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Sample records for refuse derived fuel

  1. Refuse-derived fuels

    SciTech Connect

    Krause, H.H.

    1980-10-01

    The rationale for energy recovery from municipal refuse is discussed, and planning for future installations for this purpose is cited. The composition and energy content of bulk waste, shredded refuse, and pelletized material are compared. Potential problems encountered with refuse combustion in the areas of slagging, corrosion, and stack emissions are outlined.

  2. Refuse-derived fuels

    NASA Astrophysics Data System (ADS)

    Krause, H. H.

    1980-09-01

    The rationale for energy recovery from municipal refuse is discussed, and planning for future installations for this purpose is cited. The composition and energy content of bulk waste, shredded refuse, and pelletized material are compared. Potential problems encountered with refuse combustion in the areas of slagging, corrosion, and stack emissions are outlined.

  3. Binder enhanced refuse derived fuel

    DOEpatents

    Daugherty, Kenneth E.; Venables, Barney J.; Ohlsson, Oscar O.

    1996-01-01

    A refuse derived fuel (RDF) pellet having about 11% or more particulate calcium hydroxide which is utilized in a combustionable mixture. The pellets are used in a particulate fuel bring a mixture of 10% or more, on a heat equivalent basis, of the RDF pellet which contains calcium hydroxide as a binder, with 50% or more, on a heat equivalent basis, of a sulphur containing coal. Combustion of the mixture is effective to produce an effluent gas from the combustion zone having a reduced SO.sub.2 and polycyclic aromatic hydrocarbon content of effluent gas from similar combustion materials not containing the calcium hydroxide.

  4. Jet flames of a refuse derived fuel

    SciTech Connect

    Weber, Roman; Kupka, Tomasz; Zajac, Krzysztof

    2009-04-15

    This paper is concerned with combustion of a refuse derived fuel in a small-scale flame. The objective is to provide a direct comparison of the RDF flame properties with properties of pulverized coal flames fired under similar boundary conditions. Measurements of temperature, gas composition (O{sub 2}, CO{sub 2}, CO, NO) and burnout have demonstrated fundamental differences between the coal flames and the RDF flames. The pulverized coals ignite in the close vicinity of the burner and most of the combustion is completed within the first 300 ms. Despite the high volatile content of the RDF, its combustion extends far into the furnace and after 1.8 s residence time only a 94% burnout has been achieved. This effect has been attributed not only to the larger particle size of fluffy RDF particles but also to differences in RDF volatiles if compared to coal volatiles. Substantial amounts of oily tars have been observed in the RDF flames even though the flame temperatures exceeded 1300 C. The presence of these tars has enhanced the slagging propensity of RDF flames and rapidly growing deposits of high carbon content have been observed. (author)

  5. Utilization of Refuse Derived Fuels by the United States Navy,

    DTIC Science & Technology

    1983-07-01

    makes the use of landfills less desirable for solid waste disposal. As such, new disposal methods that are environmentally safe and economi- cally...fuel for use in a heat recove:y system. Refuse * derived fuels (MDF) can be in the form of raw rieiuse, %leaksified riuse, puw- dered refuse, gas, or...maximum allowable as specified in 40 CFR 261.24. A URI can theoretically produce steam at a lower cost than conventional methods being used today. These

  6. Refuse-derived fuels still a long-term goal

    SciTech Connect

    Singh, R.

    1981-11-17

    A report on the Institution of Civil Engineers' two-day international symposium held in London in November, titled ''The practical implications of the reuse of solid wastes''. Topics dealt with included: systems for mechanical separation, reclamation and re- use of secondary materials; refuse-derived fuels; use of raw refuse in land reclamation; methane recovery from landfills and direct landfill as a major disposal option.

  7. Utilization of refuse derived fuels by the United States Navy

    SciTech Connect

    Lehr, D.L.

    1983-07-01

    The Resource Conservation and Recovery Act and the Safe Drinking Water Act are forcing those in charge of landfills to adhere to more stringent operating standards. This, along with the growing scarcity of landfill availability, makes the use of landfills less desirable for solid waste disposal. As such, new disposal methods that are environmentally safe and economically practical must be found. One alternative, that is not really new but which has gained renewed interest, is incineration. The Resource Conservation and Recovery Act also requires that government agencies should direct their installations to recover as many resources as possible. Therefore if incineration is to be implemented, heat recovery should be incorporated into the system. There are several processes available to convert raw refuse into a fuel for use in a heat recovery system. Refuse derived fuels (RDF) can be in the form of raw refuse, densified refuse, powdered refuse, gas, or pyrolytic oil. The only form of RDF that is economically feasible for systems designed to process less than 200 TPD (tons per day) is raw refuse. Most Navy bases generate far less than 200 TPD of solid waste and therefore the Navy has focused most of its attention on modular heat recovery incinerator (HRI) systems that utilize raw refuse as fuel.

  8. Energetic utilisation of refuse derived fuels from landfill mining.

    PubMed

    Rotheut, Martin; Quicker, Peter

    2017-02-19

    The residence of municipal solid waste within a landfill body results in a significant change of material properties. Experiences with the energetic utilisation of the burnable fractions from formerly landfilled waste are hardly documented, the influence of refuse derived fuels (RDF) from such materials on the performance of modern waste-to-energy plants is not sufficiently described in scientific literature. Therefore this study focuses on the energetic utilisation of refuse derived fuel from landfilled waste, processed in a mechanical waste treatment facility, and the impact of the material on the operation of the incineration plant. Additionally, the possibility of direct combustion of non-pre-treated excavated landfill material has been evaluated in the same facility. First, sampling and analysis of the fuel has been carried out. Based on this, a large-scale combustion experiment was planned and conducted in an industrial waste-to-energy plant. Steam mass flow rate, concentration of harmful substances in the raw gas, as well as total emissions of the facility have been monitored in detail. Furthermore, the influence of the landfilled material on the additive consumption has been determined. The combustion residues (bottom ash) were also sampled and analysed. Based on the evaluation of operating data and analysis of both fuel and residue, suitable thermal treatment approaches for the refuse-derived fuel and the non-pre-treated excavated material have been assessed.

  9. Refuse derived fuels: New technologies for successful operations

    SciTech Connect

    Ohlsson, O.O.

    1988-01-01

    The rising cost of refuse disposal, coupled with the decreasing availability of land suitable for the siting of new landfills have greatly accelerated the use of refuse-derived fuel (RDF) processing systems as a viable technology of the disposal of our municipal solid waste. The energy products produces by an RDF processing facility-electricity and/or steam, as well as the recovery of other valuable materials from the waste stream, coupled with the inherent flexibility of the RDF technology to be used in varying forms, over a wide range of combustion technologies, makes it an extremely desirable waste-to-energy system. Use of an RDF prepared fuel product can also provide a potentially beneficial reduction of air emissions, and trace metals in the ash when compared to the burning of unprocessed solid waste. This paper discusses the problems which have been encountered in the past with RDF systems; the current status of these facilities including institutional considerations and system economics; and the future potential of RDF processing systems. 6 refs., 5 figs.

  10. Densified refuse derived fuel: An alternative energy source

    SciTech Connect

    Ohlsson, O. ); Daugherty, K.E. ); Venables, B.J. )

    1986-01-01

    The objective of this research effort is to produce an environmentally acceptable, chemically/biologically stable, and storable densified refuse derived fuel (dRDF) pellet. To accomplish this, a suitable binder(s) must be used. Over 150 binders were investigated by a laboratory screening procedure. Thirteen binder/binder combinations of the initial group of 150 binders were selected for further pilot plant studies. Approximately seven tons of RDF from Ames, Iowa and Refcom, Pompano Beach, Florida were pelletized in the summer-1985 in a series of experiments at the Jacksonville, Florida Naval Air Station using these binder. The pelletized dRDF was then subjected to a battery of chemical and physical tests. Results to date and work to be accomplished during the next fiscal year will be discussed. 2 figs., 2 tabs.

  11. Densified refuse derived fuel as a power source

    SciTech Connect

    Daugherty, K.E.; Safa, A.; Ohlsson, O.; Venables, B.J.

    1986-04-01

    This project is aimed at producing environmentally acceptable, chemically/biologically stable, and storable densified- Refuse Derived Fuel (d-RDF) pellets which are similar to lignite coal. To accomplish this, a suitable binder (s) must be used. Over 100 binders were investigated by a laboratory screening procedure. Six binding materials were selected for pilot plant/commercial scale studies. Approximately seven tons of RDF from Ames, Iowa and Refcom, Pompano Beach, Florida were pelletized in the summer-1985 in a series of experiments at the Jacksonville, Florida Naval Air Station using these binders. The pelletized d-RDF was then subjected to a battery of chemical and physical tests. Results to date are discussed.

  12. Production, quality and quality assurance of Refuse Derived Fuels (RDFs).

    PubMed

    Sarc, R; Lorber, K E

    2013-09-01

    This contribution describes characterization, classification, production, application and quality assurance of Refuse Derived Fuels (RDFs) that are increasingly used in a wide range of co-incineration plants. It is shown in this paper, that the fuel-parameter, i.e. net calorific value [MJ/kg(OS)], particle size d(90) or d(95) [mm], impurities [w%], chlorine content [w%], sulfur content [w%], fluorine content [w%], ash content [w%], moisture [w%] and heavy metals content [mg/kg(DM)], can be preferentially used for the classification of different types of RDF applied for co-incineration and substitution of fossil-fuel in different industial sectors. Describing the external production of RDF by processing and confectioning of wastes as well as internal processing of waste at the incineration plant, a case study is reported on the application of RDF made out of different household waste fractions in a 120,000t/yr Waste to Energy (WtE) circulating fluidized bed (CFB) incinerator. For that purpose, delivered wastes, as well as incinerator feedstock material (i.e. after internal waste processing) are extensively investigated. Starting with elaboration of sampling plan in accordance with the relevant guidelines and standards, waste from different suppliers was sampled. Moreover, manual sorting analyses and chemical analyses were carried out. Finally, results of investigations are presented and discussed in the paper.

  13. An approach to determining the economic feasibility of refuse-derived fuels and materials recovery processing

    SciTech Connect

    Gershman, H.W.

    1980-06-01

    An approach for determining the economic feasibility of refuse-derived fuel production and the recovery of various materials is demonstrated, using data developed for the metropolitan Washington, D.C., area as input. The processing facility, designed to handle 650 tpd of refuse, is described. Since materials revenues can be predicted with a higher degree of certainty than refuse fuel revenues, it is necessary to determine what revenues the sale of solid waste fuel will have to generate for projected economics to be the same as an alternative disposal practice. (1 diagram, 8 references, 6 tables)

  14. Results of emissions testing while burning densified refuse derived fuel, Dordt College, Sioux Center, Iowa

    SciTech Connect

    Not Available

    1989-10-01

    Pacific Environmental Services, Inc. provided engineering and source testing services to the Council of Great Lake Governors to support their efforts in promoting the development and utilization of densified refuse derived fuels (d-RDF) and pelletized wastepaper fuels in small steam generating facilities. The emissions monitoring program was designed to provide a complete air emissions profile while burning various refuse derived fuels. The specific goal of this test program was to conduct air emissions tests at Dordt College located in Sioux Center, Iowa and to identify a relationship between fuel types and emission characteristics. The sampling protocol was carried out June 12 through June 20, 1989 on boiler {number sign}4. This unit had been previously modified to burn d-RDF. The boiler was not equipped with any type of air pollution control device so the emissions samples were collected from the boiler exhaust stack on the roof of the boilerhouse. The emissions that were sampled included: particulates; PM{sub 10} particulates; hydrochloric acid; dioxins; furans; polychlorinated biphenyls (PCB); metals and continuous monitors for CO, CO{sub 2}O{sub 2}SO{sub x}NO{sub x} and total hydrocarbons. Grab samples of the fuels were collected, composited and analyzed for heating value, moisture content, proximate and ultimate analysis, ash fusion temperature, bulk density and elemental ash analysis. Grab samples of the boiler ash were also collected and analyzed for total hydrocarbons total dioxins, total furans, total PCBs and heavy metals. 77 figs., 20 tabs.

  15. Hydrogen gas generation from refuse-derived fuel (RDF) under wet conditions.

    PubMed

    Sakka, Makiko; Kimura, Tetsuya; Sakka, Kazuo; Ohmiya, Kunio

    2004-02-01

    An explosion has recently occurred at a silo containing refuse-derived fuels (RDF) in Japan. There is a possibility that microorganisms are involved in generation of combustible gas from RDF and this study was aimed at showing the presence of bacteria that can ferment RDF pellets. All RDF samples tested contained a relatively high number of viable bacterial cells, 1.4x10(5) to 3.2x10(6) viable cells/g. These bacteria in the RDF samples fermented them to generate heat and hydrogen gas.

  16. Steam gasification of tyre waste, poplar, and refuse-derived fuel: A comparative analysis

    SciTech Connect

    Galvagno, S. Casciaro, G.; Casu, S.; Martino, M.; Mingazzini, C.; Russo, A.; Portofino, S.

    2009-02-15

    In the field of waste management, thermal disposal is a treatment option able to recover resources from 'end of life' products. Pyrolysis and gasification are emerging thermal treatments that work under less drastic conditions in comparison with classic direct combustion, providing for reduced gaseous emissions of heavy metals. Moreover, they allow better recovery efficiency since the process by-products can be used as fuels (gas, oils), for both conventional (classic engines and heaters) and high efficiency apparatus (gas turbines and fuel cells), or alternatively as chemical sources or as raw materials for other processes. This paper presents a comparative study of a steam gasification process applied to three different waste types (refuse-derived fuel, poplar wood and scrap tyres), with the aim of comparing the corresponding yields and product compositions and exploring the most valuable uses of the by-products.

  17. Steam gasification of tyre waste, poplar, and refuse-derived fuel: a comparative analysis.

    PubMed

    Galvagno, S; Casciaro, G; Casu, S; Martino, M; Mingazzini, C; Russo, A; Portofino, S

    2009-02-01

    In the field of waste management, thermal disposal is a treatment option able to recover resources from "end of life" products. Pyrolysis and gasification are emerging thermal treatments that work under less drastic conditions in comparison with classic direct combustion, providing for reduced gaseous emissions of heavy metals. Moreover, they allow better recovery efficiency since the process by-products can be used as fuels (gas, oils), for both conventional (classic engines and heaters) and high efficiency apparatus (gas turbines and fuel cells), or alternatively as chemical sources or as raw materials for other processes. This paper presents a comparative study of a steam gasification process applied to three different waste types (refuse-derived fuel, poplar wood and scrap tyres), with the aim of comparing the corresponding yields and product compositions and exploring the most valuable uses of the by-products.

  18. An approach to determining the economic feasibility of refuse-derived fuel and materials recovery processing

    NASA Astrophysics Data System (ADS)

    Gershman, H. W.

    1980-06-01

    An approach for determining the economic feasibility of refuse-derived fuel production and the recovery of materials is presented. This information is based on data developed for the metropolitan Washington, D.C. area as input for the consideration of a regional resource recovery program which would eventually encompass 4000 t/day of municipal solid waste; it is designed to recover refuse-derived fuel (RDF), ferrous and nonferrous metals, flint and color-mixed glass cullet, color-mixed glass fines, and waste newspapers. The planning process requires estimates of recovery product revenues and of process feasibility; since materials revenues can be predicted with a greater degree of certainty than RDF revenues, it becomes necessary to determine what revenues will be required from the sale of RDF so that predicted economics can be the same as the alternative disposal practice. A technique is described which will assist the decisionmaker in evaluating the economic feasibility of the proposed project by determining the RDF 'Indifference Value'.

  19. Development and evaluation of lime enhanced refuse-derived fuel (RDF) pellets

    SciTech Connect

    Ohlsson, O.O.

    1996-12-31

    The disposal of municipal solid waste (MSW) is of increasing concern for municipalities and state governments throughout the US. There are two technologies currently in use for the combustion of MSW: (1) mass burning in which unprocessed MSW is burned in a heat recovery furnace, and (2) a refuse-derived fuel (RDF) product, which consists of the organic (combustible) fraction of MSW which has been processed to produce a more homogeneous fuel product than raw MSW. The RDF is either marketed to outside users or combusted on-site in a dedicated or existing furnace. In an attempt to alleviate the problems encountered with RDF as a feedstock, Argonne National Laboratory (ANL) and the University of North Texas (UNT) under the sponsorship of the US Department of Energy (DOE) began a multi-phase research study to investigate the development of a low-cost binder that would improve the quality of RDF pellets.

  20. Sample preparation for thermo-gravimetric determination and thermo-gravimetric characterization of refuse derived fuel.

    PubMed

    Robinson, T; Bronson, B; Gogolek, P; Mehrani, P

    2016-02-01

    Thermo-gravimetric analysis (TGA) is a useful method for characterizing fuels. In the past it has been applied to the study of refuse derived fuel (RDF) and related materials. However, the heterogeneity of RDF makes the preparation of small representative samples very difficult and this difficulty has limited the effectiveness of TGA for characterization of RDF. A TGA method was applied to a variety of materials prepared from a commercially available RDF using a variety of procedures. Applicability of TGA method to the determination of the renewable content of RDF was considered. Cryogenic ball milling was found to be an effective means of preparing RDF samples for TGA. When combined with an effective sample preparation, TGA could be used as an alternative method for assessing the renewable content of RDF.

  1. Comparison of coal/solid recovered fuel (SRF) with coal/refuse derived fuel (RDF) in a fluidised bed reactor

    SciTech Connect

    Wagland, S.T.; Kilgallon, P.; Coveney, R.; Garg, A.; Smith, R.; Longhurst, P.J.; Pollard, S.J.T.; Simms, N.

    2011-06-15

    An experimental study was undertaken to compare the differences between municipal solid waste (MSW) derived solid recovered fuel (SRF) (complying with CEN standards) and refuse derived fuel (RDF). Both fuels were co-combusted with coal in a 50 kW fluidised bed combustor and the metal emissions were compared. Synthetic SRF was prepared in the laboratory by grinding major constituents of MSW such as paper, plastic, textile and wood. RDF was obtained from a local mechanical treatment plant. Heavy metal emissions in flue gas and ash samples from the (coal + 10% SRF) fuel mixture were found to be within the acceptable range and were generally lower than that obtained for coal + 10% RDF fuel mixture. The relative distribution of heavy metals in ash components and the flue gas stream shows the presence of a large fraction (up to 98%) of most of the metals in the ash (except Hg and As). Thermo-gravimetric (TG) analysis of SRF constituents was performed to understand the behaviour of fuel mixtures in the absence and presence of air. The results obtained from the experimental study will enhance the confidence of fuel users towards using MSW-derived SRF as an alternative fuel.

  2. Comparison of coal/solid recovered fuel (SRF) with coal/refuse derived fuel (RDF) in a fluidized bed reactor.

    PubMed

    Wagland, S T; Kilgallon, P; Coveney, R; Garg, A; Smith, R; Longhurst, P J; Pollard, S J T; Simms, N

    2011-06-01

    An experimental study was undertaken to compare the differences between municipal solid waste (MSW) derived solid recovered fuel (SRF) (complying with CEN standards) and refuse derived fuel (RDF). Both fuels were co-combusted with coal in a 50 kW fluidized bed combustor and the metal emissions were compared. Synthetic SRF was prepared in the laboratory by grinding major constituents of MSW such as paper, plastic, textile and wood. RDF was obtained from a local mechanical treatment plant. Heavy metal emissions in flue gas and ash samples from the (coal+10% SRF) fuel mixture were found to be within the acceptable range and were generally lower than that obtained for coal+10% RDF fuel mixture. The relative distribution of heavy metals in ash components and the flue gas stream shows the presence of a large fraction (up to 98%) of most of the metals in the ash (except Hg and As). Thermo-gravimetric (TG) analysis of SRF constituents was performed to understand the behaviour of fuel mixtures in the absence and presence of air. The results obtained from the experimental study will enhance the confidence of fuel users towards using MSW-derived SRF as an alternative fuel.

  3. Feasibility of burning refuse derived fuel in institutional size oil-fired boilers. Final report

    SciTech Connect

    1980-10-01

    This study investigates the feasibility of retrofitting existing oil-fired boilers of institutional size, approximately 3.63 to 36.3 Mg steam/h (8000 to 80,000 lbs steam/h) for co-firing with refuse-derived fuel (RDF). Relevant quantities describing mixtures of oil and RDF and combustion products for various levels of excess air are computed. Savings to be realized from the use of RDF are derived under several assumptions and allowable costs for a retrofit are estimated. An extensive survey of manufacturers of burners, boilers, and combustion systems showed that no hardware or proven design is yet available for such retrofit. Approaches with significant promises are outlined: the slagging burner, and a dry ash double vortex burner for low heat input from RDF. These two systems, and an evaluation of a small separate RDF dedicated combustor in support of the oil-fired boiler, are recommended as topics for future study.

  4. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOEpatents

    Diebold, James P.; Scahill, John W.; Chum, Helena L.; Evans, Robert J.; Rejai, Bahman; Bain, Richard L.; Overend, Ralph P.

    1996-01-01

    A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

  5. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOEpatents

    Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

    1996-04-02

    A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

  6. Co-firing high sulfur coal with refuse derived fuels. Quarterly report, October - December 1996

    SciTech Connect

    Pan, W.-P.; Riley, J.T.; Lloyd, W.G.

    1996-12-01

    The objectives of this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the effect of S0{sub 2} on the formation of chlorine during combustion processes was examined. To simulate the conditions used in the AFBC system, experiments were conducted in a quartz tube in an electrically heated furnace. The principle analytical technique used for identification of the products from this study was GC/MS. The evolved gas was trapped by an absorbent and analyzed with a GC/MS system. The preliminary results indicate an inhibiting effect of S0{sub 2} on the Deacon Reaction. Secondly, information on the evolution of chlorine, sulfur and organic compounds from coals 95031 and 95011 were studied with the AFBC system. 2 figs., 1 tab.

  7. Detection of hydrogen gas-producing anaerobes in refuse-derived fuel (RDF) pellets.

    PubMed

    Sakka, Makiko; Kimura, Tetsuya; Ohmiya, Kunio; Sakka, Kazuo

    2005-11-01

    Recently, we reported that refuse-derived fuel (RDF) pellets contain a relatively high number of viable bacterial cells and that these bacteria generate heat and hydrogen gas during fermentation under wet conditions. In this study we analyzed bacterial cell numbers of RDF samples manufactured with different concentrations of calcium hydroxide, which is usually added to waste materials for the prevention of rotting of food wastes and the acceleration of drying of solid wastes, and determined the amount of hydrogen gas produced by them under wet conditions. Furthermore, we analyzed microflora of the RDF samples before and during fermentation by denaturing gradient gel electrophoresis of 16S rDNA followed by sequencing. We found that the RDF samples contained various kinds of clostridia capable of producing hydrogen gas.

  8. Pyrolysis of biomass and refuse-derived fuel performance in laboratory scale batch reactor

    NASA Astrophysics Data System (ADS)

    Kluska, Jacek; Klein, Marek; Kazimierski, Paweł; Kardaś, Dariusz

    2014-03-01

    The results of pyrolysis of pine chips and refuse derived fuel fractions are presented. The experiments were carried out in a pilot pyrolysis reactor. The feedstock was analyzed by an elemental analyzer and the X-ray fluorescence spectrometer to determine the elemental composition. To find out optimum conditions for pyrolysis and mass loss as a function of temperature the thermogravimetric analysis was applied. Gases from the thermogravimetric analysis were directed to the infrared spectrometer using gas-flow cuvette to online analysis of gas composition. Chemical composition of the produced gas was measured using gas chromatography with a thermal conductivity detector and a flame ionization detector. The product analysis also took into account the mass balance of individual products.

  9. Separation of harmful impurities from refuse derived fuels (RDF) by a fluidized bed.

    PubMed

    Krüger, B; Mrotzek, A; Wirtz, S

    2014-02-01

    In firing systems of cement production plants and coal-fired power plants, regular fossil fuels are increasingly substituted by alternative fuels. Rising energy prices and ambitious CO2-reduction goals promote the use of alternative fuels as a significant contribution to efficient energy recovery. One possibility to protect energy resources are refuse-derived fuels (RDF), which are produced during the treatment of municipal solid, commercial and industrial waste. The waste fractions suitable for RDF have a high calorific value and are often not suitable for material recycling. With current treatment processes, RDF still contains components which impede the utilization in firing systems or limit the degree of substitution. The content of these undesired components may amount to 4 wt%. These, in most cases incombustible particles which consist of mineral, ceramic and metallic materials can cause damages in the conveying systems (e. g. rotary feeder) or result in contaminations of the products (e. g. cement, chalk). Up-to-date separation processes (sieve machine, magnet separator or air classifier) have individual weaknesses that could hamper a secure separation of these particles. This article describes a new technology for the separation of impurities from refuse derived fuels based on a rotating fluidized bed. In this concept a rotating motion of the particle bed is obtained by the tangential injection of the fluidization gas in a static geometry. The RDF-particles experience a centrifugal force which fluidized the bed radially. The technical principle allows tearing up of particle clusters to single particles. Radially inwards the vertical velocity is much lower thus particles of every description can fall down there. For the subsequent separation of the particles by form and density an additionally cone shaped plate was installed in the centre. Impurities have a higher density and a compact form compared to combustible particles and can be separated with a high

  10. A preliminary evaluation of a combined tire- and refuse-derived fuel (TDF-RDF)

    SciTech Connect

    Stessel, R.I.; Amari, T.; Themelis, N.J.; Wearnick, I.K.

    1999-07-01

    In dense urban areas of the US, it is now becoming clear that waste management is far from economically-optimum. Even with the popularity of inexpensive land disposal, hauling and recycling costs are driving up the average waste bill. An historic option has been refuse-derived fuel, or RDF. Difficulties included low energy content and difficulty obtaining uniformity. Today, many resource-recovery technologies used in RDF are finding their way into materials recovery facilities (MRFs), some of which are reviving the automated processing of waste. Any MRF, automated or not, will have residue streams. Currently, one of the most significant problems is waste tires. Local options are difficult to locate in dense urban areas. As fuels, tires typically have energy contents considerably above those for which most solid-fuel combustors are designed, leading to thermal imbalances and various forms of failure. This paper suggests a new fuel that can be either co-fired with coal, or used in its own right in a combustor primarily designed for coal: TDF-RDF. A preliminary examination is undertaken of thermal and emissions characteristics, and possible costs for a few applications of the fuel. Immediately, TDF is already cleaner-burning than many coals, even in sulfur emissions. RDF has been widely-regarded as being similarly cleanly. Posited MRF residue streams should be still cleaner, and more consistent, than RDF. Overall, there is quite a potential for developing a fuel that would allow old coal powerplants in historic urban centers to be better neighbors, while helping with a few problems in municipal waste management.

  11. Single particle refuse-derived fuel devolatilization: Experimental measurements of reaction products

    SciTech Connect

    Lai, Weichuan; Krieger-Brockett, B. . Dept. of Chemical Engineering)

    1993-11-01

    The authors present experimentally measured devolatilization product yields from single particles of refuse-derived fuel (RDF), a more uniform, transportable municipal solid waste. Disposal costs and environmental concerns have stimulated interest in thermochemical conversion of this material to chemicals and fuels. The composition, reaction conditions, and particle properties were systematically varied over the range found in practice to develop quantitative measures that rank the process controllables' influence on altering the product slate. Specialized regression methods and experimental designs enhanced the accuracy in view of the feed heterogeneity and offer a general method to extract real effects from experimental and sample noise''. The results have been verified successfully using actual commercial RDF and fabricated compositions that surpass those normally found in municipal waste to anticipate the influence of trends in recycling. The results show that the reaction conditions have a greater influence on altering fuel utilization and the relative yields of char, condensibles, and gases than does the composition over the range found in MSW and RDF.

  12. Co-Combustion of Refuse Derived Fuel with Anthracites in a CFB Boiler

    NASA Astrophysics Data System (ADS)

    Kim, Dong-Won; Lee, Jong-Min; Kim, Jae-Sung

    Combustion of Refuse derived fuel (RDF) is considered as a priority solution to energy recovery from municipal solid waste (MSW). The co-combustion characteristics of anthracite coals with RDF were determined in the commercial scale Tonghae CFB Power Plant. As the feeding ratio of the RDF to the anthracites increased to 5%, temperature and pressure were not changed in comparison with firing only anthracites. The amount of the required air was reduced due to high O2 content in RDF relative to the anthracites. The emissions of NOx, SOx, HCl and Dioxin were also measured. According to higher mixing ratio of the RDF to the anthracites, SOx, NOx emissions slightly decreased and HCl emissions increased, because RDF has relatively smaller S, N and higher CI than the anthracites. Heavy metals of the fly ash and bottom ash and the dioxin emissions were far below Korean maximum permissible concentration level at incinerator. The results showed that it is of great use and technically possible to co-combustion of RDF with the anthracites by 5% in the form of fuel recovery and energy production in commercial scale CFB boiler.

  13. Two stages catalytic pyrolysis of refuse derived fuel: production of biofuel via syncrude.

    PubMed

    Miskolczi, N; Buyong, F; Angyal, A; Williams, P T; Bartha, L

    2010-11-01

    Thermo-catalytic pyrolysis of refuse derived fuels with different catalysts had been conducted in a two stages process due to its important potential value as fuel. The first stage was a pure thermal pyrolysis in a horizontal tubular reactor with feed rate of 0.5kg hourly. The second stage was a semi-batch process in the presence of catalysts. Results showed that the tested catalysts significantly have affected the quantity of products. E.g. gas yield could be increased with 350% related to the catalyst free case using ZSM-5, while that of pyrolytic oil was 115% over Y-zeolite. Gases consisted of mainly CO and CO(2) obtained from the tubular reactor, while dominantly hydrocarbons from the second stage. Ni-Mo-catalyst and Co-Mo-catalyst had shown activity in pyrolytic oil upgrading via in-situ hydrogenation-dehydrogenation reactions. Sulphur, nitrogen and chlorine level in pyrolytic oils could be significantly declined by using of catalysts.

  14. Activated carbons prepared from refuse derived fuel and their gold adsorption characteristics.

    PubMed

    Buah, William K; Williams, Paul T

    2010-02-01

    Activated carbons produced from refuse derived fuel (RDF), which had been prepared from municipal solid waste have been characterized and evaluated for their potential for gold adsorption from gold chloride solution. Pyrolysis of the RDF produced a char, which was then activated via steam gasification to produce activated carbons. Steam gasification of the char at 900 degrees C for 3 h yielded 73 wt% activated carbon. The derived activated carbon had a surface area of 500 m2 g(-1) and a total pore volume of 0.19 cm3 g(-1). The gold adsorption capacity of the activated carbon was 32.1 mg Au g(-1) of carbon when contacted with an acidified gold chloride solution. The gold adsorption capacity was comparable to that of a commercial activated carbon tested under the same conditions and was well in the range of values of activated carbons used in the gold industry. Demineralization of the RDF activated carbon in a 5 M HCl solution resulted in enhancement of its textural properties but a reduction in the gold adsorption rate, indicating that the metal content of the RDF activated carbon influenced its gold adsorption rate.

  15. Design considerations and operating experience in firing refuse derived fuel in a circulating fluidized bed combustor

    SciTech Connect

    Piekos, S.J.; Matuny, M.

    1997-12-31

    The worldwide demand for cleaner, more efficient methods to dispose of municipal solid waste has stimulated interest in processing solid waste to produce refuse derived fuel (RDF) for use in circulating fluidized bed (CFB) boilers. The combination of waste processing and materials recovery systems and CFB boiler technology provides the greatest recovery of useful resources from trash and uses the cleanest combustion technology available today to generate power. Foster Wheeler Power Systems along with Foster Wheeler Energy Corporation and several other Foster Wheeler sister companies designed, built, and now operates a 1600 tons per day (TPD) (1450 metric tons) municipal waste-to-energy project located in Robbins, Illinois, a suburb of Chicago. This project incorporates waste processing systems to recover recyclable materials and produce RDF. It is the first project in the United States to use CFB boiler technology to combust RDF. This paper will provide an overview of the Robbins, Illinois waste-to-energy project and will examine the technical and environmental reasons for selecting RDF waste processing and CFB combustion technology. Additionally, this paper will present experience with handling and combusting RDF and review the special design features incorporated into the CFB boiler and waste processing system that make it work.

  16. Investigation on the spontaneous combustion of refuse-derived fuels during storage using a chemiluminescence technique.

    PubMed

    Matunaga, Atsushi; Yasuhara, Akio; Shimizu, Yoshitada; Wakakura, Masahide; Shibamoto, Takayuki

    2008-12-01

    Refuse-derived fuel (RDF), a high-caloric material, is used by various combustion processes, such as power plants, as alternative fuel. Several explosion accidents, however, possibly initiated by the spontaneous combustion of stored RDF, have been reported in Japan. Therefore the spontaneous combustion of RDF prepared from domestic garbage was investigated using chemiluminescence. RDF samples were heated either under air or under nitrogen for 1, 2, or 4 h at 120 or 140 degrees C and then cooled by an air or nitrogen stream. All RDF samples exhibited chemiluminescence. In air-treated RDF samples (heated and cooled by air), chemiluminescence after ageing was shown to be slightly lower than before ageing, whereas in nitrogen-treated samples (both heated and cooled by nitrogen) chemiluminescence decreased significantly after ageing. When nitrogen was replaced with air during aging, however, a sudden increase of chemiluminescence was observed. On the other hand, when cooling was done with air, chemiluminescence increased. Higher chemiluminescence was also observed during high-temperature treatment. Further experiments on cellulose, one of the major components of domestic garbage, exhibited similar chemiluminescence patterns to those of RDF when treated by the same methods as those used for RDF ageing. Chemiluminescence from cellulose increased significantly when the atmospheric gas was changed from nitrogen to air, suggesting that oxygen in the air promoted the formation of hydroperoxide from cellulose. Therefore, it is hypothesized that cellulose plays an important role in the formation of chemiluminescence from RDF. The formation of chemiluminescence indicated that radicals are formed from RDF by oxidation or thermal degradation at room or atmospheric temperatures and may subsequently lead to spontaneous combustion.

  17. Plasma gasification of refuse derived fuel in a single-stage system using different gasifying agents.

    PubMed

    Agon, N; Hrabovský, M; Chumak, O; Hlína, M; Kopecký, V; Masláni, A; Bosmans, A; Helsen, L; Skoblja, S; Van Oost, G; Vierendeels, J

    2016-01-01

    The renewable evolution in the energy industry and the depletion of natural resources are putting pressure on the waste industry to shift towards flexible treatment technologies with efficient materials and/or energy recovery. In this context, a thermochemical conversion method of recent interest is plasma gasification, which is capable of producing syngas from a wide variety of waste streams. The produced syngas can be valorized for both energetic (heat and/or electricity) and chemical (ammonia, hydrogen or liquid hydrocarbons) end-purposes. This paper evaluates the performance of experiments on a single-stage plasma gasification system for the treatment of refuse-derived fuel (RDF) from excavated waste. A comparative analysis of the syngas characteristics and process yields was done for seven cases with different types of gasifying agents (CO2+O2, H2O, CO2+H2O and O2+H2O). The syngas compositions were compared to the thermodynamic equilibrium compositions and the performance of the single-stage plasma gasification of RDF was compared to that of similar experiments with biomass and to the performance of a two-stage plasma gasification process with RDF. The temperature range of the experiment was from 1400 to 1600 K and for all cases, a medium calorific value syngas was produced with lower heating values up to 10.9 MJ/Nm(3), low levels of tar, high levels of CO and H2 and which composition was in good agreement to the equilibrium composition. The carbon conversion efficiency ranged from 80% to 100% and maximum cold gas efficiency and mechanical gasification efficiency of respectively 56% and 95%, were registered. Overall, the treatment of RDF proved to be less performant than that of biomass in the same system. Compared to a two-stage plasma gasification system, the produced syngas from the single-stage reactor showed more favourable characteristics, while the recovery of the solid residue as a vitrified slag is an advantage of the two-stage set-up.

  18. An Economic Model of Future Coal/Densified Refuse-Derived Fuel Use at Wright-Patterson AFB, Ohio.

    DTIC Science & Technology

    1981-09-01

    DCUMETATON PkGEREAD INSTRUCTIONS REPORT DOCUMAEHTAT1OH PAGE DE.Ri C0MsLrT1cGFoRs TBEFORE COMPLETING FORM 1. RPORTMUM--En-12. OVT CC7~j 1 3. ME ENT*S...CATA6OG NUMOER LSSR 97-81 4. TITLE (and Subeitle) S. TYPE OF REPORT a PERIOD COVIRED AN ECONOMIC MODEL OF FUTURE COAL/DENSIFIED Master’s thesis REFUSE...DERIVED FUEL USE AT WRIGHT- 6. PERFORMING OAG. REPORT NUMBER PATTERSON AFB OH 7. AUTMOR(a) U. CONTRACT OR GRANT NUMGR(s) Richard G. Fedors, Captain, USAF

  19. Coal-firing sulfur coal with refuse derived fuels. Technical progress report {number_sign}7, [April--June 1996

    SciTech Connect

    Pan, Wei-Ping, Riley, J.T.; Lloyd, W.G.

    1996-05-31

    The objectives for this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the organic compounds tentatively identified as combustion products in the previous report were confirmed by comparing retention times with pure samples. Secondly, a reduced amount of unburned carbon in the fly ash and an oxygen concentration at about 3--6% in the flue gases were achieved by the addition of removable heat exchange tubes in the AFBC system.

  20. Densified refuse-derived fuel (d-RDF) burn at Marcy Psychiatric Center. Final report Mar 80-Nov 80

    SciTech Connect

    Galson, E.

    1980-11-01

    A densified refuse derived fuel (d-RDF) product was fired for approximately 50 hours as a supplemental fuel in a coal fired spreader stoker boiler at the Marcy Psychiatric Center in Marcy, New York. Observations were made and photographs were taken of plant operation during all phases of the test project. Opacity and particulate emission tests were performed while firing d-RDF in a ratio of 1:2 with coal (by volume) and while firing 100 percent coal at high and low loads to provide comparisons with State Department of Environmental Conservation emission standards. No significant disadvantages over coal were found in burning d-RDF/coal in ratios up to 2:1 (43 percent heat input by d-RDF). Fuel handling, boiler operation, boiler efficiency, particulate emissions and opacity were similar for the coal and d-RDF/coal mixtures.

  1. Study of organic compounds evolved during the co-firing of coal and refuse derived fuel using TG/MS

    SciTech Connect

    Puroshothama, Shobha; Lu, R.; Yang, Xiaodong

    1996-10-01

    The evolution of organic compounds during the combustion of carbonaceous fuel coupled with solid waste disposal and limited landfill space has been a cause for concern. Co-firing high sulfur coal with refuse derived fuel seems an attractive alternative technique to tackle the dual problem of controlling SO{sub x} emissions as well as those of the chlorinated organic toxins. The TG serves to emulate the conditions of the fluidized bed combustor and the MS serves as the detector for evolved gases. This versatile combination is used to study the decomposition pathway as well as predict the conditions at which various compounds are formed and may serve as a means of reducing the formation of these chlorinated organic compounds.

  2. Refuse-Derived Fuels in U.S. Air Force Heating and Power Systems.

    DTIC Science & Technology

    1986-01-01

    Couer , P. W., Boyd, W. K., and Olexsey, R. A., "Corrosion and Deposits from Combustion of Solid Waste, Part VI--Processed Refuse as a Supplementary...w9Uw wjrw_1, lk, _i-Ar , W-1 -ww14* . 34. Krause, H. H., Vaughn, D. A., Couer , P. W., Boyd, W. K., and Oberacker, D. A., "Corrosion and Deposits

  3. MUNICIPAL WASTE COMBUSTION MULTIPOLLUTANT STUDY EMISSION TEST REPORT, MAINE ENERGY RECOVERY COMPANY, REFUSE DERIVED FUEL FACILITY, BIDDEFORD, MAINE - VOLUME II: APPENDICES A-F

    EPA Science Inventory

    The report gives results of an emission test of a new municipal solid waste combustor, in Biddeford, ME, that burns refuse-derived fuel and is equipped with a lime spray dryer fabric filter (SD/FF) emission control system. Control efficiency of the SD/FF emission control system ...

  4. MUNICIPAL WASTE COMBUSTION MULTIPOLLUTANT STUDY EMISSION TEST REPORT, MAINE ENERGY RECOVERY COMPANY, REFUSE DERIVED FUEL FACILITY, BIDDEFORD, MAINE - VOLUME III: APPENDICES G-N

    EPA Science Inventory

    The report gives results of an emission test of a new municipal solid waste combustor, in Biddeford, ME, that burns refuse-derived fuel and is equipped with a lime spray dryer fabric filter (SD/FF) emission control system. Control efficiency of the SD/FF emission control system ...

  5. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 5, [October--December 1995

    SciTech Connect

    Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

    1995-11-30

    Studies involving the tubular furnace are in the process of identifying the ideal experimental coal-to-refuse derived fuel(RDF) ratio for use in the AFBC system. A series of experiments with this furnace has been performed to determine the possible chemical pathway for formation of chlorinated organic compounds during the combustion of various RDF sources. Phenol and chlorine appear to be likely reactants necessary for the formation of these compounds. The main goal of these experiment is to determine the exact experimental conditions for the formation of chlorinated organic compounds, as well as methods to inhibit their development. Work on the fluidized bed combustor has involved five combustion runs, in which a combustion efficiency of greater than 96% and with a consistent CO{sub 2} concentration of approximately 13% was obtained. Modifications responsible for these improvements include the addition of the underbed fuel feed system and revision of the flue gas sampling system. New methods of determining combustion efficiency and percentage of SO{sub 2} capture using TG techniques to analyze combustion products are being developed. The current outlook using this TGA/FTIR method is very promising, since previously obscured reactions are being studied. the analysis of combustion products is revealing a more complete picture of the combustion process within the AFBC system.

  6. Industrial innovations for tomorrow: Advances in industrial energy-efficiency technologies. Commercial power plant tests blend of refuse-derived fuel and coal to generate electricity

    SciTech Connect

    Not Available

    1993-11-01

    MSW can be converted to energy in two ways. One involves the direct burning of MSW to produce steam and electricity. The second converts MSW into refuse-derived fuel (RDF) by reducing the size of the MSW and separating metals, glass, and other inorganic materials. RDF can be densified or mixed with binders to form fuel pellets. As part of a program sponsored by DOE`s Office of Industrial Technologies, the National Renewable Energy Laboratory participated in a cooperative research and development agreement to examine combustion of binder-enhanced, densified refuse-derived fuel (b-d RDF) pellets with coal. Pelletized b-d RDF has been burned in coal combustors, but only in quantities of less than 3% in large utility systems. The DOE project involved the use of b-d RDF in quantities up to 20%. A major goal was to quantify the pollutants released during combustion and measure combustion performance.

  7. Recovery of plastic wastes from dumpsite as refuse-derived fuel and its utilization in small gasification system.

    PubMed

    Chiemchaisri, Chart; Charnnok, Boonya; Visvanathan, Chettiyappan

    2010-03-01

    An effort to utilize solid wastes at dumpsite as refuse-derived fuel (RDF) was carried out. The produced RDF briquette was then utilized in the gasification system. These wastes were initially examined for their physical composition and chemical characteristics. The wastes contained high plastic content of 24.6-44.8%, majority in polyethylene plastic bag form. The plastic wastes were purified by separating them from other components through manual separation and trommel screen after which their content increased to 82.9-89.7%. Subsequently, they were mixed with binding agent (cassava root) and transformed into RDF briquette. Maximum plastic content in RDF briquette was limit to 55% to maintain physical strength and maximum chlorine content. The RDF briquette was tested in a down-draft gasifier. The produced gas contained average energy content of 1.76 MJ/m(3), yielding cold gas efficiency of 66%. The energy production cost from this RDF process was estimated as USD0.05 perkWh.

  8. RDF (Refuse Derived Fuel) Utilization in a Navy Stoker Coal-Fired Boiler.

    DTIC Science & Technology

    1984-10-01

    based upon the most practical and economical fuel mix. RDF-3 has a high degree of refinement and is best suited for use with pulverized coal where...thermally efficient way to convert waste to energy products. The factors contributing to this high conver- sion efficiency are the ability of the boiler...are also disadvantages with the RDF-to-energy conversion scheme, including the following: An MSW-to-RDF processing plant will require complex, high

  9. Co-firing high sulfur coal with refuse derived fuels. Final report

    SciTech Connect

    Pan, W.P.; Riley, J.T.; Lloyd, W.G.

    1997-11-30

    This project was designed to evaluate the combustion performance of and emissions from a fluidized bed combustor during the combustion of mixtures of high sulfur and/or high chlorine coals and municipal solid waste (MSW). The project included four major tasks, which were as follows: (1) Selection, acquisition, and characterization of raw materials for fuels and the determination of combustion profiles of combination fuels using thermal analytical techniques; (2) Studies of the mechanisms for the formation of chlorinated organics during the combustion of MSW using a tube furnace; (3) Investigation of the effect of sulfur species on the formation of chlorinated organics; and (4) Examination of the combustion performance of combination fuels in a laboratory scale fluidized bed combustor. Several kinds of coals and the major combustible components of the MSW, including PVC, newspaper, and cellulose were tested in this project. Coals with a wide range of sulfur and chlorine contents were used. TGA/MS/FTIR analyses were performed on the raw materials and their blends. The possible mechanism for the formation of chlorinated organics during combustion was investigated by conducting a series of experiments in a tube furnace. The effect of sulfur dioxide on the formation of molecular chlorine during combustion processes was examined in this study.

  10. Determination of aflatoxins in air samples of refuse-derived fuel by thin-layer chromatography with laser-induced fluorescence spectrometric detection

    SciTech Connect

    Bicking, M.K.L.; Kniseley, R.N.; Svec, H.J.

    1983-02-01

    An analytical method is described which allows determination of aflatoxins in a complex matrix. An apparatus has been developed that quantitates fluorescent compounds on thin-layer chromatography plates. A nitrogen laser excitation source produces a detection limit of 10 pg for four aflatoxins. Aflatoxin B1 has been found at levels up to 17 ppb in solid samples collected from the air at a plant which produces refuse-derived fuel. 7 figures, 1 table.

  11. Studies of the combustion of coal/refuse derived fuels using thermogravimetric-Fourier transform infrared-mass spectrometry

    SciTech Connect

    Lu, Huagang; Li, Jigui; Lloyd, W.G.

    1995-11-01

    According to a report of the Environmental Protection Agency (EPA), `Characterization of Municipal Solid Waste (MSW) in the United States`, the total MSW produced in the U.S. increased from 179 million tons in 1988 to 195 million tons in 1990. The EPA predicted that the country would produce about 216 million tons of garbage in the year 2000. The amount of waste generated and the rapidly declining availability of sanitary landfills has forced most municipalities to evaluate alternative waste management technologies for reducing the volume of waste sent to landfills. The fraction of MSW that is processed by such technologies as separation and recycling, composting, and waste-to-energy was forecast to increase from a few percent today to 30-40% by the year 2000. Waste-to-energy conversion of MSW can appear to be attractive because of the energy recovered, the economic value of recycled materials, and the cost savings derived from reduced landfill usage. However, extra care needs to be taken in burning MSW or refuse-derived fuel (RDF) to optimize the operating conditions of a combustor so that the combustion takes place in an environmentally acceptable manner. For instance, polychlorinated dibenzodioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) have been found in the precipitator fly ash and flue gas of some incinerator facilities in the United States and Europe. The amount of PCDDs and PCDFs occurs only in the parts-per-billion to parts-per-trillion range, but these chlorinated organics exhibit very high toxicity (LD{sub 50} < 10 {mu}g/Kg). The compound 2,3,7,8-tetrachlorodibenzodioxin has been found to be acnegenic, carcinogenic, and teratogenic. This has slowed or even stopped the construction and operation of waste-to-energy plants.

  12. Co-firing high sulfur coal with refuse derived fuels. Technical report {number_sign}4

    SciTech Connect

    Pan, W.P.; Riley, J.T.; Lloyd, W.G.

    1995-08-03

    In order to study combustion performance under conditions similar to that in the AFBC system, the authors conducted a series of experiments at a heating rate of 100 C/min using the TGA/FTIR/MS system. Results indicate that more hydrocarbons are evolved at the faster heating rate, owing to incomplete combustion of the fuel. Chlorinated organic compounds can be formed at high heating rates. Certain oxidation products such as organic acids and alcohols are obtained at the slow heating rate. To simulate the conditions used in the atmospheric fluidized bed combustor (AFBC) at Western Kentucky University, studies were also conducted using a quartz tube in a tube furnace. The temperature conditions were kept identical to those of the combustor. The products evolved from the combustion of coal, PVC, and mixtures of the two were trapped in suitable solvents at different temperatures, and analyzed using the Shimadzu GC/MS system. The detection limits and the GC/MS analytical parameters were also established. The experiments were conducted keeping in mind the broader perspective; that of studying conditions conducive to the formation of chlorinated organic compounds from the combustion of coal/MSW blends. 32 figs., 16 tabs.

  13. Inhalation health effects of fine particles from the co-combustion of coal and refuse derived fuel.

    PubMed

    Fernandez, Art; Wendt, Jost O L; Wolski, Natacha; Hein, Klaus R G; Wang, Shengjun; Witten, Mark L

    2003-06-01

    This paper is concerned with health effects from the inhalation of particulate matter (PM) emitted from the combustion of coal, and from the co-combustion of refuse derived fuel (RDF) and pulverized coal mixtures, under both normal and low NO(x) conditions. Specific issues focus on whether the addition of RDF to coal has an effect on PM toxicity, and whether the application of staged combustion (for low NO(x)) may also be a factor in this regard. Ash particles were sampled and collected from a pilot scale combustion unit and then re-suspended and diluted to concentrations of approximately 1000 microg/m(3). These particles were inhaled by mice, which were held in a nose-only exposure configuration. Exposure tests were for 1 h per day, and involved three sets (eight mice per set) of mice. These three sets were exposed over 8, 16, and 24 consecutive days, respectively. Pathological lung damage was measured in terms of increases in lung permeability. Results show that the re-suspended coal/RDF ash appeared to cause very different effects on lung permeability than did coal ash alone. In addition, it was also shown that a "snapshot" of lung properties after a fixed number of daily 1-h exposures, can be misleading, since apparent repair mechanisms cause lung properties to change over a period of time. For the coal/RDF, the greatest lung damage (in terms of lung permeability increase) occurred at the short exposure period of 8 days, and thereafter appeared to be gradually repaired. Ash from staged (low NO(x)) combustion of coal/RDF appeared to cause greater lung injury than that from unstaged (high NO(x)) coal/RDF combustion, although the temporal behavior and (apparent) repair processes in each case were similar. In contrast to this, coal ash alone showed a slight decrease of lung permeability after 1 and 3 days, and this disappeared after 12 days. These observations are interpreted in the light of mechanisms proposed in the literature. The results all suggest that the

  14. Refuse derived fuel (RDF) plasma torch gasification as a feasible route to produce low environmental impact syngas for the cement industry.

    PubMed

    López-Sabirón, Ana M; Fleiger, Kristina; Schäfer, Stefan; Antoñanzas, Javier; Irazustabarrena, Ane; Aranda-Usón, Alfonso; Ferreira, Germán A

    2015-08-01

    Plasma torch gasification (PTG) is currently researched as a technology for solid waste recovery. However, scientific studies based on evaluating its environmental implications considering the life cycle assessment (LCA) methodology are lacking. Therefore, this work is focused on comparing the environmental effect of the emissions of syngas combustion produced by refuse derived fuel (RDF) and PTG as alternative fuels, with that related to fossil fuel combustion in the cement industry. To obtain real data, a semi-industrial scale pilot plant was used to perform experimental trials on RDF-PTG.The results highlight that PTG for waste to energy recovery in the cement industry is environmentally feasible considering its current state of development. A reduction in every impact category was found when a total or partial substitution of alternative fuel for conventional fuel in the calciner firing (60 % of total thermal energy input) was performed. Furthermore, the results revealed that electrical energy consumption in PTG is also an important parameter from the LCA approach.

  15. Production and Use of Densified Refuse-Derived Fuel (DRDF) in Military Central Heating and Power Plants.

    DTIC Science & Technology

    1980-03-01

    Table 5 shows the shift in relative position rock. dust , etc.) 20 23 between cardboard and paper as there is process move- ment from raw refuse to RDF...point of the conveyors, including spillage of material .4 As indicated in the process flow diagram in Figure and emission of high volumes of dust . The... process , which is believed to designed to receive up to 500 tons per day of solid reduce the possibility of explosion from dust , which is waste

  16. NATIONAL INCINERATOR TESTING AND EVALUATION PROGRAM: THE ENVIRONMENTAL CHARACTERIZATION OF REFUSE-DERIVED FUEL (RDF) COMBUSTION TECHNOLOGY - MID-CONNECTICUT FACILITY,

    EPA Science Inventory

    The report gives results of an environmental characterization of refuse-derived, semi-suspension burning technology at a facility in Hartford, CT, that represents state-of-the-art technology, including a spray dryer/fabric filter flue gas cleaning (FGC) system for each unit. The ...

  17. Health and environmental effects of refuse derived fuel (RDF) production and RDF/coal co-firing technologies

    SciTech Connect

    O'Toole, J.J.; Wessels, T.E.; Lynch, J.F.; Fassel, V.A.; Lembke, L.L.; Kniseley, R.N.; Norton, G.A.; Junk, G.A.; Richard, J.J.; Dekalb, E.L.; Dobosy, R.J.

    1981-10-01

    Six facilities, representing the scope of different co-firing techniques with their associated RDF production systems were reviewed in detail for combustion equipment, firing modes, emission control systems, residue handling/disposal, and effluent wastewater treatment. These facilities encompass all currently operational or soon to be operational co-firing plants and associated RDF production systems. Occupational health and safety risks for these plants were evaluated on the basis of fatal and nonfatal accidents and disease arising from the respective fuel cycles, coal and RDF. Occupational risks include exposure to pathogenic organisms in the workplace. Unusual events that are life threatening in the RDF processing industry (e.g., explosions) are also discussed and remedial and safety measures reviewed. 80 refs., 4 figs., 30 tabs.

  18. Destruction and formation of PCDD/Fs in a fluidised bed combustor co-incinerating automotive shredder residue with refuse derived fuel and wastewater treatment sludge.

    PubMed

    Van Caneghem, J; Vermeulen, I; Block, C; Van Brecht, A; Van Royen, P; Jaspers, M; Wauters, G; Vandecasteele, C

    2012-03-15

    During an eight day trial automotive shredder residue (ASR) was added to the usual waste feed of a Fluidized Bed Combustor (FBC) for waste-to-energy conversion; the input waste mix consisted of 25% ASR, 25% refuse-derived fuel (RDF) and 50% wastewater treatment (WWT) sludge. All inputs and outputs were sampled and the concentration of the 17 PCDD/Fs with TEF-values was determined in order to obtain "PCDD/F fingerprints". The ASR contained approximately 9000 ng PCDD/Fs/kg(DW), six times more than the RDF and 10 times more than the WWT sludge. The fingerprint of ASR and RDF was dominated by HpCDD and OCDD, which accounted for 90% of the total PDDD/F content, whereas the WWT sludge contained relatively more HpCDFs and OCDF (together 70%). The flue gas cleaning residue (FGCR) and fly and boiler ash contained approximately 30,000 and 2500 ng PCDD/Fs/kg(DW), respectively. The fingerprints of these outputs were also dominated by HpCDFs and OCDF. The bottom ash contained only OCDD and OCDF, in total 8 ng PCDD/Fs/kg (DW). From the comparison of the bottom ash fingerprints with the fingerprints of the other output fractions and of the inputs, it could be concluded that the PCDD/Fs in the waste were destroyed and new PCDD/Fs were formed in the post combustion process by de novo synthesis. During the ASR-co-incineration, the PCDD/F congener concentrations in the fly and boiler ash, FGCR and flue gas were 1.25-10 times higher compared to the same output fractions generated during incineration of the usual waste mix (70% RDF and 30% WWT sludge). The concentration of the higher chlorinated PCDD/Fs increased most. As these congeners have the lowest TEF-factors, the total PCDD/F output, expressed in kg TEQ/year, of the FBC did not increase significantly when ASR was co-incinerated. Due to the relatively high copper levels in the ASR, the copper concentrations in the FBCs outputs increased. As copper catalysis the de novo syntheses, this could explain the increase in PCDD

  19. Co-combustion of refuse derived fuel and coal in a cyclone furnace at the Baltimore Gas and Electric Company, C. P. Crane Station

    SciTech Connect

    Not Available

    1982-03-01

    A co-combustion demonstration burn of coal and fluff refuse-derived fuel (RDF) was conducted by Teledyne National and Baltimore Gas and Electric Company. This utility has two B and W cyclone furnaces capable of generating 400 MW. The facility is under a prohibition order to convert from No. 6 oil to coal; as a result, it was desirable to demonstrate that RDF, which has a low sulfur content, can be burned in combination with coals containing up to 2% sulfur, thus reducing overall sulfur emissions without deleterious effects. Each furnace consists of four cyclones capable of generating 1,360,000 pounds per hour steam. The tertiary air inlet of one of the cyclones was modified with an adapter to permit fluff RDF to be pneumatically blown into the cyclone. At the same time, coal was fed into the cyclone furnace through the normal coal feeding duct, where it entered the burning chamber tangentially and mixed with the RDF during the burning process. Secondary shredded fluff RDF was prepared by the Baltimore County Resource Recovery Facility. The RDF was discharged into a receiving station consisting of a belt conveyor discharging into a lump breaker, which in turn, fed the RDF into a pneumatic line through an air-lock feeder. A total of 2316 tons were burned at an average rate of 5.6 tons per hour. The average heat replacement by RDF for the cyclone was 25%, based on Btu input for a period of forty days. The range of RDF burned was from 3 to 10 tons per hour, or 7 to 63% heat replacement. The average analysis of the RDF (39 samples) for moisture, ash, heat (HHV) and sulfur content were 18.9%, 13.4%, 6296 Btu/lb and 0.26% respectively. RDF used in the test was secondary shredded through 1-1/2 inch grates producing the particle size distribution of from 2 inches to .187 inches. Findings to date after inspection of the boiler and superheater indicate satisfactory results with no deleterious effects from the RDF.

  20. Proposed draft document for GSA office waste removal and procurement of densified refuse derived fuel for use as a supplemental fuel in GAS operated boilers

    NASA Astrophysics Data System (ADS)

    Campbell, J. A.

    1981-09-01

    A contract specifying waste collection and disposal from buildings managed by Government Services Administration (GSA) in the Washington, D. C. area and the production and delivery of pelletized fuel for burning with coal in one or two GSA steam generating plants is given.

  1. Operational Test Report: Effects of Moisture and Composition on Densified Refuse-Derived Fuel and System Operating Parameters RDF-3 and RDF-5.

    DTIC Science & Technology

    1986-04-01

    86010NCEL"April 1986 An Investigation Conducted By SYSTECH Corporation Sponsored By Naval Facilities Contract Report Engineering Command OPERATIONAL TEST...operating parameter evaluations, refuse composition and refuse moisture were the controlled variables. It was determined that the most effective way to...carts were sealed and left overnight to allow time for the water to be absorbed by the refuse components. RDF characteristics were then measured at

  2. Co-firing a pressurized fluidized-bed combustion system with coal and refuse derived fuels and/or sludges. Task 16

    SciTech Connect

    DeLallo, M.; Zaharchuk, R.

    1994-01-01

    The co-firing of waste materials with coal in utility scale power plants has emerged as an effective approach to produce energy and manage municipal waste. Leading this approach, the atmospheric fluidized-bed combustor (AFBC) has demonstrated its commercial acceptance in the utility market as a reliable source of power burning a variety of waste and alternative fuels. The fluidized bed, with its stability of combustion, reduces the amount of thermochemical transients and provides for easier process control. The application of pressurized fluidized-bed combustor (PFBC) technology, although relatively new, can provide significant enhancements to the efficient production of electricity while maintaining the waste management benefits of AFBC. A study was undertaken to investigate the technical and economic feasibility of co-firing a PFBC with coal and municipal and industrial wastes. Focus was placed on the production of electricity and the efficient disposal of wastes for application in central power station and distributed locations. Wastes considered for co-firing include municipal solid waste (MSW), tire-derived fuel (TDF), sewage sludge, and industrial de-inking sludge. Issues concerning waste material preparation and feed, PFBC operation, plant emissions, and regulations are addressed. This paper describes the results of this investigation, presents conclusions on the key issues, and provides recommendations for further evaluation.

  3. Alternative fuel trucks case studies: Running refuse haulers on compressed natural gas

    SciTech Connect

    Norton, P.; Kelly, K.

    1996-07-01

    This document details the experience of New York City`s compressed natural gas refuse haulers. These 35 ton vehicles have engines that displace 10 liters and provide 240 horsepower. Fuel economy, range, cost, maintenance, repair issues, and emissions are discussed. Photographs and figures illustrate the attributes of these alternative fuel vehicles.

  4. An investigation on the fuel savings potential of hybrid hydraulic refuse collection vehicles

    SciTech Connect

    Bender, Frank A. Bosse, Thomas; Sawodny, Oliver

    2014-09-15

    Highlights: • Driving cycle acquisition in a refuse collection vehicle. • Vehicle modeling and validation for numerical simulations based on the measured driving cycle. • Fuel consumption analysis for a conventional diesel vehicle and a hybrid hydraulic vehicle. - Abstract: Refuse trucks play an important role in the waste collection process. Due to their typical driving cycle, these vehicles are characterized by large fuel consumption, which strongly affects the overall waste disposal costs. Hybrid hydraulic refuse vehicles offer an interesting alternative to conventional diesel trucks, because they are able to recuperate, store and reuse braking energy. However, the expected fuel savings can vary strongly depending on the driving cycle and the operational mode. Therefore, in order to assess the possible fuel savings, a typical driving cycle was measured in a conventional vehicle run by the waste authority of the City of Stuttgart, and a dynamical model of the considered vehicle was built up. Based on the measured driving cycle and the vehicle model including the hybrid powertrain components, simulations for both the conventional and the hybrid vehicle were performed. Fuel consumption results that indicate savings of about 20% are presented and analyzed in order to evaluate the benefit of hybrid hydraulic vehicles used for refuse collection.

  5. Feasibility of landfill gas as a liquefied natural gas fuel source for refuse trucks.

    PubMed

    Zietsman, Josias; Bari, Muhammad Ehsanul; Rand, Aaron J; Gokhale, Bhushan; Lord, Dominique; Kumar, Sunil

    2008-05-01

    The purpose of this paper is to develop a methodology to evaluate the feasibility of using landfill gas (LFG) as a liquefied natural gas (LNG) fuel source for heavy-duty refuse trucks operating on landfills. Using LFG as a vehicle fuel can make the landfills more self-sustaining, reduce their dependence on fossil fuels, and reduce emissions and greenhouse gases. Acrion Technologies Inc. in association with Mack Trucks Inc. developed a technology to generate LNG from LFG using the CO2 WASH process. A successful application of this process was performed at the Eco Complex in Burlington County, PA. During this application two LNG refuse trucks were operated for 600 hr each using LNG produced from gases from the landfill. The methodology developed in this paper can evaluate the feasibility of three LFG options: doing nothing, electricity generation, and producing LNG to fuel refuse trucks. The methodology involved the modeling of several components: LFG generation, energy recovery processes, fleet operations, economic feasibility, and decision-making. The economic feasibility considers factors such as capital, maintenance, operational, and fuel costs, emissions and tax benefits, and the sale of products such as surplus LNG and food-grade carbon dioxide (CO2). Texas was used as a case study. The 96 landfills in Texas were prioritized and 17 landfills were identified that showed potential for converting LFG to LNG for use as a refuse truck fuel. The methodology was applied to a pilot landfill in El Paso, TX. The analysis showed that converting LFG to LNG to fuel refuse trucks proved to be the most feasible option and that the methodology can be applied for any landfill that considers this option.

  6. Refuse recycling and recovery

    SciTech Connect

    Holmes, J.R.

    1981-01-01

    Sanitary landfill of domestic, commercial, and industrial wastes is the predominant method of waste disposal in the United Kingdom. Although there was various waste disposal processes at various stages of design and test, landfill and incineration are still the only reliable methods of waste processing. Methods of recovery and use of refuse are examined in this book together with various separation processes, waste derived fuels, refuse composting, and glass and metal recovery. (Refs. 39).

  7. Real-world activity, fuel use, and emissions of diesel side-loader refuse trucks

    NASA Astrophysics Data System (ADS)

    Sandhu, Gurdas S.; Frey, H. Christopher; Bartelt-Hunt, Shannon; Jones, Elizabeth

    2016-03-01

    Diesel refuse trucks have the worst fuel economy of onroad highway vehicles. The real-world effectiveness of recently introduced emission controls during low speed and low engine load driving has not been verified for these vehicles. A portable emission measurement system (PEMS) was used to measure rates of fuel use and emissions on six side-loader refuse trucks. The objectives were to: (1) characterize activity, fuel use, and emissions; (2) evaluate variability between cycles and trucks; and (3) compare results with the MOVES emission factor model. Quality assured data cover 210,000 s and 550 miles of operation during which the trucks collected 4200 cans and 50 tons of waste material. The average fuel economy was 2.6 mpg. Trash collection contributed 70%-80% of total fuel use and emissions. The daily activity Operating Mode (OpMode) distribution and cycle average fuel use and emissions is different from previously used cycles such as Central Business District (CBD), New York Garbage Truck (NYGT), and William H. Martin (WHM). NOx emission rates for trucks with selective catalytic reduction were over 90% lower than those for trucks without. Similarly, trucks with diesel particulate filters had over 90% lower particulate matter (PM) emissions than trucks without. Compared to unloaded trucks, loaded truck averaged 18% lower fuel economy while NOx and PM emissions were higher by 65% and 16%, respectively. MOVES predicted values are highly correlated to empirical data; however, MOVES estimates are 37% lower for NOx and 300% higher for PM emission rates. The data presented here can be used to develop more representative cycles and improve emission factors for side-loader refuse trucks, which in turn can improve the accuracy of refuse truck emission inventories.

  8. The characteristics of organic sludge/sawdust derived fuel.

    PubMed

    Chen, Wei-Sheng; Chang, Fang-Chih; Shen, Yun-Hwei; Tsai, Min-Shing

    2011-05-01

    A fundamental study of the characteristics of a sludge refuse-derived fuel (RDF) and the combustion behaviors were done. The test data demonstrate good results for the development of energy recovery technology of organic sludge or waste. The ash deposit formation propensity has been based on pretreatment, temperature and the ratio of organic sludge to sawdust. The usage of organic sludge and waste as an alternative fuel is cost effective and has environmental benefits.

  9. Refuse derived soluble bio-organics enhancing tomato plant growth and productivity

    SciTech Connect

    Sortino, Orazio; Dipasquale, Mauro; Montoneri, Enzo; Tomasso, Lorenzo; Perrone, Daniele G.; Vindrola, Daniela; Negre, Michele; Piccone, Giuseppe

    2012-10-15

    Highlights: Black-Right-Pointing-Pointer Municipal bio-wastes are a sustainable source of bio-based products. Black-Right-Pointing-Pointer Refuse derived soluble bio-organics promote chlorophyll synthesis. Black-Right-Pointing-Pointer Refuse derived soluble bio-organics enhance plant growth and fruit ripening rate. Black-Right-Pointing-Pointer Sustainable chemistry exploiting urban refuse allows sustainable development. Black-Right-Pointing-Pointer Chemistry, agriculture and the environment benefit from biowaste technology. - Abstract: Municipal bio-refuse (CVD), containing kitchen wastes, home gardening residues and public park trimmings, was treated with alkali to yield a soluble bio-organic fraction (SBO) and an insoluble residue. These materials were characterized using elemental analysis, potentiometric titration, and 13C NMR spectroscopy, and then applied as organic fertilizers to soil for tomato greenhouse cultivation. Their performance was compared with a commercial product obtained from animal residues. Plant growth, fruit yield and quality, and soil and leaf chemical composition were the selected performance indicators. The SBO exhibited the best performance by enhancing leaf chlorophyll content, improving plant growth and fruit ripening rate and yield. No product performance-chemical composition relationship could be assessed. Solubility could be one reason for the superior performance of SBO as a tomato growth promoter. The enhancement of leaf chlorophyll content is discussed to identify a possible link with the SBO photosensitizing properties that have been demonstrated in other work, and thus with photosynthetic performance.

  10. Designing the microturbine engine for waste-derived fuels.

    PubMed

    Seljak, Tine; Katrašnik, Tomaž

    2016-01-01

    Presented paper deals with adaptation procedure of a microturbine (MGT) for exploitation of refuse derived fuels (RDF). RDF often possess significantly different properties than conventional fuels and usually require at least some adaptations of internal combustion systems to obtain full functionality. With the methodology, developed in the paper it is possible to evaluate the extent of required adaptations by performing a thorough analysis of fuel combustion properties in a dedicated experimental rig suitable for testing of wide-variety of waste and biomass derived fuels. In the first part key turbine components are analyzed followed by cause and effect analysis of interaction between different fuel properties and design parameters of the components. The data are then used to build a dedicated test system where two fuels with diametric physical and chemical properties are tested - liquefied biomass waste (LW) and waste tire pyrolysis oil (TPO). The analysis suggests that exploitation of LW requires higher complexity of target MGT system as stable combustion can be achieved only with regenerative thermodynamic cycle, high fuel preheat temperatures and optimized fuel injection nozzle. Contrary, TPO requires less complex MGT design and sufficient operational stability is achieved already with simple cycle MGT and conventional fuel system. The presented approach of testing can significantly reduce the extent and cost of required adaptations of commercial system as pre-selection procedure of suitable MGT is done in developed test system. The obtained data can at the same time serve as an input for fine-tuning the processes for RDF production.

  11. Preparation and sorption properties of porous materials from refuse paper and plastic fuel (RPF).

    PubMed

    Kadirova, Z; Kameshima, Y; Nakajima, A; Okada, K

    2006-09-01

    Porous materials consisting of activated carbon and amorphous CaO-Al(2)O(3)-SiO(2) (CAS) compound were prepared from refuse paper and plastic fuel (RPF), (a mixture of old paper and plastic) by carbonizing and/or activating treatments. Samples formed by chemical activation using K(2)CO(3) showed a high specific surface area (S(BET)) of 1330 m(2)/g but a lower ash content due to being washed after activation. By contrast, samples prepared by physical activation using steam showed rather lower S(BET) (510 m(2)/g) due to higher ash contents. The physically activated samples showed much higher uptake properties for Ni(2+) (a representative heavy metal) and phosphate ions (a representative of a harmful oxyanion) than the chemically activated samples because of the higher content of amorphous CAS in the former samples. By contrast, the chemically activated samples showed higher uptake for methylene blue (MB, a representative organic material) than the physically activated samples because of the higher activated carbon content of higher surface area. Although differences in the sorption properties for Ni(2+), phosphate ion and MB were found between the physically and chemically activated samples, both samples show excellent multiple sorption properties for cation-anion combinations and inorganic-organic sorbents.

  12. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOEpatents

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  13. In-use measurement of the activity, fuel use, and emissions of front-loader refuse trucks

    NASA Astrophysics Data System (ADS)

    Sandhu, Gurdas S.; Frey, H. Christopher; Bartelt-Hunt, Shannon; Jones, Elizabeth

    2014-08-01

    Field measurements were made for six front-loader refuse trucks for over 560 miles (901 km) and 47 h of operation using a portable emissions measurement system, electronic control unit data logger, and global positioning system receivers. Daily activity, fuel use rates, and emission rates are quantified in terms of operating mode bins defined by the U.S. Environmental Protection Agency for the MOVES emission factor model. On average, 44 (±4) percent of time was spent at idle, 5 (±1) percent braking or decelerating, 11 (±2) percent coasting, 23 (±3) percent cruising or accelerating at low speed (up to 25 mph, 40.2 kmph), 10 (±2) percent cruising or accelerating at moderate speed (25-50 mph, 40.2 to 80.4 kmph), and 7 (±3) percent cruising or accelerating at high speed (50 mph, 80.4 kmph or higher). Fuel use and emission rates varied among operating modes by factors of 6-24. The estimated daily activity cycle average fuel economy ranges from 2.3 to 3.2 mpg (0.98-1.4 kmpl). The PM emission rates for trucks with diesel particulate filters are 98 percent lower compared to those without. Variation in truck weight lead to differences in average fuel use and emission rates of 20 percent or less, except for hydrocarbons. The variation in the empirically-based daily activity cycle average rates were highly correlated with MOVES estimates, except for hydrocarbons. The data collected here are useful for quantifying daily activity specific to front-loaders, and for developing fuel use and emission estimates and models for this type of vehicle.

  14. Production of liquid fuels out of plant biomass and refuse: Methods, cost, potential

    SciTech Connect

    Woick, B.; Friedrich, R.

    1981-09-01

    Different ways of producing biomass and its conversion into high grade fuel for vehicles are reviewed with particular reference to physical and geographical factors, pertaining in the Federal Republic of Germany (FRG). Even with the potentially small amount of biomass in the FRG, the fueling of diesel engines with rape oil or modified ethanol, which can be obtained from any cellulosic feedstock, seems to pose the fewest difficulties and promises greatest efficiency. However, the amount of fuel produced from biomass can probably only meet a very small percentage of the total amount required.

  15. Refuse derived soluble bio-organics enhancing tomato plant growth and productivity.

    PubMed

    Sortino, Orazio; Dipasquale, Mauro; Montoneri, Enzo; Tomasso, Lorenzo; Perrone, Daniele G; Vindrola, Daniela; Negre, Michele; Piccone, Giuseppe

    2012-10-01

    Municipal bio-refuse (CVD), containing kitchen wastes, home gardening residues and public park trimmings, was treated with alkali to yield a soluble bio-organic fraction (SBO) and an insoluble residue. These materials were characterized using elemental analysis, potentiometric titration, and 13C NMR spectroscopy, and then applied as organic fertilizers to soil for tomato greenhouse cultivation. Their performance was compared with a commercial product obtained from animal residues. Plant growth, fruit yield and quality, and soil and leaf chemical composition were the selected performance indicators. The SBO exhibited the best performance by enhancing leaf chlorophyll content, improving plant growth and fruit ripening rate and yield. No product performance-chemical composition relationship could be assessed. Solubility could be one reason for the superior performance of SBO as a tomato growth promoter. The enhancement of leaf chlorophyll content is discussed to identify a possible link with the SBO photosensitizing properties that have been demonstrated in other work, and thus with photosynthetic performance.

  16. MUNICIPAL WASTE COMBUSTION MULTIPOLLUTANT STUDY EMISSION TEST REPORT, MAINE ENERGY RECOVERY COMPANY, RE- FUSE DERIVED FUEL FACILITY, BIDDEFORD, MAINE - VOLUME I: SUMMARY OF RESULTS

    EPA Science Inventory

    The report gives results of an emission test of a new municipal solid waste combustor, in Biddeford, ME, that burns refuse-derived fuel and is equipped with a lime spray dryer fabric filter (SD/FF) emission control system. ontrol efficiency of the SD/FF emission control system wa...

  17. Geiselbullach refuse incineration plant

    SciTech Connect

    Not Available

    1990-03-01

    The vast diversity of wastes, heightened awareness of environmental problems, and unabating demand for power and raw materials, are making it imperative to minimize waste-dumping. Refuse incineration power plants present an ecologically and economically sound answer to this problem, since they also enable communities and large industrial facilities to convert their wastes into electricity and energy for district heating. The refuse produced each year by 1,000,000 people represents a resource equivalent to $30 million of fuel oil. This plant is now converting into energy the waste produced by a population of 280,000. The conversion and expansion were completed without any significant interruption to plant operation. The modernized plant complies fully with today's stringent legal requirements for obtaining an operating license in West Germany. Because landfill sites are becoming increasingly scarce everywhere, thermal processes that dispose of refuse and simultaneously generate electrical power and heat are creating a great deal of interest.

  18. MUNICIPAL WASTE COMBUSTION ASSESSMENT: FOSSIL FUEL CO-FIRING

    EPA Science Inventory

    The report identifies refuse derived fuel (RDF) processing operations and various RDF types; describes such fossil fuel co-firing techniques as coal fired spreader stokers, pulverized coal wall fired boilers, pulverized coal tangentially fired boilers, and cyclone fired boilers; ...

  19. School Refusal

    ERIC Educational Resources Information Center

    Wimmer, Mary

    2008-01-01

    School attendance is an ongoing concern for administrators, particularly in middle level and high school. Frequent absences affect student learning, test scores, and social development. Absenteeism is often the result of emotional disorders, such as anxiety or depression. Administrators who understand the causes of school refusal behavior and are…

  20. Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels

    SciTech Connect

    Gormley, Robert J.; Link, Dirk D.; Baltrus, John P.; Zandhuis, Paul H.

    2009-01-01

    A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber a-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile a-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived fuel as did both the fuel and additive for a synthetic F-T jet fuel additized with benzyl alcohol, but less for the unadditized synthetic fuel. The specific compounds or classes of compounds involved in the partitioning were identified and a semiquantitative comparison of relative partitioning of the compounds of interest was made. The results provide another step forward in improving the confidence level of using additized, fully synthetic jet fuel in the place of petroleum-derived fuel.

  1. Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels

    SciTech Connect

    Gormley, R.J.; Link, D.D.; Baltrus, J.P.; Zandhuis, P.H.

    2008-01-01

    A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber o-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile o-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived fuel as did both the fuel and additive for a synthetic F-T jet fuel additized with benzyl alcohol, but less for the unadditized synthetic fuel. The specific compounds or classes of compounds involved in the partitioning were identified and a semiquantitative comparison of relative partitioning of the compounds of interest was made. The results provide another step forward in improving the confidence level of using additized, fuIly synthetic jet fuel in the place of petroleum-derived fueL

  2. Flocculation characteristics of an isolated mutant flocculent Saccharomyces cerevisiae strain and its application for fuel ethanol production from kitchen refuse.

    PubMed

    Ma, Kedong; Wakisaka, Minato; Sakai, Kenji; Shirai, Yoshihito

    2009-04-01

    A stable mutant flocculent yeast strain of Saccharomyces cerevisiae KRM-1 was isolated during repeated-batch ethanol fermentation using kitchen refuse as the medium. The mechanism of flocculation and interaction with the medium was investigated. According to sugar inhibition assay, it was found that the mutant flocculent strain was a NewFlo phenotype. Flocculation was completely inhibited by protease, proteinase K and partially reduced by treatments with carbohydrate-hydrolyzing enzymes. Flocculation ability showed no difference for pH 3.0-6.0. Furthermore, the mutant flocculent yeast provided repeated-batch cultivations employing cell recycles by flocculation over 10 rounds of cultivation for the production of ethanol from kitchen refuse medium, resulting in relatively high productivity averaging 8.25 g/L/h over 10 batches and with a maximal of 10.08 g/L/h in the final batch. Cell recycle by flocculation was fast and convenient, and could therefore be applicable for industrial-scale ethanol production.

  3. Performance Analysis of Cofiring Densified Refuse Derived Fuel in a Military Boiler.

    DTIC Science & Technology

    1981-12-01

    Occupational Health and Safety Implications of Firing dRDF on a Long Term Basis 44 High Load Rate Boiler Performance Tests on dRDF Blends and dRDF Alone...Literature 52 High Pressure Compaction and Baling of Solid Waste 54 Systems Analysis for the Development of Small Resource Recovery Systems 56 Evaluation of...is of conventional design with a high ceiling, suspended t-ar sihaker, roilup doors on either end and ,:ufficient length to accon-Irouate -- o

  4. Management Impact Assessment of Refuse-Derived Fuel Implementation at Wright-Patterson Air Force Base.

    DTIC Science & Technology

    1982-03-19

    Richard K. McIntosh 9. PERFORMING ORGANIZATION NAME AND ADDRESS 10. PROGRAM ELEMENT PROJECT. TASK ULTRASYSTEMS, INC. AREA & WORK UNIT NUMBERS 10340...Democracy Lane Program Element : 64708F Fairfax, Virginia 22030 JON: 20545017 I. CONTROLLING OFFICE NAME AND ADDRESS 12. REPORT DATE Air Force Engineering...having reviewed the RDF project at WPAFB and interviewed people in all of the involved organizational elements and functional areas within those

  5. Densified Refuse-Derived Fuels-Overview of Production Processes and Combustion Characteristics.

    DTIC Science & Technology

    1984-05-01

    Louis. MS NRL Code 58WM Washi ngton. DC 22 NS’ (CO. Biomedical Rsch Lab, Oakland C’A: (’odte 44 (SCCUrn Officer) Oakland. (A. ( COdIC S4 INorfolk...icies\\ NEW MEXICO SOLAR FNI RGY INS I, Dr /siihCl 1 11 ( race1 \\\\I NY CITY CONILNI FN (Oil LLG BROOKLNN NN (I IIIRARY NYS ENERGiY OFFICE Ibrain

  6. Size exclusion chromatographic analysis of refuse-derived fuel for mycotoxins

    SciTech Connect

    Bicking, M.K.; Kniseley, R.N.

    1980-11-01

    A Styragel packing material is characterized in several solvent systems by using a series of test solutes and mycotoxins. Differences in interpretation with other work are discussed. Three different separation modes are generated on one stationary phase. An improved separation of mycotoxins from a compilcated matrix results by simultaneously using size exclusion and liquid-liquid partitioning. 4 figures, 3 tables.

  7. Technology Evaluation for Densified Refuse-Derived Fuel Specifications and Acquisition.

    DTIC Science & Technology

    1983-12-01

    4.2 Properties of aRUF . .. .. ..... ..... ..... ..... 29 4.3 Material Handling of aRDF .. .. ..... ..... ....... 30 4.4 Storage of dRDF...specifications. 4.3 MATERIAL HANDLING UF aRUF In light of tne fdet tnat tne generation anc, usSpersion of tines aL the unloading point and ouring conveyance at...and correlated with toe slagging and clinkering that has occurred at all racilities ourning RUF or coal/RDF mixtures. 4.6 ANALYSES OF aRUF PROPERTIES

  8. Progress on coal-derived fuels for aviation systems

    NASA Technical Reports Server (NTRS)

    Witcofski, R. D.

    1978-01-01

    Synthetic aviation kerosene (Syn. Jet-A), liquid methane (LCH4), and liquid hydrogen (LH2) appear to be the most promising coal-derived fuels. Liquid hydrogen aircraft configurations, their fuel systems, and their ground requirements at the airport are identified. These aircraft appear viable, particularly for long haul use, where aircraft fueled with coal derived LH2 would consume 9 percent less coal resources than would aircraft fueled with coal derived Syn. Jet-A. Distribution of hydrogen from the point of manufacture to airports may pose problems. Synthetic JET-A would appear to cause fewer concerns to the air transportation industry. Of the three candidate fuels, LCH4 is the most energy efficient to produce, and an aircraft fueled with coal derived LCH4 may provide both the most efficient utilization of coal resources and the least expensive ticket as well.

  9. Production of distillate fuels from biomass-derived polyoxygenates

    DOEpatents

    Kania, John; Blommel, Paul; Woods, Elizabeth; Dally, Brice; Lyman, Warren; Cortright, Randy

    2017-03-14

    The present invention provides methods, reactor systems and catalysts for converting biomass and biomass-derived feedstocks to C.sub.8+ hydrocarbons using heterogenous catalysts. The product stream may be separated and further processed for use in chemical applications, or as a neat fuel or a blending component in jet fuel and diesel fuel, or as heavy oils for lubricant and/or fuel oil applications.

  10. Progress on coal-derived fuels for aviation systems

    NASA Technical Reports Server (NTRS)

    Witcofski, R. D.

    1978-01-01

    The results of engineering studies of coal-derived aviation fuels and their potential application to the air transportation system are presented. Synthetic aviation kerosene (SYN. JET-A), liquid methane (LCH4) and liquid hydrogen (LH2) appear to be the most promising coal-derived fuels. Aircraft configurations fueled with LH2, their fuel systems, and their ground requirements at the airport are identified. Energy efficiency, transportation hazards, and costs are among the factors considered. It is indicated that LCH4 is the most energy efficient to produce, and provides the most efficient utilization of coal resources and the least expensive ticket as well.

  11. Development of alternative fuels from coal-derived syngas

    SciTech Connect

    Not Available

    1991-03-22

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels development Unit (AFDU). The program will initially involve a continuation of the work performed under the Liquid Phase Methanol Program but will later draw upon information and technologies generated in current and future DOE-funded contracts, as well as test commercially available catalysts. 1 fig., 3 tabs.

  12. Test burning of tire-derived fuel in solid fuel combustors

    SciTech Connect

    Dennis, D.C.

    1994-12-31

    This study was commissioned to determine the overall viability of utilizing scrap tire chips, known as tire-derived fuel (TDF), as a supplemental fuel in conventional coal-fired boilers. The study involved actual tests at Monsanto Company`s W.G. Krummrich Plant in Sauget, Illinois, as well as general extrapolations as to the feasibility of using TDF at other sites. This report will show that TDF can be an excellent supplemental fuel supply, providing a cost-effective fuel source while helping to alleviate the dilemma of scrap tire disposal.

  13. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  14. Myeloid Derived Suppressor Cells: Fuel the Fire.

    PubMed

    Achyut, B R; Arbab, Ali S

    2014-08-01

    Low oxygen tension, hypoxia, is a characteristic of many tumors and associated with the poor prognosis. Hypoxia invites bone marrow derived cells (BMDCs) from bone marrow to the site of tumor. These recruited CXCR4+ BMDCs provide favorable environment for the tumor growth by acquiring pro-angiogenic phenotype such as CD45+VEGFR2+ Endothelial Progenitor Cells (EPC), or CD45+Tie2+ myeloid cells. CD11b+CD13+ myeloid population of the BMDCs modulate tumor progression. These myeloid populations retain immunosuppressive characteristics, for example, myeloid derived suppressor cells (MDSCs), and regulates immune- suppression by inhibiting cytotoxic T cell function. In addition, MDSCs were observed at the premetastatic niche of the distant organs in other tumors. Protumorigenic and prometastatic role of the myeloid cells provides a basis for therapeutic targeting of immunosuppression and thus inhibiting tumor development and metastasis.

  15. Production of jet fuels from coal-derived liquids

    SciTech Connect

    Knudson, C.L.

    1990-06-01

    Samples of jet fuel (JP-4, JP-8, JP-8X) produced from the liquid by-products of the gasification of lignite coal from the Great Plains Gasification Plant were analyzed to determine the quantity and type of organo-oxygen compounds present. Results were compared to similar fuel samples produced from petroleum. Large quantities of oxygen compounds were found in the coal-derived liquids and were removed in the refining process. Trace quantities of organo-oxygenate compounds were suspected to be present in the refined fuels. Compounds were identified and quantified as part of an effort to determine the effect of these compounds in fuel instability. Results of the analysis showed trace levels of phenols, naphthols, benzofurans, hexanol, and hydrogenated naphthols were present in levels below 100 ppM. 9 figs., 3 tabs.

  16. Conversion of Pentose-Derived Furans into Hydrocarbon Fuels

    SciTech Connect

    Moens, L.; Johnson, D. K.

    2012-01-01

    We are interested in the conversion of biomass-derived hemicellulose into hydrocarbon molecules that can be used in the formulation of 'drop-in' fuels such as gasoline (C5-12), diesel (C10-20) and jet fuel (C9-16). Our focus lies on the use of furfuryl alcohol as a starting material since that is already produced commercially from hemicellulose-derived pentoses. The steps required to convert the latter into hydrocarbons are 1) oligomerization of furfuryl alcohol to form dimers (C10) and trimers (C15), and 2) hydrotreatment of the dimers and trimers to produce a mixture of linear hydrocarbons with carbon chain lengths in the range of diesel and jet fuels. However, furfuryl alcohol readily polymerizes to form resins in the presence of an acid catalyst, and the exothermic oligomerization must be carried out under reaction control. This presentation will discuss our progress in the development of this sugar-to-hydrocarbon pathway.

  17. Vertical combustor for particulate refuse

    NASA Astrophysics Data System (ADS)

    Chung, P. M.; Carlson, L.

    1981-03-01

    A one-dimensional model is constructed of a vertical combustor for refuse particle combustion in order to analyze it for waste energy recovery. The three components of the model, fuel particles, inert solid particles and the gaseous mixture are described by momentum, energy, and mass conservation equations, resulting in three different flow velocities and temperatures for the medium. The gaseous component is further divided into six chemical species that evolve in combustion at temperatures below about 1367 K. A detailed description is given of the fuel particle combustion through heating, devolatilization, and combustion of the volatile gas in the boundary layer, return of the flame sheet to the fuel surface, and char combustion. The solutions show the combustor to be viable for U.S. refuse which consists of combustibles that can be volatilized up to 85 to 95% below 1366 K. Char combustion, however, is found to be too slow to be attempted in the combustor, where the fuel residence time is of the order of 2 s.

  18. Clean Cities Niche Market Overview: Refuse Haulers (Brochure)

    SciTech Connect

    Shea, S.

    2011-09-01

    Refuse haulers are ideal for the adoption of alternative fuels and advanced vehicle technologies. By using fuels like natural gas, propane, or biodiesel, and technologies like hybrid electric and hydraulic hybrid systems, the refuse-hauling sector could substantially decrease its petroleum use and greenhouse gas emissions. Fleet managers should explore the benefits of the fuels and technologies available, as well as the individual fleet needs, before adoption.

  19. Conversion of Biomass-Derived Furans into Hydrocarbon Fuels

    SciTech Connect

    Moens, L.; Johnson, D. K.

    2013-01-01

    One of the most studied chemical transformations of carbohydrates is their thermocatalytic dehydration to form furans. Cellulose-derived glucose is thereby converted into 5-hydroxymethylfurfuraldehyde (5-HMF), while the hemicellulose-derived pentoses (e.g., xylose, arabinose) form furfuraldehyde. Our objective is to identify new pathways to convert furfuryl alcohol into a mixture of aliphatic hydrocarbons that can be used as drop-in fuels for diesel (C10-20) and jet fuel (C9-16) blends. Furfuryl alcohol is produced commercially through hydrogenation of furfuraldehyde that is derived from hemicellulose-derived pentoses via acid-catalyzed dehydration. The steps that we are currently pursuing to convert furfuryl alcohol into hydrocarbons are 1) oligomerization of furfuryl alcohol to form dimers (C10) and trimers (C15), and 2) hydrotreatment of the dimers and trimers to produce a mixture of linear hydrocarbons with carbon chain lengths in the range of diesel and jet fuels. This presentation will discuss our progress in the development of this pathway.

  20. Development of alternative fuels from coal-derived syngas

    SciTech Connect

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products' laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively benign'' system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE's program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  1. Microbial production of fatty acid-derived fuels and chemicals

    PubMed Central

    Lennen, Rebecca M; Pfleger, Brian F

    2013-01-01

    Fatty acid metabolism is an attractive route to produce liquid transportation fuels and commodity oleochemicals from renewable feedstocks. Recently, genes and enzymes, which comprise metabolic pathways for producing fatty acid-derived compounds (e.g. esters, alkanes, olefins, ketones, alcohols, polyesters) have been elucidated and used in engineered microbial hosts. The resulting strains often generate products at low percentages of maximum theoretical yields, leaving significant room for metabolic engineering. Economically viable processes will require strains to approach theoretical yields, particularly for replacement of petroleum-derived fuels. This review will describe recent progress toward this goal, highlighting the scientific discoveries of each pathway, ongoing biochemical studies to understand each enzyme, and metabolic engineering strategies that are being used to improve strain performance. PMID:23541503

  2. Combustion Of Poultry-Derived Fuel in a CFBC

    NASA Astrophysics Data System (ADS)

    Jia, Lufei; Anthony, Edward J.

    Poultry farming generates large quantities of waste. Current disposal practice is to spread the poultry wastes onto farmland as fertilizer. However, as the factory farms for poultry grow both in numbers and size, the amount of poultry wastes generated has increased significandy in recent years. In consequence, excessive application of poultry wastes on farmland is resulting in more and more contaminants entering the surface water. One of the options being considered is the use of poultry waste as power plant fuel. Since poultry-derived fuel (PDF) is biomass, its co-firing will have the added advantage of reducing greenhouse gas emissions from power generation. To evaluate the combustion characteristics of co-firing PDF with coal, combustion tests of mixtures of coal and PDF were conducted in CanmetENERGY's pilot-scale CFBC. The goal of the tests was to verify that PDF can be co-fired with coal and, more importantly, that emissions from the combustion process are not adversely affected by the presence of PDF in the fuel feed. The test results were very promising and support the view that co-firing in an existing coal-fired CFBC is an effective method of utilizing this potential fuel, both resolving a potential waste disposal problem and reducing the amount of CO2 released by the boiler.

  3. A fresh look at coal-derived liquid fuels

    SciTech Connect

    Paul, A.D.

    2009-01-15

    35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

  4. Feasibility of implementing a municipal waste-to-energy system to supply Youngstown thermal with a solid fuel or steam system

    SciTech Connect

    Not Available

    1984-01-01

    The municipal solid waste and economics of disposal are discussed. Youngstown Thermal's existing system and its economics are described. The technical feasibilities of refuse-derived fuels and refuse mass-burning are explored. Economic evaluations and institutional considerations are included. (MHR)

  5. Pathways for Biomass-Derived Lignin to Hydrocarbon Fuels

    SciTech Connect

    Laskar, Dhrubojyoti; Yang, Bin; Wang, Huamin; Lee, Guo-Shuh J.

    2013-09-01

    Production of hydrocarbon fuel from biomass-derived lignin sources with current version of biorefinery infrastructure would significantly improve the total carbon use in biomass and make biomass conversion more economically viable. Thus, developing specialty and commodity products from biomass derived-lignin has been an important industrial and scientific endeavor for several decades. However, deconstruction of lignin’s complex polymeric framework into low molecular weight reactive moieties amenable for deoxygenation and subsequent processing into hydrocarbons has been proven challenging. This review offers a comprehensive outlook on the existing body of work that has been devoted to catalytic processing of lignin derivatives into hydrocarbon fuels, focusing on: (1) The intrinsic complexity and characteristic structural features of biomass-derived lignin; (2) Existing processing technologies for the isolation and depolymerization of bulk lignin (including detailed mechanistic considerations); (3) Approaches aimed at significantly improving the yields of depolymerized lignin species amenable to catalytic upgrading, and; (4) Catalytic upgrading, using aqueous phase processes for transforming depolymerized lignin to hydrocarbon derivatives. Technical barriers and challenges to the valorization of lignin are highlighted throughout. The central goal of this review is to present an array of strategies that have been reported to obtain lignin, deconstruct it to reactive intermediates, and reduce its substantial oxygen content to yield hydrocarbon liquids. In this regard, reaction networks with reference to studies of lignin model compounds are exclusively surveyed. Special attention is paid to catalytic hydrodeoxygenation, hydrogenolyis and hydrogenation. Finally, this review addresses important features of lignin that are vital to economic success of hydrocarbon production.

  6. Impact study on the use of biomass-derived fuels in gas turbines for power generation

    SciTech Connect

    Moses, C A; Bernstein, H

    1994-01-01

    This report evaluates the properties of fuels derived from biomass, both gaseous and liquid, against the fuel requirements of gas turbine systems for gernating electrical power. The report attempts to be quantitative rather than merely qualitative to establish the significant variations in the properties of biomass fuels from those of conventional fuels. Three general categories are covered: performance, durability, and storage and handling.

  7. The Concept and Economics of RDF-3 (Refuse Derived Fuel) Utilization in a Navy Size Pulverized Coal Boiler.

    DTIC Science & Technology

    1983-05-01

    Rates: Technical/Operational 7-2 Cost Projections for 10% and 20% Substitu- tion Rates: Financial 7-4 Viii SECTION 1.0 EXECUTIVE SUMMARY This report...potential methods for making the proposed concept more economically attractive and provides comparitive technical, operational and financial information...X , 1 ;W ; ;1 ;1 :1 ; 44 4v’" a * 4 N >C gmo "lt4I ~ @ td ’O~ 4 C C, NC Q =N a 4 L, I’ at ~ *~~NN " I J * 4 ~ 4~ 4I 44; 1.4 It I N 4 N -12 4 i N 4 4

  8. Fluidized bed gasification of waste-derived fuels.

    PubMed

    Arena, Umberto; Zaccariello, Lucio; Mastellone, Maria Laura

    2010-07-01

    Five alternative waste-derived fuels obtained from municipal solid waste and different post-consumer packaging were fed in a pilot-scale bubbling fluidized bed gasifier, having a maximum feeding capacity of 100 kg/h. The experimental runs utilized beds of natural olivine, quartz sand or dolomite, fluidized by air, and were carried out under various values of equivalence ratio. The process resulted technically feasible with all the materials tested. The olivine, a neo-silicate of Fe and Mg with an olive-green colour, has proven to be a good candidate to act as a bed catalyst for tar removal during gasification of polyolefin plastic wastes. Thanks to its catalytic activity it is possible to obtain very high fractions of hydrogen in the syngas (between 20% and 30%), even using air as the gasifying agent, i.e. in the most favourable economical conditions and with the simplest plant and reactor configuration. The catalytic activity of olivine was instead reduced or completely inhibited when waste-derived fuels from municipal solid wastes and aggregates of different post-consumer plastic packagings were fed. Anyhow, these materials have given acceptable performance, yielding a syngas of sufficient quality for energy applications after an adequate downstream cleaning.

  9. Fluidized bed gasification of waste-derived fuels

    SciTech Connect

    Arena, Umberto; Zaccariello, Lucio; Mastellone, Maria Laura

    2010-07-15

    Five alternative waste-derived fuels obtained from municipal solid waste and different post-consumer packaging were fed in a pilot-scale bubbling fluidized bed gasifier, having a maximum feeding capacity of 100 kg/h. The experimental runs utilized beds of natural olivine, quartz sand or dolomite, fluidized by air, and were carried out under various values of equivalence ratio. The process resulted technically feasible with all the materials tested. The olivine, a neo-silicate of Fe and Mg with an olive-green colour, has proven to be a good candidate to act as a bed catalyst for tar removal during gasification of polyolefin plastic wastes. Thanks to its catalytic activity it is possible to obtain very high fractions of hydrogen in the syngas (between 20% and 30%), even using air as the gasifying agent, i.e. in the most favourable economical conditions and with the simplest plant and reactor configuration. The catalytic activity of olivine was instead reduced or completely inhibited when waste-derived fuels from municipal solid wastes and aggregates of different post-consumer plastic packagings were fed. Anyhow, these materials have given acceptable performance, yielding a syngas of sufficient quality for energy applications after an adequate downstream cleaning.

  10. Fossil fuel derivatives with reduced carbon. Phase I final report

    SciTech Connect

    Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

    1999-06-30

    This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

  11. Ecofriendly in-line process monitoring: a case study. Anthracene photodegradation in the presence of refuse-derived soluble bio-organics.

    PubMed

    Bianco Prevot, A; Avetta, P; Fabbri, D; Montoneri, E; Morales-Rubio, A; de la Guardia, M

    2012-08-01

    Photodegradation of anthracene has been studied in aqueous solutions containing soluble bio-organic substances isolated from urban refuse. To perform a preliminary rapid feasibility study of this process while reducing the amount of analytical effort and reagents, an experimental set-up was developed comprising a Teflon coil surrounding a UV-lamp and coupled with an in-line spectrofluorimeter. In this fashion only few millilitres of solution are needed to study the degradation process. Furthermore, the in-line spectroscopic approach enables monitoring of the process without consumption of reagents. Additional studies by liquid chromatography and use of toxicity tests clearly indicated that the apparent inhibition effect of bio-organic compounds on anthracene degradation is not relevant. The results imply that urban refuse may be used as an auxiliary in the recovery of polycyclic aromatic hydrocarbons from contaminated soil by washing, without deleterious effects on the photodegradation of anthracene and other aromatic pollutants.

  12. Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels

    SciTech Connect

    2010-07-01

    The University of Alabama will develop fuel-flexible, low-emissions burner technology for the metal processing industry that is capable of using biomass-derived liquid fuels, such as glycerin or fatty acids, as a substitute for natural gas. By replacing a fossil fuel with biomass fuels, this new burner will enable a reduction in energy consumption and greenhouse gas emissions and an increase in fuel flexibility.

  13. Method of extracting coal from a coal refuse pile

    DOEpatents

    Yavorsky, Paul M.

    1991-01-01

    A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

  14. Production of Jet Fuels from Coal-Derived Liquids. Volume 14. Oxygenates Content of Coal-Derived Jet Fuels

    DTIC Science & Technology

    1990-06-01

    Compour-W RI Rt JP-4 JP-8 BuLk JP-8X Cumilative wtX wt% wt% wt% wt% JP-4 Bulk JP- SX 1. n-C4 400.0 0.001 0.11 0.04 0.02 0.11 0.02 2. 466.0 2.837 0.21 0.07...DATA FOR COAL-DERIVED JET FUELS # Conound RI Rt JP-4 JP-8 Bulk JP-8X Cumulative wtX wtX wt% wtX wtX JP-4 Bulk JP- SX 166. C2-Decalin 1306.2 24.869 0.16...boiling cyclopentadiene ( CDP ) dimers and other material that decomposed to small sulfur-containing compounds and cycloolefins. Nitrogen base

  15. Combustion characteristics of coal and refuse from passenger trains.

    PubMed

    Fu-min, Ren; Feng, Yue; Ming, Gao; Min, Yu

    2010-07-01

    Refuse from passenger trains is becoming a significant issue with the development of the Chinese railway. Co-firing is regarded as a promising thermal technology, both environmentally and economically, in reducing the quantity of refuse. The co-firing property of passenger train refuse with coal, however, may differ due to the differences in the composition of the refuse. In the present study, combustion properties of refuse from passenger train samples and the mixture of refuse with coal were studied in a tube furnace. Thermo analysis methods, such as thermogravimetry (TG), differential scanning calorimetry (DSC), differential thermal analysis (DTA) and derivative thermogravimetry (DTG) analyses were employed to evaluate combustion performance. We found that the mixture of passenger train refuse and coal at a ratio of 1:1 has a lower ignition and burnout temperature than the coal-only sample. Moreover, refuse from railway passenger trains has more reactive combustion properties than the coal-only sample, and the addition of railway passenger train refuse to coal can promote the reactivity of coal.

  16. Utilization of spent activated carbon to enhance the combustion efficiency of organic sludge derived fuel.

    PubMed

    Chen, Wei-Sheng; Lin, Chang-Wen; Chang, Fang-Chih; Lee, Wen-Jhy; Wu, Jhong-Lin

    2012-06-01

    This study examines the heating value and combustion efficiency of organic sludge derived fuel, spent activated carbon derived fuel, and derived fuel from a mixture of organic sludge and spent activated carbon. Spent activated carbon was sampled from an air pollution control device of an incinerator and characterized by XRD, XRF, TG/DTA, and SEM. The spent activated carbon was washed with deionized water and solvent (1N sulfuric acid) and then processed by the organic sludge derived fuel manufacturing process. After washing, the salt (chloride) and sulfide content could be reduced to 99% and 97%, respectively; in addition the carbon content and heating value were increased. Different ratios of spent activated carbon have been applied to the organic sludge derived fuel to reduce the NO(x) emission of the combustion.

  17. Refusal to medical interventions.

    PubMed

    Palacios, G; Herreros, B; Pacho, E

    2014-10-01

    Refusal to medical interventions is the not acceptance, voluntary and free, of an indicated medical intervention. What the physician should do in case of refusal? It is understandable that the rejection of a validated medical intervention is difficult to accept by the responsible physician when raises the conflict protection of life versus freedom of choice. Therefore it is important to follow some steps to incorporate the most relevant aspects of the conflict. These steps include: 1) Give complete information to patients, informing on possible alternatives, 2) determine whether the patient can decide (age, competency and level of capacity), 3) to ascertain whether the decision is free, 4) analyze the decision with the patient, 5) to persuade, 6) if the patient kept in the rejection decision, consider conscientious objection, 7) take the decision based on the named criteria, 8) finally, if the rejection is accepted, offer available alternatives.

  18. Children with pervasive refusal.

    PubMed

    Lask, B; Britten, C; Kroll, L; Magagna, J; Tranter, M

    1991-07-01

    Four children are described with a potentially life threatening condition manifested by profound and pervasive refusal to eat, drink, walk, talk, or care for themselves in any way over a period of several months. The multiplicity and severity of the symptoms in these children do not fit comfortably into any existing diagnostic category. Long term and highly skilled nursing and psychiatric care is required to help these children to recover. The possible causes of this syndrome are discussed.

  19. Pervasive refusal syndrome.

    PubMed

    Wright, Barry; Beverley, David

    2012-04-01

    We report here on a case of severe pervasive refusal syndrome. This is of interest for three reasons. Firstly, most reported cases are adolescent girls; our case is regarding an adolescent boy. Secondly, he was successfully treated at home and thirdly, the serology showed an apparent infective pre-cursor to the illness with evidence of possible autoimmune serology. A 14-year old boy deteriorated from a picture where diagnosed CFS/ME developed into Pervasive Refusal Syndrome. This included the inability to move or speak, with closed eyes, multiple tics, facial grimacing, heightened sensitivity to noise (hyperacusis) and touch (hyperaesthesia), and inability or unwillingness to eat anything except small amounts of sloppy food. Successful rehabilitation is reported. Finally the issue of nomenclature is discussed, raising the question whether Pervasive Refusal Syndrome would be better renamed in a way that does not imply that the condition is always volitional and oppositional, as this can distract focus away from an alliance between family and clinicians.

  20. An environmentally benign soybean derived fuel as a blending stock or replacement for home heating oil.

    PubMed

    Mushrush, G; Beal, E J; Spencer, G; Wynne, J H; Lloyd, C L; Hughes, J M; Walls, C L; Hardy, D R

    2001-05-01

    The use of bio-derived materials both as fuels and/or as blending stocks becomes more attractive as the price of middle distillate fuels, especially home heating oil, continues to rise. Historically, many biomass and agricultural derived materials have been suggested. One of the most difficult problems encountered with home heating oil is that of storage stability. High maintenance costs associated with home heating oil are, in large part, because of this stability problem. In the present research, Soygold, a soybean derived fuel, was added in concentrations of 10%-20% to both a stable middle distillate fuel and an unstable home heating oil. Fuel instability in this article will be further related to the organo-nitrogen compounds present. The soy-fuel mixtures proved stable, and the addition of the soy liquid enhanced both the combustion properties, and dramatically improved the stability of the unstable home heating oil.

  1. The health effects of fossil fuel derived particles.

    PubMed

    Grigg, J

    2002-02-01

    Over the past 10 years there has been increasing evidence that particles generated by the combustion of fossil fuels adversely affect health. To what extent should paediatricians be concerned about particle pollution? This review assesses what we know, and what we still need to know about the health effects of fossil fuel particles.

  2. Biodiesel: The use of vegetable oils and their derivatives as alternative diesel fuels

    SciTech Connect

    Knothe, G.; Bagby, M.O.

    1996-10-01

    Vegetable oils and their derivatives (especially methyl esters), commonly referred to as {open_quotes}biodiesel{close_quotes}, are prominent candidates as alternative diesel fuels. They have advanced from being purely experimental fuels to initial stages of commercialization. They are technically competitive with or offer technical advantages compared to conventional diesel fuel. Besides being a renewable resource, biodiesel reduces most emissions while engine performance and fuel economy are nearly identical compared to conventional fuels. Several problems, however, remain, which include economics, combustion, some emissions, lube oil contamination, and low-temperature properties. An overview on all the mentioned aspects of biodiesel will be presented.

  3. Applications study of advanced power generation systems utilizing coal-derived fuels, volume 2

    NASA Technical Reports Server (NTRS)

    Robson, F. L.

    1981-01-01

    Technology readiness and development trends are discussed for three advanced power generation systems: combined cycle gas turbine, fuel cells, and magnetohydrodynamics. Power plants using these technologies are described and their performance either utilizing a medium-Btu coal derived fuel supplied by pipeline from a large central coal gasification facility or integrated with a gasification facility for supplying medium-Btu fuel gas is assessed.

  4. EVALUATION OF TIRE-DERIVED FUEL FOR USE IN NITROGEN OXIDE REDUCTION BY REBURNING

    EPA Science Inventory

    Tire-derived fuel (TDF) was tested in a small-scale (44 kW or 150,000 Btu/hr) combustor to determine its feasibility as a fuel for use in reburning for control of nitrogen oxide (NO). TDF was gravity-fed into upward flowing combustion gases from a primary natural gas flame doped ...

  5. Will biodiesel derived from algal oils live up to its promise? A fuel property assessment

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Algae have been attracting considerable attention as a source of biodiesel recently. This attention is largely due to the claimed high production potential of algal oils while circumventing the food vs. fuel issue. However, the properties of biodiesel fuels derived from algal oils have been only spa...

  6. Airfoil cooling hole plugging by combustion gas impurities of the type found in coal derived fuels

    NASA Technical Reports Server (NTRS)

    Deadmore, D. L.; Lowell, C. E.

    1979-01-01

    The plugging of airfoil cooling holes by typical coal-derived fuel impurities was evaluated using doped combustion gases in an atmospheric pressure burner rig. Very high specific cooling air mass flow rates reduced or eliminated plugging. The amount of flow needed was a function of the composition of the deposit. It appears that plugging of film-cooled holes may be a problem for gas turbines burning coal-derived fuels.

  7. Disposal of municipal refuse and RDF in Japan by a two-bed pyrolysis system

    SciTech Connect

    Ishii, N.; Ishi, Y.; Ito, K. Hirayama, Y.

    1985-01-01

    This system efficiently and effectively produces high-quality, high-heating-value fuel gas from municipal refuse and RDF. In 1978, the commercial demonstration plant was constructed in Yokohama and since 1979 it has operated with municipal solid waste, RDF, and industrial refuse. The technology is now ready for commercialization.

  8. Recapturing NERVA-Derived Fuels for Nuclear Thermal Propulsion

    SciTech Connect

    Qualls, A L; Hancock, Emily F

    2011-01-01

    The Department of Energy is working with NASA to examine fuel options for Nuclear Thermal Propulsion applications. Extensive development and testing was performed on graphite-based fuels during the Nuclear Engineer Rocket Vehicle Application (NERVA) and Rover programs through the early 1970s. This paper explores the possibility of recapturing the technology and the issues associated with using it for the next generation of nuclear thermal rockets. The issues discussed include a comparison of today's testing capabilities, analysis techniques and methods, and knowledge to that of previous development programs and presents a plan to recapture the technology for a flight program.

  9. Comprehensive two-dimensional gas chromatography for the analysis of synthetic and crude-derived jet fuels.

    PubMed

    van der Westhuizen, Rina; Ajam, Mariam; De Coning, Piet; Beens, Jan; de Villiers, André; Sandra, Pat

    2011-07-15

    Fully synthetic jet fuel (FSJF) produced via Fischer-Tropsch (FT) technology was recently approved by the international aviation fuel authorities. To receive approval, comparison of FSJF and crude-derived fuel and blends on their qualitative and quantitative hydrocarbon composition was of utmost importance. This was performed by comprehensive two-dimensional gas chromatography (GC×GC) in the reversed phase mode. The hydrocarbon composition of synthetic and crude-derived jet fuels is very similar and all compounds detected in the synthetic product are also present in crude-derived fuels. Quantitatively, the synthetic fuel consists of a higher degree of aliphatic branching with less than half the aromatic content of the crude-derived fuel. GC×GC analyses also indicated the presence of trace levels of hetero-atomic impurities in the crude-derived product that were absent in the synthetic product. While clay-treatment removed some of the impurities and improved the fuel stability, the crude-derived product still contained traces of cyclic and aromatic S-containing compounds afterwards. Lower level of aromatics and the absence of sulphur are some of the factors that contribute to the better fuel stability and environmental properties of the synthetic fuel. GC×GC was further applied for the analysis of products during Jet Fuel Thermal Oxidation Testing (JFTOT), which measures deposit formation of a fuel under simulated engine conditions. JFTOT showed the synthetic fuel to be much more stable than the crude-derived fuel.

  10. Production of Jet Fuels from Coal Derived Liquids. Volume 7. GPGP Jet Fuels Production Program. Evaluation of Technical Uncertainties for Producing Jet Fuels from Liquid By-Products of the Great Plains Gasification Plant

    DTIC Science & Technology

    1989-01-01

    AFWAL-TR-87-2042 VOLUME VII PRODUCTION OF JET FUELS FROM COAL DERIVED LIQUIDS I VOLUME VII -- GPGP JET FUELS PRODUCTION PROGRAM -- EVALUATION OF o...from Coal Derived Liquids, Vol VII - GPGP Jet Fuels Production Program - Evaluation of Technical Uncertainties for Producing Jet Fuels from Liquid By...potential of jet fuel production from the liquid by-product streams produced by the gasification of lignite at the Great Plains Gasification Plant ( GPGP

  11. Life cycle assessment of camelina oil derived biodiesel and jet fuel in the Canadian Prairies.

    PubMed

    Li, Xue; Mupondwa, Edmund

    2014-05-15

    This study evaluated the environmental impact of biodiesel and hydroprocessed renewable jet fuel derived from camelina oil in terms of global warming potential, human health, ecosystem quality, and energy resource consumption. The life cycle inventory is based on production activities in the Canadian Prairies and encompasses activities ranging from agricultural production to oil extraction and fuel conversion. The system expansion method is used in this study to avoid allocation and to credit input energy to co-products associated with the products displaced in the market during camelina oil extraction and fuel processing. This is the preferred allocation method for LCA analysis in the context of most renewable and sustainable energy programs. The results show that greenhouse gas (GHG) emissions from 1 MJ of camelina derived biodiesel ranged from 7.61 to 24.72 g CO2 equivalent and 3.06 to 31.01 kg CO2/MJ equivalent for camelina HRJ fuel. Non-renewable energy consumption for camelina biodiesel ranged from 0.40 to 0.67 MJ/MJ; HRJ fuel ranged from -0.13 to 0.52 MJ/MJ. Camelina oil as a feedstock for fuel production accounted for the highest contribution to overall environmental performance, demonstrating the importance of reducing environmental burdens during the agricultural production process. Attaining higher seed yield would dramatically lower environmental impacts associated with camelina seed, oil, and fuel production. The lower GHG emissions and energy consumption associated with camelina in comparison with other oilseed derived fuel and petroleum fuel make camelina derived fuel from Canadian Prairies environmentally attractive.

  12. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect

    Paul A. Erickson

    2006-01-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  13. The use of modified tyre derived fuel for compression ignition engines.

    PubMed

    Pilusa, T J

    2017-02-01

    This study investigated physical and chemical modification of tyre-derived fuel oil (TDFO) obtained from pyrolysis of waste tyres and rubber products for application as an alternative fuel for compression ignition engines (CIE's). TDFO collected from a local waste tyre treatment facility was refined via a novel "oxidative gas-phase fractional distillation over 13× molecular sieves" to recover the light to medium fractions of the TDFO while oxidising and capturing some sulphur compounds in a gas phase. This was followed by desulphurization and chemical modification to improve cetane number, kinematic viscosity and fuel stability. The resulting fuel was tested in an ADE407T truck engine to compare its performance with petroleum diesel fuel. It was discovered that gas phase oxidative fractional distillation reduces the low boiling point sulphur compounds in TDFO such as mercaptans. Using petroleum diesel fuel as a reference, it was observed that the produced fuel has a lower cetane number, flash point and viscosity. On storage the fuel tends to form fibrous microstructures as a result of auto-oxidation of asphaltenes present in the fuel. Mixtures of alkyl nitrate, vinyl acetate, methacrylic anhydride, methyl-tert butyl ether, n-hexane and n-heptane were used to chemically modify the fuel in accordance with the minimum fuel specifications as per SANS 342. The engine performance tests results did not show any sign of engine ceasing or knocking effect. The power-torque trend was very consistent and compared well with petroleum diesel fuelled engine. The levels of total sulphur are still considerably high compared to other cleaner fuel alternatives derived from zero sulphur sources.

  14. Coal/biomass fuels and the gas turbine: Utilization of solid fuels and their derivatives

    SciTech Connect

    DeCorso, M.; Newby, R.; Anson, D.; Wenglarz, R.; Wright, I.

    1996-06-01

    This paper discusses key design and development issues in utilizing coal and other solid fuels in gas turbines. These fuels may be burned in raw form or processed to produce liquids or gases in more or less refined forms. The use of such fuels in gas turbines requires resolution of technology issues which are of little or no consequence for conventional natural gas and refined oil fuels. For coal, these issues are primarily related to the solid form in which coal is naturally found and its high ash and contaminant levels. Biomass presents another set of issues similar to those of coal. Among the key areas discussed are effects of ash and contaminant level on deposition, corrosion, and erosion of turbine hot parts, with particular emphasis on deposition effects.

  15. Life cycle assessment of fuel ethanol derived from corn grain via dry milling.

    PubMed

    Kim, Seungdo; Dale, Bruce E

    2008-08-01

    Life cycle analysis enables to investigate environmental performance of fuel ethanol used in an E10 fueled compact passenger vehicle. Ethanol is derived from corn grain via dry milling. This type of analysis is an important component for identifying practices that will help to ensure that a renewable fuel, such as ethanol, may be produced in a sustainable manner. Based on data from eight counties in seven Corn Belt states as corn farming sites, we show ethanol derived from corn grain as E10 fuel would reduce nonrenewable energy and greenhouse gas emissions, but would increase acidification, eutrophication and photochemical smog, compared to using gasoline as liquid fuel. The ethanol fuel systems considered in this study offer economic benefits, namely more money returned to society than the investment for producing ethanol. The environmental performance of ethanol fuel system varies significantly with corn farming sites because of different crop management practices, soil properties, and climatic conditions. The dominant factor determining most environmental impacts considered here (i.e., greenhouse gas emissions, acidification, eutrophication, and photochemical smog formation) is soil related nitrogen losses (e.g., N2O, NOx, and NO3-). The sources of soil nitrogen include nitrogen fertilizer, crop residues, and air deposition. Nitrogen fertilizer is probably the primary source. Simulations using an agro-ecosystem model predict that planting winter cover crops would reduce soil nitrogen losses and increase soil organic carbon levels, thereby greatly improving the environmental performance of the ethanol fuel system.

  16. Highly selective condensation of biomass-derived methyl ketones as a source of aviation fuel.

    PubMed

    Sacia, Eric R; Balakrishnan, Madhesan; Deaner, Matthew H; Goulas, Konstantinos A; Toste, F Dean; Bell, Alexis T

    2015-05-22

    Aviation fuel (i.e., jet fuel) requires a mixture of C9 -C16 hydrocarbons having both a high energy density and a low freezing point. While jet fuel is currently produced from petroleum, increasing concern with the release of CO2 into the atmosphere from the combustion of petroleum-based fuels has led to policy changes mandating the inclusion of biomass-based fuels into the fuel pool. Here we report a novel way to produce a mixture of branched cyclohexane derivatives in very high yield (>94 %) that match or exceed many required properties of jet fuel. As starting materials, we use a mixture of n-alkyl methyl ketones and their derivatives obtained from biomass. These synthons are condensed into trimers via base-catalyzed aldol condensation and Michael addition. Hydrodeoxygenation of these products yields mixtures of C12 -C21 branched, cyclic alkanes. Using models for predicting the carbon number distribution obtained from a mixture of n-alkyl methyl ketones and for predicting the boiling point distribution of the final mixture of cyclic alkanes, we show that it is possible to define the mixture of synthons that will closely reproduce the distillation curve of traditional jet fuel.

  17. Environmental Life Cycle Assessment of Coal-Biomass to Liquid Jet Fuel Compared to Petroleum-Derived JP-8 Jet Fuel

    DTIC Science & Technology

    2010-03-01

    64 Co- Gasification of Coal and Biomass ...Fuels from Biomass jet fuel components Cellulose CO + H2 “BTL or CBTL” “first generation”“second generation” Lignin gasification (or co- gasification ...than typical petroleum derived fuel resulting in a lower total GWP during the fuel’s life cycle. Gasification is breaking down the coal and biomass

  18. Development of OTM Syngas Process and Testing of Syngas Derived Ultra-clean Fuels in Diesel Engines and Fuel Cells

    SciTech Connect

    E.T. Robinson; John Sirman; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Dan Corgard; John Hemmings

    2005-05-01

    This final report summarizes work accomplished in the Program from January 1, 2001 through December 31, 2004. Most of the key technical objectives for this program were achieved. A breakthrough material system has lead to the development of an OTM (oxygen transport membrane) compact planar reactor design capable of producing either syngas or hydrogen. The planar reactor shows significant advantages in thermal efficiency and a step change reduction in costs compared to either autothermal reforming or steam methane reforming with CO{sub 2} recovery. Syngas derived ultra-clean transportation fuels were tested in the Nuvera fuel cell modular pressurized reactor and in International Truck and Engine single cylinder test engines. The studies compared emission and engine performance of conventional base fuels to various formulations of ultra-clean gasoline or diesel fuels. A proprietary BP oxygenate showed significant advantage in both applications for reducing emissions with minimal impact on performance. In addition, a study to evaluate new fuel formulations for an HCCI engine was completed.

  19. Hydrodeoxygenation processes: advances on catalytic transformations of biomass-derived platform chemicals into hydrocarbon fuels.

    PubMed

    De, Sudipta; Saha, Basudeb; Luque, Rafael

    2015-02-01

    Lignocellulosic biomass provides an attractive source of renewable carbon that can be sustainably converted into chemicals and fuels. Hydrodeoxygenation (HDO) processes have recently received considerable attention to upgrade biomass-derived feedstocks into liquid transportation fuels. The selection and design of HDO catalysts plays an important role to determine the success of the process. This review has been aimed to emphasize recent developments on HDO catalysts in effective transformations of biomass-derived platform molecules into hydrocarbon fuels with reduced oxygen content and improved H/C ratios. Liquid hydrocarbon fuels can be obtained by combining oxygen removal processes (e.g. dehydration, hydrogenation, hydrogenolysis, decarbonylation etc.) as well as by increasing the molecular weight via C-C coupling reactions (e.g. aldol condensation, ketonization, oligomerization, hydroxyalkylation etc.). Fundamentals and mechanistic aspects of the use of HDO catalysts in deoxygenation reactions will also be discussed.

  20. Why parents refuse immunization?

    PubMed

    Kajetanowicz, Andrzej; Kajetanowicz, Aleksandra

    Rates of child immunization are falling in many countries, leading to the increase of morbidity and mortality from diseases controlled by vaccinations. The simplified model of the natural history of immunization follows a sequence of fear of the disease before vaccination, followed by acceptance of the vaccination until plateau, where the population forgets the morbidity and mortality of pre-immunization. Historical factors including withdrawals of vaccines, and publications regarding the true or falsified dangers of vaccines still resonate with parents. Building on these historical factors, unscientific sources such as naturopaths, homeopaths, chiropractors, celebrities and lay-people with anecdotal evidence and even scientific sources such as some universities and some medical doctors push their views on anti-vaccination, which proves to make the decision to vaccinate more difficult on parents. The main reason that parents refuse vaccination is a desire to protect their children. These parents believe that vaccination is harmful, or that not vaccinated children are healthier than vaccinated children. Scientific data often will lose with pseudoscientific, false or anecdotal data that have higher sensational and emotional impact on parents. With so many sources giving so many factors which sometimes contradict themselves, it is indeed difficult for a parent to make a clear decision for their child.

  1. Integrated process for the catalytic conversion of biomass-derived syngas into transportation fuels

    SciTech Connect

    Dagle, Vanessa Lebarbier; Smith, Colin; Flake, Matthew; Albrecht, Karl O.; Gray, Michel J.; Ramasamy, Karthikeyan K.; Dagle, Robert A.

    2016-01-01

    Efficient synthesis of renewable fuels that will enable cost competitiveness with petroleum-derived fuels remains a grand challenge for U.S. scientists. In this paper, we report on an integrated catalytic approach for producing transportation fuels from biomass-derived syngas. The composition of the resulting hydrocarbon fuel can be modulated to meet specified requirements. Biomass-derived syngas is first converted over an Rh-based catalyst into a complex aqueous mixture of condensable C2+ oxygenated compounds (predominantly ethanol, acetic acid, acetaldehyde, ethyl acetate). This multi-component aqueous mixture then is fed to a second reactor loaded with a ZnxZryOz mixed oxide catalyst, which has tailored acid-base sites, to produce an olefin mixture rich in isobutene. The olefins then are oligomerized using a solid acid catalyst (e.g., Amberlyst-36) to form condensable olefins with molecular weights that can be targeted for gasoline, jet, and/or diesel fuel applications. The product rich in long-chain olefins (C7+) is finally sent to a fourth reactor that is needed for hydrogenation of the olefins into paraffin fuels. Simulated distillation of the hydrotreated oligomerized liquid product indicates that ~75% of the hydrocarbons present are in the jet-fuel range. Process optimization for the oligomerization step could further improve yield to the jet-fuel range. All of these catalytic steps have been demonstrated in sequence, thus providing proof-of-concept for a new integrated process for the production of drop-in biofuels. This unique and flexible process does not require external hydrogen and also could be applied to non-syngas derived feedstock, such as fermentation products (e.g., ethanol, acetic acid, etc.), other oxygenates, and mixtures thereof containing alcohols, acids, aldehydes and/or esters.

  2. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    DOEpatents

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2016-07-05

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  3. Production of Jet Fuels from Coal Derived Liquids. Volume 4. GPGP Jet Fuels Production Program-Feed Analyses Compilation and Review

    DTIC Science & Technology

    1988-07-01

    DTICFORM70ASTOCK IS EXHAUSTED. o Volume IV 00 PRODUCTION OF JET FUELS FROM COAL DERIVED LIQUIDS SVOL IV - GPGP JET FUELS PRODUCTION PROGRAM-FEEDI ANALYSES...DERIVED LIQUIDS - VOL IV - GPGP JET FUELS PRODUCTION PROGRAM - FEED ANALYSIS COMPILATION AND REVIEW 12. PERSONAL AUTHOR(S) R.J. Rossi 13a. TYPE OF REPORT...the gasification of lignite at the Great Plains Gasification Plant ( GPGP ) in Beulah, North Dakota. Funding has been provided to the Department of

  4. Effects of coal-derived trace species on performance of molten carbonate fuel cells. Final report

    SciTech Connect

    Not Available

    1992-05-01

    The Carbonate Fuel Cell is a very promising option for highly efficient generation of electricity from many fuels. If coal-gas is to be used, the interactions of coal-derived impurities on various fuel cell components need to be understood. Thus the effects on Carbonate Fuel Cell performance due to ten different coal-derived contaminants viz., NH{sub 3}, H{sub 2}S, HC{ell}, H{sub 2}Se, AsH{sub 3}, Zn, Pb, Cd, Sn, and Hg, have been studied at Energy Research Corporation. Both experimental and theoretical evaluations were performed, which have led to mechanistic insights and initial estimation of qualitative tolerance levels for each species individually and in combination with other species. The focus of this study was to investigate possible coal-gas contaminant effects on the anode side of the Carbonate Fuel Cell, using both out-of-cell thermogravimetric analysis by isothermal TGA, and fuel cell testing in bench-scale cells. Separate experiments detailing performance decay in these cells with high levels of ammonia contamination (1 vol %) and with trace levels of Cd, Hg, and Sn, have indicated that, on the whole, these elements do not affect carbonate fuel cell performance. However, some performance decay may result when a number of the other six species are present, singly or simultaneously, as contaminants in fuel gas. In all cases, tolerance levels have been estimated for each of the 10 species and preliminary models have been developed for six of them. At this stage the models are limited to isothermal, benchscale (300 cm{sup 2} size) single cells. The information obtained is expected to assist in the development of coal-gas cleanup systems, while the contaminant performance effects data will provide useful basic information for modeling fuel cell endurance in conjunction with integrated gasifier/fuel-cell systems (IGFC).

  5. Effects of coal-derived trace species on performance of molten carbonate fuel cells

    SciTech Connect

    Not Available

    1992-05-01

    The Carbonate Fuel Cell is a very promising option for highly efficient generation of electricity from many fuels. If coal-gas is to be used, the interactions of coal-derived impurities on various fuel cell components need to be understood. Thus the effects on Carbonate Fuel Cell performance due to ten different coal-derived contaminants viz., NH{sub 3}, H{sub 2}S, HC{ell}, H{sub 2}Se, AsH{sub 3}, Zn, Pb, Cd, Sn, and Hg, have been studied at Energy Research Corporation. Both experimental and theoretical evaluations were performed, which have led to mechanistic insights and initial estimation of qualitative tolerance levels for each species individually and in combination with other species. The focus of this study was to investigate possible coal-gas contaminant effects on the anode side of the Carbonate Fuel Cell, using both out-of-cell thermogravimetric analysis by isothermal TGA, and fuel cell testing in bench-scale cells. Separate experiments detailing performance decay in these cells with high levels of ammonia contamination (1 vol %) and with trace levels of Cd, Hg, and Sn, have indicated that, on the whole, these elements do not affect carbonate fuel cell performance. However, some performance decay may result when a number of the other six species are present, singly or simultaneously, as contaminants in fuel gas. In all cases, tolerance levels have been estimated for each of the 10 species and preliminary models have been developed for six of them. At this stage the models are limited to isothermal, benchscale (300 cm{sup 2} size) single cells. The information obtained is expected to assist in the development of coal-gas cleanup systems, while the contaminant performance effects data will provide useful basic information for modeling fuel cell endurance in conjunction with integrated gasifier/fuel-cell systems (IGFC).

  6. Use of pyrolysis-derived fuel in a gas turbine engine

    SciTech Connect

    Kasper, J.M.; Jasas, G.B.; Trauth, R.L.

    1983-01-01

    Combustion of a pyrolytically derived oil has been demonstrated in a J69-T-29 gas turbine combustor rig. The fuel was derived from agricultural and forest products/wastes through a pyrolysis conversion process which yields the oil and a residual char. The char was ground to a mean size of 25 microns and mixed with the oil and JP-4 in additional combustor rig tests. Analysis of the oil and char showed that both have hydrogen/carbon ratios less than 1.0 for the combustible components. The oil has a water content of 29%, a room temperature viscosity of 250 cS, and a pH of 2.9. The combustion system of the J69 consists of an annular combustor and a centrifugal fuel injector rotating as shaft speed. The centrifugal fuel injector can use slurry fuels without clogging and provides good atomization with viscous fuels. The combustor rig was operated at pressures and temperatures lower than those of the engine, and JP-4 was used as a baseline fuel. Test results indicate that use of pyrolytic oil will result in engine combustion efficiencies of over 99%. The pyrolytic oil may also be used as a supplement to JP-4. Additional development will be necessary to use the pyrolytic char as a gas turbine fuel.

  7. Recent Perspectives Concerning School Refusal Behavior

    ERIC Educational Resources Information Center

    Witts, Benjamin; Houlihan, Daniel

    2007-01-01

    A review of the literature regarding school refusal was conducted. It was found that the term School Refusal Behavior has gone through many changes. These changes encompass nomenclature, etiology, and treatment. The names used to describe the behavior of school refusal have ranged from truancy in the 1930s to School Refusal Behavior in the 1990s.…

  8. Fuel areal density distributions derived from nuclear scattering signatures

    NASA Astrophysics Data System (ADS)

    Bionta, R. M.; Casey, D. T.; Cerjan, C. J.; Yeamans, C. B.; Gatu Johnson, M. G.

    2016-10-01

    The spatial variation of activities measured in the array of 20 Nuclear Activation Detectors mounted on the flanges around the NIF target chamber (FNADs) are correlated with asymmetries in the underlying fuel areal density of compressed ICF targets. The asymmetric areal density distributions cause variations in the neutron spectra with direction which are seen in the dsr (down scattered ratio) metric, the ratio of the number of 10-12 MeV neutrons to the number of 13-15 MeV neutrons. We show, using a simple physics based simulation of neutron scattering through an idealized non-uniform DT shell with a realistic neutron source, that for most shots an areal distribution can be found which reproduces both the FNAD activity and the dsr measurements. Furthermore, by linking the simulation to a Marquardt minimizer, we fit the areal distribution to a truncated set of spherical harmonics. Prepared by LLNL under Contract DE-AC52-07NA27344.

  9. Towards Safer Rocket Fuels: Hypergolic Imidazolylidene-Borane Compounds as Replacements for Hydrazine Derivatives.

    PubMed

    Huang, Shi; Qi, Xiujuan; Liu, Tianlin; Wang, Kangcai; Zhang, Wenquan; Li, Jianlin; Zhang, Qinghua

    2016-07-11

    Currently, toxic and volatile hydrazine derivatives are still the main fuel choices for liquid bipropellants, especially in some traditional rocket propulsion systems. Therefore, the search for safer hypergolic fuels as replacements for hydrazine derivatives has been one of the most challenging tasks. In this study, six imidazolylidene-borane compounds with zwitterionic structure have been synthesized and characterized, and their hypergolic reactivity has been studied. As expected, these compounds exhibited fast spontaneous combustion upon contact with white fuming nitric acid (WFNA). Among them, compound 5 showed excellent integrated properties including wide liquid operating range (-70-160 °C), superior loading density (0.99 g cm(-3) ), ultrafast ignition delay times with WFNA (15 ms), and high specific impulse (303.5 s), suggesting promising application potential as safer hypergolic fuels in liquid bipropellant formulations.

  10. Heterogeneous catalysts for the transformation of fatty acid triglycerides and their derivatives to fuel hydrocarbons

    NASA Astrophysics Data System (ADS)

    Yakovlev, Vadim A.; Khromova, Sofia A.; Bukhtiyarov, Valerii I.

    2011-10-01

    The results of studies devoted to the catalysts for transformation of fatty acid triglycerides and their derivatives to fuel hydrocarbons are presented and described systematically. Various approaches to the use of heterogeneous catalysts for the production of biofuel from these raw materials are considered. The bibliography includes 134 references.

  11. QUANTIFYING HAZARDOUS SPECIES IN PARTICULATE MATTER DERIVED FROM FOSSIL-FUEL COMBUSTION

    EPA Science Inventory

    An analysis protocol that combines X-ray absorption near-edge structure spectroscopy with selective leaching has been developed to examine hazardous species in size- segregated particulate matter (PM) samples derived from the combustion of fossil fuels. The protocol has been used...

  12. Bioconversion of coal derived synthesis gas to liquid fuels

    NASA Astrophysics Data System (ADS)

    Jain, M. K.; Worden, R. M.; Grethlein, A.

    1994-07-01

    The overall objective of the project is to develop an integrated two-stage fermentation process for conversion of coal-derived synthesis gas to a mixture of alcohols. This is achieved in two steps. In the first step, Butyribacterium methylotrophicum converts carbon monoxide (CO) to butyric and acetic acids. Subsequent fermentation of the acids by Clostridium acetobutylicum leads to the production of butanol and ethanol. The tasks for this quarter were: development/isolation of superior strains for fermentation of syngas; evaluation of bioreactor configuration for improved mass transfer of syngas; recovery of carbon and electrons from H2-CO2; initiation of pervaporation for recovery of solvents; and selection of solid support material for trickle-bed fermentation. Technical progress included the following: butyrate production was enhanced during H2/CO2 (50/50) batch fermentation; isolation of CO-utilizing anaerobic strains is in progress; pressure (15 psig) fermentation was evaluated as a means of increasing CO availability; polyurethane foam packing material was selected for trickle bed solid support; cell recycle fermentation on syngas operated for 3 months. Acetate was the primary product at pH 6.8; trickle bed and gas lift fermentor designs were modified after initial water testing; and pervaporation system was constructed (No alcohol selectivity was shown with the existing membranes during initial start-up).

  13. Potential hazards associated with combustion of bio-derived versus petroleum-derived diesel fuel

    PubMed Central

    Bünger, Jürgen; Krahl, Jürgen; Schröder, Olaf; Schmidt, Lasse; Westphal, Götz A.

    2012-01-01

    Fuels from renewable resources have gained worldwide interest due to limited fossil oil sources and the possible reduction of atmospheric greenhouse gas. One of these fuels is so called biodiesel produced from vegetable oil by transesterification into fatty acid methyl esters (FAME). To get a first insight into changes of health hazards from diesel engine emissions (DEE) by use of biodiesel scientific studies were reviewed which compared the combustion of FAME with common diesel fuel (DF) for legally regulated and non-regulated emissions as well as for toxic effects. A total number of 62 publications on chemical analyses of DEE and 18 toxicological in vitro studies were identified meeting the criteria. In addition, a very small number of human studies and animal experiments were available. In most studies, combustion of biodiesel reduces legally regulated emissions of carbon monoxide, hydrocarbons, and particulate matter. Nitrogen oxides are regularly increased. Among the non-regulated emissions aldehydes are increased, while polycyclic aromatic hydrocarbons are lowered. Most biological in vitro assays show a stronger cytotoxicity of biodiesel exhaust and the animal experiments reveal stronger irritant effects. Both findings are possibly caused by the higher content of nitrogen oxides and aldehydes in biodiesel exhaust. The lower content of PAH is reflected by a weaker mutagenicity compared to DF exhaust. However, recent studies show a very low mutagenicity of DF exhaust as well, probably caused by elimination of sulfur in present DF qualities and the use of new technology diesel engines. Combustion of vegetable oil (VO) in common diesel engines causes a strongly enhanced mutagenicity of the exhaust despite nearly unchanged regulated emissions. The newly developed fuel “hydrotreated vegetable oil” (HVO) seems to be promising. HVO has physical and chemical advantages compared to FAME. Preliminary results show lower regulated and non-regulated emissions and a

  14. Potential hazards associated with combustion of bio-derived versus petroleum-derived diesel fuel.

    PubMed

    Bünger, Jürgen; Krahl, Jürgen; Schröder, Olaf; Schmidt, Lasse; Westphal, Götz A

    2012-10-01

    Fuels from renewable resources have gained worldwide interest due to limited fossil oil sources and the possible reduction of atmospheric greenhouse gas. One of these fuels is so called biodiesel produced from vegetable oil by transesterification into fatty acid methyl esters (FAME). To get a first insight into changes of health hazards from diesel engine emissions (DEE) by use of biodiesel scientific studies were reviewed which compared the combustion of FAME with common diesel fuel (DF) for legally regulated and non-regulated emissions as well as for toxic effects. A total number of 62 publications on chemical analyses of DEE and 18 toxicological in vitro studies were identified meeting the criteria. In addition, a very small number of human studies and animal experiments were available. In most studies, combustion of biodiesel reduces legally regulated emissions of carbon monoxide, hydrocarbons, and particulate matter. Nitrogen oxides are regularly increased. Among the non-regulated emissions aldehydes are increased, while polycyclic aromatic hydrocarbons are lowered. Most biological in vitro assays show a stronger cytotoxicity of biodiesel exhaust and the animal experiments reveal stronger irritant effects. Both findings are possibly caused by the higher content of nitrogen oxides and aldehydes in biodiesel exhaust. The lower content of PAH is reflected by a weaker mutagenicity compared to DF exhaust. However, recent studies show a very low mutagenicity of DF exhaust as well, probably caused by elimination of sulfur in present DF qualities and the use of new technology diesel engines. Combustion of vegetable oil (VO) in common diesel engines causes a strongly enhanced mutagenicity of the exhaust despite nearly unchanged regulated emissions. The newly developed fuel "hydrotreated vegetable oil" (HVO) seems to be promising. HVO has physical and chemical advantages compared to FAME. Preliminary results show lower regulated and non-regulated emissions and a

  15. Air emission from the co-combustion of alternative derived fuels within cement plants: Gaseous pollutants.

    PubMed

    Richards, Glen; Agranovski, Igor E

    2015-02-01

    Cement manufacturing is a resource- and energy-intensive industry, utilizing 9% of global industrial energy use while releasing more than 5% of global carbon dioxide (CO₂) emissions. With an increasing demand of production set to double by 2050, so too will be its carbon footprint. However, Australian cement plants have great potential for energy savings and emission reductions through the substitution of combustion fuels with a proportion of alternative derived fuels (ADFs), namely, fuels derived from wastes. This paper presents the environmental emissions monitoring of 10 cement batching plants while under baseline and ADF operating conditions, and an assessment of parameters influencing combustion. The experiential runs included the varied substitution rates of seven waste streams and the monitoring of seven target pollutants. The co-combustion tests of waste oil, wood chips, wood chips and plastic, waste solvents, and shredded tires were shown to have the minimal influence when compared to baseline runs, or had significantly reduced the unit mass emission factor of pollutants. With an increasing ADF% substitution, monitoring identified there to be no subsequent emission effects and that key process parameters contributing to contaminant suppression include (1) precalciner and kiln fuel firing rate and residence time; (2) preheater and precalciner gas and material temperature; (3) rotary kiln flame temperature; (4) fuel-air ratio and percentage of excess oxygen; and (5) the rate of meal feed and rate of clinker produced.

  16. Bio-derived Fuel Blend Dilution of Marine Engine Oil and Imapct on Friction and Wear Behavior

    SciTech Connect

    Ajayi, Oyelayo O.; Lorenzo-Martin, Cinta; Fenske, George R.; Corlett, John; Murphy, Chris; Przesmitzki, Steve

    2016-04-01

    To reduce the amount of petroleum-derived fuel used in vehicles and vessels powered by internal combustion engines, the addition of bio-derived fuel extenders is a common practice. Ethanol is perhaps the most common bio-derived fuel used for blending, and butanol is being evaluated as a promising alternative. The present study determined the fuel dilution rate of three lubricating oils (E0, E10, and i-B16) in a marine engine operating in on-water conditions with a start-and-stop cycle protocol. The level of fuel dilution increased with the number of cycles for all three fuels. The most dilution was observed with i-B16 fuel, and the least with E10 fuel. In all cases, fuel dilution substantially reduced the oil viscosity. The impacts of fuel dilution and the consequent viscosity reduction on the lubricating capability of the engine oil in terms of friction, wear, and scuffing prevention were evaluated by four different tests protocols. Although the fuel dilution of the engine oil had minimal effect on friction, because the test conditions were under the boundary lubrication regime, significant effects were observed on wear in many cases. Fuel dilution also was observed to reduce the load-carrying capacity of the engine oils in terms of scuffing load reduction.

  17. Alternative Bio-Derived JP-8 Class Fuel and JP-8 Fuel: Flame Tube Combustor Test Results Compared using a GE TAPS Injector Configuration

    NASA Technical Reports Server (NTRS)

    Hicks, Yolanda R.; Tedder, Sarah A.; Anderson, Robert C.

    2016-01-01

    This paper presents results from tests in a flame tube facility, where a bio-derived alternate fuel was compared with JP-8 for emissions and general combustion performance. A research version of General Electric Aviation (GE) TAPS injector was used for the tests. Results include combustion efficiency from gaseous emission measurements, 2D planar laser-based imaging as well as basic flow visualization of the flame. Four inlet test conditions were selected that simulate various engine power conditions relevant to NASA Fundamental Aeronautics Supersonics Project and Environmentally Responsible Aviation Program. One inlet condition was a pilot-only test point. The other three inlet conditions incorporated fuel staging via a split between the pilot and main circuits of either 10%/90% or 20%/80%. For each engine power condition, three fuel mixes were used: 100% JP-8; 100% alternative; and a blend of the two, containing 75% alternative. Results for the inlet cases that have fuel split between pilot and main, indicate that fuel from the pilot appears to be evaporated by the time it reaches the dome exit. Main circuit liquid evaporates within a downstream distance equal to annulus height, no matter the fuel. Some fuel fluorescence images for a 10%/90% fuel staging case show a distinct difference between JP-8 and bio-derived fuel. OH PLIF results indicate that OH forms in a region more centrally-located for the JP-8 case downstream of the pilot, in its central recirculation region (CRZ). For the bio-derived Hydrotreated Renewable Jet (HRJ) fuel, however, we do not see much OH in the CRZ. The OH image structure near the dome exit is similar for the two fuels, but farther downstream the OH in the CRZ is much more apparent for the JP-8 than for the alternate fuel. For all conditions, there was no discernable difference between fuel types in combustion efficiency or emissions.

  18. Evaluation of tire-derived fuel for use in nitrogen oxide reduction by reburning.

    PubMed

    Miller, C A; Lemieux, P M; Touati, A

    1998-08-01

    Tire-derived fuel (TDF) was tested in a small-scale (44 kW or 150,000 Btu/hr) combustor to determine its feasibility as a fuel for use in reburning for control of nitrogen oxide (NO). TDF was gravity-fed into upward flowing combustion gases from a primary natural gas flame doped with ammonia to simulate a high NO combustion process. Emissions of NO, oxygen, carbon dioxide, carbon monoxide, and particulate matter were measured. The tests varied the nominal primary NO level from 600 to 1,200 ppm and the primary stoichiometry from 1.1 to 1.2, and used both natural gas and TDF as reburn fuels. The reburn injection rate was varied to achieve 8-20% of the total heat input from the reburn fuel. NO emissions reductions ranged between 20 and 63% when using TDF, depending upon the rate of TDF injection, primary NO, and primary stoichiometry. NO emission reductions when using natural gas as the reburn fuel were consistently higher than those when using TDF. While additional work remains to optimize the process and evaluate costs, TDF has been shown to have the potential to be a technically viable reburning fuel.

  19. Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates.

    PubMed

    Román-Leshkov, Yuriy; Barrett, Christopher J; Liu, Zhen Y; Dumesic, James A

    2007-06-21

    Diminishing fossil fuel reserves and growing concerns about global warming indicate that sustainable sources of energy are needed in the near future. For fuels to be useful in the transportation sector, they must have specific physical properties that allow for efficient distribution, storage and combustion; these properties are currently fulfilled by non-renewable petroleum-derived liquid fuels. Ethanol, the only renewable liquid fuel currently produced in large quantities, suffers from several limitations, including low energy density, high volatility, and contamination by the absorption of water from the atmosphere. Here we present a catalytic strategy for the production of 2,5-dimethylfuran from fructose (a carbohydrate obtained directly from biomass or by the isomerization of glucose) for use as a liquid transportation fuel. Compared to ethanol, 2,5-dimethylfuran has a higher energy density (by 40 per cent), a higher boiling point (by 20 K), and is not soluble in water. This catalytic strategy creates a route for transforming abundant renewable biomass resources into a liquid fuel suitable for the transportation sector, and may diminish our reliance on petroleum.

  20. A preliminary assessment of the feasibility of deriving liquid and gaseous fuels from grown and waste organics

    NASA Technical Reports Server (NTRS)

    Graham, R. W.; Reynolds, T. W.; Hsu, Y. Y.

    1976-01-01

    The anticipated depletion of our resources of natural gas and petroleum in a few decades has caused a search for renewable sources of fuel. Among the possibilities is the chemical conversion of waste and grown organic matter into gaseous or liquid fuels. The overall feasibility of such a system is considered from the technical, economic, and social viewpoints. Although there are a number of difficult problems to overcome, this preliminary study indicates that this option could provide between 4 and 10 percent of the U.S. energy needs. Estimated costs of fuels derived from grown organic material are appreciably higher than today's market price for fossil fuel. The cost of fuel derived from waste organics is competitive with fossil fuel prices. Economic and social reasons will prohibit the allocation of good food producing land to fuel crop production.

  1. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect

    Paul A. Erickson

    2004-06-30

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the third report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 30, 2004. This quarter saw progress in five areas. These areas are: (1) External evaluation of coal based methanol and the fuel cell grade baseline fuel, (2) Design, set up and initial testing of the autothermal reactor, (3) Experiments to determine the axial and radial thermal profiles of the steam reformers, (4) Catalyst degradation studies, and (5) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  2. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect

    Paul A. Erickson

    2004-04-01

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

  3. Thermal stability of some aircraft turbine fuels derived from oil shale and coal

    NASA Technical Reports Server (NTRS)

    Reynolds, T. W.

    1977-01-01

    Thermal stability breakpoint temperatures are shown for 32 jet fuels prepared from oil shale and coal syncrudes by various degrees of hydrogenation. Low severity hydrotreated shale oils, with nitrogen contents of 0.1 to 0.24 weight percent, had breakpoint temperatures in the 477 to 505 K (400 to 450 F) range. Higher severity treatment, lowering nitrogen levels to 0.008 to 0.017 weight percent, resulted in breakpoint temperatures in the 505 to 533 K (450 to 500 F) range. Coal derived fuels showed generally increasing breakpoint temperatures with increasing weight percent hydrogen, fuels below 13 weight percent hydrogen having breakpoints below 533 K (500 F). Comparisons are shown with similar literature data.

  4. Urban residential refuse composition and generation rates for the 20th century.

    PubMed

    Walsh, Daniel C

    2002-11-15

    Examination of historical data shows that 3.5 x 10(8) tonnes (t) of residential refuse was discarded in New York City (NYC) during the 20th century. Maximum and minimum rates of per capita mass discard of residential refuse during this time are reported in 1940 (940 kg per capita yr(-1)) and 1961, 1963 (320 kg per capita yr(-1)), respectively. Since 1980, per capita residential refuse discard rates have been steady and comparatively low (430 kg per capita yr(-1) +/- 2.5%). Fuel ash accounted for approximately 34% of residential refuse in NYC during the century. A decline of refuse bulk density (as collected) from approximately 500 to 200 kg m(-3) and an increase in refuse organic matter content from 20% to 80% (by mass) is reported between 1920 and 1990 and is due largely to mass fraction reductions forfuel ash and increases for paper and plastic. Approximately 4.9 x 10(8) t of refuse was disposed in NYC during the 20th century (including commercial and residential refuse), representing a total pool of about 8.0 x 10(7) t of organic carbon (as C) that has entered city landfills and incinerators.

  5. 33 CFR 401.89 - Transit refused.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 3 2011-07-01 2011-07-01 false Transit refused. 401.89 Section... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations General § 401.89 Transit refused. (a) An officer may refuse to allow a vessel to transit when, (1) The vessel is not equipped in accordance with §§ 401.5...

  6. 33 CFR 401.89 - Transit refused.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 3 2012-07-01 2012-07-01 false Transit refused. 401.89 Section... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations General § 401.89 Transit refused. (a) An officer may refuse to allow a vessel to transit when, (1) The vessel is not equipped in accordance with §§ 401.5...

  7. 33 CFR 401.89 - Transit refused.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 3 2014-07-01 2014-07-01 false Transit refused. 401.89 Section... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations General § 401.89 Transit refused. (a) An officer may refuse to allow a vessel to transit when, (1) The vessel is not equipped in accordance with §§ 401.5...

  8. 33 CFR 401.89 - Transit refused.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 3 2010-07-01 2010-07-01 false Transit refused. 401.89 Section... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations General § 401.89 Transit refused. (a) An officer may refuse to allow a vessel to transit when, (1) The vessel is not equipped in accordance with §§ 401.5...

  9. 33 CFR 401.89 - Transit refused.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 3 2013-07-01 2013-07-01 false Transit refused. 401.89 Section... TRANSPORTATION SEAWAY REGULATIONS AND RULES Regulations General § 401.89 Transit refused. (a) An officer may refuse to allow a vessel to transit when, (1) The vessel is not equipped in accordance with §§ 401.5...

  10. Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper

    NASA Astrophysics Data System (ADS)

    Li, Christina W.; Ciston, Jim; Kanan, Matthew W.

    2014-04-01

    The electrochemical conversion of CO2 and H2O into liquid fuel is ideal for high-density renewable energy storage and could provide an incentive for CO2 capture. However, efficient electrocatalysts for reducing CO2 and its derivatives into a desirable fuel are not available at present. Although many catalysts can reduce CO2 to carbon monoxide (CO), liquid fuel synthesis requires that CO is reduced further, using H2O as a H+ source. Copper (Cu) is the only known material with an appreciable CO electroreduction activity, but in bulk form its efficiency and selectivity for liquid fuel are far too low for practical use. In particular, H2O reduction to H2 outcompetes CO reduction on Cu electrodes unless extreme overpotentials are applied, at which point gaseous hydrocarbons are the major CO reduction products. Here we show that nanocrystalline Cu prepared from Cu2O (`oxide-derived Cu') produces multi-carbon oxygenates (ethanol, acetate and n-propanol) with up to 57% Faraday efficiency at modest potentials (-0.25 volts to -0.5 volts versus the reversible hydrogen electrode) in CO-saturated alkaline H2O. By comparison, when prepared by traditional vapour condensation, Cu nanoparticles with an average crystallite size similar to that of oxide-derived copper produce nearly exclusive H2 (96% Faraday efficiency) under identical conditions. Our results demonstrate the ability to change the intrinsic catalytic properties of Cu for this notoriously difficult reaction by growing interconnected nanocrystallites from the constrained environment of an oxide lattice. The selectivity for oxygenates, with ethanol as the major product, demonstrates the feasibility of a two-step conversion of CO2 to liquid fuel that could be powered by renewable electricity.

  11. Preliminary Investigation for Engine Performance by Using Tire-Derived Pyrolysis Oil-Diesel Blended Fuels

    NASA Astrophysics Data System (ADS)

    Rofiqul, Islam M.; Haniu, Hiroyuki; Alam, Beg R.; Takai, Kazunori

    In the first phase of the present study, the pyrolysis oil derived from light automotive tire waste has been characterized including fuel properties, elemental analyses, FT-IR, 1H-NMR, GC-MS and distillation. The studies on the oil show that it can be used as liquid fuel with a gross calorific value (GCV) of 42.00 MJ/kg and empirical formula of CH1.27O0.025N0.006. In the second phase of the investigation, the performance of a diesel engine was studied blending the pyrolysis oil with diesel fuel in different ratios. The experimental results show that the bsfc of pyrolysis oil-diesel blended fuels slightly increases and hence the brake thermal efficiency decreases compared to those of neat diesel. The pyrolysis oil-diesel blends show lower carbon monoxide (CO) emission but higher oxides of nitrogen (NOx) emissions than those of neat diesel. However, NOx emissions with pyrolysis oil-diesel blended fuels reduced when EGR was applied.

  12. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect

    Paul A. Erickson

    2006-04-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

  13. Reduction of CO2 Emissions from Mobile Sources by Alternative Fuels Derived from Biomass.

    DTIC Science & Technology

    1993-11-01

    those goals with alcohol fuels derived from biomass produced as short-rotation woody crops. Emphasis is on the Hydrocarb process , now under evaluation...that a process such as Hydrocarb, that can leverage biomass with natural gas, should maximize petroleum displacement at least cost. Because of these...on the Hydrocarb process , now under evaluation by the EPA for production of methanol from biomass and natural gas. Factors considered in this

  14. 36 CFR 1002.14 - Sanitation and refuse.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 3 2013-07-01 2012-07-01 true Sanitation and refuse. 1002.14... RECREATION § 1002.14 Sanitation and refuse. (a) The following are prohibited: (1) Disposing of refuse in other than refuse receptacles. (2) Using government refuse receptacles or other refuse facilities...

  15. Investigation of Engineering and Design Considerations in Selecting Conveyors for Densified Refuse-Derived Fuel (dRDF) and dRDF: Coal Mixtures.

    DTIC Science & Technology

    1981-08-01

    16 Vibrated Bulk Density ... ........... . 18 Angle of External Friction; Angle of Internal Friction, Cohesiveness, Flowability ... Flowability -- flow functiont 13. Lumps - size - weight 14. Specific gravity* 15. Moisture Content 16. Particle Hardness 17. Screen Analysis and particle...the conveyor can be loaded to a maximum capacity (i.e., filling a maximum belt cross section) under static conditions (i.e., with the belt at rest

  16. RDF (Refuse-Derived Fuel) Co-Firing Cost/Benefit Analysis Using the NCEL RDF Cost Model. Volume 1. Project Results.

    DTIC Science & Technology

    1986-08-01

    2-1 2.2 Initial Data Collection . ................ 2-2 3.0 Case Study Cost/Benefit Analysis ..... .............. ... 3-1 3.1 Introduction...RDFCostModl. VlumeII* ..,,.. continstherefrencd apenic . Tese ppedics cntai prgra ,-’-’ litigs mdfiatondtals cmlee rorm utut oreah civty vi"i-.... and ativiy...considerable effort in the study of the RDF technology. This has included the determination of optimum heat recovery incinerator (HRI) design, the systemization

  17. POLYCHLORINATED DIBENZO-P-DIOXINS AND DIBENZOFURANS: REMOVAL FROM FLUE GAS AND DISTRIBUTION IN ASH/RESIDUE OF A REFUSE-DERIVED FUEL COMBUSTOR

    EPA Science Inventory

    The paper gives results of an early-1989 investigation of the effect of changing combustion and flue gas cleaning (FGC) system variables on the performance of these systems. Using information from earlier characterization tests at the same site (Mid-Connecticut facility in Hartfo...

  18. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect

    Paul A. Erickson

    2005-04-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

  19. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect

    Paul A. Erickson

    2005-09-30

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the eighth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2004-September 30, 2005 and includes an entire review of the progress for year 2 of the project. This year saw progress in eight areas. These areas are: (1) steam reformer transient response, (2) steam reformer catalyst degradation, (3) steam reformer degradation tests using bluff bodies, (4) optimization of bluff bodies for steam reformation, (5) heat transfer enhancement, (6) autothermal reforming of coal derived methanol, (7) autothermal catalyst degradation, and (8) autothermal reformation with bluff bodies. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  20. NREL Evaluates Performance of Hydraulic Hybrid Refuse Vehicles

    SciTech Connect

    2015-09-01

    This highlight describes NREL's evaluation of the in-service performance of 10 next-generation hydraulic hybrid refuse vehicles (HHVs), 8 previous-generation (model year 2013) HHVs, and 8 comparable conventional diesel vehicles operated by Miami-Dade County's Public Works and Waste Management Department in southern Florida. Launched in March 2015, the on-road portion of this 12-month evaluation focuses on collecting and analyzing vehicle performance data - fuel economy, maintenance costs, and drive cycles - from the HHVs and the conventional diesel vehicles. The fuel economy of heavy-duty vehicles, such as refuse trucks, is largely dependent on the load carried and the drive cycles on which they operate. In the right applications, HHVs offer a potential fuel-cost advantage over their conventional counterparts. This advantage is contingent, however, on driving behavior and drive cycles with high kinetic intensity that take advantage of regenerative braking. NREL's evaluation will assess the performance of this technology in commercial operation and help Miami-Dade County determine the ideal routes for maximizing the fuel-saving potential of its HHVs. Based on the field data, NREL will develop a validated vehicle model using the Future Automotive Systems Technology Simulator, also known as FASTSim, to study the impacts of route selection and other vehicle parameters. NREL is also analyzing fueling and maintenance data to support total-cost-of-ownership estimations and forecasts. The study aims to improve understanding of the overall usage and effectiveness of HHVs in refuse operation compared to similar conventional vehicles and to provide unbiased technical information to interested stakeholders.

  1. Biomass-derived Syngas Utilization for Fuels and Chemicals - Final Report

    SciTech Connect

    Dayton, David C

    2010-03-24

    Executive Summary The growing gap between petroleum production and demand, mounting environmental concerns, and increasing fuel prices have stimulated intense interest in research and development (R&D) of alternative fuels, both synthetic and bio-derived. Currently, the most technically defined thermochemical route for producing alternative fuels from lignocellulosic biomass involves gasification/reforming of biomass to produce syngas (carbon monoxide [CO] + hydrogen [H2]), followed by syngas cleaning, Fischer-Tropsch synthesis (FTS) or mixed alcohol synthesis, and some product upgrading via hydroprocessing or separation. A detailed techno-economic analysis of this type of process has recently been published [1] and it highlights the need for technical breakthroughs and technology demonstration for gas cleanup and fuel synthesis. The latter two technical barrier areas contribute 40% of the total thermochemical ethanol cost and 70% of the production cost, if feedstock costs are factored out. Developing and validating technologies that reduce the capital and operating costs of these unit operations will greatly reduce the risk for commercializing integrated biomass gasification/fuel synthesis processes for biofuel production. The objective of this project is to develop and demonstrate new catalysts and catalytic processes that can efficiently convert biomass-derived syngas into diesel fuel and C2-C4 alcohols. The goal is to improve the economics of the processes by improving the catalytic activity and product selectivity, which could lead to commercialization. The project was divided into 4 tasks: Task 1: Reactor Systems: Construction of three reactor systems was a project milestone. Construction of a fixed-bed microreactor (FBR), a continuous stirred tank reactor (CSTR), and a slurry bubble column reactor (SBCR) were completed to meet this milestone. Task 2: Iron Fischer-Tropsch (FT) Catalyst: An attrition resistant iron FT catalyst will be developed and tested

  2. Quantifying hazardous species in particulate matter derived from fossil-fuel combustion.

    PubMed

    Huggins, Frank E; Huffman, Gerald P; Linak, William P; Miller, C Andrew

    2004-03-15

    An analysis protocol that combines X-ray absorption near-edge structure spectroscopy with selective leaching has been developed to examine hazardous species in size-segregated particulate matter (PM) samples derived from the combustion of fossil fuels. The protocol has been used to identify and determine quantitatively the amounts of three important toxic species in combustion-derived PM: viz., nickel sulfides in residual oil fly ash (ROFA) PM, and Cr(VI) and As(III) species in coal fly ash PM. Although it has been assumed that these toxic species might exist in PM derived from fossil-fuel combustion, the results presented here constitute the first direct determination of them in combustion-derived PM and their potential bioavailability. Detailed information on the presence of these toxic species in PM samples is of significant interest to epidemiological and toxicological studies of the health effects of both source and ambient PM. Additionally, information is obtained on insoluble forms that may be useful for source attribution and on the distribution of phases between size fractions that may be related to formation mechanisms of specific toxic species during combustion.

  3. Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

    SciTech Connect

    Steven Markovich

    2010-06-30

    This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

  4. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect

    Paul A. Erickson

    2004-09-30

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  5. Performance and economics of advanced energy conversion systems for coal and coal-derived fuels

    NASA Technical Reports Server (NTRS)

    Corman, J. C.; Fox, G. R.

    1978-01-01

    The desire to establish an efficient Energy Conversion System to utilize the fossil fuel of the future - coal - has produced many candidate systems. A comparative technical/economic evaluation was performed on the seven most attractive advanced energy conversion systems. The evaluation maintains a cycle-to-cycle consistency in both performance and economic projections. The technical information base can be employed to make program decisions regarding the most attractive concept. A reference steam power plant was analyzed to the same detail and, under the same ground rules, was used as a comparison base. The power plants were all designed to utilize coal or coal-derived fuels and were targeted to meet an environmental standard. The systems evaluated were two advanced steam systems, a potassium topping cycle, a closed cycle helium system, two open cycle gas turbine combined cycles, and an open cycle MHD system.

  6. Characteristic changes in algal organic matter derived from Microcystis aeruginosa in microbial fuel cells.

    PubMed

    Wang, Huan; Lu, Lu; Liu, Dongmei; Cui, Fuyi; Wang, Peng

    2015-11-01

    The objective of this study was to investigate behavior of algal organic matter (AOM) during bioelectrochemical oxidation in microbial fuel cell in terms of compositions and structures. Study revealed that the AOM derived from blue-green algae Microcystis aeruginosa could be degraded more completely (82% COD removal) in microbial fuel cells (MFCs) than by anaerobic fermentation (24% COD removal) in a control reactor without closed-circuit electrode and electricity was produced simultaneously. A variety of techniques were used to characterize the changes in AOM compositions and structures during bioelectrochemical oxidation. The presence of syntrophic interactions between electrochemical active bacteria and fermentative bacteria to degrade large molecular organics into small molecular substances, which could be oxidized by electrode but not by fermentation. The dominant tryptophan protein-like substances, humic acid-like substances and Chlorophyll a in AOM were highly degraded during MFC treatment.

  7. Behavior or Nonmetallic Materials in Shale Oil Derived Jet Fuels and in High Aromatic and High Sulfur Petroleum Fuels

    DTIC Science & Technology

    1978-07-01

    Sealants (Noncuring Type) 30 6. Elastomeric Marmon Clamp Seals 34 7. Elastomeric O-Ring Materials 38 8. Fuel Cell Baffle Materials 42 9. Internal Fuel Cell...fuel bladder materials, bladder repair adhesives, groove sealants, elastomeric o-ring materials, elasto- meric Marmon clamp seals, fuel tank coatings...a. EC-2216 EC-2216 is a room temperature curing epoxy- polyamide struc- tural adhesive manufactured by 3M Company. The initial test results have

  8. Project Startup: Evaluating the Performance of Hydraulic Hybrid Refuse Vehicles

    SciTech Connect

    2015-09-01

    The Fleet Test and Evaluation Team at the National Renewable Energy Laboratory (NREL) is evaluating the in-service performance of 10 next-generation hydraulic hybrid refuse vehicles (HHVs), 8 previous-generation HHVs, and 8 comparable conventional diesel vehicles operated by Miami-Dade County's Public Works and Waste Management Department in southern Florida. The HHVs under study - Autocar E3 refuse trucks equipped with Parker Hannifin's RunWise Advanced Series Hybrid Drive systems - can recover as much as 70 percent of the energy typically lost during braking and reuse it to power the vehicle. NREL's evaluation will assess the performance of this technology in commercial operation and help Miami-Dade County determine the ideal routes for maximizing the fuel-saving potential of its HHVs.

  9. Hot Corrosion of Nickel-Base Alloys in Biomass-Derived Fuel Simulated Atmosphere

    SciTech Connect

    Leyens, C.; Pint, B.A.; Wright, I.G.

    1999-02-28

    Biomass fuels are considered to be a promising renewable source of energy. However, impurities present in the fuel may cause corrosion problems with the materials used in the hot sections of gas turbines and only limited data are available so far. As part of the Advanced Turbine Systems Program initiated by the U.S. Department of Energy, the present study provides initial data on the hot corrosion resistance of different nickel-base alloys against sodium sulfate-induced corrosion as a baseline, and against salt compositions simulating biomass-derived fuel deposits. Single crystal nickel-superalloy Rene N5, a cast NiCrAlY alloy, a NiCoCrAlY alloy representing industrially used overlay compositions, and a model {beta}NiAl+Hf alloy were tested in 1h thermal cycles at 950 C with different salt coatings deposited onto the surfaces. Whereas the NiCoCrAlY alloy exhibited reasonable resistance against pure sodium sulfate deposits, the NiCrAiY alloy and Rene N5 were attacked severely. Although considered to be an ideal alumina former in air and oxygen at higher temperatures, {beta}NiAl+Hf also suffered from rapid corrosion attack at 950 C when coated with sodium sulfate. The higher level of potassium present in biomass fuels compared with conventional fuels was addressed by testing a NiCoCrAlY alloy coated with salts of different K/Na atomic ratios. Starting at zero Na, the corrosion rate increased considerably when sodium was added to potassium sulfate. In an intermediate region the corrosion rate was initially insensitive to the K/Na ratio but accelerated when very Na-rich compositions were deposited. The key driver for corrosion of the NiCoCrAlY alloy was sodium sulfate rather than potassium sulfate, and no simple additive or synergistic effect of combining sodium and potassium was found.

  10. Effects of furan derivatives and phenolic compounds on electricity generation in microbial fuel cells

    NASA Astrophysics Data System (ADS)

    Catal, Tunc; Fan, Yanzhen; Li, Kaichang; Bermek, Hakan; Liu, Hong

    Lignocellulosic biomass is an attractive fuel source for MFCs due to its renewable nature and ready availability. Furan derivatives and phenolic compounds could be potentially formed during the pre-treatment process of lignocellulosic biomass. In this study, voltage generation from these compounds and the effects of these compounds on voltage generation from glucose in air-cathode microbial fuel cells (MFCs) were examined. Except for 5-hydroxymethyl furfural (5-HMF), all the other compounds tested were unable to be utilized directly for electricity production in MFCs in the absence of other electron donors. One furan derivate, 5-HMF and two phenolic compounds, trans-cinnamic acid and 3,5-dimethoxy-4-hydroxy-cinnamic acid did not affect electricity generation from glucose at a concentration up to 10 mM. Four phenolic compounds, including syringaldeyhde, vanillin, trans-4-hydroxy-3-methoxy, and 4-hydroxy cinnamic acids inhibited electricity generation at concentrations above 5 mM. Other compounds, including 2-furaldehyde, benzyl alcohol and acetophenone, inhibited the electricity generation even at concentrations less than 0.2 mM. This study suggests that effective electricity generation from the hydrolysates of lignocellulosic biomass in MFCs may require the employment of the hydrolysis methods with low furan derivatives and phenolic compounds production, or the removal of some strong inhibitors prior to the MFC operation, or the improvement of bacterial tolerance against these compounds through the enrichment of new bacterial cultures or genetic modification of the bacterial strains.

  11. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. Emission testing indicates that the coal derived material has more trace metals related to coal than petroleum, as seen in previous runs. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. The co-coking of the runs with the new coal have begun, with the coke yield similar to previous runs, but the gas yield is lower and the liquid yield is higher. Characterization of the products continues. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking.

  12. The Space Station integrated refuse management system

    NASA Technical Reports Server (NTRS)

    1988-01-01

    The University of Central Florida's design of an Integrated Refuse Management System for the proposed International Space Station is addressed. Four integratable subsystems capable of handling an estimated Orbiter shortfall of nearly 40,000 lbs of refuse produced annually are discussed. The subsystems investigated were: (1) collection and transfer; (2) recycle and reuse; (3) advanced disposal; and (4) propulsion assist in disposal. Emphasis is placed on the recycling or reuse of those materials ultimately providing a source of Space Station refuse. Special consideration is given to various disposal methods capable of completely removing refuse from close proximity of the Space Station. There is evidence that pyrolysis is the optimal solution for disposal of refuse through employment of a Rocket Jettison Vehicle. Additionally, design considerations and specifications of the Refuse Management System are discussed. Optimal and alternate design solutions for each of the four subsystems are summarized. Finally, the system configuration is described and reviewed.

  13. Carbon Nanohorn-Derived Graphene Nanotubes as a Platinum-Free Fuel Cell Cathode.

    PubMed

    Unni, Sreekuttan M; Illathvalappil, Rajith; Bhange, Siddheshwar N; Puthenpediakkal, Hasna; Kurungot, Sreekumar

    2015-11-04

    Current low-temperature fuel cell research mainly focuses on the development of efficient nonprecious electrocatalysts for the reduction of dioxygen molecule due to the reasons like exorbitant cost and scarcity of the current state-of-the-art Pt-based catalysts. As a potential alternative to such costly electrocatalysts, we report here the preparation of an efficient graphene nanotube based oxygen reduction electrocatalyst which has been derived from single walled nanohorns, comprising a thin layer of graphene nanotubes and encapsulated iron oxide nanoparticles (FeGNT). FeGNT shows a surface area of 750 m(2)/g, which is the highest ever reported among the metal encapsulated nanotubes. Moreover, the graphene protected iron oxide nanoparticles assist the system to attain efficient distribution of Fe-Nx and quaternary nitrogen based active reaction centers, which provides better activity and stability toward the oxygen reduction reaction (ORR) in acidic as well as alkaline conditions. Single cell performance of a proton exchange membrane fuel cell by using FeGNT as the cathode catalyst delivered a maximum power density of 200 mW cm(-2) with Nafion as the proton exchange membrane at 60 °C. The facile synthesis strategy with iron oxide encapsulated graphitic carbon morphology opens up a new horizon of hope toward developing Pt-free fuel cells and metal-air batteries along with its applicability in other energy conversion and storage devices.

  14. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect

    Paul A. Erickson

    2004-04-01

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the first such report that will be submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1--December 31, 2003. This quarter saw progress in three areas. These areas are: (1) Evaluations of coal based methanol and the fuel cell grade baseline fuel, (2) Design and set up of the autothermal reactor, as well as (3) Set up and data collection of baseline performance using the steam reformer. All of the projects are proceeding on schedule. During this quarter one conference paper was written that will be presented at the ASME Power 2004 conference in March 2004, which outlines the research direction and basis for looking at the coal to hydrogen pathway.

  15. Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose

    PubMed Central

    Sheng, Xueru; Li, Ning; Li, Guangyi; Wang, Wentao; Yang, Jinfan; Cong, Yu; Wang, Aiqin; Wang, Xiaodong; Zhang, Tao

    2015-01-01

    For the first time, renewable high density aviation fuels were synthesized at high overall yield (95.6%) by the Guerbet reaction of cyclopentanol which can be derived from lignocellulose, followed by the hydrodeoxygenation (HDO). The solvent-free Guerbet reaction of cyclopentanol was carried out under the co-catalysis of solid bases and Raney metals. Among the investigated catalyst systems, the combinations of magnesium-aluminium hydrotalcite (MgAl-HT) and Raney Ni (or Raney Co) exhibited the best performances. Over them, high carbon yield (96.7%) of C10 and C15 oxygenates was achieved. The Guerbet reaction products were further hydrodeoxygenated to bi(cyclopentane) and tri(cyclopentane) over a series of Ni catalysts. These alkanes have high densities (0.86 g mL−1 and 0.91 g mL−1) and can be used as high density aviation fuels or additives to bio-jet fuel. Among the investigated HDO catalysts, the 35 wt.% Ni-SiO2-DP prepared by deposition-precipitation method exhibited the highest activity. PMID:25826744

  16. Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose.

    PubMed

    Sheng, Xueru; Li, Ning; Li, Guangyi; Wang, Wentao; Yang, Jinfan; Cong, Yu; Wang, Aiqin; Wang, Xiaodong; Zhang, Tao

    2015-03-31

    For the first time, renewable high density aviation fuels were synthesized at high overall yield (95.6%) by the Guerbet reaction of cyclopentanol which can be derived from lignocellulose, followed by the hydrodeoxygenation (HDO). The solvent-free Guerbet reaction of cyclopentanol was carried out under the co-catalysis of solid bases and Raney metals. Among the investigated catalyst systems, the combinations of magnesium-aluminium hydrotalcite (MgAl-HT) and Raney Ni (or Raney Co) exhibited the best performances. Over them, high carbon yield (96.7%) of C10 and C15 oxygenates was achieved. The Guerbet reaction products were further hydrodeoxygenated to bi(cyclopentane) and tri(cyclopentane) over a series of Ni catalysts. These alkanes have high densities (0.86 g mL(-1) and 0.91 g mL(-1)) and can be used as high density aviation fuels or additives to bio-jet fuel. Among the investigated HDO catalysts, the 35 wt.% Ni-SiO2-DP prepared by deposition-precipitation method exhibited the highest activity.

  17. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect

    Paul A. Erickson

    2005-06-30

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the seventh report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 31, 2005. This quarter saw progress in these areas. These areas are: (1) Steam reformer transient response, (2) Heat transfer enhancement, (3) Catalyst degradation, (4) Catalyst degradation with bluff bodies, and (5) Autothermal reforming of coal-derived methanol. All of the projects are proceeding on or slightly ahead of schedule.

  18. 36 CFR 2.14 - Sanitation and refuse.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 36 Parks, Forests, and Public Property 1 2012-07-01 2012-07-01 false Sanitation and refuse. 2.14... RESOURCE PROTECTION, PUBLIC USE AND RECREATION § 2.14 Sanitation and refuse. (a) The following are prohibited: (1) Disposing of refuse in other than refuse receptacles. (2) Using government refuse...

  19. 36 CFR 1002.14 - Sanitation and refuse.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 36 Parks, Forests, and Public Property 3 2012-07-01 2012-07-01 false Sanitation and refuse. 1002... AND RECREATION § 1002.14 Sanitation and refuse. (a) The following are prohibited: (1) Disposing of refuse in other than refuse receptacles. (2) Using government refuse receptacles or other...

  20. 36 CFR 1002.14 - Sanitation and refuse.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 3 2011-07-01 2011-07-01 false Sanitation and refuse. 1002... AND RECREATION § 1002.14 Sanitation and refuse. (a) The following are prohibited: (1) Disposing of refuse in other than refuse receptacles. (2) Using government refuse receptacles or other...

  1. 36 CFR 1002.14 - Sanitation and refuse.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 36 Parks, Forests, and Public Property 3 2014-07-01 2014-07-01 false Sanitation and refuse. 1002... AND RECREATION § 1002.14 Sanitation and refuse. (a) The following are prohibited: (1) Disposing of refuse in other than refuse receptacles. (2) Using government refuse receptacles or other...

  2. 36 CFR 2.14 - Sanitation and refuse.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Sanitation and refuse. 2.14... RESOURCE PROTECTION, PUBLIC USE AND RECREATION § 2.14 Sanitation and refuse. (a) The following are prohibited: (1) Disposing of refuse in other than refuse receptacles. (2) Using government refuse...

  3. 36 CFR 1002.14 - Sanitation and refuse.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 36 Parks, Forests, and Public Property 3 2010-07-01 2010-07-01 false Sanitation and refuse. 1002... AND RECREATION § 1002.14 Sanitation and refuse. (a) The following are prohibited: (1) Disposing of refuse in other than refuse receptacles. (2) Using government refuse receptacles or other...

  4. 36 CFR 2.14 - Sanitation and refuse.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Sanitation and refuse. 2.14... RESOURCE PROTECTION, PUBLIC USE AND RECREATION § 2.14 Sanitation and refuse. (a) The following are prohibited: (1) Disposing of refuse in other than refuse receptacles. (2) Using government refuse...

  5. 36 CFR 2.14 - Sanitation and refuse.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 36 Parks, Forests, and Public Property 1 2014-07-01 2014-07-01 false Sanitation and refuse. 2.14... RESOURCE PROTECTION, PUBLIC USE AND RECREATION § 2.14 Sanitation and refuse. (a) The following are prohibited: (1) Disposing of refuse in other than refuse receptacles. (2) Using government refuse...

  6. 36 CFR 2.14 - Sanitation and refuse.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 1 2013-07-01 2013-07-01 false Sanitation and refuse. 2.14... RESOURCE PROTECTION, PUBLIC USE AND RECREATION § 2.14 Sanitation and refuse. (a) The following are prohibited: (1) Disposing of refuse in other than refuse receptacles. (2) Using government refuse...

  7. Radiocarbon-based assessment of fossil fuel-derived contaminant associations in sediments.

    PubMed

    White, Helen K; Reddy, Christopher M; Eglinton, Timothy I

    2008-08-01

    Hydrophobic organic contaminants (HOCs) are associated with natural organic matter (OM) in the environment via mechanisms such as sorption or chemical binding. The latter interactions are difficult to quantitatively constrain, as HOCs can reside in different OM pools outside of conventional analytical windows. Here, we exploited natural abundance variations in radiocarbon (14C) to trace various fossil fuel-derived HOCs (14C-free) within chemically defined fractions of contemporary OM (modern 14C content) in 13 samples including marine and freshwater sediments and one dust and one soil sample. Samples were sequentially treated by solvent extraction followed by saponification. Radiocarbon analysis of the bulk sample and resulting residues was then performed. Fossil fuel-derived HOCs released by these treatments were quantified from an isotope mass balance approach as well as by gas chromatography-mass spectrometry. For the majority of samples (n = 13), 98-100% of the total HOC pool was solvent extractable. Nonextracted HOCs are only significant (29% of total HOC pool)in one sample containing p,p-2,2-bis(chlorophenyl)-1,1,1-trichloroethane and its metabolites. The infrequency of significant incorporation of HOCs into nonextracted OM residues suggests that most HOCs are mobile and bioavailable in the environment and, as such, have a greater potential to exert adverse effects.

  8. Effective Intervention for School Refusal Behaviour

    ERIC Educational Resources Information Center

    Nuttall, Clare; Woods, Kevin

    2013-01-01

    Evaluation of successful professional intervention for two case studies of female adolescents' school refusal behaviour is presented. Data gathered from the young person, professionals, and parents in each case are synthesised to propose a multi-level, ecologically situated model of intervention for school refusal behaviour. The proposed model…

  9. The space station integrated refuse management system

    NASA Technical Reports Server (NTRS)

    Anderson, Loren A.

    1988-01-01

    The design and development of an Integrated Refuse Management System for the proposed International Space Station was performed. The primary goal was to make use of any existing potential energy or material properties that refuse may possess. The secondary goal was based on the complete removal or disposal of those products that could not, in any way, benefit astronauts' needs aboard the Space Station. The design of a continuous living and experimental habitat in space has spawned the need for a highly efficient and effective refuse management system capable of managing nearly forty-thousand pounds of refuse annually. To satisfy this need, the following four integrable systems were researched and developed: collection and transfer; recycle and reuse; advance disposal; and propulsion assist in disposal. The design of a Space Station subsystem capable of collecting and transporting refuse from its generation site to its disposal and/or recycling site was accomplished. Several methods of recycling or reusing refuse in the space environment were researched. The optimal solution was determined to be the method of pyrolysis. The objective of removing refuse from the Space Station environment, subsequent to recycling, was fulfilled with the design of a jettison vehicle. A number of jettison vehicle launch scenarios were analyzed. Selection of a proper disposal site and the development of a system to propel the vehicle to that site were completed. Reentry into the earth atmosphere for the purpose of refuse incineration was determined to be the most attractive solution.

  10. Refuse pile design considerations. [Coal preparation plant

    SciTech Connect

    Sawarynski, T.J.

    1981-12-01

    This paper discusses current trends of coarse and fine coal refuse disposal techniques. Emphasis is on site-specific engineering to tailor safe, cost effective, and environmentally sound refuse disposal systems to the needs of a particular mine. Geotechnical design considerations are discussed in relation to system performance, regulatory acceptance, and industry use. 2 refs.

  11. The Functional Assessment of School Refusal Behavior

    ERIC Educational Resources Information Center

    Kearney, Christopher A.; Lemos, Amie; Silverman, Jenna

    2004-01-01

    School refusal behavior refers to child-motivated refusal to attend school and/or difficulty attending classes for an entire day (Kearney & Silverman, 1996). As such, the term represents an umbrella construct for many historical ones that have been used to describe youths with problematic absenteeism, including truancy, psychoneurotic truancy,…

  12. Development of OTM Syngas Process and Testing of Syngas Derived Ultra-clean Fuels in Diesel Engines and Fuel Cells

    SciTech Connect

    E.T. Robinson; James P. Meagher; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Siv Aasland; Charles Besecker; Jack Chen Bart A. van Hassel; Olga Polevaya; Rafey Khan; Piyush Pilaniwalla

    2002-12-31

    This topical report summarizes work accomplished for the Program from November 1, 2001 to December 31, 2002 in the following task areas: Task 1: Materials Development; Task 2: Composite Development; Task 4: Reactor Design and Process Optimization; Task 8: Fuels and Engine Testing; 8.1 International Diesel Engine Program; 8.2 Nuvera Fuel Cell Program; and Task 10: Program Management. Major progress has been made towards developing high temperature, high performance, robust, oxygen transport elements. In addition, a novel reactor design has been proposed that co-produces hydrogen, lowers cost and improves system operability. Fuel and engine testing is progressing well, but was delayed somewhat due to the hiatus in program funding in 2002. The Nuvera fuel cell portion of the program was completed on schedule and delivered promising results regarding low emission fuels for transportation fuel cells. The evaluation of ultra-clean diesel fuels continues in single cylinder (SCTE) and multiple cylinder (MCTE) test rigs at International Truck and Engine. FT diesel and a BP oxygenate showed significant emissions reductions in comparison to baseline petroleum diesel fuels. Overall through the end of 2002 the program remains under budget, but behind schedule in some areas.

  13. Novel polybenzimidazole derivatives for high temperature polymer electrolyte membrane fuel cell applications

    NASA Astrophysics Data System (ADS)

    Xiao, Lixiang

    Recent advances have made polymer electrolyte membrane fuel cells (PEMFCs) a leading alternative to internal combustion engines for both stationary and transportation applications. In particular, high temperature polymer electrolyte membranes operational above 120°C without humidification offer many advantages including fast electrode kinetics, high tolerance to fuel impurities and simple thermal and water management systems. A series of polybenzimidazole (PBI) derivatives including pyridine-based PBI (PPBI) and sulfonated PBI (SPBI) homopolymers and copolymers have been synthesized using polyphosphoric acid (PPA) as both solvent and polycondensation agent. High molecular weight PBI derivative polymers were obtained with well controlled backbone structures in terms of pyridine ring content, polymer backbone rigidity and degree of sulfonation. A novel process, termed the PPA process, has been developed to prepare phosphoric acid (PA) doped PBI membranes by direct-casting of the PPA polymerization solution without isolation or re-dissolution of the polymers. The subsequent hydrolysis of PPA to PA by moisture absorbed from the atmosphere usually induced a transition from the solution-like state to a gel-like state and produced PA doped PBI membranes with a desirable suite of physiochemical properties characterized by the PA doping levels, mechanical properties and proton conductivities. The effects of the polymer backbone structure on the polymer characteristics and membrane properties, i.e., the structure-property relationships of the PBI derivative polymers have been studied. The incorporation of additional basic nitrogen containing pyridine rings and sulfonic acid groups enhanced the polymer solubility in acid and dipolar solvents while retaining the inherently high thermal stability of the PBI heteroaromatic backbone. In particular, the degradation of the SPBI polymers with reasonable high molecular weights commenced above 450°C, notably higher than other

  14. Renewable liquid fuels from catalytic reforming of biomass-derived oxygenated hydrocarbons

    NASA Astrophysics Data System (ADS)

    Barrett, Christopher J.

    Diminishing fossil fuel reserves and growing concerns about global warming require the development of sustainable sources of energy. Fuels for use in the transportation sector must have specific physical properties that allow for efficient distribution, storage, and combustion; these requirements are currently fulfilled by petroleum-derived liquid fuels. The focus of this work has been the development of two new biofuels that have the potential to become widely used transportation fuels from carbohydrate intermediates. Our first biofuel has cetane numbers ranging from 63 to 97 and is comprised of C7 to C15 straight chain alkanes. These alkanes can be blended with diesel like fuels or with P-series biofuel. Production involves a solid base catalyzed aldol condensation with mixed Mg-Al-oxide between furfural or 5-hydroxymethylfurfural (HMF) and acetone, followed by hydrogenation over Pd/Al2O3, and finally hydrogenation/dehydration over Pt/SiO2-Al2O3. Water was the solvent for all process steps, except for the hydrogenation/dehydration stage where hexadecane was co-fed to spontaneously separate out all alkane products and eliminate the need for energy intensive distillation. A later optimization identified Pd/MgO-ZrO2 as a hydrothermally stable bifunctional catalyst to replace Pd/Al2O3 and the hydrothermally unstable Mg-Al-oxide catalysts along with optimizing process parameters, such as temperature and molar ratios of reactants to maximize yields to heavier alkanes. Our second biofuel involved creating an improved process to produce HMF through the acid-catalyzed dehydration of fructose in a biphasic reactor. Additionally, we developed a technique to further convert HMF into 2,5-dimethylfuran (DMF) by hydrogenolysis of C-O bonds over a copper-ruthenium catalyst. DMF has many properties that make it a superior blending agent to ethanol: it has a high research octane number at 119, a 40% higher energy density than ethanol, 20 K higher boiling point, and is insoluble in

  15. Caregivers Who Refuse Preventive Care for Their Children: The Relationship Between Immunization and Topical Fluoride Refusal

    PubMed Central

    2014-01-01

    Objectives. The aim of this study was to examine caregivers’ refusal of preventive medical and dental care for children. Methods. Prevalence rates of topical fluoride refusal based on dental records and caregiver self-reports were estimated for children treated in 3 dental clinics in Washington State. A 60-item survey was administered to 1024 caregivers to evaluate the association between immunization and topical fluoride refusal. Modified Poisson regression models were used to estimate prevalence rate ratios (PRRs). Results. The prevalence of topical fluoride refusal was 4.9% according to dental records and 12.7% according to caregiver self-reports. The rate of immunization refusal was 27.4%. In the regression models, immunization refusal was significantly associated with topical fluoride refusal (dental record PRR = 1.61; 95% confidence interval [CI] = 1.32, 1.96; P < .001; caregiver self-report PRR = 6.20; 95% CI = 3.21, 11.98; P < .001). Caregivers younger than 35 years were significantly more likely than older caregivers to refuse both immunizations and topical fluoride (P < .05). Conclusions. Caregiver refusal of immunizations is associated with topical fluoride refusal. Future research should identify the behavioral and social factors related to caregiver refusal of preventive care with the goal of developing multidisciplinary strategies to help caregivers make optimal preventive care decisions for children. PMID:24832428

  16. DESIGNING AN OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION

    SciTech Connect

    K. Payette; D. Tillman

    2001-04-01

    During the period January 1, 2001-March 31, 2001, Allegheny Energy Supply Co., LLC (Allegheny) finalized the engineering of the Willow Island cofiring project, completed the fuel characterizations for both the Willow Island and Albright Generating Station projects, and initiated construction of both projects. Allegheny and its contractor, Foster Wheeler, selected appropriate fuel blends and issued purchase orders for all processing and mechanical equipment to be installed at both sites. This report summarizes the activities associated with the Designer Opportunity Fuel program, and demonstrations at Willow Island and Albright Generating Stations. The third quarter of the project involved completing the detailed designs for the Willow Island Designer Fuel project. It also included complete characterization of the coal and biomass fuels being burned, focusing upon the following characteristics: proximate and ultimate analysis; higher heating value; carbon 13 nuclear magnetic resonance testing for aromaticity, number of aromatic carbons per cluster, and the structural characteristics of oxygen in the fuel; drop tube reactor testing for high temperature devolatilization kinetics and generation of fuel chars; thermogravimetric analyses (TGA) for char oxidation kinetics; and related testing. The construction at both sites commenced during this quarter, and was largely completed at the Albright Generating Station site.

  17. Life cycle assessment of switchgrass- and corn stover-derived ethanol-fueled automobiles.

    PubMed

    Spatari, Sabrina; Zhang, Yimin; MacLean, Heather L

    2005-12-15

    Utilizing domestically produced cellulose-derived ethanol for the light-duty vehicle fleet can potentially improve the environmental performance and sustainability of the transport and energy sectors of the economy. A life cycle assessment model was developed to examine environmental implications of the production and use of ethanol in automobiles in Ontario, Canada. The results were compared to those of low-sulfur reformulated gasoline (RFG) in a functionally equivalent automobile. Two time frames were evaluated, one near-term (2010), which examines converting a dedicated energy crop (switchgrass) and an agricultural residue (corn stover) to ethanol; and one midterm (2020), which assumes technological improvements in the switchgrass-derived ethanol life cycle. Near-term results show that, compared to a RFG automobile, life cycle greenhouse gas (GHG) emissions are 57% lower for an E85-fueled automobile derived from switchgrass and 65% lower for ethanol from corn stover, on a grams of CO2 equivalent per kilometer basis. Corn stover ethanol exhibits slightly lower life cycle GHG emissions, primarily due to sharing emissions with grain production. Through projected improvements in crop and ethanol yields, results for the mid-term scenario show that GHG emissions could be 25-35% lower than those in 2010 and that, even with anticipated improvements in RFG automobiles, E85 automobiles could still achieve up to 70% lower GHG emissions across the life cycle.

  18. 9 CFR 93.806 - Animals refused entry.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... FOR MEANS OF CONVEYANCE AND SHIPPING CONTAINERS Elephants, Hippopotami, Rhinoceroses, and Tapirs § 93.806 Animals refused entry. Any elephant, hippopotamus, rhinoceros, or tapir refused entry into...

  19. 9 CFR 93.806 - Animals refused entry.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... FOR MEANS OF CONVEYANCE AND SHIPPING CONTAINERS Elephants, Hippopotami, Rhinoceroses, and Tapirs § 93.806 Animals refused entry. Any elephant, hippopotamus, rhinoceros, or tapir refused entry into...

  20. 9 CFR 93.806 - Animals refused entry.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... FOR MEANS OF CONVEYANCE AND SHIPPING CONTAINERS Elephants, Hippopotami, Rhinoceroses, and Tapirs § 93.806 Animals refused entry. Any elephant, hippopotamus, rhinoceros, or tapir refused entry into...

  1. 9 CFR 93.806 - Animals refused entry.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... FOR MEANS OF CONVEYANCE AND SHIPPING CONTAINERS Elephants, Hippopotami, Rhinoceroses, and Tapirs § 93.806 Animals refused entry. Any elephant, hippopotamus, rhinoceros, or tapir refused entry into...

  2. 9 CFR 93.806 - Animals refused entry.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... FOR MEANS OF CONVEYANCE AND SHIPPING CONTAINERS Elephants, Hippopotami, Rhinoceroses, and Tapirs § 93.806 Animals refused entry. Any elephant, hippopotamus, rhinoceros, or tapir refused entry into...

  3. Biological Production of a Hydrocarbon Fuel Intermediate Polyhydroxybutyrate (Phb) from a Process Relevant Lignocellulosic Derived Sugar

    SciTech Connect

    Wang, Wei; Mohagheghi, Ali; Mittal, Ashutosh; Pilath, Heidi; Johnson, David K.

    2015-03-22

    PHAs are synthesized by many microorganisms to serve as intracellular carbon storage molecules. In some bacterial strains, PHB can account for up to 80% of cell mass. In addition to its application in the packaging sector, PHB also has great potential as an intermediate in the production of hydrocarbon fuels. PHB can be thermally depolymerized and decarboxylated to propene which can be upgraded to hydrocarbon fuels via commercial oligomerization technologies. In recent years a great effort has been made in bacterial production of PHB, yet the production cost of the polymer is still much higher than conventional petrochemical plastics. The high cost of PHB is because the cost of the substrates can account for as much as half of the total product cost in large scale fermentation. Thus searching for cheaper and better substrates is very necessary for PHB production. In this study, we demonstrate production of PHB by Cupriavidus necator from a process relevant lignocellulosic derived sugar stream, i.e., saccharified hydrolysate slurry from pretreated corn stover. Good cell growth was observed on slurry saccharified with advanced enzymes and 40~60% of PHB was accumulated in the cells. The mechanism of inhibition in the toxic hydrolysate generated by pretreatment and saccharification of biomass, will be discussed.

  4. Nonactivated and activated biochar derived from bananas as alternative cathode catalyst in microbial fuel cells.

    PubMed

    Yuan, Haoran; Deng, Lifang; Qi, Yujie; Kobayashi, Noriyuki; Tang, Jiahuan

    2014-01-01

    Nonactivated and activated biochars have been successfully prepared by bananas at different thermotreatment temperatures. The activated biochar generated at 900°C (Biochar-act900) exhibited improved oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) performances in alkaline media, in terms of the onset potential and generated current density. Rotating disk electron result shows that the average of 2.65 electrons per oxygen molecule was transferred during ORR of Biochar-act900. The highest power density of 528.2 mW/m(2) and the maximum stable voltage of 0.47 V were obtained by employing Biochar-act900 as cathode catalyst, which is comparable to the Pt/C cathode. Owning to these advantages, it is expected that the banana-derived biochar cathode can find application in microbial fuel cell systems.

  5. Patients' refusal to participate in clinical research.

    PubMed

    van den Berg, L; Lobatto, R M; Zuurmond, W W; de Lange, J J; Wagemans, M F; Bezemer, P D

    1997-05-01

    The number of protocol-eligible patients, refusing to participate in a clinical trial is often not mentioned. The aim of this study is to report the number of refusers and to evaluate the reasons for not participating in a clinical study concerning post-operative pain relief and to assess the potential influence on the final study results. Patients refusing to participate in the study were recorded and evaluated for reasons of refusal. The post-operative pain relief techniques applied in this trial are commonly used, but nevertheless the refusal rate was higher than expected. When it was mentioned that an epidural technique was a part of the trial, 16.7% of the total protocol-eligible group refused. The responses of those offered an epidural could be divided into two groups: the adamant pros and cons to this technique. It can be concluded that in order to be able to judge the validity of results and thus for good clinical practice, the number of patients refusing to participate in a clinical trial and their reasons, should be mentioned in all publications.

  6. The Legal Ethical Backbone of Conscientious Refusal.

    PubMed

    Munthe, Christian; Nielsen, Morten Ebbe Juul

    2017-01-01

    This article analyzes the idea of a legal right to conscientious refusal for healthcare professionals from a basic legal ethical standpoint, using refusal to perform tasks related to legal abortion (in cases of voluntary employment) as a case in point. The idea of a legal right to conscientious refusal is distinguished from ideas regarding moral rights or reasons related to conscientious refusal, and none of the latter are found to support the notion of a legal right. Reasons for allowing some sort of room for conscientious refusal for healthcare professionals based on the importance of cultural identity and the fostering of a critical atmosphere might provide some support, if no countervailing factors apply. One such factor is that a legal right to healthcare professionals' conscientious refusal must comply with basic legal ethical tenets regarding the rule of law and equal treatment, and this requirement is found to create serious problems for those wishing to defend the idea under consideration. We conclude that the notion of a legal right to conscientious refusal for any profession is either fundamentally incompatible with elementary legal ethical requirements, or implausible because it undermines the functioning of a related professional sector (healthcare) or even of society as a whole.

  7. Electrocatalytic processing of renewable biomass-derived compounds for production of chemicals, fuels and electricity

    NASA Astrophysics Data System (ADS)

    Xin, Le

    The dual problems of sustaining the fast growth of human society and preserving the environment for future generations urge us to shift our focus from exploiting fossil oils to researching and developing more affordable, reliable and clean energy sources. Human beings had a long history that depended on meeting our energy demands with plant biomass, and the modern biorefinery technologies realize the effective conversion of biomass to production of transportation fuels, bulk and fine chemicals so to alleviate our reliance on fossil fuel resources of declining supply. With the aim of replacing as much non-renewable carbon from fossil oils with renewable carbon from biomass as possible, innovative R&D activities must strive to enhance the current biorefinery process and secure our energy future. Much of my Ph.D. research effort is centered on the study of electrocatalytic conversion of biomass-derived compounds to produce value-added chemicals, biofuels and electrical energy on model electrocatalysts in AEM/PEM-based continuous flow electrolysis cell and fuel cell reactors. High electricity generation performance was obtained when glycerol or crude glycerol was employed as fuels in AEMFCs. The study on selective electrocatalytic oxidation of glycerol shows an electrode potential-regulated product distribution where tartronate and mesoxalate can be selectively produced with electrode potential switch. This finding then led to the development of AEMFCs with selective production of valuable tartronate or mesoxalate with high selectivity and yield and cogeneration of electricity. Reaction mechanisms of electrocatalytic oxidation of ethylene glycol and 1,2-propanediol were further elucidated by means of an on-line sample collection technique and DFT modeling. Besides electro-oxidation of biorenewable alcohols to chemicals and electricity, electrocatalytic reduction of keto acids (e.g. levulinic acid) was also studied for upgrading biomass-based feedstock to biofuels while

  8. Legal briefing: conscience clauses and conscientious refusal.

    PubMed

    Pope, Thaddeus Mason

    2010-01-01

    This issue's "Legal Briefing" column covers legal developments pertaining to conscience clauses and conscientious refusal. Not only has this topic been the subject of recent articles in this journal, but it has also been the subject of numerous public and professional discussions. Over the past several months, conscientious refusal disputes have had an unusually high profile not only in courthouses, but also in legislative and regulatory halls across the United States. Healthcare providers' own moral beliefs have been obstructing and are expected to increasingly obstruct patients' access to medical services. For example, some providers, on ethical or moral grounds, have denied: (1) sterilization procedures to pregnant patients, (2) pain medications in end-of-life situations, and (3) information about emergency contraception to rape victims. On the other hand, many healthcare providers have been forced to provide medical treatment that is inconsistent with their moral beliefs. There are two fundamental types of conscientious objection laws. First, there are laws that permit healthcare workers to refuse providing - on ethical, moral, or religious grounds healthcare services that they might otherwise have a legal or employer-mandated obligation to provide. Second, there are laws directed at forcing healthcare workers to provide services to which they might have ethical, moral, or religious objections. Both types of laws are rarely comprehensive, but instead target: (1) certain types of healthcare providers, (2) specific categories of healthcare services, (3) specific patient circumstances, and (4) certain conditions under which a right or obligation is triggered. For the sake of clarity, I have grouped recent legal developments concerning conscientious refusal into eight categories: 1. Abortion: right to refuse 2. Abortion: duty to provide 3. Contraception: right to refuse 4. Contraception: duty to provide 5. Sterilization: right to refuse 6. Fertility, HIV, vaccines

  9. Production of Jet Fuels from Coal-Derived Liquids. Volume 13. Evaluation of Storage and Thermal Stability of Jet Fuels Derived from Coal Liquids

    DTIC Science & Technology

    1990-05-01

    at the Great Plains Gasification Plant ( GPGP ) in Beulah, North Dakota. Funding was provided to the Department of Energy. (DOE), Pittsburgh Energy...Petroleum and Energy Research-(NIPER)>of the lIT Research Institute to study the storage and thermal stability of a JP-8 fuel produced from the GPGP liquid by...fuel produced from the GPGP liquid by-product streams. DOE/PETC was funded through Military Interdepartmental Purchase Request (MIPR) FY1455-86- N0657

  10. Alternative Fuels

    EPA Pesticide Factsheets

    Alternative fuels include gaseous fuels such as hydrogen, natural gas, and propane; alcohols such as ethanol, methanol, and butanol; vegetable and waste-derived oils; and electricity. Overview of alternative fuels is here.

  11. Pervasive refusal syndrome - A clinical challenge.

    PubMed

    Kaku, Sowmyashree Mayur; Kommu, John Vijay Sagar; Seshadri, Shekhar; Girimaji, Satish Chandra; Srinath, Shoba

    2015-10-01

    Pervasive refusal syndrome is described as a condition comprising varying degrees of refusal across several domains; social withdrawal; resistance to treatment and is potentially life threatening with no detectable organic cause. Female predominance, refusal to eat with low weight, body image distortion, depressive features, premorbid personality issues similar to eating disorders have been noted, with 67% cases having complete recovery. In this paper, we describe what is probably the first case reported from India, of a child, who presented with neuropsychiatric symptoms, and treated with electroconvulsive therapy along with medications, but, sadly had a fatal outcome.

  12. Molecularly Engineered Azobenzene Derivatives for High Energy Density Solid-State Solar Thermal Fuels.

    PubMed

    Cho, Eugene N; Zhitomirsky, David; Han, Grace G D; Liu, Yun; Grossman, Jeffrey C

    2017-03-15

    Solar thermal fuels (STFs) harvest and store solar energy in a closed cycle system through conformational change of molecules and can release the energy in the form of heat on demand. With the aim of developing tunable and optimized STFs for solid-state applications, we designed three azobenzene derivatives functionalized with bulky aromatic groups (phenyl, biphenyl, and tert-butyl phenyl groups). In contrast to pristine azobenzene, which crystallizes and makes nonuniform films, the bulky azobenzene derivatives formed uniform amorphous films that can be charged and discharged with light and heat for many cycles. Thermal stability of the films, a critical metric for thermally triggerable STFs, was greatly increased by the bulky functionalization (up to 180 °C), and we were able to achieve record high energy density of 135 J/g for solid-state STFs, over a 30% improvement compared to previous solid-state reports. Furthermore, the chargeability in the solid state was improved, up to 80% charged from 40% charged in previous solid-state reports. Our results point toward molecular engineering as an effective method to increase energy storage in STFs, improve chargeability, and improve the thermal stability of the thin film.

  13. Advection of surface-derived organic carbon fuels microbial reduction in Bangladesh groundwater

    NASA Astrophysics Data System (ADS)

    Mailloux, Brian J.; Trembath-Reichert, Elizabeth; Cheung, Jennifer; Watson, Marlena; Stute, Martin; Freyer, Greg A.; Ferguson, Andrew S.; Matin Ahmed, Kazi; Jahangir Alam, Md.; Buchholz, Bruce A.; Thomas, James; Layton, Alice C.; Zheng, Yan; Bostick, Benjamin C.; van Geen, Alexander

    2013-04-01

    Chronic exposure to arsenic (As) by drinking shallow groundwater causes widespread disease in Bangladesh and neighboring countries. The release of As naturally present in sediment to groundwater has been linked to the reductive dissolution of iron oxides coupled to the microbial respiration of organic carbon (OC). The source of OC driving this microbial reduction-carbon deposited with the sediments or exogenous carbon transported by groundwater-is still debated despite its importance in regulating aquifer redox status and groundwater As levels. Here, we used the radiocarbon (14C) signature of microbial DNA isolated from groundwater samples to determine the relative importance of surface and sediment-derived OC. Three DNA samples collected from the shallow, high-As aquifer and one sample from the underlying, low-As aquifer were consistently younger than the total sediment carbon, by as much as several thousand years. This difference and the dominance of heterotrophic microorganisms implies that younger, surface-derived OC is advected within the aquifer, albeit more slowly than groundwater, and represents a critical pool of OC for aquifer microbial communities. The vertical profile shows that downward transport of dissolved OC is occurring on anthropogenic timescales, but bomb 14C-labeled dissolved OC has not yet accumulated in DNA and is not fueling reduction. These results indicate that advected OC controls aquifer redox status and confirm that As release is a natural process that predates human perturbations to groundwater flow. Anthropogenic perturbations, however, could affect groundwater redox conditions and As levels in the future.

  14. High performance liquid chromatographic hydrocarbon group-type analyses of mid-distillates employing fuel-derived fractions as standards

    NASA Technical Reports Server (NTRS)

    Seng, G. T.; Otterson, D. A.

    1983-01-01

    Two high performance liquid chromatographic (HPLC) methods have been developed for the determination of saturates, olefins and aromatics in petroleum and shale derived mid-distillate fuels. In one method the fuel to be analyzed is reacted with sulfuric acid, to remove a substantial portion of the aromatics, which provides a reacted fuel fraction for use in group type quantitation. The second involves the removal of a substantial portion of the saturates fraction from the HPLC system to permit the determination of olefin concentrations as low as 0.3 volume percent, and to improve the accuracy and precision of olefins determinations. Each method was evaluated using model compound mixtures and real fuel samples.

  15. Effect of fuel properties on performance of a single aircraft turbojet combustor. [from coal and oil-shale derived syncrudes

    NASA Technical Reports Server (NTRS)

    Butze, H. F.; Ehlers, R. C.

    1975-01-01

    The performance of a single-can JT8D combustor was investigated with a number of fuels exhibiting wide variations in chemical composition and volatility. Performance parameters investigated were combustion efficiency, emissions of CO, unburned hydrocarbons and NOx, as well as liner temperatures and smoke. At the simulated idle condition no significant differences in performance were observed. At cruise, liner temperatures and smoke increased sharply with decreasing hydrogen content of the fuel. No significant differences were observed in the performance of an oil-shale derived JP-5 and a petroleum-based Jet A fuel except for emissions of NOx which were higher with the oil-shale JP-5. The difference is attributed to the higher concentration of fuel-bound nitrogen in the oil-shale JP-5.

  16. Life-cycle assessment of energy use and greenhouse gas emissions of soybean-derived biodiesel and renewable fuels.

    PubMed

    Huo, Hong; Wang, Michael; Bloyd, Cary; Putsche, Vicky

    2009-02-01

    In this study, we used Argonne National Laboratory's Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model to assess the life-cycle energy and greenhouse gas (GHG) emission impacts of four soybean-derived fuels: biodiesel fuel produced via transesterification, two renewable diesel fuels (I and II) produced from different hydrogenation processes, and renewable gasoline produced from catalytic cracking. Five approaches were employed to allocate the coproducts: a displacement approach; two allocation approaches, one based on the energy value and the other based on the market value; and two hybrid approaches that integrated the displacement and allocation methods. The relative rankings of soybean-based fuels in terms of energy and environmental impacts were different under the different approaches, and the reasons were analyzed. Results from the five allocation approaches showed that although the production and combustion of soybean-based fuels might increase total energy use, they could have significant benefits in reducing fossil energy use (>52%), petroleum use (>88%), and GHG emissions (>57%) relative to petroleum fuels. This study emphasized the importance of the methods used to deal with coproduct issues and provided a comprehensive solution for conducting a life-cycle assessment of fuel pathways with multiple coproducts.

  17. Life-Cycle Assessment of Energy Use and Greenhouse Gas Emissions of Soybean-Derived Biodiesel and Renewable Fuels

    SciTech Connect

    Huo, H.; Wang, M.; Bloyd, C.; Putsche, V.

    2009-01-01

    In this study, we used Argonne National Laboratory's Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model to assess the life-cycle energy and greenhouse gas (GHG) emission impacts of four soybean-derived fuels: biodiesel fuel produced via transesterification, two renewable diesel fuels (I and II) produced from different hydrogenation processes, and renewable gasoline produced from catalytic cracking. Five approaches were employed to allocate the coproducts: a displacement approach; two allocation approaches, one based on the energy value and the other based on the market value; and two hybrid approaches that integrated the displacement and allocation methods. The relative rankings of soybean-based fuels in terms of energy and environmental impacts were different under the different approaches, and the reasons were analyzed. Results from the five allocation approaches showed that although the production and combustion of soybean-based fuels might increase total energy use, they could have significant benefits in reducing fossil energy use (>52%), petroleum use (>88%), and GHG emissions (>57%) relative to petroleum fuels. This study emphasized the importance of the methods used to deal with coproduct issues and provided a comprehensive solution for conducting a life-cycle assessment of fuel pathways with multiple coproducts.

  18. Energy and emission benefits of alternative transportation liquid fuels derived from switchgrass: a fuel life cycle assessment.

    PubMed

    Wu, May; Wu, Ye; Wang, Michael

    2006-01-01

    We conducted a mobility chains, or well-to-wheels (WTW), analysis to assess the energy and emission benefits of cellulosic biomass for the U.S. transportation sector in the years 2015-2030. We estimated the life-cycle energy consumption and emissions associated with biofuel production and use in light-duty vehicle (LDV) technologies by using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model. Analysis of biofuel production was based on ASPEN Plus model simulation of an advanced fermentation process to produce fuel ethanol/protein, a thermochemical process to produce Fischer-Tropsch diesel (FTD) and dimethyl ether (DME), and a combined heat and power plant to co-produce steam and electricity. Our study revealed that cellulosic biofuels as E85 (mixture of 85% ethanol and 15% gasoline by volume), FTD, and DME offer substantial savings in petroleum (66-93%) and fossil energy (65-88%) consumption on a per-mile basis. Decreased fossil fuel use translates to 82-87% reductions in greenhouse gas emissions across all unblended cellulosic biofuels. In urban areas, our study shows net reductions for almost all criteria pollutants, with the exception of carbon monoxide (unchanged), for each of the biofuel production option examined. Conventional and hybrid electric vehicles, when fueled with E85, could reduce total sulfur oxide (SO(x)) emissions to 39-43% of those generated by vehicles fueled with gasoline. By using bio-FTD and bio-DME in place of diesel, SO(x) emissions are reduced to 46-58% of those generated by diesel-fueled vehicles. Six different fuel production options were compared. This study strongly suggests that integrated heat and power co-generation by means of gas turbine combined cycle is a crucial factor in the energy savings and emission reductions.

  19. Dependence of Fuel Properties During Blending of Iso-Paraffinic Kerosene and Petroleum-Derived Jet Fuel

    DTIC Science & Technology

    2008-11-01

    such as algae , grasses and organic wastes are of interest due to the potential reduction in associated carbon footprint when using these feedstocks...years storage. The ―failure‖ level is based upon the previous JP-5 peroxide specification limit of 1 mequiv/kg (~800 M, assuming fuel S.G. = 0.800...found in MIL-T-5624P. The peroxide specification limit was eliminated in 1995 update to the MIL Spec. Studies were conducted using the FT fuel, JP

  20. Leachate recirculation between alternating aged refuse bioreactors and its effect on refuse decomposition.

    PubMed

    Sun, Xiaojie; Sun, Yingjie; Zhao, Youcai; Wang, Ya-Nan

    2014-01-01

    In a sequencing batch bioreactor landfill system which combined a fresh and an aged refuse bioreactor, blockage occurred frequently in the aged refuse bioreactor during the treatment of leachate from the fresh refuse bioreactor. To overcome this problem, another aged refuse bioreactor was added, when blockage occurred, the two aged refuse bioreactor operated alternatively. A fresh refuse bioreactor F combined with two alternating aged refuse bioreactors A1 and A2 was called alternate recirculation process (ARP) in this study. The bioreactor system was operated in three stages, and the three bioreactors were exposed to air to facilitate surface re-aeration. The effect of the ARP on the accelerated degradation of fresh refuse was compared before and after blockage occurs in A1. The results indicated that ARP can improve the leachate production rate. The average daily net production rates of leachate in Stages 2 and 3 were approximately 2.1 and 1.6 mL (kgrefuse d)(-1), respectively, which exceeded that of Stage 1 (1.3 mL (kg refuse d)(-1)). The chemical oxygen demand and NH3-N concentrations of the leachate from Stage 1 are 1000 and 25mgL(-1) after 2.1 and 2.7 y, respectively. For Stages 2 and 3, these concentrations reach approximately after 0.877 and 1.3 y. Faster refuse settlement was observed in Stages 2 and 3, with an average daily settlement of approximately 0.11%, as compared with Stage 1 (approximately 0.099%). ARP can accelerate the biodegradation of the fresh refuse and overcome the problem of the blockage in the aged refuse reactor.

  1. Food Refusal in Children: A Review of the Literature

    ERIC Educational Resources Information Center

    Williams, Keith E.; Field, Douglas G.; Seiverling, Laura

    2010-01-01

    Food refusal is a severe feeding problem in which children refuse to eat all or most foods presented and exhibit problems with growth. This review discusses the definition, etiology, and interventions pertaining to food refusal. The interventions utilized for food refusal typically consist of several treatment components. These treatment…

  2. 20 CFR 654.414 - Garbage and other refuse.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... made for collection of refuse at least twice a week, or more often if necessary. The disposal of refuse... 20 Employees' Benefits 3 2014-04-01 2014-04-01 false Garbage and other refuse. 654.414 Section 654... Garbage and other refuse. (a) Durable, fly-tight, clean containers in good condition of a minimum...

  3. 7 CFR 319.8-26 - Material refused entry.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ..., or other expenses incidental to the safeguarding or disposal of material refused entry by the... 7 Agriculture 5 2014-01-01 2014-01-01 false Material refused entry. 319.8-26 Section 319.8-26... Provisions § 319.8-26 Material refused entry. Any material refused entry for noncompliance with...

  4. 20 CFR 654.414 - Garbage and other refuse.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... made for collection of refuse at least twice a week, or more often if necessary. The disposal of refuse... 20 Employees' Benefits 3 2012-04-01 2012-04-01 false Garbage and other refuse. 654.414 Section 654... Garbage and other refuse. (a) Durable, fly-tight, clean containers in good condition of a minimum...

  5. 20 CFR 654.414 - Garbage and other refuse.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... made for collection of refuse at least twice a week, or more often if necessary. The disposal of refuse... 20 Employees' Benefits 3 2013-04-01 2013-04-01 false Garbage and other refuse. 654.414 Section 654... Garbage and other refuse. (a) Durable, fly-tight, clean containers in good condition of a minimum...

  6. 7 CFR 319.8-26 - Material refused entry.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ..., or other expenses incidental to the safeguarding or disposal of material refused entry by the... 7 Agriculture 5 2011-01-01 2011-01-01 false Material refused entry. 319.8-26 Section 319.8-26... Provisions § 319.8-26 Material refused entry. Any material refused entry for noncompliance with...

  7. 7 CFR 319.8-26 - Material refused entry.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ..., or other expenses incidental to the safeguarding or disposal of material refused entry by the... 7 Agriculture 5 2012-01-01 2012-01-01 false Material refused entry. 319.8-26 Section 319.8-26... Provisions § 319.8-26 Material refused entry. Any material refused entry for noncompliance with...

  8. 20 CFR 654.414 - Garbage and other refuse.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... made for collection of refuse at least twice a week, or more often if necessary. The disposal of refuse... 20 Employees' Benefits 3 2011-04-01 2011-04-01 false Garbage and other refuse. 654.414 Section 654... Garbage and other refuse. (a) Durable, fly-tight, clean containers in good condition of a minimum...

  9. 7 CFR 319.8-26 - Material refused entry.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ..., or other expenses incidental to the safeguarding or disposal of material refused entry by the... 7 Agriculture 5 2010-01-01 2010-01-01 false Material refused entry. 319.8-26 Section 319.8-26... Provisions § 319.8-26 Material refused entry. Any material refused entry for noncompliance with...

  10. 20 CFR 654.414 - Garbage and other refuse.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... made for collection of refuse at least twice a week, or more often if necessary. The disposal of refuse... 20 Employees' Benefits 3 2010-04-01 2010-04-01 false Garbage and other refuse. 654.414 Section 654... Garbage and other refuse. (a) Durable, fly-tight, clean containers in good condition of a minimum...

  11. 7 CFR 319.8-26 - Material refused entry.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ..., or other expenses incidental to the safeguarding or disposal of material refused entry by the... 7 Agriculture 5 2013-01-01 2013-01-01 false Material refused entry. 319.8-26 Section 319.8-26... Provisions § 319.8-26 Material refused entry. Any material refused entry for noncompliance with...

  12. One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels

    DOEpatents

    Sen, Ayusman; Yang, Weiran

    2014-03-18

    The invention relates to a method for manufacture of hydrocarbon fuels and oxygenated hydrocarbon fuels such as alkyl substituted tetrahydrofurans such as 2,5-dimethyltetrahydrofuran, 2-methyltetrahydrofuran, 5-methylfurfural and mixtures thereof. The method generally entails forming a mixture of reactants that includes carbonaceous material, water, a metal catalyst and an acid reacting that mixture in the presence of hydrogen. The reaction is performed at a temperature and for a time sufficient to produce a furan type hydrocarbon fuel. The process may be adapted to provide continuous manufacture of hydrocarbon fuels such as a furan type fuel.

  13. Comparing observations of fossil fuel-derived CO2 in California with predictions from bottom-up inventories

    NASA Astrophysics Data System (ADS)

    Graven, H. D.; Lueker, T.; Fischer, M. L.; Guilderson, T. P.; Keeling, R. F.; Brophy, K.; Arnold, T.; Bambha, R.; Callahan, W.; Campbell, J. E.; Frankenberg, C.; Hsu, Y.; Iraci, L. T.; Jeong, S.; Kim, J.; LaFranchi, B. W.; Lehman, S.; Manning, A.; Michelsen, H. A.; Miller, J. B.; Newman, S.; Parazoo, N.; Sloop, C.; Walker, S.; Whelan, M.; Wunch, D.

    2015-12-01

    The US state of California has a progressive climate change mitigation policy, AB-32, enacted in 2006 to reduce greenhouse gas emissions 15% by 2020 and then a further 80% by 2050. Bottom-up inventories indicate California's fossil fuel CO2 emissions are currently about 100 Mt C per year, but different inventories show discrepancies of ±15% in the state-wide total, and some larger discrepancies in various sub-regions of the state. We are developing a top-down framework for investigating fossil fuel and biospheric CO2 fluxes in California using atmospheric observations and models. California has a relatively dense collaborative network of greenhouse gas observations run by several universities, government laboratories and Earth Networks. Using this collaborative network, we conducted three field campaigns in 2014-15 to sample flasks at 10 tower sites across the state. Flasks were analysed for atmospheric CO2 and CO concentrations and for stable isotopes and radiocarbon in CO2. The flask observations of radiocarbon in CO2 allow patterns of fossil fuel-derived and biospheric CO2 to be distinguished at relatively high resolution across the state. We will report initial results from the observations showing regional gradients in fossil fuel-derived CO2 and fluctuations from changing weather patterns. We will compare the observations of fossil fuel-derived CO2 to predictions from several bottom-up inventories and two atmospheric models. Linking the flask data with observations from OCO-2, TCCON, aircraft flights and ground-based in situ analyzers, we will examine the variation in total CO2 and its drivers over California. Further analysis is planned to integrate the data into an inversion framework for fossil fuel and biospheric CO2 fluxes over California.

  14. Advection of surface-derived organic carbon fuels microbial reduction in Bangladesh groundwater

    PubMed Central

    Mailloux, Brian J.; Trembath-Reichert, Elizabeth; Cheung, Jennifer; Watson, Marlena; Stute, Martin; Freyer, Greg A.; Ferguson, Andrew S.; Ahmed, Kazi Matin; Alam, Md. Jahangir; Buchholz, Bruce A.; Thomas, James; Layton, Alice C.; Zheng, Yan; Bostick, Benjamin C.; van Geen, Alexander

    2013-01-01

    Chronic exposure to arsenic (As) by drinking shallow groundwater causes widespread disease in Bangladesh and neighboring countries. The release of As naturally present in sediment to groundwater has been linked to the reductive dissolution of iron oxides coupled to the microbial respiration of organic carbon (OC). The source of OC driving this microbial reduction—carbon deposited with the sediments or exogenous carbon transported by groundwater—is still debated despite its importance in regulating aquifer redox status and groundwater As levels. Here, we used the radiocarbon (14C) signature of microbial DNA isolated from groundwater samples to determine the relative importance of surface and sediment-derived OC. Three DNA samples collected from the shallow, high-As aquifer and one sample from the underlying, low-As aquifer were consistently younger than the total sediment carbon, by as much as several thousand years. This difference and the dominance of heterotrophic microorganisms implies that younger, surface-derived OC is advected within the aquifer, albeit more slowly than groundwater, and represents a critical pool of OC for aquifer microbial communities. The vertical profile shows that downward transport of dissolved OC is occurring on anthropogenic timescales, but bomb 14C-labeled dissolved OC has not yet accumulated in DNA and is not fueling reduction. These results indicate that advected OC controls aquifer redox status and confirm that As release is a natural process that predates human perturbations to groundwater flow. Anthropogenic perturbations, however, could affect groundwater redox conditions and As levels in the future. PMID:23487743

  15. Re-Evaluating Neptunium in Uranyl Phases Derived from Corroded Spent Fuel

    SciTech Connect

    Fortner, Jeffrey A.; Finch, Robert J.; Kropf, A. Jeremy; Cunnane, James C.

    2004-11-15

    Interest in mechanisms that may control radioelement release from corroded commercial spent nuclear fuel (CSNF) has been heightened by the selection of the Yucca Mountain site in Nevada as the repository for high-level nuclear waste in the United States. Neptunium is an important radionuclide in repository models owing to its relatively long half-life and its high aqueous mobility as neptunyl [Np(V)O{sub 2}{sup +}]. The possibility of neptunium sequestration into uranyl alteration phases produced by corroding CSNF would suggest a process for lowering neptunium concentration and subsequent migration from a geologic repository. However, there remains little experimental evidence that uranyl compounds will, in fact, serve as long-term host phases for the retention of neptunium under conditions expected in a deep geologic repository. To directly explore this possibility, we examined specimens of uranyl alteration phases derived from humid-air-corroded CSNF by X-ray absorption spectroscopy to better determine neptunium uptake in these phases. Although neptunium fluorescence was readily observed from as-received CSNF, it was not observed from the uranyl alteration rind. We establish upper limits for neptunium incorporation into CSNF alteration phases that are significantly below previously reported concentrations obtained by using electron energy loss spectroscopy (EELS). We attribute the discrepancy to a plural-scattering event that creates a spurious EELS peak at the neptunium-M{sub V} energy.

  16. Re-evaluating neptunium in uranyl phases derived from corroded spent fuel.

    SciTech Connect

    Fortner, J. A.; Finch, R. J.; Kropf, A. J.; Cunnane, J. C.; Chemical Engineering

    2004-11-01

    Interest in mechanisms that may control radioelement release from corroded commercial spent nuclear fuel (CSNF) has been heightened by the selection of the Yucca Mountain site in Nevada as the repository for high-level nuclear waste in the United States. Neptunium is an important radionuclide in repository models owing to its relatively long half-life and its high aqueous mobility as neptunyl [Np(V)O+2]. The possibility of neptunium sequestration into uranyl alteration phases produced by corroding CSNF would suggest-a process for lowering neptunium concentration and subsequent migration from a geologic repository. However, there remains little experimental evidence that uranyl compounds will, in fact, serve as long-term host phases for the retention of neptunium under conditions expected in a deep geologic repository. To directly explore this possibility, we examined specimens of uranyl alteration phases derived from humid-air-corroded CSNF by X-ray absorption spectroscopy to better determine neptunium uptake in these phases. Although neptunium fluorescence was readily observed from as-received CSNF, it was not observed from the uranyl alteration rind. We establish upper limits for neptunium incorporation into CSNF alteration phases that are significantly below previously reported concentrations obtained by using electron energy loss spectroscopy (EELS). We attribute the discrepancy to a plural-scattering event that creates a spurious EELS peak at the neptunium-MV energy.

  17. Bioconversion of coal-derived synthesis gas to liquid fuels. [Butyribacterium methylotrophicum

    SciTech Connect

    Jain, M.K.

    1991-01-01

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  18. Tracking the spectroscopic and chromatographic changes of algal derived organic matter in a microbial fuel cell.

    PubMed

    Hur, Jin; Lee, Bo-Mi; Choi, Kwang-Soon; Min, Booki

    2014-02-01

    Changes in the characteristics of algae-derived organic matter (AOM) were examined upon the operation of a microbial fuel cell (MFC) using multiple analytical methods. Temporal variations in the UV absorption and fluorescence excitation-emission matrix of the AOM revealed that less condensed humic-like components and large-sized protein-like fluorescent compounds were preferentially decomposed over the period of electricity generation. They also showed that low UV-absorbing extracellular organic matters (EOM) were produced at the end of the operation. SEC chromatograms demonstrated that smaller-sized UV-absorbing components were initially decomposed, followed by the net production of EOM with an intermediate molecular weight. Fourier transform infrared (FT-IR) spectra showed that proteins and polysaccharides were the two most dominant structures of the AOM in the MFC. Two-dimensional correlation spectroscopy combined with FT-IR provided additional valuable information on the sequential changes of the AOM, which occurred in the order of proteins → acidic functional groups → polysaccharides → amino acids/proteins.

  19. Characterising the composition of waste-derived fuels using a novel image analysis tool.

    PubMed

    Peddireddy, S; Longhurst, P J; Wagland, S T

    2015-06-01

    An experimental study was completed using a previously developed and innovative image analysis approach, which has been applied here to shredded waste materials representative of waste-derived fuels. Waste components were collected from source-segregated recycling containers and shredded to <150 mm. These materials were then used to produce 3× samples of different composition. The samples were spread to represent materials on a conveyor belt, and multiple images of each sample were captured using 10×10 cm and 20×20 cm quadrats. The images were processed using ERDAS Imagine software to determine the area covered by each waste component. This coverage was converted into a mass using density data determined as part of this study, yielding a determined composition which was then compared with the known composition of the samples. The image analysis results indicated a strong correlation with the actual values (mean r=0.89). The area coverage of the sample (10×10 cm or 20×20 cm) contributes to the accuracy as the dot-grid approach used with the particle size within the samples may result in components not being sufficiently monitored. This manuscript presents initial results of the application of an adapted innovative image-based method, and critically assesses how the technique could be improved and developed in the future.

  20. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial

  1. DESIGNING AN OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION AND COFIRING SAWDUST WITH COAL AT ALBRIGHT GENERATING STATION

    SciTech Connect

    K. Payette; D. Tillman

    2003-01-01

    During the period October 1, 2002--December 31, 2002, Allegheny Energy Supply Co., LLC (Allegheny) completed the first year of testing at the Willow Island cofiring project. This included data acquisition and analysis associated with certain operating parameters and environmental results. Over 2000 hours of cofiring operation were logged at Willow Island, and about 4,000 tons of sawdust were burned along with slightly more tire-derived fuel (TDF). The results were generally favorable. During this period, also, a new grinder was ordered for the Albright Generating Station to handle oversized material rejected by the disc screen. This report summarizes the activities associated with the Designer Opportunity Fuel program, and demonstrations at Willow Island and Albright Generating Stations. It details the test results at Willow Island and summarizes the grinder program at Albright.

  2. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

  3. An integrated appraisal of energy recovery options in the United Kingdom using solid recovered fuel derived from municipal solid waste.

    PubMed

    Garg, A; Smith, R; Hill, D; Longhurst, P J; Pollard, S J T; Simms, N J

    2009-08-01

    This paper reports an integrated appraisal of options for utilising solid recovered fuels (SRF) (derived from municipal solid waste, MSW) in energy intensive industries within the United Kingdom (UK). Four potential co-combustion scenarios have been identified following discussions with industry stakeholders. These scenarios have been evaluated using (a) an existing energy and mass flow framework model, (b) a semi-quantitative risk analysis, (c) an environmental assessment and (d) a financial assessment. A summary of results from these evaluations for the four different scenarios is presented. For the given ranges of assumptions; SRF co-combustion with coal in cement kilns was found to be the optimal scenario followed by co-combustion of SRF in coal-fired power plants. The biogenic fraction in SRF (ca. 70%) reduces greenhouse gas (GHG) emissions significantly ( approximately 2500 g CO(2) eqvt./kg DS SRF in co-fired cement kilns and approximately 1500 g CO(2) eqvt./kg DS SRF in co-fired power plants). Potential reductions in electricity or heat production occurred through using a lower calorific value (CV) fuel. This could be compensated for by savings in fuel costs (from SRF having a gate fee) and grants aimed at reducing GHG emission to encourage the use of fuels with high biomass fractions. Total revenues generated from coal-fired power plants appear to be the highest ( 95 pounds/t SRF) from the four scenarios. However overall, cement kilns appear to be the best option due to the low technological risks, environmental emissions and fuel cost. Additionally, cement kiln operators have good experience of handling waste derived fuels. The scenarios involving co-combustion of SRF with MSW and biomass were less favourable due to higher environmental risks and technical issues.

  4. DESIGNING AN OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION

    SciTech Connect

    K. Payette; D. Tillman

    2001-01-01

    During the period October 1, 2000 - December 31, 2000, Allegheny Energy Supply Co., LLC (Allegheny) executed a Cooperative Agreement with the National Energy Technology Laboratory to implement a major cofiring demonstration at the Willow Island Generating Station Boiler No.2. Willow Island Boiler No.2 is a cyclone boiler. Allegheny also will demonstrate separate injection cofiring at the Albright Generating Station Boiler No.3, a tangentially fired boiler. The Allegheny team includes Foster Wheeler as its primary subcontractor. Additional subcontractors are Cofiring Alternatives and N.S. Harding and Associates. This report summarizes the activities associated with the Designer Opportunity Fuel program, and demonstrations at Willow Island and Albright Generating Stations. The second quarter of the project involved completing the designs for each location. Further, geotechnical investigations proceeded at each site. Preparations were made to perform demolition on two small buildings at the Willow Island site. Fuels strategies were initiated for each site. Test planning commenced for each site. A groundbreaking ceremony was held at the Willow Island site on October 18, with Governor C. Underwood being the featured speaker.

  5. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  6. Development of alternative fuels from coal-derived syngas. Quarterly status report No. 6, January 1--March 31, 1992

    SciTech Connect

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products` laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively ``benign`` system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE`s program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  7. Refusing The Choice: Balancing Life and Work

    NASA Astrophysics Data System (ADS)

    Brooks, J.

    2012-12-01

    The Choice The intellect of man is forced to choose perfection of the life, or of the work, And if it take the second must refuse A heavenly mansion, raging in the dark. When all that story's finished, what's the news? In luck or out the toil has left its mark: That old perplexity an empty purse, Or the day's vanity, the night's remorse. William Butler Yeats William Yeats put forward The Choice that I feel too many scientists feel they must make. Too often, many choose to leave science. How do we refuse this choice and find balance between life and our careers? While I don't know the answer, I will share choices that have lead to not perfection but satisfaction in science careers and lives. The role of mentors, supportive spouses, the luck of the job, and flexibility in research directions have all contributed to being able to refuse to choose.

  8. Performance, methanol tolerance and stability of Fe-aminobenzimidazole derived catalyst for direct methanol fuel cells

    NASA Astrophysics Data System (ADS)

    Sebastián, David; Serov, Alexey; Artyushkova, Kateryna; Atanassov, Plamen; Aricò, Antonino S.; Baglio, Vincenzo

    2016-07-01

    Highly active and durable non-platinum group metals (non-PGM) catalyst based on iron-nitrogen-carbon (Fe-N-C) for the oxygen reduction reaction (ORR) derived from pyrolyzed Fe-aminobenzimidazole (Fe-ABZIM) was synthesized by sacrificial support method (SSM), and characterized by several physical-chemical techniques: scanning electron microscopy, transmission electron microscopy, Brunauer-Emmett-Teller method and X-ray photoelectron spectroscopy. In half-cell electrochemical configuration, the Fe-ABZIM catalyst presented a significant improvement of ORR activity with respect to a recently reported non-PGM formulation based on Fe-aminoantipyrine, with an enhancement of half-wave potential of about 85 mV in O2-saturated sulfuric acid solution. To the moment, the gap with respect to a benchmark Pt/C catalyst was about 90 mV. The Fe-ABZIM catalyst showed a remarkably high tolerance to methanol, resulting in superior ORR performance compared to Pt/C at methanol concentrations higher than 0.02 M. In direct methanol fuel cell (DMFC) good performances were also obtained. A durability test (100 h) at 90 °C, feeding 5 M methanol, was carried out. A certain decrease of performance was recorded, amounting to -0.20 mW cm-2 h-1 at the very beginning of test and -0.05 mW cm-2 h-1 at the end. However, the Fe-ABZIM is more adequate than previously reported formulations in terms of both ORR activity and stability.

  9. Test and evaluation of shale derived jet fuel by the United States Air Force

    SciTech Connect

    Delaney, C.L.

    1985-01-01

    In June 1980, the United States Congress passed the Energy Security Act which provided for the formation of the United States Synthetic Fuels Corporation and amended the Defense Production Act of 1950 to provide for synthetic fuels for the Department of Defense (DOD). A subsequent law, P.L., 96-304, appropriated up to $20 billion for financial incentives to foster a national synthetic fuel industry. The initial synthetic fuel project funded under the Energy Security Act is the Unocal Parachute Creek Project in Colorado with an expected shale oil production of 10,000 bbls/day. The Defense Fuel Supply Center (DFSC) contracted with Gary Energy Refining Company, Fruita, Colorado to provide approximately 5,000 bbls/day of shale JP-4 for the United States Air Force (USAF) using crude from the Parachute Creek Project, with initial deliveries to begin in 1985.

  10. Improving surface coal refuse disposal site inspections

    SciTech Connect

    Meister, R.A.; Hoffman, R.L.

    1980-06-01

    The study on improving surface coal refuse disposal site inspections included surface inspections of 15 refuse disposal sites. Monthly aerial photos were taken of the sites and computer methods were used to determine elevation changes. Photogrammetric techniques that were used are described in detail. A comparison of the results of each of these inspection techniques is included. A detailed evaluation of the photogrammetric techniques was made and conclusions were drawn concerning the advantages and disadvantages of using aerial photography and photogrammetry as part of the inspection procedure. Operators' opinions of the aerial photography methods are included.

  11. Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing.

    PubMed

    Serrano-Ruiz, Juan Carlos; Luque, Rafael; Sepúlveda-Escribano, Antonio

    2011-11-01

    Global warming issues and the medium-term depletion of fossil fuel reserves are stimulating researchers around the world to find alternative sources of energy and organic carbon. Biomass is considered by experts the only sustainable source of energy and organic carbon for our industrial society, and it has the potential to displace petroleum in the production of chemicals and liquid transportation fuels. However, the transition from a petroleum-based economy to one based on biomass requires new strategies since the petrochemical technologies, well-developed over the last century, are not valid to process the biomass-derived compounds. Unlike petroleum feedstocks, biomass derived platform molecules possess a high oxygen content that gives them low volatility, high solubility in water, high reactivity and low thermal stability, properties that favour the processing of these resources by catalytic aqueous-phase technologies at moderate temperatures. This tutorial review is aimed at providing a general overview of processes, technologies and challenges that lie ahead for a range of different aqueous-phase transformations of some of the key biomass-derived platform molecules into liquid fuels for the transportation sector and related high added value chemicals.

  12. Low Emissions Burner Technology for Metal Processing Industry using Byproducts and Biomass Derived Liquid Fuels

    SciTech Connect

    Agrawal, Ajay; Taylor, Robert

    2013-09-30

    This research and development efforts produced low-emission burner technology capable of operating on natural gas as well as crude glycerin and/or fatty acids generated in biodiesel plants. The research was conducted in three stages (1) Concept definition leading to the design and development of a small laboratory scale burner, (2) Scale-up to prototype burner design and development, and (3) Technology demonstration with field vefiication. The burner design relies upon the Flow Blurring (FB) fuel injection based on aerodynamically creating two-phase flow near the injector exit. The fuel tube and discharge orifice both of inside diameter D are separated by gap H. For H < 0.25D, the atomizing air bubbles into liquid fuel to create a two-phase flow near the tip of the fuel tube. Pressurized two-phase fuel-air mixture exits through the discharge orifice, which results in expansion and breakup of air bubbles yielding a spray with fine droplets. First, low-emission combustion of diesel, biodiesel and straight VO (soybean oil) was achieved by utilizing FB injector to yield fine sprays for these fuels with significantly different physical properties. Visual images for these baseline experiments conducted with heat release rate (HRR) of about 8 kW illustrate clean blue flames indicating premixed combustion for all three fuels. Radial profiles of the product gas temperature at the combustor exit overlap each other signifying that the combustion efficiency is independent of the fuel. At the combustor exit, the NOx emissions are within the measurement uncertainties, while CO emissions are slightly higher for straight VO as compared to diesel and biodiesel. Considering the large variations in physical and chemical properties of fuels considered, the small differences observed in CO and NOx emissions show promise for fuel-flexible, clean combustion systems. FB injector has proven to be very effective in atomizing fuels with very different physical properties, and it offers a

  13. Evaluation of Exxon Donor Solvent (EDS) coal-derived liquid as utility diesel fuel. Final report

    SciTech Connect

    Heater, W.R.; Froh, T.W.; Ariga, S.; Baker, Q.A.; Piispanen, W.; Webb, P.; Trayser, D.; Keane, W.J.

    1983-10-01

    The program consisted of three phases: (I) characterization of the physical and chemical properties of EDS, (II) evaluation of EDS in a laboratory medium-speed diesel engine, and (III) evaluation of EDS in a low-speed diesel engine operating at a utility. The characteristics of high aromatic content and low cetane number that were found during Phase I made it unlikely that EDS could be used as a direct substitute for diesel fuel without engine modification to provide ignition assistance. Phase II was conducted on a 12-cylinder General Electric Company 7FDL diesel engine. Blends of up to 30% EDS and 70% 0.2 diesel fuel (DF-2) were successfully consumed. Dual fuel tests were also conducted on a single cylinder by injecting EDS through the existing engine fuel oil system and injecting DF-2 through an auxiliary nozzle as an ignition source. Acceptable operation was achieved using 5 to 10% pilot oil heat input. Phase III was conducted on a 16-cylinder Cooper-Bessemer LSV-16-GDT diesel engine at an EUC plant in Easton, Maryland. Blends of up to 66.7% EDS and 33.3% DF-2 were successfully consumed. Dual fuel tests were also conducted on a single cylinder by injecting EDS through the existing fuel oil system and using a natural-gas-fueled precombustion chamber as an ignition source. Acceptable operation was achieved using 3 to 6% pilot gas heat input. The program confirmed that it is feasible to consume significant proportions of EDS in a diesel engine, but more development is needed before EDS can be considered a viable alternative liquid fuel for diesel engines, and an industrial hygiene program is needed to assure safe handling of the fuel.

  14. Fluidized bed combustion of pelletized biomass and waste-derived fuels

    SciTech Connect

    Chirone, R.; Scala, F.; Solimene, R.; Salatino, P.; Urciuolo, M.

    2008-10-15

    The fluidized bed combustion of three pelletized biogenic fuels (sewage sludge, wood, and straw) has been investigated with a combination of experimental techniques. The fuels have been characterized from the standpoints of patterns and rates of fuel devolatilization and char burnout, extent of attrition and fragmentation, and their relevance to the fuel particle size distribution and the amount and size distribution of primary ash particles. Results highlight differences and similarities among the three fuels tested. The fuels were all characterized by limited primary fragmentation and relatively long devolatilization times, as compared with the time scale of particle dispersion away from the fuel feeding ports in practical FBC. Both features are favorable to effective lateral distribution of volatile matter across the combustor cross section. The three fuels exhibited distinctively different char conversion patterns. The high-ash pelletized sludge burned according to the shrinking core conversion pattern with negligible occurrence of secondary fragmentation. The low-ash pelletized wood burned according to the shrinking particle conversion pattern with extensive occurrence of secondary fragmentation. The medium-ash pelletized straw yielded char particles with a hollow structure, resembling big cenospheres, characterized by a coherent inorganic outer layer strong enough to prevent particle fragmentation. Inert bed particles were permanently attached to the hollow pellets as they were incorporated into ash melts. Carbon elutriation rates were very small for all the fuels tested. For pelletized sludge and straw, this was mostly due to the shielding effect of the coherent ash skeleton. For the wood pellet, carbon attrition was extensive, but was largely counterbalanced by effective afterburning due to the large intrinsic reactivity of attrited char fines. The impact of carbon attrition on combustion efficiency was negligible for all the fuels tested. The size

  15. Further investigation of the impact of the co-combustion of tire-derived fuel and petroleum coke on the petrology and chemistry of coal combustion products

    SciTech Connect

    Hower, J.C.; Robertson, J.D.; Elswick, E.R.; Roberts, J.M.; Brandsteder, K.; Trimble, A.S.; Mardon, S.M.

    2007-07-01

    A Kentucky cyclone-fired unit burns coal and tire-derived fuel, sometimes in combination with petroleum coke. A parallel pulverized combustion (pc) unit at the same plant burns the same coal, without the added fuels. The petrology, chemistry, and sulfur isotope distribution in the fuel and resulting combustion products was investigated for several configurations of the fuel blend. Zinc and Cd in the combustion products are primarily contributed from the tire-derived fuel, the V and Ni are primarily from the petroleum coke, and the As and Hg are probably largely from the coal. The sulfur isotope distribution in the cyclone unit is complicated due to the varying fuel sources. The electrostatic precipitator (ESP) array in the pc unit shows a subtle trend towards heavier S isotopic ratios in the cooler end of the ESP.

  16. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  17. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  18. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-04-23

    This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  19. 28 CFR 345.34 - Refusal to employ.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (FPI) INMATE WORK PROGRAMS Recruitment and Hiring Practices § 345.34 Refusal to employ. (a) The SOI has... documented by a memorandum to the unit team listing reasons for the refusal, with a copy to the...

  20. Applications study of advanced power generation systems utilizing coal-derived fuels. Volume 1: Executive summary

    NASA Technical Reports Server (NTRS)

    Robson, F. L.

    1981-01-01

    The technology status of phosphoric acid and molten carbon fuel cells, combined gas and steam turbine cycles, and magnetohydrodynamic energy conversion systems was assessed and the power performance of these systems when operating with medium-Btu fuel gas whether delivered by pipeline to the power plant or in an integrated mode in which the coal gasification process and power system are closely coupled as an overall power plant was evaluated. Commercially available combined-cycle gas turbine systems can reach projected required performance levels for advanced systems using currently available technology. The phosphoric acid fuel cell appears to be the next most likely candidate for commercialization. On pipeline delivery, the systems efficiency ranges from 40.9% for the phosphoric acid fuel cell to 63% for the molten carbonate fuel cell system. The efficiencies of the integrated power plants vary from approximately 39-40% for the combined cycle to 46-47% for the molden carbonate fuel cell systems. Conventional coal-fired steam stations with flue-gas desulfurization have only 33-35% efficiency.

  1. Recent decreases in fossil-fuel emissions of ethane and methane derived from firn air.

    PubMed

    Aydin, Murat; Verhulst, Kristal R; Saltzman, Eric S; Battle, Mark O; Montzka, Stephen A; Blake, Donald R; Tang, Qi; Prather, Michael J

    2011-08-10

    Methane and ethane are the most abundant hydrocarbons in the atmosphere and they affect both atmospheric chemistry and climate. Both gases are emitted from fossil fuels and biomass burning, whereas methane (CH(4)) alone has large sources from wetlands, agriculture, landfills and waste water. Here we use measurements in firn (perennial snowpack) air from Greenland and Antarctica to reconstruct the atmospheric variability of ethane (C(2)H(6)) during the twentieth century. Ethane levels rose from early in the century until the 1980s, when the trend reversed, with a period of decline over the next 20 years. We find that this variability was primarily driven by changes in ethane emissions from fossil fuels; these emissions peaked in the 1960s and 1970s at 14-16 teragrams per year (1 Tg = 10(12) g) and dropped to 8-10 Tg  yr(-1) by the turn of the century. The reduction in fossil-fuel sources is probably related to changes in light hydrocarbon emissions associated with petroleum production and use. The ethane-based fossil-fuel emission history is strikingly different from bottom-up estimates of methane emissions from fossil-fuel use, and implies that the fossil-fuel source of methane started to decline in the 1980s and probably caused the late twentieth century slow-down in the growth rate of atmospheric methane.

  2. [Professionals' training and refusal of nursing care].

    PubMed

    Bay, Corinne

    2016-10-01

    A patient's refusal of nursing care concerns the caregivers. Future professionals must be prepared for it and student nurses are trained to deal with such situations. It is also important to empower patients and support them in their choice. This article presents the example of the Haute École Robert Schuman in Libramont, Belgium.

  3. Energy balances in the production and end use of alcohols derived from biomass. A fuels-specific comparative analysis of alternate ethanol production cycles

    SciTech Connect

    Not Available

    1980-10-01

    Considerable public interest and debate have been focused on the so-called energy balance issue involved in the conversion of biomass materials into ethanol for fuel use. This report addresses questions of net gains in premium fuels that can be derived from the production and use of ethanol from biomass, and shows that for the US alcohol fuel program, energy balance need not be a concern. Three categories of fuel gain are discussed in the report: (1) Net petroleum gain; (2) Net premium fuel gain (petroleum and natural gas); and (3) Net energy gain (for all fuels). In this study the investment of energy (in the form of premium fuels) in alcohol production includes all investment from cultivating, harvesting, or gathering the feedstock and raw materials, through conversion of the feedstock to alcohol, to the delivery to the end-user. To determine the fuel gains in ethanol production, six cases, encompassing three feedstocks, five process fuels, and three process variations, have been examined. For each case, two end-uses (automotive fuel use and replacement of petrochemical feedstocks) were scrutinized. The end-uses were further divided into three variations in fuel economy and two different routes for production of ethanol from petrochemicals. Energy requirements calculated for the six process cycles accounted for fuels used directly and indirectly in all stages of alcohol production, from agriculture through distribution of product to the end-user. Energy credits were computed for byproducts according to the most appropriate current use.

  4. 25 CFR 135.6 - Refusal of water delivery.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 25 Indians 1 2013-04-01 2013-04-01 false Refusal of water delivery. 135.6 Section 135.6 Indians... INDIAN IRRIGATION PROJECT Charges Assessed Against Irrigation District Lands § 135.6 Refusal of water delivery. The right is reserved to the United States to refuse the delivery of water to each of the...

  5. 25 CFR 135.23 - Refusal of water delivery.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 25 Indians 1 2013-04-01 2013-04-01 false Refusal of water delivery. 135.23 Section 135.23 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR FINANCIAL ACTIVITIES CONSTRUCTION ASSESSMENTS, CROW... District § 135.23 Refusal of water delivery. The right is reserved to refuse the delivery of water to...

  6. 9 CFR 98.9 - Embryos refused entry.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 9 Animals and Animal Products 1 2014-01-01 2014-01-01 false Embryos refused entry. 98.9 Section 98... EMBRYOS AND ANIMAL SEMEN Ruminant and Swine Embryos from Regions Free of Rinderpest and Foot-and-Mouth Disease; and Embryos of Horses and Asses § 98.9 Embryos refused entry. Any embryo refused entry into...

  7. 9 CFR 98.9 - Embryos refused entry.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 9 Animals and Animal Products 1 2012-01-01 2012-01-01 false Embryos refused entry. 98.9 Section 98... EMBRYOS AND ANIMAL SEMEN Ruminant and Swine Embryos from Regions Free of Rinderpest and Foot-and-Mouth Disease; and Embryos of Horses and Asses § 98.9 Embryos refused entry. Any embryo refused entry into...

  8. 9 CFR 98.9 - Embryos refused entry.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 9 Animals and Animal Products 1 2013-01-01 2013-01-01 false Embryos refused entry. 98.9 Section 98... EMBRYOS AND ANIMAL SEMEN Ruminant and Swine Embryos from Regions Free of Rinderpest and Foot-and-Mouth Disease; and Embryos of Horses and Asses § 98.9 Embryos refused entry. Any embryo refused entry into...

  9. 9 CFR 98.9 - Embryos refused entry.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Embryos refused entry. 98.9 Section 98... EMBRYOS AND ANIMAL SEMEN Ruminant and Swine Embryos from Regions Free of Rinderpest and Foot-and-Mouth Disease; and Embryos of Horses and Asses § 98.9 Embryos refused entry. Any embryo refused entry into...

  10. 9 CFR 98.9 - Embryos refused entry.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 9 Animals and Animal Products 1 2011-01-01 2011-01-01 false Embryos refused entry. 98.9 Section 98... EMBRYOS AND ANIMAL SEMEN Ruminant and Swine Embryos from Regions Free of Rinderpest and Foot-and-Mouth Disease; and Embryos of Horses and Asses § 98.9 Embryos refused entry. Any embryo refused entry into...

  11. School Refusal Behavior: Prevalence, Characteristics, and the Schools' Response.

    ERIC Educational Resources Information Center

    Stickney, Marcella I.; Miltenberger, Raymond G.

    1998-01-01

    A survey of 288 elementary and secondary North Dakota schools found 75% had a school refusal behavior (SRB) identification system in place, 57% had a school psychologist available, principals were most frequently responsible for identifying school refusers, 2.3% of students were identified as school refusers of which 49% falsely claimed illness,…

  12. Refusal Skill Ability: An Examination of Adolescent Perceptions of Effectiveness

    ERIC Educational Resources Information Center

    Nichols, Tracy R.; Birnel, Sara; Graber, Julia A.; Brooks-Gunn, Jeanne; Botvin, Gilbert J.

    2010-01-01

    This pilot study examined whether refusal assertion as defined by a proven drug prevention program was associated with adolescent perceptions of effectiveness by comparing two sets of coded responses to adolescent videotaped refusal role-plays (N = 63). The original set of codes was defined by programmatic standards of refusal assertion and the…

  13. 30 CFR 817.83 - Coal mine waste: Refuse piles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Coal mine waste: Refuse piles. 817.83 Section... ACTIVITIES § 817.83 Coal mine waste: Refuse piles. Refuse piles shall meet the requirements of § 817.81, the...) Drainage control. (1) If the disposal area contains springs, natural or manmade water courses, or...

  14. 30 CFR 817.83 - Coal mine waste: Refuse piles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Coal mine waste: Refuse piles. 817.83 Section... ACTIVITIES § 817.83 Coal mine waste: Refuse piles. Refuse piles shall meet the requirements of § 817.81, the...) Drainage control. (1) If the disposal area contains springs, natural or manmade water courses, or...

  15. 30 CFR 816.83 - Coal mine waste: Refuse piles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Coal mine waste: Refuse piles. 816.83 Section... ACTIVITIES § 816.83 Coal mine waste: Refuse piles. Refuse piles shall meet the requirements of § 816.81, the...) Drainage control. (1) If the disposal area contains springs, natural or manmade water courses, or...

  16. 30 CFR 816.83 - Coal mine waste: Refuse piles.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Coal mine waste: Refuse piles. 816.83 Section... ACTIVITIES § 816.83 Coal mine waste: Refuse piles. Refuse piles shall meet the requirements of § 816.81, the...) Drainage control. (1) If the disposal area contains springs, natural or manmade water courses, or...

  17. 30 CFR 816.83 - Coal mine waste: Refuse piles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Coal mine waste: Refuse piles. 816.83 Section... ACTIVITIES § 816.83 Coal mine waste: Refuse piles. Refuse piles shall meet the requirements of § 816.81, the...) Drainage control. (1) If the disposal area contains springs, natural or manmade water courses, or...

  18. 30 CFR 816.83 - Coal mine waste: Refuse piles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Coal mine waste: Refuse piles. 816.83 Section... ACTIVITIES § 816.83 Coal mine waste: Refuse piles. Refuse piles shall meet the requirements of § 816.81, the...) Drainage control. (1) If the disposal area contains springs, natural or manmade water courses, or...

  19. 30 CFR 817.83 - Coal mine waste: Refuse piles.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Coal mine waste: Refuse piles. 817.83 Section... ACTIVITIES § 817.83 Coal mine waste: Refuse piles. Refuse piles shall meet the requirements of § 817.81, the...) Drainage control. (1) If the disposal area contains springs, natural or manmade water courses, or...

  20. 30 CFR 817.83 - Coal mine waste: Refuse piles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Coal mine waste: Refuse piles. 817.83 Section... ACTIVITIES § 817.83 Coal mine waste: Refuse piles. Refuse piles shall meet the requirements of § 817.81, the...) Drainage control. (1) If the disposal area contains springs, natural or manmade water courses, or...

  1. 21 CFR 316.14 - Refusal to provide written recommendations.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 5 2013-04-01 2013-04-01 false Refusal to provide written recommendations. 316.14... (CONTINUED) DRUGS FOR HUMAN USE ORPHAN DRUGS Written Recommendations for Investigations of Orphan Drugs § 316.14 Refusal to provide written recommendations. (a) FDA may refuse to provide written...

  2. 21 CFR 316.14 - Refusal to provide written recommendations.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 5 2014-04-01 2014-04-01 false Refusal to provide written recommendations. 316.14... (CONTINUED) DRUGS FOR HUMAN USE ORPHAN DRUGS Written Recommendations for Investigations of Orphan Drugs § 316.14 Refusal to provide written recommendations. (a) FDA may refuse to provide written...

  3. 21 CFR 316.14 - Refusal to provide written recommendations.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 5 2011-04-01 2011-04-01 false Refusal to provide written recommendations. 316.14... (CONTINUED) DRUGS FOR HUMAN USE ORPHAN DRUGS Written Recommendations for Investigations of Orphan Drugs § 316.14 Refusal to provide written recommendations. (a) FDA may refuse to provide written...

  4. 21 CFR 316.14 - Refusal to provide written recommendations.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 5 2012-04-01 2012-04-01 false Refusal to provide written recommendations. 316.14... (CONTINUED) DRUGS FOR HUMAN USE ORPHAN DRUGS Written Recommendations for Investigations of Orphan Drugs § 316.14 Refusal to provide written recommendations. (a) FDA may refuse to provide written...

  5. 19 CFR 12.114 - Release or refusal of delivery.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false Release or refusal of delivery. 12.114 Section 12... delivery. If the completed Notice of Arrival directs the port director to release the shipment of... directs the port director to refuse delivery of the shipment, the shipment shall be refused delivery...

  6. 20 CFR 229.81 - Refusal to accept vocational rehabilitation.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 20 Employees' Benefits 1 2010-04-01 2010-04-01 false Refusal to accept vocational rehabilitation... Refusal to accept vocational rehabilitation. The DIB O/M is not payable for any month in which the disabled employee refuses, without good reason, to accept vocational rehabilitation services...

  7. 30 CFR 77.215 - Refuse piles; construction requirements.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Refuse piles; construction requirements. 77.215... COAL MINES Surface Installations § 77.215 Refuse piles; construction requirements. (a) Refuse deposited on a pile shall be spread in layers and compacted in such a manner so as to minimize the flow of...

  8. 30 CFR 77.215 - Refuse piles; construction requirements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Refuse piles; construction requirements. 77.215... COAL MINES Surface Installations § 77.215 Refuse piles; construction requirements. (a) Refuse deposited on a pile shall be spread in layers and compacted in such a manner so as to minimize the flow of...

  9. 30 CFR 77.215 - Refuse piles; construction requirements.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Refuse piles; construction requirements. 77.215... COAL MINES Surface Installations § 77.215 Refuse piles; construction requirements. (a) Refuse deposited on a pile shall be spread in layers and compacted in such a manner so as to minimize the flow of...

  10. 30 CFR 77.215 - Refuse piles; construction requirements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Refuse piles; construction requirements. 77.215... COAL MINES Surface Installations § 77.215 Refuse piles; construction requirements. (a) Refuse deposited on a pile shall be spread in layers and compacted in such a manner so as to minimize the flow of...

  11. 30 CFR 77.215 - Refuse piles; construction requirements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Refuse piles; construction requirements. 77.215... COAL MINES Surface Installations § 77.215 Refuse piles; construction requirements. (a) Refuse deposited on a pile shall be spread in layers and compacted in such a manner so as to minimize the flow of...

  12. 21 CFR 316.14 - Refusal to provide written recommendations.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 5 2010-04-01 2010-04-01 false Refusal to provide written recommendations. 316.14... (CONTINUED) DRUGS FOR HUMAN USE ORPHAN DRUGS Written Recommendations for Investigations of Orphan Drugs § 316.14 Refusal to provide written recommendations. (a) FDA may refuse to provide written...

  13. 25 CFR 135.23 - Refusal of water delivery.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 25 Indians 1 2012-04-01 2011-04-01 true Refusal of water delivery. 135.23 Section 135.23 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR FINANCIAL ACTIVITIES CONSTRUCTION ASSESSMENTS, CROW... District § 135.23 Refusal of water delivery. The right is reserved to refuse the delivery of water to...

  14. 25 CFR 135.23 - Refusal of water delivery.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 25 Indians 1 2011-04-01 2011-04-01 false Refusal of water delivery. 135.23 Section 135.23 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR FINANCIAL ACTIVITIES CONSTRUCTION ASSESSMENTS, CROW... District § 135.23 Refusal of water delivery. The right is reserved to refuse the delivery of water to...

  15. 25 CFR 135.6 - Refusal of water delivery.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 25 Indians 1 2011-04-01 2011-04-01 false Refusal of water delivery. 135.6 Section 135.6 Indians... INDIAN IRRIGATION PROJECT Charges Assessed Against Irrigation District Lands § 135.6 Refusal of water delivery. The right is reserved to the United States to refuse the delivery of water to each of the...

  16. 25 CFR 135.23 - Refusal of water delivery.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false Refusal of water delivery. 135.23 Section 135.23 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR FINANCIAL ACTIVITIES CONSTRUCTION ASSESSMENTS, CROW... District § 135.23 Refusal of water delivery. The right is reserved to refuse the delivery of water to...

  17. 25 CFR 135.6 - Refusal of water delivery.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 25 Indians 1 2012-04-01 2011-04-01 true Refusal of water delivery. 135.6 Section 135.6 Indians... INDIAN IRRIGATION PROJECT Charges Assessed Against Irrigation District Lands § 135.6 Refusal of water delivery. The right is reserved to the United States to refuse the delivery of water to each of the...

  18. 25 CFR 135.6 - Refusal of water delivery.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false Refusal of water delivery. 135.6 Section 135.6 Indians... INDIAN IRRIGATION PROJECT Charges Assessed Against Irrigation District Lands § 135.6 Refusal of water delivery. The right is reserved to the United States to refuse the delivery of water to each of the...

  19. The economic production of alcohol fuels from coal-derived synthesis gas

    SciTech Connect

    Kugler, E.L.; Dadyburjor, D.B.; Yang, R.Y.K.

    1995-12-31

    The objectives of this project are to discover, (1) study and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas. Specifically, alternative methods of preparing catalysts are to be investigated, and novel catalysts, including sulfur-tolerant ones, are to be pursued. (Task 1); (2) explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. (Task 1); (3) simulate by computer the most energy efficient and economically efficient process for converting coal to energy, with primary focus on converting syngas to fuel alcohols. (Task 2); (4) develop on the bench scale the best holistic combination of chemistry, catalyst, reactor and total process configuration integrated with the overall coal conversion process to achieve economic optimization for the conversion of syngas to liquid products within the framework of achieving the maximum cost effective transformation of coal to energy equivalents. (Tasks 1 and 2); and (5) evaluate the combustion, emission and performance characteristics of fuel alcohols and blends of alcohols with petroleum-based fuels. (Task 2)

  20. Nanochemistry-derived Bi2WO6 nanostructures: towards production of sustainable chemicals and fuels induced by visible light.

    PubMed

    Zhang, Nan; Ciriminna, Rosaria; Pagliaro, Mario; Xu, Yi-Jun

    2014-08-07

    Low cost and easily made bismuth tungstate (Bi2WO6) could be one of the key technologies to make chemicals and fuels from biomass, atmospheric carbon dioxide and water at low cost using solar radiation as an energy source. Its narrow band gap (2.8 eV) enables ideal visible light (λ > 400 nm) absorption. Yet, it is the material's shape, namely the superstructure morphology wisely created via a nanochemistry approach, which leads to better electron-hole separation and much higher photoactivity. Recent results coupled to the versatile photochemistry of this readily available semiconductor suggest that the practical application of nanochemistry-derived Bi2WO6 nanostructures for the synthesis of value-added fine chemicals and fuel production is possible. We describe progress in this important field of chemical research from a nanochemistry viewpoint, and identify opportunities for further progress.

  1. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  2. REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS

    SciTech Connect

    Paul Chin; Xiaolei Sun; George W. Roberts; Amornmart Sirijarhuphan; Sourabh Pansare; James G. Goodwin Jr; Richard W. Rice; James J. Spivey

    2005-06-01

    Hydrocarbon fuels must be reformed in a series of steps to provide hydrogen for use in proton exchange membrane fuel cells (PEMFCs). Preferential oxidation (PROX) is one method to reduce the CO concentration to less than 10 ppm in the presence of {approx}40% H{sub 2}, CO{sub 2}, and steam. This will prevent CO poisoning of the PEMFC anode. Structured supports, such as ceramic monoliths, can be used for the PROX reaction. Alternatively, metal foams offer a number of advantages over the traditional ceramic monolith.

  3. Preliminary assessment of systems for deriving liquid and gaseous fuels from waste or grown organics

    NASA Technical Reports Server (NTRS)

    Graham, R. W.; Reynolds, T. W.; Hsu, Y. Y.

    1976-01-01

    The overall feasibility of the chemical conversion of waste or grown organic matter to fuel is examined from the technical, economic, and social viewpoints. The energy contribution from a system that uses waste and grown organic feedstocks is estimated as 4 to 12 percent of our current energy consumption. Estimates of today's market prices for these fuels are included. Economic and social issues are as important as technology in determining the feasibility of such a proposal. An orderly program of development and demonstration is recommended to provide reliable data for an assessment of the viability of the proposal.

  4. Children of divorce: the differential diagnosis of contact refusal.

    PubMed

    Freeman, Bradley W

    2011-07-01

    Contact refusal is a common phenomenon that can occur during the course of, or after, divorce, which affects the relationship between a child and the parent. This article defines the concept of contact refusal and discusses the importance of its recognition. The concept is further narrowed to focus on the child as the one refusing contact, not the parent, which can happen as well. Various types of contact refusals are illustrated in the article through clinical vignettes, and an approach to categorizing the various types of contact refusal is presented.

  5. Pd/activated carbon sorbents for mid-temperature capture of mercury from coal-derived fuel gas.

    PubMed

    Li, Dekui; Han, Jieru; Han, Lina; Wang, Jiancheng; Chang, Liping

    2014-07-01

    Higher concentrations of Hg can be emitted from coal pyrolysis or gasification than from coal combustion, especially elemental Hg. Highly efficient Hg removal technology from coal-derived fuel gas is thus of great importance. Based on the very excellent Hg removal ability of Pd and the high adsorption abilities of activated carbon (AC) for H₂S and Hg, a series of Pd/AC sorbents was prepared by using pore volume impregnation, and their performance in capturing Hg and H₂S from coal-derived fuel gas was investigated using a laboratory-scale fixed-bed reactor. The effects of loading amount, reaction temperature and reaction atmosphere on Hg removal from coal-derived fuel gas were studied. The sorbents were characterized by N₂ adsorption, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results indicated that the efficiency of Hg removal increased with the increasing of Pd loading amount, but the effective utilization rate of the active component Pd decreased significantly at the same time. High temperature had a negative influence on the Hg removal. The efficiency of Hg removal in the N₂-H₂S-H₂-CO-Hg atmosphere (simulated coal gas) was higher than that in N₂-H₂S-Hg and N₂-Hg atmospheres, which showed that H₂ and CO, with their reducing capacity, could benefit promote the removal of Hg. The XPS results suggested that there were two different ways of capturing Hg over sorbents in N₂-H₂S-Hg and N₂-Hg atmospheres.

  6. Deriving In-Use PHEV Fuel Economy Predictions from Standardized Test Cycle Results

    SciTech Connect

    John Smart; Richard "Barney" Carlson; Jeff Gonder; Aaron Brooker

    2009-09-01

    Plug-in hybrid electric vehicles (PHEVs) have potential to reduce or eliminate the U.S. dependence on foreign oil. Quantifying the amount of petroleum each uses, however, is challenging. To estimate in-use fuel economy for conventional vehicles the Environmental Protection Agency (EPA) conducts chassis dynamometer tests on standard historic drive cycles and then adjusts the resulting “raw” fuel economy measurements downward. Various publications, such as the forthcoming update to the SAE J1711 recommended practice for PHEV fuel economy testing, address the challenges of applying standard test procedures to PHEVs. This paper explores the issue of how to apply an adjustment method to such “raw” PHEV dynamometer test results in order to more closely estimate the in-use fuel and electricity consumption characteristics of these vehicles. The paper discusses two possible adjustment methods, and evaluates one method by applying it to dynamometer data and comparing the result to in-use fleet data (on an aftermarket conversion PHEV). The paper will also present the methodologies used to collect the data needed for this comparison.

  7. Fuel and lubricant additives from acid treated mixtures of vegetable oil derived amides and esters

    SciTech Connect

    Bonazza, B.R.; Devault, A.N.

    1981-05-26

    Vegetable oils such as corn oil, peanut oil, and soy oil are reacted with polyamines to form a mixture containing amides, imides, half esters, and glycerol with subsequent treatment with a strong acid such as sulfonic acid to produce a product mix that has good detergent properties in fuels and lubricants.

  8. Biomass-derived Lignin to Jet Fuel Range Hydrocarbons via Aqueous Phase Hydrodeoxygenation

    SciTech Connect

    Wang, Hongliang; Ruan, Hao; Pei, Haisheng; Wang, Huamin; Chen, Xiaowen; Tucker, Melvin P.; Cort, John R.; Yang, Bin

    2015-09-14

    A catalytic process, involving the hydrodeoxygenation (HDO) of the dilute alkali extracted corn stover lignin catalysed by noble metal catalyst (Ru/Al2O3) and acidic zeolite (H+-Y), to produce lignin-substructure-based hydrocarbons (C7-C18), primarily C12-C18 cyclic structure hydrocarbons in the jet fuel range, was demonstrated.

  9. A mineral magnetic investigation into fuel derived deposits from Old Scatness Broch, Shetland

    NASA Astrophysics Data System (ADS)

    Dewar, I.; Batt, C. M.; Peters, C.

    There is increasing interest in the use of measurements of magnetic mineralogy to answer archaeological questions (e.g. R. Thompson, F. Oldfield, Environmental Magnetism, Allen & Unwin, London, 1986, p. 83; The IRM Quarterly 9(4) (2000) 2; Physics and Chemistry of the Earth (A) 25(5) (2000) 455; Archaeological Prospection 8(4) (2001) 227). The aim of the research presented here is to explain the distinctive magnetic signatures which characterise the fuel ash deposits encountered during excavation at Old Scatness Broch, Shetland, and to attempt to identify fuel sources used at the site by comparison with modern analogues. Archaeological deposits thought to contain fuel ash, from a variety of contexts and periods within the site were sampled and were supplemented by samples of modern fuel sources, including a variety of forms of peat, turf and wood. Magnetic investigations included mass specific magnetic susceptibility, high temperature variation in susceptibility, fractional conversion and laboratory imparted remanences. The archaeological deposits are shown to comprise complex mixtures of minerals with different thermal histories. Whilst most of the archaeological ash deposits were closest in magnetic characteristics to modern turf ash, some appeared to have close parallels with furnace residues obtained from reconstruction iron-smelting. The

  10. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO

  11. Municipal solid waste combustion: Fuel testing and characterization

    SciTech Connect

    Bushnell, D.J.; Canova, J.H.; Dadkhah-Nikoo, A.

    1990-10-01

    The objective of this study is to screen and characterize potential biomass fuels from waste streams. This will be accomplished by determining the types of pollutants produced while burning selected municipal waste, i.e., commercial mixed waste paper residential (curbside) mixed waste paper, and refuse derived fuel. These materials will be fired alone and in combination with wood, equal parts by weight. The data from these experiments could be utilized to size pollution control equipment required to meet emission standards. This document provides detailed descriptions of the testing methods and evaluation procedures used in the combustion testing and characterization project. The fuel samples will be examined thoroughly from the raw form to the exhaust emissions produced during the combustion test of a densified sample.

  12. Refuse-to-energy is not dead

    SciTech Connect

    Gould, R.N.

    1988-11-01

    As noted in this paper, GAA (Government Advisory Associates) recently completed its fourth national survey of the refuse-to-energy business in the U.S. A total of 368 facilities were examined in all stages of project development. Contrary to the opinion of some doomsayers, refuse-to-energy in the U.S. is still a growing industry. Nevertheless, there has been some retrenchment in the past year due to political and environmental concerns, some legitimate and others unfounded. There are currently significant uncertainties in federal and state regulatory policies regarding air emissions and ash disposal which have led a number of private and public developers to hold off on planned new facilities. In any event, the long-term outlook for the industry is good, given the few disposal options available for solid waste planners faced with rising landfill costs and the prospect of few new landfills being sited.

  13. Hydrocyclone separation of coal refuse fines

    SciTech Connect

    Clendenin, H.B.

    1983-12-01

    The following conclusions are drawn from the research reported herein: (1) The experimental hydrocyclone apparatus, designed to allow control of the vortex finder length, overflow diameter, underflow diameter, cone angle, and inlet flow rate, is a suitable system for determining the effect of each variable stated on the washing of coal refuse fines. (2) Color-coded spheres of different diameters and specific gravities correlate well as a model of coal refuse fines in the range of 0.0937 inches and larger, insofar as their size and density responding to hydrocyclone separation. (3) Data taken on two experimental systems, using coal refuse fines samples from a gob pile, verify the dimensional analysis by their good correlation. The data collected can be assumed as a guide to geometrically similar hydrocyclones of different sizes. (4) The concentration of solids used during this work was not investigated but is considered a variable of importance in application. (5) Using the experimental hydrocyclone system and spheres along with the concepts of dimensional analysis and similitude, design curves can be generated showing the effect of each parameter on specific gravity separation. (6) Based on the guidance of the design curves, and confirmed by experimentation, a hydrocyclone configuration is recommended for separation of coal refuse fines. (7) Small changes in the vortex finder length causes significant changes in the specific gravity of solids reporting to the overflow. (8) Gob should be pre-screened to remove clay. At that time the undersize material should be sent to a settling pond to be handled as settling pond fines if handled any more at all. 22 references, 44 figures, 16 tables.

  14. Conscientious refusal in healthcare: the Swedish solution.

    PubMed

    Munthe, Christian

    2017-04-01

    The Swedish solution to the legal handling of professional conscientious refusal in healthcare is described. No legal right to conscientious refusal for any profession or class of professional tasks exists in Sweden, regardless of the religious or moral background of the objection. The background of this can be found in strong convictions about the importance of public service provision and related civic duties, and ideals about rule of law, equality and non-discrimination. Employee's requests to change work tasks are handled on a case-by-case basis within the frames of labour law, ensuring full voluntariness, and also employer's privilege regarding the organisation and direction of work, and duties of public institutions to provide services. Two complicating aspects of this solution related to the inclusion of 'alternative medical' service providers in a national health service, and professional insistence on conscientious refusal rights to accept legalised assisted dying are discussed. The latter is found to undermine the pragmatic reasons behind recent attempts by prolife groups to challenge the Swedish solution related to legal abortion in courts.

  15. Exploring Sustainable Rocket Fuels: [Imidazolyl-Amine-BH2](+)-Cation-Based Ionic Liquids as Replacements for Toxic Hydrazine Derivatives.

    PubMed

    Huang, Shi; Qi, Xiujuan; Zhang, Wenquan; Liu, Tianlin; Zhang, Qinghua

    2015-12-01

    The application of hypergolic ionic liquids as propellant fuels is a newly emerging area in the fields of chemistry and propulsion science. Herein, a new class of [imidazolyl-amine-BH2](+)-cation-based ionic liquids, which included fuel-rich anions, such as dicyanamide (N(CN)2(-)) and cyanoborohydride (BH3CN(-)) anions, were synthesized and characterized. As expected, all of the ionic liquids exhibited spontaneous combustion upon contact with the oxidizer 100 % HNO3. The densities of these ionic liquids varied from 0.99-1.12 g cm(-3), and the heats of formation, predicted based on Gaussian 09 calculations, were between -707.7 and 241.8 kJ mol(-1). Among them, the salt of compound 5, that is, (1-allyl-1H-imidazole-3-yl)-(trimethylamine)-dihydroboronium dicyanamide, exhibited the lowest viscosity (168 MPa s), good thermal properties (Tg <-70 °C, Td >130 °C), and the shortest ignition-delay time (18 ms) with 100 % HNO3. These ionic fuels, as "green" replacements for toxic hydrazine-derivatives, may have potential applications as bipropellant formulations.

  16. Production of Jet Fuels from Coal-Derived Liquids. Volume 8. Heteroatom Removal by Catalytic Processing

    DTIC Science & Technology

    1989-01-01

    distillation profiles of JP-4, JP-8, and GPGP tar oil stream ....................................... 7 2 Autoclave system used during tar oil upgrading...Table Title Page 1 Properties of JP-4, JP-8, and JP-8X aviation turbine fuels .... 3 2 Results of the elemental analyses of the GPGP liquid by...product streams ............................................ 4 3 Proton and carbon-13 NMR data for GPGP liquid streams ......... 5 4 Results of ASTM D86

  17. Preface to the Issue: Transformations of Biomass and its Derivatives to Fuels and Chemicals

    DOE PAGES

    Lin, Hongfei; Biddinger, Elizabeth J.; Mukarakate, Calvin; ...

    2016-07-01

    The research activities on biofuels and bio-products have been growing steadily regardless the volatility of the crude oil price in the past decade. The major driver is the imperative need of tackling the challenge of climate change. With the low carbon footprints, fuels and chemicals produced from renewable biomass resources, as the replacement of their petroleum counterparts, can contribute significantly on carbon emission reduction.

  18. High-Temperature Desulfurization of Heavy Fuel-Derived Reformate Gas Streams for SOFC Applications

    NASA Technical Reports Server (NTRS)

    Flytzani-Stephanopoulos, Maria; Surgenor, Angela D.

    2007-01-01

    Desulfurization of the hot reformate gas produced by catalytic partial oxidation or autothermal reforming of heavy fuels, such as JP-8 and jet fuels, is required prior to using the gas in a solid oxide fuel cell (SOFC). Development of suitable sorbent materials involves the identification of sorbents with favorable sulfidation equilibria, good kinetics, and high structural stability and regenerability at the SOFC operating temperatures (650 to 800 C). Over the last two decades, a major barrier to the development of regenerable desulfurization sorbents has been the gradual loss of sorbent performance in cyclic sulfidation and regeneration at such high temperatures. Mixed oxide compositions based on ceria were examined in this work as regenerable sorbents in simulated reformate gas mixtures and temperatures greater than 650 C. Regeneration was carried out with dilute oxygen streams. We have shown that under oxidative regeneration conditions, high regeneration space velocities (greater than 80,000 h(sup -1)) can be used to suppress sulfate formation and shorten the total time required for sorbent regeneration. A major finding of this work is that the surface of ceria and lanthanan sorbents can be sulfided and regenerated completely, independent of the underlying bulk sorbent. This is due to reversible adsorption of H2S on the surface of these sorbents even at temperatures as high as 800 C. La-rich cerium oxide formulations are excellent for application to regenerative H2S removal from reformate gas streams at 650 to 800 C. These results create new opportunities for compact sorber/regenerator reactor designs to meet the requirements of solid oxide fuel cell systems at any scale.

  19. Characterization of char derived from various types of solid wastes from the standpoint of fuel recovery and pretreatment before landfilling.

    PubMed

    Hwang, I H; Matsuto, T; Tanaka, N; Sasaki, Y; Tanaami, K

    2007-01-01

    Carbonization is a kind of pyrolysis process to produce char from organic materials under an inert atmosphere. In this work, chars derived from various solid wastes were characterized from the standpoint of fuel recovery and pretreatment of waste before landfilling. Sixteen kinds of municipal and industrial solid wastes such as residential combustible wastes, non-combustible wastes, bulky wastes, construction and demolition wastes, auto shredder residue, and sludges were carbonized at 500 degrees C for 1h under nitrogen atmosphere. In order to evaluate the quality of char as fuel, proximate analysis and heating value were examined. The composition of raw waste had a significant influence on the quality of produced char. The higher the ratio of woody biomass in waste, the higher heating value of char produced. Moreover, an equation to estimate heating value of char was developed by using the weight fraction of fixed carbon and volatile matter in char. De-ashing and chlorine removal were performed to improve the quality of char. The pulverization and sieving method seems to be effective for separation of incombustibles such as metal rather than ash. Most char met a 0.5 wt% chlorine criterion for utilization as fuel in a shaft blast furnace after it was subjected to repeated water-washing. Carbonization could remove a considerable amount of organic matter from raw waste. In addition, the leaching of heavy metals such as chrome, cadmium, and lead appears to be significantly suppressed by carbonization regardless of the type of raw waste. From these results, carbonization could be considered as a pretreatment method for waste before landfilling, as well as for fuel recovery.

  20. Zinc isotopic composition of particulate matter generated during the combustion of coal and coal + tire-derived fuels.

    PubMed

    Borrok, David M; Gieré, Reto; Ren, Minghua; Landa, Edward R

    2010-12-01

    Atmospheric Zn emissions from the burning of coal and tire-derived fuel (TDF) for power generation can be considerable. In an effort to lay the foundation for tracking these contributions, we evaluated the Zn isotopes of coal, a mixture of 95 wt % coal + 5 wt % TDF, and the particulate matter (PM) derived from their combustion in a power-generating plant. The average Zn concentrations and δ(66)Zn were 36 mg/kg and 183 mg/kg and +0.24‰ and +0.13‰ for the coal and coal + TDF, respectively. The δ(66)Zn of the PM sequestered in the cyclone-type mechanical separator was the lightest measured, -0.48‰ for coal and -0.81‰ for coal+TDF. The δ(66)Zn of the PM from the electrostatic precipitator showed a slight enrichment in the heavier Zn isotopes relative to the starting material. PM collected from the stack had the heaviest δ(66)Zn in the system, +0.63‰ and +0.50‰ for the coal and coal + TDF, respectively. Initial fractionation during the generation of a Zn-rich vapor is followed by temperature-dependent fractionation as Zn condenses onto the PM. The isotopic changes of the two fuel types are similar, suggesting that their inherent chemical differences have only a secondary impact on the isotopic fractionation process.

  1. Zinc isotopic composition of particulate matter generated during the combustion of coal and coal + tire-derived fuels

    USGS Publications Warehouse

    Borrok, D.M.; Gieré, R.; Ren, M.; Landa, E.R.

    2010-01-01

    Atmospheric Zn emissions from the burning of coal and tire-derived fuel (TDF) for power generation can be considerable. In an effort to lay the foundation for tracking these contributions, we evaluated the Zn isotopes of coal, a mixture of 95 wt % coal + 5 wt % TDF, and the particulate matter (PM) derived from their combustion in a power-generating plant. The average Zn concentrations and δ(66)Zn were 36 mg/kg and 183 mg/kg and +0.24‰ and +0.13‰ for the coal and coal + TDF, respectively. The δ(66)Zn of the PM sequestered in the cyclone-type mechanical separator was the lightest measured, -0.48‰ for coal and -0.81‰ for coal+TDF. The δ(66)Zn of the PM from the electrostatic precipitator showed a slight enrichment in the heavier Zn isotopes relative to the starting material. PM collected from the stack had the heaviest δ(66)Zn in the system, +0.63‰ and +0.50‰ for the coal and coal + TDF, respectively. Initial fractionation during the generation of a Zn-rich vapor is followed by temperature-dependent fractionation as Zn condenses onto the PM. The isotopic changes of the two fuel types are similar, suggesting that their inherent chemical differences have only a secondary impact on the isotopic fractionation process.

  2. 40 CFR Table 3 to Subpart Cb of... - Municipal Waste Combustor Operating Guidelines

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...-derived fuel mixed fuel-fired combustor 150 4 Spreader stoker coal/refuse-derived fuel mixed fuel-fired... conversion 250 c 24 Spreader stoker fixed floor refuse-derived fuel-fired combustor/100 percent coal...

  3. Production of biomass fuel for resource recovery: Trash recycling in Dade County, Florida

    SciTech Connect

    Mauriello, P.J.; Brooks, K.G.

    1997-12-01

    Dade County, Florida has been in the forefront of resources recovery from municipal solid waste since the early 1980`s. The County completed its 3,000 tons per day (six days per week) refuse derived fuel waste-to-energy facility in 1982. The Resources Recovery facility is operated under a long-term agreement with Montenay-Dade, Ltd. The trash processing capability of this facility was upgraded in 1997 to process 860 tons per day (six days per week) of trash into a biomass fuel which is used off-site to produce electrical energy. Under current Florida law, facilities like trash-to-fuel that produce alternative clean-burning fuels for the production of energy may receive credit for up to one-half of the state`s 30 percent waste reduction goal.

  4. DESCRIPTIVE ANALYSES OF PEDIATRIC FOOD REFUSAL AND ACCEPTANCE

    PubMed Central

    Borrero, Carrie S.W; Woods, Julia N; Borrero, John C; Masler, Elizabeth A; Lesser, Aaron D

    2010-01-01

    Functional analyses of inappropriate mealtime behavior typically include conditions to determine if the contingent delivery of attention, tangible items, or escape reinforce food refusal. In the current investigation, descriptive analyses were conducted for 25 children who had been admitted to a program for the assessment and treatment of food refusal to determine if the consequences commonly delivered during functional analyses were observed during parent-conducted meals. The conditional probabilities for the delivery of attention, tangible items, and escape following food refusal and acceptance were compared to the unconditional probabilities of each event. Results showed that attention and escape most frequently followed refusal and differed depending on the topography of refusal. Implications for further evaluations of food refusal using similar methods are discussed. PMID:20808496

  5. The Comparison of Hydrotreated Vegetable Oils With Respect to Petroleum Derived Fuels and the Effects of Transient Plasma Ignition in a Compression-Ignition Engine

    DTIC Science & Technology

    2012-09-01

    algae and camelina derived biofuels as well as the effects of Transient Plasma Ignition in a Compression-Ignition Engine. Testing was conducted for...Hydrotreated Renewable Diesel, algae , and benchmarked against F-76 and Diesel #2 fuels as well as Hydrotreated Renewable Jet, camelina, benchmarked...analysis were performed at each matrix point. The algae and camelina fuels averaged 1.4 Crank Angle Degrees earlier ignition, 2 Crank Angle Degrees

  6. Combustion studies of coal-derived solid fuels. Part IV. Correlation of ignition temperatures from thermogravimetry and free-floating experiments

    USGS Publications Warehouse

    Rostam-Abadi, M.; DeBarr, J.A.; Chen, W.T.

    1992-01-01

    The usefulness of TG as an efficient and practical method to characterize the combustion properties of fuels used in large-scale combustors is of considerable interest. Relative ignition temperatures of a lignite, an anthracite, a bituminous coal and three chars derived from this coal were measured by a free-floating technique. These temperatures were correlated with those estimated from TG burning profiles of the fuels. ?? 1992.

  7. IOW refuse incinerator to warm prisoners

    SciTech Connect

    Mason, D.

    1981-09-22

    Talks are underway for the possible construction of an incinerator on the Isle of Wight that would serve the prisons with heat. Construction would start in January 1985 and after a six-month trial period, the incinerator would be in full operation by 1987. Annual saving in energy terms would be as much as 1 million gallons of oil a year if a local hospital would also be linked to the heating scheme. The estimated cost of processing refuse by the incinerator is 7 pounds/tonne as opposed to the present 6 pounds/tonne by landfill disposal.

  8. Conscientious refusals and reason-giving.

    PubMed

    Marsh, Jason

    2014-07-01

    Some philosophers have argued for what I call the reason-giving requirement for conscientious refusal in reproductive healthcare. According to this requirement, healthcare practitioners who conscientiously object to administering standard forms of treatment must have arguments to back up their conscience, arguments that are purely public in character. I argue that such a requirement, though attractive in some ways, faces an overlooked epistemic problem: it is either too easy or too difficult to satisfy in standard cases. I close by briefly considering whether a version of the reason-giving requirement can be salvaged despite this important difficulty.

  9. Electrochemical Coupling of Biomass-Derived Acids: New C8 Platforms for Renewable Polymers and Fuels.

    PubMed

    Wu, Linglin; Mascal, Mark; Farmer, Thomas J; Arnaud, Sacha Pérocheau; Wong Chang, Maria-Angelica

    2017-01-10

    Electrolysis of biomass-derived carbonyl compounds is an alternative to condensation chemistry for supplying products with chain length >C6 for biofuels and renewable materials production. Kolbe coupling of biomass-derived levulinic acid is used to obtain 2,7-octanedione, a new platform molecule only two low process-intensity steps removed from raw biomass. Hydrogenation to 2,7-octanediol provides a chiral secondary diol largely unknown to polymer chemistry, whereas intramolecular aldol condensation followed by hydrogenation yields branched cycloalkanes suitable for use as high-octane, cellulosic gasoline. Analogous electrolysis of an itaconic acid-derived methylsuccinic monoester yields a chiral 2,5-dimethyladipic acid diester, another underutilized monomer owing to lack of availability.

  10. Electrochemical Coupling of Biomass‐Derived Acids: New C8 Platforms for Renewable Polymers and Fuels

    PubMed Central

    Wu, Linglin; Farmer, Thomas J.; Arnaud, Sacha Pérocheau; Wong Chang, Maria‐Angelica

    2016-01-01

    Abstract Electrolysis of biomass‐derived carbonyl compounds is an alternative to condensation chemistry for supplying products with chain length >C6 for biofuels and renewable materials production. Kolbe coupling of biomass‐derived levulinic acid is used to obtain 2,7‐octanedione, a new platform molecule only two low process‐intensity steps removed from raw biomass. Hydrogenation to 2,7‐octanediol provides a chiral secondary diol largely unknown to polymer chemistry, whereas intramolecular aldol condensation followed by hydrogenation yields branched cycloalkanes suitable for use as high‐octane, cellulosic gasoline. Analogous electrolysis of an itaconic acid‐derived methylsuccinic monoester yields a chiral 2,5‐dimethyladipic acid diester, another underutilized monomer owing to lack of availability. PMID:27873475

  11. Flame blowout and pollutant emissions in vitiated combustion of conventional and bio-derived fuels

    NASA Astrophysics Data System (ADS)

    Singh, Bhupinder

    The widening gap between the demand and supply of fossil fuels has catalyzed the exploration of alternative sources of energy. Interest in the power, water extraction and refrigeration (PoWER) cycle, proposed by the University of Florida, as well as the desirability of using biofuels in distributed generation systems, has motivated the exploration of biofuel vitiated combustion. The PoWER cycle is a novel engine cycle concept that utilizes vitiation of the air stream with externally-cooled recirculated exhaust gases at an intermediate pressure in a semi-closed cycle (SCC) loop, lowering the overall temperature of combustion. It has several advantages including fuel flexibility, reduced air flow, lower flame temperature, compactness, high efficiency at full and part load, and low emissions. Since the core engine air stream is vitiated with the externally cooled exhaust gas recirculation (EGR) stream, there is an inherent reduction in the combustion stability for a PoWER engine. The effect of EGR flow and temperature on combustion blowout stability and emissions during vitiated biofuel combustion has been characterized. The vitiated combustion performance of biofuels methyl butanoate, dimethyl ether, and ethanol have been compared with n-heptane, and varying compositions of syngas with methane fuel. In addition, at high levels of EGR a sharp reduction in the flame luminosity has been observed in our experimental tests, indicating the onset of flameless combustion. This drop in luminosity may be a result of inhibition of processes leading to the formation of radiative soot particles. One of the objectives of this study is finding the effect of EGR on soot formation, with the ultimate objective of being able to predict the boundaries of flameless combustion. Detailed chemical kinetic simulations were performed using a constant-pressure continuously stirred tank reactor (CSTR) network model developed using the Cantera combustion code, implemented in C++. Results have

  12. Delta13C values of grasses as a novel indicator of pollution by fossil-fuel-derived greenhouse gas CO2 in urban areas.

    PubMed

    Lichtfouse, Eric; Lichtfouse, Michel; Jaffrézic, Anne

    2003-01-01

    A novel fossil fuel pollution indicator based on the 13C/12C isotopic composition of plants has been designed. This bioindicator is a promising tool for future mapping of the sequestration of fossil fuel CO2 into urban vegetation. Theoretically, plants growing in fossil-fuel-CO2-contaminated areas, such as major cities, industrial centers, and highway borders, should assimilate a mixture of global atmospheric CO2 of delta13C value of -8.02 per thousand and of fossil fuel CO2 of average delta13C value of -27.28 per thousand. This isotopic difference should, thus, be recorded in plant carbon. Indeed, this study reveals that grasses growing near a major highway in Paris, France, have strikingly depleted delta13C values, averaging at -35.08 per thousand, versus rural grasses that show an average delta13C value of -30.59 per thousand. A simple mixing model was used to calculate the contributions of fossil-fuel-derived CO2 to the plant tissue. Calculation based on contaminated and noncontaminated isotopic end members shows that urban grasses assimilate up to 29.1% of fossil-fuel-CO2-derived carbon in their tissues. The 13C isotopic composition of grasses thus represents a promising new tool for the study of the impact of fossil fuel CO2 in major cities.

  13. Effects of coal-derived trace species on the performance of carbonate fuel cells

    SciTech Connect

    Pigeaud, A. ); Wilemski, G. )

    1992-01-01

    NH{sub 3} Cd, Hg, and Sn have no noticeable effects on carbonate fuel cell performance. Zn and Pb (the latter in the presence of Se) had minor effects, while the interactions of H{sub 2}S, HC{ell}, H{sub 2}Se and As are more significant. Because H{sub 2}S had already been extensively investigated earlier by various groups, the focus in this study was centered on the latter three elements. It appears that HC{ell}, H{sub 2}Se, and As need to be limited to sub-ppM levels in a manner similar to H{sub 2}S. These findings, of course, should be considered qualitative because they were obtained in single, isothermally operated, bench-sale cells, and are applicable for individual contaminants.

  14. Effects of coal-derived trace species on the performance of carbonate fuel cells

    SciTech Connect

    Pigeaud, A.; Wilemski, G.

    1992-09-01

    NH{sub 3} Cd, Hg, and Sn have no noticeable effects on carbonate fuel cell performance. Zn and Pb (the latter in the presence of Se) had minor effects, while the interactions of H{sub 2}S, HC{ell}, H{sub 2}Se and As are more significant. Because H{sub 2}S had already been extensively investigated earlier by various groups, the focus in this study was centered on the latter three elements. It appears that HC{ell}, H{sub 2}Se, and As need to be limited to sub-ppM levels in a manner similar to H{sub 2}S. These findings, of course, should be considered qualitative because they were obtained in single, isothermally operated, bench-sale cells, and are applicable for individual contaminants.

  15. DESIGNING AND OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION AND COFIRING SAWDUST WITH COAL AT ALBRIGHT GENERATING STATION

    SciTech Connect

    K. Payette; D. Tillman

    2004-06-01

    During the period July 1, 2000-March 31, 2004, Allegheny Energy Supply Co., LLC (Allegheny) conducted an extensive demonstration of woody biomass cofiring at its Willow Island and Albright Generating Stations. This demonstration, cofunded by USDOE and Allegheny, and supported by the Biomass Interest Group (BIG) of EPRI, evaluated the impacts of sawdust cofiring in both cyclone boilers and tangentially-fired pulverized coal boilers. The cofiring in the cyclone boiler--Willow Island Generating Station Unit No.2--evaluated the impacts of sawdust alone, and sawdust blended with tire-derived fuel. The biomass was blended with the coal on its way to the combustion system. The cofiring in the pulverized coal boiler--Albright Generating Station--evaluated the impact of cofiring on emissions of oxides of nitrogen (NO{sub x}) when the sawdust was injected separately into the furnace. The demonstration of woody biomass cofiring involved design, construction, and testing at each site. The results addressed impacts associated with operational issues--capacity, efficiency, and operability--as well as formation and control of airborne emissions such as NO{sub x}, sulfur dioxide (SO{sub 2}2), opacity, and mercury. The results of this extensive program are detailed in this report.

  16. Chemicals derived from pyrolysis bio-oils as antioxidants in fuels and lubricants

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Softwood and hardwood lignins and hardwood were pyrolyzed to produce bio-oils to produce lignin-derived bio-oils of which phenols were the major component. These bio-oils were extracted with alkali to yield a range of lignin-related phenols having molecular weights (MWs) from 110 to 344. When tested...

  17. Particulate emissions from a stationary engine fueled with ultra-low-sulfur diesel and waste-cooking-oil-derived biodiesel.

    PubMed

    Betha, Raghu; Balasubramanian, Rajasekhar

    2011-10-01

    Stationary diesel engines, especially diesel generators, are increasingly being used in both developing countries and developed countries because of increased power demand. Emissions from such engines can have adverse effects on the environment and public health. In this study, particulate emissions from a domestic stationary diesel generator running on ultra-low-sulfur diesel (ULSD) and biodiesel derived from waste cooking oil were characterized for different load conditions. Results indicated a reduction in particulate matter (PM) mass and number emissions while switching diesel to biodiesel. With increase in engine load, it was observed that particle mass increased, although total particle counts decreased for all the fuels. The reduction in total number concentration at higher loads was, however, dependent on percentage of biodiesel in the diesel-biodiesel blend. For pure biodiesel (B100), the reduction in PM emissions for full load compared to idle mode was around 9%, whereas for ULSD the reduction was 26%. A large fraction of ultrafine particles (UFPs) was found in the emissions from biodiesel compared to ULSD. Nearly 90% of total particle concentration in biodiesel emissions comprised ultrafine particles. Particle peak diameter shifted from a smaller to a lower diameter with increase in biodiesel percentage in the fuel mixture.

  18. Particulate Emissions from a Stationary Engine Fueled with Ultra-Low-Sulfur Diesel and Waste-Cooking-Oil-Derived Biodiesel.

    PubMed

    Betha, Raghu; Balasubramanian, Rajasekhar

    2011-10-01

    Stationary diesel engines, especially diesel generators, are increasingly being used in both developing countries and developed countries because of increased power demand. Emissions from such engines can have adverse effects on the environment and public health. In this study, particulate emissions from a domestic stationary diesel generator running on ultra-low-sulfur diesel (ULSD) and biodiesel derived from waste cooking oil were characterized for different load conditions. Results indicated a reduction in particulate matter (PM) mass and number emissions while switching diesel to biodiesel. With increase in engine load, it was observed that particle mass increased, although total particle counts decreased for all the fuels. The reduction in total number concentration at higher loads was, however, dependent on percentage of biodiesel in the diesel-biodiesel blend. For pure biodiesel (B100), the reduction in PM emissions for full load compared to idle mode was around 9%, whereas for ULSD the reduction was 26%. A large fraction of ultrafine particles (UFPs) was found in the emissions from biodiesel compared to ULSD. Nearly 90% of total particle concentration in biodiesel emissions comprised ultrafine particles. Particle peak diameter shifted from a smaller to a lower diameter with increase in biodiesel percentage in the fuel mixture. [Box: see text].

  19. Biological Production of a Hydrocarbon Fuel Intermediate Polyhydroxybutyrate (PHB) from a Process Relevant Lignocellulosic Derived Sugar (Poster)

    SciTech Connect

    Wang, W.; Mittal, A.; Mohagheghi, A.; Johnson, D. K.

    2014-04-01

    PHAs are synthesized by many microorganisms to serve as intracellular carbon storage molecules. In some bacterial strains, PHB can account for up to 80% of cell mass. In addition to its application in the packaging sector, PHB also has great potential as an intermediate in the production of hydrocarbon fuels. PHB can be thermally depolymerized and decarboxylated to propene which can be upgraded to hydrocarbon fuels via commercial oligomerization technologies. Cupriavidus necator is the microorganism that has been most extensively studied and used for PHB production on an industrial scale; However the substrates used for producing PHB are mainly fructose, glucose, sucrose, fatty acids, glycerol, etc., which are expensive. In this study, we demonstrate production of PHB from a process relevant lignocellulosic derived sugar stream, i.e., saccharified slurry from pretreated corn stover. The strain was first investigated in shake flasks for its ability to utilize glucose, xylose and acetate. In addition, the strain was also grown on pretreated lignocellulose hydrolyzate slurry and evaluated in terms of cell growth, sugar utilization, PHB accumulation, etc. The mechanism of inhibition in the toxic hydrolysate generated by the pretreatment and saccharification process of biomass, was also studied.

  20. Energy Conversion Alternatives Study (ECAS), General Electric Phase 1. Volume 1: Executive summary. [using coal or coal derived fuels

    NASA Technical Reports Server (NTRS)

    Corman, J. C.

    1976-01-01

    A data base for the comparison of advanced energy conversion systems for utility applications using coal or coal-derived fuels was developed. Estimates of power plant performance (efficiency), capital cost, cost of electricity, natural resource requirements, and environmental intrusion characteristics were made for ten advanced conversion systems. Emphasis was on the energy conversion system in the context of a base loaded utility power plant. All power plant concepts were premised on meeting emission standard requirements. A steam power plant (3500 psig, 1000 F) with a conventional coal-burning furnace-boiler was analyzed as a basis for comparison. Combined cycle gas/steam turbine system results indicated competitive efficiency and a lower cost of electricity compared to the reference steam plant. The Open-Cycle MHD system results indicated the potential for significantly higher efficiency than the reference steam plant but with a higher cost of electricity.

  1. Combustion-derived substances in deep basins of Puget Sound: historical inputs from fossil fuel and biomass combustion.

    PubMed

    Kuo, Li-Jung; Louchouarn, Patrick; Herbert, Bruce E; Brandenberger, Jill M; Wade, Terry L; Crecelius, Eric

    2011-04-01

    Reconstructions of 250 years historical inputs of two distinct types of black carbon (soot/graphitic black carbon (GBC) and char-BC) were conducted on sediment cores from two basins of the Puget Sound, WA. Signatures of polycyclic aromatic hydrocarbons (PAHs) were also used to support the historical reconstructions of BC to this system. Down-core maxima in GBC and combustion-derived PAHs occurred in the 1940s in the cores from the Puget Sound Main Basin, whereas in Hood Canal such peak was observed in the 1970s, showing basin-specific differences in inputs of combustion byproducts. This system showed relatively higher inputs from softwood combustion than the northeastern U.S. The historical variations in char-BC concentrations were consistent with shifts in climate indices, suggesting an influence of climate oscillations on wildfire events. Environmental loading of combustion byproducts thus appears as a complex function of urbanization, fuel usage, combustion technology, environmental policies, and climate conditions.

  2. Glass and glass-derivative seals for use in energy-efficient fuel cells and lamps

    SciTech Connect

    Scott Misture; Arun Varshineya; Matthew Hall; Sylvia DeCarr; Steve Bancheri

    2005-07-28

    For solid oxide fuel cells (SOFC), a series of 18 sealing glasses have been prepared and characterized. From the whole design space, several glasses were ''downselected'' and studied in detail to describe their behaviors in simulated fuel cell environments. One of the glasses was found to outperform all others, including the well-known G18 sealant developed at Pacific Northwest National Laboratory. The new glass composition showed lower bulk electrical conductivity, excellent sealing and wetting behavior when sealing under applied load, and qualitatively superior performance when exposed to wet hydrogen for 800 hours. Traditional melting was used to prepare all of the glasses that were studied in detail. The sol-gel approach was used to synthesize several compositions, but it was found that the glasses crystallized very rapidly during heating, precluding sealing. The glass characterization included measurements of the viscosity and thermal expansion of the glasses, as well as the thermal expansion of the partly crystalline glass ceramics. In addition, the wetting and sintering behavior of all glasses has been measured, as well as the crystallization behavior. The time and temperature at which crystalline phases form from the glasses has been determined for all of the glasses. Each glass ceramic contains at least two crystalline phases, and most of the crystalline phases have been positively identified. The body of fundamental data provides a platform for future developments for high temperature sealants, and the newly-developed glass compositions appear promising for large-scale testing. The second component of the work, focused on seals for higher-temperature discharge lighting, has focused on determining the phase relations in the yttria-alumina-silica system at various silica levels. Functional testing of one of the candidate sealants demonstrated that it performs well in current HID lighting applications. Further testing is required to evaluate its performance

  3. Fine and ultrafine particles generated during fluidized bed combustion of different solid fuels

    SciTech Connect

    Urciuolo, M.; Barone, A.; D'Alessio, A.; Chirone, R.

    2008-12-15

    The paper reports an experimental study carried out with a 110-mm ID fluidized bed combustor focused on the characterization of particulates formation/emission during combustion of coal and non-fossil solid fuels. Fuels included: a bituminous coal, a commercial predried and granulated sludge (GS), a refuse-derived fuel (RDF), and a biomass waste (pine seed shells). Stationary combustion experiments were carried out analyzing the fate of fuel ashes. Fly ashes collected at the combustor exhaust were characterized both in terms of particle size distribution and chemical composition, with respect to both trace and major elements. Tapping-Mode Atomic Force Microscopy (TM-AFM) technique and high-efficiency cyclone-type collector devices were used to characterize the size and morphology of the nanometric-and micronic-size fractions of fly ash emitted at the exhaust respectively. Results showed that during the combustion process: I) the size of the nanometric fraction ranges between 2 and 65 nm; ii) depending on the fuel tested, combustion-assisted attrition or the production of the primary ash particles originally present in the fuel particles, are responsible of fine particle generation. The amount in the fly ash of inorganic compounds is larger for the waste-derived fuels, reflecting the large inherent content of these compounds in the parent fuels.

  4. Comparative techno-economic analysis and process design for indirect liquefaction pathways to distillate-range fuels via biomass-derived oxygenated intermediates upgrading: Liquid Transportation Fuel Production via Biomass-derived Oxygenated Intermediates Upgrading

    SciTech Connect

    Tan, Eric C. D.; Snowden-Swan, Lesley J.; Talmadge, Michael; Dutta, Abhijit; Jones, Susanne; Ramasamy, Karthikeyan K.; Gray, Michel; Dagle, Robert; Padmaperuma, Asanga; Gerber, Mark; Sahir, Asad H.; Tao, Ling; Zhang, Yanan

    2016-09-27

    This paper presents a comparative techno-economic analysis (TEA) of five conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates. The four emerging pathways of interest are compared with one conventional pathway (Fischer-Tropsch) for the production of the hydrocarbon blendstocks. The processing steps of the four emerging pathways include: biomass to syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation. Conversion of biomass-derived syngas to oxygenated intermediates occurs via three different pathways, producing: 1) mixed alcohols over a MoS2 catalyst, 2) mixed oxygenates (a mixture of C2+ oxygenated compounds, predominantly ethanol, acetic acid, acetaldehyde, ethyl acetate) using an Rh-based catalyst, and 3) ethanol from syngas fermentation. This is followed by the conversion of oxygenates/alcohols to fuel-range olefins in two approaches: 1) mixed alcohols/ethanol to 1-butanol rich mixture via Guerbet reaction, followed by alcohol dehydration, oligomerization, and hydrogenation, and 2) mixed oxygenates/ethanol to isobutene rich mixture and followed by oligomerization and hydrogenation. The design features a processing capacity of 2,000 tonnes/day (2,205 short tons) of dry biomass. The minimum fuel selling prices (MFSPs) for the four developing pathways range from $3.40 to $5.04 per gasoline-gallon equivalent (GGE), in 2011 US dollars. Sensitivity studies show that MFSPs can be improved with co-product credits and are comparable to the commercial Fischer-Tropsch benchmark ($3.58/GGE). Overall, this comparative TEA study documents potential economics for the developmental biofuel pathways via mixed oxygenates.

  5. GLASS AND GLASS-DERIVATIVE SEALS FOR USE IN ENERGY-EFFICIENT FUEL CELLS AND LAMPS

    SciTech Connect

    Scott Misture; Arun Varshneya; Matthew Hall; Sylvia DeCarr; Steve Bancheri

    2004-08-15

    As the project approaches the end of the first year, the materials screening components of the work are ahead of schedule, while all other tasks are on schedule. For solid oxide fuel cells (SOFC), a series of 16 sealing glasses have been prepared and characterized. Traditional melting was used to prepare all of the glasses, and the sol-gel approach has been used to prepare some of the glasses as well as other compositions that might be viable because of the low processing temperatures afforded by the sol-gel method. The glass characterization included measurements of the viscosity and thermal expansion of the glasses, as well as the thermal expansion of the partly crystalline glass ceramics. In addition, the wetting and sintering behavior of all glasses has been measured, as well as the crystallization behavior. The time and temperature at which crystalline phases form from the glasses has been determined for all of the glasses. Each glass ceramic contains at least two crystalline phases, and most of the crystalline phases have been positively identified. Room temperature leak testing has been completed for all sealants, and experiments are in progress to determine the DC electrochemical degradation and degradation in wet hydrogen. The second component of the work, focused on seals for higher-temperature discharge lighting, has focused on determining the phase relations in the yttria--alumina--silica system at various silica levels. Again, traditional melting and sol-gel synthesis have been employed, and the sol-gel method was successful for preparing new phases that were discovered during the work. High temperature diffraction and annealing studies have clarified the phase relations for the samples studies, although additional work remains. Four new phases have been identified and synthesized in pure form, from which full structure solutions were obtained as well as the anisotropic thermal expansion for each phase. Functional testing of lamps are on on-going and

  6. Combating Work Refusal Using Research-Based Practices

    ERIC Educational Resources Information Center

    Billingsley, Glenna M.

    2016-01-01

    Academic expectations are often antecedents for various types of inappropriate classroom behavior for students with challenging behavior. Effective interventions for managing these behaviors must involve techniques that combat academic refusal. Addressing the underlying issues of resistance or refusal to perform academically in school using…

  7. 9 CFR 98.20 - Embryos refused entry.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 9 Animals and Animal Products 1 2014-01-01 2014-01-01 false Embryos refused entry. 98.20 Section... CERTAIN ANIMAL EMBRYOS AND ANIMAL SEMEN Ruminant and Swine Embryos From Regions Where Rinderpest or Foot-and-Mouth Disease Exists § 98.20 Embryos refused entry. If any embryos are determined to be...

  8. 9 CFR 98.20 - Embryos refused entry.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 9 Animals and Animal Products 1 2013-01-01 2013-01-01 false Embryos refused entry. 98.20 Section... CERTAIN ANIMAL EMBRYOS AND ANIMAL SEMEN Ruminant and Swine Embryos From Regions Where Rinderpest or Foot-and-Mouth Disease Exists § 98.20 Embryos refused entry. If any embryos are determined to be...

  9. 9 CFR 98.20 - Embryos refused entry.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 9 Animals and Animal Products 1 2011-01-01 2011-01-01 false Embryos refused entry. 98.20 Section... CERTAIN ANIMAL EMBRYOS AND ANIMAL SEMEN Ruminant and Swine Embryos From Regions Where Rinderpest or Foot-and-Mouth Disease Exists § 98.20 Embryos refused entry. If any embryos are determined to be...

  10. 9 CFR 98.20 - Embryos refused entry.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 9 Animals and Animal Products 1 2012-01-01 2012-01-01 false Embryos refused entry. 98.20 Section... CERTAIN ANIMAL EMBRYOS AND ANIMAL SEMEN Ruminant and Swine Embryos From Regions Where Rinderpest or Foot-and-Mouth Disease Exists § 98.20 Embryos refused entry. If any embryos are determined to be...

  11. 9 CFR 98.20 - Embryos refused entry.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Embryos refused entry. 98.20 Section... CERTAIN ANIMAL EMBRYOS AND ANIMAL SEMEN Ruminant and Swine Embryos From Regions Where Rinderpest or Foot-and-Mouth Disease Exists § 98.20 Embryos refused entry. If any embryos are determined to be...

  12. 14 CFR 121.586 - Authority to refuse transportation.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 3 2010-01-01 2010-01-01 false Authority to refuse transportation. 121.586 Section 121.586 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF TRANSPORTATION... transportation. (a) No certificate holder may refuse transportation to a passenger on the basis that, because...

  13. Empirical Examination of a Multicomponent Treatment for Pediatric Food Refusal.

    ERIC Educational Resources Information Center

    Hoch, Theodore A.; Babbitt, Roberta L.; Farrar-Schneider, Debra; Berkowitz, Merrill J.; Owens, J. Carl; Knight, Terry L.; Snyder, Angela M.; Rizol, Laura M.; Wise, David T.

    2001-01-01

    This paper reports on assessment and treatment of food refusal for four inpatient boys (ages 2,3,3, and 9) receiving tube feedings. It used a contingency contacting procedure extended by a component analysis. Data suggest that food refusal appeared to be maintained primarily by negative reinforcement contingencies. Caregiver responses indicated a…

  14. 25 CFR 135.6 - Refusal of water delivery.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 25 Indians 1 2014-04-01 2014-04-01 false Refusal of water delivery. 135.6 Section 135.6 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR FINANCIAL ACTIVITIES CONSTRUCTION ASSESSMENTS, CROW INDIAN IRRIGATION PROJECT Charges Assessed Against Irrigation District Lands § 135.6 Refusal of water delivery. The right is reserved to the...

  15. 25 CFR 135.23 - Refusal of water delivery.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 25 Indians 1 2014-04-01 2014-04-01 false Refusal of water delivery. 135.23 Section 135.23 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR FINANCIAL ACTIVITIES CONSTRUCTION ASSESSMENTS, CROW INDIAN IRRIGATION PROJECT Charges Assessed Against Non-Indian Lands Not Included in an Irrigation District § 135.23 Refusal of water...

  16. 28 CFR 345.34 - Refusal to employ.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 28 Judicial Administration 2 2011-07-01 2011-07-01 false Refusal to employ. 345.34 Section 345.34 Judicial Administration FEDERAL PRISON INDUSTRIES, INC., DEPARTMENT OF JUSTICE FEDERAL PRISON INDUSTRIES (FPI) INMATE WORK PROGRAMS Recruitment and Hiring Practices § 345.34 Refusal to employ. (a) The SOI...

  17. 28 CFR 345.34 - Refusal to employ.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 28 Judicial Administration 2 2012-07-01 2012-07-01 false Refusal to employ. 345.34 Section 345.34 Judicial Administration FEDERAL PRISON INDUSTRIES, INC., DEPARTMENT OF JUSTICE FEDERAL PRISON INDUSTRIES (FPI) INMATE WORK PROGRAMS Recruitment and Hiring Practices § 345.34 Refusal to employ. (a) The SOI...

  18. 28 CFR 345.34 - Refusal to employ.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 28 Judicial Administration 2 2013-07-01 2013-07-01 false Refusal to employ. 345.34 Section 345.34 Judicial Administration FEDERAL PRISON INDUSTRIES, INC., DEPARTMENT OF JUSTICE FEDERAL PRISON INDUSTRIES (FPI) INMATE WORK PROGRAMS Recruitment and Hiring Practices § 345.34 Refusal to employ. (a) The SOI...

  19. 28 CFR 345.34 - Refusal to employ.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 28 Judicial Administration 2 2014-07-01 2014-07-01 false Refusal to employ. 345.34 Section 345.34 Judicial Administration FEDERAL PRISON INDUSTRIES, INC., DEPARTMENT OF JUSTICE FEDERAL PRISON INDUSTRIES (FPI) INMATE WORK PROGRAMS Recruitment and Hiring Practices § 345.34 Refusal to employ. (a) The SOI...

  20. 47 CFR 73.4005 - Advertising-refusal to sell.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 4 2011-10-01 2011-10-01 false Advertising-refusal to sell. 73.4005 Section 73.4005 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES RADIO BROADCAST SERVICES Rules Applicable to All Broadcast Stations § 73.4005 Advertising—refusal to sell. See...

  1. 47 CFR 73.4005 - Advertising-refusal to sell.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 4 2010-10-01 2010-10-01 false Advertising-refusal to sell. 73.4005 Section 73.4005 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES RADIO BROADCAST SERVICES Rules Applicable to All Broadcast Stations § 73.4005 Advertising—refusal to sell. See...

  2. 47 CFR 73.4005 - Advertising-refusal to sell.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 4 2013-10-01 2013-10-01 false Advertising-refusal to sell. 73.4005 Section 73.4005 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES RADIO BROADCAST SERVICES Rules Applicable to All Broadcast Stations § 73.4005 Advertising—refusal to sell. See...

  3. 47 CFR 73.4005 - Advertising-refusal to sell.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 4 2014-10-01 2014-10-01 false Advertising-refusal to sell. 73.4005 Section 73.4005 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES RADIO BROADCAST SERVICES Rules Applicable to All Broadcast Stations § 73.4005 Advertising—refusal to sell. See...

  4. 47 CFR 73.4005 - Advertising-refusal to sell.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 4 2012-10-01 2012-10-01 false Advertising-refusal to sell. 73.4005 Section 73.4005 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) BROADCAST RADIO SERVICES RADIO BROADCAST SERVICES Rules Applicable to All Broadcast Stations § 73.4005 Advertising—refusal to sell. See...

  5. 43 CFR 15.4 - Refuse and polluting substances.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 43 Public Lands: Interior 1 2013-10-01 2013-10-01 false Refuse and polluting substances. 15.4 Section 15.4 Public Lands: Interior Office of the Secretary of the Interior KEY LARGO CORAL REEF PRESERVE § 15.4 Refuse and polluting substances. No person shall dump or deposit in or on the waters of...

  6. 43 CFR 15.4 - Refuse and polluting substances.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 43 Public Lands: Interior 1 2014-10-01 2014-10-01 false Refuse and polluting substances. 15.4 Section 15.4 Public Lands: Interior Office of the Secretary of the Interior KEY LARGO CORAL REEF PRESERVE § 15.4 Refuse and polluting substances. No person shall dump or deposit in or on the waters of...

  7. 43 CFR 15.4 - Refuse and polluting substances.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 43 Public Lands: Interior 1 2011-10-01 2011-10-01 false Refuse and polluting substances. 15.4 Section 15.4 Public Lands: Interior Office of the Secretary of the Interior KEY LARGO CORAL REEF PRESERVE § 15.4 Refuse and polluting substances. No person shall dump or deposit in or on the waters of...

  8. 43 CFR 15.4 - Refuse and polluting substances.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 43 Public Lands: Interior 1 2012-10-01 2011-10-01 true Refuse and polluting substances. 15.4 Section 15.4 Public Lands: Interior Office of the Secretary of the Interior KEY LARGO CORAL REEF PRESERVE § 15.4 Refuse and polluting substances. No person shall dump or deposit in or on the waters of...

  9. Household Refuse Analysis: Theory, Method, and Applications in Social Science.

    ERIC Educational Resources Information Center

    Rathje, William L., Ed.; Ritenbaugh, Cheryl K., Ed.

    1984-01-01

    The articles in this issue explore the current parameters of household refuse analysis. An overview of garbage research studies is presented; research methodology, theories, and applications are examined. U.S. household refuse is compared to the discards of households in Mexico City. (RM)

  10. 16 CFR 1210.18 - Refusal of importation.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 16 Commercial Practices 2 2013-01-01 2013-01-01 false Refusal of importation. 1210.18 Section 1210.18 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION CONSUMER PRODUCT SAFETY ACT REGULATIONS SAFETY STANDARD FOR CIGARETTE LIGHTERS Certification Requirements § 1210.18 Refusal of importation....

  11. 16 CFR 1210.18 - Refusal of importation.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 16 Commercial Practices 2 2012-01-01 2012-01-01 false Refusal of importation. 1210.18 Section 1210.18 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION CONSUMER PRODUCT SAFETY ACT REGULATIONS SAFETY STANDARD FOR CIGARETTE LIGHTERS Certification Requirements § 1210.18 Refusal of importation....

  12. 22 CFR 41.121 - Refusal of individual visas.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ...)(8). When a visa application has been properly completed and executed in accordance with the... refusal on the application. Upon refusing the nonimmigrant visa, the consular officer shall retain the...) If an alien, who has not yet filed a visa application, seeks advice from a consular officer,...

  13. 22 CFR 42.81 - Procedure in refusing individual visas.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Procedure in refusing individual visas. (a) Issuance or refusal mandatory. When a visa application has been..., Application for Immigrant Visa and Alien Registration, has been executed by the applicant. When an immigrant... presentation of additional evidence and the applicant indicates an intention to submit such evidence,...

  14. 30 CFR 77.214 - Refuse piles; general.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... located in areas which are a safe distance from all underground mine airshafts, preparation plants... covered with clay or other inert material as the piles are constructed. (c) A fireproof barrier of clay or inert material shall be constructed between old and new refuse piles. (d) Roadways to refuse piles...

  15. 16 CFR 1210.18 - Refusal of importation.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 16 Commercial Practices 2 2010-01-01 2010-01-01 false Refusal of importation. 1210.18 Section 1210.18 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION CONSUMER PRODUCT SAFETY ACT REGULATIONS SAFETY STANDARD FOR CIGARETTE LIGHTERS Certification Requirements § 1210.18 Refusal of importation....

  16. 16 CFR 1210.18 - Refusal of importation.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 16 Commercial Practices 2 2011-01-01 2011-01-01 false Refusal of importation. 1210.18 Section 1210.18 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION CONSUMER PRODUCT SAFETY ACT REGULATIONS SAFETY STANDARD FOR CIGARETTE LIGHTERS Certification Requirements § 1210.18 Refusal of importation....

  17. Psychosocial Characteristics of Adolescents Who Refuse Cancer Treatment.

    ERIC Educational Resources Information Center

    Blotcky, Alan D.; And Others

    1985-01-01

    Psychosocial variables were examiend by comparing 10 adolescents (and their mothers) who had refused cancer treatment with a group of 10 consenting adolescents who were matched on demographic and illness variables. Adolescent refusers scored lower on State Anxiety and Subjective Distress but scored higher on Trait Anxiety, Religiosity, and…

  18. 22 CFR 40.6 - Basis for refusal.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 22 Foreign Relations 1 2014-04-01 2014-04-01 false Basis for refusal. 40.6 Section 40.6 Foreign Relations DEPARTMENT OF STATE VISAS REGULATIONS PERTAINING TO BOTH NONIMMIGRANTS AND IMMIGRANTS UNDER THE IMMIGRATION AND NATIONALITY ACT, AS AMENDED General Provisions § 40.6 Basis for refusal. A visa can be...

  19. 22 CFR 40.6 - Basis for refusal.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 22 Foreign Relations 1 2012-04-01 2012-04-01 false Basis for refusal. 40.6 Section 40.6 Foreign Relations DEPARTMENT OF STATE VISAS REGULATIONS PERTAINING TO BOTH NONIMMIGRANTS AND IMMIGRANTS UNDER THE IMMIGRATION AND NATIONALITY ACT, AS AMENDED General Provisions § 40.6 Basis for refusal. A visa can be...

  20. 22 CFR 40.6 - Basis for refusal.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Basis for refusal. 40.6 Section 40.6 Foreign Relations DEPARTMENT OF STATE VISAS REGULATIONS PERTAINING TO BOTH NONIMMIGRANTS AND IMMIGRANTS UNDER THE IMMIGRATION AND NATIONALITY ACT, AS AMENDED General Provisions § 40.6 Basis for refusal. A visa can be...

  1. 22 CFR 40.6 - Basis for refusal.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 22 Foreign Relations 1 2013-04-01 2013-04-01 false Basis for refusal. 40.6 Section 40.6 Foreign Relations DEPARTMENT OF STATE VISAS REGULATIONS PERTAINING TO BOTH NONIMMIGRANTS AND IMMIGRANTS UNDER THE IMMIGRATION AND NATIONALITY ACT, AS AMENDED General Provisions § 40.6 Basis for refusal. A visa can be...

  2. 22 CFR 40.6 - Basis for refusal.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 22 Foreign Relations 1 2011-04-01 2011-04-01 false Basis for refusal. 40.6 Section 40.6 Foreign Relations DEPARTMENT OF STATE VISAS REGULATIONS PERTAINING TO BOTH NONIMMIGRANTS AND IMMIGRANTS UNDER THE IMMIGRATION AND NATIONALITY ACT, AS AMENDED General Provisions § 40.6 Basis for refusal. A visa can be...

  3. 43 CFR 15.4 - Refuse and polluting substances.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 43 Public Lands: Interior 1 2010-10-01 2010-10-01 false Refuse and polluting substances. 15.4 Section 15.4 Public Lands: Interior Office of the Secretary of the Interior KEY LARGO CORAL REEF PRESERVE § 15.4 Refuse and polluting substances. No person shall dump or deposit in or on the waters of...

  4. Results of combustion and emissions testing when co-firing blends of binder-enhanced densified refuse-derived fuel (b-dRDF) pellets and coal in a 440 MW{sub e} cyclone fired combustor. Volume 3: Appendices

    SciTech Connect

    Ohlsson, O.

    1994-07-01

    This report contains the data resulting from the co-firing of b-dRDF pellets and coal in a 440-MW{sub e} cyclone-fired combustor. These tests were conducted under a Collaborative Research and Development Agreement (CRADA). The CRADA partners included the U.S. Department of Energy (DOE), National Renewable Energy Laboratory (NREL), Argonne National Laboratory (ANL), Otter Tail Power Company, Green Isle Environmental, Inc., XL Recycling Corporation, and Marblehead Lime Company. The report is made up of three volumes. This volume contains other supporting information, along with quality assurance documentation and safety and test plans. With this multi-volume approach, readers can find information at the desired level of detail, depending on individual interest or need.

  5. Organic derivatives of hydrazine and hydroxylamine and future reprocessing of irradiated nuclear fuel

    SciTech Connect

    Koltunov, V.S.; Baranov, S.M.

    1994-07-01

    Reductants of Pu and Np that are used in extraction suffer from a number of deficiencies such as the formation of Fe(III), Fe(II), and ammonium (hydrazine) nitrates. This increases the amount of salts in the radioactive waste solutions, the instability of U(IV) in the organic phase, and the potential explosiveness owing to the formation of azides (hydrazine) and others. Therefore, the search for and investigation of new highly efficient reductants of Pu and Np that do not form salts should become an important thrust for improving thrust extraction in the near future. Organic derivatives of hydrazine and hydroxylamine are the first step in this direction. These comparatively rapidly convert Np(VI) to Np(V) and Pu(IV) to Pu(III), thereby stabilizing the pair Pu(III)-Np(V). This is most convenient for separating Pu and Np from U by reductive back-extraction in the first extraction cycle.

  6. REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS

    SciTech Connect

    Paul Chin; George W. Roberts; James J. Spivey

    2003-12-31

    Uses for structured catalytic supports, such as ceramic straight-channel monoliths and ceramic foams, have been established for a long time. One of the most prominent examples is the washcoated ceramic monolith as a three-way catalytic converter for gasoline-powered automobiles. A distinct alternative to the ceramic monolith is the metal foam, with potential use in fuel cell-powered automobiles. The metal foams are characterized by their pores per inch (ppi) and density ({rho}). In previous research, using 5 wt% platinum (Pt) and 0.5 wt% iron (Fe) catalysts, washcoated metal foams, 5.08 cm in length and 2.54 cm in diameter, of both varying and similar ppi and {rho} were tested for their activity (X{sub CO}) and selectivity (S{sub CO}) on a CO preferential oxidation (PROX) reaction in the presence of a H{sub 2}-rich gas stream. The variances in these metal foams' activity and selectivity were much larger than expected. Other structured supports with 5 wt% Pt, 0-1 wt% Fe weight loading were also examined. A theory for this phenomenon states that even though these structured supports have a similar nominal catalyst weight loading, only a certain percentage of the Pt/Fe catalyst is exposed on the surface as an active site for CO adsorption. We will use two techniques, pulse chemisorption and temperature programmed desorption (TPD), to characterize our structured supports. Active metal count, metal dispersion, and other calculations will help clarify the causes for the activity and selectivity variations between the supports. Results on ceramic monoliths show that a higher Fe loading yields a lower dispersion, potentially because of Fe inhibition of the Pt surface for CO adsorption. This theory is used to explain the reason for activity and selectivity differences for varying ppi and {rho} metal foams; less active and selective metal foams have a lower Fe loading, which justifies their higher metal dispersion. Data on the CO desorption temperature and average metal

  7. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas

    SciTech Connect

    Bhatt, B.L.

    1992-09-01

    As part of the DOE-sponsored contract for the Synthesis of Dimethyl Ether (DME) and Alternative Fuels in the Liquid Phase from Coal- Derived Syngas, the single-step, slurry phase DME synthesis process was developed. The development involved screening of catalyst systems, process variable studies, and catalyst life studies in two 300 ml stirred autoclaves. As a spin-off of the Liquid Phase Methanol (LPMEOH*) process, the new process significantly improves the syngas conversion efficiency of the LPMEOH process. This improvement can be achieved by replacing a portion of methanol catalyst with a dehydration catalyst in the reactor, resulting in the product methanol being converted to DME, thus avoiding the thermodynamic equilibrium constraint of the methanol reaction. Overall, this increases syngas conversion per-pass. The selectivity and productivity of DME and methanol are affected by the catalyst system employed as well as operating conditions. A preferred catalyst system, consisting of a physical mixture of a methanol catalyst and a gamma alumina, was identified. An improvement of about 50% in methanol equivalent productivity was achieved compared to the LPMEOH process. Results from the process variable study indicate that higher pressure and CO[sub 2] removal benefit the process significantly. Limited life studies performed on the preferred catalyst system suggest somewhat higher than expected deactivation rate for the methanol catalyst. Several DME/methanol mixtures were measured for their key properties as transportation fuels. With small amounts of DME added, significant improvements in both flash points and Reid Vapor Pressure (RVP) were observed over the corresponding values of methanol alone.

  8. Biological production of liquid fuels from biomass

    SciTech Connect

    1982-01-01

    A scheme for the production of liquid fuels from renewable resources such as poplar wood and lignocellulosic wastes from a refuse hydropulper was investigated. The particular scheme being studied involves the conversion of a cellulosic residue, resulting from a solvent delignified lignocellulosic feed, into either high concentration sugar syrups or into ethyl and/or butyl alcohol. The construction of a pilot apparatus for solvent delignifying 150 g samples of lignocellulosic feeds was completed. Also, an analysis method for characterizing the delignified product has been selected and tested. This is a method recommended in the Forage Fiber Handbook. Delignified samples are now being prepared and tested for their extent of delignification and susceptibility to enzyme hydrolysis. Work is continuing on characterizing the cellulase and cellobiase enzyme systems derived from the YX strain of Thermomonospora.

  9. The carnivorous Venus flytrap uses prey-derived amino acid carbon to fuel respiration.

    PubMed

    Fasbender, Lukas; Maurer, Daniel; Kreuzwieser, Jürgen; Kreuzer, Ines; Schulze, Waltraud X; Kruse, Jörg; Becker, Dirk; Alfarraj, Saleh; Hedrich, Rainer; Werner, Christiane; Rennenberg, Heinz

    2017-04-01

    The present study was performed to elucidate the fate of carbon (C) and nitrogen (N) derived from protein of prey caught by carnivorous Dionaea muscipula. For this, traps were fed (13) C/(15) N-glutamine (Gln). The release of (13) CO2 was continuously monitored by isotope ratio infrared spectrometry. After 46 h, the allocation of C and N label into different organs was determined and tissues were subjected to metabolome, proteome and transcriptome analyses. Nitrogen of Gln fed was already separated from its C skeleton in the decomposing fluid secreted by the traps. Most of the Gln-C and Gln-N recovered inside plants were localized in fed traps. Among nonfed organs, traps were a stronger sink for Gln-C compared to Gln-N, and roots were a stronger sink for Gln-N compared to Gln-C. A significant amount of the Gln-C was respired as indicated by (13) C-CO2 emission, enhanced levels of metabolites of respiratory Gln degradation and increased abundance of proteins of respiratory processes. Transcription analyses revealed constitutive expression of enzymes involved in Gln metabolism in traps. It appears that prey not only provides building blocks of cellular constituents of carnivorous Dionaea muscipula, but also is used for energy generation by respiratory amino acid degradation.

  10. Effects of subchronic inhalation exposure of rats to emissions from a diesel engine burning soybean oil-derived biodiesel fuel.

    PubMed

    Finch, G L; Hobbs, C H; Blair, L F; Barr, E B; Hahn, F F; Jaramillo, R J; Kubatko, J E; March, T H; White, R K; Krone, J R; Ménache, M G; Nikula, K J; Mauderly, J L; Van Gerpen, J; Merceica, M D; Zielinska, B; Stankowski, L; Burling, K; Howell, S

    2002-10-01

    There is increasing interest in diesel fuels derived from plant oils or animal fats ("biodiesel"), but little information on the toxicity of biodiesel emissions other than bacterial mutagenicity. F344 rats were exposed by inhalation 6 h/day, 5 days/wk for 13 wk to 1 of 3 dilutions of emissions from a diesel engine burning 100% soybean oil-derived fuel, or to clean air as controls. Whole emissions were diluted to nominal NO(x) concentrations of 5, 25, or 50 ppm, corresponding to approximately 0.04, 0.2, and 0.5 mg particles/m(3), respectively. Biologically significant, exposure-related effects were limited to the lung, were greater in females than in males, and were observed primarily at the highest exposure level. There was a dose-related increase in the numbers of alveolar macrophages and the numbers of particles in the macrophages, as expected from repeated exposure, but no neutrophil response even at the highest exposure level. The macrophage response was reduced 28 days after cessation of the exposure. Among the high-level females, the group mean lung weight/body weight ratio was increased, and minimal, multifocal bronchiolar metaplasia of alveolar ducts was observed in 4 of 30 rats. Lung weights were not significantly increased, and metaplasia of the alveolar ducts was not observed in males. An increase in particle-laden macrophages was the only exposure-related finding in lungs at the intermediate and low levels, with fewer macrophages and fewer particles per macrophage at the low level. Alveolar histiocytosis was observed in a few rats in both exposed and control groups. There were statistically significant, but minor and not consistently exposure-related, differences in body weight, nonpulmonary organ weights, serum chemistry, and glial fibrillary acidic protein in the brain. There were no significant exposure-related effects on survival, clinical signs, feed consumption, ocular toxicity, hematology, neurohistology, micronuclei in bone marrow, sister

  11. Recycling of aged refuse from a closed landfill.

    PubMed

    Zhao, Youcai; Song, Liyan; Huang, Renhua; Song, Lijie; Li, Xiong

    2007-04-01

    In this study, refuse excavated from a typical refuse landfill in Shanghai after 8-10 years of placement was characterized in terms of particle size, total nitrogen, total phosphorus, and biodegradable matter. The refuse contained a large and diverse population of micro-organisms with a high capacity for decomposing refractory organic matter present in some wastewaters, including leachate. It was found that the aged refuse was quite stable after about a decade of decomposition in the warm, humid climate of southern China. The fine fractions resembled and had the properties of black soil, a medium that is suitable for green construction, organic fertilizer, or as bioreactor media for biological treatment of organic wastewaters. Excavation of the aged refuse would make about 50% of the space available for fresh refuse. The plastics, glass, textiles, and cans can be readily mechanically separated and recycled after cleaning. It is estimated that at least 200 millions tonnes of such aged refuse are available in China alone, and at least 10 times that much is buried worldwide. Hence, the evaluation of mined landfill waste and consideration of its potential uses is of great significance.

  12. Characteristics and Outcomes of Elderly Patients Refused to ICU

    PubMed Central

    Pintado, María-Consuelo; Villa, Patricia; González-García, Natalia; Luján, Jimena; Molina, Rocío; Trascasa, María; López-Ramos, Esther; Martínez, Cristina; Cambronero, José-Andrés; de Pablo, Raúl

    2013-01-01

    Background. There are few data regarding the process of deciding which elderly patients are refused to ICU admission, their characteristics, and outcome. Methods. Prospective longitudinal observational cohort study. We included all consecutive patients older than 75 years, who were evaluated for admission to but were refused to treatment in ICU, during 18 months, with 12-month followup. We collected demographic data, ICU admission/refusal reasons, previous functional and cognitive status, comorbidity, severity of illness, and hospital and 12-month mortality. Results. 338 elderly patients were evaluated for ICU admission and 88 were refused to ICU (26%). Patients refused because they were “too ill to benefit” had more comorbidity and worse functional and mental situation than those admitted to ICU; there were no differences in illness severity. Hospital mortality rate of the whole study cohort was 36.3%, higher in patients “too ill to benefit” (55.6% versus 35.8%, P < 0.01), which also have higher 1-year mortality (73.7% versus 42.5%, P < 0.01). High comorbidity, low functional status, unavailable ICU beds, and age were associated with refusal decision on multivariate analysis. Conclusions. Prior functional status and comorbidity, not only the age or severity of illness, can help us more to make the right decision of admitting or refusing to ICU patients older than 75 years. PMID:24453879

  13. Bioconversion of coal-derived synthesis gas to liquid fuels. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect

    Jain, M.K.

    1991-12-31

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  14. Removal potential of toxic 2378-substituted PCDD/F from incinerator flue gases by waste-derived activated carbons.

    PubMed

    Hajizadeh, Yaghoub; Onwudili, Jude A; Williams, Paul T

    2011-06-01

    The application of activated carbons has become a commonly used emission control protocol for the removal or adsorption of persistent organic pollutants from the flue gas streams of waste incinerators. In this study, the 2378-substituted PCDD/F removal efficiency of three types of activated carbons derived from the pyrolysis of refuse derived fuel, textile waste and scrap tyre was investigated and compared with that of a commercial carbon. Experiments were carried out in a laboratory scale fixed-bed reactor under a simulated flue gas at 275°C with a reaction period of four days. The PCDD/F in the solid matrices and exhaust gas, were analyzed using gas chromatography coupled with a triple quadrupole mass spectrometer. In the absence of activated carbon adsorbent, there was a significant increase in the concentration of toxic PCDD/F produced in the reacted flyash, reaching up to 6.6 times higher than in the raw flyash. In addition, there was a substantial release of PCDD/F into the gas phase, which was found in the flue gas trapping system. By application of the different commercial, refuse derived fuel, textile and tyre activated carbons the total PCDD/F toxic equivalent removal efficiencies in the exhaust gas stream were 58%, 57%, 64% and 52%, respectively. In general, the removal of the PCDDs was much higher with an average of 85% compared to PCDFs at 41%. Analysis of the reacted activated carbons showed that there was some formation of PCDD/F, for instance, a total of 60.6 μg I-TEQ kg(-1) toxic PCDD/F was formed in the refuse derived fuel activated carbon compared to 34 μg I-TEQ kg(-1) in the commercial activated carbon. The activated carbons derived from the pyrolysis of waste, therefore, showed good potential as a control material for PCDD/F emissions in waste incinerator flue gases.

  15. Removal potential of toxic 2378-substituted PCDD/F from incinerator flue gases by waste-derived activated carbons

    SciTech Connect

    Hajizadeh, Yaghoub; Onwudili, Jude A.; Williams, Paul T.

    2011-06-15

    The application of activated carbons has become a commonly used emission control protocol for the removal or adsorption of persistent organic pollutants from the flue gas streams of waste incinerators. In this study, the 2378-substituted PCDD/F removal efficiency of three types of activated carbons derived from the pyrolysis of refuse derived fuel, textile waste and scrap tyre was investigated and compared with that of a commercial carbon. Experiments were carried out in a laboratory scale fixed-bed reactor under a simulated flue gas at 275 deg. C with a reaction period of four days. The PCDD/F in the solid matrices and exhaust gas, were analyzed using gas chromatography coupled with a triple quadrupole mass spectrometer. In the absence of activated carbon adsorbent, there was a significant increase in the concentration of toxic PCDD/F produced in the reacted flyash, reaching up to 6.6 times higher than in the raw flyash. In addition, there was a substantial release of PCDD/F into the gas phase, which was found in the flue gas trapping system. By application of the different commercial, refuse derived fuel, textile and tyre activated carbons the total PCDD/F toxic equivalent removal efficiencies in the exhaust gas stream were 58%, 57%, 64% and 52%, respectively. In general, the removal of the PCDDs was much higher with an average of 85% compared to PCDFs at 41%. Analysis of the reacted activated carbons showed that there was some formation of PCDD/F, for instance, a total of 60.6 {mu}g I-TEQ kg{sup -1} toxic PCDD/F was formed in the refuse derived fuel activated carbon compared to 34 {mu}g I-TEQ kg{sup -1} in the commercial activated carbon. The activated carbons derived from the pyrolysis of waste, therefore, showed good potential as a control material for PCDD/F emissions in waste incinerator flue gases.

  16. Combustion studies of coal derived solid fuels by thermogravimetric analysis. III. Correlation between burnout temperature and carbon combustion efficiency

    USGS Publications Warehouse

    Rostam-Abadi, M.; DeBarr, J.A.; Chen, W.T.

    1990-01-01

    Burning profiles of 35-53 ??m size fractions of an Illinois coal and three partially devolatilized coals prepared from the original coal were obtained using a thermogravimetric analyzer. The burning profile burnout temperatures were higher for lower volatile fuels and correlated well with carbon combustion efficiencies of the fuels when burned in a laboratory-scale laminar flow reactor. Fuels with higher burnout temperatures had lower carbon combustion efficiencies under various time-temperature conditions in the laboratory-scale reactor. ?? 1990.

  17. DESIGNING AN OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION AND COFIRING SAWDUST WITH COAL AT ALBRIGHT GENERATING STATION

    SciTech Connect

    K. Payette; D. Tillman

    2001-10-01

    During the period July 1, 2001--September 30, 2001, Allegheny Energy Supply Co., LLC (Allegheny) continued construction of the Willow Island cofiring project, completed the installation of the fuel storage facility, the fuel receiving facility, and the processing building. All mechanical equipment has been installed and electrical construction has proceeded. During this time period significant short term testing of the Albright Generating Station cofiring facility was completed, and the 100-hour test was planned for early October. The testing demonstrated that cofiring at the Albright Generating Station could contribute to a ''4P Strategy''--reduction of SO{sub 2}, NO{sub x}, mercury, and greenhouse gas emissions. This report summarizes the activities associated with the Designer Opportunity Fuel program, and demonstrations at Willow Island and Albright Generating Stations. It details the construction activities at both sites along with the combustion modeling at the Willow Island site.

  18. Carbon-13 and proton nuclear magnetic resonance analysis of shale-derived refinery products and jet fuels and of experimental referee broadened-specification jet fuels

    NASA Technical Reports Server (NTRS)

    Dalling, D. K.; Bailey, B. K.; Pugmire, R. J.

    1984-01-01

    A proton and carbon-13 nuclear magnetic resonance (NMR) study was conducted of Ashland shale oil refinery products, experimental referee broadened-specification jet fuels, and of related isoprenoid model compounds. Supercritical fluid chromatography techniques using carbon dioxide were developed on a preparative scale, so that samples could be quantitatively separated into saturates and aromatic fractions for study by NMR. An optimized average parameter treatment was developed, and the NMR results were analyzed in terms of the resulting average parameters; formulation of model mixtures was demonstrated. Application of novel spectroscopic techniques to fuel samples was investigated.

  19. The right to refuse treatment: a model act.

    PubMed Central

    1983-01-01

    Although the right to refuse medical treatment is universally recognized as a fundamental principle of liberty, this right is not always honored. A refusal can be thwarted either because a patient is unable to competently communicate or because providers insist on continuing treatment. To help enhance the patient's right to refuse treatment, many states have enacted so-called "living will" or "natural death" statutes. We believe the time has come to move beyond these current legislative models, and we therefore propose a Model Act that clearly enunciates an individual's right to refuse treatment, does not limit its exercise to the terminally ill or to heroic measures, and provides a mechanism by which individuals can set forth their wishes in advance and designate another person to enforce them. PMID:6869647

  20. 27 CFR 46.273 - Refusing entry or examination.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... PRODUCTS AND CIGARETTE PAPERS AND TUBES Floor Stocks Tax on Certain Tobacco Products, Cigarette Papers, and Cigarette Tubes Held for Sale on April 1, 2009 Ttb Authorities § 46.273 Refusing entry or examination....

  1. 27 CFR 46.273 - Refusing entry or examination.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... PRODUCTS AND CIGARETTE PAPERS AND TUBES Floor Stocks Tax on Certain Tobacco Products, Cigarette Papers, and Cigarette Tubes Held for Sale on April 1, 2009 Ttb Authorities § 46.273 Refusing entry or examination....

  2. 27 CFR 46.273 - Refusing entry or examination.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... PRODUCTS AND CIGARETTE PAPERS AND TUBES Floor Stocks Tax on Certain Tobacco Products, Cigarette Papers, and Cigarette Tubes Held for Sale on April 1, 2009 Ttb Authorities § 46.273 Refusing entry or examination....

  3. Understanding Partnerships: A Rural College's Role in Recycling Refuse.

    ERIC Educational Resources Information Center

    Adams, Frank G.

    2000-01-01

    Describes the partnership that was formed by a county government, three city governments, Weyerhaeuser Company, and Cossatot Technical College in Arkansas to solve the refuse problem when the local landfill closed. (JOW)

  4. 7 CFR 322.19 - Inspection; refusal of entry.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... Restricted Organisms § 322.19 Inspection; refusal of entry. (a) APHIS may inspect any restricted organism at the time of importation to determine if the organism meets all of the requirements of this part....

  5. 7 CFR 322.19 - Inspection; refusal of entry.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... Restricted Organisms § 322.19 Inspection; refusal of entry. (a) APHIS may inspect any restricted organism at the time of importation to determine if the organism meets all of the requirements of this part....

  6. 27 CFR 46.273 - Refusing entry or examination.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... PRODUCTS AND CIGARETTE PAPERS AND TUBES Floor Stocks Tax on Certain Tobacco Products, Cigarette Papers, and Cigarette Tubes Held for Sale on April 1, 2009 Ttb Authorities § 46.273 Refusing entry or examination....

  7. The functional profiles of school refusal behavior. Diagnostic aspects.

    PubMed

    Kearney, Christopher A; Albano, Anne Marie

    2004-01-01

    School refusal behavior is a common problem seen by mental health professionals and by educators but little consensus is available as to its classification, assessment, and treatment. This study assessed 143 youth with primary school refusal behavior and their parents to examine diagnoses that are most commonly associated with proposed functions of school refusal behavior. As expected, results indicated that great heterogeneity in diagnoses marks this population. In general, anxiety-related diagnoses were associated more with negatively reinforced school refusal behavior; separation anxiety disorder was associated more with attention-seeking behavior; and oppositional defiant disorder and conduct disorder were associated more with pursuit of tangible reinforcement outside of school. These results are discussed within the context of classification, assessment, and treatment of this population.

  8. 37 CFR 211.7 - Reconsideration procedure for refusals to register.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... refusals to register. 211.7 Section 211.7 Patents, Trademarks, and Copyrights COPYRIGHT OFFICE, LIBRARY OF... refusals to register. The requirements prescribed in § 202.5 of this chapter for reconsideration of refusals to register copyright claims are applicable to requests to reconsider refusals to register...

  9. 37 CFR 211.7 - Reconsideration procedure for refusals to register.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... refusals to register. 211.7 Section 211.7 Patents, Trademarks, and Copyrights U.S. COPYRIGHT OFFICE... for refusals to register. The requirements prescribed in § 202.5 of this chapter for reconsideration of refusals to register copyright claims are applicable to requests to reconsider refusals...

  10. 37 CFR 212.7 - Reconsideration procedure for refusals to register.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... refusals to register. 212.7 Section 212.7 Patents, Trademarks, and Copyrights COPYRIGHT OFFICE, LIBRARY OF... procedure for refusals to register. The requirements prescribed in § 202.5 of this chapter for reconsideration of refusals to register copyright claims are applicable to requests to reconsider refusals...

  11. 37 CFR 212.7 - Reconsideration procedure for refusals to register.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... refusals to register. 212.7 Section 212.7 Patents, Trademarks, and Copyrights COPYRIGHT OFFICE, LIBRARY OF... procedure for refusals to register. The requirements prescribed in § 202.5 of this chapter for reconsideration of refusals to register copyright claims are applicable to requests to reconsider refusals...

  12. 37 CFR 212.7 - Reconsideration procedure for refusals to register.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... refusals to register. 212.7 Section 212.7 Patents, Trademarks, and Copyrights U.S. COPYRIGHT OFFICE... Reconsideration procedure for refusals to register. The requirements prescribed in § 202.5 of this chapter for reconsideration of refusals to register copyright claims are applicable to requests to reconsider refusals...

  13. 37 CFR 211.7 - Reconsideration procedure for refusals to register.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... refusals to register. 211.7 Section 211.7 Patents, Trademarks, and Copyrights COPYRIGHT OFFICE, LIBRARY OF... refusals to register. The requirements prescribed in § 202.5 of this chapter for reconsideration of refusals to register copyright claims are applicable to requests to reconsider refusals to register...

  14. 37 CFR 211.7 - Reconsideration procedure for refusals to register.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... refusals to register. 211.7 Section 211.7 Patents, Trademarks, and Copyrights COPYRIGHT OFFICE, LIBRARY OF... refusals to register. The requirements prescribed in § 202.5 of this chapter for reconsideration of refusals to register copyright claims are applicable to requests to reconsider refusals to register...

  15. 37 CFR 212.7 - Reconsideration procedure for refusals to register.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... refusals to register. 212.7 Section 212.7 Patents, Trademarks, and Copyrights COPYRIGHT OFFICE, LIBRARY OF... procedure for refusals to register. The requirements prescribed in § 202.5 of this chapter for reconsideration of refusals to register copyright claims are applicable to requests to reconsider refusals...

  16. 37 CFR 211.7 - Reconsideration procedure for refusals to register.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... refusals to register. 211.7 Section 211.7 Patents, Trademarks, and Copyrights COPYRIGHT OFFICE, LIBRARY OF... refusals to register. The requirements prescribed in § 202.5 of this chapter for reconsideration of refusals to register copyright claims are applicable to requests to reconsider refusals to register...

  17. 37 CFR 212.7 - Reconsideration procedure for refusals to register.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... refusals to register. 212.7 Section 212.7 Patents, Trademarks, and Copyrights COPYRIGHT OFFICE, LIBRARY OF... procedure for refusals to register. The requirements prescribed in § 202.5 of this chapter for reconsideration of refusals to register copyright claims are applicable to requests to reconsider refusals...

  18. Analysis of response covariationamong multiple topographies of food refusal.

    PubMed Central

    Sevin, Bart M; Gulotta, Charles S; Sierp, Barbara J; Rosica, Leigh A; Miller, Lorionna J

    2002-01-01

    This study examined the effects of sequentially introducing treatment across multiple topographies of food refusal. Treatment with nonremoval of the spoon produced an increase in food acceptance and a decrease in disruption, but expulsion of food increased. When expulsion was treated, packing of food increased. Finally, when packing was treated, all refusal behaviors remained low, and acceptance continued to occur at high and stable levels. PMID:11936547

  19. Analysis of response covariationamong multiple topographies of food refusal.

    PubMed

    Sevin, Bart M; Gulotta, Charles S; Sierp, Barbara J; Rosica, Leigh A; Miller, Lorionna J

    2002-01-01

    This study examined the effects of sequentially introducing treatment across multiple topographies of food refusal. Treatment with nonremoval of the spoon produced an increase in food acceptance and a decrease in disruption, but expulsion of food increased. When expulsion was treated, packing of food increased. Finally, when packing was treated, all refusal behaviors remained low, and acceptance continued to occur at high and stable levels.

  20. Development of OTM Syngas Process and Testing of Syngas Derived Ulta-clean Fuels in Diesel Engines and Fuel Cells Budget Period 3

    SciTech Connect

    E.T. Robinson; John Sirman; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Dan Corgard; Siv Aasland; Kjersti Kleveland; Ann Hooper; Leo Bonnell; John Hemmings; Jack Chen; Bart A. Van Hassel

    2004-12-31

    This topical report summarizes work accomplished for the Program from January 1, 2003 through December 31,2004 in the following task areas: Task 1--Materials Development; Task 2--Composite Development; Task 4--Reactor Design and Process Optimization; Task 8--Fuels and Engine Testing; 8.1 International Diesel Engine Program; and Task IO: Program Management. Most of the key technical objectives for this budget period were achieved. Only partial success was achieved relative to cycle testing under pressure Major improvements in material performance and element reliability have been achieved. A breakthrough material system has driven the development of a compact planar reactor design capable of producing either hydrogen or syngas. The planar reactor shows significant advantages in thermal efficiency and costs compared to either steam methane reforming with CO{sub 2} recovery or autothermal reforming. The fuel and engine testing program is complete The single cylinder test engine evaluation of UCTF fuels begun in Budget Period 2 was finished this budget period. In addition, a study to evaluate new fuel formulations for an HCCl engine was completed.

  1. DEVELOPMENT OF OTM SYNGAS PROCESS AND TESTING OF SYNGAS-DERIVED ULTRA-CLEAN FUELS IN DIESEL ENGINES AND FUEL CELLS

    SciTech Connect

    E.T. Robinson; James P. Meagher; Ravi Prasad

    2001-10-31

    This topical report summarizes work accomplished for the Program from January 1 through September 15, 2001 in the following task areas: Task 1--materials development; Task 2--composite element development; Task 3--tube fabrication; Task 4--reactor design and process optimization; Task 5--catalyst development; Task 6--P-1 operation; Task 8--fuels and engine testing; and Task 10--project management. OTM benchmark material, LCM1, exceeds the commercial oxygen flux target and was determined to be sufficiently robust to carry on process development activities. Work will continue on second-generation OTM materials that will satisfy commercial life targets. Three fabrication techniques for composite elements were determined to be technically feasible. These techniques will be studied and a lead manufacturing process for both small and large-scale elements will be selected in the next Budget Period. Experiments in six P-0 reactors, the long tube tester (LTT) and the P-1 pilot plant were conducted. Significant progress in process optimization was made through both the experimental program and modeling studies of alternate reactor designs and process configurations. Three tailored catalyst candidates for use in OTM process reactors were identified. Fuels for the International diesel engine and Nuvera fuel cell tests were ordered and delivered. Fuels testing and engine development work is now underway.

  2. Pervasive refusal syndrome. Three German cases provide further illustration.

    PubMed

    Jans, Thomas; Ball, Juliane; Preiss, Maike; Haberhausen, Michael; Warnke, Andreas; Renner, Tobias J

    2011-09-01

    Pervasive refusal syndrome (PRS) has been proposed as a new diagnostic entity among child and adolescent psychiatric disorders. It is characterized by a cluster of life-threatening symptoms including refusal of hood intake, decreased or complete lack of mobilization, and lack of communication as well as retreat from normal life activities. Active refusal to accept help as well as neglect of personal care have been core features of PRS in the limited number of cases reported in the last decade. There have, however; been cases with predominantly passive resistance, indicating the possibility that there may be a continuum from active refusal to passive resistance within PRS. Postulating this continuum allows for the integration of "depressive devitalization" -- a refusal syndrome mainly characterized by passive resistance -- into the concept of PRS. Here, three case vignettes of adolescent patients with PRS are presented. The patients' symptomatology can be allocated on this continuum of PRS. PRS and dissociative disorders are compared in greater detail and contrasted within this discussion of differential diagnoses at the poles of such a continuum. PRS is a useful diagnosis for cases involving symptoms of predominating refusal and retreat which cannot satisfactorily be classified by existing diagnostic categories, and which can mostly clearly be separated from dissociative disorder.

  3. Liquid-phase penetration under unsteady in-cylinder conditions: Soy- and Cuphea-derived biodiesel fuels vs. conventional diesel

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Accelerated dilution of engine-lubrication oil is a significant potential issue when fueling with biodiesel. Biodiesel produced from some feedstocks is less volatile than conventional diesel, which makes wall-impingement of liquid fuel more likely, a problem that could be exacerbated by advanced in...

  4. Energy life cycle assessment of rice straw bio-energy derived from potential gasification technologies.

    PubMed

    Shie, Je-Lueng; Chang, Ching-Yuan; Chen, Ci-Syuan; Shaw, Dai-Gee; Chen, Yi-Hung; Kuan, Wen-Hui; Ma, Hsiao-Kan

    2011-06-01

    To be a viable alternative, a biofuel should provide a net energy gain and be capable of being produced in large quantities without reducing food supplies. Amounts of agricultural waste are produced and require treatment, with rice straw contributing the greatest source of such potential bio-fuel in Taiwan. Through life-cycle accounting, several energy indicators and four potential gasification technologies (PGT) were evaluated. The input energy steps for the energy life cycle assessment (ELCA) include collection, generator, torrefaction, crushing, briquetting, transportation, energy production, condensation, air pollution control and distribution of biofuels to the point of end use. Every PGT has a positive energy benefit. The input of energy required for the transportation and pre-treatment are major steps in the ELCA. On-site briquetting of refused-derived fuel (RDF) provides an alternative means of reducing transportation energy requirements. Bio-energy sources, such as waste rice straw, provide an ideal material for the bio-fuel plant.

  5. Evaluation of advanced combustion concepts for dry NO sub x suppression with coal-derived, gaseous fuels

    NASA Technical Reports Server (NTRS)

    Beebe, K. W.; Symonds, R. A.; Notardonato, J. J.

    1982-01-01

    The emissions performance of a rich lean combustor (developed for liquid fuels) was determined for combustion of simulated coal gases ranging in heating value from 167 to 244 Btu/scf (7.0 to 10.3 MJ/NCM). The 244 Btu/scf gas is typical of the product gas from an oxygen blown gasifier, while the 167 Btu/scf gas is similar to that from an air blown gasifier. NOx performance of the rich lean combustor did not meet program goals with the 244 Btu/scf gas because of high thermal NOx, similar to levels expected from conventional lean burning combustors. The NOx emissions are attributed to inadequate fuel air mixing in the rich stage resulting from the design of the large central fuel nozzle delivering 71% of the total gas flow. NOx yield from ammonia injected into the fuel gas decreased rapidly with increasing ammonia level, and is projected to be less than 10% at NH3 levels of 0.5% or higher. NOx generation from NH3 is significant at ammonia concentrations significantly less than 0.5%. These levels may occur depending on fuel gas cleanup system design. CO emissions, combustion efficiency, smoke and other operational performance parameters were satisfactory. A test was completed with a catalytic combustor concept with petroleum distillate fuel. Reactor stage NOx emissions were low (1.4g NOx/kg fuel). CO emissions and combustion efficiency were satisfactory. Airflow split instabilities occurred which eventually led to test termination.

  6. Gas turbine demonstration of pyrolysis: derived fuels. Third technical progress report, July 1, 1979-December 31, 1981

    SciTech Connect

    Jasas, G.; Kasper, J.

    1982-01-01

    The objective of this program is to demonstrate the feasibility of utilizing pyrolytic oil and char as a fuel for a combustion turbine engine. This is the first phase of an extended program with the ultimate goal of commercializing a gas turbine engine and electrical generating system which is independent of petroleum-based fuels. Maximum use of existing technology and current production engine hardware (Teledyne CAE Model J69-T-29 Turbojet Engine) is being incorporated for a sequence of test evaluations rating from isolated combustor component tests to full scale engine demonstration tests. The technical goals to be achieved during the course of this project are: pyrolytic fuel characterization in terms of its properties and constituents; pyrolytic fuel combustion technology in gas turbine application in terms of pyrolytic oil atomization, quantity of char burned, emissions, performance and associated combustion system aerothermodynamics; pyrolytic fuel (oil and char slurry) handling, mixing, and storage technology; and engine materials compatibility with the the pyrolytic fuel and its combustion products. Progress achieved during the period from July 1979 through Deember 1981 in design, analysis, an project management hardware fabrication and procurement, fuel chemistry and properties, and combustor rig tests are summarized.

  7. DESIGNING AN OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION AND COFIRING SAWDUST WITH COAL AT ALBRIGHT GENERATING STATION

    SciTech Connect

    K. Payette; D. Tillman

    2003-04-30

    During the period January 1, 2003--March 31, 2003, Allegheny Energy Supply Co., LLC (Allegheny) proceeded with improvements to both the Willow Island and Albright Generating Station cofiring systems. These improvements were designed to increase the resource base for the projects, and to address issues that came up during the first year of operations. This report summarizes the activities associated with the Designer Opportunity Fuel program, and demonstrations at Willow Island and Albright Generating Stations.

  8. Municipal Solid Waste Combustion : Fuel Testing and Characterization : Task 1 Report, May 30, 1990-October 1, 1990.

    SciTech Connect

    Bushnell, Dwight J.; Canova, Joseph H.; Dadkhah-Nikoo, Abbas.

    1990-10-01

    The objective of this study is to screen and characterize potential biomass fuels from waste streams. This will be accomplished by determining the types of pollutants produced while burning selected municipal waste, i.e., commercial mixed waste paper residential (curbside) mixed waste paper, and refuse derived fuel. These materials will be fired alone and in combination with wood, equal parts by weight. The data from these experiments could be utilized to size pollution control equipment required to meet emission standards. This document provides detailed descriptions of the testing methods and evaluation procedures used in the combustion testing and characterization project. The fuel samples will be examined thoroughly from the raw form to the exhaust emissions produced during the combustion test of a densified sample.

  9. Open air refuse burning video: Proton Dan the science man explores open air refuse burning

    SciTech Connect

    Eastburn, M.D.; Sipple, J.L.; Deramo, A.R.

    1999-07-01

    The goal of this video is to educate school children to the potential hazards of open air trash burning; to demonstrate alternative ways to dispose of trash; and to motivate students to take action to change the behavior of their parents with regard to trash burning. The burning of household trash, although illegal, is still a common practice in rural areas of Delaware. Enforcement has been difficult because the practice is often performed at night and is done across a wide rural area that is difficult to patrol on a continuing basis. The prohibition on trash burning (revised Regulation 13 of The Delaware Code of Regulations Governing The Control of Air Pollution) has been in effect since 1968, but the public has been slow to comply because trash burning has been practiced for many generations and because much of the public is unaware of the environmental impacts and/or the human health risks. This video may be valuable for other States to use as a public outreach tool regarding their problems with open air refuse burning. The focus of the video is a 7th grade science class is given various assignments relating to Earth Day and preservation of natural resources. Two children in particular are given the assignment to research and report on the hazards of open air trash burning and are asked to investigate alternative ways to dispose of refuse. Upon brainstorming how to find information on the topic, the kids decide to contact the host of a popular children's science show on broadcast television named Proton Dan the Science Man (a fictitious character and show based on Bill Nye the Science Guy). The host then invites the kids to the studio where he films his show and takes them through the topic. The TV host character takes the children to several external locations like a landfill, recycling centers, etc..

  10. Why do UK military personnel refuse the anthrax vaccination?

    PubMed

    Murphy, Dominic; Marteau, Theresa; Hotopf, Matthew; Rona, Roberto J; Wessely, Simon

    2008-09-01

    The purpose of this study was to understand the reasons why some UK military personnel refused the anthrax vaccination. Data were collected from 5,302 members of the UK Armed Forces who had been deployed to Iraq since 2003 and had been offered the anthrax vaccination. As part of a larger questionnaire, information was collected on acceptance or refusal of the vaccination. Twenty-eight percent of participants refused the anthrax vaccination; of these 51% indicated that they refused vaccination because of concern that it was being offered voluntarily. Reasons differed between those deployed during the war-fighting phase in Iraq, who were concerned about being supplied with insufficient or unclear information (75% vs. 66%), and those involved on subsequent deployments, who felt that there was no longer a risk that biological weapons would be used against them (61% vs. 43%). Thus, refusal rates were related to perception of the threat. In addition, our results indicated the importance of providing individuals with relevant information to aid them in making decisions to receive the anthrax vaccination or not. The findings provide evidence that for some people, the policy to increase confidence in the anthrax vaccination program may have led to a decrease in levels of trust.

  11. DESIGNING AN OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION AND COFIRING SAWDUST WITH COAL AT ALBRIGHT GENERATING STATION

    SciTech Connect

    K. Payette; D. Tillman

    2004-01-01

    During the period October 1, 2003-December 31, 2003, Allegheny Energy Supply Co., LLC (Allegheny) continued with demonstration operations at the Willow Island Generating Station and improvements to the Albright Generating Station cofiring systems. The demonstration operations at Willow Island were designed to document integration of biomass cofiring into commercial operations, including evaluating new sources of biomass supply. The Albright improvements were designed to increase the resource base for the projects, and to address issues that came up during the first year of operations. This report summarizes the activities associated with the Designer Opportunity Fuel program, and demonstrations at Willow Island and Albright Generating Stations.

  12. DESIGNING AN OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION AND COFIRING SAWDUST WITH COAL AT ALBRIGHT GENERATING STATION

    SciTech Connect

    K. Payette; D. Tillman

    2003-07-01

    During the period April 1, 2003--June 30, 2003, Allegheny Energy Supply Co., LLC (Allegheny) proceeded with demonstration operations at the Willow Island Generating Station and improvements to the Albright Generating Station cofiring systems. The demonstration operations at Willow Island were designed to document integration of biomass cofiring into commercial operations. The Albright improvements were designed to increase the resource base for the projects, and to address issues that came up during the first year of operations. This report summarizes the activities associated with the Designer Opportunity Fuel program, and demonstrations at Willow Island and Albright Generating Stations.

  13. Microstructural changes in NiFe2O4 ceramics prepared with powders derived from different fuels in sol-gel auto-combustion technique

    NASA Astrophysics Data System (ADS)

    Chauhan, Lalita; Bokolia, Renuka; Sreenivas, K.

    2016-05-01

    Structural properties of Nickel ferrite (NiFe2O4) ceramics prepared from powders derived from sol gel auto-combustion method using different fuels (citric acid, glycine and Dl-alanine) are compared. Changes in the structural properties at different sintering temperatures are investigated. X-ray diffraction (XRD) confirms the formation of single phase material with cubic structure. Ceramics prepared using the different powders obtained from different fuels show that that there are no significant changes in lattice parameters. However increasing sintering temperatures show significant improvement in density and grain size. The DL-alanine fuel is found to be the most effective fuel for producing NIFe2O4 powders by the sol-gel auto combustion method and yields highly crystalline powders in the as-burnt stage itself at a low temperature (80 °C). Subsequent use of the powders in ceramic manufacturing produces dense NiFe2O4 ceramics with a uniform microstructure and a large grain size.

  14. Performance characteristics of a diesel engine using low- and medium-energy gases as a fuel supplement (fumigation)

    NASA Technical Reports Server (NTRS)

    Monford, L. G.

    1976-01-01

    The use of low- and medium-energy gases derived from solid waste is investigated. Gases that simulate those gases that could be derived from refuse were injected into the air inlet of a 298-kilowatt (400 horsepower) diesel engine as a fuel supplement. This process is called fumigation. Three different gases with thermal-energy contents of 6.11 MJ/cu m (164 Btu/cu ft), 18.1 MJ/cu m (485 Btu/cu ft), and 18.8 MJ/cu m (505 Btu/cu ft, respectively, were used at rates ranging as high as 20 percent of the normal fuel oil energy at four different engine load points. The test results indicated approximately 100 percent gas energy utilization with no observable deleterious effect on the engine.

  15. Physicians' refusal to resuscitate at borderline gestational age.

    PubMed

    Mercurio, Mark R

    2005-11-01

    Most neonatologists believe there is a minimal gestational age, below which it is appropriate to refuse to provide resuscitation or intensive care. Determination of this threshold should involve knowledge of the outcome data, but also an understanding of the potential for misuse of these data. In particular, there is a risk of deception, of the parents and of ourselves, due to the uncertainty of the true gestational age, and the "self-fulfilling prophecy" that may occur when a center refuses to try below a certain gestational age because they have had no survivors below that age. Finally, any refusal to treat requires ethical justification. Concepts such as futility and patient's best interest should play a role in the determination of the gestational age threshold, applied in light of the data's inherent weaknesses.

  16. Knowledge-based fault diagnosis system for refuse collection vehicle

    NASA Astrophysics Data System (ADS)

    Tan, CheeFai; Juffrizal, K.; Khalil, S. N.; Nidzamuddin, M. Y.

    2015-05-01

    The refuse collection vehicle is manufactured by local vehicle body manufacturer. Currently; the company supplied six model of the waste compactor truck to the local authority as well as waste management company. The company is facing difficulty to acquire the knowledge from the expert when the expert is absence. To solve the problem, the knowledge from the expert can be stored in the expert system. The expert system is able to provide necessary support to the company when the expert is not available. The implementation of the process and tool is able to be standardize and more accurate. The knowledge that input to the expert system is based on design guidelines and experience from the expert. This project highlighted another application on knowledge-based system (KBS) approached in trouble shooting of the refuse collection vehicle production process. The main aim of the research is to develop a novel expert fault diagnosis system framework for the refuse collection vehicle.

  17. Knowledge-based fault diagnosis system for refuse collection vehicle

    SciTech Connect

    Tan, CheeFai; Juffrizal, K.; Khalil, S. N.; Nidzamuddin, M. Y.

    2015-05-15

    The refuse collection vehicle is manufactured by local vehicle body manufacturer. Currently; the company supplied six model of the waste compactor truck to the local authority as well as waste management company. The company is facing difficulty to acquire the knowledge from the expert when the expert is absence. To solve the problem, the knowledge from the expert can be stored in the expert system. The expert system is able to provide necessary support to the company when the expert is not available. The implementation of the process and tool is able to be standardize and more accurate. The knowledge that input to the expert system is based on design guidelines and experience from the expert. This project highlighted another application on knowledge-based system (KBS) approached in trouble shooting of the refuse collection vehicle production process. The main aim of the research is to develop a novel expert fault diagnosis system framework for the refuse collection vehicle.

  18. Organic reactions for the electrochemical and photochemical production of chemical fuels from CO2--The reduction chemistry of carboxylic acids and derivatives as bent CO2 surrogates.

    PubMed

    Luca, Oana R; Fenwick, Aidan Q

    2015-11-01

    The present review covers organic transformations involved in the reduction of CO2 to chemical fuels. In particular, we focus on reactions of CO2 with organic molecules to yield carboxylic acid derivatives as a first step in CO2 reduction reaction sequences. These biomimetic initial steps create opportunities for tandem electrochemical/chemical reductions. We draw parallels between long-standing knowledge of CO2 reactivity from organic chemistry, organocatalysis, surface science and electrocatalysis. We point out some possible non-faradaic chemical reactions that may contribute to product distributions in the production of solar fuels from CO2. These reactions may be accelerated by thermal effects such as resistive heating and illumination.

  19. A preliminary assessment of the feasibility of deriving liquid and gaseous fuels from grown and waste organics

    NASA Technical Reports Server (NTRS)

    Graham, R. W.; Reynolds, T. W.; Hsu, Y.-Y.

    1976-01-01

    An estimate is obtained of the yearly supply of organic material for conversion to fuels, the energy potential is evaluated, and the fermentation and pyrolysis conversion processes are discussed. An investigation is conducted of the estimated cost of fuel from organics and the conclusions of an overall evaluation are presented. It is found that climate, land availability and economics of agricultural production and marketing, food demand, fertilizer shortage, and water availability combine to cast doubts on the feasibility of producing grown organic matter for fuel, in competition with food, feed, or fiber. Less controversial is the utilization of agricultural, industrial, and domestic waste as a conversion feedstock. The evaluation of a demonstration size system is recommended.

  20. The economical production of alcohol fuels from coal-derived synthesis gas: Case studies, design, and economics

    SciTech Connect

    1995-10-01

    This project is a combination of process simulation and catalyst development aimed at identifying the most economical method for converting coal to syngas to linear higher alcohols to be used as oxygenated fuel additives. There are two tasks. The goal of Task 1 is to discover, study, and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas, and to explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. The goal of Task 2 is to simulate, by computer, energy efficient and economically efficient processes for converting coal to energy (fuel alcohols and/or power). The primary focus is to convert syngas to fuel alcohols. This report contains results from Task 2. The first step for Task 2 was to develop computer simulations of alternative coal to syngas to linear higher alcohol processes, to evaluate and compare the economics and energy efficiency of these alternative processes, and to make a preliminary determination as to the most attractive process configuration. A benefit of this approach is that simulations will be debugged and available for use when Task 1 results are available. Seven cases were developed using different gasifier technologies, different methods for altering the H{sub 2}/CO ratio of the syngas to the desired 1.1/1, and with the higher alcohol fuel additives as primary products and as by-products of a power generation facility. Texaco, Shell, and Lurgi gasifier designs were used to test gasifying coal. Steam reforming of natural gas, sour gas shift conversion, or pressure swing adsorption were used to alter the H{sub 2}/CO ratio of the syngas. In addition, a case using only natural gas was prepared to compare coal and natural gas as a source of syngas.

  1. DESIGNING AN OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION AND COFIRING SAWDUST WITH COAL AT ALBRIGHT GENERATING STATION

    SciTech Connect

    K. Payette; D. Tillman

    2003-10-01

    During the period July 1, 2003-September 30, 2003, Allegheny Energy Supply Co., LLC (Allegheny) proceeded with demonstration operations at the Willow Island Generating Station and improvements to the Albright Generating Station cofiring systems. The demonstration operations at Willow Island were designed to document integration of bio mass cofiring into commercial operations, including evaluating new sources of biomass supply. The Albright improvements were designed to increase the resource base for the projects, and to address issues that came up during the first year of operations. During this period, a major presentation summarizing the program was presented at the Pittsburgh Coal Conference. This report summarizes the activities associated with the Designer Opportunity Fuel program, and demonstrations at Willow Island and Albright Generating Stations.

  2. Combustion rates of chars from high-volatile fuels for FBC application

    SciTech Connect

    Masi, S.; Salatino, P.; Senneca, O.

    1997-12-31

    The fluidized bed combustion of high volatile fuels is often associated with huge occurrence of comminution phenomena. These result into in-bed generation of substantial amounts of carbon fines which further undergo competitive processes of combustion and elutriation. The small size of carbon fines generated by comminution is such that their further combustion is largely controlled by the intrinsic kinetics of carbon oxidation, alone or in combination with intraparticle diffusion. The competition between fine combustion and elutriation strongly affects the efficiency of fixed carbon conversion and calls for thorough characterization of the combustion kinetics and of residence times of fines in a fluidized bed of coarse solids. In this paper a collection of intrinsic combustion kinetic and porosimetric data for chars from three high-volatile fuels suitable for FBC application is presented. Chars from a Refuse Derived Fuel (RDF), a Tyre Derived Fuel (TDF) and a biomass (Robinia Pseudoacacia) are obtained from devolatilization, in fluidized bed, of fuel samples. Thermogravimetric analysis, mercury porosimetry and helium pycnometry are used to characterize the reactivity and the pore structure of the chars. Combustion rates are characterized over a wide range of temperatures (320--850 C) and oxygen partial pressures, covering the entire range of interest in fluidized bed combustion. Analysis of thermogravimetric and porosimetric data is directed to obtaining the parameters (pre-exponential factors, reaction orders, activation energies, intraparticle diffusivities) of combustion kinetic submodels for application in fluidized bed combustor modeling.

  3. Production of Jet Fuels from Coal Derived Liquids. Volume 9. Results of Bench-Scale and Pilot Plant Testing

    DTIC Science & Technology

    1989-06-01

    Amoco Oil Company has conducted bench- and pilot plant-scale experiments to produce jet fuels from the tar oil from the Great Plains Coal ... Gasification Plant in Beulah, North Dakota. Experiments show that the hydroprocessing conditions recommended in Task I are not severe enough to saturate the

  4. Toxicity of water-soluble fractions of biodiesel fuels derived from castor oil, palm oil, and waste cooking oil.

    PubMed

    Leite, Maria Bernadete Neiva Lemos; de Araújo, Milena Maria Sampaio; Nascimento, Iracema Andrade; da Cruz, Andrea Cristina Santos; Pereira, Solange Andrade; do Nascimento, Núbia Costa

    2011-04-01

    Concerns over the sustained availability of fossil fuels and their impact on global warming and pollution have led to the search for fuels from renewable sources to address worldwide rising energy demands. Biodiesel is emerging as one of the possible solutions for the transport sector. It shows comparable engine performance to that of conventional diesel fuel, while reducing greenhouse gas emissions. However, the toxicity of products and effluents from the biodiesel industry has not yet been sufficiently investigated. Brazil has a very high potential as a biodiesel producer, in view of its climatic conditions and vast areas for cropland, with consequent environmental risks because of possible accidental biodiesel spillages into water bodies and runoff to coastal areas. This research determined the toxicity to two marine organisms of the water-soluble fractions (WSF) of three different biodiesel fuels obtained by methanol transesterification of castor oil (CO), palm oil (PO), and waste cooking oil (WCO). Microalgae and sea urchins were used as the test organisms, respectively, for culture-growth-inhibition and early-life-stage-toxicity tests. The toxicity levels of the analyzed biodiesel WSF showed the highest toxicity for the CO, followed by WCO and the PO. Methanol was the most prominent contaminant; concentrations increased over time in WSF samples stored up to 120 d.

  5. Fuel flexible fuel injector

    DOEpatents

    Tuthill, Richard S; Davis, Dustin W; Dai, Zhongtao

    2015-02-03

    A disclosed fuel injector provides mixing of fuel with airflow by surrounding a swirled fuel flow with first and second swirled airflows that ensures mixing prior to or upon entering the combustion chamber. Fuel tubes produce a central fuel flow along with a central airflow through a plurality of openings to generate the high velocity fuel/air mixture along the axis of the fuel injector in addition to the swirled fuel/air mixture.

  6. 76 FR 29796 - Agency Information Collection Activities; Submission for OMB Review; Comment Request; Refuse...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-23

    ...; Refuse Piles and Impounding Structures, Recordkeeping and Reporting Requirements ACTION: Notice. SUMMARY... information collection request (ICR) titled, ``Refuse Piles and Impounding Structures, Recordkeeping and... agency generally cannot conduct or sponsor a collection of information, and the public is generally...

  7. DESIGNING AN OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION AND COFIRING SAWDUST WITH COAL AT ALBRIGHT GENERATING STATION

    SciTech Connect

    K. Payette; D. Tillman

    2002-01-01

    During the period October 1, 2001--December 31, 2001, Allegheny Energy Supply Co., LLC (Allegheny) completed construction of the Willow Island cofiring project. This included completion of the explosion proof electrical wiring, the control system, and the control software. Procedures for system checkout, shakedown, and initial operation were initiated during this period. During this time period the 100-hour test of the Albright Generating Station cofiring facility was completed. The testing demonstrated that cofiring at the Albright Generating Station could reliably contribute to a ''4P Strategy''--reduction of SO{sub 2}, NO{sub x}, mercury, and greenhouse gas emissions over a significant load range. During this period of time Allegheny Energy conducted facility tours of both Albright and Willow Island for the Biomass Interest Group of the Electric Power Research Institute. This report summarizes the activities associated with the Designer Opportunity Fuel program, and demonstrations at Willow Island and Albright Generating Stations. It details the completion of construction activities at the Willow Island site along with the 100-hr test at the Albright site.

  8. 7 CFR 322.10 - Inspection; refusal of entry.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation of Adult Honeybees, Honeybee Germ Plasm, and Bees Other Than Honeybees From Approved Regions § 322.10 Inspection; refusal of entry. (a) Shipments of honeybees, honeybee germ plasm, and bees other than...

  9. 7 CFR 322.10 - Inspection; refusal of entry.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation of Adult Honeybees, Honeybee Germ Plasm, and Bees Other Than Honeybees From Approved Regions § 322.10 Inspection; refusal of entry. (a) Shipments of honeybees, honeybee germ plasm, and bees other than...

  10. 7 CFR 322.34 - Inspection; refusal of entry.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 5 2014-01-01 2014-01-01 false Inspection; refusal of entry. 322.34 Section 322.34 Agriculture Regulations of the Department of Agriculture (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation...

  11. 7 CFR 322.34 - Inspection; refusal of entry.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 5 2013-01-01 2013-01-01 false Inspection; refusal of entry. 322.34 Section 322.34 Agriculture Regulations of the Department of Agriculture (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation...

  12. 7 CFR 322.10 - Inspection; refusal of entry.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation of Adult Honeybees, Honeybee Germ Plasm, and Bees Other Than Honeybees From Approved Regions § 322.10 Inspection; refusal of entry. (a) Shipments of honeybees, honeybee germ plasm, and bees other than...

  13. 7 CFR 322.19 - Inspection; refusal of entry.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 5 2012-01-01 2012-01-01 false Inspection; refusal of entry. 322.19 Section 322.19 Agriculture Regulations of the Department of Agriculture (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation...

  14. 7 CFR 322.34 - Inspection; refusal of entry.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 5 2010-01-01 2010-01-01 false Inspection; refusal of entry. 322.34 Section 322.34 Agriculture Regulations of the Department of Agriculture (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation...

  15. 7 CFR 322.19 - Inspection; refusal of entry.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 5 2013-01-01 2013-01-01 false Inspection; refusal of entry. 322.19 Section 322.19 Agriculture Regulations of the Department of Agriculture (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation...

  16. 7 CFR 322.34 - Inspection; refusal of entry.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 5 2011-01-01 2011-01-01 false Inspection; refusal of entry. 322.34 Section 322.34 Agriculture Regulations of the Department of Agriculture (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation...

  17. 7 CFR 322.34 - Inspection; refusal of entry.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 5 2012-01-01 2012-01-01 false Inspection; refusal of entry. 322.34 Section 322.34 Agriculture Regulations of the Department of Agriculture (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation...

  18. 7 CFR 322.19 - Inspection; refusal of entry.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 5 2014-01-01 2014-01-01 false Inspection; refusal of entry. 322.19 Section 322.19 Agriculture Regulations of the Department of Agriculture (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation...

  19. 7 CFR 322.10 - Inspection; refusal of entry.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation of Adult Honeybees, Honeybee Germ Plasm, and Bees Other Than Honeybees From Approved Regions § 322.10 Inspection; refusal of entry. (a) Shipments of honeybees, honeybee germ plasm, and bees other than...

  20. 7 CFR 322.10 - Inspection; refusal of entry.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS, AND BEEKEEPING EQUIPMENT Importation of Adult Honeybees, Honeybee Germ Plasm, and Bees Other Than Honeybees From Approved Regions § 322.10 Inspection; refusal of entry. (a) Shipments of honeybees, honeybee germ plasm, and bees other than...

  1. 21 CFR 211.50 - Sewage and refuse.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 4 2010-04-01 2010-04-01 false Sewage and refuse. 211.50 Section 211.50 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS: GENERAL CURRENT GOOD MANUFACTURING PRACTICE FOR FINISHED PHARMACEUTICALS Buildings and Facilities § 211.50...

  2. Pervasive refusal syndrome among asylum-seeking children.

    PubMed

    Von Folsach, Liv Lyngå; Montgomery, Edith

    2006-07-01

    A number of asylum-seeking children in Sweden have developed a pervasive loss of function associated with profound social withdrawal. The syndrome is called Depressive Devitalization. The aim of this study was to identify possible aetiological factors, outline the similarities between Depressive Devitalization and Pervasive Refusal Syndrome and to explore possible differential diagnoses. The research was based on a literature study. Databases searched included PsychINFO, Medline, Pub med, COCHRANE and PILOTS. Possible aetiological factors identified included: Children having a perfectionist, ambitious and conscientious premorbid personality, psychiatric problems of children and parents, and traumatic events. Symptoms between the two syndromes differed only in pattern of refusal and neurological symptoms. None of the differential diagnoses explored could account for all features. The individual impact of aetiological factors requires further investigation. Children might previously have been diagnosed with a number of differential diagnoses, though none of these accounts for all symptoms seen in the syndromes. Depressive Devitalization and Pervasive Refusal Syndrome are suggested to be subgroups of the same refusal syndrome.

  3. 22 CFR 42.81 - Procedure in refusing individual visas.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ..., Application for Immigrant Visa and Alien Registration, or Form DS-260, Electronic Application for Immigrant Visa and Alien Registration, has been executed by the applicant. When an immigrant visa is refused, an... of additional evidence and the applicant indicates an intention to submit such evidence,...

  4. 22 CFR 42.81 - Procedure in refusing individual visas.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ..., Application for Immigrant Visa and Alien Registration, or Form DS-260, Electronic Application for Immigrant Visa and Alien Registration, has been executed by the applicant. When an immigrant visa is refused, an... of additional evidence and the applicant indicates an intention to submit such evidence,...

  5. 22 CFR 41.121 - Refusal of individual visas.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... overcome by the presentation of additional evidence, the officer shall so inform the alien. The consular...), INA 221(g), or INA 222(g) or other applicable law. Certain classes of nonimmigrant aliens are exempted... ineligible and refuses the issuance of a visa, he or she must inform the alien of the ground(s)...

  6. Treating Total Liquid Refusal with Backward Chaining and Fading.

    ERIC Educational Resources Information Center

    Hagopian, Louis P.; And Others

    1996-01-01

    In this study of a 12-year-old boy with autism, mental retardation, and a history of severe gastrointestinal problems, who refused liquids and food, backward chaining was used to shape drinking from a cup and a fading procedure was used to increase the water he was required to drink. (Author/CR)

  7. 50 CFR 14.53 - Detention and refusal of clearance.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 50 Wildlife and Fisheries 1 2010-10-01 2010-10-01 false Detention and refusal of clearance. 14.53 Section 14.53 Wildlife and Fisheries UNITED STATES FISH AND WILDLIFE SERVICE, DEPARTMENT OF THE INTERIOR TAKING, POSSESSION, TRANSPORTATION, SALE, PURCHASE, BARTER, EXPORTATION, AND IMPORTATION OF WILDLIFE...

  8. [Anorexia and refusal to eat in the elderly].

    PubMed

    Hazif-Thomas, Cyril; Thomas, Philippe

    2016-01-01

    The question of the links between anorexia and the refusal to eat in the elderly is often the cause of major difficulties with regard to therapeutic strategies within caregiving teams. Likewise, few studies have been carried out into the diachronic links between teenage anorexia and that of the elderly. The role of the multi-disciplinary team is essential.

  9. Descriptive Analyses of Pediatric Food Refusal and Acceptance

    ERIC Educational Resources Information Center

    Borrero, Carrie S. W.; Woods, Julia N.; Borrero, John C.; Masler, Elizabeth A.; Lesser, Aaron D.

    2010-01-01

    Functional analyses of inappropriate mealtime behavior typically include conditions to determine if the contingent delivery of attention, tangible items, or escape reinforce food refusal. In the current investigation, descriptive analyses were conducted for 25 children who had been admitted to a program for the assessment and treatment of food…

  10. [Refusal of personal hygiene care and nursing responsibility].

    PubMed

    Peyé, Anne

    2013-03-01

    Situations of patients refusing personal hygiene care are frequent. Sources of difficulties and questioning for caregivers, they can lead to maltreatment. In order to avoid this pitfall, it is essential to support the teams in their approach around representations of caregiving and nursing responsibility.

  11. Invitation Refusals in Cameroon French and Hexagonal French

    ERIC Educational Resources Information Center

    Farenkia, Bernard Mulo

    2015-01-01

    Descriptions of regional pragmatic variation in French are lacking to date the focus has been on a limited range of speech acts, including apologies, requests, compliments and responses to compliments. The present paper, a systematic analysis of invitation refusals across regional varieties of French, is designed to add to the research on…

  12. Understanding Excessive School Absenteeism as School Refusal Behavior

    ERIC Educational Resources Information Center

    Dube, Shanta R.; Orpinas, Pamela

    2009-01-01

    Understanding excessive absenteeism is important to ameliorating the negative outcomes associated with the behavior. The present study examined behavioral reinforcement profiles of school refusal behavior: negative reinforcement (avoidance) and positive reinforcement (gaining parental attention or receiving tangible benefits from not attending…

  13. 48 CFR 807.304-77 - Right of first refusal.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... a result of the anticipated contract from the servicing Human Resources Service office. The list... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false Right of first refusal. 807.304-77 Section 807.304-77 Federal Acquisition Regulations System DEPARTMENT OF VETERANS...

  14. 7 CFR 29.93 - When appeal may be refused.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 2 2014-01-01 2014-01-01 false When appeal may be refused. 29.93 Section 29.93 Agriculture Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards, Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE COMMODITY STANDARDS AND STANDARD...

  15. 21 CFR 514.111 - Refusal to approve an application.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 6 2011-04-01 2011-04-01 false Refusal to approve an application. 514.111 Section 514.111 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES... evaluate the safety of such drugs, are appropriate for the use of animal experimentation data; and...

  16. 21 CFR 514.111 - Refusal to approve an application.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 6 2013-04-01 2013-04-01 false Refusal to approve an application. 514.111 Section 514.111 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES... evaluate the safety of such drugs, are appropriate for the use of animal experimentation data; and...

  17. 21 CFR 514.111 - Refusal to approve an application.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 6 2012-04-01 2012-04-01 false Refusal to approve an application. 514.111 Section 514.111 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES... evaluate the safety of such drugs, are appropriate for the use of animal experimentation data; and...

  18. 21 CFR 1.94 - Hearing on refusal of admission.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 1 2012-04-01 2012-04-01 false Hearing on refusal of admission. 1.94 Section 1.94 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES GENERAL GENERAL... written notice to that effect, stating the reasons therefor. The notice shall specify a place and a...

  19. 21 CFR 514.111 - Refusal to approve an application.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... substance formed in or on food because of the use of such drug; (ii) The cumulative effect on man or animal... 21 Food and Drugs 6 2014-04-01 2014-04-01 false Refusal to approve an application. 514.111 Section 514.111 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN...

  20. 21 CFR 1.94 - Hearing on refusal of admission.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 1 2013-04-01 2013-04-01 false Hearing on refusal of admission. 1.94 Section 1.94 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES GENERAL GENERAL... written notice to that effect, stating the reasons therefor. The notice shall specify a place and a...