Sample records for protonnyj inzhektor ionov
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JPRS Report Science & Technology, USSR: Science & Technology Policy
1989-02-17
Nikolay Ilich Ionov, doctor of physical and mathematical sciences, Mikhail Aleksandrovich Mitstev, Vladimir Ilich Paleyev, candidates of physical...Petrovich Stepa- nov, doctor of chemical sciences, deputy director, Niko- lay Grigoryevich Ilyushchenko, Vladimir Yakovlevich Kudyakov and Mikhail ...Shestakov, USSR Academy of Sciences corre- sponding member, Mikhail Viktorovich Gusev, Andrey Borisovich Rubin and Feliks Fedorovich Litvin
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NASA Astrophysics Data System (ADS)
Ionov, Dmitri
2010-05-01
, major and trace element and isotope compositions of fertile lherzolites and thus cannot provide viable alternatives to the concept of melt extraction from pristine mantle as the major mechanism of CLM formation. Published data on xenoliths from andesitic volcanoes and on supra-subduction oceanic peridotites [4] show that the most common rocks in mantle wedge lithosphere are highly refractory harzburgites characterized by a combination of variable but generally high modal opx (18-30%) with very low modal cpx (1.5-3%). At a given olivine (or MgO) content, they have higher opx and silica, and lower cpx, Al and Ca contents than normal refractory peridotite xenoliths in continental basalts; the Mg-Si and Al-Si trends in those rocks resemble those in cratonic peridotites. These features may indicate either fluid fluxing during melting in the mantle wedge or selective post-melting metasomatic enrichments in silica to transform some olivine to opx. High oxygen fugacities and radiogenic Os-isotope compositions in those rocks may be related to enrichments by slab-derived fluids, but these features are not always coupled with trace element enrichments or patterns commonly attributed to "subduction zone metasomatism" deduced from studies of arc volcanic rocks and experiments. The valuable insights provided by experimental work and xenolith case studies are difficult to apply to many natural peridotite series because late-stage processes commonly overlap the evidence for initial melting. References: [1] Herzberg C., J. Petrol. 45: 2507 (2004). [2] Ionov D. & Sobolev A., GCA 72 (S1): A410 (2008). [3] Ionov D., Contrib. Miner. Petrol. (2007) [4] Ionov D., J. Petrol. doi: 10.1093/petrology/egp090 (2010)
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Re-Os-PGE constraints on continental lithosphere assembly: a case study in eastern Russia
NASA Astrophysics Data System (ADS)
Nelson, W. R.; Ionov, D. A.; Shirey, S. B.; Prikhod'Ko, V. S.
2010-12-01
Archean cratons are the old, stable nuclei around which continents are assembled as non-cratonic material is added to the periphery of cratons by subduction-driven accretion, volcanism, and reworking of existing material. In eastern Eurasia, Phanerozoic subduction-related processes have severely altered cratonic mantle at the SE margin of Siberia (Tok) and destabilized North China cratonic mantle, resulting in early Mesozoic delamination and possible recycling into the convecting mantle. It is unclear how younger, off-craton continental mantle lithosphere is produced and modified during subsequent subduction and collision events, what mantle compositions can form in these settings, and whether any previous cratonic lithosphere may be retained. In order to investigate this problem, we collected Re-Os and PGE data on 24 peridotite xenoliths from four basaltic eruptive centers - Fevralsky, Sveyagin, Medvezhy, and Kurose - located along a cross section of the eastern Eurasian mantle between the Siberian craton and Japan. Fevralsky spinel lherzolites are the closest xenoliths to the Siberian craton. Like peridotites from Tok (Ionov et al., 2006), some Fevralsky xenoliths record metasomatic influence (Al2O3 = 4.6-4.9 wt. %; Re =0.33-2.42 ppb). However, unlike the Tok peridotites, this event did not significantly affect primitive mantle-like abundances of Os (3.3-3.9 ppb) and other PGE, or 187Os/188Os ratios (0.1185-0.1282). Further south, Sveyagin spinel lherzolites are from a Proterozoic microcontinent accreted to Eurasia during the Mesozoic. Sveyagin xenoliths have not experienced Re addition. Instead, Re (0.06-0.20 ppb) and PGE concentrations, 187Os/188Os (0.120-0.129), and 187Re/188Os (0.182-0.433) are consistent with minor to moderate melt extraction from primitive mantle. A Re-Os isochron estimates that Sveyagin xenoliths formed at ~ 1.9 Ga, consistent with TMA ages (1.4-3.4 Ga). This may be coeval with a metasomatic event that affected the Tok region (Ionov et al
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NASA Astrophysics Data System (ADS)
Krause, J.; Brügmann, G. E.; Pushkarev, E. V.
2009-04-01
The partitioning of trace elements between rock forming minerals in igneous rocks is largely controlled by physical and chemical parameters e.g. temperature, pressure and chemical composition of the minerals and the coexisting melt. In the present study partition coefficients for REE between hornblende, orthopyroxene, feldspars, apatite and clinopyroxene in a suite of co-genetic alkaline and tholeiitic mafic rocks from the Ural Mountains (Russia) were calculated. The results give insights to the influence of the chemical composition of the parental melt on the partitioning behaviour of the REE. Nepheline-bearing, alkaline melanogabbros (tilaites) are assumed to represent the most fractionated products of the melt that formed the ultramafic cumulates in zoned mafic-ultramafic complexes in the Ural Mountains. Co-genetic with the latter is a suite of olivine gabbros, gabbronorites and hornblende gabbros formed from a tholeiitic parental melt. Negative anomalies for the HFSE along with low Nb and Ta contents and a positive Sr anomaly indicate a subduction related origin of all parental melts. The nepheline gabbros consist predominantly of coarse-grained clinopyroxene phenocrysts in a matrix of fine grained clinopyroxene, olivine, plagioclase, K-feldspar and nepheline with accessory apatite. The tholeiitic gabbros have equigranular to porphyric textures with phenocrysts of olivine, pyroxene and hornblende in a plagioclase rich matrix with olivine hornblende, pyroxene and accessory apatite. Element concentrations of adjacent matrix grains and rims of phenochrysts were measured with LA-ICPMS. The distribution of REE between hornblende and clinopyroxene in the tholeiitic rocks is similar for most of the elements (DHblCpx(La-Tm) = 2.7-2.8, decreasing to 2.6 and 2.4 for Yb and Lu, respectively). These values are about two times higher than published data (e.g. Ionov et al. 1997). Partition coefficients for orthopyroxene/clinopyroxene systematically decrease from the HREE
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Magnesium Isotopic Composition of Kamchatka Sub-Arc Mantle Peridotites
NASA Astrophysics Data System (ADS)
Hu, Y.; Teng, F. Z.; Ionov, D. A.
2016-12-01
Subduction of the oceanic slab may add a crustal isotopic signal to the mantle wedge. The highly variable Mg isotopic compositions (δ26Mg) of the subducted oceanic crust input[1] and arc lava output[2] imply a distinctive Mg isotopic signature of the mantle wedge. Magnesium isotopic data on samples from the sub-arc mantle are still limited, however. To characterize the Mg isotopic composition of typical sub-arc mantle, 17 large and fresh spinel harzburgite xenoliths from Avacha volcano were analyzed. The harzburgites were formed by 30% melt extraction at ≤ 1 2 GPa and fluid fluxing condition, and underwent possible fluid metasomatism as suggested by distinctively high orthopyroxene mode in some samples, the presence of accessory amphibole and highly variable Ba/La ratios[3]. However, their δ26Mg values display limited variation from -0.32 to -0.21, which are comparable to the mantle average at -0.25 ± 0.07[4]. The overall mantle-like and homogenous δ26Mg of Avacha sub-arc peridotites are consistent with their similar chemical compositions and high MgO contents (> 44 wt%) relative to likely crustal fluids. Furthermore, clinopyroxene (-0.24 ± 0.10, 2SD, n = 5), a late-stage mineral exsolved from high-temperature, Ca-rich residual orthopyroxene, is in broad Mg isotopic equilibrium with olivine (-0.27 ± 0.04, 2SD, n = 17) and orthopyroxene (-0.22 ± 0.06, 2SD, n = 17). Collectively, this study finds that the Kamchatka mantle wedge, as represented by the Avacha peridotites, has a mantle-like δ26Mg, and low-degree fluid-mantle interaction does not cause significant Mg isotope fractionation in sub-arc mantle peridotites. [1] Wang et al., EPSL, 2012 [2] Teng et al., PNAS, 2016 [3] Ionov, J. Petrol., 2010, [4] Teng et al., GCA, 2010.
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NASA Astrophysics Data System (ADS)
Antoine, Bénard; Luc-Serge, Doucet; Sabine, Palle; Dmitri A., Ionov
2010-05-01
. 0.4 along Z axis) 2PEF enables analysis of 3D textural relations of tiny individual MSS globules (˜10 μm) in their various habitus. Statistical microgeometric descriptions can be derived from volumetric image data. These results may permit refinement of models concerning (re-) crystallisation kinetics and miscibility conditions of sulphur species in various media likely to act in different mantle environments: silicate melt, fluid-rich silicate melt, silicate-rich fluid. Furthermore, this study provides 3D images with improved resolution of several components (silicate phases, sulfides, silicate glass) over the full thickness (>100 μm) of rock slices which cannot be done with classical methods. Besides 3D imaging of ‘hidden' phases in mantle rocks, it opens up new possibilities for other domains in geosciences like crystallography or petrophysics. [1] Bénard & Ionov (2010) GRA, this volume [2] Abramoff, M.D., Magelhaes, P.J. & Ram, S.J. (2004) Image processing with ImageJ. Biophoton. Int., 11, 36-42
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NASA Astrophysics Data System (ADS)
Ionov, Dmitri A.; Doucet, Luc S.; Xu, Yigang; Golovin, Alexander V.; Oleinikov, Oleg B.
2018-03-01
The Obnazhennaya kimberlite in the NE Siberian craton hosts a most unusual cratonic xenolith suite, with common rocks rich in pyroxenes and garnet, and no sheared peridotites. We report petrographic and chemical data for whole rocks (WR) and minerals of 20 spinel and garnet peridotites from Obnazhennaya with Re-depletion Os isotope ages of 1.8-2.9 Ga (Ionov et al., 2015a) as well as 2 pyroxenites. The garnet-bearing rocks equilibrated at 1.6-2.8 GPa and 710-1050 °C. Some xenoliths contain vermicular spinel-pyroxene aggregates with REE patterns in clinopyroxene mimicking those of garnet. The peridotites show significant scatter of Mg# (0.888-0.924), Cr2O3 (0.2-1.4 wt.%) and high NiO (0.3-0.4 wt.%). None are pristine melting residues. Low-CaO-Al2O3 (≤0.9 wt.%) dunites and harzburgites are melt-channel materials. Peridotites with low to moderate Al2O3 (0.4-1.8 wt.%) usually have CaO > Al2O3, and some have pockets of calcite texturally equilibrated with olivine and garnet. Such carbonates, exceptional in mantle xenoliths and reported here for the first time for the Siberian mantle, provide direct evidence for modal makeover and Ca and LREE enrichments by ephemeral carbonate-rich melts. Peridotites rich in CaO and Al2O3 (2.7-8.0 wt.%) formed by reaction with silicate melts. We infer that the mantle lithosphere beneath Obnazhennaya, initially formed in the Mesoarchean, has been profoundly modified. Pervasive inter-granular percolation of highly mobile and reactive carbonate-rich liquids may have reduced the strength of the mantle lithosphere leading the way for reworking by silicate melts. The latest events before the kimberlite eruption were the formation of the carbonate-phlogopite pockets, fine-grained pyroxenite veins and spinel-pyroxene symplectites. The reworked lithospheric sections are preserved at Obnazhennaya, but similar processes could erode lithospheric roots in the SE Siberian craton (Tok) and the North China craton, where ancient melting residues and
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NASA Astrophysics Data System (ADS)
Wagner, Christiane
2017-04-01
data are compared with data on opx2 in mantle xenoliths, mostly observed in the mantle wedge above active or inactive subduction zones ([4] and references therein), as well as experimental data [5, 6]. These metasomatic opx2 are characterized by lower Al, Ca and Cr than opx1, as observed in Mont Coupet. Together with the presence of pores and of chloroapatite, the compositional characteristics of our samples are interpreted as the signature of Si-rich and Cl-bearing metasomatic fluids. They are similar to slab-derived fluids and may be in relation to the subduction event occurring during the Variscan orogeny, a possibility envisaged by [3] from recent Li isotopic studies. [1] Wagner, Goldschmidt Conf., 2015; [2] Wagner & Deloule, EGU, 2016; [3] Gu, PhD Thesis, Nancy, France, 2016; [4] Benard & Ionov, J. Petrol., 2013; [5] Perchuk & Yapaskurt, Geoch. Intern., 2013; [6] Grant et al, Am. Mineral., 2016.
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NASA Astrophysics Data System (ADS)
Doucet, Luc-Serge; Ionov, Dmitri A.; Ashchepkov, Igor
2010-05-01
contents. The broad range of heavy REE appears to be controlled by the presence and the abundance of garnet and is also related to microstructures such that granular spinel harzburgites have lower HREE contents than "fertile" porphyroclastic garnet lherzolites. Trace elements in cpx and garnet have equilibrated patterns in porphyroclastic peridotites and complex sinusoidal shapes in granular peridotites. Bulk-rock major element compositions show important variations in Mg# (0.89 - 0.93), SiO2 (41.5 - 46.6%), Al2O3 (0.3 - 4%) and CaO (0.3 - 4%). As for compatible trace elements, the major element compositions appear to be related to microstructures. Calculated modal compositions show highly variable opx contents (4.5 - 24%), which are generally lower than in Kaapvaal peridotites but are similar to those from the North Atlantic craton [3]. Overall, modal compositions and the contents of low-mobility elements, are consistent with an origin by variable degrees of partial melting of fertile mantle [1-3]. The range in FeO contents (6-8.5%) may indicate either variable melting depths [2] or post-melting enrichments. Enrichments in SiO2 show some similarities to those in supra-subduction xenoliths [4]; enrichments in highly incompatible elements can be explained by metasomatism with possible involvement of subduction-related fluids. Strong correlations between chemical compositions and microstructures indicate the involvement of tectonic processes in melt percolation and metasomatism. We suggest that the cratonic lithosphere in Siberia was formed in three stages: (1) formation of proto-cratonic mantle by high-degree melting at variable depth, (2) accretion of the proto-craton domains in subduction-related settings, (3) metasomatism commonly accompanied by deformation. [1] Boyd et al (1997) Contrib. Mineral. Petrol. 128, 228-246. [2] Herzberg (2004) J. Petrol. 45, 2507-2530. [3] Wittig et al (2008) Lithos 71, 289-322. [4] Ionov (2009) J. Petrol. In press