Projections of Atmospheric Nutrient Deposition to the Chesapeake Bay Watershed

EPA Science Inventory

Atmospheric deposition remains one of the largest loadings of nutrients to the Chesapeake Bay watershed. The interplay between future land use, climate, and emission changes, however, will cause shifts in the future nutrient deposition regime (e.g., oxidized vs. reduced nitrogen...

Evaluation of a Leaf Collection and Street Cleaning Program as a Way to Reduce Nutrients and Organic Carbon in Urban Runoff

NASA Astrophysics Data System (ADS)

Selbig, W.

2016-12-01

Organic detritus can be major sources of nutrients and organic carbon in urban stormwater, especially in areas with dense overhead tree canopy. In order to meet impending regulation to reduce nutrient loads, many cities will require information on structural and non-structural stormwater control measures that target organic detritus. Most cities already conduct some level of leaf collection and existing street cleaning programs; however, few studies have quantified their water-quality benefits. The U.S Geological Survey measured the water-quality benefits of a municipal leaf collection program coupled with street cleaning in Madison, WI, USA during the months of October through November of 2014 and 2015. The calibration phase of the study (2014) characterized nutrient and organic carbon concentrations and loads in runoff from two paired basins without leaf collection or street cleaning. During the treatment phase (2015), leaf collection and street cleaning was done in the test basin by city personnel on a weekly basis. Additionally, prior to each precipitation event, USGS personnel removed as much organic debris from the street surface as reasonably possible. The control remained without street cleaning or leaf collection for the entire monitoring period. During the fall, leaf collection and street cleaning was able to remove the increased amount of organic debris from the curb and street surface which resulted in statistically significant (p<0.05) reductions in loads of phosphorus, nitrogen and organic carbon. Total and dissolved phosphorus loads were reduced by 84 and 83 percent, respectively. Similarly, total and dissolved organic carbon was reduced by 81 and 86 percent, and total and dissolved nitrogen was reduced by 74 and 71 percent, respectively. In the control basin, 60 percent of the annual phosphorus load occurred in fall (winter excluded), the majority of which was dissolved as orthophosphorus, compared to only 16 percent in the test basin. While the leaf collection practices adopted during this study may surpass those used by most municipal programs, results from this study suggest a significant reduction of nutrient and organic carbon loads in urban stormwater is feasible when leaves and other organic detritus are removed from streets prior to precipitation events.

Temporal responses of coastal hypoxia to nutrient loading and physical controls

NASA Astrophysics Data System (ADS)

Kemp, W. M.; Testa, J. M.; Conley, D. J.; Gilbert, D.; Hagy, J. D.

2009-12-01

The incidence and intensity of hypoxic waters in coastal aquatic ecosystems has been expanding in recent decades coincident with eutrophication of the coastal zone. Worldwide, there is strong interest in reducing the size and duration of hypoxia in coastal waters, because hypoxia causes negative effects for many organisms and ecosystem processes. Although strategies to reduce hypoxia by decreasing nutrient loading are predicated on the assumption that this action would reverse eutrophication, recent analyses of historical data from European and North American coastal systems suggest little evidence for simple linear response trajectories. We review published parallel time-series data on hypoxia and loading rates for inorganic nutrients and labile organic matter to analyze trajectories of oxygen (O2) response to nutrient loading. We also assess existing knowledge of physical and ecological factors regulating O2 in coastal marine waters to facilitate analysis of hypoxia responses to reductions in nutrient (and/or organic matter) inputs. Of the 24 systems identified where concurrent time series of loading and O2 were available, half displayed relatively clear and direct recoveries following remediation. We explored in detail 5 well-studied systems that have exhibited complex, non-linear responses to variations in loading, including apparent "regime shifts". A summary of these analyses suggests that O2 conditions improved rapidly and linearly in systems where remediation focused on organic inputs from sewage treatment plants, which were the primary drivers of hypoxia. In larger more open systems where diffuse nutrient loads are more important in fueling O2 depletion and where climatic influences are pronounced, responses to remediation tended to follow non-linear trends that may include hysteresis and time-lags. Improved understanding of hypoxia remediation requires that future studies use comparative approaches and consider multiple regulating factors. These analyses should consider: (1) the dominant temporal scales of the hypoxia, (2) the relative contributions of inorganic and organic nutrients, (3) the influence of shifts in climatic and oceanographic processes, and (4) the roles of feedback interactions whereby O2-sensitive biogeochemistry, trophic interactions, and habitat conditions influence the nutrient and algal dynamics that regulate O2 levels.

Groundwater – The disregarded component in lake water and nutrient budgets. Part 2: effects of groundwater on nutrients

USGS Publications Warehouse

Lewandowski, Jörg; Meinikmann, Karin; Nützmann, Gunnar; Rosenberry, Donald O.

2015-01-01

Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer-lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater-borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N2 in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer-lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater-borne P loads vary from 0.74 to 2900 mg PO4-P m−2 year−1; for N, these loads vary from 0.001 to 640 g m−2 year−1. Even small amounts of seepage can carry large nutrient loads due to often high nutrient concentrations in groundwater. Large spatial heterogeneity, uncertain areal extent of the interface and difficult accessibility make every determination of LGD a challenge. However, determinations of LGD are essential to effective lake management.

Variability in climate change simulations affects needed long-term riverine nutrient reductions for the Baltic Sea.

PubMed

Bring, Arvid; Rogberg, Peter; Destouni, Georgia

2015-06-01

Changes to runoff due to climate change may influence management of nutrient loading to the sea. Assuming unchanged river nutrient concentrations, we evaluate the effects of changing runoff on commitments to nutrient reductions under the Baltic Sea Action Plan. For several countries, climate projections point to large variability in load changes in relation to reduction targets. These changes either increase loads, making the target more difficult to reach, or decrease them, leading instead to a full achievement of the target. The impact of variability in climate projections varies with the size of the reduction target and is larger for countries with more limited commitments. In the end, a number of focused actions are needed to manage the effects of climate change on nutrient loads: reducing uncertainty in climate projections, deciding on frameworks to identify best performing models with respect to land surface hydrology, and increasing efforts at sustained monitoring of water flow changes.

Variability in climate change simulations affects needed long-term riverine nutrient reductions for the Baltic Sea

DOE PAGES

Bring, Arvid; Rogberg, Peter; Destouni, Georgia

2015-05-28

Changes to runoff due to climate change may influence management of nutrient loading to the sea. Assuming unchanged river nutrient concentrations, we evaluate the effects of changing runoff on commitments to nutrient reductions under the Baltic Sea Action Plan. For several countries, climate projections point to large variability in load changes in relation to reduction targets. These changes either increase loads, making the target more difficult to reach, or decrease them, leading instead to a full achievement of the target. The impact of variability in climate projections varies with the size of the reduction target and is larger for countriesmore » with more limited commitments. Finally, in the end, a number of focused actions are needed to manage the effects of climate change on nutrient loads: reducing uncertainty in climate projections, deciding on frameworks to identify best performing models with respect to land surface hydrology, and increasing efforts at sustained monitoring of water flow changes.« less

Variability in climate change simulations affects needed long-term riverine nutrient reductions for the Baltic Sea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bring, Arvid; Rogberg, Peter; Destouni, Georgia

Changes to runoff due to climate change may influence management of nutrient loading to the sea. Assuming unchanged river nutrient concentrations, we evaluate the effects of changing runoff on commitments to nutrient reductions under the Baltic Sea Action Plan. For several countries, climate projections point to large variability in load changes in relation to reduction targets. These changes either increase loads, making the target more difficult to reach, or decrease them, leading instead to a full achievement of the target. The impact of variability in climate projections varies with the size of the reduction target and is larger for countriesmore » with more limited commitments. Finally, in the end, a number of focused actions are needed to manage the effects of climate change on nutrient loads: reducing uncertainty in climate projections, deciding on frameworks to identify best performing models with respect to land surface hydrology, and increasing efforts at sustained monitoring of water flow changes.« less

Effects of changes in nutrient loading and composition on hypoxia dynamics and internal nutrient cycling of a stratified coastal lagoon

NASA Astrophysics Data System (ADS)

Zhu, Yafei; McCowan, Andrew; Cook, Perran L. M.

2017-10-01

The effects of changes in catchment nutrient loading and composition on the phytoplankton dynamics, development of hypoxia and internal nutrient dynamics in a stratified coastal lagoon system (the Gippsland Lakes) were investigated using a 3-D coupled hydrodynamic biogeochemical water quality model. The study showed that primary production was equally sensitive to changed dissolved inorganic and particulate organic nitrogen loads, highlighting the need for a better understanding of particulate organic matter bioavailability. Stratification and sediment carbon enrichment were the main drivers for the hypoxia and subsequent sediment phosphorus release in Lake King. High primary production stimulated by large nitrogen loading brought on by a winter flood contributed almost all the sediment carbon deposition (as opposed to catchment loads), which was ultimately responsible for summer bottom-water hypoxia. Interestingly, internal recycling of phosphorus was more sensitive to changed nitrogen loads than total phosphorus loads, highlighting the potential importance of nitrogen loads exerting a control over systems that become phosphorus limited (such as during summer nitrogen-fixing blooms of cyanobacteria). Therefore, the current study highlighted the need to reduce both total nitrogen and total phosphorus for water quality improvement in estuarine systems.

Modeling the relative importance of nutrient and carbon loads ...

EPA Pesticide Factsheets

The Louisiana continental shelf (LCS) in the northern Gulf of Mexico experiences bottom water hypoxia in the summer. In order to gain a more fundamental understanding of the controlling factors leading to hypoxia, the Gulf of Mexico Dissolved Oxygen Model (GoMDOM) was applied to this area to simulate dissolved oxygen concentrations in the water as a function of various nutrient loadings. The model is a numerical, biogeochemical, three-dimensional ecological model that receives its physical transport data from the Navy Coastal Ocean Model (NCOM-LCS). GoMDOM was calibrated to a large set of nutrient, phytoplankton, dissolved oxygen, sediment nutrient flux, sediment oxygen demand (SOD), primary production, and respiration data collected in 2006 and corroborated with field data collected in 2003. The primary objective was to use the model to estimate a nutrient load reduction of both nitrogen and phosphorus necessary to reduce the size of the hypoxic area to 5,000 km2, a goal established in the 2008 Gulf of Mexico Hypoxia Action Plan prepared by the Mississippi River/Gulf of Mexico Watershed Nutrient Task Force. Using the year 2006 as a test case, the model results suggest that the nitrogen and phosphorus load reduction from the Atchafalaya and Mississippi River basins would need to be reduced by 64% to achieve the target hypoxia area. The Louisiana continental shelf (LCS) in the northern part of the Gulf of Mexico has a history of subsurface hypoxia in the summer.

River delta network hydraulic residence time distributions and their role in coastal nutrient biogeochemistry

NASA Astrophysics Data System (ADS)

Hiatt, M. R.; Castaneda, E.; Twilley, R.; Hodges, B. R.; Passalacqua, P.

2015-12-01

River deltas have the potential to mitigate increased nutrient loading to coastal waters by acting as biofilters that reduce the impact of nutrient enrichment on downstream ecosystems. Hydraulic residence time (HRT) is known to be a major control on biogeochemical processes and deltaic floodplains are hypothesized to have relatively long HRTs. Hydrological connectivity and delta floodplain inundation induced by riverine forces, tides, and winds likely alter surface water flow patterns and HRTs. Since deltaic floodplains are important elements of delta networks and receive significant fluxes of water, sediment, and nutrients from distributary channels, biogeochemical transformations occurring within these zones could significantly reduce nutrient loading to coastal receiving waters. However, network-scale estimates of HRT in river deltas are lacking and little is known about the effects of tides, wind, and the riverine input on the HRT distribution. Subsequently, there lacks a benchmark for evaluating the impact of engineered river diversions on coastal nutrient ecology. In this study, we estimate the HRT of a coastal river delta by using hydrodynamic modeling supported by field data and relate the HRT to spatial and temporal patterns in nitrate levels measured at discrete stations inside a delta island at Wax Lake Delta. We highlight the control of the degree of hydrological connectivity between distributary channels and interdistributary islands on the network HRT distribution and address the roles of tides and wind on altering the shape of the distribution. We compare the observed nitrate concentrations to patterns of channel-floodplain hydrological connectivity and find this connectivity to play a significant role in the nutrient removal. Our results provide insight into the potential role of deltaic wetlands in reducing the nutrient loading to near-shore waters in response to large-scale river diversions.

Bacteria Contribute to Sediment Nutrient Release and Reflect Progressed Eutrophication-Driven Hypoxia in an Organic-Rich Continental Sea

PubMed Central

Sinkko, Hanna; Lukkari, Kaarina; Sihvonen, Leila M.; Sivonen, Kaarina; Leivuori, Mirja; Rantanen, Matias; Paulin, Lars; Lyra, Christina

2013-01-01

In the sedimental organic matter of eutrophic continental seas, such as the largest dead zone in the world, the Baltic Sea, bacteria may directly participate in nutrient release by mineralizing organic matter or indirectly by altering the sediment’s ability to retain nutrients. Here, we present a case study of a hypoxic sea, which receives riverine nutrient loading and in which microbe-mediated vicious cycles of nutrients prevail. We showed that bacterial communities changed along the horizontal loading and vertical mineralization gradients in the Gulf of Finland of the Baltic Sea, using multivariate statistics of terminal restriction fragments and sediment chemical, spatial and other properties of the sampling sites. The change was mainly explained by concentrations of organic carbon, nitrogen and phosphorus, which showed strong positive correlation with Flavobacteria, Sphingobacteria, Alphaproteobacteria and Gammaproteobacteria. These bacteria predominated in the most organic-rich coastal surface sediments overlain by oxic bottom water, whereas sulphate-reducing bacteria, particularly the genus Desulfobacula, prevailed in the reduced organic-rich surface sediments in the open sea. They correlated positively with organic nitrogen and phosphorus, as well as manganese oxides. These relationships suggest that the bacterial groups participated in the aerobic and anaerobic degradation of organic matter and contributed to nutrient cycling. The high abundance of sulphate reducers in the surficial sediment layers reflects the persistence of eutrophication-induced hypoxia causing ecosystem-level changes in the Baltic Sea. The sulphate reducers began to decrease below depths of 20 cm, where members of the family Anaerolineaceae (phylum Chloroflexi) increased, possibly taking part in terminal mineralization processes. Our study provides valuable information on how organic loading affects sediment bacterial community compositions, which consequently may maintain active nutrient recycling. This information is needed to improve our understanding on nutrient cycling in shallow seas where the dead zones are continuously spreading worldwide. PMID:23825619

Nitrogen enrichment suppresses other environmental drivers and homogenizes salt marsh leaf microbiome

DOE PAGES

Daleo, Pedro; Alberti, Juan; Jumpponen, Ari; ...

2018-04-12

Microbial community assembly is affected by a combination of forces that act simultaneously, but the mechanisms underpinning their relative influences remain elusive. This gap strongly limits our ability to predict human impacts on microbial communities and the processes they regulate. Here, we experimentally demonstrate that increased salinity stress, food web alteration and nutrient loading interact to drive outcomes in salt marsh fungal leaf communities. Both salinity stress and food web alterations drove communities to deterministically diverge, resulting in distinct fungal communities. Increased nutrient loads, nevertheless, partially suppressed the influence of other factors as determinants of fungal assembly. Using a nullmore » model approach, we found that increased nutrient loads enhanced the relative importance of stochastic over deterministic divergent processes; without increased nutrient loads, samples from different treatments showed a relatively (deterministic) divergent community assembly whereas increased nutrient loads drove the system to more stochastic assemblies, suppressing the effect of other treatments. These results demonstrate that common anthropogenic modifications can interact to control fungal community assembly. As a result, our results suggest that when the environmental conditions are spatially heterogeneous (as in our case, caused by specific combinations of experimental treatments), increased stochasticity caused by greater nutrient inputs can reduce the importance of deterministic filters that otherwise caused divergence, thus driving to microbial community homogenization.« less

Nitrogen enrichment suppresses other environmental drivers and homogenizes salt marsh leaf microbiome.

PubMed

Daleo, Pedro; Alberti, Juan; Jumpponen, Ari; Veach, Allison; Ialonardi, Florencia; Iribarne, Oscar; Silliman, Brian

2018-06-01

Microbial community assembly is affected by a combination of forces that act simultaneously, but the mechanisms underpinning their relative influences remain elusive. This gap strongly limits our ability to predict human impacts on microbial communities and the processes they regulate. Here, we experimentally demonstrate that increased salinity stress, food web alteration and nutrient loading interact to drive outcomes in salt marsh fungal leaf communities. Both salinity stress and food web alterations drove communities to deterministically diverge, resulting in distinct fungal communities. Increased nutrient loads, nevertheless, partially suppressed the influence of other factors as determinants of fungal assembly. Using a null model approach, we found that increased nutrient loads enhanced the relative importance of stochastic over deterministic divergent processes; without increased nutrient loads, samples from different treatments showed a relatively (deterministic) divergent community assembly whereas increased nutrient loads drove the system to more stochastic assemblies, suppressing the effect of other treatments. These results demonstrate that common anthropogenic modifications can interact to control fungal community assembly. Furthermore, our results suggest that when the environmental conditions are spatially heterogeneous (as in our case, caused by specific combinations of experimental treatments), increased stochasticity caused by greater nutrient inputs can reduce the importance of deterministic filters that otherwise caused divergence, thus driving to microbial community homogenization. © 2018 by the Ecological Society of America.

Nitrogen enrichment suppresses other environmental drivers and homogenizes salt marsh leaf microbiome

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daleo, Pedro; Alberti, Juan; Jumpponen, Ari

Microbial community assembly is affected by a combination of forces that act simultaneously, but the mechanisms underpinning their relative influences remain elusive. This gap strongly limits our ability to predict human impacts on microbial communities and the processes they regulate. Here, we experimentally demonstrate that increased salinity stress, food web alteration and nutrient loading interact to drive outcomes in salt marsh fungal leaf communities. Both salinity stress and food web alterations drove communities to deterministically diverge, resulting in distinct fungal communities. Increased nutrient loads, nevertheless, partially suppressed the influence of other factors as determinants of fungal assembly. Using a nullmore » model approach, we found that increased nutrient loads enhanced the relative importance of stochastic over deterministic divergent processes; without increased nutrient loads, samples from different treatments showed a relatively (deterministic) divergent community assembly whereas increased nutrient loads drove the system to more stochastic assemblies, suppressing the effect of other treatments. These results demonstrate that common anthropogenic modifications can interact to control fungal community assembly. As a result, our results suggest that when the environmental conditions are spatially heterogeneous (as in our case, caused by specific combinations of experimental treatments), increased stochasticity caused by greater nutrient inputs can reduce the importance of deterministic filters that otherwise caused divergence, thus driving to microbial community homogenization.« less

Character and Trends of Water Quality in the Blue River Basin, Kansas City Metropolitan Area, Missouri and Kansas, 1998 through 2007

USGS Publications Warehouse

Wilkison, Donald H.; Armstrong, Daniel J.; Hampton, Sarah A.

2009-01-01

Water-quality and ecological character and trends in the metropolitan Blue River Basin were evaluated from 1998 through 2007 to provide spatial and temporal resolution to factors that affect the quality of water and biota in the basin and provide a basis for assessing the efficacy of long-term combined sewer control and basin management plans. Assessments included measurements of stream discharge, pH, dissolved oxygen, specific conductance, turbidity, nutrients (dissolved and total nitrogen and phosphorus species), fecal-indicator bacteria (Escherichia coli and fecal coliform), suspended sediment, organic wastewater and pharmaceutical compounds, and sources of these compounds as well as the quality of stream biota in the basin. Because of the nature and myriad of factors that affect basin water quality, multiple strategies are needed to decrease constituent loads in streams. Strategies designed to decrease or eliminate combined sewer overflows (CSOs) would substantially reduce the annual loads of nutrients and fecal-indicator bacteria in Brush Creek, but have little effect on Blue River loadings. Nonpoint source reductions to Brush Creek could potentially have an equivalent, if not greater, effect on water quality than would CSO reductions. Nonpoint source reductions could also substantially decrease annual nutrient and bacteria loadings to the Blue River and Indian Creek. Methods designed to decrease nutrient loads originating from Blue River and Indian Creek wastewater treatment plants (WWTPs) could substantially reduce the overall nutrient load in these streams. For the main stem of the Blue River and Indian Creek, primary sources of nutrients were nonpoint source runoff and WWTPs discharges; however, the relative contribution of each source varied depending on how wet or dry the year was and the number of upstream WWTPs. On Brush Creek, approximately two-thirds of the nutrients originated from nonpoint sources and the remainder from CSOs. Nutrient assimilation processes, which reduced total nitrogen loads by approximately 13 percent and total phosphorus loads by double that amount in a 20-kilometer reach of the Blue River during three synoptic base-flow sampling events between August through September 2004 and September 2005, likely are limited to selected periods during any given year and may not substantially reduce annual nutrient loads. Bacteria densities typically increased with increasing urbanization, and bacteria loadings to the Blue River and Indian Creek were almost entirely the result of nonpoint source runoff. WWTPs contributed, on average, less than 1 percent of the bacteria to these reaches, and in areas of the Blue River that had combined sewers, CSOs contributed only minor amounts (less than 2 percent) of the total annual load in 2005. The bulk of the fecal-indicator bacteria load in Brush Creek also originated from nonpoint sources with the remainder from CSOs. From October 2002 through September 2007, estimated daily mean Escherichia coli bacteria density in upper reaches of the Blue River met the State of Missouri secondary contact criterion standard approximately 85 percent of the time. However, in lower Blue River reaches, the same threshold was exceeded approximately 45 percent of the time. The tributary with the greatest number of CSO discharge points, Brush Creek, contributed approximately 10 percent of the bacteria loads to downstream reaches. The tributary Town Fork Creek had median base-flow Escherichia coli densities that were double that of other basin sites and stormflow densities 10 times greater than those in other parts of the basin largely because approximately one-fourth of the runoff in the Town Fork Creek Basin is believed to originate in combined sewers. Genotypic source typing of bacteria indicated that more than half of the bacteria in this tributary originated from human sources with two storms contributing the bulk of all bacteria sourced as human. However, areas outsid

Environmental response of an Irish estuary to changing land management practices.

PubMed

Ní Longphuirt, Sorcha; O'Boyle, Shane; Stengel, Dagmar Brigitte

2015-07-15

Anthropogenic pressures have led to problems of nutrient over-enrichment and eutrophication in estuarine and coastal systems on a global scale. Recent improvements in farming practices, specifically a decrease in fertiliser application rates, have reduced nutrient loadings in Ireland. In line with national and European Directives, monitoring of Irish estuarine systems has been conducted for the last 30years, allowing a comparison of the effectiveness of measures undertaken to improve water quality and chemical and biological trends. The Blackwater Estuary, which drains a large agricultural catchment on the south coast of Ireland, has experienced a decrease in calculated nitrogen (N) (17%) and phosphorus (P) (20%) loads in the last decade. Monitored long-term river inputs reflect the reductions while estuarine P concentrations, chlorophyll and dissolved oxygen saturation show concurrent improvement. Consistently high N concentrations suggest a decoupling between N loads and estuarine responses. This highlights the complex interaction between N and P load reductions, and biochemical processes relating to remineralisation and primary production which can alter the effectiveness of the estuarine filter in reducing nutrient transport to the coastal zone. Effective management and reduction of both diffuse and point nutrient sources to surface waters require a consideration of the processes which may alter the effectiveness of measures in estuarine and coastal waters. Copyright © 2015. Published by Elsevier B.V.

Annual Nutrient Loadings, Primary Productivity, and Trophic State of Lake Koocanusa, Montana and British Columbia, 1972-80

USGS Publications Warehouse

Woods, Paul F.

1982-01-01

Limnological data collected at Lake Koocanusa were used to investigate the relationship of nutrient loadings, primary productivity, and trophic state of the reservoir during 1972-80. The reservoir, on the Kootenai River, was impounded by Libby Dam on March 21, 1972. Manipulation of the 7.16-cubic-kilometer reservoir for flood control, its primary function, created large fluctuations in reservoir volume and produced annual lake-filling times that ranged from 0.14 to 0.66 year. Loadings of nitrogen and phosphorus prior to and following impoundment of Lake Koocanusa were found to be large enough to predict eutrophic conditions. Beginning in 1976, total phosphorus loadings, but not total nitrogen loadings, were substantially reduced following improvements in waste-water treatment at a fertilizer plant located upstream from the reservoir. The closure of Libby Dam substantially reduced loadings of nitrogen and phosphorus downstream from Lake Koocanusa. On the average, the reservoir retained 63 percent of its influent loading of total phosphorus and 25 percent of its influent loading of total nitrogen. Daily areal and volumetric primary productivity varied widely in each year at four sampled limnological stations. During the 9 years studied, daily areal primary productivity, in milligrams of carbon fixed per square meter, ranged from 0.4 to 420.0; the mean of the 313 sampled days was 128.5. Annual areal primary productivity ranged from 23.2 to 38.5 grams of carbon fixed per square meter and thereby categorized Lake Koocanusa as oligotrophic. The relationship of annual areal primary productivity and 12 selected environmental variables was determined by multiple regression analysis. One of the models that was derived used two variables-annual euphotic zone depth and annual areal phosphorus loading-and accounted for 62.0 percent of the variation in annual areal primary productivity. The distribution of chlorophyll a within the water column indicated that, on the average, more than one-half of the phytoplankton in the reservoir was beneath the euphotic zone. These results support the hypothesis that the reservoir's weak thermal structure had allowed circulation of phytoplankton out of the euphotic zone. The trophic state of Lake Koocanusa was categorized as eutrophic when based on the relationship of the nutrient loadings and the reservoir's ratio of mean depth to hydraulic-residence time. This result conflicted with the oligotrophic ranking the reservoir received based on its areal primary productivity. The discrepancy in trophic state was attributed mainly to the failure of nutrient loading models to adequately account for physical processes within reservoirs. Part of the nutrient loading that entered Lake Koocanusa was unavailable to phytoplankton because the nutrients were carried beneath the euphotic zone by large volumes of interflow and underflow. Another part of the nutrient loading was adsorbed to suspended sediment and removed from the water column. Thus, phytoplankton primary productivity was controlled not only by nutrients, but also by other limno logical processes.

Identifying external nutrient reduction requirements and potential in the hypereutrophic Lake Taihu Basin, China.

PubMed

Peng, Jiao-Ting; Zhu, Xiao-Dong; Sun, Xiang; Song, Xiao-Wei

2018-04-01

Reducing external nutrient loads is the first step for controlling eutrophication. Here, we identified external nutrient reduction requirements and potential of strategies for achieving reductions to remediate a eutrophic water body, Lake Taihu, China. A mass balance approach based on the entire lake was used to identify nutrient reduction requirements; an empirical export coefficient approach was introduced to estimate the nutrient reduction potential of the overall program on integrated regulation of Taihu Lake Basin (hereafter referred to as the "Guideline"). Reduction requirements included external total nitrogen (TN) and total phosphorus (TP) loads, which should be reduced by 41-55 and 25-50%, respectively, to prevent nutrient accumulation in Lake Taihu and to meet the planned water quality targets. In 2010, which is the most seriously polluted calendar year during the 2008-2014 period, the nutrient reduction requirements were estimated to be 36,819 tons of N and 2442 tons of P, and the potential nutrient reduction strategies would reduce approximately 25,821 tons of N and 3024 tons of P. Since there is a net N remaining in the reduction requirements, it should be the focus and deserves more attention in identifying external nutrient reduction strategies. Moreover, abatement measures outlined in the Guideline with high P reduction potential required large monetary investments. Achieving TP reduction requirement using the cost-effective strategy costs about 80.24 million USD. The design of nutrient reduction strategies should be enacted according to regional and sectoral differences and the cost-effectiveness of abatement measures.

Nutrient storage rates in a national marsh receiving waste water

Treesearch

J.A. Nyman

2000-01-01

Artificial wetlands are commonly used to improve water quality in rivers and the coastal zone. In most wetlands associated with rivers, denitrification is probably the primary process that reduces nutrient loading. Where rivers meet oceans, however, significant amounts of nutrients might be permanently buried in wetlands because of global sea-level rise and regional...

Least-cost control of agricultural nutrient contributions to the Gulf of Mexico hypoxic zone.

PubMed

Rabotyagov, Sergey; Campbell, Todd; Jha, Manoj; Gassman, Philip W; Arnold, Jeffrey; Kurkalova, Lyubov; Secchi, Silvia; Feng, Hongli; Kling, Catherine L

2010-09-01

In 2008, the hypoxic zone in the Gulf of Mexico, measuring 20 720 km2, was one of the two largest reported since measurement of the zone began in 1985. The extent of the hypoxic zone is related to nitrogen and phosphorous loadings originating on agricultural fields in the upper Midwest. This study combines the tools of evolutionary computation with a water quality model and cost data to develop a trade-off frontier for the Upper Mississippi River Basin specifying the least cost of achieving nutrient reductions and the location of the agricultural conservation practices needed. The frontier allows policymakers and stakeholders to explicitly see the trade-offs between cost and nutrient reductions. For example, the cost of reducing annual nitrate-N loadings by 30% is estimated to be US$1.4 billion/year, with a concomitant 36% reduction in P and the cost of reducing annual P loadings by 30% is estimated to be US$370 million/year, with a concomitant 9% reduction in nitrate-N.

Internal cycling, not external loading, decides the nutrient limitation in eutrophic lake: A dynamic model with temporal Bayesian hierarchical inference.

PubMed

Wu, Zhen; Liu, Yong; Liang, Zhongyao; Wu, Sifeng; Guo, Huaicheng

2017-06-01

Lake eutrophication is associated with excessive anthropogenic nutrients (mainly nitrogen (N) and phosphorus (P)) and unobserved internal nutrient cycling. Despite the advances in understanding the role of external loadings, the contribution of internal nutrient cycling is still an open question. A dynamic mass-balance model was developed to simulate and measure the contributions of internal cycling and external loading. It was based on the temporal Bayesian Hierarchical Framework (BHM), where we explored the seasonal patterns in the dynamics of nutrient cycling processes and the limitation of N and P on phytoplankton growth in hyper-eutrophic Lake Dianchi, China. The dynamic patterns of the five state variables (Chla, TP, ammonia, nitrate and organic N) were simulated based on the model. Five parameters (algae growth rate, sediment exchange rate of N and P, nitrification rate and denitrification rate) were estimated based on BHM. The model provided a good fit to observations. Our model results highlighted the role of internal cycling of N and P in Lake Dianchi. The internal cycling processes contributed more than external loading to the N and P changes in the water column. Further insights into the nutrient limitation analysis indicated that the sediment exchange of P determined the P limitation. Allowing for the contribution of denitrification to N removal, N was the more limiting nutrient in most of the time, however, P was the more important nutrient for eutrophication management. For Lake Dianchi, it would not be possible to recover solely by reducing the external watershed nutrient load; the mechanisms of internal cycling should also be considered as an approach to inhibit the release of sediments and to enhance denitrification. Copyright © 2017 Elsevier Ltd. All rights reserved.

Bayesian Modeling of the Assimilative Capacity Component of Stream Nutrient Export

EPA Science Inventory

Implementing stream restoration techniques and best management practices to reduce nonpoint source nutrients implies enhancement of the assimilative capacity for the stream system. In this paper, a Bayesian method for evaluating this component of a TMDL load capacity is developed...

Management of Local Stressors Can Improve the Resilience of Marine Canopy Algae to Global Stressors

PubMed Central

Strain, Elisabeth M. A.; van Belzen, Jim; van Dalen, Jeroen; Bouma, Tjeerd J.; Airoldi, Laura

2015-01-01

Coastal systems are increasingly threatened by multiple local anthropogenic and global climatic stressors. With the difficulties in remediating global stressors, management requires alternative approaches that focus on local scales. We used manipulative experiments to test whether reducing local stressors (sediment load and nutrient concentrations) can improve the resilience of foundation species (canopy algae along temperate rocky coastlines) to future projected global climate stressors (high wave exposure, increasing sea surface temperature), which are less amenable to management actions. We focused on Fucoids (Cystoseira barbata) along the north-western Adriatic coast in the Mediterranean Sea because of their ecological relevance, sensitivity to a variety of human impacts, and declared conservation priority. At current levels of sediment and nutrients, C. barbata showed negative responses to the simulated future scenarios of high wave exposure and increased sea surface temperature. However, reducing the sediment load increased the survival of C. barbata recruits by 90.24% at high wave exposure while reducing nutrient concentrations resulted in a 20.14% increase in the survival and enhanced the growth of recruited juveniles at high temperature. We conclude that improving water quality by reducing nutrient concentrations, and particularly the sediment load, would significantly increase the resilience of C. barbata populations to projected increases in climate stressors. Developing and applying appropriate targets for specific local anthropogenic stressors could be an effective management action to halt the severe and ongoing loss of key marine habitats. PMID:25807516

Efficiencies of forestry best management practices for reducing sediment and nutrient losses in the eastern United States

Treesearch

Pamela Edwards; Karl W.J. Williard

2010-01-01

Quantifying the effects of forestry best management practices (BMPs) on sediment and nutrient loads is a critical need. Through an exhaustive literature search, three paired forested watershed studies in the eastern United States were found that permitted the calculation of BMP efficiencies--the percent reduction in sediment or nutrients achieved by BMPs. For sediment...

Changes in nitrogen isotope ratios in estuarine biota following nutrient reductions to Narragansett Bay

EPA Science Inventory

Increased nutrient inputs globally have resulted in widespread eutrophication to many coastal water bodies including Narragansett Bay. Efforts to reduce point source nitrogen load¬ings from waste water treatment facilities (WWTFs) and combined sewer overflows (CSOs) started i...

Nitrogen and phosphorus loading from drained wetlands adjacent to Upper Klamath and Agency lakes, Oregon

USGS Publications Warehouse

Snyder, Daniel T.; Morace, Jennifer L.

1997-01-01

The results of this study could be useful in helping to prioritize which drained wetlands may provide the greatest benefits with regard to reducing nutrient loads to the lake if restoration or land-use modifications are instituted. Recent acquisition and planned restoration of drained wetland areas at the Wood River and Williamson River North properties may produce significant reduction in the quantity of nutrients released by the decomposition of peat soils of these areas. If the water table rises to predrainage levels, the peats soils may become inundated most of the year, resulting in the continued long-term storage of nutrients within the peat soils by reducing aerobic decomposition. The maximum benefit, in terms of decreasing potential nutrient loss due to peat decomposition, could be the reduction of total nitrogen and total phosphorus loss to about one-half that of the 1994–95 annual loss estimated for all the drained wetlands sampled for this study.

Sediment Budgets and Sources Inform a Novel Valley Bottom Restoration Practice Impacted by Legacy Sediment: The Big Spring Run, PA, Restoration Experiment

NASA Astrophysics Data System (ADS)

Walter, R. C.; Merritts, D.; Rahnis, M. A.; Gellis, A.; Hartranft, J.; Mayer, P. M.; Langland, M.; Forshay, K.; Weitzman, J. N.; Schwarz, E.; Bai, Y.; Blair, A.; Carter, A.; Daniels, S. S.; Lewis, E.; Ohlson, E.; Peck, E. K.; Schulte, K.; Smith, D.; Stein, Z.; Verna, D.; Wilson, E.

2017-12-01

Big Spring Run (BSR), a small agricultural watershed in southeastern Pennsylvania, is located in the Piedmont Physiographic Province, which has the highest nutrient and sediment yields in the Chesapeake Bay watershed. To effectively reduce nutrient and sediment loading it is important to monitor the effect of management practices on pollutant reduction. Here we present results of an ongoing study, begun in 2008, to understand the impact of a new valley bottom restoration strategy for reducing surface water sediment and nutrient loads. We test the hypotheses that removing legacy sediments will reduce sediment and phosphorus loads, and that restoring eco-hydrological functions of a buried Holocene wetland (Walter & Merritts 2008) will improve surface and groundwater quality by creating accommodation space to trap sediment and process nutrients. Comparisons of pre- and post-restoration gage data show that restoration lowered the annual sediment load by at least 118 t yr-1, or >75%, from the 1000 m-long restoration reach, with the entire reduction accounted for by legacy sediment removal. Repeat RTK-GPS surveys of pre-restoration stream banks verified that >90 t yr-1 of suspended sediment was from bank erosion within the restoration reach. Mass balance calculations of 137Cs data indicate 85-100% of both the pre-restoration and post-restoration suspended sediment storm load was from stream bank sources. This is consistent with trace element data which show that 80-90 % of the pre-restoration outgoing suspended sediment load at BSR was from bank erosion. Meanwhile, an inventory of fallout 137Cs activity from two hill slope transects adjacent to BSR yields average modern upland erosion rates of 2.7 t ha-1 yr-1 and 5.1 t ha-1 yr-1, showing modest erosion on slopes and deposition at toe of slopes. We conclude that upland farm slopes contribute little soil to the suspended sediment supply within this study area, and removal of historic valley bottom sediment effectively reduced bank erosion and sediment and phosphorus loads. Enhanced deposition further contributed to load reductions; prior to restoration, there was no deposition on tile pads on the 1.5 m-high legacy sediment "floodplain" terrace, whereas after restoration deposition on the low, restored floodplain showed net accumulation of 0.009 ± 0.012 m yr-1.

Urban Runoff and Nutrients Loading Control from Sustainable BMPs (Invited)

NASA Astrophysics Data System (ADS)

Xiao, Q.

2009-12-01

Climate change alters hydrodynamic and nutrient dynamic in both large and small geographic scales. These changes in our freshwater system directly affect drinking water, food production, business, and all aspects of our life. Along with climate change is increasing urbanization which alters natural landscape. Urban runoff has been identified as one of many potential drivers of the decline of pelagic fishes in san Francisco Bay-Delta region. Recent found of Pyrethroids in American River has increased scientists, public, and policy makers’ concern about our fresh water system. Increasing our understanding about the fundamental hydrodynamic, nutrient dynamics, and the transport mechanics of runoff and nutrients are important for future water resource and ecosystem management. Urbanization has resulted in significantly increasing the amount of impervious land cover. Most impervious land covers are hydrophobic that alters surface runoff because of the effects on surface retention storage, rainfall interception, and infiltration. Large volumes of excess storm runoff from urbanized areas cause flooding, water pollution, groundwater recharge deficits, destroyed habitat, beach closures, and toxicity to aquatic organisms. Parking lot alone accounts for more than 11% of these impervious surfaces. Contrast to impervious parking lot, turfgrass can accouter for 12% of urban land in California. Irrigated urban landscapes create considerable benefits to our daily living. However, the use of fertilizers and pesticides has caused environmental problems. Preventing fertilizers and pesticides from entering storm drains is an important goal for both landscape and storm runoff managers. Studies of urban runoff have found that the most fertilizers and pesticides are from dry weather runoff which conveys pollutants to sidewalks, streets, and storm drains. Controlling surface runoff is critical to preventing these pollutants from entering storm drains and water bodies. Large scale construction of runoff retention basins and treatment facilities to meet TMDL (Total Maximum Daily Load) regulations are not cost-effective or practical. An alternative approach is to control runoff and nutrients on-site through installation of decentralized BMPs that detain and infiltrate runoff before it reaches storm drains. Recent developed green-infrastructure which integrating engineered soil and trees to reduce runoff and nutrients loading is a self-sustained best management practice (BMP). This BMP has been testing and used in urban runoff control. In Davis, CA this type of BMPs were installed in a parking lot and a residential property to evaluate the system’s effectiveness on reducing storm runoff and pollutant loading from the parking lot and irrigated landscape. Storm runoff and pollutant loading were measured and monitored during February 2007 thru May 2009 from the parking lot. The BMP reduced surface runoff and nutrients by 88.8% and 95.3%, respectively. In the residential irrigated landscape, the dry-weather runoff was monitored during 2007 irrigation season, the BMP captured almost all dry weather runoff. The performance of these BMPs demonstrated their potential use for reducing runoff and nutrients loading. Control urban runoff from these 23% landscape (i.e., parking lot and irrigated turf grass) could largely alter the runoff and nutrients transport and their dynamic in our water system.

Wetland Management Reduces Sediment and Nutrient Loading to the Upper Mississippi River

EPA Science Inventory

Restored riparian wetlands in the Upper Mississippi River basin have the potential to remove sediment and nutrients from tributaries before they flow into the Mississippi River. For 3 yr we calculated retention efficiencies of a marsh complex, which consisted of a restored marsh...

Potential dual use of biochar for wastewater treatment and soil amelioration

NASA Astrophysics Data System (ADS)

Marschner, Bernd; Werner, Steffen; Alfes, Karsten; Lübken, Manfred

2013-04-01

Irrigating crops with wastewater from open drainage channels is a common practice in urban agricultural production in many dry regions of Africa, Asia and Latin America. While the wastewater-borne nutrients reduce the need for inputs of mineral fertilizers or manures and thus reduce production costs, wastewater-borne pathogens and contaminants pose a health risk for the producers and consumers of the crops. Furthermore, the input of nutrients with the irrigation water may greatly exceed crop requirements and thus lead to unproductive leaching losses of nutrients. It is generally acknowledged that biochar additions can increase the soil's sorption and retention capacity for nutrients and water. However, positive effects on crop production are generally only observed, if this is combined with mineral fertilizers or manures due to the low nutrient content of biochars. Biochar possibly also has a high potential for use in water purification, replacing the coal-based activated carbon as a sorbent for contaminants and pathogens. It was therefore hypothesized that biochar can be used for pathogen removal from wastewater while at the same time being loaded with nutrients and contaminants. If contaminants are of minor concern the "loaded" biochar can be used as a soil amendment, providing not only long-term sorption capacity but also nutrients. Experiments were conducted with pyrochar from Miscanthus, rice husks and wood chips, which strongly differed in elemental composition, MIR-DRIFT spectra, surface charge properties and sorption potential for DOC and phosphate. When used as top filter layer in a sand column system, the biochars effectively reduced E. coli concentrations from raw wastewater by up to 2 log units. While biochars from rice husks and Miscanthus accumulated N substantially, wood chip biochar showed no N retention. On the other hand, P accumulation was most pronounced for wood chip biochar. Ongoing incubation experiments with the "loaded" and fresh biochar in soils indicate that the pretreatment with wastewater alters biochar's stability and their effects on N-mineralization.

Evaluation of nutrient retention in vegetated filter strips using the SWAT model.

PubMed

Elçi, Alper

2017-11-01

Nutrient fluxes in stream basins need to be controlled to achieve good water quality status. In stream basins with intensive agricultural activities, nutrients predominantly come from diffuse sources. Therefore, best management practices (BMPs) are increasingly implemented to reduce nutrient input to streams. The objective of this study is to evaluate the impact of vegetated filter strip (VFS) application as an agricultural BMP. For this purpose, SWAT is chosen, a semi-distributed water quality assessment model that works at the watershed scale, and applied on the Nif stream basin, a small-sized basin in Western Turkey. The model is calibrated with an automated procedure against measured monthly discharge data. Nutrient loads for each sub-basin are estimated considering basin-wide data on chemical fertilizer and manure usage, population data for septic tank effluents and information about the land cover. Nutrient loads for 19 sub-basins are predicted on an annual basis. Average total nitrogen and total phosphorus loads are estimated as 47.85 t/yr and 13.36 t/yr for the entire basin. Results show that VFS application in one sub-basin offers limited retention of nutrients and that a selection of 20-m filter width is most effective from a cost-benefit perspective.

Evaluating Aquatic Life Benefits of Reducing Nutrient Loading ...

EPA Pesticide Factsheets

Theoretical linkages between excess nutrient loading, nutrient-enhanced community metabolism (i.e., production and respiration), and hypoxia in estuaries are well-understood. In seasonally-stratified estuaries and coastal systems (e.g., Chesapeake Bay, northern Gulf of Mexico), hypoxia is predominantly seasonal, such that the spatial extent indicates potential aquatic life impacts. However, in relatively small and shallow Gulf of Mexico bays and bayous, hypoxia frequently occurs episodically or on a diel basis. This study utilized continuous DO monitoring and 3-D hydrodynamic (Environmental Fluid Dynamics Code) and water quality (Water Quality Analysis Simulation Program) models to examine physical and biological controls on DO dynamics and ecosystem metabolism in Weeks Bay, AL. Observed vertical DO gradients varied on a diel basis, with larger amplitude variations at depth relative to the surface, underscoring the importance of benthic production and respiration as a driver of ecosystem metabolism in shallow estuaries. Hydrodynamic and water quality models simulated seasonal and event-driven dynamics, but struggled to resolve the amplitude of daily DO fluctuations, particularly in bottom waters. Using these data in conjunction with the 10-year continuous O2 record from Weeks Bay, we applied empirical relationships and simple scaling relations to predict how reducing nutrient loading may affect the frequency, severity and duration of hypoxia. We further applied

Estimation of particulate nutrient load using turbidity meter.

PubMed

Yamamoto, K; Suetsugi, T

2006-01-01

The "Nutrient Load Hysteresis Coefficient" was proposed to evaluate the hysteresis of the nutrient loads to flow rate quantitatively. This could classify the runoff patterns of nutrient load into 15 patterns. Linear relationships between the turbidity and the concentrations of particulate nutrients were observed. It was clarified that the linearity was caused by the influence of the particle size on turbidity output and accumulation of nutrients on smaller particles (diameter < 23 microm). The L-Q-Turb method, which is a new method for the estimation of runoff loads of nutrients using a regression curve between the turbidity and the concentrations of particulate nutrients, was developed. This method could raise the precision of the estimation of nutrient loads even if they had strong hysteresis to flow rate. For example, as for the runoff load of total phosphorus load on flood events in a total of eight cases, the averaged error of estimation of total phosphorus load by the L-Q-Turb method was 11%, whereas the averaged estimation error by the regression curve between flow rate and nutrient load was 28%.

Climate Variability Impacts on Watershed Nutrient Delivery and Reservoir Production

NASA Astrophysics Data System (ADS)

White, J. D.; Prochnow, S. J.; Zygo, L. M.; Byars, B. W.

2005-05-01

Reservoirs in agricultural dominated watersheds tend to exhibit pulse-system behavior especially if located in climates dominated by summer convective precipitation inputs. Concentration and bulk mass of nutrient and sediment inputs into reservoir systems vary in terms of timing and magnitude of delivery from watershed sources to reservoirs under these climate conditions. Reservoir management often focuses on long-term average inputs without considering short and long-term impacts of variation in loading. In this study we modeled a watershed-reservoir system to assess how climate variability affects reservoir primary production through shifts in external loading and internal recycling of limiting nutrients. The Bosque watershed encompasses 423,824 ha in central Texas which delivers water to Lake Waco, a 2900 ha reservoir that is the primary water source for the city of Waco and surrounding areas. Utilizing the Soil Water Assessment Tool for the watershed and river simulations and the CE-Qual-2e model for the reservoir, hydrologic and nutrient dynamics were simulated for a 10 year period encompassing two ENSO cycles. The models were calibrated based on point measurement of water quality attributes for a two year time period. Results indicated that watershed delivery of nutrients was affected by the presence and density of small flood-control structure in the watershed. However, considerable nitrogen and phosphorus loadings were derived from soils in the upper watershed which have had long-term waste-application from concentrated animal feeding operations. During El Niño years, nutrient and sediment loads increased by 3 times above non-El Niño years. The simulated response within the reservoir to these nutrient and sediment loads had both direct and indirect. Productivity evaluated from chlorophyll a and algal biomass increased under El Niño conditions, however species composition shifts were found with an increase in cyanobacteria dominance. In non-El Niño years, species composition was more evenly distributed. At the longer time scale, El Niño events with accompanying increase in nutrient loads were followed by years in which productivity declined below levels predicted solely by nutrient ratios. This was due to subtle shifts in organic matter decomposition where productive years are followed by increases in refractory material which sequesters nutrients and reduces internal loading.

Characterization of nutrient, organic carbon, and sediment loads and concentrations from the Mississippi River into the northern Gulf of Mexico

USGS Publications Warehouse

Turner, R.E.; Rabalais, N.N.; Alexander, Richard B.; McIsaac, G.; Howarth, R.W.

2007-01-01

We synthesize and update the science supporting the Action Plan for Reducing, Mitigating, and Controlling Hypoxia in the Northern Gulf of Mexico (Mississippi River/Gulf of Mexico Watershed Nutrient Task Force 2001) with a focus on the spatial and temporal discharge and patterns of nutrient and organic carbon delivery to the northern Gulf of Mexico, including data through 2006. The discharge of the Mississippi River watershed over 200 years varies but is not demonstrably increasing or decreasing. About 30% of the Mississippi River was shunted westward to form the Atchafalaya River, which redistributed water and nutrient loads on the shelf. Data on nitrogen concentrations from the early 1900s demonstrate that the seasonal and annual concentrations in the lower river have increased considerably since then, including a higher spring loading, following the increase in fertilizer applications after World WarII. The loading of total nitrogen (TN) fell from 1990 to 2006, but the loading of total phosphorus (TP) has risen slightly, resulting in a decline in the TN:TP ratios. The present TN:TP ratios hover around an average indicative of potential nitrogen limitation on phytoplankton growth, or balanced growth limitation, but not phosphorus limitation. The dissolved nitrogen:dissolved silicate ratios are near the Redfield ratio indicative of growth limitations on diatoms. Although nutrient concentrations are relatively high compared to those in many other large rivers, the water quality in the Mississippi River is not unique in that nutrient loads can be described by a variety of land-use models. There is no net removal of nitrogen from water flowing through the Atchafalaya basin, but the concentrations of TP and suspended sediments are lower at the exit point (Morgan City, Louisiana) than in the water entering the Atchafalaya basin. The removal of nutrients entering offshore waters through diversion of river water into wetlands is presently less than 1% of the total loadings going directly offshore, and would be less than 8% if the 10,093 km2 of coastal wetlands were successfully engineered for that purpose. Wetland loss is an insignificant contribution to the carbon loading offshore, compared to in situ marine production. The science-based conclusions in the Action Plan about nutrient loads and sources to the hypoxic zone off Louisiana are sustained by research and monitoring occurring in the subsequent 10 years.

Effectiveness of submerged drains in reducing subsidence of peat soils in agricultural use, and their effects on water management and nutrient loading of surface water: modelling of a case study in the western peat soil area of The Netherlands

NASA Astrophysics Data System (ADS)

Hendriks, Rob F. A.; van den Akker, Jan J. A.

2017-04-01

Effectiveness of submerged drains in reducing subsidence of peat soils in agricultural use, and their effects on water management and nutrient loading of surface water: modelling of a case study in the western peat soil area of The Netherlands In the Netherlands, about 8% of the area is covered by peat soils. Most of these soils are in use for dairy farming and, consequently, are drained. Drainage causes decomposition of peat by oxidation and accordingly leads to surface subsidence and greenhouse gas emission. Submerged drains that enhance submerged infiltration of water from ditches during the dry and warm summer half year were, and are still, studied in The Netherlands as a promising tool for reducing peat decomposition by raising groundwater levels. For this purpose, several pilot field studies in the Western part of the Dutch peat area were conducted. Besides the effectiveness of submerged drains in reducing peat decomposition and subsidence by raising groundwater tables, some other relevant or expected effects of these drains were studied. Most important of these are water management and loading of surface water with nutrients nitrogen, phosphorus and sulphate. Because most of these parameters are not easy to assess and all of them are strongly depending on the meteorological conditions during the field studies some of these studies were modelled. The SWAP model was used for evaluating the hydrological results on groundwater table and water discharge and recharge. Effects of submerged drains were assessed by comparing the results of fields with and without drains. An empirical relation between deepest groundwater table and subsidence was used to convert effects on groundwater table to effects on subsidence. With the SWAP-ANIMO model nutrient loading of surface water was modelled on the basis of field results on nutrient concentrations . Calibrated models were used to assess effects in the present situation, as thirty-year averages, under extreme weather conditions and for two extreme climate scenarios of the Royal Netherlands Meteorological Institute. In this study the model results of one of the pilot studies are presented. The case study 'de Krimpenerwaard' is situated in the peat area in the "Green Heart" between the major cities of Amsterdam, The Hague, Rotterdam and Utrecht. Model results show a halving of soil subsidence, a strong increase of water recharge but a lower increase of water discharge, and generally small to moderate effects on nutrient loading , all depending (strongly) on meteorological conditions.

Response of Submerged Macrophyte Communities to External and Internal Restoration Measures in North Temperate Shallow Lakes.

PubMed

Hilt, Sabine; Alirangues Nuñez, Marta M; Bakker, Elisabeth S; Blindow, Irmgard; Davidson, Thomas A; Gillefalk, Mikael; Hansson, Lars-Anders; Janse, Jan H; Janssen, Annette B G; Jeppesen, Erik; Kabus, Timm; Kelly, Andrea; Köhler, Jan; Lauridsen, Torben L; Mooij, Wolf M; Noordhuis, Ruurd; Phillips, Geoff; Rücker, Jacqueline; Schuster, Hans-Heinrich; Søndergaard, Martin; Teurlincx, Sven; van de Weyer, Klaus; van Donk, Ellen; Waterstraat, Arno; Willby, Nigel; Sayer, Carl D

2018-01-01

Submerged macrophytes play a key role in north temperate shallow lakes by stabilizing clear-water conditions. Eutrophication has resulted in macrophyte loss and shifts to turbid conditions in many lakes. Considerable efforts have been devoted to shallow lake restoration in many countries, but long-term success depends on a stable recovery of submerged macrophytes. However, recovery patterns vary widely and remain to be fully understood. We hypothesize that reduced external nutrient loading leads to an intermediate recovery state with clear spring and turbid summer conditions similar to the pattern described for eutrophication. In contrast, lake internal restoration measures can result in transient clear-water conditions both in spring and summer and reversals to turbid conditions. Furthermore, we hypothesize that these contrasting restoration measures result in different macrophyte species composition, with added implications for seasonal dynamics due to differences in plant traits. To test these hypotheses, we analyzed data on water quality and submerged macrophytes from 49 north temperate shallow lakes that were in a turbid state and subjected to restoration measures. To study the dynamics of macrophytes during nutrient load reduction, we adapted the ecosystem model PCLake. Our survey and model simulations revealed the existence of an intermediate recovery state upon reduced external nutrient loading, characterized by spring clear-water phases and turbid summers, whereas internal lake restoration measures often resulted in clear-water conditions in spring and summer with returns to turbid conditions after some years. External and internal lake restoration measures resulted in different macrophyte communities. The intermediate recovery state following reduced nutrient loading is characterized by a few macrophyte species (mainly pondweeds) that can resist wave action allowing survival in shallow areas, germinate early in spring, have energy-rich vegetative propagules facilitating rapid initial growth and that can complete their life cycle by early summer. Later in the growing season these plants are, according to our simulations, outcompeted by periphyton, leading to late-summer phytoplankton blooms. Internal lake restoration measures often coincide with a rapid but transient colonization by hornworts, waterweeds or charophytes. Stable clear-water conditions and a diverse macrophyte flora only occurred decades after external nutrient load reduction or when measures were combined.

Determining storm sampling requirements for improving precision of annual load estimates of nutrients from a small forested watershed.

PubMed

Ide, Jun'ichiro; Chiwa, Masaaki; Higashi, Naoko; Maruno, Ryoko; Mori, Yasushi; Otsuki, Kyoichi

2012-08-01

This study sought to determine the lowest number of storm events required for adequate estimation of annual nutrient loads from a forested watershed using the regression equation between cumulative load (∑L) and cumulative stream discharge (∑Q). Hydrological surveys were conducted for 4 years, and stream water was sampled sequentially at 15-60-min intervals during 24 h in 20 events, as well as weekly in a small forested watershed. The bootstrap sampling technique was used to determine the regression (∑L-∑Q) equations of dissolved nitrogen (DN) and phosphorus (DP), particulate nitrogen (PN) and phosphorus (PP), dissolved inorganic nitrogen (DIN), and suspended solid (SS) for each dataset of ∑L and ∑Q. For dissolved nutrients (DN, DP, DIN), the coefficient of variance (CV) in 100 replicates of 4-year average annual load estimates was below 20% with datasets composed of five storm events. For particulate nutrients (PN, PP, SS), the CV exceeded 20%, even with datasets composed of more than ten storm events. The differences in the number of storm events required for precise load estimates between dissolved and particulate nutrients were attributed to the goodness of fit of the ∑L-∑Q equations. Bootstrap simulation based on flow-stratified sampling resulted in fewer storm events than the simulation based on random sampling and showed that only three storm events were required to give a CV below 20% for dissolved nutrients. These results indicate that a sampling design considering discharge levels reduces the frequency of laborious chemical analyses of water samples required throughout the year.

Testing of The Harp Guidelines On A Small Watershed In Finland

NASA Astrophysics Data System (ADS)

Granlund, K.; Rekolainen, S.

TESTING of THE HARP GUIDELINES ON A SMALL WATERSHED IN FIN- LAND K. Granlund, S. Rekolainen Finnish Environment Institute, Research Department kirsti.granlund@vyh.fi Watersheds have emerged as environmental units for assessing, controlling and reduc- ing non-point-source pollution. Within the framework of the international conventions, such as OSPARCOM, HELCOM, and in the implementation of the EU Water Frame- work Directive, the criteria for model selection is of key importance. Harmonized Quantification and Reporting Procedures for Nutrients (HARP) aims at helping the implementation of OSPAR's (Convention for the Protection of the Marine Environ- ment of the North-East Atlantic) strategy in controlling eutrophication and reducing nutrient input to marine ecosystems by 50nitrogen and phosphorus losses from both point and nonpoint sources and help assess the effectiveness of the pollution reduction strategy. The HARP guidelines related respectively to the "Quantification of Nitrogen and Phosphorus Losses from Diffuse Anthropogenic Sources and Natural Background Losses" and to the "Quantification and Reporting of the Retention of Nitrogen and Phosphorus in River Catchments" were tested on a small, well instrumented agricul- tural watershed in Finland. The project was coordinated by the Environment Institute of the Joint Research Centre. Three types of methodologies for estimating nutrient losses to watercourses were eval- uated during the project. Simple methods based on regression equations or loading functions provide a quick method for estimating nutrient losses. Through these meth- ods the pollutant load can be related to parameters such as slope, soil type, land-use, management practices etc. Relevant nutrient loading functions for the study catch- ment were collected during the project. One mid-range model was applied to simulate the nitrogen cycle in a simplified manner in relation to climate, soil properties, land- use and management practices. Physically based models describe in detail the water and nutrient cycle within the watershed. ICECREAM and SWAT models were applied on the study watershed. ICECREAM is a management model based on CREAMS model for predicting field-scale runoff and erosion. The nitrogen and phosphorus sub- models are based on GLEAMS model. SWAT is a continuous time and spatially dis- tributed model, which includes hydrological, sediment and chemical processes in river 1 basins.The simple methods and the mid-range model for nitrogen proved to be fast and easy to apply, but due limited information on crop-specific loading functions and ni- trogen process rates (e.g. mineralisation in soil), only order-of-magnitude estimates for nutrient loads could be calculated. The ICECREAM model was used to estimate crop-specific nutrient losses from the agricultural area. The potential annual nutrient loads for the whole catchment were then calculated by including estimates for nutri- ent loads from other land-use classes (forested area and scattered settlement). Finally, calibration of the SWAT model was started to study in detail the effects of catchment characteristics on nutrient losses. The preliminary results of model testing are pre- sented and the suitability of different methodologies for estimating nutrient losses in Finnish catchments is discussed. 2

Revised method and outcomes for estimating soil phosphorus losses from agricultural land in the Chesapeake Bay watershed model

USDA-ARS?s Scientific Manuscript database

Current restoration efforts for the Chesapeake Bay watershed mandate a timeline for reducing the load of nutrients and sediment to receiving waters. The Chesapeake Bay Watershed Model (WSM) has been used for two decades to simulate hydrology and nutrient and sediment transport; however, spatial limi...

Estimating the effects of agricultural conservation practices on phosphorus loads in the Mississippi-Atchafalaya River basin

USDA-ARS?s Scientific Manuscript database

Agriculture in the Mississippi-Atchafalaya River basin (MARB) is important in terms of both the national economy and the nutrients discharged to the basin and the Gulf of Mexico. Conservation practices are installed on cropland to reduce the nutrient losses. A recent study by the Conservation Effec...

Narrow grass hedge effects on nutrient transport following swine slurry application

USDA-ARS?s Scientific Manuscript database

The effectiveness of a narrow grass hedge in reducing runoff nutrient loads following swine slurry application was examined in this study. Slurry was applied to 0.75-m wide by 4.0-m long plots established on an Aksarben silty clay loam soil located in southeast Nebraska. Manure treatments consisted ...

Incorporating Green Infrastructure into Water Resources Management Plans to Address Water Quality Impairments

NASA Astrophysics Data System (ADS)

Piscopo, A. N.; Detenbeck, N. E.

2017-12-01

Managers of urban watersheds with excessive nutrient loads are more frequently turning to green infrastructure (GI) to manage their water quality impairments. The effectiveness of GI is dependent on a number of factors, including (1) the type and placement of GI within the watershed, (2) the specific nutrients to be treated, and (3) the uncertainty in future climates. Although many studies have investigated the effectiveness of individual GI units for different types of nutrients, relatively few have considered the effectiveness of GI on a watershed scale, the scale most relevant to management plans. At the watershed scale, endless combinations of GI type and location are possible, each with different effectiveness in reducing nutrient loads, minimizing costs, and maximizing co-benefits such as reducing runoff. To efficiently generate management plan options that balance the tradeoffs between these objectives, we simulate candidate options using EPA's Stormwater Management Model for multiple future climates and determine the Pareto optimal set of solution options using a multi-objective evolutionary algorithm. Our approach is demonstrated for an urban watershed in Rockville, Maryland.

Water Quality Protection from Nutrient Pollution: Case ...

EPA Pesticide Factsheets

Water bodies and coastal areas around the world are threatened by increases in upstream sediment and nutrient loads, which influence drinking water sources, aquatic species, and other ecologic functions and services of streams, lakes, and coastal water bodies. For example, increased nutrient fluxes from the Mississippi River Basin have been linked to increased occurrences of seasonal hypoxia in northern Gulf of Mexico. Lake Erie is another example where in the summer of 2014 nutrients, nutrients, particularly phosphorus, washed from fertilized farms, cattle feedlots, and leaky septic systems; caused a severe algae bloom, much of it poisonous; and resulted in the loss of drinking water for a half-million residents. Our current management strategies for point and non-point source nutrient loadings need to be improved to protect and meet the expected increased future demands of water for consumption, recreation, and ecological integrity. This presentation introduces management practices being implemented and their effectiveness in reducing nutrient loss from agricultural fields, a case analysis of nutrient pollution of the Grand Lake St. Marys and possible remedies, and ongoing work on watershed modeling to improve our understanding on nutrient loss and water quality. Presented at the 3rd International Conference on Water Resource and Environment.

A screening-level modeling approach to estimate nitrogen ...

EPA Pesticide Factsheets

This paper presents a screening-level modeling approach that can be used to rapidly estimate nutrient loading and assess numerical nutrient standard exceedance risk of surface waters leading to potential classification as impaired for designated use. It can also be used to explore best management practice (BMP) implementation to reduce loading. The modeling framework uses a hybrid statistical and process based approach to estimate source of pollutants, their transport and decay in the terrestrial and aquatic parts of watersheds. The framework is developed in the ArcGIS environment and is based on the total maximum daily load (TMDL) balance model. Nitrogen (N) is currently addressed in the framework, referred to as WQM-TMDL-N. Loading for each catchment includes non-point sources (NPS) and point sources (PS). NPS loading is estimated using export coefficient or event mean concentration methods depending on the temporal scales, i.e., annual or daily. Loading from atmospheric deposition is also included. The probability of a nutrient load to exceed a target load is evaluated using probabilistic risk assessment, by including the uncertainty associated with export coefficients of various land uses. The computed risk data can be visualized as spatial maps which show the load exceedance probability for all stream segments. In an application of this modeling approach to the Tippecanoe River watershed in Indiana, USA, total nitrogen (TN) loading and risk of standard exce

Hydrological regulation drives regime shifts: evidence from paleolimnology and ecosystem modeling of a large shallow Chinese lake.

PubMed

Kong, Xiangzhen; He, Qishuang; Yang, Bin; He, Wei; Xu, Fuliu; Janssen, Annette B G; Kuiper, Jan J; van Gerven, Luuk P A; Qin, Ning; Jiang, Yujiao; Liu, Wenxiu; Yang, Chen; Bai, Zelin; Zhang, Min; Kong, Fanxiang; Janse, Jan H; Mooij, Wolf M

2017-02-01

Quantitative evidence of sudden shifts in ecological structure and function in large shallow lakes is rare, even though they provide essential benefits to society. Such 'regime shifts' can be driven by human activities which degrade ecological stability including water level control (WLC) and nutrient loading. Interactions between WLC and nutrient loading on the long-term dynamics of shallow lake ecosystems are, however, often overlooked and largely underestimated, which has hampered the effectiveness of lake management. Here, we focus on a large shallow lake (Lake Chaohu) located in one of the most densely populated areas in China, the lower Yangtze River floodplain, which has undergone both WLC and increasing nutrient loading over the last several decades. We applied a novel methodology that combines consistent evidence from both paleolimnological records and ecosystem modeling to overcome the hurdle of data insufficiency and to unravel the drivers and underlying mechanisms in ecosystem dynamics. We identified the occurrence of two regime shifts: one in 1963, characterized by the abrupt disappearance of submerged vegetation, and another around 1980, with strong algal blooms being observed thereafter. Using model scenarios, we further disentangled the roles of WLC and nutrient loading, showing that the 1963 shift was predominantly triggered by WLC, whereas the shift ca. 1980 was attributed to aggravated nutrient loading. Our analysis also shows interactions between these two stressors. Compared to the dynamics driven by nutrient loading alone, WLC reduced the critical P loading and resulted in earlier disappearance of submerged vegetation and emergence of algal blooms by approximately 26 and 10 years, respectively. Overall, our study reveals the significant role of hydrological regulation in driving shallow lake ecosystem dynamics, and it highlights the urgency of using multi-objective management criteria that includes ecological sustainability perspectives when implementing hydrological regulation for aquatic ecosystems around the globe. © 2016 John Wiley & Sons Ltd.

Factors affecting nutrient trends in major rivers of the Chesapeake Bay Watershed

USGS Publications Warehouse

Sprague, Lori A.; Langland, M.J.; Yochum, S.E.; Edwards, R.E.; Blomquist, J.D.; Phillips, S.W.; Shenk, G.W.; Preston, S.D.

2000-01-01

Trends in nutrient loads and flow-adjusted concentrations in the major rivers entering Chesapeake Bay were computed on the basis of water-quality data collected between 1985 and 1998 at 29 monitoring stations in the Susquehanna, Potomac, James, Rappahannock, York, Patuxent, and Choptank River Basins. Two computer models?the Chesapeake Bay Watershed Model (WSM) and the U.S. Geological Survey?s 'Spatially Referenced Regressions on Watershed attributes' (SPARROW) Model?were used to help explain the major factors affecting the trends. Results from WSM simulations provided information on temporal changes in contributions from major nutrient sources, and results from SPARROW model simulations provided spatial detail on the distribution of nutrient yields in these basins. Additional data on nutrient sources, basin characteristics, implementation of management practices, and ground-water inputs to surface water were analyzed to help explain the trends. The major factors affecting the trends were changes in nutrient sources and natural variations in streamflow. The dominant source of nitrogen and phosphorus from 1985 to 1998 in six of the seven tributary basins to Chesapeake Bay was determined to be agriculture. Because of the predominance of agricultural inputs, changes in agricultural nutrient sources such as manure and fertilizer, combined with decreases in agricultural acreage and implementation of best management practices (BMPs), had the greatest impact on the trends in flow-adjusted nutrient concentrations. Urban acreage and population, however, were noted to be increasing throughout the Chesapeake Bay Watershed, and as a result, delivered loads of nutrients from urban areas increased during the study period. Overall, agricultural nutrient management, in combination with load decreases from point sources due to facility upgrades and the phosphate detergent ban, led to downward trends in flow-adjusted nutrient concentrations atmany of the monitoring stations in the watershed. The loads of nutrients, however, were not reduced significantly at most of the monitoring stations. This is due primarily to higher streamflow in the latter years of the monitoring period, which led to higher loading in those years.Results of this study indicate a need for more detailed information on BMP effectiveness under a full range of hydrologic conditions and in different areas of the watershed; an internally consistent fertilizer data set; greater consideration of the effects of watershed processes on nutrient transport; a refinement of current modeling efforts; and an expansion of the non-tidal monitoring network in the Chesapeake Bay Watershed.

Spatial optimization of watershed management practices for nitrogen load reduction using a modeling-optimization framework

EPA Science Inventory

Best management practices (BMPs) are perceived as being effective in reducing nutrient loads transported from non-point sources (NPS) to receiving water bodies. The objective of this study was to develop a modeling-optimization framework that can be used by watershed management p...

Land application of spent gypsum from ditch filters: phosphorus source or sink?

USDA-ARS?s Scientific Manuscript database

Agricultural drainage ditches can provide a direct connection between fields and surface waters, and some have been shown to deliver high loads of phosphorus (P) to sensitive water bodies. A potential way to reduce nutrient loads in drainage ditches is to install filter structures containing P sorbi...

Protecting the Green Behind the Gold: Catchment-Wide Restoration Efforts Necessary to Achieve Nutrient and Sediment Load Reduction Targets in Gold Coast City, Australia

NASA Astrophysics Data System (ADS)

Waltham, Nathan J.; Barry, Michael; McAlister, Tony; Weber, Tony; Groth, Dominic

2014-10-01

The Gold Coast City is the tourist center of Australia and has undergone rapid and massive urban expansion over the past few decades. The Broadwater estuary, in the heart of the City, not only offers an array of ecosystems services for many important aquatic wildlife species, but also supports the livelihood and lifestyles of residents. Not surprisingly, there have been signs of imbalance between these two major services. This study combined a waterway hydraulic and pollutant transport model to simulate diffuse nutrient and sediment loads under past and future proposed land-use changes. A series of catchment restoration initiatives were modeled in an attempt to define optimal catchment scale restoration efforts necessary to protect and enhance the City's waterways. The modeling revealed that for future proposed development, a business as usual approach to catchment management will not reduce nutrient and sediment loading sufficiently to protect the community values. Considerable restoration of upper catchment tributaries is imperative, combined with treatment of stormwater flow from intensively developed sub-catchment areas. Collectively, initiatives undertaken by regulatory authorities to date have successfully reduced nutrient and sediment loading reaching adjoining waterways, although these programs have been ad hoc without strategic systematic planning and vision. Future conservation requires integration of multidisciplinary science and proactive management driven by the high ecological, economical, and community values placed on the City's waterways. Long-term catchment restoration and conservation planning requires an extensive budget (including political and societal support) to handle ongoing maintenance issues associated with scale of restoration determined here.

Multiyear nutrient removal performance of three constructed wetlands intercepting tile drain flows from grazed pastures.

PubMed

Tanner, Chris C; Sukias, James P S

2011-01-01

Subsurface tile drain flows can be a major s ource of nurient loss from agricultural landscapes. This study quantifies flows and nitrogen and phosphorus yields from tile drains at three intensively grazed dairy pasture sites over 3- to 5-yr periods and evaluates the capacity of constructed wetlands occupying 0.66 to 1.6% of the drained catchments too reduce nutrient loads. Continuous flow records are combined with automated flow-proportional sampling of nutrient concentrations to calculate tile drain nutrient yields and wetland mass removal rates. Annual drainage water yields rangedfrom 193 to 564 mm (16-51% of rainfall) at two rain-fed sites and from 827 to 853 mm (43-51% of rainfall + irrigation) at an irrigated site. Annually, the tile drains exported 14 to 109 kg ha(-1) of total N (TN), of which 58 to 90% was nitrate-N. Constructed wetlands intercepting these flows removed 30 to 369 gTN m(-2) (7-63%) of influent loadings annually. Seasonal percentage nitrate-N and TN removal were negatively associated with wetland N mass loadings. Wetland P removal was poor in all wetlands, with 12 to 115% more total P exported annually overall than received. Annually, the tile drains exported 0.12 to 1.38 kg ha of total P, of which 15 to 93% was dissolved reactive P. Additional measures are required to reduce these losses or provide supplementary P removal. Wetland N removal performance could be improved by modifying drainage systems to release flows more gradually and improving irrigation practices to reduce drainage losses.

The Effect of Restored and Native Oxbows on Hydraulic Loads of Nutrients and Stream Water Quality

EPA Science Inventory

The use of oxbow wetlands has been identified as a potential strategy to reduce nutrient transport from agricultural drainage tiles to streams in Iowa. In 2013 and 2014, a study was conducted in north central Iowa in a native oxbow in the Lyons Creek watershed and two reconstruc...

Characterization of biomass residues and their amendment effects on water sorption and nutrient leaching in sandy soil.

PubMed

Wang, Letian; Tong, Zhaohui; Liu, Guodong; Li, Yuncong

2014-07-01

In this study, we evaluated the efficiency of two types of biomass residues (fermentation residues from a bioethanol process, FB; brown mill residues from a papermaking process, BM) as amendments for a sandy soil. The characteristics of these residues including specific surface areas, morphologies and nutrient sorption capacity were measured. The effects of biorefinery residues on water and nutrient retention were investigated in terms of different particle sizes and loadings. The results indicated that bio-based wastes FB and BM were able to significantly improve water and nutrient retention of sandy soil. The residues with larger surface areas had better water and nutrient retention capability. Specifically, in the addition of 10% loading, FB and BM was able to improve water retention by approximately 150% and 300%, while reduce 99% of ammonium and phosphate concentration in the leachate compare to the soil control, respectively. Copyright © 2014 Elsevier Ltd. All rights reserved.

Optimal implementation of green infrastructure practices to reduce adverse impacts of urban areas on hydrology and water quality

NASA Astrophysics Data System (ADS)

Liu, Y.; Collingsworth, P.; Pijanowski, B. C.; Engel, B.

2016-12-01

Nutrient loading from Maumee River watershed is a significant reason for the harmful algal blooms (HABs) problem in Lake Erie. Although studies have explored strategies to reduce nutrient loading from agricultural areas in the Maumee River watershed, the nutrient loading in urban areas also needs to be reduced. Green infrastructure practices are popular approaches for stormwater management and useful for improving hydrology and water quality. In this study, the Long-Term Hydrologic Impact Assessment-Low Impact Development 2.1 (L-THIA-LID 2.1) model was used to determine how different strategies for implementing green infrastructure practices can be optimized to reduce impacts on hydrology and water quality in an urban watershed in the upper Maumee River system. Community inputs, such as the types of green infrastructure practices of greatest interest and environmental concerns for the community, were also considered during the study. Based on community input, the following environmental concerns were considered: runoff volume, Total Suspended Solids (TSS), Total Phosphorous (TP), Total Kjeldahl Nitrogen (TKN), and Nitrate+Nitrite (NOx); green infrastructure practices of interest included rain barrel, cistern, green roof, permeable patio, porous pavement, grassed swale, bioretention system, grass strip, wetland channel, detention basin, retention pond, and wetland basin. Spatial optimization of green infrastructure practice implementation was conducted to maximize environmental benefits while minimizing the cost of implementation. The green infrastructure practice optimization results can be used by the community to solve hydrology and water quality problems.

Lake Nutrient Responses to Integrated Conservation Practices in an Agricultural Watershed.

PubMed

Lizotte, Richard E; Yasarer, Lindsey M W; Locke, Martin A; Bingner, Ronald L; Knight, Scott S

2017-03-01

Watershed-scale management efforts to reduce nutrient loads and improve the conservation of lakes in agricultural watersheds require effective integration of a variety of agricultural conservation best management practices (BMPs). This paper documents watershed-scale assessments of the influence of multiple integrated BMPs on oxbow lake nutrient concentrations in a 625-ha watershed of intensive row-crop agricultural activity during a 14-yr monitoring period (1996-2009). A suite of BMPs within fields and at field edges throughout the watershed and enrollment of 87 ha into the Conservation Reserve Program (CRP) were implemented from 1995 to 2006. Total phosphorus (TP), soluble reactive phosphorus (SRP), ammonium, and nitrate were measured approximately biweekly from 1996 to 2009, and total nitrogen (TN) was measured from 2001 to 2009. Decreases in several lake nutrient concentrations occurred after BMP implementation. Reductions in TP lake concentrations were associated with vegetative buffers and rainfall. No consistent patterns of changes in TN or SRP lake concentrations were observed. Reductions in ammonium lake concentrations were associated with conservation tillage and CRP. Reductions in nitrate lake concentrations were associated with vegetative buffers. Watershed simulations conducted with the AnnAGNPS (Annualized Agricultural Non-Point Source) model with and without BMPs also show a clear reduction in TN and TP loads to the lake after the implementation of BMPs. These results provide direct evidence of how watershed-wide BMPs assist in reducing nutrient loading in aquatic ecosystems and promote a more viable and sustainable lake ecosystem. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Mitigating cyanobacterial harmful algal blooms in aquatic ecosystems impacted by climate change and anthropogenic nutrients.

PubMed

Paerl, Hans W; Gardner, Wayne S; Havens, Karl E; Joyner, Alan R; McCarthy, Mark J; Newell, Silvia E; Qin, Boqiang; Scott, J Thad

2016-04-01

Mitigating the global expansion of cyanobacterial harmful blooms (CyanoHABs) is a major challenge facing researchers and resource managers. A variety of traditional (e.g., nutrient load reduction) and experimental (e.g., artificial mixing and flushing, omnivorous fish removal) approaches have been used to reduce bloom occurrences. Managers now face the additional effects of climate change on watershed hydrologic and nutrient loading dynamics, lake and estuary temperature, mixing regime, internal nutrient dynamics, and other factors. Those changes favor CyanoHABs over other phytoplankton and could influence the efficacy of control measures. Virtually all mitigation strategies are influenced by climate changes, which may require setting new nutrient input reduction targets and establishing nutrient-bloom thresholds for impacted waters. Physical-forcing mitigation techniques, such as flushing and artificial mixing, will need adjustments to deal with the ramifications of climate change. Here, we examine the suite of current mitigation strategies and the potential options for adapting and optimizing them in a world facing increasing human population pressure and climate change. Copyright © 2015 Elsevier B.V. All rights reserved.

Sources and loads of nutrients in the South Platte River, Colorado and Nebraska, 1994-95

USGS Publications Warehouse

Litke, D.W.

1996-01-01

The South Platte River Basin was one of 20 river basins selected in 1991 for investigation as part of the U.S. Geological Survey's National Water- Quality Assessment (NAWQA) Program. Nationwide, nutrients have been identified as one of the primary nationwide water-quality concerns and are of particular interest in the South Platte River Basin where nutrient concentrations are large compared to concentrations in other NAWQA river basins. This report presents estimates of the magnitude of nutrient-source inputs to the South Platte River Basin, describes nutrient concen- trations and loads in the South Platte River during different seasons, and presents comparisons of nutrient inputs to instream nutrient loads. Annual nutrient inputs to the basin were estimated to be 306,000 tons of nitrogen and 41,000 tons of phosphorus. The principal nutrient sources were wastewater-treatment plants, fertilizer and manure applications, and atmospheric deposition. To characterize nutrient concentrations and loads in the South Platte River during different seasons, five nutrient synoptic samplings were conducted during 1994 and 1995. Upstream from Denver, Colorado, during April 1994 and January 1995, total nitrogen concentrations were less than 2 milligrams per liter (mg/L), and total phosphorus concentrations were less than 0.2 mg/L. The water in the river at this point was derived mostly from forested land in the mountains west of Denver. Total nutrient concentrations increased through the Denver metropolitan area, and concentration peaks occurred just downstream from each of Denver's largest wastewater-treatment plants with maximum concentrations of 13.6 mg/L total nitrogen and 2.4 mg/L total phosphorus. Nutrient concen- concentrations generally decreased downstream from Denver. Upstream from Denver during April 1994 and January 1995, total nitrogen loads were less than 1,000 pounds per day (lb/d), and total phosphorus loads were less than 125 lb/d. Total nutrient loads increased through the Denver metropolitan area, and load peaks occurred just downstream from each of Denver's largest wastewater-treatment plants, with a maximum load of 14,000 lb/d total nitrogen and 2,300 lb/d total phosphorus. In April 1994, nutrient loads generally decreased from Henderson, Colorado, to North Platte, Nebraska. In January 1995, however, nutrient loads increased from Henderson to Kersey, Colorado (maximum loads of 31,000 lb/d total nitrogen and 3,000 lb/d total phosphorus), and then decreased from Kersey to North Platte. Seasonal nutrient loads primarily were dependent on streamflow. Total nitrogen loads were largest in June 1994 and January 1995 when streamflows also were largest. During June, streamflow was large, but nitrogen concentrations were small, which indicated that snowmelt runoff diluted the available supply of nitrogen. Total phosphorus loads were largest in June, when streamflow and phosphorus concentrations were large, which indicated an additional source of phosphorus during snowmelt runoff. Streamflow along the South Platte River was smallest in April and August 1994, and nutrient loads also were smallest during these months. The downstream pattern for nutrient loads did not vary much by season. Loads were large at Henderson, decreased between Henderson and Kersey, and usually were largest at Kersey. The magnitude of the decrease in loads between Henderson and Kersey varied between synoptics and was dependent on the amount of water removed by irrigation ditches. Nutrient loads leaving the basin were very small compared to the estimated total nutrient inputs to the basin. Streamflow balances indicated that the South Platte River is a gaining river throughout much of its length; streamflow-balance residuals were as large as 15 cubic feet per second per mile. Nutrient-load balances indicated that increases in river nitrate loads were, in some places, due to nitrification and, elsewhere, were due to the influx of nitrate-enriched ground water to

The nutrient-load hypothesis: patterns of resource limitation and community structure driven by competition for nutrients and light.

PubMed

Brauer, Verena S; Stomp, Maayke; Huisman, Jef

2012-06-01

Resource competition theory predicts that the outcome of competition for two nutrients depends on the ratio at which these nutrients are supplied. Yet there is considerable debate whether nutrient ratios or absolute nutrient loads determine the species composition of phytoplankton and plant communities. Here we extend the classical resource competition model for two nutrients by including light as additional resource. Our results suggest the nutrient-load hypothesis, which predicts that nutrient ratios determine the species composition in oligotrophic environments, whereas nutrient loads are decisive in eutrophic environments. The underlying mechanism is that nutrient enrichment shifts the species interactions from competition for nutrients to competition for light, which favors the dominance of superior light competitors overshadowing all other species. Intermediate nutrient loads can generate high biodiversity through a fine-grained patchwork of two-species and three-species coexistence equilibria. Depending on the species traits, however, competition for nutrients and light may also produce multiple alternative stable states, suppressing the predictability of the species composition. The nutrient-load hypothesis offers a solution for several discrepancies between classical resource competition theory and field observations, explains why eutrophication often leads to diversity loss, and provides a simple conceptual framework for patterns of biodiversity and community structure observed in nature.

Chesapeake Bay Tributary Strategies

EPA Pesticide Factsheets

Chesapeake Bay Tributary Strategies were developed by the seven watershed jurisdictions and outlined the river basin-specific implementation activities to reduce nutrient and sediment pollutant loads from point and nonpoint sources.

Linking river nutrient concentrations to land use and rainfall in a paddy agriculture-urban area gradient watershed in southeast China.

PubMed

Xia, Yongqiu; Ti, Chaopu; She, Dongli; Yan, Xiaoyuan

2016-10-01

The effects of land use and land-use changes on river nutrient concentrations are not well understood, especially in the watersheds of developing countries that have a mixed land use of rice paddy fields and developing urban surfaces. Here, we present a three-year study of a paddy agricultural-urban area gradient watershed in southeast China. The annual anthropogenic nitrogen (N) input from the agricultural region to the urban region was high, yet the results showed that the monthly nutrient concentrations in the river were low in the rainy seasons. The nutrient concentrations decreased continuously as the river water passed through the traditional agriculture region (TAR; paddy rice and wheat rotation) and increased substantially in the city region (CR). The traditional agricultural reference region exported most of the nutrient loads at high flows (>1mmd(-1)), the intensified agricultural region (IAR, aquaculture and poultry farming) exported most of the nutrient loads at moderate flows (between 0.5 and 1mmd(-1)), and the CR reference area exported most of the nutrient loads under low to moderate flows. We developed a statistical model to link variations in the nutrient concentrations to the proportion of land-use types and rainfall. The statistical results showed that impervious surfaces, which we interpret as a proxy for urban activities including sewage disposal, were the most important drivers of nutrient concentrations, whereas water surfaces accounted for a substantial proportion of the nutrient sinks. Therefore, to efficiently reduce water pollution, sewage from urban areas must be addressed as a priority, although wetland restoration could also achieve substantial pollutant removal. Copyright © 2016. Published by Elsevier B.V.

Nutrient concentrations and loads in the northeastern United States - Status and trends, 1975-2003

USGS Publications Warehouse

Trench, Elaine C. Todd; Moore, Richard B.; Ahearn, Elizabeth A.; Mullaney, John R.; Hickman, R. Edward; Schwarz, Gregory E.

2012-01-01

The U.S. Geological Survey (USGS) National Water-Quality Assessment Program (NAWQA) began regional studies in 2003 to synthesize information on nutrient concentrations, trends, stream loads, and sources. In the northeastern United States, a study area that extends from Maine to central Virginia, nutrient data were evaluated for 130 USGS water-quality monitoring stations. Nutrient data were analyzed for trends in flow-adjusted concentrations, modeled instream (non-flow-adjusted) concentrations, and stream loads for 32 stations with 22 to 29 years of water-quality and daily mean streamflow record during 1975-2003 (termed the long-term period), and for 46 stations during 1993-2003 (termed the recent period), by using a coupled statistical model of streamflow and water quality developed by the USGS. Recent trends in flow-adjusted concentrations of one or more nutrients also were analyzed for 90 stations by using Tobit regression. Annual stream nutrient loads were estimated, and annual nutrient yields were calculated, for 47 stations for the long-term and recent periods, and for 37 additional stations that did not have a complete streamflow and water-quality record for 1993-2003. Nutrient yield information was incorporated for 9 drainage basins evaluated in a national NAWQA study, for a total of 93 stations evaluated for nutrient yields. Long-term downward trends in flow-adjusted concentrations of total nitrogen and total phosphorus (18 and 19 of 32 stations, respectively) indicate regional improvements in nutrient-related water-quality conditions. Most of the recent trends detected for total phosphorus were upward (17 of 83 stations), indicating possible reversals to the long-term improvements. Concentrations of nutrients in many streams persist at levels that are likely to affect aquatic habitat adversely and promote freshwater or coastal eutrophication. Recent trends for modeled instream concentrations, and modeled reference concentrations, were evaluated relative to ecoregion-based nutrient criteria proposed by the U.S. Environmental Protection Agency. Instream concentrations of total nitrogen and total phosphorus persist at levels higher than proposed criteria at more than one-third and about one-half, respectively, of the 46 stations analyzed. Long-term trends in nutrient loads were primarily downward, with downward trends in total nitrogen and total phosphorus loads detected at 12 and 17 of 32 stations, respectively. Upward trends were rare, with one upward trend for total nitrogen loads and none for total phosphorus. Trends in loads of nitrite-plus-nitrate nitrogen included 7 upward and 8 downward trends among 32 stations. Downward trends in loads of ammonia nitrogen and total Kjeldahl nitrogen were detected at all six stations evaluated. Long-term downward trends detected in four of the five largest drainage basins evaluated include: total nitrogen loads for the Connecticut, Delaware, and James Rivers; total Kjeldahl nitrogen and ammonia nitrogen loads for the Susquehanna River; ammonia nitrogen and nitrite-plus-nitrate nitrogen loads for the James River; and total phosphorus loads for the Connecticut and Delaware Rivers. No trends in load were detected for the Potomac River. Nutrient yields were evaluated relative to the extent of land development in 93 drainage basins. The undeveloped land-use category included forested drainage basins with undeveloped land ranging from 75 to 100 percent of basin area. Median total nitrogen yields for the 27 undeveloped drainage basins evaluated, including 9 basins evaluated in a national NAWQA study, ranged from 290 to 4,800 pounds per square mile per year (lb/mi2/yr). Total nitrogen yields even in the most pristine drainage basins may be elevated relative to natural conditions, because of high rates of atmospheric deposition of nitrogen in parts of the northeastern United States. Median total phosphorus yields ranged from 12 to 330 lb/mi2/yr for the 26 undeveloped basins evaluated. The undeveloped category includes some large drainage basins with point-source discharges and small percentages of developed land; in these basins, streamflow from undeveloped headwater areas dilutes streamflow in more urbanized reaches, and dampens but does not eliminate the point-source "signal" of higher nutrient loads. Median total nitrogen yields generally do not exceed 1,700 lb/mi2/yr, and median total phosphorus yields generally do not exceed 100 lb/mi2/yr, in the drainage basins that are least affected by human land-use and waste-disposal practices. Agricultural and urban land use has increased nutrient yields substantially relative to undeveloped drainage basins. Median total nitrogen yields for 24 agricultural basins ranged from 1,700 to 26,000 lb/mi2/yr, and median total phosphorus yields ranged from 94 to 1,000 lb/mi2/yr. The maximum estimated total nitrogen and total phosphorus yields, 32,000 and 16,000 lb/mi2/yr, respectively, for all stations in the region were in small (less than 50 square miles (mi2)) agricultural drainage basins. Median total nitrogen yields ranged from 1,400 to 17,000 lb/mi2/yr in 26 urbanized drainage basins, and median total phosphorus yields ranged from 43 to 1,900 lb/mi2/yr. Urbanized drainage basins with the highest nutrient yields are generally small (less than 300 mi2) and are drained by streams that receive major point-source discharges. Instream nutrient loads were evaluated relative to loads from point-source discharges in four drainage basins: the Quinebaug River Basin in Connecticut, Massachusetts, and Rhode Island; the Raritan River Basin in New Jersey; the Patuxent River Basin in Maryland; and the James River Basin in Virginia. Long-term downward trends in nutrient loads, coupled with similar trends in flow-adjusted nutrient concentrations, indicate long-term reductions in the delivery of most nutrients to these streams. However, the absence of recent downward trends in load for most nutrients, coupled with instream concentrations that exceed proposed nutrient criteria in several of these waste-receiving streams, indicates that challenges remain in reducing delivery of nutrients to streams from point sources. During dry years, the total nutrient load from point sources in some of the drainage basins approached or equaled the nutrient load transported by the stream.

Response of Submerged Macrophyte Communities to External and Internal Restoration Measures in North Temperate Shallow Lakes

PubMed Central

Hilt, Sabine; Alirangues Nuñez, Marta M.; Bakker, Elisabeth S.; Blindow, Irmgard; Davidson, Thomas A.; Gillefalk, Mikael; Hansson, Lars-Anders; Janse, Jan H.; Janssen, Annette B. G.; Jeppesen, Erik; Kabus, Timm; Kelly, Andrea; Köhler, Jan; Lauridsen, Torben L.; Mooij, Wolf M.; Noordhuis, Ruurd; Phillips, Geoff; Rücker, Jacqueline; Schuster, Hans-Heinrich; Søndergaard, Martin; Teurlincx, Sven; van de Weyer, Klaus; van Donk, Ellen; Waterstraat, Arno; Willby, Nigel; Sayer, Carl D.

2018-01-01

Submerged macrophytes play a key role in north temperate shallow lakes by stabilizing clear-water conditions. Eutrophication has resulted in macrophyte loss and shifts to turbid conditions in many lakes. Considerable efforts have been devoted to shallow lake restoration in many countries, but long-term success depends on a stable recovery of submerged macrophytes. However, recovery patterns vary widely and remain to be fully understood. We hypothesize that reduced external nutrient loading leads to an intermediate recovery state with clear spring and turbid summer conditions similar to the pattern described for eutrophication. In contrast, lake internal restoration measures can result in transient clear-water conditions both in spring and summer and reversals to turbid conditions. Furthermore, we hypothesize that these contrasting restoration measures result in different macrophyte species composition, with added implications for seasonal dynamics due to differences in plant traits. To test these hypotheses, we analyzed data on water quality and submerged macrophytes from 49 north temperate shallow lakes that were in a turbid state and subjected to restoration measures. To study the dynamics of macrophytes during nutrient load reduction, we adapted the ecosystem model PCLake. Our survey and model simulations revealed the existence of an intermediate recovery state upon reduced external nutrient loading, characterized by spring clear-water phases and turbid summers, whereas internal lake restoration measures often resulted in clear-water conditions in spring and summer with returns to turbid conditions after some years. External and internal lake restoration measures resulted in different macrophyte communities. The intermediate recovery state following reduced nutrient loading is characterized by a few macrophyte species (mainly pondweeds) that can resist wave action allowing survival in shallow areas, germinate early in spring, have energy-rich vegetative propagules facilitating rapid initial growth and that can complete their life cycle by early summer. Later in the growing season these plants are, according to our simulations, outcompeted by periphyton, leading to late-summer phytoplankton blooms. Internal lake restoration measures often coincide with a rapid but transient colonization by hornworts, waterweeds or charophytes. Stable clear-water conditions and a diverse macrophyte flora only occurred decades after external nutrient load reduction or when measures were combined. PMID:29515607

Assessing the impacts of climate change on discharge and nutrient losses from a karstic agricultural sub-basin in the Upper Chesapeake Bay watershed

USDA-ARS?s Scientific Manuscript database

The health of the Chesapeake Bay Basin ecosystem, which lies within the heavily populated Northeastern United States, relies on reducing nutrient loading to the Chesapeake Bay by the 2025 TMDL deadline and on into the future. Doing so requires evaluating the impact of current agricultural management...

Assessment of nutrient loadings of a large multipurpose prairie reservoir

NASA Astrophysics Data System (ADS)

Morales-Marín, L. A.; Wheater, H. S.; Lindenschmidt, K. E.

2017-07-01

The relatively low water flow velocities in reservoirs cause them to have high capacities for retaining sediments and pollutants, which can lead to a reduction in downstream nutrient loading. Hence, nutrients can progressively accumulate in reservoirs, resulting in the deterioration of aquatic ecosystems and water quality. Lake Diefenbaker (LD) is a large multipurpose reservoir, located on the South Saskatchewan River (SSR), that serves as a major source of freshwater in Saskatchewan, Canada. Over the past several years, changes in land use (e.g. expansion of urban areas and industrial developments) in the reservoir's catchment have heightened concerns about future water quality in the catchment and in the reservoir. Intensification of agricultural activities has led to an increase in augmented the application of manure and fertilizer for crops and pasture. Although previous research has attempted to quantify nutrient retention in LD, there is a knowledge gap related to the identification of major nutrient sources and quantification of nutrient export from the catchment at different spatial scales. Using the SPAtially Referenced Regression On Watershed (SPARROW) model, this gap has been addressed by assessing water quality regionally, and identifying spatial patterns of factors and processes that affect water quality in the LD catchment. Model results indicate that LD retains about 70% of the inflowing total nitrogen (TN) and 90% of the inflowing total phosphorus (TP) loads, of which fertilizer and manure applied to agricultural fields contribute the greatest proportion. The SPARROW model will be useful as a tool to guide the optimal implementation of nutrient management plans to reduce nutrient inputs to LD.

The impacts of no-till practice on nitrate and phosphorus loss: A meta-analysis

NASA Astrophysics Data System (ADS)

Wang, L.; Daryanto, S.; Jacinthe, P. A.

2017-12-01

Although no-till (NT) has been promoted as an alternative land management practice to conventional tillage (CT), its impact on water quality, especially nitrate (NO3-) and phosphorus (P) loss remain controversial. We conducted a meta-analysis to compare NO3- and P (dissolved P, particulate P and total P) concentration and load in NT and CT systems, including the co-varying physical (e.g., climate region, rainfall variability, transport pathways, slope gradient) and management variables (e.g., NT duration, crop species). In general, NT increased the amount of dissolved nutrient loss (both NO3- and P), but reduced that of particulate nutrient (particulate P). Specifically, NT resulted in an overall increase of runoff NO3- concentration in comparison to CT, but similar runoff NO3- load. In contrast, NO3- load via leaching was greater under NT than under CT, although NO3- concentration in leachate was similar under both tillage practices, indicating that the effect of NT on NO3- load was largely determined by changes in water flux. NT adoption, in comparison to CT, reduced particulate P concentration by 45% and load by 55%, but increased dissolved P loss by 35% (for both concentration and load). Some variations, however, were recorded with different co-varying variables. NT was, for example, least effective in reducing leachate NO3- concentration in fields planted with wheat, but generated lower leachate NO3- concentration from soybean fields (no N fertilizer applied). In contrast, total P concentration was similar with CT at NT fields planted with soybean and at sites under prolonged NT duration ( 10 years). The limited impact of NT on dissolved nutrient loss (both NO3- and P) remains a serious impediment toward harnessing the water quality benefits of this management practice and suggests that NT needs to be complemented with other management practices (e.g., cover crops, split fertilizer application, occasional tillage).

Impacts of elevated terrestrial nutrient loads and temperature on pelagic food-web efficiency and fish production.

PubMed

Lefébure, R; Degerman, R; Andersson, A; Larsson, S; Eriksson, L-O; Båmstedt, U; Byström, P

2013-05-01

Both temperature and terrestrial organic matter have strong impacts on aquatic food-web dynamics and production. Temperature affects vital rates of all organisms, and terrestrial organic matter can act both as an energy source for lower trophic levels, while simultaneously reducing light availability for autotrophic production. As climate change predictions for the Baltic Sea and elsewhere suggest increases in both terrestrial matter runoff and increases in temperature, we studied the effects on pelagic food-web dynamics and food-web efficiency in a plausible future scenario with respect to these abiotic variables in a large-scale mesocosm experiment. Total basal (phytoplankton plus bacterial) production was slightly reduced when only increasing temperatures, but was otherwise similar across all other treatments. Separate increases in nutrient loads and temperature decreased the ratio of autotrophic:heterotrophic production, but the combined treatment of elevated temperature and terrestrial nutrient loads increased both fish production and food-web efficiency. CDOM: Chl a ratios strongly indicated that terrestrial and not autotrophic carbon was the main energy source in these food webs and our results also showed that zooplankton biomass was positively correlated with increased bacterial production. Concomitantly, biomass of the dominant calanoid copepod Acartia sp. increased as an effect of increased temperature. As the combined effects of increased temperature and terrestrial organic nutrient loads were required to increase zooplankton abundance and fish production, conclusions about effects of climate change on food-web dynamics and fish production must be based on realistic combinations of several abiotic factors. Moreover, our results question established notions on the net inefficiency of heterotrophic carbon transfer to the top of the food web. © 2013 Blackwell Publishing Ltd.

Climate change and agricultural development: adapting Polish agriculture to reduce future nutrient loads in a coastal watershed.

PubMed

Piniewski, Mikołaj; Kardel, Ignacy; Giełczewski, Marek; Marcinkowski, Paweł; Okruszko, Tomasz

2014-09-01

Currently, there is a major concern about the future of nutrient loads discharged into the Baltic Sea from Polish rivers because they are main contributors to its eutrophication. To date, no watershed-scale studies have properly addressed this issue. This paper fills this gap by using a scenario-modeling framework applied in the Reda watershed, a small (482 km²) agricultural coastal area in northern Poland. We used the SWAT model to quantify the effects of future climate, land cover, and management changes under multiple scenarios up to the 2050s. The combined effect of climate and land use change on N-NO3 and P-PO4 loads is an increase by 20-60 and 24-31 %, respectively, depending on the intensity of future agricultural usage. Using a scenario that assumes a major shift toward a more intensive agriculture following the Danish model would bring significantly higher crop yields but cause a great deterioration of water quality. Using vegetative cover in winter and spring (VC) would be a very efficient way to reduce future P-PO4 loads so that they are lower than levels observed at present. However, even the best combination of measures (VC, buffer zones, reduced fertilization, and constructed wetlands) would not help to remediate heavily increased N-NO3 loads due to climate change and agricultural intensification.

Nutrient loss in leachate and surface runoff from surface-broadcast and subsurface-banded broiler litter.

PubMed

Lamba, Jasmeet; Srivastava, Puneet; Way, Thomas R; Sen, Sumit; Wood, C Wesley; Yoo, Kyung H

2013-09-01

Subsurface band application of poultry litter has been shown to reduce the transport of nutrients from fields in surface runoff compared with conventional surface broadcast application. Little research has been conducted to determine the effects of surface broadcast application and subsurface banding of litter on nutrients in leachate. Therefore, a field experiment was conducted to determine the effects of subsurface band application and surface broadcast application of poultry litter on nutrient losses in leachate. Zero-tension pan and passive capillary fiberglass wick lysimeters were installed in situ 50 cm beneath the soil surface of an established tall fescue ( Schreb.) pasture on a sandy loam soil. The treatments were surface broadcast and subsurface-banded poultry litter at 5 Mg ha and an unfertilized control. Results of the rainfall simulations showed that the concentrations of PO-P and total phosphorus (TP) in leachate were reduced by 96 and 37%, respectively, in subsurface-banded litter treatment compared with the surface-applied litter treatment. There was no significant difference in PO-P concentration between control and subsurface-banded litter treatment in leachate. The trend in the loading of nutrients in leachate was similar to the trend in concentration. Concentration and loading of the nutrients (TP, PO-P, NH-N, and NO-N) in runoff from the subsurface-banded treatment were significantly less than for the surface-applied treatment and were similar to those from control plots. These results show that, compared with conventional surface broadcast application of litter, subsurface band application of litter can greatly reduce loss of P in surface runoff and leachate. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Nutrient pressures and ecological responses to nutrient loading reductions in Danish streams, lakes and coastal waters

NASA Astrophysics Data System (ADS)

Kronvang, Brian; Jeppesen, Erik; Conley, Daniel J.; Søndergaard, Martin; Larsen, Søren E.; Ovesen, Niels B.; Carstensen, Jacob

2005-03-01

The Danish National Aquatic Monitoring and Assessment Programme (NOVA) was launched in 1988 following the adoption of the first Danish Action Plan on the Aquatic Environment in 1987 with the aim to reduce by 50% the nitrogen (N) loading and by 80% the phosphorus (P) loading to the aquatic environment. The 14 years of experience gathered from NOVA have shown that discharges of total N (TN) and P (TP) from point sources to the Danish Aquatic Environment have been reduced by 69% (N) and 82% (P) during the period 1989 2002. Consequently, the P concentration has decreased markedly in most Danish lakes and estuaries. Considerable changes in agricultural practice have resulted in a reduction of the net N-surplus from 136 to 88 kg N ha-1 yr-1 (41%) and the net P-surplus from 19 to 11 kg P ha-1 yr-1 (42%) during the period 1985 2002. Despite these efforts Danish agriculture is today the major source of both N (>80%) and P (>50%) in Danish streams, lakes and coastal waters. A non-parametric statistical trend analysis of TN concentrations in streams draining dominantly agricultural catchments has shown a significant (p<0.05) downward trend in 48 streams with the downward trend being stronger in loamy compared to sandy catchments, and more pronounced with increasing dominance of agricultural exploitation in the catchments. In contrast, a statistical trend analysis of TP concentrations in streams draining agricultural catchments did not reveal any significant trends. The large reduction in nutrient loading from point and non-point sources has in general improved the ecological conditions of Danish lakes in the form of increased summer Secchi depth, decreased chlorophyll a and reduced phytoplankton biomass. Major changes have also occurred in the fish communities in lakes, with positive cascading effects on water quality. In Danish estuaries and coastal waters only a few significant improvements in the ecological quality have been observed, although it is expected that the observed reduced nutrient concentrations are likely to improve the ecological quality of estuaries and coastal waters in Denmark in the long term.

Analyzing Variability in Landscape Nutrient Loading Using Spatially-Explicit Maps in the Great Lakes Basin

NASA Astrophysics Data System (ADS)

Hamlin, Q. F.; Kendall, A. D.; Martin, S. L.; Whitenack, H. D.; Roush, J. A.; Hannah, B. A.; Hyndman, D. W.

2017-12-01

Excessive loading of nitrogen and phosphorous to the landscape has caused biologically and economically damaging eutrophication and harmful algal blooms in the Great Lakes Basin (GLB) and across the world. We mapped source-specific loads of nitrogen and phosphorous to the landscape using broadly available data across the GLB. SENSMap (Spatially Explicit Nutrient Source Map) is a 30m resolution snapshot of nutrient loads ca. 2010. We use these maps to study variable nutrient loading and provide this information to watershed managers through NOAA's GLB Tipping Points Planner. SENSMap individually maps nutrient point sources and six non-point sources: 1) atmospheric deposition, 2) septic tanks, 3) non-agricultural chemical fertilizer, 4) agricultural chemical fertilizer, 5) manure, and 6) nitrogen fixation from legumes. To model source-specific loads at high resolution, SENSMap synthesizes a wide range of remotely sensed, surveyed, and tabular data. Using these spatially explicit nutrient loading maps, we can better calibrate local land use-based water quality models and provide insight to watershed managers on how to focus nutrient reduction strategies. Here we examine differences in dominant nutrient sources across the GLB, and how those sources vary by land use. SENSMap's high resolution, source-specific approach offers a different lens to understand nutrient loading than traditional semi-distributed or land use based models.

Hindcasting of nutrient loadings from its catchment on a highly valuable coastal lagoon: the example of the Fleet, Dorset, UK, 1866–2004

PubMed Central

Weber, Geraint J; O'Sullivan, Patrick E; Brassley, Paul

2006-01-01

Background Nutrient loadings from its catchment upon The Fleet, a highly valuable coastal lagoon in Southern England, were hindcast for the period AD 1866–2004, using a catchment model, export coefficients, and historical data on land use changes, livestock numbers, and human population. Agriculture was the main nutrient source throughout, other inputs representing minor contributions. Permanent pasture was historically the main land use, with temporary grassland and cereals increasing during the mid-20th century. Sheep, the main 19th century livestock, were replaced by cattle during the 1930s. Results Total nitrogen loadings rose from ca 41 t yr-1 during the late 19th century to 49–54 t yr-1 for the mid-20th, increasing to 98 t yr-1 by 1986. Current values are ca 77 t yr-1. Total phosphorus loads increased from ca 0.75 t yr-1 for the late 19th century to ca 1.6 t yr-1 for the mid-20th, reached ca 2.2 t yr-1 in 1986, and are now ca 1.5 t yr-1. Loadings rose most rapidly between 1946 and 1988, owing to increased use of inorganic fertilisers, and rising sheep and cattle numbers. Livestock were the main nutrient source throughout, but inputs from inorganic fertilisers increased after 1946, peaking in 1986. Sewage treatment works and other sources contribute little nitrogen, but ca 35% of total phosphorus. Abbotsbury Swannery, an ancient Mute Swan community, provides ca 0.5% of total nitrogen, and ca 5% of total phosphorus inputs. Conclusion The Fleet has been grossly overloaded with nitrogen since 1866, climaxing during the 1980s. Total phosphorus inputs lay below 'permissible' limits until the 1980s, exceeding them in inner, less tidal parts of the lagoon, during the 1940s. Loadings on Abbotsbury Bay exceeded 'permissible' limits by the 1860s, becoming 'dangerous' during the mid-20th century. Phosphorus stripping at point sources will not significantly reduce loadings to all parts of the lagoon. Installation of 5 m buffer strips throughout the catchment and shoreline will marginally affect nitrogen loadings, but will reduce phosphorus inputs to the West Fleet below 'permissible' limits. Only a combination of measures will significantly affect Abbotsbury Bay, where, without effluent diversion, loadings will remain beyond 'permissible'. PMID:17196108

Simulating hydrological and geochemical processes in a karstic watershed of the Upper Chesapeake Bay

USDA-ARS?s Scientific Manuscript database

Water quality improvement in the Chesapeake Bay is a grave concern. An initiative to reduce the nutrient loads to the streams in the watershed has been undertaken to attain a target total maximum daily load (TMDL) at Chesapeake Bay. A general guideline with a list of best management practices (BMPs)...

Low Impact Development for Industrial Areas

DTIC Science & Technology

2015-07-01

Stormwater program managers are faced with increasingly stringent stormwater discharge limits for heavy metals such as copper, zinc , nutrients, total...limits for heavy metals such as copper, zinc , nutrients, total suspended solids (TSS), oil and grease. These limits are required to reduce...U.S. EPA), state agencies, and local agencies set permit limits as part of the total mass daily loading regulatory framework. Copper, zinc , lead

Agricultural nutrient loadings to the freshwater environment: the role of climate change and socioeconomic change

NASA Astrophysics Data System (ADS)

Xie, Hua; Ringler, Claudia

2017-10-01

Human activities, in particular agricultural production, interfere with natural cycles of nutrient elements, nitrogen (N) and phosphorus (P), leading to growing concerns about water quality degradation related to excessive nutrient loadings. Increases in agricultural production in response to population growth and wealth generation further increase risks associated with nutrient pollution. This paper presents results from projections of nutrient exports from global agricultural crop and pasture systems to the water environment generated using a process-based modeling approach. Brazil, China, India and the United States account for more than half of estimated global N and P loadings in the base year. Each country boasts large agriculture centers where high calculated loading values are found. Rapid growth in global agricultural nutrient loadings is projected. Growth of agricultural pollution loading is fastest in the group of low-income developing countries and loading growth rates also vary substantially with climate change scenario. Counter measures need to be taken to address the environmental risks associated with the projected rapid increase of agricultural nutrient loadings.

Proximate and Ultimate Limiting Nutrients in the Mississippi River Plume: Implications for Hypoxia Reduction Through Nutrient Management

NASA Astrophysics Data System (ADS)

Fennel, K.; Laurent, A.

2016-02-01

A large hypoxic area (15,000 km2 on average) forms every summer over the Texas-Louisiana shelf in the northern Gulf of Mexico due to decay of organic matter that is primarily derived from nutrient inputs from the Mississippi/Atchafalaya River System. Efforts are underway to reduce the extent of hypoxic conditions through nutrient management in the watershed; for example, an interagency Hypoxia Task Force is developing Action Plans with input from various stakeholders that set out targets for hypoxia reduction. An open question is by how much nutrient loads would have to be decreased in order to produce the desired reductions in hypoxia and when these would be measurable over natural variability. We have performed a large number of multi-year nutrient load reduction scenarios with a regional biogeochemical model for the region. The model is based on the Regional Ocean Modeling System (ROMS), explicitly includes nitrogen (N) and phosphorus (P) species as inorganic nutrients, and has been shown to realistically reproduce the key processes responsible for hypoxia generation. We have quantified the effects of differential reductions in river N and P loads on hypoxic extent. An assessment of the effects of N versus P reductions is important because, thus far, nutrient management efforts have focused on N, yet P is known to limit primary production in spring and early summer. A debate is ongoing as to whether targets for P reductions should be set and whether nutrient reduction efforts should focus solely on P, which results primarily from urban and industrial point sources and is uncoupled from agricultural fertilizer application. Our results strongly indicate that N is the `ultimate' limiting nutrient to primary production determining the areal extent and duration of hypoxic conditions in a cumulative sense, while P is temporarily limiting in spring. Although reductions in river P load would decrease hypoxic extent in early summer, they would have a much smaller effect than N reductions on the cumulative extent and duration of hypoxic conditions. Combined reductions of N and P have the greatest effect.

Proximate versus ultimate limiting nutrients in the Mississippi River Plume and Implications for Hypoxia Reductions through Nutrient Management

NASA Astrophysics Data System (ADS)

Fennel, Katja; Laurent, Arnaud

2016-04-01

A large hypoxic area (15,000 km2 on average) forms every summer over the Texas-Louisiana shelf in the northern Gulf of Mexico due to decay of organic matter that is primarily derived from nutrient inputs from the Mississippi/Atchafalaya River System. Efforts are underway to reduce the extent of hypoxic conditions through nutrient management in the watershed; for example, an interagency Hypoxia Task Force is developing Action Plans with input from various stakeholders that set out targets for hypoxia reduction. An open question is how far nutrient loads would have to be decreased in order to produce the desired reductions in hypoxia and when these would be measurable given significant natural variability. We have simulated a large number of multi-year nutrient load reduction scenarios with a regional biogeochemical model for the region. The model is based on the Regional Ocean Modeling System (ROMS), explicitly includes nitrogen (N) and phosphorus (P) species as inorganic nutrients, and has been shown to realistically reproduce the key processes responsible for hypoxia generation. We have quantified the effects of differential reductions in river N and P loads on hypoxic extent. An assessment of the effects of N versus P reductions is important because, thus far, nutrient management efforts have focused on N, yet P is known to limit primary production in spring and early summer. A debate is ongoing as to whether targets for P reductions should be set and whether nutrient reduction efforts should focus solely on P, which results primarily from urban and industrial point sources and is uncoupled from agricultural fertilizer application. Our results strongly indicate that N is the 'ultimate' limiting nutrient to primary production determining the areal extent and duration of hypoxic conditions in a cumulative sense, while P is temporarily limiting in spring. Although reductions in river P load would decrease hypoxic extent in early summer, they would have a much smaller effect than N reductions on the cumulative extent and duration of hypoxic conditions. Combined reductions of N and P have the greatest effect.

The effect of restored and native oxbows on hydraulic loads of nutrients and stream water quality

USGS Publications Warehouse

Kalkhoff, Stephen J.; Hubbard, Laura E.; Joseph P.Schubauer-Berigan,

2016-01-01

The use of oxbow wetlands has been identified as a potential strategy to reduce nutrient transport from agricultural drainage tiles to streams in Iowa. In 2013 and 2014, a study was conducted in north-central Iowa in a native oxbow in the Lyons Creek watershed and two restored oxbow wetlands in the Prairie Creek watershed (Smeltzer west and Smeltzer east) to assess their effectiveness at reducing nitrogen and phosphorus loads. The tile line inlets carrying agricultural runoff to the oxbows, the outfall from the oxbows, and the surface waters in the streams receiving the outfall water were monitored for discharge and nutrients from February 2013 to September 2015. Smeltzer west and east also had four monitoring wells each, two in the upland and two between the oxbow and Prairie Creek to monitor surface water-groundwater interaction. The Smeltzer west and east oxbow sites also were instrumented to continuously measure the nitrate concentration. Rainfall was measured at one Lyons Creek and one Smeltzer site. Daily mean nitrate-N concentrations in Lyons Creek in 2013 ranged from 11.8 mg/L to 40.9 mg/L, the median daily mean nitrate-N concentration was 33.0 mg/L. Daily mean nitrate-N concentrations in Prairie Creek in 2013 ranged from 0.07 mg/L in August to 32.2 mg/L in June. In 2014, daily mean nitrate-N concentrations in Prairie Creek ranged from 0.17 mg/L in April to 26.7 mg/L in July; the daily mean nitrate-N concentration for the sampled period was 9.78 mg/L. Nutrient load reduction occurred in oxbow wetlands in Lyons and Prairie Creek watersheds in north-central Iowa but efficiency of reduction was variable. Little nutrient reduction occurred in the native Lyons Creek oxbow during 2013. Concentrations of all nutrient constituents were not significantly (P>0.05, Wilcoxon rank sum) different in water discharging from the tile line than in water leaving the Lyons Creek oxbow. A combination of physical features and flow conditions suggest that the residence time of water in the oxbow may not have been sufficient to allow for removal of substantial amounts of nutrients. Approximately 54 percent less nitrate-N was measured leaving the Smeltzer west oxbow than was measured entering from a small 6-inch field tile. The efficiency of nitrate-N removal in the oxbow was not able to be definitively quantified as other hydrologic factors such as overland and groundwater flow into and through the oxbow were not addressed and may provide alternative routes for nutrient transport. Damage to the Smeltzer east oxbow outfall weir prevented analysis of its nutrient load reduction capability. The study provides important information to managers and land owners looking for strategies to reduce nutrient transport from fields. Additional research is needed to understand how increased discharge from larger field tiles and drainage district mains may influence the efficiency of nutrient reduction in relation to the size, type, and landscape setting of a wetland.

The effect of sampling frequency on the accuracy of nitrogen load estimates from a drained loblolly pine plantation in eastern North Carolina

Treesearch

George M. Chescheir; François Birgand; Shiying Tian; Mohamed A. Youssef; Devendra M. Amatya

2010-01-01

Nutrient loading in drainage outflow is estimated from measured flows and nutrient concentrations in the drainage water. The loading function is ideally continuous, representing the product of continuously measured outflows and nutrient concentrations in drainage water. However, loading is often estimated as the product of continuously measured outflow and nutrient...

Impacts of fertilization on water quality of a drained pine plantation: a worst case scenario.

PubMed

Beltran, Bray J; Amatya, Devendra M; Youssef, Mohamed; Jones, Martin; Callahan, Timothy J; Skaggs, R Wayne; Nettles, Jami E

2010-01-01

Intensive plantation forestry will be increasingly important in the next 50 yr to meet the high demand for domestic wood in the United States. However, forest management practices can substantially influence downstream water quality and ecology. This study analyses, the effect of fertilization on effluent water quality of a low gradient drained coastal pine plantation in Carteret County, North Carolina using a paired watershed approach. The plantation consists of three watersheds, two mature (31-yr) and one young (8-yr) (age at treatment). One of the mature watersheds was commercially thinned in 2002. The mature unthinned watershed was designated as the control. The young and mature-thinned watersheds were fertilized at different rates with Arborite (Encee Chemical Sales, Inc., Bridgeton, NC), and boron. The outflow rates and nutrient concentrations in water drained from each of the watersheds were measured. Nutrient concentrations and loadings were analyzed using general linear models (GLM). Three large storm events occurred within 47 d of fertilization, which provided a worst case scenario for nutrient export from these watersheds to the receiving surface waters. Results showed that average nutrient concentrations soon after fertilization were significantly (alpha = 0.05) higher on both treatment watersheds than during any other period during the study. This increase in nutrient export was short lived and nutrient concentrations and loadings were back to prefertilization levels as soon as 3 mo after fertilization. Additionally, the mature-thinned watershed presented higher average nutrient concentrations and loadings when compared to the young watershed, which received a reduced fertilizer rate than the mature-thinned watershed.

The Potential Importance of Conservation, Restoration and Altered Management Practices for Water Quality in the Wabash River Watershed

NASA Astrophysics Data System (ADS)

Yang, G.; Best, E. P.; Goodwin, S.

2013-12-01

Non-point source (NPS) pollution is one of the leading causes of water quality impairment within the United States. Conservation, restoration and altered management (CRAM) practices may effectively reduce NPS pollutants to receiving water bodies and enhance local and regional ecosystem services. Barriers for the implementation of CRAM include uncertainties related to the extent to which nutrients are removed by CRAM at various spatial and temporal scales, longevity, optimal placement of CRAM within the landscape, and implementation / operation / maintenance costs. We conducted a study aimed at the identification of optimal placement of CRAM in watersheds that reduces N loading to an environmentally sustainable level, at an acceptable, known, cost. For this study, we used a recently developed screening-level modeling approach, WQM-TMDL-N, running in the ArcGIS environment, to estimate nitrogen loading under current land use conditions (NLCD 2006). This model was equipped with a new option to explore the performances of placement of various CRAM types and areas to reduce nitrogen loading to a State-accepted Total Maximum Daily Load (TMDL) standard, with related annual average TN concentration, and a multi-objective algorithm optimizing load and cost. CRAM practices explored for implementation in rural area included buffer strips, nutrient management practices, and wetland restoration. We initially applied this modeling approach to the Tippecanoe River (TR) watershed (8-digit HUC), a headwater of the Wabash River (WR) watershed, where CRAM implementation in rural and urban areas is being planned and implemented at various spatial scales. Consequences of future land use are explored using a 2050 land use/land cover map forecasted by the Land Transformation Model. The WR watershed, IN, drains two-thirds of the state's 92 counties and supports predominantly agricultural land use. Because the WR accounts for over 40% of the nutrient loads of the Ohio River and significantly contributes to the anoxic zone in the Gulf of Mexico (GOM), reduction in TN loading of the WR are expected to directly benefit downstream ecosystem services, including fisheries in the GOM. This modeling approach can be used in support of sustainable integrated watershed management planning.

Estimation of Total Nitrogen and Phosphorus in New England Streams Using Spatially Referenced Regression Models

USGS Publications Warehouse

Moore, Richard Bridge; Johnston, Craig M.; Robinson, Keith W.; Deacon, Jeffrey R.

2004-01-01

The U.S. Geological Survey (USGS), in cooperation with the U.S. Environmental Protection Agency (USEPA) and the New England Interstate Water Pollution Control Commission (NEIWPCC), has developed a water-quality model, called SPARROW (Spatially Referenced Regressions on Watershed Attributes), to assist in regional total maximum daily load (TMDL) and nutrient-criteria activities in New England. SPARROW is a spatially detailed, statistical model that uses regression equations to relate total nitrogen and phosphorus (nutrient) stream loads to nutrient sources and watershed characteristics. The statistical relations in these equations are then used to predict nutrient loads in unmonitored streams. The New England SPARROW models are built using a hydrologic network of 42,000 stream reaches and associated watersheds. Watershed boundaries are defined for each stream reach in the network through the use of a digital elevation model and existing digitized watershed divides. Nutrient source data is from permitted wastewater discharge data from USEPA's Permit Compliance System (PCS), various land-use sources, and atmospheric deposition. Physical watershed characteristics include drainage area, land use, streamflow, time-of-travel, stream density, percent wetlands, slope of the land surface, and soil permeability. The New England SPARROW models for total nitrogen and total phosphorus have R-squared values of 0.95 and 0.94, with mean square errors of 0.16 and 0.23, respectively. Variables that were statistically significant in the total nitrogen model include permitted municipal-wastewater discharges, atmospheric deposition, agricultural area, and developed land area. Total nitrogen stream-loss rates were significant only in streams with average annual flows less than or equal to 2.83 cubic meters per second. In streams larger than this, there is nondetectable in-stream loss of annual total nitrogen in New England. Variables that were statistically significant in the total phosphorus model include discharges for municipal wastewater-treatment facilities and pulp and paper facilities, developed land area, agricultural area, and forested area. For total phosphorus, loss rates were significant for reservoirs with surface areas of 10 square kilometers or less, and in streams with flows less than or equal to 2.83 cubic meters per second. Applications of SPARROW for evaluating nutrient loading in New England waters include estimates of the spatial distributions of total nitrogen and phosphorus yields, sources of the nutrients, and the potential for delivery of those yields to receiving waters. This information can be used to (1) predict ranges in nutrient levels in surface waters, (2) identify the environmental variables that are statistically significant predictors of nutrient levels in streams, (3) evaluate monitoring efforts for better determination of nutrient loads, and (4) evaluate management options for reducing nutrient loads to achieve water-quality goals.

Effects of ecosystem-based management treatments

Treesearch

Michael G. Harrington; Carl E. Fiedler; Stephen F. Arno; Ward W. McCaughey; Leon J. Theroux; Clinton E. Carlson; Kristin L. Zouhar; Thomas H. DeLuca; Donald J. Bedunah; Dayna M. Ayers; Elizabeth A. Beringer; Sallie J. Hejl; Lynn Bacon; Robert E. Benson; Jane Kapler Smith; Rick Floch

1999-01-01

The prescribed burn treatments were applied to reduce pre-existing and new slash fuel loadings, reduce understory tree density to lower crown fire potential, stimulate vigor of decadent understory vegetation, produce mineral seedbeds for seral species establishment, and increase availability of mineral nutrients. To test the feasibility of prescribed burning under a...

Use of Principal Components Analysis to Explain Controls on Nutrient Fluxes to the Chesapeake Bay

NASA Astrophysics Data System (ADS)

Rice, K. C.; Mills, A. L.

2017-12-01

The Chesapeake Bay watershed, on the east coast of the United States, encompasses about 166,000-square kilometers (km2) of diverse land use, which includes a mixture of forested, agricultural, and developed land. The watershed is now managed under a Total Daily Maximum Load (TMDL), which requires implementation of management actions by 2025 that are sufficient to reduce nitrogen, phosphorus, and suspended-sediment fluxes to the Chesapeake Bay and restore the bay's water quality. We analyzed nutrient and sediment data along with land-use and climatic variables in nine sub watersheds to better understand the drivers of flux within the watershed and to provide relevant management implications. The nine sub watersheds range in area from 300 to 30,000 km2, and the analysis period was 1985-2014. The 31 variables specific to each sub watershed were highly statistically significantly correlated, so Principal Components Analysis was used to reduce the dimensionality of the dataset. The analysis revealed that about 80% of the variability in the whole dataset can be explained by discharge, flux, and concentration of nutrients and sediment. The first two principal components (PCs) explained about 68% of the total variance. PC1 loaded strongly on discharge and flux, and PC2 loaded on concentration. The PC scores of both PC1 and PC2 varied by season. Subsequent analysis of PC1 scores versus PC2 scores, broken out by sub watershed, revealed management implications. Some of the largest sub watersheds are largely driven by discharge, and consequently large fluxes. In contrast, some of the smaller sub watersheds are more variable in nutrient concentrations than discharge and flux. Our results suggest that, given no change in discharge, a reduction in nutrient flux to the streams in the smaller watersheds could result in a proportionately larger decrease in fluxes of nutrients down the river to the bay, than in the larger watersheds.

Effects of nutrient load on microbial activities within a seagrass-dominated ecosystem: Implications of changes in seagrass blue carbon.

PubMed

Liu, Songlin; Jiang, Zhijian; Wu, Yunchao; Zhang, Jingping; Arbi, Iman; Ye, Feng; Huang, Xiaoping; Macreadie, Peter Ian

2017-04-15

Nutrient loading is a leading cause of global seagrass decline, triggering shifts from seagrass- to macroalgal-dominance. Within seagrass meadows of Xincun Bay (South China Sea), we found that nutrient loading (due to fish farming) increased sediment microbial biomass and extracellular enzyme activity associated with carbon cycling (polyphenol oxidase, invertase and cellulase), with a corresponding decrease in percent sediment organic carbon (SOC), suggesting that nutrients primed microorganism and stimulated SOC remineralization. Surpisingly, however, the relative contribution of seagrass-derived carbon to bacteria (δ 13 C bacteria ) increased with nutrient loading, despite popular theory being that microbes switch to consuming macroalgae which are assumed to provide a more labile carbon source. Organic carbon sources of fungi were unaffected by nutrient loading. Overall, this study suggests that nutrient loading changes the relative contribution of seagrass and algal sources to SOC pools, boosting sediment microbial biomass and extracellular enzyme activity, thereby possibly changing seagrass blue carbon. Copyright © 2017 Elsevier Ltd. All rights reserved.

Nutrient and sediment concentrations and loads in the Steele Bayou Basin, northwestern Mississippi, 2010–14

USGS Publications Warehouse

Hicks, Matthew B.; Murphy, Jennifer C.; Stocks, Shane J.

2017-06-01

The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers-Vicksburg District, monitored streamflow, water quality, and sediment at two stations on the Steele Bayou in northwestern Mississippi from October 2010 through September 2014 to characterize nutrient and sediment concentrations and loads in areas where substantial implementation of conservation efforts have been implemented. The motivation for this effort was to quantify improvements, or lack thereof, in water quality in the Steele Bayou watershed as a result of implementing large- and small-scale best-management practices aimed at reducing nutrient and sediment concentrations and loads. The results of this study document the hydrologic, water-quality, and sedimentation status of these basins following over two decades of ongoing implementation of conservation practices.Results from this study indicate the two Steele Bayou stations have comparable loads and yields of total nitrogen, phosphorus, and suspended sediment when compared to other agricultural basins in the southeastern and central United States. However, nitrate plus nitrite yields from basins in the Mississippi River alluvial plain, including the Steele Bayou Basin, are generally lower than other agricultural basins in the southeastern and central United States.Seasonal variation in nutrient and sediment loads was observed at both stations and for most constituents. About 50 percent of the total annual nutrient and sediment load was observed during the spring (February through May) and between 25 and 50 percent was observed during late fall and winter (October through January). These seasonal patterns probably reflect a combination of seasonal patterns in precipitation, runoff, streamflow, and in the timing of fertilizer application.Median concentrations of total nitrogen, nitrate plus nitrite, total phosphorus, orthophosphate, and suspended sediment were slightly higher at the upstream station, Steele Bayou near Glen Allan, than at the downstream station, Steele Bayou at Grace Road at Hopedale, MS, although the differences typically were not statistically significant. Mean annual loads of nitrate plus nitrite and suspended sediment were also larger at the upstream station, although the annual loads at both stations were generally within the 95-percent confidence intervals of each other.

Sources and transport of algae and nutrients in a Californian river in a semi-arid climate

USGS Publications Warehouse

Ohte, N.; Dahlgren, R.A.; Silva, S.R.; Kendall, C.; Kratzer, C.R.; Doctor, D.H.

2007-01-01

1. To elucidate factors contributing to dissolved oxygen (DO) depletion in the Stockton Deep Water Ship Channel in the lower San Joaquin River, spatial and temporal changes in algae and nutrient concentrations were investigated in relation to flow regime under the semiarid climate conditions. 2. Chlorophyll-a (chl-a) concentration and loads indicated that most algal biomass was generated by in-stream growth in the main stem of the river. The addition of algae from tributaries and drains was small (c.15% of total chl-a load), even though high concentrations of chl-a were measured in some source waters. 3. Nitrate and soluble-reactive phosphorus (SRP) were available in excess as a nutrient source for algae. Although nitrate and SRP from upstream tributaries contributed (16.9% of total nitrate load and 10.8% of total SRP load), nutrients derived from agriculture and other sources in the middle and lower river reaches were mostly responsible (20.2% for nitrate and 48.0% for SRP) for maintaining high nitrate and SRP concentrations in the main stem. 4. A reduction in nutrient discharge would attenuate the algal blooms that accelerate DO depletion in the Stockton Deep Water Ship Channel. The N : P ratio, in the main stem suggests that SRP reduction would be a more viable option for algae reduction than nitrogen reduction. 5. Very high algal growth rates in the main stem suggest that reducing the algal seed source in upstream areas would also be an effective strategy. ?? 2007 Blackwell Publishing Ltd.

Modeling the contribution of point sources and non-point sources to Thachin River water pollution.

PubMed

Schaffner, Monika; Bader, Hans-Peter; Scheidegger, Ruth

2009-08-15

Major rivers in developing and emerging countries suffer increasingly of severe degradation of water quality. The current study uses a mathematical Material Flow Analysis (MMFA) as a complementary approach to address the degradation of river water quality due to nutrient pollution in the Thachin River Basin in Central Thailand. This paper gives an overview of the origins and flow paths of the various point- and non-point pollution sources in the Thachin River Basin (in terms of nitrogen and phosphorus) and quantifies their relative importance within the system. The key parameters influencing the main nutrient flows are determined and possible mitigation measures discussed. The results show that aquaculture (as a point source) and rice farming (as a non-point source) are the key nutrient sources in the Thachin River Basin. Other point sources such as pig farms, households and industries, which were previously cited as the most relevant pollution sources in terms of organic pollution, play less significant roles in comparison. This order of importance shifts when considering the model results for the provincial level. Crosschecks with secondary data and field studies confirm the plausibility of our simulations. Specific nutrient loads for the pollution sources are derived; these can be used for a first broad quantification of nutrient pollution in comparable river basins. Based on an identification of the sensitive model parameters, possible mitigation scenarios are determined and their potential to reduce the nutrient load evaluated. A comparison of simulated nutrient loads with measured nutrient concentrations shows that nutrient retention in the river system may be significant. Sedimentation in the slow flowing surface water network as well as nitrogen emission to the air from the warm oxygen deficient waters are certainly partly responsible, but also wetlands along the river banks could play an important role as nutrient sinks.

Estimation of Shallow Groundwater Discharge and Nutrient Load into a River

Treesearch

Ying Ouyang

2012-01-01

Pollution of rivers with excess nutrients due to groundwater discharge, storm water runoff, surface loading,and atmospheric deposition is an increasing environmental concern worldwide. While the storm water runoff and surface loading of nutrients into many rivers have been explored in great detailed, the groundwater discharge of nutrients into the rivers has not yet...

Impact of simulated atmospheric nitrogen deposition on nutrient cycling and carbon sink via mycorrhizal fungi in two nutrient-poor peatlands

NASA Astrophysics Data System (ADS)

Larmola, Tuula; Kiheri, Heikki; Bubier, Jill L.; van Dijk, Netty; Dise, Nancy; Fritze, Hannu; Hobbie, Erik A.; Juutinen, Sari; Laiho, Raija; Moore, Tim R.; Pennanen, Taina

2017-04-01

Peatlands store one third of the global soil carbon (C) pool. Long-term fertilization experiments in nutrient-poor peatlands showed that simulated atmospheric nitrogen (N) deposition does not enhance ecosystem C uptake but reduces C sink potential. Recent studies have shown that a significant proportion of C input to soil in low-fertility forests entered the soil through mycorrhizal fungi, rather than as plant litter. Is atmospheric N deposition diminishing peatland C sink potential due to the suppression of ericoid mycorrhizal fungi? We studied how nutrient addition influences plant biomass allocation and the extent to which plants rely on mycorrhizal N uptake at two of the longest-running nutrient addition experiments on peatlands, Whim Bog, United Kingdom, and Mer Bleue Bog, Canada. We determined the peak growing season aboveground biomass production and coverage of vascular plants using the point intercept method. We also analyzed isotopic δ15N patterns and nutrient contents in leaves of dominant ericoid mycorrhizal shrubs as well as the non-mycorrhizal sedge Eriophorum vaginatum under different nutrient addition treatments. The treatments receive an additional load of 1.6-6.4 N g m-2 y-1 either as ammonium (NH4) nitrate (NO3) or NH4NO3 and with or without phosphorus (P) and potassium (K), alongside unfertilized controls. After 11-16 years of nutrient addition, the vegetation structure had changed remarkably. Ten of the eleven nutrient addition treatments showed an increase of up to 60% in total vascular plant abundance. Only three (NH4Cl, NH4ClPK, NaNO3PK) of the nutrient addition treatments showed a concurrent decrease of down to 50% in the relative proportion of ericoid mycorrhizal shrubs to total vascular plant abundance. The response to nutrient load may be explained by the water table depth, the form of N added and whether N was added with PK. Shrubs were strong competitors at the dry Mer Bleue bog while sedges gained in abundance at the wetter Whim bog. Our results also suggest that the impacts of reduced and oxidized N on above ground biomass of ericoid shrubs differ and that plants have become increasingly P limited under high simulated atmospheric N deposition. Combined with mycorrhizal abundance and foliar isotopic δ15N patterns, the data will allow us to estimate the extent to which plants rely on mycorrhizal N uptake and whether mycorrhizal responses are linked to diminished C sink potential. This evidence is needed to establish critical loads for C sink potential in peatlands.

Overfishing and nutrient pollution interact with temperature to disrupt coral reefs down to microbial scales.

PubMed

Zaneveld, Jesse R; Burkepile, Deron E; Shantz, Andrew A; Pritchard, Catharine E; McMinds, Ryan; Payet, Jérôme P; Welsh, Rory; Correa, Adrienne M S; Lemoine, Nathan P; Rosales, Stephanie; Fuchs, Corinne; Maynard, Jeffrey A; Thurber, Rebecca Vega

2016-06-07

Losses of corals worldwide emphasize the need to understand what drives reef decline. Stressors such as overfishing and nutrient pollution may reduce resilience of coral reefs by increasing coral-algal competition and reducing coral recruitment, growth and survivorship. Such effects may themselves develop via several mechanisms, including disruption of coral microbiomes. Here we report the results of a 3-year field experiment simulating overfishing and nutrient pollution. These stressors increase turf and macroalgal cover, destabilizing microbiomes, elevating putative pathogen loads, increasing disease more than twofold and increasing mortality up to eightfold. Above-average temperatures exacerbate these effects, further disrupting microbiomes of unhealthy corals and concentrating 80% of mortality in the warmest seasons. Surprisingly, nutrients also increase bacterial opportunism and mortality in corals bitten by parrotfish, turning normal trophic interactions deadly for corals. Thus, overfishing and nutrient pollution impact reefs down to microbial scales, killing corals by sensitizing them to predation, above-average temperatures and bacterial opportunism.

Overfishing and nutrient pollution interact with temperature to disrupt coral reefs down to microbial scales

PubMed Central

Zaneveld, Jesse R.; Burkepile, Deron E.; Shantz, Andrew A.; Pritchard, Catharine E.; McMinds, Ryan; Payet, Jérôme P.; Welsh, Rory; Correa, Adrienne M. S.; Lemoine, Nathan P.; Rosales, Stephanie; Fuchs, Corinne; Maynard, Jeffrey A.; Thurber, Rebecca Vega

2016-01-01

Losses of corals worldwide emphasize the need to understand what drives reef decline. Stressors such as overfishing and nutrient pollution may reduce resilience of coral reefs by increasing coral–algal competition and reducing coral recruitment, growth and survivorship. Such effects may themselves develop via several mechanisms, including disruption of coral microbiomes. Here we report the results of a 3-year field experiment simulating overfishing and nutrient pollution. These stressors increase turf and macroalgal cover, destabilizing microbiomes, elevating putative pathogen loads, increasing disease more than twofold and increasing mortality up to eightfold. Above-average temperatures exacerbate these effects, further disrupting microbiomes of unhealthy corals and concentrating 80% of mortality in the warmest seasons. Surprisingly, nutrients also increase bacterial opportunism and mortality in corals bitten by parrotfish, turning normal trophic interactions deadly for corals. Thus, overfishing and nutrient pollution impact reefs down to microbial scales, killing corals by sensitizing them to predation, above-average temperatures and bacterial opportunism. PMID:27270557

Numerical simulations of river discharges, nutrient flux and nutrient dispersal in Jakarta Bay, Indonesia.

PubMed

van der Wulp, Simon A; Damar, Ario; Ladwig, Norbert; Hesse, Karl-J

2016-09-30

The present application of numerical modelling techniques provides an overview of river discharges, nutrient flux and nutrient dispersal in Jakarta Bay. A hydrological model simulated river discharges with a total of 90 to 377m(3)s(-1) entering Jakarta Bay. Daily total nitrogen and total phosphorus loads ranged from 40 to 174tons and 14 to 60tons, respectively. Flow model results indicate that nutrient gradients are subject to turbulent mixing by tides and advective transport through circulation driven by wind, barotropic and baroclinic pressure gradients. The bulk of nutrient loads originate from the Citarum and Cisadane rivers flowing through predominantly rural areas. Despite lower nutrient loads, river discharges from the urban area of Jakarta exhibit the highest impact of nutrient concentrations in the near shore area of Jakarta Bay and show that nutrient concentrations were not only regulated by nutrient loads but were strongly regulated by initial river concentrations and local flow characteristics. Copyright © 2016 Elsevier Ltd. All rights reserved.

It Takes Two to Tango: When and Where Dual Nutrient (N & P) Reductions Are Needed to Protect Lakes and Downstream Ecosystems.

PubMed

Paerl, Hans W; Scott, J Thad; McCarthy, Mark J; Newell, Silvia E; Gardner, Wayne S; Havens, Karl E; Hoffman, Daniel K; Wilhelm, Steven W; Wurtsbaugh, Wayne A

2016-10-06

Preventing harmful algal blooms (HABs) is needed to protect lakes and downstream ecosystems. Traditionally, reducing phosphorus (P) inputs was the prescribed solution for lakes, based on the assumption that P universally limits HAB formation. Reduction of P inputs has decreased HABs in many lakes, but was not successful in others. Thus, the "P-only" paradigm is overgeneralized. Whole-lake experiments indicate that HABs are often stimulated more by combined P and nitrogen (N) enrichment rather than N or P alone, indicating that the dynamics of both nutrients are important for HAB control. The changing paradigm from P-only to consideration of dual nutrient control is supported by studies indicating that (1) biological N fixation cannot always meet lake ecosystem N needs, and (2) that anthropogenic N and P loading has increased dramatically in recent decades. Sediment P accumulation supports long-term internal loading, while N may escape via denitrification, leading to perpetual N deficits. Hence, controlling both N and P inputs will help control HABs in some lakes and also reduce N export to downstream N-sensitive ecosystems. Managers should consider whether balanced control of N and P will most effectively reduce HABs along the freshwater-marine continuum.

Contribution of Wastewater Treatment Plant Effluents to Nutrient Dynamics in Aquatic Systems: A Review

NASA Astrophysics Data System (ADS)

Carey, Richard O.; Migliaccio, Kati W.

2009-08-01

Excessive nutrient loading (considering nitrogen and phosphorus) is a major ongoing threat to water quality and here we review the impact of nutrient discharges from wastewater treatment plants (WWTPs) to United States (U.S.) freshwater systems. While urban and agricultural land uses are significant nonpoint nutrient contributors, effluent from point sources such as WWTPs can overwhelm receiving waters, effectively dominating hydrological characteristics and regulating instream nutrient processes. Population growth, increased wastewater volumes, and sustainability of critical water resources have all been key factors influencing the extent of wastewater treatment. Reducing nutrient concentrations in wastewater is an important aspect of water quality management because excessive nutrient concentrations often prevent water bodies from meeting designated uses. WWTPs employ numerous physical, chemical, and biological methods to improve effluent water quality but nutrient removal requires advanced treatment and infrastructure that may be economically prohibitive. Therefore, effluent nutrient concentrations vary depending on the particular processes used to treat influent wastewater. Increasingly stringent regulations regarding nutrient concentrations in discharged effluent, along with greater freshwater demand in populous areas, have led to the development of extensive water recycling programs within many U.S. regions. Reuse programs provide an opportunity to reduce or eliminate direct nutrient discharges to receiving waters while allowing for the beneficial use of reclaimed water. However, nutrients in reclaimed water can still be a concern for reuse applications, such as agricultural and landscape irrigation.

Quality of water and bottom sediments, and nutrient and dissolved-solids loads in the Apopka-Beauclair Canal, Lake County, Florida, 1986-90

USGS Publications Warehouse

Schiffer, D.M.

1994-01-01

Nutrient-rich water enters Lake Beauclair and other lakes downstream from Lake Apopka in the Ocklawaha River chain of lakes in central Florida. Two sources of the nutrient-rich water are Lake Apopka outflow and drainage from farming operations adjacent to the Apopka-Beauclair Canal. Two flow and water- quality monitoring sites were established to measure nutrient and dissolved-solids loads at the outflow from lake Apopka and at a control structure on the Apopka-Beauclair Canal downstream from farming activities. Samples were collected biweekly for analysis of nutrients and monthly for analysis of major ions for 4 years. Most of the nutrient load transported through the lock and dam on the Apopka-Beauclair Canal was transported during periods of high discharge. In April 1987, when discharges were as high as 589 cubic feet per second, loads transported through the lock and dam accounted for 59 percent of the ammonia-plus- organic nitrogen load, 61 percent of the total nitrogen load, and 59 percent of the phosphorus load transported during the 1987 water year. Constituent concentrations in annual bottom sediment samples from the canal indicated that most of the constituent load is not being transported down- stream. An alternative approach was derived for determining the relative constituent load from farm input along the canal: Load computations using this approach indicated that, with the exception of phosphorus, nutrient and dissolved-solids loads due to farm activity along the canal account for 10 percent or less of the total load at the Apopka-Beauclair canal lock and dam. (USGS)

Early warning indicators for river nutrient and sediment loads in tropical seagrass beds: a benchmark from a near-pristine archipelago in Indonesia.

PubMed

van Katwijk, M M; van der Welle, M E W; Lucassen, E C H E T; Vonk, J A; Christianen, M J A; Kiswara, W; al Hakim, I Inayat; Arifin, A; Bouma, T J; Roelofs, J G M; Lamers, L P M

2011-07-01

In remote, tropical areas human influences increase, potentially threatening pristine seagrass systems. We aim (i) to provide a bench-mark for a near-pristine seagrass system in an archipelago in East Kalimantan, by quantifying a large spectrum of abiotic and biotic properties in seagrass meadows and (ii) to identify early warning indicators for river sediment and nutrient loading, by comparing the seagrass meadow properties over a gradient with varying river influence. Abiotic properties of water column, pore water and sediment were less suitable indicators for increased sediment and nutrient loading than seagrass properties. Seagrass meadows strongly responded to higher sediment and nutrient loads and proximity to the coast by decreasing seagrass cover, standing stock, number of seagrass species, changing species composition and shifts in tissue contents. Our study confirms that nutrient loads are more important than water nutrient concentrations. We identify seagrass system variables that are suitable indicators for sediment and nutrient loading, also in rapid survey scenarios with once-only measurements. Copyright © 2011 Elsevier Ltd. All rights reserved.

High-frequency phosphorus and nitrate measurements for improved statutory water quality monitoring and management

NASA Astrophysics Data System (ADS)

Bieroza, Magdalena

2017-04-01

High-frequency nutrient (phosphorus and nitrogen) monitoring using wet-chemistry analysers and optical sensors has revolutionised the collection of biogeochemical data from streams, rivers and lakes. Matching the nutrient measurement time with timescales of hydrological responses has revealed biogeochemical patterns and nutrient hydrological responses not observed previously. Capturing a wider range of nutrient concentrations compared to traditional coarse resolution sampling enables more accurate estimation of mean concentrations and loads and thus improved water body classification. However, to date the scientific insights from the high-frequency nutrient monitoring studies have not been translated into policy and operational responses. The pertinent question is where and how often to measure nutrients to satisfy statutory monitoring requirements for the Water Framework Directive and the Nitrates Directive. Therefore this paper discusses how the reduced data uncertainty and improved process understanding obtained with the high-frequency measurements can improve statutory nutrient monitoring, using case studies from England and Sweden.

Characterization and Placement of Wetlands for Integrated ...

EPA Pesticide Factsheets

Constructed wetlands have been recognized as an efficient and cost-effective conservation practice to protect water quality through reducing the transport of sediments and nutrients from upstream croplands to downstream water bodies. The challenge resides in targeting the strategic location of wetlands within agricultural watersheds to maximize the reduction in nutrient loads while minimizing their impact on crop production. Furthermore, agricultural watersheds involve complex interrelated processes requiring a systems approach to evaluate the inherent relationships between wetlands and multiple sediment/nutrient sources (sheet, rill, ephemeral gully, channels) and other conservation practices (filter strips). This study describes new capabilities of the USDA’s Annualized Agricultural Non-Point Source pollutant loading model, AnnAGNPS. A developed AnnAGNPS GIS-based wetland component, AgWet, is introduced to identify potential sites and characterize individual artificial or natural wetlands at a watershed scale. AgWet provides a simplified, semi-automated, and spatially distributed approach to quantitatively evaluate wetlands as potential conservation management alternatives. AgWet is integrated with other AnnAGNPS components providing seamless capabilities of estimating the potential sediment/nutrient reduction of individual wetlands. This technology provides conservationists the capability for improved management of watershed systems and support for nutrient

Influence of Three Permeable Pavement Surfaces on Nitrogen Treatment

EPA Science Inventory

Nitrogen is a stressor of concern in many nutrient sensitive watersheds often associated with algal blooms and resulting fish kills. Communities are increasingly installing green infrastructure stormwater control measures (SCMs) to reduce pollutant loads associated with stormwat...

Context-dependency in the effects of nutrient loading and consumers on the availability of space in marine rocky environments.

PubMed

Bulleri, Fabio; Russell, Bayden D; Connell, Sean D

2012-01-01

Enhanced nutrient loading and depletion of consumer populations interact to alter the structure of aquatic plant communities. Nonetheless, variation between adjacent habitats in the relative strength of bottom-up (i.e. nutrients) versus top-down (i.e. grazing) forces as determinants of community structure across broad spatial scales remains unexplored. We experimentally assessed the importance of grazing pressure and nutrient availability on the development of macroalgal assemblages and the maintenance of unoccupied space in habitats differing in physical conditions (i.e. intertidal versus subtidal), across regions of contrasting productivity (oligotrophic coasts of South Australia versus the more productive coasts of Eastern Australia). In Eastern Australia, grazers were effective in maintaining space free of macroalgae in both intertidal and subtidal habitats, irrespective of nutrient levels. Conversely, in South Australia, grazers could not prevent colonization of space by turf-forming macroalgae in subtidal habitats regardless of nutrients levels, yet in intertidal habitats removal of grazers reduced unoccupied space when nutrients were elevated. Assessing the effects of eutrophication in coastal waters requires balancing our understanding between local consumer pressure and background oceanographic conditions that affect productivity. This broader-based understanding may assist in reconciling disproportionately large local-scale variation, a characteristic of ecology, with regional scale processes that are often of greater relevance to policy making and tractability to management.

Root cortical aerenchyma inhibits radial nutrient transport in maize (Zea mays).

PubMed

Hu, Bo; Henry, Amelia; Brown, Kathleen M; Lynch, Jonathan P

2014-01-01

Formation of root cortical aerenchyma (RCA) can be induced by nutrient deficiency. In species adapted to aerobic soil conditions, this response is adaptive by reducing root maintenance requirements, thereby permitting greater soil exploration. One trade-off of RCA formation may be reduced radial transport of nutrients due to reduction in living cortical tissue. To test this hypothesis, radial nutrient transport in intact roots of maize (Zea mays) was investigated in two radiolabelling experiments employing genotypes with contrasting RCA. In the first experiment, time-course dynamics of phosphate loading into the xylem were measured from excised nodal roots that varied in RCA formation. In the second experiment, uptake of phosphate, calcium and sulphate was measured in seminal roots of intact young plants in which variation in RCA was induced by treatments altering ethylene action or genetic differences. In each of three paired genotype comparisons, the rate of phosphate exudation of high-RCA genotypes was significantly less than that of low-RCA genotypes. In the second experiment, radial nutrient transport of phosphate and calcium was negatively correlated with the extent of RCA for some genotypes. The results support the hypothesis that RCA can reduce radial transport of some nutrients in some genotypes, which could be an important trade-off of this trait.

Using high-frequency sensors to identify hydroclimatological controls on storm-event variability in catchment nutrient fluxes and source zone activation

NASA Astrophysics Data System (ADS)

Blaen, Phillip; Khamis, Kieran; Lloyd, Charlotte; Krause, Stefan

2017-04-01

At the river catchment scale, storm events can drive highly variable behaviour in nutrient and water fluxes, yet short-term dynamics are frequently missed by low resolution sampling regimes. In addition, nutrient source contributions can vary significantly within and between storm events. Our inability to identify and characterise time dynamic source zone contributions severely hampers the adequate design of land use management practices in order to control nutrient exports from agricultural landscapes. Here, we utilise an 8-month high-frequency (hourly) time series of streamflow, nitrate concentration (NO3) and fluorescent dissolved organic matter concentration (FDOM) derived from optical in-situ sensors located in a headwater agricultural catchment. We characterised variability in flow and nutrient dynamics across 29 storm events. Storm events represented 31% of the time series and contributed disproportionately to nutrient loads (43% of NO3 and 36% of CDOM) relative to their duration. Principal components analysis of potential hydroclimatological controls on nutrient fluxes demonstrated that a small number of components, representing >90% of variance in the dataset, were highly significant model predictors of inter-event variability in catchment nutrient export. Hysteresis analysis of nutrient concentration-discharge relationships suggested spatially discrete source zones existed for NO3 and FDOM, and that activation of these zones varied on an event-specific basis. Our results highlight the benefits of high-frequency in-situ monitoring for characterising complex short-term nutrient dynamics and unravelling connections between hydroclimatological variability and river nutrient export and source zone activation under extreme flow conditions. These new process-based insights are fundamental to underpinning the development of targeted management measures to reduce nutrient loading of surface waters.

Land Cover - Nutrient Export Relationships in Space and Time

EPA Science Inventory

The relationship between watershed land-cover composition and nutrient export has been well established through several meta-analyses. The meta-analyses reveal that nutrient loads from watersheds dominated by natural vegetation tend to be lower than nutrient loads from watershed...

Nutrient load estimates for Manila Bay, Philippines using population data

NASA Astrophysics Data System (ADS)

Sotto, Lara Patricia A.; Beusen, Arthur H. W.; Villanoy, Cesar L.; Bouwman, Lex F.; Jacinto, Gil S.

2015-06-01

A major source of nutrient load to periodically hypoxic Manila Bay is the urban nutrient waste water flow from humans and industries to surface water. In Manila alone, the population density is as high as 19,137 people/km2. A model based on a global point source model by Morée et al. (2013) was used to estimate the contribution of the population to nitrogen and phosphorus emissions which was then used in a water transport model to estimate the nitrogen (N) and phosphorus (P) loads to Manila Bay. Seven scenarios for 2050 were tested, with varying degrees and amounts for extent of sewage treatment, and population growth rates were also included. In scenario 1, the sewage connection and treatment remains the same as 2010; in scenario 2, sewage connection is improved but the treatment is the same; in scenario 3, the sewage connection as well as treatment is improved (70% tertiary); and in scenario 4, a more realistic situation of 70% primary treatment achieved with 100% connection to pipes is tested. Scenarios 5, 6, and 7 have the same parameters as 1, 2, and 3 respectively, but with the population growth rate per province reduced to half of what was used in 1, 2, and 3. In all scenarios, a significant increase in N and P loads was observed (varying from 27% to 469% relative to 2010 values). This was found even in scenario 3 where 70% of the waste water undergoes tertiary treatment which removes 80% N and 90% P. However, the lowest increase in N and P load into the bay was achieved in scenarios 5 to 7 where population growth rate is reduced to half of 2010 values. The results suggest that aside from improving sewage treatment, the continued increase of the human population in Manila at current growth rates will be an important determinant of N and P load into Manila Bay.

Effects of internal phosphorus loadings and food-web structure on the recovery of a deep lake from eutrophication

USGS Publications Warehouse

Lepori, Fabio; Roberts, James J.

2017-01-01

We used monitoring data from Lake Lugano (Switzerland and Italy) to assess key ecosystem responses to three decades of nutrient management (1983–2014). We investigated whether reductions in external phosphorus loadings (Lext) caused declines in lake phosphorus concentrations (P) and phytoplankton biomass (Chl a), as assumed by the predictive models that underpinned the management plan. Additionally, we examined the hypothesis that deep lakes respond quickly to Lext reductions. During the study period, nutrient management reduced Lext by approximately a half. However, the effects of such reduction on P and Chl a were complex. Far from the scenarios predicted by classic nutrient-management approaches, the responses of P and Chl a did not only reflect changes in Lext, but also variation in internal P loadings (Lint) and food-web structure. In turn, Lint varied depending on basin morphometry and climatic effects, whereas food-web structure varied due to apparently stochastic events of colonization and near-extinction of key species. Our results highlight the complexity of the trajectory of deep-lake ecosystems undergoing nutrient management. From an applied standpoint, they also suggest that [i] the recovery of warm monomictic lakes may be slower than expected due to the development of Lint, and that [ii] classic P and Chl a models based on Lext may be useful in nutrient management programs only if their predictions are used as starting points within adaptive frameworks.

THE COMPARISON OF TWO WATERSHEDS USING A WATERSHED NUTRIENT LOADING MODEL

EPA Science Inventory

Monitoring data, collected from the Yaquina River, Oregon, from 1999 through 2002 were used as the basis for developing the nutrient flux model as part of a larger agency program for quantifying nutrient processes. The PNWL nitrate loading model indicates that the nitrate load is...

EVALUATION OF SAMPLING FREQUENCIES REQUIRED TO ESTIMATE NUTRIENT AND SUSPENDED SEDIMENT LOADS IN LARGE RIVERS

EPA Science Inventory

Nutrients and suspended sediments in streams and large rivers are two major issues facing state and federal agencies. Accurate estimates of nutrient and sediment loads are needed to assess a variety of important water-quality issues including total maximum daily loads, aquatic ec...

Variable primary producer responses to nutrient and ...

EPA Pesticide Factsheets

Mesocosm experiments have been used to evaluate the impacts of nutrient loading on estuarine plant communities in order to develop nutrient response relationships. Mesocosm eutrophication studies tend to focus on long residence time systems. In the Pacific Northwest, many estuaries have high nutrient loads, short water residence times, seasonal macroalgal blooms, while intertidal seagrass meadows persist under what appear to be largely naturally-derived eutrophic conditions. Using experimental mesocosms, we examined how primary producer communities in rapidly flushed systems respond to a range of temperature (10 and 20 °C) and nutrient loads (ambient, 1.5, 3 and 6 x ambient). Thermal and nutrient loading regimes were maintained for three sets of 3 week-duration experiments during the summer of 2013. Statistical analysis was performed using an information criterion approach to evaluate the best fit model. Green macroalgal (GMA) growth and tissue N increased in response to nutrient loading. Irrespective of nutrient load, GMA at 10 °C remained intercalated among seagrass shoots, but at 20 °C formed floating mats that overtopped seagrass. Outgassing of O2 in combination with photosynthetic O2 production likely induced floating mat formation. No phytoplankton blooms were observed. Zostera japonica leaf biomass and C:N responded to temperature while other metrics exhibited no statistically significant difference. Z. marina growth, wasting disease, and morphological

Nutrient loading and selected water-quality and biological characteristics of Dickinson Bayou near Houston, Texas, 1995-97

USGS Publications Warehouse

East, Jeffery W.; Paul, Edna M.; Porter, Stephen D.

1998-01-01

Algal samples were collected at seven stations and were analyzed for periphyton identification and enumeration, and chlorophyll a and chlorophyll b concentrations. The large relative abundance of soil algae at stations in the middle of the watershed likely indicates the cumulative effects on water quality of agricultural nonpoint sources. Farther downstream near the State Highway 3 bridge, and downstream of three major tributary inflows, the increase in abundance of soil algae to a larger-than-expected level might reflect water-quality influences from predominantly urban nonpoint sources in the drainage basins of the three major tributary inflows. Nutrient concentrations do not appear to limit algal production in the upper (non-tidal) reach of Dickinson Bayou; but nutrient concentrations could have been limiting benthicalgal production in the lower (tidal) reach of the bayou during the time of the synoptic survey. If nitrogen is the limiting resource for algal productivity in the tidal reach of Dickinson Bayou, eutrophication of the system could be (at least partially) mitigated if nonpoint-source nutrient loads into the Bayou were reduced. 

Longitudinal Loading and Nutrient Compositional Gradients in an Agriculturally Managed Watershed in West-Central Wisconsin

DTIC Science & Technology

2004-09-01

i.e., fertilizer and manure subsidies ). Nitrogen. Similar to total P, flow-weighted mean total N concentrations were not significantly different at...often used as a soil nutrient subsidy on corn and is also spread on hayfields after cutting, partly as a means of reducing manure surplus...James, W. F., Kennedy, R. H., and Gaugush, R F. (1990). “ Effects of large-scale metalimnetic migration events of phosphorus dynamics in a north

Management Practices Used in Agricultural Drainage Ditches to Reduce Gulf of Mexico Hypoxia.

PubMed

Faust, Derek R; Kröger, Robert; Moore, Matthew T; Rush, Scott A

2018-01-01

Agricultural non-point sources of nutrients and sediments have caused eutrophication and other water quality issues in aquatic and marine ecosystems, such as the annual occurrence of hypoxia in the Gulf of Mexico. Management practices have been implemented adjacent to and in agricultural drainage ditches to promote their wetland characteristics and functions, including reduction of nitrogen, phosphorus, and sediment losses downstream. This review: (1) summarized studies examining changes in nutrient and total suspended solid concentrations and loads associated with management practices in drainage ditches (i.e., riser and slotted pipes, two-stage ditches, vegetated ditches, low-grade weirs, and organic carbon amendments) with emphasis on the Lower Mississippi Alluvial Valley, (2) quantified management system effects on nutrient and total suspended solid concentrations and loads and, (3) identified information gaps regarding water quality associated with these management practices and research needs in this area. In general, management practices used in drainage ditches at times reduced losses of total suspended solids, N, and P. However, management practices were often ineffective during storm events that were uncommon and intense in duration and volume, although these types of events could increase in frequency and intensity with climate change. Studies on combined effects of management practices on drainage ditch water quality, along with research towards improved nutrient and sediment reduction efficiency during intense storm events are urgently needed.

Nutrient and Suspended-Sediment Transport and Trends in the Columbia River and Puget Sound Basins, 1993-2003

USGS Publications Warehouse

Wise, Daniel R.; Rinella, Frank A.; Rinella, Joseph F.; Fuhrer, Greg J.; Embrey, Sandra S.; Clark, Gregory M.; Schwarz, Gregory E.; Sobieszczyk, Steven

2007-01-01

This study focused on three areas that might be of interest to water-quality managers in the Pacific Northwest: (1) annual loads of total nitrogen (TN), total phosphorus (TP) and suspended sediment (SS) transported through the Columbia River and Puget Sound Basins, (2) annual yields of TN, TP, and SS relative to differences in landscape and climatic conditions between subbasin catchments (drainage basins), and (3) trends in TN, TP, and SS concentrations and loads in comparison to changes in landscape and climatic conditions in the catchments. During water year 2000, an average streamflow year in the Pacific Northwest, the Columbia River discharged about 570,000 pounds per day of TN, about 55,000 pounds per day of TP, and about 14,000 tons per day of SS to the Pacific Ocean. The Snake, Yakima, Deschutes, and Willamette Rivers contributed most of the load discharged to the Columbia River. Point-source nutrient loads to the catchments (almost exclusively from municipal wastewater treatment plants) generally were a small percentage of the total in-stream nutrient loads; however, in some reaches of the Spokane, Boise, Walla Walla, and Willamette River Basins, point sources were responsible for much of the annual in-stream nutrient load. Point-source nutrient loads generally were a small percentage of the total catchment nutrient loads compared to nonpoint sources, except for a few catchments where point-source loads comprised as much as 30 percent of the TN load and as much as 80 percent of the TP load. The annual TN and TP loads from point sources discharging directly to the Puget Sound were about equal to the annual loads from eight major tributaries. Yields of TN, TP, and SS generally were greater in catchments west of the Cascade Range. A multiple linear regression analysis showed that TN yields were significantly (p < 0.05) and positively related to precipitation, atmospheric nitrogen load, fertilizer and manure load, and point-source load, and were negatively related to average slope. TP yields were significantly related positively to precipitation, and point-source load and SS yields were significantly related positively to precipitation. Forty-eight percent of the available monitoring sites for TN had significant trends in concentration (2 increasing, 19 decreasing), 32 percent of the available sites for TP had significant trends in concentration (7 increasing, 9 decreasing), and 40 percent of the available sites for SS had significant trends in concentration (4 increasing, 15 decreasing). The trends in load followed a similar pattern, but with fewer sites showing significant trends. The results from this study indicate that inputs from nonpoint sources of nutrients probably have decreased over time in many of the catchments. Despite the generally small contribution of point-source nutrient loads, they still may have been partially responsible for the significant decreasing trends for nutrients at sites where the total point-source nutrient loads to the catchments equaled a substantial proportion of the in-stream load.

Dual permeability modeling of tile drain management influences on hydrologic and nutrient transport characteristics in macroporous soil

NASA Astrophysics Data System (ADS)

Frey, Steven K.; Hwang, Hyoun-Tae; Park, Young-Jin; Hussain, Syed I.; Gottschall, Natalie; Edwards, Mark; Lapen, David R.

2016-04-01

Tile drainage management is considered a beneficial management practice (BMP) for reducing nutrient loads in surface water. In this study, 2-dimensional dual permeability models were developed to simulate flow and transport following liquid swine manure and rhodamine WT (strongly sorbing) tracer application on macroporous clay loam soils under controlled (CD) and free drainage (FD) tile management. Dominant flow and transport characteristics were successfully replicated, including higher and more continuous tile discharge and lower peak rhodamine WT concentrations in FD tile effluent; in relation to CD, where discharge was intermittent, peak rhodamine concentrations higher, and mass exchange from macropores into the soil matrix greater. Explicit representation of preferential flow was essential, as macropores transmitted >98% of surface infiltration, tile flow, and tile solute loads for both FD and CD. Incorporating an active 3rd type lower boundary condition that facilitated groundwater interaction was imperative for simulating CD, as the higher (relative to FD) water table enhanced water and soluble nutrient movement from the soil profile into deeper groundwater. Scenario analysis revealed that in conditions where slight upwards hydraulic gradients exist beneath tiles, groundwater upwelling can influence the concentration of surface derived solutes in tile effluent under FD conditions; whereas the higher and flatter CD water table can restrict groundwater upwelling. Results show that while CD can reduce tile discharge, it can also lead to an increase in surface-application derived nutrient concentrations in tile effluent and hence surface water receptors, and it can promote NO3 loading into groundwater. This study demonstrates dual permeability modeling as a tool for increasing the conceptual understanding of tile drainage BMPs.

Groundwater nutrient concentrations near an incised midwestern stream: Effects of floodplain lithology and land management

USGS Publications Warehouse

Schilling, K.E.; Jacobson, P.

2008-01-01

It has been recognized that subsurface lithology plays an important role in controlling nutrient cycling and transport in riparian zones. In Iowa and adjacent states, the majority of alluvium preserved in small and moderate sized valleys consists of Holocene-age organic-rich, and fine-grained loam. In this paper, we describe and evaluate spatial and temporal patterns of lithology and groundwater nutrient concentrations at a riparian well transect across Walnut Creek at the Neal Smith National Wildlife Refuge in Jasper County, Iowa. Land treatment on one side of the stream reduced the grass cover to bare ground and allowed assessment of the effects of land management on nutrient concentrations. Results indicated that groundwater in Holocene alluvium is very nutrient rich with background concentrations of nitrogen, phosphorus and dissolved organic carbon that exceed many environmentally sensitive criteria. Average concentrations of ammonium exceeded 1 mg/l in several wells under grass cover whereas nitrate concentrations exceeded 20 mg/l in wells under bare ground. Phosphate concentrations ranged from 0.1 to 1.3 mg/l and DOC concentrations exceeded 5 mg/l in many wells. Denitrification, channel incision, land management and geologic age of alluvium were found to contribute to variable nutrient loading patterns at the site. Study results indicated that riparian zones of incised streams downcutting through nutrient-rich Holocene alluvium can potentially be a significant source of nutrient loadings to streams. ?? 2008 Springer Science+Business Media B.V.

Ocean and Coastal Acidification off New England and Nova Scotia

EPA Science Inventory

New England coastal and adjacent Nova Scotia shelf waters have a reduced buffering capacity because of significant freshwater input, making the region’s waters potentially more vulnerable to coastal acidification. Nutrient loading and heavy precipitation events further acid...

Spatial Characterization of Riparian Buffer Effects on Sediment Loads from Watershed Systems

EPA Science Inventory

Understanding all watershed systems and their interactions is a complex, but critical, undertaking when developing practices designed to reduce topsoil loss and chemical/nutrient transport from agricultural fields. The presence of riparian buffer vegetation in agricultural lands...

Controls on methane concentrations and fluxes in streams draining human-dominated landscapes

USGS Publications Warehouse

Crawford, John T.; Stanley, Emily H.

2016-01-01

Streams and rivers are active processors of carbon, leading to significant emissions of CO2 and possibly CH4 to the atmosphere. Patterns and controls of CH4 in fluvial ecosystems remain relatively poorly understood. Furthermore, little is known regarding how major human impacts to fluvial ecosystems may be transforming their role as CH4 producers and emitters. Here, we examine the consequences of two distinct ecosystem changes as a result of human land use: increased nutrient loading (primarily as nitrate), and increased sediment loading and deposition of fine particles in the benthic zone. We did not find support for the hypothesis that enhanced nitrate loading down-regulates methane production via thermodynamic or toxic effects. We did find strong evidence that increased sedimentation and enhanced organic matter content of the benthos lead to greater methane production (diffusive + ebullitive flux) relative to pristine fluvial systems in northern Wisconsin (upper Midwest, USA). Overall, streams in a human-dominated landscape of southern Wisconsin were major regional sources of CH4 to the atmosphere, equivalent to ~20% of dairy cattle emissions, or ~50% of a landfill’s annual emissions. We suggest that restoration of the benthic environment (reduced fine deposits) could lead to reduced CH4 emissions, while decreasing nutrient loading is likely to have limited impacts to this ecosystem process.

Coastal hypoxia responses to remediation

NASA Astrophysics Data System (ADS)

Kemp, W. M.; Testa, J. M.; Conley, D. J.; Gilbert, D.; Hagy, J. D.

2009-07-01

The incidence and intensity of hypoxic waters in coastal aquatic ecosystems has been expanding in recent decades coincident with eutrophication of the coastal zone. Because of the negative effects hypoxia has on many organisms, extensive efforts have been made to reduce the size and duration of hypoxia in many coastal waters. Although it has been broadly assumed that reductions in nutrient loading rates would reverse eutrophication and consequently, hypoxia, recent analyses of historical data from European and North American coastal systems suggest little evidence for simple linear response trajectories. We review existing data, analyses, and models that relate variations in the extent and intensity of hypoxia to changes in loading rates for inorganic nutrients and labile organic matter. We also assess existing knowledge of physical and ecological factors regulating oxygen in coastal marine waters and examine a broad range of examples where hypoxia responses to reductions in nutrient (or organic matter) inputs have been documented. Of the 22 systems identified where concurrent time series of loading and O2 were available, half displayed relatively clear and direct recoveries following remediation. We explored in detail 5 well-studied systems that have exhibited complex, non-linear responses to loading, including apparent "regime shifts." A summary of these analyses suggests that O2 conditions improved rapidly and linearly in systems where remediation focused on organic inputs from sewage plants, which were the primary drivers of hypoxia. In larger more open systems where diffuse nutrient loads are more important in fueling O2 depletion and where climatic influences are pronounced, responses to remediation tend to follow non-linear trends that may include hysteresis and time-lags. Improved understanding of hypoxia remediation requires that future studies use comparative approaches and consider multiple regulating factors including: (1) the dominant temporal scales of the hypoxia, (2) the relative contributions of inorganic and organic nutrients, (3) the influence of shifts in climatic and oceanographic processes, and (4) the roles of feedback interactions whereby O2-sensitive biogeochemistry, food-webs, and habitats influence the nutrient and algal dynamics that regulate O2 levels.

Physiological responses of the seagrass Thalassia hemprichii (Ehrenb.) Aschers as indicators of nutrient loading.

PubMed

Zhang, Jingping; Huang, Xiaoping; Jiang, Zhijian

2014-06-30

To select appropriate bioindicators for the evaluation of the influence of nutrients from human activities in a Thalassia hemprichii meadow, environmental variables and plant performance parameters were measured in Xincun Bay, Hainan Island, South China. Nutrient concentrations in the bay decreased along a gradient from west to southeast. Moreover, the nutrients decreased with an increase in the distance from the shore on the southern side of the bay. Among the candidate indicators, the P content of the tissues closely mirrored the two nutrient loading gradients. The epiphytic algae biomass and the N content in the tissues mirrored one of the two nutrient loading trends. The leaf length, however, exhibited a significant negative correlation with the nutrient gradients. We propose that changes in the P content of T. hemprichii, followed by epiphytic algae biomass and N content of the tissues, may be the useful indicators of nutrient loading to coastal ecosystems. Copyright © 2014 Elsevier Ltd. All rights reserved.

Comparison of two methods for estimating discharge and nutrient loads from Tidally affected reaches of the Myakka and Peace Rivers, West-Central Florida

USGS Publications Warehouse

Levesque, V.A.; Hammett, K.M.

1997-01-01

The Myakka and Peace River Basins constitute more than 60 percent of the total inflow area and contribute more than half the total tributary inflow to the Charlotte Harbor estuarine system. Water discharge and nutrient enrichment have been identified as significant concerns in the estuary, and consequently, it is important to accurately estimate the magnitude of discharges and nutrient loads transported by inflows from both rivers. Two methods for estimating discharge and nutrient loads from tidally affected reaches of the Myakka and Peace Rivers were compared. The first method was a tidal-estimation method, in which discharge and nutrient loads were estimated based on stage, water-velocity, discharge, and water-quality data collected near the mouths of the rivers. The second method was a traditional basin-ratio method in which discharge and nutrient loads at the mouths were estimated from discharge and loads measured at upstream stations. Stage and water-velocity data were collected near the river mouths by submersible instruments, deployed in situ, and discharge measurements were made with an acoustic Doppler current profiler. The data collected near the mouths of the Myakka River and Peace River were filtered, using a low-pass filter, to remove daily mixed-tide effects with periods less than about 2 days. The filtered data from near the river mouths were used to calculate daily mean discharge and nutrient loads. These tidal-estimation-method values were then compared to the basin-ratio-method values. Four separate 30-day periods of differing streamflow conditions were chosen for monitoring and comparison. Discharge and nutrient load estimates computed from the tidal-estimation and basin-ratio methods were most similar during high-flow periods. However, during high flow, the values computed from the tidal-estimation method for the Myakka and Peace Rivers were consistently lower than the values computed from the basin-ratio method. There were substantial differences between discharges and nutrient loads computed from the tidal-estimation and basin-ratio methods during low-flow periods. Furthermore, the differences between the methods were not consistent. Discharges and nutrient loads computed from the tidal-estimation method for the Myakka River were higher than those computed from the basin-ratio method, whereas discharges and nutrients loads computed by the tidal-estimation method for the Peace River were not only lower than those computed from the basin-ratio method, but they actually reflected a negative, or upstream, net movement. Short-term tidal measurement results should be used with caution, because antecedent conditions can influence the discharge and nutrient loads. Continuous tidal data collected over a 1- or 2-year period would be necessary to more accurately estimate the tidally affected discharge and nutrient loads for the Myakka and Peace River Basins.

Hardening fertilization and nutrient loading of conifer seedlings

Treesearch

R. Kasten Dumroese

2003-01-01

Continuing to fertilize bareroot and container seedlings during the hardening process (from cessation of height growth until lifting) can improve seedling viability. The process of fertilizing during hardening has many names, but in the last decade a new term, nutrient loading, has come into use. The process of nutrient loading seedlings leads to luxury consumption...

Uncertainty in nutrient loads from tile drained landscapes: Effect of sampling frequency, calculation algorithm, and compositing strategies

USDA-ARS?s Scientific Manuscript database

Accurate estimates of annual nutrient loads are required to evaluate trends in water quality following changes in land use or management and to calibrate and validate water quality models. While much emphasis has been placed on understanding the uncertainty of watershed-scale nutrient load estimates...

Saving the Baltic Sea, the inland waters of its drainage basin, or both? spatial perspectives on reducing P-loads in eastern Sweden.

PubMed

Andersson, Ingela; Jarsjö, Jerker; Petersson, Mona

2014-11-01

Nutrient loads from inland sources to the Baltic Sea and adjacent inland waters need to be reduced in order to prevent eutrophication and meet requirements of the European Water Framework Directive (WFD) and the Baltic Sea Action Plan (BSAP). We here investigate the spatial implications of using different possible criteria for reducing water-borne phosphorous (P) loads in the Northern Baltic Sea River Basin District (NBS-RBD) in Sweden. Results show that most catchments that have a high degree of internal eutrophication do not express high export of P from their outlets. Furthermore, due to lake retention, lake catchments with high P-loads per agricultural area (which is potentially of concern for the WFD) did not considerably contribute to the P-loading of the Baltic Sea. Spatially uniform water quality goals may, therefore, not be effective in NBS-RBD, emphasizing more generally the need for regional adaptation of WFD and BSAP-related goals.

Characteristics of Nitrogen and Phosphorus Effluent Load from a Paddy-field District Implementing Crop Rotation

NASA Astrophysics Data System (ADS)

Hama, Takehide; Aoki, Takeru; Osuga, Katsuyuki; Nakamura, Kimihito; Sugiyama, Sho; Kawashima, Shigeto

Implementation of collective crop rotation in a paddy-field district may increase nutrients effluent load. We have investigated a paddy-field district implementing collective crop rotation of wheat and soybeans, measured temporal variations in nutrients concentration of drainage water and the amount of discharged water for consecutive three years, and estimated nutrients effluent load from the district during the irrigation and non-irrigation periods. As a result, the highest concentration of nutrients was observed during the non-irrigation period in every investigation year. It was shown that high nutrients concentration of drainage water during the non-irrigation period was caused by runoff of fertilizer applied to wheat because the peaks of nutrients concentration of drainage water were seen in rainy days after fertilizer application in the crop-rotation field. The effluent load during the non-irrigation periods was 16.9-22.1 kgN ha-1 (nitrogen) and 0.84-1.42 kgP ha-1 (phosphorus), which respectively accounted for 46-66% and 27-54% of annual nutrients effluent load.

Impacts of housing development on nutrients flow along canals in a peri-urban area of Bangkok, Thailand.

PubMed

Honda, R; Hara, Y; Sekiyama, M; Hiramatsu, A

2010-01-01

Change of nutrients load and flow according to land-use change induced by housing development was investigated in Bang Yai, Nonthaburi, Thailand, which located in the peri-urban area of Bangkok. Each house in the newly developed residential community was regulated to be equipped with a septic tank to collect night soil. However, greywater and leachate from the septic tank was collected by a community sewage system and discharged into the canals with insufficient treatment, while the canals still function as infrastructure for irrigation and transportation. In the study area, built-up area became 1.4 times and agricultural fields decreased by 13% from 2003 until 2007. Total nutrients load to the canals was increased by 25% as nitrogen and 14% as phosphorus according to the increase of built-up area. Net nutrients load from agricultural fields was largely set off when we evaluated nutrients inflow from the canals to the agricultural field through irrigation. Consequently, nutrients load from domestic wastewater accounted most of net nutrients load into the canal.

A Regional Assessment of the Effects of Conservation Practices on In-stream Water Quality

NASA Astrophysics Data System (ADS)

Garcia, A. M.; Alexander, R. B.; Arnold, J.; Norfleet, L.; Robertson, D. M.; White, M.

2011-12-01

The Conservation Effects Assessment Program (CEAP), initiated by USDA Natural Resources Conservation Service (NRCS), has the goal of quantifying the environmental benefits of agricultural conservation practices. As part of this effort, detailed farmer surveys were compiled to document the adoption of conservation practices. Survey data showed that up to 38 percent of cropland in the Upper Mississippi River basin is managed to reduce sediment, nutrient and pesticide loads from agricultural activities. The broader effects of these practices on downstream water quality are challenging to quantify. The USDA-NRCS recently reported results of a study that combined farmer surveys with process-based models to deduce the effect of conservation practices on sediment and chemical loads in farm runoff and downstream waters. As a follow-up collaboration, USGS and USDA scientists conducted a semi-empirical assessment of the same suite of practices using the USGS SPARROW (SPAtially Referenced Regression On Watershed attributes) modeling framework. SPARROW is a hybrid statistical and mechanistic stream water quality model of annual conditions that has been used extensively in studies of nutrient sources and delivery. In this assessment, the USDA simulations of the effects of conservation practices on loads in farm runoff were used as an explanatory variable (i.e., change in farm loads per unit area) in a component of an existing a SPARROW model of the Upper Midwest. The model was then re-calibrated and tested to determine whether the USDA estimate of conservation adoption intensity explained a statistically significant proportion of the spatial variability in stream nutrient loads in the Upper Mississippi River basin. The results showed that the suite of conservation practices that NRCS has catalogued as complete nutrient and sediment management are a statistically significant feature in the Midwestern landscape associated with phosphorous runoff and delivery to downstream waters. Effects on the delivery of nitrogen will be also be studied. Estimates of the magnitude of this effect using SPARROW indicated that phosphorus load reductions ranged from about 2 - 38% for various spatial scales. This is less than reported by the USDA CEAP simulations, which ranged from 15 - 49%. Nevertheless, the results indicated that conservation practices play a significant role in reducing phosphorus pollution from agricultural activities to downstream receiving water bodies.

Future nutrient load scenarios for the Baltic Sea due to climate and lifestyle changes.

PubMed

Hägg, Hanna Eriksson; Lyon, Steve W; Wällstedt, Teresia; Mörth, Carl-Magnus; Claremar, Björn; Humborg, Christoph

2014-04-01

Dynamic model simulations of the future climate and projections of future lifestyles within the Baltic Sea Drainage Basin (BSDB) were considered in this study to estimate potential trends in future nutrient loads to the Baltic Sea. Total nitrogen and total phosphorus loads were estimated using a simple proxy based only on human population (to account for nutrient sources) and stream discharges (to account for nutrient transport). This population-discharge proxy provided a good estimate for nutrient loads across the seven sub-basins of the BSDB considered. All climate scenarios considered here produced increased nutrient loads to the Baltic Sea over the next 100 years. There was variation between the climate scenarios such that sub-basin and regional differences were seen in future nutrient runoff depending on the climate model and scenario considered. Regardless, the results of this study indicate that changes in lifestyle brought about through shifts in consumption and population potentially overshadow the climate effects on future nutrient runoff for the entire BSDB. Regionally, however, lifestyle changes appear relatively more important in the southern regions of the BSDB while climatic changes appear more important in the northern regions with regards to future increases in nutrient loads. From a whole-ecosystem management perspective of the BSDB, this implies that implementation of improved and targeted management practices can still bring about improved conditions in the Baltic Sea in the face of a warmer and wetter future climate.

Ecological Forecasting: Microbial Contamination and Atmospheric Loadings of Nutrients to Land and Water

EPA Science Inventory

The development of ecological forecasts, namely, methodologies to predict the chemical, biological, and physical changes in terrestrial and aquatic ecosystems is desirable so that effective strategies for reducing the adverse impacts of human activities and extreme natural events...

Data-driven nutrient analysis and reality check: Human inputs, catchment delivery and management effects

NASA Astrophysics Data System (ADS)

Destouni, G.

2017-12-01

Measures for mitigating nutrient loads to aquatic ecosystems should have observable effects, e.g, in the Baltic region after joint first periods of nutrient management actions under the Baltic Sea Action Plan (BASP; since 2007) and the EU Water Framework Directive (WFD; since 2009). Looking for such observable effects, all openly available water and nutrient monitoring data since 2003 are compiled and analyzed for Sweden as a case study. Results show that hydro-climatically driven water discharge dominates the determination of waterborne loads of both phosphorus and nitrogen. Furthermore, the nutrient loads and water discharge are all similarly well correlated with the ecosystem status classification of Swedish water bodies according to the WFD. Nutrient concentrations, which are hydro-climatically correlated and should thus reflect human effects better than loads, have changed only slightly over the study period (2003-2013) and even increased in moderate-to-bad status waters, where the WFD and BSAP jointly target nutrient decreases. These results indicate insufficient distinction and mitigation of human-driven nutrient components by the internationally harmonized applications of both the WFD and the BSAP. Aiming for better general identification of such components, nutrient data for the large transboundary catchments of the Baltic Sea and the Sava River are compared. The comparison shows cross-regional consistency in nutrient relationships to driving hydro-climatic conditions (water discharge) for nutrient loads, and socio-economic conditions (population density and farmland share) for nutrient concentrations. A data-driven screening methodology is further developed for estimating nutrient input and retention-delivery in catchments. Its first application to nested Sava River catchments identifies characteristic regional values of nutrient input per area and relative delivery, and hotspots of much larger inputs, related to urban high-population areas.

Long-term agroecosystem research in the central Mississippi river basin: dissolved nitrogen and phosphorus transport in a high-runoff-potential watershed.

PubMed

Lerch, R N; Baffaut, C; Kitchen, N R; Sadler, E J

2015-01-01

Long-term monitoring data from agricultural watersheds are needed to determine if efforts to reduce nutrient transport from crop and pasture land have been effective. Goodwater Creek Experimental Watershed (GCEW), located in northeastern Missouri, is a high-runoff-potential watershed dominated by claypan soils. The objectives of this study were to: (i) summarize dissolved NH-N, NO-N, and PO-P flow-weighted concentrations (FWC), daily loads, and yields (unit area loads) in GCEW from 1992 to 2010; (ii) assess time trends and relationships between precipitation, land use, and fertilizer inputs and nutrient transport; and (iii) provide context to the GCEW data by comparisons with other Corn Belt watersheds. Significant declines in annual and quarterly FWCs and yields occurred for all three nutrient species during the study, and the decreases were most evident for NO-N. Substantial decreases in first- and fourth-quarter NO-N FWCs and daily loads and modest decreases in first-quarter PO-P daily loads were observed. Declines in NO-N and PO-P transport were attributed to decreased winter wheat ( L.) and increased corn ( L.) production that shifted fertilizer application from fall to spring as well as to improved management, such as increased use of incorporation. Regression models and correlation analyses indicated that precipitation, land use, and fertilizer inputs were critical factors controlling transport. Within the Mississippi River Basin, NO-N yields in GCEW were much lower than in tile-drained areas, but PO-P yields were among the highest in the basin. Overall, results demonstrated that reductions in fall-applied fertilizer and improved fertilizer management reduced N and P transport in GCEW. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Optimal implementation of best management practices to improve agricultural hydrology and water quality

NASA Astrophysics Data System (ADS)

Liu, Y.; Engel, B.; Collingsworth, P.; Pijanowski, B. C.

2017-12-01

Nutrient loading from the Maumee River watershed is a significant reason for the harmful algal blooms (HABs) problem in Lake Erie. Strategies to reduce nutrient loading from agricultural areas in the Maumee River watershed need to be explored. Best management practices (BMPs) are popular approaches for improving hydrology and water quality. Various scenarios of BMP implementation were simulated in the AXL watershed (an agricultural watershed in Maumee River watershed) using Soil and Water Assessment Tool (SWAT) and a new BMP cost tool to explore the cost-effectiveness of the practices. BMPs of interest included vegetative filter strips, grassed waterways, blind inlets, grade stabilization structures, wetlands, no-till, nutrient management, residue management, and cover crops. The following environmental concerns were considered: streamflow, Total Phosphorous (TP), Dissolved Reactive Phosphorus (DRP), Total Kjeldahl Nitrogen (TKN), and Nitrate+Nitrite (NOx). To obtain maximum hydrological and water quality benefits with minimum cost, an optimization tool was developed to optimally select and place BMPs by connecting SWAT, the BMP cost tool, and optimization algorithms. The optimization tool was then applied in AXL watershed to explore optimization focusing on critical areas (top 25% of areas with highest runoff volume/pollutant loads per area) vs. all areas of the watershed, optimization using weather data for spring (March to July, due to the goal of reducing spring phosphorus in watershed management plan) vs. full year, and optimization results of implementing BMPs to achieve the watershed management plan goal (reducing 2008 TP levels by 40%). The optimization tool and BMP optimization results can be used by watershed groups and communities to solve hydrology and water quality problems.

Competition for nutrients and light: testing advances in resource competition with a natural phytoplankton community.

PubMed

Burson, Amanda; Stomp, Maayke; Greenwell, Emma; Grosse, Julia; Huisman, Jef

2018-05-01

A key challenge in ecology is to understand how nutrients and light affect the biodiversity and community structure of phytoplankton and plant communities. According to resource competition models, ratios of limiting nutrients are major determinants of species composition. At high nutrient levels, however, species interactions may shift to competition for light, which might make nutrient ratios less relevant. The "nutrient-load hypothesis" merges these two perspectives, by extending the classic model of competition for two nutrients to include competition for light. Here, we test five key predictions of the nutrient-load hypothesis using multispecies competition experiments. A marine phytoplankton community sampled from the North Sea was inoculated in laboratory chemostats provided with different nitrogen (N) and phosphorus (P) loads to induce either single resource limitation or co-limitation of N, P, and light. Four of the five predictions were validated by the experiments. In particular, different resource limitations favored the dominance of different species. Increasing nutrient loads caused changes in phytoplankton species composition, even if the N:P ratio of the nutrient loads remained constant, by shifting the species interactions from competition for nutrients to competition for light. In all treatments, small species became dominant whereas larger species were competitively excluded, supporting the common view that small cell size provides a competitive advantage under resource-limited conditions. Contrary to expectation, all treatments led to coexistence of diatoms, cyanobacteria and green algae, resulting in a higher diversity of species than predicted by theory. Because the coexisting species comprised three phyla with different photosynthetic pigments, we speculate that niche differentiation in the light spectrum might play a role. Our results show that mechanistic resource competition models that integrate nutrient-based and light-based approaches provide an important step forward to understand and predict how changing nutrient loads affect community composition. © 2018 The Authors Ecology published by Wiley Periodicals, Inc. on behalf of Ecological Society of America.

Aquatic macrophytes can be used for wastewater polishing but not for purification in constructed wetlands

NASA Astrophysics Data System (ADS)

Tang, Yingying; Harpenslager, Sarah F.; van Kempen, Monique M. L.; Verbaarschot, Evi J. H.; Loeffen, Laury M. J. M.; Roelofs, Jan G. M.; Smolders, Alfons J. P.; Lamers, Leon P. M.

2017-02-01

The sequestration of nutrients from surface waters by aquatic macrophytes and sediments provides an important service to both natural and constructed wetlands. While emergent species take up nutrients from the sediment, submerged and floating macrophytes filter nutrients directly from the surface water, which may be more efficient in constructed wetlands. It remains unclear, however, whether their efficiency is sufficient for wastewater purification and how plant species and nutrient loading affects nutrient distribution over plants, water and sediment. We therefore determined nutrient removal efficiencies of different vegetation (Azolla filiculoides, Ceratophyllum demersum and Myriophyllum spicatum) and sediment types (clay, peaty clay and peat) at three nutrient input rates, in a full factorial, outdoor mesocosm experiment. At low loading (0.43 mg P m-2 d-1), plant uptake was the main pathway (100 %) for phosphorus (P) removal, while sediments showed a net P release. A. filiculoides and M. spicatum showed the highest biomass production and could be harvested regularly for nutrient recycling, whereas C. demersum was outcompeted by spontaneously developing macrophytes and algae. Higher nutrient loading only stimulated A. filiculoides growth. At higher rates ( ≥ 21.4 mg P m-2 d-1), 50-90 % of added P ended up in sediments, with peat sediments becoming more easily saturated. For nitrogen (N), 45-90 % was either taken up by the sediment or lost to the atmosphere at loadings ≥ 62 mg N m-2 d-1. This shows that aquatic macrophytes can indeed function as an efficient nutrient filter but only for low loading rates (polishing) and not for high rates (purification). The outcome of this controlled study not only contributes to our understanding of nutrient dynamics in constructed wetlands but also shows the differential effects of wetland sediment types and plant species. Furthermore, the acquired knowledge may benefit the application of macrophyte harvesting to remove and recycle nutrients from both constructed wetlands and nutrient-loaded natural wetlands.

Targets set to reduce Lake Erie algae

USGS Publications Warehouse

Evans, Mary

2016-01-01

In February 2016, the Great Lakes Executive Committee, which oversees the implementation of the Great Lakes Water Quality Agreement (GLWQA) between the U.S. and Canada, approved phosphorus loading targets for Lake Erie to reduce the size of harmful algal blooms (HABs), reduce the presence of the low oxygen zone in the central basin, and protect nearshore water quality. The targets are set with respect to the nutrient loads calculated for 2008. To reduce the impacts of HABs on Lake Erie a target was set of a 40 percent reduction in total and soluble reactive phosphorus loads in the spring from two Canadian rivers and several Michigan and Ohio rivers, especially the Maumee River (https://binational.net/2016/02/22/ finalptargets-ciblesfinalesdep/). States and the province of Ontario are already developing Domestic Action Plans to accomplish the reductions and scientists are developing research and monitoring plans to assess progress.

Water quality and hydrology of Silver Lake, Oceana County, Michigan, with emphasis on lake response to nutrient loading

USGS Publications Warehouse

Brennan, Angela K.; Hoard, Christopher J.; Duris, Joseph W.; Ogdahl, Mary E.; Steinman, Alan D.

2016-01-29

Simulations also were run using the BATHTUB model to evaluate the number of days Silver Lake could experience algal blooms (algal blooms are defined as modeled chlorophyll a in excess of 10 micrograms per liter [µg/L]) as a result of an increase/decrease in phosphorus and nitrogen loading from groundwater, Hunter Creek, and (or) a combination of sources. If the phosphorus and nitrogen loading from Hunter Creek is decreased (and all other sources are not altered), Silver Lake will continue to experience algal blooms, but less frequently than what is currently experienced. The same scenario holds true if the nutrient loading from groundwater is decreased. Another scenario was simulated using a combination of sources, which includes increases and decreases in phosphorus and nitrogen loading from sources that are the most likely to be managed, and includes groundwater (as a result of conversion of household septic to sewers), Hunter Creek (conversion of household septic to sewers), and lawn runoff. Results of the BATHTUB model indicated that a 50-percent reduction of phosphorus and nitrogen from these sources would result in a considerable decrease in algal bloom frequency (from 231 to 132 days) and severity, and a 75-percent reduction would greatly reduce algal bloom occurrence on Silver Lake (from 231 to 57 days). BATHTUB model scenarios based on septic load model: A scenario also was conducted using the BATHTUB model to simulate the conversion of septic to sewer and included a low, high, and medium (likely) scenario of nutrient loading to Silver Lake. Simulations of the BATHTUB model indicated that, under the likely scenario, the conversion of all onsite septic treatment to sewers would result in an overall change in lake trophic status from eutrophic to mesotrophic, thereby reducing the frequency of algal blooms and algal bloom intensity on Silver Lake (chlorophyll a >10 µg/L, from 231 to 184 days per year, or chlorophyll a >20 µg/L, from 80 to 49 days per year).

Incorporating uncertainty into the ranking of SPARROW model nutrient yields from Mississippi/Atchafalaya River basin watersheds

USGS Publications Warehouse

Robertson, Dale M.; Schwarz, Gregory E.; Saad, David A.; Alexander, Richard B.

2009-01-01

Excessive loads of nutrients transported by tributary rivers have been linked to hypoxia in the Gulf of Mexico. Management efforts to reduce the hypoxic zone in the Gulf of Mexico and improve the water quality of rivers and streams could benefit from targeting nutrient reductions toward watersheds with the highest nutrient yields delivered to sensitive downstream waters. One challenge is that most conventional watershed modeling approaches (e.g., mechanistic models) used in these management decisions do not consider uncertainties in the predictions of nutrient yields and their downstream delivery. The increasing use of parameter estimation procedures to statistically estimate model coefficients, however, allows uncertainties in these predictions to be reliably estimated. Here, we use a robust bootstrapping procedure applied to the results of a previous application of the hybrid statistical/mechanistic watershed model SPARROW (Spatially Referenced Regression On Watershed attributes) to develop a statistically reliable method for identifying “high priority” areas for management, based on a probabilistic ranking of delivered nutrient yields from watersheds throughout a basin. The method is designed to be used by managers to prioritize watersheds where additional stream monitoring and evaluations of nutrient-reduction strategies could be undertaken. Our ranking procedure incorporates information on the confidence intervals of model predictions and the corresponding watershed rankings of the delivered nutrient yields. From this quantified uncertainty, we estimate the probability that individual watersheds are among a collection of watersheds that have the highest delivered nutrient yields. We illustrate the application of the procedure to 818 eight-digit Hydrologic Unit Code watersheds in the Mississippi/Atchafalaya River basin by identifying 150 watersheds having the highest delivered nutrient yields to the Gulf of Mexico. Highest delivered yields were from watersheds in the Central Mississippi, Ohio, and Lower Mississippi River basins. With 90% confidence, only a few watersheds can be reliably placed into the highest 150 category; however, many more watersheds can be removed from consideration as not belonging to the highest 150 category. Results from this ranking procedure provide robust information on watershed nutrient yields that can benefit management efforts to reduce nutrient loadings to downstream coastal waters, such as the Gulf of Mexico, or to local receiving streams and reservoirs.

Instream Attenuation of Nitrogen and Phosphorus in Non-Point Source Dominated Streams: Hydrologic and Biogeochemical Controls

NASA Astrophysics Data System (ADS)

Bray, E. N.; Chen, X.; Keller, A. A.

2010-12-01

Non-point source inputs of total nitrogen (TN) and total phosphorus (TP) in rivers are the leading causes of water quality degradation in the United States (Turner and Rabalais, 2003; Broussard and Turner, 2009). Yet it remains a challenge to adequately quantify the relative role and influence of physical hydrological processes versus biogeochemical processes on the attenuation of TN and TP for individual river reaches. A watershed-scale study of instream dynamics and attenuation of TN and TP in northeastern U.S. headwater streams demonstrates that physical and hydrological processes exert greater control over nutrient removal than biogeochemical processes. To explore these interactions under various attenuation scenarios, we developed the watershed-scale model (WARMF) for 97 catchments to simulate watershed processes, hydrology, and diffuse source loads of nutrients. We simulated a hypothetical nutrient release at a rate of 1 kg/d of TN (50% as ammonium and 50% as nitrate) and TP (100% as phosphate) to predict response lengths of downstream catchments. Resulting attenuation factors are presented as the change in mean load at a given location, normalized to the change in the catchment in which the load is applied. Results indicate that for most catchments, the TN and TP load increase is attenuated from the stream within a few tens of kilometers. Fifty percent attenuation occurs across length scales ranging from a few hundreds of meters to kilometers if the load is introduced in the headwaters, indicating the most rapid nutrient removal occurs in the smallest headwater streams but generally decreases with distance downstream. There are some differences in the attenuation factors for TN and TP, although the pattern of attenuation is the same. Sensitivity analyses highlight five hydrological parameters of paramount importance to concentrations of N and P, namely precipitation, evaporation coefficients (magnitude and skewness), soil layer thickness, soil saturated moisture and soil hydraulic conductivity. These model parameters have a significant effect on the concentrations of nutrients, with TN exhibiting greater sensitivity. Further, attenuation results suggest that stream depth, flow regime, and density of agriculture in small headwater streams are potentially important controls to nutrient uptake and removal; i.e. during periods of low flow, dilution is reduced, attenuation length increases, and removal processes may be dominated by settling as opposed to biogeochemistry. Instream attenuation and model results can be used to assess 1) the scale and nature of best management practices which must be adopted to result in nutrient reductions, 2) the downstream distance at which load reductions will be effective, and 3) the hydrological characteristics of the river network which exert considerable influence on attenuation lengths and nutrient removal.

Basin scale controls on CO2 and CH4 emissions from the Upper Mississippi River

USGS Publications Warehouse

Crawford, John T.; Loken, Luke C.; Stanley, Emily H.; Stets, Edward G.; Dornblaser, Mark M.; Striegl, Robert G.

2016-01-01

The Upper Mississippi River, engineered for river navigation in the 1930s, includes a series of low-head dams and navigation pools receiving elevated sediment and nutrient loads from the mostly agricultural basin. Using high-resolution, spatially resolved water quality sensor measurements along 1385 river kilometers, we show that primary productivity and organic matter accumulation affect river carbon dioxide and methane emissions to the atmosphere. Phytoplankton drive CO2to near or below atmospheric equilibrium during the growing season, while anaerobic carbon oxidation supports a large proportion of the CO2 and CH4 production. Reductions of suspended sediment load, absent of dramatic reductions in nutrients, will likely further reduce net CO2emissions from the river. Large river pools, like Lake Pepin, which removes the majority of upstream sediments, and large agricultural tributaries downstream that deliver significant quantities of sediments and nutrients, are likely to persist as major geographical drivers of greenhouse gas emissions.

Modeling the Response of Nutrient Concentrations and Primary Productivity in Lake Michigan to Nutrient Loading Scenarios

EPA Science Inventory

A water quality model, LM3 Eutro, will be used to estimate the response of nutrient concentrations and primary productivity in Lake Michigan to nutrient loading scenarios. This work is part of a larger effort, the Future Midwestern landscapes study, that will estimate the produc...

Estimating Summer Nutrient Concentrations in Northeastern Lakes from SPARROW Load Predictions and Modeled Lake Depth and Volume

EPA Science Inventory

Global nutrient cycles have been altered by use of fossil fuels and fertilizers resulting in increases in nutrient loads to aquatic systems. In the United States, excess nutrients have been repeatedly reported as the primary cause of lake water quality impairments. Setting nutr...

A COMPARATIVE ANALYSIS OF NUTRIENT LOADING, NUTRIENT RETENTION AND NET ECOSYSTEM METABOLISM IN THREE TIDAL RIVER ESTUARIES DIFFERING PREDOMINATELY BY THEIR WATERSHED LAND USE TYPES.

EPA Science Inventory

Abstract and oral presentation for the Estuarine Research Federation Conference.

Estuarine retention of watershed nutrient loads, system-wide nutrient biogeochemical fluxes, and net ecosystem metabolism (NEM) were determined in three estuaries exhibiting differing magnitud...

Performance of five plant species in removal of nitrogen and phosphorus from an experimental phytoremediation system in the Ningxia irrigation area.

PubMed

Chen, Chongjuan; Zhao, Tiancheng; Liu, Ruliang; Luo, Liangguo

2017-09-10

Agricultural non-point source (ANPS) pollution is an important contributor to elevated nitrogen (N) and phosphorus (P) in surface waters, which can cause serious environmental problems. Considerable effort has therefore gone into the development of methods that control the ANPS input of N and P to surface waters. Phytoremediation has been extensively used because it is cost-effective, environmentally friendly, and efficient. The N and P loads from agricultural drainage are a potential threat to the water quality of the Yellow River in Ningxia, China. Yet, phytoremediation has only rarely been applied within the Ningxia irrigation area. In an experimental set-up, five species (Ipomoea aquatica, IA; Lactuca sativa, LS; Oryza sativa, OS; Typha latifolia, TL; Zizania latifolia, ZL) were evaluated for their ability to reduce N and P loads over 62 days and five observation periods. Total N and P concentrations, plant biomass, and nutrient content were measured. The results showed that OS, LS, and IA performed better than ZL and TL in terms of nutrients removal, biomass accumulation, and nutrients storage. The highest overall removal rates of N and P (57.7 and 57.3%, respectively) were achieved by LS treatment. In addition, plant uptake contributed significantly to nutrient removal, causing a 25.9-72.0% reduction in N removal and a 54.3-86.5% reduction in P removal. Thus, this study suggests that OS, LS, and IA would be more suitable than ZL and TL for controlling nutrient loads in the Ningxia irrigation area using phytoremediation.

Modeling Nutrient Loading to Watersheds in the Great Lakes Basin: A Detailed Source Model at the Regional Scale

NASA Astrophysics Data System (ADS)

Luscz, E.; Kendall, A. D.; Martin, S. L.; Hyndman, D. W.

2011-12-01

Watershed nutrient loading models are important tools used to address issues including eutrophication, harmful algal blooms, and decreases in aquatic species diversity. Such approaches have been developed to assess the level and source of nutrient loading across a wide range of scales, yet there is typically a tradeoff between the scale of the model and the level of detail regarding the individual sources of nutrients. To avoid this tradeoff, we developed a detailed source nutrient loading model for every watershed in Michigan's lower peninsula. Sources considered include atmospheric deposition, septic tanks, waste water treatment plants, combined sewer overflows, animal waste from confined animal feeding operations and pastured animals, as well as fertilizer from agricultural, residential, and commercial sources and industrial effluents . Each source is related to readily-available GIS inputs that may vary through time. This loading model was used to assess the importance of sources and landscape factors in nutrient loading rates to watersheds, and how these have changed in recent decades. The results showed the value of detailed source inputs, revealing regional trends while still providing insight to the existence of variability at smaller scales.

Integrating Spatial Land Use Analysis and Mathematical Material Flow Analysis for Nutrient Management: A Case Study of the Bang Pakong River Basin in Thailand

NASA Astrophysics Data System (ADS)

Kupkanchanakul, Wallapa; Kwonpongsagoon, Suphaphat; Bader, Hans-Peter; Scheidegger, Ruth

2015-05-01

Rivers in developing and emerging countries often lack good water quality. Tools to assess the water quality in rivers, including identification of possible sources of pollution, are therefore of increasing importance. The aim of this study is to apply mathematical material flow and spatial land use analyses to identify and geographically locate the main nitrogen and phosphorus sources and processes in Bang Pakong Basin (BPB). Potential measures to mitigate the nitrogen and phosphorus loads to the water system can then be efficiently evaluated. The combination of these two methods reveals the overall nutrient load as well as local "hot spots." This allows possible mitigation measures to be discussed with regard to their spatial location. This approach goes beyond previous work in which mathematical material flow analysis was shown to be a useful tool to investigate sources of nutrients regardless of their location. The results show that the main sources contributing nutrients to waterways are aquaculture, such as shrimp, tilapia, catfish, and sea bass farming, as well as rice paddies along the main river. Additional sources contributing nutrients to this basin are field crops, livestock, aquaculture, households, and industry. High levels of nutrient inflows come from feeds and fertilizers through aquaculture and rice cultivation. The excess nutrients run into the waterways by direct discharge from aquaculture and runoff processes from rice paddies. Scenario analysis shows that management practices for aquaculture, rice, pig, and poultry farming are key drivers for reducing nutrients in the BPB.

Integrating spatial land use analysis and mathematical material flow analysis for nutrient management: a case study of the Bang Pakong River Basin in Thailand.

PubMed

Kupkanchanakul, Wallapa; Kwonpongsagoon, Suphaphat; Bader, Hans-Peter; Scheidegger, Ruth

2015-05-01

Rivers in developing and emerging countries often lack good water quality. Tools to assess the water quality in rivers, including identification of possible sources of pollution, are therefore of increasing importance. The aim of this study is to apply mathematical material flow and spatial land use analyses to identify and geographically locate the main nitrogen and phosphorus sources and processes in Bang Pakong Basin (BPB). Potential measures to mitigate the nitrogen and phosphorus loads to the water system can then be efficiently evaluated. The combination of these two methods reveals the overall nutrient load as well as local "hot spots." This allows possible mitigation measures to be discussed with regard to their spatial location. This approach goes beyond previous work in which mathematical material flow analysis was shown to be a useful tool to investigate sources of nutrients regardless of their location. The results show that the main sources contributing nutrients to waterways are aquaculture, such as shrimp, tilapia, catfish, and sea bass farming, as well as rice paddies along the main river. Additional sources contributing nutrients to this basin are field crops, livestock, aquaculture, households, and industry. High levels of nutrient inflows come from feeds and fertilizers through aquaculture and rice cultivation. The excess nutrients run into the waterways by direct discharge from aquaculture and runoff processes from rice paddies. Scenario analysis shows that management practices for aquaculture, rice, pig, and poultry farming are key drivers for reducing nutrients in the BPB.

Nitrogen deposition and exceedance of critical loads for nutrient nitrogen in Irish grasslands.

PubMed

Henry, Jason; Aherne, Julian

2014-02-01

High resolution nitrogen (N) deposition maps were developed to assess the exceedance of empirical critical loads of nutrient N for grasslands in Ireland. Nitrogen emissions have remained relatively constant during the past 20 yrs and are projected to remain constant under current legislation. Total N deposition (estimated as wet nitrate [NO3(-)] and ammonium [NH4(+)] plus dry NO× and NH3) ranged from 2 to 22 kg Nha(-1)yr(-1) (mean=12 kg Nha(-1)yr(-1)) to grasslands. Empirical critical loads for nutrient N were set at 15 kg Nha(-1)yr(-1) for both acid and calcareous grasslands; exceedance was observed for ~35% (~2,311 km(2)) of mapped acid grasslands. In contrast, only ~9% of calcareous grasslands (~35 km(2)) received N deposition in excess of the critical load. Reduced N deposition (primarily dry NH3) represented the dominant form to grasslands (range 55-90%) owing to significant emissions associated with livestock (primarily cattle). The extent of exceedance in acid grasslands suggests that N deposition to this habitat type may lead to adverse impacts such as a decline in plant species diversity and soil acidification. Further, given that elevated N deposition was dominated by NH3 associated with agricultural emissions rather than long-range transboundary sources, future improvements in air quality need to be driven by national policies. © 2013.

Relating watershed nutrient loads to satellite derived estuarine water quality

EPA Science Inventory

Nutrient enhanced phytoplankton production is a cause of degraded estuarine water quality. Yet, relationships between watershed nutrient loads and the spatial and temporal scales of phytoplankton blooms and subsequent water quality impairments remain unquantified for most systems...

Management of hydro-biogeochemical connectivity of geographically isolated wetlands to reduce the risk of eutrophication of Lake Winnipeg

NASA Astrophysics Data System (ADS)

Creed, Irena F.; Ameli, Ali

2017-04-01

Lake Winnipeg - a transboundary water resource that is the 10th largest freshwater lake in the world - was recently listed as the most threatened lake in the world due to eutrophication. Its watershed has experienced amongst the highest geographically isolated wetland (GIW) drainage rates in the world, leading to increased nutrient loads to remaining wetlands and downstream streams and lakes. GIWs are surrounded by uplands - and thus collect and store water from the surrounding landscape during snowmelt or storm events, and filter nutrients before slowly returning water to the water cycle. When drained, GIWs become connected to downstream flows and nutrients move unimpeded from and through them to downstream waters. Therefore, effective GIW management strategies can reduce nutrient loads to regional surface water bodies in the Lake Winnipeg watershed. But, how do we prioritize wetland protection and restoration efforts? We know that hydrologic connections to GIWs vary in length and timing, and hypothesize that long and slow hydrologic connections to a GIW have higher potential for P retention, while short and fast hydrologic connections to a GIW have lower potential for P retention along the flow path, leading to higher P concentrations within the GIW. We test these hypotheses in a watershed that drains into the North Saskatchewan River and ultimately to Lake Winnipeg. Using a novel model that quantifies the continuum of time and length variations of subsurface-surface hydrological connections to each GIW, we explore the relationship between length and time and time of hydrologic connection to a GIW and nutrients in the GIW. We found that GIWs are not always "isolated" islands - rather, they are connected to other surface waters in diverse ways. GIWs with no modeled surface or subsurface hydrological connections had the lowest nutrient concentrations and algal biomass. Recharge GIWs have lower concentrations of nutrients than discharge wetlands. Discharge GIWs with longer (slower) connections removed more nutrients along flow path to the wetland than discharge GIWs with shorter (faster) connections. Based on our findings, GIWs with long and slow hydrological connections have the highest potential for retaining phosphorus and therefore reducing eutrophication of downstream waters, and therefore should be prioritized in wetland protection and restoration strategies.

Nutrient dynamics in five off-stream reservoirs in the lower South Platte River basin, March-September 1995

USGS Publications Warehouse

Sprague, Lori A.

2002-01-01

In 1995, the U.S. Geological Survey conducted a study to characterize nutrient concentrations in five off-stream reservoirs in the lower South Platte River Basin?Riverside, Jackson, Prewitt, North Sterling, and Julesburg. These reservoirs are critical sources of irrigation water for agricultural areas, and several also are used for fishing, boating, swimming, hunting, and camping. Data collected for this study include depth profiles of water temperature, dissolved oxygen, pH, and specific conductance; nutrient species concentrations in the water column, bottom sediment, and inflow and outflow canals; and chlorophyll-a concentrations in the water column. Data were collected during the irrigation season from March through September 1995 at five sites each in Riverside, Jackson, Prewitt, and Julesburg Reservoirs and at six sites in North Sterling Reservoir. The five reservoirs studied are located in similar geographic, climatic, and land-use areas and, as a result, have a number of similarities in their internal nutrient dynamics. Nitrogen concentrations in the reservoirs were highest in March and decreased through September as a result of dilution from river inflows and biological activity. From March through June, decreases in nitrogen concentrations in the river and biological activity contributed to decreases in reservoir concentrations. From July through September, inflows from the river were cut off, and biological activity in the reservoirs led to further decreases in nitrate concentrations, which fell to near or below detectable levels. Phosphorus concentrations in the reservoirs did not show the same consistent decrease from March through September. Phosphorus likely was recycled continuously back to algae during the study period through processes such as excretion from fish, decay of aquatic plants and animals, and release of orthophosphate from bottom sediment during periods of low oxygen. With the exception of phosphorus in Jackson Reservoir, the reservoirs acted as a sink for both nitrogen and phosphorus; the percentage of the total mass (initial storage plus inflows) trapped in the reservoirs during the study period ranged from 49 to 88 percent for nitrogen and from 20 to 86 percent for phosphorus. The nutrient loading, morphology, and operation of the five reservoirs differed, however, leading to several important differences in nutrient dynamics among the reservoirs. Mean nutrient concentrations during the study period decreased in a downstream direction from Riverside Reservoir to Julesburg Reservoir because concentrations in the source water?the South Platte River?decreased downstream as a result of increased distance from wastewater loading upstream from Kersey, Colorado, and the replacement of diverted river water with more dilute ground-water return flow. North Sterling was an exception to this decrease; the strong stratification and resulting anoxia that developed in the reservoir led to nutrient release from the bottom sediments that offset the decrease in external nutrient loading. Variations in nutrient loading also contributed to differences in the nutrient limiting algal growth in the reservoirs, as indicated by mass nitrogen:phosphorus ratios. In Riverside and Jackson Reservoirs, nitrogen became the potential limiting nutrient by midsummer as biological activity depleted the available supply of nitrogen while the high initial phosphorus load was recycled. Prewitt, North Sterling, and Julesburg Reservoirs, with lower initial loadings of phosphorus, were phosphorus-limited throughout the study period, with additional colimitation of nitrogen as biological uptake reduced nitrogen concentrations to near or below laboratory detection limits. The percentage of the total nitrogen and phosphorus mass lost through outflow and trapped in the reservoir due to processes such as biological uptake and sedimentation varied between reservoirs.Generally, reservoirs with short residence times such as North Ste

Temporal Responses of Coastal Hypoxia to Nutrient Loading and Physical Controls.

EPA Science Inventory

The incidence and intensity of hypoxic waters in coastal aquatic ecosystems has been expanding in recent decades coincident with eutrophication of the coastal zone. Because of the negative effects hypoxia has on many organisms, extensive efforts have been made to reduce the size ...

Status of Lake Erie phosphorus loads and concentrations

EPA Science Inventory

Under the Great Lakes Water Quality Protocol of 2012, nutrient loading and nutrient concentrations for open and nearshore waters must be re-evaluated for Substance Objectives that are consistent with overall Ecosystem Objectives. One of the primary driving nutrients of interest ...

Inter-event variability in urban stormwater runoff response associated with hydrologic connectivity

NASA Astrophysics Data System (ADS)

Hondula, K. L.

2015-12-01

Urbanization alters the magnitude and composition of hydrologic and biogeochemical fluxes from watersheds, with subsequent deleterious consequences for receiving waters. Projected changes in storm characteristics such as rainfall intensity and event size are predicted to amplify these impacts and render current regulations inadequate for protecting surface water quality. As stormwater management practices (BMPs) are increasingly being relied upon to reduce excess nutrient pollution in runoff from residential development, empirical investigation of their performance across a range of conditions is warranted. Despite substantial investment in urban and suburban BMPs, significant knowledge gaps exist in understanding how landscape structure and precipitation event characteristics influence the amount of stormwater runoff and associated nutrient loads from these complex catchments. Increasing infiltration of stormwater before it enters the sewer network (source control) is hypothesized to better mimic natural hydrologic and biogeochemical fluxes compared to more centralized BMPs at sewer outlets such as wet and dry ponds. Rainfall and runoff quality and quantity were monitored in four small (1-5 ha) residential catchments in Maryland to test the efficacy of infiltration-based stormwater management practices in comparison to end-of-pipe BMPs. Results indicated that reduced hydrologic connectivity associated with infiltration-based practices affected the relationship between the magnitude of rainfall events and water yield , but only for small precipitation events: compared to end-of-pipe BMPs, source control was associated with both lower runoff ratios and lower nutrient export per area for a given rainfall event size. We found variability in stormwater runoff responses (water yield, quality, and nutrient loads) was associated with precipitation event size, antecedent rainfall, and hydrologic connectivity as quantified by a modified directional connectivity index. Accounting for the interactive effects of landscape structure and precipitation event characteristics can reduce the uncertainty surrounding stormwater runoff responses in complex urban watersheds.

Hydrology and the hypothetical effects of reducing nutrient applications of water quality in the Bald Eagle Creek Headwaters, southeastern Pennsylvania prior to implementation of agricultural best-management practices

USGS Publications Warehouse

Fishel, D.K.; Langland, M.J.; Truhlar, M.V.

1991-01-01

The report characterizes a 0.43-square-mile agricultural watershed in York County, underlain by albite-chlorite and oligoclase-mica schist in the Lower Susquehanna River basin, that is being studied as part of the U.S. Environmental Protection Agency's Chesapeake Bay Program. The water quality of Bald Eagle Creek was studied from October 1985 through September 1987 prior to the implementation of Best-Management Practices to reduce nutrient and sediment discharge into Muddy Creek, a tributary to the Chesapeake Bay. About 88 percent of the watershed is cropland and pasture, and nearly 33 percent of the cropland is used for corn. The animal population is entirely dairy cattle. About 85,640 pounds of nitrogen (460 pounds per acre) and 21,800 pounds of phosphorus (117 pounds per acre) were applied to fields; 52 percent of the nitrogen and 69 percent of the phosphorus was from commercial fertilizer. Prior to fertilization, nitrate nitrogen in the soil ranged from 36 to 136 pounds per acre and phosphorus ranged from 0.89 to 5.7 pounds per acre in the top 4 feet of soil. Precipitation was about 18 percent below normal and streamflow about 35 percent below normal during the 2-year study. Eighty-four percent of the 20.44 inches of runoff was base flow. Median concentrations of total nitrogen and dissolved phosphorous in base flow were 0.05 and 0.04 milligrams per liter as phosphorus, respectively. Concentrations of dissolved nitrate in base flow increased following wet periods after crops were harvested and manure was applied. During the growing season, concentrations decreased similarly to those observed in carbonate-rock areas as nutrient uptake and evapotranspiration by corn increased. About 4,550 pounds of suspended sediment, 5,250 pounds of nitrogen, and 66.6 pounds of phosphorus discharged in base flow during the 2-year period. The suspended sediment load was about 232,000 pounds in stormflow from 26 storms that contributed 51 percent of the total stormflow. The nitrogen load was about 651 pounds and the phosphorus load was about 74 pounds in stormflow from 16 storms that contributed 28 percent of the total stormflow. It is estimated that concentrations of total nitrogen and phosphorus in base flow need to be reduced by 12 and 48 percent, respectively, to detect changes during the nutrient-management phase. Likewise, loads to total nitrogen and phosphorus in base flow need to be reduced by 62 and 57 percent.

Watershed delineation and nitrogen source analysis for Bayou ...

EPA Pesticide Factsheets

Nutrient pollution in stormwater runoff from urbanized areas contributes to water quality degradation in streams and receiving waterbodies. Agriculture, population growth, and industrial activities are significant sources of nitrogen inputs for surface waters. Increased nitrogen loading stimulates eutrophication through algal blooms, which leads to an overall decrease in drinking water and aquatic habitat quality. Bayou Chico, a highly urbanized watershed in the Pensacola Bay system in northwest Florida, is a nutrient-impaired waterbody under management to reduce bacteria and nutrient loadings, in accordance with the Florida Department of Environmental Protection’s (FDEP) Basin Management Action Plan. Best management practices and green infrastructure (GI) throughout Bayou Chico help reduce nitrogen inputs by retaining and filtering water. GI can function as a nitrogen sink by sorption or infiltration into soils, sequestration into plant material, and denitrification through microbial processes. However, a better understanding of the efficiency of these systems is needed to better inform management practices on future nitrogen reduction. This project will address two issues relating to the presence of nitrogen in the Bayou Chico watershed: 1) the identification of specific nitrogen sources within urbanized areas, and 2) the potential rates of nitrogen removal and sequestration from GI and nitrogen transport throughout the bayou. To accomplish these goals, nitr

Reducing nitrogen export from the corn belt to the Gulf of Mexico: agricultural strategies for remediating hypoxia

USGS Publications Warehouse

McLellan, Eileen; Robertson, Dale M.; Schilling, Keith; Tomer, Mark; Kostel, Jill; Smith, Douglas G.; King, Kevin

2015-01-01

SPAtially Referenced Regression on Watershed models developed for the Upper Midwest were used to help evaluate the nitrogen-load reductions likely to be achieved by a variety of agricultural conservation practices in the Upper Mississippi-Ohio River Basin (UMORB) and to compare these reductions to the 45% nitrogen-load reduction proposed to remediate hypoxia in the Gulf of Mexico (GoM). Our results indicate that nitrogen-management practices (improved fertilizer management and cover crops) fall short of achieving this goal, even if adopted on all cropland in the region. The goal of a 45% decrease in loads to the GoM can only be achieved through the coupling of nitrogen-management practices with innovative nitrogen-removal practices such as tile-drainage treatment wetlands, drainage–ditch enhancements, stream-channel restoration, and floodplain reconnection. Combining nitrogen-management practices with nitrogen-removal practices can dramatically reduce nutrient export from agricultural landscapes while minimizing impacts to agricultural production. With this approach, it may be possible to meet the 45% nutrient reduction goal while converting less than 1% of cropland in the UMORB to nitrogen-removal practices. Conservationists, policy makers, and agricultural producers seeking a workable strategy to reduce nitrogen export from the Corn Belt will need to consider a combination of nitrogen-management practices at the field scale and diverse nitrogen-removal practices at the landscape scale.

Explanatory characteristics for nutrient concentrations and loads in the Sava River Catchment and cross-regionally

NASA Astrophysics Data System (ADS)

Levi, L.; Cvetkovic, V.; Destouni, G.

2015-12-01

This study compiles estimates of waterborne nutrient concentrations and loads in the Sava River Catchment (SRC). Based on this compilation, we investigate hotspots of nutrient inputs and retention along the river, as well as concentration and load correlations with river discharge and various human drivers of excess nutrient inputs to the SRC. For cross-regional assessment and possible generalization, we also compare corresponding results between the SRC and the Baltic Sea Drainage Basin (BSDB). In the SRC, one small incremental subcatchment, which is located just downstream of Zagreb and has the highest population density among the SRC subcatchments, is identified as a major hotspot for net loading (input minus retention) of both total nitrogen (TN) and total phosphorus (TP) to the river and through it to downstream areas of the SRC. The other SRC subcatchments exhibit relatively similar characteristics with smaller net nutrient loading. The annual loads of both TN and TP along the Sava River exhibit dominant temporal variability with considerably higher correlation with annual river discharge (R2 = 0.51 and 0.28, respectively) than that of annual average nutrient concentrations (R2 = 0.0 versus discharge for both TN and TP). Nutrient concentrations exhibit instead dominant spatial variability with relatively high correlation with population density among the SRC subcatchments (R2=0.43-0.64). These SRC correlation characteristics compare well with corresponding ones for the BSDB, even though the two regions are quite different in their hydroclimatic, agricultural and wastewater treatment conditions. Such cross-regional consistency in dominant variability type and explanatory catchment characteristics may be a useful generalization basis, worthy of further investigation, for at least first-order estimation of nutrient concentration and load conditions in less data-rich regions.

Loads of nitrate, phosphorus, and total suspended solids from Indiana watersheds

USGS Publications Warehouse

Bunch, Aubrey R.

2016-01-01

Transport of excess nutrients and total suspended solids (TSS) such as sediment by freshwater systems has led to degradation of aquatic ecosystems around the world. Nutrient and TSS loads from Midwestern states to the Mississippi River are a major contributor to the Gulf of Mexico Hypoxic Zone, an area of very low dissolved oxygen concentration in the Gulf of Mexico. To better understand Indiana’s contribution of nutrients and TSS to the Mississippi River, annual loads of nitrate plus nitrite as nitrogen, total phosphorus, and TSS were calculated for nine selected watersheds in Indiana using the load estimation model, S-LOADEST. Discrete water-quality samples collected monthly by the Indiana Department of Environmental Management’s Fixed Stations Monitoring Program from 2000–2010 and concurrent discharge data from the U. S. Geological Survey streamflow gages were used to create load models. Annual nutrient and TSS loads varied across Indiana by watershed and hydrologic condition. Understanding the loads from large river sites in Indiana is important for assessing contributions of nutrients and TSS to the Mississippi River Basin and in determining the effectiveness of best management practices in the state. Additionally, evaluation of loads from smaller upstream watersheds is important to characterize improvements at the local level and to identify priorities for reduction.

External nutrient loading from land, sea and atmosphere to all 656 Swedish coastal water bodies.

PubMed

Bryhn, Andreas C; Dimberg, Peter H; Bergström, Lena; Fredriksson, Ronny E; Mattila, Johanna; Bergström, Ulf

2017-01-30

Identifying the main sources of nutrient loading is a key factor for efficient mitigation of eutrophication. This study has investigated the pathways of external nutrient loading to 656 coastal water bodies along the entire Swedish coastline. The studied water bodies have been delineated to meet requirements in the European Union's Water Framework Directive, and recent status assessments have shown that 57% of them fail to attain good or high ecological status with respect to nutrients. The analysis in the study was performed on data from mass-balance based nutrient budgets computed using the modelling framework Vattenwebb. The external nutrient contribution from the sea to the water bodies was highly variable, ranging from about 1% to nearly 100%, but the median contribution was >99% of the total external loading regarding both nitrogen and phosphorus. External loading from the atmosphere and local catchment area played a minor role in general. However, 45 coastal water bodies received >25% of the external nitrogen and phosphorus from their catchments. Loading from land typically peaked in April following ice-break and snow melting and was comparatively low during summer. The results indicate that for many eutrophicated Swedish coastal water bodies, nutrient abatement is likely to be optimally effective when potential measures in all of the catchment area of the concerned sea basin are considered. Local-scale mitigation in single water bodies will likely be locally effective only in the small proportion of areas where water and thereby also nutrient input from the catchment is high compared to the influx from the sea. Future studies should include nutrient reduction scenarios in order to refine these conclusions and to identify relevant spatial scales for coastal eutrophication mitigation measures from a water body perspective. Copyright © 2017 Elsevier Ltd. All rights reserved.

Evaluation of Land Use, Land Management and Soil Conservation Strategies to Reduce Non-Point Source Pollution Loads in the Three Gorges Region, China

NASA Astrophysics Data System (ADS)

Strehmel, Alexander; Schmalz, Britta; Fohrer, Nicola

2016-11-01

The construction of the Three Gorges Dam in China and the subsequent impoundment of the Yangtze River have induced a major land use change in the Three Gorges Reservoir Region, which fosters increased inputs of sediment and nutrients from diffuse sources into the water bodies. Several government programs have been implemented to mitigate high sediment and nutrient loads to the reservoir. However, institutional weaknesses and a focus on economic development have so far widely counteracted the effectiveness of these programs. In this study, the eco-hydrological model soil and water assessment tool is used to assess the effects of changes in fertilizer amounts and the conditions of bench terraces in the Xiangxi catchment in the Three Gorges Reservoir Region on diffuse matter releases. With this, the study aims at identifying efficient management measures, which should have priority. The results show that a reduction of fertilizer amounts cannot reduce phosphorus loads considerably without inhibiting crop productivity. The condition of terraces in the catchment has a strong impact on soil erosion and phosphorus releases from agricultural areas. Hence, if economically feasible, programmes focusing on the construction and maintenance of terraces in the region should be implemented. Additionally, intercropping on corn fields as well as more efficient fertilization schemes for agricultural land were identified as potential instruments to reduce diffuse matter loads further. While the study was carried out in the Three Gorges Region, its findings may also beneficial for the reduction of water pollution in other mountainous areas with strong agricultural use.

Evaluation of Land Use, Land Management and Soil Conservation Strategies to Reduce Non-Point Source Pollution Loads in the Three Gorges Region, China.

PubMed

Strehmel, Alexander; Schmalz, Britta; Fohrer, Nicola

2016-11-01

The construction of the Three Gorges Dam in China and the subsequent impoundment of the Yangtze River have induced a major land use change in the Three Gorges Reservoir Region, which fosters increased inputs of sediment and nutrients from diffuse sources into the water bodies. Several government programs have been implemented to mitigate high sediment and nutrient loads to the reservoir. However, institutional weaknesses and a focus on economic development have so far widely counteracted the effectiveness of these programs. In this study, the eco-hydrological model soil and water assessment tool is used to assess the effects of changes in fertilizer amounts and the conditions of bench terraces in the Xiangxi catchment in the Three Gorges Reservoir Region on diffuse matter releases. With this, the study aims at identifying efficient management measures, which should have priority. The results show that a reduction of fertilizer amounts cannot reduce phosphorus loads considerably without inhibiting crop productivity. The condition of terraces in the catchment has a strong impact on soil erosion and phosphorus releases from agricultural areas. Hence, if economically feasible, programmes focusing on the construction and maintenance of terraces in the region should be implemented. Additionally, intercropping on corn fields as well as more efficient fertilization schemes for agricultural land were identified as potential instruments to reduce diffuse matter loads further. While the study was carried out in the Three Gorges Region, its findings may also beneficial for the reduction of water pollution in other mountainous areas with strong agricultural use.

Predicting nutrient and sediment loadings to streams from landscape metrics: A multiple watershed study from the United States Mid-Atlantic Region

Treesearch

K. Bruce Jones; Anne C. Neale; Malisha S. Nash; Rick D. van Remortel; James D. Wickham; Kurt H. Riitters; Robert V. O' Neill

2001-01-01

There has been an increasing interest in evaluating the relative condition or health of water resources at regional and national scales. Of particular interest is an ability to identify those areas where surface and ground waters have the greatest potential for high levels of nutrient and sediment loadings. High levels of nutrient and sediment loadings can have adverse...

Long-term Changes in Water Quality and Productivity in the Patuxent River Estuary: 1985 to 2003

EPA Science Inventory

We conducted a quantitative assessment of estuarine ecosystem responses to reduced phosphorus and nitrogen loading from sewage treatment facilities and to variability in freshwater flow and non-point nutrient inputs to the Patuxent River estuary. We analyzed a 19-year data set o...

The Utilization of Edge-of-Field Monitoring of Agricultural Runoff in Addressing Nonpoint Source Pollution

USDA-ARS?s Scientific Manuscript database

While basin-scale studies and modeling are important tools in relating land uses to water quality concerns, edge-of-field monitoring (EOFM) provides the necessary resolution to spatially target, design, and evaluate in-field conservation practices for reducing nutrient and sediment loading from agri...

Farm-system modeling to evaluate environmental losses, profitability, and best management practice cost-effectiveness

USDA-ARS?s Scientific Manuscript database

To meet Chesapeake Bay Total Maximum Daily Load requirements for agricultural pollution, conservation districts and farmers are tasked with implementing best management practices (BMPs) that reduce farm losses of nutrients and sediment. The importance of the agricultural industry to the regional eco...

SEASONAL AND ANNUAL MODELING OF REDUCED NITROGEN COMPOUNDS OVER THE EASTERN UNITED STATES: EMISSIONS, AMBIENT LEVELS, AND DEPOSITION AMOUNTS

EPA Science Inventory

Detailed description of the distributions and seasonal trends of atmospheric nitrogen compounds is of considerable interest given their role in formation of acidic substances, tropospheric ozone and particulate matter and nutrient loading effects resulting from their deposition t...

USING STABLE ISOTOPES AND MECHANISTIC MODELS TO EXAMINE CARBON RESOURCE PARTITIONING IN THALASSIA TESTUDINUM AND ZOSTERA MARINA

EPA Science Inventory

Natural and anthropogenic stress negatively impact seagrass production and ecosystem function. Our goal is to better understand seagrass response to reduced light, nutrient and organic loading at a variety of ecological scales (individual to landscape) in order to help develop p...

AIRSHED DOMAINS FOR MODELING ATMOSPHERIC DEPOSITION OF OXIDIZED AND REDUCED NITROGEN TO THE NEUSE/PAMLICO SYSTEM OF NORTH CAROLINA

EPA Science Inventory

Atmospheric deposition is important to nutrient loadings to coastal estuaries. Atmospheric emissions of nitrogen travel hundreds of kilometers as they are removed via atmospheric deposition. Long-range transport from outside the Neuse/Pamlico system in North Carolina is an impo...

Nutrient loadings to streams of the continental United States from municipal and industrial effluent?

USGS Publications Warehouse

Maupin, Molly A.; Ivahnenko, Tamara

2011-01-01

Data from the United States Environmental Protection Agency Permit Compliance System national database were used to calculate annual total nitrogen (TN) and total phosphorus (TP) loads to surface waters from municipal and industrial facilities in six major regions of the United States for 1992, 1997, and 2002. Concentration and effluent flow data were examined for approximately 118,250 facilities in 45 states and the District of Columbia. Inconsistent and incomplete discharge locations, effluent flows, and effluent nutrient concentrations limited the use of these data for calculating nutrient loads. More concentrations were reported for major facilities, those discharging more than 1 million gallons per day, than for minor facilities, and more concentrations were reported for TP than for TN. Analytical methods to check and improve the quality of the Permit Compliance System data were used. Annual loads were calculated using "typical pollutant concentrations" to supplement missing concentrations based on the type and size of facilities. Annual nutrient loads for over 26,600 facilities were calculated for at least one of the three years. Sewage systems represented 74% of all TN loads and 58% of all TP loads. This work represents an initial set of data to develop a comprehensive and consistent national database of point-source nutrient loads. These loads can be used to inform a wide range of water-quality management, watershed modeling, and research efforts at multiple scales.

Modeling Nutrient Release in the Tai Lake Basin of China: Source Identification and Policy Implications

NASA Astrophysics Data System (ADS)

Liu, Beibei; Liu, Heng; Zhang, Bing; Bi, Jun

2013-03-01

Because nutrient enrichment has become increasingly severe in the Tai Lake Basin of China, identifying sources and loads is crucial for watershed nutrient management. This paper develops an empirical framework to estimate nutrient release from five major sectors, which requires fewer input parameters and produces acceptable accuracy. Sectors included are industrial manufacturing, livestock breeding (industrial and family scale), crop agriculture, household consumption (urban and rural), and atmospheric deposition. Results show that in the basin (only the five sectors above), total nutrient loads of nitrogen (N) and phosphorus (P) into aquatic systems in 2008 were 33043.2 tons N a-1 and 5254.4 tons P a-1, and annual area-specific nutrient loads were 1.94 tons N km-2 and 0.31 tons P km-2. Household consumption was the major sector having the greatest impact (46 % in N load, 47 % in P load), whereas atmospheric deposition (18 %) and crop agriculture (15 %) sectors represented other significant proportions of N load. The load estimates also indicate that 32 % of total P came from the livestock breeding sector, making it the second largest phosphorus contributor. According to the nutrient pollution sectors, six best management practices are selected for cost-effectiveness analysis, and feasible options are recommended. Overall, biogas digester construction on industrial-scale farms is proven the most cost-effective, whereas the building of rural decentralized facilities is the best alternative under extreme financial constraint. However, the reduction potential, average monetary cost, and other factors such as risk tolerance of policy makers should all be considered in the actual decision-making process.

Application of the SPARROW model to assess surface-water nutrient conditions and sources in the United States Pacific Northwest

USGS Publications Warehouse

Wise, Daniel R.; Johnson, Henry M.

2013-01-01

The watershed model SPARROW (Spatially Referenced Regressions on Watershed attributes) was used to estimate mean annual surface-water nutrient conditions (total nitrogen and total phosphorus) and to identify important nutrient sources in catchments of the Pacific Northwest region of the United States for 2002. Model-estimated nutrient yields were generally higher in catchments on the wetter, western side of the Cascade Range than in catchments on the drier, eastern side. The largest source of locally generated total nitrogen stream load in most catchments was runoff from forestland, whereas the largest source of locally generated total phosphorus stream load in most catchments was either geologic material or livestock manure (primarily from grazing livestock). However, the highest total nitrogen and total phosphorus yields were predicted in the relatively small number of catchments where urban sources were the largest contributor to local stream load. Two examples are presented that show how SPARROW results can be applied to large rivers—the relative contribution of different nutrient sources to the total nitrogen load in the Willamette River and the total phosphorus load in the Snake River. The results from this study provided an understanding of the regional patterns in surface-water nutrient conditions and should be useful to researchers and water-quality managers performing local nutrient assessments.

Developement of watershed and reference loads for a TMDL in Charleston Harbor System, SC.

Treesearch

Silong Lu; Devenra Amatya; Jamie Miller

2005-01-01

It is essential to determine point and non-point source loads and their distribution for development of a dissolved oxygen (DO) Total Maximum Daily Load (TMDL). A series of models were developed to assess sources of oxygen-demand loadings in Charleston Harbor, South Carolina. These oxygen-demand loadings included nutrients and BOD. Stream flow and nutrient...

Policy Guidance From a Multi-scale Suite of Natural Field and Digital Laboratories of Change: Hydrological Catchment Studies of Nutrient and Pollutant Source Releases, Waterborne Transport-Transformations and Mass Flows in Water Ecosystems

NASA Astrophysics Data System (ADS)

Destouni, G.

2008-12-01

Continental fresh water transports and loads excess nutrients and pollutants from various land surface sources, through the landscape, into downstream inland and coastal water environments. Our ability to understand, predict and control the eutrophication and the pollution pressures on inland, coastal and marine water ecosystems relies on our ability to quantify these mass flows. This paper synthesizes a series of hydro- biogeochemical studies of nutrient and pollutant sources, transport-transformations and mass flows in catchment areas across a range of scales, from continental, through regional and national, to individual drainage basin scales. Main findings on continental scales include correlations between country/catchment area, population and GDP and associated pollutant and nutrient loading, which differ significantly between world regions with different development levels. On regional scales, essential systematic near-coastal gaps are identified in the national monitoring of nutrient and pollutant loads from land to the sea. Combination of the unmonitored near-coastal area characteristics with the relevant regional nutrient and pollutant load correlations with these characteristics shows that the unmonitored nutrient and pollutant mass loads to the sea may often be as large as, or greater than the monitored river loads. Process studies on individual basin- scales show long-term nutrient and pollutant memories in the soil-groundwater systems of the basins, which may continue to uphold large mass loading to inland and coastal waters long time after mitigation of the sources. Linked hydro-biogeochemical-economic model studies finally demonstrate significant comparative advantages of policies that demand explicit quantitative account of the uncertainties implied by these monitoring gaps and long-term nutrient-pollution memories and time lags, and other knowledge, data and model limitations, instead of the now common neglect or subjective implicit handling of such uncertainties in strategies and practices for combating water pollution and eutrophication.

Which offers more scope to suppress river phytoplankton blooms: reducing nutrient pollution or riparian shading?

PubMed

Hutchins, M G; Johnson, A C; Deflandre-Vlandas, A; Comber, S; Posen, P; Boorman, D

2010-10-01

River flow and quality data, including chlorophyll-a as a surrogate for river phytoplankton biomass, were collated for the River Ouse catchment in NE England, which according to established criteria is a largely unpolluted network. Against these data, a daily river quality model (QUESTOR) was setup and successfully tested. Following a review, a river quality classification scheme based on phytoplankton biomass was proposed. Based on climate change predictions the model indicated that a shift from present day oligotrophic/mesotrophic conditions to a mesotrophic/eutrophic system could occur by 2080. Management options were evaluated to mitigate against this predicted decline in quality. Reducing nutrient pollution was found to be less effective at suppressing phytoplankton growth than the less costly option of establishing riparian shading. In the Swale tributary, ongoing efforts to reduce phosphorus loads in sewage treatment works will only reduce peak (95th percentile) phytoplankton by 11%, whereas a reduction of 44% is possible if riparian tree cover is also implemented. Likewise, in the Ure, whilst reducing nitrate loads by curtailing agriculture in the headwaters may bring about a 10% reduction, riparian shading would instead reduce levels by 47%. Such modelling studies are somewhat limited by insufficient field data but offer a potentially very valuable tool to assess the most cost-effective methods of tackling effects of eutrophication. Copyright 2010 Elsevier B.V. All rights reserved.

Up-to-date modification of the anaerobic sludge digestion process introducing a separate sludge digestion mode.

PubMed

Sato, K; Ochi, S; Mizuochi, M

2001-01-01

Sewage treatment plants in Japan are subjected to advanced treatment to remove nutrients and hence control eutrophication problems in lakes and bays. This paper discusses the advantages and disadvantages of the separate digestion treatment mode for sludge generated from advanced wastewater treatment. In the separate digestion only primary sludge is digested and the excess activated sludge is directly dewatered. Separate digestion can reduce the return load of nutrients to approximately one third, and has major potential for the beneficial use of sludge.

Nutrient enrichment enhances black band disease progression in corals

NASA Astrophysics Data System (ADS)

Voss, Joshua D.; Richardson, Laurie L.

2006-11-01

Infectious diseases are recognized as significant contributors to the dramatic loss of corals observed worldwide. However, the causes of increased coral disease prevalence and severity are not well understood. One potential factor is elevated nutrient concentration related to localized anthropogenic activities such as inadequate waste water treatment or terrestrial runoff. In this study the effect of nutrient enrichment on the progression of black band disease (BBD) was investigated using both in situ and laboratory experiments. Experimental increases in localized nutrient availability using commercial time release fertilizer in situ resulted in doubling of BBD progression and coral tissue loss in the common reef framework coral Siderastrea siderea. Laboratory experiments in which artificially infected S. siderea colonies were exposed to increased nitrate concentrations (up to 3 μM) demonstrated similar increases in BBD progression. These findings provide evidence that the impacts of this disease on coral populations are exacerbated by nutrient enrichment and that management to curtail excess nutrient loading may be important for reducing coral cover loss due to BBD.

Time-scale Dependence of Response of an Estuarine Water Quality Model to Nutrient Loading

EPA Science Inventory

We describe calibration and evaluation of a water quality model being implemented for Narragansett Bay to quantify the response of concentrations of nutrients, phytoplankton chlorophyll a and dissolved oxygen in the Bay to loading rates of nutrients and other boundary conditions....

EFFECTS OF NUTRIENT LOADING ON BIOGEOCHEMICAL AND MICROBIAL PROCESSES IN A NEW ENGLAND SALT MARSH

EPA Science Inventory

Coastal marshes represent an important transitional zone between uplands and estuaries. One important function of marshes is to assimilate nutrient inputs from uplands, thus providing a buffer for anthropogenic nutrient loads. We examined the effects of nitrogen (N) and phosphoru...

Estimates of long-term mean-annual nutrient loads considered for use in SPARROW models of the Midcontinental region of Canada and the United States, 2002 base year

USGS Publications Warehouse

Saad, David A.; Benoy, Glenn A.; Robertson, Dale M.

2018-05-11

Streamflow and nutrient concentration data needed to compute nitrogen and phosphorus loads were compiled from Federal, State, Provincial, and local agency databases and also from selected university databases. The nitrogen and phosphorus loads are necessary inputs to Spatially Referenced Regressions on Watershed Attributes (SPARROW) models. SPARROW models are a way to estimate the distribution, sources, and transport of nutrients in streams throughout the Midcontinental region of Canada and the United States. After screening the data, approximately 1,500 sites sampled by 34 agencies were identified as having suitable data for calculating the long-term mean-annual nutrient loads required for SPARROW model calibration. These final sites represent a wide range in watershed sizes, types of nutrient sources, and land-use and watershed characteristics in the Midcontinental region of Canada and the United States.

Concentrations and estimated loads of nutrients, mercury, and polychlorinated biphenyls in selected tributaries to Lake Michigan, 2005-6

USGS Publications Warehouse

Westenbroek, Stephen M.

2010-01-01

The Lake Michigan Mass Balance Project (LMMBP) measured and modeled the concentrations of environmentally persistent contaminants in air, river and lake water, sediment, and fish and bird tissues in and around Lake Michigan for an 18-month period spanning 1994-95. Tributary loads were calculated as part of the LMMBP. The work described in this report was designed to provide updated concentration data and load estimates for 5 nutrients, total mercury, and total polychlorinated biphenyl (PCB) at 5 of the original 11 LMMBP sampling sites. Samples were collected at five Lake Michigan tributary monitoring sites during 2005 and 2006. Annual loads calculated for the 2005-6 sampling period are as much as 50 percent lower relative to the 1994-95 time period. Differences between the loads calculated for the two time periods are likely related to a combination of (1) biases introduced by a reduced level of sampling effort, (2) differences in hydrological characteristics, and (3) actual environmental change. Estimated annual total mercury loads during 2005-6 ranged from 51 kilograms per year (kg/yr) in the Fox River to 2.2 kg/yr in the Indiana Harbor and Ship Canal. Estimated annual total PCB loads during 2005-6 ranged from 132 kg/yr in the Fox River to 6.2 kg/yr in the Grand River.

Exponential Nutrient Loading as a Means to Optimize Bareroot Nursery Fertility of Oak Species

Treesearch

Zonda K. D. Birge; Douglass F. Jacobs; Francis K. Salifu

2006-01-01

Conventional fertilization in nursery culture of hardwoods may involve supply of equal fertilizer doses at regularly spaced intervals during the growing season, which may create a surplus of available nutrients in the beginning and a deficiency in nutrient availability by the end of the growing season. A method of fertilization termed “exponential nutrient loading” has...

Advances in fertilization for hardwood regeneration

Treesearch

Douglass F. Jacobs

2013-01-01

Optimizing fertilization programs in the nursery and field may help improve regeneration and restoration of temperate deciduous hardwoods. Our research program has demonstrated the applicability of nutrient loading in fine hardwood systems to promote seedling uptake and storage of nutrients during the nursery phase. We also have shown the benefits of nutrient loading...

A multi-agency nutrient dataset used to estimate loads, improve monitoring design, and calibrate regional nutrient SPARROW models

USGS Publications Warehouse

Saad, David A.; Schwarz, Gregory E.; Robertson, Dale M.; Booth, Nathaniel

2011-01-01

Stream-loading information was compiled from federal, state, and local agencies, and selected universities as part of an effort to develop regional SPAtially Referenced Regressions On Watershed attributes (SPARROW) models to help describe the distribution, sources, and transport of nutrients in streams throughout much of the United States. After screening, 2,739 sites, sampled by 73 agencies, were identified as having suitable data for calculating long-term mean annual nutrient loads required for SPARROW model calibration. These sites had a wide range in nutrient concentrations, loads, and yields, and environmental characteristics in their basins. An analysis of the accuracy in load estimates relative to site attributes indicated that accuracy in loads improve with increases in the number of observations, the proportion of uncensored data, and the variability in flow on observation days, whereas accuracy declines with increases in the root mean square error of the water-quality model, the flow-bias ratio, the number of days between samples, the variability in daily streamflow for the prediction period, and if the load estimate has been detrended. Based on compiled data, all areas of the country had recent declines in the number of sites with sufficient water-quality data to compute accurate annual loads and support regional modeling analyses. These declines were caused by decreases in the number of sites being sampled and data not being entered in readily accessible databases.

Nutrient loads of small-scale swine manure composting to groundwater and its prevention by covering: a case study.

PubMed

Cheng, Jianbo; Qiao, Junjing; Chen, Yucheng; Yang, Zhimin

2015-10-01

Small-scale composting is applied to recycle manure and biomass around the globe. Piles frequently site outside near field where bio-waste comes or compost goes within developing rural regions. However, little equipment or policy besides cover of common materials addressed concerns about its exposure to rainfall and subsequent leachate towards groundwater. In addition, little is known about its nutrient load to groundwater and covers' effect on nutrient unloading. Differently covered swine manure piles were composted outdoors with exposure to rain, then columns consisted of resultant compost of varying maturing age and soil were leached by simulated rainfall. Leachate TN, NH4 (+)-N, NO3 (-)-N, TP, and DP were modeled by regression analysis, and further, integral of quadratic curve or nutrient load index (NLI) was designated as proxy for nutrient load. Log response ratio was employed to qualify covers' effect on nutrient unloading. This case raised higher concern about leachate NH4 (+)-N than NO3 (-)-N for former's lower category in groundwater quality standard. The integrated NLIs or general nutrient load for six intervals, averagely divided from composting day of 60-120, decreased by 31, 37, 45, 56, and 73 % consecutively. Covers could unload nutrient to underground and function better to prevent P than N from leaching. Capabilities of piles covered by rice straw (CR) and soil (CS) to unload respectively are 77 and 72 % of by film (CF).

Modeling nutrient release in the Tai Lake basin of China: source identification and policy implications.

PubMed

Liu, Beibei; Liu, Heng; Zhang, Bing; Bi, Jun

2013-03-01

Because nutrient enrichment has become increasingly severe in the Tai Lake Basin of China, identifying sources and loads is crucial for watershed nutrient management. This paper develops an empirical framework to estimate nutrient release from five major sectors, which requires fewer input parameters and produces acceptable accuracy. Sectors included are industrial manufacturing, livestock breeding (industrial and family scale), crop agriculture, household consumption (urban and rural), and atmospheric deposition. Results show that in the basin (only the five sectors above), total nutrient loads of nitrogen (N) and phosphorus (P) into aquatic systems in 2008 were 33043.2 tons N a(-1) and 5254.4 tons P a(-1), and annual area-specific nutrient loads were 1.94 tons N km(-2) and 0.31 tons P km(-2). Household consumption was the major sector having the greatest impact (46 % in N load, 47 % in P load), whereas atmospheric deposition (18 %) and crop agriculture (15 %) sectors represented other significant proportions of N load. The load estimates also indicate that 32 % of total P came from the livestock breeding sector, making it the second largest phosphorus contributor. According to the nutrient pollution sectors, six best management practices are selected for cost-effectiveness analysis, and feasible options are recommended. Overall, biogas digester construction on industrial-scale farms is proven the most cost-effective, whereas the building of rural decentralized facilities is the best alternative under extreme financial constraint. However, the reduction potential, average monetary cost, and other factors such as risk tolerance of policy makers should all be considered in the actual decision-making process.

Relation of nutrient concentrations, nutrient loading, and algal production to changes in water levels in Kabetogama Lake, Voyageurs National Park, northern Minnesota, 2008-09

USGS Publications Warehouse

Christensen, Victoria G.; Maki, Ryan P.; Kiesling, Richard L.

2011-01-01

Nutrient enrichment has led to excessive algal growth in Kabetogama Lake, Voyageurs National Park, northern Minnesota. Water- and sediment-quality data were collected during 2008-09 to assess internal and external nutrient loading. Data collection was focused in Kabetogama Lake and its inflows, the area of greatest concern for eutrophication among the lakes of Voyageurs National Park. Nutrient and algal data were used to determine trophic status and were evaluated in relation to changes in Kabetogama Lake water levels following changes to dam operation starting in 2000. Analyses were used to estimate external nutrient loading at inflows and assess the potential contribution of internal phosphorus loading. Kabetogama Lake often was mixed vertically, except for a few occasionally stratified areas, including Lost Bay in the northeastern part of Kabetogama Lake. Stratification, combined with larger bottom-water nutrient concentrations, larger sediment phosphorus concentrations, and estimated phosphorus release rates from sediment cores indicate that Lost Bay may be one of several areas that may be contributing substantially to internal loading. Internal loading is a concern because nutrients may cause excessive algal growth including potentially toxic cyanobacteria. The cyanobacterial hepatotoxin, microcystin, was detected in 7 of 14 cyanobacterial bloom samples, with total concentrations exceeding 1.0 microgram per liter, the World Health Organization's guideline for finished drinking water for the congener, microcystin-LR. Comparisons of the results of this study to previous studies indicate that chlorophyll-a concentrations and trophic state indices have improved since 2000, when the rules governing dam operation changed. However, total-phosphorus concentrations have not changed significantly since 2000.

Weak and Habitat-Dependent Effects of Nutrient Pollution on Macrofaunal Communities of Southeast Australian Estuaries

PubMed Central

Nicastro, Andrea; Bishop, Melanie J.

2013-01-01

Among the impacts of coastal settlements to estuaries, nutrient pollution is often singled out as a leading cause of modification to the ecological communities of soft sediments. Through sampling of 48 sites, distributed among 16 estuaries of New South Wales, Australia, we tested the hypotheses that (1) anthropogenic nutrient loads would be a better predictor of macrofaunal communities than estuarine geomorphology or local sediment characteristics; and (2) local environmental context, as determined largely by sediment characteristics, would modify the relationship between nutrient loading and community composition. Contrary to the hypothesis, multivariate multiple regression analyses revealed that sediment grain size was the best predictor of macrofaunal assemblage composition. When samples were stratified according to median grain size, relationships between faunal communities and nitrogen loading and latitude emerged, but only among estuaries with sandier sediments. In these estuaries, capitellid and nereid polychaetes and chironomid larvae were the taxa that showed the strongest correlations with nutrient loading. Overall, this study failed to provide evidence of a differential relationship between diffuse nutrient enrichment and benthic macrofauna across a gradient of 7° of latitude and 4°C temperature. Nevertheless, as human population growth continues to place increasing pressure on southeast Australian estuaries, manipulative field studies examining when and where nutrient loading will lead to significant changes in estuarine community structure are needed. PMID:23799037

Fifteen-year study of environmental dredging effect on variation of nitrogen and phosphorus exchange across the sediment-water interface of an urban lake.

PubMed

Liu, Cheng; Zhong, Jicheng; Wang, Jianjun; Zhang, Lu; Fan, Chengxin

2016-12-01

Environmental dredging has been applied widely in Chinese lakes to reduce their internal nutrient loads. However, the efficacy of dredging to reduce internal loading of nitrogen (N) and phosphorus (P) and to improve water quality has been questioned by some researchers. In this study, the long-term (∼15 years) effects of dredging to reduce internal N and P loading in a closed, polluted urban lake were investigated. The results showed that the release of soluble reactive phosphorus (SRP) could be suppressed quickly after dredging, and that the dredging effect was sustained for about 18 months. A significant release of NH 4 + -N was discovered during the first 2-8 months after dredging, followed by maintenance of low-level release rates for about 21-32 months. The continuous inflowing of external pollution loading led to the increase in the release rates of SRP and NH 4 + -N. The external pollution loading was therefore reduced three years after dredging to strengthen the remediation effect. After that, high diffusive flux from the sediment was observed for both NH 4 + -N and SRP during summer seasons for about six years, followed by a decreasing trend. The NH 4 + -N concentration in the overlying water was reduced after the reduction of external loading, while a high concentration of SRP in the overlying water was still observed during summer seasons. In conclusion, the mid-term (<3 years) reduction of internal N and P loading could be achieved by dredging if the external pollution loading were not reduced. Achieving long-term control would require modification of external loading. Copyright © 2016 Elsevier Ltd. All rights reserved.

Nutrient Mass Balance for the Mobile River Basin in Alabama, Georgia, and Mississippi

NASA Astrophysics Data System (ADS)

Harned, D. A.; Harvill, J. S.; McMahon, G.

2001-12-01

The source and fate of nutrients in the Mobile River drainage basin are important water-quality concerns in Alabama, Georgia, and Mississippi. Land cover in the basin is 74 percent forested, 16 percent agricultural, 2.5 percent developed, and 4 percent wetland. A nutrient mass balance calculated for 18 watersheds in the Mobile River Basin indicates that agricultural non-point nitrogen and phosphorus sources and urban non-point nitrogen sources are the most important factors associated with nutrients in the streams. Nitrogen and phosphorus inputs from atmospheric deposition, crop fertilizer, biological nitrogen fixation, animal waste, and point sources were estimated for each of the 18 drainage basins. Total basin nitrogen inputs ranged from 27 to 93 percent from atmospheric deposition (56 percent mean), 4 to 45 percent from crop fertilizer (25 percent mean), <0.01 to 31 percent from biological nitrogen fixation (8 percent mean), 2 to 14 percent from animal waste (8 percent mean), and 0.2 to 11 percent from point sources (3 percent mean). Total basin phosphorus inputs ranged from 10 to 39 percent from atmospheric deposition (26 percent mean), 7 to 51 percent from crop fertilizer (28 percent mean), 20 to 64 percent from animal waste (41 percent mean), and 0.2 to 11 percent from point sources (3 percent mean). Nutrient outputs for the watersheds were estimated by calculating instream loads and estimating nutrient uptake, or withdrawal, by crops. The difference between the total basin inputs and outputs represents nutrients that are retained or processed within the basin while moving from the point of use to the stream, or in the stream. Nitrogen output, as a percentage of the total basin nitrogen inputs, ranged from 19 to 79 percent for instream loads (35 percent mean) and from 0.01 to 32 percent for crop harvest (10 percent mean). From 53 to 87 percent (75 percent mean) of nitrogen inputs were retained within the 18 basins. Phosphorus output ranged from 9 to 29 percent for instream loads (18 percent mean) and from 0.01 to 23 percent for crop harvest (7 percent mean). The basins retained from 60 to 87 percent (74 percent mean) of phosphorous inputs. Correlation of basin nutrient output loads and concentrations with the basin inputs and correlation of output loads and concentrations with basin land use were tested using the Spearman rank test. The correlation analysis indicated that higher nitrogen concentrations in the streams are associated with urban areas and higher loads are associated with agriculture; high phosphorus output loads and concentrations are associated with agriculture. Higher nutrient loads in agricultural basins are partly an effect of basin size-- larger basins generate larger nutrient loads. Nutrient loads and concentrations showed no significant correlation to point-source inputs. Nitrogen loads were significantly (p<0.05, correlation coefficient >0.5) higher in basins with greater cropland areas. Nitrogen concentrations also increased as residential, commercial, and total urban areas increased. Phosphorus loads were positively correlated with animal-waste inputs, pasture, and total agricultural land. Phosphorus concentrations were highest in basins with the greatest amounts of row-crop agriculture.

Prescription Fire and Anion Retention in Tahoe Forest Soils

USDA-ARS?s Scientific Manuscript database

Prescribed burning is a possible option to reduce fire potential in the Lake Tahoe Basin (California and Nevada). However, subsequent nutrient loading to the lake is a major concern. The effect of residual ash on anion leaching, primarily O-PO4 and SO42-, was studied in both the field and laboratory...

Pathways of nutrient loading and impacts on plant diversity in a New York peatland

USGS Publications Warehouse

Drexler, J.Z.; Bedford, B.L.

2002-01-01

Nutrient loading is a subtle, yet serious threat to the preservation of high diversity wetlands such as peatlands. Pathways of nutrient loading and impacts on plant diversity in a small peatland in New York State, USA were determined by collecting and analyzing a suite of hydrogeological, hydro-chemical, soil, and vegetation data. Piezometer clusters within an intensive network constituted hydro-chemical sampling points and focal points for randomly selected vegetation quadrats and soil-coring locations. Hydrogeological data and nutrient analyses showed that P and K loading occurred chiefly by means of overland flow from an adjacent farm field, whereas N loading occurred predominantly through ground-water flow from the farm field. Redundancy analysis and polynomial regression showed that nutrients, particularly total P in peat, total K in peat, extractable NH4-N, and NO3-N flux in ground water, were strongly negatively correlated with plant diversity measures at the site. No other environmental variables except vegetation measures associated with eutrophication demonstrated such a strong relationship with plant diversity. Nitrate loading over 4 mg m -2 day-1 was associated with low plant diversity, and Ca fluxes between 80 and 130 mg m-2 day-1 were associated with high plant diversity. Areas in the site with particularly low vascular plant and bryophyte species richness and Shannon-Wiener diversity (H') occurred adjacent to the farm field and near a hillside spring. High H' and species richness of vascular plants and bryophytes occurred in areas that were further removed from agriculture, contained no highly dominant vegetation, and were situated directly along the ground-water flow paths of springs. These areas were characterized by relatively constant water levels and consistent, yet moderate fluxes of base cations and nutrients. Overall, this study demonstrates that knowledge of site hydrogeology is crucial for determining potential pathways of nutrient loading and for developing relationships between nutrient inflows and wetland plant diversity. ?? 2002, The Society of Wetland Scientists.

Surface-water nutrient conditions and sources in the United States Pacific Northwest

USGS Publications Warehouse

Wise, D.R.; Johnson, H.M.

2011-01-01

The SPAtially Referenced Regressions On Watershed attributes (SPARROW) model was used to perform an assessment of surface-water nutrient conditions and to identify important nutrient sources in watersheds of the Pacific Northwest region of the United States (U.S.) for the year 2002. Our models included variables representing nutrient sources as well as landscape characteristics that affect nutrient delivery to streams. Annual nutrient yields were higher in watersheds on the wetter, west side of the Cascade Range compared to watersheds on the drier, east side. High nutrient enrichment (relative to the U.S. Environmental Protection Agency's recommended nutrient criteria) was estimated in watersheds throughout the region. Forest land was generally the largest source of total nitrogen stream load and geologic material was generally the largest source of total phosphorus stream load generated within the 12,039 modeled watersheds. These results reflected the prevalence of these two natural sources and the low input from other nutrient sources across the region. However, the combined input from agriculture, point sources, and developed land, rather than natural nutrient sources, was responsible for most of the nutrient load discharged from many of the largest watersheds. Our results provided an understanding of the regional patterns in surface-water nutrient conditions and should be useful to environmental managers in future water-quality planning efforts.

NUTRIENT LOADING EFFECTS ON BIOGEOCHEMICAL AND MICROBIAL PROCESSES IN A NEW ENGLAND HIGH SALT MARCH (SPARTINA PATENS)

EPA Science Inventory

An ever-increasing population in the coastal zone has led to increased nutrient loading to estuaries worldwide. Marshes represent an important transitional zone between uplands and estuaries and can intercept nutrient inputs from uplands. We examined the effects of N and P fertil...

EFFECTS OF NUTRIENT LOADING ON BIOGEOCHEMICAL AND MICROBIAL PROCESSES IN A NEW ENGLAND HIGH SALT MARCH (SPARTINA PATENS)

EPA Science Inventory

An ever-increasing population in the coastal zone has led to increased nutrient loading to estuaries worldwide. Marshes represent an important transitional zone between uplands and estuaries and can intercept nutrient inputs from uplands. We examined the effects of N and P fertil...

Managed nutrient reduction impacts on nutrient concentrations, water clarity, primary production, and hypoxia in a north temperate estuary

NASA Astrophysics Data System (ADS)

Oviatt, Candace; Smith, Leslie; Krumholz, Jason; Coupland, Catherine; Stoffel, Heather; Keller, Aimee; McManus, M. Conor; Reed, Laura

2017-12-01

Except for the Providence River and side embayments like Greenwich Bay, Narragansett Bay can no longer be considered eutrophic. In summer 2012 managed nitrogen treatment in Narragansett Bay achieved a goal of reducing effluent dissolved inorganic nitrogen inputs by over 50%. Narragansett Bay represents a small northeast US estuary that had been heavily loaded with sewage effluent nutrients since the late 1800s. The input reduction was reflected in standing stock nutrients resulting in a statistically significant 60% reduction in concentration. In the Providence River estuary, total nitrogen decreased from 100 μm to about 40 μm, for example. We tested four environmental changes that might be associated with the nitrogen reduction. System apparent production was significantly decreased by 31% and 45% in the upper and mid Bay. Nutrient reductions resulted in statistically improved water clarity in the mid and upper Bay and in a 34% reduction in summer hypoxia. Nitrogen reduction also reduced the winter spring diatom bloom; winter chlorophyll levels after nutrient reduction have been significantly lower than before the reduction. The impact on the Bay will continue to evolve over the next few years and be a natural experiment for other temperate estuaries that will be experiencing nitrogen reduction. To provide perspective we review factors effecting hypoxia in other estuaries with managed nutrient reduction and conclude that, as in Narragansett Bay, physical factors can be as important as nutrients. On a positive note managed nutrient reduction has mitigated further deterioration in most estuaries.

Ecosystem responses to long-term nutrient management in an urban estuary: Tampa Bay, Florida, USA

NASA Astrophysics Data System (ADS)

Greening, H.; Janicki, A.; Sherwood, E. T.; Pribble, R.; Johansson, J. O. R.

2014-12-01

In subtropical Tampa Bay, Florida, USA, we evaluated restoration trajectories before and after nutrient management strategies were implemented using long-term trends in nutrient loading, water quality, primary production, and seagrass extent. Following citizen demands for action, reduction in wastewater nutrient loading of approximately 90% in the late 1970s lowered external total nitrogen (TN) loading by more than 50% within three years. Continuing nutrient management actions from public and private sectors were associated with a steadily declining TN load rate and with concomitant reduction in chlorophyll-a concentrations and ambient nutrient concentrations since the mid-1980s, despite an increase of more than 1 M people living within the Tampa Bay metropolitan area. Water quality (chlorophyll-a concentration, water clarity as indicated by Secchi disk depth, total nitrogen concentration and dissolved oxygen) and seagrass coverage are approaching conditions observed in the 1950s, before the large increases in human population in the watershed. Following recovery from an extreme weather event in 1997-1998, water clarity increased significantly and seagrass is expanding at a rate significantly different than before the event, suggesting a feedback mechanism as observed in other systems. Key elements supporting the nutrient management strategy and concomitant ecosystem recovery in Tampa Bay include: 1) active community involvement, including agreement about quantifiable restoration goals; 2) regulatory and voluntary reduction in nutrient loadings from point, atmospheric, and nonpoint sources; 3) long-term water quality and seagrass extent monitoring; and 4) a commitment from public and private sectors to work together to attain restoration goals. A shift from a turbid, phytoplankton-based system to a clear water, seagrass-based system that began in the 1980s following comprehensive nutrient loading reductions has resulted in a present-day Tampa Bay which looks and functions much like it did in the relatively pre-disturbance 1950s period.

THE RELATIONSHIP BETWEEN LAND-BASED NITROGEN LOADING AND EELGRASS EXTENT FOR EMBAYMENTS IN SOUTHERN NEW ENGLAND: INITIAL MODEL CONSTRUCTION

EPA Science Inventory

This report outlines research results of the US EPA Atlantic Ecology Division in fulfilling the National Health and Environmental Effects Laboratory's Aquatic Stressors Nutrient Program's charge to develop nutrient load-ecological response models useful in setting loading limits ...

Methods for Estimating Annual Wastewater Nutrient Loads in the Southeastern United States

USGS Publications Warehouse

McMahon, Gerard; Tervelt, Larinda; Donehoo, William

2007-01-01

This report describes an approach for estimating annual total nitrogen and total phosphorus loads from point-source dischargers in the southeastern United States. Nutrient load estimates for 2002 were used in the calibration and application of a regional nutrient model, referred to as the SPARROW (SPAtially Referenced Regression On Watershed attributes) watershed model. Loads from dischargers permitted under the National Pollutant Discharge Elimination System were calculated using data from the U.S. Environmental Protection Agency Permit Compliance System database and individual state databases. Site information from both state and U.S. Environmental Protection Agency databases, including latitude and longitude and monitored effluent data, was compiled into a project database. For sites with a complete effluent-monitoring record, effluent-flow and nutrient-concentration data were used to develop estimates of annual point-source nitrogen and phosphorus loads. When flow data were available but nutrient-concentration data were missing or incomplete, typical pollutant-concentration values of total nitrogen and total phosphorus were used to estimate load. In developing typical pollutant-concentration values, the major factors assumed to influence wastewater nutrient-concentration variability were the size of the discharger (the amount of flow), the season during which discharge occurred, and the Standard Industrial Classification code of the discharger. One insight gained from this study is that in order to gain access to flow, concentration, and location data, close communication and collaboration are required with the agencies that collect and manage the data. In addition, the accuracy and usefulness of the load estimates depend on the willingness of the states and the U.S. Environmental Protection Agency to provide guidance and review for at least a subset of the load estimates that may be problematic.

Nutrient supply and mercury dynamics in marine ecosystems: A conceptual model

PubMed Central

Chen, Celia Y.; Hammerschmidt, Chad R.; Mason, Robert P.; Gilmour, Cynthia C.; Sunderland, Elsie M.; Greenfield, Ben K.; Buckman, Kate L.; Lamborg, Carl H.

2013-01-01

There is increasing interest and concern over the impacts of mercury (Hg) inputs to marine ecosystems. One of the challenges in assessing these effects is that the cycling and trophic transfer of Hg are strongly linked to other contaminants and disturbances. In addition to Hg, a major problem facing coastal waters is the impacts of elevated nutrient, particularly nitrogen (N), inputs. Increases in nutrient loading alter coastal ecosystems in ways that should change the transport, transformations and fate of Hg, including increases in fixation of organic carbon and deposition to sediments, decreases in the redox status of sediments and changes in fish habitat. In this paper we present a conceptual model which suggests that increases in loading of reactive N to marine ecosystems might alter Hg dynamics, decreasing bioavailabilty and trophic transfer. This conceptual model is most applicable to coastal waters, but may also be relevant to the pelagic ocean. We present information from case studies that both support and challenge this conceptual model, including marine observations across a nutrient gradient; results of a nutrient-trophic transfer Hg model for pelagic and coastal ecosystems; observations of Hg species, and nutrients from coastal sediments in the northeastern U.S.; and an analysis of fish Hg concentrations in estuaries under different nutrient loadings. These case studies suggest that changes in nutrient loading can impact Hg dynamics in coastal and open ocean ecosystems. Unfortunately none of the case studies is comprehensive; each only addresses a portion of the conceptual model and has limitations. Nevertheless, our conceptual model has important management implications. Many estuaries near developed areas are impaired due to elevated nutrient inputs. Widespread efforts are underway to control N loading and restore coastal ecosystem function. An unintended consequence of nutrient control measures could be to exacerbate problems associated with Hg contamination. Additional focused research and monitoring are needed to critically examine the link between nutrient supply and Hg contamination of marine waters. PMID:22749872

Nutrient supply and mercury dynamics in marine ecosystems: a conceptual model.

PubMed

Driscoll, Charles T; Chen, Celia Y; Hammerschmidt, Chad R; Mason, Robert P; Gilmour, Cynthia C; Sunderland, Elsie M; Greenfield, Ben K; Buckman, Kate L; Lamborg, Carl H

2012-11-01

There is increasing interest and concern over the impacts of mercury (Hg) inputs to marine ecosystems. One of the challenges in assessing these effects is that the cycling and trophic transfer of Hg are strongly linked to other contaminants and disturbances. In addition to Hg, a major problem facing coastal waters is the impacts of elevated nutrient, particularly nitrogen (N), inputs. Increases in nutrient loading alter coastal ecosystems in ways that should change the transport, transformations and fate of Hg, including increases in fixation of organic carbon and deposition to sediments, decreases in the redox status of sediments and changes in fish habitat. In this paper we present a conceptual model which suggests that increases in loading of reactive N to marine ecosystems might alter Hg dynamics, decreasing bioavailabilty and trophic transfer. This conceptual model is most applicable to coastal waters, but may also be relevant to the pelagic ocean. We present information from case studies that both support and challenge this conceptual model, including marine observations across a nutrient gradient; results of a nutrient-trophic transfer Hg model for pelagic and coastal ecosystems; observations of Hg species, and nutrients from coastal sediments in the northeastern U.S.; and an analysis of fish Hg concentrations in estuaries under different nutrient loadings. These case studies suggest that changes in nutrient loading can impact Hg dynamics in coastal and open ocean ecosystems. Unfortunately none of the case studies is comprehensive; each only addresses a portion of the conceptual model and has limitations. Nevertheless, our conceptual model has important management implications. Many estuaries near developed areas are impaired due to elevated nutrient inputs. Widespread efforts are underway to control N loading and restore coastal ecosystem function. An unintended consequence of nutrient control measures could be to exacerbate problems associated with Hg contamination. Additional focused research and monitoring are needed to critically examine the link between nutrient supply and Hg contamination of marine waters. Copyright © 2012 Elsevier Inc. All rights reserved.

Macro-grazer herbivory regulates seagrass response to pulse and press nutrient loading.

PubMed

Ravaglioli, Chiara; Capocchi, Antonella; Fontanini, Debora; Mori, Giovanna; Nuccio, Caterina; Bulleri, Fabio

2018-05-01

Coastal ecosystems are exposed to multiple stressors. Predicting their outcomes is complicated by variations in their temporal regimes. Here, by means of a 16-month experiment, we investigated tolerance and resistance traits of Posidonia oceanica to herbivore damage under different regimes of nutrient loading. Chronic and pulse nutrient supply were combined with simulated fish herbivory, treated as a pulse stressor. At ambient nutrient levels, P. oceanica could cope with severe herbivory, likely through an increase in photosynthetic activity. Elevated nutrient levels, regardless of the temporal regime, negatively affected plant growth and increased leaf nutritional quality. This ultimately resulted in a reduction of plant biomass that was particularly severe under chronic fertilization. Our results suggest that both chronic and pulse nutrient loadings increase plant palatability to macro-grazers. Strategies for seagrass management should not be exclusively applied in areas exposed to chronic fertilization since even short-term nutrient pulses could alter seagrass meadows. Copyright © 2018 Elsevier Ltd. All rights reserved.

High-frequency monitoring of water fluxes and nutrient loads to assess the effects of controlled drainage on water storage and nutrient transport

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rozemeijer, J. C.; Visser, A.; Borren, W.

High nitrogen (N) and phosphorus (P) fluxes from upstream agriculture threaten aquatic ecosystems in surface waters and estuaries, especially in areas characterized by high agricultural N and P inputs and densely drained catchments like the Netherlands. Controlled drainage has been recognized as an effective option to optimize soil moisture conditions for agriculture and to reduce unnecessary losses of fresh water and nutrients. This is achieved by introducing control structures with adjustable overflow levels into subsurface tube drain systems. A small-scale (1 ha) field experiment was designed to investigate the hydrological and chemical changes after introducing controlled drainage. Precipitation rates andmore » the response of water tables and drain fluxes were measured in the periods before the introduction of controlled drainage (2007–2008) and after (2009–2011). For the N and P concentration measurements, auto-analyzers for continuous records were combined with passive samplers for time-averaged concentrations at individual drain outlets. The experimental setup enabled the quantification of changes in the water and solute balance after introducing controlled drainage. The results showed that introducing controlled drainage reduced the drain discharge and increased the groundwater storage in the field. To achieve this, the overflow levels have to be elevated in early spring, before the drain discharge stops due to dryer conditions and falling groundwater levels. The groundwater storage in the field would have been larger if the water levels in the adjacent ditch were controlled as well by an adjustable weir. The N concentrations and loads increased, which was largely related to elevated concentrations in one of the three monitored tube drains. The P loads via the tube drains reduced due to the reduction in discharge after introducing controlled drainage. Furthermore, this may be counteracted by the higher groundwater levels and the larger contribution of N- and P-rich shallow groundwater and overland flow to the surface water.« less

High-frequency monitoring of water fluxes and nutrient loads to assess the effects of controlled drainage on water storage and nutrient transport

DOE PAGES

Rozemeijer, J. C.; Visser, A.; Borren, W.; ...

2016-01-19

High nitrogen (N) and phosphorus (P) fluxes from upstream agriculture threaten aquatic ecosystems in surface waters and estuaries, especially in areas characterized by high agricultural N and P inputs and densely drained catchments like the Netherlands. Controlled drainage has been recognized as an effective option to optimize soil moisture conditions for agriculture and to reduce unnecessary losses of fresh water and nutrients. This is achieved by introducing control structures with adjustable overflow levels into subsurface tube drain systems. A small-scale (1 ha) field experiment was designed to investigate the hydrological and chemical changes after introducing controlled drainage. Precipitation rates andmore » the response of water tables and drain fluxes were measured in the periods before the introduction of controlled drainage (2007–2008) and after (2009–2011). For the N and P concentration measurements, auto-analyzers for continuous records were combined with passive samplers for time-averaged concentrations at individual drain outlets. The experimental setup enabled the quantification of changes in the water and solute balance after introducing controlled drainage. The results showed that introducing controlled drainage reduced the drain discharge and increased the groundwater storage in the field. To achieve this, the overflow levels have to be elevated in early spring, before the drain discharge stops due to dryer conditions and falling groundwater levels. The groundwater storage in the field would have been larger if the water levels in the adjacent ditch were controlled as well by an adjustable weir. The N concentrations and loads increased, which was largely related to elevated concentrations in one of the three monitored tube drains. The P loads via the tube drains reduced due to the reduction in discharge after introducing controlled drainage. Furthermore, this may be counteracted by the higher groundwater levels and the larger contribution of N- and P-rich shallow groundwater and overland flow to the surface water.« less

High-frequency monitoring of water fluxes and nutrient loads to assess the effects of controlled drainage on water storage and nutrient transport

NASA Astrophysics Data System (ADS)

Rozemeijer, J. C.; Visser, A.; Borren, W.; Winegram, M.; van der Velde, Y.; Klein, J.; Broers, H. P.

2016-01-01

High nitrogen (N) and phosphorus (P) fluxes from upstream agriculture threaten aquatic ecosystems in surface waters and estuaries, especially in areas characterized by high agricultural N and P inputs and densely drained catchments like the Netherlands. Controlled drainage has been recognized as an effective option to optimize soil moisture conditions for agriculture and to reduce unnecessary losses of fresh water and nutrients. This is achieved by introducing control structures with adjustable overflow levels into subsurface tube drain systems. A small-scale (1 ha) field experiment was designed to investigate the hydrological and chemical changes after introducing controlled drainage. Precipitation rates and the response of water tables and drain fluxes were measured in the periods before the introduction of controlled drainage (2007-2008) and after (2009-2011). For the N and P concentration measurements, auto-analyzers for continuous records were combined with passive samplers for time-averaged concentrations at individual drain outlets. The experimental setup enabled the quantification of changes in the water and solute balance after introducing controlled drainage. The results showed that introducing controlled drainage reduced the drain discharge and increased the groundwater storage in the field. To achieve this, the overflow levels have to be elevated in early spring, before the drain discharge stops due to dryer conditions and falling groundwater levels. The groundwater storage in the field would have been larger if the water levels in the adjacent ditch were controlled as well by an adjustable weir. The N concentrations and loads increased, which was largely related to elevated concentrations in one of the three monitored tube drains. The P loads via the tube drains reduced due to the reduction in discharge after introducing controlled drainage. However, this may be counteracted by the higher groundwater levels and the larger contribution of N- and P-rich shallow groundwater and overland flow to the surface water.

Abrupt stop of deep water turnover with lake warming: Drastic consequences for algal primary producers.

PubMed

Yankova, Yana; Neuenschwander, Stefan; Köster, Oliver; Posch, Thomas

2017-10-23

After strong fertilization in the 20 th century, many deep lakes in Central Europe are again nutrient poor due to long-lasting restoration (re-oligotrophication). In line with reduced phosphorus and nitrogen loadings, total organismic productivity decreased and lakes have now historically low nutrient and biomass concentrations. This caused speculations that restoration was overdone and intended fertilizations are needed to ensure ecological functionality. Here we show that recent re-oligotrophication processes indeed accelerated, however caused by lake warming. Rising air temperatures strengthen thermal stabilization of water columns which prevents thorough turnover (holomixis). Reduced mixis impedes down-welling of oxygen rich epilimnetic (surface) and up-welling of phosphorus and nitrogen rich hypolimnetic (deep) water. However, nutrient inputs are essential for algal spring blooms acting as boost for annual food web successions. We show that repeated lack (since 1977) and complete stop (since 2013) of holomixis caused drastic epilimnetic phosphorus depletions and an absence of phytoplankton spring blooms in Lake Zurich (Switzerland). By simulating holomixis in experiments, we could induce significant vernal algal blooms, confirming that there would be sufficient hypolimnetic phosphorus which presently accumulates due to reduced export. Thus, intended fertilizations are highly questionable, as hypolimnetic nutrients will become available during future natural or artificial turnovers.

Nutrient Fluxes From Profundal Sediment of Ultra-Oligotrophic Lake Tahoe, California/Nevada: Implications for Water Quality and Management in a Changing Climate

NASA Astrophysics Data System (ADS)

Beutel, Marc W.; Horne, Alexander J.

2018-03-01

A warming climate is expected to lead to stronger thermal stratification, less frequent deep mixing, and greater potential for bottom water anoxia in deep, temperate oligotrophic lakes. As a result, there is growing interest in understanding nutrient cycling at the profundal sediment-water interface of these rare ecosystems. This paper assessed nutrient content and nutrient flux rates from profundal sediment at Lake Tahoe, California/Nevada, USA. Sediment is a large reservoir of nutrients, with the upper 5 cm containing reduced nitrogen (˜6,300 metric tons) and redox-sensitive phosphorus (˜710 metric tons) equivalent to ˜15 times the annual external load. Experimental results indicate that if deep water in Lake Tahoe goes anoxic, profundal sediment will release appreciable amounts of phosphate (0.13-0.29 mg P/m2·d), ammonia (0.49 mg N/m2·d), and iron to overlaying water. Assuming a 10 year duration of bottom water anoxia followed by a deep-water mixing event, water column phosphate, and ammonia concentrations would increase by an estimated 1.6 µg P/L and 2.9 µg N/L, nearly doubling ambient concentrations. Based on historic nutrient enrichment assays this could lead to a ˜40% increase in algal growth. Iron release could have the dual effect of alleviating nitrate limitation on algal growth while promoting the formation of fine iron oxyhydroxide particles that degrade water clarity. If the depth and frequency of lake mixing decrease in the future as hydrodynamic models suggest, large-scale in-lake management strategies that impede internal nutrient loading in Lake Tahoe, such as bottom water oxygen addition or aluminum salt addition, may need to be considered.

Performance of nutrient-loaded red oak and white oak seedlings on mine lands in southern Indiana

Treesearch

K. Francis Salifu; Douglass F. Jacobs; Zonda K. D. Birge

2008-01-01

Exponential nutrient loading was used to build nutrient reserves in northern red oak (Quercus rubra) and white oak (Q. alba) seedlings during standard bareroot nursery culture at the Vallonia State Nursery, Indiana. Nursery grown seedlings were outplanted the following year onto a mine reclamation site in southern Indiana to...

Yields and trends of nutrients and total suspended solids in nontidal areas of the Chesapeake Bay basin, 1985-96

USGS Publications Warehouse

Langland, Michael J.

1998-01-01

Excessive concentrations of nutrients and suspended solids in water adversely affect water quality in the Chesapeake Bay. High levels of nutrients in the Bay result in algal blooms and suspended solids reduce water clarity, both of which decrease the amount of light reaching submerged aquatic vegetation (SAV). The die off and decomposition of algae and SAV deplete oxygen supplies in the water. Low dissolved oxygen (DO) levels (less than 5.0 milligrams per liter for aquatic life, U.S. Environmental Protection Agency, 1986) can lead to fish kills and stress other living resources in the Bay. In 1987, the Chesapeake Bay Agreement called for a 40-percent reduction in the amount of controllable nutrients reaching the Chesapeake Bay by the year 2000. This goal was based on results of computer simulations that predicted that periods of low DO would be reduced or eliminated if nutrient inputs to the Bay were reduced by that amount. In an effort to achieve that goal, nutrient-reduction strategies, including banning phosphate detergents, upgrading sewagetreatment plants, controlling runoff from agricultural and urban areas, and preserving forest and wetland areas (Zynjuk, 1995), were implemented in many areas of the basin to help reduce nutrient inputs to the Bay. In 1997, a basinwide reevaluation of the 40-percent reduction goal was initiated to determine if that goal is achievable and to identify and document any changes in water quality and living resources in response to nutrient-reduction strategies. In support of this reevaluation, the U.S. Geological Survey (USGS) designed a database and retrieved water-quality data from approximately 1,300 nontidal stream sites in the Chesapeake Bay Basin (Langland and others, 1995). At 84 of the 1,300 sites, where sufficient data were available, trends, yields, and annual loads of nutrients and suspended solids were estimated for 1985 through 1996. This report presents: (1) spatial distribution of available nutrient and suspended-solids data for the 84 sites, (2) yields of nutrients and total suspended solids, and (3) trends in concentrations of nutrients and total suspended solids. Results presented here are limited to analyses for total nitrogen (TN), nitrate nitrogen (NO3), total phosphorus (TP), and total suspended solids (TSS).

Nutrient Loadings to Streams of the Continental United States from Municipal and Industrial Effluent

USGS Publications Warehouse

Maupin, M.A.; Ivahnenko, T.

2011-01-01

Data from the United States Environmental Protection Agency Permit Compliance System national database were used to calculate annual total nitrogen (TN) and total phosphorus (TP) loads to surface waters from municipal and industrial facilities in six major regions of the United States for 1992, 1997, and 2002. Concentration and effluent flow data were examined for approximately 118,250 facilities in 45 states and the District of Columbia. Inconsistent and incomplete discharge locations, effluent flows, and effluent nutrient concentrations limited the use of these data for calculating nutrient loads. More concentrations were reported for major facilities, those discharging more than 1million gallons per day, than for minor facilities, and more concentrations were reported for TP than for TN. Analytical methods to check and improve the quality of the Permit Compliance System data were used. Annual loads were calculated using "typical pollutant concentrations" to supplement missing concentrations based on the type and size of facilities. Annual nutrient loads for over 26,600 facilities were calculated for at least one of the three years. Sewage systems represented 74% of all TN loads and 58% of all TP loads. This work represents an initial set of data to develop a comprehensive and consistent national database of point-source nutrient loads. These loads can be used to inform a wide range of water-quality management, watershed modeling, and research efforts at multiple scales. ?? 2011 American Water Resources Association. This article is a U.S. Government work and is in the public domain in the USA.

Rating curve estimation of nutrient loads in Iowa rivers

USGS Publications Warehouse

Stenback, G.A.; Crumpton, W.G.; Schilling, K.E.; Helmers, M.J.

2011-01-01

Accurate estimation of nutrient loads in rivers and streams is critical for many applications including determination of sources of nutrient loads in watersheds, evaluating long-term trends in loads, and estimating loading to downstream waterbodies. Since in many cases nutrient concentrations are measured on a weekly or monthly frequency, there is a need to estimate concentration and loads during periods when no data is available. The objectives of this study were to: (i) document the performance of a multiple regression model to predict loads of nitrate and total phosphorus (TP) in Iowa rivers and streams; (ii) determine whether there is any systematic bias in the load prediction estimates for nitrate and TP; and (iii) evaluate streamflow and concentration factors that could affect the load prediction efficiency. A commonly cited rating curve regression is utilized to estimate riverine nitrate and TP loads for rivers in Iowa with watershed areas ranging from 17.4 to over 34,600km2. Forty-nine nitrate and 44 TP datasets each comprising 5-22years of approximately weekly to monthly concentrations were examined. Three nitrate data sets had sample collection frequencies averaging about three samples per week. The accuracy and precision of annual and long term riverine load prediction was assessed by direct comparison of rating curve load predictions with observed daily loads. Significant positive bias of annual and long term nitrate loads was detected. Long term rating curve nitrate load predictions exceeded observed loads by 25% or more at 33% of the 49 measurement sites. No bias was found for TP load prediction although 15% of the 44 cases either underestimated or overestimate observed long-term loads by more than 25%. The rating curve was found to poorly characterize nitrate and phosphorus variation in some rivers. ?? 2010 .

Coastal eutrophication as a driver of salt marsh loss.

PubMed

Deegan, Linda A; Johnson, David Samuel; Warren, R Scott; Peterson, Bruce J; Fleeger, John W; Fagherazzi, Sergio; Wollheim, Wilfred M

2012-10-18

Salt marshes are highly productive coastal wetlands that provide important ecosystem services such as storm protection for coastal cities, nutrient removal and carbon sequestration. Despite protective measures, however, worldwide losses of these ecosystems have accelerated in recent decades. Here we present data from a nine-year whole-ecosystem nutrient-enrichment experiment. Our study demonstrates that nutrient enrichment, a global problem for coastal ecosystems, can be a driver of salt marsh loss. We show that nutrient levels commonly associated with coastal eutrophication increased above-ground leaf biomass, decreased the dense, below-ground biomass of bank-stabilizing roots, and increased microbial decomposition of organic matter. Alterations in these key ecosystem properties reduced geomorphic stability, resulting in creek-bank collapse with significant areas of creek-bank marsh converted to unvegetated mud. This pattern of marsh loss parallels observations for anthropogenically nutrient-enriched marshes worldwide, with creek-edge and bay-edge marsh evolving into mudflats and wider creeks. Our work suggests that current nutrient loading rates to many coastal ecosystems have overwhelmed the capacity of marshes to remove nitrogen without deleterious effects. Projected increases in nitrogen flux to the coast, related to increased fertilizer use required to feed an expanding human population, may rapidly result in a coastal landscape with less marsh, which would reduce the capacity of coastal regions to provide important ecological and economic services.

Impact of Climate Variability and Landscape Patterns on Water Budget and Nutrient Loads in a Peri-urban Watershed: A Coupled Analysis Using Process-based Hydrological Model and Landscape Indices.

PubMed

Li, Chongwei; Zhang, Yajuan; Kharel, Gehendra; Zou, Chris B

2018-06-01

Nutrient discharge into peri-urban streams and reservoirs constitutes a significant pressure on environmental management, but quantitative assessment of non-point source pollution under climate variability in fast changing peri-urban watersheds is challenging. Soil and Water Assessment Tool (SWAT) was used to simulate water budget and nutrient loads for landscape patterns representing a 30-year progression of urbanization in a peri-urban watershed near Tianjin metropolis, China. A suite of landscape pattern indices was related to nitrogen (N) and phosphorous (P) loads under dry and wet climate using CANOCO redundancy analysis. The calibrated SWAT model was adequate to simulate runoff and nutrient loads for this peri-urban watershed, with Nash-Sutcliffe coefficient (NSE) and coefficient of determination (R 2 ) > 0.70 and percentage bias (PBIAS) between -7 and +18 for calibration and validation periods. With the progression of urbanization, forest remained the main "sink" landscape while cultivated and urban lands remained the main "source" landscapes with the role of orchard and grassland being uncertain and changing with time. Compared to 1984, the landscape use pattern in 2013 increased nutrient discharge by 10%. Nutrient loads modelled under wet climate were 3-4 times higher than that under dry climate for the same landscape pattern. Results indicate that climate change could impose a far greater impact on runoff and nutrient discharge in a peri-urban watershed than landscape pattern change.

Impact of Climate Variability and Landscape Patterns on Water Budget and Nutrient Loads in a Peri-urban Watershed: A Coupled Analysis Using Process-based Hydrological Model and Landscape Indices

NASA Astrophysics Data System (ADS)

Li, Chongwei; Zhang, Yajuan; Kharel, Gehendra; Zou, Chris B.

2018-06-01

Nutrient discharge into peri-urban streams and reservoirs constitutes a significant pressure on environmental management, but quantitative assessment of non-point source pollution under climate variability in fast changing peri-urban watersheds is challenging. Soil and Water Assessment Tool (SWAT) was used to simulate water budget and nutrient loads for landscape patterns representing a 30-year progression of urbanization in a peri-urban watershed near Tianjin metropolis, China. A suite of landscape pattern indices was related to nitrogen (N) and phosphorous (P) loads under dry and wet climate using CANOCO redundancy analysis. The calibrated SWAT model was adequate to simulate runoff and nutrient loads for this peri-urban watershed, with Nash-Sutcliffe coefficient (NSE) and coefficient of determination ( R 2) > 0.70 and percentage bias (PBIAS) between -7 and +18 for calibration and validation periods. With the progression of urbanization, forest remained the main "sink" landscape while cultivated and urban lands remained the main "source" landscapes with the role of orchard and grassland being uncertain and changing with time. Compared to 1984, the landscape use pattern in 2013 increased nutrient discharge by 10%. Nutrient loads modelled under wet climate were 3-4 times higher than that under dry climate for the same landscape pattern. Results indicate that climate change could impose a far greater impact on runoff and nutrient discharge in a peri-urban watershed than landscape pattern change.

Nutrient loading and consumers: Agents of change in open-coast macrophyte assemblages

PubMed Central

Nielsen, Karina J.

2003-01-01

Human activities are significantly altering nutrient regimes and the abundance of consumers in coastal ecosystems. A field experiment in an open-coast, upwelling ecosystem showed that small increases in nutrients increased the biomass and evenness of tide pool macrophytes where consumer abundance and nutrient loading rates were low. Consumers, when abundant, had negative effects on the diversity and biomass of macrophytes. Nutrient loading increases and consumers are less abundant and efficient as wave exposure increases along open coastlines. Experimentally reversing the natural state of nutrient supply and consumer pressure at a wave-protected site to match wave-exposed sites caused the structure of the macrophyte assemblage to converge on that found naturally in wave-exposed pools. The increases in evenness and abundance were driven by increases in structurally complex functional groups. In contrast, increased nutrient loading in semienclosed marine or estuarine ecosystems is typically associated with declines in macrophyte diversity because of increases in structurally simple and opportunistic functional groups. If nutrient concentration of upwelled waters changes with climatic warming or increasing frequency of El Niños, as predicted by some climate models, these results suggest that macrophyte abundance and evenness along wave-swept open-coasts will also change. Macrophytes represent a significant fraction of continental shelf production and provide important habitat for many marine species. The combined effects of shifting nutrient regimes and overexploitation of consumers may have unexpected consequences for the structure and functioning of open-coast communities. PMID:12796509

Nutrient loading and consumers: agents of change in open-coast macrophyte assemblages.

PubMed

Nielsen, Karina J

2003-06-24

Human activities are significantly altering nutrient regimes and the abundance of consumers in coastal ecosystems. A field experiment in an open-coast, upwelling ecosystem showed that small increases in nutrients increased the biomass and evenness of tide pool macrophytes where consumer abundance and nutrient loading rates were low. Consumers, when abundant, had negative effects on the diversity and biomass of macrophytes. Nutrient loading increases and consumers are less abundant and efficient as wave exposure increases along open coastlines. Experimentally reversing the natural state of nutrient supply and consumer pressure at a wave-protected site to match wave-exposed sites caused the structure of the macrophyte assemblage to converge on that found naturally in wave-exposed pools. The increases in evenness and abundance were driven by increases in structurally complex functional groups. In contrast, increased nutrient loading in semienclosed marine or estuarine ecosystems is typically associated with declines in macrophyte diversity because of increases in structurally simple and opportunistic functional groups. If nutrient concentration of upwelled waters changes with climatic warming or increasing frequency of El Niños, as predicted by some climate models, these results suggest that macrophyte abundance and evenness along wave-swept open-coasts will also change. Macrophytes represent a significant fraction of continental shelf production and provide important habitat for many marine species. The combined effects of shifting nutrient regimes and overexploitation of consumers may have unexpected consequences for the structure and functioning of open-coast communities.

Climate change impacts on runoff, sediment, and nutrient loads in an agricultural watershed in the Lower Mississippi River Basin

USDA-ARS?s Scientific Manuscript database

Projected climate change can impact various aspects of agricultural systems, including the nutrient and sediment loads exported from agricultural fields. This study evaluated the potential changes in runoff, sediment, nitrogen, and phosphorus loads using projected climate estimates from 2041 – 2070 ...

User-inspired Research Quantifies How Floodplain Restoration Paired With Cover Crops Reduces Nutrient Export From an Agricultural Catchment Translating to Conservation Success in the Midwestern Cornbelt.

NASA Astrophysics Data System (ADS)

Tank, J. L.; Hanrahan, B.; Christopher, S. F.; Mahl, U. H.; Royer, T. V.

2017-12-01

The Midwestern US has undergone extensive land use change as forest, wetlands, and prairies have been converted to agroecosystems. Today, excess fertilizer nutrients from farm fields enter agricultural streams, which degrades both local and downstream water quality. We are quantifying the nutrient reduction benefits of two conservation practices implemented at the catchment scale. In partnership with The Nature Conservancy, in a small Indiana catchment, we have quantified how 600m of floodplain restoration (i.e., a two-stage ditch) increased nitrate-N removal via denitrification and reduced sediment export, but impacts on stream nutrient concentrations were negligible due to very high catchment loading relative to the short implementation reach. Requests from state and federal partners led to development and parameterization of a new two-stage ditch module in the SWAT model to determine the potential catchment-scale benefits when implementation lengths were extended. More recently, in partnership with state SWCD managers, we have added a landscape practice to quantify how winter cover crops reduce nutrient loss from fields, sampling year-round nutrient fluxes from multiple subsurface tile drains and longitudinally along the stream channel. Nitrate-N and dissolved P fluxes were significantly lower in tiles draining fields with cover crops compared to those without. At the urging of farmers and federal NRCS partners, we also linked tile drain nutrient reductions to changes in soil chemistry. Both soil nitrate-N and dissolved P were lower in cover cropped fields, and we found significant correlations between soil and tile drain nutrients, which may encourage future adoption of the conservation practice as soil health benefits appeal to farmers. As biogeochemists, this research has provided valuable insights on how floodplains and land cover change can alter patterns of catchment-scale nutrient export. The translation of successful soil and water quality outcomes through this significant regional demonstration project make it a potentially powerful agent of change for advancing conservation success.

A study on the optimal hydraulic loading rate and plant ratios in recirculation aquaponic system.

PubMed

Endut, Azizah; Jusoh, A; Ali, N; Wan Nik, W B; Hassan, A

2010-03-01

The growths of the African catfish (Clarias gariepinus) and water spinach (Ipomoea aquatica) were evaluated in recirculation aquaponic system (RAS). Fish production performance, plant growth and nutrient removal were measured and their dependence on hydraulic loading rate (HLR) was assessed. Fish production did not differ significantly between hydraulic loading rates. In contrast to the fish production, the water spinach yield was significantly higher in the lower hydraulic loading rate. Fish production, plant growth and percentage nutrient removal were highest at hydraulic loading rate of 1.28 m/day. The ratio of fish to plant production has been calculated to balance nutrient generation from fish with nutrient removal by plants and the optimum ratio was 15-42 gram of fish feed/m(2) of plant growing area. Each unit in RAS was evaluated in terms of oxygen demand. Using specified feeding regime, mass balance equations were applied to quantify the waste discharges from rearing tanks and treatment units. The waste discharged was found to be strongly dependent on hydraulic loading rate. 2009 Elsevier Ltd. All rights reserved.

Response in the water quality of the Salton Sea, California, to changes in phosphorus loading: An empirical modeling approach

USGS Publications Warehouse

Robertson, Dale M.; Schladow, S.G.

2008-01-01

Salton Sea, California, like many other lakes, has become eutrophic because of excessive nutrient loading, primarily phosphorus (P). A Total Maximum Daily Load (TMDL) is being prepared for P to reduce the input of P to the Sea. In order to better understand how P-load reductions should affect the average annual water quality of this terminal saline lake, three different eutrophication programs (BATHTUB, WiLMS, and the Seepage Lake Model) were applied. After verifying that specific empirical models within these programs were applicable to this saline lake, each model was calibrated using water-quality and nutrient-loading data for 1999 and then used to simulate the effects of specific P-load reductions. Model simulations indicate that a 50% decrease in external P loading would decrease near-surface total phosphorus concentrations (TP) by 25-50%. Application of other empirical models demonstrated that this decrease in loading should decrease near-surface chlorophyll a concentrations (Chl a) by 17-63% and increase Secchi depths (SD) by 38-97%. The wide range in estimated responses in Chl a and SD were primarily caused by uncertainty in how non-algal turbidity would respond to P-load reductions. If only the models most applicable to the Salton Sea are considered, a 70-90% P-load reduction is required for the Sea to be classified as moderately eutrophic (trophic state index of 55). These models simulate steady-state conditions in the Sea; therefore, it is difficult to ascertain how long it would take for the simulated changes to occur after load reductions. ?? 2008 Springer Science+Business Media B.V.

Effects of Storm Events on Bacteria and Nutrients in the Bayou Chico Watershed

NASA Astrophysics Data System (ADS)

Hobbs, S. E.; Truong, S.

2017-12-01

Levels of Escherichia coli and abiotic nutrients often increase in response to storm events due to urban runoff. The urban setting, aging septic systems, and ample pet waste (predominant sources of bacterial and nutrient contamination) that surround Bayou Chico, provide abundant possibilities for contamination. E. coli is a gram-negative, rod shaped bacteria commonly found in the intestines of animals; while some strains are harmless, others produce dangerous toxins that can cause side effects and sometimes death. Along with E. coli, inorganic nutrient concentrations (orthophosphate, nitrate/nitrite, and ammonium) are key indicators of water quality. Dissolved nutrients promote the growth of primary producers and excessive amounts lead to algal blooms, often reducing biodiversity. Four sites were sampled weekly in June and July 2017; during which, June had the highest rainfall in comparison to the past three years; these four sites represented three different sub-watersheds of the Bayou Chico Watershed, with differing land-use at each site. Historical nutrient and bacterial data from the Bream Fishermen Association was also compared and examined to determine long term trends and obtain a more in-depth understanding of the dynamics of water quality in th urban setting. E. coli levels were universally high (ranging from 98 to 12,997 MPN/100mL) for all sites and did not show observable correlations to rainfall; possibly influenced by the systemic and anomalous heavy precipitation during most of the summer study period. Nitrate was detected at levels between 2.5 and 154.0 µM, while ammonium levels ranged from 0 to 16.1 µM. Three of four stations showed extremely elevated dissolved inorganic nitrogen and ammonium while one station showed low levels of these nutrients. Correlations between these nutrient loads and rainfall, support the hypothesis that runoff into tributary creeks contributes significant inorganic nutrient loads to the Bayou Chico urban estuary.

Nutrients and water masses in the Gulf of Maine - Georges Bank region: Variability and importance to blooms of the toxic dinoflagellate Alexandrium fundyense.

PubMed

Townsend, D W; McGillicuddy, D J; Thomas, M A; Rebuck, N R

2014-05-01

We report here the results of ten oceanographic survey cruises carried out in the Gulf of Maine - Georges Bank region of the Northwest Atlantic during the late spring to summer period in 2007, 2008 and 2010, for which we examine and characterize relationships among dissolved inorganic nutrient fields, water mass dynamics and cell densities of the toxic dinoflagellate Alexandrium fundyense . Nutrients are supplied to continental shelf waters of the Gulf of Maine - Georges Bank region by inflows of deep offshore water masses; once in the Gulf they are transported with the residual circulation and mix with surface waters, both in the Gulf and on the Bank. Those fluxes of offshore water masses and their nutrient loads are the major source of nutrients for phytoplankton production in the region, including annual blooms of A. fundyense in the Gulf and on Georges Bank. This much is already known. We suggest here that the locations and magnitude of A. fundyense blooms are controlled in part by variable nutrient fluxes to the interior Gulf of Maine from offshore, and, those interior Gulf of Maine waters are, in turn, the main nutrient source to Georges Bank, which are brought onto the Bank by tidal pumping on the Northern Flank. We present evidence that nitrate is the initial form of nitrogenous nutrient for A. fundyense blooms, but it is quickly depleted to limiting concentrations of less than 0.5 μM, at which time continued growth and maintenance of the population is likely fueled by recycled ammonium. We also show that phosphate may be the limiting nutrient over much of Georges Bank in summer, allowing recycled ammonium concentrations to increase. Our temperature-salinity analyses reveal spatial and temporal (seasonal and interannual) variability in the relative proportions of two deep source waters that enter the Gulf of Maine at depth through the Northeast Channel: Warm Slope Water (WSW) and Labrador Slope Water (LSW). Those two source waters are known to vary in their nutrient loads, with nitrate concentrations about 50% higher in WSW than LSW, for example, and as such the proportions of these two water masses to one another are important determinants of the overall nutrient loads in the interior Gulf. In addition to these deep slope water fluxes, we show evidence here of episodic fluxes of relatively fresh and low-nutrient shelf waters from the Nova Scotian Shelf, which enter the Gulf in pulses at depths between the surface and approximately 150 m, displacing deep slope waters, and consequently they significantly dilute the Gulf's interior waters, reducing nutrient concentrations and, in turn, affect the magnitude of A. fundyense blooms.

Nutrients and water masses in the Gulf of Maine - Georges Bank region: Variability and importance to blooms of the toxic dinoflagellate Alexandrium fundyense

PubMed Central

Townsend, D.W.; McGillicuddy, D.J.; Thomas, M.A.; Rebuck, N.R.

2015-01-01

We report here the results of ten oceanographic survey cruises carried out in the Gulf of Maine - Georges Bank region of the Northwest Atlantic during the late spring to summer period in 2007, 2008 and 2010, for which we examine and characterize relationships among dissolved inorganic nutrient fields, water mass dynamics and cell densities of the toxic dinoflagellate Alexandrium fundyense. Nutrients are supplied to continental shelf waters of the Gulf of Maine - Georges Bank region by inflows of deep offshore water masses; once in the Gulf they are transported with the residual circulation and mix with surface waters, both in the Gulf and on the Bank. Those fluxes of offshore water masses and their nutrient loads are the major source of nutrients for phytoplankton production in the region, including annual blooms of A. fundyense in the Gulf and on Georges Bank. This much is already known. We suggest here that the locations and magnitude of A. fundyense blooms are controlled in part by variable nutrient fluxes to the interior Gulf of Maine from offshore, and, those interior Gulf of Maine waters are, in turn, the main nutrient source to Georges Bank, which are brought onto the Bank by tidal pumping on the Northern Flank. We present evidence that nitrate is the initial form of nitrogenous nutrient for A. fundyense blooms, but it is quickly depleted to limiting concentrations of less than 0.5 μM, at which time continued growth and maintenance of the population is likely fueled by recycled ammonium. We also show that phosphate may be the limiting nutrient over much of Georges Bank in summer, allowing recycled ammonium concentrations to increase. Our temperature-salinity analyses reveal spatial and temporal (seasonal and interannual) variability in the relative proportions of two deep source waters that enter the Gulf of Maine at depth through the Northeast Channel: Warm Slope Water (WSW) and Labrador Slope Water (LSW). Those two source waters are known to vary in their nutrient loads, with nitrate concentrations about 50% higher in WSW than LSW, for example, and as such the proportions of these two water masses to one another are important determinants of the overall nutrient loads in the interior Gulf. In addition to these deep slope water fluxes, we show evidence here of episodic fluxes of relatively fresh and low-nutrient shelf waters from the Nova Scotian Shelf, which enter the Gulf in pulses at depths between the surface and approximately 150 m, displacing deep slope waters, and consequently they significantly dilute the Gulf's interior waters, reducing nutrient concentrations and, in turn, affect the magnitude of A. fundyense blooms. PMID:26028824

Wildfire Effects on In-stream Nutrient Processing and Hydrologic Transport

NASA Astrophysics Data System (ADS)

Rhea, A.; Covino, T. P.; Rhoades, C.; Fegel, T.

2017-12-01

In many forests throughout the Western U.S., drought, climate change, and growing fuel loads are contributing to increased fire frequency and severity. Wildfires can influence watershed nutrient retention as they fundamentally alter the biological composition and physical structure in upland landscapes, riparian corridors, and stream channels. While numerous studies have documented substantial short-term increases in stream nutrient concentrations and export (particularly reactive nitrogen, N) following forest fires, the long-term implications for watershed nutrient cycling remain unclear. For example, recent work indicates that nitrate concentrations and export can remain elevated for a decade or more following wildfire, yet the controls on these processes are unknown. In this research, we use empirical observations from nutrient tracer injections, nutrient diffusing substrates, and continuous water quality monitoring to isolate biological and physical controls on nutrient export across a burn-severity gradient. Tracer results demonstrate substantial stream-groundwater exchange, but little biological nutrient uptake in burned streams. This in part explains patterns of elevated nutrient export. Paired nutrient diffusing substrate experiments allow us to further investigate shifts in N, phosphorus, and carbon limitation that may suppress post-fire stream nutrient uptake. By isolating the mechanisms that reduce the capacity of fire-affected streams to retain and transform nutrient inputs, we can better predict dynamics in post-fire water quality and help prioritize upland and riparian restoration.

Surface-Water Nutrient Conditions and Sources in the United States Pacific Northwest1

PubMed Central

Wise, Daniel R; Johnson, Henry M

2011-01-01

Abstract The SPAtially Referenced Regressions On Watershed attributes (SPARROW) model was used to perform an assessment of surface-water nutrient conditions and to identify important nutrient sources in watersheds of the Pacific Northwest region of the United States (U.S.) for the year 2002. Our models included variables representing nutrient sources as well as landscape characteristics that affect nutrient delivery to streams. Annual nutrient yields were higher in watersheds on the wetter, west side of the Cascade Range compared to watersheds on the drier, east side. High nutrient enrichment (relative to the U.S. Environmental Protection Agency's recommended nutrient criteria) was estimated in watersheds throughout the region. Forest land was generally the largest source of total nitrogen stream load and geologic material was generally the largest source of total phosphorus stream load generated within the 12,039 modeled watersheds. These results reflected the prevalence of these two natural sources and the low input from other nutrient sources across the region. However, the combined input from agriculture, point sources, and developed land, rather than natural nutrient sources, was responsible for most of the nutrient load discharged from many of the largest watersheds. Our results provided an understanding of the regional patterns in surface-water nutrient conditions and should be useful to environmental managers in future water-quality planning efforts. PMID:22457584

Impact of a wastewater treatment plant on microbial community composition and function in a hyporheic zone of a eutrophic river

NASA Astrophysics Data System (ADS)

Atashgahi, Siavash; Aydin, Rozelin; Dimitrov, Mauricio R.; Sipkema, Detmer; Hamonts, Kelly; Lahti, Leo; Maphosa, Farai; Kruse, Thomas; Saccenti, Edoardo; Springael, Dirk; Dejonghe, Winnie; Smidt, Hauke

2015-11-01

The impact of the installation of a technologically advanced wastewater treatment plant (WWTP) on the benthic microbial community of a vinyl chloride (VC) impacted eutrophic river was examined two years before, and three and four years after installation of the WWTP. Reduced dissolved organic carbon and increased dissolved oxygen concentrations in surface water and reduced total organic carbon and total nitrogen content in the sediment were recorded in the post-WWTP samples. Pyrosequencing of bacterial 16S rRNA gene fragments in sediment cores showed reduced relative abundance of heterotrophs and fermenters such as Chloroflexi and Firmicutes in more oxic and nutrient poor post-WWTP sediments. Similarly, quantitative PCR analysis showed 1-3 orders of magnitude reduction in phylogenetic and functional genes of sulphate reducers, denitrifiers, ammonium oxidizers, methanogens and VC-respiring Dehalococcoides mccartyi. In contrast, members of Proteobacteria adapted to nutrient-poor conditions were enriched in post-WWTP samples. This transition in the trophic state of the hyporheic sediments reduced but did not abolish the VC respiration potential in the post-WWTP sediments as an important hyporheic sediment function. Our results highlight effective nutrient load reduction and parallel microbial ecological state restoration of a human-stressed urban river as a result of installation of a WWTP.

Variable climatic conditions dominate recent phytoplankton dynamics in Chesapeake Bay

NASA Astrophysics Data System (ADS)

Harding, Lawrence W., Jr.; Mallonee, Michael E.; Perry, Elgin S.; Miller, W. David; Adolf, Jason E.; Gallegos, Charles L.; Paerl, Hans W.

2016-03-01

Variable climatic conditions strongly influence phytoplankton dynamics in estuaries globally. Our study area is Chesapeake Bay, a highly productive ecosystem providing natural resources, transportation, and recreation for nearly 16 million people inhabiting a 165,000-km2 watershed. Since World War II, nutrient over-enrichment has led to multiple ecosystem impairments caused by increased phytoplankton biomass as chlorophyll-a (chl-a). Doubled nitrogen (N) loadings from 1945-1980 led to increased chl-a, reduced water clarity, and low dissolved oxygen (DO), while decreased N loadings from 1981-2012 suggest modest improvement. The recent 30+ years are characterized by high inter-annual variability of chl-a, coinciding with irregular dry and wet periods, complicating the detection of long-term trends. Here, we synthesize time-series data for historical and recent N loadings (TN, NO2 + NO3), chl-a, floral composition, and net primary productivity (NPP) to distinguish secular changes caused by nutrient over-enrichment from spatio-temporal variability imposed by climatic conditions. Wet years showed higher chl-a, higher diatom abundance, and increased NPP, while dry years showed lower chl-a, lower diatom abundance, and decreased NPP. Our findings support a conceptual model wherein variable climatic conditions dominate recent phytoplankton dynamics against a backdrop of nutrient over-enrichment, emphasizing the need to separate these effects to gauge progress toward improving water quality in estuaries.

Variable climatic conditions dominate recent phytoplankton dynamics in Chesapeake Bay.

PubMed

Harding, Lawrence W; Mallonee, Michael E; Perry, Elgin S; Miller, W David; Adolf, Jason E; Gallegos, Charles L; Paerl, Hans W

2016-03-30

Variable climatic conditions strongly influence phytoplankton dynamics in estuaries globally. Our study area is Chesapeake Bay, a highly productive ecosystem providing natural resources, transportation, and recreation for nearly 16 million people inhabiting a 165,000-km(2) watershed. Since World War II, nutrient over-enrichment has led to multiple ecosystem impairments caused by increased phytoplankton biomass as chlorophyll-a (chl-a). Doubled nitrogen (N) loadings from 1945-1980 led to increased chl-a, reduced water clarity, and low dissolved oxygen (DO), while decreased N loadings from 1981-2012 suggest modest improvement. The recent 30+ years are characterized by high inter-annual variability of chl-a, coinciding with irregular dry and wet periods, complicating the detection of long-term trends. Here, we synthesize time-series data for historical and recent N loadings (TN, NO2 + NO3), chl-a, floral composition, and net primary productivity (NPP) to distinguish secular changes caused by nutrient over-enrichment from spatio-temporal variability imposed by climatic conditions. Wet years showed higher chl-a, higher diatom abundance, and increased NPP, while dry years showed lower chl-a, lower diatom abundance, and decreased NPP. Our findings support a conceptual model wherein variable climatic conditions dominate recent phytoplankton dynamics against a backdrop of nutrient over-enrichment, emphasizing the need to separate these effects to gauge progress toward improving water quality in estuaries.

Variable climatic conditions dominate recent phytoplankton dynamics in Chesapeake Bay

PubMed Central

Harding, Jr., Lawrence W.; Mallonee, Michael E.; Perry, Elgin S.; Miller, W. David; Adolf, Jason E.; Gallegos, Charles L.; Paerl, Hans W.

2016-01-01

Variable climatic conditions strongly influence phytoplankton dynamics in estuaries globally. Our study area is Chesapeake Bay, a highly productive ecosystem providing natural resources, transportation, and recreation for nearly 16 million people inhabiting a 165,000-km2 watershed. Since World War II, nutrient over-enrichment has led to multiple ecosystem impairments caused by increased phytoplankton biomass as chlorophyll-a (chl-a). Doubled nitrogen (N) loadings from 1945–1980 led to increased chl-a, reduced water clarity, and low dissolved oxygen (DO), while decreased N loadings from 1981–2012 suggest modest improvement. The recent 30+ years are characterized by high inter-annual variability of chl-a, coinciding with irregular dry and wet periods, complicating the detection of long-term trends. Here, we synthesize time-series data for historical and recent N loadings (TN, NO2 + NO3), chl-a, floral composition, and net primary productivity (NPP) to distinguish secular changes caused by nutrient over-enrichment from spatio-temporal variability imposed by climatic conditions. Wet years showed higher chl-a, higher diatom abundance, and increased NPP, while dry years showed lower chl-a, lower diatom abundance, and decreased NPP. Our findings support a conceptual model wherein variable climatic conditions dominate recent phytoplankton dynamics against a backdrop of nutrient over-enrichment, emphasizing the need to separate these effects to gauge progress toward improving water quality in estuaries. PMID:27026279

Impact of river basin management on coastal water quality and ecosystem services: A southern Baltic estuary

NASA Astrophysics Data System (ADS)

Schernewski, Gerald; Hürdler, Jens; Neumann, Thomas; Stybel, Nardine; Venohr, Markus

2010-05-01

Eutrophication management is still a major challenge in the Baltic Sea region. Estuaries or coastal waters linked to large rivers cannot be managed independently. Nutrient loads into these coastal ecosystems depend on processes, utilisation, structure and management in the river basin. In practise this means that we need a large scale approach and integrated models and tools to analyse, assess and evaluate the effects of nutrient loads on coastal water quality as well as the efficiency of river basin management measures on surface waters and especially lagoons and estuaries. The Odra river basin, the Szczecin Lagoon and its coastal waters cover an area of about 150,000 km² and are an eutrophication hot-spot in the Baltic region. To be able to carry out large scale, spatially integrative analyses, we linked the river basin nutrient flux model MONERIS to the coastal 3D-hydrodynamic and ecosystem model ERGOM. Objectives were a) to analyse the eutrophication history in the river basin and the resulting functional changes in the coastal waters between early 1960's and today and b) to analyse the effects of an optimal nitrogen and phosphorus management scenario in the Oder/Odra river basin on coastal water quality. The models show that an optimal river basin management with reduced nutrient loads (e.g. N-load reduction of 35 %) would have positive effects on coastal water quality and algae biomass. The availability of nutrients, N/P ratios and processes like denitrification and nitrogen-fixation would show spatial and temporal changes. It would have positive consequences for ecosystems functions, like the nutrient retention capacity, as well. However, this optimal scenario is by far not sufficient to ensure a good coastal water quality according to the European Water Framework Directive. A "good" water quality in the river will not be sufficient to ensure a "good" water quality in the coastal waters. Further, nitrogen load reductions bear the risk of increased potentially toxic, blue-green algae blooms. The presentation will summarize recent results (Behrendt et al. 2009, Schernewski et al. 2009, Schernewski et al. in press, Schernewski et al. submitted) and give an overview how Climate Change and socio-economic transformation processes in the river basin will effect coastal water quality during the next decades. The opportunities and threats of a changing lagoon ecosystem for tourism and fisheries, the major economic activities, will be shown.

Nutrient production from dairy cattle manure and loading on arable land.

PubMed

Won, Seunggun; Shim, Soo-Min; You, Byung-Gu; Choi, Yoon-Seok; Ra, Changsix

2017-01-01

Along with increasing livestock products via intensive rearing, the accumulation of livestock manure has become a serious issue due to the fact that there is finite land for livestock manure recycling via composting. The nutrients from livestock manure accumulate on agricultural land and the excess disembogues into streams causing eutrophication. In order to systematically manage nutrient loading on agricultural land, quantifying the amount of nutrients according to their respective sources is very important. However, there is a lack of research concerning nutrient loss from livestock manure during composting or storage on farms. Therefore, in the present study we quantified the nutrients from dairy cattle manure that were imparted onto agricultural land. Through investigation of 41 dairy farms, weight reduction and volatile solids (VS), total nitrogen (TN), and total phosphorus (TP) changes of dairy cattle manure during the storage and composting periods were analyzed. In order to support the direct investigation and survey on site, the three cases of weight reduction during the storing and composting periods were developed according to i) experiment, ii) reference, and iii) theoretical changes in phosphorus content (ΔP = 0). The data revealed the nutrient loading coefficients (NLCs) of VS, TN, and TP on agricultural land were 1.48, 0.60, and 0.66, respectively. These values indicated that the loss of nitrogen and phosphorus was 40% and 34%, respectively, and that there was an increase of VS since bedding materials were mixed with excretion in the barn. As result of nutrient-footprint analyses, the amounts of TN and TP particularly entered on arable land have been overestimated if applying the nutrient amount in fresh manure. The NLCs obtained in this study may assist in the development of a database to assess the accurate level of manure nutrient loading on soil and facilitate systematic nutrient management.

Spatial characterization of riparian buffer effects on sediment loads from watershed systems.

PubMed

Momm, Henrique G; Bingner, Ronald L; Yuan, Yongping; Locke, Martin A; Wells, Robert R

2014-09-01

Understanding all watershed systems and their interactions is a complex, but critical, undertaking when developing practices designed to reduce topsoil loss and chemical/nutrient transport from agricultural fields. The presence of riparian buffer vegetation in agricultural landscapes can modify the characteristics of overland flow, promoting sediment deposition and nutrient filtering. Watershed simulation tools, such as the USDA-Annualized Agricultural Non-Point Source (AnnAGNPS) pollution model, typically require detailed information for each riparian buffer zone throughout the watershed describing the location, width, vegetation type, topography, and possible presence of concentrated flow paths through the riparian buffer zone. Research was conducted to develop GIS-based technology designed to spatially characterize riparian buffers and to estimate buffer efficiency in reducing sediment loads in a semiautomated fashion at watershed scale. The methodology combines modeling technology at different scales, at individual concentrated flow paths passing through the riparian zone, and at watershed scales. At the concentrated flow path scale, vegetative filter strip models are applied to estimate the sediment-trapping efficiency for each individual flow path, which are aggregated based on the watershed subdivision and used in the determination of the overall impact of the riparian vegetation at the watershed scale. This GIS-based technology is combined with AnnAGNPS to demonstrate the effect of riparian vegetation on sediment loadings from sheet and rill and ephemeral gully sources. The effects of variability in basic input parameters used to characterize riparian buffers, onto generated outputs at field scale (sediment trapping efficiency) and at watershed scale (sediment loadings from different sources) were evaluated and quantified. The AnnAGNPS riparian buffer component represents an important step in understanding and accounting for the effect of riparian vegetation, existing and/or managed, in reducing sediment loads at the watershed scale. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Riparian shrub buffers reduce surface water pollutant loads

Treesearch

W. A. Geyer; C. Barden; K. Mankin; D. Devlin

2003-01-01

Surface water resources in Kansas often contain concentrations of pesticides, nutrients, and sediments that are of concern to local citizens. The United States Geological Survey reported in 1999 that 97 percent of streams and 82 percent of lakes in Kansas would not fully support all uses as designated by state statutes (U.S. Geological Survey 1999). Bacteria and...

Informing Lake Erie agriculture nutrient management via scenario evaluation

USGS Publications Warehouse

Scavia, Donald; Kalcic, Margaret; Muenich, Rebecca Logsdon; Aloysius, Noel; Arnold, Jeffrey; Boles, Chelsie; Confesor, Remegio; DePinto, Joseph; Gildow, Marie; Martin, Jay; Read, Jennifer; Redder, Todd; Robertson, Dale M.; Sowa, Scott P.; Wang, Yu-Chen; White, Michael; Yen, Haw

2016-01-01

Therefore, the overall goal of this study was to identify potential options for agricultural management to reduce phosphorus loads and lessen future HABs in Lake Erie. We applied multiple watershed models to test the ability of a series of land management scenarios, developed in consultation with agricultural and environmental stakeholders, to reach the proposed targets. 

Reducing nitrogen export from the corn belt to the Gulf of Mexico: Agricultural strategies for remediating hypoxia

USDA-ARS?s Scientific Manuscript database

We used the SPARROW model for the Upper Mississippi River Basin to evaluate the potential water quality benefits (nutrient load reductions) likely to be achieved by a variety of agricultural conservation practices in the Upper Mississippi-Ohio River system, and to compare these to the 45% nitrogen l...

Effects of prescribed fire on wildlife and wildlife habitat in selected ecosystems of North America

Treesearch

William M. Block; L. Mike Conner; Paul A. Brewer; Paulette Ford; Jonathan Haufler; Andrea Litt; Ronald E. Masters; Laura R. Mitchell; Jane Park

2016-01-01

Prescribed fire is applied widely as a management tool in North America to meet various objectives such as reducing fuel loads and fuel continuity, returning fire to an ecosystem, enhancing wildlife habitats, improving forage, preparing seedbeds, improving watershed conditions, enhancing nutrient cycling, controlling exotic weeds, and enhancing resilience from...

Effects of conifer treatments on soil nutrient availability and plant composition in sagebrush steppe

USDA-ARS?s Scientific Manuscript database

Piñon-juniper woodlands of the western United States have expanded 2 to 10-fold since the late 1800’s. Since the 1950’s woodland control measures using chainsaws, heavy equipment and prescribed fire have been used to reduce woodlands and restore big sagebrush steppe and decrease woody fuel loading. ...

Seasonal variations of nitrogen and phosphorus retention in an agricultural drainage river in East China.

PubMed

Chen, Dingjiang; Lu, Jun; Wang, Hailong; Shen, Yena; Kimberley, Mark O

2010-02-01

Riverine retention decreases loads of nitrogen (N) and phosphorus (P) in running water. It is an important process in nutrient cycling in watersheds. However, temporal riverine nutrient retention capacity varies due to changes in hydrological, ecological, and nutrient inputs into the watershed. Quantitative information of seasonal riverine N and P retention is critical for developing strategies to combat diffuse source pollution and eutrophication in riverine and coastal systems. This study examined seasonal variation of riverine total N (TN) and total P (TP) retention in the ChangLe River, an agricultural drainage river in east China. Water quality, hydrological parameters, and hydrophyte coverage were monitored along the ChangLe River monthly during 2004-2006. Nutrient export loads (including chemical fertilizer, livestock, and domestic sources) entering the river from the catchment area were computed using an export coefficient model based on estimated nutrient sources. Riverine TN and TP retention loads (RNRL and RPRL) were estimated using mass balance calculations. Temporal variations in riverine nutrient retention were analyzed statistically. Estimated annual riverine retention loads ranged from 1,538 to 2,127 t year(-1) for RNRL and from 79.4 to 90.4 t year(-1) for RPRL. Monthly retention loads varied from 6.4 to 300.8 t month(-1) for RNRL and from 1.4 to 15.3 t month(-1) for RPRL. Both RNRL and RPRL increased with river flow, water temperature, hydrophyte coverage, monthly sunshine hours, and total TN and TP inputs. Dissolved oxygen concentration and the pH level of the river water decreased with RNRL and RPRL. Riverine nutrient retention ratios (retention as a percentage of total input) were only related to hydrophyte coverage and monthly sunshine hours. Monthly variations in RNRL and RPRL were functions of TN and TP loads. Riverine nutrient retention capacity varied with environmental conditions. Annual RNRL and RPRL accounted for 30.3-48.3% and 52.5-71.2%, respectively, of total input TN and TP loads in the ChangLe River. Monthly riverine retention ratios were 3.5-88.7% for TN and 20.5-92.6% for TP. Hydrophyte growth and coverage on the river bed is the main cause for seasonal variation in riverine nutrient retention capacity. The total input TN and TP loads were the best indicators of RNRL and RPRL, respectively. High riverine nutrient retention capacity during summer due to hydrophytic growth is favorable to the avoidance of algal bloom in both river systems and coastal water in southeast China. Policies should be developed to strictly control nutrient applications on agricultural lands. Strategies for promoting hydrophyte growth in rivers are desirable for water quality management.

Groundwater flux and nutrient loading in the northeast section of Bear Lake, Muskegon County, Michigan, 2015

USGS Publications Warehouse

Totten, Alexander R.; Maurer, Jessica A.; Duris, Joseph W.

2017-11-30

Bear Lake in North Muskegon, Michigan, is listed as part of the Muskegon Lake area of concern as designated by the U.S. Environmental Protection Agency. This area of concern was designated as a result of eutrophication and beneficial use impairments. On the northeast end of Bear Lake, two man-made retention ponds (Willbrandt Pond East and Willbrandt Pond West), formerly used for celery farming, may contribute nutrients to Bear Lake. Willbrandt Ponds (East and West) were previously muck fields that were actively used for celery farming from the early 1900s until 2002. The restoration and reconnection of the Willbrandt Ponds into Bear Lake prompted concerns of groundwater nutrient loading into Bear Lake. Studies done by the State of Michigan and Grand Valley State University revised initial internal phosphorus load estimates and indicated an imbalance in the phosphorus budget in Bear Lake. From June through November 2015, the U.S. Geological Survey (USGS) did an investigative study to quantify the load of nutrients from shallow groundwater around the Willbrandt Ponds in an effort to update the phosphorus budget to Bear Lake. Seven sampling locations were established, including five shallow groundwater wells and two surface-water sites, in the Willbrandt pond study area and Bear Lake. A total of 12 nutrient samples and discrete water-level measurements were collected from each site from June through November 2015. Continuous water-level data were recorded for both surface-water monitoring locations for the entire sampling period.Water-level data indicated that Willbrandt Pond West had the highest average water-level elevation of all sites monitored, which indicated the general direction of flux is from Willbrandt Pond West to Bear Lake. Nutrient and chloride loading from Willbrandt Pond West to Bear Lake was calculated using two distinct methods: Dupuit and direct seepage methods. Shallow groundwater loading calculations were determined by using groundwater levels to first determine a flux of shallow groundwater, then nutrient concentrations to determine a load. It was determined that Willbrandt Pond East and Willbrandt Pond West contributed between 2 to 4 percent of the total annual phosphorus load to Bear Lake by way of shallow groundwater flow. Annual loads calculated for other constituents include orthophosphate (40–100 pounds per year [lb P/yr]), total nitrogen (200–830 lb/yr), chloride (12,700–32,100 lb/yr), and ammonia (130–670 lb N/yr). Study results indicated that mean groundwater and surface-water nutrient concentrations calculated in this study were higher than reported Michigan statewide values. The data collected in this study allow understanding of groundwater nutrient loading into Bear Lake in an effort to help inform future restoration and management decisions.

Effects of Urban Stormwater Infrastructure and Spatial Scale on Nutrient Export and Runoff from Semi-Arid Urban Catchments

NASA Astrophysics Data System (ADS)

Hale, R. L.; Turnbull, L.; Earl, S.; Grimm, N. B.

2011-12-01

There has been an abundance of literature on the effects of urbanization on downstream ecosystems, particularly due to changes in nutrient inputs as well as hydrology. Less is known, however, about nutrient transport processes and processing in urban watersheds. Engineered drainage systems are likely to play a significant role in controlling the transport of water and nutrients downstream, and variability in these systems within and between cities may lead to differences in the effects of urbanization on downstream ecosystems over time and space. We established a nested stormwater sampling network with 12 watersheds ranging in scale from 5 to 17000 ha in the Indian Bend Wash watershed in Scottsdale, AZ. Small (<200ha) watersheds had uniform land cover (medium density residential), but were drained by a variety of stormwater infrastructure including surface runoff, pipes, natural or modified washes, and retention basins. At the outlet of each of these catchments we monitored rainfall and discharge, and sampled stormwater throughout runoff events for dissolved nitrogen (N), phosphorus (P), and organic carbon (oC). Urban stormwater infrastructure is characterized by a range of hydrologic connectivity. Piped watersheds are highly connected and runoff responds linearly to rainfall events, in contrast to watersheds drained with retention basins and washes, where runoff exhibits a nonlinear threshold response to rainfall events. Nutrient loads from piped watersheds scale linearly with total storm rainfall. Because of frequent flushing, nutrient concentrations from these sites are lower than from wash and retention basin drained sites and total nutrient loads exhibit supply limitation, e.g., nutrient loads are poorly predicted by storm rainfall and are strongly controlled by factors that determine the amount of nutrients stored within the watershed, such as antecedent dry days. In contrast, wash and retention basin-drained watersheds exhibit transport limitation. These watersheds flow less frequently than pipe-drained sites and therefore stormwater has higher concentrations of nutrients, although total loads are significantly lower. Nonlinearities in cross-storm rainfall-nutrient loading relationships for the wash and retention basin watersheds suggest that these systems may become supply limited during large rain events. Results show that characteristics of the hydrologic network such as hydrologic connectivity mediate terrestrial-aquatic linkages. Specifically, we see that increased hydrologic connectivity, as in the piped watershed, actually decreases the predictive power of storm size with regard to nutrient export, whereas nutrient loads from poorly connected watersheds are strongly predicted by storm size.

Using AnnAGNPS to Predict the Effects of Tile Drainage Control on Nutrient and Sediment Loads for a River Basin.

PubMed

Que, Z; Seidou, O; Droste, R L; Wilkes, G; Sunohara, M; Topp, E; Lapen, D R

2015-03-01

Controlled tile drainage (CTD) can reduce pollutant loading. The Annualized Agricultural Nonpoint Source model (AnnAGNPS version 5.2) was used to examine changes in growing season discharge, sediment, nitrogen, and phosphorus loads due to CTD for a ∼3900-km agriculturally dominated river basin in Ontario, Canada. Two tile drain depth scenarios were examined in detail to mimic tile drainage control for flat cropland: 600 mm depth (CTD) and 200 mm (CTD) depth below surface. Summed for five growing seasons (CTD), direct runoff, total N, and dissolved N were reduced by 6.6, 3.5, and 13.7%, respectively. However, five seasons of summed total P, dissolved P, and total suspended solid loads increased as a result of CTD by 0.96, 1.6, and 0.23%. The AnnAGNPS results were compared with mass fluxes observed from paired experimental watersheds (250, 470 ha) in the river basin. The "test" experimental watershed was dominated by CTD and the "reference" watershed by free drainage. Notwithstanding environmental/land use differences between the watersheds and basin, comparisons of seasonal observed and predicted discharge reductions were comparable in 100% of respective cases. Nutrient load comparisons were more consistent for dissolved, relative to particulate water quality endpoints. For one season under corn crop production, AnnAGNPS predicted a 55% decrease (CTD) in dissolved N from the basin. AnnAGNPS v. 5.2 treats P transport from a surface pool perspective, which is appropriate for many systems. However, for assessment of tile drainage management practices for relatively flat tile-dominated systems, AnnAGNPS may benefit from consideration of P and particulate transport in the subsurface. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Nutrient and sediment concentrations, yields, and loads in impaired streams and rivers in the Taunton River Basin, Massachusetts, 1997-2008

USGS Publications Warehouse

Barbaro, Jeffrey R.; Sorenson, Jason R.

2013-01-01

Rapid development, population growth, and the changes in land and water use accompanying development are placing increasing stress on water resources in the Taunton River Basin. An assessment by the Massachusetts Department of Environmental Protection determined that a number of tributary streams to the Taunton River are impaired for a variety of beneficial uses because of nutrient enrichment. Most of the impaired reaches are in the Matfield River drainage area in the vicinity of the City of Brockton. In addition to impairments of stream reaches in the basin, discharge of nutrient-rich water from the Taunton River contributes to eutrophication of Mount Hope and Narragansett Bays. To assess water quality and loading in the impaired tributary stream reaches in the basin, the U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection compiled existing water-quality data from previous studies for the period 1997-2006, developed and calibrated a Hydrological Simulation Program-FORTRAN (HSPF) precipitation-runoff model to simulate streamflow in areas of the basin that contain the impaired reaches for the same time period, and collected additional streamflow and water-quality data from sites on the Matfield and Taunton Rivers in 2008. A majority of the waterquality samples used in the study were collected between 1999 and 2006. Overall, the concentration, yield, and load data presented in this report represent water-quality conditions in the basin for the period 1997-2008. Water-quality data from 52 unique sites were used in the study. Most of the samples from previous studies were collected between June and September under dry weather conditions. Simulated or measured daily mean streamflow and water-quality data were used to estimate constituent yields and loads in the impaired tributary stream reaches and the main stem of the Taunton River and to develop yield-duration plots for reaches with sufficient water-quality data. Total phosphorus concentrations in the impaired-reach areas ranged from 0.0046 to 0.91 milligrams per liter (mg/L) in individual samples (number of samples (n)=331), with a median of 0.090 mg/L; total nitrogen concentrations ranged from 0.34 to 14 mg/L in individual samples (n=139), with a median of 1.35 mg/L; and total suspended solids concentrations ranged from 2/d) for total phosphorus and 100 lb/mi2/d for total nitrogen in these reaches. In most of the impaired reaches not affected by the Brockton Advanced Water Reclamation Facility outfall, yields were lower than in reaches downstream from the outfall, and the difference between measured and threshold yields was fairly uniform over a wide range of flows, suggesting that multiple processes contribute to nonpoint loading in these reaches. The Northeast and Mid-Atlantic SPAtially-Referenced Regression On Watershed (SPARROW) models for total phosphorus and total nitrogen also were used to estimate annual nutrient loads in the impaired tributary stream reaches and main stem of the Taunton River and predict the distribution of these loads among point and diffuse sources in reach drainage areas. SPARROW is a regional, statistical model that relates nutrient loads in streams to upstream sources and land-use characteristics and can be used to make predictions for streams that do not have nutrient-load data. The model predicts mean annual loads based on longterm streamflow and water-quality data and nutrient source conditions for the year 2002. Predicted mean annual nutrient loads from the SPARROW models were consistent with the measured yield and load data from sampling sites in the basin. For conditions in 2002, the Brockton Advanced Water Reclamation Facility outfall accounted for over 75 percent of the total nitrogen load and over 93 percent of the total phosphorus load in the Salisbury Plain and Matfield Rivers downstream from the outfall. Municipal point sources also accounted for most of the load in the main stem of the Taunton River. Multiple municipal wastewater discharges in the basin accounted for about 76 and 46 percent of the delivered loads of total phosphorus and total nitrogen, respectively, to Mount Hope Bay. For similarly sized watersheds, total delivered loads were lower in watersheds without point sources compared to those with point sources, and sources associated with developed land accounted for most of the delivered phosphorus and nitrogen loads to the impaired reaches. The concentration, yield, and load data evaluated in this study may not be representative of current (2012) point-source loading in the basin; in particular, most of the water-quality data used in the study (1999-2006) were collected prior to completion of upgrades to the Brockton Advanced Water Reclamation Facility that reduced total phosphorus and nitrogen concentrations in treated effluent. Effluent concentration data indicate that, for a given flow rate, effluent loads of total phosphorus and total nitrogen declined by about 80 and 30 percent, respectively, between the late 1990s and 2008 in response to plant upgrades. Consequently, current (2012) water-quality conditions in the impaired reaches downstream from the facility likely have improved compared to conditions described in the report.

Combining Natural Attenuation Capacity and use of Targeted Technological Mitigation Measures for Reducing Diffuse Nutrient Emissions to Surface Waters: The Danish Way

NASA Astrophysics Data System (ADS)

Kronvang, B.; Højberg, A. L.; Hoffmann, C. C.; Windolf, J.; Blicher-Mathiesen, G.

2015-12-01

Excess nitrogen (N) and phosphorus (P) emissions to surface waters are a high priority environmental problem worldwide for protection of water resources in times of population growth and climate change. As clean water is a scarce resource the struggle for reducing nutrient emissions are an ongoing issue for many countries and regions. Since the mid1980s a wide range of national regulatory general measures have been implemented to reduce land based nitrogen (N) and phosphorus (P) loadings of the Danish aquatic environment. These measures have addressed both point source emissions and emissions from diffuse sources especially from agricultural production. Following nearly 4 decades of combating nutrient pollution our surface waters such as lakes and estuaries are only slowly responding on the 50% reduction in N and 56% reduction in P. Therefore, the implementation of the EU Water Framework Directive in Danish surface waters still call for further reductions of N and P loadings. Therefore, a new era of targeted implemented measures was the outcome of a Commission on Nature and Agriculture established by the Danish Government in 2013. Their White Book points to the need of increased growth and better environment through more targeted and efficient regulation using advanced technological mitigation methods that are implemented intelligently according to the local natural attenuation capacity for nutrients in the landscape. As a follow up a national consensus model for N was established chaining existing leaching, 3D groundwater and surface water models that enable a calculation of the N dynamics and attenuation capacity within a scale of 15 km2. Moreover, several research projects have been conducted to investigate the effect of a suite of targeted mitigation measures such as restored natural wetlands, constructed wetlands, controlled drainage, buffer strips and constructed buffer strips. The results of these studies will be shared in this presentation.

Effect of phosphorous concentrations on sedimentary distributions and isotopic composition of algal lipid biomarkers in lakes from central Switzerland

NASA Astrophysics Data System (ADS)

Ladd, N.; Dubois, N.; Schubert, C. J.

2015-12-01

Lakes in the Swiss central plateau experienced increasing anthropogenic phosphorous loading throughout much of the 20th century. Since the 1980s concerted remediation efforts on the part of the Swiss government have significantly reduced P concentrations in most lakes and reversed previous eutrophication. However, P concentrations remain elevated above their preindustrial levels in many sites. High quality monitoring of lake nutrient levels since the 1950s, along with several lakes of wide-ranging P concentrations in close proximity, make central Switzerland an ideal location for studying the ways in which nutrient loading affects the organic composition of lacustrine sediments. Results of such studies can be used to develop proxies of eutrophication in sites where fewer historical data exist, and to reconstruct historical P concentrations in local lakes from the time before record keeping began. We analyzed the distributions of algal lipid biomarkers from surface sediment and sediment traps collected in the spring of 2015 from ten lakes with variable P concentrations in central Switzerland. Sedimentary lipid distributions from these lakes confirm that biomarkers associated with algal and cyanobacterial sources are more abundant in the sediment of lakes with greater P loading. The dry sedimentary concentrations of biomarkers such as brassicasterol (primarily diatom source) and diplopterol (cyanobacteria source), as well as the less source specific short-chain n-alkanols, linearly increase from 0.3 - 1.9 μg/g as total phosphorous in the upper water column increases by 1 μg/L over a range of 7 - 50 μg/L. We also present preliminary hydrogen isotope data from these biomarkers. Hydrogen isotopes of algal lipids primarily reflect the source water in which the algae grew, and this relationship has been developed as a paleohydrologic proxy. However, laboratory cultures of marine algae demonstrate that they discriminate more against 2H under nutrient replete conditions. We present the first field assessment of how nutrient availability influences 2H fractionation in freshwater algae, and demonstrate how such measurements can be used to infer past information about anthropogenic nutrient loading.

Evaluating changes in water quality with respect to nonpoint source nutrient management strategies in the Chesapeake Bay Watershed

NASA Astrophysics Data System (ADS)

Keisman, J.; Sekellick, A.; Blomquist, J.; Devereux, O. H.; Hively, W. D.; Johnston, M.; Moyer, D.; Sweeney, J.

2014-12-01

Chesapeake Bay is a eutrophic ecosystem with periodic hypoxia and anoxia, algal blooms, diminished submerged aquatic vegetation, and degraded stocks of marine life. Knowledge of the effectiveness of actions taken across the watershed to reduce nitrogen (N) and phosphorus (P) loads to the bay (i.e. "best management practices" or BMPs) is essential to its restoration. While nutrient inputs from point sources (e.g. wastewater treatment plants and other industrial and municipal operations) are tracked, inputs from nonpoint sources, including atmospheric deposition, farms, lawns, septic systems, and stormwater, are difficult to measure. Estimating reductions in nonpoint source inputs attributable to BMPs requires compilation and comparison of data on water quality, climate, land use, point source discharges, and BMP implementation. To explore the relation of changes in nonpoint source inputs and BMP implementation to changes in water quality, a subset of small watersheds (those containing at least 10 years of water quality monitoring data) within the Chesapeake Watershed were selected for study. For these watersheds, data were compiled on geomorphology, demographics, land use, point source discharges, atmospheric deposition, and agricultural practices such as livestock populations, crop acres, and manure and fertilizer application. In addition, data on BMP implementation for 1985-2012 were provided by the Environmental Protection Agency Chesapeake Bay Program Office (CBPO) and the U.S. Department of Agriculture. A spatially referenced nonlinear regression model (SPARROW) provided estimates attributing N and P loads associated with receiving waters to different nutrient sources. A recently developed multiple regression technique ("Weighted Regressions on Time, Discharge and Season" or WRTDS) provided an enhanced understanding of long-term trends in N and P loads and concentrations. A suite of deterministic models developed by the CBPO was used to estimate expected nutrient load reductions attributable to BMPs. Further quantification of the relation of land-based nutrient sources and BMPs to water quality in the bay and its tributaries must account for inconsistency in BMP data over time and uncertainty regarding BMP locations and effectiveness.

Biomass production in the Lower Mississippi River Basin: Mitigating associated nutrient and sediment discharge to the Gulf of Mexico.

PubMed

Ha, Miae; Zhang, Zhonglong; Wu, May

2018-04-24

A watershed model was developed using the Soil and Water Assessment Tool (SWAT) that simulates nitrogen, phosphorus, and sediment loadings in the Lower Mississippi River Basin (LMRB). The LMRB SWAT model was calibrated and validated using 21 years of observed flow, sediment, and water-quality data. The baseline model results indicate that agricultural lands within the Lower Mississippi River Basin (LMRB) are the dominant sources of nitrogen and phosphorus discharging into the Gulf of Mexico. The model was further used to evaluate the impact of biomass production, in the presence of riparian buffers in the LMRB, on suspended-sediment and nutrient loading discharge from the Mississippi River into the Gulf of Mexico. The interplay among land use, riparian buffers, crop type, land slope, water quality, and hydrology were anlyzed at various scales. Implementing a riparian buffer in the dominant agricultural region within the LMRB could reduce suspended sediment, nitrogen, and phosphorus loadings at the regional scale by up to 65%, 38%, and 39%, respectively. Implementation of this land management practice can reduce the suspended-sediment content and improve the water quality of the discharge from the LMRB into the Gulf of Mexico and support the potential production of bioenergy and bio-products within the Mississippi River Basin. Copyright © 2017 Elsevier B.V. All rights reserved.

Source Separation of Urine as an Alternative Solution to Nutrient Management in Biological Nutrient Removal Treatment Plants.

PubMed

Jimenez, Jose; Bott, Charles; Love, Nancy; Bratby, John

2015-12-01

Municipal wastewater contains a mixture of brown (feces and toilet paper), yellow (urine), and gray (kitchen, bathroom and wash) waters. Urine contributes approximately 70-80% of the nitrogen (N), 50-70% of the phosphorus (P) load and 60-70% of the pharmaceutical residues in normal domestic sewage. This study evaluated the impact of different levels of source separation of urine on an existing biological nutrient removal (BNR) process. A process model of an existing biological nutrient removal (BNR) plant was used. Increasing the amount of urine diverted from the water reclamation facilities, has little impact on effluent ammonia (NH₃-N) concentration, but effluent nitrate (NO₃-N) concentration decreases. If nitrification is necessary then no reduction in the sludge age can be realized. However, a point is reached where the remaining influent nitrogen load matches the nitrogen requirements for biomass growth, and no residual nitrogen needs to be nitrified. That allows a significant reduction in sludge age, implying reduced process volume requirements. In situations where nitrification is required, lower effluent nitrate (NO₃-N) concentrations were realized due to both the lower influent nitrogen content in the wastewater and a more favorable nitrogen-to-carbon ratio for denitrification. The external carbon requirement for denitrification decreases as the urine separation efficiency increases due to the lower influent nitrogen content in the wastewater and a more favorable nitrogen-to-carbon ratio for denitrification. The effluent phosphorus concentration decreases when the amount of urine sent to water reclamation facilities is decreased due to lower influent phosphorus concentrations. In the case of chemical phosphate removal, urine separation reduces the amount of chemicals required.

Spatial optimization of watershed management practices for nitrogen load reduction using a modeling-optimization framework.

PubMed

Yang, Guoxiang; Best, Elly P H

2015-09-15

Best management practices (BMPs) can be used effectively to reduce nutrient loads transported from non-point sources to receiving water bodies. However, methodologies of BMP selection and placement in a cost-effective way are needed to assist watershed management planners and stakeholders. We developed a novel modeling-optimization framework that can be used to find cost-effective solutions of BMP placement to attain nutrient load reduction targets. This was accomplished by integrating a GIS-based BMP siting method, a WQM-TMDL-N modeling approach to estimate total nitrogen (TN) loading, and a multi-objective optimization algorithm. Wetland restoration and buffer strip implementation were the two BMP categories used to explore the performance of this framework, both differing greatly in complexity of spatial analysis for site identification. Minimizing TN load and BMP cost were the two objective functions for the optimization process. The performance of this framework was demonstrated in the Tippecanoe River watershed, Indiana, USA. Optimized scenario-based load reduction indicated that the wetland subset selected by the minimum scenario had the greatest N removal efficiency. Buffer strips were more effective for load removal than wetlands. The optimized solutions provided a range of trade-offs between the two objective functions for both BMPs. This framework can be expanded conveniently to a regional scale because the NHDPlus catchment serves as its spatial computational unit. The present study demonstrated the potential of this framework to find cost-effective solutions to meet a water quality target, such as a 20% TN load reduction, under different conditions. Copyright © 2015 Elsevier Ltd. All rights reserved.

Macrophyte Community Response to Nitrogen Loading and ...

EPA Pesticide Factsheets

Empirical determination of nutrient loading thresholds that negatively impact seagrass communities have been elusive due to the multitude of factors involved. Using a mesocosm system that simulated Pacific Northwest estuaries, we evaluated macrophyte metrics across gradients of NO3 loading (0, 1.5, 3 and 6x ambient) and temperature (10 and 20 °C). Macroalgal growth, biomass, and C:N responded positively to increased NO3 load and floating algal mats developed at 20 ºC. Zostera japonica metrics, including C:N, responded more to temperature than to NO3 loading. Z. marina biomass exhibited a negative temperature effect and in some cases a negative NO3 effect, while growth rate increased with temperature. Shoot survival decreased at 20 ºC but was not influenced by NO3 loading. Wasting disease index exhibited a significant temperature by NO3 interaction consistent with increased disease susceptibility. Community shifts observed were consistent with the nutrient loading hypothesis at 20 ºC, but there was no evidence of other eutrophication symptoms due to the short residence time. The Nutrient Pollution Index tracked the NO3 gradient at 10 ºC but exhibited no response at 20 ºC. We suggest that systems characterized by cool temperatures, high NO3 loads, and short residence time may be resilient to many symptoms of eutrophication. Estuarine systems characterized by cool temperatures, high nutrient loads and rapid flushing may be resilient to some symptoms

Simulation of dissolved nutrient export from the Dongjiang river basin with a grid-based NEWS model

NASA Astrophysics Data System (ADS)

Rong, Qiangqiang; Su, Meirong; Yang, Zhifeng; Cai, Yanpeng; Yue, Wencong; Dang, Zhi

2018-06-01

In this research, a grid-based NEWS model was proposed through coupling the geographic information system (GIS) with the Global NEWS model framework. The model was then applied to the Dongjiang River basin to simulate the dissolved nutrient export from this area. The model results showed that the total amounts of the dissolved nitrogen and phosphorus exported from the Dongjiang River basin were approximately 27154.87 and 1389.33 t, respectively. 90 % of the two loads were inorganic forms (i.e. dissolved inorganic nitrogen and phosphorus, DIN and DIP). Also, the nutrient export loads did not evenly distributed in the basin. The main stream watershed of the Dongjiang River basin has the largest DIN and DIP export loads, while the largest dissolved organic nitrogen and phosphorus (DON and DOP) loads were observed in the middle and upper stream watersheds of the basin, respectively. As for the nutrient exported from each subbasin, different sources had different influences on the output of each nutrient form. For the DIN load in each subbasin, fertilization application, atmospheric deposition and biological fixation were the three main contributors, while eluviation was the most important source for DON. In terms of DIP load, fertilizer application and breeding wastewater were the main contributors, while eluviation and fertilizer application were the two main sources for DOP.

Pollutant loading from low-density residential neighborhoods in California.

PubMed

Bale, Andrew E; Greco, Steven E; Pitton, Bruno J L; Haver, Darren L; Oki, Lorence R

2017-08-01

This paper presents a comparison of pollutant load estimations for runoff from two geographically distinct residential suburban neighborhoods in northern and southern California. The two neighborhoods represent a single urban land use type: low-density residential in small catchments (<0.3 km 2 ) under differing regional climates and irrigation practices. Pollutant loads of pesticides, nutrients, and drinking water constituents of concern are estimated for both storm and non-storm runoff. From continuous flow monitoring, it was found that a daily cycle of persistent runoff that peaks mid-morning occurs at both sites. These load estimations indicate that many residential neighborhoods in California produce significant non-storm pollutant loads year-round. Results suggest that non-storm flow accounted for 47-69% of total annual runoff and significantly contributed to annual loading rates of most nutrients and pesticides at both sites. At the Southern California site, annual non-storm loads are 1.2-10 times higher than storm loads of all conventional constituents and nutrients with one exception (total suspended solids). At the Northern California site, annual storm loads range from 51 to 76% of total loads for all conventional constituents and nutrients with one exception (total dissolved solids). Non-storm yields of pesticides at the Southern California site range from 1.3-65 times higher than those at the Northern California site. The disparity in estimated pollutant loads between the two sites indicates large potential variation from site-to-site within the state and suggests neighborhoods in drier and milder climates may produce significantly larger non-storm loads due to persistent dry season runoff and year-round pest control.

Chronic nutrient enrichment increases prevalence and severity of coral disease and bleaching.

PubMed

Vega Thurber, Rebecca L; Burkepile, Deron E; Fuchs, Corinne; Shantz, Andrew A; McMinds, Ryan; Zaneveld, Jesse R

2014-02-01

Nutrient loading is one of the strongest drivers of marine habitat degradation. Yet, the link between nutrients and disease epizootics in marine organisms is often tenuous and supported only by correlative data. Here, we present experimental evidence that chronic nutrient exposure leads to increases in both disease prevalence and severity and coral bleaching in scleractinian corals, the major habitat-forming organisms in tropical reefs. Over 3 years, from June 2009 to June 2012, we continuously exposed areas of a coral reef to elevated levels of nitrogen and phosphorus. At the termination of the enrichment, we surveyed over 1200 scleractinian corals for signs of disease or bleaching. Siderastrea siderea corals within enrichment plots had a twofold increase in both the prevalence and severity of disease compared with corals in unenriched control plots. In addition, elevated nutrient loading increased coral bleaching; Agaricia spp. of corals exposed to nutrients suffered a 3.5-fold increase in bleaching frequency relative to control corals, providing empirical support for a hypothesized link between nutrient loading and bleaching-induced coral declines. However, 1 year later, after nutrient enrichment had been terminated for 10 months, there were no differences in coral disease or coral bleaching prevalence between the previously enriched and control treatments. Given that our experimental enrichments were well within the ranges of ambient nutrient concentrations found on many degraded reefs worldwide, these data provide strong empirical support to the idea that coastal nutrient loading is one of the major factors contributing to the increasing levels of both coral disease and coral bleaching. Yet, these data also suggest that simple improvements to water quality may be an effective way to mitigate some coral disease epizootics and the corresponding loss of coral cover in the future. © 2013 John Wiley & Sons Ltd.

Are watershed and lacustrine controls on planktonic N2 fixation hierarchically structured?

PubMed

Scott, J Thad; Doyle, Robert D; Prochnow, Shane J; White, Joseph D

2008-04-01

N2 fixation can be an important source of N to limnetic ecosystems and can influence the structure of phytoplankton communities. However, watershed-scale conditions that favor N2 fixation in lakes and reservoirs have not been well studied. We measured N2 fixation and lacustrine variables monthly over a 19-month period in Waco Reservoir, Texas, USA, and linked these data with nutrient-loading estimates from a physically based watershed model. Readily available topographic, soil, land cover, effluent discharge, and climate data were used in the Soil and Water Assessment Tool (SWAT) to derive watershed nutrient-loading estimates. Categorical and regression tree (CART) analysis revealed that lacustrine and watershed correlates of N2 fixation were hierarchically structured. Lacustrine conditions showed greater predictive capability temporally. For instance, low NO3(-) concentration (<25 microg N/L) and high water temperatures (>27 degrees C) in the reservoir were correlated with the initiation of N2 fixation seasonally. When lacustrine conditions were favorable for N2 fixation, watershed conditions appeared to influence spatial patterns of N2 fixation within the reservoir. For example, spatially explicit patterns of N2 fixation were correlated with the ratio of N:P in nutrient loadings and the N loading rate, which were driven by anthropogenic activity in the watershed and periods of low stream flow, respectively. Although N2 fixation contributed <5% of the annual N load to the reservoir, 37% of the N load was derived from atmospheric N2 fixation during summertime when stream flow in the watershed was low. This study provides evidence that watershed anthropogenic activity can exert control on planktonic N2 fixation, but that temporality is controlled by lacustrine conditions. Furthermore, this study also supports suggestions that reduced inflows may increase the propensity of N2-fixing cyanobacterial blooms in receiving waters of anthropogenically modified landscapes.

Modeling the effects of climatic and land use changes on phytoplankton and water quality of the largest Turkish freshwater lake: Lake Beyşehir.

PubMed

Bucak, Tuba; Trolle, Dennis; Tavşanoğlu, Ü Nihan; Çakıroğlu, A İdil; Özen, Arda; Jeppesen, Erik; Beklioğlu, Meryem

2018-04-15

Climate change and intense land use practices are the main threats to ecosystem structure and services of Mediterranean lakes. Therefore, it is essential to predict the future changes and develop mitigation measures to combat such pressures. In this study, Lake Beyşehir, the largest freshwater lake in the Mediterranean basin, was selected to study the impacts of climate change and various land use scenarios on the ecosystem dynamics of Mediterranean freshwater ecosystems and the services that they provide. For this purpose, we linked catchment model outputs to the two different processed-based lake models: PCLake and GLM-AED, and tested the scenarios of five General Circulation Models, two Representation Concentration Pathways and three different land use scenarios, which enable us to consider the various sources of uncertainty. Climate change and land use scenarios generally predicted strong future decreases in hydraulic and nutrient loads from the catchment to the lake. These changes in loads translated into alterations in water level as well as minor changes in chlorophyll a (Chl-a) concentrations. We also observed an increased abundance of cyanobacteria in both lake models. Total phosphorus, temperature and hydraulic loading were found to be the most important variables determining cyanobacteria biomass. As the future scenarios revealed only minor changes in Chl-a due to the significant decrease in nutrient loads, our results highlight that reduced nutrient loading in a warming world may play a crucial role in offsetting the effects of temperature on phytoplankton growth. However, our results also showed increased abundance of cyanobacteria in the future may threaten ecosystem integrity and may limit drinking water ecosystem services. In addition, extended periods of decreased hydraulic loads from the catchment and increased evaporation may lead to water level reductions and may diminish the ecosystem services of the lake as a water supply for irrigation and drinking water. Copyright © 2017 Elsevier B.V. All rights reserved.

Nutrients removal and substrate enzyme activities in vertical subsurface flow constructed wetlands for mariculture wastewater treatment: Effects of ammonia nitrogen loading rates and salinity levels.

PubMed

Li, Meng; Liang, Zhenlin; Callier, Myriam D; Roque d'orbcastel, Emmanuelle; Sun, Guoxiang; Ma, Xiaona; Li, Xian; Wang, Shunkui; Liu, Ying; Song, Xiefa

2018-06-01

This study aims to investigate the effects of ammonia nitrogen loading rates and salinity levels on nutrients removal rates and substrate enzyme activities of constructed wetland (CW) microcosms planted with Salicornia bigelovii treating mariculture wastewater. Activities of urease (UA), dehydrogenase (DA), protease (PrA) and phosphatase (PA) were considered. Using principal component analysis (PCA), nutrient removal index (NRI) and enzyme activity index (EAI) were developed to evaluate the effects. The results revealed that increasing ammonia nitrogen loading rates had positive effects on nitrogen removal rates (i.e. NH 4 -N and DIN) and enhanced substrate enzyme activities. Compared with low salinity (i.e. 15 and 22), high salinity levels (i.e. 29 and 36) enhanced nutrients removal rates, DA and UA, but weaken PA and PrA. In conclusion, CW microcosms with Salicornia bigelovii can be used for the removal of nutrients under a range of ammonia nitrogen loadings and high salinity levels. Copyright © 2018 Elsevier Ltd. All rights reserved.

Elkhorn Slough: Detecting Eutrophication through Geospatial Modeling Applications

NASA Astrophysics Data System (ADS)

Caraballo Álvarez, I. O.; Childs, A.; Jurich, K.

2016-12-01

Elkhorn Slough in Monterey, California, has experienced substantial nutrient loading and eutrophication over the past 21 years as a result of fertilizer-rich runoff from nearby agricultural fields. This study seeks to identify and track spatial patterns of eutrophication hotspots and the correlation to land use changes, possible nutrient sources, and general climatic trends using remotely sensed and in situ data. Threats of rising sea level, subsiding marshes, and increased eutrophication hotspots demonstrate the necessity to analyze the effects of increasing nutrient loads, relative sea level changes, and sedimentation within Elkhorn Slough. The Soil & Water Assessment Tool (SWAT) model integrates specified inputs to assess nutrient and sediment loading and their sources. TerrSet's Land Change Modeler forecasts the future potential of land change transitions for various land cover classes around the slough as a result of nutrient loading, eutrophication, and increased sedimentation. TerrSet's Earth Trends Modeler provides a comprehensive analysis of image time series to rapidly assess long term eutrophication trends and detect spatial patterns of known hotspots. Results from this study will inform future coastal management practices and provide greater spatial and temporal insight into Elkhorn Slough eutrophication dynamics.

Pasture BMP effectiveness using an HRU-based subarea approach in SWAT.

PubMed

Sheshukov, Aleksey Y; Douglas-Mankin, Kyle R; Sinnathamby, Sumathy; Daggupati, Prasad

2016-01-15

Many conservation programs have been established to motivate producers to adopt best management practices (BMP) to minimize pasture runoff and nutrient loads, but a process is needed to assess BMP effectiveness to help target implementation efforts. A study was conducted to develop and demonstrate a method to evaluate water-quality impacts and the effectiveness of two widely used BMPs on a livestock pasture: off-stream watering site and stream fencing. The Soil and Water Assessment Tool (SWAT) model was built for the Pottawatomie Creek Watershed in eastern Kansas, independently calibrated at the watershed outlet for streamflow and at a pasture site for nutrients and sediment runoff, and also employed to simulate pollutant loads in a synthetic pasture. The pasture was divided into several subareas including stream, riparian zone, and two grazing zones. Five scenarios applied to both a synthetic pasture and a whole watershed were simulated to assess various combinations of widely used pasture BMPs: (1) baseline conditions with an open stream access, (2) an off-stream watering site installed in individual subareas in the pasture, and (3) stream or riparian zone fencing with an off-stream watering site. Results indicated that pollutant loads increase with increasing stocking rates whereas off-stream watering site and/or stream fencing reduce time cattle spend in the stream and nutrient loads. These two BMPs lowered organic P and N loads by more than 59% and nitrate loads by 19%, but TSS and sediment-attached P loads remained practically unchanged. An effectiveness index (EI) quantified impacts from the various combinations of off-stream watering sites and fencing in all scenarios. Stream bank contribution to pollutant loads was not accounted in the methodology due to limitations of the SWAT model, but can be incorporated in the approach if an amount of bank soil loss is known for various stocking rates. The proposed methodology provides an adaptable framework for pasture BMP assessment and was utilized to represent a consistent, defensible process to quantify the effectiveness of BMP proposals in a BMP auction in eastern Kansas. Copyright © 2015 Elsevier Ltd. All rights reserved.

Development of an epiphyte indicator of nutrient enrichment. A ...

EPA Pesticide Factsheets

An extensive review of the literature on epiphytes on submerged aquatic vegetation (SAV), primarily seagrasses but including some brackish and freshwater rooted macrophytes, was conducted in order to evaluate the evidence for response of epiphyte metrics to increased nutrients. Evidence from field observational studies together with laboratory and field mesocosm experiments was assembled from the literature and evaluated for evidence of a hypothesized positive response to nutrient addition. There was general consistency in the results to confirm that elevated nutrients tended to increase the load of epiphytes on the surface of SAV, in the absence of other limiting factors. In spite of multiple sources of uncontrolled variation, positive relationships of epiphyte load to nutrient concentration or load (either N or P) were often observed along strong anthropogenic or natural nutrient gradients in coastal regions, although response patterns may only be evident for parts of the year. Mesocosm nutrient studies tended to be more common for temperate regions and field addition studies more common for tropical and subtropical regions. Addition of nutrients via the water column tended to elicit stronger epiphyte responses than sediment additions, and may be a factor in the lack of epiphyte response reported in some studies. Mesograzer activity is a critical covariate for epiphyte response under experimental nutrient elevation, but the epiphyte response is highly de

Hydrology and the effects of selected agricultural best-management practices in the Bald Eagle Creek Watershed, York County, Pennsylvania, prior to and during nutrient management : Water-Quality Study for the Chesapeake Bay Program

USGS Publications Warehouse

Langland, Michael J.; Fishel, David K.

1995-01-01

The U.S. Geological Survey, in cooperation with the Susquehanna River Basin Commission and the Pennsylvania Department of Environmental Resources, conducted a study as part of the U.S. Environmental Protection Agency's Chesapeake Bay Program to determine the effects of nutrient management of surface-water quality by reducing animal units in a 0.43-square-mile agricultural watershed in York County. The study was conducted primarily from October 1985 through September 1990 prior to and during the implementation of nutrient-management practices designed to reduce nutrient and sediment discharges. Intermittent sampling continued until August 1991. The Bald Eagle Creek Basin is underlain by schist and quartzite. About 87 percent of the watershed is cropland and pasture. Nearly 33 percent of the cropland was planted in corn prior to nutrient management, whereas 22 percent of the cropland was planted in corn during the nutrient-management phase. The animal population was reduced by 49 percent during nutrient management. Average annual applications of nitrogen and phosphorus from manure to cropland were reduced by 3,940 pounds (39 percent) and 910 pounds (46 percent), respectively, during nutrient management. A total of 94,560 pounds of nitrogen (538 pounds per acre) and 26,400 pounds of phosphorus (150 pounds per acre) were applied to the cropland as commercial fertilizer and manure during the 5-year study. Core samples from the top 4 feet of soil were collected prior to and during nutrient management and analyzed from concentrations of nitrogen and phosphorus. The average amount of nitrate nitrogen in the soil ranged from 36 to 135 pounds per acre, and soluble phosphorus ranged from 0.39 to 2.5 pounds per acre, prior to nutrient management. During nutrient management, nitrate nitrogen in the soil ranged from 21 to 291 pounds per acre and soluble phosphorus ranged from 0.73 to 1.7 pounds per acre. Precipitation was about 18 percent below normal and streamflow was about 35 percent below normal prior to nutrient management, whereas precipitation was 4 percent above normal and streamflow was 3 percent below normal during the first 2 years of nutrient management. Eighty-four percent of the 20.44 inches of streamflow was base flow prior to nutrient management and 54 percent of the 31.14 inches of streamflow was base flow during the first 2 years of the nutrient-management phase. About 31 percent of the measured precipitation during the first 4 years of the study was discharged as surface water; the remaining 69 percent was removed as evapotranspiration or remained in ground-water storage. Median concentrations of total nitrogen and dissolved nitrate plus nitrite in base flow increased from 4.9 and 4.1 milligrams per liter as nitrogen, respectively, prior to nutrient management to 5.8 and 5.0 milligrams per liter, respectively, during nutrient management. Median concentrations of ammonia nitrogen and organic nitrogen did not change significantly in base flow. Median concentrations of total and dissolved phosphorus in base flow did not change significantly and were 0.05 and 0.03 milligrams per liter as phosphorus, respectively, prior to the management phase, and 0.05 and 0.04 milligrams per liter, respectively, during the management phase. Concentrations and loads of dissolved nitrite plus nitrate in base flow increased following wet periods after crops were harvested and manure was applied. During the growing season, concentrations and loads decreased as nutrient utilization and evapotranspiration by corn increased. About 4,550 pounds of suspended sediment 5,300 pounds of nitrogen, and 70.4 pounds of phosphorous discharged in base flow in the 2 years prior to nutrient management. During the first 2 years of nutrient management about 2,860 pounds of suspended sediment, 5,700 pounds of nitrogen, and 46.6 pounds of phosphorus discharged in base flow. Prior to nutrient management, about 260,000 pounds of suspende

A comparison of drainage basin nutrient inputs with instream nutrient loads for seven rivers in Georgia and Florida, 1986-90

USGS Publications Warehouse

Asbury, C.E.; Oaksford, E.T.

1997-01-01

Instream nutrient loads of the Altamaha, Suwannee, St. Johns, Satilla, Ogeechee, Withlacoochee, and Ochlockonee River Basins were computed and compared with nutrient inputs for each basin for the period 1986-90. Nutrient constituents that were considered included nitrate, ammonia, organic nitrogen, and total phosphorus. Sources of nutrients considered for this analysis included atmospheric deposition, fertilizer, animal waste, wastewater-treatment plant discharge, and septic discharge. The mean nitrogen input ranged from 2,400 kilograms per year per square kilometer (kg/yr)km2 in the Withlacoochee River Basin to 5,470 (kg/yr)km2 in the Altamaha River Basin. The Satilla and Ochlockonee River Basins also had large amounts of nitrogen input per unit area, totaling 5,430 and 4,920 (kg/yr)km2, respectively.Fertilizer or animal waste, as sources of nitrogen, predominated in all basins. Atmospheric deposition contributed less than one-fourth of the mean total nitrogen input to all basins and was consistently the third largest input in all but the Ogeechee River Basin, where it was the second largest.The mean total phosphorus input ranged from 331 (kg/yr)km2 in the Withlacoochee River Basin to 1,380 (kg/yr)km2 in both the Altamaha and Satilla River Basins. The Ochlockonee River Basin had a phosphorus input of 1,140 (kg/yr)km2.Per unit area, the Suwannee River discharged the highest instream mean total nitrogen and phosphorus loads and also discharged higher instream nitrate loads per unit area than the other six rivers. Phosphorus loads in stream discharge were highest in the Suwannee and Ochlockonee Rivers.The ratio of nutrient outputs to inputs for the seven studied rivers ranged from 4.2 to 14.9 percent, with the St. Johns (14.9 percent) and Suwannee (12.1 percent) Rivers having significantly higher percentages than those from the other basins. The output/input percentages for mean total phosphorus ranged from 1.0 to 7.0 percent, with the St. Johns (6.2 percent) and Suwannee (7.0 percent) Rivers exporting the highest percentage of phosphorus.Although instream nutrient loads constitute only one of the various pathways nutrients may take in leaving a river basin, only a relatively small part of nutrient input to the basin leaves the basin in stream discharge for the major coastal rivers examined in this study. The actual amount of nutrient transported in a river basin depends on the ways in which nutrients are physically handled, geographically distributed, and chemically assimilated within a river basin.

On-farm treatment of dairy soiled water using aerobic woodchip filters.

PubMed

Ruane, Eimear M; Murphy, Paul N C; Healy, Mark G; French, Padraig; Rodgers, Michael

2011-12-15

Dairy soiled water (DSW) is produced on dairy farms through the washing-down of milking parlours and holding areas, and is generally applied to land. However, there is a risk of nutrient loss to surface and ground waters from land application. The aim of this study was to use aerobic woodchip filters to remove organic matter, suspended solids (SS) and nutrients from DSW. This novel treatment method would allow the re-use of the final effluent from the woodchip filters to wash down yards, thereby reducing water usage and environmental risks associated with land spreading. Three replicate 100 m(2) farm-scale woodchip filters, each 1 m deep, were constructed and operated to treat DSW from 300 cows over an 11-month study duration. The filters were loaded at a hydraulic loading rate of 30 L m(-2) d(-1), applied in four doses through a network of pipes on the filter surface. Average influent concentrations of chemical oxygen demand (COD), SS and total nitrogen (TN) of 5750 ± 1441 mg L(-1), 602 ± 303 mg L(-1) and 357 ± 100 mg L(-1), respectively, were reduced by 66, 86 and 57% in the filters. Effluent nutrient concentrations remained relatively stable over the study period, indicating the effectiveness of the filter despite increasing and/or fluctuating influent concentrations. Woodchip filters are a low cost, minimal maintenance treatment system, using a renewable resource that can be easily integrated into existing farm infrastructure. Copyright © 2011 Elsevier Ltd. All rights reserved.

Nanocomposite PAAm/methyl cellulose/montmorillonite hydrogel: evidence of synergistic effects for the slow release of fertilizers.

PubMed

Bortolin, Adriel; Aouada, Fauze A; Mattoso, Luiz H C; Ribeiro, Caue

2013-08-07

In this work, we synthesized a novel series of hydrogels composed of polyacrylamide (PAAm), methylcellulose (MC), and calcic montmorillonite (MMt) appropriate for the controlled release of fertilizers, where the components presented a synergistic effect, giving very high fertilizer loading in their structure. The synthesized hydrogel was characterized in relation to morphological, hydrophilic, spectroscopic, structural, thermal, and kinetic properties. After those characterizations, the application potential was verified through sorption and desorption studies of a nitrogenated fertilizer, urea (CO(NH2)2). The swelling degree results showed that the clay loading considerably reduces the water absorption capability; however, the hydrolysis process favored the urea adsorption in the hydrogel nanocomposites, increasing the load content according to the increase of the clay mass. The FTIR spectra indicated that there was incorporation of the clay with the polymeric matrix of the hydrogel and that incorporation increased the water absorption speed (indicated by the kinetic constant k). By an X-ray diffraction technique, good nanodispersion (intercalation) and exfoliation of the clay platelets in the hydrogel matrix were observed. Furthermore, the presence of the montmorillonite in the hydrogel caused the system to liberate the nutrient in a more controlled manner than that with the neat hydrogel in different pH ranges. In conclusion, excellent results were obtained for the controlled desorption of urea, highlighting the hydrolyzed hydrogels containing 50% calcic montmorillonite. This system presented the best desorption results, releasing larger amounts of nutrient and almost 200 times slower than pure urea, i.e., without hydrogel. The total values of nutrients present in the system show that this material is potentially viable for application in agriculture as a nutrient carrier vehicle.

Tile Drainage Management Influences on Surface-Water and Groundwater Quality following Liquid Manure Application.

PubMed

Frey, Steven K; Topp, Ed; Ball, Bonnie R; Edwards, Mark; Gottschall, Natalie; Sunohara, Mark; Zoski, Erin; Lapen, David R

2013-01-01

This study investigated the potential for controlled tile drainage (CD) to reduce bacteria and nutrient loading to surface water and groundwater from fall-season liquid manure application (LMA) on four macroporous clay loam plots, of which two had CD and two had free-draining (FD) tiles. Rhodamine WT (RWT) was mixed into the manure and monitored in the tile water and groundwater following LMA. Tile water and groundwater quality were influenced by drainage management. Following LMA on the FD plots, RWT, nutrients, and bacteria moved rapidly via tiles to surface water; at the CD plots, tiles did not flow until the first post-LMA rainfall, so the immediate risk of LMA-induced contamination of surface water was abated. During the 36-d monitoring period, flow-weighted average specific conductance, redox potential, and turbidity, as well as total Kjeldahl N (TKN), total P (TP), NH-N, reactive P, and RWT concentrations, were higher in the CD tile effluent; however, because of lower tile discharge from the CD plots, there was no significant ( ≤ 0.05) difference in surface water nutrient and RWT loading between the CD and FD plots when all tiles were flowing. The TKN, TP, and RWT concentrations in groundwater also tended to be higher at the CD plots. Bacteria behaved differently than nutrients and RWT, with no significant difference in total coliform, , fecal coliform, fecal streptococcus, and concentrations between the CD and FD tile effluent; however, for all but , hourly loading was higher from the FD plots. Results indicate that CD has potential for mitigating bacteria movement to surface water. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Nutrient sources and transport in the Missouri River Basin, with emphasis on the effects of irrigation and reservoirs

USGS Publications Warehouse

Brown, J.B.; Sprague, L.A.; Dupree, J.A.

2011-01-01

SPAtially Referenced Regressions On Watershed attributes (SPARROW) models were used to relate instream nutrient loads to sources and factors influencing the transport of nutrients in the Missouri River Basin. Agricultural inputs from fertilizer and manure were the largest nutrient sources throughout a large part of the basin, although atmospheric and urban inputs were important sources in some areas. Sediment mobilized from stream channels was a source of phosphorus in medium and larger streams. Irrigation on agricultural land was estimated to decrease the nitrogen load reaching the Mississippi River by as much as 17%, likely as a result of increased anoxia and denitrification in the soil zone. Approximately 16% of the nitrogen load and 33% of the phosphorus load that would have otherwise reached the Mississippi River was retained in reservoirs and lakes throughout the basin. Nearly half of the total attenuation occurred in the eight largest water bodies. Unlike the other major tributary basins, nearly the entire instream nutrient load leaving the outlet of the Platte and Kansas River subbasins reached the Mississippi River. Most of the larger reservoirs and lakes in the Platte River subbasin are upstream of the major sources, whereas in the Kansas River subbasin, most of the source inputs are in the southeast part of the subbasin where characteristics of the area and proximity to the Missouri River facilitate delivery of nutrients to the Mississippi River.

Nutrient Sources and Transport in the Missouri River Basin, with Emphasis on the Effects of Irrigation and Reservoirs1

PubMed Central

Brown, Juliane B; Sprague, Lori A; Dupree, Jean A

2011-01-01

Abstract SPAtially Referenced Regressions On Watershed attributes (SPARROW) models were used to relate instream nutrient loads to sources and factors influencing the transport of nutrients in the Missouri River Basin. Agricultural inputs from fertilizer and manure were the largest nutrient sources throughout a large part of the basin, although atmospheric and urban inputs were important sources in some areas. Sediment mobilized from stream channels was a source of phosphorus in medium and larger streams. Irrigation on agricultural land was estimated to decrease the nitrogen load reaching the Mississippi River by as much as 17%, likely as a result of increased anoxia and denitrification in the soil zone. Approximately 16% of the nitrogen load and 33% of the phosphorus load that would have otherwise reached the Mississippi River was retained in reservoirs and lakes throughout the basin. Nearly half of the total attenuation occurred in the eight largest water bodies. Unlike the other major tributary basins, nearly the entire instream nutrient load leaving the outlet of the Platte and Kansas River subbasins reached the Mississippi River. Most of the larger reservoirs and lakes in the Platte River subbasin are upstream of the major sources, whereas in the Kansas River subbasin, most of the source inputs are in the southeast part of the subbasin where characteristics of the area and proximity to the Missouri River facilitate delivery of nutrients to the Mississippi River. PMID:22457581

Simulation of hydrodynamics, water quality, and lake sturgeon habitat volumes in Lake St. Croix, Wisconsin and Minnesota, 2013

USGS Publications Warehouse

Smith, Erik A.; Kiesling, Richard L.; Ziegeweid, Jeffrey R.; Elliott, Sarah M.; Magdalene, Suzanne

2018-01-05

Lake St. Croix is a naturally impounded, riverine lake that makes up the last 40 kilometers of the St. Croix River. Substantial land-use changes during the past 150 years, including increased agriculture and urban development, have reduced Lake St. Croix water-quality and increased nutrient loads delivered to Lake St. Croix. A recent (2012–13) total maximum daily load phosphorus-reduction plan set the goal to reduce total phosphorus loads to Lake St. Croix by 20 percent by 2020 and reduce Lake St. Croix algal bloom frequencies. The U.S. Geological Survey, in cooperation with the National Park Service, developed a two-dimensional, carbon-based, laterally averaged, hydrodynamic and water-quality model, CE–QUAL–W2, that addresses the interaction between nutrient cycling, primary production, and trophic dynamics to predict responses in the distribution of water temperature, oxygen, and chlorophyll a. Distribution is evaluated in the context of habitat for lake sturgeon, including a combination of temperature and dissolved oxygen conditions termed oxy-thermal habitat.The Lake St. Croix CE–QUAL–W2 model successfully reproduced temperature and dissolved oxygen in the lake longitudinally (from upstream to downstream), vertically, and temporally over the seasons. The simulated water temperature profiles closely matched the measured water temperature profiles throughout the year, including the prediction of thermocline transition depths (often within 1 meter), the absolute temperature of the thermocline transitions (often within 1.0 degree Celsius), and profiles without a strong thermocline transition. Simulated dissolved oxygen profiles matched the trajectories of the measured dissolved oxygen concentrations at multiple depths over time, and the simulated concentrations matched the depth and slope of the measured concentrations.Additionally, trends in the measured water-quality data were captured by the model simulation, gaining some potential insights into the underlying mechanisms of critical Lake St. Croix metabolic processes. The CE–QUAL–W2 model tracked nitrate plus nitrite, total nitrogen, and total phosphorus throughout the year. Inflow nutrient contributions (loads), largely dominated by upstream St. Croix River loads, were the most important controls on Lake St. Croix water quality. Close to 60 percent of total phosphorus to the lake was from phosphorus derived from organic matter, and about 89 percent of phosphorus to Lake St. Croix was delivered by St. Croix River inflows. The Lake St. Croix CE–QUAL–W2 model offered potential mechanisms for the effect of external and internal loadings on the biotic response regarding the modeled algal community types of diatoms, green algae, and blue-green algae. The model also suggested the seasonal dominance of blue-green algae in all four pools of the lake.A sensitivity analysis was completed to test the total maximum daily load phosphorus-reduction scenario responses of total phosphorus and chlorophyll a. The modeling indicates that phosphorus reductions would result in similar Lake St. Croix reduced concentrations, although chlorophyll a concentrations did not decrease in the same proportional amounts as the total phosphorus concentrations had decreased. The smaller than expected reduction in algal growth rates highlighted that although inflow phosphorus loads are important, other constituents also can affect the algal response of the lake, such as changes in light penetration and the breakdown of organic matter releasing nutrients.The available habitat suitable for lake sturgeon was evaluated using the modeling results to determine the total volume of good-growth habitat, optimal growth habitat, and lethal temperature habitat. Overall, with the calibrated model, the fish habitat volume in general contained a large proportion of good-growth habitat and a sustained period of optimal growth habitat in the summer. Only brief periods of lethal oxy-thermal habitat were present in Lake St. Croix during the model simulation.

Internal ecosystem feedbacks enhance nitrogen-fixing cyanobacteria blooms and complicate management in the Baltic Sea.

PubMed

Vahtera, Emil; Conley, Daniel J; Gustafsson, Bo G; Kuosa, Harri; Pitkänen, Heikki; Savchuk, Oleg P; Tamminen, Timo; Viitasalo, Markku; Voss, Maren; Wasmund, Norbert; Wulff, Fredrik

2007-04-01

Eutrophication of the Baltic Sea has potentially increased the frequency and magnitude of cyanobacteria blooms. Eutrophication leads to increased sedimentation of organic material, increasing the extent of anoxic bottoms and subsequently increasing the internal phosphorus loading. In addition, the hypoxic water volume displays a negative relationship with the total dissolved inorganic nitrogen pool, suggesting greater overall nitrogen removal with increased hypoxia. Enhanced internal loading of phosphorus and the removal of dissolved inorganic nitrogen leads to lower nitrogen to phosphorus ratios, which are one of the main factors promoting nitrogenfixing cyanobacteria blooms. Because cyanobacteria blooms in the open waters of the Baltic Sea seem to be strongly regulated by internal processes, the effects of external nutrient reductions are scale-dependent. During longer time scales, reductions in external phosphorus load may reduce cyanobacteria blooms; however, on shorter time scales the internal phosphorus loading can counteract external phosphorus reductions. The coupled processes inducing internal loading, nitrogen removal, and the prevalence of nitrogen-fixing cyanobacteria can qualitatively be described as a potentially self-sustaining "vicious circle." To effectively reduce cyanobacteria blooms and overall signs of eutrophication, reductions in both nitrogen and phosphorus external loads appear essential.

Data to support statistical modeling of instream nutrient load based on watershed attributes, southeastern United States, 2002

USGS Publications Warehouse

Hoos, Anne B.; Terziotti, Silvia; McMahon, Gerard; Savvas, Katerina; Tighe, Kirsten C.; Alkons-Wolinsky, Ruth

2008-01-01

This report presents and describes the digital datasets that characterize nutrient source inputs, environmental characteristics, and instream nutrient loads for the purpose of calibrating and applying a nutrient water-quality model for the southeastern United States for 2002. The model area includes all of the river basins draining to the south Atlantic and the eastern Gulf of Mexico, as well as the Tennessee River basin (referred to collectively as the SAGT area). The water-quality model SPARROW (SPAtially-Referenced Regression On Watershed attributes), developed by the U.S. Geological Survey, uses a regression equation to describe the relation between watershed attributes (predictors) and measured instream loads (response). Watershed attributes that are considered to describe nutrient input conditions and are tested in the SPARROW model for the SAGT area as source variables include atmospheric deposition, fertilizer application to farmland, manure from livestock production, permitted wastewater discharge, and land cover. Watershed and channel attributes that are considered to affect rates of nutrient transport from land to water and are tested in the SAGT SPARROW model as nutrient-transport variables include characteristics of soil, landform, climate, reach time of travel, and reservoir hydraulic loading. Datasets with estimates of each of these attributes for each individual reach or catchment in the reach-catchment network are presented in this report, along with descriptions of methods used to produce them. Measurements of nutrient water quality at stream monitoring sites from a combination of monitoring programs were used to develop observations of the response variable - mean annual nitrogen or phosphorus load - in the SPARROW regression equation. Instream load of nitrogen and phosphorus was estimated using bias-corrected log-linear regression models using the program Fluxmaster, which provides temporally detrended estimates of long-term mean load well-suited for spatial comparisons. The detrended, or normalized, estimates of load are useful for regional-scale assessments but should be used with caution for local-scale interpretations, for which use of loads estimated for actual time periods and employing more detailed regression analysis is suggested. The mean value of the nitrogen yield estimates, normalized to 2002, for 637 stations in the SAGT area is 4.7 kilograms per hectare; the mean value of nitrogen flow-weighted mean concentration is 1.2 milligrams per liter. The mean value of the phosphorus yield estimates, normalized to 2002, for the 747 stations in the SAGT area is 0.66 kilogram per hectare; the mean value of phosphorus flow-weighted mean concentration is 0.17 milligram per liter. Nutrient conditions measured in streams affected by substantial influx or outflux of water and nutrient mass across surface-water basin divides do not reflect nutrient source and transport conditions in the topographic watershed; therefore, inclusion of such streams in the SPARROW modeling approach is considered inappropriate. River basins identified with this concern include south Florida (where surface-water flow paths have been extensively altered) and the Oklawaha, Crystal, Lower Sante Fe, Lower Suwanee, St. Marks, and Chipola River basins in central and northern Florida (where flow exchange with the underlying regional aquifer may represent substantial nitrogen influx to and outflux from the surface-water basins).

Adaptive Management of Return Flows: Lessons from a Case Study in Environmental Water Delivery to a Floodplain River

NASA Astrophysics Data System (ADS)

Wolfenden, Benjamin J.; Wassens, Skye M.; Jenkins, Kim M.; Baldwin, Darren S.; Kobayashi, Tsuyoshi; Maguire, James

2018-03-01

For many floodplain rivers, reinstating wetland connectivity is necessary for ecosystems to recover from decades of regulation. Environmental return flows (the managed delivery of wetland water to an adjacent river) can be used strategically to facilitate natural ecosystem connectivity, enabling the transfer of nutrients, energy, and biota from wetland habitats to the river. Using an informal adaptive management framework, we delivered return flows from a forested wetland complex into a large lowland river in south-eastern Australia. We hypothesized that return flows would (a) increase river nutrient concentrations; (b) reduce wetland nutrient concentrations; (c) increase rates of ecosystem metabolism through the addition of potentially limiting nutrients, causing related increases in the concentration of water column chlorophyll-a; and (d) increase the density and species richness of microinvertebrates in riverine benthic habitats. Our monitoring results demonstrated a small increase in the concentrations of several key nutrients but no evidence for significant ecological responses was found. Although return flows can be delivered from forested floodplain areas without risking hypoxic blackwater events, returning nutrient and carbon-rich water to increase riverine productivity is limited by the achievable scale of return flows. Nevertheless, using return flows to flush carbon from floodplains may be a useful management tool to reduce carbon loads, preparing floodplains for subsequent releases (e.g., mitigating the risk of hypoxic blackwater events). In this example, adaptive management benefited from a semi-formal collaboration between science and management that allowed for prompt decision-making.

Low rate loading-induced convection enhances net transport into the intervertebral disc in vivo.

PubMed

Gullbrand, Sarah E; Peterson, Joshua; Mastropolo, Rosemarie; Roberts, Timothy T; Lawrence, James P; Glennon, Joseph C; DiRisio, Darryl J; Ledet, Eric H

2015-05-01

The intervertebral disc primarily relies on trans-endplate diffusion for the uptake of nutrients and the clearance of byproducts. In degenerative discs, diffusion is often diminished by endplate sclerosis and reduced proteoglycan content. Mechanical loading-induced convection has the potential to augment diffusion and enhance net transport into the disc. The ability of convection to augment disc transport is controversial and has not been demonstrated in vivo. To determine if loading-induced convection can enhance small molecule transport into the intervertebral disc in vivo. Net transport was quantified via postcontrast enhanced magnetic resonance imaging (MRI) into the discs of the New Zealand white rabbit lumbar spine subjected to in vivo cyclic low rate loading. Animals were administered the MRI contrast agent gadodiamide intravenously and subjected to in vivo low rate loading (0.5 Hz, 200 N) via a custom external loading apparatus for either 2.5, 5, 10, 15, or 20 minutes. Animals were then euthanized and the lumbar spines imaged using postcontrast enhanced MRI. The T1 constants in the nucleus, annulus, and cartilage endplates were quantified as a measure of gadodiamide transport into the loaded discs compared with the adjacent unloaded discs. Microcomputed tomography was used to quantify subchondral bone density. Low rate loading caused the rapid uptake and clearance of gadodiamide in the nucleus compared with unloaded discs, which exhibited a slower rate of uptake. Relative to unloaded discs, low rate loading caused a maximum increase in transport into the nucleus of 16.8% after 5 minutes of loading. Low rate loading increased the concentration of gadodiamide in the cartilage endplates at each time point compared with unloaded levels. Results from this study indicate that forced convection accelerated small molecule uptake and clearance in the disc induced by low rate mechanical loading. Low rate loading may, therefore, be therapeutic to the disc as it may enhance the nutrient uptake and waste product clearance. Copyright © 2015 Elsevier Inc. All rights reserved.

Assessing the response of the Pamlico Sound, North Carolina, USA to human and climatic disturbances: Management implications

USGS Publications Warehouse

Paerl, H.W.; Peierls, B.L.; Hall, N. S.; Joyner, A. R.; Christian, R.R.; Bales, Jerad D.; Riggs, S.R.

2010-01-01

The Pamlico Sound (PS) with its sub-estuaries is the largest lagoonal ecosystem in the United States. It exhibits periodically strong salinity stratification and an average freshwater residence time of 1 year for the sound proper. This relatively long residence time promotes effective use and cycling of nutrients, allowing the system to support high rates of primary and secondary production, and serve as a vitally important fisheries nursery. This hydrologic characteristic also makes the system highly sensitive to nutrient over-enrichment and eutrophication. The PS is experiencing ecological change in response to increasing human activity and climatic perturbations. Human impacts include a rise in nutrient, sediment, and other pollutant loads that accompany urbanization and agricultural and industrial growth in its watersheds and airsheds. Since the mid-1990s, the PS has witnessed a sudden rise in tropical storm and hurricane impacts, with eight hurricanes and four tropical storms having made landfall in the PS watershed during the 1996 to 2007 period. Each of these storms had unique hydrologic, nutrient, and other pollutant loading effects. In addition, since the early 2000s, the region has experienced record droughts, which are continuing. Variable freshwater discharges from storms and droughts have caused large oscillations in nutrient enrichment, reflected ultimately in differential phytoplankton production, biomass, and community compositional responses. Floodwaters from the two wettest hurricanes, Fran (1996) and Floyd (1999), and from Tropical Storm Ernesto (2006) exerted long-term (months) effects on hydrology, nutrient loads, and algal production. Windy but relatively dry hurricanes, like Irene (1999) and Isabel (2003), caused strong vertical mixing, storm surges, but relatively minor changes in river flow, flushing, and nutrient loads. These contrasting effects are accompanied by biogeochemical (hypoxia, nutrient cycling) and habitat alterations, and associated food web disturbances. Each storm type influenced algal growth and compositional dynamics; however, their respective ecological impacts differed substantially. Changes in hydrologic and wind forcing resulting from changes in frequency and intensity of storms and droughts strongly influence water and habitat quality. These changes must be integrated with nutrient loading/dilution effects when assessing and predicting ecological responses to nutrient and hydrologic variability on this and other large lagoonal ecosystems.

Nutrient production from dairy cattle manure and loading on arable land

PubMed Central

You, Byung-Gu; Choi, Yoon-Seok; Ra, Changsix

2017-01-01

Objective Along with increasing livestock products via intensive rearing, the accumulation of livestock manure has become a serious issue due to the fact that there is finite land for livestock manure recycling via composting. The nutrients from livestock manure accumulate on agricultural land and the excess disembogues into streams causing eutrophication. In order to systematically manage nutrient loading on agricultural land, quantifying the amount of nutrients according to their respective sources is very important. However, there is a lack of research concerning nutrient loss from livestock manure during composting or storage on farms. Therefore, in the present study we quantified the nutrients from dairy cattle manure that were imparted onto agricultural land. Methods Through investigation of 41 dairy farms, weight reduction and volatile solids (VS), total nitrogen (TN), and total phosphorus (TP) changes of dairy cattle manure during the storage and composting periods were analyzed. In order to support the direct investigation and survey on site, the three cases of weight reduction during the storing and composting periods were developed according to i) experiment, ii) reference, and iii) theoretical changes in phosphorus content (ΔP = 0). Results The data revealed the nutrient loading coefficients (NLCs) of VS, TN, and TP on agricultural land were 1.48, 0.60, and 0.66, respectively. These values indicated that the loss of nitrogen and phosphorus was 40% and 34%, respectively, and that there was an increase of VS since bedding materials were mixed with excretion in the barn. Conclusion As result of nutrient-footprint analyses, the amounts of TN and TP particularly entered on arable land have been overestimated if applying the nutrient amount in fresh manure. The NLCs obtained in this study may assist in the development of a database to assess the accurate level of manure nutrient loading on soil and facilitate systematic nutrient management. PMID:27492346

Identification of watershed priority management areas under water quality constraints: A simulation-optimization approach with ideal load reduction

NASA Astrophysics Data System (ADS)

Dong, Feifei; Liu, Yong; Wu, Zhen; Chen, Yihui; Guo, Huaicheng

2018-07-01

Targeting nonpoint source (NPS) pollution hot spots is of vital importance for placement of best management practices (BMPs). Although physically-based watershed models have been widely used to estimate nutrient emissions, connections between nutrient abatement and compliance of water quality standards have been rarely considered in NPS hotspot ranking, which may lead to ineffective decision-making. It's critical to develop a strategy to identify priority management areas (PMAs) based on water quality response to nutrient load mitigation. A water quality constrained PMA identification framework was thereby proposed in this study, based on the simulation-optimization approach with ideal load reduction (ILR-SO). It integrates the physically-based Soil and Water Assessment Tool (SWAT) model and an optimization model under constraints of site-specific water quality standards. To our knowledge, it was the first effort to identify PMAs with simulation-based optimization. The SWAT model was established to simulate temporal and spatial nutrient loading and evaluate effectiveness of pollution mitigation. A metamodel was trained to establish a quantitative relationship between sources and water quality. Ranking of priority areas is based on required nutrient load reduction in each sub-watershed targeting to satisfy water quality standards in waterbodies, which was calculated with genetic algorithm (GA). The proposed approach was used for identification of PMAs on the basis of diffuse total phosphorus (TP) in Lake Dianchi Watershed, one of the three most eutrophic large lakes in China. The modeling results demonstrated that 85% of diffuse TP came from 30% of the watershed area. Compared with the two conventional targeting strategies based on overland nutrient loss and instream nutrient loading, the ILR-SO model identified distinct PMAs and narrowed down the coverage of management areas. This study addressed the urgent need to incorporate water quality response into PMA identification and showed that the ILR-SO approach is effective to guide watershed management for aquatic ecosystem restoration.

Assessing nutrient flows in septic tanks by eliciting expert judgement: a promising method in the context of developing countries.

PubMed

Montangero, Agnes; Belevi, Hasan

2007-03-01

Simple models based on the physical and biochemical processes occurring in septic tanks, pit and urine diversion latrines were developed to determine the nutrient flows in these systems. Nitrogen and phosphorus separation in different output materials from these on-site sanitation installations were thus determined. Moreover, nutrient separation in septic tanks was also assessed through literature values and by eliciting expert judgement. Use of formal expert elicitation technique proved to be effective, particularly in the context of developing countries where data is often scarce but expert judgement readily available. In Vietnam, only 5-14% and 11-27% of the nitrogen and phosphorus input, respectively, are removed from septic tanks with the faecal sludge. The remaining fraction leaves the tank via the liquid effluent. Unlike septic tanks, urine diversion latrines allow to immobilize most of the nutrients either in form of stored urine or dehydrated faecal matter. These latrines thus contribute to reducing the nutrient load in the environment and lowering consumption of energy and non-renewable resources for fertiliser production.

Mercury in the pelagic food web of Lake Champlain.

PubMed

Miller, Eric K; Chen, Celia; Kamman, Neil; Shanley, James; Chalmers, Ann; Jackson, Brian; Taylor, Vivien; Smeltzer, Eric; Stangel, Pete; Shambaugh, Angela

2012-04-01

Lake Champlain continues to experience mercury contamination resulting in public advisories to limit human consumption of top trophic level fish such as walleye. Prior research suggested that mercury levels in biota could be modified by differences in ecosystem productivity as well as mercury loadings. We investigated relationships between mercury in different trophic levels in Lake Champlain. We measured inorganic and methyl mercury in water, seston, and two size fractions of zooplankton from 13 sites representing a range of nutrient loading conditions and productivity. Biomass varied significantly across lake segments in all measured ecosystem compartments in response to significant differences in nutrient levels. Local environmental factors such as alkalinity influenced the partitioning of mercury between water and seston. Mercury incorporation into biota was influenced by the biomass and mercury content of different ecosystem strata. Pelagic fish tissue mercury was a function of fish length and the size of the mercury pool associated with large zooplankton. We used these observations to parameterize a model of mercury transfers in the Lake Champlain food web that accounts for ecosystem productivity effects. Simulations using the mercury trophic transfer model suggest that reductions of 25-75% in summertime dissolved eplimnetic total mercury will likely allow fish tissue mercury concentrations to drop to the target level of 0.3 μg g(-1) in a 40-cm fish in all lake segments. Changes in nutrient loading and ecosystem productivity in eutrophic segments may delay any response to reduced dissolved mercury and may result in increases in fish tissue mercury.

Winery wastewater treatment using the land filter technique.

PubMed

Christen, E W; Quayle, W C; Marcoux, M A; Arienzo, M; Jayawardane, N S

2010-08-01

This study outlines a new approach to the treatment of winery wastewater by application to a land FILTER (Filtration and Irrigated cropping for Land Treatment and Effluent Reuse) system. The land FILTER system was tested at a medium size rural winery crushing approximately 20,000 tonnes of grapes. The approach consisted of a preliminary treatment through a coarse screening and settling in treatment ponds, followed by application to the land FILTER planted to pasture. The land FILTER system efficiently dealt with variable volumes and nutrient loads in the wastewater. It was operated to minimize pollutant loads in the treated water (subsurface drainage) and provide adequate leaching to manage salt in the soil profile. The land FILTER system was effective in neutralizing the pH of the wastewater and removing nutrient pollutants to meet EPA discharge limits. However, suspended solids (SS) and biological oxygen demand (BOD) levels in the subsurface drainage waters slightly exceeded EPA limits for discharge. The high organic content in the wastewater initially caused some soil blockage and impeded drainage in the land FILTER site. This was addressed by reducing the hydraulic loading rate to allow increased soil drying between wastewater irrigations. The analysis of soil characteristics after the application of wastewater found that there was some potassium accumulation in the profile but sodium and nutrients decreased after wastewater application. Thus, the wastewater application and provision of subsurface drainage ensured adequate leaching, and so was adequate to avoid the risk of soil salinisation. Crown Copyright 2010. Published by Elsevier Ltd. All rights reserved.

Mercury in the Pelagic Food Web of Lake Champlain

PubMed Central

Chen, Celia; Kamman, Neil; Shanley, James; Chalmers, Ann; Jackson, Brian; Taylor, Vivien; Smeltzer, Eric; Stangel, Pete; Shambaugh, Angela

2013-01-01

Lake Champlain continues to experience mercury contamination resulting in public advisories to limit human consumption of top trophic level fish such as walleye. Prior research suggested that mercury levels in biota could be modified by differences in ecosystem productivity as well as mercury loadings. We investigated relationships between mercury in different trophic levels in Lake Champlain. We measured inorganic and methyl mercury in water, seston, and two size fractions of zooplankton from 13 sites representing a range of nutrient loading conditions and productivity. Biomass varied significantly across lake segments in all measured ecosystem compartments in response to significant differences in nutrient levels. Local environmental factors such as alkalinity influenced the partitioning of mercury between water and seston. Mercury incorporation into biota was influenced by the biomass and mercury content of different ecosystem strata. Pelagic fish tissue mercury was a function of fish length and the size of the mercury pool associated with large zooplankton. We used these observations to parameterize a model of mercury transfers in the Lake Champlain food web that accounts for ecosystem productivity effects. Simulations using the mercury trophic transfer model suggest that reductions of 25 to 75% in summertime dissolved eplimnetic total mercury will likely allow fish tissue mercury concentrations to drop to the target level of 0.3 µg g−1 in a 40-cm fish in all lake segments. Changes in nutrient loading and ecosystem productivity in eutrophic segments may delay any response to reduced dissolved mercury and may result in increases in fish tissue mercury. PMID:22193540

Variation in chlorophyll content per unit leaf area in spring wheat and implications for selection in segregating material.

PubMed

Hamblin, John; Stefanova, Katia; Angessa, Tefera Tolera

2014-01-01

Reduced levels of leaf chlorophyll content per unit leaf area in crops may be of advantage in the search for higher yields. Possible reasons include better light distribution in the crop canopy and less photochemical damage to leaves absorbing more light energy than required for maximum photosynthesis. Reduced chlorophyll may also reduce the heat load at the top of canopy, reducing water requirements to cool leaves. Chloroplasts are nutrient rich and reducing their number may increase available nutrients for growth and development. To determine whether this hypothesis has any validity in spring wheat requires an understanding of genotypic differences in leaf chlorophyll content per unit area in diverse germplasm. This was measured with a SPAD 502 as SPAD units. The study was conducted in series of environments involving up to 28 genotypes, mainly spring wheat. In general, substantial and repeatable genotypic variation was observed. Consistent SPAD readings were recorded for different sampling positions on leaves, between different leaves on single plant, between different plants of the same genotype, and between different genotypes grown in the same or different environments. Plant nutrition affected SPAD units in nutrient poor environments. Wheat genotypes DBW 10 and Transfer were identified as having consistent and contrasting high and low average SPAD readings of 52 and 32 units, respectively, and a methodology to allow selection in segregating populations has been developed.

The use of acoustic doppler meters to estimate sediment and nutrient concentrations in freshwater inflows to Texas coastal ecosystems

Treesearch

Zullmar Lucena; Micheal Lee

2016-01-01

Excessive sediment and nutrient loading are among the leading causes of impairment in water bodies of the United States due to their effect on biologic productivity, water quality, and aquatic food webs. Understanding the nutrient and suspended sediment loads affecting estuarine waters is fundamental to the assessment of the physical, chemical, and biological processes...

Climate change and wetland loss impacts on a western river's water quality

NASA Astrophysics Data System (ADS)

Records, R. M.; Arabi, M.; Fassnacht, S. R.; Duffy, W. G.; Ahmadi, M.; Hegewisch, K. C.

2014-11-01

An understanding of potential stream water quality conditions under future climate is critical for the sustainability of ecosystems and the protection of human health. Changes in wetland water balance under projected climate could alter wetland extent or cause wetland loss (e.g., via increased evapotranspiration and lower growing season flows leading to reduced riparian wetland inundation) or altered land use patterns. This study assessed the potential climate-induced changes to in-stream sediment and nutrient loads in the snowmelt-dominated Sprague River, Oregon, western US. Additionally, potential water quality impacts of combined changes in wetland water balance and wetland area under future climatic conditions were evaluated. The study utilized the Soil and Water Assessment Tool (SWAT) forced with statistical downscaling of general circulation model (GCM) data from the Coupled Model Intercomparison Project 5 (CMIP5) using the Multivariate Adaptive Constructed Analogs (MACA) method. Our findings suggest that, in the Sprague River, (1) mid-21st century nutrient and sediment loads could increase significantly during the high-flow season under warmer, wetter climate projections or could change only nominally in a warmer and somewhat drier future; (2) although water quality conditions under some future climate scenarios and no wetland loss may be similar to the past, the combined impact of climate change and wetland losses on nutrient loads could be large; (3) increases in stream total phosphorus (TP) concentration with wetland loss under future climate scenarios would be greatest at high-magnitude, low-probability flows; and (4) loss of riparian wetlands in both headwaters and lowlands could increase outlet TP loads to a similar degree, but this could be due to distinctly different mechanisms in different parts of the watershed.

Forecasting future phosphorus export to the Laurentian Great Lakes from land-derived nutrient inputs

NASA Astrophysics Data System (ADS)

LaBeau, M. B.; Robertson, D. M.; Mayer, A. S.; Pijanowski, B. C.

2011-12-01

Anthropogenic use of the land through agricultural and urban activities has significantly increased phosphorus loading to rivers that flow to the Great Lakes. Phosphorus (P) is a critical element in the eutrophication of the freshwater ecosystems, most notably the Great Lakes. To better understand factors influencing phosphorus delivery to aquatic systems and thus their potential harmful effects to lake ecosystems, models that predict P export should incorporate account for changing changes in anthropogenic activities. Land-derived P from high yielding sources, such as agriculture and urban areas, affect eutrophication at various scales (e.g. specific bays to all of Lake Erie). SPARROW (SPAtially Referenced Regression On Watershed attributes) is a spatially explicit watershed model that has been used to understand linkages between land-derived sources and nutrient transport to the Great Lakes. The Great Lakes region is expected to experience a doubling of urbanized areas along with a ten percent increase in agricultural use over the next 40 years, which is likely to increase P loading. To determine how these changes will impact P loading, SPARROW have been developed that relate changes in land use to changes in nutrient sources, including relationships between row crop acreage and fertilizer intensity and urban land use and point source intensity. We used land use projections from the Land Transformation Model, a, spatially explicit, neural-net based land change model. Land use patterns from current to 2040 were used as input into HydroSPARROW, a forecasting tool that enables SPARROW to simulate the effects of various land-use and climate scenarios. Consequently, this work is focusing on understanding the effects of how specific agriculture and urbanization activities affect P loading in the watersheds of the Laurentian Great Lakes to potentially find strategies to reduce the extent and severity of future eutrophication.

Context-dependent effects of nutrient loading on the coral-algal mutualism.

PubMed

Shantz, Andrew A; Burkepile, Deron E

2014-07-01

Human-mediated increases in nutrient availability alter patterns of primary production, impact species diversity, and threaten ecosystem function. Nutrients can also alter community structure by disrupting the relationships between nutrient-sharing mutualists that form the foundation of communities. Given their oligotrophic nature and the dependence of reef-building corals on symbiotic relationships, coral reefs may be particularly vulnerable to excess nutrients. However, individual studies suggest complex, even contradictory, relationships among nutrient availability, coral physiology, and coral growth. Here, we used meta-analysis to establish general patterns of the impact of nitrogen (N) and phosphorus (P) on coral growth and photobiology. Overall, we found that over a wide range of concentrations, N reduced coral calcification 11%, on average, but enhanced metrics of coral photobiology, such as photosynthetic rate. In contrast, P enrichment increased average calcification rates by 9%, likely through direct impacts on the calcification process, but minimally impacted coral photobiology. There were few synergistic impacts of combined N and P on corals, as the nutrients impact corals via different pathways. Additionally, the response of corals to increasing nutrient availability was context dependent, varying with coral taxa and morphology, enrichment source, and nutrient identity. For example, naturally occurring enrichment from fish excretion increased coral growth, while human-mediated enrichment tended to decrease coral growth. Understanding the nuances of the relationship between nutrients and corals may allow for more targeted remediation strategies and suggest how other global change drivers such as overfishing and climate change will shape how nutrient availability impacts corals.

Nutrition labels in bar graph format deemed most useful for consumer purchase decisions using adaptive conjoint analysis.

PubMed

Geiger, C J; Wyse, B W; Parent, C R; Hansen, R G

1991-07-01

This study estimated the effects of changing multiple levels and combinations of nutrition information format, load, expression, and order on consumers' perceptions of label usefulness in purchase decisions using adaptive conjoint analysis. A shopping mall intercept survey, which was administered by a marketing research firm, assessed consumer preferences for 12 label alternatives produced on Campbell's soup cans to portray nutrition information realistically; 252 of 258 respondents completed the computer interactive interview. Consumers significantly preferred the bar graph format to the bar graph/nutrient density and traditional label formats. Consumers considered the bar graph/nutrient density format to be as useful as the traditional label format. There was a highly significant difference among the three levels of information load; the most information load was preferred regardless of nutrient importance. Consumers significantly preferred nutrition information stated in absolute numbers and percentages vs in absolute numbers only in traditional, or in percentages only expressions. There was a significant difference between consumer preferences for the two types of information order. The findings indicate that consumers clearly preferred the nutrition label that displayed all nutrient values using a bar graph format, offered the most information load, and expressed nutrient values using both absolute numbers and percentages. Consumers also preferred nutrition information rearranged in an order that grouped nutrients that should be consumed in adequate amounts on the top, calories in the middle, and nutrients that should be consumed in lesser amounts on the bottom of the label.

Digital data used to relate nutrient inputs to water quality in the Chesapeake Bay watershed

USGS Publications Warehouse

Brakebill, John W.; Preston, Stephen D.

1999-01-01

Digital data sets were compiled by the U. S. Geological Survey (USGS) and used as input for a collection of Spatially Referenced Regressions On Watershed attributes for the Chesapeake Bay region. These regressions relate streamwater loads to nutrient sources and the factors that affect the transport of these nutrients throughout the watershed. A digital segmented network based on watershed boundaries serves as the primary foundation for spatially referencing total nitrogen and total phosphorus source and land-surface characteristic data sets within a Geographic Information System. Digital data sets of atmospheric wet deposition of nitrate, point-source discharge locations, land cover, and agricultural sources such as fertilizer and manure were created and compiled from numerous sources and represent nitrogen and phosphorus inputs. Some land-surface characteristics representing factors that affect the transport of nutrients include land use, land cover, average annual precipitation and temperature, slope, and soil permeability. Nutrient input and land-surface characteristic data sets merged with the segmented watershed network provide the spatial detail by watershed segment required by the models. Nutrient stream loads were estimated for total nitrogen, total phosphorus, nitrate/nitrite, amonium, phosphate, and total suspended soilds at as many as 109 sites within the Chesapeake Bay watershed. The total nitrogen and total phosphorus load estimates are the dependent variables for the regressions and were used for model calibration. Other nutrient-load estimates may be used for calibration in future applications of the models.

Nutrient Enrichment Drives Gulf of Mexico Hypoxia

NASA Astrophysics Data System (ADS)

Boesch, Donald F.; Boynton, Walter R.; Crowder, Larry B.; Diaz, Robert J.; Howarth, Robert W.; Mee, Laurence D.; Nixon, Scott W.; Rabalais, Nancy N.; Rosenberg, Rutger; Sanders, James G.; Scavia, Donald; Turner, R. Eugene

2009-04-01

During most summers over the past 30 years, bottom dissolved oxygen across a large area of the Louisiana and upper Texas continental shelf declined to concentrations too low (hypoxia) for most fish and large invertebrate animals to survive. This area is one of the best known “dead zones” proliferating around the world [Diaz and Rosenberg, 2008]. During July 2008, hypoxic bottom waters extended across 20,720 square kilometers (Figure 1), but they were probably even more extensive because winds from Hurricane Dolly mixed the waters off Texas before the survey could be completed. Increased inputs of nutrients (principally nitrogen and phosphorus) from the U.S. agricultural heartland within the Mississippi-Atchafalaya River Basin (MARB) are implicated in the development and spread of hypoxia in the Gulf of Mexico. Consequently, the causes of, and solutions for, hypoxia have been subjects of extensive debate and analysis. An integrated scientific assessment led to a 2001 Action Plan [Mississippi River/Gulf of Mexico Watershed Nutrient Task Force, 2001] with a goal of reducing the area of the hypoxic zone to less than 5000 square kilometers by reducing nitrogen loading [Rabalais et al., 2007].

A scenario and forecast model for Gulf of Mexico hypoxic area and volume

USGS Publications Warehouse

Scavia, Donald; Evans, Mary Anne; Obenour, Daniel R.

2013-01-01

For almost three decades, the relative size of the hypoxic region on the Louisiana-Texas continental shelf has drawn scientific and policy attention. During that time, both simple and complex models have been used to explore hypoxia dynamics and to provide management guidance relating the size of the hypoxic zone to key drivers. Throughout much of that development, analyses had to accommodate an apparent change in hypoxic sensitivity to loads and often cull observations due to anomalous meteorological conditions. Here, we describe an adaptation of our earlier, simple biophysical model, calibrated to revised hypoxic area estimates and new hypoxic volume estimates through Bayesian estimation. This application eliminates the need to cull observations and provides revised hypoxic extent estimates with uncertainties, corresponding to different nutrient loading reduction scenarios. We compare guidance from this model application, suggesting an approximately 62% nutrient loading reduction is required to reduce Gulf hypoxia to the Action Plan goal of 5,000 km2, to that of previous applications. In addition, we describe for the first time, the corresponding response of hypoxic volume. We also analyze model results to test for increasing system sensitivity to hypoxia formation, but find no strong evidence of such change.

Uneven nutrient load and potential offsite loss

USDA-ARS?s Scientific Manuscript database

Landscape and management often results in uneven nutrient loads within a field. The hypotheses of this study are that: 1) phosphorus accumulates at low areas in the landscape adjacent to waterways; and 2) nitrate at lower landscape positions will be decreased in the subsoil due to denitrification an...

Quantitative Models for Ecosystem Assessment in Narragansett Bay: Response to Nutrient Loading and Other Stressors

EPA Science Inventory

Multiple drivers, including nutrient loading and climate change, affect the Narragansett Bay ecosystem. Managers are interested in understanding the timing and magnitude of these effects, as well as ecosystem responses to restoration actions, such as the capacity and potential fo...

Development of an epiphyte indicator of nutrient enrichment: Threshold values for seagrass epiphyte load

EPA Science Inventory

Metrics of epiphyte load on macrophytes were evaluated for use as quantitative biological indicators for nutrient impacts in estuarine waters, based on review and analysis of the literature on epiphytes and macrophytes, primarily seagrasses, but including some brackish and freshw...

FUTURE AQUATIC NUTRIENT LIMITATIONS. (R827785E02)

EPA Science Inventory

Nutrient limitation of phytoplankton growth in aquatic systems is moving towards a higher incidence of P and Si limitation as a result of increased nitrogen loading, a N:P fertilizer use of 26:1 (molar basis), population growth, and relatively stable silicate loading. This res...

Study of nonpoint source nutrient loading in the Patuxent River basin, Maryland

USGS Publications Warehouse

Preston, S.D.

1997-01-01

Study of nonpoint-source (NPS) nutrient loading in Maryland has focused on the Patuxent watershed because of its importance and representativeness of conditions in the State. Evaluation of NPS nutrient loading has been comprehensive and has included long-term monitoring, detailed watershed modeling, and synoptic sampling studies. A large amount of information has been compiled for the watershed and that information is being used to identify primary controls and efficient management strategies for NPS nutrient loading. Results of the Patuxent NPS study have identified spatial trends in water quality that appear to be related to basin charcteristics such as land use, physiography, andgeology. Evaluation of the data compiled by the study components is continuing and is expected to provide more detailed assessments of the reasons for spatial trends. In particular, ongoing evaluation of the watershed model output is expected to provide detailed information on the relative importance of nutrient sources and transport pathways across the entire watershed. Planned future directions of NPS evaluation in the State of Maryland include continued study of water quality in the Patuxent watershed and a shift in emphasis to a statewide approach. Eventually, the statewide approach will become the primary approach usedby the State to evaluate NPS loading. The information gained in the Patuxent study and the tools developed will represent valuable assets indeveloping the statewide NPS assessment program.

Pinon-juniper reduction increases soil water availability of the resource growth pool

Treesearch

Bruce A. Roundy; Kert Young; Nathan Cline; April Hulet; Richard F. Miller; Robin J. Tausch; Jeanne C. Chambers; Ben Rau

2014-01-01

Managers reduce piñon (Pinus spp.) and juniper (Juniperus spp.) trees that are encroaching on sagebrush (Artemisia spp.) communities to lower fuel loads and increase cover of desirable understory species. All plant species in these communities depend on soil water held at > −1.5 MPa matric potential in the upper 0.3 m of soil for nutrient...

Future riverine nitrogen export to US coastal regions ...

EPA Pesticide Factsheets

Excess nitrogen (N) in the environment degrades ecosystems and adversely affects human health. Here we examine predictions of contemporary (2000) and future (2030) coastal N loading in the continental US by the Nutrient Export from WaterSheds (NEWS) model. Future output is from storylines of the Millennium Ecosystem Assessment (MEA) and two additional scenarios that reflect “business as usual” and “ambitious” approaches to nutrient management. Modeled total nitrogen (TN) export by rivers to US coastal areas ranged between 2.5 Tg N y-1 in 2000 and 1.9 - 3.0 Tg N y-1 in 2030, depending on scenario. Differences among scenarios reflect the interactions of increased food and energy demands associated with population growth and efforts to reduce losses of N to the environment. Depending on year and scenario, agriculture supplies 25-43% of coastal TN, atmospheric N deposition 6-8%, human sewage 6-12%, and natural and particulate N sources account for the remainder. Our analysis suggests that achieving reductions in coastal N loading will require aggressive management actions. Coastal TN export could be reduced 22% between 2000 and 2030 to 1.9 Tg N y-1 if currently available best management practices and technologies are fully implemented to control N from agriculture, fossil fuel emissions, and wastewater effluent. If N management capabilities do not improve by 2030, coastal N loads could increase 20% to 3.0 Tg N y-1, due primarily to increases in N from agricu

Classification of Regional Patterns of Environmental Drivers and Benthic Habitats in Pacific Northwest Estuaries

EPA Science Inventory

While increased anthropogenic nutrient loading of coastal ecosystems is a growing ecological and economic problem both in the U.S. and globally, the extent of such excess nutrient loading in Pacific Northwest estuaries is poorly known. To help determine the vulnerability of Pacif...

Expansion of the MANAGE database with forest and drainage studies

USDA-ARS?s Scientific Manuscript database

The “Measured Annual Nutrient loads from AGricultural Environments” (MANAGE) database was published in 2006 to expand an early 1980’s compilation of nutrient export (load) data from agricultural land uses at the field or farm spatial scale. Then in 2008, MANAGE was updated with 15 additional studie...

Application of Hierarchy Theory to Cross-Scale Hydrologic Modeling of Nutrient Loads

EPA Science Inventory

We describe a model called Regional Hydrologic Modeling for Environmental Evaluation 16 (RHyME²) for quantifying annual nutrient loads in stream networks and watersheds. RHyME² is 17 a cross-scale statistical and process-based water-quality model. The model ...

DEVELOPMENT OF NITROGEN LOADING-RESPONSE RELATIONSHIPS FOR ESTUARINE WATERS USING AN EMPIRICAL COMPARATIVE SYSTEMS APPROACH

EPA Science Inventory

There is growing evidence that human activities have dramatically changed the amounts, distribution, and movement of major nutrient elements (nitrogen-N and phosphorus-P) in the landscape and have increased nutrient loading to receiving waters. Some of these changes affect use o...

Long-term changes in the phosphorus loading to and trophic state of the Salton Sea, California

USGS Publications Warehouse

Robertson, Dale M.; Schladow, S.G.; Holdren, G.C.

2008-01-01

The Salton Sea (Sea) is a eutrophic to hypereutrophic lake characterized by high nutrient concentrations, low water clarity, and high biological productivity. Based on dissolved phosphorus (P) and nitrogen (N) concentrations and N:P ratios, P is typically the limiting nutrient in the Sea and, therefore, should be the primary nutrient of concern when considering management efforts. Flows in the major tributaries to the Sea have been measured since 1965, whereas total P (TP) concentrations were only measured intermittently by various agencies since 1968. These data were used to estimate annual P loading from 1965 to 2002. Annual loads have increased steadily from ???940,000 kg around 1968 to ???1,450,000 kg in 2002 (???55% increase), primarily a result of increased TP concentrations and loads in the New River. Although the eutrophic condition of the Salton Sea is of great concern, only limited nutrient data are available for the Sea. It is difficult to determine whether the eutrophic state of the Sea has degraded or possibly even improved slightly in response to the change in P loading because of variability in the data and changes in the sampling and analytical methodologies. ?? 2008 Springer Science+Business Media B.V.

Agricultural utilization of biosolids: A review on potential effects on soil and plant grown.

PubMed

Sharma, Bhavisha; Sarkar, Abhijit; Singh, Pooja; Singh, Rajeev Pratap

2017-06-01

Environmental and economic implications linked with the proper ecofriendly disposal of modern day wastes, has made it essential to come up with alternative waste management practices that reduce the environmental pressures resulting from unwise disposal of such wastes. Urban wastes like biosolids are loaded with essential plant nutrients. In this view, agricultural use of biosolids would enable recycling of these nutrients and could be a sustainable approach towards management of this hugely generated waste. Therefore biosolids i.e. sewage sludge can serve as an important resource for agricultural utilization. Biosolids are characterized by the occurrence of beneficial plant nutrients (essential elements and micro and macronutrients) which can make help them to work as an effective soil amendment, thereby minimizing the reliance on chemical fertilizers. However, biosolids might contain toxic heavy metals that may limit its usage in the cropland. Heavy metals at higher concentration than the permissible limits may lead to food chain contamination and have fatal consequences. Biosolids amendment in soil can improve physical and nutrient property of soil depending on the quantity and portion of the mixture. Hence, biosolids can be a promising soil ameliorating supplement to increase plant productivity, reduce bioavailability of heavy metals and also lead to effective waste management. Copyright © 2017 Elsevier Ltd. All rights reserved.

Economic analysis of best management practices to reduce watershed phosphorus losses.

PubMed

Rao, Nalini S; Easton, Zachary M; Lee, David R; Steenhuis, Tammo S

2012-01-01

In phosphorus-limited freshwater systems, small increases in phosphorus (P) concentrations can lead to eutrophication. To reduce P inputs to these systems, various environmental and agricultural agencies provide producers with incentives to implement best management practices (BMPs). In this study, we examine both the water quality and economic consequences of systematically protecting saturated, runoff-generating areas from active agriculture with selected BMPs. We also examine the joint water quality/economic impacts of these BMPs-specifically BMPs focusing on barnyards and buffer areas. Using the Variable Source Loading Function model (a modified Generalized Watershed Loading Function model) and net present value analysis (NPV), the results indicate that converting runoff-prone agricultural land to buffers and installing barnyard BMPs are both highly effective in decreasing dissolved P loss from a single-farm watershed, but are also costly for the producer. On average, including barnyard BMPs decreases the nutrient loading by about 5.5% compared with only implementing buffers. The annualized NPV for installing both buffers on only the wettest areas of the landscape and implementing barnyard BMPs becomes positive only if the BMPs lifetime exceeds 15 yr. The spatial location of the BMPs in relation to runoff producing areas, the time frame over which the BMPs are implemented, and the marginal costs of increasing buffer size were found to be the most critical considerations for water quality and profitability. The framework presented here incorporates estimations of nutrient loading reductions in the economic analysis, and is applicable to farms facing BMP adoption decisions. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

SUSPENDED AND BENTHIC SEDIMENT RELATIONSHIPS IN THE YAQUINA ESTUARY, OREGON: NUTRIENT PROCESSING

EPA Science Inventory

Measurements of nutrient loading and subsequent nutrient processing are fundamental for determining biogeochemical processes in rivers and estuaries. In Oregon coastal watersheds, nutrient transport is strongly seasonal with up to 94% of the riverine dissolved nitrate and silic...

Water and nutrient budgets for Vancouver Lake, Vancouver, Washington, October 2010-October 2012

USGS Publications Warehouse

Sheibley, Rich W.; Foreman, James R.; Marshall, Cameron A.; Welch, Wendy B.

2014-01-01

Vancouver Lake, a large shallow lake in Clark County, near Vancouver, Washington, has been undergoing water-quality problems for decades. Recently, the biggest concern for the lake are the almost annual harmful cyanobacteria blooms that cause the lake to close for recreation for several weeks each summer. Despite decades of interest in improving the water quality of the lake, fundamental information on the timing and amount of water and nutrients entering and exiting the lake is lacking. In 2010, the U.S. Geological Survey conducted a 2-year field study to quantify water flows and nutrient loads in order to develop water and nutrient budgets for the lake. This report presents monthly and annual water and nutrient budgets from October 2010–October 2012 to identify major sources and sinks of nutrients. Lake River, a tidally influenced tributary to the lake, flows into and out of the lake almost daily and composed the greatest proportion of both the water and nutrient budgets for the lake, often at orders of magnitude greater than any other source. From the water budget, we identified precipitation, evaporation and groundwater inflow as minor components of the lake hydrologic cycle, each contributing 1 percent or less to the total water budget. Nutrient budgets were compiled monthly and annually for total nitrogen, total phosphorus, and orthophosphate; and, nitrogen loads were generally an order of magnitude greater than phosphorus loads across all sources. For total nitrogen, flow from Lake River at Felida, Washington, made up 88 percent of all inputs into the lake. For total phosphorus and orthophosphate, Lake River at Felida flowing into the lake was 91 and 76 percent of total inputs, respectively. Nutrient loads from precipitation and groundwater inflow were 1 percent or less of the total budgets. Nutrient inputs from Burnt Bridge Creek and Flushing Channel composed 12 percent of the total nitrogen budget, 8 percent of the total phosphorus budget, and 21 percent of the orthophosphate budget. We identified several data gaps and areas for future research, which include the need for better understanding nutrient inputs to the lake from sediment resuspension and better quantification of indirect nutrient inputs to the lake from Salmon Creek.

Environmental and economic trade-offs in a watershed when using corn stover for bioenergy.

PubMed

Gramig, Benjamin M; Reeling, Carson J; Cibin, Raj; Chaubey, Indrajeet

2013-02-19

There is an abundant supply of corn stover in the United States that remains after grain is harvested which could be used to produce cellulosic biofuels mandated by the current Renewable Fuel Standard (RFS). This research integrates the Soil Water Assessment Tool (SWAT) watershed model and the DayCent biogeochemical model to investigate water quality and soil greenhouse gas flux that results when corn stover is collected at two different rates from corn-soybean and continuous corn crop rotations with and without tillage. Multiobjective watershed-scale optimizations are performed for individual pollutant-cost minimization criteria based on the economic cost of each cropping practice and (individually) the effect on nitrate, total phosphorus, sediment, or global warming potential. We compare these results with a purely economic optimization that maximizes stover production at the lowest cost without taking environmental impacts into account. We illustrate trade-offs between cost and different environmental performance criteria, assuming that nutrients contained in any stover collected must be replaced. The key finding is that stover collection using the practices modeled results in increased contributions to atmospheric greenhouse gases while reducing nitrate and total phosphorus loading to the watershed relative to the status quo without stover collection. Stover collection increases sediment loading to waterways relative to when no stover is removed for each crop rotation-tillage practice combination considered; no-till in combination with stover collection reduced sediment loading below baseline conditions without stover collection. Our results suggest that additional information is needed about (i) the level of nutrient replacement required to maintain grain yields and (ii) cost-effective management practices capable of reducing soil erosion when crop residues are removed in order to avoid contributions to climate change and water quality impairments as a result of using corn stover to satisfy the RFS.

Optimal implementation of green infrastructure practices to minimize influences of land use change and climate change on hydrology and water quality: Case study in Spy Run Creek watershed, Indiana.

PubMed

Liu, Yaoze; Engel, Bernard A; Collingsworth, Paris D; Pijanowski, Bryan C

2017-12-01

Nutrient loading from the Maumee River watershed is a significant reason for the harmful algal blooms (HABs) problem in Lake Erie. The nutrient loading from urban areas needs to be reduced with the installation of green infrastructure (GI) practices. The Long-Term Hydrologic Impact Assessment-Low Impact Development 2.1 (L-THIA-LID 2.1) model was used to explore the influences of land use (LU) and climate change on water quantity and quality in Spy Run Creek watershed (SRCW) (part of Maumee River watershed), decide whether and where excess phosphorus loading existed, identify critical areas to understand where the greatest amount of runoff/pollutants originated, and optimally implement GI practices to obtain maximum environmental benefits with the lowest costs. Both LU/climate changes increased runoff/pollutants generated from the watershed. Areas with the highest runoff/pollutant amount per area, or critical areas, differed for various environmental concerns, land uses (LUs), and climates. Compared to optimization considering all areas, optimization conducted only in critical areas can provide similar cost-effective results with decreased computational time for low levels of runoff/pollutant reductions, but critical area optimization results were not as cost-effective for higher levels of runoff/pollutant reductions. Runoff/pollutants for 2011/2050 LUs/climates could be reduced to amounts of 2001 LU/climate by installation of GI practices with annual expenditures of $0.34 to $2.05 million. The optimization scenarios that were able to obtain the 2001 runoff level in 2011/2050, can also reduce all pollutants to 2001 levels in this watershed. Copyright © 2017 Elsevier B.V. All rights reserved.

Importance of diffuse pollution control in the Patzcuaro Lake Basin in Mexico.

PubMed

Carro, Marco Mijangos; Dávila, Jorge Izurieta; Balandra, Antonieta Gómez; López, Rubén Hernández; Delgadillo, Rubén Huerto; Chávez, Javier Sánchez; Inclán, Luís Bravo

2008-01-01

In the catchment area of the Lake Patzcuaro in Central Mexico (933 km2) the apportionments of erosion, sediment, nutrients and pathogen coming from thirteen micro basins were estimated with the purpose of identifying critical areas in which best management practices need to be implemented in order to reduce their contribution to the lake pollution and eutrophication. The ArcView Generalized Watershed Loading Functions model (AV-GWLF) was applied to estimate the loads and sources of nutrients. The main results show that the total annual contribution of nitrogen from point sources were 491 tons and from diffuse pollution 2,065 tons, whereas phosphorus loads where 116 and 236 tons, respectively during a thirty year simulation period. Micro basins with predominant agricultural and animal farm land use (56% of the total area) accounts for a high percentage of nitrogen load 33% and phosphorus 52%. On the other hand, Patzcuaro and Quiroga micro basins which comprise approximately 10% of the total catchment area and are the most populated and visited towns by tourist 686,000 people every year, both contributes with 10.1% of the total nitrogen load and 3.2% of phosphorus. In terms of point sources of nitrogen and phosphorus the last towns contribute with 23.5% and 26.6% respectively. Under this situation the adoption of best management practices are an imperative task since the sedimentation and pollution in the lake has increased dramatically in the last twenty years. Copyright (c) IWA Publishing 2008.

Nutrient and sediment concentrations and corresponding loads during the historic June 2008 flooding in eastern Iowa

USGS Publications Warehouse

Hubbard, L.; Kolpin, D.W.; Kalkhoff, S.J.; Robertson, Dale M.

2011-01-01

A combination of above-normal precipitation during the winter and spring of 2007-2008 and extensive rainfall during June 2008 led to severe flooding in many parts of the midwestern United States. This resulted in transport of substantial amounts of nutrients and sediment from Iowa basins into the Mississippi River. Water samples were collected from 31 sites on six large Iowa tributaries to the Mississippi River to characterize water quality and to quantify nutrient and sediment loads during this extreme discharge event. Each sample was analyzed for total nitrogen, dissolved nitrate plus nitrite nitrogen, dissolved ammonia as nitrogen, total phosphorus, orthophosphate, and suspended sediment. Concentrations measured near peak flow in June 2008 were compared with the corresponding mean concentrations from June 1979 to 2007 using a paired t test. While there was no consistent pattern in concentrations between historical samples and those from the 2008 flood, increased flow during the flood resulted in near-peak June 2008 flood daily loads that were statistically greater (p < 0.05) than the median June 1979 to 2007 daily loads for all constituents. Estimates of loads for the 16-d period during the flood were calculated for four major tributaries and totaled 4.95 x 10(7) kg of nitrogen (N) and 2.9 x 10(6) kg of phosphorus (P) leaving Iowa, which accounted for about 22 and 46% of the total average annual nutrient yield, respectively. This study demonstrates the importance of large flood events to the total annual nutrient load in both small streams and large rivers.

Application of a Three-Dimensional Water Quality Model as a Decision Support Tool for the Management of Land-Use Changes in the Catchment of an Oligotrophic Lake

NASA Astrophysics Data System (ADS)

Trolle, Dennis; Spigel, Bob; Hamilton, David P.; Norton, Ned; Sutherland, Donna; Plew, David; Allan, Mathew G.

2014-09-01

While expansion of agricultural land area and intensification of agricultural practices through irrigation and fertilizer use can bring many benefits to communities, intensifying land use also causes more contaminants, such as nutrients and pesticides, to enter rivers, lakes, and groundwater. For lakes such as Benmore in the Waitaki catchment, South Island, New Zealand, an area which is currently undergoing agricultural intensification, this could potentially lead to marked degradation of water clarity as well as effects on ecological, recreational, commercial, and tourism values. We undertook a modeling study to demonstrate science-based options for consideration of agricultural intensification in the catchment of Lake Benmore. Based on model simulations of a range of potential future nutrient loadings, it is clear that different areas within Lake Benmore may respond differently to increased nutrient loadings. A western arm (Ahuriri) could be most severely affected by land-use changes and associated increases in nutrient loadings. Lake-wide annual averages of an eutrophication indicator, the trophic level index (TLI) were derived from simulated chlorophyll a, total nitrogen, and total phosphorus concentrations. Results suggest that the lake will shift from oligotrophic (TLI = 2-3) to eutrophic (TLI = 4-5) as external loadings are increased eightfold over current baseline loads, corresponding to the potential land-use intensification in the catchment. This study provides a basis for use of model results in a decision-making process by outlining the environmental consequences of a series of land-use management options, and quantifying nutrient load limits needed to achieve defined trophic state objectives.

Nutrient and sediment concentrations and corresponding loads during the historic June 2008 flooding in eastern Iowa.

PubMed

Hubbard, L; Kolpin, D W; Kalkhoff, S J; Robertson, D M

2011-01-01

A combination of above-normal precipitation during the winter and spring of 2007-2008 and extensive rainfall during June 2008 led to severe flooding in many parts of the midwestern United States. This resulted in transport of substantial amounts of nutrients and sediment from Iowa basins into the Mississippi River. Water samples were collected from 31 sites on six large Iowa tributaries to the Mississippi River to characterize water quality and to quantify nutrient and sediment loads during this extreme discharge event. Each sample was analyzed for total nitrogen, dissolved nitrate plus nitrite nitrogen, dissolved ammonia as nitrogen, total phosphorus, orthophosphate, and suspended sediment. Concentrations measured near peak flow in June 2008 were compared with the corresponding mean concentrations from June 1979 to 2007 using a paired t test. While there was no consistent pattern in concentrations between historical samples and those from the 2008 flood, increased flow during the flood resulted in near-peak June 2008 flood daily loads that were statistically greater (p < 0.05) than the median June 1979 to 2007 daily loads for all constituents. Estimates of loads for the 16-d period during the flood were calculated for four major tributaries and totaled 4.95 x 10(7) kg of nitrogen (N) and 2.9 x 10(6) kg of phosphorus (P) leaving Iowa, which accounted for about 22 and 46% of the total average annual nutrient yield, respectively. This study demonstrates the importance of large flood events to the total annual nutrient load in both small streams and large rivers.

Effect of multi-nutrient insufficiency on markers of one carbon metabolism in young women: response to a methionine load.

PubMed

Katre, P; Joshi, S; Bhat, D S; Deshmukh, M; Gurav, N; Pandit, S; Lubree, H; Marczewski, S; Bennett, C; Gruca, L; Kalyanaraman, K; Naik, S S; Yajnik, C S; Kalhan, S C

2016-06-01

Multi-nutrient insufficiencies as a consequence of nutritional and economic factors are common in India and other developing countries. We have examined the impact of multi-nutrient insufficiency on markers of one carbon (1C) metabolism in the blood, and response to a methionine load in clinically healthy young women. Young women from Pune, India (n=10) and Cleveland, USA (n=13) were studied. Blood samples were obtained in the basal state and following an oral methionine load (50 mg/kg of body weight in orange juice). Plasma concentrations of vitamin B12, folate and B6 were measured in the basal state. The effect of methionine load on the levels of methionine, total homocysteine, cysteine, glutathione and amino acids was examined. Indian women were significantly shorter and lighter compared with the American women and had lower plasma concentration of vitamins B12, folate and B6, essential amino acids and glutathione, but higher concentration of total homocysteine. The homocysteine response to methionine load was higher in Indian women. The plasma concentrations of glycine and serine increased in the Indian women after methionine (in juice) load. A significant negative correlation between plasma B6 and homocysteine (r= -0.70), and plasma folate and glycine and serine levels were observed in the Indian group (P<0.05) but not in the American group. Multi-nutrient insufficiency in the Indian women caused unique changes in markers of whole body protein and 1C metabolism. These data would be useful in developing nutrient intervention strategies.

Estimation of Tile Drainage Contribution to Streamflow and Nutrient Export Loads

NASA Astrophysics Data System (ADS)

Schilling, K. E.; Arenas Amado, A.; Jones, C. S.; Weber, L. J.

2015-12-01

Subsurface drainage is a very common practice in the agricultural U.S. Midwest. It is typically installed in poorly drained soils in order to enhance crop yields. The presence of tile drains creates a route for agrichemicals to travel and therefore negatively impacts stream water quality. This study estimated through end-member analyses the contributions of tile drainage, groundwater, and surface runoff to streamflow at the watershed scale based on continuously monitored data. Especial attention was devoted to quantifying tile drainage impact on watershed streamflow and nutrient export loads. Data analyzed includes streamflow, rainfall, soil moisture, shallow groundwater levels, in-stream nitrate+nitrite concentrations and specific conductance. Data were collected at a HUC12 watershed located in Northeast Iowa, USA. Approximately 60% of the total watershed area is devoted to agricultural activities and forest and grassland are the other two predominant land uses. Results show that approximately 20% of total annual streamflow comes from tile drainage and during rainfall events tile drainage contribution can go up to 30%. Furthermore, for most of the analyzed rainfall events groundwater responded faster and in a more dramatic fashion than tile drainage. The State of Iowa is currently carrying out a plan to reduce nutrients in Iowa waters and the Gulf of Mexico (Iowa Nutrient Reduction Strategy). The outcome of this investigation has the potential to assist in Best Management Practice (BMP) scenario selection and therefore help the state achieve water quality goals.

Effectiveness of SWAT in characterizing the watershed hydrology in the snowy-mountainous Lower Bear Malad River (LBMR) watershed in Box Elder County, Utah

NASA Astrophysics Data System (ADS)

Salha, A. A.; Stevens, D. K.

2015-12-01

Distributed watershed models are essential for quantifying sediment and nutrient loads that originate from point and nonpoint sources. Such models are primary means towards generating pollutant estimates in ungaged watersheds and respond well at watershed scales by capturing the variability in soils, climatic conditions, land uses/covers and management conditions over extended periods of time. This effort evaluates the performance of the Soil and Water Assessment Tool (SWAT) model as a watershed level tool to investigate, manage, and characterize the transport and fate of nutrients in Lower Bear Malad River (LBMR) watershed (Subbasin HUC 16010204) in Utah. Water quality concerns have been documented and are primarily attributed to high phosphorus and total suspended sediment concentrations caused by agricultural and farming practices along with identified point sources (WWTPs). Input data such as Digital Elevation Model (DEM), land use/Land cover (LULC), soils, and climate data for 10 years (2000-2010) is utilized to quantify the LBMR streamflow. Such modeling is useful in developing the required water quality regulations such as Total Maximum Daily Loads (TMDL). Measured concentrations of nutrients were closely captured by simulated monthly nutrient concentrations based on the R2 and Nash- Sutcliffe fitness criteria. The model is expected to be able to identify contaminant non-point sources, identify areas of high pollution risk, locate optimal monitoring sites, and evaluate best management practices to cost-effectively reduce pollution and improve water quality as required by the LBMR watershed's TMDL.

Effects of nutrient enrichment derived from fish farming activities on macroinvertebrate assemblages in a subtropical region of Hong Kong.

PubMed

Gao, Qin-Feng; Cheung, Kwok-Leung; Cheung, Siu-Gin; Shin, Paul K S

2005-01-01

To study the correlation between nutrient enrichment derived from fish farming activities and changes in macrobenthic assemblages, a one-year field study was conducted in Kau Sai Bay marine fish culture zone of Hong Kong. Bimonthly sediment samples were collected at six stations: two at the fish cages, two near the boundary of the fish culture area, and two reference sites further away from the culture area. Sediment physico-chemical characteristics in terms of silt/clay fraction, moisture content, total organic carbon (TOC), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were analyzed. The macrobenthos (>0.5 mm) present in the sediment were sorted, identified and enumerated. On average, TOC, TKN and TP levels at the fish cage stations were 82.8%, 128.5% and 1315.7% higher than those at the reference stations, respectively. As a result, the N:P molar ratio was greatly reduced from 8.75 at the reference stations to 1.83 at the fish cage stations. Univariate and multivariate analyses revealed that diversity of macrofauna was significantly reduced and community structure differed at the fish cage stations relative to the reference sites. The intermediary stations near the fish culture area showed a transitional state of disturbance. Faunal diversity was negatively correlated with nutrient level, reflecting the adverse impacts of nutrient enrichment derived from fish farming activities on the benthic assemblages. Whilst in subtropical Asia-Pacific trash fish is the major feed for fish culture resulting in a higher nutrient loading and nutrient ratio accumulated in the sediment beneath the fish rafts, the effects of nutrient enrichment on macrobenthic assemblages are comparable to that in temperate waters owing to relatively high sediment metabolism rate and smaller fish culture scale in Hong Kong.

Factors controlling stream water nitrate and phosphor loads during precipitation events

NASA Astrophysics Data System (ADS)

Rozemeijer, J. C.; van der Velde, Y.; van Geer, F. G.; de Rooij, G. H.; Broers, H. P.; Bierkens, M. F. P.

2009-04-01

Pollution of surface waters in densely populated areas with intensive land use is a serious threat to their ecological, industrial and recreational utilization. European and national manure policies and several regional and local pilot projects aim at reducing pollution loads to surface waters. For the evaluation of measures, water authorities and environmental research institutes are putting a lot of effort into monitoring surface water quality. Fro regional surface water quality monitoring, the measurement locations are usually situated in the downstream part of the catchment to represent a larger area. The monitoring frequency is usually low (e.g. monthly), due to the high costs for sampling and analysis. As a consequence, human induced trends in nutrient loads and concentrations in these monitoring data are often concealed by the large variability of surface water quality caused by meteorological variations. Because natural surface water quality variability is poorly understood, large uncertainties occur in the estimates of (trends in) nutrient loads or average concentrations. This study aims at uncertainty reduction in the estimates of mean concentrations and loads of N and P from regional monitoring data. For this purpose, we related continuous N and P records of stream water to variations in precipitation, discharge, groundwater level and tube drain discharge. A specially designed multi scale experimental setup was installed in an agricultural lowland catchment in The Netherlands. At the catchment outlet, continuous measurements of water quality and discharge were performed from July 2007-January 2009. At an experimental field within the catchment continuous measurements of precipitation, groundwater levels and tube drain discharges were collected. 20 significant rainfall events with a variety of antecedent conditions, durations and intensities were selected for analysis. Singular and multiple regression analysis was used to identify relations between the continuous N and P records and characteristics of the dynamics of discharge, precipitation, groundwater level and tube drain discharge. From this study, we conclude that generally available and easy to measure explanatory data (such as continuous records of discharge, precipitation and groundwater level) can reduce uncertainty in estimations of N and P loads and mean concentrations. However, for capturing the observed short load pulses of P, continuous or discharge proportional sampling is needed.

Factors affecting stream nutrient loads: A synthesis of regional SPARROW model results for the continental United States

USGS Publications Warehouse

Preston, Stephen D.; Alexander, Richard B.; Schwarz, Gregory E.; Crawford, Charles G.

2011-01-01

We compared the results of 12 recently calibrated regional SPARROW (SPAtially Referenced Regressions On Watershed attributes) models covering most of the continental United States to evaluate the consistency and regional differences in factors affecting stream nutrient loads. The models - 6 for total nitrogen and 6 for total phosphorus - all provide similar levels of prediction accuracy, but those for major river basins in the eastern half of the country were somewhat more accurate. The models simulate long-term mean annual stream nutrient loads as a function of a wide range of known sources and climatic (precipitation, temperature), landscape (e.g., soils, geology), and aquatic factors affecting nutrient fate and transport. The results confirm the dominant effects of urban and agricultural sources on stream nutrient loads nationally and regionally, but reveal considerable spatial variability in the specific types of sources that control water quality. These include regional differences in the relative importance of different types of urban (municipal and industrial point vs. diffuse urban runoff) and agriculture (crop cultivation vs. animal waste) sources, as well as the effects of atmospheric deposition, mining, and background (e.g., soil phosphorus) sources on stream nutrients. Overall, we found that the SPARROW model results provide a consistent set of information for identifying the major sources and environmental factors affecting nutrient fate and transport in United States watersheds at regional and subregional scales. ?? 2011 American Water Resources Association. This article is a U.S. Government work and is in the public domain in the USA.

Nutrient-based ecological consideration of a temporary river catchment affected by a reservoir operation to facilitate efficient management.

PubMed

Tzoraki, Ourania A; Dörflinger, Gerald; Kathijotes, Nicholas; Kontou, Artemis

2014-01-01

The water quality status of the Kouris river in Cyprus was examined in order to fulfil the requirements for ecological quality as defined by the Water Framework Directive-2000/60/EC. Nitrate concentration (mean value) was increased in the Limnatis (2.8 mg L(-1)) tributary in comparison with the Kryos (2.1 mg L(-1)) and Kouris (1.0 mg L(-1)) tributaries depicting the influence of anthropogenic activities. The total maximum daily nutrients loads (TMDLs) based on the flow duration curves approach, showed that nutrients loads exceeded threshold values (33.3-75.6% in all hydrologic condition classes in the Kouris tributary, and 65-78% in the Limnatis tributary) especially under low flow conditions. The TMDL graph is intended to guide the temporal schedule for chemical sampling in all hydrologic classes. Kouris reservoir is an oligotrophic system, strongly influenced by the river's flash-flood character but also by the implemented management practices. Kouris river outflow, which was reduced to one-tenth in the post dam period altered the wetland hydrologic network and contributed to the decrease of aquifer thickness. Continuous evaluation and update of the River Basin Management Plans will be the basis for the sustainable development of the Kouris basin.

Impact assessment of projected climate change on diffuse phosphorous loss in Xin'anjiang catchment, China.

PubMed

Zhai, Xiaoyan; Zhang, Yongyong

2018-02-01

Diffuse nutrient loss is a serious threat to water security and has severely deteriorated water quality throughout the world. Xin'anjiang catchment, as a main drinking water source for Hangzhou City, has been a national concern for water environment protection with payment for watershed services construction. Detection of diffuse phosphorous (DP) pollution dynamics under climate change is significant for sustainable water quality management. In this study, the impact of projected climate change on DP load was analyzed using SWAT to simulate the future changes of diffuse components (carriers: water discharge and sediment; nutrient: DP) at both station and sub-catchment scales under three climate change scenarios (RCP2.6, RCP4.5, and RCP8.5). Results showed that wetting and warming years were expected with increasing tendencies of both precipitation and temperature in the two future periods (2020s: 2021~2030, 2030s: 2031~2040) except in the 2020s in the RCP2.6 scenario, and the annual average increasing ratios of precipitation and temperature reached - 1.79~3.79% and 0.48~1.27 °C, respectively, comparing with those in the baseline (2000s: 2001~2010). Climate change evidently altered annual and monthly average water discharge and sediment load, while it has a remarkable impact on the timing and monthly value of DP load at station scale. DP load tended to increase in the non-flood season at Yuliang due to strengthened nutrient flushing from rice land into rivers with increasing precipitation and enhanced phosphorous cycle in soil layers with increasing temperature, while it tended to decrease in the flood season at Yuliang and in most months at Tunxi due to restricted phosphorous reaction with reduced dissolved oxygen content and enhanced dilution effect. Spatial variability existed in the changes of sediment load and DP load at sub-catchment scale due to climate change. DP load tended to decrease in most sub-catchments and was the most remarkable in the RCP8.5 scenario (2020s, - 9.00~2.63%; 2030s, - 11.16~7.89%), followed by RCP2.6 (2020s, - 10.00~2.90%; 2030s, - 9.00~6.63%) and RCP4.5 (2020s, - 6.81~5.49%, 2030s, - 10.00~9.09%) scenarios. Decreasing of DP load mainly aggregated in the western and eastern mountainous regions, while it tended to increase in the northern and middle regions. This study was expected to provide insights into diffuse nutrient loss control and management in Xin'anjiang catchment, and scientific references for the implementation of water environmental protection in China.

Estimates of Nutrient Loading by Ground-Water Discharge into the Lynch Cove Area of Hood Canal, Washington

USGS Publications Warehouse

Simonds, F. William; Swarzenski, Peter W.; Rosenberry, Donald O.; Reich, Christopher D.; Paulson, Anthony J.

2008-01-01

Low dissolved oxygen concentrations in the waters of Hood Canal threaten marine life in late summer and early autumn. Oxygen depletion in the deep layers and landward reaches of the canal is caused by decomposition of excess phytoplankton biomass, which feeds on nutrients (primarily nitrogen compounds) that enter the canal from various sources, along with stratification of the water column that prevents mixing and replenishment of oxygen. Although seawater entering the canal is the largest source of nitrogen, ground-water discharge to the canal also contributes significant quantities, particularly during summer months when phytoplankton growth is most sensitive to nutrient availability. Quantifying ground-water derived nutrient loads entering an ecologically sensitive system such as Hood Canal is a critical component of constraining the total nutrient budget and ultimately implementing effective management strategies to reduce impacts of eutrophication. The amount of nutrients entering Hood Canal from ground water was estimated using traditional and indirect measurements of ground-water discharge, and analysis of nutrient concentrations. Ground-water discharge to Hood Canal is variable in space and time because of local geology, variable hydraulic gradients in the ground-water system adjacent to the shoreline, and a large tidal range of 3 to 5 meters. Intensive studies of ground-water seepage and hydraulic-head gradients in the shallow, nearshore areas were used to quantify the freshwater component of submarine ground-water discharge (SGD), whereas indirect methods using radon and radium geochemical tracers helped quantify total SGD and recirculated seawater. In areas with confirmed ground-water discharge, shore-perpendicular electrical resistivity profiles, continuous electromagnetic seepage-meter measurements, and continuous radon measurements were used to visualize temporal variations in ground-water discharge over several tidal cycles. The results of these field investigations show that ground-water discharge into the Lynch Cove area of Hood Canal is highly dynamic and strongly affected by the large tidal range. In areas with a steep shoreline and steep hydraulic gradient, ground-water discharge is spatially concentrated in or near the intertidal zone, with increased discharge during low tide. Topographically flat areas with weak hydraulic gradients had more spatial variability, including larger areas of seawater recirculation and more widely dispersed discharge. Measured total-dissolved-nitrogen concentrations in ground water ranged from below detection limits to 2.29 milligrams per liter and the total load entering Lynch Cove was estimated to be approximately 98 ? 10.3 metric tons per year (MT/yr). This estimate is based on net freshwater seepage rates from Lee-type seepage meter measurements and can be compared to estimates derived from geochemical tracer mass balance estimates (radon and radium) of 231 to 749 MT/yr, and previous water-mass-balance estimates (14 to 47 MT/ yr). Uncertainty in these loading estimates is introduced by complex biogeochemical cycles of relevant nutrient species, the representativeness of measurement sites, and by energetic dynamics at the coastal aquifer-seawater interface caused by tidal forcing.

Discharge, water-quality characteristics, and nutrient loads from McKay Bay, Delaney Creek, and East Bay, Tampa, Florida, 1991-1993

USGS Publications Warehouse

Stoker, Y.E.; Levesque, V.A.; Fritz, E.M.

1996-01-01

Nutrient enrichment in Tampa Bay has caused a decline in water quality in the estuary. Efforts to reduce the nutrient loading to Tampa Bay have resulted in improvement in water quality from 1981 to 1991. However, Tampa Bay still is onsidered enriched with nutrients. Water quality in East Bay (located at the northeastern part of Hillsborough Bay, which is an embayment in Tampa Bay) is not improving at the same rate as the rest of the bay. East Bay is the center of shipping activity in Tampa Bay and the seventh largest port in the United States. One of the primary cargoes is phosphate ore and related products such as fertilizer. The potential for nutrient loading to East Bay from shipping activities is high and has not previously been measured. Nitrogen and phosphorus loads from East Bay to Hillsborough Bay were measured during selected time periods during June 1992 through May 1993; these data were used to estimate seasonal and annual loads. These loads were evaluated to determine whether the loss of fertilizer products from shipping activities resulted in increased nutrient loading to Hillsborough Bay. Discharge was measured, and water-quality samples were collected at the head of East Bay (exiting McKay Bay), and at the mouth of East Bay. Discharge and nitrogen and phosphorus concentrations for the period June 1992 through May 1993 were used to compute loads. Discharges from McKay Bay, Delaney Creek, and East Bay are highly variable because of the effect of tide. Flow patterns during discharge measurements generally were unidirectional in McKay Bay and Delaney Creek, but more complex, bidirectional patterns were observed at the mouth of East Bay. Tidally affected discharge data were digitally filtered with the Godin filter to remove the effects of tide so that residual, or net, discharge could be determined. Daily mean discharge from McKay Bay ranged from -1,900 to 2,420 cubic feet per second; from Delaney Creek, -3.8 to 162 cubic feet per second; and from East Bay, -437 to 3,780 cubic feet per second. Water quality in McKay Bay, Delaney Creek, and East Bay varies vertically, areally, and seasonally. Specific conductance and concentrations of phosphorus and ammonia nitrogen were greater near the bottom than near the surface at the head and mouth of East Bay. Concentrations of total nitrogen and ammonia plus organic nitrogen generally were greater at the head of East Bay than at the mouth, indicating that McKay Bay is the primary source of nitrogen to East Bay. Concentrations of total ammonia nitrogen, nitrite plus nitrate nitrogen, phosphorus, orthophosphorus, and suspended solids and values of turbidity and specific conductance generally were greater at the mouth of East Bay than at the head. The greatest concentrations of nitrogen and phosphorus were measured in Delaney Creek. In East Bay and McKay Bay, the greatest concentrations of nitrogen, phosphorus, and ammonia plus organic nitrogen occurred in summer, whereas turbidity, specific conductance, and concentrations of suspended solids were greater in winter. The greatest daily mean loads from McKay Bay and East Bay occurred in late June 1992 and April and May 1993 and coincided with periods of daily mean discharge greater than about 2,000 cubic feet per second. Although concentrations of nitrogen and phosphorus were greater in Delaney Creek than in McKay Bay and East Bay, loads were minimal because of minimal discharges from Delaney Creek. Monthly loads of total nitrogen ranged from about 20 tons to about 83 tons at McKay Bay; from about 1 ton to 4.2 tons at Delaney Creek; and from about 17 tons to 76 tons at the mouth of East Bay. Monthly loads of phosphorus ranged from about 11 tons to about 45 tons at McKay Bay; from about 0.62 ton to 2.6 tons at Delaney Creek; and from about 10 tons to about 45 tons at the mouth of East Bay. The results of this study indicate that nitrogen and phosphorus loads from the basin draining directly to East Bay (excluding loads from the McKa

FOOD WEB AND COMMUNITY COMPOSITION CHANGES IN RESPONSE TO NUTRIENT LOADING IN FRESHWATER AND MARINE COASTAL SYSTEMS (ESTUARIES AND COASTAL WETLANDS)

EPA Science Inventory

Our research will investigate the mechanisms by which increased loading of nutrients to coastal waters alters the structure and dynamics of food webs, resulting in declines in populations of ecologically and commercially important organisms. Research across NHEERL Divisions will...

Monitoring water quality in Northwest Atlantic coastal waters using dinoflagellate cysts

EPA Science Inventory

Nutrient pollution is a major environmental problem in many coastal waters around the US. Determining the total input of nutrients to estuaries is a challenge. One method to evaluate nutrient input is through nutrient loading models. Another method relies upon using indicators as...

DEVELOPMENT OF A METHOD FOR DETERMINING PHOSPHORUS NUTRIENT CRITERIA IN STREAMS AND RIVERS OF THE MID-ATLANTIC REGION

EPA Science Inventory

Nutrient enrichment of phosphorus and nitrogen is the second most cited cause for impairment of streams and rivers in the U.S. There is a need to develop stream nutrient criteria to control nutrient loadings. Since biotic metrics can assess the overall impact of nutrient enrichm...

Changes in distributional patterns of plaice Pleuronectes platessa in the central and eastern North Sea; do declining nutrient loadings play a role?

NASA Astrophysics Data System (ADS)

Støttrup, Josianne G.; Munk, Peter; Kodama, Masashi; Stedmon, Colin

2017-09-01

Since the beginning of the 1990s, there has been a change in the relative distribution of smaller age-classes of plaice Pleuronectes platessa (age 1-3) in the North Sea. The abundances have increased in deeper, more offshore areas, while coastal abundances have been stagnant or declining. For the same time period available time series data on nutrient conditions in the coastal North Sea area show that the freshwater nitrogen loading has decreased by about 50%. While nutrient concentrations in the ambient environment have been shown to influence growth in juvenile plaice through influence on their prey, we here inspect the potential linkage between distributional changes in plaice and the decline in nutrient loading. We compare plaice observations in coastal areas in the eastern North Sea, which have experienced large changes in eutrophication, with observations for the Dogger Bank, a large sandbank in a shallow offshore area of the North Sea. The Dogger Bank, was used as a reference location assuming this area has been less influenced from coastal eutrophication but similar regional climate conditions, and here we found no changes in the abundances of juvenile plaice. The increase in the use of offshore habitats as nursery areas by juvenile plaice in the North Sea appears not related to water depth per se but driven by specific processes dominating in near-shore areas and may be related to changes in nutrient loadings. This point to the importance of separating more general depth-related factors from conditions specific for near-shore areas, such as nutrient loadings in coastal waters and export offshore. The concurrent changes in environment and in distribution of juvenile plaice may have implications for environmental and fisheries management.

Sources of nitrogen and phosphorus emissions to Irish rivers and coastal waters: Estimates from a nutrient load apportionment framework.

PubMed

Mockler, Eva M; Deakin, Jenny; Archbold, Marie; Gill, Laurence; Daly, Donal; Bruen, Michael

2017-12-01

More than half of surface water bodies in Europe are at less than good ecological status according to Water Framework Directive assessments, and diffuse pollution from agriculture remains a major, but not the only, cause of this poor performance. Agri-environmental policy and land management practices have, in many areas, reduced nutrient emissions to water. However, additional measures may be required in Ireland to further decouple the relationship between agricultural productivity and emissions to water, which is of vital importance given on-going agricultural intensification. The Source Load Apportionment Model (SLAM) framework characterises sources of phosphorus (P) and nitrogen (N) emissions to water at a range of scales from sub-catchment to national. The SLAM synthesises land use and physical characteristics to predict emissions from point (wastewater, industry discharges and septic tank systems) and diffuse sources (agriculture, forestry, etc.). The predicted annual nutrient emissions were assessed against monitoring data for 16 major river catchments covering 50% of the area of Ireland. At national scale, results indicate that total average annual emissions to surface water in Ireland are over 2700tyr -1 of P and 82,000tyr -1 of N. The proportional contributions from individual sources show that the main sources of P are from municipal wastewater treatment plants and agriculture, with wide variations across the country related to local anthropogenic pressures and the hydrogeological setting. Agriculture is the main source of N emissions to water across all regions of Ireland. These policy-relevant results synthesised large amounts of information in order to identify the dominant sources of nutrients at regional and local scales, contributing to the national nutrient risk assessment of Irish water bodies. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.

Puget Sound Dissolved Oxygen Modeling Study: Development of an Intermediate Scale Water Quality Model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khangaonkar, Tarang; Sackmann, Brandon S.; Long, Wen

2012-10-01

The Salish Sea, including Puget Sound, is a large estuarine system bounded by over seven thousand miles of complex shorelines, consists of several subbasins and many large inlets with distinct properties of their own. Pacific Ocean water enters Puget Sound through the Strait of Juan de Fuca at depth over the Admiralty Inlet sill. Ocean water mixed with freshwater discharges from runoff, rivers, and wastewater outfalls exits Puget Sound through the brackish surface outflow layer. Nutrient pollution is considered one of the largest threats to Puget Sound. There is considerable interest in understanding the effect of nutrient loads on themore » water quality and ecological health of Puget Sound in particular and the Salish Sea as a whole. The Washington State Department of Ecology (Ecology) contracted with Pacific Northwest National Laboratory (PNNL) to develop a coupled hydrodynamic and water quality model. The water quality model simulates algae growth, dissolved oxygen, (DO) and nutrient dynamics in Puget Sound to inform potential Puget Sound-wide nutrient management strategies. Specifically, the project is expected to help determine 1) if current and potential future nitrogen loadings from point and non-point sources are significantly impairing water quality at a large scale and 2) what level of nutrient reductions are necessary to reduce or control human impacts to DO levels in the sensitive areas. The project did not include any additional data collection but instead relied on currently available information. This report describes model development effort conducted during the period 2009 to 2012 under a U.S. Environmental Protection Agency (EPA) cooperative agreement with PNNL, Ecology, and the University of Washington awarded under the National Estuary Program« less

Prairie and turf buffer strips for controlling runoff from paved surfaces.

PubMed

Steinke, K; Stier, J C; Kussow, W R; Thompson, A

2007-01-01

Eutrophication of surface waters due to nonpoint source pollution from urban environments has raised awareness of the need to decrease runoff from roads and other impervious surfaces. These concerns have led to precautionary P application restrictions on turf and requirements for vegetative buffer strips. The impacts of two plant communities and three impervious/pervious surface ratios were assessed on runoff water quality and quantity. A mixed forb/grass prairie and a Kentucky bluegrass (Poa pratensis L.) blend were seeded and runoff was monitored and analyzed for total volume, total P, soluble P, soluble organic P, bioavailable P, total suspended solids, and total organic suspended solids. Mean annual runoff volumes, all types of mean annual P nutrient losses, and sediment loads were not significantly affected by treatments because over 80% of runoff occurred during frozen soil conditions. Total P losses from prairie and turf were similar, averaging 1.96 and 2.12 kg ha(-1) yr(-1), respectively. Vegetation appeared to be a likely contributor of nutrients, particularly from prairie during winter dormancy. When runoff occurred during non-frozen soil conditions turf allowed significantly (P < or = 0.10) lower runoff volumes compared with prairie vegetation and the 1:2 and 1:4 impervious/pervious surface ratios had less runoff than the 1:1 ratio (P < or = 0.05). In climates where the majority of runoff occurs during frozen ground conditions, vegetative buffers strips alone are unlikely to dramatically reduce runoff and nutrient loading into surface waters. Regardless of vegetation type or size, natural nutrient biogeochemical cycling will cause nutrient loss in surface runoff waters, and these values may represent baseline thresholds below which values cannot be obtained.

Gastric volume rather than nutrient content inhibits food intake.

PubMed

Phillips, R J; Powley, T L

1996-09-01

To evaluate the separate contributions of distension and nutrient stimulation of the stomach to the inhibition of short-term food intake and, particularly, to reassess previous analyses based on the inflatable gastrointestinal cuff, four experiments were performed. Rats equipped with pyloric cuffs and indwelling gastric catheters consumed a liquid diet ad libitum. Their consumption during short-term (30 min) feeding bout was measured after gastric infusions on cuff-open and cuff-closed trials. Animals taking meals (approximately 5 ml) with cuffs closed immediately after receiving intragastric infusions of 2.5, 5, 7.5, or 10 ml of normal saline exhibited both suppression at the smallest infusion and a dose-dependent reduction across the other volumes (experiment 1). Additionally, when the test diet concentration was varied, animals with their cuffs closed consumed a constant volume, not a constant number of calories (experiment 2). Furthermore, cuff-closed animals exhibited no more suppression to 5-ml intragastric infusions of nutrients (including, on different trials, 50 and 100% Isocal diet; 10, 20, and 40% glucose; and 40% sucrose and 40% fructose) than to the same volume of saline (experiments 3 and 4). In contrast, on cuff-open trials in which gastric contents could empty into the duodenum, these same nutrient loads were more effective (except fructose) than saline in producing suppression of food intake. In summary, although both limited gastric distension with the pylorus occluded and intestinal nutrient stimulation with the cuff open effectively reduced intake, cuff-closed gastric loads of mixed macronutrients or carbohydrate solutions of 2-8 kcal, pH from 5.8 to 6.7, and osmolarities between 117 and 2,294 mosM/kg produced only the distension-based suppression generated by the same volume of saline.

Pile burning effects on soil water repellency, infiltration, and downslope water chemistry in the Lake Tahoe Basin, USA

Treesearch

Ken Hubbert; Matt Busse; Steven Overby; Carol Shestak; Ross Gerrard

2015-01-01

Thinning of conifers followed by pile burning has become a popular treatment to reduce fuel loads in the Lake Tahoe Basin. However, concern has been voiced about burning within or near riparian areas because of the potential effect on nutrient release and, ultimately, lake water quality. Our objective was to quantify the effects of pile burning on soil physical and...

Nutrient loads within the Sava River Catchment and comparison with load relations in the Baltic region

NASA Astrophysics Data System (ADS)

Levi, Lea; Cvetkovic, Vladimir; Destouni, Georgia

2015-04-01

This study compiles estimates of total nitrogen and phosphorus loads in the Sava River Catchment (SRC), investigates the load relations to human drivers of excess nutrient loading, and compares them with corresponding relations implied by data reported for the Baltic region. Nutrient load data, associated average discharge concentrations (ratio of load to water discharge) and their relations to human drivers are investigated across subcatchments of the SRC with different agricultural and population conditions. The Zagreb subcatchment, which has the smallest area but the highest population density and runoff among the investigated SRC subcatchments, exhibits the highest loads of both nitrogen and phosphorus. Overall for the SRC, results show high correlation (R2=0.93-0.95) of nutrient loads with population density and of concentrations with farmland share. A further question investigated here is then to what degree these relations are comparable with such relations found also for the Baltic region. The two regions are otherwise quite different in their climatic, agricultural and wastewater treatment conditions, so relation consistency, even if surprising, would be important in indicating some degree of relation transferability worthy of further investigation also in other regions. For the Baltic region corresponding correlations to those found in the SRC are in the range R2=0.79-0.88. In particular nitrogen and phosphorus concentration correlations with farmland share are qualitatively consistent between the regions. At the same time, phosphorus concentration correlation with population density shows quite different results between regions. Obtained results indicate a certain level of transferability of dependencies between the two regions and call for further detailed investigations on finer spatial-temporal scales.

Scenario analysis of the impacts of socioeconomic development on phosphorous export and loading from the Dongting Lake watershed, China.

PubMed

Hou, Ying; Chen, Weiping; Liao, Yuehua; Luo, Yueping

2017-12-01

Socioeconomic development in lake watersheds is closely related with lake nutrient pollution. As the second largest freshwater lake in China, the Dongting Lake has been experiencing an increase in nutrient loading and a growing risk of eutrophication. This study aimed to reveal the likely impacts of the socioeconomic development of the Dongting Lake watershed on the phosphorous pollution in the lake. We estimated the contributions from different sources and sub-watersheds to the total phosphorous (TP) export and loading from the Dongting Lake watershed under two most likely socioeconomic development scenarios. Moreover, we predicted the likely permissible and actual TP loadings to the Dongting Lake. Under both two scenarios, three secondary sub-watersheds-the upper and lower reaches of the Xiang River watershed and the Dongting Lake Area-are expected to dominate the contribution to the TP export from the Dongting Lake watershed in 2020. Three primary sub-watersheds-the Dongting Lake Area, the Xiang River, and the Yuan River watersheds-are predicted to be the major contributors to the TP loading from the entire watershed. The two scenarios are expected to have a slight difference in TP export and lake TP loading. Livestock husbandry is expected to be the predominant anthropogenic TP source in each of the sub-watersheds under both scenarios. Compared to 2010, permissible TP loading is not expected to increase but actual TP loading is predicted to grow significantly in 2020. Our study provides methodologies to identify the key sources and regions of lake nutrient loading from watersheds with complex socioeconomic context, and to reveal the potential influences of socioeconomic development on nutrient pollution in lake watersheds.

Eutrophication study at the Panjiakou-Daheiting Reservoir system, northern Hebei Province, People's Republic of China: Chlorophyll-a model and sources of phosphorus and nitrogen

USGS Publications Warehouse

Domagalski, Joseph L.; Lin, Chao; Luo, Yang; Kang, Jie; Wang, Shaoming; Brown, Larry R.; Munn, Mark D.

2007-01-01

Concentrations, loads, and sources of nitrate and total phosphorus were investigated at the Panjiakou and Daheiting Reservoir system in northern Hebei Province, People's Republic of China. The Luan He River is the primary source of water to these reservoirs, and the upstream watershed has a mix of land uses including agriculture, forest, and one large urban center. The reservoirs have a primary use for storage of drinking water and partially supply Tianjin City with its annual needs. Secondary uses include flood control and aqua culture (fish cages). The response of the reservoir system from phosphorus input, with respect to chlorophyll-a production from algae, was fitted to a model of normalized phosphorus loading that regresses the average summer-time chlorophyll-a concentration to the average annual phosphorus concentration of the reservoir. Comparison of the normalized phosphorus loading and chlorophyll-a response of this system to other reservoirs throughout the world indicate a level of eutrophication that will require up to an approximate 5–10-fold decrease in annual phosphorus load to bring the system to a more acceptable level of algal productivity. Isotopes of nitrogen and oxygen in dissolved nitrate were measured from the headwater streams and at various locations along the major rivers that provide the majority of water to these reservoirs. Those isotopic measurements indicate that the sources of nitrate change from natural background in the rivers to animal manure and septic waste upstream of the reservoir. Although the isotopic measurements suggest that animal and septic wastes are a primary source of nutrients, measurements of the molar ratio of nitrogen to phosphorus are more indicative of row-cropping practices. Options for reduction of nutrient loads include changing the management practices of the aqua culture, installation of new sewage treatment systems in the large urbanized area of the upper watershed, and agricultural management practices that would reduce the loading of nutrients and soil erosion from that land use.

Retrofitting impervious urban infrastructure with green technology for rainfall-runoff restoration, indirect reuse and pollution load reduction.

PubMed

Sansalone, John; Raje, Saurabh; Kertesz, Ruben; Maccarone, Kerrilynn; Seltzer, Karl; Siminari, Michele; Simms, Peter; Wood, Brandon

2013-12-01

The built environs alter hydrology and water resource chemistry. Florida is subject to nutrient criteria and is promulgating "no-net-load-increase" criteria for runoff and constituents (nutrients and particulate matter, PM). With such criteria, green infrastructure, hydrologic restoration, indirect reuse and source control are potential design solutions. The study simulates runoff and constituent load control through urban source area re-design to provide long-term "no-net-load-increases". A long-term continuous simulation of pre- and post-development response for an existing surface parking facility is quantified. Retrofits include a biofiltration area reactor (BAR) for hydrologic and denitrification control. A linear infiltration reactor (LIR) of cementitious permeable pavement (CPP) provides infiltration, adsorption and filtration. Pavement cleaning provided source control. Simulation of climate and source area data indicates re-design achieves "no-net-load-increases" at lower costs compared to standard construction. The retrofit system yields lower cost per nutrient load treated compared to Best Management Practices (BMPs). Copyright © 2013 Elsevier Ltd. All rights reserved.

Variable primary producer responses to nutrient and temperature manipulations in mesocosms: temperature usually trumps nutrient effects

EPA Science Inventory

Mesocosm experiments have been used to evaluate the impacts of nutrient loading on estuarine plant communities in order to develop nutrient response relationships. Mesocosm eutrophication studies tend to focus on long residence time systems. In the Pacific Northwest, many estuari...

The regionalization of national-scale SPARROW models for stream nutrients

USGS Publications Warehouse

Schwarz, Gregory E.; Alexander, Richard B.; Smith, Richard A.; Preston, Stephen D.

2011-01-01

This analysis modifies the parsimonious specification of recently published total nitrogen (TN) and total phosphorus (TP) national-scale SPAtially Referenced Regressions On Watershed attributes models to allow each model coefficient to vary geographically among three major river basins of the conterminous United States. Regionalization of the national models reduces the standard errors in the prediction of TN and TP loads, expressed as a percentage of the predicted load, by about 6 and 7%. We develop and apply a method for combining national-scale and regional-scale information to estimate a hybrid model that imposes cross-region constraints that limit regional variation in model coefficients, effectively reducing the number of free model parameters as compared to a collection of independent regional models. The hybrid TN and TP regional models have improved model fit relative to the respective national models, reducing the standard error in the prediction of loads, expressed as a percentage of load, by about 5 and 4%. Only 19% of the TN hybrid model coefficients and just 2% of the TP hybrid model coefficients show evidence of substantial regional specificity (more than ±100% deviation from the national model estimate). The hybrid models have much greater precision in the estimated coefficients than do the unconstrained regional models, demonstrating the efficacy of pooling information across regions to improve regional models.

Phosphorus and nitrogen concentrations and loads at Illinois River south of Siloam Springs, Arkansas, 1997-1999

USGS Publications Warehouse

Green, W. Reed; Haggard, Brian E.

2001-01-01

Water-quality sampling consisting of every other month (bimonthly) routine sampling and storm event sampling (six storms annually) is used to estimate annual phosphorus and nitrogen loads at Illinois River south of Siloam Springs, Arkansas. Hydrograph separation allowed assessment of base-flow and surfacerunoff nutrient relations and yield. Discharge and nutrient relations indicate that water quality at Illinois River south of Siloam Springs, Arkansas, is affected by both point and nonpoint sources of contamination. Base-flow phosphorus concentrations decreased with increasing base-flow discharge indicating the dilution of phosphorus in water from point sources. Nitrogen concentrations increased with increasing base-flow discharge, indicating a predominant ground-water source. Nitrogen concentrations at higher base-flow discharges often were greater than median concentrations reported for ground water (from wells and springs) in the Springfield Plateau aquifer. Total estimated phosphorus and nitrogen annual loads for calendar year 1997-1999 using the regression techniques presented in this paper (35 samples) were similar to estimated loads derived from integration techniques (1,033 samples). Flow-weighted nutrient concentrations and nutrient yields at the Illinois River site were about 10 to 100 times greater than national averages for undeveloped basins and at North Sylamore Creek and Cossatot River (considered to be undeveloped basins in Arkansas). Total phosphorus and soluble reactive phosphorus were greater than 10 times and total nitrogen and dissolved nitrite plus nitrate were greater than 10 to 100 times the national and regional averages for undeveloped basins. These results demonstrate the utility of a strategy whereby samples are collected every other month and during selected storm events annually, with use of regression models to estimate nutrient loads. Annual loads of phosphorus and nitrogen estimated using regression techniques could provide similar results to estimates using integration techniques, with much less investment.

Temporal and spatial trends in nutrient and sediment loading to Lake Tahoe, California-Nevada, USA

USGS Publications Warehouse

Coats, Robert; Lewis, Jack; Alvarez, Nancy L.; Arneson, Patricia

2016-01-01

Since 1980, the Lake Tahoe Interagency Monitoring Program (LTIMP) has provided stream-discharge and water quality data—nitrogen (N), phosphorus (P), and suspended sediment—at more than 20 stations in Lake Tahoe Basin streams. To characterize the temporal and spatial patterns in nutrient and sediment loading to the lake, and improve the usefulness of the program and the existing database, we have (1) identified and corrected for sources of bias in the water quality database; (2) generated synthetic datasets for sediments and nutrients, and resampled to compare the accuracy and precision of different load calculation models; (3) using the best models, recalculated total annual loads over the period of record; (4) regressed total loads against total annual and annual maximum daily discharge, and tested for time trends in the residuals; (5) compared loads for different forms of N and P; and (6) tested constituent loads against land use-land cover (LULC) variables using multiple regression. The results show (1) N and P loads are dominated by organic N and particulate P; (2) there are significant long-term downward trends in some constituent loads of some streams; and (3) anthropogenic impervious surface is the most important LULC variable influencing water quality in basin streams. Many of our recommendations for changes in water quality monitoring and load calculation methods have been adopted by the LTIMP.

Nitrogen and phosphorus effluent loads from a paddy-field district adopting collective crop rotation.

PubMed

Hama, T; Aoki, T; Osuga, K; Sugiyama, S; Iwasaki, D

2012-01-01

Japanese paddy rice systems commonly adopt the rotation of vegetables, wheat and soybeans with paddy rice. Crop rotation may, however, increase the nutrient load in effluent discharged from the district because more fertilizer is applied to the rotation crops than is applied to paddy crops. We investigated a paddy-field district subject to collective crop rotation and quantified the annual nutrient load of effluent from the district in three consecutive years. The total annual exports of nitrogen and phosphorus over the investigation period ranged from 30.3 to 40.6 kg N ha(-1) and 2.62 to 3.13 kg P ha(-1). The results suggest that rotation cropping increases the effluent nutrient load because applied fertilizer is converted to nitrate, and surface runoff is increased due to the absence of shuttering boards at the field outlets.

A screening-level modeling approach to estimate nitrogen loading and standard exceedance risk, with application to the Tippecanoe River watershed, Indiana

EPA Science Inventory

This paper presents a screening-level modeling approach that can be used to rapidly estimate nutrient loading and assess numerical nutrient standard exceedance risk of surface waters leading to potential classification as impaired for designated use. It can also be used to explor...

SIMULATED RESPONSES OF THE GULF OF MEXICO HYPOXIA TO VARIATIONS IN CLIMATE AND ANTHROPOGENIC NUTRIENT LOADING. (R827785E02)

EPA Science Inventory

A mathematical model was used to simulate monthly responses of the Gulf of Mexico hypoxia to variations in climate and anthropogenic nutrient loading over a 45-year period. We examined six hypothetical future scenarios that are based on observed and projected changes in the Mi...

Epiphyte loads on seagrasses and microphytobenthos abundance are not reliable indicators of nutrient availability in oligotrophic coastal ecosystems.

PubMed

Fourqurean, James W; Muth, Meredith F; Boyer, Joseph N

2010-07-01

Despite marked gradients in nutrient availability that control the abundance and species composition of seagrasses in south Florida, and the importance of nutrient availability in controlling abundance and composition of epiphytes on seagrasses in other locations, we did not find that epiphyte load on the dominant seagrass, Thalassia testudinum, or that the relative contribution of algal epiphytes to the epiphyte community, was positively correlated with nutrient availability in the water column or the sediment in oligotrophic seagrass beds. Further, the abundance of microphytobenthos, as indicated by Chlorophyll-a concentration in the sediments, was not directly correlated with concentrations of nutrients in the sediments. Our results suggest that epiphyte and microphytobenthos abundance are not unambiguous indicators of nutrient availability in relatively pristine seagrass environments, and therefore would make poor candidates for indicators of the status and trends of seagrass ecosystems in relatively low-nutrient environments like the Florida Keys. Copyright 2010 Elsevier Ltd. All rights reserved.

Sediments influence accumulation of two macroalgal species through novel but differing interactions with nutrients and herbivory

NASA Astrophysics Data System (ADS)

Clausing, Rachel J.; Bittick, Sarah Joy; Fong, Caitlin R.; Fong, Peggy

2016-12-01

Despite increasing concern that sediment loads from disturbed watersheds facilitate algal dominance on tropical reefs, little is known of how sediments interact with two primary drivers of algal communities, nutrients and herbivory. We examined the effects of sediment loads on the thalli of two increasingly abundant genera of macroalgae, Galaxaura and Padina, in a bay subject to terrestrial sediment influx in Mo'orea, French Polynesia. Field experiments examining (1) overall effects of ambient sediments and (2) interacting effects of sediments (ambient/removal) and herbivores (caged/uncaged) demonstrated that sediments had strong but opposite effects on both species' biomass accumulation. Sediment removal increased accumulation of Padina boryana Thivy 50% in the initial field experiment but had no effect in the second; rather, in a novel interaction, herbivores overcompensated for increases in tissue nutrient stores that occurred with sediments loads, likely by preferential consumption of nutrient-rich meristematic tissues. Despite negative effects of sediments on biomass, Padina maintained rapid growth across treatments in both experiments. In contrast, positive growth in Galaxaura divaricata Kjellman only occurred with ambient sediment loads. In mesocosm experiments testing interactions of added nutrients and sediments on growth, Galaxaura grew at equivalent rates with sediments (collected from thalli on the reef) as with additions of nitrate and phosphate, suggesting sediments provide a nutrient subsidy. For Padina, however, the only effect was a 50% reduction in growth with sediment. Overall, retention of thallus sediments creates a positive feedback that Galaxaura appears to require to sustain net growth, while Padina merely tolerates sediments. These results indicate that sediments can modify nutrient and herbivore control of algae in ways that differ among species, with the potential for strong and unexpected effects on the abundance and composition of tropical reef macroalgae.

Phosphorus and nitrogen fluxes carried by 21 Finnish agricultural rivers in 1985-2006.

PubMed

Ekholm, Petri; Rankinen, Katri; Rita, Hannu; Räike, Antti; Sjöblom, Heidi; Raateland, Arjen; Vesikko, Ljudmila; Cano Bernal, José Enrique; Taskinen, Antti

2015-04-01

The Finnish Agri-Environmental Programme aims to reduce nutrient load to waters. Using national monitoring data, we estimated the agricultural load (incl. natural background) of total phosphorus (TP) and total nitrogen (TN) transported by 21 Finnish rivers to the northern Baltic Sea and analysed the flow-adjusted trends in the loads and concentrations from 1985 to 2006. We also related the loads to spatial and temporal patterns in catchment and agricultural characteristics. Agricultural load of TN increased, especially in the rivers discharging into the Bothnian Bay, while the load of TP decreased in most of the rivers, except those discharging into the Archipelago Sea. The trends may partly be related to a decrease in grassed area (TP, TN) and increased mineralisation (TN), but the available data on catchment and agricultural characteristics did not fully explain the observed pattern. Our study showed that data arising from relatively infrequent monitoring may prove useful for analysing long-term trend. The mutual correlation among the explaining variables hampered the analysis of the load generating factors.

What does atmospheric nitrogen contribute to the Gulf of Mexico area of oxygen depletion?

NASA Astrophysics Data System (ADS)

Rabalais, N. N.

2017-12-01

The northern Gulf of Mexico influenced by the freshwater discharge and nutrient loads of the Mississippi River watershed is the location of the world's second largest human-caused area of coastal hypoxia. Over 500 more anthropogenic `dead zones' exist in coastal waters. The point source inputs within the Mississippi River watershed account for about ten per cent of the total nitrogen inputs to the Mississippi River, with the remaining being nonpoint source. Atmospheric nitrogen makes up about sixteen per cent of the nonpoint source input of nitrogen. Most of the NOx is generated within the Ohio River watershed from the burning of fossil fuels. Some remains to be deposited into the same watershed, but the airshed deposits much of the NOx along the U.S. eastern seaboard, including Chesapeake Bay, which also has a hypoxia problem. Most of the volatilized ammonia is produced from fertilizers or manure within the upper Mississippi River watershed, is deposited within a localized airshed, and is not airborne long distances like the NOx. The atmospheric nitrogen input to the coastal waters affected by hypoxia is considered to be minimal. In the last half century, the nitrogen load from the Mississippi River to the Gulf of Mexico has increased 300 percent. During this period, low oxygen bottom-waters have developed in the coastal waters and worsened coincident with the increase in the nitrogen load. The 31-yr average size of the bottom-water hypoxia area in the Gulf of Mexico is 13,800 square kilometers, well over the 5,000 square kilometers goal of the Mississippi River Nutrient/Gulf of Mexico Hypoxia Task Force. Knowing the amounts and sources of excess nutrients to watersheds with adjacent coastal waters experiencing eutrophication and hypoxia is important in the management strategies to reduce those nutrients and improve water quality.

SPARROW models used to understand nutrient sources in the Mississippi/Atchafalaya River Basin

USGS Publications Warehouse

Robertson, Dale M.; Saad, David A.

2013-01-01

Nitrogen (N) and phosphorus (P) loading from the Mississippi/Atchafalaya River Basin (MARB) has been linked to hypoxia in the Gulf of Mexico. To describe where and from what sources those loads originate, SPAtially Referenced Regression On Watershed attributes (SPARROW) models were constructed for the MARB using geospatial datasets for 2002, including inputs from wastewater treatment plants (WWTPs), and calibration sites throughout the MARB. Previous studies found that highest N and P yields were from the north-central part of the MARB (Corn Belt). Based on the MARB SPARROW models, highest N yields were still from the Corn Belt but centered over Iowa and Indiana, and highest P yields were widely distributed throughout the center of the MARB. Similar to that found in other studies, agricultural inputs were found to be the largest N and P sources throughout most of the MARB: farm fertilizers were the largest N source, whereas farm fertilizers, manure, and urban inputs were dominant P sources. The MARB models enable individual N and P sources to be defined at scales ranging from SPARROW catchments (∼50 km2) to the entire area of the MARB. Inputs of P from WWTPs and urban areas were more important than found in most other studies. Information from this study will help to reduce nutrient loading from the MARB by providing managers with a description of where each of the sources of N and P are most important, thus providing a basis for prioritizing management actions and ultimately reducing the extent of Gulf hypoxia.

Scientific Guidance for Rehabilitation of the Chesapeake Bay Ecosystem under the Changing Climate.

NASA Astrophysics Data System (ADS)

Boesch, D. F.; Johnson, Z. P.; Li, M.

2017-12-01

While the Chesapeake Bay is an estuary and not a marginal sea on the scale of the Baltic Sea or the Gulf of Mexico, it has a complex set of environmental issues and multiple political jurisdictions such that it can serve as a test bed for science-informed management in larger marine systems. In particular, the Chesapeake Bay possesses a relatively advanced effort to ameliorate eutrophication, reduce toxic stresses, rehabilitate critical habitats, and sustainably utilized resources. Furthermore, both scientists and managers are addressing these challenges while now beginning to incorporate the effects of changes in temperature, precipitation and runoff, sea level, ocean boundary conditions, and pH. Increases in temperature and sea level are already apparent and future conditions can be estimated from global model projections, although sea level and ocean exchanges are also affected by variations in Gulf Stream flows and mesoscale climate. Changes in the volume, seasonality and variability in freshwater delivery from the multiple rivers discharging to the bay are harder to project with confidence, but may have pervasive consequences for circulation, reducing nutrient loads to ameliorate eutrophication, biogeochemical processes, and biotic distributions and dynamics. Science is now challenged to inform multiple adaptation strategies, including minimizing the vulnerability of humans and infrastructure, sustaining important tidal wetlands, managing sediment resources, sustaining living resources, redefining achievable ecosystem rehabilitation goals, and achieving shifting goals for nutrient load reductions. At the same time, science will also have to identify effective means to meet these challenges while also reducing greenhouse gas emissions.

Agronomic benefits of biochar as a soil amendment after its use as waste water filtration medium.

PubMed

Werner, Steffen; Kätzl, Korbinian; Wichern, Marc; Buerkert, Andreas; Steiner, Christoph; Marschner, Bernd

2018-02-01

In many water-scarce countries, waste water is used for irrigation which poses a health risk to farmers and consumers. At the same time, it delivers nutrients to the farming systems. In this study, we tested the hypotheses that biochar can be used as a filter medium for waste water treatment to reduce pathogen loads. At the same time, the biochar is becoming enriched with nutrients and therefore can act as a fertilizer for soil amendment. We used biochar as a filter medium for the filtration of raw waste water and compared the agronomic effects of this "filterchar" (FC) and the untreated biochar (BC) in a greenhouse pot trial on spring wheat biomass production on an acidic sandy soil from Niger. The biochar filter showed the same removal of pathogens as a common sand filter (1.4 log units on average). We did not observe a nutrient accumulation in FC compared to untreated BC. Instead, P, Mg and K were reduced during filtration while N content remained unchanged. Nevertheless, higher biomass (Triticum L. Spp.) production in BC (+72%) and FC (+37%) treatments (20 t ha -1 ), compared with the unamended control, were found. There were no significant differences in aboveground biomass production between BC and FC. Soil available P content was increased by BC (+106%) and FC (+52%) application. Besides, mineral nitrogen content was reduced in BC treated soil and to a lesser extent when FC was used. This may be explained by reduced sorption affinity for mineral nitrogen compounds on FC surfaces. Although the nutrients provided by FC decreased, due to leaching in the filter, it still yielded higher biomass than the unamended control. Copyright © 2017 Elsevier Ltd. All rights reserved.

Nutrients in the Great Lakes. Teacher's Guide and Student Workbook.

ERIC Educational Resources Information Center

Brothers, Chris; And Others

This teacher guide and student workbook set presents two learning activities, designed for fifth through ninth grade students, that concentrate on nutrients in the Great Lakes. In activity A, students simulate aquatic habitats using lake water and goldfish in glass jars and observe the effects of nutrient loading and nutrient limitation on aquatic…

How phosphorus limitation can control climatic gas sources and sinks

NASA Astrophysics Data System (ADS)

Gypens, Nathalie; Borges, Alberto V.; Ghyoot, Caroline

2017-04-01

Since the 1950's, anthropogenic activities severely increased river nutrient loads in European coastal areas. Subsequent implementation of nutrient reduction policies have considerably reduced phosphorus (P) loads from mid-1980's, while nitrogen (N) loads were maintained, inducing a P limitation of phytoplankton growth in many eutrophied coastal areas such as the Southern Bight of the North Sea (SBNS). When dissolved inorganic phosphorous (DIP) is limiting, most phytoplankton organisms are able to indirectly acquire P from dissolved organic P (DOP). We investigate the impact of DOP use on the importance of phytoplankton production and atmospheric fluxes of CO2 and dimethylsulfide (DMS) in the SBNS from 1951 to 2007 using an extended version of the R-MIRO-BIOGAS model. This model includes a description of the ability of phytoplankton organisms to use DOP as a source of P. Results show that primary production can increase up to 70% due to DOP uptake in limiting DIP conditions. Consequently, simulated DMS emissions double while CO2 emissions to the atmosphere decrease, relative to the reference simulation without DOP uptake. At the end of the simulated period (late 2000's), the net direction of air-sea CO2 annual flux, changed from a source to a sink for atmospheric CO2 in response to use of DOP and increase of primary production.

Modeling riverine nutrient transport to the Baltic Sea: a large-scale approach.

PubMed

Mörth, Carl-Magnus; Humborg, Christoph; Eriksson, Hanna; Danielsson, Asa; Medina, Miguel Rodriguez; Löfgren, Stefan; Swaney, Dennis P; Rahm, Lars

2007-04-01

We developed for the first time a catchment model simulating simultaneously the nutrient land-sea fluxes from all 105 major watersheds within the Baltic Sea drainage area. A consistent modeling approach to all these major watersheds, i.e., a consistent handling of water fluxes (hydrological simulations) and loading functions (emission data), will facilitate a comparison of riverine nutrient transport between Baltic Sea subbasins that differ substantially. Hot spots of riverine emissions, such as from the rivers Vistula, Oder, and Daugava or from the Danish coast, can be easily demonstrated and the comparison between these hot spots, and the relatively unperturbed rivers in the northern catchments show decisionmakers where remedial actions are most effective to improve the environmental state of the Baltic Sea, and, secondly, what percentage reduction of riverine nutrient loads is possible. The relative difference between measured and simulated fluxes during the validation period was generally small. The cumulative deviation (i.e., relative bias) [Sigma(Simulated - Measured)/Sigma Measured x 100 (%)] from monitored water and nutrient fluxes amounted to +8.2% for runoff, to -2.4% for dissolved inorganic nitrogen, to +5.1% for total nitrogen, to +13% for dissolved inorganic phosphorus and to +19% for total phosphorus. Moreover, the model suggests that point sources for total phosphorus compiled by existing pollution load compilations are underestimated because of inconsistencies in calculating effluent loads from municipalities.

In situ nitrification rates and activity of present nitrifiers in the bottom water layer of two Baltic coastal zones affected by different riverine nutrient loads

NASA Astrophysics Data System (ADS)

Bartl, I.; Münster Happel, E.; Riemann, L.; Voss, M.

2016-02-01

Baltic coastal zones are among the most eutrophied in the world receiving high loads of nitrogen from riverine inputs. However, not only the loads but also the internal dynamics in coastal zones might have positive feedback on eutrophication through efficient remineralisation of organic material in the bottom water. Therefore, we studied nitrification, which is a vital remineralisation process, near the seafloor along with the community of nitrifying microorganisms. We hypothesize that a high nutrient and organic matter load leads to elevated ammonium concentrations in coastal waters and thus stimulates nitrification rates and alters the nitrifying community. Here we present results from 3 cruises combining nitrification rate measurements by 15N-incubations with sequence-based analyses of present and active nitrifiers in the bottom water of two sites in the Baltic Sea receiving different nutrient loads. The first results from the Bonus projects COCOA and BLUEPRINT indicate an increase of nitrification rates with depth as well as distance from the river mouth. In situ rates in the bottom water of the nutrient rich Vistula plume range from 53 to 197 nmol L-1 d-1 and from 10 to 646 nmol L-1 d-1 during winter and summer, respectively. In the nutrient poor Öre estuary rates increased significantly by 11 nmol L-1 d-1 from the river mouth to the outermost station. The relationship between nitrification rates, nitrifiers and trophic state of the coastal zone shall be discussed.

Evaluating the performance of a retrofitted stormwater wet pond for treatment of urban runoff.

PubMed

Schwartz, Daniel; Sample, David J; Grizzard, Thomas J

2017-06-01

This paper describes the performance of a retrofitted stormwater retention pond (Ashby Pond) in Northern Virginia, USA. Retrofitting is a common practice which involves modifying existing structures and/or urban landscapes to improve water quality treatment, often compromising standards to meet budgetary and site constraints. Ashby Pond is located in a highly developed headwater watershed of the Potomac River and the Chesapeake Bay. A total maximum daily load (TMDL) was imposed on the Bay watershed by the US Environmental Protection Agency in 2010 due to excessive sediment and nutrient loadings leading to eutrophication of the estuary. As a result of the TMDL, reducing nutrient and sediment discharged loads has become the key objective of many stormwater programs in the Bay watershed. The Ashby Pond retrofit project included dredging of accumulated sediment to increase storage, construction of an outlet structure to control flows, and repairs to the dam. Due to space limitations, pond volume was less than ideal. Despite this shortcoming, Ashby Pond provided statistically significant reductions of phosphorus, nitrogen, and suspended sediments. Compared to the treatment credited to retention ponds built to current state standards, the retrofitted pond provided less phosphorus but more nitrogen reduction. Retrofitting the existing stock of ponds in a watershed to at least partially meet current design standards could be a straightforward way for communities to attain downstream water quality goals, as these improvements represent reductions in baseline loads, whereas new ponds in new urban developments simply limit future load increases or maintain the status quo.

Nutrient variations from swine manure to agricultural land

PubMed Central

You, Byung-Gu; Shim, Soomin; Choi, Yoon-Seok

2018-01-01

Objective Swine manure in Korea is separated into solid and liquid phases which are composted separately and then applied on land. The nutrient accumulation in soil has been a big issue in Korea but the basic investigation about nutrient input on arable land has not been achieved in detail. Within the nutrient production from livestock at the national level, most values are calculated by multiplication of the number of animals with the excreta unit per animal. However, the actual amount of nutrients from swine manure may be totally different with the nutrients applied to soil since livestock breeding systems are not the same with each country. Methods This study investigated 15 farms producing solid compost and 14 farms producing liquid compost. Composting for solid phase used the Turning+Aeration (TA) or Turning (T) only methods, while liquid phase aeration composting was achieved by continuous (CA), intermittent (IA), or no aeration (NA). Three scenarios were constructed for investigating solid compost: i) farm investigation, ii) reference study, and iii) theoretical P changes (ΔP = 0), whereas an experiment for water evaporation was conducted for analyzing liquid compost. Results In farm investigation, weight loss rates of 62% and 63% were obtained for TA and T, respectively, while evaporation rates for liquid compost were 8.75, 7.27, and 5.14 L/m2·d for CA, IA, and NA, respectively. Farm investigation provided with the combined nutrient load (solid+liquid) of VS, N, and P of 117.6, 7.2, and 2.7 kg/head·yr. Nutrient load calculated from farm investigation is about two times higher than the calculated with reference documents. Conclusion The nutrient loading coefficients from one swine (solid+liquid) were (volatile solids, 0.79; nitrogen, 0.53; phosphorus, 0.71) with nutrient loss of 21%, 47%, and 29%, respectively. The nutrient count from livestock manure using the excretion unit has probably been overestimated without consideration of the nutrient loss. PMID:29268574

A potential integrated water quality strategy for the Mississippi River Basin and the Gulf of Mexico.

PubMed

Greenhalgh, S; Faeth, P

2001-11-22

Nutrient pollution, now the leading cause of water quality impairment in the U.S., has had significant impact on the nation"s waterways. Excessive nutrient pollution has been linked to habitat loss, fish kills, blooms of toxic algae, and hypoxia (oxygen-depleted water). The hypoxic "dead zone" in the Gulf of Mexico is one of the most striking illustrations of what can happen when too many nutrients from inland watersheds reach coastal areas. Despite programs to improve municipal wastewater treatment facilities, more stringent industrial wastewater requirements, and agricultural programs designed to reduce sediment loads in waterways, water quality and nutrient pollution continues to be a problem, and in many cases has worsened. We undertook a policy analysis to assess how the agricultural community could better reduce its contribution to the dead zone and also to evaluate the synergistic impacts of these policies on other environmental concerns such as climate change. Using a sectorial model of U.S. agriculture, we compared policies including untargeted conservation subsidies, nutrient trading, Conservation Reserve Program extension, agricultural sales of carbon and greenhouse gas credits, and fertilizer reduction. This economic and environmental analysis is watershed-based, primarily focusing on nitrogen in the Mississippi River basin, which allowed us to assess the distribution of nitrogen reduction in streams, environmental co-benefits, and impact on agricultural cash flows within the Mississippi River basin from various options. The model incorporates a number of environmental factors, making it possible to get a more a complete picture of the costs and co-benefits of nutrient reduction. These elements also help to identify the policy options that minimize the costs to farmers and maximize benefits to society.

Nutrients, high light, and shallow depths favor the expansion of the brown macroalgae Turbinaria ornata in the coral reefs of Mo'orea, French Polynesia

NASA Astrophysics Data System (ADS)

Rogers, J.; Cordoba, G.; Nieves, M.; Barber, P. H.; Fong, P.; Sura, S.

2016-02-01

Coral reefs provide food, recreation and economic resources for billions of people. Despite this importance, anthropogenic stressors including climate change and nutrification threaten coral reefs globally, causing phase-shifts to algal dominated ecosystems and loss of coral habitats. Throughout the tropical South Pacific, the brown macroalgae Turbinaria ornata is expanding its range and now dominates areas where corals used to thrive, especially shallow areas on fringing reefs of French Polynesia. Abiotic factors like light and nutrient availability could enhance the expansion of T. ornata by promoting its growth or by making it physically tougher, which could reduce herbivory pressure and enhance its survival in high energy zones. To understand the abiotic factors favoring growth and survival of T. ornata in Mo'orea, French Polynesia, we conducted a field experiment testing the effect of nutrients (+/- fertilizer), depth (1m within Turbinaria zone, 1.5m at border, 2m below depth distribution), and light (+/- shade) on the growth and toughness of T. ornata. Three-factor ANOVA showed that an interaction between nutrients and light favored T. ornata biomass accumulation (p=0.04). In addition, T. ornata from shallow depths were significantly tougher than intermediate depths (p=0.01). These results imply that nutrient enrichment combined with high light levels common in shallow coral reefs may promote growth and expansion of T. ornata to near-shore reef environments. Increased survival and population growth is likely further enhanced by increased toughness of T. ornata in shallow areas, which may limit herbivore grazing and improve survival in strong wave action or currents. Future research should examine whether reducing nutrient loading to coastal waters may limit the expansion of T. ornata in the South Pacific.

Nutrients, High Light and Shallow Depths Favor the Expansion of the Brown Macroalgae Turbinaria ornata in the Coral Reefs of Mo'orea, French Polynesia

NASA Astrophysics Data System (ADS)

Nieves, M.; Cordoba, G.; Rogers, J.

2016-02-01

Coral reefs provide food, recreation and economic resources for billions of people. Despite this importance, anthropogenic stressors including climate change and nutrification threaten coral reefs globally, causing phase-shifts to algal dominated ecosystems and loss of coral habitats. Throughout the tropical South Pacific, the brown macroalgae Turbinaria ornata is expanding its range and now dominates areas where corals used to thrive, especially shallow areas on fringing reefs of French Polynesia. Abiotic factors like light and nutrient availability could enhance the expansion of T. ornata by promoting its growth or by making it physically tougher, which could reduce herbivory pressure and enhance its survival in high energy zones. To understand the abiotic factors favoring growth and survival of T. ornata in Mo'orea, French Polynesia, we conducted a field experiment testing the effect of nutrients (+/- fertilizer), depth (1m within Turbinaria zone, 1.5m at border, 2m below depth distribution), and light (+/- shade) on the growth and toughness of T. ornata. Three-factor ANOVA showed that an interaction between nutrients and light favored T. ornata biomass accumulation (p=0.04). In addition, T. ornata from shallow depths were significantly tougher than those at intermediate depths (p=0.01). These results imply that nutrient enrichment combined with high light levels common in shallow coral reefs may promote growth and expansion of T. ornata to near-shore reef environments. Increased survival and population growth is likely further enhanced by increased toughness of T. ornata in shallow areas, which may limit herbivore grazing and improve survival in strong wave action or currents. Future research should examine whether reducing nutrient loading to coastal waters may limit the expansion of T. ornata in the South Pacific.

Watershed Modeling to Assess the Sensitivity of Streamflow, Nutrient, and Sediment Loads to Potential Climate Change and Urban Development in 20 U.S. Watersheds (Final Report)

EPA Science Inventory

In September 2013, EPA announced the release of the final report, Watershed Modeling to Assess the Sensitivity of Streamflow, Nutrient, and Sediment Loads to Potential Climate Change and Urban Development in 20 U.S. Watersheds.

Watershed modeling was conducted in ...

Application of the coastal generalized ecosystem model (CGEM) to assess the impacts of a potential future climate scenario on northern Gulf of Mexico hypoxia

EPA Science Inventory

Mechanistic hypoxia models for the northern Gulf of Mexico are being used to guide policy goals for Mississippi River nutrient loading reductions. However, to date, these models have not examined the effects of both nutrient loads and future climate. Here, we simulate a future c...

Modelling nutrient fluxes from diffuse and point emissions to river loads: the Estonian part of the transboundary Lake Peipsi/Chudskoe drainage basin (Russia/Estonia/Latvia).

PubMed

Mourad, D; van der Perk, M

2004-01-01

First results are presented of a large-scale GIS-based nutrient transport modelling for the 1985-1999 period in the Estonian part of the transboundary drainage basin of Lake Peipsi (Estonian)/Chudskoe (Russian), one of the largest lakes in Europe, shared by Russia and Estonia. Although the lake is relatively undisturbed by human pollution, it is vulnerable for eutrophication by increased river loads, as shown in the past, when the north-eastern part of the former Soviet Union suffered from intensive agriculture. The collapse of the Soviet Union caused a dramatic decline in fertilizer application rates and widespread abandonment of agricultural land. Although concentration measurements and modelling results indicate a general decrease in nutrient loads, modelling is complicated by the transfer of nutrients from diffuse emissions, which is strongly governed by retention and assumed periodic release from storages within the river basin, like the root zone, tile drains, ditches, channels, bed sediments, floodplains and lakes. Modelling diffuse emission contribution to river loads can be improved by better knowledge about the spatial and temporal distribution of this retention and release within the drainage basin.

Impact assessment of non-indigenous jellyfish species on the estuarine community dynamic: A model of medusa phase

NASA Astrophysics Data System (ADS)

Muha, Teja Petra; Teodósio, Maria Alexandra; Ben-Hamadou, Radhouan

2017-03-01

Non-indigenous jellyfish species (NIJS) Blackforida virginica have recently been introduced to the Guadiana Estuary. A modelling approach was used for the assessment of the species-specific impact on the native community, during the medusa phase. The novel interactions between NIJS and the native community are assessed through biomass variation including hydrodynamic and climatic variables. Sensitivity analysis shows that both native species, as well as NIJS highly depend on the water discharge regime, nutrient contribution and the amount of detritus production. Abiotic factors such as the Northern Atlantic Oscillation, water discharge, nutrient load and detritus production are the most influential factors for the dynamics of the estuarine ecosystem demonstrated by the model. Low water discharge and low nutrient retention rate appear to be the most favourable conditions for B. virginica. The species is a non-selective predator able to integrate into the system effectively and has caused a decrease in the biomass of other organisms in the estuarine ecosystem throughout the summer after dam removal. The B. virginica significant impact can be evaluated only when the jellyfish detritus food pathway is involved. The B. virginica predatory impact potential, as well as food preference, appears to be the most influential factors for the overall biomass variation. On the contrary, winter freshwater pulses reduce the survival rate of jellyfish polyps which results in a decrease of medusa during summer. The model presents a strong ecohydrology movement where the fluctuation of organism biomass strongly depends on the hydrological conditions including the amount of nutrient load.

Effect of Nutrient Management Planning on Crop Yield, Nitrate Leaching and Sediment Loading in Thomas Brook Watershed

NASA Astrophysics Data System (ADS)

Amon-Armah, Frederick; Yiridoe, Emmanuel K.; Ahmad, Nafees H. M.; Hebb, Dale; Jamieson, Rob; Burton, David; Madani, Ali

2013-11-01

Government priorities on provincial Nutrient Management Planning (NMP) programs include improving the program effectiveness for environmental quality protection, and promoting more widespread adoption. Understanding the effect of NMP on both crop yield and key water-quality parameters in agricultural watersheds requires a comprehensive evaluation that takes into consideration important NMP attributes and location-specific farming conditions. This study applied the Soil and Water Assessment Tool (SWAT) to investigate the effects of crop and rotation sequence, tillage type, and nutrient N application rate on crop yield and the associated groundwater leaching and sediment loss. The SWAT model was applied to the Thomas Brook Watershed, located in the most intensively managed agricultural region of Nova Scotia, Canada. Cropping systems evaluated included seven fertilizer application rates and two tillage systems (i.e., conventional tillage and no-till). The analysis reflected cropping systems commonly managed by farmers in the Annapolis Valley region, including grain corn-based and potato-based cropping systems, and a vegetable-horticulture system. ANOVA models were developed and used to assess the effects of crop management choices on crop yield and two water-quality parameters (i.e., leaching and sediment loading). Results suggest that existing recommended N-fertilizer rate can be reduced by 10-25 %, for grain crop production, to significantly lower leaching ( P > 0.05) while optimizing the crop yield. The analysis identified the nutrient N rates in combination with specific crops and rotation systems that can be used to manage leaching while balancing impacts on crop yields within the watershed.

Fish farming enhances biomass and nutrient loss in Posidonia oceanica (L.) Delile

NASA Astrophysics Data System (ADS)

Apostolaki, Eugenia T.; Marbà, Núria; Holmer, Marianne; Karakassis, Ioannis

2009-02-01

Fish farming impact on the seasonal biomass, carbon and nutrient (nitrogen and phosphorus) balance of the endemic Mediterranean seagrass Posidonia oceanica was assessed in the Aegean Sea (Greece) in order to detect changes in magnitude and fate of seagrass production and nutrient incorporation with organic loading of the meadows. Phosphorus concentration in the leaves, rhizomes and roots was enhanced under the cages throughout the study. Standing biomass was diminished by 64% and carbon, nitrogen and phosphorus standing stock by 64%, 61% and 48%, respectively, under the cages in relation to those at the control. Seagrass production decreased by 68% and element (C, N, P) incorporation by 67%, 58% and 58%, respectively, under the cages. Leaf shedding was reduced by 81% and loss of elements (C, N, and P) through shedding by 82%, 74% and 72%, respectively, under the cages. Leaf and element (C, N, P) residual loss rate, accounting for grazing and mechanical breakage of leaves, was decreased by 79%, 85%, 100% and 96%, respectively, at the control station. At the control station, 13.98 g C m -2 yr -1, 1.91 g N m -2 yr -1 and 0.05 g P m -2 yr -1 were produced in excess of export and loss. In contrast, under the cages 12.69 g C m -2 yr -1, 0.31 g N m -2 yr -1 and 0.04 g P m -2 yr -1 were released from the meadow. Organic loading due to fish farm discharges transformed the seagrass meadow under the cages from a typical sink to a source of organic carbon and nutrients.

Scaling issues in multi-criteria evaluation of combinations of measures for integrated river basin management

NASA Astrophysics Data System (ADS)

Dietrich, Jörg

2016-05-01

In integrated river basin management, measures for reaching the environmental objectives can be evaluated at different scales, and according to multiple criteria of different nature (e.g. ecological, economic, social). Decision makers, including responsible authorities and stakeholders, follow different interests regarding criteria and scales. With a bottom up approach, the multi criteria assessment could produce a different outcome than with a top down approach. The first assigns more power to the local community, which is a common principle of IWRM. On the other hand, the development of an overall catchment strategy could potentially make use of synergetic effects of the measures, which fulfils the cost efficiency requirement at the basin scale but compromises local interests. Within a joint research project for the 5500 km2 Werra river basin in central Germany, measures have been planned to reach environmental objectives of the European Water Framework directive (WFD) regarding ecological continuity and nutrient loads. The main criteria for the evaluation of the measures were costs of implementation, reduction of nutrients, ecological benefit and social acceptance. The multi-criteria evaluation of the catchment strategies showed compensation between positive and negative performance of criteria within the catchment, which in the end reduced the discriminative power of the different strategies. Furthermore, benefit criteria are partially computed for the whole basin only. Both ecological continuity and nutrient load show upstream-downstream effects in opposite direction. The principles of "polluter pays" and "overall cost efficiency" can be followed for the reduction of nutrient losses when financial compensations between upstream and downstream users are made, similar to concepts of emission trading.

Nutrient loading and macrophyte growth in Wilson Inlet, a bar-built southwestern Australian estuary

NASA Astrophysics Data System (ADS)

Lukatelich, R. J.; Schofield, N. J.; McComb, A. J.

1987-02-01

Wilson Inlet is a 'bar-built' estuary, open to the ocean only when a sandbar has been breached after river flow. estimates are presented of phosphorus and nitrogen loadings from rivers, losses to the ocean, and amounts present in estuarine components during a particular year. Following bar opening, a volume of water equivalent to 35% of estuarine volume at the time was lost, providing a major loss of dissolved nutrients from the estuary. While the bar was open (51 days) water was displaced through river flow, but there was little tidal exchange. There was net retention of phosphorus (about 60% of river input) and some loss of nitrogen (less than 15%). Much of the nutrient held in the estuary was in surface sediments, but concentrations have shown little change with time and are similar to other southwestern estuaries. In contrast there have been massive increases in the biomass of Ruppia megacarpa Mason in recent years; this constitutes more than 90% of plant biomass. The nutrient bank in this plant is large compared to the water column, and amounts recycled through plant material greatly exceeded riverine loading in the year of the study. Tissue N concentrations were relatively high and constant, tissue P relatively low and seasonally variable, suggesting P limitation of plant biomass. Estimates of nutrient loading from streams showed relatively higher nutrient inputs from catchments cleared for agriculture. These are in higher rainfall areas, have high drainage densities, large proportions of sandy soils and are subjected to phosphatic fertilizer application.

Nutrient Loads Flowing into Coastal Waters from the Main Rivers of China (2006–2012)

PubMed Central

Tong, Yindong; Zhao, Yue; Zhen, Gengchong; Chi, Jie; Liu, Xianhua; Lu, Yiren; Wang, Xuejun; Yao, Ruihua; Chen, Junyue; Zhang, Wei

2015-01-01

Based on monthly monitoring data of unfiltered water, the nutrient discharges of the eight main rivers flowing into the coastal waters of China were calculated from 2006 to 2012. In 2012, the total load of NH3-N (calculated in nitrogen), total nitrogen (TN, calculated in nitrogen) and total phosphorus (TP, calculated in phosphorus) was 5.1 × 105, 3.1 × 106 and 2.8 × 105 tons, respectively, while in 2006, the nutrient load was 7.4 × 105, 2.2 × 106 and 1.6 × 105 tons, respectively. The nutrient loading from the eight major rivers into the coastal waters peaked in summer and autumn, probably due to the large water discharge in the wet season. The Yangtze River was the largest riverine nutrient source for the coastal waters, contributing 48% of the NH3-N discharges, 66% of the TN discharges and 84% of the TP discharges of the eight major rivers in 2012. The East China Sea received the majority of the nutrient discharges, i.e. 50% of NH3-N (2.7 × 105 tons), 70% of TN (2.2 × 106 tons) and 87% of TP (2.5 × 105 tons) in 2012. The riverine discharge of TN into the Yellow Sea and Bohai Sea was lower than that from the direct atmospheric deposition, while for the East China Sea, the riverine TN input was larger. PMID:26582206

Nutrient Loads Flowing into Coastal Waters from the Main Rivers of China (2006-2012).

PubMed

Tong, Yindong; Zhao, Yue; Zhen, Gengchong; Chi, Jie; Liu, Xianhua; Lu, Yiren; Wang, Xuejun; Yao, Ruihua; Chen, Junyue; Zhang, Wei

2015-11-19

Based on monthly monitoring data of unfiltered water, the nutrient discharges of the eight main rivers flowing into the coastal waters of China were calculated from 2006 to 2012. In 2012, the total load of NH3-N (calculated in nitrogen), total nitrogen (TN, calculated in nitrogen) and total phosphorus (TP, calculated in phosphorus) was 5.1 × 10(5), 3.1 × 10(6) and 2.8 × 10(5) tons, respectively, while in 2006, the nutrient load was 7.4 × 10(5), 2.2 × 10(6) and 1.6 × 10(5) tons, respectively. The nutrient loading from the eight major rivers into the coastal waters peaked in summer and autumn, probably due to the large water discharge in the wet season. The Yangtze River was the largest riverine nutrient source for the coastal waters, contributing 48% of the NH3-N discharges, 66% of the TN discharges and 84% of the TP discharges of the eight major rivers in 2012. The East China Sea received the majority of the nutrient discharges, i.e. 50% of NH3-N (2.7 × 10(5) tons), 70% of TN (2.2 × 10(6) tons) and 87% of TP (2.5 × 10(5) tons) in 2012. The riverine discharge of TN into the Yellow Sea and Bohai Sea was lower than that from the direct atmospheric deposition, while for the East China Sea, the riverine TN input was larger.

Sediment and nutrient budgets are inherently dynamic: evidence from a long-term study of two subtropical reservoirs

NASA Astrophysics Data System (ADS)

O'Brien, Katherine R.; Weber, Tony R.; Leigh, Catherine; Burford, Michele A.

2016-12-01

Accurate reservoir budgets are important for understanding regional fluxes of sediment and nutrients. Here we present a comprehensive budget of sediment (based on total suspended solids, TSS), total nitrogen (TN) and total phosphorus (TP) for two subtropical reservoirs on rivers with highly intermittent flow regimes. The budget is completed from July 1997 to June 2011 on the Somerset and Wivenhoe reservoirs in southeast Queensland, Australia, using a combination of monitoring data and catchment model predictions. A major flood in January 2011 accounted for more than half of the water entering and leaving both reservoirs in that year, and approximately 30 % of water delivered to and released from Wivenhoe over the 14-year study period. The flood accounted for an even larger proportion of total TSS and nutrient loads: in Wivenhoe more than one-third of TSS inputs and two-thirds of TSS outputs between 1997 and 2011 occurred during January 2011. During non-flood years, mean historical concentrations provided reasonable estimates of TSS and nutrient loads leaving the reservoirs. Calculating loads from historical mean TSS and TP concentrations during January 2011, however, would have substantially underestimated outputs over the entire study period, by up to a factor of 10. The results have important implications for sediment and nutrient budgets in catchments with highly episodic flow. First, quantifying inputs and outputs during major floods is essential for producing reliable long-term budgets. Second, sediment and nutrient budgets are dynamic, not static. Characterizing uncertainty and variability is therefore just as important for meaningful reservoir budgets as accurate quantification of loads.

Trophic and stoichiometric consequences of nutrification for the intertidal tropical zoanthid Zoanthus sociatus.

PubMed

Leal, Miguel C; Rocha, Rui J M; Anaya-Rojas, Jaime M; Cruz, Igor C S; Ferrier-Pagès, Christine

2017-06-15

Zoanthids are conspicuous and abundant members of intertidal environments, where they are exposed to large environmental fluctuations and subject to increasing loads of anthropogenic nutrients. Here we assess the trophic ecology and stoichiometric consequences of nutrient loading for symbiotic zoanthids inhabiting different intertidal habitats. More specifically, we analysed the stable isotope signature (δ 13 C and δ 15 N), elemental composition (C, N and P) and stoichiometry (C:N, C:P, N:P) of Zoanthus sociatus differently exposed to nutrification. Results suggest that autotrophy is the main feeding mode of zoanthids and that the effect water nutrient content differently affects the elemental phenotype of zoanthids depending on tidal habitat. Additionally, habitat effects on Z. sociatus P-related stoichiometric traits highlight functional differences likely associated with variation in Symbiodinium density. These findings provide an innovative approach to assess how cnidarian-dinoflagellate symbioses response to ecosystem changes in environmentally dynamic reef flats, particularly nutrient loading. Copyright © 2017 Elsevier Ltd. All rights reserved.

The spatial structure and temporal synchrony of water quality in stream networks

NASA Astrophysics Data System (ADS)

Abbott, Benjamin; Gruau, Gerard; Zarneske, Jay; Barbe, Lou; Gu, Sen; Kolbe, Tamara; Thomas, Zahra; Jaffrezic, Anne; Moatar, Florentina; Pinay, Gilles

2017-04-01

To feed nine billion people in 2050 while maintaining viable aquatic ecosystems will require an understanding of nutrient pollution dynamics throughout stream networks. Most regulatory frameworks such as the European Water Framework Directive and U.S. Clean Water Act, focus on nutrient concentrations in medium to large rivers. This strategy is appealing because large rivers integrate many small catchments and total nutrient loads drive eutrophication in estuarine and oceanic ecosystems. However, there is growing evidence that to understand and reduce downstream nutrient fluxes we need to look upstream. While headwater streams receive the bulk of nutrients in river networks, the relationship between land cover and nutrient flux often breaks down for small catchments, representing an important ecological unknown since 90% of global stream length occurs in catchments smaller than 15 km2. Though continuous monitoring of thousands of small streams is not feasible, what if we could learn what we needed about where and when to implement monitoring and conservation efforts with periodic sampling of headwater catchments? To address this question we performed repeat synoptic sampling of 56 nested catchments ranging in size from 1 to 370 km2 in western France. Spatial variability in carbon and nutrient concentrations decreased non-linearly as catchment size increased, with thresholds in variance for organic carbon and nutrients occurring between 36 and 68 km2. While it is widely held that temporal variance is higher in smaller streams, we observed consistent temporal variance across spatial scales and the ranking of catchments based on water quality showed strong synchrony in the water chemistry response to seasonal variation and hydrological events. We used these observations to develop two simple management frameworks. The subcatchment leverage concept proposes that mitigation and restoration efforts are more likely to succeed when implemented at spatial scales expressing high variability in the target parameter, which indicates decreased system inertia and demonstrates that alternative system responses are possible. The subcatchment synchrony concept suggests that periodic sampling of headwaters can provide valuable information about pollutant sources and inherent resilience in subcatchments and that if agricultural activity were redistributed based on this assessment of catchment vulnerability to nutrient loading, water quality could be improved while maintaining crop yields.

Nutrient sequestration in Aquitaine lakes (SW France) limits nutrient flux to the coastal zone

NASA Astrophysics Data System (ADS)

Buquet, Damien; Anschutz, Pierre; Charbonnier, Céline; Rapin, Anne; Sinays, Rémy; Canredon, Axel; Bujan, Stéphane; Poirier, Dominique

2017-12-01

Oligotrophic coastal zones are disappearing from increased nutrient loading. The quantity of nutrients reaching the coast is determined not only by their original source (e.g. fertilizers used in agriculture, waste water discharges) and the land use, but also by the pathways through which nutrients are cycled from the source to the river mouth. In particular, lakes sequester nutrients and, hence, reduce downstream transfer of nutrients to coastal environments. Here, we quantify the impact of Aquitaine great lakes on the fluxes of dissolved macro-nutrients (N, P, Si) to the Bay of Biscay. For that, we have measured nutrient concentrations and fluxes in 2014 upstream and downstream lakes of Lacanau and Carcans-Hourtin, which belongs to the catchment of the Arcachon Bay, which is the largest coastal lagoon of the Bay of Biscay French coast. Data were compared to values obtained from the Leyre river, the main freshwater and nutrient source for the lagoon. Results show that processes in lakes greatly limit nutrient flux to the lagoon compared to fluxes from Leyre river, although the watershed is similar in terms of land cover. In lakes, phosphorus and silicon are trapped for long term in the sediment, silicon as amorphous biogenic silica and phosphorus as organic P and P associated with Fe-oxides. Nitrogen that enters lakes mostly as nitrate is used for primary production. N is mineralized in the sediment; a fraction diffuses as ammonium. N2 production through benthic denitrification extracts only 10% of dissolved inorganic nitrogen from the aquatic system. The main part is sequestered in organic-rich sediment that accumulates below 5 m depth in both lakes.

NUTRIENT CONTAMINATION AS A RESULT OF POINT SOURCE DISCHARGES: A SURVEY

EPA Science Inventory

Nutrients are common contaminants in Gulf of Mexico estuaries and when present in high concentrations, they can cause excessive algal growths and hypoxic conditions. The magnitude and biological significance of nutrient loading to estuarine waters receiving treated wastewaters is...

MICROBIAL ENZYME ACTIVITY FOR CHARACTERIZING NUTRIENT LOADING TO GREAT LAKES COASTAL WETLANDS

EPA Science Inventory

Energy and material flows in aquatic ecosystems are mediated by microbial carbon and nutrient cycling. Extracellular enzymes produced by the microbial community aid in the degradation of organic matter and the resultant acquisition of limiting nutrients. Organic carbon sequestrat...

Evaluating the relative roles of ecological regions and land-cover composition for guiding establishment of nutrient criteria

Treesearch

James D. Wickham; Kurt H. Riitters; Timothy G. Wade; K. Bruce Jones

2005-01-01

The continuing degradation of United States surface waters by excessive nutrient loads has motivated the establishment of nutrient criteria for streams, lakes, and estuaries as a means to protect aquatic resources. Nutrient criteria have been established based on ecoregional differences, recognizing that geographic variation in climate, topography, geology, and land...

Microstructural and associated chemical changes during the composting of a high temperature biochar: Mechanisms for nitrate, phosphate and other nutrient retention and release

USDA-ARS?s Scientific Manuscript database

Recent studies have demonstrated the importance of the nutrient status of biochar and soils prior to its inclusion in particular agricultural systems. Pre-treatment of nutrient-reactive biochar, where nutrients are loaded into pores and onto surfaces, gives improved yield outcomes compared to untrea...

Using a Hydrodynamic and Biogeochemical Model to Investigate the Effects of Nutrient Loading from a Wastewater Treatment Plant into Lake Michigan

NASA Astrophysics Data System (ADS)

Khazaei, B.; Bravo, H.; Bootsma, H.

2017-12-01

There is clear evidence that excessive nutrient, in particular phosphorus (P), loading into Lake Michigan has produced significant problems, such as algal blooms, hypoxia, and reduced water quality. Addressing those problems requires understanding the transport and fate of P in the lake. The dominance of mixing and dispersion processes on the P transport has been demonstrated, yet recent research has shown the remarkable influence of dreissenid mussels and Cladophora on water clarity and the P budget. Since mussels and Cladophora tend to concentrate near the coastlines, nearshore-offshore P exchange is of a big importance. In this research, a computer model was developed to simulate the P cycle by incorporating the biogeochemical processes relevant to the transport of P into a 3D high-resolution hydrodynamic model. The near-bottom biogeochemical model consists of three linked modules: Cladophora, mussel, and sediment storage modules. The model was applied to the Milwaukee Metropolitan Sewerage District South Shore Wastewater Treatment Plant, between June and October of 2013 and 2015, as a case study. The plant outfall introduces a point source of P into the study domain—the nearshore zone of Lake Michigan adjacent to Milwaukee County. The model was validated against field observations of water temperature, dissolved phosphorus (DP), particulate phosphorus (PP), Cladophora biomass, and P content. The model simulations showed reasonably good agreement with field measurements. Model results showed a) different temporal patterns in 2013 and 2015, b) a larger range of fluctuations in DP than that in PP, and c) that the effects of mussels and Cladophora could explain the differences in patterns and ranges. PP concentrations showed more frequent spikes of concentration in 2013 due to resuspension events during that year because of stronger winds. The model is being applied as a management tool to test scenarios of nutrient loading to determine effluent P limits for the treatment plant. The alongshore lengths of the surface layer-footprints of total phosphorus (TP) that exceeded the target concentration of 7 μg L-1 during 25% of the summer season were approximately 30 and 24 Km in 2013 and 2015, respectively. That result indicates that the footprint was reduced by the application of a more efficient loading scenario in 2015.

Transposing Concentration-Discharge Curves onto Unmonitored Catchments to Estimate Seasonal Nutrient Loads

NASA Astrophysics Data System (ADS)

Minaudo, C.; Moatar, F.; Abbott, B. W.; Dupas, R.; Gascuel-Odoux, C.; Pinay, G.; Roubeix, V.; Danis, P. A.

2017-12-01

Many lakes and reservoirs in Europe suffer from severe eutrophication. Accurate quantification of nutrient loads are critical for effective mitigation measures, but this information is often unknown. For example, in France, only 50 out of 481 lakes and reservoirs have national monitoring allowing estimation of interannual nitrogen and phosphorus loads, and even these loads are computed from low-frequency data. To address this lack of data, we developed a straightforward method to predict seasonal loads in lake tributaries. First, we analyzed concentration-discharge (C-Q) curves in monitored catchments and identified slopes, intercepts, and coefficient of variation of the log(C)-log(Q) regressions determined for both low and high flows, separated by the median daily flow [Moatar et al., 2017]. Then, we used stepwise multiple linear regression models to empirically link the characteristics of C-Q curves with a set of catchment descriptors such as land use, lithology, morphology indices, climate, and hydrological indicators. Modeled C-Q relationships were then used to estimate annual and seasonal nutrient loads in nearby and similar unmonitored catchments. We implemented this approach on a large dataset from France where stream flow was surveyed daily and water quality (suspended solids, nitrate, total phosphorus, and orthophosphate concentrations) was measured on a monthly basis at 233 stations over the past 20 years in catchments from 10 to 3000 km². The concentration at the median daily flow (seen here as a metric of the general level of contamination in a catchment) was predicted with uncertainty ranging between 30 and 100 %, depending on the variable. C-Q slopes were predicted with large errors, but a sensitivity analysis was conducted to determine the impact of C-Q slopes uncertainties on computed annual and seasonal loads. This approach allows estimation of seasonal and annual nutrient loads and could be potentially implemented to improve protection and restoration of aquatic ecosystems. Moatar, F., B. W. Abbott, C. Minaudo, F. Curie, and G. Pinay. 2017. Elemental properties, hydrology, and biology interact to shape concentration-discharge curves for carbon, nutrients, sediment, and major ions. Water Resources Research 53:1270-1287.

Fate and effects of nitrogen and phosphorus in shallow vegetated aquatic ecosystems

USGS Publications Warehouse

Fairchild, James F.; Vradenburg, Leigh Ann

2006-01-01

Nitrate concentrations have greatly increased in streams and rivers draining agricultural regions of the Midwestern United States, increasing nitrate transport to the Gulf of Mexico has been implicated in the hypoxic conditions that threaten the productivity of marine fisheries. Increases in nitrate concentrations have been attributed to a combination of factors including agricultural expansion, increased nitrogen application rates, increased tile drainage, and loss of riparian Wetlands, These landscape-level changes have resulted in a decreased natural capacity for nitrogen uptake, removal, and cycling back to the atmosphere. Land managers are increasingly interested in using wetland construction and rehabilitation as a management practice to reduce loss of nitrate from the terrestrial systems. Yet, relatively little is known about the limnological factors involved in nitrate removal by Wetland systems.We conducted a series of studies from 1999-2000 to investigate the functional capacity of shallow, macrophyte-dominated pond wetland systems for uptake, assimilation, and retention of nitrogen (N) and phosphorus (P). We evaluated four factors that were hypothesized to influence nutrient uptake and assimilation: 1) nitrate loading rates; 2) nitrogen to phosphorus (N.P) ratios; 3) frequency of dosing/application; and 4) timing of dose initiation.Nutrient assimilation was rapid; store than 90% of added nutrients were removed from the water column in all treatments. Neither variation in N:P ratios (evaluated range, <13:1 to -114.1), frequency of application (weekly or bi-weekly), nor liming of dose initiation relative to macrophyte development (0%, 15-25%, or 75-90% maximum biomass) had significant effects on nutrient assimilation of wetland community dynamics. Maximum loading of nitrate (60 g N/m2 2.4 g P/m2) applied as six weekly doses stimulated algal communities, but inhibited macrophyte communities.Predicted shifts from a stable state of macrophyte- to phytoplankton-dominance did not occur due to nutrient additions. Macrophytes, phytoplankton, and the sediment surface were all significant factors in the removal of nitrate from the Water column. Overall, these shallow macrophyte-dominated systems provided an efficient means of removing nutrients from the water column. Construction or rehabilitation of shallow, vegetated wetlands may offer promise as land management practices for nutrient removal in agricultural watersheds.

Water quality and ecosystem management: Data-driven reality check of effects in streams and lakes

NASA Astrophysics Data System (ADS)

Destouni, Georgia; Fischer, Ida; Prieto, Carmen

2017-08-01

This study investigates nutrient-related water quality conditions and change trends in the first management periods of the EU Water Framework Directive (WFD; since 2009) and Baltic Sea Action Plan (BASP; since 2007). With mitigation of nutrients in inland waters and their discharges to the Baltic Sea being a common WFD and BSAP target, we use Sweden as a case study of observable effects, by compiling and analyzing all openly available water and nutrient monitoring data across Sweden since 2003. The data compilation reveals that nutrient monitoring covers only around 1% (down to 0.2% for nutrient loads) of the total number of WFD-classified stream and lake water bodies in Sweden. The data analysis further shows that the hydro-climatically driven water discharge dominates the determination of waterborne loads of both total phosphorus and total nitrogen across Sweden. Both water discharge and the related nutrient loads are in turn well correlated with the ecosystem status classification of Swedish water bodies. Nutrient concentrations do not exhibit such correlation and their changes over the study period are on average small, but concentration increases are found for moderate-to-bad status waters, for which both the WFD and the BSAP have instead targeted concentration decreases. In general, these results indicate insufficient distinction and mitigation of human-driven nutrient components in inland waters and their discharges to the sea by the internationally harmonized applications of the WFD and the BSAP. The results call for further comparative investigations of observable large-scale effects of such regulatory/management frameworks in different parts of the world.

Transcriptional and Physiological Responses to Nutrient Loading on Toxin Formation and Photosynthesis in Microcystis Aeruginosa FACHB-905

PubMed Central

Peng, Guotao; Lin, Sijie; Fan, Zhengqiu; Wang, Xiangrong

2017-01-01

An important goal of understanding harmful algae blooms is to determine how environmental factors affect the growth and toxin formation of toxin-producing species. In this study, we investigated the transcriptional responses of toxin formation gene (mcyB) and key photosynthesis genes (psaB, psbD and rbcL) of Microcystis aeruginosa FACHB-905 in different nutrient loading conditions using real-time reverse transcription quantitative polymerase chain reaction (RT-qPCR). Three physio-biochemical parameters (malondialdehyde (MDA), superoxide dismutase (SOD) and glutathione (GSH)) were also evaluated to provide insight into the physiological responses of Microcystis cells. We observed an upregulation of mcyB gene in nutrient-deficient conditions, especially in nitrogen (N) limitation condition, and the transcript abundance declined after the nutrient were resupplied. Differently, high transcription levels were seen in phosphorus (P) deficient treatments for key photosynthesis genes throughout the culture period, while those in N-deficient cells varied with time, suggesting an adaptive regulation of Microsystis cells to nutrient stress. Increased contents of antioxidant enzymes (SOD and GSH) were seen in both N and P-deficient conditions, suggesting the presence of excess amount of free radical generation caused by nutrient stress. The amount of SOD and GSH continued to increase even after the nutrient was reintroduced and a strong correlation was seen between the MDA and enzyme activities, indicating the robust effort of rebalancing the redox system in Microcystis cells. Based on these transcriptional and physiological responses of M. aeruginosa to nutrient loading, these results could provide more insight into Microcystis blooms management and toxin formation regulation. PMID:28513574

Transcriptional and Physiological Responses to Nutrient Loading on Toxin Formation and Photosynthesis in Microcystis Aeruginosa FACHB-905.

PubMed

Peng, Guotao; Lin, Sijie; Fan, Zhengqiu; Wang, Xiangrong

2017-05-17

An important goal of understanding harmful algae blooms is to determine how environmental factors affect the growth and toxin formation of toxin-producing species. In this study, we investigated the transcriptional responses of toxin formation gene ( mcyB ) and key photosynthesis genes ( psaB , psbD and rbcL) of Microcystis aeruginosa FACHB-905 in different nutrient loading conditions using real-time reverse transcription quantitative polymerase chain reaction (RT-qPCR). Three physio-biochemical parameters (malondialdehyde (MDA), superoxide dismutase (SOD) and glutathione (GSH)) were also evaluated to provide insight into the physiological responses of Microcystis cells. We observed an upregulation of mcyB gene in nutrient-deficient conditions, especially in nitrogen (N) limitation condition, and the transcript abundance declined after the nutrient were resupplied. Differently, high transcription levels were seen in phosphorus (P) deficient treatments for key photosynthesis genes throughout the culture period, while those in N-deficient cells varied with time, suggesting an adaptive regulation of Microsystis cells to nutrient stress. Increased contents of antioxidant enzymes (SOD and GSH) were seen in both N and P-deficient conditions, suggesting the presence of excess amount of free radical generation caused by nutrient stress. The amount of SOD and GSH continued to increase even after the nutrient was reintroduced and a strong correlation was seen between the MDA and enzyme activities, indicating the robust effort of rebalancing the redox system in Microcystis cells. Based on these transcriptional and physiological responses of M. aeruginosa to nutrient loading, these results could provide more insight into Microcystis blooms management and toxin formation regulation.

The response of epiphytic bacteria on Vallisneria natans (Lour.) Hara (Hydrocharitaceae) to increasing nutrient loadings.

PubMed

Cai, Xianlei; Yao, Ling; Gao, Guang; Xie, Yinfeng; Zhang, Yingying; Tang, Xiangming

2016-06-01

To investigate the effects of water column nutrient loading on epiphytic bacteria, we determined the abundance and community composition of epiphytic bacteria on the submerged macrophyte Vallisneria natans (Lour.) Hara during the growth season (June-October) under four different nutrient concentrations (nitrogen (N)-phosphorus (P) in mg L(-1) : 0.5-0.05, 1.0-0.1, 5.0-0.5, 10.0-1.0; hereafter NP-1, NP-2, NP-3, NP-4, respectively), using epifluorescence microscopy method and terminal restriction fragment length polymorphism (T-RFLP) analysis, respectively. Relative to low nutrient conditions (NP-1), there was no significant effect on the epiphytic bacterial community, and even a decrease in the number of epiphytic bacteria, which linked to the well growth status of host macrophytes at moderate nutrient conditions (NP-2). However, further nutrient enrichment induced significant increase in the abundance of epiphytic bacteria, and marked changes in the community structures of epiphytic bacteria. Furthermore, at high nutrient conditions, epiphytic bacterial communities varied widely temporally, and were not stable compared with those at the lower nutrient conditions. These results indicated that the effects of nutrient enrichment on epiphytic bacteria were nonlinear and dependent on the nutrient concentrations in the water. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Developing a nutrient pollution model to assist policy makers by using a meso-scale Minimum Information Requirement (MIR) approach

NASA Astrophysics Data System (ADS)

Adams, R.; Quinn, P. F.; Bowes, M. J.

2014-09-01

A model for simulating runoff pathways and water quality fluxes has been developed using the Minimum Information (MIR) approach. The model, the Catchment Runoff Attenuation Tool (CRAFT) is applicable to meso-scale catchments which focusses primarily on hydrological pathways that mobilise nutrients. Hence CRAFT can be used investigate the impact of management intervention strategies designed to reduce the loads of nutrients into receiving watercourses. The model can help policy makers, for example in Europe, meet water quality targets and consider methods to obtain "good" ecological status. A case study of the 414 km2 Frome catchment, Dorset UK, has been described here as an application of the CRAFT model. The model was primarily calibrated on ten years of weekly data to reproduce the observed flows and nutrient (nitrate nitrogen - N - and phosphorus - P) concentrations. Also data from two years of sub-daily high resolution monitoring at the same site were also analysed. These data highlighted some additional signals in the nutrient flux, particularly of soluble reactive phosphorus, which were not observable in the weekly data. This analysis has prompted the choice of using a daily timestep for this meso-scale modelling study as the minimum information requirement. A management intervention scenario was also run to show how the model can support catchment managers to investigate how reducing the concentrations of N and P in the various flow pathways. This scale appropriate modelling tool can help policy makers consider a range of strategies to to meet the European Union (EU) water quality targets for this type of catchment.

Effect of gamma irradiation on the microbial load, nutrient composition and free radical scavenging activity of Nelumbo nucifera rhizome

NASA Astrophysics Data System (ADS)

Khattak, Khanzadi Fatima; Simpson, Thomas James; Ihasnullah

2009-03-01

The assurance of microbial quality is necessary to make plant materials suitable for human consumption and commercialization. The aim of the present study was to evaluate the possibility to apply the gamma radiation treatment on the rhizome samples of Nelumbo nucifera for microbial decontamination. The radiation processing was carried out at dose levels of 1, 2, 4 and 6 kGy. The irradiated and control samples were analyzed for microbial load, organoleptic acceptance, extraction yield, proximate composition, phenolic contents and DPPH scavenging activity. The results indicated that gamma radiation treatment significantly reduced microbial load and increased the storability of the irradiated samples. The treated samples were also acceptable sensorically. The extraction yield and phenolic contents increased with the increase of radiation dose. Gamma radiation also enhanced the DPPH scavenging activity.

Subterranean Groundwater Nutrient Input to Coastal Oceans and Coral Reef Sustainability

NASA Astrophysics Data System (ADS)

Paytan, A.; Street, J. H.

2003-12-01

Coral reefs are often referred to as the tropical rain forests of the oceans because of their high productivity and biodiversity. Recent observations in coral reefs worldwide have shown clear degradation in water quality and coral reef health and diversity. The implications of this are severe, including tremendous economic losses mostly though fishing and tourism. Nutrient loading has been implicated as one possible cause for the ecosystem decline. A previously unappreciated potential source of nutrient loading is submarine ground water discharge (SGW). Ground water in many cases has high nutrient content from sewage pollution and fertilizer application for agriculture and landscaping. To better understand the effect of this potential source of nutrient input and degrading water quality, we are exploring the contribution of SGW to the nutrient levels in coral reefs. A key to this approach is determining the amount and source of SGW that flows into the coast as well as its nutrient concentrations. The SGW flux and associated input of chemical dissolved load (nutrient, DOC, trace elements and other contaminants) is quantified using naturally occurring Ra isotopes. Radium isotopes have been shown to be excellent tracers for SGW inputs into estuaries and coastal areas (Moore, 1996; Hussain et al., 1999; Kerst et al., 2000). Measurements of Ra activity within the coral reef, the lagoons and the open waters adjacent to the reef provide valuable information regarding the input of Ra as well as nutrients and possibly pollutant from groundwater discharge. Through this analysis the effect of SGD on the delicate carbon and nutrient balance of the fragile coral reef ecosystem could be evaluated. In addition to quantifying the contribution of freshwater to the nutrient mass balance in the reef, information regarding the length of time a water parcel has remained in the near-shore region over the reef can be estimated using the Ra isotope quartet.

Couplings of watersheds and coastal waters: Sources and consequences of nutrient enrichment in Waquoit Bay, Massachusetts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Valiela, I.; Foreman, K.; LaMontagne, M.

1992-12-01

Human activities on coastal watersheds provide the major sources of nutrients entering shallow coastal ecosystems. Nutrient loadings from watersheds alter structure and function of receiving aquatic ecosystems. To investigate this coupling of land to marine systems, a series of subwatersheds of Waquoit Bay differing in degree of urbanization and with widely different nutrient loading rates was studied. The subwatersheds differ in septic tanks numbers and forest acreage. Ground water is the major mechanism that transports nutrients to coastal waters. Some attenuation of nutrient concentrations within the aquifer or at the sediment-water interface, but significant increases in the nutrient content ofmore » groundwater arriving at the shore's edge are in urbanized areas. The groundwater flows through the sediment-water boundary, and sufficient groundwater-borne nutrients (nitrogen in particular) traverse the sediment-water boundary to cause significant changes in the aquatic ecosystem. These loading-dependent alterations include increased nutrients in water, greater primary production by phytoplankton, and increased macroalgal biomass and growth. The increased macroalgal biomass dominates the bay ecosystem through second- or third-order effects such as alterations of nutrient status of water columns and increasing frequency of anoxic events. The increases in seaweeds have decreased the areas covered by eelgrass habitats. The change in habitat type, plus the increased frequency of anoxic events, change the composition of the benthic fauna. The importance of bottom-up control in shallow coastal food webs is evident. The coupling of land to sea by groundwater-borne nutrient transport is mediated by a complex series of steps, making it unlikely to find a one-to-one relation between land use and conditions in the aquatic ecosystem. Appropriate models may provide a way to deal with the complexities of the coupling. 22 refs., 14 figs., 5 tabs.« less

Seasonal sediment and nutrients transport patterns

USDA-ARS?s Scientific Manuscript database

It is essential to understand sediment and nutrient sources and their spatial and temporal patterns in order to design effective mitigation strategies. However, long-term data sets to determine sediment and nutrient loadings are scarce and expensive to collect. The goal of this study was to determin...

Watershed Modeling to Assess the Sensitivity of Streamflow, Nutrient, and Sediment Loads to Potential Climate Change and Urban Development in 20 U.S. Watersheds (External Review Draft)

EPA Science Inventory

EPA has released for independent external peer review and public comment a draft report titled, Watershed Modeling to Assess the Sensitivity of Streamflow, Nutrient, and Sediment Loads to Potential Climate Change and Urban Development in 20 U.S. Watersheds. This is a draft...

Feasibility of Estimating Relative Nutrient Contributions of Agriculture and Forests Using MODIS Time Series

NASA Technical Reports Server (NTRS)

Ross, Kenton W.; Gasser, Gerald; Spiering, Bruce

2010-01-01

Around the Gulf of Mexico, high-input crops in several regions make a significant contribution to nutrient loading of small to medium estuaries and to the near-shore Gulf. Some crops cultivated near the coast include sorghum in Texas, rice in Texas and Louisiana, sugarcane in Florida and Louisiana, citrus orchards in Florida, pecan orchards in Mississippi and Alabama, and heavy sod and ornamental production around Mobile and Tampa Bay. In addition to crops, management of timberlands in proximity to the coasts also plays a role in nutrient loading. In the summer of 2008, a feasibility project is planned to explore the use of NASA data to enhance the spatial and temporal resolution of near-coast nutrient source information available to the coastal community. The purpose of this project is to demonstrate the viability of nutrient source information products applicable to small to medium watersheds surrounding the Gulf of Mexico. Conceptually, these products are intended to complement estuarine nutrient monitoring.

Eutrophication threatens Caribbean seagrasses - An example from Curaçao and Bonaire.

PubMed

Govers, Laura L; Lamers, Leon P M; Bouma, Tjeerd J; de Brouwer, Jan H F; van Katwijk, Marieke M

2014-12-15

Seagrass beds are globally declining due to human activities in coastal areas. We here aimed to identify threats from eutrophication to the valuable seagrass beds of Curaçao and Bonaire in the Caribbean, which function as nursery habitats for commercial fish species. We documented surface- and porewater nutrient concentrations, and seagrass nutrient concentrations in 6 bays varying in nutrient loads. Water measurements only provided a momentary snapshot, due to timing, tidal stage, etc., but Thalassia testudinum nutrient concentrations indicated long-term nutrient loads. Nutrient levels in most bays did not raise any concern, but high leaf % P values of Thalassia in Piscadera Bay (∼0.31%) and Spanish Water Bay (∼0.21%) showed that seagrasses may be threatened by eutrophication, due to emergency overflow of waste water and coastal housing. We thus showed that seagrasses may be threatened and measures should be taken to prevent loss of these important nursery areas due to eutrophication. Copyright © 2014 Elsevier Ltd. All rights reserved.

Feasibility of Estimating Relative Nutrient Contributions of Agriculture using MODIS Time Series

NASA Technical Reports Server (NTRS)

Ross, Kenton W.; Gasser, Gerald; Spiering, Bruce

2008-01-01

Around the Gulf of Mexico, high-input crops in several regions make a significant contribution to nutrient loading of small to medium estuaries and to the near-shore Gulf. Some crops cultivated near the coast include sorghum in Texas, rice in Texas and Louisiana, sugarcane in Florida and Louisiana, citrus orchards in Florida, pecan orchards in Mississippi and Alabama, and heavy sod and ornamental production around Mobile and Tampa Bay. In addition to crops, management of timberlands in proximity to the coasts also plays a role in nutrient loading. In the summer of 2008, a feasibility project is planned to explore the use of NASA data to enhance the spatial and temporal resolution of near-coast nutrient source information available to the coastal community. The purpose of this project is to demonstrate the viability of nutrient source information products applicable to small to medium watersheds surrounding the Gulf of Mexico. Conceptually, these products are intended to complement estuarine nutrient monitoring.

Combined effects of global climate change and regional ecosystem drivers on an exploited marine food web.

PubMed

Niiranen, Susa; Yletyinen, Johanna; Tomczak, Maciej T; Blenckner, Thorsten; Hjerne, Olle; Mackenzie, Brian R; Müller-Karulis, Bärbel; Neumann, Thomas; Meier, H E Markus

2013-11-01

Changes in climate, in combination with intensive exploitation of marine resources, have caused large-scale reorganizations in many of the world's marine ecosystems during the past decades. The Baltic Sea in Northern Europe is one of the systems most affected. In addition to being exposed to persistent eutrophication, intensive fishing, and one of the world's fastest rates of warming in the last two decades of the 20th century, accelerated climate change including atmospheric warming and changes in precipitation is projected for this region during the 21st century. Here, we used a new multimodel approach to project how the interaction of climate, nutrient loads, and cod fishing may affect the future of the open Central Baltic Sea food web. Regionally downscaled global climate scenarios were, in combination with three nutrient load scenarios, used to drive an ensemble of three regional biogeochemical models (BGMs). An Ecopath with Ecosim food web model was then forced with the BGM results from different nutrient-climate scenarios in combination with two different cod fishing scenarios. The results showed that regional management is likely to play a major role in determining the future of the Baltic Sea ecosystem. By the end of the 21st century, for example, the combination of intensive cod fishing and high nutrient loads projected a strongly eutrophicated and sprat-dominated ecosystem, whereas low cod fishing in combination with low nutrient loads resulted in a cod-dominated ecosystem with eutrophication levels close to present. Also, nonlinearities were observed in the sensitivity of different trophic groups to nutrient loads or fishing depending on the combination of the two. Finally, many climate variables and species biomasses were projected to levels unseen in the past. Hence, the risk for ecological surprises needs to be addressed, particularly when the results are discussed in the ecosystem-based management context. © 2013 John Wiley & Sons Ltd.

Combined and synergistic effects of climate change and urbanization on water quality in the Wolf Bay watershed, southern Alabama.

PubMed

Wang, Ruoyu; Kalin, Latif

2018-02-01

This study investigated potential changes in flow, total suspended solid (TSS) and nutrient (nitrogen and phosphorous) loadings under future climate change, land use/cover (LULC) change and combined change scenarios in the Wolf Bay watershed, southern Alabama, USA. Four Global Circulation Models (GCMs) under three Special Report Emission Scenarios (SRES) of greenhouse gas were used to assess the future climate change (2016-2040). Three projected LULC maps (2030) were employed to reflect different extents of urbanization in future. The individual, combined and synergistic impacts of LULC and climate change on water quantity/quality were analyzed by the Soil and Water Assessment Tool (SWAT). Under the "climate change only" scenario, monthly distribution and projected variation of TSS are expected to follow a pattern similar to streamflow. Nutrients are influenced both by flow and management practices. The variation of Total Nitrogen (TN) and Total Phosphorous (TP) generally follow the flow trend as well. No evident difference in the N:P ratio was projected. Under the "LULC change only" scenario, TN was projected to decrease, mainly due to the shrinkage of croplands. TP will increase in fall and winter. The N:P ratio shows a strong decreasing potential. Under the "combined change" scenario, LULC and climate change effect were considered simultaneously. Results indicate that if future loadings are expected to increase/decrease under any individual scenario, then the combined change will intensify that trend. Conversely, if their effects are in opposite directions, an offsetting effect occurs. Science-based management practices are needed to reduce nutrient loadings to the Bay. Copyright © 2017. Published by Elsevier B.V.

Nutrient Removal through Oyster Habitat Restoration in the Indian River Lagoon, Florida

NASA Astrophysics Data System (ADS)

Gallagher, S. M.; Schmidt, C. A.; Walters, L.; Blank, R.

2017-12-01

In 2016, an algae bloom in the Indian River Lagoon (IRL) caused a state of emergency in Florida. As with many estuaries, nutrient loading in the IRL has led to periodic eutrophication. While previous studies have shown oyster bed restoration reduces suspended organic matter in estuaries, similar reductions to net nutrient loads are not well established. In addition, previous studies have focused on seasonal variation rather than ongoing yearly effects. Here, we determine the net nitrogen and phosphorus effects of oyster restoration in the IRL over seven years. Analysis of aerial images from 1943 and 2009 showed 14.7 ha of oyster beds were destroyed by boat traffic in the IRL (40% loss). According to our measurements of restored oyster bed sediment, this equates to a maximum of 1,580,000 kg•N•yr-1 of lost denitrification potential; this is equivalent to 150% of estimated current nitrogen loading in the IRL. Oyster restoration began in the IRL in 2007 and has recovered 7.7% of the lost beds and denitrification potential (1.13 ha and 107,000 kg•N•yr-1•ha-1). In all cases, denitrification reached a maximum within two years and remained significantly higher than open sediment for at least the seven years observed. Denitrification benefits came at the cost of mobilizing a maximum of 3450 kg ha-1 of recalcitrant phosphorus from restored bed sediment. This effect was limited to the two years following restoration, whereas increased denitrification was ongoing. Overall, our results show oyster restoration achieved maximum denitrification within two years and maintained significant denitrification benefits for at least seven years. In addition, our results are useful for future oyster restoration projects since they quantify nitrogen benefits in terms of phosphorus mobilization.

A hydrologic network supporting spatially referenced regression modeling in the Chesapeake Bay watershed

USGS Publications Warehouse

Brakebill, J.W.; Preston, S.D.

2003-01-01

The U.S. Geological Survey has developed a methodology for statistically relating nutrient sources and land-surface characteristics to nutrient loads of streams. The methodology is referred to as SPAtially Referenced Regressions On Watershed attributes (SPARROW), and relates measured stream nutrient loads to nutrient sources using nonlinear statistical regression models. A spatially detailed digital hydrologic network of stream reaches, stream-reach characteristics such as mean streamflow, water velocity, reach length, and travel time, and their associated watersheds supports the regression models. This network serves as the primary framework for spatially referencing potential nutrient source information such as atmospheric deposition, septic systems, point-sources, land use, land cover, and agricultural sources and land-surface characteristics such as land use, land cover, average-annual precipitation and temperature, slope, and soil permeability. In the Chesapeake Bay watershed that covers parts of Delaware, Maryland, Pennsylvania, New York, Virginia, West Virginia, and Washington D.C., SPARROW was used to generate models estimating loads of total nitrogen and total phosphorus representing 1987 and 1992 land-surface conditions. The 1987 models used a hydrologic network derived from an enhanced version of the U.S. Environmental Protection Agency's digital River Reach File, and course resolution Digital Elevation Models (DEMs). A new hydrologic network was created to support the 1992 models by generating stream reaches representing surface-water pathways defined by flow direction and flow accumulation algorithms from higher resolution DEMs. On a reach-by-reach basis, stream reach characteristics essential to the modeling were transferred to the newly generated pathways or reaches from the enhanced River Reach File used to support the 1987 models. To complete the new network, watersheds for each reach were generated using the direction of surface-water flow derived from the DEMs. This network improves upon existing digital stream data by increasing the level of spatial detail and providing consistency between the reach locations and topography. The hydrologic network also aids in illustrating the spatial patterns of predicted nutrient loads and sources contributed locally to each stream, and the percentages of nutrient load that reach Chesapeake Bay.

Effect of cyclic and static tensile loading on water content and solute diffusion in canine flexor tendons: an in vitro study.

PubMed

Hannafin, J A; Arnoczky, S P

1994-05-01

This study was designed to determine the effects of various loading conditions (no load and static and cyclic tensile load) on the water content and pattern of nutrient diffusion of canine flexor tendons in vitro. Region D (designated by Okuda et al.) of the flexor digitorum profundus was subjected to a cyclic or static tensile load of 100 g for times ranging from 5 minutes to 24 hours. The results demonstrated a statistically significant loss of water in tendons subjected to both types of load as compared with the controls (no load). This loss appeared to progress with time. However, neither static nor cyclic loading appeared to alter the diffusion of 3H-glucose into the tendon over a 24-hour period compared with the controls. These results suggest that any benefit in tendon repair derived from intermittent passive motion is probably not a result of an increase in the diffusion of small nutrients in response to intermittent tensile load.

Eutrophication of Buttermilk Bay, a cape cod coastal embayment: Concentrations of nutrients and watershed nutrient budgets

NASA Astrophysics Data System (ADS)

Valiela, Ivan; Costa, Joseph E.

1988-07-01

Nutrient concentrations in Buttermilk Bay, a coastal embayment on the northern end of Buzzards Bay, MA, are higher in the nearshore where salinities are lower. This pattern suggests that freshwater sources may contribute significantly to nutrient inputs into Buttermilk Bay. To evaluate the relative importance of the various sources we estimated inputs of nutrients by each major source into the watershed and into the bay itself. Septic systems contributed about 40% of the nitrogen and phosphorus entering the watershed, with precipitation and fertilizer use adding the remainder. Groundwater transported over 85% of the nitrogen and 75% of the phosphorus entering the bay. Most nutrients entering the watershed failed to reach the bay; uptake by forests, soils, denitrification, and adsorption intercepted two-thirds of the nitrogen and nine-tenths of the phosphorus that entered the watershed. The nutrients that did reach the bay most likely originated from subsoil injections into groundwater by septic tanks, plus some leaching of fertilizers. Buttermilk Bay water has relatively low nutrient concentrations, probably because of uptake of nutrients by macrophytes and because of relatively rapid tidal flushing. Annual budgets of nutrients entering the watershed showed a low nitrogen-to-phosphorus ratio of 6, but passage of nutrients through the watershed raised N/P to 23, probably because of adsorption of PO4 during transit. The N/P ratio of water that leaves the watershed and presumably enters the bay is probably high enough to maintain active growth of nitrogenlimited coastal producers. There is a seasonal shift in N/P in the water column of Buttermilk Bay. N/P exceeded the 16∶1 Redfield ratio during midwinter; the remainder of the year N/P fell below 16∶1. This suggests that annual budgets do not provide sufficiently detailed data with which to interpret nutrient-limitation of producers. Further, some idea of water turnover is also needed to evaluate impact of loading rates. Urbanization of watersheds seems to increase loadings to nearshore environments, and to shift the nutrient loadings delivered to coastal waters to relatively high N-to-P ratios, potentially stimulating growth of nitrogen-limited primary producers.

Resilience of Floating Treatment Wetlands to Repeated Freeze-Thaw Cycles

NASA Astrophysics Data System (ADS)

Ortega, K.; Marchetto, P.; Magner, J.

2017-12-01

Floating treatment wetlands (FTWs), made of a matrix of recycled polyethylene terephthalate (PET) fibers, are currently being used as a method to reduce nutrient loading in lakes. The matrix encourages growth of biofilms, which uptake nutrients from the water. However, the usefulness of FTWs has only been assessed in areas where the lakes do not freeze over in the winter. Repeated freeze-thaw cycles were run on sections of the FTWs in a laboratory setting in order to test the resilience of the PET fibers over the FTWs' advertised fifteen-year lifespan. Preliminary findings suggest that the stresses caused by freezing and thawing of the surrounding water contribute to deterioration of the PET fibers, leading to production of microplastics. Estimations indicate that approximately 0.063% of a FTW's mass could be lost as microplastics over the course of its lifespan. Production of microplastics contributes to plastic pollution in the treatment water, possibly offsetting any nutrient remediation the FTWs perform.

ENERGY AND NUTRIENT EXTRACTION FROM ONSITE WASTEWATER - PHASE I

EPA Science Inventory

Onsite wastewater systems are a significant source of nutrient loading to the environment and there is a demand for technologies that remove nutrients at the source. Most desired are passive, low-...

ROLE OF OCEANIC AND RIVERINE SOURCES IN NUTRIENT AND PHYTOPLANKTON DYNAMICS IN YAQUINA BAY, OREGON

EPA Science Inventory

There is evidence that coastal ecosystems are experiencing environmental problems due to excess nutrients. The numerous sources, forms, and pathways of nutrients make it difficult to determine the effect of increases in anthropogenic loading. This is particularly evident in Pac...

Phytoplankton biomass and composition in a well-flushed, sub-tropical estuary: The contrasting effects of hydrology, nutrient loads and allochthonous influences.

PubMed

Hart, J A; Phlips, E J; Badylak, S; Dix, N; Petrinec, K; Mathews, A L; Green, W; Srifa, A

2015-12-01

The primary objective of this study was to examine trends in phytoplankton biomass and species composition under varying nutrient load and hydrologic regimes in the Guana Tolomato Matanzas estuary (GTM), a well-flushed sub-tropical estuary located on the northeast coast of Florida. The GTM contains both regions of significant human influence and pristine areas with only modest development, providing a test case for comparing and contrasting phytoplankton community dynamics under varying degrees of nutrient load. Water temperature, salinity, Secchi disk depth, nutrient concentrations and chlorophyll concentrations were determined on a monthly basis from 2002 to 2012 at three representative sampling sites in the GTM. In addition, microscopic analyses of phytoplankton assemblages were carried out monthly for a five year period from 2005 through 2009 at all three sites. Results of this study indicate that phytoplankton biomass and composition in the GTM are strongly influenced by hydrologic factors, such as water residence times and tidal exchanges of coastal waters, which in turn are affected by shifts in climatic conditions, most prominently rainfall levels. These influences are exemplified by the observation that the region of the GTM with the longest water residence times but lowest nutrient loads exhibited the highest phytoplankton peaks of autochthonous origin. The incursion of a coastal bloom of the toxic dinoflagellate Karenia brevis into the GTM in 2007 demonstrates the potential importance of allochthonous influences on the ecosystem. Copyright © 2015 Elsevier Ltd. All rights reserved.

What is the role of fresh groundwater and recirculated seawater in conveying nutrients to the coastal ocean?

USGS Publications Warehouse

Weinstein, Y.; Yechieli, Y.; Shalem, Y.; Burnett, W.C.; Swarzenski, P.W.; Herut, B.

2011-01-01

Submarine groundwater discharge (SGD) is a major process operating at the land-sea interface. Quantifying the SGD nutrient loads and the marine/terrestrial controls of this transport is of high importance, especially in oligotrophic seas such as the eastern Mediterranean. The fluxes of nutrients in groundwater discharging from the seafloor at Dor Bay (southeastern Mediterranean) were studied in detail using seepage meters. Our main finding is that the terrestrial, fresh groundwater is the main conveyor of DIN and silica to the coastal water, with loads of 500 and 560 mol/yr, respectively, per 1 m shoreline. Conversely, recirculated seawater is nutrient-poor, and its role is mainly as a dilution agent. The nutrient loads regenerated in the subterranean estuary (sub-bay sediment) are relatively small, consisting mostly of ammonium (24 mol/yr). On the other hand, the subterranean estuary at Dor Bay sequesters as much as 100 mol N/yr per 1 m shoreline, mainly via denitrification processes. These, and observations from other SGD sites, imply that the subterranean estuary at some coastal systems may function more as a sink for nitrogen than a source. This further questions the extent of nutrient contributions to the coastal water by some subterranean estuaries and warrants systematic evaluation of this process in various hydrological and marine trophic conditions. ?? 2011 American Chemical Society.

Characterizing the Fate and Mobility of Phosphorus in Utah Lake Sediments

NASA Astrophysics Data System (ADS)

Randall, M.; Carling, G. T.; Nelson, S.; Bickmore, B.; Miller, T.

2016-12-01

An increasing number of lakes worldwide are impacted by eutrophication and harmful algal blooms due to nutrient inputs. Utah Lake, located in northern Utah, is a eutrophic freshwater lake that is unique because it is naturally shallow, turbid, and alkaline with high dissolved oxygen levels. Recently, the Utah Division of Water Quality has proposed a new rule to limit phosphorus (P) loading to Utah Lake from wastewater treatment plants in an effort to mitigate eutrophication. However, reducing external P loads may not lead to immediate improvements in water quality due to the legacy pool of nutrients in lake sediments. The purpose of this study is to characterize the fate and mobility of P in Utah Lake to better understand P cycling in this unique system. We analyzed P speciation, mineralogy, and binding capacity in lake sediment samples collected from 9 locations across Utah Lake. P concentrations in sediment ranged from 1120 to 1610 ppm, with highest concentrations in Provo Bay near the major metropolitan area. Likewise, P concentrations in sediment pore water were highest in Provo Bay with concentrations up to 4 mg/L. Sequential leach tests indicate that 30-45% of P is bound to apatite and another 40-55% is adsorbed onto the surface of redox sensitive Fe/Mn hydroxides. This was confirmed by SEM images, which showed the highest P concentrations correlating with both Ca (apatite) and Fe (Fe hydroxides). The apatite-bound P fraction is likely immobile, but the P fraction sorbed to Fe/Mn hydroxides is potentially bioavailable under changing redox conditions. Batch sorption results indicate that lake sediments have a high capacity to absorb and remove P from the water column, with an average uptake of 70-96% of P from spiked surface water with concentrations ranging from 1-10 mg/L. Mineral precipitation and sorption to bottom sediments is an efficient removal mechanism of P in Utah Lake, but a significant portion of P may be available for resuspension and cycling in surface waters. Mitigating lake eutrophication is a complex problem that goes beyond reducing nutrient loads to the water body and requires a better understanding of internal P cycling.

External nutrient sources, internal nutrient pools, and phytoplankton production in Chesapeake Bay

DOE Office of Scientific and Technical Information (OSTI.GOV)

Magnien, R.E.; Summers, R.M.; Sellner, K.G.

1992-12-01

External nutrient loadings, internal nutrient pools, and phytoplankton production were examined for three major subsystems of the Chesapeake Bay Estuary-the upper Mainstem, the Patuxent Estuary, and the Potomac Estuary-during 1985-1989. The atomic nitrogen to phosphorus ratios (TN:TP) of total loads were 51, 29 and 35, respectively. Most of these loads entered at the head of the estuaries from riverine sources and major wastewater treatment plants. Seven-16% of the nitrogen load entered the head of each estuary as particulate matter in contrast to 48-69% for phosphorus. The difference seems to favor a greater loss of phosphorus than nitrogen through sedimentation andmore » burial. A major storm event in the Potomac watershed greatly increased the particulate fraction of nitrogen and phosphorus and lowered the TN:TP in the river-borne loads and accounted for 11% of the nitrogen and 31% of the phosphorus delivered to the estuary by the Potomac River during the entire 60- month period examined here. Within the Mainstem estuary, salinity dilution plots revealed strong net sources of ammonium and phosphate in the oligohaline to upper mesohaline region. indicating considerable internal recycling of nutrients to surface waters. A net sink of nitrate was indicated during summer. Phytoplankton biomass in the mesohaline Mainstem reached a peak in spring and was relatively constant throughout the other seasons. In the Patuxent and Potomac, the TN:TP ratios of external loads are 2-4 times higher than those observed over the previous two decades. These changes are attributed to point-source phosphorus controls and the likelihood that nitrogen-rich nonpoint source inputs, including contributions from the atmosphere, have increased. These higher N:P ratios now suggest a greater overall potential for phosphorus-limitation rather than nitrogen-limitation of phytoplankton in the areas studied. 66 refs., 6 figs., 7 tabs.« less

Relation of water quality to land use in the drainage basins of six tributaries to the lower Delaware River, New Jersey, 2002-07

USGS Publications Warehouse

Baker, Ronald J.; Esralew, Rachel A.

2010-01-01

Concentrations and loads of water-quality constituents in six streams in the lower Delaware River Basin of New Jersey were determined in a multi-year study conducted by the U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection. Two streams receive water from relatively undeveloped basins, two from largely agricultural basins, and two from heavily urbanized basins. Each stream was monitored during eight storms and at least eight times during base flow during 2002-07. Sampling was conducted during base flow before each storm, when stage was first observed to rise, and several times during the rising limb of the hydrographs. Agricultural and urban land use has resulted in statistically significant increases in loads of nitrogen and phosphorus species relative to loads in undeveloped basins. For example, during the growing season, median storm flow concentrations of total nitrogen in the two streams in agricultural areas were 6,290 and 1,760 mg/L, compared to 988 and 823 mg/L for streams in urban areas, and 719 and 333 mg/L in undeveloped areas. Although nutrient concentrations and loads were clearly related to land useurban, agricultural, and undeveloped within the drainage basins, other basin characteristics were found to be important. Residual nutrients entrapped in lake sediments from streams that received effluent from recently removed sewage-treatment plants are hypothesized to be the cause of extremely high levels of nutrient loads to one urban stream, whereas another urban stream with similar land-use percentages (but without the legacy of sewage-treatment plants) had much lower levels of nutrients. One of the two agricultural streams studied had higher nutrient loads than the other, especially for total phosphorous and organic nitrogen. This difference appears to be related to the presence (or absence) of livestock (cattle).

Assessment of the Spatial and Temporal Variations of Water Quality for Agricultural Lands with Crop Rotation in China by Using a HYPE Model

PubMed Central

Yin, Yunxing; Jiang, Sanyuan; Pers, Charlotta; Yang, Xiaoying; Liu, Qun; Yuan, Jin; Yao, Mingxing; He, Yi; Luo, Xingzhang; Zheng, Zheng

2016-01-01

Many water quality models have been successfully used worldwide to predict nutrient losses from anthropogenically impacted catchments, but hydrological and nutrient simulations with limited data are difficult considering the transfer of model parameters and complication of model calibration and validation. This study aims: (i) to assess the performance capabilities of a new and relatively more advantageous model, namely, Hydrological Predictions for the Environment (HYPE), that simulates stream flow and nutrient load in agricultural areas by using a multi-site and multi-objective parameter calibration method and (ii) to investigate the temporal and spatial variations of total nitrogen (TN) and total phosphorous (TP) concentrations and loads with crop rotation by using the model for the first time. A parameter estimation tool (PEST) was used to calibrate parameters. Results show that the parameters related to the effective soil porosity were highly sensitive to hydrological modeling. N balance was largely controlled by soil denitrification processes. P balance was influenced by the sedimentation rate and production/decay of P in rivers and lakes. The model reproduced the temporal and spatial variations of discharge and TN/TP relatively well in both calibration (2006–2008) and validation (2009–2010) periods. Among the obtained data, the lowest Nash-Suttclife efficiency of discharge, daily TN load, and daily TP load were 0.74, 0.51, and 0.54, respectively. The seasonal variations of daily TN concentrations in the entire simulation period were insufficient, indicated that crop rotation changed the timing and amount of N output. Monthly TN and TP simulation yields revealed that nutrient outputs were abundant in summer in terms of the corresponding discharge. The area-weighted TN and TP load annual yields in five years showed that nutrient loads were extremely high along Hong and Ru rivers, especially in agricultural lands. PMID:26999184

Effects of agricultural nutrient management on nitrogen fate and transport in Lancaster County, Pennsylvania

USGS Publications Warehouse

Hall, D.W.; Risser, D.W.

1993-01-01

Nitrogen inputs to, and outputs from, a 55-acre site in Lancaster County, Pennsylvania, were estimated to determine the pathways and relative magnitude of loads of nitrogen entering and leaving the site, and to compare the loads of nitrogen before and after the implementation of nutrient management. Inputs of nitrogen to the site were manure fertilizer, commercial fertilizer, nitrogen in precipitation, and nitrogen in ground-water inflow; and these sources averaged 93, 4, 2, and 1 percent of average annual nitrogen additions, respectively. Outputs of nitrogen from the site were nitrogen in harvested crops, loads of nitrogen in surface runoff, volatilization of nitrogen, and loads of nitrogen in ground-water discharge, which averaged 37, less than 1,25, and 38 percent of average annual nitrogen removals from the site, respectively. Virtually all of the nitrogen leaving the site that was not removed in harvested crops or by volatilization was discharged in the ground water. Applications of manure and fertilizer nitrogen to 47.5 acres of cropped fields decreased about 33 percent, from an average of 22,700 pounds per year (480 pounds per acre per year) before nutrient management to 15,175 pounds of nitrogen per year (320 pounds per acre per year) after the implementation of nutrient management practices. Nitrogen loads in ground-water discharged from the site decreased about 30 percent, from an average of 292 pounds of nitrogen per million gallons of ground water before nutrient management to an average of 203 pounds of nitrogen per million gallons as a result of the decreased manure and commercial fertilizer applications. Reductions in manure and commercial fertilizer applications caused a reduction of approximately 11,000 pounds (3,760 pounds per year, 70 pounds per acre per year) in the load of nitrogen discharged in ground water from the 55-acre site during the three-year period 1987-1990.

Broiler Litter × Industrial By-Products Reduce Nutrients and Microbial Losses in Surface Runoff When Applied to Forages.

PubMed

Adeli, Ardeshir; Read, John J; Brooks, John P; Miles, Dana; Feng, Gary; Jenkins, Johnie N

2017-03-01

The inability to incorporate broiler litter (BL) into permanent hayfields and pastures leads to nutrient accumulation near the soil surface and increases the potential transport of nutrients in runoff. This study was conducted on Marietta silt loam soil to determine the effect of flue gas desulfurization (FGD) gypsum and lignite on P, N, C, and microbial concentrations in runoff. Treatments were (i) control (unfertilized) and (ii) BL at 13.4 Mg ha alone or (iii) treated with either FGD gypsum or lignite applied at 20% (w/w) (2.68 Mg ha). Rainfall simulators were used to produce a 5.6 cm h storm event sufficient in duration to cause 15 min of continuous runoff. Repeated rains were applied at 3-d intervals to determine how long FGD gypsum and lignite are effective in reducing loss of litter-derived N, P, and C from soil. Application of BL increased N, P, and C concentrations in runoff as compared to the control. Addition of FGD gypsum reduced ( < 0.05) water-soluble P and dissolved organic C concentrations in runoff by 39 and 16%, respectively, as compared to BL alone. Lignite reduced runoff total N and NH-N concentrations by 38 and 70%, respectively, as compared to BL alone. Addition of FGD gypsum or lignite failed to significantly reduce microbial loads in runoff, although both treatments reduced microbial concentration by >20%. Thus, BL treated with FGD and lignite can be considered as cost-effective management practices in the mitigation of P, N, and C and possibly microbial concentration in runoff. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Elucidating the impacts of initial supersaturation and seed crystal loading on struvite precipitation kinetics, fines production, and crystal growth.

PubMed

Agrawal, Shantanu; Guest, Jeremy S; Cusick, Roland D

2018-04-01

To reduce intra-plant nutrient cycling, and recover phosphorus (P) fertilizers from nutrient-rich sidestreams, wastewater utilities increasingly elect to employ struvite precipitation processes without a clear understanding of the inherent tradeoffs associated with specific design and operating decisions. Specifically, the impact of reactor conditions on struvite crystallization rate, and distribution between formation of fines particles and secondary growth onto large diameter seed crystals represent critical knowledge gaps limiting the predictive capabilities of existing process models. In this work, the relative impacts of initial supersaturation (S i ), and seed loading, on P removal kinetics, and struvite solids distribution were investigated. In experiments conducted at different levels of initial supersaturation (1.7-2.4) and seed loading (0-25 g L -1 ), struvite fines represented the majority of phosphate solids formed in 10 of 12 conditions. While total P removal was dependent on S i , and primarily attributed to formation of fines, the concentration of struvite seed granules had a significant impact on the rate of P removal. Struvite seed granules increased the rate of precipitation by reducing induction time of primary nucleation of struvite fines. Secondary crystal growth represented the majority of struvite solids formed at high seed loading and low S i , but presented the tradeoff of low total removal and low rate of removal. To convey the significance of these findings on process modeling, we show how a prominent kinetic model with a first-order dependency on solid struvite concentration over-predicts P removal rate when total mass is dominated by large diameter seeds (0.9 mm). This works reveals the critical role of struvite fines in P removal, and highlights the need to account for their production and kinetic importance in struvite process design and operation. Copyright © 2018 Elsevier Ltd. All rights reserved.

A comparison of additional treatment processes to limit particle accumulation and microbial growth during drinking water distribution.

PubMed

Liu, G; Lut, M C; Verberk, J Q J C; Van Dijk, J C

2013-05-15

Water quality changes, particle accumulation and microbial growth occurring in pilot-scale water distribution systems fed with normally treated and additional treated groundwater were monitored over a period of almost one year. The treatment processes were ranked in the following order: nanofiltration (NF) > (better than) ultrafiltration (UF) > ion exchange (IEX) for limiting particle accumulation. A different order was found for limiting overall microbial growth: NF > IEX > UF. There were strong correlations between particle load and particle accumulation, and between nutrient load and microbial growth. It was concluded that particle accumulation can be controlled by reducing the particle load in water treatment plants; and the microbial growth can be better controlled by limiting organic nutrients rather than removing biomass in water treatment plants. The major focus of this study was on microbial growth. The results demonstrated that growth occurred in all types of treated water, including the phases of bulk water, biofilm and loose deposits. Considering the growth in different phases, similar growth in bulk water was observed for all treatments; NF strongly reduced growth both in loose deposits and in biofilm; UF promoted growth in biofilm, while strongly limiting growth in loose deposits. IEX had good efficiency in between UF and NF, limiting both growths in loose deposits and in biofilm. Significant growth was found in loose deposits, suggesting that loose deposit biomass should be taken into account for growth evaluation and/or prediction. Strong correlations were found between microbial growth and pressure drop in a membrane fouling simulator which proved that a membrane fouling simulator can be a fast growth predictor (within a week). Different results obtained by adenosine triphosphate and flow cytometry cell counts revealed that ATP can accurately describe both suspended and particle-associated biomass, and flow cytometry files of TCC measurements needs to be further processed for particle loaded samples and/or a pretreatment protocol should be developed. Copyright © 2013 Elsevier Ltd. All rights reserved.

Agricultural and urban pollution

NASA Technical Reports Server (NTRS)

Brehmer, M. L.

1972-01-01

The degradation produced by the introduction of agricultural and urban wastes into estuarine systems, with emphasis on the Chesapeake Bay area, is discussed. The subjects presented are: (1) effects of sediment loading and (2) organic and nutrient loading problems. The impact of high turbidity on the biological life of the bay is analyzed. The sources of nutrients which produce over-enrichment of the waters and the subsequent production of phytoplankton are examined.

Nutrients, Select Pesticides, and Suspended Sediment in the Karst Terrane of the Sinking Creek Basin, Kentucky, 2004-06

USGS Publications Warehouse

Crain, Angela S.

2010-01-01

This report presents the results of a study by the U.S. Geological Survey, in cooperation with the Kentucky Department of Agriculture, on nutrients, select pesticides, and suspended sediment in the karst terrane of the Sinking Creek Basin. Streamflow, nutrient, select pesticide, and suspended-sediment data were collected at seven sampling stations from 2004 through 2006. Concentrations of nitrite plus nitrate ranged from 0.21 to 4.9 milligrams per liter (mg/L) at the seven stations. The median concentration of nitrite plus nitrate for all stations sampled was 1.6 mg/L. Total phosphorus concentrations were greater than 0.1 mg/L, the U.S. Environmental Protection Agency's recommended maximum concentration, in 45 percent of the samples. Concentrations of orthophosphates ranged from less than 0.006 to 0.46 mg/L. Concentrations of nutrients generally were larger during spring and summer months, corresponding to periods of increased fertilizer application on agricultural lands. Concentrations of suspended sediment ranged from 1.0 to 1,490 mg/L at the seven stations. Of the 47 pesticides analyzed, 14 were detected above the adjusted method reporting level of 0.01 micrograms per liter (mug/L). Although these pesticides were detected in water-quality samples, they generally were found at less than part-per-billion concentrations. Atrazine was the only pesticide detected at concentrations greater than U.S. Environmental Protection Agency drinking water standard of 3 mug/L, and the maximum detected concentration was 24.6 mug/L. Loads and yields of nutrients, selected pesticides, and suspended sediment were estimated at two mainstream stations on Sinking Creek, a headwater station (Sinking Creek at Rosetta) and a station at the basin outlet (Sinking Creek near Lodiburg). Mean daily streamflow data were available for the estimation of loads and yields from a stream gage at the basin outlet station; however, only periodic instantaneous flow measurements were available for the headwaters station; mean daily flows at the headwater station were, therefore, estimated using a mathematical record-extension technique known as the Maintenance of Variance-Extension, type 1 (MOVE.1). The estimation of mean daily streamflows introduced a large amount of uncertainty into the loads and yields estimates at the headwater station. Total estimated loads of select (five most commonly detected) pesticides from the Sinking Creek Basin were about 0.01 to 1.2 percent of the estimated application, indicating pesticides possibly are retained within the watershed. Mean annual loads [(in/lb)/yr] for nutrients and suspended sediment were estimated at the two Sinking Creek mainstem sampling stations. The relation between estimated and measured instantaneous loads of nitrite plus nitrate at the Sinking Creek near Lodiburg station indicate a reasonably tight distribution over the range of loads. The model for loads of nitrite plus nitrate at the Sinking Creek at Rosetta station indicates small loads were overestimated and underestimated. Relations between estimated and measured loads of total phosphorus and orthophosphate at both Sinking Creek mainstem stations showed similar patterns to the loads of nitrite plus nitrate at each respective station. The estimated mean annual load of suspended sediment is about 14 times larger at the Sinking Creek near Lodiburg station than at the Sinking Creek near Rosetta station. Estimated yields of nutrients and suspended sediment increased from the headwater to downstream monitoring stations on Sinking Creek. This finding suggests that sources of nutrients and suspended sediment are not evenly distributed throughout the karst terrane of the Sinking Creek Basin. Yields of select pesticides generally were similar from the headwater to downstream monitoring stations. However, the estimated yield of atrazine was about five times higher at the downstream station on Sinking Creek than at the headwater station on Sinking Creek.

Nutrient attenuation in rivers and streams, Puget Sound Basin, Washington

USGS Publications Warehouse

Sheibley, Rich W.; Konrad, Christopher P.; Black, Robert W.

2015-01-01

From a management perspective, preservation and improvement of instream nutrient attenuation should focus on increasing the travel time through a reach and contact time of water sediment (reactive) surfaces and lowering nutrient concentrations (and loads) to avoid saturation of instream attenuation and increase attenuation efficiency. These goals can be reached by maintaining and restoring channel-flood plain connectivity, maintaining and restoring healthy riparian zones along streams, managing point and nonpoint nutrient loads to streams and rivers, and restoring channel features that promote attenuation such as the addition of woody debris and maintaining pool-riffle morphologies. Many of these management approaches are already being undertaken during projects aimed to restore quality salmon habitat. Therefore, there is a dual benefit to these projects that also may lead to enhanced potential for nitrogen and phosphorus attenuation.

Nutrient mitigation in a temporary river basin.

PubMed

Tzoraki, Ourania; Nikolaidis, Nikolaos P; Cooper, David; Kassotaki, Elissavet

2014-04-01

We estimate the nutrient budget in a temporary Mediterranean river basin. We use field monitoring and modelling tools to estimate nutrient sources and transfer in both high and low flow conditions. Inverse modelling by the help of PHREEQC model validated the hypothesis of a losing stream during the dry period. Soil and Water Assessment Tool model captured the water quality of the basin. The 'total daily maximum load' approach is used to estimate the nutrient flux status by flow class, indicating that almost 60% of the river network fails to meet nitrogen criteria and 50% phosphate criteria. We recommend that existing well-documented remediation measures such as reforestation of the riparian area or composting of food process biosolids should be implemented to achieve load reduction in close conjunction with social needs.

EPISODIC EVENTS: THE EFFECT OF FLOODS ON NUTRIENT TRANSPORT IN A NORTHWESTERN, USA ESTUARY

EPA Science Inventory

To estimate the effects of storms on nutrient transport, dissolved nutrients and suspended sediment loads were measured relative to stream discharge in the Yaquina River, OR for three storm events. Episodic events, particularly high rainfall or flood events may transport high di...

Evaluation of existing and modified wetland equations in the SWAT model

USDA-ARS?s Scientific Manuscript database

The drainage significantly alters flow and nutrient pathways in small watersheds and reliable simulation at this scale is needed for effective planning of nutrient reduction strategies. The Soil and Water Assessment Tool (SWAT) has been widely utilized for prediction of flow and nutrient loads, but...

WETLAND MORPHOLOGIC AND BIOGEOGRAPHIC INFLUENCES ON ALGAL RESPONSES TO NUTRIENT LOADING IN GREAT LAKES COASTAL WETLANDS

EPA Science Inventory

We are testing the influence of wetland morphology (protected vs. riverine) and biogeography (upper vs. lower Great Lakes) on algal responses to nutrients in Great Lakes Coastal wetlands. Principal components analysis using nutrient-specific GIS data was used to select sites wit...

Spatial optimization of cropping pattern for sustainable food and biofuel production with minimal downstream pollution.

PubMed

Femeena, P V; Sudheer, K P; Cibin, R; Chaubey, I

2018-04-15

Biofuel has emerged as a substantial source of energy in many countries. In order to avoid the 'food versus fuel competition', arising from grain-based ethanol production, the United States has passed regulations that require second generation or cellulosic biofeedstocks to be used for majority of the biofuel production by 2022. Agricultural residue, such as corn stover, is currently the largest source of cellulosic feedstock. However, increased harvesting of crops residue may lead to increased application of fertilizers in order to recover the soil nutrients lost from the residue removal. Alternatively, introduction of less-fertilizer intensive perennial grasses such as switchgrass (Panicum virgatum L.) and Miscanthus (Miscanthus x giganteus Greef et Deu.) can be a viable source for biofuel production. Even though these grasses are shown to reduce nutrient loads to a great extent, high production cost have constrained their wide adoptability to be used as a viable feedstock. Nonetheless, there is an opportunity to optimize feedstock production to meet bioenergy demand while improving water quality. This study presents a multi-objective simulation optimization framework using Soil and Water Assessment Tool (SWAT) and Multi Algorithm Genetically Adaptive Method (AMALGAM) to develop optimal cropping pattern with minimum nutrient delivery and minimum biomass production cost. Computational time required for optimization was significantly reduced by loose coupling SWAT with an external in-stream solute transport model. Optimization was constrained by food security and biofuel production targets that ensured not more than 10% reduction in grain yield and at least 100 million gallons of ethanol production. A case study was carried out in St. Joseph River Watershed that covers 280,000 ha area in the Midwest U.S. Results of the study indicated that introduction of corn stover removal and perennial grass production reduce nitrate and total phosphorus loads without compromising on food and biofuel production. Optimization runs yielded an optimal cropping pattern with 32% of watershed area in stover removal, 15% in switchgrass and 2% in Miscanthus. The optimal scenario resulted in 14% reduction in nitrate and 22% reduction in total phosphorus from the baseline. This framework can be used as an effective tool to take decisions regarding environmentally and economically sustainable strategies to minimize the nutrient delivery at minimal biomass production cost, while simultaneously meeting food and biofuel production targets. Copyright © 2018 Elsevier Ltd. All rights reserved.

Factors influencing the nitrification efficiency of fluidized bed filter with a plastic bead medium

USGS Publications Warehouse

Sandu, S.I.; Boardman, G.D.; Watten, B.J.; Brazil, B.L.

2002-01-01

The performance of fluidized bed nitrification filters charged with 2 ?? 4 ABS plastic beads (specific gravity 1.06) was evaluated. Three unique bed-height to diameter ratios were established, in triplicate, using column diameters of 12.7, 15.2 and 17.8 cm. Filters received water spiked with recycled nutrients and ammonia (TAN), from one of the three 500 1 feed tank system. With daily ammonia loading fixed at 8.6 g per system, TAN removal increased with column diameter at each of four tests hydraulic loading rates (6, 8, 10 and 12 Lpm). TAN in recirculated water (influent) rose from 0.5 to 1.0 mg/1 as ammonia loading increased from 180 mg/m2-day to 360 mg/m2-day. When hydraulic loading was fixed at 12 Lpm, TAN removal (%) was maximized with ammonia loadings ranging from 225 to 270 mg/m2-day. Biofilm thickness increased with ammonia loading, but decreased with increased hydraulic loading rates. Fluidized beds of ABS plastic beads were effective in reducing energy costs (head loss) of water treatment. ?? 2002 Elsevier Science B.V. All rights reserved.

Response of Polish rivers (Vistula, Oder) to reduced pressure from point sources and agriculture during the transition period (1988-2008)

NASA Astrophysics Data System (ADS)

Pastuszak, Marianna; Stålnacke, Per; Pawlikowski, Krzysztof; Witek, Zbigniew

2012-06-01

The Vistula and Oder Rivers, two out of the seven largest rivers in the Baltic drainage basin, were responsible for 25% of total riverine nitrogen (TN) and 37% of total riverine phosphorus (TP) input to the Baltic Sea in 2000. The aim of this paper is to evaluate the response of these two rivers to changes that took place in Polish economy during the transition period (1988-2008). The economic changes encompassed: construction of nearly 900 waste water treatment plants in 1999-2008, modernization or closure of obsolete factories, economizing in water consumption, closure or change of ownership of State-owned farms, a drop in fertilizer application, and a decline in livestock stocking. More intensive agriculture and higher point source emissions in the Oder than in the Vistula basin resulted in higher concentrations of TN, nitrate (NO3-N), and TP in the Oder waters in the entire period of our studies. In both rivers, nutrient concentrations and loads showed significant declining trends in the period 1988-2008. TN loads decreased by ca. 20% and 25% in the Vistula and Oder; TP loads dropped by ca. 15% and 65% in the Vistula and Oder. The reduction in phosphorus loads was particularly pronounced in the Oder basin, which was characterized by efficient management systems aiming at mitigation of nutrient emission from the point sources and greater extent of structural changes in agricultural sector during the transition period. The trends in riverine loads are discussed in the paper in relation to socio-economical changes during the transition period, and with respect to physiographic features.

Factors Affecting Nitrate Delivery to Streams from Shallow Ground Water in the North Carolina Coastal Plain

USGS Publications Warehouse

Harden, Stephen L.; Spruill, Timothy B.

2008-01-01

An analysis of data collected at five flow-path study sites between 1997 and 2006 was performed to identify the factors needed to formulate a comprehensive program, with a focus on nitrogen, for protecting ground water and surface water in the North Carolina Coastal Plain. Water-quality protection in the Coastal Plain requires the identification of factors that affect the transport of nutrients from recharge areas to streams through the shallow ground-water system. Some basins process or retain nitrogen more readily than others, and the factors that affect nitrogen processing and retention were the focus of this investigation to improve nutrient management in Coastal Plain streams and to reduce nutrient loads to coastal waters. Nitrate reduction in ground water was observed at all five flow-path study sites in the North Carolina Coastal Plain, although the extent of reduction at each site was influenced by various environmental, hydrogeologic, and geochemical factors. Denitrification was the most common factor responsible for decreases in nitrate along the ground-water flow paths. Specific factors, some of which affect denitrification rates, that appeared to influence ground-water nitrate concentrations along the flow paths or in the streams include soil drainage, presence or absence of riparian buffers, evapotranspiration, fertilizer use, ground-water recharge rates and residence times, aquifer properties, subsurface tile drainage, sources and amounts of organic matter, and hyporheic processes. The study data indicate that the nitrate-reducing capacity of the buffer zone combined with that of the hyporheic zone can substantially lower the amount of ground-water nitrate discharged to streams in agricultural settings of the North Carolina Coastal Plain. At the watershed scale, the effects of ground-water discharge on surface-water quality appear to be greatly influenced by streamflow conditions and the presence of extensive riparian vegetation. Streamflow statistics that reflect base flow and the general hydrologic dynamics of a stream are important in understanding nutrient transport from a watershed and may be useful indicators of watersheds that are likely to have higher yields of nutrients and water. Combining streamflow statistics with information on such factors as land use, soil drainage, extent of riparian vegetation, geochemical conditions, and subsurface tile drainage in the Coastal Plain can be useful in identifying watersheds that are most likely to export excessive nitrogen due to nonpoint-source loadings and watersheds that are effective in processing nitrogen.

Microstructural and associated chemical changes during the composting of a high temperature biochar: Mechanisms for nitrate, phosphate and other nutrient retention and release.

PubMed

Joseph, Stephen; Kammann, Claudia I; Shepherd, Jessica G; Conte, Pellegrino; Schmidt, Hans-Peter; Hagemann, Nikolas; Rich, Anne M; Marjo, Christopher E; Allen, Jessica; Munroe, Paul; Mitchell, David R G; Donne, Scott; Spokas, Kurt; Graber, Ellen R

2018-03-15

Recent studies have demonstrated the importance of the nutrient status of biochar and soils prior to its inclusion in particular agricultural systems. Pre-treatment of nutrient-reactive biochar, where nutrients are loaded into pores and onto surfaces, gives improved yield outcomes compared to untreated biochar. In this study we have used a wide selection of spectroscopic and microscopic techniques to investigate the mechanisms of nutrient retention in a high temperature wood biochar, which had negative effects on Chenopodium quinoa above ground biomass yield when applied to the system without prior nutrient loading, but positive effects when applied after composting. We have compared non-composted biochar (BC) with composted biochar (BCC) to elucidate the differences which may have led to these results. The results of our investigation provide evidence for a complex series of reactions during composting, where dissolved nutrients are first taken up into biochar pores along a concentration gradient and through capillary action, followed by surface sorption and retention processes which block biochar pores and result in deposition of a nutrient-rich organomineral (plaque) layer. The lack of such pretreatment in the BC samples would render it reactive towards nutrients in a soil-fertilizer system, making it a competitor for, rather than provider of, nutrients for plant growth. Copyright © 2017 Elsevier B.V. All rights reserved.

[Research on land use structure optimization based on nonpoint source dissolved nitrogen load estimation in Shuaishui watershed].

PubMed

Lu, Yu-Chao; Bi, Meng-Fei; Li, Ze-Li; Sha, Jian; Wang, Yu-Qiu; Qian, Li-Ping

2014-06-01

Regional Nutrient Management (ReNuMa) was applied to estimate dissolved nitrogen (DN) load and perform source apportionment in Shuaishui watershed during 2000-2010. Satisfactory performance of ReNuMa was revealed by the E(ns) and R2 of greater than 0.9 in calibrating and validating streamflow and DN. The average nonpoint DN load in this watershed was 1.11 x 10(3) t x a(-1), with the load intensity of (0.75 +/- 0.22) t x km(-2). Among all the land uses, paddy field had the largest DN load intensity [28.60 kg x (hm2 x a)(-1)], while forest had the least [2.71 kg x (hm2 x a)(-1)]. Agricultural land (including paddy, grain, cash crop, tea plant and orchard) contributed most to DN load in Shuaishui watershed, indicating that the human dominated agricultural activities was the major contributor of nonpoint source pollution. Land use structure optimization for Shuaishui watershed in 2015 was conducted under the rule of reducing pollutants loads and maximizing the agricultural output value. The results demonstrated that agricultural monetary growth was accompanied with the increasing DN load at the optimal level, although output increment was higher than that of DN load.

Biological nutrient removal by internal circulation upflow sludge blanket reactor after landfill leachate pretreatment.

PubMed

Abood, Alkhafaji R; Bao, Jianguo; Abudi, Zaidun N

2013-10-01

The removal of biological nutrient from mature landfill leachate with a high nitrogen load by an internal circulation upflow sludge blanket (ICUSB) reactor was studied. The reactor is a set of anaerobic-anoxic-aerobic (A2/O) bioreactors, developed on the basis of an expended granular sludge blanket (EGSB), granular sequencing batch reactor (GSBR) and intermittent cycle extended aeration system (ICEAS). Leachate was subjected to stripping by agitation process and poly ferric sulfate coagulation as a pretreatment process, in order to reduce both ammonia toxicity to microorganisms and the organic contents. The reactor was operated under three different operating systems, consisting of recycling sludge with air (A2/O), recycling sludge without air (low oxygen) and a combination of both (A2/O and low oxygen). The lowest effluent nutrient levels were realised by the combined system of A2/O and low oxygen, which resulted in effluent of chemical oxygen demand (COD), NH3-N and biological oxygen demand (BOD5) concentrations of 98.20, 13.50 and 22.50 mg/L. The optimal operating conditions for the efficient removal of biological nutrient using the ICUSB reactor were examined to evaluate the influence of the parameters on its performance. The results showed that average removal efficiencies of COD and NH3-N of 96.49% and 99.39%, respectively were achieved under the condition of a hydraulic retention time of 12 hr, including 4 hr of pumping air into the reactor, with dissolved oxygen at an rate of 4 mg/L and an upflow velocity 2 m/hr. These combined processes were successfully employed and effectively decreased pollutant loading.

The competing impacts of climate change and nutrient reductions on dissolved oxygen in Chesapeake Bay

NASA Astrophysics Data System (ADS)

Irby, Isaac D.; Friedrichs, Marjorie A. M.; Da, Fei; Hinson, Kyle E.

2018-05-01

The Chesapeake Bay region is projected to experience changes in temperature, sea level, and precipitation as a result of climate change. This research uses an estuarine-watershed hydrodynamic-biogeochemical modeling system along with projected mid-21st-century changes in temperature, freshwater flow, and sea level rise to explore the impact climate change may have on future Chesapeake Bay dissolved-oxygen (DO) concentrations and the potential success of nutrient reductions in attaining mandated estuarine water quality improvements. Results indicate that warming bay waters will decrease oxygen solubility year-round, while also increasing oxygen utilization via respiration and remineralization, primarily impacting bottom oxygen in the spring. Rising sea level will increase estuarine circulation, reducing residence time in bottom waters and increasing stratification. As a result, oxygen concentrations in bottom waters are projected to increase, while oxygen concentrations at mid-depths (3 < DO < 5 mg L-1) will typically decrease. Changes in precipitation are projected to deliver higher winter and spring freshwater flow and nutrient loads, fueling increased primary production. Together, these multiple climate impacts will lower DO throughout the Chesapeake Bay and negatively impact progress towards meeting water quality standards associated with the Chesapeake Bay Total Maximum Daily Load. However, this research also shows that the potential impacts of climate change will be significantly smaller than improvements in DO expected in response to the required nutrient reductions, especially at the anoxic and hypoxic levels. Overall, increased temperature exhibits the strongest control on the change in future DO concentrations, primarily due to decreased solubility, while sea level rise is expected to exert a small positive impact and increased winter river flow is anticipated to exert a small negative impact.

Hydrogeologic controls on groundwater discharge and nitrogen loads in a coastal watershed

USGS Publications Warehouse

Russoniello, Chrtopher J.; Konikow, Leonard F.; Kroeger, Kevin D.; Fernandez, Cristina; Andres, A. Scott; Michael, Holly A.

2016-01-01

Submarine groundwater discharge (SGD) is a small portion of the global water budget, but a potentially large contributor to coastal nutrient budgets due to high concentrations relative to stream discharge. A numerical groundwater flow model of the Inland Bays Watershed, Delaware, USA, was developed to identify the primary hydrogeologic factors that affect groundwater discharge rates and transit times to streams and bays. The distribution of groundwater discharge between streams and bays is sensitive to the depth of the water table below land surface. Higher recharge and reduced hydraulic conductivity raised the water table and increased discharge to streams relative to bays compared to the Reference case (in which 66% of recharge is discharged to streams). Increases to either factor decreased transit times for discharge to both streams and bays compared to the Reference case (in which mean transit times are 56.5 and 94.3 years, respectively), though sensitivity to recharge is greater. Groundwater-borne nitrogen loads were calculated from nitrogen concentrations measured in discharging fresh groundwater and modeled SGD rates. These loads combined with long SGD transit times suggest groundwater-borne nitrogen reductions and estuarine water quality improvements will lag decades behind implementation of efforts to manage nutrient sources. This work enhances understanding of the hydrogeologic controls on and uncertainties in absolute and relative rates and transit times of groundwater discharge to streams and bays in coastal watersheds.

Challenges with effective nutrient supplementation for amphibians: A review of cricket studies.

PubMed

Livingston, Shannon; Lavin, Shana R; Sullivan, Kathleen; Attard, Lydia; Valdes, Eduardo V

2014-01-01

Over the last 25 years, numerous studies have investigated the impact of insect supplementation on insect nutrient content. In light of recent nutrition related challenges with regards to zoo amphibians fed an insect based diet, this review attempts to comprehensively compile both anecdotal and published data in the context of practical application on this topic. Insects, primarily crickets, used for amphibian diets historically demonstrate low concentrations of key nutrients including calcium and vitamin A. Commonly used practices for supplementation involving powder dusting or gut loading have been shown to improve delivery of calcium and vitamin A, though often not reaching desired nutrient concentrations. The large variety of factors influencing insect nutrient content are difficult to control, making study design, and results often inconsistent. Formulation and availability of more effective gut loading diets, combined with a standardized protocol for insect husbandry and dietary management may be the most effective way to supplement insects for use in amphibian feeding programs. Ideally, the nutritional improvement of feeder insects would begin at the breeder level; however, until this becomes a viable choice, we confirm that supplementation of crickets through both gut-loading and dusting appear necessary to support the nutritional health of amphibians and other insectivores in managed collections. © 2014 Wiley Periodicals, Inc.

Historical trend of nitrogen and phosphorus loads from the upper Yangtze River basin and their responses to the Three Gorges Dam.

PubMed

Sun, Chengchun; Shen, Zhenyao; Liu, Ruimin; Xiong, Ming; Ma, Fangbing; Zhang, Ouyang; Li, Yangyang; Chen, Lei

2013-12-01

Excessive inputs of nitrogen and phosphorus (N and P) degrade surface water quality worldwide. Impoundment of reservoirs alters the N and P balance of a basin. In this study, riverine nutrient loads from the upper Yangtze River basin (YRB) at the Yichang station were estimated using Load Estimator (LOADEST). Long-term load trends and monthly variabilities during three sub-periods based on the construction phases of the Three Gorges Dam (TGD) were analyzed statistically. The dissolved inorganic nitrogen (DIN) loads from the upper YRB for the period from 1990 to 2009 ranged from 30.47 × 10(4) to 78.14 × 10(4) t, while the total phosphorus (TP) loads ranged from 2.54 × 10(4) to 7.85 × 10(4) t. DIN increased rapidly from 1995 to 2002 mainly as a result of increased fertilizer use. Statistics of fertilizer use in the upper YRB agreed on this point. However, the trend of the TP loads reflected the combined effect of removal by sedimentation in reservoirs and increased anthropogenic inputs. After the TGD impoundment in 2003, decreasing trends in both DIN and TP loads were found. The reduction in DIN was mainly caused by ammonium consumption and transference. From an analysis of monthly loads, it was found that DIN had a high correlation to discharges. For TP loads, an average decrease of 4.91 % in October was found when the TGD impoundment occurred, but an increase of 4.23 % also occurred in July, corresponding to the washout from sediment deposited in the reservoir before July. Results of this study revealed the TGD had affected nutrient loads in the basin, and it had played a role in nutrient reduction after its operation.

El-Niño/Southern Oscillation (ENSO) influences on monthly NO 3 load and concentration, stream flow and precipitation in the Little River Watershed, Tifton, Georgia (GA)

NASA Astrophysics Data System (ADS)

Keener, V. W.; Feyereisen, G. W.; Lall, U.; Jones, J. W.; Bosch, D. D.; Lowrance, R.

2010-02-01

SummaryAs climate variability increases, it is becoming increasingly critical to find predictable patterns that can still be identified despite overall uncertainty. The El-Niño/Southern Oscillation is the best known pattern. Its global effects on weather, hydrology, ecology and human health have been well documented. Climate variability manifested through ENSO has strong effects in the southeast United States, seen in precipitation and stream flow data. However, climate variability may also affect water quality in nutrient concentrations and loads, and have impacts on ecosystems, health, and food availability in the southeast. In this research, we establish a teleconnection between ENSO and the Little River Watershed (LRW), GA., as seen in a shared 3-7 year mode of variability for precipitation, stream flow, and nutrient load time series. Univariate wavelet analysis of the NINO 3.4 index of sea surface temperature (SST) and of precipitation, stream flow, NO 3 concentration and load time series from the watershed was used to identify common signals. Shared 3-7 year modes of variability were seen in all variables, most strongly in precipitation, stream flow and nutrient load in strong El Niño years. The significance of shared 3-7 year periodicity over red noise with 95% confidence in SST and precipitation, stream flow, and NO 3 load time series was confirmed through cross-wavelet and wavelet-coherence transforms, in which common high power and co-variance were computed for each set of data. The strongest 3-7 year shared power was seen in SST and stream flow data, while the strongest co-variance was seen in SST and NO 3 load data. The strongest cross-correlation was seen as a positive value between the NINO 3.4 and NO 3 load with a three-month lag. The teleconnection seen in the LRW between the NINO 3.4 index and precipitation, stream flow, and NO 3 load can be utilized in a model to predict monthly nutrient loads based on short-term climate variability, facilitating management in high risk seasons.

Drainage Basins as Large-Scale Field Laboratories of Change: Hydro-biogeochemical- economic Model Study Support for Water Pollution and Eutrophication Management Under Uncertainty

NASA Astrophysics Data System (ADS)

Destouni, G.

2008-12-01

Excess nutrient and pollutant releases from various point and diffuse sources at and below the land surface, associated with land use, industry and households, pose serious eutrophication and pollution risks to inland and coastal water ecosystems worldwide. These risks must be assessed, for instance according to the EU Water Framework Directive (WFD). The WFD demands economically efficient, basin-scale water management for achieving and maintaining good physico-chemical and ecological status in all the inland and coastal waters of EU member states. This paper synthesizes a series of hydro-biogeochemical and linked economic efficiency studies of basin-scale waterborne nutrient and pollutant flows, the development over the last decades up to the current levels of these flows, the main monitoring and modelling uncertainties associated with their quantification, and the effectiveness and economic efficiency of different possible abatement strategies for abating them in order to meet WFD requirements and other environmental goals on local, national and international levels under climate and other regional change. The studies include different Swedish and Baltic Sea drainage basins. Main findings include quantification of near-coastal monitoring gaps and long-term nutrient and pollutant memory in the subsurface (soil-groundwater-sediment) water systems of drainage basins. The former may significantly mask nutrient and pollutant loads to the sea while the latter may continue to uphold large loads to inland and coastal waters long time after source mitigation. A methodology is presented for finding a rational trade-off between the two resource-demanding options to reduce, or accept and explicitly account for the uncertainties implied by these monitoring gaps and long-term nutrient-pollution memories and time lags, and other knowledge, data and model uncertainties that limit the effectiveness and efficiency of water pollution and eutrophication management.

Effects of pasture renovation on hydrology, nutrient runoff, and forage yield.

PubMed

de Koff, J P; Moore, P A; Formica, J; Van Eps, M; DeLaune, P B

2011-01-01

Proper pasture management is important in promoting optimal forage growth and reducing runoff and nutrient loss. Pasture renovation is a management tool that improves aeration by mechanically creating holes or pockets within the soil. Pasture renovation was performed before manure application (poultry litter or swine slurry) on different pasture soils and rainfall simulations were conducted to identify the effects of pasture renovation on nutrient runoff and forage growth. Renovation of small plots resulted in significant and beneficial hydrological changes. During the first rainfall simulation, runoff volumes were 45 to 74% lower for seven out of eight renovated treatments, and infiltration rates increased by 3 to 87% for all renovated treatments as compared with nonrenovated treatments. Renovation of pasture soils fertilized with poultry litter led to significant reductions in dissolved reactive P (DRP) (74-87%), total P (TP) (76-85%), and total nitrogen (TN) (72-80%) loads in two of the three soils studied during the first rainfall simulation. Renovation did not result in any significant differences in forage yields. Overall, beneficial impacts of renovation lasted up to 3 mo, the most critical period for nutrient runoff following manure application. Therefore, renovation could be an important best management practice in these areas.

Nutrient Loading and Algal Response in West Thompson Lake, Thompson, Connecticut, 2003-2005

USGS Publications Warehouse

Morrison, Jonathan; Colombo, Michael J.

2008-01-01

Water quality and nutrient loads were characterized for parts of the Quinebaug River and West Thompson Lake in northeastern Connecticut during 2003 to 2005. The West Thompson Lake watershed is a mainly forested watershed that receives treated municipal wastewater from several point sources in Massachusetts. The lake is a flood-control reservoir formed in 1966 by impoundment of the Quinebaug River. Median concentrations of total phosphorus in two inflow (upstream) and one outflow (downstream) sampling stations on the Quinebaug River were higher than the nutrient criteria recommended by the U.S. Environmental Protection Agency (USEPA) for rivers and streams in aggregate Ecoregion XIV. In general, concentrations of total phosphorus in West Thompson Lake also were above the nutrient criteria recommended by USEPA for lakes and impoundments in aggregate Ecoregion XIV. The trophic status of West Thompson Lake has changed since 1995 from a hypereutrophic lake to a eutrophic lake; however, the lake still has large algal blooms. These blooms are predominated by blue-green algae, with chlorophyll-a concentrations of more than 30 micrograms per liter and algal cell counts as high as 73,000 cells/mL. Water samples collected during the summer of 2005 identified phosphorus as the primary limiting nutrient early in the season, but algal growth is probably co-limited by phosphorus and nitrogen later in the season. Lake-bottom sediments were collected from several areas throughout the lake and ranged in thickness from less than 1 foot (ft) to more than 3 ft. Concentrations of phosphorus in sediments differed throughout the lake; the highest values were found in the middle of the lake. Concentrations of total phosphorus also increased from an average 1,800 milligrams per kilogram (mg/kg) in the upper layers of sediment to more than 6,000 mg/kg at depth in the sediment. Annual, seasonal, and monthly loads and yields of nutrients were calculated for the three sampling locations on the Quinebaug River to develop a nutrient mass-balance model (budget) for West Thompson Lake. The average annual yields of total phosphorus during 2000 to 2005 were 115 pounds per square mile per year (lb/mi2/yr) at Quinebaug (inflow station), 116 lb/mi2/yr at Red Bridge Road (inflow station), and 97.9 lb/mi2/yr at West Thompson (outflow station). The 18-percent decrease in the average annual yield of total phosphorus between the inflow station at Red Bridge Road and the outlet of West Thompson Lake at West Thompson indicates that a significant part of the phosphorus load is retained in the lake. Annual yields of total phosphorus at Quinebaug have decreased significantly since the 1980s, from 362 lb/mi2/yr (for 1981-1990) to 115 lb/mi2/yr (1996-2005). The annual net export of phosphorus in West Thompson Lake during water years 2000 to 2005 ranged from -36 percent (2005) to 1 percent (2002) of the incoming load. Seasonal mass-balance data for total phosphorus during the summers of 2000 to 2003, when streamflow was at or lower than normal, indicated a net export of phosphorus that ranged from 3.4 percent (2003) to 30.7 percent (2002) of the incoming load. During the summer of 2004, however, streamflows were much higher than normal, and there was a negative export of phosphorus in West Thompson Lake of -3.9 percent. The annual net export of nitrogen in West Thompson Lake during water years 2000 to 2005 ranged from -5 percent (2002) to 4 percent (2001) of the incoming load. No clear pattern was evident to relate total nitrogen export to seasonal variables or runoff. Removal of phosphorus during the summer by wastewater-treatment plants (WWTPs) in Massachusetts reduces the concentration and load of total phosphorus entering West Thompson Lake in the summer; however, the large amount of phosphorus retained in the lake during the other seasons, in addition to the phosphorus stored in the lake-bottom sediments, may become available to fuel algal blooms in the lake

Promoting nitrate removal in rain gardens | Science Inventory ...

EPA Pesticide Factsheets

Rain gardens are vegetated surface depressions, often located at low points in landscapes, designed to receive stormwater runoff from roads, roofs, and parking lots. The gardens’ sandy soils allow stormwater to drain quickly to the native soils below and eventually to groundwater. The rain garden vegetation and soils remove pollutants and nutrients from stormwater runoff through biological and physical processes such as plant uptake and sorption to soil particles. In comparison with stormwater release to receiving waters through conventional storm drain systems, infiltrating stormwater through rain gardens reduces peak flows and loadings of both pollutants and nutrients. This reduction improves the physical and biological integrity of receiving streams by reducing stream bank erosion and negative effects on stream communities. While local governments and individual homeowners are building these systems, relatively few scientific studies have documented the ability of rain gardens to remove pollutants and nutrients. This U.S. EPA long-term research project investigates: 1) the performance of rain gardens in removing pollutants, and 2) whether currently-accepted design standards can be adjusted to improve nitrate removal capabilities. Typical rain garden designs provide large removals of pollutants of concern, including heavy metals, phosphorus, total nitrogen, and ammonium. The gardens have been less successful in removing nitrate, an importan

The effect of poultry manure application rate and AlCl(3) treatment on bacterial fecal indicators in runoff.

PubMed

Brooks, J P; Adeli, A; McLaughlin, M R; Miles, D M

2012-12-01

Increasing costs associated with inorganic fertilizer have led to widespread use of broiler litter. Proper land application, typically limiting nutrient loss, is essential to protect surface water. This study was designed to evaluate litter-borne microbial runoff (heterotrophic plate count bacteria, staphylococci, Escherichia coli, enterococci, and Clostridium perfringens) while applying typical nutrient-control methods. Field studies were conducted in which plots with high and low litter rates, inorganic fertilizer, AlCl(3)-treated litter, and controls were rained on five times using a rain generator. Overall, microbial runoff from poultry litter applied plots was consistently greater (2-5 log(10) plot(-1)) than controls. No appreciable effect on microbial runoff was noted from variable litter application rate or AlCl(3) treatments, though rain event, not time, significantly affected runoff load. C. perfringens and staphylococci runoff were consistently associated with poultry litter application, during early rain events, while other indicators were unreliable. Large microbial runoff pulses were observed, ranging from 10(2) to 10(10) CFU plot(-1); however, only a small fraction of litter-borne microbes were recoverable in runoff. This study indicated that microbial runoff from litter-applied plots can be substantial, and that methods intended to reduce nutrient losses do not necessarily reduce microbial runoff.

Long-term nutrient reductions lead to the unprecedented recovery of a temperate coastal region.

PubMed

Lefcheck, Jonathan S; Orth, Robert J; Dennison, William C; Wilcox, David J; Murphy, Rebecca R; Keisman, Jennifer; Gurbisz, Cassie; Hannam, Michael; Landry, J Brooke; Moore, Kenneth A; Patrick, Christopher J; Testa, Jeremy; Weller, Donald E; Batiuk, Richard A

2018-04-03

Humans strongly impact the dynamics of coastal systems, yet surprisingly few studies mechanistically link management of anthropogenic stressors and successful restoration of nearshore habitats over large spatial and temporal scales. Such examples are sorely needed to ensure the success of ecosystem restoration efforts worldwide. Here, we unite 30 consecutive years of watershed modeling, biogeochemical data, and comprehensive aerial surveys of Chesapeake Bay, United States to quantify the cascading effects of anthropogenic impacts on submersed aquatic vegetation (SAV), an ecologically and economically valuable habitat. We employ structural equation models to link land use change to higher nutrient loads, which in turn reduce SAV cover through multiple, independent pathways. We also show through our models that high biodiversity of SAV consistently promotes cover, an unexpected finding that corroborates emerging evidence from other terrestrial and marine systems. Due to sustained management actions that have reduced nitrogen concentrations in Chesapeake Bay by 23% since 1984, SAV has regained 17,000 ha to achieve its highest cover in almost half a century. Our study empirically demonstrates that nutrient reductions and biodiversity conservation are effective strategies to aid the successful recovery of degraded systems at regional scales, a finding which is highly relevant to the utility of environmental management programs worldwide.

Organic matter loading by hippopotami causes subsidy overload resulting in downstream hypoxia and fish kills.

PubMed

Dutton, Christopher L; Subalusky, Amanda L; Hamilton, Stephen K; Rosi, Emma J; Post, David M

2018-05-16

Organic matter and nutrient loading into aquatic ecosystems affects ecosystem structure and function and can result in eutrophication and hypoxia. Hypoxia is often attributed to anthropogenic pollution and is not common in unpolluted rivers. Here we show that organic matter loading from hippopotami causes the repeated occurrence of hypoxia in the Mara River, East Africa. We documented 49 high flow events over 3 years that caused dissolved oxygen decreases, including 13 events resulting in hypoxia, and 9 fish kills over 5 years. Evidence from experiments and modeling demonstrates a strong mechanistic link between the flushing of hippo pools and decreased dissolved oxygen in the river. This phenomenon may have been more widespread throughout Africa before hippopotamus populations were severely reduced. Frequent hypoxia may be a natural part of tropical river ecosystem function, particularly in rivers impacted by large wildlife.

Microbial and Nutrient Concentration and Load Data During Stormwater Runoff at a Swine Concentrated Animal Feeding Operation in the North Carolina Coastal Plain, 2006-2007

USGS Publications Warehouse

Harden, Stephen L.

2008-01-01

This report summarizes water-quality and hydrologic data collected during 2006-2007 to characterize bacteria and nutrient loads associated with overland runoff and subsurface tile drainage in spray fields at a swine concentrated animal feeding operation. Four monitoring locations were established at the Lizzie Research Site in the North Carolina Coastal Plain Physiographic Province for collecting discharge and water-quality data during stormwater-runoff events. Water stage was measured continuously at each monitoring location. A stage-discharge relation was developed for each site and was used to compute instantaneous discharge values for collected samples. Water-quality samples were collected for five storm events during 2006-2007 for analysis of nutrients and fecal indicator bacteria. Instantaneous loads of nitrite plus nitrate, total coliform, Escherichia coli (E. coli), and enterococci were computed for selected times during the five storm events.

Responses of stream nitrate and DOC loadings to hydrological forcing and climate change in an upland forest of the northeastern United States

NASA Astrophysics Data System (ADS)

Sebestyen, Stephen D.; Boyer, Elizabeth W.; Shanley, James B.

2009-06-01

In coming decades, higher annual temperatures, increased growing season length, and increased dormant season precipitation are expected across the northeastern United States in response to anthropogenic forcing of global climate. We synthesized long-term stream hydrochemical data from the Sleepers River Research Watershed in Vermont, United States, to explore the relationship of catchment wetness to stream nitrate and DOC loadings. We modeled changes in growing season length and precipitation patterns to simulate future climate scenarios and to assess how stream nutrient loadings respond to climate change. Model results for the 2070-2099 time period suggest that stream nutrient loadings during both the dormant and growing seasons will respond to climate change. During a warmer climate, growing season stream fluxes (runoff +20%, nitrate +57%, and DOC +58%) increase as more precipitation (+28%) and quick flow (+39%) occur during a longer growing season (+43 days). During the dormant season, stream water and nutrient loadings decrease. Net annual stream runoff (+8%) and DOC loading (+9%) increases are commensurate with the magnitude of the average increase of net annual precipitation (+7%). Net annual stream water and DOC loadings are primarily affected by increased dormant season precipitation. In contrast, decreased annual loading of stream nitrate (-2%) reflects a larger effect of growing season controls on stream nitrate and the effects of lengthened growing seasons in a warmer climate. Our findings suggest that leaching of nitrate and DOC from catchment soils will be affected by anthropogenic climate forcing, thereby affecting the timing and magnitude of annual stream loadings in the northeastern United States.

TiO2 nanoparticles for the remediation of eutrophic shallow freshwater systems: Efficiency and impacts on aquatic biota under a microcosm experiment.

PubMed

Bessa da Silva, Márcia; Abrantes, Nelson; Nogueira, Verónica; Gonçalves, Fernando; Pereira, Ruth

2016-09-01

The application of nanomaterials (NMs) in the remediation of eutrophic waters, particularly in the control of internal loading of nutrients, has been started, but limited investigations evaluated the effectiveness of these new treatment approaches and of their potential impacts on species from shallow freshwater lakes. The present work investigated, under a microcosm experiment, the application of a TiO2 nanomaterial both for reducing nutrient (mainly phosphorus and nitrogen forms) desorption and release from sediments (preventive treatment-PT) and for eliminating algal blooms (remediation treatment-RT). Furthermore, we also intended to assess the potential impacts of nano-TiO2 application on key freshwater species. The results showed the effectiveness of nano-TiO2 in controlling the release of phosphates from surface sediment and the subsequent reduction of total phosphorus in the water column. A reduction in total nitrogen was also observed. Such changes in nutrient dynamics contributed to a progressive inhibition of development of algae after the application of the NM in PT microcosms. Concerning the ability of nano-TiO2 to interact with algal cells, this interaction has likely occurred, mainly in RT, enhancing the formation of aggregates and their rapid settlement, thus reducing the algal bloom. Both treatments caused deleterious effects on freshwater species. In PT, Daphnia magna and Lemna minor showed a significant inhibition of several endpoints. Conversely, no inhibitory effect on the growth of Chironomus riparius was recorded. In opposite, C. riparius was the most affected species in RT microcosms. Such difference was probably caused by the formation of larger TiO2-algae aggregates in RT, under a high algal density, that rapidly settled in the sediment, becoming less available for pelagic species. In summary, despite the effectiveness of both treatments in controlling internal nutrient loading and in the mitigating algal bloom episodes, their negative effects on biota have to be seriously taken into account. Copyright © 2016 Elsevier B.V. All rights reserved.

Trees and Streets as Drivers of Urban Stormwater Nutrient Pollution.

PubMed

Janke, Benjamin D; Finlay, Jacques C; Hobbie, Sarah E

2017-09-05

Expansion of tree cover is a major management goal in cities because of the substantial benefits provided to people, and potentially to water quality through reduction of stormwater volume by interception. However, few studies have addressed the full range of potential impacts of trees on urban runoff, which includes deposition of nutrient-rich leaf litter onto streets connected to storm drains. We analyzed the influence of trees on stormwater nitrogen and phosphorus export across 19 urban watersheds in Minneapolis-St. Paul, MN, U.S.A., and at the scale of individual streets within one residential watershed. Stormwater nutrient concentrations were highly variable across watersheds and strongly related to tree canopy over streets, especially for phosphorus. Stormwater nutrient loads were primarily related to road density, the dominant control over runoff volume. Street canopy exerted opposing effects on loading, where elevated nutrient concentrations from trees near roads outweighed the weak influence of trees on runoff reduction. These results demonstrate that vegetation near streets contributes substantially to stormwater nutrient pollution, and therefore to eutrophication of urban surface waters. Urban landscape design and management that account for trees as nutrient pollution sources could improve water quality outcomes, while allowing cities to enjoy the myriad benefits of urban forests.

LONG-TERM CHANGES IN WATERSHED NUTRIENT INPUTS AND RIVERINE EXPORTS IN THE NEUSE RIVER, NORTH CAROLINA. (U915590)

EPA Science Inventory

We compared patterns of historical watershed nutrient inputs with in-river nutrient loads for the Neuse River, NC. Basin-wide sources of both nitrogen and phosphorus have increased substantially during the past century, marked by a sharp increase in the last 10 years resulting...

Fall fertilization enhanced nitrogen storage and translocation in Larix olgensis seedlings

Treesearch

Y. Zhu; R. K. Dumroese; G. L. Li; J. R. Pinto; Y. Liu

2013-01-01

Fall nutrient loading of deciduous forest nursery seedlings is of special interest because of foliage abscission and varied translocation patterns. For non-deciduous seedlings in the nursery, fall fertilization typically can reverse nutrient dilution and possibly increase nutrient reserves; however, this technique has received little attention with deciduous conifer...

Nutrient additions by waterfowl to lakes and reservoirs: predicting their effects on productivity and water quality

USGS Publications Warehouse

Manny, Bruce A.; Johnson, W.C.; Wetzel, R.G.

1994-01-01

Lakes and reservoirs provide water for human needs and habitat for aquatic birds. Managers of such waters may ask whether nutrients added by waterfowl degrade water quality. For lakes and reservoirs where primary productivity is limited by phosphorus (P), we developed a procedure that integrates annual P loads from waterfowl and other external sources, applies a nutrient load-response model, and determines whether waterfowl that used the lake or reservoir degraded water quality. Annual P loading by waterfowl can be derived from a figure in this report, using the days per year that each kind spent on any lake or reservoir. In our example, over 6500 Canada geese (Branta canadensis) and 4200 ducks (mostly mallards, Anas platyrhynchos) added 4462 kg of carbon (C), 280 kg of nitrogen (N), and 88 kg of P y-1 to Wintergreen Lake in southwestern Michigan, mostly during their migration. These amounts were 69% of all C, 27% of all N, and 70% of all P that entered the lake from external sources. Loads from all external sources totaled 840 mg P m-2 y-1. Application of a nutrient load-response model to this concentration, the hydraulic load (0.25 m y-1), and the water residence time (9.7 y) of Wintergreen Lake yielded an average annual concentration of total P in the lake of 818 mg m-3 that classified the lake as hypertrophic. This trophic classification agreed with independent measures of primary productivity, chlorophyll-a, total P, total N, and Secchi disk transparency made in Wintergreen Lake. Our procedure showed that waterfowl caused low water quality in Wintergreen Lake.

A Bayesian changepoint-threshold model to examine the effect of TMDL implementation on the flow-nitrogen concentration relationship in the Neuse River basin.

PubMed

Alameddine, Ibrahim; Qian, Song S; Reckhow, Kenneth H

2011-01-01

In-stream nutrient concentrations are well known to exhibit a strong relationship with river flow. The use of flow measurements to predict nutrient concentrations and subsequently nutrient loads is common in water quality modeling. Nevertheless, most adopted models assume that the relationship between flow and concentration is fixed across time as well as across different flow regimes. In this study, we developed a Bayesian changepoint-threshold model that relaxes these constraints and allows for the identification and quantification of any changes in the underlying flow-concentration relationship across time. The results from our study support the occurrence of a changepoint in time around the year 1999, which coincided with the period of implementing nitrogen control measures as part of the TMDL program developed for the Neuse Estuary in North Carolina. The occurrence of the changepoint challenges the underlying assumption of temporal invariance in the flow-concentrations relationship. The model results also point towards a transition in the river nitrogen delivery system from a point source dominated loading system towards a more complicated nonlinear system, where non-point source nutrient delivery plays a major role. Moreover, we use the developed model to assess the effectiveness of the nitrogen reduction measures in achieving a 30% drop in loading. The results indicate that while there is a strong evidence of a load reduction, there still remains a high level of uncertainty associated with the mean nitrogen load reduction. We show that the level of uncertainty around the estimated load reduction is not random but is flow related. Copyright © 2010 Elsevier Ltd. All rights reserved.

The Catchment Runoff Attenuation Flux Tool, a minimum information requirement nutrient pollution model

NASA Astrophysics Data System (ADS)

Adams, R.; Quinn, P. F.; Bowes, M. J.

2015-04-01

A model for simulating runoff pathways and water quality fluxes has been developed using the minimum information requirement (MIR) approach. The model, the Catchment Runoff Attenuation Flux Tool (CRAFT), is applicable to mesoscale catchments and focusses primarily on hydrological pathways that mobilise nutrients. Hence CRAFT can be used to investigate the impact of flow pathway management intervention strategies designed to reduce the loads of nutrients into receiving watercourses. The model can help policy makers meet water quality targets and consider methods to obtain "good" ecological status. A case study of the 414 km2 Frome catchment, Dorset, UK, has been described here as an application of CRAFT in order to highlight the above issues at the mesoscale. The model was primarily calibrated on 10-year records of weekly data to reproduce the observed flows and nutrient (nitrate nitrogen - N; phosphorus - P) concentrations. Data from 2 years with sub-daily monitoring at the same site were also analysed. These data highlighted some additional signals in the nutrient flux, particularly of soluble reactive phosphorus, which were not observable in the weekly data. This analysis has prompted the choice of using a daily time step as the minimum information requirement to simulate the processes observed at the mesoscale, including the impact of uncertainty. A management intervention scenario was also run to demonstrate how the model can support catchment managers investigating how reducing the concentrations of N and P in the various flow pathways. This mesoscale modelling tool can help policy makers consider a range of strategies to meet the European Union (EU) water quality targets for this type of catchment.

Recovery of a top predator mediates negative eutrophic effects on seagrass

USGS Publications Warehouse

Hughes, Brent B.; Eby, Ron; Van Dyke, Eric; Tinker, M. Tim; Marks, Corina I.; Johnson, Kenneth S.; Wasson, Kerstin

2013-01-01

A fundamental goal of the study of ecology is to determine the drivers of habitat-forming vegetation, with much emphasis given to the relative importance to vegetation of “bottom-up” forces such as the role of nutrients and “top-down” forces such as the influence of herbivores and their predators. For coastal vegetation (e.g., kelp, seagrass, marsh, and mangroves) it has been well demonstrated that alterations to bottom-up forcing can cause major disturbances leading to loss of dominant vegetation. One such process is anthropogenic nutrient loading, which can lead to major changes in the abundance and species composition of primary producers, ultimately affecting important ecosystem services. In contrast, much less is known about the relative importance of apex predators on coastal vegetated ecosystems because most top predator populations have been depleted or lost completely. Here we provide evidence that an unusual four-level trophic cascade applies in one such system, whereby a top predator mitigates the bottom-up influences of nutrient loading. In a study of seagrass beds in an estuarine ecosystem exposed to extreme nutrient loading, we use a combination of a 50-y time series analysis, spatial comparisons, and mesocosm and field experiments to demonstrate that sea otters (Enhydra lutris) promote the growth and expansion of eelgrass (Zostera marina) through a trophic cascade, counteracting the negative effects of agriculturally induced nutrient loading. Our results add to a small but growing body of literature illustrating that significant interactions between bottom-up and top-down forces occur, in this case with consequences for the conservation of valued ecosystem services provided by seagrass.

Recovery of a top predator mediates negative eutrophic effects on seagrass

PubMed Central

Hughes, Brent B.; Eby, Ron; Van Dyke, Eric; Tinker, M. Tim; Marks, Corina I.; Johnson, Kenneth S.; Wasson, Kerstin

2013-01-01

A fundamental goal of the study of ecology is to determine the drivers of habitat-forming vegetation, with much emphasis given to the relative importance to vegetation of “bottom-up” forces such as the role of nutrients and “top-down” forces such as the influence of herbivores and their predators. For coastal vegetation (e.g., kelp, seagrass, marsh, and mangroves) it has been well demonstrated that alterations to bottom-up forcing can cause major disturbances leading to loss of dominant vegetation. One such process is anthropogenic nutrient loading, which can lead to major changes in the abundance and species composition of primary producers, ultimately affecting important ecosystem services. In contrast, much less is known about the relative importance of apex predators on coastal vegetated ecosystems because most top predator populations have been depleted or lost completely. Here we provide evidence that an unusual four-level trophic cascade applies in one such system, whereby a top predator mitigates the bottom-up influences of nutrient loading. In a study of seagrass beds in an estuarine ecosystem exposed to extreme nutrient loading, we use a combination of a 50-y time series analysis, spatial comparisons, and mesocosm and field experiments to demonstrate that sea otters (Enhydra lutris) promote the growth and expansion of eelgrass (Zostera marina) through a trophic cascade, counteracting the negative effects of agriculturally induced nutrient loading. Our results add to a small but growing body of literature illustrating that significant interactions between bottom-up and top-down forces occur, in this case with consequences for the conservation of valued ecosystem services provided by seagrass. PMID:23983266

Nutrient load summaries for major lakes and estuaries of the Eastern United States, 2002

USGS Publications Warehouse

Moorman, Michelle C.; Hoos, Anne B.; Bricker, Suzanne B.; Moore, Richard B.; García, Ana María; Ator, Scott W.

2014-01-01

Nutrient enrichment of lakes and estuaries across the Nation is widespread. Nutrient enrichment can stimulate excessive plant and algal growth and cause a number of undesirable effects that impair aquatic life and recreational activities and can also result in economic effects. Understanding the amount of nutrients entering lakes and estuaries, the physical characteristics affecting the nutrient processing within these receiving waterbodies, and the natural and manmade sources of nutrients is fundamental to the development of effective nutrient reduction strategies. To improve this understanding, sources and stream transport of nutrients to 255 major lakes and 64 estuaries in the Eastern United States were estimated using Spatially Referenced Regression on Watershed attributes (SPARROW) nutrient models.

Passive flux meter measurement of water and nutrient flux in saturated porous media: bench-scale laboratory tests.

PubMed

Cho, Jaehyun; Annable, Michael D; Jawitz, James W; Hatfield, Kirk

2007-01-01

The passive nutrient flux meter (PNFM) is introduced for simultaneous measurement of both water and nutrient flux through saturated porous media. The PNFM comprises a porous sorbent pre-equilibrated with a suite of alcohol tracers, which have different partitioning coefficients. Water flux was estimated based on the loss of loaded resident tracers during deployment, while nutrient flux was quantified based on the nutrient solute mass captured on the sorbent. An anionic resin, Lewatit 6328 A, was used as a permeable sorbent and phosphate (PO4(3-)) was the nutrient studied. The phosphate sorption capacity of the resin was measured in batch equilibration tests as 56 mg PO4(3-) g(-1), which was determined to be adequate capacity to retain PO4(3-) loads intercepted over typical PNFM deployment periods in most natural systems. The PNFM design was validated with bench-scale laboratory tests for a range of 9.8 to 28.3 cm d(-1) Darcy velocities and 6 to 43 h deployment durations. Nutrient and water fluxes measured by the PNFM averaged within 6 and 12% of the applied values, respectively, indicating that the PNFM shows promise as a tool for simultaneous measurement of water and nutrient fluxes.

Selected nutrients and pesticides in streams of the eastern Iowa basins, 1970-95

USGS Publications Warehouse

Schnoebelen, Douglas J.; Becher, Kent D.; Bobier, Matthew W.; Wilton, Thomas

1999-01-01

 The statistical analysis of the nutrient data typically indicated a strong positive correlation of nitrate with streamflow. Total phosphorus concentrations with streamflow showed greater variability than nitrate, perhaps reflecting the greater potential of transport of phosphorus on sediment rather than in the dissolved phase as with nitrate. Ammonia and ammonia plus organic nitrogen showed no correlation with streamflow or a weak positive correlation. Seasonal variations and the relations of nutrients and pesticides to streamflow generally corresponded with nonpoint‑source loadings, although possible point sources for nutrients were indicated by the data at selected monitoring sites. Statistical trend tests for concentrations and loads were computed for nitrate, ammonia, and total phosphorus. Trend analysis indicated decreases for ammonia and total phosphorus concentrations at several sites and increases for nitrate concentrations at other sites in the study unit.

Volcanic nutrient inputs and trophic state of Lake Caviahue, Patagonia, Argentina

NASA Astrophysics Data System (ADS)

Pedrozo, Fernando L.; Temporetti, Pedro F.; Beamud, Guadalupe; Diaz, Mónica M.

2008-12-01

The strategies for eutrophication control, remediation, and policy management are often defined for neutral to alkaline freshwater systems, as they are most suitable for human use. The influence of nutrients on eutrophication in a naturally-acidic lake is poorly known. The main purpose of the present work is to evaluate the significance of volcanic nutrients in the control of the trophic state of the acidic Lake Caviahue, located at North Patagonia, Argentina. Acidic water systems were most studied on artificial acidified lakes, such as mining lakes in Germany or pit lakes in the United States. Lake Caviahue received a very high P load (42-192 ton P/yr) and low N load (14 ton N/yr), mainly as ammonium with quite low N:P ratios (< 1.0). The magmatic activity of the Copahue volcano represents the main natural contribution of nutrients and acidity to the Lake Caviahue. The lake is oligotrophic in terms of CHLa. Neither the transparency nor the nutrient, dissolved or particulate, contents are to date representative of the trophic state of the lake. High P loads do not imply the eutrophication of the lake. We suggest that nitrogen and not phosphorus represents the key control nutrient in volcanically acidified lakes as TON was better related to CHLa observed (0.13-0.36 mg/m 3) in the lake. The pH increased around one unit (pH 2.0-3.0) during the last five years suggesting that the lake has not yet returned to a stable state.

Methodology for estimating nutrient loads discharged from the east coast canals to Biscayne Bay, Miami-Dade County, Florida

USGS Publications Warehouse

Lietz, Arthur C.

1999-01-01

Biscayne Bay is an oligotrophic, subtropical estuary located along the southeastern coast of Florida that provides habitat for a variety of plant and animal life. Concern has arisen with regard to the ecological health of Biscayne Bay because of the presence of nutrient-laden discharges from the east coast canals that drain into the bay. This concern, as well as planned diversion of discharges for ecosystem restoration from the urban and agricultural corridors of Miami-Dade County to Everglades National Park, served as the impetus for a study conducted during the 1996 and 1997 water years to estimate nutrient loads discharged from the east coast canals into Biscayne Bay. Analytical results indicated that the highest concentration of any individual nutrient sampled for in the study was 4.38 mg/L (milligrams per liter) for nitrate at one site, and the lowest concentrations determined were below the detection limits for orthophosphate at six sites and nitrite at four sites. Median concentrations for all the sites were 0.75 mg/L for total organic nitrogen, 0.10 mg/L for ammonia, 0.02 mg/L for nitrite, 0.18 mg/L for nitrate, 0.20 mg/L for nitrite plus nitrate nitrogen, 0.02 mg/L for total phosphorus, and 0.005 mg/L for orthophosphate. The maximum total phosphorus concentration of 0.31 mg/L was the only nutrient concentration to exceed U.S. Environmental Protection Agency (1986) water-quality criteria. High concentrations of total phosphorus usually reflect contamination as a result of human activities. Five sites exceeded the fresh-water quality standard of 0.5 mg/L for ammonia concentration as determined by the Miami-Dade County Department of Environmental Resources Management. Median total organic nitrogen concentrations were higher in urban and forested/wetland areas than in agricultural areas; median concentrations of nitrite, nitrate, and nitrite plus nitrate nitrogen were higher in agricultural areas than in urban and forested/wetland areas; and ammonia, total phosphorus, and orthophosphate concentrations were higher in urban areas than in agricultural and forested/wetland areas. These results coincide with expected differences in nutrient concentrations based on knowledge of point and nonpoint source influences and nutrient cycling. The Wilcoxon signed ranks test (WSRT) was used to compare differences between point (grab) samples and depth-integrated samples for total nitrogen and total phosphorus concentrations at 12 east coast canal sites. Statistically significant differences (alpha level of 0.025) in total phosphorus concentrations between point (grab) samples collected 1.0 meter deep and depth-integrated samples were detected at three sites. One site also showed statistically significant differences in total phosphorus concentrations between point (grab) samples collected 0.5 meter deep and depth-integrated samples. There were no statistically significant differences in total nitrogen and total phosphorus concentrations between point (grab) samples collected 0.5 meter deep and 1.0 meter deep for all the sites. Results of the line of organic correlation, a fitting procedure used to compare point (grab) and depth-integrated samples where statistically significant differences exist as defined by the WSRT, indicated that point (grab) samples underestimate total phosphorus concentrations when compared to depth-integrated samples. This underestimation probably can be attributed to the reduced suspended-sediment concentrations near the surface during periods of flow as compared to those near the streambed. Predictive models were developed to estimate total nitrogen and total phosphorus loads by means of an ordinary least-squares regression technique. Instantaneous discharge was used as the independent variable, and total phosphorus load or total nitrogen load represented the dependent variable. A software program called Estimator was used to develop the regression models and to compute total nitrogen and total phosphorus loads

Marine west coast forests: Chapter 9

USGS Publications Warehouse

Perakis, Steven S.; Geiser, Linda H.; Lilleskov, Erik A.; Pardo, Linda H.; Robin-Abbott, Molly J.; Driscoll, Charles T.

2011-01-01

Human activities have greatly increased nitrogen emissions and deposition across large areas of Earth. Although nitrogen is an essential nutrient for plant growth, too much nitrogen in excess of critical loads leads to losses of biodiversity, soil and stream acidification, nutrient imbalances, and other deleterious effects. In a new report quantifying critical loads of nitrogen deposition across the United States, USGS scientist Steve Perakis and co-authors provided a chapter about responses of marine west coast forests. Much of this region is understudied with respect to nitrogen deposition, and in this chapter the authors identify known adverse effects and estimate critical loads of nitrogen deposition for western Oregon and Washington and southeast Alaska forests. Perakis also contributed to the synthesis chapter, which includes background, objectives, advantages and uncertainties of critical loads, an overview of critical loads across U.S. ecoregions, and other topics.

Estimating Nitrogen Loads, BMPs, and Target Loads Exceedance Risks

EPA Science Inventory

The Wabash River (WR) watershed, IN, drains two-thirds of the state’s 92 counties and has primarily agricultural land use. The nutrient and sediment loads of the WR significantly increase loads of the Ohio River ultimately polluting the Gulf of Mexico. The objective of this study...

Impact of co-digestion on existing salt and nutrient mass balances for a full-scale dairy energy project.

PubMed

Camarillo, Mary Kay; Stringfellow, William T; Spier, Chelsea L; Hanlon, Jeremy S; Domen, Jeremy K

2013-10-15

Anaerobic digestion of manure and other agricultural waste streams with subsequent energy production can result in more sustainable dairy operations; however, importation of digester feedstocks onto dairy farms alters previously established carbon, nutrient, and salinity mass balances. Salt and nutrient mass balance must be maintained to avoid groundwater contamination and salination. To better understand salt and nutrient contributions of imported methane-producing substrates, a mass balance for a full-scale dairy biomass energy project was developed for solids, carbon, nitrogen, sulfur, phosphorus, chloride, and potassium. Digester feedstocks, consisting of thickened manure flush-water slurry, screened manure solids, sudan grass silage, and feed-waste, were tracked separately in the mass balance. The error in mass balance closure for most elements was less than 5%. Manure contributed 69.2% of influent dry matter while contributing 77.7% of nitrogen, 90.9% of sulfur, and 73.4% of phosphorus. Sudan grass silage contributed high quantities of chloride and potassium, 33.3% and 43.4%, respectively, relative to the dry matter contribution of 22.3%. Five potential off-site co-digestates (egg waste, grape pomace, milk waste, pasta waste, whey wastewater) were evaluated for anaerobic digestion based on salt and nutrient content in addition to bio-methane potential. Egg waste and wine grape pomace appeared the most promising co-digestates due to their high methane potentials relative to bulk volume. Increasing power production from the current rate of 369 kW to the design value of 710 kW would require co-digestion with either 26800 L d(-1) egg waste or 60900 kg d(-1) grape pomace. However, importation of egg waste would more than double nitrogen loading, resulting in an increase of 172% above the baseline while co-digestion with grape pomace would increase potassium by 279%. Careful selection of imported co-digestates and management of digester effluent is required to manage salt and nutrient mass loadings and reduce groundwater impacts. Copyright © 2013 Elsevier Ltd. All rights reserved.

2020s scenario analysis of nutrient load in the Mekong River Basin using a distributed hydrological model.

PubMed

Yoshimura, Chihiro; Zhou, Maichun; Kiem, Anthony S; Fukami, Kazuhiko; Prasantha, Hapuarachchi H A; Ishidaira, Hiroshi; Takeuchi, Kuniyoshi

2009-10-01

A distributed hydrological model, YHyM, was integrated with the export coefficient concept and applied to simulate the nutrient load in the Mekong River Basin. In the validation period (1992-1999), Nash-Sutcliffe efficiency was 76.4% for discharge, 65.9% for total nitrogen, and 45.3% for total phosphorus at Khong Chiam. Using the model, scenario analysis was then performed for the 2020s taking into account major anthropogenic factors: climate change, population, land cover, fertilizer use, and industrial waste water. The results show that the load at Kompong Cham in 2020s is 6.3 x 10(4)tN a(-1) (+13.0% compared to 1990s) and 4.3 x 10(3)tP a(-1) (+24.7%). Overall, the noticeable nutrient sources are cropland in the middle region and urban load in the lower region. The installation of waste water treatment plants in urban areas possibly cut 60.6%N and 19.9%P of the estimated increase in the case without any treatment.

Long-Term Changes in Nitrogen Budgets and Retention in the Elbe Estuary

NASA Astrophysics Data System (ADS)

Eisele, Annika; van Beusekom, Justus E. E.; Wirtz, Kai

2016-04-01

Eutrophication remains one of the major factors influencing the ecological state of coastal ecosystems. Coastal eutrophication is in turn intimately linked to riverine nutrient loads. At the freshwater side of the estuary, nutrient loads can easily be quantified but estuarine processes including organic matter import from the sea and loss factors like denitrification can modify the actual nutrient loads reaching the coastal seas. We quantified and localized nutrient retention processes by analyzing changes of nutrient concentrations along the estuary and constructing nutrient budgets. Two methods -the Officer method based on conservative mixing and a new method based on changes in nitrogen concentrations along the freshwater part of the estuary- were compared using long term records for the Elbe River, a major European waterway. Nutrient budgets and dynamics reveal that nutrient retention processes in the water column play a substantial role in the Elbe River. Overall, ~25 mio mol/day N are imported into the Elbe estuary and ~20 mio mol/day DIN is exported, with obvious variations depending on river discharge and season. A nitrogen loss of about 20% falls within the range found in other studies. Whereas in the 1980s a significant part of the nitrogen input was retained by the estuary, in the 1990s and 2000s most of the imported total nitrogen was exported as DIN. At present, the retention of nitrogen -presumably due to increased denitrification- increases again. As these long-term changes in the retention capacity of the Elbe were supported by both methods, the calibrated station-based approach can now be used to calculate nutrient budgets in estuaries where no or only few transect data are available, such as the Weser and Ems estuary. Our presentation will finally discuss the possible impact of increased phytoplankton import from the Elbe River and increased import of suspended matter from the North Sea ecosystem on estuarine nitrogen dynamics.

Pathogen and nutrient pulsing and attenuation in "accidental" urban wetland networks along the Salt River in Phoenix, AZ

NASA Astrophysics Data System (ADS)

Palta, M. M.; Grimm, N. B.

2013-12-01

Increases in available nutrients and bacteria in urban streams are at the forefront of research concerns within the ecological and medical communities, and both pollutants are expected to become more problematic under projected changes in climate. Season, discharge, instream conditions (oxygen, water velocity), and weather conditions (antecedent moisture) all may influence loading rates to and the retention capabilities of wetlands fed by urban runoff and storm flow. The aim of this research was to examine the effect of these variables on nutrient (nitrogen, phosphorus) and Escherichia coli (E. coli) loading and attenuation along flow paths in urban wetland networks along the Salt River in Phoenix, AZ. Samples were collected for one year along flowpaths through wetlands that formed below six perennially flowing outfalls. Collection took place monthly during baseflow (dry season) conditions, and before and immediately following storm events, in the summer monsoon and winter rainy seasons. Water quality was assessed at the following points: immediately downstream of the outfall, mid-wetland, and downstream of the wetland. For determination of E. coli counts, samples were plated on coliform-selective media (Chromocult) and incubated for 24 hours. Plates were then used to enumerate E. coli. For determination of nutrient concentrations, samples were filtered and frozen until they could be analyzed by ion chromatography and automated wet chemistry. During both summer and winter, total discharge into the wetlands increased during storm events. Concentrations of PO43+, NH4+, and E. coli were significantly higher following storm events than during baseflow conditions, and post-storm peaks in concentration ('pulses') were higher during the summer monsoon than in winter storms. Pulses of pollutants during storms were highest when preceded by hot, dry conditions. NO3- was high in both base and stormflow. E. coli counts and nutrient concentrations dropped along flowpaths through the wetlands, indicating high attenuation capability even during storms. Attenuation of nutrients during baseflow appeared to be a function of microbial processing, while during stormflow, when water retention time in the wetlands was reduced, attenuation was likely explained by other factors, such as sediment adsorption. Potential tradeoffs emerged between removal of NO3- (highest under low dissolved oxygen) and E. coli (highest under high dissolved oxygen) during baseflow. Climate change models project increases in severe droughts and extreme precipitation events for the southwestern United States, which can lead to more sewage leakages and increases in contaminated runoff from impervious surfaces in urban areas. Wetlands are constructed or restored to mitigate microbial contamination of wastewater. Our research indicates that even "accidental" urban wetlands can serve to reduce downstream transport of nutrients and pathogens in storm and wastewater. However, wetland restoration or design targeting increased water retention time may increase the capability of accidental wetlands in this urban desert river channel to remove nutrients and pathogens from stormwater.

Cost-Effectiveness Analysis of Surface Flow Constructed Wetlands (SFCW) for Nutrient Reduction in Drainage Discharge from Agricultural Fields in Denmark.

PubMed

Gachango, F G; Pedersen, S M; Kjaergaard, C

2015-12-01

Constructed wetlands have been proposed as cost-effective and more targeted technologies in the reduction of nitrogen and phosphorous water pollution in drainage losses from agricultural fields in Denmark. Using two pig farms and one dairy farm situated in a pumped lowland catchment as case studies, this paper explores the feasibility of implementing surface flow constructed wetlands (SFCW) based on their cost effectiveness. Sensitivity analysis is conducted by varying the cost elements of the wetlands in order to establish the most cost-effective scenario and a comparison with the existing nutrients reduction measures carried out. The analyses show that the cost effectiveness of the SFCW is higher in the drainage catchments with higher nutrient loads. The range of the cost effectiveness ratio on nitrogen reduction differs distinctively with that of catch crop measure. The study concludes that SFCW could be a better optimal nutrients reduction measure in drainage catchments characterized with higher nutrient loads.

Temporal and spatial distributions of nutrients under the influence of human activities in Sishili Bay, northern Yellow Sea of China.

PubMed

Wang, Yujue; Liu, Dongyan; Dong, Zhijun; Di, Baoping; Shen, Xuhong

2012-12-01

The temporal and spatial distributions of dissolved inorganic nitrogen (DIN), dissolved organic nitrogen (DON), soluble reactive phosphorus (SRP) and dissolved reactive silica (DRSi) together with chlorophyll-a, temperature and salinity were analyzed monthly from December 2008 to March 2010 at four zones in Sishili Bay located in the northern Yellow Sea. The nutrient distribution was impacted by seasonal factors (biotic factors, temperature and wet deposition), physical factors (water exchange) and anthropogenic loadings. The seasonal variations of nutrients were mainly determined by the seasonal factors and the spatial distribution of nutrients was mainly related to water exchange. Anthropogenic loadings for DIN, SRP and DRSi were mainly from point sources, but for DON, non-point sources were also important. Nutrient limitation has changed from DIN in 1997 to SRP and DRSi in 2010, and this has resulted in changes in the dominant red tide species from diatom to dinoflagellates. Copyright © 2012 Elsevier Ltd. All rights reserved.

Nutrient loading to Lewisville Lake, north-central Texas, 1984-87

USGS Publications Warehouse

Gain, W.S.; Baldys, Stanley

1995-01-01

The estimated long-term (1974-89 water years) average annual total nitrogen load (excluding loads from sewage-treatment plants in ungaged areas) is 11,800 pounds per day. The estimated long-term (1974 89 water years) average annual total phosphorus load (excluding loads from sewage-treatment plants in ungaged areas) is 1,100 pounds per day.

Water-quality assessment of the Lower Susquehanna River Basin, Pennsylvania and Maryland; sources, characteristics, analysis and limitations of nutrient and suspended-sediment data, 1975-90

USGS Publications Warehouse

Hainly, R.A.; Loper, C.A.

1997-01-01

This report describes analyses of available information on nutrients and suspended sediment collected in the Lower Susquehanna River Basin during water years 1975-90. Most of the analyses were applied to data collected during water years 1980-89. The report describes the spatial and temporal availability of nutrient and suspended-sediment data and presents a preliminary concept of the spatial and temporal patterns of concentrations and loads within the basin. Where data were available, total and dissolved forms of nitrogen and phosphorus species from precipitation, surface water, ground water, and springwater, and bottom material from streams and reservoirs were evaluated. Suspended-sediment data from streams also were evaluated. The U.S. Geological Survey National Water Information System (NWIS) database was selected as the primary database for the analyses. Precipitation-quality data from the National Atmospheric Deposition Program (NADP) and bottom-material-quality data from the National Uranium Resource Evaluation (NURE) were used to supplement the water-quality data from NWIS. Concentrations of nutrients were available from 3 precipitation sites established for longterm monitoring purposes, 883 wells (854 synoptic areal survey sites and 29 project and research sites), 23 springs (17 synoptic areal survey sites and 6 project and research sites), and 894 bottom-material sites (840 synoptic areal survey sites and 54 project and research sites). Concentrations of nutrients and (or) suspended sediment were available from 128 streams (36 long-term monitoring sites, 51 synoptic areal survey sites, and 41 project and research sites). Concentrations of nutrients and suspended sediment in streams varied temporally and spatially and were related to land use, agricultural practices, and streamflow. A general north-to-south pattern of increasing median nitrate concentrations, from 2 to 5 mg/L, was detected in samples collected in study unit streams. In streams that drain areas dominated by agriculture, concentrations of nutrients and suspended sediment tend to be elevated with respect to those found in areas of other land-use types and are related to the amount of commercial fertilizer and animal manure applied to the area drained by the streams. Animal manure is the dominant source of nitrogen for the streams in the lower, agricultural part of the basin. Concentrations of nutrients in samples from wells varied with season and well depth and were related to hydrogeologic setting. Median concentrations of nitrate were 2.5 and 3.5 mg/L for wells drawing water at depths of 0 to 100 ft and 101 to 200 ft, respectively. The lowest median concentrations for nitrate in ground water from wells were generally found in siliciclastic-bedrock, forested settings of the Ridge and Valley Physiographic Province, and the highest were found in carbonate-bedrock agricultural settings of the Piedmont Physiographic Province. Twenty-five percent of the measurements from wells in carbonate rocks in the Piedmont Physiographic Province exceeded the Pennsylvania drinking-water standard. An estimate of mass balance of nutrient loads within the Lower Susquehanna River Basin was produced by combining the available information on stream loads, atmosphericdeposition loads, commercial-fertilizer applications, animal-manure production, privateseptic-system nonpoint-source loads, and municipal and industrial point-source loads. The percentage of the average annual nitrate load carried in base flow of streams in the study unit ranged from 45 to 76 percent, and the average annual phosphorus load carried in base flow ranged from 20 to 33 percent. Average annual yields of nutrients and suspended sediment from tributary basins are directly related to percentage of drainage area in agriculture and inversely to drainage area. Information required to compute loads of nitrogen and phosphorus were available for all sources except atmospheric deposition, for which only nitrogen data were available. Atmospheric deposition is the dominant source of nitrogen for the mostly forested basins draining the upper half of the study unit. The estimate of total annual nitrogen load to the study unit from precipitation is 98.8 million pounds. Nonpoint and point sources of nutrients were estimated. Nonpoint and point sources combined, including atmospheric deposition, provide a potential annual load of 390 million pounds of nitrogen and 79.5 million pounds of phosphorus. The range of percentages of the estimated nonpoint and point sources that were measured in the stream was 20 to 47 percent for nitrogen and 6 to 14 percent for phosphorus. On the average, the Susquehanna River discharges 141,000 pounds of nitrogen and 7,920 pounds of phosphorus to the Lower Susquehanna River reservoir system each year. About 98 percent of the nitrogen and 60 percent of the phosphorus passes through the reservoir system. Interpretations of available water-quality data and conclusions about the water quality of the Lower Susquehanna River Basin were limited by the scarcity of certain types of water-quality data and current ancillary data. A more complete assessment of the water quality of the basin with respect to nutrients and suspended sediment would be enhanced by the availability of additional data for multiple samples over time from all water environments; samples from streams in the northern and western part of the basin; samples from streams and springs throughout the basin during high base-flow or stormflow conditions; and information on current land-use, and nutrient loading from all types of land-use settings.

Forms and subannual variability of nitrogen and phosphorus loading to global river networks over the 20th century

NASA Astrophysics Data System (ADS)

Vilmin, Lauriane; Mogollón, José M.; Beusen, Arthur H. W.; Bouwman, Alexander F.

2018-04-01

Nitrogen (N) and phosphorus (P) play a major role in the biogeochemical functioning of aquatic systems. N and P transfer to surface freshwaters has amplified during the 20th century, which has led to widespread eutrophication problems. The contribution of different sources, natural and anthropogenic, to total N and P loading to river networks has recently been estimated yearly using the Integrated Model to Assess the Global Environment - Global Nutrient Model (IMAGE-GNM). However, eutrophic events generally result from a combination of physicochemical conditions governed by hydrological dynamics and the availability of specific nutrient forms that vary at subyearly timescales. In the present study, we define for each simulated nutrient source: i) its speciation, and ii) its subannual temporal pattern. Thereby, we simulate the monthly loads of different N (ammonium, nitrate + nitrite, and organic N) and P forms (dissolved and particulate inorganic P, and organic P) to global river networks over the whole 20th century at a half-degree spatial resolution. Results indicate that, together with an increase in the delivery of all nutrient forms to global rivers, the proportion of inorganic forms in total N and P inputs has risen from 30 to 43% and from 56 to 65%, respectively. The high loads originating from fertilized agricultural lands and the increasing proportion of sewage inputs have led to a greater proportion of DIN forms (ammonium and nitrate), that are usually more bioavailable. Soil loss from agricultural lands, which delivers large amounts of particle-bound inorganic P to surface freshwaters, has become the dominant P source, which is likely to lead to an increased accumulation of legacy P in slow flowing areas (e.g., lakes and reservoirs). While the TN:TP ratio of the loads has remained quite stable, the DIN:DIP molar ratio, which is likely to affect algal development the most, has increased from 18 to 27 globally. Human activities have also affected the timing of nutrient delivery to surface freshwaters. Increasing wastewater emissions in growing urban areas induces constant local pressure on the quality of aquatic systems by delivering generally highly bioavailable nutrient forms, even in periods of low runoff.

Data Used in Analyses of Trends, and Nutrient and Suspended-Sediment Loads for Streams in the Southeastern United States, 1973-2005

USGS Publications Warehouse

Staub, Erik L.; Peak, Kelly L.; Tighe, Kirsten C.; Sadorf, Eric M.; Harned, Douglas A.

2010-01-01

Water-quality data from selected surface-water monitoring sites in the Southeastern United States were assessed for trends in concentrations of nutrients, suspended sediment, and major constituents and for in-stream nutrient and suspended-sediment loads for the period 1973-2005. The area of interest includes river basins draining into the southern Atlantic Ocean, the Gulf of Mexico, and the Tennessee River-drainage basins in Hydrologic Regions 03 (South Atlantic - Gulf) and 06 (Tennessee). This data assessment is related to studies of several major river basins as part of the U.S. Geological Survey National Water-Quality Assessment Program, which was designed to assess national water-quality trends during a common time period (1993-2004). Included in this report are data on which trend tests could be performed from 44 U.S. Geological Survey National Water Information System (NWIS) sampling sites. The constituents examined include major ions, nutrients, and suspended sediment; the physical properties examined include pH, specific conductance, dissolved oxygen, and streamflow. Also included are data that were tested for trends from an additional 290 sites from the U.S. Environmental Protection Agency Storage and Retrieval (STORET) database. The trend analyses of the STORET data were limited to total nitrogen and total phosphorus concentrations. Data from 48 U.S. Geological Survey NWIS sampling sites with sufficient water-quality and continuous streamflow data for estimating nutrient and sediment loads are included. The methods of data compilation and modification used prior to performing trend tests and load estimation are described. Results of the seasonal Kendall trend test and the Tobit trend test are given for the 334 monitoring sites, and in-stream load estimates are given for the 48 monitoring sites. Basin characteristics are provided, including regional landscape variables and agricultural nutrient sources (annual variations in cropping and fertilizer use). The data and results presented in this report are in tabular format and can be downloaded and used by environmental researchers and water managers, particularly in the Southeast.

Impact of the river nutrient load variability on the North Aegean ecosystem functioning over the last decades

NASA Astrophysics Data System (ADS)

Tsiaras, K. P.; Petihakis, G.; Kourafalou, V. H.; Triantafyllou, G.

2014-02-01

The impact of river load variability on the North Aegean ecosystem functioning over the last decades (1980-2000) was investigated by means of a coupled hydrodynamic/biogeochemical model simulation. Model results were validated against available SeaWiFS Chl-a and in situ data. The simulated food web was found dominated by small cells, in agreement with observations, with most of the carbon channelled through the microbial loop. Diatoms and dinoflagellates presented a higher relative abundance in the more productive coastal areas. The increased phosphate river loads in the early 80s resulted in nitrogen and silicate deficiency in coastal, river-influenced regions. Primary production presented a decreasing trend for most areas. During periods of increased phosphate/nitrate inputs, silicate deficiency resulted in a relative decrease of diatoms, triggering an increase of dinoflagellates. Such an increase was simulated in the late 90s in the Thermaikos Gulf, in agreement with the observed increased occurrence of Harmful Algal Blooms. Microzooplankton was found to closely follow the relative increase of dinoflagellates under higher nutrient availability, showing a faster response than mesozooplankton. Sensitivity simulations with varying nutrient river inputs revealed a linear response of net primary production and plankton biomass. A stronger effect of river inputs was simulated in the enclosed Thermaikos Gulf, in terms of productivity and plankton composition, showing a significant increase of dinoflagellates relative abundance under increased nutrient loads.

Ensemble modeling informs hypoxia management in the northern Gulf of Mexico.

PubMed

Scavia, Donald; Bertani, Isabella; Obenour, Daniel R; Turner, R Eugene; Forrest, David R; Katin, Alexey

2017-08-15

A large region of low-dissolved-oxygen bottom waters (hypoxia) forms nearly every summer in the northern Gulf of Mexico because of nutrient inputs from the Mississippi River Basin and water column stratification. Policymakers developed goals to reduce the area of hypoxic extent because of its ecological, economic, and commercial fisheries impacts. However, the goals remain elusive after 30 y of research and monitoring and 15 y of goal-setting and assessment because there has been little change in river nitrogen concentrations. An intergovernmental Task Force recently extended to 2035 the deadline for achieving the goal of a 5,000-km 2 5-y average hypoxic zone and set an interim load target of a 20% reduction of the spring nitrogen loading from the Mississippi River by 2025 as part of their adaptive management process. The Task Force has asked modelers to reassess the loading reduction required to achieve the 2035 goal and to determine the effect of the 20% interim load reduction. Here, we address both questions using a probabilistic ensemble of four substantially different hypoxia models. Our results indicate that, under typical weather conditions, a 59% reduction in Mississippi River nitrogen load is required to reduce hypoxic area to 5,000 km 2 The interim goal of a 20% load reduction is expected to produce an 18% reduction in hypoxic area over the long term. However, due to substantial interannual variability, a 25% load reduction is required before there is 95% certainty of observing any hypoxic area reduction between consecutive 5-y assessment periods.

Ensemble modeling informs hypoxia management in the northern Gulf of Mexico

PubMed Central

Bertani, Isabella; Obenour, Daniel R.; Turner, R. Eugene; Forrest, David R.; Katin, Alexey

2017-01-01

A large region of low-dissolved-oxygen bottom waters (hypoxia) forms nearly every summer in the northern Gulf of Mexico because of nutrient inputs from the Mississippi River Basin and water column stratification. Policymakers developed goals to reduce the area of hypoxic extent because of its ecological, economic, and commercial fisheries impacts. However, the goals remain elusive after 30 y of research and monitoring and 15 y of goal-setting and assessment because there has been little change in river nitrogen concentrations. An intergovernmental Task Force recently extended to 2035 the deadline for achieving the goal of a 5,000-km2 5-y average hypoxic zone and set an interim load target of a 20% reduction of the spring nitrogen loading from the Mississippi River by 2025 as part of their adaptive management process. The Task Force has asked modelers to reassess the loading reduction required to achieve the 2035 goal and to determine the effect of the 20% interim load reduction. Here, we address both questions using a probabilistic ensemble of four substantially different hypoxia models. Our results indicate that, under typical weather conditions, a 59% reduction in Mississippi River nitrogen load is required to reduce hypoxic area to 5,000 km2. The interim goal of a 20% load reduction is expected to produce an 18% reduction in hypoxic area over the long term. However, due to substantial interannual variability, a 25% load reduction is required before there is 95% certainty of observing any hypoxic area reduction between consecutive 5-y assessment periods. PMID:28760996

BIOGEOCHEMICAL INDICATORS IN AQUATIC ECOSYSTEMS

EPA Science Inventory

Loadings of excess organic wastes and associated nutrients to aquatic systems has numerous deleterious consequences with respect to the ecosystem services provided by these important ecosystems including perturbation of organic matter and nutrient cycling rates, reduction in diss...

NRMRL'S NUTRIENT-RELATED RISK MANAGEMENT RESEARCH

EPA Science Inventory

Anthropogenic loadings of nutrients into our Nation's atmosphere, aquatic, and terrestrial ecosystems have increased dramatically within the past few decades. Environmental impairments associated with this over fertilization include aquatic habitat loss due to low dissolved oxyge...

FORAGES AND PASTURES SYMPOSIUM: Improving soil health and productivity on grasslands using managed grazing of livestock.

PubMed

Russell, J R; Bisinger, J J

2015-06-01

Beyond grazing, managed grasslands provide ecological services that may offer economic incentives for multifunctional use. Increasing biodiversity of plant communities may maximize net primary production by optimizing utilization of available light, water, and nutrient resources; enhance production stability in response to climatic stress; reduce invasion of exotic species; increase soil OM; reduce nutrient leaching or loading in surface runoff; and provide wildlife habitat. Strategically managed grazing may increase biodiversity of cool-season pastures by creating disturbance in plant communities through herbivory, treading, nutrient cycling, and plant seed dispersal. Soil OM will increase carbon and nutrient sequestration and water-holding capacity of soils and is greater in grazed pastures than nongrazed grasslands or land used for row crop or hay production. However, results of studies evaluating the effects of different grazing management systems on soil OM are limited and inconsistent. Although roots and organic residues of pasture forages create soil macropores that reduce soil compaction, grazing has increased soil bulk density or penetration resistance regardless of stocking rates or systems. But the effects of the duration of grazing and rest periods on soil compaction need further evaluation. Because vegetative cover dissipates the energy of falling raindrops and plant stems and tillers reduce the rate of surface water flow, managing grazing to maintain adequate vegetative cover will minimize the effects of treading on water infiltration in both upland and riparian locations. Through increased diversity of the plant community with alterations of habitat structure, grazing systems can be developed that enhance habitat for wildlife and insect pollinators. Although grazing management may enhance the ecological services provided by grasslands, environmental responses are controlled by variations in climate, soil, landscape position, and plant community resulting in considerable spatial and temporal variation in the responses. Furthermore, a single grazing management system may not maximize livestock productivity and each of the potential ecological services provided by grasslands. Therefore, production and ecological goals must be integrated to identify the optimal grazing management system.

Sources and Transport of Nutrients, Organic Carbon, and Chlorophyll-a in the San Joaquin River Upstream of Vernalis, California, during Summer and Fall, 2000 and 2001

USGS Publications Warehouse

Kratzer, Charles R.; Dileanis, Peter D.; Zamora, Celia; Silva, Steven R.; Kendall, Carol; Bergamaschi, Brian A.; Dahlgren, Randy A.

2004-01-01

Oxidizable materials from the San Joaquin River upstream of Vernalis can contribute to low dissolved oxygen episodes in the Stockton Deep Water Ship Channel that can inhibit salmon migration in the fall. The U.S. Geological Survey collected and analyzed samples at four San Joaquin River sites in July through October 2000 and June through November 2001, and at eight tributary sites in 2001. The data from these sites were supplemented with data from samples collected and analyzed by the University of California at Davis at three San Joaquin River sites and eight tributary sites as part of a separate study. Streamflows in the San Joaquin River were slightly above the long-term average in 2000 and slightly below average in 2001. Nitrate loads at Vernalis in 2000 were above the long-term average, whereas loads in 2001 were close to average. Total nitrogen loads in 2000 were slightly above average, whereas loads in 2001 were slightly below average. Total phosphorus loads in 2000 and 2001 were well below average. These nutrient loads correspond with the flow-adjusted concentration trends--nitrate concentrations significantly increased since 1972 (p 0.05). Loading rates of nutrients and dissolved organic carbon increased in the San Joaquin River in the fall with the release of wetland drainage into Mud Slough and with increased reservoir releases on the Merced River. During August 2000 and September 2001, the chlorophyll-a loading rates and concentrations in the San Joaquin River declined and remained low during the rest of the sampling period. The most significant tributary sources of nutrients were the Tuolumne River, Harding Drain, and Mud Slough. The most significant tributary sources of dissolved organic carbon were Salt Slough, Mud Slough, and the Tuolumne and Stanislaus Rivers. Compared with nutrients and dissolved organic carbon, the tributaries were minor sources of chlorophyll-a, suggesting that most of the chlorophyll-a was produced in the San Joaquin River rather than its tributaries. On the basis of the carbon-to-nitrogen ratios and the d13C of particulate organic matter in the San Joaquin River and tributaries, the particulate organic matter in the river was mostly phytoplankton. On the basis of the d15N values of the particulate organic matter, and of total dissolved nitrogen and nitrate, the nitrate in the San Joaquin River probably was a significant nutrient source for the phytoplankton. The range of d15N and d18O values of nitrate in the San Joaquin River and tributaries suggest that animal waste or sewage was a significant source of nitrate in the river at the time the samples were collected.

Concentrations and Loads of Nutrients and Suspended Sediments in Englesby Brook and Little Otter Creek, Lake Champlain Basin, Vermont, 2000-2005

USGS Publications Warehouse

Medalie, Laura

2007-01-01

The effectiveness of best-management practices (BMPs) in improving water quality in Lake Champlain tributaries was evaluated from 2000 through 2005 on the basis of analysis of data collected on concentrations of total phosphorus and suspended sediment in Englesby Brook, an urban stream in Burlington, and Little Otter Creek, an agricultural stream in Ferrisburg. Data also were collected on concentrations of total nitrogen in the Englesby Brook watershed. In the winter of 2001-2002, one of three planned structural BMPs was installed in the urban watershed. At approximately the same time, a set of barnyard BMPs was installed in the agricultural watershed; however, the other planned BMPs, which included streambank fencing and nutrient management, were not implemented within the study period. At Englesby Brook, concentrations of phosphorus ranged from 0.024 to 0.3 milligrams per liter (mg/L) during base-flow and from 0.032 to 11.8 mg/L during high-flow conditions. Concentrations of suspended sediment ranged from 3 to 189 mg/L during base-flow and from 5 to 6,880 mg/L during high-flow conditions. An assessment of the effectiveness of an urban BMP was made by comparing concentrations and loads of phosphorus and suspended sediment before and after a golf-course irrigation pond in the Englesby Brook watershed was retrofitted with the objective of reducing sediment transport. Results from a modified paired watershed study design showed that the BMP reduced concentrations of phosphorus and suspended sediment during high-flow events - when average streamflow was greater than 3 cubic feet per second. While construction of the BMP did not reduce storm loads of phosphorus or suspended sediment, an evaluation of changes in slope of double-mass curves showing cumulative monthly streamflow plotted against cumulative monthly loads indicated a possible reduction in cumulative loads of phosphorus and suspended sediment after BMP construction. Results from the Little Otter Creek assessment of agricultural BMPs showed that concentrations of phosphorus ranged from 0.016 to 0.141 mg/L during base-flow and from 0.019 to 0.565 mg/L during high-flow conditions at the upstream monitoring station. Concentrations of suspended sediment ranged from 2 to 13 mg/L during base-flow and from 1 to 473 mg/L during high-flow conditions at the upstream monitoring station. Concentrations of phosphorus ranged from 0.018 to 0.233 mg/L during base-flow and from 0.019 to 1.95 mg/L during high-flow conditions at the downstream monitoring station. Concentrations of suspended sediment ranged from 10 to 132 mg/L during base-flow and from 8 to 1,190 mg/L during high-flow conditions at the downstream monitoring station. Annual loads of phosphorus at the downstream monitoring station were significantly larger than loads at the upstream monitoring station, and annual loads of suspended sediment at the downstream monitoring station were larger than loads at the upstream monitoring station for 4 out of 6 years. On a monthly basis, loads of phosphorus and suspended sediment at the downstream monitoring station were significantly larger than loads at the upstream monitoring station. Pairs of concentrations of phosphorus and monthly loads of phosphorus and suspended sediment from the upstream and downstream monitoring stations were evaluated using the paired watershed study design. The only significant reduction between the calibration and treatment periods was for monthly loads of phosphorus; all other evaluations showed no change between periods.

Future climate and land uses effects on flow and nutrient loads of a Mediterranean catchment in South Australia.

PubMed

Shrestha, Manoj K; Recknagel, Friedrich; Frizenschaf, Jacqueline; Meyer, Wayne

2017-07-15

Mediterranean catchments experience already high seasonal variability alternating between dry and wet periods, and are more vulnerable to future climate and land use changes. Quantification of catchment response under future changes is particularly crucial for better water resources management. This study assessed the combined effects of future climate and land use changes on water yield, total nitrogen (TN) and total phosphorus (TP) loads of the Mediterranean Onkaparinga catchment in South Australia by means of the eco-hydrological model SWAT. Six different global climate models (GCMs) under two representative concentration pathways (RCPs) and a hypothetical land use change were used for future simulations. The climate models suggested a high degree of uncertainty, varying seasonally, in both flow and nutrient loads; however, a decreasing trend was observed. Average monthly TN and TP load decreased up to -55% and -56% respectively and were found to be dependent on flow magnitude. The annual and seasonal water yield and nutrient loads may only slightly be affected by envisaged land uses, but significantly altered by intermediate and high emission scenarios, predominantly during the spring season. The combined scenarios indicated the possibility of declining flow in future but nutrient enrichment in summer months, originating mainly from the land use scenario, that may elevate the risk of algal blooms in downstream drinking water reservoir. Hence, careful planning of future water resources in a Mediterranean catchment requires the assessment of combined effects of multiple climate models and land use scenarios on both water quantity and quality. Copyright © 2017 Elsevier B.V. All rights reserved.

Hydrology and water quality of forested lands in eastern North Carolina

Treesearch

G.M. Chescheir; M.E. Lebo; D.M. Amatya; J. Hughes; J.W. Gilliam; R.W. Skaggs; R.B. Herrmann

2003-01-01

Nonpoint sources of nutrients (NPS) are a widespread source of surface water pollution throu&out the United States. Characterizing the sources of this NPS nutrient loading is challenging due to variation in land management practices, physioyaphic setting, site conditions such as soil type, and climatic variation. For nutrients, there is the added challenge of...

Increasing floodplain connectivity through urban stream restoration increases nutrient and sediment retention

USGS Publications Warehouse

McMillan, Sara K.; Noe, Gregory

2017-01-01

Stream restoration practices frequently aim to increase connectivity between the stream channel and its floodplain to improve channel stability and enhance water quality through sediment trapping and nutrient retention. To measure the effectiveness of restoration and to understand the drivers of these functional responses, we monitored five restored urban streams that represent a range of channel morphology and restoration ages. High and low elevation floodplain plots were established in triplicate in each stream to capture variation in floodplain connectivity. We measured ecosystem geomorphic and soil attributes, sediment and nutrient loading, and rates of soil nutrient biogeochemistry processes (denitrification; N and P mineralization) then used boosted regression trees (BRT) to identify controls on sedimentation and nutrient processing. Local channel and floodplain morphology and position within the river network controlled connectivity with increased sedimentation at sites downstream of impaired reaches and at floodplain plots near the stream channel and at low elevations. We observed that nitrogen loading (both dissolved and particulate) was positively correlated with denitrification and N mineralization and dissolved phosphate loading positively influenced P mineralization; however, none of these input rates or transformations differed between floodplain elevation categories. Instead, continuous gradients of connectivity were observed rather than categorical shifts between inset and high floodplains. Organic matter and nutrient content in floodplain soils increased with the time since restoration, which highlights the importance of recovery time after construction that is needed for restored systems to increase ecosystem functions. Our results highlight the importance of restoring floodplains downstream of sources of impairment and building them at lower elevations so they flood frequently, not just during bankfull events. This integrated approach has the greatest potential for increasing trapping of sediment, nutrients, and associated pollutants in restored streams and thereby improving water quality in urban watersheds.

Constituent concentrations, loads, and yields to Beaver Lake, Arkansas, water years 1999-2008

USGS Publications Warehouse

Bolyard, Susan E.; De Lanois, Jeanne L.; Green, W. Reed

2010-01-01

Beaver Lake is a large, deep-storage reservoir used as a drinking-water supply and considered a primary watershed of concern in the State of Arkansas. As such, information is needed to assess water quality, especially nutrient enrichment, nutrient-algal relations, turbidity, and sediment issues within the reservoir system. Water-quality samples were collected at three main inflows to Beaver Lake: the White River near Fayetteville, Richland Creek at Goshen, and War Eagle Creek near Hindsville. Water-quality samples collected over the period represented different flow conditions (from low to high). Constituent concentrations, flow-weighted concentrations, loads, and yields from White River, Richland Creek, and War Eagle Creek to Beaver Lake for water years 1999-2008 were documented for this report. Constituents include total ammonia plus organic nitrogen, dissolved nitrite plus nitrate nitrogen, dissolved orthophosphorus (soluble reactive phosphorus), total phosphorus, total nitrogen, dissolved organic carbon, total organic carbon, and suspended sediment. Linear regression models developed by computer program S-LOADEST were used to estimate loads for each constituent for the 10-year period at each station. Constituent yields and flow-weighted concentrations for each of the three stations were calculated for the study. Constituent concentrations and loads and yields varied with time and varied among the three tributaries contributing to Beaver Lake. These differences can result from differences in precipitation, land use, contributions of nutrients from point sources, and variations in basin size. Load and yield estimates varied yearly during the study period, water years 1999-2008, with the least nutrient and sediment load and yields generally occurring in water year 2006, and the greatest occurring in water year 2008, during a year with record amounts of precipitation. Flow-weighted concentrations of most constituents were greatest at War Eagle Creek near Hindsville than White River near Fayetteville and Richland Creek at Goshen. Loads and yields of most constituents were greater at the War Eagle Creek and White River stations than at the Richland Creek Station.

Streamflow and water-quality data for selected watersheds in the Lake Tahoe basin, California and Nevada, through September 1998

USGS Publications Warehouse

Rowe, T.G.; Saleh, D.K.; Watkins, S.A.; Kratzer, C.R.

2002-01-01

The U.S. Geological Survey, in cooperation with the Tahoe Regional Planning Agency, and the University of California, Davis-Tahoe Research Group, has monitored tributaries in the Lake Tahoe Basin since 1988. This monitoring has characterized streamflow and has determined concentrations of nutrients and suspended sediment, which may have contributed to loss of clarity in Lake Tahoe. The Lake Tahoe Interagency Monitoring Program was developed to collect water-quality data in the basin. In 1998, the tributary-monitoring program included 41 water-quality stations in 14 of the 63 watersheds totaling half the area tributary to Lake Tahoe. The monitored watershed areas range from 1.08 square miles for First Creek to 56.5 square miles for the Upper Truckee River.Annual and unit runoff for 20 primary and secondary streamflow gaging stations in 10 selected watersheds are described. Water years 1988-98 were used to compare runoff data. The Upper Truckee River at South Lake Tahoe, Calif., had the highest annual runoff and Logan House Creek near Glenbrook, Nev., had the lowest. Blackwood Creek near Tahoe City, Calif., had the highest unit runoff and Logan House Creek had the lowest. The highest instantaneous peak flow was recorded at Upper Truckee River at South Lake Tahoe during the January 2, 1997, flood event.Certain water-quality measurements were made in the field. Ranges and median values of those measurements are described for 41 stations. Water temperature ranged from 0 to 23?C. Specific conductance ranged from 13 to 900 microsiemens per centimeter at 25?C. pH ranged from 6.7 to 10.6. Dissolved-oxygen concentrations ranged from 5.2 to 12.6 mg/L and from 70 to 157 percent of saturation.Loads, yields, and trends of nutrients and suspended sediment during water years 1988-98 at the streamflow gaging stations also are described. The Upper Truckee River at South Lake Tahoe had the largest median monthly load for five of the six measured nutrients and of suspended sediment, while Trout Creek at South Lake Tahoe had the largest median monthly load for the remaining nutrient. Logan House Creek near Glenbrook had the smallest median monthly loads for all nutrients and suspended sediment. Seasonal load summaries at selected stations showed nutrient and suspended-sediment loads were greatest in the spring months of April, May and June and least in the summer months of July, August, and September. Monthly load comparisons also were described for five watersheds with multiple stations.Incline Creek had the highest combined rank for all nutrients and sediment. Incline Creek had the largest monthly yields for dissolved nitrite plus nitrate nitrogen and soluble reactive phosphorus. Third Creek had the second highest combined rank and had the largest monthly yields for total nitrogen, total phosphorus, biologically reactive iron, and suspended sediment. Edgewood Creek had the largest monthly yield for dissolved ammonia nitrogen. Logan House Creek had the lowest combined rank and the smallest monthly yields for all nutrients and sediment.Trends in concentrations are either decreasing or not significant for all nutrients in all sampled watersheds, with the exception of biologically reactive iron. Biologically reactive iron and suspended sediment show an increasing trend in three watersheds and decreasing or no significant trend in the other seven watersheds.

The Regionalization of National-Scale SPARROW Models for Stream Nutrients

USGS Publications Warehouse

Schwarz, G.E.; Alexander, R.B.; Smith, R.A.; Preston, S.D.

2011-01-01

This analysis modifies the parsimonious specification of recently published total nitrogen (TN) and total phosphorus (TP) national-scale SPAtially Referenced Regressions On Watershed attributes models to allow each model coefficient to vary geographically among three major river basins of the conterminous United States. Regionalization of the national models reduces the standard errors in the prediction of TN and TP loads, expressed as a percentage of the predicted load, by about 6 and 7%. We develop and apply a method for combining national-scale and regional-scale information to estimate a hybrid model that imposes cross-region constraints that limit regional variation in model coefficients, effectively reducing the number of free model parameters as compared to a collection of independent regional models. The hybrid TN and TP regional models have improved model fit relative to the respective national models, reducing the standard error in the prediction of loads, expressed as a percentage of load, by about 5 and 4%. Only 19% of the TN hybrid model coefficients and just 2% of the TP hybrid model coefficients show evidence of substantial regional specificity (more than ??100% deviation from the national model estimate). The hybrid models have much greater precision in the estimated coefficients than do the unconstrained regional models, demonstrating the efficacy of pooling information across regions to improve regional models. ?? 2011 American Water Resources Association. This article is a U.S. Government work and is in the public domain in the USA.

Suspended-sediment and nutrient loads for Waiakea and Alenaio Streams, Hilo, Hawaii, 2003-2006

USGS Publications Warehouse

Presley, Todd K.; Jamison, Marcael T.J.; Nishimoto, Dale C.

2008-01-01

Suspended sediment and nutrient samples were collected during wet-weather conditions at three sites on two ephemeral streams in the vicinity of Hilo, Hawaii during March 2004 to March 2006. Two sites were sampled on Waiakea Stream at 80- and 860-foot altitudes during March 2004 to August 2005. One site was sampled on Alenaio Stream at 10-foot altitude during November 2005 to March 2006. The sites were selected to represent different land uses and land covers in the area. Most of the drainage area above the upper Waiakea Stream site is conservation land. The drainage areas above the lower site on Waiakea Stream, and the site on Alenaio Stream, are a combination of conservation land, agriculture, rural, and urban land uses. In addition to the sampling, continuous-record streamflow sites were established at the three sampling sites, as well as an additional site on Alenaio Stream at altitude of 75 feet and 0.47 miles upstream from the sampling site. Stage was measured continuously at 15-minute intervals at these sites. Discharge, for any particular instant, or for selected periods of time, were computed based on a stage-discharge relation determined from individual discharge measurements. Continuous records of discharge were computed at the two sites on Waiakea Stream and the upper site on Aleniao Stream. Due to non-ideal hydraulic conditions within the channel of Alenaio Stream, a continuous record of discharge was not computed at the lower site on Alenaio Stream where samples were taken. Samples were analyzed for suspended sediment, and the nutrients total nitrogen, dissolved nitrite plus nitrate, and total phosphorus. Concentration data were converted to instantaneous load values: loads are the product of discharge and concentration, and are presented as tons per day for suspended sediment or pounds per day for nutrients. Daily-mean loads were computed by estimating concentrations relative to discharge using graphical constituent loading analysis techniques. Daily-mean loads were computed at the two Waiakea Stream sampling sites for the analyzed constituents, during the period October 1, 2003 to September 30, 2005. No record of daily-mean load was computed for the Alenaio Stream sampling site due to the problems with computing a discharge record. The maximum daily-mean loads for the upper site on Waiakea Stream for suspended sediment was 79 tons per day, and the maximum daily-mean loads for total nitrogen, dissolved nitrite plus nitrate, and total phosphorus were 1,350, 13, and 300 pounds per day, respectively. The maximum daily-mean loads for the lower site on Waiakea Stream for suspended sediment was 468 tons per day, and the maximum daily-mean loads for total nitrogen, nitrite plus nitrate, and total phosphorus were 913, 8.5, and 176 pounds per day, respectively. From the estimated continuous daily-mean load record, all of the maximum daily-mean loads occurred during October 2003 and September 2004, except for suspended sediment load for the lower site, which occurred on September 15, 2005. Maximum values were not all caused by a single storm event. Overall, the record of daily-mean loads showed lower loads during storm events for suspended sediments and nutrients at the downstream site of Waiakea Stream during 2004 than at the upstream site. During 2005, however, the suspended sediment loads were higher at the downstream site than the upstream site. Construction of a flood control channel between the two sites in 2005 may have contributed to the change in relative suspended-sediment loads.

Organic matter degradation drives benthic cyanobacterial mat abundance on Caribbean coral reefs.

PubMed

Brocke, Hannah J; Polerecky, Lubos; de Beer, Dirk; Weber, Miriam; Claudet, Joachim; Nugues, Maggy M

2015-01-01

Benthic cyanobacterial mats (BCMs) are impacting coral reefs worldwide. However, the factors and mechanisms driving their proliferation are unclear. We conducted a multi-year survey around the Caribbean island of Curaçao, which revealed highest BCM abundance on sheltered reefs close to urbanised areas. Reefs with high BCM abundance were also characterised by high benthic cover of macroalgae and low cover of corals. Nutrient concentrations in the water-column were consistently low, but markedly increased just above substrata (both sandy and hard) covered with BCMs. This was true for sites with both high and low BCM coverage, suggesting that BCM growth is stimulated by a localised, substrate-linked release of nutrients from the microbial degradation of organic matter. This hypothesis was supported by a higher organic content in sediments on reefs with high BCM coverage, and by an in situ experiment which showed that BCMs grew within days on sediments enriched with organic matter (Spirulina). We propose that nutrient runoff from urbanised areas stimulates phototrophic blooms and enhances organic matter concentrations on the reef. This organic matter is transported by currents and settles on the seabed at sites with low hydrodynamics. Subsequently, nutrients released from the organic matter degradation fuel the growth of BCMs. Improved management of nutrients generated on land should lower organic loading of sediments and other benthos (e.g. turf and macroalgae) to reduce BCM proliferation on coral reefs.

Quantifying the Temporal Inequality of Nutrient Loads with a Novel Metric

NASA Astrophysics Data System (ADS)

Gall, H. E.; Schultz, D.; Rao, P. S.; Jawitz, J. W.; Royer, M.

2015-12-01

Inequality is an emergent property of many complex systems. For a given series of stochastic events, some events generate a disproportionately large contribution to system responses compared to other events. In catchments, such responses cause streamflow and solute loads to exhibit strong temporal inequality, with the vast majority of discharge and solute loads exported during short periods of time during which high-flow events occur. These periods of time are commonly referred to as "hot moments". Although this temporal inequality is widely recognized, there is currently no uniform metric for assessing it. We used a novel application of Lorenz Inequality, a method commonly used in economics to quantify income inequality, to quantify the spatial and temporal inequality of streamflow and nutrient (nitrogen and phosphorus) loads exported to the Chesapeake Bay. Lorenz Inequality and the corresponding Gini Coefficient provide an analytical tool for quantifying inequality that can be applied at any temporal or spatial scale. The Gini coefficient (G) is a formal measure of inequality that varies from 0 to 1, with a value of 0 indicating perfect equality (i.e., fluxes and loads are constant in time) and 1 indicating perfect inequality (i.e., all of the discharge and solute loads are exported during one instant in time). Therefore, G is a simple yet powerful tool for providing insight into the temporal inequality of nutrient transport. We will present the results of our detailed analysis of streamflow and nutrient time series data collected since the early 1980's at 30 USGS gauging stations in the Chesapeake Bay watershed. The analysis is conducted at an annual time scale, enabling trends and patterns to be assessed both temporally (over time at each station) and spatially (for the same period of time across stations). The results of this analysis have the potential to create a transformative new framework for identifying "hot moments", improving our ability to temporally and spatially target implementation of best management practices to ultimately improve water quality in the Chesapeake Bay. This method also provides insight into the temporal scales at which hydrologic and biogeochemical variability dominate nutrient export dynamics.

A modeling study examining the impact of nutrient boundaries ...

EPA Pesticide Factsheets

A mass balance eutrophication model, Gulf of Mexico Dissolved Oxygen Model (GoMDOM), has been developed and applied to describe nitrogen, phosphorus and primary production in the Louisiana shelf of the Gulf of Mexico. Features of this model include bi-directional boundary exchanges, an empirical site-specific light attenuation equation, estimates of 56 river loads and atmospheric loads. The model was calibrated for 2006 by comparing model output to observations in zones that represent different locations in the Gulf. The model exhibited reasonable skill in simulating the phosphorus and nitrogen field data and primary production observations. The model was applied to generate a nitrogen mass balance estimate, to perform sensitivity analysis to compare the importance of the nutrient boundary concentrations versus the river loads on nutrient concentrations and primary production within the shelf, and to provide insight into the relative importance of different limitation factors on primary production. The mass budget showed the importance of the rivers as the major external nitrogen source while the atmospheric load contributed approximately 2% of the total external load. Sensitivity analysis showed the importance of accurate estimates of boundary nitrogen concentrations on the nitrogen levels on the shelf, especially at regions further away from the river influences. The boundary nitrogen concentrations impacted primary production less than nitrogen concent

Stream nitrate responses to hydrological forcing and climate change in northern forests of the USA (Invited)

NASA Astrophysics Data System (ADS)

Sebestyen, S. D.; Campbell, J. L.; Shanley, J. B.; Pourmokhtarian, A.; Driscoll, C. T.; Boyer, E. W.

2009-12-01

There is a need to understand how climate variability and change affect nutrient delivery to surface waters. We analyzed long-term records of hydrochemical data to explore how the forms, concentrations, and loadings of nitrogen in forest streams throughout the northern USA vary with catchment wetness. We considered projected changes in growing season length and precipitation patterns to simulate future climate scenarios and to assess how stream nitrate loading responds to hydrological forcing under different climate change scenarios. At the Sleepers River Research Watershed in northeastern Vermont, model results suggest that stream nutrient loadings over the next century will respond to hydrological forcing during climate change that affects the amount of water that flows through the landscape. For example, growing season stream water yield (+20%) and nitrate loadings (+57%) increase in response to greater amounts of precipitation (+28%) during a warmer climate with a longer growing season (+43 days). We further explore these findings by presenting model results from a biogeochemical process model (PnET-BGC) to separate changes that are due to biogeochemical cycling and the effects of hydrological forcing. Our findings suggest that nitrogen cycling and transport will intensify during anthropogenic climate forcing, thereby affecting the timing and magnitude of annual stream nutrient loadings in northern forests of the USA.

Responses of stream nitrate and dissolved organic carbon loadings to hydrological forcing and climate change in an upland forest of the northeast USA

USGS Publications Warehouse

Sebestyen, Stephen D.; Boyer, Elizabeth W.; Shanley, James B.

2009-01-01

[1] In coming decades, higher annual temperatures, increased growing season length, and increased dormant season precipitation are expected across the northeastern United States in response to anthropogenic forcing of global climate. We synthesized long-term stream hydrochemical data from the Sleepers River Research Watershed in Vermont, United States, to explore the relationship of catchment wetness to stream nitrate and DOC loadings. We modeled changes in growing season length and precipitation patterns to simulate future climate scenarios and to assess how stream nutrient loadings respond to climate change. Model results for the 2070–2099 time period suggest that stream nutrient loadings during both the dormant and growing seasons will respond to climate change. During a warmer climate, growing season stream fluxes (runoff +20%, nitrate +57%, and DOC +58%) increase as more precipitation (+28%) and quick flow (+39%) occur during a longer growing season (+43 days). During the dormant season, stream water and nutrient loadings decrease. Net annual stream runoff (+8%) and DOC loading (+9%) increases are commensurate with the magnitude of the average increase of net annual precipitation (+7%). Net annual stream water and DOC loadings are primarily affected by increased dormant season precipitation. In contrast, decreased annual loading of stream nitrate (−2%) reflects a larger effect of growing season controls on stream nitrate and the effects of lengthened growing seasons in a warmer climate. Our findings suggest that leaching of nitrate and DOC from catchment soils will be affected by anthropogenic climate forcing, thereby affecting the timing and magnitude of annual stream loadings in the northeastern United States.

Responses of stream nitrate and DOC loadings to hydrological forcing and climate change in an upland forest of the northeastern United States

USGS Publications Warehouse

Sebestyen, S.D.; Boyer, E.W.; Shanley, J.B.

2009-01-01

In coming decades, higher annual temperatures, increased growing season length, and increased dormant season precipitation are expected across the northeastern United States in response to anthropogenic forcing of global climate. We synthesized long-term stream hydrochemical data from the Sleepers River Research Watershed in Vermont, United States, to explore the relationship of catchment wetness to stream nitrate and DOC loadings. We modeled changes in growing season length and precipitation patterns to simulate future climate scenarios and to assess how stream nutrient loadings respond to climate change. Model results for the 2070-2099 time period suggest that stream nutrient loadings during both the dormant and growing seasons will respond to climate change. During a warmer climate, growing season stream fluxes (runoff+20%, nitrate +57%, and DOC +58%) increase as more precipitation (+28%) and quick flow (+39%) occur during a longer growing season (+43 days). During the dormant season, stream water and nutrient loadings decrease. Net annual stream runoff (+8%) and DOC loading (+9%) increases are commensurate with the magnitude of the average increase of net annual precipitation (+7%). Net annual stream water and DOC loadings are primarily affected by increased dormant season precipitation. In contrast, decreased annual loading of stream nitrate (-2%) reflects a larger effect of growing season controls on stream nitrate and the effects of lengthened growing seasons in a warmer climate. Our findings suggest that leaching of nitrate and DOC from catchment soils will be affected by anthropogenic climate forcing, thereby affecting the timing and magnitude of annual stream loadings in the northeastern United States. Copyright 2009 by the American Geophysical Union.