Science.gov

Sample records for quarterly topical progress

  1. Evaluation of geothermal energy in Arizona. Quarterly topical progress report, July 1-September 30, 1981

    SciTech Connect

    White, D.H.

    1981-01-01

    Progress is reported on the following: the legislative and institutional program, cities program, outreach, the integrated alcohol/feedlot/geothermal operation, geothermal energy in the mining industry, geothermal space heating and cooling, identification of a suitable industry for a remote geothermal site, irrigation pumping, coal-fired/geothermal-assisted power plants, and area development plans. (MHR)

  2. Quarterly Progress Report

    SciTech Connect

    David Gray; Glen Tomlinson

    1998-11-12

    The Federal Energy Technology Center (FETC) at Pittsburgh contracted with the MJTRE Corporation to perform Research Guidance Studies that will assist the Center and other relevant offices in the Department of Energy in evaluating and prioritizing research in the areas of coal and natural gas conversion. MITRE was reorganized in December 1995, which resulted in the formation of Mitretek Systems Inc. Mitretek has been performing this work on MITRE's behalf awaiting completion of contract novation to Mitretek. The contract was novated in February 1998 to Mitretek Systems. The overall objectives of this contract are to provide support to DOE in the following areas: (1) technical and economic analyses of current and future coal-based energy conversion technologies and other similar emerging technologies such as coal-waste coprocessing, natural gas conversion, and biomass conversion technologies for the production of fuels, chemicals and electric power,(2) monitor progress in these technologies with respect to technical, economic, and environmental impact (including climate change), (3) conduct specific and generic project economic and technical feasibility studies based on these technologies, (4) identify long-range R&D areas that have the greatest potential for process improvements, and (5) investigate optimum configurations and associated costs for production of high quality energy products via refining and their performance in end-use applications.

  3. Evaluation of geothermal energy in Arizona. Arizona geothermal planning/commercialization team. Quarterly topical progress report, April 1-June 30, 1980

    SciTech Connect

    White, D.H.; Mancini, F.; Goldstone, L.A.; Malysa, L.

    1980-06-30

    Progress is reported on the following: geothermal prospect identification, area development plans, site specific development analysis, time phased project plans, institutional analysis, hydrothermal commercialization baseline report, and the public outreach program. (MHR)

  4. Evaluation of geothermal energy in Arizona. Arizona geothermal planning/commercialization team. Quarterly topical progress report, July 1-September 30, 1980

    SciTech Connect

    White, D.H.; Mancini, F.; Goldstone, L.A.; Malysa, L.

    1980-01-01

    Progress is reviewed on the following: area development plans, evaluation of geothermal applications, continued evaluation of geothermal resources, engineering and economic analyses, technical assistance in the state of Arizona, the impact of various growth patterns upon geothermal energy development, and the outreach program. (MHR)

  5. LFCM (liquid-fed ceramic melter) vitrification technology: Quarterly progress report, October-December 1986

    SciTech Connect

    Brouns, R.A.; Allen, C.R.; Powell, J.A.

    1987-09-01

    This report describes the progress in developing, testing, applying, and documenting liquid-fed ceramic melter (LFCM) vitrification technology. Progress in the following technical subject areas during the first quarter of FY 1987 is discussed. Topics include melting process chemistry and glass development, feed preparation and transfer systems, melter systems, off-gas systems, canister filling and handling systems, and process/product modeling.

  6. LFCM vitrification technology: Quarterly progress report, July-September 1987

    SciTech Connect

    Brouns, R.A.; Allen, C.R.; Powell, J.A.; Bates, S.O.; Bray, L.A.; Budden, M.J.; Dierks, R.D.; Elliott, M.L.; Elmore, M.R.; Faletti, D.W.; Farnsworth, R.K.; Holton, L.K. Jr.; Kuhn, W.L.; Mellinger, G.B.; Nakaoka, R.K.; Peterson, M.E.; Piepel, G.F.; Powell, J.A.; Pulsipher, B.A.; Reimus, M.A.H.; Surma, J.E.; Wiemers, K.D.

    1988-09-01

    This report describes the progress in developing, testing, applying and documenting liquid-fed ceramic melter vitrification technology. Progress in the following technical subject areas during the fourth quarter of FY 1987 is discussed: melting process chemistry and glass development, feed preparation and transfer systems, canister filling and handling systems, and process/product modeling and control.

  7. (Topics in theoretical physics). Progress report

    SciTech Connect

    Not Available

    1985-01-01

    Progress is reported in these areas: supersymmetry and conformal invariance and new structures in two dimensional critical phenomena; spinor fields and new applications and techniques for studying Ising model correlation factors; superstring compactification and high energy physics applications for novel two dimensional critical points; ordered and disordered spatial structure in dynamical systems; and fermion-boson mass relations in BCS type theories. Research is proposed in covariant formulation of the superstring, topics in superconformal field theory and new structures in two dimensional critical phenomena, ordered and disordered spatial structure in dynamical systems, and field theory over Galois fields. 48 refs. (LEW)

  8. Quarterly Technical Progress Report June 2015

    SciTech Connect

    Buchholz, Bruce A.

    2015-06-08

    The project has two main goals: 1) Identify the types of adducts naphthalene (NA) forms with DNA and 2) determine whether adduct formation correlates with site selective tumor formation in defined subcompartments of the respiratory tract (respiratory and olfactory nasal epithelium and airways of mice, rats and rhesus monkeys). Five tasks are associated with the completion of the goals. Task 1: Contracting and Animal Use Approvals. IACUC and ACURO approvals are complete, The subcontract with UC Davis (UCD) was executed in December 2014. Task 2: Perform In Vitro Study for Goal 1. Rat samples exposed and in freezer while adduct standards are being made. Mouse samples need to be exposed in next quarter. Task 3: Perform In Vitro Study for Goal 2. Mouse ex vivo samples completed. Rat and monkey samples need to be completed in the next quarter. Task 4: Sample Preparation and Analysis. Mouse Goal 2 samples completed. Other samples remain to be done. Task 5: Data Interpretation and Reporting. Need rat data to write paper on adduct formation.

  9. Progress Report FY04 Quarter 1

    SciTech Connect

    Couch, R G; Wang, P

    2004-01-29

    In this quarter, a simulation has been carried out to validate the FEM model for a production facility mill configuration, focusing on the shape change evolution of the slab. Results of ingot shape evolution for a 13 pass rolling simulation are given in Figure 1. It was observed that the rollover of the slab is strongly dependent on friction. More studies on friction laws may be necessary for more accurate prediction. Another important feature is the mesh dependence of the result. More frequent remeshing may be necessary to be able to capture the deformation behavior more accurately. These issues are currently being investigated. Also, we expect that ATC will provide the refined fracture model to LLNL shortly. Once available, appropriate modifications will be made in the FEM subroutines, and the validation process for slab fracture will continue.

  10. LFCM vitrification technology. Quarterly progress report, October-December 1985

    SciTech Connect

    Burkholder, H.C.; Jarrett, J.H.; Minor, J.E.

    1986-09-01

    This report is compiled by the Nuclear Waste Treatment Program and the Hanford Waste Vitrification Program at Pacific Northwest Laboratory to document progress on liquid-fed ceramic melter (LFCM) vitrification technology. Progress in the following technical subject areas during the first quarter of FY 1986 is discussed: melting process chemistry and glass development, feed preparation and transfer systems, melter systems, canister filling and handling systems, off-gas systems, process/product modeling and control, and supporting studies.

  11. LFCM vitrification technology. Quarterly progress report, July-September 1985

    SciTech Connect

    Burkholder, H.C.; Jarrett, J.H.; Minor, J.E.

    1986-05-01

    This report is compiled by the Nuclear Waste Treatment Program and the Hanford Waste Vitrification Program at Pacific Northwest Laboratory to document progress on liquid-fed ceramic melter (LFCM) vitrification technology. Progress in the following technical subject areas during the fourth quarter of FY 1985 is discussed: melting process chemistry and glass development, feed preparation and transfer systems, melter systems, canister filling and handling systems, off-gas systems, process/product modeling and control, and supporting studies.

  12. Heber geothermal binary demonstration project quarterly technical progress report, July 1, 1981--September 30, 1981

    SciTech Connect

    Lacy, R.G.; Allen, R.F.; Alsup, R.A.; Liparidis, G.S.; Van De Mark, G.D.

    1983-08-01

    The purpose of this quarterly technical progress report is to document work completed on the nominal 65 Megawatt (Mwe gross) Heber Geothermal Binary Demonstration Project, located at Heber, California, during the period of July 1, 1981, through September 30, 1981. The work was performed by San Diego Gas and Electric Company under the support and cooperation of the US Department of Energy, the Electric Power Research Institute, the Imperial Irrigation District, the California Department of Water Resources, and the Southern California Edison Company. Topics covered in this quarterly report include progress made in the areas of Wells and Fluid production and Injection Systems, Power Plant Design and Construction, Power Plant Demonstration, and Data Acquisition and Dissemination.

  13. Heber geothermal binary demonstration project quarterly technical progress report, October 1, 1982--December 31, 1982

    SciTech Connect

    Lacy, R.G.; Allen, R.F.; Dixon, J.R.; Hsiao, W.P.; Liparidis, G.S.; Lombard, G.L.; Nelson, T.T.; Van De Mark, G.D.

    1983-05-01

    The purpose of this quarterly technical progress report is to document work completed on the nominal 65 Megawatt (Mwe gross) Heber Geothermal Binary Demonstration Project, located at Heber, California, during the period of October 1, 1982--December 31, 1982. The work was performed by San Diego Gas and Electric Company under the support and cooperation of the U.S. Department of Energy, the Electric Power Research Institute, the Imperial Irrigation District, the California Department of Water Resources, and the Southern California Edison Company. Topics covered in this quarterly report include progress made in the areas of Wells and Fluid Production and Injection Systems, Power Plant Design and Construction, Power Plant Demonstration, and Data Acquisition and Dissemination.

  14. Scholarly but Relevant: A Comparison of Topic Frequency between "Journalism Quarterly,""Journal of Broadcasting & Electronic Media," and RTNDA "Communicator."

    ERIC Educational Resources Information Center

    Ozmun, David

    A study compared the topics addressed in a professional trade publication, the RTNDA (Radio and Television News Directors Association) "Communicator," with topics specifically addressing broadcast news in the scholarly journals "Journalism Quarterly" and "Journal of Broadcasting and Electronic Media." The purpose of…

  15. Advanced Reactor Safety Research Division. Quarterly progress report, January 1-March 31, 1980

    SciTech Connect

    Agrawal, A.K.; Cerbone, R.J.; Sastre, C.

    1980-06-01

    The Advanced Reactor Safety Research Programs quarterly progress report describes current activities and technical progress in the programs at Brookhaven National Laboratory sponsored by the USNRC Division of Reactor Safety Research. The projects reported each quarter are the following: HTGR Safety Evaluation, SSC Code Development, LMFBR Safety Experiments, and Fast Reactor Safety Code Validation.

  16. Advanced Reactor Safety Research Division. Quarterly progress report, April 1-June 30, 1980

    SciTech Connect

    Romano, A.J.

    1980-01-01

    The Advanced Reactor Safety Research Programs Quarterly Progress Report describes current activities and technical progress in the programs at Brookhaven National Laboratory sponsored by the USNRC Division of Reactor Safety Research. The projects reported each quarter are the following: HTGR safety evaluation, SSC Code Development, LMFBR Safety Experiments, and Fast Reactor Safety Code Validation.

  17. Tribopolymerization as an anti-wear mechanism. Quarterly progress report

    SciTech Connect

    Furey, M.J.

    1996-04-01

    The primary objective of this activity is to obtain the necessary data which would enhance, promote, and encourage the introduction of advanced lubrication technology into the marketplace. This includes (a) defining specific but different applications, (b) establishing the limits or ranges of applied loads, speeds, and temperatures over which the concept of tribopolymerization would work in reducing wear and/or friction, (c) continuing in efforts to understand the film-forming process (this rates to (b) above), using this knowledge to develop new and even more effective additives, and (d) exploring possible connections with private and investment companies for the licensing and marketing of products which will reduce friction and wear in a variety of applications. Progress was made in several different but connected areas. These included (a) establishing of load/velocity limits of selected monomers for ceramic lubrication, (b) the discovery of new and effective monomers designed for higher temperature anti-wear applications, (c) improvements and modifications of the high load/high speed pin-on-disk machine, (d) the initiation of related or spin-off projects designed to get their advanced technology into the marketplace, (e) the filing of three new patent applications, and (f) collaborative research with Dr. Kajdas--the co-inventor with Dr. Furey--on tribopolymerization as a novel and effective approach to the boundary lubrication of ceramics and steel. These and other elements of progress made during the first Quarter of 1996 are discussed briefly.

  18. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, July 1--September 30, 1992

    SciTech Connect

    Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-11-01

    This is the twelfth Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Major topics reported are: Summaries of the final reports produced by Lehigh University, West Virginia University, and Vander Sande Associates under the Participants Program are presented. Analytical data produced by CONSOL are provided in Appendix I for all samples employed in the Participants Program and issued with the samples to research groups in the Participants Program. A paper was presented at the 1992 US Department of Energy Pittsburgh Energy Technology Center Liquefaction Contractors` Review Conference, held in Pittsburgh September 23--24, 1992, entitled ``The Chemical Nature of Coal Liquid Resids and the Implications for Process Development``. It appears as Appendix 2 in this report.

  19. Water Reactor Safety Research Division quarterly progress report, January 1-March 31, 1980

    SciTech Connect

    Romano, A.J.

    1980-06-01

    The Water Reactor Safety Research Programs Quarterly Report describes current activities and technical progress in the programs at Brookhaven National Laboratory sponsored by the USNRC Division of Reactor Safety Research. The projects reported each quarter are the following: LWR Thermal Hydraulic Development, Advanced Code Evaluation, TRAC Code Assessment, and Stress Corrosion Cracking of PWR Steam Generator Tubing.

  20. Water Reactor Safety Research Division. Quarterly progress report, April 1-June 30, 1980

    SciTech Connect

    Abuaf, N.; Levine, M.M.; Saha, P.; van Rooyen, D.

    1980-08-01

    The Water Reactor Safety Research Programs quarterly report describes current activities and technical progress in the programs at Brookhaven National Laboratory sponsored by the USNRC Division of Reactor Safety Research. The projects reported each quarter are the following: LWR Thermal Hydraulic Development, Advanced Code Evlauation, TRAC Code Assessment, and Stress Corrosion Cracking of PWR Steam Generator Tubing.

  1. Stanford Geothermal Program (quarterly technical progress reports, July--September 1990 and October--December 1990)

    SciTech Connect

    Not Available

    1991-02-18

    For the summer quarter, progress is summarized and data are presented on the following: well test analysis of finite-conductivity fractures, theoretical investigation of adsorption phenomena, and optimization of reinjection strategy. For the fall quarter, activity focused on the adsorption and well testing projects. A new project investigating reinjection at the Geysers was initiated. (MHR)

  2. Quarterly Program Progress Report April 1, 2002-June 30, 2002

    SciTech Connect

    Palafox, Neal A., MD, MPH

    2002-07-31

    DOE B188 DOE/PHRI Special Medical Care Program in the Republic of the Marshall Islands (RMI)Quarterly Program Progress Report The DOE/PHRI Special Medical Care Program continues to provide, on a year round basis, a broad spectrum of medical care to the DOE patient population. During the fourth quarter of Year 4, the following medical services were provided: (1) Annual medical examinations for the DOE patient population (see Exhibit 1 for details). (2) Medications for the DOE patient population. (3) Preventive and primary medical care to the DOE patient population in the RMI as time and resources permit. (4) Additional manpower for the outpatient clinics at Ebeye and Majuro Hospitals (see Exhibit 2 for details). (5) Ancillary services such as labs, radiology and pharmacy in coordination with Kwajalein Hospital, Majuro Hospital and the 177 Health Care Program (177 HCP). (6) Referrals to Ebeye Hospital, Majuro Hospital and Kwajalein Hospital as necessary. (7) Referrals to Straub Clinic and Hospital in Honolulu as necessary (for details see Exhibit 1). (8) Monitored and adjusted monthly annual examination schedules based on equipment failure at Kwajalein. In addition to the above, the program was also involved in the following activities during this quarter: (1) Organized and conducted continuing medical education (CME) talks for the program's RMI staff and other RMI healthcare workers. (2) Held meetings with RMI government officials and Local Atoll government officials. (3) Input past medical records into the Electronic Medical Record (EMR) system. (4) Made adjustments to and created more templates for the EMR system. (5) Coordinated with the Public Health Departments on Majuro and Ebeye. (6) Met with PEACESAT to discuss possible collaboration on high speed Internet access. (7) Looked for opportunities to expand the program's telehealth capabilities. (8) Participated in the DOE-RMI Meeting in Honolulu. (9) Finalized the agreement with the RMI Ministry of Health and

  3. Progress Report and Topical Survey, 1980-1981.

    DTIC Science & Technology

    1981-03-01

    welcomes the transmittal of comments about the choice and desgin of its research program, and of information about topics connected with the subject of...7 AD-AlOS5 117 STANFORD) UNIV CA CENTER FOR RESEARCH ON ORGANIZATION--ETC FIG 12/1 PROGRESS REPORT AND TOPICAL SURVEY, 1980-1981. UI MAR 81 NOGR1R-79...C-0685 * fCLASFDfl l lf f N LJ OFFICE OF NAVAL RESEARCH ONR Project: CENTER FOR RESEARCH ON ORGANIZATIONAL EFFICIENCY Stanford University

  4. Los Alamos National Laboratory Science Education Programs. Quarterly progress report, April 1--June 30, 1995

    SciTech Connect

    Gill, D.

    1995-09-01

    This report is quarterly progress report on the Los Alamos National Laboratory Science Education Programs. Included in the report are dicussions on teacher and faculty enhancement, curriculum improvement, student support, educational technology, and institutional improvement.

  5. AR and TD Fossil Energy Materials Program. Quarterly progress report for the period ending December 31, 1981

    SciTech Connect

    Not Available

    1982-04-01

    The ORNL Fossil Energy Materials Program Office compiles and issues this combined quarterly progress report from camera-ready copies submitted by each of the participating subcontractor organizations. This report of activities on the program is organized in accordance with a work breakdown structure defined in the AR and TD Fossil Energy Materials Program Plan for FY 1982-1986 in which projects are organized according to fossil energy technologies. This report is divided into parts and chapters with each part describing projects related to a particular fossil energy technology. Chapters within a part provide details of the various projects associated with that technology. We hope this series of AR and TD Fossil Energy Materials Program quarterly progress reports will aid in the dissemination of information developed on the program. Plans for the program will be issued annually. A draft of the program plan for FY 1982 to 1986 has been prepared and is in the review process. The implementation of these plans will be reflected by these quarterly progress reports, and this dissemination of information will bw augmented by topical or final reports as appropriate.

  6. Environmental surveillance program. Quarterly progress report, July--September, 1993

    SciTech Connect

    Walker, D.W.; Hall, L.F.; Downs, J.

    1996-02-01

    This report contains data developed from monitoring site measurements and laboratory analyses of environmental samples that were collected during the period of July-September, 1993. Because some laboratory procedures are lengthy and could adversely affect the desired timeliness of reports, results of some analyses from this time period will be included in the next quarterly report. Quarterly reports, then, will be routine periodic documents that present continually updated information concerning the potential presence of environmental contaminants in the vicinity of the Idaho National Engineering Laboratory (INEL). During the third calendar quarter of 1993, Environmental Surveillance Program (ESP) measurements did not reveal unexpected levels of contaminants in any environmental samples measured or analyzed. Most of the results reported in this document are related to off-site air and ground water measurements. Future reports will include results of monitoring at additional locations and for additional environmental materials. Annual reports from the ESP will contain data generated during the previous four calendar quarters, and will display measurement trends for various combinations of locations, contaminants and environmental media. The annual report will also include more interpretive material and discussions than will normally be found in quarterly reports.

  7. Coal Combustion Science quarterly progress report, April--June 1990

    SciTech Connect

    Hardesty, D.R.; Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01

    This document provides a quarterly status report of the Coal Combustion Science Program that is being conducted at the Combustion, Research Facility, Sandia National Laboratories, Livermore, California. Coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 56 refs., 25 figs., 13 tabs.

  8. Quarterly Progress Report, April 1, 1976-June 30, 1976.

    ERIC Educational Resources Information Center

    Cooney, Joan Ganz

    Quarterly activities are summarized for each of the following areas: (1) Sesame Street research, (2) Sesame Street production, (3) The Electric Company research, (4) The Electric Company production, (5) community education services, (6) public affairs, and (7) personnel. Activities are outlined within each section, and the public affairs section…

  9. Quarterly Progress Report, April 1, 1976-June 30, 1976.

    ERIC Educational Resources Information Center

    Cooney, Joan Ganz

    Quarterly activities are summarized for each of the following areas: (1) Sesame Street research, (2) Sesame Street production, (3) The Electric Company research, (4) The Electric Company production, (5) community education services, (6) public affairs, and (7) personnel. Activities are outlined within each section, and the public affairs section…

  10. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, July 1--September 30, 1993

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1994-03-01

    This is the Sixteenth Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Major topics reported are: Fifty-eight process samples from HRI CTSL Bench Unit Run CC-15 (227-75) were analyzed to provide information on process performance. Run CC-15 was operated for 14 periods (days) from October 21 through November 3, 1992 in the thermal/catalytic configuration with Black Thunder Mine (Wyodak and Anderson seams) coal and Shell S-317 Ni/Mo supported extrudate catalyst. The run was made to test performance with and without a dispersed hydrous iron hydroxide catalyst precursor impregnated in the coal. Results are compared with those of previous HRI CTSL bench unit Run CC-1, which was operated in the catalytic/catalytic configuration, also with Shell S-317 catalyst. Several HRI Run CC-15 product distillate fractions prepared by the National Institute for Petroleum and Energy Research (NIPER) for petroleum inspection tests were further characterized by CONSOL. These characterization data are presented. MicroAutoclave tests and chemical analyses were performed to evaluate the solvent quality of two potential solvents for Alberta Research Council ARC. Eight product samples from catalytic dehydrogenation experiments were characterized for the University of Pittsburgh. A description is presented of the thermogravimetric analysis (TGA) method for determination of resid concentration/resid conversion, which was adapted for use in-house from HRI`s standard method. A brief summary of the status of the Participants Program is given.

  11. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, April 1--June 30, 1992

    SciTech Connect

    Brandes, S.D.; Lancet, M.S.; Robbins, G.A.; Winschel, R.A.; Burke, F.P.

    1992-11-01

    This is the eleventh Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Major topics reported are: (1) The results of a study designed to determine the effects of the conditions employed at the Wilsonville slurry preheater vessel on coal conversion is described. (2) Stable carbon isotope ratios were determined and used to source the carbon of three product samples from Period 49 of UOP bench-scale coprocessing Run 37. The results from this coprocessing run agree with the general trends observed in other coprocessing runs that we have studied. (3) Microautoclave tests and chemical analyses were performed to ``calibrate`` the reactivity of the standard coal used for determining donor solvent quality of process oils in this contract. (4) Several aspects of Wilsonville Close-Coupled Integrated Two-Stage Liquefaction (CC-ITSL) resid conversion kinetics were investigated; results are presented. Error limits associated with calculations of deactivation rate constants previously reported for Runs 258 and 261 are revised and discussed. A new procedure is described that relates the conversions of 850{degrees}F{sup +} , 1050{degrees}F{sup +}, and 850 {times} 1050{degrees}F material. Resid conversions and kinetic constants previously reported for Run 260 were incorrect; corrected data and discussion are found in Appendix I of this report.

  12. Management of dry flue gas desulfurization by-products in underground mines. Quarterly technical progress report, April 1995--June 1995

    SciTech Connect

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-07-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. Previous quarterly Technical Progress Reports have set forth the specific objectives of the program, and a discussion of these is not repeated here. Rather, this report discusses the technical progress made during the period April 1 - June 30, 1995. A final topical report on the SEEC, Inc. demonstration of its technology for the transporting of coal combustion residues was completed during the quarter, although final printing of the report was accomplished early in July, 1995. The SEEC technology involves the use of Collapsible Intermodal Containers (CIC`s) developed by SEEC, and the transportation of such containers - filled with fly ash or other coal combustion residues - on rail coal cars or other transportation means. Copies of the final topical report, entitled {open_quotes}The Development and Testing of Collapsible Intermodal Containers for the Handling and Transport of Coal Combustion Residues{close_quotes} were furnished to the Morgantown Energy Technology Center. The Rapid Aging Test colums were placed in operation during the quarter. This test is to determine the long-term reaction of both the pneumatic and hydraulic mixtures to brine as a leaching material, and simulates the conditions that will be encountered in the actual underground placement of the coal combustion residues mixtures. The tests will continue for about one year.

  13. PFBC HGCU Test Facility. Technical progress report: Third Quarter, CY 1993

    SciTech Connect

    Not Available

    1993-10-01

    This is the sixteenth Technical Progress Report submitted to the Department of Energy (DOE) in connection with the cooperative agreement between the DOE and Ohio Power Company for the Tidd PFBC (pressurized fluidized-bed combustion) Hot Gas Clean Up Test Facility (HGCU). This report covers the period of work completed during the Third Quarter of CY 1993. During this quarter, the Advanced Particle Filter (APF) was operated for a total of 1295 hours. This represents 58% availability during July, August, September, and including June 30 of the previous quarter. The operating dates and times since initial operation are summarized. The APF operating temperatures and differential pressures are provided. Details of the APF runs during this quarter are included in this report.

  14. Mechanism for Clastogenic Activity of Naphthalene. Quarterly Technical Progress Report

    SciTech Connect

    Buchholz, B. A.

    2016-02-05

    The project has two main goals: 1) Identify the types of adducts naphthalene (NA) forms with DNA and 2) determine whether adduct formation correlates with site selective tumor formation in defined subcompartments of the respiratory tract (respiratory and olfactory nasal epithelium and airways of mice, rats and rhesus monkeys). Five tasks are associated with the completion of the goals. Task 1: Contracting and Animal Use Approvals. IACUC and ACURO approvals are complete. The subcontract with UC Davis (UCD) was executed in December 2014. Task 2: Perform In Vitro Study for Goal 1. Rat and mouse samples exposures completed. Monkey samples need to be exposed in next quarter. Task 3: Perform In Vitro Study for Goal 2. Mouse and rat ex vivo exposures completed. Monkey samples need to be completed in the next quarter. Task 4: Sample Preparation and Analysis. Mouse and Rat Goal 2 samples completed. Monkey samples remain to be done for Goal 2. Rat samples completed for Goal 1. Mouse and Monkey samples for Goal 1 need to be completed. Task 5: Data Interpretation and Reporting. Poster will be presented at 2016 Society of Toxicology Meeting. Outline for paper on adduct formation complete and similar to poster for SOT meeting.

  15. Molecular catalytic coal liquid conversion: Quarterly progress report

    SciTech Connect

    Stock, L.M.

    1994-09-30

    Research work has concentrated on the two general tasks that were described in the original proposal. The first task concerns the development of molecular organometallic homogeneous catalysts that can be used in the hydrogenation of coal liquids. The second task concerns non-metallic organic bases which can activate dihydrogen for arene hydrogenation, and that can be used in the conversion of coal liquids. In this Quarter, the great bulk of the efforts were expended on investigating the organic base-activated reactions of dihydrogen. The authors have proven that the reagents can effect the hydrogenation of two ring and other polycondensed aromatic hydrocarbons. Various strong organic bases were employed as the catalysts for hydrogenation of naphthalene. Several effective catalyst systems have been found for this purpose. The dependence of the reaction rates on the various factors such as temperature, hydrogen pressure, reaction time, solvents, etc. were thoroughly investigated. The substitution of dideuterium gas for dihydrogen gas in the catalytic reduction of naphthalene and anthracene has been found to provide important information concerning the simultaneous D-H exchange reactions that occur during the course of the reduction reactions. In addition, work on the development of molecular organometallic homogeneous catalysts was also done. The authors have prepared two organometallic compounds: naphthalenemolybdenum tricarbonyl and 1-methylnaphthalenemolybdenum tricarbonyl to extend the work that was begun on organometallic compounds in the last Quarter.

  16. 75 FR 52035 - Grantee Quarterly Progress Report; Extension of the Office of Management and Budget's (OMB...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-08-24

    ... Occupational Safety and Health Administration Grantee Quarterly Progress Report; Extension of the Office of...: Occupational Safety and Health Administration (OSHA), Labor. ACTION: Request for public comment. SUMMARY: OSHA..., OSHA Docket No. OSHA-2010- 0021, U.S. Department of Labor, Occupational Safety and...

  17. Responsive copolymers for enhanced petroleum recovery. Quarterly technical progress report, March 22, 1993--June 22, 1993

    SciTech Connect

    McCormick, C.; Hester, R.

    1993-08-01

    The overall goal of this research is the development of advanced water-soluble copolymers for use in enhanced oil recovery which rely on reversible microheterogeneous associations for mobility control and reservoir conformance. Technical progress for the quarter is summarized for the following tasks: advanced copolymer syntheses; characterization of molecular structure of copolymers; and polymer solution rheology.

  18. Electrostatic beneficiation of coal. Quarterly technical progress report, July 1--September 30, 1995

    SciTech Connect

    Mazumder, M.K.; Lindquist, D.; Tennal, K.B.

    1995-10-01

    The report discusses the progress made during the eighth quarter on the following tasks: assessing beneficiation (sulfur vs. ash); effect of weathering on charging and separation; charge measurement with E-SPART analyzer; particle measurement using image processing; and petrographic analysis. Some experimental data are included.

  19. HAMS (Hypoxia, Monitoring, and Mitigation System) II Quarterly Progress Report (Technical and Financial)

    DTIC Science & Technology

    2015-04-10

    percent VO2max and heart rate). VO2max represents the functional limit of their respiratory and circulatory systems to deliver O2 to active muscles...Report (Technical and Financial) Quarterly Progress Report Technical and Financial Hypoxia, Monitoring, and Mitigation System Contract...Transmitter: options ......................................................................... 10 Figure 5: HAMS II System Block diagram

  20. Nuclear materials stabilization and packaging. Quarterly progress report, October 1--December 31, 1995

    SciTech Connect

    Chidester, K.M.

    1996-05-01

    Progress is reported for Los Alamos Nuclear Materials Stabilization and Packaging projects for the first quarter of Fiscal Year 1996. Development and production activities in Plutonium Recovery and Processing, Plutonium Packaging, and Uranium Recovery and Processing are covered. Packaging quality assurance activities are reported.

  1. Projects at the Western Environmental Technology Office. Quarterly technical progress report, January 1--March 31, 1995

    SciTech Connect

    1995-06-01

    This quarterly report briefly describes recent progress in eight projects. The projects are entitled Biomass Remediation Project; Heavy Metal-Contaminated Soil Project; MHD Shutdown; Mine Waste Technology Program; Plasma Projects; Resource Recovery Project; Spray Casting Project; and Watervliet Arsenal Project.

  2. Operation Breakthrough, 1973-1974. Final Evaluation Report. And: Fourth Quarterly Progress Report for Operation Breakthrough.

    ERIC Educational Resources Information Center

    EDCON Associates, Willow Grove, PA.

    The document comprises the final evaluation report and the fourth quarterly progress report of Operation Breakthrough, an experimental demonstration project to upgrade Spanish-speaking workers in entry-level factory jobs. Ten classes at six sites with a total of 133 students were held; 53 attended at least 50 of the total 150 hours. Classes were…

  3. LFCM (liquid-fed ceramic melter) vitrification technology: Quarterly progress report, January--March 1987

    SciTech Connect

    Brouns, R. A.; Allen, C. R.; Powell, J. A.

    1988-05-01

    This report is compiled by the Nuclear Waste Treatment Program and the Hanford Waste Vitrification Program at Pacific Northwest Laboratory to describe the progress in developing, testing, applying and documenting liquid-fed ceramic melter vitrification technology. Progress in the following technical subject areas during the second quarter of FY 1987 is discussed: melting process chemistry and glass development, feed preparation and transfer systems, melter systems, canister filling and handling systems, and process/product modeling. 23 refs., 14 figs., 10 tabs.

  4. [Establishment and support of the International Power Institute]. Quarterly technical progress report, October--December, 1997

    SciTech Connect

    Coles, J.E.

    1998-04-02

    This is the quarterly report of the International Power Institute for October--December 1997. The topics of the report include pre-cooperative agreement activities, a discussion of the deputy director position, the IPI brochure, exploration of collaborative arrangements, formation of the IPI advisory board, a review of the advisory board meeting, report of a meeting with African electric utility executives, report of a visit to South Africa to explore a collaborative relationship.

  5. Performance Plan: Progress Report 2nd Quarter Fiscal Year 2000.

    ERIC Educational Resources Information Center

    Department of Education, Washington, DC. Student Financial Assistance.

    This document is progress report on the U.S. Department of Education's Student Financial Assistance (SFA) programs. Regarding its customer satisfaction objective, SFA notes that it looks to private sector leaders in e-commerce and promotes electronic services; offers electronic filing of the Free Application For Student Aid (FAFSA); offers most…

  6. Technical review of the SWELL product. Second quarterly progress report

    SciTech Connect

    Alexanian, G.

    1998-03-23

    This progress report describes design and marketing efforts made to reduce the cost of the product, and reassess its market potential in light of reduced manufacturing costs and modified design. Marketing has looked at applications in agriculture, the turf grass industry, and golf coarse applications. The new controller offers energy efficiency in control of valves and minimization of costs associated with hard wired systems.

  7. Coal combustion science. Quarterly progress report, April 1993--June 1993

    SciTech Connect

    Hardesty, D.R.

    1994-05-01

    This document is a quarterly status report of the Coal Combustion Science Project that is being conducted at the Combustion Research Facility, Sandia National Laboratories. The information reported is for Apr-Jun 1993. The objective of this work is to support the Office of Fossil Energy in executing research on coal combustion science. This project consists of basic research on coal combustion that supports both the PETC Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. The objective of the kinetics and mechanisms of pulverized coal char combustion task is to characterize the combustion behavior of selected US coals under conditions relevant to industrial pulverized coal-fired furnaces. Work is being done in four areas: kinetics of heterogeneous fuel particle populations; char combustion kinetics at high carbon conversion; the role of particle structure and the char formation process in combustion and; unification of the Sandia char combustion data base. This data base on the high temperature reactivities of chars from strategic US coals will permit identification of important fuel-specific trends and development of predictive capabilities for advanced coal combustion systems. The objective of the fate of inorganic material during coal combustion task is the establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of inorganic material during coal combustion as a function of coal type, particle size and temperature, the initial forms and distribution of inorganic species in the unreacted coal, and the local gas temperature and composition. In addition, optical diagnostic capabilities are being developed for in situ, real-time detection of inorganic vapor species and surface species during ash deposition. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

  8. Nuclear waste management. Quarterly progress report, October-December 1979

    SciTech Connect

    Platt, A.M.; Powell, J.A.

    1980-04-01

    Progress and activities are reported on the following: high-level waste immobilization, alternative waste forms, nuclear waste materials characterization, TRU waste immobilization programs, TRU waste decontamination, krypton solidification, thermal outgassing, iodine-129 fixation, monitoring of unsaturated zone transport, well-logging instrumentation development, mobile organic complexes of fission products, waste management system and safety studies, assessment of effectiveness of geologic isolation systems, waste/rock interactions technology, spent fuel and fuel pool integrity program, and engineered barriers. (DLC)

  9. Projects at the Component Development and Integration Facility. Quarterly technical progress report, July 1--September 30, 1993

    SciTech Connect

    Not Available

    1993-12-31

    This quarterly technical progress report presents progress on the projects at the Component Development and Integration Facility (CDIF) during the first quarter of FY94. The CDIF is a major US Department of Energy test facility in Butte, Montana, operated by MSE, Inc. Projects in progress include: MHD Proof-of-Concept project; mine waste technology pilot program; plasma projects; resource recovery project; sodium sulfide/ferrous sulfate project; soil washing project; and spray casting project.

  10. Projects at the Component Development and Integration Facility. Quarterly technical progress report, April 1--June 30, 1993

    SciTech Connect

    Not Available

    1993-12-01

    This quarterly technical progress report presents progress on the projects at the Component Development and Integration Facility (CDIF) during the third quarter of FY93. The CDIF is a major US Department of Energy test facility in Butte, Montana, operated by MSE, Inc. Projects in progress include: MHD Proof-of-Concept Project; Mine Waste Technology Program; Plasma Projects; Resource Recovery Project; Sodium Sulfide/Ferrous Sulfate Project; Soil Washing Project; and Spray Casting Project.

  11. Projects at the Component Development and Integration Facility. Quarterly technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect

    Not Available

    1994-08-01

    This quarterly technical progress report presents progress on the projects at the Component Development and Integration Facility (CDIF) during the second quarter of FY94. The CDIF is a major US Department of Energy test facility in Butte, Montana, operated by MSE, Inc. Projects in progress include: Biomass Remediation Project; Heavy Metal-Contaminated Soil Project; MHD Shutdown; Mine Waste Technology Pilot Program; Plasma Projects; Resource Recovery Project; Sodium Sulfide/Ferrous Sulfate Project; and Spray Casting Project.

  12. Projects at the Component Development and Integration Facility. Quarterly technical progress report, October 1--December 31, 1992

    SciTech Connect

    Not Available

    1992-12-31

    This quarterly technical progress report presents progress on the projects at the component Development and Integration Facility (CDIF) during the first quarter of FY93. The CDIF is a major US Department of Energy (DOE) test facility in Butte, Montana, operated by MSE, Inc. Projects in progress include: MHD proof-of-concept project; mine waste pilot program; plasma projects; resource recovery project; sodium sulfide/ferrous sulfate project; soil washing project; and spray casting project.

  13. Quarterly technical progress report, April-June 1982

    SciTech Connect

    1984-04-01

    Progress reports are presented for the following tasks: (1) preparation of low-rank coals; application of liquefaction processes to low-rank coals; (2) slagging fixed-bed gasification; (3) atmospheric fluidized-bed combustion of low-rank coal; (4) ash fouling and combustion modification for low-rank coal; (5) combined flue gas cleanup/simultaneous SO/sub x/-NO/sub x/ control; (6) particulate control and hydrocarbons and trace element emissions from low-rank coals; (7) waste characterization and disposal; and (9) exploratory research.

  14. Methyl chloride via oxyhydrochlorination of methane. Quarterly technical progress report No. 6, January--March 1993

    SciTech Connect

    Not Available

    1993-11-01

    The purpose of this contract is to develop a process for converting light alkane gases to methyl chloride via oxyhydrochlorination using highly selective, stable catalysts in fixed-bed reactors designed to remove the large amount of heat generated, so as to control the reaction temperature. Further, the objective is to obtain the engineering data base necessary for developing a commercially feasible process and to evaluate the economics of the process. This document reports significant progress this quarter toward the development of a stable heterogeneous packed bed catalyst for the oxyhydrochlorination of methane. This quarter`s data shows a catalyst which gave an average 18% methane conversion and 78% MeCl selectivity for a 12 day period of time. The PDU (Process Development Unit) design engineering effort made significant progress this quarter. A bid on a modular unit by Xytel Corp. was received and evaluated. The pre-engineering estimate showed that costs were considerably higher than the original project capital estimates. A rigorous effort was made to eliminate all non-essential equipment and scope of work. A reduced scope was agreed upon and in the second round both Xytel and the Dow Corning in-house facilities engineering team were allowed to bid on the package.

  15. Damage analysis and fundamental studies. Quarterly progress report, October-December 1979

    SciTech Connect

    Doran, D. G.

    1980-02-01

    Progress on each of the following topics is outlined: (1) rotating target neutron source, (2) fusion materials irradiation test facility, (3) environmental characterization, (4) damage production, and (5) damage microstructure evolution and mechanical behavior. (MOW)

  16. West Hackberry Tertiary Project. Quarterly technical progress report, January 1, 1996--March 31, 1996

    SciTech Connect

    Gillham, T.; Cerveny, B.; Turek, E.

    1996-04-10

    The goal of the West Hackberry Tertiary Project is to demonstrate the technical and economic feasibility of combining air injection with the Double Displacement Process for tertiary oil recovery. The Double Displacement Process is the gas displacement of a water invaded oil column for the purpose of recovering oil through gravity drainage. The novel aspect of this project is the use of air as the injection fluid. The target reservoir for the project is the Camerina C-1,2,3 sand located on the West Flank of West Hackberry Field in Cameron Parish, Louisiana. If successful, this project will demonstrate that the use of air injection in the Double Displacement Process can economically recover oil in reservoirs where tertiary oil recovery is presently uneconomic. The first quarter of 1996 was outstanding both in terms of volume of air injected and low cost operations. More air was injected during this quarter than in any preceding quarter. The compressors experienced much improved run time with minimal repairs. Low operating costs resulted from no repairs required for injection or production wells. A discussion of the following topics are contained herein: (1) performance summary for the injection and production wells, (2) air compressor operations, (3) updated bottom hole pressure data, (4) technology transfer activities and (5) plans for the upcoming quarter.

  17. Mitigation of biofouling using coatings. Quarterly progress report No. 3

    SciTech Connect

    Meyer, A. E.; King, R. W.

    1981-06-22

    Progress is reported in a project in which the objectives are to evaluate benefits associated with control of the surface energetic properties of materials used in heat exchangers, and to identify preferred ranges of these surface conditions that minimize deposits of biological fouling known to deteriorate heat exchange efficiencies in seawater, brackish water and freshwater systems. The technical approach employed uses special diagnostic plates in novel flow cells where fluid flow conditions can be well-controlled, modifying the surface chemistry and surface energy of the plates with very thin coatings and examining the earliest events of biofouling caused by macromolecules and microbial organisms. Information is included on exposure experiments and results and heat exchange experiments.

  18. Tribopolymerization as an anti-wear mechanism. Quarterly progress report

    SciTech Connect

    Furey, M.J.

    1996-04-01

    During the first three months of 1996, progress on the Energy-Related Project was made in several different but connected areas. These included (a) establishing of load/velocity limits of selected monomers for ceramic lubrication, (b) the discovery of new and effective monomers designed for higher temperature anti-wear applications, (c) improvements and modifications of the high load/high speed pin-on-disk machine, (d) the initiation of related or spin-off projects designed to get the advanced technology into the marketplace, (e) the filing of three new patent applications, and (f) collaborative research with Dr. Kajdas -- the co-inventor with Dr. Furey -- on tribopolymerization as a novel and effective approach to the boundary lubrication of ceramics and steel.

  19. Nuclear waste management. Quarterly progress report, October through December 1980

    SciTech Connect

    Chikalla, T.D.; Powell, J.A.

    1981-03-01

    Progress reports and summaries are presented under the following headings: high-level waste process development; alternative waste forms; nuclear waste materials characterization center; TRU waste immobilization; TRU waste decontamination; krypton solidification; thermal outgassing; iodine-129 fixation; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; mobility of organic complexes of radionuclides in soils; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology; high level waste form preparation; development of backfill material; development of structural engineered barriers; ONWI disposal charge analysis; spent fuel and fuel component integrity program; analysis of spent fuel policy implementation; analysis of postulated criticality events in a storage array of spent LWR fuel; asphalt emulsion sealing of uranium tailings; liner evaluation for uranium mill tailings; multilayer barriers for sealing of uranium tailings; application of long-term chemical biobarriers for uranium tailings; revegetation of inactive uranium tailing sites; verification instrument development.

  20. Appalachian Clean Coal Technology Consortium. Quarterly technical progress report, 1996

    SciTech Connect

    Yoon, R.-H.; Phillips, D.I.; Luttrell, G.H.; Basim, B.; Sohn, S.; Jiang, X.; Tao, D.; Parekh, B.K.; Meloy, T.

    1996-10-01

    The Appalachian Clean Coal Technology Consortium (ACCTC) has been established to help U.S. Coal producers, particularly those in the Appalachian region, increase the production of lower-sulfur coal. The cooperative research conducted as part of the consortium activities will help utilities meet the emissions standards established by the 1990 Clean Air Act Amendments, enhance the competitiveness of U.S. coals in the world market, create jobs in economically-depressed coal producing regions, and reduce U.S. dependence on foreign energy supplies. The consortium has three charter members, including Virginia Polytechnic Institute and State University, West Virginia University, and the University of Kentucky. The Consortium also includes industry affiliate members that form an Advisory Committee. In keeping with the recommendations of the Advisory Committee, first-year R&D activities were focused on two areas of research: fine coal dewatering and modeling of spirals. The industry representatives to the Consortium identified fine coal dewatering as the most needed area of technology development. Dewatering studies were conducted by Virginia Tech`s Center for Coal and Minerals Processing and a spiral model was developed by West Virginia University. For the University of Kentucky the advisory board approved a project entitled: ``A Study of Novel Approaches for Destabilization of Flotation Froth``. Project management and administration will be provided by Virginia Tech., for the first year. Progress reports for coal dewatering and destabilization of flotation froth studies are presented in this report.

  1. Short-rotation woody-crops program. Quarterly progress report for period ending May 31, 1981

    SciTech Connect

    Cushman, J.H.; Ranney, J.W.

    1982-04-01

    Progress of twenty projects in the Short Rotation Woody Crops Program is summarized for the period March 1 through May 31, 1981. Individual quarterly reports included from each of the projects discuss accomplishments within specific project objectives and identify recent papers and publications resulting from the research. The major project activities are species screening and genetic selection, stand establishment and cultural treatment, and harvest, collection, transportation, and storage.

  2. Short-rotation woody-crops program. Quarterly progress report for period ending August 31, 1981

    SciTech Connect

    Cushman, J.H.; Ranney, J.W.

    1982-04-01

    Progress of twenty-one projects in the Short Rotation Woody Crops Program is summarized for the period June 1 through August 31, 1981. Individual quarterly reports included from each of the projects discuss accomplishments within specific project objectives and identify recent papers and publications resulting from the research. The major program activities are species screening and genetic selection, stand establishment and cultural treatment, and harvest, collection, transportation, and storage.

  3. Quarterly Progress Report: Modeling and Simulation of the Homopolar Motor Test Apparatus

    DTIC Science & Technology

    2006-05-01

    Quarterly Progress Report: Modeling and Simulation of the Homopolar Motor Test Apparatus 5. FUNDING NUMBERS Contract # N00014-1-0588 6. AUTHOR(S) K...superconducting homopolar motor /generator (SCHPMG) machine for ship propulsion. Electrical contact (brush/slip ring) performance is a limiting factor in SCHPMG...SUBJECT TERMS superconducting homopolar motors , inhomogenous brush wear, polarity dependence, destabilized force 15. NUMBER OF PAGES 11 16. PRICE CODE

  4. Nuclear magnetic resonance studies of granular flows: Technical progress report, quarter ending 09/30/93

    SciTech Connect

    Not Available

    1993-10-27

    This Technical Progress Report for the quarter ending 09/30/93 describes work on two tasks which are part of nuclear magnetic resonance studies of granular flows. (1) Research has been directed toward improving concentration measurements under reasonably fast conditions. (2) The process continues of obtaining comprehensive velocity, concentration, and diffusion information at several angular velocities of the cylinder for seeds (mustard, sesame, and sunflower seeds) flowing in a half-filled cylinder.

  5. Heat Source Technology Programs. Quarterly progress report, April--June 1993

    SciTech Connect

    George, T.G.

    1993-12-01

    This quarterly report describes activities performed in support of Cassini fueled-clad production and studies related to the use of {sup 238}PuO{sub 2} in radioisotope power systems carried out for the Office of Special Applications of the US Department of Energy (DOE) by Los Alamos National Laboratory (LANL). Most of the activities described are ongoing; the results and conclusions described may change as the work progresses.

  6. MHD Integrated Topping Cycle Project. Eighteenth quarterly technical progress report, November 1, 1991--January 31, 1992

    SciTech Connect

    Not Available

    1992-07-01

    This eighteenth quarterly technical progress report of the MHD Integrated Topping cycle Project presents the accomplishments during the period November 1, 1991 to January 31, 1992. The precombustor is fully assembled. Manufacturing of all slagging stage components has been completed. All cooling panels were welded in place and the panel/shell gap was filled with RTV. Final combustor assembly is in progress. The low pressure cooling subsystem (LPCS) was delivered to the CDIF. Second stage brazing issues were resolved. The construction of the two anode power cabinets was completed.

  7. Robotic weld overlay coatings for erosion control. Quarterly technical progress report, April 1993--June 1993

    SciTech Connect

    Levin, B.F.; Dupont, J.N.; Marder, A.R.

    1993-07-20

    Twelve weld overlay hardfacing alloys have been selected for preliminary erosion testing based upon a literature review. Four of the selected coatings were deposited on a 1018 steel substrate using plasma arc welding process. During the past quarter, the remaining eight coatings were deposited in the same manner. Ten samples from each coatings were prepared for erosion testing. Microstructural characterization of each coating is in progress. This progress report describes coating deposition and sample preparation procedures. Relation between coatings hardness and formation of cracks in coatings is discussed.

  8. Progressive Learning of Topic Modeling Parameters: A Visual Analytics Framework.

    PubMed

    El-Assady, Mennatallah; Sevastjanova, Rita; Sperrle, Fabian; Keim, Daniel; Collins, Christopher

    2017-08-29

    Topic modeling algorithms are widely used to analyze the thematic composition of text corpora but remain difficult to interpret and adjust. Addressing these limitations, we present a modular visual analytics framework, tackling the understandability and adaptability of topic models through a user-driven reinforcement learning process which does not require a deep understanding of the underlying topic modeling algorithms. Given a document corpus, our approach initializes two algorithm configurations based on a parameter space analysis that enhances document separability. We abstract the model complexity in an interactive visual workspace for exploring the automatic matching results of two models, investigating topic summaries, analyzing parameter distributions, and reviewing documents. The main contribution of our work is an iterative decision-making technique in which users provide a document-based relevance feedback that allows the framework to converge to a user-endorsed topic distribution. We also report feedback from a two-stage study which shows that our technique results in topic model quality improvements on two independent measures.

  9. PFBC HGCU test facility technical progress report. First Quarter, CY 1994

    SciTech Connect

    Not Available

    1994-04-01

    This is the eighteenth Technical Progress Report submitted in connection with the cooperative agreement between the DOE and Ohio Power Company for the Tidd PFBC Hot Gas Clean Up Test Facility. During this quarter, the Tidd Hot Gas Clean Up System operated for 835 hours during six separate test runs. The system was starting into a seventh run at the end of the quarter. Highlights of this period are summarized below: the longest run during the quarter was approximately 333 hours; filter pressure drop was stable during all test runs this quarter using spoiling air to the primary cyclone upstream of the Advanced Particle Filter (APF); the tempering air system was commissioned this quarter which enabled the unit to operate at full load conditions while limiting the gas temperature in the APF to 1,400 F; during a portion of the one run, the tempering air was removed and the filter operated without problems up to 1,450 F; ash sampling was performed by Battelle personnel upstream and downstream of the APF and ash loading and particle size distribution data were obtained, a summary report is included; a hot area on the APF head was successfully repaired in service; a hot spot on the top of an expansion joint was successfully repaired by drilling holes from the inside of the pipe and pumping in refractory insulation; a corrosion inspection program for the HGCU system was issued giving recommendations for points to inspect; filter internal inspections following test runs 13 and 17 revealed a light coating (up to 1/4 inch thick) of residual ash on the candles and some ash bridging between the dust sheds and inner rows of candles. Data from these inspections are included with this report.

  10. Co-sponsored second quarter progress review conference on district heating

    SciTech Connect

    1980-01-01

    A summary of the progress review conference on district heating and cooling systems is presented. The agenda and lists of speakers and attendees are presented. A history of district heating and some present needs and future policies are given and an excerpt from the National District Heating Program Strategy (DOE, March 1980) is included. Following the presentation, District Heating and Cooling Systems Program, by Alan M. Rubin, a fact sheet on DOE's Integrated Community Energy Systems Program and information from an oral presentation, District Heating and Cooling Systems for Communities Through Power Plant Retrofit Distribution Network, are given. The Second Quarterly Oral Report to the US DOE on the District Heating and Cooling Project in Detroit; the executive summary of the Piqua, Ohio District Heating and Cooling Demonstration Project; the Second Quarterly Report of the Moorehead, Minnesota District Heating Project; and the report from the Moorehead, Minnesota mayor on the Hot Water District Heating Project are presented.

  11. Experimental investigation of fuel vaporization on combustion efficiency. Third quarterly progress report, January-March 1980

    SciTech Connect

    1980-01-01

    A summary of the progress achieved under the above referenced contract during the third quarter is reported here. After instituting a number of modifications, a suitable preheat flame which could provide the desired vaporization surface temperature to within an acceptable heat-up time (approx. 30 secs) was finally attained. Successful switchover to a stable vaporized and pre-mixed blue oil flame was also obtained. Preliminary data with this blue flame are presented along with vaporization surface temperature history. Adaptation of this configuration to the boiler was also initiated during this quarter so that thermal efficiency and other measurements could be conducted to assess the relative merits of oil vaporization over the spray combustion flame. Some peripheral problems identified during this experimental phase still need to be resolved during the adaptation. The details of the above results and some preliminary data obtained in the thermal efficiency set-up with the preheat flame alone are presented in the body of this report.

  12. Geothermal direct-heat utilization assistance. Quarterly project progress report, July--September 1997

    SciTech Connect

    1997-10-01

    This report summarizes geothermal technical assistance, R and D and technology transfer activities of the Geo-Heat Center at Oregon Institute of Technology for the fourth quarter of FY-97 (July--September 1997). It describes 213 contacts with parties during this period related to technical assistance with geothermal direct heat projects. Areas dealt with include requests for general information including maps, geothermal heat pumps, resource and well data, space heating and cooling, greenhouses, acquaculture, equipment, district heating, resorts and spas, and industrial applications. Research activities include the completion of a Comprehensive Greenhouse Developer Package. Work accomplished on the revision of the Geothermal Direct Use Engineering and Design Guidebook are discussed. Outreach activities include the publication of the Quarterly Bulletin (Vol. 18, No. 3), dissemination of information mainly through mailings of publications, geothermal library acquisition and use, participation in workshops, short courses, and technical meetings by the staff, and progress monitor reports on geothermal activities.

  13. Methyl chloride via oxyhydrochlorination of methane. Quarterly technical progress report No. 10, January 1944--March 1994

    SciTech Connect

    1994-08-01

    In work related to the design and construction of the Process Development Unit (PDU) this quarter involved further detail design and a real start to the construction activities. Status updates are given below for each discipline in the Task 2.0 and 3.0 headings. This work is progressing well. with the caveat of several small slips in the scheduling. On the catalyst development front this quarter was extremely productive. Many catalyst screening experiments were completed and they showed that control of the reaction exotherm is going to be quite challenging under PDU conditions. The presence of much more efficient reactor design and the ability to maintain closer to isothermal conditions is expected to give a significant advantage in actual PDU operation. A major concern at the moment is the cost of La in the catalyst being used. An action plan to remedy this is being put together.

  14. [Geothermal system temperature-depth database and model for data analysis]. 5. quarterly technical progress report

    SciTech Connect

    Blackwell, D.D.

    1998-04-25

    During this first quarter of the second year of the contract activity has involved several different tasks. The author has continued to work on three tasks most intensively during this quarter: the task of implementing the data base for geothermal system temperature-depth, the maintenance of the WWW site with the heat flow and gradient data base, and finally the development of a modeling capability for analysis of the geothermal system exploration data. The author has completed the task of developing a data base template for geothermal system temperature-depth data that can be used in conjunction with the regional data base that he had already developed and is now implementing it. Progress is described.

  15. Power systems development facility. Quarterly technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect

    Not Available

    1994-07-01

    This quarterly technical progress report summarizes work completed during the last quarter of the Second Budget Period, January 1 through March 31, 1994, entitled {open_quotes}Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.{close_quotes} The objective of this project is to evaluate hot gas particulate control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size.

  16. Topical immunomodulators--progress towards treating inflammation, infection, and cancer.

    PubMed

    Hengge, U R; Benninghoff, B; Ruzicka, T; Goos, M

    2001-10-01

    Immunomodulators include both immunostimulatory and immunosuppressive agents. Only recently have the basic mechanisms of topical immunotherapy been elucidated. Besides topical contact sensitisers (eg, diphencyprone or dinitrochlorobenzene), newer agents of the imidazoquinoline family such as imiquimod and resiquimod act by inducing cytokine secretion from monocytes or macrophages (interferon-alpha, interleukin-12, tumour-necrosis factor-alpha). The locally generated immune milieu leads to a Th1-dominance and cell-mediated immunity that have been used clinically to treat viral infections such as human papillomavirus (HPV), herpes simplex virus (HSV), mollusca, and cancerous lesions including initial squamous cell and basal cell carcinoma in immunocompetent and immunosuppressed patients. While these agents improve antigen-presentation by dendritic cells, they also act on B cells and lead to the synthesis of antibodies such as IgG2a much like the recently discovered immunostimulatory CpG-sequences that stimulate innate immunity. These sequences act as "danger signals" since they occur in bacterial and viral DNA, but are selectively methylated and inactivated in the mammalian genome. They share the induction of the same cytokines as imidazoquinolines but they show different magnitudes and kinetics of response. Topical immunotherapy with immunostimulatory agents shows potential for effective and patient-friendly treatment of inflammatory, infectious, and cancerous skin diseases. Immunoenhancers such as imdazoquinolines and CpG-sequences also have adjuvant properties that could improve conventional (protein) and DNA vaccination against cancer, atopy, and allergies.

  17. Decontamination Systems Information and Research Program. Quarterly technical progress report, January 1--March 31, 1994

    SciTech Connect

    Not Available

    1994-05-01

    West Virginia University (WVU) and the US DOE Morgantown Energy Technology Center (METC) entered into a Cooperative Agreement on August 29, 1992 entitled ``Decontamination Systems Information and Research Programs.`` Stipulated within the Agreement is the requirement that WVU submit to METC a series of Technical Progress Reports on a quarterly basis. This report comprises the first Quarterly Technical Progress Report for Year 2 of the Agreement. This report reflects the progress and/or efforts performed on the sixteen (16) technical projects encompassed by the Year 2 Agreement for the period of January 1 through March 31, 1994. In situ bioremediation of chlorinated organic solvents; Microbial enrichment for enhancing in-situ biodegradation of hazardous organic wastes; Treatment of volatile organic compounds (VOCs) using biofilters; Drain-enhanced soil flushing (DESF) for organic contaminants removal; Chemical destruction of chlorinated organic compounds; Remediation of hazardous sites with steam reforming; Soil decontamination with a packed flotation column; Use of granular activated carbon columns for the simultaneous removal of organics, heavy metals, and radionuclides; Monolayer and multilayer self-assembled polyion films for gas-phase chemical sensors; Compact mercuric iodide detector technology development; Evaluation of IR and mass spectrometric techniques for on-site monitoring of volatile organic compounds; A systematic database of the state of hazardous waste clean-up technologies; Dust control methods for insitu nuclear and hazardous waste handling; Winfield Lock and Dam remediation; and Socio-economic assessment of alternative environmental restoration technologies.

  18. PFBC HGCU Test Facility. Technical progress report No. 24, Third quarter, CY 1995

    SciTech Connect

    1995-10-01

    This is the twenty-fourth and final Technical Progress Report submitted to the Department of Energy (DOE) in connection with the cooperative agreement between the DOE and Ohio Power Company for the Tidd PFBC Hot Gas Clean Up Test Facility. This report covers the work completed during the Third Quarter of CY 1995. All activity this quarter was directed toward the completion of the program final report. A draft copy of the final report was forwarded to DOE during this quarter, and DOE submitted their comments on the report to AEPSC. DOE requested that Westinghouse write an appendix to the report covering the performance of the fail-safe regenerator devices during Tad operation, and Westinghouse subsequently prepared the appendix. Additional DOE comments were incorporated into the report, and it will be issued in camera-ready form by the end of October, 1995, which is the program end date. Appendix 1 presents the results of filter candle posttest examination by Westinghouse performed on selected filter candles following final shutdown of the system.

  19. PFBC HGCU Test Facility technical progress report second quarter, CY 1994

    SciTech Connect

    Mudd, M.J.

    1994-07-01

    This is the nineteenth Technical Progress Report submitted to the Department of Energy (DOE) in connection with the cooperative agreement between the DOE and Ohio Power Company for the Tidd PFBC Hot Gas Clean Up Test Facility. During this quarter, the Tidd Hot Gas Clean Up System operated for 444 continuous hours (including 15 hours at the end of the first quarter) during Test Run 18. The system was shut down on April 18, 1994, and remained out of service for the remainder of the quarter. Highlights of this period are summarized below: operated HGCU for 444 continuous hours which was the longest run so far in 1994; completed Hazardous Air Pollutant testing; inspected Advanced Particle Filter (APF) following testing and found 28 broken filter candles; cleaned and reassembled the APF without the inner rows of candles in the upper and middle plenums since ash bridging between these candles and the center support pipe caused the candle failures; installed 30 new filter candles of different materials for testing in the APF; and installed additional air piping and valves to permit the primary cyclone to be totally spoiled in service and thereby direct all of the ash into the filter.

  20. Fossil-energy program. Quarterly progress report for June 30, 1983

    SciTech Connect

    McNeese, L.E.

    1983-08-01

    This quarterly report covers the progress made during the period March 31 through June 30 for the Oak Ridge National Laboratory research and development projects that are carried out in support of the increased utilization of coal and other fossil fuels as sources of clean energy. These projects are supported by various parts of DOE including Fossil Energy, Basic Energy Sciences, Office of Health and Environmental Research, Office of Environmental Compliance and Overview, the Electric Power Research Institute, and by the Tennessee Valley Authority and the EPA Office of Research and Development through inter-agency agreement with DOE.

  1. Integral glass encapsulation for solar arrays. Quarterly progress report No. 14

    SciTech Connect

    1980-08-01

    This is the fourteenth quarterly report under a JPL/DOE program to develop electrostatic bonding as a method of integral encapsulation of solar cells in glass. Efforts for the current phase of this program are to continue demonstrations of process uniformity of electrostatic bonding encapsulation by production of 24-cell minimodules by ESB. Additional goals of this program are to develop preformed (wire-mesh) contacts as a method of integrating cell processing into the encapsulation procedure, resulting in a low-cost module assembly technique, and to investigate low-temperature bonding to commercially available glass (Pyrex) superstrates. Progress is reported.

  2. Geothermal direct-heat utilization assistance: Quarterly project progress report, January--March 1995

    SciTech Connect

    1995-05-01

    The report summarizes geothermal activities of the Geo-Heat Center at Oregon Institute of Technology for the second quarter of FY-95. It describes 92 contacts with parties during this period related to technical assistance with geothermal direct heat projects. Areas dealt with include geothermal heat pumps, space heating, greenhouses, aquaculture, resources and equipment. Research activities are summarized on geothermal energy cost evaluation, low temperature resource assessment and ground-source heat pump case studies and utility programs. Outreach activities include the publication of a geothermal direct heat Bulletin, dissemination of information, geothermal library, and progress monitor reports on geothermal resources and utilization.

  3. Geothermal direct-heat utilization assistance. Quarterly project progress report, July 1995--September 1995

    SciTech Connect

    Lienau, P.

    1995-12-01

    The report summarizes geothermal technical assistance, R&D and technology transfer activities of the Geo-Heat Center at Oregon Institute of Technology for the fourth quarter of FY-95. It describes 80 contacts with parties during this period related to technical assistance with geothermal direct heat projects. Areas dealt with include geothermal heat pumps, space heating, greenhouses, aquaculture, equipment and resources. Research activities are summarized on low-temperature resource assessment, geothermal energy cost evaluation and marketing strategy for geothermal district heating. Outreach activities include the publication of a geothermal direct use Bulletin, dissemination of information, geothermal library, technical papers and seminars, and progress monitor reports on geothermal resources and utilization.

  4. Recent Progress in Some Active Topics on Complex Networks

    NASA Astrophysics Data System (ADS)

    Gu, J.; Zhu, Y.; Guo, L.; Jiang, J.; Chi, L.; Li, W.; Wang, Q. A.; Cai, X.

    2015-04-01

    Complex networks have been extensively studied across many fields, especially in interdisciplinary areas. It has since long been recognized that topological structures and dynamics are important aspects for capturing the essence of complex networks. The recent years have also witnessed the emergence of several new elements which play important roles in network study. By combining the results of different research orientations in our group, we provide here a review of the recent advances in regards to spectral graph theory, opinion dynamics, interdependent networks, graph energy theory and temporal networks. We hope this will be helpful for the newcomers of those fields to discover new intriguing topics.

  5. Projects at the Component Development and Integration Facility. Quarterly technical progress report, January 1--March 31, 1993

    SciTech Connect

    Not Available

    1993-09-01

    This quarterly technical progress report presents progress on several different projects at the Component Development and Integration Facility (CDIF) during the second quarter of FY93. The CDIF is a major US Department of Energy test facility in Butte, Montana, operated by MSE, Inc. Projects in progress include: MHD Proof-of-Concept Project; Mine Waste Technology Pilot Program; Plasma Furnace Projects for waste destruction; Resource Recovery Project; Sodium Sulfide/Ferrous Sulfate Project; Soil Washing Project for removal of radioactive materials; and Spray Casting Project.

  6. Robotic weld overlay coatings for erosion control. Quarterly technical progress report, October 1994--December 1994

    SciTech Connect

    Levin, B.F.; Dupont, J.N.; Marder, A.R.

    1995-01-25

    Research is presently being conducted to develop a criteria for selecting weld overlay coatings for erosion mitigation in Circulated Fluidized Beds. Initially, eleven weld overlay alloys were selected for erosion testing based upon a literature review. All eleven coatings were deposited on 1018 steel substrates using the plasma arc welding process. Ten samples from each coating were prepared for erosion testing. The coating deposition and sample preparation procedures were described in the second quarterly report. All selected coatings were erosion tested at 400{degree}C and their erosion resistance was evaluated by determining the steady state erosion rate. In addition, the microstructure of each coating was characterized before and after the erosion tests. The results of the tests are discussed in the third quarterly report. No correlations were found between room temperature hardness of the weld overlay coatings and their erosion resistance at elevated temperature. During the last quarter tensile tests were performed at 400{degree}C for the Ultimet, Inconel-625, 316L SS, C-22, and Stellite-6 wrought alloys. The erosion tests for these materials at 400{degree}C are in progress. The results of mechanical and erosion tests will be used to correlate mechanical properties of selected wrought alloys such as tensile toughness, ductility, strain hardening coefficient and yield strength to their erosion resistance at 400{degree}C. Also, the erosion behavior of the wrought alloys compared with similar weld alloys will be analyzed. The experimental procedure and results of the tensile tests are presented in this progress report.

  7. Geothermal direct-heat utilization assistance. Quarterly progress report, January--March 1993

    SciTech Connect

    Lienau, P.

    1993-03-30

    CHC (Geo-Heated Center) staff provided assistance to 103 requests from 26 states, and from Canada, Egypt, Mexico, China, Poland and Greece. A breakdown of the requests according to application include: space and district heating (19), geothermal heat pumps (24), greenhouses (10), aquaculture (4), industrial (4), equipment (3), resources (27), electric power (2) and other (20). Progress is reported on: (1) evaluation of lineshaft turbine pump problems, (2) pilot fruit drier and (3) geothermal district heating marketing tools and equipment investigation. Four presentations and two tours were conducted during the quarter, GHC Quarterly Bulletin Vol. 14, No. 4 was prepared, 14 volumes were added to the library and information was disseminated to 45 requests. Progress reports are on: (1) GHP Teleconference 93, (2) California Energy Buys Glass Mountain Prospect from Unocal and Makes Deal for Newberry Caldera, (3) New Power Plant Planned, (4) Vale to Get Power Plant, (5) BPA Approves Geothermal Project, (6) Update: San Bernardino Reservoir Study, (7) Twenty-nine Palms Geothermal Resources, (8) Geo-Ag Heat Center, Lake County, and (9) Update: Geothermal Wells at Alturas.

  8. Coal-feeder development. Second quarterly technical progress report, January-March 1980

    SciTech Connect

    Mistry, D.K.

    1981-04-01

    The pilot-scale piston-feeder development is progressing satisfactorily and should proceed as planned. The bench scale testing of components, sub-system and critical areas continued to provide very useful information in support of the development of the complete feeder. The K30M seals and polyurethane scrapers are showing very promising results. The components development facility is being upgraded and testing at the bench scale level should be vigorously perused. The upgrading of the pilot scale feeder and its system will be emphasized during the next quarter to perform feeder capabilities and limitations testing. No progress on the 5.5-in. diameter pilot scale screw feeder has been made because IRRI is waiting decision from METC as to when the feeder can be installed on the 42-in. gas producer.

  9. TOPICAL REVIEW: Progress in cold roll bonding of metals

    NASA Astrophysics Data System (ADS)

    Li, Long; Nagai, Kotobu; Yin, Fuxing

    2008-04-01

    Layered composite materials have become an increasingly interesting topic in industrial development. Cold roll bonding (CRB), as a solid phase method of bonding same or different metals by rolling at room temperature, has been widely used in manufacturing large layered composite sheets and foils. In this paper, we provide a brief overview of a technology using layered composite materials produced by CRB and discuss the suitability of this technology in the fabrication of layered composite materials. The effects of process parameters on bonding, mainly including process and surface preparation conditions, have been analyzed. Bonding between two sheets can be realized when deformation reduction reaches a threshold value. However, it is essential to remove surface contamination layers to produce a satisfactory bond in CRB. It has been suggested that the degreasing and then scratch brushing of surfaces create a strong bonding between the layers. Bonding mechanisms, in which the film theory is expressed as the major mechanism in CRB, as well as bonding theoretical models, have also been reviewed. It has also been showed that it is easy for fcc structure metals to bond compared with bcc and hcp structure metals. In addition, hardness on bonding same metals plays an important part in CRB. Applications of composites produced by CRB in industrial fields are briefly reviewed and possible developments of CRB in the future are also described. Corrections were made to the abstract and conclusion of this article on 18 June 2008. The corrected electronic version is identical to the print version.

  10. Geothermal direct-heat utilization assistance. Quarterly project progress report, October--December 1997

    SciTech Connect

    1997-01-01

    This report summarizes geothermal technical assistance, R and D and technology transfer activities of the Geo-Heat Center at Oregon Institute of Technology for the first quarter of FY-98 (October--December 1997). It describes 216 contacts with parties during this period related to technical assistance with geothermal direct heat projects. Areas dealt with include requests for general information including maps and material for high school debates, and material on geothermal heat pumps, resource and well data, space heating and cooling, greenhouses, aquaculture, equipment, district heating, resorts and spas, industrial applications, electric power and snow melting. Research activities include work on model construction specifications of lineshaft submersible pumps and plate heat exchangers, a comprehensive aquaculture developer package and revisions to the Geothermal Direct Use Engineering and Design Guidebook. Outreach activities include the publication of the Quarterly Bulletin (Vol. 18, No. 4) which was devoted entirely to geothermal activities in South Dakota, dissemination of information mainly through mailings of publications, tours of local geothermal uses, geothermal library acquisition and use, participation in workshops, short courses and technical meetings by the staff, and progress monitor reports on geothermal activities.

  11. PFBC HGCU Test Facility. Second quarterly technical progress report, CY 1992

    SciTech Connect

    Not Available

    1992-07-01

    This is the eleventh technical progress report submitted to the Department of Energy (DOE) in connection with the Cooperative Agreement between DOE and Ohio Power company for the Tidd Pressurized Fluidized Bed Combustion (PFBC) Hot Gas Clean Up Test Facility. This report covers the period of work completed during the Second Quarter of CY 1992. Activities included: The Tidd combustor internals were modified to connect the hot gas system for slipstream operation; Various pre-operational activities were completed, including pneumatic leak testing of the HGCU system, operation of the closed cycle cooling water system, operation of the back pulse compressor and air preheater, and checkout of the back pulse skid. Initial operation of the system using the bypass cyclone occurred during May 21--23, 1992; On May 23, 1992, an expansion joint ruptured, forcing the unit to be shut down. The failure was later determined to be due to stress corrosion. Following the expansion joint failure, a complete engineering review of the system was undertaken and is continuing; Contract Modification No. 6 was issued to Westinghouse during this quarter. This modification is for APF surveillance testing services; A purchase order was issued to Battelle for ash sampling hardware and testing services.

  12. PFBC HGCU Test Facility. Fourth quarterly technical progress report, CY 1992

    SciTech Connect

    Not Available

    1993-01-01

    This is the thirteenth Technical Progress Report submitted to the Department of Energy (DOE) in connection with the cooperative agreement between the DOE and Ohio Power Company for the Tidd PFBC Hot Gas Clean Up Test Facility. This report covers the period of work completed during the Fourth Quarter of CY 1992. The following are highlights of the activities that occurred during this report period: Initial operation of the Advanced Particle Filter (APF) occurred during this quarter. The following table summarizes the operating dates and times. HGCU ash lockhopper valve plugged with ash. Primary cyclone ash pluggage. Problems with the coal water paste. Unit restarted warm 13 hours later. HGCU expansion joint No. 7 leak in internal ply of bellows. Problems encountered during these initial tests included hot spots on the APP, backup cyclone and instrumentation spools, two breakdowns of the backpulse air compressor, pluggage of the APF hopper and ash removal system, failure (breakage) of 21 filter candles, leakage of the inner ply of one (1) expansion joint bellows, and numerous other smaller problems. These operating problems are discussed in detail in a subsequent section of this report. Following shutdown and equipment inspection in December, design modifications were initiated to correct the problems noted above. The system is scheduled to resume operation in March, 1993.

  13. Federal assistance program. Quarterly project progress report, January 1998--March 1998

    SciTech Connect

    1998-04-01

    This report summarizes geothermal technical assistance, R&D and technology transfer activities of the Geo-Heat Center at Oregon Institute of Technology for the second quarter of FY-98-98 (January-March, 1998). It describes 268 contacts with parties during this period related to technical assistance with geothermal direct heat projects. Areas dealt with include requests for general information including maps and material for high school debates, and material on geothermal heat pumps, resource and well data, spacing heating and cooling, greenhouses, aquaculture, equipment, district heating, resorts and spas, industrial applications, electric power and snow melting. Research activities include work on model construction specifications for line shaft submersible pumps and plate heat exchangers and a comprehensive aquaculture developer package. The revised Geothermal Direct Use Engineering and Design Guidebooks was completed, published and is available for distribution. Outreach activities include the publication of the Quarterly Bulletin (Vol. 19, No. 1) which was devoted entirely to geothermal equipment, dissemination of information mainly through mailings of publications, tours of local geothermal uses, geothermal library acquisitions and use, participation in workshops, short courses and technical meetings by the staff, and progress monitor reports on geothermal activities.

  14. Anaerobic processing of low-rank coals. Quarterly progress report, July 1--September 30, 1992

    SciTech Connect

    Jain, M.K.; Narayan, R.; Han, O.

    1992-12-31

    The overall goal of this project is to find biological methods to remove carboxylic functionalities from low-rank coals and to assess the properties of the modified coal towards coal liquefaction. The main objectives for this quarter were: (i) continuation of microbial consortia maintenance and completion of coal decarboxylation using batch reactor system, (ii) decarboxylation of model polymer, (iii) characterization of biotreated coals, and (iv) microautoclave liquefaction of the botreated coal. Progress is reported on the thermogravimetric analysis of coal biotreated in the absence of methanogens and under 5% hydrogen gas exhibits increased volatile carbon to fixed carbon ratio; that the microbial consortia developed on coal are being adapted to two different model polymers containing free carboxylic groups to examine decarboxylation ability of consortium; completion of experiments to decarboxylate two model polymers, polyacrylic acid and polymethyl methacrylate, have been completed; that the biotreated coal showed increase in THF-solubles.

  15. [Research guidance studies]. Quarterly progress report, October 1--December 31, 1997

    SciTech Connect

    Gray, D.; Tomlinson, G.

    1997-12-31

    The overall objectives of this contract are to: (1) evaluate the technical and economic merits of current direct and indirect coal liquefaction technologies and other similar emerging technologies such as coal-waste coprocessing, natural gas conversion, and biomass conversion technologies, (2) monitor progress in these technologies, (3) conduct specific and generic project economic and technical feasibility studies based on these technologies, (4) identify long-range R and D areas that have the greatest potential for process improvements, and (5) preliminarily investigate best configurations and associated costs for refining coal-derived and other non-conventional liquids in existing petroleum refineries. During this quarter, work was continued in the area of coal/oil coprocessing with existing petroleum refineries.

  16. Quarterly technical progress report, October-December 1982 on Energy Conversion Research and Development Programs

    SciTech Connect

    Not Available

    1983-10-01

    In this quarterly technical progress report, UTSI reports on the continued design work for the low mass flow train superheater. The detailed design of this component continued and the overall arrangement drawing for the superheater and air heater was finalized. The air heater procurement reached the point of contract award, but the actual purchase order award was held up pending receipt of additional funding from the Department of Energy. Testing activity reported includes two additional tests in the LMF1C series, which concludes this test series. Test data are presented, along with preliminary analyses for the combustor, nozzle, diagnostic channel, diffuser, radiant furnace/secondary combustor and Materials Test Module. In addition to the nitrogen oxide test measurements, corrosion and erosion rates for the boiler tube specimens and the materials test module are reported.

  17. MHD Integrated Topping Cycle Project. Seventeenth quarterly technical progress report, August 1, 1991--October 31, 1991

    SciTech Connect

    Not Available

    1992-07-01

    This seventeenth quarterly technical progress report of the MHD Integrated Topping Cycle Project presents the accomplishments during the period August 1, 1991 to October 31, 1991. Manufacturing of the prototypical combustor pressure shell has been completed including leak, proof, and assembly fit checking. Manufacturing of forty-five cooling panels was also completed including leak, proof, and flow testing. All precombustor internal components (combustion can baffle and swirl box) were received and checked, and integration of the components was initiated. A decision was made regarding the primary and backup designs for the 1A4 channel. The assembly of the channel related prototypical hardware continued. The cathode wall electrical wiring is now complete. The mechanical design of the diffuser has been completed.

  18. Project LIFE--Language Improvement to Facilitate Education. (Technical Progress Report; Third Quarter; March 1, 1974-May 31, 1974).

    ERIC Educational Resources Information Center

    National Foundation for the Improvement of Education, Washington, DC.

    Reported is the third quarter, fiscal year 1974 (March 1, 1974-May 31, 1974) technical progress of Project LIFE (Language Improvement to Facilitate Education), toward developing an instructional system in which filmstrips in the areas of perceptual training, perceptual thinking, and language/reading are used to assist hearing impaired children in…

  19. Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect

    Li, W.B.; Yang, R.T.

    1995-12-01

    During this quarter, progress was made on the following tasks: TPD techniques were employed to study the reaction mechanism of the selective catalytic reduction of nitrogen oxide with ammonia over iron oxide pillared clay catalyst; and a sulfur dioxide resistant iron oxide/titanium oxide catalyst was developed.

  20. The Structure and Dynamics of the Solar Corona and Inner Heliosphere-First Quarter First Year Progress Report

    NASA Technical Reports Server (NTRS)

    Mikic, Zoran; Grebowsky, J. (Technical Monitor)

    2000-01-01

    This report details progress during the first quarter of the first year of our Sun-Earth Connections Theory Program (SECTP) contract. Science Applications International Corporation (SAIC) and the University of California, Irvine (UCI) have conducted research into theoretical modeling of active regions, the solar corona, and the inner heliosphere, using the MHD model.

  1. Develop apparatus and process for second-stage drying. Quarterly progress report, September 26--December 26, 1994

    SciTech Connect

    Taylor, F.

    1995-01-05

    Progress is reported on Task 1, Computer simulation refinement and extension, and its two subtasks: Verification of computer model simulation of the drying process for lumber in a superheated kiln and Establishment of energy loss predictions for specific kiln designs for the first stage kiln. A report of a trip to the Irvington Moore Corporation facility and plans for next quarter are described.

  2. Hazardous materials in aquatic environments of the Mississippi River Basin. Quarterly progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    1995-12-01

    This report is the quarterly progress report for July through September 1995 for work done by Tulane and Xavier Universities under DOE contract number DE-FG01-93-EW53023. Accomplishments for various tasks including administrative activities, collaborative cluster projects, education projects, initiation projects, coordinated instrumentation facility, and an investigators` retreat are detailed in the report.

  3. The Amarillo National Resource Center for Plutonium. Quarterly progress detailed report, 1 November 1996--31 January 1997

    SciTech Connect

    1997-03-01

    Progress for this quarter is given for each of the following Center programs: (1) plutonium information resource; (2) advisory function (DOE and state support); (3) environmental, public health and safety; (3) communication, education, and training; and (4) nuclear and other material studies. Both summaries of the activities and detailed reports are included.

  4. Evaluation of geothermal energy in Arizona. Quarterly topical progress report, January 1, 1980-March 31, 1981

    SciTech Connect

    White, D.H.; Goldstone, L.A.; Malysa, L.

    1981-03-31

    The tasks, objectives and completed work are discussed for the legislative and institutional program, cities program, geothermal applications utilization technology, and outreach. The work on the Maryvale Terrace development and the New Mexico Energy Institute are described. (MHR)

  5. Evaluation of geothermal energy in Arizona. Quarterly topical progress report, April 1, 1981-June 30, 1981

    SciTech Connect

    White, D.H.

    1981-01-01

    Activities included the identification and delineation of geothermal prospects, the comparison of conventional energy use patterns with geothermal sources, the preparation of area development plans and the compilation of detailed economic and energy data for each area. Current emphasis is on commercialization. (MHR)

  6. Lawrence Livermore National Laboratory Safeguards and Security quarterly progress report to the US Department of Energy: Quarter ending December 31, 1993

    SciTech Connect

    Davis, G.; Mansur, D.L.; Ruhter, W.D.; Steele, E.; Strait, R.S.

    1994-01-01

    The Lawrence Livermore National Laboratory (LLNL) carries out safeguards and security activities for the Department of Energy (DOE), Office of Safeguards and Security (OSS), as well as other organizations, both within and outside the DOE. This document summarizes the activities conducted for the OSS during the first quarter of fiscal year 1994 (October through December, 1993). The nature and scope of the activities carried out for OSS at LLNL require a broad base of technical expertise. To assure projects are staffed and executed effectively, projects are conducted by the organization at LLNL best able to supply the needed technical expertise. These projects are developed and managed by senior program managers. Institutional oversight and coordination is provided through the LLNL Deputy Director`s office. At present, the Laboratory is supporting OSS in five areas: (1) Safeguards Technology, (2) Safeguards and Decision Support, (3) Computer Security, (4) DOE Automated Physical Security, and (5) DOE Automated Visitor Access Control System. This report describes the activities in each of these five areas. The information provided includes an introduction which briefly describes the activity, summary of major accomplishments, task descriptions with quarterly progress, summaries of milestones and deliverables and publications published this quarter.

  7. Lawrence Livermore National Laboratory safeguards and security quarterly progress report to the U.S. Department of Energy. Quarter ending December 31, 1996

    SciTech Connect

    Davis, G.; Mansur, D.L.; Ruhter, W.D.; Strauch, M.S.

    1997-01-01

    The Lawrence Livermore National Laboratory (LLNL) carries out safeguards and security activities for the Department of Energy (DOE), Office of Safeguards and Security (OSS), as well as other organizations, both within and outside the DOE. This document summarizes the activities conducted for the OSS during the First Quarter of Fiscal Year 1997 (October through December, 1996). The nature and scope of the activities carried out for OSS at LLNL require a broad base of technical expertise. To assure projects are staffed and executed effectively, projects are conducted by the organization at LLNL best able to supply the needed technical expertise. These projects are developed and managed by senior program managers. Institutional oversight and coordination is provided through the LLNL Deputy Director`s office. At present, the Laboratory is supporting OSS in four areas: (1) safeguards technology; (2) safeguards and material accountability; (3) computer security--distributed systems; and (4) physical and personnel security support. The remainder of this report describes the activities in each of these four areas. The information provided includes an introduction which briefly describes the activity, summary of major accomplishments, task descriptions with quarterly progress, summaries of milestones and deliverables and publications published this quarter.

  8. Lawrence Livermore National Laboratory safeguards and security quarterly progress report to the US Department of Energy: Quarter ending September 30, 1993

    SciTech Connect

    Ruhter, W.D.; Strait, R.S.; Mansur, D.L.; Davis, G.

    1993-10-01

    The Lawrence Livermore National Laboratory (LLNL) carries out safeguards and security activities for the Department of Energy (DOE), Office of Safeguards and Security (OSS), as well as other organizations, both within and outside the DOE. This document summarizes the activities conducted for the OSS during the fourth quarter of Fiscal Year 1993 (July through September, 1993). The nature and scope of the activities carried out for OSS at LLNL require a broad base of technical expertise. To assure projects are staffed and executed effectively, projects are conducted by the organization at LLNL best able to supply the needed technical expertise. These projects are developed and managed by senior program managers. Institutional oversight and coordination is provided through the LLNL Deputy Director`s office. At present, the Laboratory is supporting OSS in five areas: Safeguards Technology, Safeguard System Studies, Computer Security, DOE Automated Physical Security and DOE Automated Visitor Access Control System. The remainder of this report describes the activities in each of these five areas. The information provided includes an introduction which briefly describes the activity, summary of major accomplishments, task descriptions with quarterly progress, summaries of milestones and deliverables and publications published this quarter.

  9. Hanford Federal Facility Agreement and Consent Order quarterly progress report for the period ending June 30, 1991

    SciTech Connect

    Not Available

    1991-08-01

    This is the ninth quarterly report as required by the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1990), also known as the Tri-Party Agreement, established between the US Department of Energy (DOE), the US Environmental Protection Agency (EPA), and the Washington State Department of Ecology (Ecology). The Tri-Party Agreement sets the plan and schedule for achieving regulatory compliance and cleanup of waste sites at the Hanford Site. This report covers progress for the quarter that ended June 30, 1991. A total of 87 milestones have been completed to date. 39 refs., 1 fig.

  10. Methyl chloride via oxyhydrochlorination of methane. Quarterly technical progress report No. 13, October--December 1994

    SciTech Connect

    1995-02-01

    The purpose of this contract is to develop a process for converting light alkane gases to methyl chloride via oxyhydrochlorination using highly selective, stable catalysts in fixed-bed reactors designed to remove the large amount of heat generated, so as to control the reaction temperature. Further, the objective is to obtain the engineering data base necessary for developing a commercially feasible process and to evaluate t economics of the process. Significant progress was made in six different technical areas during this quarter. These key highlights are: (1) Evaluation of catalyst samples from UCI led to the ordering of the OHC PDU catalyst batch. This catalyst batch arrived, was screened and found to be defective, and was reordered. (2) Natural gas containing higher hydrocarbons was used as a methane source. The reactant mixture formed oxygenates at temperatures lower than observed in the past. Burning at such low temperatures seems to create a product stream containing very little CH{sub 2}Cl{sub 2}. (3) Although it has not been decided if the PDU will use natural gas from the plant or methane or natural gas from cylinders as a methane feed source, it was concluded that an adsorption unit to remove sulfur and higher hydrocarbons is not necessary at this time. (4) PDU construction was completed in December. The bulk of insulation work was completed at the end of November. Much effort has been put into pressure testing the PDU`s systems. The startup team has become adept at finding and correcting such leaks. (5) SOP writing for the PDU was completed this quarter with communication with the software programmer to insure agreement between the software and SOP.

  11. Power systems development facility. Quarterly technical progress report, July 1--September 30, 1993

    SciTech Connect

    Not Available

    1993-12-31

    This quarterly technical progress report summarizes work completed during the Second Quarter of the Second Budget Period, July 1 through September 30, 1993, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scaleup of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the existing Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/Pressurized Circulating Fluidized Bed Gas Source. Hot Gas Cleanup Units to mate to all gas streams; Combustion Gas Turbine; and Fuel Cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during this reporting period was continuing the detailed design of the facility.

  12. MHD Integrated Topping Cycle Project. Fourteenth quarterly technical progress report, November 1, 1990-- January 31, 1991

    SciTech Connect

    Not Available

    1992-02-01

    This fourteenth quarterly technical progress report of the MHD Integrated Topping Cycle Project presents the accomplishments during the period November 1, 1990 to January 31, 1991. Testing of the High Pressure Cooling Subsystem electrical isolator was completed. The PEEK material successfully passed the high temperature, high pressure duration tests (50 hours). The Combustion Subsystem drawings were CADAM released. The procurement process is in progress. An equipment specification and RFP were prepared for the new Low Pressure Cooling System (LPCS) and released for quotation. Work has been conducted on confirmation tests leading to final gas-side designs and studies to assist in channel fabrication.The final cathode gas-side design and the proposed gas-side designs of the anode and sidewall are presented. Anode confirmation tests and related analyses of anode wear mechanisms used in the selection of the proposed anode design are presented. Sidewall confirmation tests, which were used to select the proposed gas-side design, were conducted. The design for the full scale CDIF system was completed. A test program was initiated to investigate the practicality of using Avco current controls for current consolidation in the power takeoff (PTO) regions and to determine the cause of past current consolidation failures. Another important activity was the installation of 1A4-style coupons in the 1A1 channel. A description of the coupons and their location with 1A1 channel is presented herein.

  13. Fundamental mechanisms in flue gas conditioning. Quarterly technical progress report, April 1995--June 1995

    SciTech Connect

    Snyder, T.R.; Bush, P.V.

    1995-07-11

    This project is divided into four tasks. We developed our Management Plan in Task 1. Task 2, Evaluation of Mechanisms in FGD Sorbent and Ash Interactions, focused on characteristics of binary mixtures of these distinct powders. Task 3, Evaluation of Mechanisms in Conditioning Agents and Ash, was designed to examine effects of various conditioning agents on fine ash particles to determine mechanisms by which these agents alter physical properties of ash. We began Tasks 2 and 3 with an extensive literature search and assembly of existing theories. We completed this phase of the project with publication of two special Topical Reports. In our literature reviews reported in Topical Reports 1 and 2, we emphasized the roles adsorbed water can have in controlling bulk properties of powders. During the next phase of the project we analyzed a variety of fly ashes and fine powders in the laboratory. The experiments we performed were primarily designed to define the extent to which water affects key properties of ashes, powders, and mixtures of sorbents and ashes. We have recently completed a series of pilot-scale tests designed to determine the effects that adsorbed water has on fabric filtration and electrostatic precipitation of entrained fly ash particles in actual flue gas environments. Under Task 4 we will issue our Final Report that will summarize the results of our laboratory and pilot-scale work and will also include a model of flue gas conditioning. Our efforts during this reporting quarter have been directed toward production of the Draft Final Report and the Flue Gas Conditioning Model. In addition to these efforts, we have prepared a paper for presentation at the Eleventh Annual Coal Preparation, Utilization, and Environmental Control Contractor`s Conference to be held in Pittsburgh in July, 1995.

  14. Great Plains Coal Gasification Project: Quarterly technical progress report, April-June 1988 (Fourth fiscal quarter, 1987-1988)

    SciTech Connect

    Not Available

    1988-07-29

    This progress report describes the operation of the Great Plains Gasification Plant, including lignite coal production, SNG production, gas quality, by-products, and certain problems encountered. (LTN)

  15. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, October 1--December 31, 1992

    SciTech Connect

    Brandes, S.D.; Winschel, R.A.; Burke, F.P.; Robbins, G.A.

    1993-10-01

    The Research and Development Department of CONSOL Inc. is conducted a program to characterize process and product streams from direct coal liquefaction process development projects sponsored by the Department of Energy. In this program, CONSOL obtains samples from current process development activities in coal liquefaction and coal-oil coprocessing, and characterizes them using established analytical techniques. In addition, selected samples are characterized by other analytical techniques to evaluate their potential for aiding process development. These analyses and interpretation of the results in relation to process operations are provided by the subcontractor. Major topics reported in this thirteenth quarterly report are the following: (1) Analyses were performed on three coals and eleven process oils from HRI, Inc. process development unit Run 260--03, which was the first process development unit test of Black Thunder Mine subbituminous coal, significant operating problems were encountered, and sample properties are discussed in context to the operational problems; (2) a summary of the status of the Participants Program is given; (3) summaries of the final reports produced by the University of Chicago, the University of Utah, Iowa State University, and the University of Kentucky under the Participants Program, are presented.

  16. AGEX II: Technical quarterly, Volume 2

    SciTech Connect

    Ekdahl, C.

    1995-03-01

    The AGEX II Technical Quarterly publishes short technical contributions on above ground experiments that use pulsed power and laser drivers. The Quarterly is intended to provide rapid exposure of timely technical ideas and results as well as a means for documenting AGEX II progress and scientific quality for the AGEX II community. Suitable topics include experimental results, diagnostic apparatus, theoretical design, and scaling, among others.

  17. EDS coal liquefaction process development: Phase V. Quarterly technical progress report, January 1-March 31, 1984

    SciTech Connect

    1984-07-01

    This report is the twenty-first Quarterly Technical Progress Report for US Department of Energy Cooperative Agreement No. DE-FC05-77ET10069 for EDS Coal Liquefaction Process Development Phase V. A detailed comparison of RCLU, CLPP, and ECLP yields has been initiated. This study builds off previous yield modeling results, which found that RCLU, CLPP, and ECLP yields were generally consistent given the scatter of the data, although some differences were noted. These pilot unit yield differences have now been quantified, and operating/configurational differences which account for some of them have been identified. Preliminary yield comparison results after correcting for these known process differences between the pilot plants indicate that: RCLU and CLPP yields are generally consistent; ECLP's conversion is about 5 lb/100 lb DAF coal lower than RCLU/CLPP at comparable operating conditions; and work has been initiated to define the EDS slurry preheater feed system design (based on slurry distributor manifold guidelines and coking correlation predictions, which influence furnace pass control issues such as slurry flow measurement). EDS hydrotreated naphtha showed a low level of systemic toxicity to rats exposed to the vapor six hours per day, five days per week for thirteen weeks.

  18. MHD Integrated Topping Cycle Project. Sixteenth quarterly technical progress report, May 1991--July 1991

    SciTech Connect

    Not Available

    1992-03-01

    The Magnetohydrodynamics (MHD) Integrated Topping Cycle (ITC) Project represents the culmination of the proof-of-concept (POC) development stage in the US Department of Energy (DOE) program to advance MHD technology to early commercial development stage utility power applications. The project is a joint effort, combining the skills of three topping cycle component developers: TRW, Avco/TDS, and Westinghouse. TRW, the prime contractor and system integrator, is responsible for the 50 thermal megawatt (50 MW{sub t}) slagging coal combustion subsystem. Avco/TDS is responsible for the MHD channel subsystem (nozzle, channel, diffuser, and power conditioning circuits), and Westinghouse is responsible for the current consolidation subsystem. The ITC Project will advance the state-of-the-art in MHD power systems with the design, construction, and integrated testing of 50 MW{sub t} power train components which are prototypical of the equipment that will be used in an early commercial scale MHD utility retrofit. Long duration testing of the integrated power train at the Component Development and Integration Facility (CDIF) in Butte, Montana will be performed, so that by the early 1990`s, an engineering data base on the reliability, availability, maintainability and performance of the system will be available to allow scaleup of the prototypical designs to the next development level. This Sixteenth Quarterly Technical Progress Report covers the period May 1, 1991 to July 31, 1991.

  19. Heterogeneous kinetics of coal gasification. Quarterly technical progress report, 1 April 1983-30 June 1983

    SciTech Connect

    Calo, J.M.; Ganapathi, R.

    1983-01-01

    In the current quarterly technical progress report we present data and results on transient kinetic studies of the steam-char reaction system for activated coconut and lignite chars. These experiments were conducted in a fashion similar to the previous char-CO/sub 2/ studies, under approximately the same experimental conditions. The two principal product species, H/sub 2/ and CO, were monitored using the automatic mass programming system developed especially for this project. In order to perform the steam-char experiments, the original apparatus was modified by the addition of a steam generation/condensate removal system. The steam-char reaction system, being somewhat more complex than the CO/sub 2/-char reaction system, was modeled with a six-parameter, elementary kinetic scheme. The ''effective'' active site concentrations determined from the steam gasification data were of the same order of magnitude, and behaved in a similar fashion, to those obtained for the CO/sub 2/ gasification studies. The implications of this result are briefly discussed. 21 refs., 23 figs., 2 tabs.

  20. Pipeline gas demonstration plant, Phase I. Quarterly technical progress report for June 1980-August 1980

    SciTech Connect

    Eby, R.J.

    1980-09-01

    Work was performed in the following tasks in Phase I of the Pipeline Gas Demonstration Plant Program: Demonstration Plant Process Design; Site Evaluation and Selection; Demonstration Plant Environmental Analysis; Feedstock Plans, Licenses, Permits and Easements; Demonstration Plant Definitive Design; Economic Reassessment; Technical Support; Long Lead Procurement List; and Project Management. The following Major Contract Deliverables were submitted to the Government: Process Evaluation Report - TIC Version; Conceptual Commercial Plant Design Report - TIC Version; Demonstration Plant Design Analysis Report - TIC Version; Demonstration Plant Process Design Report; Site Master Plan; and Prevention of Significant Deterioration Documentation. The major work activity has been the effort in Demonstration Plant Definitive Design which commenced following the completion of the Process Design Baseline Packages for the fourteen Demonstration Plant process areas. Task VIII, Economic Reassessment was opened in this quarter. Completion of the TIC copies of the ICGG major deliverables constituted a significant effort in this period. Work has progressed satisfactorily in the other Tasks in support of the Demonstration Plant Program.

  1. Development of the integrated environmental control model. Quarterly progress report, April 1995--June 1995

    SciTech Connect

    Kalagnanam, J.R.; Rubin, E.S.

    1995-06-01

    The purpose of this contract is to develop and refine the Integrated Environmental Control Model (IECM). In its current configuration, the IECM provides a capability to model various conventional and advanced processes for controlling air pollutant emissions from coal-fired power plants before, during, or after combustion. The principal purpose of the model is to calculate the performance, emissions, and cost of power plant configurations employing alternative environmental control methods. The model consists of various control technology modules, which may be integrated into a complete utility plant in any desired combination. In contrast to conventional deterministic models, the IECM offers the unique capability to assign probabilistic values to all model input parameters, and to obtain probabilistic outputs in the form of cumulative distribution functions indicating the likelihood of different costs and performance results. The work in this contract is divided into two phases. Phase I deals with further developing the existing version of the IECM and training PETC personnel on the effective use of the model. Phase H deals with creating new technology modules, linking the IECM with PETC databases, and training PETC personnel on the effective use of the updated model. The present report summarizes recent progress on the Phase I effort during the period April 1, 1995 through June 30, 1995. This report presents additional revisions to the new cost models of flue gas desulfurization (FGD) technology initially reported in our fourth quarterly report. For convenience, the complete description of the revised FGD models are presented here.

  2. TIDD PFBC Demonstration Project: Third quarterly technical progress report 1992, CY 1992

    SciTech Connect

    Not Available

    1992-10-01

    This is the 22nd Technical Progress Report submitted to the Department of Energy in connection with the Cooperative Agreement between the DOE and the Ohio Power Company for the Tidd PFBC Demonstration Plant. This report covers the period from July 1, 1992 to September 30, 1992. The unit was operated for a total of 903 hours (including gas turbine air prewarming). There were 9 gas turbine starts, 11 preheating starts, and 8 operating periods with coal fire. The peak gross output of 59 MWH was achieved for the period of 1600 to 1700 hours on September 23, 1992. The longest coal fire was 422 hourb beginning at 1349 hours on August 9, 1992. Total gross generation was 32,418 MWH, and coal consumption was 15,846 tons. Testing was completed on the gas turbine blade resonance frequency problem. The report showed that a resonant frequency problem existing at high LPT speeds and at a mostly closed guide vane position. An operating curve was developed by ABBC to avoid the points of blade resonance. Monitoring of solid, liquid and gaseous waste streams, as detailed in the operations phase monitoring requirements in the EMP, were performed throughout the quarter.

  3. PFBC HGCU Test Facility. Second quarterly technical progress report, CY 1993

    SciTech Connect

    Not Available

    1993-07-01

    This is the fifteenth Technical Progress Report submitted to the Department of Energy (DOE) in connection with the cooperative agreement between the DOE and Ohio Power Company for the Tidd Pressurized Fluidized Bed Combustion (PFBC) Hot Gas Clean Up Test Facility. This report covers the period of work completed during the Second Quarter of CY 1993.Work accomplished during the reporting period includes: the expansion joint heaters and control system were installed and tested. The system consists of 8 bellows heaters and 14 heaters on the adjacent piping. During initial testing, 11 of the 14 pipe and heaters failed due to overheating caused by control and installation problems; A pneumatically powered vibrator was installed in the APF manway nozzle to vibrate the hopper liner during back pulsing. This should eliminate any build-up on the pipes of the hopper; Two half capacity diesel driven back-up pulse air compressors were rented and installed; Installation of an emergency ash removal system was completed. The system enables ash to be removed via a line connected to the pipe between the outlet of the screw cooler and the inlet of the lockhopper system; Installation of the spoiling air line, valves, and metering orifice to the primary cyclone was completed; Numerous revisions were made to the Net 90 instrumentation and control system and the POPS data trending system to enhance system control and performance monitoring capability.

  4. EDS coal liquefaction process development. Phase V. Quarterly technical progress report, July 1-September 30, 1980

    SciTech Connect

    1981-02-01

    This report is the tenth Quarterly Technical Progress Report for US Department of Energy Cooperative Agreement No. DE-FC01-77ET10069 (formerly EF-77-A-01-2893) for Exxon Donor Solvent (EDS) Coal Liquefaction Process Development - Phase V. The Laboratory Process Research and Development studies were conducted at various Exxon Research and Engineering Co. (ER and E) facilities: Research and Development Division at Baytown, Texas; Products Research Division at Linden, New Jersey; and the Exxon Research and Development Laboratories at Baton Rouge, Louisiana. The Engineering Research and Development studies were performed at the Synthetic Fuels Engineering and Exxon Engineering Technology Departments of ER and E at Florham Park, New Jersey. The information dealing with the Management, Detailed Engineering, and Procurement activities related to revamp of the FLEXICOKING Prototype Unit was generated at Exxon Company, USA, Houston, Texas, and Exxon Engineering - Project Management Department of ER and E, Florham Park, New Jersey. The information dealing with operation of the 250 T/D Exxon Coal Liquefaction Pilot Plant (ECLP) was generated at Exxon Company, USA, Houston, Texas.

  5. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, January 1--March 31, 1992

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-08-01

    This is the tenth Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Process oils from Wilsonville Run 262 were analyzed to provide information on process performance. Run 262 was operated from July 10 through September 30, 1991, in the thermal/catalytic Close-Coupled Integrated Two-Stage Liquefaction (CC-ITSL) configuration with ash recycle. The feed coal was Black Thunder Mine subbituminous coal. The high/low temperature sequence was used. Each reactor was operated at 50% of the available reactor volume. The interstage separator was in use throughout the run. The second-stage reactor was charged with aged Criterion 324 catalyst (Ni/Mo on 1/16 inch alumina extrudate support). Slurry catalysts and sulfiding agent were fed to the first-stage reactor. Molyvan L is an organometallic compound which contains 8.1% Mo, and is commercially available as an oil-soluble lubricant additive. It was used in Run 262 as a dispersed hydrogenation catalyst precursor, primarily to alleviate deposition problems which plagued past runs with Black Thunder coal. One test was made with little supported catalyst in the second stage. The role of phenolic groups in donor solvent properties was examined. In this study, four samples from direct liquefaction process oils were subjected to O-methylation of the phenolic groups, followed by chemical analysis and solvent quality testing.

  6. Solvent Refined Coal (SRC) process. Quarterly technical progress report, April 1979-June 1979

    SciTech Connect

    Not Available

    1980-02-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) Project for the period March 25, 1979, through June 24, 1979. SRC-I turnaround activities at the Fort Lewis Pilot Plant and several other problems delayed successful startup until April 11. Slurry was injected to the Lummus Deashing Unit for the first time April 12. After approximately eight days, slurry feed was diverted because of indications that solids were accumulating in the settler vessel. The Fort Lewis Pilot Plant was shut down from April 28 to May 12, 1979, while the Lummus Unit settler vessel was hydroblasted. Cleaning of the settler vessel was complete May 10. Modifications to the unit were nearly complete at the end of the reporting period. Slurry feed to the Lummus Unit was reestablished June 15. To date, continuous production of specification product at design rates has not been achieved. One material balance run, MBR 79-1, was completed using Kentucky No. 9/14 coal at proposed design conditions for the SRC-I Demonstration Plant. Process Development Unit P-99 was on-stream for all of the second quarter of 1979, with the exception of a two-week scheduled turn-around. Six different run conditions were tested feeding Pittsburgh Seam coal from the Powhatan No. 5 Mine.

  7. Gypsy Field Project in reservoir characterization. [Quarterly progress report], January 1--March 31, 1995

    SciTech Connect

    O`Meara, D.J. Jr.

    1995-05-18

    The overall objective of this project is to use the extensive Gypsy Field laboratory and data set as a focus for developing and testing reservoir characterization methods that are targeted at improved recovery of conventional oil. The Gypsy Field laboratory consists of coupled outcrop and subsurface sites which have been characterized to a degree of detail not possible in a production operation. Data from these sites entail geological descriptions, core measurements, well logs, vertical seismic surveys, a 3D seismic survey, crosswell seismic surveys, and pressure transient well tests. The overall project consists of four interdisciplinary sub-projects which are closely interlinked: Modeling depositional environments; sweep efficiency; tracer testing; and integrated 3D seismic interpretation. The first of these aims at improving out ability to model complex depositional environments which trap movable oil. The second is a development geophysics project which proposes to improve the quality of reservoir geological models through better use of 3D seismic data. The third investigates the usefulness of a new numerial technique for identifying unswept oil through rapid calculation of sweep efficiency in large reservoir models. The fourth explores what can be learned from tracer tests in complex depositional environments, particularly those which are fluvial dominated. During this quarter, the main activities involved the ``Tracer Testing`` and ``Sweep Efficiency`` Projects``, for which the progress is reported.

  8. Advancement of flash hydrogasification. Quarterly technical progress report, January-March 1984

    SciTech Connect

    Falk, A.Y.

    1984-06-25

    This first quarterly report documents technical progress during the period 31 December 1983 through 30 March 1984. The technical effort is 17 months in duration and is divided into two major technical tasks: Task VII, Hardware Fabrication and PDU Modifications, and Task VIII, Performance Testing. The design of test hardware and process development unit modifications had been previously completed as part of Task VI of the current contract. Task VII involves the fabrication of test hardware and modification of an existing 1-ton/h hydroliquefaction PDU at Rockwell's facilities for use as a hydrogasifier test facility. During this report period, fabrication of the test hardware and modifications to the PDU were initiated. Test hardware fabrication is now approximately 80% complete and should be completed by the end of May 1984. PDU modifications are progressing well and should be completed by the end of June 1984. The completed test hardware fabrication and PDU modifications will allow the conduct of short duration (1 to 2 h) hydrogasification tests along with preburner assembly performance evaluation tests in order to fulfill the test program objectives. Separate supplies of hydrogen, oxygen, methane, carbon monoxide, and water (for steam generation) are provided for this purpose. The modified facility is designed to accommodate both 10- and 20-ft-long hydrogasifier reactors so that residence times will be in the range of 2 to 6 s when coal is fed at a nominal 1/2 ton/h into reactors at 1000 psia pressure. Provisions are being made for real-time analysis of the product gases using an on-line gas chromatograph system. Test planning was the only Task VIII effort active during this report period. An initial (preliminary) test matrix has been defined. Preparation of a data analysis plan is underway, and data reduction programs are being programmed. 17 references, 25 figures, 6 tables.

  9. Advanced alternate planar geometry solid oxide fuel cells. Interim quarterly technical progress report, November 1, 1988--January 31, 1989

    SciTech Connect

    Prouse, D.; Elangovan, S.; Khandkar, A.; Donelson, R.; Marianowski, L.

    1989-12-31

    During this quarter, progress was made at Ceramatec in seal development and conductivity measurements of YIG compositions. A creep test was completed on the porous/dense/porous triilayer. IGT provided a discussion on possible interconnect materials. The following tasks are reported on: cell design analysis, program liaison and test facility preparation, cell component fabrication/development, out-of-cell tests. 9 figs, 2 tabs.

  10. Effects of surface chemistry on the porous structure of coal. Quarterly technical progress report, April 1996--June 1996

    SciTech Connect

    Anderson, S.A.; Radovic, L.R.; Hatcher, P.G.

    1996-11-01

    Objective is to use {sup 129}Xe NMR to study the microporous structure of coals. During this quarter, we have: performed a presaturation experiment on Wyodak subbituminous coal, monitored the progress of Xe adsorption in an anthracite, focusing on the changes observed in the external-surface adsorbed gas signal, used an echo sequence to obtain {sup 129}Xe NMR spectra of Blind Canyon hvAb coal, and improved and repeated the successive oxygen adsorption and desorption experiment on a microporous carbon.

  11. BX in situ oil shale project. Quarterly technical progress report, September 1-November 30, 1981

    SciTech Connect

    Dougan, P.M.

    1981-12-20

    September 1, 1981-November 30, 1981, was the fourth consecutive quarter of superheated steam injection at the BX In Situ Oil Shale Project. During the quarter, 117,520 barrels of water as steam were injected into project injection wells at an average wellhead temperature of 715/sup 0/F and an average wellhead pressure of 1378 PSIG. During the same period, 148,516 barrels of fluid were produced from the project production wells for a produced-to-injected fluid ratio of 1.26 to 1.0. Net oil production for the quarter was 169 barrels.

  12. Methyl chloride via oxyhydrochlorination of methane. Quarterly technical progress report No. 7, April--June 1993

    SciTech Connect

    Not Available

    1994-01-01

    The purpose of this contract is to develop a process for converting light alkane gases to methyl chloride via oxyhydrochlorination using highly selective, stable catalysts in fixed-bed reactors designed to remove the large amount of heat generated, so as to control the reaction temperature. Further, the objective is to obtain the engineering data base necessary for developing a commercially feasible process and to evaluate the economics of the process. Several key technology areas were evaluated this quarter. The catalyst definition effort focused on the determination of the role of the Li and La promoters that have been found to be useful in enhancing Cu based oxyhydrochlorination of methane catalysts. Initial experiments show that the La acts to provide a much more active catalyst than the Cu only case. The role of the Li is ambiguous at this point. The Li enhances the stability of the La promoted catalyst, but gives only marginal improvement by itself This work will be continued, with additional emphasis on the analysis of the catalysts to determine the structural role that the promoters may play. The separation unit operation definition made significant progress by demonstrating in a laboratory system that a process solvent may be used to remove the product CH{sub 3}Cl from the reactor effluent stream. To date the data has been qualitative, but clear. Work will continue to gather the information possible in the laboratory to help with PDU design. An extensive amount of testing was performed on the chosen process solvent, Multitherm. A comprehensive review of all the thermal testing and associated FTIR, UV/VIS, and physical property testing is included in this report. This work shows that Multitherm should give the desired stability and solubility that are necessary to make the separation unit operation successful.

  13. Solvent refined coal (SRC) process. Quarterly technical progress report, January 1980-March 1980. [In process streams

    SciTech Connect

    Not Available

    1981-01-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) project at the SRC Pilot Plant in Fort Lewis, Wahsington, and the Process Development Unit (P-99) in Harmarville, Pennsylvania. After the remaining runs of the slurry preheater survey test program were completed January 14, the Fort Lewis Pilot Plant was shut down to inspect Slurry Preheater B and to insulate the coil for future testing at higher rates of heat flux. Radiographic inspection of the coil showed that the welds at the pressure taps and the immersion thermowells did not meet design specifications. Slurry Preheater A was used during the first 12 days of February while weld repairs and modifications to Slurry Preheater B were completed. Two attempts to complete a material balance run on Powhatan No. 6 Mine coal were attempted but neither was successful. Slurry Preheater B was in service the remainder of the quarter. The start of a series of runs at higher heat flux was delayed because of plugging in both the slurry and the hydrogen flow metering systems. Three baseline runs and three slurry runs of the high heat flux program were completed before the plant was shut down March 12 for repair of the Inert Gas Unit. Attempts to complete a fourth slurry run at high heat flux were unsuccessful because of problems with the coal feed handling and the vortex mix systems. Process Development Unit (P-99) completed three of the four runs designed to study the effect of dissolver L/D ratio. The fourth was under way at the end of the period. SRC yield correlations have been developed that include coal properties as independent variables. A preliminary ranking of coals according to their reactivity in PDU P-99 has been made. Techniques for studying coking phenomenona are now in place.

  14. PFBC HGCU Test Facility. Fourth quarterly technical progress report, [October--December 1993

    SciTech Connect

    Not Available

    1994-01-01

    The APF was shut down on September 23, 1993 and no operation was performed during this quarter. This report summarizes inspection, candle reinstallation, retrofit and accelerometer testing conducted during this three month outage.

  15. Fischer Tropsch synthesis in supercritical fluids. Quarterly technical progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Akgerman, A.; Bukur, D.B.

    1996-05-01

    Our objective for this quarter was to compare performance of the Ruhrchemie catalyst in different modes of operation: fixed bed reactor (conventional and supercritical mode of operation), and stirred tank slurry reactor. Diffusion coefficients are discussed.

  16. Synthesis of acrylates. Quarterly progress report, April 1, 1995--June 30, 1995

    SciTech Connect

    1995-09-05

    The objective of this research is to develop a condensation/oxidation route for the synthesis of acrylates/methacrylates from coal-derived synthesis gas. This quarter work continued on the development of catalysts for propionate synthesis.

  17. Lawrence Livermore National Laboratory safeguards and security quarterly progress report to the US Department of Energy. Quarterly report

    SciTech Connect

    Davis, G.; Mansur, D.L.; Ruhter, W.D.; Steele, E.; Strait, R.S.

    1994-04-01

    The Safeguards Technology Program (STP) is a program in LLNL`s Nuclear Chemistry Division that develops advanced, nondestructive-analysis (NDA) technology for measurement of special nuclear materials. Our work focuses on R&D relating to x- and gamma-ray spectrometry techniques and to the development of computer codes for interpreting the spectral data obtained by these techniques. A review of the Safeguards Technology Program at LLNL by representatives of the Department of Energy Office of Safeguards and Security and Office of Research was conducted via teleconference on March 4, 1994. Objectives, milestones, and recent accomplishments were presented for each of the four LLNL tasks in NDA, and plans to address user needs in these NDA areas were discussed. An informal presentation on the LLNL Safeguards Technology Program was presented to the JOWOG-30 meeting at the Los Alamos National Laboratory on March 10, 1994. The JOWOG meetings bring together representatives from Laboratories in the DOE complex, as well as their counterparts from the United Kingdom. Within JOWOG-30 a variety of topics are discussed, including NDA and its various applications within the U.S. and U.K. complexes.

  18. Investigation of mineral transformations and ash deposition during staged combustion. Quarterly technical progress report, January 1, 1996--March 31, 1996

    SciTech Connect

    Harb, J.N.

    1996-05-01

    Progress during the tenth quarter of a three-year study of ash formation and deposition was made in several areas. One of the key contributions this quarter was the development of an algorithm to distinguish between ash particles that are associated with char particles (included) and ash particles which are excluded. This algorithm was used to determine the extent to which pyrite transformations are influenced by whether the pyrite grains are included or excluded. The results indicate that pyrite oxidation is slower for included pyrite grains. Replicate experiments were also performed for the Pittsburgh No. 8 coal (washed) under both staged and conventional conditions. An objective of these experiments was to validate the effect of staged combustion on the size distribution of ash particles as reported for the previous quarter. Analysis of the new samples and repeat analyses of previous samples showed no significant difference in the ash particle size for samples collected at stoichiometric ratios of 0.75 (before the stage) and 1.04. The number of points in the new analyses was considerably higher than in previous analyses, resulting in greater confidence. The similarity in the ash composition for samples collected under staged and conventional conditions was also verified this quarter with replicate samples and analyses. The net result is that staged combustion does not appear to have a significant impact on either ash size or composition for the Pittsburgh No. 8 coal. Finally, numerical simulations of the temperature distribution in the laboratory combustor were performed and evaluated. Also, a paper documenting the classification algorithm developed last quarter was presented at the March ACS meeting in New Orleans and published in the ACS Division of Fuel Chemistry Preprints.

  19. Topically Applied Metal Chelator Reduces Thermal Injury Progression in a Rat Model of Brass Comb Burn

    PubMed Central

    Wang, Cheng Z.; El Ayadi, Amina; Goswamy, Juhi; Finnerty, Celeste C.; Mifflin, Randy; Sousse, Linda; Enkhbaatar, Perenlei; Papaconstantinou, John; Herndon, David N.; Ansari, Naseem H.

    2016-01-01

    Oxidative stress may be involved in the cellular damage and tissue destruction as burn wounds continues to progress after abatement of the initial insult. Since iron and calcium ions play key roles in oxidative stress, this study tested whether topical application of Livionex formulation (LF) lotion, that contains disodium EDTA as a metal chelator and methyl sulfonyl methane (MSM) as a permeability enhancer, would prevent or reduce burn injury. Methods We used an established brass comb burn model with some modifications. Topical application of LF lotion was started 5 minutes post-burn, and repeated every 8 hours for 3 consecutive days. Rats were euthanized and skin harvested for histochemistry and immunohistochemistry. Formation of protein adducts of 4-hydroxynonenal (HNE), malonadialdehyde (MDA) and acrolein (ACR) and expression of aldehyde dehydrogenase (ALDH) isozymes, ALDH1 and ALDH2 were assessed. Results LF lotion-treated burn sites and interspaces showed mild morphological improvement compared to untreated burn sites. Furthermore, the lotion significantly decreased the immunostaining of lipid aldehyde-protein adducts including protein -HNE, -MDA and -ACR adducts, and restored the expression of aldehyde dehydrogenase isozymes in the unburned interspaces. Conclusion This data, for the first time, demonstrates that a topically applied EDTA-containing lotion protects burn injury progression with a concomitant decrease in the accumulation of reactive lipid aldehydes and protection of aldehyde dehydrogenase isozymes. Present studies are suggestive of therapeutic intervention of burn injury by this novel lotion. PMID:26392023

  20. Topically applied metal chelator reduces thermal injury progression in a rat model of brass comb burn.

    PubMed

    Wang, Cheng Z; Ayadi, Amina El; Goswamy, Juhi; Finnerty, Celeste C; Mifflin, Randy; Sousse, Linda; Enkhbaatar, Perenlei; Papaconstantinou, John; Herndon, David N; Ansari, Naseem H

    2015-12-01

    Oxidative stress may be involved in the cellular damage and tissue destruction as burn wounds continues to progress after abatement of the initial insult. Since iron and calcium ions play key roles in oxidative stress, this study tested whether topical application of Livionex formulation (LF) lotion, that contains disodium EDTA as a metal chelator and methyl sulfonyl methane (MSM) as a permeability enhancer, would prevent or reduce burns. We used an established brass comb burn model with some modifications. Topical application of LF lotion was started 5 min post-burn, and repeated every 8 h for 3 consecutive days. Rats were euthanized and skin harvested for histochemistry and immunohistochemistry. Formation of protein adducts of 4-hydroxynonenal (HNE), malonadialdehyde (MDA) and acrolein (ACR) and expression of aldehyde dehydrogenase (ALDH) isozymes, ALDH1 and ALDH2 were assessed. LF lotion-treated burn sites and interspaces showed mild morphological improvement compared to untreated burn sites. Furthermore, the lotion significantly decreased the immunostaining of lipid aldehyde-protein adducts including protein -HNE, -MDA and -ACR adducts, and restored the expression of aldehyde dehydrogenase isozymes in the unburned interspaces. This data, for the first time, demonstrates that a topically applied EDTA-containing lotion protects burns progression with a concomitant decrease in the accumulation of reactive lipid aldehydes and protection of aldehyde dehydrogenase isozymes. Present studies are suggestive of therapeutic intervention of burns by this novel lotion. Copyright © 2015 Elsevier Ltd and ISBI. All rights reserved.

  1. Development of a $10/kW bipolar separator plate. Technical quarterly progress report, July 1--September 30, 1998

    SciTech Connect

    1998-12-31

    The authors have identified a moldable graphite blend separator plate material, have molded complex shape bipolar separator plates, have tested the molded plate properties and function in single fuel cells, and have designed a conceptual rapid manufacturing line. In this quarter, the project received a three-month interim funding period to continue progress while the proposal is in DOE review. Thus, this fourth quarterly report is submitted in place of the originally scheduled final report for this project. All of the objectives of this project have been accomplished. Specifically, the electrical, chemical, and physical properties of the molded separator plates have met or exceeded the DOE specifications. Performance and endurance tests of the molded plates in single cells have shown comparable performance to the state-of-art machined graphite separator plates. The DOE cost target of $10 per kW appears to be achievable with the low cost composite materials.

  2. I-NERI QUARTERLY TECHNICAL PROGRESS REPORT - JANUARY 1 - MARCH 31, 2005

    SciTech Connect

    Chang Oh

    2005-03-01

    codes. The three categories of experiments were performed in the facility; (1) upper pool cooling trip test, (2) LOFC experiment, (3) emissivity measurement experiment. (C) Prof. NO continued Task 3. (Prof NO) The experimental work of air ingress is going on without any concern: Geometry and size effect test has been completed. The conversion factor for internal surface area was obtained through this experiment. Burn-off test was performed and the uniformity of internal reaction was confirmed. (D) INEEL engineers continued to extend the diffusion model for multiple chemical species and made some calculations. (E) Prof. Lee and Martin at University of Michigan continued to analyze the effect of the stochastic fuel on the neutronic analysis and have initiated fuel depletion calculations for the VHTGR core. Progress during the past quarter includes: Further analysis of stochastic fuel geometry; Preliminary Monte Carlo depletion of full-core VHTGR; and Installation of MCNP5 on Unix cluster.

  3. Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, July 1992--September 1992

    SciTech Connect

    Not Available

    1992-11-01

    Preparation of the baseline economic assessment, based on Wilsonville Run {number_sign}263J, continued. This baseline study will serve as the reference against which the results of this program will be compared. During the quarter calculation of the material and energy balances for the conceptual commercial plant were completed and estimation of the investment for the main process units was begun (Wyoming plant site basis). A presentation on the technical results of the baseline study was prepared and delivered at the Quarterly Project Review Meeting in Pittsburgh.

  4. Solar energy systems simulation and analysis. 1st quarterly progress report, September 30-December 30, 1979

    SciTech Connect

    Vant-Hull, L.L.

    1980-01-20

    The primary objective of this contract is to generate User's Guides for several University of Houston developed codes relating to the performance and optimization of solar power tower or solar central receiver systems. Although certain planned generalizations of the codes for a user's version have been delayed until the second quarter, an acceptable outline of the User's Guide has been produced, and documentation is underway. During the second quarter a draft of this user's guide will be prepared, the code generalizations carried to a logical conclusion and preliminary steps in documenting other components of our code library initiated.

  5. Liquid fossil-fuel technology. Quarterly technical progress report, January-March 1983

    SciTech Connect

    Linville, B.

    1983-07-01

    Accomplishments for the quarter ending March 1983 are presented under the following headings: liquid fossil fuel cycle, processing, utilization, and project integration and technology transfer. Feature articles for this quarter are: (1) abandoned oil field reports issued; (2) oilfield water data bank report published; (3) microbial enhanced recovery report issued; (4) polymer-augmented project could be economic today; (5) carbon dioxide EOR estimates given; (6) BETC passes 65th milestone; and (7) fifty achievements for fifty years (1918-1968). BETC publications are also listed. (ATT)

  6. Investigation of mineral transformations and ash deposition during staged combustion. Quarterly technical progress report, October 1, 1995--December 31, 1995

    SciTech Connect

    Harb, J.N.

    1996-02-07

    Progress during the ninth quarter of a three-year study of ash formation and deposition was made in several areas. One of the key contributions this quarter was the development of an enhanced method for classification of CCSEM data. This classification algorithm permits grouping and comparison of particles previously labeled as ``unclassifiable.`` A second analytical advancement, also made this quarter, provides more detailed information on the distribution of minerals in the coal and the potential for coalescence. This new multiple analysis technique is also applicable to ash and will permit identification of heterogeneous ash particles. Additional analyses of ash samples were also performed and it was found that the firing of Pittsburgh {number_sign}8 under staged combustion conditions yields an ash with a significantly larger particle size distribution than that obtained under conventional firing conditions, but without a significant change in composition. the size difference was noted previously, but the new classification algorithm allowed a detailed comparison of all composition groups, including unclassifiable particles, in the ashes. A mechanistic explanation for this behavior has been developed and is provided in the report. Finally, a paper documenting the new classification algorithm has been prepared and is scheduled for presentation at the March ACS meeting in New Orleans.

  7. Bench-scale testing of the micronized magnetite process. Second quarterly technical progress report, October 1994--December 1994

    SciTech Connect

    1995-01-19

    This document contains the Quarterly Technical Progress Report for the Micronized Magnetite Testing Project being performed at PETC`s Process Research Facility (PRF). This second quarterly report covers the period from October, 1994 through December, 1994. The main accomplishments of Custom Coals and the project subcontractors, during this period, included: (1) Submitted all overdue project documents and kept up with routine reporting requirements; (2) Worked with CLI Corporation, the design subcontractor, and completed the circuit design and finalized all design drawings; (3) Specified and procured all of the process equipment for the circuit, as well as a number of ancillary equipment, instruments, and supplies; (4) Assisted Vangura Iron Inc. in detailing and constructing the structural and platework steel; (5) Subcontracted Rizzo & Sons to perform the circuit mechanical and electrical installation, and prepared for January 23rd installation start date; (6) Organized and prepared for coal and magnetite procurement; (7) Specified and organized an operating personnel plan for the commissioning and testing tasks in the project; (8) Assessed analytical challenges for project, and began to research problem areas. This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the abovementioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  8. Application of selected microorganisms for organic sulfur removal from coal: Quarterly progress report, December 15, 1988--March 15, 1989

    SciTech Connect

    Boyden, B. H.

    1989-12-13

    Progress is reported on coal desulfurization by microorganisms. This quarter, ten pounds of Illinois No. 6 coal were ground, homogenized and stored under nitrogen. Arrangements are being made to procure quantities of Kentucky No. 11 and Pittsburgh No. 8 coals. Treatment of the Illinois No. 6 coal for pyrite and sulfate removal is proceeding. Some delay was encountered due to inactive (i.e., old, lysed, few viable cells) cultures of Thiobacillus ferrooxidans and Thiobacillus thiooxidans, but new cultures were obtained. Also, screening of 45 pathway isolates and 45 bacteria continued. 1 tab. (CBS)

  9. Toms Creek Integrated Gasification Combined Cycle Demonstration Project. Final quarterly technical progress report for the period ending March 31, 1993

    SciTech Connect

    Feher, G.

    1993-05-24

    This Quarterly Technical Progress Report for the period ending March 31, 1993 summarizes the work done to data by Tampella Power Corporation and Enviropower, Inc. on the integrated combined-cycle power plant project. Efforts were concentrated on the Toms Creek PDS (Preliminary Design and Studies). Tampella Power Corporation`s efforts were concentrated on the Toms Creek Preliminary Process Flow Diagram (PFD) and Piping and Instrument Diagrams (P&IDs). Tampella Power Corporation also prepared Heat and Material Balances (H&MBs) for different site-specific cases.

  10. Integral glass encapsulation for solar arrays. Quarterly progress Report No. 12, October 11, 1979-January 10, 1980

    SciTech Connect

    Young, Peter R.

    1980-02-01

    This is the twelfth quarterly report under a JPL/DOE program for the development of electrostatic bonding as a method of integral encapsulation of solar cells in glass. Efforts for the current phase of this program are to continue to demonstrate process uniformity of electrostatic bonding encapsulation. Additional goals of this program are to develop preformed (wire mesh) contacts as a method of integrating cell processing into the encapsulation procedure resulting in a low cost module assembly technique, and to investigate low-temperature bonding to commercially available glass (pyrex) substrates. Progress is reported.

  11. Geothermal direct-heat utilization assistance. Quarterly project progress report, July 1996--September 1996. Federal Assistance Program

    SciTech Connect

    Lienau, P.

    1996-11-01

    This report summarizes geothermal technical assistance, R&D and technology transfer activities of the Geo-Heat Center at Oregon Institute of Technology for the fourth quarter of FY-96. It describes 152 contacts with parties during this period related to technical assistance with geothermal direct heat projects. Areas dealt with include geothermal heat pumps, space heating, greenhouses, aquaculture, equipment, economics and resources. Research activities are summarized on greenhouse peaking. Outreach activities include the publication of a geothermal direct use Bulletin, dissemination of information, geothermal library, technical papers and seminars, and progress monitor reports on geothermal resources and utilization.

  12. Amarillo National Resource Center for Plutonium quarterly technical progress report, August 1, 1997--October 31, 1997

    SciTech Connect

    1997-12-31

    This report summarizes activities of the Amarillo National Resource Center for Plutonium during the quarter. The report describes the Electronic Resource Library; DOE support activities; current and future environmental health and safety programs; pollution prevention and pollution avoidance; communication, education, training, and community involvement programs; and nuclear and other material studies, including plutonium storage and disposition studies.

  13. Fischer Tropsch synthesis in supercritical fluids. Quarterly technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect

    Akgerman, A.; Bukur, D.B.

    1996-05-01

    Our objectives for this quarter were: (1) to install and test the temperature probe and the flammable gas detector: (2) to conduct Fischer-Tropsch synthesis experiments at baseline conditions and at a high pressure in order to test the newly constructed fixed bed reactor assembly.

  14. Magnetically controlled deposition of metals using gas plasma. Quarterly progress report, April--June 1997

    SciTech Connect

    1997-07-01

    The objective of the grant is to develop a method of spraying materials on a substrate in a controlled manner to eliminate the waste inherent in present plating processes. The process under consideration is magnetically controlled plasma spraying. As noted in the last several quarterly reports, the project is no longer on schedule. Difficulties with modeling compressible flow caused a slip in the schedule. The field equations have been cast in a format that allows solution using Finite Element (FE) techniques. The development of the computer code that will allow evaluation of the proposed technique and design of an experiment to prove the proposed process is complete. Work last quarter was centered on validating the magnetic field equation and developing the mesh for the final plasma torch flow problem. Results of a test problem used to validate the magnetic calculation were included with the second quarterly report in 1997. The effort this quarter focused on running the actual plasma spray model on the finite element code, and developing a stand alone code (SPRAY.for) that will be used to calculate the trajectory of the particles used for plating the substrate.

  15. The Monitoring Commission for Desegregation Implementation's Quarterly Progress Report on Monitoring Project CANAL.

    ERIC Educational Resources Information Center

    Davidson, Mary E.; And Others

    This quarterly report, covering February 1 through June 30, 1989, summarizes problems with Project Creating a New Approach to Learning (CANAL), part of a court-mandated desegregation plan to reduce inequities in predominantly Black and Hispanic American schools in Chicago (Illinois). CANAL's goal is to train the constituent representatives of the…

  16. PFBC HGCU Test facility. Technical progress report, Fourth quarter, CY 1994

    SciTech Connect

    1995-01-01

    During this quarter, the Tidd Hot Gas Clean Up System completed a 691-hour test run which began during the third quarter. Table 1 summarizes all test runs since initial operation. Following this test run the system was shut down and the filter opened for inspection and recandling. The system remained out of service during the remainder of the quarter. In addition to monitoring and evaluating the performance of the HGCU system during testing, engineering effort was devoted to posttest inspection of the APF (Advanced Particle Filter) and evaluation of the effects of totally spoiling the primary cyclone. In addition, the authors worked with Westinghouse in the selection of replacement candles that were installed during the fourth quarter. During the unit outage this quarter, the primary cyclone upstream of the APF was modified to force all of the ash to pass through the cyclone and enter the APF without using spoiling air. Appendices to this report describe the dust shroud support strap design; an analysis of the effect of support-transferred vibrations on the failure of ceramic candle filters; the Tidd APF operation; the Tidd APF boroscope inspection; a general inspection of Tidd filter internals; tally of Tidd filters; ash formations in the W-APF-October 1994 post-test inspection; characterization of the as-manufactured and PFBC-exposed 3M CVI-SiC composite filter matrix; strength characterization of the first and second generation candle filters after 1,705 hours of PFBC operation at Tidd; and filters used in the December 1994 recandling effort at Tidd.

  17. Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report 4, July--September 1993

    SciTech Connect

    McCormick, R.L.; Jha, M.C.; Streuber, R.D.

    1993-12-07

    This document is the fourth quarterly technical progress report under Contract No. DE-AC22-92PC92110, {open_quotes}Development of Vanadium-Phosphate Catalysts for Methanol Production by Selective Oxidation of Methane.{close_quotes} During this quarter, the authors focused primarily on catalyst activity testing in the microreactor. Additional blank runs using methane and methanol were performed. Initial attempts at preparing a silica supported catalyst are described. These results are discussed in detail and plans for the coming quarter are outlined.

  18. Contracts for field projects and supporting research on enhanced oil recovery and improved drilling technology. Progress review No. 34, quarter ending March 31, 1983

    SciTech Connect

    Linville, B.

    1983-07-01

    Progress achieved for the quarter ending March 1983 are presented for field projects and supporting research for the following: chemical flooding; carbon dioxide injection; and thermal/heavy oil. In addition, progress reports are presented for: resource assessment technology; extraction technology; environmental and safety; microbial enhanced oil recovery; oil recovered by gravity mining; improved drilling technology; and general supporting research. (ATT)

  19. Computational mechanics research and support for aerodynamics and hydraulics at TFHRC. Quarterly report January through March 2011. Year 1 Quarter 2 progress report.

    SciTech Connect

    Lottes, S. A.; Kulak, R. F.; Bojanowski, C.

    2011-05-19

    This project was established with a new interagency agreement between the Department of Energy and the Department of Transportation to provide collaborative research, development, and benchmarking of advanced three-dimensional computational mechanics analysis methods to the aerodynamics and hydraulics laboratories at the Turner-Fairbank Highway Research Center for a period of five years, beginning in October 2010. The analysis methods employ well-benchmarked and supported commercial computational mechanics software. Computational mechanics encompasses the areas of Computational Fluid Dynamics (CFD), Computational Wind Engineering (CWE), Computational Structural Mechanics (CSM), and Computational Multiphysics Mechanics (CMM) applied in Fluid-Structure Interaction (FSI) problems. The major areas of focus of the project are wind and water loads on bridges - superstructure, deck, cables, and substructure (including soil), primarily during storms and flood events - and the risks that these loads pose to structural failure. For flood events at bridges, another major focus of the work is assessment of the risk to bridges caused by scour of stream and riverbed material away from the foundations of a bridge. Other areas of current research include modeling of flow through culverts to assess them for fish passage, modeling of the salt spray transport into bridge girders to address suitability of using weathering steel in bridges, vehicle stability under high wind loading, and the use of electromagnetic shock absorbers to improve vehicle stability under high wind conditions. This quarterly report documents technical progress on the project tasks for the period of January through March 2011.

  20. Stanford Geothermal Program (quarterly technical report, April--June 1991; topical report, July 1, 1990--June 30, 1991)

    SciTech Connect

    Not Available

    1991-07-16

    The reinjection task on optimizing injection into the Palinpinon geothermal field in the Philippines was completed. Progress is summarized on experimental investigation of absorption, estimation of adsorption parameters from experimental and field data, the theoretical study of adsorption isotherms, and interpreting pressure data. (MHR)

  1. Stanford Geothermal Program [quarterly technical report, April--June 1991; topical report, July 1, 1990--June 30, 1991

    SciTech Connect

    Not Available

    1991-07-16

    The reinjection task on optimizing injection into the Palinpinon geothermal field in the Philippines was completed. Progress is summarized on experimental investigation of absorption, estimation of adsorption parameters from experimental and field data, the theoretical study of adsorption isotherms, and interpreting pressure data. (MHR)

  2. Oxidation of phenolics in supercritical water. Combined quarterly technical progress report, December 1, 1995--May 31, 1996

    SciTech Connect

    1996-11-01

    Over the past two quarters, our work has focused on three main areas. The first area of interest involved a reexamination of the rate laws that were formed in past quarters. A possible error was discovered for the analytical methods used in the o-cresol oxidation study and the data were corrected, yielding a new rate equation. The data for hydroxybenzaldehydes were studied again, this time as a system of parallel oxidation and thermolysis reactions. The second area in which progress was made was the study of the thermolysis of nitrophenols and dihydroxybenzenes in supercritical water. These investigations were needed to determine the effect that pyrolysis or hydrolysis had on our previous supercritical water oxidation experiments. Thirdly, we have continued to investigate the use of molecular orbital theory in the determination reactivity indices. A reactivity index, such as the enthalpy of formation, may be used in a structure-reactivity relationship to summarize the kinetics for the oxidation of phenolics in supercritical water. Progress in each of these areas is summarized.

  3. Advanced research and technology development fossil energy materials program. Quarterly progress report for the period ending September 30, 1981

    SciTech Connect

    Bradley, R.A.

    1981-12-01

    This is the fourth combined quarterly progress report for those projects that are part of the Advanced Research and Technology Development Fossil Energy Materials Program. The objective is to conduct a program of research and development on materials for fossil energy applications with a focus on the longer-term and generic needs of the various fossil fuel technologies. The program includes research aimed toward a better understanding of materials behavior in fossil energy environments and the development of new materials capable of substantial enhancement of plant operations and reliability. Work performed on the program generally falls into the Applied Research and Exploratory Development categories as defined in the DOE Technology Base Review, although basic research and engineering development are also conducted. A substantial portion of the work on the AR and TD Fossil Energy Materials Program is performed by participating cntractor organizations. All subcontractor work is monitored by Program staff members at ORNL and Argonne National Laboratory. This report is organized in accordance with a work breakdown structure defined in the AR and TD Fossil Energy Materials Program Plan for FY 1981 in which projects are organized according to fossil energy technologies. We hope this series of AR and TD Fossil Energy Materials Program quarterly progress reports will aid in the dissemination of information developed on the program.

  4. Coal-fired MHD combustor development project: Phase IIIB. First quarterly technical progress report, 13 January-30 April 1982

    SciTech Connect

    1982-05-20

    The first quarterly technical progress report of the Coal-Fired MHD Combustor Development Project (Phase IIIB) presents the accomplishments during the period 13 January to 30 April, 1982. The scope of work covered by this quarterly report relates to those tasks associated with preparing the TRW 20 MW/sub t/ MHD coal combustor for delivery to AERL for integrated power tests and the work associated with the preliminary design of a 50 MW/sub t/ coal-fired combustor. Progress during this reporting period is described. All new 20 MW/sub t/ hardware was designed and fabricated. Interface coordination meetings were conducted with AERL and DOE. Interface control drawings were completed and a 20 MW/sub t/ coal combustion User's manual was delivered to AERL. The User's manual contained a shipping plan, a crew training plan, an assembly manual, interface documentation and recommended operating procedures. Facility/combustor set-up was completed and the pre-delivery 20 MW/sub t/ coal combustor qualification test series was completed. The 50 MW/sub t/ coal-fired MHD combustor preliminary designs were finalized and the DOE preliminary design review (PDR) was successfully completed.

  5. Energy efficient louver and blind. Technical progress report for Quarter 2, 1996

    SciTech Connect

    Khajavi, S.

    1996-07-26

    In this quarter we jumped ahead and performed Task 5 which is testing to get empirical energy saving data. One 4` X 3` horizontal Incredibling prototype and one black and one white conventional control blinds with the same size were delivered to the Lawrence Berekely Laboratories Mobile Test Facility in Reno. The blinds are still in testing since we had only two sunny days in the month of June and we encountered some hardware problem with the computers at the lab.

  6. Anaerobic bioprocessing of low-rank coals. Quarterly progress report, January 1--March 31, 1992

    SciTech Connect

    Jain, M.K.; Narayan, R.; Han, O.

    1992-04-15

    The overall goal of this project is to find biological methods to remove carboxylic functionalities from low-rank coals and to assess the properties of the modified coal towards coal liquefaction. The main objectives for this quarter were: (1) continuation of microbial consortia development and maintenance, (2) crude enzyme study using best decarboxylating organisms, (3) decarboxylation of lignite, demineralized Wyodak coal and model polymers, and (4) characterization of biotreated coals.

  7. Enforcement actions: Significant actions resolved; Quarterly progress report, October--December 1993: Volume 12, No. 4

    SciTech Connect

    1994-03-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (October - December 1993) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication.

  8. Geothermal direct-heat utilization assistance. Quarterly project progress report, July 1994--September 1994

    SciTech Connect

    Not Available

    1994-10-01

    This paper is a third quarter 1994 report of activities of the Geo-Heat Center of Oregon Institute of Technology. It describes contacts with parties during this period related to assistance with geothermal direct heat applications. Areas dealt with include geothermal heat pumps, space heating, greenhouses, aquaculture, resources, and equipment. Research is also being conducted on failures of vertical lineshaft turbines in geothermal wells.

  9. OTEC support services. Quarterly technical progress report No. 7, 15 November 1979-14 February 1980

    SciTech Connect

    1980-02-01

    The technical engineering and management support services provided by VSE corporation for the Ocean Thermal Energy Conversion Program of the Ocean Systems Branch, Division of Central Solar Technology during this quarter are described. The seven tasks include (1) survey, analysis evaluation, and recommendation concerning program performance, (2) program technical monitoring, (3) development and implementation of methodology to identify and evaluate program alternatives, (4) technical assessments, (5) OTEC system integration, (6) environment and siting considerations; and (7) transmission subsystem considerations. (WHK)

  10. Anaerobic bioprocessing of low-rank coals. Quarterly progress report, October 1--December 31, 1991

    SciTech Connect

    Jain, M.K.; Narayan, R.; Han, O.

    1992-01-30

    The overall goal of this project is to find biological methods to remove carboxylic functionalities from low-rank coals under ambient conditions and to assess the properties of these modified coals towards coal liquefaction. The main objectives of this quarter were: (1) continuation of microbial consortia development, (2) evaluation of the isolated organisms for decarboxylation, (3) selection of best performing culture (known cultures vs. new isolates), and (4) coal decarboxylation using activated carbon as blanks. The project began on September 12, 1990.

  11. Coal precursors for carbon molecular seives. Quarterly progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Kopp, O.C.

    1995-09-29

    Shortly after our Quarterly Report for the period April 1, 1995 - June 30, 1995 was submitted, we completed the last two thermogravimetric-mass spectrographic (TG/MS) analyses of our samples. The results of these analyses will be included in the Final Report with the TG/MS data accumulated for the other coal samples. We then turned our attention to activating each of the coals using air activation. The results of the activation study are reported below.

  12. Geothermal direct-heat utilization assistance. Quarterly progress report, April--June 1993

    SciTech Connect

    Not Available

    1993-08-01

    Progress is reported on the following R&D activities: evaluation of lineshaft turbine pump problems, geothermal district heating marketing strategy, and greenhouse peaking analysis. Other activities are reported on technical assistance, technology transfer, and the geothermal progress monitor.

  13. Lincoln County nuclear waste project. Quarterly progress report, October 1, 1991--December 31, 1991

    SciTech Connect

    1996-03-01

    This document included the following three progress reports to the Yucca Mountain Project Office on radioactive waste storage in Lincoln County, Nevada: financial status report; federal cash transactions report; and technical progress report.

  14. Chemistry {ampersand} Materials Science progress report summary of selected research and development topics, FY97

    SciTech Connect

    Newkirk, L.

    1997-12-01

    This report contains summaries of research performed in the Chemistry and Materials Science division. Topics include Metals and Ceramics, High Explosives, Organic Synthesis, Instrument Development, and other topics.

  15. Amarillo National Resource Center for Plutonium quarterly technical progress report, August 1--October 31, 1998

    SciTech Connect

    1998-11-01

    This paper describes activities of the Center under the following topical sections: Electronic resource library; Environmental restoration and protection; Health and safety; Waste management; Communication program; Education program; Training; Analytical development; Materials science; Plutonium processing and handling; and Storage.

  16. High temperature packing test program. First quarterly technical progress report, October 1-December 26, 1981

    SciTech Connect

    Not Available

    1982-02-12

    The program was undertaken to improve the technical understanding of the performance of plunger packings in coal liquefaction pilot plant feed pumps. During the first quarter of FY 1982, visits were made to the H-Coal, EDS and SRC-I pilot plants, where technical discussions were held with maintenance and engineering personnel, and the maintenance records and work orders for the plunger pumps were reviewed. Technical discussions were held with engineering personnel at the manufacturing facilities of three plunger pump manufacturers' companies. Contracts and technical discussions with packing vendors were initiated. Design of the laboratory tests was started.

  17. Enforcement actions: Significant actions resolved material licensees. Quarterly progress report, April 1995--June 1995

    SciTech Connect

    1995-08-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (April-June 1995) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to material licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication.

  18. Modeling, design, and life performance prediction for energy production from geothermal reservoirs. First quarter progress report

    SciTech Connect

    Swenson, D.

    1997-08-15

    The objective of this project is to both transfer existing Hot Dry Rock two-dimensional fractured reservoir analysis capability to the geothermal industry and to extend the analysis concepts to three dimensions. In this quarter, the primary focus has been on interaction with industry, development of the Geocrack3D model, and maintenance of Geocrack2D. It is important to emphasize that the modeling is complementary to current industry modeling, in that they focus on flow in fractured rock and on the coupled effect of thermal cooling, while a primary focus of current modeling technology is multi-phase flow.

  19. Geothermal direct-heat utilization assistance. Quarterly project progress report, January--March 1994

    SciTech Connect

    Not Available

    1994-05-01

    The Geo-Heat Center provides technical assistance on geothermal direct heat applications to developers, consultants and the public which could include: data and information on low-temperature (< 1500 C) resources, space and district heating, geothermal heat pumps, greenhouses, aquaculture, industrial processes and other technologies. This assistance could include preliminary engineering feasibility studies, review of direct-use project plans, assistance in project material and equipment selection, analysis and solutions of project operating problems, and information on resources and utilization. The following are brief descriptions of technical assistance provided during the second quarter of the program.

  20. Nucla circulating atmospheric fluidized bed demonstration project. Quarterly technical progress report, October--December 1990

    SciTech Connect

    Not Available

    1991-01-31

    During the fourth quarter of 1990, steady-state performance testing at the Nucla Circulating Fluidized Bed (CFB) resumed under sponsorship of the US Department of Energy. Co-sponsorship of the Demonstration Test Program by the Electric Power Research Institute (EPRI) was completed on June 15, 1990. From October through December, 1990, Colorado-Ute Electric Association (CUEA) completed a total of 23 steady-state performance tests, 4 dynamic tests, and set operating records during November and December as the result of improved unit operating reliability. Highlight events and achievements during this period of operation are presented.

  1. Enforcement actions: Significant actions resolved. Quarterly progress report, April--June 1993: Volume 12, No. 2

    SciTech Connect

    Not Available

    1993-09-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (April--June 1993) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication.

  2. Novel concepts in electrochemical solar cells. Quarterly technical progress report, December 15, 1980-March 15, 1981

    SciTech Connect

    Not Available

    1981-01-01

    During the past quarter, the following areas were emphasized: (a) characterization of redox couples with very positive potentials in room-temperature AlCl/sub 3/-BPC electrolytes and comparison of the electrochemical behavior of decamethyl ferrocene in these electrolytes with the previously-studied ferrocene/ferricenium ion couple, (b) photoelectrochemical characterization of CdSe thin-film anodes in aqueous polysulfide electrolytes and (c) refinement of the admittance measurement technique for extraction of Mott-Schottky parameters. The results of research in these areas are detailed in turn below.

  3. Mild coal pretreatment to improve liquefaction reactivity. Quarterly technical progress report, September--November 1991

    SciTech Connect

    Miller, R.L.

    1991-12-31

    This report describes work completed during the fifth quarter of a three year project to study the effects of mild chemical pretreatment on coal dissolution reactivity during low severity liquefaction or coal/oil coprocessing. The overall objective of this research is to elucidate changes in the chemical and physical structure of coal by pretreating with methanol or other simple organic solvent and a trace amount of hydrochloric acid and measure the influence of these changes on coal dissolution reactivity. Work this quarter focused on analytical characterization of untreated and treated Wyodak subbituminous coal and Illinois {number_sign}6 bituminous coal. Mossbauer spectroscopy and x-ray diffraction techniques were used to study the effect of methanol/HCl pretreatment on the composition of each coal`s inorganic phase. Results from these studies indicated that calcite is largely removed during pretreatment, but that other mineral species such as pyrite are unaffected. This finding is significant, since calcite removal appears to directly correlate with low severity liquefaction enhancement. Further work will be performed to study this phenomenon in more detail.

  4. Catalytic conversion of light alkanes. Quarterly progress report, April 1--June 30, 1992

    SciTech Connect

    Lyons, J.E.

    1992-06-30

    The second Quarterly Report of 1992 on the Catalytic Conversion of Light Alkanes reviews the work done between April 1, 1992 and June 31, 1992 on the Cooperative Agreement. The mission of this work is to devise a new catalyst which can be used in a simple economic process to convert the light alkanes in natural gas to oxygenate products that can either be used as clean-burning, high octane liquid fuels, as fuel components or as precursors to liquid hydrocarbon uwspomdon fuel. During the past quarter we have continued to design, prepare, characterize and test novel catalysts for the mild selective reaction of light hydrocarbons with air or oxygen to produce alcohols directly. These catalysts are designed to form active metal oxo (MO) species and to be uniquely active for the homolytic cleavage of the carbon-hydrogen bonds in light alkanes producing intermediates which can form alcohols. We continue to investigate three molecular environments for the active catalytic species that we are trying to generate: electron-deficient macrocycles (PHASE I), polyoxometallates (PHASE II), and regular oxidic lattices including zeolites and related structures as well as other molecular surface structures having metal oxo groups (PHASE I).

  5. Cuprous oxide photovoltaic cells. Third quarterly technical progress report, October 9, 1979 to January 8, 1980

    SciTech Connect

    Trivich, D.

    1980-01-08

    Previous work in this laboratory on cuprous oxide Schottky barrier photovoltaic cells showed that some potential improvements were limited by chemical degradations at the junction (1), e.g., in Al/Cu/sub 2/O cells, the aluminum reduced the surface of the Cu/sub 2/O to metallic Cu. The present project is being devoted to a study of methods to avoid this problem and also to the development of other methods of improving the efficiency of Cu/sub 2/O cells. The first quarterly report was devoted to a study of thin oxide interlayers between the metal and the Cu/sub 2/O which gives MIS structures. The most stable interlayers were obtained with SiO/sub 2/. The second quarterly report covered some initial work on heterojunctions with other oxides on Cu/sub 2/O. The most stable heterojunctions were obtained with CdO on Cu/sub 2/O. The present report presents some results on Auger studies of the oxide heterojunctions, the preparation of doped Cu/sub 2/O by introduction of impurities in the starting copper, the exploration of several method for the study of diffusion length, and some initial attempts on the laser annealing of Cu/sub 2/O.

  6. Geothermal direct-heat utilization assistance. Federal Assistance Program quarterly project progress report, April 1--June 30, 1998

    SciTech Connect

    1998-07-01

    This report summarizes geothermal technical assistance, R and D and technology transfer activities of the Geo-Heat Center at Oregon Institute of Technology for the third quarter of FY98 (April--June, 1998). It describes 231 contacts with parties during this period related to technical assistance with geothermal direct heat projects. Areas dealt with included requests for general information including material for high school and university students, and material on geothermal heat pumps, resource and well data, spacing heating and cooling, greenhouses, aquaculture, equipment, district heating, resorts and spas, industrial applications, snow melting and electric power. Research activities include work on model construction specifications for line shaft submersible pumps and plate heat exchangers, and a comprehensive aquaculture developers package. A brochure on Geothermal Energy in Klamath County was developed for state and local tourism use. Outreach activities include the publication of the Quarterly Bulletin (Vol. 19, No. 2) with articles on research at the Geo-Heat Center, sustainability of geothermal resources, injection well drilling in Boise, ID and a greenhouse project in the Azores. Other outreach activities include dissemination of information mainly through mailings of publications, tours of local geothermal uses, geothermal library acquisitions and use, participation in workshops, short courses and technical meetings by the staff, and progress monitor reports on geothermal activities.

  7. Hot gas cleanup test facility for gasification and pressurized combustion. Quarterly technical progress report, April 1--June 30, 1992

    SciTech Connect

    Not Available

    1992-12-01

    This quarterly technical progress report summarizes work completed during the Seventh Quarter of the First Budget Period, April 1 through June 30, 1992, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion will include the consideration of the following modules at the test facility in addition to the existing Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/Pressurized Circulating Fluidized Bed Gas Source; Hot Gas Cleanup Units to mate to all gas streams. Combustion Gas Turbine; Fuel Cell and associated gas treatment; and Externally Fired Gas Turbine/Water Augmented Gas Turbine. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF).

  8. Selenium fractionation and cycling in the intertidal zone of the Carquinez Strait. Quarterly progress report, October 1995--December 1995

    SciTech Connect

    Zawislanski, P.T.; McGrath, A.E.; Benson, S.M.

    1996-01-01

    This quarterly report describes the research on selenium (Se) cycling in the marshes and mudflats of the Carquinez Strait between October 1, 1995 and December 31, 1995. Chapter 2 contains descriptions of field activities and laboratory work related to chemical characterization of sediments and soils. Eh and pH data are presented. Chapter 3 contains a summary of work in progress on the extraction of various Se species from sediment/soil samples, and efforts in measuring suspended sediment Se. Chapter 4 describes advances made in the analysis of parts-per-trillion level Se, using a lanthanum hydroxide co-precipitation method, and the determination of matrix effects. Chapter 5 is an update on stable Se isotope research and Se purification techniques. The reader is referred to the 1995 Annual Report for details on the project design, site selection, and methodology.

  9. Selenium fractionation and cycling in the intertidal zone of the Carquinez Strait. Quarterly progress report, January 1996--March 1996

    SciTech Connect

    Zawislanski, P.T.; Benson, S.M.; Brownfield, A.A.

    1996-04-01

    This quarterly report describes research on selenium (Se) cycling in the marshes and mudflats of the Carquinez Strait between January 1, 1996 and March 31, 1996. Chapter 2 contains descriptions of results of extractions and analyses of sediment cores from the intertidal zone of the Martinez and Benicia field sites, including some x-ray spectroscopy data related to the characterization of the sediment Eh-pH regime. Chapter 3 contains a summary of work in progress on the extraction of various Se species from sediment/soil samples, and efforts in measuring suspended sediment Se. Chapter 4 is an update on stable Se isotope research and Se purification techniques. Chapter 5 describes the rationale, design, and preliminary results of a plant-Se study. Chapter 6 presents the design of a recently initiated sediment dynamics study. The leader is referred to the 1995 Annual Report for details on the project design, site selection, and methodology.

  10. Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, October 1, 1994--December 31, 1994

    SciTech Connect

    Li, W.B.; Yang, R.T.

    1994-12-31

    During the past quarter, progress was made in three tasks. The poisoning effects of alkali metals (as Na{sub 2}O, K{sub 2}0 and Cs{sub 2}O) on iron oxide pillared clay (Fe-Bentonite) catalyst for selective catalytic reduction (SCR) of NO with NH{sub 3} were investigated. The effects of sulfur dioxide and water vapor on the performance of the high activity catalyst, that is, Ce-doped Fe-Bentonite pillared clay (Ce-Fe-Bentonite) were examined. In addition, an iron ion-exchanged titania pillared clay (Ti-PILC) was prepared and its catalytic activity for the SCR of NO with NH{sub 3} was studied, which showed a high activity and a high S0{sub 2} and H{sub 2}0 resistance at high temperatures (i.e., above 400{degree}C).

  11. Geothermal direct-heat utilization assistance: Federal assistance program. Quarterly project progress report, October--December 1995

    SciTech Connect

    1996-02-01

    The report summarizes geothermal technical assistance, R&D and technology transfer activities of the Geo-Heat Center at Oregon Institute of Technology for the first quarter of FY-96. It describes 90 contacts with parties during this period related to technical assistance with geothermal direct heat projects. Areas dealt with include geothermal heat pumps, space heating, greenhouses, aquaculture, equipment and resources. Research activities are summarized on low-temperature resource assessment, geothermal district heating system cost evaluation and silica waste utilization project. Outreach activities include the publication of a geothermal direct use Bulletin, dissemination of information, geothermal library, technical papers and seminars, development of a webpage, and progress monitor reports on geothermal resources and utilization.

  12. Selenium fractionation and cycling in the intertidal zone of Carquinez Strait. Quarterly progress report, April 1996--June 1996

    SciTech Connect

    Zawislanski, P.T.; Benson, S.M.; Brownfield, A.A.; Chau, S.

    1996-07-01

    This quarterly report describes research on selenium (Se) cycling in the marshes and mudflats of the Carquinez Strait between 4/1/96 and 6/30/96. Chapter 2 contains descriptions of results of extractions and analyses of sediment cores from the intertidal zone of the Martinez and Benicia field sites, including Se fractionation data from Martinez Regional Park. Chapter 3 contains a summary of work in progress on the extraction of various Se species from sediment/soil samples, and efforts in measuring suspended sediment Se. Chapter 4 is an update on stable Se isotope research and Se purification techniques. Chapter 5 describes the recent developments in low-level Se analytical methods. Chapter 6 presents preliminary sedimentation rate data from the Martinez field site. Exciting new developments in x-ray spectroscopy of clams are presented in Chapter 7. The reader is referred to the 1995 Annual Report for details on the project design, site selection, and methodology.

  13. Mild coal pretreatment to improve liquefaction reactivity. Quarterly technical progress report, June--August 1991

    SciTech Connect

    Miller, R.L.

    1991-12-31

    This report describes work completed during the fourth quarter of a three year project to study the effects of mild chemical pretreatment on coal dissolution reactivity during low severity liquefaction or coal/oil coprocessing. The overall objective of this research is to elucidate changes in the chemical and physical structure of coal by pretreating with methanol or other simple organic solvent and a trace amount of hydrochloric acid and measure the influence of these changes on coal dissolution reactivity. This work is part of a larger effort to develop a new coal liquefaction or coal/oil coprocessing scheme consisting of three main process steps: (1) mile pretreatment of the feed coal to enhance dissolution reactivity and dry the coal, (2) low severity thermal dissolution of the pretreated coal to obtain a very reactive coal-derived residual material amenable to upgrading, and (3) catalytic upgrading of the residual products to distillate liquids.

  14. Commercialization of atom interferometers for borehole gravity gradiometry. Quarterly technical progress report, October--December 1992

    SciTech Connect

    Clauser, J.F.

    1993-01-30

    Perform a mathematical analysis of the tomography inversion problem for various configurations of a borehole gravity gradiometer. Our simulations typically call for logging a hole for about 4km of depth. Within the limits imposed by our presumed detector sensitivity, the device appears to be capable of measuring the 0.1 g/cm{sup 3} density in all rings to about 10% accuracy, with the rings extending out to about 500 meters from the hole. At this range, the vertical resolution has dropped to about 50m. Closer to the hole, the resolution improves so that we can determine the density in each of about 400 rings. We anticipate that this most important task (No. l) will be complete within the next quarter.

  15. Orcas Power and Light Company [fourth quarterly] technical progress report, July--September 1992

    SciTech Connect

    Not Available

    1992-12-31

    After a year of operating the G-Van, OPALCO concluded that the company transportation needs were not being met by the G-Van. The previous quarterly report mentioned battery problems with the Solectria (No. 51). This problem is one of reduced range and power and has been determined to be caused by one or more individual monoblock failures. The local Solectria representative and Solectria headquarters personnel have been aware of this unsatisfactory condition and are continuing their attempt to solve it. The Solectria and G-Van continue to be used intermittently by company personnel for errands and engineering trips. Generally, the smaller, compact size of the Solectria make it the most preferred by company drivers. Clearly the G-Van is not selected for use because of its size and weight. It is important to note that the driver dissatisfaction is not related to the fact that it is an electric van, but more its lack of maneuverability.

  16. Orcas Power and Light Company [fourth quarterly] technical progress report, July--September 1992

    SciTech Connect

    Not Available

    1992-01-01

    After a year of operating the G-Van, OPALCO concluded that the company transportation needs were not being met by the G-Van. The previous quarterly report mentioned battery problems with the Solectria (No. 51). This problem is one of reduced range and power and has been determined to be caused by one or more individual monoblock failures. The local Solectria representative and Solectria headquarters personnel have been aware of this unsatisfactory condition and are continuing their attempt to solve it. The Solectria and G-Van continue to be used intermittently by company personnel for errands and engineering trips. Generally, the smaller, compact size of the Solectria make it the most preferred by company drivers. Clearly the G-Van is not selected for use because of its size and weight. It is important to note that the driver dissatisfaction is not related to the fact that it is an electric van, but more its lack of maneuverability.

  17. Supercritical fluid thermodynamics for coal processing: Quarterly progress report, September 15, 1988--December 31, 1988

    SciTech Connect

    Eckert, C.A.

    1988-01-01

    Because of their unusual solvating and mass transfer properties, supercritical fluids show potential for a variety of coal processing applications. To establish a database of coal model compound equilibria, this quarter we have measured the solubility of 5,6-dimethyl-benzimidazole and anthraquinone in supercritical butane. In addition, we have used fluorescence spectroscopy to study the nature of the intermolecular interactions in the systems of pyrene and naphthalene in supercritical CO/sub 2/, C/sub 2/H/sub 4/, and CF/sub 3/H. The spectroscopy measurements are being used to guide the development of an equation of state that can be used to predict the solubility behavior so systems can be designed for the processing of coal with supercritical fluids. 4 figs.

  18. Pulsed atmospheric fluidized bed combustion. Quarterly technical progress report, July 1992--September 1992

    SciTech Connect

    Not Available

    1992-10-01

    The design of the Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) as described in the Quarterly Report for the period April--June, 1992 was reviewed and minor modifications were included. The most important change made was in the coal/limestone preparation and feed system. Instead of procuring pre-sized coal for testing of the PAFBC, it was decided that the installation of a milling system would permit greater flexibility in the testing with respect to size distributions and combustion characteristics in the pulse combustor and the fluid bed. Particle size separation for pulse combustor and fluid bed will be performed by an air classifier. The modified process flow diagram for the coal/limestone handling system is presented in Figure 1. The modified process flow diagrams of the fluidized bed/steam cycle and ash handling systems are presented in Figures 2 and 3, respectively.

  19. Fischer Tropsch synthesis in supercritical fluids. Quarterly technical progress report, October 1, 1993--December 31, 1993

    SciTech Connect

    Akgerman, A.; Bukur, D.B.

    1993-12-31

    Objectives for the first quarter for Task A, Diffusion Coefficients of F-T Products in Supercritical Fluids, were to measure diffusion coefficients of 1-tetradecene in subcritical propane and the diffusion coefficients of 1-octene and 1-tetradecene in subcritical propane and the diffusion coefficients of 1-octene and 1-tetradecene in subcritical and supercritical ethane. We planned to use ethane as a solvent because its lower critical temperature enabled measurements without modification of the existing unit. Our objective was to investigate the behavior of the diffusion coefficients in crossing from subcritical to supercritical conditions. Objectives for Task B, Fischer Tropsch reaction related studies, were: (1) to install and test the temperature probe and the flammable gas detector: (2) to conduct Fischer-Tropsch experiments at baseline conditions and at a high pressure in order to test the newly constructed fixed bed reactor assembly. Accomplishments and problems, are presented.

  20. Pulsed atmospheric fluidized bed combustion. Quarterly technical progress report, April--June 1993

    SciTech Connect

    Not Available

    1993-07-30

    In this quarter the design of the plant structures was completed 70%. The design philosophy of the structure economizes on the use of steel by providing supports for the hot cyclone and hot gas duct connecting the cyclone to the boiler while fulfilling the needs for platforms and walkways at the various levels necessary for operational access. Figures 1 through 6 indicate the layout of the plant structure. At the same time the structure for the Coarse Coal Silo V-2 and Limestone Silo V-4 were incorporated and completed. Following completion of the piping pressure drop calculations, pipe sizing and layout drawings, detailed drawings of the piping in different views are being prepared. The pulse combustor is used to burn fine coal particles and provide an ignition source and supplementary heat to the fluid bed. The following is a description of the components: air plenum, fine coal injectors, aerovalves, water jacket, and tailpipe inserts.

  1. OTEC support services. Quarterly technical progress report No. 16, 15 February 1982-14 May 1982

    SciTech Connect

    Not Available

    1982-05-01

    Technical progress is reported in the area of OTEC program survey, analysis, evaluation, and recommendation concerning program performance, including OTEC commercialization support and program technical engineering and instrumentation analysis. Progress is also reported in the areas of program technical monitoring, OTEC system integration, and transmission subsystem considerations. Participation in meetings, conferences, etc. is also reported. (LEW)

  2. Development of analytical procedures for coprocessing. Quarterly technical progress report, April 1, 1991--June 30, 1991

    SciTech Connect

    Green, J.B.; Anderson, R.P.

    1991-07-01

    The overall objective of the contract is to improve understanding of the fundamental chemistry of coprocessing. A primary objective is to evaluate methods to distinguish between compound classes originating from coal versus those originating from petroleum resid while a corollary objective is to provide detailed knowledge on the composition of coprocessing products. This and the prior quarterly report summarize work conducted in support of the latter objective in which process development unit samples produced by HRI, Inc. were subjected to detailed analysis. Coprocessing resid samples selected for detailed analysis were made under constant conditions except for variations in coal concentration or in the coal (New Mexico subbituminous or Texas lignite). Separation of the resids into acid, base, saturate, and neutral-aromatic subtractions, separation of the neutral-aromatics by ring number and high temperature gas chromatography were discussed in the previous quarterly. This report includes results of nonaqueous titrations, elemental analyses and infrared spectroscopy. The hydrocarbon skeletons of saturated hydrocarbons in the coprocessing resids appear to be fundamentally different than those of aromatic species. Neutral-aromatic fractions contain minor levels of sulfur compounds, an unknown proportion of ether or other oxygen-containing species, and major concentrations of aromatic hydrocarbons containing from 3 to 7 aromatic rings. Base fractions contain predominantly single nitrogen compounds of azaarene or aminoaromatic type. Aminoaromatics (compounds analogous to aniline) are present in significant amounts in products made from New Mexico subbituminous coal but are nearly absent in the Texas lignite product. Acid fractions contain appreciable quantities of pyrrolic benzologs, but surprisingly low concentrations of compounds with a free OH group.

  3. Damage analysis and fundamental studies. Quarterly progress report, July-September 1980

    SciTech Connect

    Not Available

    1980-11-01

    This report is organized along topical lines in parallel to a Program Plan of the same title so that activities and accomplishments may be followed readily, relative to that Program Plan. Thus, the work of a given laboratory may appear throughout the report. The Table of Contents is annotated for the convenience of the reader.

  4. DEBLICOM: Deaf-Blind Communication & Control Systems: First Quarterly Progress Report.

    ERIC Educational Resources Information Center

    Kafafian, Haig

    Reported on is the first phase of development of DEBLICOM, a code for a two-way communication system for deaf-blind individuals who may be speech-impaired. Brief sections cover the following topics: alternatives to and considerations for the development of cutaneous codes for deaf-blind people; the DEBLICOM system which provides a means of…

  5. Electrostatic beneficiation of coal. Quarterly technical progress report, July 1, 1996--September 30, 1996

    SciTech Connect

    Mazumder, M.K.; Lindquist, D.; Tennal, K.B.

    1996-11-01

    Progress reports are presented for the following tasks: single particle measurement of size and charge; electrodynamic balance for trapping single particles for measurement; and tribocharging of coal particles passed through a circular tube.

  6. OTEC support services. Quarterly technical progress report No. 17, 15 May 1982-14 August 1982

    SciTech Connect

    1982-08-01

    Progress relative to accomplishments and relative to meetings, conferences, etc. are reported in the areas of OTEC commercialization support, program technical engineering and instrumentation analysis, technical and management services, OTEC system integration, and transmission subsystem considerations. (LEW)

  7. OTEC support services. Quarterly technical progress report No. 11, 15 November 1980-14 February 1981

    SciTech Connect

    1981-02-01

    Technical engineering and management support services for the Ocean Thermal Energy Conversion Program are listed along with their objectives. Progress is reported on the following: technical assessments, OTEC system integration, environment and siting considerations, and transmission subsystem considerations. (MHR)

  8. Tunable composite membranes for gas separations. Quarterly technical progress report, May--July 1996

    SciTech Connect

    Ferraris, J.P.; Balkus, K.J. Jr.; Musselman, I.H.

    1996-08-05

    Significant progress has been made in the synthesis and characterization of conducting polymer composite membranes for gas separations. Zeolite/polyalkylthiophene composite membranes have been prepared and characterized for zeolite NaY.

  9. Amarillo National Resource Center for Plutonium. Quarterly technical progress report, May 1, 1997--July 31, 1997

    SciTech Connect

    1997-09-01

    Progress summaries are provided from the Amarillo National Center for Plutonium. Programs include the plutonium information resource center, environment, public health, and safety, education and training, nuclear and other material studies.

  10. Light-water-reactor safety research program. Quarterly progress report, January-March 1980

    SciTech Connect

    Massey, W.E.; Kyger, J.A.

    1980-08-01

    This progress report summarizes the Argonne National Laboratory work performed during January, February, and March 1980 on water-reactor-safety problems. The research and development area covered is Transient Fuel Response and Fission-Product Release.

  11. Geothermal direct-heat utilization assistance. Quarterly project progress report, April--June 1993

    SciTech Connect

    Lienau, P.

    1993-06-01

    Technical assistance was provided to 60 requests from 19 states. R&D progress is reported on: evaluation of lineshaft turbine pump problems, geothermal district heating marketing strategy, and greenhouse peaking analysis. Two presentations and one tour were conducted, and three technical papers were prepared. The Geothermal Progress Monitor reported: USGS Forum on Mineral Resources, Renewable Energy Tax Credits Not Working as Congress Intended, Geothermal Industry Tells House Panel, Newberry Pilot Project, and Low-Temperature Geothermal Resources in Nevada.

  12. ERIP invention 637. Technical progress report 2nd quarter, April 1997--June 1997

    SciTech Connect

    Thacker, G.W.

    1997-07-22

    This technical report describes progress in the development of the Pegasus plow, a stalk and root embedding apparatus. Prototype testing is reported, and includes the addition of precision tillage. Disease data, organic matter, and nitrogen levels results are very briefly described. Progress in marketing is also reported. Current marketing issues include test use by cotton and wheat growers, establishment of dealer relationships, incorporation of design modifications, expansion of marketing activities, and expansion of loan and lease program.

  13. Characterization of air toxics from a laboratory coal-fired combustor and utility scale power plants. Quarterly progress report No. 14, January--March, 1995

    SciTech Connect

    1995-05-01

    This report summarized progress on Task 3, Power Plant Studies, and Task 4, Technical Management and Reporting. Task 3 this quarter involved sampling of flue gas from Units 6 and 7 of the host power plant. The operating parameters during the sampling period are given. Laboratory analyses are in progress. Under Task 4, internal and external QA/QC audits were conducted. A data base management system was prepared. An appendix contains a data compilation of plant operating data.

  14. Low-cost-silicon-process development. Phase IV: process improvement. Second quarterly technical progress report

    SciTech Connect

    Giraudi, R. V.; Newman, C. G.

    1981-04-01

    A number of promising techniques for improving the overall yield and economics of the tribromosilane based process to produce solar cell grade silicon is investigated. The current work is aimed at the identification of an optimum process and the characterization of that process through mini-plant operation and analysis. The three project tasks include process improvement studies, kinetic studies, and process economic studies. During this second quarter reporting period process improvement studies continued in the mini-plant, focusing on the correlation of current mini-plant yield results with prior laboratory scale work. Silicon bromination in the synthesis unit and tribromosilane purification in the distillation unit proceeded efficiently and without complication during this reporting period. Tribromosilane yields in the synthesis unit were low due to unobtainable higher reaction temperatures. Initial polycrystalline silicon production studies have indicated consistent yields of 85%. The laboratory scale static bulb reactor system was calibrated by observing the decomposition of t-butyl chloride. These results compared very well to results obtained by previous investigators for the same decomposition. Upon the conclusion of the calibration tests, the tribromosilane decomposition rate study was initiated. Two decompositions were completed and it was concluded that the reaction order can not be determined at this time. A free space reactor apparatus was assembled and tribromosilane decompositions, as a function of dilution in argon, was studied.

  15. LLNL Underground-Coal-Gasification Project. Quarterly progress report, July-September 1981

    SciTech Connect

    Stephens, D.R.; Clements, W.

    1981-11-09

    We have continued our laboratory studies of forward gasification in small blocks of coal mounted in 55-gal drums. A steam/oxygen mixture is fed into a small hole drilled longitudinally through the center of the block, the coal is ignited near the inlet and burns toward the outlet, and the product gases come off at the outlet. Various diagnostic measurements are made during the course of the burn, and afterward the coal block is split open so that the cavity can be examined. Development work continues on our mathematical model for the small coal block experiments. Preparations for the large block experiments at a coal outcrop in the Tono Basin of Washington State have required steadily increasing effort with the approach of the scheduled starting time for the experiments (Fall 1981). Also in preparation is the deep gasification experiment, Tono 1, planned for another site in the Tono Basin after the large block experiments have been completed. Wrap-up work continues on our previous gasification experiments in Wyoming. Results of the postburn core-drilling program Hoe Creek 3 are presented here. Since 1976 the Soviets have been granted four US patents on various aspects of the underground coal gasification process. These patents are described here, and techniques of special interest are noted. Finally, we include ten abstracts of pertinent LLNL reports and papers completed during the quarter.

  16. Peat biogasification development program. Quarterly progress report No. 4, July 1-September 30, 1980

    SciTech Connect

    Not Available

    1980-10-15

    During this reporting period preliminary data were taken for the kinetic models necessary for a peat biogasification process. A limited number of batch experiments were conducted to obtain rate data for the solubilization kinetic model. The analysis of the pretreatment batch tests was slowed down this quarter because the High Pressure Liquid Chromatography (HPLC) solvent system was altered. This was done because a mass balance around the HPLC with the solvent system (85% H/sub 2/O/15% acetonitrile) was incomplete. The preliminary data indicate that the new solvent system developed seems to be acceptable. Pretreated peat, both oxidized and unoxidized, has been fermented to fuel gas with conversions up to 20%. The fermentation experiments show that oxidation temperature has little effect on anaerobic digestion. Continuous digesters were set up to obtain rate data for the fermentation model. Preliminary process models were developed for the three phases of peat biogasification, namely, solubilization, oxidation, and fermentation. Rate data for the solubilization phase were taken, but more is needed to develop the model further.

  17. Microstructural effects in abrasive wear. Quarterly progress report, September 15-December 15, 1979

    SciTech Connect

    Fiore, N F; Kosel, T H; Channigiri, M; Desai, V; Fulcher, J

    1980-01-15

    This is the 11th quarterly report describing research aimed at establishing quantitative relations between microstructure and wear resistance of highly alloyed materials, including high-Cr white irons and experimental Co-base and Ni-base powder metallurgy (PM) alloys. The specific types of wear under study are low-stress abrasion and gouging wear encountered in mining, coal conversion and transfer applications. The white irons range in carbide volume fracton (v/sub f/) from 10 to 45%. They are of carefully balanced composition to produce maximum carbide hardness, v/sub f/ and matrix hardenability at minimum alloy content. Effort has been devoted to metallographic characterization of these alloys and to low-stress abrasion testing against dry SiO/sub 2/. Low-stress abrasion resistance passes through a maximum at intermediate v/sub f/, a finding which corroborates wet-sand, low-stress test results from another laboratory. Low- and high-matrix alloy content Co-base alloys are also under investigation. Both types of alloys have been processed by powder metallurgy (PM) to display a uniform array of fine, medium or coarse carbides in a FCC matrix. Extensive effort has been expended to develop metallographic procedures for characterizing the microstructures of the alloys. Of particular significance is the development of a one-step electrolytic etching-staining procedure which reveals matrix, matrix grain boundaries and carbides simultaneously in high contrast.

  18. Western Research Institute quarterly technical progress report, July--September 1993

    SciTech Connect

    Not Available

    1993-12-31

    Accomplishments for the quarter are described briefly for the following areas of research: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers process studies. Tar sand research is on recycle oil pyrolysis and extraction (ROPE{sup TM}) Process. Coal research includes: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: CROW{sup TM} field demonstration with Bell Lumber and Pole; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; characterization of petroleum residua; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid state NMR analysis of Mowry formation shale from different sedimentary basins; solid state NMR analysis of naturally and artificially matured kerogens; and development of an effective method for the clean-up of natural gas.

  19. Development of analytical procedures for coprocessing. Quarterly technical progress report, July 1, 1990--September 30, 1990

    SciTech Connect

    Anderson, R.P.

    1991-05-01

    This is the eighth quarterly report under DOE Contract No. DE-AC22-88PC88810, Development of Analytical Procedures for Coprocessing. The overall objective of the contract is to improve our understanding of the fundamental chemistry of coprocessing. This includes the evaluation of methods to distinguish between compound classes originating from coal versus those originating from petroleum resid. Techniques being evaluated include carbon isotope ratios and the variations in compound classes in response to changes in the coal/resid ratio in the feed. A final objective of this project is to provide detailed knowledge on the composition of coprocessing products. This report reviews the use of isotope ratios to determine the source of compound classes (e.g., acids, bases, neutrals, aromatics, saturates, etc.). Selective isotope fractionation is a complicating factor in the use of carbon isotope ratios to determine the source of coprocessing products. Other researchers have shown that through the use of appropriate correction factors to correct for this isotope selectivity, isotope ratios can be used to quantitatively determine the source of coprocessing fractions obtained by distillation. It is concluded in this report that although isotope ratios may provide qualitative information on the source of coprocessing compound classes, that the high degree of isotope selectivity in compound classes originating from a single feed prohibits the quantitative determination of the origin of such compound classes.

  20. Supercritical fluid reactions for coal processing. Quarterly progress report, October 1, 1995--December 31, 1995

    SciTech Connect

    Eckert, C.A.

    1995-12-31

    The goal of this work is to design benign solvent/cosolvent systems for reactions which will achieve optimum desulfurization and/or denitrogenation in the pre-treatment of coal or coal liquids. Supercritical fluids present excellent opportunities for the pre- treatment of coal, hence we shall utilize supercritical fluids (SCF) as a reaction medium. The specific objectives of this work are three fold. The first objective is the quantification of the intermolecular interactions affecting reaction transition states in SCF`s via kinetic measurements using well characterized Diels-Alder reactions. The second objective is the characterization of the thermodynamics of the reacting systems. From the thermodynamics of the reacting species detailed information about the transition state may be determined. The third objective is the development of molecular level mathematical models using the results from the first two objectives. The models shall be developed using both an equation of state approach and linear solvation energy relationships with solvatochromic parameters. During this quarter, the solubility of the nitrogen bearing dienophile 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) has been measured as a function of pressure at 40 C, with the exception of points at 2500 psig and 3000 psig. When collection of these last points has been accomplished, the collection of all preliminary data needed to begin kinetic studies of the Diels-Alder reaction between PTAD and anthracene at 40 C in supercritical CO{sub 2} will be complete.

  1. Supercritical fluid reactions for coal processing. Quarterly progress report, October 1, 1996--December 31, 1996

    SciTech Connect

    Eckert, C.A.

    1994-09-01

    Exciting opportunities exist for the application of supercritical fluid (SCF) reactions for the pre-treatment of coal. Utilizing reactants which resemble the organic nitrogen containing components of coal, we propose to develop a method to tailor chemical reactions in supercritical fluid solvents for the specific application of coal denitrogenation. The Diels - Alder reaction of anthracene and 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) was chosen as the model system and was investigated in supercritical carbon dioxide. During this quarter, measurement of the density dependence of the kinetic rate constant for PTAD and anthracene in supercritical solvents was continued. Having completed studies of rates versus density in pure CO{sub 2} at 40C, attention was focused on CO{sub 2}/Cosolvent mixtures. Experiments were performed using binary mixtures of CO{sub 2} and either chloroform or acetone as cosolvent. Cosolvent concentrations were varied between 0.00826 mol/L and 0.0826 mol/L. The cosolvents produced no significant change in the rate constant over that of pure CO{sub 2} at these concentrations.

  2. Studies of clusters. Fourth quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Farley, J.W.

    1993-08-01

    Positive cluster ions were produced, and the mass spectrum was measured using a radiofrequency quadrupole mass spectrometer. Mass spectra are attached, showing the cluster ions produced using pure ammonia. They have the general formula (NH {sub 3}){sub n}H {sub m}{sup +}, where n and m are integers. Peaks with different numbers of hydrogens can barely be resolved. This shows that the ion source can produce cluster ions. The development of sensitive laser techniques is necessary for probing the clusters. During this quarter, we succeeded in using a weak diode laser was used to probe a bean of negative molecular ion. The work on the visible absorption spectrum of D{sub 2}O{sup +} continues, and is now in the analysis phase. The work on the infrared vibrational -- rotational spectrum of H{sup 15}NO{sup {minus}} continues. In the second ion beam machine, a complete reworking of the voltages has been completed, and is being reassembled.

  3. Oxidation of phenolics in supercritical water. Quarterly technical progress report, September 1, 1993--November 30, 1993

    SciTech Connect

    Savage, P.E.

    1993-12-31

    Oxidation reactions are accomplished in an isothermal, high-pressure, flow reactor designed specifically for operation at supercritical water conditions. The reactor feed stream is prepared by mixing two separate streams. One stream is an aqueous solution of the phenolic reactant and the second stream is water with dissolved oxygen. Controlling the flow rates of these two streams allows us to control the reactor residence time and the relative amounts of the phenol and oxygen fed to the reactor. The reactor effluent is cooled and depressorized and then collected for analysis. The gaseous products are analyzed by gas chromatography (GC). The liquid-phase products are analyzed by GC, high-performance liquid chromatography, and GC-mass spectrometry. Our work to date has focused on the oxidation of cresols in SCW. We have explored the effects of temperature, pressure, and the concentrations of o-cresol, oxygen, and water. Table I gives these experimental conditions and the resulting ocresol conversions. We reported a portion of this data in our previous quarterly report. New information is given in the last three columns where we report the molar yields of phenol, CO{sub 2}, and CO. Molar yields were calculated as the molar flow rate of a given product divided by the initial molar flow rate of o-cresol and normalized by the stoichiometric coefficient. Earlier, we used the o-cresol conversion data to determine the parameters in a global reaction rate law for o-cresol disappearance.

  4. Isobutanol-methanol mixtures from synthesis gas. Quarterly technical progress report, 1 January--31 March 1995

    SciTech Connect

    Iglesia, E.

    1995-04-24

    The contract objectives are: to design a catalytic material for the synthesis of isobutanol with a productivity of 200 g isoalcohols/g-cat-h and a molar isobutanol/methanol ratio near unity; and to develop structure-function rules for the design of catalysts for the selective conversion of synthesis gas to isoalcohols. Several catalyst samples have been prepared by controlled co-precipitation from aqueous mixtures of metal nitrates. The composition of these materials is based on reports of best available catalysts for methanol synthesis, for isobutanol synthesis, and for methanol coupling reactions. The mechanical construction and pressure testing of the microreactor system has been completed. The in-situ infrared spectrophotometer equipped with a nitrogen purge is fully operational. The temperature-programmed surface reaction (TPSR) unit has been designed; construction will begin during the third quarter FY`95. Air Products and Chemicals has provided us with a sample of a BASF isobutanol synthesis catalyst and with catalytic data obtained on this catalyst in a LaPorte test run. This catalyst will serve as a benchmark for the certification of our new microreactor system.

  5. PEPCO turbo-Z battery charger system. Technical progress report, calendar quarter ending March 31, 1998

    SciTech Connect

    Rose, J.

    1998-04-30

    During the First Quarter of 1998, the engineers working on this Grant have dramatically increased the rate of work. They are developing a Flexible Battery Charger Control Board, a Battery Charger Test Stand, and writing software that can be used with both. The status is as follows: (a) Flexible Battery Charger Control Board -- a preliminary electrical design is complete. They are now investigating how the control design might incorporate provisions for an additional Electric Vehicle charging feature. This additional design is based on SAE J2293 -- Recommended Practice for EV Communications. Investigation of J2293 is being considered for controlling a power supply using proprietary Capacitive Charging Coupler, and controlling the power supply with this control board. (b) Battery Test Stand -- the preliminary hardware design is complete. The design includes some very desirable additions to the specifications, including an AC line source for the charger being tested and a battery simulator. Purchasing of the equipment and materials for the test stand is underway. The engineers have been working in the SAE standards setting committees for Electric Vehicles for several years. In particular, they have been working to set the Capacitive Coupler as the standard for connecting an EV to the utility grid system. Substantial test data has been distributed to the committee members on the Conductive and Inductive Charging Systems. It is their opinion that they have a superior coupling mechanism, and they are proceeding to develop this technology.

  6. Gypsy Field project in reservoir characterization. Quarterly progress report, May 19--September 30, 1994

    SciTech Connect

    O`Meara, D.J. Jr.

    1994-12-31

    The overall objective of this project is to use the extensive Gypsy Field laboratory and data set as a focus for developing and testing reservoir characterization methods that are targeted at improved recovery of conventional oil. The Gypsy Field laboratory consists of coupled outcrop and subsurface sites which have been characterized to a degree of detail not possible in a production operation. Data from these sites entail geological descriptions, core measurements, well logs, vertical seismic surveys, a 3D seismic survey, crosswell seismic surveys, and pressure transient well tests. The overall project consists of four interdisciplinary sub-projects which are closely interlinked: Modeling deposition environments; Integrated 3D seismic interpretation; Sweep Efficiency; and Tracer testing. During this quarter, main activities involved three sub-projects: Modeling Depositional Environments. The use of thin-plate and tension splines for detecting discontinuities in geological or petrophysical properties was examined. In an example derived from the Gypsy outcrop, tension splines were clearly superior. Integrated 3D Seismic Interpretation. A three-dimensional geological model of the Gypsy subsurface site has been constructed using 3D seismic data, constrained by well log and core data. Eight seismic horizons were mapped based on seismic data yielding geometrical information on major sand and shale zones. Sweep Efficiency. As a first step in examining the cubature method as an alternative to IMPES schemes, the equations and a numerical scheme have been formulated for two-dimensional flow in heterogeneous reservoirs. Development has begun on a computer program for implementing this numerical scheme.

  7. Stable carbon isotope analysis of coprocessing materials: Quarterly technical progress report, October 1--December 31, 1988

    SciTech Connect

    Burke, F.P.; Winschel, R.A.; Lancet, M.S.

    1989-03-01

    Consol R and D will develop and demonstrate stable carbon isotope analysis as a method to quantitatively distinguish coal-derived and petroleum-derived carbon in products from coal/petroleum coprocessing. The approach taken will be to develop the method, then demonstrate its application on authentic continuous-unit products. The significance of selective isotopic fractionation will be determined and, if necessary, corrections will be applied to account for it. Precision, accuracy and range of applicability will be defined. The value of accessory analytical techniques will also be assessed. Results achieved this quarter include: feed and product fractions from hydroprocessing bench unit runs at the Kentucky Center for Applied Energy Research (CAER) were received, and samples from a Kentucky tar sand bitumen-only run were analyzed for carbon isotope ratios. Repeat carbon isotope analyses of seven samples from HRI Coprocessing Run 227-53 resulted in improved carbon balances for one run period. Athabasca ASB, Cold Lake ASB and Maya ASB were fractionated by distillation and solubility fractionation to determine the homogeneity of each petroleum with respect to carbon isotope ratios. 9 figs., 2 tabs.

  8. Separation of flue-gas scrubber sludge into marketable products. Third year, second quarterly technical progress report, December 1, 1995--February 29, 1996 (Quarter {number_sign}10)

    SciTech Connect

    Kawatra, S.K.; Eisele, T.C.

    1996-03-01

    To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of. Knowledge of scrubber sludge characteristics is necessary for the development of purification technologies which will make it possible to directly utilize scrubber sludges rather than landfilling them. This project is studying the use of minimal-reagent froth flotation as the purification process, using the surface properties of the particles of unreacted limestone to remove them and their associated impurities from the material, leaving a purified calcium sulfite/gypsum product. In the current quarter, research was focused on two different areas. The first part of this quarter the optimization of the feed slurry percent solids for the two inch water-only cyclone was completed. The optimization of the vortex finder, spigot diameter and inlet feed pressure was completed in the previous quarter. The second part of this quarter began the investigation of why water-only cycloning helps froth flotation performance. The hypothesis is that water-only cycloning scrubs the surface of the unreacted limestone. This scrubbing effect provides a clean calcium carbonate surface, which results in better flotation reagent adsorption. This study used the scanning electron microscope to investigate the surface of the unreacted limestone particles.

  9. The Relationship between Types of Paragraphs and Topic Progression Used in Paragraphs Written by Iranian EFL Students

    ERIC Educational Resources Information Center

    Ghabanchi, Zargham; Alavi, Sahar Zahed

    2011-01-01

    Using Lautmatti's (1978) framework, this study examines the types of topic progression techniques used in 120 paragraphs written by 40 Iranian undergraduate students. Each student was asked to write three types of paragraphs; namely, those of comparison and contrast, cause-effect, and chronology. The present study investigates the relationship…

  10. The Relationship between Types of Paragraphs and Topic Progression Used in Paragraphs Written by Iranian EFL Students

    ERIC Educational Resources Information Center

    Ghabanchi, Zargham; Alavi, Sahar Zahed

    2011-01-01

    Using Lautmatti's (1978) framework, this study examines the types of topic progression techniques used in 120 paragraphs written by 40 Iranian undergraduate students. Each student was asked to write three types of paragraphs; namely, those of comparison and contrast, cause-effect, and chronology. The present study investigates the relationship…

  11. Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, April 1993--June 1993

    SciTech Connect

    Not Available

    1993-08-01

    Section 1 contains a report of the progress by the University of Kentucky Center for Applied Energy Research on the following tasks: laboratory support (liquefaction in dewaxed and hydrotreated dewaxed solvent); CO pretreatment (effect of process variables on CO pretreatment, CO-pretreated product characterization, and liquefaction results); and iron based dispersed catalysts (production, characterization and testing of sulfated hematites and reaction model development). Section 2 contains a progress report by CONSOL, Inc. on the following tasks: laboratory support; pretreatment work on dewaxing; pretreatment work on agglomeration; and economic evaluation. Progress by Sandia National Laboratories is reported in Section 3 on the following: laboratory support (TGA methods) and solvent pretreatment (coker tar hydrogenation and coal liquefaction results). Section 4 gives a preliminary technical assessment by LDP Associates on the following: baseline economic assessment; assessment of improved coal conversion; and fluid coking.

  12. Geothermal direct-heat utilization assistance. Quarterly project progress report, October--December 1993

    SciTech Connect

    Not Available

    1993-12-31

    This report consists of brief summaries of the activities of the Geo-Heat Center during the report period. Technical assistance was given to requests from 20 states in the following applications: space and district heating; geothermal heat pumps; greenhouses; aquaculture; industrial plants; electric power; resource/well; equipment; and resort/spa. Research and development activities progressed on (1) compilation of data on low-temperature resources and (2) evaluation of groundwater vs. ground-coupled heat pumps. Also summarized are technology transfer activities and geothermal progress monitoring activities.

  13. Amarillo National Resource Center for Plutonium. Quarterly technical progress report, November 1, 1997--January 31, 1998

    SciTech Connect

    1998-03-01

    This report provides information on projects conducted by the Amarillo National Resource Center for Plutonium, a consortium of Texas A&M University, Texas Tech University, and the University of Texas. Progress is reported for four major areas: (1) plutonium information resource; (2) environmental, safety, and health; (3) communication, education, training, and community involvement; and (4) nuclear and other material studies. Environmental, safety, and health projects reported include a number of studies on high explosives. Progress reported for nuclear material studies includes storage and waste disposal investigations.

  14. Bioconversion of coal derived synthesis gas to liquid fuels. Quarterly technical progress report, 1 April--30 June 1994

    SciTech Connect

    Jain, M.K.; Worden, R.M.; Grethlein, A.

    1994-07-18

    The overall objective of the project is to develop an integrated two-stage fermentation process for conversion of coal-derived synthesis gas to a mixture of alcohols. This is achieved in two steps. In the first step, Butyribacterium methylotrophicum converts carbon monoxide (CO) to butyric and acetic acids. Subsequent fermentation of the acids by Clostridium acetobutylicum leads to the production of butanol and ethanol. The tasks for this quarter were: development/isolation of superior strains for fermentation of syngas; evaluation of bioreactor configuration for improved mass transfer of syngas; recovery of carbon and electrons from H{sub 2}-CO{sub 2}; initiation of pervaporation for recovery of solvents; and selection of solid support material for trickle-bed fermentation. Technical progress included the following. Butyrate production was enhanced during H{sub 2}/CO{sub 2} (50/50) batch fermentation. Isolation of CO-utilizing anaerobic strains is in progress. Pressure (15 psig) fermentation was evaluated as a means of increasing CO availability. Polyurethane foam packing material was selected for trickle bed solid support. Cell recycle fermentation on syngas operated for 3 months. Acetate was the primary product at pH 6.8. Trickle bed and gas lift fermentor designs were modified after initial water testing. Pervaporation system was constructed. No alcohol selectivity was shown with the existing membranes during initial start-up.

  15. Alloy development for irradiation performance. Quarterly progress report for period ending March 31, 1980

    SciTech Connect

    Ashdown, B.G.

    1980-06-01

    This report is organized along topical lines in parallel to a Program Plan of the same title so that activities and accomplishments may be followed readily relative to that Program Plan. Thus, the work of a given laboratory may appear throughout the report. Chapters 1, 2, 8, and 9 review activities on analysis and evaluation, test methods development, status of irradiation experiments, and corrosion testing and hydrogen permeation studies, respectively. These activities relate to each of the alloy development paths. Chapters 3, 4, 5, 6, and 7 present the ongoing work on each alloy development path. The Table of Contents is annotated for the convenience of the reader.

  16. Alloy development for irradiation performance. Quarterly progress report for period ending September 30, 1980

    SciTech Connect

    Not Available

    1980-12-01

    This report is organized along topical lines in parallel to a Program Plan of the same title so that activities and accomplishments may be followed readily relative to that Program Plan. Thus, the work of a given laboratory may appear throughout the report. Chapters 1, 2, 8, and 9 review activities on analysis and evaluation, test methods development, status of irradiation experiments, and corrosion testing and hydrogen permeation studies, respectively. These activities relate to each of the alloy development paths. Chapters 3, 4, 5, 6, and 7 present the ongoing work on each alloy development path. The Table of Contents is annotated for the convenience of the reader.

  17. Alloy development for irradiation performance. Quarterly progress report for period ending June 30, 1980

    SciTech Connect

    Ashdown, B.G.

    1980-10-01

    This report is organized along topical lines in parallel to a Program Plan of the same title so that activities and accomplishments may be followed readily relative to that Program Plan. Thus, the work of a given laboratory may appear throughout the report. Chapters 1, 2, 8, and 9 review activities on analysis and evaluation, test methods development, status of irradiation experiments, and corrosion testing and hydrogen permeation studies, respectively. These activities relate to each of the alloy development paths. Chapters 3, 4, 5, 6, and 7 present the ongoing work on each alloy development path. The Table of Contents is annotated for the convenience of the reader.

  18. LANL Q2 2016 Quarterly Progress Report. Science Campaign and ICF

    SciTech Connect

    Douglas, Melissa Rae

    2016-04-07

    This progress report includes highlights for the Science Campaign and ICF about Advanced Certification and Assessment Methodologies, Implosion Hydrodynamics (C-1, SCE), Materials and Nuclear Science (C-1, C-2), Capabilities for Nuclear Intelligence, and High Energy Density Science (C-1, C-4, C-10). Upcoming meetings, briefings, and experiments are then listed for April and May.

  19. Responsive copolymers for enhanced petroleum recovery. Quarterly technical progress report, September 22, 1992--December 22, 1992

    SciTech Connect

    McCormick, C.; Hester, R.

    1992-12-31

    The overall goal of this research is the development of advanced water-soluble copolymers for use in enhanced oil recovery which rely on reversible microheterogeneous associations for mobility control and reservoir conformance. Technical progress is summarized for the following tasks: advanced copolymer synthesis; characterization of macromolecular structure and properties; and solution rheology in a porous media.

  20. Great Basin paleoenvironmental studies project; Technical progress report: First quarter (January--August 1993)

    SciTech Connect

    1993-12-31

    Project goals, project tasks, progress on tasks, and problems encountered are described and discussed for each of the studies that make up the Great Basin Paleoenvironmental Studies Project for Yucca Mountain. These studies are: Paleobotany, Paleofauna, Geomorphology, and Transportation. Budget summaries are also given for each of the studies and for the overall project.

  1. Geothermal Drilling and Completion Technology Development Program. Quarterly progress report, October 1980-December 1980

    SciTech Connect

    Kelsey, J.R.

    1981-03-01

    The progress, status, and results of ongoing Research and Development (R and D) within the Geothermal Drilling and Completion Technology Development Program are described. The program emphasizes the development of geothermal drilling hardware, drilling fluids, completion technology, and lost circulation control methods. Advanced drilling systems are also under development.

  2. Electrostatic beneficiation of coal. Quarterly technical progress report, April 1, 1996--June 30, 1996

    SciTech Connect

    Mazumder, M.K.; Lindquist, D.; Tennal, K.B.

    1996-07-01

    Progress reports are presented for the following: modification to the electrostatic separator; review of DOE specifications for minimum beneficiation and calculations of grinding requirements based on washability; two-pass beneficiation; analysis of different sieve fractions; measurement of charge to mass ratio as a function of height of deposition; and charging of coal against different materials.

  3. Geothermal Drilling and Completion Technology Development Program. Quarterly progress report, January 1981-March 1981

    SciTech Connect

    Kelsey, J.R.

    1981-06-01

    The progress, status, and results of ongoing Research and Development (R and D) within the Geothermal Drilling and Completion Technology Development Program are described. The program emphasizes the development of geothermal drilling hardware, drilling fluids, completion technology, and lost circulation control methods as they apply to advanced drilling systems.

  4. Evaluation of geothermal energy in Arizona. Quarterly progress report, July 1-September 30, 1981

    SciTech Connect

    White, D.H.; Goldstone, L.A.

    1981-01-01

    Progress is reported on the following: legislative and institutional program, cities program, geothermal applications utilization technology, integrated alcohol/feedlot/geothermal operation, geothermal energy in the mining industry, geothermal space heating and cooling, identification of a suitable industry for a remote geothermal site, irrigation pumping, coal-fired/geothermal-assisted power plants, area development plans, and outreach. (MHR)

  5. Amarillo National Resource Center for Plutonium. Quarterly technical progress report, May 1--July 31, 1998

    SciTech Connect

    1998-09-01

    Progress is reported on research projects related to the following: Electronic resource library; Environment, safety, and health; Communication, education, training, and community involvement; Nuclear and other materials; and Reporting, evaluation, monitoring, and administration. Technical studies investigate remedial action of high explosives-contaminated lands, radioactive waste management, nondestructive assay methods, and plutonium processing, handling, and storage.

  6. Alloy development for irradiation performance. Quarterly progress report for period ending December 31, 1980

    SciTech Connect

    Not Available

    1981-04-01

    Progress is reported in eight sections: analysis and evaluation studies, test matrices and test methods development, Path A Alloy Development (austenitic stainless steels), Path C Alloy Development (Ti and V alloys), Path D Alloy Development (Fe alloys), Path E Alloy Development (ferritic steels), irradiation experiments and materials inventory, and materials compatibility and hydrogen permeation studies. (DLC)

  7. Responsive copolymers for enhanced petroleum recovery. Quarterly technical progress report, December 22, 1992--March 21, 1993

    SciTech Connect

    Hester, R.; McCormick, C.

    1993-06-01

    The overall objective of this research is the development of advanced water-soluble copolymers for use in enhanced oil recovery which rely on reversible microheterogeneous associations for mobility control and reservoir conformance. Technical progress is summarized for the following tasks: advanced copolymer synthesis; characterization of molecular structure; and solution rheology.

  8. OTEC support services. Quarterly technical progress report No. 21, 15 May-15 August 1983

    SciTech Connect

    Not Available

    1983-09-01

    Progress is reported on the system integration, system engineering, and management services for the OTEC program under the following tasks: (1) survey, analysis, and evaluation; (2) program technical monitoring; (3) development and implementation of methodology; (4) technical assessments; (5) OTEC systems integration; (6) environment and siting considerations; and (7) transmission subsystem considerations.

  9. OTEC support services. Quarterly technical progress report No. 18, 15 August 1982-14 November 1982

    SciTech Connect

    Not Available

    1982-11-01

    After a brief description of the technical engineering and management support services for the OTEC Program and of the task objectives, technical progress is reported in the areas of: survey, analysis, and evaluation; program technical monitoring; and transmission subsystem subsytem considerations. (LEW)

  10. OTEC support services quarterly technical progress report No. 14, 15 August 1981-14 November 1981

    SciTech Connect

    1981-11-01

    The progress in the areas of system integration, system engineering, and management services is reported. The effort is divided into seven tasks: survey, analysis, and evaluation of technical program status; program technical monitoring; development and implementation of methodology for identification, evaluation, and trade-off for major subsystem configurations; technical assessments; OTEC system integration; environment and siting considerations; and transmission subsystem considerations. (LEW)

  11. Performance Plan: Progress Report 4th Quarter Fiscal Year 2000. Student Financial Assistance.

    ERIC Educational Resources Information Center

    Office of Student Financial Assistance (ED), Washington, DC.

    This is the final report on the fiscal year of Student Financial Assistance (SFA). It reports on progress toward three objectives: (1) customer satisfaction; (2) reducing the overall cost of delivering student aid; and (3) employee satisfaction. Of the planned projects, SFA completed all but three. One was postponed, one was dropped as not cost…

  12. Alloy development for irradiation performance. Quarterly progress report for period ending December 31, 1979

    SciTech Connect

    Ashdown, B.G.

    1980-04-01

    Progress is reported concerning preparation of a materials handbook for fusion, creep-fatigue of first-wall structural materials, test results on miniature compact tension fracture toughness specimens, austenitic stainless steels, Fe-Ni-Cr alloys, iron-base alloys with long-range crystal structure, ferritic steels, irradiation experiments, corrosion testing, and hydrogen permeation studies. (FS)

  13. Use of gamma radiation as a form of preservation of sweet potatoes. Quarterly progress report

    SciTech Connect

    Not Available

    1985-01-01

    This progress report covers: harvest and conditioning following harvest; effects of ..gamma.. radiation on the sweet potato weevil, organoleptic properties of sweet potatoes, protein content of same, and sweet potato quality (vitamins, color, texture, and carbohydrates). Evaluation of preliminary results indicate that changes should be made in irradiation procedures/conditions and analyses. (DLC)

  14. Interim Performance Objectives. Progress Report, 3rd Quarter Fiscal Year 1999.

    ERIC Educational Resources Information Center

    Office of Student Financial Assistance (ED), Washington, DC.

    This document contains a progress report on three categories of interim performance objectives outlined by the Office of Student Financial Assistance (OSFA) in winter 1999. These objectives were to: (1) improve customer service; (2) reduce the overall cost of delivering student aid; and (3) transform the OSFA into a performance-based organization.…

  15. Development of high efficiency cascade solar cells. Quarterly technical progress report No. 3

    SciTech Connect

    Not Available

    1980-03-31

    Progress is reported in the following areas: AlGaAsSb/GaAsSb materials development, GaInP materials development via VPE, GaAlAs/GaAs cell development, and OM/CVD studies. Spectral response, V-I characteristics, and electron microprobe analysis results are presented. (WHK)

  16. Electrochemical photovoltaic cells. Project 65021 quarterly technical progress report, October 15, 1979-January 15, 1980

    SciTech Connect

    Ang, P.G.P.; Remick, R.J.; Sammells, A.F.

    1980-03-01

    During the third quarter of this program, liquid junction devices based upon the semiconductors MoSe/sub 2/, MoS/sub 2/, GaAs, and CdSe have been evaluated. Lifetime testing of MoSe/sub 2/ and MoS/sub 2/ materials in acidic halogen electrolytes at constant current densities of 5 mA/cm/sup 2/ have shown excellent stability to date. For MoSe/sub 2/ single crystals in the electrolyte 1M HBr + 1M Br/sub 2/, short-circuit currents of 63 mA/cm/sup 2/ were achieved with a power conversion efficiency of 6.7% for 200 mW/cm/sup 2/ xenon light illumination. Transient potentiostatic measurements made on MoSe/sub 2/ in this electrolyte indicated little diffusion control, with exchange currents being of the order of 1 to 10 mA/cm/sup 2/. Good photoresponse of MoS/sub 2/ has been observed in 1M HBr + 1M Br/sub 2/. The performance of the natural crystal is comparable to the performance of a single-crystal MoS/sub 2/ in this electrolyte. CdSe thermally evaporated onto porous titanium gave efficiencies of about 4% with 100 mW/cm/sup 2/ xenon illumination. Experimental work was initiated on the dye sensitization of Fe/sub 2/O/sub 3/ and TiO/sub 2/ materials. Of the twelve dyes evaluated, little enhancement of the photoresponse of these materials was noted. Solid-state photoelectrochemical cells have been fabricated, based upon LiI. Cells of the configuration - cond. glass CdSe/LiI + PbI/sub 2//LiI/LiI + C + PbI/sub 2//cond. glass - were fabricated. Photoresponses up to 150 mV were observed.

  17. Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, October 1993--December 1993

    SciTech Connect

    Not Available

    1994-02-01

    Several promising leads that have developed during the course of this program are being evaluated in this phase of the study. These have been selected from those that can be economically evaluated within the time constraints of the program schedule. A detailed plan for evaluating these approaches was formulated. The individual steps that will be evaluated are: (1) Dewaxing of the distillate recycle solvent stream treating either 25% or 100% of the stream. (2) Hydrotreating the dewaxed distillate streams in a downflow fixed bed reactor. (3) Agglomerating the coal using both the 25% and 100% dewaxed-hydrotreated distillate streams. (4) Liquefying the as-received coal and the agglomerated coals using two different Mo-promoted hematite particulate catalysts. (5) Liquefying two different Mo-Fe impregnated coals. (6) Liquefying the two off-agglomerated, Mo-Fe impregnated coals. The effect of the presence of molybdenum in the 1050{degrees}F{sup +} will be determined by making comparisons in both Mo-containing and Mo-free full range V-131B process solvent. The solvents that will be used in this study are the full-range reconstituted Mo-containing V-131B from Run 262E and a Mo-free V-131B made up of 1050{degrees}F{sup +} bottoms from Run 258K V-131B and V-1074 distillate from Run 262E. The series of experiments are described and a chart has been prepared summarizing this series of runs. The plan requires significant exchange of samples between the different participants in the program with the schedule timed for providing the data for economic evaluation within the next quarterly reporting period.

  18. Electric and Hybrid Vehicle Program; Site Operator Program. Quarterly progress report, October--December 1991

    SciTech Connect

    Warren, J.F.

    1992-01-01

    Activities during the first quarter centered around integrating the new participants into the program. A meeting of the Site Operators, in conjunction with the first meeting of the Electric Vehicle Users Task Force, was held in October. A second meeting of the Task Force was held in December. During these meetings the new contractual requirements were explained to the participants. The Site Operator Data Base was distributed and explained. The Site Operators will begin using the data base in December 1991 and will supply the operating and maintenance data to the INEL on a monthly basis. The Operators requested that they be able to have access to the data of the other Operators and it was agreed that they would be provided this on floppy disk monthly from the INEL. Presentations were made to the DOE sponsored Automotive Technology Development-Contractors Coordination Meeting in October. An overview of the program was given by EG&G. Representatives from Arizona Public Service, Texas A&M University, and York Technical College provided details of their programs and the results and future goals. Work was begun on commercializing the Versatile Data Acquisition System (VDAS). A Scope of Work has been written for a Cooperative Research and Development Agreement (CRADA) to be submitted to the USABC. If implemented, the CRADA will provide funds for the development and commercialization of the VDAS. Participants in the Site Operator Program will test prototypes of the system within their fleets, making the data available to the USABC and other interested organizations. The USABC will provide recommendations on the data to be collected. Major activities by the majority of the Operators were involved with the continued operation and demonstration of existing vehicles. In addition, several of the operators were involved in identifying and locating vehicles to be added to their fleets. A list of the vehicles in each Site Operator fleet is included as Appendix A to this report.

  19. (Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending December 31, 1985

    SciTech Connect

    Not Available

    1986-10-01

    Microbial desulfurization is the use of ''bugs'' to remove sulfur from coal. Four projects illustrate the variety of ways in which microbes can be used to desulfurize coal. In the liquefaction program area, a joint effort between PETC and Catalytic, Inc., was established for process-modeling studies of two-stage coal liquefaction experiments at Wilsonville. Researchers at PETC have developed a process model for Integrated Two-Stage Liquefaction and are currently focusing on characterization of an engineering (ASPEN Public) simulator. The goal of this work is to establish realistic process performance indices for different reactor configurations and coal feedstocks based on heat and material balance calculations. In another liquefaction research effort this quarter, Hydrocarbon Research, Inc., started the first bench run under its new contract for research on low-severity, two-stage liquefaction. The run is planned for 29 days and will test nine separate operating conditions. Research in the field of magnetohydrodynamics (MHD) continued at the Avco Everett Research Laboratory (AERL). A significant achievement fiscal year was the first-time operation of the Avco MK VIII channel with the total power controlled and/or consolidated using nonresistive circuitry. An electrostatic precipitator (ESP) was delivered, installed, and tested at the DOE's MHD Coal-Fired Flow Facility at the University of Tennessee Space Institute. Shakedown tests of PETC's Continuous Life-Cycle Copper Oxide Test Facility are complete. This PETC facility will be used to conduct the first integrated process tests of the Fluidized-Bed Copper Oxide Process unit for the control of SO/sub 2/ and NO/sub x/. PETC has recently initiated a project to study the fundamental properties of coal surfaces by measuring the heat of immersion of coal and its associated mineral matter using a Setaram C-80 heat flow calorimeter.

  20. Development of analytical procedures for coprocessing. Quarterly technical progress report, January 1, 1991--March 31, 1991

    SciTech Connect

    Anderson, R.P.

    1991-06-01

    This is the tenth quarterly report under DOE Contract No. DE-AC22-88PC88810, Development of Analytical Procedures for Coprocessing. The overall objective of the contract is to improve understanding of the fundamental chemistry of coprocessing. A primary objective is to evaluate methods to distinguish between compound classes originating from coal versus those originating from petroleum resid while a corollary objective is to provide detailed knowledge on the composition of coprocessing products. This report summarizes work conducted in support of the latter objective in which process development unit samples produced by HRI, Inc. are being subjected to detailed analysis. Coprocessing resid samples selected for detailed analysis were made under constant conditions except for variations in coal concentration or in the coal (New Mexico subbituminous or Texas lignite). The soluble material was separated into strong and weak acids, strong and weak bases, and neutrals. The predominant fraction from the ABN separations was the neutral fraction (67-81%). All of the polar fractions increase with increasing coal concentration. The concentration of saturates in the neutrals is high in a run with 33% subbituminous coal but drops substantially with either increasing coal concentration or the substitution of lignite for subbituminous coal. High temperature gas chromatography showed that both the neutral aromatics fractions and saturates fractions from all of the runs are extremely similar regardless of the coal concentration or coal type. The neutral aromatics fractions were further separated by ring number separation. Chromatograms were again very similar regardless of the initial coal concentration or coal type with most material eluting in the 3-ring to 6-ring region.

  1. (Pittsburgh Energy Technology Center): Quarterly technical progress report, period ending September 30, 1986

    SciTech Connect

    Not Available

    1986-01-01

    Among the major energy technology milestones was the selection of nine projects by the US DOE that will demonstrate innovative clean coal technologies under the nearly $400 million first phase of the Clean Coal Technology Program. Four of the projects, which are to be cost-shared by private industry, were assigned to PETC for negotiation and management. A DOE contractor, the Union Carbide Corp., has filed three patent applications for the development of Fischer-Tropsch catalysts. The improvements in synthesis gas conversion technology resulting from these inventions include lower methane production, increased yield of non-gaseous products; higher yield of olefins; improved levels of single-pass, synthesis gas conversion; and greater catalyst stability. A major impetus this quarter was in flue gas cleanup technology that seeks to develop low-cost options for controlling pollutants produced from coal combustion. As part of an experimental program to study the direct injection of sorbent into a duct for combined SO/sub 2//NO/sub x/ removal, researchers at the University of Tennessee Space Institute characterized the hydrodynamics of the injection process. Nearly all of the design work was completed for the first part of General Electric's Environmental Services Division's contract that involves the design and construction of a 12-MW proof-of-concept plant to test SO/sub 2/ removal by spraying a sorbent directly into the flue gas contained in a duct. Researchers at PETC are investigating a technique called explosive comminution, or shattering of the coal into very small bits, to produce a premium low-ash, low-sulfur solid fuel. Significant milestones were achieved in PETC's MHD.

  2. Direct catalytic decomposition of nitric oxide. Quarterly technical progress report No. 10, January--March 1994

    SciTech Connect

    Flytzani-Stephanopoulos, M.; Sarofim, A.F.; Zhang, Y.; Sun, T.

    1994-06-01

    This project investigates a suitable catalyst system for the direct nitric oxide decomposition in post-combustion gas streams. This process does not use a reductant, such as the ammonia used in the Selective Catalytic Reduction (SCR) of NO{sub x} to nitrogen. Therefore, it is a greatly simplified process basically involving passing the flue gas through a catalytic converter. Catalysts are prepared by incorporating metal cations into zeolite supports according to ion exchange procedures widely used in preparation of metal/zeolite catalysts. Particular emphasis is given in this work on promoted Cu-exchanged zeolites, especially the catalyst systems Mg/Cu-ZSM-5 and Ce/Cu-ZSM-5, which are promising for NO conversion to nitrogen at typical flue gas O{sub 2} and NO levels and over the temperature range of 673--873{degrees}C. The effect of zeolite modification, copper exchange level and catalyst preparation conditions on the catalytic activity are studied in O{sub 2}-free, O{sub 2}-rich gases, as well as wet (2--20% H{sub 2}O) gas streams in a packed-bed microreactor. Characterization of catalysts is performed by XRD, STEM, TEM and ESR. During this quarter it was found that severe steaming (20% H{sub 2}O) of Na-ZSM-5 at temperatures above 600{degrees}C caused partial vitreous glass formation and dealumination. Unpromoted Cu-ZSM-5 catalysts suffer drastic loss of NO decomposition activity in wet gas streams at 500{degrees}C. Activity is partially recovered in dry gas. Copper migration out of the zeolite channels leading to CuO formation has been identified by STEM/EDX. In Ce/Cu-ZSM-5 catalysts the wet gas activity i`s greatly improved. CuO particle formation is less extensive and the dry gas activity is largely recovered upon removal of the water vapor.

  3. MHD Integrated Topping Cycle Project. Fifteenth quarterly technical progress report, February 1991--April 1991

    SciTech Connect

    Not Available

    1992-02-01

    A summary of the work is excerpted here. Final design of an MHD channel for the ITC program POC test has been completed. The channel was designed to be capable of 1.5 MW {sub e} power output and a lifetime of 2000 hours. Emphasis was placed upon durability and reliability. Hence, specific measures were taken to design against channel damage due to electric faults. The life-limiting issues associated with electrochemical corrosion and erosion of gas-side surfaces were addressed by the use of various materials with proven wear characteristics in a coal-fired MHD channel environment. Pitting of prototypical sidewall coupons was observed in the CDIF workhorse testing. The most likely cause of the observed pitting, water leaks resulting from cooling water tube braze failures, has been remedied. New brazing procedures and isolation of the sidebar gas-side material from water contact will prevent sidebar pitting in the prototypical channel. Water-side corrosion tests reported in this quarterly report include the latest results of tungsten-copper elements at controlled pH, heat flux and voltage levels. In the combustion subsystem, efforts continued to focus on understanding and improving the current levels of slag recovery and seed utilization achieved by the combustor. Analytical support was also provided in the areas of slag rejection system operation, precombustor operation, and oil burner design modification. Channel data analysis activities continued in support of prototypical coupon testing at the CDIF. Analyses are presented on channel wall slagging behavior and sidewall voltage distributions.

  4. Quarterly technical progress report for the period ending June 30, 1984

    SciTech Connect

    Not Available

    1984-10-01

    The Magnetohydrodynamics Program (Component Development and Integration Facility) in Butte, Montana, continued its site preparation for the TRW first-stage combustor installation. In the area of flue gas cleanup, our in-house research program is continuing its investigation into the causes of sorbent attrition in PETC's fluidized-bed copper oxide process for simultaneous SO/sub 2//NO/sub x/ removal. Interwoven with these tests is a series of spray dryer/electrostatic precipitator tests that are being conducted with the cooperation of Wheelabrator-Frye, Inc. This test series was completed this quarter, and the data show that when using a Kentucky coal, Wheelabrator-Frye's electrostatic precipitator provides excellent particulate control efficiency while using a spray dryer for sulfur dioxide removal. A unique project at Carnegie-Mellon University is looking at the concept of integrated environmental control for coal-fired power plants making use of precombustion, combustion, and postcombustion control, including systems for the simultaneous removal of more than one pollutant. The objective of this research is to develop a computer model and assessment for integrated environmental control systems that utilize conventional or advanced systems. The Liquid Phase Methanol Project Development Unit in LaPorte, Texas, was restarted after a successful shakedown run was completed. PETC has recently begun an in-house research project aimed at exploring the basic chemistry of liquefying coal in the presence of water under supercritical conditions. In the Alternative Fuels Technology Program, the Gulf Research and Development Company has completed the preliminary testing phase of its erosion test loop. Their results indicate that when pumping a coal-water slurry fuel through a flow loop, the erosion rate increases as velocity increases, suggesting a well-defined relationship between these two parameters.

  5. Low cost solar array project. Quarterly progress report, January-March, 1981

    SciTech Connect

    Not Available

    1981-01-01

    The engineering design, fabrication, assembly, operation, economic analysis, and process support R and D for an Experimental Process System Development Unit (EPSDU) are presented. The civil construction work was completed and the mechanical bid package is in preparation. The electrical design effort is in progress. Parallel efforts which complement the mechanical design are the process flow diagrams and control instrumentation logic for startup operation and shutdown. These are in progress and will identify all process and utility streams, control systems, and flow logic. The data collection system takes the signals from the instrumentation, translates them into engineering units and finally develops a data report which summarizes all key performance parameters. Cleaning procedures have been established to assure a contamination-free product and inspection visits have been made to the fabricators of specialty equipment.

  6. Chemical Engineering Division Fuel Cycle Programs. Quarterly progress report, October-December 1981

    SciTech Connect

    Steindler, M.J.; Bates, J.K.; Cannon, T.F.

    1982-05-01

    Methods of measuring rates of leaching from simulated waste glasses using neutron activation analysis and radiotracers have been developed. Laboratory-scale impact tests of solid alternative waste forms are being performed to obtain a size analysis of the fragments. Logging techniques are being developed to measure the relative amount of residual oil in a depleted oil reservoir by injecting gamma-active solution into it. Work to test the behavior of radionuclides leached from proposed nuclear-waste repositories using laboratory-analog experiments is in progress. High potassium levels in crushed granite from a Northern Illinois drill hole are probably derived by the leaching of potassium feldspar. Testing and development of equipment for the destructive analysis of full-length irradiated fuel rods from the LWBR are in progress. 19 figures, 13 tables.

  7. Geothermal drilling and completion technology development program. Quarterly progress report, October-December 1979

    SciTech Connect

    Varnado, S.G.

    1980-01-01

    The progress, status, and results of ongoing Research and Development (R and D) within the Geothermal Drilling and Completion Technology Development Program are described. The program emphasizes the development of geothermal drilling hardware, drilling fluids, and completion technology. Advanced drilling systems are also under development. The goals of the program are to develop the technology required to reduce well costs by 25% by 1982 and by 50% by 1986.

  8. Geothermal drilling and completion technology development program. Quarterly progress report, January-March 1980

    SciTech Connect

    Varnado, S.G.

    1980-04-01

    The progress, status, and results of ongoing Research and Development (R and D) within the Geothermal Drilling and Completion Technology Development Program are described. The program emphasizes the development of geothermal drilling hardware, drilling fluids, completion technology, and lost circulation control methods. Advanced drilling systems are also under development. The goals of the program are to develop the technology required to reduce well costs by 25% by 1983 and by 50% by 1987.

  9. NF-κB, the first quarter-century: remarkable progress and outstanding questions

    PubMed Central

    Hayden, Matthew S.; Ghosh, Sankar

    2012-01-01

    The ability to sense and adjust to the environment is crucial to life. For multicellular organisms, the ability to respond to external changes is essential not only for survival but also for normal development and physiology. Although signaling events can directly modify cellular function, typically signaling acts to alter transcriptional responses to generate both transient and sustained changes. Rapid, but transient, changes in gene expression are mediated by inducible transcription factors such as NF-κB. For the past 25 years, NF-κB has served as a paradigm for inducible transcription factors and has provided numerous insights into how signaling events influence gene expression and physiology. Since its discovery as a regulator of expression of the κ light chain gene in B cells, research on NF-κB continues to yield new insights into fundamental cellular processes. Advances in understanding the mechanisms that regulate NF-κB have been accompanied by progress in elucidating the biological significance of this transcription factor in various physiological processes. NF-κB likely plays the most prominent role in the development and function of the immune system and, not surprisingly, when dysregulated, contributes to the pathophysiology of inflammatory disease. As our appreciation of the fundamental role of inflammation in disease pathogenesis has increased, so too has the importance of NF-κB as a key regulatory molecule gained progressively greater significance. However, despite the tremendous progress that has been made in understanding the regulation of NF-κB, there is much that remains to be understood. In this review, we highlight both the progress that has been made and the fundamental questions that remain unanswered after 25 years of study. PMID:22302935

  10. Mechanical interactions of rough surfaces. Quarterly progress report, July 1-September 30, 1986

    SciTech Connect

    McCool, J.I.

    1986-09-01

    Objectives are to study lubricated contacts of rough surfaces under combined rolling, sliding, and spinning, and to develop techniques for analyzing digitized rough surface profiles. A summary is presented of annual progress and of the papers presented at conferences and those published. An example is given of the use of the computer tool MICROCOND. Rq (surface roughness), q, and microfracture data are discussed for silicon nitride coupons. (DLC)

  11. Fossil Energy Program quarterly progress report for the period ending March 31, 1986

    SciTech Connect

    Bradley, R.A.

    1986-06-01

    This report covers progress made during the period January 1 through March 31, 1986, for research and development projects that contribute to the advancement of various fossil energy technologies. Projects on the Fossil Energy Program are supported by DOE Office of Fossil Energy, DOE Office of Basic Energy Sciences, and the Tennessee Valley Authority. The Fossil Energy Program organization chart is shown in the Appendix.

  12. Cadmium sulfide-copper sulfide heterojunction cell research. Quarterly progress report, March 1-May 31, 1980

    SciTech Connect

    1980-11-01

    A complete statistical analysis of the yield of CdS/Cu/sub 2/S cells produced by the standard processes is presented. Progress has been made on producing (CdZn)S films with the appropriate properties to yield high efficiency cells. Further studies of capacitance and transient-capacitance are reported. Defects in electron beam deposited glass are shown to be responsible for lack of effective sealing against atmospheric attack.

  13. Pulse combustion technology for heating applications. Quarterly progress report, January 1-March 31, 1980

    SciTech Connect

    Blomquist, C.A.; Clinch, J.M.; Ahrens, F.W.

    1980-04-01

    The primary purpose of the research program described in this progress report is to develop and expand the technology base for fossil-fuel-fired pulse combustion heating systems. A major goal of the program is to develop design data and design procedures for pulse combustion burners. This design capability will contribute to the accelerated industrial development of cost-effective, high-efficiency systems for a variety of heating applications.

  14. Geothermal drilling and completion technology development program. Quarterly progress report, April-June 1980

    SciTech Connect

    Varnado, S.G.

    1980-07-01

    The progress, status, and results of ongoing research and development (R and D) within the Geothermal Drilling and Completion Technology Development Program are reported. The program emphasizes the development of geothermal drilling hardware, drilling fluids, completion technology, and lost circulation control methods. Advanced drilling systems are also under development. The goals of the program are to develop the technology required to reduce well costs by 25% by 1983 and by 50% by 1987.

  15. Plutonium Residue Recovery (PuRR) project: Quarterly progress report, initial report through March 1988

    SciTech Connect

    Pittenger, L.C.; Alire, R.M.; Coops, M.S.; Priest, R.E.; Thompson, D.S.; Condit, R.H.; Burris, L.; Pierce, R.D.

    1988-06-27

    The PuRR project integrates a number of well understood pyrochemical concepts into one functional process for the recovery of plutonium from scrap and residues. Critical process steps have been identified. Confirming experiments are now in progress at Lawrence Livermore National Laboratory (LLNL) and Argonne National Laboratory (ANL) to demonstrate the successful application of the pyrochemical process described in this document. 3 refs., 12 figs.

  16. Shale oil value enhancement research. First quarterly technical progress report, March 1, 1993--May 31, 1993

    SciTech Connect

    Bunger, J.W.; Russell, C.P.; Devineni, P.A.V.; Cogswell, D.E.; Wiser, J.W.

    1993-06-25

    Concurrent progress is being made in all key areas, namely, separation, characterization and market assessment. The market area, not one of our traditionally strong areas, has been going better than expected. We believe this is due mainly to the emerging interest in new and unconventional materials. The characterization work has been progressing solidly with the fundamental Z-BASIC correlations providing information not heretofore available in the chemical literature. Our agreement with Hewlett-Packard regarding the purchase of equipment at a reduced price is complete and the gc-ms will be ordered shortly. The separation work has progressed satisfactorily although an unexpected amount of time has been required for ``facilities`` and ``equipment`` related issues. Some of these issues have dealt with safety and regulatory compliance when storing larger quantities of samples. These now seem to be solved. We have a lot of direct experience in shale oil separations dating back to the OXY project and before. Also, we will streamline our work by going to prepacked micro-separation tools for some of our separation characterization work. This will allow us to stay on schedule. Overall, we are on schedule with the project. All administration requirements are in place and the accounting and financial records are current.

  17. Damage analysis and fundamental studies. Quarterly progress report, April-June 1980

    SciTech Connect

    Not Available

    1980-08-01

    The DAFS program element is a national effort composed of contributions from a number of National Laboratories and other government laboratories, universities, and industrial laboratories. It was organized by the Materials and Radiation Effects Branch, Office of Fusion Energy, DOE, and a Task Group on Damage Analysis and Fundamental Studies which operates under the auspices of that Branch. The purpose of this series of reports is to provide a working technical record of that effort for the use of the program participants, for the fusion energy program in general, and for the Department of Energy. This report is organized along topical lines in parallel to a Program Plan of the same title so that activities and accomplishments may be followed readily, relative to that Program Plan.

  18. Damage analysis and fundamental studies. Quarterly progress report, January-March 1980

    SciTech Connect

    Not Available

    1980-05-01

    The DAFS program element is a national effort composed of contributions from a number of National Laboratories and other government laboratories, universities, and industrial laboratories. It was organized by the Materials and Radiation Effects Branch, Office of Fusion Energy, DOE, and a Task Group on Damage Analysis and Fundamental Studies which operates under the auspices of that Branch. The purpose of this series of reports is to provide a working technical record of that effort for the use of the program participants, for the fusion energy program in general, and for the Department of Energy. This report is organized along topical lines in parallel to a Program Plan of the same title so that activities and accomplishments may be followed readily, relative to that Program Plan. Thus, the work of a given laboratory may appear throughout the report. The Table of Contents is annotated for the convenience of the reader.

  19. Electric and hybrid vehicle program: Site operator program. Quarterly progress report, April--June, 1994 (3rd quarter of FY-1994)

    SciTech Connect

    Kiser, D.M.; Brown, H.L.

    1994-10-01

    The DOE Site Operator Program was initially established to meet the requirements of the Electric and Hybrid Vehicle Research, Development, and Demonstration Act of 1976. The Program has since evolved in response to new legislation and interests. Its mission now includes three major activity categories; advancement of Electric Vehicle (EV) technologies, development of infrastructure elements needed to support significant EV use, and increasing public awareness and acceptance of EVs. The 13 Program participants, their geographic locations, and the principal thrusts of their efforts are identified. The EV inventories of each participant are summarized. This third quarter report (FY-94) will include a summary of activities from the previous three quarters. The report section sequence has been revised to provide a more easily seen program overview, and specific operator activities are now included.

  20. Installation of a stoker-coal preparation plant in Krakow, Poland. Quarterly technical progress report No. 2, August--October, 1994

    SciTech Connect

    Rozelle, P.

    1996-01-01

    This report describes the progress made during the second Quarter of a two year project to demonstrate that the air pollution, from a traveling grate stoker being used to heat water at a central heating plant in Krakow Poland, can be reduced significantly by replacing the unwashed, unsized coal now being used with a mechanically cleaned, double sized stoker fuel and by optimizing the operating parameters of the stoker. It is anticipated that these improvements will prove to be cost effective and hence be adopted in the other central heating plants in Krakow and indeed throughout Eastern European cities where coal is the primary source of heating fuel. EFH Coal Company has formed a partnership with two Polish institutions -- MPEC a central heating company in Krakow and Naftokrak-Naftobudowa, preparation plant designers and fabricators for this effort. The washability data from a 20mm x 0.5mm size fraction of raw coal from the Staszic Mine were evaluated. The data show that the ash content of this coal can be reduced from 24.4 percent to 6.24 percent by washing in a heavy media cyclone at 1.825 sp.gr.; the actual yield of clean coal would be 76.1 percent. The quest for long-term sources of raw coal to feed the proposed 300 tph stoker coal preparation plant continued throughout the reporting period. Meetings were held with Polish coal preparation equipment suppliers to obtain price and delivery quotations for long lead-time process equipment. Preliminary cost evaluations were the topic of several meetings with financial institutions regarding the cost of producing a quality stoker coal in Poland and for identifying sources of private capital to help cost share the project. The search for markets for surplus production from the new plant continued.

  1. Lawrence Livermore National Laboratory safeguards and security quarterly progress report to the US Department of Energy, quarter ending March 31, 1993

    SciTech Connect

    Ruhter, W.D.; Strait, R.S.; Mansur, D.L.; Davis, G.

    1993-04-01

    This quarterly report discusses activities in the Safeguards Technology Program (STP) which is a program in LLNL`s Nuclear Chemistry Division that develop advanced, nondestructive-analysis (NDA) technology for measurement of special nuclear materials. The work focuses on R&D relating to x{minus} and gamma-ray spectrometry techniques and to the development of computer codes for interpreting the spectral data obtained by these techniques.

  2. Electric and Hybrid Vehicle Program, Site Operator Program. Quarterly progress report, October--December 1995 (first quarter of fiscal year 1996)

    SciTech Connect

    Francfort, J.E.; Bassett, R.R.; Briasco, S.

    1996-03-01

    This is the Site Operator Program quarterly report for USDOE electric and hybrid vehicle research. Its mission now includes the three major activity categories of advancement of electric vehicle (EV) technologies, development of infrastructure elements needed to support significant EV use and increasing public awareness and acceptance of EVs. The 11 Site Operator Program participants, their geographic locations, and the principal thrusts of their efforts are identified. The EV inventories of the site operators totals about 250 vehicles. The individual fleets are summarized.

  3. Lawrence Livermore National Laboratory safeguards and security quarterly progress report to the US Department of Energy. Quarter ending June 30, 1996

    SciTech Connect

    Davis, B.; Davis, G.; Johnson, D; Mansur, D.L.; Ruhter, W.D.; Strait, R.S.

    1996-07-01

    LLNL carries out safeguards and security activities for DOE Office of Safeguards and Security (OSS) and other organizations, both within and outside DOE. This document summarizes activities conducted for OSS during this quarter. LLNL is supporting OSS in six areas: safeguards technology, safeguards and materials accountability, computer security/distributed system, complex-wide access control, standardization of security systems, and information technology & security center. This document describes the activities in each of these six areas.

  4. Fingerprinting of groundwater by ICP-MS. Quarterly progress report, October 1, 1995--December 31, 1995

    SciTech Connect

    Stetzenbach, K.

    1996-02-01

    This document is a progress report for the Fingerprinting of Ground Water by ICP-MS project during the time period from October 1, 1995 to December 31, 1995. The groundwater fingerprinting study has been expanded by including samples from more wells on the Nevada Test Site and from the region east and north of Yucca Mountain as well as from several more springs in the area. Geochemical analyses of these new samples were performed in order to more thoroughly evaluate the regional groundwater chemistry and flow regime. The results of the geochemical analyses are described in this report.

  5. Geothermal direct-heat utilization assistance. Quarterly project progress report, January--March 1996

    SciTech Connect

    1996-05-01

    This report summarizes geothermal technical assistance, R&D, and technology transfer activities of the Geo-Heat Center. It describes 95 contacts with parties during this period related to technical assistance with goethermal direct heat projects. Areas dealt with include geothermal heat pumps, space heating, greenhouses, aquaculture, equipment, economics, and resources. Research activities are summarized on geothermal district heating system cost evaluation and silica waste utilization project. Outreach activities include publication of a geothermal direct use Bulletin, dissemination of information, goethermal library, technical papers and seminars, and progress monitor reports on geothermal resources and utilization.

  6. Thermionic cogeneration burner assessment study. Third quarterly technical progress report, April-June, 1983

    SciTech Connect

    Not Available

    1983-01-01

    The specific tasks of this study are to mathematically model the thermionic cogeneration burner, experimentally confirm the projected energy flows in a thermal mock-up, make a cost estimate of the burner, including manufacturing, installation and maintenance, review industries in general and determine what groups of industries would be able to use the electrical power generated in the process, select one or more industries out of those for an in-depth study, including determination of the performance required for a thermionic cogeneration system to be competitive in that industry. Progress is reported. (WHK)

  7. Decontamination Systems Information and Research Program. Quarterly technical progress report, January 1--March 31, 1993

    SciTech Connect

    Not Available

    1993-04-01

    This reports reports the progress/efforts performed on six technical projects: 1. systematic assessment of the state of hazardous waste clean-up technologies; 2. site remediation technologies (SRT):drain- enhanced soil flushing for organic contaminants removal; 3. SRT: in situ bio-remediation of organic contaminants; 4. excavation systems for hazardous waste sites: dust control methods for in-situ nuclear waste handling; 5. chemical destruction of polychlorinated biphenyls; and 6. development of organic sensors: monolayer and multilayer self-assembled films for chemical sensors.

  8. New technology for sulfide reduction and increased oil recovery. Second quarter progress report

    SciTech Connect

    1998-12-20

    The purpose of this project is to demonstrate reduction of sulfide contamination, as well as possible improvement of production in oil and gas production systems. This will be accomplished by application of the BioCompetitive Exclusion (BCX) process developed by GMT. A broad spectrum of well types and geographical locations is anticipated. The BCX process is designed to manipulate indigenous reservoir bacteria with the addition of synergistic inorganic chemical formulae. These treatments will stimulate growth of beneficial microbes, while suppressing metabolic activity of sulfate reducing bacteria (SRB), the primary source of harmful sulfide production. Progress in 7 oil and gas fields is summarized.

  9. Decontamination Systems Information and Research Program. Quarterly technical progress report, July 1--September 30, 1993

    SciTech Connect

    Not Available

    1993-10-01

    Progress reports are presented for the following projects: systematic assessment of the state of hazardous waste clean-up technologies; site remediation technologies--drain-enhanced soil flushing (DESF) for organic contaminants removal; excavation systems for hazardous waste sites; chemical destruction of polychlorinated biphenyls; development of organic sensors--monolayer and multilayer self-assembled films for chemical sensors; Winfield Lock and Dam remediation; Winfield cleanup survey; assessment of technologies for hazardous waste site remediation--non-treatment technologies and pilot scale test facility implementation; assessment of environmental remediation storage technology; assessment of environmental remediation excavation technology; assessment of environmental remediation monitoring technology; and remediation of hazardous sites with steam reforming.

  10. Development of the selective hydrophobic coagulation process. Tenth quarterly technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1994-08-01

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, known as Selective Hydrophobic Coagulation (SHC), has been studied since 1986. The SHC process differs from oil agglomeration, shear flocculation, polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. Often, simple pH control is all that is required to (1) induced the coagulation of coal particles, and (2) effectively disperse particles of mineral matter. When the coal is superficially oxidized, a small dosage of reagents may be used to promote coagulation. During the past quarter, calculations were carried out under Subtask 2.3 (Predicting Optimum Conditions Using the Extended DLVO Equation) to explain the selectivity window that occurs between pH 7--9 in the SHC process. These calculations suggest that particle interactions involving the edge surfaces of clay are the most important, while interactions involving silica and face surfaces of clay are not as important. Experiments were also continued under Subtask 3.3 (Advanced Separation Methods) to investigate the performance of a centrifuge for separating hydrophobic coagula from dispersed mineral matter. These tests show that coagula recovery increases with centrifugal field strength and decreases with solids content and feed flow rate. Work is now in progress to evaluate the performance of a vacuum filter for coagula recovery.

  11. Stability, rheology and flow of coal-water mixtures. Quarterly progress report, September 1-November 30, 1984

    SciTech Connect

    Turian, R.M.

    1984-01-01

    This is the first quarterly progress report on the subject DOE grant since the starting date of September 1, 1984. During the present reporting period we have been occupied with the details of starting up of the project. Activities during this period have included hiring graduate research assistants for the project, providing them with full details of the research and its objectives, design and construction of research equipment, purchase and installation of coal slurry preparation equipment, setting up of newly purchased research instruments, and testing and calibration of instruments and equipment. Our objective is to test and hopefully establish a definitive method for measurement of yield stress as an intrinsic property (as contrasted to a rheological model parameter) which will then be related to the microstructure of the coal suspension. We have also calibrated the new capillary tubes using Newtonian standards, and tested them extensively using stabilized titanium dioxide dispersions and the laterite slurries discussed above. Among major new instruments that are being set up are the mercury porosimeter and the BET adsorption apparatus. We hope to start preliminary tests on concentrated coal suspensions during the coming period.

  12. Molten salt coal gasification process development unit, Phase 2. Quarterly technical progress report No. 1, July-September 1980

    SciTech Connect

    Slater, M.H.

    1980-10-01

    This represents the first quarterly progress report on Phase 2 of the Molten Salt Coal Gasification Process Development Unit (PDU) Program. Phase 1 of this program started in March 1976 and included the design, construction, and initial operation of a PDU to test the Molten Salt Coal Gasification Process. On July 24, 1980, Phase 2 of the program was initiated. It covers a 1-year operations program utilizing the existing PDU and is planned to include five runs with a targeted total operating time of 9 weeks. The primary activities during the period covered by this report related to preparations for PDU Run 6, the initial run of the Phase 2 program. These activities included restaffing the PDU operations group, reactivation of the facility, and effecting plant modifications and improvements based on an evaluation of previous operation experience. The Melt Withdrawal System which had proven unreliable during the previous runs, was completely redesigned; thermal and flow analyses were performed; new components procured; and assembly initiated. Run 6 which is scheduled for the next report period, is aimed primarily at verifying the adequacy of the redesigned Melt Withdrawal System.

  13. Molten Salt Coal Gasification Process Development Unit. Phase 2. Quarterly technical progress report No. 2, October-December 1980

    SciTech Connect

    Slater, M. H.

    1981-01-20

    This represents the second quarterly progress report on Phase 2 of the Molten Salt Coal Gasification Process Development Unit (PDU) Program. Phase 1 of this program started in March 1976 and included the design, construction, and initial operation of the PDU. On June 25, 1980, Phase 2 of the program was initiated. It covers a 1-year operations program utilizing the existing PDU and is planned to include five runs with a targeted total operating time of 9 weeks. During this report period, Run 6, the initial run of the Phase 2 program was completed. The gasification system was operated for a total of 95 h at pressures up to 10 atm. Average product gas HHV values of 100 Btu/scf were recorded during 10-atm operation, while gasifying coal at a rate of 1100 lb/h. The run was terminated when the melt overflow system plugged after 60 continuous hours of overflow. Following this run, melt withdrawal system revisions were made, basically by changing the orifice materials from Monofrax to an 80 Cobalt-20 Chromium alloy. By the end of the report period, the PDU was being prepared for Run 7.

  14. Bioconversion of coal derived synthesis gas to liquid fuels. Final quarterly technical progress report, July 1, 1993--September 30, 1993

    SciTech Connect

    Jain, M.K.; Worden, R.M.; Grethlein, H.

    1993-10-25

    The overall objective of the project is to develop an integrated two stage fermentation process for conversion of coal-derived synthesis gas to a mixture of alcohols. This is achieved in two steps. In the first step, Butyribacterium methylotrophicum converts carbon monoxide (CO) to butyric and acetic acids. Subsequent fermentation of the acids by Clostridium acetobutylicum leads to the production of butanol and ethanol. The tasks for this quarter were: (1) development/isolation of superior strains for fermentation of syngas, (2) optimization of process conditions for fermentation of syngas, (3) evaluation of bioreactor configuration for improved mass transfer of syngas, (4) development of a membrane-based pervaporation system, (5) optimization of process conditions for reducing carbon and electron loss by H{sub 2}-CO{sub 2} fermentation, and (6) synthesis gas fermentation in single-stage by co-culture. Progress is reported in isolation of CO utilizing anaerobic strains; investigating the product profile for the fermentation of syngas by B. methylotrophicum; and determining the effect of carbon monoxide on growth of C. acetobutylicum.

  15. Effects of surface chemistry on the porous structure of coal. Quarterly technical progress report, January 1996--March 1996

    SciTech Connect

    Anderson, S.A.; Radovic, L.R.; Hatcher, P.G.

    1996-08-01

    The primary objective of this work is to use {sup 129}Xe NMR to characterize the microporous structure of coals. Another objective is to use this technique to describe the effect of controlled opening of the micropores in a microporous carbon by oxygen chemisorption/desorption. The primary goal of the NMR work is to measure the micropore sizes in coal; more broadly, it is to better tailor the {sup 129}Xe NMR method for use with coal, and to investigate other ways it may be used to describe pore structure in coal, with emphasis on determining whether micropores in coal are connected or isolated. During this quarter, we have: (i) investigated particle size effect on the chemical shift of xenon adsorbed in a set of size-graded vitrinites; (ii) tracked the progress of xenon adsorption via xenon NMR, including particle size effect on the adsorption process; (iii) completed a preliminary test for chemical shift anisotropy in coal; and (iv) examined a microporous carbon by {sup 129}Xe NMR after two cycles of oxygen chemisorption/desorption.

  16. Base program on energy related research. Quarterly technical progress report, August--October 1993

    SciTech Connect

    Not Available

    1993-12-31

    Progress reports are presented for the following area of studies: oil and gas; advanced systems applications; environmental technologies; and applied energy science. Oil and gas includes the following tasks: CROW{sup TM} process modeling; and miscible-immiscible gas injection processes. Advanced systems applications covers: development and optimization of a process for the production of a premium solid fuel from Western U.S. coals; development of an on-line alkali monitoring probe; optimization of the recycle oil process for Eastern oil shale; and process support and development. Tasks in the environmental technologies are: solid waste management; and remediation of contaminated soils. Applied energy science covers heavy oil/plastics co-processing.

  17. Electrostatic beneficiation of coal. Quarterly technical progress report, April 1--June 30, 1995

    SciTech Connect

    Mazumder, M.K.; Lindquist, D.; Tennal, K.B.

    1995-07-01

    A chamber has been set up for exposing ground coal to controlled relative humidities. Four levels in the range of 10% to 95% are planned. The change in moisture content of the coal powders will be determined after exposure. Charge to mass ratio acquired in tribocharging and the degree of electrostatic beneficiation will be determined as a function of the relative humidity used for each of the exposures. The authors also discuss their progress in grinding of the coal; the low percentage of coal recovered after separation and the possibility that these losses were a result of holdup in the expansion cone; the design and modeling of the electric curtain; particle size measurement using image processing; and the petrographic analyses of finely and coarsely ground Illinois No. 6 coal.

  18. Blowdown heat transfer separate-effects program. Quarterly progress report, January-March 1980

    SciTech Connect

    Craddick, W.G.; Anklam, T.M.; Bohanan, R.E.; Felde, D.K.; Flanders, R.M.; Hagar, R.C.; Hyman, C.R.; Mailen, G.S.; Mullins, C.B.; Ott, L.J.

    1980-06-01

    Six additional bundle uncovery/recovery tests were performed in the Thermal-Hydraulic Test Facility during January, bringing the total number of these tests to eight. Data taken during the tests were found to be contaminated by numerous spurious spikes. Work to remove the spurious spikes is under way. Posttest analysis of the tests is approx.20% completed. The recovery portion of one of the tests will be analyzed by COBRA/TRAC, currently being developed by Pacific Northwest Laboratories (PNL). Work to debug the code for this application is in progress at PNL. The uncovery/recovery tests apparently caused damage to the 0-rings that form part of the loop pressure boundary. Refurbishment of the 0-ring seal system is being performed concurrently with scheduled loop modifications that include installation of ten in-bundle differential pressure instruments. Design, procurement, and fabrication of the in-bundle gamma densitometer system are continuing on schedule.

  19. Great basin paleoenvironmental studies project; Technical progress report first quarter (year 2), June--August 1994

    SciTech Connect

    1994-10-01

    The paleobiotic and geomorphic records are being examined for the local and regional impact of past climates to assess Yucca Mountain`s suitability as a high-level nuclear waste repository. The project includes botanical, faunal, and geomorphic components that will be integrated to accomplish this goal Progress reports are presented for: Paleobotenical studies in the Great Basin; Paleofaunas studies in the Great Basin; Geomorphology studies in the Great Basin; and Transportation. The goal of the transportation project is to compare the results from three models (FESWMS-2DH, DAMBRK, and FLO-2D) that have been suggested as appropriate for evaluating flood flows on alluvial fans with the results obtained from the traditional one-dimensional, stochastic model used in previous research performed by DRI for the Yucca Mountain Project.

  20. Application of multitracer technology to petroleum reservoir studies. Quarterly progress report, April 1--June 30, 1992

    SciTech Connect

    Senum, G.I.

    1992-09-01

    The objectives of this research program are to: Improve the assessment of the character of petroleum reservoirs using tracer technology for the monitoring and improvement of EOR techniques, specifically, (a) to apply the presently available multitracer perfluorocarbon tracer (PFI) technology to the study of petroleum reservoirs in characterizing reservoir bulk subsurface flow transport and dispersion rates; and (b) to demonstrate that PFTs with differing physical properties will interact with differing rates of adsorption and dispersion within such reservoirs, from which may be inferred difference in the character and/or extent of petroleum in those reservoirs. Develop additional tracers, and tracer injection, sampling and analyses methodologies for use in petroleum reservoir characterization experiments. Develop a data base of petroleum transport and dispersion properties from tracer experiments for use by modellers for developing, validating and extending petroleum reservoirs models used for characterizing petroleum reservoirs. Technical progress is discussed according to the three ongoing field experiments at the Naval Petroleum Reserve in California (NPRC).

  1. Pipeline gas demonstration plant, Phase I. Quarterly technical progress report for September 1980-November 1980

    SciTech Connect

    Eby, R.J.

    1980-12-01

    Work was performed in the following tasks in Phase I of the Pipeline Gas Demonstration Plant Program: Site Evaluation and Selection; Demonstration Plant Environmental Analysis; Feedstock Plans, Licenses, Permits and Easements; Demonstration Plant Definitive Design; Construction Planning; Economic Reassessment; Technical Support; Long Lead Procurement List; and Project Management. The Preliminary Construction Schedule was delivered to the Government on October 3, 1980, constituting an early delivery of the construction schedule called for in the scope of work for Task VI. The major work activity continues to be the effort in Task VI, Demonstration Plant Definitive Design, with two 30% Design Review meetings being held with the Government. Work in Task VII, Construction Planning, was initiated. Work has progressed satisfactorily in the other tasks in support of the Demonstration Plant Program. A Cost Change Proposal was submitted because of an increase in the scope of work and an extension of the schedule for Phase I to 47 months.

  2. Electrostatic precipitation of condensed acid mist: Third quarterly technical progress report, March 1--May 31, 1989

    SciTech Connect

    Not Available

    1989-01-01

    Acid mists can sometimes constitute a significant portion of the total particulate emissions from power plants burning high-sulfur coals. A wet electrostatic precipitator (WESP) is the best control option for acid mist. The mist would blind a fabric filter and attack glass fiber fabrics. A wet ESP is required because the acid would quickly corrode the plates in a conventional dry ESP. The wet ESP also offers the advantages of no rapping reentrainment and no sensitivity to fly ash resistivity. The project is organized in two phases. Phase I, which is scheduled for September 1988 to September 1989, involves the WESP fabrication, laboratory and pilot combustor testing, and computer modeling. Phase II, which is scheduled for September 1989 to September 1990, involves the solicitation of a utility demonstration site, preliminary site measurements, and planning for the demonstration test program. Progress on Phase I work is addressed in this discussion. 5 refs., 4 figs.

  3. Responsive copolymers for enhanced petroleum recovery. Quarterly technical progress report, June 23--September 21, 1994

    SciTech Connect

    McCormick, C.; Hester, R.

    1994-12-31

    Summaries are given on the technical progress on three tasks of this project. Monomer and polymer synthesis discusses the preparation of 1(7-aminoheptyloxymethyl)naphthalene and poly(maleic anhydride-alt-ethyl vinyl ether). Task 2, Characterization of molecular structure, discusses terpolymer solution preparation, UV analysis, fluorescence analysis, low angle laser light scattering, and viscometry. The paper discusses the effects of hydrophobic groups, the effect of pH, the effect of electrolyte addition, and photophysical studies. Task 3, Solution properties, describes the factorial experimental design for characterizing polymer solutions by light scattering, the light scattering test model, orthogonal factorial test design, linear regression in coded space, confidence level for coded space test mode coefficients, coefficients of the real space test model, and surface analysis of the model equations.

  4. Molecular biology of coal bio-desulfurization. Quarterly technical progress report, January 1--March 31, 1992

    SciTech Connect

    Young, K.D.; Gallagher, J.R.

    1992-04-30

    Genes cloned from Rhodococcus rhodochrous IGTS8 can transfer the DBT desulfurization phenotype to a different species (R. Fascians). The product was identified as 2-phenylphenol by gas chromatography. This result parallels the results we have previously reported for the activity of these genes in a DBT-negative mutant of IGTS8. Thus, the evidence is strong that we have identified and cloned the entire set of genes that are responsible for this very specific desulfurization reaction. Sequencing of these genes has commenced. A genomic library was constructed from the bacterium, Besulfovibrio desulfuricans. Screening has not yet identified a clone that carries the desulfurization genes from that organism. Two open reading frames, doxH and doxJ, in the C18 DBT degradation pathway were mutated and are now believed to be dispensable to that pathway. Finally, progress was made toward beginning to sequence the DBT dixoygenase genes from strain A15.

  5. Soot formation in synthetic-fuel droplets. First quarterly technical progress report

    SciTech Connect

    England, G.; Kramlich, J.; Payne, R.

    1981-01-01

    The objective of this project is to provide detailed information on methods of minimizing soot formation during synthetic liquid fuel combustion under conditions which minimize fuel nitrogen conversion to nitric oxide. The program consists of two tasks. The purpose of the first task, Fuel Screening Studies, is to investigate the impact of fuel properties on particulate production, to establish the importance of droplet size and examine atomizer effects, and to develop techniques for surrogate fuels productions. In the second task, Flame Studies, the fundamental details of soot formation from synfuel droplet combustion will be investigated in variable slip velocity configurations. This present report describes technical progress during the first three months of the program effort (October-December 1980). During this initial period, attention has focused on the definition of the different experimental efforts and on the design and construction of the required hardware. Aspects of this work are discussed.

  6. Exploratory research on solvent refined coal liquefaction. Quarterly technical progress report, April 1-June 30, 1979

    SciTech Connect

    1980-07-01

    This report summarizes the progress of the Exploratory Research on Solvent Refined Coal Liquefaction project by The Pittsburgh and Midway Coal Mining Company's Merriam Laboratory for the period April 1, 1979 through June 30, 1979. Experimental work included a number of short residence time runs, but discussion of that work has been delayed until a later report. Experimental work reported focuses on an investigation of the decline in solvent quality experienced by the Wilsonville Pilot Plant during runs in support of the SRC I Demonstration Plant. A four run series was initiated with Wilsonville solvent; both the coal used at Wilsonville (Kentucky 6/11 - Pyro Mine) and Kentucky 9/14 coal from the Colonial Mine were used. The effect of pyrite addition to the Pyro Mine coal was investigated. No solvent quality or coking problems were experienced in the Merriam runs. Significant changes in solvent composition were apparent and equilibrated solvent samples were returned to Wilsonville for solvent quality testing.

  7. Innovative hybrid gas/electric chiller cogeneration. Quarterly technical progress report, April--June, 2000

    SciTech Connect

    Nowakowski, G.

    2000-07-01

    A meeting was held at Alturdyne's facility in San Diego to discuss project progress. Cliff Carpenter, the NETL Program Manager, attended the meeting. As a result of the meeting, several decisions were made: (1) A General Motors engine would be specified as the prime mover; (2) A Carrier reciprocating compressor would be specified, however a Hitachi screw compressor with an integral oil sump was an interesting candidate if it was available in the right size and for the right price; (3) The motor/generator would provide two functions: as an induction motor and as a synchronous generator. The variable speed, constant frequency feature will not be included in the first generation product; and (4) The refrigerant will be R134-A.

  8. Low severity coal liquefaction promoted by cyclic olefins. Quarterly technical progress report, April--June 1996

    SciTech Connect

    Curtis, C.W.

    1997-12-31

    The goal of this research is to develop a methodology for analyzing the reactivity of cyclic olefins in situ in a high temperature and high pressure infrared cell. Cyclic olefins, such as 1,4,5,8-tetrahydronaphthalene (isotetralin) and 1,4,5,8,9,10-hexahydroanthracene (HHA), are highly reactive donor compounds that readily donate their hydrogen to coal and model acceptors when heated to temperatures of 200{degrees}C and above. These donors are active donors in the low severity liquefaction of coal at 350{degrees}C as shown in the research performed in this project. The infrared studies are being performed in a high temperature infrared cell that was obtained from AABSPEC. Modifications to that cell have been made and have been reported in previous progress reports.

  9. Coal transformation chemistry. First quarterly progress report, March 1, 1980-May 31, 1980

    SciTech Connect

    Stock, Leon M.; Alemany, L. B.; Handy, C. I.; King, H. -H.

    1980-01-01

    Considerable progress has been made on the development of a convenient procedure for the alkylation of Illinois No. 6 coal in liquid ammonia. The results are presented in summary in Section IIIB, Task 1 and in more detail in Section IVB. Work on the chemistry of the liquefaction reaction has led to the conclusion that phenolic compounds participate in free radical reactions in hydrogen donor solvents. Phenolic compounds and benzoic acid derivatives do not function as acid catalysts in their reactions with tetralin and other representative compounds. In addition, the reaction of styrene with tetralin at 400/sup 0/C has been shown to be a complex process involving rather deepseated chemical transformations. The results are presented in summary in Section IIIB, Task 3 and in more detail in Section IVC.

  10. Controlling incipient oxidation of pyrite for improved rejection. Technical progress report for the ninth quarter, October 1--December 31, 1994

    SciTech Connect

    Yoon, R.H.; Richardson, P.E.

    1995-07-01

    The major objectives of this work are (1) to determine the Eh-pH conditions under which pyrite is stable, (2) to determine the mechanism of the initial stages of pyrite oxidation, and (3) to determine if the semi-conducting properties of pyrite effects its oxidation behavior. It is known that moderate oxidation of pyrite produces a hydrophobic surface product. This hydrophobic product makes it extremely difficult to depress pyrite in coal flotation circuits. The eventual objective of this work is to prevent pyrite oxidation in order to better depress pyrite in coal flotation circuits. It has been shown that by holding the potential of pyrite at its stable potential during fracture, pyrite undergoes neither oxidation nor reduction. It has also been found that fresh pyrite surfaces created by fracture in an electrochemical begin to oxidize at potentials that are about 200 mV more negative than the potentials reported in the literature for pyrite oxidation. This report period, electrochemical impedance spectroscopy (EIS) studies were continued. As discussed in the seventh quarterly progress report, the impedance of pyrite does not show the characteristics expected for either semi-conducting or metallic electrodes. Additional studies were conducted to confirm the anomalous impedance behavior. For this purpose, freshly fractured surfaces were progressively polished on 600 and 1,200 grit silicon carbide paper, and with 0.3 {micro} {alpha}-alumina and 0.05 {micro} {gamma}-alumina micropolish. Polishing is known to introduce defects in the lattice structure of semi-conducting electrodes and it was anticipated that the defects would effect the interfacial capacitance.

  11. Malignant transformation of oral lichen planus by a chronic inflammatory process. Use of topical corticosteroids to prevent this progression?

    PubMed

    Otero-Rey, Eva Maria; Suarez-Alen, Fatima; Peñamaria-Mallon, Manuel; Lopez-Lopez, Jose; Blanco-Carrion, Andres

    2014-11-01

    Oral lichen planus is a potentially malignant disorder with a capacity, although low, for malignant transformation. Of all the factors related to the process of malignant transformation, it is believed that the chronic inflammatory process plays a key role in the development of oral cancer. This inflammatory process is capable of providing a microenvironment based on different inflammatory cells and molecules that affect cellular growth, proliferation and differentiation. The objectives of our study are: to review the available evidence about the possible relationship between the chronic inflammatory process present in oral lichen planus and its malignant transformation, to discuss the potential therapeutic implications derived from this relationship and to study the role that topical corticosteroids play in the control of oral lichen planus inflammation and its possible progression to malignant transformation. The maintenance of a minimum dose of topical corticosteroids could prevent the inflammatory progression of oral lichen planus to oral cancer.

  12. Transition metal catalysis of hydrogen shuttling in coal liquefaction. Quarterly technical progress report, September 1, 1985-November 30, 1985

    SciTech Connect

    Eisch, J.J.

    1986-01-01

    The ultimate objective of this research is to uncover new catalytic processes for the liquefaction of coal and for upgrading coal-derived fuels by removing undesirable organosulfur, organonitrogen and organooxygen constituents. Basic to both the liquefaction of coal and the purification of coal liquids is the transfer of hydrogen from such sources as dihydrogen, metal hydrides or partially reduced aromatic hydrocarbons to the extensive aromatic rings in coal itself or to aromatic sulfides, amines and ethers. Accordingly, this study is exploring how such crucial hydrogen-transfer processes might be catalyzed by soluble, low-valent transition metal complexes under moderate conditions of temperature and pressure. During the fifth quarter of this three-year grant the following phases of this study received particular attention: (a) the principal investigator completed his three-month period as visiting scientist at Cornell University, October 1 to December 31, 1985, with Professor Roald Hoffmann on the topic of Extended Hueckel Molecular Orbital calculations of organometallic structure; (b) final gas evolution studies between LiAlH/sub 4/ and bipyridyl(1,5-cyclooctadiene) nickel have been made and the related manuscript written for publication; (c) gas evolution studies between diisobutylaluminum hydride and phosphine complexes of Pt(0) and Ni(0) have been undertaken, as part of our trying to understand how powerful reducing agents can be generated from such combinations; (d) hydrogen shuttling studies continue between dihydroaromatic hydrocarbons and Ni(0) complexes; (e) studies on the cleavage of benzylic C-C bonds by Ni(0) and Cr(0) complexes are being intensified; and (f) attempts are being made to isolate crystalline samples of several organonickel intermediates in the foregoing cleavage reactions, so that x-ray structure determinations can be carried out.

  13. Development of vanidum-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report, 1996

    SciTech Connect

    McCormick, R.L.; Alptekin, G.O.

    1996-06-01

    Activities this past quarter, focused on acquisition of kinetic data for oxidation of formaldehyde and methanol on these catalysts. In the next quarter these results will be used to propose a simple reaction network and kinetic model. To date we have completed Task 1: Laboratory Setup and Task 2: Process Variable Study. Activities in the current quarter focused on finalizing these tasks and on Task 3: Promoters and Supports, this task is approximately 50% completed. Task 4: Advanced Catalysts is to be initiated in the next quarter. Specific accomplishments this quarter include: finalizing and calibrating a new reaction product analytical system with markedly improved precision and accuracy relative to older. approaches; development of procedures for accurately feeding formaldehyde to the reactor; examination of formaldehyde and methanol oxidation kinetics over vanadyl pyrophosphate at a range of temperatures; and preliminary studies of methane oxidation over a silica support.

  14. Nuclear Medicine Program progress report for quarter ending June 30, 1993

    SciTech Connect

    Knapp, F.F. Jr.; Ambrose, K.R.; Beets, A.L.; Callahan, A.P.; Hsieh, B.T.; McPherson, D.W.; Mirzadeh, S.; Lambert, C.R.

    1993-07-01

    The ``IQNP`` agent is an antagonist for the cholinergic-muscarinic receptor. Since the IQNP molecule has two asymmetric centers and either cis or trans isomerism of the vinyl iodide, there are eight possible isomeric combinations. In this report, the systematic synthesis, purification and animal testing of several isomers of radioiodinated ``IQNP`` are reported. A dramatic and unexpected relation between the absolute configuration at the two asymmetric centers and the stereochemistry of the vinyl iodide on receptor specificity was observed. The E-(R)(R) isomer shows specific and significant localization (per cent dose/gram at 6 hours) in receptor-rich cerebral structures (i.e. Cortex = 1.38 + 0.31; Striatum = 1.22 + 0.20) and low uptake in tissues rich in the M{sub 2} subtype (Heart = 0.10; Cerebellum = 0.04). In contrast, the E-(R)(S) isomer shows very low receptor-specific uptake (Cortex = 0.04; Striatum = 0.02), demonstrating the importance of absolute configuration at the acetate center. An unexpected and important observation is that the stereochemistry of the vinyl iodine appears to affect receptor subtype specificity, since the Z-(R,S)(R) isomer shows much higher uptake in the heart (0.56 + 0.12) and cerebellum (0.17 + 0.04). Studies are now in progress to confirm these exciting results in vitro. Progress has also continued during this period with several collaborative programs. The first large-scale clinical tungsten-188/rhenium-188 generator prototype (500 mCi) was fabricated and supplied to the Center for Molecular Medicine and Immunology (CMMI), in Newark, New Jersey, for Phase I clinical trials of rhenium-188-labeled anti CEA antibodies for patient treatment. Collaborative studies are also continuing in conjunction with the Nuclear Medicine Department at the University of Massachusetts where a generator is in use to compare the biological properties of {open_quotes}direct{close_quotes} and {open_quotes}indirect{close_quotes} labeled antibodies.

  15. Low cost solar array project. Quarterly progress report, January-March 1980

    SciTech Connect

    Not Available

    1980-01-01

    The overall objective of the LSA Silicon Material Task is to establish a chemical process for producing silicon at a rate and rice commensurate with the production goals of the LSA project for solar-cell modules. As part of -- overall Silicon Material Task, Union Carbide developed the silane-silicon process and advanced the technology to the point where it has a definite potential for providing high-purity polysilicon on a commercial scale at a price of $14/kg by 1986 (1980 dollars). This work, completed under Phases I and II of the contract, provided a firm base for the Phase III program (initiated in April 1979) aimed at establishing the practicality of the process by pursuing the following specific objectives: (1) design, fabricate, install, and operate an Experimental Process System Development Unit (EPSDU) sized for 100 MT/Yr to obtain extensive performance data to establish the data base for the design of commercial facilities; (2) perform support research and development to provide an information base usable for the EPSDU and for technological design and economic analysis for potential scale-up of the process; and (3) perform iterative economic analyses of the estimated product cost for the production of semiconductor-grade silicon in a facility capably of producing 1000 MT/Yr. Progress is repoted in detail. (WHK)

  16. Great Basin paleoenvironmental studies project; Technical progress report: Fourth quarter, March--May, 1994

    SciTech Connect

    1994-07-01

    Examination of the paleoenvironmental and geomorphic records to determine the local and regional impact of past climates will advance the assessment of Yucca Mountain`s suitability as a high-level nuclear waste repository. Paleobotanical studies will reconstruct the response of vegetation to climate change at the community and the organismal levels in order to identify periods of mesic climate at Yucca Mountain and the adjacent region during the last 20,000 to 50,000 years. Constructing a history of Great Basin vertebrates, particularly mammals, will provide empirical evidence of past environmental and climatic conditions within the Great Basin. The objective of the geomorphology component of the program is to document the responses of surficial processes and landforms to the climatic changes documented by studies of packrat middens, pollens, and faunal distributions. The goal of the transportation component is to compare the results from three models (FESWMS-2DH, DAMBRK, and FLO-2D) that have been suggested as appropriate for evaluating flood flows on alluvial fans with the results obtained from the traditional one-dimensional, stochastic model used in previous research for the Yucca Mountain Project. Progress on all these tasks is described.

  17. Tidd PFBC Demonstration Project fourth quarterly technical progress report, CY 1992

    SciTech Connect

    Not Available

    1993-01-01

    This is the 23rd technical progress report submitted to the Department of Energy in connection with the cooperative agreement between the DOE and the Ohio Power Company for the Tidd PFBC Demonstration Plant. This report covers the period from October 1, 1992 to December 31, 1992. Major activities during this period involve: (1) The unit was operated for a total of 714 hours (including gas turbine air prewarming). There were seven gas turbine starts, seven bed preheater starts, and seven operating periods with coal fire. The peak gross output of 64 MWH was achieved for the period of 1000 to 1100 hours on November 23, 1992. The longest coal fire was 285 hours beginning at 1211 hours on November 25, 1992. (2) Total gross generation was 24,643, and coal consumption was 11,900 tons. (3) The hot gas clean up system was commissioned. (4) Active end fluidization system to address sparge duct cracking and deformation problem was jointly initiated by ABB carbon, B&W and AEPSC. (5) All testing continued using Plum Run dolomite. This approach was taken as a conservative means to avoid sintering and unit trips which were encountered during the previous two start-ups in September using limestone and (6) monitoring of solid, liquid and gaseous waste streams, as detailed in the operations phase monitoring requirements in the EMP, were performed.

  18. Base program on energy related research. Quarterly progress report, August--October 1995

    SciTech Connect

    1995-12-31

    Brief progress reports are presented for the following tasks: oil and gas; advanced systems applications; environmental technologies; applied energy science; and remediation. Oil and gas includes the following subtasks: CROW{trademark} process modeling; miscible/immiscible gas injection processes; development of a portable data acquisition system and coalbed methane simulator; and tank bottom waste processing using the TaBooRR{trademark} process. Advanced systems applications include; development and optimization of a process for the production of a premium solid fuel from Western U.S. coals; process support and development; and Easter shale oil residue as an asphalt additive. Environmental technologies include: Conditioning and hydration reactions associated with Clean Coal Technology ash disposal/utilization; remediation of contaminated soil; Syn-Ag{trademark} Process--Coal combustion ash management option; Maxi-Acid{trademark} Process--in-situ amelioration of acid mine drainage; and spill test facility data base; Applied energy science includes: heavy/oil plastics co-processing; and fossil fuel and hydrocarbon conversion using hydrogen-rich plasmas. Remediation covers North site remediation.

  19. Coolside waste management research. Quarterly technical progress report, July 1, 1992--September 30, 1992

    SciTech Connect

    Not Available

    1992-12-31

    TCLP analysis of the Coolside pellets and Ottawa base sand materials were completed. The metal concentrations for the 8 RCRA metals were well below the trigger values with all but Ag and Se being below the drinking water standard levels. The initial and final pH values showed the sand had essentially no neutralization capacity while the neutralization capacity of the pilot plant materials was above the 0.7 meq/g upper level for use of extraction solution {number_sign}1 but well below the 2 meq/g upper level of the {number_sign}2 solution neutralization capacity. Complete metals analysis in addition to the RCRA metals are also reported. Complete metals, proximate, and ultimate analyses for the pilot plant test samples were completed. Sizable concentrations of calcium well above the Coolside samples were observed. Interpretation of these results are in progress. Monitoring of swell on Coolside solid waste samples compacted in CBR molds continued with no increase in swell being observed since the last reporting period. The permeability of a specimen remolded near 95% of standard dry density and optimum moisture content and aged at room temperature for 178 days was 1.72 {times} 10{sup {minus}6} cm/sec.

  20. Advanced Coal Conversion Process Demonstration Project. Quarterly technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect

    1996-02-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1994, through March 31, 1994. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

  1. TIDD PFBC Demonstration Project. First quarterly technical progress report, CY 1993

    SciTech Connect

    Not Available

    1993-04-01

    This is the 24th Technical Progress Report submitted in connection with the cooperative agreement between the DOE and the Ohio Power Company for the Tidd Pressurized Fluidized Bed Combustion (PFBC) Demonstration Plant. This report covers the period from January 1, 1993 to March 31, 1993. The following activities are reported: The unit was operated for a total of 331 hours (including gas turbine air prewarming). There were three gas turbine starts, five bed preheater starts, and two operating periods with coal fire. The peak gross output of 61 MWH was achieved for the period of 2200 to 2300 hours on January 20, 1993. The longest coal fire was 273 hours beginning at 0605 hours on January 20, 1993; total gross generation was 13,453 MWH, and coal consumption was 6,481 tons; The sorbent fines injection system was installed and is ready for use; A totally new secondary ash removal system was designed; New sparge ducts are being fabricated to replace the existing ducts; The plant was found to be in compliance with applicable Ohio regulation after an EPA inspection; and The unit has been out of service since early February due to the failure of the gas turbine. Replacement parts are being fabricated

  2. Soot formation in synthetic-fuel droplets. Second quarterly technical progress report

    SciTech Connect

    England, G.; Kramlich, J.; Payne, R.

    1981-04-01

    The main objective of this program is to provide detailed information on methods of minimizing soot formation during synthetic liquid fuel combustion under conditions which minimize the formation of nitric oxides. The program comprises two main tasks, Fuel Screening Studies, and Flame Studies. The purpose of the first task is to investigate the impact of fuel properties on particulate production, to establish the importance of droplet size and examine atomizer effects, and to develop techniques for surrogate fuels production. In the second task, fundamental details of soot formation from synfuel droplet combustion will be investigated in variable slip velocity configurations. This report describes technical progress during the second three-month period of program effort (January-March 1981). During this period attention has continued to be focussed on the design, construction and commissioning of experimental systems. The Task 1 tunnel furnace modification was completed and made operational, and some preliminary fuel screening studies were carried out. Similarly, construction of the controlled flow droplet reactor was completed and efforts directed towards the design and testing of diagnostic systems. Details of this work are discussed.

  3. Methyl chloride via oxyhydrochlorination of methane. Quarterly technical progress report No. 16, July 1995--September 1995

    SciTech Connect

    1996-03-01

    Continuous progress is being made toward the contract objectives in our attempt to produce {open_quotes}Methyl Chloride via Oxyhydrochlorination of Methane.{close_quotes} Specifically, gains have been achieved in Task 1.0 Catalyst Development and Separation Unit Operation Development and Task 4.0 PDU Startup. Catalyst development continued forward to examine the copper, lanthanum, and lithium loadings as well as support surface area in four factor, two level, fully crossed design experiments carried out at five temperatures between 290{degrees}C and 310{degrees}C. Eight of the sixteen runs have been completed. Evaluation of these runs as a three factor, two level, fully crossed experiment has yielded some useful information. The choice of the Cu/La/Li metals system has been confirmed, and the high Cu, low La, low Li system hasn`t proven itself to be the most active at this point. Chemical feeds were brought on-line to the PDU. Small amounts of methyl chloride were made before the system was shut down due to equipment failure. Glass-lined equipment was found to be failing due to chemical etching. Replacement equipment with other materials of construction have been ordered. In addition, the FTIR windows clouded soon after chemical feeds were started. This materials problem is also being investigated.

  4. Solvent Refined Coal (SRC) process. Quarterly technical progress report, January 1979-March 1979

    SciTech Connect

    Not Available

    1980-02-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) Project by the Pittsburg and Midway Coal Mining Co. for the Department of Energy for the period January 1, 1979 to March 31, 1979. Activities included the operation and modification of the Solvent Refined Coal Pilot Plant at Fort Lewis, Washington; the Process Development Unit P-99 at Harmarville, Pennsylvania; and research at Merriam Laboratory in Merriam, Kansas. The Pilot Plant processed Powhatan No. 5 Coal in the SRC-II mode of operation studying the effect of coal particle size and system temperature on coal slurry blending and the effect of carbon monoxide concentration in the reaction feed gas on process yields. January and February were spent completing installation of a fourth High Pressure Separator on Process Development Unit P-99 to better simulate operating conditions for the proposed Demonstration Plant. During March, one run was completed at P-99 feeding Pittsburgh Seam Coal from the Powhatan No. 5 Mine. Merriam investigations included a study of the effect of iron containing additives on SRC-I operation, the addition of carbon monoxide to the feed gas, utilization of a hydrogenated solvent (Cresap process solvent) in the SRC-I mode under both normal and short residence time operating conditions, and development of a simulated distillation technique to determine the entire boiling range distribution of product oils.

  5. Tidd PFBC Demonstration Project fourth quarterly technical progress report, CY 1992

    SciTech Connect

    Not Available

    1993-01-01

    This is the 23rd technical progress report submitted to the Department of Energy in connection with the cooperative agreement between the DOE and the Ohio Power Company for the Tidd PFBC Demonstration Plant. This report covers the period from October 1, 1992 to December 31, 1992. Major activities during this period involve: (1) The unit was operated for a total of 714 hours (including gas turbine air prewarming). There were seven gas turbine starts, seven bed preheater starts, and seven operating periods with coal fire. The peak gross output of 64 MWH was achieved for the period of 1000 to 1100 hours on November 23, 1992. The longest coal fire was 285 hours beginning at 1211 hours on November 25, 1992. (2) Total gross generation was 24,643, and coal consumption was 11,900 tons. (3) The hot gas clean up system was commissioned. (4) Active end fluidization system to address sparge duct cracking and deformation problem was jointly initiated by ABB carbon, B W and AEPSC. (5) All testing continued using Plum Run dolomite. This approach was taken as a conservative means to avoid sintering and unit trips which were encountered during the previous two start-ups in September using limestone and (6) monitoring of solid, liquid and gaseous waste streams, as detailed in the operations phase monitoring requirements in the EMP, were performed.

  6. Improving reservoir conformance using gelled polymer systems. Quarterly progress report, July 1--September 30, 1994

    SciTech Connect

    Green, D.W.; Willhite, G.P.

    1994-11-01

    The general objectives are to (1) to identify and develop gelled polymer systems which have potential to improve reservoir conformance of fluid displacement processes, (2) to determine the performance of these systems in bulk and in porous media, and (3) to develop methods to predict the capability of these systems to recover oil from petroleum reservoirs. This work focuses on three types of gel systems an aqueous polysaccharide (KUSP 1) system that gels as a function of pH, the chromium(III)-polyacrylamide system and the aluminum citratepolyacrylamide system. Laboratory research is directed at the fundamental understanding of the physics and chemistry of the gelation process in bulk form and in porous media. This knowledge will be used to develop conceptual and mathematical models of the gelation process. Mathematical models will then be extended to predict the performance of gelled polymer treatments in oil reservoirs. Technical progress is described for three studies: Physical and chemical characterization of gel systems (chemical reaction kinetics of KUSP1); Mechanisms of in situ gelation; and Mathematical modeling of gel systems.

  7. Jointly sponsored research program quarterly technical progress report, January--March 1994

    SciTech Connect

    Not Available

    1994-08-01

    Progress reports are presented for the following tasks: Development and demonstration of a practical electric downhole steam generator for thermal recovery of heavy oil and tar; wetting behavior of selected crude oil/brine/rock systems; coal gasification, power generation, and product market study; impact of leachate from clean coal technology waste on the stability of clay liners; investigation of coprocessing of heavy oil, automobile shredder residue, and coal; injection into coal seams for simultaneous CO{sub 2} mitigation and enhanced recovery of coalbed methane; optimization of carbonizer operations in the FMC coke process; chemical sensor and field screening technology development; demonstration of the Koppelman ``Series C`` Power River Basin coal as feed; remote chemical sensor development; market assessment and technical feasibility study of PFBC ash use; solid-state NMR analysis and interpretation of naturally and artificially matured kerogens; Crow{trademark} field demonstration with Bell Lumber and Pole; ``B`` series pilot plant tests; and in-situ treatment of manufactured gas plant contaminated soils demonstration program.

  8. Nuclear-waste-management. Quarterly progress report, July-September 1981

    SciTech Connect

    Chikalla, T.D.; Powell, J.A.

    1981-12-01

    Progress reports and summaries are presented for the following: high-level waste process development, alternate waste forms; TMI zeolite vitrification demonstration program; nuclear waste materials characterization center; TRU waste immobilization; TRU waste decontamination; krypton implantation; thermal outgassing; iodine-129 fixation; NWVP off-gas analysis; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; verification instrument development; mobility of organic complexes of radionuclides in soils; handbook of methods to decrease the generation of low-level waste; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology program; high-level waste form preparation; development of backfill materials; development of structural engineered barriers; disposal charge analysis; analysis of spent fuel policy implementation; spent fuel and fuel pool component integrity program; analysis of postulated criticality events in a storage array of spent LWR fuel; asphalt emulsion sealing of uranium mill tailings; liner evaluation for uranium mill tailings; multilayer barriers for sealing uranium tailings; application of long-term chemical biobarriers for uranium tailings; and revegetation of inactive uranium tailings sites.

  9. MHD Coal Fired Flow Facility. Quarterly technical progress report, July-September 1980

    SciTech Connect

    Altstatt, M. C.; Attig, R. C.; Brosnan, D. A.

    1980-11-01

    Significant activity, task status, planned research, testing, development, and conclusions for the Magnetohydrodynamics (MHD) Coal-Fired Flow Facility (CFFF) and the Energy Conversion Facility (ECF) are described. On Task 1, the first phase of the downstream quench system was completed. On Task 2, all three combustor sections were completed, hydrotested, ASME code stamped, and delivered to UTSI. The nozzle was also delivered. Fabrication of support stands and cooling water manifolds for the combustor and vitiation heater were completed, heat transfer and thermal stress analysis, along with design development, were conducted on the generator and radiant furnace and secondary combustor installation progressed as planned. Under Task 3 an Elemental Analyzer and Atomic Absorption Spectrophotometer/Graphite Furnace were received and installed, sites were prepared for two air monitoring stations, phytoplankton analysis began, and foliage and soil sampling was conducted using all study plots. Some 288 soil samples were combined to make 72 samples which were analyzed. Also, approval was granted to dispose of MHD flyash and slag at the Franklin County landfill. Task 4 effort consisted of completing all component test plans, and establishing the capability of displaying experimental data in graphical format. Under Task 7, a preliminary testing program for critical monitoring of the local current and voltage non-uniformities in the generator electrodes was outlined, electrode metal wear characteristics were documented, boron nitride/refrasil composite interelectrode sealing was improved, and several refractories for downstream MHD applications were evaluated with promising results.

  10. Plasma theory and simulation. Quarterly progress report Nos. 1-2, 1 January-30 June 1988

    SciTech Connect

    Birdsall, C.K.

    1988-06-30

    A magnetized plasma next to an absorbing wall is simulated, showing positive wall charging causing a large E-field near the wall, than a large ExB drift, then a Kelvin-Helmholtz instability, vortices, and coalescence. Particle transport to the walls is Bohm-like, for omega sub pi > omega sub ci. Plasma transport across B/sub O/ to a wall is studied without and with an active antenna buried in the wall. Particle losses are increased appreciably by the fields of the antenna. Small-angle Coulomb collisions produce a drag force and diffusion tensor, which are calculated self-consistently. This produces a FP-PIC method. An example is shown for a beam scattering off fixed ions. Implicit particle simulations are discussed for bounded plasma. The effect of source distribution on the sheath potential is discussed. Initiation of an effort to simulate a traveling-wave tube is discussed. Substantial progress was made in making the authors standard periodic code ES1 work efficiently on a fast PC. A plasma sheath reference listing is discussed.

  11. Peat biogasification development program. Quarterly progress report No. 5, for period October 1 - December 31, 1980

    SciTech Connect

    Wise, Dr., Donald L.

    1981-01-15

    Progress is reported in the peat biogasification development program. The objective of the research is to compile the necessary data for the design and operation of a peat anaerobic digestion process development unit. Five areas are addressed: pretreatment information; anaerobic digestion; evaluation of waste streams; process model development and economic analysis; and planning for the process development unit. During the reporting period extensive data was taken for the development of the predictive process model. A number of batch and continuous pretreatment experiments were completed and analyzed. The four samples being analyzed through solvent extration were completed, and the results are presented. Work on High Pressure Liquid Chromatography continued, and the development of the gradient elution solvent system was completed with encouraging results. Pretreated peat has been batch fermented; the continuously oxidized peat has shown conversions of close to 30%. This is significantly higher than the conversions for the batch oxidized peat. Continuous digesters have been in operation for approximately one month. Development of a predictive process model for the three phases of peat biogasification, solubilization, oxidation, and fermentation, continued with very good results. The models for solubilization and oxidation were developed and experimental data are being gathered for the fermentation phase of the process model. (DMC)

  12. Jointly sponsored research program. Quarterly technical progress report, October--December 1993

    SciTech Connect

    Deans, H.A.

    1994-05-01

    This is a progress report on work performed by Western Research Institute for the U.S. DOE, Morgantown Energy Technology Center in the period October- December 1993. Tasks addressed include: development and demonstration of a practical electric downhole steam generator for thermal recovery of heavy oil and tar; wetting behavior of selected crude oil/brine/rock systems; coal gasification, power generation, and product market study; the impact of leachate from clean coal technology waste on the stability of clay liners; investigation of coprocessing of heavy oil, automobile shredder residue, and coal; injection into coal seams for simultaneous CO{sub 2} mitigation and enhanced recovery of coalbed methane; optimization of carbonizer operations in the FMC coke process; chemical sensor and field screening technology development; demonstration of the koppelman {open_quotes}series c{close_quotes} process using a batch test unit with Powder River Basin coal as feed; remote chemical sensor development; market assessment and technical feasibility study of PFBC ash use; solid-state NMR analysis and interpretation of naturally and artificially matured kerogens; Crow{trademark} field demonstration with bell lumber and pole; {open_quotes}B{close_quotes} series pilot plant tests; in situ treatment of manufactured gas plant contaminated soils demonstration program.

  13. Great Basin paleoenvironmental studies project; Technical progress report, second quarter, September--November, 1993

    SciTech Connect

    1993-12-31

    Progress is described in the four tasks associated with this project. Task 1, Paleobotanical studies in the Great Basin, has as its objective the reconstruction of the response of vegetation to climate in order to identify periods of mesic climate at Yucca Mountain during the last 20,000 to 50,000 years. Past extremes in infiltration rates are expected to serve as estimates of climate that may be expected during the next 10,000 years at Yucca Mtn. Task 2, Paleofaunas, will construct a history of Great Basin vertebrates that will provide empirical evidence of past environmental and climatic conditions. The objective of Task 3, Geomorphology, is to document the responses of surficial processes and landforms to the climatic changes documented by studies of packrat middens, pollen, and faunal distributions. The goal of Task 4, Transportation, is to compare the results from three models that have been suggested as appropriate for evaluating flood flows on alluvial fans with the results obtained from the traditional one-dimensional, stochastic model used in previous research for Yucca Mountain. This research looked at three alluvial fans with rail transportation alignments crossing them.

  14. Electric and Hybrid Vehicle Program, Site Operator Program. Quarterly progress report for July through September 1994 (Fourth quarter of fiscal year 1994)

    SciTech Connect

    Kiser, D.M.; Brown, H.L.

    1995-03-01

    The Site Operator Program was initially established by the Department of Energy (DOE) to incorporate the electric vehicle activities dictated by the Electric and Hybrid Vehicle Research, Development and Demonstration Act of 1976. In the ensuing years, the Program has evolved in response to new legislation and interests. The Program currently includes twelve sites located in diverse geographic, metrologic, and metropolitan areas across the US. Information is shared reciprocally with a thirteenth site, not under Program contract. The vehicles are operator-owned, except for two Griffon vans. The Mission Statement of the Site Operator Program includes three major activities: advancement of electric vehicle technologies; development of infrastructure elements necessary to support significant electric vehicle use; and increasing the awareness and acceptance of electric vehicles (EVs) by the public. The current participants in the Site Operator Program are shown. The ultimate thrust of program activities varies among sites, reflecting not only the Operator`s business interests but also geographic and climate-related operating conditions. This fourth quarter report (FY-94) includes a summary of activities from the previous three quarters. The report section sequence has been revised to provide a more easily seen program overview, and specific operator activities are now found in Appendix A.

  15. Low cost solar array project. Quarterly progress report, July-September 1980

    SciTech Connect

    Not Available

    1980-01-01

    The overall objective of the LSA Silicon Material Task is to establish a chemical process for producing silicon at a rate and price commensurate with the production goals of the LSA project for solar-cell modules. As part of the overall Silicon Material Task, Union Carbide developed the silane-silicon process and advanced the technology to the point where it has a definite potential for providing high-purity polysilicon on a commercial scale at a price of $14/kg by 1986 (1980 dollars). This process for preparing semiconductor-grade silicon in the EPSDU from metallurgical-grade (M-G) silicon is based on a well-integrated arrangement of purification steps that provides a cost-effective process system. The three basic steps entail converting M-G silicon to trichlorosilane, redistributing the trichlorosilane to produce silane, and thermally decomposing the silane to form amorphous silicon powder. The powder is then melted and the molten silicon is cast into polycrystalline silicon for subsequent use in fabricating solar cells. Progress is reported on the following tasks: (1) design, fabricate, install, and operate an Experimental Process System Development Unit (EPSDU) sized for 100 MT/Yr to obtain extensive performance data to establish the data base for the design of commercial facilities; (2) perform supporting research and development to provide an information base usable for the EPSDU and for technological design and economic analysis for potential scale-up of the process; and (3) perform iterative economic analyses of the estimated product cost for the product of semiconductor-grade silicon in a facility capable of producing 1000 MT/Yr. (WHK)

  16. Low-Cost Solar-Array Project. Quarterly progress report, April-June 1980

    SciTech Connect

    Not Available

    1980-01-01

    The overall objective of the LSA Silicon Material Task is to establish a chemical process for producing silicon at a rate and price commensurate with the production goals of the LSA project for solar-cell modules. As part of the overall Silicon Material Task, Union Carbide developed the silane-silicon process and advanced the technology to the point where it has a definite potential for providing high-purity polysilicon on a commercial scale at a price of $14/kg by 1986 (1980 dollars). This work, completed under Phases I and II of the contract, provided a firm base for the Phase III Program (initiated in April 1979) aimed at establishing the practicality of the process by pursuing the following specific objectives: (1) design, fabricate, install, and operate an Experimental Process System Development Unit (EPSDU) sized for 100 MT/yr to obtain extensive performance data to establish the data base for the design of commercial facilities; (2) perform support research and development to provide an information base usable for the EPSDU and for technological design and economic analysis for potential scale-up of the process; and (3) perform iterative economic analyses of the estimated product cost for the production of semiconductor-grade silicon in a facility capable of producing 1000 MT/yr. This process for preparing semiconductor-grade silicon in the EPSDU from metallurgical-grade (M-G) silicon is based on a well-integrated arrangement of purification steps that provides a cost-effective process system. The three basic steps entail converting M-G silicon to trichlorosilane, redistributing the trichlorosilane to produce silane, and thermally decomposing the silane to form amorphous silicon powder. The powder is then melted and the molten silicon is cast to polycrystalline for subsequent use in fabricating solar cells. Progress is reported in detail. (WHK)

  17. (Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending March 31, 1986

    SciTech Connect

    Not Available

    1986-11-01

    Significant progress in catalytic technology was made. Union Carbide researchers discovered a new ruthenium-containing catalyst system that converts methanol to ethanol upon reaction with syngas at relatively low pressures and temperatures. The reduced reaction pressure is a major breakthrough in methanol homologation technology. Chevron Research Co. issued Interim Report No. 12 on the refining and upgrading of oils produced from Wyodak and Illinois coals by the Lummus Crest Integrated Two-Stage Liquefaction Process. This process produces high-density fuel products that have shown potential as jet fuels. Interest in development of high-density fuel and fuel products was reinforced when DOE/Air Force, DOE HQ, and PETC representatives met to discuss a program to assess the feasibility of producing jet fuel from coal-derived materials from commercial-scale synfuels plants. PETC will implement the program for the Department of Defense through an interagency agreement. Another important area of coal-research activity involves the development of flue gas cleanup technology. Successful operation of the NOXSO Flue Gas Treatment Process at a scale equivalent to the generation of 0.75 MW of electricity has demonstrated that the simultaneous removal of 95% of the SO/sub 2/ and 87% of the NO/sub x/ in the flue gas can be obtained. Hydrocarbon Research, Inc., submitted two reports following the completion of its two-year test program designed to investigate the use of a cascade-catalyst system to reduce overall product cost. PETC's coal preparation researchers recently completed a 30-test evaluation of some of the operating parameters of a heavy-liquid cyclone process. PETC's projects involving international cooperation are discussed in some detail.

  18. High sulfur coal research at the SIUC Coal Technology Laboratory. Quarterly progress report

    SciTech Connect

    Not Available

    1984-01-01

    The research effort addressed in this cooperative agreement includes the conduct of a high-sulfur coal research program and the establishment of a research facility, the Coal Technology Laboratory at the site of the former Carbondale Mining Technology Center. The associated research program is broadly based and directed toward high-sulfur coal, the goal being expand the technology to allow for the increased use of high-sulfur coal in an environmentally acceptable manner. Progress continues to be made on the research in the four areas of coal science, coal preparation, coal conversion, and coal utilization. In the Coal Science area, the maceral separation laboratory is about 90% operational. In the area of coal preparation, a mechanical auger feeder device for introducing material into an experimental hydrocyclone along its axis was constructed and incorporated. A froth flotation pilot plant has been acquired and renovated. Coal conversion studies included experiments to examine the effects of chemical pretreatment on supercritical extraction and desulfurization of coal. It was found that with pretreatment a high-sulfur coal containing predominantly organic sulfur experienced a 57% reduction in sulfur on a concentration basis. Without pretreatment, the sulfur reduction was only 40%. In the work examining the mechanism of hydrogen sulfide formation from iron sulfides, it was found that hydrogen sulfide is formed from hydrogen and iron sulfides by a Langmuir-Hinselwood mechanism. Mixtures of H/sub 2/ and D/sub 2/ produce (H,D)H/sub 2/S with random distributions of H and D. Preliminary studies have been conducted in a 10 cm diameter laboratory scale AFBC unit preparatory to the tests to be conducted on waste fuels.

  19. Chemical Engineering Division fuel cycle programs. Quarterly progress report, July-September 1978

    SciTech Connect

    Steindler, M.J.; Ader, M.; Barletta, R.E.

    1980-01-01

    Fuel cycle work included hydraulic performance and extraction efficiency of eight-stage centrifugal contactors, flowsheet for the Aralex process, Ru and Zr extraction in a miniature centrifugal contactor, study of Zr aging in the organic phase and its effect on Zr extraction and hydraulic testing of the 9-cm-ID contactor. Work for predicting accident consequences in LWR fuel processing covered the relation between energy input (to subdivide a solid) and the modes of particle size frequency distribution. In the pyrochemical and dry processing program corrosion-testing materials for containment vessels and equipment for studying carbide reactions in bismuth is under way. Analytical studies have been made of salt-transport processes; efforts to spin tungsten crucibles 13 cm dia continue, and other information on tungsten fabrication is being assembled; the process steps of the chloride volatility process have been demonstrated and the thoria powder product used to produce oxide pellets; solubility of UO/sub 2/, PuO/sub 2/, and fission products in molten alkali nitrates is being investigated; work was continued on reprocessing actinide oxides by extracting the actinides into ammonium chloroaluminate from bismuth; the preparation of thorium-uranium carbide from the oxide is being studied as a means of improving the oxide reactivity; studies are in progress on producing uranium metal and decontaminated ThO/sub 2/ by the reaction of (Th,U)O/sub 2/ solid solution in molten salts containing ThCl/sub 4/ and thorium metal chips. In the molten tin process, no basic thermodynamic or kinetic factors have been found that may limit process development.

  20. Nuclear Medicine Program progress report for quarter ending September 30, 1988

    SciTech Connect

    Knapp, F.F. Jr.; Ambrose, K.R.; Callahan, A.P.; McPherson, D.W.; Srivastava, P.C.; Allred, J.F.; Blystone, S.L.; Kropp, A.; Lisic, E.C.; Rice, D.E.

    1989-03-01

    During this period the properties of the unknown metabolite released from Langendorff-perfused rat hearts administered radioiodinated 15-(p-iodophenyl)-3-R,S-methylpentadecanoic acid (BMIPP) have been further evaluated. Identification of this metabolite is important to provide a better understanding of the myocardial metabolism of methyl-branched fatty acids and to illuminate the factors affecting myocardial retention of such agents. The metabolite is the principal component in the outflow of the isolated rat hearts. Following isolation and purification of the metabolite, treatment with NaBH/sub 4/ had no effect on the chromatographic properties. In contrast, a much less polar product was formed by treatment with acetic anhydride, suggesting the presence of a primary or secondary hydroxyl group. In addition, the metabolite is soluble in dilute base and extracted from an acid solution with ether, demonstrating the presence of a carboxyl group. These combined results suggest BMIPP is metabolized to a hydroxy acid of unknown structure. Studies are now in progress to identify this material. Studies of the effects of chain length on the complexation of a series of p-carboxyalkylphenylglyoxal bis-(N-alkylthiosemicarbazones) (TSC) have continued. After complexation with either Cu-64 or Cu-67 followed by activation to the tetrafluorophenyl esters, the bifunctional ligands were attached to BSA and purified by G-25 Sephadex. Yields varied from 2--3% to 40%, with higher yields for the shorter chain analogues. Because of simpler formation and higher yield, future studies will focus on the radiolabeling of antibodies with the short-chain analogues of the 1,2-diketone TSC derivatives. Also during this period (I-131)IPPA was supplied to collaborators at the Institute of Clinical and Experimental Nuclear Medicine in Bonn, West Germany, for studies with an isolated working rat heart model.

  1. Instrumentation of dynamic gas pulse loading system. Technical progress report, first quarter 1992

    SciTech Connect

    Mohaupt, H.

    1992-04-14

    The overall goal of this work is to further develop and field test a system of stimulating oil and gas wells, which increases the effective radius of the well bore so that more oil can flow into it, by recording pressure during the gas generation phase in real time so that fractures can be induced more predictably in the producing formation. Task 1: Complete the laboratory studies currently underway with the prototype model of the instrumentation currently being studied. Task 2: Perform field tests of the model in the Taft/Bakersfield area, utilizing operations closest to the engineers working on the project, and optimize the unit for various conditions encountered there. Task 3: Perform field test of the model in DGPL jobs which are scheduled in the mid-continent area, and optimize the unit for downhole conditions encountered there. Task 4: Analyze and summarize the results achieved during the complete test series, documenting the steps for usage of downhole instrumentation in the field, and compile data specifying use of the technology by others. Task 5: Prepare final report for DOE, and include also a report on the field tests completed. Describe and estimate the probability of the technology being commercialized and in what time span. The project has made substantial technical progress, though we are running about a month behind schedule. Expenditures are in line with the schedule. Increased widespread interest in the use of DGPL stimulation has kept us very busy. The computer modeling and test instrumentation developed under this program is already being applied to commercial operations.

  2. Build, install and demonstrate a variable stroke pump control and windmill system: 2nd quarterly technical progress report

    SciTech Connect

    Not Available

    1986-12-30

    Most of the time during the second quarter has been spent on the new gear drive. At the end of the 1st quarter the VSM (Variable Stroke Mechanism) was approximately 50% complete. Some work was done the second quarter on the VSM. An all steel mount was nearly completed for the hydraulic cyclinder. The purchased parts to finish the plumbing are on hand, the feedback control chain purchased, and one of the two pulleys was made. A safety device, that could be optional, is being designed and constructed. This addition would prevent damage to the equipment if all of the hydraulic fluid were lost for some reason.

  3. Particulate behavior in a controlled-profile pulverized coal-fired reactor: A study of coupled turbulent particle dispersion and thermal radiation transport. Quarterly technical progress report, June 15, 1995--September 14, 1995

    SciTech Connect

    Queiroz, M.; Webb, B.W.

    1995-11-01

    During the sixteenth quarter progress has been made in the area of turbulence modeling and in the data reduction of heat flux measurements. A multiple-time-scale turbulence model was developed for axisymmetric, swirling flows.

  4. An investigation of the mechanism of IGA/SCC of alloy 600 in corrosion accelerating heated crevice environments. Quarterly Technical Progress Report No. 4 for the period May 1, 2000 through July 31, 2000

    SciTech Connect

    Dr. Jesse Lumsden

    2000-07-31

    OAK-B135 An investigation of the mechanism of IGA/SCC of alloy 600 in corrosion accelerating heated crevice environments. Quarterly Technical Progress Report No. 4 for the period May 1, 2000 through July 31, 2000

  5. Coal-fired high performance power generating system. Quarterly progress report, October 1, 1994--December 31, 1994

    SciTech Connect

    1995-08-01

    This report covers work carried out under Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, {open_quotes}Engineering Development of a Coal-Fired High Performance Power Generation System{close_quotes} between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of (1) > 47% thermal efficiency; (2) NO{sub x}, SO{sub x} and particulates {<=}25% NSPS; (3) cost {>=}65% of heat input; (4) all solid wastes benign. In our design consideration, we have tried to render all waste streams benign and if possible convert them to a commercial product. It appears that vitrified slag has commercial values. If the flyash is reinjected through the furnace, along with the dry bottom ash, then the amount of the less valuable solid waste stream (ash) can be minimized. A limitation on this procedure arises if it results in the buildup of toxic metal concentrations in either the slag, the flyash or other APCD components. We have assembled analytical tools to describe the progress of specific toxic metals in our system. The outline of the analytical procedure is presented in the first section of this report. The strengths and corrosion resistance of five candidate refractories have been studied in this quarter. Some of the results are presented and compared for selected preparation conditions (mixing, drying time and drying temperatures). A 100 hour pilot-scale stagging combustor test of the prototype radiant panel is being planned. Several potential refractory brick materials are under review and five will be selected for the first 100 hour test. The design of the prototype panel is presented along with some of the test requirements.

  6. Computational mechanics research and support for aerodynamics and hydraulics at TFHRC, year 1 quarter 3 progress report.

    SciTech Connect

    Lottes, S.A.; Kulak, R.F.; Bojanowski, C.

    2011-08-26

    The computational fluid dynamics (CFD) and computational structural mechanics (CSM) focus areas at Argonne's Transportation Research and Analysis Computing Center (TRACC) initiated a project to support and compliment the experimental programs at the Turner-Fairbank Highway Research Center (TFHRC) with high performance computing based analysis capabilities in August 2010. The project was established with a new interagency agreement between the Department of Energy and the Department of Transportation to provide collaborative research, development, and benchmarking of advanced three-dimensional computational mechanics analysis methods to the aerodynamics and hydraulics laboratories at TFHRC for a period of five years, beginning in October 2010. The analysis methods employ well-benchmarked and supported commercial computational mechanics software. Computational mechanics encompasses the areas of Computational Fluid Dynamics (CFD), Computational Wind Engineering (CWE), Computational Structural Mechanics (CSM), and Computational Multiphysics Mechanics (CMM) applied in Fluid-Structure Interaction (FSI) problems. The major areas of focus of the project are wind and water loads on bridges - superstructure, deck, cables, and substructure (including soil), primarily during storms and flood events - and the risks that these loads pose to structural failure. For flood events at bridges, another major focus of the work is assessment of the risk to bridges caused by scour of stream and riverbed material away from the foundations of a bridge. Other areas of current research include modeling of flow through culverts to assess them for fish passage, modeling of the salt spray transport into bridge girders to address suitability of using weathering steel in bridges, vehicle stability under high wind loading, and the use of electromagnetic shock absorbers to improve vehicle stability under high wind conditions. This quarterly report documents technical progress on the project tasks

  7. Computational mechanics research and support for aerodynamics and hydraulics at TFHRC, year 2 quarter 2 progress report

    SciTech Connect

    Lottes, S.A.; Bojanowski, C.; Shen, J.; Xie, Z.; Zhai, Y.

    2012-06-28

    The computational fluid dynamics (CFD) and computational structural mechanics (CSM) focus areas at Argonne's Transportation Research and Analysis Computing Center (TRACC) initiated a project to support and compliment the experimental programs at the Turner-Fairbank Highway Research Center (TFHRC) with high performance computing based analysis capabilities in August 2010. The project was established with a new interagency agreement between the Department of Energy and the Department of Transportation to provide collaborative research, development, and benchmarking of advanced three-dimensional computational mechanics analysis methods to the aerodynamics and hydraulics laboratories at TFHRC for a period of five years, beginning in October 2010. The analysis methods employ well benchmarked and supported commercial computational mechanics software. Computational mechanics encompasses the areas of Computational Fluid Dynamics (CFD), Computational Wind Engineering (CWE), Computational Structural Mechanics (CSM), and Computational Multiphysics Mechanics (CMM) applied in Fluid-Structure Interaction (FSI) problems. The major areas of focus of the project are wind and water effects on bridges - superstructure, deck, cables, and substructure (including soil), primarily during storms and flood events - and the risks that these loads pose to structural failure. For flood events at bridges, another major focus of the work is assessment of the risk to bridges caused by scour of stream and riverbed material away from the foundations of a bridge. Other areas of current research include modeling of flow through culverts to improve design allowing for fish passage, modeling of the salt spray transport into bridge girders to address suitability of using weathering steel in bridges, CFD analysis of the operation of the wind tunnel in the TFHRC wind engineering laboratory. This quarterly report documents technical progress on the project tasks for the period of January through March

  8. Computational mechanics research and support for aerodynamics and hydraulics at TFHRC, year 2 quarter 1 progress report.

    SciTech Connect

    Lottes, S.A.; Bojanowski, C.; Shen, J.; Xie, Z.; Zhai, Y.

    2012-04-09

    The computational fluid dynamics (CFD) and computational structural mechanics (CSM) focus areas at Argonne's Transportation Research and Analysis Computing Center (TRACC) initiated a project to support and compliment the experimental programs at the Turner-Fairbank Highway Research Center (TFHRC) with high performance computing based analysis capabilities in August 2010. The project was established with a new interagency agreement between the Department of Energy and the Department of Transportation to provide collaborative research, development, and benchmarking of advanced three-dimensional computational mechanics analysis methods to the aerodynamics and hydraulics laboratories at TFHRC for a period of five years, beginning in October 2010. The analysis methods employ well-benchmarked and supported commercial computational mechanics software. Computational mechanics encompasses the areas of Computational Fluid Dynamics (CFD), Computational Wind Engineering (CWE), Computational Structural Mechanics (CSM), and Computational Multiphysics Mechanics (CMM) applied in Fluid-Structure Interaction (FSI) problems. The major areas of focus of the project are wind and water effects on bridges - superstructure, deck, cables, and substructure (including soil), primarily during storms and flood events - and the risks that these loads pose to structural failure. For flood events at bridges, another major focus of the work is assessment of the risk to bridges caused by scour of stream and riverbed material away from the foundations of a bridge. Other areas of current research include modeling of flow through culverts to improve design allowing for fish passage, modeling of the salt spray transport into bridge girders to address suitability of using weathering steel in bridges, CFD analysis of the operation of the wind tunnel in the TFHRC wind engineering laboratory. This quarterly report documents technical progress on the project tasks for the period of October through December

  9. Charge distribution analysis of catalysts under simulated reaction conditions. Second quarterly technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Freund, F.

    1993-11-01

    New furnaces were built based on fused silica with NiChrome heating elements custom-wound on alumina ceramic to self-compensate for induced magnetic fields during operation. During tests these furnaces failed due to thermal stresses caused by the high temperature cement used to hold the alumina ceramic in place. As a third solution pieces of boron nitride have been procured from which new furnace bodies will be machined during the third quarter. In order to increase the in-house capacity for machining ceramic parts a small lathe was ordered. The implementation of the LabView data acquisition software from National Instruments, Inc. took more time than anticipated and is still not completed. Major difficulties had to be overcome during the integration of the separate positive and negative high voltage supplies ({plus_minus}1000V). It became apparent that a custom-designed switch had to be installed to safeguard the data acquisition modules and the Apple Macintosh Quadra 700 computer again inadvertent exposure to the high voltages during switching operations. Martin Vasey, the software consultant, has made significant progress but the task is far from complete. Major time was spent on integrating the National Instruments GPIB Board with the Omega Temperature Controller via an the RS 232 port and to overcome compatibility problems. Because the Omega Temperature Controller failed catastrophically during tests completion of this task has been put on hold. To proceed with the work one of the PERKIN-ELMER Pt-wound furnaces which is available in the P.I.`s laboratory has been installed for the initial runs.

  10. Heterogeneous catalytic process for alcohol fuels from syngas. Fifth quarterly technical progress report, January--March 1993

    SciTech Connect

    Bassett, M.R.; Minahan, D.M.; Nagaki, D.A.

    1993-12-01

    As stated last quarter, we discovered potassium as an impurity in the mixed metal oxides. The potassium was probably incorporated into the solid during the coprecipitation using K{sub 2}CO{sub 3}. Currently NH{sub 4}OH is being used as the precipitating base. We have discovered that the precipitation agent influences the surface composition of the mixed-metal oxides. Chemical analysis of the surface and bulk compositions showed significant differences in surface compositions of the K{sub 2}CO{sub 3} and NH{sub 4}OH precipitated catalysts. In TPR experiments we have discovered that the precipitating pH markedly affects the reducibility of the ZnMnCr oxides. This shows that the choice of base as well as the pH strongly affects the surface composition of the mixed metal catalysts. Additional studies are in progress in which we are studying how the precipitating agents affect the surface composition of the mixed metal oxide catalysts and how the different surface compositions affect their chemical properties and their interactions with the supported metal particles. Catalysts from our last design show a total selectivity to alcohols of 86%, a 3:1 ratio of methanol to isobutanol and an isobutanol productivity of 30--38 g/kg-hr. Process conversion is estimated to be 7--8%. These are encouraging results, and it is hoped that manipulation of process variables such as temperature, pressure, syngas ratio and space velocity will lead to further improved performance.

  11. Computational mechanics research and support for aerodynamics and hydraulics at TFHRC year 1 quarter 4 progress report.

    SciTech Connect

    Lottes, S.A.; Kulak, R.F.; Bojanowski, C.

    2011-12-09

    high wind conditions. This quarterly report documents technical progress on the project tasks for the period of July through September 2011.

  12. Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, 1 January 1994--31 March 1994

    SciTech Connect

    Chen, J.P.; Cheng, L.S.; Hausladen, M.C.; Kikkinides, E.S.; Yang, R.T.

    1994-05-01

    During the past quarter, progress has been made in four tasks as summarized below: Task 1: A delaminated Fe{sub 2}O{sub 3} pillared clay was synthesized and carefully characterized. The chemical composition was measured by ICP atomic emission spectrometry. The structural changes in the clay as well as the iron oxide particle sizes were characterized by X-ray diffraction techniques. Task 2: The Selective Catalytic Reduction (SCR, i.e., NO reduction with NH{sub 3}) activities of the delaminated pillared clay were tested and compared with four other most active SCR catalysts: a commercial V{sub 2}O{sub 5} + WO{sub 3}/TiO{sub 2} catalyst, a Fe{sub 2}O{sub 3}-pillared clay, and two supported Fe{sub 2}O{sub 3} catalysts (on Al{sub 2}O{sub 3} and TiO{sub 2}). The delaminated Fe{sub 2}O{sub 3} pillared clay exhibited the highest SCR activities. Catalyst stability test showed that the delaminated sample was also stable. Task 3: To further increase the SCR activity of the delaminated pillared clay, Cr{sub 2}O{sub 3} was doped as a promoter by incipient wetness. Task 4: Deactivation effects of SO{sub 2} and H{sub 2}O on the SCR activities of the delaminated Fe{sub 2}O{sub 3} pillared clay were studied, and compared with other SCR catalysts. The delaminated clay catalyst showed the least deactivation.

  13. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly progress report, July - September 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1996-10-01

    The advanced fine-coal cleaning techniques such as column flotation, recovers a low-ash ultra-fine size clean-coal product. However, economical dewatering of the clean coal product to less than 20 percent moisture using conventional technology is difficult. This research program objective is to evaluate a novel coal surface modification technique developed at the University of Kentucky Center for Applied Energy Research in conjunction with conventional and advanced dewatering technique at a pilot scale. The study which is in progress is being conducted at the Powell Mountain Coal Company`s Mayflower preparation plant located in St. Charles, VA. During this quarter laboratory dewatering studies were conducted using a 4-in diameter laboratory chemical centrifuge. The baseline data provided a filter cake with about 32% moisture. Addition of 0.3 kg/t of a cationic surfactant lowered the moisture to 29%. Addition of anionic and non-ionic surfactant was not effective in reducing the filter cake moisture content. In the pilot scale studies, a comparison was conducted between the high pressure and vacuum dewatering techniques. The base line data with high pressure and vacuum filtration provided filter cakes with 23.6% and 27.8% moisture, respectively. Addition of 20 g/t of cationic flocculent provided 21% filter cake moisture using the high pressure filter. A 15% moisture filter cake was obtained using 1.5 kg/t of non-ionic surfactant. Vacuum filter provided about 23% to 25% moisture product with additional reagents. The high pressure filter processed about 3 to 4 times more solids compared to vacuum filter.

  14. Alternative Framework in "Body Coordination" Topic: A Progress Report for Interior of Malaysia

    ERIC Educational Resources Information Center

    Seligin, Davy; Ishak, Mohd. Zaki; Goropos, Jominin

    2015-01-01

    This preliminary study was conducted in interior of Malaysia. The study employed the Body Coordination Two Tier Concept Test to assess students' understandings of body coordination topic. The test consisted of 14 questions as two tier question style. The students needed to select the answer and write down the justifications of each answer.…

  15. Coal log pipeline research at University of Missouri. Second quarterly technical progress report, 1 April--30 June 1996

    SciTech Connect

    Liu, H.

    1996-06-01

    During this quarter, significant progress has been made in the following, fronts of coal log pipeline research, development and technology transfer: 1. Design of the special 300-ton coal log compaction machine was completed, Furthermore, much progress has been made in the design of the system needed to feed coal into the coal log compaction machine, and the design of the system to remove logs automatically as soon as they are compacted. 2. Coal mixtures containing different amounts of moisture were compacted into 1.91- inch-diameter coal logs rapidly (in 6 seconds). It was found that for the Mettiki coal tested, the optimum moisture is around 8%. Under the test conditions (room temperature and 3% binders), the rapidly compacted coal logs with 8% moisture had less than 4% weight loss in 350 cycles of circulation. 3. Completed evaluation of the effectiveness of using wall lubricants to enhance coal log quality. Both calcium sterarate and MoS{sub 2} were found to be effective. 4. It was found that when the interior of a mold is not cleaned after coal log has been compacted, the coal mixture film clinging to the wall hardens in time and form a hard crust which affects the quality of the next log to be produced. But, if the second log is produced immediately after the first, no hard crust is formed and the quality of the second log, is not affected. 5. Coal logs made with the coal crushed by the Gundlach Company were found to be better than coal logs made with the coal crushed by the CPRC`s hammer mill. 7. A 320-ft-long, 6-inch-diameter coal log pipeline test facility was constructed in Rolla during this period. 8. Completed the simulation of an 8-inch-diameter, 20-mile-long coal log pipeline recirculating loop driven by a pump bypass. 9. Continued improvement was accomplished in the hydraulic model of HCP and CLP to predict pressure drop and capsule velocity for both single capsules and capsule train. Also, work has started to extend the analysis to sloped pipelines.

  16. Quarterly Progress Report for the Chemical and Energy Research Section of the Chemical Technology Division: July-September 1999

    SciTech Connect

    Jubin, R.T.

    2001-04-16

    This report summarizes the major activities conducted in the Chemical and Energy Research Section of the Chemical Technology Division at Oak Ridge National Laboratory (ORNL) during the period July-September 1999. The section conducts basic and applied research and development in chemical engineering, applied chemistry, and bioprocessing, with an emphasis on energy-driven technologies and advanced chemical separations for nuclear and waste applications. The report describes the various tasks performed within ten major areas of research: Hot Cell Operations, Process Chemistry, Molten Salt Reactor Experiment (MSRE) Remediation Studies, Chemistry Research, Physical Properties Research, Biochemical Engineering, Separations and Materials Synthesis, Fluid Structures and Properties, Biotechnology Research, and Molecular Studies. The name of a technical contact is included with each task described, and readers are encouraged to contact these individuals if they need additional information. Activities conducted within the area of the Cell Operations involved the testing of two continuously stirred tank reactors in series to evaluate the Savannah River-developed process of small-tank tetraphenylborate precipitation to remove cesium, strontium and transuranics from supernatant. Within the area of Process Chemistry, various topics related to solids formation in process solutions from caustic treatment of Hanford sludge were addressed. Saltcake dissolution efforts continued, including the development of a predictive algorithm. New initiatives for the section included modeling activities centered on detection of hydrogen in {sup 233}U storage wells and wax formation in petroleum mixtures, as well as support for the Spallation Neutron Source (investigation of transmutation products formed during operation). Other activities involved in situ grouting and evaluation of options for use (i.e., as castable shapes) of depleted uranium. In a continuation of activities of the preceding

  17. Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report No. 6, July--September 1994

    SciTech Connect

    McCormick, R.L.

    1995-01-10

    This is the eighth quarterly technical progress report. During this quarter the project was initiated, after transfer via a novation agreement, at the Colorado School of Mines. Project initiation activities have included: set up of catalyst synthesis apparatus; training on x-ray diffraction and FTIR apparatus; set up of catalyst testing reactor; set up of reactor product analytical systems; and set up of method development for measuring catalyst acidity via FTIR. At the end of this quarter significant progress had been made towards completion of these initiation activities. Several catalyst syntheses have been performed and the catalysts characterized by x-ray diffraction and FTIR. The catalyst testing reactor system is operational. Reactor product analysis system is nearing completion. Initiation of this system was delayed by the unavailability of a Valco valve which has just recently arrived. Set up of the in-situ FTIR cell for catalyst acidity studies has begun. In this report the results of several catalyst syntheses are reported along with characterization results. In particular, impregnation of vanadyl pyrophosphate with potassim nitrate dramatically reduced the number of surface hydroxyl groups. Such groups may be important in the non-selective, total oxidation of hydrocarbons. Also, preliminary experimental results on FTIR spectra of adsorbed pyridine are presented. It is shown that pyridine adsorbed on the catalyst surface can be easily observed by the diffuse reflectance IR technique. We plan to apply this technique to measurement of the acid site strength of surfaces modified with promoters.

  18. Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, October 1, 1996--December 31, 1996

    SciTech Connect

    Bai, T.

    1997-01-01

    This quarterly technical progress report describes work performed under DOE Grant No. DE-FG22-94MT94011 during the period September 1, 1996 to December 31, 1996 which covers the nineth quarter of the project. The objective of this investigation is to characterize the operation of a fan powered infrared burner (IR burner) at various gas compositions and ambient conditions and develop design guidelines for appliances containing PIR burners for satisfactory performance. The fan powered infrared burner is a technology introduced more recently in the residential and commercial markets. It is a surface combustor that elevates the temperature of the burner head to a radiant condition. A variety of metallic and ceramic materials are used for the burner heads. It has been demonstrated that infrared burners produce low CO and NO{sub x} emissions in a controlled geometric space. As the environmental regulations become more stringent, infrared burners are receiving increasing interests.

  19. Application of integrated reservoir management and reservoir characterization to optimize infill drilling. Quarterly technical progress report, September 13--December 12, 1996

    SciTech Connect

    1996-12-12

    Eighteen 10-acre infill wells have been drilled and completed as part of the Field Demonstration phase of the project at the North Robertson (Clearfork) Unit (NRU). The fourteen producing wells are pumped-off and producing at stable rates. The four injection wells are completed and have been on injection for three to four weeks. Current Unit production is approximately 3,400 STBO/D, of which approximately 900 STBO/D is being produced from the 10-acre infill wells. A change in the Statement of Work has been approved so that additional 10-acre infill wells can be drilled and/or 20-acre producing wells can be converted to injection during the next quarter as budget constraints and rig availability allow. Technical progress is described for the quarter in many related areas: implementation of the field demonstration; reservoir characterization; reservoir management activities and performance analysis; reservoir simulation; and technology transfer.

  20. Quarterly Technical Progress Report

    SciTech Connect

    Mary K. Banken

    1998-06-30

    This project has identified all FDD oil reservoirs in Oklahoma; grouped those reservoirs into plays that have similar depositional origins; collected, organized, and analyzed all available data; conducted characterization and simulation studies on selected reservoirs in each plays; and implemented a technology transfer program targeted to the operators of FDD reservoirs. By fulfilling these objectives, the FDD project has had the goal of helping to sustain the life expectancy of existing wells and provide incentive for development and exploratory wells with the ultimate objective of increasing oil recovery.

  1. Quarterly Technical Progress Report

    SciTech Connect

    Yi Hua Ma

    1998-03-16

    The temperature dependence of the oxygen flux across the BaCe0G03 dense membrane (BCG membrane) tube was investigated. In the temperature range of 688C to 955C, the increase in the oxygen flux with temperature obeyed the Arrhenius law. An increase in the helium sweep flow membrane tube. rate in the tube side resulted in an increase in the oxygen flux through the The oxygen fluxes through the BCG dense membrane tube were measured at different oxygen partial pressures in the shell side. The oxygen flux increased with the oxygen partial pressure in the shell side. The BCG dense membrane was tested in a membrane reactor for the catalytic oxidative coupling of methane. The BCG membrane is not a complete combustion catalyst, and the catalytic activity of the BCG membrane was found to be much higher than the Argonne dense membrane. As the oxygen partial pressure in the shell side increased, the C2 decreased while the C2 yield remained unchanged, indicating that non-selective, reactions still played a significant role in the membrane reactor.

  2. Evaluation of using cyclocranes to support drilling and production of oil and gas in wetland areas. Fourth quarterly technical progress report, Second quarter, 1993

    SciTech Connect

    Eggington, W.J.

    1993-09-01

    The planned program falls under wetlands area research related to drilling, production, and transportation of oil and gas resources. Specifically the planned program addresses an evaluation of using cyclocraft to transport drill rigs, mud, pipes and other materials and equipment in a cost effective and environmentally safe manner to support oil and gas drilling and production operations in wetland areas. The cyclocraft is a proven hybrid aircraft that utilizes aerostatic and aerodynamic lift. This type of aircraft has considerable payload capacity, VTOL capability, high controllability, low operating cost, low downwash and high safety. The benefits of using a cyclocraft to transport drill rigs and materials over environmentally-sensitive surfaces would be significant. The cyclocraft has considerable cost and operational advantages over the helicopter. The major activity during the second quarter of 1993 was focussed on completion of Task 4, Preliminary Design. The selected design has been designated H.1 Cyclocraft by MRC. Also during the report period, Task 6, Ground Support, was completed and a report containing the results was submitted to DOE. This task addressed the complete H.1 Cyclocraft system, i.e. it included the need personnel, facilities and equipment to support cyclocraft operations in wetland areas.

  3. Evaluation of using cyclocranes to support drilling and production of oil and gas in wetland areas. Fifth quarterly technical progress report, Third quarter, 1993

    SciTech Connect

    Eggington, W.J.

    1993-12-31

    The planned program falls under wetlands area research related to drilling, production, and transportation of oil and gas resources. Specifically the planned program addresses an evaluation of using cyclocraft to transport drill rigs, mud, pipes and other materials and equipment in a cost effective and environmentally safe manner to support oil and gas drilling and production operations in wetland areas. The cyclocraft is a proven hybrid aircraft that utilizes aerostatic and aerodynamic lift. This type of aircraft has considerable payload capacity, VTOL capability, high controllability, low operating cost, low downwash and high safety. The benefits of using a cyclocraft to transport drill rigs and materials over environmentally-sensitive surfaces would be significant. The cyclocraft has considerable cost and operational advantages over the helicopter. In 1992, Task 1, Environmental Considerations, and Task 2, Transport Requirements, were completed. In the first two quarters of 1993, Task 3, Parametric Analysis, Task 4, Preliminary Design, and Task 6, Ground Support, were completed. Individual reports containing results obtained from each of these tasks were submitted to DOE. In addition, through June 30, 1993, a Subscale Test Plan was prepared under Task 5, Subscale Tests, and work was initiated on Task 7, Environmental Impacts, Task 8, Development Plan, Task 9, Operating Costs, and Task 10, Technology Transfer.

  4. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 12, July--September 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-10-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction and operation of a 2-t/hr process development unit. The project began in October, 1992, and is scheduled for completion by June, 1997. During Quarter 12 (July--September 1995), work continued on the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at Lady Dunn. Under Subtask 4.4, additional toxic trace element analysis of column flotation samples finalized the data set. Data analysis indicates that reasonably good mass balances were achieved for most elements. The final Subtask 6.3 Selective Agglomeration Process Optimization topical report was issued this quarter. Preliminary Subtask 6.4 work investigating coal-water-fuel slurry formulation indicated that selective agglomeration products formulate slurries with lower viscosities than advanced flotation products. Work continued on Subtask 6.5 agglomeration bench-scale testing. Results indicate that a 2 lb ash/MBtu product could be produced at a 100-mesh topsize with the Elkhorn No. 3 coal. The detailed design of the 2 t/hr selective agglomeration module neared completion this quarter with the completion of additional revisions of both the process flow, and the process piping and instrument diagrams. Construction of the 2 t/hr PDU and advanced flotation module was completed this quarter and startup and shakedown testing began.

  5. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report, November 1991--January 1992

    SciTech Connect

    Not Available

    1992-08-01

    The objective of this research is to develop information to be used by private industry and government agencies for planning waste disposal practices associated with advanced coal processes. To accomplish this objective, DOE has contracted Radian Corporation and the North Dakota Energy & Environmental Research Center (EERC) to design, construct, and monitor a limited number of field disposal tests with advanced coal process wastes. These field tests will be monitored over a three year period with the emphasis on collecting data on the field disposal of these wastes. Accomplishments for this past quarter are as follows: The 9th quarterly measurements at the Colorado site took place in December, 1991. Permeability and neutron absorption moisture content measurements were made and on site data was collected from the data logger; The 9th quarterly sampling at the Ohio site took place in November 1991. Permeability and moisture content measurements were made, and water samples were collected from the wells and lysimeters; The second quarterly core and water samples from the first Illinois test case were collected in mid November, and field data were collected from the data logger; Chemical analysis of all core and water samples continued; all chemical analyses except for some tests on Illinois second quarter cores are now complete.

  6. Electric and hybrid vehicle program; Site Operator Program. Quarterly progress report, January--March 1992 (Second quarter of fiscal year 1992)

    SciTech Connect

    Warren, J.F.

    1992-05-01

    Activities during the second quarter included the second meeting of the Site Operators in Phoenix, AZ in late April. The meeting was held in conjunction with the Solar and Electric 500 Race activities. Delivery of vehicles ordered previously has begun, although two of the operators are experiencing some delays in receiving their vehicles. Public demonstration activities continue, with an apparent increasing level of awareness and interest being displayed by the public. Initial problems with the Site Operator Database have been corrected and revised copies of the program have been supplied to the Program participants. Operating and Maintenance data is being supplied and submitted to INEL on a monthly basis. Interest in the Site Operator Program is being reflected in requests for information from several organizations from across the country, representing a wide diversity of interests. These organizations have been referred to existing Site Operators with the explanation that the program will not be adding new participants, but that most of the existing organizations are willing to work with other groups. The exception to this was the addition of Potomac Electric Power Company (PEPCO) to the program. PEPCO has been awarded a subcontract to operate and maintain the DOE owned G-Van and Escort located in Washington, DC. They will provide data on these vehicles, as well as a Solectria Force which PEPCO has purchased. The Task Force intends to be actively involved in the infrastructure development in a wide range of areas. These include, among others, personnel development, safety, charging, and servicing. Work continues in these areas. York Technical College (YORK) has completed the draft outline for the EV Technician course. This is being circulated to organizations around the country for comments. Kansas State University (KSU) is working with a private sector company to develop a energy dispensing meter for opportunity charging in public areas.

  7. Combustion of pulverized coal in vortex structures. Quarterly progress report No. 6, January 1, 1995--March 31, 1995

    SciTech Connect

    Gollahalli, S.R.

    1995-03-01

    This sixth quarterly report describes the activities and accomplishments of the research team at the University of Oklahoma, Norman, Oklahoma, related to the project entitled ``Combustion of Pulverized Coal in Vortex Structures`` during the period January 1, 1995 to March 31, 1995. The work performed in this quarter consisted of the following four tasks: (1) design and fabrication of a computer-driven traversing mechanism for traversing LDV transmitter and receiving optics, (2) color schlieren photography, (3) presenting a report in the panel-review meeting in Pittsburgh, (4) installation of additional safety devices in response to the letter of Dr. Sean Plasynski, and (5) streamwise velocity measurement in the isothermal heterogeneous shear layer with nonreacting particles using LDV. In the next quarter, we plan to continue this work with heated shear layers in which particles undergo pyrolysis. Flow visualization and mean velocity field measurement instrumentation will continue as the major experimental techniques.

  8. BX in-situ oil-shale project. Quarterly technical progress report, June 1, 1981-August 31, 1981

    SciTech Connect

    Dougan, P.M.

    1981-09-20

    June 1, 1981-August 31, 1981 was the third consecutive quarter of superheated steam injection at the BX In Situ Oil Shale Project. Injection was continuous except for the period of July 14th to August 1st when the injection was suspended during the drilling of core hole BX-37. During the quarter, 99,760 barrels of water as superheated steam were injected into Project injection wells at an average well head temperature of 752/sup 0/F and an average wellhead pressure of 1312 PSIG. During the same period, 135,469 barrels of fluid were produced from the Project production wells for a produced to injected fluid ratio of 1.36 to 1.0. Net oil production during the quarter was 38 barrels.

  9. Technology development for cobalt F-T catalysts. Quarterly technical progress report No. 7, April 1, 1994--June 30, 1994

    SciTech Connect

    Singleton, A.H.

    1995-05-31

    This project`s goal is the development of a commercially viable, cobalt-based Fischer-Tropsch (F-T) catalyst for use in a slurry bubble column (SBC) reactor. During the seventh quarter, significant progress in several areas has enabled us to make a number of important conclusions. Preliminary catalyst preparation of 3 batches of a Ru-promoted 20% Co/Al{sub 2}O{sub 3} has confirmed the similarity in catalysts prepared by Energy International and by Calsicat using the same procedure. This similarity was evident in both fixed and SBC reactor studies. All TiO{sub 2}-supported Co catalysts have been found to have poor F-T properties in both the fixed-bed and SBC reactors. These catalysts had been prepared following exactly the procedures given in the Exxon patents. One of the main problems in using TiO{sub 2} as a support is the fact that it has low surface area for supporting a 20 wt % Co catalyst. Another problem is that it does not seem to be robust enough for use in a SBC reactor. Ru promotion of Co/SiO{sub 2} does not have as dramatic an effect on catalyst activity as seen for Co/Al{sub 2}O{sub 3}. However, it does play a major role in maintaining higher activity (factor of 2 in the SBCR) when K is added to Co/Sr/SiO{sub 2}. Zr has been clearly shown by us to significantly enhance the F-T activity of Co/SiO{sub 2}. Such promotion is a basis for many of the Shell cobalt F-T patents. Latest results indicate that Zr also improves the activity of Co/Al{sub 2}O{sub 3}, although the methane selectivity is also slightly elevated. Finally, for our design of a ``benchmark`` Co F- T catalyst, research has now shown using both fixed-bed and SBC reactors that 0.3 wt % K is the optimum amount to use with Ru- promoted 20 wt % Co/Al{sub 2}O{sub 3}. This amount of K greatly improves higher hydrocarbon selectivity without causing an unacceptable loss of activity.

  10. Compatibility of refrigerants and lubricants with motor materials. Quarterly technical progress report, April 1, 1992--June 30, 1992

    SciTech Connect

    Doerr, R.; Kujak, S.

    1992-07-23

    During this last quarter, evaluations were complete on the motor materials after 500-hr exposures to refrigerants CFC-123, HFC-134a and HCFC-22 at 90{degrees}C. Materials were also evaluated after exposure to nitrogen at 127{degrees}C to determine effect of the thermal exposure. Other exposures were started during this quarter with refrigerants HCFC-124, HFC-125, HFC-143a, HFC-32 and HFC-152a. One 500 hr exposure is set up per week and one is analyzed the same week. This will enable Trane to complete the 500 hour exposures by the end of the year.

  11. Geothermal direct-heat utilization assistance. Federal Assistance Program, Quarterly project progress report, October--December 1994

    SciTech Connect

    Not Available

    1994-12-31

    The report summarizes activities of the Geo-Heat Center (GHC) at Oregon Institute of Technology for the first quarter of Fiscal Year 1995. It describes contacts with parties during this period related to assistance with geothermal direct heat projects. Areas dealt with include geothermal heat pumps, space heating, greenhouses, aquaculture, resources and equipment. Research is also being conducted on geothermal energy cost evaluation, low-temperature geothermal resource assessment, use of silica waste from the Cerro Prieto geothermal field as construction materials and geothermal heat pumps. Outreach activities include the publication of a quarterly Bulletin on direct heat applications and dissemination of information on low-temperature geothermal resources and utilization.

  12. Preliminary design and assessment of a 50,000-BPD coal-to-methanol-to-gasoline plant. Quarterly technical progress report, 1 April 1982-30 June 1982

    SciTech Connect

    Not Available

    1982-01-01

    The technical efforts associated with the Statement of Work for the preliminary design and assessment of a 50,000-BPD Coal-to-Methanol-to-Gasoline Plant continued at an accelerated rate. Physical accomplishment increased from 39.6% (March 1982) to 69.1% (June 1982). All contracts were in place prior to the commencement of this quarter and the only significant contractual action bearing on Statement of Work requirements was DOE's approval of a Grace request for modification of the Dames and Moore Subcontract to recognize certain additions and/or expansions resulting from the scoping meeting process. The narrative of this report discusses progress of work associated with technical activities for both the 50,000-BPD and 12,500-BPD plants. Significant progress in the process and mechanical design was achieved following the receipt of all design packages and data from vendors for incorporation in process design documentation. This information enabled the preparation of all process and utility flow diagrams, plot plans, evaluations, and associated direct capital cost estimates for the 50,000-BPD plant. The basic design of all process units comprising the Gasoline Plant was completed, and engineering efforts directed toward supplying inputs for the development of capital and operating cost estimates and economic assessments. Development of engineering documentation for the 12,500-BPD plant was initiated and progressed significantly during the quarter. Development of capital and operating cost estimates for the smaller plant was also active.

  13. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report 6, January--March 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1996-05-03

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine clean coal. Economical dewatering of an ultra-fine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1- March 31, 1996.

  14. Cross-flow, filter-sorbent catalyst for particulate, SO{sub 2} and NO{sub x} control. Seventh quarterly technical progress report

    SciTech Connect

    Benedek, K.; Flytzani-Stephanopoulos, M.

    1992-01-01

    This report describes work performed on a new concept for integrated pollutant control: a cross-flow filter comprised of layered, gas permeable membranes that act as a particle filter, an SO {sub 2} sorbent, and a NO {sub x} reduction catalyst. One critical element of the R&D program is the development of mixed metal oxide materials that serve as combined SO {sub 2} sorbents and NO {sub x} reduction catalysts. In this seventh quarterly progress report, we summarize the performance characteristics of three promising sorbent/catalyst materials tested in powder form.

  15. Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report No. 9, April 1995--June 1995

    SciTech Connect

    McCormick, R.L.

    1995-09-14

    This document is the ninth quarterly technical progress report under Contract No. DE-AC22-92PC92110 {open_quotes}Development of Vanadium-Phosphate Catalysts for Methanol Production by Selective Oxidation of Methane{close_quotes}. Activities were focused on fine tuning of the microreactor system by elimination of transport effects and improvements in the analytical system. Process variable studies were conducted on vanadyl pyrophosphate and screening studies were conducted on several modified catalyst. One additional catalyst was prepared and characterization studies continued. These results are reported.

  16. Contracts for field projects and supporting research on enhanced oil recovery: Progress review No. 74, Quarter ending March 31, 1993

    SciTech Connect

    Not Available

    1994-03-01

    Accomplishments for the past quarter are presented for the following tasks: chemical flooding--supporting research; gas displacement--supporting research; thermal recovery--supporting research; geoscience technology; resource assessment technology; microbial technology; field demonstrations in high-priority reservoir classes; and novel technology. A list of available publication is also provided.

  17. NRC TLD Direct Radiation Monitoring Network. Volume 15, No. 4: Quarterly progress report, October--December 1995

    SciTech Connect

    Struckmeyer, R.

    1996-03-01

    This report presents the results of the NRC Direct Radiation Monitoring Network for the fourth quarter of 1995. It provides the ambient radiation levels measured in the vicinity of 75 sites throughout the United States. In addition, it describes the equipment used, monitoring station selection criteria, characterization of the dosimeter response, calibration procedures, statistical methods, intercomparison, and quality assurance program.

  18. Configurational diffusion of asphaltenes in fresh and aged catalyst extrudates. Quarterly progress report, June 20, 1995--September 20, 1995

    SciTech Connect

    Guin, J.A.

    1996-01-01

    The objective of this research is to determine the relationship between the size and shape of coal and petroleum macromolecules and their diffusion rates i.e., effective diffusivities, in catalyst pore structures. This quarter, three petroleum and two coal asphaltenes were prepared from petroleum asphalts and coal derived solids separately by solvent extraction.

  19. Underground gasification for steeply dipping coal beds: Phase III. Quarterly progress report, April 1-June 30, 1981. [Rawlins Test 2

    SciTech Connect

    Not Available

    1981-12-01

    Preparations are being made for the August start-up of Rawlins Test 2. Site construction activities began May 4 with the mobilization of the construction subcontractor. The drilling program was completed this quarter with the installation of instrumentation wells. The Experimental Basis Document, PGA Operating Manual, and DAS Operating Manual have also been completed.

  20. Support of enhanced oil recovery to independent producers in Texas. Quarterly technical progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Fotouh, K.H.

    1995-09-30

    The main objective of this project is to support independent oil producers in Texas and to improve the productivity of marginal wells utilizing enhanced oil recovery techniques. The main task carried out this quarter was the generation of an electronic data base.

  1. Progress in paediatric parasitology: a preface to a topic focusing on ever younger subjects.

    PubMed

    Stothard, J Russell; Chiodini, Peter; Booth, Mark

    2011-10-01

    Without realizing it perhaps, the research activities of many parasitologists are often focused upon the study of parasites most commonly found in children. Though there is little recognition of paediatric parasitology as a separate topic within medical parasitology, with the global interest in promotion of maternal and child health, alleviation of diseases associated with poverty and requirements of 'child-sized' medicines, a more formal consideration is now timely. Recent research, for example, has highlighted that defining precisely the 'first-age' at which parasites interfere with a child's health, or normal developmental processes, is being revised. Attention is now drawn towards ever younger subjects, for parasites have the capacity to also influence the health of the foetus within the in utero environment, altering immune-development. These subtle, yet evolutionary profound interactions perhaps manifest themselves as to why some children are more prone to infection(s), develop overt disease and sadly die while others do not. Here, we address the growing importance of paediatric parasitology and its applications within disease control strategies as highlighted in the 2010 Autumn Symposium of the British Society of Parasitology.

  2. Short-term energy outlook. Quarterly projections, Third quarter 1995

    SciTech Connect

    1995-08-02

    The Energy Information Administration (EIA) prepares quarterly, short-term energy supply, demand, and price projections for publication in February, May, August, and November in the Short-Term Energy Outlook (Outlook). An annual supplement analyzes the performance of previous forecasts, compares recent projections with those of other forecasting services, and discusses current topics related to the short-term energy markets. The forecast period for this issue of the Outlook extends from the third quarter of 1995 through the fourth quarter of 1996. Values for the second quarter of 1995, however, are preliminary EIA estimates.

  3. F-Area Seepage Basins groundwater monitoring report. First quarter 1992

    SciTech Connect

    Not Available

    1992-06-01

    This progress report from the Savannah River Plant for first quarter 1992 includes discussion on the following topics: description of facilities; hydrostratigraphic units; monitoring well nomenclature; integrity of the monitoring well network; groundwater monitoring data; analytical results exceeding standards; tritium, nitrate, and pH time-trend data; water levels; groundwater flow rates and directions; upgradient versus downgradient results.

  4. F-Area Seepage Basins groundwater monitoring report, fourth quarter 1991 and 1991 summary

    SciTech Connect

    Not Available

    1992-03-01

    This progress report for fourth quarter 1991 and 1991 summary fro the Savannah River Plant includes discussion on the following topics: description of facilities; hydrostratigraphic units; monitoring well nomenclature; integrity of the monitoring well network; groundwater monitoring data; analytical results exceeding standards; tritium, nitrate, and pH time-trend data; water levels; groundwater flow rates and directions; upgradient versus downgradient results.

  5. F-Area Seepage Basins groundwater monitoring report. Second quarter 1992

    SciTech Connect

    Not Available

    1992-09-01

    This progress report from the Savannah River Plant for second quarter 1992 includes discussion on the following topics: description of facilities; hydrostratigraphic units; monitoring well nomenclature; integrity of the monitoring well network; groundwater monitoring data; analytical results exceeding standards; tritium, nitrate, and pH time-trend data; water levels; groundwater flow rates and directions; upgradient versus downgradient results.

  6. REVIEWS OF TOPICAL PROBLEMS: Experimental tests of general relativity: recent progress and future directions

    NASA Astrophysics Data System (ADS)

    Turyshev, S. G.

    2009-01-01

    Einstein's general theory of relativity is the standard theory of gravity, especially where the needs of astronomy, astrophysics, cosmology, and fundamental physics are concerned. As such, this theory is used for many practical purposes involving spacecraft navigation, geodesy, and time transfer. We review the foundations of general relativity, discuss recent progress in tests of relativistic gravity, and present motivations for the new generation of high-accuracy tests of new physics beyond general relativity. Space-based experiments in fundamental physics are presently capable of uniquely addressing important questions related to the fundamental laws of nature. We discuss the advances in our understanding of fundamental physics that are anticipated in the near future and evaluate the discovery potential of a number of recently proposed space-based gravitational experiments.

  7. Trustee Quarterly, 1997.

    ERIC Educational Resources Information Center

    Hutchins, Sally, Ed.

    1997-01-01

    These four issues of "Trustee Quarterly" focus on current topics affecting community college trustees. Issue 1 focuses on the learning revolution and serves as a guide for community college trustees. It offers the following feature articles by Terry O'Banion: "Education Reform: Two Waves,""The Second Wave and the Community…

  8. Trustee Quarterly, 1994.

    ERIC Educational Resources Information Center

    Trustee Quarterly, 1994

    1994-01-01

    The four issues of "Trustee Quarterly" combined here focus on topics of current concern to community college trustees. The winter 1994 issues offers these feature articles: "Honoring Retiring Presidents," by Terry O'Banion; "Trustees as Reluctant Leaders: The Board/CEO Relationship," Norma Jean Germond, John Keyser, and Vaughn A. Sherman; and…

  9. Trustee Quarterly, 1994.

    ERIC Educational Resources Information Center

    Trustee Quarterly, 1994

    1994-01-01

    The four issues of "Trustee Quarterly" combined here focus on topics of current concern to community college trustees. The winter 1994 issues offers these feature articles: "Honoring Retiring Presidents," by Terry O'Banion; "Trustees as Reluctant Leaders: The Board/CEO Relationship," Norma Jean Germond, John Keyser, and Vaughn A. Sherman; and…

  10. Trustee Quarterly, 1992.

    ERIC Educational Resources Information Center

    Trustee Quarterly, 1992

    1992-01-01

    The four issues of "Trustee Quarterly" contained in this document focus on topics of current concern to community college trustees. The winter 1992 issue offers articles on the trustee's role in politics, community colleges as community catalysts, Lewis and Clark Community College's (Illinois) strategic planning process, staff development…

  11. Trustee Quarterly, 1993.

    ERIC Educational Resources Information Center

    Trustee Quarterly, 1993

    1993-01-01

    The four issues of "Trustee Quarterly" contained in this document focus on topics of current concern to community college trustees. The winter 1993 issue offers articles on the prospects for educational reform under the Clinton administration and the current Congress, strategies for obtaining needed resources from the state legislature, and the…

  12. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 11, April--June, 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-07-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 tons of each of three project coals, by each process. During Quarter 11 (April--June, 1995), work continued on the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at the Lady Dunn Preparation Plant with the installation and calibration of a refurbished 30-inch diameter column. The evaluation of toxic trace element data for column flotation samples continued, with preliminary analysis indicating that reasonably good mass balances were achieved for most elements, and that significant reductions in the concentration of many elements were observed from raw coal, to flotation feed, to flotation product samples. Significant progress was made on Subtask 6.5 selective agglomeration bench-scale testing. Data from this work indicates that project ash specifications can be met for all coals evaluated, and that the bulk of the bridging liquid (heptane) can be removed from the product for recycle to the process. The detailed design of the 2 t/hr selective agglomeration module progressed this quarter with the completion of several revisions of both the process flow, and the process piping and instrument diagrams. Procurement of coal for PDU operation began with the purchase of 800 tons of Taggart coal. Construction of the 2 t/hr PDU continued through this reporting quarter and is currently approximately 60% complete.

  13. Characterization and supply of coal based fuels. Quarterly technical progress report, February 1, 1987--April 30, 1987

    SciTech Connect

    Not Available

    1987-07-01

    Contract objectives are as follows: develop fuel specifications to serve combustor requirements; select coals having appropriate compositional and quality characteristics as well as an economically attractive reserve base; provide quality assurance for both the parent coals and the fuel forms; and deliver premium coal-based fuels to combustor developers as needed for their contract work. During the second quarter of this contract effort, the primary activities were involved with: continuation of development of fuel requirements (i.e., specifications, quantities, schedule); acquisition and bench-scale characterization of candidate coal samples; selection of coal water slurry fuel manufacturer; procurement of parent coal for fuel production; deep cleaning by froth flotation of parent coal; production of solid fuel (i.e., size reduction of deep cleaned parent coal) and delivery to combustors/experimenters; production of slurry fuel and delivery to combustors/experimenters; and completion of Final Version of First Quarterly Report.

  14. Increasing heavy oil reserves in the Wilmington oil field through advanced reservoir characterization and thermal production technologies. Quarterly technical progress report, March 30, 1995--June 30, 1995

    SciTech Connect

    Clarke, D.; Ershaghi, I.; Davies, D.; Phillips, C.; Mondragon, J.

    1995-07-28

    This is the first quarterly technical progress report for the project. Although the contract was awarded on March 30, 1995 and Pre-Award Approval was given on January 26, 1995, the partners of this project initiated work on October 1, 1994. As such, this progress report summarizes the work performed from project inception. The production and injection data, reservoir engineering data, and digitized and normalized log data were all completed sufficiently by the end of the quarter to start work on the basic reservoir engineering and geologic stochastic models. Basic reservoir engineering analysis began June 1 and will continue to March, 1996. Design work for the 5 observation/core holes, oil finger printing of the cored oil sands, and tracers surveys began in January, 1995. The wells will be drilled from July--August, 1995 and tracer injection work is projected to start in October, 1995. A preliminary deterministic 3-D geologic model was completed in June which is sufficient to start work on the stochastic 3-D geologic model. The four proposed horizontal wells (two injectors and two producers) have been designed, equipment has been ordered, and the wells will be drilled from mid-August through September. Four existing steam injection wells were converted to hot water injection in March, 1995. Initial rates were kept low to minimize operational problems. Injection rates will be increased significantly in July.

  15. [Design of gas and electric rotary furnaces for the glass industry]. Quarterly progress report, September 20--December 20, 1997

    SciTech Connect

    Pochan, D.

    1997-12-31

    The authors have continually stressed that the two most critical material parameters for the success of the rotary furnace are the hearth plate and the molding release powder. Both of these issues have been solidly addressed in this quarter. They have tested the three best candidates for hearth plate material this quarter. Although they had to use the in-house gas furnaces for the testing, one of the materials combines the best heating efficiency with the least sticking tendency. This material will be used for the electric prototype. The molding release powder is mainly used for preventing the glass from adhering to the hearth plate while the glass is softening for pressing. They recently visited several companies in Japan who also repress glass. The release agent that they use is Boron Nitride. They have identified a supplier within New York state, but their concern is the very high price of this material. They are bringing in samples of different grades for experimentation, but the focus continues to be to eliminate the need for any powder. An additional area for material testing was addressed during this quarter. Once the glass is in the tool (mold) for pressing, the glass has the potential to adhere to the metal that the tool and die are made from (usually steel). Both the powder and a spraying of a carbon product are currently used to reduce this problem. Alternate materials for the tooling and/or surface coatings of the steel need to be identified and tested. During this quarter, they conducted some off-site test runs on two candidate coating materials: platinum and titanium.

  16. Configurational diffusion of asphaltenes in fresh and aged catalyst extrudates. Quarterly progress report, December 20, 1994--March 20, 1995

    SciTech Connect

    Guin, J.A.

    1995-08-01

    This quarter, GPC column efficiency and resolution were tested. Better resolution and separation of petroleum asphaltenes were obtained in GPC by connecting four columns (1000{Angstrom}, 1000{Angstrom}, 500{Angstrom}, 500{Angstrom} pore sizes, respectively) in series. A good linear column calibration curve was obtained using several polystyrene standards with molecular weights ranging from 500 to 5 {times} 10{sup 4}. The molecular weight distribution of a petroleum asphaltenes was approximated by the polystyrene calibration curve.

  17. Enforcement actions: Significant actions resolved. Volume 14, No. 2, Part 1: Individual actions. Quarterly progress report, April--June 1995

    SciTech Connect

    1995-09-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (April--June 1995) and includes copies of Orders sent by the Nuclear Regulatory Commission to individuals with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC. The Commission believes this information may be useful to licensees in making employment decisions.

  18. Magnetic relaxation - coal swelling, extraction, pore size. Quarterly technical progress report, April 1, 1994--June 31, 1994

    SciTech Connect

    Doetschman, D.C.

    1994-08-01

    Work this quarter involved a CW EPR examination of the density separated fractions of the Lewiston-Stockton Argonne Coal and the initiation of EPR studies to probe molecular motion in coal pores. Eighteen densities between 1.24 g/cm{sup 3} and 1.56 g/cm{sup 3} were separated and combined into seven density ranges. Radicals with a narrow EPR line appear only in the samples with densities above 1.48 g/cm{sup 3}.

  19. Bench-scale testing of on-line control of column flotation using a novel analyzer. Second quarterly technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect

    Not Available

    1993-04-16

    This document contains the second quarterly technical progress report for PTI`s Bench-Scale Testing Project of a circuit integrating PTI`s KEN-FLOTE{trademark} Column Flotation Technology and PTI`s On-Line Quality Monitor and Control System. The twelve-month project involves installation and testing of a 200--300 lb/hr. bench-scale testing circuit at PETC`s Coal Preparation Process Research Facility (CPPRF) for two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). The project schedule timeline by task series for the twelve month project, as it was laid out in the initial Project Work Plan. At the present time, all tasks are progressing according to schedule with the exception of the Task 800 Circuit Testing and Sample Prep and Task 1000 Circuit Decommissioning, which have slipped approximately five weeks due to delays incurred within in the project.

  20. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, 3rd quarter, 1994

    SciTech Connect

    Wehner, S.; Smith, V.; Cole, R.; Brugman, B.; Vogt, J.

    1994-10-18

    The principal objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s (DOE) objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Texaco Exploration and Production Inc`s. (TEPI) long-term plans are to implement a full-scale miscible CO{sub 2} project in the CVU. However, the current market precludes acceleration of such a capital intensive project. The DOE partnership provides some relief to the associated R and D risks, allowing TEPI to evaluate a proven Gulf-coast sandstone technology in a waterflooded carbonate environment. Technical progress is described on the following studies: Porosity and permeability relationships; Initial water saturation and oil-water contact; Geostatistical realization; and Parametric simulation.

  1. CO{sub 2} Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Quarterly technical progress report, Fourth quarter 1995

    SciTech Connect

    Wehner, S.; Prieditis, J.

    1996-02-05

    The principle objective of the Central Vacuum Unit (CVU) CO{sub 2} Huff-n-Puff (H-n-P) project is to determine the feasibility and practicality of the technology in a waterflooded shallow shelf carbonate environment. The results of parametric simulation of the CO{sub 2} H-n-P process, coupled with the CVU reservoir characterization components will determine if this process is technically and economically feasible for field implementation. The technology transfer objective of the project is to disseminate the knowledge gained through an innovative plan in support of the Department of Energy`s objective of increasing domestic oil production and deferring the abandonment of shallow shelf carbonate (SSC) reservoirs. Texaco Exploration and Production Inc`s. (TEPI) mid-term plans are to implement a full-scale miscible CO{sub 2} project in the CVU. TEPI has concluded all of the Tasks associated with the First Budget Period. The DOE approved the TEPI continuation application. Budget Period No. 2 is now in progress. Initial injection of CO{sub 2} began in November, and after a short shut-in period for the soak, the well was returned to production in late December, 1995.

  2. Combustion of pulverized coal in vortex structures. Quarterly progress report No. 8, July 1, 1995--September 30, 1995

    SciTech Connect

    Gollahalli, S.R.

    1995-10-01

    This eighth quarterly report describes the activities and accomplishments of the research team at the University of Oklahoma, Norman, Oklahoma, related to the project entitled {open_quotes}Combustion of Pulverized Coal in Vortex Structures{close_quotes} during the period July 1, 1995 to September 30, 1995. The work performed in this quarter consisted of the following four tasks: (i) Completion of the schlieren flow visualization experiments, (ii) Conducting experiments with particulate laden shear layers in cold flow to measure mean velocity and turbulence intensity field, (iii) Conducting experiments with particulate laden shear layers in heated flow where the initial temperature was above the pyrolysis temperature of the coal, (iii) Conducting experiments with particulate laden shear layers in heated flow where the initial temperature was above the ignition temperature of the coal, and (iv) Revising and preparing the final version of a paper for the Energy Conference to be held in Houston in 1996. A 90-day no-cost extension of the project was obtained. In the final quarter, we plan to complete this work by conducting the final task of measuring concentration fields.

  3. A calcium oxide sorbent process for bulk separation of carbon dioxide. Quarterly progress report 19, January--March, 1994

    SciTech Connect

    Harrison, D.P.

    1994-04-01

    This research project is investigating the technical feasibility of a high-temperature, high-pressure (HTHP) process for the bulk separation of CO{sub 2} from coal-derived gas. Indirect evidence which suggested that the water-gas shift reaction occurred simultaneously with CO{sub 2} removal was found. Occurrence of the simultaneous reactions created the possibility of a direct one-step process for the manufacture of hydrogen from coal-gas while at the same time separating a concentrated stream of CO{sub 2}. Previous quarterly reports have described the design, construction, and commissioning of the fixed-bed reactor, development of analytical procedures, and results of a number of tests using dolomite sorbent precursor. During the current quarter, additional tests were carried out to study the effects of calcination gas composition, temperature, and space velocity using the standard dolomite sorbents. Alternate sorbents were tested to provide direct comparison of dolomite and limestone performance. Tests were performed using an empty reactor and reactor packed with commercial shift catalyst to learn more of the characteristics of the shift reaction in the absence of carbonation. Toward the end of the quarter, emphasis changed to sorbent durability and a number of multicycle tests were completed.

  4. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, April--June 1992

    SciTech Connect

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1992-08-26

    Research in this project centers upon developing a new approach to the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates all aspects of the coal liquefaction process including coal selection, pretreatment, coal swelling with catalyst impregnation, coal liquefaction experimentation, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. The project is being carried out under contract to the United States Department of Energy. On May 28, 1992, the Department of Energy authorized starting the experimental aspects of this projects; therefore, experimentation at Amoco started late in this quarterly report period. Research contracts with Auburn University, Pennsylvania State University, and Foster Wheeler Development Corporation were signed during June, 1992, so their work was just getting underway. Their work will be summarized in future quarterly reports. A set of coal samples were sent to Hazen Research for beneficiation. The samples were received and have been analyzed. The literature search covering coal swelling has been up-dated, and preliminary coal swelling experiments were carried out. Further swelling experimentation is underway. An up-date of the literature on the liquefaction of coal using dispersed catalysts is nearing completion; it will be included in the next quarterly report.

  5. Strategic Petroleum Reserve quarterly report

    SciTech Connect

    Not Available

    1993-08-15

    This Quarterly Report highlights activities undertaken during the second quarter of calendar year 1993, including: inventory of petroleum products stored in the Reserve, under contract and in transit at the end of the calendar quarter; fill rate for the current quarter and projected fill rate for the next calendar quarter; average price of the petroleum products acquired during the calendar quarter; current and projected storage capacity and plans to accelerate the acquisition or construction of such capacity; analysis of existing or anticipated problems with the acquisition and storage of petroleum products, and future expansion of storage capacity; funds obligated by the Secretary from the SPR Petroleum Account and the Strategic Petroleum Reserve Account during the prior calendar quarter and in total; and major environmental actions completed, in progress, or anticipated.

  6. Liquefaction of coals using ultra-fine particle, unsupported catalysts: In situ generation by rapid expansion of supercritical fluid solutions. Quarterly technical progress report, January 1, 1991--March 31, 1991

    SciTech Connect

    Not Available

    1991-09-01

    The program objective is to generate ultra-fine catalyst particles (20 to 400 {Angstrom} in size) and quantify their potential for improving coal dissolution in the solubilization stage of two-stage catalytic-catalytic liquefaction systems. In the first quarterly report for this program the concept behind our approach was detailed, the structure of the program was presented, key technical issues were identified, preliminary designs were outlined, and technical progress was discussed. All progress made during the second quarter of this program related to experiment design of the proposed supercritical expansion technique for generating ultra-fine, iron compound, catalyst particles. This second quarterly report, therefore, presents descriptions of the final designs for most system components; diagnostic approaches and designs for determining particles size and size distributions, and the composition of the pre-expansion supercritical solution; and the overall technique progress made during this reporting period. 6 refs., 15 figs., 1 tab.

  7. Development of molten carbonate fuel cell power plant. Quarterly technical progress report, February 1-April 30, 1980

    SciTech Connect

    Peterson, J. R.

    1980-01-01

    Work has been initiated during this first quarter under all four program tasks and by all major participants as described. Task 1.0 activity (establish power plant reference design) concentrated upon definition of user requirements and establishment of power plant subsystem alternatives and characteristics. Task 2.0 work (stack and cell design development and verification) was initiated with a heavy emphasis upon test facilities preparation. A total of 27 laboratory cells were operated during this reporting period and a total of nine cells continued on test at the end of the quarter. Investigation of alternative anode and cathode materials proceeded; a dual-porosity anode was fabricated and tested. Over 10,000 endurance hours on a state-of-the-art cell carried-over from a previous program has been achieved and 1500 hours endurance has been obtained with sheet metal cells. Results presented for electrolyte structure development include comparative data for spray-dried and modified aqueous slurry process powders. Shake-down tests with a rotating disc electrode apparatus for fundamental measurements are described. Concept designs for both prototype and subscale stacks have been identified. Task 3.0 effort (development capability for full-scale stack tests) included preparation of an overall test plan to commercialization for molten carbonate fuel cells and of a functional specification for the tenth-scale stack test facility; drafts of both documents were completed for internal review. Cost-effective manufacturing assessment of available designs and processes was initiated. Task 4.0 work (develop capabilities for operation of stacks on coal-derived gas) included gathering of available contaminants concentration and effects information and preparation of initial projections of contaminant ranges and concentrations. Accomplishments to date and activities planned for the next quarter are described.

  8. Enforcement actions: Significant actions resolved reactor licensees. Volume 14, No. 2, Part 2, Quarterly progress report, April--June 1995

    SciTech Connect

    1995-08-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (April--June 1995) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to reactor licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication.

  9. Enforcement actions: Significant actions resolved material licensees (non-medical). Quarterly progress report, October 1994--December 1994

    SciTech Connect

    1995-02-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (October - December 1994) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to material licensees (non-medical) with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication.

  10. Enforcement actions: Significant actions resolved medical licensees. Quarterly progress report, January 1995--March 1995. Volume 14, No. 1, Part 2

    SciTech Connect

    1995-05-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (January-March 1995) and includes copies of letters, Notices, and Orders sent by the Nuclear Regulatory Commission to medical licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication.

  11. Development of tailored ceramics for geologic storage of nuclear wastes. Quarterly progress report, January 1-March 31, 1980

    SciTech Connect

    Not Available

    1980-05-15

    In the second quarter of activities on developing Tailored Ceramic waste forms for SRP waste compositions, emphasis was on the chemistry controlling the incorporation of the waste elements into the crystalline phases of the high-alumina content ceramic and the major factors affecting the consolidation process. Research on the design and synthesis of oxide and phosphate ceramic waste forms has continued with emphasis on fluorite-structure oxides and on rare earth phosphates with the monazite structure. Dissolution studies to date indicate that monazite is very stable.

  12. Production and screening of carbon products precursors from coal. Quarterly progress report, July 1, 1996--September 30, 1996

    SciTech Connect

    Zondlo, J.; Stiller, A.

    1996-10-25

    This quarterly report covers activities during the period from July 1, 1996 through September 30, 1996 on the development of carbon products precursor materials from coal. The first year of the project ended in February, 1996; however, the WVU research effort continued through August 14, 1997 on a no-cost extension of the original contract. PETC chose to exercise the option for continuation of the projects and $100,000 became available on August 9, 1996. The objective for year two is to focus on development of those carbon products from coal-based solvent extract precursors which have the greatest possibility for commercial success.

  13. Bioconversion of coal derived synthesis gas to liquid fuels. Quarterly technical progress report, October 1, 1994--December 27, 1994

    SciTech Connect

    Jain, M.K.; Worden, R.M.; Grethlein, A.

    1995-01-16

    The overall objective of the project is to develop an integrated two-stage fermentation process for conversion of coal-derived synthesis gas to a mixture of alcohols. This is achieved in two steps. In the first step, Butyribacterium methylotrophicum converts carbon monoxide (CO) to butyric and acetic acids. Subsequent fermentation of the acids by Clostridium acetobutylicum leads to the production of butanol and ethanol. The tasks for this quarter were: (1) Development/isolation of superior strains for fermentation of syngas; (2) Evaluation of bioreactor configuration for improved mass transfer of syngas, specifically gas lift; (3) Pervaporation for recovery of solvents; (4) Write and submit final report.

  14. Enforcement actions: Significant actions resolved reactor licensees. Quarterly progress report, October--December 1994, Volume 13, No. 4, Part 1

    SciTech Connect

    1995-02-01

    This compilation summarizes significant enforcement actions that have been resolved during one quarterly period (October--December 1994) and includes copies of letters Notices, and Orders sent by the Nuclear Regulatory Commission to reactor licensees with respect to these enforcement actions. It is anticipated that the information in this publication will be widely disseminated to managers and employees engaged in activities licensed by the NRC, so that actions can be taken to improve safety by avoiding future violations similar to those described in this publication.

  15. Advanced coal gasification system for electric power generation. Third quarterly progress report, April 1-June 30, 1980

    SciTech Connect

    1980-07-25

    The operation, maintenance and modifications to the Westinghouse gasification process development unit during the quarter are reviewed. The tests of the gasifier-agglomerator included direct coal feed as well as oxygen-blown gasification of a char or coal bed. Then the whole system was tested in single and double stage operation. Laboratory support involved fluidized bed test facilities at ambient temperature and at design temperature for devolatilization and gasification studies. Other laboratory systems were related to thermal analysis and pressurized high temperature studies of gasification and gas cleaning. (LTN)

  16. Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report 3, April--June 1993

    SciTech Connect

    McCormick, R.L.; Jha, M.C.; Streuber, R.D.

    1993-08-20

    This document is the third quarterly technical progress report under Contract No. AC22-92PC92110, ``Development of Vanadium-Phosphate Catalysts for Methanol Production by Selective Oxidation of Methane.`` During this quarter, we have continued to develop methods for catalyst activation by investigating activation in wet gas environments. This procedure leads to the formation of highly crystalline (VO){sub 2}P{sub 2}O{sub 7}, while activation under identical conditions, but with no moisture, leads to a poorly crystalline sample. Published data indicate that the highly crystalline form is representative of commercial butane oxidation catalysts. The main focus of our work during this quarter has been in the area of catalyst testing in the microreactor system. In order to confirm that our microreactor system was providing reliable data, we tested a V{sub 2}O{sub 5}/SiO{sub 2} catalyst at atmospheric pressure and temperatures from 500 to 600{degree}C using 90 to 95 percent CH{sub 4}/O{sub 2}. Several studies of methane oxidation using this catalyst have been published with reasonably good agreement between different research groups. We were not able to reproduce the literature data using steel reactors. However, when the steel reactor was lined with quartz and the postcatalyst reactor volume was minimized by packing with quartz chips, we obtained results which agree closely with those previously published. Using the same quartz reactor and test conditions, we also tested a highly crystalline (wet activated) VPO catalyst.

  17. Desulfurization of coal with hydroperoxides of vegetable oils. [Quarterly progress report], December 1, 1994--February 28, 1995

    SciTech Connect

    Smith, G.V.; Gaston, R.D.; Song, Ruozhi; Cheng, Jianjun; Shi, Feng; Gholson, K.L.; Ho, K.K.

    1995-12-31

    This project proposes a new method for removing organic sulfur from Illinois coals using readily available farm products. It proposes to use air and vegetable oils to disrupt the coal matrix, oxidize sulfur forms, increase volatiles, and desulfurize coal. This will be accomplished by impregnating coals with polyunsaturated oils, converting the oils to their hydroperoxides, and heating. Since these oils are relatively inexpensive and easily applied, this project could lead to a cost effective method for removing organic sulfur from coals. Moreover, the oils are environmentally safe; they will produce no noxious products and will improve burning qualities of the solid products. Preliminary experiments showed that IBC 104 coal catalyzes the formation of hydroperoxides in safflower oil and that more sulfur is extracted from the treated than untreated coal. During the first quarter the requirement of an added photosensitizer was eliminated, the catalytic effect of coal was confirmed, and the existence of a complex set of reactions was revealed. During this second quarter working with IBC-108 coal (2.3% organic S. 0.4% pyrite S), the effects of different ratios of oil:coal, different extraction solvents, and different temperatures were examined. A new pretreatment which combines alkali with linseed oil was discovered. Best organic sulfur removal is approximately 26% using alkali pretreatment combined with linseed oil at 1OO{degree}C. BTU loses can be kept to a minimum of 3% with proper use of solvents.

  18. Advanced sulfur control concepts in hot-gas desulfurization technology. Quarterly technical progress report, July--September 1995

    SciTech Connect

    Harrison, D.P.

    1995-10-01

    Both the Antek total sulfur analyzer and the modifications to the Shimadzu GC-14A gas chromatograph to be used for analysis for SO{sub 2} and H{sub 2}S were delivered during the quarter. Problems were faced during the installation and calibration phases of both instruments. By the end of the quarter we believe that the GC problems have been solved, but problems remain with the Antek analyzer. It appears that too much sulfur (as SO{sub 2}) reaches the UV detector and causes it to become saturated. This shows up as a maximum in the instrument calibration curve. At 200 psia, the capillary flow restrictor allows a total flow rate of about 180 sccm, and the maximum occurs at about 1 % H{sub 2}S in the calibration gas. Reducing the pressure so that the total flow is reduced to about 25 sccm shifts the calibration curve maximum to about 5.7% H{sub 2}S. It appears that we must reduce the total flow rate to the detector or provide additional dilution. This may be accomplished by increasing the resistance of the capillary restrictor, by diverting a portion of the flow leaving the pyrotube to vent, or adding an inert such as N{sub 2} to the gases exiting the pyrotube. We are in contact with Antek representatives about the problem. Both the atmospheric pressure and high pressure electrobalances were used during the quarter to study the regeneration of FeS in atmospheres of O{sub 2}/N{sub 2} or H{sub 2}O/N{sub 2}. In the atmospheric pressure unit the effects of temperature (600 - 800{degrees}C), flow rate (130 - 500 sccm), and reactive gas mol fraction (0.005 to 0.03 O{sub 2} and 0.1 to 0.5 H{sub 2}O) are being studied. Regeneration tests completed to date in the high pressure unit have utilized only O{sub 2}/N. and the parameters studied include temperature (600 - 800{degrees}C), flow rate (500 - 1000 sccm), pressure (1 - 15 atm) ad O{sub 2} mol fraction (0.005 - 0.03).

  19. High temperature electrochemical separation of H{sub 2}S from coal gasification process streams. Quarterly progress report, April 1, 1992--June 30, 1992

    SciTech Connect

    Winnick, J.

    1992-10-01

    An advanced process for the separation of hydrogen sulfide from coal gasification product streams through an electrochemical membrane is being developed using the funds from this grant. H{sub 2}S is removed from the syn-gas stream, split into hydrogen, which enriches the syn-gas, and sulfur, which can be condensed from an inert gas sweep stream. The process allows removal of H{sub 2}S without cooling the gas stream and with negligible pressure loss through the separator. The process is economically attractive by the lack of adsorbents and the lack of a Claus process for sulfur recovery. Research conducted during the present quarter is here highlighted, with an emphasis on progress towards the goal of an economically viable H{sub 2}S removal technology for use in coal gasification facilities providing polished fuel for co-generation coal fired electrical power facilities and Molten Carbonate Fuel Cell electrical power facilities.

  20. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report, April 1996--June 1996

    SciTech Connect

    Tao, D.; Groppo, J.G.; Parekh, B.K.

    1996-07-31

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from April 1 - June 30, 1996.

  1. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report, No. 4, July 1995--September 1995

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1995-11-06

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from July 1 - September 29, 1995.

  2. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report 2, January 1995--March 1995

    SciTech Connect

    Groppo, J.G.; Parekh, B.K.

    1995-05-05

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1 to March 31, 1995.

  3. High temperature membranes for H{sub 2}S and SO{sub 2} separations. Quarterly progress report, October 1, 1991--December 31, 1991

    SciTech Connect

    Winnick, J.

    1991-12-31

    High temperature membrane separation techniques have been applied to gas mixtures involved in coal utilization. For coal gasification, H{sub 2}S has been removed from the syn-gas stream, split into hydrogen, which enriches the syn-gas, and sulfur, which can be condensed from an inert gas sweep stream. For coal combustion, SO{sub 2} has been separated from the flue gas, with concentrated SO{sub 3} produced as a by-product. Both processes appear economically viable but each requires fundamental improvements: both the H{sub 2}S cell and the SO{sub 2} cell require more efficient membranes and the H{sub 2}S cell needs a more efficient anode. Membranes will be fabricated by either hot-pressing, impregnation of sintered bodies or tape casting. Research conducted during the present quarter is highlighted, with an emphasis on progress towards these goals.

  4. Research and development for the declassification productivity initiative. Quarterly report, January 1997--August 1997

    SciTech Connect

    Bessonet, C.G. de

    1997-03-05

    The highlight for the first quarter was the presentation of research progress and findings at the DPI Symposium on March 5, 1997. Since that presentation, additional progress was slowed down due to the decreased budget funding for year two, and consequently, the decrease in time-effort of the principal investigators. This report summarizes the progress in each of the topical areas to date. A research article has been prepared for publication for the Optical Character Recognition project; two progress reports are included for the Logical Analysis project; and two progress reports for the Knowledge Representation project. Research activities for the Tipster Technology project will resume this fall.

  5. Bench-scale testing of on-line control of column flotation using a novel analyzer. Quarterly technical progress report, September 21, 1992--December 31, 1992

    SciTech Connect

    Not Available

    1992-01-22

    This document contains the first quarterly technical progress report for PTI`s Bench-Scale Testing Project of a circuit integrating PTI`s KEN-FLOTETM Column Flotation Technology and PTI`s On-Line Quality Monitor Control System. The twelve-month project will involve installation of a 300 lb/hr. bench-scale testing circuit at PETC`s Coal Preparation Process Research Facility (CPPRF) and testing of two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). Figure 1 contains the project plan as well as the approach to completing the major tasks within the twelvemonth project. The project is broken down into three phases, which include: Phase I - Preparation: The preparation phase was performed principally at PTI`s Calumet offices from October through December, 1992. It involved building of the equipment and circuitry, as well as some preliminary design and equipment testing. Phase II - ET Circuit Installation and Testing: This installation and testing phase of the project will be performed at PETC`s CPPRF from January through May, 1993, and will be the major focus of the project. It will involve testing of the continuous 300 lb/hr. circuit. Phase II - Project Finalization: The project finalization phase will occur from June through September, 1993, at PTI`s Calumet offices and will involve finalizing analytical work and data evaluation, as well as final project reporting. This quarterly progress report principally summarizes the results from the Phase I preparation work and the plan for the early portions of the Phase 11 installation and commissioning, which will occur in January and the first week of February, 1993.

  6. Bench-scale testing of on-line control of column flotation using a novel analyzer. Third quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Not Available

    1993-08-24

    This document contains the third quarterly technical progress report for PTI`s Bench-Scale Testing Project of a circuit integrating PTI`s KEN-FLOTETM Column Flotation Technology and PTI`s On-Line Quality Monitor and Control System. The twelve-month project involves installation and testing of a 200--300 lb/hr. bench-scale flotation circuit at PETC`s Coal Preparation Process Research Facility (CPPRF) for two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). Figure 1 contains the project plan, as well as the approach to completing the major tasks within the twelve-month project schedule. The project is broken down into three phases, which include: Phase I -- Preparation: The preparation phase was performed principally at PTI`s Calumet offices from October through December, 1992. It involved building of the equipment and circuitry, as well as some preliminary design and equipment testing; Phase II -- ET Circuit Installation and Testing: This installation and testing phase of the project was performed at PETC`s CPPRF from January through June, 1993, and was the major focus of the project. It involved testing of the continuous 200--300 lb/hr. circuit; and Phase III -- Project Finalization: The project finalization phase is occurring from July through September, 1993, at PTI`s Calumet offices and involves finalizing analytical work and data evaluation, as well as final project reporting. This Third Quarterly Technical Progress Report principally summarizes the results from the benchscale testing with the second coal (Pittsburgh No. 8 Seam Coal), which occurred in April through June, 1993. It also contains preliminary economic evaluations that will go into the Final Report, as well as the plan for the final reporting task.

  7. Configurational diffusion of asphaltenes in fresh and aged catalyst extrudates. Quarterly progress report, December 20, 1995--March 20, 1996

    SciTech Connect

    Guin, J.A.

    1996-07-01

    The objective of this research is to determine the relationship between the size and shape of coal and petroleum macromolecules and their diffusion rates i.e., effective diffusivities, in catalyst pore structures. That is, how do the effective intrapore diffusivities depend on molecule configuration and pore geometry? This quarter, adsorptive diffusion of both coal and petroleum asphaltenes in THF into porous catalysts were performed. A mathematical model with linear adsorption isotherm for asphaltene diffusion was developed. The molecular weight distribution of both asphaltenes were ascertained by GPC using polystyrene standards. The asphaltene diffusion data were simulated fairly well by the mathematical model, and linear adsorption constants were obtained for asphaltene fractions with different equivalent polystyrene molecular weights.

  8. Vapor pressures and heats of vaporization of primary coal tars. Quarterly technical progress report, July 1 - September 31, 1996

    SciTech Connect

    Suuberg, E.M.; Oja, V.; Lilly, W.D.

    1996-12-31

    The vapor pressure correlations that exist at present for coal tars are very crude and they are not considered reliable to even an order of magnitude. This project seeks to address this important gap in the near term by direct measurement of vapor pressures of coal tar fractions, by application of well-established techniques and modifications thereof. The principal objectives of the program are to: (1) obtain data on the vapor pressures and heats of vaporization of tars from a range of ranks of coal; (2) develop correlations based on a minimum set of conveniently measurable characteristics of the tars; and (3) develop equipment that would allow performing such measurements in a reliable, straightforward fashion. During this quarter we have extended the work on measurements of vapor pressures of coal tars, using the continuous Knudsen effusion technique. These results need further analysis and therefore in this report we describe only the general idea behind the technique, and also show some typical results.

  9. Photovoltaic mechanisms in polycrystalline thin film silicon solar cells. Quarterly technical progress report No. 1, July 30-October 31, 1980

    SciTech Connect

    Sopori, B.

    1980-07-30

    Major accomplishments during the first quarter of the contract period are reported. Small area diode fabrication and analysis has been continued. This technique has further been applied to many RTR ribbons. An optical technique for determination of crystallite orientations has been placed in operation. This technique has many distinct advantages. These are: (1) rapid; (2) can be set-up very inexpensively; (3) well suited for polycrystalline substrates of small grain size; and (4) can easily characterize twins. Accuracies obtained with this technique are about the same as that of the Laue technique. A technique to qualitatively evaluate grain boundary activity in unprocessed substrates has been used and valuable results obtained. Further analysis is being done to use this technique for quantitative evaluation. A major study of G.B. orientation effects is underway. Initial results on RTR ribbons have shown a good correlation of G.B. barrier height with misorientation (tilt boundaries).

  10. An advanced control system for fine coal flotation. Fifth quarterly technical progress report, October 1, 1996--December 31, 1996

    SciTech Connect

    Adel, G.T.; Luttrell, G.H.

    1997-03-04

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on- line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as reagent dosage, pulp density and pulp level are adjusted using model-base control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the fifth quarter of this project, all work was on hold pending the final novation of the contract to Virginia Polytechnic Institute and State University.

  11. Development of high-efficiency solar cells on silicon web. Seventh quarterly progress report, October 1-December 31, 1985

    SciTech Connect

    Meier, D.L.; Greggi, J.; Rai-Choudhury, P.

    1986-03-06

    The seventh quarterly report describes the results of work aimed at identifying and reducing sources of carrier recombination both in the starting web silicon material and in the processed cells. Cross-sectional TEM measurements of several web cells have been made and analyzed. The effect of the heavily twinned region on cell efficiency has been modeled, and the modeling results compared to measured values for processed cells. The effects of low-energy, high-dose hydrogen ion implantation on cell efficiency and diffusion length have been examined. Cells have been fabricated from web silicon known to have a high diffusion length, with a new double-layer antireflection coating being applied to these cells. A new contact system, to be used with oxide-passivated cells and which greatly reduces the area of contact between metal and silicon, has been designed. Finally, the application of DLTS measurements to beveled samples has been further investigated.

  12. Rheological properties essential for the atomization of coal water slurries (CWS). Quarterly progress report, March 15--June 15, 1993

    SciTech Connect

    Ohene, F.

    1993-09-01

    The overall objective of this project is to perform experiments to understand the effect of high shear and extensional properties on the atomization of coal-water slurries (CWS). In the atomization studies, the mean drop size of the CWS sprays will be determined at various air-to CWS. A correlation between the extensional and high shear properties, particle size distributions and the atomization will be made in order to determine the influence of these parameters on the atomization of CWS. A theoretical relationship between the sauter mean diameter, (SMD), the Air/Fuel ratio and the viscosity was derived during the previous quarter. The established relationship was modified to account for the high shear viscosity data.

  13. Configurational diffusion of asphaltenes in fresh and aged catalysts extrudates. Quarterly progress report, June 20, 1992--September 20, 1992

    SciTech Connect

    Guin, J.A.; Tarrer, A.R.

    1992-12-01

    The objective of this research is to determine the relationship between the size and shape of coal and petroleum macromolecules and their diffusion rates i.e., effective diffusivities, in catalyst pore structures. That is, how do the effective intrapore diffusivities depend on molecule configuration and pore geometry. Based on the work done, the following conclusions can be drawn: The intrapore diffusional model can be set up mathematically based on certain assumptions, and the mathematical model can be solved numberically; the numerical solution discussed in this quarterly report can be used for typical situations given suitable values for parameters E, R and n; comparison with known solutions for special cases shows the numerical solution to be accurate.

  14. Surfactant studies for bench-scale operation. Fourth quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Hickey, G.S.; Sharma, P.K.

    1993-07-23

    A phase 2 study has been initiated to investigate surfactant- assisted coal liquefaction, with the objective of quantifying the enhancement in liquid yields and product quality. This report covers the fourth quarter of work. The major accomplishments were (1) Completion of coal liquefaction autoclave reactor runs and related analysis with Illinois {number_sign}6 coal with time as a variable at 375{degree}C, and pressures of 1800 psig; (2) an investigation into the mechanism of the effect that the lignosulfonate surfactant has in enhancing liquefaction yields; and (3) completion of a bench-scale test with the surfactant in the continuous flow Catalytic Two Stage Liquefaction Process (CTSL) reactor at HRI.

  15. Field study of disposed wastes from advanced coal processes. Quarterly technical progress report, October--December 1992

    SciTech Connect

    Not Available

    1992-12-31

    The specific objectives for the reporting period of October, 1992 to December, 1992 were as follows: (1) Finish analyzing leachates from the third annual core samples from the Ohio site, collected in August 1992; (2) Collect and analyze the sixth quarterly water samples from the first Illinois test case in August, 1992. Make field measurements and collect data from the data logger; (3) Begin construction of the second Illinois test case; (4) Continue production of a video presentation on the project; (5) Load all remaining EERC data on the Colorado and Ohio sites into the project database; (6) Finalize plans with METC for continued monitoring at the Colorado and Ohio sites beyond the initial three year period, and (7) Submit and the Final Case Report on the Colorado site to the DOE and EPRI.

  16. Bioconversion of coal-derived synthesis gas to liquid fuels. Quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Jain, M.K.; Worden, R.M.; Grethlein, H.

    1993-07-16

    The overall objective of the project is to develop two stage fermentation process for conversion of coal-derived synthesis gas to a mixture of alcohols. This is achieved in two steps. In the first step, B .methylotrophicum converts carbon monoxide (CO) to butyric and acetic acids. Subsequent fermentation of the acids by Clostridium acetobutylicum leads to the production of butanol and ethanol. The tasks for this quarter were: Development/isolation of superior strains for fermentation of syn gas; optimization of process conditions for fermentation of syn gas; evaluation of bioreactor configuration for improved mass transfer of syn gas; and optimization of process conditions for reducing carbon and electron loss by H{sub 2}-CO{sub 2} fermentation.

  17. Oxidation of coal and coal pyrite mechanisms and influence on surface characteristics. [Quarterly] technical progress report, April--June 1993

    SciTech Connect

    Doyle, F.M.

    1993-06-30

    The objective of this research is to develop a mechanistic understanding of the oxidation of coal and coal pyrite, and to correlate the intrinsic physical and chemical properties of these minerals, along with changes resulting from oxidation, with those surface properties that influence the behavior in physical cleaning processes. The results will provide fundamental insight into oxidation, in terms of the bulk and surface chemistry, the microstructure, and the semiconductor properties of the pyrite. During the eleventh quarter, dry thermal oxidation tests were done on coal samples from the Pennsylvania State Coal Bank. As-received and oxidized coal samples were studied by ion-exchange methods to determine the carboxylate and phenolic group concentrations. Film flotation tests were done to characterize the flotability of as-received and oxidized coals. In addition, electrokinetic tests were done on different coals, to obtain information pertinent to the selection of flotation reagents. DRIFT analysis was done to characterize the structure of coals.

  18. Rhelogical properties essential for the atomization of coal water slurries (CWS). Quarterly progress report, June 15, 1992--September 15, 1992

    SciTech Connect

    Ohene, F.

    1992-12-31

    The overall objective of this project is to perform experiments to understand the effect of high shear and extensional properties on the atomization of coal-water slurries (CWS). In the atomization studies, the mean drop size of the CWS sprays will be determined at various air-to CWS. A correlation between the extensional and high shear properties, particle size distributions and the atomization will be made in order to determine the influence of these parameters on the atomization of CWS. During the past quarter, several experimental studies on pressure dependent atomization of Coal-water slurries and simulated fluids were performed. Also surface tension, elastic, high and low shear viscosities were performed. These tests were performed to initiate the understanding of the fundamental parameters that govern the atomization process of CWS.

  19. Assistance to the states with risk based data management. Quarterly technical progress report, April 1--June 30, 1995

    SciTech Connect

    Paque, M.J.

    1995-07-28

    The Tasks of this project are to: (1) complete implementation of a Risk Based Data Management System (RBDMS) in the States of Alaska, Mississippi, Montana, Nebraska; and (2) conduct Area of Review (AOR) Workshops in the states of California, Oklahoma, Kansas, and Texas. The RBDMS was designed to be a comprehensive database with the ability to expand into multiple areas, including oil and gas production. The database includes comprehensive well information for both producing and injection wells. It includes automated features for performing functions redated to AOR analyses, environmental risk analyses, well evaluation, permit evaluation, compliance monitoring, operator bonding assessments, operational monitoring and tracking, and more. This quarterly report describes the status of the development of the RBDMS project in both stated tasks and proposes further steps in its implementation.

  20. A novel carbon-based process for flue gas cleanup. Fourth quarterly technical progress report, April 1--June 30, 1992

    SciTech Connect

    Gangwal, S.K.; Silveston, P.L.

    1992-07-01

    The objective of this project is to demonstrate the preliminary technical and economic feasibility of a novel carbon-based process for removal of at least 95% SO{sub 2} and at least 75% NO{sub x} from coal combustion flue gas. In the process, flue gas leaving the electrostatic precipitator (ESP) is passed through a trickle bed of activated carbon catalyst employing a periodic flush of low strength sulfuric acid. The SO{sub 2} is oxidized to SO{sub 3} and removed as medium strength sulfuric acid. The SO{sub 2}-free flue gas is then mixed with NH{sub 3}, and the NO{sub x} in the gas is subjected to selective catalytic reduction (SCR) to N{sub 2} over a fixed bed of activated carbon catalyst. In the previous three quarters, a detailed project management plan was prepared describing the experimental setup, work plan, and test plan. The experimental system was completed for SO{sub 2} conversion at Waterloo and for NO{sub x} conversion at RTI. Shakedown experiments were completed. In the present quarter, the NO{sub x} removal performance of two additional modified carbon catalysts (MCCII and MCCIII) was studied. MCCII showed NO{sub x} removal efficiency which was similar to that observed for MCCI. However, MCCI was considerably less active for NO{sub x} removal. SO{sub 2} removal experiments with NO present in the feed gas were performed with MCCI. SO{sub 2} removal efficiency was consistently about 98% over each of 10 cycles and was very similar to that observed earlier with no NO present in the feed. Finally, a preliminary economic evaluation of the process was performed and a project review meeting was held. The economic evaluation showed that the Rn-Waterloo process was competitive with SCR/IFGD and other combined SO{sub 2}/NO{sub x}, removal processes.

  1. Fine particle clay catalysts for coal liquefaction. Quarterly technical progress report, November 9, 1992--February 8, 1993

    SciTech Connect

    Olson, E.S.

    1995-10-01

    The mixed iron/alumina pillared clay catalysts and clay-supported iron catalysts have been shown in previous reports of this project to significantly improve yields of heptane-soluble products obtained in the liquefaction of both as received and acid-exchanged Wyodak subbituminous coal and Blind Canyon bituminous coal. In this quarter, the soluble product (LSW) obtained from the noncatalytic low-severity liquefaction of Wyodak coal was used as a feed to determine the activity of iron based catalysts for the hydrogenation and depolymerization steps. Comparison data for liquefaction of the soluble LSW with other catalysts were desired, and these data were obtained for a dispersed form of iron sulfide, prepared via iron hydroxyoxide (PETC method). The iron oxyhydroxide catalyst was directly precipitated on LSW product using either water or ethanol as the solvent. An insight into the functioning of the mixed iron/alumina pillared clay in coal liquefaction was investigated by preparing and studying an iron oxoaluminate structure. An investigation of new methods for the production of tetralin soluble iron oxometallate catalysts and the determination of their catalytic activities was continued in this quarter. The hydrogenation activity of iron oxoaluminate was investigated using pyrene and 1-methylnaphthalene as the test compounds, and results were compared with thermal reactions. In order to determine the loss of activity, recovered catalyst was recycled a second time for the hydrotreating of pyrene. Reaction of 1-methylnaphthalene with iron oxoaluminate also gave very high conversion to 1- and 5-methyltetralins and small amount of 2- and 6-methyltetralins. Liquefaction of Wyodak subbituminous and Blind Canyon bituminous coal was investigated using an in situ sulfided soluble iron oxoaluminate catalyst.

  2. Fine particle clay catalysts for coal liquefaction. Quarterly technical progress report, February 9, 1993--May 8, 1993

    SciTech Connect

    Olson, E.S.

    1995-10-01

    An investigation of new methods for the production and utilization of tetralin-soluble iron oxometallate precursors for coal liquefaction catalysts was continued in this quarter. Further descriptions of the catalytic activities of the sulfided forms were obtained. The hydrogenation activities of catalysts derived from iron oxotitanate and cobalt oxoaluminate were investigated using pyrene as a the test compound, and results were compared with thermal reactions. The hydrogenation activity of iron oxotitanate was superior to other catalysts including iron oxoaluminate. The hydrogenation activity of cobalt oxoaluminate was similar to that of iron oxoaluminate reported in previous quarterly report. The liquefaction of Wyodak subbituminous coal was investigated using in situ sulfided iron oxotitanate catalyst. In order to improve the usefulness of iron oxoaluminate as a liquefaction catalyst, iron oxoaluminate was supported on acid-treated montmorillonite (K-10). Supporting the iron oxoaluminate on an acidic support significantly improved the hydrogenation activity of iron oxoaluminate. The hydrocracking activity was increased by a large factor. Thus the aluminate and titanate structures surrounding the pyrrhotite that forms during sulfidation have a beneficial effect in preventing deactivation of the iron sites, and the presence of the acidic sites in the clay results in effective catalytic synergism between catalyst and support. These clay-supported iron oxometallates are highly promising catalysts for coal liquefaction. Iron oxyhydroxide and triiron supported on acid-treated montmorillonite (K-10) were tested for the liquefaction of ion-exchanged Wyodak (IEW) to minimize effects of the coal mineral matter. Both sulfided catalysts gave very high conversions of coal to THF-soluble and heptane-soluble (oils) products.

  3. Investigation of mineral transformations and ash deposition during staged combustion. Quarterly technical progress report, October 1, 1996--December 31, 1996

    SciTech Connect

    Harb, J.N.

    1997-02-13

    The key issues addressed this quarter were related to operational problems in the coal feed system, namely, the inability to accurately measure all of air entering the system, and plugging of coal in the feed lines due to poor entrainment. Both of these problems caused unacceptable uncertainty and/or fluctuations in the operating conditions and therefore required solutions. The coal entrainment problem was solved by installing a new educator designed for entraining solids in gas streams. All of the air entering the reactor now flows through the educator, either as motive air or through the suction air inlet. This ensures that the coal is entrained at relatively high velocity, so that it will flow to the reactor without forming slugs in the lines. A new feeder shroud was also installed with an air jet directed towards the auger to sweep off the tip in order to reduce pulsations when feeding coal. The problems associated with accurately metering the air have been somewhat more difficult to resolve. New strategies for completely closing the system have been tested and look promising. A new flowmeter was also purchased with cost sharing funds to directly measure the air flow rate of the two phase stream (after the coal injection point). If the system can be operated without leaks, then the changes will provide two independent measurements of the air flow to ensure accuracy. If the system cannot be sealed, the new flowmeter will still provide reliable measurement of the air flow and permit proper operation of the combustor. Consequently, we feel that the problems have been resolved and we look forward to a productive next quarter.

  4. Nonequilibrium sulfur capture and retention in an air cooled slagging coal combustor. Quarterly technical progress report, 1996

    SciTech Connect

    Zauderer, B.

    1996-11-01

    The objective of this 24 month project is to determine the degree of sulfur retention in slag in a full scale cyclone coal combustor with sulfur capture by calcium oxide sorbent injection into the combustor. This sulfur capture process consists of two steps: Capture of sulfur with calcined calcium oxide followed by impact of the reacted sulfur-calcium particles on the liquid slag lining the combustor. The sulfur bearing slag must be removed within several minutes from the combustor to prevent re-evolution of the sulfur from the slag. To accomplish this requires slag mass flow rates in the range of several 100 lb/hr. To study this two step process in the combustor, two groups of tests are being implemented. In the first group, calcium sulfate in the form of gypsum, or plaster of Paris, was injected in the combustor to determine sulfur evolution from slag. In the second group, the entire process is tested with limestone and/or calcium hydrate injected into the combustor. This entire effort consists of a series of up to 16 parametric tests in a 20 MMtu/hr slagging, air cooled, cyclone combustor. During the present quarterly reporting period ending September 30,1996, three tests in this project were implemented, bringing the total tests to 5. In addition, a total of 10 test days were completed during this quarter on the parallel project that utilizes the same 20 MMtu/hr combustor. The results of that project, especially those related to improved slagging performance, have a direct bearing on this project in assuring proper operation at the high slag flow rates that may be necessary to achieve high sulfur retention in slag.

  5. A novel carbon-based process for flue gas cleanup. Fifth quarterly technical progress report, July 1--September 30, 1992

    SciTech Connect

    Gangwal, S.K.; Silveston, P.L.

    1992-10-01

    The objective of this project is to demonstrate the preliminary technical and economic feasibility of a novel carbon-based process for removal of at least 95% S0{sub 2} and at least 75 % NO{sub x}, from coal combustion flue gas. In the process, flue gas leaving the electrostatic precipitator (ESP) is passed through a trickle bed of activated carbon catalyst employing a periodic flush of low strength sulfuric acid. The S0{sub 2} is oxidized to S0{sub 3} and removed as medium strength sulfuric acid. The S0{sub 2}-free flue gas is then mixed with NH{sub 3}, and the NO{sub x} in the gas is subjected to selective catalytic reduction (SCR) to N{sub 2} over a fixed bed of activated carbon catalyst. In the previous four quarters, a detailed project management plan was prepared describing the experimental setup, work plan, and test plan. The experimental system was completed for SO{sub 2} conversion at Waterloo and for NO{sub x} conversion at Research Triangle Institute. Shakedown experiments were completed. The NO{sub x} removal performance of two additional modified carbon catalysts (MCCII and MCCIII) was studied. MCCII showed NO{sub 2} removal efficiency which was similar to that observed for MCCI. However, MCCIII was considerably less active for NO{sub x} removal. In the present quarter, further tests of MCCI were performed for SO{sub 2} removal with NO in the feed gas, except the reactor was operated at 130{degrees}C (instead of 80{degrees}C during previous tests). Tests were also performed with MCCII for NO removal with nominally 100 ppm SO{sub 2} in the feed gas.

  6. Synthesis of acrylates and methacrlyates from coal-derived syngas. Quarterly technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect

    Tischer, R.E.; Spivey, J.J.

    1995-08-01

    The objective Task 1, Synthesis of Propionates, is to develop the technology for the synthesis of low-cost propionates. These propionates are the basic feedstock for the subsequent reaction with formaldehyde to produce the target molecule, methyl methacrylate (MMA). Eastman has explored several possible routes to the propionates and has concluded that the most promising is the synthesis of propionic anhydride from the reaction of propionic acid from and ethylene (and also hydrogen in some cases). The main advantage of the anhydride over the acid is that its subsequent reaction with formaldehyde does not produce water, which can lead to undesired byproducts. Bechtel is carrying out a cost analysis of the Eastman route to the anhydride to determine if it is potentially competitive with commercially practiced routes to the same molecule. The answer is expected next quarter. The objective Task 2, Condensation Catalysis to develop catalysts for the condensation of the propionate (propionic anhydride is our target molecule) with formaldehyde. This reaction produces methacrylic acid (MAA), which would then be reacted with methanol to produce MMA in the slurry reactor. We have synthesized a wide range of catalysts and the results show that there is substantial byproduct formation, including 3-pentanone and some propionic acid. Our results show the highest yields of MAA using an alkalized alumina (1%Na/{sub y}-AI{sub 2}O{sub 3}). Although the condensation of propionic acid with formaldehyde is well studied in the literature, little is reported on the condensation of the anhydride. Although it is likely that the same general types of acid/base catalysts that promote the acid condensation will also promote that of the anhydride, the strength and balance of the acid and base sites is likely to be different. We plan to explore the relationship of the catalyst properties and MMA yields using the Altamira system, due to be delivered this next quarter.

  7. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly progress report No. 10, January--March 1995

    SciTech Connect

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-04-27

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and benchscale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 ton lots of each of three project coals, by each process. The project began in October, 1992 and is scheduled for completion by June, 1997. During Quarter 10 (January--March, 1995), preliminary work continued for the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at the Lady Dunn Preparation Plant. Towards this end, laboratory flotation testing and refurbishing of the column have been started. The final version of the Subtask 4.2 Advanced Flotation Process Optimization Research topical report was issued, as was a draft version of the Subtask 4.3 report discussing the formulation of coal-water slurry fuels (CWF) from advanced flotation products. A number of product samples from Subtask 4.4 testing were sent to both Combustion Engineering and Penn State for combustion testing. The evaluation of toxic trace element analyses of column flotation products also continued. The detailed design of the 2 t/hr PDU was essentially completed with the approval of various process flow, plant layout, electrical, and vendor equipment drawings. The final version of the Subtask 6.5 -- Selective Agglomeration Bench-Scale Design and Test Plan Report was issued during this reporting quarter. Design and construction of this 25 lb/hr selective agglomeration test unit was completed and preliminary testing started. Construction of the 2 t/hr PDU began following the selection of TIC. The Industrial Company as the construction subcontractor.

  8. F-Area Acid/Caustic Basin groundwater monitoring report. 1991 Annual report, fourth quarter 1991 and 1991 summary report

    SciTech Connect

    Thompson, C.Y.

    1992-03-01

    This progress report for fourth quarter 1991 and 1992 summary from the Savannah River Plant includes discussion on the following topics: groundwater monitoring data; analytical results exceeding standards; upgradient versus downgradient results; turbidity results exceeding standards; water elevations, flow directions, and flow rates.

  9. Development of the Selective Hydrophobic Coagulation process. Fifth quarterly technical progress report, October 1, 1992--December 30, 1992

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1992-12-31

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, Selective Hydrophobic Coagulation (SHC), has been studied since 1986 under the sponsorship of the US Department of Energy (Contracts AC22-86PC91221 and AC22-90PC90174). The SHC process differs from oil agglomeration, shear or polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. In most cases, simple pH control is all that is required to (1) induce the coagulation of coal particles and (2) effectively disperse particles of mineral matter. If the coal is oxidized, a small dosage of reagents can be used to enhance the process. During the quarter, the Anutech Mark IV surface force apparatus was used to generate surface force-distance data for the mica/dodecylamine hydrochloride system (Task 2.1.1). Work to characterize the hydrophobicity of this system and the mica/DDOA{sup {minus}} system was also initiated (Task 2.1.2). In Task 3, the mixing/coagulation characteristics of a small Kenics static mixer/agitation system have been investigated (Task 3.2.1), a lamella thickener for the recovery of coagula has been built (Task 3.3.1), and the test program for the recovery of coagula by column flotation has been initiated (Task 3.3.4).

  10. Development of the selective hydrophobic coagulation process. Fourth quarterly technical progress report, July 1, 1992--September 30, 1992

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1992-12-31

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, Selective Hydrophobic Coagulation (SHC), has been studied since 1986 under the sponsorship of the US Department of Energy. The SHC process differs from oil agglomeration, shear or polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. In most cases, simple pH control is all that is required to (i) induce the coagulation of coal particles and (ii) effectively disperse particles of mineral matter. If the coal is oxidized, a small dosage of reagents can be used to enhance the process. The technical work program was initiated on July 1, 1992. Force-distance curves were generated for DDOA Br-coated mica surfaces in water and used to calculate hydrophobicity constants and decay lengths for this system; and a new device for the measurement of water contact angles, similar to the Wilhelmy plate balance, has been built 225 kg samples of Pittsburgh No. 8 and Elkhom No. 3 seam coals were obtained; a static mixer test facility for the study of coagula growth was set up and was undergoing shakedown tests at the end of the quarter; a bench-scale lamella thickener was being constructed; and preliminary coagula/ mineral separation tests were being conducted in a bench-scale continuous drum filter.

  11. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1993--June 1993

    SciTech Connect

    Not Available

    1993-07-30

    Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the designs of the remaining major components of the integrated system were completed and the equipment was ordered. DOE has elected to modify the scope of the existing R&D program being conducted under this contract to include testing of a simulated TSCA incinerator ash. The modification will be in the form of an additional Task (Task 8 -- TSCA Ash Testing) to the original Statement of Work.

  12. Quarterly progress report on configurational diffusion of asphaltenes in fresh and aged catalyst extrudates, September 20, 1995--December 20, 1995

    SciTech Connect

    Guin, J.A.

    1995-12-31

    The objective of this research is to determine the relationship between the size and shape of coal and petroleum macromolecules and their diffusion rates i.e., effective diffusivities, in catalyst pore structures. That is, how do the effective intrapore diffusivities depend on molecule configuration and pore geometry. The research is divided into the following tasks: (1) relationship between effective intrapore diffusion coefficients, molecular size and pore geometry; (2) effects of solvent composition, solute concentration, and temperature on the molecular configuration and diffusion rate of coal and petroleum asphaltenes in catalysts pore; and (3) assessment of diffusional limitations in aged catalysts. This quarter, the GPC column efficiency was rechecked by using acetone injection. The calibration curve for the GPC was rechecked through polystyrene standards with narrow molecular weight distributions. Some experiments on adsorption and diffusion of coal asphaltenes through porous catalysts were performed. The asphaltenes were grouped into nine fractions with the concentration being determined via GPC. It was found that the uptake rate for one asphaltene fraction is different from those for other fractions. Comparison of experimental uptake data shows a difference in hindered diffusion behavior between petroleum asphaltenes and coal asphaltenes.

  13. Configurational diffusion of asphaltenes in fresh and aged catalyst extrudates. Quarterly progress report, March 20, 1996--June 20, 1996

    SciTech Connect

    Guin, J.A.

    1996-10-01

    This quarter, hindered diffusion of one coal and two petroleum asphaltenes was studied by adsorptive uptake in THF from a bath surrounding a commercial NiMo/Al{sub 2}O{sub 3} catalyst. Several asphaltene fractions were defined via SEC (size exclusion chromatography), with the molecular weight of each fraction being determined by its elution characteristics using polystyrene standards. It was found that both the coal and petroleum asphaltenes have very broad molecular weight distributions; however, the molecular weights of the coal asphaltenes (50--1000) were much smaller than those of the two petroleum asphaltenes (300--10000 and 300--20000 respectively). Simulation results showed that even though the properties of coal and petroleum asphaltenes were quite different, the values of model parameters for the fractions of the three asphaltenes had the same trend; with increasing molecular weight of the fraction, the adsorption constant monotonically increases, and the effective diffusivity decreases. The experimental diffusion data of the three asphaltenes were well represented by similar mathematical models.

  14. Configurational diffusion of asphaltenes in fresh and aged catalyst extrudates. Quarterly progress report, June 20--September 30, 1996

    SciTech Connect

    Guin, J.A.

    1996-12-31

    The objective of this research is to determine the relationship between the size and shape of coal and petroleum macromolecules and their diffusion rates i.e., effective diffusivities, in catalyst pore structures. That is, how do the effective intrapore diffusivities depend on molecule configuration and pore geometry. The study involves three tasks: Relationship between effective intrapore diffusion coefficients, molecular size, and pore geometry; Effects of solvent composition, solute concentration, and temperature on the molecular configuration and diffusion rate of coal and petroleum asphaltenes in catalyst pores; and Assessment of diffusional limitations in aged catalysts. This quarter, uptake experiments of coal and petroleum asphaltenes into porous catalyst were performed using different initial concentrations, temperatures, and solvents. The adsorption-diffusion parameters were obtained by simulating the experimental data with the mathematical model. The results showed that the adsorption constants for coal asphaltene fractions at 0.5 mg/cm{sup 3} initial concentration are less than those at 0.05 mg/cm{sup 3}, indicating the non-linearity of coal asphaltene adsorption on porous catalyst. Comparison of uptake results using different solvents showed that the adsorption constants with solvent toluene are much larger than those with THF solvent. The effect of temperature on the adsorptive uptake was complex, with the adsorptivity for coal asphaltenes at 35 C exceeding that at 25 C in the lower (< 10{sup 3}) molecular weight region; while the adsorptivities for petroleum asphaltenes are about the same at 20, 35, and 50 C.

  15. Development of molten carbonate fuel cell power plant technology. Quarterly technical progress report No. 2, January 1-March 31, 1980

    SciTech Connect

    Healy, H. C.; Sanderson, R. A.; Wertheim, F. J.; Farris, P. F.; Mientek, A. P.; Maricle, D. L.; Briggs, T. A.; Preston, Jr., J. L.; Louis, G. A.; Abrams, M. L.; Bushnell, C. L.; Nickols, R. C.; Gelting, R. L.; Katz, M.; Stewart, R. C.; Kunz, H. R.; Gruver, G. A.; Bregoli, L. J.; Steuernagel, W. H.; Smith, R.; Smith, S. W.; Szymanski, S. T.

    1980-08-01

    The overall objective of this 29-month program is to develop and verify the design of a prototype molten carbonate fuel cell stack which meets the requirements of 1990's competitive coal-fired electrical utility central station or industrial cogeneration power plants. During this quarter, effort was continued in all four major task areas: Task 1 - system studies to define the reference power plant design; Task 2 - cell and stack design, development and verification; Task 3 - preparation for fabrication and testing of the full-scale prototype stack; and Task 4 - developing the capability for operation of stacks on coal-derived gas. In the system study activity of Task 1, preliminary module and cell stack design requirements were completed. Fuel processor characterization has been completed by Bechtel National, Inc. Work under Task 2 defined design approaches for full-scale stack busbars and electrical isolation of reactant manifolds and reactant piping. Preliminary design requirements were completed for the anode. Conductive nickel oxide for cathode fabrication has been made by oxidation and lithiation of porous nickel sheet stock. A method of mechanizing the tape casting process for increased production rates was successfully demonstrated under Task 3. In Task 4, theoretical calculations indicated that hydrogen cyanide and ammonia, when present as impurities in the stack fuel gas, will have no harmful effects. Laboratory experiments using higher than anticipated levels of ethylene showed no harmful effects. Components for the mobile test facility are being ordered.

  16. An advanced control system for fine coal flotation. Fourth quarterly technical progress report, July 1, 1996--September 30, 1996

    SciTech Connect

    Adel, G.T.; Luttrell, G.H.

    1997-03-04

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as reagent dosage, pulp density and pulp level are adjusted using model-based control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the fourth quarter of this project, a final attempt was made to calibrate a video-based ash analyzer for use in this application. It was concluded that the low ash content and the coarse particle size of the flotation tailings slurry at the Maple Meadow plant site made the video-based system unsuitable for this application. Plans are now underway to lease a nuclear-based analyzer as the primary sensor for this project.

  17. Superior catalysts for selective catalytic reduction of nitric oxides; Quarterly technical progress report, October 1, 1993--December 31, 1993

    SciTech Connect

    Chen, J.P.; Cheng, L.S.; Kikkinides, E.S.; Yang, R.T.

    1993-12-31

    Work was done in three tasks during the first quarter. In Task 1, a new SCR reactor system has been built, complete with on-line GC and MS analyses. The GC is used to monitor the N{sub 2} product so the NO{sub x} > N{sub 2} conversion can be calculated. The MS is used to analyze the N{sub 2}0 concentration. In addition, a wet analytical technique has been established for SO{sub 3} analysis. The new SCR system and the SO{sub 3} analytical technique have been subjected to shakedown tests with success. Along with the existing SCR reactor system, there are now two systems that are being run independently. In Task 2, a procedure for the synthesis of stable Fe{sub 2}O{sub 3} Pillared clay has been established. Inductive coupled plasma spectrometric analysis (ICP) has been used to analyze the chemical composition of the Fe{sub 2}O{sub 3} Pillared clay. Preliminary results for the SCR activities of the Fe{sub 2}O{sub 3} pillared clay are obtained in Task 3. The results show that the activities are near that of the commercial V{sub 2}O{sub 5}/TiO{sub 2} catalysts. However, the SO{sub 2}-to-SO{sub 3} conversion is substantially lower with the pillared clay catalyst, which could be an important advantage.

  18. Quarterly Technical Progress Report of Radioisotope Power System Materials Production and Technology Program tasks for April 2000 through June 2000

    SciTech Connect

    Moore, J.P.

    2000-10-23

    The Office of Space and Defense Power Systems (OSDPS) of the Department of Energy (DOE) provides Radioisotope Power Systems (RPS) for applications where conventional power systems are not feasible. For example, radioisotope thermoelectric generators were supplied by the DOE to the National Aeronautics and Space Administration for deep space missions including the Cassini Mission launched in October of 1997 to study the planet Saturn. The Oak Ridge National Laboratory (ORNL) has been involved in developing materials and technology and producing components for the DOE for more than three decades. For the Cassini Mission, for example, ORNL was involved in the production of carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, and clad vent sets (CVSs) and weld shields (WSs). This quarterly report has been divided into three sections to reflect program guidance from OSDPS for fiscal year (FY) 2000. The first section deals primarily with maintenance of the capability to produce flight quality carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, clad vent sets (CVSs), and weld shields (WSs). In all three cases, production maintenance is assured by the manufacture of limited quantities of flight quality (FQ) components. The second section deals with several technology activities to improve the manufacturing processes, characterize materials, or to develop technologies for two new RPS. The last section is dedicated to studies of the potential for the production of 238Pu at ORNL.

  19. Bench-scale testing of the micronized magnetite process. Third quarterly technical progress report, January 1995--March 1995

    SciTech Connect

    1995-04-29

    The major focus of the project, which is scheduled to occur through December 1995, will be to install and test a 500{number_sign}/hr. fine-coal cleaning circuit at DOE`s Process Research Facility (PRF), located at the Pittsburgh Energy Technology Center (PETC). The circuit will utilize an extremely fine, micron-sized magnetite media and small diameter cyclones to make efficient density separations on minus-28-Mesh coal. The overall objectives of the project are to: Determine the effects of operating time on the characteristics of the recirculating medium in a continuous integrated processing circuit, and subsequently, the sensitivity of cyclone separation performance to the quality of the recirculating medium; and determine the technical and economic feasibility of various unit operations and systems in optimizing the separation and recovery of the micronized magnetite from the coal products. This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  20. Bench-scale testing of the micronized magnetite process. Eighth quarterly technical progress report, April--June, 1996

    SciTech Connect

    1996-08-13

    The major focus of the project is to install and test a 500 lbs./hr. fine-coal cleaning circuit at DOE`s Process Research Facility (PRF), located at the Pittsburgh Energy Technology Center (PETC). The circuit will utilize an extremely fine, micron-sized magnetite media and small diameter cyclones to make efficient density separations on minus-28-Mesh coal. The circuit consists of three subcircuits: Classification Circuit; Dense-Medium Cycloning Circuit; and Magnetite Recovery Circuit. The testing scope involves initial closed-loop testing of each subcircuit to optimize the performance of the equipment in each subcircuit (i.e., Component Testing), followed by open-circuit testing of the entire integrated circuit to optimize the process and quantify the process efficiency (i.e., Integrated Testing). This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the above mentioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  1. Bench-scale testing of the micronized magnetite process. Seventh quarterly technical progress report, January--March, 1996

    SciTech Connect

    1996-08-13

    The major focus of the project is to install and test a 500 lbs./hr. fine-coal cleaning circuit at DOE`s Process Research Facility (PRF), located at the Pittsburgh Energy Technology Center (PETC). The circuit will utilize an extremely fine, micron-sized magnetite media and small diameter cyclones to make efficient density separations on minus-28-Mesh coal. The circuit consists of three subcircuits: Classification Circuit; Dense-Medium Cycloning Circuit; and Magnetite Recovery Circuit. The testing scope involves initial closed-loop testing of each subcircuit to optimize the performance of the equipment in each subcircuit (i.e., Component Testing), followed by open-circuit testing of the entire integrated circuit to optimize the process and quantify the process efficiency (i.e., Integrated Testing). This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the above mentioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  2. Bench-scale testing of the micronized magnetite process. Sixth quarterly technical progress report, October--December, 1995

    SciTech Connect

    1996-08-13

    The major focus of the project is to install and test a 500 lbs./hr. fine-coal cleaning circuit at DOE`s Process Research Facility (PRF), located at the Pittsburgh Energy Technology Center (PETC). The circuit will utilize an extremely fine, micron-sized magnetite media and small diameter cyclones to make efficient density separations on minus-28-Mesh coal. The circuit consists of three subcircuits: Classification Circuit; Dense-Medium Cycloning Circuit; and Magnetite Recovery Circuit. The testing scope involves initial closed-loop testing of each subcircuit to optimize the performance of the equipment in each subcircuit (i.e., Component Testing), followed by open-circuit testing of the entire integrated circuit to optimize the process and quantify the process efficiency (i.e., Integrated Testing). This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the above mentioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  3. Bench-scale testing of the micronized magnetite process. Fourth quarterly technical progress report, April--June 1995

    SciTech Connect

    1995-08-10

    The main accomplishments of Custom Coals and the project subcontractors, during this period, included: continued purchase of small equipment and supplies for the circuit; completed the circuit commissioning task; procured one lot of PennMag Grade-K and one lot Grade-L magnetite; completed work on analytical investigations; completed Classifying Circuit Component Testing on Pittsburgh No. 8 coal; completed the final Heavy-Media cyclone component testing on the Pittsburgh No. 8 seam using Grade-K and Grade-L magnetites; continued QA/QC tests on wet screening, wet splitting, Marcy Balance, and reproducibility checks on component tests and component test samples; and completed the magnetite recovery circuit component testing with and without screens using the Grade-K magnetite and the Pittsburgh No. 8 coal seam. This report contains a short discussion of the project description, objectives, budget, schedule, and teaming arrangement. It also includes a detailed discussion of the above mentioned project accomplishments and plans, organized by the various task series within the project work plan. The final section contains an outline of the specific project goals for the next quarterly reporting period.

  4. Configurational diffusion of asphaltenes in fresh and aged catalyst extrudates. Quarterly progress report, March 20, 1994--June 20, 1994

    SciTech Connect

    Guin, J.A.; Tarrer, A.R.

    1994-08-01

    The objective of this research is to determine the relationship between the size and shape of coal and petroleum macromolecules and their diffusion rates in catalyst pore structures. This quarter, the authors developed a mathematical diffusion model for catalysts with a nonuniform pore structure during the adsorptive diffusion process due to the adsorbed layer of solute molecules on the catalyst pore walls. Diffusion experiments with quinoline and polystyrene were performed. Effective diffusivities were obtained by fitting the experimental data with a diffusion model. Results showed that the uniform pore model did not satisfactorily represent the diffusion behavior of larger polystyrene molecules, which gave rise to very high tortuosity values. The shrinking pore model better represented the adsorptive diffusion uptake behavior of a solute from the surrounding bath, especially for a diffusing solute with larger molecular size. Adsorption of solute molecules on the catalyst pore walls further restricts the diffusion rate due to increased steric and hydrodynamic hindrance factors. The tortuosity factor could also increase during adsorptive diffusion processes due to the increased constrictions caused by the adsorbed solute molecules.

  5. Fine particle clay catalysts for coal liquefaction. Quarterly technical progress report, May 8, 1993--August 8, 1993

    SciTech Connect

    Olson, E.S.

    1995-10-01

    High hydrocracking and liquefaction activity can be achieved with 10 wt.% of sulfided clay-supported iron catalysts. Further tests and demonstrations of this activity were required. Iron hydroxyoxide was generated on acid-treated montmorillonite. The new batch of catalyst exhibited high hydrocracking activity, Three hour tests with the solubilized intermediate from low-severity treatment of Wyodak coal (LSW) gave a high conversion (45%) of the heptane-insoluble LSW intermediate to heptane-soluble products. An investigation of new methods for the production of catalysts from tetralin-soluble iron oxometallates and the determination of their catalytic activities was continued in this quarter. Iron oxotitanate and iron oxoaluminate gave very high conversions of LSW to heptane solubles (61% and 54%, respectively). The high yields of heptane soluble products obtained with these catalysts offers a potential for use in liquefaction stages with solubilized coal, or at least serve as a model for producing active catalysts via mixed metal oxides. Methods for successfully testing dispersed iron catalysts with the low-severity intermediate were also devised. Catalyst recovered from the dispersed iron hydroxyoxide-catalyzed reaction of ion-exchanged Wyodak gave a high conversion (47%) of LSW to heptane solubles.

  6. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, April 1--June 30, 1995

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-09-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. The paper describes activities carried out this quarter. 11 refs., 21 figs., 17 tabs.

  7. (Study of the behavioral and biological effects of high intensity 60 Hz electric fields): Quarterly technical progress report No. 29

    SciTech Connect

    Orr, J.L.

    1989-07-14

    Activities this quarter involved all phases of the project plus a meeting of the Joint Committee in Tokyo. Detailed mapping of the exposure facility is scheduled to be completed during the week of August 14, 1989. Both electric and magnetic fields should be available for tests of the components of the tether and blood sampling system for the neuroendocrine pilot study in September 1989. The groups for the social behavior study are stabilizing appropriately. Details on the formation of the groups and their status has been provided. Dr. Coelho has included information related to aspects of the social experiment ranging from age estimation in baboons through the cardiovascular consequences of psychosocial stress. In addition, a draft manuscript is included on the data from the previous experiments which describes the effects of 30 and 60 kV/m electric fields on the social behavior of baboons. Tests of the blood handling procedures and analysis methods have been completed. With the exception of the catecholamine analyses, the handling procedures and variability in replicate measurements are satisfactory. Logistic and practical considerations now weigh strongly against including the analysis of the blood samples for catecholamines. Preliminary tests indicate that a sampling procedure which will work for the other compounds is probably not satisfactory for the catecholamines.

  8. Quarterly Technical Progress Report of Radioisotope Power System Materials Production and Technology Program tasks for January 2000 through March 2000

    SciTech Connect

    Moore, J.P.

    2000-08-18

    The Office of Space and Defense Power Systems (OSDPS) of the Department of Energy (DOE) provides radioisotope Power Systems (BPS) for applications where conventional power systems are not feasible. For example, radioisotope thermoelectric generators were supplied by the DOE to the National Aeronautics and Space Administration for deep space missions including the Cassini Mission launched in October of .I 997 to study the planet Saturn. The Oak Ridge National Laboratory (ORNL) has been involved in developing materials and technology and producing components for the DOE for more than three decades. For the Cassini Mission, for example, ORNL was involved in the production of carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, and clad vent sets (CVSs) and weld shields (WSs). This quarterly report has been divided into three sections to reflect program guidance from OSDPS for fiscal year (FY) 2000. The first section deals primarily with maintenance of the capability to produce flight quality carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, clad vent sets (CVSs), and weld shields (WSs). In all three cases, production maintenance is assured by the manufacture of limited quantities of flight quality (FQ) components. The second section deals with several technology activities to improve the manufacturing processes, characterize materials, or to develop technologies for two new RPS. The last section is dedicated to studies of the potential for the production of 238Pu at OBNL.

  9. Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Quarterly technical progress report, July--September 1995

    SciTech Connect

    Song, Chunshan; Schmidt, E.; Schobert, H.H.

    1996-01-01

    Coal liquefaction involves cleavage of methylene, dimethylene and ether bridges connecting polycyclic aromatic units and the reactions of various oxygen functional groups. Here in this quarterly, we report on the hydrocracking of 4-(l-naphthylmethyl)bibenzyl in the presence of iron (Fe) catalysts and sulfur and residual wall catalytic effect. Catalytic hydrocracking of 4-(1-naphthylmethyl)bibenzyl (NMBB) predominantly yielded naphthalene and 4-methylbibenzyl. Various iron compounds were examined as catalyst precursors. Sulfur addition to most catalyst precursors led to substantially higher catalyst activity and higher conversion. NMBB was also treated with sulfur in the absence of iron compounds, in concentrations of 1.2-3.4 wt%, corresponding to the conditions present in reactions with added iron compounds. Increasing sulfur concentrations led to higher NMBB conversions. Furthermore, sulfur had a permanent effect on the reactor walls. A black sulfide layer formed on the surface which could not be removed mechanically. The supposed non-catalytic reactions done in the same reactor but after experiments with added sulfur showed higher conversions than comparable experiments done in new reactors. This wall catalytic effect can be reduced by treating the sulfided reactors with hydrochloric acid. The results of this work demonstrate the significant effect of sulfur addition and sulfur-induced residual wall effects on carbon-carbon bond cleavage and hydrogenation of aromatics.

  10. Development of the Selective Hydrophobic Coagulation process. Seventh quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1993-11-01

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, known as Selective Hydrophobic Coagulation (SHC), has been studied under the sponsorship of the US Department of Energy since 1986 (Contracts DE-AC22-86PC91221 and DE-AC22-90PC90174). The SHC process differs from oil agglomeration, shear flocculation, polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. Often, simple pH control is all that is required to (i) induce the coagulation of coal particles, and (ii) effectively disperse particles of mineral matter. When the coal is superficially oxidized, a small dosage of reagents may be used to promote coagulation. During the quarter, work was completed on the development of the hydrophobic interaction energy function (Subtask 2.1) and the extended DLVO equation (Subtask 2.2.). Work to predict optimum operating conditions using the extended DLVO equation (Subtask 2.3) is underway. In Task 3 -- Process Development, work was completed on the study to determine the effect of mixing on coagula growth (Subtask 3.2) and on the use of column flotation for the recovery of coal coagula (subtask 3.3.4). Work is underway on the use of the lamella thickener and filter for the recovery of coagula (Subtasks 3.3.1 and 3.3.2).

  11. Technology development for cobalt F-T catalysts. Quarterly technical progress report No. 8, July 1, 1994--September 30, 1994

    SciTech Connect

    Singleton, A.H.

    1995-04-18

    The objective of this project is to investigate the influence of various promoters, additives, and supports on minimizing the methane selectivity and increasing the water-gas shift (WGS) activity of cobalt (Co) Fischer-Tropsch (F-T) catalysts. The ultimate goal of this investigation is to identify and demonstrate a catalyst preparation procedure that will be scaled up for the reproducible synthesis of commercial quantities of supported Co catalysts with desired activity, selectivity, and lifetime for use in F-T synthesis in three-phase slurry bubble column reactors. Accomplishments for this quarter are: Four new catalysts were formulated and prepared during this period under both subtasks 1.2 and 1.3 and five more catalysts were prepared by Calsicat; The characterization of all the catalysts in order to determine their physical properties (BET surface area, pore volume, pore size diameter, particle size distribution), as well as the cobalt reducibility, extent of reduction, and dispersion) was continued; Seven new catalysts have been tested for their F-T synthesis performance; An investigation of the effect of pre-treatment (i.e. calcination in static air versus flowing air, direct reduction without prior calcination) of a selected number of catalysts upon their performance for F-T synthesis was continued during this period.

  12. Floatabilities of treated coal in water at room temperature. Annual topical report, September 1992--August 1993

    SciTech Connect

    Kwon, K.C.; Rohrer, R.L.; Lai, R.W.; Finseth, D.H.

    1993-12-31

    This report contains a research paper entitled ``Floatability of Treated Coal in Water at Room Temperature.`` Experimental data on equilibrium adsorption loadings of probe compounds on coal, and flotation of raw coals as well as treated coal were obtained, using Illinois No. 6 coal (PSOC-1539), Adaville No. 1 coal (PSOC-1544), Wyodak coal (PSOC-1545) and Pittsburgh No. 8 coal (PSOC-1549). The raw data of this Annual Topical Report are also available in the Quarterly Progress Report for the period April--June 1993 and the Quarterly Progress Report July--September 1993.

  13. Investigate the effectivness of calcium-treated coals in the capture of sulfur gases generated in staged fired combustors. Third quarterly technical progress report, May 1-July 31, 1983

    SciTech Connect

    Porter, J. H.; Manning, M. P.; Benedek, K. R.; Sharma, P. K.

    1983-09-01

    In this quarter's work, a new procedure was developed to add calcium to pulverized coal. The method has been found to increase the calcium content of bituminous coal to 12% calcium by weight, which corresponds to a Ca/S ratio of greater than 2. Progress was also made on the combustion test facility this quarter. A new modification of the low-flow coal feeder has made that system steady and reliable. With the furnace wired and plumbed, and the other subsystems complete, the facility is almost ready to burn the treated coals.

  14. Geological and petrophysical characterization of the Ferron Sandstone for 3-D simulation of a fluvial-deltaic reservoir. Quarterly progress report, July 1--September 30, 1995

    SciTech Connect

    Allison, M.L.

    1995-10-30

    The objective of this project is to develop a comprehensive, interdisciplinary, and quantitative characterization of a fluvial-deltaic reservoir which will allow realistic inter-well and reservoir-scale modeling to be constructed for improved oil-field development in similar reservoirs world-wide. The geological and petrophysical properties of the Cretaceous Ferron Sandstone in east-central Utah will be quantitatively determined. Both new and existing data will be integrated into a three-dimensional representation of spatial variations in porosity, storativity, and tensorial rock permeability at a scale appropriate for inter-well to regional-scale reservoir simulation. Results could improve reservoir management through proper infill and extension drilling strategies, reduction of economic risks, increased recovery from existing oil fields, and more reliable reserve calculations. Transfer of the project results to the petroleum industry is an integral component of the project. Technical progress this quarter is divided into regional stratigraphy, case studies, stochastic modeling and fluid-flow simulation, and technology transfer activities. The regional stratigraphy of the Ferron Sandstone outcrop belt is being described and interpreted. Detailed geological and petrophysical characterization of the primary reservoir lithofacies typically found in a fluvial-dominated deltaic reservoir, is continuing at selected case-study areas. Interpretations of lithofacies, bounding surfaces, and other geologic information are being combined with permeability measurements from closely spaced traverses and from drill-hole cores (existing and two drilled during the quarter). Petrophysical and statistical analyses are being incorporated with the geological characterization to develop a three-dimensional model of the reservoirs through fluid-flow simulation.

  15. Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane: Quarterly technical progress report 15, October 1-December 31, 1996

    SciTech Connect

    McCormick, R.L., Alptekin, G.O.

    1997-04-02

    This document is the fifteenth quarterly technical progress report under Contract No. DE-AC22-92PC921 `Development of Vanadium- Phosphate Catalysts for Methanol Production by Selective Oxidation of Methane` and covers the period October-December, 1996. Vanadium phosphate, vanadyl pyrophosphate specifically, is used commercially to oxidize butane to maleic anhydride and is one of the few examples of an active and selective oxidation catalyst for alkanes. In this project we are examining this catalyst for the methane oxidation reaction. Initial process variable and kinetic studies indicated that vanadyl pyrophosphate is a reasonably active catalyst below 5000{degrees}C but produces CO as the primary product, no formaldehyde or methanol were observed. A number of approaches for modification of the phosphate catalyst to improve selectivity have been tried during this project. During this quarter we have obtained surface areas of catalysts prepared with modified surface acidity. The results confirm the enhanced activity of two of the modified preparations in methanol conversion (a test reaction for surface acid sites). In previous work we noted no improvement in methane oxidation selectivity for these catalysts. Surface areas, surface analysis by XPS, and bulk analysis by ICP-AA have been obtained for vanadyl pyrophosphate promoted by Cr, Cu, and Fe. These data indicate that roughly one tenth of the surface metal atoms are promoter. A similar analysis was obtained for the bulk. Preliminary examination of binding energies suggests a slightly more reduced surface for the Cr and Fe promoted catalysts which exhibit a significant selectivity to formaldehyde in methane oxidation. A more detailed kinetic model has also been developed to aid in comparing the promoted catalysts and is discussed. Plans for the coming months are outlined.

  16. Systems and economic analysis of microalgae ponds for conversion of CO{sub 2} to biomass. Fourth quarterly technical progress report, June 16, 1994--September 15, 1994

    SciTech Connect

    Benemann, J.R.; Oswald, W.J.

    1994-12-28

    The threat of global warming, mounting concerns about air and water pollution, prospective food shortages, and declining reserves of low-cost fossil fuels, have spawned a burgeoning interest in photobiological processes using microalgae as a method of large-scale utilization of CO{sub 2} for the production of fuels, food, and waste treatment. The major activity during this quarter was the development of cost data for the algal production system, including alternatives to the basic design previously used. The results of this work are still being developed and will be reported in the Final Report. This progress report summarizes a study of a production processes for one specific alga, Botryococcus braunii. This alga is of particular interest in this project as it produces an almost pure hydrocarbon fuel, and does so in rather large amounts. Technology for the production of this organism has, however, not yet been developed. This progress report reviews the literature on this interesting alga and suggests potential methods for its production. 62 refs.

  17. Fluid seals development for coal liquefaction slurry pumps. Quarterly technical progress report No. 11, 1 April 1985-30 June 1985. [Reciprocating pumps

    SciTech Connect

    Burcham, R.E.

    1985-07-22

    This quarterly progress report covers the work performed during the period 1 April 1985 to 30 June 1985 on the Fluid Seals Development for Coal Liquefaction Slurry Pumps Program. The work was sponsored by the Department of Energy, Pittsburgh Technology Center, to develop technology for hydrostatic fluid seals to be used in coal slurry centrifugal and reciprocating pumps. The scope of the program consists of the following tasks: (1) Task 1A: Survey of current practices for centrifugal and reciprocating coal slurry pump seals; (2) Task 1B: Preliminary evaluation of three alternative centrifugal and reciprocating fluid seal concepts; (3) Task 2: Detail evaluation of the best two centrifugal and reciprocating fluid seal concepts; (4) Task 3A: Design and fabrication of the selected centrifugal and reciprocating fluid seal concept, Design and fabrication of the centrifugal and reciprocating seal testers; (5) Task 3B: Laboratory seal testing of the centrifugal and reciprocating fluid seals; and (6) Task 4: Field testing of the centrifugal and reciprocating fluid seals. Tasks 1, 2, 3A, and 3B have been completed. Task 4 is in progress. 2 figs.

  18. Float zone silicon sheet growth. Technical progress report quarterly report No. 8, July 1, 1995--September 30, 1995

    SciTech Connect

    Bleil, C.E.

    1995-12-01

    Research continued on float zone silicon sheet growth. Progress is described in the following 8 tasks: heat pipe construction; heat pipe heater and heat extraction system; optical temperature monitoring system; replenishment source development; RF electrode assembly; solid-liquid interface monitors; ribbon seed preparation; and overall system assembly.

  19. Contracts for field projects and supporting research on enhanced oil recovery. Progress review No. 71, quarter ending June 30, 1992

    SciTech Connect

    Not Available

    1993-06-01

    Progress reports are presented for the following tasks: chemical flooding--supporting research; gas displacement--supporting research; thermal recovery--supporting research; geoscience technology; resource assessment technology; microbial technology; and novel technology. A list of available publication is also provided.

  20. Uranium recovery research sponsored by the Nuclear Regulatory Commission at Pacific Northwest Laboratory. Quarterly progress report, June-September 1983

    SciTech Connect

    Foley, M.G.; Deutsch, W.J.; Gee, G.W.; Hartley, J.N.; Kalkwarf, D.R.; Mayer, D.W.; Nelson, R.W.; Opitz, B.E.; Peterson, S.R.; Serne, R.J.

    1983-11-01

    This report documents progress for the following major research projects: stabilization, engineering, and monitoring alternatives assessment for improving regulation of uranium recovery operations and waste management; attenuation of radon emission from uranium tailings; assessment of leachate movement from uranium mill tailings; and methods of minimizing ground-water contaminants from in-situ leach uranium mining.

  1. Contracts for field projects and supporting research on enhanced oil recovery. Progress review quarter ending September 30, 1993

    SciTech Connect

    Not Available

    1994-08-01

    Progress reports are presented for the following tasks: chemical flooding--supporting research; gas displacement--supporting research; thermal recovery--supporting research; geoscience technology; resource assessment technology; and field demonstrations in high-priority reservoir classes. A list of available publications is also included.

  2. DOE Waste Package Project. Quarterly progress report, April 1, 1993--June 30, 1993 and end of year summary report

    SciTech Connect

    Ladkany, S.G.

    1993-08-01

    Contents of this report are as follows: Overview and progress of waste package project and container design; waste container alternate design considerations; structural analysis and design of nuclear waste package canister; manipulation of the nuclear waste container; design requirements of various rock tunnel shapes for long term storage of high level waste; and transport phenomena in the near field.

  3. Evaluation of hyperbaric filtration for fine coal dewatering. Third quarterly technical progress report, March 1, 1993--May 31, 1993

    SciTech Connect

    Parekh, B.K.; Hogg, R.; Fonseca, A.

    1993-09-01

    The main objectives of the project are to investigate the fundamental aspects of particle-liquid interaction in fine coal dewatering, to conduct laboratory and pilot plant studies on the applicability of hyperbaric filter systems and to develop process conditions for dewatering of fine clean coal to less than 20 percent moisture. Progress is described.

  4. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, July 1--September 30, 1995

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-12-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. Some of the contract activities for this quarter are: We completed many of the analyses on the 81 samples received from HTI bench-scale run CMSL-9, in which coal, coal/mixed plastics, and coal/high density polyethylene were fed; Liquid chromatographic separations of the 15 samples in the University of Delaware sample set were completed; and WRI completed CP/MAS {sup 13}C-NMR analyses on the Delaware sample set.

  5. Development of the selective hydrophobic coagulation process. Technical progress report for the ninth quarter, October 1--December 31, 1993

    SciTech Connect

    Yoon, R.H.; Luttrell, G.H.

    1994-07-01

    A novel technique for selectively coagulating and separating coal from dispersed mineral matter has been developed at Virginia Tech. The process, known as Selective Hydrophobic Coagulation (SHC), has been studied under the sponsorship of the U.S. Department of Energy since 1986 (Contracts DE-AC22-86PC91221 & DE-AC22- 9OPC90174). The SHC process differs from oil agglomeration, shear flocculation, polymer flocculation, and electrolytic coagulation processes in that it does not require reagents or additives to induce the formation of coagula. Often, simple pH control is all that is required to (i) induce the coagulation of coal particles, and (ii) effectively disperse particles of mineral matter. When the coal is superficially oxidized, a small dosage of reagents may be used to promote coagulation. During the past quarter, stability calculations were carried out to develop a better understanding of the selective coagulation of fine coal and associated mineral matter. The calculations were performed for interactions involving coal, silica and clay particles. The analyses suggest that the heterocoagulation of the edges of clay particles with coal particles controls the overall selectivity of the SHC process. In Subtask 3.3, froth flotation was explored as a possible technique for recovering hydrophobic coagula. Experimental test data obtained using this technique were analyzed using a statistical regression program. The analyses indicate that froth flotation can be used to successfully recover hydrophobic coagula provided that adequate precautions are taken to minimize coagula breakage due to turbulence. Recommendations include the use of low aeration rates and little or no additions of wash water.

  6. Organic complexant-enhanced mobility of toxic elements in low-level wastes. Quarterly progress report, January-March 1984

    SciTech Connect

    Swanson, J.L.

    1984-06-01

    The results obtained during the third quarter's activities of a project whose objective is to determine how and to what extent organic complexants affect the mobility of toxic elements in subsurface groundwaters at commercial low-level waste disposal sites are described. This project will study nonradioactive toxic elements as well as elements having radioactive isotopes of importance (e.g. /sup 63/Ni, /sup 239/Pu, /sup 241/Am). Organic complexants used in the nuclear industry are being emphasized, but others are being examined. Generic soil components (e.g. hydrous oxides, silica, clays) are being used so that the results will be broadly applicable. Substantiation of the previously indicated sorption of a Pu(IV)-EDTA complex by hydrous ferric oxide (Fe/sub 2/O/sub 3/.xH/sub 2/O) was obtained by comparing the sorption of EDTA in the presence and absence of Pu. Additional data on the sorption of a Ni-EDTA complex by Fe/sub 2/O/sub 3/.xH/sub 2/O were also obtained. Preliminary Ni sorption data were obtained with other complexants (picolinic acid and citric acid), and another generic soil component (TiO/sub 2/). Sorption of a Ni-EDTA complex by an anion exchange resin was observed. Complexed species are thus likely to be present in the resin wastes from certain reactor decontamination solution clean-up operations. An experimental problem that caused some erroneous results for uncomplexed Ni was discovered and corrected. The filters being used to assure good separation of solid and liquid phases were removing Ni from solution, which skewed some earlier results. 11 references, 13 figures, 2 tables.

  7. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, July 1993--September 1993

    SciTech Connect

    Not Available

    1993-10-30

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater systems to be developed have multiple use applications; however, the Phase 3 research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the past quarter, the major effort was completing some of the system modification installation designs, completing industry funded testing, developing a surrogate TSCA ash composition, and completing the TSCA ash Test Plan. The installation designs will be used for the equipment modifications planned for the end of CY 93. The industry funded testing consisted of vitrifying Spent Aluminum Potliner (SPL) which is a listed hazardous waste. This testing has verified that SPL can be vitrified into a safe, recyclable glass product. Some results from this testing are provided in Section 2.2.1. The surrogate TSCA ash composition was developed with input from various DOE laboratories and subcontractors. The surrogate ash consists of a mixture of MSW fly ash and bottom ash spiked with heavy metal contaminants. The levels of metal additives are sufficient to ascertain the partitioning of the contaminants between the glass and effluent flow streams. Details of the surrogate composition and the planned testing is provided in Section 4.2.2.

  8. Precombustion removal of hazardous air pollutant precursors. Third quarterly technical progress report, April 1, 1996--June 30, 1996

    SciTech Connect

    1996-07-19

    This project involves the development of an optimized, bench-scale processing circuit capable of efficiently removing trace elements from run-of-mine coals. The optimized circuit will be developed using characterization data obtained from detailed washability studies and release analyses tests conducted with several eastern US coals. The optimized circuit will incorporate a variety of conventional and advanced coal cleaning processes which are believed to be the most cost-effective and commercially viable. The coal products from the optimized circuit will be further treated with complexing agents specifically designed to extract organometallic trace elements that are difficult to remove by physical cleaning operations. Finally, innovative bioremediation schemes will be investigated as a means of controlling the release of trace elements from the process waste streams. Emphasis has been placed on the development of a processing circuit which maximizes the rejection of trace elements, minimizes the production of coal fines which are costly to process and less marketable, and minimizes the downstream impacts of the process waste streams on the environment. During the past quarter, the project work plan and all associated technical/management reports were successfully approved. Activities associated with the selection and acquisition of all three base coal samples have also been completed. Characterization work is continuing to move ahead at an accelerated pace in both Subtask 3.2--Washability Analysis and Subtask 3.3-- Flotation Release Analyses. In addition, mineralogical analyses are underway as part of the characterization work. In Task 4--Bench-Scale Testing, the experimental program is now well underway to assess the trace element cleanability of the Pittsburgh No. 8 coal. Effort has also been initiated under Task 4--Toxics Fate Studies to identify viable methods for controlling the release of trace metals from refuse samples for the Pittsburgh No. 8 seam.

  9. Vapor pressures and heats of vaporization of primary coal tars. Quarterly technical progress report, July 1--September 30, 1995

    SciTech Connect

    Suuberg, E.M.

    1995-12-31

    There is significant current interest in general area of coal pyrolysis, particularly because of the central role of pyrolysis in all thermally driven coal conversion processes-gasification, combustion, liquefaction, mild gasification, or thermal beneficiation. There remain several key data needs in these application areas. Among them is a need for more reliable correlation for prediction of vapor pressure of heavy, primary coal tars. The vapor pressure correlations that exist at present for coal tars are very crude and they are not considered reliable to even an order of magnitude when applied to tars. The present project seeks to address this important gap in the near term by direct measurement of vapor pressures of coal tar fractions, by application of well-established techniques and modifications thereof. The principal objectives of the program are to: (1) obtain data on the vapor pressures and heats of vaporization of tars from a range of ranks of coal, (2) develop correlations based on a minimum set of conveniently measurable characteristics of the tars, (3) develop equipment that would allow performing such measurements in a reliable, straightforward fashion. A significant amount of time has been devoted during this quarter to extending the work on measurements of vapor pressures of tars. For this purpose, cellulose tar and cellulose tar related compounds have been selected as model systems. Cellulose tar has a much narrower distribution of molecular weight than does coal tar, and it is much more homogeneous. Thus it is better to develop the methods to be used for coal tars on this simpler model system first.

  10. Fine particle clay catalysts for coal liquefaction. Quarterly technical progress report, May 9, 1992--August 8, 1992

    SciTech Connect

    Olson, E.S.

    1995-10-01

    An investigation of new methods for the production of mixed pillared clay catalysts and clay-supported catalysts and determination of their catalytic activities were continued in this quarter. To demonstrate the reproducibility of the preparative method for high activity iron/alumina-pillared montmorillonite catalysts, a new batch of the catalyst was prepared and tested for hydrocracking activity with bibenzyl. This preparation gave conversion and product distribution similar to that reported previously. The mixed iron/alumina-pillared clay was also prepared using a pillaring solution that was aged for longer period of time. To determine the importance of the type of pillaring support in hydrocracking activity, iron/zirconia-pillared montmorillonite was prepared using the same technique as that for iron/alumina-pillared montmorillonite. The reaction of bibenzyl with the sulfided iron/zirconia-pillared catalyst gave a lower hydrocracking conversion than the iron/alumina-pillared catalyst. Addition of a second catalytic metal to the clay support was attempted to determine if a synergistic effect could improve liquefaction. Ferric nitrate and stannous chloride were added to the clay, but the resulting catalyst was relatively poor for hydrocracking and hydrogenation compared with ferric nitrate supported on the clay. New disposable iron catalysts with high acidity and surface area are desired for coal liquefaction. Synthetic iron aluminosilicates were prepared by methods similar to those used for the nickel-substituted synthetic mica montmorillonite (NiSMM) catalysts, which are very effective for hydrogenation and reforming of hydrocarbons. The iron aluminosilicate catalysts were tested for hydrocracking and hydrogenation of bibenzyl, naphthalene and pyrene. Pyrene hydrogenation was effectively catalyzed by the sulfided synthetic iron catalyst.

  11. High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, October--December 1992, Revision 1

    SciTech Connect

    Klier, K.; Herman, R.G.; Johansson, M.A.; Feeley, O.C.

    1993-04-01

    The objective of the proposed research is to synthesize high octane ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE) directly from H{sub 2}/CO/CO{sub 2} coal-derived synthesis gas via alcohol mixtures that are rich in methanol and 2-methyl-l-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The testing of strongly acidic catalysts for the conversion of a mixture of methanol and isobutanol to ethers and hydrocarbons was continued. Under standardized test conditions the catalysts tested this quarter were: phosphotungstic acid supported on zirconia (PW{sub 12}/ZrO{sub 2}), ``niobic acid`` (Nb{sub 2}O{sub 5}{center_dot}xH{sub 2}O), and an iron and manganese doped sulfate-modified zirconia (Fe/Mn/ZrO{sub 2}/SO{sub 4}{sup 2{minus}}). The overall activity of these catalysts followed the order of Fe/Mn/ZrO{sub 2}/SO{sub 4}{sup 2{minus}} > PW{sub 12}/ZrO{sub 2} >Nb{sub 2}O{sub 5}{center_dot}xH{sub 2}O With the Fe/Mn/ZrO{sub 2}/SO{sub 4}{sup 2{minus}} catalyst approaching ZrO{sub 2}/SO{sub 4}{sup 2{minus}} in both activity and selectivity for isobutene production. The effect of the presence of water on the reaction of methanol and isobutanol over ZrO{sub 2}/SO{sub 4}{sup 2{minus}} was determined to be insignificant under the reaction conditions investigated.

  12. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, October 1--December 31, 1994

    SciTech Connect

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-05-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. During this quarter, analyses were completed on 65 process samples from representative periods of HRI Run POC-2 in which coal, coal/plastics, and coal/rubber were the feedstocks. A sample of the oil phase of the oil/water separator from HRI Run POC-1 was analyzed to determine the types and concentrations of phenolic compounds. Chemical analyses and microautoclave tests were performed to monitor the oxidation and measure the reactivity of the standard coal (Old Ben Mine No. 1) which has been used for the last six years to determine solvent quality of process oils analyzed in this and previous DOE contracts.

  13. Fine particle clay catalysts for coal liquefaction. Quarterly technical progress report, February 9, 1992--May 8, 1992

    SciTech Connect

    Olson, E.S.

    1995-10-01

    An investigation of new methods for the production of iron-pillared clay catalysts and clay-supported iron hydroxyoxide catalysts and the determination of their catalytic activities was continued in this quarter. Previous work in this project showed that a catalyst prepared by adding ferric nitrate and ammonia to an acid-washed clay gave an active catalyst following sulfidation. Further testing of this catalyst with a model compound showed that its hydrocracking activity was considerably lower when used in 10% concentration rather than 50%. In contrast, the mixed iron/alumina pillared clay catalysts were still highly effective at 10% concentration and gave good conversions at one and two hour reaction times. An investigation of preparation methods demonstrated that calcination of both the iron hydroxyoxide-impregnated clay and the mixed iron/alumina pillared clays is essential for activity. High activity was obtained for these catalysts only when they were removed from the aqueous media rapidly, dried, and calcined. The use of ferric sulfate to prepare a clay-supported sulfated iron catalyst was attempted, the resulting catalyst was relatively inactive for hydrocracking. Several new catalysts were synthesized with the idea of decreasing the pillar density and thereby increasing the micropore volume. A zirconia-pillared clay with low pillar density was prepared and intercalated with triiron complex. The hydrocracking activity of this catalyst was somewhat lower than that of the mixed alumina/iron-pillared catalyst. Other new catalysts, that were prepared by first pillaring with an organic ammonium pillaring agent, then introducing a lower number of silica or alumina pillars, and finally the iron component, were also tested. The mixed alumina/iron-pillared catalysts was further tested at low concentration for pyrene hydrogenating and hydrocracking activities.

  14. Studies of incipient oxidation of pyrite for improved rejection. Fifth quarterly technical progress report, October 1, 1993--December 31, 1993

    SciTech Connect

    Yoon, R.H.; Richardson, P.E.

    1993-12-31

    Oxidation of fresh surfaces of coal- and mineral-pyrite has been studied using electrochemical and photoelectrochemical techniques. This work was undertaken to better understand the oxidation processes that cause self-induced flotation of pyrite. Fresh surfaces were created by fracturing pyrite in situ, i.e., in solution. Chronoamperometry was used to determine the potential at which a newly created surface does not show oxidation or reduction currents. The ``stable`` potentials for pyrite are {minus}0.28 V (SHE) at pH 9.2 and 0 V at pH 4.6. Subsequent cyclic voltammograms show the incipient oxidation mechanism that involves the formation of sulfur products, which are believed to be hydrophobic. It is shown that the lower flotation edge of pyrite coincides with its incipient oxidation potential. The photocurrent generated at fractured pyrite surfaces by chopped illumination was used to determine the semiconducting characteristics of the electrodes. The results indicate that a spontaneous depletion layer is formed on the fresh surfaces of n-type pyrite. The depletion layer is attributed to an intrinsic, acceptor-like surface state. Charge storage in this surface state pins the band edges over a wide potential range, accounting for the metallic-like electrochemical behavior that has been reported for pyrite. The existence of an intrinsic surface state is consistent with XPS studies on pyrite surfaces prepared in vacuum, which reveal an FeS-like species in the surface region. During this report period, all of the data previously obtained has been analyzed in an attempt to better understand the mechanism of pyrite flotation with respect to its oxidation. The results of this analysis are included in this quarterly report. In addition, samples of pyrite from seven different sources were obtained. In situ fracture, photoelectrochemical and cyclic voltammetry studies have been conducted on electrodes made from these pyrites.

  15. Fine particle clay catalysts for coal liquefaction. Quarterly technical progress report, November 9, 1991--February 8, 1992

    SciTech Connect

    Olson, E.S.

    1995-10-01

    The investigation of methods for the production and testing of iron-pillared clay catalysts was continued in this quarter. The surface area of the mixed alumina/iron pillared clay catalyst decreased to 51 m{sup 2}/g on sulfidation. Thus the stability of the alumina pillars during the sulfidation and thermal treatments prevented the total collapse that occurred in the case of the iron-pillared clays. Previously the mixed alumina/iron pillared clays were tested for hydrocracking activities with bibenzyl. This testing was extended to a determination of activity with a second model compound substrate (pyrene), representative of the polynuclear aromatic systems present in coal. Testing of the mixed alumina/iron-pillared catalysts with 1-methylnaphthalene gave interesting results that demonstrate shape selectivity. The clay-supported iron hydroxyoxide catalysts prepared by impregnation of iron species on acidic clays were further investigated. Sulfidation of these catalysts using the carbon disulfide in situ method gave hydrocracking activities with bibenzyl that were somewhat less than those obtained by presulfidation with H{sub 2}/H{sub 2}S mixtures. Liquefaction of Wyodak subbituminous coal was very successful with the iron impregnated clay catalyst, giving a highly soluble product. High conversions were also obtained with the mixed alumina/iron-pillared clay catalyst, but the yield of oil-solubles was considerably lower. Several new catalysts were synthesized with the idea of decreasing the pillar density and thereby increasing the micropore volume. These catalysts were prepared by first pillaring with an organic ammonium pillaring agent, then introducing a lower number of silica or alumina pillars. Finally the iron component was added either before or after thermal removal of organic pillars.

  16. Evaluation, engineering and development of advanced cyclone processes. Quarterly technical progress report No. 15, April 1, 1994--June 30, 1994

    SciTech Connect

    1994-12-31

    The project goal is to develop an advanced coal beneficiation technology that can achieve high recovery of the parent coal`s calorific value, while maximizing pyritic sulfur removal. Coal cleaning is to be accomplished by physical means incorporating an advanced form of cycloning or gravimetric process. Evaluation of different media types and their attendant systems for recovery, concentration, and regeneration is to be completed. Phase I, media evaluation, now completed involved a paper study and a number of laboratory tests to eliminate all but the best media options. Phase II, media testing, involved detailed testing of the more promising media and separators in a closed-loop pilot facility circuit. In the final phase, Phase III, it is proposed to test individual components of the process using the optimum medium, separator, and medium recovery systems(s) selected in prior phases. Some of the highlights for this reporting period are: (1) Outomec conducted a second set of hot water wash experiments. These hot water experiments, using prefiltered medium, yielded a significant improvement in calcium nitrate recovery, and showed a consistent decrease in residuum calcium nitrate with increasing wash rate. (2) Several alternatives were investigated for potential reduction in thermal regeneration process costs. Culligan, Spin Tek, and Rochem, manufacturers of reverse osmosis or ultra filtration systems were contacted. Rochem ultimately performed laboratory experiments. Starting with a dilute medium density of 1.07, the Rochem laboratory system achieved a density of 1.11. A density of 1.22 sg would be commercially attainable. This is less than the target medium density of 1.35, meaning that if their system were utilized, some thermal means would still be required to regenerate medium to operating density. (3) Management and Technical Systems initiated work on a preliminary economic study and will submit a report during the next quarterly reporting period.

  17. Low-rank coal research under the UND/DOE cooperative agreement. Quarterly technical progress report, July-September 1983

    SciTech Connect

    Wiltsee, G.A. Jr.

    1983-01-01

    Two long gasification tests were accomplished (66 and 72 hours of slagging operation) this quarter, and the balance of the wastewater needed for the second cooling tower (CT) test (approx. 11,000 gallons) was generated. Eleven thousand gallons of slagging fixed-bed gasifier (SFBG) wastewater were solvent extracted and ammonia stripped (AS) to nominal levels of 160 mg/1 phenol and 600 mg/1 NH/sub 3/. This wastewater is being further treated by activated sludge (AS) and granular activated carbon (GAC) processing to prepare a high quality makeup for the second CT test. Phenol mass balances indicated that > 90 pct of the phenol was stripped from the tower, indicating that previous assumptions of high levels of biodegradation were erroneous. Over 80 pct of the ammonia and about 25 pct of the methanol were also stripped. Data collected during steady state operation of the bench-scale rotating biological contractor indicate complete removal of phenolics and alcohols, and 94 pct removal of BOD. Nitrification also occurred in this unit, with over 30 pct removal of ammonia. Problems due to individual bacteria, present in the biotreated wastewater, passing through the multi-media filter and thus decreasing the carbon adsorption efficiency of the GAC system, have resulted in lower treatment rates than originally anticipated. As a result, to achieve the desired treatment, the contact time of the wastewater with the carbon in the granular activated carbon system has been increased. Since this has decreased the treatment rate, a larger carbon adsorption system has been designed and is presently being constructed.

  18. Fossil Energy Program quarterly progress report for the period ending June 30, 1985. [Ni-Fe aluminides

    SciTech Connect

    Bradley, R.A.

    1985-09-01

    This report covers progress made during the period April 1 through June 30, 1985, for research and development projects that contribute to the advancement of various fossil energy technologies. Projects on the Fossil Energy Program are supported by DOE Office of Fossil Energy, DOE Office of Basic Energy Sciences, the Electric Power Research Institute, and the Tennessee Valley Authority. The Fossil Energy Program organization chart is shown in Appendix A. Summaries and progress reports are presented for the following: (1) materials research and development; (2) fossil energy enviromental programs; (3) coal conversion development; (4) process analysis and development; (5) generalized equilibrium models of liquids and gaseous fuels supply; (6) fluidized bed combustion joint program; and (7) coal chemistry.

  19. Advanced Turbine Systems (ATS) program conceptual design and product development. Quarterly progress report, December 1, 1995--February 29, 1996

    SciTech Connect

    1997-06-01

    This report describes the overall program status of the General Electric Advanced Gas Turbine Development program, and reports progress on three main task areas. The program is focused on two specific products: (1) a 70-MW class industrial gas turbine based on the GE90 core technology, utilizing a new air cooling methodology; and (2) a 200-MW class utility gas turbine based on an advanced GE heavy-duty machine, utilizing advanced cooling and enhancement in component efficiency. The emphasis for the industrial system is placed on cycle design and low emission combustion. For the utility system, the focus is on developing a technology base for advanced turbine cooling while achieving low emission combustion. The three tasks included in this progress report are on: conversion to a coal-fueled advanced turbine system, integrated program plan, and design and test of critical components. 13 figs., 1 tab.

  20. Space Power MHD (magnetohydrodynamic) System: Third quarterly technical progress report, 1 November 1987-31 January 1988

    SciTech Connect

    Not Available

    1988-03-15

    This progress report of the Space Power MHD System project presents the accomplishments during 1 November 1987 through 31 January 1988. The scope of work covered encompasses the definition of an MHD power system conceptual design and development plan (Task 1). Progress included the following: Subcontracts were issued to the MIT Plasma Fusion Center and the Westinghouse R and D Center. The performance of the 100 MW 500 sec. power system was optimized and the design concept finalized, including mass and energy balances. Mass and cost estimates were prepared. A design review was held at DOE/PETC. This also included the review of the technical issues definition and of the R and D Plan. Following the review, a final iteration on the conceptual design was initiated. Formulation of the R and D Plan was continued. Preparation of the Task 1 R and D Report was initiated. 12 figs.