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Sample records for relaxation time scale

  1. Current relaxation time scales in toroidal plasmas

    SciTech Connect

    Mikkelsen, D.R.

    1987-02-01

    An approximate normal mode analysis of plasma current diffusion in tokamaks is presented. The work is based on numerical solutions of the current diffusion equation in cylindrical geometry. Eigenvalues and eigenfunctions are shown for a broad range of plasma conductivity profile shapes. Three classes of solutions are considered which correspond to three types of tokamak operation. Convenient approximations to the three lowest eigenvalues in each class are presented and simple formulae for the current relaxation time scales are given.

  2. Various time-scales of relaxation

    NASA Astrophysics Data System (ADS)

    Ali-Akbari, M.; Charmchi, F.; Ebrahim, H.; Shahkarami, L.

    2016-08-01

    Via gauge-gravity duality, relaxation of far-from-equilibrium initial states in a strongly coupled gauge theory has been investigated. In the system we consider in this paper there are two ways where the state under study can deviate from its equilibrium: anisotropic pressure and time-dependent expectation value of a scalar operator with Δ =3 . In the gravity theory, this system corresponds to Einstein's general relativity with a nontrivial metric, including the anisotropy function, coupled to a massive scalar matter field. We study the effect of different initial configurations for the scalar field and anisotropy function on physical processes such as thermalization, i.e., time evolution of an event horizon; equilibration of the expectation value of a scalar operator; and isotropization. We also discuss time ordering of these time-scales.

  3. Role of relaxation time scale in noisy signal transduction.

    PubMed

    Maity, Alok Kumar; Chaudhury, Pinaki; Banik, Suman K

    2015-01-01

    Intra-cellular fluctuations, mainly triggered by gene expression, are an inevitable phenomenon observed in living cells. It influences generation of phenotypic diversity in genetically identical cells. Such variation of cellular components is beneficial in some contexts but detrimental in others. To quantify the fluctuations in a gene product, we undertake an analytical scheme for studying few naturally abundant linear as well as branched chain network motifs. We solve the Langevin equations associated with each motif under the purview of linear noise approximation and derive the expressions for Fano factor and mutual information in close analytical form. Both quantifiable expressions exclusively depend on the relaxation time (decay rate constant) and steady state population of the network components. We investigate the effect of relaxation time constraints on Fano factor and mutual information to indentify a time scale domain where a network can recognize the fluctuations associated with the input signal more reliably. We also show how input population affects both quantities. We extend our calculation to long chain linear motif and show that with increasing chain length, the Fano factor value increases but the mutual information processing capability decreases. In this type of motif, the intermediate components act as a noise filter that tune up input fluctuations and maintain optimum fluctuations in the output. For branched chain motifs, both quantities vary within a large scale due to their network architecture and facilitate survival of living system in diverse environmental conditions.

  4. Active open boundary forcing using dual relaxation time-scales in downscaled ocean models

    NASA Astrophysics Data System (ADS)

    Herzfeld, M.; Gillibrand, P. A.

    2015-05-01

    Regional models actively forced with data from larger scale models at their open boundaries often contain motion at different time-scales (e.g. tidal and low frequency). These motions are not always individually well specified in the forcing data, and one may require a more active boundary forcing while the other exert less influence on the model interior. If a single relaxation time-scale is used to relax toward these data in the boundary equation, then this may be difficult. The method of fractional steps is used to introduce dual relaxation time-scales in an open boundary local flux adjustment scheme. This allows tidal and low frequency oscillations to be relaxed independently, resulting in a better overall solution than if a single relaxation parameter is optimized for tidal (short relaxation) or low frequency (long relaxation) boundary forcing. The dual method is compared to the single relaxation method for an idealized test case where a tidal signal is superimposed on a steady state low frequency solution, and a real application where the low frequency boundary forcing component is derived from a global circulation model for a region extending over the whole Great Barrier Reef, and a tidal signal subsequently superimposed.

  5. Attractors of relaxation discrete-time systems with chaotic dynamics on a fast time scale.

    PubMed

    Maslennikov, Oleg V; Nekorkin, Vladimir I

    2016-07-01

    In this work, a new type of relaxation systems is considered. Their prominent feature is that they comprise two distinct epochs, one is slow regular motion and another is fast chaotic motion. Unlike traditionally studied slow-fast systems that have smooth manifolds of slow motions in the phase space and fast trajectories between them, in this new type one observes, apart the same geometric objects, areas of transient chaos. Alternating periods of slow regular motions and fast chaotic ones as well as transitions between them result in a specific chaotic attractor with chaos on a fast time scale. We formulate basic properties of such attractors in the framework of discrete-time systems and consider several examples. Finally, we provide an important application of such systems, the neuronal electrical activity in the form of chaotic spike-burst oscillations.

  6. NMR permeability estimators in `chalk' carbonate rocks obtained under different relaxation times and MICP size scalings

    NASA Astrophysics Data System (ADS)

    Rios, Edmilson Helton; Figueiredo, Irineu; Moss, Adam Keith; Pritchard, Timothy Neil; Glassborow, Brent Anthony; Domingues, Ana Beatriz Guedes; Azeredo, Rodrigo Bagueira de Vasconcellos

    2016-07-01

    The effect of the selection of different nuclear magnetic resonance (NMR) relaxation times for permeability estimation is investigated for a set of fully brine-saturated rocks acquired from Cretaceous carbonate reservoirs in the North Sea and Middle East. Estimators that are obtained from the relaxation times based on the Pythagorean means are compared with estimators that are obtained from the relaxation times based on the concept of a cumulative saturation cut-off. Select portions of the longitudinal (T1) and transverse (T2) relaxation-time distributions are systematically evaluated by applying various cut-offs, analogous to the Winland-Pittman approach for mercury injection capillary pressure (MICP) curves. Finally, different approaches to matching the NMR and MICP distributions using different mean-based scaling factors are validated based on the performance of the related size-scaled estimators. The good results that were obtained demonstrate possible alternatives to the commonly adopted logarithmic mean estimator and reinforce the importance of NMR-MICP integration to improving carbonate permeability estimates.

  7. NMR permeability estimators in 'chalk' carbonate rocks obtained under different relaxation times and MICP size scalings

    NASA Astrophysics Data System (ADS)

    Rios, Edmilson Helton; Figueiredo, Irineu; Moss, Adam Keith; Pritchard, Timothy Neil; Glassborow, Brent Anthony; Guedes Domingues, Ana Beatriz; Bagueira de Vasconcellos Azeredo, Rodrigo

    2016-07-01

    The effect of the selection of different nuclear magnetic resonance (NMR) relaxation times for permeability estimation is investigated for a set of fully brine-saturated rocks acquired from Cretaceous carbonate reservoirs in the North Sea and Middle East. Estimators that are obtained from the relaxation times based on the Pythagorean means are compared with estimators that are obtained from the relaxation times based on the concept of a cumulative saturation cut-off. Select portions of the longitudinal (T1) and transverse (T2) relaxation-time distributions are systematically evaluated by applying various cut-offs, analogous to the Winland-Pittman approach for mercury injection capillary pressure (MICP) curves. Finally, different approaches to matching the NMR and MICP distributions using different mean-based scaling factors are validated based on the performance of the related size-scaled estimators. The good results that were obtained demonstrate possible alternatives to the commonly adopted logarithmic mean estimator and reinforce the importance of NMR-MICP integration to improving carbonate permeability estimates.

  8. Rotational relaxation time as unifying time scale for polymer and fiber drag reduction.

    PubMed

    Boelens, A M P; Muthukumar, M

    2016-05-01

    Using hybrid direct numerical simulation plus Langevin dynamics, a comparison is performed between polymer and fiber stress tensors in turbulent flow. The stress tensors are found to be similar, suggesting a common drag reducing mechanism in the onset regime for both flexible polymers and rigid fibers. Since fibers do not have an elastic backbone, this must be a viscous effect. Analysis of the viscosity tensor reveals that all terms are negligible, except the off-diagonal shear viscosity associated with rotation. Based on this analysis, we identify the rotational orientation time as the unifying time scale setting a new time criterion for drag reduction by both flexible polymers and rigid fibers.

  9. Nonadiabatic dynamics of electron transfer in solution: Explicit and implicit solvent treatments that include multiple relaxation time scales

    SciTech Connect

    Schwerdtfeger, Christine A.; Soudackov, Alexander V.; Hammes-Schiffer, Sharon

    2014-01-21

    The development of efficient theoretical methods for describing electron transfer (ET) reactions in condensed phases is important for a variety of chemical and biological applications. Previously, dynamical dielectric continuum theory was used to derive Langevin equations for a single collective solvent coordinate describing ET in a polar solvent. In this theory, the parameters are directly related to the physical properties of the system and can be determined from experimental data or explicit molecular dynamics simulations. Herein, we combine these Langevin equations with surface hopping nonadiabatic dynamics methods to calculate the rate constants for thermal ET reactions in polar solvents for a wide range of electronic couplings and reaction free energies. Comparison of explicit and implicit solvent calculations illustrates that the mapping from explicit to implicit solvent models is valid even for solvents exhibiting complex relaxation behavior with multiple relaxation time scales and a short-time inertial response. The rate constants calculated for implicit solvent models with a single solvent relaxation time scale corresponding to water, acetonitrile, and methanol agree well with analytical theories in the Golden rule and solvent-controlled regimes, as well as in the intermediate regime. The implicit solvent models with two relaxation time scales are in qualitative agreement with the analytical theories but quantitatively overestimate the rate constants compared to these theories. Analysis of these simulations elucidates the importance of multiple relaxation time scales and the inertial component of the solvent response, as well as potential shortcomings of the analytical theories based on single time scale solvent relaxation models. This implicit solvent approach will enable the simulation of a wide range of ET reactions via the stochastic dynamics of a single collective solvent coordinate with parameters that are relevant to experimentally accessible

  10. Nonadiabatic dynamics of electron transfer in solution: Explicit and implicit solvent treatments that include multiple relaxation time scales

    NASA Astrophysics Data System (ADS)

    Schwerdtfeger, Christine A.; Soudackov, Alexander V.; Hammes-Schiffer, Sharon

    2014-01-01

    The development of efficient theoretical methods for describing electron transfer (ET) reactions in condensed phases is important for a variety of chemical and biological applications. Previously, dynamical dielectric continuum theory was used to derive Langevin equations for a single collective solvent coordinate describing ET in a polar solvent. In this theory, the parameters are directly related to the physical properties of the system and can be determined from experimental data or explicit molecular dynamics simulations. Herein, we combine these Langevin equations with surface hopping nonadiabatic dynamics methods to calculate the rate constants for thermal ET reactions in polar solvents for a wide range of electronic couplings and reaction free energies. Comparison of explicit and implicit solvent calculations illustrates that the mapping from explicit to implicit solvent models is valid even for solvents exhibiting complex relaxation behavior with multiple relaxation time scales and a short-time inertial response. The rate constants calculated for implicit solvent models with a single solvent relaxation time scale corresponding to water, acetonitrile, and methanol agree well with analytical theories in the Golden rule and solvent-controlled regimes, as well as in the intermediate regime. The implicit solvent models with two relaxation time scales are in qualitative agreement with the analytical theories but quantitatively overestimate the rate constants compared to these theories. Analysis of these simulations elucidates the importance of multiple relaxation time scales and the inertial component of the solvent response, as well as potential shortcomings of the analytical theories based on single time scale solvent relaxation models. This implicit solvent approach will enable the simulation of a wide range of ET reactions via the stochastic dynamics of a single collective solvent coordinate with parameters that are relevant to experimentally accessible

  11. Relaxation times estimation in MRI

    NASA Astrophysics Data System (ADS)

    Baselice, Fabio; Caivano, Rocchina; Cammarota, Aldo; Ferraioli, Giampaolo; Pascazio, Vito

    2014-03-01

    Magnetic Resonance Imaging is a very powerful techniques for soft tissue diagnosis. At the present, the clinical evaluation is mainly conducted exploiting the amplitude of the recorded MR image which, in some specific cases, is modified by using contrast enhancements. Nevertheless, spin-lattice (T1) and spin-spin (T2) relaxation times can play an important role in many pathology diagnosis, such as cancer, Alzheimer or Parkinson diseases. Different algorithms for relaxation time estimation have been proposed in literature. In particular, the two most adopted approaches are based on Least Squares (LS) and on Maximum Likelihood (ML) techniques. As the amplitude noise is not zero mean, the first one produces a biased estimator, while the ML is unbiased but at the cost of high computational effort. Recently the attention has been focused on the estimation in the complex, instead of the amplitude, domain. The advantage of working with real and imaginary decomposition of the available data is mainly the possibility of achieving higher quality estimations. Moreover, the zero mean complex noise makes the Least Square estimation unbiased, achieving low computational times. First results of complex domain relaxation times estimation on real datasets are presented. In particular, a patient with an occipital lesion has been imaged on a 3.0T scanner. Globally, the evaluation of relaxation times allow us to establish a more precise topography of biologically active foci, also with respect to contrast enhanced images.

  12. First Passage Times, Lifetimes, and Relaxation Times of Unfolded Proteins

    NASA Astrophysics Data System (ADS)

    Dai, Wei; Sengupta, Anirvan M.; Levy, Ronald M.

    2015-07-01

    The dynamics of proteins in the unfolded state can be quantified in computer simulations by calculating a spectrum of relaxation times which describes the time scales over which the population fluctuations decay to equilibrium. If the unfolded state space is discretized, we can evaluate the relaxation time of each state. We derive a simple relation that shows the mean first passage time to any state is equal to the relaxation time of that state divided by the equilibrium population. This explains why mean first passage times from state to state within the unfolded ensemble can be very long but the energy landscape can still be smooth (minimally frustrated). In fact, when the folding kinetics is two-state, all of the unfolded state relaxation times within the unfolded free energy basin are faster than the folding time. This result supports the well-established funnel energy landscape picture and resolves an apparent contradiction between this model and the recently proposed kinetic hub model of protein folding. We validate these concepts by analyzing a Markov state model of the kinetics in the unfolded state and folding of the miniprotein NTL9 (where NTL9 is the N -terminal domain of the ribosomal protein L9), constructed from a 2.9 ms simulation provided by D. E. Shaw Research.

  13. Relaxation time in disordered molecular systems

    SciTech Connect

    Rocha, Rodrigo P.; Freire, José A.

    2015-05-28

    Relaxation time is the typical time it takes for a closed physical system to attain thermal equilibrium. The equilibrium is brought about by the action of a thermal reservoir inducing changes in the system micro-states. The relaxation time is intuitively expected to increase with system disorder. We derive a simple analytical expression for this dependence in the context of electronic equilibration in an amorphous molecular system model. We find that the disorder dramatically enhances the relaxation time but does not affect its independence of the nature of the initial state.

  14. Rounded stretched exponential for time relaxation functions.

    PubMed

    Powles, J G; Heyes, D M; Rickayzen, G; Evans, W A B

    2009-12-01

    A rounded stretched exponential function is introduced, C(t)=exp{(tau(0)/tau(E))(beta)[1-(1+(t/tau(0))(2))(beta/2)]}, where t is time, and tau(0) and tau(E) are two relaxation times. This expression can be used to represent the relaxation function of many real dynamical processes, as at long times, t>tau(0), the function converges to a stretched exponential with normalizing relaxation time, tau(E), yet its expansion is even or symmetric in time, which is a statistical mechanical requirement. This expression fits well the shear stress relaxation function for model soft soft-sphere fluids near coexistence, with tau(E)relaxation (both the modulus and viscosity forms). It is shown that both the dielectric spectra and dynamic shear modulus imaginary parts approach the real axis with a slope equal to 0 at high frequency, whereas the dynamic viscosity has an infinite slope in the same limit. This indicates that inertial effects at high frequency are best discerned in the modulus rather than the viscosity Cole-Cole plot. As a consequence of the even expansion in time of the shear stress relaxation function, the value of the storage modulus derived from it at very high frequency exceeds that in the infinite frequency limit (i.e., G(infinity)).

  15. A quantum relaxation-time approximation for finite fermion systems

    SciTech Connect

    Reinhard, P.-G.; Suraud, E.

    2015-03-15

    We propose a relaxation time approximation for the description of the dynamics of strongly excited fermion systems. Our approach is based on time-dependent density functional theory at the level of the local density approximation. This mean-field picture is augmented by collisional correlations handled in relaxation time approximation which is inspired from the corresponding semi-classical picture. The method involves the estimate of microscopic relaxation rates/times which is presently taken from the well established semi-classical experience. The relaxation time approximation implies evaluation of the instantaneous equilibrium state towards which the dynamical state is progressively driven at the pace of the microscopic relaxation time. As test case, we consider Na clusters of various sizes excited either by a swift ion projectile or by a short and intense laser pulse, driven in various dynamical regimes ranging from linear to strongly non-linear reactions. We observe a strong effect of dissipation on sensitive observables such as net ionization and angular distributions of emitted electrons. The effect is especially large for moderate excitations where typical relaxation/dissipation time scales efficiently compete with ionization for dissipating the available excitation energy. Technical details on the actual procedure to implement a working recipe of such a quantum relaxation approximation are given in appendices for completeness.

  16. Mirror cosmological relaxation of the electroweak scale

    NASA Astrophysics Data System (ADS)

    Matsedonskyi, Oleksii

    2016-01-01

    The cosmological relaxation mechanism proposed in [1] allows for a dynamically generated large separation between the weak scale and a theory cutoff, using a sharp change of theory behaviour upon crossing the limit between unbroken and broken symmetry phases. In this note we present a variation of this scenario, in which stabilization of the electroweak scale in the right place is ensured by the Z 2 symmetry exchanging the Standard Model (SM) with its mirror copy. We sketch the possible ways to produce viable thermal evolution of the Universe and discuss experimental accessibility of the new physics effects. We show that in this scenario the mirror SM can either have sizeable couplings with the ordinary one, or, conversely, can interact with it with a negligible strength. The overall cutoff allowed by such a construction can reach 109 GeV.

  17. Spin-Lattice Relaxation Times in 1H NMR Spectroscopy.

    ERIC Educational Resources Information Center

    Wink, Donald J.

    1989-01-01

    Discussed are the mechanisms of nuclear magnetic relaxation, and applications of relaxation times. The measurement of spin-lattice relaxations is reviewed. It is stressed that sophisticated techniques such as these are becoming more important to the working chemist. (CW)

  18. Alternate Forms Reliability of the Behavioral Relaxation Scale: Preliminary Results

    ERIC Educational Resources Information Center

    Lundervold, Duane A.; Dunlap, Angel L.

    2006-01-01

    Alternate forms reliability of the Behavioral Relaxation Scale (BRS; Poppen,1998), a direct observation measure of relaxed behavior, was examined. A single BRS score, based on long duration observation (5-minute), has been found to be a valid measure of relaxation and is correlated with self-report and some physiological measures. Recently,…

  19. Relaxation times and charge conductivity of silicene

    NASA Astrophysics Data System (ADS)

    Mazloom, Azadeh; Parhizgar, Fariborz; Abedinpour, Saeed H.; Asgari, Reza

    2016-07-01

    We investigate the transport and single particle relaxation times of silicene in the presence of neutral and charged impurities. The static charge conductivity is studied using the semiclassical Boltzmann formalism when the spin-orbit interaction is taken into account. The screening is modeled within Thomas-Fermi and random-phase approximations. We show that the transport relaxation time is always longer than the single particle one. Easy electrical controllability of both carrier density and band gap in this buckled two-dimensional structure makes it a suitable candidate for several electronic and optoelectronic applications. In particular, we observe that the dc charge conductivity could be easily controlled through an external electric field, a very promising feature for applications as electrical switches and transistors. Our findings would be qualitatively valid for other buckled honeycomb lattices of the same family, such as germanine and stanine.

  20. Relaxation time measurements by an electronic method.

    NASA Technical Reports Server (NTRS)

    Brousseau, R.; Vanier, J.

    1973-01-01

    Description of a simple electronic system that permits the direct measurement of time constants of decaying signals. The system was used in connection with relaxation experiments on hydrogen and rubidium masers and was found to operate well. The use of a computing counter in the systems gives the possibility of making averages on several experiments and obtaining the standard deviation of the results from the mean. The program for the computing counter is given.

  1. Crossover time in relative fluctuations characterizes the longest relaxation time of entangled polymers

    NASA Astrophysics Data System (ADS)

    Uneyama, Takashi; Akimoto, Takuma; Miyaguchi, Tomoshige

    2012-09-01

    In entangled polymer systems, there are several characteristic time scales, such as the entanglement time and the disengagement time. In molecular simulations, the longest relaxation time (the disengagement time) can be determined by the mean square displacement (MSD) of a segment or by the shear relaxation modulus. Here, we propose the relative fluctuation analysis method, which is originally developed for characterizing large fluctuations, to determine the longest relaxation time from the center of mass trajectories of polymer chains (the time-averaged MSDs). Applying the method to simulation data of entangled polymers (by the slip-spring model and the simple reptation model), we provide a clear evidence that the longest relaxation time is estimated as the crossover time in the relative fluctuations.

  2. Robust solid 129Xe longitudinal relaxation times

    NASA Astrophysics Data System (ADS)

    Limes, M. E.; Ma, Z. L.; Sorte, E. G.; Saam, B.

    2016-09-01

    We find that if solid xenon is formed from liquid xenon, denoted "ice," there is a 10% increase in 129Xe longitudinal relaxation T1 time (taken at 77 K and 2 T) over a trickle-freeze formation, denoted "snow." Forming xenon ice also gives an unprecedented reproducibility of 129Xe T1 measurements across a range of 77-150 K. This temperature dependence roughly follows the theory of spin rotation mediated by Raman scattering of harmonic phonons, though it results in a smaller-than-predicted spin-rotation coupling strength cK 0/h . Enriched ice 129Xe T1 experiments show no isotopic dependence of bulk relaxation mechanisms at 77 K and at kilogauss fields.

  3. Quantitative analysis of conformational exchange contributions to 1H-15N multiple-quantum relaxation using field-dependent measurements. Time scale and structural characterization of exchange in a calmodulin C-terminal domain mutant.

    PubMed

    Lundström, Patrik; Akke, Mikael

    2004-01-28

    Multiple-quantum spin relaxation is a sensitive probe for correlated conformational exchange dynamics on microsecond to millisecond time scales in biomolecules. We measured differential 1H-15N multiple-quantum relaxation rates for the backbone amide groups of the E140Q mutant of the C-terminal domain of calmodulin at three static magnetic field strengths. The differential multiple-quantum relaxation rates range between -88.7 and 92.7 s(-1), and the mean and standard deviation are 7.0 +/- 24 s(-1), at a static magnetic field strength of 14.1 T. Together with values of the 1H and 15N chemical shift anisotropies (CSA) determined separately, the field-dependent data enable separation of the different contributions from dipolar-dipolar, CSA-CSA, and conformational exchange cross-correlated relaxation mechanisms to the differential multiple-quantum relaxation rates. The procedure yields precise quantitative information on the dominant conformational exchange contributions observed in this protein. The field-dependent differences between double- and zero-quantum relaxation rates directly benchmark the rates of conformational exchange, showing that these are fast on the chemical shift time scale for the large majority of residues in the protein. Further analysis of the differential 1H-15N multiple-quantum relaxation rates using previously determined exchange rate constants and populations, obtained from 15N off-resonance rotating-frame relaxation data, enables extraction of the product of the chemical shift differences between the resonance frequencies of the 1H and 15N spins in the exchanging conformations, deltasigma(H)deltasigma(N). Thus, information on the 1H chemical shift differences is obtained, while circumventing complications associated with direct measurements of conformational exchange effects on 1H single-quantum coherences in nondeuterated proteins. The method significantly increases the information content available for structural interpretation of the

  4. Detection of weak signals through nonlinear relaxation times for a Brownian particle in an electromagnetic field.

    PubMed

    Jiménez-Aquino, J I; Romero-Bastida, M

    2011-07-01

    The detection of weak signals through nonlinear relaxation times for a Brownian particle in an electromagnetic field is studied in the dynamical relaxation of the unstable state, characterized by a two-dimensional bistable potential. The detection process depends on a dimensionless quantity referred to as the receiver output, calculated as a function of the nonlinear relaxation time and being a characteristic time scale of our system. The latter characterizes the complete dynamical relaxation of the Brownian particle as it relaxes from the initial unstable state of the bistable potential to its corresponding steady state. The one-dimensional problem is also studied to complement the description.

  5. Characteristic length scales of the secondary relaxations in glass-forming glycerol.

    PubMed

    Gupta, S; Mamontov, E; Jalarvo, N; Stingaciu, L; Ohl, M

    2016-03-01

    We investigate the secondary relaxations and their link to the main structural relaxation in glass-forming liquids using glycerol as a model system. We analyze the incoherent neutron scattering signal dependence on the scattering momentum transfer, Q , in order to obtain the characteristic length scale for different secondary relaxations. Such a capability of neutron scattering makes it somewhat unique and highly complementary to the traditional techniques of glass physics, such as light scattering and broadband dielectric spectroscopy, which provide information on the time scale, but not the length scales, of relaxation processes. The choice of suitable neutron scattering techniques depends on the time scale of the relaxation of interest. We use neutron backscattering to identify the characteristic length scale of 0.7 Å for the faster secondary relaxation described in the framework of the mode-coupling theory (MCT). Neutron spin-echo is employed to probe the slower secondary relaxation of the excess wing type at a low temperature ( ∼ 1.13T g . The characteristic length scale for this excess wing dynamics is approximately 4.7 Å. Besides the Q -dependence, the direct coupling of neutron scattering signal to density fluctuation makes this technique indispensable for measuring the length scale of the microscopic relaxation dynamics. PMID:27021657

  6. Scaling behaviour of relaxation dependencies in metaloxide superconductors

    NASA Technical Reports Server (NTRS)

    Sidorenko, A. S.; Panaitov, G. I.; Gabovich, A. M.; Moiseev, D. P.; Postnikov, V. M.

    1990-01-01

    Superconducting glass state has been investigated in different types of metaloxide ceramics, Y-Ba-Cu-O, Bi-Sr-Ca-Cu-O, Ba-Pb-Bi-O, using the highly sensitive SQUID magnetometer. The analysis of long-time relaxation processes of thermoremanent magnetization m(sup trm) (+) = M(sub o) - Slnt displayed scaling dependence of the decay rate S = -dM/dlnt on quantity of trapped magnetic flux M(sub o): 1gs = 31g M(sub o) - observed universal dependence S is approximately M(sup 3) (sub o) seems to one of the features of superconducting glass state in metaloxide ceramics.

  7. Short-Time Beta Relaxation in Glass-Forming Liquids Is Cooperative in Nature

    NASA Astrophysics Data System (ADS)

    Karmakar, Smarajit; Dasgupta, Chandan; Sastry, Srikanth

    2016-02-01

    Temporal relaxation of density fluctuations in supercooled liquids near the glass transition occurs in multiple steps. Using molecular dynamics simulations for three model glass-forming liquids, we show that the short-time β relaxation is cooperative in nature. Using finite-size scaling analysis, we extract a growing length scale associated with beta relaxation from the observed dependence of the beta relaxation time on the system size. We find, in qualitative agreement with the prediction of the inhomogeneous mode coupling theory, that the temperature dependence of this length scale is the same as that of the length scale that describes the spatial heterogeneity of local dynamics in the long-time α -relaxation regime.

  8. Short-Time Beta Relaxation in Glass-Forming Liquids Is Cooperative in Nature.

    PubMed

    Karmakar, Smarajit; Dasgupta, Chandan; Sastry, Srikanth

    2016-02-26

    Temporal relaxation of density fluctuations in supercooled liquids near the glass transition occurs in multiple steps. Using molecular dynamics simulations for three model glass-forming liquids, we show that the short-time β relaxation is cooperative in nature. Using finite-size scaling analysis, we extract a growing length scale associated with beta relaxation from the observed dependence of the beta relaxation time on the system size. We find, in qualitative agreement with the prediction of the inhomogeneous mode coupling theory, that the temperature dependence of this length scale is the same as that of the length scale that describes the spatial heterogeneity of local dynamics in the long-time α-relaxation regime.

  9. Nuclear Spin Relaxation Times for Methane-Helium ``Slush'' at 4 MHz using Pulsed NMR

    NASA Astrophysics Data System (ADS)

    Hamida, J. A.; Sullivan, N. S.

    2006-09-01

    We report measurements of the nuclear spin-lattice relaxation times (T1) and spin-spin relaxation times (T2) for small grains of methane suspended in liquid helium (methane-helium "slush") for temperatures 2 Krelaxation rate 1/T2 is consistent with internal diffusion as opposed to surface scattering, which has been shown to be dominant for hydrogen-helium "slush". The most interesting feature observed for methane-helium mixtures is the existence of three different time scales for samples aged at 4.2 K. The possible origins of this distribution of relaxation times are discussed.

  10. Clustered continuous-time random walks: diffusion and relaxation consequences

    PubMed Central

    Weron, Karina; Stanislavsky, Aleksander; Jurlewicz, Agnieszka; Meerschaert, Mark M.; Scheffler, Hans-Peter

    2012-01-01

    We present a class of continuous-time random walks (CTRWs), in which random jumps are separated by random waiting times. The novel feature of these CTRWs is that the jumps are clustered. This introduces a coupled effect, with longer waiting times separating larger jump clusters. We show that the CTRW scaling limits are time-changed processes. Their densities solve two different fractional diffusion equations, depending on whether the waiting time is coupled to the preceding jump, or the following one. These fractional diffusion equations can be used to model all types of experimentally observed two power-law relaxation patterns. The parameters of the scaling limit process determine the power-law exponents and loss peak frequencies. PMID:22792038

  11. Cosmological Relaxation of the Electroweak Scale

    NASA Astrophysics Data System (ADS)

    Graham, Peter W.; Kaplan, David E.; Rajendran, Surjeet

    2015-11-01

    A new class of solutions to the electroweak hierarchy problem is presented that does not require either weak-scale dynamics or anthropics. Dynamical evolution during the early Universe drives the Higgs boson mass to a value much smaller than the cutoff. The simplest model has the particle content of the standard model plus a QCD axion and an inflation sector. The highest cutoff achieved in any technically natural model is 108 GeV .

  12. Ultrafast relaxation rates and reversal time in disordered ferrimagnets

    NASA Astrophysics Data System (ADS)

    Suarez, O. J.; Nieves, P.; Laroze, D.; Altbir, D.; Chubykalo-Fesenko, O.

    2015-10-01

    In response to ultrafast laser pulses, single-phase metals have been classified as "fast" (with magnetization quenching on the time scale of the order of 100 fs and recovery in the time scale of several picoseconds and below) and "slow" (with longer characteristic time scales). Disordered ferrimagnetic alloys consisting of a combination of "fast" transition (TM) and "slow" rare-earth (RE) metals have been shown to exhibit an ultrafast all-optical switching mediated by the heat mechanism. The behavior of the characteristic time scales of coupled alloys is more complicated and is influenced by many parameters such as the intersublattice exchange, doping (RE) concentration, and the temperature. Here, the longitudinal relaxation times of each sublattice are analyzed within the Landau-Lifshitz-Bloch framework. We show that for moderate intersublattice coupling strength both materials slow down as a function of slow (RE) material concentration. For larger coupling, the fast (TM) material may become faster, while the slow (RE) one is still slower. These conclusions may have important implications in the switching time of disordered ferrimagnets such as GdFeCo with partial clustering. Using atomistic modeling, we show that in the moderately coupled case, the reversal would start in the Gd-rich region, while the situation may be reversed if the coupling strength is larger.

  13. Times of metastable droplet relaxation to equilibrium states

    NASA Astrophysics Data System (ADS)

    Tovbin, Yu. K.; Komarov, V. N.; Zaitseva, E. S.

    2016-10-01

    Times of metastable droplet relaxation to their equilibrium state are calculated at saturated vapor pressures, depending on the droplet size. It is shown that for small droplets with radius R = 6 molecular diameters (or ~2 nm) the relaxation times are ~1 ns (which is comparable to the characteristic flight times of rarefied gas molecules). For large droplets with radius R ~ 800 molecular diameters, the relaxation times are as long as 10 μs. At a fixed droplet radius (6 ≤ R ≤ 800), the range of variation in relaxation time from the melting point to the critical temperature does not exceed one order of magnitude: the lower the temperature, the slower the relaxation process.

  14. Correlation of transverse relaxation time with structure of biological tissue

    NASA Astrophysics Data System (ADS)

    Furman, Gregory B.; Meerovich, Victor M.; Sokolovsky, Vladimir L.

    2016-09-01

    Transverse spin-spin relaxation of liquids entrapped in nanocavities with different orientational order is theoretically investigated. Based on the bivariate normal distribution of nanocavities directions, we have calculated the anisotropy of the transverse relaxation time for biological systems, such as collagenous tissues, articular cartilage, and tendon. In the framework of the considered model, the dipole-dipole interaction is determined by a single coupling constant. The calculation results for the transverse relaxation time explain the angular dependence observed in MRI experiments with biological objects. The good agreement with the experimental data is obtained by adjustment of only one parameter which characterizes the disorder in fiber orientations. The relaxation time is correlated with the degree of ordering in biological tissues. Thus, microstructure of the tissues can be revealed from the measurement of relaxation time anisotropy. The clinical significance of the correlation, especially in the detection of damage must be evaluated in a large prospective clinical trials.

  15. Occupational Cohort Time Scales

    PubMed Central

    Roth, H. Daniel

    2015-01-01

    Purpose: This study explores how highly correlated time variables (occupational cohort time scales) contribute to confounding and ambiguity of interpretation. Methods: Occupational cohort time scales were identified and organized through simple equations of three time scales (relational triads) and the connections between these triads (time scale web). The behavior of the time scales was examined when constraints were imposed on variable ranges and interrelationships. Results: Constraints on a time scale in a triad create high correlations between the other two time scales. These correlations combine with the connections between relational triads to produce association paths. High correlation between time scales leads to ambiguity of interpretation. Conclusions: Understanding the properties of occupational cohort time scales, their relational triads, and the time scale web is helpful in understanding the origins of otherwise obscure confounding bias and ambiguity of interpretation. PMID:25647318

  16. Relaxation time effects of wave ripples on tidal beaches

    NASA Astrophysics Data System (ADS)

    Austin, M. J.; Masselink, G.; O'Hare, T. J.; Russell, P. E.

    2007-08-01

    Seabed roughness due to wave ripples is a key factor in controlling sediment transport processes in the nearshore zone. Roughness is commonly considered a function of the ripple geometry, which in turn, can be predicted from sediment and hydrodynamic parameters. Existing ripple predictors consider the bed morphology to be in equilibrium with the hydrodynamics, whereas recent laboratory measurements show that the time scale for ripple development is of the order of tens of minutes to hours. Here we show that wave ripples on tidal beaches are significantly affected by relaxation time effects, with ripple height and length progressively increasing during the rising tide and remaining constant during the falling tide. Moreover, we examine the ripples in the context of existing empirical models and suggest how the temporal evolution over a tidal cycle may be predicted.

  17. Dynamics of continuous-time random walk, fractal time dispersion, and fractional exponential time relaxation

    NASA Astrophysics Data System (ADS)

    Liu, Fu-Sui; Chao, Wen

    1989-10-01

    This paper attempts to establish the dynamics of a microscopic model for a continuous-time random walk. The waiting-time distribution Q(t) is derived from the time-dependent perturbation theory of quantum mechanics for the walker's motion coupled with the media. The walker's motion includes the hopping of a localized particle and a spin (or dipole) flip. The medium is modeled as a harmonic heat bath. The walker moves among a set of degenerate localized states. The scaling behavior of the effective spectrum at low frequency with index β is modeled by using stochastic theory. It is found that Q(t)=exp(-at(2-β)) for 0<=β<2 and Q(t)~t-α for β=2. The applications of our theory include dispersion diffusion, the transient drift of hopping control light excitation in a-Si:H, and thermoremanent magnetization relaxation in spin glasses.

  18. Ab Initio Electronic Relaxation Times and Transport in Noble Metals

    NASA Astrophysics Data System (ADS)

    Mustafa, Jamal I.; Bernardi, Marco; Neaton, Jeffrey B.; Louie, Steven G.

    Relaxation times employed to study electron transport in metals are typically assumed to be constants and obtained empirically using the Drude model. Here, we employ ab initio calculations to compute the electron-phonon relaxation times of Cu, Ag, and Au, and find that they vary significantly on the Fermi surface, spanning ~15 -45 fs. We compute room temperature resistivities in excellent agreement with experiment by combining GW bandstructures, Wannier-interpolated band velocities, and ab initio relaxation times. Our calculations are compared to other approximations used for the relaxation times. Additionally, an importance sampling scheme is introduced to speed up the convergence of resistivity and transport calculations by sampling directly points on the Fermi surface. This work was supported by NSF Grant No. DMR15-1508412 and U.S. DOE under Contract No. DE-AC02-05CH11231. Computational resources have been provided by DOE at LBNL's NERSC facility.

  19. Multiple-Relaxation-Time Lattice Boltzmann Models in 3D

    NASA Technical Reports Server (NTRS)

    dHumieres, Dominique; Ginzburg, Irina; Krafczyk, Manfred; Lallemand, Pierre; Luo, Li-Shi; Bushnell, Dennis M. (Technical Monitor)

    2002-01-01

    This article provides a concise exposition of the multiple-relaxation-time lattice Boltzmann equation, with examples of fifteen-velocity and nineteen-velocity models in three dimensions. Simulation of a diagonally lid-driven cavity flow in three dimensions at Re=500 and 2000 is performed. The results clearly demonstrate the superior numerical stability of the multiple-relaxation-time lattice Boltzmann equation over the popular lattice Bhatnagar-Gross-Krook equation.

  20. Relaxation time and elasticity during polymerization with DER 332

    NASA Astrophysics Data System (ADS)

    Venkateshan, K.; Johari, G. P.

    2006-10-01

    To complement a study of the dielectric relaxation time's relation with the velocity of propagation of hypersound wave in a polymerizing liquid [K. Venkateshan and G. P. Johari J. Chem. Phys.125, 014907 (2006)], we report results of an analogous study by using the same diglycidylether of bisphenol-A that had been used for measuring the velocity. The data show that the logarithmic relaxation time increases linearly with the square of the velocity of propagation of transverse hypersound wave.

  1. Landauer’s formula with finite-time relaxation: Kramers’ crossover in electronic transport

    NASA Astrophysics Data System (ADS)

    Gruss, Daniel; Velizhanin, Kirill A.; Zwolak, Michael

    2016-04-01

    Landauer’s formula is the standard theoretical tool to examine ballistic transport in nano- and meso-scale junctions, but it necessitates that any variation of the junction with time must be slow compared to characteristic times of the system, e.g., the relaxation time of local excitations. Transport through structurally dynamic junctions is, however, increasingly of interest for sensing, harnessing fluctuations, and real-time control. Here, we calculate the steady-state current when relaxation of electrons in the reservoirs is present and demonstrate that it gives rise to three regimes of behavior: weak relaxation gives a contact-limited current; strong relaxation localizes electrons, distorting their natural dynamics and reducing the current; and in an intermediate regime the Landauer view of the system only is recovered. We also demonstrate that a simple equation of motion emerges, which is suitable for efficiently simulating time-dependent transport.

  2. Landauer’s formula with finite-time relaxation: Kramers’ crossover in electronic transport

    DOE PAGES

    Gruss, Daniel; Velizhanin, Kirill A.; Zwolak, Michael

    2016-04-20

    Landauer’s formula is the standard theoretical tool to examine ballistic transport in nano- and meso-scale junctions, but it necessitates that any variation of the junction with time must be slow compared to characteristic times of the system, e.g., the relaxation time of local excitations. Transport through structurally dynamic junctions is, however, increasingly of interest for sensing, harnessing fluctuations, and real-time control. Here, we calculate the steady-state current when relaxation of electrons in the reservoirs is present and demonstrate that it gives rise to three regimes of behavior: weak relaxation gives a contact-limited current; strong relaxation localizes electrons, distorting their naturalmore » dynamics and reducing the current; and in an intermediate regime the Landauer view of the system only is recovered. Lastly, we also demonstrate that a simple equation of motion emerges, which is suitable for efficiently simulating time-dependent transport.« less

  3. Landauer’s formula with finite-time relaxation: Kramers’ crossover in electronic transport

    PubMed Central

    Gruss, Daniel; Velizhanin, Kirill A.; Zwolak, Michael

    2016-01-01

    Landauer’s formula is the standard theoretical tool to examine ballistic transport in nano- and meso-scale junctions, but it necessitates that any variation of the junction with time must be slow compared to characteristic times of the system, e.g., the relaxation time of local excitations. Transport through structurally dynamic junctions is, however, increasingly of interest for sensing, harnessing fluctuations, and real-time control. Here, we calculate the steady-state current when relaxation of electrons in the reservoirs is present and demonstrate that it gives rise to three regimes of behavior: weak relaxation gives a contact-limited current; strong relaxation localizes electrons, distorting their natural dynamics and reducing the current; and in an intermediate regime the Landauer view of the system only is recovered. We also demonstrate that a simple equation of motion emerges, which is suitable for efficiently simulating time-dependent transport. PMID:27094206

  4. Femtosecond time-resolved electronic relaxation dynamics in tetrathiafulvalene

    SciTech Connect

    Staedter, D.; Polizzi, L.; Thiré, N.; Mairesse, Y.; Mayer, P.; Blanchet, V.

    2015-05-21

    In the present paper, the ultrafast electronic relaxation of tetrathiafulvalene (TTF) initiated around 4 eV is studied by femtosecond time-resolved velocity-map imaging. The goal is to investigate the broad double structure observed in the absorption spectrum at this energy. By monitoring the transients of the parent cation and its fragments and by varying the pump and the probe wavelengths, two internal conversions and intramolecular vibrational relaxation are detected both on the order of a few hundred of femtoseconds. Photoelectron images permit the assignment of a dark electronic state involved in the relaxation. In addition, the formation of the dimer of TTF has been observed.

  5. Analysis of the Palierne model by relaxation time spectrum

    NASA Astrophysics Data System (ADS)

    Kwon, Mi Kyung; Cho, Kwang Soo

    2016-02-01

    Viscoelasticity of immiscible polymer blends is affected by relaxation of the interface. Several attempts have been made for linear viscoelasticity of immiscible polymer blends. The Palierne model (1990) and the Gramespacher-Meissner model (1992) are representative. The Gramespacher-Meissner model consists of two parts: ingredients and interface. Moreover, it provides us the formula of the peak of interface in weighted relaxation time spectrum, which enables us to analyze the characteristics relating to interface more obviously. However, the Gramespacher-Meissner model is a kind of empirical model. Contrary to the Gramespacher-Meissner model, the Palierne model was derived in a rigorous manner. In this study, we investigated the Palierne model through the picture of the Gramespacher-Meissner model. We calculated moduli of immiscible blend using two models and obtained the weighted relaxation time spectra of them. The fixed-point iteration of Cho and Park (2013) was used in order to determine the weighted relaxation spectra.

  6. Evaluation of brain edema using magnetic resonance proton relaxation times

    SciTech Connect

    Fu, Y.; Tanaka, K.; Nishimura, S. )

    1990-01-01

    Experimental and clinical studies on the evaluation of water content in cases of brain edema were performed in vivo, using MR proton relaxation times (longitudinal relaxation time, T1; transverse relaxation time, T2). Brain edema was produced in the white matter of cats by the direct infusion method. The correlations between proton relaxation times obtained from MR images and the water content of white matter were studied both in autoserum-infused cats and in saline-infused cats. The correlations between T1 as well as T2 and the water content in human vasogenic brain edema were also examined and compared with the data obtained from the serum group. T1 and T2 showed good correlations with the water content of white matter not only in the experimental animals but also in the clinical cases. The quality of the edema fluid did not influence relaxation time and T1 seemed to represent almost solely the water content of the tissue. T2, however, was affected by the nature of existence of water and was more sensitive than T1 in detecting extravasated edema fluid. It seems feasible therefore to evaluate the water content of brain edema on the basis of T1 values.

  7. Mindfulness meditation and relaxation training increases time sensitivity.

    PubMed

    Droit-Volet, S; Fanget, M; Dambrun, M

    2015-01-01

    Two experiments examined the effect of mindfulness meditation and relaxation on time perception using a temporal bisection task. In Experiment 1, the participants performed a temporal task before and after exercises of mindfulness meditation or relaxation. In Experiment 2, the procedure was similar than that used in Experiment 1, except that the participants were trained to mediate or relax every day over a period of several weeks. The results showed that mindfulness meditation exercises increased sensitivity to time and lengthened perceived time. However, this temporal improvement with meditation exercises was primarily observed in the experienced meditators. Our results also showed the experienced meditators were less anxious than the novice participants, and that the sensitivity to time increased when the level of anxiety decreased. Our results were explained by the practice of mindfulness technique that had developed individuals' abilities in devoting more attention resources to temporal information processing.

  8. Real-time relaxation and kinetics in hot scalar QED: Landau damping

    SciTech Connect

    Boyanovsky, D.; de Vega, H.J.; Holman, R.; Kumar, S.P.; Pisarski, R.D.

    1998-12-01

    The real time evolution of non-equilibrium expectation values with soft length scales {approximately}k{sup {minus}1}{gt}(eT){sup {minus}1} is solved in hot scalar electrodynamics, with a view towards understanding relaxational phenomena in the QGP and the electroweak plasma. We find that the gauge invariant non-equilibrium expectation values relax via {ital power laws} to asymptotic amplitudes that are determined by the quasiparticle poles. The long time relaxational dynamics and relevant time scales are determined by the behavior of the retarded self-energy not at the small frequencies, but at the Landau damping thresholds. This explains the presence of power laws and not of exponential decay. In the process we rederive the HTL effective action using {ital non-equilibrium} field theory. Furthermore we obtain the influence functional, the Langevin equation and the fluctuation-dissipation theorem for the soft modes, identifying the correlators that emerge in the classical limit. We show that a Markovian approximation fails to describe the dynamics {ital both} at short and long times. We find that the distribution function for soft quasiparticles relaxes with a power law through Landau damping. We also introduce a novel kinetic approach that goes beyond the standard Boltzmann equation by incorporating off-shell processes and find that the distribution function for soft quasiparticles relaxes with a power law through Landau damping. We find an unusual dressing dynamics of bare particles and anomalous (logarithmic) relaxation of hard quasiparticles. {copyright} {ital 1998} {ital The American Physical Society}

  9. Ensemble Pulsar Time Scale

    NASA Astrophysics Data System (ADS)

    Yin, D. S.; Gao, Y. P.; Zhao, S. H.

    2016-05-01

    Millisecond pulsars can generate another type of time scale that is totally independent of the atomic time scale, because the physical mechanisms of the pulsar time scale and the atomic time scale are quite different from each other. Usually the pulsar timing observational data are not evenly sampled, and the internals between data points range from several hours to more than half a month. What's more, these data sets are sparse. And all these make it difficult to generate an ensemble pulsar time scale. Hence, a new algorithm to calculate the ensemble pulsar time scale is proposed. Firstly, we use cubic spline interpolation to densify the data set, and make the intervals between data points even. Then, we employ the Vondrak filter to smooth the data set, and get rid of high-frequency noise, finally adopt the weighted average method to generate the ensemble pulsar time scale. The pulsar timing residuals represent clock difference between the pulsar time and atomic time, and the high precision pulsar timing data mean the clock difference measurement between the pulsar time and atomic time with a high signal to noise ratio, which is fundamental to generate pulsar time. We use the latest released NANOGRAV (North American Nanohertz Observatory for Gravitational Waves) 9-year data set to generate the ensemble pulsar time scale. This data set is from the newest NANOGRAV data release, which includes 9-year observational data of 37 millisecond pulsars using the 100-meter Green Bank telescope and 305-meter Arecibo telescope. We find that the algorithm used in this paper can lower the influence caused by noises in timing residuals, and improve long-term stability of pulsar time. Results show that the long-term (> 1 yr) frequency stability of the pulsar time is better than 3.4×10-15.

  10. Phenomenological Theory of the Translational Relaxation Times in Gases

    NASA Technical Reports Server (NTRS)

    Zuckerwar, Allan J.

    1999-01-01

    The exact solution to the classical equations governing the translational dispersion and absorption of sound in a gas obscures its relaxational character because of its mathematical complexity. The approach taken here is to solve the secular equation by the method of Pade approximants, which even to the relatively low order R(sub 11) yields a remarkably close approximation to the exact solution over a wide range of frequency/pressure (f/P) ratios. As a result, translational relaxation can be formulated in terms of a conventional relaxation process with well-defined relaxation times, relaxation strength, collision numbers, additivity relations, etc. To extend the theory to high values of f/P ratio, a model is proposed to account for the noncontinuum behavior of the transport coefficients (viscosity and thermal conductivity) as the molecular mean free path approaches the acoustical enclosure dimensions. The theoretical dispersion and absorption show good agreement with measurements in argon over the classical and transition regions of f/P, but a discrepancy appears at higher values of f/P, where collective propagating modes, assumed in the theory, give way to single-particle modes, prevailing in the experiments.

  11. Relaxation Characteristics of 828 DGEBA Epoxy Over Long Time Periods

    NASA Astrophysics Data System (ADS)

    Hoo, Jasmine; Reprogle, Riley C.; Wisler, Brian; Arechederra, Gabriel K.; McCoy, John D.; Kropka, Jamie M.; Long, Kevin N.

    The mechanical relaxation response in uniaxial compression of a diglycidyl ether of bisphenol-A epoxy was studied over long time periods. The epoxy, 828DEA, was Epon 828 cured with diethanolamine (DEA). A sample was compressed at constant strain rate and held at various strain levels for days to allow the sample to relax. The sample was then compressed further and held once more. The relaxation curves were fit with a stretched exponential function. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under Contract DE-AC04-94AL85000.

  12. Electron–ion relaxation time in moderately degenerate plasma

    SciTech Connect

    Vronskii, M. A. Koryakina, Yu. V.

    2015-09-15

    A formula is derived for the electron–ion relaxation time in a partially degenerate plasma with electron-ion interaction via a central field. The resulting expression in the form of an integral of the transport cross section generalizes the well-known Landau and Brysk approximations.

  13. Modeling the Relaxation Time of DNA Confined in a Nanochannel

    NASA Astrophysics Data System (ADS)

    Wang, Yanwei; Tree, Douglas R.; Dorfman, Kevin D.

    2014-03-01

    Using a mapping between a dumbbell model and fine-grained Monte Carlo simulations, we have computed the relaxation time of λ-DNA in a high ionic strength buffer confined in a nanochannel (Tree et al., Biomicrofluidics 2013, 7, 054118). The relaxation time thus obtained agrees quantitatively with experimental data (Reisner et al., PRL 2005, 94, 196101) using only a single O(1) fitting parameter to account for the uncertainty in model parameters. In addition to validating our mapping, this agreement supports our previous estimates of the friction coefficient of DNA confined in a nanochannel (Tree et al., PRL 2012, 108, 228105), which have been difficult to validate due to the lack of direct experimental data. Furthermore, our calculation shows that as the channel size passes below ~100 nm (or roughly the Kuhn length of DNA) there is a dramatic drop in the relaxation time. Inasmuch as the chain friction rises with decreasing channel size, the reduction in the relaxation time can be solely attributed to the sharp decline in the fluctuations of the chain extension. Practically, the low variance in the observed DNA extension in such small channels has important implications for genome mapping. This work was supported by the NIH (R01-HG005216 and R01-HG006851) and the NSFC (21204061) and was carried out in part using computing resources at the University of Minnesota Supercomputing Institute.

  14. Modeling the relaxation time of DNA confined in a nanochannel

    PubMed Central

    Tree, Douglas R.; Wang, Yanwei; Dorfman, Kevin D.

    2013-01-01

    Using a mapping between a Rouse dumbbell model and fine-grained Monte Carlo simulations, we have computed the relaxation time of λ-DNA in a high ionic strength buffer confined in a nanochannel. The relaxation time thus obtained agrees quantitatively with experimental data [Reisner et al., Phys. Rev. Lett. 94, 196101 (2005)] using only a single O(1) fitting parameter to account for the uncertainty in model parameters. In addition to validating our mapping, this agreement supports our previous estimates of the friction coefficient of DNA confined in a nanochannel [Tree et al., Phys. Rev. Lett. 108, 228105 (2012)], which have been difficult to validate due to the lack of direct experimental data. Furthermore, the model calculation shows that as the channel size passes below approximately 100 nm (or roughly the Kuhn length of DNA) there is a dramatic drop in the relaxation time. Inasmuch as the chain friction rises with decreasing channel size, the reduction in the relaxation time can be solely attributed to the sharp decline in the fluctuations of the chain extension. Practically, the low variance in the observed DNA extension in such small channels has important implications for genome mapping. PMID:24309551

  15. Landauer's formula with finite-time relaxation: Kramers' crossover in electronic transport

    NASA Astrophysics Data System (ADS)

    Gruss, Daniel; Velizhanin, Kirill; Zwolak, Michael

    Landauer's formula relates the conductance of a region of interest to its transmission probability. It is the standard theoretical tool to examine ballistic transport in nano- and meso-scale junctions and devices. This view of transport as transmission necessitates a simplified view of transmission, one occurring through an essentially fixed structure. Starting from a description of transport that includes relaxation of electrons in the reservoirs, we derive a Landauer-like formula for the steady-state current. We demonstrate that the finite relaxation time gives rise to three regimes of behavior. Weak relaxation within a small region nearby to the junction gives a contact limited current. Strong relaxation also influences the current by localizing electrons, distorting their natural dynamics and reducing the current. In an intermediate regime, the standard Landauer view is recovered. This behavior is analogous to Kramers' turnover in chemical reactions. Supported by UMD/CNST Cooperative Research Agreement, Award 70NANB10H193.

  16. Measurement of cyclotron resonance relaxation time in the two-dimensional electron system

    SciTech Connect

    Andreev, I. V. Muravev, V. M.; Kukushkin, I. V.; Belyanin, V. N.

    2014-11-17

    Dependence of cyclotron magneto-plasma mode relaxation time on electron concentration and temperature in the two-dimensional electron system in GaAs/AlGaAs quantum wells has been studied. Comparative analysis of cyclotron and transport relaxation time has been carried out. It was demonstrated that with the temperature increase transport relaxation time tends to cyclotron relaxation time. It was also shown that cyclotron relaxation time, as opposed to transport relaxation time, has a weak electron density dependence. The cyclotron time can exceed transport relaxation time by an order of magnitude in a low-density range.

  17. Relaxed Time Slot Negotiation for Grid Resource Allocation

    NASA Astrophysics Data System (ADS)

    Son, Seokho; Sim, Kwang Mong

    Since participants in a computational grid may be independent bodies, some mechanisms are necessary for resolving the differences in their preferences for price and desirable time slots for utilizing/leasing computing resources. Whereas there are mechanisms for supporting price negotiation for grid resource allocation, there is little or no negotiation support for allocating mutually acceptable time slots for grid participants. The contribution of this work is designing a negotiation mechanism for facilitating time slot negotiations between grid participants. In particular, this work adopts a relaxed time slot negotiation protocol designed to enhance the success rate and resource utilization level by allowing some flexibility for making slight adjustments following a tentative agreement for a mutually acceptable time slot. The ideas of the relaxed time slot negotiation are implemented in an agent-based grid testbed, and empirical results of the relaxed time slot negotiation mechanism carried out, (i) a consumer and a provider agent have a mutually satisfying agreement on time slot and price, (ii) consumer agents achieved higher success rates in negotiation, and (iii) provider agents achieved higher utility and resource utilization of overall grid.

  18. Subsecond pore-scale displacement processes and relaxation dynamics in multiphase flow

    PubMed Central

    Armstrong, Ryan T; Ott, Holger; Georgiadis, Apostolos; Rücker, Maja; Schwing, Alex; Berg, Steffen

    2014-01-01

    With recent advances at X-ray microcomputed tomography (μCT) synchrotron beam lines, it is now possible to study pore-scale flow in porous rock under dynamic flow conditions. The collection of four-dimensional data allows for the direct 3-D visualization of fluid-fluid displacement in porous rock as a function of time. However, even state-of-the-art fast-μCT scans require between one and a few seconds to complete and the much faster fluid movement occurring during that time interval is manifested as imaging artifacts in the reconstructed 3-D volume. We present an approach to analyze the 2-D radiograph data collected during fast-μCT to study the pore-scale displacement dynamics on the time scale of 40 ms which is near the intrinsic time scale of individual Haines jumps. We present a methodology to identify the time intervals at which pore-scale displacement events in the observed field of view occur and hence, how reconstruction intervals can be chosen to avoid fluid-movement-induced reconstruction artifacts. We further quantify the size, order, frequency, and location of fluid-fluid displacement at the millisecond time scale. We observe that after a displacement event, the pore-scale fluid distribution relaxes to (quasi-) equilibrium in cascades of pore-scale fluid rearrangements with an average relaxation time for the whole cascade between 0.5 and 2.0 s. These findings help to identify the flow regimes and intrinsic time and length scales relevant to fractional flow. While the focus of the work is in the context of multiphase flow, the approach could be applied to many different μCT applications where morphological changes occur at a time scale less than that required for collecting a μCT scan. PMID:25745271

  19. Temperature dependence of proton relaxation times in vitro.

    PubMed

    Nelson, T R; Tung, S M

    1987-01-01

    Accurate measurement of tissue relaxation characteristics is dependent on many factors, including field strength and temperature. The purpose of this study was to evaluate the relationship between sample temperature, viscosity and proton spin-lattice relaxation time (T1) and spin-spin relaxation time (T2). A review of two basic models of relaxation the simple molecular motion model and the fast exchange two state model is given with reference to their thermal dependencies. The temperature dependence for both T1 and T2 was studied on a 0.15 Tesla whole body magnetic resonance imager. Thirteen samples comprising both simple and complex materials were investigated by using a standard spin-echo (SE) technique and a modified Carr-Purcell-Meiboom-Gill (CPMG) multi-echo sequence. A simple linear relationship between T1 and temperature was observed for all samples over the range of 20 degrees C to 50 degrees C. There is an inverse relationship between viscosity and T1 and T2. A quantity called the temperature dependence coefficient (TDC) is introduced and defined as the percent rate of change of the proton relaxation time referenced to a specific temperature. The large TDC found for T1 values, e.g. 2.37%/degrees C for CuSO4 solutions and 3.59%/degrees C for light vegetable oils at 22 degrees C, indicates that a temperature correction should be made when comparing in-vivo and in-vitro T1 times. The T2 temperature dependence is relatively small. PMID:3041151

  20. Inversion of generalized relaxation time distributions with optimized damping parameter

    NASA Astrophysics Data System (ADS)

    Florsch, Nicolas; Revil, André; Camerlynck, Christian

    2014-10-01

    Retrieving the Relaxation Time Distribution (RDT), the Grains Size Distribution (GSD) or the Pore Size Distribution (PSD) from low-frequency impedance spectra is a major goal in geophysics. The “Generalized RTD” generalizes parametric models like Cole-Cole and many others, but remains tricky to invert since this inverse problem is ill-posed. We propose to use generalized relaxation basis function (for instance by decomposing the spectra on basis of generalized Cole-Cole relaxation elements instead of the classical Debye basis) and to use the L-curve approach to optimize the damping parameter required to get smooth and realistic inverse solutions. We apply our algorithm to three examples, one synthetic and two real data sets, and the program includes the possibility of converting the RTD into GSD or PSD by choosing the value of the constant connecting the relaxation time to the characteristic polarization size of interest. A high frequencies (typically above 1 kHz), a dielectric term in taken into account in the model. The code is provided as an open Matlab source as a supplementary file associated with this paper.

  1. Time-dependent corona models - Scaling laws

    NASA Technical Reports Server (NTRS)

    Korevaar, P.; Martens, P. C. H.

    1989-01-01

    Scaling laws are derived for the one-dimensional time-dependent Euler equations that describe the evolution of a spherically symmetric stellar atmosphere. With these scaling laws the results of the time-dependent calculations by Korevaar (1989) obtained for one star are applicable over the whole Hertzsprung-Russell diagram and even to elliptic galaxies. The scaling is exact for stars with the same M/R-ratio and a good approximation for stars with a different M/R-ratio. The global relaxation oscillation found by Korevaar (1989) is scaled to main sequence stars, a solar coronal hole, cool giants and elliptic galaxies.

  2. Hyperpolarized nanodiamond with long spin-relaxation times

    PubMed Central

    Rej, Ewa; Gaebel, Torsten; Boele, Thomas; Waddington, David E.J.; Reilly, David J.

    2015-01-01

    The use of hyperpolarized agents in magnetic resonance, such as 13C-labelled compounds, enables powerful new imaging and detection modalities that stem from a 10,000-fold boost in signal. A major challenge for the future of the hyperpolarization technique is the inherently short spin-relaxation times, typically <60 s for 13C liquid-state compounds, which limit the time that the signal remains boosted. Here we demonstrate that 1.1% natural abundance 13C spins in synthetic nanodiamond can be hyperpolarized at cryogenic and room temperature without the use of free radicals, and, owing to their solid-state environment, exhibit relaxation times exceeding 1 h. Combined with the already established applications of nanodiamonds in the life sciences as inexpensive fluorescent markers and non-cytotoxic substrates for gene and drug delivery, these results extend the theranostic capabilities of nanoscale diamonds into the domain of hyperpolarized magnetic resonance. PMID:26450570

  3. Carrier relaxation time divergence in single and double layer cuprates

    NASA Astrophysics Data System (ADS)

    Schneider, M. L.; Rast, S.; Onellion, M.; Demsar, J.; Taylor, A. J.; Glinka, Y.; Tolk, N. H.; Ren, Y. H.; Lüpke, G.; Klimov, A.; Xu, Y.; Sobolewski, R.; Si, W.; Zeng, X. H.; Soukiassian, A.; Xi, X. X.; Abrecht, M.; Ariosa, D.; Pavuna, D.; Krapf, A.; Manzke, R.; Printz, J. O.; Williamsen, M. S.; Downum, K. E.; Guptasarma, P.; Bozovic, I.

    2003-12-01

    We report the transient optical pump-probe reflectivity measurements on single and double layer cuprate single crystals and thin films of ten different stoichiometries. We find that with sufficiently low fluence the relaxation time (tauR) of all samples exhibits a power law divergence with temperature (T): tauR ∝ T^{-3 ± 0.5}. Further, the divergence has an onset temperature above the superconducting transition temperature for all superconducting samples. Possible causes of this divergence are discussed.

  4. On relaxation times in the Navier-Stokes-Voigt model

    NASA Astrophysics Data System (ADS)

    Layton, William J.; Rebholz, Leo G.

    2013-03-01

    We study analytically and numerically the relaxation time of flow evolution governed by the Navier-Stokes-Voigt (NSV) model. We first show that for the Taylor-Green vortex decay problem, NSV admits an exact solution which evolves slower than true fluid flow. Secondly, we show numerically for a channel flow test problem using standard discretisation methods that although NSV provides more regular solutions compared to usual Navier-Stokes solutions, NSV approximations take significantly longer to reach the steady state.

  5. Damping effects in doped graphene: The relaxation-time approximation

    NASA Astrophysics Data System (ADS)

    Kupčić, I.

    2014-11-01

    The dynamical conductivity of interacting multiband electronic systems derived by Kupčić et al. [J. Phys.: Condens. Matter 90, 145602 (2013), 10.1088/0953-8984/25/14/145602] is shown to be consistent with the general form of the Ward identity. Using the semiphenomenological form of this conductivity formula, we have demonstrated that the relaxation-time approximation can be used to describe the damping effects in weakly interacting multiband systems only if local charge conservation in the system and gauge invariance of the response theory are properly treated. Such a gauge-invariant response theory is illustrated on the common tight-binding model for conduction electrons in doped graphene. The model predicts two distinctly resolved maxima in the energy-loss-function spectra. The first one corresponds to the intraband plasmons (usually called the Dirac plasmons). On the other hand, the second maximum (π plasmon structure) is simply a consequence of the Van Hove singularity in the single-electron density of states. The dc resistivity and the real part of the dynamical conductivity are found to be well described by the relaxation-time approximation, but only in the parametric space in which the damping is dominated by the direct scattering processes. The ballistic transport and the damping of Dirac plasmons are thus the problems that require abandoning the relaxation-time approximation.

  6. Krylov-subspace acceleration of time periodic waveform relaxation

    SciTech Connect

    Lumsdaine, A.

    1994-12-31

    In this paper the author uses Krylov-subspace techniques to accelerate the convergence of waveform relaxation applied to solving systems of first order time periodic ordinary differential equations. He considers the problem in the frequency domain and presents frequency dependent waveform GMRES (FDWGMRES), a member of a new class of frequency dependent Krylov-subspace techniques. FDWGMRES exhibits many desirable properties, including finite termination independent of the number of timesteps and, for certain problems, a convergence rate which is bounded from above by the convergence rate of GMRES applied to the static matrix problem corresponding to the linear time-invariant ODE.

  7. Diffusion MRI/NMR magnetization equations with relaxation times

    NASA Astrophysics Data System (ADS)

    de, Dilip; Daniel, Simon

    2012-10-01

    Bloch-Torrey diffusion magnetization equation ignores relaxation effects of magnetization. Relaxation times are important in any diffusion magnetization studies of perfusion in tissues(Brain and heart specially). Bloch-Torrey equation cannot therefore describe diffusion magnetization in a real-life situation where relaxation effects play a key role, characteristics of tissues under examination. This paper describes derivations of two equations for each of the y and z component diffusion NMR/MRI magnetization (separately) in a rotating frame of reference, where rf B1 field is applied along x direction and bias magnetic field(Bo) is along z direction. The two equations are expected to further advance the science & technology of Diffusion MRI(DMRI) and diffusion functional MRI(DFMRI). These two techniques are becoming increasingly important in the study and treatment of neurological disorders, especially for the management of patients with acute stroke. It is rapidly becoming a standard for white matter disorders, as diffusion tensor imaging (DTI) can reveal abnormalities in white matter fibre structure and provide models of brain connectivity.

  8. Multi-scale times and modes of fast and slow relaxation in solutions with coexisting spherical and cylindrical micelles according to the difference Becker-Döring kinetic equations

    NASA Astrophysics Data System (ADS)

    Babintsev, Ilya A.; Adzhemyan, Loran Ts.; Shchekin, Alexander K.

    2014-08-01

    The eigenvalues and eigenvectors of the matrix of coefficients of the linearized kinetic equations applied to aggregation in surfactant solution determine the full spectrum of characteristic times and specific modes of micellar relaxation. The dependence of these relaxation times and modes on the total surfactant concentration has been analyzed for concentrations in the vicinity and well above the second critical micelle concentration (cmc2) for systems with coexisting spherical and cylindrical micelles. The analysis has been done on the basis of a discrete form of the Becker-Döring kinetic equations employing the Smoluchowsky diffusion model for the attachment rates of surfactant monomers to surfactant aggregates with matching the rates for spherical aggregates and the rates for large cylindrical micelles. The equilibrium distribution of surfactant aggregates in solution has been modeled as having one maximum for monomers, another maximum for spherical micelles and wide slowly descending branch for cylindrical micelles. The results of computations have been compared with the analytical ones known in the limiting cases from solutions of the continuous Becker-Döring kinetic equation. They demonstrated a fair agreement even in the vicinity of the cmc2 where the analytical theory looses formally its applicability.

  9. Determining pore length scales and pore surface relaxivity of rock cores by internal magnetic fields modulation at 2MHz NMR.

    PubMed

    Liu, Huabing; Nogueira d'Eurydice, Marcel; Obruchkov, Sergei; Galvosas, Petrik

    2014-09-01

    Pore length scales and pore surface relaxivities of rock cores with different lithologies were studied on a 2MHz Rock Core Analyzer. To determine the pore length scales of the rock cores, the high eigenmodes of spin bearing molecules satisfying the diffusion equation were detected with optimized encoding periods in the presence of internal magnetic fields Bin. The results were confirmed using a 64MHz NMR system, which supports the feasibility of high eigenmode detection at fields as low as 2MHz. Furthermore, this methodology was combined with relaxometry measurements to a two-dimensional experiment, which provides correlation between pore length and relaxation time. This techniques also yields information on the surface relaxivity of the rock cores. The estimated surface relaxivities were then compared to the results using an independent NMR method.

  10. Dielectric relaxation, resonance and scaling behaviors in Sr3Co2Fe24O41 hexaferrite.

    PubMed

    Tang, Rujun; Jiang, Chen; Qian, Wenhu; Jian, Jie; Zhang, Xin; Wang, Haiyan; Yang, Hao

    2015-08-28

    The dielectric properties of Z-type hexaferrite Sr3Co2Fe24O41 (SCFO) have been investigated as a function of temperature from 153 to 503 K between 1 and 2 GHz. The dielectric responses of SCFO are found to be frequency dependent and thermally activated. The relaxation-type dielectric behavior is observed to be dominating in the low frequency region and resonance-type dielectric behavior is found to be dominating above 10(8) Hz. This frequency dependence of dielectric behavior is explained by the damped harmonic oscillator model with temperature dependent coefficients. The imaginary part of impedance (Z″) and modulus (M″) spectra show that there is a distribution of relaxation times. The scaling behaviors of Z″ and M″ spectra further suggest that the distribution of relaxation times is temperature independent at low frequencies. The dielectric loss spectra at different temperatures have not shown a scaling behavior above 10(8) Hz. A comparison between the Z″ and the M″ spectra indicates that the short-range charges motion dominates at low temperatures and the long-range charges motion dominates at high temperatures. The above results indicate that the dielectric dispersion mechanism in SCFO is temperature independent at low frequencies and temperature dependent at high frequencies due to the domination of resonance behavior.

  11. Multiple-relaxation-time model for the correct thermohydrodynamic equations.

    PubMed

    Zheng, Lin; Shi, Baochang; Guo, Zhaoli

    2008-08-01

    A coupling lattice Boltzmann equation (LBE) model with multiple relaxation times is proposed for thermal flows with viscous heat dissipation and compression work. In this model the fixed Prandtl number and the viscous dissipation problems in the energy equation, which exist in most of the LBE models, are successfully overcome. The model is validated by simulating the two-dimensional Couette flow, thermal Poiseuille flow, and the natural convection flow in a square cavity. It is found that the numerical results agree well with the analytical solutions and/or other numerical results.

  12. Theoretical evaluation of bulk viscosity: Expression for relaxation time

    NASA Astrophysics Data System (ADS)

    Hossein Mohammad Zaheri, Ali; Srivastava, Sunita; Tankeshwar, K.

    2007-10-01

    A theoretical calculation of bulk viscosity has been carried out by deriving an expression for the relaxation time which appears in the formula for bulk viscosity derived by Okumura and Yonezawa. The expression involved a pair distribution function and interaction potential. Numerical results have been obtained over a wide range of densities and temperatures for Lennard-Jones fluids. It is found that our results provide a good description of bulk viscosity as has been judged by comparing the results with nonequilibrium molecular dynamics results. In addition, our results demonstrate the importance of the multiparticle correlation function.

  13. Electron number dependence of spin triplet-singlet relaxation time

    NASA Astrophysics Data System (ADS)

    Li, H. O.; Xiao, M.; Cao, G.; You, J.; Guo, G. P.

    2014-02-01

    In a GaAs single quantum dot, the relaxation time T1 between spin triplet and singlet states has been measured for the last few even electron numbers. The singlet-triplet energy separation EST is tuned as a control parameter for the comparison of T1 between different electron numbers. T1 steadily decreases with increasing electron numbers from 2-electrons to 6-electrons. This implies an enhancement of the spin-orbit coupling strength due to multi-electron interaction in a quantum dot.

  14. Rapid MRI method for mapping the longitudinal relaxation time

    NASA Astrophysics Data System (ADS)

    Hsu, Jung-Jiin; Glover, Gary H.

    2006-07-01

    A novel method for mapping the longitudinal relaxation time in a clinically acceptable time is developed based on a recent proposal [J.-J. Hsu, I.J. Lowe, Spin-lattice relaxation and a fast T1-map acquisition method in MRI with transient-state magnetization, J. Magn. Reson. 169 (2004) 270-278] and the speed of the spiral pulse sequence. The method acquires multiple curve-fitting samples with one RF pulse train. It does not require RF pulses of specific flip angles (e.g., 90° or 180°), nor are the long recovery waiting time and the measurement of the magnetization at thermal equilibrium needed. Given the value of the flip angle, the curve fitting is semi-logarithmic and not computationally intensive. On a heterogeneous phantom, the average percentage difference between measurements of the present method and those of an inversion-recovery method is below 2.7%. In mapping the human brain, the present method, for example, can obtain four curve-fitting samples for five 128 × 128 slices in less than 3.2 s and the results are in agreement with other studies in the literature.

  15. Impact of Internal Magnetic Field Gradients on the NMR Relaxation Time Distribution

    NASA Astrophysics Data System (ADS)

    Grombacher, D. J.; Fay, E. L.; Knight, R. J.

    2014-12-01

    We explore the impact of internal magnetic field gradients, which arise due to the presence of a magnetic susceptibility contrast between grains and the pore fluid, on the relaxation time distribution. Relaxation times provide powerful insight into the pore geometry. This link to pore geometry relies on the fast-diffusion assumption, where relaxation is controlled by the pore surface and each pore is treated as isolated and is described by a single relaxation time. This allows the relaxation time distribution to be interpreted as a pore size distribution. However, internal gradients can complicate this interpretation by providing an additional relaxation mechanism impacting the decay. We present both synthetic and laboratory studies investigating the impact of internal gradients on the relaxation time distribution. A COMSOL multiphysics package is employed to determine the magnetic field's spatial distribution across the pore space, and to simulate the pore's NMR relaxation. The NMR simulation accounts for both surface relaxation, and relaxation related to internal gradients. We observe that as the influence of internal gradients increases, through either greater magnetic susceptibility contrasts or the use of longer echo times, the shape of the relaxation time distribution is altered. In these cases, relaxation within a single pore is no longer described by a single characteristic relaxation time, instead requiring multiple relaxation times to capture the time-dependent behavior. As a result, the relaxation time distribution is broadened and shifted to faster relaxation times. Laboratory results, performed for several samples sieved to ensure narrow grain size distributions and with varying magnitudes of magnetic susceptibility contrasts, exhibit similar trends to those observed in the synthetic studies. These results have significant implications for the interpretation of relaxation data to obtain pore size distributions, and the derived estimates of hydraulic

  16. The time correlation function perspective of NMR relaxation in proteins

    NASA Astrophysics Data System (ADS)

    Shapiro, Yury E.; Meirovitch, Eva

    2013-08-01

    We applied over a decade ago the two-body coupled-rotator slowly relaxing local structure (SRLS) approach to NMR relaxation in proteins. One rotator is the globally moving protein and the other rotator is the locally moving probe (spin-bearing moiety, typically the 15N-1H bond). So far we applied SRLS to 15N-H relaxation from seven different proteins within the scope of the commonly used data-fitting paradigm. Here, we solve the SRLS Smoluchowski equation using typical best-fit parameters as input, to obtain the corresponding generic time correlation functions (TCFs). The following new information is obtained. For actual rhombic local ordering and main ordering axis pointing along C_{i - 1}^α - C_i^α, the measurable TCF is dominated by the (K,K') = (-2,2), (2,2), and (0,2) components (K is the order of the rank 2 local ordering tensor), determined largely by the local motion. Global diffusion axiality affects the analysis significantly when the ratio between the parallel and perpendicular components exceeds approximately 1.5. Local diffusion axiality has a large and intricate effect on the analysis. Mode-coupling becomes important when the ratio between the global and local motional rates falls below 0.01. The traditional method of analysis - model-free (MF) - represents a simple limit of SRLS. The conditions under which the MF and SRLS TCFs are the same are specified. The validity ranges of wobble-in-a-cone and rotation on the surface of a cone as local motions are determined. The evolution of the intricate Smoluchowski operator from the simple diffusion operator for a sphere reorienting in isotropic medium is delineated. This highlights the fact that SRLS is an extension of the established stochastic theories for treating restricted motions. This study lays the groundwork for TCF-based comparison between mesoscopic SRLS and atomistic molecular dynamics.

  17. Dependence on chain length of NMR relaxation times in mixtures of alkanes

    NASA Astrophysics Data System (ADS)

    Freed, Denise E.

    2007-05-01

    Many naturally occurring fluids, such as crude oils, consist of a very large number of components. It is often of interest to determine the composition of the fluids in situ. Diffusion coefficients and nuclear magnetic resonance (NMR) relaxation times can be measured in situ and depend on the size of the molecules. It has been shown [D. E. Freed et al., Phys. Rev. Lett. 94, 067602 (2005)] that the diffusion coefficient of each component in a mixture of alkanes follows a scaling law in the chain length of that molecule and in the mean chain length of the mixture, and these relations were used to determine the chain length distribution of crude oils from NMR diffusion measurements. In this paper, the behavior of NMR relaxation times in mixtures of chain molecules is addressed. The author explains why one would expect scaling laws for the transverse and longitudinal relaxation times of mixtures of short chain molecules and mixtures of alkanes, in particular. It is shown how the power law dependence on the chain length can be calculated from the scaling laws for the translational diffusion coefficients. The author fits the literature data for NMR relaxation in binary mixtures of alkanes and finds that its dependence on chain length agrees with the theory. Lastly, it is shown how the scaling laws in the chain length and the mean chain length can be used to determine the chain length distribution in crude oils that are high in saturates. A good fit is obtained between the NMR-derived chain length distributions and the ones from gas chromatography.

  18. Critical comparison between time- and frequency-domain relaxation functions

    NASA Astrophysics Data System (ADS)

    Snyder, Chad R.; Mopsik, Frederick I.

    1999-07-01

    Considerable work has been performed on providing a theoretical basis for the Kohlrausch-Williams-Watts (KWW) and Havriliak-Negami (HN) relaxation functions. Because of this, several papers have examined the ``interconnection'' of these two functions. In this paper, we demonstrate that, with achievable instrumental sensitivity, these two functions are distinguishable. We further address the issue of the ``universal'' limiting power laws and the ability to obtain the exponents associated with them. Finally, the stability and accuracy of our numerical Laplace transform is demonstrated by comparison between functions with known analytical time and frequency solutions. The stability of our algorithm indicates that the method of Alvarez and co-workers [F. Alvarez, A. Alegría, and J. Colmenero, Phys. Rev. B 44, 7306 (1991)] is an unnecessary approximation for converting between the time and frequency domain.

  19. Unified Theory of Activated Relaxation in Liquids over 14 Decades in Time

    SciTech Connect

    Mirigian, Stephen; Schweizer, Kenneth

    2013-01-01

    We formulate a predictive theory at the level of forces of activated relaxation in hard-sphere fluids and thermal liquids that covers in a unified manner the apparent Arrhenius, crossover, and deeply supercooled regimes. The alpha relaxation event involves coupled cage-scale hopping and a long-range collective elastic distortion of the surrounding liquid, which results in two inter-related, but distinct, barriers. The strongly temperature and density dependent collective barrier is associated with a growing length scale, the shear modulus, and density fluctuations. Thermal liquids are mapped to an effective hard-sphere fluid based on matching long wavelength density fluctuation amplitudes, resulting in a zeroth-order quasi-universal description. The theory is devoid of fit parameters, has no divergences at finite temperature nor below jamming, and captures the key features of the alpha time of molecular liquids from picoseconds to hundreds of seconds.

  20. Upper D region chemical kinetic modeling of LORE relaxation times

    NASA Astrophysics Data System (ADS)

    Gordillo-Vázquez, F. J.; Luque, A.; Haldoupis, C.

    2016-04-01

    The recovery times of upper D region electron density elevations, caused by lightning-induced electromagnetic pulses (EMP), are modeled. The work was motivated from the need to understand a recently identified narrowband VLF perturbation named LOREs, an acronym for LOng Recovery Early VLF events. LOREs associate with long-living electron density perturbations in the upper D region ionosphere; they are generated by strong EMP radiated from large peak current intensities of ±CG (cloud to ground) lightning discharges, known also to be capable of producing elves. Relaxation model scenarios are considered first for a weak enhancement in electron density and then for a much stronger one caused by an intense lightning EMP acting as an impulsive ionization source. The full nonequilibrium kinetic modeling of the perturbed mesosphere in the 76 to 92 km range during LORE-occurring conditions predicts that the electron density relaxation time is controlled by electron attachment at lower altitudes, whereas above 79 km attachment is balanced totally by associative electron detachment so that electron loss at these higher altitudes is controlled mainly by electron recombination with hydrated positive clusters H+(H2O)n and secondarily by dissociative recombination with NO+ ions, a process which gradually dominates at altitudes >88 km. The calculated recovery times agree fairly well with LORE observations. In addition, a simplified (quasi-analytic) model build for the key charged species and chemical reactions is applied, which arrives at similar results with those of the full kinetic model. Finally, the modeled recovery estimates for lower altitudes, that is <79 km, are in good agreement with the observed short recovery times of typical early VLF events, which are known to be associated with sprites.

  1. Implicit versus explicit momentum relaxation time solution for semiconductor nanowires

    SciTech Connect

    Marin, E. G. Ruiz, F. G. Godoy, A. Tienda-Luna, I. M.; Gámiz, F.

    2015-07-14

    We discuss the necessity of the exact implicit Momentum Relaxation Time (MRT) solution of the Boltzmann transport equation in order to achieve reliable carrier mobility results in semiconductor nanowires. Firstly, the implicit solution for a 1D electron gas with a isotropic bandstructure is presented resulting in the formulation of a simple matrix system. Using this solution as a reference, the explicit approach is demonstrated to be inaccurate for the calculation of inelastic anisotropic mechanisms such as polar optical phonons, characteristic of III-V materials. Its validity for elastic and isotropic mechanisms is also evaluated. Finally, the implications of the MRT explicit approach inaccuracies on the total mobility of Si and III-V NWs are studied.

  2. Dependence of Brownian and Néel relaxation times on magnetic field strength

    SciTech Connect

    Deissler, Robert J. Wu, Yong; Martens, Michael A.

    2014-01-15

    Purpose: In magnetic particle imaging (MPI) and magnetic particle spectroscopy (MPS) the relaxation time of the magnetization in response to externally applied magnetic fields is determined by the Brownian and Néel relaxation mechanisms. Here the authors investigate the dependence of the relaxation times on the magnetic field strength and the implications for MPI and MPS. Methods: The Fokker–Planck equation with Brownian relaxation and the Fokker–Planck equation with Néel relaxation are solved numerically for a time-varying externally applied magnetic field, including a step-function, a sinusoidally varying, and a linearly ramped magnetic field. For magnetic fields that are applied as a step function, an eigenvalue approach is used to directly calculate both the Brownian and Néel relaxation times for a range of magnetic field strengths. For Néel relaxation, the eigenvalue calculations are compared to Brown's high-barrier approximation formula. Results: The relaxation times due to the Brownian or Néel mechanisms depend on the magnitude of the applied magnetic field. In particular, the Néel relaxation time is sensitive to the magnetic field strength, and varies by many orders of magnitude for nanoparticle properties and magnetic field strengths relevant for MPI and MPS. Therefore, the well-known zero-field relaxation times underestimate the actual relaxation times and, in particular, can underestimate the Néel relaxation time by many orders of magnitude. When only Néel relaxation is present—if the particles are embedded in a solid for instance—the authors found that there can be a strong magnetization response to a sinusoidal driving field, even if the period is much less than the zero-field relaxation time. For a ferrofluid in which both Brownian and Néel relaxation are present, only one relaxation mechanism may dominate depending on the magnetic field strength, the driving frequency (or ramp time), and the phase of the magnetization relative to the

  3. Time dependent parallel viscosity and relaxation rate of poloidal rotation in the banana regime

    SciTech Connect

    Hsu, C.T.; Shaing, K.C.; Gormley, R. )

    1994-01-01

    Time dependent ion parallel viscous force in the banana regime with arbitrary inverse aspect ratio [epsilon] is calculated using the eigenfunction approach. The flux surface averaged viscosity is then used to study the relaxation process of the poloidal rotation which leads to oscillatory relaxation behavior. The relaxation rate [nu][sub [ital p

  4. Optical Relaxation Time Enhancement in Graphene-Passivated Metal Films

    PubMed Central

    Chugh, Sunny; Mehta, Ruchit; Man, Mengren; Chen, Zhihong

    2016-01-01

    Due to the small skin depth in metals at optical frequencies, their plasmonic response is strongly dictated by their surface properties. Copper (Cu) is one of the standard materials of choice for plasmonic applications, because of its high conductivity and CMOS compatibility. However, being a chemically active material, it gets easily oxidized when left in ambient environment, causing an inevitable degradation in its plasmonic resonance. Here, for the first time, we report a strong enhancement in the optical relaxation time in Cu by direct growth of few-layer graphene that is shown to act as an excellent passivation layer protecting Cu surface from any deterioration. Spectroscopic ellipsometry measurements reveal a 40–50% reduction in the total scattering rate in Cu itself, which is attributed to an improvement in its surface properties. We also study the impact of graphene quality and show that high quality graphene leads to an even larger improvement in electron scattering rate. These findings are expected to provide a big push towards graphene-protected Cu plasmonics. PMID:27461968

  5. Optical Relaxation Time Enhancement in Graphene-Passivated Metal Films

    NASA Astrophysics Data System (ADS)

    Chugh, Sunny; Mehta, Ruchit; Man, Mengren; Chen, Zhihong

    2016-07-01

    Due to the small skin depth in metals at optical frequencies, their plasmonic response is strongly dictated by their surface properties. Copper (Cu) is one of the standard materials of choice for plasmonic applications, because of its high conductivity and CMOS compatibility. However, being a chemically active material, it gets easily oxidized when left in ambient environment, causing an inevitable degradation in its plasmonic resonance. Here, for the first time, we report a strong enhancement in the optical relaxation time in Cu by direct growth of few-layer graphene that is shown to act as an excellent passivation layer protecting Cu surface from any deterioration. Spectroscopic ellipsometry measurements reveal a 40–50% reduction in the total scattering rate in Cu itself, which is attributed to an improvement in its surface properties. We also study the impact of graphene quality and show that high quality graphene leads to an even larger improvement in electron scattering rate. These findings are expected to provide a big push towards graphene-protected Cu plasmonics.

  6. Unified Theory of Activated Relaxation in Cold Liquids over 14 Decades in Time

    NASA Astrophysics Data System (ADS)

    Schweizer, Kenneth; Mirigian, Stephen

    2014-03-01

    We formulate a predictive theory at the level of forces of activated relaxation in thermal liquids that covers in a unified manner the apparent Arrhenius, crossover and deeply supercooled regimes (J.Phys.Chem.Lett.4,3648(2013)). The alpha relaxation event involves coupled cage-scale hopping and a long range cooperative elastic distortion of the surrounding liquid, which results in two inter-related, but distinct, barriers. The strongly temperature and density dependent collective barrier is associated with a growing length scale, the shear modulus and density fluctuations. Thermal liquids are mapped to an effective hard sphere fluid based on matching long wavelength density fluctuation amplitudes. The theory is devoid of fit parameters, has no divergences at finite temperature nor below jamming, and captures the key features of the alpha relaxation time in molecular liquids from picoseconds to hundreds of seconds. The approach is extended to polymer liquids based on the Kuhn length as the key variable. The influence of chain length and backbone stiffness on the glass transition temperature and fragility have been studied where degree of polymerization enters via corrections to asymptotic conformational statistics.

  7. Similarity and scaling in creep and load relaxation of single-crystal halite (NaCl)

    NASA Astrophysics Data System (ADS)

    Stone, Donald S.; Plookphol, Thawatchai; Cooper, Reid F.

    2004-12-01

    This work explores the physical basis for Hart's mechanical equation of state in high-temperature plasticity. The experiments seek to identify a possible microstructural basis for the "hardness" parameters associated with load relaxation curves. The experiments also seek to examine the microstructural basis for scaling in load relaxation data and to explore the relationship between creep and load relaxation. Constant stress creep and load relaxation tests were conducted on [100] oriented single crystals of halite at 700°C and stresses between 0.6 and 3 MPa. Load relaxation tests were performed at 400°C up to a stress level of 13 MPa. After testing, specimens were sectioned, and dislocation densities and subgrain size distributions were measured. Results at 700°C reveal that distributions of subgrain size in crystals crept at different stress levels are similar to each other; that is, they have the same shape but different average subgrain sizes depending on stress level. Hardness curves obtained from load relaxation experiments at different levels of work hardening were found to correspond to different average subgrain size. Load relaxation data from 700°C and 400°C belong to a single-parameter family of curves, with hardness curves translating onto each other with a scaling slope m = 0.33 ± 0.05. Subgrain size distributions generated in creep are statistically identical to those from load relaxation. The hardness parameter, σ*, specified as the (apparent) high-strain rate limit of stress in the load relaxation data, is approximately 50Gb/DI, where G is the shear modulus, b is the Burgers vector, and DI is the mean intercept subgrain diameter. During creep under constant stress the subgrain size evolves until a steady value is approached. The experimental data lend credence to Hart's interpretation that load relaxation data represent (nearly) constant "structure" with subgrain size playing the role of the structural variable.

  8. Reconstruction of relaxation time distribution from linear electrochemical impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Zhang, Yanxiang; Chen, Yu; Yan, Mufu; Chen, Fanglin

    2015-06-01

    Linear electrochemical impedance spectroscopy (EIS), and in particular its representation of distribution of relaxation time (DRT), enables the identification of the number of processes and their nature involved in electrochemical cells. With the advantage of high frequency resolution, DRT has recently drawn increasing attention for applications in solid oxide fuel cells (SOFCs). However, the method of DRT reconstruction is not yet presented clearly in terms of what mathematical treatments and theoretical assumptions have been made. Here we present unambiguously a method to reconstruct DRT function of impedance based on Tikhonov regularization. By using the synthetic impedances and analytic DRT functions of RQ element, generalized finite length Warburg element, and Gerischer element with physical quantities representative to those of SOFC processes, we show that the quality of DRT reconstruction is sensitive to the sampling points per decade (ppd) of frequency from the impedance measurement. The robustness of the DRT reconstruction to resist noise imbedded in impedance data and numerical calculations can be accomplished by optimizing the weighting factor λ according to well defined criterion.

  9. State of water at 136 K determined by its relaxation time.

    PubMed

    Johari, G P

    2005-03-21

    Dielectric relaxation time of pure bulk water has been determined from the dielectric loss tangent scans against temperature at two frequencies. After calculating the frequency-independent background loss, the relaxation loss was obtained, and the relaxation time determined. The dielectric relaxation time of water is 35 +/- 13 s at 136 +/- 1 K, which is comparable with its structural relaxation time of ca. 33 s estimated from its T(g) endotherm (G. P. Johari, A. Hallbrucker and E. Mayer, Nature, 1987, 330, 552). Therefore, water is an ultraviscous liquid at 136 K, and this removes the basis for a comparison-based inference that water is a rigid glass up to a temperature of 165 K or higher (Y. Yue and C. A. Angell, Nature, 2004, 427, 717). The method yields satisfactory values for the relaxation time of stable glasses at their known calorimetric T(g). PMID:19791317

  10. Scaling between relaxation, transport and caged dynamics in a binary mixture on a per-component basis.

    PubMed

    Puosi, F; De Michele, C; Leporini, D

    2013-03-28

    The universal scaling between the average slow relaxation/transport and the average picosecond rattling motion inside the cage of the first neighbors has been evidenced in a variety of numerical simulations and experiments. Here, we first show that the scaling does not need information concerning the arbitrarily-defined glass transition region and relies on a single characteristic length scale a(2)(1/2) which is determined even far from that region. This prompts the definition of a novel reduced rattling amplitude (1/2) which has been investigated by extensive molecular-dynamics simulations addressing the slow relaxation, the diffusivity, and the fast cage-dynamics of both components of an atomic binary mixture. States with different potential, density, and temperature are considered. It is found that if two states exhibit coinciding incoherent van Hove function on the picosecond timescale, the coincidence is observed at long times too, including the large-distance exponential decay--a signature of heterogeneous dynamics--observed when the relaxation is slow. A major result of the present study is that the correlation plot between the diffusivity of the two components of the binary mixtures and their respective reduced rattling amplitude collapse on the same master curve. This holds true also for the structural relaxation of the two components and the unique master curve coincides with the one of the average scaling. It is shown that the breakdown of the Stokes-Einstein law exhibited by the distinct atomic species of the mixture and the monomers of a chain in a polymer melt is predicted at the same reduced rattling amplitude. Finally, we evidence that the well-known temperature/density thermodynamic scaling of the transport and the relaxation of the mixture is still valid on the picosecond timescale of the rattling motion inside the cage. This provides a link between the fast dynamics and the thermodynamic scaling of the slow dynamics. PMID:23556783

  11. Short relaxation times but long transient times in both simple and complex reaction networks

    PubMed Central

    Henry, Adrien; Martin, Olivier C.

    2016-01-01

    When relaxation towards an equilibrium or steady state is exponential at large times, one usually considers that the associated relaxation time τ, i.e. the inverse of the decay rate, is the longest characteristic time in the system. However, that need not be true, other times such as the lifetime of an infinitesimal perturbation can be much longer. In the present work, we demonstrate that this paradoxical property can arise even in quite simple systems such as a linear chain of reactions obeying mass action (MA) kinetics. By mathematical analysis of simple reaction networks, we pin-point the reason why the standard relaxation time does not provide relevant information on the potentially long transient times of typical infinitesimal perturbations. Overall, we consider four characteristic times and study their behaviour in both simple linear chains and in more complex reaction networks taken from the publicly available database ‘Biomodels’. In all these systems, whether involving MA rates, Michaelis–Menten reversible kinetics, or phenomenological laws for reaction rates, we find that the characteristic times corresponding to lifetimes of tracers and of concentration perturbations can be significantly longer than τ. PMID:27411726

  12. The time dependence of rock healing as a universal relaxation process, a tutorial

    NASA Astrophysics Data System (ADS)

    Snieder, Roel; Sens-Schönfelder, Christoph; Wu, Renjie

    2016-10-01

    The material properties of earth materials often change after the material has been perturbed (slow dynamics). For example, the seismic velocity of subsurface materials changes after earthquakes, and granular materials compact after being shaken. Such relaxation processes are associated by observables that change logarithmically with time. Since the logarithm diverges for short and long times, the relaxation can, strictly speaking, not have a log-time dependence. We present a self-contained description of a relaxation function that consists of a superposition of decaying exponentials that has log-time behavior for intermediate times, but converges to zero for long times, and is finite for t = 0. The relaxation function depends on two parameters, the minimum and maximum relaxation time. These parameters can, in principle, be extracted from the observed relaxation. As an example, we present a crude model of a fracture that is closing under an external stress. Although the fracture model violates some of the assumptions on which the relaxation function is based, it follows the relaxation function well. We provide qualitative arguments that the relaxation process, just like the Gutenberg-Richter law, is applicable to a wide range of systems and has universal properties.

  13. Time Course of Corticospinal Excitability and Intracortical Inhibition Just before Muscle Relaxation

    PubMed Central

    Suzuki, Tomotaka; Sugawara, Kenichi; Ogahara, Kakuya; Higashi, Toshio

    2016-01-01

    Using transcranial magnetic stimulation (TMS), we investigated how short-interval intracortical inhibition (SICI) was involved with transient motor cortex (M1) excitability changes observed just before the transition from muscle contraction to muscle relaxation. Ten healthy participants performed a simultaneous relaxation task of the ipsilateral finger and foot, relaxing from 10% of their maximal voluntary contraction (MVC) force after the go signal. In the simple reaction time (RT) paradigm, single or paired TMS pulses were randomly delivered after the go signal, and motor evoked potentials (MEPs) were recorded from the right first dorsal interosseous (FDI) muscle. We analyzed the time course prior to the estimated relaxation reaction time (RRT), defined here as the onset of voluntary relaxation. SICI decreased in the 80–100 ms before RRT, and MEPs were significantly greater in amplitude in the 60–80 ms period before RRT than in the other intervals in single-pulse trials. TMS pulses did not effectively increase RRT. These results show that cortical excitability in the early stage, before muscle relaxation, plays an important role in muscle relaxation control. SICI circuits may vary between decreased and increased activation to continuously maintain muscle relaxation during or after a relaxation response. With regard to M1 excitability dynamics, we suggest that SICI also dynamically changes throughout the muscle relaxation process. PMID:26858619

  14. Geologic time scale bookmark

    USGS Publications Warehouse

    ,

    2012-01-01

    This bookmark, designed for use with U.S. Geological Survey activities at the 2nd USA Science and Engineering Festival (April 26–29, 2012), is adapted from the more detailed Fact Sheet 2010–3059 "Divisions of Geologic Time." The information that it presents is widely sought by educators and students.

  15. Oxide growth stress measurements and relaxation mechanisms for alumina scales grown on FeCrAlY: Oxide growth stress measurements and relaxation mechanisms

    SciTech Connect

    Tortorelli, P. F.; Specht, E. D.; More, K. L.; Hou, P. Y.

    2012-08-08

    Early-stage tensile stress evolution in α-Al2O3 scales during oxidation of FeCrAlY at 1000, 1050, 1100, and 1200 °C was monitored in situ by use of synchrotron radiation. Tensile stress development as a function of oxidation temperature indicated a dynamic interplay between stress generation and relaxation. An analysis of the time dependence of the data indicated that the observed relaxation of the initial tensile stress in the oxide scales at 1100 and 1200°C is dominated by creep in the α-Al2O3. A thin layer of a (Fe,Cr,Al) oxide was observed at the oxide-gas interface, consistent with a mechanism whereby the conversion of (Fe,Cr,Al)2O3 to α-Al2O3 produces an initial tensile stress in the alumina scale.

  16. The derivation of thermal relaxation time between two-phase bubbly flow

    NASA Astrophysics Data System (ADS)

    Mohammadein, S. A.

    2006-03-01

    Thermal relaxation time constant is derived analytically for the relaxed model with unequal phase-temperatures of a vapour bubble at saturation temperature and a non-steady temperature field around the growing vapour bubble. The energy and state equation are solved between two finite boundary conditions. Thermal relaxation time perform a good agreement with Mohammadein (in Doctoral thesis, PAN, Gdansk, 1994) and Moby Dick experiment in terms of non-equilibrium homogeneous model (Bilicki et al. in Proc R Soc Lond A428:379-397, 1990) for lower values of initial void fraction. Thermal relaxation is affected by Jacob number, superheating, initial bubble radius and thermal diffusivity.

  17. T2 relaxation time is related to liver fibrosis severity

    PubMed Central

    Siqueira, Luiz; Uppal, Ritika; Alford, Jamu; Fuchs, Bryan C.; Yamada, Suguru; Tanabe, Kenneth; Chung, Raymond T.; Lauwers, Gregory; Chew, Michael L.; Boland, Giles W.; Sahani, Duhyant V.; Vangel, Mark; Hahn, Peter F.; Caravan, Peter

    2016-01-01

    Background The grading of liver fibrosis relies on liver biopsy. Imaging techniques, including elastography and relaxometric, techniques have had varying success in diagnosing moderate fibrosis. The goal of this study was to determine if there is a relationship between the T2-relaxation time of hepatic parenchyma and the histologic grade of liver fibrosis in patients with hepatitis C undergoing both routine, liver MRI and liver biopsy, and to validate our methodology with phantoms and in a rat model of liver fibrosis. Methods This study is composed of three parts: (I) 123 patients who underwent both routine, clinical liver MRI and biopsy within a 6-month period, between July 1999 and January 2010 were enrolled in a retrospective study. MR imaging was performed at 1.5 T using dual-echo turbo-spin echo equivalent pulse sequence. T2 relaxation time of liver parenchyma in patients was calculated by mono-exponential fit of a region of interest (ROI) within the right lobe correlating to histopathologic grading (Ishak 0–6) and routine serum liver inflammation [aspartate aminotransferase (AST) and alanine aminotransferase (ALT)]. Statistical comparison was performed using ordinary logistic and ordinal logistic regression and ANOVA comparing T2 to Ishak fibrosis without and using AST and ALT as covariates; (II) a phantom was prepared using serial dilutions of dextran coated magnetic iron oxide nanoparticles. T2 weighed imaging was performed by comparing a dual echo fast spin echo sequence to a Carr-Purcell-Meigboom-Gill (CPMG) multi-echo sequence at 1.5 T. Statistical comparison was performed using a paired t-test; (III) male Wistar rats receiving weekly intraperitoneal injections of phosphate buffer solution (PBS) control (n=4 rats); diethylnitrosamine (DEN) for either 5 (n=5 rats) or 8 weeks (n=4 rats) were MR imaged on a Bruker Pharmascan 4.7 T magnet with a home-built bird-cage coil. T2 was quantified by using a mono-exponential fitting algorithm on multi-slice multi

  18. Mechanisms of postseismic relaxation after a great subduction earthquake constrained by cross-scale thermomechanical model and geodetic observations

    NASA Astrophysics Data System (ADS)

    Sobolev, Stephan; Muldashev, Iskander

    2016-04-01

    According to conventional view, postseismic relaxation process after a great megathrust earthquake is dominated by fault-controlled afterslip during first few months to year, and later by visco-elastic relaxation in mantle wedge. We test this idea by cross-scale thermomechanical models of seismic cycle that employs elasticity, mineral-physics constrained non-linear transient viscous rheology and rate-and-state friction plasticity. As initial conditions for the models we use thermomechanical models of subduction zones at geological time-scale including a narrow subduction channel with low static friction for two settings, similar to the Southern Chile in the region of the great Chile Earthquake of 1960 and Japan in the region of Tohoku Earthquake of 2011. We next introduce in the same models classic rate-and state friction law in subduction channels, leading to stick-slip instability. The models start to generate spontaneous earthquake sequences and model parameters are set to closely replicate co-seismic deformations of Chile and Japan earthquakes. In order to follow in details deformation process during the entire seismic cycle and multiple seismic cycles we use adaptive time-step algorithm changing integration step from 40 sec during the earthquake to minute-5 year during postseismic and interseismic processes. We show that for the case of the Chile earthquake visco-elastic relaxation in the mantle wedge becomes dominant relaxation process already since 1 hour after the earthquake, while for the smaller Tohoku earthquake this happens some days after the earthquake. We also show that our model for Tohoku earthquake is consistent with the geodetic observations for the day-to-4year time range. We will demonstrate and discuss modeled deformation patterns during seismic cycles and identify the regions where the effects of afterslip and visco-elastic relaxation can be best distinguished.

  19. Time-parallel iterative methods for parabolic PDES: Multigrid waveform relaxation and time-parallel multigrid

    SciTech Connect

    Vandewalle, S.

    1994-12-31

    Time-stepping methods for parabolic partial differential equations are essentially sequential. This prohibits the use of massively parallel computers unless the problem on each time-level is very large. This observation has led to the development of algorithms that operate on more than one time-level simultaneously; that is to say, on grids extending in space and in time. The so-called parabolic multigrid methods solve the time-dependent parabolic PDE as if it were a stationary PDE discretized on a space-time grid. The author has investigated the use of multigrid waveform relaxation, an algorithm developed by Lubich and Ostermann. The algorithm is based on a multigrid acceleration of waveform relaxation, a highly concurrent technique for solving large systems of ordinary differential equations. Another method of this class is the time-parallel multigrid method. This method was developed by Hackbusch and was recently subject of further study by Horton. It extends the elliptic multigrid idea to the set of equations that is derived by discretizing a parabolic problem in space and in time.

  20. Scaling of transverse nuclear magnetic relaxation due to magnetic nanoparticle aggregation.

    PubMed

    Brown, Keith A; Vassiliou, Christophoros C; Issadore, David; Berezovsky, Jesse; Cima, Michael J; Westervelt, R M

    2010-10-01

    The aggregation of superparamagnetic iron oxide (SPIO) nanoparticles decreases the transverse nuclear magnetic resonance (NMR) relaxation time T2CP of adjacent water molecules measured by a Carr-Purcell-Meiboom-Gill (CPMG) pulse-echo sequence. This effect is commonly used to measure the concentrations of a variety of small molecules. We perform extensive Monte Carlo simulations of water diffusing around SPIO nanoparticle aggregates to determine the relationship between T2CP and details of the aggregate. We find that in the motional averaging regime T2CP scales as a power law with the number N of nanoparticles in an aggregate. The specific scaling is dependent on the fractal dimension d of the aggregates. We find T2CP∝N-0.44 for aggregates with d = 2.2, a value typical of diffusion limited aggregation. We also find that in two-nanoparticle systems, T2CP is strongly dependent on the orientation of the two nanoparticles relative to the external magnetic field, which implies that it may be possible to sense the orientation of a two-nanoparticle aggregate. To optimize the sensitivity of SPIO nanoparticle sensors, we propose that it is best to have aggregates with few nanoparticles, close together, measured with long pulse-echo times. PMID:20689678

  1. Investigating low frequency dielectric properties of a composite using the distribution of relaxation times technique

    SciTech Connect

    Tuncer, Enis

    2006-01-01

    The distribution of relaxation times approach, a less frequently employed dielectric data analysis technique, is utilized to better understand the relaxation characteristics of composites consisting of metal-coated, hollow glass spheres dispersed in a paraffin wax matrix. The dielectric properties of the composite samples are measured by means of impedance spectroscopy in the frequency range 0.1mHz to 10 MHz. The application of a mixture law is not appropriate for the analysis of the frequency-dependent properties of the considered system on this broad frequency range. However, utilization of the distribution of relaxation times procedure to study the dielectric behaviour shows clear trends in the mixtures' relaxation spectra. Relaxation processes of the paraffin wax and those specific to the composites are found from the extracted distribution of relaxation times spectra. The influence of the filler concentration, q, on the dielectric properties is examined; a relaxation with a narrow distribution at intermediate frequencies becomes broad with the addition of the filler. This relaxation, in the form of the low-frequency-dispersions (also known as constant phase angle) phenomenon, dominates the dielectric properties of the composites with high bead concentration, q > 0:15. The variation in dielectric properties of individual samples whose bead concentrations q are nominally the same is discussed in terms of possible microstructural variations.

  2. Investigating low-frequency dielectric properties of a composite using the distribution of relaxation times technique

    SciTech Connect

    Tuncer, Enis; Bowler, Nicola; Youngs, I. J.; Lymer, K. P.

    2006-01-01

    The distribution of relaxation times approach, a less frequently employed dielectric data analysis technique, is utilized to better understand the relaxation characteristics of composites consisting of metal-coated, hollow glass spheres dispersed in a paraffin wax matrix. The dielectric properties of the composite samples are measured by means of impedance spectroscopy in the frequency range 0.1 mHz to 10 MHz. The application of a mixture law is not appropriate for the analysis of the frequency-dependent properties of the considered system on this broad frequency range. However, utilization of the distribution of relaxation times procedure to study the dielectric behaviour shows clear trends in the mixtures' relaxation spectra. Relaxation processes of the paraffin wax and those specific to the composites are found from the extracted distribution of relaxation times spectra. The influence of the filler concentration, q, on the dielectric properties is examined; a relaxation with a narrow distribution at intermediate frequencies becomes broad with the addition of the filler. This relaxation, in the form of the low-frequency-dispersions (also known as constant phase angle) phenomenon, dominates the dielectric properties of the composites with high bead concentration, q>0.15. The variation in dielectric properties of individual samples whose bead concentrations q are nominally the same is discussed in terms of possible microstructural variations.

  3. Spin relaxation time dependence on optical pumping intensity in GaAs:Mn

    SciTech Connect

    Burobina, V.; Binek, Ch.

    2014-04-28

    We analyze the dependence of electron spin relaxation time on optical pumping intensity in a partially compensated acceptor semiconductor GaAs:Mn using analytic solutions for the kinetic equations of the charge carrier concentrations. Our results are applied to previous experimental data of spin-relaxation time vs. excitation power for magnetic concentrations of approximately 10{sup 17} cm{sup −3}. The agreement of our analytic solutions with the experimental data supports the mechanism of the earlier-reported atypically long electron-spin relaxation time in the magnetic semiconductor.

  4. Slow Dynamics in Berea Sandstone: a Non-logarithmic Relaxation at Early Times Revealed by Dynamic Acousto-Elasticity.

    NASA Astrophysics Data System (ADS)

    Riviere, J. V.; Shokouhi, P.; Marone, C.; Elsworth, D.; Guyer, R. A.; Johnson, P. A.

    2015-12-01

    We study nonlinear elastic/acoustic phenomena in rocks at the laboratory scale, with the goal of understanding observations at crustal scales, for instance during strong ground motion and earthquake slip processes. In particular, a long-term goal is to relate microstructure of rocks/gouge to nonlinear acoustic properties. A dynamic perturbation with modest (i.e. acoustic) strain amplitude (10-6 < ɛ < 10-5) in rocks typically leads to a transient elastic softening (elastic modulus decrease) followed by a log(t)-relaxation back to the initial elastic modulus as soon as the excitation is turned off. The relaxation typically lasts from minutes to hours depending on rock type and amplitude/duration/frequency of perturbation. This log(t)-recovery implies that no characteristic time or rate can be extracted, i.e., the relaxation spectrum is flat. In this study, we use Dynamic Acousto-Elasticity (DAE) to probe the relaxation characteristics of a sample of Berea sandstone to explore short-term relaxation, down to 10-4s (DAE is the dynamic equivalent of measuring acoustic velocity as a function of applied pressure). We find that early recovery does not follow a logarithmic law, while some earlier studies based on resonance techniques and at times larger than 1s do exhibit log(t)-recovery. From this non-log(t) dataset, we extract a spectrum of relaxation rates and discuss the potential relation between characteristic rates and rock microstructure. We also discuss the possible links between transient elastic softening and transient increase in permeability due to dynamic perturbation.

  5. Variable thermal properties and thermal relaxation time in hyperbolic heat conduction

    NASA Technical Reports Server (NTRS)

    Glass, David E.; Mcrae, D. Scott

    1989-01-01

    Numerical solutions were obtained for a finite slab with an applied surface heat flux at one boundary using both the hyperbolic (MacCormack's method) and parabolic (Crank-Nicolson method) heat conduction equations. The effects on the temperature distributions of varying density, specific heat, and thermal relaxation time were calculated. Each of these properties had an effect on the thermal front velocity (in the hyperbolic solution) as well as the temperatures in the medium. In the hyperbolic solutions, as the density or specific heat decreased with temperature, both the temperatures within the medium and the thermal front velocity increased. The value taken for the thermal relaxation time was found to determine the 'hyperbolicity' of the heat conduction model. The use of a time dependent relaxation time allowed for solutions where the thermal energy propagated as a high temperature wave initially, but approached a diffusion process more rapidly than was possible with a constant large relaxation time.

  6. Time-resolved positron annihilation spectroscopy study of relaxation dynamics of ion damage in fused quartz

    NASA Astrophysics Data System (ADS)

    Tsuchida, Hidetsugu; Mizuno, Shohei; Tsutsumi, Hironori; Kinomura, Atsushi; Suzuki, Ryoichi; Itoh, Akio

    2016-05-01

    Relaxation dynamics of ion damage in fused quartz is investigated by our newly developed pump–probe technique combining energetic ions (pump) with slow positrons (probe). This method enables determination of time-resolved positron lifetime. We study the time-dependent relaxation of ion damage, by analyzing the intensity variation in the ortho-positronium lifetime component associated with irradiation damage. For irradiation with 160 keV He ions in the temperature range of 300–573 K, the positron annihilation lifetime spectra are obtained as a function of time after ion irradiation. We observe that the relaxation time of ion damage is strongly influenced by specimen temperatures; the relaxation time constant is approximately 400 ms at room temperature (300 K) and becomes smaller with an increasing temperature. Analysis for the effect of temperature on damage accumulation reveals that the activation energy for thermal annealing of the observed damage is approximately 0.1 eV.

  7. The effect of fast electronic relaxation times on the 1H and 7Li magnetic relaxation dispersion modulated by the translational encounter of cation/cation pairs

    NASA Astrophysics Data System (ADS)

    Dinesen, T. R. J.; Bryant, R. G.

    1999-04-01

    1H and 7Li magnetic relaxation dispersion data are presented, showing the field dependence of the spin-lattice relaxation rates of (H 3C) 4N + and Li(H 2O) n+ in Gd(III) and Mn(II) solutions. The limit of short electronic relaxation time is observed for Gd(III) up to about 7 T, in contrast to Mn(II) solutions wherein the intermolecular contribution to nuclear relaxation is dominated by relative translational diffusion. These results contradict the assumption made by Fries et al. (Chem. Phys. Lett. 286 (1998) 93) that the electron relaxation times may be neglected in the analysis of tetramethylammonium proton relaxation rates in Gd(III) solutions.

  8. Secondary and primary relaxations in hyperbranched polyglycerol: a comparative study in the frequency and time domains.

    PubMed

    Garcia-Bernabé, Abel; Dominguez-Espinosa, Gustavo; Diaz-Calleja, Ricardo; Riande, Evaristo; Haag, Rainer

    2007-09-28

    The non-Debye relaxation behavior of hyperbranched polyglycerol was investigated by broadband dielectric spectroscopy. A thorough study of the relaxations was carried out paying special attention to truncation effects on deconvolutions of overlapping processes. Hyperbranched polyglycerol exhibits two relaxations in the glassy state named in increasing order of frequency beta and gamma processes. The study of the evolution of these two fast processes with temperature in the time retardation spectra shows that the beta absorption is swallowed by the alpha in the glass-liquid transition, the gamma absorption being the only relaxation that remains operative in the liquid state. In heating, a temperature is reached at which the alpha absorption vanishes appearing the alphagamma relaxation. Two characteristics of alpha absorptions, decrease of the dielectric strength with increasing temperature and rather high activation energy, are displayed by the alphagamma process. Williams' ansatz seems to hold for these topologically complex macromolecules. PMID:17902934

  9. Secondary and primary relaxations in hyperbranched polyglycerol: a comparative study in the frequency and time domains.

    PubMed

    Garcia-Bernabé, Abel; Dominguez-Espinosa, Gustavo; Diaz-Calleja, Ricardo; Riande, Evaristo; Haag, Rainer

    2007-09-28

    The non-Debye relaxation behavior of hyperbranched polyglycerol was investigated by broadband dielectric spectroscopy. A thorough study of the relaxations was carried out paying special attention to truncation effects on deconvolutions of overlapping processes. Hyperbranched polyglycerol exhibits two relaxations in the glassy state named in increasing order of frequency beta and gamma processes. The study of the evolution of these two fast processes with temperature in the time retardation spectra shows that the beta absorption is swallowed by the alpha in the glass-liquid transition, the gamma absorption being the only relaxation that remains operative in the liquid state. In heating, a temperature is reached at which the alpha absorption vanishes appearing the alphagamma relaxation. Two characteristics of alpha absorptions, decrease of the dielectric strength with increasing temperature and rather high activation energy, are displayed by the alphagamma process. Williams' ansatz seems to hold for these topologically complex macromolecules.

  10. Mesoscopic dynamics of fermionic cold atoms - Quantitative analysis of transport coefficients and relaxation times

    NASA Astrophysics Data System (ADS)

    Kikuchi, Yuta; Tsumura, Kyosuke; Kunihiro, Teiji

    2016-05-01

    We give a quantitative analysis of the dynamical properties of fermionic cold atomic gases in normal phase, such as the shear viscosity, heat conductivity, and viscous relaxation times, using the novel microscopic expressions derived by the renormalization group (RG) method, where the Boltzmann equation is faithfully solved to extract the hydrodynamics without recourse to any ansatz. In particular, we examine the quantum statistical effects, temperature dependence, and scattering-length dependence of the transport coefficients and the viscous relaxation times. The numerical calculation shows that the relation τπ = η / P, which is derived in the relaxation-time approximation (RTA) and is used in most of the literature, turns out to be satisfied quite well, while the similar relation for the viscous relaxation time τJ of the heat conductivity is satisfied only approximately with a considerable error.

  11. Multiple-relaxation-time lattice Boltzmann modeling of incompressible flows in porous media

    NASA Astrophysics Data System (ADS)

    Liu, Qing; He, Ya-Ling

    2015-07-01

    In this paper, a two-dimensional eight-velocity multiple-relaxation-time (MRT) lattice Boltzmann (LB) model is proposed for incompressible porous flows at the representative elementary volume scale based on the Brinkman-Forchheimer-extended Darcy model. In the model, the porosity is included into the pressure-based equilibrium moments, and the linear and nonlinear drag forces of the porous matrix are incorporated into the model by adding a forcing term to the MRT-LB equation in the moment space. Through the Chapman-Enskog analysis, the incompressible generalized Navier-Stokes equations can be recovered. Numerical simulations of several typical porous flows are carried out to validate the present MRT-LB model. It is found that the present numerical results agree well with the analytical solutions and/or other numerical results reported in the literature.

  12. Probing the Nuclear Spin-Lattice Relaxation Time at the Nanoscale

    NASA Astrophysics Data System (ADS)

    Wagenaar, J. J. T.; den Haan, A. M. J.; de Voogd, J. M.; Bossoni, L.; de Jong, T. A.; de Wit, M.; Bastiaans, K. M.; Thoen, D. J.; Endo, A.; Klapwijk, T. M.; Zaanen, J.; Oosterkamp, T. H.

    2016-07-01

    Nuclear spin-lattice relaxation times are measured on copper using magnetic-resonance force microscopy performed at temperatures down to 42 mK. The low temperature is verified by comparison with the Korringa relation. Measuring spin-lattice relaxation times locally at very low temperatures opens up the possibility to measure the magnetic properties of inhomogeneous electron systems realized in oxide interfaces, topological insulators, and other strongly correlated electron systems such as high-Tc superconductors.

  13. Time scales of Magmatic Processes

    NASA Astrophysics Data System (ADS)

    Hawkesworth, C. J.

    2002-05-01

    Knowledge of the rates of natural processes is critical to the development of physically realistic models. For magmatic processes, rates are increasingly well determined from short lived isotopes, and from diffusion modified element profiles, on time scales that vary from 10s of 1000s of years to a few years. Our understanding of the melting processes beneath MOR have been revolutionised by the application of U-series isotopes, because they include isotopes with half lives similar to the time scales of melt generation and extraction. For island arcs there is much discussion of how to incorporate suggestions that Ra and Ba are transferred from the slab in a few 1000 years, and yet significantly more time is required to generate the excess Pa isotopes. Once in the crust, crystallisation and differentiation may be driven by cooling, degassing and decompression, and these should be characterised by different time scales. Crystals preserve rich high-resolution records of changing magma compositions, but the time scales of those changes are difficult to establish. Isotope studies have shown that more evolved rock types tend to contain more old crystals that may be 10s of 1000s of years old at the time of eruption. Whether these are xenocrysts, or evidence for long term crystallisation histories remains controversial. Moreover, diffusion modified element profiles, and crystal size distributions, suggest that crystals are often less than a 100 years old. An alternative approach is to consider U-series isotope ratios in the magma, and how these may change with degree of magma evolution. These suggest that differentiation time scales may be up to 200 ky for magmas at the base of the crust, but for magmas that crystallise at shallower levels the time scales are much shorter. In some cases these are in weeks and months, and crystallisation is likely to be due to decompression and degassing. One consequence of the short crystallisation times, is that there may be insufficient

  14. Multi-scales nuclear spin relaxation of liquids in porous media

    NASA Astrophysics Data System (ADS)

    Korb, Jean-Pierre

    2010-03-01

    The magnetic field dependence of the nuclear spin-lattice relaxation rate 1/T(ω) is a rich source of dynamical information for characterizing the molecular dynamics of liquids in confined environments. Varying the magnetic field changes the Larmor frequency ω, and thus the fluctuations to which the nuclear spin relaxation is sensitive. Moreover, this method permits a more complete characterization of the dynamics than the usual measurements as a function of temperature at fixed magnetic field strength, because many common solvent liquids have phase transitions that may alter significantly the character of the dynamics over the temperature range usually studied. Further, the magnetic field dependence of the spin-lattice relaxation rate, 1/T(ω), provides a good test of the theories that relate the measurement to the microdynamical behavior of the liquid. This is especially true in spatially confined systems where the effects of reduced dimensionality may force more frequent reencounters of the studied proton spin-bearing molecules with paramagnetic impurities at the pore surfaces that may alter the correlation functions that enter the relaxation equations in a fundamental way. We show by low field NMR relaxation that changing the amount of surface paramagnetic impurities leads to striking different pore-size dependences of the relaxation times T and T of liquids in pores. Here, we focus mainly on high surface area porous materials including calibrated porous silica glasses, granular packings, heterogeneous catalytic materials, cement-based materials and natural porous materials such as clay minerals and rocks. Recent highlights NMR relaxation works are reviewed for these porous materials, like continuous characterization of the evolving microstructure of various cementitious materials and measurement of wettability in reservoir carbonate rocks. Although, the recent applications of 2-dimensional T-T and T-z-store-T correlation experiments for characterization of

  15. Difference-NMR techniques for selection of components on the basis of relaxation times

    NASA Astrophysics Data System (ADS)

    Harris, Douglas J.; de Azevedo, Eduardo R.; Bonagamba, Tito J.

    2003-05-01

    This work describes a numerical methodology to obtain more efficient relaxation filters to selectively retain or remove components based on relaxation times. The procedure uses linear combinations of spectra with various recycle or filter delays to obtain components that are both quantitative and pure. Modulation profiles are calculated assuming exponential relaxation behavior. The method is general and can be applied to a wide range of solution or solid-state NMR experiments including direct-polarization (DP), or filtered cross-polarization (CP) spectra. 13C NMR experiments on isotactic poly(1-butene) and dimethyl sulfone showed the utility of the technique for selectively suppressing peaks.

  16. Cosmology and astrophysics from relaxed galaxy clusters - III. Thermodynamic profiles and scaling relations

    NASA Astrophysics Data System (ADS)

    Mantz, A. B.; Allen, S. W.; Morris, R. G.; Schmidt, R. W.

    2016-03-01

    This is the third in a series of papers studying the astrophysics and cosmology of massive, dynamically relaxed galaxy clusters. Our sample comprises 40 clusters identified as being dynamically relaxed and hot (i.e. massive) in Papers I and II of this series. Here we consider the thermodynamics of the intracluster medium, in particular the profiles of density, temperature and related quantities, as well as integrated measurements of gas mass, average temperature, total luminosity and centre-excluded luminosity. We fit power-law scaling relations of each of these quantities as a function of redshift and cluster mass, which can be measured precisely and with minimal bias for these relaxed clusters using hydrostatic arguments. For the thermodynamic profiles, we jointly model the density and temperature and their intrinsic scatter as a function of radius, thus also capturing the behaviour of the gas pressure and entropy. For the integrated quantities, we also jointly fit a multidimensional intrinsic covariance. Our results reinforce the view that simple hydrodynamical models provide a good description of relaxed clusters outside their centres, but that additional heating and cooling processes are important in the inner regions (radii r ≲ 0.5 r2500 ≈ 0.15 r500). The thermodynamic profiles remain regular, with small intrinsic scatter, down to the smallest radii where deprojection is straightforward (˜20 kpc); within this radius, even the most relaxed systems show clear departures from spherical symmetry. Our results suggest that heating and cooling are continuously regulated in a tight feedback loop, allowing the cluster atmosphere to remain stratified on these scales.

  17. Relaxation Time Distribution (RTD) of Spectral Induced Polarization (SIP) data from environmental studies

    NASA Astrophysics Data System (ADS)

    Ntarlagiannis, D.; Ustra, A.; Slater, L. D.; Zhang, C.; Mendonça, C. A.

    2015-12-01

    In this work we present an alternative formulation of the Debye Decomposition (DD) of complex conductivity spectra, with a new set of parameters that are directly related to the continuous Debye relaxation model. The procedure determines the relaxation time distribution (RTD) and two frequency-independent parameters that modulate the induced polarization spectra. The distribution of relaxation times quantifies the contribution of each distinct relaxation process, which can in turn be associated with specific polarization processes and characterized in terms of electrochemical and interfacial parameters as derived from mechanistic models. Synthetic tests show that the procedure can successfully fit spectral induced polarization (SIP) data and accurately recover the RTD. The procedure was applied to different data sets, focusing on environmental applications. We focus on data of sand-clay mixtures artificially contaminated with toluene, and crude oil-contaminated sands experiencing biodegradation. The results identify characteristic relaxation times that can be associated with distinct polarization processes resulting from either the contaminant itself or transformations associated with biodegradation. The inversion results provide information regarding the relative strength and dominant relaxation time of these polarization processes.

  18. Rotational relaxation times of individual compounds within simulations of molecular asphalt models

    NASA Astrophysics Data System (ADS)

    Zhang, Liqun; Greenfield, Michael L.

    2010-05-01

    The dynamical properties of a complex system incorporate contributions from the diverse components from which it is constituted. To study this relationship in a multicomponent system, relaxation times based on rotation autocorrelation functions in molecular dynamics simulations were analyzed for molecules in two sets of unmodified and polymer-modified model asphalt/bitumen systems over 298-473 K. The model asphalt systems were proposed previously to approximate the chemical and mechanical properties of real asphalts. Relaxations were modeled using a modified Kaulrausch-Williams-Watts function and were based on the third Legendre polynomial of normal vector time correlation functions for aromatic species (asphaltene, polar aromatic, naphthene aromatic). Both the end-to-end vector and the longest axis eigenvector of the radius of gyration matrix were used for time correlation functions of chain molecules (C22, polystyrene). Decreases in temperature induced large increases in relaxation time consistent with the Vogel-Fulcher-Tammann equation. The presence of a polymer slowed the decay of each correlation function to some extent. The product of relaxation time and diffusion coefficient revealed qualitative differences between larger and smaller molecules in the same system. These relaxation mechanisms remained coupled for small molecules, while the larger asphaltene and polymer molecules revealed significant slowdowns in rotation compared to translational diffusion at lower temperatures. Smaller values of the stretched exponential parameter β for asphaltenes compared to smaller molecules suggested a broader range of relaxation times and were consistent with this distinction. Difficulties in converging polymer chain relaxation times are discussed in terms of fluctuations in the magnitude and orientation of the end-to-end vector and chain axis eigenvector. Viscosity results suggested by the Debye-Stokes-Einstein relationship are consistent with trends shown in the

  19. Time-Dependent Behaviors of Granite: Loading-Rate Dependence, Creep, and Relaxation

    NASA Astrophysics Data System (ADS)

    Hashiba, K.; Fukui, K.

    2016-07-01

    To assess the long-term stability of underground structures, it is important to understand the time-dependent behaviors of rocks, such as their loading-rate dependence, creep, and relaxation. However, there have been fewer studies on crystalline rocks than on tuff, mudstone, and rock salt, because the high strength of crystalline rocks makes the detection of their time-dependent behaviors much more difficult. Moreover, studies on the relaxation, temporal change of stress and strain (TCSS) conditions, and relations between various time-dependent behaviors are scarce for not only granites, but also other rocks. In this study, previous reports on the time-dependent behaviors of granites were reviewed and various laboratory tests were conducted using Toki granite. These tests included an alternating-loading-rate test, creep test, relaxation test, and TCSS test. The results showed that the degree of time dependence of Toki granite is similar to other granites, and that the TCSS resembles the stress-relaxation curve and creep-strain curve. A viscoelastic constitutive model, proposed in a previous study, was modified to investigate the relations between the time-dependent behaviors in the pre- and post-peak regions. The modified model reproduced the stress-strain curve, creep, relaxation, and the results of the TCSS test. Based on a comparison of the results of the laboratory tests and numerical simulations, close relations between the time-dependent behaviors were revealed quantitatively.

  20. Microscopic photometric quantification of stiffness and relaxation time of red blood cells in a flow chamber.

    PubMed

    Artmann, G M

    1995-01-01

    The Microscopic Photometric Monolayer Technique provides a tool to measure red blood cell (RBC) stiffness (resistance to elongation) and relaxation time. It combines many of the advantages of flow channel studies of point-attached RBCs with the simplicity, sensitivity and accuracy of photometric light transmission measurement. This technique allows the study of the effects of physicochemical factors on the elongation and relaxation time of the same cells within an average of four to five thousand cells adhered as a monolayer to glass. Further, the time course of physicochemical effects on cell membrane and wash-in/wash-out kinetics of interactions can be followed. An automated version of this technique was developed. A dense monolayer of point-attached RBCs was prepared at the bottom of a flow-chamber. A steady-state flow, with stepwise increases of flow rate, induced the RBC elongation. The light transmission perpendicular through the monolayer plane was measured photometrically. Photomicrographs compared with photometric results showed that the flow-induced bending and curvature change of RBC membrane was associated with the increase of light transmission. There was a linear correlation between the photometric index of elongation and the elongation taken from photomicrographs for shear stresses up to 0.75 Pa. A stiffness parameter, S (in Pa), was defined as the ratio of shear stress and elongation at a shear stress of 0.25 Pa. Following a sudden flow stoppage, the RBCs returned to their resting shape and the RBC relaxation time was measured. The stiffness-relaxation time product, V (in mPas), was calculated to provide an estimate of viscosity. Diamide treatment, known to stiffen RBCs, did result in dose-dependent decreases of elongation and relaxation time. With increasing temperature, the relaxation time decreased at a rate of -2.96 ms/K; the stiffness increased significantly at a rate of 0.0038 Pa/K, and the stiffness-relaxation time product decreased with -2

  1. Ultrafast NMR T1 Relaxation Measurements: Probing Molecular Properties in Real Time

    PubMed Central

    Smith, Pieter E. S.; Donovan, Kevin J.; Szekely, Or; Baias, Maria; Frydman, Lucio

    2016-01-01

    The longitudinal relaxation properties of NMR active nuclei carry useful information about the site-specific chemical environments and about the mobility of molecular fragments. Molecular mobility is in turn a key parameter reporting both on stable properties like size, as well as on dynamic ones such as transient interactions and irreversible aggregation. In order to fully investigate the latter, a fast sampling of the relaxation parameters of transiently formed molecular species may be needed. Nevertheless, the acquisition of longitudinal relaxation data is typically slow, being limited by the requirement that the time for which the nucleus relaxes be varied incrementally until a complete build-up curve is generated. Recently a number of single-shot inversion recovery methods have been developed capable of alleviating this need; still, these may be challenged by either spectral resolution restrictions or when coping with very fast relaxing nuclei. Here we present a new experiment to measure the T1s of multiple nuclear spins that experience fast longitudinal relaxation, while retaining full high-resolution chemical shift information. Good agreement is observed between T1s measured with conventional means and T1s measured using the new technique. The method is applied to the real time investigation of the reaction between D-xylose and sodium borate, which is in turn elucidated with the aid of ancillary ultrafast and conventional 2D TOCSY measurements. PMID:23878001

  2. Double multiple-relaxation-time lattice Boltzmann model for solid-liquid phase change with natural convection in porous media

    NASA Astrophysics Data System (ADS)

    Liu, Qing; He, Ya-Ling

    2015-11-01

    In this paper, a double multiple-relaxation-time lattice Boltzmann model is developed for simulating transient solid-liquid phase change problems in porous media at the representative elementary volume scale. The model uses two different multiple-relaxation-time lattice Boltzmann equations, one for the flow field and the other for the temperature field with nonlinear latent heat source term. The model is based on the generalized non-Darcy formulation, and the solid-liquid interface is traced through the liquid fraction which is determined by the enthalpy-based method. The present model is validated by numerical simulations of conduction melting in a semi-infinite space, solidification in a semi-infinite corner, and convection melting in a square cavity filled with porous media. The numerical results demonstrate the efficiency and accuracy of the present model for simulating transient solid-liquid phase change problems in porous media.

  3. Multiple conformational states of the hammerhead ribozyme, broad time range of relaxation and topology of dynamics

    PubMed Central

    Menger, Marcus; Eckstein, Fritz; Porschke, Dietmar

    2000-01-01

    The dynamics of a hammerhead ribozyme was analyzed by measurements of fluorescence-detected temperature jump relaxation. The ribozyme was substituted at different positions by 2-aminopurine (2-AP) as fluorescence indicator; these substitutions do not inhibit catalysis. The general shape of relaxation curves reported from different positions of the ribozyme is very similar: a fast decrease of fluorescence, mainly due to physical quenching, is followed by a slower increase of fluorescence due to conformational relaxation. In most cases at least three relaxation time constants in the time range from a few microseconds to ~200 ms are required for fitting. Although the relaxation at different positions of the ribozyme is similar in general, suggesting a global type of ribozyme dynamics, a close examination reveals differences, indicating an individual local response. For example, 2-AP in a tetraloop reports mainly the local loop dynamics known from isolated loops, whereas 2-AP located at the core, e.g. at the cleavage site or its vicinity, also reports relatively large amplitudes of slower components of the ribozyme dynamics. A variant with an A→G substitution in domain II, resulting in an inactive form, leads to the appearance of a particularly slow relaxation process (τ ≈200 ms). Addition of Mg2+ ions induces a reduction of amplitudes and in most cases a general increase of time constants. Differences between the hammerhead variants are clearly demonstrated by subtraction of relaxation curves recorded under corresponding conditions. The changes induced in the relaxation response by Mg2+ are very similar to those induced by Ca2+. The relaxation data do not provide any evidence for formation of Mg2+-inner sphere complexes in hammerhead ribozymes, because a Mg2+-specific relaxation effect was not visible. However, a Mg2+-specific effect was found for a dodeca-riboadenylate substituted with 2-AP, showing that the fluorescence of 2-AP is able to indicate inner sphere

  4. Dielectric relaxation time of bulk water at 136-140 K, background loss and crystallization effects

    NASA Astrophysics Data System (ADS)

    Johari, G. P.

    2005-04-01

    Dielectric relaxation time, τ, of ultraviscous bulk water has been determined by analyzing its loss tangent, tanδ, data, which had been measured on heating the vapor-deposited amorphous solid water and hyperquenched glassy water in our earlier studies. [Johari, Hallbrucker, and Mayer, J. Chem. Phys. 95, 2955 (1991); 97, 5851 (1992)]. As for glasses and liquids generally, the measured tanδ of water is the sum of a frequency-independent background loss and a frequency-dependent relaxational loss. A two-frequency method is provided for determining the background loss and used for obtaining the relaxational part of tanδ. After considering the structural relaxation and crystal-nuclei growth effects, τ for water has been determined. At 136±1K, it is 2.5±0.6s when a single relaxation time is (untenably) assumed, and 42±14s when a distribution of relaxation times, a characteristic of viscous liquids, is assumed, with Davidson-Cole distribution parameter of 0.75. Structural relaxation time of ˜70s for water at 136K, which was originally estimated from the DSC endotherm [Johari, Hallbrucker, and Mayer, Nature (London) 330, 552 (1987)], has been revised to ˜33s. Temperature dependence of τ could not be determined because ultraviscous water crystallizes too rapidly to cubic ice containing stacking faults and intergranular water. The study demonstrates that water is a liquid over the 136-155K range, thus removing the basis for a recent contention on its state.

  5. Time scales in cognitive neuroscience

    PubMed Central

    Papo, David

    2013-01-01

    Cognitive neuroscience boils down to describing the ways in which cognitive function results from brain activity. In turn, brain activity shows complex fluctuations, with structure at many spatio-temporal scales. Exactly how cognitive function inherits the physical dimensions of neural activity, though, is highly non-trivial, and so are generally the corresponding dimensions of cognitive phenomena. As for any physical phenomenon, when studying cognitive function, the first conceptual step should be that of establishing its dimensions. Here, we provide a systematic presentation of the temporal aspects of task-related brain activity, from the smallest scale of the brain imaging technique's resolution, to the observation time of a given experiment, through the characteristic time scales of the process under study. We first review some standard assumptions on the temporal scales of cognitive function. In spite of their general use, these assumptions hold true to a high degree of approximation for many cognitive (viz. fast perceptual) processes, but have their limitations for other ones (e.g., thinking or reasoning). We define in a rigorous way the temporal quantifiers of cognition at all scales, and illustrate how they qualitatively vary as a function of the properties of the cognitive process under study. We propose that each phenomenon should be approached with its own set of theoretical, methodological and analytical tools. In particular, we show that when treating cognitive processes such as thinking or reasoning, complex properties of ongoing brain activity, which can be drastically simplified when considering fast (e.g., perceptual) processes, start playing a major role, and not only characterize the temporal properties of task-related brain activity, but also determine the conditions for proper observation of the phenomena. Finally, some implications on the design of experiments, data analyses, and the choice of recording parameters are discussed. PMID:23626578

  6. Rotational-angular-momentum relaxation mechanisms in the energy-corrected-sudden scaling theory

    NASA Astrophysics Data System (ADS)

    Bonamy, L.; Emond, F.

    1995-02-01

    In calculating the infrared (IR) band shape for bending modes, the angular-momentum coupling between vibration, rotation, and radiation must be taken into account. The accuracy of the energy-corrected-sudden (ECS) model has been proved through many recent applications in isotropic Raman Q-branch profiles. Furthermore, this model is based on the physical infinite-order-sudden (IOS) approximation, which allows inclusion of the other relaxation mechanisms required when considering other spectroscopic branches, such as IR Q-bending bands. To include, in a consistent way, the role of the vibrational angular momentum in the rovibrational relaxation matrix, the relaxation of the rotational angular momentum J and of its associated higher-order tensors [J](2),. . . (basically absent in the IOS approximation) is enforced in the present ECS model. Application to the 2076.86 cm-1 infrared rovibrational band of 12C16O2 leads to the determination of the [J](2) relaxation time in agreement with previous values obtained from different measurements. The present theory may be applied to other spectroscopic bands, such as the anisotropic Raman ones.

  7. Probing of structural relaxation times in the glassy state of sucrose and trehalose based on dynamical properties of two secondary relaxation processes

    SciTech Connect

    Kaminski, K.; Adrjanowicz, K.; Paluch, M.; Kaminska, E.

    2011-06-15

    Time-dependent isothermal dielectric measurements were carried out deeply in the glassy state on two very important saccharides: sucrose and trehalose. In both compounds two prominent secondary relaxation processes were identified. The faster one is an inherent feature of the whole family of carbohydrates. The slower one can also be detected in oligo- and polysaccharides. It was shown earlier that the {beta} process is the Johari-Goldstein (JG) relaxation coupled to motions of the glycosidic linkage, while the {gamma} relaxation originates from motions of the exocyclic hydroxymethyl unit. Recently, it was shown that the JG relaxation process can be used to determine structural relaxation times in the glassy state [R. Casalini and C. M. Roland, Phys. Rev. Lett. 102, 035701 (2009)]. In this paper we present the results of an analysis of the data obtained during aging using two independent approaches. The first was proposed by Casalini and Roland, and the second one is based on the variation of the dielectric strength of the secondary relaxation process during aging [J. K. Vij and G. Power, J. Non-Cryst. Solids 357, 783 (2011)]. Surprisingly, we found that the estimated structural relaxation times in the glassy state of both saccharides are almost the same, independent of the type of secondary mode. This finding calls into question the common view that secondary modes of intramolecular origin do not provide information about the dynamics of the glassy state.

  8. Understanding generalized inversions of nuclear magnetic resonance transverse relaxation time in porous media.

    PubMed

    Mitchell, J; Chandrasekera, T C

    2014-12-14

    The nuclear magnetic resonance transverse relaxation time T2, measured using the Carr-Purcell-Meiboom-Gill (CPMG) experiment, is a powerful method for obtaining unique information on liquids confined in porous media. Furthermore, T2 provides structural information on the porous material itself and has many applications in petrophysics, biophysics, and chemical engineering. Robust interpretation of T2 distributions demands appropriate processing of the measured data since T2 is influenced by diffusion through magnetic field inhomogeneities occurring at the pore scale, caused by the liquid/solid susceptibility contrast. Previously, we introduced a generic model for the diffusion exponent of the form -ante(k) (where n is the number and te the temporal separation of spin echoes, and a is a composite diffusion parameter) in order to distinguish the influence of relaxation and diffusion in CPMG data. Here, we improve the analysis by introducing an automatic search for the optimum power k that best describes the diffusion behavior. This automated method is more efficient than the manual trial-and-error grid search adopted previously, and avoids variability through subjective judgments of experimentalists. Although our method does not avoid the inherent assumption that the diffusion exponent depends on a single k value, we show through simulation and experiment that it is robust in measurements of heterogeneous systems that violate this assumption. In this way, we obtain quantitative T2 distributions from complicated porous structures and demonstrate the analysis with examples of ceramics used for filtration and catalysis, and limestone of relevance to the construction and petroleum industries. PMID:25494741

  9. Understanding generalized inversions of nuclear magnetic resonance transverse relaxation time in porous media.

    PubMed

    Mitchell, J; Chandrasekera, T C

    2014-12-14

    The nuclear magnetic resonance transverse relaxation time T2, measured using the Carr-Purcell-Meiboom-Gill (CPMG) experiment, is a powerful method for obtaining unique information on liquids confined in porous media. Furthermore, T2 provides structural information on the porous material itself and has many applications in petrophysics, biophysics, and chemical engineering. Robust interpretation of T2 distributions demands appropriate processing of the measured data since T2 is influenced by diffusion through magnetic field inhomogeneities occurring at the pore scale, caused by the liquid/solid susceptibility contrast. Previously, we introduced a generic model for the diffusion exponent of the form -ante(k) (where n is the number and te the temporal separation of spin echoes, and a is a composite diffusion parameter) in order to distinguish the influence of relaxation and diffusion in CPMG data. Here, we improve the analysis by introducing an automatic search for the optimum power k that best describes the diffusion behavior. This automated method is more efficient than the manual trial-and-error grid search adopted previously, and avoids variability through subjective judgments of experimentalists. Although our method does not avoid the inherent assumption that the diffusion exponent depends on a single k value, we show through simulation and experiment that it is robust in measurements of heterogeneous systems that violate this assumption. In this way, we obtain quantitative T2 distributions from complicated porous structures and demonstrate the analysis with examples of ceramics used for filtration and catalysis, and limestone of relevance to the construction and petroleum industries.

  10. Understanding generalized inversions of nuclear magnetic resonance transverse relaxation time in porous media

    NASA Astrophysics Data System (ADS)

    Mitchell, J.; Chandrasekera, T. C.

    2014-12-01

    The nuclear magnetic resonance transverse relaxation time T2, measured using the Carr-Purcell-Meiboom-Gill (CPMG) experiment, is a powerful method for obtaining unique information on liquids confined in porous media. Furthermore, T2 provides structural information on the porous material itself and has many applications in petrophysics, biophysics, and chemical engineering. Robust interpretation of T2 distributions demands appropriate processing of the measured data since T2 is influenced by diffusion through magnetic field inhomogeneities occurring at the pore scale, caused by the liquid/solid susceptibility contrast. Previously, we introduced a generic model for the diffusion exponent of the form -ant_e^k (where n is the number and te the temporal separation of spin echoes, and a is a composite diffusion parameter) in order to distinguish the influence of relaxation and diffusion in CPMG data. Here, we improve the analysis by introducing an automatic search for the optimum power k that best describes the diffusion behavior. This automated method is more efficient than the manual trial-and-error grid search adopted previously, and avoids variability through subjective judgments of experimentalists. Although our method does not avoid the inherent assumption that the diffusion exponent depends on a single k value, we show through simulation and experiment that it is robust in measurements of heterogeneous systems that violate this assumption. In this way, we obtain quantitative T2 distributions from complicated porous structures and demonstrate the analysis with examples of ceramics used for filtration and catalysis, and limestone of relevance to the construction and petroleum industries.

  11. Understanding generalized inversions of nuclear magnetic resonance transverse relaxation time in porous media

    SciTech Connect

    Mitchell, J.; Chandrasekera, T. C.

    2014-12-14

    The nuclear magnetic resonance transverse relaxation time T{sub 2}, measured using the Carr-Purcell-Meiboom-Gill (CPMG) experiment, is a powerful method for obtaining unique information on liquids confined in porous media. Furthermore, T{sub 2} provides structural information on the porous material itself and has many applications in petrophysics, biophysics, and chemical engineering. Robust interpretation of T{sub 2} distributions demands appropriate processing of the measured data since T{sub 2} is influenced by diffusion through magnetic field inhomogeneities occurring at the pore scale, caused by the liquid/solid susceptibility contrast. Previously, we introduced a generic model for the diffusion exponent of the form −ant{sub e}{sup k} (where n is the number and t{sub e} the temporal separation of spin echoes, and a is a composite diffusion parameter) in order to distinguish the influence of relaxation and diffusion in CPMG data. Here, we improve the analysis by introducing an automatic search for the optimum power k that best describes the diffusion behavior. This automated method is more efficient than the manual trial-and-error grid search adopted previously, and avoids variability through subjective judgments of experimentalists. Although our method does not avoid the inherent assumption that the diffusion exponent depends on a single k value, we show through simulation and experiment that it is robust in measurements of heterogeneous systems that violate this assumption. In this way, we obtain quantitative T{sub 2} distributions from complicated porous structures and demonstrate the analysis with examples of ceramics used for filtration and catalysis, and limestone of relevance to the construction and petroleum industries.

  12. Time derivatives of the spectrum: Relaxing the stationarity assumption

    NASA Astrophysics Data System (ADS)

    Prieto, G. A.; Thomson, D. J.; Vernon, F. L.

    2005-12-01

    Spectrum analysis of seismic waveforms has played a significant role towards the understanding of multiple aspects of Earth structure and earthquake source physics. In recent years the multitaper spectrum estimation approach (Thomson, 1982) has been applied to geophysical problems providing not only reliable estimates of the spectrum, but also estimates of spectral uncertainties (Thomson and Chave, 1991). However, these improved spectral estimates were developed under the assumption of local stationarity and provide an incomplete description of the observed process. It is obvious that due to the intrinsic attenuation of the Earth, the amplitudes, and thus the frequency contents are changing with time as waves pass through a seismic station. There have been incredible improvements in different techniques to analyze non-stationary signals, including wavelet decomposition, Wigner-Ville spectrum and the dual-frequency spectrum. We apply one of the recently developed techniques, the Quadratic Inverse Theory (Thomson, 1990, 1994), combined with the multitaper technique to look at the time derivatives of the spectrum. If the spectrum is reasonably white in a certain bandwidth, using QI theory, we can estimate the derivatives of the spectrum at each frequency. We test synthetic signals to corroborate the approach and apply it the records of small earthquakes at local distances. This is a first approach to try and combine the classical spectrum analysis without the assumption of stationarity that is generally taken.

  13. Option pricing during post-crash relaxation times

    NASA Astrophysics Data System (ADS)

    Dibeh, Ghassan; Harmanani, Haidar M.

    2007-07-01

    This paper presents a model for option pricing in markets that experience financial crashes. The stochastic differential equation (SDE) of stock price dynamics is coupled to a post-crash market index. The resultant SDE is shown to have stock price and time dependent volatility. The partial differential equation (PDE) for call prices is derived using risk-neutral pricing. European call prices are then estimated using Monte Carlo and finite difference methods. Results of the model show that call option prices after the crash are systematically less than those predicted by the Black-Scholes model. This is a result of the effect of non-constant volatility of the model that causes a volatility skew.

  14. Relaxation times in deformed polymer glasses: A comparison between molecular simulations and two theories

    NASA Astrophysics Data System (ADS)

    Rottler, Jörg

    2016-08-01

    Relaxation times in polymer glasses are computed with molecular dynamics simulations of a coarse-grained polymer model during creep and constant strain rate deformation. The dynamics is governed by a competition between physical aging that increases relaxation times and applied load or strain rate which accelerates dynamics. We compare the simulation results quantitatively to two recently developed theories of polymer deformation, which treat aging and rejuvenation in an additive manner. Through stress release and strain rate reversal simulations, we then show that the quantity governing mechanical rejuvenation is the rate of irreversible work performed on the polymer.

  15. Direct Visualization of Short Transverse Relaxation Time Component (ViSTa)

    PubMed Central

    Oh, Se-Hong; Bilello, Michel; Schindler, Matthew; Markowitz, Clyde E.; Detre, John A.; Lee, Jongho

    2013-01-01

    White matter of the brain has been demonstrated to have multiple relaxation components. Among them, the short transverse relaxation time component (T2 < 40 ms; T2* < 25 ms at 3T) has been suggested to originate from myelin water whereas long transverse relaxation time components have been associated with axonal and/or interstitial water. In myelin water imaging, T2 or T2* signal decay is measured to estimate myelin water fraction based on T2 or T2* differences among the water components. This method has been demonstrated to be sensitive to demyelination in the brain but suffers from low SNR and image artifacts originating from ill-conditioned multi-exponential fitting. In this study, a novel approach that selectively acquires short transverse relaxation time signal is proposed. The method utilizes a double inversion RF pair to suppress a range of long T1 signal. This suppression leaves short T2* signal, which has been suggested to have short T1, as the primary source of the image. The experimental results confirms that after suppression of long T1 signals, the image is dominated by short T2* in the range of myelin water, allowing us to directly visualize the short transverse relaxation time component in the brain. Compared to conventional myelin water imaging, this new method of direct visualization of short relaxation time component (ViSTa) provides high quality images. When applied to multiple sclerosis patients, chronic lesions show significantly reduced signal intensity in ViSTa images suggesting sensitivity to demyelination. PMID:23796545

  16. The effects of bone on proton NMR relaxation times of surrounding liquids

    NASA Technical Reports Server (NTRS)

    Davis, C. A.; Genant, H. K.; Dunham, J. S.

    1986-01-01

    Preliminary attempts by our group at UCSF to assess fat content of vertebral marrow in the lumbar spine using relaxation time information demonstrated that the presence of trabecular bone affects relaxation times. The objective of this work was a thorough study of the effects of bone on NMR relaxation characteristics of surrounding liquids. Trabecular bone from autopsy specimens was ground up and sifted into a series of powders with graded densities ranging from 0.3 gm/cc to 0.8 gm/cc. Each powder was placed first in n-saline and then in cottonseed oil. With spectroscopy, spin-lattice relaxation times (T1) and effective spin-spin relaxation times (T2*) were measured for each liquid in each bone powder. As bone density and surface to volume ratio increased, T1 decreased faster for saline than for oil. T2* decreased significantly for both water and oil as the surface to volume ratio increased. It was concluded that effects of water on T1 could be explained by a surface interaction at the bone/liquid interface, which restricted rotational and translational motion of nearby molecules. The T1s of oil were not affected since oil molecules are nonpolar, do not participate in significant intermolecular hydrogen bonding, and therefore would not be expected to interact strongly with the bone surface. Effects on T2* could be explained by local magnetic field inhomogeneities created by discontinuous magnetic susceptibility near the bone surface. These preliminary results suggest that water in contact with trabecular bone in vivo will exhibit shortened relaxation times.

  17. Direct visualization of short transverse relaxation time component (ViSTa).

    PubMed

    Oh, Se-Hong; Bilello, Michel; Schindler, Matthew; Markowitz, Clyde E; Detre, John A; Lee, Jongho

    2013-12-01

    White matter of the brain has been demonstrated to have multiple relaxation components. Among them, the short transverse relaxation time component (T2<40 ms; T2⁎<25 ms at 3 T) has been suggested to originate from myelin water whereas long transverse relaxation time components have been associated with axonal and/or interstitial water. In myelin water imaging, T2 or T2⁎ signal decay is measured to estimate myelin water fraction based on T2 or T2⁎ differences among the water components. This method has been demonstrated to be sensitive to demyelination in the brain but suffers from low SNR and image artifacts originating from ill-conditioned multi-exponential fitting. In this study, a novel approach that selectively acquires short transverse relaxation time signal is proposed. The method utilizes a double inversion RF pair to suppress a range of long T1 signal. This suppression leaves short T2⁎ signal, which has been suggested to have short T1, as the primary source of the image. The experimental results confirm that after suppression of long T1 signals, the image is dominated by short T2⁎ in the range of myelin water, allowing us to directly visualize the short transverse relaxation time component in the brain. Compared to conventional myelin water imaging, this new method of direct visualization of short relaxation time component (ViSTa) provides high quality images. When applied to multiple sclerosis patients, chronic lesions show significantly reduced signal intensity in ViSTa images suggesting sensitivity to demyelination.

  18. Application of scaling theory to vibrational relaxation in linear anharmonic triatomic molecules

    NASA Astrophysics Data System (ADS)

    Clary, D. C.; DePristo, Andrew E.

    1983-09-01

    The energy-corrected-sudden (ECS) scaling theory is extended to vibrational relaxation in the collisions of anharmonic linear triatomic molecules with atoms. Application is made to the collisions of He atoms with 12C 16O2, 14C 16O2, and 12C 18O2. By combining the rate constants for the (0110 → 0000) transitions, calculated using the vibrational close-coupling rotational infinite-order-sudden (VCC-IOS) method, with the ECS scaling theory, we predict rate constants for the transitions (1000 → 0110), (0220 → 0110) and (0200 → 0110). These agree very well with the rate constants computed directly using the VCC-IOS technique. This comparison presents a particularly severe test of the accuracy of the ECS scaling theory for anharmonic polyatomics since Fermi resonance effects are large for the 1000 and 0200 levels in CO2.

  19. Strange scaling and relaxation of finite-size fluctuation in thermal equilibrium

    NASA Astrophysics Data System (ADS)

    Yamaguchi, Yoshiyuki Y.

    2016-07-01

    We numerically exhibit two strange phenomena of finite-size fluctuation in thermal equilibrium of a paradigmatic long-range interacting system having a second-order phase transition. One is a nonclassical finite-size scaling at the critical point, which differs from the prediction by statistical mechanics. With the aid of this strange scaling, the scaling theory for infinite-range models conjectures the nonclassical values of critical exponents for the correlation length. The other is relaxation of the fluctuation strength from one level to another in spite of being in thermal equilibrium. A scenario is proposed to explain these phenomena from the viewpoint of the Casimir invariants and their nonexactness in finite-size systems, where the Casimir invariants are conserved in the Vlasov dynamics describing the long-range interacting systems in the limit of large population. This scenario suggests appearance of the reported phenomena in a wide class of isolated long-range interacting systems.

  20. Strange scaling and relaxation of finite-size fluctuation in thermal equilibrium.

    PubMed

    Yamaguchi, Yoshiyuki Y

    2016-07-01

    We numerically exhibit two strange phenomena of finite-size fluctuation in thermal equilibrium of a paradigmatic long-range interacting system having a second-order phase transition. One is a nonclassical finite-size scaling at the critical point, which differs from the prediction by statistical mechanics. With the aid of this strange scaling, the scaling theory for infinite-range models conjectures the nonclassical values of critical exponents for the correlation length. The other is relaxation of the fluctuation strength from one level to another in spite of being in thermal equilibrium. A scenario is proposed to explain these phenomena from the viewpoint of the Casimir invariants and their nonexactness in finite-size systems, where the Casimir invariants are conserved in the Vlasov dynamics describing the long-range interacting systems in the limit of large population. This scenario suggests appearance of the reported phenomena in a wide class of isolated long-range interacting systems. PMID:27575102

  1. Relaxation-time limit in the multi-dimensional bipolar nonisentropic Euler-Poisson systems

    NASA Astrophysics Data System (ADS)

    Li, Yeping; Zhou, Zhiming

    2015-05-01

    In this paper, we consider the multi-dimensional bipolar nonisentropic Euler-Poisson systems, which model various physical phenomena in semiconductor devices, plasmas and channel proteins. We mainly study the relaxation-time limit of the initial value problem for the bipolar full Euler-Poisson equations with well-prepared initial data. Inspired by the Maxwell iteration, we construct the different approximation states for the case τσ = 1 and σ = 1, respectively, and show that periodic initial-value problems of the certain scaled bipolar nonisentropic Euler-Poisson systems in the case τσ = 1 and σ = 1 have unique smooth solutions in the time interval where the classical energy transport equation and the drift-diffusive equation have smooth solution. Moreover, it is also obtained that the smooth solutions converge to those of energy-transport models at the rate of τ2 and those of the drift-diffusive models at the rate of τ, respectively. The proof of these results is based on the continuation principle and the error estimates.

  2. Increasing energy relaxation time of superconducting qubits with nonmagnetic infrared filter and shield

    NASA Astrophysics Data System (ADS)

    Yuhao, Liu; Mengmeng, Li; Dong, Lan; Guangming, Xue; Xinsheng, Tan; Haifeng, Yu; Yang, Yu

    2016-05-01

    One of the primary origins of the energy relaxation in superconducting qubits is the quasiparticle loss. The quasiparticles can be excited remarkably by infrared radiation. In order to minimize the density of quasiparticle and increase the qubit relaxation time, we design and fabricate the infrared filter and shield for superconducting qubits. In comparison with previous filters and shields, a nonmagnetic dielectric is used as the infrared absorbing material, greatly suppressing the background magnetic fluctuations. The filters can be made to impedance-match with other microwave devices. Using the as-fabricated infrared filter and shield, we increased the relaxation time of a transmon qubit from 519 ns to 1125 ns. Project supported by the National Natural Science Foundation of China (Grant Nos. 91321310, 11274156, 11474152, 11474153, 61521001, and 11504165) and the State Key Program for Basic Research of China (Grant Nos. 2011CB922104 and 2011CBA00205).

  3. Nanosecond spin relaxation times in single layer graphene spin valves with hexagonal boron nitride tunnel barriers

    NASA Astrophysics Data System (ADS)

    Singh, Simranjeet; Katoch, Jyoti; Xu, Jinsong; Tan, Cheng; Zhu, Tiancong; Amamou, Walid; Hone, James; Kawakami, Roland

    2016-09-01

    We present an experimental study of spin transport in single layer graphene using atomic sheets of hexagonal boron nitride (h-BN) as a tunnel barrier for spin injection. While h-BN is expected to be favorable for spin injection, previous experimental studies have been unable to achieve spin relaxation times in the nanosecond regime, suggesting potential problems originating from the contacts. Here, we investigate spin relaxation in graphene spin valves with h-BN barriers and observe room temperature spin lifetimes in excess of a nanosecond, which provides experimental confirmation that h-BN is indeed a good barrier material for spin injection into graphene. By carrying out measurements with different thicknesses of h-BN, we show that few layer h-BN is a better choice than monolayer for achieving high non-local spin signals and longer spin relaxation times in graphene.

  4. Nonradiative Relaxation in Real-Time Electronic Dynamics OSCF2: Organolead Triiodide Perovskite.

    PubMed

    Nguyen, Triet S; Parkhill, John

    2016-09-01

    We apply our recently developed nonequilibrium real-time time-dependent density functional theory (OSCF2) to investigate the transient spectrum and relaxation dynamics of the tetragonal structure of methylammonium lead triiodide perovskite (MAPbI3). We obtain an estimate of the interband relaxation kinetics and identify multiple ultrafast cooling channels for hot electrons and hot holes that largely corroborate the dual valence-dual conduction model. The computed relaxation rates and absorption spectra are in good agreement with the existing experimental data. We present the first ab initio simulations of the perovskite transient absorption (TA) spectrum, substantiating the assignment of induced bleaches and absorptions including a Pauli-bleach signal. This paper validates both OSCF2 as a good qualitative model of electronic dynamics, and the dominant interpretation of the TA spectrum of this material. PMID:27523194

  5. Predicting permeability from the characteristic relaxation time and intrinsic formation factor of complex conductivity spectra

    NASA Astrophysics Data System (ADS)

    Revil, A.; Binley, A.; Mejus, L.; Kessouri, P.

    2015-08-01

    Low-frequency quadrature conductivity spectra of siliclastic materials exhibit typically a characteristic relaxation time, which either corresponds to the peak frequency of the phase or the quadrature conductivity or a typical corner frequency, at which the quadrature conductivity starts to decrease rapidly toward lower frequencies. This characteristic relaxation time can be combined with the (intrinsic) formation factor and a diffusion coefficient to predict the permeability to flow of porous materials at saturation. The intrinsic formation factor can either be determined at several salinities using an electrical conductivity model or at a single salinity using a relationship between the surface and quadrature conductivities. The diffusion coefficient entering into the relationship between the permeability, the characteristic relaxation time, and the formation factor takes only two distinct values for isothermal conditions. For pure silica, the diffusion coefficient of cations, like sodium or potassium, in the Stern layer is equal to the diffusion coefficient of these ions in the bulk pore water, indicating weak sorption of these couterions. For clayey materials and clean sands and sandstones whose surface have been exposed to alumina (possibly iron), the diffusion coefficient of the cations in the Stern layer appears to be 350 times smaller than the diffusion coefficient of the same cations in the pore water. These values are consistent with the values of the ionic mobilities used to determine the amplitude of the low and high-frequency quadrature conductivities and surface conductivity. The database used to test the model comprises a total of 202 samples. Our analysis reveals that permeability prediction with the proposed model is usually within an order of magnitude from the measured value above 0.1 mD. We also discuss the relationship between the different time constants that have been considered in previous works as characteristic relaxation time, including

  6. Hot-electron energy relaxation time in Ga-doped ZnO films

    SciTech Connect

    Šermukšnis, E. Liberis, J.; Ramonas, M.; Matulionis, A.; Toporkov, M.; Liu, H. Y.; Avrutin, V.; Özgür, Ü.; Morkoç, H.

    2015-02-14

    Hot-electron energy relaxation time is deduced for Ga-doped ZnO epitaxial layers from pulsed hot-electron noise measurements at room temperature. The relaxation time increases from ∼0.17 ps to ∼1.8 ps when the electron density increases from 1.4 × 10{sup 17 }cm{sup −3} to 1.3 × 10{sup 20 }cm{sup −3}. A local minimum is resolved near an electron density of 1.4 × 10{sup 19 }cm{sup −3}. The longest energy relaxation time (1.8 ps), observed at the highest electron density, is in good agreement with the published values obtained by optical time-resolved luminescence and absorption experiments. Monte Carlo simulations provide a qualitative interpretation of our observations if hot-phonon accumulation is taken into account. The local minimum of the electron energy relaxation time is explained by the ultrafast plasmon-assisted decay of hot phonons in the vicinity of the plasmon–LO-phonon resonance.

  7. Separation of Time Scales in a Quantum Newton's Cradle.

    PubMed

    van den Berg, R; Wouters, B; Eliëns, S; De Nardis, J; Konik, R M; Caux, J-S

    2016-06-01

    We provide detailed modeling of the Bragg pulse used in quantum Newton's-cradle-like settings or in Bragg spectroscopy experiments for strongly repulsive bosons in one dimension. We reconstruct the postpulse time evolution and study the time-dependent local density profile and momentum distribution by a combination of exact techniques. We further provide a variety of results for finite interaction strengths using a time-dependent Hartree-Fock analysis and bosonization-refermionization techniques. Our results display a clear separation of time scales between rapid and trap-insensitive relaxation immediately after the pulse, followed by slow in-trap periodic behavior. PMID:27314723

  8. Relationship between the crystallization rates of amorphous nifedipine, phenobarbital, and flopropione, and their molecular mobility as measured by their enthalpy relaxation and (1)H NMR relaxation times.

    PubMed

    Aso, Y; Yoshioka, S; Kojima, S

    2000-03-01

    Isothermal crystallization of amorphous nifedipine, phenobarbital, and flopropione was studied at temperatures above and below their glass transition temperatures (T(g)). A sharp decrease in the crystallization rate with decreasing temperature was observed for phenobarbital and flopropione, such that no crystallization was observed at temperatures 20-30 degrees C lower than their T(g) within ordinary experimental time periods. In contrast, the crystallization rate of nifedipine decreased moderately with decreasing temperature, and considerable crystallization was observed at 40 degrees C below its T(g) within 4 months. The molecular mobility of these amorphous drugs was assessed by enthalpy relaxation and (1)H-NMR relaxation measurements. The enthalpy relaxation time of nifedipine was smaller than that of phenobarbital or flopropinone at the same T - T(g) values, suggesting higher molecular mobility of nifedipine. The spin-lattice relaxation time in the rotating frame (T(1rho)) decreased markedly at temperature above T(g). The slope of the Arrhenius type plot of the T(1rho) for nifedipine protons changed at about 10 degrees C below the T(g), whereas the slope for phenobarbital protons became discontinuous at about 10 degrees C above the T(g). Even at temperatures below its T(g), the spin-spin relaxation process of nifedipine could be described by the sum of its Gaussian relaxation, which is characteristic of solid protons, and its Lorentzian relaxation, which is characteristic of protons with higher mobility. In contrast, no Lorentzian relaxation was observed for phenobarbital or flopropione at temperatures below their T(g). These results also suggest that nifedipine has higher molecular mobility than phenobarbital and flopropione at temperatures below T(g). The faster crystallization of nifedipine than that of phenobarbital or flopropione observed at temperatures below its T(g) may be partly ascribed to its higher molecular mobility at these temperatures.

  9. A high-precision approach to reconstruct distribution of relaxation times from electrochemical impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Zhang, Yanxiang; Chen, Yu; Li, Mei; Yan, Mufu; Ni, Meng; Xia, Changrong

    2016-03-01

    A new Tikhonov regularization approach without adjusting parameters is proposed for reconstructing distribution of relaxation time (DRT). It is capable of eliminating the pseudo peaks and capturing discontinuities in the DRT, making it feasible to resolve the number and the nature of electrochemical processes without making assumptions.

  10. Will spin-relaxation times in molecular magnets permit quantum information processing?

    NASA Astrophysics Data System (ADS)

    Ardavan, Arzhang

    2007-03-01

    Certain computational tasks can be efficiently implemented using quantum logic, in which the information-carrying elements are permitted to exist in quantum superpositions. To achieve this in practice, a physical system that is suitable for embodying quantum bits (qubits) must be identified. Some proposed scenarios employ electron spins in the solid state, for example phosphorous donors in silicon, quantum dots, heterostructures and endohedral fullerenes, motivated by the long electron-spin relaxation times exhibited by these systems. An alternative electron-spin based proposal exploits the large number of quantum states and the non-degenerate transitions available in high spin molecular magnets. Although these advantages have stimulated vigorous research in molecular magnets, the key question of whether the intrinsic spin relaxation times are long enough has hitherto remained unaddressed. Using X-band pulsed electron spin resonance, we measure the intrinsic spin-lattice (T1) and phase coherence (T2) relaxation times in molecular nanomagnets for the first time. In Cr7M heterometallic wheels, with M = Ni and Mn, phase coherence relaxation is dominated by the coupling of the electron spin to protons within the molecule. In deuterated samples T2 reaches 3 μs at low temperatures, which is several orders of magnitude longer than the duration of spin manipulations, satisfying a prerequisite for the deployment of molecular nanomagnets in quantum information applications.

  11. Reassessing the single relaxation time Lattice Boltzmann method for the simulation of Darcy’s flows

    NASA Astrophysics Data System (ADS)

    Prestininzi, Pietro; Montessori, Andrea; La Rocca, Michele; Succi, Sauro

    2016-09-01

    It is shown that the single relaxation time (SRT) version of the Lattice Boltzmann (LB) equation permits to compute the permeability of Darcy’s flows in porous media within a few percent accuracy. This stands in contrast with previous claims of inaccuracy, which we relate to the lack of recognition of the physical dependence of the permeability on the Knudsen number.

  12. Scaling and alpha-helix regulation of protein relaxation in a lipid bilayer

    NASA Astrophysics Data System (ADS)

    Qiu, Liming; Buie, Creighton; Cheng, Kwan Hon; Vaughn, Mark W.

    2014-12-01

    Protein conformation and orientation in the lipid membrane plays a key role in many cellular processes. Here we use molecular dynamics simulation to investigate the relaxation and C-terminus diffusion of a model helical peptide: beta-amyloid (Aβ) in a lipid membrane. We observed that after the helical peptide was initially half-embedded in the extracelluar leaflet of phosphatidylcholine (PC) or PC/cholesterol (PC/CHOL) membrane, the C-terminus diffused across the membrane and anchored to PC headgroups of the cytofacial lipid leaflet. In some cases, the membrane insertion domain of the Aβ was observed to partially unfold. Applying a sigmoidal fit to the process, we found that the characteristic velocity of the C-terminus, as it moved to its anchor site, scaled with θu-4/3, where θu is the fraction of the original helix that was lost during a helix to coil transition. Comparing this scaling with that of bead-spring models of polymer relaxation suggests that the C-terminus velocity is highly regulated by the peptide helical content, but that it is independent of the amino acid type. The Aβ was stabilized by the attachment of the positive Lys28 side chain to the negative phosphate of PC or 3β oxygen of CHOL in the extracellular lipid leaflet and of the C-terminus to its anchor site in the cytofacial lipid leaflet.

  13. Boiling temperature as a scaling parameter for the microscopic relaxation dynamics in molecular liquids.

    PubMed

    Mamontov, Eugene

    2013-08-15

    At sufficiently high temperatures, the center-of-mass microscopic diffusion dynamics of liquids is characterized by a single component, often with weak temperature dependence. In this regime, the effective cage made by the neighbor particles cannot be sustained and readily breaks down, enabling long-range diffusion. As the temperature is decreased, the cage relaxation becomes impeded, leading to a higher viscosity with more pronounced temperature dependence. On the microscopic scale, the sustained caging effect leads to a separation between a faster in-cage relaxation component and a slower cage-breaking relaxation component. The evidence for the separate dynamic components, as opposed to a single stretched component, is provided by quasielastic neutron scattering experiments. We use a simple method to evaluate the extent of the dynamic components separation as a function of temperature in a group of related aromatic molecular liquids. We find that, regardless of the glass-forming capabilities or lack thereof, progressively more pronounced separation between the in-cage and cage-breaking dynamic components develops on cooling down as the ratio of T(b)/T, where T(b) is the boiling temperature, increases. This reflects the microscopic mechanism behind the empirical rule for the glass forming capability based on the ratio of boiling and melting temperatures, T(b)/T(m). When a liquid's T(b)/T(m) happens to be high, the liquid can readily be supercooled below its T(m) because the liquid's microscopic relaxation dynamics is already impeded at T(m), as evidenced by a sustained caging effect manifested through the separation of the in-cage and cage-breaking dynamic components. Our findings suggest certain universality in the temperature dependence of the microscopic diffusion dynamics in molecular liquids, regardless of their glass-forming capabilities. Unless the insufficiently low (with respect to T(b)) melting temperature, T(m), intervenes and makes crystallization

  14. Very short NMR relaxation times of anions in ionic liquids: New pulse sequence to eliminate the acoustic ringing

    NASA Astrophysics Data System (ADS)

    Klimavicius, Vytautas; Gdaniec, Zofia; Balevicius, Vytautas

    2014-11-01

    NMR relaxation processes of anions were studied in two neat imidazolium-based room temperature ionic liquids (RTILs) 1-decyl-3-methyl-imidazolium bromide- and chloride. The spin-lattice and spin-spin relaxations of 81Br and 35Cl nuclei were found to be extremely fast due to very strong quadrupolar interactions. The determined relaxation rates are comparable with those observed in the solids or in some critical organic solute/water/salt systems. In order to eliminate the acoustic ringing of the probe-head during relaxation times measurements the novel pulse sequence has been devised. It is based on the conventional inversion recovery pulse sequence, however, instead of the last 90° pulse the subsequence of three 90° pulses applied along axes to fulfill the phase cycling condition is used. Using this pulse sequence it was possible to measure T1 for both studied nuclei. The viscosity measurements have been carried out and the rotational correlation times were calculated. The effective 35Cl quadrupolar coupling constant was found to be almost one order lower than that for 81Br, i.e. 1.8 MHz and 16.0 MHz, respectively. Taking into account the facts that the ratio of (Q(35Cl)/Q(81Br))2 ≈ 0.1 and EFG tensors on the anions are quite similar, analogous structural organizations are expected for both RTILs. The observed T1/T2 (1.27-1.44) ratios were found to be not sufficiently high to confirm the presence of long-living (on the time scale of ⩾10-8 s) mesoscopic structures or heterogeneities in the studied neat ionic liquids.

  15. Scaling parallels in the non-Debye dielectric relaxation of ionic glasses and dipolar supercooled liquids

    SciTech Connect

    Sidebottom, D.L.; Green, P.F.; Brow, R.K.

    1997-07-01

    We compare the dielectric response of ionic glasses and dipolar liquids near the glass transition. Our work is divided into two parts. In the first section we examine ionic glasses and the two prominent approaches to analyzing the dielectric response. The conductivity of ion-conducting glasses displays a power law dispersion {sigma}({omega}){proportional_to}{omega}{sup n}, where n{approx}0.67, but frequently the dielectric response is analyzed using the electrical modulus M{sup {asterisk}}({omega})=1/{var_epsilon}{sup {asterisk}}({omega}), where {var_epsilon}{sup {asterisk}}({omega})={var_epsilon}({omega}){minus}i{sigma}({omega})/{omega} is the complex permittivity. We reexamine two specific examples where the shape of M{sup {asterisk}}({omega}) changes in response to changes in (a) temperature and (b) ion concentration, to suggest fundamental changes in ion dynamics are occurring. We show, however, that these changes in the shape of M{sup {asterisk}}({omega}) occur in the absence of changes in the scaling properties of {sigma}({omega}), for which n remains constant. In the second part, we examine the dielectric relaxation found in dipolar liquids, for which {var_epsilon}{sup {asterisk}}({omega}) likewise exhibits changes in shape on approach to the glass transition. Guided by similarities of M{sup {asterisk}}({omega}) in ionic glasses and {var_epsilon}{sup {asterisk}}({omega}) in dipolar liquids, we demonstrate that a recent scaling approach proposed by Dixon and co-workers for {var_epsilon}{sup {asterisk}}({omega}) of dipolar relaxation also appears valid for M{sup {asterisk}}({omega}) in the ionic case. While this suggests that the Dixon scaling approach is more universal than previously recognized, we demonstrate how the dielectric response can be scaled in a linear manner using an alternative data representation. {copyright} {ital 1997} {ital The American Physical Society}

  16. Prolongation of Relaxation Time in Extraocular Muscles With Brain Derived Neurotrophic Factor in Adult Rabbit

    PubMed Central

    Nelson, Krysta R.; Stevens, Shanlee M.; McLoon, Linda K.

    2016-01-01

    Purpose We tested the hypothesis that short-term treatment with brain derived neurotrophic factor (BDNF) would alter the contractile characteristics of rabbit extraocular muscle (EOM). Methods One week after injections of BDNF in adult rabbit superior rectus muscles, twitch properties were determined in treated and control muscles in vitro. Muscles were also examined for changes in mean cross-sectional areas, neuromuscular junction size, and percent of myofibers expressing specific myosin heavy chain isoforms, and sarcoendoplasmic reticulum calcium ATPases (SERCA) 1 and 2. Results Brain derived neurotrophic factor–treated muscles had prolonged relaxation times compared with control muscles. Time to 50% relaxation, time to 100% relaxation, and maximum rate of relaxation were increased by 24%, 27%, and 25%, respectively. No significant differences were seen in time to peak force, twitch force, or maximum rate of contraction. Brain derived neurotrophic factor treatment significantly increased mean cross-sectional areas of slow twitch and tonic myofibers, with increased areas ranging from 54% to 146%. Brain derived neurotrophic factor also resulted in an increased percentage of slow twitch myofibers in the orbital layers, ranging from 54% to 77%, and slow-tonic myofibers, ranging from 44% to 62%. No significant changes were seen SERCA1 or 2 expression or in neuromuscular junction size. Conclusions Short-term treatment with BDNF significantly prolonged the duration and rate of relaxation time and increased expression of both slow-twitch and slow-tonic myosin-expressing myofibers without changes in neuromuscular junctions or SERCA expression. The changes induced by BDNF treatment might have potential therapeutic value in dampening/reducing uncontrolled eye oscillations in nystagmus. PMID:27802489

  17. Relaxation of terrace-width distributions: Physical information from Fokker Planck time

    NASA Astrophysics Data System (ADS)

    Hamouda, Ajmi BH.; Pimpinelli, Alberto; Einstein, T. L.

    2008-12-01

    Recently some of us have constructed a Fokker-Planck formalism to describe the equilibration of the terrace-width distribution of a vicinal surface from an arbitrary initial configuration. However, the meaning of the associated relaxation time, related to the strength of the random noise in the underlying Langevin equation, was rather unclear. Here we present a set of careful kinetic Monte Carlo simulations that demonstrate convincingly that the time constant shows activated behavior with a barrier that has a physically plausible dependence on the energies of the governing microscopic model. Remarkably, the rate-limiting step for relaxation in the far-from-equilibrium regime is the generation of kink-antikink pairs, involving the breaking of three lateral bonds on a cubic {0 0 1} surface, in contrast to the processes breaking two bonds that dominate equilibrium fluctuations. After an initial regime, the Fokker-Planck time at least semiquantitatively tracks the actual physical time.

  18. Relaxation times of the two-phonon processes with spin-flip and spin-conserving in quantum dots

    SciTech Connect

    Wang, Zi-Wu; Liu, Lei; Li, Shu-Shen

    2014-04-07

    We perform a theoretical investigation on the two-phonon processes of the spin-flip and spin-conserving relaxation in quantum dots in the frame of the Huang-Rhys' lattice relaxation model. We find that the relaxation time of the spin-flip is two orders of magnitude longer than that of the spin-conserving, which is in agreement with previous experimental measurements. Moreover, the opposite variational trends of the relaxation time as a function of the energy separation for two-phonon processes are obtained in different temperature regime. The relaxation times display the oscillatory behaviors at the demarcation point with increasing magnetic field, where the energy separation matches the optical phonon energy and results in the optical phonon resonance. These results are useful in understanding the intraband levels' relaxation in quantum dots and could be helpful in designing photoelectric and spin-memory devices.

  19. Probing of structural relaxation times in the glassy state of sucrose and trehalose based on dynamical properties of two secondary relaxation processes

    NASA Astrophysics Data System (ADS)

    Kaminski, K.; Adrjanowicz, K.; Kaminska, E.; Paluch, M.

    2011-06-01

    Time-dependent isothermal dielectric measurements were carried out deeply in the glassy state on two very important saccharides: sucrose and trehalose. In both compounds two prominent secondary relaxation processes were identified. The faster one is an inherent feature of the whole family of carbohydrates. The slower one can also be detected in oligo- and polysaccharides. It was shown earlier that the β process is the Johari-Goldstein (JG) relaxation coupled to motions of the glycosidic linkage, while the γ relaxation originates from motions of the exocyclic hydroxymethyl unit. Recently, it was shown that the JG relaxation process can be used to determine structural relaxation times in the glassy state [R. Casalini and C. M. Roland, Phys. Rev. Lett.PRLTAO0031-900710.1103/PhysRevLett.102.035701 102, 035701 (2009)]. In this paper we present the results of an analysis of the data obtained during aging using two independent approaches. The first was proposed by Casalini and Roland, and the second one is based on the variation of the dielectric strength of the secondary relaxation process during aging [J. K. Vij and G. Power, J. Non-Cryst. SolidsJNCSBJ0022-309310.1016/j.jnoncrysol.2010.07.067 357, 783 (2011)]. Surprisingly, we found that the estimated structural relaxation times in the glassy state of both saccharides are almost the same, independent of the type of secondary mode. This finding calls into question the common view that secondary modes of intramolecular origin do not provide information about the dynamics of the glassy state.

  20. Sensitivity of proton NMR relaxation times in a HTPB based polyurethane elastomer to thermo-oxidative aging.

    SciTech Connect

    Assink, Roger Alan; Mowery, Daniel Michael; Celina, Mathias Christopher

    2004-09-01

    Solid-state {sup 1}H NMR relaxometry studies were conducted on a hydroxy-terminated polybutadiene (HTPB) based polyurethane elastomer thermo-oxidatively aged at 80 C. The {sup 1}H T{sub 1}, T{sub 2}, and T{sub 1{rho}} relaxation times of samples thermally aged for various periods of time were determined as a function of NMR measurement temperature. The response of each measurement was calculated from a best-fit linear function of the relaxation time vs. aging time. It was found that the T{sub 2,H} and T{sub 1{rho},H} relaxation times exhibited the largest response to thermal degradation, whereas T{sub 1,H} showed minimal change. All of the NMR relaxation measurements on solid samples showed significantly less sensitivity to thermal aging than the T{sub 2,H} relaxation times of solvent-swollen samples.

  1. Using Dielectric Relaxation Spectroscopy to Characterize the Glass Transition Time of Polydextrose.

    PubMed

    Buehler, Martin G; Kindle, Michael L; Carter, Brady P

    2015-06-01

    Dielectric relaxation spectroscopy was used to characterize the glass transition time, tg , of polydextrose, where the glass transition temperature, Tg , and water activity, aw (relative humidity), were held constant during polydextrose relaxation. The tg was determined from a shift in the peak frequency of the imaginary capacitance spectrum with time. It was found that when the peak frequency reaches 30 mHz, polydextrose undergoes glass transition. Glass transition time, tg , is the time for polydextrose to undergo glass transition at a specific Tg and aw . Results lead to a modified state diagram, where Tg is depressed with increasing aw . This curve forms a boundary: (a) below the boundary, polydextrose does not undergo glass transition and (b) above the boundary, polydextrose rapidly undergoes glass transition. As the boundary curve is specified by a tg value, it can assist in the selection of storage conditions. An important point on the boundary curve is at aw = 0, where Tg0 = 115 °C. The methodology can also be used to calculate the stress-relaxation viscosity of polydextrose as a function of Tg and aw , which is important when characterizing the flow properties of polydextrose initially in powder form.

  2. Effect of gadolinium-DTPA on the magnetic relaxation times of normal and infarcted myocardium. [Dogs

    SciTech Connect

    Wesbey, G.E.; Higgins, C.B.; McNamara, M.T.; Engelstad, B.L.; Lipton, M.J.; Sievers, R.; Ehman, R.L.; Lovin, J.; Brasch, R.C.

    1984-10-01

    Acute myocardial infarctions were produced in 11 dogs by ligation of the left anterior descending coronary artery. Twenty-four hours after ligation Gd-DTPA was injected intravenously, followed by cardiectomy either 90 seconds (3 dogs) or 5 minutes (5 dogs) later. The remaining 3 dogs had cardiectomy without injection of Gd-DTPA at 24 hours after coronary occlusion. The 3 dogs that did not receive Gd-DTPA had longer T1 and T2 relaxation times in infarcted myocardium than in normal myocardium. The T1 and T2 relaxation times of normal myocardium at 90 seconds postinjection of Gd-DTPA were significantly shorter than those of the normal myocardium of animals that did not receive Gd-DTPA. At five minutes postinjection, significantly greater T1 shortening was exhibited in the infarcted myocardium compared with adjacent normal myocardium in the dogs injected with Gd-DTPA. Thus, Gd-DTPA has differential and time-varying effects on relaxation times of normal and infarcted myocardium.

  3. Estimation of stress relaxation time for normal and abnormal breast phantoms using optical technique

    NASA Astrophysics Data System (ADS)

    Udayakumar, K.; Sujatha, N.

    2015-03-01

    Many of the early occurring micro-anomalies in breast may transform into a deadliest cancer tumor in future. Probability of curing early occurring abnormalities in breast is more if rightly identified. Even in mammogram, considered as a golden standard technique for breast imaging, it is hard to pick up early occurring changes in the breast tissue due to the difference in mechanical behavior of the normal and abnormal tissue when subjected to compression prior to x-ray or laser exposure. In this paper, an attempt has been made to estimate the stress relaxation time of normal and abnormal breast mimicking phantom using laser speckle image correlation. Phantoms mimicking normal breast is prepared and subjected to precise mechanical compression. The phantom is illuminated by a Helium Neon laser and by using a CCD camera, a sequence of strained phantom speckle images are captured and correlated by the image mean intensity value at specific time intervals. From the relation between mean intensity versus time, tissue stress relaxation time is quantified. Experiments were repeated for phantoms with increased stiffness mimicking abnormal tissue for similar ranges of applied loading. Results shows that phantom with more stiffness representing abnormal tissue shows uniform relaxation for varying load of the selected range, whereas phantom with less stiffness representing normal tissue shows irregular behavior for varying loadings in the given range.

  4. Systolic and diastolic time intervals in pulsus alternans - Significance of alternating isovolumic relaxation

    NASA Technical Reports Server (NTRS)

    Spodick, D. H.; Quarry, V. M.; Khan, A. H.

    1974-01-01

    Systolic and diastolic time intervals in 14 cardiac patients with pulsus alternans revealed significant alternation of preinjection period (PEP), isovolumic contraction time (IVCT), left ventricular ejection time (LVET), ejection time index (ETI), PEP/LVET, and carotid dD/dt with better functional values in the strong beats. Cycle length, duration of electromechanical systole (EMS) and total diastole, i.e., isovolumic relaxation period (IRP) and diastolic filling period (DFP) occurred in 7 out of 8 patients. These diastolic intervals alternated reciprocally such that the IRP of the strong beats encroached upon the DFP of the next (weak) beats.

  5. Bulk viscosity and relaxation time of causal dissipative relativistic fluid dynamics

    NASA Astrophysics Data System (ADS)

    Huang, Xu-Guang; Kodama, Takeshi; Koide, Tomoi; Rischke, Dirk H.

    2011-02-01

    The microscopic formulas of the bulk viscosity ζ and the corresponding relaxation time τΠ in causal dissipative relativistic fluid dynamics are derived by using the projection operator method. In applying these formulas to the pionic fluid, we find that the renormalizable energy-momentum tensor should be employed to obtain consistent results. In the leading-order approximation in the chiral perturbation theory, the relaxation time is enhanced near the QCD phase transition, and τΠ and ζ are related as τΠ=ζ/[β{(1/3-cs2)(ɛ+P)-2(ɛ-3P)/9}], where ɛ, P, and cs are the energy density, pressure, and velocity of sound, respectively. The predicted ζ and τΠ should satisfy the so-called causality condition. We compare our result with the results of the kinetic calculation by Israel and Stewart and the string theory, and confirm that all three approaches are consistent with the causality condition.

  6. Lattice Boltzmann equation with multiple effective relaxation times for gaseous microscale flow.

    PubMed

    Guo, Zhaoli; Zheng, Chuguang; Shi, Baochang

    2008-03-01

    The standard lattice Boltzmann equation (LBE) is inadequate for simulating gas flows with a large Knudsen number. In this paper we propose a generalized lattice Boltzmann equation with effective relaxation times based on a recently developed generalized Navier-Stokes constitution [Guo, Europhys Lett. 80, 24001 (2007)] for nonequilibrium flows. A kinetic boundary condition corresponding to a generalized second-order slip scheme is also designed for the model. The LBE model and the boundary condition are analyzed for a unidirectional flow, and it is found that in order to obtain the generalized Navier-Stokes equations, the relaxation times must be properly chosen and are related to the boundary condition. Numerical results show that the proposed method is able to capture the Knudsen layer phenomenon and can yield improved predictions in comparison with the standard lattice Boltzmann equation.

  7. Study of anisotropy in nuclear magnetic resonance relaxation times of water protons in skeletal muscle.

    PubMed Central

    Kasturi, S R; Chang, D C; Hazlewood, C F

    1980-01-01

    The anisotropy of the spin-lattice relaxation time (T1) and the spin-spin relaxation times (T2) of water protons in skeletal muscle tissue have been studied by the spin-echo technique. Both T1 and T2 have been measured for the water protons of the tibialis anterior muscle of mature male rats for theta = 0, 55, and 90 degrees, where theta is the orientation of the muscle fiber with respect to the static field. The anisotropy in T1 and T2 has been measured at temperatures of 28, -5 and -10 degrees C. No significant anisotropy was observed in the T1 of the tissue water, while an average anisotropy of approximately 5% was observed in T2 at room temperature. The average anisotropy of T2 at -5 and -10 degrees C was found to be approximately 2 and 1.3%, respectively. PMID:6266530

  8. The generalized Phillips-Twomey method for NMR relaxation time inversion

    NASA Astrophysics Data System (ADS)

    Gao, Yang; Xiao, Lizhi; Zhang, Yi; Xie, Qingming

    2016-10-01

    The inversion of NMR relaxation time involves the Fredholm integral equation of the first kind. Due to its ill-posedness, numerical solutions to this type of equations are often found much less accurate and bear little resemblance to the true solution. There has been a strong interest in finding a well-posed method for this ill-posed problem since 1950s. In this paper, we prove the existence, the uniqueness, the stability and the convergence of the generalized Phillips-Twomey regularization method for solving this type of equations. Numerical simulations and core analyses arising from NMR transverse relaxation time inversion are conducted to show the effectiveness of the generalized Phillips-Twomey method. Both the simulation results and the core analyses agree well with the model and the realities.

  9. Shear Viscosity Coefficient and Relaxation Time of Causal Dissipative Hydrodynamics in QCD

    SciTech Connect

    Koide, T.; Nakano, E.; Kodama, T.

    2009-07-31

    The shear viscosity coefficient and the corresponding relaxation time for causal dissipative hydrodynamics are calculated based on the microscopic formula proposed in T. Koide and T. Kodama [Phys. Rev. E 78, 051107 (2008)]. Here, the exact formula is transformed into a more compact form and applied to evaluate these transport coefficients in the chiral perturbation theory and perturbative QCD. It is shown that in the leading order calculation, the causal shear viscosity coefficient eta reduces to that of the ordinary Green-Kubo-Nakano formula, and the relaxation time tau{sub p}i is related to eta and pressure P by a simple relationship, tau{sub p}i=eta/P.

  10. Advances in time-scale algorithms

    NASA Technical Reports Server (NTRS)

    Stein, S. R.

    1993-01-01

    The term clock is usually used to refer to a device that counts a nearly periodic signal. A group of clocks, called an ensemble, is often used for time keeping in mission critical applications that cannot tolerate loss of time due to the failure of a single clock. The time generated by the ensemble of clocks is called a time scale. The question arises how to combine the times of the individual clocks to form the time scale. One might naively be tempted to suggest the expedient of averaging the times of the individual clocks, but a simple thought experiment demonstrates the inadequacy of this approach. Suppose a time scale is composed of two noiseless clocks having equal and opposite frequencies. The mean time scale has zero frequency. However if either clock fails, the time-scale frequency immediately changes to the frequency of the remaining clock. This performance is generally unacceptable and simple mean time scales are not used. First, previous time-scale developments are reviewed and then some new methods that result in enhanced performance are presented. The historical perspective is based upon several time scales: the AT1 and TA time scales of the National Institute of Standards and Technology (NIST), the A.1(MEAN) time scale of the US Naval observatory (USNO), the TAI time scale of the Bureau International des Poids et Measures (BIPM), and the KAS-1 time scale of the Naval Research laboratory (NRL). The new method was incorporated in the KAS-2 time scale recently developed by Timing Solutions Corporation. The goal is to present time-scale concepts in a nonmathematical form with as few equations as possible. Many other papers and texts discuss the details of the optimal estimation techniques that may be used to implement these concepts.

  11. Deducting the temperature dependence of the structural relaxation time in equilibrium far below the nominal Tg by aging the decoupled conductivity relaxation to equilibrium

    NASA Astrophysics Data System (ADS)

    Wojnarowska, Z.; Ngai, K. L.; Paluch, M.

    2014-05-01

    Using broadband dielectric spectroscopy we investigate the changes in the conductivity relaxation times τσ observed during the physical aging of the protic ionic conductor carvedilol dihydrogen phosphate (CP). Due to the large decoupling of ion diffusion from host molecule reorientation, the ion conductivity relaxation time τσ(Tage,tage) can be directly measured at temperatures Tage below Tg for exceedingly long aging times tage till τσ(Tage,tage) has reached the equilibrium value τ _σ ^{eq} ( {T_{age} } ). The dependence of τσ(Tage,tage) on tage is well described by the stretched exponential function, τ _σ ( {T_{age},t_{age} } ) = Aexp[ { - ( {{t_{age} }/{τ _{age ( {T_{age} } )}}} )^β } ] + τ _σ ^{eq} ( {T_{age} } ), where β is a constant and τage(Tage) can be taken as the structural α-relaxation time of the equilibrium liquid at T = Tage. The value of τ _σ ^{eq} ( {T_{age} } ) obtained after 63 days long annealing of CP, deviates from the Vogel-Fulcher-Tammann-Hesse (VFTHσ) dependence of τσ(T) determined from data taken above Tg and extrapolated down to Tage. Concurrently, τage(Tage) also deviates from the Vogel-Fulcher-Tammann-Hesse (VFTHα) dependence. The results help to answer the longstanding question of whether the VFTH dependence of τσ(T) as well as the structural α-relaxation time τα(T) holds or not in the equilibrium liquid state far below Tg.

  12. Deducting the temperature dependence of the structural relaxation time in equilibrium far below the nominal Tg by aging the decoupled conductivity relaxation to equilibrium.

    PubMed

    Wojnarowska, Z; Ngai, K L; Paluch, M

    2014-05-01

    Using broadband dielectric spectroscopy we investigate the changes in the conductivity relaxation times τσ observed during the physical aging of the protic ionic conductor carvedilol dihydrogen phosphate (CP). Due to the large decoupling of ion diffusion from host molecule reorientation, the ion conductivity relaxation time τσ(Tage,tage) can be directly measured at temperatures Tage below Tg for exceedingly long aging times tage till τσ(Tage,tage) has reached the equilibrium value τσ(eq)(Tage). The dependence of τσ(Tage,tage) on tage is well described by the stretched exponential function, τσ(Tage, tage) = Aexp[-((tage)/(τage(Tage)))(β)] + τσ(eq)(Tage), where β is a constant and τage(Tage) can be taken as the structural α-relaxation time of the equilibrium liquid at T = Tage. The value of τσ(eq)(Tage) obtained after 63 days long annealing of CP, deviates from the Vogel-Fulcher-Tammann-Hesse (VFTHσ) dependence of τσ(T) determined from data taken above Tg and extrapolated down to Tage. Concurrently, τage(Tage) also deviates from the Vogel-Fulcher-Tammann-Hesse (VFTHα) dependence. The results help to answer the longstanding question of whether the VFTH dependence of τσ(T) as well as the structural α-relaxation time τα(T) holds or not in the equilibrium liquid state far below Tg.

  13. T2 Relaxation Time Quantitation Differs Between Pulse Sequences in Articular Cartilage

    PubMed Central

    Matzat, Stephen J.; McWalter, Emily J.; Kogan, Feliks; Chen, Weitian; Gold, Garry E.

    2015-01-01

    Background To compare T2 relaxation time measurements between MR pulse sequences at 3 Tesla in agar phantoms and in vivo patellar, femoral, and tibial articular cartilage. Methods T2 relaxation times were quantified in phantoms and knee articular cartilage of eight healthy individuals using a single echo spin echo (SE) as a reference standard and five other pulse sequences: multi-echo SE (MESE), fast SE (2D-FSE), magnetization-prepared spoiled gradient echo (3D-MAPSS), three-dimensional (3D) 3D-FSE with variable refocusing flip angle schedules (3D vfl-FSE), and quantitative double echo steady state (qDESS). Cartilage was manually segmented and average regional T2 relaxation times were obtained for each sequence. A regression analysis was carried out between each sequence and the reference standard, and root-mean-square error (RMSE) was calculated. Results Phantom measurements from all sequences demonstrated strong fits (R2>0.8; P<0.05). For in vivo cartilage measurements, R2 values, slope, and RMSE were: MESE: 0.25/0.42/5.0 ms, 2D-FSE: 0.64/1.31/9.3 ms, 3D-MAPSS: 0.51/0.66/3.8 ms, 3D vfl-FSE: 0.30/ 0.414.2 ms, qDESS: 0.60/0.90/4.6 ms. Conclusion 2D-FSE, qDESS, and 3D-MAPSS demonstrated the best fits with SE measurements as well as the greatest dynamic ranges. The 3D-MAPSS, 3D vfl-FSE, and qDESS demonstrated the closest average measurements to SE. Discrepancies in T2 relaxation time quantitation between sequences suggest that care should be taken when comparing results between studies. PMID:25244647

  14. In-vivo T2-relaxation times of asymptomatic cervical intervertebral discs.

    PubMed

    Driscoll, Sean J; Zhong, Weiye; Torriani, Martin; Mao, Haiqing; Wood, Kirkham B; Cha, Thomas D; Li, Guoan

    2016-03-01

    Limited research exists on T2-mapping techniques for cervical intervertebral discs and its potential clinical utility. The objective of this research was to investigate the in-vivo T2-relaxation times of cervical discs, including C2-C3 through C7-T1. Ten asymptomatic subjects were imaged using a 3.0 T MR scanner and a sagittal multi-slice multi-echo sequence. Using the mid-sagittal image, intervertebral discs were divided into five regions-of-interest (ROIs), centered along the mid-line of the disc. Average T2 relaxation time values were calculated for each ROI using a mono-exponential fit. Differences in T2 values between disc levels and across ROIs of the same disc were examined. For a given ROI, the results showed a trend of increasing relaxation times moving down the spinal column, particularly in the middle regions (ROIs 2, 3 and 4). The C6-C7 and C7-T1 discs had significantly greater T2 values compared to superior discs (discs between C2 and C6). The results also showed spatial homogeneity of T2 values in the C3-C4, C4-C5, and C5-C6 discs, while C2-C3, C6-C7, and C7-T1 showed significant differences between ROIs. The findings indicate there may be inherent differences in T2-relaxation time properties between different cervical discs. Clinical evaluations utilizing T2-mapping techniques in the cervical spine may need to be level-dependent.

  15. Pseudopotential multi-relaxation-time lattice Boltzmann model for cavitation bubble collapse with high density ratio

    NASA Astrophysics Data System (ADS)

    Shan, Ming-Lei; Zhu, Chang-Ping; Yao, Cheng; Yin, Cheng; Jiang, Xiao-Yan

    2016-10-01

    The dynamics of the cavitation bubble collapse is a fundamental issue for the bubble collapse application and prevention. In the present work, the modified forcing scheme for the pseudopotential multi-relaxation-time lattice Boltzmann model developed by Li Q et al. [Li Q, Luo K H and Li X J 2013 Phys. Rev. E 87 053301] is adopted to develop a cavitation bubble collapse model. In the respects of coexistence curves and Laplace law verification, the improved pseudopotential multi-relaxation-time lattice Boltzmann model is investigated. It is found that the thermodynamic consistency and surface tension are independent of kinematic viscosity. By homogeneous and heterogeneous cavitation simulation, the ability of the present model to describe the cavitation bubble development as well as the cavitation inception is verified. The bubble collapse between two parallel walls is simulated. The dynamic process of a collapsing bubble is consistent with the results from experiments and simulations by other numerical methods. It is demonstrated that the present pseudopotential multi-relaxation-time lattice Boltzmann model is applicable and efficient, and the lattice Boltzmann method is an alternative tool for collapsing bubble modeling. Project supported by the National Natural Science Foundation of China (Grant Nos. 11274092 and 1140040119) and the Natural Science Foundation of Jiangsu Province, China (Grant No. SBK2014043338).

  16. Viscosity, relaxation time, and dynamics within a model asphalt of larger molecules

    NASA Astrophysics Data System (ADS)

    Li, Derek D.; Greenfield, Michael L.

    2014-01-01

    The dynamics properties of a new "next generation" model asphalt system that represents SHRP AAA-1 asphalt using larger molecules than past models is studied using molecular simulation. The system contains 72 molecules distributed over 12 molecule types that range from nonpolar branched alkanes to polar resins and asphaltenes. Molecular weights range from 290 to 890 g/mol. All-atom molecular dynamics simulations conducted at six temperatures from 298.15 to 533.15 K provide a wealth of correlation data. The modified Kohlrausch-Williams-Watts equation was regressed to reorientation time correlation functions and extrapolated to calculate average rotational relaxation times for individual molecules. The rotational relaxation rate of molecules decreased significantly with increasing size and decreasing temperature. Translational self-diffusion coefficients followed an Arrhenius dependence. Similar activation energies of ˜42 kJ/mol were found for all 12 molecules in the model system, while diffusion prefactors spanned an order of magnitude. Viscosities calculated directly at 533.15 K and estimated at lower temperatures using the Debye-Stokes-Einstein relationship were consistent with experimental data for asphalts. The product of diffusion coefficient and rotational relaxation time showed only small changes with temperature above 358.15 K, indicating rotation and translation that couple self-consistently with viscosity. At lower temperatures, rotation slowed more than diffusion.

  17. Viscosity, relaxation time, and dynamics within a model asphalt of larger molecules

    SciTech Connect

    Li, Derek D.; Greenfield, Michael L.

    2014-01-21

    The dynamics properties of a new “next generation” model asphalt system that represents SHRP AAA-1 asphalt using larger molecules than past models is studied using molecular simulation. The system contains 72 molecules distributed over 12 molecule types that range from nonpolar branched alkanes to polar resins and asphaltenes. Molecular weights range from 290 to 890 g/mol. All-atom molecular dynamics simulations conducted at six temperatures from 298.15 to 533.15 K provide a wealth of correlation data. The modified Kohlrausch-Williams-Watts equation was regressed to reorientation time correlation functions and extrapolated to calculate average rotational relaxation times for individual molecules. The rotational relaxation rate of molecules decreased significantly with increasing size and decreasing temperature. Translational self-diffusion coefficients followed an Arrhenius dependence. Similar activation energies of ∼42 kJ/mol were found for all 12 molecules in the model system, while diffusion prefactors spanned an order of magnitude. Viscosities calculated directly at 533.15 K and estimated at lower temperatures using the Debye-Stokes-Einstein relationship were consistent with experimental data for asphalts. The product of diffusion coefficient and rotational relaxation time showed only small changes with temperature above 358.15 K, indicating rotation and translation that couple self-consistently with viscosity. At lower temperatures, rotation slowed more than diffusion.

  18. Excited state dynamics in SO2. I. Bound state relaxation studied by time-resolved photoelectron-photoion coincidence spectroscopy.

    PubMed

    Wilkinson, Iain; Boguslavskiy, Andrey E; Mikosch, Jochen; Bertrand, Julien B; Wörner, Hans Jakob; Villeneuve, David M; Spanner, Michael; Patchkovskii, Serguei; Stolow, Albert

    2014-05-28

    The excited state dynamics of isolated sulfur dioxide molecules have been investigated using the time-resolved photoelectron spectroscopy and time-resolved photoelectron-photoion coincidence techniques. Excited state wavepackets were prepared in the spectroscopically complex, electronically mixed (B̃)(1)B1/(Ã)(1)A2, Clements manifold following broadband excitation at a range of photon energies between 4.03 eV and 4.28 eV (308 nm and 290 nm, respectively). The resulting wavepacket dynamics were monitored using a multiphoton ionisation probe. The extensive literature associated with the Clements bands has been summarised and a detailed time domain description of the ultrafast relaxation pathways occurring from the optically bright (B̃)(1)B1 diabatic state is presented. Signatures of the oscillatory motion on the (B̃)(1)B1/(Ã)(1)A2 lower adiabatic surface responsible for the Clements band structure were observed. The recorded spectra also indicate that a component of the excited state wavepacket undergoes intersystem crossing from the Clements manifold to the underlying triplet states on a sub-picosecond time scale. Photoelectron signal growth time constants have been predominantly associated with intersystem crossing to the (c̃)(3)B2 state and were measured to vary between 750 and 150 fs over the implemented pump photon energy range. Additionally, pump beam intensity studies were performed. These experiments highlighted parallel relaxation processes that occurred at the one- and two-pump-photon levels of excitation on similar time scales, obscuring the Clements band dynamics when high pump beam intensities were implemented. Hence, the Clements band dynamics may be difficult to disentangle from higher order processes when ultrashort laser pulses and less-differential probe techniques are implemented.

  19. Relaxed clocks and inferences of heterogeneous patterns of nucleotide substitution and divergence time estimates across whales and dolphins (Mammalia: Cetacea).

    PubMed

    Dornburg, Alex; Brandley, Matthew C; McGowen, Michael R; Near, Thomas J

    2012-02-01

    Various nucleotide substitution models have been developed to accommodate among lineage rate heterogeneity, thereby relaxing the assumptions of the strict molecular clock. Recently developed "uncorrelated relaxed clock" and "random local clock" (RLC) models allow decoupling of nucleotide substitution rates between descendant lineages and are thus predicted to perform better in the presence of lineage-specific rate heterogeneity. However, it is uncertain how these models perform in the presence of punctuated shifts in substitution rate, especially between closely related clades. Using cetaceans (whales and dolphins) as a case study, we test the performance of these two substitution models in estimating both molecular rates and divergence times in the presence of substantial lineage-specific rate heterogeneity. Our RLC analyses of whole mitochondrial genome alignments find evidence for up to ten clade-specific nucleotide substitution rate shifts in cetaceans. We provide evidence that in the uncorrelated relaxed clock framework, a punctuated shift in the rate of molecular evolution within a subclade results in posterior rate estimates that are either misled or intermediate between the disparate rate classes present in baleen and toothed whales. Using simulations, we demonstrate abrupt changes in rate isolated to one or a few lineages in the phylogeny can mislead rate and age estimation, even when the node of interest is calibrated. We further demonstrate how increasing prior age uncertainty can bias rate and age estimates, even while the 95% highest posterior density around age estimates decreases; in other words, increased precision for an inaccurate estimate. We interpret the use of external calibrations in divergence time studies in light of these results, suggesting that rate shifts at deep time scales may mislead inferences of absolute molecular rates and ages.

  20. Long-time scale spectral diffusion in PMMA: Beyond the TLS model?

    NASA Astrophysics Data System (ADS)

    Müller, J.; Haarer, D.; Khodykin, O. V.; Kharlamov, B. M.

    1999-05-01

    Spectral diffusion (SD) in PMMA doped with H 2-TPP is investigated at 4.2 K on a time scale of 3 ÷ 10 6 s via optical hole burning. Two contradictory (in frames of the TLS model) results are obtained. The first is the absence of aging effects which put the upper limit for the TLS relaxation times to tens of minutes. The second is an intensive superlogarithmic SD on the whole time scale of the experiment, which evidences the presence of very slow relaxations, independent of the sample history on the time scale of up to 2 months. The presented results provide the clear evidence of the deviation of SD behavior from the TLS model predictions at moderately low temperatures. The concept of structural relaxations is applied for a qualitative interpretation of the experimental data.

  1. Assessment of the time constant of relaxation: insights from simulations and hemodynamic measurements

    NASA Technical Reports Server (NTRS)

    De Mey, S.; Thomas, J. D.; Greenberg, N. L.; Vandervoort, P. M.; Verdonck, P. R.

    2001-01-01

    The objective of this study was to use high-fidelity animal data and numerical simulations to gain more insight into the reliability of the estimated relaxation constant derived from left ventricular pressure decays, assuming a monoexponential model with either a fixed zero or free moving pressure asymptote. Comparison of the experimental data with the results of the simulations demonstrated a trade off between the fixed zero and the free moving asymptote approach. The latter method more closely fits the pressure curves and has the advantage of producing an extra coefficient with potential diagnostic information. On the other hand, this method suffers from larger standard errors on the estimated coefficients. The method with fixed zero asymptote produces values of the time constant of isovolumetric relaxation (tau) within a narrow confidence interval. However, if the pressure curve is actually decaying to a nonzero pressure asymptote, this method results in an inferior fit of the pressure curve and a biased estimation of tau.

  2. Comparative study of acoustic relaxation time of cholesteric liquid crystal and mixtures

    NASA Astrophysics Data System (ADS)

    Bhave, Manisha G.; Gharde, Rita; Radha, S.

    2016-09-01

    The present study focuses on the relaxation processes in Cholesteric Liquid Crystal and mixtures. We have dispersed two different monomers in CLC to form Polymer dispersed liquid crystals (PDCLCs). PDLC films have a remarkable electro-optical behavior since they can be switched from highly light scattering state (OFF) to transparent state (ON) simply by application of an electric field. We have also doped ferroelectric nano - powder (NP) in CLC. The phase transitions occurred at temperatures lower than those exhibited by the mesogenic component before doping. The viscosity, ultrasonic velocity and density show variation with change in the material as well as temperature. The acoustic relaxation time and ultrasonic attenuation decrease with increase in temperature for CLC and CLC+NP. The parameters of PDCLC2 in comparison with PDCLC1 are more linear in isotropic and anisotropic regions. For PDCLC2 the values reach maximum value at the Cholesteric-isotropic transition.

  3. Stability of Rasch Scales over Time

    ERIC Educational Resources Information Center

    Taylor, Catherine S.; Lee, Yoonsun

    2010-01-01

    Item response theory (IRT) methods are generally used to create score scales for large-scale tests. Research has shown that IRT scales are stable across groups and over time. Most studies have focused on items that are dichotomously scored. Now Rasch and other IRT models are used to create scales for tests that include polytomously scored items.…

  4. Afterslip and viscoelastic relaxation model inferred from the large-scale post-seismic deformation following the 2010 Mw 8.8 Maule earthquake (Chile)

    NASA Astrophysics Data System (ADS)

    Klein, E.; Fleitout, L.; Vigny, C.; Garaud, J. D.

    2016-06-01

    Megathrust earthquakes of magnitude close to 9 are followed by large-scale (thousands of km) and long-lasting (decades), significant crustal and mantle deformation. This deformation can be observed at the surface and quantified with GPS measurements. Here we report on deformation observed during the 5 yr time span after the 2010 Mw 8.8 Maule Megathrust Earthquake (2010 February 27) over the whole South American continent. With the first 2 yr of those data, we use finite element modelling (FEM) to relate this deformation to slip on the plate interface and relaxation in the mantle, using a realistic layered Earth model and Burgers rheologies. Slip alone on the interface, even up to large depths, is unable to provide a satisfactory fit simultaneously to horizontal and vertical displacements. The horizontal deformation pattern requires relaxation both in the asthenosphere and in a low-viscosity channel along the deepest part of the plate interface and no additional low-viscosity wedge is required by the data. The vertical velocity pattern (intense and quick uplift over the Cordillera) is well fitted only when the channel extends deeper than 100 km. Additionally, viscoelastic relaxation alone cannot explain the characteristics and amplitude of displacements over the first 200 km from the trench and aseismic slip on the fault plane is needed. This aseismic slip on the interface generates stresses, which induce additional relaxation in the mantle. In the final model, all three components (relaxation due to the coseismic slip, aseismic slip on the fault plane and relaxation due to aseismic slip) are taken into account. Our best-fit model uses slip at shallow depths on the subduction interface decreasing as function of time and includes (i) an asthenosphere extending down to 200 km, with a steady-state Maxwell viscosity of 4.75 × 1018 Pa s; and (ii) a low-viscosity channel along the plate interface extending from depths of 55-135 km with viscosities below 1018 Pa s.

  5. Fundamental studies of stress distributions and stress relaxation in oxide scales on high temperature alloys. [Final progress report

    SciTech Connect

    Shores, D.A.; Stout, J.H.; Gerberich, W.W.

    1993-06-01

    This report summarizes a three-year study of stresses arising in the oxide scale and underlying metal during high temperature oxidation and of scale cracking. In-situ XRD was developed to measure strains during oxidation over 1000{degrees}C on pure metals. Acoustic emission was used to observe scale fracture during isothermal oxidation and cooling, and statistical analysis was used to infer mechanical aspects of cracking. A microscratch technique was used to measure the fracture toughness of scale/metal interface. A theoretical model was evaluated for the development and relaxation of stresses in scale and metal substrate during oxidation.

  6. Electron spin relaxation time in (110) InGaAs/InAlAs quantum wells

    SciTech Connect

    Yokota, Nobuhide; Yasuda, Yusuke; Ikeda, Kazuhiro; Kawaguchi, Hitoshi

    2014-07-14

    Electron spin relaxation time τ{sub s} in InGaAs/InAlAs quantum wells (QWs) grown on (110) and (100) InP substrates was investigated by pump-probe transmission measurements. Similar τ{sub s} of 0.83–1.0 ns were measured at room temperature for all the measured (110) and (100) QWs, indicating suppression of the D'yakonov-Perel' spin relaxation mechanism in (110) QWs is not effective in InGaAs/InAlAs QWs as opposed to GaAs/AlGaAs QWs. Contribution of the Bir-Aronov-Pikus mechanism dominant in (110) GaAs/AlGaAs QWs was found to be small in both the (110) and (100) InGaAs/InAlAs QWs from the weak dependences of τ{sub s} on pump intensity at room temperature. These results suggest that the spin relaxation mechanism dominant in InGaAs/InAlAs QWs at a temperature higher than 200 K is the Elliott-Yafet mechanism independent of the crystal orientation among the above three major mechanisms.

  7. Ground-state atomic polarization relaxation-time measurement of Rb filled hypocycloidal core-shaped Kagome HC-PCF

    NASA Astrophysics Data System (ADS)

    Bradley, T. D.; Ilinova, E.; McFerran, J. J.; Jouin, J.; Debord, B.; Alharbi, M.; Thomas, P.; Gérôme, F.; Benabid, F.

    2016-09-01

    We report on the measurement of ground-state atomic polarization relaxation time of Rb vapor confined in five different hypocycloidal core-shape Kagome hollow-core photonic crystal fibers made with uncoated silica glass. We are able to distinguish between wall-collision and transit-time effects in an optical waveguide and deduce the contribution of the atom’s dwell time at the core wall surface. In contrast with conventional macroscopic atomic cell configuration, and in agreement with Monte Carlo simulations, the measured relaxation times were found to be at least one order of magnitude longer than the limit set by atom-wall collisional from thermal atoms. This extended relaxation time is explained by the combination of a stronger contribution of the slow atoms in the atomic polarization build-up, and of the relatively significant contribution of dwell time to the relaxation process of the ground state polarization.

  8. The timing of eukaryotic evolution: does a relaxed molecular clock reconcile proteins and fossils?

    PubMed

    Douzery, Emmanuel J P; Snell, Elizabeth A; Bapteste, Eric; Delsuc, Frédéric; Philippe, Hervé

    2004-10-26

    The use of nucleotide and amino acid sequences allows improved understanding of the timing of evolutionary events of life on earth. Molecular estimates of divergence times are, however, controversial and are generally much more ancient than suggested by the fossil record. The limited number of genes and species explored and pervasive variations in evolutionary rates are the most likely sources of such discrepancies. Here we compared concatenated amino acid sequences of 129 proteins from 36 eukaryotes to determine the divergence times of several major clades, including animals, fungi, plants, and various protists. Due to significant variations in their evolutionary rates, and to handle the uncertainty of the fossil record, we used a Bayesian relaxed molecular clock simultaneously calibrated by six paleontological constraints. We show that, according to 95% credibility intervals, the eukaryotic kingdoms diversified 950-1,259 million years ago (Mya), animals diverged from choanoflagellates 761-957 Mya, and the debated age of the split between protostomes and deuterostomes occurred 642-761 Mya. The divergence times appeared to be robust with respect to prior assumptions and paleontological calibrations. Interestingly, these relaxed clock time estimates are much more recent than those obtained under the assumption of a global molecular clock, yet bilaterian diversification appears to be approximately 100 million years more ancient than the Cambrian boundary.

  9. Estimation of water retention parameters from nuclear magnetic resonance relaxation time distributions

    PubMed Central

    Costabel, Stephan; Yaramanci, Ugur

    2013-01-01

    [1] For characterizing water flow in the vadose zone, the water retention curve (WRC) of the soil must be known. Because conventional WRC measurements demand much time and effort in the laboratory, alternative methods with shortened measurement duration are desired. The WRC can be estimated, for instance, from the cumulative pore size distribution (PSD) of the investigated material. Geophysical applications of nuclear magnetic resonance (NMR) relaxometry have successfully been applied to recover PSDs of sandstones and limestones. It is therefore expected that the multiexponential analysis of the NMR signal from water-saturated loose sediments leads to a reliable estimation of the WRC. We propose an approach to estimate the WRC using the cumulative NMR relaxation time distribution and approximate it with the well-known van-Genuchten (VG) model. Thereby, the VG parameter n, which controls the curvature of the WRC, is of particular interest, because it is the essential parameter to predict the relative hydraulic conductivity. The NMR curves are calibrated with only two conventional WRC measurements, first, to determine the residual water content and, second, to define a fixed point that relates the relaxation time to a corresponding capillary pressure. We test our approach with natural and artificial soil samples and compare the NMR-based results to WRC measurements using a pressure plate apparatus and to WRC predictions from the software ROSETTA. We found that for sandy soils n can reliably be estimated with NMR, whereas for samples with clay and silt contents higher than 10% the estimation fails. This is the case when the hydraulic properties of the soil are mainly controlled by the pore constrictions. For such samples, the sensitivity of the NMR method for the pore bodies hampers a plausible WRC estimation. Citation: Costabel, S., and U. Yaramanci (2013), Estimation of water retention parameters from nuclear magnetic resonance relaxation time distributions, Water

  10. A density-matrix model of photosynthetic electron transfer with microscopically estimated vibrational relaxation times

    NASA Astrophysics Data System (ADS)

    Parson, William W.; Warshel, Arieh

    2004-01-01

    The dispersed-polaron (spin-boson) model is reviewed briefly and then used to develop a density-matrix model for studies of electron transfer in condensed phases. The frequencies and Franck-Condon factors for solvent vibrational modes that are coupled to electron transfer are obtained from molecular dynamics (MD) simulations by the dispersed-polaron treatment. Microscopic rate constants for vibrational relaxations, dephasing and coherence transfer between the solvent modes are obtained by fitting the time dependence of the solvent coordinates in the density-matrix treatment to the corresponding time dependence obtained from molecular-dynamics simulations with a classical linear-response approximation. This is done by adjusting a single parameter, the time constant for thermal equilibration of the two lowest levels of a solvent mode ( T10). The model thus focuses on the coupling between solvent modes, rather than on the more widely studied coupling of solute modes by the thermal bath. The resulting density-matrix model is used to examine vibronic coupling in the initial electron-transfer step in photosynthetic bacterial reaction centers. Values of T10 in the range of 1-2 ps are consistent with molecular-dynamics simulations of the time-dependent energy gap between the reactant and product states (P* and P +B -), and also with the damping of coherent vibrational motions that are seen experimentally after excitation of reaction centers with a short pulse of light. In both the density-matrix model and the MD simulations, the autocorrelation function of the energy gap also has a decay component with a time constant of about 50 fs, which we ascribe to the group dephasing of oscillatory motions at many different frequencies. This component is insensitive to vibrational relaxations and is largely irrelevant to the electron-transfer dynamics. Using values of T10 in the range of 1-2 ps, a model with five vibrational modes reproduces the main features of electron transfer

  11. Electron spin relaxation time measurements using radiofrequency longitudinally detected ESR and application in oximetry.

    PubMed

    Panagiotelis, I; Nicholson, I; Hutchison, J M

    2001-03-01

    Longitudinally detected ESR (LODESR) involves transverse ESR irradiation with a modulated source and observing oscillations in the spin magnetization parallel to the main magnetic field. In this study, radiofrequency-LODESR was used for oximetry by measuring the relaxation times of the electron. T1e and T2e were measured by investigating LODESR signal magnitude as a function of detection frequency. We have also predicted theoretically and verified experimentally the LODESR signal phase dependence on detection frequency and relaxation times. These methods are valid even for inhomogeneous lines provided that T1e>T2e. We have also developed a new method for measuring T1e, valid for inhomogeneous spectra, for all values of T1e and T2e, based on measuring the spectral area as a function of detection frequency. We have measured T1e and T2e for lithium phthalocyanine crystals, for the nitroxide TEMPOL, and for the single line agent Triarylmethyl (TAM). Furthermore, we have collected spectra from aqueous solutions of TEMPOL and TAM at different oxygen concentrations and confirmed that T1e values are reduced with increased oxygen concentration. We have also measured the spin-lattice electronic relaxation time for degassed aqueous solutions of the same agents at different agent concentrations. T1e decreases as a function of concentration for TAM while it remains independent of free radical concentration for TEMPOL, a major advantage for oxygen mapping. This method, combined with the ability of LODESR to provide images of exogenous free radicals in vivo, presents an attractive alternative to the conventional transverse ESR linewidth based oximetry methods.

  12. Relaxation time of the Cooper pairs near Tc in cuprate superconductors

    NASA Astrophysics Data System (ADS)

    Ramallo, M. V.; Carballeira, C.; Viña, J.; Veira, J. A.; Mishonov, T.; Pavuna, D.; Vidal, F.

    1999-10-01

    It is first shown that the thermal fluctuation effects on the transport and on the thermodynamic observables above the superconducting transition may provide, when they are analyzed simultaneously and consistently, a powerful tool to access the relaxation time, τ0, of the Cooper pairs with wave vector k = 0 in high-temperature cuprate superconductors (HTSC). Then, we apply this procedure to optimally doped YBa2Cu3O7 - δ (Y-123) crystals. It is found that in this HTSC τ0 follows, within 20% accuracy, the BCS temperature behaviour and amplitude given by τ0 = πhbar/[8kB(T - Tc0)].

  13. A Novel Statistical Approach for Brain MR Images Segmentation Based on Relaxation Times

    PubMed Central

    Ferraioli, Giampaolo; Pascazio, Vito

    2015-01-01

    Brain tissue segmentation in Magnetic Resonance Imaging is useful for a wide range of applications. Classical approaches exploit the gray levels image and implement criteria for differentiating regions. Within this paper a novel approach for brain tissue joint segmentation and classification is presented. Starting from the estimation of proton density and relaxation times, we propose a novel method for identifying the optimal decision regions. The approach exploits the statistical distribution of the involved signals in the complex domain. The technique, compared to classical threshold based ones, is able to globally improve the classification rate. The effectiveness of the approach is evaluated on both simulated and real datasets. PMID:26798631

  14. Density Relaxation in Time-Dependent Density Functional Theory: Combining Relaxed Density Natural Orbitals and Multireference Perturbation Theories for an Improved Description of Excited States.

    PubMed

    Ronca, Enrico; Angeli, Celestino; Belpassi, Leonardo; De Angelis, Filippo; Tarantelli, Francesco; Pastore, Mariachiara

    2014-09-01

    Making use of the recently developed excited state charge displacement analysis [E. Ronca et al., J. Chem. Phys. 140, 054110 (2014)], suited to quantitatively characterize the charge fluxes coming along an electronic excitation, we investigate the role of the density relaxation effects in the overall description of electronically excited states of different nature, namely, valence, ionic, and charge transfer (CT), considering a large set of prototypical small and medium-sized molecular systems. By comparing the response densities provided by time-dependent density functional theory (TDDFT) and the corresponding relaxed densities obtained by applying the Z-vector postlinear-response approach [N. C. Handy and H. F. Schaefer, J. Chem. Phys. 81, 5031 (1984)] with those obtained by highly correlated state-of-the-art wave function calculations, we show that the inclusion of the relaxation effects is imperative to get an accurate description of the considered excited states. We also examine what happens at the quality of the response function when an increasing amount of Hartree-Fock (HF) exchange is included in the functional, showing that the usually improved excitation energies in the case of CT states are not always the consequence of an improved description of their overall properties. Remarkably, we find that the relaxation of the response densities is always able to reproduce, independently of the extent of HF exchange in the functional, the benchmark wave function densities. Finally, we propose a novel and computationally convenient strategy, based on the use of the natural orbitals derived from the relaxed TDDFT density to build zero-order wave function for multireference perturbation theory calculations. For a significant set of different excited states, the proposed approach provided accurate excitation energies, comparable to those obtained by computationally demanding ab initio calculations.

  15. A method for measuring the Néel relaxation time in a frozen ferrofluid

    NASA Astrophysics Data System (ADS)

    Tackett, Ronald J.; Thakur, Jagdish; Mosher, Nathaniel; Perkins-Harbin, Emily; Kumon, Ronald E.; Wang, Lihua; Rablau, Corneliu; Vaishnava, Prem P.

    2015-08-01

    We report a novel method of determining the average Néel relaxation time and its temperature dependence by calculating derivatives of the measured time dependence of temperature for a frozen ferrofluid exposed to an alternating magnetic field. The ferrofluid, composed of dextran-coated Fe3O4 nanoparticles (diameter 13.7 nm ± 4.7 nm), was synthesized via wet chemical precipitation and characterized by x-ray diffraction and transmission electron microscopy. An alternating magnetic field of constant amplitude ( H 0 = 20 kA/m) driven at frequencies of 171 kHz, 232 kHz, and 343 kHz was used to determine the temperature dependent magnetic energy absorption rate in the temperature range from 160 K to 210 K. We found that the specific absorption rate of the ferrofluid decreased monotonically with temperature over this range at the given frequencies. From these measured data, we determined the temperature dependence of the Néel relaxation time and estimate a room-temperature magnetocrystalline anisotropy constant of 40 kJ/m3, in agreement with previously published results.

  16. Relationship between Structural and Stress Relaxation in a Block-Copolymer Melt

    SciTech Connect

    Patel, Amish J.; Narayanan, Suresh; Sandy, Alec; Mochrie, Simon G. J.; Garetz, Bruce A.; Watanabe, Hiroshi; Balsara, Nitash P.

    2006-06-30

    The relationship between structural relaxation on molecular length scales and macroscopic stress relaxation was explored in a disordered block-copolymer melt. Experiments show that the structural relaxation time, measured by x-ray photon correlation spectroscopy is larger than the terminal stress relaxation time, measured by rheology, by factors as large as 100. We demonstrate that the structural relaxation data are dominated by the diffusion of intact micelles while the stress relaxation data are dominated by contributions due to disordered concentration fluctuations.

  17. Rapid and simple determination of T1 relaxation times in time-domain NMR by Continuous Wave Free Precession sequence

    NASA Astrophysics Data System (ADS)

    Moraes, Tiago Bueno; Monaretto, Tatiana; Colnago, Luiz Alberto

    2016-09-01

    Longitudinal (T1) and transverse (T2) relaxation times have been widely used in time-domain NMR (TD-NMR) to determine several physicochemical properties of petroleum, polymers, and food products. The measurement of T2 through the CPMG pulse sequence has been used in most of these applications because it denotes a rapid, robust method. On the other hand, T1 has been occasionally used in TD-NMR due to the long measurement time required to collect multiple points along the T1 relaxation curve. Recently, several rapid methods to measure T1 have been proposed. Those methods based upon single shot, known as Continuous Wave Free Precession (CWFP) pulse sequences, have been employed in the simultaneous measurement of T1 and T2 in a rapid fashion. However, these sequences can be used exclusively in instrument featuring short dead time because the magnitude of the signal at thermal equilibrium is required. In this paper, we demonstrate that a special CWFP sequence with a low flip angle can be a simple and rapid method to measure T1 regardless of instruments dead time. Experimental results confirmed that the method called CWFP-T1 may be used to measure both single T1 value and T1 distribution in heterogeneous samples. Therefore, CWFP-T1 sequence can be a feasible alternative to CPMG in the determination of physicochemical properties, particularly in processes where fast protocols are requested such as industrial applications.

  18. Rapid and simple determination of T1 relaxation times in time-domain NMR by Continuous Wave Free Precession sequence.

    PubMed

    Moraes, Tiago Bueno; Monaretto, Tatiana; Colnago, Luiz Alberto

    2016-09-01

    Longitudinal (T1) and transverse (T2) relaxation times have been widely used in time-domain NMR (TD-NMR) to determine several physicochemical properties of petroleum, polymers, and food products. The measurement of T2 through the CPMG pulse sequence has been used in most of these applications because it denotes a rapid, robust method. On the other hand, T1 has been occasionally used in TD-NMR due to the long measurement time required to collect multiple points along the T1 relaxation curve. Recently, several rapid methods to measure T1 have been proposed. Those methods based upon single shot, known as Continuous Wave Free Precession (CWFP) pulse sequences, have been employed in the simultaneous measurement of T1 and T2 in a rapid fashion. However, these sequences can be used exclusively in instrument featuring short dead time because the magnitude of the signal at thermal equilibrium is required. In this paper, we demonstrate that a special CWFP sequence with a low flip angle can be a simple and rapid method to measure T1 regardless of instruments dead time. Experimental results confirmed that the method called CWFP-T1 may be used to measure both single T1 value and T1 distribution in heterogeneous samples. Therefore, CWFP-T1 sequence can be a feasible alternative to CPMG in the determination of physicochemical properties, particularly in processes where fast protocols are requested such as industrial applications. PMID:27376553

  19. Long-time atomistic evolution of grain boundary in nickel using the kinetic activation-relaxation technique

    NASA Astrophysics Data System (ADS)

    Mahmoud, Sami; Trochet, Mickaël; Restrepo, Oscar; Mousseau, Normand

    The microscopic mechanisms associated with the evolution of metallic materials are still a matter of debate as both experimental and numerical approaches fail to provide a detailed atomic picture of their time evolution. Here, we use the kinetic activation-relaxation technique (k-ART), an unbiased off-lattice kinetic Monte Carlo method with on-the-fly catalog building to overcome these limitations and follow the atomistic evolution of a 10.000-atom grain boundary Ni system over macroscopic time scales. We first characterize the kinetic properties of four different empirical potentials, the embedded atom method (EAM), the first and second modified embedded atom method (MEAM1NN and MEAM2NN respectively) and the Reax force field (ReaxFF) potentials. Comparing the energetics, the elastic effects and the diffusion mechanisms for systems with one to three vacancies and one to three self-interstitials in nickel simulated over second time scale, we conclude that ReaxFF and EAM potentials are closest to experimental values. We then proceed to study the long-time evolution of a grain boundary with the Reax forcefield and to offer a detailed description of its energy landscape, including the exact description of short and long-range effects on self-diffusion along the interface

  20. Review of time scales. [Universal Time-Ephemeris Time-International Atomic Time

    NASA Technical Reports Server (NTRS)

    Guinot, B.

    1974-01-01

    The basic time scales are presented: International Atomic Time, Universal Time, and Universal Time (Coordinated). These scales must be maintained in order to satisfy specific requirements. It is shown how they are obtained and made available at a very high level of precision.

  1. The effect of the polymer relaxation time on the nonlinear energy cas- cade and dissipation of statistically steady and decaying homogeneous isotropic turbulence

    NASA Astrophysics Data System (ADS)

    Valente, Pedro C.; da Silva, Carlos B.; Pinho, Fernando T.

    2013-11-01

    We report a numerical study of statistically steady and decaying turbulence of FENE-P fluids for varying polymer relaxation times ranging from the Kolmogorov dissipation time-scale to the eddy turnover time. The total turbulent kinetic energy dissipation is shown to increase with the polymer relaxation time in both steady and decaying turbulence, implying a ``drag increase.'' If the total power input in the statistically steady case is kept equal in the Newtonian and the viscoelastic simulations the increase in the turbulence-polymer energy transfer naturally lead to the previously reported depletion of the Newtonian, but not the overall, kinetic energy dissipation. The modifications to the nonlinear energy cascade with varying Deborah/Weissenberg numbers are quantified and their origins investigated. The authors acknowledge the financial support from Fundação para a Ciência e a Tecnologia under grant PTDC/EME-MFE/113589/2009.

  2. Time scale in quasifission reactions

    SciTech Connect

    Back, B.B.; Paul, P.; Nestler, J.

    1995-08-01

    The quasifission process arises from the hindrance of the complete fusion process when heavy-ion beams are used. The strong dissipation in the system tends to prevent fusion and lead the system towards reseparation into two final products of similar mass reminiscent of a fission process. This dissipation slows down the mass transfer and shape transformation and allows for the emission of high energy {gamma}-rays during the process, albeit with a low probability. Giant Dipole {gamma} rays emitted during this time have a characteristic spectral shape and may thus be discerned in the presence of a background of {gamma} rays emitted from the final fission-like fragments. Since the rate of GDR {gamma} emission is very well established, the strength of this component may therefore be used to measure the timescale of the quasifission process. In this experiment we studied the reaction between 368-MeV {sup 58}Ni and a {sup 165}Ho target, where deep inelastic scattering and quasifission processes are dominant. Coincidences between fission fragments (detected in four position-sensitive avalanche detectors) and high energy {gamma} rays (measured in a 10{close_quotes} x 10{close_quotes} actively shielded NaI detector) were registered. Beams were provided by the Stony Brook Superconducting Linac. The {gamma}-ray spectrum associated with deep inelastic scattering events is well reproduced by statistical cooling of projectile and target-like fragments with close to equal initial excitation energy sharing. The y spectrum associated with quasifission events is well described by statistical emission from the fission fragments alone, with only weak evidence for GDR emission from the mono-nucleus. A 1{sigma} limit of t{sub ss} < 11 x 10{sup -21} s is obtained for the mono-nucleus lifetime, which is consistent with the lifetime obtained from quasifission fragment angular distributions. A manuscript was accepted for publication.

  3. Multiple time scale methods in tokamak magnetohydrodynamics

    SciTech Connect

    Jardin, S.C.

    1984-01-01

    Several methods are discussed for integrating the magnetohydrodynamic (MHD) equations in tokamak systems on other than the fastest time scale. The dynamical grid method for simulating ideal MHD instabilities utilizes a natural nonorthogonal time-dependent coordinate transformation based on the magnetic field lines. The coordinate transformation is chosen to be free of the fast time scale motion itself, and to yield a relatively simple scalar equation for the total pressure, P = p + B/sup 2//2..mu../sub 0/, which can be integrated implicitly to average over the fast time scale oscillations. Two methods are described for the resistive time scale. The zero-mass method uses a reduced set of two-fluid transport equations obtained by expanding in the inverse magnetic Reynolds number, and in the small ratio of perpendicular to parallel mobilities and thermal conductivities. The momentum equation becomes a constraint equation that forces the pressure and magnetic fields and currents to remain in force balance equilibrium as they evolve. The large mass method artificially scales up the ion mass and viscosity, thereby reducing the severe time scale disparity between wavelike and diffusionlike phenomena, but not changing the resistive time scale behavior. Other methods addressing the intermediate time scales are discussed.

  4. Kalman plus weights: a time scale algorithm

    NASA Technical Reports Server (NTRS)

    Greenhall, C. A.

    2001-01-01

    KPW is a time scale algorithm that combines Kalman filtering with the basic time scale equation (BTSE). A single Kalman filter that estimates all clocks simultaneously is used to generate the BTSE frequency estimates, while the BTSE weights are inversely proportional to the white FM variances of the clocks. Results from simulated clock ensembles are compared to previous simulation results from other algorithms.

  5. Cross-Scale Modelling of Subduction from Minute to Million of Years Time Scale

    NASA Astrophysics Data System (ADS)

    Sobolev, S. V.; Muldashev, I. A.

    2015-12-01

    Subduction is an essentially multi-scale process with time-scales spanning from geological to earthquake scale with the seismic cycle in-between. Modelling of such process constitutes one of the largest challenges in geodynamic modelling today.Here we present a cross-scale thermomechanical model capable of simulating the entire subduction process from rupture (1 min) to geological time (millions of years) that employs elasticity, mineral-physics-constrained non-linear transient viscous rheology and rate-and-state friction plasticity. The model generates spontaneous earthquake sequences. The adaptive time-step algorithm recognizes moment of instability and drops the integration time step to its minimum value of 40 sec during the earthquake. The time step is then gradually increased to its maximal value of 5 yr, following decreasing displacement rates during the postseismic relaxation. Efficient implementation of numerical techniques allows long-term simulations with total time of millions of years. This technique allows to follow in details deformation process during the entire seismic cycle and multiple seismic cycles. We observe various deformation patterns during modelled seismic cycle that are consistent with surface GPS observations and demonstrate that, contrary to the conventional ideas, the postseismic deformation may be controlled by viscoelastic relaxation in the mantle wedge, starting within only a few hours after the great (M>9) earthquakes. Interestingly, in our model an average slip velocity at the fault closely follows hyperbolic decay law. In natural observations, such deformation is interpreted as an afterslip, while in our model it is caused by the viscoelastic relaxation of mantle wedge with viscosity strongly varying with time. We demonstrate that our results are consistent with the postseismic surface displacement after the Great Tohoku Earthquake for the day-to-year time range. We will also present results of the modeling of deformation of the

  6. Enhancing Web applications in radiology with Java: estimating MR imaging relaxation times.

    PubMed

    Dagher, A P; Fitzpatrick, M; Flanders, A E; Eng, J

    1998-01-01

    Java is a relatively new programming language that has been used to develop a World Wide Web-based tool for estimating magnetic resonance (MR) imaging relaxation times, thereby demonstrating how Java may be used for Web-based radiology applications beyond improving the user interface of teaching files. A standard processing algorithm coded with Java is downloaded along with the hypertext markup language (HTML) document. The user (client) selects the desired pulse sequence and inputs data obtained from a region of interest on the MR images. The algorithm is used to modify selected MR imaging parameters in an equation that models the phenomenon being evaluated. MR imaging relaxation times are estimated, and confidence intervals and a P value expressing the accuracy of the final results are calculated. Design features such as simplicity, object-oriented programming, and security restrictions allow Java to expand the capabilities of HTML by offering a more versatile user interface that includes dynamic annotations and graphics. Java also allows the client to perform more sophisticated information processing and computation than is usually associated with Web applications. Java is likely to become a standard programming option, and the development of stand-alone Java applications may become more common as Java is integrated into future versions of computer operating systems.

  7. WATER AND METABOLITE TRANSVERSE T2 RELAXATION TIME ABNORMALITIES IN THE WHITE MATTER IN SCHIZOPHRENIA

    PubMed Central

    Du, Fei; Cooper, Alissa; Cohen, Bruce M.; Renshaw, Perry F.; Öngür, Dost

    2012-01-01

    Multiple lines of evidence suggest that microstructural abnormalities in the white matter are important in the pathophysiology of schizophrenia. Diffusion MRI approaches which can provide evidence on tissue structure have been widely used to probe these abnormalities in vivo, but transverse relaxation times (T2) may provide additional insights since they are determined by molecule-microenvironment interactions not revealed by diffusion MRI. T2 of water – located both intra and extracellularly – and N-acetylaspartate (NAA – located intracellularly) reflect related but distinct processes due to their differential localization and interactions with other molecules. In this study, we collected water and NAA T2 data from 16 healthy subjects (HC), and 16 patients with schizophrenia (SZ) at 4 Tesla in a 9cc voxel in the right prefrontal white matter. The SZ group had longer water but shorter NAA T2 relaxation times when compared with the HC group. This pattern resulted in a statistically significant metabolite x group interaction (F(18,1):4.980, p=0.039). Prolongation of water T2 and shortening of NAA T2 is consistent with an impoverishment of white matter macromolecule structures (including myelin) and abnormal intra-axonal milieu and volume in SZ. PMID:22356802

  8. Unsteady immiscible multiphase flow validation of a multiple-relaxation-time lattice Boltzmann method

    NASA Astrophysics Data System (ADS)

    Leclaire, S.; Pellerin, N.; Reggio, M.; Trépanier, J.-Y.

    2014-03-01

    The lattice Boltzmann modeling of immiscible multiphase flows needs to be further validated, especially when density variation occurs between the different flow phases. From this perspective, the goal of this research is to introduce the multiple-relaxation-time operator into a lattice Boltzmann model in order to improve its numerical stability in the presence of large density and viscosity ratios. Essentially, this research shows that the introduction of this operator greatly improves the numerical stability of the approach compared to the original single-relaxation-time collision operator. In many lattice Boltzmann research studies, multiphase lattice Boltzmann methods are validated using a reduced number of test cases, and unsteady flow test cases are frequently omitted before much more complex flow configurations are simulated. In this context, several test cases are proposed to evaluate the behavior of a lattice Boltzmann method for simulating immiscible multiphase flows with high density and viscosity ratios. These are: (1) two-phase Couette flow; (2) three-phase Laplace law; (3) three-phase Zalesak disk; (4) two-phase flow between oscillating plates; (5) two-phase capillary wave; and (6) the two-phase oscillating cylindrical bubble. The first two involve a steady regime, and the remaining four an unsteady regime.

  9. On the nonlinear variation of dc conductivity with dielectric relaxation time

    NASA Astrophysics Data System (ADS)

    Johari, G. P.; Andersson, Ove

    2006-09-01

    The long-known observations that dc conductivity σdc of an ultraviscous liquid varies nonlinearly with the dielectric relaxation time τ, and the slope of the logσdc against logτ plot deviates from -1 are currently seen as two of the violations of the Debye-Stokes-Einstein equation. Here we provide a formalism using a zeroth order Bjerrum description for ion association to show that in addition to its variation with temperature T and pressure P, impurity ion population varies with a liquid's equilibrium dielectric permittivity. Inclusion of this electrostatic effect modifies the Debye-Stokes-Einstein equation to log(σdcτ )=constant+logα, where α is the T and P-dependent degree of ionic dissociation of an electrolytic impurity. Variation of a liquid's shear modulus with T and P would add to the nonlinearity of σdc-τ relation, as would a nonequivalence of the shear and dielectric relaxation times, proton transfer along the hydrogen bonds, or occurrence of another chemical process. This is illustrated by using the data for ultraviscous acetaminophen-aspirin liquid.

  10. Determining Stroke Onset Time Using Quantitative MRI: High Accuracy, Sensitivity and Specificity Obtained from Magnetic Resonance Relaxation Times

    PubMed Central

    McGarry, Bryony L.; Rogers, Harriet J.; Knight, Michael J.; Jokivarsi, Kimmo T.; Gröhn, Olli H.J.; Kauppinen, Risto A.

    2016-01-01

    Many ischaemic stroke patients are ineligible for thrombolytic therapy due to unknown onset time. Quantitative MRI (qMRI) is a potential surrogate for stroke timing. Rats were subjected to permanent middle cerebral artery occlusion and qMRI parameters including hemispheric differences in apparent diffusion coefficient, T2-weighted signal intensities, T1 and T2 relaxation times (qT1, qT2) and f1, f2 and Voverlap were measured at hourly intervals at 4.7 or 9.4 T. Accuracy and sensitivity for identifying strokes scanned within and beyond 3 h of onset was determined. Accuracy for Voverlap, f2 and qT2 (>90%) was significantly higher than other parameters. At a specificity of 1, sensitivity was highest for Voverlap (0.90) and f2 (0.80), indicating promise of these qMRI indices in the clinical assessment of stroke onset time.

  11. Average-atom treatment of relaxation time in x-ray Thomson scattering from warm dense matter

    NASA Astrophysics Data System (ADS)

    Johnson, W. R.; Nilsen, J.

    2016-03-01

    The influence of finite relaxation times on Thomson scattering from warm dense plasmas is examined within the framework of the average-atom approximation. Presently most calculations use the collision-free Lindhard dielectric function to evaluate the free-electron contribution to the Thomson cross section. In this work, we use the Mermin dielectric function, which includes relaxation time explicitly. The relaxation time is evaluated by treating the average atom as an impurity in a uniform electron gas and depends critically on the transport cross section. The calculated relaxation rates agree well with values inferred from the Ziman formula for the static conductivity and also with rates inferred from a fit to the frequency-dependent conductivity. Transport cross sections determined by the phase-shift analysis in the average-atom potential are compared with those evaluated in the commonly used Born approximation. The Born approximation converges to the exact cross sections at high energies; however, differences that occur at low energies lead to corresponding differences in relaxation rates. The relative importance of including relaxation time when modeling x-ray Thomson scattering spectra is examined by comparing calculations of the free-electron dynamic structure function for Thomson scattering using Lindhard and Mermin dielectric functions. Applications are given to warm dense Be plasmas, with temperatures ranging from 2 to 32 eV and densities ranging from 2 to 64 g/cc.

  12. Average-atom treatment of relaxation time in x-ray Thomson scattering from warm dense matter.

    PubMed

    Johnson, W R; Nilsen, J

    2016-03-01

    The influence of finite relaxation times on Thomson scattering from warm dense plasmas is examined within the framework of the average-atom approximation. Presently most calculations use the collision-free Lindhard dielectric function to evaluate the free-electron contribution to the Thomson cross section. In this work, we use the Mermin dielectric function, which includes relaxation time explicitly. The relaxation time is evaluated by treating the average atom as an impurity in a uniform electron gas and depends critically on the transport cross section. The calculated relaxation rates agree well with values inferred from the Ziman formula for the static conductivity and also with rates inferred from a fit to the frequency-dependent conductivity. Transport cross sections determined by the phase-shift analysis in the average-atom potential are compared with those evaluated in the commonly used Born approximation. The Born approximation converges to the exact cross sections at high energies; however, differences that occur at low energies lead to corresponding differences in relaxation rates. The relative importance of including relaxation time when modeling x-ray Thomson scattering spectra is examined by comparing calculations of the free-electron dynamic structure function for Thomson scattering using Lindhard and Mermin dielectric functions. Applications are given to warm dense Be plasmas, with temperatures ranging from 2 to 32 eV and densities ranging from 2 to 64 g/cc.

  13. Unusual longitudinal relaxation time behaviour of colloidal solutions of superparamagnetic nanoparticles

    NASA Astrophysics Data System (ADS)

    Carvalho, A.; Taborda, A.

    2007-12-01

    Superparamagnetic nanoparticles are very interesting objects having many applications among which MRI contrast agents are one of the more important. In this work the longitudinal relaxation times of Endorem and Lumirem, two colloidal solutions of iron oxide nanoparticles used as contrast agents for magnetic resonance imaging were measured at magnetic field intensities similar to the ones used in MRI. T1 was seen to depend on nanoparticle concentrations as expected but, for the Lumirem, also on the time spend by the sample under the influence of the static magnetic field. The T1 evolution was measured for colloidal solutions both different concentrations and different viscosities. The strange T1 dependence is presented and discussed relating to the nanoparticles superparamagnetic properties. It is shown that one of the possible reasons for the fact is the formation of local field enhanced linear arrays of SPIO.

  14. Dynamical theory of spin noise and relaxation: Prospects for real-time NMR measurements.

    PubMed

    Field, Timothy R

    2014-11-01

    Recent developments in theoretical aspects of spin noise and relaxation and their interrelationship reveal a modified spin density, distinct from the density matrix, as the necessary object to describe fluctuations in spin systems. These fluctuations are to be viewed as an intrinsic quantum mechanical property of such systems immersed in random magnetic environments and are observed as "spin noise" in the absence of any radio frequency excitation. With the prospect of ultrafast digitization, the role of spin noise in real-time parameter extraction for (NMR) spin systems, and the advantage over standard techniques, is of essential importance, especially for systems containing a small number of spins. In this article we outline prospects for harnessing the recent dynamical theory in terms of spin-noise measurement, with attention to real-time properties.

  15. Going up in time and length scales in modeling polymers

    NASA Astrophysics Data System (ADS)

    Grest, Gary S.

    Polymer properties depend on a wide range of coupled length and time scales, with unique macroscopic viscoelastic behavior stemming from interactions at the atomistic level. The need to probe polymers across time and length scales and particularly computational modeling is inherently challenging. Here new paths to probing long time and length scales including introducing interactions into traditional bead-spring models and coarse graining of atomistic simulations will be compared and discussed. Using linear polyethylene as a model system, the degree of coarse graining with two to six methylene groups per coarse-grained bead derived from a fully atomistic melt simulation were probed. We show that the degree of coarse graining affects the measured dynamic. Using these models we were successful in probing highly entangled melts and were able reach the long-time diffusive regime which is computationally inaccessible using atomistic simulations. We simulated the relaxation modulus and shear viscosity of well-entangled polyethylene melts for scaled times of 500 µs. Results for plateau modulus are in good agreement with experiment. The long time and length scale is coupled to the macroscopic viscoelasticity where the degree of coarse graining sets the minimum length scale instrumental in defining polymer properties and dynamics. Results will be compared to those obtained from simple bead-spring models to demonstrate the additional insight that can be gained from atomistically inspired coarse grained models. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  16. Temperature dependence of proton NMR relaxation times at earth's magnetic field

    NASA Astrophysics Data System (ADS)

    Niedbalski, Peter; Kiswandhi, Andhika; Parish, Christopher; Ferguson, Sarah; Cervantes, Eduardo; Oomen, Anisha; Krishnan, Anagha; Goyal, Aayush; Lumata, Lloyd

    The theoretical description of relaxation processes for protons, well established and experimentally verified at conventional nuclear magnetic resonance (NMR) fields, has remained untested at low fields despite significant advances in low field NMR technology. In this study, proton spin-lattice relaxation (T1) times in pure water and water doped with varying concentrations of the paramagnetic agent copper chloride have been measured from 6 to 92oC at earth's magnetic field (1700 Hz). Results show a linear increase of T1 with temperature for each of the samples studied. Increasing the concentration of the copper chloride greatly reduced T1 and reduced dependence on temperature. The consistency of the results with theory is an important confirmation of past results, while the ability of an ultra-low field NMR system to do contrast-enhanced magnetic resonance imaging (MRI) is promising for future applicability to low-cost medical imaging and chemical identification. This work is supported by US Dept of Defense Award No. W81XWH-14-1-0048 and the Robert A. Welch Foundation Grant No. AT-1877.

  17. 7Li relaxation time measurements at very low magnetic field by 1H dynamic nuclear polarization

    NASA Astrophysics Data System (ADS)

    Zeghib, Nadir; Grucker, Daniel

    2001-09-01

    Dynamic nuclear polarization (DNP) of water protons was used to measure the relaxation time of lithium at very low magnetic field as a demonstration of the use of DNP for nuclei less abundant than water protons. Lithium (Li+) was chosen because it is an efficient treatment for manic-depressive illness, with an unknown action mechanism. After having recalled the theoretical basis of a three-spin system comprising two nuclei - the water proton of the solvent, the dissolved Li+ ion and the free electron of a free radical - we have developed a transient solution in order to optimize potential biological applications of Li DNP. The three-spin model has allowed computation of all the parameters of the system - the longitudinal relaxation rate per unit of free radical concentration, the dipolar and scalar part of the coupling between the nuclei and the electron, and the maximum signal enhancement achievable for both proton and lithium spins. All these measurements have been obtained solely through the detection of the proton resonance.

  18. Dependence of the time of the appearance of a Stark echo response on irreversible relaxation of a system

    NASA Astrophysics Data System (ADS)

    Akhmedshina, E. N.; Nefed'ev, L. A.; Garnaeva, G. I.

    2016-09-01

    The dependence of the time of the appearance of a Stark (gradient) echo response on the irreversible transverse relaxation time of a system in the nanosecond range and on the width of the excitation region of an inhomogeneously broadened line has been investigated. It has been shown that the use of nonresonant laser pulses with an artificially created spatial inhomogeneity makes it possible to determine the relaxation time in the nanosecond range from the time of the appearance of a Stark (gradient) echo response, which is a more accurate method than the method of determining the relaxation time from the decay of the intensity by varying time intervals of the exposure to inhomogeneous electromagnetic fields.

  19. Characterization of the uncertainty of divergence time estimation under relaxed molecular clock models using multiple loci.

    PubMed

    Zhu, Tianqi; Dos Reis, Mario; Yang, Ziheng

    2015-03-01

    Genetic sequence data provide information about the distances between species or branch lengths in a phylogeny, but not about the absolute divergence times or the evolutionary rates directly. Bayesian methods for dating species divergences estimate times and rates by assigning priors on them. In particular, the prior on times (node ages on the phylogeny) incorporates information in the fossil record to calibrate the molecular tree. Because times and rates are confounded, our posterior time estimates will not approach point values even if an infinite amount of sequence data are used in the analysis. In a previous study we developed a finite-sites theory to characterize the uncertainty in Bayesian divergence time estimation in analysis of large but finite sequence data sets under a strict molecular clock. As most modern clock dating analyses use more than one locus and are conducted under relaxed clock models, here we extend the theory to the case of relaxed clock analysis of data from multiple loci (site partitions). Uncertainty in posterior time estimates is partitioned into three sources: Sampling errors in the estimates of branch lengths in the tree for each locus due to limited sequence length, variation of substitution rates among lineages and among loci, and uncertainty in fossil calibrations. Using a simple but analogous estimation problem involving the multivariate normal distribution, we predict that as the number of loci ([Formula: see text]) goes to infinity, the variance in posterior time estimates decreases and approaches the infinite-data limit at the rate of 1/[Formula: see text], and the limit is independent of the number of sites in the sequence alignment. We then confirmed the predictions by using computer simulation on phylogenies of two or three species, and by analyzing a real genomic data set for six primate species. Our results suggest that with the fossil calibrations fixed, analyzing multiple loci or site partitions is the most effective way

  20. Time constant of defect relaxation in ion-irradiated 3C-SiC

    SciTech Connect

    Wallace, J. B.; Bayu Aji, L. B.; Kucheyev, S. O.; Shao, L.

    2015-05-18

    Above room temperature, the buildup of radiation damage in SiC is a dynamic process governed by the mobility and interaction of ballistically generated point defects. Here, we study the dynamics of radiation defects in 3C-SiC bombarded at 100 °C with 500 keV Ar ions, with the total ion dose split into a train of equal pulses. Damage–depth profiles are measured by ion channeling for a series of samples irradiated under identical conditions except for different durations of the passive part of the beam cycle. Results reveal an effective defect relaxation time constant of ∼3 ms (for second order kinetics) and a dynamic annealing efficiency of ∼40% for defects in both Si and C sublattices. This demonstrates a crucial role of dynamic annealing at elevated temperatures and provides evidence of the strong coupling of defect accumulation processes in the two sublattices of 3C-SiC.

  1. Effects of the individual particle relaxation time on superspin glass dynamics

    NASA Astrophysics Data System (ADS)

    Andersson, Mikael Svante; De Toro, Jose Angel; Lee, Su Seong; Normile, Peter S.; Nordblad, Per; Mathieu, Roland

    2016-02-01

    The low temperature dynamic magnetic properties of two dense magnetic nanoparticle assemblies with similar superspin glass transition temperatures Tg˜140 K are compared. The two samples are made from batches of 6 and 8 nm monodisperse γ -Fe2O3 nanoparticles, respectively. The properties of the individual particles are extracted from measurements on reference samples where the particles have been covered with a thick silica coating. The blocking temperatures of these dilute assemblies are found at 12.5 K for the 6 nm particles and at 35 K for the 8 nm particles, which implies different anisotropy energy barriers of the individual particles and vastly different temperature evolution of their relaxation times. The results of the measurements on the concentrated particle assemblies suggest a strong influence of the particle energy barrier on the details of the aging dynamics, memory behavior, and apparent superspin dimensionality of the particles.

  2. Multiple-relaxation-time lattice Boltzmann method for immiscible fluids at high Reynolds numbers.

    PubMed

    Fakhari, Abbas; Lee, Taehun

    2013-02-01

    The lattice Boltzmann method for immiscible multiphase flows with large density ratio is extended to high Reynolds number flows using a multiple-relaxation-time (MRT) collision operator, and its stability and accuracy are assessed by simulating the Kelvin-Helmholtz instability. The MRT model is successful at damping high-frequency oscillations in the kinetic energy emerging from traveling waves generated by the inclusion of curvature. Numerical results are shown to be in good agreement with prior studies using adaptive mesh refinement techniques applied to the Navier-Stokes equations. Effects of viscosity and surface tension, as well as density ratio, are investigated in terms of the Reynolds and Weber numbers. It is shown that increasing the Reynolds number results in a more chaotic interface evolution and eventually shattering of the interface, while surface tension is shown to have a stabilizing effect.

  3. Pinch-off dynamics, extensional viscosity and relaxation time of dilute and ultradilute aqueous polymer solutions

    NASA Astrophysics Data System (ADS)

    Biagioli, Madeleine; Dinic, Jelena; Jimenez, Leidy Nallely; Sharma, Vivek

    Free surface flows and drop formation processes present in printing, jetting, spraying, and coating involve the development of columnar necks that undergo spontaneous surface-tension driven instability, thinning, and pinch-off. Stream-wise velocity gradients that arise within the thinning neck create and extensional flow field, which induces micro-structural changes within complex fluids that contribute elastic stresses, changing the thinning and pinch-off dynamics. In this contribution, we use dripping-onto-substrate (DoS) extensional rheometry technique for visualization and analysis of the pinch-off dynamics of dilute and ultra-dilute aqueous polyethylene oxide (PEO) solutions. Using a range of molecular weights, we study the effect of both elasticity and finite extensibility. Both effective relaxation time and the transient extensional viscosity are found to be strongly concentration-dependent even for highly dilute solutions.

  4. Equilibrium distributions and relaxation times in gaslike economic models: An analytical derivation

    NASA Astrophysics Data System (ADS)

    Calbet, Xavier; López, José-Luis; López-Ruiz, Ricardo

    2011-03-01

    A step-by-step procedure to derive analytically the exact dynamical evolution equations of the probability density functions (PDFs) of well-known kinetic wealth exchange economic models is shown. This technique gives a dynamical insight into the evolution of the PDF, for example, allowing the calculation of its relaxation times. Their equilibrium PDFs can also be calculated by finding its stationary solutions. This gives as a result an integro-differential equation, which can be solved analytically in some cases and numerically in others. This should provide some guidance into the type of PDFs that can be derived from particular economic agent exchange rules or, for that matter, any other kinetic model of gases with particular collision physics.

  5. T2 relaxation time correlates of face recognition deficits in temporal lobe epilepsy.

    PubMed

    Bengner, Thomas; Siemonsen, Susanne; Stodieck, Stefan; Fiehler, Jens

    2008-11-01

    This study explored structural correlates of immediate and delayed face recognition in 22 nonsurgical patients with nonlesional, unilateral mesial temporal lobe epilepsy (TLE, 10 left/12 right). We measured T2 relaxation time bilaterally in the hippocampus, the amygdala, and the fusiform gyrus. Apart from raised T2 values in the ipsilateral hippocampus, we found increased T2 values in the ipsilateral amygdala. Patients with right TLE exhibited impaired face recognition as a result of a decrease from immediate to delayed recognition. Higher T2 values in the right than left fusiform gyrus or hippocampus were related to worse immediate face recognition, but did not correlate with 24-hour face recognition. These preliminary results indicate that structural changes in the fusiform gyrus and hippocampus may influence immediate face recognition deficits, but have no linear influence on long-term face recognition in TLE. We suggest that long-term face recognition depends on a right hemispheric network encompassing structures outside the temporal lobe.

  6. A multiple relaxation time extension of the constant speed kinetic model

    NASA Astrophysics Data System (ADS)

    Zadehgol, Abed; Ashrafizaadeh, Mahmud

    2016-02-01

    In this work, a multiple relaxation time (MRT) extension of the recently introduced constant speed kinetic model (CSKM) is proposed. The CSKM, which is an entropic kinetic model and based on unconventional entropies of Burg and Tssalis, was introduced in [A. Zadehgol and M. Ashrafizaadeh, J. Comput. Phys. 274, 803 (2014)]; [A. Zadehgol Phys. Rev. E 91, 063311 (2015)] as an extension of the model of Boghosian et al. [Phys. Rev. E 68, 025103 (2003)] in the limit of fixed speed continuous velocities. The present extension improves the stability of the previous models at very high Reynolds numbers, while allowing for a more convenient orthogonal lattice. The model is verified by solving the following benchmark problems: (i) the lid driven square cavity and (ii) the Kelvin-Helmholtz instability of thin shear layers in a doubly periodic square domain.

  7. Mouse Activity across Time Scales: Fractal Scenarios

    PubMed Central

    Lima, G. Z. dos Santos; Lobão-Soares, B.; do Nascimento, G. C.; França, Arthur S. C.; Muratori, L.; Ribeiro, S.; Corso, G.

    2014-01-01

    In this work we devise a classification of mouse activity patterns based on accelerometer data using Detrended Fluctuation Analysis. We use two characteristic mouse behavioural states as benchmarks in this study: waking in free activity and slow-wave sleep (SWS). In both situations we find roughly the same pattern: for short time intervals we observe high correlation in activity - a typical 1/f complex pattern - while for large time intervals there is anti-correlation. High correlation of short intervals ( to : waking state and to : SWS) is related to highly coordinated muscle activity. In the waking state we associate high correlation both to muscle activity and to mouse stereotyped movements (grooming, waking, etc.). On the other side, the observed anti-correlation over large time scales ( to : waking state and to : SWS) during SWS appears related to a feedback autonomic response. The transition from correlated regime at short scales to an anti-correlated regime at large scales during SWS is given by the respiratory cycle interval, while during the waking state this transition occurs at the time scale corresponding to the duration of the stereotyped mouse movements. Furthermore, we find that the waking state is characterized by longer time scales than SWS and by a softer transition from correlation to anti-correlation. Moreover, this soft transition in the waking state encompass a behavioural time scale window that gives rise to a multifractal pattern. We believe that the observed multifractality in mouse activity is formed by the integration of several stereotyped movements each one with a characteristic time correlation. Finally, we compare scaling properties of body acceleration fluctuation time series during sleep and wake periods for healthy mice. Interestingly, differences between sleep and wake in the scaling exponents are comparable to previous works regarding human heartbeat. Complementarily, the nature of these sleep-wake dynamics could lead to a better

  8. Nuclear Spin-Lattice Relaxation Times from Continuous Wave NMR Spectroscopy.

    ERIC Educational Resources Information Center

    Wooten, Jan B.; And Others

    1979-01-01

    The experiment described, suitable for undergraduate physical chemistry laboratories, illustrates the general principles of relaxation and introduces the nmr concepts of saturation and spin-inversion. (BB)

  9. Dielectric relaxation studies of binary mixture of β-picoline and methanol using time domain reflectometry at different temperatures

    NASA Astrophysics Data System (ADS)

    Trivedi, C. M.; Rana, V. A.; Hudge, P. G.; Kumbharkhane, A. C.

    2016-08-01

    Complex permittivity spectra of binary mixtures of varying concentrations of β-picoline and Methanol (MeOH) have been obtained using time domain reflectometry (TDR) technique over frequency range 10 MHz to 25 GHz at 283.15, 288.15, 293.15 and 298.15 K temperatures. The dielectric relaxation parameters namely static permittivity (ɛ0), high frequency limit permittivity (ɛ∞1) and the relaxation time (τ) were determined by fitting complex permittivity data to the single Debye/Cole-Davidson model. Complex nonlinear least square (CNLS) fitting procedure was carried out using LEVMW software. The excess permittivity (ɛ0E) and the excess inverse relaxation time (1/τ)E which contain information regarding molecular structure and interaction between polar-polar liquids were also determined. From the experimental data, parameters such as effective Kirkwood correlation factor (geff), Bruggeman factor (fB) and some thermo dynamical parameters have been calculated. Excess parameters were fitted to the Redlich-Kister polynomial equation. The values of static permittivity and relaxation time increase nonlinearly with increase in the mol-fraction of MeOH at all temperatures. The values of excess static permittivity (ɛ0E) and the excess inverse relaxation time (1/τ)E are negative for the studied β-picoline — MeOH system at all temperatures.

  10. On resonance phase alternated CWFP sequences for rapid and simultaneous measurement of relaxation times.

    PubMed

    Monaretto, Tatiana; Andrade, Fabiana Diuk; Moraes, Tiago Bueno; Souza, Andre Alves; deAzevedo, Eduardo Ribeiro; Colnago, Luiz Alberto

    2015-10-01

    T1 and T2 relaxation times have been frequently used as probes for physical-chemical properties in several time-domain NMR applications (TD-NMR) such as food, polymers and petroleum industries. T2 measurements are usually achieved using the traditional Carr-Purcell-Meiboom-Gill (CPMG) pulse sequence because it is a fast and robust method. On the other hand, the traditional methods for determining T1, i.e., inversion and saturation recovery, are time-consuming, driving several authors to develop rapid 1D and 2D methods to obtain T1 and T2 or T1/T2 ratio. However, these methods usually require sophisticated processing and/or high signal to noise ratio (SNR). This led us to develop simple methods for rapid and simultaneous determination of T1 and T2 using Continuous Wave Free Precession (CWFP) and Carr-Purcell Continuous Wave Free Precession (CP-CWFP) pulse sequences. Nevertheless, a drawback of these sequences is that they require specific adjustment of the frequency offset or the time interval between pulses (Tp). In this paper we present an alternative form of these sequences, named CWFPx-x, CP-CWFPx-x, where a train of π/2 pulses with phases alternated by π enable performing the experiments on-resonance and independently of Tp, when Tprelaxation times are determined using the magnitude of the signals after the first pulse |M0| and in the steady-state |Mss|, as well as the exponential time constant T(∗) to reach the steady-state regime, as in conventional CWFP. CP-CWFPx-x shows the highest dynamic range to measure T(∗) among CWFP sequences and, therefore, is the best technique to measure T1 and T2 since it is less susceptible to SNR and can be performed for any T1/T2 ratio. PMID:26363504

  11. On resonance phase alternated CWFP sequences for rapid and simultaneous measurement of relaxation times

    NASA Astrophysics Data System (ADS)

    Monaretto, Tatiana; Andrade, Fabiana Diuk; Moraes, Tiago Bueno; Souza, Andre Alves; deAzevedo, Eduardo Ribeiro; Colnago, Luiz Alberto

    2015-10-01

    T1 and T2 relaxation times have been frequently used as probes for physical-chemical properties in several time-domain NMR applications (TD-NMR) such as food, polymers and petroleum industries. T2 measurements are usually achieved using the traditional Carr-Purcell-Meiboom-Gill (CPMG) pulse sequence because it is a fast and robust method. On the other hand, the traditional methods for determining T1, i.e., inversion and saturation recovery, are time-consuming, driving several authors to develop rapid 1D and 2D methods to obtain T1 and T2 or T1/T2 ratio. However, these methods usually require sophisticated processing and/or high signal to noise ratio (SNR). This led us to develop simple methods for rapid and simultaneous determination of T1 and T2 using Continuous Wave Free Precession (CWFP) and Carr-Purcell Continuous Wave Free Precession (CP-CWFP) pulse sequences. Nevertheless, a drawback of these sequences is that they require specific adjustment of the frequency offset or the time interval between pulses (Tp). In this paper we present an alternative form of these sequences, named CWFPx-x, CP-CWFPx-x, where a train of π/2 pulses with phases alternated by π enable performing the experiments on-resonance and independently of Tp, when Tp < T2∗. Moreover, a CPMG type sequence with π/2 refocusing pulses shows similar results to CP-CWFP when the pulses are alternated between y and -y axis, CPMG90y-y. In these approaches, the relaxation times are determined using the magnitude of the signals after the first pulse |M0| and in the steady-state |Mss|, as well as the exponential time constant T∗ to reach the steady-state regime, as in conventional CWFP. CP-CWFPx-x shows the highest dynamic range to measure T∗ among CWFP sequences and, therefore, is the best technique to measure T1 and T2 since it is less susceptible to SNR and can be performed for any T1/T2 ratio.

  12. Measuring non-radiative relaxation time of fluorophores with biomedical applications by intensity-modulated laser-induced photoacoustic effect

    PubMed Central

    Soroushian, Behrouz; Yang, Xinmai

    2011-01-01

    Modulated tone-burst light was employed to measure non-radiative relaxation time of fluorophores with biomedical importance through photoacoustic effect. Non-radiative relaxation time was estimated through the frequency dependence of photoacoustic signal amplitude. Experiments were performed on solutions of new indocyanine green (IR-820), which is a near infrared dye and has biomedical applications, in two different solvents (water and dimethyl sulfoxide (DMSO)). A 1.5 times slower non-radiative relaxation for the solution of dye in DMSO was observed comparing with the aqueous solution. This result agrees well with general finding that non-radiative relaxation of molecules in triplet state depends on viscosity of solvents in which they are dissolved. Measurements of the non-radiative relaxation time can be used as a new source of contrast mechanism in photoacoustic imaging technique. The proposed method has potential applications such as imaging tissue oxygenation and mapping of other chemophysical differences in microenvironment of exogenous biomarkers. PMID:22025981

  13. Strong anisotropy of momentum-relaxation time induced by intermolecular vibrations of single-crystal organic semiconductors

    NASA Astrophysics Data System (ADS)

    Ishii, Hiroyuki; Kobayashi, Nobuhiko; Hirose, Kenji

    2013-11-01

    We present a theoretical study of the relationships between intermolecular vibrations and anisotropic transport properties of pentacene and rubrene single-crystal organic semiconductors. Using our wave-packet approach based on the Kubo formula beyond the effective-mass approximation with the assumption of an isotropic momentum-relaxation time, we find that the intermolecular vibrations induce a strong anisotropic momentum-relaxation time but moderate the anisotropy of carrier mobility much more than that of the effective mass. This clarifies the mechanism behind the deviation of the anisotropic ratio of mobility from that of effective mass observed in angle-resolved photoelectron spectroscopy experiments.

  14. Soil and litter phosphorus-31 nuclear magnetic resonance spectroscopy: extractants, metals, and phosphorus relaxation times.

    PubMed

    Cade-Menun, B J; Liu, C W; Nunlist, R; McColl, J G

    2002-01-01

    Phosphorus-31 nuclear magnetic resonance (NMR) spectroscopy is an excellent tool with which to study soil organic P, allowing quantitative, comparative analysis of P forms. However, for 31P NMR to be tative, all peaks must be completely visible, and in their correct relative proportions. There must be no line broadening, and adequate delay times must be used to avoid saturation of peaks. The objective of this study was to examine the effects of extractants on delay times and peak saturation. Two samples (a forest litter and a mineral soil sample) and three extractants (0.25 M NaOH, NaOH plus Chelex (Bio-Rad Laboratories, Hercules, CA), and NaOH plus EDTA) were used to determine the differences in the concentration of P and cations solubilized by each extractant, and to measure spin-lattice (T1) relaxation times of P peaks in each extract. For both soil and litter, NaOH-Chelex extracted the lowest concentrations of P. For the litter sample, T1 values were short for all extractants due to the high Fe concentration remaining after extraction. For the soil sample, there were noticeable differences among the extractants. The NaOH-Chelex sample had less Fe and Mn remaining in solution after extraction than the other extractants, and the longest delay times used in the study, 6.4 s, were not long enough for quantitative analysis. Delay times of 1.5 to 2 s for the NaOH and NaOH-EDTA were adequate. Line broadening was highest in the NaOH extracts, which had the highest concentration of Fe. On the basis of these results, recommendations for future analyses of soil and litter samples by solution 31P NMR spectroscopy include: careful selection of an extractant; measurement of paramagnetic ions extracted with P; use of appropriate delay times and the minimum number of scans; and measurement of T1 values whenever possible.

  15. Lineshape theory of pigment-protein complexes: How the finite relaxation time of nuclei influences the exciton relaxation-induced lifetime broadening.

    PubMed

    Dinh, Thanh-Chung; Renger, Thomas

    2016-07-21

    In pigment-protein complexes, often the excited states are partially delocalized and the exciton-vibrational coupling in the basis of delocalized states contains large diagonal and small off-diagonal elements. This inequality may be used to introduce potential energy surfaces (PESs) of exciton states and to treat the inter-PES coupling in Markov and secular approximations. The resulting lineshape function consists of a Lorentzian peak that is broadened by the finite lifetime of the exciton states caused by the inter-PES coupling and a vibrational sideband that results from the mutual displacement of the excitonic PESs with respect to that of the ground state. So far analytical expressions have been derived that relate the exciton relaxation-induced lifetime broadening to the Redfield [T. Renger and R. A. Marcus, J. Chem. Phys. 116, 9997 (2002)] or modified Redfield [M. Schröder, U. Kleinekathöfer, and M. Schreiber, J. Chem. Phys. 124, 084903 (2006)] rate constants of exciton relaxation, assuming that intra-PES nuclear relaxation is fast compared to inter-PES transfer. Here, we go beyond this approximation and provide an analytical expression, termed Non-equilibrium Modified Redfield (NeMoR) theory, for the lifetime broadening that takes into account the finite nuclear relaxation time. In an application of the theory to molecular dimers, we find that, for a widely used experimental spectral density of the exciton-vibrational coupling of pigment-protein complexes, the NeMoR spectrum at low-temperatures (T < 150 K) is better approximated by Redfield than by modified Redfield theory. At room temperature, the lifetime broadening obtained with Redfield theory underestimates the NeMoR broadening, whereas modified Redfield theory overestimates it by a similar amount. A fortuitous error compensation in Redfield theory is found to explain the good performance of this theory at low temperatures. Since steady state spectra of PPCs are often measured at low temperatures

  16. Lineshape theory of pigment-protein complexes: How the finite relaxation time of nuclei influences the exciton relaxation-induced lifetime broadening

    NASA Astrophysics Data System (ADS)

    Dinh, Thanh-Chung; Renger, Thomas

    2016-07-01

    In pigment-protein complexes, often the excited states are partially delocalized and the exciton-vibrational coupling in the basis of delocalized states contains large diagonal and small off-diagonal elements. This inequality may be used to introduce potential energy surfaces (PESs) of exciton states and to treat the inter-PES coupling in Markov and secular approximations. The resulting lineshape function consists of a Lorentzian peak that is broadened by the finite lifetime of the exciton states caused by the inter-PES coupling and a vibrational sideband that results from the mutual displacement of the excitonic PESs with respect to that of the ground state. So far analytical expressions have been derived that relate the exciton relaxation-induced lifetime broadening to the Redfield [T. Renger and R. A. Marcus, J. Chem. Phys. 116, 9997 (2002)] or modified Redfield [M. Schröder, U. Kleinekathöfer, and M. Schreiber, J. Chem. Phys. 124, 084903 (2006)] rate constants of exciton relaxation, assuming that intra-PES nuclear relaxation is fast compared to inter-PES transfer. Here, we go beyond this approximation and provide an analytical expression, termed Non-equilibrium Modified Redfield (NeMoR) theory, for the lifetime broadening that takes into account the finite nuclear relaxation time. In an application of the theory to molecular dimers, we find that, for a widely used experimental spectral density of the exciton-vibrational coupling of pigment-protein complexes, the NeMoR spectrum at low-temperatures (T < 150 K) is better approximated by Redfield than by modified Redfield theory. At room temperature, the lifetime broadening obtained with Redfield theory underestimates the NeMoR broadening, whereas modified Redfield theory overestimates it by a similar amount. A fortuitous error compensation in Redfield theory is found to explain the good performance of this theory at low temperatures. Since steady state spectra of PPCs are often measured at low temperatures

  17. Lineshape theory of pigment-protein complexes: How the finite relaxation time of nuclei influences the exciton relaxation-induced lifetime broadening.

    PubMed

    Dinh, Thanh-Chung; Renger, Thomas

    2016-07-21

    In pigment-protein complexes, often the excited states are partially delocalized and the exciton-vibrational coupling in the basis of delocalized states contains large diagonal and small off-diagonal elements. This inequality may be used to introduce potential energy surfaces (PESs) of exciton states and to treat the inter-PES coupling in Markov and secular approximations. The resulting lineshape function consists of a Lorentzian peak that is broadened by the finite lifetime of the exciton states caused by the inter-PES coupling and a vibrational sideband that results from the mutual displacement of the excitonic PESs with respect to that of the ground state. So far analytical expressions have been derived that relate the exciton relaxation-induced lifetime broadening to the Redfield [T. Renger and R. A. Marcus, J. Chem. Phys. 116, 9997 (2002)] or modified Redfield [M. Schröder, U. Kleinekathöfer, and M. Schreiber, J. Chem. Phys. 124, 084903 (2006)] rate constants of exciton relaxation, assuming that intra-PES nuclear relaxation is fast compared to inter-PES transfer. Here, we go beyond this approximation and provide an analytical expression, termed Non-equilibrium Modified Redfield (NeMoR) theory, for the lifetime broadening that takes into account the finite nuclear relaxation time. In an application of the theory to molecular dimers, we find that, for a widely used experimental spectral density of the exciton-vibrational coupling of pigment-protein complexes, the NeMoR spectrum at low-temperatures (T < 150 K) is better approximated by Redfield than by modified Redfield theory. At room temperature, the lifetime broadening obtained with Redfield theory underestimates the NeMoR broadening, whereas modified Redfield theory overestimates it by a similar amount. A fortuitous error compensation in Redfield theory is found to explain the good performance of this theory at low temperatures. Since steady state spectra of PPCs are often measured at low temperatures

  18. Picosecond-time-resolved studies of nonradiative relaxation in ruby and alexandrite

    SciTech Connect

    Gayen, S.K.; Wang, W.B.; Petricevic, V.; Alfano, R.R.

    1985-01-01

    Dynamics of the nonradiative transitions between the /sup 4/T/sub 2/ pump band and the /sup 2/E storage level of the Cr/sup 3 +/ ion in ruby and alexandrite crystals is studied using the picosecond excite-and-probe absorption technique. A 527-nm picosecond pulse excites the /sup 4/T/sub 2/ state of the Cr/sup 3 +/ ion, and an infrared picosecond probe pulse monitors the subsequent growth and decay of population in the excited states as a function of pump-probe delay. An upper limit of 7 ps is determined for the nonradiative lifetime of the /sup 4/T/sub 2/ state in ruby. A vibrational relaxation time of 25 ps for the /sup 4/T/sub 2/ band in alexandrite is estimated. The time to attain thermal equilibrium population between the /sup 2/E and /sup 4/T/sub 2/ levels of alexandrite following excitation of /sup 4/T/sub 2/ band is estimated to be approx. 100 ps.

  19. T2 relaxation time post febrile status epilepticus predicts cognitive outcome.

    PubMed

    Barry, Jeremy M; Choy, ManKin; Dube, Celine; Robbins, Ashlee; Obenaus, Andre; Lenck-Santini, Pierre Pascal; Scott, Rod C; Baram, Tallie Z; Holmes, Gregory L

    2015-07-01

    Evidence from animal models and patient data indicates that febrile status epilepticus (FSE) in early development can result in permanently diminished cognitive abilities. To understand the variability in cognitive outcome following FSE, we used MRI to measure dynamic brain metabolic responses to the induction of FSE in juvenile rats. We then compared these measurements to the ability to learn an active avoidance spatial task weeks later. T2 relaxation times were significantly lower in FSE rats that were task learners in comparison to FSE non-learners. While T2 time in whole brain held the greatest predictive power, T2 in hippocampus and basolateral amygdala were also excellent predictors. These signal differences in response to FSE indicate that rats that fail to meet metabolic and oxygen demand are more likely to develop spatial cognition deficits. Place cells from FSE non-learners had significantly larger firing fields and higher in-field firing rate than FSE learners and control animals and imply increased excitability in the pyramidal cells of FSE non-learners. These findings suggest a mechanistic cause for the spatial memory deficits in active avoidance and are relevant to other acute neurological insults in early development where cognitive outcome is a concern. PMID:25939697

  20. Mouse activity across time scales: fractal scenarios.

    PubMed

    Lima, G Z dos Santos; Lobão-Soares, B; do Nascimento, G C; França, Arthur S C; Muratori, L; Ribeiro, S; Corso, G

    2014-01-01

    In this work we devise a classification of mouse activity patterns based on accelerometer data using Detrended Fluctuation Analysis. We use two characteristic mouse behavioural states as benchmarks in this study: waking in free activity and slowwave sleep (SWS). In both situations we find roughly the same pattern: for short time intervals we observe high correlation in activity--a typical 1/f complex pattern--while for large time intervals there is anti-correlation. High correlation of short intervals (0.01 s to 2 s: waking state and 0.01 s to 0.1 s: SWS) is related to highly coordinated muscle activity. In the waking state we associate high correlation both to muscle activity and to mouse stereotyped movements (grooming, waking, etc.). On the other side, the observed anti-correlation over large time scales (30 s to 300 s: waking state and 0.3 s to 5 s: SWS) during SWS appears related to a feedback autonomic response. The transition from correlated regime at short scales to an anti-correlated regime at large scales during SWS is given by the respiratory cycle interval, while during the waking state this transition occurs at the time scale corresponding to the duration of the stereotyped mouse movements. Furthermore, we find that the waking state is characterized by longer time scales than SWS and by a softer transition from correlation to anticorrelation. Moreover, this soft transition in the waking state encompass a behavioural time scale window that gives rise to a multifractal pattern. We believe that the observed multifractality in mouse activity is formed by the integration of several stereotyped movements each one with a characteristic time correlation. Finally, we compare scaling properties of body acceleration fluctuation time series during sleep and wake periods for healthy mice. Interestingly, differences between sleep and wake in the scaling exponents are comparable to previous works regarding human heartbeat. Complementarily, the nature of these sleep

  1. Global scale precipitation from monthly to centennial scales: empirical space-time scaling analysis, anthropogenic effects

    NASA Astrophysics Data System (ADS)

    de Lima, Isabel; Lovejoy, Shaun

    2016-04-01

    The characterization of precipitation scaling regimes represents a key contribution to the improved understanding of space-time precipitation variability, which is the focus here. We conduct space-time scaling analyses of spectra and Haar fluctuations in precipitation, using three global scale precipitation products (one instrument based, one reanalysis based, one satellite and gauge based), from monthly to centennial scales and planetary down to several hundred kilometers in spatial scale. Results show the presence - similarly to other atmospheric fields - of an intermediate "macroweather" regime between the familiar weather and climate regimes: we characterize systematically the macroweather precipitation temporal and spatial, and joint space-time statistics and variability, and the outer scale limit of temporal scaling. These regimes qualitatively and quantitatively alternate in the way fluctuations vary with scale. In the macroweather regime, the fluctuations diminish with time scale (this is important for seasonal, annual, and decadal forecasts) while anthropogenic effects increase with time scale. Our approach determines the time scale at which the anthropogenic signal can be detected above the natural variability noise: the critical scale is about 20 - 40 yrs (depending on the product, on the spatial scale). This explains for example why studies that use data covering only a few decades do not easily give evidence of anthropogenic changes in precipitation, as a consequence of warming: the period is too short. Overall, while showing that precipitation can be modeled with space-time scaling processes, our results clarify the different precipitation scaling regimes and further allow us to quantify the agreement (and lack of agreement) of the precipitation products as a function of space and time scales. Moreover, this work contributes to clarify a basic problem in hydro-climatology, which is to measure precipitation trends at decadal and longer scales and to

  2. The hippocampus, time, and memory across scales.

    PubMed

    Howard, Marc W; Eichenbaum, Howard

    2013-11-01

    A wealth of experimental studies with animals have offered insights about how neural networks within the hippocampus support the temporal organization of memories. These studies have revealed the existence of "time cells" that encode moments in time, much as the well-known "place cells" map locations in space. Another line of work inspired by human behavioral studies suggests that episodic memories are mediated by a state of temporal context that changes gradually over long time scales, up to at least a few thousand seconds. In this view, the "mental time travel" hypothesized to support the experience of episodic memory corresponds to a "jump back in time" in which a previous state of temporal context is recovered. We suggest that these 2 sets of findings could be different facets of a representation of temporal history that maintains a record at the last few thousand seconds of experience. The ability to represent long time scales comes at the cost of discarding precise information about when a stimulus was experienced--this uncertainty becomes greater for events further in the past. We review recent computational work that describes a mechanism that could construct such a scale-invariant representation. Taken as a whole, this suggests the hippocampus plays its role in multiple aspects of cognition by representing events embedded in a general spatiotemporal context. The representation of internal time can be useful across nonhippocampal memory systems.

  3. Revisiting spin-lattice relaxation time measurements for dilute spins in high-resolution solid-state NMR spectroscopy.

    PubMed

    Fu, Riqiang; Li, Jun; Cui, Jingyu; Peng, Xinhua

    2016-07-01

    Numerous nuclear magnetic resonance (NMR) measurements of spin-lattice relaxation times (T1S) for dilute spins such as (13)C have led to investigations of the motional dynamics of individual functional groups in solid materials. In this work, we revisit the Solomon equations and analyze how the heteronuclear cross relaxation between the dilute S (e.g. (13)C) and abundant I (e.g. (1)H) spins affects the measured T1S values in solid-state NMR in the absence of (1)H saturation during the recovery time. It is found theoretically that at the beginning of the S spin magnetization recovery, the existence of non-equilibrium I magnetization introduces the heteronuclear cross relaxation effect onto the recovery of the S spin magnetization and confirmed experimentally that such a heteronuclear cross relaxation effect results in the recovery overshoot phenomena for the dilute spins when T1S is on the same order of T1H, leading to inaccurate measurements of the T1S values. Even when T1S is ten times larger than T1H, the heteronuclear cross relaxation effect on the measured T1S values is still noticeable. Furthermore, this cross relaxation effect on recovery trajectory of the S spins can be manipulated and even suppressed by preparing the initial I and S magnetization, so as to obtain the accurate T1S values. A sample of natural abundance l-isoleucine powder has been used to demonstrate the T1S measurements and their corresponding measured T1C values under various experimental conditions. PMID:27187211

  4. Revisiting spin-lattice relaxation time measurements for dilute spins in high-resolution solid-state NMR spectroscopy.

    PubMed

    Fu, Riqiang; Li, Jun; Cui, Jingyu; Peng, Xinhua

    2016-07-01

    Numerous nuclear magnetic resonance (NMR) measurements of spin-lattice relaxation times (T1S) for dilute spins such as (13)C have led to investigations of the motional dynamics of individual functional groups in solid materials. In this work, we revisit the Solomon equations and analyze how the heteronuclear cross relaxation between the dilute S (e.g. (13)C) and abundant I (e.g. (1)H) spins affects the measured T1S values in solid-state NMR in the absence of (1)H saturation during the recovery time. It is found theoretically that at the beginning of the S spin magnetization recovery, the existence of non-equilibrium I magnetization introduces the heteronuclear cross relaxation effect onto the recovery of the S spin magnetization and confirmed experimentally that such a heteronuclear cross relaxation effect results in the recovery overshoot phenomena for the dilute spins when T1S is on the same order of T1H, leading to inaccurate measurements of the T1S values. Even when T1S is ten times larger than T1H, the heteronuclear cross relaxation effect on the measured T1S values is still noticeable. Furthermore, this cross relaxation effect on recovery trajectory of the S spins can be manipulated and even suppressed by preparing the initial I and S magnetization, so as to obtain the accurate T1S values. A sample of natural abundance l-isoleucine powder has been used to demonstrate the T1S measurements and their corresponding measured T1C values under various experimental conditions.

  5. Revisiting spin-lattice relaxation time measurements for dilute spins in high-resolution solid-state NMR spectroscopy

    NASA Astrophysics Data System (ADS)

    Fu, Riqiang; Li, Jun; Cui, Jingyu; Peng, Xinhua

    2016-07-01

    Numerous nuclear magnetic resonance (NMR) measurements of spin-lattice relaxation times (T1S) for dilute spins such as 13C have led to investigations of the motional dynamics of individual functional groups in solid materials. In this work, we revisit the Solomon equations and analyze how the heteronuclear cross relaxation between the dilute S (e.g. 13C) and abundant I (e.g. 1H) spins affects the measured T1S values in solid-state NMR in the absence of 1H saturation during the recovery time. It is found theoretically that at the beginning of the S spin magnetization recovery, the existence of non-equilibrium I magnetization introduces the heteronuclear cross relaxation effect onto the recovery of the S spin magnetization and confirmed experimentally that such a heteronuclear cross relaxation effect results in the recovery overshoot phenomena for the dilute spins when T1S is on the same order of T1H, leading to inaccurate measurements of the T1S values. Even when T1S is ten times larger than T1H, the heteronuclear cross relaxation effect on the measured T1S values is still noticeable. Furthermore, this cross relaxation effect on recovery trajectory of the S spins can be manipulated and even suppressed by preparing the initial I and S magnetization, so as to obtain the accurate T1S values. A sample of natural abundance L-isoleucine powder has been used to demonstrate the T1S measurements and their corresponding measured T1C values under various experimental conditions.

  6. Multiple time scales is well named.

    PubMed

    Gibbon, J

    1999-03-01

    Staddon and Higa's article is a critique of scalar expectancy theory, and a proposed alternative, multiple time scales. The critique is generally flawed, both factually and logically. The alternative is bewildering in its flexibility, opaque in its quantitative description, and never addressed to real data.

  7. Structure of Student Time Management Scale (STMS)

    ERIC Educational Resources Information Center

    Balamurugan, M.

    2013-01-01

    With the aim of constructing a Student Time Management Scale (STMS), the initial version was administered and data were collected from 523 standard eleventh students. (Mean age = 15.64). The data obtained were subjected to Reliability and Factor analysis using PASW Statistical software version 18. From 42 items 14 were dropped, resulting in the…

  8. Relaxing the closure assumption in single-season occupancy models: staggered arrival and departure times

    USGS Publications Warehouse

    Kendall, William L.; Hines, James E.; Nichols, James D.; Grant, Evan H. Campbell

    2013-01-01

    Occupancy statistical models that account for imperfect detection have proved very useful in several areas of ecology, including species distribution and spatial dynamics, disease ecology, and ecological responses to climate change. These models are based on the collection of multiple samples at each of a number of sites within a given season, during which it is assumed the species is either absent or present and available for detection while each sample is taken. However, for some species, individuals are only present or available for detection seasonally. We present a statistical model that relaxes the closure assumption within a season by permitting staggered entry and exit times for the species of interest at each site. Based on simulation, our open model eliminates bias in occupancy estimators and in some cases increases precision. The power to detect the violation of closure is high if detection probability is reasonably high. In addition to providing more robust estimation of occupancy, this model permits comparison of phenology across sites, species, or years, by modeling variation in arrival or departure probabilities. In a comparison of four species of amphibians in Maryland we found that two toad species arrived at breeding sites later in the season than a salamander and frog species, and departed from sites earlier.

  9. Multiple-relaxation-time lattice Boltzmann simulations of turbulent channel and pipe flows.

    NASA Astrophysics Data System (ADS)

    Opadrishta, Harish; Peng, Cheng; Wang, Lian-Ping

    2015-11-01

    The mesoscopic Lattice Boltzmann method (LBM) has become a reliable alternative for solving incompressible turbulent flows. However, the statistics of a simulated turbulent flow near a curved boundary may deviate from the physical rotational invariance (RI) of lattice coordinates. The main objective of this study is to compare the effects of different lattice models on the simulation results of turbulent flows, and explore ways to restore RI near a curved boundary. We will apply D3Q19 and D3Q27 multiple-relaxation-time LBM models to simulate turbulent pipe and channel flows. The statistics of the simulated flows are examined to quantify the nature of departures from RI. To help understand whether the departure is originated from the bounce-back scheme at the solid wall, we will perform simulations of a turbulent channel flow with walls orientated at an angle from the lattice grid, and test the use of an overset lattice grid near a pipe wall. The Chapman-Enskog analysis of these models will be performed to probe RI errors near a boundary. Our goal is to eventually perform an accurate direct numerical simulation of a turbulent pipe flow, and compare the results to previous simulations based on the Navier-Stokes equations.

  10. [Time-resolved optical studies of charge relaxation and charge transfer at electrode interfaces

    SciTech Connect

    Not Available

    1992-01-01

    Key components were identified in a quantitative model of carrier relaxation in semiconductor electrodes: nonlinear aspects of nonradiative and radiative recombination, effect of space charge field on carrier dynamics, self-absorption effects in direct gas semiconductors, and influence of surface state population kinetics on charge carrier recombination. For CdSe, the first three are operative (no direct proof of the last one). A realistic kinetic model for carrier recombination in the bulk of CdSe was used which includes important nonlinear effects, both radiative and nonradiative. The change in interfacial recombination velocity with the chemical nature of the sinterface was studied (n-CdSe/silane interfaces). Temperature effect (278 to 328 K) on fluorescence decay of n-CdSe in contact with 0.5 M KOH was found to be weak. An analytical solution was obtained for time-resolved fluoresence from electrodes under potential bias, and is being tested. Fluorescence work on a different material, CdS, indicate different recombination kinetics; this material was used to directly pump an optical transition of a surface state.

  11. [Time-resolved optical studies of charge relaxation and charge transfer at electrode interfaces

    SciTech Connect

    Not Available

    1992-12-31

    Key components were identified in a quantitative model of carrier relaxation in semiconductor electrodes: nonlinear aspects of nonradiative and radiative recombination, effect of space charge field on carrier dynamics, self-absorption effects in direct gas semiconductors, and influence of surface state population kinetics on charge carrier recombination. For CdSe, the first three are operative (no direct proof of the last one). A realistic kinetic model for carrier recombination in the bulk of CdSe was used which includes important nonlinear effects, both radiative and nonradiative. The change in interfacial recombination velocity with the chemical nature of the sinterface was studied (n-CdSe/silane interfaces). Temperature effect (278 to 328 K) on fluorescence decay of n-CdSe in contact with 0.5 M KOH was found to be weak. An analytical solution was obtained for time-resolved fluoresence from electrodes under potential bias, and is being tested. Fluorescence work on a different material, CdS, indicate different recombination kinetics; this material was used to directly pump an optical transition of a surface state.

  12. Proton relaxation times and interstitial fluid pressure in human melanoma xenografts.

    PubMed Central

    Lyng, H.; Tufto, I.; Skretting, A.; Rofstad, E. K.

    1997-01-01

    The interstitial fluid pressure (IFP) and the proton spin-lattice and spin-spin relaxation times (T1 and T2) of some experimental tumours have been shown to be related to tumour water content. These observations have led to the hypothesis that magnetic resonance imaging (MRI) might be a clinically useful non-invasive method for assessment of tumour IFP. The purpose of the work reported here was to examine the general validity of this hypothesis. R-18 human melanoma xenografts grown intradermally in Balb/c nu/nu mice were used as the tumour model system. Median T1 and T2 were determined by spin-echo MRI using a 1.5-T clinical whole-body tomograph. IFP was measured using the wick-in-needle technique. No correlation was found between tumour IFP and fractional tumour water content. Moreover, there was no correlation between median T1 or T2 and IFP, suggesting that proton T1 and T2 values determined by MRI cannot be used clinically to assess tumour IFP and thereby to predict the uptake of macromolecular therapeutic agents. PMID:9010023

  13. Effects of electric field on the entropy, viscosity, relaxation time, and glass-formation.

    PubMed

    Johari, G P

    2013-04-21

    By using the known formalism for the effect of an externally applied electric field, E, on thermodynamics of a dielectric material, we calculated the field-induced configurational entropy factor, ΔSconf (E)/E(2), of 50 dipolar liquids, including those whose static permittivity, εs, decreases on cooling. The field induced change, ΔSconf (E), is found to be experimentally detectable only when E is on the order of 10(5) V∕cm, a value less than the dielectric breakdown field strength of some liquids but in the range of nonlinear dielectric response. We argue that the dielectric response is formally nonlinear already for E > 0, and then show that the difference between the Langevin-function and the extrapolated linear response is < 0.15% for E in the 10(5) V∕cm range. Therefore, such high E values may be used to estimate ΔSconf (E). We conclude that (i) for E in the 10(5) V∕cm range, ΔSconf (E) is high enough to produce a measurable change in the viscosity and relaxation time of some ultraviscous liquids with prominent dipolar interactions, thereby changing their glass formation temperature, and (ii) application of E would reversibly transform, isothermally, some liquids to glass, and transform some glasses to liquid. Finally, we suggest that the effect of E can be used to determine the merits of the models for non-Arrhenius kinetics.

  14. Laboratory observations of time-dependent frictional strengthening and stress relaxation in natural and synthetic fault gouges

    NASA Astrophysics Data System (ADS)

    Carpenter, B. M.; Ikari, M. J.; Marone, C.

    2016-02-01

    Interseismic recovery of fault strength (healing) following earthquake failure is a fundamental requirement of the seismic cycle and likely plays a key role in determining the stability and slip behavior of tectonic faults. We report on laboratory measurements of time- and slip-dependent frictional strengthening for natural and synthetic gouges to evaluate the role of mineralogy in frictional strengthening. We performed slide-hold-slide (SHS) shearing experiments on nine natural fault gouges and eight synthetic gouges at conditions of 20 MPa normal stress, 100% relative humidity (RH), large shear strain (~15), and room temperature. Phyllosilicate-rich rocks show the lowest rates of frictional strengthening. Samples rich in quartz and feldspar exhibit intermediate rates of frictional strengthening, and calcite-rich gouges show the largest values. Our results show that (1) the rates of frictional strengthening and creep relaxation scale with frictional strength, (2) phyllosilicate-rich fault gouges have low strength and healing characteristics that promote stable, aseismic creep, (3) most natural fault gouges exhibit intermediate rates of frictional strengthening, consistent with a broad range of fault slip behaviors, and (4) calcite-rich fault rocks show the highest rates of frictional strengthening, low values of dilation upon reshear, and high frictional strengths, all of which would promote seismogenic behavior.

  15. Effects of spin diffusion on electron spin relaxation time measured with a time-resolved microscopic photoluminescence technique

    SciTech Connect

    Ikeda, Kazuhiro Kawaguchi, Hitoshi

    2015-02-07

    We performed measurements at room temperature for a GaAs/AlGaAs multiple quantum well grown on GaAs(110) using a time-resolved microscopic photoluminescence (micro-PL) technique to find what effects spin diffusion had on the measured electron spin relaxation time, τ{sub s}, and developed a method of estimating the spin diffusion coefficient, D{sub s}, using the measured data and the coupled drift-diffusion equations for spin polarized electrons. The spatial nonuniformities of τ{sub s} and the initial degree of electron spin polarization caused by the pump intensity distribution inside the focal spot were taken into account to explain the dependence of τ{sub s} on the measured spot size, i.e., a longer τ{sub s} for a smaller spot size. We estimated D{sub s} as ∼100 cm{sup 2}/s, which is similar to a value reported in the literature. We also provided a qualitative understanding on how spin diffusion lengthens τ{sub s} in micro-PL measurements.

  16. Structural relaxation dynamics and annealing effects of sodium silicate glass.

    PubMed

    Naji, Mohamed; Piazza, Francesco; Guimbretière, Guillaume; Canizarès, Aurélien; Vaills, Yann

    2013-05-01

    Here we report high-precision measurements of structural relaxation dynamics in the glass transition range at the intermediate and short length scale for a strong sodium silicate glass during long annealing times. We evidence for the first time the heterogeneous dynamics at the intermediate range order by probing the acoustic longitudinal frequency in the GHz region by Brillouin light scattering spectroscopy. Or, from in-situ Raman measurements, we show that relaxation is indeed homogeneous at the interatomic length scale. Our results show that the dynamics at the intermediate range order contains two distinct relaxation time scales, a fast and a slow component, differing by about a 10-fold factor below Tg and approaching to one another past the glass transition. The slow relaxation time agrees with the shear relaxation time, proving that Si-O bond breaking constitutes the primary control of structural relaxation at the intermediate range order.

  17. MRI of bone marrow in the distal radius: in vivo precision of effective transverse relaxation times

    NASA Technical Reports Server (NTRS)

    Grampp, S.; Majumdar, S.; Jergas, M.; Lang, P.; Gies, A.; Genant, H. K.

    1995-01-01

    The effective transverse relaxation time T2* is influenced by the presence of trabecular bone, and can potentially provide a measure of bone density as well as bone structure. We determined the in vivo precision of T2* in repeated bone marrow measurements. The T2* measurements of the bone marrow of the distal radius were performed twice within 2 weeks in six healthy young volunteers using a modified water-presaturated 3D Gradient-Recalled Acquisition at Steady State (GRASS) sequence with TE 7, 10, 12, 20, and 30; TR 67; flip angle (FA) 90 degrees. An axial volume covering a length of 5.6 cm in the distal radius was measured. Regions of interest (ROIs) were determined manually and consisted of the entire trabecular bone cross-section extending proximally from the radial subchondral endplate. Reproducibility of T2* and area measurements was expressed as the absolute precision error (standard deviation [SD] in ms or mm2) or as the relative precision error (SD/mean x 100, or coefficient of variation [CV] in %) between the two-point measurements. Short-term precision of T2* and area measurements varied depending on section thickness and location of the ROI in the distal radius. Absolute precision errors for T2* times were between 1.3 and 2.9 ms (relative precision errors 3.8-9.5 %) and for area measurements between 20 and 55 mm2 (relative precision errors 5.1-16.4%). This MR technique for quantitative assessment of trabecular bone density showed reasonable reproducibility in vivo and is a promising future tool for the assessment of osteoporosis.

  18. Accuracy metrics for judging time scale algorithms

    NASA Technical Reports Server (NTRS)

    Douglas, R. J.; Boulanger, J.-S.; Jacques, C.

    1994-01-01

    Time scales have been constructed in different ways to meet the many demands placed upon them for time accuracy, frequency accuracy, long-term stability, and robustness. Usually, no single time scale is optimum for all purposes. In the context of the impending availability of high-accuracy intermittently-operated cesium fountains, we reconsider the question of evaluating the accuracy of time scales which use an algorithm to span interruptions of the primary standard. We consider a broad class of calibration algorithms that can be evaluated and compared quantitatively for their accuracy in the presence of frequency drift and a full noise model (a mixture of white PM, flicker PM, white FM, flicker FM, and random walk FM noise). We present the analytic techniques for computing the standard uncertainty for the full noise model and this class of calibration algorithms. The simplest algorithm is evaluated to find the average-frequency uncertainty arising from the noise of the cesium fountain's local oscillator and from the noise of a hydrogen maser transfer-standard. This algorithm and known noise sources are shown to permit interlaboratory frequency transfer with a standard uncertainty of less than 10(exp -15) for periods of 30-100 days.

  19. Atomic scale strain relaxation in axial semiconductor III-V nanowire heterostructures.

    PubMed

    de la Mata, María; Magén, César; Caroff, Philippe; Arbiol, Jordi

    2014-11-12

    Combination of mismatched materials in semiconductor nanowire heterostructures offers a freedom of bandstructure engineering that is impossible in standard planar epitaxy. Nevertheless, the presence of strain and structural defects directly control the optoelectronic properties of these nanomaterials. Understanding with atomic accuracy how mismatched heterostructures release or accommodate strain, therefore, is highly desirable. By using atomic resolution high angle annular dark field scanning transmission electron microscopy combined with geometrical phase analyses and computer simulations, we are able to establish the relaxation mechanisms (including both elastic and plastic deformations) to release the mismatch strain in axial nanowire heterostructures. Formation of misfit dislocations, diffusion of atomic species, polarity transfer, and induced structural transformations are studied with atomic resolution at the intermediate ternary interfaces. Two nanowire heterostructure systems with promising applications (InAs/InSb and GaAs/GaSb) have been selected as key examples.

  20. A comment on the use of flushing time, residence time, and age as transport time scales

    USGS Publications Warehouse

    Monsen, N.E.; Cloern, J.E.; Lucas, L.V.; Monismith, Stephen G.

    2002-01-01

    Applications of transport time scales are pervasive in biological, hydrologic, and geochemical studies yet these times scales are not consistently defined and applied with rigor in the literature. We compare three transport time scales (flushing time, age, and residence time) commonly used to measure the retention of water or scalar quantities transported with water. We identify the underlying assumptions associated with each time scale, describe procedures for computing these time scales in idealized cases, and identify pitfalls when real-world systems deviate from these idealizations. We then apply the time scale definitions to a shallow 378 ha tidal lake to illustrate how deviations between real water bodies and the idealized examples can result from: (1) non-steady flow; (2) spatial variability in bathymetry, circulation, and transport time scales; and (3) tides that introduce complexities not accounted for in the idealized cases. These examples illustrate that no single transport time scale is valid for all time periods, locations, and constituents, and no one time scale describes all transport processes. We encourage aquatic scientists to rigorously define the transport time scale when it is applied, identify the underlying assumptions in the application of that concept, and ask if those assumptions are valid in the application of that approach for computing transport time scales in real systems.

  1. Measurement of the relaxation time of hot electrons in laser-solid interaction at relativistic laser intensities

    SciTech Connect

    Chen, H; Shepherd, R; Chung, H K; Dyer, G; Faenov, A; Fournier, K B; Hansen, S B; Hunter, J; Kemp, A; Pikuz, T; Ping, Y; Widmann, K; Wilks, S C; Beiersdorfer, P

    2006-08-22

    The authors have measured the relaxation time of hot electrons in short pulse laser-solid interactions using a picosecond time-resolved x-ray spectrometer and a time-integrated electron spectrometer. Employing laser intensities of 10{sup 17}, 10{sup 18}, and 10{sup 19} W/cm{sup 2}, they find increased laser coupling to hot electrons as the laser intensity becomes relativistic and thermalization of hot electrons at timescales on the order of 10 ps at all laser intensities. They propose a simple model based on collisional coupling and plasma expansion to describe the rapid relaxation of hot electrons. The agreement between the resulting K{sub {alpha}} time-history from this model with the experiments is best at highest laser intensity and less satisfactory at the two lower laser intensities.

  2. A numerical study of vector resonant relaxation

    NASA Astrophysics Data System (ADS)

    Kocsis, Bence; Tremaine, Scott

    2015-04-01

    Stars bound to a supermassive black hole interact gravitationally. Persistent torques acting between stellar orbits lead to a rapid resonant relaxation of the orbital orientation vectors (`vector' resonant relaxation) and slower relaxation of the eccentricities (`scalar' resonant relaxation), both at rates much faster than two-body or non-resonant relaxation. We describe a new parallel symplectic integrator, N-RING, which follows the dynamical evolution of a cluster of N stars through vector resonant relaxation, by averaging the pairwise interactions over the orbital period and periapsis precession time-scale. We use N-RING to follow the evolution of clusters containing over 104 stars for tens of relaxation times. Among other results, we find that the evolution is dominated by torques among stars with radially overlapping orbits, and that resonant relaxation can be modelled as a random walk of the orbit normals on the sphere, with angular step size ranging from ˜0.5-1 rad. The relaxation rate in a cluster with a fixed number of stars is proportional to the root mean square (rms) mass of the stars. The rms torque generated by the cluster stars is reduced below the torque between Kepler orbits due to apsidal precession and declines weakly with the eccentricity of the perturbed orbit. However, since the angular momentum of an orbit also decreases with eccentricity, the relaxation rate is approximately eccentricity-independent for e ≲ 0.7 and grows rapidly with eccentricity for e ≳ 0.8. We quantify the relaxation using the autocorrelation function of the spherical multipole moments; this decays exponentially and the e-folding time may be identified with the vector resonant relaxation time-scale.

  3. Relaxation times and modes of disturbed aggregate distribution in micellar solutions with fusion and fission of micelles

    SciTech Connect

    Zakharov, Anatoly I.; Adzhemyan, Loran Ts.; Shchekin, Alexander K.

    2015-09-28

    We have performed direct numerical calculations of the kinetics of relaxation in the system of surfactant spherical micelles under joint action of the molecular mechanism with capture and emission of individual surfactant molecules by molecular aggregates and the mechanism of fusion and fission of the aggregates. As a basis, we have taken the difference equations of aggregation and fragmentation in the form of the generalized kinetic Smoluchowski equations for aggregate concentrations. The calculations have been made with using the droplet model of molecular surfactant aggregates and two modified Smoluchowski models for the coefficients of aggregate-monomer and aggregate-aggregate fusions which take into account the effects of the aggregate size and presence of hydrophobic spots on the aggregate surface. A full set of relaxation times and corresponding relaxation modes for nonequilibrium aggregate distribution in the aggregation number has been found. The dependencies of these relaxation times and modes on the total concentration of surfactant in the solution and the special parameter controlling the probability of fusion in collisions of micelles with other micelles have been studied.

  4. Hemispheric Asymmetries in Substorm Recovery Time Scales

    NASA Technical Reports Server (NTRS)

    Fillingim, M. O.; Chua, D H.; Germany, G. A.; Spann, James F.

    2009-01-01

    Previous statistical observations have shown that the recovery time scales of substorms occurring in the winter and near equinox (when the nighttime auroral zone was in darkness) are roughly twice as long as the recovery time scales for substorms occurring in the summer (when the nighttime auroral region was sunlit). This suggests that auroral substorms in the northern and southern hemispheres develop asymmetrically during solstice conditions with substorms lasting longer in the winter (dark) hemisphere than in the summer (sunlit) hemisphere. Additionally, this implies that more energy is deposited by electron precipitation in the winter hemisphere than in the summer one during substorms. This result, coupled with previous observations that have shown that auroral activity is more common when the ionosphere is in darkness and is suppressed when the ionosphere is in daylight, strongly suggests that the ionospheric conductivity plays an important role governing how magnetospheric energy is transferred to the ionosphere during substorms. Therefore, the ionosphere itself may dictate how much energy it will accept from the magnetosphere during substorms rather than this being an externally imposed quantity. Here, we extend our earlier work by statistically analyzing the recovery time scales for a large number of substorms observed in the conjugate hemispheres simultaneously by two orbiting global auroral imagers: Polar UVI and IMAGE FUV. Our current results are consistent with previous observations. The recovery time scales are observed to be longer in the winter (dark) hemisphere while the auroral activity has a shorter duration in the summer (sunlit) hemisphere. This leads to an asymmetric energy input from the magnetosphere to the ionosphere with more energy being deposited in the winter hemisphere than in the summer hemisphere.

  5. Scaling of light and dark time intervals.

    PubMed

    Marinova, J

    1978-01-01

    Scaling of light and dark time intervals of 0.1 to 1.1 s is performed by the mehtod of magnitude estimation with respect to a given standard. The standards differ in duration and type (light and dark). The light intervals are subjectively estimated as longer than the dark ones. The relation between the mean interval estimations and their magnitude is linear for both light and dark intervals.

  6. Harsh corporal punishment is associated with increased T2 relaxation time in dopamine-rich regions.

    PubMed

    Sheu, Yi-Shin; Polcari, Ann; Anderson, Carl M; Teicher, Martin H

    2010-11-01

    Harsh corporal punishment (HCP) was defined as frequent parental administration of corporal punishment (CP) for discipline, with occasional use of objects such as straps, or paddles. CP is linked to increased risk for depression and substance abuse. We examine whether long-term exposure to HCP acts as sub-traumatic stressor that contributes to brain alterations, particularly in dopaminergic pathways, which may mediate their increased vulnerability to drug and alcohol abuse. Nineteen young adults who experienced early HCP but no other forms of maltreatment and twenty-three comparable controls were studied. T2 relaxation time (T2-RT) measurements were performed with an echo planar imaging TE stepping technique and T2 maps were calculated and analyzed voxel-by-voxel to locate regional T2-RT differences between groups. Previous studies indicated that T2-RT provides an indirect index of resting cerebral blood volume. Region of interest (ROI) analyses were also conducted in caudate, putamen, nucleus accumbens, anterior cingulate cortex, dorsolateral prefrontal cortex, thalamus, globus pallidus and cerebellar hemispheres. Voxel-based relaxometry showed that HCP was associated with increased T2-RT in right caudate and putamen. ROI analyses also revealed increased T2-RT in dorsolateral prefrontal cortex, substantia nigra, thalamus and accumbens but not globus pallidus or cerebellum. There were significant associations between T2-RT measures in dopamine target regions and use of drugs and alcohol, and memory performance. Alteration in the paramagnetic or hemodynamic properties of dopaminergic cell body and projection regions were observed in subjects with HCP, and these findings may relate to their increased risk for drug and alcohol abuse.

  7. Thermoelectric properties of bismuth telluride nanowires in the constant relaxation-time approximation

    NASA Astrophysics Data System (ADS)

    Bejenari, I.; Kantser, V.

    2008-09-01

    Electronic structure of bismuth telluride nanowires with the growth directions [110] and [015] is studied in the framework of the anisotropic effective-mass method using the parabolic band approximation. The components of the electron and hole effective-mass tensors for six valleys are calculated for both growth directions. For a square nanowire, in the temperature range from 77 to 500 K, the dependence of the Seebeck coefficient S , the thermal κ , and electrical conductivity σ , as well as the figure of merit ZT on the nanowire thickness and on the excess hole concentration pex , are investigated in the constant relaxation-time approximation. The carrier confinement is shown to play essential role for nanowires with cross section less than 30×30nm2 . In contrast to the excess holes (impurities), the confinement decreases both the carrier concentration and the thermal conductivity but increases the maximum value of the Seebeck coefficient. The confinement effect is stronger for the direction [015] than for the direction [110] due to the carrier mass difference for these directions. In the restricted temperature range, the size quantum limit is valid when the P -type nanowire cross section is smaller than 8×10nm2 ( 6×7 and 5×5nm2 ) at the excess hole concentration pex=2×1018cm-3 ( pex=5×1018cm-3 and pex=1×1019cm-3 correspondingly). The carrier confinement increases the maximum value of ZT and shifts it toward high temperatures. For the growth direction [110], the maximum value of the figure of merit for the P -type nanowire is equal to 1.4, 1.6, and 2.8, correspondingly, at temperatures 310, 390, and 480 K and the cross sections 30×30 , 15×15 , and 7×7nm2 (pex=5×1018cm-3) . At room temperature, the figure of merit equals 1.2, 1.3, and 1.7, respectively.

  8. Liquidity crises on different time scales.

    PubMed

    Corradi, Francesco; Zaccaria, Andrea; Pietronero, Luciano

    2015-12-01

    We present an empirical analysis of the microstructure of financial markets and, in particular, of the static and dynamic properties of liquidity. We find that on relatively large time scales (15 min) large price fluctuations are connected to the failure of the subtle mechanism of compensation between the flows of market and limit orders: in other words, the missed revelation of the latent order book breaks the dynamical equilibrium between the flows, triggering the large price jumps. On smaller time scales (30 s), instead, the static depletion of the limit order book is an indicator of an intrinsic fragility of the system, which is related to a strongly nonlinear enhancement of the response. In order to quantify this phenomenon we introduce a measure of the liquidity imbalance present in the book and we show that it is correlated to both the sign and the magnitude of the next price movement. These findings provide a quantitative definition of the effective liquidity, which proves to be strongly dependent on the considered time scales.

  9. Liquidity crises on different time scales

    NASA Astrophysics Data System (ADS)

    Corradi, Francesco; Zaccaria, Andrea; Pietronero, Luciano

    2015-12-01

    We present an empirical analysis of the microstructure of financial markets and, in particular, of the static and dynamic properties of liquidity. We find that on relatively large time scales (15 min) large price fluctuations are connected to the failure of the subtle mechanism of compensation between the flows of market and limit orders: in other words, the missed revelation of the latent order book breaks the dynamical equilibrium between the flows, triggering the large price jumps. On smaller time scales (30 s), instead, the static depletion of the limit order book is an indicator of an intrinsic fragility of the system, which is related to a strongly nonlinear enhancement of the response. In order to quantify this phenomenon we introduce a measure of the liquidity imbalance present in the book and we show that it is correlated to both the sign and the magnitude of the next price movement. These findings provide a quantitative definition of the effective liquidity, which proves to be strongly dependent on the considered time scales.

  10. Multidimensional scaling of musical time estimations.

    PubMed

    Cocenas-Silva, Raquel; Bueno, José Lino Oliveira; Molin, Paul; Bigand, Emmanuel

    2011-06-01

    The aim of this study was to identify the psycho-musical factors that govern time evaluation in Western music from baroque, classic, romantic, and modern repertoires. The excerpts were previously found to represent variability in musical properties and to induce four main categories of emotions. 48 participants (musicians and nonmusicians) freely listened to 16 musical excerpts (lasting 20 sec. each) and grouped those that seemed to have the same duration. Then, participants associated each group of excerpts to one of a set of sine wave tones varying in duration from 16 to 24 sec. Multidimensional scaling analysis generated a two-dimensional solution for these time judgments. Musical excerpts with high arousal produced an overestimation of time, and affective valence had little influence on time perception. The duration was also overestimated when tempo and loudness were higher, and to a lesser extent, timbre density. In contrast, musical tension had little influence. PMID:21853763

  11. Short-time scale behavior modeling within long-time scale fuel cycle evaluations

    SciTech Connect

    Johnson, M.; Tsvetkov, P.; Lucas, S.

    2012-07-01

    Typically, short-time and long-time scales in nuclear energy system behavior are accounted for with entirely separate models. However, long-term changes in system characteristics do affect short-term transients through material variations. This paper presents an approach to consistently account for short-time scales within a nuclear system lifespan. The reported findings and developments are of significant importance for small modular reactors and other nuclear energy systems operating in autonomous modes. It is necessary to simulate the short time-scale kinetic behavior of the reactor as well as the long time-scale dynamics that occur with fuel burnup. The former is modeled using the point kinetics equations, while the latter is modeled by the Bateman equations. (authors)

  12. RADIAL TRANSPORT OF LARGE-SCALE MAGNETIC FIELDS IN ACCRETION DISKS. II. RELAXATION TO STEADY STATES

    SciTech Connect

    Takeuchi, Taku; Okuzumi, Satoshi

    2014-12-20

    We study the time evolution of a large-scale magnetic flux threading an accretion disk. The induction equation of the mean poloidal field is solved under the standard viscous disk model. Magnetic flux evolution is controlled by two timescales: one is the timescale of the inward advection of the magnetic flux, τ{sub adv}. This is induced by the dragging of the flux by the accreting gas. The other is the outward diffusion timescale of the magnetic flux τ{sub dif}. We consider diffusion due to the Ohmic resistivity. These timescales can be significantly different from the disk viscous timescale τ{sub disk}. The behaviors of the magnetic flux evolution are quite different depending on the magnitude relationship of the timescales τ{sub adv}, τ{sub dif}, and τ{sub disk}. The most interesting phenomena occur when τ{sub adv} << τ{sub dif}, τ{sub disk}. In such a case, the magnetic flux distribution approaches a quasi-steady profile much faster than the viscous evolution of the gas disk, and the magnetic flux has also been tightly bundled to the inner part of the disk. In the inner part, although the poloidal magnetic field becomes much stronger than the interstellar magnetic field, the field strength is limited to the maximum value that is analytically given by our previous work. We also find a condition for the initial large magnetic flux, which is a fossil of the magnetic field dragging during the early phase of star formation that survives for a duration in which significant gas disk evolution proceeds.

  13. South Atlantic Spreading Velocities and Time Scales

    NASA Astrophysics Data System (ADS)

    Clark, S. R.; Smethurst, M. A.; Bianchi, M. C.

    2013-12-01

    Plate reconstructions based on hierarchical spherical rotations have been around for many years. For the breakup of Pangea and Gondwana, these reconstructions are based on two major sources: magnetic isochrons and geological evidence for the onset of rifting and the tightness of the fit between continents. These reconstructions imply spreading velocities and it is the changes in velocities that can be used to probe questions of the forces moving plates around. In order to calculate the velocities correctly though, the importance of the choice of geologic time scale is often ignored. In this talk, we focus on the South Atlantic and calculate the spreading velocity errors implied by the choice of time scale for three major epochs: the Cenozoic and Late Mesozoic, the Cretaceous Quiet Zone and the Late Cretaceous to the Early Jurassic. In addition, we report the spreading velocities implied through these phases by various available magnetic isochron-derived reconstructions and the geological fits for South America and Africa used by large scale global reconstruction as well as in recent papers. Finally, we will highlight the implications for the choice of the mantle reference frame on African plate velocities.

  14. Dynamic Relaxation of Financial Indices

    NASA Astrophysics Data System (ADS)

    Shen, J.; Zheng, B.; Lin, H.; Qiu, T.

    The dynamic relaxation of the German DAX both before and after a large price-change is investigated. The dynamic behavior is characterized by a power law. At the minutely time scale, the exponent p governing the power-law behavior takes a same value before and after the large price change, while at the daily time scale, it is different. Numerical simulations of an interacting EZ herding model are performed for comparison.

  15. Deciphering Time Scale Hierarchy in Reaction Networks.

    PubMed

    Nagahata, Yutaka; Maeda, Satoshi; Teramoto, Hiroshi; Horiyama, Takashi; Taketsugu, Tetsuya; Komatsuzaki, Tamiki

    2016-03-01

    Markovian dynamics on complex reaction networks are one of the most intriguing subjects in a wide range of research fields including chemical reactions, biological physics, and ecology. To represent the global kinetics from one node (corresponding to a basin on an energy landscape) to another requires information on multiple pathways that directly or indirectly connect these two nodes through the entire network. In this paper we present a scheme to extract a hierarchical set of global transition states (TSs) over a discrete-time Markov chain derived from first-order rate equations. The TSs can naturally take into account the multiple pathways connecting any pair of nodes. We also propose a new type of disconnectivity graph (DG) to capture the hierarchical organization of different time scales of reactions that can capture changes in the network due to changes in the time scale of observation. The crux is the introduction of the minimum conductance cut (MCC) in graph clustering, corresponding to the dividing surface across the network having the "smallest" transition probability between two disjoint subnetworks (superbasins on the energy landscape) in the network. We present a new combinatorial search algorithm for finding this MCC. We apply our method to a reaction network of Claisen rearrangement of allyl vinyl ether that consists of 23 nodes and 66 links (saddles on the energy landscape) connecting them. We compare the kinetic properties of our DG to those of the transition matrix of the rate equations and show that our graph can properly reveal the hierarchical organization of time scales in a network. PMID:26641663

  16. Scaling laws from geomagnetic time series

    USGS Publications Warehouse

    Voros, Z.; Kovacs, P.; Juhasz, A.; Kormendi, A.; Green, A.W.

    1998-01-01

    The notion of extended self-similarity (ESS) is applied here for the X - component time series of geomagnetic field fluctuations. Plotting nth order structure functions against the fourth order structure function we show that low-frequency geomagnetic fluctuations up to the order n = 10 follow the same scaling laws as MHD fluctuations in solar wind, however, for higher frequencies (f > l/5[h]) a clear departure from the expected universality is observed for n > 6. ESS does not allow to make an unambiguous statement about the non triviality of scaling laws in "geomagnetic" turbulence. However, we suggest to use higher order moments as promising diagnostic tools for mapping the contributions of various remote magnetospheric sources to local observatory data. Copyright 1998 by the American Geophysical Union.

  17. Dislocation-mediated relaxation in nanograined columnar palladium films revealed by on-chip time-resolved HRTEM testing

    PubMed Central

    Colla, M. -S.; Amin-Ahmadi, B.; Idrissi, H.; Malet, L.; Godet, S.; Raskin, J. -P.; Schryvers, D.; Pardoen, T.

    2015-01-01

    The high-rate sensitivity of nanostructured metallic materials demonstrated in the recent literature is related to the predominance of thermally activated deformation mechanisms favoured by a large density of internal interfaces. Here we report time-resolved high-resolution electron transmission microscopy creep tests on thin nanograined films using on-chip nanomechanical testing. Tests are performed on palladium, which exhibited unexpectedly large creep rates at room temperature. Despite the small 30-nm grain size, relaxation is found to be mediated by dislocation mechanisms. The dislocations interact with the growth nanotwins present in the grains, leading to a loss of coherency of twin boundaries. The density of stored dislocations first increases with applied deformation, and then decreases with time to drive additional deformation while no grain boundary mechanism is observed. This fast relaxation constitutes a key issue in the development of various micro- and nanotechnologies such as palladium membranes for hydrogen applications. PMID:25557273

  18. Slip-flow in complex porous media as determined by a multi-relaxation-time lattice Boltzmann model

    NASA Astrophysics Data System (ADS)

    Landry, C. J.; Prodanovic, M.; Eichhubl, P.

    2014-12-01

    The pores and throats of shales and mudrocks are predominantly found within a range of 1-100 nm, within this size range the flow of gas at reservoir conditions will fall within the slip-flow and low transition-flow regime (0.001 < Kn < 0.5). Currently, the study of slip-flows is for the most part limited to simple tube and channel geometries, however, the geometry of mudrock pores is often sponge-like (organic matter) and/or platy (clays). Molecular dynamics (MD) simulations can be used to predict slip-flow in complex geometries, but due to prohibitive computational demand are generally limited to small volumes (one to several pores). Here we present a multi-relaxation-time lattice Boltzmann model (LBM) parameterized for slip-flow (Guo et al. 2008) and adapted here to complex geometries. LBMs are inherently parallelizable, such that flow in complex geometries of significant (near REV-scale) volumes can be readily simulated at a fraction of the computational cost of MD simulations. At the macroscopic-scale the LBM is parameterized with local effective viscosities at each node to capture the variance of the mean-free-path of gas molecules in a bounded system. The corrected mean-free-path for each lattice node is determined using the mean distance of the node to the pore-wall and Stop's correction for mean-free-paths in an infinite parallel-plate geometry. At the microscopic-scale, a combined bounce-back specular-reflection boundary condition is applied to the pore-wall nodes to capture Maxwellian-slip. The LBM simulation results are first validated in simple tube and channel geometries, where good agreement is found for Knudsen numbers below 0.1, and fair agreement is found for Knudsen numbers between 0.1 and 0.5. More complex geometries are then examined including triangular-ducts and ellipsoid-ducts, both with constant and tapering/expanding cross-sections, as well as a clay pore-network imaged from a hydrocarbon producing shale by sequential focused ion

  19. SU-E-I-64: Transverse Relaxation Time in Methylene Protons of Non-Alcoholic Fatty Liver Disease Rats

    SciTech Connect

    Song, K-H; Lee, D-W; Choe, B-Y

    2015-06-15

    Purpose: The aim of this study was to evaluate transverse relaxation time of methylene resonance compared to other lipid resonances. Methods: The examinations were performed using a 3.0 T scanner with a point — resolved spectroscopy (PRESS) sequence. Lipid relaxation time in a lipid phantom filled with canola oil was estimated considering repetition time (TR) as 6000 msec and echo time (TE) as 40 — 550 msec. For in vivo proton magnetic resonance spectroscopy ({sup 1}H — MRS), eight male Sprague — Dawley rats were given free access to a normal - chow (NC) and eight other male Sprague-Dawley rats were given free access to a high — fat (HF) diet. Both groups drank water ad libitum. T{sub 2} measurements in the rats’ livers were conducted at a fixed TR of 6000 msec and TE of 40 – 220 msec. Exponential curve fitting quality was calculated through the coefficients of determination (R{sup 2}). Results: A chemical analysis of phantom and liver was not performed but a T{sub 2} decay curve was acquired. The T{sub 2} relaxation time of methylene resonance was estimated as follows: NC rats, 37.07 ± 4.32 msec; HF rats, 31.43 ± 1.81 msec (p < 0.05). The extrapolated M0 values were higher in HF rats than in NC rats (p < 0.005). Conclusion: This study of {sup 1}H-MRS led to sufficient spectral resolution and signal — to — noise ratio differences to characterize all observable resonances for yielding T{sub 2} relaxation times of methylene resonance. {sup 1}H — MRS relaxation times may be useful for quantitative characterization of various liver diseases, including fatty liver disease. This study was supported by grant (2012-007883 and 2014R1A2A1A10050270) from the Mid-career Researcher Program through the NRF funded by Ministry of Science. In addition, this study was supported by the Industrial R&D of MOTIE/KEIT (10048997, Development of the core technology for integrated therapy devices based on real-time MRI-guided tumor tracking)

  20. Deriving time-dependent diffusion and relaxation rate in porous systems using eigenfunctions of the Laplace operator.

    PubMed

    Nordin, Matias; Jacobi, Martin Nilsson; Nydén, Magnus

    2009-12-01

    Porous systems are investigated using eigendecomposition of the Laplace matrix. Three parameters; tortuosity, surface-to-pore volume ratio and relaxation rate are derived from the eigenvalue spectrum of the Laplace matrix and connected to the parameters in the Padé approximation, an expression often used to describe the time-dependent diffusion coefficient in porous systems. The Padé length is identified for systems with large pore to connector volume ratio. The results are compared with simulations.

  1. The Effect of Rotation on Two-Dimensional Problem of a Fiber-Reinforced Thermoelastic with One Relaxation Time

    NASA Astrophysics Data System (ADS)

    Othman, Mohamed I. A.; Said, Samia M.

    2012-01-01

    In this article, the Lord-Shulman (L-S) theory with one relaxation time and coupled theory are applied to study the influence of reinforcement on the total deformation of a rotating thermoelastic half-space and the interaction with each other. The problem of a thermal shock has been solved numerically using normal mode analysis. Numerical results for the temperature, displacement, and thermal stress components are given and illustrated graphically for both L-S and coupled theories.

  2. Alterations in Magnetic Resonance Imaging T2 Relaxation Times of the Ovine Intervertebral Disc Due to Non-enzymatic Glycation

    PubMed Central

    Jazini, Ehsan; Sharan, Alok D; Morse, Lee Jae; Dyke, Jonathon P; Aronowitz, Eric A; Chen, Louis KH; Tang, Simon Y

    2011-01-01

    Study Design An in vitro study using ovine intervertebral discs to correlate the effects of advanced glycation end-products (AGEs) with disc hydration evaluated by magnetic resonance imaging (MRI). Objective To determine the relationship between the level of AGEs and tissue water content in intervertebral discs using T2 relaxation MRI. Summary of Background Data AGEs result from nonenzymatic glycation, and AGEs have been shown to accumulate in the IVD tissue with aging and degeneration. AGEs can alter biochemical properties, including the hydrophobicity of the extracellular matrix. Since one of the degenerative signs of the IVD is the reduced hydration, it was hypothesized that increased levels of tissue AGEs may contribute to disc hydration. T2 relaxation MRI has been shown to be sensitive to the hydration status of the disc, and may be valuable in detecting the changes in the IVD mediated by the increase of AGEs. Methods Thirty-eight IVDs were obtained from 4 ovine spines, and the annulus fibrosis (AF) and nucleus pulposus (NP) tissues were isolated from these discs. The tissues were incubated in either a ribosylation or control solution for up to 8 days to induce the formation of AGEs. These tissues were subsequently analyzed for tissue water content and concentration of AGEs. T2 relaxation times were obtained from these tissues after ribosylation. Results Ribosylation led to the increased accumulation of AGEs and reduced water content in both the AF and NP in a dose-dependent manner. When analyzed by MRI, ribosylation significantly altered the mean T2 relaxation times in the NP (p=0.001), but not in the AF (p=0.912). Furthermore, the mean T2 values in the NP significantly decreased with increasing periods of incubation time (p<0.001). Conclusion This study demonstrates that levels of AGEs in the IVD may affect the tissue water content. Moreover, these ribosylation-mediated changes in tissue hydration were detectable using T2 relaxation MRI. T2 relaxation MRI

  3. Polarized Alkali-Metal Vapor with Minute-Long Transverse Spin-Relaxation Time

    NASA Astrophysics Data System (ADS)

    Balabas, M. V.; Karaulanov, T.; Ledbetter, M. P.; Budker, D.

    2010-08-01

    We demonstrate lifetimes of Zeeman populations and coherences in excess of 60 sec in alkali-metal vapor cells with inner walls coated with an alkene material. This represents 2 orders of magnitude improvement over the best paraffin coatings. We explore the temperature dependence of cells coated with this material and investigate spin-exchange relaxation-free magnetometry in a room-temperature environment, a regime previously inaccessible with conventional coating materials.

  4. Toward an objective Phanerozoic time scale

    NASA Astrophysics Data System (ADS)

    Carr, Paul F.; Jones, Brian G.; Quinn, Barry G.; Wright, Anthony J.

    1984-05-01

    Previous age estimations of period, series, and stage boundaries for the Phanerozoic have usually relied on a subjective approach, in which visual inspection was used to determine each time interval. This subjectivity can be eliminated partially by fitting a piecewise linear regression model of radiometric age on a variable calculated from the biostratigraphic data, enabling the computation of estimates of, and confidence limits for, various boundaries of interest. This method is illustrated by calculating the duration of each Phanerozoic system and thus the quantitative age of all the system boundaries. The method can be extended to investigate any part of the Phanerozoic time scale in more detail, provided sufficient biostratigraphically well-controlled isotopic age data are available, as for example, for the Cenozoic and the Eocene. *Present address: University of Queensland, St. Lucia, Queensland, Australia 4067

  5. Effects of hydrophobic treatments of stone on pore water studied by continuous distribution analysis of NMR relaxation times.

    PubMed

    Appolonia, L; Borgia, G C; Bortolotti, V; Brown, R J; Fantazzini, P; Rezzaro, G

    2001-01-01

    The effects of protective hydrophobic products applied to porous media such as stone or mortar vary greatly with the product, the porous medium, and the mode of application. Nuclear Magnetic Resonance (NMR) measurements on fluids in the pore spaces of both treated and untreated samples can give information on the contact of the fluid with the internal surfaces, which is affected by all the above factors. Continuous distributions of relaxation times T(1) and T(2) of water in the pores of both synthetic and natural porous media were obtained before and after hydrophobic treatment. The synthetic porous media are ceramic filter materials characterized by narrow distributions of pore dimensions and show that the treatment does not produce large changes in the relaxation times of the water. For three travertine samples most of a long relaxation time component, presumably from the largest pores, remains after treatment, while the amplitude of an intermediate component is greatly reduced. For three pudding-stone samples, treatment leads to a substantial loss from the long component and an even greater loss from the intermediate component. PMID:11445343

  6. Effects of Off-Resonance Irradiation, Cross-Relaxation, and Chemical Exchange on Steady-State Magnetization and Effective Spin-Lattice Relaxation Times

    NASA Astrophysics Data System (ADS)

    Kingsley, Peter B.; Monahan, W. Gordon

    2000-04-01

    In the presence of an off-resonance radiofrequency field, recovery of longitudinal magnetization to a steady state is not purely monoexponential. Under reasonable conditions with zero initial magnetization, recovery is nearly exponential and an effective relaxation rate constant R1eff = 1/T1eff can be obtained. Exact and approximate formulas for R1eff and steady-state magnetization are derived from the Bloch equations for spins undergoing cross-relaxation and chemical exchange between two sites in the presence of an off-resonance radiofrequency field. The relaxation formulas require that the magnetization of one spin is constant, but not necessarily zero, while the other spin relaxes. Extension to three sites with one radiofrequency field is explained. The special cases of off-resonance effects alone and with cross-relaxation or chemical exchange, cross-relaxation alone, and chemical exchange alone are compared. The inaccuracy in saturation transfer measurements of exchange rate constants by published formulas is discussed for the creatine kinase reaction.

  7. Distributions of transverse relaxation times for soft-solids measured in strongly inhomogeneous magnetic fields.

    PubMed

    Chelcea, R I; Fechete, R; Culea, E; Demco, D E; Blümich, B

    2009-02-01

    The single-sided NMR-MOUSE sensor that operates in highly inhomogeneous magnetic fields is used to record a CPMG (1)H transverse relaxation decay by CPMG echo trains for a series of cross-linked natural rubber samples. Effective transverse relaxation rates 1/T(2,short) and 1/T(2,long) were determined by a bi-exponential fit. A linear dependence of transverse relaxation rates on cross-link density is observed for medium to large values of cross-link density. As an alternative to multi-exponential fits the possibility to analyze the dynamics of soft polymer network in terms of multi-exponential decays via the inverse Laplace transformation was studied. The transient regime and the effect of the T(1)/T(2) ratio in inhomogeneous static and radiofrequency magnetic fields on the CPMG decays were studied numerically using a dedicated C++ program to simulate the temporal and spatial dependence of the CPMG response. A correction factor T(2)/T(2,eff) is derived as a function of the T(1)/T(2) ratio from numerical simulations and compared with earlier results from two different well logging devices. High-resolution T(1)-T(2) correlations maps are obtained by two-dimensional Laplace inversion of CPMG detected saturation recovery curves. The T(1)-T(2) experimental correlations maps were corrected for the T(1)/T(2) effect using the derived T(2)/T(2,eff) correction factor.

  8. Parametric instabilities in picosecond time scales

    SciTech Connect

    Baldis, H.A.; Rozmus, W.; Labaune, C.; Mounaix, Ph.; Pesme, D.; Baton, S.; Tikhonchuk, V.T.

    1993-03-01

    The coupling of intense laser light with plasmas is a rich field of plasma physics, with many applications. Among these are inertial confinement fusion (ICF), x-ray lasers, particle acceleration, and x-ray sources. Parametric instabilities have been studied for many years because of their importance to ICF; with laser pulses with duration of approximately a nanosecond, and laser intensities in the range 10{sup 14}--10{sup 15}W/cm{sup 2} these instabilities are of crucial concern because of a number of detrimental effects. Although the laser pulse duration of interest for these studies are relatively long, it has been evident in the past years that to reach an understanding of these instabilities requires their characterization and analysis in picosecond time scales. At the laser intensities of interest, the growth rate for stimulated Brillouin scattering (SBS) is of the order of picoseconds, and of an order of magnitude shorter for stimulated Raman scattering (SRS). In this paper the authors discuss SBS and SRS in the context of their evolution in picosecond time scales. They describe the fundamental concepts associated with their growth and saturation, and recent work on the nonlinear treatment required for the modeling of these instabilities at high laser intensities.

  9. In vivo relaxation time measurements on a murine tumor model--prolongation of T1 after photodynamic therapy.

    PubMed

    Liu, Y H; Hawk, R M; Ramaprasad, S

    1995-01-01

    RIF tumors implanted on mice feet were investigated for changes in relaxation times (T1 and T2) after photodynamic therapy (PDT). Photodynamic therapy was performed using Photofrin II as the photosensitizer and laser light at 630 nm. A home-built proton solenoid coil in the balanced configuration was used to accommodate the tumors, and the relaxation times were measured before, immediately after, and up to several hours after therapy. Several control experiments were performed untreated tumors, tumors treated with Photofrin II alone, or tumors treated with laser light alone. Significant increases in T1s of water protons were observed after PDT treatment. In all experiments, 31P spectra were recorded before and after the therapy to study the tumor status and to confirm the onset of PDT. These studies show significant prolongation of T1s after the PDT treatment. The spin-spin relaxation measurements, on the other hand, did not show such prolongation in T2 values after PDT treatment.

  10. Electron spin relaxation times and rapid scan EPR imaging of pH-sensitive amino-substituted trityl radicals.

    PubMed

    Elajaili, Hanan B; Biller, Joshua R; Tseitlin, Mark; Dhimitruka, Ilirian; Khramtsov, Valery V; Eaton, Sandra S; Eaton, Gareth R

    2015-04-01

    Carboxy-substituted trityl (triarylmethyl) radicals are valuable in vivo probes because of their stability, narrow lines, and sensitivity of their spectroscopic properties to oxygen. Amino-substituted trityl radicals have the potential to monitor pH in vivo, and the suitability for this application depends on spectral properties. Electron spin relaxation times T1 and T2 were measured at X-band for the protonated and deprotonated forms of two amino-substituted triarylmethyl radicals. Comparison with relaxation times for carboxy-substituted triarylmethyl radicals shows that T1 exhibits little dependence on protonation or the nature of the substituent, which makes it useful for measuring O2 concentration, independent of pH. Insensitivity of T1 to changes in substituents is consistent with the assignment of the dominant contribution to spin lattice relaxation as a local mode that involves primarily atoms in the carbon and sulfur core. Values of T2 vary substantially with pH and the nature of the aryl group substituent, reflecting a range of dynamic processes. The narrow spectral widths for the amino-substituted triarylmethyl radicals facilitate spectral-spatial rapid scan electron paramagnetic resonance imaging, which was demonstrated with a phantom. The dependence of hyperfine splittings patterns on pH is revealed in spectral slices through the image.

  11. H-1 Relaxation Times of Metabolites in Biological Samples Obtained with Nondestructive Ex-vivo Slow-MAS NMR

    SciTech Connect

    Hu, Jian Zhi; Wind, Robert A.; Rommereim, Donald N.

    2006-03-01

    Methods suitable for measuring 1H relaxation times such as T1, T2 and T1p, in small sized biological objects including live cells, excised organs and tissues, oil seeds etc., were developed in this work. This was achieved by combining inversion-recovery, spin-echo, or spin lock segment with the phase-adjusted spinning sideband (PASS) technique that was applied at slow sample spinning rate. Here, 2D-PASS was used to produce a high-resolution 1H spectrum free from the magnetic susceptibility broadening so that the relaxation parameters of individual metabolite can be determined. Because of the slow spinning employed, tissue and cell damage due to sample spinning is minimized. The methodologies were demonstrated by measuring 1H T1, T2 and T1p of metabolites in excised rat livers and sesame seeds at spinning rates of as low as 40 Hz.

  12. Second order rate constants for intramolecular conversions: Application to gas-phase NMR relaxation times

    NASA Astrophysics Data System (ADS)

    Bauer, S. H.; Lazaar, K. I.

    1983-09-01

    The usually quoted expression for the second order rate constant, for a unimolecular reaction at the low pressure limit, is valid only for strictly irreversible processes. Its application to isomerization reactions (which are to some extent reversible) is demonstrably in error; corrected expressions have been published. Attention is directed to intramolecular conversions over low barriers, for which the inappropriateness of the unidirectional expression becomes obvious. For such isomerizations we propose a model which incorporates only operationally observable states, so that an essential conceptual ambiguity is avoided. Use of this model is illustrated for the syn⇄anti conversions of methyl nitrite, derived from a gas phase NMR coalescence curve (Mc:Tc). The present data suggest that during isomerization the alkyl nitrites may not be completely ergodic on a time scale of 10-9 s. A regional phase-space model is proposed which has the appropriate formalism to account for this behavior.

  13. EDITORIAL: Special issue on time scale algorithms

    NASA Astrophysics Data System (ADS)

    Matsakis, Demetrios; Tavella, Patrizia

    2008-12-01

    This special issue of Metrologia presents selected papers from the Fifth International Time Scale Algorithm Symposium (VITSAS), including some of the tutorials presented on the first day. The symposium was attended by 76 persons, from every continent except Antarctica, by students as well as senior scientists, and hosted by the Real Instituto y Observatorio de la Armada (ROA) in San Fernando, Spain, whose staff further enhanced their nation's high reputation for hospitality. Although a timescale can be simply defined as a weighted average of clocks, whose purpose is to measure time better than any individual clock, timescale theory has long been and continues to be a vibrant field of research that has both followed and helped to create advances in the art of timekeeping. There is no perfect timescale algorithm, because every one embodies a compromise involving user needs. Some users wish to generate a constant frequency, perhaps not necessarily one that is well-defined with respect to the definition of a second. Other users might want a clock which is as close to UTC or a particular reference clock as possible, or perhaps wish to minimize the maximum variation from that standard. In contrast to the steered timescales that would be required by those users, other users may need free-running timescales, which are independent of external information. While no algorithm can meet all these needs, every algorithm can benefit from some form of tuning. The optimal tuning, and even the optimal algorithm, can depend on the noise characteristics of the frequency standards, or of their comparison systems, the most precise and accurate of which are currently Two Way Satellite Time and Frequency Transfer (TWSTFT) and GPS carrier phase time transfer. The interest in time scale algorithms and its associated statistical methodology began around 40 years ago when the Allan variance appeared and when the metrological institutions started realizing ensemble atomic time using more than

  14. EDITORIAL: Special issue on time scale algorithms

    NASA Astrophysics Data System (ADS)

    Matsakis, Demetrios; Tavella, Patrizia

    2008-12-01

    This special issue of Metrologia presents selected papers from the Fifth International Time Scale Algorithm Symposium (VITSAS), including some of the tutorials presented on the first day. The symposium was attended by 76 persons, from every continent except Antarctica, by students as well as senior scientists, and hosted by the Real Instituto y Observatorio de la Armada (ROA) in San Fernando, Spain, whose staff further enhanced their nation's high reputation for hospitality. Although a timescale can be simply defined as a weighted average of clocks, whose purpose is to measure time better than any individual clock, timescale theory has long been and continues to be a vibrant field of research that has both followed and helped to create advances in the art of timekeeping. There is no perfect timescale algorithm, because every one embodies a compromise involving user needs. Some users wish to generate a constant frequency, perhaps not necessarily one that is well-defined with respect to the definition of a second. Other users might want a clock which is as close to UTC or a particular reference clock as possible, or perhaps wish to minimize the maximum variation from that standard. In contrast to the steered timescales that would be required by those users, other users may need free-running timescales, which are independent of external information. While no algorithm can meet all these needs, every algorithm can benefit from some form of tuning. The optimal tuning, and even the optimal algorithm, can depend on the noise characteristics of the frequency standards, or of their comparison systems, the most precise and accurate of which are currently Two Way Satellite Time and Frequency Transfer (TWSTFT) and GPS carrier phase time transfer. The interest in time scale algorithms and its associated statistical methodology began around 40 years ago when the Allan variance appeared and when the metrological institutions started realizing ensemble atomic time using more than

  15. Consistent scaling of persistence time in metapopulations.

    PubMed

    Yaari, Gur; Ben-Zion, Yossi; Shnerb, Nadav M; Vasseur, David A

    2012-05-01

    Recent theory and experimental work in metapopulations and metacommunities demonstrates that long-term persistence is maximized when the rate at which individuals disperse among patches within the system is intermediate; if too low, local extinctions are more frequent than recolonizations, increasing the chance of regional-scale extinctions, and if too high, dynamics exhibit region-wide synchrony, and local extinctions occur in near unison across the region. Although common, little is known about how the size and topology of the metapopulation (metacommunity) affect this bell-shaped relationship between dispersal rate and regional persistence time. Using a suite of mathematical models, we examined the effects of dispersal, patch number, and topology on the regional persistence time when local populations are subject to demographic stochasticity. We found that the form of the relationship between regional persistence time and the number of patches is consistent across all models studied; however, the form of the relationship is distinctly different among low, intermediate, and high dispersal rates. Under low and intermediate dispersal rates, regional persistence times increase logarithmically and exponentially (respectively) with increasing numbers of patches, whereas under high dispersal, the form of the relationship depends on local dynamics. Furthermore, we demonstrate that the forms of these relationships, which give rise to the bell-shaped relationship between dispersal rate and persistence time, are a product of recolonization and the region-wide synchronization (or lack thereof) of population dynamics. Identifying such metapopulation attributes that impact extinction risk is of utmost importance for managing and conserving the earth's evermore fragmented populations.

  16. Tracking Temperature-Dependent Relaxation Times of Ferritin Nanomagnets with a Wideband Quantum Spectrometer

    NASA Astrophysics Data System (ADS)

    Schäfer-Nolte, Eike; Schlipf, Lukas; Ternes, Markus; Reinhard, Friedemann; Kern, Klaus; Wrachtrup, Jörg

    2014-11-01

    We demonstrate the tracking of the spin dynamics of ensemble and individual magnetic ferritin proteins from cryogenic up to room temperature using the nitrogen-vacancy color center in diamond as a magnetic sensor. We employ different detection protocols to probe the influence of the ferritin nanomagnets on the longitudinal and transverse relaxation of the nitrogen-vacancy center, which enables magnetic sensing over a wide frequency range from Hz to GHz. The temperature dependence of the observed spectral features can be well understood by the thermally induced magnetization reversals of the ferritin and enables the determination of the anisotropy barrier of single ferritin molecules.

  17. Time Horizon and Social Scale in Communication

    NASA Astrophysics Data System (ADS)

    Krantz, D. H.

    2010-12-01

    In 2009 our center (CRED) published a first version of The Psychology of Climate Change Communication. In it, we attempted to summarize facts and concepts from psychological research that could help guide communication. While this work focused on climate change, most of the ideas are at least partly applicable for communication about a variety of natural hazards. Of the many examples in this guide, I mention three. Single-action bias is the human tendency to stop considering further actions that might be needed to deal with a given hazard, once a single action has been taken. Another example is the importance of group affiliation in motivating voluntary contributions to joint action. A third concerns the finding that group participation enhances understanding of probabilistic concepts and promotes action in the face of uncertainty. One current research direction, which goes beyond those included in the above publication, focuses on how time horizons arise in the thinking of individuals and groups, and how these time horizons might influence hazard preparedness. On the one hand, individuals sometimes appear impatient, organizations look for immediate results, and officials fail to look beyond the next election cycle. Yet under some laboratory conditions and in some subcultures, a longer time horizon is adopted. We are interested in how time horizon is influenced by group identity and by the very architecture of planning and decision making. Institutional changes, involving long-term contractual relationships among communities, developers, insurers, and governments, could greatly increase resilience in the face of natural hazards. Communication about hazards, in the context of such long-term contractual relationships might look very different from communication that is first initiated by immediate threat. Another new direction concerns the social scale of institutions and of communication about hazards. Traditionally, insurance contracts share risk among a large

  18. Dynamics of phosphate head groups in biomembranes. Comprehensive analysis using phosphorus-31 nuclear magnetic resonance lineshape and relaxation time measurements.

    PubMed Central

    Dufourc, E J; Mayer, C; Stohrer, J; Althoff, G; Kothe, G

    1992-01-01

    Phospholipid head group dynamics have been studied by pulsed phosphorus-31 nuclear magnetic resonance (31P-NMR) of unoriented and macroscopically aligned dimyristoylphosphatidylcholine model membranes in the temperature range, 203-343 K. Lineshapes and echo intensities have been recorded as a function of interpulse delay times, temperature and macroscopic orientation of the bilayer normal with respect to the magnetic field. The dipolar proton-phosphorus (1H-31P) contribution to the transverse relaxation time, T2E, and to lineshapes was eliminated by means of a proton spin-lock sequence. In case of longitudinal spin relaxation, T1Z, the amount of dipolar coupling was evaluated by measuring the maximum nuclear Overhauser enhancement. Hence, the results could be analyzed by considering chemical shift anisotropy as the only relaxation mechanism. The presence of various minima both in T1Z and T2E temperature plots as well as the angular dependence of these relaxation times allowed description of the dynamics of the phosphate head group in the 31P-NMR time window, by three different motional classes, i.e., intramolecular, intermolecular and collective motions. The intramolecular motions consist of two hindered rotations and one free rotation around the bonds linking the phosphate head group to the glycerol backbone. These motions are the fastest in the hierarchy of time with correlation times varying from less than 10(-12) to 10(-6) s in the temperature range investigated. The intermolecular motions are assigned to phospholipid long axis rotation and fluctuation. They have correlation times ranging from 10(-11) s at high temperatures to 10(-3) s at low temperatures. The slowest motion affecting the 31P-NMR observables is assigned to viscoelastic modes, i.e., so called order director fluctuations and is only detected at high temperatures, above the main transition in pulse frequency dependent T2ECP experiments. Comprehensive analysis of the phosphate head group dynamics

  19. Time-domain simulation of constitutive relations for nonlinear acoustics including relaxation for frequency power law attenuation media modeling

    NASA Astrophysics Data System (ADS)

    Jiménez, Noé; Camarena, Francisco; Redondo, Javier; Sánchez-Morcillo, Víctor; Konofagou, Elisa E.

    2015-10-01

    We report a numerical method for solving the constitutive relations of nonlinear acoustics, where multiple relaxation processes are included in a generalized formulation that allows the time-domain numerical solution by an explicit finite differences scheme. Thus, the proposed physical model overcomes the limitations of the one-way Khokhlov-Zabolotskaya-Kuznetsov (KZK) type models and, due to the Lagrangian density is implicitly included in the calculation, the proposed method also overcomes the limitations of Westervelt equation in complex configurations for medical ultrasound. In order to model frequency power law attenuation and dispersion, such as observed in biological media, the relaxation parameters are fitted to both exact frequency power law attenuation/dispersion media and also empirically measured attenuation of a variety of tissues that does not fit an exact power law. Finally, a computational technique based on artificial relaxation is included to correct the non-negligible numerical dispersion of the finite difference scheme, and, on the other hand, improve stability trough artificial attenuation when shock waves are present. This technique avoids the use of high-order finite-differences schemes leading to fast calculations. The present algorithm is especially suited for practical configuration where spatial discontinuities are present in the domain (e.g. axisymmetric domains or zero normal velocity boundary conditions in general). The accuracy of the method is discussed by comparing the proposed simulation solutions to one dimensional analytical and k-space numerical solutions.

  20. Linear-scaling source-sink algorithm for simulating time-resolved quantum transport and superconductivity

    NASA Astrophysics Data System (ADS)

    Weston, Joseph; Waintal, Xavier

    2016-04-01

    We report on a "source-sink" algorithm which allows one to calculate time-resolved physical quantities from a general nanoelectronic quantum system (described by an arbitrary time-dependent quadratic Hamiltonian) connected to infinite electrodes. Although mathematically equivalent to the nonequilibrium Green's function formalism, the approach is based on the scattering wave functions of the system. It amounts to solving a set of generalized Schrödinger equations that include an additional "source" term (coming from the time-dependent perturbation) and an absorbing "sink" term (the electrodes). The algorithm execution time scales linearly with both system size and simulation time, allowing one to simulate large systems (currently around 106 degrees of freedom) and/or large times (currently around 105 times the smallest time scale of the system). As an application we calculate the current-voltage characteristics of a Josephson junction for both short and long junctions, and recover the multiple Andreev reflection physics. We also discuss two intrinsically time-dependent situations: the relaxation time of a Josephson junction after a quench of the voltage bias, and the propagation of voltage pulses through a Josephson junction. In the case of a ballistic, long Josephson junction, we predict that a fast voltage pulse creates an oscillatory current whose frequency is controlled by the Thouless energy of the normal part. A similar effect is found for short junctions; a voltage pulse produces an oscillating current which, in the absence of electromagnetic environment, does not relax.

  1. Hydrogen transfer in vibrationally relaxing benzoic acid dimers: Time-dependent density matrix dynamics and infrared spectra

    NASA Astrophysics Data System (ADS)

    Scheurer, Christoph; Saalfrank, Peter

    1996-02-01

    We employ time-dependent density matrix theory to characterize the concerted double-hydrogen transfer in benzoic acid dimers—the ``system''—embedded in their crystalline environment—the ``bath.'' The Liouville-von Neumann equation for the time evolution of the reduced nuclear density matrix is solved numerically, employing one- and two-dimensional models [R. Meyer and R. R. Ernst, J. Chem. Phys. 93, 5528 (1990)], the state representation for all operators and a matrix propagator based on Newton's polynomials [M. Berman, R. Kosloff, and H. Tal-Ezer, J. Phys. A 25, 1283 (1992)]. Dissipative processes such as environment-induced vibrational energy and phase relaxation, are accounted for within the Lindblad dynamical semigroup approach. The calculation of temperature-dependent relaxation matrix elements is based on a microscopic, perturbative theory proposed earlier [R. Meyer and R. R. Ernst, J. Chem. Phys. 93, 5528 (1990)]. For the evaluation of the dissipative system dynamics, we compute (i) time-dependent state populations, (ii) energy and entropy flow between system and bath, (iii) expectation values for the hydrogen transfer coordinate, (iv) characteristic dephasing times and (v) temperature-dependent infrared spectra, determined with a recently proposed method by Neugebauer et al. Various ``pure'' and ``thermal'' nonequilibrium initial states are considered, and their equilibration with the bath followed in time.

  2. Consistent rationalization of type-2 topoisomerases' unknotting, decatenating, supercoil-relaxing actions and their scaling relation.

    PubMed

    Liu, Zhirong; Chan, Hue Sun

    2015-09-01

    How type-2 topoisomerases discern global topology from local properties of DNA is not known precisely but the hypothesis that the enzymes selectively pass double-helix strands at hook-like juxtapositions is promising. Building upon an investigation of unknotting and decatenating using an improved wormlike DNA model, here we focus primarily on the enzymes' action in narrowing the distribution of linking number (Lk) in supercoiled DNA. Consistent with experiments, with selective passage at a hooked juxtaposition, the simulated narrowing factor RLk diminishes with decreasing DNA circle size but approaches an asymptotic RLk ≈ 1.7-1.8 for circle size ≳3.5 kb. For the larger DNA circles, we found that (RLk - 1) ≈ 0.42log10RK ≈ 0.68log10RL and thus RK ≈ (RL)(1.6) holds for the computed RLk and knot and catenane reduction factors RK and RL attained by selective passage at different juxtaposition geometries. Remarkably, this general scaling relation is essentially identical to that observed experimentally for several type-2 topoisomerases from a variety of organisms, indicating that the different disentangling powers of the topoisomerases likely arise from variations in the hooked geometries they select. Taken together, our results suggest strongly that type-2 topoisomerases recognize not only the curvature of the G-segment but also that of the T-segment.

  3. Ellipsoidal Relaxation of Deformed Vesicles

    NASA Astrophysics Data System (ADS)

    Yu, Miao; Lira, Rafael B.; Riske, Karin A.; Dimova, Rumiana; Lin, Hao

    2015-09-01

    Theoretical analysis and experimental quantification on the ellipsoidal relaxation of vesicles are presented. The current work reveals the simplicity and universal aspects of this process. The Helfrich formula is shown to apply to the dynamic relaxation of moderate-to-high tension membranes, and a closed-form solution is derived which predicts the vesicle aspect ratio as a function of time. Scattered data are unified by a time scale, which leads to a similarity behavior, governed by a distinctive solution for each vesicle type. Two separate regimes in the relaxation are identified, namely, the "entropic" and the "constant-tension" regimes. The bending rigidity and the initial membrane tension can be simultaneously extracted from the data analysis, posing the current approach as an effective means for the mechanical analysis of biomembranes.

  4. Kibble-Zurek mechanism beyond adiabaticity: Finite-time scaling with critical initial slip

    NASA Astrophysics Data System (ADS)

    Huang, Yingyi; Yin, Shuai; Hu, Qijun; Zhong, Fan

    2016-01-01

    The Kibble-Zurek mechanism demands an initial adiabatic stage before an impulse stage to have a frozen correlation length that generates topological defects in a cooling phase transition. Here we study such a driven critical dynamics but with an initial condition that is near the critical point and that is far away from equilibrium. In this case, there is no initial adiabatic stage at all and thus adiabaticity is broken. However, we show that there again exists a finite length scale arising from the driving that divides the evolution into three stages. A relaxation-finite-time-scaling-adiabatic scenario is then proposed in place of the adiabatic-impulse-adiabatic scenario of the original Kibble-Zurek mechanism. A unified scaling theory, which combines finite-time scaling with critical initial slip, is developed to describe the universal behavior and is confirmed with numerical simulations of a two-dimensional classical Ising model.

  5. Time Scales, Bedforms and Bedload Transport

    NASA Astrophysics Data System (ADS)

    Dhont, B.

    2015-12-01

    Bedload transport rates in mountain streams may exhibit wide fluctuations even under constant flow conditions. A better understanding of bedload pulses is key to predict natural hazards induced by torrential activity and sediment issues in mountainous areas. Several processes such as bedforms migration, grain sorting and random particles' trajectories are evoked as the driving agents of pulse formation and development. Quantifying the effects of these processes is a difficult task. This work aims to investigate the interactions between bedload transport and bedform dynamics in steep gravel-bed rivers. Experiments are carried out in a 17-m long 60-cm wide flume inclined at an angle of 2.7%. The bed is initially flat and made of homogenous natural gravel with a mean diameter of 6 mm. We imposed 200 identical hydrographs (of 1 hr duration) at the flume inlet (the bed surface was not flattened out during these cycling floods). The input hydrograph and the input sediment discharge are nearly triangular. Bed topography is measured after each flood using ultrasound sensors while the bedload transport rate is steadily monitored at the outlet using accelerometers (accelerometers fixed on metallic plates record the impacts of the grains flowing out of the flume). For the sake of comparison, a similar experiment consisting of 19 floods of 10 hours is carried out under constant supply conditions. We show that accelerometers are a cost effective technique to obtain high-frequency bedload discharge data. Spectral analysis of the bedload timeseries is used to highlight the different time scales corresponding to different bedload transport processes. We show that long timeseries are necessary to capture the different processes that drive bedload transport, including the resilience time after a perturbation of the bed. The alternate bars that develop and migrate along the flume are found to significantly influence bedload transport rate fluctuations.

  6. Ultra-Slow Dielectric Relaxation Process in Polyols

    NASA Astrophysics Data System (ADS)

    Yomogida, Yoshiki; Minoguchi, Ayumi; Nozaki, Ryusuke

    2004-04-01

    Dielectric relaxation processes with relaxation times larger than that for the structural α process are reported for glycerol, xylitol, sorbitol and their mixtures for the first time. Appearance of this ultra-slow process depends on cooling rate. More rapid cooling gives larger dielectric relaxation strength. However, relaxation time is not affected by cooling rate and shows non-Arrhenius temperature dependence with correlation to the α process. It can be considered that non-equilibrium dynamic structure causes the ultra-slow process. Scale of such structure would be much larger than that of the region for the cooperative molecular orientations for the α process.

  7. Effect of tissue fat and water content on nuclear magnetic resonance relaxation times of cardiac and skeletal muscle.

    PubMed

    Scholz, T D; Fleagle, S R; Parrish, F C; Breon, T; Skorton, D J

    1990-01-01

    Understanding tissue determinants that affect the nuclear magnetic resonance (NMR) properties of myocardium would improve noninvasive characterization of myocardial tissue. To determine if NMR relaxation times would reflect changes in tissue fat content, two experimental models were investigated. First, an idealized model using mixtures of beef skeletal muscle and beef fat was studied to investigate the effects of a wide range of tissue fat content. Second, myocardium with varying fat content from hogs raised to have varying degrees of ponderosity was analyzed. Tissue fat and water contents and spin-lattice (T1) and spin-spin (T2) relaxation times at 20 MHz were measured. The skeletal muscle/fat mixtures ranged in fat content from 35% to 95% with water content variations from 50% to 75%. Water content decreased as fat content increased. A significant inverse linear relationship was found between T1 and sample fat content (r = -0.997). Spin-spin relaxation times showed a significant positive curvilinear relationship with fat content (r2 = 0.96). In the animal experiments, 18 hogs were studied with samples obtained from both right and left ventricular (LV) free walls, with care taken to avoid epicardial fat. Myocardial fat content ranged from 3% to 25%. A significant correlation was found between LV fat content and corrected LV mass (r = 0.62), which suggested that the increase in LV mass could be explained, at least in part, by changes in myocardial fat content. Similar to the muscle/fat mixture model, a significant positive curvilinear relationship was found between myocardial T2 and tissue fat content (r2 = 0.67) for all the myocardial samples.(ABSTRACT TRUNCATED AT 250 WORDS)

  8. An optimal modification of a Kalman filter for time scales

    NASA Technical Reports Server (NTRS)

    Greenhall, C. A.

    2003-01-01

    The Kalman filter in question, which was implemented in the time scale algorithm TA(NIST), produces time scales with poor short-term stability. A simple modification of the error covariance matrix allows the filter to produce time scales with good stability at all averaging times, as verified by simulations of clock ensembles.

  9. Graphic analysis of relaxation times of enzyme-catalysed reactions. An extension of the graphic method of King and Altman.

    PubMed Central

    Zhao, M

    1992-01-01

    An extension of the graphic method of King & Altman (1956) (J. Phys. Chem. 60, 1375-1378) is applied to the analysis of relaxation times of enzyme-catalysed reactions and a simple graphic method is presented. Clear-cut graphs, simple drawing, easy operation (without the need to perform the usual complex mathematical operations), and reliable results are the main characteristics of this kind of graphic method. A system of enzyme-catalysed reactions (E <--> ES <--> EP) is used as the actual example for illustrating the graphic method. PMID:1445198

  10. Spin relaxation and linear-in-electric-field frequency shift in an arbitrary, time-independent magnetic field

    SciTech Connect

    Clayton, Steven Michael

    2010-12-03

    A method is presented to calculate the spin relaxation times T{sub 1}, T{sub 2} due to a nonuniform magnetic field, and the linear-in-electric-field precession frequency shift {delta}{omega}{sub E} when an electric field is present, in the diffusion approximation for spins confined to a rectangular cell. It is found that the rectangular cell geometry admits of a general result for T{sub 1}, T{sub 2}, and {delta}{omega}{sub E} in terms of the spatial cosine-transform components of the magnetic field.

  11. Lattice-level observation of the elastic-to-plastic relaxation process with subnanosecond resolution in shock-compressed Ta using time-resolved in situ Laue diffraction

    DOE PAGES

    Wehrenberg, C. E.; Comley, A. J.; Barton, N. R.; Coppari, F.; Fratanduono, D.; Huntington, C. M.; Maddox, B. R.; Park, H. -S.; Plechaty, C.; Prisbrey, S. T.; et al

    2015-09-29

    We report direct lattice level measurements of plastic relaxation kinetics through time-resolved, in-situ Laue diffraction of shock-compressed single-crystal [001] Ta at pressures of 27-210 GPa. For a 50 GPa shock, a range of shear strains is observed extending up to the uniaxial limit for early data points (<0.6 ns) and the average shear strain relaxes to a near steady state over ~1 ns. For 80 and 125 GPa shocks, the measured shear strains are fully relaxed already at 200 ps, consistent with rapid relaxation associated with the predicted threshold for homogeneous nucleation of dislocations occurring at shock pressure ~65 GPa.more » The relaxation rate and shear stresses are used to estimate the dislocation density and these quantities are compared to the Livermore Multiscale Strength model as well as various molecular dynamics simulations.« less

  12. Scaling of Langevin and molecular dynamics persistence times of nonhomogeneous fluids.

    PubMed

    Olivares-Rivas, Wilmer; Colmenares, Pedro J

    2012-01-01

    The existing solution for the Langevin equation of an anisotropic fluid allowed the evaluation of the position-dependent perpendicular and parallel diffusion coefficients, using molecular dynamics data. However, the time scale of the Langevin dynamics and molecular dynamics are different and an ansatz for the persistence probability relaxation time was needed. Here we show how the solution for the average persistence probability obtained from the backward Smoluchowski-Fokker-Planck equation (SE), associated to the Langevin dynamics, scales with the corresponding molecular dynamics quantity. Our SE perpendicular persistence time is evaluated in terms of simple integrals over the equilibrium local density. When properly scaled by the perpendicular diffusion coefficient, it gives a good match with that obtained from molecular dynamics. PMID:22400522

  13. Scaling of Langevin and molecular dynamics persistence times of nonhomogeneous fluids.

    PubMed

    Olivares-Rivas, Wilmer; Colmenares, Pedro J

    2012-01-01

    The existing solution for the Langevin equation of an anisotropic fluid allowed the evaluation of the position-dependent perpendicular and parallel diffusion coefficients, using molecular dynamics data. However, the time scale of the Langevin dynamics and molecular dynamics are different and an ansatz for the persistence probability relaxation time was needed. Here we show how the solution for the average persistence probability obtained from the backward Smoluchowski-Fokker-Planck equation (SE), associated to the Langevin dynamics, scales with the corresponding molecular dynamics quantity. Our SE perpendicular persistence time is evaluated in terms of simple integrals over the equilibrium local density. When properly scaled by the perpendicular diffusion coefficient, it gives a good match with that obtained from molecular dynamics.

  14. Comparison of different pulse sequences for in vivo determination of T1 relaxation times in the human brain.

    PubMed

    Kjaer, L; Henriksen, O

    1988-01-01

    Quantitative in vivo determination of T1 relaxation times by magnetic resonance imaging (MRI) is hampered by several potential sources of error. This study focused on the influence of the radiofrequency pulse sequences applied with special attention to the significance of the repetition time (TR). T1 measurements were performed on the human brain using a whole body MR scanner operating at 1.5 tesla. Three different pulse sequences were compared including two 6-points inversion recovery (IR) sequences with TR = 2.0 s and 4.0, respectively, and a 12-points partial saturation inversion recovery (PSIR) sequence with TR varying between 0.24 and 8.0 s. The median T1 relaxation times obtained in cortical grey matter and cerebrospinal fluid were significantly shorter in the IR experiments at TR = 2 s than in those carried out at TR = 4 s. Concerning white matter the discrepancy was much less pronounced, but still statistically significant. Supplementary phantom measurements indicated that the higher T1 values are increasingly underestimated when TR is reduced to 2 s. The results suggest that the PSIR sequence or IR sequences with a TR greater than 2 X the T1 level of the tissue type investigated should be employed for accurate T1 determination by MRI in clinical work.

  15. Helium-3 relaxation time measurements at low temperatures for the neutron electric dipole moment (nEDM) experiment

    NASA Astrophysics Data System (ADS)

    Ye, Qiang

    The search for the existence of a nonzero neutron electric dipole moment (nEDM) has the potential to reveal new sources of T and CP violation beyond the Standard Model and may have a significant impact on our understanding of the universe. A new experiment aiming at two orders of magnitude improvement (˜ 10--28 e·cm) over the current experimental upper limit has been proposed in the United States. In the experiment, the measurement cell will be made of dTPB-dPS coated acrylic and filled with superfluid 4He at ˜300-500 mK. The measurement of the neutron precession frequency will rely on the spin-dependence of the cross section of the nuclear reaction between polarized neutrons and 3He atoms: n⃗+H3 ⃗e → p + t + 764 keV. Polarized 3He will also be used as a comagnetometer based on the nuclear magnetic resonance technique. The 3He polarization needs to have sufficiently long relaxation time so that little polarization is lost during the measurement period in order to achieve the proposed sensitivity. Understanding the relaxation mechanism of 3He polarization in the measurement cell under the nEDM experimental conditions and maintaining 3He polarization is crucial for the experiment. With the presence of superfluid 4He, 3He relaxation time measurements in a dTPB-dPS coated cylindrical acrylic cell at the temperature of 1.9 K and ˜400 mK have been performed at the Triangle University Nuclear Laboratory (TUNL) on the campus of Duke University. The extracted depolarization probabilities of polarized 3He on the cell surface are on the order of (1 -- 2) x 10--7 at 1.9 K and ˜ 4.7 x 10--7 at ˜400 mK. The extrapolated relaxation time of polarized 3He in the nEDM cell geometry is ˜ 4870 seconds at ˜400 mK, which is sufficiently long for the nEDM experiment and further improvements are anticipated.

  16. A two-time-scale, two-temperature scenario for nonlinear rheology

    PubMed

    Berthier; Barrat; Kurchan

    2000-05-01

    We investigate a general scenario for "glassy" or "jammed" systems driven by an external, nonconservative force, analogous to a shear force in a fluid. In this scenario, the drive results in the suppression of the usual aging process, and the correlation and response functions become time translation invariant. The relaxation time and the response functions are then dependent on the intensity of the drive and on temperature. We investigate this dependence within the framework of a dynamical closure approximation that becomes exact for disordered, fully connected models. The relaxation time is shown to be a decreasing function of the drive ("shear thinning" effect). The correlation functions below the glass transition temperature (Tc) display a two-time-scale relaxation pattern, similar to that observed at equilibrium slightly above Tc. We also study the violation of the fluctuation-dissipation relationship in the driven system. This violation is very reminiscent of the one that takes place in a system aging below Tc at zero drive. It involves, in particular the appearance of a two-temperature regime, in the sense of an effective fluctuation-dissipation temperature [L. F. Cugliandolo, J. Kurchan, and L. Peliti, Phys. Rev. E 55, 3898 (1997)]. Although our results are, in principle, limited to the closure relations that hold for mean-field models, we argue that a number of the salient features are not inherent to the approximation scheme, and may be tested in experiments and simulations. PMID:11031599

  17. Teaching about time by understanding Geologic Time Scales: The Geological Society of America Geologic Time Scale and its history

    NASA Astrophysics Data System (ADS)

    Geissman, J. W.; Walker, J. D.

    2012-12-01

    Geologic time scales, of one form or another, are used in most undergraduate geosciences courses, even including introductory physical geology or equivalent. However, satisfactory discussions of how geologic time scales originated, and how they have evolved to modern versions, are far too often conveniently or inconveniently left out of classroom discussions. Yet it is these kinds of discussions that have the potential of solidifying student appreciation of deep time and rates of geologic processes. We use the history and development of the Geological Society of America Geologic Time Scale, which reflects major developments in the fields of stratigraphy, geochronology, magnetic polarity stratigraphy, astrochronology, and chemostratigraphy, as a focus of how specific details of time scales can be used to teach about time. Advances in all of these fields have allowed many parts of the time scale to be calibrated to precisions approaching less than 0.05 %. Notable time intervals for which collaborative, multifaceted efforts have led to dramatic improvements in our understanding of the character and temporal resolution of key evolutionary events, in both marine and terrestrial environments, include the Triassic-Jurassic, Permo-Triassic, and Neoproterozoic-Phanerozoic boundaries (or transitions). Many of the details, but certainly not all, can be incorporated in discussions of how we know about geologic time in the classroom. For example, we presently understand that both the end-Permian ecological crisis and the biostratigraphic Permian-Triassic boundary, as calibrated by conodonts, lie within a ca. 700 ka long normal polarity chron. The reverse to normal polarity transition at the beginning of this chron is ca. 100 ka earlier than the ecological crisis and thus slightly older than the current estimate, based on high precision U-Pb zircon age determinations, of ca. 252.4 Ma for the Permian-Triassic boundary. This polarity transition occurred during the early part of

  18. Detection of crossover time scales in multifractal detrended fluctuation analysis

    NASA Astrophysics Data System (ADS)

    Ge, Erjia; Leung, Yee

    2013-04-01

    Fractal is employed in this paper as a scale-based method for the identification of the scaling behavior of time series. Many spatial and temporal processes exhibiting complex multi(mono)-scaling behaviors are fractals. One of the important concepts in fractals is crossover time scale(s) that separates distinct regimes having different fractal scaling behaviors. A common method is multifractal detrended fluctuation analysis (MF-DFA). The detection of crossover time scale(s) is, however, relatively subjective since it has been made without rigorous statistical procedures and has generally been determined by eye balling or subjective observation. Crossover time scales such determined may be spurious and problematic. It may not reflect the genuine underlying scaling behavior of a time series. The purpose of this paper is to propose a statistical procedure to model complex fractal scaling behaviors and reliably identify the crossover time scales under MF-DFA. The scaling-identification regression model, grounded on a solid statistical foundation, is first proposed to describe multi-scaling behaviors of fractals. Through the regression analysis and statistical inference, we can (1) identify the crossover time scales that cannot be detected by eye-balling observation, (2) determine the number and locations of the genuine crossover time scales, (3) give confidence intervals for the crossover time scales, and (4) establish the statistically significant regression model depicting the underlying scaling behavior of a time series. To substantive our argument, the regression model is applied to analyze the multi-scaling behaviors of avian-influenza outbreaks, water consumption, daily mean temperature, and rainfall of Hong Kong. Through the proposed model, we can have a deeper understanding of fractals in general and a statistical approach to identify multi-scaling behavior under MF-DFA in particular.

  19. Le Chatelier's principle with multiple relaxation channels

    NASA Astrophysics Data System (ADS)

    Gilmore, R.; Levine, R. D.

    1986-05-01

    Le Chatelier's principle is discussed within the constrained variational approach to thermodynamics. The formulation is general enough to encompass systems not in thermal (or chemical) equilibrium. Particular attention is given to systems with multiple constraints which can be relaxed. The moderation of the initial perturbation increases as additional constraints are removed. This result is studied in particular when the (coupled) relaxation channels have widely different time scales. A series of inequalities is derived which describes the successive moderation as each successive relaxation channel opens up. These inequalities are interpreted within the metric-geometry representation of thermodynamics.

  20. Estimate of blow-up and relaxation time for self-gravitating Brownian particles and bacterial populations.

    PubMed

    Chavanis, P-H; Sire, C

    2004-08-01

    We determine an exact asymptotic expression of the blow-up time t(coll) for self-gravitating Brownian particles or bacterial populations (chemotaxis) close to the critical point in d=3. We show that t(coll) = t(*) (eta- eta(c) )(-1/2) with t(*) =0.917 677 02..., where eta represents the inverse temperature (for Brownian particles) or the mass (for bacterial colonies), and eta(c) is the critical value of eta above which the system blows up. This result is in perfect agreement with the numerical solution of the Smoluchowski-Poisson system. We also determine the exact asymptotic expression of the relaxation time close to but above the critical temperature and derive a large time asymptotic expansion for the density profile exactly at the critical point.

  1. Evaluation of the kinetic and relaxation time of gentamicin sulfate released from hybrid biomaterial Bioglass-chitosan scaffolds

    NASA Astrophysics Data System (ADS)

    Wers, E.; Oudadesse, H.; Lefeuvre, B.; Merdrignac-Conanec, O.; Barroug, A.

    2015-10-01

    Chitosan scaffolds, combined with bioactive glass 46S6, were prepared to serve as gentamicin sulfate delivery in situ systems for bone biomaterials. This work presents a study about the effect of the ratio chitosan/bioactive glass (CH/BG) on the release of gentamicin sulfate and on the bioactivity during in vitro experiments. SEM observations allowed understanding the bond between the glass grains and the chitosan matrix. In vitro results showed that scaffolds form a hydroxyapatite (HA) Ca10(PO4)6(OH)2 after 15 days of immersion in a simulated body fluid (SBF).The interest of this study is to see that the increase of the content of bioactive glass in the chitosan matrix slows the release of gentamicin sulfate in the liquid medium. Starting concentration of gentamicin sulfate has an influence on the relaxation time of the scaffolds. Indeed, an increasing concentration delays the return to a new equilibrium. Contents of chitosan and bioactive glass do not affect the relaxation time. Synthesized scaffolds could be adapted to a clinical situation: severity and type of infection, weight and age of the patient.

  2. Hyperpolarized 13C NMR lifetimes in the liquid-state: relating structures and T1 relaxation times

    NASA Astrophysics Data System (ADS)

    Parish, Christopher; Niedbalski, Peter; Hashami, Zohreh; Fidelino, Leila; Kovacs, Zoltan; Lumata, Lloyd

    Among the various attempts to solve the insensitivity problem in nuclear magnetic resonance (NMR), the physics-based technique dissolution dynamic nuclear polarization (DNP) is probably the most successful method of hyperpolarization or amplifying NMR signals. Using this technique, liquid-state NMR signal enhancements of several thousand-fold are expected for low-gamma nuclei such as carbon-13. The lifetimes of these hyperpolarized 13C NMR signals are directly related to their 13C spin-lattice relaxation times T1. Depending upon the 13C isotopic location, the lifetimes of hyperpolarized 13C compounds can range from a few seconds to minutes. In this study, we have investigated the hyperpolarized 13C NMR lifetimes of several 13C compounds with various chemical structures from glucose, acetate, citric acid, naphthalene to tetramethylallene and their deuterated analogs at 9.4 T and 25 deg C. Our results show that the 13C T1s of these compounds can range from a few seconds to more than 60 s at this field. Correlations between the chemical structures and T1 relaxation times will be discussed and corresponding implications of these results on 13C DNP experiments will be revealed. US Dept of Defense Award No. W81XWH-14-1-0048 and Robert A. Welch Foundation Grant No. AT-1877.

  3. Time scales in Galveston Bay: An unsteady estuary

    NASA Astrophysics Data System (ADS)

    Rayson, Matthew D.; Gross, Edward S.; Hetland, Robert D.; Fringer, Oliver B.

    2016-04-01

    Estuarine time scales including the turnover, particle e-folding time, the age (calculated with a passive tracer), and residence time (calculated with Lagrangian particles) were computed using a three-dimensional hydrodynamic model of Galveston Bay, a low-flow, partially stratified estuary. Time scales were computed during a time period when river flow varied by several orders of magnitude and all time scales therefore exhibited significant temporal variability because of the unsteadiness of the system. The spatial distributions of age and residence time were qualitatively similar and increased from 15 days in a shipping channel to >45 days in the upper estuary. Volume-averaged age and residence time decreased during high-flow conditions. Bulk time scales, including the freshwater and salinity turnover times, were far more variable due to the changing river discharge and salt flux through the estuary mouth. A criterion for calculating a suitable averaging time is discussed to satisfy a steady state assumption and to estimate a more representative bulk time scale. When scaled with a freshwater advective time, all time scales were approximately equal to the advective time scale during high-flow conditions and many times higher during low-flow conditions. The mean age, Lagrangian residence, and flushing times exhibited a relationship that was weakly dependent on the freshwater advective time scale demonstrating predictability even in an unsteady, realistic estuary.

  4. Kinetics of isothermal structural relaxation in metallic glasses measured by real-time diffraction using synchrotron radiation

    NASA Astrophysics Data System (ADS)

    Hajlaoui, K.; Yousfi, M. A.; Ouelhazi, I.; Georgarakis, K.; Tourki, Z.; Vaughan, G.; Yavari, A. R.

    2011-02-01

    Quantitative measurements of the excess free volume in Pd40Cu30Ni10P20 and Cu55Zr30Ti10Pd5 metallic glasses during in situ isothermal annealing at various temperatures are used to identify physical parameters of structural relaxation in metallic glasses and to discuss proposed models describing this process. The free-volume model is found to provide a simple and predictive description for structural relaxation phenomena. We show that structural relaxation kinetics follows a second-order law in a satisfactory manner. The activation energy for relaxation is found to depend on annealing temperature and the extent of structural relaxation.

  5. A Quaternary Geomagnetic Instability Time Scale

    NASA Astrophysics Data System (ADS)

    Singer, B. S.

    2013-12-01

    Reversals and excursions of Earth's geomagnetic field create marker horizons that are readily detected in sedimentary and volcanic rocks worldwide. An accurate and precise chronology of these geomagnetic field instabilities is fundamental to understanding several aspects of Quaternary climate, dynamo processes, and surface processes. For example, stratigraphic correlation between marine sediment and polar ice records of climate change across the cryospheres benefits from a highly resolved record of reversals and excursions. The temporal patterns of dynamo behavior may reflect physical interactions between the molten outer core and the solid inner core or lowermost mantle. These interactions may control reversal frequency and shape the weak magnetic fields that arise during successive dynamo instabilities. Moreover, weakening of the axial dipole during reversals and excursions enhances the production of cosmogenic isotopes that are used in sediment and ice core stratigraphy and surface exposure dating. The Geomagnetic Instability Time Scale (GITS) is based on the direct dating of transitional polarity states recorded by lava flows using the 40Ar/39Ar method, in parallel with astrochronologic age models of marine sediments in which O isotope and magnetic records have been obtained. A review of data from Quaternary lava flows and sediments yields a GITS comprising 10 polarity reversals and 27 excursions during the past 2.6 million years. Nine of the ten reversals bounding chrons and subchrons are associated with 40Ar/39Ar ages of transitionally-magnetized lava flows. The tenth, the Guass-Matuyama chron boundary, is tightly bracketed by 40Ar/39Ar dated ash deposits. Of the 27 well-documented excursions, 14 occurred during the Matuyama chron and 13 during the Brunhes chron; 19 have been dated directly using the 40Ar/39Ar method on transitionally-magnetized volcanic rocks and form the backbone of the GITS. Excursions are clearly not the rare phenomena once thought

  6. Spin and Time-Reversal Symmetries of Superconducting Electron Pairs Probed by the Muon Spin Rotation and Relaxation Technique

    NASA Astrophysics Data System (ADS)

    Higemoto, Wataru; Aoki, Yuji; MacLaughlin, Douglas E.

    2016-09-01

    Unconventional superconductivity based on the strong correlation of electrons is one of the central issues of solid-state physics. Although many experimental techniques are appropriate for investigating unconventional superconductivity, a complete perspective has not been established yet. The symmetries of electron pairs are crucial properties for understanding the essential state of unconventional superconductivity. In this review, we discuss the investigation of the time-reversal and spin symmetries of superconducting electron pairs using the muon spin rotation and relaxation technique. By detecting a spontaneous magnetic field under zero field and/or the temperature dependence of the muon Knight shift in the superconducting phase, the time-reversal symmetry and spin parity of electron pairs have been determined for several unconventional superconductors.

  7. Asymptotic dependence of the relaxation time of the magnetization of a ferromagnetic particle on the anisotropy of the particle

    NASA Astrophysics Data System (ADS)

    Scully, C. N.; Cregg, P. J.; Crothers, D. S. F.

    1992-01-01

    It is known that the direction of the magnetization vector of very fine single-domain ferromagnetic particles fluctuates under the influence of thermal agitation. Perturbation theory is applied rigorously to a singular integral equation to derive an asymptotic formula for the relaxation time of the magnetization, for the case of uniaxial anisotropy and an applied magnetic field. The result agrees with that of Brown [Phys. Rev. 130, 1677 (1963)] as described succinctly by Aharoni [Phys. Rev. 177, 793 (1969)]. It should be emphasized that both Gilbert's equation and the earlier Landau-Lifshitz equation are merely phenomenological equations, which are used to explain the time decay of the average magnetization. Brown suggested that the Gilbert equation should be augmented by a white-noise driving term in order to explain the effect of thermal fluctuations of the surroundings on the magnetization.

  8. Concentration Regimes of Biopolymers Xanthan, Tara, and Clairana, Comparing Dynamic Light Scattering and Distribution of Relaxation Time

    PubMed Central

    Oliveira, Patrícia D.; Michel, Ricardo C.; McBride, Alan J. A.; Moreira, Angelita S.; Lomba, Rosana F. T.; Vendruscolo, Claire T.

    2013-01-01

    The aim of this work was to evaluate the utilization of analysis of the distribution of relaxation time (DRT) using a dynamic light back-scattering technique as alternative method for the determination of the concentration regimes in aqueous solutions of biopolymers (xanthan, clairana and tara gums) by an analysis of the overlap (c*) and aggregation (c**) concentrations. The diffusion coefficients were obtained over a range of concentrations for each biopolymer using two methods. The first method analysed the behaviour of the diffusion coefficient as a function of the concentration of the gum solution. This method is based on the analysis of the diffusion coefficient versus the concentration curve. Using the slope of the curves, it was possible to determine the c* and c** for xanthan and tara gum. However, it was not possible to determine the concentration regimes for clairana using this method. The second method was based on an analysis of the DRTs, which showed different numbers of relaxation modes. It was observed that the concentrations at which the number of modes changed corresponded to the c* and c**. Thus, the DRT technique provided an alternative method for the determination of the critical concentrations of biopolymers. PMID:23671627

  9. Climate change relaxes the time constraints for late-born offspring in a long-distance migrant.

    PubMed

    Tomotani, Barbara M; Gienapp, Phillip; Beersma, Domien G M; Visser, Marcel E

    2016-09-28

    Animals in seasonal environments need to fit their annual-cycle stages, such as moult and migration, in a tight schedule. Climate change affects the phenology of organisms and causes advancements in timing of these annual-cycle stages but not necessarily at the same rates. For migratory birds, this can lead to more severe or more relaxed time constraints in the time from fledging to migration, depending on the relative shifts of the different stages. We tested how a shift in hatch date, which has advanced due to climate change, impacts the organization of the birds' whole annual cycle. We experimentally advanced and delayed the hatch date of pied flycatcher chicks in the field and then measured the timing of their annual-cycle stages in a controlled laboratory environment. Hatch date affected the timing of moult and pre-migratory fattening, but not migration. Early-born birds hence had a longer time to fatten up than late-born ones; the latter reduced their interval between onset of fattening and migration to be able to migrate at the same time as the early-born birds. This difference in time constraints for early- and late-born individuals may explain why early-born offspring have a higher probability to recruit as a breeding bird. Climate change-associated advancements of avian egg-lay dates, which in turn advances hatch dates, can thus reduce the negative fitness consequences of reproducing late, thereby reducing the selection for early egg-laying migratory birds.

  10. Phase transitions in semidefinite relaxations

    PubMed Central

    Javanmard, Adel; Montanari, Andrea; Ricci-Tersenghi, Federico

    2016-01-01

    Statistical inference problems arising within signal processing, data mining, and machine learning naturally give rise to hard combinatorial optimization problems. These problems become intractable when the dimensionality of the data is large, as is often the case for modern datasets. A popular idea is to construct convex relaxations of these combinatorial problems, which can be solved efficiently for large-scale datasets. Semidefinite programming (SDP) relaxations are among the most powerful methods in this family and are surprisingly well suited for a broad range of problems where data take the form of matrices or graphs. It has been observed several times that when the statistical noise is small enough, SDP relaxations correctly detect the underlying combinatorial structures. In this paper we develop asymptotic predictions for several detection thresholds, as well as for the estimation error above these thresholds. We study some classical SDP relaxations for statistical problems motivated by graph synchronization and community detection in networks. We map these optimization problems to statistical mechanics models with vector spins and use nonrigorous techniques from statistical mechanics to characterize the corresponding phase transitions. Our results clarify the effectiveness of SDP relaxations in solving high-dimensional statistical problems. PMID:27001856

  11. Phase transitions in semidefinite relaxations.

    PubMed

    Javanmard, Adel; Montanari, Andrea; Ricci-Tersenghi, Federico

    2016-04-19

    Statistical inference problems arising within signal processing, data mining, and machine learning naturally give rise to hard combinatorial optimization problems. These problems become intractable when the dimensionality of the data is large, as is often the case for modern datasets. A popular idea is to construct convex relaxations of these combinatorial problems, which can be solved efficiently for large-scale datasets. Semidefinite programming (SDP) relaxations are among the most powerful methods in this family and are surprisingly well suited for a broad range of problems where data take the form of matrices or graphs. It has been observed several times that when the statistical noise is small enough, SDP relaxations correctly detect the underlying combinatorial structures. In this paper we develop asymptotic predictions for several detection thresholds, as well as for the estimation error above these thresholds. We study some classical SDP relaxations for statistical problems motivated by graph synchronization and community detection in networks. We map these optimization problems to statistical mechanics models with vector spins and use nonrigorous techniques from statistical mechanics to characterize the corresponding phase transitions. Our results clarify the effectiveness of SDP relaxations in solving high-dimensional statistical problems. PMID:27001856

  12. On time scales and time synchronization using LORAN-C as a time reference signal

    NASA Technical Reports Server (NTRS)

    Chi, A. R.

    1974-01-01

    The long term performance of the eight LORAN-C chains is presented in terms of the Coordinated Universal Time (UTC) of the U.S. Naval Observatory (USNO); and the use of the LORAN-C navigation system for maintaining the user's clock to a UTC scale is described. The atomic time scale and the UTC of several national laboratories and observatories relative to the international atomic time are reported. Typical performance of several NASA tracking station clocks, relative to the USNO master clock, is also presented.

  13. Measurement of solute proton spin-lattice relaxation times in water using the 1,3,3,1 sequence

    SciTech Connect

    Sankar, S.S.; Mole, P.A.; Coulson, R.L.

    1986-12-01

    /sup 1/H NMR spin-lattice relaxation times (T1) of the N-CH3 proton resonances of phosphocreatine (PCr) and creatine (Cr) in water solutions were obtained using the 1,3,3,1 pulse sequence. These T1 values were equivalent to those obtained in D/sub 2/O and water using either the conventional inversion-recovery experiment or the 1,3,3,1 pulse sequence. Thus, the 1,3,3,1 sequence of proton NMR can provide an independent means along with phosphorous NMR for assess PCr and for the study of the creatine kinase reaction (PCr + ADP in equilibrium ATP + Cr) in aqueous solutions and perhaps in biological preparations.

  14. Laterally localizing potential as a tool for controlling the electron spin relaxation time in GaAs quantum wells

    SciTech Connect

    Larionov, A. V.; Il’in, A. I.

    2013-12-15

    The coherent spin dynamics of electrons localized in a plane of GaAs quantum wells is studied experimentally by the application of an electrically controlled potential. The localizing potential is produced with the use of a metal gate with submicrometer windows deposited onto the sample surface. The photoinduced spin Kerr effect is used to study the electron spin lifetime as a function of the temperature, applied bias, and magnetic field for gates with different sets of windows. It is shown that, with an electrically controlled laterally localizing potential, it is possible to gradually change the electron spin lifetime from several hundreds of picoseconds to several tens of nanoseconds. The dependence of the electron spin relaxation time on the sizes of the lateral localization region is in good qualitative agreement with theoretical prediction.

  15. Spin-echo methods for the determination of 31P transverse relaxation times of the ATP NMR signals in vivo.

    PubMed

    Straubinger, K; Jung, W I; Bunse, M; Lutz, O; Küper, K; Dietze, G

    1994-01-01

    31P magnetic resonance spectroscopy (MRS) examinations of the calf muscles of healthy volunteers were performed to determine T2 of the coupled ATP signals by use of the Hahn spin-echo and the frequency-selective spin-echo method. Additional measurements with the J-coupling refocused double echo are presented. The most reliable determination of T2 relaxation times is possible with the frequency-selective spin echo. The other methods yield substantially wrong results. Theoretical explanations are given how J-coupling and pulse-angle deviations affect the signals and therefore the T2 determinations. The calculations for a weakly coupled homonuclear AX spin system are shown because they demonstrate most of the relevant facts. In addition, some important results for a homonuclear AMX spin system, which the ATP is considered to be, are given.

  16. An Adaptive Fourier Filter for Relaxing Time Stepping Constraints for Explicit Solvers

    SciTech Connect

    Gelb, Anne; Archibald, Richard K

    2015-01-01

    Filtering is necessary to stabilize piecewise smooth solutions. The resulting diffusion stabilizes the method, but may fail to resolve the solution near discontinuities. Moreover, high order filtering still requires cost prohibitive time stepping. This paper introduces an adaptive filter that controls spurious modes of the solution, but is not unnecessarily diffusive. Consequently we are able to stabilize the solution with larger time steps, but also take advantage of the accuracy of a high order filter.

  17. Knee muscle strength correlates with joint cartilage T2 relaxation time in young participants with risk factors for osteoarthritis.

    PubMed

    Macías-Hernández, Salvador Israel; Miranda-Duarte, Antonio; Ramírez-Mora, Isabel; Cortés-González, Socorro; Morones-Alba, Juan Daniel; Olascoaga-Gómez, Andrea; Coronado-Zarco, Roberto; Soria-Bastida, María de Los Angeles; Nava-Bringas, Tania Inés; Cruz-Medina, Eva

    2016-08-01

    The objective of this study is to correlate T2 relaxation time (T2RT), measured by magnetic resonance imaging (MRI) with quadriceps and hamstring strength in young participants with risk factors for knee osteoarthritis (OA). A descriptive cross-sectional study was conducted with participants between 20 and 40 years of age, without diagnosis of knee OA. Their T2 relaxation time was measured through MRI, and their muscle strength (MS) was measured with an isokinetic dynamometer. Seventy-one participants were recruited, with an average age of 28.3 ± 5.5 years; 39 (55 %) were females. Negative correlations were found between T2RT and quadriceps peak torque (QPT) in males in the femur r = -0.46 (p = 0.01), tibia r = -0.49 (p = 0.02), and patella r = -0.44 (p = 0.01). In women, correlations were found among the femur r = -0.43 (p = 0.01), tibia r = -0.61 (p = 0.01), and patella r = -0.32 (p = 0.05) and among hamstring peak torque (HPT), in the femur r = -0.46 (p = 0.01), hamstring total work (HTW) r = -0.42 (p = 0.03), and tibia r = -0.33 (p = 0.04). Linear regression models showed good capacity to predict T2RT through QPT in both genders. The present study shows that early changes in femoral, tibial, and patellar cartilage are significantly correlated with MS, mainly QPT, and that these early changes might be explained by MS, which could play an important role in pre-clinical phases of the disease.

  18. Anomalous D'yakonov-Perel' spin relaxation in semiconductor quantum wells under a strong magnetic field in the Voigt configuration

    NASA Astrophysics Data System (ADS)

    Zhou, Y.; Yu, T.; Wu, M. W.

    2013-06-01

    We report an anomalous scaling of the D’yakonov-Perel’ spin relaxation with the momentum relaxation in semiconductor quantum wells under a strong magnetic field in the Voigt configuration. We focus on the case in which the external magnetic field is perpendicular to the spin-orbit-coupling-induced effective magnetic field and its magnitude is much larger than the latter one. It is found that the longitudinal spin relaxation time is proportional to the momentum relaxation time even in the strong-scattering limit, indicating that the D’yakonov-Perel’ spin relaxation demonstrates Elliott-Yafet-like behavior. Moreover, the transverse spin relaxation time is proportional (inversely proportional) to the momentum relaxation time in the strong- (weak-) scattering limit, both in the opposite trends against the well-established conventional D’yakonov-Perel’ spin relaxation behaviors. We further demonstrate that all the above anomalous scaling relations come from the unique form of the effective inhomogeneous broadening.

  19. Evidences of a Common Scaling Under Cooling and Compression for Slow and Fast Relaxations: Relevance of Local Modes for the Glass Transition

    NASA Astrophysics Data System (ADS)

    Capaccioli, S.; Kessairi, K.; Prevosto, D.; Thayyil, Md. Shahin; Lucchesi, M.; Rolla, P. A.

    The present study demonstrates, by means of broadband dielectric measurements, that the primary α- and the secondary Johari-Goldstein (JG) β-processes are strongly correlated, in contrast with the widespread opinion of statistical independence of these processes. This occurs for different glass-forming systems, over a wide temperature and pressure range. In fact, we found that the ratio of the α- and β- relaxation times is invariant when calculated at different combinations of P and T that maintain either the primary or the JG relaxation times constant. The α-β interdependence is quantitatively confirmed by the clear dynamic scenario of two master curves (one for α-, one for β-relaxation) obtained when different isothermal and isobaric data are plotted together versus the reduced variable T g (P)/T, where T g is the glass transition temperature. Additionally, the α-β mutual dependence is confirmed by the overall superposition of spectra measured at different T-P combinations but with an invariant α-relaxation time.

  20. On the Uncertainty of the Annular Mode Time Scale

    NASA Astrophysics Data System (ADS)

    Kim, Junsu; Reichler, Thomas

    2015-04-01

    The proper simulation of the annular mode (AM) time scale may be regarded as an important benchmark for climate models. Previous research demonstrated that climate models systematically overestimate this time scale. As suggested by the fluctuation-dissipation theorem, this may imply that models are overly sensitive to external forcings. Previous research also made it clear that calculating the AM time scale is a slowly converging process, necessitating relatively long time series and casting doubts on the usefulness of the historical reanalysis record to constrain climate models in terms of the AM time scale. Here, we use a 4000-year-long control simulation with the GFDL climate model CM2.1 to study the effects of internal atmospheric variability on the stability of the AM time scale. In particular, we ask whether a model's AM time scale and climate sensitivity can be constrained from the 50-year-long reanalysis record. We find that internal variability attaches large uncertainty to the AM time scale when diagnosed from decadal records. Even under fixed forcing conditions, at least 100 years of data are required in order to keep the uncertainty in the AM time scale of the Northern Hemisphere to 10%; over the Southern Hemisphere the required length increases to 200 years. If nature's AM time scale is similarly variable, there is no guarantee that the historical reanalysis record is a fully representative target for model evaluation. We further use the model simulation to investigate the dynamical coupling between the stratosphere and the troposphere from the perspective of the AM time scale. Over the Northern Hemisphere we find only weak indication for influences from stratosphere-troposphere coupling on the AM time scale. The situation is very different over the Southern Hemisphere, where we find robust connections between the AM time scale in the stratosphere and that in the troposphere, confirming and extending earlier results of influences of stratospheric

  1. Determining characteristic plastic-relaxation times using micro- and nanocrystalline nickel as an example

    NASA Astrophysics Data System (ADS)

    Borodin, E. N.; Selyutina, N. S.; Petrov, Yu. V.

    2016-03-01

    Based on the concept of the incubation time of plastic deformation, an integral yield criterion is introduced and time effects of irreversible deformation are considered. The efficiency of the approach is demonstrated using micro and nanocrystalline nickel as an example. The parameters of the phenomenological model are treated physically from the viewpoint of the behavior of the defect structure of the material, which is controlled by the dislocation sliding and grain-boundary slip mechanisms in a wide range of the rate of deformation.

  2. Scale-dependent intrinsic entropies of complex time series.

    PubMed

    Yeh, Jia-Rong; Peng, Chung-Kang; Huang, Norden E

    2016-04-13

    Multi-scale entropy (MSE) was developed as a measure of complexity for complex time series, and it has been applied widely in recent years. The MSE algorithm is based on the assumption that biological systems possess the ability to adapt and function in an ever-changing environment, and these systems need to operate across multiple temporal and spatial scales, such that their complexity is also multi-scale and hierarchical. Here, we present a systematic approach to apply the empirical mode decomposition algorithm, which can detrend time series on various time scales, prior to analysing a signal's complexity by measuring the irregularity of its dynamics on multiple time scales. Simulated time series of fractal Gaussian noise and human heartbeat time series were used to study the performance of this new approach. We show that our method can successfully quantify the fractal properties of the simulated time series and can accurately distinguish modulations in human heartbeat time series in health and disease.

  3. Timing signatures of large scale solar eruptions

    NASA Astrophysics Data System (ADS)

    Balasubramaniam, K. S.; Hock-Mysliwiec, Rachel; Henry, Timothy; Kirk, Michael S.

    2016-05-01

    We examine the timing signatures of large solar eruptions resulting in flares, CMEs and Solar Energetic Particle events. We probe solar active regions from the chromosphere through the corona, using data from space and ground-based observations, including ISOON, SDO, GONG, and GOES. Our studies include a number of flares and CMEs of mostly the M- and X-strengths as categorized by GOES. We find that the chromospheric signatures of these large eruptions occur 5-30 minutes in advance of coronal high temperature signatures. These timing measurements are then used as inputs to models and reconstruct the eruptive nature of these systems, and explore their utility in forecasts.

  4. Stress Relaxation for Granular Materials near Jamming under Cyclic Compression

    NASA Astrophysics Data System (ADS)

    Farhadi, Somayeh; Zhu, Alex Z.; Behringer, Robert P.

    2015-10-01

    We have explored isotropically jammed states of semi-2D granular materials through cyclic compression. In each compression cycle, systems of either identical ellipses or bidisperse disks transition between jammed and unjammed states. We determine the evolution of the average pressure P and structure through consecutive jammed states. We observe a transition point ϕm above which P persists over many cycles; below ϕm, P relaxes slowly. The relaxation time scale associated with P increases with packing fraction, while the relaxation time scale for collective particle motion remains constant. The collective motion of the ellipses is hindered compared to disks because of the rotational constraints on elliptical particles.

  5. Stress Relaxation for Granular Materials near Jamming under Cyclic Compression.

    PubMed

    Farhadi, Somayeh; Zhu, Alex Z; Behringer, Robert P

    2015-10-30

    We have explored isotropically jammed states of semi-2D granular materials through cyclic compression. In each compression cycle, systems of either identical ellipses or bidisperse disks transition between jammed and unjammed states. We determine the evolution of the average pressure P and structure through consecutive jammed states. We observe a transition point ϕ_{m} above which P persists over many cycles; below ϕ_{m}, P relaxes slowly. The relaxation time scale associated with P increases with packing fraction, while the relaxation time scale for collective particle motion remains constant. The collective motion of the ellipses is hindered compared to disks because of the rotational constraints on elliptical particles. PMID:26565498

  6. A mixed relaxed clock model.

    PubMed

    Lartillot, Nicolas; Phillips, Matthew J; Ronquist, Fredrik

    2016-07-19

    Over recent years, several alternative relaxed clock models have been proposed in the context of Bayesian dating. These models fall in two distinct categories: uncorrelated and autocorrelated across branches. The choice between these two classes of relaxed clocks is still an open question. More fundamentally, the true process of rate variation may have both long-term trends and short-term fluctuations, suggesting that more sophisticated clock models unfolding over multiple time scales should ultimately be developed. Here, a mixed relaxed clock model is introduced, which can be mechanistically interpreted as a rate variation process undergoing short-term fluctuations on the top of Brownian long-term trends. Statistically, this mixed clock represents an alternative solution to the problem of choosing between autocorrelated and uncorrelated relaxed clocks, by proposing instead to combine their respective merits. Fitting this model on a dataset of 105 placental mammals, using both node-dating and tip-dating approaches, suggests that the two pure clocks, Brownian and white noise, are rejected in favour of a mixed model with approximately equal contributions for its uncorrelated and autocorrelated components. The tip-dating analysis is particularly sensitive to the choice of the relaxed clock model. In this context, the classical pure Brownian relaxed clock appears to be overly rigid, leading to biases in divergence time estimation. By contrast, the use of a mixed clock leads to more recent and more reasonable estimates for the crown ages of placental orders and superorders. Altogether, the mixed clock introduced here represents a first step towards empirically more adequate models of the patterns of rate variation across phylogenetic trees.This article is part of the themed issue 'Dating species divergences using rocks and clocks'.

  7. A mixed relaxed clock model

    PubMed Central

    2016-01-01

    Over recent years, several alternative relaxed clock models have been proposed in the context of Bayesian dating. These models fall in two distinct categories: uncorrelated and autocorrelated across branches. The choice between these two classes of relaxed clocks is still an open question. More fundamentally, the true process of rate variation may have both long-term trends and short-term fluctuations, suggesting that more sophisticated clock models unfolding over multiple time scales should ultimately be developed. Here, a mixed relaxed clock model is introduced, which can be mechanistically interpreted as a rate variation process undergoing short-term fluctuations on the top of Brownian long-term trends. Statistically, this mixed clock represents an alternative solution to the problem of choosing between autocorrelated and uncorrelated relaxed clocks, by proposing instead to combine their respective merits. Fitting this model on a dataset of 105 placental mammals, using both node-dating and tip-dating approaches, suggests that the two pure clocks, Brownian and white noise, are rejected in favour of a mixed model with approximately equal contributions for its uncorrelated and autocorrelated components. The tip-dating analysis is particularly sensitive to the choice of the relaxed clock model. In this context, the classical pure Brownian relaxed clock appears to be overly rigid, leading to biases in divergence time estimation. By contrast, the use of a mixed clock leads to more recent and more reasonable estimates for the crown ages of placental orders and superorders. Altogether, the mixed clock introduced here represents a first step towards empirically more adequate models of the patterns of rate variation across phylogenetic trees. This article is part of the themed issue ‘Dating species divergences using rocks and clocks’. PMID:27325829

  8. Estimation of divergence times in litostomatean ciliates (Ciliophora: Intramacronucleata), using Bayesian relaxed clock and 18S rRNA gene.

    PubMed

    Vďačný, Peter

    2015-08-01

    The class Litostomatea comprises a diverse assemblage of free-living and endosymbiotic ciliates. To understand diversification dynamic of litostomateans, divergence times of their main groups were estimated with the Bayesian molecular dating, a technique allowing relaxation of molecular clock and incorporation of flexible calibration points. The class Litostomatea very likely emerged during the Cryogenian around 680 Mya. The origin of the subclass Rhynchostomatia is dated to about 415 Mya, while that of the subclass Haptoria to about 654 Mya. The order Pleurostomatida, emerging about 556 Mya, was recognized as the oldest group within the subclass Haptoria. The order Spathidiida appeared in the Paleozoic about 442 Mya. The three remaining haptorian orders evolved in the Paleozoic/Mesozoic periods: Didiniida about 419 Mya, Lacrymariida about 269 Mya, and Haptorida about 194 Mya. The subclass Trichostomatia originated from a spathidiid ancestor in the Mesozoic about 260 Mya. A further goal of this study was to investigate the impact of various settings on posterior divergence time estimates. The root placement and tree topology as well as the priors of the rate-drift model, birth-death process and nucleotide substitution rate, had no significant effect on calculation of posterior divergence time estimates. However, removal of calibration points could significantly change time estimates at some nodes.

  9. Modeling orbital changes on tectonic time scales

    NASA Technical Reports Server (NTRS)

    Crowley, Thomas J.

    1992-01-01

    Geologic time series indicate significant 100 ka and 400 ka pre-Pleistocene climate fluctuations, prior to the time of such fluctuations in Pleistocene ice sheets. The origin of these fluctuations must therefore depend on phenomena other than the ice sheets. In a previous set of experiments, we tested the sensitivity of an energy balance model to orbital insolation forcing, specifically focusing on the filtering effect of the Earth's geography. We found that in equatorial areas, the twice-yearly passage of the sun across the equator interacts with the precession index to generate 100 ka and 400 ka power in our modeled time series. The effect is proportional to the magnitude of land in equatorial regions. We suggest that such changes may reflect monsoonal variations in the real climate system, and the subsequent wind and weathering changes may transfer some of this signal to the marine record. A comparison with observed fluctuations of Triassic lake levels is quite favorable. A number of problems remain to be studied or clarified: (1) the EBM experiments need to be followed up by a limited number of GCM experiments; (2) the sensitivity to secular changes in orbital forcing needs to be examined; (3) the possible modifying role of sedimentary processes on geologic time series warrants considerably more study; (4) the effect of tectonic changes on Earth's rotation rate needs to be studied; and (5) astronomers need to make explicit which of their predictions are robust and geologists and astronomers have to agree on which of the predictions are most testable in the geologic record.

  10. Climate change relaxes the time constraints for late-born offspring in a long-distance migrant.

    PubMed

    Tomotani, Barbara M; Gienapp, Phillip; Beersma, Domien G M; Visser, Marcel E

    2016-09-28

    Animals in seasonal environments need to fit their annual-cycle stages, such as moult and migration, in a tight schedule. Climate change affects the phenology of organisms and causes advancements in timing of these annual-cycle stages but not necessarily at the same rates. For migratory birds, this can lead to more severe or more relaxed time constraints in the time from fledging to migration, depending on the relative shifts of the different stages. We tested how a shift in hatch date, which has advanced due to climate change, impacts the organization of the birds' whole annual cycle. We experimentally advanced and delayed the hatch date of pied flycatcher chicks in the field and then measured the timing of their annual-cycle stages in a controlled laboratory environment. Hatch date affected the timing of moult and pre-migratory fattening, but not migration. Early-born birds hence had a longer time to fatten up than late-born ones; the latter reduced their interval between onset of fattening and migration to be able to migrate at the same time as the early-born birds. This difference in time constraints for early- and late-born individuals may explain why early-born offspring have a higher probability to recruit as a breeding bird. Climate change-associated advancements of avian egg-lay dates, which in turn advances hatch dates, can thus reduce the negative fitness consequences of reproducing late, thereby reducing the selection for early egg-laying migratory birds. PMID:27655765

  11. Centric scan SPRITE for spin density imaging of short relaxation time porous materials.

    PubMed

    Chen, Quan; Halse, Meghan; Balcom, Bruce J

    2005-02-01

    The single-point ramped imaging with T1 enhancement (SPRITE) imaging technique has proven to be a very robust and flexible method for the study of a wide range of systems with short signal lifetimes. As a pure phase encoding technique, SPRITE is largely immune to image distortions generated by susceptibility variations, chemical shift and paramagnetic impurities. In addition, it avoids the line width restrictions on resolution common to time-based sampling, frequency encoding methods. The standard SPRITE technique is however a longitudinal steady-state imaging method; the image intensity is related to the longitudinal steady state, which not only decreases the signal-to-noise ratio, but also introduces many parameters into the image signal equation. A centric scan strategy for SPRITE removes the longitudinal steady state from the image intensity equation and increases the inherent image intensity. Two centric scan SPRITE methods, that is, Spiral-SPRITE and Conical-SPRITE, with fast acquisition and greatly reduced gradient duty cycle, are outlined. Multiple free induction decay (FID) points may be acquired during SPRITE sampling for signal averaging to increase signal-to-noise ratio or for T2* and spin density mapping without an increase in acquisition time. Experimental results show that most porous sedimentary rock and concrete samples have a single exponential T2* decay due to susceptibility difference-induced field distortion. Inhomogeneous broadening thus dominates, which suggests that spin density imaging can be easily obtained by SPRITE. PMID:15833624

  12. Centric scan SPRITE for spin density imaging of short relaxation time porous materials.

    PubMed

    Chen, Quan; Halse, Meghan; Balcom, Bruce J

    2005-02-01

    The single-point ramped imaging with T1 enhancement (SPRITE) imaging technique has proven to be a very robust and flexible method for the study of a wide range of systems with short signal lifetimes. As a pure phase encoding technique, SPRITE is largely immune to image distortions generated by susceptibility variations, chemical shift and paramagnetic impurities. In addition, it avoids the line width restrictions on resolution common to time-based sampling, frequency encoding methods. The standard SPRITE technique is however a longitudinal steady-state imaging method; the image intensity is related to the longitudinal steady state, which not only decreases the signal-to-noise ratio, but also introduces many parameters into the image signal equation. A centric scan strategy for SPRITE removes the longitudinal steady state from the image intensity equation and increases the inherent image intensity. Two centric scan SPRITE methods, that is, Spiral-SPRITE and Conical-SPRITE, with fast acquisition and greatly reduced gradient duty cycle, are outlined. Multiple free induction decay (FID) points may be acquired during SPRITE sampling for signal averaging to increase signal-to-noise ratio or for T2* and spin density mapping without an increase in acquisition time. Experimental results show that most porous sedimentary rock and concrete samples have a single exponential T2* decay due to susceptibility difference-induced field distortion. Inhomogeneous broadening thus dominates, which suggests that spin density imaging can be easily obtained by SPRITE.

  13. The search for negative amplitude components in quasi-continuous distributions of relaxation times: the example of 1H magnetization exchange in articular cartilage and hydrated collagen

    NASA Astrophysics Data System (ADS)

    Fantazzini, Paola; Galassi, Francesca; Bortolotti, Villiam; Brown, Robert J. S.; Vittur, Franco

    2011-06-01

    When inverting nuclear magnetic resonance relaxation data in order to obtain quasi-continuous distributions of relaxation times for fluids in porous media, it is common practice to impose a non-negative (NN) constraint on the distributions. While this approach can be useful in reducing the effects of data distortion and/or preventing wild oscillations in the distributions, it may give misleading results in the presence of real negative amplitude components. Here, some examples of valid negative components for articular cartilage and hydrated collagen are given. Articular cartilage is a connective tissue, consisting mainly of collagen, proteoglycans and water, which can be considered, in many aspects, as a porous medium. Separate T1 relaxation data are obtained for low-mobility ('solid') macromolecular 1H and for higher-mobility ('liquid') 1H by the separation of these components in free induction decays, with α denoting the solid/liquid 1H ratio. When quasi-continuous distributions of relaxation times (T1) of the solid and liquid signal components of cartilage or collagen are computed from experimental relaxation data without imposing the usual NN constraint, valid negative peaks may appear. The features of the distributions, in particular negative peaks, and the fact that peaks at longer times for macromolecular and water protons are at essentially the same T1, are interpreted as the result of a magnetization exchange between these two spin pools. For the only-slightly-hydrated collagen samples, with α>1, the exchange leads to small negative peaks at short T1 times for the macromolecular component. However, for the cartilage, with substantial hydration or for a strongly hydrated collagen sample, both with αLt1, the behavior is reversed, with a negative peak for water at short times. The validity of a negative peak may be accepted (dismissed) by a high (low) cost of NN in error of fit. Computed distributions for simulated data using observed signal

  14. A molecular time-scale for eukaryote evolution recalibrated with the continuous microfossil record

    PubMed Central

    Berney, Cédric; Pawlowski, Jan

    2006-01-01

    Recent attempts to establish a molecular time-scale of eukaryote evolution failed to provide a congruent view on the timing of the origin and early diversification of eukaryotes. The major discrepancies in molecular time estimates are related to questions concerning the calibration of the tree. To limit these uncertainties, we used here as a source of calibration points the rich and continuous microfossil record of dinoflagellates, diatoms and coccolithophorids. We calibrated a small-subunit ribosomal RNA tree of eukaryotes with four maximum and 22 minimum time constraints. Using these multiple calibration points in a Bayesian relaxed molecular clock framework, we inferred that the early radiation of eukaryotes occurred near the Mesoproterozoic–Neoproterozoic boundary, about 1100 million years ago. Our results indicate that most Proterozoic fossils of possible eukaryotic origin cannot be confidently assigned to extant lineages and should therefore not be used as calibration points in molecular dating. PMID:16822745

  15. Objective quality measurement for audio time-scale modification

    NASA Astrophysics Data System (ADS)

    Liu, Fang; Lee, Jae-Joon; Kuo, C. C. J.

    2003-11-01

    The recent ITU-T Recommendation P.862, known as the Perceptual Evaluation of Speech Quality (PESQ) is an objective end-to-end speech quality assessment method for telephone networks and speech codecs through the measurement of received audio quality. To ensure that certain network distortions will not affect the estimated subjective measurement determined by PESQ, the algorithm takes into account packet loss, short-term and long-term time warping resulted from delay variation. However, PESQ does not work well for time-scale audio modification or temporal clipping. We investigated the factors that impact the perceived quality when time-scale modification is involved. An objective measurement of time-scale modification is proposed in this research, where the cross-correlation values obtained from time-scale modification synchronization are used to evaluate the quality of a time-scaled audio sequence. This proposed objective measure has been verified by a subjective test.

  16. Spatially resolved measurements of mean spin-spin relaxation time constants.

    PubMed

    Nechifor, Ruben Emanuel; Romanenko, Konstantin; Marica, Florea; Balcom, Bruce J

    2014-02-01

    Magnetic Resonance measurements of the T2 distribution have become very common and they are a powerful way to probe microporous fluid bearing solids. While the structure of the T2 distribution, and changes in the structure, are often very informative, it is common to reduce the T2 distribution to a mean numeric quantity in order to provide a quantitative interpretation of the distribution. Magnetic Resonance Imaging measurements of the T2 distribution have recently been introduced, but they are time consuming, especially for 2 and 3 spatial dimensions. In this paper we explore a direct MRI measurement of the arithmetic mean of 1/T2, characterizing the distribution by using the initial slope of the spatially resolved T2 decay in a CPMG prepared Centric Scan SPRITE experiment. The methodology is explored with a test phantom sample and realistic petroleum reservoir core plug samples. The arithmetic mean of 1/T2 is related to the harmonic mean of T2. The mean obtained from the early decay is explored through measurements of uniform saturated core plug samples and by comparison to other means determined from the complete T2 distribution. Complementary data were obtained using SE-SPI T2 distribution MRI measurements. The utility of the arithmetic mean 1/T2 is explored through measurements of centrifuged core plug samples where the T2 distribution varies spatially. The harmonic mean T2 obtained from the early decay was employed to estimate the irreducible water saturation for core plug samples. PMID:24361482

  17. Spatially resolved measurements of mean spin-spin relaxation time constants

    NASA Astrophysics Data System (ADS)

    Nechifor, Ruben Emanuel; Romanenko, Konstantin; Marica, Florea; Balcom, Bruce J.

    2014-02-01

    Magnetic Resonance measurements of the T2 distribution have become very common and they are a powerful way to probe microporous fluid bearing solids. While the structure of the T2 distribution, and changes in the structure, are often very informative, it is common to reduce the T2 distribution to a mean numeric quantity in order to provide a quantitative interpretation of the distribution. Magnetic Resonance Imaging measurements of the T2 distribution have recently been introduced, but they are time consuming, especially for 2 and 3 spatial dimensions. In this paper we explore a direct MRI measurement of the arithmetic mean of 1/T2, characterizing the distribution by using the initial slope of the spatially resolved T2 decay in a CPMG prepared Centric Scan SPRITE experiment. The methodology is explored with a test phantom sample and realistic petroleum reservoir core plug samples. The arithmetic mean of 1/T2 is related to the harmonic mean of T2. The mean obtained from the early decay is explored through measurements of uniform saturated core plug samples and by comparison to other means determined from the complete T2 distribution. Complementary data were obtained using SE-SPI T2 distribution MRI measurements. The utility of the arithmetic mean 1/T2 is explored through measurements of centrifuged core plug samples where the T2 distribution varies spatially. The harmonic mean T2 obtained from the early decay was employed to estimate the irreducible water saturation for core plug samples.

  18. Effects of osmotic manipulation of intracellular hydration of HeLa S-3 cells on their proton NMR relaxation times.

    PubMed

    Wheatley, D N; Rimmington, J E; Foster, M A

    1990-01-01

    Pellets of HeLa from suspension cultured cells in isotonic medium (300 mosmolar) were introduced into a Bruker CXP100 NMR spectrophotometer at 80 mHz within 5 min of the start of centrifugation. T1 and T2 times were measured within a total elapsed time of 20-25 min at 80 mHz and 37 degrees C, and averaged 1430 msec and 120 msec, respectively. Extrapolation to zero extracellular space gave a corrected T1 of 1370 msec. For cells collected after 10 min in hypotonic medium (down to 30 mosmolar) increased proton density correlated well with increased cell water content, but relaxation times did not rise in proportion to that predicted for the entry of "bulk" water (T1 of 4700 msec), except when swelling approached lysis point. Cells partially dehydrated by 10 min in hypertonic medium of up to 1500 mosmolar have also been analyzed, but once again the shortening of T1 was not proportional to the loss of "free" (bulk phase) water. At the upper limit of hypertonic treatment, lacunae or vacuoles of a watery nature separated within the cytomatrix, preventing maximum dehydration. The relationship of cell water to T1 is complex over the whole range of tonicity that HeLa S-3 cells tolerate. The data indicate, however, that hypotonically induced water probably has an average T1 time considerably lower than bulk phase water. In contrast, raising the total extracellular volume with medium had precisely the predicted effect on T1 time, further strengthening the case that water taken up by cell acquires a shorter T1 time. Cells adapting to hypotonic conditions oscillated in size and water content over 2-3 hr before returning to near their initial volume. Under these circumstances, T1 oscillated in the same way but with a reduced amplitude, consistent with the above findings.

  19. Rapid evaluation of time scale using an optical clock

    NASA Astrophysics Data System (ADS)

    Ido, T.; Hachisu, H.; Nakagawa, F.; Hanado, Y.

    2016-06-01

    Feasibility of steering a time scale using an optical clock is investigated. Since the high stability of optical frequency standards enables rapid evaluation of the scale interval, the requirement for the continuous operation is mitigated. Numerical simulations with the input of real calibration data by a 87Sr lattice clock indicated that the calibrations once in two weeks maintain the time scale within 5 ns level using a currently available hydrogen maser at NICT. “Optical” steering of a time scale by the intermittent calibrations frees an optical frequency standard from being dedicated to the steering, enabling other applications using the same apparatus.

  20. Simulations of Bingham plastic flows with the multiple-relaxation-time lattice Boltzmann model

    NASA Astrophysics Data System (ADS)

    Chen, SongGui; Sun, QiCheng; Jin, Feng; Liu, JianGuo

    2014-03-01

    Fresh cement mortar is a type of workable paste, which can be well approximated as a Bingham plastic and whose flow behavior is of major concern in engineering. In this paper, Papanastasiou's model for Bingham fluids is solved by using the multiplerelaxation-time lattice Boltzmann model (MRT-LB). Analysis of the stress growth exponent m in Bingham fluid flow simulations shows that Papanastasiou's model provides a good approximation of realistic Bingham plastics for values of m > 108. For lower values of m, Papanastasiou's model is valid for fluids between Bingham and Newtonian fluids. The MRT-LB model is validated by two benchmark problems: 2D steady Poiseuille flows and lid-driven cavity flows. Comparing the numerical results of the velocity distributions with corresponding analytical solutions shows that the MRT-LB model is appropriate for studying Bingham fluids while also providing better numerical stability. We further apply the MRT-LB model to simulate flow through a sudden expansion channel and the flow surrounding a round particle. Besides the rich flow structures obtained in this work, the dynamics fluid force on the round particle is calculated. Results show that both the Reynolds number Re and the Bingham number Bn affect the drag coefficients C D , and a drag coefficient with Re and Bn being taken into account is proposed. The relationship of Bn and the ratio of unyielded zone thickness to particle diameter is also analyzed. Finally, the Bingham fluid flowing around a set of randomly dispersed particles is simulated to obtain the apparent viscosity and velocity fields. These results help simulation of fresh concrete flowing in porous media.

  1. Effects of in-pulse transverse relaxation in 3D ultrashort echo time sequences: Analytical derivation, comparison to numerical simulation and experimental application at 3 T

    NASA Astrophysics Data System (ADS)

    Springer, Fabian; Steidle, Günter; Martirosian, Petros; Claussen, Claus D.; Schick, Fritz

    2010-09-01

    The introduction of ultrashort-echo-time-(UTE)-sequences to clinical whole-body MR scanners has opened up the field of MR characterization of materials or tissues with extremely fast signal decay. If the transverse relaxation time is in the range of the RF-pulse duration, approximation of the RF-pulse by an instantaneous rotation applied at the middle of the RF-pulse and immediately followed by free relaxation will lead to a distinctly underestimated echo signal. Thus, the regular Ernst equation is not adequate to correctly describe steady state signal under those conditions. The paper presents an analytically derived modified Ernst equation, which correctly describes in-pulse relaxation of transverse magnetization under typical conditions: The equation is valid for rectangular excitation pulses, usually applied in 3D UTE sequences. Longitudinal relaxation time of the specimen must be clearly longer than RF-pulse duration, which is fulfilled for tendons and bony structures as well as many solid materials. Under these conditions, the proposed modified Ernst equation enables adequate and relatively simple calculation of the magnetization of materials or tissues. Analytically derived data are compared to numerical results obtained by using an established Runge-Kutta-algorithm based on the Bloch equations. Validity of the new approach was also tested by systematical measurements of a solid polymeric material on a 3 T whole-body MR scanner. Thus, the presented modified Ernst equation provides a suitable basis for T1 measurements, even in tissues with T2 values as short as the RF-pulse duration: independent of RF-pulse duration, the 'variable flip angle method' led to consistent results of longitudinal relaxation time T1, if the T2 relaxation time of the material of interest is known as well.

  2. Calculation of the electron spin relaxation times in InSb and InAs by the projection-reduction method

    SciTech Connect

    Kang, Nam Lyong

    2014-12-07

    The electron spin relaxation times in a system of electrons interacting with piezoelectric phonons mediated through spin-orbit interactions were calculated using the formula derived from the projection-reduction method. The results showed that the temperature and magnetic field dependence of the relaxation times in InSb and InAs were similar. The piezoelectric material constants obtained by a comparison with the reported experimental result were P{sub pe}=4.0×10{sup 22} eV/m for InSb and P{sub pe}=1.2×10{sup 23} eV/m for InAs. The result also showed that the relaxation of the electron spin by the Elliot-Yafet process is more relevant for InSb than InAs at a low density.

  3. Multiple time scales in multi-state models.

    PubMed

    Iacobelli, Simona; Carstensen, Bendix

    2013-12-30

    In multi-state models, it has been the tradition to model all transition intensities on one time scale, usually the time since entry into the study ('clock-forward' approach). The effect of time since an intermediate event has been accommodated either by changing the time scale to time since entry to the new state ('clock-back' approach) or by including the time at entry to the new state as a covariate. In this paper, we argue that the choice of time scale for the various transitions in a multi-state model should be dealt with as an empirical question, as also the question of whether a single time scale is sufficient. We illustrate that these questions are best addressed by using parametric models for the transition rates, as opposed to the traditional Cox-model-based approaches. Specific advantages are that dependence of failure rates on multiple time scales can be made explicit and described in informative graphical displays. Using a single common time scale for all transitions greatly facilitates computations of probabilities of being in a particular state at a given time, because the machinery from the theory of Markov chains can be applied. However, a realistic model for transition rates is preferable, especially when the focus is not on prediction of final outcomes from start but on the analysis of instantaneous risk or on dynamic prediction. We illustrate the various approaches using a data set from stem cell transplant in leukemia and provide supplementary online material in R. PMID:24027131

  4. Shear Relaxations of Confined Liquids.

    NASA Astrophysics Data System (ADS)

    Carson, George Amos, Jr.

    Ultrathin (<40 A) films of octamethylcyclotetrasiloxane (OMCTS), hexadecane, and dodecane were subjected to linear and non-linear oscillatory shear between flat plates. Shearing frequencies of 0.1 to 800 s^{-1} were applied at pressures from zero to 0.8 MPa using a surface rheometer only recently developed. In most cases the plates were atomically smooth mica surfaces; the role of surface interactions was examined by replacing these with alkyl chain monolayers. OMCTS and hexadecane were examined at a temperature about 5 Celsius degrees above their melting points and tended to solidify. Newtonian plateaus having enormous viscosities were observed at low shear rates. The onset of shear thinning implied relaxation times of about 0.1 s in the linear structure of the confined liquids. Large activation volumes (~80 nm ^3) suggested that shear involved large-scale collective motion. Dodecane was studied at a much higher temperature relative to its melting point and showed no signs of impending solidification though it exhibited well-defined regions of Newtonian response and power law shear thinning. When treated with molecular sieves before use, dodecane had relaxation times which were short (0.02 s) compared to hexadecane, but still exhibited large-scale collective motion. When treated with silica gel, an unexplained long -time relaxation (10 s) was seen in the Newtonian viscosity of dodecane. The relaxation time of the linear structure, 0.005 s was very small, and the storage modulus was unresolvable. The small activation volume (7nm^3) indicated a much lower level of collective motion. The activation volume remained small when dodecane was confined between tightly bound, low energy, alkyl monolayers. At low strains the storage and loss moduli became very large (>10^4 Pa), probably due to interactions with flaws in the monolayers. Dramatic signs of wall slip were observed at large strains even at low pressures.

  5. Relaxation properties in classical diamagnetism.

    PubMed

    Carati, A; Benfenati, F; Galgani, L

    2011-06-01

    It is an old result of Bohr that, according to classical statistical mechanics, at equilibrium a system of electrons in a static magnetic field presents no magnetization. Thus a magnetization can occur only in an out of equilibrium state, such as that produced through the Foucault currents when a magnetic field is switched on. It was suggested by Bohr that, after the establishment of such a nonequilibrium state, the system of electrons would quickly relax back to equilibrium. In the present paper, we study numerically the relaxation to equilibrium in a modified Bohr model, which is mathematically equivalent to a billiard with obstacles, immersed in a magnetic field that is adiabatically switched on. We show that it is not guaranteed that equilibrium is attained within the typical time scales of microscopic dynamics. Depending on the values of the parameters, one has a relaxation either to equilibrium or to a diamagnetic (presumably metastable) state. The analogy with the relaxation properties in the Fermi Pasta Ulam problem is also pointed out.

  6. Relaxation properties in classical diamagnetism

    NASA Astrophysics Data System (ADS)

    Carati, A.; Benfenati, F.; Galgani, L.

    2011-06-01

    It is an old result of Bohr that, according to classical statistical mechanics, at equilibrium a system of electrons in a static magnetic field presents no magnetization. Thus a magnetization can occur only in an out of equilibrium state, such as that produced through the Foucault currents when a magnetic field is switched on. It was suggested by Bohr that, after the establishment of such a nonequilibrium state, the system of electrons would quickly relax back to equilibrium. In the present paper, we study numerically the relaxation to equilibrium in a modified Bohr model, which is mathematically equivalent to a billiard with obstacles, immersed in a magnetic field that is adiabatically switched on. We show that it is not guaranteed that equilibrium is attained within the typical time scales of microscopic dynamics. Depending on the values of the parameters, one has a relaxation either to equilibrium or to a diamagnetic (presumably metastable) state. The analogy with the relaxation properties in the Fermi Pasta Ulam problem is also pointed out.

  7. In vivo proton magnetic resonance spectroscopy of liver metabolites in non-alcoholic fatty liver disease in rats: T2 relaxation times in methylene protons.

    PubMed

    Song, Kyu-Ho; Baek, Hyeon-Man; Lee, Do-Wan; Choe, Bo-Young

    2015-10-01

    The aim of this study was to evaluate the transverse relaxation time of methylene resonance as compared to other lipid resonances. The examinations were performed using a 3.0 T scanner with a point-resolved spectroscopy (PRESS) sequence. Lipid relaxation time in a lipid phantom filled with canola oil was estimated with a repetition time (TR) of 6000ms and echo time (TE) of 40-550ms. For in vivo proton magnetic resonance spectroscopy ((1)H-MRS), eight male Sprague-Dawley rats were given free access to a normal-chow (NC) and another eight male Sprague-Dawley rats were given free access to a high-fat (HF) diet. Both groups drank water ad libitum. T2 measurements in the rats' livers were conducted at a fixed TR of 6000ms and TE of 40-220ms. Exponential curve fitting quality was calculated through the coefficients of determination (R(2)). Chemical analyses of the phantom and livers were not performed, but T2 decay curves were acquired. The T2 relaxation time of methylene resonance was estimated as follows: NC rats, 37.1±4.3ms; HF rats, 31.4±1.8ms (p<0.05). The extrapolated M0 values were higher in HF rats than in NC rats (p<0.005). This study of (1)H MRS led to sufficient spectral resolution and signal-to-noise ratio differences to characterize the T2 relaxation times of methylene resonance. (1)H MRS relaxation times may be useful for quantitative characterization of various liver diseases, including fatty liver disease.

  8. High homogeneity B(1) 30.2 MHz Nuclear Magnetic Resonance Probe for off-resonance relaxation times measurements.

    PubMed

    Baranowski, M; Woźniak-Braszak, A; Jurga, K

    2011-01-01

    This paper reports on design and construction of a double coil high-homogeneity ensuring Nuclear Magnetic Resonance Probe for off-resonance relaxation time measurements. NMR off-resonance experiments pose unique technical problems. Long irradiation can overheat the sample, dephase the spins because of B(1) field inhomogeneity and degrade the signal received by requiring the receiver bandwidth to be broader than that needed for normal experiment. The probe proposed solves these problems by introducing a separate off-resonance irradiation coil which is larger than the receiver coil and is wound up on the dewar tube that separates it from the receiver coil thus also thermally protects the sample from overheating. Large size of the irradiation coil also improves the field homogeneity because as a ratio of the sample diameter to the magnet (coil) diameter increases, the field inhomogeneity also increases (Blümich et al., 2008) [1]. The small receiver coil offers maximization of the filling factor and a high signal to the noise ratio.

  9. Nuclear spin relaxation times in hydrogen-helium and methane-helium slush at 4 MHz using pulsed NMR

    NASA Astrophysics Data System (ADS)

    Hamida, J. A.

    2005-03-01

    We compare the nuclear spin-lattice and nuclear spin-spin relaxation times observed for small grains of hydrogen suspended in liquid helium (hydrogen-helium ``slush'') with that of methane-helium ``slush.'' The transport properties of these ``slush'' materials are critical to NASA's goal of realizing atomic propellant designs for future spacecraft. Atoms of active propellants are stored cryogenically in a host matrix such as hydrogen (H2) or methane (CH4) to prevent recombination while liquid helium is ideal for holding the host matrix and for easy transportation. The host matrix must therefore be stable in liquid helium. We find that for hydrogen ``slush,'' NMR rate is consistent with scattering at grain boundaries due to the large electric quadrupole moment of hydrogen; on the other hand the ``slush'' rate for methane is consistent with internal diffusion as opposed to surface scattering. We conclude that for atomic propellants, methane is a better host than hydrogen because grains of methane are better isolated from the helium bath.

  10. Relaxation phenomena in disordered systems

    NASA Astrophysics Data System (ADS)

    Sciortino, F.; Tartaglia, P.

    1997-02-01

    In this article we discuss how the assumptions of self-similarity imposed on the distribution of independently relaxing modes, as well as on their amplitude and characteristic times, manifest in the global relaxation phenomena. We also review recent applications of such approach to the description of relaxation phenomena in microemulsions and molecular glasses.

  11. Energy relaxation and separation of a hot electron-hole pair in organic aggregates from a time-dependent wavepacket diffusion method

    SciTech Connect

    Han, Lu; Liang, WanZhen; Zhao, Yi; Zhong, Xinxin

    2014-06-07

    The time-dependent wavepacket diffusive method [X. Zhong and Y. Zhao, J. Chem. Phys. 138, 014111 (2013)] is extended to investigate the energy relaxation and separation of a hot electron-hole pair in organic aggregates with incorporation of Coulomb interaction and electron-phonon coupling. The pair initial condition generated by laser pulse is represented by a Gaussian wavepacket with a central momentum. The results reveal that the hot electron energy relaxation is very well described by two rate processes with the fast rate much larger than the slow one, consistent with experimental observations, and an efficient electron-hole separation is accomplished accompanying the fast energy relaxation. Furthermore, although the extra energy indeed helps the separation by overcoming the Coulomb interaction, the width of initial wavepacket is much sensitive to the separation efficiency and the narrower wavepacket generates the more separated charges. This behavior may be useful to understand the experimental controversy of the hot carrier effect on charge separation.

  12. Optimal dynamic voltage scaling for wireless sensor nodes with real-time constraints

    NASA Astrophysics Data System (ADS)

    Cassandras, Christos G.; Zhuang, Shixin

    2005-11-01

    Sensors are increasingly embedded in manufacturing systems and wirelessly networked to monitor and manage operations ranging from process and inventory control to tracking equipment and even post-manufacturing product monitoring. In building such sensor networks, a critical issue is the limited and hard to replenish energy in the devices involved. Dynamic voltage scaling is a technique that controls the operating voltage of a processor to provide desired performance while conserving energy and prolonging the overall network's lifetime. We consider such power-limited devices processing time-critical tasks which are non-preemptive, aperiodic and have uncertain arrival times. We treat voltage scaling as a dynamic optimization problem whose objective is to minimize energy consumption subject to hard or soft real-time execution constraints. In the case of hard constraints, we build on prior work (which engages a voltage scaling controller at task completion times) by developing an intra-task controller that acts at all arrival times of incoming tasks. We show that this optimization problem can be decomposed into two simpler ones whose solution leads to an algorithm that does not actually require solving any nonlinear programming problems. In the case of soft constraints, this decomposition must be partly relaxed, but it still leads to a scalable (linear in the number of tasks) algorithm. Simulation results are provided to illustrate performance improvements in systems with intra-task controllers compared to uncontrolled systems or those using inter-task control.

  13. Multiple time scale complexity analysis of resting state FMRI.

    PubMed

    Smith, Robert X; Yan, Lirong; Wang, Danny J J

    2014-06-01

    The present study explored multi-scale entropy (MSE) analysis to investigate the entropy of resting state fMRI signals across multiple time scales. MSE analysis was developed to distinguish random noise from complex signals since the entropy of the former decreases with longer time scales while the latter signal maintains its entropy due to a "self-resemblance" across time scales. A long resting state BOLD fMRI (rs-fMRI) scan with 1000 data points was performed on five healthy young volunteers to investigate the spatial and temporal characteristics of entropy across multiple time scales. A shorter rs-fMRI scan with 240 data points was performed on a cohort of subjects consisting of healthy young (age 23 ± 2 years, n = 8) and aged volunteers (age 66 ± 3 years, n = 8) to investigate the effect of healthy aging on the entropy of rs-fMRI. The results showed that MSE of gray matter, rather than white matter, resembles closely that of f (-1) noise over multiple time scales. By filtering out high frequency random fluctuations, MSE analysis is able to reveal enhanced contrast in entropy between gray and white matter, as well as between age groups at longer time scales. Our data support the use of MSE analysis as a validation metric for quantifying the complexity of rs-fMRI signals.

  14. Liquidity spillover in international stock markets through distinct time scales.

    PubMed

    Righi, Marcelo Brutti; Vieira, Kelmara Mendes

    2014-01-01

    This paper identifies liquidity spillovers through different time scales based on a wavelet multiscaling method. We decompose daily data from U.S., British, Brazilian and Hong Kong stock markets indices in order to calculate the scale correlation between their illiquidities. The sample is divided in order to consider non-crisis, sub-prime crisis and Eurozone crisis. We find that there are changes in correlations of distinct scales and different periods. Association in finest scales is smaller than in coarse scales. There is a rise on associations in periods of crisis. In frequencies, there is predominance for significant distinctions involving the coarsest scale, while for crises periods there is predominance for distinctions on the finest scale.

  15. Liquidity Spillover in International Stock Markets through Distinct Time Scales

    PubMed Central

    Righi, Marcelo Brutti; Vieira, Kelmara Mendes

    2014-01-01

    This paper identifies liquidity spillovers through different time scales based on a wavelet multiscaling method. We decompose daily data from U.S., British, Brazilian and Hong Kong stock markets indices in order to calculate the scale correlation between their illiquidities. The sample is divided in order to consider non-crisis, sub-prime crisis and Eurozone crisis. We find that there are changes in correlations of distinct scales and different periods. Association in finest scales is smaller than in coarse scales. There is a rise on associations in periods of crisis. In frequencies, there is predominance for significant distinctions involving the coarsest scale, while for crises periods there is predominance for distinctions on the finest scale. PMID:24465918

  16. Scaling features of texts, images and time series

    NASA Astrophysics Data System (ADS)

    Pavlov, Alexey N.; Ebeling, Werner; Molgedey, Lutz; Ziganshin, Amir R.; Anishchenko, Vadim S.

    2001-11-01

    In the given paper, we consider the scaling features of long letter sequences like human writings, discretized images and discretized financial data. Using several approaches we show that the symbolic strings and time series being analyzed have a complex multiscale structure and demonstrate different scalings for large and small fluctuations. We discuss complex phenomena in the scaling behavior of partition functions in the case of high frequency DAX-future data.

  17. Extreme reaction times determine fluctuation scaling in human color vision

    NASA Astrophysics Data System (ADS)

    Medina, José M.; Díaz, José A.

    2016-11-01

    In modern mental chronometry, human reaction time defines the time elapsed from stimulus presentation until a response occurs and represents a reference paradigm for investigating stochastic latency mechanisms in color vision. Here we examine the statistical properties of extreme reaction times and whether they support fluctuation scaling in the skewness-kurtosis plane. Reaction times were measured for visual stimuli across the cardinal directions of the color space. For all subjects, the results show that very large reaction times deviate from the right tail of reaction time distributions suggesting the existence of dragon-kings events. The results also indicate that extreme reaction times are correlated and shape fluctuation scaling over a wide range of stimulus conditions. The scaling exponent was higher for achromatic than isoluminant stimuli, suggesting distinct generative mechanisms. Our findings open a new perspective for studying failure modes in sensory-motor communications and in complex networks.

  18. Investigation of doped calcium aluminosilicate glass: A coupling between thermal-expansion and thermal-diffusion models for assessment of nonradiative relaxation time and characteristic diffusion time

    NASA Astrophysics Data System (ADS)

    Souza Filho, N. E.; Nogueira, A. C.; Rohling, J. H.; Baesso, M. L.; Medina, A. N.; Siqueira, A. P. L.; Sampaio, J. A.; Vargas, H.; Bento, A. C.

    2009-11-01

    This paper discusses the use of photoacoustic models to obtain the nonradiative relaxation time (τ) and characteristic diffusion time (τβ) for a sample showing visible absorption bands from fluorescent ion-doped low-silica calcium aluminosilicate glass. Two models allowing phase shift analyses, the thermal-expansion and thermal-diffusion models, are briefly reviewed. These models have limitations when the photoacoustic signal depends on both factors, in a coupling mechanism. An alternative model is proposed to take both thermal expansion and thermal diffusion into account with a single temperature solution for the heat-coupled differential equation. This model is simulated for absorbing samples near the thermally thick region. The model is applied to Eu-V codoped glass showing intermediate signal dependence from ω-1.0 to ω-3/2. The nonradiative time and characteristic diffusion time are derived with 33<τ(ms)<39, and τβ(ms)˜70 ms for the Eu-ion and 340<τβ(ms)<710 for the V-ion. Four absorption bands were analyzed (280, 350, 420, and 600 nm), which showed a signal dependence from ω-1.1 to ω-1.52. Absorption coefficients were derived from τβ in the range of 15<β(cm-1)<51, which agreed fairly well with spectrophotometer data for the same ions.

  19. The development and relaxation of growth strains in thermally grown Al{sub 2}O{sub 3} scales.

    SciTech Connect

    Hou, P. Y.; Paulikas, A. P.; Veal, B. W.; LBNL

    2009-01-01

    The strains in alumina thin films growing on high-temperature alloys at 1,000-1,100 C and during cooling have been successfully measured in-situ using a novel x-ray technique, exploiting synchrotron radiation at the Advanced Photon Source at Argonne National Laboratory. This paper summarizes results obtained from model alloys, with or without the presence of a reactive element, such as Zr, Hf, and Y, to show the importance of the dynamic nature of the stress evolution process and the effects of alloy composition on the generation and relaxation of these stresses.

  20. Membrane fluidity profiles as deduced by saturation-recovery EPR measurements of spin-lattice relaxation times of spin labels

    PubMed Central

    Mainali, Laxman; Feix, Jimmy B.; Hyde, James S.; Subczynski, Witold K.

    2011-01-01

    There are no easily obtainable EPR spectral parameters for lipid spin labels that describe profiles of membrane fluidity. The order parameter, which is most often used as a measure of membrane fluidity, describes the amplitude of wobbling motion of alkyl chains relative to the membrane normal and does not contain explicitly time or velocity. Thus, this parameter can be considered as nondynamic. The spin-lattice relaxation rate (T−11) obtained from saturation-recovery EPR measurements of lipid spin labels in deoxygenated samples depends primarily on the rotational correlation time of the nitroxide moiety within the lipid bilayer. Thus, T−11 can be used as a convenient quantitative measure of membrane fluidity that reflects local membrane dynamics. T−11 profiles obtained for 1-palmitoyl-2-(n-doxylstearoyl)phosphatidylcholine (n-PC) spin labels in dimyristoylphosphatidylcholine (DMPC) membranes with and without 50 mol% cholesterol are presented in parallel with profiles of the rotational diffusion coefficient, R⊥, obtained from simulation of EPR spectra using Freed's model. These profiles are compared with profiles of the order parameter obtained directly from EPR spectra and with profiles of the order parameter obtained from simulation of EPR spectra. It is shown that T−11 and R⊥ profiles reveal changes in membrane fluidity that depend on the motional properties of the lipid alkyl chain. We find that cholesterol has a rigidifying effect only to the depth occupied by the rigid steroid ring structure and a fluidizing effect at deeper locations. These effects cannot be differentiated by profiles of the order parameter. All profiles in this study were obtained at X-band (9.5 GHz). PMID:21868272

  1. Spatial analysis of magnetic resonance T1ρ and T2 relaxation times improves classification between subjects with and without osteoarthritis

    PubMed Central

    Carballido-Gamio, Julio; Stahl, Robert; Blumenkrantz, Gabrielle; Romero, Adan; Majumdar, Sharmila; Link, Thomas M.

    2009-01-01

    Purpose: Studies have shown that functional analysis of knee cartilage based on magnetic resonance (MR) relaxation times is a valuable tool in the understanding of osteoarthritis (OA). In this work, the regional spatial distribution of knee cartilage T1ρ and T2 relaxation times based on texture and laminar analyses was studied to investigate if they provide additional insight compared to global mean values in the study of OA. Methods: Knee cartilage of 36 subjects, 19 healthy controls and 17 with mild OA, was divided into 16 compartments. T1ρ and T2 relaxation times were studied with first order statistics, eight texture parameters with four different orientations using gray-level co-occurrence matrices and by subdividing each compartment into two different layers: Deep and superficial. Receiver operating characteristic curve analysis was performed to evaluate the potential of each technique to correctly classify the populations. Results: Although the deep and superficial cartilage layers had in general significantly different T1ρ and T2 relaxation times, they performed similarly in terms of subject discrimination. The subdivision of lateral and medial femoral compartments into weight-bearing and non-weight-bearing regions did not improve discrimination. Also it was found that the most sensitive region was the patella and that T1ρ discriminated better than T2. The most important finding was that with respect to global mean values, laminar and texture analyses improved subject discrimination. Conclusions: Results of this study suggest that spatially assessing MR images of the knee cartilage relaxation times using laminar and texture analyses could lead to better and probably earlier identification of cartilage matrix abnormalities in subjects with OA. PMID:19810478

  2. One-Shot Measurement of Spin-Lattice Relaxation Times in the Off-Resonance Rotating Frame of Reference with Applications to Breast

    NASA Astrophysics Data System (ADS)

    Fairbanks, Ethan Jefferson

    1994-01-01

    Off-resonance spin locking makes use of the novel relaxation time T_{1rho} ^{rm off}, which may be useful in characterizing breast disease. Knowledge of T _{rm 1rho}^{rm off} is essential for optimization of spin -locking imaging methods. The purpose of this work was to develop an optimal imaging technique for in vivo measurement of T_{rm 1rho}^ {rm off}. Measurement of T _{1rho}^{rm off } using conventional methods requires long exam times which are not suitable for patients. Exam time may be shortened by utilizing a one-shot method developed by Look and Locker, making in vivo measurements possible. The imaging method consisted of a 180^circ inversion pulse followed by a series of small-angle alpha pulses to tip a portion of the longitudinal magnetization into the transverse plane for readout. During each relaxation interval (between alpha pulses), a spin-locking pulse was applied off-resonance to achieve T_ {1rho}^{rm off} relaxation. The value of T_{rm 1rho}^{rm off} was then determined using a three-parameter non-linear least-squares fitting procedure. Values of T_ {1rho}^{rm off} were measured for normal and pathologic breast tissues at several resonant offsets. These measurements revealed that image contrast can be manipulated by altering the resonant offset of the spin-locking pulse. Whereas T _1 relaxation times were nearly identical for normal and cancerous tissues, T_{1 rho}^{rm off} relaxation times differed significantly. These results may be useful in improving image contrast in magnetic resonance imaging.

  3. Carbon-14 time scale extended: comparison of chronologies.

    PubMed

    Grootes, P M

    1978-04-01

    Thermal diffusion isotopic enrichment of carbon-14 has extended the radiocarbon dating range to about 75,000 years ago. Twenty-eight samples obtained up to June 1976, mainly from northwest Europe, were dated. Consideration of the basic assumptions of carbon-14 dating and of the sources of contamination indicates that the ages are generally reliable. Together with the pollen analytic and stratigraphic the dates yield a more detailed radiocarbon time scale for climatic variations in northwest Europe, showing three early glacial interstades. The radiocarbon time scale agrees with the Camp Century chronology and with the thorium-230 ages of corals representing high sea level stands on New Guinea. Ther is a discrepancy between the radiocarbon time scale and the deep-sea chronology, which may be due to correlation errors. With a modified interpretation of the correlation, all four time scales agree within the estimated experimental uncertainties of the dating techniques used.

  4. NEA Scout Solar Sail: Half-scale Fold Time Lapse

    NASA Video Gallery

    In this time lapse, the Near-Earth Asteroid Scout (NEA Scout) CubeSat team rolls a half-scale prototype of the small satellite's solar sail in preparation for a deployment test. During its mission,...

  5. Diffusion Time-Scale of Porous Pressure-Sensitive Paint

    NASA Technical Reports Server (NTRS)

    Liu, Tianshu; Teduka, Norikazu; Kameda, Masaharu; Asai, Keisuke

    2001-01-01

    Pressure-sensitive paint (PSP) is an optical pressure sensor that utilizes the oxygen quenching of luminescence. PSP measurements in unsteady aerodynamic flows require fast time response of the paint. There are two characteristic time-scales that are related to the time response of PSP. One is the luminescent lifetime representing an intrinsic physical limit for the achievable temporal resolution of PSP. Another is the time-scale of oxygen diffusion across the PSP layer. When the time-scale of oxygen diffusion is much larger than the luminescent lifetime, the time response of PSP is controlled by oxygen diffusion. In a thin homogenous polymer layer where diffusion is Fickian, the oxygen concentration 1021 can be described by the diffusion equation in one-dimension.

  6. Time scale for point-defect equilibration in nanostructures

    SciTech Connect

    Millett, Paul C.; Wolf, Dieter; Desai, Tapan; Yamakov, Vesselin

    2008-10-20

    Molecular dynamics simulations of high-temperature annealing are performed on nanostructured materials enabling direct observation of vacancy emission from planar defects (i.e., grain boundaries and free surfaces) to populate the initially vacancy-free grain interiors on a subnanosecond time scale. We demonstrate a universal time-length scale correlation that governs these re-equilibration processes, suggesting that nanostructures are particularly stable against perturbations in their point-defect concentrations, caused for example by particle irradiation or temperature fluctuations.

  7. Measurement of wall relaxation times of polarized Helium-3 in bulk liquid Helium-4 for the neutron electric dipole moment experiment

    NASA Astrophysics Data System (ADS)

    Yoder, Jacob

    The Neutron Electric Dipole Moment (nEDM) experiment that will take place at the Spallation Neutron Source (SNS) in Oak Ridge, Tennessee will measure the electric dipole moment (EDM) of the neutron with a precision of order 10-28 e-cm, utilizing spin-polarized 3He in bulk liquid 4He to detect neutron precession in a 10 mG magnetic field and 50 kV/cm electric field. Since depolarized 3He will produce a background, relaxation of the polarized 3He, characterized by the probability of depolarization per bounce, Pd, was measured for materials that will be in contact with polarized 3He. Depolarization probabilities were determined from measurements of the longitudinal relaxation time of polarized 3He in bulk liquid 4He inside an acrylic cell coated with the wavelength shifter deuterated tetraphenyl butadiene (d-TPB), which will be used to coat the nEDM measurement cell. Relaxation measurements were also performed while rods, made from plumbing material Torlon and valve bellows material BeCu, were present in the cell. The BeCu was coated with Pyralin resin prior to relaxation measurements, while relaxation measurements were performed both before and after the Torlon rod was coated with Pyralin resin. The depolarization probabilities were found to be Pd-TPBd <1.32x10-7 PBareTorlon d=1.01+/-0.08 x10-6 PCoatedTorlon d=2.5+/-0.1 x10-7 PCoatedBeCu d=7.9+/-0.3 x10-7 The relaxation rates extrapolated from the observed values of Pd for d-TPB, coated Torlon, and coated BeCu in the nEDM apparatus were found to be consistent with design goals.

  8. Characteristic Time Scales of Characteristic Magmatic Processes and Systems

    NASA Astrophysics Data System (ADS)

    Marsh, B. D.

    2004-05-01

    Every specific magmatic process, regardless of spatial scale, has an associated characteristic time scale. Time scales associated with crystals alone are rates of growth, dissolution, settling, aggregation, annealing, and nucleation, among others. At the other extreme are the time scales associated with the dynamics of the entire magmatic system. These can be separated into two groups: those associated with system genetics (e.g., the production and transport of magma, establishment of the magmatic system) and those due to physical characteristics of the established system (e.g., wall rock failure, solidification front propagation and instability, porous flow). The detailed geometry of a specific magmatic system is particularly important to appreciate; although generic systems are useful, care must be taken to make model systems as absolutely realistic as possible. Fuzzy models produce fuzzy science. Knowledge of specific time scales is not necessarily useful or meaningful unless the hierarchical context of the time scales for a realistic magmatic system is appreciated. The age of a specific phenocryst or ensemble of phenocrysts, as determined from isotopic or CSD studies, is not meaningful unless something can be ascertained of the provenance of the crystals. For example, crystal size multiplied by growth rate gives a meaningful crystal age only if it is from a part of the system that has experienced semi-monotonic cooling prior to chilling; crystals entrained from a long-standing cumulate bed that were mechanically sorted in ascending magma may not reveal this history. Ragged old crystals rolling about in the system for untold numbers of flushing times record specious process times, telling more about the noise in the system than the life of typical, first generation crystallization processes. The most helpful process-related time scales are those that are known well and that bound or define the temporal style of the system. Perhaps the most valuable of these

  9. Discrete effect on the halfway bounce-back boundary condition of multiple-relaxation-time lattice Boltzmann model for convection-diffusion equations.

    PubMed

    Cui, Shuqi; Hong, Ning; Shi, Baochang; Chai, Zhenhua

    2016-04-01

    In this paper, we will focus on the multiple-relaxation-time (MRT) lattice Boltzmann model for two-dimensional convection-diffusion equations (CDEs), and analyze the discrete effect on the halfway bounce-back (HBB) boundary condition (or sometimes called bounce-back boundary condition) of the MRT model where three different discrete velocity models are considered. We first present a theoretical analysis on the discrete effect of the HBB boundary condition for the simple problems with a parabolic distribution in the x or y direction, and a numerical slip proportional to the second-order of lattice spacing is observed at the boundary, which means that the MRT model has a second-order convergence rate in space. The theoretical analysis also shows that the numerical slip can be eliminated in the MRT model through tuning the free relaxation parameter corresponding to the second-order moment, while it cannot be removed in the single-relaxation-time model or the Bhatnagar-Gross-Krook model unless the relaxation parameter related to the diffusion coefficient is set to be a special value. We then perform some simulations to confirm our theoretical results, and find that the numerical results are consistent with our theoretical analysis. Finally, we would also like to point out the present analysis can be extended to other boundary conditions of lattice Boltzmann models for CDEs.

  10. Discrete effect on the halfway bounce-back boundary condition of multiple-relaxation-time lattice Boltzmann model for convection-diffusion equations.

    PubMed

    Cui, Shuqi; Hong, Ning; Shi, Baochang; Chai, Zhenhua

    2016-04-01

    In this paper, we will focus on the multiple-relaxation-time (MRT) lattice Boltzmann model for two-dimensional convection-diffusion equations (CDEs), and analyze the discrete effect on the halfway bounce-back (HBB) boundary condition (or sometimes called bounce-back boundary condition) of the MRT model where three different discrete velocity models are considered. We first present a theoretical analysis on the discrete effect of the HBB boundary condition for the simple problems with a parabolic distribution in the x or y direction, and a numerical slip proportional to the second-order of lattice spacing is observed at the boundary, which means that the MRT model has a second-order convergence rate in space. The theoretical analysis also shows that the numerical slip can be eliminated in the MRT model through tuning the free relaxation parameter corresponding to the second-order moment, while it cannot be removed in the single-relaxation-time model or the Bhatnagar-Gross-Krook model unless the relaxation parameter related to the diffusion coefficient is set to be a special value. We then perform some simulations to confirm our theoretical results, and find that the numerical results are consistent with our theoretical analysis. Finally, we would also like to point out the present analysis can be extended to other boundary conditions of lattice Boltzmann models for CDEs. PMID:27176432

  11. Multi-scale description and prediction of financial time series

    NASA Astrophysics Data System (ADS)

    Nawroth, A. P.; Friedrich, R.; Peinke, J.

    2010-08-01

    A new method is proposed that allows a reconstruction of time series based on higher order multi-scale statistics given by a hierarchical process. This method is able to model financial time series not only on a specific scale but for a range of scales. The method itself is based on the general n-scale joint probability density, which can be extracted directly from given data. It is shown how based on this n-scale statistics, general n-point probabilities can be estimated from which predictions can be achieved. Exemplary results are shown for the German DAX index. The ability to model correctly the behaviour of the original process for different scales simultaneously and in time is demonstrated. As a main result it is shown that this method is able to reproduce the known volatility cluster, although the model contains no explicit time dependence. Thus a new mechanism is shown how, in a stationary multi-scale process, volatility clustering can emerge.

  12. Russian national time scale long-term stability

    NASA Technical Reports Server (NTRS)

    Alshina, A. P.; Gaigerov, B. A.; Koshelyaevsky, N. B.; Pushkin, S. B.

    1994-01-01

    The Institute of Metrology for Time and Space NPO 'VNIIFTRI' generates the National Time Scale (NTS) of Russia -- one of the most stable time scales in the world. Its striking feature is that it is based on a free ensemble of H-masers only. During last two years the estimations of NTS longterm stability based only on H-maser intercomparison data gives a flicker floor of about (2 to 3) x 10(exp -15) for averaging times from 1 day to 1 month. Perhaps the most significant feature for a time laboratory is an extremely low possible frequency drift -- it is too difficult to estimate it reliably. The other estimations, free from possible inside the ensemble correlation phenomena, are available based on the time comparison of NTS relative to the stable enough time scale of outer laboratories. The data on NTS comparison relative to the time scale of secondary time and frequency standards at Golitzino and Irkutsk in Russia and relative to NIST, PTB and USNO using GLONASS and GPS time transfer links gives stability estimations which are close to that based on H-maser intercomparisons.

  13. Exponentials and Laplace transforms on nonuniform time scales

    NASA Astrophysics Data System (ADS)

    Ortigueira, Manuel D.; Torres, Delfim F. M.; Trujillo, Juan J.

    2016-10-01

    We formulate a coherent approach to signals and systems theory on time scales. The two derivatives from the time-scale calculus are used, i.e., nabla (forward) and delta (backward), and the corresponding eigenfunctions, the so-called nabla and delta exponentials, computed. With these exponentials, two generalised discrete-time Laplace transforms are deduced and their properties studied. These transforms are compatible with the standard Laplace and Z transforms. They are used to study discrete-time linear systems defined by difference equations. These equations mimic the usual continuous-time equations that are uniformly approximated when the sampling interval becomes small. Impulse response and transfer function notions are introduced. This implies a unified mathematical framework that allows us to approximate the classic continuous-time case when the sampling rate is high or to obtain the standard discrete-time case, based on difference equations, when the time grid becomes uniform.

  14. An x-ray method for direct determination of the strain state and strain relaxation in micron-scale passivated metallization lines during thermal cycling

    SciTech Connect

    Besser, P.R. ); Brennan, S. ); Bravman, J.C. )

    1994-01-01

    We describe a method for directly determining the strain state of passivated metal lines. Synchrotron radiation in the grazing incidence geometry is used to directly measure the in-plane interplanar spacing along the length and width of the lines, while the strain normal to the surface of the line is measured using conventional diffraction methods. The entire strain state is thereby defined. Previous work has measured out-of-plane reflections, fit them to a straight line as a trigonometric function of the angle of orientation, and extrapolated to determine the principal strains. The equivalence of the two x-ray methods on the same sample is demonstrated at room temperature before and after thermal cycling. For short time strain relaxation experiments during thermal cycling, measurement of the three principal strains leads to the direct calculation of the stress relaxation. We apply the strain determination technique to Al--0.5%Cu lines passivated with Si[sub 3]N[sub 4] as the lines are thermally cycled from room temperature to 450 [degree]C and back. The strain state, stress state, and strain relaxation of the lines are calculated at several temperatures during thermal cycling.

  15. The scaling of time series size towards detrended fluctuation analysis

    NASA Astrophysics Data System (ADS)

    Gao, Xiaolei; Ren, Liwei; Shang, Pengjian; Feng, Guochen

    2016-06-01

    In this paper, we introduce a modification of detrended fluctuation analysis (DFA), called multivariate DFA (MNDFA) method, based on the scaling of time series size N. In traditional DFA method, we obtained the influence of the sequence segmentation interval s, and it inspires us to propose a new model MNDFA to discuss the scaling of time series size towards DFA. The effectiveness of the procedure is verified by numerical experiments with both artificial and stock returns series. Results show that the proposed MNDFA method contains more significant information of series compared to traditional DFA method. The scaling of time series size has an influence on the auto-correlation (AC) in time series. For certain series, we obtain an exponential relationship, and also calculate the slope through the fitting function. Our analysis and finite-size effect test demonstrate that an appropriate choice of the time series size can avoid unnecessary influences, and also make the testing results more accurate.

  16. Controllability of multiplex, multi-time-scale networks

    NASA Astrophysics Data System (ADS)

    Pósfai, Márton; Gao, Jianxi; Cornelius, Sean P.; Barabási, Albert-László; D'Souza, Raissa M.

    2016-09-01

    The paradigm of layered networks is used to describe many real-world systems, from biological networks to social organizations and transportation systems. While recently there has been much progress in understanding the general properties of multilayer networks, our understanding of how to control such systems remains limited. One fundamental aspect that makes this endeavor challenging is that each layer can operate at a different time scale; thus, we cannot directly apply standard ideas from structural control theory of individual networks. Here we address the problem of controlling multilayer and multi-time-scale networks focusing on two-layer multiplex networks with one-to-one interlayer coupling. We investigate the practically relevant case when the control signal is applied to the nodes of one layer. We develop a theory based on disjoint path covers to determine the minimum number of inputs (Ni) necessary for full control. We show that if both layers operate on the same time scale, then the network structure of both layers equally affect controllability. In the presence of time-scale separation, controllability is enhanced if the controller interacts with the faster layer: Ni decreases as the time-scale difference increases up to a critical time-scale difference, above which Ni remains constant and is completely determined by the faster layer. We show that the critical time-scale difference is large if layer I is easy and layer II is hard to control in isolation. In contrast, control becomes increasingly difficult if the controller interacts with the layer operating on the slower time scale and increasing time-scale separation leads to increased Ni, again up to a critical value, above which Ni still depends on the structure of both layers. This critical value is largely determined by the longest path in the faster layer that does not involve cycles. By identifying the underlying mechanisms that connect time-scale difference and controllability for a simplified

  17. Time scale construction from multiple sources of information (Invited)

    NASA Astrophysics Data System (ADS)

    Malinverno, A.

    2013-12-01

    Geological age estimates are provided by diverse chronometers, such as radiometric measurements, astrochronology, and the spacing of magnetic anomalies recorded on mid-ocean ridges by seafloor spreading. These age estimates are affected by errors that can be systematic (e.g., biased radiometric dates due to imperfect assumptions) or random (e.g., imprecise recording of astronomical cycles in sedimentary records). Whereas systematic errors can be reduced by improvements in technique and calibration, uncertainties due to random errors will always be present and need to be dealt with. A Bayesian framework can be used to construct an integrated time scale that is based on several uncertain sources of information. In this framework, each piece of data and the final time scale have an associated probability distribution that describes their uncertainty. The key calculation is to determine the uncertainty in the time scale from the uncertain data that constrain it. In practice, this calculation can be performed by Monte Carlo sampling. In Markov chain Monte Carlo algorithms, the time scale is iteratively perturbed and the perturbed time scale is accepted or rejected depending on how closely it fits the data. The final result is a large ensemble of possible time scales that are consistent with all the uncertain data; while the average of this ensemble defines a 'best' time scale, the ensemble variability quantifies the time scale uncertainty. An example of this approach is the M-sequence (Late Jurassic-Early Cretaceous, ~160-120 Ma) MHTC12 geomagnetic polarity time scale (GPTS) of Malinverno et al. (2012, J. Geophys. Res., B06104, doi:10.1029/2012JB009260). Previous GPTSs were constructed by interpolating between dated marine magnetic anomalies while assuming constant or smoothly varying spreading rates. These GPTSs were typically based on magnetic lineations from one or a few selected spreading centers, and an undesirable result is that they imply larger spreading rate

  18. Slow-time-scale magnetic fields driven by fast-time-scale waves in an underdense relativistic Vlasov plasma

    NASA Astrophysics Data System (ADS)

    Zhu, Shao-ping; He, X. T.; Zheng, C. Y.

    2001-01-01

    Slow-time-scale magnetic fields driven by fast-time-scale electromagnetic waves or plasma waves are examined from the perspective of the Vlasov-Maxwell equations for a relativistic Vlasov plasma. An equation for slow-time-scale magnetic field is obtained. The field proposed in the present paper is a result of wave-wave beating which drives a solenoidal current. The magnitude of the slow-time-scale magnetic field proposed here can be as high as 20 MG at the critical surface for a laser intensity I=1018W/cm2 at wavelength λ0=1.05 μm. The predicted magnetic field is observed in two-dimensional particle simulations presented here.

  19. RELAXATION PROCESSES IN SOLAR WIND TURBULENCE

    SciTech Connect

    Servidio, S.; Carbone, V.; Gurgiolo, C.; Goldstein, M. L.

    2014-07-10

    Based on global conservation principles, magnetohydrodynamic (MHD) relaxation theory predicts the existence of several equilibria, such as the Taylor state or global dynamic alignment. These states are generally viewed as very long-time and large-scale equilibria, which emerge only after the termination of the turbulent cascade. As suggested by hydrodynamics and by recent MHD numerical simulations, relaxation processes can occur during the turbulent cascade that will manifest themselves as local patches of equilibrium-like configurations. Using multi-spacecraft analysis techniques in conjunction with Cluster data, we compute the current density and flow vorticity and for the first time demonstrate that these localized relaxation events are observed in the solar wind. Such events have important consequences for the statistics of plasma turbulence.

  20. Multiple-time scales analysis of physiological time series under neural control

    NASA Technical Reports Server (NTRS)

    Peng, C. K.; Hausdorff, J. M.; Havlin, S.; Mietus, J. E.; Stanley, H. E.; Goldberger, A. L.

    1998-01-01

    We discuss multiple-time scale properties of neurophysiological control mechanisms, using heart rate and gait regulation as model systems. We find that scaling exponents can be used as prognostic indicators. Furthermore, detection of more subtle degradation of scaling properties may provide a novel early warning system in subjects with a variety of pathologies including those at high risk of sudden death.

  1. Time scale bias in erosion rates of glaciated landscapes

    PubMed Central

    Ganti, Vamsi; von Hagke, Christoph; Scherler, Dirk; Lamb, Michael P.; Fischer, Woodward W.; Avouac, Jean-Philippe

    2016-01-01

    Deciphering erosion rates over geologic time is fundamental for understanding the interplay between climate, tectonic, and erosional processes. Existing techniques integrate erosion over different time scales, and direct comparison of such rates is routinely done in earth science. On the basis of a global compilation, we show that erosion rate estimates in glaciated landscapes may be affected by a systematic averaging bias that produces higher estimated erosion rates toward the present, which do not reflect straightforward changes in erosion rates through time. This trend can result from a heavy-tailed distribution of erosional hiatuses (that is, time periods where no or relatively slow erosion occurs). We argue that such a distribution can result from the intermittency of erosional processes in glaciated landscapes that are tightly coupled to climate variability from decadal to millennial time scales. In contrast, we find no evidence for a time scale bias in spatially averaged erosion rates of landscapes dominated by river incision. We discuss the implications of our findings in the context of the proposed coupling between climate and tectonics, and interpreting erosion rate estimates with different averaging time scales through geologic time. PMID:27713925

  2. Multiple time scales in the microwave ionization of Rydberg atoms

    SciTech Connect

    Buchleitner, A.; Delande, D.; Zakrzewski, J.; Mantegna, R.N.; Arndt, M.; Walther, H. ||||

    1995-11-20

    We investigate the time dependence of the ionization probability of Rydberg atoms driven by microwave fields, both numerically and experimentally. Our exact quantum results provide evidence for an algebraic decay law on suitably chosen time scales, a phenomenon that is considered to be the signature of nonhyperbolic scattering in unbounded classically chaotic motion. {copyright} {ital 1995} {ital The} {ital American} {ital Physical} {ital Society}.

  3. Atomic Time Scales for the 21st Century

    NASA Astrophysics Data System (ADS)

    Arias, E. F.

    2014-06-01

    The International Bureau of Weights and Measures, in coordination with international organizations and national institutes, maintains and disseminates Coordinated Universal Time (UTC). Other timescales exist for different purposes. This article describes the state-of-the-art in the elaboration of these time scales.

  4. Auroral Substorm Time Scales: Seasonal and IMF Variations

    NASA Technical Reports Server (NTRS)

    Chua, D.; Parks, G. K.; Brittnacher, M.; Germany, G. A.; Spann, J. F.; Six, N. Frank (Technical Monitor)

    2002-01-01

    The time scales and phases of auroral substorm, activity are quantied in this study using the hemispheric power computed from Polar Ultraviolet Imager (UVI) images. We have applied this technique to several hundred substorm events and we are able to quantify how the characterist act, of substorms vary with season and IMF Bz orientation. We show that substorm time scales vary more strongly with season than with IMF Bz orientation. The recovery time for substorm. activity is well ordered by whether or not the nightside oral zone is sunlit. The recovery time scales for substorms occurring in the winter and equinox periods are similar and are both roughly a factor of two longer than in summer when the auroral oval is sunlit. Our results support the hypothesis that the ionosphere plays an active role in governing the dynamics of the aurora.

  5. Nanosecond relaxation dynamics of protein GB1 identified by the time-dependent red shift in the fluorescence of tryptophan and 5-fluorotryptophan.

    PubMed

    Toptygin, Dmitri; Gronenborn, Angela M; Brand, Ludwig

    2006-12-28

    The B1 domain of Streptococcal protein G (GB1) is a small, thermostable protein containing a single tryptophan residue. We recorded time-resolved fluorescence of the wild-type GB1 and its 5-fluorotryptophan (5FTrp) variant at more than 30 emission wavelengths between 300 and 470 nm. The time-resolved emission spectra reveal no signs of heterogeneity, but show a time-dependent red shift characteristic of microscopic dielectric relaxation. This is true for both 5FTrp and unmodified Trp in GB1. The time-dependent red shifts in the fluorescence of 5FTrp and unmodified Trp are essentially identical, confirming that the shift is caused by the relaxation of the protein matrix rather than by the fluorophore itself. The total amplitude (but not the rate) of the time-dependent red shift depends on the fluorophore, specifically, on the magnitude of the vector difference between its excited state and ground state electric dipole moments; for 5FTrp this is estimated to be about 88% of that for the unmodified Trp. The decay of the excited state fluorophore population is not monoexponential for either fluorophore; however, the deviation from the monoexponential decay law is larger in the case of unmodified Trp. The relaxation dynamics of GB1 was found to be considerably faster than that of other proteins studied previously, consistent with the small size, tightly packed core, and high thermodynamic stability of GB1.

  6. Study on vibrational relaxation dynamics of phenol-water complex by picosecond time-resolved IR-UV pump-probe spectroscopy in a supersonic molecular beam

    NASA Astrophysics Data System (ADS)

    Miyazaki, Yasunori; Inokuchi, Yoshiya; Ebata, Takayuki; Petković, Milena

    2013-06-01

    A comparative study of vibrational energy relaxation (VER) between the monohydrated complexes of phenol-d0 and phenol-d1 is investigated in a supersonic molecular beam. The direct time-resolved measurement of energy redistribution from the phenolic OH/OD stretching mode of the phenol-d0-H2O/phenol-d1-D2O is performed by picosecond IR-UV pump-probe spectroscopy. Two complexes follow the same relaxation process that begins with the intramolecular vibrational energy redistribution (IVR) and the intermolecular vibrational energy redistribution (IVR), which is followed by the vibrational predissociation (VP). The difference in the relaxation lifetimes between them is discussed by anharmonic force field and RRKM calculations. Anharmonic analysis implies that intra- (IVR) and intermolecular (IVR) relaxations occur in parallel in the complexes. The RRKM-predicted dissociation (VP) lifetimes show qualitative agreement with the observed results, suggesting that VP takes place after the statistical energy distribution in the complexes.

  7. Thermodynamics constrains allometric scaling of optimal development time in insects.

    PubMed

    Dillon, Michael E; Frazier, Melanie R

    2013-01-01

    Development time is a critical life-history trait that has profound effects on organism fitness and on population growth rates. For ectotherms, development time is strongly influenced by temperature and is predicted to scale with body mass to the quarter power based on 1) the ontogenetic growth model of the metabolic theory of ecology which describes a bioenergetic balance between tissue maintenance and growth given the scaling relationship between metabolism and body size, and 2) numerous studies, primarily of vertebrate endotherms, that largely support this prediction. However, few studies have investigated the allometry of development time among invertebrates, including insects. Abundant data on development of diverse insects provides an ideal opportunity to better understand the scaling of development time in this ecologically and economically important group. Insects develop more quickly at warmer temperatures until reaching a minimum development time at some optimal temperature, after which development slows. We evaluated the allometry of insect development time by compiling estimates of minimum development time and optimal developmental temperature for 361 insect species from 16 orders with body mass varying over nearly 6 orders of magnitude. Allometric scaling exponents varied with the statistical approach: standardized major axis regression supported the predicted quarter-power scaling relationship, but ordinary and phylogenetic generalized least squares did not. Regardless of the statistical approach, body size alone explained less than 28% of the variation in development time. Models that also included optimal temperature explained over 50% of the variation in development time. Warm-adapted insects developed more quickly, regardless of body size, supporting the "hotter is better" hypothesis that posits that ectotherms have a limited ability to evolutionarily compensate for the depressing effects of low temperatures on rates of biological processes. The

  8. Thermodynamics Constrains Allometric Scaling of Optimal Development Time in Insects

    PubMed Central

    Dillon, Michael E.; Frazier, Melanie R.

    2013-01-01

    Development time is a critical life-history trait that has profound effects on organism fitness and on population growth rates. For ectotherms, development time is strongly influenced by temperature and is predicted to scale with body mass to the quarter power based on 1) the ontogenetic growth model of the metabolic theory of ecology which describes a bioenergetic balance between tissue maintenance and growth given the scaling relationship between metabolism and body size, and 2) numerous studies, primarily of vertebrate endotherms, that largely support this prediction. However, few studies have investigated the allometry of development time among invertebrates, including insects. Abundant data on development of diverse insects provides an ideal opportunity to better understand the scaling of development time in this ecologically and economically important group. Insects develop more quickly at warmer temperatures until reaching a minimum development time at some optimal temperature, after which development slows. We evaluated the allometry of insect development time by compiling estimates of minimum development time and optimal developmental temperature for 361 insect species from 16 orders with body mass varying over nearly 6 orders of magnitude. Allometric scaling exponents varied with the statistical approach: standardized major axis regression supported the predicted quarter-power scaling relationship, but ordinary and phylogenetic generalized least squares did not. Regardless of the statistical approach, body size alone explained less than 28% of the variation in development time. Models that also included optimal temperature explained over 50% of the variation in development time. Warm-adapted insects developed more quickly, regardless of body size, supporting the “hotter is better” hypothesis that posits that ectotherms have a limited ability to evolutionarily compensate for the depressing effects of low temperatures on rates of biological processes

  9. Relaxation selective pulses in fast relaxing systems.

    PubMed

    Lopez, Christopher J; Lu, Wei; Walls, Jamie D

    2014-05-01

    In this work, the selectivity or sharpness of the saturation profiles for relaxation selective pulses (R^rsps) that suppress magnetization possessing relaxation times of T2=T2(rsp) and T1=αT2 for α∈12,∞ was optimized. Along with sharpening the selectivity of the R^rsps, the selective saturation of these pulses was also optimized to be robust to both B0 and B1 inhomogeneities. Frequency-swept hyperbolic secant and adiabatic time-optimal saturation pulse inputs were found to work best in the optimizations, and the pulse lengths required to selectivity saturate the magnetization were always found to be less than the inversion recovery delay, T1ln(2). The selectivity of the optimized relaxation selective pulses was experimentally demonstrated in aqueous solutions with varying concentrations of the paramagnetic species, [Mn(+2)], and for use in solvent suppression. Finally, the "rotational" properties of spin relaxation were explored along with an analytical derivation of adiabatic time-optimal saturation pulses. PMID:24631803

  10. Deviations from uniform power law scaling in nonstationary time series

    NASA Technical Reports Server (NTRS)

    Viswanathan, G. M.; Peng, C. K.; Stanley, H. E.; Goldberger, A. L.

    1997-01-01

    A classic problem in physics is the analysis of highly nonstationary time series that typically exhibit long-range correlations. Here we test the hypothesis that the scaling properties of the dynamics of healthy physiological systems are more stable than those of pathological systems by studying beat-to-beat fluctuations in the human heart rate. We develop techniques based on the Fano factor and Allan factor functions, as well as on detrended fluctuation analysis, for quantifying deviations from uniform power-law scaling in nonstationary time series. By analyzing extremely long data sets of up to N = 10(5) beats for 11 healthy subjects, we find that the fluctuations in the heart rate scale approximately uniformly over several temporal orders of magnitude. By contrast, we find that in data sets of comparable length for 14 subjects with heart disease, the fluctuations grow erratically, indicating a loss of scaling stability.

  11. Relation between Direct Observation of Relaxation and Self-Reported Mindfulness and Relaxation States

    ERIC Educational Resources Information Center

    Hites, Lacey S.; Lundervold, Duane A.

    2013-01-01

    Forty-four individuals, 18-47 (MN 21.8, SD 5.63) years of age, took part in a study examining the magnitude and direction of the relationship between self-report and direct observation measures of relaxation and mindfulness. The Behavioral Relaxation Scale (BRS), a valid direct observation measure of relaxation, was used to assess relaxed behavior…

  12. Physics in space-time with scale-dependent metrics

    NASA Astrophysics Data System (ADS)

    Balankin, Alexander S.

    2013-10-01

    We construct three-dimensional space Rγ3 with the scale-dependent metric and the corresponding Minkowski space-time Mγ,β4 with the scale-dependent fractal (DH) and spectral (DS) dimensions. The local derivatives based on scale-dependent metrics are defined and differential vector calculus in Rγ3 is developed. We state that Mγ,β4 provides a unified phenomenological framework for dimensional flow observed in quite different models of quantum gravity. Nevertheless, the main attention is focused on the special case of flat space-time M1/3,14 with the scale-dependent Cantor-dust-like distribution of admissible states, such that DH increases from DH=2 on the scale ≪ℓ0 to DH=4 in the infrared limit ≫ℓ0, where ℓ0 is the characteristic length (e.g. the Planck length, or characteristic size of multi-fractal features in heterogeneous medium), whereas DS≡4 in all scales. Possible applications of approach based on the scale-dependent metric to systems of different nature are briefly discussed.

  13. Relaxation System

    NASA Technical Reports Server (NTRS)

    1987-01-01

    Environ Corporation's relaxation system is built around a body lounge, a kind of super easy chair that incorporates sensory devices. Computer controlled enclosure provides filtered ionized air to create a feeling of invigoration, enhanced by mood changing aromas. Occupant is also surrounded by multidimensional audio and the lighting is programmed to change colors, patterns, and intensity periodically. These and other sensory stimulators are designed to provide an environment in which the learning process is stimulated, because research has proven that while an individual is in a deep state of relaxation, the mind is more receptive to new information.

  14. Gd-EOB-DTPA-Enhanced MR Imaging of the Liver: The Effect on T2 Relaxation Times and Apparent Diffusion Coefficient (ADC)

    PubMed Central

    Cieszanowski, Andrzej; Podgórska, Joanna; Rosiak, Grzegorz; Maj, Edyta; Grudziński, Ireneusz P.; Kaczyński, Bartosz; Szeszkowski, Wojciech; Milczarek, Krzysztof; Rowiński, Olgierd

    2016-01-01

    Summary Background To investigate the effect of gadoxetic acid disodium (Gd-EOB-DTPA) on T2 relaxation times and apparent diffusion coefficient (ADC) values of the liver and focal liver lesions on a 1.5-T system. Material/Methods Magnetic resonance (MR) studies of 50 patients with 35 liver lesions were retrospectively analyzed. All examinations were performed at 1.5T and included T2-weighted turbo spin-echo (TSE) and diffusion-weighted (DW) images acquired before and after intravenous administration of Gd-EOB-DTPA. To assess the effect of this hepatobiliary contrast agent on T2-weighted TSE images and DW images T2 relaxation times and ADC values of the liver and FLLs were calculated and compared pre- and post-injection. Results The mean T2 relaxation times of the liver and focal hepatic lesions were lower on enhanced than on unenhanced T2-weighted TSE images (decrease of 2.7% and 3.6% respectively), although these differences were not statistically significant. The mean ADC values of the liver showed statistically significant decrease (of 4.6%) on contrast-enhanced DW images, compared to unenhanced images (P>0.05). The mean ADC value of liver lesions was lower on enhanced than on unenhanced DW images, but this difference (of 2.9%) did not reach statistical significance. Conclusions The mean T2 relaxation times of the liver and focal liver lesions as well as the mean ADC values of liver lesions were not significantly different before and after administration of Gd-EOB-DTPA. Therefore, acquisition of T2-weighted and DW images between the dynamic contrast-enhanced examination and hepatobiliary phase is feasible and time-saving. PMID:27026795

  15. Correlated and uncorrelated heart rate fluctuations during relaxing visualization

    NASA Astrophysics Data System (ADS)

    Papasimakis, N.; Pallikari, F.

    2010-05-01

    The heart rate variability (HRV) of healthy subjects practicing relaxing visualization is studied by use of three multiscale analysis techniques: the detrended fluctuation analysis (DFA), the entropy in natural time (ENT) and the average wavelet (AWC) coefficient. The scaling exponent of normal interbeat interval increments exhibits characteristics of the presence of long-range correlations. During relaxing visualization the HRV dynamics change in the sense that two new features emerge independent of each other: a respiration-induced periodicity that often dominates the HRV at short scales (<40 interbeat intervals) and the decrease of the scaling exponent at longer scales (40-512 interbeat intervals). In certain cases, the scaling exponent during relaxing visualization indicates the breakdown of long-range correlations. These characteristics have been previously seen in the HRV dynamics during non-REM sleep.

  16. NMR T{sub 1} relaxation time measurements and calculations with translational and rotational components for liquid electrolytes containing LiBF{sub 4} and propylene carbonate

    SciTech Connect

    Richardson, P. M. Voice, A. M. Ward, I. M.

    2013-12-07

    Longitudinal relaxation (T{sub 1}) measurements of {sup 19}F, {sup 7}Li, and {sup 1}H in propylene carbonate/LiBF{sub 4} liquid electrolytes are reported. Comparison of T{sub 1} values with those for the transverse relaxation time (T{sub 2}) confirm that the measurements are in the high temperature (low correlation time) limit of the T{sub 1} minimum. Using data from pulsed field gradient measurements of self-diffusion coefficients and measurements of solution viscosity measured elsewhere, it is concluded that although in general there are contributions to T{sub 1} from both translational and rotational motions. For the lithium ions, this is mainly translational, and for the fluorine ions mainly rotational.

  17. Impact of neonate haematocrit variability on the longitudinal relaxation time of blood: Implications for arterial spin labelling MRI

    PubMed Central

    De Vis, J.B.; Hendrikse, J.; Groenendaal, F.; de Vries, L.S.; Kersbergen, K.J.; Benders, M.J.N.L.; Petersen, E.T.

    2014-01-01

    Background and purpose The longitudinal relaxation time of blood (T1b) is influenced by haematocrit (Hct) which is known to vary in neonates. The purpose of this study was threefold: to obtain T1b values in neonates, to investigate how the T1b influences quantitative arterial spin labelling (ASL), and to evaluate if known relationships between T1b and haematocrit (Hct) hold true when Hct is measured by means of a point-of-care device. Materials and methods One hundred and four neonates with 120 MR scan sessions (3 T) were included. The T1b was obtained from a T1 inversion recovery sequence. T1b-induced changes in ASL cerebral blood flow estimates were evaluated. The Hct was obtained by means of a point-of-care device. Linear regression analysis was used to investigate the relation between Hct and MRI-derived R1 of blood (the inverse of the T1b). Results Mean T1b was 1.85 s (sd 0.2 s). The mean T1b in preterm neonates was 1.77 s, 1.89 s in preterm neonates scanned at term-equivalent age (TEA) and 1.81 s in diseased neonates. The T1b in the TEA was significantly different from the T1b in the preterm (p < 0.05). The change in perfusion induced by the T1b was −11% (sd 9.1%, p < 0.001). The relation between arterial-drawn Hct and R1b was R1b = 0.80 × Hct + 0.22, which falls within the confidence interval of the previously established relationships, whereas capillary-drawn Hct did not correlate with R1b. Conclusion We demonstrated a wide variability of the T1b in neonates and the implications it could have in methods relying on the actual T1b as for instance ASL. It was concluded that arterial-drawn Hct values obtained from a point-of-care device can be used to infer the T1b whereas our data did not support the use of capillary-drawn Hct for T1b correction. PMID:24818078

  18. Radiofrequency (RF) Coil Impacts the Value and Reproducibility of Cartilage Spin-Spin (T2) Relaxation Time Measurements

    PubMed Central

    Dardzinski, BJ; Schneider, E

    2013-01-01

    Introduction T2 (spin-spin) relaxation time is frequently used for compositional assessment of articular cartilage. However little is known about the influence of MR system components on these measurements. The reproducibility and range of cartilage T2 values were evaluated using different extremity radiofrequency (RF) coils with potential differences in flip angle uniformity and SNR. Method Ten knees underwent 3 Tesla MR exams using RF coils with different signal-to-noise (SNR): quadrature transmit/receive (QTR); quadrature transmit/eight-channel phased-array receive (QT8PAR). Each knee was scanned twice per coil (4 exams total). T2 values were calculated for the central medial and lateral femoral (cMF, cLF) and medial and lateral tibial (MT, LT) cartilage. Results The flip angle varied across a central 40mm diameter region-of-interest of each coil by <1.5%. However SNR was significantly higher using QT8PAR than QTR (p<0.001). T2 values for cMF (50.7msec/45.9msec) and MT (48.2msec/41.6msec) were significantly longer with QT8PAR than QTR (p<0.05). T2 reproducibility was improved using QT8PAR for cMF and cLF (4.8%/5.8% and 4.1%/6.5%; p<0.001), similar for LT (3.8%/3.6%; p=1.0), and worse for MT (3.7%/3.3%; p<0.001). T2 varied spatially, with cLF having the longest (52.0msec) and the LT having the shortest (40.6msec) values. All deep cartilage had significantly longer, and less variable, T2 values using QT8PAR (higher SNR; p<0.03). Conclusions SNR varied spatially depending upon coil, but refocusing flip angle did not. With higher SNR, significantly longer T2 values were measured for deep (all plates) and global (MT, cMF) cartilage. T2 values varied by depth and plate, in agreement with prior studies. PMID:23376528

  19. Native myocardial longitudinal (T 1) relaxation time: Regional, age, and sex associations in the healthy adult heart

    PubMed Central

    Rauhalammi, Samuli M.O.; Mangion, Kenneth; Barrientos, Pauline Hall; Carrick, David J.A.; Clerfond, Guillaume; McClure, John; McComb, Christie; Radjenovic, Aleksandra

    2016-01-01

    Purpose To use magnetic resonance imaging (MRI) at two field strengths to assess healthy adults' regional myocardial noncontrast (native) T 1 relaxation time distribution, and global myocardial native T 1 between sexes and across age groups. Materials and Methods In all, 84 healthy volunteers underwent MRI at 1.5T and 3.0T. T 1 maps were acquired in three left ventricular short axis slices using an optimized modified Look–Locker inversion recovery investigational prototype sequence. T 1 measurements in msec were calculated from 16 regions‐of‐interest, and a global T 1 value from all evaluable segments per subject. Associations were assessed with a multivariate linear regression model. Results In total, 1297 (96.5%) segments were evaluable at 1.5T and 1263 (94.0%) segments at 3.0T. Native T 1 was higher in septal than lateral myocardium (1.5T: 956.3 ± 44.4 vs. 939.2 ± 54.2 msec; P < 0.001; 3.0T: 1158.2 ± 45.9 vs. 1148.9 ± 56.9 msec; P = 0.012). Native T 1 decreased with increasing age in females but not in males. Among lowest age tertile (<33 years) global native T 1 was higher in females than in males at 1.5T (960.0 ± 20.3 vs. 931.5 ± 22.2 msec, respectively; P = 0.003) and 3.0T (1166.5 ± 19.7 vs. 1130.2 ± 20.6 msec; P < 0.001). No sex differences were observed in upper age tertile (≥55 years) at 1.5T (937.7 ± 25.4 vs. 934.7 ± 22.3 msec; P = 0.762) or 3.0T (1153.0 ± 30.0 vs. 1132.3 ± 23.5 msec; P = 0.056). Association of global native T 1 to age (P = 0.002) and sex (P < 0.001) was independent of field strength and body size. Conclusion In healthy adults, native T 1 values are highest in the ventricular septum. Global native T 1 was inversely associated with age in women, but not in men. J. Magn. Reson. Imaging 2016;44:541–548. PMID:26946323

  20. Segregation time-scales in model granular flows

    NASA Astrophysics Data System (ADS)

    Staron, Lydie; Phillips, Jeremy C.

    2016-04-01

    Segregation patterns in natural granular systems offer a singular picture of the systems evolution. In many cases, understanding segregation dynamics may help understanding the system's history as well as its future evolution. Among the key questions, one concerns the typical time-scales at which segregation occurs. In this contribution, we present model granular flows simulated by means of the discrete Contact Dynamics method. The granular flows are bi-disperse, namely exhibiting two grain sizes. The flow composition and its dynamics are systematically varied, and the segregation dynamics carefully analyzed. We propose a physical model for the segregation that gives account of the observed dependence of segregation time scales on composition and dynamics. References L. Staron and J. C. Phillips, Stress partition and micro-structure in size-segregating granular flows, Phys. Rev. E 92 022210 (2015) L. Staron and J. C. Phillips, Segregation time-scales in bi-disperse granular flows, Phys. Fluids 26 (3), 033302 (2014)

  1. An algorithm for the Italian atomic time scale

    NASA Technical Reports Server (NTRS)

    Cordara, F.; Vizio, G.; Tavella, P.; Pettiti, V.

    1994-01-01

    During the past twenty years, the time scale at the IEN has been realized by a commercial cesium clock, selected from an ensemble of five, whose rate has been continuously steered towards UTC to maintain a long term agreement within 3 x 10(exp -13). A time scale algorithm, suitable for a small clock ensemble and capable of improving the medium and long term stability of the IEN time scale, has been recently designed taking care of reducing the effects of the seasonal variations and the sudden frequency anomalies of the single cesium clocks. The new time scale, TA(IEN), is obtained as a weighted average of the clock ensemble computed once a day from the time comparisons between the local reference UTC(IEN) and the single clocks. It is foreseen to include in the computation also ten cesium clocks maintained in other Italian laboratories to further improve its reliability and its long term stability. To implement this algorithm, a personal computer program in Quick Basic has been prepared and it has been tested at the IEN time and frequency laboratory. Results obtained using this algorithm on the real clocks data relative to a period of about two years are presented.

  2. Evaluation of Scaling Invariance Embedded in Short Time Series

    PubMed Central

    Pan, Xue; Hou, Lei; Stephen, Mutua; Yang, Huijie; Zhu, Chenping

    2014-01-01

    Scaling invariance of time series has been making great contributions in diverse research fields. But how to evaluate scaling exponent from a real-world series is still an open problem. Finite length of time series may induce unacceptable fluctuation and bias to statistical quantities and consequent invalidation of currently used standard methods. In this paper a new concept called correlation-dependent balanced estimation of diffusion entropy is developed to evaluate scale-invariance in very short time series with length . Calculations with specified Hurst exponent values of show that by using the standard central moving average de-trending procedure this method can evaluate the scaling exponents for short time series with ignorable bias () and sharp confidential interval (standard deviation ). Considering the stride series from ten volunteers along an approximate oval path of a specified length, we observe that though the averages and deviations of scaling exponents are close, their evolutionary behaviors display rich patterns. It has potential use in analyzing physiological signals, detecting early warning signals, and so on. As an emphasis, the our core contribution is that by means of the proposed method one can estimate precisely shannon entropy from limited records. PMID:25549356

  3. Evaluation of scaling invariance embedded in short time series.

    PubMed

    Pan, Xue; Hou, Lei; Stephen, Mutua; Yang, Huijie; Zhu, Chenping

    2014-01-01

    Scaling invariance of time series has been making great contributions in diverse research fields. But how to evaluate scaling exponent from a real-world series is still an open problem. Finite length of time series may induce unacceptable fluctuation and bias to statistical quantities and consequent invalidation of currently used standard methods. In this paper a new concept called correlation-dependent balanced estimation of diffusion entropy is developed to evaluate scale-invariance in very short time series with length ~10(2). Calculations with specified Hurst exponent values of 0.2,0.3,...,0.9 show that by using the standard central moving average de-trending procedure this method can evaluate the scaling exponents for short time series with ignorable bias (≤0.03) and sharp confidential interval (standard deviation ≤0.05). Considering the stride series from ten volunteers along an approximate oval path of a specified length, we observe that though the averages and deviations of scaling exponents are close, their evolutionary behaviors display rich patterns. It has potential use in analyzing physiological signals, detecting early warning signals, and so on. As an emphasis, the our core contribution is that by means of the proposed method one can estimate precisely shannon entropy from limited records.

  4. Time scales for molecule formation by ion-molecule reactions

    NASA Technical Reports Server (NTRS)

    Langer, W. D.; Glassgold, A. E.

    1976-01-01

    Analytical solutions are obtained for nonlinear differential equations governing the time-dependence of molecular abundances in interstellar clouds. Three gas-phase reaction schemes are considered separately for the regions where each dominates. The particular case of CO, and closely related members of the Oh and CH families of molecules, is studied for given values of temperature, density, and the radiation field. Nonlinear effects and couplings with particular ions are found to be important. The time scales for CO formation range from 100,000 to a few million years, depending on the chemistry and regime. The time required for essentially complete conversion of C(+) to CO in the region where the H3(+) chemistry dominates is several million years. Because this time is longer than or comparable to dynamical time scales for dense interstellar clouds, steady-state abundances may not be observed in such clouds.

  5. Memory on multiple time-scales in an Abelian sandpile

    NASA Astrophysics Data System (ADS)

    Sokolov, Andrey; Melatos, Andrew; Kieu, Tien; Webster, Rachel

    2015-06-01

    We report results of a numerical analysis of the memory effects in two-dimensional Abelian sandpiles. It is found that a sandpile forgets its instantaneous configuration in two distinct stages: a fast stage and a slow stage, whose durations roughly scale as N and N2 respectively, where N is the linear size of the sandpile. We confirm the presence of the longer time-scale by an independent diagnostic based on analysing emission probabilities of a hidden Markov model applied to a time-averaged sequence of avalanche sizes. The application of hidden Markov modelling to the output of sandpiles is novel. It discriminates effectively between a sandpile time series and a shuffled control time series with the same time-averaged event statistics and hence deserves further development as a pattern-recognition tool for Abelian sandpiles.

  6. Initial evaluation of hepatic T1 relaxation time as an imaging marker of liver disease associated with autosomal recessive polycystic kidney disease (ARPKD).

    PubMed

    Gao, Ying; Erokwu, Bernadette O; DeSantis, David A; Croniger, Colleen M; Schur, Rebecca M; Lu, Lan; Mariappuram, Jose; Dell, Katherine M; Flask, Chris A

    2016-01-01

    Autosomal recessive polycystic kidney disease (ARPKD) is a potentially lethal multi-organ disease affecting both the kidneys and the liver. Unfortunately, there are currently no non-invasive methods to monitor liver disease progression in ARPKD patients, limiting the study of potential therapeutic interventions. Herein, we perform an initial investigation of T1 relaxation time as a potential imaging biomarker to quantitatively assess the two primary pathologic hallmarks of ARPKD liver disease: biliary dilatation and periportal fibrosis in the PCK rat model of ARPKD. T1 relaxation time results were obtained for five PCK rats at 3 months of age using a Look-Locker acquisition on a Bruker BioSpec 7.0 T MRI scanner. Six three-month-old Sprague-Dawley (SD) rats were also scanned as controls. All animals were euthanized after the three-month scans for histological and biochemical assessments of bile duct dilatation and hepatic fibrosis for comparison. PCK rats exhibited significantly increased liver T1 values (mean ± standard deviation = 935 ± 39 ms) compared with age-matched SD control rats (847 ± 26 ms, p = 0.01). One PCK rat exhibited severe cholangitis (mean T1  = 1413 ms), which occurs periodically in ARPKD patients. The observed increase in the in vivo liver T1 relaxation time correlated significantly with three histological and biochemical indicators of biliary dilatation and fibrosis: bile duct area percent (R = 0.85, p = 0.002), periportal fibrosis area percent (R = 0.82, p = 0.004), and hydroxyproline content (R = 0.76, p = 0.01). These results suggest that hepatic T1 relaxation time may provide a sensitive and non-invasive imaging biomarker to monitor ARPKD liver disease.

  7. The Galaxy Viewed at Very Short Time-Scales

    NASA Astrophysics Data System (ADS)

    Radnia, Navid; Siegmund, O.; Welsh, B.; Mcphate, J.; Rogers, D.; Charles, P.; Buckley, D.

    2010-01-01

    We present high time-resolution astronomical observations recorded with the Berkeley Visible Image Tube (BVIT) photon counting detector mounted on the 10m South African Large Telescope (SALT). Relative B and V-band photometric fluxes were obtained as a function of time for targets that included Polar-type cataclysmic variables (UZ For, OY Car, V1033Cen), low-mass X-ray binaries (GX 339-4, UY Vol), pulsars (PSR 0540-69), dMe flare stars (CN Leo) and active galactic nucleii (Mkn 618). These observations, which were recorded during several nights of engineering time at SALT in early 2009, indicate that there are many types of astrophysical processes operating over very short time-scales in a wide variety of astronomical objects. The high-time resolution capability of the BVIT detector allowed emission features occurring on time-scales as short as tens of milli-seconds to be revealed. In particular, we have measured the optical period of the PSR 0540-69 pulsar to be 0.05065018808s and we have also detected several quasi-periodic oscillations operating on time-scales of < 0.5 s in the emitted flux from the X-ray transient source, GX 339-4. These preliminary data indicate that the new field of high time-resolution astronomy is providing important new insights into the transient nature of the Universe.

  8. Renormalized time scale for anticipating and lagging synchronization.

    PubMed

    Hayashi, Yoshikatsu; Nasuto, Slawomir J; Eberle, Henry

    2016-05-01

    Anticipating synchronization has been recently proposed as a mechanism of interaction in dynamical systems which are able to bring about predictions of future states of a driver system. We suggest that an interesting insight into anticipating synchronization can be obtained by the renormalization of the time scale in the driven system. Our approach directly links the feedback delay of the driven system with the renormalized time scale of the driven system, identifying the main component in the anticipating synchronization paradigm and suggesting an alternative method to generate anticipating and lagging synchronization. PMID:27300902

  9. Dynamics symmetries of Hamiltonian system on time scales

    SciTech Connect

    Peng, Keke Luo, Yiping

    2014-04-15

    In this paper, the dynamics symmetries of Hamiltonian system on time scales are studied. We study the symmetries and quantities based on the calculation of variation and Lie transformation group. Particular focus lies in: the Noether symmetry leads to the Noether conserved quantity and the Lie symmetry leads to the Noether conserved quantity if the infinitesimal transformations satisfy the structure equation. As the new application of result, at end of the article, we give a simple example of Noether symmetry and Lie symmetry on time scales.

  10. Dynamics of condensate formation in stochastic transport with pair-factorized steady states: Nucleation and coarsening time scales.

    PubMed

    Nagel, Hannes; Janke, Wolfhard

    2016-05-01

    Driven diffusive systems such as the zero-range process (ZRP) and the pair-factorized steady states (PFSS) stochastic transport process are versatile tools that lend themselves to the study of transport phenomena on a generic level. While their mathematical structure is simple enough to allow significant analytical treatment, they offer a variety of interesting phenomena. With appropriate dynamics, the ZRP and PFSS models feature a condensation transition where, for a supercritical density, the translational symmetry breaks spontaneously and excess particles form a single-site or spatially extended condensate, respectively. In this paper we numerically study the typical time scales of the two stages of this condensation process: Nucleation and coarsening. Nucleation is the first stage of condensation where the bulk system relaxes to its stationary distribution and droplet nuclei form in the system. These droplets then gradually grow or evaporate in the coarsening regime to coalesce in a single condensate when the system finally relaxes to the stationary state. We use the ZRP condensation model to discuss the choice of the estimation method for the nucleation time scale and present scaling exponents for the ZRP and PFSS condensation models with respect to the choice of the typical droplet nuclei mass. We then proceed to present scaling exponents in the coarsening regime of the ZRP for partially asymmetric dynamics and the PFSS model for symmetric and asymmetric dynamics. PMID:27300835

  11. Dynamics of condensate formation in stochastic transport with pair-factorized steady states: Nucleation and coarsening time scales

    NASA Astrophysics Data System (ADS)

    Nagel, Hannes; Janke, Wolfhard

    2016-05-01

    Driven diffusive systems such as the zero-range process (ZRP) and the pair-factorized steady states (PFSS) stochastic transport process are versatile tools that lend themselves to the study of transport phenomena on a generic level. While their mathematical structure is simple enough to allow significant analytical treatment, they offer a variety of interesting phenomena. With appropriate dynamics, the ZRP and PFSS models feature a condensation transition where, for a supercritical density, the translational symmetry breaks spontaneously and excess particles form a single-site or spatially extended condensate, respectively. In this paper we numerically study the typical time scales of the two stages of this condensation process: Nucleation and coarsening. Nucleation is the first stage of condensation where the bulk system relaxes to its stationary distribution and droplet nuclei form in the system. These droplets then gradually grow or evaporate in the coarsening regime to coalesce in a single condensate when the system finally relaxes to the stationary state. We use the ZRP condensation model to discuss the choice of the estimation method for the nucleation time scale and present scaling exponents for the ZRP and PFSS condensation models with respect to the choice of the typical droplet nuclei mass. We then proceed to present scaling exponents in the coarsening regime of the ZRP for partially asymmetric dynamics and the PFSS model for symmetric and asymmetric dynamics.

  12. Midfrontal theta tracks action monitoring over multiple interactive time scales.

    PubMed

    Cohen, Michael X

    2016-11-01

    Quickly detecting and correcting mistakes is a crucial brain function. EEG studies have identified an idiosyncratic electrophysiological signature of online error correction, termed midfrontal theta. Midfrontal theta has so far been investigated over the fast time-scale of a few hundred milliseconds. But several aspects of behavior and brain activity unfold over multiple time scales, displaying "scale-free" dynamics that have been linked to criticality and optimal flexibility when responding to changing environmental demands. Here we used a novel line-tracking task to demonstrate that midfrontal theta is a transient yet non-phase-locked response that is modulated by task performance over at least three time scales: a few hundred milliseconds at the onset of a mistake, task performance over a fixed window of the previous 5s, and scale-free-like fluctuations over many tens of seconds. These findings provide novel evidence for a role of midfrontal theta in online behavioral adaptation, and suggest new approaches for linking EEG signatures of human executive functioning to its neurobiological underpinnings. PMID:27475291

  13. Midfrontal theta tracks action monitoring over multiple interactive time scales.

    PubMed

    Cohen, Michael X

    2016-11-01

    Quickly detecting and correcting mistakes is a crucial brain function. EEG studies have identified an idiosyncratic electrophysiological signature of online error correction, termed midfrontal theta. Midfrontal theta has so far been investigated over the fast time-scale of a few hundred milliseconds. But several aspects of behavior and brain activity unfold over multiple time scales, displaying "scale-free" dynamics that have been linked to criticality and optimal flexibility when responding to changing environmental demands. Here we used a novel line-tracking task to demonstrate that midfrontal theta is a transient yet non-phase-locked response that is modulated by task performance over at least three time scales: a few hundred milliseconds at the onset of a mistake, task performance over a fixed window of the previous 5s, and scale-free-like fluctuations over many tens of seconds. These findings provide novel evidence for a role of midfrontal theta in online behavioral adaptation, and suggest new approaches for linking EEG signatures of human executive functioning to its neurobiological underpinnings.

  14. Broad-scale gravity changes following the 2011 Tohoku-Oki thrust and 2012 Indian Ocean strike-slip earthquakes and implications for coseismic dilatation and viscoelastic relaxation

    NASA Astrophysics Data System (ADS)

    Han, S. C.; Sauber, J. M.; Pollitz, F. F.; Riva, R.; Okal, E. A.

    2014-12-01

    We analyzed spatially- and temporally-continuous GRACE gravity observations by decomposing the gravity field changes into five independent moment tensor elements to understand the regional surface and interior deformation in response to post-earthquake stress/strain redistribution. For the 2011 Tohoku-Oki thrust earthquake, the GRACE data revealed postseismic gravity increase by 6 microGal over a 500-km scale within a couple of years, which is nearly 40-50 % of the coseismic gravity change. It originates mostly from changes in the isotropic component corresponding to the Mrr moment tensor element. For the 2012 Indian Ocean strike-slip earthquakes, the postseismic gravity change was similar to the coseismic change (including the Mw 8.6 and Mw 8.2 ruptures) with the magnitude smaller by ~80 % in two years. The gravity change corresponding to the Mtp moment tensor element is dominant (and also Mtt-Mpp to a lesser extent). In both earthquakes, the exponential decay with rapid change within a year and gradual change afterwards is a characteristic temporal pattern. We also compared the two earthquakes in terms of their respective seafloor vertical and interior deformation (Bouguer gravity). The processes responsible for the coseismic and postseismic gravity changes at a such spatial scale are, respectively, the density change (dilatation) and the viscoelastic deformation without much perturbation in density. The postseismic gravity variation is best modeled by bi-viscous relaxation with a transient and steady-state viscosity of 10^18 and 10^19 Pa s, respectively, for the asthenosphere. Furthermore, we found viscoelastic relaxation triggered by the partially-ruptured elastic lithosphere is a main driver of the local subsidence above the rupture region reported from the GPS-acoustic seafloor surveying after the 2011 Tohoku-Oki earthquake.

  15. Relaxation dynamics in correlated quantum dots

    SciTech Connect

    Andergassen, S.; Schuricht, D.; Pletyukhov, M.; Schoeller, H.

    2014-12-04

    We study quantum many-body effects on the real-time evolution of the current through quantum dots. By using a non-equilibrium renormalization group approach, we provide analytic results for the relaxation dynamics into the stationary state and identify the microscopic cutoff scales that determine the transport rates. We find rich non-equilibrium physics induced by the interplay of the different energy scales. While the short-time limit is governed by universal dynamics, the long-time behavior features characteristic oscillations as well as an interplay of exponential and power-law decay.

  16. Time Scale Calculus - a new perspectives for synthetic seismogram calculations

    NASA Astrophysics Data System (ADS)

    Waskiewicz, Kamil; Debski, Wojciech

    2013-04-01

    Synthetic, numerically generated seismograms are one of the key factors of any interpretation of recorded seismic data. At the early stage of development, calculation of full seismic waveforms was impossible due to a limited computational resource so we were forced to used only some selected characteristics of seismic waves relatively easy for numerical calculations like first arrival times, maximum amplitude, approximate source spectra, to name a few. Continues development of computational resources as well as progress in numerical techniques has opened possibilities of generation the full, 3-component seismograms incorporating many physically important elements like wave attenuation, anisotropy or randomness of the media. Although achieved results are impressive we still need new numerical methods to tackle existing problems with the synthetic seismogram generation. In this contribution we present a novel approach to discretization of the wave equation which brings together continues and discrete numerical analysis of the seismic waves. The foundations of this new technique, called Time Scale Calculus, have been formulated by Hilger in late eighties and is very dynamically developing. The Time scale calculus, due to its universality seems to have a great potential when practical applications are considered. Thus we have decided to bring the Time Scale calculus concept closer to geophysical, or more precisely to seismological applications. This presentation is intend as a basic introduction to the time scales calculus considered from seismological point of view. We shortly present and discuss the possibility of using the Time Scales (TS) technique for solving the simplest acoustic 2D wave equation keeping in mind its particular applications for mining induced seismicity.

  17. Separation of time scales in the HCA model for sand

    NASA Astrophysics Data System (ADS)

    Niemunis, Andrzej; Wichtmann, Torsten

    2014-10-01

    Separation of time scales is used in a high cycle accumulation (HCA) model for sand. An important difficulty of the model is the limited applicability of the Miner's rule to multiaxial cyclic loadings applied simultaneously or in a combination with monotonic loading. Another problem is the lack of simplified objective HCA formulas for geotechnical settlement problems. Possible solutions of these problems are discussed.

  18. Speech Compensation for Time-Scale-Modified Auditory Feedback

    ERIC Educational Resources Information Center

    Ogane, Rintaro; Honda, Masaaki

    2014-01-01

    Purpose: The purpose of this study was to examine speech compensation in response to time-scale-modified auditory feedback during the transition of the semivowel for a target utterance of /ija/. Method: Each utterance session consisted of 10 control trials in the normal feedback condition followed by 20 perturbed trials in the modified auditory…

  19. Maximum principles for second order dynamic equations on time scales

    NASA Astrophysics Data System (ADS)

    Stehlik, Petr; Thompson, Bevan

    2007-07-01

    This paper establishes some new maximum principles for second order dynamic equations on time scales, including: a strong maximum principle; a generalized maximum principle; and a boundary point lemma. The new results include, as special cases, well-known ideas for ordinary differential equations and difference equations.

  20. Gott Time Machines, BTZ Black Hole Formation, and Choptuik Scaling

    NASA Astrophysics Data System (ADS)

    Birmingham, Danny; Sen, Siddhartha

    2000-02-01

    We study the formation of Bañados-Teitelboim-Zanelli black holes by the collision of point particles. It is shown that the Gott time machine, originally constructed for the case of vanishing cosmological constant, provides a precise mechanism for black hole formation. As a result, one obtains an exact analytic understanding of the Choptuik scaling.

  1. Time scale algorithm: Definition of ensemble time and possible uses of the Kalman filter

    NASA Technical Reports Server (NTRS)

    Tavella, Patrizia; Thomas, Claudine

    1990-01-01

    The comparative study of two time scale algorithms, devised to satisfy different but related requirements, is presented. They are ALGOS(BIPM), producing the international reference TAI at the Bureau International des Poids et Mesures, and AT1(NIST), generating the real-time time scale AT1 at the National Institute of Standards and Technology. In each case, the time scale is a weighted average of clock readings, but the weight determination and the frequency prediction are different because they are adapted to different purposes. The possibility of using a mathematical tool, such as the Kalman filter, together with the definition of the time scale as a weighted average, is also analyzed. Results obtained by simulation are presented.

  2. An improved method to analyze the stress relaxation of ligaments following a finite ramp time based on the quasi-linear viscoelastic theory.

    PubMed

    Abramowitch, Steven D; Woo, Savio L

    2004-02-01

    The quasi-linear viscoelastic (QLV) theory proposed by Fung (1972) has been frequently used to model the nonlinear time- and history-dependent viscoelastic behavior of many soft tissues. It is common to use five constants to describe the instantaneous elastic response (constants A and B) and reduced relaxation function (constants C, tau 1, and tau 2) on experiments with finite ramp times followed by stress relaxation to equilibrium. However, a limitation is that the theory is based on a step change in strain which is not possible to perform experimentally. Accounting for this limitation may result in regression algorithms that converge poorly and yield nonunique solutions with highly variable constants, especially for long ramp times (Kwan et al. 1993). The goal of the present study was to introduce an improved approach to obtain the constants for QLV theory that converges to a unique solution with minimal variability. Six goat femur-medial collateral ligament-tibia complexes were subjected to a uniaxial tension test (ramp time of 18.4 s) followed by one hour of stress relaxation. The convoluted QLV constitutive equation was simultaneously curve-fit to the ramping and relaxation portions of the data (r2 > 0.99). Confidence intervals of the constants were generated from a bootstrapping analysis and revealed that constants were distributed within 1% of their median values. For validation, the determined constants were used to predict peak stresses from a separate cyclic stress relaxation test with averaged errors across all specimens measuring less than 6.3 +/- 6.0% of the experimental values. For comparison, an analysis that assumed an instantaneous ramp time was also performed and the constants obtained for the two approaches were compared. Significant differences were observed for constants B, C, tau 1, and tau 2, with tau 1 differing by an order of magnitude. By taking into account the ramping phase of the experiment, the approach allows for viscoelastic

  3. THEORETICAL REVIEW The Hippocampus, Time, and Memory Across Scales

    PubMed Central

    Howard, Marc W.; Eichenbaum, Howard

    2014-01-01

    A wealth of experimental studies with animals have offered insights about how neural networks within the hippocampus support the temporal organization of memories. These studies have revealed the existence of “time cells” that encode moments in time, much as the well-known “place cells” map locations in space. Another line of work inspired by human behavioral studies suggests that episodic memories are mediated by a state of temporal context that changes gradually over long time scales, up to at least a few thousand seconds. In this view, the “mental time travel” hypothesized to support the experience of episodic memory corresponds to a “jump back in time” in which a previous state of temporal context is recovered. We suggest that these 2 sets of findings could be different facets of a representation of temporal history that maintains a record at the last few thousand seconds of experience. The ability to represent long time scales comes at the cost of discarding precise information about when a stimulus was experienced—this uncertainty becomes greater for events further in the past. We review recent computational work that describes a mechanism that could construct such a scale-invariant representation. Taken as a whole, this suggests the hippocampus plays its role in multiple aspects of cognition by representing events embedded in a general spatiotemporal context. The representation of internal time can be useful across nonhippocampal memory systems. PMID:23915126

  4. Improvement of the relaxation time and the order parameter of nematic liquid crystal using a hybrid alignment mixture of carbon nanotube and polyimide

    SciTech Connect

    Lee, Hyojin; Yang, Seungbin; Lee, Ji-Hoon; Soo Park, Young

    2014-05-12

    We examined the electrooptical properties of a nematic liquid crystal (LC) sample whose substrates were coated with a mixture of carbon nanotube (CNT) and polyimide (PI). The relaxation time of the sample coated with 1.5 wt. % CNT mixture was about 35% reduced compared to the pure polyimide sample. The elastic constant and the order parameter of the CNT-mixture sample were increased and the fast relaxation of LC could be approximated to the mean-field theory. We found the CNT-mixed polyimide formed more smooth surface than the pure PI from atomic force microscopy images, indicating the increased order parameter is related to the smooth surface topology of the CNT-polyimide mixture.

  5. Characterization of a binary karst aquifer using process time scales

    NASA Astrophysics Data System (ADS)

    Birk, Steffen; Wagner, Thomas

    2013-04-01

    Within "a theoretical framework for the interpretation of karst spring signals" (Covington, EGU2012-853-1) process length scales that characterize the travel distances required for damping pulses of physicochemical parameters of spring waters such as electrical conductivity and temperature were derived (Covington et al., J. Geophys. Res., 2012). These length scales can be converted to corresponding process time scales characterizing the travel times needed for damping the pulses. This is particularly convenient if the travel distance is unknown. In this case the time lag between the increase of spring discharge and subsequent physicochemical responses at the spring may provide an estimate of the travel time. In binary karst aquifers with localized recharge from a sinking stream, the recharge pulse can be directly observed and thus travel times are readily obtained from the time delay of the physicochemical spring responses. If the spring response is strongly damped travel times can be inferred from artificial tracer testing. In this work, time scales for carbonate dissolution and heat transport were used for characterizing the binary Lurbach-Tanneben karst aquifer (Austria). This aquifer receives allogenic recharge from the sinking stream Lurbach and is drained by two springs, namely the Hammerbach and the Schmelzbach. The two springs show different thermal responses to two recharge events in December 2008: Whereas the temperature of the Schmelzbach responds within one day after the flood pulse in the Lurbach, the temperature signal is strongly damped at the Hammerbach. The evaluation based on the thermal time scale thus suggests that the Schmelzbach spring is fed by conduits with hydraulic diameters at least in the order of decimetres. In contrast, the damping of the thermal responses at the Hammerbach may be due to lower hydraulic diameters and/or longer residence times. Interestingly, the Hammerbach did show thermal responses in the time before a flood event in

  6. Experimental issues in the measurement of multi-component relaxation times in articular cartilage by microscopic MRI

    NASA Astrophysics Data System (ADS)

    Wang, Nian; Xia, Yang

    2013-10-01

    A number of experimental issues in the measurement of multi-component T2 and T1ρ relaxations in native and enzymatically digested articular cartilage were investigated by microscopic MRI (μMRI). The issues included the bath solutions (physiological saline and phosphate buffered saline (PBS)), the imaging resolution (35-140 μm), the specimen orientations (0° and 55°), and the strength of spin-lock frequencies (0.5-2 kHz) in the T1ρ experiments. In addition to cartilage, the samples of agar gel and doped water solution were also used in the investigation. Two imaging sequences were used: CPMG-SE and MSME. All raw data were analyzed by the non-negative least square (NNLS) method. The MSME sequence was shown to result in the observation of multi-component T2, even in the gel and liquid samples, demonstrating the artificial uncleanness of this sequence in the multi-component measurements. The soaking of cartilage in PBS reduced the observable T2 components to one at both 0° and 55°, suggesting the effect of phosphate ions on proton exchange between different pools of water molecules. The cartilage orientation with respect to the external magnetic field and the spin-lock strengths in the T1ρ experiment both affected the quantification of the multi-component relaxation. The transitions between a mono-component and multi-components in cartilage under various experimental conditions call for the extra caution in interpreting the relaxation results.

  7. Real-time simulation of large-scale floods

    NASA Astrophysics Data System (ADS)

    Liu, Q.; Qin, Y.; Li, G. D.; Liu, Z.; Cheng, D. J.; Zhao, Y. H.

    2016-08-01

    According to the complex real-time water situation, the real-time simulation of large-scale floods is very important for flood prevention practice. Model robustness and running efficiency are two critical factors in successful real-time flood simulation. This paper proposed a robust, two-dimensional, shallow water model based on the unstructured Godunov- type finite volume method. A robust wet/dry front method is used to enhance the numerical stability. An adaptive method is proposed to improve the running efficiency. The proposed model is used for large-scale flood simulation on real topography. Results compared to those of MIKE21 show the strong performance of the proposed model.

  8. Characterizing Complex Time Series from the Scaling of Prediction Error.

    NASA Astrophysics Data System (ADS)

    Hinrichs, Brant Eric

    This thesis concerns characterizing complex time series from the scaling of prediction error. We use the global modeling technique of radial basis function approximation to build models from a state-space reconstruction of a time series that otherwise appears complicated or random (i.e. aperiodic, irregular). Prediction error as a function of prediction horizon is obtained from the model using the direct method. The relationship between the underlying dynamics of the time series and the logarithmic scaling of prediction error as a function of prediction horizon is investigated. We use this relationship to characterize the dynamics of both a model chaotic system and physical data from the optic tectum of an attentive pigeon exhibiting the important phenomena of nonstationary neuronal oscillations in response to visual stimuli.

  9. The Available Time Scale: Measuring Foster Parents' Available Time to Foster

    ERIC Educational Resources Information Center

    Cherry, Donna J.; Orme, John G.; Rhodes, Kathryn W.

    2009-01-01

    This article presents a new measure of available time specific to fostering, the Available Time Scale (ATS). It was tested with a national sample of 304 foster mothers and is designed to measure the amount of time foster parents are able to devote to fostering activities. The ATS has excellent reliability, and good support exists for its validity.…

  10. Energy and time determine scaling in biological and computer designs.

    PubMed

    Moses, Melanie; Bezerra, George; Edwards, Benjamin; Brown, James; Forrest, Stephanie

    2016-08-19

    Metabolic rate in animals and power consumption in computers are analogous quantities that scale similarly with size. We analyse vascular systems of mammals and on-chip networks of microprocessors, where natural selection and human engineering, respectively, have produced systems that minimize both energy dissipation and delivery times. Using a simple network model that simultaneously minimizes energy and time, our analysis explains empirically observed trends in the scaling of metabolic rate in mammals and power consumption and performance in microprocessors across several orders of magnitude in size. Just as the evolutionary transitions from unicellular to multicellular animals in biology are associated with shifts in metabolic scaling, our model suggests that the scaling of power and performance will change as computer designs transition to decentralized multi-core and distributed cyber-physical systems. More generally, a single energy-time minimization principle may govern the design of many complex systems that process energy, materials and information.This article is part of the themed issue 'The major synthetic evolutionary transitions'. PMID:27431524

  11. Anomalous multiphoton photoelectric effect in ultrashort time scales.

    PubMed

    Kupersztych, J; Raynaud, M

    2005-09-30

    In a multiphoton photoelectric process, an electron needs to absorb a given number of photons to escape the surface of a metal. It is shown for the first time that this number is not a constant depending only on the characteristics of the metal and light, but varies with the interaction duration in ultrashort time scales. The phenomenon occurs when electromagnetic energy is transferred, via ultrafast excitation of electron collective modes, to conduction electrons in a duration less than the electron energy damping time. It manifests itself through a dramatic increase of electron production.

  12. Wavelet analysis and scaling properties of time series

    NASA Astrophysics Data System (ADS)

    Manimaran, P.; Panigrahi, Prasanta K.; Parikh, Jitendra C.

    2005-10-01

    We propose a wavelet based method for the characterization of the scaling behavior of nonstationary time series. It makes use of the built-in ability of the wavelets for capturing the trends in a data set, in variable window sizes. Discrete wavelets from the Daubechies family are used to illustrate the efficacy of this procedure. After studying binomial multifractal time series with the present and earlier approaches of detrending for comparison, we analyze the time series of averaged spin density in the 2D Ising model at the critical temperature, along with several experimental data sets possessing multifractal behavior.

  13. Rejuvenation in scale-free optics and enhanced diffraction cancellation life-time.

    PubMed

    Parravicini, J; Conti, C; Agranat, A J; DelRe, E

    2012-11-19

    We demonstrate rejuvenation in scale-free optical propagation. The phenomenon is caused by the non-ergodic relaxation of the dipolar glass that mediates the photorefractive nonlinearity in compositionally-disordered lithium-enriched potassium-tantalate-niobate (KTN:Li). We implement rejuvenation to halt aging in the dipolar glass and extend the duration of beam diffraction cancellation.

  14. Accuracy Assessment in rainfall upscaling in multiple time scales

    NASA Astrophysics Data System (ADS)

    Yu, H.; Wang, C.; Lin, Y.

    2008-12-01

    Long-term hydrologic parameters, e.g. annual precipitations, are usually used to represent the general hydrologic characteristics in a region. Recently, the analysis of the impact of climate change to hydrological patterns primarily relies on the measurement and/or the estimations in long time scales, e.g. year. Under the general condition of the prevalence of short-term measurements, therefore, it is important to understand the accuracy of upscaling for the long-term estimations of hydrologic parameters. This study applies spatiotemporal geostatistical method to analyze and discuss the accuracy of precipitation upscaling in Taiwan under the different time scales, and also quantifies the uncertainty in the upscaled long-term precipitations. In this study, two space-time upscaling approaches developed by Bayesian Maximum Entropy method (BME) are presented 1) UM1: data aggregation followed by BME estimation and 2) UM2: BME estimation followed by aggregation. The investigation and comparison are also implemented to assess the performance of the rainfall estimations in multiple time scales in Taiwan by the two upscaling. Keywords: upscaling, geostatistics, BME, uncertainty analysis

  15. Reconstructions of solar irradiance on centennial time scales

    NASA Astrophysics Data System (ADS)

    Krivova, Natalie; Solanki, Sami K.; Dasi Espuig, Maria; Kok Leng, Yeo

    Solar irradiance is the main external source of energy to Earth's climate system. The record of direct measurements covering less than 40 years is too short to study solar influence on Earth's climate, which calls for reconstructions of solar irradiance into the past with the help of appropriate models. An obvious requirement to a competitive model is its ability to reproduce observed irradiance changes, and a successful example of such a model is presented by the SATIRE family of models. As most state-of-the-art models, SATIRE assumes that irradiance changes on time scales longer than approximately a day are caused by the evolving distribution of dark and bright magnetic features on the solar surface. The surface coverage by such features as a function of time is derived from solar observations. The choice of these depends on the time scale in question. Most accurate is the version of the model that employs full-disc spatially-resolved solar magnetograms and reproduces over 90% of the measured irradiance variation, including the overall decreasing trend in the total solar irradiance over the last four cycles. Since such magnetograms are only available for about four decades, reconstructions on time scales of centuries have to rely on disc-integrated proxies of solar magnetic activity, such as sunspot areas and numbers. Employing a surface flux transport model and sunspot observations as input, we have being able to produce synthetic magnetograms since 1700. This improves the temporal resolution of the irradiance reconstructions on centennial time scales. The most critical aspect of such reconstructions remains the uncertainty in the magnitude of the secular change.

  16. Time scale of diffusion in molecular and cellular biology

    NASA Astrophysics Data System (ADS)

    Holcman, D.; Schuss, Z.

    2014-05-01

    Diffusion is the driver of critical biological processes in cellular and molecular biology. The diverse temporal scales of cellular function are determined by vastly diverse spatial scales in most biophysical processes. The latter are due, among others, to small binding sites inside or on the cell membrane or to narrow passages between large cellular compartments. The great disparity in scales is at the root of the difficulty in quantifying cell function from molecular dynamics and from simulations. The coarse-grained time scale of cellular function is determined from molecular diffusion by the mean first passage time of molecular Brownian motion to a small targets or through narrow passages. The narrow escape theory (NET) concerns this issue. The NET is ubiquitous in molecular and cellular biology and is manifested, among others, in chemical reactions, in the calculation of the effective diffusion coefficient of receptors diffusing on a neuronal cell membrane strewn with obstacles, in the quantification of the early steps of viral trafficking, in the regulation of diffusion between the mother and daughter cells during cell division, and many other cases. Brownian trajectories can represent the motion of a molecule, a protein, an ion in solution, a receptor in a cell or on its membrane, and many other biochemical processes. The small target can represent a binding site or an ionic channel, a hidden active site embedded in a complex protein structure, a receptor for a neurotransmitter on the membrane of a neuron, and so on. The mean time to attach to a receptor or activator determines diffusion fluxes that are key regulators of cell function. This review describes physical models of various subcellular microdomains, in which the NET coarse-grains the molecular scale to a higher cellular-level, thus clarifying the role of cell geometry in determining subcellular function.

  17. Sublinear scaling for time-dependent stochastic density functional theory

    SciTech Connect

    Gao, Yi; Neuhauser, Daniel; Baer, Roi; Rabani, Eran

    2015-01-21

    A stochastic approach to time-dependent density functional theory is developed for computing the absorption cross section and the random phase approximation (RPA) correlation energy. The core idea of the approach involves time-propagation of a small set of stochastic orbitals which are first projected on the occupied space and then propagated in time according to the time-dependent Kohn-Sham equations. The evolving electron density is exactly represented when the number of random orbitals is infinite, but even a small number (≈16) of such orbitals is enough to obtain meaningful results for absorption spectrum and the RPA correlation energy per electron. We implement the approach for silicon nanocrystals using real-space grids and find that the overall scaling of the algorithm is sublinear with computational time and memory.

  18. Thermal lens measurements in liquids on a submicrosecond time scale

    SciTech Connect

    Isak, S. J.; Komorowski, S. J.; Merrow, C. N.; Poston, P. E.; Eyring, E. M.

    1989-03-01

    The use of the thermal lens method is shown to be quite suitable for kinetic studies of quenching on a submicrosecond time scale. The lower limit of time resolution that can be achieved is determined by the acoustic transit time, /tau//sub /ital a//, in the medium. A thermal lens signal with a 100-ns time constant due to the quenched triplet state of benzophenone is readily measured. The thermal lens method is superior to the photoacoustic (PA) method in the breadth of the accessible time range, and in the significantly fewer measurements required to obtain accurate data, including no requirement for a reference sample; it is also less sensitive to geometrical and laser power requirements than is the PA method.

  19. In situ determination of surface relaxivities for unconsolidated sediments

    NASA Astrophysics Data System (ADS)

    Duschl, Markus; Galvosas, Petrik; Brox, Timothy I.; Pohlmeier, Andreas; Vereecken, Harry

    2015-08-01

    NMR relaxometry has developed into a method for rapid pore-size determination of natural porous media. Nevertheless, it is prone to uncertainties because of unknown surface relaxivities which depend mainly on the chemical composition of the pore walls as well as on the interfacial dynamics of the pore fluid. The classical approach for the determination of surface relaxivities is the scaling of NMR relaxation times by surface to volume ratios measured by gas adsorption or mercury intrusion. However, it is preferable that a method for the determination of average pore sizes uses the same substance, water, as probe molecule for both relaxometry and surface to volume measurements. One should also ensure that in both experiments the dynamics of the probe molecule takes place on similar length scales, which are in the order of some microns. Therefore, we employed NMR diffusion measurements with different observation times using bipolar pulsed field gradients and applied them to unconsolidated sediments (two purified sands, two natural sands, and one soil). The evaluation by Mitra's short-time model for diffusion in restricted environments yielded information about the surface to volume ratios which is independent of relaxation mechanisms. We point out that methods based on NMR diffusometry yield pore dimensions and surface relaxivities consistent with a pore space as sampled by native pore fluids via the diffusion process. This opens a way to calibrate NMR relaxation measurements with other NMR techniques, providing information about the pore-size distribution of natural porous media directly from relaxometry.

  20. Entropy Production of Nanosystems with Time Scale Separation

    NASA Astrophysics Data System (ADS)

    Wang, Shou-Wen; Kawaguchi, Kyogo; Sasa, Shin-ichi; Tang, Lei-Han

    2016-08-01

    Energy flows in biomolecular motors and machines are vital to their function. Yet experimental observations are often limited to a small subset of variables that participate in energy transport and dissipation. Here we show, through a solvable Langevin model, that the seemingly hidden entropy production is measurable through the violation spectrum of the fluctuation-response relation of a slow observable. For general Markov systems with time scale separation, we prove that the violation spectrum exhibits a characteristic plateau in the intermediate frequency region. Despite its vanishing height, the plateau can account for energy dissipation over a broad time scale. Our findings suggest a general possibility to probe hidden entropy production in nanosystems without direct observation of fast variables.

  1. Entropy Production of Nanosystems with Time Scale Separation.

    PubMed

    Wang, Shou-Wen; Kawaguchi, Kyogo; Sasa, Shin-Ichi; Tang, Lei-Han

    2016-08-12

    Energy flows in biomolecular motors and machines are vital to their function. Yet experimental observations are often limited to a small subset of variables that participate in energy transport and dissipation. Here we show, through a solvable Langevin model, that the seemingly hidden entropy production is measurable through the violation spectrum of the fluctuation-response relation of a slow observable. For general Markov systems with time scale separation, we prove that the violation spectrum exhibits a characteristic plateau in the intermediate frequency region. Despite its vanishing height, the plateau can account for energy dissipation over a broad time scale. Our findings suggest a general possibility to probe hidden entropy production in nanosystems without direct observation of fast variables. PMID:27563943

  2. The contribution of time-dependent stress relaxation in protein gels to the recoverable energy that is used as a tool to describe food texture

    NASA Astrophysics Data System (ADS)

    de Jong, Saskia; van Vliet, Ton; de Jongh, Harmen H. J.

    2015-11-01

    The recoverable energy (RE), defined as the ratio of the work exerted on a test specimen during compression and recovered upon subsequent decompression, has been shown to correlate to sensory profiling of protein-based food products. Understanding the mechanism determining the time-dependency of RE is primordial. This work aims to identify the protein-specific impact on the recoverable energy by stress dissipation via relaxation of (micro)structural rearrangements within protein gels. To this end, caseinate and gelatin gels are studied for their response to time-dependent mechanical deformation as they are known to develop structurally distinct network morphologies. This work shows that in gelatin gels no significant stress relaxation occurs on the seconds timescale, and consequently no time-dependency of the amount of energy stored in this material is observed. In caseinate gels, however, the energy dissipation via relaxation processes does contribute significantly to the time-dependency of reversible stored energy in the network. This can explain the obtained RE as a function of applied deformation at slow deformation rates. At faster deformation, an additional contribution to the dissipated energy is apparent, that increases with the deformation rate, which might point to the role of energy dissipation related to friction of the serum entrapped by the protein-network. This work shows that engineering strategies focused on controlling viscous flow in protein gels could be more effective to dictate the ability to elastically store energy in protein gels than routes that direct protein-specific aggregation and/or network-assembly.

  3. Determination of intra-axial brain tumors cellularity through the analysis of T2 Relaxation time of brain tumors before surgery using MATLAB software

    PubMed Central

    Abdolmohammadi, Jamil; Shafiee, Mohsen; Faeghi, Fariborz; Arefan, Douman; Zali, Alireza; Motiei-Langroudi, Rouzbeh; Farshidfar, Zahra; Nazarlou, Ali Kiani; Tavakkoli, Ali; Yarham, Mohammad

    2016-01-01

    Introduction Timely diagnosis of brain tumors could considerably affect the process of patient treatment. To do so, para-clinical methods, particularly MRI, cannot be ignored. MRI has so far answered significant questions regarding tumor characteristics, as well as helping neurosurgeons. In order to detect the tumor cellularity, neuro-surgeons currently have to sample specimens by biopsy and then send them to the pathology unit. The aim of this study is to determine the tumor cellularity in the brain. Methods In this cross-sectional study, 32 patients (18 males and 14 females from 18–77 y/o) were admitted to the neurosurgery department of Shohada-E Tajrish Hospital in Tehran, Iran from April 2012 to February 2014. In addition to routine pulse sequences, T2W Multi echo pulse sequences were taken and the images were analyzed using the MATLAB software to determine the brain tumor cellularity, compared with the biopsy Results These findings illustrate the need for more T2 relaxation time decreases, the higher classes of tumors will stand out in the designed table. In this study, the results show T2 relaxation time with a 85% diagnostic weight, compared with the biopsy, to determine the brain tumor cellularity (p<0.05). Conclusion Our results indicate that the T2 relaxation time feature is the best method to distinguish and present the degree of intra-axial brain tumors cellularity (85% accuracy compared to biopsy). The use of more data is recommended in order to increase the percent accuracy of this techniques. PMID:27757181

  4. Solar Irradiance Variations on Active Region Time Scales

    NASA Technical Reports Server (NTRS)

    Labonte, B. J. (Editor); Chapman, G. A. (Editor); Hudson, H. S. (Editor); Willson, R. C. (Editor)

    1984-01-01

    The variations of the total solar irradiance is an important tool for studying the Sun, thanks to the development of very precise sensors such as the ACRIM instrument on board the Solar Maximum Mission. The largest variations of the total irradiance occur on time scales of a few days are caused by solar active regions, especially sunspots. Efforts were made to describe the active region effects on total and spectral irradiance.

  5. Biogenic Calcium Phosphate Transformation in Soils over Millennium Time Scales

    SciTech Connect

    Sato, S.; Neves, E; Solomon, D; Liang, B; Lehmann, J

    2009-01-01

    Changes in bioavailability of phosphorus (P) during pedogenesis and ecosystem development have been shown for geogenic calcium phosphate (Ca-P). However, very little is known about long-term changes of biogenic Ca-P in soil. Long-term transformation characteristics of biogenic Ca-P were examined using anthropogenic soils along a chronosequence from centennial to millennial time scales. Phosphorus fractionation of Anthrosols resulted in overall consistency with the Walker and Syers model of geogenic Ca-P transformation during pedogenesis. The biogenic Ca-P (e.g., animal and fish bones) disappeared to 3% of total P within the first ca. 2,000 years of soil development. This change concurred with increases in P adsorbed on metal-oxides surfaces, organic P, and occluded P at different pedogenic time. Phosphorus K-edge X-ray absorption near-edge structure (XANES) spectroscopy revealed that the crystalline and therefore thermodynamically most stable biogenic Ca-P was transformed into more soluble forms of Ca-P over time. While crystalline hydroxyapatite (34% of total P) dominated Ca-P species after about 600-1,000 years, {Beta}-tricalcium phosphate increased to 16% of total P after 900-1,100 years, after which both Ca-P species disappeared. Iron-associated P was observable concurrently with Ca-P disappearance. Soluble P and organic P determined by XANES maintained relatively constant (58-65%) across the time scale studied. Conclusions - Disappearance of crystalline biogenic Ca-P on a time scale of a few thousand years appears to be ten times faster than that of geogenic Ca-P.

  6. Scaling detection in time series: diffusion entropy analysis.

    PubMed

    Scafetta, Nicola; Grigolini, Paolo

    2002-09-01

    The methods currently used to determine the scaling exponent of a complex dynamic process described by a time series are based on the numerical evaluation of variance. This means that all of them can be safely applied only to the case where ordinary statistical properties hold true even if strange kinetics are involved. We illustrate a method of statistical analysis based on the Shannon entropy of the diffusion process generated by the time series, called diffusion entropy analysis (DEA). We adopt artificial Gauss and Lévy time series, as prototypes of ordinary and anomalous statistics, respectively, and we analyze them with the DEA and four ordinary methods of analysis, some of which are very popular. We show that the DEA determines the correct scaling exponent even when the statistical properties, as well as the dynamic properties, are anomalous. The other four methods produce correct results in the Gauss case but fail to detect the correct scaling in the case of Lévy statistics. PMID:12366207

  7. Time scale interactions and the coevolution of humans and water

    NASA Astrophysics Data System (ADS)

    Sivapalan, Murugesu; Blöschl, Günter

    2015-09-01

    We present a coevolutionary view of hydrologic systems, revolving around feedbacks between environmental and social processes operating across different time scales. This brings to the fore an emphasis on emergent phenomena in changing water systems, such as the levee effect, adaptation to change, system lock-in, and system collapse due to resource depletion. Changing human values play a key role in the emergence of these phenomena and should therefore be considered as internal to the system. Guidance is provided for the framing and modeling of these phenomena to test alternative hypotheses about how they arose. A plurality of coevolutionary models, from stylized to comprehensive system-of-system models, may assist strategic water management for long time scales through facilitating stakeholder participation, exploring the possibility space of alternative futures, and helping to synthesize the observed dynamics in a wide range of case studies. Future research opportunities lie in exploring emergent phenomena arising from time scale interactions through historical, comparative, and process studies of human-water feedbacks.

  8. Computational Modeling of Semiconductor Dynamics at Femtosecond Time Scales

    NASA Technical Reports Server (NTRS)

    Agrawal, Govind P.; Goorjian, Peter M.

    1998-01-01

    The main objective of the Joint-Research Interchange NCC2-5149 was to develop computer codes for accurate simulation of femtosecond pulse propagation in semiconductor lasers and semiconductor amplifiers [I]. The code should take into account all relevant processes such as the interband and intraband carrier relaxation mechanisms and the many-body effects arising from the Coulomb interaction among charge carriers [2]. This objective was fully accomplished. We made use of a previously developed algorithm developed at NASA Ames [3]-[5]. The new algorithm was tested on several problems of practical importance. One such problem was related to the amplification of femtosecond optical pulses in semiconductors. These results were presented in several international conferences over a period of three years. With the help of a postdoctoral fellow, we also investigated the origin of instabilities that can lead to the formation of femtosecond pulses in different kinds of lasers. We analyzed the occurrence of absolute instabilities in lasers that contain a dispersive host material with third-order nonlinearities. Starting from the Maxwell-Bloch equations, we derived general multimode equations to distinguish between convective and absolute instabilities. We find that both self-phase modulation and intensity-dependent absorption can dramatically affect the absolute stability of such lasers. In particular, the self-pulsing threshold (the so-called second laser threshold) can occur at few times the first laser threshold even in good-cavity lasers for which no self-pulsing occurs in the absence of intensity-dependent absorption. These results were presented in an international conference and published in the form of two papers.

  9. Scaling brain size, keeping timing: evolutionary preservation of brain rhythms.

    PubMed

    Buzsáki, György; Logothetis, Nikos; Singer, Wolf

    2013-10-30

    Despite the several-thousand-fold increase of brain volume during the course of mammalian evolution, the hierarchy of brain oscillations remains remarkably preserved, allowing for multiple-time-scale communication within and across neuronal networks at approximately the same speed, irrespective of brain size. Deployment of large-diameter axons of long-range neurons could be a key factor in the preserved time management in growing brains. We discuss the consequences of such preserved network constellation in mental disease, drug discovery, and interventional therapies.

  10. Scaling Brain Size, Keeping Timing: Evolutionary Preservation of Brain Rhythms

    PubMed Central

    Buzsáki, György; Logothetis, Nikos; Singer, Wolf

    2014-01-01

    Despite the several-thousand-fold increase of brain volume during the course of mammalian evolution, the hierarchy of brain oscillations remains remarkably preserved, allowing for multiple-time-scale communication within and across neuronal networks at approximately the same speed, irrespective of brain size. Deployment of large-diameter axons of long-range neurons could be a key factor in the preserved time management in growing brains. We discuss the consequences of such preserved network constellation in mental disease, drug discovery, and interventional therapies. PMID:24183025

  11. Scale and time dependence of serial correlations in word-length time series of written texts

    NASA Astrophysics Data System (ADS)

    Rodriguez, E.; Aguilar-Cornejo, M.; Femat, R.; Alvarez-Ramirez, J.

    2014-11-01

    This work considered the quantitative analysis of large written texts. To this end, the text was converted into a time series by taking the sequence of word lengths. The detrended fluctuation analysis (DFA) was used for characterizing long-range serial correlations of the time series. To this end, the DFA was implemented within a rolling window framework for estimating the variations of correlations, quantified in terms of the scaling exponent, strength along the text. Also, a filtering derivative was used to compute the dependence of the scaling exponent relative to the scale. The analysis was applied to three famous English-written literary narrations; namely, Alice in Wonderland (by Lewis Carrol), Dracula (by Bram Stoker) and Sense and Sensibility (by Jane Austen). The results showed that high correlations appear for scales of about 50-200 words, suggesting that at these scales the text contains the stronger coherence. The scaling exponent was not constant along the text, showing important variations with apparent cyclical behavior. An interesting coincidence between the scaling exponent variations and changes in narrative units (e.g., chapters) was found. This suggests that the scaling exponent obtained from the DFA is able to detect changes in narration structure as expressed by the usage of words of different lengths.

  12. Nanosecond Relaxation Dynamics of Hydrated Proteins: Water versus protein contributions

    SciTech Connect

    Khodadadi, S; Curtis, J. E.; Sokolov, Alexei P

    2011-01-01

    We have studied picosecond to nanosecond dynamics of hydrated protein powders using dielectric spectroscopy and molecular dynamics (MD) simulations. Our analysis of hydrogen-atom single particle dynamics from MD simulations focused on main ( main tens of picoseconds) and slow ( slow nanosecond) relaxation processes that were observed in dielectric spectra of similar hydrated protein samples. Traditionally, the interpretation of these processes observed in dielectric spectra has been ascribed to the relaxation behavior of hydration water tightly bounded to a protein and not to protein atoms. Detailed analysis of the MD simulations and comparison to dielectric data indicate that the observed relaxation process in the nanosecond time range of hydrated protein spectra is mainly due to protein atoms. The relaxation processes involve the entire structure of protein including atoms in the protein backbone, side chains, and turns. Both surface and buried protein atoms contribute to the slow processes; however, surface atoms demonstrate slightly faster relaxation dynamics. Analysis of the water molecule residence and dipolar relaxation correlation behavior indicates that the hydration water relaxes at much shorter time scales.

  13. Modulated heterodyne light scattering set-up for measuring long relaxation time at small and wide angle

    SciTech Connect

    Leone, Nancy; Villari, Valentina; Micali, Norberto

    2012-08-15

    We present a simple, compact, and versatile experimental setup working in the heterodyne detection mode with modulation of the reference beam. The system is implemented with a collection optics based on a unimodal optical fiber coupler. This choice allows the heterodyne to be used in a wide range of scattering angles, even for very small ones, without losing the optical beating. The apparatus can be successfully used to study translational diffusive dynamics of dispersed particles at scattering angles smaller than 5 Degree-Sign and it is suitable for exploring slow relaxation processes in sub-Hertz frequency domain, for example, in glass-forming systems. It is also possible to measure the electrophoretic mobility by applying an electric field into a charged particles solution.

  14. Two-time-scale population evolution on a singular landscape

    NASA Astrophysics Data System (ADS)

    Xu, Song; Jiao, Shuyun; Jiang, Pengyao; Ao, Ping

    2014-01-01

    Under the effect of strong genetic drift, it is highly probable to observe gene fixation or gene loss in a population, shown by singular peaks on a potential landscape. The genetic drift-induced noise gives rise to two-time-scale diffusion dynamics on the bipeaked landscape. We find that the logarithmically divergent (singular) peaks do not necessarily imply infinite escape times or biological fixations by iterating the Wright-Fisher model and approximating the average escape time. Our analytical results under weak mutation and weak selection extend Kramers's escape time formula to models with B (Beta) function-like equilibrium distributions and overcome constraints in previous methods. The constructed landscape provides a coherent description for the bistable system, supports the quantitative analysis of bipeaked dynamics, and generates mathematical insights for understanding the boundary behaviors of the diffusion model.

  15. Density relaxation and particle motion characteristics in a non-ionic deep eutectic solvent (acetamide + urea): time-resolved fluorescence measurements and all-atom molecular dynamics simulations.

    PubMed

    Das, Anuradha; Das, Suman; Biswas, Ranjit

    2015-01-21

    Temperature dependent relaxation dynamics, particle motion characteristics, and heterogeneity aspects of deep eutectic solvents (DESs) made of acetamide (CH3CONH2) and urea (NH2CONH2) have been investigated by employing time-resolved fluorescence measurements and all-atom molecular dynamics simulations. Three different compositions (f) for the mixture [fCH3CONH2 + (1 - f)NH2CONH2] have been studied in a temperature range of 328-353 K which is ∼120-145 K above the measured glass transition temperatures (∼207 K) of these DESs but much lower than the individual melting temperature of either of the constituents. Steady state fluorescence emission measurements using probe solutes with sharply different lifetimes do not indicate any dependence on excitation wavelength in these metastable molten systems. Time-resolved fluorescence anisotropy measurements reveal near-hydrodynamic coupling between medium viscosity and rotation of a dissolved dipolar solute. Stokes shift dynamics have been found to be too fast to be detected by the time-resolution (∼70 ps) employed, suggesting extremely rapid medium polarization relaxation. All-atom simulations reveal Gaussian distribution for particle displacements and van Hove correlations, and significant overlap between non-Gaussian (α2) and new non-Gaussian (γ) heterogeneity parameters. In addition, no stretched exponential relaxations have been detected in the simulated wavenumber dependent acetamide dynamic structure factors. All these results are in sharp contrast to earlier observations for ionic deep eutectics with acetamide [Guchhait et al., J. Chem. Phys. 140, 104514 (2014)] and suggest a fundamental difference in interaction and dynamics between ionic and non-ionic deep eutectic solvent systems.

  16. Density relaxation and particle motion characteristics in a non-ionic deep eutectic solvent (acetamide + urea): Time-resolved fluorescence measurements and all-atom molecular dynamics simulations

    NASA Astrophysics Data System (ADS)

    Das, Anuradha; Das, Suman; Biswas, Ranjit

    2015-01-01

    Temperature dependent relaxation dynamics, particle motion characteristics, and heterogeneity aspects of deep eutectic solvents (DESs) made of acetamide (CH3CONH2) and urea (NH2CONH2) have been investigated by employing time-resolved fluorescence measurements and all-atom molecular dynamics simulations. Three different compositions (f) for the mixture [fCH3CONH2 + (1 - f)NH2CONH2] have been studied in a temperature range of 328-353 K which is ˜120-145 K above the measured glass transition temperatures (˜207 K) of these DESs but much lower than the individual melting temperature of either of the constituents. Steady state fluorescence emission measurements using probe solutes with sharply different lifetimes do not indicate any dependence on excitation wavelength in these metastable molten systems. Time-resolved fluorescence anisotropy measurements reveal near-hydrodynamic coupling between medium viscosity and rotation of a dissolved dipolar solute. Stokes shift dynamics have been found to be too fast to be detected by the time-resolution (˜70 ps) employed, suggesting extremely rapid medium polarization relaxation. All-atom simulations reveal Gaussian distribution for particle displacements and van Hove correlations, and significant overlap between non-Gaussian (α2) and new non-Gaussian (γ) heterogeneity parameters. In addition, no stretched exponential relaxations have been detected in the simulated wavenumber dependent acetamide dynamic structure factors. All these results are in sharp contrast to earlier observations for ionic deep eutectics with acetamide [Guchhait et al., J. Chem. Phys. 140, 104514 (2014)] and suggest a fundamental difference in interaction and dynamics between ionic and non-ionic deep eutectic solvent systems.

  17. Density relaxation and particle motion characteristics in a non-ionic deep eutectic solvent (acetamide + urea): Time-resolved fluorescence measurements and all-atom molecular dynamics simulations

    SciTech Connect

    Das, Anuradha; Das, Suman; Biswas, Ranjit

    2015-01-21

    Temperature dependent relaxation dynamics, particle motion characteristics, and heterogeneity aspects of deep eutectic solvents (DESs) made of acetamide (CH{sub 3}CONH{sub 2}) and urea (NH{sub 2}CONH{sub 2}) have been investigated by employing time-resolved fluorescence measurements and all-atom molecular dynamics simulations. Three different compositions (f) for the mixture [fCH{sub 3}CONH{sub 2} + (1 − f)NH{sub 2}CONH{sub 2}] have been studied in a temperature range of 328-353 K which is ∼120-145 K above the measured glass transition temperatures (∼207 K) of these DESs but much lower than the individual melting temperature of either of the constituents. Steady state fluorescence emission measurements using probe solutes with sharply different lifetimes do not indicate any dependence on excitation wavelength in these metastable molten systems. Time-resolved fluorescence anisotropy measurements reveal near-hydrodynamic coupling between medium viscosity and rotation of a dissolved dipolar solute. Stokes shift dynamics have been found to be too fast to be detected by the time-resolution (∼70 ps) employed, suggesting extremely rapid medium polarization relaxation. All-atom simulations reveal Gaussian distribution for particle displacements and van Hove correlations, and significant overlap between non-Gaussian (α{sub 2}) and new non-Gaussian (γ) heterogeneity parameters. In addition, no stretched exponential relaxations have been detected in the simulated wavenumber dependent acetamide dynamic structure factors. All these results are in sharp contrast to earlier observations for ionic deep eutectics with acetamide [Guchhait et al., J. Chem. Phys. 140, 104514 (2014)] and suggest a fundamental difference in interaction and dynamics between ionic and non-ionic deep eutectic solvent systems.

  18. Density relaxation and particle motion characteristics in a non-ionic deep eutectic solvent (acetamide + urea): time-resolved fluorescence measurements and all-atom molecular dynamics simulations.

    PubMed

    Das, Anuradha; Das, Suman; Biswas, Ranjit

    2015-01-21

    Temperature dependent relaxation dynamics, particle motion characteristics, and heterogeneity aspects of deep eutectic solvents (DESs) made of acetamide (CH3CONH2) and urea (NH2CONH2) have been investigated by employing time-resolved fluorescence measurements and all-atom molecular dynamics simulations. Three different compositions (f) for the mixture [fCH3CONH2 + (1 - f)NH2CONH2] have been studied in a temperature range of 328-353 K which is ∼120-145 K above the measured glass transition temperatures (∼207 K) of these DESs but much lower than the individual melting temperature of either of the constituents. Steady state fluorescence emission measurements using probe solutes with sharply different lifetimes do not indicate any dependence on excitation wavelength in these metastable molten systems. Time-resolved fluorescence anisotropy measurements reveal near-hydrodynamic coupling between medium viscosity and rotation of a dissolved dipolar solute. Stokes shift dynamics have been found to be too fast to be detected by the time-resolution (∼70 ps) employed, suggesting extremely rapid medium polarization relaxation. All-atom simulations reveal Gaussian distribution for particle displacements and van Hove correlations, and significant overlap between non-Gaussian (α2) and new non-Gaussian (γ) heterogeneity parameters. In addition, no stretched exponential relaxations have been detected in the simulated wavenumber dependent acetamide dynamic structure factors. All these results are in sharp contrast to earlier observations for ionic deep eutectics with acetamide [Guchhait et al., J. Chem. Phys. 140, 104514 (2014)] and suggest a fundamental difference in interaction and dynamics between ionic and non-ionic deep eutectic solvent systems. PMID:25612718

  19. Multiple-relaxation-time lattice Boltzmann model for incompressible miscible flow with large viscosity ratio and high Péclet number

    NASA Astrophysics Data System (ADS)

    Meng, Xuhui; Guo, Zhaoli

    2015-10-01

    A lattice Boltzmann model with a multiple-relaxation-time (MRT) collision operator is proposed for incompressible miscible flow with a large viscosity ratio as well as a high Péclet number in this paper. The equilibria in the present model are motivated by the lattice kinetic scheme previously developed by Inamuro et al. [Philos. Trans. R. Soc. London, Ser. A 360, 477 (2002), 10.1098/rsta.2001.0942]. The fluid viscosity and diffusion coefficient depend on both the corresponding relaxation times and additional adjustable parameters in this model. As a result, the corresponding relaxation times can be adjusted in proper ranges to enhance the performance of the model. Numerical validations of the Poiseuille flow and a diffusion-reaction problem demonstrate that the proposed model has second-order accuracy in space. Thereafter, the model is used to simulate flow through a porous medium, and the results show that the proposed model has the advantage to obtain a viscosity-independent permeability, which makes it a robust method for simulating flow in porous media. Finally, a set of simulations are conducted on the viscous miscible displacement between two parallel plates. The results reveal that the present model can be used to simulate, to a high level of accuracy, flows with large viscosity ratios and/or high Péclet numbers. Moreover, the present model is shown to provide superior stability in the limit of high kinematic viscosity. In summary, the numerical results indicate that the present lattice Boltzmann model is an ideal numerical tool for simulating flow with a large viscosity ratio and/or a high Péclet number.

  20. Development of a sub-scale dynamics model for pressure relaxation of multi-material cells in Lagrangian hydrodynamics

    SciTech Connect

    Harrison, Alan K; Shashkov, Mikhail J; Fung, Jimmy; Canfield, Thomas R; Kamm, James R

    2010-10-14

    We have extended the Sub-Scale Dynamics (SSD) closure model for multi-fluid computational cells. Volume exchange between two materials is based on the interface area and a notional interface translation velocity, which is derived from a linearized Riemann solution. We have extended the model to cells with any number of materials, computing pressure-difference-driven volume and energy exchange as the algebraic sum of pairwise interactions. In multiple dimensions, we rely on interface reconstruction to provide interface areas and orientations, and centroids of material polygons. In order to prevent unphysically large or unmanageably small material volumes, we have used a flux-corrected transport (FCT) approach to limit the pressure-driven part of the volume exchange. We describe the implementation of this model in two dimensions in the FLAG hydrodynamics code. We also report on Lagrangian test calculations, comparing them with others made using a mixed-zone closure model due to Tipton, and with corresponding calculations made with only single-material cells. We find that in some cases, the SSD model more accurately predicts the state of material in mixed cells. By comparing the algebraic forms of both models, we identify similar dependencies on state and dynamical variables, and propose explanations for the apparent higher fidelity of the SSD model.

  1. Dominant time scale for brittle fragmentation of vesicular magma by decompression

    NASA Astrophysics Data System (ADS)

    Kameda, Masaharu; Kuribara, Hideaki; Ichihara, Mie

    2008-07-01

    Brittle fragmentation was examined in a vesicular material analogous to magma, in this case, maltose syrup with bubbles. All the key time scales for magma fragmentation are controlled in the experiment using a rapid decompression facility. It was found that the onset of fragmentation can be well characterized using the Maxwell relaxation time τ r and the decompression time Δt dec, in the case where sufficiently large stress is generated in the material. As the ratio Δt dec/τ r increases from less than unity to over fifty, the response of the specimen changes from brittle fragmentation to ductile expansion without fragmentation. During the transition, the specimen exhibits small ductile deformation before the onset of fragmentation. The transition occurs even though the stress at the bubble wall is the same. The results suggest that Δt dec/τ r is the controlling parameter not only for the onset of, but also for the variation of magma fragmentation by decompression.

  2. Unconventional Superconductivity in La7Ir3 Revealed by Muon Spin Relaxation: Introducing a New Family of Noncentrosymmetric Superconductor That Breaks Time-Reversal Symmetry

    NASA Astrophysics Data System (ADS)

    Barker, J. A. T.; Singh, D.; Thamizhavel, A.; Hillier, A. D.; Lees, M. R.; Balakrishnan, G.; Paul, D. McK.; Singh, R. P.

    2015-12-01

    The superconductivity of the noncentrosymmetric compound La7 Ir3 is investigated using muon spin rotation and relaxation. Zero-field measurements reveal the presence of spontaneous static or quasistatic magnetic fields below the superconducting transition temperature Tc=2.25 K —a clear indication that the superconducting state breaks time-reversal symmetry. Furthermore, transverse-field rotation measurements suggest that the superconducting gap is isotropic and that the pairing symmetry of the superconducting electrons is predominantly s wave with an enhanced binding strength. The results indicate that the superconductivity in La7 Ir3 may be unconventional and paves the way for further studies of this family of materials.

  3. Measurement of longitudinal relaxation times in crowded 1H NMR spectra using one- and two-dimensional maximum quantum (MAXY) NMR spectroscopy

    NASA Astrophysics Data System (ADS)

    Liu, Maili; Ye, Chaohui; Farrant, R. Duncan; Nicholson, Jeremy K.; Lindon, John C.

    Methods for measuring longitudinal relaxation times of protons in heavily overlapped 1H NMR spectra are introduced and exemplified using a solution of cholesteryl acetate. The methods are based on 1-dimensional and 2-dimensional maximum quantum NMR spectroscopy (MAXY), which makes possible the selective detection of CH, CH2 and CH31H NMR resonances. A modification of the BIRD pulse sequence to achieve selective inversion of protons bonded to either 12C or 13C is given. The approach should find application in studies of molecular dynamics where isotopic enrichment is not possible and the level of available sample dictates the use of 1H NMR spectroscopy.

  4. Lattice-level observation of the elastic-to-plastic relaxation process with subnanosecond resolution in shock-compressed Ta using time-resolved in situ Laue diffraction

    SciTech Connect

    Wehrenberg, C. E.; Comley, A. J.; Barton, N. R.; Coppari, F.; Fratanduono, D.; Huntington, C. M.; Maddox, B. R.; Park, H. -S.; Plechaty, C.; Prisbrey, S. T.; Remington, B. A.; Rudd, R. E.

    2015-09-29

    We report direct lattice level measurements of plastic relaxation kinetics through time-resolved, in-situ Laue diffraction of shock-compressed single-crystal [001] Ta at pressures of 27-210 GPa. For a 50 GPa shock, a range of shear strains is observed extending up to the uniaxial limit for early data points (<0.6 ns) and the average shear strain relaxes to a near steady state over ~1 ns. For 80 and 125 GPa shocks, the measured shear strains are fully relaxed already at 200 ps, consistent with rapid relaxation associated with the predicted threshold for homogeneous nucleation of dislocations occurring at shock pressure ~65 GPa. The relaxation rate and shear stresses are used to estimate the dislocation density and these quantities are compared to the Livermore Multiscale Strength model as well as various molecular dynamics simulations.

  5. Time scale hierarchies in the functional organization of complex behaviors.

    PubMed

    Perdikis, Dionysios; Huys, Raoul; Jirsa, Viktor K

    2011-09-01

    Traditional approaches to cognitive modelling generally portray cognitive events in terms of 'discrete' states (point attractor dynamics) rather than in terms of processes, thereby neglecting the time structure of cognition. In contrast, more recent approaches explicitly address this temporal dimension, but typically provide no entry points into cognitive categorization of events and experiences. With the aim to incorporate both these aspects, we propose a framework for functional architectures. Our approach is grounded in the notion that arbitrary complex (human) behaviour is decomposable into functional modes (elementary units), which we conceptualize as low-dimensional dynamical objects (structured flows on manifolds). The ensemble of modes at an agent's disposal constitutes his/her functional repertoire. The modes may be subjected to additional dynamics (termed operational signals), in particular, instantaneous inputs, and a mechanism that sequentially selects a mode so that it temporarily dominates the functional dynamics. The inputs and selection mechanisms act on faster and slower time scales then that inherent to the modes, respectively. The dynamics across the three time scales are coupled via feedback, rendering the entire architecture autonomous. We illustrate the functional architecture in the context of serial behaviour, namely cursive handwriting. Subsequently, we investigate the possibility of recovering the contributions of functional modes and operational signals from the output, which appears to be possible only when examining the output phase flow (i.e., not from trajectories in phase space or time). PMID:21980278

  6. Time scaling of tree rings cell production in Siberia

    NASA Astrophysics Data System (ADS)

    Popkova, Margarita; Babushkina, Elena; Tychkov, Ivan; Shishov, Vladimir; Vaganov, Eugene

    2016-04-01

    It is assumed that an annual tree-ring growth is adequately determined by a linear function of local or regional precipitation and temperature with a set of coefficients that are temporally invariant. But often that relations are non-linear. The process-based tree-ring VS-model can be used to resolve the critical processes linking climate variables to tree-ring formation. This work describes a new block of VS-model which allows to estimate a cell production in tree rings and transfer it into time scale based on the simulated integral growth rates of the model. In the algorithm of time identification for cell production we used a integral growth rates simulated by the VS-model for each growing season. The obtained detailed approach with a calculation of the time of each cell formation improves significantly the date accuracy of new cell formation in growing season. As a result for each cell in the tree-ring we estimate the temporal moment of the cell production corresponded to the seasonal growth rate in the same time scale. The approach was applied and tested for the cell measurements obtained for Scots pine (Pinus sylvestris) for the period 1964-2013 in Malaya Minusa river (Khakassia, South Siberia). The work was supported by the Russian Science Foundation (RSF # 14-14-00219)

  7. A Hierarchy of Time-Scales and the Brain

    PubMed Central

    Kiebel, Stefan J.; Daunizeau, Jean; Friston, Karl J.

    2008-01-01

    In this paper, we suggest that cortical anatomy recapitulates the temporal hierarchy that is inherent in the dynamics of environmental states. Many aspects of brain function can be understood in terms of a hierarchy of temporal scales at which representations of the environment evolve. The lowest level of this hierarchy corresponds to fast fluctuations associated with sensory processing, whereas the highest levels encode slow contextual changes in the environment, under which faster representations unfold. First, we describe a mathematical model that exploits the temporal structure of fast sensory input to track the slower trajectories of their underlying causes. This model of sensory encoding or perceptual inference establishes a proof of concept that slowly changing neuronal states can encode the paths or trajectories of faster sensory states. We then review empirical evidence that suggests that a temporal hierarchy is recapitulated in the macroscopic organization of the cortex. This anatomic-temporal hierarchy provides a comprehensive framework for understanding cortical function: the specific time-scale that engages a cortical area can be inferred by its location along a rostro-caudal gradient, which reflects the anatomical distance from primary sensory areas. This is most evident in the prefrontal cortex, where complex functions can be explained as operations on representations of the environment that change slowly. The framework provides predictions about, and principled constraints on, cortical structure–function relationships, which can be tested by manipulating the time-scales of sensory input. PMID:19008936

  8. The Role of Time-Scales in Socio-hydrology

    NASA Astrophysics Data System (ADS)

    Blöschl, Günter; Sivapalan, Murugesu

    2016-04-01

    Much of the interest in hydrological modeling in the past decades revolved around resolving spatial variability. With the rapid changes brought about by human impacts on the hydrologic cycle, there is now an increasing need to refocus on time dependency. We present a co-evolutionary view of hydrologic systems, in which every part of the system including human systems, co-evolve, albeit at different rates. The resulting coupled human-nature system is framed as a dynamical system, characterized by interactions of fast and slow time scales and feedbacks between environmental and social processes. This gives rise to emergent phenomena such as the levee effect, adaptation to change and system collapse due to resource depletion. Changing human values play a key role in the emergence of these phenomena and should therefore be considered as internal to the system in a dynamic way. The co-evolutionary approach differs from the traditional view of water resource systems analysis as it allows for path dependence, multiple equilibria, lock-in situations and emergent phenomena. The approach may assist strategic water management for long time scales through facilitating stakeholder participation, exploring the possibility space of alternative futures, and helping to synthesise the observed dynamics of different case studies. Future research opportunities include the study of how changes in human values are connected to human-water interactions, historical analyses of trajectories of system co-evolution in individual places and comparative analyses of contrasting human-water systems in different climate and socio-economic settings. Reference Sivapalan, M. and G. Blöschl (2015) Time scale interactions and the coevolution of humans and water. Water Resour. Res., 51, 6988-7022, doi:10.1002/2015WR017896.

  9. Terrestrial Waters and Sea Level Variations on Interannual Time Scale

    NASA Technical Reports Server (NTRS)

    Llovel, W.; Becker, M.; Cazenave, A.; Jevrejeva, S.; Alkama, R.; Decharme, B.; Douville, H.; Ablain, M.; Beckley, B.

    2011-01-01

    On decadal to multi-decadal time scales, thermal expansion of sea waters and land ice loss are the main contributors to sea level variations. However, modification of the terrestrial water cycle due to climate variability and direct anthropogenic forcing may also affect sea level. For the past decades, variations in land water storage and corresponding effects on sea level cannot be directly estimated from observations because these are almost non-existent at global continental scale. However, global hydrological models developed for atmospheric and climatic studies can be used for estimating total water storage. For the recent years (since mid-2002), terrestrial water storage change can be directly estimated from observations of the GRACE space gravimetry mission. In this study, we analyse the interannual variability of total land water storage, and investigate its contribution to mean sea level variability at interannual time scale. We consider three different periods that, each, depend on data availability: (1) GRACE era (2003-2009), (2) 1993-2003 and (3) 1955-1995. For the GRACE era (period 1), change in land water storage is estimated using different GRACE products over the 33 largest river basins worldwide. For periods 2 and 3, we use outputs from the ISBA-TRIP (Interactions between Soil, Biosphere, and Atmosphere-Total Runoff Integrating Pathways) global hydrological model. For each time span, we compare change in land water storage (expressed in sea level equivalent) to observed mean sea level, either from satellite altimetry (periods 1 and 2) or tide gauge records (period 3). For each data set and each time span, a trend has been removed as we focus on the interannual variability. We show that whatever the period considered, interannual variability of the mean sea level is essentially explained by interannual fluctuations in land water storage, with the largest contributions arising from tropical river basins.

  10. Single-relaxation-time lattice Boltzmann scheme for advection-diffusion problems with large diffusion-coefficient heterogeneities and high-advection transport.

    PubMed

    Perko, Janez; Patel, Ravi A

    2014-05-01

    The paper presents an approach that extends the flexibility of the standard lattice Boltzmann single relaxation time scheme in terms of spatial variation of dissipative terms (e.g., diffusion coefficient) and stability for high Péclet mass transfer problems. Spatial variability of diffusion coefficient in SRT is typically accommodated through the variation of relaxation time during the collision step. This method is effective but cannot deal with large diffusion coefficient variations, which can span over several orders of magnitude in some natural systems. The approach explores an alternative way of dealing with large diffusion coefficient variations in advection-diffusion transport systems by introducing so-called diffusion velocity. The diffusion velocity is essentially an additional convective term that replaces variations in diffusion coefficients vis-à-vis a chosen reference diffusion coefficient which defines the simulation time step. Special attention is paid to the main idea behind the diffusion velocity formulation and its implementation into the lattice Boltzmann framework. Finally, the performance, stability, and accuracy of the diffusion velocity formulation are discussed via several advection-diffusion transport benchmark examples. These examples demonstrate improved stability and flexibility of the proposed scheme with marginal consequences on the numerical performance.

  11. EEG-based time and spatial interpretation of activation areas for relaxation and words writing between poor and capable dyslexic children.

    PubMed

    Mohamad, N B; Lee, Khuan Y; Mansor, W; Mahmoodin, Z; Fadzal, C W N F C W; Amirin, S

    2015-01-01

    Symptoms of dyslexia such as difficulties with accurate and/or fluent word recognition, and/or poor spelling as well as decoding abilities, are easily misinterpreted as laziness and defiance amongst school children. Indeed, 37.9% of 699 school dropouts and failures are diagnosed as dyslexic. Currently, Screening for dyslexia relies heavily on therapists, whom are few and subjective, yet objective methods are still unavailable. EEG has long been a popular method to study the cognitive processes in human such as language processing and motor activity. However, its interpretation is limited to time and frequency domain, without visual information, which is still useful. Here, our research intends to illustrate an EEG-based time and spatial interpretation of activated brain areas for the poor and capable dyslexic during the state of relaxation and words writing, being the first attempt ever reported. From the 2D distribution of EEG spectral at the activation areas and its progress with time, it is observed that capable dyslexics are able to relax compared to poor dyslexics. During the state of words writing, neural activities are found higher on the right hemisphere than the left hemisphere of the capable dyslexics, which suggests a neurobiological compensation pathway in the right hemisphere, during reading and writing, which is not observed in the poor dyslexics.

  12. Two-body relaxation in simulated cosmological haloes

    NASA Astrophysics Data System (ADS)

    El-Zant, Amr A.

    2006-08-01

    This paper aims to quantify, in a general manner that does not directly resort to large-scale calculations, discreteness effects acting on the dynamics of dark matter haloes forming in the context of cosmological simulations. By generalizing the standard formulation of two-body relaxation to the case when the size and mass distributions are variable, and parametrizing the time evolution using established empirical relations, we find that the dynamics of a million-particle halo is noise-dominated within the inner per cent of the final virial radius. Far larger particle numbers (~108) are required for the rms perturbations to the velocity to drop to the 10per cent level there. The radial scaling of the relaxation time is simple and strong: trelax ~r2, implying that numbers >>108 are required to faithfully model the very inner regions; artificial relaxation may thus constitute an important factor, contributing to the contradictory claims concerning the persistence of a power-law density cusp to the very centre. The cores of substructure haloes can be many relaxation times old. Since relaxation first causes their expansion before recontraction occurs, it may render them either more difficult or easier to disrupt, depending on their orbital parameters. This may modify the characteristics of the subhalo distribution; and if, as suggested by several authors, it is parent-satellite interactions that determine halo profiles, the overall structure of the system may be affected. We derive simple closed form formulae for the characteristic relaxation time of both parents and satellites, and an elementary argument deducing the weak N-scaling reported by Diemand et al. when the main contribution comes from relaxing subhaloes.

  13. Decay of surface nanostructures via long-time-scale dynamics

    SciTech Connect

    Voter, A.F.; Stanciu, N.

    1998-11-01

    This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The authors have developed a new approach for extending the time scale of molecular dynamics simulations. For infrequent-event systems, the category that includes most diffusive events in the solid phase, this hyperdynamics method can extend the simulation time by a few orders of magnitude compared to direct molecular dynamics. The trajectory is run on a potential surface that has been biased to raise the energy in the potential basins without affecting the transition state region. The method is described and applied to surface and bulk diffusion processes, achieving microsecond and millisecond simulation times. The authors have also developed a new parallel computing method that is efficient for small system sizes. The combination of the hyperdynamics with this parallel replica dynamics looks promising as a general materials simulation tool.

  14. Optimal Control Modification for Time-Scale Separated Systems

    NASA Technical Reports Server (NTRS)

    Nguyen, Nhan T.

    2012-01-01

    Recently a new optimal control modification has been introduced that can achieve robust adaptation with a large adaptive gain without incurring high-frequency oscillations as with the standard model-reference adaptive control. This modification is based on an optimal control formulation to minimize the L2 norm of the tracking error. The optimal control modification adaptive law results in a stable adaptation in the presence of a large adaptive gain. This study examines the optimal control modification adaptive law in the context of a system with a time scale separation resulting from a fast plant with a slow actuator. A singular perturbation analysis is performed to derive a modification to the adaptive law by transforming the original system into a reduced-order system in slow time. A model matching conditions in the transformed time coordinate results in an increase in the actuator command that effectively compensate for the slow actuator dynamics. Simulations demonstrate effectiveness of the method.

  15. Multiple-Time Scaling and Universal Behavior of the Earthquake Interevent Time Distribution

    SciTech Connect

    Bottiglieri, M.; Godano, C.; Lippiello, E.; Arcangelis, L. de

    2010-04-16

    The interevent time distribution characterizes the temporal occurrence in seismic catalogs. Universal scaling properties of this distribution have been evidenced for entire catalogs and seismic sequences. Recently, these universal features have been questioned and some criticisms have been raised. We investigate the existence of universal scaling properties by analyzing a Californian catalog and by means of numerical simulations of an epidemic-type model. We show that the interevent time distribution exhibits a universal behavior over the entire temporal range if four characteristic times are taken into account. The above analysis allows us to identify the scaling form leading to universal behavior and explains the observed deviations. Furthermore, it provides a tool to identify the dependence on the mainshock magnitude of the c parameter that fixes the onset of the power law decay in the Omori law.

  16. (31)P-MRS of healthy human brain: ATP synthesis, metabolite concentrations, pH, and T1 relaxation times.

    PubMed

    Ren, Jimin; Sherry, A Dean; Malloy, Craig R

    2015-11-01

    The conventional method for measuring brain ATP synthesis is (31)P saturation transfer (ST), a technique typically dependent on prolonged pre-saturation with γ-ATP. In this study, ATP synthesis rate in resting human brain is evaluated using EBIT (exchange kinetics by band inversion transfer), a technique based on slow recovery of γ-ATP magnetization in the absence of B1 field following co-inversion of PCr and ATP resonances with a short adiabatic pulse. The unidirectional rate constant for the Pi → γ-ATP reaction is 0.21 ± 0.04 s(-1) and the ATP synthesis rate is 9.9 ± 2.1 mmol min(-1)  kg(-1) in human brain (n = 12 subjects), consistent with the results by ST. Therefore, EBIT could be a useful alternative to ST in studying brain energy metabolism in normal physiology and under pathological conditions. In addition to ATP synthesis, all detectable (31)P signals are analyzed to determine the brain concentration of phosphorus metabolites, including UDPG at around 10 ppm, a previously reported resonance in liver tissues and now confirmed in human brain. Inversion recovery measurements indicate that UDPG, like its diphosphate analogue NAD, has apparent T1 shorter than that of monophosphates (Pi, PMEs, and PDEs) but longer than that of triphosphate ATP, highlighting the significance of the (31)P-(31)P dipolar mechanism in T1 relaxation of polyphosphates. Another interesting finding is the observation of approximately 40% shorter T1 for intracellular Pi relative to extracellular Pi, attributed to the modulation by the intracellular phosphoryl exchange reaction Pi ↔ γ-ATP. The sufficiently separated intra- and extracellular Pi signals also permit the distinction of pH between intra- and extracellular environments (pH 7.0 versus pH 7.4). In summary, quantitative (31)P MRS in combination with ATP synthesis, pH, and T1 relaxation measurements may offer a promising tool to detect biochemical alterations at early stages of brain dysfunctions and diseases

  17. (31)P-MRS of healthy human brain: ATP synthesis, metabolite concentrations, pH, and T1 relaxation times.

    PubMed

    Ren, Jimin; Sherry, A Dean; Malloy, Craig R

    2015-11-01

    The conventional method for measuring brain ATP synthesis is (31)P saturation transfer (ST), a technique typically dependent on prolonged pre-saturation with γ-ATP. In this study, ATP synthesis rate in resting human brain is evaluated using EBIT (exchange kinetics by band inversion transfer), a technique based on slow recovery of γ-ATP magnetization in the absence of B1 field following co-inversion of PCr and ATP resonances with a short adiabatic pulse. The unidirectional rate constant for the Pi → γ-ATP reaction is 0.21 ± 0.04 s(-1) and the ATP synthesis rate is 9.9 ± 2.1 mmol min(-1)  kg(-1) in human brain (n = 12 subjects), consistent with the results by ST. Therefore, EBIT could be a useful alternative to ST in studying brain energy metabolism in normal physiology and under pathological conditions. In addition to ATP synthesis, all detectable (31)P signals are analyzed to determine the brain concentration of phosphorus metabolites, including UDPG at around 10 ppm, a previously reported resonance in liver tissues and now confirmed in human brain. Inversion recovery measurements indicate that UDPG, like its diphosphate analogue NAD, has apparent T1 shorter than that of monophosphates (Pi, PMEs, and PDEs) but longer than that of triphosphate ATP, highlighting the significance of the (31)P-(31)P dipolar mechanism in T1 relaxation of polyphosphates. Another interesting finding is the observation of approximately 40% shorter T1 for intracellular Pi relative to extracellular Pi, attributed to the modulation by the intracellular phosphoryl exchange reaction Pi ↔ γ-ATP. The sufficiently separated intra- and extracellular Pi signals also permit the distinction of pH between intra- and extracellular environments (pH 7.0 versus pH 7.4). In summary, quantitative (31)P MRS in combination with ATP synthesis, pH, and T1 relaxation measurements may offer a promising tool to detect biochemical alterations at early stages of brain dysfunctions and diseases.

  18. Time Scale Optimization and the Hunt for Astronomical Cycles in Deep Time Strata

    NASA Astrophysics Data System (ADS)

    Meyers, Stephen R.

    2016-04-01

    A valuable attribute of astrochronology is the direct link between chronometer and climate change, providing a remarkable opportunity to constrain the evolution of the surficial Earth System. Consequently, the hunt for astronomical cycles in strata has spurred the development of a rich conceptual framework for climatic/oceanographic change, and has allowed exploration of the geologic record with unprecedented temporal resolution. Accompanying these successes, however, has been a persistent skepticism about appropriate astrochronologic testing and circular reasoning: how does one reliably test for astronomical cycles in stratigraphic data, especially when time is poorly constrained? From this perspective, it would seem that the merits and promise of astrochronology (e.g., a geologic time scale measured in ≤400 kyr increments) also serves as its Achilles heel, if the confirmation of such short rhythms defies rigorous statistical testing. To address these statistical challenges in astrochronologic testing, a new approach has been developed that (1) explicitly evaluates time scale uncertainty, (2) is resilient to common problems associated with spectrum confidence level assessment and 'multiple testing', and (3) achieves high statistical power under a wide range of conditions (it can identify astronomical cycles when present in data). Designated TimeOpt (for "time scale optimization"; Meyers 2015), the method employs a probabilistic linear regression model framework to investigate amplitude modulation and frequency ratios (bundling) in stratigraphic data, while simultaneously determining the optimal time scale. This presentation will review the TimeOpt method, and demonstrate how the flexible statistical framework can be further extended to evaluate (and optimize upon) complex sedimentation rate models, enhancing the statistical power of the approach, and addressing the challenge of unsteady sedimentation. Meyers, S. R. (2015), The evaluation of eccentricity

  19. Time scale algorithms for an inhomogeneous group of atomic clocks

    NASA Technical Reports Server (NTRS)

    Jacques, C.; Boulanger, J.-S.; Douglas, R. J.; Morris, D.; Cundy, S.; Lam, H. F.

    1993-01-01

    Through the past 17 years, the time scale requirements at the National Research Council (NRC) have been met by the unsteered output of its primary laboratory cesium clocks, supplemented by hydrogen masers when short-term stability better than 2 x 10(exp -12)tau(sup -1/2) has been required. NRC now operates three primary laboratory cesium clocks, three hydrogen masers, and two commercial cesium clocks. NRC has been using ensemble averages for internal purposes for the past several years, and has a realtime algorithm operating on the outputs of its high-resolution (2 x 10(exp -13) s at 1 s) phase comparators. The slow frequency drift of the hydrogen masers has presented difficulties in incorporating their short-term stability into the ensemble average, while retaining the long-term stability of the laboratory cesium frequency standards. We report on this work on algorithms for an inhomogeneous ensemble of atomic clocks, and on our initial work on time scale algorithms that could incorporate frequency calibrations at NRC from the next generation of Zacharias fountain cesium frequency standards having frequency accuracies that might surpass 10(exp -15), or from single-trapped-ion frequency standards (Ba+, Sr+,...) with even higher potential accuracies. The requirements for redundancy in all the elements (including the algorithms) of an inhomogeneous ensemble that would give a robust real-time output of the algorithms are presented and discussed.

  20. Time scales in the context of general relativity.

    PubMed

    Guinot, Bernard

    2011-10-28

    Towards 1967, the accuracy of caesium frequency standards reached such a level that the relativistic effect could not be ignored anymore. Corrections began to be applied for the gravitational frequency shift and for distant time comparisons. However, these corrections were not applied to an explicit theoretical framework. Only in 1991 did the International Astronomical Union provide metrics (then improved in 2000) for a definition of space-time coordinates in reference systems centred at the barycentre of the Solar System and at the centre of mass of the Earth. In these systems, the temporal coordinates (coordinate times) can be realized on the basis of one of them, the International Atomic Time (TAI), which is itself a realized time scale. The definition and the role of TAI in this context will be recalled. There remain controversies regarding the name to be given to the unit of coordinate times and to other quantities appearing in the theory. However, the idea that astrometry and celestial mechanics should adopt the usual metrological rules is progressing, together with the use of the International System of Units, among astronomers. PMID:21930569