTRS)

    Englert, Peter A. J. (Editor); Reedy, Robert C. (Editor); Michel, Rolf (Editor)

    1989-01-01

    Abstracts of reports from the proceedings are presented. The presentations were divided into discussion topics. The following general topic areas were used: (1) measured cosmogenic noble gas and radionuclide production rates in meteorite and planetary surface samples; (2) cross-section measurements and simulation experiments; and (3) interpretation of sample studies and simulation experiments.

  3. Calculation of gamma radiation dose rate and radon concentration due to granites used as building materials in Iran.

    PubMed

    Abbasi, A

    2013-07-01

    Natural radioactivity concentrations in granite building materials that are commonly used in Iran have been surveyed by using a gamma-ray spectrometry system, using a high-purity germanium detector. Health hazards from gamma radiation doses due to granite and radon concentration have been calculated. The dose rate of exposure from granite building materials on humans is obtained as a result of an external exposure from gamma-emitting radionuclides in the granites. Another mode of exposure is from the inhalation of the decay products of (222)Ra and (220)Ra. The average concentrations of (232)Th, (226)Ra and (40)K were in the ranges of 6.5-172.2, 3.8-94.2 and 556.9-1539.2 Bq kg(-1), respectively. The radon exhalation rates have also been studied and values were in the range of 0.32 ± 0.01 to 7.86 ± 1.65 Bq m(-2) h(-1). For two models of standard living rooms (5.0 m × 4.0 m area; 2.8 m), the radon concentration (Ci) and the absorbed dose (D) rates were calculated and the results were found to be 10.64-29.32 Bq m(-3), 3.84-68.02 nGy h(-1) and 0.02-0.33 mSv y(-1) for Model 1, 10.07-15.38 Bq m(-3) and 2.29-39.99 nGy h(-1) for Model 2, respectively. According to our estimations, mechanical ventilation systems (λν = 0.5 h(-1)) in a room all granite samples would produce radon concentration <100 Bq m(-3).

  4. Drill-in fluid reduces formation damage, increases production rates

    SciTech Connect

    Hands, N.; Kowbel, K.; Nouris, R.

    1998-07-13

    A sodium formate drill-in fluid system reduced formation damage, resulting in better-than-expected production rates for an off-shore Dutch development well. Programmed to optimize production capacity and reservoir drainage from a Rotliegend sandstone gas discovery, the 5-7/8-in. subhorizontal production interval was drilled and completed barefoot with a unique, rheologically engineered sodium formate drill-in fluid system. The new system, consisting of a sodium formate (NaCOOH) brine as the base fluid and properly sized calcium carbonate as the formation-bridging agent, was selected on the basis of its well-documented record in reducing solids impairment and formation damage in similar sandstone structures in Germany. The system was engineered around the low-shear-rate viscosity (LSRV) concept, designed to provide exceptional rheological properties. After describing the drilling program, the paper gives results on the drilling and completion.

  5. Model for GCR-particle fluxes in stony meteorites and production rates of cosmogenic nuclides

    SciTech Connect

    Reedy, R.C.

    1984-01-01

    A model is presented for the differential fluxes of galactic-cosmic-ray (GCR) particles with energies above 1 MeV inside any spherical stony meteorite as a function of the meteorite's radius and the sample's depth. This model is based on the Reedy-Arnold equations for the energy-dependent fluxes of GCR particles in the moon and is an extension of flux parameters that were derived for several meteorites of various sizes. This flux is used to calculate the production rates of many cosmogenic nuclides as a function of radius and depth. The peak production rates for most nuclides made by the reactions of energetic GCR particles occur near the centers of meteorites with radii of 40 to 70 g cm/sup -2/. Although the model has some limitations, it reproduces well the basic trends for the depth-dependent production of cosmogenic nuclides in stony meteorites of various radii. These production profiles agree fairly well with measurements of cosmogenic nuclides in meteorites. Some of these production profiles are different than those calculated by others. The chemical dependence of the production rates for several nuclides varies with size and depth. 25 references, 8 figures.

  6. THE PRODUCTION RATE OF SN Ia EVENTS IN GLOBULAR CLUSTERS

    SciTech Connect

    Washabaugh, Pearce C.; Bregman, Joel N. E-mail: jbregman@umich.edu

    2013-01-01

    In globular clusters, dynamical evolution produces luminous X-ray emitting binaries at a rate about 200 times greater than in the field. If globular clusters also produce SN Ia at a high rate, it would account for many of the SN Ia production in early-type galaxies and provide insight into their formation. Here we use archival Hubble Space Telescope (HST) images of nearby galaxies that have hosted an SN Ia to examine the rate at which globular clusters produce these events. The location of the SN Ia is registered on an HST image obtained before the event or after the supernova (SN) faded. Of the 36 nearby galaxies examined, 21 had sufficiently good data to search for globular cluster hosts. None of the 21 SNe have a definite globular cluster counterpart, although there are some ambiguous cases. This places an upper limit to the enhancement rate of SN Ia production in globular clusters of about 42 at the 95% confidence level, which is an order of magnitude lower than the enhancement rate for luminous X-ray binaries. Even if all of the ambiguous cases are considered as having a globular cluster counterpart, the upper bound for the enhancement rate is 82 at the 95% confidence level, still a factor of several below that needed to account for half of the SN Ia events. Barring unforeseen selection effects, we conclude that globular clusters are not responsible for producing a significant fraction of the SN Ia events in early-type galaxies.

  7. MEASURED AND CALCULATED HEATING AND DOSE RATES FOR THE HFIR HB4 BEAM TUBE AND COLD SOURCE

    SciTech Connect

    Slater, Charles O; Primm, Trent; Pinkston, Daniel; Cook, David Howard; Selby, Douglas L; Ferguson, Phillip D; Bucholz, James A; Popov, Emilian L

    2009-03-01

    The High Flux Isotope Reactor at the Oak Ridge National Laboratory was upgraded to install a cold source in horizontal beam tube number 4. Calculations were performed and measurements were made to determine heating within the cold source and dose rates within and outside a shield tunnel surrounding the beam tube. This report briefly describes the calculations and presents comparisons of the measured and calculated results. Some calculated dose rates are in fair to good agreement with the measured results while others, particularly those at the shield interfaces, differ greatly from the measured results. Calculated neutron exposure to the Teflon seals in the hydrogen transfer line is about one fourth of the measured value, underpredicting the lifetime by a factor of four. The calculated cold source heating is in good agreement with the measured heating.

  8. 5 CFR 532.253 - Special rates or rate ranges for leader, supervisory, and production facilitating positions.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Special rates or rate ranges for leader....253 Special rates or rate ranges for leader, supervisory, and production facilitating positions. (a... shall establish special rates for leader, supervisory, and production facilitating positions,...

  9. Automated Production of High Rep Rate Foam Targets

    NASA Astrophysics Data System (ADS)

    Hall, F.; Spindloe, C.; Haddock, D.; Tolley, M.; Nazarov, W.

    2016-04-01

    Manufacturing low density targets in the numbers needed for high rep rate experiments is highly challenging. This report summarises advances from manual production to semiautomated and the improvements that follow both in terms of production time and target uniformity. The production process is described and shown to be improved by the integration of an xyz robot with dispensing capabilities. Results are obtained from manual and semiautomated production runs and compared. The variance in the foam thickness is reduced significantly which should decrease experimental variation due to target parameters and could allow for whole batches to be characterised by the measurement of a few samples. The work applies to both foil backed and free standing foam targets.

  10. A comparison of the indirect estimate of mean arterial pressure calculated by the conventional equation and calculated to compensate for a change in heart rate.

    PubMed

    Rogers, G; Oosthuyse, T

    2000-02-01

    The standard equation used to calculate mean arterial pressure (MAP) assumes that diastole persists for 2/3 and systole for 1/3 of each cardiac cycle. This ratio is altered when heart rate increases, and therefore we investigated the efficacy of predicting MAP during exercise using non-invasive indirect methods. Eight subjects exercised on a cycle ergometer for 3 minute intervals to elicit heart rates between 100-110, 120-130, 140-150, 160-170, and 180-190 beats/min. In the last minute of each 3 min interval an ECG recording was taken and systolic (SP) and diastolic (DP) blood pressure was measured by manual auscultation. MAP was calculated for each heart rate interval by: MAP=DP+1/3(SP-DP) (method A), and MAP= DP + Fs(SP- DP) (method B), where Fs is the fraction of the cardiac cycle comprising systole, measured from the ECG. Fs increased from 0.35+/-0.049 at rest to 0.47+/-0.039 at a heart rate of 180-190 beats/min. MAP measured by method B was consistently greater than MAP calculated by method A at all heart rates greater than resting heart rate (p<0.01). The error incurred when using the standard MAP equation (method A) to derive MAP during exercise (measured as the percentage difference between method A and B) increased linearly with heart rate (r=0.98). The standard MAP equation should not be applied during exercise, as it does not account for the change in the systolic: diastolic period ratio as heart rate increases.

  11. 75 FR 81533 - Antidumping Proceedings: Calculation of the Weighted Average Dumping Margin and Assessment Rate...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-28

    ... International Trade Administration 19 CFR Part 351 RIN 0625-AA87 Antidumping Proceedings: Calculation of the... comments regarding the calculation of the weighted average dumping margin and antidumping duty assessment... providing offsets for non-dumped comparisons. Antidumping Proceedings: Calculation of the...

  12. Calculation of Heavy Ion Inactivation and Mutation Rates in Radial Dose Model of Track Structure

    NASA Technical Reports Server (NTRS)

    Cucinotta, Francis A.; Wilson, John W.; Shavers, Mark R.; Katz, Robert

    1997-01-01

    In the track structure model, the inactivation cross section is found by summing an inactivation probability over all impact parameters from the ion to the sensitive sites within the cell nucleus. The inactivation probability is evaluated by using the dose response of the system to gamma rays and the radial dose of the ions and may be equal to unity at small impact parameters. We apply the track structure model to recent data with heavy ion beams irradiating biological samples of E. Coli, B. Subtilis spores, and Chinese hamster (V79) cells. Heavy ions have observed cross sections for inactivation that approach and sometimes exceed the geometric size of the cell nucleus. We show how the effects of inactivation may be taken into account in the evaluation of the mutation cross sections in the track structure model through correlation of sites for gene mutation and cell inactivation. The model is fit to available data for HPRT (hypoxanthine guanine phosphoribosyl transferase) mutations in V79 cells, and good agreement is found. Calculations show the high probability for mutation by relativistic ions due to the radial extension of ions track from delta rays. The effects of inactivation on mutation rates make it very unlikely that a single parameter such as LET (linear energy transfer) can be used to specify radiation quality for heavy ion bombardment.

  13. Configuration interaction calculations of potential curves and annihilation rates for positronic complexes of alkali monoxides.

    PubMed

    Buenker, Robert J; Liebermann, Heinz-Peter

    2009-09-21

    Ab initio multireference single- and double-excitation configuration interaction calculations have been carried out to compute the potential curves and annihilation rates (ARs) of positronic molecular complexes of a series of alkali monoxides. The dissociation limit for the lowest states of these systems consists of the positive alkali ion ground state (M(+)) and the OPs (e(+)O(-)) complex formed by attaching the positron to O(-), even though the ground state of the corresponding neutral molecule always correlates with uncharged fragments (M+O). The positron affinity of the neutral oxide (2)Pi state is greater than that of (2)Sigma(+) in each case, so that the e(+)MO ground state always has (3,1)Pi symmetry, despite the fact that both KO and RbO have (2)Sigma(+) ground states. The bonding in the positronic systems is highly ionic at all internuclear distances and this causes their ARs to decrease gradually as the positive alkali ion approaches the OPs fragment.

  14. Developing ratings for food products: lessons learned from media rating systems.

    PubMed

    Kunkel, Dale; McKinley, Christopher

    2007-01-01

    Children regularly consume low-nutrient, high-calorie food that is not consistent with a healthful diet, contributing to an increasing epidemic of overweight and obesity. Among the multiple causes of this problem is the food industry's emphasis on marketing calorie-dense food products to children. The Institute of Medicine (IOM) has recommended that industry adopt a uniform system of simplified food ratings to convey the nutritional qualities of food in a manner that is understandable and appealing to children and youth. This report analyzes the need for such a system in a food marketing environment that increasingly identifies healthful products for the consumer in inconsistent fashion. It considers evidence regarding current usage of food labeling and draws parallels with media rating systems in discussing the prospects for a uniform food rating system that would accomplish the IOM's objective.

  15. Light dose versus rate of delivery: implications for macroalgal productivity.

    PubMed

    Desmond, Matthew J; Pritchard, Daniel W; Hepburn, Christopher D

    2017-04-07

    The role of how light is delivered over time is an area of macroalgal photosynthesis that has been overlooked but may play a significant role in controlling rates of productivity and the structure and persistence of communities. Here we present data that quantify the relative influence of total quantum dose and delivery rate on the photosynthetic productivity of five ecologically important Phaeophyceae species from southern New Zealand. Results suggested that greater net oxygen production occurs when light is delivered at a lower photon flux density (PFD) over a longer period compared to a greater PFD over a shorter period, given the same total dose. This was due to greater efficiency (α) at a lower PFD which, for some species, meant a compensatory effect can occur. This resulted in equal or greater productivity even when the total quantum dose of the lower PFD was significantly reduced. It was also shown that light limitation at Huriawa Peninsula, where macroaglae were sourced, may be restricting the acclimation potential of species at greater depths, and that even at shallow depth periods of significant light limitation are likely to occur. This research is of particular interest as the variability of light delivery to coastal reef systems increases as a result of anthropogenic disturbances, and as the value of in situ community primary productivity estimates is recognised.

  16. Neutron capture production rates of cosmogenic 60Co, 59Ni and 36Cl in stony meteorites

    NASA Technical Reports Server (NTRS)

    Spergel, M. S.; Reedy, R. C.; Lazareth, O. W.; Levy, P. W.

    1986-01-01

    Results for neutron flux calculations in stony meteoroids (of various radii and compositions) and production rates for Cl-36, Ni-59, and Co-60 are reported. The Ni-59/Co-60 ratio is nearly constant with depth in most meteorites: this effect is consistent with the neutron flux and capture cross section properties. The shape of the neutron flux energy spectrum, varies little with depth in a meteorite. The size of the parent meteorite can be determined from one of its fragments, using the Ni-59/Co-60 ratios, if the parent meteorite was less than 75 g/cm(2) in radius. If the parent meteorite was larger, a lower limit on the size of the parent meteorite can be determined from a fragment. In C3 chondrites this is not possible. In stony meteorites with R less than 50 g/cm(2) the calculated Co-60 production rates (mass less than 4 kg), are below 1 atom/min g-Co. The highest Co-60 production rates occur in stony meteorites with radius about 250 g/cm(2) (1.4 m across). In meteorites with radii greater than 400 g/cm(2), the maximum Co-60 production rate occurs at a depth of about 175 g/cm(2) in L-chondrite, 125 g/cm(2) in C3 chrondrite, and 190 g/cm(2) in aubrites.

  17. Entropy production rate as a constraint for collisionless fluid closures

    SciTech Connect

    Fleurence, E.; Sarazin, Y.; Garbet, X.; Dif-Pradalier, G.; Ghendrih, Ph.; Grandgirard, V.; Ottaviani, M.

    2006-11-30

    A novel method is proposed to construct collisionless fluid closures accounting for some kinetic properties. The first dropped fluid moment is assumed to be a linear function of the lower order ones. Optimizing the agreement between the fluid and kinetic entropy production rates is used to constrain the coefficients of the linear development. This procedure is applied to a reduced version of the interchange instability. The closure, involving the absolute value of the wave vector, is non-local in real space. In this case, the linear instability thresholds are the same, and the linear growth rates exhibit similar characteristics. Such a method is applicable to other models and classes of instabilities.

  18. Local Entropy Production Rates in a Polymer Electrolyte Membrane Fuel Cell

    NASA Astrophysics Data System (ADS)

    Siemer, Marc; Marquardt, Tobias; Valadez Huerta, Gerardo; Kabelac, Stephan

    2017-01-01

    A modeling study on a polymer electrolyte membrane fuel cell by means of non-equilibrium thermodynamics is presented. The developed model considers a one-dimensional cell in steady-state operation. The temperature, concentration and electric potential profiles are calculated for every domain of the cell. While the gas diffusion and the catalyst layers are calculated with established classical modeling approaches, the transport processes in the membrane are calculated with the phenomenological equations as dictated by the non-equilibrium thermodynamics. This approach is especially instructive for the membrane as the coupled transport mechanisms are dominant. The needed phenomenological coefficients are approximated on the base of conventional transport coefficients. Knowing the fluxes and their intrinsic corresponding forces, the local entropy production rate is calculated. Accordingly, the different loss mechanisms can be detected and quantified, which is important for cell and stack optimization.

  19. Calculation of the Rate of M>6.5 Earthquakes for California and Adjacent Portions of Nevada and Mexico

    USGS Publications Warehouse

    Frankel, Arthur; Mueller, Charles

    2008-01-01

    One of the key issues in the development of an earthquake recurrence model for California and adjacent portions of Nevada and Mexico is the comparison of the predicted rates of earthquakes with the observed rates. Therefore, it is important to make an accurate determination of the observed rate of M>6.5 earthquakes in California and the adjacent region. We have developed a procedure to calculate observed earthquake rates from an earthquake catalog, accounting for magnitude uncertainty and magnitude rounding. We present a Bayesian method that corrects for the effect of the magnitude uncertainty in calculating the observed rates. Our recommended determination of the observed rate of M>6.5 in this region is 0.246 ? 0.085 (for two sigma) per year, although this rate is likely to be underestimated because of catalog incompleteness and this uncertainty estimate does not include all sources of uncertainty.

  20. Measurements of in situ chemical ozone (oxidant) production rates

    NASA Astrophysics Data System (ADS)

    Huang, Hao; Faloon, Kate; Najera, Juan; Bloss, William

    2013-04-01

    Tropospheric ozone is a major air pollutant, harmful to human health, agricultural crops and vegetation, the main precursor to the atmospheric oxidants which initiate the degradation of most reactive gases emitted to the atmosphere, and an important greenhouse gas in its own right. The capacity to understand and predict tropospheric ozone levels is a key goal for atmospheric science - but one which is challenging, as ozone is formed in the atmosphere from the complex oxidation of VOCs in the presence of NOx and sunlight, on a timescale such that in situ chemical processes, deposition and transport all affect ozone levels. Known uncertainties in emissions, chemistry, dynamics and deposition affect the accuracy of predictions of current and future ozone levels, and hinder development of optimal air quality policies to mitigate against ozone exposure. Recently new approaches to directly measure the local chemical ozone production rate, bypassing the many uncertainties in emissions and chemical schemes, have been developed (Cazorla & Brune, AMT 2010). Here, we describe the development of an analogous Ozone Production Rate (OPR) approach: Air is sampled into parallel reactors, within which ozone formation either occurs as in the ambient atmosphere, or is suppressed. Comparisons of ozone levels exiting a pair of such reactors determines the net chemical oxidant production rate, after correction for perturbation of the NOx-O3 photochemical steady state, and when operated under conditions such that wall effects are minimised. We report preliminary measurements of local chemical ozone production made during the UK NERC ClearfLo (Clean Air for London) campaign at an urban background location in London in January and July 2012. The OPR system was used to measure the local chemical oxidant formation rate, which is compared with observed trends in O3 and NOx and the prevailing meteorology, and with the predictions of a detailed zero-dimensional atmospheric chemistry model

  1. 42 CFR 413.220 - Methodology for calculating the per-treatment base rate under the ESRD prospective payment system...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... rate under the ESRD prospective payment system effective January 1, 2011. 413.220 Section 413.220... Disease (ESRD) Services and Organ Procurement Costs § 413.220 Methodology for calculating the per-treatment base rate under the ESRD prospective payment system effective January 1, 2011. (a) Data...

  2. 42 CFR 413.220 - Methodology for calculating the per-treatment base rate under the ESRD prospective payment system...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... rate under the ESRD prospective payment system effective January 1, 2011. 413.220 Section 413.220... Disease (ESRD) Services and Organ Procurement Costs § 413.220 Methodology for calculating the per-treatment base rate under the ESRD prospective payment system effective January 1, 2011. (a) Data...

  3. On the accuracy of instantaneous gas exchange rates, energy expenditure, and respiratory quotient calculations obtained in indirect whole room calorimeter

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This paper analyzes the accuracy of metabolic rate calculations performed in the whole room indirect calorimeter using the molar balance equations. The equations are treated from the point of view of cause-effect relationship where the gaseous exchange rates representing the unknown causes need to b...

  4. MO-D-213-07: RadShield: Semi- Automated Calculation of Air Kerma Rate and Barrier Thickness

    SciTech Connect

    DeLorenzo, M; Wu, D; Rutel, I; Yang, K

    2015-06-15

    Purpose: To develop the first Java-based semi-automated calculation program intended to aid professional radiation shielding design. Air-kerma rate and barrier thickness calculations are performed by implementing NCRP Report 147 formalism into a Graphical User Interface (GUI). The ultimate aim of this newly created software package is to reduce errors and improve radiographic and fluoroscopic room designs over manual approaches. Methods: Floor plans are first imported as images into the RadShield software program. These plans serve as templates for drawing barriers, occupied regions and x-ray tube locations. We have implemented sub-GUIs that allow the specification in regions and equipment for occupancy factors, design goals, number of patients, primary beam directions, source-to-patient distances and workload distributions. Once the user enters the above parameters, the program automatically calculates air-kerma rate at sampled points beyond all barriers. For each sample point, a corresponding minimum barrier thickness is calculated to meet the design goal. RadShield allows control over preshielding, sample point location and material types. Results: A functional GUI package was developed and tested. Examination of sample walls and source distributions yields a maximum percent difference of less than 0.1% between hand-calculated air-kerma rates and RadShield. Conclusion: The initial results demonstrated that RadShield calculates air-kerma rates and required barrier thicknesses with reliable accuracy and can be used to make radiation shielding design more efficient and accurate. This newly developed approach differs from conventional calculation methods in that it finds air-kerma rates and thickness requirements for many points outside the barriers, stores the information and selects the largest value needed to comply with NCRP Report 147 design goals. Floor plans, parameters, designs and reports can be saved and accessed later for modification and recalculation

  5. Growth rates and production of heterotrophic bacteria and phytoplankton in the North Pacific subtropical gyre

    NASA Astrophysics Data System (ADS)

    Jones, David R.; Karl, David M.; Laws, Edward A.

    1996-10-01

    In field work conducted at 26°N, 155°W, in the North Pacific subtropical gyre, phytoplankton growth rates μp estimated from 14C labeling of chlorophyll a (chl a) averaged approximately one doubling per day in the euphotic zone (0-150 m). Microbial (microalgal plus heterotrophic bacterial) growth rates μm calculated from the incorporation of 3H-adenine into DNA were comparable to or exceeded phytoplankton growth rates at most depths in the euphotic zone. Photosynthetic rates averaged 727 mg C m -2 day -1 Phytoplankton carbon biomass, calculated from 14C labeling of chl a, averaged 7.2 mg m -3 in the euphotic zone. Vertical profiles of particulate DNA and ATP suggested that no more than 15% of particulate DNA was associated with actively growing cells. Heterotrophic bacterial carbon biomass was estimated from a two-year average at station ALOHA (22°45'N, 158°W) of flow cytometric counts of unpigmented, bacteria-size particles which bound DAPI on the assumption that 15% of the particles were actively growing cells and that heterotrophic bacterial cells contained 20 fg C cell -1 The heterotrophic bacterial carbon so calculated averaged 1.1 mg m -3 in the euphotic zone. Heterotrophic bacterial production was estimated to be 164 mg C m -2 day -1 or 23% of the calculated photosynthetic rate. Estimated heterotrophic bacterial growth rates averaged 0.97 day -1 in the euphotic zone and reached 4.7 day - at a depth of 20 m. Most heterotrophic bacterial production occurred in the upper 40 m of the euphotic zone, suggesting that direct excretion by phytoplankton, perhaps due to photorespiration or ultraviolet light effects, was a significant source of dissolved organic carbon for the bacteria.

  6. 5 CFR 532.253 - Special rates or rate ranges for leader, supervisory, and production facilitating positions.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 5 Administrative Personnel 1 2013-01-01 2013-01-01 false Special rates or rate ranges for leader....253 Special rates or rate ranges for leader, supervisory, and production facilitating positions. (a) When special rates or rate ranges are established for nonsupervisory positions, a lead agency...

  7. Photochemical free radical production rates in the eastern Caribbean

    NASA Astrophysics Data System (ADS)

    Dister, Brian; Zafiriou, Oliver C.

    1993-02-01

    Potential photochemical production rates of total (NO-scavengeable) free radicals were surveyed underway (> 900 points) in the eastern Caribbean and Orinoco delta in spring and fall 1988. These data document seasonal trends and large-scale (˜ 10-1000 km) variability in the pools of sunlight-generated reactive transients, which probably mediate a major portion of marine photoredox transformations. Radical production potential was detectable in all waters and was reasonably quantifiable at rates above 0.25 nmol L-1 min-1 sun-1. Radical production rates varied from ˜ 0.1-0.5 nmol L-1 min-1 of full-sun illumination in "blue water" to > 60 nmol L-1 min-1 in some estuarine waters in the high-flow season. Qualitatively, spatiotemporal potential rate distributions strikingly resembled that of "chlorophyll" (a riverine-influence tracer of uncertain specificity) in 1979-1981 CZCS images of the region [Müller-Karger et al., 1988] at all scales. Basin-scale occurrence of greatly enhanced rates in fall compared to spring is attributed to terrestrial chromophore inputs, primarily from the Orinoco River, any contributions from Amazon water and nutrient-stimulus effects could not be resolved. A major part of the functionally photoreactive colored organic matter (COM) involved in radical formation clearly mixes without massive loss out into high-salinity waters, although humic acids may flocculate in estuaries. A similar conclusion applies over smaller scales for COM as measured optically [Blough et al., this issue]. Furthermore, optical absorption and radical production rates were positively correlated in the estuarine region in fall. These cruises demonstrated that photochemical techniques are now adequate to treat terrestrial photochemical chromophore inputs as an estuarine mixing problem on a large scale, though the ancillary data base does not currently support such an analysis in this region. Eastern Caribbean waters are not markedly more reactive at comparable salinities

  8. r-process Lanthanide Production and Heating Rates in Kilonovae

    NASA Astrophysics Data System (ADS)

    Lippuner, Jonas; Roberts, Luke F.

    2015-12-01

    r-process nucleosynthesis in material ejected during neutron star mergers may lead to radioactively powered transients called kilonovae. The timescale and peak luminosity of these transients depend on the composition of the ejecta, which determines the local heating rate from nuclear decays and the opacity. Kasen et al. and Tanaka & Hotokezaka pointed out that lanthanides can drastically increase the opacity in these outflows. We use the new general-purpose nuclear reaction network SkyNet to carry out a parameter study of r-process nucleosynthesis for a range of initial electron fractions Ye, initial specific entropies s, and expansion timescales τ. We find that the ejecta is lanthanide-free for Ye ≳ 0.22-0.30, depending on s and τ. The heating rate is insensitive to s and τ, but certain, larger values of Ye lead to reduced heating rates, due to individual nuclides dominating the heating. We calculate approximate light curves with a simplified gray radiative transport scheme. The light curves peak at about a day (week) in the lanthanide-free (-rich) cases. The heating rate does not change much as the ejecta becomes lanthanide-free with increasing Ye, but the light-curve peak becomes about an order of magnitude brighter because it peaks much earlier when the heating rate is larger. We also provide parametric fits for the heating rates between 0.1 and 100 days, and we provide a simple fit in Ye, s, and τ to estimate whether or not the ejecta is lanthanide-rich.

  9. r-PROCESS LANTHANIDE PRODUCTION AND HEATING RATES IN KILONOVAE

    SciTech Connect

    Lippuner, Jonas; Roberts, Luke F.

    2015-12-20

    r-process nucleosynthesis in material ejected during neutron star mergers may lead to radioactively powered transients called kilonovae. The timescale and peak luminosity of these transients depend on the composition of the ejecta, which determines the local heating rate from nuclear decays and the opacity. Kasen et al. and Tanaka and Hotokezaka pointed out that lanthanides can drastically increase the opacity in these outflows. We use the new general-purpose nuclear reaction network SkyNet to carry out a parameter study of r-process nucleosynthesis for a range of initial electron fractions Y{sub e}, initial specific entropies s, and expansion timescales τ. We find that the ejecta is lanthanide-free for Y{sub e} ≳ 0.22−0.30, depending on s and τ. The heating rate is insensitive to s and τ, but certain, larger values of Y{sub e} lead to reduced heating rates, due to individual nuclides dominating the heating. We calculate approximate light curves with a simplified gray radiative transport scheme. The light curves peak at about a day (week) in the lanthanide-free (-rich) cases. The heating rate does not change much as the ejecta becomes lanthanide-free with increasing Y{sub e}, but the light-curve peak becomes about an order of magnitude brighter because it peaks much earlier when the heating rate is larger. We also provide parametric fits for the heating rates between 0.1 and 100 days, and we provide a simple fit in Y{sub e}, s, and τ to estimate whether or not the ejecta is lanthanide-rich.

  10. Estimates of Biogenic Methane Production Rates in Deep Marine Sediments

    NASA Astrophysics Data System (ADS)

    Colwell, F. S.; Boyd, S.; Delwiche, M. E.; Reed, D. W.

    2004-12-01

    Much of the methane in natural gas hydrates in marine sediments is made by methanogens. Current models used to predict hydrate distribution and concentration in these sediments require estimates of microbial methane production rates. However, accurate estimates are difficult to achieve because of the bias introduced by sampling and because methanogen activities in these sediments are low and not easily detected. To derive useful methane production rates for marine sediments we have measured the methanogen biomass in samples taken from different depths in Hydrate Ridge (HR) sediments off the coast of Oregon and, separately, the minimal rates of activity for a methanogen in a laboratory reactor. For methanogen biomass, we used a polymerase chain reaction assay in real time to target the methanogen-specific mcr gene. Using this method we found that a majority of the samples collected from boreholes at HR show no evidence of methanogens (detection limit: less than 100 methanogens per g of sediment). Most of the samples with detectable numbers of methanogens were from shallow sediments (less than 10 meters below seafloor [mbsf]) although a few samples with apparently high numbers of methanogens (greater than 10,000 methanogens per g) were from as deep as 230 mbsf and were associated with notable geological features (e.g., the bottom-simulating reflector and an ash-bearing zone with high fluid movement). Laboratory studies with Methanoculleus submarinus (isolated from a hydrate zone at the Nankai Trough) maintained in a biomass recycle reactor showed that when this methanogen is merely surviving, as is likely the case in deep marine sediments, it produces approximately 0.06 fmol methane per cell per day. This is far lower than rates reported for methanogens in other environments. By combining this estimate of specific methanogenic rates and an extrapolation from the numbers of methanogens at selected depths in the sediment column at HR sites we have derived a maximum

  11. 42 CFR 412.523 - Methodology for calculating the Federal prospective payment rates.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 2 2010-10-01 2010-10-01 false Methodology for calculating the Federal prospective... SERVICES Prospective Payment System for Long-Term Care Hospitals § 412.523 Methodology for calculating the..., under the update methodology described in section 1886(b)(3)(B)(ii) of the Act for each year....

  12. Zymomonas mobilis mutants with an increased rate of alcohol production

    SciTech Connect

    Osman, Y.A.; Ingram, L.O.

    1987-07-01

    Two new derivatives of Zymomonas mobilis CP4 were isolated from enrichment cultures after 18 months of serial transfer. These new strains were selected for the ability to grow and produce ethanol rapidly on transfer into fresh broth containing ethanol and allyl alcohol. Ethanol production by these strains was examined in batch fermentations under three sets of conditions. Both new derivatives were found to be superior to the parent strain CP4 with respect to the speed and completeness of glucose conversion to ethanol. The best of these, strain YO2, produced 9.5% ethanol (by weight; 11.9% by volume) after 17.4 h compared with 31.8 h for the parent strain CP4. The addition of 1 mM magnesium sulfate improved ethanol production in all three strains. Two factors contributed to the decrease in fermentation time required by the mutants: more rapid growth with minimal lag on subculturing and the retention of higher rates of ethanol production as fermentation proceeded. Alcohol dehydrogenase isozymes were altered in both new strains and no longer catalyzed the oxidation of allyl alcohol into the toxic product acrolein. This loss of allyl alcohol-oxidizing capacity is proposed as a primary factor contributing to increased allyl alcohol resistance, although it is likely that other mutations affecting glycolysis also contribute to the improvement in ethanol production.

  13. Dose equivalent rate constants and barrier transmission data for nuclear medicine facility dose calculations and shielding design.

    PubMed

    Kusano, Maggie; Caldwell, Curtis B

    2014-07-01

    A primary goal of nuclear medicine facility design is to keep public and worker radiation doses As Low As Reasonably Achievable (ALARA). To estimate dose and shielding requirements, one needs to know both the dose equivalent rate constants for soft tissue and barrier transmission factors (TFs) for all radionuclides of interest. Dose equivalent rate constants are most commonly calculated using published air kerma or exposure rate constants, while transmission factors are most commonly calculated using published tenth-value layers (TVLs). Values can be calculated more accurately using the radionuclide's photon emission spectrum and the physical properties of lead, concrete, and/or tissue at these energies. These calculations may be non-trivial due to the polyenergetic nature of the radionuclides used in nuclear medicine. In this paper, the effects of dose equivalent rate constant and transmission factor on nuclear medicine dose and shielding calculations are investigated, and new values based on up-to-date nuclear data and thresholds specific to nuclear medicine are proposed. To facilitate practical use, transmission curves were fitted to the three-parameter Archer equation. Finally, the results of this work were applied to the design of a sample nuclear medicine facility and compared to doses calculated using common methods to investigate the effects of these values on dose estimates and shielding decisions. Dose equivalent rate constants generally agreed well with those derived from the literature with the exception of those from NCRP 124. Depending on the situation, Archer fit TFs could be significantly more accurate than TVL-based TFs. These results were reflected in the sample shielding problem, with unshielded dose estimates agreeing well, with the exception of those based on NCRP 124, and Archer fit TFs providing a more accurate alternative to TVL TFs and a simpler alternative to full spectral-based calculations. The data provided by this paper should assist

  14. Revised Production Rates for Na-22 and Mn-54 in Meteorites Using Cross Sections Measured for Neutron-induced Reactions

    NASA Technical Reports Server (NTRS)

    Sisterson, J. M.; Kim, K. J.; Reedy, R. C.

    2004-01-01

    The interactions of galactic cosmic rays (GCR) with extraterrestrial bodies produce small amounts of radionuclides and stable isotopes. The production rates of many relatively short-lived radionuclides, including 2.6-year Na-22 and 312-day Mn-54, have been measured in several meteorites collected very soon after they fell. Theoretical models used to calculate production rates for comparison with the measured values rely on input data containing good cross section measurements for all relevant reactions. Most GCR particles are protons, but secondary neutrons make most cosmogenic nuclides. Calculated production rates using only cross sections for proton-induced reactions do not agree well with measurements. One possible explanation is that the contribution to the production rate from reactions initiated by secondary neutrons produced in primary GCR interactions should be included explicitly. This, however, is difficult to do because so few of the relevant cross sections for neutron-induced reactions have been measured.

  15. Subterranean production of neutrons, 39Ar and 21Ne: Rates and uncertainties

    NASA Astrophysics Data System (ADS)

    Šrámek, Ondřej; Stevens, Lauren; McDonough, William F.; Mukhopadhyay, Sujoy; Peterson, R. J.

    2017-01-01

    Accurate understanding of the subsurface production rate of the radionuclide 39Ar is necessary for argon dating techniques and noble gas geochemistry of the shallow and the deep Earth, and is also of interest to the WIMP dark matter experimental particle physics community. Our new calculations of subsurface production of neutrons, 21Ne , and 39Ar take advantage of the state-of-the-art reliable tools of nuclear physics to obtain reaction cross sections and spectra (TALYS) and to evaluate neutron propagation in rock (MCNP6). We discuss our method and results in relation to previous studies and show the relative importance of various neutron, 21Ne , and 39Ar nucleogenic production channels. Uncertainty in nuclear reaction cross sections, which is the major contributor to overall calculation uncertainty, is estimated from variability in existing experimental and library data. Depending on selected rock composition, on the order of 107-1010 α particles are produced in one kilogram of rock per year (order of 1-103 kg-1 s-1); the number of produced neutrons is lower by ∼ 6 orders of magnitude, 21Ne production rate drops by an additional factor of 15-20, and another one order of magnitude or more is dropped in production of 39Ar. Our calculation yields a nucleogenic 21Ne /4He production ratio of (4.6 ± 0.6) ×10-8 in Continental Crust and (4.2 ± 0.5) ×10-8 in Oceanic Crust and Depleted Mantle. Calculated 39Ar production rates span a great range from 29 ± 9 atoms kg-rock-1 yr-1 in the K-Th-U-enriched Upper Continental Crust to (2.6 ± 0.8) × 10-4 atoms kg-rock-1 yr-1 in Depleted Upper Mantle. Nucleogenic 39Ar production exceeds the cosmogenic production below ∼700 m depth and thus, affects radiometric ages of groundwater. The 39Ar chronometer, which fills in a gap between 3H and 14C , is particularly important given the need to tap deep reservoirs of ancient drinking water.

  16. Production of scandium-44m and scandium-44g with deuterons on calcium-44: cross section measurements and production yield calculations

    NASA Astrophysics Data System (ADS)

    Duchemin, C.; Guertin, A.; Haddad, F.; Michel, N.; Métivier, V.

    2015-09-01

    HIGHLIGHTS • Production of Sc-44m, Sc-44g and contaminants. • Experimental values determined using the stacked-foil technique. • Thick-Target production Yield (TTY) calculations. • Comparison with the TALYS code version 1.6. Among the large number of radionuclides of medical interest, Sc-44 is promising for PET imaging. Either the ground-state Sc-44g or the metastable-state Sc-44m can be used for such applications, depending on the molecule used as vector. This study compares the production rates of both Sc-44 states, when protons or deuterons are used as projectiles on an enriched Calcium-44 target. This work presents the first set of data for the deuteron route. The results are compared with the TALYS code. The Thick-Target production Yields of Sc-44m and Sc-44g are calculated and compared with those for the proton route for three different scenarios: the production of Sc-44g for conventional PET imaging, its production for the new 3 γ imaging technique developed at the SUBATECH laboratory and the production of a Sc-44m/Sc-44g in vivo generator for antibody labelling.

  17. Experimental particle formation rates spanning tropospheric sulfuric acid and ammonia abundances, ion production rates, and temperatures

    NASA Astrophysics Data System (ADS)

    Kürten, Andreas; Bianchi, Federico; Almeida, Joao; Kupiainen-Määttä, Oona; Dunne, Eimear M.; Duplissy, Jonathan; Williamson, Christina; Barmet, Peter; Breitenlechner, Martin; Dommen, Josef; Donahue, Neil M.; Flagan, Richard C.; Franchin, Alessandro; Gordon, Hamish; Hakala, Jani; Hansel, Armin; Heinritzi, Martin; Ickes, Luisa; Jokinen, Tuija; Kangasluoma, Juha; Kim, Jaeseok; Kirkby, Jasper; Kupc, Agnieszka; Lehtipalo, Katrianne; Leiminger, Markus; Makhmutov, Vladimir; Onnela, Antti; Ortega, Ismael K.; Petäjä, Tuukka; Praplan, Arnaud P.; Riccobono, Francesco; Rissanen, Matti P.; Rondo, Linda; Schnitzhofer, Ralf; Schobesberger, Siegfried; Smith, James N.; Steiner, Gerhard; Stozhkov, Yuri; Tomé, António; Tröstl, Jasmin; Tsagkogeorgas, Georgios; Wagner, Paul E.; Wimmer, Daniela; Ye, Penglin; Baltensperger, Urs; Carslaw, Ken; Kulmala, Markku; Curtius, Joachim

    2016-10-01

    Binary nucleation of sulfuric acid and water as well as ternary nucleation involving ammonia are thought to be the dominant processes responsible for new particle formation (NPF) in the cold temperatures of the middle and upper troposphere. Ions are also thought to be important for particle nucleation in these regions. However, global models presently lack experimentally measured NPF rates under controlled laboratory conditions and so at present must rely on theoretical or empirical parameterizations. Here with data obtained in the European Organization for Nuclear Research CLOUD (Cosmics Leaving OUtdoor Droplets) chamber, we present the first experimental survey of NPF rates spanning free tropospheric conditions. The conditions during nucleation cover a temperature range from 208 to 298 K, sulfuric acid concentrations between 5 × 105 and 1 × 109 cm-3, and ammonia mixing ratios from zero added ammonia, i.e., nominally pure binary, to a maximum of 1400 parts per trillion by volume (pptv). We performed nucleation studies under pure neutral conditions with zero ions being present in the chamber and at ionization rates of up to 75 ion pairs cm-3 s-1 to study neutral and ion-induced nucleation. We found that the contribution from ion-induced nucleation is small at temperatures between 208 and 248 K when ammonia is present at several pptv or higher. However, the presence of charges significantly enhances the nucleation rates, especially at 248 K with zero added ammonia, and for higher temperatures independent of NH3 levels. We compare these experimental data with calculated cluster formation rates from the Atmospheric Cluster Dynamics Code with cluster evaporation rates obtained from quantum chemistry.

  18. 40 CFR 1065.642 - SSV, CFV, and PDP molar flow rate calculations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Calculations and Data Requirements § 1065.642 SSV... ranges of dilution air dewpoint versus calibration air dewpoint in Table 3 of § 1065.640, you may set...

  19. Linear extension rates and gross carbonate production of Acropora cervicornis at Coral Gardens, Belize.

    NASA Astrophysics Data System (ADS)

    Peeling, E.; Greer, L.; Lescinsky, H.; Humston, R.; Wirth, K. R.; Baums, I. B.; Curran, A.

    2014-12-01

    Branching Acropora coral species have fast growth and carbonate production rates, and thus have functioned as important reef-building species throughout the Pleistocene and Holocene. Recently, net carbonate production (kg CaCO3 m-2 year-1) has been recognized as an important measure of reef health, especially when monitoring endangered species, such as Acropora cervicornis. This study examines carbonate production in a thriving population of A. cervicornis at the Coral Gardens reef in Belize. Photographic surveys were conducted along five transects of A. cervicornis-dominated reefs from 2011-2014. Matching photographs from 2013 and 2014 were scaled to 1 m2 and compared to calculate 84 individual A. cervicornis linear extension rates across the reef. Linear extension rates averaged 12.4 cm/yr and were as high as 17 cm/yr in some areas of the reef. Carbonate production was calculated two ways. The first followed the standard procedure of multiplying percent live coral cover, by the linear extension rate and skeletal density. The second used the number of live coral tips per square meter in place of percent live coral multiplied by the average cross-sectional area of the branches. The standard method yielded a carbonate production rate of 113 kg CaCO3 m-2 year-1 for the reef, and the tip method yielded a rate of 6 kg m-2 year-1. We suggest that the tip method is a more accurate measure of production, because A. cervicornis grows primarily from the live tips, with only limited radial growth and resheeting over dead skeleton. While this method omits the contributions of radial growth and resheeting, and is therefore somewhat of an underestimate, our future work will quantify these aspects of growth in a more complete carbonate budget. Still, our estimate suggests a carbonate production rate per unit area of A. cervicornis that is on par with other Caribbean coral species, rather than two orders of magnitude higher as reported by Perry et al (2013). Although gross coral

  20. Universal scaling of production rates across mammalian lineages.

    PubMed

    Hamilton, Marcus J; Davidson, Ana D; Sibly, Richard M; Brown, James H

    2011-02-22

    Over many millions of years of independent evolution, placental, marsupial and monotreme mammals have diverged conspicuously in physiology, life history and reproductive ecology. The differences in life histories are particularly striking. Compared with placentals, marsupials exhibit shorter pregnancy, smaller size of offspring at birth and longer period of lactation in the pouch. Monotremes also exhibit short pregnancy, but incubate embryos in eggs, followed by a long period of post-hatching lactation. Using a large sample of mammalian species, we show that, remarkably, despite their very different life histories, the scaling of production rates is statistically indistinguishable across mammalian lineages. Apparently all mammals are subject to the same fundamental metabolic constraints on productivity, because they share similar body designs, vascular systems and costs of producing new tissue.

  1. Production of carboxylates from high rate activated sludge through fermentation.

    PubMed

    Cagnetta, C; Coma, M; Vlaeminck, S E; Rabaey, K

    2016-10-01

    The aim of this work was to study the key parameters affecting fermentation of high rate activated A-sludge to carboxylates, including pH, temperature, inoculum, sludge composition and iron content. The maximum volatile fatty acids production was 141mgCg(-1) VSSfed, at pH 7. Subsequently the potential for carboxylate and methane production for A-sludge from four different plants at pH 7 and 35°C were compared. Initial BOD of the sludge appeared to be key determining carboxylate yield from A-sludge. Whereas methanogenesis could be correlated linearly to the quantity of ferric used for coagulation, fermentation did not show a dependency on iron presence. This difference may enable a strategy whereby A-stage sludge is separated to achieve fermentation, and iron dosing for phosphate removal is only implemented at the B-stage.

  2. Universal scaling of production rates across mammalian lineages

    PubMed Central

    Hamilton, Marcus J.; Davidson, Ana D.; Sibly, Richard M.; Brown, James H.

    2011-01-01

    Over many millions of years of independent evolution, placental, marsupial and monotreme mammals have diverged conspicuously in physiology, life history and reproductive ecology. The differences in life histories are particularly striking. Compared with placentals, marsupials exhibit shorter pregnancy, smaller size of offspring at birth and longer period of lactation in the pouch. Monotremes also exhibit short pregnancy, but incubate embryos in eggs, followed by a long period of post-hatching lactation. Using a large sample of mammalian species, we show that, remarkably, despite their very different life histories, the scaling of production rates is statistically indistinguishable across mammalian lineages. Apparently all mammals are subject to the same fundamental metabolic constraints on productivity, because they share similar body designs, vascular systems and costs of producing new tissue. PMID:20798111

  3. Forest turnover rates follow global and regional patterns of productivity

    USGS Publications Warehouse

    Stephenson, N.L.; van Mantgem, P.J.

    2005-01-01

    Using a global database, we found that forest turnover rates (the average of tree mortality and recruitment rates) parallel broad-scale patterns of net primary productivity. First, forest turnover was higher in tropical than in temperate forests. Second, as recently demonstrated by others, Amazonian forest turnover was higher on fertile than infertile soils. Third, within temperate latitudes, turnover was highest in angiosperm forests, intermediate in mixed forests, and lowest in gymnosperm forests. Finally, within a single forest physiognomic type, turnover declined sharply with elevation (hence with temperature). These patterns of turnover in populations of trees are broadly similar to the patterns of turnover in populations of plant organs (leaves and roots) found in other studies. Our findings suggest a link between forest mass balance and the population dynamics of trees, and have implications for understanding and predicting the effects of environmental changes on forest structure and terrestrial carbon dynamics. ??2005 Blackwell Publishing Ltd/CNRS.

  4. The Production Rate and Employment of Ph.D. Astronomers

    NASA Astrophysics Data System (ADS)

    Metcalfe, Travis S.

    2008-02-01

    In an effort to encourage self-regulation of the astronomy job market, I examine the supply of, and demand for, astronomers over time. On the supply side, I document the production rate of Ph.D. astronomers from 1970 to 2006 using the UMI Dissertation Abstracts database, along with data from other independent sources. I compare the long-term trends in Ph.D. production with federal astronomy research funding over the same time period, and I demonstrate that additional funding is correlated with higher subsequent Ph.D. production. On the demand side, I monitor the changing patterns of employment using statistics about the number and types of jobs advertised in the AAS Job Register from 1984 to 2006. Finally, I assess the sustainability of the job market by normalizing this demand by the annual Ph.D. production. The most recent data suggest that there are now annual advertisements for about one postdoctoral job, half a faculty job, and half a research/support position for every new domestic Ph.D. recipient in astronomy and astrophysics. The average new astronomer might expect to hold up to 3 jobs before finding a steady position.

  5. The Production Rate and Employment of Ph.D. Astronomers

    NASA Astrophysics Data System (ADS)

    Metcalfe, Travis S.

    2007-05-01

    As in many sciences, the production rate of new Ph.D. astronomers is decoupled from the global demand for trained scientists. As noted by Thronson (1991, PASP, 103, 90), overproduction appears to be built into the system, making the mathematical formulation of surplus astronomer production similar to that for industrial pollution models -- an unintended side effect of the process. Following Harris (1994, ASP Conf., 57, 12), I document the production of Ph.D. astronomers from 1990 to 2005 using the online Dissertation Abstracts database. To monitor the changing patterns of employment, I examine the number of postdoctoral, tenure-track, and other jobs advertised in the AAS Job Register during this same period. Although the current situation is clearly unsustainable, it was much worse a decade ago with nearly 7 new Ph.D. astronomers in 1995 for every new tenure-track job. While the number of new permanent positions steadily increased throughout the late 1990's, the number of new Ph.D. recipients gradually declined. After the turn of the century, the production of new astronomers leveled off, but new postdoctoral positions grew dramatically. There has also been recent growth in the number of non-tenure-track lecturer, research, and support positions. This is just one example of a larger cultural shift to temporary employment that is happening throughout society -- it is not unique to astronomy.

  6. Calculated hydroxyl A2 sigma --> X2 pi (0, 0) band emission rate factors applicable to atmospheric spectroscopy.

    PubMed

    Cageao, R P; Ha, Y L; Jiang, Y; Morgan, M F; Yung, Y L; Sander, S P

    1997-05-01

    A calculation of the A2 sigma --> X2 pi (0, 0) band emission rate factors and line center absorption cross sections of OH applicable to its measurement using solar resonant fluorescence in the terrestrial atmosphere is presented in this paper. The most accurate available line parameters have been used. Special consideration has been given to the solar input flux because of its highly structured Fraunhofer spectrum. The calculation for the OH atmospheric emission rate factor in the solar resonant fluorescent case is described in detail with examples and intermediate results. Results of this calculation of OH emission rate factors for individual rotational lines are on average 30% lower than the values obtained in an earlier work.

  7. Carbon Calculator for Land Use Change from Biofuels Production (CCLUB) Users’ Manual and Technical Documentation

    SciTech Connect

    Dunn, Jennifer B.; Qin, Zhangcai; Mueller, Steffen; Kwon, Ho-young; Wander, Michelle M.; Wang, Michael

    2016-09-01

    The $\\underline{C}$arbon $\\underline{C}$alculator for $\\underline{L}$and $\\underline{U}$se Change from $\\underline{B}$iofuels Production (CCLUB) calculates carbon emissions from land use change (LUC) for four different ethanol production pathways including corn grain ethanol and cellulosic ethanol from corn stover, Miscanthus, and switchgrass. This document discusses the version of CCLUB released September 30, 2014 which includes corn and three cellulosic feedstocks: corn stover, Miscanthus, and switchgrass.

  8. Calculation: Values and Consumption Rates of Locally Produced Food and Tap Water for the Receptor of Interest

    SciTech Connect

    J. Bland

    2000-07-31

    This calculation produces standard statistical data on the consumption of locally produced food and tap water. The results of this calculation provide input parameters for the GENII-S (Leigh et al. 1993) computer code to support calculation of Biosphere Dose Conversion Factors (BDCF) for the nominal performance (groundwater contamination) scenario and the volcanic eruption (contamination of soil by volcanic ash deposition) scenario. The requirement and parameters for these data are identified in ''Identification Of The Critical Group (Consumption Of Locally Produced Food And Tap Water)'' (CRWMS M&O 2000a). This calculation is performed in accordance with the ''Development Plan for Calculation: Values and Consumption Rates of Locally Produced Food and Tap Water for the Receptor of Interest'' (CRWMS M&O 2000b).

  9. Mixed quantum classical calculation of proton transfer reaction rates: From deep tunneling to over the barrier regimes

    SciTech Connect

    Xie, Weiwei; Xu, Yang; Zhu, Lili; Shi, Qiang

    2014-05-07

    We present mixed quantum classical calculations of the proton transfer (PT) reaction rates represented by a double well system coupled to a dissipative bath. The rate constants are calculated within the so called nontraditional view of the PT reaction, where the proton motion is quantized and the solvent polarization is used as the reaction coordinate. Quantization of the proton degree of freedom results in a problem of non-adiabatic dynamics. By employing the reactive flux formulation of the rate constant, the initial sampling starts from the transition state defined using the collective reaction coordinate. Dynamics of the collective reaction coordinate is treated classically as over damped diffusive motion, for which the equation of motion can be derived using the path integral, or the mixed quantum classical Liouville equation methods. The calculated mixed quantum classical rate constants agree well with the results from the numerically exact hierarchical equation of motion approach for a broad range of model parameters. Moreover, we are able to obtain contributions from each vibrational state to the total reaction rate, which helps to understand the reaction mechanism from the deep tunneling to over the barrier regimes. The numerical results are also compared with those from existing approximate theories based on calculations of the non-adiabatic transmission coefficients. It is found that the two-surface Landau-Zener formula works well in calculating the transmission coefficients in the deep tunneling regime, where the crossing point between the two lowest vibrational states dominates the total reaction rate. When multiple vibrational levels are involved, including additional crossing points on the free energy surfaces is important to obtain the correct reaction rate using the Landau-Zener formula.

  10. Mixed quantum classical calculation of proton transfer reaction rates: from deep tunneling to over the barrier regimes.

    PubMed

    Xie, Weiwei; Xu, Yang; Zhu, Lili; Shi, Qiang

    2014-05-07

    We present mixed quantum classical calculations of the proton transfer (PT) reaction rates represented by a double well system coupled to a dissipative bath. The rate constants are calculated within the so called nontraditional view of the PT reaction, where the proton motion is quantized and the solvent polarization is used as the reaction coordinate. Quantization of the proton degree of freedom results in a problem of non-adiabatic dynamics. By employing the reactive flux formulation of the rate constant, the initial sampling starts from the transition state defined using the collective reaction coordinate. Dynamics of the collective reaction coordinate is treated classically as over damped diffusive motion, for which the equation of motion can be derived using the path integral, or the mixed quantum classical Liouville equation methods. The calculated mixed quantum classical rate constants agree well with the results from the numerically exact hierarchical equation of motion approach for a broad range of model parameters. Moreover, we are able to obtain contributions from each vibrational state to the total reaction rate, which helps to understand the reaction mechanism from the deep tunneling to over the barrier regimes. The numerical results are also compared with those from existing approximate theories based on calculations of the non-adiabatic transmission coefficients. It is found that the two-surface Landau-Zener formula works well in calculating the transmission coefficients in the deep tunneling regime, where the crossing point between the two lowest vibrational states dominates the total reaction rate. When multiple vibrational levels are involved, including additional crossing points on the free energy surfaces is important to obtain the correct reaction rate using the Landau-Zener formula.

  11. Chlorine-36 Production Rate Calibration by the CRONUS-Earth Project

    NASA Astrophysics Data System (ADS)

    Phillips, F. M.; Marrero, S.; Stone, J. O.; Lifton, N. A.

    2012-12-01

    Among the cosmogenic nuclides commonly used for Quaternary geochronology and geomorphology (36Cl, 10Be, 26Al, 3He, and 14C), the production rate of 36Cl has proved particularly difficult to calibrate because of the multiple nuclear reactions that lead to its production (3 major reactions and 5 minor ones). Achieving a consensus on the production constants for 36Cl has therefore been a major emphasis of the NSF-funded Cosmic Ray Produced Nuclide Systematics on Earth (CRONUS-Earth) Project. The most suitable for 36Cl calibration of the sites sampled by CRONUS-Earth proved to be ignimbrites from Younger Dryas-correlative moraines near the Quelccaya Ice Cap in Peru, basalts from the similar-aged Tabernacle Hill flow in Utah, and granodiorite boulders on a similar-aged moraine at Baboon Lakes in the Sierra Nevada, California. Production rates were estimated by minimizing 36Cl concentration residuals, with production scaled between the sites using the recently developed Lifton-Sato formulation. The scaling parameters employed were cut-off rigidity of 0 GV, solar modulation parameter of 587.4 MV, and air pressure of 1013.25 hPa; production-rate parameters obtained using this scaling approach are not directly comparable to those previously estimated using alternative scaling methods. This approach yielded sea-level high-latitude production rates of 55±2 atoms 36Cl (g Ca)-1 yr-1, 157±5 atoms 36Cl (g K)-1 yr-1, and 704±140 neutrons (g air)-1 yr-1. The results from the minimization did not meet tests for statistical significance and therefore the parameter-rate uncertainties could not be determined directly from the calibration data set. An independent secondary data set consisting of 82 samples from 16 localities and compiled from 7 separate published studies was therefore employed for this purpose. Average deviations of calculated 36Cl ages from independently determined ages increased from about 10% for samples where 36Cl production was nearly all from spallation

  12. Determination of absolute configuration of natural products: theoretical calculation of electronic circular dichroism as a tool

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Determination of absolute configuration (AC) is one of the most challenging features in the structure elucidation of chiral natural products, especially those with complex structures. With revolutionary advancements in the area of quantum chemical calculations of chiroptical spectroscopy over the pa...

  13. Direct Measurement of the Unimolecular Decay Rate of Criegee Intermediates to OH Products

    NASA Astrophysics Data System (ADS)

    Liu, Fang; Fang, Yi; Klippenstein, Stephen; McCoy, Anne; Lester, Marsha

    Ozonolysis of alkenes is an important non-photolytic source of OH radicals in the troposphere. The production of OH radicals proceeds though formation and unimolecular decay of Criegee intermediates such as syn-CH3CHOO and (CH3)2COO. These alkyl-substituted Criegee intermediates can undergo a 1,4-H transfer reaction to form an energized vinyl hydroperoxide species, which breaks apart to OH and vinoxy products. Recently, this laboratory used IR excitation in the C-H stretch overtone region to initiate the unimolecular decay of syn-CH3CHOO and (CH3)2COO Criegee intermediates, leading to OH formation. Here, direct time-domain measurements are performed to observe the rate of appearance of OH products under collision-free conditions utilizing UV laser-induced fluorescence for detection. The experimental rates are in excellent agreement with statistical RRKM calculations using barrier heights predicted from high-level electronic structure calculations. Accurate determination of the rates and barrier heights for unimolecular decay of Criegee intermediates is essential for modeling the kinetics of alkene ozonolysis reactions, a significant OH radical source in atmospheric chemistry, as well as the steady-state concentration of Criegee intermediates in the atmosphere. This research was supported through the National Science Foundation under grant CHE-1362835.

  14. Estimating long-term exposure levels in process-type industries using production rates.

    PubMed

    Kalliokoski, P

    1990-06-01

    Exposure to toluene in two publication rotogravure plants was investigated to examine how accurately long-term exposure can be estimated on the basis of production rate. Toluene consumption was used as the measure of production rate. Continuous area monitoring was used to find a correlation between production rate and airborne level of toluene. Workers' exposure levels were first estimated by combining data on toluene concentrations in various monitoring sites with data supplied by the workers on the time spent in these areas. These calculated exposure levels were found to correlate well with the actual exposure levels obtained by breathing zone sampling. There was also a fairly high correlation between the concentration of toluene in front of the press and the consumption of toluene if the process conditions remained stable. It was, however, necessary to investigate this association separately for the situations where the degree of enclosure of the press or number of emission sources were unusual or when the workers stayed in the control rooms, which were separated from the other pressroom areas. A reasonably high correlation between the variables of the main interest, that is, the calculated toluene exposures and the consumption of toluene, was found in one of the plants investigated, whereas this correlation was low in the other plant. Even though this kind of estimation procedure does not always lead to accurate exposure levels, it helps in understanding how those are affected by the process parameters.

  15. Calculation of rates of exciton dissociation into hot charge-transfer states in model organic photovoltaic interfaces

    NASA Astrophysics Data System (ADS)

    Vázquez, Héctor; Troisi, Alessandro

    2013-11-01

    We investigate the process of exciton dissociation in ordered and disordered model donor/acceptor systems and describe a method to calculate exciton dissociation rates. We consider a one-dimensional system with Frenkel states in the donor material and states where charge transfer has taken place between donor and acceptor. We introduce a Green's function approach to calculate the generation rates of charge-transfer states. For disorder in the Frenkel states we find a clear exponential dependence of charge dissociation rates with exciton-interface distance, with a distance decay constant β that increases linearly with the amount of disorder. Disorder in the parameters that describe (final) charge-transfer states has little effect on the rates. Exciton dissociation invariably leads to partially separated charges. In all cases final states are “hot” charge-transfer states, with electron and hole located far from the interface.

  16. The effect of soil moisture on nitrous oxide production rates in large enclosed ecosystems

    NASA Astrophysics Data System (ADS)

    van Haren, J.; Colodner, D.; Lin, G.; Murthy, R.

    2001-12-01

    On land, nitrous oxide (N2O) is mainly produced in soils by bacterial processes such as nitrification and denitrification. Once in the atmosphere N2O contributes to the greenhouse effect and stratospheric ozone destruction. Nitrification and denitrification are strongly dependent on soil moisture content, amongst other soil parameters. At Biosphere 2 Center we have begun to test the utility of meso-scale closed systems for understanding the relationship between soil properties and trace gas production at larger scales. We investigated the relationship between soil moisture content and soil N2O efflux in two large experimental closed systems (Tropical Rainforest (TR) and Intensive Forestry (IF) Mesocosms) at Biosphere 2 Center. N2O was measured every hour with an automated GC system. The daily N2O production rate was calculated as the rate of increase of N2O during the daytime, when the mesocosm was materially closed. We furthermore measured N2O and nitrate concentrations in the soil, as well as nitrate and N2O production rates in local areas. In the Rainforest Mesocosm, we found a very reproducible relationship between soil moisture content and N2O efflux, including the transient spikes in production rate upon wetting. In the Forestry Mesocosm the relation between soil moisture and N2O efflux was less clearcut.

  17. MORATE 6.5: A new version of a computer program for direct dynamics calculations of chemical reaction rate constants

    NASA Astrophysics Data System (ADS)

    Hu, Wei-Ping; Lynch, Gillian C.; Liu, Yi-Ping; Rossi, Ivan; Stewart, James J. P.; Steckler, Rozeanne; Garrett, Bruce C.; Isaacson, Alan D.; Lu, Da-hong; Melissas, Vasilios S.; Truhlar, Donald G.

    1995-08-01

    MORATE (Molecular Orbital RATE calculations) is a computer program for direct dynamics calculations of unimolecular and bimolecular rate constants of gas-phase chemical reactions involving atoms, diatoms, or polyatomic species. The dynamical methods used are conventional or variational transition state theory and multidimensional semiclassical approximations for tunneling and nonclassical reflection. Variational transition states are found by a one-dimensional search of generalized-transition-state dividing surfaces perpendicular to the minimum-energy path, and tunneling probabilities are evaluated by multidimensional semiclassical algorithms, including the small-curvature and large-curvature tunneling approximations and the microcanonical optimized multidimensional tunneling approximation. The computer program is a conventiently interfaced package consisting of the POLYRATE program, version 6.5, for dynamical rate constant calculations, and the MOPAC program, version 5.05mn, for semiempirical electronic structure computations. In single-level mode, the potential energies, gradients, and higher derivatives of the potential are computed whenever needed by electronic structure calculations employing semiempirical molecular orbital theory without the intermediary of a global or semiglobal fit. All semiempirical methods available in MOPAC, in particular MINDO/3, MNDO, AM1, and PM3, can be called on to calculate the potential, gradient, or Hessian, as required at various steps of the dynamics calculations, and, in addition, the code has flexible options for electronic structure calculations with neglect of diatomic differential overlap and specific reaction parameters (NDDO-SRP). In dual-level mode, MINDO/3, MNDO, AM1, PM3, or NDDO-SRP is used as a lower level to calculate the reaction path, and interpolated corrections to energies and frequencies are added; these corrections are based on higher-level data read from an external file.

  18. Buyer-vendor coordination for fixed lifetime product with quantity discount under finite production rate

    NASA Astrophysics Data System (ADS)

    Zhang, Qinghong; Luo, Jianwen; Duan, Yongrui

    2016-03-01

    Buyer-vendor coordination has been widely addressed; however, the fixed lifetime of the product is seldom considered. In this paper, we study the coordination of an integrated production-inventory system with quantity discount for a fixed lifetime product under finite production rate and deterministic demand. We first derive the buyer's ordering policy and the vendor's production batch size in decentralised and centralised systems. We then compare the two systems and show the non-coordination of the ordering policies and the production batch sizes. To improve the supply chain efficiency, we propose quantity discount contract and prove that the contract can coordinate the buyer-vendor supply chain. Finally, we present analytically tractable solutions and give a numerical example to illustrate the benefits of the proposed quantity discount strategy.

  19. 2014 Guide to Calculating School Improvement Ratings for Alternative Schools and ESE Centers

    ERIC Educational Resources Information Center

    Florida Department of Education, 2014

    2014-01-01

    The purpose of this technical assistance paper is to provide a description of the procedures used to determine school improvement ratings for alternative schools and ESE centers for the most recently completed school year. School improvement ratings are part of Florida's school accountability system, which originated with the Florida Legislature's…

  20. Substrate inhibition and control for high rate biogas production

    SciTech Connect

    Shin, H.S.

    1982-01-01

    This research addresses a critical aspect of the technical feasibility of biogas recovery with poultry manure using anaerobic digestion, namely, inhibition and toxicity factors limiting methane generation under high rate conditions. The research was designed to identify the limiting factors and to examine alternative pretreatment and in situ control methods for the anaerobic digestion of poultry manure as an energy producing system. Biogas production was indicated by the daily gas volume produced per unit digester capacity. Enhanced biogas generation from the anaerobic digester systems using poultry manure was studied in laboratory- and pilot-scale digester operations. It was found that ammonia nitrogen concentration above 4000 mg/l was inhibitory to biogas production. Pretreatment of the manure by elutriation was effective for decreasing inhibitory/toxic conditions. Increased gas production resulted without an indication of serious inhibition by increased volatile acids, indicating a limitation of available carbon sources. For poultry manure digestion, the optimum pH range was 7.1 to 7.6. Annual costs for pretreatment/biogas systems for 10,000, 30,000 and 50,000 birds were estimated and compared with annual surplus energy produced. The economic break-even point was achieved in digesters for greater than 30,000 birds. Capital cost of the digester system was estimated to be $18,300 with annual costs around $4000. It is anticipated that the digester system could be economically applied to smaller farms as energy costs increase.

  1. An Efficient Method to Calculate the Failure Rate of Dynamic Systems with Random Parameters using the Total Probability Theorem

    DTIC Science & Technology

    2015-05-12

    using a vibratory system . Our approach can be easily extended to non-stationary Gaussian input processes. Introduction The response of a vibratory...Page 1 of 9 15IDM-0105 An Efficient Method to Calculate the Failure Rate of Dynamic Systems with Random Parameters using the Total Probability...failure rate of a linear vibratory system with random parameters excited by stationary Gaussian processes. The response of such a system is non

  2. 42 CFR 419.32 - Calculation of prospective payment rates for hospital outpatient services.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... outpatient services furnished in 1999 would have equaled the base expenditure target calculated in § 419.30... inpatient market basket percentage increase applicable under section 1886(b)(3)(B)(iii) of the Act reduced... 1, 2001 and before April 1, 2001, by the hospital inpatient market basket percentage...

  3. 42 CFR 419.32 - Calculation of prospective payment rates for hospital outpatient services.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... outpatient services furnished in 1999 would have equaled the base expenditure target calculated in § 419.30... inpatient market basket percentage increase applicable under section 1886(b)(3)(B)(iii) of the Act reduced... 1, 2001 and before April 1, 2001, by the hospital inpatient market basket percentage...

  4. Equations for calculating orbiter surface erosion and breakage rates in IUS and SSUS SRM exhaust plumes

    NASA Technical Reports Server (NTRS)

    Wilson, S. W.

    1978-01-01

    Equations and coefficients for calculating the flux of solid particles in the exhaust plumes of the interim upper stage and SSUS solid rocket motors (SRM) are considered. Modifications required to account for the independent motions of the orbiter and the SRM, such as will result during an on-orbit SRM firing are described.

  5. Detailed microscopic calculation of stellar electron and positron capture rates on 24Mg for O+Ne+Mg core simulations

    NASA Astrophysics Data System (ADS)

    Nabi, Jameel-Un

    2008-09-01

    A few white dwarfs, located in binary systems, may acquire sufficiently high mass-accretion rates resulting in the burning of carbon and oxygen under nondegenerate conditions forming an O+Ne+Mg core. These O+Ne+Mg cores are gravitationally less bound than more massive progenitor stars and can release more energy due to the nuclear burning. They are also amongst the probable candidates for low entropy r-process sites. Recent observations of subluminous Type II-P supernovae (e.g. 2005cs, 2003gd, 1999br and 1997D) were able to rekindle the interest in 8-10 Modot which develop O+Ne+Mg cores. Microscopic calculations of capture rates on 24Mg, which may contribute significantly to the collapse of O+Ne+Mg cores, using the shell model and the proton-neutron quasiparticle random-phase approximation (pn-QRPA) theory, were performed earlier and comparisons made. Simulators, however, may require these capture rates on a fine scale. For the first time, a detailed microscopic calculation of the electron and positron capture rates on 24Mg on an extensive temperature-density scale is presented here. This type of scale is more appropriate for interpolation purposes and of greater utility for simulation codes. The calculations are done using the pn-QRPA theory using a separable interaction. The deformation parameter, believed to be a key parameter in QRPA calculations, is adopted from experimental data to increase the reliability of the QRPA results further. The resulting calculated rates are up to a factor of 14 or more enhanced as compared to shell model rates and may lead to some interesting scenarios for core collapse simulators.

  6. Regional Contrasts of the Warming Rate over Land Significantly Depend on the Calculation Methods of Mean Air Temperature.

    PubMed

    Wang, Kaicun; Zhou, Chunlüe

    2015-07-22

    Global analyses of surface mean air temperature (T(m)) are key datasets for climate change studies and provide fundamental evidences for global warming. However, the causes of regional contrasts in the warming rate revealed by such datasets, i.e., enhanced warming rates over the northern high latitudes and the "warming hole" over the central U.S., are still under debate. Here we show these regional contrasts depend on the calculation methods of T(m). Existing global analyses calculate T(m) from daily minimum and maximum temperatures (T2). We found that T2 has a significant standard deviation error of 0.23 °C/decade in depicting the regional warming rate from 2000 to 2013 but can be reduced by two-thirds using T(m) calculated from observations at four specific times (T4), which samples diurnal cycle of land surface air temperature more often. From 1973 to 1997, compared with T4, T2 significantly underestimated the warming rate over the central U.S. and overestimated the warming rate over the northern high latitudes. The ratio of the warming rate over China to that over the U.S. reduces from 2.3 by T2 to 1.4 by T4. This study shows that the studies of regional warming can be substantially improved by T4 instead of T2.

  7. Numerical calculation of protein-ligand binding rates through solution of the Smoluchowski equation using smoothed particle hydrodynamics

    DOE PAGES

    Pan, Wenxiao; Daily, Michael; Baker, Nathan A.

    2015-05-07

    Background: The calculation of diffusion-controlled ligand binding rates is important for understanding enzyme mechanisms as well as designing enzyme inhibitors. Methods: We demonstrate the accuracy and effectiveness of a Lagrangian particle-based method, smoothed particle hydrodynamics (SPH), to study diffusion in biomolecular systems by numerically solving the time-dependent Smoluchowski equation for continuum diffusion. Unlike previous studies, a reactive Robin boundary condition (BC), rather than the absolute absorbing (Dirichlet) BC, is considered on the reactive boundaries. This new BC treatment allows for the analysis of enzymes with “imperfect” reaction rates. Results: The numerical method is first verified in simple systems and thenmore » applied to the calculation of ligand binding to a mouse acetylcholinesterase (mAChE) monomer. Rates for inhibitor binding to mAChE are calculated at various ionic strengths and compared with experiment and other numerical methods. We find that imposition of the Robin BC improves agreement between calculated and experimental reaction rates. Conclusions: Although this initial application focuses on a single monomer system, our new method provides a framework to explore broader applications of SPH in larger-scale biomolecular complexes by taking advantage of its Lagrangian particle-based nature.« less

  8. 77 FR 18256 - Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-27

    ... SECURITY U.S. Customs and Border Protection Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on Customs Duties AGENCY: Customs and Border Protection, Department of... refunds (overpayments) of customs duties. For the calendar quarter beginning April 1, 2012, the...

  9. 77 FR 2308 - Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-01-17

    ... SECURITY U.S. Customs and Border Protection Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on Customs Duties AGENCY: U.S. Customs and Border Protection, Department of... refunds (overpayments) of customs duties. For the calendar quarter beginning January 1, 2012, the...

  10. 78 FR 63238 - Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-10-23

    ... SECURITY U.S. Customs and Border Protection Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on Customs Duties AGENCY: U.S. Customs and Border Protection, Department of... refunds (overpayments) of customs duties. For the calendar quarter beginning October 1, 2013, the...

  11. 75 FR 59279 - Quarterly IRS Interest Rates Used In Calculating Interest On Overdue Accounts and Refunds On...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-27

    ... SECURITY U.S. Customs and Border Protection Quarterly IRS Interest Rates Used In Calculating Interest On Overdue Accounts and Refunds On Customs Duties AGENCY: Customs and Border Protection, Department of... refunds (overpayments) of customs duties. For the calendar quarter beginning October 1, 2010, the...

  12. 78 FR 37839 - Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-06-24

    ... SECURITY U.S. Customs and Border Protection Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on Customs Duties AGENCY: U.S. Customs and Border Protection, Department of... refunds (overpayments) of customs duties. For the calendar quarter beginning July 1, 2013, the...

  13. 75 FR 419 - Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-05

    ... Doc No: E9-31353] DEPARTMENT OF HOMELAND SECURITY U.S. Customs and Border Protection Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on Customs Duties AGENCY: Customs and Border Protection, Department of Homeland Security. ACTION: General notice. SUMMARY:...

  14. 76 FR 41283 - Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-07-13

    ... SECURITY U.S. Customs and Border Protection Quarterly IRS Interest Rates Used in Calculating Interest on Overdue Accounts and Refunds on Customs Duties AGENCY: Customs and Border Protection, Department of... refunds (overpayments) of customs duties. For the calendar quarter beginning July 1, 2011, the...

  15. Multiple-estimate Monte Carlo calculation of the dose rate constant for a cesium-131 interstitial brachytherapy seed

    SciTech Connect

    Wittman, Richard S.; Fisher, Darrell R.

    2007-01-03

    The purpose of this study was to calculate a more accurate dose rate constant for the Cs-131 (model CS-1, IsoRay Medical, Inc., Richland, Washington) interstitial brachytherapy seed. Previous measurements of the dose rate constant for this seed have been reported by others with incongruity. Recent direct measurements by thermoluminescence dosimetry and by gamma-ray spectroscopy were about 15 percent greater than earlier thermoluminescence dosimetry measurements. Therefore, we set about to calculate independent values by a Monte Carlo approach that combined three estimates as a consistency check, and to quantify the computational uncertainty. The calculated dose rate constant for the Cs-131 seed was 1.040 cGy h^{-1} U^{-1} for an ionization chamber model and 1.032 cGy h^{-1} U^{-1} for a circular ring model. A formal value of 2.2% uncertainty was calculated for both values. The range of our multi-estimate values were from 1.032 cGy h^{-1} U^{-1} to 1.061 cGy h^{-1} U^{-1}. We also modeled three I-125 seeds with known dose rate constants to test the accuracy of this study's approach.

  16. Numerical calculation of protein-ligand binding rates through solution of the Smoluchowski equation using smoothed particle hydrodynamics

    SciTech Connect

    Pan, Wenxiao; Daily, Michael; Baker, Nathan A.

    2015-05-07

    Background: The calculation of diffusion-controlled ligand binding rates is important for understanding enzyme mechanisms as well as designing enzyme inhibitors. Methods: We demonstrate the accuracy and effectiveness of a Lagrangian particle-based method, smoothed particle hydrodynamics (SPH), to study diffusion in biomolecular systems by numerically solving the time-dependent Smoluchowski equation for continuum diffusion. Unlike previous studies, a reactive Robin boundary condition (BC), rather than the absolute absorbing (Dirichlet) BC, is considered on the reactive boundaries. This new BC treatment allows for the analysis of enzymes with “imperfect” reaction rates. Results: The numerical method is first verified in simple systems and then applied to the calculation of ligand binding to a mouse acetylcholinesterase (mAChE) monomer. Rates for inhibitor binding to mAChE are calculated at various ionic strengths and compared with experiment and other numerical methods. We find that imposition of the Robin BC improves agreement between calculated and experimental reaction rates. Conclusions: Although this initial application focuses on a single monomer system, our new method provides a framework to explore broader applications of SPH in larger-scale biomolecular complexes by taking advantage of its Lagrangian particle-based nature.

  17. Calculations of rate constants for the three-body recombination of H2 in the presence of H2

    NASA Technical Reports Server (NTRS)

    Schwenke, David W.

    1988-01-01

    A new global potential energy hypersurface for H2 + H2 is constructed and quasiclassical trajectory calculations performed using the resonance complex theory and energy transfer mechanism to estimate the rate of three body recombination over the temperature range 100 to 5000 K. The new potential is a faithful representation of ab initio electron structure calculations, is unchanged under the operation of exchanging H atoms, and reproduces the accurate H3 potential as one H atom is pulled away. Included in the fitting procedure are geometries expected to be important when one H2 is near or above the dissociation limit. The dynamics calculations explicitly include the motion of all four atoms and are performed efficiently using a vectorized variable-stepsize integrator. The predicted rate constants are approximately a factor of two smaller than experimental estimates over a broad temperature range.

  18. Program for PET image alignment: Effects on calculated differences in cerebral metabolic rates for glucose

    SciTech Connect

    Phillips, R.L.; London, E.D.; Links, J.M.; Cascella, N.G. )

    1990-12-01

    A program was developed to align positron emission tomography images from multiple studies on the same subject. The program allowed alignment of two images with a fineness of one-tenth the width of a pixel. The indications and effects of misalignment were assessed in eight subjects from a placebo-controlled double-blind crossover study on the effects of cocaine on regional cerebral metabolic rates for glucose. Visual examination of a difference image provided a sensitive and accurate tool for assessing image alignment. Image alignment within 2.8 mm was essential to reduce variability of measured cerebral metabolic rates for glucose. Misalignment by this amount introduced errors on the order of 20% in the computed metabolic rate for glucose. These errors propagate to the difference between metabolic rates for a subject measured in basal versus perturbed states.

  19. Comparisons of Neutron Cross Sections and Isotopic Composition Calculations for Fission-Product Evaluations

    NASA Astrophysics Data System (ADS)

    Kim, Do Heon; Gil, Choong-Sup; Chang, Jonghwa; Lee, Yong-Deok

    2005-05-01

    The neutron absorption cross sections for 18 fission products evaluated within the framework of the KAERI (Korea Atomic Energy Research Institute)-BNL (Brookhaven National Laboratory) international collaboration have been compared with ENDF/B-VI.7. Also, the influence of the new evaluations on the isotopic composition calculations of the fission products has been estimated through the OECD/NEA burnup credit criticality benchmarks (Phase 1B) and the LWR/Pu recycling benchmarks. These calculations were performed by WIMSD-5B with the 69-group libraries prepared from three evaluated nuclear data libraries: ENDF/B-VI.7, ENDF/B-VI.8 including the new evaluations in the resonance region covering the thermal region, and the expected ENDF/B-VII including those in the upper resonance region up to 20 MeV. For Xe-131, the composition calculated with ENDF/B-VI.8 shows a maximum difference of 5.02% compared to ENDF/B-VI.7. However, the isotopic compositions of all the fission products calculated with the expected ENDF/B-VII show no differences when compared to ENDF/B-VI.7 for the thermal reactor benchmark cases.

  20. Dose Rate Calculations from Radioactive Vascular Stents: DPK Versus Exact MC Approach

    NASA Astrophysics Data System (ADS)

    Gorodkov, S.; Möslang, A.; Vladimirov, P.

    Vascular stents activated with radioactive isotopes are planned to be used in clinical practice to prevent restenosis in human coronary arteries after balloon angioplasty. Medical stents are cylindrical meshes and their complex geometry is usually treated for energy dose calculation with approximate dose point kernel (DPK) approach. The important point missed in the DPK approach is the absence of the stent material and, hence, the absence of energy absorption inside the stent. We have performed a comparison between DPK and exact Monte Carlo calculations for some simplified stent models. It appears that DPK approximation significantly overestimates pike dose values especially for the case of γ-emitting sources. We suggest DPK kernel normalization, which minimizes the difference at relatively far distances, while significant discrepancies near the stent surface still remain.

  1. Production rates of terrestrial in-situ-produced cosmogenic nuclides

    SciTech Connect

    Reedy, R.C.; Tuniz, C.; Fink, D.

    1993-12-31

    Production rates of cosmogenic nuclides made in situ in terrestrial samples and how they are applied to the interpretation of measured radionuclide concentrations were discussed at a one-day Workshop held 2 October 1993 in Sydney, Australia. The status of terrestrial in-situ studies using the long-lived radionuclides {sup 10}Be, {sup 14}C, {sup 26}Al, {sup 36}Cl, and {sup 41}Ca and of various modeling and related studies were presented. The relative uncertainties in the various factors that go into the interpretation of these terrestrial in-situ cosmogenic nuclides were discussed. The magnitudes of the errors for these factors were estimated and none dominated the final uncertainty.

  2. Changes in atmospheric composition inferred from ionospheric production rates

    NASA Technical Reports Server (NTRS)

    Titheridge, J. E.

    1974-01-01

    Changes in the total electron content of the ionosphere near sunrise are used to determine the integrated production rate in the ionosphere (Q) from 1965 to 1971 at latitudes of 34S, 20N, and 34N. The observed regular semiannual variation in Q through a range of 1:3:1 is interpreted as an increase in the ratio O/N2 (relative densities) near the equinoxes. It follows that there is a worldwide semiannual variation in atmospheric composition, with the above ratio maximum just after the equinoxes. There is a large seasonal variation in the Northern hemisphere with a maximum in mid-summer. This effect is absent in the Southern hemisphere. At all times except solar maximum in the Northern hemisphere there is a global asymmetry. The ratio O/N2 is about three times as large in the Northern hemisphere. The overall mechanism appears to be N2 absorption.

  3. Structure-activity correlations for organophosphorus ester anticholinesterases. Part 2: CNDO/2 calculations applied to ester hydrolysis rates

    NASA Technical Reports Server (NTRS)

    Johnson, H.; Kenley, R. A.; Rynard, C.; Golub, M. A.

    1984-01-01

    Quantitative structure-activity relationships are presented for the hydrolysis of organophosphorus esters, RR'P(O)X, where R and R' are alkyl and/or alkoxy groups and X is fluorine, chlorine or a phenoxy group. CNDO/2 calculations provide values for molecular parameters that correlate with alkaline hydrolysis rates. For each subset of esters with the same leaving group, X, the CNDO-derived net atomic charge at the central phosphorus atom correlates well with the alkaline hydrolysis rate constants. For the whole set of esters with different leaving groups, equations are derived that relate charge, orbital energy and bond order to the hydrolysis rate constants.

  4. Mcnp-Based Methodology to Calculate Helium Production in Bwr Shrouds

    NASA Astrophysics Data System (ADS)

    Sitaraman, S.; Chiang, R.-T.; Oliver, B. M.

    2003-06-01

    A three-dimensional computational method based on Monte Carlo radiation transport techniques was developed to calculate thermal and fast neutron fields in the downcomer region of a Boiling Water Reactor (BWR). This methodology was validated using measured data obtained from an operating BWR. The helium production was measured in stainless steel at locations near the shroud and compared with values from the Monte Carlo calculations. The methodology produced results that were in agreement with measurements, thereby providing a useful tool for the determination of helium levels in shroud components.

  5. Associated Higgs-W-boson production at hadron colliders: a fully exclusive QCD calculation at NNLO.

    PubMed

    Ferrera, Giancarlo; Grazzini, Massimiliano; Tramontano, Francesco

    2011-10-07

    We consider QCD radiative corrections to standard model Higgs-boson production in association with a W boson in hadron collisions. We present a fully exclusive calculation up to next-to-next-to-leading order (NNLO) in QCD perturbation theory. To perform this NNLO computation, we use a recently proposed version of the subtraction formalism. Our calculation includes finite-width effects, the leptonic decay of the W boson with its spin correlations, and the decay of the Higgs boson into a bb pair. We present selected numerical results at the Tevatron and the LHC.

  6. Aftershock decay, productivity, and stress rates in Hawaii: Indicators of temperature and stress from magma sources

    USGS Publications Warehouse

    Klein, Fred W.; Wright, Tom; Nakata, Jennifer

    2006-01-01

    We examined dozens of aftershock sequences in Hawaii in terms of Gutenberg-Richter and modified Omori law parameters. We studied p, the rate of aftershock decay; Ap, the aftershock productivity, defined as the observed divided by the expected number of aftershocks; and c, the time delay when aftershock rates begin to fall. We found that for earthquakes shallower than 20 km, p values >1.2 are near active magma centers. We associate this high decay rate with higher temperatures and faster stress relaxation near magma reservoirs. Deep earthquakes near Kilauea's inferred magma transport path show a range of p values, suggesting the absence of a large, deep magma reservoir. Aftershock productivity is >4.0 for flank earthquakes known to be triggered by intrusions but is normal (0.25 to 4.0) for isolated main shocks. We infer that continuing, post-main shock stress from the intrusion adds to the main shock's stress step and causes higher Ap. High Ap in other zones suggests less obvious intrusions and pulsing magma pressure near Kilauea's feeding conduit. We calculate stress rates and stress rate changes from pre-main shock and aftershock rates. Stress rate increased after many intrusions but decreased after large M7–8 earthquakes. Stress rates are highest in the seismically active volcano flanks and lowest in areas far from volcanic centers. We found sequences triggered by intrusions tend to have high Ap, high (>0.10 day) c values, a stress rate increase, and sometimes a peak in aftershock rate hours after the main shock. We interpret these values as indicating continuing intrusive stress after the main shock.

  7. Products cooked in preheated versus non-preheated ovens. Baking times, calculated energy consumption, and product quality compared.

    PubMed

    Odland, D; Davis, C

    1982-08-01

    Plain muffins, yellow cake, baked custard, apple pie, tuna casserole, frozen tuna casserole, cheese soufflé, and meat loaf were baked in preheated and non-preheated standard gas, continuous-clean gas, standard electric, and self-cleaning electric ovens. Products generally required 5 min. or less extra baking time when cooked in non-preheated rather than in preheated ovens. The variability in baking times often was less between preheated and non-preheated ovens than among oven types. Calculated energy consumption values showed that usually less energy was required to bake products in non-preheated than in preheated ovens; savings averaged about 10 percent. Few significant differences were found in physical measurements or eating quality either between preheated and non-preheated ovens or among oven types. Overall, for the products tested, findings confirmed that preheating the oven is not essential for good product quality and, therefore, is an unnecessary use of energy.

  8. Enhancing microalgal photosynthesis and productivity in wastewater treatment high rate algal ponds for biofuel production.

    PubMed

    Sutherland, Donna L; Howard-Williams, Clive; Turnbull, Matthew H; Broady, Paul A; Craggs, Rupert J

    2015-05-01

    With microalgal biofuels currently receiving much attention, there has been renewed interest in the combined use of high rate algal ponds (HRAP) for wastewater treatment and biofuel production. This combined use of HRAPs is considered to be an economically feasible option for biofuel production, however, increased microalgal productivity and nutrient removal together with reduced capital costs are needed before it can be commercially viable. Despite HRAPs being an established technology, microalgal photosynthesis and productivity is still limited in these ponds and is well below the theoretical maximum. This paper critically evaluates the parameters that limit microalgal light absorption and photosynthesis in wastewater HRAPs and examines biological, chemical and physical options for improving light absorption and utilisation, with the view of enhancing biomass production and nutrient removal.

  9. 78 FR 39784 - International Product Change-Priority Mail International Regional Rate Boxes-Non-Published Rates

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-02

    ... Product Change--Priority Mail International Regional Rate Boxes--Non-Published Rates AGENCY: Postal... with the Postal Regulatory Commission to add Priority Mail International Regional Rate Boxes--Non... the Postal Regulatory Commission: (1) A request to add Priority Mail International Regional Rate...

  10. 50 CFR Table 3 to Part 679 - Product Recovery Rates for Groundfish Species and Conversion Rates for Pacific Halibut

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 50 Wildlife and Fisheries 9 2010-10-01 2010-10-01 false Product Recovery Rates for Groundfish Species and Conversion Rates for Pacific Halibut 3 Table 3 to Part 679 Wildlife and Fisheries FISHERY... Rates for Groundfish Species and Conversion Rates for Pacific Halibut ER28JA02.074 ER10JY02.000...

  11. 50 CFR Table 3 to Part 679 - Product Recovery Rates for Groundfish Species and Conversion Rates for Pacific Halibut

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 50 Wildlife and Fisheries 11 2011-10-01 2011-10-01 false Product Recovery Rates for Groundfish Species and Conversion Rates for Pacific Halibut 3 Table 3 to Part 679 Wildlife and Fisheries FISHERY... Rates for Groundfish Species and Conversion Rates for Pacific Halibut ER11JY11.007 ER11JY11.008...

  12. Recent developments in cosmogenic nuclide production rate scaling

    NASA Astrophysics Data System (ADS)

    Lifton, N. A.

    2013-12-01

    A new cosmogenic nuclide production rate scaling model based on analytical fits to Monte Carlo simulations of atmospheric cosmic ray flux spectra (both of which agree well with measured spectra) enables identification and quantification of the biases in previously published models (Lifton, N., Sato, T., Dunai, T., in review, Earth and Planet. Sci. Lett.). Scaling predictions derived from the new model (termed LSD) suggest two potential sources of bias in the previous models: different energy responses of the secondary neutron detectors used in developing the models, and different geomagnetic parameterizations. In addition, the particle flux spectra generated by the LSD model allow one to generate nuclide-specific scaling factors that reflect the influences of the flux energy distribution and the relevant excitation functions (probability of nuclide production in a given nuclear reaction as a function of energy). Resulting scaling factors indicate 3He shows the strongest positive deviation from the flux-based scaling, while 14C exhibits a negative deviation. These results are consistent with previous studies showing an increasing 3He/10Be ratio with altitude in the Himalayas, but with a much lower magnitude for the effect. Furthermore, the new model provides a flexible framework for exploring the implications of future advances in model inputs. For example, the effects of recently updated paleomagnetic models (e.g. Korte et al., 2011, Earth and Planet Sci. Lett. 312, 497-505) on scaling predictions will also be presented.

  13. Calculation on cosmic-ray muon exposure rate in non-walled concrete buildings.

    PubMed

    Fujitaka, K; Abe, S

    1984-06-01

    Computer simulations on the exposure indoors from cosmic ray muons were practiced in the framework of non-scattering and non-cascade assumptions. The model buildings were two-dimensional, rectangular, and were made of a normal concrete. A stratified structure was assumed in each building, where no mezzanine was considered. Walls were not taken into account yet. The distributions of the exposure rates in 26-story buildings were illustrated in contour maps for various sets of parameters. All of them gave basically archlike patterns. Analyses of the results showed that the exposure rate is affected most largely by the floor board thickness. The ceiling height would be an insignificant factor for short buildings. The min/max ratio of the muon exposure rate in a moderate size building was estimated to be more than 0.7.

  14. Sensitivity study of forecasted aftershock seismicity based on Coulomb stress calculation and rate- and state-dependent frictional response

    NASA Astrophysics Data System (ADS)

    Cocco, M.; Hainzl, S.; Catalli, F.; Enescu, B.; Lombardi, A. M.; Woessner, J.

    2010-05-01

    We use the Dieterich (1994) physics-based approach to simulate the spatiotemporal evolution of seismicity caused by stress changes applied to an infinite population of nucleating patches modeled through a rate- and state-dependent friction law. According to this model, seismicity rate changes depend on the amplitude of stress perturbation, the physical constitutive properties of faults (represented by the parameter Aσ), the stressing rate, and the background seismicity rate of the study area. In order to apply this model in a predictive manner, we need to understand the impact of physical model parameters and the correlations between them. First, we discuss different definitions of the reference seismicity rate and show their impact on the computed rate of earthquake production for the 1992 Landers earthquake sequence as a case study. Furthermore, we demonstrate that all model parameters are strongly correlated for physical and statistical reasons. We discuss this correlation, emphasizing that the estimations of the background seismicity rate, stressing rate, and Aσ are strongly correlated to reproduce the observed aftershock productivity. Our analytically derived relation demonstrates the impact of these model parameters on the Omori-like aftershock decay: the c value and the productivity of the Omori law, implying a p value smaller than or equal to 1. Finally, we discuss an optimal strategy to constrain model parameters for near-real-time forecasts.

  15. Global bioenergy capacity as constrained by observed biospheric productivity rates

    NASA Astrophysics Data System (ADS)

    Smith, W. K.; Zhao, M.; Running, S. W.

    2011-12-01

    Virtually all global energy forecasts include an expectation that bioenergy will be a substantial energy source for the future. Multiple current estimates of global bioenergy potential (GBP) range from 500-1,500 EJ yr-1 or 100-300% of 2009 global primary energy consumption (GPEC09), suggesting bioenergy could conceivably replace fossil fuels entirely. However, these estimates are based on extrapolation of plot-level production rates which largely neglect complex global climatic and land-use constraints. We estimated GBP using satellite-derived, observed global primary productivity data from 2000-2006, which integrates global climate data and detects seasonal vegetation dynamics. Land-use constraints were then applied to account for current crop and forestry harvest requirements, human-controlled pasturelands, remote regions, and nature conservation areas. We show GBP is limited to 52-248 EJ yr-1 or 10-49% of GPEC09, a range lower than many current GBP estimates by a factor of four. Even attaining the low-end of this range requires utilization of all harvest residues over 31 million km2 (Mkm2), while the high-end requires additional harvest over 41 Mkm2, an area roughly three times current global cropland extent. Although, exploitation of pasture and remote land could significantly contribute to GBP, the availability of these land areas remains controversial due to critical concerns regarding indirect land-use change and carbon debt. Future energy policy is of unparalleled importance to humanity, and our results are critical in estimating quantitative limitations on the overall potential for global bioenergy production.

  16. A real-time path rating calculation tool powered by HPC

    SciTech Connect

    2016-06-09

    If transmission path ratings are determined in real time and optimized control methods can be implemented, congestion problems can be more effectively managed using the existing transmission assets, reducing congestion costs, avoiding capital expenditures for new physical assets, increasing revenues from the existing system, and maintaining reliability. In just one illustrative case, a BPA study has shown that a 1000-MW rating increase for a transmission path generates $15M in annual revenue, even if only 25% of the increased margin can be tapped for just 25% of the year.

  17. Shell-model calculations of beta-decay rates for s- and r-process nucleosyntheses

    NASA Astrophysics Data System (ADS)

    Takahashi, K.; Mathews, G. J.; Bloom, S. D.

    1985-10-01

    Examples of large-basis shell-model calculations of Gamow-Teller (BETA)-decay properties of specific interest in the astrophysical s- and r- processes are presented. Numerical results are given for: (1) the GT-matrix elements for the excited state decays of the unstable s-process nucleus Tc-99; and (2) the GT-strength function for the neutron-rich nucleus Cd-130, which lies on the r-process path. The results are discussed in conjunction with the astrophysics problems.

  18. Synechococcus production and grazing loss rates in nearshore tropical waters.

    PubMed

    Heng, Pei Li; Lim, Joon Hai; Lee, Choon Weng

    2017-03-01

    Temporal variation of Synechococcus, its production (μ) and grazing loss (g) rates were studied for 2 years at nearshore stations, i.e. Port Dickson and Port Klang along the Straits of Malacca. Synechococcus abundance at Port Dickson (0.3-2.3 × 10(5) cell ml(-1)) was always higher than at Port Klang (0.3-7.1 × 10(4) cell ml(-1)) (p < 0.001). μ ranged up to 0.98 day(-1) (0.51 ± 0.29 day(-1)), while g ranged from 0.02 to 0.31 day(-1) (0.15 ± 0.07 day(-1)) at Port Klang. At Port Dickson, μ and g averaged 0.47 ± 0.13 day(-1) (0.29-0.82 day(-1)) and 0.31 ± 0.14 day(-1) (0.13-0.63 day(-1)), respectively. Synechococcus abundance did not correlate with temperature (p > 0.25), but nutrient and light availability were important factors for their distribution. The relationship was modelled as log Synechococcus = 0.37Secchi - 0.01DIN + 4.52 where light availability (as Secchi disc depth) was a more important determinant. From a two-factorial experiment, nutrients were not significant for Synechococcus growth as in situ nutrient concentrations exceeded the threshold for saturated growth. However, light availability was important and elevated Synechococcus growth rates especially at Port Dickson (F = 5.94, p < 0.05). As for grazing loss rates, they were independent of either nutrients or light intensity (p > 0.30). In nearshore tropical waters, an estimated 69 % of Synechococcus production could be grazed.

  19. Efficient calculation of low energy statistical rates for gas phase dissociation using umbrella sampling

    NASA Astrophysics Data System (ADS)

    Mella, Massimo

    2006-03-01

    Monte Carlo (MC) simulations can be used to compute microcanonical statistical rates of gas phase dissociation reactions. Unfortunately, the MC approach may suffer from a slow convergence and large statistical errors for energies just above the dissociation threshold. In this work, umbrella sampling is proposed as a device to reduce the statistical error of MC rate constants. The method is tested by computing the classical dissociation rate for the reaction [H5O2+]*→H2O+H3O+ over the range of internal energy 38rate constants and classical Rice-Ramsperberg-Kassel harmonic theory shows that anharmonicity plays an important role in the dissociation process of the Zundel cation (H5O2+) at all energies.

  20. 42 CFR 412.624 - Methodology for calculating the Federal prospective payment rates.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... interrupted patient stay is to receive inpatient acute care hospital services, an amount based on the... payment rates. 412.624 Section 412.624 Public Health CENTERS FOR MEDICARE & MEDICAID SERVICES, DEPARTMENT OF HEALTH AND HUMAN SERVICES MEDICARE PROGRAM PROSPECTIVE PAYMENT SYSTEMS FOR INPATIENT...

  1. Should thermostatted ring polymer molecular dynamics be used to calculate thermal reaction rates?

    SciTech Connect

    Hele, Timothy J. H.; Suleimanov, Yury V.

    2015-08-21

    We apply Thermostatted Ring Polymer Molecular Dynamics (TRPMD), a recently proposed approximate quantum dynamics method, to the computation of thermal reaction rates. Its short-time transition-state theory limit is identical to rigorous quantum transition-state theory, and we find that its long-time limit is independent of the location of the dividing surface. TRPMD rate theory is then applied to one-dimensional model systems, the atom-diatom bimolecular reactions H + H{sub 2}, D + MuH, and F + H{sub 2}, and the prototypical polyatomic reaction H + CH{sub 4}. Above the crossover temperature, the TRPMD rate is virtually invariant to the strength of the friction applied to the internal ring-polymer normal modes, and beneath the crossover temperature the TRPMD rate generally decreases with increasing friction, in agreement with the predictions of Kramers theory. We therefore find that TRPMD is approximately equal to, or less accurate than, ring polymer molecular dynamics for symmetric reactions, and for certain asymmetric systems and friction parameters closer to the quantum result, providing a basis for further assessment of the accuracy of this method.

  2. Improved Ionospheric Electrodynamic Models and Application to Calculating Joule Heating Rates

    NASA Technical Reports Server (NTRS)

    Weimer, D. R.

    2004-01-01

    Improved techniques have been developed for empirical modeling of the high-latitude electric potentials and magnetic field aligned currents (FAC) as a function of the solar wind parameters. The FAC model is constructed using scalar magnetic Euler potentials, and functions as a twin to the electric potential model. The improved models have more accurate field values as well as more accurate boundary locations. Non-linear saturation effects in the solar wind-magnetosphere coupling are also better reproduced. The models are constructed using a hybrid technique, which has spherical harmonic functions only within a small area at the pole. At lower latitudes the potentials are constructed from multiple Fourier series functions of longitude, at discrete latitudinal steps. It is shown that the two models can be used together in order to calculate the total Poynting flux and Joule heating in the ionosphere. An additional model of the ionospheric conductivity is not required in order to obtain the ionospheric currents and Joule heating, as the conductivity variations as a function of the solar inclination are implicitly contained within the FAC model's data. The models outputs are shown for various input conditions, as well as compared with satellite measurements. The calculations of the total Joule heating are compared with results obtained by the inversion of ground-based magnetometer measurements. Like their predecessors, these empirical models should continue to be a useful research and forecast tools.

  3. Al-26-production rates and Mn-53/Al-26 production rate ratios in nonantarctic chondrites and their application to bombardment histories

    NASA Astrophysics Data System (ADS)

    Herpers, U.; Englert, P.

    1983-11-01

    The long-lived spallogenic radionuclides Al-26 and Mn-53 were systematically studied in a large number of nonantarctic meteorites by nondestructive gamma-gamma-coincidence technique and neutron activation, respectively. From the Al-26-activities normalized to the main target element, silicon, an average production rate of 298 + or - 55 (dpm/kg Si/equ/) was derived. Baed on 15 chondrites with exposure ages equal to or greater than 12,000,000 a and depth profiles of Dhurmsala and Keyes, an average production rate ratio (Mn-53/Al-26)(prod) = 1.48 + or - 0.15 (dpm/kg Fe / dpm/kg Si/equ/) was calculated, which seems to be depth-independent for meteorites with preatmospheric radii R less than 35 cm. Mn-53/Al-26-radiation ages for 29 stones with short exposure ages were determined. A comparison of the results with the respective Mn-53 and Ne-21-exposure ages generally shows a good agreement. The cosmic ray bombardment age scale covered by this method is the range for T(rad) from 1,000,000 to 10,000,000 a.

  4. Application of Origen2.1 in the decay photon spectrum calculation of spallation products

    NASA Astrophysics Data System (ADS)

    Hong, Shuang; Yang, Yong-Wei; Xu, Hu-Shan; Meng, Hai-Yan; Zhang, Lu; Liu, Zhao-Qing; Gao, Yu-Cui; Chen, Kang

    2016-11-01

    Origen2.1 is a widely used computer code for calculating the burnup, decay, and processing of radioactive materials. However, the nuclide library of Origen2.1 is used for existing reactors like pressurized water reactors. To calculate the photon spectrum released by the decay of spallation products, we have made specific libraries for the ADS tungsten spallation target, based on the results given by the FLUKA Monte Carlo code. All the data used to make the Origen2.1 libraries are obtained from Nuclear structure & decay Data (NuDat2.6). The accumulated activity of spallation products and the contribution of nuclides to photon emission are given in this paper. Supported by Strategic Priority Research Program of Chinese Academy of Sciences (XDA03030102)

  5. Calculation of energy deposition, photon and neutron production in proton therapy of thyroid gland using MCNPX.

    PubMed

    Mowlavi, Ali Asghar; Fornasie, Maria Rosa; de Denaro, Mario

    2011-01-01

    In this study, the MCNPX code has been used to simulate a proton therapy in thyroid gland, in order to calculate the proton energy deposition in the target region. As well as, we have calculated the photon and neutron production spectra due to proton interactions with the tissue. We have considered all the layers of tissue, from the skin to the thyroid gland, and an incident high energy pencil proton beam. The results of the simulation show that the best proton energy interval, to cover completely the thyroid tissue, is from 42 to 54 MeV, assuming that the thyroid gland has a 14 mm thickness and is located 11.2mm under the skin surface. The most percentage of deposited energy (78%) is related to the 54 MeV proton energy beam. Total photon and neutron production are linear and polynomial second order functions of the proton energy, respectively.

  6. Comparison of calculated and experimental thermal attachment rate constants for SF6 in the temperature range 200-600 K

    NASA Technical Reports Server (NTRS)

    Orient, O. J.; Chutjian, A.

    1986-01-01

    Electron-attachment cross sections are calcualted for the process e(-) + SF6 yields SF6(-) in the energy range 1-200 meV. An electron scattering approximation is used in which diatomiclike potential energy curves near the equilibrium SF6 ground state are constructed from recent spectroscopic data. Excellent agreement is found over the entire energy range with experimental attachment cross sections at a temperature of 300 K for s-wave (l = 0) scattering. The same calculation, with appropriate adjustment of the thermal populations, is used to calculate attachment rate constants in the range 50-600 K for both s- and p-wave scattering.

  7. Automated Discovery of New Chemical Reactions and Accurate Calculation of Their Rates

    DTIC Science & Technology

    2015-06-02

    either experimentally or by using quantum chemistry). 15.  SUBJECT TERMS combustion chemistry, kinetics, reaction pathways 16.  SECURITY CLASSIFICATION...serendipity (either experimentally or by using quantum chemistry). In this project we develop a much more systematic approach, using high...performance computing to search for reactions connecting a specified reactant to each possible product, and using quantum chemistry to determine the reaction

  8. Calculation of laminar heating rates on three-dimensional configurations using the axisymmetric analogue

    NASA Technical Reports Server (NTRS)

    Hamilton, H. H., II

    1980-01-01

    A theoretical method was developed for computing approximate laminar heating rates on three dimensional configurations at angle of attack. The method is based on the axisymmetric analogue which is used to reduce the three dimensional boundary layer equations along surface streamlines to an equivalent axisymmetric form by using the metric coefficient which describes streamline divergence (or convergence). The method was coupled with a three dimensional inviscid flow field program for computing surface streamline paths, metric coefficients, and boundary layer edge conditions.

  9. The calculation of the thermal rate coefficient by a method combining classical and quantum mechanics

    NASA Astrophysics Data System (ADS)

    Wahnström, Göran; Carmeli, Benny; Metiu, Horia

    1988-02-01

    We propose and test a method for computing flux-flux correlation functions (and thermal rate coefficients) which divides the degrees of freedom in two groups, one treated classically and the other quantum mechanically. The method is tested by applying it to a simple model for which we can also obtain exact results. The approximate method gives good results if the mass associated with the classical degrees of freedom exceeds 16 a.u.

  10. Calculation of Zonal Winds using Accelerometer and Rate Data from Mars Global Surveyor

    NASA Technical Reports Server (NTRS)

    Baird, Darren T.; Tolson, Robert; Bougher, Stephen; Steers, Brian

    2006-01-01

    The Mars Global Surveyor spacecraft was initially placed into a high eccentricity, nearly polar orbit about Mars with a 45-hour period. To accomplish the science objectives of the mission, a 2-hour, circular orbit was required. Using a method known as aerobraking, numerous passes through the upper atmosphere slowed the spacecraft, thereby reducing the orbital period and eccentricity. To successfully perform aerobraking, the spacecraft was designed to be longitudinally, aerodynamically stable in pitch and yaw. Since the orbit is nearly polar, the yaw orientation of the spacecraft was sensitive to disturbances caused by the zonal components of wind (east-to-west or west-to-east) acting on the spacecraft at aerobraking altitudes. Zonal wind velocities were computed by equating the aerodynamic and inertia-related torques acting on the spacecraft. Comparisons of calculated zonal winds with those computed from the Mars Thermospheric Global Circulation Model are discussed.

  11. A simple method for calculating growth rates of petroleum hydrocarbon plumes

    USGS Publications Warehouse

    Bekins, B.A.; Cozzarelli, I.M.; Curtis, G.P.

    2005-01-01

    Consumption of aquifer Fe(III) during biodegradation of ground water contaminants may result in expansion of a contaminant plume, changing the outlook for monitored natural attenuation. Data from two research sites contaminated with petroleum hydrocarbons show that toluene and xylenes degrade under methanogenic conditions, but the benzene and ethylbenzene plumes grow as aquifer Fe(III) supplies are depleted. By considering a one-dimensional reaction front in a constant unidirectional flow field, it is possible to derive a simple expression for the growth rate of a benzene plume. The method balances the mass flux of benzene with the Fe(III) content of the aquifer, assuming that the biodegradation reaction is instantaneous. The resulting expression shows that the benzene front migration is retarded relative to the ground water velocity by a factor that depends on the concentrations of hydrocarbon and bioavailable Fe(III). The method provides good agreement with benzene plumes at a crude oil study site in Minnesota and a gasoline site in South Carolina. Compared to the South Carolina site, the Minnesota site has 25% higher benzene flux but eight times the Fe(III), leading to about one-sixth the expansion rate. Although it was developed for benzene, toluene, ethylbenzene, and xylenes, the growth-rate estimation method may have applications to contaminant plumes from other persistent contaminant sources. Copyright ?? 2005 National Ground Water Association.

  12. A simple method for calculating growth rates of petroleum hydrocarbon plumes.

    PubMed

    Bekins, Barbara A; Cozzarelli, Isabelle M; Curtis, Gary P

    2005-01-01

    Consumption of aquifer Fe(III) during biodegradation of ground water contaminants may result in expansion of a contaminant plume, changing the outlook for monitored natural attenuation. Data from two research sites contaminated with petroleum hydrocarbons show that toluene and xylenes degrade under methanogenic conditions, but the benzene and ethylbenzene plumes grow as aquifer Fe(III) supplies are depleted. By considering a one-dimensional reaction front in a constant unidirectional flow field, it is possible to derive a simple expression for the growth rate of a benzene plume. The method balances the mass flux of benzene with the Fe(III) content of the aquifer, assuming that the biodegradation reaction is instantaneous. The resulting expression shows that the benzene front migration is retarded relative to the ground water velocity by a factor that depends on the concentrations of hydrocarbon and bioavailable Fe(III). The method provides good agreement with benzene plumes at a crude oil study site in Minnesota and a gasoline site in South Carolina. Compared to the South Carolina site, the Minnesota site has 25% higher benzene flux but eight times the Fe(III), leading to about one-sixth the expansion rate. Although it was developed for benzene, toluene, ethylbenzene, and xylenes, the growth-rate estimation method may have applications to contaminant plumes from other persistent contaminant sources.

  13. Implementation of a Thermodynamic Solver within a Computer Program for Calculating Fission-Product Release Fractions

    NASA Astrophysics Data System (ADS)

    Barber, Duncan Henry

    During some postulated accidents at nuclear power stations, fuel cooling may be impaired. In such cases, the fuel heats up and the subsequent increased fission-gas release from the fuel to the gap may result in fuel sheath failure. After fuel sheath failure, the barrier between the coolant and the fuel pellets is lost or impaired, gases and vapours from the fuel-to-sheath gap and other open voids in the fuel pellets can be vented. Gases and steam from the coolant can enter the broken fuel sheath and interact with the fuel pellet surfaces and the fission-product inclusion on the fuel surface (including material at the surface of the fuel matrix). The chemistry of this interaction is an important mechanism to model in order to assess fission-product releases from fuel. Starting in 1995, the computer program SOURCE 2.0 was developed by the Canadian nuclear industry to model fission-product release from fuel during such accidents. SOURCE 2.0 has employed an early thermochemical model of irradiated uranium dioxide fuel developed at the Royal Military College of Canada. To overcome the limitations of computers of that time, the implementation of the RMC model employed lookup tables to pre-calculated equilibrium conditions. In the intervening years, the RMC model has been improved, the power of computers has increased significantly, and thermodynamic subroutine libraries have become available. This thesis is the result of extensive work based on these three factors. A prototype computer program (referred to as SC11) has been developed that uses a thermodynamic subroutine library to calculate thermodynamic equilibria using Gibbs energy minimization. The Gibbs energy minimization requires the system temperature (T) and pressure (P), and the inventory of chemical elements (n) in the system. In order to calculate the inventory of chemical elements in the fuel, the list of nuclides and nuclear isomers modelled in SC11 had to be expanded from the list used by SOURCE 2.0. A

  14. 30 CFR 250.1159 - May the Regional Supervisor limit my well or reservoir production rates?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... reservoir production rates? 250.1159 Section 250.1159 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT... Supervisor limit my well or reservoir production rates? (a) The Regional Supervisor may set a Maximum Production Rate (MPR) for a producing well completion, or set a Maximum Efficient Rate (MER) for a...

  15. 30 CFR 250.1159 - May the Regional Supervisor limit my well or reservoir production rates?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... reservoir production rates? 250.1159 Section 250.1159 Mineral Resources BUREAU OF SAFETY AND ENVIRONMENTAL... my well or reservoir production rates? (a) The Regional Supervisor may set a Maximum Production Rate (MPR) for a producing well completion, or set a Maximum Efficient Rate (MER) for a reservoir, or...

  16. 30 CFR 250.1159 - May the Regional Supervisor limit my well or reservoir production rates?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... reservoir production rates? 250.1159 Section 250.1159 Mineral Resources BUREAU OF SAFETY AND ENVIRONMENTAL... my well or reservoir production rates? (a) The Regional Supervisor may set a Maximum Production Rate (MPR) for a producing well completion, or set a Maximum Efficient Rate (MER) for a reservoir, or...

  17. 30 CFR 250.1159 - May the Regional Supervisor limit my well or reservoir production rates?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... reservoir production rates? 250.1159 Section 250.1159 Mineral Resources MINERALS MANAGEMENT SERVICE... reservoir production rates? (a) The Regional Supervisor may set a Maximum Production Rate (MPR) for a producing well completion, or set a Maximum Efficient Rate (MER) for a reservoir, or both, if the...

  18. 30 CFR 250.1159 - May the Regional Supervisor limit my well or reservoir production rates?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... reservoir production rates? 250.1159 Section 250.1159 Mineral Resources BUREAU OF SAFETY AND ENVIRONMENTAL... my well or reservoir production rates? (a) The Regional Supervisor may set a Maximum Production Rate (MPR) for a producing well completion, or set a Maximum Efficient Rate (MER) for a reservoir, or...

  19. Analysis of two production inventory systems with buffer, retrials and different production rates

    NASA Astrophysics Data System (ADS)

    Jose, K. P.; Nair, Salini S.

    2017-02-01

    This paper considers the comparison of two ( {s,S} ) production inventory systems with retrials of unsatisfied customers. The time for producing and adding each item to the inventory is exponentially distributed with rate β . However, a production rate α β higher than β is used at the beginning of the production. The higher production rate will reduce customers' loss when inventory level approaches zero. The demand from customers is according to a Poisson process. Service times are exponentially distributed. Upon arrival, the customers enter into a buffer of finite capacity. An arriving customer, who finds the buffer full, moves to an orbit. They can retry from there and inter-retrial times are exponentially distributed. The two models differ in the capacity of the buffer. The aim is to find the minimum value of total cost by varying different parameters and compare the efficiency of the models. The optimum value of α corresponding to minimum total cost is an important evaluation. Matrix analytic method is used to find an algorithmic solution to the problem. We also provide several numerical or graphical illustrations.

  20. Toward a molecular theory of homogeneous bubble nucleation: II. Calculation of the number density of critical nuclei and the rate of nucleation.

    PubMed

    Torabi, Korosh; Corti, David S

    2013-10-17

    In the present paper, we develop a method to calculate the rate of homogeneous bubble nucleation within a superheated L-J liquid based on the (n,v) equilibrium embryo free energy surface introduced in the first paper (DOI: 10.1021/jp404149n). We express the nucleation rate as the product of the concentration of critical nuclei within the metastable liquid phase and the relevant forward rate coefficient. We calculate the forward rate coefficient of the critical nuclei from their average lifetime as determined from MD simulations of a large number of embryo trajectories initiated from the transitional region of the metastable liquid configuration space. Therefore, the proposed rate coefficient does not rely on any predefined reaction coordinate. In our model, the critical nuclei belong to the region of the configuration space where the committor probability is about one-half, guaranteeing the dynamical relevance of the proposed embryos. One novel characteristic of our approach is that we define a limit for the configuration space of the equilibrium metastable phase and do not include the configurations that have zero committor probability in the nucleation free energy surface. Furthermore, in order to take into account the transitional degrees of freedom of the critical nuclei, we develop a simulation-based approach for rigorously mapping the free energy of the (n,v) equilibrium embryos to the concentration of the critical nuclei within the bulk metastable liquid phase.

  1. STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE [SEC 1 & 2

    SciTech Connect

    HU, T.A.

    2003-09-30

    Flammable gases such as hydrogen, ammonia, and methane are observed in the tank dome space of the Hanford Site high-level waste tanks. This report assesses the steady-state flammability level under normal and off-normal ventilation conditions in the tank dome space for 177 double-shell tanks and single-shell tanks at the Hanford Site. The steady-state flammability level was estimated from the gas concentration of the mixture in the dome space using estimated gas release rates, Le Chatelier's rule and lower flammability limits of fuels in an air mixture. A time-dependent equation of gas concentration, which is a function of the gas release and ventilation rates in the dome space, has been developed for both soluble and insoluble gases. With this dynamic model, the time required to reach the specified flammability level at a given ventilation condition can be calculated. In the evaluation, hydrogen generation rates can be calculated for a given tank waste composition and its physical condition (e.g., waste density, waste volume, temperature, etc.) using the empirical rate equation model provided in Empirical Rate Equation Model and Rate Calculations of Hydrogen Generation for Hanford Tank Waste, HNF-3851. The release rate of other insoluble gases and the mass transport properties of the soluble gas can be derived from the observed steady-state gas concentration under normal ventilation conditions. The off-normal ventilation rate is assumed to be natural barometric breathing only. A large body of data is required to do both the hydrogen generation rate calculation and the flammability level evaluation. For tank waste that does not have sample-based data, a statistical-based value from probability distribution regression was used based on data from tanks belonging to a similar waste group. This report (Revision 3) updates the input data of hydrogen generation rates calculation for 177 tanks using the waste composition information in the Best-Basis Inventory Detail

  2. The trend of production rates with heliocentric distance for comet P/Halley

    NASA Astrophysics Data System (ADS)

    Fink, U.

    1994-03-01

    Comet P/Halley was observed spectroscopically in the wavelength range 5200-10,400 A during 10 observing runs, roughly a month apart from 1985 August 28 to 1986 June 6. The observations span a heliocentric distance from 0.73 to 2.52 AU. This data set is analyzed to determine the course of the production rate with heliocentric distance for C2, NH2, CN, and the continuum. The effect of changing the Haser scale lengths and their heliocentric distance dependence is examined. The production rate ratios to water change only in a minor way, but the absolute values of the production rates are more severely affected. Fluorescent efficiencies, or g-factors for the CN red system are calculated, and band intensity ratios for NH2 and CN are presented. Using presently available fluorescence efficiencies and Haser scale lengths, mixing ratios for the parents of C2, CN, and NH2 with respect to water are: 0.34 +/- 0.07%, 0.15 +/- 0.04%, and 0.13 +/- 0.05%. It is found that these mixing ratios are essentially constant over the heliocentric distance range of the observations, implying a rather uniform nucleus and uniform outgassing characteristics, although there are indications of smaller scale day-to-day variations. The results provide strong observational confirmation that water evaporation controls the activity of the comet over the distance range studied. Continuum values Af rho are determined, and their ratios to QH2O are found to have a clear dependence with heliocentric distance approximately r-1.0 with a post-perihelion enhancement. No correlation of the production rate ratios with light curve of P/Halley were found, nor was there any correlation of the C2 or CN production with the dust.

  3. Predicting Reduction Rates of Energetic Nitroaromatic Compounds Using Calculated One-Electron Reduction Potentials

    SciTech Connect

    Salter-Blanc, Alexandra; Bylaska, Eric J.; Johnston, Hayley; Tratnyek, Paul G.

    2015-02-11

    The evaluation of new energetic nitroaromatic compounds (NACs) for use in green munitions formulations requires models that can predict their environmental fate. The susceptibility of energetic NACs to nitro reduction might be predicted from correlations between rate constants (k) for this reaction and one-electron reduction potentials (E1NAC) / 0.059 V, but the mechanistic implications of such correlations are inconsistent with evidence from other methods. To address this inconsistency, we have reevaluated existing kinetic data using a (non-linear) free-energy relationship (FER) based on the Marcus theory of outer-sphere electron transfer. For most reductants, the results are inconsistent with rate limitation by an initial, outer-sphere electron transfer, suggesting that the strong correlation between k and E1NAC is justified only as an empirical model. This empirical correlation was used to calibrate a new quantitative structure-activity relationship (QSAR) using previously reported values of k for non-energetic NAC reduction by Fe(II) porphyrin and newly reported values of E1NAC determined using density functional theory at the B3LYP/6-311++G(2d,2p) level with the COSMO solvation model. The QSAR was then validated for energetic NACs using newly measured kinetic data for 2,4,6-trinitrotoluene (TNT), 2,4-dinitrotoluene (2,4-DNT), and 2,4-dinitroanisole (DNAN). The data show close agreement with the QSAR, supporting its applicability to energetic NACs.

  4. Predicting Reduction Rates of Energetic Nitroaromatic Compounds Using Calculated One-Electron Reduction Potentials

    DOE PAGES

    Salter-Blanc, Alexandra; Bylaska, Eric J.; Johnston, Hayley; ...

    2015-02-11

    The evaluation of new energetic nitroaromatic compounds (NACs) for use in green munitions formulations requires models that can predict their environmental fate. The susceptibility of energetic NACs to nitro reduction might be predicted from correlations between rate constants (k) for this reaction and one-electron reduction potentials (E1NAC) / 0.059 V, but the mechanistic implications of such correlations are inconsistent with evidence from other methods. To address this inconsistency, we have reevaluated existing kinetic data using a (non-linear) free-energy relationship (FER) based on the Marcus theory of outer-sphere electron transfer. For most reductants, the results are inconsistent with rate limitation bymore » an initial, outer-sphere electron transfer, suggesting that the strong correlation between k and E1NAC is justified only as an empirical model. This empirical correlation was used to calibrate a new quantitative structure-activity relationship (QSAR) using previously reported values of k for non-energetic NAC reduction by Fe(II) porphyrin and newly reported values of E1NAC determined using density functional theory at the B3LYP/6-311++G(2d,2p) level with the COSMO solvation model. The QSAR was then validated for energetic NACs using newly measured kinetic data for 2,4,6-trinitrotoluene (TNT), 2,4-dinitrotoluene (2,4-DNT), and 2,4-dinitroanisole (DNAN). The data show close agreement with the QSAR, supporting its applicability to energetic NACs.« less

  5. Average hydrodynamic correction for the Brownian dynamics calculation of flocculation rates in concentrated dispersions

    NASA Astrophysics Data System (ADS)

    Urbina-Villalba, German; García-Sucre, Máximo; Toro-Mendoza, Jhoan

    2003-12-01

    In order to account for the hydrodynamic interaction (HI) between suspended particles in an average way, Honig et al. [J. Colloid Interface Sci. 36, 97 (1971)] and more recently Heyes [Mol. Phys. 87, 287 (1996)] proposed different analytical forms for the diffusion constant. While the formalism of Honig et al. strictly applies to a binary collision, the one from Heyes accounts for the dependence of the diffusion constant on the local concentration of particles. However, the analytical expression of the latter approach is more complex and depends on the particular characteristics of each system. Here we report a combined methodology, which incorporates the formula of Honig et al. at very short distances and a simple local volume-fraction correction at longer separations. As will be shown, the flocculation behavior calculated from Brownian dynamics simulations employing the present technique, is found to be similar to that of Batchelor’s tensor [J. Fluid. Mech. 74, 1 (1976); 119, 379 (1982)]. However, it corrects the anomalous coalescence found in concentrated systems as a result of the overestimation of many-body HI.

  6. Normalized impact factor (NIF): an adjusted method for calculating the citation rate of biomedical journals.

    PubMed

    Owlia, P; Vasei, M; Goliaei, B; Nassiri, I

    2011-04-01

    The interests in journal impact factor (JIF) in scientific communities have grown over the last decades. The JIFs are used to evaluate journals quality and the papers published therein. JIF is a discipline specific measure and the comparison between the JIF dedicated to different disciplines is inadequate, unless a normalization process is performed. In this study, normalized impact factor (NIF) was introduced as a relatively simple method enabling the JIFs to be used when evaluating the quality of journals and research works in different disciplines. The NIF index was established based on the multiplication of JIF by a constant factor. The constants were calculated for all 54 disciplines of biomedical field during 2005, 2006, 2007, 2008 and 2009 years. Also, ranking of 393 journals in different biomedical disciplines according to the NIF and JIF were compared to illustrate how the NIF index can be used for the evaluation of publications in different disciplines. The findings prove that the use of the NIF enhances the equality in assessing the quality of research works produced by researchers who work in different disciplines.

  7. Comparison between Measured and Calculated Sediment Transport Rates in North Fork Caspar Creek, California

    NASA Astrophysics Data System (ADS)

    Kim, T. W.; Yarnell, S. M.; Yager, E.; Leidman, S. Z.

    2015-12-01

    Caspar Creek is a gravel-bedded stream located in the Jackson Demonstration State Forest in the coast range of California. The Caspar Creek Experimental Watershed has been actively monitored and studied by the Pacific Southwest Research Station and California Department of Forestry and Fire Protection for over five decades. Although total annual sediment yield has been monitored through time, sediment transport during individual storm events is less certain. At a study site on North Fork Caspar Creek, cross-section averaged sediment flux was collected throughout two storm events in December 2014 and February 2015 to determine if two commonly used sediment transport equations—Meyer-Peter-Müller and Wilcock—approximated observed bedload transport. Cross-section averaged bedload samples were collected approximately every hour during each storm event using a Helley-Smith bedload sampler. Five-minute composite samples were collected at five equally spaced locations along a cross-section and then sieved to half-phi sizes to determine the grain size distribution. The measured sediment flux values varied widely throughout the storm hydrographs and were consistently less than two orders of magnitude in value in comparison to the calculated values. Armored bed conditions, changing hydraulic conditions during each storm and variable sediment supply may have contributed to the observed differences.

  8. New Calculation of Antiproton Production by Cosmic Ray Protons and Nuclei

    NASA Astrophysics Data System (ADS)

    Kachelriess, Michael; Moskalenko, Igor V.; Ostapchenko, Sergey S.

    2015-04-01

    A dramatic increase in the accuracy and statistics of space-borne cosmic ray (CR) measurements has yielded several breakthroughs over the last several years. The most puzzling is the rise in the positron fraction above ∼10 GeV over the predictions of the propagation models assuming pure secondary production. The accuracy of the antiproton production cross section is critical for astrophysical applications and searches for new physics since antiprotons in CRs seem to hold the keys to many puzzles including the origin of those excess positrons. However, model calculations of antiproton production in CR interactions with interstellar gas are often employing parameterizations that are out of date or are using outdated physical concepts. This may lead to an incorrect interpretation of antiproton data which could have broad consequences for other areas of astrophysics. In this work, we calculate antiproton production in pp-, pA-, and AA-interactions using EPOS-LHC and QGSJET-II-04, two of the most advanced Monte Carlo (MC) generators tuned to numerous accelerator data including those from the Large Hadron Collider (LHC). We show that the antiproton yields obtained with these MC generators differ by up to an order of magnitude from yields of parameterizations commonly used in astrophysics.

  9. Cortisol production rates measured by liquid chromatography/mass spectrometry

    SciTech Connect

    Esteban, N.V.; Yergey, A.L. )

    1990-04-01

    Cortisol production rates (FPRs) in physiologic and pathologic states in humans have been investigated over the past 30 years. However, there has been conflicting evidence concerning the validity of the currently accepted value of FPRs in humans (12 to 15 mg/m2/d) as determined by radiotracer methodology. The present study reviews previous methods proposed for the measurement of FPRs in humans and discusses the applications of the first method for the direct determination of 24-hour plasma FPRs during continuous administration of a stable isotope, using a thermospray high-pressure liquid chromatography-mass spectrometry technique. The technique is fast, sensitive, and, unlike gas chromatography-mass spectrometry methods, does not require derivatization, allowing on-line detection and quantification of plasma cortisol after a simple extraction procedure. The results of determination of plasma FPRs by stable tracer/mass spectrometry are directly in units of mass/time and, unlike radiotracer methods, are independent of any determination of volume of distribution or cortisol concentration. Our methodology offers distinct advantages over radiotracer techniques in simplicity and reliability since only single measurements of isotope ratios are required. The technique was validated in adrenalectomized patients. Circadian variations in daily FRPs were observed in normal volunteers, and, to date, results suggest a lower FRP in normal children and adults than previously believed. 88 references.

  10. RayXpert V1: 3D software for the gamma dose rate calculation by Monte Carlo

    NASA Astrophysics Data System (ADS)

    Peyrard, P. F.; Pourrouquet, P.; Dossat, C.; Thomas, J. C.; Chatry, N.; Lavielle, D.; Chatry, C.

    2014-06-01

    RayXpert has been developed to ease the access to the power and accuracy of the 3D Monte Carlo method in the field of gamma dose rate estimate. Optimization methods have been implemented to address dose calculation behind thick 3D structures. At the same time, the engineering interface makes all the preprocessing tasks (modeling, material settings,…) faster using predefined tables and push button features.

  11. Walking in the woods with quantum chemistry--applications of quantum chemical calculations in natural products research.

    PubMed

    Tantillo, Dean J

    2013-08-01

    This Highlight describes applications of quantum chemical calculations to problems in natural products chemistry, including the elucidation of natural product structures (distinguishing between constitutional isomers, distinguishing between diastereomers, and assigning absolute configuration) and determination of reasonable mechanisms for their formation.

  12. Critical behavior of entropy production and learning rate: Ising model with an oscillating field

    NASA Astrophysics Data System (ADS)

    Zhang, Yirui; Barato, Andre C.

    2016-11-01

    We study the critical behavior of the entropy production of the Ising model subject to a magnetic field that oscillates in time. The mean-field model displays a phase transition that can be either first or second-order, depending on the amplitude of the field and on the frequency of oscillation. Within this approximation the entropy production rate is shown to have a discontinuity when the transition is first-order and to be continuous, with a jump in its first derivative, if the transition is second-order. In two dimensions, we find with numerical simulations that the critical behavior of the entropy production rate is the same, independent of the frequency and amplitude of the field. Its first derivative has a logarithmic divergence at the critical point. This result is in agreement with the lack of a first-order phase transition in two dimensions. We analyze a model with a field that changes at stochastic time-intervals between two values. This model allows for an informational theoretic interpretation, with the system as a sensor that follows the external field. We calculate numerically a lower bound on the learning rate, which quantifies how much information the system obtains about the field. Its first derivative with respect to temperature is found to have a jump at the critical point.

  13. Effect of growth rate on plasmid DNA production and metabolic performance of engineered Escherichia coli strains.

    PubMed

    Wunderlich, Martin; Taymaz-Nikerel, Hilal; Gosset, Guillermo; Ramírez, Octavio T; Lara, Alvaro R

    2014-03-01

    Two engineered Escherichia coli strains, designated VH33 and VH34, were compared to their parent strain W3110 in chemostat mode during plasmid DNA (pDNA) production. In strain VH33 the glucose uptake system was modified with the aim of reducing overflow metabolism. The strain VH34 has an additional deletion of the pyruvate kinase A gene (pykA) to increase pDNA formation. pDNA formation rates as well as kinetic and stoichiometric parameters were investigated in dependence of the growth rate within a range from 0.02 to 0.25 h(-1). Differences between strains were found in terms of the biomass yields on nitrogen and oxygen, as well as on the cell maintenance coefficients. The deletion of pykA led to a significantly increased pDNA yield and productivity. At an optimal growth rate of 0.20 h(-1) it was nearly 60% higher than that of W3110 and VH33. Metabolic fluxes calculated by metabolite balance analysis showed differences mainly in reactions catalyzed by pyruvate kinase and glucose 6-phosphate dehydrogenase. The obtained data are useful for the design of cultivation schemes for pDNA production by E. coli.

  14. Numerical calculation of protein-ligand binding rates through solution of the Smoluchowski equation using smooth particle hydrodynamics

    SciTech Connect

    Pan, Wenxiao; Daily, Michael D.; Baker, Nathan A.

    2015-12-01

    We demonstrate the accuracy and effectiveness of a Lagrangian particle-based method, smoothed particle hydrodynamics (SPH), to study diffusion in biomolecular systems by numerically solving the time-dependent Smoluchowski equation for continuum diffusion. The numerical method is first verified in simple systems and then applied to the calculation of ligand binding to an acetylcholinesterase monomer. Unlike previous studies, a reactive Robin boundary condition (BC), rather than the absolute absorbing (Dirichlet) boundary condition, is considered on the reactive boundaries. This new boundary condition treatment allows for the analysis of enzymes with "imperfect" reaction rates. Rates for inhibitor binding to mAChE are calculated at various ionic strengths and compared with experiment and other numerical methods. We find that imposition of the Robin BC improves agreement between calculated and experimental reaction rates. Although this initial application focuses on a single monomer system, our new method provides a framework to explore broader applications of SPH in larger-scale biomolecular complexes by taking advantage of its Lagrangian particle-based nature.

  15. Large-scale production of kappa-carrageenan droplets for gel-bead production: theoretical and practical limitations of size and production rate.

    PubMed

    Hunik, J H; Tramper, J

    1993-01-01

    Immobilization of biocatalysts in kappa-carrageenan gel beads is a widely used technique nowadays. Several methods are used to produce the gel beads. The gel-bead production rate is usually sufficient to make the relatively small quantities needed for bench-scale experiments. The droplet diameter can, within limits, be adjusted to the desired size, but it is difficult to predict because of the non-Newtonian fluid behavior of the kappa-carrageenan solution. Here we present the further scale-up of the extrusion technique with the theory to predict the droplet diameters for non-Newtonian fluids. The emphasis is on the droplet formation, which is the rate-limiting step in this extrusion technique. Uniform droplets were formed by breaking up a capillary jet with a sinusoidal signal of a vibration exciter. At the maximum production rate of 27.6 dm3/h, uniform droplets with a diameter of (2.1 +/- 0.12) x 10(-3) m were obtained. This maximum flow rate was limited by the power transfer of the vibration exciter to the liquid flow. It was possible to get a good prediction of the droplet diameter by estimating the local viscosity from shear-rate calculations and an experimental relation between the shear rate and viscosity. In this way the theory of Newtonian fluids could be used for the non-Newtonian kappa-carrageenan solution. The calculated optimal break-up frequencies and droplet sizes were in good agreement with those found in the experiments.

  16. In-situ Measurements of Ozone Production Rates and Comparisons to Model-derived Production Rates During the Houston, TX and Denver, CO DISCOVER-AQ Campaigns

    NASA Astrophysics Data System (ADS)

    Baier, B. C.; Brune, W. H.; Miller, D. O.; Lefer, B. L.

    2015-12-01

    Tropospheric ozone (O3) is a secondary pollutant that has harmful effects on human and plant life. The climate and urban emissions in Houston, TX and Denver, CO can be conducive for significant ozone production and thus, high ozone events. Tighter government strategies for ozone mitigation have been proposed, which involve reducing the current EPA eight-hour ozone standard from 75 ppb to 65-70 ppb. These strategies rely on the reduction of ozone precursors in order to decrease the ozone production rate, P(O3). The changes in the ozone concentration at a certain location are dependent upon P(O3), so decreasing P(O3) can decrease ozone levels provided that it has not been transported from other areas. Air quality models test reduction strategies before they are implemented, locate ozone sources, and predict ozone episodes. Traditionally, P(O3) has been calculated by models. However, large uncertainties in model emissions inventories, chemical mechanisms, and meteorology can reduce confidence in this approach. A new instrument, the Measurement of Ozone Production Sensor (MOPS) directly measures P(O3) and can provide an alternate approach to determining P(O3). An updated version of the Penn State MOPS (MOPSv2.0) was deployed to Houston, TX and Denver, CO as a part of NASA's DISCOVER-AQ field campaign in the summers of 2013 and 2014, respectively. We present MOPS directly-measured P(O3) rates from these areas, as well as comparisons to zero-dimensional and three-dimensional modeled P(O3) using the RACM2 and MCMv2.2 mechanisms. These comparisons demonstrate the potential of the MOPS to test and evaluate model-derived P(O3), to advance the understanding of model chemical mechanisms, and to improve predictions of high ozone events.

  17. Calculation of relative glomerular filtration rate and correlation with delayed technetium-99m DMSA imaging

    SciTech Connect

    Taylor, A. Jr.; Kipper, M.; Witztum, K.

    1986-01-01

    The relative renal uptake of Tc-99m DMSA was compared with the relative glomerular filtration rate (GFR) in ten patients with serum creatinines ranging from 0.3 to 2.5 mg/dl. Relative GFR was based on the renal uptake of Tc-99m DTPA determined by two methods: 1) integrating the counts from 1 to 3 minutes postinjection and correcting for background. 2) Totalizing the individual renal counts in a single 15-second frame from 2:45 minutes to 3:00 minutes postinjection and correcting for background. The two methods of determining relative DTPA uptake showed excellent correlation, r = 0.98. Relative DMSA uptake determined at 24 hours post-injection using computer-assisted regions of interest showed excellent correlation with the relative GFR determined by either the integral or single-frame method, r = 0.98. The addition of background subtraction for the DMSA images at 24 hours did not improve the correlation.

  18. Comparison between Theoretical Calculation and Experimental Results of Excitation Functions for Production of Relevant Biomedical Radionuclides

    SciTech Connect

    Menapace, E.; Birattari, C.; Bonardi, M.L.; Groppi, F.; Morzenti, S.; Zona, C.

    2005-05-24

    The radionuclide production for biomedical applications has been brought up in the years, as a special nuclear application, at INFN LASA Laboratory, particularly in co-operation with the JRC-Ispra of EC. Mainly scientific aspects concerning radiation detection and the relevant instruments, the measurements of excitation functions of the involved nuclear reactions, the requested radiochemistry studies and further applications have been investigated. On the side of the nuclear data evaluations, based on nuclear model calculations and critically selected experimental data, the appropriate competence has been developed at ENEA Division for Advanced Physics Technologies. A series of high specific activity accelerator-produced radionuclides in no-carrier-added (NCA) form, for uses in metabolic radiotherapy and for PET radiodiagnostics, are investigated. In this work, last revised measurements and model calculations are reviewed for excitation functions of natZn(d,X)64Cu, 66Ga reactions, referring to irradiation experiments at K=38 variable energy Cyclotron of JRC-Ispra. Concerning the reaction data for producing 186gRe and 211At/211gPo (including significant emission spectra) and 210At, most recent and critically selected experimental results are considered and discussed in comparison with model calculations paying special care to pre-equilibrium effects estimate and to the appropriate overall parameterization. Model calculations are presented for 226Ra(p,2n)225Ac reaction, according to the working program of the ongoing IAEA CRP on the matter.

  19. Decline and depletion rates of oil production: a comprehensive investigation.

    PubMed

    Höök, Mikael; Davidsson, Simon; Johansson, Sheshti; Tang, Xu

    2014-01-13

    Two of the most fundamental concepts in the current debate about future oil supply are oilfield decline rates and depletion rates. These concepts are related, but not identical. This paper clarifies the definitions of these concepts, summarizes the underlying theory and empirically estimates decline and depletion rates for different categories of oilfield. A database of 880 post-peak fields is analysed to determine typical depletion levels, depletion rates and decline rates. This demonstrates that the size of oilfields has a significant influence on decline and depletion rates, with generally high values for small fields and comparatively low values for larger fields. These empirical findings have important implications for oil supply forecasting.

  20. Heat production rate from radioactive elements in igneous and metamorphic rocks in Eastern Desert, Egypt.

    PubMed

    Abbady, Adel G E; El-Arabi, A M; Abbady, A

    2006-01-01

    Radioactive heat-production data of Igneous and Metamorphic outcrops in the Eastern Desert are presented. Samples were analysed using a low level gamma-ray spectrometer (HPGe) in the laboratory. A total of 205 rock samples were investigated, covering all major rock types of the area. The heat-production rate of igneous rocks ranges from 0.11 (basalt) to 9.53 microWm(-3) (granite). In metamorphic rocks it varies from 0.28 (serpentinite ) to 0.91 microWm(-3) (metagabbro). The contribution due to U is about 51%, as that from Th is 31% and 18% from K. The corresponding values in igneous rocks are 76%, 19% and 5%, respectively. The calculated values showed good agreement with global values except in some areas containing granites.

  1. Reply to Nicholson's comment on "Consistent calculation of aquatic gross production from oxygen triple isotope measurements" by Kaiser (2011)

    NASA Astrophysics Data System (ADS)

    Kaiser, J.; Abe, O.

    2012-08-01

    The comment by Nicholson (2011a) questions the "consistency" of the "definition" of the "biological end-member" used by Kaiser (2011a) in the calculation of oxygen gross production. "Biological end-member" refers to the relative oxygen isotope ratio difference between photosynthetic oxygen and Air-O2 (abbreviated 17δP and 18δP for 17O/16O and 18O/16O, respectively). The comment claims that this leads to an overestimate of the discrepancy between previous studies and that the resulting gross production rates are "30% too high". Nicholson recognises the improved accuracy of Kaiser's direct calculation ("dual-delta") method compared to previous approximate approaches based on 17O excess (17Δ) and its simplicity compared to previous iterative calculation methods. Although he correctly points out that differences in the normalised gross production rate (g) are largely due to different input parameters used in Kaiser's "base case" and previous studies, he does not acknowledge Kaiser's observation that iterative and dual-delta calculation methods give exactly the same g for the same input parameters (disregarding kinetic isotope fractionation during air-sea exchange). The comment is based on misunderstandings with respect to the "base case" 17δP and 18δP values. Since direct measurements of 17δP and 18δPdo not exist or have been lost, Kaiser constructed the "base case" in a way that was consistent and compatible with literature data. Nicholson showed that an alternative reconstruction of 17δP gives g values closer to previous studies. However, unlike Nicholson, we refrain from interpreting either reconstruction as a benchmark for the accuracy of g. A number of publications over the last 12 months have tried to establish which of these two reconstructions is more accurate. Nicholson draws on recently revised measurements of the relative 17O/16O difference between VSMOW and Air-O2 (17δVSMOW; Barkan and Luz, 2011), together with new measurements of photosynthetic

  2. Calculating clear-sky radiative heating rates using the Fu-Liou RTM with inputs from observed and reanalyzed profiles

    NASA Astrophysics Data System (ADS)

    Dolinar, E. K.; Dong, X.; Xi, B.

    2015-12-01

    One-dimensional radiative transfer models (RTM) are a common tool used for calculating atmospheric heating rates and radiative fluxes. In the forward sense, RTMs use known (or observed) quantities of the atmospheric state and surface characteristics to determine the appropriate surface and top-of-atmosphere (TOA) radiative fluxes. The NASA CERES science team uses the modified Fu-Liou RTM to calculate atmospheric heating rates and surface and TOA fluxes using the CERES observed TOA shortwave (SW) and longwave (LW) fluxes as constraints to derive global surface and TOA radiation budgets using a reanalyzed atmospheric state (e.g. temperature and various greenhouse gases) from the newly developed MERRA-2. However, closure studies have shown that using the reanalyzed state as input to the RTM introduces some disparity between the RTM calculated fluxes and surface observed ones. The purpose of this study is to generate a database of observed atmospheric state profiles, from satellite and ground-based sources, at several permanent Atmospheric Radiation Measurement (ARM) Program sites, including the Southern Great Plains (SGP), Northern Slope of Alaska (NSA) and Tropical Western Pacific Nauru (TWP-C2), and Eastern North Atlantic (ENA) permanent facilities. Since clouds are a major modulator of radiative transfer within the Earth's atmosphere, we will focus on the clear-sky conditions in this study, which will set up the baseline for our cloudy studies in the future. Clear-sky flux profiles are calculated using the Edition 4 NASA LaRC modified Fu-Liou RTM. The aforementioned atmospheric profiles generated in-house are used as input into the RTM, as well as from reanalyses. The calculated surface and TOA fluxes are compared with ARM surface measured and CERES satellite observed SW and LW fluxes, respectively. Clear-sky cases are identified by the ARM radar-lidar observations, as well as satellite observations, at the select ARM sites.

  3. How to Calculate Renyi Entropy from Heart Rate Variability, and Why it Matters for Detecting Cardiac Autonomic Neuropathy.

    PubMed

    Cornforth, David J; Tarvainen, Mika P; Jelinek, Herbert F

    2014-01-01

    Cardiac autonomic neuropathy (CAN) is a disease that involves nerve damage leading to an abnormal control of heart rate. An open question is to what extent this condition is detectable from heart rate variability (HRV), which provides information only on successive intervals between heart beats, yet is non-invasive and easy to obtain from a three-lead ECG recording. A variety of measures may be extracted from HRV, including time domain, frequency domain, and more complex non-linear measures. Among the latter, Renyi entropy has been proposed as a suitable measure that can be used to discriminate CAN from controls. However, all entropy methods require estimation of probabilities, and there are a number of ways in which this estimation can be made. In this work, we calculate Renyi entropy using several variations of the histogram method and a density method based on sequences of RR intervals. In all, we calculate Renyi entropy using nine methods and compare their effectiveness in separating the different classes of participants. We found that the histogram method using single RR intervals yields an entropy measure that is either incapable of discriminating CAN from controls, or that it provides little information that could not be gained from the SD of the RR intervals. In contrast, probabilities calculated using a density method based on sequences of RR intervals yield an entropy measure that provides good separation between groups of participants and provides information not available from the SD. The main contribution of this work is that different approaches to calculating probability may affect the success of detecting disease. Our results bring new clarity to the methods used to calculate the Renyi entropy in general, and in particular, to the successful detection of CAN.

  4. Nuclear data production, calculation and measurement: a global overview of the gamma heating issue

    NASA Astrophysics Data System (ADS)

    Colombier, A.-C.; Amharrak, H.; Fourmentel, D.; Ravaux, S.; Régnier, D.; Gueton, O.; Hudelot, J.-P.; Lemaire, M.

    2013-03-01

    The gamma heating evaluation in different materials found in current and future generations of nuclear reactor (EPRTM, GENIV, MTR-JHR), is becoming an important issue especially for the design of many devices (control rod, heavy reflector, in-core & out-core experiments…). This paper deals with the works started since 2009 in the Reactor Studies Department of CEA Cadarache in ordre to answer to several problematic which have been identified as well for nuclear data production and calculation as for experimental measurement methods. The selected subjects are: Development of a Monte Carlo code (FIFRELIN) to simulate the prompt fission gamma emission which represents the major part of the gamma heating production inside the core Production and qualification of new evaluations of nuclear data especially for radiative capture and inelastic neutron scattering which are the main sources of gamma heating out-core Development and qualification of a recommended method for the total gamma heating calculation using the Monte Carlo simulation code TRIPOLI-4 Development, test and qualification of new devices dedicated to the in-core gamma heating measurement as well in MTR-JHR as in zero power facilities (EOLE-MINERVE) of CEA, Cadarache to increase the experimental measurement accuracy.

  5. Application of Thermodynamic Calculations to the Pyro-refining Process for Production of High Purity Bismuth

    NASA Astrophysics Data System (ADS)

    Mezbahul-Islam, Mohammad; Belanger, Frederic; Chartrand, Patrice; Jung, In-Ho; Coursol, Pascal

    2017-02-01

    The present work has been performed with the aim to optimize the existing process for the production of high purity bismuth (99.999 pct). A thermo-chemical database including most of the probable impurities of bismuth (Bi-X, X = Ag, Au, Al, Ca, Cu, Fe, Mg, Mn, Na, Ni, Pb, S, Sb, Sn, Si, Te, Zn) has been constructed to perform different thermodynamic calculations required for the refining process. Thermodynamic description for eight of the selected binaries, Bi-Ca, Cu, Mn, Ni, Pb, S, Sb, and Sn, has been given in the current paper. Using the current database, different thermodynamic calculations have been performed to explain the steps involved in the bismuth refining process.

  6. Sensitivity study of forecasted aftershock seismicity based on Coulomb stress calculation and rate- and state-dependent frictional response (Invited)

    NASA Astrophysics Data System (ADS)

    Cocco, M.; Hainzl, S.; Woessner, J.; Enescu, B.; Catalli, F.; Lombardi, A.

    2009-12-01

    It is nowadays well established that both Coulomb stress perturbations and the rate- and state-dependent frictional response of fault populations are needed to model the spatial and temporal evolution of seismicity. This represents the most popular physics-based approach to forecast the rate of earthquake production and its performances have to be verified with respect to alternative statistical methods. Despite the numerous applications of Coulomb stress interactions, a rigorous validation of the forecasting capabilities is still missing. In this work, we use the Dieterich (1994) physics-based approach to simulate the spatio-temporal evolution of seismicity caused by stress changes applied to an infinite population of nucleating patches modelled through a rate- and state-dependent friction law. According to this model, seismicity rate changes depend on the amplitude of stress perturbation, the physical constitutive properties of faults (represented by the parameter Aσ), the stressing rate and the background seismicity rate of the study area. In order to apply this model in a predictive manner, we need to understand the variability of input physical model parameters and their correlations. We first discuss the impact of uncertainties in model parameters and, in particular, in computed coseismic stress perturbations on the seismicity rate changes forecasted through the frictional model. We aim to understand how the variability of Coulomb stress changes affects the correlation between predicted and observed changes in the rate of earthquake production. We use the aftershock activity following the 1992 M 7.3 Landers (California) earthquake as one of our case studies. We analyze the variability of stress changes resulting from the use of different published slip distributions. We find that the standard deviation of the uncertainty is of the same size as the absolute stress change and that their ratio, the coefficient of variation (CV), is approximately constant in

  7. Carbon Calculator for Land Use Change from Biofuels Production (CCLUB). Users' manual and technical documentation.

    SciTech Connect

    Mueller, S; Dunn, JB; Wang, M

    2012-06-07

    The Carbon Calculator for Land Use Change from Biofuels Production (CCLUB) calculates carbon emissions from land use change (LUC) for four different ethanol production pathways including corn grain ethanol and cellulosic ethanol from corn stover, miscanthus, and switchgrass. This document discusses the version of CCLUB released May 31, 2012 which includes corn, as did the previous CCLUB version, and three cellulosic feedstocks: corn stover, miscanthus, and switchgrass. CCLUB calculations are based upon two data sets: land change areas and above- and below-ground carbon content. Table 1 identifies where these data are stored and used within the CCLUB model, which is built in MS Excel. Land change area data is from Purdue University's Global Trade Analysis Project (GTAP) model, a computable general equilibrium (CGE) economic model. Section 2 describes the GTAP data CCLUB uses and how these data were modified to reflect shrubland transitions. Feedstock- and spatially-explicit below-ground carbon content data for the United States were generated with a surrogate model for CENTURY's soil organic carbon sub-model (Kwon and Hudson 2010) as described in Section 3. CENTURY is a soil organic matter model developed by Parton et al. (1987). The previous CCLUB version used more coarse domestic carbon emission factors. Above-ground non-soil carbon content data for forest ecosystems was sourced from the USDA/NCIAS Carbon Online Estimator (COLE) as explained in Section 4. We discuss emission factors used for calculation of international greenhouse gas (GHG) emissions in Section 5. Temporal issues associated with modeling LUC emissions are the topic of Section 6. Finally, in Section 7 we provide a step-by-step guide to using CCLUB and obtaining results.

  8. Scattering rates for leptogenesis: Damping of lepton flavour coherence and production of singlet neutrinos

    NASA Astrophysics Data System (ADS)

    Garbrecht, Björn; Glowna, Frank; Schwaller, Pedro

    2013-12-01

    Using the Closed Time Path (CTP) approach, we perform a systematic leading order calculation of the relaxation rate of flavour correlations of left-handed Standard Model leptons. This quantity is of pivotal relevance for flavoured leptogenesis in the Early Universe, and we find it to be 5.19×10-3T at T=107 GeV and 4.83×10-3T at T=1013 GeV, in substantial agreement with estimates used in previous phenomenological analyses. These values apply to the Standard Model with a Higgs-boson mass of 125 GeV. The dependence of the numerical coefficient on the temperature T is due to the renormalisation group running. The leading linear and logarithmic dependencies of the flavour relaxation rate on the gauge and top-quark couplings are extracted, such that the results presented in this work can readily be applied to extensions of the Standard Model. We also derive the production rate of light (compared to the temperature) sterile right-handed neutrinos, a calculation that relies on the same methods. We confirm most details of earlier results, but find a substantially larger contribution from the t-channel exchange of fermions.

  9. Nuclear model calculation and targetry recipe for production of 110mIn.

    PubMed

    Kakavand, T; Mirzaii, M; Eslami, M; Karimi, A

    2015-10-01

    (110m)In is potentially an important positron emitting that can be used in positron emission tomography. In this work, the excitation functions and production yields of (110)Cd(d, 2n), (111)Cd(d, 3n), (nat)Cd(d, xn), (110)Cd(p, n), (111)Cd(p, 2n), (112)Cd(p, 3n) and (nat)Cd(p, xn) reactions to produce the (110m)In were calculated using nuclear model code TALYS and compared with the experimental data. The yield of isomeric state production of (110)In was also compared with ground state production ones to reach the optimal energy range of projectile for the high yield production of metastable state. The results indicate that the (110)Cd(p, n)(110m)In is a high yield reaction with an isomeric ratio (σ(m)/σ(g)) of about 35 within the optimal incident energy range of 15-5 MeV. To make the target, cadmium was electroplated on a copper substrate in varying electroplating conditions such as PH, DC current density, temperature and time. A set of cold tests were also performed on the final sample under several thermal shocks to verify target resistance. The best electroplated cadmium target was irradiated with 15 MeV protons at current of 100 µA for one hour and the production yield of (110m)In and other byproducts were measured.

  10. Development and field deployment of an instrument to measure ozone production rates in the troposphere

    NASA Astrophysics Data System (ADS)

    Sklaveniti, S.; Locoge, N.; Dusanter, S.; Leonardis, T.; Lew, M.; Bottorff, B.; Sigler, P. S. R.; Stevens, P. S.; Wood, E. C. D.; Kundu, S.; Gentner, D. R.

    2015-12-01

    Ozone is a greenhouse gas and a primary constituent of urban smog, irritating the respiratory system and damaging the vegetation. The current understanding of ozone chemistry in the troposphere indicates that net ozone production P(O3) occurs when peroxy radicals (HO2+RO2) react with NO producing NO2, whose photolysis leads to O3 formation. P(O3) values can be calculated from peroxy radical concentrations, either from ambient measurements or box model outputs. These two estimation methods often disagree for NOx mixing ratios higher than a few ppb, questioning our ability to measure peroxy radicals under high NOx conditions or indicating that there are still unknowns in our understanding of the radical and ozone production chemistry. Direct measurements of ozone production rates will help to address this issue and improve air quality regulations. We will present the development of an instrument for direct measurements of ozone production rates (OPR). The OPR instrument consists of three parts: (i) two quartz flow tubes sampling ambient air ("Ambient" and "Reference" flow tube), (ii) an O3-to-NO2 conversion unit, and (iii) a Cavity Attenuated Phase Shift (CAPS) monitor to measure NO2. The air in the Ambient flow tube undergoes the same photochemistry as in ambient air, while the Reference flow tube is covered by a UV filter limiting the formation of ozone. Exiting the flow tubes, ozone is converted into NO2 and the sum O3+NO2 (Ox) is measured by the CAPS monitor. The difference in Ox between the two flow tubes divided by the residence time yields the Ox production rate, P(Ox). P(O3) is assumed to be equal to P(Ox) when NO2 is efficiently photolyzed during daytime. We will present preliminary results from the Indiana Radical, Reactivity and Ozone Production Intercomparison (IRRONIC) campaign in Bloomington, Indiana, during July 2015, where ozone production rates were measured by introducing various amounts of NO inside the flow tubes to investigate the ozone

  11. Role of calculated glomerular filtration rate using percutaneous nephrostomy creatinine clearance in the era of radionuclide scintigraphy

    PubMed Central

    Patil, Sunil Raghunath; Pawar, Prakash Wamanrao; Savalia, Abhishek Jaysukhbhai; Mundhe, Shankar Tanaji; Narwade, Sayalee Suryabhan; Tamhankar, Ashwin Sunil

    2017-01-01

    Context: Gates method tends to over-estimate glomerular filtration rate (GFR) in borderline functioning kidneys. We study the role of calculated GFR in these cases in decision-making regarding performing kidney-sparing surgery or nephrectomy. Aims: The aim of this study is to find the correlation between GFR calculated by percutaneous nephrostomy (PCN) urine creatinine clearance in obstructed kidneys and GFR by radionuclide scintigraphy. It also studies the role of this calculated GFR in borderline functioning kidneys. Settings and Design: Single tertiary care center; retrospective. Materials and Methods: A total of 46 patients in whom PCN was inserted as an emergency measure in an obstructed kidney and for whom diethylene-triamine-penta-acetic acid/ethylene-di-cysteine (DTPA/EC) scan was also done (Gates method) were analyzed retrospectively. PCN creatinine clearance was calculated for 3 consecutive days, and the mean value was used. Statistical Analysis Used: Pearson's correlational analysis; Chi-square test. Results: Overall strong correlation was found between the two GFR values (Pearson's r = 0.540692, P < 0.001). Totally 26 patients (56.52%) had comparable GFR values (P > 0.05). Among the 36 patients with borderline functioning kidneys, DTPA/EC scan significantly over-estimated GFR in one-third of the patients. The management plan was changed in 7 out of those patients (46.67%), with nephrectomy performed in all instead of kidney-sparing procedure. When the highest value of calculated GFR was compared, 28 patients had comparable GFRs (60.87%). Conclusions: GFR based on radionuclide scintigraphy may be insufficient for evaluation of residual renal function to determine the management of obstructed kidney with borderline function. For adequate decision-making, other factors including creatinine clearance via PCN should also be considered. Gates method tends to overestimate GFR as compared to calculated creatinine clearance at low GFR levels. PMID:28216932

  12. Determination of optimal lot size and production rate for multi-production channels with limited capacity

    NASA Astrophysics Data System (ADS)

    Huang, Yeu-Shiang; Wang, Ruei-Pei; Ho, Jyh-Wen

    2015-07-01

    Due to the constantly changing business environment, producers often have to deal with customers by adopting different procurement policies. That is, manufacturers confront not only predictable and regular orders, but also unpredictable and irregular orders. In this study, from the perspective of upstream manufacturers, both regular and irregular orders are considered in coping with the situation in which an uncertain demand is faced by the manufacturer, and a capacity confirming mechanism is used to examine such demand. If the demand is less than or equal to the capacity of the ordinary production channel, the general supply channel is utilised to fully account for the manufacturing process, but if the demand is greater than the capacity of the ordinary production channel, the contingency production channel would be activated along with the ordinary channel to satisfy the upcoming high demand. Besides, the reproductive property of the probability distribution is employed to represent the order quantity of the two types of demand. Accordingly, the optimal production rates and lot sizes for both channels are derived to provide managers with insights for further production planning.

  13. Calculation of passive sampling rates from both native PCBs and depuration compounds in indoor and outdoor environments.

    PubMed

    Persoon, Carolyn; Hornbuckle, Keri C

    2009-02-01

    Passive sampling has become a practical way of sampling persistent organic pollutants over large spatial and remote areas; however, its ease in use is also coupled with some uncertainty in calculating air concentrations from accumulated mass. Here we report a comparison study of polyurethane-foam-based passive samplers (PUF-PAS) for quantitatively determining the sampling rates of polychlorinated biphenyls (PCBs) from air. We measured both uptake of native PCBs and loss of depuration compounds and determined the sampling rates (R-values) for multiple samplers harvested at three different time periods. The uptake of native PCBs in the linear phase was similar to the loss of depuration compounds for indoor air and behaved as predicted. A single R-value of 2.6m(3)d(-1) was calculated from the mean of 12 samplers deployed indoors from three harvest dates with a range of 2.0-3.4m(3)d(-1) for both uptake of native PCBs and loss of depuration compounds. Loss of depuration compounds in outdoor air also followed the predicted linear behavior with a range of calculated R-value of 4.4-8.4m(3)d(-1). Uptake of native PCBs behavior was extremely variable, probably due to changes in ambient air concentrations and resulted in R-values of 1.6-11.5m(3)d(-1) with greater variation seen in higher chlorinated homolog groups.

  14. Beam line shielding calculations for an Electron Accelerator Mo-99 production facility

    SciTech Connect

    Mocko, Michal

    2016-05-03

    The purpose of this study is to evaluate the photon and neutron fields in and around the latest beam line design for the Mo-99 production facility. The radiation dose to the beam line components (quadrupoles, dipoles, beam stops and the linear accelerator) are calculated in the present report. The beam line design assumes placement of two cameras: infra red (IR) and optical transition radiation (OTR) for continuous monitoring of the beam spot on target during irradiation. The cameras will be placed off the beam axis offset in vertical direction. We explored typical shielding arrangements for the cameras and report the resulting neutron and photon dose fields.

  15. Using symmetry-adapted optimized sum-of-products basis functions to calculate vibrational spectra

    NASA Astrophysics Data System (ADS)

    Leclerc, Arnaud; Carrington, Tucker

    2016-01-01

    Vibrational spectra can be computed without storing full-dimensional vectors by using low-rank sum-of-products (SOP) basis functions. We introduce symmetry constraints in the SOP basis functions to make it possible to separately calculate states in different symmetry subgroups. This is done using a power method to compute eigenvalues and an alternating least squares method to optimize basis functions. Owing to the fact that the power method favours the convergence of the lowest states, one must be careful not to exclude basis functions of some symmetries. Exploiting symmetry facilitates making assignments and improves the accuracy. The method is applied to the acetonitrile molecule.

  16. 78 FR 70633 - Change in Rates and Classes of General Applicability for Competitive Products

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-11-26

    ... Service Change in Rates and Classes of General Applicability for Competitive Products; Notice #0;#0... SERVICE Change in Rates and Classes of General Applicability for Competitive Products AGENCY: Postal Service. ACTION: Notice of a change in rates of general applicability for competitive products....

  17. A particle-hole calculation for pion production in relativistic heavy-ion collisions

    NASA Astrophysics Data System (ADS)

    Norbury, J. W.; Deutchman, P. A.; Townsend, L. W.

    1985-02-01

    A differential cross section for pi-meson production in peripheral heavy-ion collisions is formulated within the context of a particle-hole model in the Tamm-Dancoff approximation. This is the first attempt at a fully quantum-mechanical particle-hole calculation for pion production in relativistic heavy-ion collisions. The particular reaction studied is an O-16 projectile colliding with a C-12 target at rest. In the projectile a linear combination of isobar-hole states is formed, with the possibility of a coherent isobar giant resonance. The target can be excited to its giant M1 resonance (J-pi = 1(+), T = 1) at 15.11 MeV, or to its isobar analog neighbors, B-12 at 13.4 MeV and N-12 at 17.5 MeV. The theory is compared to recent experimental results.

  18. A particle-hole calculation for pion production in relativistic heavy-ion collisions

    NASA Technical Reports Server (NTRS)

    Norbury, J. W.; Deutchman, P. A.; Townsend, L. W.

    1985-01-01

    A differential cross section for pi-meson production in peripheral heavy-ion collisions is formulated within the context of a particle-hole model in the Tamm-Dancoff approximation. This is the first attempt at a fully quantum-mechanical particle-hole calculation for pion production in relativistic heavy-ion collisions. The particular reaction studied is an O-16 projectile colliding with a C-12 target at rest. In the projectile a linear combination of isobar-hole states is formed, with the possibility of a coherent isobar giant resonance. The target can be excited to its giant M1 resonance (J-pi = 1(+), T = 1) at 15.11 MeV, or to its isobar analog neighbors, B-12 at 13.4 MeV and N-12 at 17.5 MeV. The theory is compared to recent experimental results.

  19. INTERWELL CONNECTIVITY AND DIAGNOSIS USING CORRELATION OF PRODUCTION AND INJECTION RATE DATA IN HYDROCARBON PRODUCTION

    SciTech Connect

    Jerry L. Jensen; Larry W. Lake; Thang D. Bui; Ali Al-Yousef; Pablo Gentil

    2004-08-01

    This report details much of the progress on inferring interwell communication from well rate fluctuations. The goal of the project was to investigate the feasibility of inferring reservoir properties through weights derived from correlations between injection and production rates. We have focused on and accomplished the following items: (1) We have identified two possible causes for the source of negative weights. These are colinearity between injectors, and nonstationarity of be production data. (2) Colinearity has been addressed through ridge regression. Though there is much to be done here, such regression represents a trade-off between a minimum variance estimator and a biased estimator. (3) We have applied the ridge regression and the original Albertoni procedure to field data from the Magnus field. (4) The entire procedure (with several options) has been codified as a spreadsheet add-in. (5) Finally, we have begun, and report on, an extension of the method to predicting oil rates. Successful completion of these items will constitute the bulk of the final year's report.

  20. A Novel Method for Calculation of Strain Energy Release Rate of Asymmetric Double Cantilever Laminated Composite Beams

    NASA Astrophysics Data System (ADS)

    Shokrieh, M. M.; Zeinedini, A.

    2014-06-01

    In this research, a novel data reduction method for calculation of the strain energy release rate ( SERR) of asymmetric double cantilever beams ( ADCB) is presented. For this purpose the elastic beam theory ( EBT) is modified and the new method is called as the modified elastic beam theory ( MEBT). Also, the ADCB specimens are modeled using ABAQUS/Standard software. Then, the initiation of delamination of ADCB specimens is modeled using the virtual crack closure technique ( VCCT). Furthermore, magnitudes of the SERR for different samples are also calculated by an available data reduction method, called modified beam theory ( MBT). Using the hand lay-up method, different laminated composite samples are manufactured by E-glass/epoxy unidirectional plies. In order to measure the SERR, all samples are tested using an experimental setup. The results determined by the new data reduction method ( MEBT) show good agreements with the results of the VCCT and the MBT.

  1. Influence of the superposition approximation on calculated effective dose rates from galactic cosmic rays at aerospace-related altitudes

    NASA Astrophysics Data System (ADS)

    Copeland, Kyle

    2015-07-01

    The superposition approximation was commonly employed in atmospheric nuclear transport modeling until recent years and is incorporated into flight dose calculation codes such as CARI-6 and EPCARD. The useful altitude range for this approximation is investigated using Monte Carlo transport techniques. CARI-7A simulates atmospheric radiation transport of elements H-Fe using a database of precalculated galactic cosmic radiation showers calculated with MCNPX 2.7.0 and is employed here to investigate the influence of the superposition approximation on effective dose rates, relative to full nuclear transport of galactic cosmic ray primary ions. Superposition is found to produce results less than 10% different from nuclear transport at current commercial and business aviation altitudes while underestimating dose rates at higher altitudes. The underestimate sometimes exceeds 20% at approximately 23 km and exceeds 40% at 50 km. Thus, programs employing this approximation should not be used to estimate doses or dose rates for high-altitude portions of the commercial space and near-space manned flights that are expected to begin soon.

  2. Enhanced capture rate for haze defects in production wafer inspection

    NASA Astrophysics Data System (ADS)

    Auerbach, Ditza; Shulman, Adi; Rozentsvige, Moshe

    2010-03-01

    Photomask degradation via haze defect formation is an increasing troublesome yield problem in the semiconductor fab. Wafer inspection is often utilized to detect haze defects due to the fact that it can be a bi-product of process control wafer inspection; furthermore, the detection of the haze on the wafer is effectively enhanced due to the multitude of distinct fields being scanned. In this paper, we demonstrate a novel application for enhancing the wafer inspection tool's sensitivity to haze defects even further. In particular, we present results of bright field wafer inspection using the on several photo layers suffering from haze defects. One way in which the enhanced sensitivity can be achieved in inspection tools is by using a double scan of the wafer: one regular scan with the normal recipe and another high sensitivity scan from which only the repeater defects are extracted (the non-repeater defects consist largely of noise which is difficult to filter). Our solution essentially combines the double scan into a single high sensitivity scan whose processing is carried out along two parallel routes (see Fig. 1). Along one route, potential defects follow the standard recipe thresholds to produce a defect map at the nominal sensitivity. Along the alternate route, potential defects are used to extract only field repeater defects which are identified using an optimal repeater algorithm that eliminates "false repeaters". At the end of the scan, the two defect maps are merged into one with optical scan images available for all the merged defects. It is important to note, that there is no throughput hit; in addition, the repeater sensitivity is increased relative to a double scan, due to a novel runtime algorithm implementation whose memory requirements are minimized, thus enabling to search a much larger number of potential defects for repeaters. We evaluated the new application on photo wafers which consisted of both random and haze defects. The evaluation procedure

  3. Cosmogenic Cl-36 production rates in meteorites and the lunar surface

    NASA Technical Reports Server (NTRS)

    Nishiizumi, K.; Arnold, J. R.; Kubik, P. W.; Elmore, D.; Reedy, R. C.

    1989-01-01

    Activity vs. depth profiles of cosmic ray produced Cl-36 were measured in metal from two cores each in the St. Severin and Jilin chondrites and in lunar core 15008. Production of Cl-36 in these samples range from high-energy reactions with Fe and Ni to low-energy reactions with Ca and K and possibly neutron-capture reactions with Cl-36. The cross sections used in the Reedy-Arnold model for neutron-induced reactions were adjusted to get production rates that fit the measured Cl-36 activities in St. Severin metal and in the lunar soil of core 15008. The Cl-36 in metal from St. Severin has a fairly flat activity-vs-depth profile, unlike most other cosmogenic nuclides in bulk samples from St. Severin, which increase in concentration with depth. In metal from Jilin, a decrease in Cl-36 was observed near its center. The length of Jilin's most recent cosmic-ray exposure was approximately 0.5 My. Lunar core 15008 has an excess in Cl-36 of about 4 dpm/kg near its surface that was produced by solar-proton-induced reactions. The calculated production rates are consistent with these measured trends in 15008.

  4. Cosmogenic /sup 36/Cl production rates in meteorites and the lunar surface

    SciTech Connect

    Nishiizumi, K.; Kubik, P.W.; Elmore, D.; Reedy, R.C.; Arnold, J.R.

    1988-01-01

    Activity-versus-depth profiles of cosmic-ray-produced /sup 36/Cl were measured in metal from two cores each in the St. Severin and Jilin chondrites and in lunar core 15008. Production of /sup 36/Cl in these samples range from high-energy reactions with Fe and Ni to low-energy reactions with Ca and K and possibly neutron-capture reactions with /sup 35/Cl. The cross sections used in the Reedy-Arnold model for neutron-induced reactions were adjusted to get production rates that fit the measured /sup 36/Cl activities in St. Severin metal and in the lunar soil of core 15008. The /sup 36/Cl in metal from St. Severin has a fairly flat activity-versus-depth profile, unlike most other cosmogenic nuclides in bulk samples from St. Severin, which increase in concentration with depth. In metal from Jilin, a decrease in /sup 36/Cl was observed near its center. The length of Jilin's most recent cosmic-ray exposure was /approximately/0.5 My. Lunar core 15008 has an excess in /sup 36/Cl of about 4 dpm/kg near its surface that was produced by solar-proton-induced reactions. The calculated production rates are consistent with these measured trends in 15008. 39 refs., 4 figs., 3 tabs.

  5. An alternative radiometric method for calculating the sedimentation rates: application to an intertidal region (SW of Spain).

    PubMed

    Ligero, R A; Casas-Ruiz, M; Barrera, M; Barbero, L; Meléndez, M J

    2010-09-01

    A new method using the inventory determined for the activity of the radionuclide (137)Cs, coming from global radioactive fallout has been utilised to calculate the sedimentation rates. The method has been applied in a wide intertidal region in the Bay of Cádiz Natural Park (SW Spain). The sedimentation rates estimated by the (137)Cs inventory method ranged from 0.26 cm/year to 1.72 cm/year. The average value of the sedimentation rate obtained is 0.59 cm/year, and this rate has been compared with those resulting from the application of the (210)Pb dating technique. A good agreement between the two procedures has been found. From the study carried out, it has been possible for the first time, to draw a map of sedimentation rates for this zone where numerous physico-chemical, oceanographic and ecological studies converge, since it is situated in a region of great environmental interest. This area, which is representative of common environmental coastal scenarios, is particularly sensitive to perturbations related to climate change, and the results of the study will allow to make short and medium term evaluations of this change.

  6. Optimal Spray Application Rates for Ornamental Nursery Liner Production

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Spray deposition and coverage at different application rates for nursery liners of different sizes were investigated to determine the optimal spray application rates. Experiments were conducted on two and three-year old red maple liners. A traditional hydraulic sprayer with vertical booms was used t...

  7. Target Heart Rate Calculator

    MedlinePlus

    ... try exercising within the upper range of your target zone. (If just beginning an exercise program, consult your doctor first.) Source: National Heart, Lung, and Blood Institute ... Information Cancer Prevention & Detection Cancer Basics Signs & Symptoms of Cancer Treatments & Side ...

  8. Comparison of calculated and experimentally resolved rate constants for excitation energy transfer in C-phycocyanin. 2. Trimers

    SciTech Connect

    Debreczeny, M.F.; Sauer, K.; Zhou, J.; Bryant, D.A.

    1995-05-18

    Resolution of the absorption spectrum of the {beta}{sub 155} chromophore in C-phycocyanin (PC) trimers is achieved by comparison of the steady state absorption spectra of ({alpha}{sup PC}{beta}{sup PC}){sub 3} and ({alpha}{sup PC}{beta}{sup *}){sub 3}. Comparison of the anisotropy decays of ({alpha}{sup PC}{beta}{sup PC}){sub 3} and ({alpha}{sup PC}{beta}{sup *}){sub 3} also greatly aids in the assignment of the dominant kinetic processes in PC trimers. A comparison is made of calculated Foerster rate constants for energy transfer with those rate constants resolved experimentally in the PC trimers. 35 refs.., 10 figs., 2 tabs.

  9. Comparison of calculated and experimentally resolved rate constants for excitation energy transfer in C-phycocyanin. 1. Monomers

    SciTech Connect

    Debreczeny, M.P.; Sauer, K.; Zhou, J.; Bryant, D.A.

    1995-05-18

    Rate constants for excitation energy transfer in light-harvesting protein, C-phycocyanin (PC), in the monomeric aggregation state, isolated from the cyanobacterium cynechococcus sp. PCC 7002, are calculated, using Foerster theory and compared with the results of time-resolved fluorescence measurements. The assignments of the energy-transfer rate constants in PC monomers are confirmed here by time-resolved fluorescence anisotropy measurements of the PC monomers isolated from both the wild-type and a mutant strain (cpcB/C155S) whose PC is missing the {beta}{sub 155} chromophore. It is concluded that the Foerster model of resonant energy transfer in the weak coupling limit successfully describes the dominant energy-transfer processes in this protein in the monomeric state. 31 refs., 3 figs., 4 tabs.

  10. Actinometric measurements and theoretical calculations of j/O3/, the rate of photolysis of ozone to O/1D/

    NASA Technical Reports Server (NTRS)

    Dickerson, R. R.; Stedman, D. H.; Chameides, W. L.; Crutzen, P. J.; Fishman, J.

    1979-01-01

    The paper presents an experimental technique which measures j/O3-O(1-D)/, the rate of solar photolysis of ozone to singlet oxygen atoms. It is shown that a flow actinometer carries dilute O3 in N2O into direct sunlight where the O(1D) formed reacts with N2O to form NO which chemiluminescence detects, with a time resolution of about one minute. Measurements indicate a photolysis rate of 1.2 (+ or - .2) x 10 to the -5/s for a cloudless sky, 45 deg zenith angle, 0.345 cm ozone column and zero albedo. Finally, ground level results compare with theoretical calculations based on the UV actinic flux as a function of ozone column and solar zenith angle.

  11. Specific light uptake rates can enhance astaxanthin productivity in Haematococcus lacustris.

    PubMed

    Lee, Ho-Sang; Kim, Z-Hun; Park, Hanwool; Lee, Choul-Gyun

    2016-05-01

    Lumostatic operation was applied for efficient astaxanthin production in autotrophic Haematococcus lacustris cultures using 0.4-L bubble column photobioreactors. The lumostatic operation in this study was performed with three different specific light uptake rates (q(e)) based on cell concentration, cell projection area, and fresh weight as one-, two- and three-dimensional characteristics values, respectively. The q(e) value from the cell concentration (q(e1D)) obtained was 13.5 × 10⁻⁸ μE cell⁻¹ s⁻¹, and the maximum astaxanthin concentration was increased to 150 % compared to that of a control with constant light intensity. The other optimum q e values by cell projection area (q(e2D)) and fresh weight (q( e3D)) were determined to be 195 μE m⁻² s⁻¹ and 10.5 μE g⁻¹ s⁻¹ for astaxanthin production, respectively. The maximum astaxanthin production from the lumostatic cultures using the parameters controlled by cell projection area (2D) and fresh weight (3D) also increased by 36 and 22% over that of the controls, respectively. When comparing the optimal q e values among the three different types, the lumostatic cultures using q(e) based on fresh weight showed the highest astaxanthin productivity (22.8 mg L⁻¹ day⁻¹), which was a higher level than previously reported. The lumostatic operations reported here demonstrated that more efficient and effective astaxanthin production was obtained by H. lacustris than providing a constant light intensity, regardless of which parameter is used to calculate the specific light uptake rate.

  12. Radio-frequency wave enhanced runaway production rate

    SciTech Connect

    Chan, V.S.; McClain, F.W.

    1983-06-01

    Enhancement of runaway electron production (over that of an Ohmic discharge) can be achieved by the addition of radio-frequency waves. This effect is studied analytically and numerically using a two-dimensional Fokker--Planck quasilinear equation.

  13. The Hydroxyl Radical Reaction Rate Constant and Products of Cyclohexanol

    DTIC Science & Technology

    2007-10-01

    atmospheric degradation mechanism. The observed products and their formation yields were: cyclohexanone (0.55 0.06), hexanedial (0.32 0.15), 3...COL, tridecane, and decane were obtained from Aldrich with a purity of 99%. Pentanal (99%) and cyclohexanone (99%) were purchased through Ultra... Cyclohexanone (CON) was the only OH COL re- action product observed during the initial kinetic ex- periments. Its presence was also detected later using

  14. Survey of Productivity Rates Used for Highway Construction

    DTIC Science & Technology

    1988-01-01

    changes are offered. Also included in this paper are discussions concerning the importance of productivity in the construction industry , and the...SUPPLEMENTAL BIBLIOGRAPHY. .-.......... 149 Vg • 1 iv V, LIST OF FIGURES ’ Figure 1.. 1986 Productivity Increases For Various U.S. Industries . . .. . ........ 6...1.2 Project Participants .... .......... 8 1.3 Reasons For Nonproductive Time In The • Construction Industry ..... .......... 9 3.1a UF Survey

  15. Calculated volatilization rates of fuel oxygenate compounds and other gasoline-related compounds from rivers and streams

    USGS Publications Warehouse

    Pankow, J.F.; Rathbun, R.E.; Zogorski, J.S.

    1996-01-01

    Large amounts of the 'fuel-oxygenate' compound methyl-tert-butyl ether (MTBE) are currently being used in gasoline to reduce carbon monoxide and ozone in urban air and to boost fuel octane. Because MTBE can be transported to surface waters in various ways, established theory was used to calculate half-lives for MTBE volatilizing from flowing surface waters. Similar calculations were made for benzene as a representative of the 'BTEX' group of compounds (benzene, toluene, ethyl benzene, and the xylenes), and for tert-butyl alcohol (TBA). The calculations were made as a function of the mean flow velocity u (m/day), the mean flow depth h (m), the ambient temperature, and the wind speed. In deep, slow-moving flows, MTBE volatilizes at rates which are similar to those for the BTEX compounds. In shallow, fast-moving flows, MTBE volatilizes more slowly than benzene, though in such flows both MTBE and benzene volatilize quickly enough that these differences may often not have much practical significance. TBA was found to be essentially nonvolatile from water.

  16. BDflex: A method for efficient treatment of molecular flexibility in calculating protein-ligand binding rate constants from Brownian dynamics simulations

    NASA Astrophysics Data System (ADS)

    Greives, Nicholas; Zhou, Huan-Xiang

    2012-10-01

    A method developed by Northrup et al. [J. Chem. Phys. 80, 1517 (1984)], 10.1063/1.446900 for calculating protein-ligand binding rate constants (ka) from Brownian dynamics (BD) simulations has been widely used for rigid molecules. Application to flexible molecules is limited by the formidable computational cost to treat conformational fluctuations during the long BD simulations necessary for ka calculation. Here, we propose a new method called BDflex for ka calculation that circumvents this problem. The basic idea is to separate the whole space into an outer region and an inner region, and formulate ka as the product of kE and bar η _d, which are obtained by separately solving exterior and interior problems. kE is the diffusion-controlled rate constant for the ligand in the outer region to reach the dividing surface between the outer and inner regions; in this exterior problem conformational fluctuations can be neglected. bar η _d is the probability that the ligand, starting from the dividing surface, will react at the binding site rather than escape to infinity. The crucial step in reducing the determination of bar η _d to a problem confined to the inner region is a radiation boundary condition imposed on the dividing surface; the reactivity on this boundary is proportional to kE. By confining the ligand to the inner region and imposing the radiation boundary condition, we avoid multiple-crossing of the dividing surface before reaction at the binding site and hence dramatically cut down the total simulation time, making the treatment of conformational fluctuations affordable. BDflex is expected to have wide applications in problems where conformational fluctuations of the molecules are crucial for productive ligand binding, such as in cases where transient widening of a bottleneck allows the ligand to access the binding pocket, or the binding site is properly formed only after ligand entrance induces the closure of a lid.

  17. An approach to remote monitoring of heart rate variability (HRV) using microwave radar during a calculation task.

    PubMed

    Suzuki, Satoshi; Matsui, Takemi; Sugawara, Keitaro; Asao, Takafumi; Kotani, Kentaro

    2011-01-01

    Recently, nonrestrictive and noninvasive sensing techniques to measure vital signs have been actively researched and developed. This study aimed to develop a prototype system to monitor cardiac activity using microwave radar without making contact with the body and without removing clothing--namely, a completely noncontact, remote monitoring system. In addition, heart rate and changes in heart rate variability (HRV) during simple mental arithmetic tasks were observed with the prototype system. The prototype system has a microwave Doppler radar antenna with 24 GHz frequency and approximately 7 mW output power. The experiments were conducted with seven subjects (23.00±0.82 years). We found that the prototype system captured heart rate and HRV precisely. The strong relationship between the heart rates during tasks (r=0.96), LF (cross-correlation=0.76), and LF/HF (cross-correlation=0.73) of HRV calculated from the prototype system and from electrocardiograph (ECG) measurements were confirmed. The proposed completely noncontact, remote method appears promising for future monitoring of cardiac activity as an indicator of changes in mental workload in workplaces.

  18. Interwell Connectivity and Diagnosis Using Correlation of Production and Injection Rate Data in Hydrocarbon Production

    SciTech Connect

    Jerry L. Jensen; Larry W. Lake; Ali Al-Yousef; Dan Weber; Ximing Liang; T.F. Edgar; Nazli Demiroren; Danial Kaviani

    2007-03-31

    This report details progress and results on inferring interwell communication from well rate fluctuations. Starting with the procedure of Albertoni and Lake (2003) as a foundation, the goal of the project was to develop further procedures to infer reservoir properties through weights derived from correlations between injection and production rates. A modified method, described in Yousef and others (2006a,b), and herein referred to as the 'capacitance model', is the primary product of this research project. The capacitance model (CM) produces two quantities, {lambda} and {tau}, for each injector-producer well pair. For the CM, we have focused on the following items: (1) Methods to estimate {lambda} and {tau} from simulated and field well rates. The original method uses both non-linear and linear regression and lacks the ability to include constraints on {lambda} and {tau}. The revised method uses only non-linear regression, permitting constraints to be included as well as accelerating the solution so that problems with large numbers of wells are more tractable. (2) Approaches to integrate {lambda} and {tau} to improve connectivity evaluations. Interpretations have been developed using Lorenz-style and log-log plots to assess heterogeneity. Testing shows the interpretations can identify whether interwell connectivity is controlled by flow through fractures, high-permeability layers, or due to partial completion of wells. Applications to the South Wasson and North Buck Draw Fields show promising results. (3) Optimization of waterflood injection rates using the CM and a power law relationship for watercut to maximize economic return. Tests using simulated data and a range of oil prices show the approach is working. (4) Investigation of methods to increase the robustness of {lambda} and {tau} estimates. Human interventions, such as workovers, also cause rate fluctuations and can be misinterpreted by the model if bottom hole pressure data are not available. A revised

  19. Effects of chemical compositions and ensiling on the biogas productivity and degradation rates of agricultural and food processing by-products.

    PubMed

    Kafle, Gopi Krishna; Kim, Sang Hun

    2013-08-01

    The objective of this study was to investigate the effects of chemical compositions and ensiling on the biogas productivity and degradation rates of agricultural and food processing by-products (AFPBPs) using the biogas potential test. The AFPBPs were classified based on their chemical compositions (i.e., carbohydrate, protein and fat contents). The biogas and methane potentials of AFPBPs were calculated to range from 450 to 777 mL/g volatile solids (VS) and 260-543 mL/g VS, respectively. AFPBPs with high fat and protein contents produced significantly higher amounts of biogas than AFPBPs with high carbohydrate and low fat contents. The degradation rate was faster for AFPBPs with high carbohydrate contents compared to AFPBPs with high protein and fat contents. The lag phase and biogas production duration were lower when using ensiled AFPBPs than when using nonsilage AFPBPs. Among the four different silages tested, two silages significantly improved biogas production compared to the nonsilage AFPBPs.

  20. Simplified Two-Time Step Method for Calculating Combustion Rates and Nitrogen Oxide Emissions for Hydrogen/Air and Hydorgen/Oxygen

    NASA Technical Reports Server (NTRS)

    Molnar, Melissa; Marek, C. John

    2005-01-01

    A simplified single rate expression for hydrogen combustion and nitrogen oxide production was developed. Detailed kinetics are predicted for the chemical kinetic times using the complete chemical mechanism over the entire operating space. These times are then correlated to the reactor conditions using an exponential fit. Simple first order reaction expressions are then used to find the conversion in the reactor. The method uses a two-time step kinetic scheme. The first time averaged step is used at the initial times with smaller water concentrations. This gives the average chemical kinetic time as a function of initial overall fuel air ratio, temperature, and pressure. The second instantaneous step is used at higher water concentrations (> 1 x 10(exp -20) moles/cc) in the mixture which gives the chemical kinetic time as a function of the instantaneous fuel and water mole concentrations, pressure and temperature (T4). The simple correlations are then compared to the turbulent mixing times to determine the limiting properties of the reaction. The NASA Glenn GLSENS kinetics code calculates the reaction rates and rate constants for each species in a kinetic scheme for finite kinetic rates. These reaction rates are used to calculate the necessary chemical kinetic times. This time is regressed over the complete initial conditions using the Excel regression routine. Chemical kinetic time equations for H2 and NOx are obtained for H2/air fuel and for the H2/O2. A similar correlation is also developed using data from NASA s Chemical Equilibrium Applications (CEA) code to determine the equilibrium temperature (T4) as a function of overall fuel/air ratio, pressure and initial temperature (T3). High values of the regression coefficient R2 are obtained.

  1. Summary of Simplified Two Time Step Method for Calculating Combustion Rates and Nitrogen Oxide Emissions for Hydrogen/Air and Hydrogen/Oxygen

    NASA Technical Reports Server (NTRS)

    Marek, C. John; Molnar, Melissa

    2005-01-01

    A simplified single rate expression for hydrogen combustion and nitrogen oxide production was developed. Detailed kinetics are predicted for the chemical kinetic times using the complete chemical mechanism over the entire operating space. These times are then correlated to the reactor conditions using an exponential fit. Simple first order reaction expressions are then used to find the conversion in the reactor. The method uses a two time step kinetic scheme. The first time averaged step is used at the initial times with smaller water concentrations. This gives the average chemical kinetic time as a function of initial overall fuel air ratio, temperature, and pressure. The second instantaneous step is used at higher water concentrations (greater than l x 10(exp -20)) moles per cc) in the mixture which gives the chemical kinetic time as a function of the instantaneous fuel and water mole concentrations, pressure and temperature (T(sub 4)). The simple correlations are then compared to the turbulent mixing times to determine the limiting properties of the reaction. The NASA Glenn GLSENS kinetics code calculates the reaction rates and rate constants for each species in a kinetic scheme for finite kinetic rates. These reaction rates are used to calculate the necessary chemical kinetic times. This time is regressed over the complete initial conditions using the Excel regression routine. Chemical kinetic time equations for H2 and NOx are obtained for H2/Air fuel and for H2/O2. A similar correlation is also developed using data from NASA's Chemical Equilibrium Applications (CEA) code to determine the equilibrium temperature (T(sub 4)) as a function of overall fuel/air ratio, pressure and initial temperature (T(sub 3)). High values of the regression coefficient R squared are obtained.

  2. Ab initio and RRKM calculations for multichannel rate constants of the C{sub 2}H{sub 3}+O{sub 2} reaction

    SciTech Connect

    Mebel, A.M.; Diau, E.W.G.; Lin, M.C.; Morokuma, K.

    1996-10-09

    A potential energy surface for the reaction of vinyl radical with molecular oxygen has been studied using the ab initio G2M(RCC, MP2) method. The most favorable reaction pathway leading to the major CHO+CH{sub 2}O products is described. The C{sub 2}H{sub 3}O+O products can be formed by elimination of the oxygen atom from C{sub 2}H{sub 3}OO via TS 23, which is by 7.8 kcal/mol lower in energy than the reactants, but by 6.5 kcal/mol higher than TS 9`. The hydrogen migration in 1` gives rise to another significant product channel: C{sub 2}H{sub 3}+O{sub 2} {yields} 1` {yields} TS 25` {yields} C{sub 2}H{sub 2}+O{sub 2}H, with TS 25` lying below C{sub 2}H{sub 3}+O{sub 2} by 3.5 kcal/mol. Multichannel RRKM calculations have been carried out for the total and individual rate constants for various channels using the G2M(RCC, MP2) energetics and molecular parameters of the intermediates and transition states. The computed low pressure reaction rate constant is in quantitative agreement with experiment. At atmospheric pressure, the title reaction is dominated by the stabilization of vinylperoxy radical C{sub 2}H{sub 3}OO at room temperature. In the 500-900 K temperature range, the CHO+CH{sub 2}O channel has the highest rate constant, and at T >= 900 K, C{sub 2}H{sub 3}O+O are the major products. At very high temperatures, the channel producing C{sub 2}H{sub 2} + O{sub 2}H becomes competitive. 15 refs., 3 figs., 4 tabs.

  3. The Water Production Rate of Comet 2009 P1 (Garradd) throughout the 2011-2012 Apparition

    NASA Astrophysics Data System (ADS)

    Combi, Michael R.; Mäkinen, J. T. T.; Bertaux, J.; Quémerais, E.; Ferron, S.

    2012-10-01

    The all-sky hydrogen Lyman-alpha camera, SWAN (Solar Wind Anisotropies), on the SOlar and Heliospheric Observatory (SOHO) satellite made observations of the hydrogen coma of comet 2009 P1 (Garradd) throughout its apparition from August 15, 2011 through April 6, 2012. SOHO has been operating in a halo orbit around the Earth-Sun L1 Lagrange point since its launch in late 1995. Most water vapor produced by the comet is ultimately photodissociated into two H atoms and one O atom producing a huge atomic hydrogen coma that is routinely observed in the daily full-sky SWAN images in comets of sufficient brightness. Water production rates were calculated from 117 images over 8 months of the apparition using our time-resolved model (Mäkinen & Combi, 2005, Icarus 177, 217), yielding about 1 observation every 2 days on the average. The activity during much of the pre-perihelion leg was dominated by likely seasonal variability rather than a consistent increasing trend with decreasing heliocentric distance and varied between 1 and 3 x 1029 s-1. A single peak value for the water production rate (4 x 1029 s-1) was found on November 3, 2011, 50 days before perihelion. On the other hand during the post-perihelion leg the production rate decreased rather consistently from 2 x 1029 s-1at perihelion, approximately as r-4.6, where r is the heliocentric distance. The overall shape of the variation with time over the apparition shows many of the same general features as the visual light curve of Yoshida (http://www.aerith.net/comet/catalog/index-T-earth.html). SOHO is an international cooperative mission between ESA and NASA. Support from grant NNX11AH50G from the NASA Planetary Astronomy Program is also acknowledged.

  4. Cross section calculations for subthreshold pion production in peripheral heavy-ion collisions

    NASA Technical Reports Server (NTRS)

    Norbury, J. W.; Cucinotta, F. A.; Deutchman, P. A.; Townsend, L. W.

    1986-01-01

    Total cross sections angular distributions, and spectral distributions for the exclusive production of charged and neutral subthreshold pions produced in peripheral nucleus-nucleus collisions are calculated by using a particle-hole formalism. The pions result from the formation and decay of an isobar giant resonance state formed in a C-12 nucleus. From considerations of angular momentum conservation and for the sake of providing a unique experimental signature, the other nucleus, chosen for this work to be C-12 also, is assumed to be excited to one of its isovector (1+) giant resonance states. The effects of nucleon recoil by the pion emission are included, and Pauli blocking and pion absorption effects are studied by varying the isobar width. Detailed comparisons with experimental subthreshold pion data for incident energies between 35 and 86 MeV/nucleon are made.

  5. Comparison of optics and electronics for the calculation of matrix-vector products

    NASA Technical Reports Server (NTRS)

    Gary, C. K.

    1992-01-01

    Optical processors are attractive because of their ability to perform massively parallel operations such as matrix vector products. The inherently analog nature of optical calculations requires that optical processors be based on analog computations. While the speed at which such analog operations can be performed as well as the natural parallelism of optical systems are great advantages of optical processors, the analog representation of values severely limits the achievable accuracy. Furthermore, optical processors are limited by the need to convert information to and from the intensity of light. Digitization can be used to increase the accuracy of optical matrix-vector processors, but causes a severe reduction in speed. This paper compares the throughput and power requirements of optical and electronic processors, showing that optical matrix-vector processors can provide a greater number of operations/Watt than conventional electronics.

  6. Quantifying melt production and degassing rate at mid-ocean ridges from global mantle convection models with plate motion history

    NASA Astrophysics Data System (ADS)

    Li, Mingming; Black, Benjamin; Zhong, Shijie; Manga, Michael; Rudolph, Maxwell L.; Olson, Peter

    2016-07-01

    The Earth's surface volcanism exerts first-order controls on the composition of the atmosphere and the climate. On Earth, the majority of surface volcanism occurs at mid-ocean ridges. In this study, based on the dependence of melt fraction on temperature, pressure, and composition, we compute melt production and degassing rate at mid-ocean ridges from three-dimensional global mantle convection models with plate motion history as the surface velocity boundary condition. By incorporating melting in global mantle convection models, we connect deep mantle convection to surface volcanism, with deep and shallow mantle processes internally consistent. We compare two methods to compute melt production: a tracer method and an Eulerian method. Our results show that melt production at mid-ocean ridges is mainly controlled by surface plate motion history, and that changes in plate tectonic motion, including plate reorganizations, may lead to significant deviation of melt production from the expected scaling with seafloor production rate. We also find a good correlation between melt production and degassing rate beneath mid-ocean ridges. The calculated global melt production and CO2 degassing rate at mid-ocean ridges varies by as much as a factor of 3 over the past 200 Myr. We show that mid-ocean ridge melt production and degassing rate would be much larger in the Cretaceous, and reached maximum values at ˜150-120 Ma. Our results raise the possibility that warmer climate in the Cretaceous could be due in part to high magmatic productivity and correspondingly high outgassing rates at mid-ocean ridges during that time.

  7. High rate of methane leakage from natural gas production

    NASA Astrophysics Data System (ADS)

    Balcerak, Ernie

    2013-10-01

    Natural gas production is growing as the United States seeks domestic sources of relatively clean energy. Natural gas combustion produces less carbon dioxide emissions than coal or oil for the amount of energy produced. However, one source of concern is that some natural gas leaks to the atmosphere from the extraction point, releasing methane, a potent greenhouse gas.

  8. Calculation of rate constants for dissociative attachment of low-energy electrons to hydrogen halides HCl, HBr, and HI and their deuterated analogs

    SciTech Connect

    Houfek, Karel; Cizek, Martin; Horacek, Jiri

    2002-12-01

    Calculations of rate constants for the process of dissociative attachment of low-energy electrons to hydrogen halides HCl, HBr, and HI and for the reverse process of associative detachment based on the nonlocal resonance model are reported. The calculated data are of importance for the modeling of plasma processes, environmental chemistry, etc. The calculated dissociative attachment rate constants are found to be in good agreement with existing experimental data. It is shown that at low temperatures the rate constants are very sensitive to small changes of the parameters of the nonlocal resonance model used for the calculation of the rate constants and represent a severe test of the theory. The isotopic effect and its dependence on the temperature is also discussed. The calculations of rate constants for the reverse process of associative detachment are also reported and discussed.

  9. Weak Interaction Rates of sd-SHELL Nuclei in Stellar Environments Calculated in the Proton-Neutron Quasiparticle Random-Phase Approximation

    NASA Astrophysics Data System (ADS)

    Nabi, J.-U.; Klapdor-Kleingrothaus, H. V.

    1999-03-01

    Allowed weak interaction rates for sd-shell nuclei in stellar environment are calculated using a generalized form of proton-neutron quasi-particle RPA model with separable Gamow-Teller forces. The calculated capture and decay rates take into consideration the latest experimental energy levels and ft-value compilations. Weak rates calculated are tabulated at the same points of density and temperature as those of Oda et al. [Atomic Data and Nuclear Data Tables 56, 231 (1994)]. The results are also compared with earlier works. Particle emission processes from excited states, previously ignored, are taken into account and are found to significantly affect some β decay rates.

  10. 19 CFR 351.406 - Calculation of normal value if sales are made at less than cost of production.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... Price, Fair Value, and Normal Value § 351.406 Calculation of normal value if sales are made at less than cost of production. (a) Introduction. In determining normal value, the Secretary may disregard sales of... 19 Customs Duties 3 2013-04-01 2013-04-01 false Calculation of normal value if sales are made...

  11. 19 CFR 351.406 - Calculation of normal value if sales are made at less than cost of production.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... Price, Fair Value, and Normal Value § 351.406 Calculation of normal value if sales are made at less than cost of production. (a) Introduction. In determining normal value, the Secretary may disregard sales of... 19 Customs Duties 3 2014-04-01 2014-04-01 false Calculation of normal value if sales are made...

  12. 19 CFR 351.406 - Calculation of normal value if sales are made at less than cost of production.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... Price, Fair Value, and Normal Value § 351.406 Calculation of normal value if sales are made at less than cost of production. (a) Introduction. In determining normal value, the Secretary may disregard sales of... 19 Customs Duties 3 2011-04-01 2011-04-01 false Calculation of normal value if sales are made...

  13. 19 CFR 351.406 - Calculation of normal value if sales are made at less than cost of production.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... Price, Fair Value, and Normal Value § 351.406 Calculation of normal value if sales are made at less than cost of production. (a) Introduction. In determining normal value, the Secretary may disregard sales of... 19 Customs Duties 3 2012-04-01 2012-04-01 false Calculation of normal value if sales are made...

  14. 19 CFR 351.406 - Calculation of normal value if sales are made at less than cost of production.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Price, Fair Value, and Normal Value § 351.406 Calculation of normal value if sales are made at less than cost of production. (a) Introduction. In determining normal value, the Secretary may disregard sales of... 19 Customs Duties 3 2010-04-01 2010-04-01 false Calculation of normal value if sales are made...

  15. Optimization of pilot high rate algal ponds for simultaneous nutrient removal and lipids production.

    PubMed

    Arbib, Zouhayr; de Godos, Ignacio; Ruiz, Jesús; Perales, José A

    2017-07-01

    Special attention is required to the removal of nitrogen and phosphorous in treated wastewaters. Although, there are a wide range of techniques commercially available for nutrient up-take, these processes entail high investment and operational costs. In the other hand, microalgae growth can simultaneously remove inorganic constituents of wastewater and produce energy rich biomass. Among all the cultivation technologies, High Rate Algae Ponds (HRAPs), are accepted as the most appropriate system. However, the optimization of the operation that maximizes the productivity, nutrient removal and lipid content in the biomass generated has not been established. In this study, the effect of two levels of depth and the addition of CO2 were evaluated. Batch essays were used for the calculation of the kinetic parameters of microbial growth that determine the optimum conditions for continuous operation. Nutrient removal and lipid content of the biomass generated were analyzed. The best conditions were found at depth of 0.3m with CO2 addition (biomass productivity of 26.2gTSSm(-2)d(-1) and a lipid productivity of 6.0glipidsm(-2)d(-1)) in continuous mode. The concentration of nutrients was in all cases below discharge limits established by the most restrictive regulation for wastewater discharge.

  16. HyPEP-FY 07 Annual Report: A Hydrogen Production Plant Efficiency Calculation Program

    SciTech Connect

    Chang Oh

    2007-09-01

    The Very High Temperature Gas-Cooled Reactor (VHTR) coupled to the High Temperature Steam Electrolysis (HTSE) process is one of two reference integrated systems being investigated by the U.S. Department of Energy and Idaho National Laboratory for the production of hydrogen. In this concept the VHTR outlet temperature of 900 °C provides thermal energy and high efficiency electricity for the electrolysis of steam in the HTSE process. In the second reference system the Sulfur Iodine (SI) process is coupled to the VHTR to produce hydrogen thermochemically. In the HyPEP project we are investigating and characterizing these two reference systems with respect to production, operability, and safety performance criteria. Under production, plant configuration and working fluids are being studied for their effect on efficiency. Under operability, control strategies are being developed with the goal of maintaining equipment within operating limits while meeting changes in demand. Safety studies are to investigate plant response for equipment failures. Specific objectives in FY07 were (1) to develop HyPEP Beta and verification and validation (V&V) plan, (2) to perform steady state system integration, (3) to perform parametric studies with various working fluids and power conversion unit (PCU) configurations, (4) the study of design options such as pressure, temperature, etc. (5) to develop a control strategy and (6) to perform transient analyses for plant upsets, control strategy, etc for hydrogen plant with PCU. This report describes the progress made in FY07 in each of the above areas. (1) The HyPEP code numeric scheme and Graphic User Interface have been tested and refined since the release of the alpha version a year ago. (2) The optimal size and design condition for the intermediate heat exchanger, one of the most important components for integration of the VHTR and HTSE plants, was estimated. (3) Efficiency calculations were performed for a variety of working fluids for

  17. Effects of culture (China vs. US) and task on perceived hazard: Evidence from product ratings, label ratings, and product to label matching.

    PubMed

    Lesch, Mary F; Rau, Pei-Luen Patrick; Choi, YoonSun

    2016-01-01

    In the current study, 44 Chinese and 40 US college students rated their perceived hazard in response to warning labels and products and attempted to match products with warning labels communicating the same level of hazard. Chinese participants tended to provide lower ratings of hazard in response to labels, but hazard perceived in response to products did not significantly differ as a function of culture. When asked to match a product with a warning label, Chinese participants' hazard perceptions appeared to be better calibrated, than did US participants', across products and labels. The results are interpreted in terms of constructivist theory which suggests that risk perceptions vary depending on the "frame of mind" evoked by the environment/context. Designers of warnings must be sensitive to the fact that product users' cognitive representations develop within a culture and that risk perceptions will vary based on the context in which they are derived.

  18. High hydrogen production rate of microbial electrolysis cell (MEC) with reduced electrode spacing.

    PubMed

    Cheng, Shaoan; Logan, Bruce E

    2011-02-01

    Practical applications of microbial electrolysis cells (MECs) require high hydrogen production rates and a compact reactor. These goals can be achieved by reducing electrode spacing but high surface area anodes are needed. The brush anode MEC with electrode spacing of 2 cm had a higher hydrogen production rate and energy efficiency than an MEC with a flat cathode and a 1-cm electrode spacing. The maximum hydrogen production rate with a 2 cm electrode spacing was 17.8 m(3)/m(3)d at an applied voltage of E(ap)=1 V. Reducing electrode spacing increased hydrogen production rates at the lower applied voltages, but not at the higher (>0.6 V) applied voltages. These results demonstrate that reducing electrode spacing can increase hydrogen production rate, but that the closest electrode spacing do not necessarily produce the highest possible hydrogen production rates.

  19. Calculation of. beta. -ray absorbed dose rate for /sup 131/I applied to the inflorescence of Tradescantia

    SciTech Connect

    Bingo, K.; Tano, S.; Numakunai, T.; Yoshida, Y.; Yamaguchi, H.

    1981-03-01

    Effects of /sup 131/I applied to the inflorescence on the induction of somatic mutations in Tradescantia stamen hairs were previously investigated, and the doubling dose (activity) was estimated to be 4 nCi. In the present paper, the absorbed dose rate in stamen hairs of Tradescantia for ..beta.. rays from the applied /sup 131/I was calculated. The doubling dose for the /sup 131/I (4 nCi) applied to the inflorescence was estimated to be higher than 0.3 rad (assuming uniform distribution of /sup 131/I on the surface of the buds and assuming that the shape of the buds was a sphere) and lower than 1.0 rad.

  20. Ring-Polymer Molecular Dynamics Rate Coefficient Calculations for Insertion Reactions: X + H2 → HX + H (X = N, O).

    PubMed

    Li, Yongle; Suleimanov, Yury V; Guo, Hua

    2014-02-20

    The thermal rate constants of two prototypical insertion-type reactions, namely, N/O + H2 → NH/OH + H, are investigated with ring polymer molecular dynamics (RPMD) on full-dimensional potential energy surfaces using recently developed RPMDrate code. It is shown that the unique ability of the RPMD approach among the existing theoretical methods to capture the quantum effects, e.g., tunneling and zero-point energy, as well as recrossing dynamics quantum mechanically with ring-polymer trajectories leads to excellent agreement with rigorous quantum dynamics calculations. The present result is encouraging for future applications of the RPMD method and the RPMDrate code to complex-forming chemical reactions involving polyatomic reactants.

  1. Convergence rate calculation of simultaneous iterative reconstruction technique algorithm for diffuse optical tomography image reconstruction: A feasibility study

    NASA Astrophysics Data System (ADS)

    Chuang, Ching-Cheng; Tsai, Jui-che; Chen, Chung-Ming; Yu, Zong-Han; Sun, Chia-Wei

    2012-04-01

    Diffuse optical tomography (DOT) is an emerging technique for functional biological imaging. The imaging quality of DOT depends on the imaging reconstruction algorithm. The SIRT has been widely used for DOT image reconstruction but there is no criterion to truncate based on any kind of residual parameter. The iteration loops will always be decided by experimental rule. This work presents the CR calculation that can be great help for SIRT optimization. In this paper, four inhomogeneities with various shapes of absorption distributions are simulated as imaging targets. The images are reconstructed and analyzed based on the simultaneous iterative reconstruction technique (SIRT) method. For optimization between time consumption and imaging accuracy in reconstruction process, the numbers of iteration loop needed to be optimized with a criterion in algorithm, that is, the root mean square error (RMSE) should be minimized in limited iterations. For clinical applications of DOT, the RMSE cannot be obtained because the measured targets are unknown. Thus, the correlations between the RMSE and the convergence rate (CR) in SIRT algorithm are analyzed in this paper. From the simulation results, the parameter CR reveals the related RMSE value of reconstructed images. The CR calculation offers an optimized criterion of iteration process in SIRT algorithm for DOT imaging. Based on the result, the SIRT can be modified with CR calculation for self-optimization. CR reveals an indicator of SIRT image reconstruction in clinical DOT measurement. Based on the comparison result between RMSE and CR, a threshold value of CR (CRT) can offer an optimized number of iteration steps for DOT image reconstruction. This paper shows the feasibility study by utilizing CR criterion for SIRT in simulation and the clinical application of DOT measurement relies on further investigation.

  2. Measured and Calculated Neutron Spectra and Dose Equivalent Rates at High Altitudes; Relevance to SST Operations and Space Research

    NASA Technical Reports Server (NTRS)

    Foelsche, T.; Mendell, R. B.; Wilson, J. W.; Adams, R. R.

    1974-01-01

    Results of the NASA Langley-New York University high-altitude radiation study are presented. Measurements of the absorbed dose rate and of secondary fast neutrons (1 to 10 MeV energy) during the years 1965 to 1971 are used to determine the maximum radiation exposure from galactic and solar cosmic rays of supersonic transport (SST) and subsonic jet occupants. The maximum dose equivalent rates that the SST crews might receive turn out to be 13 to 20 percent of the maximum permissible dose rate (MPD) for radiation workers (5 rem/yr). The exposure of passengers encountering an intense giant-energy solar particle event could exceed the MPD for the general population (0.5 rem/yr), but would be within these permissible limits if in such rare cases the transport descends to subsonic altitude; it is in general less than 12 percent of the MPD. By Monte Carlo calculations of the transport and buildup of nucleons in air for incident proton energies E of 0.02 to 10 GeV, the measured neutron spectra were extrapolated to lower and higher energies and for galactic cosmic rays were found to continue with a relatively high intensity to energies greater than 400 MeV, in a wide altitude range. This condition, together with the measured intensity profiles of fast neutrons, revealed that the biologically important fast and energetic neutrons penetrate deep into the atmosphere and contribute approximately 50 percent of the dose equivalant rates at SST and present subsonic jet altitudes.

  3. Effects of track structure and cell inactivation on the calculation of heavy ion mutation rates in mammalian cells

    NASA Technical Reports Server (NTRS)

    Cucinotta, F. A.; Wilson, J. W.; Shavers, M. R.; Katz, R.

    1996-01-01

    It has long been suggested that inactivation severely effects the probability of mutation by heavy ions in mammalian cells. Heavy ions have observed cross sections of inactivation that approach and sometimes exceed the geometric size of the cell nucleus in mammalian cells. In the track structure model of Katz the inactivation cross section is found by summing an inactivation probability over all impact parameters from the ion to the sensitive sites within the cell nucleus. The inactivation probability is evaluated using the dose-response of the system to gamma-rays and the radial dose of the ions and may be equal to unity at small impact parameters for some ions. We show how the effects of inactivation may be taken into account in the evaluation of the mutation cross sections from heavy ions in the track structure model through correlation of sites for gene mutation and cell inactivation. The model is fit to available data for HPRT mutations in Chinese hamster cells and good agreement is found. The resulting calculations qualitatively show that mutation cross sections for heavy ions display minima at velocities where inactivation cross sections display maxima. Also, calculations show the high probability of mutation by relativistic heavy ions due to the radial extension of ions track from delta-rays in agreement with the microlesion concept. The effects of inactivation on mutations rates make it very unlikely that a single parameter such as LET or Z*2/beta(2) can be used to specify radiation quality for heavy ion bombardment.

  4. Interwell Connectivity and Diagnosis Using Correlation of Production and Injection Rate Data in Hydrocarbon Production

    SciTech Connect

    Jerry L. Jensen; Larry W. Lake; Ali Al-Yousef; Pablo Gentil; Nazli Demiroren

    2005-05-31

    This report details progress on inferring interwell communication from well rate fluctuations. Starting with the procedure of Albertoni and Lake (2003) as a foundation, the goal of the project is to develop further procedures to infer reservoir properties through weights derived from correlations between injection and production rates. A modified method, described in Jensen et al. (2005) and Yousef et al. (2005), and herein referred to as the ''capacitance model'', produces two quantities, {lambda} and {tau}, for each injector-producer well pair. We have focused on the following items: (1) Approaches to integrate {lambda} and {tau} to improve connectivity evaluations. Interpretations have been developed using Lorenz-style and log-log plots to assess heterogeneity. Testing shows the interpretations can identify whether interwell connectivity is controlled by flow through fractures, high-permeability layers, or due to partial completion of wells. Applications to the South Wasson and North Buck Draw Fields show promising results. (2) Optimization of waterflood injection rates using the capacitance model and a power law relationship for watercut to maximize economic return. Initial tests using simulated data and a range of oil prices show the approach is working. (3) Spectral analysis of injection and production data to estimate interwell connectivity and to assess the effects of near-wellbore gas on the results. Development of methods and analysis are ongoing. (4) Investigation of methods to increase the robustness of the capacitance method. These methods include revising the solution method to simultaneously estimate {lambda} and {tau} for each well pair. This approach allows for further constraints to be imposed during the computation, such as limiting {tau} to a range of values defined by the sampling interval and duration of the field data. This work is proceeding. Further work on this project includes the following: (1) Refinement and testing of the waterflood

  5. Direct measurement and theoretical calculation of the rate coefficient for Cl + CH3 from T = 202 - 298 K.

    SciTech Connect

    Payne, Walter A.; Harding, Lawrence B.; Stief, Louis J.; Parker, James F. , 1925-; Klippenstein, Stephen J.; Nesbitt, Fred L.; Cody, Regina J.

    2004-10-01

    The rate coefficient has been measured under pseudo-first-order conditions for the Cl + CH{sub 3} association reaction at T = 202, 250, and 298 K and P = 0.3-2.0 Torr helium using the technique of discharge-flow mass spectrometry with low-energy (12-eV) electron-impact ionization and collision-free sampling. Cl and CH{sub 3} were generated rapidly and simultaneously by reaction of F with HCl and CH{sub 4}, respectively. Fluorine atoms were produced by microwave discharge in an approximately 1% mixture of F{sub 2} in He. The decay of CH{sub 3} was monitored under pseudo-first-order conditions with the Cl-atom concentration in large excess over the CH{sub 3} concentration ([Cl]{sub 0}/[CH{sub 3}]{sub 0} = 9-67). Small corrections were made for both axial and radial diffusion and minor secondary chemistry. The rate coefficient was found to be in the falloff regime over the range of pressures studied. For example, at T = 202 K, the rate coefficient increases from 8.4 x 10{sup -12} at P = 0.30 Torr He to 1.8 x 10{sup -11} at P = 2.00 Torr He, both in units of cm{sup 3} molecule{sup -1} s{sup -1}. A combination of ab initio quantum chemistry, variational transition-state theory, and master-equation simulations was employed in developing a theoretical model for the temperature and pressure dependence of the rate coefficient. Reasonable empirical representations of energy transfer and of the effect of spin-orbit interactions yield a temperature- and pressure-dependent rate coefficient that is in excellent agreement with the present experimental results. The high-pressure limiting rate coefficient from the RRKM calculations is k{sub 2} = 6.0 x 10{sup -11} cm{sup 3} molecule{sup -1} s{sup -1}, independent of temperature in the range from 200 to 300 K.

  6. HDRMC, an accelerated Monte Carlo dose calculator for high dose rate brachytherapy with CT-compatible applicators

    SciTech Connect

    Chibani, Omar C-M Ma, Charlie

    2014-05-15

    Purpose: To present a new accelerated Monte Carlo code for CT-based dose calculations in high dose rate (HDR) brachytherapy. The new code (HDRMC) accounts for both tissue and nontissue heterogeneities (applicator and contrast medium). Methods: HDRMC uses a fast ray-tracing technique and detailed physics algorithms to transport photons through a 3D mesh of voxels representing the patient anatomy with applicator and contrast medium included. A precalculated phase space file for the{sup 192}Ir source is used as source term. HDRM is calibrated to calculated absolute dose for real plans. A postprocessing technique is used to include the exact density and composition of nontissue heterogeneities in the 3D phantom. Dwell positions and angular orientations of the source are reconstructed using data from the treatment planning system (TPS). Structure contours are also imported from the TPS to recalculate dose-volume histograms. Results: HDRMC was first benchmarked against the MCNP5 code for a single source in homogenous water and for a loaded gynecologic applicator in water. The accuracy of the voxel-based applicator model used in HDRMC was also verified by comparing 3D dose distributions and dose-volume parameters obtained using 1-mm{sup 3} versus 2-mm{sup 3} phantom resolutions. HDRMC can calculate the 3D dose distribution for a typical HDR cervix case with 2-mm resolution in 5 min on a single CPU. Examples of heterogeneity effects for two clinical cases (cervix and esophagus) were demonstrated using HDRMC. The neglect of tissue heterogeneity for the esophageal case leads to the overestimate of CTV D90, CTV D100, and spinal cord maximum dose by 3.2%, 3.9%, and 3.6%, respectively. Conclusions: A fast Monte Carlo code for CT-based dose calculations which does not require a prebuilt applicator model is developed for those HDR brachytherapy treatments that use CT-compatible applicators. Tissue and nontissue heterogeneities should be taken into account in modern HDR

  7. Kinetic modeling of hydrogen production rate by photoautotrophic cyanobacterium A. variabilis ATCC 29413 as a function of both CO2 concentration and oxygen production rate.

    PubMed

    Salleh, Siti Fatihah; Kamaruddin, Azlina; Uzir, Mohamad Hekarl; Mohamed, Abdul Rahman; Shamsuddin, Abdul Halim

    2017-02-07

    Hydrogen production by cyanobacteria could be one of the promising energy resources in the future. However, there is very limited information regarding the kinetic modeling of hydrogen production by cyanobacteria available in the literature. To provide an in-depth understanding of the biological system involved during the process, the Haldane's noncompetitive inhibition equation has been modified to determine the specific hydrogen production rate (HPR) as a function of both dissolved CO2 concentration (CTOT) and oxygen production rate (OPR). The highest HPR of 15 [Formula: see text] was found at xCO2 of 5% vol/vol and the rate consequently decreased when the CTOT and OPR were 0.015 k mol m(-3) and 0.55 mL h(-1), respectively. The model provided a fairly good estimation of the HPR with respect to the experimental data collected.

  8. A parallel code to calculate rate-state seismicity evolution induced by time dependent, heterogeneous Coulomb stress changes

    NASA Astrophysics Data System (ADS)

    Cattania, C.; Khalid, F.

    2016-09-01

    The estimation of space and time-dependent earthquake probabilities, including aftershock sequences, has received increased attention in recent years, and Operational Earthquake Forecasting systems are currently being implemented in various countries. Physics based earthquake forecasting models compute time dependent earthquake rates based on Coulomb stress changes, coupled with seismicity evolution laws derived from rate-state friction. While early implementations of such models typically performed poorly compared to statistical models, recent studies indicate that significant performance improvements can be achieved by considering the spatial heterogeneity of the stress field and secondary sources of stress. However, the major drawback of these methods is a rapid increase in computational costs. Here we present a code to calculate seismicity induced by time dependent stress changes. An important feature of the code is the possibility to include aleatoric uncertainties due to the existence of multiple receiver faults and to the finite grid size, as well as epistemic uncertainties due to the choice of input slip model. To compensate for the growth in computational requirements, we have parallelized the code for shared memory systems (using OpenMP) and distributed memory systems (using MPI). Performance tests indicate that these parallelization strategies lead to a significant speedup for problems with different degrees of complexity, ranging from those which can be solved on standard multicore desktop computers, to those requiring a small cluster, to a large simulation that can be run using up to 1500 cores.

  9. Determination of equilibrium electron temperature and times using an electron swarm model with BOLSIG+ calculated collision frequencies and rate coefficients

    NASA Astrophysics Data System (ADS)

    Pusateri, Elise N.; Morris, Heidi E.; Nelson, Eric M.; Ji, Wei

    2015-08-01

    Electromagnetic pulse (EMP) events produce low-energy conduction electrons from Compton electron or photoelectron ionizations with air. It is important to understand how conduction electrons interact with air in order to accurately predict EMP evolution and propagation. An electron swarm model can be used to monitor the time evolution of conduction electrons in an environment characterized by electric field and pressure. Here a swarm model is developed that is based on the coupled ordinary differential equations (ODEs) described by Higgins et al. (1973), hereinafter HLO. The ODEs characterize the swarm electric field, electron temperature, electron number density, and drift velocity. Important swarm parameters, the momentum transfer collision frequency, energy transfer collision frequency, and ionization rate, are calculated and compared to the previously reported fitted functions given in HLO. These swarm parameters are found using BOLSIG+, a two term Boltzmann solver developed by Hagelaar and Pitchford (2005), which utilizes updated cross sections from the LXcat website created by Pancheshnyi et al. (2012). We validate the swarm model by comparing to experimental effective ionization coefficient data in Dutton (1975) and drift velocity data in Ruiz-Vargas et al. (2010). In addition, we report on electron equilibrium temperatures and times for a uniform electric field of 1 StatV/cm for atmospheric heights from 0 to 40 km. It is shown that the equilibrium temperature and time are sensitive to the modifications in the collision frequencies and ionization rate based on the updated electron interaction cross sections.

  10. Calculation of the Helfferich number to identify the rate-controlling step of ion exchange for a batch process

    SciTech Connect

    Bunzl, K.

    1995-08-01

    The Helfferich number He is used frequently as a valuable criterion to decide whether for an ion exchange process film diffusion or particle diffusion of the ions is the rate-determining step. The corresponding equation given by Helfferich is restricted, however, for the boundary condition of an infinite solution volume. In the present paper, the Helfferich number is calculated also for a finite solution volume, i.e., for a typical batch process. Because the resulting equation can be solved only numerically, the results are presented in graphical form. It is also examined for which batch processes the conventional Helfferich number already yields a conservative and thus a very simple and useful estimate of the rate-determining step. Information on the kinetics of ion exchange reactions is required not only for the economic employment of synthetic ion exchangers in the industry and the laboratory but also for a better understanding of these processes in natural systems, as, e.g., the sorption of nutrient and toxic ions by the soil.

  11. Determination of equilibrium electron temperature and times using an electron swarm model with BOLSIG+ calculated collision frequencies and rate coefficients

    DOE PAGES

    Pusateri, Elise N.; Morris, Heidi E.; Nelson, Eric M.; ...

    2015-08-04

    Electromagnetic pulse (EMP) events produce low-energy conduction electrons from Compton electron or photoelectron ionizations with air. It is important to understand how conduction electrons interact with air in order to accurately predict EMP evolution and propagation. An electron swarm model can be used to monitor the time evolution of conduction electrons in an environment characterized by electric field and pressure. Here a swarm model is developed that is based on the coupled ordinary differential equations (ODEs) described by Higgins et al. (1973), hereinafter HLO. The ODEs characterize the swarm electric field, electron temperature, electron number density, and drift velocity. Importantmore » swarm parameters, the momentum transfer collision frequency, energy transfer collision frequency, and ionization rate, are calculated and compared to the previously reported fitted functions given in HLO. These swarm parameters are found using BOLSIG+, a two term Boltzmann solver developed by Hagelaar and Pitchford (2005), which utilizes updated cross sections from the LXcat website created by Pancheshnyi et al. (2012). We validate the swarm model by comparing to experimental effective ionization coefficient data in Dutton (1975) and drift velocity data in Ruiz-Vargas et al. (2010). In addition, we report on electron equilibrium temperatures and times for a uniform electric field of 1 StatV/cm for atmospheric heights from 0 to 40 km. We show that the equilibrium temperature and time are sensitive to the modifications in the collision frequencies and ionization rate based on the updated electron interaction cross sections.« less

  12. Determination of equilibrium electron temperature and times using an electron swarm model with BOLSIG+ calculated collision frequencies and rate coefficients

    SciTech Connect

    Pusateri, Elise N.; Morris, Heidi E.; Nelson, Eric M.; Ji, Wei

    2015-08-04

    Electromagnetic pulse (EMP) events produce low-energy conduction electrons from Compton electron or photoelectron ionizations with air. It is important to understand how conduction electrons interact with air in order to accurately predict EMP evolution and propagation. An electron swarm model can be used to monitor the time evolution of conduction electrons in an environment characterized by electric field and pressure. Here a swarm model is developed that is based on the coupled ordinary differential equations (ODEs) described by Higgins et al. (1973), hereinafter HLO. The ODEs characterize the swarm electric field, electron temperature, electron number density, and drift velocity. Important swarm parameters, the momentum transfer collision frequency, energy transfer collision frequency, and ionization rate, are calculated and compared to the previously reported fitted functions given in HLO. These swarm parameters are found using BOLSIG+, a two term Boltzmann solver developed by Hagelaar and Pitchford (2005), which utilizes updated cross sections from the LXcat website created by Pancheshnyi et al. (2012). We validate the swarm model by comparing to experimental effective ionization coefficient data in Dutton (1975) and drift velocity data in Ruiz-Vargas et al. (2010). In addition, we report on electron equilibrium temperatures and times for a uniform electric field of 1 StatV/cm for atmospheric heights from 0 to 40 km. We show that the equilibrium temperature and time are sensitive to the modifications in the collision frequencies and ionization rate based on the updated electron interaction cross sections.

  13. Giotto IMS measurements of the production rate of hydrogen cyanide in the coma of Comet Halley

    NASA Technical Reports Server (NTRS)

    Ip, W.-H.; Balsiger, H.; Geiss, J.; Goldstein, B. E.; Kettmann, G.

    1990-01-01

    The ion composition measurements in the ionosphere of Comet Halley by the ion mass spectrometer (IMS) experiment on the Giotto spacecraft are used to estimate the relative abundance of HCN. From a comparison of the normalized number density of ions with mass-to-charge (M/q) ratio of 28 AMU/e with steady-state photochemical models, it can be determined that the production rate of HCN directly from the central nucleus is Q(HCN) is less than about 0.0002 Q(H2O) at the time of Giotto encounter. The related photochemical- model calculations also indicate that Q(NH3)/Q(H2O) at the time of Giotto encounter. The related photo-chemical model calculations also indicate that Q(HN3)/Q(H2O) equals about 0.005, in agreement with recent determination from ground-based observations. The estimated value of Q(HCN) is lower than the relative abundance of Q(HCN)/Q(H2O) of about 0.001, as derived from radio observations of the 88.6 GHz emission of the J = 1 - 0 transition of HCN. The difference may be the result of time variations of the coma composition and dynamics, as well as other model-dependent effects.

  14. 37 CFR 1.775 - Calculation of patent term extension for a human drug, antibiotic drug or human biological product.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... extension for a human drug, antibiotic drug or human biological product. 1.775 Section 1.775 Patents... Review § 1.775 Calculation of patent term extension for a human drug, antibiotic drug or human biological product. (a) If a determination is made pursuant to § 1.750 that a patent for a human drug,...

  15. 37 CFR 1.775 - Calculation of patent term extension for a human drug, antibiotic drug or human biological product.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... extension for a human drug, antibiotic drug or human biological product. 1.775 Section 1.775 Patents... Review § 1.775 Calculation of patent term extension for a human drug, antibiotic drug or human biological product. (a) If a determination is made pursuant to § 1.750 that a patent for a human drug,...

  16. 37 CFR 1.775 - Calculation of patent term extension for a human drug, antibiotic drug or human biological product.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... extension for a human drug, antibiotic drug or human biological product. 1.775 Section 1.775 Patents... Review § 1.775 Calculation of patent term extension for a human drug, antibiotic drug or human biological product. (a) If a determination is made pursuant to § 1.750 that a patent for a human drug,...

  17. 37 CFR 1.775 - Calculation of patent term extension for a human drug, antibiotic drug or human biological product.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... extension for a human drug, antibiotic drug or human biological product. 1.775 Section 1.775 Patents... Review § 1.775 Calculation of patent term extension for a human drug, antibiotic drug or human biological product. (a) If a determination is made pursuant to § 1.750 that a patent for a human drug,...

  18. 37 CFR 1.775 - Calculation of patent term extension for a human drug, antibiotic drug or human biological product.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... extension for a human drug, antibiotic drug or human biological product. 1.775 Section 1.775 Patents... Review § 1.775 Calculation of patent term extension for a human drug, antibiotic drug or human biological product. (a) If a determination is made pursuant to § 1.750 that a patent for a human drug,...

  19. EARLINET Single Calculus Chain - technical - Part 2: Calculation of optical products

    NASA Astrophysics Data System (ADS)

    Mattis, Ina; D'Amico, Giuseppe; Baars, Holger; Amodeo, Aldo; Madonna, Fabio; Iarlori, Marco

    2016-07-01

    In this paper we present the automated software tool ELDA (EARLINET Lidar Data Analyzer) for the retrieval of profiles of optical particle properties from lidar signals. This tool is one of the calculus modules of the EARLINET Single Calculus Chain (SCC) which allows for the analysis of the data of many different lidar systems of EARLINET in an automated, unsupervised way. ELDA delivers profiles of particle extinction coefficients from Raman signals as well as profiles of particle backscatter coefficients from combinations of Raman and elastic signals or from elastic signals only. Those analyses start from pre-processed signals which have already been corrected for background, range dependency and hardware specific effects. An expert group reviewed all algorithms and solutions for critical calculus subsystems which are used within EARLINET with respect to their applicability for automated retrievals. Those methods have been implemented in ELDA. Since the software was designed in a modular way, it is possible to add new or alternative methods in future. Most of the implemented algorithms are well known and well documented, but some methods have especially been developed for ELDA, e.g., automated vertical smoothing and temporal averaging or the handling of effective vertical resolution in the case of lidar ratio retrievals, or the merging of near-range and far-range products. The accuracy of the retrieved profiles was tested following the procedure of the EARLINET-ASOS algorithm inter-comparison exercise which is based on the analysis of synthetic signals. Mean deviations, mean relative deviations, and normalized root-mean-square deviations were calculated for all possible products and three height layers. In all cases, the deviations were clearly below the maximum allowed values according to the EARLINET quality requirements.

  20. Aqueous photodegradation of 4-tert-butylphenol: By-products, degradation pathway and theoretical calculation assessment.

    PubMed

    Wu, Yanlin; Shi, Jin; Chen, Hongche; Zhao, Jianfu; Dong, Wenbo

    2016-10-01

    4-tert-butylphenol (4-t-BP), an endocrine disrupting chemical, is widely distributed in natural bodies of water but is difficult to biodegrade. In this study, we focused on the transformation of 4-t-BP in photo-initiated degradation processes. The steady-state photolysis and laser flash photolysis (LFP) experiments were conducted in order to elucidate its degradation mechanism. Identification of products was performed using the GC-MS, LC-MS and theoretical calculation techniques. The oxidation pathway of 4-t-BP by hydroxyl radical (HO) was also studied and H2O2 was added to produce HO. 4-tert-butylcatechol and 4-tert-butylphenol dimer were produced in 4-t-BP direct photolysis. 4-tert-butylcatechol and hydroquinone were produced by the oxidation of HO. But the formation mechanism of 4-tert-butylcatechol in the two processes was different. The benzene ring was fractured in 4-t-BP oxidation process and 29% of TOC was degraded after 16h irradiation.

  1. Energy transfer among CP29 chlorophylls: calculated Förster rates and experimental transient absorption at room temperature.

    PubMed Central

    Cinque, G; Croce, R; Holzwarth, A; Bassi, R

    2000-01-01

    The energy transfer rates between chlorophylls in the light harvesting complex CP29 of higher plants at room temperature were calculated ab initio according to the Förster mechanism (Förster T. 1948, Ann. Physik. 2:55-67). Recently, the transition moment orientation of CP29 chlorophylls was determined by differential linear dichroism and absorption spectroscopy of wild-type versus mutant proteins in which single chromophores were missing (Simonetto R., Crimi M., Sandonà D., Croce R., Cinque G., Breton J., and Bassi R. 1999. Biochemistry. 38:12974-12983). In this way the Q(y) transition energy and chlorophyll a/b affinity of each binding site was obtained and their characteristics supported by reconstruction of steady-state linear dichroism and absorption spectra at room temperature. In this study, the spectral form of individual chlorophyll a and b ligands within the protein environment was experimentally determined, and their extinction coefficients were also used to evaluate the absolute overlap integral between donors and acceptors employing the Stepanov relation for both the emission spectrum and the Stokes shift. This information was used to calculate the time-dependent excitation redistribution among CP29 chlorophylls on solving numerically the Pauli master equation of the complex: transient absorption measurements in the (sub)picosecond time scale were simulated and compared to pump-and-probe experimental data in the Q(y) region on the native CP29 at room temperature upon selective excitation of chlorophylls b at 640 or 650 nm. The kinetic model indicates a bidirectional excitation transfer over all CP29 chlorophylls a species, which is particularly rapid between the pure sites A1-A2 and A4-A5. Chlorophylls b in mixed sites act mostly as energy donors for chlorophylls a, whereas site B5 shows high and bidirectional coupling independent of the pigment hosted. PMID:11023879

  2. Estimating methane production rates in bogs and landfills by deuterium enrichment of pore water

    USGS Publications Warehouse

    Siegel, D.I.; Chanton, J.P.; Glaser, P.H.; Chasar, L.S.; Rosenberry, D.O.

    2001-01-01

    Raised bogs and municipal waste landfills harbor large populations of methanogens within their domed deposits of anoxic organic matter. Although the methane emissions from these sites have been estimated by various methods, limited data exist on the activity of the methanogens at depth. We therefore analyzed the stable isotopic signature of the pore waters in two raised bogs from northern Minnesota to identify depth intervals in the peat profile where methanogenic metabolism occurs. Methanogenesis enriched the deuterium (2H) content of the deep peat pore waters by as much as +11% (Vienna Standard Mean Sea Water), which compares to a much greater enrichment factor of +70% in leachate from New York City's Fresh Kills landfill. The bog pore waters were isotopically dated by tritium (3H) to be about 35 years old at 1.5 m depth, whereas the landfill leachate was estimated as ~ 17 years old from Darcy flow calculations. According to an isotopic mass balance the observed deuterium enrichment indicates that about 1.2 g of CH4m-3 d-1 were produced within the deeper peat, compared to about 2.8 g CH4 m-3 d-1 in the landfill. The values for methane production in the bog peat are substantially higher than the flux rates measured at the surface of the bogs or at the landfill, indicating that deeper methane production may be much higher than was previously assumed.

  3. Comparison of experimental and calculated attachment rate constants for CFCl3 and CCl4 in the temperature range 294-500 K

    NASA Technical Reports Server (NTRS)

    Orient, O. J.; Chutjian, A.; Crompton, R. W.; Cheung, B.

    1989-01-01

    Electron-attachment cross sections and rate constants have been measured and calculated for the dissociative attachment processes e + CFCl3 - Cl(-) + CFCl2 and e + CCl4 - Cl(-) + CCl3. Good agreement over the electron-energy range 1-200 meV is found in energy dependence between present calculated cross sections and experimental cross sections at 300 K. The same calculation, with suitable adjustment of thermal populations, was used to calculate electron-attachment rate constants in the range 50-600 K. Experimental rate constants for CFCl3 and CCl4 were measured at temperatures of 294, 404, and 496 K (CFCl3) and 294, 400, and 500 K (CCl4) using the Cavalleri electron-density sampling method. Good agreement is found between present measurements and calculations, poor agreement with flowing-afterglow Langmuir-probe (FALP) data in CFCl3 at the higher temperatures, and reasonable agreement with FALP data for CCl4.

  4. Scaling in situ cosmogenic nuclide production rates using analytical approximations to atmospheric cosmic-ray fluxes

    NASA Astrophysics Data System (ADS)

    Lifton, Nathaniel; Sato, Tatsuhiko; Dunai, Tibor J.

    2014-01-01

    Several models have been proposed for scaling in situ cosmogenic nuclide production rates from the relatively few sites where they have been measured to other sites of interest. Two main types of models are recognized: (1) those based on data from nuclear disintegrations in photographic emulsions combined with various neutron detectors, and (2) those based largely on neutron monitor data. However, stubborn discrepancies between these model types have led to frequent confusion when calculating surface exposure ages from production rates derived from the models. To help resolve these discrepancies and identify the sources of potential biases in each model, we have developed a new scaling model based on analytical approximations to modeled fluxes of the main atmospheric cosmic-ray particles responsible for in situ cosmogenic nuclide production. Both the analytical formulations and the Monte Carlo model fluxes on which they are based agree well with measured atmospheric fluxes of neutrons, protons, and muons, indicating they can serve as a robust estimate of the atmospheric cosmic-ray flux based on first principles. We are also using updated records for quantifying temporal and spatial variability in geomagnetic and solar modulation effects on the fluxes. A key advantage of this new model (herein termed LSD) over previous Monte Carlo models of cosmogenic nuclide production is that it allows for faster estimation of scaling factors based on time-varying geomagnetic and solar inputs. Comparing scaling predictions derived from the LSD model with those of previously published models suggest potential sources of bias in the latter can be largely attributed to two factors: different energy responses of the secondary neutron detectors used in developing the models, and different geomagnetic parameterizations. Given that the LSD model generates flux spectra for each cosmic-ray particle of interest, it is also relatively straightforward to generate nuclide-specific scaling

  5. Correlation of gene expression and protein production rate - a system wide study

    PubMed Central

    2011-01-01

    Background Growth rate is a major determinant of intracellular function. However its effects can only be properly dissected with technically demanding chemostat cultivations in which it can be controlled. Recent work on Saccharomyces cerevisiae chemostat cultivations provided the first analysis on genome wide effects of growth rate. In this work we study the filamentous fungus Trichoderma reesei (Hypocrea jecorina) that is an industrial protein production host known for its exceptional protein secretion capability. Interestingly, it exhibits a low growth rate protein production phenotype. Results We have used transcriptomics and proteomics to study the effect of growth rate and cell density on protein production in chemostat cultivations of T. reesei. Use of chemostat allowed control of growth rate and exact estimation of the extracellular specific protein production rate (SPPR). We find that major biosynthetic activities are all negatively correlated with SPPR. We also find that expression of many genes of secreted proteins and secondary metabolism, as well as various lineage specific, mostly unknown genes are positively correlated with SPPR. Finally, we enumerate possible regulators and regulatory mechanisms, arising from the data, for this response. Conclusions Based on these results it appears that in low growth rate protein production energy is very efficiently used primarly for protein production. Also, we propose that flux through early glycolysis or the TCA cycle is a more fundamental determining factor than growth rate for low growth rate protein production and we propose a novel eukaryotic response to this i.e. the lineage specific response (LSR). PMID:22185473

  6. The Effect of Humic Substances on the Production Rate of Alkyl Nitrates in Seawater

    NASA Astrophysics Data System (ADS)

    Heiss, E. M.; Dahl, E. E.

    2008-12-01

    Alkyl nitrates are produced photochemically in seawater by the reaction of organic peroxy radicals and nitric oxide (ROO + NO). Dissolved organic matter (DOM) is a source of organic peroxy radicals in seawater, but it is unclear as to which fraction of DOM is important for alkyl nitrate formation. Dissolved humics may be important to alkyl nitrate production. The production rates of C1-C3 alkyl nitrates were observed in 0.2 μm filtered open ocean seawater as a function of nitrite concentration. The net production rates of methyl, ethyl, isopropyl, and n-propyl nitrate increased with increasing nitrite concentrations. Suwannee River humics were added to seawater samples and the net production rates of alkyl nitrates were determined. The production rate of ethyl nitrate increased at nitrite concentrations above 20 μM nitrite by a factor of ~5 with the addition of humic substances. The addition of humic substances to the water samples also resulted in an increase in the ratio of isopropyl nitrate production to ethyl nitrate production by a factor of ~3 compared to nitrite only additions. The ratio of isopropyl to ethyl nitrate production with additional humics is also greater than production rates determined using open ocean water in previous studies. The ratios of methyl nitrate and n-propyl nitrate production to ethyl nitrate production did not change significantly. The minimal change in alkyl nitrate production rates at nitrite concentrations below 20 μM indicates that NO may be the limiting reactant in this particular water sample. The effect of the humics at high nitrite concentrations shows that organic peroxy radicals are an important reactant in the production of alkyl nitrates. The difference between production rate patterns with the addition of humics compared to the nitrite only incubations indicate that humics are not the only source of organic peroxy radicals affecting open ocean water alkyl nitrate formation.

  7. Outdoor pilot-scale production of Nannochloropsis gaditana: influence of culture parameters and lipid production rates in tubular photobioreactors.

    PubMed

    San Pedro, A; González-López, C V; Acién, F G; Molina-Grima, E

    2014-10-01

    This work studied outdoor pilot scale production of Nannochloropsis gaditana in tubular photobioreactors. The growth and biomass composition of the strain were studied under different culture strategies: continuous-mode (varying nutrient supply and dilution rate) and two-stage cultures aiming lipid enhancement. Besides, parameters such as irradiance, specific nitrate input and dilution rate were used to obtain models predicting growth, lipid and fatty acids production rates. The range of optimum dilution rate was 0.31-0.351/day with maximum biomass, lipid and fatty acids productivities of 590, 110 and 66.8 mg/l day, respectively. Nitrate limitation led to an increase in lipid and fatty acids contents (from 20.5% to 38.0% and from 16.9% to 23.5%, respectively). Two-stage culture strategy provided similar fatty acids productivities (56.4 mg/l day) but the neutral lipids content was doubled.

  8. Effective helium burning rates and the production of the neutrino nuclei.

    PubMed

    Austin, Sam M; West, Christopher; Heger, Alexander

    2014-03-21

    Effective values for the key helium burning reaction rates, triple-α and (12)C(α, γ)(16)O, are obtained by adjusting their strengths so as to obtain the best match with the solar abundance pattern of isotopes uniquely or predominately made in core-collapse supernovae. These effective rates are then used to determine the production of the neutrino isotopes. The use of effective rates considerably reduces the uncertainties in the production factors arising from uncertainties in the helium burning rates, and improves our ability to use the production of B11 to constrain the neutrino emission from supernovae.

  9. Seasonal Changes in Mycosporine-Like Amino Acid Production Rate with Respect to Natural Phytoplankton Species Composition

    PubMed Central

    Ha, Sun-Yong; Lee, Yeonjung; Kim, Min-Seob; Kumar, K. Suresh; Shin, Kyung-Hoon

    2015-01-01

    After in situ incubation at the site for a year, phytoplanktons in surface water were exposed to natural light in temperate lakes (every month); thereafter, the net production rate of photoprotective compounds (mycosporine-like amino acids, MAAs) was calculated using 13C labeled tracer. This is the first report describing seasonal variation in the net production rate of individual MAAs in temperate lakes using a compound-specific stable isotope method. In the mid-latitude region of the Korean Peninsula, UV radiation (UVR) usually peaks from July to August. In Lake Paldang and Lake Cheongpyeong, diatoms dominated among the phytoplankton throughout the year. The relative abundance of Cyanophyceae (Anabaena spiroides) reached over 80% during July in Lake Cheongpyeong. Changes in phytoplankton abundance indicate that the phytoplankton community structure is influenced by seasonal changes in the net production rate and concentration of MAAs. Notably, particulate organic matter (POM) showed a remarkable change based on the UV intensity occurring during that period; this was because of the fact that cyanobacteria that are highly sensitive to UV irradiance dominated the community. POM cultured in Lake Paldang had the greatest shinorine (SH) production rate during October, i.e., 83.83 ± 10.47 fgC·L−1·h−1. The dominance of diatoms indicated that they had a long-term response to UVR. Evaluation of POM cultured in Lake Cheongpyeong revealed that there was an increase in the net MAA production in July (when UVR reached the maximum); a substantial amount of SH, i.e., 17.62 ± 18.34 fgC·L−1·h−1, was recorded during this period. Our results demonstrate that both the net production rate as well as the concentration of MAAs related to photoinduction depended on the phytoplankton community structure. In addition, seasonal changes in UVR also influenced the quantity and production of MAAs in phytoplanktons (especially Cyanophyceae). PMID:26561820

  10. Seasonal Changes in Mycosporine-Like Amino Acid Production Rate with Respect to Natural Phytoplankton Species Composition.

    PubMed

    Ha, Sun-Yong; Lee, Yeonjung; Kim, Min-Seob; Kumar, K Suresh; Shin, Kyung-Hoon

    2015-11-06

    After in situ incubation at the site for a year, phytoplanktons in surface water were exposed to natural light in temperate lakes (every month); thereafter, the net production rate of photoprotective compounds (mycosporine-like amino acids, MAAs) was calculated using (13)C labeled tracer. This is the first report describing seasonal variation in the net production rate of individual MAAs in temperate lakes using a compound-specific stable isotope method. In the mid-latitude region of the Korean Peninsula, UV radiation (UVR) usually peaks from July to August. In Lake Paldang and Lake Cheongpyeong, diatoms dominated among the phytoplankton throughout the year. The relative abundance of Cyanophyceae (Anabaena spiroides) reached over 80% during July in Lake Cheongpyeong. Changes in phytoplankton abundance indicate that the phytoplankton community structure is influenced by seasonal changes in the net production rate and concentration of MAAs. Notably, particulate organic matter (POM) showed a remarkable change based on the UV intensity occurring during that period; this was because of the fact that cyanobacteria that are highly sensitive to UV irradiance dominated the community. POM cultured in Lake Paldang had the greatest shinorine (SH) production rate during October, i.e., 83.83 ± 10.47 fgC·L(-1)·h(-1). The dominance of diatoms indicated that they had a long-term response to UVR. Evaluation of POM cultured in Lake Cheongpyeong revealed that there was an increase in the net MAA production in July (when UVR reached the maximum); a substantial amount of SH, i.e., 17.62 ± 18.34 fgC·L(-1)·h(-1), was recorded during this period. Our results demonstrate that both the net production rate as well as the concentration of MAAs related to photoinduction depended on the phytoplankton community structure. In addition, seasonal changes in UVR also influenced the quantity and production of MAAs in phytoplanktons (especially Cyanophyceae).

  11. Results of calculations of external gamma radiation exposure rates from local fallout and the related radionuclide compositions of two hypothetical 1-MT nuclear bursts. Final report

    SciTech Connect

    Hicks, H.

    1984-12-01

    This report presents data on calculated gamma radiation exposure rates and local surface deposition of related radionuclides resulting from two hypothetical 1-Mt nuclear bursts. Calculations are made of the debris from two types of bombs: one containing /sup 235/U as a fissionable material (designated oralloy), the other containing /sup 238/U (designated tuballoy). 4 references.

  12. Quasiclassical trajectory study of the F + H 2 system. Rate constants, kinetic isotope effects and energy partitioning among reaction products

    NASA Astrophysics Data System (ADS)

    Rosenman, Efrat; Persky, Avigdor

    1995-06-01

    Quasiclassical trajectory calculations were carried out for the reactions F + H 2, F + D 2, and F + HD, using two potential energy surfaces T5A and 6SEC. The results which include rate constants and kinetic isotope effects as a function of temperature, isotopic branching ratios for F + HD as a function off collision energy and the energy partitioning and vibrational state distributions of the products at room temperature, are compared with experimental data. For most of the quantities under study, the results for the 6SEC surface are in qualitative agreement with experiment, as opposed to the results for the T5A surface. The conclusions from the present study concerning the quality of the 6SEC surface are consistent with the conclusions of Aoiz et al. which are based mainly on calculations of vibrationally state resolved differential cross sections and vibrational distributions of products, for specific collision energies.

  13. Calculated Third Order Rate Constants for Interpreting the Mechanisms of Hydrolyses of Chloroformates, Carboxylic Acid Halides, Sulfonyl Chlorides and Phosphorochloridates

    PubMed Central

    Bentley, T. William

    2015-01-01

    Hydrolyses of acid derivatives (e.g., carboxylic acid chlorides and fluorides, fluoro- and chloroformates, sulfonyl chlorides, phosphorochloridates, anhydrides) exhibit pseudo-first order kinetics. Reaction mechanisms vary from those involving a cationic intermediate (SN1) to concerted SN2 processes, and further to third order reactions, in which one solvent molecule acts as the attacking nucleophile and a second molecule acts as a general base catalyst. A unified framework is discussed, in which there are two reaction channels—an SN1-SN2 spectrum and an SN2-SN3 spectrum. Third order rate constants (k3) are calculated for solvolytic reactions in a wide range of compositions of acetone-water mixtures, and are shown to be either approximately constant or correlated with the Grunwald-Winstein Y parameter. These data and kinetic solvent isotope effects, provide the experimental evidence for the SN2-SN3 spectrum (e.g., for chloro- and fluoroformates, chloroacetyl chloride, p-nitrobenzoyl p-toluenesulfonate, sulfonyl chlorides). Deviations from linearity lead to U- or V-shaped plots, which assist in the identification of the point at which the reaction channel changes from SN2-SN3 to SN1-SN2 (e.g., for benzoyl chloride). PMID:26006228

  14. Estimation of production losses caused by the coffee berry borer (Coleoptera: Scolytidae) and calculation of an economic damage threshold in Togolese coffee plots.

    PubMed

    Wegbe, Komlan; Cilas, Christian; Decazy, Bernard; Alauzet, Claude; Dufour, Bernard

    2003-10-01

    The coffee berry borer, Hypothenemus hampei (Ferrari) (Coleoptera: Scolytidae), which exists in all coffee producing zones, is a major pest. The seriousness of this scolytid was assessed in Togolese plots spread over five agroclimatic zones, by determining the attack rate from a sample of coffee trees. The work was carried out over 2 yr and revealed that weight losses were proportional to the attack rates. The average infestation rates were 5.64% in the first year and 6.36% in the second year, while total production losses amounted to 2.60% and 3.18%, respectively, for the same periods. Generally speaking, attack rates in the plots were low and varied considerably within a given zone. Plantations located on plateau were more severely attacked than those in the plains. A relationship was established between total losses and the cost of insecticide treatment; this relationship was used to calculate an economic damage threshold beyond which control proves to be cost effective.

  15. Correction of in situ cosmogenic nuclide production rates for geomagnetic field intensity variations during the past 800,000 years

    NASA Astrophysics Data System (ADS)

    Masarik, Jozef; Frank, Martin; Schäfer, Jörg M.; Wieler, Rainer

    2001-09-01

    We present integrated relative production rates for cosmogenic nuclides in rock surfaces, which take into account reported variations of the geomagnetic field intensity during the past 800,000 yr. The calculations are based on the model simulating cosmic ray particle interactions with the Earth's atmosphere given by Masarik and Beer ["Simulation of particle fluxes and cosmogenic nuclide production in the Earth's atmosphere," J. Geophys. Res. 104(D10), 12099-12111, 1999]. Corrections are nearly independent on altitude between sea level and at least 5000 m. The correction factors are essentially identical for all stable and radioactive cosmogenic nuclides with half-lives longer than a few hundred thousand years. At the equator, integrated production rates for exposure ages between ˜40,000 to 800,000 yr are 10 to 12% higher than the present-day values, whereas at latitudes >40°, geomagnetic field intensity variations have hardly influenced in situ cosmogenic nuclide production. Correction factors for in situ 14C production rates differ from those of longer-lived nuclides. They are always smaller than ˜2% because the magnetic field intensity remained rather constant during the past ˜10 kyr, when the major fraction of the 14C extant today was produced.

  16. Relativistic many-body Moller-Plesset perturbation theory calculations of the energy levels and transition rates in Na-like to P-like Xe ions

    SciTech Connect

    Vilkas, Marius J.; Ishikawa, Yasuyuki; Traebert, Elmar

    2008-09-15

    Relativistic multireference many-body perturbation theory calculations have been performed for Xe{sup 43+} to Xe{sup 39+} ions, resulting in energy levels, electric dipole transition rates, and level lifetimes. The second-order many-body perturbation theory calculation of energy levels included mass shifts, the frequency-dependent Breit correction, and Lamb shifts. The calculated transition energies and E1 transition rates are used to present synthetic spectra in the extreme ultraviolet range for some of the Xe ions.

  17. 40 CFR Table I-3 to Subpart I of... - Default Emission Factors (1-Uij) for Gas Utilization Rates (Uij) and By-Product Formation Rates...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Default Emission Factors (1-Uij) for Gas Utilization Rates (Uij) and By-Product Formation Rates (Bijk) for Semiconductor Manufacturing for... Gas Utilization Rates (Uij) and By-Product Formation Rates (Bijk) for Semiconductor Manufacturing...

  18. 40 CFR Table I-3 to Subpart I of... - Default Emission Factors (1-Uij) for Gas Utilization Rates (Uij) and By-Product Formation Rates...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Default Emission Factors (1-Uij) for Gas Utilization Rates (Uij) and By-Product Formation Rates (Bijk) for Semiconductor Manufacturing for... Factors (1-Uij) for Gas Utilization Rates (Uij) and By-Product Formation Rates (Bijk) for...

  19. 40 CFR Table I-4 to Subpart I of... - Default Emission Factors (1-Uij) for Gas Utilization Rates (Uij) and By-Product Formation Rates...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Default Emission Factors (1-Uij) for Gas Utilization Rates (Uij) and By-Product Formation Rates (Bijk) for Semiconductor Manufacturing for... Factors(1-Uij) for Gas Utilization Rates (Uij) and By-Product Formation Rates (Bijk) for...

  20. Exact solutions for the entropy production rate of several irreversible processes.

    PubMed

    Ross, John; Vlad, Marcel O

    2005-11-24

    We investigate thermal conduction described by Newton's law of cooling and by Fourier's transport equation and chemical reactions based on mass action kinetics where we detail a simple example of a reaction mechanism with one intermediate. In these cases we derive exact expressions for the entropy production rate and its differential. We show that at a stationary state the entropy production rate is an extremum if and only if the stationary state is a state of thermodynamic equilibrium. These results are exact and independent of any expansions of the entropy production rate. In the case of thermal conduction we compare our exact approach with the conventional approach based on the expansion of the entropy production rate near equilibrium. If we expand the entropy production rate in a series and keep terms up to the third order in the deviation variables and then differentiate, we find out that the entropy production rate is not an extremum at a nonequilibrium steady state. If there is a strict proportionality between fluxes and forces, then the entropy production rate is an extremum at the stationary state even if the stationary state is far away from equilibrium.

  1. Titan-like exoplanets: Variations in geometric albedo and effective transit height with haze production rate

    NASA Astrophysics Data System (ADS)

    Checlair, Jade; McKay, Christopher P.; Imanaka, Hiroshi

    2016-09-01

    Extensive studies characterizing Titan present an opportunity to study the atmospheric properties of Titan-like exoplanets. Using an existing model of Titan's atmospheric haze, we computed geometric albedo spectra and effective transit height spectra for six values of the haze production rate (zero haze to twice present) over a wide range of wavelengths (0.2-2 μm). In the geometric albedo spectra, the slope in the UV-visible changes from blue to red when varying the haze production rate values from zero to twice the current Titan value. This spectral feature is the most effective way to characterize the haze production rates. Methane absorption bands in the visible-NIR compete with the absorbing haze, being more prominent for smaller haze production rates. The effective transit heights probe a region of the atmosphere where the haze and gas are optically thin and that is thus not effectively probed by the geometric albedo. The effective transit height decreases smoothly with increasing wavelength, from 376 km to 123 km at 0.2 and 2 μm, respectively. When decreasing the haze production rate, the methane absorption bands become more prominent, and the effective transit height decreases with a steeper slope with increasing wavelength. The slope of the geometric albedo in the UV-visible increases smoothly with increasing haze production rate, while the slope of the effective transit height spectra is not sensitive to the haze production rate other than showing a sharp rise when the haze production rate increases from zero. We conclude that geometric albedo spectra provide the most sensitive indicator of the haze production rate and the background Rayleigh gas. Our results suggest that important and complementary information can be obtained from the geometric albedo and motivates improvements in the technology for direct imaging of nearby exoplanets.

  2. Titan-Like Exoplanets: Variations in Geometric Albedo and Effective Transit Height with Haze Production Rate

    NASA Technical Reports Server (NTRS)

    Checlair, Jade; McKay, Christopher P.; Imanaka, Hiroshi

    2016-01-01

    Extensive studies characterizing Titan present an opportunity to study the atmospheric properties of Titan-like exoplanets. Using an existing model of Titan's atmospheric haze, we computed geometric albedo spectra and effective transit height spectra for six values of the haze production rate (zero haze to twice present) over a wide range of wavelengths (0.2-2 microns). In the geometric albedo spectra, the slope in the UV-visible changes from blue to red when varying the haze production rate values from zero to twice the current Titan value. This spectral feature is the most effective way to characterize the haze production rates. Methane absorption bands in the visible-NIR compete with the absorbing haze, being more prominent for smaller haze production rates. The effective transit heights probe a region of the atmosphere where the haze and gas are optically thin and that is thus not effectively probed by the geometric albedo. The effective transit height decreases smoothly with increasing wavelength, from 376 km to 123 km at 0.2 and 2 microns, respectively. When decreasing the haze production rate, the methane absorption bands become more prominent, and the effective transit height decreases with a steeper slope with increasing wavelength. The slope of the geometric albedo in the UV-visible increases smoothly with increasing haze production rate, while the slope of the effective transit height spectra is not sensitive to the haze production rate other than showing a sharp rise when the haze production rate increases from zero. We conclude that geometric albedo spectra provide the most sensitive indicator of the haze production rate and the background Rayleigh gas. Our results suggest that important and complementary information can be obtained from the geometric albedo and motivates improvements in the technology for direct imaging of nearby exoplanets.

  3. Respirometric kinetic parameter calculations of a batch jet loop bioreactor treating leachate and oxygen uptake rate estimation by DTM.

    PubMed

    Ince, M; Yildiz, F; Engin, G Onkal; Engin, S N; Keskinler, B

    2008-05-30

    A novel circulating jet loop bioreactor adapted for organic matter oxidation has been designed and constructed. In this study, the input was leachate samples collected from Kemerburgaz Odayeri waste landfill site located on the European side of Istanbul. Controlling the jet loop bioreactor to realize high rates of purification depends on maintaining the appropriate loadings and operating conditions. This requires collecting various system data to estimate the dynamics of the system satisfactorily with the aim of keeping certain parameters within the specified range. The differential transform method (DTM) based solution of the state equations reveals the current state of the process so that any deviation in the system parameters can be immediately detected and regulated accordingly. The respirometric method for kinetic parameter calculations for biodegradation has been used for some time. In many studies, the respirometer was designed separately, usually in bench-scale. However, when a separate respirometer is used, the scale effect and parameters that affect the hydrodynamic structure of the system should be taken into consideration. In this study, therefore, the jet loop reactor itself was used as a respirometer. Thus, the kinetic parameters found reflecting the characteristics of microorganisms used for biodegradation would be more realistic. If the main reactor, here the jet loop reactor, would be used as the respirometer, the kinetic parameter changes can easily be monitored in the long run. Using the bioreactor as a respirometer, the most important kinetic parameters, Ks, kd and micromax were found to be 11,000 mg L(-1), 0.019 day(-1), and 0.21 day(-1), respectively. The stoichiometric coefficient, Y, was found to be 0.28 gr gr(-1) for the present system.

  4. Measurements of radon exhalation rate in NORM used as consumer products in Japan.

    PubMed

    Iwaoka, Kazuki; Hosoda, Masahiro; Yajima, Kazuaki; Tokonami, Shinji

    2017-01-25

    Twenty-five beauty products known to contain natural radionuclides were collected, and their (222)Rn mass exhalation rates were measured. The effective doses to workers due to (222)Rn exhaled from these products were estimated. The (222)Rn mass exhalation rates of these products were below 177 μBq kg(-1) s(-1) and were almost identical to those of natural rocks in Japan. The maximum effective dose of (222)Rn exhaled from these products was 71 μSv y(-1).

  5. Rapid rates of soil production in the western Southern Alps, New Zealand

    NASA Astrophysics Data System (ADS)

    Larsen, I. J.; Almond, P. C.; Eger, A.; Stone, J. O.; Malcolm, B.; Montgomery, D. R.

    2012-12-01

    Quantifying rates of soil production is necessary for determining the relative magnitude of the processes that drive the evolution of mountain topography and for assessing proposed links among tectonic uplift, erosion, weathering, and global biogeochemical cycles. However, little is known about the role soil production plays in the denudation of rapidly uplifting mountains. We addressed this problem by sampling soil and river sediment from five catchments in the rapidly uplifting and high rainfall portion of the western Southern Alps, New Zealand. Soils were sampled from ridgetops with subalpine forest and dense alpine shrubland vegetation. Results from 11 measurements of in situ-produced 10Be in soils from three catchments show that rock is rapidly converted to soil, with the highest measured rate approaching 2 mm yr-1. Soil production rates at two of the ridgetops decline exponentially as soil depth increases, consistent with previously proposed soil production functions. The third site exhibits an ambiguous soil production rate-depth relationship. The y-intercepts, or maximum predicted soil production rate where the soil depth is equal to zero, at the sites with well-defined soil production functions are 7-9 times greater than those in other tectonically-active mountains and 1-2 orders of magnitude greater than values from drier and more tectonically-quiescent landscapes, indicating that rock can be converted to soil at substantially higher rates than previously recognized. The maximum predicted soil production rate values are 1.5 to 2.5 times lower than watershed-scale denudation rates inferred from in situ 10Be concentrations in stream sediment, indicating that soil production rates approach, but do not reach catchment-averaged values, which also reflect denudation by bedrock landslides. Ongoing work on additional samples will lead to a refinement of the soil production functions and provide rates for two additional sites. In-progress measurement of zirconium

  6. High Acetic Acid Production Rate Obtained by Microbial Electrosynthesis from Carbon Dioxide.

    PubMed

    Jourdin, Ludovic; Grieger, Timothy; Monetti, Juliette; Flexer, Victoria; Freguia, Stefano; Lu, Yang; Chen, Jun; Romano, Mark; Wallace, Gordon G; Keller, Jurg

    2015-11-17

    High product specificity and production rate are regarded as key success parameters for large-scale applicability of a (bio)chemical reaction technology. Here, we report a significant performance enhancement in acetate formation from CO2, reaching comparable productivity levels as in industrial fermentation processes (volumetric production rate and product yield). A biocathode current density of -102 ± 1 A m(-2) and an acetic acid production rate of 685 ± 30 (g m(-2) day(-1)) have been achieved in this study. High recoveries of 94 ± 2% of the CO2 supplied as the sole carbon source and 100 ± 4% of electrons into the final product (acetic acid) were achieved after development of a mature biofilm, reaching an elevated product titer of up to 11 g L(-1). This high product specificity is remarkable for mixed microbial cultures, which would make the product downstream processing easier and the technology more attractive. This performance enhancement was enabled through the combination of a well-acclimatized and enriched microbial culture (very fast start-up after culture transfer), coupled with the use of a newly synthesized electrode material, EPD-3D. The throwing power of the electrophoretic deposition technique, a method suitable for large-scale production, was harnessed to form multiwalled carbon nanotube coatings onto reticulated vitreous carbon to generate a hierarchical porous structure.

  7. 40 CFR Table S-1 to Subpart S of... - Basic Parameters for the Calculation of Emission Factors for Lime Production

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Basic Parameters for the Calculation of Emission Factors for Lime Production S Table S-1 to Subpart S of Part 98 Protection of Environment... Manufacturing Pt. 98, Subpt. S, Table S-1 Table S-1 to Subpart S of Part 98—Basic Parameters for the...

  8. Biota Modeling in EPA's Preliminary Remediation Goal and Dose Compliance Concentration Calculators for Use in EPA Superfund Risk Assessment: Explanation of Intake Rate Derivation, Transfer Factor Compilation, and Mass Loading Factor Sources

    SciTech Connect

    Manning, Karessa L.; Dolislager, Fredrick G.; Bellamy, Michael B.

    2016-11-01

    The Preliminary Remediation Goal (PRG) and Dose Compliance Concentration (DCC) calculators are screening level tools that set forth Environmental Protection Agency s (EPA) recommended approaches, based upon currently available information with respect to risk assessment, for response actions at Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) sites, commonly known as Superfund. The screening levels derived by the PRG and DCC calculators are used to identify isotopes contributing the highest risk and dose as well as establish preliminary remediation goals. Each calculator has a residential gardening scenario and subsistence farmer exposure scenarios that require modeling of the transfer of contaminants from soil and water into various types of biota (crops and animal products). New publications of human intake rates of biota; farm animal intakes of water, soil, and fodder; and soil to plant interactions require updates be implemented into the PRG and DCC exposure scenarios. Recent improvements have been made in the biota modeling for these calculators, including newly derived biota intake rates, more comprehensive soil mass loading factors (MLFs), and more comprehensive soil to tissue transfer factors (TFs) for animals and soil to plant transfer factors (BV s). New biota have been added in both the produce and animal products categories that greatly improve the accuracy and utility of the PRG and DCC calculators and encompass greater geographic diversity on a national and international scale.

  9. Variability in root production, phenology, and turnover rate among 12 temperate tree species.

    PubMed

    McCormack, M Luke; Adams, Thomas S; Smithwick, Erica A H; Eissenstat, David M

    2014-08-01

    The timing of fine root production and turnover strongly influences both the seasonal potential for soil resource acquisition among competing root systems and the plant fluxes of root carbon into soil pools. However, basic patterns and variability in the rates and timing or fine root production and turnover are generally unknown among perennial plants species. We address this shortfall using a heuristic model relating root phenology to turnover together with three years of minirhizotron observations of root dynamics in 12 temperate tree species grown in a common garden. We specifically investigated how the amount and the timing of root production differ among species and how they impact estimates of fine root turnover. Across the 12 species, there was wide variation in the timing of root production with some species producing a single root flush in early summer and others producing roots either more uniformly over the growing season or in multiple pulses. Additionally, the pattern and timing of root production appeared to be consistent across years for some species but varied in others. Root turnover rate was related to total root production (P < 0.001) as species with greater root production typically had faster root turnover rates. We also found that, within species, annual root production varied up to a threefold increase between years, which led to large interannual differences in turnover rate. Results from the heuristic model indicated that shifting the pattern or timing of root production can impact estimates of root turnover rates for root populations with life spans less than one year while estimates of root turnover rate for longer lived roots were unaffected by changes in root phenology. Overall, we suggest that more detailed observations of root phenology and production will improve fidelity of root turnover estimates. Future efforts should link patterns of root phenology and production with whole-plant life history traits and variation in annual and

  10. Calculating Production Ratios for Computer-Based Multimedia Instruction: Descriptive Analyses of Production Data of Experienced Developers.

    ERIC Educational Resources Information Center

    Cates, Ward Mitchell

    2002-01-01

    Reports descriptive analyses of production data gathered from experienced instructional developers who used a commercial authoring package and supplemental coding over a one-year period to produce three separate instructional lessons on thinking skills as part of a larger commercial educational product. (Author/LRW)

  11. Assessing the Impact of Low Rate Initial Production on Army Missile System Procurement

    DTIC Science & Technology

    1994-03-01

    is not presently configured as a "fire and forget" weapon. The system utilizes semiactive laser or radar guidance against heavily armored vehicles at...Low Rate Initial Production (LRIP) has upon Army missile system development. It focuses on: (1) regulatory guidance on the use of LRIP in the...Low Rate Initial Production (LRIP) has upon Army missile system development. It focuses on: (1) regulatory guidance on the use of LRIP in the

  12. Formulation and solution of the delayed gamma dose rate problem using the concept of effective delayed gamma production cross section

    SciTech Connect

    Liew, S.L.; Ku, L.P.

    1989-06-01

    With appropriate approximations, the delayed gamma dose rate problem can be formulated in terms of the effective delayed gamma production cross section. The coupled neutron-delayed-gamma transport equations then take the same form as the coupled neutron-prompt-gamma transport equations and they can, therefore, be solved directly in the same manner. This eliminates the need for the tedious and error prone flux coupling step in conventional calculations. Mathematical formulation and solution algorithms are derived. The advantages of this method are illustrated by an example of its application in the solution of a practical design problem. 62 refs., 10 figs., 1 tab.

  13. N2O production rate of an enriched ammonia-oxidising bacteria culture exponentially correlates to its ammonia oxidation rate.

    PubMed

    Law, Yingyu; Ni, Bing-Jie; Lant, Paul; Yuan, Zhiguo

    2012-06-15

    The relationship between the ammonia oxidation rate (AOR) and nitrous oxide production rate (N(2)OR) of an enriched ammonia-oxidising bacteria (AOB) culture was investigated. The AOB culture was enriched in a nitritation system fed with synthetic anaerobic digester liquor. The AOR was controlled by adjusting the dissolved oxygen (DO) and pH levels and also by varying the initial ammonium (NH(4)(+)) concentration in batch experiments. Tests were also performed directly on the parent reactor where a stepwise decrease/increase in DO was implemented to alter AOR. The experimental data indicated a clear exponential relationship between the biomass specific N(2)OR and AOR. Four metabolic models were used to analyse the experimental data. The metabolic model formulated based on aerobic N(2)O production from the decomposition of nitrosyl radical (NOH) predicted the exponential correlation observed experimentally. The experimental data could not be reproduced by models developed on the basis of N(2)O production through nitrite (NO(2)(-)) and nitric oxide (NO) reduction by AOB.

  14. A spreadsheet calculator for estimating biogas production and economic measures for UK-based farm-fed anaerobic digesters.

    PubMed

    Wu, Anthony; Lovett, David; McEwan, Matthew; Cecelja, Franjo; Chen, Tao

    2016-11-01

    This paper presents a spreadsheet calculator to estimate biogas production and the operational revenue and costs for UK-based farm-fed anaerobic digesters. There exist sophisticated biogas production models in published literature, but the application of these in farm-fed anaerobic digesters is often impractical. This is due to the limited measuring devices, financial constraints, and the operators being non-experts in anaerobic digestion. The proposed biogas production model is designed to use the measured process variables typically available at farm-fed digesters, accounting for the effects of retention time, temperature and imperfect mixing. The estimation of the operational revenue and costs allow the owners to assess the most profitable approach to run the process. This would support the sustained use of the technology. The calculator is first compared with literature reported data, and then applied to the digester unit on a UK Farm to demonstrate its use in a practical setting.

  15. Calculated rate constants of the chemical reactions involving the main byproducts SO2F, SOF2, SO2F2 of SF6 decomposition in power equipment

    NASA Astrophysics Data System (ADS)

    Fu, Yuwei; Rong, Mingzhe; Yang, Kang; Yang, Aijun; Wang, Xiaohua; Gao, Qingqing; Liu, Dingxin; Murphy, Anthony B.

    2016-04-01

    SF6 is widely used in electrical equipment as an insulating gas. In the presence of an electric arc, partial discharge (PD) or spark, SF6 dissociation products (such as SF2, SF3 and SF4) react with the unavoidable gas impurities (such as water vapor and oxygen), electrodes and surrounding solid insulation materials, forming several toxic and corrosive byproducts. The main stable decomposition products are SO2F, SO2F2 and SOF2, which have been confirmed experimentally to have a direct relationship with discharge faults, and are thus expected to be useful in the fault diagnosis of power equipment. Various studies have been performed of the main SF6 decomposition species and their concentrations under different types of faults. However, most of the experiments focused on the qualitative analysis of the relationship between the stable products and discharge faults. Although some theoretical research on the formation of main SF6 derivatives have been carried out using chemical kinetics models, the basic data (chemical reactions and their rate constants) adopted in the model are inaccurate and incomplete. The complex chemical reactions of SF6 with the impurities are ignored in most cases. The rate constants of some reactions obtained at ambient temperature or in a narrow temperature range are adopted in the models over a far greater range, for example up to 12 000 K, due to the difficulty in the experimental measurement and theoretical estimation of rate coefficients, particularly at high temperatures. Therefore, improved theoretical models require not only the consideration of additional SF6 decomposition reactions in the presence of impurities but also on improved values of rate constants. This paper is devoted to determining the rate constants of the chemical reactions relating to the main byproducts of SF6 decomposition in SF6 gas-insulated power equipment: SO2F, SOF2 and SO2F2. Quantum chemistry calculations with density functional theory, conventional

  16. Aircraft crew radiation workplaces: comparison of measured and calculated ambient dose equivalent rate data using the EURADOS in-flight radiation data base.

    PubMed

    Beck, Peter; Bartlett, David; Lindborg, Lennart; McAulay, Ian; Schnuer, Klaus; Schraube, Hans; Spurny, Frantisek

    2006-01-01

    In May 2000, the chairman of the European Radiation Dosimetry Group (EURADOS) invited a number of experts with experience of cosmic radiation dosimetry to form a working group (WG 5) on aircraft crew dosimetry. Three observers from the Article 31 Group of Experts as well as one observer from the Joint Aviation Authorities (JAA) were also appointed. The European Commission funded the meetings. Full meetings were organised in January 2001 and in November 2001. An editorial group, who are the authors of this publication, started late in 2002 to finalise a draft report, which was submitted to the Article 31 Group of Experts in June 2003. The methods and data reported are the product of the work of 26 research institutes from the EU, USA and Canada. Some of the work was supported by contracts with the European Commission, Directorate General XII, Science, Research and Development. A first overview of the EC report was published late in 2004. In this publication we focus on a comparison of measured and calculated ambient dose rate data using the EURADOS In-Flight Data Base. The evaluation of results obtained by different methods and groups, and comparison of measurement results and the results of calculations were performed in terms of the operational quantity ambient dose equivalent, H*(10). Aspects of measurement uncertainty are reported also. The paper discusses the estimation of annual doses for given flight hours and gives an outline of further research needed in the field of aircraft crew dosimetry, such as the influence of solar particle events.

  17. Specific growth rate and substrate dependent polyhydroxybutyrate production in Saccharomyces cerevisiae.

    PubMed

    Kocharin, Kanokarn; Nielsen, Jens

    2013-03-21

    Production of the biopolymer polyhydroxybutyrate (PHB) in Saccharomyces cerevisiae starts at the end of exponential phase particularly when the specific growth rate is decreased due to the depletion of glucose in the medium. The specific growth rate and the type of carbon source (fermentable/non-fermentable) have been known to influence the cell physiology and hence affect the fermentability of S. cerevisiae. The production of PHB utilizes cytosolic acetyl-CoA as a precursor and the S. cerevisiae employed in this study is therefore a strain with the enhanced cytosolic acetyl-CoA supply. Growth and PHB production at different specific growth rates were evaluated on glucose, ethanol and a mixture of glucose and ethanol as carbon source. Ethanol as carbon source yielded a higher PHB production compared to glucose since it can be directly used for cytosolic acetyl-CoA production and hence serves as a precursor for PHB production. However, this carbon source results in lower biomass yield and hence it was found that to ensure both biomass formation and PHB production a mixture of glucose and ethanol was optimal, and this resulted in the highest volumetric productivity of PHB, 8.23 mg/L · h-1, at a dilution rate of 0.1 h-1.

  18. Elemental weathering fluxes and saprolite production rate in a Central African lateritic terrain (Nsimi, South Cameroon)

    NASA Astrophysics Data System (ADS)

    Braun, Jean-Jacques; Marechal, Jean-Christophe; Riotte, Jean; Boeglin, Jean-Loup; Bedimo Bedimo, Jean-Pierre; Ndam Ngoupayou, Jules Remy; Nyeck, Brunot; Robain, Henri; Sekhar, M.; Audry, Stéphane; Viers, Jérôme

    2012-12-01

    The comparison between contemporary and long-term weathering has been carried out in the Small Experimental Watershed (SEW) of Nsimi, South Cameroon in order to quantify the export fluxes of major and trace elements and the residence time of the lateritic weathering cover. We focus on the hillside system composed of a thick lateritic weathering cover topped by a soil layer. This study is built on the recent improvements of the hillside hydrological functioning and on the analyses of major and trace elements. The mass balance calculation at the weathering horizon scale performed with the parent rock as reference indicates (i) strong depletion profiles for alkalis (Na, K, Rb) and alkaline earths (Mg, Ca, Sr, Ba), (ii) moderate depletion profiles for Si, P, Cd, Cu, Zn, Ni and Co, (iii) depletion/enrichment profiles for Al, Ga, Ge, Sn, Pb, LREE, HREE, Y, U, Fe, V, Cr, Mn. It is noteworthy that (i) Mn and Ce are not significantly redistributed according to oxidative processes as it is the case for Fe, V and Cr, and (ii) Ge is fractionated compared to silica with enrichment in Fe-rich horizons. The calculations performed for the topsoil with iron crust as parent material reference reveal that the degradation of the iron crust is accompanied by the loss of most of the constituting elements, among which are those specifically accumulated as the redox sensitive elements (Fe, V, Cr) and iron oxide related elements like Th. The overall current elemental fluxes from the hillside system at the springs and the seepage zones are extremely low due to the inert lateritic mineralogy. Ninety-four percent of the whole Na flux generated from the hillside corrected from atmospheric deposits (77 mol/ha/yr) represents the current weathering rates of plagioclase (oligoclase) in the system, the other remaining 6% may be attributed to the dissolution of hornblende. The silica hillside flux is 300 mol/ha/yr and can be mostly attributed to the plagioclase and kaolinite dissolution. Al and Ga

  19. Phenotypic engineering of sperm-production rate confirms evolutionary predictions of sperm competition theory

    PubMed Central

    Sekii, Kiyono; Vizoso, Dita B.; Kuales, Georg; De Mulder, Katrien; Ladurner, Peter; Schärer, Lukas

    2013-01-01

    Sperm production is a key male reproductive trait and an important parameter in sperm competition theory. Under sperm competition, paternity success is predicted to depend strongly on male allocation to sperm production. Furthermore, because sperm production is inherently costly, individuals should economize in sperm expenditure, and conditional adjustment of the copulation frequency according to their sperm availability may be expected. However, experimental studies showing effects of sperm production on mating behaviour and paternity success have so far been scarce, mainly because sperm production is difficult to manipulate directly in animals. Here, we used phenotypic engineering to manipulate sperm-production rate, by employing dose-dependent RNA interference (RNAi) of a spermatogenesis-specific gene, macbol1, in the free-living flatworm Macrostomum lignano. We demonstrate (i) that our novel dose-dependent RNAi approach allows us to induce high variability in sperm-production rate; (ii) that a reduced sperm-production rate is associated with a decreased copulation frequency, suggesting conditional adjustment of mating behaviour; and (iii) that both sperm production and copulation frequency are important determinants of paternity success in a competitive situation, as predicted by sperm competition theory. Our study clearly documents the potential of phenotypic engineering via dose-dependent RNAi to test quantitative predictions of evolutionary theory. PMID:23446521

  20. D0 Silicon Upgrade: Calculating Mass Flow Rates at Sub-Sonic Conditions Trhough Venturis (FT-4052-H & FT-4053-H) and an Orifice Plate (F)-2019-H)

    SciTech Connect

    Zaczek, Mauiusz; /Fermilab

    1996-08-15

    The purpose of this engineering note is to explain the method involved in calculating the mass flow rates through venturis and orifice plates at sub-sonic conditions. In particular, the mass flow rate calculations are required for two FLOW-DYNE venturi flow meters, serial no. 35821 and no. 35822, and an orifice plate flow meter, serial no. 35823. The two venturis, FT-4052-H and FT-4053-H, are located in the D-Zero VLPC valve box at the refrigerator and the orifice plate, FO-2019-H, is on the high pressure helium supply line in the assembly building.